Determination of the cathode and anode voltage drops in high power low-pressure amalgam lamps

Energy Technology Data Exchange (ETDEWEB)

Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation); Vasiliev, A. I., E-mail: vasiliev@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V.; Startsev, A. Yu. [Joint Stock Company NPO LIT (Russian Federation); Kudryavtsev, N. N. [Moscow Institute of Physics and Technology (State University) (Russian Federation)

2011-12-15

For the first time, cathode and anode drops of powerful low-pressure amalgam lamps were measured. The lamp discharge current is 3.2 A, discharge current frequency is 43 kHz, linear electric power is 2.4 W/cm. The method of determination of a cathode drop is based on the change of a lamp operating voltage at variation of the electrode filament current at constant discharge current. The total (cathode plus anode) drop of voltage was measured by other, independent ways. The maximum cathode fall is 10.8 V; the anode fall corresponding to the maximal cathode fall is 2.4 V. It is shown that in powerful low pressure amalgam lamps the anode fall makes a considerable contribution (in certain cases, the basic one) to heating of electrodes. Therefore, the anode fall cannot be neglected, at design an electrode and ballast of amalgam lamps with operating discharge current frequency of tens of kHz.

Two-beam virtual cathode accelerator

International Nuclear Information System (INIS)

Peter, W.

1992-01-01

A proposed method to control the motion of a virtual cathode is investigated. Applications to collective ion acceleration and microwave generation are indicated. If two counterstreaming relativistic electron beams of current I are injected into a drift tube of space-charge-limiting current I L = 2I, it is shown that one beam can induce a moving virtual cathode in the other beam. By dynamically varying the current injected into the drift tube region, the virtual cathode can undergo controlled motion. For short drift tubes, the virtual cathodes on each end are strongly-coupled and undergo coherent large-amplitude spatial oscillations within the drift tube

Investigation of the Effects of Cathode Flow Fraction and Position on the Performance and Operation of the High Voltage Hall Accelerator

Science.gov (United States)

Kamhawi, Hani; Huang, Wensheng; Haag, Thomas

2014-01-01

The National Aeronautics and Space Administration (NASA) Science Mission Directorate In- Space Propulsion Technology office is sponsoring NASA Glenn Research Center (GRC) to develop a 4 kW-class Hall thruster propulsion system for implementation in NASA science missions. Tests were performed within NASA GRC Vacuum Facility 5 at background pressure levels that were six times lower than what has previously been attained in other vacuum facilities. A study was conducted to assess the impact of varying the cathode-to-anode flow fraction and cathode position on the performance and operational characteristics of the High Voltage Hall Accelerator (HiVHAc) thruster. In addition, the impact of injecting additional xenon propellant in the vicinity of the cathode was also assessed. Cathode-to-anode flow fraction sensitivity tests were performed for power levels between 1.0 and 3.9 kW. It was found that varying the cathode flow fraction from 5 to approximately 10% of the anode flow resulted in the cathode-to-ground voltage becoming more positive. For an operating condition of 3.8 kW and 500 V, varying the cathode position from a distance of closest approach to 600 mm away did not result in any substantial variation in thrust but resulted in the cathode-to-ground changing from -17 to -4 V. The change in the cathode-to-ground voltage along with visual observations indicated a change in how the cathode plume was coupling to the thruster discharge. Finally, the injection of secondary xenon flow in the vicinity of the cathode had an impact similar to increasing the cathode-to-anode flow fraction, where the cathode-to-ground voltage became more positive and discharge current and thrust increased slightly. Future tests of the HiVHAc thruster are planned with a centrally mounted cathode in order to further assess the impact of cathode position on thruster performance.

High-Capacity, High-Voltage Composite Oxide Cathode Materials

Science.gov (United States)

Hagh, Nader M.

2015-01-01

This SBIR project integrates theoretical and experimental work to enable a new generation of high-capacity, high-voltage cathode materials that will lead to high-performance, robust energy storage systems. At low operating temperatures, commercially available electrode materials for lithium-ion (Li-ion) batteries do not meet energy and power requirements for NASA's planned exploration activities. NEI Corporation, in partnership with the University of California, San Diego, has developed layered composite cathode materials that increase power and energy densities at temperatures as low as 0 degC and considerably reduce the overall volume and weight of battery packs. In Phase I of the project, through innovations in the structure and morphology of composite electrode particles, the partners successfully demonstrated an energy density exceeding 1,000 Wh/kg at 4 V at room temperature. In Phase II, the team enhanced the kinetics of Li-ion transport and electronic conductivity at 0 degC. An important feature of the composite cathode is that it has at least two components that are structurally integrated. The layered material is electrochemically inactive; however, upon structural integration with a spinel material, the layered material can be electrochemically activated and deliver a large amount of energy with stable cycling.

A new SOI high-voltage device with a step-thickness drift region and its analytical model for the electric field and breakdown voltage

International Nuclear Information System (INIS)

Luo Xiaorong; Zhang Wei; Zhang Bo; Li Zhaoji; Yang Shouguo; Zhan Zhan; Fu Daping

2008-01-01

A new SOI high-voltage device with a step-thickness drift region (ST SOI) and its analytical model for the two-dimension electric field distribution and the breakdown voltage are proposed. The electric field in the drift region is modulated and that of the buried layer is enhanced by the variable thickness SOI layer, thereby resulting in the enhancement of the breakdown voltage. Based on the Poisson equation, the expression for the two-dimension electric field distribution is presented taking the modulation effect into account, from which the RESURF (REduced SURface Field) condition and the approximate but explicit expression for the maximal breakdown voltage are derived. The analytical model can explain the effects of the device parameters, such as the step height and the step length of the SOI layer, the doping concentration and the buried oxide thickness, on the electric field distribution and the breakdown voltage. The validity of this model is demonstrated by a comparison with numerical simulations. Improvement on both the breakdown voltage and the on-resistance (R on ) for the ST SOI is obtained due to the variable thickness SOI layer

Cathode materials review

Science.gov (United States)

Daniel, Claus; Mohanty, Debasish; Li, Jianlin; Wood, David L.

2014-06-01

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

Cathode materials review

International Nuclear Information System (INIS)

Daniel, Claus; Mohanty, Debasish; Li, Jianlin; Wood, David L.

2014-01-01

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO 2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research

Cathode materials review

Energy Technology Data Exchange (ETDEWEB)

Daniel, Claus, E-mail: danielc@ornl.gov; Mohanty, Debasish, E-mail: danielc@ornl.gov; Li, Jianlin, E-mail: danielc@ornl.gov; Wood, David L., E-mail: danielc@ornl.gov [Oak Ridge National Laboratory, 1 Bethel Valley Road, MS6472 Oak Ridge, TN 37831-6472 (United States)

2014-06-16

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

Leakage Current Degradation Due to Ion Drift and Diffusion in Tantalum and Niobium Oxide Capacitors

Directory of Open Access Journals (Sweden)

Kuparowitz Martin

2017-06-01

Full Text Available High temperature and high electric field applications in tantalum and niobium capacitors are limited by the mechanism of ion migration and field crystallization in a tantalum or niobium pentoxide insulating layer. The study of leakage current (DCL variation in time as a result of increasing temperature and electric field might provide information about the physical mechanism of degradation. The experiments were performed on tantalum and niobium oxide capacitors at temperatures of about 125°C and applied voltages ranging up to rated voltages of 35 V and 16 V for tantalum and niobium oxide capacitors, respectively. Homogeneous distribution of oxygen vacancies acting as positive ions within the pentoxide layer was assumed before the experiments. DCL vs. time characteristics at a fixed temperature have several phases. At the beginning of ageing the DCL increases exponentially with time. In this period ions in the insulating layer are being moved in the electric field by drift only. Due to that the concentration of ions near the cathode increases producing a positively charged region near the cathode. The electric field near the cathode increases and the potential barrier between the cathode and insulating layer decreases which results in increasing DCL. However, redistribution of positive ions in the insulator layer leads to creation of a ion concentration gradient which results in a gradual increase of the ion diffusion current in the direction opposite to the ion drift current component. The equilibrium between the two for a given temperature and electric field results in saturation of the leakage current value. DCL vs. time characteristics are described by the exponential stretched law. We found that during the initial part of ageing an exponent n = 1 applies. That corresponds to the ion drift motion only. After long-time application of the electric field at a high temperature the DCL vs. time characteristics are described by the exponential

Phosphorus Enrichment as a New Composition in the Solid Electrolyte Interphase of High-Voltage Cathodes and Its Effects on Battery Cycling

Energy Technology Data Exchange (ETDEWEB)

Yan, Pengfei; Zheng, Jianming; Kuppan, Saravanan; Li, Qiuyan; Lv, Dongping; Xiao, Jie; Chen, Guoying; Zhang, Jiguang; Wang, Chong M.

2015-11-10

Immersion of a solid into liquid often leads to the modification of both the structure and chemistry of surface of the solid, which subsequently affects the chemical and physical properties of the system. For the case of the rechargeable lithium ion battery, such a surface modification is termed as solid electrolyte interphase (SEI) layer, which has been perceived to play critical role for the stable operation of the batteries. However, the structure and chemical composition of SEI layer and its spatial distribution and dependence on the battery operating condition remain unclear. By using aberration corrected scanning transmission electron microscopy coupled with ultra-high sensitive energy dispersive x-ray spectroscopy, we probed the structure and chemistry of SEI layer on several high voltage cathodes. We show that layer-structured cathodes, when cycled at a high cut off voltage, can form a P-rich SEI layer on their surface, which is a direct evidence of Li-salt (LiPF6) decomposition. Our systematical investigations indicate such cathode/Li-salt side reaction shows strong dependence on structure of the cathode materials, operating voltage and temperature, indicating the feasibility of SEI engineering. These findings provide us valuable insights into the complex interface between the high-voltage cathode and the electrolyte.

A Low-input-voltage Wireless Power Transfer for Biomedical Implants

DEFF Research Database (Denmark)

Jiang, Hao; Bai, Kangjun; Zhu, Weijie

2015-01-01

Wireless power transfer is an essential technology to increase implants' longevity. A pair of inductivelycoupled coils operating at radio-frequency is extensively used to deliver electrical power to implants wirelessly. In this system, a power conditioning circuit is required convert the induced...... in the rectifier for the efficient AC to DC conversion. This requirement results in larger coil size, shorter operating distance or more stringent geometrical alignment between the two coils. In this paper, a low-input-voltage wireless power transfer has been demonstrated. In this system, the opencircuit voltage...... time-varying AC power harvested by the receiving coil to a stable DC power that is needed for powering circuits and sensors. Most existing power conditioning circuits require the induced voltage of the receiving coil to be significantly higher than the turn-on voltage of the diodes used...

Electron emission of cathode holder of vacuum diode of an intense electron-beam accelerator and its effect on the output voltage

Directory of Open Access Journals (Sweden)

Xin-Bing Cheng

2011-04-01

Full Text Available The vacuum diode which is used to generate relativistic electron beams is one of the most important parts of a pulsed-power modulator. In this paper, the electron emission of cathode holder of a vacuum diode and its effect on the output voltage is investigated by experiments on an intense electron-beam accelerator with 180 ns full width at half maximum and 200–500 kV output voltage. First, the field emission is analyzed and the electric field of the vacuum chamber is calculated. Then, the flatness of the output voltage is discussed before and after adding an insulation plate when a water load is used. It is found that the electron emission at the edges of the cathode holder is the main reason to cause the change of the flatness. Last, a piece of polyester film is used as a target to further show the electron emission of the cathode holder. This analysis shows that decreasing the electron emission of the cathode holder in such a pulse power modulator could be a good way to improve the quality of the output voltage.

Construction update and drift velocity calibration for the CLAS drift chamber system

International Nuclear Information System (INIS)

Mestayer, M.D.; Barbosa, F.J.; Bonneau, P.; Burtin, E.; Christo, S.; Doolittle, G.; Dytman, S.A.; Gilfoyle, G.P.; Hyde-Wright, C.E.; Klein, A.; Kossov, M.V.; Kuhn, S.E.; Magahiz, R.; Miskimen, R.A.; Murphy, L.Y.; O'Meara, J.E.; Pyron, T.D.; Qin, L.; Raue, B.A.; Schumacher, R.A.; Tuzel, W.; Weinstein, L.B.; Yegneswaran, A.

1995-01-01

We briefly describe the drift chamber system for the CLAS detector at CEBAF, concentrating on the method which will be used to calibrate the drift velocity function. We identify key features of the function which should apply to any small-cell drift chamber geometry in which the cathode and anode surfaces are wires. Using these ideas, we describe a simple method to compensate for variations in the drift velocity function due to environmental changes. (orig.)

Construction update and drift velocity calibration for the CLAS drift chamber system

Energy Technology Data Exchange (ETDEWEB)

Mestayer, M.D. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Barbosa, F.J. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Bonneau, P. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Burtin, E. [University of South Carolina, Columbia, SC (United States); Christo, S. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Doolittle, G. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Dytman, S.A. [University of Pittsburg, Pittsburg, PA (United States); Gilfoyle, G.P. [University of Richmond, Richmond, VA (United States); Hyde-Wright, C.E. [Old Dominion University, Norfolk, VA (United States); Klein, A. [Old Dominion University, Norfolk, VA (United States); Kossov, M.V. [Christopher Newport University, Newport News, VA (United States); Kuhn, S.E. [Old Dominion University, Norfolk, VA (United States); Magahiz, R. [Carnegie-Mellon Univ., Pittsburgh, PA (United States); Miskimen, R.A. [University of Massachussetts, Amherst, MA (United States); Murphy, L.Y. [CE Saclay, Gif sur Yvette (France); O`Meara, J.E. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Pyron, T.D. [Old Dominion University, Norfolk, VA (United States); Qin, L. [Old Dominion University, Norfolk, VA (United States); Raue, B.A. [Old Dominion University, Norfolk, VA (United States); Schumacher, R.A. [Carnegie-Mellon Univ., Pittsburgh, PA (United States); Tuzel, W. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Weinstein, L.B. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States); Yegneswaran, A. [Continuous Electron Beam Accelerator Facility, Newport News, VA (United States)

1995-12-11

We briefly describe the drift chamber system for the CLAS detector at CEBAF, concentrating on the method which will be used to calibrate the drift velocity function. We identify key features of the function which should apply to any small-cell drift chamber geometry in which the cathode and anode surfaces are wires. Using these ideas, we describe a simple method to compensate for variations in the drift velocity function due to environmental changes. (orig.).

Studies of electron drift velocity in nitrogen and isobutane

Energy Technology Data Exchange (ETDEWEB)

Goncalves, Josemary A.C.; Botelho, Suzana; Tobias, Carmen C.B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Pontificia Univ. Catolica de Sao Paulo (PUC/SP), SP (Brazil); Vivaldini, Tulio C.; Lima, Iara B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Ridenti, Marco A.; Pascholati, Paulo R. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Fisica. Lab. do Acelerador Linear; Fonte, Paulo; Mangiarotti, Alessio [Universidade de Coimbra (Portugal). Dept. de fisica. Lab. de Instrumentacao e Fisica Experimental de Particulas

2009-07-01

Full text: The electron drift velocity is one of the most important transport parameters used to describe the physical behaviour of gas discharges and the development of avalanches in gaseous detectors, mainly when temporal information is significant, as in drift chambers and in the recent Resistive Plate Chambers (RPCs). Although many filling gases, isobutane is frequently used in RPCs, due to its excellent timing properties, but at high electric fields conditions there are insufficient data available in literature. In the present work we report the preliminary results related to the dependence of the electron drift velocity for isobutane as function of the reduced electric field E/N, in the range of 100 Td up to 216 Td. There are different methods to determine electron drift velocity in a gas, and our measurements were based on the Pulsed Townsend technique, which consists of extracting electrons from a metallic cathode and accelerates them toward the anode by a uniform electric field. Once the drift distance and the transit time are known, the drift velocities can be determined. In our system, the incidence of a nitrogen laser beam (LTB MNL200-LD) liberates electron from the cathode made of aluminium (40mm diameter). By means of a high voltage supply (Bertan, 225-30), these electrons are accelerated toward the anode (made of a high resistivity glass - 2:10{sup 12}{omega} cm) and this movement produces a fast electric signal in the anode, which is digitalized in an oscilloscope (LeCroy WavePro 7000) with 1 GHz bandwidth and 10 GS/s. The values obtained were compared to that ones of a Bolsig+ simulation code. In order to validate the technique and to analyze non-uniformity effects, results for nitrogen are also presented. (author)

Studies of electron drift velocity in nitrogen and isobutane

International Nuclear Information System (INIS)

Goncalves, Josemary A.C.; Botelho, Suzana; Tobias, Carmen C.B.; Vivaldini, Tulio C.; Lima, Iara B.; Ridenti, Marco A.; Pascholati, Paulo R.; Fonte, Paulo; Mangiarotti, Alessio

2009-01-01

Full text: The electron drift velocity is one of the most important transport parameters used to describe the physical behaviour of gas discharges and the development of avalanches in gaseous detectors, mainly when temporal information is significant, as in drift chambers and in the recent Resistive Plate Chambers (RPCs). Although many filling gases, isobutane is frequently used in RPCs, due to its excellent timing properties, but at high electric fields conditions there are insufficient data available in literature. In the present work we report the preliminary results related to the dependence of the electron drift velocity for isobutane as function of the reduced electric field E/N, in the range of 100 Td up to 216 Td. There are different methods to determine electron drift velocity in a gas, and our measurements were based on the Pulsed Townsend technique, which consists of extracting electrons from a metallic cathode and accelerates them toward the anode by a uniform electric field. Once the drift distance and the transit time are known, the drift velocities can be determined. In our system, the incidence of a nitrogen laser beam (LTB MNL200-LD) liberates electron from the cathode made of aluminium (40mm diameter). By means of a high voltage supply (Bertan, 225-30), these electrons are accelerated toward the anode (made of a high resistivity glass - 2:10 12 Ω cm) and this movement produces a fast electric signal in the anode, which is digitalized in an oscilloscope (LeCroy WavePro 7000) with 1 GHz bandwidth and 10 GS/s. The values obtained were compared to that ones of a Bolsig+ simulation code. In order to validate the technique and to analyze non-uniformity effects, results for nitrogen are also presented. (author)

Breakdown assisted by a novel electron drift injection in the J-TEXT tokamak

International Nuclear Information System (INIS)

Wang, Nengchao; Jin, Hai; Zhuang, Ge; Ding, Yonghua; Pan, Yuan; Cen, Yishun; Chen, Zhipeng; Huang, Hai; Liu, Dequan; Rao, Bo; Zhang, Ming; Zou, Bichen

2014-01-01

A novel electron drift injection (EDI) system aiming to improve breakdown behavior has been designed and constructed on the Joint Texas EXperiment Tokamak Tokamak. Electrons emitted by the system undergo the E×B drift, ∇B drift and curvature drift in sequence in order to traverse the confining magnetic field. A local electrostatic well, generated by a concave-shaped plate biased more negative than the cathode, is introduced to interrupt the emitted electrons moving along the magnetic field line (in the parallel direction) in an attempt to bring an enhancement of the injection efficiency and depth. A series of experiments have demonstrated the feasibility of this method, and a penetration distance deeper than 9.5 cm is achieved. Notable breakdown improvements, including the reduction of breakdown delay and average loop voltage, are observed for discharges assisted by EDI. The lower limit of successfully ionized pressure is expanded

Cathodic voltage-controlled electrical stimulation of titanium for prevention of methicillin-resistant Staphylococcus aureus and Acinetobacter baumannii biofilm infections.

Science.gov (United States)

Canty, Mary; Luke-Marshall, Nicole; Campagnari, Anthony; Ehrensberger, Mark

2017-01-15

Antibiotic resistance of bacterial biofilms limits available treatment methods for implant-associated orthopaedic infections. This study evaluated the effects of applying cathodic voltage-controlled electrical stimulations (CVCES) of -1.5V and -1.8V (vs. Ag/AgCl) to coupons of commercially pure titanium (cpTi) incubated in cultures of methicillin-resistant Staphylococcus aureus (MRSA) and Acinetobacter baumannii (A. baumannii) as a method of preventing bacterial attachment. Stimulations were applied for 2, 4, and 8h and coupon-associated and planktonic colony-forming units (CFU) were enumerated following stimulation. Compared to open circuit potential (OCP) controls, CVCES for 4h at -1.8V significantly reduced coupon-associated MRSA CFU by 99.9% (1.30×10 4 vs. 4.45×10 7 , p=0.047) and A. baumannii coupon-associated CFU by 99.9% (1.64×10 4 vs. 5.93×10 7 , p=0.001) and reduced planktonic CFU below detectable levels for both strains. CVCES at -1.8V for 8h also reduced coupon-associated and planktonic CFU below detectable levels for each strain. CVCES at -1.5V for 4 and 8h, and -1.8V for 2h did not result in clinically relevant reductions. For 4 and 8h stimulations, the current density was significantly higher for -1.8V than -1.5V, an effect directly related to the rate of water and oxygen reduction on the cpTi surface. This significantly increased the pH, a suspected influence in decreased CFU viability. The voltage-dependent electrochemical properties of cpTi likely contribute to the observed antimicrobial effects of CVCES. This study revealed that CVCES of titanium could prevent coupon-associated and planktonic CFU of Gram-positive MRSA and Gram-negative A. baumannii from reaching detectable levels in a magnitude-dependent and time-dependent manner. Periprosthetic joint infection is a devastating outcome of total joint arthroplasty and has led to increased patient morbidity and rising healthcare costs. Current treatments are limited by the growing prevalence of

Characterising large area silicon drift detectors with MOS injectors

International Nuclear Information System (INIS)

Bonvicini, V.; Rashevsky, A.; Vacchi, A.

1999-01-01

In the framework of the INFN DSI project, the first prototypes of a large-area Silicon Drift Detector (SDD) have been designed and produced on 5'' diameter wafers of Neutron Transmutation Doped (NTD) silicon with a resistivity of 3000 Ω·cm. The detector is a 'butterfly' bi-directional structure with a drift length of 32 mm and the drifting charge is collected by two arrays of anodes having a pitch of 200 μm. The high-voltage divider is integrated on-board and is realised with p + implantations. For test and calibration purposes, the detector has a new type of MOS injector. The paper presents results obtained to injecting charge at the maximum drift distance (32mm) from the anodes by means of the MOS injecting structure, As front-end electronics, the authors have used a 32-channels low-noise bipolar VLSI circuit (OLA, Omni-purpose Low-noise Amplifer) specifically designed for silicon drift detectors. The uniformity of the drift time in different regions of the sensitive area and its dependence on the ambient temperature are studied

[4,4‧-bi(1,3,2-dioxathiolane)] 2,2‧-dioxide: A novel cathode additive for high-voltage performance in lithium ion batteries

Science.gov (United States)

Lee, Sang Hyun; Yoon, Sukeun; Hwang, Eui-Hyung; Kwon, Young-Gil; Lee, Young-Gi; Cho, Kuk Young

2018-02-01

High-voltage operation of lithium-ion batteries (LIBs) is a facile approach to obtaining high specific energy density, especially for LiNi0·5Mn0·3Co0·2O2 (NMC532) cathodes currently used in mid- and large-sized energy storage devices. However, high-voltage charging (>4.3 V) is accompanied by a rapid capacity fade over long cycles due to severe continuous electrolyte decomposition and instability at the cathode surface. In this study, the sulfite-based compound, [4,4‧-bi(1,3,2-dioxathiolane)] 2,2‧-dioxide (BDTD) is introduced as a novel electrolyte additive to enhance electrochemical performances of alumina-coated NMC532 cathodes cycled in the voltage range of 3.0-4.6 V. X-ray photoelectron spectroscopy (XPS) and AC impedance of cells reveal that BDTD preferentially oxidizes prior to the electrolyte solvents and forms stable film layers on to the cathode surface, preventing increased impedance caused by repeated electrolyte solvent decomposition in high-voltage operation. The cycling performance of the Li/NMC532 half-cell using an electrolyte of 1.0 M LiPF6 in ethylene carbonate/ethyl methyl carbonate (3/7, in volume) can be improved by adding a small amount of BDTD into the electrolyte. BDTD enables the usage of sulfite-type additives for cathodes in high-voltage operation.

Ion source with plasma cathode

International Nuclear Information System (INIS)

Yabe, E.

1987-01-01

A long lifetime ion source with plasma cathode has been developed for use in ion implantation. In this ion source, a plasma of a nonreactive working gas serves as a cathode in place of a thermionic tungsten filament used in the Freeman ion source. In an applied magnetic field, the plasma is convergent, i.e., filamentlike; in zero magnetic field, it turns divergent and spraylike. In the latter case, the plasma exhibits a remarkable ability when the working gas has an ionization potential larger than the feed gas. By any combination of a working gas of either argon or neon and a feed gas of AsF 5 or PF 5 , the lifetime of this ion source was found to be more than 90 h with an extraction voltage of 40 kV and the corresponding ion current density 20 mA/cm 2 . Mass spectrometry results show that this ion source has an ability of generating a considerable amount of As + and P + ions from AsF 5 and PF 5 , and hence will be useful for realizing a fully cryopumped ion implanter system. This ion source is also eminently suitable for use in oxygen ion production

Linear inductive voltage adders (IVA) for advanced hydrodynamic radiography

International Nuclear Information System (INIS)

Mazarakis, M.G.; Boyes, J.D.; Johnson, D.L.

1998-01-01

The electron beam which drifts through the multiple cavities of conventional induction linacs (LIA) is replaced in an IVA by a cylindrical metal conductor which extends along the entire length of the device and effectuates the addition of the accelerator cavity voltages. In the approach to radiography, the linear inductive voltage adder drives a magnetically immersed electron diode with a millimeter diameter cathode electrode and a planar anode/bremsstrahlung converter. Both anode and cathode electrodes are immersed in a strong (15--50 T) solenoidal magnetic field. The electron beam cross section is approximately of the same size as the cathode needle and generates a similar size, very intense x-ray beam when it strikes the anode converter. An IVA driven diode can produce electron beams of equal size and energy as a LIA but with much higher currents (40--50 kA versus 4--5 kA), simpler hardware and thus lower cost. The authors present here first experimental validations of the technology utilizing HERMES 3 and SABRE IVA accelerators. The electron beam voltage and current were respectively of the order of 10 MV and 40 kA. X-ray doses of up to 1 kR at sign 1 m and spot sizes as small as 1.7 mm (at 200 R doses) were measured

Cold cathode arc model in mercury discharges

International Nuclear Information System (INIS)

Li, Y.M.; Byszewski, W.W.; Budinger, A.B.

1990-01-01

Voltage/current characteristics measured during the starting of metal halide lamps indicate a low voltage discharge when condensates (mainly mercury) are localized on the electrodes. In this case, even with a cold cathode which does not emit electrons, the current is very high and voltage across the lamp drops to about 15 to 20 V. This type of discharge is similar to the cold cathode mercury vapor arc found in mercury pool rectifiers. The cathode sheath in the mercury vapor arc is characterized by very small cathode spot size, on the order of 10 -c cm 2 , very high current density of about 10 6 A/cm 2 and very low cathode fall of approximately 10 volts. The discharge is modified and generalized to describe the cathode phenomena in the cold cathode mercury vapor arc. The sensitivity of calculated discharge parameters with respect to such modifications were examined. Results show that the cathode fall voltage remains fairly constant (7-8 volts) with large fractional variations of metastable mercury atoms bombarding the cathode. This result compares very well with experimental waveforms when anode fall and plasma voltage approximations are incorporated

High-Current-Density Thermionic Cathodes and the Generation of High-Voltage Electron Beams

Science.gov (United States)

1989-04-30

Cathode Temperature =1700 OC Figure 37: Peak gun voltage = 90 kV -57- 60- 0 EGUN 327 ~40 0S 20’ Vacuum 5 .2 x 10 Tor 0 o 0 15202 30 Time (jis...by modeling the filament as a thin disk. The shape of the H - V -, 2 actual filament is sketched in Fig. 2. The EGUN code 1 131 is used to calculate

An Integrated Chip High-Voltage Power Receiver for Wireless Biomedical Implants

Directory of Open Access Journals (Sweden)

Vijith Vijayakumaran Nair

2015-06-01

Full Text Available In near-field wireless-powered biomedical implants, the receiver voltage largely overrides the compliance of low-voltage power receiver systems. To limit the induced voltage, generally, low-voltage topologies utilize limiter circuits, voltage clippers or shunt regulators, which are power-inefficient methods. In order to overcome the voltage limitation and improve power efficiency, we propose an integrated chip high-voltage power receiver based on the step down approach. The topology accommodates voltages as high as 30 V and comprises a high-voltage semi-active rectifier, a voltage reference generator and a series regulator. Further, a battery management circuit that enables safe and reliable implant battery charging based on analog control is proposed and realized. The power receiver is fabricated in 0.35-μm high-voltage Bipolar-CMOS-DMOStechnology based on the LOCOS0.35-μm CMOS process. Measurement results indicate 83.5% power conversion efficiency for a rectifier at 2.1 mA load current. The low drop-out regulator based on the current buffer compensation and buffer impedance attenuation scheme operates with low quiescent current, reduces the power consumption and provides good stability. The topology also provides good power supply rejection, which is adequate for the design application. Measurement results indicate regulator output of 4 ± 0.03 V for input from 5 to 30 V and 10 ± 0.05 V output for input from 11 to 30 V with load current 0.01–100 mA. The charger circuit manages the charging of the Li-ion battery through all if the typical stages of the Li-ion battery charging profile.

A new linear induction voltage adder approach to radiography

International Nuclear Information System (INIS)

Mazarakis, M.G.; Poukey, J.W.; Frost, C.A.; Johnson, D.L.; Shope, S.L.; Halbleib, J.A.; Prestwich, K.R.; Turman, B.N.; Smith, I.

1992-01-01

At present, two types of accelerators are being utilized for x-ray radiography: first a linear RF or induction accelerator with multiple accelerating gaps and beam vacuum magnetic transport systems; and second, single gap pulse-power devices with a high voltage Blumlein pulse forming line. The authors present a conceptual design of a new type of linear induction accelerator that can bridge the gap between the two devices. It can produce 30--50-kA electron currents small diameter (∼ 1 mm) and high energy (12--20-MV) beams. There is no beam drifting through the device. The voltage addition of the accelerating gaps occurs at the central self-magnetically insulated cathode electrode. The electron beam is created at the high voltage end in a single gap diode. A magnetically-immersed foilless diode can produce high quality 0.5 mm radius 30--50 kA beams. A short 100--200-kG small bore solenoidal coil is required to maintain the beam radius during transport from the cathode tips to the x-ray converter target, 50--70 cm downstream. The idea of very high impedance MITL voltage adder accelerators was first tested with RADLAC II/SMILE experiments where 12--14-MV, 50-kA 1 cm radius beams were produced with 2--3 mm annulus thickness. A 12.5 m eight-stage voltage adder was utilized, coupled to a 20 kG magnetically immersed foilless diode. In addition the magnetically-immersed foilless diodes with very thin (mm diameter) cathode tips were investigated in experiments with the IBEX accelerator. As an example of this new accelerator technology the authors present the following point design for a 16-MV, 50-kA accelerator producing 1-mm diameter electron beams. The design is based on a cavity fed MITL voltage adder which performs the series addition of the voltage pulses from 16 identical inductively-isolated cavity feed systems. Each cavity is a structure that is driven by one 14 ohm pulse-forming line, providing a 1 MV voltage pulse to the accelerating gap

2013 Estorm - Invited Paper - Cathode Materials Review

Energy Technology Data Exchange (ETDEWEB)

Daniel, Claus [ORNL; Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Wood III, David L [ORNL

2014-01-01

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403 431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783 789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

Synthesis of aluminum nitride films by plasma immersion ion implantation-deposition using hybrid gas-metal cathodic arc gun

International Nuclear Information System (INIS)

Shen Liru; Fu, Ricky K.Y.; Chu, Paul K.

2004-01-01

Aluminum nitride (AlN) is of interest in the industry because of its excellent electronic, optical, acoustic, thermal, and mechanical properties. In this work, aluminum nitride films are deposited on silicon wafers (100) by metal plasma immersion ion implantation and deposition (PIIID) using a modified hybrid gas-metal cathodic arc plasma source and with no intentional heating to the substrate. The mixed metal and gaseous plasma is generated by feeding the gas into the arc discharge region. The deposition rate is found to mainly depend on the Al ion flux from the cathodic arc source and is only slightly affected by the N 2 flow rate. The AlN films fabricated by this method exhibit a cubic crystalline microstructure with stable and low internal stress. The surface of the AlN films is quite smooth with the surface roughness on the order of 1/2 nm as determined by atomic force microscopy, homogeneous, and continuous, and the dense granular microstructures give rise to good adhesion with the substrate. The N to Al ratio increases with the bias voltage applied to the substrates. A fairly large amount of O originating from the residual vacuum is found in the samples with low N:Al ratios, but a high bias reduces the oxygen concentration. The compositions, microstructures and crystal states of the deposited films are quite stable and remain unchanged after annealing at 800 deg. C for 1 h. Our hybrid gas-metal source cathodic arc source delivers better AlN thin films than conventional PIIID employing dual plasmas

A wireless transmission system powered by an enzyme biofuel cell implanted in an orange.

Science.gov (United States)

MacVittie, Kevin; Conlon, Tyler; Katz, Evgeny

2015-12-01

A biofuel cell composed of catalytic electrodes made of "buckypaper" modified with PQQ-dependent glucose dehydrogenase and FAD-dependent fructose dehydrogenase on the anode and with laccase on the cathode was used to activate a wireless information transmission system. The cathode/anode pair was implanted in orange pulp extracting power from its content (glucose and fructose in the juice). The open circuit voltage, Voc, short circuit current density, jsc, and maximum power produced by the biofuel cell, Pmax, were found as ca. 0.6 V, ca. 0.33 mA·cm(-2) and 670 μW, respectively. The voltage produced by the biofuel cell was amplified with an energy harvesting circuit and applied to a wireless transmitter. The present study continues the research line where different implantable biofuel cells are used for the activation of electronic devices. The study emphasizes the biosensor and environmental monitoring applications of implantable biofuel cells harvesting power from natural sources, rather than their biomedical use. Copyright © 2014 Elsevier B.V. All rights reserved.

Negative hydrogen ion beam extraction from an AC heated cathode driven Bernas-type ion source

Energy Technology Data Exchange (ETDEWEB)

Okano, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

2015-04-08

A plasma grid structure was installed to a Bernas-type ion source used for ion implantation equipment. A negative hydrogen (H{sup −}) ion beam was extracted by an AC driven ion source by adjusting the bias to the plasma grid. The extracted electron current was reduced by positively biasing the plasma grid, while an optimum plasma grid bias voltage for negative ion beam extraction was found to be positive 3 V with respect to the arc chamber. Source operations with AC cathode heating show extraction characteristics almost identical to that with DC cathode heating, except a minute increase in H{sup −} current at higher frequency of cathode heating current.

Negligible degradation upon in situ voltage cycling of a PEMFC using an electrospun niobium-doped tin oxide supported Pt cathode.

Science.gov (United States)

Savych, Iuliia; Subianto, Surya; Nabil, Yannick; Cavaliere, Sara; Jones, Deborah; Rozière, Jacques

2015-07-14

Novel platinum-catalysed, corrosion-resistant, loose-tube-structured electrocatalysts for proton exchange membrane fuel cells have been obtained using single-needle electrospinning associated with a microwave-assisted polyol method. Monodisperse platinum particles supported on Nb-SnO2 demonstrated higher electrochemical stability than conventional Pt/C electrodes during ex situ potential cycling and comparable activity in the oxygen reduction reaction. In situ fuel cell operation under accelerated stress test conditions of a membrane electrode assembly elaborated using a Pt/C anode and Pt/Nb-SnO2 cathode confirmed that the voltage loss is significantly lower for the novel cathode than for an MEA prepared using conventional Pt/C supported electrocatalysts. Furthermore, the Nb-SnO2 stabilised the supported platinum nanoparticles against dissolution, migration and reprecipitation in the membrane. Pt/Nb-SnO2 loose-tubes constitute a mitigation strategy for two known degradation mechanisms in PEMFC: corrosion of the carbon support at the cathode, and dissolution of Pt at high cell voltages.

On stationary states of electron beams in drift space

International Nuclear Information System (INIS)

Kovalev, N.F.

2002-01-01

The article is devoted to studying the conditions of formation and existence of virtual cathodes. The problem on stationary states of the strongly magnetized electron beams in the homogeneous drift channels is discussed. The problem on the planar and coaxial moduli of the drift spaces is considered. The possibility of existing the virtual cathodes in the coaxial tubular beams by the injection currents, smaller than the threshold ones is highly proved. The inaccuracy of results of a number of works, studying the properties of the virtual cathodes in the strongly magnetized electron beams, is shown [ru

Lifetime control of the minority carrier in PiN diodes by He+ ion implantation

International Nuclear Information System (INIS)

Tanaka, Y.; Kojima, K.; Takao, K.; Okamoto, M.; Kawasaki, M.; Takatsuka, A.; Yatsuo, T.; Arai, K.

2005-01-01

This paper reports the first demonstration of the lifetime control of the minority carrier in 4H-SiC PiN diodes by He + ion implantation. In this work, we fabricated 4H-SiC PiN diodes with the epitaxial junction and the blocking voltage of 2.6 kV, precisely corresponding to the theoretical blocking voltage calculated from the doping concentration (4.0 x 10 15 /cm 2 ) and the thickness of the drift layer (16.5 μm). He + ion implantation was performed with the energy and the dose of 400 kV and 1.0 x 10 13 -2.0 x 10 14 /cm 2 , respectively. We observed no different characteristics in the blocking voltage (2.6kV) and leakage current ( + ion implantation. However, we confirmed the improvement of the current recovery characteristics in the diodes with He + ion implantation. (orig.)

Capacitance-voltage characteristics of GaAs ion-implanted structures

Directory of Open Access Journals (Sweden)

Privalov E. N.

2008-08-01

Full Text Available A noniterative numerical method is proposed to calculate the barrier capacitance of GaAs ion-implanted structures as a function of the Schottky barrier bias. The features of the low- and high-frequency capacitance-voltage characteristics of these structures which are due to the presence of deep traps are elucidated.

Enhanced high voltage cyclability of LiCoO{sub 2} cathode by adopting poly[bis-(ethoxyethoxyethoxy)phosphazene] with flame-retardant property as an electrolyte additive for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Zhou, Mingjiong; Qin, Chenyang; Liu, Zhen; Feng, Li; Su, Xiaoru; Chen, Yifeng [School of Materials Science and Chemical Engineering, Ningbo University, Fenghua Road 818, Ningbo, 315211 (China); Xia, Lan, E-mail: Lan.Xia@nottingham.edu.cn [Department of Chemical and Environmental Engineering, Faculty of Science and Engineering, Centre for Sustainable Energy Technologies (CSET), University of Nottingham Ningbo China, Taikang East Road 199, Ningbo, 315100 (China); Ningbo Institute of Materials Technology & Engineering (NIMTE), Chinese Academy of Science (CAS), Zhongguan West Road 1219, Ningbo, 315201 (China); Xia, Yonggao, E-mail: xiayg@nimte.ac.cn [Ningbo Institute of Materials Technology & Engineering (NIMTE), Chinese Academy of Science (CAS), Zhongguan West Road 1219, Ningbo, 315201 (China); Liu, Zhaoping [Ningbo Institute of Materials Technology & Engineering (NIMTE), Chinese Academy of Science (CAS), Zhongguan West Road 1219, Ningbo, 315201 (China)

2017-05-01

Highlights: • EEEP with electro-oxidable of the P-O bond can serves as a high-voltage additive. • EEEP tend to be electro-oxidized on LiCoO{sub 2} cathode prior to the solvents. • The high-voltage cyclability of LiCoO{sub 2} cathode is obviously improved using EEEP. - Abstract: Poly[bis-(ethoxyethoxyethoxy)phosphazene] (EEEP) with electro-oxidable of the P-O bond is prepared by a facile method and utilized as an electrolyte additive to enhance the cycling performance of LiCoO{sub 2} cathodes under high-voltage operations. We found that 5 wt.% EEEP made the blank electrolyte obviously reduce the flammability, as well as the capacity retention of Li/LiCoO{sub 2} half-cell assembling with the EEEP-containing electrolyte is elevated to 89.9% from 51.2% after 100 cycles at a high cutoff voltage of 4.4 V. The enhanced cycling performance of LiCoO{sub 2} cathode in the EEEP-containing electrolyte at a high potential should be ascribed to the formation of stable film on the cathode surface, resulting in suppression of the subsequent decomposition of electrolyte under high voltage working. The characterization from scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) indicates that EEEP can be electrochemically oxidized to form a robust and protective film on LiCoO{sub 2}, and improve the interfacial stability of LiCoO{sub 2} cathode/electrolyte at high potentials.

Improving breakdown voltage performance of SOI power device with folded drift region

Science.gov (United States)

Qi, Li; Hai-Ou, Li; Ping-Jiang, Huang; Gong-Li, Xiao; Nian-Jiong, Yang

2016-07-01

A novel silicon-on-insulator (SOI) high breakdown voltage (BV) power device with interlaced dielectric trenches (IDT) and N/P pillars is proposed. In the studied structure, the drift region is folded by IDT embedded in the active layer, which results in an increase of length of ionization integral remarkably. The crowding phenomenon of electric field in the corner of IDT is relieved by the N/P pillars. Both traits improve two key factors of BV, the ionization integral length and electric field magnitude, and thus BV is significantly enhanced. The electric field in the dielectric layer is enhanced and a major portion of bias is borne by the oxide layer due to the accumulation of inverse charges (holes) at the corner of IDT. The average value of the lateral electric field of the proposed device reaches 60 V/μm with a 10 μm drift length, which increases by 200% in comparison to the conventional SOI LDMOS, resulting in a breakdown voltage of 607 V. Project supported by the Guangxi Natural Science Foundation of China (Grant Nos. 2013GXNSFAA019335 and 2015GXNSFAA139300), Guangxi Experiment Center of Information Science of China (Grant No. YB1406), Guangxi Key Laboratory of Wireless Wideband Communication and Signal Processing of China, Key Laboratory of Cognitive Radio and Information Processing (Grant No. GXKL061505), Guangxi Key Laboratory of Automobile Components and Vehicle Technology of China (Grant No. 2014KFMS04), and the National Natural Science Foundation of China (Grant Nos. 61361011, 61274077, and 61464003).

Contribution to mechanical and crystallographic analysis of molyledenum layers prepared by magnetron cathode sputtering

International Nuclear Information System (INIS)

Bosland, P.

1988-01-01

Molybdenum coatings presenting different compression stresses are elaborated by magnetron cathode sputtering by varying the negative voltage of the substrate during deposition. Stress evolution is accompanied by crystal texture evolution and argon content incorporated in the layers. Crystallite orientation is explained by a phenomenon similar to canalisation observed in ion implantation. In a same deposit each component presents its own deformations different from neighbouring components [fr

Development of long lifetime-high current plasma cathode ion source

International Nuclear Information System (INIS)

Yabe, Eiji; Takayama, Kazuo; Fukui, Ryota.

1987-01-01

A long lifetime ion source with plasma cathode has been developed for use in ion implantation. In this ion source, a plasma of a nonreactive working gas serves as a cathode in place of a thermionic tungsten filament used in the Freeman ion source. In an applied magnetic field, the plasma cathode is convergent, i.e. filament-like; in zero magnetic field, it turns divergent and spray-like. In the latter case, the plasma exhibits a remarkable ability when the working gas has an ionization potential larger than the feed gas. By any combination of a working gas of either argon or neon and a feed gas of AsF 5 or PF 5 , the lifetime of this ion source was found to be more than 90 hours with an extraction voltage of 40 kV and the corresponding ion current density 20 mA/cm 2 . Mass spectrometry results show that this ion source has an ability of generating a considerable amount of As + and P + ions from AsF 5 and PF 5 , and hence will be useful for realizing a fully cryopumped ion implanter system. This ion source is eminently suitable for use in oxygen ion production. (author)

The Effects of Voltage and Concentration of Sodium Bicarbonate on Electrochemical Synthesis of Ethanol from Carbon Dioxide Using Brass as Cathode

Science.gov (United States)

Ramadan, Septian; Fariduddin, Sholah; Rizki Aminudin, Afianti; Kurnia Hayatri, Antisa; Riyanto

2017-11-01

The effects of voltage and concentration of sodium bicarbonate were investigated to determine the optimum conditions of the electrochemical synthesis process to convert carbon dioxide into ethanol. The conversion process is carried out using a sodium bicarbonate electrolyte solution in an electrochemical synthesis reactor equipped with a cathode and anode. As the cathode was used brass, while as the anode carbon was utilized. Sample of the electrochemical synthesis process was analyzed by gas chromatography to determine the content of the compounds produced. The optimum electrochemical synthesis conditions to convert carbon dioxide into ethanol are voltage and concentration of sodium bicarbonate are 3 volts and 0.4 M with ethanol concentration of 1.33%.

Arc cathode spots

International Nuclear Information System (INIS)

Schrade, H.O.

1989-01-01

Arc spots are usually highly unstable and jump statistically over the cathode surface. In a magnetic field parallel to the surface, preferably they move in the retrograde direction; i.e., opposite to the Lorentzian rule. If the field is inclined with respect to the surface, the spots drift away at a certain angle with respect to the proper retrograde direction (Robson drift motion). These well-known phenomena are explained by one stability theory

Controlled phase stability of highly Na-active triclinic structure in nanoscale high-voltage Na2-2xCo1+xP2O7 cathode for Na-ion batteries

Science.gov (United States)

Song, Hee Jo; Kim, Jae-Chan; Dar, Mushtaq Ahmad; Kim, Dong-Wan

2018-02-01

With the increasing demand for high energy density in energy-storage systems, a high-voltage cathode is essential in rechargeable Li-ion and Na-ion batteries. The operating voltage of a triclinic-polymorph Na2CoP2O7, also known as the rose form, is above 4.0 V (vs. Na/Na+), which is relatively high compared to that of other cathode materials. Thus, it can be employed as a potential high-voltage cathode material in Na-ion batteries. However, it is difficult to synthesize a pure rose phase because of its low phase stability, thus limiting its use in high-voltage applications. Herein, compositional-engineered, rose-phase Na2-2xCo1+xP2O7/C (x = 0, 0.1 and 0.2) nanopowder are prepared using a wet-chemical method. The Na2-2xCo1+xP2O7/C cathode shows high electrochemical reactivity with Na ions at 4.0 V, delivering high capacity and high energy density.

Suppressed oxygen extraction and degradation of LiNixMnyCozO2 cathodes at high charge cut-off voltages

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jianming; Yan, Pengfei; Zhang, Jiandong; Engelhard, Mark H.; Zhu, Zihua; Polzin, Bryant J.; Trask, Steve; Xiao, Jie; Wang, Chongmin; Zhang, Jiguang

2017-09-01

The capacity degradation mechanism in lithium nickel-manganese-cobalt oxide (NMC) cathodes (LiNi1/3Mn1/3Co1/3O2 (NMC333) and LiNi0.4Mn0.4Co0.2O2 (NMC442)) during high-voltage (cut-off of 4.8 V) operation has been investigated. In contrast to NMC442, NMC333 exhibits rapid structural changes including severe micro-crack formation and phase transformation from a layered to a disordered rock-salt structure, as well as interfacial degradation during high-voltage cycling, leading to a rapid increase of the electrode resistance and fast capacity decline. The fundamental reason behind the poor structural and interfacial stability of NMC333 was found to be correlated to its high Co content and the significant overlap between the Co3+/4+ t(2g) and O2- 2p bands, resulting in oxygen removal and consequent structural changes at high voltages. In addition, oxidation of the electrolyte solvents by the extracted oxygen species generates acidic species, which then attack the electrode surface and form highly resistive LiF. These findings highlight that both the structural and interfacial stability should be taken into account when tailoring cathode materials for high voltage battery systems

Fluctuation-Coupling of Cathode Cavity Pressure and Arc Voltage in a dc Plasma Torch with a Long Inter-Electrode Channel at Reduced Pressure

International Nuclear Information System (INIS)

Cao Jin-Wen; Huang He-Ji; Pan Wen-Xia

2014-01-01

Fluctuations of cathode cavity pressure and arc voltage are observed experimentally in a dc plasma torch with a long inter-electrode channel. The results show that they have the same frequency of around 4 kHz under typical experimental conditions. The observed phase difference between the pressure and the voltage, which is influenced by the path length between the pressure sensor and the cathode cavity, varies with different input powers. Combined with numerical simulation, the position of the pressure perturbation origin is estimated, and the results show that it is located at 0.01–0.05 m upstream of the inter-electrode channel outlet

Semi-empirical model for the threshold voltage of a double implanted MOSFET and its temperature dependence

Energy Technology Data Exchange (ETDEWEB)

Arora, N D

1987-05-01

A simple and accurate semi-empirical model for the threshold voltage of a small geometry double implanted enhancement type MOSFET, especially useful in a circuit simulation program like SPICE, has been developed. The effect of short channel length and narrow width on the threshold voltage has been taken into account through a geometrical approximation, which involves parameters whose values can be determined from the curve fitting experimental data. A model for the temperature dependence of the threshold voltage for the implanted devices has also been presented. The temperature coefficient of the threshold voltage was found to change with decreasing channel length and width. Experimental results from various device sizes, both short and narrow, show very good agreement with the model. The model has been implemented in SPICE as part of the complete dc model.

Superposed Redox Chemistry of Fused Carbon Rings in Cyclooctatetraene-Based Organic Molecules for High-Voltage and High-Capacity Cathodes.

Science.gov (United States)

Zhao, Xiaolin; Qiu, Wujie; Ma, Chao; Zhao, Yingqin; Wang, Kaixue; Zhang, Wenqing; Kang, Litao; Liu, Jianjun

2018-01-24

Even though many organic cathodes have been developed and have made a significant improvement in energy density and reversibility, some organic materials always generate relatively low voltage and limited discharge capacity because their energy storage mechanism is solely based on redox reactions of limited functional groups [N-O, C═X (X = O, N, S)] linking to aromatic rings. Here, a series of cyclooctatetraene-based (C 8 H 8 ) organic molecules were demonstrated to have electrochemical activity of high-capacity and high-voltage from carbon rings by means of first-principles calculations and electronic structure analysis. Fused molecules of C 8 -C 4 -C 8 (C 16 H 12 ) and C 8 -C 4 -C 8 -C 4 -C 8 (C 24 H 16 ) contain, respectively, four and eight electron-deficient carbons, generating high-capacity by their multiple redox reactions. Our sodiation calculations predict that C 16 H 12 and C 24 H 16 exhibit discharge capacities of 525.3 and 357.2 mA h g -1 at the voltage change from 3.5 to 1.0 V and 3.7 to 1.3 V versus Na + /Na, respectively. Electronic structure analysis reveals that the high voltages are attributed to superposed electron stabilization mechanisms, including double-bond reformation and aromatization from carbon rings. High thermodynamic stability of these C 24 H 16 -based systems strongly suggests feasibility of experimental realization. The present work provides evidence that cyclooctatetraene-based organic molecules fused with the C 4 ring are promising in designing high-capacity and high-voltage organic rechargeable cathodes.

Influence of bias voltage on properties of AlCrN coatings prepared by cathodic arc deposition

International Nuclear Information System (INIS)

Lomello, F.; Sanchette, F.; Schuster, F.; Tabarant, M.; Billard, A.

2013-01-01

AlCrN coatings were prepared by vacuum cathodic arc deposition. This low-temperature technique has been chosen due to its versatility, allowing the industrial up-scaling. In this study, the attention was focused on the correlation of the bias voltage with the resulting mechanical-tribological properties. For this purpose, the bias voltage was varied from 0 to -150 V. Indeed, the variation of grain sizes from 24 to 16 nm as well as the residual stresses from -0.68 to -8.94 GPa lead to obtain different mechanical-tribological properties. In this context, the sample deposited at -100 V exhibited an enhanced hardness (50 ± 2 GPa) and an acceptable wear resistance. (authors)

Procedure for the ion implantation of MOS elements

International Nuclear Information System (INIS)

Gessner, T.; Vetter, E.; Tolonics, J.

1986-01-01

The ion implantation procedure is applied to the doping of MOS elements. The invention guarantees a homogeneous doping in the dose range from 10 10 to 10 12 ions/cm 2 without additional installations of mechanical orifices in high-current implantation devices. The ion source parameters like cathode heating current, pressure at the ion source, extraction and acceleration voltages correspond to the dose range (10 10 to 10 12 ions/cm 2 ) for single charged ions of the doping agent. Double or triple charged ions generated at the ion source have been separated mass-analytically, accelerated and scanned. Ion densities below 100 nA/cm 2 have been obtained

The third generation multi-purpose plasma immersion ion implanter for surface modification of materials

CERN Document Server

Tang Bao Yin; Wang Xiao Feng; Gan Kong Yin; Wang Song Yan; Chu, P K; Huang Nian Ning; Sun Hong

2002-01-01

The third generation multi-purpose plasma immersion ion implantation (PIII) equipment has been successfully used for research and development of surface modification of biomedical materials, metals and their alloys in the Southwest Jiaotong University. The implanter equipped with intense current, pulsed cathodic arc metal plasma sources which have both strong coating function and gas and metal ion implantation function. Its pulse high voltage power supply can provide big output current. It can acquire very good implantation dose uniformity. The equipment can both perform ion implantation and combine ion implantation with sputtering deposition and coating to form many kinds of synthetic surface modification techniques. The main design principles, features of important components and achievement of research works in recent time have been described

Facilely solving cathode/electrolyte interfacial issue for high-voltage lithium ion batteries by constructing an effective solid electrolyte interface film

International Nuclear Information System (INIS)

Xu, Jingjing; Xia, Qingbo; Chen, Fangyuan; Liu, Tao; Li, Li; Cheng, Xueyuan; Lu, Wei; Wu, Xiaodong

2016-01-01

The cathode/electrolyte interface stability is the key factor for the cyclic performance and the safety performance of lithium ion batteries. Suppression of consuming key elements in the electrode materials is essential in this concern. In this purpose, we investigate a facile strategy to solve interfacial issue for high-voltage lithium ion batteries by adding an oxidable fluorinated phosphate, Bis(2,2,2-trifluoroethyl) Phosphite (BTFEP), as a sacrificial additive in electrolyte. We demonstrate that BTFEP additive could be oxidized at slightly above 4.28 V which is a relatively lower voltage than that of solvents, and the oxidative products facilitate in-situ forming a stable solid electrolyte interphase (SEI) film on the cathode surface. The results manifest the SEI film validly restrains the generation of HF and the interfacial side reaction between high-voltage charged LiNi 0.5 Mn 1.5 O 4 (LNMO) and electrolyte, hence, the dissolution of Mn and Ni is effectively suppressed. Finally, the cyclic performance of LNMO after 200 cycles was remarkably improved from 68.4% in blank electrolyte to 95% in 1 wt% BTFEP-adding electrolyte.

Co-intercalation of Mg(2+) and Na(+) in Na(0.69)Fe2(CN)6 as a High-Voltage Cathode for Magnesium Batteries.

Science.gov (United States)

Kim, Dong-Min; Kim, Youngjin; Arumugam, Durairaj; Woo, Sang Won; Jo, Yong Nam; Park, Min-Sik; Kim, Young-Jun; Choi, Nam-Soon; Lee, Kyu Tae

2016-04-06

Thanks to the advantages of low cost and good safety, magnesium metal batteries get the limelight as substituent for lithium ion batteries. However, the energy density of state-of-the-art magnesium batteries is not high enough because of their low operating potential; thus, it is necessary to improve the energy density by developing new high-voltage cathode materials. In this study, nanosized Berlin green Fe2(CN)6 and Prussian blue Na(0.69)Fe2(CN)6 are compared as high-voltage cathode materials for magnesium batteries. Interestingly, while Mg(2+) ions cannot be intercalated in Fe2(CN)6, Na(0.69)Fe2(CN)6 shows reversible intercalation and deintercalation of Mg(2+) ions, although they have the same crystal structure except for the presence of Na(+) ions. This phenomenon is attributed to the fact that Mg(2+) ions are more stable in Na(+)-containing Na(0.69)Fe2(CN)6 than in Na(+)-free Fe2(CN)6, indicating Na(+) ions in Na(0.69)Fe2(CN)6 plays a crucial role in stabilizing Mg(2+) ions. Na(0.69)Fe2(CN)6 delivers reversible capacity of approximately 70 mA h g(-1) at 3.0 V vs Mg/Mg(2+) and shows stable cycle performance over 35 cycles. Therefore, Prussian blue analogues are promising structures for high-voltage cathode materials in Mg batteries. Furthermore, this co-intercalation effect suggests new avenues for the development of cathode materials in hybrid magnesium batteries that use both Mg(2+) and Na(+) ions as charge carriers.

An implantable neurostimulator with an integrated high-voltage inductive power-recovery frontend

International Nuclear Information System (INIS)

Wang Yuan; Zhang Xu; Liu Ming; Li Peng; Chen Hongda

2014-01-01

This paper present a highly-integrated neurostimulator with an on-chip inductive power-recovery frontend and high-voltage stimulus generator. In particular, the power-recovery frontend includes a high-voltage full-wave rectifier (up to 100 V AC input), high-voltage series regulators (24/5 V outputs) and a linear regulator (1.8/3.3 V output) with bandgap voltage reference. With the high voltage output of the series regulator, the proposed neurostimulator could deliver a considerably large current in high electrode-tissue contact impedance. This neurostimulator has been fabricated in a CSMC 1 μm 5/40/700 V BCD process and the total silicon area including pads is 5.8 mm 2 . Preliminary tests are successful as the neurostimulator shows good stability under a 13.56 MHz AC supply. Compared to previously reported works, our design has advantages of a wide induced voltage range (26–100 V), high output voltage (up to 24 V) and high-level integration, which are suitable for implantable neurostimulators. (semiconductor integrated circuits)

Ion Back-Bombardment of GaAs Photocathodes Inside DC High Voltage Electron Guns

CERN Document Server

Grames, Joseph M; Brittian, Joshua; Charles, Daniel; Clark, Jim; Hansknecht, John; Lynn Stutzman, Marcy; Poelker, Matthew; Surles-Law, Kenneth E

2005-01-01

The primary limitation for sustained high quantum efficiency operation of GaAs photocathodes inside DC high voltage electron guns is ion back-bombardment of the photocathode. This process results from ionization of residual gas within the cathode/anode gap by the extracted electron beam, which is subsequently accelerated backwards to the photocathode. The damage mechanism is believed to be either destruction of the negative electron affinity condition at the surface of the photocathode or damage to the crystal structure by implantation of the bombarding ions. This work characterizes ion formation within the anode/cathode gap for gas species typical of UHV vacuum chambers (i.e., hydrogen, carbon monoxide and methane). Calculations and simulations are performed to determine the ion trajectories and stopping distance within the photocathode material. The results of the simulations are compared with test results obtained using a 100 keV DC high voltage GaAs photoemission gun and beamline at currents up to 10 mA D...

Compatibility of a Conventional Non-aqueous Magnesium Electrolyte with a High Voltage V₂O₅ Cathode and Mg Anode

Energy Technology Data Exchange (ETDEWEB)

Sa, Niya [Argonne National Lab. (ANL), Argonne, IL (United States); Proffit, Danielle L. [Argonne National Lab. (ANL), Argonne, IL (United States); Lipson, Albert L. [Argonne National Lab. (ANL), Argonne, IL (United States); Liu, Miao [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Gautam, Gopalakrishnan Sai [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Hahn, Nathan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Feng, Zhenxing [Argonne National Lab. (ANL), Argonne, IL (United States); Fister, Timothy T. [Argonne National Lab. (ANL), Argonne, IL (United States); Ren, Yang [Argonne National Lab. (ANL), Argonne, IL (United States); Sun, Cheng-Jun [Argonne National Lab. (ANL), Argonne, IL (United States); Vaughey, John T. [Argonne National Lab. (ANL), Argonne, IL (United States); Liao, Chen [Argonne National Lab. (ANL), Argonne, IL (United States); Fenter, Paul A. [Argonne National Lab. (ANL), Argonne, IL (United States); Ceder, Gerbrand [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Zavadil, Kevin R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Burrell, Anthony K. [Argonne National Lab. (ANL), Argonne, IL (United States)

2015-08-01

A major roadblock for magnesium ion battery development is the availability of an electrolyte that can deposit Mg reversibly and at the same time is compatible with a high voltage cathode. We report a prospective full magnesium cell utilizing a simple, non-aqueous electrolyte composed of high concentration magnesium bis(trifluoromethane sulfonyl)imide in diglyme, which is compatible with a high voltage vanadium pentoxide (V₂O₅) cathode and a Mg metal anode. For this system, plating and stripping of Mg metal can be achieved with magnesium bis(trifluoromethane sulfonyl)imide in diglyme electrolyte over a wide concentration range, however, reversible insertion of Mg into V₂O₅ cathode can only be attained at high electrolyte concentrations. Reversible intercalation of Mg into V₂O₅ is characterized and confirmed by X-ray diffraction, X-ray absorption near edge spectroscopy and energy dispersive spectroscopy.

Enhanced electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode at high cutoff voltage by modifying electrode/electrolyte interface with lithium metasilicate

International Nuclear Information System (INIS)

Fu, Jiale; Mu, Daobin; Wu, Borong; Bi, Jiaying; Liu, Xiaojiang; Peng, Yiyuan; Li, Yiqing; Wu, Feng

2017-01-01

Highlights: •The electrochemical properties of the LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode are investigated at high voltage of 4.6 V. •The Li 2 SiO 3 suppresses the decomposition of LiPF 6 and carbonate solvents. •Li 2 SiO 3 helpfully retards the transition metal dissolution by consuming HF. •The enhanced electrochemical properties of the LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode mixed with Li 2 SiO 3 . -- Abstract: Developing high-voltage Li ion batteries (LIBs) is an important trend to meet the requirement of high energy density battery. However, high voltage will cause a series of problems harming the cycle performance of LIBs at the same time. This work is to investigate the effect of inorganic substance Li 2 SiO 3 on the electrochemical performance of LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NCM622) cathode at high cutoff voltage of 4.6 V. XRD result shows that the structure of NCM622 cathode material is not affected by mixing Li 2 SiO 3 . However, XPS and EIS tests indicate that Li 2 SiO 3 has an evident influence on suppressing the decomposition of LiPF 6 and carbonate solvents at high voltage, reducing interfacial solid film impedance and modifying electrode/electrolyte interface. In addition, Li 2 SiO 3 retards the transition metal dissolution by consuming HF. Therefore, it enhances the electrochemical properties of the NCM622 cathode significantly. The highest discharge capacity increases to 191.7 mA h g -1 by mixing Li 2 SiO 3 , compared with the value of 180 mA h g -1 in the case of NCM622 cathode. The NCM622 electrode mixed with Li 2 SiO 3 also exhibits a better capacity retention of 73.4% after 200 cycles and a high rate capability at 20C with the value of 89 mA h g -1 , in contrast with 62.2% and 31 mA h g -1 attained in the NCM622 cathode.

Advanced plasma flow simulations of cathodic-arc and ferroelectric plasma sources for neutralized drift compression experiments

Directory of Open Access Journals (Sweden)

Adam B. Sefkow

2008-07-01

Full Text Available Large-space-scale and long-time-scale plasma flow simulations are executed in order to study the spatial and temporal evolution of plasma parameters for two types of plasma sources used in the neutralized drift compression experiment (NDCX. The results help assess the charge neutralization conditions for ion beam compression experiments and can be employed in more sophisticated simulations, which previously neglected the dynamical evolution of the plasma. Three-dimensional simulations of a filtered cathodic-arc plasma source show the coupling efficiency of the plasma flow from the source to the drift region depends on geometrical factors. The nonuniform magnetic topology complicates the well-known general analytical considerations for evaluating guiding-center drifts, and particle-in-cell simulations provide a self-consistent evaluation of the physics in an otherwise challenging scenario. Plasma flow profiles of a ferroelectric plasma source demonstrate that the densities required for longitudinal compression experiments involving ion beams are provided over the drift length, and are in good agreement with measurements. Simulations involving azimuthally asymmetric plasma creation conditions show that symmetric profiles are nevertheless achieved at the time of peak on-axis plasma density. Also, the ferroelectric plasma expands upstream on the thermal expansion time scale, and therefore avoids the possibility of penetration into the acceleration gap and transport sections, where partial neutralization would increase the beam emittance. Future experiments on NDCX will investigate the transverse focusing of an axially compressing intense charge bunch to a sub-mm spot size with coincident focal planes using a strong final-focus solenoid. In order to fill a multi-tesla solenoid with the necessary high-density plasma for beam charge neutralization, the simulations predict that supersonically injected plasma from the low-field region will penetrate and

Vacuum arc cathode spot motion in oblique magnetic fields: An interpretation of the Robson experiment

Energy Technology Data Exchange (ETDEWEB)

Beilis, I. I. [Electrical Discharge and Plasma Laboratory, School of Electrical Engineering, Fleischman Faculty of Engineering, Tel Aviv University, P.O.B. 39040, Tel Aviv 69978 (Israel)

2016-09-15

A model was developed of vacuum arc cathode spot motion in a magnetic field that obliquely intercepts the cathode surface. The model takes into account a force under an electric field caused by retrograde spot motion across the normal component of the magnetic field, producing a drift velocity component in the direction of the acute angle between the magnetic field and the cathode surface. The relationship between velocity of the retrograde direction and drift velocity of the cathode spot motion to the acute angle was developed. The dependencies of the drift angle θ on the acute angle φ, magnetic field strength B, and arc current I were calculated. It was found that the calculated θ increased with φ, B, and I in accordance with Robson's measurements.

Focused cathode design to reduce anode heating during vircator operation

Energy Technology Data Exchange (ETDEWEB)

Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A. [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)

2013-10-15

Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

Mitigating Voltage Decay of Li-Rich Cathode Material via Increasing Ni Content for Lithium-Ion Batteries.

Science.gov (United States)

Shi, Ji-Lei; Zhang, Jie-Nan; He, Min; Zhang, Xu-Dong; Yin, Ya-Xia; Li, Hong; Guo, Yu-Guo; Gu, Lin; Wan, Li-Jun

2016-08-10

Li-rich layered materials have been considered as the most promising cathode materials for future high-energy-density lithium-ion batteries. However, they suffer from severe voltage decay upon cycling, which hinders their further commercialization. Here, we report a Li-rich layered material 0.5Li2MnO3·0.5LiNi0.8Co0.1Mn0.1O2 with high nickel content, which exhibits much slower voltage decay during long-term cycling compared to conventional Li-rich materials. The voltage decay after 200 cycles is 201 mV. Combining in situ X-ray diffraction (XRD), ex situ XRD, ex situ X-ray photoelectron spectroscopy, and scanning transmission electron microscopy, we demonstrate that nickel ions act as stabilizing ions to inhibit the Jahn-Teller effect of active Mn(3+) ions, improving d-p hybridization and supporting the layered structure as a pillar. In addition, nickel ions can migrate between the transition-metal layer and the interlayer, thus avoiding the formation of spinel-like structures and consequently mitigating the voltage decay. Our results provide a simple and effective avenue for developing Li-rich layered materials with mitigated voltage decay and a long lifespan, thereby promoting their further application in lithium-ion batteries with high energy density.

Enhancement of breakdown voltage for fully-vertical GaN-on-Si p-n diode by using strained layer superlattice as drift layer

Science.gov (United States)

Mase, Suguru; Hamada, Takeaki; Freedsman, Joseph J.; Egawa, Takashi

2018-06-01

We have demonstrated a vertical GaN-on-Si p-n diode with breakdown voltage (BV) as high as 839 V by using a low Si-doped strained layer superlattice (SLS). The p-n vertical diode fabricated by using the n‑-SLS layer as a part of the drift layer showed a remarkable enhancement in BV, when compared with the conventional n‑-GaN drift layer of similar thickness. The vertical GaN-on-Si p-n diodes with 2.3 μm-thick n‑-GaN drift layer and 3.0 μm-thick n‑-SLS layer exhibited a differential on-resistance of 4.0 Ω · cm2 and a BV of 839 V.

About the Compatibility between High Voltage Spinel Cathode Materials and Solid Oxide Electrolytes as a Function of Temperature.

Science.gov (United States)

Miara, Lincoln; Windmüller, Anna; Tsai, Chih-Long; Richards, William D; Ma, Qianli; Uhlenbruck, Sven; Guillon, Olivier; Ceder, Gerbrand

2016-10-12

The reactivity of mixtures of high voltage spinel cathode materials Li 2 NiMn 3 O 8 , Li 2 FeMn 3 O 8 , and LiCoMnO 4 cosintered with Li 1.5 Al 0.5 Ti 1.5 (PO 4 ) 3 and Li 6.6 La 3 Zr 1.6 Ta 0.4 O 12 electrolytes is studied by thermal analysis using X-ray-diffraction and differential thermoanalysis and thermogravimetry coupled with mass spectrometry. The results are compared with predicted decomposition reactions from first-principles calculations. Decomposition of the mixtures begins at 600 °C, significantly lower than the decomposition temperature of any component, especially the electrolytes. For the cathode + Li 6.6 La 3 Zr 1.6 Ta 0.4 O 12 mixtures, lithium and oxygen from the electrolyte react with the cathodes to form highly stable Li 2 MnO 3 and then decompose to form stable and often insulating phases such as La 2 Zr 2 O 7 , La 2 O 3 , La 3 TaO 7 , TiO 2 , and LaMnO 3 which are likely to increase the interfacial impedance of a cathode composite. The decomposition reactions are identified with high fidelity by first-principles calculations. For the cathode + Li 1.5 Al 0.5 Ti 1.5 (PO 4 ) 3 mixtures, the Mn tends to oxidize to MnO 2 or Mn 2 O 3 , supplying lithium to the electrolyte for the formation of Li 3 PO 4 and metal phosphates such as AlPO 4 and LiMPO 4 (M = Mn, Ni). The results indicate that high temperature cosintering to form dense cathode composites between spinel cathodes and oxide electrolytes will produce high impedance interfacial products, complicating solid state battery manufacturing.

1020 steel coated with Ti/TiN by Cathodic Arc and Ion Implantation

International Nuclear Information System (INIS)

Bermeo, F; Quintana, J P; Kleiman, A; Márquez, A; Sequeda, F

2017-01-01

TiN coatings have been widely studied in order to improve mechanical properties of steels. In this work, thin Ti/TiN films were prepared by plasma based immersion ion implantation and deposition (PBII and D) with a cathodic arc on AISI 1020 steel substrates. Substrates were exposed to the discharge during 1 min in vacuum for the deposition of a Tiunderlayer with the aim of improving the adhesion to the substrate. Then, a TiN layer was deposited during 6 min in a nitrogen environment at a pressure of 3xl0 -4 mbar. Samples were obtained at room temperature and at 300 °C, and with or without ion implantation in order to analyze differences between the effects of each treatment on the tribological properties. The mechanical and tribological properties of the films were characterized. The coatings deposited by PBII and D at 300 °C presented the highest hardness and young modulus, the best wear resistance and corrosion performance. (paper)

Cathode characterization system: preliminary results with (Ba,Sr,Ca) O coated cathodes

International Nuclear Information System (INIS)

Nono, M.C.A.; Goncalves, J.A.N.; Barroso, J.J.; Dallaqua, R.S.; Spassovsky, I.

1993-01-01

The performance of a cathode characterization system for studying the emission parameters of thermal electron emitters is reported. The system consists of vacuum chamber, power supplies and equipment for measuring and control. Measurements have been taken of the emission current as function of cathode temperature and anode voltage. Several (Ba, Sr) O coated cathodes were tested and the results have shown good agreement with Child's and Richardson's laws. The experimental work function is between 1.0 and 2.0 e V. All emission parameters measured are consistent with international literature data. (author)

On the relation between the frequency of oscillation of a virtual cathode and injected current in one-dimensional grounded drift space

International Nuclear Information System (INIS)

Kumar, Raghwendra; Puri, R.R.; Biswas, D.

2004-01-01

The relationship between the injected current density j 0 and the dominant fundamental oscillation frequency f of a virtual cathode in a one-dimensional grounded infinite planar drift space of length L is determined numerically. If the electrons, each of mass m e and charge e, are injected with velocity v 0 , it is found that for vertical bar j 0 vertical bar >>m e v 0 3 /18π vertical bar e vertical bar L 2 , f∼√(vertical bar j 0 vertical bar) which is in contrast to the relation f∼vertical bar j 0 vertical bar reported by earlier workers

Li- and Mn-Rich Cathode Materials: Challenges to Commercialization

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jianming [Energy and Environmental Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA; Myeong, Seungjun [School of Energy and Chemical Engineering, Green Energy Materials Development Center, Ulsan National Institute of Science and Technology (UNIST), Korea 689-798; Cho, Woongrae [School of Energy and Chemical Engineering, Green Energy Materials Development Center, Ulsan National Institute of Science and Technology (UNIST), Korea 689-798; Yan, Pengfei [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA; Xiao, Jie [Energy and Environmental Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA; Wang, Chongmin [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA; Cho, Jaephil [School of Energy and Chemical Engineering, Green Energy Materials Development Center, Ulsan National Institute of Science and Technology (UNIST), Korea 689-798; Zhang, Ji-Guang [Energy and Environmental Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard Richland WA 99354 USA

2016-12-14

The lithium- and manganese-rich (LMR) layered structure cathode exhibit one of the highest specific energy (~900 Wh kg-1) among all the cathode materials. However, the practical applications of LMR cathodes are still hindered by several significant challenges including voltage fade, large initial capacity loss, poor rate capability and limited cycle life. Herein, we review the recent progresses and understandings on the application of LMR cathode materials from practical point of view. Several key parameters of LMR cathodes that affect the LMR/graphite full cell operation are systematically analysed. These factors include the first cycle capacity loss, voltage fade, powder tap density, electrode density of LMR based cathode etc. New approaches to minimize the detrimental effect of these factors are highlighted in this work. We also provided the perspectives for the future research on LMR cathode materials, focusing on addressing the fundamental problems of LMR cathodes while always keeping practical considerations in mind.

Explosive emission cathode on the base of carbon plastic fibre

International Nuclear Information System (INIS)

Korenev, S.A.; Baranov, A.M.; Kostyuchenko, S.V.; Chernenko, N.M.

1989-01-01

A fabrication process for explosive emission cathodes on the base of carbon plastic fibre of practically any geometrical shape and dimensions is developed. Experimental studies of electron beam current collection from cathodes, 2cm in diameter, at voltages across the diode of 10 and 150-250kV. It is shown that the ignition voltage for cathode plasma is ∼2kV at the interelectrode diode gap of 5mm and residual gas pressure of ∼5x10 -5 Torr. The carbon-fibre cathode, fabricated in this way, provides more stable current collection of an electron beam (without oscillations) than other cathodes

A high-efficiency low-voltage CMOS rectifier for harvesting energy in implantable devices.

Science.gov (United States)

Hashemi, S Saeid; Sawan, Mohamad; Savaria, Yvon

2012-08-01

We present, in this paper, a new full-wave CMOS rectifier dedicated for wirelessly-powered low-voltage biomedical implants. It uses bootstrapped capacitors to reduce the effective threshold voltage of selected MOS switches. It achieves a significant increase in its overall power efficiency and low voltage-drop. Therefore, the rectifier is good for applications with low-voltage power supplies and large load current. The rectifier topology does not require complex circuit design. The highest voltages available in the circuit are used to drive the gates of selected transistors in order to reduce leakage current and to lower their channel on-resistance, while having high transconductance. The proposed rectifier was fabricated using the standard TSMC 0.18 μm CMOS process. When connected to a sinusoidal source of 3.3 V peak amplitude, it allows improving the overall power efficiency by 11% compared to the best recently published results given by a gate cross-coupled-based structure.

Cathodic Polarization Coats Titanium Based Implant Materials with Enamel Matrix Derivate (EMD

Directory of Open Access Journals (Sweden)

Matthias J. Frank

2014-03-01

Full Text Available The idea of a bioactive surface coating that enhances bone healing and bone growth is a strong focus of on-going research for bone implant materials. Enamel matrix derivate (EMD is well documented to support bone regeneration and activates growth of mesenchymal tissues. Thus, it is a prime candidate for coating of existing implant surfaces. The aim of this study was to show that cathodic polarization can be used for coating commercially available implant surfaces with an immobilized but functional and bio-available surface layer of EMD. After coating, XPS revealed EMD-related bindings on the surface while SIMS showed incorporation of EMD into the surface. The hydride layer of the original surface could be activated for coating in an integrated one-step process that did not require any pre-treatment of the surface. SEM images showed nano-spheres and nano-rods on coated surfaces that were EMD-related. Moreover, the surface roughness remained unchanged after coating, as it was shown by optical profilometry. The mass peaks observed in the matrix-assisted laser desorption/ionization time-of-flight mass spectroscopy (MALDI-TOF MS analysis confirmed the integrity of EMD after coating. Assessment of the bioavailability suggested that the modified surfaces were active for osteoblast like MC3M3-E1 cells in showing enhanced Coll-1 gene expression and ALP activity.

Computer controlled drifting of Si(Li) detectors

International Nuclear Information System (INIS)

Landis, D.A.; Wong, Y.K.; Walton, J.T.; Goulding, F.S.

1989-01-01

A relatively inexpensive computer-controlled system for performing the drift process used in fabricating Si(Li) detectors is described. The system employs a small computer to monitor the leakage current, applied voltage and temperature on eight individual drift stations. The associated computer program initializes the drift process, monitors the drift progress and then terminates the drift when an operator set drift time has elapsed. The improved control of the drift with this system has been well demonstrated over the past three years in the fabrication of a variety of Si(Li) detectors. A few representative system responses to detector behavior during the drift process are described

Electron emission of cathode holder of vacuum diode of an intense electron-beam accelerator and its effect on the output voltage

OpenAIRE

Xin-Bing Cheng; Jin-Liang Liu; Hong-Bo Zhang; Zhi-Qiang Hong; Bao-Liang Qian

2011-01-01

The vacuum diode which is used to generate relativistic electron beams is one of the most important parts of a pulsed-power modulator. In this paper, the electron emission of cathode holder of a vacuum diode and its effect on the output voltage is investigated by experiments on an intense electron-beam accelerator with 180 ns full width at half maximum and 200–500 kV output voltage. First, the field emission is analyzed and the electric field of the vacuum chamber is calculated. Then, the fla...

The explosive cathode on the base of carbon-fibrous plastic material

International Nuclear Information System (INIS)

Korenev, S.A.; Baranov, A.M.; Kostyuchenko, S.V.; Chernenko, N.M.

1988-01-01

Production process of exploseve cathodes on the base of carbon-fibrous plastic material of any geometric form and size is discussed. Experimental study of current take-off from cathodes with diameter 2 cm of 10 kV and 150-250 kV voltage are given. It is shown that ignition voltage of cathode plasma is 2 kV with 5 mm gap electrode of diode and 5 ·10 -5 Tor pressure of residual gas. It is shown that carbon-fibrous cathode, made by this technology, provides more stable current take-off electron beam (withoud oscillations) in comparison with other cathodes

Design Of Photovoltaic Powered Cathodic Protection System

Directory of Open Access Journals (Sweden)

Golina Samir Adly

2017-07-01

Full Text Available The corrosion caused by chemical reaction between metallic structures and surrounding mediums such as soil or water .the CP cathodic protection system is used to protect metallic structure against corrosion. Cathodic protection CP used to minimize corrosion by utilizing an external source of electrical current which forces the entire structure to become a cathode. There are two Types of cathodic protection system Galvanic current Impressed current.the Galvanic current is called a sacrificial anode is connected to the protected structure cathode through a DC power supply. In Galvanic current system a current passes from the sacrificing anode to the protected structure .the sacrificial anode is corroded rather than causing the protected structure corrosion .protected structure requires a constant current to stop the corrosion which determined by area structure metal and the surrounding medium. The rains humidity are decrease soil resistivity and increase the DC current .The corrosion and over protection resulting from increase in the DC current is harmful for the metallic structure. This problem can be solved by conventional cathodic protection system by manual adjustment of DC voltage periodically to obtain a constant current .the manual adjustment of DC voltage depends on experience of the technician and using the accuracy of the measuring equipment. The errors of measuring current depend on error from the technician or error from the measuring equipment. the corrosion of structure may occur when the interval between two successive adjustment is long .An automatically regulated cathodic protection system is used to overcome problems from conventional cathodic protection system .the regulated cathodic protection system adjust the DC voltage of the system automatically when it senses the variations of surrounding medium resistivity so the DC current is constant at the required level.

Large area dispenser cathode applied to high current linac

International Nuclear Information System (INIS)

Yang Anmin; China Academy of Engineering Physics, Mianyang; Wu Dengxue; Liu Chenjun; Xia Liansheng; Wang Wendou; Zhang Kaizhi

2005-01-01

The paper introduced a dispenser cathode (411 M) which was 55 mm in diameter. A 200 kV long pulsed power generator with 2 μs flattop based on Marx-PEN and system with heat and voltage insulation were built. A 52 A space charge limited current was gained, when the temperature was 1165 degree C and the filament current was 18 A on the cathode and the voltage of the pulse was 75 kV at the cathode test stand. Experimental results show that the current values are consistent with the numerical simulation. The experiment reveals that the deflated gas will influence the cathode emission ability. (authors)

Magnetically insulated coaxial vacuum diode with partial space-charge-limited explosive emission from edge-type cathode

Energy Technology Data Exchange (ETDEWEB)

Belomyttsev, S. Ya.; Rostov, V. V.; Romanchenko, I. V. [Institute of High Current Electronics SB RAS, 2/3 Akademichesky Avenue, 634055 Tomsk (Russian Federation); Shunailov, S. A.; Sharypov, K. A.; Shpak, V. G.; Ulmaskulov, M. R. [Institute of Electrophysics UB RAS, 106 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Kolomiets, M. D. [Ural Federal University, 19 Mira Str., 620002 Ekaterinburg (Russian Federation); Mesyats, G. A. [P. N. Lebedev Physical Institute, RAS, 53 Lenin Avenue, 119991 Moscow (Russian Federation); Yalandin, M. I. [Institute of Electrophysics UB RAS, 106 Amundsen Str., 620016 Ekaterinburg (Russian Federation); P. N. Lebedev Physical Institute, RAS, 53 Lenin Avenue, 119991 Moscow (Russian Federation)

2016-01-14

The vacuum current associated with any type of electron emission for arbitrary configuration of the diode depends on the combination of the applied electric field and vacuum space charge (VSC) field created by the current. Such fundamental statement should give very close links between the diode current and the normalized cathode field θ which has been introduced by Forbes in 2008 for planar diodes as a reduction in the cathode surface field: θ = field-with/field-without VSC. This article reports the universal approximation of the type of cos(πθ/2) that is the ratio of the actual current and the fully space-charge-limited current. Also, the theoretical treatment and the experimental method of determination of the dynamic emissive characteristics of the macroscopic explosive emission from edge-type cathodes in the coaxial diode are developed. The experimental results obtained with a picosecond time reference between the cathode voltage and the onset of the high-current electron beam exhibit a good coincidence with the theoretical predictions. The presented methods enable the analysis of a real-time-resolved dynamics associated with the dense, magnetized electron beam formation, acceleration and drift motion, including kinematic effects and the phase-stable excitation of high-power microwave oscillators.

Mechanical structure of the TOPAZ barrel drift chamber

International Nuclear Information System (INIS)

Morimoto, T.; Maruyama, K.; Okuno, H.

1987-07-01

A Barrel Drift Chamber (BDC) is constructed for the TOPAZ experiment at TRISTAN, KEK. The BDC has a cylindrical shape with dimensions of 325.2 cm in inner diameter, 347.2 cm in outer diameter and 500 cm long. It consists of 1232 drift tubes made of conductive plastic cathodes, which are staggered in four layers. In this report, a design of the mechanical structure and construction procedures are described in detail. (author)

Auxiliary glow discharge in the trigger unit of a hollow-cathode thyratron

Energy Technology Data Exchange (ETDEWEB)

Korolev, Yu. D.; Landl, N. V., E-mail: landl@lnp.hcei.tsc.ru; Geyman, V. G.; Frants, O. B.; Shemyakin, I. A.; Nekhoroshev, V. O. [Russian Academy of Sciences, Institute of High-Current Electronics, Siberian Branch (Russian Federation)

2016-08-15

Results from studies of a low-current glow discharge with a hollow cathode are presented. A specific feature of the discharge conditions was that a highly emissive tablet containing cesium carbonate was placed in the cathode cavity. In the absence of a tablet, the discharge ignition voltage was typically ≥3.5 kV, while the burning voltage was in the range of 500–600 V. The use of the tablet made it possible to decrease the ignition voltage to 280 V and maintain the discharge burning voltage at a level of about 130 V. A model of the current sustainment in a hollow-cathode discharge is proposed. Instead of the conventional secondary emission yield, the model uses a generalized emission yield that takes into account not only ion bombardment of the cathode, but also the emission current from an external source. The model is used to interpret the observed current−voltage characteristics. The results of calculations agree well with the experimental data. It is shown that, in some discharge modes, the external emission current from the cathode can reach 25% of the total discharge current.

Wire- and cathode pulses in a counter of square cross section with a thin wire as central conductor operating in limited streamer mode

Science.gov (United States)

Carli, Ch.; Erd, Ch.; Leder, G.; Pernicka, M.; Regler, M.; Schnizer, B.

1989-11-01

Streamer tubes are becoming increasingly important in high-energy physics experiments. They are used as drift tubes for the localisation of charged-particle tracks, and also as sampling devices in sandwich calorimeters with cathode readout only. The streamer pulses carry charges which are several orders of magnitude larger than pulses from proportional chambers; this provides a good signal-to-noise ratio and makes them appropriate for a wide field of applications in highly compact detectors. The signals induced on the cathodes are also important for measuring — in addition to the anode wire - a second coordinate, and for resolving ambiguities in track recognition. When connecting the signals from two opposite cathodes to the two inputs of a differential amplifier, a left/right bit could be added after suitable buffering via the same signal line as used for time digitalisation. Another essential feature is the association of time information from the anode wire and the cathode. For the streamer tube used in this experiment the pulses induced on the cathode on either side of the particle, and on the anode, are measured by a fast analog-to-digital converter. A simple two-dimensional model ρ( r, θ) at t = 0, without any time-dependent effects other than a constant electron drift velocity of 50 μm/ns, is used to compare the charge distribution in a streamer with the measurements of the pulse lengths at the two opposite cathode strips. First the field generated by a static voltage is calculated. Then the effect of a "space charge" is evaluated. The Green's function of the square domain is a prerequisite for determining the field and the surface charge distribution on the electrodes. It is obtained from that of a concentric circular counter by a conformal mapping. Representations of Green's functions are calculated by series expansions.

Suppression of threshold voltage variability in MOSFETs by adjustment of ion implantation parameters

Science.gov (United States)

Park, Jae Hyun; Chang, Tae-sig; Kim, Minsuk; Woo, Sola; Kim, Sangsig

2018-01-01

In this study, we investigate threshold voltage (VTH) variability of metal-oxide-semiconductor field-effect transistors induced by random dopant fluctuation (RDF). Our simulation work demonstrates not only the influence of the implantation parameters such as its dose, tilt angle, energy, and rotation angle on the RDF-induced VTH variability, but also the solution to reduce the effect of this variability. By adjusting the ion implantation parameters, the 3σ (VTH) is reduced from 43.8 mV to 28.9 mV. This 34% reduction is significant, considering that our technique is very cost effective and facilitates easy fabrication, increasing availability.

Performance improvement of a PEMFC system controlling the cathode outlet air flow

Energy Technology Data Exchange (ETDEWEB)

Feroldi, Diego; Serra, Maria; Riera, Jordi [Institut de Robotica i Informatica Industrial, Universitat Politecnica de Catalunya-Consejo Superior de Investigaciones Cientificas, C. Llorens i Artigas 4, 08028 Barcelona (Spain)

2007-06-10

This paper presents a stationary and dynamic study of the advantages of using a regulating valve for the cathode outlet flow in combination with the compressor motor voltage as manipulated variables in a fuel cell system. At a given load current, the cathode input and output flow rate determine the cathode pressure and stoichiometry, and consequently determine the oxygen partial pressure, the generated voltage and the compressor power consumption. In order to maintain a high efficiency during operation, the cathode output regulating valve has to be adjusted to the operating conditions, specially marked by the current drawn from the stack. Besides, the appropriate valve manipulation produces an improvement in the transient response of the system. The influence of this input variable is exploited by implementing a predictive control strategy based on dynamic matrix control (DMC), using the compressor voltage and the cathode output regulating valve as manipulated variables. The objectives of this control strategy are to regulate both the fuel cell voltage and oxygen excess ratio in the cathode, and thus, to improve the system performance. All the simulation results have been obtained using the MATLAB-Simulink environment. (author)

Improved high-voltage performance of LiNi1/3Co1/3Mn1/3O2 cathode with Tris(2,2,2-trifluoroethyl) phosphite as electrolyte additive

International Nuclear Information System (INIS)

Wang, Long; Ma, Yulin; Li, Qin; Cui, Yingzhi; Wang, Panpan; Cheng, Xinqun; Zuo, Pengjian; Du, Chunyu; Gao, Yunzhi

2017-01-01

Tris(2,2,2-trifluoroethyl) phosphite (TTFEP) is investigated as an electrolyte additive to improve the electrochemical performance of LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathode at high operating voltage (4.6 V). Charge/discharge measurements demonstrate that TTFEP is effective to improve the cycling stability and rate capability of LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathode. The capacity retention of LiNi 1/3 Co 1/3 Mn 1/3 O 2 /Li cell with 1% TTFEP-containing electrolyte reaches up to 85.4% after 100 cycles at 0.5C (1C = 160 mA g −1 ), while that of the cell with the baseline electrolyte (1 M LiPF 6 in EC/DMC electrolyte) only remains 74.2%. Moreover, the discharge capacity of the cathode with 1% TTFEP-containing electrolyte could maintain around 112.0 mAh g −1 at 4C. Based on the characterization of electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), a protective interphase film formed on the cathode surface can be found due to the preferential oxidation of TTFEP, which inhibits the electrolyte decomposition and mitigates the cathode structural destruction, leading to the improved electrochemical performance of LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathode at high voltage.

Thermal drift reduction with multiple bias current for MOSFET dosimeters

Energy Technology Data Exchange (ETDEWEB)

Carvajal, M A; Martinez-Olmos, A; Morales, D P; Lopez-Villanueva, J A; Palma, A J [Departamento de Electronica y TecnologIa de Computadores, ETSIIT, Universidad de Granada, E-18071 Granada (Spain); Lallena, A M, E-mail: carvajal@ugr.es [Departamento de Fisica Atomica, Molecular y Nuclear, Universidad de Granada, E-18071 Granada (Spain)

2011-06-21

New thermal compensation methods suitable for p-channel MOSFET (pMOS) dosimeters with the usual dose readout procedure based on a constant drain current are presented. Measuring the source-drain voltage shifts for two or three different drain currents and knowing the value of the zero-temperature coefficient drain current, I{sub ZTC}, the thermal drift of source-drain or threshold voltages can be significantly reduced. Analytical expressions for the thermal compensation have been theoretically deduced on the basis of a linear dependence on temperature of the parameters involved. The proposed thermal modelling has been experimentally proven. These methods have been applied to a group of ten commercial pMOS transistors (3N163). The thermal coefficients of the source-drain voltage and the threshold voltage were reduced from -3.0 mV deg. C{sup -1}, in the worst case, down to -70 {mu}V deg. C{sup -1}. This means a thermal drift of -2.4 mGy deg. C{sup -1} for the dosimeter. When analysing the thermal drifts of all the studied transistors, in the temperature range from 19 to 36 deg. C, uncertainty was obtained in the threshold voltage due to a thermal drift of {+-}9mGy (2 SD), a commonly acceptable value in most radiotherapy treatments. The procedures described herein provide thermal drift reduction comparable to that of other technological or numerical strategies, but can be used in a very simple and low-cost dosimetry sensor.

Cathode fall measurement in a dielectric barrier discharge in helium

Energy Technology Data Exchange (ETDEWEB)

Hao, Yanpeng; Zheng, Bin; Liu, Yaoge [School of Electric Power, South China University of Technology, Guangzhou 510640 (China)

2013-11-15

A method based on the “zero-length voltage” extrapolation is proposed to measure cathode fall in a dielectric barrier discharge. Starting, stable, and discharge-maintaining voltages were measured to obtain the extrapolation zero-length voltage. Under our experimental conditions, the “zero-length voltage” gave a cathode fall of about 185 V. Based on the known thickness of the cathode fall region, the spatial distribution of the electric field strength in dielectric barrier discharge in atmospheric helium is determined. The strong cathode fall with a maximum field value of approximately 9.25 kV/cm was typical for the glow mode of the discharge.

Development of the ERC cold-cathode ion source for use on the PR-30 ion-implantation system

International Nuclear Information System (INIS)

Bird, H.M.B.; Flemming, J.P.

1978-01-01

The ERC cold-cathode ion source has been in routine production use on several PR-30 systems for the past three years. This source has been further developed to improve target current, lifetime, and stability. The ion-optical lens has been changed from circular to elliptical geometry in order to provide an asymmetric beam for entry into the PR-30 analyzing magnet. This measure, as well as the use of higher extraction voltages, provides higher beam currents on the PR-30 target wafers. Beam steering in the nondispersive direction has been provided to correct the effects of minor machine misalignments, further enhancing target current. The discharge chamber has been modified to increase source lifetime. A new gas-feed control system and a new method of oven temperature control have been devised to provide good source and ion beam stability. The source operates with only occasional attention by unskilled personnel, and has been used principally for boron and arsenic implants. Target currents of 1-mA boron and 4-mA arsenic can be obtained routinely. Lifetimes are of the order of 40--80 h, depending on ion species. The source has also been used to provide 5-mA phosphorus, 4-mA argon, 3-mA helium and neon, and 0.3-mA nickel and palladium ion beams

Trigger drift chamber for the upgraded mark II detector at PEP

Science.gov (United States)

Ford, W. T.; Smith, J. G.; Wagner, S. R.; Weber, P.; White, S. L.; Alvarez, M.; Calviño, F.; Fernandez, E.

1987-04-01

A small cylindrical track detector was built as an array of single-wire drift cells with aluminized mylar cathode tubes. Point measurement resolution of ˜ 90 μm was achieved with a drift gas of 50% argon-50% ethane at atmospheric pressure. The chamber construction, electronics, and calibration are discussed. Performance results from PEP colliding-beam data are presented.

Lipon coatings for high voltage and high temperature Li-ion battery cathodes

Energy Technology Data Exchange (ETDEWEB)

Dudney, Nancy J.; Liang, Chengdu; Nanda, Jagjit; Veith, Gabriel M.; Kim, Yoongu; Martha, Surendra Kumar

2017-12-05

A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.

Knife-edge thin film field emission cathodes

International Nuclear Information System (INIS)

Lee, B.; Demroff, H.P.; Drew, M.M.; Elliott, T.S.; Mazumdar, T.K.; McIntyre, P.M.; Pang, Y.; Smith, D.D.; Trost, H.J.

1993-01-01

Cathodes made of thin-film field emission arrays (FEA) have the advantages of high current density, pulsed emission, and low bias voltage operation. The authors have developed a technology to fabricate knife-edge field emission cathodes on (110) silicon wafers. The emitter geometry is optimized for efficient modulation at high frequency. Cathode fabrication progress and preliminary analysis of their applications in RF power sources are presented

Stability of high current diode under 100-nanosecond-pulse voltage

International Nuclear Information System (INIS)

Lai Dingguo; Qiu Aici; Zhang Yongmin; Huang Jianjun; Ren Shuqing; Yang Li

2012-01-01

Stability of high current diode under pulse voltage with 80 ns and 34 ns rise time was studied on the flash Ⅱ accelerator. Influence of rise time of diode voltage on startup time and cathode emission uniformity and repeatability of diode impedance was analyzed by comparing the experimental results with numerically simulated results, and the influence mechanism was discussed. The startup time of diode increases with the increasing of rise time of voltage, and the repeatability of diode impedance decreases. Discal plane cathode is prone to emit rays intensely in the center area, the time that plasma covers the surface of the cathode increases and the shielding effect has more impact on cathode emission according to the increase of rise time. Local intense emission on the cathode increases expansion speed of plasma and reduces the effective emission area. The stability of characteristic impedance of diode under a pulse voltage with slow rise time is decreased by the combined action of expansion speed of plasma and the effective emission area. (authors)

Characteristics of a cold cathode electron source combined with secondary electron emission in a FED

International Nuclear Information System (INIS)

Lei Wei; Zhang Xiaobing; Zhou Xuedong; Zhu Zuoya; Lou Chaogang; Zhao Hongping

2005-01-01

In electron beam devices, the voltage applied to the cathode (w.r.t. grid voltage) provides the initial energy for the electrons. Based on the type of electron emission, the electron sources are (mainly) classified into thermionic cathodes and cold cathodes. The power consumption of a cold cathode is smaller than that of a thermionic cathode. The delay time of the electron emission from a cold cathode following the voltage rise is also smaller. In cathode ray tubes, field emission display (=FED) panels and other devices, the electron current emitted from the cathode needs to be modulated. Since the strong electric field, which is required to extract electrons from the cold cathode, accelerates the electrons to a high velocity near the gate electrode, the required voltage swing for the current modulation is also high. The design of the driving circuit becomes quite difficult and expensive for a high driving voltage. In this paper, an insulator plate with holes is placed in front of a cold cathode. When the primary electrons hit the surface of the insulator tunnels, secondary electrons are generated. In this paper, the characteristics of the secondary electrons emitted from the gate structure are studied. Because the energies of the secondary electrons are smaller than that of the primary electron, the driving voltage for the current modulation is decreased by the introduction of the insulator tunnels, resulting in an improved energy uniformity of the electron beam. Triode structures with inclined insulator tunnels and with double insulator plates are also fabricated and lead to further improvements in the energy uniformity. The improved energy uniformity predicted by the simulation calculations is demonstrated by the improved brightness uniformity in the screen display images

Drift chamber tracking with neural networks

International Nuclear Information System (INIS)

Lindsey, C.S.; Denby, B.; Haggerty, H.

1992-10-01

We discuss drift chamber tracking with a commercial log VLSI neural network chip. Voltages proportional to the drift times in a 4-layer drift chamber were presented to the Intel ETANN chip. The network was trained to provide the intercept and slope of straight tracks traversing the chamber. The outputs were recorded and later compared off line to conventional track fits. Two types of network architectures were studied. Applications of neural network tracking to high energy physics detector triggers is discussed

Heating of refractory cathodes by high-pressure arc plasmas: II

International Nuclear Information System (INIS)

Benilov, M S; Cunha, M D

2003-01-01

Solitary spots on infinite planar cathodes and diffuse and axially symmetric spot modes on finite cathodes of high-pressure arc discharges are studied in a wide range of arc currents. General features are analysed and extensive numerical results on planar and cylindrical tungsten cathodes of atmospheric-pressure argon arcs are given for currents of up to 100 kA. It is shown, in particular, that the temperature of cathode surface inside a solitary spot varies relatively weakly and may be estimated, to the accuracy of about 200-300 K, without actually solving the thermal conduction equation in the cathode body. Asymptotic behaviour of solutions for finite cathodes in the limiting case of high currents is found and confirmed by numerical results. A general pattern of current-voltage characteristics of various modes on finite cathodes suggested previously on the basis of bifurcation analysis is confirmed. A transition from the spot modes on a finite cathode in the limit of large cathode dimensions to the solitary spot mode on an infinite planar cathode is studied. It is found that the solitary spot mode represents a limiting form of the high-voltage spot mode on a finite cathode. A question of distinguishing between diffuse and spot modes on finite cathodes is considered

Trigger drift chamber for the upgraded Mark II detector at PEP

International Nuclear Information System (INIS)

Ford, W.T.; Smith, J.G.; Wagner, S.R.; Weber, P.; White, S.L.; Alvarez, M.; Calvino, F.; Fernandez, E.; Universidad Autonoma de Barcelona

1987-01-01

A small cylindrical track detector was built as an array of single-wire drift cells with aluminized mylar cathode tubes. Point measurement resolution of ∝90 μm was achieved with a drift gas of 50% argon-50% ethane at atmospheric pressure. The chamber construction, electronics, and calibration are discussed. Performance results from PEP colliding-beam data are presented. (orig.)

Constant potential high-voltage generator

International Nuclear Information System (INIS)

Resnick, T.A.; Dupuis, W.A.; Palermo, T.

1980-01-01

An X-ray tube voltage generator with automatic stabilization circuitry is disclosed. The generator includes a source of pulsating direct current voltage such as from a rectified 3 phase transformer. This pulsating voltage is supplied to the cathode and anode of an X-ray tube and forms an accelerating potential for electrons within that tube. The accelerating potential is stabilized with a feedback signal which is provided by a feedback network. The network includes an error signal generator which compares an instantaneous accelerating potential with a preferred reference accelerating potential and generates an error function. This error function is transmitted to a control tube grid which in turn causes the voltage difference between X-ray tube cathode and anode to stabilize and thereby reduce the error function. In this way stabilized accelerating potentials are realized and uniform X-ray energy distributions produced. (Auth.)

Drift chambers on the basis of Mylar tube blocks

Science.gov (United States)

Budagov, Yu.; Chirikov-Zorin, I.; Golovanov, L.; Khazins, D.; Kuritsin, A.; Pukhov, O.; Zhukov, V.

1993-06-01

Prototypes of drift chambers constructed of Mylar tube blocks were tested. The purpose of developing tube blocks technology was to create long chambers (up to 3-4 m). Counting and drift characteristics of the chambers for different values of the gas pressure and different diameters of sense wires are presented. The lifetime of the chambers is determined. A photoeffect in the visible spectrum on the surface of the thin film aluminium cathode, which covers the Mylar tubes was observed.

Drift chambers on the basis of Mylar tube blocks

International Nuclear Information System (INIS)

Budagov, Yu.; Chirikov-Zorin, I.; Golovanov, L.; Khazins, D.; Kuritsin, A.; Pukhov, U.; Zhukov, V.

1993-01-01

Prototypes of drift chambers constructed of Mylar tube blocks were tested. The purpose of developing tube blocks technology was to create chambers (up to 3-4 m). Counting and drift chracteristics of the chambers for different values of the gas pressure and different diameters of sense wires are presented. The lifetime of the chambers is determined. A photoeffect in the visible spectrum on the surface of the thin film aluminium cathode, which covers the Mylar tubes was observed. (orig.)

The reduction of leading- and trailing-edge of high-voltage steep pulse in plasma immersion ion implantation

International Nuclear Information System (INIS)

Zhu Zongtao; Gui Gang; Wang Zhijian; Gong Chunzhi; Yang Shiqin; Tian Xiubo

2010-01-01

During plasma immersion ion implantation (PIII) processes, due to the capacitance effect of the coaxial cable and plasma load, the output voltage pulse of high-voltage modulator possesses a longer leading- and trailing-edge time. The leading- and trailing-edge of the high voltage (HV) pulse have a critical effect on the ion-energy uniformity, depth and dose distribution during PIII processes. In this work, a tetrode was used as a hard tube to switch the DC high voltage, and a HV pulse modulator with a maximum pulse voltage of 40 kV was built successfully. The effect of the trailing-edge time on the implantation uniformity was simulated by one-dimension PIC method. The potential on the control grids of the tetrode was optimized to obtain a HV pulse with a short rise time. In our system, 200 V potential on grid one is utilized and the leading-edge time of pulse can be as small as 1 μs. The IGBTs in series was utilized to release the remnant charges reserved in the equivalent capacitance of the plasma load and coaxial cable. Thus the trailing-edge time of the HV pulse could be reduced. The effect of the driver signals with different delay time and the absorption parameters of each IGBTs were simulated by PSPICE software to optimize the design the electric circuit. (authors)

A Transient Model for Fuel Cell Cathode-Water Propagation Behavior inside a Cathode after a Step Potential

Directory of Open Access Journals (Sweden)

Der-Sheng Chan

2010-04-01

Full Text Available Most of the voltage losses of proton exchange membrane fuel cells (PEMFC are due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen diffusion rate inside the flooded cathode. To simulate the transient flooding in the cathode of a PEMFC, a transient model was developed. This model includes the material conservation of oxygen, vapor, water inside the gas diffusion layer (GDL and micro-porous layer (MPL, and the electrode kinetics in the cathode catalyst layer (CL. The variation of hydrophobicity of each layer generated a wicking effect that moves water from one layer to the other. Since the GDL, MPL, and CL are made of composite materials with different hydrophilic and hydrophobic properties, a linear function of saturation was used to calculate the wetting contact angle of these composite materials. The balance among capillary force, gas/liquid pressure, and velocity of water in each layer was considered. Therefore, the dynamic behavior of PEMFC, with saturation transportation taken into account, was obtained in this study. A step change of the cell voltage was used to illustrate the transient phenomena of output current, water movement, and diffusion of oxygen and water vapor across the entire cathode.

Charged particle transport in gaseous nitrogen at intermediate E/N using the voltage transient method

International Nuclear Information System (INIS)

Purdie, P.H.; Fletcher, J.

1992-01-01

A pulsed swarm of charged particles crossing an inter-electrode gap under the influence of an applied electric field E will produce a pulsed current in the external circuit which, when integrated over time, will result in a transient voltage pulse, the shape and magnitude of which is characteristic of the number of type of charged particles. This voltage transient technique has been used to investigate a gas discharge in nitrogen gas at values of E/N (the ratio of applied electric field to gas number density), such that ionization is non-negligible. The voltage transients have been subjected to a theoretical analysis, which has previously been reported, which includes not only cathode and anode image terms but also both electron and ion diffusion terms. Electron transport parameters are reported for E/N ≤ 350 Td (1 Td = 10 -17 V cm 2 ). Data are also obtained for the drift velocities and diffusion coefficients of the ions operative within the nitrogen discharge. An estimate is obtained for the collisional decay rate of N 2 + . 21 refs., 7 figs

Probabilistic modelling of the high-pressure arc cathode spot displacement dynamic

International Nuclear Information System (INIS)

Coulombe, Sylvain

2003-01-01

A probabilistic modelling approach for the study of the cathode spot displacement dynamic in high-pressure arc systems is developed in an attempt to interpret the observed voltage fluctuations. The general framework of the model allows to define simple, probabilistic displacement rules, the so-called cathode spot dynamic rules, for various possible surface states (un-arced metal, arced, contaminated) and to study the resulting dynamic of the cathode spot displacements over one or several arc passages. The displacements of the type-A cathode spot (macro-spot) in a magnetically rotating arc using concentric electrodes made up of either clean or contaminated metal surfaces is considered. Experimental observations for this system revealed a 1/f -tilde1 signature in the frequency power spectrum (FPS) of the arc voltage for anchoring arc conditions on the cathode (e.g. clean metal surface), while it shows a 'white noise' signature for conditions favouring a smooth movement (e.g. oxide-contaminated cathode surface). Through an appropriate choice of the local probabilistic displacement rules, the model is able to correctly represent the dynamic behaviours of the type-A cathode spot, including the FPS for the arc elongation (i.e. voltage) and the arc erosion trace formation. The model illustrates that the cathode spot displacements between re-strikes can be seen as a diffusion process with a diffusion constant which depends on the surface structure. A physical interpretation for the jumping probability associated with the re-strike event is given in terms of the electron emission processes across dielectric contaminants present on the cathode surface

Cathode materials: A personal perspective

Energy Technology Data Exchange (ETDEWEB)

Goodenough, John B. [Texas Materials Institute, University of Texas at Austin, ETC 9.102, 1 University Station, Austin, TX 78712-1063 (United States)

2007-12-06

A thermodynamically stable rechargeable battery has a voltage limited by the window of the electrolyte. An aqueous electrolyte has a window of 1.2 eV, which prevents achieving the high energy density desired for many applications. A non-aqueous electrolyte with a window of 5 eV requires Li{sup +} rather than H{sup +} as the working ion. Early experiments with Li{sub x}TiS{sub 2} cathodes showed competitive capacity and rate capability, but problems with a lithium anode made the voltage of a safe cell based on a sulfide cathode too low to be competitive with a nickel/metal-hydride battery. Transition-metal oxides can give voltages of 4.5 V versus Li{sup +}/Li{sup 0}. However, the challenge with oxides has been to obtain a competitive capacity and rate capability while retaining a high voltage with low-cost, environmentally friendly cathode materials. Comparisons will be made between layered Li{sub 1-x}MO{sub 2}, spinels Li{sub 1-x}[M{sub 2}]O{sub 4}, and olivines Li{sub 1-x}MPO{sub 4} having 0 < x < 1. Although higher capacities can be obtained with layered Li{sub 1-x}MO{sub 2} compounds, which have enabled the wireless revolution, their metastability makes them unlikely to be used in power applications. The spinel and olivine framework structures have been shown to be capable of charge/discharge rates of over 10C with a suitable temperature range for plug-in hybrid vehicles. (author)

First test of a high voltage feedthrough for liquid Argon TPCs connected to a 300 kV power supply

CERN Document Server

Cantini, C; Bueno, L Molina; Murphy, S; Radics, B; Regenfus, C; Rigaut, Y-A; Rubbia, A; Sergiampietri, F; Viant, T; Wu, S

2016-01-01

Voltages above a hundred kilo-volt will be required to generate the drift field of future very large liquid Argon Time Projection Chambers. The most delicate component is the feedthrough whose role is to safely deliver the very high voltage to the cathode through the thick insulating walls of the cryostat without compromising the purity of the argon inside. This requires a feedthrough that is typically meters long and carefully designed to be vacuum tight and have small heat input. Furthermore, all materials should be carefully chosen to allow operation in cryogenic conditions. In addition, electric fields in liquid argon should be kept below a threshold to reduce risks of discharges. The combination of all above requirements represents significant challenges from the design and manufacturing perspective. In this paper, we report on the successful operation of a feedthrough satisfying all the above requirements. The details of the feedthrough design and its manufacturing steps are provided. Very high voltages...

High-Voltage, High-Impedance Ion Beam Production

Science.gov (United States)

2009-06-01

the anode tube with a loosely-crumpled, thin aluminized- mylar foil. This spoils the virtual cathode and greatly reduces the neutron signal, as seen...ions follow ballistic (straight-line) trajectories in the drift tube (see Sec. VIII), then (except for the small displacement associated with bending...mTorr) ambient in the drift tube . Based on our previous experience, we would expect charge, but not necessarily current, neutralization of the beam

Mechanistic Insight in the Function of Phosphite Additives for Protection of LiNi0.5Co0.2Mn0.3O2 Cathode in High Voltage Li-Ion Cells.

Science.gov (United States)

He, Meinan; Su, Chi-Cheung; Peebles, Cameron; Feng, Zhenxing; Connell, Justin G; Liao, Chen; Wang, Yan; Shkrob, Ilya A; Zhang, Zhengcheng

2016-05-11

Triethlylphosphite (TEP) and tris(2,2,2-trifluoroethyl) phosphite (TTFP) have been evaluated as electrolyte additives for high-voltage Li-ion battery cells using a Ni-rich layered cathode material LiNi0.5Co0.2Mn0.3O2 (NCM523) and the conventional carbonate electrolyte. The repeated charge/discharge cycling for cells containing 1 wt % of these additives was performed using an NCM523/graphite full cell operated at the voltage window from 3.0-4.6 V. During the initial charge process, these additives decompose on the cathode surface at a lower oxidation potential than the baseline electrolyte. Impedance spectroscopy and post-test analyses indicate the formation of protective coatings by both additives on the cathode surface that prevent oxidative breakdown of the electrolyte. However, only TTFP containing cells demonstrate the improved capacity retention and Coulombic efficiency. For TEP, the protective coating is also formed, but low Li(+) ion mobility through the interphase layer results in inferior performance. These observations are rationalized through the inhibition of electrocatalytic centers present on the cathode surface and the formation of organophosphate deposits isolating the cathode surface from the electrolyte. The difference between the two phosphites clearly originates in the different properties of the resulting phosphate coatings, which may be in Li(+) ion conductivity through such materials.

Cathode ray tube screens

International Nuclear Information System (INIS)

Cockayne, B.; Robbins, D.J.; Glasper, J.L.

1982-01-01

An improved cathode ray tube screen is described which consists of a single- or a poly-crystalline slice of a material such as yttrium aluminium garnet in which dopants such as Tb 3 + , Eu 3 + , Ce 3 + or Tm 3 + are ion implanted to different depths or in different areas of the screen. Annealing the screen removes lattice damage caused by the ion implanting and assists the diffusion of the dopant into the crystal. (U.K.)

Use of Fourier domain filtering and dynamic programming in finding a titanium coil implant in high voltage x-ray images

DEFF Research Database (Denmark)

Nielsen, Henning; Hansen, Jesper Carl

2006-01-01

This paper deals with the problem of finding precise position and orientation of a titanium coil implant in humans. Analysis of high voltage X-rays stereo images are used to determine the true 3D position. High voltage images inherently presents with poor contrast. Various image processing techni...

Prediction Model and Principle of End-of-Life Threshold for Lithium Ion Batteries Based on Open Circuit Voltage Drifts

International Nuclear Information System (INIS)

Cui, Yingzhi; Yang, Jie; Du, Chunyu; Zuo, Pengjian; Gao, Yunzhi; Cheng, Xinqun; Ma, Yulin; Yin, Geping

2017-01-01

Highlights: •Open circuit voltage evolution over ageing of lithium ion batteries is deciphered. •The mechanism responsible for the end-of-life (EOL) threshold is elaborated. •A new prediction model of EOL threshold with improved accuracy is developed. •This EOL prediction model is promising for the applications in electric vehicles. -- Abstract: The end-of-life (EOL) of a lithium ion battery (LIB) is defined as the time point when the LIB can no longer provide sufficient power or energy to accomplish its intended function. Generally, the EOL occurs abruptly when the degradation of a LIB reaches the threshold. Therefore, current prediction methods of EOL by extrapolating the early degradation behavior often result in significant errors. To address this problem, this paper analyzes the reason for the EOL threshold of a LIB with shallow depth of discharge. It is found that the sudden appearance of EOL threshold results from the drift of open circuit voltage (OCV) at the end of both shallow depth and full discharges. Further, a new EOL threshold prediction model with highly improved accuracy is developed based on the OCV drifts and their evolution mechanism, which can effectively avoid the misjudgment of EOL threshold. The accuracy of this EOL threshold prediction model is verified by comparing with experimental results. The EOL threshold prediction model can be applied to other battery chemistry systems and its possible application in electric vehicles is finally discussed.

Construction of a full-length prototype of the BESIII drift chamber and on-detector test for the BESIII drift chamber electronics

International Nuclear Information System (INIS)

Qin Zhonghua; Wu Linghui; Liu Jianbei; Chinese Academy of Sciences, Beijing; Yan Zhikang; Hunan Univ., Changsha; Chen Yuanbo; Chen Chang; Xu Meihang; Wang Lan; Ma Xiaoyan; Jin Yan; Liu Rongguang; Tang Xiao; Zhang Guifang; Zhu Qiming; Sheng Huayi; Zhu Kejun

2007-01-01

A full-length prototype of the BESIII drift chamber was built. The experience gained on gas sealing, high voltage supply and front-end electronics installation should be greatly beneficial to the successful construction of the BESIII drift chamber. An on-detector test of the BESIII drift chamber electronics was carried out with the constructed prototype chamber. The noise performance, drift time and charge measurements, and electronics gains were examined specifically. The final test results indicate that the electronics have a good performance and can satisfy their design requirements. (authors)

3DII implantation effect on corrosion properties of the AISI/SAE 1020 steel

Energy Technology Data Exchange (ETDEWEB)

Dulce M., H.J.; Rueda V., Alejandro [Universidad Francisco de Paula Santander, A.A. 1055, Cucuta (Colombia); Dougar-Jabon, Valeri [Universidad Industrial de Santander, A.A. 678, Bucaramanga (Colombia)

2005-08-01

The three dimensional ion implantation technology (3DII) is one of the methods of improving the tribological characteristics and resistance to hydrogen embrittlement processes in metals. In this report, some results concerning the resistance effect of nitrogen ion implantation to oxidation of the sample, made of AISI/SAE 1020 steel, are given. The nitrogen ions were implanted in the discharge chamber of the JUPITER reactor. Both the treated and untreated samples were tested through potential-static measurements, which permitted to determine the corrosion current, the slopes that characterise the braking level of anode and cathode reactions. The polarization resistance near the corrosion potential is calculated. The results of the study encourage to consider the nitrogen ion implantation in high voltage and low pressure discharges as one of the methods of anticorrosive protection which do not change the geometric configuration of the treated steel pieces. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Drift chambers on the basis of mylar tubing blocks

International Nuclear Information System (INIS)

Budagov, Yu.A.; Golovanov, L.B.; Kuritsin, A.A.; Pukhov, O.E.; Khazins, D.M.; Chirikov-Zorin, I.E.; Joint Inst. for Nuclear Research, Dubna; Zhukov, V.Yu.

1992-01-01

We tested the models of the drift chambers, which are constructed of mylar tubing blocks. The purpose of the tubing block forming technology is to create long chambers (up to 3-4 meters). There are count and drift characteristics of the chambers for different gas pressures and different diameters of sense wires. The service time of the chambers is defined. We registered a photoeffect in the visible spectrum area, which is displayed on the surface of the mylar film cathode, covered by aluminium. 8 refs.; 5 figs

Systematic analysis and experiment of inductive coupling and induced voltage for inductively coupled wireless implantable neurostimulator application

International Nuclear Information System (INIS)

Xue, Ning; Cho, Sung-Hoon; Chang, Sung-Pil; Lee, Jeong-Bong

2012-01-01

The main strategy for wireless power transfer to implantable devices is to use inductive coupling technology. The induced voltage of implanted devices highly depends on factors such as mutual inductance between the external transmitter coil and the receiver coil, quality factor of the receiver circuit and operation frequency. In this paper, the mutual inductance under a variety of geometries of external coil and under the condition of different vertical distances, lateral displacements and angular misalignments between two coils were theoretically calculated and simulated. To ascertain the condition of maximum power transmission for certain coils’ position requirements, an LC tank (2.7 mm × 2 mm) consisting of a microfabricated gold inductor coil and a small surface mounted capacitor was designed and fabricated as the telemetric part of a neurostimulator. The induced voltage of the LC tank was measured in both air and artificial tissue media under different sizes of power coil and operation frequencies. As a result, the optimum size of a transmitter coil is selected to be of 4 mm inner radius with six turns of coil, while the whole coupling system operates at 94 MHz resonant frequency within 5–11 mm vertical distance, 0–4 mm lateral and 0°–50° angular misalignment between two coils. With the change of the above coils’ positions, the measured induced voltage drops within 30%, satisfying the surgical requirement for neurostimulator implantation. (paper)

Modelling current transfer to cathodes in metal halide plasmas

International Nuclear Information System (INIS)

Benilov, M S; Cunha, M D; Naidis, G V

2005-01-01

This work is concerned with investigation of the main features of current transfer to cathodes under conditions characteristic of metal halide (MH) lamps. It is found that the presence of MHs in the gas phase results in a small decrease of the cathode surface temperature and of the near-cathode voltage drop in the diffuse mode of current transfer; the range of stability of the diffuse mode expands. Effects caused by a variation of the work function of the cathode surface owing to formation of a monolayer of alkali metal atoms on the surface are studied for particular cases where the monolayer is composed of sodium or caesium. It is found that the formation of the sodium monolayer affects the diffuse mode of current transfer only moderately and in the same direction that the presence of metal atoms in the gas phase affects it. Formation of the caesium monolayer produces a dramatic effect: the cathode surface temperature decreases very strongly, the diffuse-mode current-voltage characteristic becomes N-S-shaped

Analytic solution of the potential and electric field of a jet type drift chamber

Energy Technology Data Exchange (ETDEWEB)

Weltin, A

1988-02-15

Starting from the known two-dimensional potential of a multiwire proportional chamber, the analytic expressions of the potential and the electric field are derived for a jet type drift chamber with a central wire plane of alternating sense and potential wires. The design goal of any jet chamber, namely the periodicity of the electric drift field, is imposed as a boundary condition at the beginning. In this way, the formulae are short and can be easily evaluated. In particular, expressions are given for the mean potential of the central wire plane, the drift field and the wire surface fields. Moreover, wire cathodes frequently used in jet chambers are described by analytic expressions. For a given drift field the difference of the potential as compared to a continuous metal cathode is presented. These results allowed to construct a two-dimensional computer simulation of the full OPAL jet chamber with no explicit periodicity but all its boundaries. Using field shaping electrodes a geometrically short yet quite satisfactory termination of a sense wire plane is demonstrated. Finally an example is presented, which is calculated in detail.

Targeted partial surface modification with nano-SiO2@Li2CoPO4F as high-voltage cathode material for LIBs

Science.gov (United States)

Chang, Caiyun; Huang, Zhipeng; Tian, Runsai; Jiang, Xinyu; Li, Chunsheng; Feng, Jijun

2017-10-01

Tuning whole/partial surface modification on cathode material with oxide material is a sought-after method to enhance the electrochemical performance in power storage field. Herein, nano-SiO2 targeted partial surface modified high voltage cathode material Li2CoPO4F has been successfully fabricated via a facile self-assembly process in silica dispersion at ambient temperature. With the aid of polar -OH groups attracted on the surface of SiO2 micelles, the nano-SiO2 preferentially nestle up along the borders and boundaries of Li2CoPO4F particles, where protection should be deployed with emphasis against the undesirable interactions between materials and electrolytes. Compared with pristine Li2CoPO4F, the SiO2 selectively modified Li2CoPO4F cathode materials, especially LCPF-3S, exhibit desirable electrochemical performances with higher discharge capacity, more outstanding cycle stability and favorable rate capability without any additional carbon involved. The greatly enhanced electrochemical properties can be attributed to the improved lithium-ion diffusion kinetics and structure tolerance during repeated lithiation/delithiation process. Such findings reveal a great potential of nano-SiO2 modified Li2CoPO4F as high energy cathode material for lithium ion batteries.

A high voltage SOI pLDMOS with a partial interface equipotential floating buried layer

International Nuclear Information System (INIS)

Wu Lijuan; Zhang Wentong; Zhang Bo; Li Zhaoji

2013-01-01

A novel silicon-on-insulator (SOI) high-voltage pLDMOS is presented with a partial interface equipotential floating buried layer (FBL) and its analytical model is analyzed in this paper. The surface heavily doped p-top layers, interface floating buried N + /P + layers, and three-step field plates are designed carefully in the FBL SOI pLDMOS to optimize the electric field distribution of the drift region and reduce the specific resistance. On the condition of ESIMOX (epoxy separated by implanted oxygen), it has been shown that the breakdown voltage of the FBL SOI pLDMOS is increased from −232 V of the conventional SOI to −425 V and the specific resistance R on,sp is reduced from 0.88 to 0.2424 Ω·cm 2 . (semiconductor devices)

Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems

Science.gov (United States)

Smart, Marshall C. (Inventor); Bugga, Ratnakumar V. (Inventor); Prakash, Surya G. (Inventor); Krause, Frederick C. (Inventor)

2015-01-01

The invention discloses various embodiments of electrolytes for use in lithium-ion batteries, the electrolytes having improved safety and the ability to operate with high capacity anodes and high voltage cathodes. In one embodiment there is provided an electrolyte for use in a lithium-ion battery comprising an anode and a high voltage cathode. The electrolyte has a mixture of a cyclic carbonate of ethylene carbonate (EC) or mono-fluoroethylene carbonate (FEC) co-solvent, ethyl methyl carbonate (EMC), a flame retardant additive, a lithium salt, and an electrolyte additive that improves compatibility and performance of the lithium-ion battery with a high voltage cathode. The lithium-ion battery is charged to a voltage in a range of from about 2.0 V (Volts) to about 5.0 V (Volts).

Increasing the Energy Efficiency of Aluminum-Reduction Cells Using Modified Cathodes

Science.gov (United States)

Jianping, Peng; Yang, Song; Yuezhong, Di; Yaowu, Wang; Naixiang, Feng

2017-10-01

A cathode with an inclined surface (5°) and increased bar collector height (230 mm high) was incorporated into two 300-kA industrial aluminum-reduction cells. The voltage of the cells with the modified cathode was reduced by approximately 200 mV when compared with that of a conventional cell with a flat cathode. Through the use of simulations, the reduction in the cell voltage was attributed to the cathode modification (40 mV) and a reduced electrolyte level of 0.5 cm (160 mV). As a result of reduced anode cathode distance (ACD), the ledge toe was extended to the anode shadow by 12 cm. This caused a large inverted horizontal current and a velocity increase. The ledge profile returned to the desired position when the cells were insulated more effectively, and the metal velocity and metal crest in the modified cells were reduced accordingly.

On the actual cathode mixed potential in direct methanol fuel cells

Science.gov (United States)

Zago, M.; Bisello, A.; Baricci, A.; Rabissi, C.; Brightman, E.; Hinds, G.; Casalegno, A.

2016-09-01

Methanol crossover is one of the most critical issues hindering commercialization of direct methanol fuel cells since it leads to waste of fuel and significantly affects cathode potential, forming a so-called mixed potential. Unfortunately, due to the sluggish anode kinetics, it is not possible to obtain a reliable estimation of cathode potential by simply measuring the cell voltage. In this work we address this limitation, quantifying the mixed potential by means of innovative open circuit voltage (OCV) tests with a methanol-hydrogen mixture fed to the anode. Over a wide range of operating conditions, the resulting cathode overpotential is between 250 and 430 mV and is strongly influenced by methanol crossover. We show using combined experimental and modelling analysis of cathode impedance that the methanol oxidation at the cathode mainly follows an electrochemical pathway. Finally, reference electrode measurements at both cathode inlet and outlet provide a local measurement of cathode potential, confirming the reliability of the innovative OCV tests and permitting the evaluation of cathode potential up to typical operating current. At 0.25 A cm-2 the operating cathode potential is around 0.85 V and the Ohmic drop through the catalyst layer is almost 50 mV, which is comparable to that in the membrane.

P-type silicon drift detectors

International Nuclear Information System (INIS)

Walton, J.T.; Krieger, B.; Krofcheck, D.; O'Donnell, R.; Odyniec, G.; Partlan, M.D.; Wang, N.W.

1995-06-01

Preliminary results on 16 CM 2 , position-sensitive silicon drift detectors, fabricated for the first time on p-type silicon substrates, are presented. The detectors were designed, fabricated, and tested recently at LBL and show interesting properties which make them attractive for use in future physics experiments. A pulse count rate of approximately 8 x l0 6 s -1 is demonstrated by the p-type silicon drift detectors. This count rate estimate is derived by measuring simultaneous tracks produced by a laser and photolithographic mask collimator that generates double tracks separated by 50 μm to 1200 μm. A new method of using ion-implanted polysilicon to produce precise valued bias resistors on the silicon drift detectors is also discussed

Investigation of Ion-Implanted Photosensitive Silicon Structures by Electrochemical Capacitance–Voltage Profiling

Energy Technology Data Exchange (ETDEWEB)

Yakovlev, G. E., E-mail: geyakovlev@etu.ru; Frolov, D. S.; Zubkova, A. V. [St. Petersburg State Electrotechnical University “LETI” (Russian Federation); Levina, E. E. [JSC National Research Institute “Electron” (Russian Federation); Zubkov, V. I.; Solomonov, A. V. [St. Petersburg State Electrotechnical University “LETI” (Russian Federation); Sterlyadkin, O. K.; Sorokin, S. A. [JSC National Research Institute “Electron” (Russian Federation)

2016-03-15

The method of electrochemical capacitance–voltage profiling is used to study boron-implanted silicon structures for CCD matrices with backside illumination. A series of specially prepared structures with different energies and doses of ion implantation and also with various materials used for the coating layers (aluminum, silicon oxide, and their combinations) is studied. The profiles of the depth distribution of majority charge carriers of the studied structures are obtained experimentally. Also, using the Poisson equation and the Fredholm equation of the first kind, the distributions of the charge-carrier concentration and of the electric field in the structures are calculated. On the basis of the analysis and comparison of theoretical and experimental concentration profiles, recommendations concerning optimization of the structures’ parameters in order to increase the value of the pulling field and decrease the effect of the surface potential on the transport of charge carriers are suggested.

Cathode plasma expansion in diode with explosive emission

International Nuclear Information System (INIS)

Zuo Yinghong; Fan Ruyu; Wang Jianguo; Zhu Jinhui

2012-01-01

The evolution characteristics of the cathode plasma in a planar diode with explosive emission were analyzed. Be- sides the axial expansion which can reduce the effective anode-cathode gap, the radial expansion of the cathode plasma which can affect the effective emitting area was also taken into account. According to the Child-Langmuir law and the experimental data of current and voltage with a electron vacuum diode under four-pulse mode, the dynamics of the cathode plasma was investigated, on the assumption that the radial speeds of the cathode plasma was approximately equal to the axial speed. The results show that the radial and axial expansion speeds of the cathode plasma are 0.9-2.8 cm/μs. (authors)

Electrochemical activation, voltage decay and hysteresis of Li-rich layered cathode probed by various cobalt content

KAUST Repository

Wu, Yingqiang

2018-02-01

The high capacity of Li-rich layered cathode materials have attracted great attention for the greater energy density lithium ion (Li-ion) batteries, but the understanding of knowledge associated with electrochemical behaviours are still needed to improve their performances further. In this study, different amount of Co content is designed in Li-rich layered compounds (0.5Li2MnO3·0.5LiMn0.5-xNi0.5-xCo2xO2, 0 ≤ x ≤ 0.2), and the stepwise electrochemical activation process is applied to explore the features. We discover that the substitution of Co3+ ions can accelerate the electrochemical activation of Li2MnO3 component, and the Co-doped compound delivers much higher capacities even they suffer an apparent voltage decay comparing to the Co-free one. Besides, a fast metal ions migration exists (e.g., from the metastable tetrahedral site to the lower energy cubic site) in initial dozens of cycles (e.g., 30 cycles at 0.1C); thereafter, they likely return to the original octahedral site, as demonstrated in the voltage decay and hysteresis analysis.

Probabilistic modelling of the high-pressure arc cathode spot displacement dynamic

CERN Document Server

Coulombe, S

2003-01-01

A probabilistic modelling approach for the study of the cathode spot displacement dynamic in high-pressure arc systems is developed in an attempt to interpret the observed voltage fluctuations. The general framework of the model allows to define simple, probabilistic displacement rules, the so-called cathode spot dynamic rules, for various possible surface states (un-arced metal, arced, contaminated) and to study the resulting dynamic of the cathode spot displacements over one or several arc passages. The displacements of the type-A cathode spot (macro-spot) in a magnetically rotating arc using concentric electrodes made up of either clean or contaminated metal surfaces is considered. Experimental observations for this system revealed a 1/f sup - sup t sup i sup l sup d sup e sup 1 signature in the frequency power spectrum (FPS) of the arc voltage for anchoring arc conditions on the cathode (e.g. clean metal surface), while it shows a 'white noise' signature for conditions favouring a smooth movement (e.g. ox...

Experimental investigation of cathode spots and plasma jets behavior subjected to two kinds of axial magnetic field electrodes

International Nuclear Information System (INIS)

Wang, Lijun; Deng, Jie; Zhou, Xin; Jia, Shenli; Qian, Zhonghao; Shi, Zongqian

2016-01-01

In this paper, cathode spot plasma jet (CSPJ) rotation and cathode spots behavior subjected to two kinds of large diameter axial magnetic field (AMF) electrode (cup-shaped and coil-shaped) are studied and analyzed based on experiments. The influence of gap distances on the CSPJ rotational behavior is analyzed. Experimental results show that CSPJ rotational phenomena extensively exist in the vacuum interrupters, and CSPJ rotational direction is along the direction of composite magnetic field (mainly the combination of the axial and azimuthal components). For coil-shaped and cup-shaped AMF electrodes, the rotational or inclination phenomena before the current peak value are much more significant than that after current peak value (for the same arc current), which is related to the larger ratio of azimuthal magnetic field B_t and AMF B_z (B_t/B_z). With the increase of the gap distance, the AMF strength decreases, when the arc current is kept as constant, the azimuthal magnetic field is kept invariable, the ratio between azimuthal magnetic field and AMF is increased, which results in the increase of rotational effect. For cathode spots motion, compared with cup-shaped electrode, coil-shaped electrode has the inverse AMF direction. The Robson drift direction of cathode spots of coil-shaped electrode is opposite to that of cup-shaped electrode. With the increase of gap distance, the Robson angle is decreased, which is associated with the reduced AMF strength. Erosion imprints of anode and cathode are also related to the CSPJ rotational phenomena and cathode spots behavior. The noise of arc voltage in the initial arcing stage is related to the weaker AMF.

Experimental investigation of cathode spots and plasma jets behavior subjected to two kinds of axial magnetic field electrodes

Energy Technology Data Exchange (ETDEWEB)

Wang, Lijun; Deng, Jie; Zhou, Xin; Jia, Shenli; Qian, Zhonghao; Shi, Zongqian [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China)

2016-04-15

In this paper, cathode spot plasma jet (CSPJ) rotation and cathode spots behavior subjected to two kinds of large diameter axial magnetic field (AMF) electrode (cup-shaped and coil-shaped) are studied and analyzed based on experiments. The influence of gap distances on the CSPJ rotational behavior is analyzed. Experimental results show that CSPJ rotational phenomena extensively exist in the vacuum interrupters, and CSPJ rotational direction is along the direction of composite magnetic field (mainly the combination of the axial and azimuthal components). For coil-shaped and cup-shaped AMF electrodes, the rotational or inclination phenomena before the current peak value are much more significant than that after current peak value (for the same arc current), which is related to the larger ratio of azimuthal magnetic field B{sub t} and AMF B{sub z} (B{sub t}/B{sub z}). With the increase of the gap distance, the AMF strength decreases, when the arc current is kept as constant, the azimuthal magnetic field is kept invariable, the ratio between azimuthal magnetic field and AMF is increased, which results in the increase of rotational effect. For cathode spots motion, compared with cup-shaped electrode, coil-shaped electrode has the inverse AMF direction. The Robson drift direction of cathode spots of coil-shaped electrode is opposite to that of cup-shaped electrode. With the increase of gap distance, the Robson angle is decreased, which is associated with the reduced AMF strength. Erosion imprints of anode and cathode are also related to the CSPJ rotational phenomena and cathode spots behavior. The noise of arc voltage in the initial arcing stage is related to the weaker AMF.

Thermal-wave balancing flow sensor with low-drift power feedback

NARCIS (Netherlands)

Dijkstra, Marcel; Lammerink, Theodorus S.J.; Pjetri, O.; de Boer, Meint J.; Berenschot, Johan W.; Wiegerink, Remco J.; Elwenspoek, Michael Curt

2014-01-01

A control system using a low-drift power-feedback signal was implemented applying thermal waves, giving a sensor output independent of resistance drift and thermo-electric offset voltages on interface wires. Kelvin-contact sensing and power control is used on heater resistors, thereby inhibiting the

Long pulse, plasma cathode E-gun

International Nuclear Information System (INIS)

Goebel, D.M.; Schumacher, R.W.; Watkins, R.M.

1993-01-01

A unique, long-pulse E-gun has been developed for high-power tube applications. The Hollow-Cathode-Plasma (HCP) E-gun overcomes the limitations of conventional thermionic-cathode guns that have limited current density (typically ≤ 10 A/cm 2 ) or field-emission guns that offer high current density but suffer from short pulsewidth capability (typically 50 A/cm 2 ), long-pulse operation without gap closure, and also requires no cathode-heater power. The gun employs a low-pressure glow discharge inside a hollow cathode (HC) structure to provide a stable, uniform plasma surface from which a high current-density electron beam can be extracted. The plasma density is controlled by a low-voltage HC discharge pulser to produce the desired electron current density at the first grid of a multi-grid accelerator system. A dc high-voltage electron-beam supply accelerates the electrons across the gap, while the HC pulser modulates the beam current to generate arbitrary pulse waveforms. The electron accelerator utilizes a multi-aperture array that produces a large area, high perveance (>35 μpervs) beam consisting initially of many individual beamlets. The E-beam is normally operated without an applied magnetic field in the ion-focused regime, where the plasma produced by beam ionization of a background gas space-charge neutralizes the beam, and the Bennett self-pinch compresses the beamlets and increases the current density. The self-pinched beam has been observed to propagate over a meter without beam breakup or instabilities. The HCP E-gun has been operated at voltages up to 150 kV, currents up to 750 A, and pulse lengths of up to 120 μsec

A new large-scale plasma source with plasma cathode

International Nuclear Information System (INIS)

Yamauchi, K.; Hirokawa, K.; Suzuki, H.; Satake, T.

1996-01-01

A new large-scale plasma source (200 mm diameter) with a plasma cathode has been investigated. The plasma has a good spatial uniformity, operates at low electron temperature, and is highly ionized under relatively low gas pressure of about 10 -4 Torr. The plasma source consists of a plasma chamber and a plasma cathode generator. The plasma chamber has an anode which is 200 mm in diameter, 150 mm in length, is made of 304 stainless steel, and acts as a plasma expansion cup. A filament-cathode-like plasma ''plasma cathode'' is placed on the central axis of this source. To improve the plasma spatial uniformity in the plasma chamber, a disk-shaped, floating electrode is placed between the plasma chamber and the plasma cathode. The 200 mm diameter plasma is measure by using Langmuir probes. As a result, the discharge voltage is relatively low (30-120 V), the plasma space potential is almost equal to the discharge voltage and can be easily controlled, the electron temperature is several electron volts, the plasma density is about 10 10 cm -3 , and the plasma density is about 10% variance in over a 100 mm diameter. (Author)

Electron beam generation form a superemissive cathode

International Nuclear Information System (INIS)

Hsu, T.-Y.; Liou, R.-L.; Kirkman-Amemiya, G.; Gundersen, M.A.

1991-01-01

An experimental study of electron beams produced by a superemissive cathode in the Back-Lighted Thyratron (BLT) and the pseudospark is presented. This work is motivated by experiments demonstrating very high current densities (≥10 kA/cm 2 over an area of 1 cm 2 ) from the pseudospark and BLT cathode. This high-density current is produced by field-enhanced thermionic emission from the ion beam-heated surface of a molybdenum cathode. This work reports the use of this cathode as a beam source, and is to be distinguished from previous work reporting hollow cathode-produced electron beams. An electron beam of more than 260 A Peak current has been produced with 15 kV applied voltage. An efficiency of ∼10% is estimated. These experimental results encourage further investigation of the super-emissive cathode as an intense electron beam source for applications including accelerator technology

Measurements on the source properties of a hollow cathode

NARCIS (Netherlands)

Vogels, J.M.M.J.; Konings, L.U.E.; Koelman, J.M.V.A.; Schram, D.C.; Bötticher, W.; Wenk, H.; Schulz-Gulde, E.

1983-01-01

The ion production rate of a hollow cathode in a magnetized arc has been measured. At low magnetic fields supersonic ion drifts have been observed. The ionized fraction of the gas flow decreases with increasing flow and the ion flux saturates at high flow rates

Cyclotron resonance in a cathode ray tube

International Nuclear Information System (INIS)

Gherbanovschi, N.; Tanasa, M.; Stoican, O.

2002-01-01

Absorption of the RF energy by the electron beam in a cathode ray tube due to the cyclotron resonance is described. The cathode ray tube is placed within a Helmholtz coils system supplied by a sawtooth current generator. In order to generate RF field and to detect RF absorption a gate dip-meter equipped with a FET transistor is used. The bias voltage variations of the FET transistors as a function of the magnetic field are recorded. The operating point of the cathode ray tube has been chosen so that the relaxation oscillations of the detection system can be observed. (authors)

Origin of microplasma instabilities during DC operation of silicon based microhollow cathode devices

Science.gov (United States)

Felix, Valentin; Lefaucheux, Philippe; Aubry, Olivier; Golda, Judith; Schulz-von der Gathen, Volker; Overzet, Lawrence J.; Dussart, Rémi

2016-04-01

The failure mechanisms of micro hollow cathode discharges (MHCD) in silicon have been investigated using their I-V characteristics, high speed photography and scanning electron microscopy. Experiments were carried out in helium. We observed I-V instabilities in the form of rapid voltage decreases associated with current spikes. The current spikes can reach values more than 100 times greater than the average MHCD current. (The peaks can be more than 1 Ampere for a few 10’s of nanoseconds.) These current spikes are correlated in time with 3-10 μm diameter optical flashes that occur inside the cavities. The SEM characterizations indicated that blister-like structures form on the Si surface during plasma operation. Thin Si layers detach from the surface in localized regions. We theorize that shallow helium implantation occurs and forms the ‘blisters’ whenever the Si is biased as the cathode. These blisters ‘explode’ when the helium pressure inside them becomes too large leading to the transient micro-arcs seen in both the optical emission and the I-V characteristics. We noted that blisters were never found on the metal counter electrode, even when it was biased as the cathode (and the Si as the anode). This observation led to a few suggestions for delaying the failure of Si MHCDs. One may coat the Si cathode (cavities) with blister resistant material; design the MHCD array to operate with the Si as the anode rather than as the cathode; or use a gas additive to prevent surface damage. Regarding the latter, tests using SF6 as the gas additive successfully prevented blister formation through rapid etching. The result was an enhanced MHCD lifetime.

Self-organization in cathode boundary layer discharges in xenon

International Nuclear Information System (INIS)

Takano, Nobuhiko; Schoenbach, Karl H

2006-01-01

Self-organization of direct current xenon microdischarges in cathode boundary layer configuration has been studied for pressures in the range 30-140 Torr and for currents in the range 50 μA-1 mA. Side-on and end-on observations of the discharge have provided information on the structure and spatial arrangement of the plasma filaments. The regularly spaced filaments, which appear in the normal glow mode when the current is lowered, have a length which is determined by the cathode fall. It varies, dependent on pressure and current, between 50 and 70 μm. The minimum diameter is approximately 80 μm, as determined from the radiative emission in the visible. The filaments are sources of extensive excimer emission. Measurements of the cathode fall length have allowed us to determine the secondary emission coefficient for the discharge in the normal glow mode and to estimate the cathode fall voltage at the transition from normal glow mode to filamentary mode. It was found that the cathode fall voltage at this transition decreases, indicating the onset of additional electron gain processes at the cathode. The regular arrangement of the filaments, self-organization, is assumed to be due to Coulomb interactions between the positively charged cathode fall channels and positive space charges on the surface of the surrounding dielectric spacer. Calculations based on these assumptions showed good agreement with experimentally observed filament patterns

Characteristics of a delay-line readout in a cylindrical drift chamber system

International Nuclear Information System (INIS)

Barber, R.; Ahmed, M.W.; Dzemidzic, M.; Empl, A.; Hungerford, E.V.; Lan, K.J.; Wilson, J.; Cooper, M.D.; Gagliardi, C.A.; Haim, D.; Kim, G.J.; Koetke, D.D.; Tribble, R.E.; Van Ausdeln, L.A.

2002-01-01

This paper reports on the design, construction, and operational characteristics of a delay-line readout implemented on the cathode foils of a cylindrical drift chamber system. The readout was used to determine the position of an event along the length of the 1.74 m drift wires in the MEGA detectors used at the Los Alamos Meson Physics Facility. The performance of the system is interpreted by comparison to a PSPICE simulation, and to simple analytical models

Study on the emission characteristics of cathodes in an ionized gas flow

International Nuclear Information System (INIS)

Maslennikov, N.M.

1975-01-01

Emission characteristics of molybdenum, tungsten and tantalum cathodes in a flow of argon and argon-potassium plasma with gas pressure of 0.04 atm, 1 atm and 0.25 atm were investigated. Gas was heated in a plasmatron. Measuring electrodes were arranged across the gas flow. Investigations in an argon plasma were carried out with the object of comparing of current-voltage dependences for potassium-activated and nonactivated cathodes. In all cases the current-voltage characteristics were growing. No saturation was observed of a current between accurent electrodes. The increase of a current between the cathodes due to the thermionic emission from the cathode began to effect at the cathode temperature of 2.470 K. The work function was found to be 5 to 5.2 ev. The comparison of the results obtained experimentally in the paper show a qualitative coincidence with calculations by some authors and a discrepancy with theoretical conceptions of other authors

Functionalized NbS2 as cathode for Li- and Na-ion batteries

KAUST Repository

Zhu, Jiajie

2017-07-27

Cathodes of Li- and Na-ion batteries usually have capacities <200 mAh/g, significantly less than the anodes. Two-dimensional materials can overcome this limitation but suffer from low voltages. In this context, we investigate NbS2 functionalized by O, F, and Cl as a cathode material by first-principles calculations, considering both the conversion and intercalation mechanisms. NbS2O2 shows a higher voltage than NbS2 for both Li and Na, but the voltage decreases drastically for increasing ion coverage. Even higher voltages and favorable dependences on the ion coverage are achieved by F and Cl functionalization. We obtain NbS2F2 and NbS2Cl2 energy densities of 1223 mW h/g and 823 mW h/g for lithiation and 1086 mW h/g and 835 mW h/g for sodiation, respectively. These values are higher than those for most state-of-the-art cathode materials (∼600 mW h/g). In addition, low diffusion barriers enable high cycling rates.

Functionalized NbS2 as cathode for Li- and Na-ion batteries

KAUST Repository

Zhu, Jiajie; Alshareef, Husam N.; Schwingenschlö gl, Udo

2017-01-01

Cathodes of Li- and Na-ion batteries usually have capacities <200 mAh/g, significantly less than the anodes. Two-dimensional materials can overcome this limitation but suffer from low voltages. In this context, we investigate NbS2 functionalized by O, F, and Cl as a cathode material by first-principles calculations, considering both the conversion and intercalation mechanisms. NbS2O2 shows a higher voltage than NbS2 for both Li and Na, but the voltage decreases drastically for increasing ion coverage. Even higher voltages and favorable dependences on the ion coverage are achieved by F and Cl functionalization. We obtain NbS2F2 and NbS2Cl2 energy densities of 1223 mW h/g and 823 mW h/g for lithiation and 1086 mW h/g and 835 mW h/g for sodiation, respectively. These values are higher than those for most state-of-the-art cathode materials (∼600 mW h/g). In addition, low diffusion barriers enable high cycling rates.

Construction and operation of a drift-collection calorimeter

International Nuclear Information System (INIS)

Ambats, I.; Ayres, D.S.; Dawson, J.W.

1984-01-01

Large areas planar drift chambers with long drift distance (up to 50 cm) have been developed for possible use in the new Soudan 2 nucleon decay detector. Design goals included fine sampling to determine the topology of complex events with several low-energy tracks. The large scale of the experiment (> 1000 metric tons) required large area inexpensive chambers, which also had good position resolution and multi-track separation. The chambers were to be installed between thin sheets of steel to form a finegrained detector. A second goal was the sampling of dE/dx with each position measurement, in order to determine the direction and particle identity of each track. In this paper we report on the construction and operation of a prototype dectector consisting of 50 chambers, separated by 3 mm-thick steel plates. Readout of drift time and pulse height from anode wires and an orthogonal grid of bussed cathode pads utilized 6-bit flash ADC's. This application of the drift-collection calorimeter technique to a nucleon decay detector follows the investigation by a number of groups of calorimeters for high energy detectors based on long drifting

Iron phosphate materials as cathodes for lithium batteries

CERN Document Server

Prosini, Pier Paolo

2011-01-01

""Iron Phosphate Materials as Cathodes for Lithium Batteries"" describes the synthesis and the chemical-physical characteristics of iron phosphates, and presents methods of making LiFePO4 a suitable cathode material for lithium-ion batteries. The author studies carbon's ability to increase conductivity and to decrease material grain size, as well as investigating the electrochemical behaviour of the materials obtained. ""Iron Phosphate Materials as Cathodes for Lithium Batteries"" also proposes a model to explain lithium insertion/extraction in LiFePO4 and to predict voltage profiles at variou

Design and Development of a control system for the Drift Tube Chamber High Voltage Power Supply

CERN Document Server

Leon Vega, Luis Gerardo

2017-01-01

This paper contains information related to the design and development of a control and data acquisition manager implemented in WinCC, a Siemens SCADA system. The goal was to manage a CAEN HV (High Voltage) system for powering a Drift Tube (DT) chamber of the CMS experiment. Basically, this manager consists of two sections: a friendly user interface and powerful scripts to manage the back-end. It is in charge of adjusting the power supply settings to the correct values needed for the DT Chamber operations (ON, OFF, Standby), depending of the requirements of the operator, managing automatically all the transition process. Also, the manager is in charge of configuring the archiving process for acquiring data and providing the history of the system. It also implements the monitoring of the status of each connected channel, alerting in case it is needed.

One-dimensional conduction through supporting electrolytes: two-scale cathodic Debye layer.

Science.gov (United States)

Almog, Yaniv; Yariv, Ehud

2011-10-01

Supporting-electrolyte solutions comprise chemically inert cations and anions, produced by salt dissolution, together with a reactive ionic species that may be consumed and generated on bounding ion-selective surfaces (e.g., electrodes or membranes). Upon application of an external voltage, a Faraday current is thereby established. It is natural to analyze this ternary-system process through a one-dimensional transport problem, employing the thin Debye-layer limit. Using a simple model of ideal ion-selective membranes, we have recently addressed this problem for moderate voltages [Yariv and Almog, Phys. Rev. Lett. 105, 176101 (2010)], predicting currents that scale as a fractional power of Debye thickness. We address herein the complementary problem of moderate currents. We employ matched asymptotic expansions, separately analyzing the two inner thin Debye layers adjacent to the ion-selective surfaces and the outer electroneutral region outside them. A straightforward calculation following comparable singular-perturbation analyses of binary systems is frustrated by the prediction of negative ionic concentrations near the cathode. Accompanying numerical simulations, performed for small values of Debye thickness, indicate a number unconventional features occurring at that region, such as inert-cation concentration amplification and electric-field intensification. The current-voltage correlation data of the electrochemical cell, obtained from compilation of these simulations, does not approach a limit as the Debye thickness vanishes. Resolution of these puzzles reveals a transformation of the asymptotic structure of the cathodic Debye layer. This reflects the emergence of an internal boundary layer, adjacent to the cathode, wherein field and concentration scaling differs from those of the Gouy-Chapman theory. The two-scale feature of the cathodic Debye layer is manifested through a logarithmic voltage scaling with Debye thickness. Accounting for this scaling, the

Electrochemical Properties of the LiNi0.6Co0.2Mn0.2O2 Cathode Material Modified by Lithium Tungstate under High Voltage.

Science.gov (United States)

Fu, Jiale; Mu, Daobin; Wu, Borong; Bi, Jiaying; Cui, Hui; Yang, Hao; Wu, Hanfeng; Wu, Feng

2018-05-31

An amount (5 wt %) of lithium tungstate (Li 2 WO 4 ) as an additive significantly improves the cycle and rate performances of the LiNi 0.6 Co 0.2 Mn 0.2 O 2 electrode at the cutoff voltage of 4.6 V. The 5 wt % Li 2 WO 4 -mixed LiNi 0.6 Co 0.2 Mn 0.2 O 2 electrode delivers a reversible capacity of 199.2 mA h g -1 and keeps 73.1% capacity for 200 cycles at 1 C. It retains 67.4% capacity after 200 cycles at 2 C and delivers a discharge capacity of 167.3 mA h g -1 at 10 C, while those of the pristine electrode are only 44.7% and 87.5 mA h g -1 , respectively. It is shown that the structure of the LiNi 0.6 Co 0.2 Mn 0.2 O 2 cathode material is not affected by mixing Li 2 WO 4 . The introduced Li 2 WO 4 effectively restrains the LiPF 6 and carbonate solvent decomposition by consuming PF 5 at high cutoff voltage, forming a stable cathode/electrolyte interface film with low resistance.

Cathode ray tube

International Nuclear Information System (INIS)

1979-01-01

A cathode ray tube comprises two electron lens means in combination to crossover the electron beam at a second crossover between the two electron lens means with one of the two lens means having a variable voltage applied thereto to control the location of the beam crossover in order to focus the beam onto a display screen at any location away from the screen center. (Auth.)

Cylindrical geometry for proportional and drift chambers

International Nuclear Information System (INIS)

Sadoulet, B.

1975-06-01

For experiments performed around storage rings such as e + e - rings or the ISR pp rings, cylindrical wire chambers are very attractive. They surround the beam pipe completely without any dead region in the azimuth, and fit well with the geometry of events where particles are more or less spherically produced. Unfortunately, cylindrical proportional or drift chambers are difficult to make. Problems are discussed and two approaches to fabricating the cathodes are discussed. (WHK)

Drift chamber system for use in a high rate environment

International Nuclear Information System (INIS)

Etkin, A.

1978-01-01

A system of short drift distance (0.125'') drift chambers is described. This system is being built for use in the Brookhaven National Laboratory Multiparticle Spectrometer. These chambers will be able to handle beam rates of several million/pulse and give a spatial resolution of the order of 150 μm. Cathode readout will provide unique 3-dimensional points for each crack. The readout will utilize three custom built integrated circuits, a four channel amplifier-shaper, a four channel discriminator and a four channel shift register delay and time digitizer. A summary of test results on a prototype is also given

Experimental investigation of high temperature high voltage thermionic diode for the space power nuclear reactor

International Nuclear Information System (INIS)

Onufriyev, Valery V.

2001-01-01

It is well known that the rise of arc from the dense glow discharge is connected with the thermion and secondary processes on the cathode surface (Granovsky, 1971; Leob, 1953; Engel, 1935). First model of breakdown of the cathode layer is connected with the increase of the cathode temperature in consequence of the ion bombardment that leads to the grows its thermo-emissive current. Other model shows the main role of the secondary effects on the cathode surface-the increase of the secondary ion emission coefficient--γ i with the grows of glow discharge voltage. But the author of this investigation work of breakdown in Cs vapor (a transmission the glow discharge into self-maintaining arc discharge) discovered the next peculiarity: the value of breakdown voltage is constant when the values of vapor temperature (its pressure p cs ) and cathode temperature T k is constant too (U b =constant with T k =constant and p cs =constant) and it is not a statistical value (Onufryev, Grishin, 1996) (that was observed in gas glow discharges other authors (Granovsky, 1971; Leob, 1953; Engel, 1935)). The investigations of thermion high voltage high temperature diode (its breakdown characteristics in closed state and voltage-current characteristics in disclosed state) showed that the value of the breakdown voltage is depended on the vapor pressure in inter-electrode gap (IEG)-p cs and cathode temperature-T k and is independent on IEG length--Δ ieg . On this base it was settled that the main role in transition of glow discharge to self-maintaining arc discharge plays an ion cathode layer but more exactly--the region of excited atoms--''Aston glow.''

Experimental investigation of high temperature high voltage thermionic diode for the space power nuclear reactor

Science.gov (United States)

Onufriyev, Valery. V.

2001-02-01

It is well known that the rise of arc from the dense glow discharge is connected with the thermion and secondary processes on the cathode surface (Granovsky, 1971; Leob, 1953; Engel, 1935). First model of breakdown of the cathode layer is connected with the increase of the cathode temperature in consequence of the ion bombardment that leads to the grows its thermo-emissive current. Other model shows the main role of the secondary effects on the cathode surface-the increase of the secondary ion emission coefficient-γi with the grows of glow discharge voltage. But the author of this investigation work of breakdown in Cs vapor (a transmission the glow discharge into self-maintaining arc discharge) discovered the next peculiarity: the value of breakdown voltage is constant when the values of vapor temperature (its pressure pcs) and cathode temperature Tk is constant too (Ub=constant with Tk=constant and pcs=constant) and it is not a statistical value (Onufryev, Grishin, 1996) (that was observed in gas glow discharges other authors (Granovsky, 1971; Leob, 1953; Engel, 1935)). The investigations of thermion high voltage high temperature diode (its breakdown characteristics in closed state and voltage-current characteristics in disclosed state) showed that the value of the breakdown voltage is depended on the vapor pressure in inter-electrode gap (IEG)-pcs and cathode temperature-Tk and is independent on IEG length-Δieg. On this base it was settled that the main role in transition of glow discharge to self-maintaining arc discharge plays an ion cathode layer but more exactly-the region of excited atoms-``Aston glow.'' .

Origin of microplasma instabilities during DC operation of silicon based microhollow cathode devices

International Nuclear Information System (INIS)

Felix, Valentin; Lefaucheux, Philippe; Aubry, Olivier; Dussart, Rémi; Golda, Judith; Schulz-von der Gathen, Volker; Overzet, Lawrence J

2016-01-01

The failure mechanisms of micro hollow cathode discharges (MHCD) in silicon have been investigated using their I-V characteristics, high speed photography and scanning electron microscopy. Experiments were carried out in helium. We observed I–V instabilities in the form of rapid voltage decreases associated with current spikes. The current spikes can reach values more than 100 times greater than the average MHCD current. (The peaks can be more than 1 Ampere for a few 10’s of nanoseconds.) These current spikes are correlated in time with 3–10 μm diameter optical flashes that occur inside the cavities. The SEM characterizations indicated that blister-like structures form on the Si surface during plasma operation. Thin Si layers detach from the surface in localized regions. We theorize that shallow helium implantation occurs and forms the ‘blisters’ whenever the Si is biased as the cathode. These blisters ‘explode’ when the helium pressure inside them becomes too large leading to the transient micro-arcs seen in both the optical emission and the I–V characteristics. We noted that blisters were never found on the metal counter electrode, even when it was biased as the cathode (and the Si as the anode). This observation led to a few suggestions for delaying the failure of Si MHCDs. One may coat the Si cathode (cavities) with blister resistant material; design the MHCD array to operate with the Si as the anode rather than as the cathode; or use a gas additive to prevent surface damage. Regarding the latter, tests using SF 6 as the gas additive successfully prevented blister formation through rapid etching. The result was an enhanced MHCD lifetime. (paper)

The fractal nature of vacuum arc cathode spots

International Nuclear Information System (INIS)

Anders, Andre

2005-01-01

Cathode spot phenomena show many features of fractals, for example self-similar patterns in the emitted light and arc erosion traces. Although there have been hints on the fractal nature of cathode spots in the literature, the fractal approach to spot interpretation is underutilized. In this work, a brief review of spot properties is given, touching the differences between spot type 1 (on cathodes surfaces with dielectric layers) and spot type 2 (on metallic, clean surfaces) as well as the known spot fragment or cell structure. The basic properties of self-similarity, power laws, random colored noise, and fractals are introduced. Several points of evidence for the fractal nature of spots are provided. Specifically power laws are identified as signature of fractal properties, such as spectral power of noisy arc parameters (ion current, arc voltage, etc) obtained by fast Fourier transform. It is shown that fractal properties can be observed down to the cutoff by measurement resolution or occurrence of elementary steps in physical processes. Random walk models of cathode spot motion are well established: they go asymptotically to Brownian motion for infinitesimal step width. The power spectrum of the arc voltage noise falls as 1/f 2 , where f is frequency, supporting a fractal spot model associated with Brownian motion

A new thin film deposition process by cathodic plasma electrolysis

International Nuclear Information System (INIS)

Paulmier, T.; Kiriakos, E.; Bell, J.; Fredericks, P.

2004-01-01

Full text: A new technique, called atmospheric pressure plasma deposition (APPD), has been developed since a few years for the deposition of carbon and DLC, Titanium or Silicon films on metal and metal alloys substrates. A high voltage (2kV) is applied in a liquid electrolytic solution between an anode and a cathode, both electrodes being cylindrical: a glow discharge is then produced and confined at the vicinity of the cathode. The physic of the plasma in the electrolytic solution near the cathode is very different form the other techniques of plasma deposition since the pressure is here close to the atmospheric pressure. We describe here the different physico-chemical processes occurring during the process. In this cathodic process, the anodic area is significantly larger than the cathode area. In a first step, the electrolytic solution is heated by Joule effect induced by the high voltage between the electrodes. Due to the high current density, the vaporization of the solution occurs near the cathode: a large amount of bubbles are produced which are stabilized at the electrode by hydrodynamic and electromagnetic forces, forming a vapour sheath. The electric field and voltage drop are then concentrated in this gas envelope, inducing the ionization of the gas and the ignition of a glow discharge at the surface of the material. This plasma induces the formation of ionized and reactive species which diffuse and are accelerated toward the cathode. These excited species are the precursors for the formation of the deposition material. At the same time, the glow discharge interacts with the electrolyte solution inducing also ionization, convection and polymerization processes in the liquid: the solution is therefore a second source of the deposition material. A wide range of films have been deposited with a thickness up to 10 micrometers. These films have been analyzed by SEM and Raman spectroscopy. The electrolytic solution has been characterized by GC-MS and the

Manganese Dioxide As Rechargeable Magnesium Battery Cathode

International Nuclear Information System (INIS)

Ling, Chen; Zhang, Ruigang

2017-01-01

Rechargeable magnesium battery (rMB) has received increased attention as a promising alternative to current Li-ion technology. However, the lack of appropriate cathode that provides high-energy density and good sustainability greatly hinders the development of practical rMBs. To date, the successful Mg 2+ -intercalation was only achieved in only a few cathode hosts, one of which is manganese dioxide. This review summarizes the research activity of studying MnO 2 in magnesium cells. In recent years, the cathodic performance of MnO 2 was impressively improved to the capacity of >150–200 mAh g −1 at voltage of 2.6–2.8 V with cyclability to hundreds or more cycles. In addition to reviewing electrochemical performance, we sketch a mechanistic picture to show how the fundamental understanding about MnO 2 cathode has been changed and how it paved the road to the improvement of cathode performance.

Manganese Dioxide As Rechargeable Magnesium Battery Cathode

Energy Technology Data Exchange (ETDEWEB)

Ling, Chen, E-mail: chen.ling@toyota.com; Zhang, Ruigang [Toyota Research Institute of North America, Ann Arbor, MI (United States)

2017-11-03

Rechargeable magnesium battery (rMB) has received increased attention as a promising alternative to current Li-ion technology. However, the lack of appropriate cathode that provides high-energy density and good sustainability greatly hinders the development of practical rMBs. To date, the successful Mg{sup 2+}-intercalation was only achieved in only a few cathode hosts, one of which is manganese dioxide. This review summarizes the research activity of studying MnO{sub 2} in magnesium cells. In recent years, the cathodic performance of MnO{sub 2} was impressively improved to the capacity of >150–200 mAh g{sup −1} at voltage of 2.6–2.8 V with cyclability to hundreds or more cycles. In addition to reviewing electrochemical performance, we sketch a mechanistic picture to show how the fundamental understanding about MnO{sub 2} cathode has been changed and how it paved the road to the improvement of cathode performance.

Lithium-manganese dioxide cells for implantable defibrillator devices - Discharge voltage models

Energy Technology Data Exchange (ETDEWEB)

Root, Michael J. [Cardiac Rhythm Management Research and Development, Boston Scientific Corp., 4100 Hamline Ave. N., St. Paul, MN 55112 (United States)

2010-08-01

The discharge potential behavior of lithium-manganese dioxide cells designed for implantable cardiac defibrillators was characterized as a function of extent of cell depletion for tests designed to discharge the cells for times between 1 and 7 years. The discharge potential curves may be separated into two segments from 0 {<=} x {<=} {proportional_to}0.51 and {proportional_to}0.51 {<=} x {<=} 1.00, where x is the dimensionless extent of discharge referenced to the rated cell capacity. The discharge potentials conform to Tafel kinetics in each segment. This behavior allows the discharge potential curves to be predicted for an arbitrary discharge load and long term discharge performance may be predicted from short term test results. The discharge potentials may subsequently be modeled by fitting the discharge curves to empirical functions like polynomials and Pade approximants. A function based on the Nernst equation that includes a term accounting for nonideal interactions between lithium ions and the cathode host material, such as the Redlich-Kister relationship, also may be used to predict discharge behavior. (author)

Operation and Applications of the Boron Cathodic Arc Ion Source

International Nuclear Information System (INIS)

Williams, J. M.; Freeman, J. H.; Klepper, C. C.; Chivers, D. J.; Hazelton, R. C.

2008-01-01

The boron cathodic arc ion source has been developed with a view to several applications, particularly the problem of shallow junction doping in semiconductors. Research has included not only development and operation of the boron cathode, but other cathode materials as well. Applications have included a large deposition directed toward development of a neutron detector and another deposition for an orthopedic coating, as well as the shallow ion implantation function. Operational experience is described and information pertinent to commercial operation, extracted from these experiments, is presented.

Joule heat generation in thermionic cathodes of high-pressure arc discharges

Energy Technology Data Exchange (ETDEWEB)

Benilov, M. S.; Cunha, M. D. [Departamento de Fisica, CCCEE, Universidade da Madeira, Largo do Municipio, 9000 Funchal (Portugal)

2013-02-14

The nonlinear surface heating model of plasma-cathode interaction in high-pressure arcs is extended to take into account the Joule effect inside the cathode body. Calculation results are given for different modes of current transfer to tungsten cathodes of different configurations in argon plasmas of atmospheric or higher pressures. Special attention is paid to analysis of energy balances of the cathode and the near-cathode plasma layer. In all the cases, the variation of potential inside the cathode is much smaller than the near-cathode voltage drop. However, this variation can be comparable to the volt equivalent of the energy flux from the plasma to the cathode and then the Joule effect is essential. Such is the case of the diffuse and mixed modes on rod cathodes at high currents, where the Joule heating causes a dramatic change of thermal and electrical regimes of the cathode. The Joule heating has virtually no effect over characteristics of spots on rod and infinite planar cathodes.

On peculiarities of using cathodes on tungsten-rhenium alloy base in vacuum luminescent low-voltage indicators

International Nuclear Information System (INIS)

Fel'dman, F.S.; Gorfinkel', B.I.; Ustinova, V.G.; Gutkina, G.I.

1975-01-01

A comparative study of cathodes prepared from W wire (VAI-AP) and from a W-Re alloy (VAR5) with a cathodoluminophor of ZnO-Zn and carbonate coatings indicates that the initial values of the anode current and the luminophor brightness are almost the same for both cathodes. The stability of the anode current and of the luminescent properties of the luminophor, however, were much better for the VAR5 cathode with a coating of ternary, fine-grained carbonate. This is attributed to the difference in the amount of active material sputtered on the cathode luminophor. The temperature of the alloy cathode is 30-40deg lower than that of the W cathode, which creates favorable conditions for decreasing the sputtering from the cathode. The operational lifetime of the cathode is also increased for this alloy

A pacemaker powered by an implantable biofuel cell operating under conditions mimicking the human blood circulatory system--battery not included.

Science.gov (United States)

Southcott, Mark; MacVittie, Kevin; Halámek, Jan; Halámková, Lenka; Jemison, William D; Lobel, Robert; Katz, Evgeny

2013-05-07

Biocatalytic electrodes made of buckypaper were modified with PQQ-dependent glucose dehydrogenase on the anode and with laccase on the cathode and were assembled in a flow biofuel cell filled with serum solution mimicking the human blood circulatory system. The biofuel cell generated an open circuitry voltage, Voc, of ca. 470 mV and a short circuitry current, Isc, of ca. 5 mA (a current density of 0.83 mA cm(-2)). The power generated by the implantable biofuel cell was used to activate a pacemaker connected to the cell via a charge pump and a DC-DC converter interface circuit to adjust the voltage produced by the biofuel cell to the value required by the pacemaker. The voltage-current dependencies were analyzed for the biofuel cell connected to an Ohmic load and to the electronic loads composed of the interface circuit, or the power converter, and the pacemaker to study their operation. The correct pacemaker operation was confirmed using a medical device - an implantable loop recorder. Sustainable operation of the pacemaker was achieved with the system closely mimicking human physiological conditions using a single biofuel cell. This first demonstration of the pacemaker activated by the physiologically produced electrical energy shows promise for future electronic implantable medical devices powered by electricity harvested from the human body.

Electrochemical performances of LiNi1−xMnxPO4 (x = 0.05–0.2) olivine cathode materials for high voltage rechargeable lithium ion batteries

DEFF Research Database (Denmark)

Karthikprabhu, S.; Karuppasamy, K.; Vikraman, Dhanasekaran

2018-01-01

This study demonstrated to synthesis of carbon-free lithium nickel phosphate (LiNiPO4) and its analogue of manganese doped LiNi1−xMnxPO4 (x = 0.05–0.2) cathode materials by a facile polyol method and their suitability for use in high voltage lithium ion batteries (LIBs). The physicochemical...

Pierce-type electron gun with a large concave LaB6 cathode

International Nuclear Information System (INIS)

Shintake, Tumoru; Ohba, Kunio; Matoba, Masaru; Katase, Akira

1981-01-01

A Pierce-type electron gun with a concave cathode of lanthanum hexaboride (LaB 6 ) 30 mm in diameter is described. At an accelerating voltage of 3 kV and a cathode temperature of 1340 0 C, a focussed electron beam of DC 300 mA was obtained. (author)

Diode with plasma cathode on the basis of a sliding discharge

International Nuclear Information System (INIS)

Korenev, S.A.

1982-01-01

The operative regime of a diode with plasma cathode on the basis of a discharge sliding over the surface of dielectric without an additional switching - on discharge generator at the glance of capacity couplings of anode and cathode assemblies is described. It is experimentally shown that at the voltage at the diode of about 150-300 kV electron beams with the 400-1000 A/cm current density can be formed. The velocity of cathode plasma motion in the direction of anode for different materials of dielctric insertion in a cathode assembly amounts to (1.5-10)x10 5 cm/s

Suppressed oxygen extraction and degradation of LiNi_xMn_yCo_zO₂ cathodes at high charge cut-off voltages

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jianming; Yan, Pengfei; Zhang, Jiandong; Engelhard, Mark H.; Zhu, Zihua; Polzin, Bryant J.; Trask, Steve; Xiao, Jie; Wang, Chongmin; Zhang, Jiguang

2017-09-01

The capacity degradation mechanism in lithium nickel–manganese–cobalt oxide (NMC) cathodes (LiNi_1/3Mn_1/3Co_1/3O₂ (NMC₃₃₃) and LiNi_0.4Mn_0.4Co_0.2O₂ (NMC₄₄₂)) during high-voltage (cut-off of 4.8 V) operation has been investigated. In contrast to NMC₄₄₂, NMC₃₃₃ exhibits rapid structural changes including severe micro-crack formation and phase transformation from a layered to a disordered rock-salt structure, as well as interfacial degradation during high-voltage cycling, leading to a rapid increase of the electrode resistance and fast capacity decline. The fundamental reason behind the poor structural and interfacial stability of NMC₃₃₃ was found to be correlated to its high Co content and the significant overlap between the Co^3+/4+ t_2g and O^2- 2p bands, resulting in oxygen removal and consequent structural changes at high voltages. In addition, oxidation of the electrolyte solvents by the extracted oxygen species generates acidic species, which then attack the electrode surface and form highly resistive LiF. These findings highlight that both the structural and interfacial stability should be taken into account when tailoring cathode materials for high voltage battery systems.

Drift chamber tracking with a VLSI neural network

International Nuclear Information System (INIS)

Lindsey, C.S.; Denby, B.; Haggerty, H.; Johns, K.

1992-10-01

We have tested a commercial analog VLSI neural network chip for finding in real time the intercept and slope of charged particles traversing a drift chamber. Voltages proportional to the drift times were input to the Intel ETANN chip and the outputs were recorded and later compared off line to conventional track fits. We will discuss the chamber and test setup, the chip specifications, and results of recent tests. We'll briefly discuss possible applications in high energy physics detector triggers

STUDY OF THE IMPACT OF THERMAL DRIFT ON RELIABILITY OF PRESSURE SENSORS

Directory of Open Access Journals (Sweden)

ABDELAZIZ BEDDIAF

2017-10-01

Full Text Available Piezoresistive pressure sensors, using a Wheatstone bridge with the piezoresistors, are typically supplied with a voltage ranging from 3 to 10 V involve thermal drift caused by Joule heating. In this paper, an accurate numerical model for optimization and predicting the thermal drift in piezoresistive pressure sensors due to the electric heater in its piezoresistors is adopted. In this case, by using the solution of 2D heat transfer equation considering Joule heating in Cartesian coordinates for the transient regime, we determine how the temperature affects the sensor when the supply voltage is applied. For this, the elevation of temperature due to the Joule heating has been calculated for various values of supply voltage and for several operating times of the sensor; by varying different geometrical parameters. Otherwise, the variation of the coefficient 44 in p-Si and pressure sensitivity as a function of the applied potential, as well as, for various times, for different dimensions of the device, have been also established. It is observed that the electrical heating leads to an important temperature rise in the piezoresistor. Consequently, it causes drift in the pressure sensitivity of the sensor upon application of a voltage. Finally, this work allows us to evaluate the reliability of sensors. Also, it permits to predict their behaviour against temperature due to the application of a voltage of a bridge and to minimize this effect by optimizing the geometrical parameters of the sensor and by reducing the supply voltage.

Base metal thermocouples drift rate dependence from thermoelement diameter

Science.gov (United States)

Pavlasek, P.; Duris, S.; Palencar, R.

2015-02-01

Temperature measurements are one of the key factors in many industrial applications that directly affect the quality, effectiveness and safety of manufacturing processes. In many industrial applications these temperature measurements are realized by thermocouples. Accuracy of thermocouples directly affects the quality of the final product of manufacturing and their durability determines the safety margins required. One of the significant effects that affect the precision of the thermocouples is short and long term stability of their voltage output. This stability issue occurs in every type of thermocouples and is caused by multiple factors. In general these factors affect the Seebeck coefficient which is a material constant, which determines the level of generated voltage when exposed to a temperature gradient. Changes of this constant result in the change of the thermocouples voltage output thus indicated temperature which can result in production quality issues, safety and health hazards. These alternations can be caused by physical and chemical changes within the thermocouple lead material. Modification of this material constant can be of temporary nature or permanent. This paper concentrates on the permanent, or irreversible changes of the Seebeck coefficient that occur in commonly used swaged MIMS Type N thermocouples. These permanent changes can be seen as systematic change of the EMF of the thermocouple when it is exposed to a high temperature over a period of time. This change of EMF by time is commonly known as the drift of the thermocouple. This work deals with the time instability of thermocouples EMF at temperatures above 1200 °C. Instability of the output voltage was taken into relation with the lead diameter of the tested thermocouples. This paper concentrates in detail on the change of voltage output of thermocouples of different diameters which were tested at high temperatures for the overall period of more than 210 hours. The gather data from this

Base metal thermocouples drift rate dependence from thermoelement diameter

International Nuclear Information System (INIS)

Pavlasek, P; Duris, S; Palencar, R

2015-01-01

Temperature measurements are one of the key factors in many industrial applications that directly affect the quality, effectiveness and safety of manufacturing processes. In many industrial applications these temperature measurements are realized by thermocouples. Accuracy of thermocouples directly affects the quality of the final product of manufacturing and their durability determines the safety margins required. One of the significant effects that affect the precision of the thermocouples is short and long term stability of their voltage output. This stability issue occurs in every type of thermocouples and is caused by multiple factors. In general these factors affect the Seebeck coefficient which is a material constant, which determines the level of generated voltage when exposed to a temperature gradient. Changes of this constant result in the change of the thermocouples voltage output thus indicated temperature which can result in production quality issues, safety and health hazards. These alternations can be caused by physical and chemical changes within the thermocouple lead material. Modification of this material constant can be of temporary nature or permanent. This paper concentrates on the permanent, or irreversible changes of the Seebeck coefficient that occur in commonly used swaged MIMS Type N thermocouples. These permanent changes can be seen as systematic change of the EMF of the thermocouple when it is exposed to a high temperature over a period of time. This change of EMF by time is commonly known as the drift of the thermocouple. This work deals with the time instability of thermocouples EMF at temperatures above 1200 °C. Instability of the output voltage was taken into relation with the lead diameter of the tested thermocouples. This paper concentrates in detail on the change of voltage output of thermocouples of different diameters which were tested at high temperatures for the overall period of more than 210 hours. The gather data from this

Design of a lead-glass drift calorimeter with MWPC detection

International Nuclear Information System (INIS)

Perez-Mendez, V.; del Guerra, A.; Mulera, T.; Hirayama, H.; Nelson, W.R.

1983-02-01

A drift collection calorimeter having a combined radiator and field-shaping structure made of lead-glass tubing is described. A high-resistance metallic layer is formed by reduction of the lead oxide at the surface of the glass and forms a continuous voltage divider for drift-field shaping. The energy resolution of such a calorimeter is modeled, for several configurations, by the Monte Carlo technique

Some characteristics of the long straw drift tubes

International Nuclear Information System (INIS)

Bychkov, V.N.; Kekelidze, G.D.; Ivanov, A.B.; Livinskij, V.V.; Lobastov, S.P.; Lysan, V.M.; Mishin, S.V.; Peshekhonov, V.D.

1998-01-01

This article represents the construction and testing of the long straw drift tubes of different types. The diameter and the length of each straw were equal to 15 mm and 3 m respectively. The cathode resistance of these straws has a small value, i.e. about 100 Ohm/m. Thus, they do not have a large attenuation length. Installation of the spacers reduces the effective straw length by 0.5 % per meter, at least

Hollow Cathode Studies for the Next Generation Ion Engines in JAXA

Science.gov (United States)

Ohkawa, Yasushi; Hayakawa, Yukio; Yoshida, Hideki; Miyazaki, Katsuhiro; Kitamura, Shoji; Kajiwara, Kenichi

The current status of experimental studies of hollow cathodes for the next-generation ion engines in the Aerospace Research and Development Directorate, JAXA is described. One of the topics on the hollow cathode studies is a life test of a discharge cathode. The keeper disk, orifice plate, and cathode tube of this discharge cathode are made of "high density graphite," which possesses much higher tolerance to ion impingement compared with conventional metal materials. The life test had started in March 2006 and the cumulative operation time reached 15,600 hours in April 2008. No severe degradation has been found both in the operation voltages and electrodes so far, and the test is favorably in progress. In addition to the life test of the discharge cathode, some experiments for design optimization of neutralizer cathodes have been performed. A life test of the neutralizer cathode is being started in June 2008.

Hollow Cathode Assembly Development for the HERMeS Hall Thruster

Science.gov (United States)

Sarver-Verhey, Timothy R.; Kamhawi, Hani; Goebel, Dan M.; Polk, James E.; Peterson, Peter Y.; Robinson, Dale A.

2016-01-01

To support the operation of the HERMeS 12.5 kW Hall Thruster for NASA's Asteroid Redirect Robotic Mission, hollow cathodes using emitters based on barium oxide impregnate and lanthanum hexaboride are being evaluated through wear-testing, performance characterization, plasma modeling, and review of integration requirements. This presentation will present the development approach used to assess the cathode emitter options. A 2,000-hour wear-test of development model Barium Oxide (BaO) hollow cathode is being performed as part of the development plan. Specifically this test is to identify potential impacts cathode emitter life during operation in the HERMeS thruster. The cathode was operated with a magnetic field-equipped anode that simulates the HERMeS hall thruster operating environment. Cathode discharge performance has been stable with the device accumulating 743 hours at the time of this report. Observed voltage changes are attributed to keeper surface condition changes during testing. Cathode behavior during characterization sweeps exhibited stable behavior, including cathode temperature. The details of the cathode assembly operation of the wear-test will be presented.

A method for measuring the electron drift velocity in working gas using a Frisch-grid ionization chamber

Energy Technology Data Exchange (ETDEWEB)

Bai, Huaiyong; Wang, Zhimin; Zhang, Luyu; Chen, Jinxiang; Zhang, Guohui, E-mail: guohuizhang@pku.edu.cn

2016-12-21

A method for measuring the electron drift velocity in working gas is proposed. Based on the cathode and the anode signal waveforms of the Frisch-grid ionization chamber, the electron drift velocity is extracted. With this method, the electron drift velocities in Ar + 10% CH{sub 4}, Ar + 3.5% CO{sub 2} and Kr + 2.7% CO{sub 2} gases have been measured and the results are compared with the existing measurements and the simulating results. Using this method, the electron drift velocity can be monitored throughout the experiment of charged particle without bothering the measurement of other parameters, such as the energy and orientation.

Development of spark cathode E-guns. Draft final reprt, Phase I, July--October 1978

International Nuclear Information System (INIS)

Loda, G.; Lindstrand, R.

1979-01-01

A 12 sided spark cathode is designed and constructed to replace the bladed, cold cathode structure in the electron gun of the Los Alamos Scientific Laboratory Antares prototype power amplifier. Design work includes computer modeling and full scale low voltage modeling. Life testing to 100,000 pulses is documented. The spark cathode offers precise control of emission site location and a high reliability

Copper sulfates as cathode materials for Li batteries

Science.gov (United States)

Schwieger, Jonathan N.; Kraytsberg, Alexander; Ein-Eli, Yair

As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO 4) 2- possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO 4·5H 2O) with respect to lithium insertion via a two-electron displacement reaction entailing the extrusion of metallic copper at a dual voltage of 3.2 V and 2.7 V followed by its reversible insertion at 3.5 V and 3.8 V. At this stage, cyclability was still shown to be limited due to the irreversible degradation to a monohydrate structure owing to constitutional water loss.

4H-SiC vertical double implanted metal–oxide–semiconductor drift region—energy aspects of its formation and analysis

International Nuclear Information System (INIS)

Alkhem, Abdel; Šašić, Rajko M; Ostojić, Stanko M; Lukić, Petar M

2014-01-01

A conventional vertical double implanted metal–oxide–semiconductor structure contains two n +  regions beneath two symmetrically posed source biases. These n +  regions are surrounded by a p-doped layer, which itself has an abrupt transition to the vertical drift region. Owing to the existence of these p-layers, the ‘drift’ region has varying cross sections: it is reduced going upward from the bottom (drain bias) to the top. Such a drift region is usually described either by a three piecewise model, which begins with constant cross section that at some point starts narrowing until at some other point it becomes reduced to the region between two p-regions, or by a two piecewise model, whose narrowing region starts right above the drain bias and finishes in the manner described before. The crucial geometrical parameters of the flow profile in the drift region, such as the slope of the cross-section reducing region and the length of the narrowest (accumulation) region are widely used but never determined, or even estimated, in the available literature. In this paper, the least-action principle has been utilized successfully in order to determine the exact values of these parameters and so make the existing models closed. The proof has also been provided, which shows that the three piecewise model described the flow profile better than a two piecewise model more adequately as long as it was permitted by the length of the entire drift region (the energy necessary to restore the specific value of drain current is smaller than for the three piecewise model). The two piecewise model can be accepted in practical calculations only for higher values of drain current far from a triode regime. (paper)

A Drift Chamber to Measure Charged Particles at COMPASS-II

Science.gov (United States)

Heitz, Robert; Compass Collaboration

2013-10-01

A new drift chamber (DC05) will be constructed to replace two tracking detector stations based on straw tubes, ST02 and ST03 in the COMPASS spectrometer. DC05 uses the designs from DC04, a previous drift chamber designed at CEA-Saclay, France, but adds the addition of more wires for improved acceptance. In addition to more wires DC05 will also change its front end electronics using a new pre-amplifier-discriminator chip (CMAD). DC05 consists of 8 layers of anode planes and 21 layers of G-10 material frames carrying cathode planes and gas windows. The wires are orientated with two layers in the vertical x-direction, two layers in the horizontal y-direction, two layers offset +10 deg of the vertical x-direction, and two layers offset -10 deg of the vertical x-direction. The wires in parallel directions are offset half a pitch to resolve left-right ambiguities. The purpose for different wire orientations is to reconstruct the 3D space particle trajectory to fit a particle track. Each layer of wires is covered on the top and bottom by a cathode plane of carbon coated mylar. All these layers are sandwiched between two steel stiffening frames for support and noise reduction. A future drift chamber, DC06, is also being designed based off of DC05. Research funded by NSF-PHY-12-05-671 Medium Energy Nuclear Physics.

High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

Energy Technology Data Exchange (ETDEWEB)

Kepler, Keith [Farasis Energy Inc; Slater, Michael [Farasis Energy Inc

2018-03-14

This Li-ion cell technology development project had three objectives: to develop advanced electrode materials and cell components to enable stable high-voltage operation; to design and demonstrate a Li-ion cell using these materials that meets the PHEV40 performance targets; and to design and demonstrate a Li-ion cell using these materials that meets the EV performance targets. The major challenge to creating stable high energy cells with long cycle life is system integration. Although materials that can give high energy cells are known, stabilizing them towards long-term cycling in the presence of other novel cell components is a major challenge. The major technical barriers addressed by this work include low cathode specific energy, poor electrolyte stability during high voltage operation, and insufficient capacity retention during deep discharge for Si-containing anodes. Through the course of this project, Farasis was able to improve capacity retention of NCM materials for 4.4+ V operation, through both surface treatment and bulk-doping approaches. Other material advances include increased rate capability and of HE-NCM materials through novel synthesis approach, doubling the relative capacity at 1C over materials synthesized using standard methods. Silicon active materials proved challenging throughout the project and ultimately were the limiting factor in the energy density vs. cycle life trade off. By avoiding silicon anodes for the lower energy PHEV design, we manufactured cells with intermediate energy density and long cycle life under high voltage operation for PHEV applications. Cells with high energy density for EV applications were manufactured targeting a 300 Wh/kg design and were able to achieve > 200 cycles.

Studies on pulsed hollow cathode capillary discharges

Energy Technology Data Exchange (ETDEWEB)

Choi, P; Dumitrescu-Zoita, C; Larour, J; Rous, J [Ecole Polytechnique, 91 - Palaiseau (France). Lab. de Physique des Milieux Ionises; Favre, M; Moreno, J; Chuaqui, H; Wyndham, E [Pontificia Univ. Catolica de Chile, Santiago (Chile). Facultad de Fisica; Zambra, M [Comision Chilena de Energia Nuclear, Santiago (Chile); Wong, C S [Univ. of Malaya, Kuala Lumpur (Malaysia). Plasma Research Lab

1997-12-31

Preliminary results on radiation characteristics of pulsed hollow cathode capillary discharges are presented. The device combines the on axis electron beam assisted ionization capabilities of the transient hollow cathode discharge with a novel high voltage low inductance geometrical design, which integrates the local energy storage into the electrode system. A nanosecond regime high temperature plasma is produced in a long, high aspect ratio capillary, with light emission in the UV to XUV region. The discharge is operated from near vacuum to pressure in the 1000 mTorr range. (author). 2 figs., 7 refs.

Electrochemical analysis of separators used in single-chamber, air-cathode microbial fuel cells

KAUST Repository

Wei, Bin; Tokash, Justin C.; Zhang, Fang; Kim, Younggy; Logan, Bruce E.

2013-01-01

Polarization, solution-separator, charge transfer, and diffusion resistances of clean and used separator electrode assemblies were examined in microbial fuel cells using current-voltage curves and electrochemical impedance spectroscopy (EIS). Current-voltage curves showed the total resistance was reduced at low cathode potentials. EIS results revealed that at a set cathode potential of 0.3 V diffusion resistance was predominant, and it substantially increased when adding separators. However, at a lower cathode potential of 0.1 V all resistances showed only slight differences with and without separators. Used separator electrode assemblies with biofilms had increased charge transfer and diffusion resistances (0.1 V) when one separator was used; however, charge transfer resistance increased, and diffusion resistance did not appreciably change with four separators. Adding a plastic mesh to compress the separators improved maximum power densities. These results show the importance of pressing separators against the cathode, and the adverse impacts of biofilm formation on electrochemical performance. © 2012 Elsevier Ltd. All Rights Reserved.

Electrochemical analysis of separators used in single-chamber, air-cathode microbial fuel cells

KAUST Repository

Wei, Bin

2013-02-01

Polarization, solution-separator, charge transfer, and diffusion resistances of clean and used separator electrode assemblies were examined in microbial fuel cells using current-voltage curves and electrochemical impedance spectroscopy (EIS). Current-voltage curves showed the total resistance was reduced at low cathode potentials. EIS results revealed that at a set cathode potential of 0.3 V diffusion resistance was predominant, and it substantially increased when adding separators. However, at a lower cathode potential of 0.1 V all resistances showed only slight differences with and without separators. Used separator electrode assemblies with biofilms had increased charge transfer and diffusion resistances (0.1 V) when one separator was used; however, charge transfer resistance increased, and diffusion resistance did not appreciably change with four separators. Adding a plastic mesh to compress the separators improved maximum power densities. These results show the importance of pressing separators against the cathode, and the adverse impacts of biofilm formation on electrochemical performance. © 2012 Elsevier Ltd. All Rights Reserved.

Ionization Waves in a Fast, Hollow-Cathode-Assisted Capillary Discharge

International Nuclear Information System (INIS)

Rutkevich, I.; Mond, M.; Kaufman, Y.; Choi, P.; Favre, M.

1999-01-01

The initial, low-current stage of the evolution of a soft x-ray emitting, hollow-cathode-assisted capillary discharge initiated by a steep high-voltage pulse is investigated. The capillary is surrounded by a shield having the cathode potential. The mean electric field E of the order of 10 kV/cm and the low gas pressure (P<1Torr) provide conditions for extensive electron runaway. This is taken into account in the formulation of the theoretical approach by retaining the inertial terms in the momentum equation for the electrons. In addition, the ionization rate is calculated by considering the cross section for ionization by high-energy electrons. The two-dimensional system of the basic equations is reduced to a system of one-dimensional equations for the axial distributions of the physical quantities by introducing appropriate radial profiles of the electric potential, and the electron gas parameters and satisfying the electrodynamic boundary conditions at the capillary wall and at the shield. The resulting system of equations admits solutions in the form of stationary ionization waves transferring the anode potential to the cathode end. Numerical calculations of such solutions for argon show that the wave velocity V increases with the gas pressure P and with the density of initial electron beam ejected from the cathode hole ahead of the ionization front, while the dependence of V on the applied voltage is weak. At the instant when the virtual anode reaches the cathode hole, the plasma in the capillary is not yet fully ionized. The traverse time of the ionization wave along the capillary calculated for various gas pressures is in reasonable agreement with experimentally registered time delay for a high-current stage resulting in voltage collapse and soft x-ray emission

Voltage breakdown on niobium and copper surfaces

International Nuclear Information System (INIS)

Werner, G.R.; Padamsee, H.; Betzwieser, J.C.; Liu, Y.G.; Rubin, K.H.R.; Shipman, J.E.; Ying, L.T.

2003-01-01

Experiments have shown that voltage breakdown in superconducting niobium RF cavities is in many ways similar to voltage breakdown on niobium cathodes in DC voltage gaps; most striking are the distinctive starburst patterns and craters that mark the site of voltage breakdown in both superconducting cavities and DC vacuum gaps. Therefore, we can learn much about RF breakdown from simpler, faster DC experiments. We have direct evidence, in the form of before'' and ''after'' pictures, that breakdown events caused by high surface electric fields occur with high probability at contaminant particles on surfaces. Although the pre-breakdown behavior (field emission) seems to depend mostly on the contaminant particles present and little on the substrate, the breakdown event itself is greatly affected by the substrate-niobium, heavily oxidized niobium, electropolished copper, and diamond-machined copper cathodes lead to different kinds of breakdown events. By studying DC voltage breakdown we hope to learn more details about the processes involved in the transition from field emission to catastrophic arcing and the cratering of the surface; as well as learning how to prevent breakdown, we would like to learn how to cause breakdown, which could be important when ''processing'' cavities to reduce field emission. (author)

Electron Emission And Beam Generation Using Ferroelectric Cathodes (electron Beam Generation, Lead Lanthanum Zicronate Titanate, High Power Traveling Wave Tube Amplfier)

CERN Document Server

Flechtner, D D

1999-01-01

In 1989, researchers at CERN published the discovery of significant electron emission (1– 100 A/cm2) from Lead- Lanthanum-Zirconate-Titanate (PLZT). The publication of these results led to international interest in ferroelectric cathodes studies for use in pulsed power devices. At Cornell University in 1991, experiments with Lead-Zirconate-Titanate (PZT) compositions were begun to study the feasibility of using this ferroelectric material as a cathode in the electron gun section of High Power Traveling Wave Tube Amplifier Experiments. Current-voltage characteristics were documented for diode voltages ranging from 50– 500,000 V with anode cathode gaps of.5– 6 cm. A linear current-voltage relation was found for voltages less than 50 kV. For diode voltages ≥ 200 kV, a typical Child-Langmuir V3/2 dependence was observed...

Oxide cathodes produced by plasma deposition

International Nuclear Information System (INIS)

Scheitrum, G.; Caryotakis, G.; Pi, T.; Umstattd, R.; Brown, I.; Montiero, O.

1997-01-01

These are two distinct applications for high-current-density, long-life thermionic cathodes. The first application is as a substitute for explosive emission cathodes used in high-power microwave (HPM) devices being developed for Air Force programs. The second application is in SLAC's X-band klystrons for the Next Linear Collider (NLC). SLAC, UCD, and LBL are developing a plasma deposition process that eliminates the problems with binders, carbonate reduction, peeling, and porosity. The emission layer is deposited using plasma deposition of metallic barium in vacuum with an oxygen background gas. An applied bias voltage drives the oxide plasma into the nickel surface. Since the oxide is deposited directly, it does not have problems with poisoning from a hydrocarbon binder. The density of the oxide layer is increased from the 40--50% for standard oxide cathodes to nearly 100% for plasma deposition

The LMF triaxial MITL voltage adder system

International Nuclear Information System (INIS)

Mazarakis, M.G.; Smith, D.L.; Bennett, L.F.; Lockner, T.R.; Olson, R.E.; Poukey, J.W.

1992-01-01

The light-ion microfusion driver design consists of multiple accelerating modules fired in coincidence and sequentially in order to provide the desired ion energy, power pulse shape and energy deposition uniformity on an Inertial Confinement Fusion (ICF) target. The basic energy source is a number of Marx generators which, through the appropriate pulse power conditioning, provide the necessary voltage pulse wave form to the accelerating gaps or feeds of each module. The cavity gaps are inductively isolated, and the voltage addition occurs in the center conductor of the voltage adder which is the positive electrode while the electrons of the sheath flow closer to the outer cylinder which is the magnetically insulated cathode electrode. Each module powers a separate two-stage extraction diode which provides a low divergence ion beam. In order to provide the two separate voltage pulses required by the diode, a triaxial adder system is designed for each module. The voltage addition occurs in two separate MITLs. The center hollow cylinder (anode) of the second MITL also serves as the outer cathode electrode for the extension of the first voltage adder MITL. The voltage of the second stage is about twice that of the first stage. The cavities are connected in series to form the outer cylinder of each module. The accelerating modules are positioned radially in a symmetrical way around the fusion chamber. A preliminary conceptual design of the LMF modules with emphasis on the voltage adders and extension MITLs will be presented and discussed

Accurate computer simulation of a drift chamber

International Nuclear Information System (INIS)

Killian, T.J.

1980-01-01

A general purpose program for drift chamber studies is described. First the capacitance matrix is calculated using a Green's function technique. The matrix is used in a linear-least-squares fit to choose optimal operating voltages. Next the electric field is computed, and given knowledge of gas parameters and magnetic field environment, a family of electron trajectories is determined. These are finally used to make drift distance vs time curves which may be used directly by a track reconstruction program. Results are compared with data obtained from the cylindrical chamber in the Axial Field Magnet experiment at the CERN ISR

Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

2015-02-24

Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

Improvement in high-voltage and high rate cycling performance of nickel-rich layered cathode materials via facile chemical vapor deposition with methane

International Nuclear Information System (INIS)

Hyuk Son, In; Park, Kwangjin; Hwan Park, Jong

2017-01-01

Nickel-rich layered-oxide materials are considered promising candidates for application as cathode material in high-energy lithium ion batteries. However, their cycling performance at high voltages and rate conditions require further improvement for the purpose of commercialization. Here, we report on the facile surface modification of nickel-rich layered oxide by chemical vapor deposition with methane which yields a conductive and protective artificial solid electrolyte interphase layer consisting of amorphous carbon, alkyl lithium carbonate, and lithium carbonate. We examine the mechanism of the protective layer formation and structural deformation of the nickel-rich layered oxide during chemical vapor deposition with methane. Via optimizing the reaction conditions, we improve the electrical conductivity as well as the interfacial stability of the nickel-rich layered oxide without inducing structural deformation. The surface-modified nickel-rich layered oxide exhibits an improved performance due to the resulting enhanced rate capability, high initial efficiency, and long cycle life at high voltage (>4.5 V).

Characterization of a cold cathode Penning ion source for the implantation of noble gases beneath 2D monolayers on metals: Ions and neutrals

Energy Technology Data Exchange (ETDEWEB)

Cun, Huanyao, E-mail: hycun1@physik.uzh.ch, E-mail: greber@physik.uzh.ch; Spescha, Annina; Schuler, Adrian; Hengsberger, Matthias; Osterwalder, Jürg; Greber, Thomas, E-mail: hycun1@physik.uzh.ch, E-mail: greber@physik.uzh.ch [Physik-Institut, Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich (Switzerland)

2016-03-15

Argon ion kinetic energy spectra at different discharge voltages (between 480 and 600 V) of a commercial cold cathode ion source IQP10/63 are reported. The high kinetic energy cut-off depends on the discharge voltage and the corresponding plasma potential due to excess positive charges which is found to be about 136 V. Exposure of single layer hexagonal boron nitride on rhodium to the beam of the ion source leads to the formation of nanotents, i.e., stable atomic protrusions. A positive bias voltage is applied to the target sample to block the positive ions produced by the ion source. However, application of a positive bias potential (800 eV), which is higher than the kinetic energy cut-off, still allows the formation of nanotents and its observation with scanning tunneling microscopy. This indicates that the ion source also produces neutral atoms with kinetic energies higher than the penetration threshold across a single layer of hexagonal boron nitride.

Survey of high-voltage pulse technology suitable for large-scale plasma source ion implantation processes

International Nuclear Information System (INIS)

Reass, W.A.

1994-01-01

Many new plasma processes ideas are finding their way from the research lab to the manufacturing plant floor. These require high voltage (HV) pulse power equipment, which must be optimized for application, system efficiency, and reliability. Although no single HV pulse technology is suitable for all plasma processes, various classes of high voltage pulsers may offer a greater versatility and economy to the manufacturer. Technology developed for existing radar and particle accelerator modulator power systems can be utilized to develop a modern large scale plasma source ion implantation (PSII) system. The HV pulse networks can be broadly defined by two classes of systems, those that generate the voltage directly, and those that use some type of pulse forming network and step-up transformer. This article will examine these HV pulse technologies and discuss their applicability to the specific PSII process. Typical systems that will be reviewed will include high power solid state, hard tube systems such as crossed-field ''hollow beam'' switch tubes and planar tetrodes, and ''soft'' tube systems with crossatrons and thyratrons. Results will be tabulated and suggestions provided for a particular PSII process

High-current and low acceleration voltage arsenic ion implanted polysilicon-gate and source-drain electrode Si mos transistor

International Nuclear Information System (INIS)

Saito, Yasuyuki; Sugimura, Yoshiro; Sugihara, Michiyuki

1993-01-01

The fabrication process of high current arsenic (As) ion implanted polysilicon (Si) gate and source drain (SD) electrode Si n-channel metal oxide-semiconductor field effect transistor (MOSFET) was examined. Poly Si film n-type doping was performed by using high current (typical current: 2mA) and relatively low acceleration voltage (40keV) As ion implantation technique (Lintott series 3). It was observed that high dose As implanted poly Si films as is show refractoriness against radical fluorine excited by microwave. Using GCA MANN4800 (m/c ID No.2, resist: OFPR) mask pattern printing technique, the high current As ion implantation technique and radical fluorine gas phase etching (Chemical dry etching: CDE) technique, the n-channel Poly Si gate (ρs = ≅100Ω/□) enhancement MQSFETs(ρs source drain = ≅50Ω/□, SiO 2 gate=380 angstrom) with off-leak-less were obtained on 3 inch Czochralski grown 2Ωcm boron doped p type wafers (Osaka titanium). By the same process, a 8 bit single chip μ-processor with 26MHz full operation was performed

Temperature Stabilized Characterization of High Voltage Power Supplies

CERN Document Server

Krarup, Ole

2017-01-01

High precision measurements of the masses of nuclear ions in the ISOLTRAP experiment relies on an MR-ToF. A major source of noise and drift is the instability of the high voltage power supplies employed. Electrical noise and temperature changes can broaden peaks in time-of-flight spectra and shift the position of peaks between runs. In this report we investigate how the noise and drift of high-voltage power supplies can be characterized. Results indicate that analog power supplies generally have better relative stability than digitally controlled ones, and that the high temperature coefficients of all power supplies merit efforts to stabilize them.

Fabrication and description of a cold cathode electron gun

International Nuclear Information System (INIS)

Sari, A.H.; Ghorannevis, M.; Hantehzadeh, M.R.; Yousefi, M.R.

2003-01-01

In this study the structure and schematic configuration of a cold cathode electron gun has been shown, which use obstructed discharge for electron producing. This type of discharge and mechanism of secondary electron emission by ions and fast neutral interaction have been described. The experiment starts in pressure of 1*10 -3 torr, in existence of helium gas. A negative DC voltage apply to a concave cathode up to -20 k V which determine electron energy

Nasicon-Type Surface Functional Modification in Core-Shell LiNi0.5Mn0.3Co0.2O2@NaTi2(PO4)3 Cathode Enhances Its High-Voltage Cycling Stability and Rate Capacity toward Li-Ion Batteries.

Science.gov (United States)

Liang, Longwei; Sun, Xuan; Wu, Chen; Hou, Linrui; Sun, Jinfeng; Zhang, Xiaogang; Yuan, Changzhou

2018-02-14

Surface modifications are established well as efficient methodologies to enhance comprehensive Li-storage behaviors of the cathodes and play a significant role in cutting edge innovations toward lithium-ion batteries (LIBs). Herein, we first logically devised a pilot-scale coating strategy to integrate solid-state electrolyte NaTi 2 (PO 4 ) 3 (NTP) and layered LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC) for smart construction of core-shell NMC@NTP cathodes. The Nasicon-type NTP nanoshell with exceptional ion conductivity effectively suppressed gradual encroachment and/or loss of electroactive NMC, guaranteed stable phase interfaces, and meanwhile rendered small sur-/interfacial electron/ion-diffusion resistance. By benefiting from immanently promoting contributions of the nano-NTP coating, the as-fabricated core-shell NMC@NTP architectures were competitively endowed with superior high-voltage cyclic stabilities and rate capacities within larger electrochemical window from 3.0 to 4.6 V when utilized as advanced cathodes for advanced LIBs. More meaningfully, the appealing electrode design concept proposed here will exert significant impact upon further constructing other high-voltage Ni-based cathodes for high-energy/power LIBs.

Development of multi-pixel x-ray source using oxide-coated cathodes.

Science.gov (United States)

Kandlakunta, Praneeth; Pham, Richard; Khan, Rao; Zhang, Tiezhi

2017-07-07

Multiple pixel x-ray sources facilitate new designs of imaging modalities that may result in faster imaging speed, improved image quality, and more compact geometry. We are developing a high-brightness multiple-pixel thermionic emission x-ray (MPTEX) source based on oxide-coated cathodes. Oxide cathodes have high emission efficiency and, thereby, produce high emission current density at low temperature when compared to traditional tungsten filaments. Indirectly heated micro-rectangular oxide cathodes were developed using carbonates, which were converted to semiconductor oxides of barium, strontium, and calcium after activation. Each cathode produces a focal spot on an elongated fixed anode. The x-ray beam ON and OFF control is performed by source-switching electronics, which supplies bias voltage to the cathode emitters. In this paper, we report the initial performance of the oxide-coated cathodes and the MPTEX source.

Applicability of the Child-Langmuir laws versions for describing the glow discharge cathode sheath in CO2

Science.gov (United States)

Lisovskiy, Valeriy; Krol, Hennadii; Osmayev, Ruslan; Yegorenkov, Vladimir

2016-09-01

This work is devoted to the determination of the law that may be applicable to the description of the cathode sheath in CO2. To this end three versions of the Child-Langmuir law have been considered - a collision free one (for the ions moving through a cathode sheath without collisions with gas molecules) as well as two collision- related versions- one for a constant mean free path of positive ions and one for a constant mobility of positive ions. The current-voltage characteristics and the cathode sheath thickness of the glow discharge in carbon oxide have been simultaneously measured in the pressure range from 0.05 to 1 Torr and with the discharge current values up to 80 mA. The inter-electrode distance has been chosen such that the discharge consists only of the cathode sheath and a small portion of the negative glow, i.e. the experiments have been performed in short tubes. In this case the voltage drop across the cathode sheath is equal approximately to the voltage drop across the electrodes. In the whole range of the discharge conditions we have studied the cathode sheath characteristics are found to obey correctly only to the Child-Langmuir law version with a constant ion mobility. The reason for this phenomenon may be related with a significant conversion of carbon dioxide molecules.

Construction and test of a silicon drift chamber

International Nuclear Information System (INIS)

Holl, P.

1985-06-01

The present thesis presents the first fully applicable silicon detectors which work as drift chambers. Four different types of detectors were constructed. By a suitable geometry and electronic lay-out one- and two-dimensional position measurements were made possible. Chapter 2 describes function and construction of the detectors, chapter 3 their fabrication process. In chapter 4 construction and results of the test of a silicon drift chamber under laboratory conditions are described. By variation of the applied voltages the optimal operational conditions could be determined and material properties of the silicon, as for instance the electron mobility measured. A position resolution better than 5 μm at a drift length up to 4 mm was reached. Chapter 5 presents the results of the test of a silicon drift chamber under real experimental conditions in a particle beam of the super proton synchroton (SPS) of CERN. The best position resolution measured there is 10 μm. Chapter 6 summarizes the obtained results and discusses finally application possibilities and improvement proposals for silicon drift chambers. (orig./HSI) [de

Electron source with a carbon-fibrous cathode for radiation-technology accelerator

International Nuclear Information System (INIS)

Korenev, S.A.

1994-01-01

The paper analyses the circuit of a full operating voltage electron source which is a direct-action electron accelerator. The electron source consists of a power supply, high-voltage multiplier-rectifier, vacuum planar diode, vacuum system and control system. The vacuum electron diode contains an autoemission carbon-fibrous cathode and beryllium foil strip anode. The results of measurements of emission characteristics of alumosilicate and carbon-fibrous cathodes are presented. The investigations into test electron source show that it can be used as a basis for creating an electron accelerator which will be capable of generating 1 MW electron beams of 1-2 MeV energy and 1 A current. 3 refs., 1 fig., 1 tab

Space and time dependent properties of the virtual cathode in a reflex-type pulsed ion diode (virtual cathode in a reflex-type pulsed ion diode)

International Nuclear Information System (INIS)

Matsumoto, Yoshio; Yano, Syukuro

1982-01-01

Properties of a virtual cathode in a pulsed ion diode composed of an insulator-mesh anode and a metal-mesh cathode were studied experimentally at anode voltages below 360kV. Potential distribution in the virtual cathode side was measured with an insulated electrostatic potential probe, and ion beam currents in virtual and real cathode sides were measured with biased ion collectors. A loss parameter for the electron current at the virtual cathode was evaluated from the measured electron current values by using relations derived from the one-dimensional Child-Langmuir theory applied to the reflex triode. The ion beam accompanies a considerable amount of electron current, and this influences the stability of the virtual cathode; this perturbation results in variations of ion current with time. Space potentials in the emitted ion beam are given, suggesting an existence of high energy electrons of several keV accelerated by positive space potential of the ion beam. (author)

Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating

Energy Technology Data Exchange (ETDEWEB)

Feng Jin

2009-01-07

This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

Copper sulfates as cathode materials for Li batteries

Energy Technology Data Exchange (ETDEWEB)

Schwieger, Jonathan N.; Kraytsberg, Alexander; Ein-Eli, Yair [Technion Israel Institute of Technology, Department of Materials Engineering, Technion City, Haifa 32000 (Israel)

2011-02-01

As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO{sub 4}){sup 2-} possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO{sub 4}.5H{sub 2}O) with respect to lithium insertion via a two-electron displacement reaction entailing the extrusion of metallic copper at a dual voltage of 3.2 V and 2.7 V followed by its reversible insertion at 3.5 V and 3.8 V. At this stage, cyclability was still shown to be limited due to the irreversible degradation to a monohydrate structure owing to constitutional water loss. (author)

Analytical threshold voltage modeling of ion-implanted strained-Si double-material double-gate (DMDG) MOSFETs

Science.gov (United States)

Goel, Ekta; Singh, Balraj; Kumar, Sanjay; Singh, Kunal; Jit, Satyabrata

2017-04-01

Two dimensional threshold voltage model of ion-implanted strained-Si double-material double-gate MOSFETs has been done based on the solution of two dimensional Poisson's equation in the channel region using the parabolic approximation method. Novelty of the proposed device structure lies in the amalgamation of the advantages of both the strained-Si channel and double-material double-gate structure with a vertical Gaussian-like doping profile. The effects of different device parameters (such as device channel length, gate length ratios, germanium mole fraction) and doping parameters (such as projected range, straggle parameter) on threshold voltage of the proposed structure have been investigated. It is observed that the subthreshold performance of the device can be improved by simply controlling the doping parameters while maintaining other device parameters constant. The modeling results show a good agreement with the numerical simulation data obtained by using ATLAS™, a 2D device simulator from SILVACO.

Accurate computer simulation of a drift chamber

CERN Document Server

Killian, T J

1980-01-01

The author describes a general purpose program for drift chamber studies. First the capacitance matrix is calculated using a Green's function technique. The matrix is used in a linear-least-squares fit to choose optimal operating voltages. Next the electric field is computed, and given knowledge of gas parameters and magnetic field environment, a family of electron trajectories is determined. These are finally used to make drift distance vs time curves which may be used directly by a track reconstruction program. The results are compared with data obtained from the cylindrical chamber in the Axial Field Magnet experiment at the CERN ISR. (1 refs).

Neutralizer Hollow Cathode Simulations and Comparisons with Ground Test Data

Science.gov (United States)

Mikellides, Ioannis G.; Snyder, John S.; Goebel, Dan M.; Katz, Ira; Herman, Daniel A.

2009-01-01

The fidelity of electric propulsion physics-based models depends largely on the validity of their predictions over a range of operating conditions and geometries. In general, increased complexity of the physics requires more extensive comparisons with laboratory data to identify the region(s) that lie outside the validity of the model assumptions and to quantify the uncertainties within its range of application. This paper presents numerical simulations of neutralizer hollow cathodes at various operating conditions and orifice sizes. The simulations were performed using a two-dimensional axisymmetric model that solves numerically a relatively extensive system of conservation laws for the partially ionized gas in these devices. A summary of the comparisons between simulation results and Langmuir probe measurements is provided. The model has also been employed to provide insight into recent ground test observations of the neutralizer cathode in NEXT. It is found that a likely cause of the observed keeper voltage drop is cathode orifice erosion. However, due to the small magnitude of this change, is approx. 0.5 V (less than 5% of the beginning-of-life value) over 10 khrs, and in light of the large uncertainties of the cathode material sputtering yield at low ion energies, other causes cannot be excluded. Preliminary simulations to understand transition to plume mode suggest that in the range of 3-5 sccm the existing 2-D model reproduces fairly well the rise of the keeper voltage in the NEXT neutralizer as observed in the laboratory. At lower flow rates the simulation produces oscillations in the keeper current and voltage that require prohibitively small time-steps to resolve with the existing algorithms.

Magnetic filtered plasma deposition and implantation technique

CERN Document Server

Zhang Hui Xing; Wu Xian Ying

2002-01-01

A high dense metal plasma can be produced by using cathodic vacuum arc discharge technique. The microparticles emitted from the cathode in the metal plasma can be removed when the metal plasma passes through the magnetic filter. It is a new technique for making high quality, fine and close thin films which have very widespread applications. The authors describe the applications of cathodic vacuum arc technique, and then a filtered plasma deposition and ion implantation system as well as its applications

High Voltage Surface Degradation on Carbon Blacks in Lithium Ion Batteries

DEFF Research Database (Denmark)

Younesi, Reza

In order to increase the power density of Li-ion batteries, much research is focused on developing cathode materials that can operate at high voltages above 4.5 V with a high capacity, high cycling stability, and rate capability. However, at high voltages all the components of positive electrodes...... including carbon black (CB) additives have a potential risk of degradation. Though the weight percentage of CB in commercial batteries is generally very small, the volumetric amount and thus the surface area of CB compose a rather large part of a cathode due to its small particle size (≈ 50 nm) and high...

Investigation of plasma potential and pulsed discharge characteristics in enhanced glow discharge plasma immersion ion implantation and deposition

International Nuclear Information System (INIS)

Li Liuhe; Lu Qiuyuan; Fu, Ricky K.Y.; Chu, Paul K.

2009-01-01

Enhanced glow discharge plasma immersion ion implantation and deposition (EGD-PII and D) does not require external plasma sources. In this technique, the plasma is produced by self-glow discharge when a high negative voltage is applied to the sample. The small-area, pointed-shape hollow anode and large area tabular cathode form an electron-focused electric field. Using a special electric field design, the electrons from either the plasma or target (secondary electrons) are focused to a special hollow anode. As a result of the special electron-focusing field, the self-glow discharge process can be enhanced to achieve effective ion implantation into the substrate. In this work, the plasma potential distribution is investigated in details and the possible pulse discharge mechanism is discussed. The unique characteristics of the pulsed plasma and plasma extinction are studied.

Emission characteristics of Y1Ba2Cu3O7-δ cathode

International Nuclear Information System (INIS)

Korenev, S.A.

1988-01-01

The results are presented of experimental investigation of the electron beam in diode with cathode on the base of Y 1 Ba 2 Cu 3 O 7-δ . After corresponding cathode training, the cathode made from Y 1 Ba 2 Cu 3 O 7-δ material may be practicable of stable current electron beam yeild. It is shown experimentally that the voltage of diode of about 100-300 kV there exists an evident possibility of forming the electron beams with the current density of 70 A-380 A/cm 2 . The motion velicity of cathode plasma in the direction of anode for this material of a cathode amounts to (1-3)x 10 6 cm/s

Cathode-follower power amplifier

International Nuclear Information System (INIS)

Giordano, S.; Puglisi, M.

1983-01-01

In circular accelerators and particularly in storage rings it is essential that the total impedance, as seen by the beam, be kept below some critical value. A model of the accelerating system was built using a single-ended cathode-follower amplifier driving a ferrite-loaded cavity. The system operated at 234.5 kHz with a peak output voltage of +-10 kV on the gap. The dynamic output impedance, as measured on the gap, was < 15 ohms

Understanding capacity fade in silicon based electrodes for lithium-ion batteries using three electrode cells and upper cut-off voltage studies

Science.gov (United States)

Beattie, Shane D.; Loveridge, M. J.; Lain, Michael J.; Ferrari, Stefania; Polzin, Bryant J.; Bhagat, Rohit; Dashwood, Richard

2016-01-01

Commercial Li-ion batteries are typically cycled between 3.0 and 4.2 V. These voltages limits are chosen based on the characteristics of the cathode (e.g. lithium cobalt oxide) and anode (e.g. graphite). When alternative anode/cathode chemistries are studied the same cut-off voltages are often, mistakenly, used. Silicon (Si) based anodes are widely studied as a high capacity alternative to graphite for Lithium-ion batteries. When silicon-based anodes are paired with high capacity cathodes (e.g. Lithium Nickel Cobalt Aluminium Oxide; NCA) the cell typically suffers from rapid capacity fade. The purpose of this communication is to understand how the choice of upper cut-off voltage affects cell performance in Si/NCA cells. A careful study of three-electrode cell data will show that capacity fade in Si/NCA cells is due to an ever-evolving silicon voltage profile that pushes the upper voltage at the cathode to >4.4 V (vs. Li/Li+). This behaviour initially improves cycle efficiency, due to liberation of new lithium, but ultimately reduces cycling efficiency, resulting in rapid capacity fade.

Subnanosecond breakdown development in high-voltage pulse discharge: Effect of secondary electron emission

Science.gov (United States)

Alexandrov, A. L.; Schweigert, I. V.; Zakrevskiy, Dm. E.; Bokhan, P. A.; Gugin, P.; Lavrukhin, M.

2017-10-01

A subnanosecond breakdown in high-voltage pulse discharge may be a key tool for superfast commutation of high power devices. The breakdown in high-voltage open discharge at mid-high pressure in helium was studied in experiment and in kinetic simulations. The kinetic model of electron avalanche development was constructed, based on PIC-MCC simulations, including dynamics of electrons, ions and fast helium atoms, produced by ions scattering. Special attention was paid to electron emission processes from cathode, such as: photoemission by Doppler-shifted resonant photons, produced in excitation processes involving fast atoms; electron emission by ions and fast atoms bombardment of cathode; the secondary electron emission (SEE) by hot electrons from bulk plasma. The simulations show that the fast atoms accumulation is the main reason of emission growth at the early stage of breakdown, but at the final stage, when the voltage on plasma gap diminishes, namely the SEE is responsible for subnanosecond rate of current growth. It was shown that the characteristic time of the current growth can be controlled by the SEE yield. The influence of SEE yield for three types of cathode material (titanium, SiC, and CuAlMg-alloy) was tested. By changing the pulse voltage amplitude and gas pressure, the area of existence of subnanosecond breakdown is identified. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time value as small as τs = 0.4 ns, for the pulse voltage amplitude of 5÷12 kV. An increase of gas pressure from 15 Torr to 30 Torr essentially decreases the time of of current front growth, whereas the pulse voltage variation weakly affects the results.

Lanthanum Manganate Based Cathodes for Solid Oxide Fuel Cells

DEFF Research Database (Denmark)

Jørgensen, Mette Juhl

Composite cathodes for solid oxide fuel cells were investigated using electrochemical impedance spectroscopy and scanning electron microscopy. The aim was to study the oxygen reduction process in the electrode in order to minimise the voltage drop in the cathode. The electrodes contained...... five processes were found to affect the impedance of LSM/YSZ composite electrodes. Two high frequency processes were ascribed to transport of oxide ions/oxygen intermediates across LSM/YSZ interfaces and through YSZ in the composite. Several competitive elementary reaction steps, which appear as one...

AlGaN/GaN metal-insulator-semiconductor high electron mobility transistors with reduced leakage current and enhanced breakdown voltage using aluminum ion implantation

Energy Technology Data Exchange (ETDEWEB)

Sun, Shichuang [Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074 (China); Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, Suzhou 215123 (China); Fu, Kai, E-mail: kfu2009@sinano.ac.cn, E-mail: cqchen@mail.hust.edu.cn; Yu, Guohao; Zhang, Zhili; Song, Liang; Deng, Xuguang; Li, Shuiming; Sun, Qian; Cai, Yong; Zhang, Baoshun [Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, Suzhou 215123 (China); Qi, Zhiqiang; Dai, Jiangnan; Chen, Changqing, E-mail: kfu2009@sinano.ac.cn, E-mail: cqchen@mail.hust.edu.cn [Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074 (China)

2016-01-04

This letter has studied the performance of AlGaN/GaN metal-insulator-semiconductor high electron mobility transistors on silicon substrate with GaN buffer treated by aluminum ion implantation for insulating followed by a channel regrown by metal–organic chemical vapor deposition. For samples with Al ion implantation of multiple energies of 140 keV (dose: 1.4 × 10{sup 14} cm{sup −2}) and 90 keV (dose: 1 × 10{sup 14} cm{sup −2}), the OFF-state leakage current is decreased by more than 3 orders and the breakdown voltage is enhanced by nearly 6 times compared to the samples without Al ion implantation. Besides, little degradation of electrical properties of the 2D electron gas channel is observed where the maximum drain current I{sub DSmax} at a gate voltage of 3 V was 701 mA/mm and the maximum transconductance g{sub mmax} was 83 mS/mm.

The effect of surface-bulk potential difference on the kinetics of intercalation in core-shell active cathode particles

Science.gov (United States)

Kazemiabnavi, Saeed; Malik, Rahul; Orvananos, Bernardo; Abdellahi, Aziz; Ceder, Gerbrand; Thornton, Katsuyo

2018-04-01

Surface modification of active cathode particles is commonly observed in battery research as either a surface phase evolving during the cycling process, or intentionally engineered to improve capacity retention, rate capability, and/or thermal stability of the cathode material. Here, a continuum-scale model is developed to simulate the galvanostatic charge/discharge of a cathode particle with core-shell heterostructure. The particle is assumed to be comprised of a core material encapsulated by a thin layer of a second phase that has a different open-circuit voltage. The effect of the potential difference between the surface and bulk phases (Ω) on the kinetics of lithium intercalation and the galvanostatic charge/discharge profiles is studied at different values of Ω, C-rates, and exchange current densities. The difference between the Li chemical potential in the surface and bulk phases of the cathode particle results in a concentration difference between these two phases. This leads to a charge/discharge asymmetry in the galvanostatic voltage profiles, causing a decrease in the accessible capacity of the particle. These effects are more significant at higher magnitudes of surface-bulk potential difference. The proposed model provides detailed insight into the kinetics and voltage behavior of the intercalation/de-intercalation processes in core-shell heterostructure cathode particles.

Optimizing AlF{sub 3} atomic layer deposition using trimethylaluminum and TaF{sub 5}: Application to high voltage Li-ion battery cathodes

Energy Technology Data Exchange (ETDEWEB)

Jackson, David H. K., E-mail: david.jackson@wisc.edu; Kuech, Thomas F. [Materials Science Program, University of Wisconsin–Madison, Madison, Wisconsin 53706 and Department of Chemical and Biological Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States); Laskar, Masihhur R.; Ellis, Ryan G. [Department of Chemical and Biological Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States); Fang, Shuyu; Hamers, Robert J. [Department of Chemistry, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States); Xu, Shenzhen; Li, Xiaoqing; Morgan, Dane [Department of Materials Science and Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States); Dreibelbis, Mark [Core R& D, Inorganic Materials and Heterogeneous Catalysis, The Dow Chemical Company, Midland, Michigan 48674 (United States); Babcock, Susan E. [Materials Science Program, University of Wisconsin–Madison, Madison, Wisconsin 53706 and Department of Materials Science and Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States); Mahanthappa, Mahesh K. [Materials Science Program, University of Wisconsin–Madison, Madison, Wisconsin 53706 and Department of Chemistry, University of Wisconsin–Madison, Madison, Wisconsin 53706 (United States)

2016-05-15

Atomic layer deposition (ALD) of conformal AlF{sub 3} coatings onto both flat silicon substrates and high-voltage LiNi{sub 0.5}Mn{sub 0.3}Co{sub 0.2}O{sub 2} (NMC) Li-ion battery cathode powders was investigated using a Al(CH{sub 3}){sub 3}/TaF{sub 5} precursor combination. This optimized approach employs easily handled ALD precursors, while also obviating the use of highly toxic HF(g). In studies conducted on planar Si wafers, the film's growth mode was dictated by a competition between the desorption and decomposition of Ta reaction byproducts. At T ≥ 200 °C, a rapid decomposition of the Ta reaction byproducts to TaC led to continuous deposition and high concentrations of TaC in the films. A self-limited ALD growth mode was found to occur when the deposition temperature was reduced to 125 °C, and the TaF{sub 5} exposures were followed by an extended purge. The lower temperature process suppressed conversion of TaF{sub x}(CH{sub 3}){sub 5−x} to nonvolatile TaC, and the long purges enabled nearly complete TaF{sub x}(CH{sub 3}){sub 5−x} desorption, leaving behind the AlF{sub 3} thin films. NMC cathode powders were coated using these optimized conditions, and coin cells employing these coated cathode particles exhibited significant improvements in charge capacity fade at high discharge rates.

Model of 1/f noise in ion implanted resistors as a function of the resistance, determined by a reverse bias voltage

International Nuclear Information System (INIS)

Beck, H.G.E.

1979-01-01

A model is presented for the 1/f noise in ion-implanted resistors. The resistance was changed by a reverse bias voltage. The model explains the experimentally found square dependence between the relative 1/f noise intensity C/C 0 and the relative change in resistance R/R 0 . (author)

Synthesis, Structure, and Sodium Mobility of Sodium Vanadium Nitridophosphate: A Zero-Strain and Safe High Voltage Cathode Material for Sodium-Ion Batteries

Directory of Open Access Journals (Sweden)

Huang Zhang

2017-06-01

Full Text Available Herein, the nitridophosphate Na3V(PO33N is synthesized by solid state method. X-ray diffraction (XRD and Rietveld refinement confirm the cubic symmetry with P213 space group. The material exhibits very good thermal stability and high operating voltage of 4.0 V vs. Na/Na+ due to V3+/V4+ redox couple. In situ X-ray diffraction studies confirm the two-phase (de-sodiation process to occur with very low volume changes. The refinement of the sodium occupancies reveal the low accessibility of sodium cations in the Na2 and Na3 sites as the main origin for the lower experimental capacity (0.38 eq. Na+, 28 mAh g−1 versus the theoretical one (1.0 eq. Na+, 74 mAh g−1. These observations provide valuable information for the further optimization of this materials class in order to access their theoretical electrochemical performance as a potentially interesting zero-strain and safe high-voltage cathode material for sodium-ion batteries.

Investigations Of A Pulsed Cathodic Vacuum Arc

Science.gov (United States)

Oates, T. W. H.; Pigott, J.; Denniss, P.; Mckenzie, D. R.; Bilek, M. M. M.

2003-06-01

Cathodic vacuum arcs are well established as a method for producing thin films for coatings and as a source of metal ions. Research into DC vacuum arcs has been going on for over ten years in the School of Physics at the University of Sydney. Recently a project was undertaken in the school to design and build a pulsed CVA for use in the investigation of plasma sheaths and plasma immersion ion implantation. Pulsed cathodic vacuum arcs generally have a higher current and plasma density and also provide a more stable and reproducible plasma density than their DC counterparts. Additionally it has been shown that if a high repetition frequency can be established the deposition rate of pulsed arcs is equal to or greater than that of DC arcs with a concomitant reduction in the rate of macro-particle formation. We present here results of our investigations into the building of a center-triggered pulsed cathodic vacuum arc. The design of the power supply and trigger mechanism and the geometry of the anode and cathode are examined. Observations of type I and II arc spots using a CCD camera, and cathode spot velocity dependence on arc current will be presented. The role of retrograde motion in a high current pulsed arc is discussed.

Investigations Of A Pulsed Cathodic Vacuum Arc

International Nuclear Information System (INIS)

Oates, T.W.H.; Pigott, J.; Denniss, P.; Mckenzie, D.R.; Bilek, M.M.M.

2003-01-01

Cathodic vacuum arcs are well established as a method for producing thin films for coatings and as a source of metal ions. Research into DC vacuum arcs has been going on for over ten years in the School of Physics at the University of Sydney. Recently a project was undertaken in the school to design and build a pulsed CVA for use in the investigation of plasma sheaths and plasma immersion ion implantation. Pulsed cathodic vacuum arcs generally have a higher current and plasma density and also provide a more stable and reproducible plasma density than their DC counterparts. Additionally it has been shown that if a high repetition frequency can be established the deposition rate of pulsed arcs is equal to or greater than that of DC arcs with a concomitant reduction in the rate of macro-particle formation. We present here results of our investigations into the building of a center-triggered pulsed cathodic vacuum arc. The design of the power supply and trigger mechanism and the geometry of the anode and cathode are examined. Observations of type I and II arc spots using a CCD camera, and cathode spot velocity dependence on arc current will be presented. The role of retrograde motion in a high current pulsed arc is discussed

PWCs and drift chambers at ISABELLE

International Nuclear Information System (INIS)

Okuno, H.; Teramoto, Y.; Wheeler, C.D.

1978-01-01

Rate effects in proportional chambers and drift chambers are addressed first. The widely used high-gas-gain chambers would have impaired performance at ISABELLE data rates. Improvement can be expected with lower gas gain, and this possibility is investigated with respect to position and time resolution. Results on chamber lifetime are summarized; space-charge effects, gain saturation, and radiation hardness of electronics are considered. The resolution of drift chambers is discussed in some detail; time resolution, double pulse resolution, and momentum resolution and multiple scattering are included. The expected high multiplicity of tracks from a single event, the high event rates, and the requirement for low gas gain necessitate revision of the methods for measuring the second coordinate. Known methods of two-dimensional point localization are summarized according to spatial accuracy, electronics requirements, and multihit capability. Delay lines, charge division, and cathode strips are considered. Particle identification by means of measurement of the relativistic rise of energy loss by conventional and unconventional means was investigated. 32 references, 3 figures, 4 tables

Effect of secondary electron emission on subnanosecond breakdown in high-voltage pulse discharge

Science.gov (United States)

Schweigert, I. V.; Alexandrov, A. L.; Gugin, P.; Lavrukhin, M.; Bokhan, P. A.; Zakrevsky, Dm E.

2017-11-01

The subnanosecond breakdown in open discharge may be applied for producing superfast high power switches. Such fast breakdown in high-voltage pulse discharge in helium was explored both in experiment and in kinetic simulations. The kinetic model of electron avalanche development was developed using PIC-MCC technique. The model simulates motion of electrons, ions and fast helium atoms, appearing due to ions scattering. It was shown that the mechanism responsible for ultra-fast breakdown development is the electron emission from cathode. The photoemission and emission by ions or fast atoms impact is the main reason of current growth at the early stage of breakdown, but at the final stage, when the voltage on discharge gap drops, the secondary electron emission (SEE) is responsible for subnanosecond time scale of current growth. It was also found that the characteristic time of the current growth τS depends on the SEE yield of the cathode material. Three types of cathode material (titanium, SiC, and CuAlMg-alloy) were tested. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time as small as τS = 0.4 ns, for the pulse voltage amplitude of 5- 12 kV..

Effects of cathode channel size and operating conditions on the performance of air-blowing PEMFCs

International Nuclear Information System (INIS)

Kim, Bosung; Lee, Yongtaek; Woo, Ahyoung; Kim, Yongchan

2013-01-01

Highlights: • Effect of cathode channel size on the air-blowing PEMFC is analyzed. • Performance and EIS tests of air-blowing PEMFCs are conducted. • Test conditions include the operating temperature, fan voltage, and anode humidity. • Flooding is a limiting factor for decreasing channel size at low temperature. • Water management is investigated by analyzing ohmic resistance. - Abstract: Air-blowing proton exchange membrane fuel cells (PEMFCs) have been developed as a potential new power source for portable electronic devices. However, air-blowing PEMFCs show lower performance than compressed-air PEMFCs because of their adverse operating conditions. In this study, the effects of the cathode channel size and operating conditions on the performance of the air-blowing PEMFC were analyzed. At the normal operating temperature, the performance of the air-blowing PEMFC improved with the decrease in the cathode channel size. However, at a low operating temperature and low fan voltage, massive flooding limits the decrease in the cathode channel size. In addition, water management in the air-blowing PEMFC was investigated by analyzing ohmic resistance. The transition current density between the humidification and the flooding region decreased with decreasing cathode channel size and operating temperature

1999 Annual Cathodic Protection Survey Report for PFP

International Nuclear Information System (INIS)

BOWMAN, T.J.

2000-01-01

This cathodic protection (CP) report documents the results of the 1999 annual CP survey of the underground piping within PFP property. An annual survey of CP systems is required by Washington Administrative Code (WAC). A spreadsheet to document the 1999 annual survey polarization data is included in this report. Graphs are included to trend the cathodic voltages and the polarization voltages at each test station on PFP property. The trending spans from 1994 to 1999. Graphs are also included to trend voltage and amperage outputs of each rectifier during the annual surveys. During the annual survey, resistance testing between the underground piping was conducted at each test station. The testing showed that all piping (with test leads into the test stations) was continuous with every pipe represented in the test stations. The resistance data is not documented in this report but can be accessed in work package 22-99-01003. During the annual survey, the wiring configurations of anode junction boxes AJB(R45-1) and AJB(45-1) were documented. The sketches can be accessed from the JCS work record of work package 22-99-01003. Analysis, conclusions, and recommendations of the 1999 annual CP survey results are included in this report

Spatio-temporal characteristics of self-pulse in hollow cathode discharge

International Nuclear Information System (INIS)

Jing, Ha; He, Shoujie

2015-01-01

The characteristics of self-pulse in hollow cathode discharge at low pressure have been investigated. The voltage-current (V-I) curves, the influence of ballast resistor on the self-pulses, and the evolution of current and voltage are measured. Both the axial and radial spatio-temporal discharge images of self-pulse are recorded. The results show that there exists the hysteresis effect in the present hollow cathode discharge. The high value of ballast resistors is favourable for the observation of self-pulses. The process of the self-pulse can be divided into three stages from the temporal discharge images, i.e., the pre-discharge, the transition from mainly axial electric field to mainly radial electric field, and the decaying process. The self-pulse is suggested to originate from the mode transition of the discharge in essence

Analysis of the Interphase on Carbon Black Formed in High Voltage Batteries

DEFF Research Database (Denmark)

Younesi, Reza; Christiansen, Ane Sælland; Scipioni, Roberto

2015-01-01

Carbon black (CB) additives commonly used to increase the electrical conductivity of electrodes in Li-ion batteries are generally believed to be electrochemically inert additives in cathodes. Decomposition of electrolyte in the surface region of CB in Li-ion cells at high voltages up to 4.9 V...... is here studied using electrochemical measurements as well as structural and surface characterizations. LiPF6 and LiClO4 dissolved in ethylene carbonate:diethylene carbonate (1:1) were used as the electrolyte to study irreversible charge capacity of CB cathodes when cycled between 4.9 V and 2.5 V....... Synchrotron-based soft X-ray photoelectron spectroscopy (SOXPES) results revealed spontaneous partial decomposition of the electrolytes on the CB electrode, without applying external current or voltage. Depth profile analysis of the electrolyte/cathode interphase indicated that the concentration of decomposed...

Ion source using a hollow cathode discharge system and especially, particle accelerator comprising said source

International Nuclear Information System (INIS)

Mourier, Georges.

1975-01-01

An ion source provided with a hollow cathode discharge system is presented. The ion extraction system is designed in view of generating a beam directed towards a point of use located far from the point of ion production. Said source essentially comprises two cathodes facing each other, an anode at a continuous voltage with respect to the cathodes, a heated filament beyond the cathode on the path of the extracted beam, and a grid between said filament and cathode. The ion extraction is limited to a certain portion of the ions present inside the plasma, so as the discharge to continue to be sustained by itself. For that purpose pierced cathodes are used, with a transparency (the ratio of the hole area to the whole cathode area) not much higher than 50% [fr

Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes

International Nuclear Information System (INIS)

Han, Binghong; Paulauskas, Tadas; Key, Baris; Peebles, Cameron; Park, Joong Sun

2017-01-01

Here, surface coating of cathode materials with Al_2O_3 has been shown to be a promising method for cathode stabilization and improved cycling performance at high operating voltages. However, a detailed understanding on how coating process and cathode composition changes the chemical composition, morphology and distribution of coating within cathode interface and bulk lattice, is still missing. In this study, we use a wet-chemical method to synthesize a series of Al_2O_3-coated LiNi_0_._5Co_0_._2Mn_0_._3O_2 and LiCoO_2 cathodes treated under various annealing temperatures and a combination of structural characterization techniques to understand the composition, homogeneity and morphology of coating layer and the bulk cathode. Nuclear magnetic resonance and electron microscopy results reveal that the nature of the interface is highly depended on the annealing temperature and cathode composition. For Al_2O_3-coated LiNi_0_._5Co_0_._2Mn_0_._3O_2, higher annealing temperature leads to more homogeneous and more closely attached coating on cathode materials, corresponding to better electrochemical performance. Lower Al_2O_3 coating content is found to be helpful to further improve the initial capacity and cyclability, which can greatly outperform the pristine cathode material. For Al_2O_3-coated LiCoO_2, the incorporation of Al into the cathode lattice is observed after annealing at high temperatures, implying the transformation from “surface coatings” to “dopants”, which is not observed for LiNi_0_._5Co_0_._2Mn_0_._3O_2. As a result, Al_2O_3-coated LiCoO_2 annealed at higher temperature shows similar initial capacity but lower retention compared to that annealed at a lower temperature, due to the intercalation of surface alumina into the bulk layered structure forming a solid solution.

Understanding the Role of Temperature and Cathode Composition on Interface and Bulk: Optimizing Aluminum Oxide Coatings for Li-Ion Cathodes.

Science.gov (United States)

Han, Binghong; Paulauskas, Tadas; Key, Baris; Peebles, Cameron; Park, Joong Sun; Klie, Robert F; Vaughey, John T; Dogan, Fulya

2017-05-03

Surface coating of cathode materials with Al 2 O 3 has been shown to be a promising method for cathode stabilization and improved cycling performance at high operating voltages. However, a detailed understanding on how coating process and cathode composition change the chemical composition, morphology, and distribution of coating within the cathode interface and bulk lattice is still missing. In this study, we use a wet-chemical method to synthesize a series of Al 2 O 3 -coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 and LiCoO 2 cathodes treated under various annealing temperatures and a combination of structural characterization techniques to understand the composition, homogeneity, and morphology of the coating layer and the bulk cathode. Nuclear magnetic resonance and electron microscopy results reveal that the nature of the interface is highly dependent on the annealing temperature and cathode composition. For Al 2 O 3 -coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 , higher annealing temperature leads to more homogeneous and more closely attached coating on cathode materials, corresponding to better electrochemical performance. Lower Al 2 O 3 coating content is found to be helpful to further improve the initial capacity and cyclability, which can greatly outperform the pristine cathode material. For Al 2 O 3 -coated LiCoO 2 , the incorporation of Al into the cathode lattice is observed after annealing at high temperatures, implying the transformation from "surface coatings" to "dopants", which is not observed for LiNi 0.5 Co 0.2 Mn 0.3 O 2 . As a result, Al 2 O 3 -coated LiCoO 2 annealed at higher temperature shows similar initial capacity but lower retention compared to that annealed at a lower temperature, due to the intercalation of surface alumina into the bulk layered structure forming a solid solution.

Self-Driven Bioelectrochemical Mineralization of Azobenzene by Coupling Cathodic Reduction with Anodic Intermediate Oxidation

International Nuclear Information System (INIS)

Liu, Rong-Hua; Li, Wen-Wei; Sheng, Guo-Ping; Tong, Zhong-Hua; Lam, Michael Hon-Wah; Yu, Han-Qing

2015-01-01

Highlights: • Azobenzene was reduced to aniline at the cathode of an acetate-fueled MFC. • Aniline was degraded at the bioanode of a single-chamber MFC. • Cathodic reduction of azobenzene was coupled with anodic oxidation of aniline. • Self-driven, complete mineralization of azobenzene in an MFC was accomplished. - Abstract: Bioelectrochemical systems have been intensively studied as a promising technology for wastewater treatment and environment remediation. Coupling of the anodic and cathodic electrochemical reactions allows an enhanced degradation of recalcitrant organics, but external power supply is usually needed to overcome the thermodynamic barrier. In this work, we report a self-driven degradation of azobenzene in a microbial fuel cell (MFC), where the cathodic reduction of azobenzene was effectively coupled with the anodic oxidation of its reduction degradation intermediate (i.e., aniline). The anodic degradation rate of aniline, as the sole carbon source, was significantly higher than that under open-circuit conditions, suggesting a considerable bioelectrochemical oxidation of aniline. Output voltages up to 8 mV were obtained in the MFC. However, a shift of cathodic electron acceptor from oxygen to azobenzene resulted in a decreased aniline degradation rate and output voltage. The present work may provide valuable implications for development of sustainable bioelectrochemical technologies for environmental remediation

The optimization of the electrostatic field inside the ZEUS forward drift chambers: Calculations and measurements

International Nuclear Information System (INIS)

Dobberstein, M.P.; Krawczyk, F.; Schaefer-Jotter, M.

1990-11-01

The electrostatic field inside small drift cells shows in general edge effects which are not negligible. These are usually corrected by field shaping wires or strips. The operating voltages of the field shaping electrodes have to be adjusted to maximize the field homogeneity. We present the underlying ideas of such an optimization procedure for the cells of the ZEUS forward drift chambers. Using the finite difference code PROFI, the optimization can be performed automatically by a multiple solution of the Poisson equation. An experimental verification of the optimal voltages was carried out measuring the gas amplifications at the six sense wires. Modifications of the drift cell geometry were necessary for calibration measurements with a laser beam. This caused additional distortions of the electrostatic field. Their influence was calculated using the MAFIA code, which allows to include open boundary conditions. (orig.)

Electrochemical performances of proton-conducting SOFC with La-Sr-Fe-O cathode fabricated by electrophoretic deposition techniques

International Nuclear Information System (INIS)

Asamoto, Makiko; Miyake, Shinji; Yonei, Yuka; Yamaura, Hiroyuki; Yahiro, Hidenori

2009-01-01

The electrochemical performances of Proton-conducting SOFC with La 0.7 Sr 0.3 FeO 3 (LSF) cathode fabricated by the electrophoretic deposition (EPD) technique were investigated. The EPD technique provided the uniform layer of LSF cathode with constant thickness and can easily control the thickness by changing an applied voltage. The power density of the SOFC cell was dependent on the thickness of LSF cathode. The activation energy was measured to elucidate the rate-determining step for LSF cathode reaction. (author)

Ion implantation into iron

International Nuclear Information System (INIS)

Iwaki, Masaya

1978-01-01

The distribution of implanted ions in iron, the friction characteristics and the corrosion of iron were studied. The distribution of Ni or Cr ions implanted into mild steel was measured. The accelerated voltage was 150 keV, and the beam current density was about 2 microampere/cm 2 . The measurement was made with an ion microanalyzer. The measured distribution was compared with that of LSS theory. Deep invasion of Ni was seen in the measured distribution. The distribution of Cr ions was different from the distribution calculated by the LSS theory. The relative friction coefficient of mild steel varied according to the dose of implanted Cu or N ions, and to the accelerating voltage. Formation of compound metals on the surfaces of metals by ion-implantation was investigated for the purpose to prevent the corrosion of metals. The resistance of mild steel in which Ni ions were implanted was larger than that of mild steel without any treatment. (Kato, T.)

Regression Analysis of the Effect of Bias Voltage on Nano- and Macrotribological Properties of Diamond-Like Carbon Films Deposited by a Filtered Cathodic Vacuum Arc Ion-Plating Method

Directory of Open Access Journals (Sweden)

Shojiro Miyake

2014-01-01

Full Text Available Diamond-like carbon (DLC films are deposited by bend filtered cathodic vacuum arc (FCVA technique with DC and pulsed bias voltage. The effects of varying bias voltage on nanoindentation and nanowear properties were evaluated by atomic force microscopy. DLC films deposited with DC bias voltage of −50 V exhibited the greatest hardness at approximately 50 GPa, a low modulus of dissipation, low elastic modulus to nanoindentation hardness ratio, and high nanowear resistance. Nanoindentation hardness was positively correlated with the Raman peak ratio Id/Ig, whereas wear depth was negatively correlated with this ratio. These nanotribological properties highly depend on the films’ nanostructures. The tribological properties of the FCVA-DLC films were also investigated using a ball-on-disk test. The average friction coefficient of DLC films deposited with DC bias voltage was lower than that of DLC films deposited with pulse bias voltage. The friction coefficient calculated from the ball-on-disk test was correlated with the nanoindentation hardness in dry conditions. However, under boundary lubrication conditions, the friction coefficient and specific wear rate had little correlation with nanoindentation hardness, and wear behavior seemed to be influenced by other factors such as adhesion strength between the film and substrate.

Understanding capacity fade in silicon based electrodes for lithium ion batteries using three electrode cells and upper cut-off voltage studies

OpenAIRE

Beattie, Shane D.; Loveridge, Melanie; Lain, Michael J.; Ferraria, Stefania; Polzin, Bryant; Bhagat, Rohit; Dashwood, R. J.

2016-01-01

Commercial Li-ion batteries are typically cycled between 3.0 and 4.2 V. These voltages limits are chosen based on the characteristics of the cathode (e.g. lithium cobalt oxide) and anode (e.g. graphite). When alternative anode/cathode chemistries are studied the same cut-off voltages are often, mistakenly, used. Silicon (Si) based anodes are widely studied as a high capacity alternative to graphite for Lithium-ion batteries. When silicon-based anodes are paired with high capacity cathodes (e....

Modification of metallic corrosion by ion implantation

International Nuclear Information System (INIS)

Clayton, C.R.

1981-01-01

This review will consider some of the properties of surface alloys, formed by ion implantation, which are effective in modifying corrosion behaviour. Examples will be given of the modification of the corrosion behaviour of pure metals, steels and other engineering alloys, resulting from implantation with metals and metalloids. Emphasis will be given to the modification of anodic processes produced by ion implantation since a review will be given elsewhere in the proceedings concerning the modification of cathodic processes. (orig.)

LSP Simulations of the Neutralized Drift Compression Experiment

CERN Document Server

Thoma, Carsten H; Gilson, Erik P; Henestroza, Enrique; Roy, Prabir K; Welch, Dale; Yu, Simon

2005-01-01

The Neutralized Drift Compression Experiment (NDCX) at Lawrence Berkeley National Laboratory involves the longitudinal compression of a singly-stripped K ion beam with a mean energy of 250 keV in a meter long plasma. We present simulation results of compression of the NDCX beam using the PIC code LSP. The NDCX beam encounters an acceleration gap with a time-dependent voltage that decelerates the front and accelerates the tail of a 500 ns pulse which is to be compressed 110 cm downstream. The simulations model both ideal and experimental voltage waveforms. Results show good longitudinal compression without significant emittance growth.

Highly durable anode supported solid oxide fuel cell with an infiltrated cathode

DEFF Research Database (Denmark)

Samson, Alfred Junio; Hjalmarsson, Per; Søgaard, Martin

2012-01-01

An anode supported solid oxide fuel cell with an La0.6Sr0.4Co1.05O3_δ (LSC) infiltrated-Ce0.9Gd0.1O1.95 (CGO) cathode that shows a stable performance has been developed. The cathode was prepared by screen printing a porous CGO backbone on top of a laminated and co-fired anode supported half cell...... was tested at 700 deg. C under a current density of 0.5 A cm-2 for 1500 h using air as oxidant and humidified hydrogen as fuel. The electrochemical performance of the cell was analyzed by impedance spectroscopy and current evoltage relationships. No measurable degradation in the cell voltage or increase...... in the resistance from the recorded impedance was observed during long term testing. The power density reached 0.79Wcm-2 at a cell voltage of 0.6 V at 750 deg. C. Post test analysis of the LSC infiltrated-CGO cathode by scanning electron microscopy revealed no significant micro-structural difference...

Non-Uniformity of Ion Implantation in Direct-Current Plasma Immersion Ion Implantation

International Nuclear Information System (INIS)

Cheng-Sen, Liu; Yu-Jia, Fan; Nan, Zhang; Li, Guan; Yuan, Yao; De-Zhen, Wang

2010-01-01

A particle-in-cell simulation is developed to study dc plasma immersion ion implantation. Particular attention is paid to the influence of the voltage applied to the target on the ion path, and the ion flux distribution on the target surface. It is found that the potential near the aperture within the plasma region is not the plasma potential, and is impacted by the voltage applied to the implanted target. A curved equipotential contour expands into the plasma region through the aperture and the extent of the expansion depends on the voltage. Ions accelerated by the electric field in the sheath form a beam shape and a flux distribution on the target surface, which are strongly dependent on the applied voltage. The results of the simulations demonstrate the formation mechanism of the grid-shadow effect, which is in agreement with the result observed experimentally. (physics of gases, plasmas, and electric discharges)

Studies on the detection characteristics of the OPERA drift tube spectrometer; Studien zu den Nachweiseigenschaften des OPERA-Driftroehrenspektrometers

Energy Technology Data Exchange (ETDEWEB)

Oldorf, Christian

2009-07-15

Within the framework of this diploma thesis the density dependent detection characteristics of the OPERA Precision Tracker are studied at a test set up with two drift tube modules. Measurements of gain, hit efficiency, spatial resolution and time-to-distance relation are presented depending on the density, anode voltage and discriminator thresholds. At a constant anode voltage the gain falls with increasing density. Therefore the hit efficiency and the spatial resolution decrease with increasing density above 1,70 kg/m{sup 3}. Within the temperature-fluctuations of 6 K inside the LNGS, an uncertainty of the spatial resolution up to 75 {mu}m is found. Within these temperature-fluctuations the upper limit for the variation of the drift distance at a drift time of 1200 ns is about 220 {mu}m. Both effects are tolerable for the spatial resolution of the OPERA Drift Tubes. (orig.)

A definitive criterion for cathodic protection

Energy Technology Data Exchange (ETDEWEB)

Alexander, Roger [Cathodic Protection Network International Ltd., Reading (United Kingdom)

2009-07-01

The corrosion reaction is defined using the Pourbaix Diagram and includes consideration of the pH, temperature, pressure, nobility of the metal and conductivity of the electrolyte. The passive zone can be established in a laboratory by creating a closed circuit condition in which the voltages can be measured. Natural corrosion cells occurring in simple conditions can be evaluated for the purpose of monitoring the performance of cathodic protection. Metal pipelines are complex networks of conductors submerged in electrolyte of infinitely variable qualities. The present method used to ascertain the effectiveness of cathodic protection has many inherent errors and results in costly and unpredictable corrosion failures. An electrode has been devised to define the exact electrical status of the corrosion reaction at its location. The design allows a closed circuit measurement of the corrosion current that can determine whether or not corrosion has been stopped by cathodic protection. This has allowed the development of software that can calculate the condition and corrosion status throughout a network of pipelines, using electrical circuit analysis common in the electronics industry. (author)

Plasma immersion ion implantation (and deposition) inside metallic tubes of different dimensions and configurations

Science.gov (United States)

Ueda, M.; Silva, C.; Santos, N. M.; Souza, G. B.

2017-10-01

There is a strong need for developing methods to coat or implant ions inside metallic tubes for many practical contemporary applications, both for industry and science. Therefore, stainless steel tubes with practical diameters of 4, 11 and 16 cm, but short lengths of 20 cm, were internally treated by nitrogen plasma immersion ion implantation (PIII). Different configurations as tube with lid in one of the ends or both sides open were tested for better PIII performance, in the case of smallest diameter tube. Among these PIII tests in tubes, using the 4 cm diameter one with a lid, it was possible to achieve tube temperatures of more than 700 °C in 15 min and maintain it during the whole treatment time (typically 2 h). Samples made of different materials were placed at the interior of the tube, as the monitors for posterior analysis, and the tube was solely pulsed by high voltage pulser producing high voltage glow discharge and hollow cathode discharge both driven by a moderate power source. In this experiment, samples of SS 304, pure Ti, Ti6Al4V and Si were used for the tests of the above methods. Results on the analysis of the surface of these nitrogen PIII treated materials, as well as on their processing methods, are presented and discussed in the paper.

Study of nanometric thin pyrolytic carbon films for explosive electron emission cathode in high-voltage planar diode

Energy Technology Data Exchange (ETDEWEB)

Baryshevsky, Vladimir; Belous, Nikolai; Gurinovich, Alexandra; Gurnevich, Evgeny [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Kuzhir, Polina, E-mail: polina.kuzhir@gmail.com [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Maksimenko, Sergey [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Molchanov, Pavel; Shuba, Mikhail [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Roddatis, Vladimir [CIC energiGUNE, Albert Einstein 48, 01510 Minano, Alava (Spain); Institut für Materialphysik of Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Kaplas, Tommi; Svirko, Yuri [Institute of Photonics, University of Eastern Finland, P.O. Box 111, Joensuu FI-80101 (Finland)

2015-04-30

We report on an experimental study of explosive electron emission properties of cathode made by nanometric thin pyrolytic carbon (PyC) films (2–150 nm) deposited on Cu substrate via methane-based chemical vapor deposition. High current density at level of 300 A/cm{sup 2} in 5 · 10{sup −5} Pa vacuum has been observed together with very stable explosive emission from the planar cathode. The Raman spectroscopy investigation proves that the PyC films remain the same after seven shots. According to the optical image analysis of the cathode before and after one and seven shots, we conclude that the most unusual and interesting feature of using the PyC films/Cu cathode for explosive emission is that the PyC layer on the top of the copper target prevents its evaporation and oxidation, which leads to higher emission stability compared to conventional graphitic/Cu cathodes, and therefore results in longer working life. - Highlights: • Explosive electron emission from pyrolytic carbon (PyC) cathode is reported. • We observe high current density, 300 A/cm{sup 2}, and stable emission parameters. • PyC integrity ensures a high application potential for high current electronics.

Assessment of the cathode contribution to the degradation of anode-supported solid oxide fuel cells

DEFF Research Database (Denmark)

Hagen, Anke; Liu, Yi-Lin; Barfod, Rasmus

2008-01-01

The degradation of anode-supported cells was studied over 1500 h as a function of cell polarization either in air or oxygen on the cathode side. Based on impedance analysis, contributions of the anode and cathode to the increase of total resistance were assigned. Accordingly, the degradation rates...... of the cathode were strongly dependent on the pO(2). Microstructural analysis of the cathode/electrolyte interface carried out after removal of the cathode showed craters on the electrolyte surface where the lanthanum strontium manganite (LSM) particles had been located. The changes of shape and size...... of these craters observed after testing correlated with the cell voltage degradation rates. The results can be interpreted in terms of element redistribution at the cathode/electrolyte interface and formation of foreign phases giving rise to a weakening of local contact points of the LSM cathode and yttria...

High voltage and high specific capacity dual intercalating electrode Li-ion batteries

Science.gov (United States)

West, William C. (Inventor); Blanco, Mario (Inventor)

2010-01-01

The present invention provides high capacity and high voltage Li-ion batteries that have a carbonaceous cathode and a nonaqueous electrolyte solution comprising LiF salt and an anion receptor that binds the fluoride ion. The batteries can comprise dual intercalating electrode Li ion batteries. Methods of the present invention use a cathode and electrode pair, wherein each of the electrodes reversibly intercalate ions provided by a LiF salt to make a high voltage and high specific capacity dual intercalating electrode Li-ion battery. The present methods and systems provide high-capacity batteries particularly useful in powering devices where minimizing battery mass is important.

Low-energy plasma-cathode electron gun with a perforated emission electrode

Science.gov (United States)

Burdovitsin, Victor; Kazakov, Andrey; Medovnik, Alexander; Oks, Efim; Tyunkov, Andrey

2017-11-01

We describe research of influence of the geometric parameters of perforated electrode on emission parameters of a plasma cathode electron gun generating continuous electron beams at gas pressure 5-6 Pa. It is shown, that the emission current increases with increasing the hole diameters and decreasing the thickness of the perforated emission electrode. Plasma-cathode gun with perforated electron can provide electron extraction with an efficiency of up to 72 %. It is shown, that the current-voltage characteristic of the electron gun with a perforated emission electrode differs from that of similar guns with fine mesh grid electrode. The plasma-cathode electron gun with perforated emission electrode is used for electron beam welding and sintering.

Mechanism of formation of subnanosecond current front in high-voltage pulse open discharge

Science.gov (United States)

Schweigert, I. V.; Alexandrov, A. L.; Zakrevsky, Dm. E.; Bokhan, P. A.

2014-11-01

The mechanism of subnanosecond current front rise observed previously in the experiment in high-voltage pulse open discharge in helium is studied in kinetic particle-in-cell simulations. The Boltzmann equations for electrons, ions, and fast atoms are solved self-consistently with the Poisson equations for the electrical potential. The partial contributions to the secondary electron emission from the ions, fast atoms, photons, and electrons, bombarding the electrode, are calculated. In simulations, as in the experiment, the discharge glows between two symmetrical cathodes and the anode grid in the midplane at P =6 Torr and the applied voltage of 20 kV. The electron avalanche development is considered for two experimental situations during the last stage of breakdown: (i) with constant voltage and (ii) with decreasing voltage. For case (i), the subnanosecond current front rise is set by photons from the collisional excitation transfer reactions. For the case (ii), the energetic electrons swamp the cathode during voltage drop and provide the secondary electron emission for the subnanosecond current rise, observed in the experiment.

Glass Polarization Induced Drift of a Closed-Loop Micro-Accelerometer

Directory of Open Access Journals (Sweden)

Wu Zhou

2018-01-01

Full Text Available The glass polarization effects were introduced in this paper to study the main cause of turn-on drift phenomenon of closed-loop micro-accelerometers. The glass substrate underneath the sensitive silicon structure underwent a polarizing process when the DC bias voltage was applied. The slow polarizing process induced an additional electrostatic field to continually drag the movable mass block from one position to another so that the sensing capacitance was changed, which led to an output drift of micro-accelerometers. This drift was indirectly tested by experiments and could be sharply reduced by a shielding layer deposited on the glass substrate because the extra electrical filed was prohibited from generating extra electrostatic forces on the movable fingers of the mass block. The experimental results indicate the average magnitude of drift decreased about 73%, from 3.69 to 0.99 mV. The conclusions proposed in this paper showed a meaningful guideline to improve the stability of micro-devices based on silicon-on-glass structures.

Glass Polarization Induced Drift of a Closed-Loop Micro-Accelerometer.

Science.gov (United States)

Zhou, Wu; He, Jiangbo; Yu, Huijun; Peng, Bei; He, Xiaoping

2018-01-20

The glass polarization effects were introduced in this paper to study the main cause of turn-on drift phenomenon of closed-loop micro-accelerometers. The glass substrate underneath the sensitive silicon structure underwent a polarizing process when the DC bias voltage was applied. The slow polarizing process induced an additional electrostatic field to continually drag the movable mass block from one position to another so that the sensing capacitance was changed, which led to an output drift of micro-accelerometers. This drift was indirectly tested by experiments and could be sharply reduced by a shielding layer deposited on the glass substrate because the extra electrical filed was prohibited from generating extra electrostatic forces on the movable fingers of the mass block. The experimental results indicate the average magnitude of drift decreased about 73%, from 3.69 to 0.99 mV. The conclusions proposed in this paper showed a meaningful guideline to improve the stability of micro-devices based on silicon-on-glass structures.

Modeling the Effects of the Cathode Composition of a Lithium Iron Phosphate Battery on the Discharge Behavior

Directory of Open Access Journals (Sweden)

Won Il Cho

2013-10-01

Full Text Available This paper reports a modeling methodology to predict the effects on the discharge behavior of the cathode composition of a lithium iron phosphate (LFP battery cell comprising a LFP cathode, a lithium metal anode, and an organic electrolyte. A one-dimensional model based on a finite element method is presented to calculate the cell voltage change of a LFP battery cell during galvanostatic discharge. To test the validity of the modeling approach, the modeling results for the variations of the cell voltage of the LFP battery as a function of time are compared with the experimental measurements during galvanostatic discharge at various discharge rates of 0.1C, 0.5C, 1.0C, and 2.0C for three different compositions of the LFP cathode. The discharge curves obtained from the model are in good agreement with the experimental measurements. On the basis of the validated modeling approach, the effects of the cathode composition on the discharge behavior of a LFP battery cell are estimated. The modeling results exhibit highly nonlinear dependencies of the discharge behavior of a LFP battery cell on the discharge C-rate and cathode composition.

The use of stainless steel and nickel alloys as low-cost cathodes in microbial electrolysis cells

KAUST Repository

Selembo, Priscilla A.

2009-05-01

Microbial electrolysis cells (MECs) are used to produce hydrogen gas from the current generated by bacteria, but low-cost alternatives are needed to typical cathode materials (carbon cloth, platinum and Nafion™). Stainless steel A286 was superior to platinum sheet metal in terms of cathodic hydrogen recovery (61% vs. 47%), overall energy recovery (46% vs. 35%), and maximum volumetric hydrogen production rate (1.5 m3 m-3 day-1 vs. 0.68 m3 m-3 day-1) at an applied voltage of 0.9 V. Nickel 625 was better than other nickel alloys, but it did not perform as well as SS A625. The relative ranking of these materials in MEC tests was in agreement with cyclic voltammetry studies. Performance of the stainless steel and nickel cathodes was further increased, even at a lower applied voltage (0.6 V), by electrodepositing a nickel oxide layer onto the sheet metal (cathodic hydrogen recovery, 52%, overall energy recovery, 48%; maximum volumetric hydrogen production rate, 0.76 m3 m-3 day-1). However, performance of the nickel oxide cathodes decreased over time due to a reduction in mechanical stability of the oxides (based on SEM-EDS analysis). These results demonstrate that non-precious metal cathodes can be used in MECs to achieve hydrogen gas production rates better than those obtained with platinum. © 2009 Elsevier B.V. All rights reserved.

The use of stainless steel and nickel alloys as low-cost cathodes in microbial electrolysis cells

KAUST Repository

Selembo, Priscilla A.; Merrill, Mathew D.; Logan, Bruce E.

2009-01-01

Microbial electrolysis cells (MECs) are used to produce hydrogen gas from the current generated by bacteria, but low-cost alternatives are needed to typical cathode materials (carbon cloth, platinum and Nafion™). Stainless steel A286 was superior to platinum sheet metal in terms of cathodic hydrogen recovery (61% vs. 47%), overall energy recovery (46% vs. 35%), and maximum volumetric hydrogen production rate (1.5 m3 m-3 day-1 vs. 0.68 m3 m-3 day-1) at an applied voltage of 0.9 V. Nickel 625 was better than other nickel alloys, but it did not perform as well as SS A625. The relative ranking of these materials in MEC tests was in agreement with cyclic voltammetry studies. Performance of the stainless steel and nickel cathodes was further increased, even at a lower applied voltage (0.6 V), by electrodepositing a nickel oxide layer onto the sheet metal (cathodic hydrogen recovery, 52%, overall energy recovery, 48%; maximum volumetric hydrogen production rate, 0.76 m3 m-3 day-1). However, performance of the nickel oxide cathodes decreased over time due to a reduction in mechanical stability of the oxides (based on SEM-EDS analysis). These results demonstrate that non-precious metal cathodes can be used in MECs to achieve hydrogen gas production rates better than those obtained with platinum. © 2009 Elsevier B.V. All rights reserved.

Space and Temporal Correlation between the Moving Virtual Anode and the Ionization Growth in a Transient Hollow Cathode Discharge

International Nuclear Information System (INIS)

Zambra, M.; Moreno, J.; Soto, L.; Silva, P.; Sylvester, G.; Alarcon, H.

2001-01-01

A Transient Hollow Cathode Discharge is a low-pressure high-voltage electric discharge between plane parallel electrodes with an axial hole in the cathode. There are essential ionization events which lead to final electrical breakdown, between them the enhanced ionization processes taking place inside the Hollow Cathode Region (HCR) and the virtual anode moving in the interelectrode region, which extends the anode potential to within the HCR. In previous works it was studied the virtual anode speed in the A-K gap and the temporal evolution of the ionization growth in the HCR separately. In this paper, the virtual anode speed has been studied temporal and space correlated with the ionization growth inside the HCR. The presence of the moving virtual anode and the ionization growth has been diagnosed by means of capacitive probes and observing the light emission at 656 nm (H-α) from a point behind the cathode aperture respectively. The discharge was operated in hydrogen gas, at pressure in the range 100-300 mTorr, with 5 mm cathode aperture and at 30 kV maximum voltage. (author)

Spin-drift transport in semiconductors

Energy Technology Data Exchange (ETDEWEB)

Miah, M Idrish [Nanoscale Science and Technology Centre and School of Biomolecular and Physical Sciences, Griffith University, Nathan, Brisbane, QLD 4111 (Australia); Department of Physics, University of Chittagong, Chittagong, Chittagong-4331 (Bangladesh)

2008-02-07

We present a study on spin transport in semiconductors under applied electric fields. Our experiments detect photoinjected electron spins and their relaxation during drift transport in intrinsic and moderately n-doped GaAs, based on the extraordinary Hall (eH) effect. For relatively low electric field (E), the optically spin-induced eH effect in n-doped GaAs is found to be enhanced with increasing doping density and not to depend much on E, indicating that a substantial amount of optical spin polarization is preserved during the drift transport in these extrinsic semiconductors. However, when the spin-oriented electrons are injected with a high E, a very significant decrease is observed in the eH voltage (V{sub eH}) due to an increase in the spin precession frequency of the hot electrons. Spin relaxation by the D'yakonov-Perel' mechanism is calculated, and is suggested to be the reason for such a rapid spin relaxation for hot electrons under a high E. However, in an intrinsic GaAs (i-GaAs), a much weaker V{sub eH} is observed and, as the electron spins scattered by holes due to the Coulomb interaction in i-GaAs, the spin relaxation by the Bir-Aronov-Pikus mechanism is considered. Skew scattering and side jump as possible mechanisms of the optically spin-induced transverse Hall currents are discussed. Based on a spin drift-diffusion model, drift and diffusion contributions to the V{sub eH} are examined. The results are also discussed in comparison with theoretical investigations.

Bioelectrochemical methane (CH4) production in anaerobic digestion at different supplemental voltages.

Science.gov (United States)

Choi, Kwang-Soon; Kondaveeti, Sanath; Min, Booki

2017-12-01

Microbial electrolysis cells (MECs) at various cell voltages (0.5, 0.7 1.0 and 1.5V) were operated in anaerobic fermentation. During the start-up period, the cathode potential decreased from -0.63 to -1.01V, and CH 4 generation increased from 168 to 199ml. At an applied voltage of 1.0V, the highest methane yields of 408.3ml CH 4 /g COD glucose was obtained, which was 30.3% higher than in the control tests (313.4ml CH 4 /g COD glucose). The average current of 5.1mA was generated at 1.0V at which the maximum methane yield was obtained. The other average currents were 1.42, 3.02, 0.53mA at 0.5, 0.7, and 1.5V, respectively. Cyclic voltammetry and EIS analysis revealed that enhanced reduction currents were present at all cell voltages with biocatalyzed cathode electrodes (no reduction without biofilm), and the highest value was obtained with 1V external voltage. Copyright © 2017 Elsevier Ltd. All rights reserved.

Manganese dioxide as a new cathode catalyst in microbial fuel cells

Science.gov (United States)

Li, Xiang; Hu, Boxun; Suib, Steven; Lei, Yu; Li, Baikun

This study focused on manganese oxides with a cryptomelane-type octahedral molecular sieve (OMS-2) structure to replace platinum as a cathode catalyst in microbial fuel cells (MFCs). Undoped (ud-OSM-2) and three catalysts doped with cobalt (Co-OMS-2), copper (Cu-OMS-2), and cerium (Ce-OMS-2) to enhance their catalytic performances were investigated. The novel OMS-2 cathodes were examined in granular activated carbon MFC (GACMFC) with sodium acetate as the anode reagent and oxygen in air as the cathode reagent. The results showed that after 400 h of operation, the Co-OMS-2 and Cu-OMS-2 exhibited good catalytic performance in an oxygen reduction reaction (ORR). The voltage of the Co-OMS-2 GACMFC was 217 mV, and the power density was 180 mW m -2. The voltage of the Cu-OMS-2 GACMFC was 214 mV and the power density was 165 mW m -2. The internal resistance (R in) of the OMS-2 GACMFCs (18 ± 1 Ω) was similar to that of the platinum GACMFCs (17 Ω). Furthermore, the degradation rates of organic substrates in the OMS-2 GACMFCs were twice those in the platinum GACMFCs, which enhance their wastewater treatment efficiencies. This study indicated that using OMS-2 manganese oxides to replace platinum as a cathodic catalyst enhances power generation, increases contaminant removal, and substantially reduces the cost of MFCs.

Manganese dioxide as a new cathode catalyst in microbial fuel cells

Energy Technology Data Exchange (ETDEWEB)

Li, Xiang; Li, Baikun [Department of Civil and Environmental Engineering, University of Connecticut, Storrs, CT 06269 (United States); Hu, Boxun [Institute of Materials Science, University of Connecticut, Storrs, CT 06269 (United States); Suib, Steven [Institute of Materials Science, University of Connecticut, Storrs, CT 06269 (United States); Department of Chemistry, University of Connecticut, Storrs, CT 06269 (United States); Department of Chemical and Biomolecular Engineering, University of Connecticut, Storrs, CT 06269 (United States); Lei, Yu. [Department of Chemical and Biomolecular Engineering, University of Connecticut, Storrs, CT 06269 (United States)

2010-05-01

This study focused on manganese oxides with a cryptomelane-type octahedral molecular sieve (OMS-2) structure to replace platinum as a cathode catalyst in microbial fuel cells (MFCs). Undoped (ud-OSM-2) and three catalysts doped with cobalt (Co-OMS-2), copper (Cu-OMS-2), and cerium (Ce-OMS-2) to enhance their catalytic performances were investigated. The novel OMS-2 cathodes were examined in granular activated carbon MFC (GACMFC) with sodium acetate as the anode reagent and oxygen in air as the cathode reagent. The results showed that after 400 h of operation, the Co-OMS-2 and Cu-OMS-2 exhibited good catalytic performance in an oxygen reduction reaction (ORR). The voltage of the Co-OMS-2 GACMFC was 217 mV, and the power density was 180 mW m{sup -2}. The voltage of the Cu-OMS-2 GACMFC was 214 mV and the power density was 165 mW m{sup -2}. The internal resistance (R{sub in}) of the OMS-2 GACMFCs (18 {+-} 1 {omega}) was similar to that of the platinum GACMFCs (17 {omega}). Furthermore, the degradation rates of organic substrates in the OMS-2 GACMFCs were twice those in the platinum GACMFCs, which enhance their wastewater treatment efficiencies. This study indicated that using OMS-2 manganese oxides to replace platinum as a cathodic catalyst enhances power generation, increases contaminant removal, and substantially reduces the cost of MFCs. (author)

X- or gamma ray converter and manufacturing method for its cathode system

Energy Technology Data Exchange (ETDEWEB)

Baeuerlein, R; Uhl, D; Diepers, H; Jablonski, K H

1981-02-05

The X-ray converter serves for application in medical diagnostics. For the cathode system of the converter a system based on low-pressure ionography is suited making use of the X-ray photoelectric emission. The electrodes of the cathode system consist of double-layer films with two external conduction layers and an insulator in between. As an auxiliary voltage can be applied between the individual layers the field gradient in the holes may be adjusted, thus increasing the quantum yield.

X- or gamma ray converter and manufacturing method for its cathode system

International Nuclear Information System (INIS)

Baeuerlein, R.; Uhl, D.; Diepers, H.; Jablonski, K.H.

1981-01-01

The X-ray converter serves for application in medical diagnostics. For the cathode system of the converter a system based on low-pressure ionography is suited making use of the X-ray photoelectric emission. The electrodes of the cathode system consist of double-layer films with two external conduction layers and an insulator in between. As an auxiliary voltage can be applied between the individual layers the field gradient in the holes may be adjusted, thus increasing the quantum yield. (orig./HP)

Reversible calcium alloying enables a practical room-temperature rechargeable calcium-ion battery with a high discharge voltage

Science.gov (United States)

Wang, Meng; Jiang, Chunlei; Zhang, Songquan; Song, Xiaohe; Tang, Yongbing; Cheng, Hui-Ming

2018-06-01

Calcium-ion batteries (CIBs) are attractive candidates for energy storage because Ca2+ has low polarization and a reduction potential (-2.87 V versus standard hydrogen electrode, SHE) close to that of Li+ (-3.04 V versus SHE), promising a wide voltage window for a full battery. However, their development is limited by difficulties such as the lack of proper cathode/anode materials for reversible Ca2+ intercalation/de-intercalation, low working voltages (performance. Here, we report a CIB that can work stably at room temperature in a new cell configuration using graphite as the cathode and tin foils as the anode as well as the current collector. This CIB operates on a highly reversible electrochemical reaction that combines hexafluorophosphate intercalation/de-intercalation at the cathode and a Ca-involved alloying/de-alloying reaction at the anode. An optimized CIB exhibits a working voltage of up to 4.45 V with capacity retention of 95% after 350 cycles.

Analytical models of lateral power devices with arbitrary vertical doping profiles in the drift region

International Nuclear Information System (INIS)

Hua Ting-Ting; Guo Yu-Feng; Yu Ying; Jian Tong; Yao Jia-Fei; Sheu Gene

2013-01-01

By solving the 2D Poisson's equation, analytical models are proposed to calculate the surface potential and electric field distributions of lateral power devices with arbitrary vertical doping profiles. The vertical and the lateral breakdown voltages are formulized to quantify the breakdown characteristic in completely-depleted and partially-depleted cases. A new reduced surface field (RESURF) criterion which can be used in various drift doping profiles is further derived for obtaining the optimal trade-off between the breakdown voltage and the on-resistance. Based on these models and the numerical simulation, the electric field modulation mechanism and the breakdown characteristics of lateral power devices are investigated in detail for the uniform, linear, Gaussian, and some discrete doping profiles along the vertical direction in the drift region. Then, the mentioned vertical doping profiles of these devices with the same geometric parameters are optimized, and the results show that the optimal breakdown voltages and the effective drift doping concentrations of these devices are identical, which are equal to those of the uniform-doped device, respectively. The analytical results of these proposed models are in good agreement with the numerical results and the previous experimental results, confirming the validity of the models presented here. (interdisciplinary physics and related areas of science and technology)

Analytical models of lateral power devices with arbitrary vertical doping profiles in the drift region

Science.gov (United States)

Hua, Ting-Ting; Guo, Yu-Feng; Yu, Ying; Gene, Sheu; Jian, Tong; Yao, Jia-Fei

2013-05-01

By solving the 2D Poisson's equation, analytical models are proposed to calculate the surface potential and electric field distributions of lateral power devices with arbitrary vertical doping profiles. The vertical and the lateral breakdown voltages are formulized to quantify the breakdown characteristic in completely-depleted and partially-depleted cases. A new reduced surface field (RESURF) criterion which can be used in various drift doping profiles is further derived for obtaining the optimal trade-off between the breakdown voltage and the on-resistance. Based on these models and the numerical simulation, the electric field modulation mechanism and the breakdown characteristics of lateral power devices are investigated in detail for the uniform, linear, Gaussian, and some discrete doping profiles along the vertical direction in the drift region. Then, the mentioned vertical doping profiles of these devices with the same geometric parameters are optimized, and the results show that the optimal breakdown voltages and the effective drift doping concentrations of these devices are identical, which are equal to those of the uniform-doped device, respectively. The analytical results of these proposed models are in good agreement with the numerical results and the previous experimental results, confirming the validity of the models presented here.

Current control for magnetized plasma in direct-current plasma-immersion ion implantation

International Nuclear Information System (INIS)

Tang Deli; Chu, Paul K.

2003-01-01

A method to control the ion current in direct-current plasma-immersion ion implantation (PIII) is reported for low-pressure magnetized inductively coupled plasma. The ion current can be conveniently adjusted by applying bias voltage to the conducting grid that separates plasma formation and implantation (ion acceleration) zones without the need to alter the rf input power, gas flux, or other operating conditions. The ion current that diminishes with an increase in grid bias in magnetized plasmas can be varied from 48 to 1 mA by increasing the grid voltage from 0 to 70 V at -50 kV sample bias and 0.5 mTorr hydrogen pressure. High implantation voltage and monoenergetic immersion implantation can now be achieved by controlling the ion current without varying the macroscopic plasma parameters. The experimental results and interpretation of the effects are presented in this letter. This technique is very attractive for PIII of planar samples that require on-the-fly adjustment of the implantation current at high implantation voltage but low substrate temperature. In some applications such as hydrogen PIII-ion cut, it may obviate the need for complicated sample cooling devices that must work at high voltage

Electronic structure of the polymer-cathode interface of an organic electroluminescent device investigated using operando hard x-ray photoelectron spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Ikeuchi, J.; Hamamatsu, H.; Miyamoto, T. [Sumitomo Chemical Co., Ltd., Advanced Materials Research Laboratory, 6 Kitahara, Tsukuba, Ibaraki 300-3294 (Japan); Tanaka, S. [Sumitomo Chemical Co., Ltd., Tsukuba Material Development Laboratory, 6 Kitahara, Tsukuba, Ibaraki 300-3294 (Japan); Yamashita, Y.; Yoshikawa, H.; Ueda, S. [National Institute for Materials Science, Synchrotron X-ray Station at SPring-8, Sayo-cho, Sayo-gun, Hyogo 679-5148 (Japan)

2015-08-28

The electronic structure of a polymer-cathode interface of an operating organic light-emitting diode (OLED) was directly investigated using hard X-ray photoelectron spectroscopy (HAXPES). The potential distribution profile of the light-emitting copolymer layer as a function of the depth under the Al/Ba cathode layer in the OLED depended on the bias voltage. We found that band bending occurred in the copolymer of 9,9-dioctylfluorene (50%) and N-(4-(2-butyl)-phenyl)diphenylamine (F8-PFB) layer near the cathode at 0 V bias, while a linear potential distribution formed in the F8-PFB when a bias voltage was applied to the OLED. Direct observation of the built-in potential and that band bending formed in the F8-PFB layer in the operating OLED suggested that charges moved in the F8-PFB layer before electron injection from the cathode.

Electronic structure of the polymer-cathode interface of an organic electroluminescent device investigated using operando hard x-ray photoelectron spectroscopy

International Nuclear Information System (INIS)

Ikeuchi, J.; Hamamatsu, H.; Miyamoto, T.; Tanaka, S.; Yamashita, Y.; Yoshikawa, H.; Ueda, S.

2015-01-01

The electronic structure of a polymer-cathode interface of an operating organic light-emitting diode (OLED) was directly investigated using hard X-ray photoelectron spectroscopy (HAXPES). The potential distribution profile of the light-emitting copolymer layer as a function of the depth under the Al/Ba cathode layer in the OLED depended on the bias voltage. We found that band bending occurred in the copolymer of 9,9-dioctylfluorene (50%) and N-(4-(2-butyl)-phenyl)diphenylamine (F8-PFB) layer near the cathode at 0 V bias, while a linear potential distribution formed in the F8-PFB when a bias voltage was applied to the OLED. Direct observation of the built-in potential and that band bending formed in the F8-PFB layer in the operating OLED suggested that charges moved in the F8-PFB layer before electron injection from the cathode

Electronic structure of the polymer-cathode interface of an organic electroluminescent device investigated using operando hard x-ray photoelectron spectroscopy

Science.gov (United States)

Ikeuchi, J.; Hamamatsu, H.; Miyamoto, T.; Tanaka, S.; Yamashita, Y.; Yoshikawa, H.; Ueda, S.

2015-08-01

The electronic structure of a polymer-cathode interface of an operating organic light-emitting diode (OLED) was directly investigated using hard X-ray photoelectron spectroscopy (HAXPES). The potential distribution profile of the light-emitting copolymer layer as a function of the depth under the Al/Ba cathode layer in the OLED depended on the bias voltage. We found that band bending occurred in the copolymer of 9,9-dioctylfluorene (50%) and N-(4-(2-butyl)-phenyl)diphenylamine (F8-PFB) layer near the cathode at 0 V bias, while a linear potential distribution formed in the F8-PFB when a bias voltage was applied to the OLED. Direct observation of the built-in potential and that band bending formed in the F8-PFB layer in the operating OLED suggested that charges moved in the F8-PFB layer before electron injection from the cathode.

Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries

Science.gov (United States)

Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon; Chang, Wonyoung

2014-09-01

We utilize transmission electron microscopy in conjunction with electron energy loss spectroscopy to investigate local degradation that occurs in LixNi0.8Co0.15Al0.05O2 cathode materials (NCA) after 30 cycles with cutoff voltages of 4.3 V and 4.8 V at 55 °C. NCA has a homogeneous crystallographic structure before electrochemical reactions; however, we observed that 30 cycles of charge/discharge reactions induced inhomogeneity in the crystallographic and electronic structures and also introduced porosity particularly at surface area. These changes were more noticeable in samples cycled with higher cutoff voltage of 4.8 V. Effect of operating temperature was further examined by comparing electronic structures of oxygen of the NCA particles cycled at both room temperature and 55 °C. The working temperature has a greater impact on the NCA cathode materials at a cutoff voltage of 4.3 V that is the practical the upper limit voltage in most applications, while a cutoff voltage of 4.8 V is high enough to cause surface degradation even at room temperature.

Expansion of the cathode spot and generation of shock waves in the plasma of a volume discharge in atmospheric-pressure helium

International Nuclear Information System (INIS)

Omarov, O. A.; Kurbanismailov, V. S.; Arslanbekov, M. A.; Gadzhiev, M. Kh.; Ragimkhanov, G. B.; Al-Shatravi, Ali J. G.

2012-01-01

The expansion of the cathode spot and the generation of shock waves during the formation and development of a pulsed volume discharge in atmospheric-pressure helium were studied by analyzing the emission spectra of the cathode plasma and the spatiotemporal behavior of the plasma glow. The transition of a diffuse volume discharge in a centimeter-long gap into a high-current diffuse mode when the gas pressure increased from 1 to 5 atm and the applied voltage rose from the statistical breakdown voltage to a 100% overvoltage was investigated. Analytical expressions for the radius of the cathode spot and its expansion velocity obtained in the framework of a spherically symmetric model agree satisfactorily with the experimental data.

A three-dimensional breakdown model of SOI lateral power transistors with a circular layout

International Nuclear Information System (INIS)

Guo Yufeng; Wang Zhigong; Sheu Gene

2009-01-01

This paper presents an analytical three-dimensional breakdown model of SOI lateral power devices with a circular layout. The Poisson equation is solved in cylindrical coordinates to obtain the radial surface potential and electric field distributions for both fully- and partially-depleted drift regions. The breakdown voltages for N + N and P + N junctions are derived and employed to investigate the impact of cathode region curvature. A modified RESURF criterion is proposed to provide a design guideline for optimizing the breakdown voltage and doping concentration in the drift region in three dimensional space. The analytical results agree well with MEDICI simulation results and experimental data from earlier publications. (semiconductor devices)

Multi-pulsed intense electron beam emission from velvet, carbon fibers, carbon nano-tubes and dispenser cathodes

International Nuclear Information System (INIS)

Xia Liansheng; Yang Anmin; Chen Yi; Zhang Huang; Liu Xingguang; Li Jin; Jiang Xiaoguo; Zhang Kaizhi; Shi Jinshui; Deng Jianjun; Zhang Linwen

2010-01-01

The experimental results of studies of four kinds of cathode emitting intense electron beams are demonstrated under multi-pulsed mode based on an experimental setup including two multi-pulse high voltage sources. The tested cathodes include velvet, carbon fibers, carbon nano-tubes (CNTs) and dispenser cathodes. The results indicate that all four are able to emit multi-pulsed beams. For velvet, carbon fiber and CNTs, the electron induced cathode plasma emission may be the main process and this means that there are differences in beam parameters from pulse to pulse. For dispenser cathodes tested in the experiment, although there is a little difference from pulse to pulse for some reason, thermal-electric field emission may be the main process. (authors)

Microwave generation enhancement of X-band CRBWO by use of coaxial dual annular cathodes

Directory of Open Access Journals (Sweden)

Yan Teng

2013-07-01

Full Text Available This paper presents an approach that greatly enhances both the output power and the conversion efficiency of the coaxial relativistic backward wave oscillator (CRBWO by using coaxial dual annular cathodes, which increases the diode current rather than the diode voltage. The reasons for the maladjustment of CRBWO under a high diode voltage are analyzed theoretically. It is found that by optimization of the diode structure, the shielding effect of the space charge of the outer beams on the inner cathode can be alleviated effectively and dual annular beams with the same kinetic energy can be explosively emitted in parallel. The coaxial reflector can enhance the conversion efficiency by improving the premodulation of the beams. The electron dump on the inner conductor ensures that the electron beams continue to provide kinetic energy to the microwave output until they vanish. Particle-in-cell (PIC simulation results show that generation can be enhanced up to an output power level of 3.63 GW and conversion efficiency of 45% at 8.97 GHz under a diode voltage of 659 kV and current of 12.27 kA. The conversion efficiency remains above 40% and the output frequency variation is less than 100 MHz over a voltage range of more than 150 kV. Also, the application of the coaxial dual annular cathodes means that the diode impedance is matched to that of the transmission line of the accelerators. This impedance matching can effectively eliminate power reflection at the diode, and thus increase the energy efficiency of the entire system.

Pulsed electron beam generation with fast repetitive double pulse system

Energy Technology Data Exchange (ETDEWEB)

Sharma, Surender Kumar; Deb, Pankaj; Shyam, Anurag, E-mail: surender80@gmail.com [Energetics and Electromagnetics Division, Bhabha Atomic Research Centre, Visakhapatnam (India); Sharma, Archana [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Mumbai (India)

2014-07-01

Longer duration high voltage pulse (∼ 100 kV, 260 ns) is generated and reported using helical pulse forming line in compact geometry. The transmission line characteristics of the helical pulse forming line are also used to develop fast repetition double pulse system with very short inter pulse interval. It overcomes the limitations caused due to circuit parameters, power supplies and load characteristics for fast repetitive high voltage pulse generation. The high voltage double pulse of 100 kV, 100 ns with an inter pulse repetition interval of 30 ns is applied across the vacuum field emission diode for pulsed electron beam generation. The electron beam is generated from cathode material by application of negative high voltage (> 100 kV) across the diode by explosive electron emission process. The vacuum field emission diode is made of 40 mm diameter graphite cathode and SS mesh anode. The anode cathode gap was 6 mm and the drift tube diameter was 10 cm. The initial experimental results of pulsed electron beam generation with fast repetitive double pulse system are reported and discussed. (author)

Contribution to crystallographical and mechanical analysis of molybdenum coatings prepared by magnetron cathode sputtering

International Nuclear Information System (INIS)

Bosland, P.

1989-07-01

Molybdenum coatings with different compression stresses are obtained by magnetron cathode sputtering by varying negative voltage applied to the substrate during deposition. Stress evolution, crystal texture and argon content are studied [fr

A high-DC-voltage GaAs photoemission gun: Transverse emittance and momentum spread measurements

International Nuclear Information System (INIS)

Engwall, D.; Bohn, C.; Cardman, L.

1997-01-01

We have built a high-DC-voltage photoemission gun and a diagnostic beamline permitting us to measure rms transverse emittance (ε x ) and rms momentum spread (δ) of short-duration electron pulses produced by illuminating the cathode with light from a mode-locked, frequency-doubled Nd:YLF laser. The electron gun is a GaAs photocathode source designed to operate at 500kV. We have measured ε x and δ for conditions ranging from emittance-dominated to space-charge-dominated. We report these measurements as functions of microbunch charge for different beam radii, pulse lengths, and voltages/field gradients at the cathode, and compare them with PARMELA calculations

Evaluation of prototype silicon drift detectors

International Nuclear Information System (INIS)

Ellison, J.; Hall, G.; Roe, S.; Lucas, A.

1988-01-01

Operating characteristics of several prototypes of silicon drift detectors are investigated. Detectors are made of unpolished silicon produced by the zone melting method and characterized by n-type conductivity and specific resistance of 3.6-4.6 kOhmxcm. The detectors comprise 40 parallel bands of 200 μm width and 1 cm length separated by 50 μm intervals. Data characterizing the potential distribution near anodes under the operating bias voltage, dependences of capacities and leakage as well as the detector space resolution

High-Current Cold Cathode Employing Diamond and Related Materials

Energy Technology Data Exchange (ETDEWEB)

Hirshfield, Jay L. [Omega-P, Inc., New Haven, CT (United States)

2014-10-22

The essence of this project was for diamond films to be deposited on cold cathodes to improve their emission properties. Films with varying morphology, composition, and size of the crystals were deposited and the emission properties of the cathodes that utilize such films were studied. The prototype cathodes fabricated by the methods developed during Phase I were tested and evaluated in an actual high-power RF device during Phase II. These high-power tests used the novel active RF pulse compression system and the X-band magnicon test facility at US Naval Research Laboratory. In earlier tests, plasma switches were employed, while tests under this project utilized electron-beam switching. The intense electron beams required in the switches were supplied from cold cathodes embodying diamond films with varying morphology, including uncoated molybdenum cathodes in the preliminary tests. Tests with uncoated molybdenum cathodes produced compressed X-band RF pulses with a peak power of 91 MW, and a maximum power gain of 16.5:1. Tests were also carried out with switches employing diamond coated cathodes. The pulse compressor was based on use of switches employing electron beam triggering to effect mode conversion. In experimental tests, the compressor produced 165 MW in a ~ 20 ns pulse at ~18× power gain and ~ 140 MW at ~ 16× power gain in a 16 ns pulse with a ~ 7 ns flat-top. In these tests, molybdenum blade cathodes with thin diamond coatings demonstrated good reproducible emission uniformity with a 100 kV, 100 ns high voltage pulse. The new compressor does not have the limitations of earlier types of active pulse compressors and can operate at significantly higher electric fields without breakdown.

Comparison of experimental target currents with analytical model results for plasma immersion ion implantation

International Nuclear Information System (INIS)

En, W.G.; Lieberman, M.A.; Cheung, N.W.

1995-01-01

Ion implantation is a standard fabrication technique used in semiconductor manufacturing. Implantation has also been used to modify the surface properties of materials to improve their resistance to wear, corrosion and fatigue. However, conventional ion implanters require complex optics to scan a narrow ion beam across the target to achieve implantation uniformity. An alternative implantation technique, called Plasma Immersion Ion Implantation (PIII), immerses the target into a plasma. The ions are extracted from the plasma directly and accelerated by applying negative high-voltage pulses to the target. An analytical model of the voltage and current characteristics of a remote plasma is presented. The model simulates the ion, electron and secondary electron currents induced before, during and after a high voltage negative pulse is applied to a target immersed in a plasma. The model also includes analytical relations that describe the sheath expansion and collapse due to negative high voltage pulses. The sheath collapse is found to be important for high repetition rate pulses. Good correlation is shown between the model and experiment for a wide variety of voltage pulses and plasma conditions

Nickel-based electrodeposits as potential cathode catalysts for hydrogen production by microbial electrolysis

Science.gov (United States)

Mitov, M.; Chorbadzhiyska, E.; Nalbandian, L.; Hubenova, Y.

2017-07-01

The development of cost-effective cathodes, operating at neutral pH and ambient temperatures, is a crucial challenge for the practical application of microbial electrolysis cell (MEC) technology. In this study, NiW and NiMo co-deposits produced by electroplating on Ni-foam are explored as cathodes in MEC. The fabricated electrodes exhibit higher corrosion stability and enhanced electrocatalytic activity towards hydrogen evolution reaction in neutral electrolyte compared to the bare Ni-foam. NiW/Ni-foam electrodes possess six times higher intrinsic catalytic activity, estimated from data obtained by linear voltammetry and chronoamperometry. The newly developed electrodes are applied as cathodes in single-chamber membrane-free MEC reactors, inoculated with wastewater and activated sludge from a municipal wastewater treatment plant. Cathodic hydrogen recovery of 79% and 89% by using NiW and NiMo cathodes, respectively, is achieved at applied voltage of 0.6 V. The obtained results reveal potential for practical application of used catalysts in MEC.

Back bombardment for dispenser and lanthanum hexaboride cathodes

Directory of Open Access Journals (Sweden)

Mahmoud Bakr

2011-06-01

Full Text Available The back bombardment (BB effect limits wide usage of thermionic rf guns. The BB effect induces not only ramping-up of a cathode’s temperature and beam current, but also degradation of cavity voltage and beam energy during a macropulse. This paper presents a comparison of the BB effect for the case of dispenser tungsten-base (DC and lanthanum hexaboride (LaB_{6} thermionic rf gun cathodes. For each, particle simulation codes are used to simulate the BB effect and electron beam dynamics in a thermionic rf gun cathode. A semiempirical equation is also used to investigate the stopping range and deposited heat power of BB electrons in the cathode material. A numerical simulation method is used to calculate the change of the cathode temperature and current density during a single macropulse. This is done by solving two differential equations for the rf gun cavity equivalent circuit and one-dimensional thermal diffusion equation. High electron emission and small beam size are required for generation of a high-brightness electron beam, and so in this work the emission properties of the cathode are taken into account. Simulations of the BB effect show that, for a pulse of 6  μs duration, the DC cathode experiences a large change in the temperature compared with LaB_{6}, and a change in current density 6 times higher. Validation of the simulation results is performed using experimental data for beam current beyond the gun exit. The experimental data is well reproduced using the simulation method.

Substrate-bias effect on the breakdown characteristic in a new silicon high-voltage device structure

International Nuclear Information System (INIS)

Li Qi; Wang Weidong; Zhao Qiuming; Wei Xueming

2012-01-01

A novel silicon double-RESURF LDMOS structure with an improved breakdown characteristic by substrate bias technology (SB) is reported. The P-type epitaxial layer is embedded between an N-type drift region and an N-type substrate to block the conduction path in the off-state and change the distributions of the bulk electric field. The substrate bias strengthens the charge share effect of the drift region near the source, and the vertical electric field peak under the drain is decreased, which is especially helpful in improving the vertical breakdown voltage in a lateral power device with a thin drift region. The numerical results by MEDICI indicate that the breakdown voltage of the proposed device is increased by 97% compared with a conventional LDMOS, while maintaining a lowon-resistance. (semiconductor devices)

Experimental investigation on the motion of cathode spots in removing oxide film on metal surface by vacuum arc

International Nuclear Information System (INIS)

Shi Zongqian; Jia Shenli; Wang Lijun; Yuan Qingjun; Song Xiaochuan

2008-01-01

The motion of vacuum arc cathode spots has a very important influence on the efficiency of removing the oxide film on the metal surface. In this paper, the characteristics of cathode spot motion are investigated experimentally. Experiments were conducted in a detachable vacuum chamber with ac (50 Hz) arc current of 1 kA (rms). A stainless steel plate covered by an oxide layer was used as the cathode. The motion of cathode spots during the descaling process was photographed by a high-speed digital camera with an exposure time of 2 μs. Experimental results indicate that the motion of cathode spots is influenced by the interaction among individual cathode jets and the position of the anode as well as the surface condition. The waveform of arc voltage is also influenced by the motion of cathode spots

On the Theory of Compensation in Lithium drifted Semiconductor Detectors

Energy Technology Data Exchange (ETDEWEB)

Lauber, A

1969-04-15

The lithium ion drift method produces detectors with a highly but not perfectly compensated intrinsic region. The amount of fixed space charge left in the depleted layer and its dependence on drift and clean-up parameters is of great practical interest. The imperfect compensation is mainly due to the presence in the depletion layer of thermally generated electron-hole pairs swept apart by the voltage applied to the detector during drift. A theoretical model is developed which takes into account the influence on the fixed space charge of mobile carrier generation and recombination. When recombination of free electrons and holes is negligible the theory predicts the formation of linear space charge gradients. When recombination is strong a constant space charge throughout a large part of the compensated layer may result. The theoretical calculations are compared with experimental findings. The influence of space charge on detector performance is discussed.

Non-isothermal electrochemical model for lithium-ion cells with composite cathodes

Science.gov (United States)

Basu, Suman; Patil, Rajkumar S.; Ramachandran, Sanoop; Hariharan, Krishnan S.; Kolake, Subramanya Mayya; Song, Taewon; Oh, Dukjin; Yeo, Taejung; Doo, Seokgwang

2015-06-01

Transition metal oxide cathodes for Li-ion batteries offer high energy density and high voltage. Composites of these materials have shown excellent life expectancy and improved thermal performance. In the present work, a comprehensive non-isothermal electrochemical model for a Lithium ion cell with a composite cathode is developed. The present work builds on lithium concentration-dependent diffusivity and thermal gradient of cathode potential, obtained from experiments. The model validation is performed for a wide range of temperature and discharge rates. Excellent agreement is found for high and room temperature with moderate success at low temperatures, which can be attributed to the low fidelity of material properties at low temperature. Although the cell operation is limited by electronic conductivity of NCA at room temperature, at low temperatures a shift in controlling process is seen, and operation is limited by electrolyte transport. At room temperature, the lithium transport in Cathode appears to be the main source of heat generation with entropic heat as the primary contributor at low discharge rates and ohmic heat at high discharge rates respectively. Improvement in electronic conductivity of the cathode is expected to improve the performance of these composite cathodes and pave way for its wider commercialization.

Improved Electron Yield and Spin-Polarization from III-V Photocathodes via Bias Enhanced Carrier Drift: Final Report

International Nuclear Information System (INIS)

Mulhollan, Gregory A.

2006-01-01

In this DOE STTR program, Saxet Surface Science, with the Stanford Linear Accelerator Center as partner, designed, built and tested photocathode structures such that optimal drift-enhanced spin-polarization from GaAs based photoemitters was achieved with minimal bias supply requirements. The forward bias surface grid composition was optimized for maximum polarization and yield, together with other construction parameters including doping profile. This program has culminated in a cathode bias structure affording increased electron spin polarization when applied to III-V based photocathodes. The optimized bias structure has been incorporated into a cathode mounting and biasing design for use in a polarized electron gun.

Effect of a calcium cathode on water-based nanoparticulate solar cells

Science.gov (United States)

Vaughan, Ben; Stapleton, Andrew; Xue, Bofei; Sesa, Elisa; Zhou, Xiaojing; Bryant, Glenn; Belcher, Warwick; Dastoor, Paul

2012-07-01

Water-based nanoparticulate (NP) and bulk heterojunction (BHJ) organic photovoltaic (OPV) devices based on blends of poly(9,9-dioctylfluorene-co-N,N-bis(4-butylphenyl)-N,Ndiphenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-co-benzothiadiazole (F8BT) have been fabricated with aluminium and calcium/aluminium cathodes. The NP devices exhibit power conversion efficiencies (PCEs) that are double that of the corresponding BHJ device. Moreover, the addition of calcium into the cathode structure results in a dramatic increase in open circuit voltage and PCEs approaching 1% for water-based polyfluorene OPV devices.

Very broad beam metal ion source for large area ion implantation application

International Nuclear Information System (INIS)

Brown, I.; Anders, S.; Dickinson, M.R.; MacGill, R.A.; Yao, X.

1993-01-01

The authors have made and operated a very broad beam version of vacuum arc ion source and used it to carry out high energy metal ion implantation of a particularly large substrate. A multiple-cathode vacuum arc plasma source was coupled to a 50 cm diameter beam extractor (multiple aperture, accel-decel configuration) operated at a net extraction voltage of up to 50 kV. The metal ion species chosen were Ni and Ta. The mean ion charge state for Ni and Ta vacuum arc plasmas is 1.8 and 2.9, respectively, and so the mean ion energies were up to about 90 and 145 keV, respectively. The ion source was operated in a repetitively pulsed mode with pulse length 250 μs and repetition rate several pulses per second. The extracted beam had a gaussian profile with FWHM about 35 cm, giving a nominal beam area of about 1,000 cm 2 . The current of Ni or Ta metal ions in the beam was up to several amperes. The targets for the ion implantation were a number of 24-inch long, highly polished Cu rails from an electromagnetic rail gun. The rails were located about 80 cm away from the ion source extractor grids, and were moved across a diameter of the vessel in such a way as to maximize the uniformity of the implant along the rail. The saturation retained dose for Ta was limited to about 4 x 10 16 cm -2 because of the rather severe sputtering, in accordance with the theoretical expectations for these implantation conditions. Here they describe the ion source, the implantation procedure, and the kinds of implants that can be produced in this way

Depth distribution of nitrogen in silicon from plasma ion implantation

International Nuclear Information System (INIS)

Vajo, J.J.; Williams, J.D.; Wei, R.; Wilson, R.G.; Matossian, J.N.

1994-01-01

Plasma Ion Implantation (PII) is an ion implantation technique that eliminates the line-of-sight restriction of conventional ion-beam implantation and therefore allows for cost effective surface modification of large-scale objects or large-number of small-scale objects. In PII, a part to be implanted is immersed in a low-pressure (10 -4 --10 -5 Torr), partially-ionized plasma that surrounds the part with a plasma sheath. The part is negatively pulse biased up to 100 keV using a repetitive train (100--1,000 Hz) of short-duration (10--40 μsec) voltage pulses. The applied voltage develops across the sheath and accelerates plasma ions into the surface, implanting them omnidirectionally and simultaneously over the entire surface of the part. The depth distribution of the implanted ions influences the extent and type of surface modification achieved and depends upon many factors. These include three rise and fall time of the voltage-pulse waveform, the voltage-pulse amplitude, the ion specie, the ion density, and the temperature of the target. Understanding the contributions to the depth distribution from each of these factors will enable prediction of conditions that will be useful for implantation of large complex parts. To investigate the contributions to the measured depth distributions from these factors nitrogen, predominantly as N + 2 , has been implanted into silicon using PII at 50 and 100 keV (25 and 50 keV per N atom). The implanted depth distributions have been determined using secondary ion mass spectroscopy and Auger electron spectroscopy depth profiling. The distributions differ from the typical, approximately Gaussian, profiles that result from conventional mass selected monoenergetic ion beam implantation. In comparison with ion beam implants and numerical simulations the profiles appear ''filled-in'' with an approximately constant nitrogen concentration for depths less than the expected average ion range

Sheath and arc-column voltages in high-pressure arc discharges

International Nuclear Information System (INIS)

Benilov, M S; Benilova, L G; Li Heping; Wu Guiqing

2012-01-01

Electrical characteristics of a 1 cm-long free-burning atmospheric-pressure argon arc are calculated by means of a model taking into account the existence of a near-cathode space-charge sheath and the discrepancy between the electron and heavy-particle temperatures in the arc column. The computed arc voltage exhibits a variation with the arc current I similar to the one revealed by the experiment and exceeds experimental values by no more than approximately 2 V in the current range 20-175 A. The sheath contributes about two-thirds or more of the arc voltage. The LTE model predicts a different variation of the arc voltage with I and underestimates the experimental values appreciably for low currents but by no more than approximately 2 V for I ≳ 120 A. However, the latter can hardly be considered as a proof of unimportance of the space-charge sheath at high currents: the LTE model overestimates both the resistance of the bulk of the arc column and the resistance of the part of the column that is adjacent to the cathode, and this overestimation to a certain extent compensates for the neglect of the voltage drop in the sheath. Furthermore, if the latter resistance were evaluated in the framework of the LTE model in an accurate way, then the overestimation would be still much stronger and the obtained voltage would significantly exceed those observed in the experiment.

Simultaneous selection of soil electroactive bacterial communities associated to anode and cathode in a two-chamber Microbial Fuel Cell

Science.gov (United States)

Chiellini, Carolina; Bacci, Giovanni; Fani, Renato; Mocali, Stefano

2016-04-01

Different bacteria have evolved strategies to transfer electrons over their cell surface to (or from) their extracellular environment. This electron transfer enables the use of these bacteria in bioelectrochemical systems (BES) such as Microbial Fuel Cells (MFCs). In MFC research the biological reactions at the cathode have long been a secondary point of interest. However, bacterial biocathodes in MFCs represent a potential advantage compared to traditional cathodes, for both their low costs and their low impact on the environment. The main challenge in biocathode set-up is represented by the selection of a bacterial community able to efficiently accept electrons from the electrode, starting from an environmental matrix. In this work, a constant voltage was supplied on a two-chamber MFC filled up with soil over three weeks in order to simultaneously select an electron donor bacterial biomass on the anode and an electron acceptor biomass on the cathode, starting from the same soil. Next Generation Sequencing (NGS) analysis was performed to characterize the bacterial community of the initial soil, in the anode, in the cathode and in the control chamber not supplied with any voltage. Results highlighted that both the MFC conditions and the voltage supply affected the soil bacterial communities, providing a selection of different bacterial groups preferentially associated to the anode (Betaproteobacteria, Bacilli and Clostridia) and to the cathode (Actinobacteria and Alphaproteobacteria). These results confirmed that several electroactive bacteria are naturally present within a top soil and, moreover, different soil bacterial genera could provide different electrical properties.

Influence of the radial spacing between cathodes on the surface composition of iron samples sintered by hollow cathode electric discharge

Directory of Open Access Journals (Sweden)

Brunatto S.F.

2001-01-01

Full Text Available The present work reports an investigation of the influence of the radial spacing between cathodes on the iron sintering process by hollow cathode electrical discharge, with surface enrichment of the alloying elements Cr and Ni. Pressed cylindrical samples of 9.5 mm diameter and density of 7.0 ± 0.1 g/cm³ were prepared by compaction of Ancorsteel 1000C iron powder. These samples, constituting the central cathode, were positioned concentrically in the interior of an external cathode machined from a tube of stainless steel AISI 310 (containing: 25% Cr, 16% Ni, 1.5% Mn, 1.5% Si, 0.03% C and the remainder Fe. Sintering was done at 1150 °C, for 120 min, utilizing radial spacings between the central and hollow cathodes of 3, 6 and 9 mm and a gas mixture of 80% Ar and 20% H2, with a flow rate of 5 cm³/s at a pressure of 3 Torr. The electric discharge was generated using a pulsed voltage power source, with a period of 200 mus. The radial spacing had only a slight influence on the quantity of atoms of alloying elements deposited and diffused on the surface of the sample. Analysis with a microprobe showed the presence of chrome (up to 4.0% and nickel (up to 3.0%, in at. % at the surface of the samples. This surface enrichment can be attributed to the mechanism of sputtering of the metallic atoms present in the external cathode, with the deposition of these elements on the sample surface and consequent diffusion within the sample.

Beam Aborts in PEP-II Rings and Lingering Drift Chamber Currents

International Nuclear Information System (INIS)

Meshkat, N.

2004-01-01

The BABAR detector at SLAC was designed to study CP-violation in B-meson decays from electron-positron collisions in the PEP-II electron-positron storage rings. Background radiation in the High Energy Ring (HER) and Low Energy Ring (LER) of PEP-II has the potential to damage the sensitive equipment in the BABAR detector. As a result, the beams in the HER and LER can be aborted to prevent such damage. In the span of a few microseconds, the HER and LER currents drop from, for example, 1450 micro Amps and 2300 micro Amps, respectively, to zero. At this time the voltage in the Drift Chamber is rapidly ramped down from a potential of 1930 V to a safe potential of 800 V, thus we would expect the currents in the Drift Chamber to quickly go to zero once the beams are aborted. However, we observe an average 15 second delay in the measured time it takes for all current in the Drift Chamber to fall below 1 micro Amp. This delay has been hypothesized as an instrumentation issue and not as a physical phenomenon. The specific sources of this error are still not completely known, but analysis suggests that it results from the interplay of the CAEN High Voltage supplies and the EPICS system and/or limitations within those systems

Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries

International Nuclear Information System (INIS)

Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon; Chang, Wonyoung

2014-01-01

We utilize transmission electron microscopy in conjunction with electron energy loss spectroscopy to investigate local degradation that occurs in Li x Ni 0.8 Co 0.15 Al 0.05 O 2 cathode materials (NCA) after 30 cycles with cutoff voltages of 4.3 V and 4.8 V at 55 °C. NCA has a homogeneous crystallographic structure before electrochemical reactions; however, we observed that 30 cycles of charge/discharge reactions induced inhomogeneity in the crystallographic and electronic structures and also introduced porosity particularly at surface area. These changes were more noticeable in samples cycled with higher cutoff voltage of 4.8 V. Effect of operating temperature was further examined by comparing electronic structures of oxygen of the NCA particles cycled at both room temperature and 55 °C. The working temperature has a greater impact on the NCA cathode materials at a cutoff voltage of 4.3 V that is the practical the upper limit voltage in most applications, while a cutoff voltage of 4.8 V is high enough to cause surface degradation even at room temperature.

Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon; Chang, Wonyoung, E-mail: cwy@kist.re.kr [Center for Energy Convergence, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of)

2014-09-08

We utilize transmission electron microscopy in conjunction with electron energy loss spectroscopy to investigate local degradation that occurs in Li{sub x}Ni{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathode materials (NCA) after 30 cycles with cutoff voltages of 4.3 V and 4.8 V at 55 °C. NCA has a homogeneous crystallographic structure before electrochemical reactions; however, we observed that 30 cycles of charge/discharge reactions induced inhomogeneity in the crystallographic and electronic structures and also introduced porosity particularly at surface area. These changes were more noticeable in samples cycled with higher cutoff voltage of 4.8 V. Effect of operating temperature was further examined by comparing electronic structures of oxygen of the NCA particles cycled at both room temperature and 55 °C. The working temperature has a greater impact on the NCA cathode materials at a cutoff voltage of 4.3 V that is the practical the upper limit voltage in most applications, while a cutoff voltage of 4.8 V is high enough to cause surface degradation even at room temperature.

Optimal pulse modulator design criteria for plasma source ion implanters

International Nuclear Information System (INIS)

Reass, W.

1993-01-01

This paper describes what are believed to be the required characteristics of a high-voltage modulator for efficient and optimal ion deposition from the ''Plasma Source Ion Implantation'' (PSII) process. The PSII process is a method to chemically or physically alter and enhance surface properties of objects by placing them in a weakly ionized plasma and pulsing the object with a high negative voltage. The attracted ions implant themselves and form chemical bonds or are interstitially mixed with the base material. Present industrial uses of implanted objects tends to be for limited-production, high-value-added items. Traditional implanting hardware uses the typical low-current (ma) semiconductor ''raster scan'' implanters. The targets must also be manipulated to maintain a surface normal to the ion beam. The PSII method can provide ''bulk'' equipment processing on a large industrial scale. For the first generation equipment, currents are scaled from milliamps to hundreds of amps, voltages to -175kV, at kilohertz rep-rates, and high plasma ion densities

Effect of self-bias voltage on the wettability, chemical functionality and nanomechanical properties of hexamethyldisiloxane films

Energy Technology Data Exchange (ETDEWEB)

Albuquerque, M.D.F. [Program of Metallurgical and Materials Engineering, COPPE, Federal University of Rio de Janeiro (UFRJ), P.O. Box 68505, 21941-972 Rio de Janeiro, RJ (Brazil); Santos, E. [Program of Metallurgical and Materials Engineering, COPPE, Federal University of Rio de Janeiro (UFRJ), P.O. Box 68505, 21941-972 Rio de Janeiro, RJ (Brazil); Faculty of Civil Engineering, University Center of Volta Redonda (UniFOA), Volta Redonda, RJ (Brazil); Perdone, R.R.T. [Program of Metallurgical and Materials Engineering, COPPE, Federal University of Rio de Janeiro (UFRJ), P.O. Box 68505, 21941-972 Rio de Janeiro, RJ (Brazil); Simao, R.A., E-mail: renata@metalmat.ufrj.br [Program of Metallurgical and Materials Engineering, COPPE, Federal University of Rio de Janeiro (UFRJ), P.O. Box 68505, 21941-972 Rio de Janeiro, RJ (Brazil)

2014-08-01

Copper and silicon substrates were coated by chemical vapor deposition using hexamethyldisiloxane (HMDSO) as the precursor gas. Substrates were placed both at the anode and cathode of a glow discharge reactor, and films were deposited using different self-bias voltages. This study focuses on comparing the differences between the hydrophilicity, polymeric character, chemical structure and nanomechanical properties of HMDSO films produced at the cathode and anode of the reactor at different self-bias voltages. Fourier transform infrared spectroscopy and Raman confocal spectroscopy indicated a significant increase in the content of organic groups when films were deposited at the anode. Analyzing the nanomechanical properties of the cathode and anode films indicated that the penetration depth was higher for samples prepared at the cathode (lower hardness) compared with the samples produced at the anode. The measured contact angles indicated that all samples became hydrophobic with water contact angles close to 100°; however, a different lyophobic character was observed when diiodomethane was used. Films produced at the anode with diiodomethane exhibited higher contact angles than did films produced at the cathode. - Highlights: • Hexamethyldisiloxane (HMDSO) films deposited by CVD on Si and Cu substrates • HMDSO films produced at the anode have greater content of organic SiO{sub 4} groups. • Films produced at the anode are harder than those deposited at the cathode. • HMDSO films produced at the cathode exhibited higher elastic recovery. • All films are hydrophobic (θ close to 100°)

Effect of self-bias voltage on the wettability, chemical functionality and nanomechanical properties of hexamethyldisiloxane films

International Nuclear Information System (INIS)

Albuquerque, M.D.F.; Santos, E.; Perdone, R.R.T.; Simao, R.A.

2014-01-01

Copper and silicon substrates were coated by chemical vapor deposition using hexamethyldisiloxane (HMDSO) as the precursor gas. Substrates were placed both at the anode and cathode of a glow discharge reactor, and films were deposited using different self-bias voltages. This study focuses on comparing the differences between the hydrophilicity, polymeric character, chemical structure and nanomechanical properties of HMDSO films produced at the cathode and anode of the reactor at different self-bias voltages. Fourier transform infrared spectroscopy and Raman confocal spectroscopy indicated a significant increase in the content of organic groups when films were deposited at the anode. Analyzing the nanomechanical properties of the cathode and anode films indicated that the penetration depth was higher for samples prepared at the cathode (lower hardness) compared with the samples produced at the anode. The measured contact angles indicated that all samples became hydrophobic with water contact angles close to 100°; however, a different lyophobic character was observed when diiodomethane was used. Films produced at the anode with diiodomethane exhibited higher contact angles than did films produced at the cathode. - Highlights: • Hexamethyldisiloxane (HMDSO) films deposited by CVD on Si and Cu substrates • HMDSO films produced at the anode have greater content of organic SiO 4 groups. • Films produced at the anode are harder than those deposited at the cathode. • HMDSO films produced at the cathode exhibited higher elastic recovery. • All films are hydrophobic (θ close to 100°)

Production of cathode pad chambers for 2nd muon tracking station of ALICE

International Nuclear Information System (INIS)

Danish Azmi, M.; Irfan, M.; Khan, I.A.; Bose, S.; Chattopadhyay, S.; Das, D.; Das, I.; Datta, P.; Dutt-Mazumder, A.K.; Jana, S.; Pal, S.; Paul, L.; Roy, P.; Sinha, T.; Sinha, B.C.

2005-01-01

The second tracking station of dimuon spectrometer of ALICE comprises of 8 cathode pad chambers whose inner radius is 23.7 cm and outer radius is 117 cm. The anode to cathode separation is 2.5 cm and the operating voltage of these chambers is around 1675 volt at an atmospheric pressure of 80% Ar + 20% CO 2 . At this operating point, the gain of the chamber is around 10 5 . In this report the quality control tests on the first production chamber have been reported

Particle-in-cell simulation of electron trajectories and irradiation uniformity in an annular cathode high current pulsed electron beam source

Energy Technology Data Exchange (ETDEWEB)

Jiang, Wei; Wang, Langping, E-mail: aplpwang@hit.edu.cn; Zhou, Guangxue; Wang, Xiaofeng

2017-02-01

Highlights: • The transmission process of electrons and irradiation uniformity was simulated. • Influence of the irradiation parameters on irradiation uniformity are discussed. • High irradiation uniformity can be obtained in a wide processing window. - Abstract: In order to study electron trajectories in an annular cathode high current pulsed electron beam (HCPEB) source based on carbon fiber bunches, the transmission process of electrons emitted from the annular cathode was simulated using a particle-in-cell model with Monte Carlo collisions (PIC-MCC). The simulation results show that the intense flow of the electrons emitted from the annular cathode are expanded during the transmission process, and the uniformity of the electron distribution is improved in the transportation process. The irradiation current decreases with the irradiation distance and the pressure, and increases with the negative voltage. In addition, when the irradiation distance and the cathode voltage are larger than 40 mm and −15 kV, respectively, a uniform irradiation current distribution along the circumference of the anode can be obtained. The simulation results show that good irradiation uniformity of circular components can be achieved by this annular cathode HCPEB source.

Ethanol tolerant Pt-alloy cathodes for DEFC applications

Energy Technology Data Exchange (ETDEWEB)

Rodriguez Valera, F.J. [CINVESTAV Unidad Saltillo, Coahuila (Mexico). Grupo de Recursos Minerales y Energeticos; Savadogo, O. [Ecole Polytechnique de Montreal, Montreal, PQ (Canada). Laboratoire de nouveaux materiaux pour l' energie et l' electrochimie

2008-07-01

Direct ethanol fuel cells (DEFCs) based on Ru/C cathodes have interesting current density versus cell voltage behaviour. In particular, the selectivity towards the oxygen reduction reaction (ORR) in acid medium in the presence of ethanol was improved when this cathode material was used. This study quantified the degree of tolerance to ethanol and the electrocatalytic activity for the ORR. It compared the specific activity towards the ORR for Pt1Co1/C and Pt3Cr1/C. The study showed that these cathodes have a high tolerance to this alcohol and demonstrated the good performance of this type of Pt-alloy in a DEFC as oxygen reduction cathodes. The performance of the Pt1Co1/C alloy was shown to be better than the Pt3Cr1/C, even when the former had a lower Pt content. The enhanced catalytic behaviour of the PtCo/C alloy can be attributed to the higher degree of allying or a smaller mean particle size and a larger surface area. Polarization measurements with relatively high ethanol concentrations confirmed the good catalytic behaviour of the PtCo/C alloy as cathode in a DEFC operating at 90 degrees C. Current work is focusing on the variation of Co content in the alloy structure and the analysis of this change in terms of ORR activity, tolerance to ethanol and electrochemical behaviour in a DEFC. 10 refs., 5 figs.

Synchronization trigger for HSFC in the optical diagnosis of intense electron beam cathodes

International Nuclear Information System (INIS)

Yang Jie; Shu Ting; Zhang Jun; Yang Jianhua; Liu Lie; Yin Yi; Luo Ling

2010-01-01

This paper presents an intense electron beam cathodes optical diagnosis platform, which consists of an accelerator using a water-dielectric helical pulse forming line (PFL) and a high speed framing camera (HSFC-PRO) with an minimum exposure of 3 ns. HSFC-PRO must work synchronously with the explosive process of the intense electron beam cathodes in order to obtain correct data. On one hand, the high voltage electrical pulse from the PFL is delayed by a water-dielectric helix line with a nearly 110ns electrical length. On the other hand, The synchronization trigger signal for the HSFC-PRO is obtained from the pre d elayed high voltage electrical pulse from the PFL. A TTL signal (5 V) with rising edge is required to trigger the HSFC. The rise time (10% to 90%) should be <20ns. As a result, the negative-edge attenuated electrical pulse with a about 25 ns rise time from the PFL can not trigger the HSFC immediately.Consequently, the polarity of the attenuated high voltage electrical pulse from the PFL is reversed by a pulse transformer. Then it is converted subsequently into a TTL signal (5 V) with rising edge via a monostable multivibrator , The rise time (10% to 90%) is <5 ns, which is suitable for HSFC absequently. This established optical diagnosis platform can supply an electrical pulse with its output voltage of 200-400 kV, risetime of ∼35ns and pulse width(FWHM) of ∼110ns. By means of delaying the electrical pulse, the synchronization trigger problem of the HSFC-PRO has been solved properly, with correlative time precision of about ns level, which sets a running start for the following intensive research of explosive emission cathodes. (authors)

Child-Langmuir law for cathode sheath of glow discharge in CO2

International Nuclear Information System (INIS)

Lisovskiy, V.A.; Krol, H.H.; Osmayev, R.O.; Yegorenkov, V.D.

2016-01-01

This work is devoted to the determination of the law that may be applicable to the description of the cathode sheath in CO 2 . To this end three versions of the Child-Langmuir law have been considered - a collision free one (for the ions moving through a cathode sheath without collisions with gas molecules) as well as two collision- related versions - one for a constant mean free path of positive ions and one for a constant mobility of positive ions. The current-voltage characteristics and the cathode sheath thickness of the glow discharge in CO 2 have been simultaneously measured in the pressure range from 0.05 to 1 Torr and with the discharge current values up to 80 mA. In the whole range of the discharge conditions we have studied the cathode sheath characteristics are found to obey correctly only to the Child-Langmuir law version with a constant ion mobility.

Li-rich layer-structured cathode materials for high energy Li-ion batteries

Science.gov (United States)

Li, Liu; Lee, Kim Seng; Lu, Li

2014-08-01

Li-rich layer-structured xLi2MnO3 ṡ (1 - x)LiMO2 (M = Mn, Ni, Co, etc.) materials have attracted much attention due to their extraordinarily high reversible capacity as the cathode material in Li-ion batteries. To better understand the nature of this type of materials, this paper reviews history of development of the Li-rich cathode materials, and provides in-depth study on complicated crystal structures and reaction mechanisms during electrochemical charge/discharge cycling. Despite the fabulous capability at low rate, several drawbacks still gap this type of high-capacity cathode materials from practical applications, for instance the large irreversible capacity loss at first cycle, poor rate capability, severe voltage decay and capacity fade during electrochemical charge/discharge cycling. This review will also address mechanisms for these inferior properties and propose various possible solutions to solve above issues for future utilization of these cathode materials in commercial Li-ion batteries.

Device for film deposition and implantation of ions inside pipes of low diameter

International Nuclear Information System (INIS)

Pogrebnjak, A.D.; Perekrjostov, V.I.; Tyurin, Yu.N.; Wood, B.P.

2002-01-01

Two principally new devices, which can be applied to deposit coatings inside the pipes of low diameter, have been developed. The thickness of coatings and films can be varied. To deposit coatings of a low thickness (about 2 nm) on inside pipe walls using a vacuum-arc source and a sputtering device, which is composed of the pipe applied for anode cooling, the constant magnet, the magnetic circuit, the anode, the cathode, the pipe subjected for coating deposition, the cathode holder, etc. Using this device, we have deposited TiC, Ta, Cr, TiN coatings of various thickness ranging from scores of nano-meters to several micro-meters and with very good adhesion to the substrate. To increase adhesion, we applied 10 to 20 kV voltage during ion implantation to the substrate. To study element and structure composition, we applied RBS, TEM, SEM, XRD analyses, micro-hardness, wear resistance tests and also those for corrosion resistance in acid media. Another version of the source was based on the pulsed plasma-detonation technology and applied an evaporating electrode (for implantation) and a powder, which was injected into a plasma jet. The jet velocity reached several kilometers per second. Current of several kilo-amps passed through the plasma jet and increased its energy. The produced in this way coating thickness reached 30 to 400 micro-meter. Application of the vacuum-arc source for subsequent coating deposition allowed us to improve the servicing characteristics of surface layers. We have deposited NiAl, CoAl, A1 2 O 3 , WC-Co, Hastelloy and stainless steel SS316L

Induced voltage due to time-dependent magnetisation textures

International Nuclear Information System (INIS)

Kudtarkar, Santosh Kumar; Dhadwal, Renu

2010-01-01

We determine the induced voltage generated by spatial and temporal magnetisation textures (inhomogeneities) in metallic ferromagnets due to the spin diffusion of non-equilibrium electrons. Using time dependent semi-classical theory as formulated in Zhang and Li and the drift-diffusion model of transport it is shown that the voltage generated depends critically on the difference in the diffusion constants of up and down spins. Including spin relaxation results in a crucial contribution to the induced voltage. We also show that the presence of magnetisation textures results in the modification of the conductivity of the system. As an illustration, we calculate the voltage generated due to a time dependent field driven helimagnet by solving the Landau-Lifshitz equation with Gilbert damping and explicitly calculate the dependence on the relaxation and damping parameters.

Derivation and Numerical Approximation of the Quantum Drift Diffusion Model for Semiconductors

International Nuclear Information System (INIS)

Ohnmar Nwe

2004-06-01

This paper is concerned with the study of the quantum drift diffusion equation for semiconductors. Derivation of the mathematical model, which describes the electeon flow through a semiconductor device due to the application of a voltage, is considered and studied in numerical point of view by using some methods

Graphene-coated hollow fiber membrane as the cathode in anaerobic electrochemical membrane bioreactors – Effect of configuration and applied voltage on performance and membrane fouling

KAUST Repository

Werner, Craig M.

2015-12-22

Electrically conductive, graphene-coated hollow-fiber porous membranes were used as cathodes in anaerobic electrochemical membrane bioreactors (AnEMBRs) operated at different applied voltages (0.7 V and 0.9 V) using a new rectangular reactor configuration, compared to a previous tubular design (0.7 V). The onset of biofouling was delayed and minimized in rectangular reactors operated at 0.9 V, compared to those at 0.7 V due to higher rates of hydrogen production. Maximum transmembrane pressures for the rectangular reactor were only 0.10 bar (0.7 V) or 0.05 bar (0.9 V) after 56 days of operation, compared to 0.46 bar (0.7 V) for the tubular reactor after 52 days. The thickness of the membrane biofouling layer was approximately 0.4 µm for rectangular reactors and 4 µm for the tubular reactor. Higher permeate quality (TSS = 0.05 mg/L) was achieved in the rectangular AnEMBR than the tubular AnEMBR (TSS = 17 mg/L), likely due to higher current densities that minimized the accumulation of cells in suspension. These results show that the new rectangular reactor design, which had increased rates of hydrogen production, successfully delayed the onset of cathode biofouling and improved reactor performance.

Graphene-coated hollow fiber membrane as the cathode in anaerobic electrochemical membrane bioreactors – Effect of configuration and applied voltage on performance and membrane fouling

KAUST Repository

Werner, Craig M.; Katuri, Krishna; Rao, Hari Ananda; Chen, Wei; Lai, Zhiping; Logan, Bruce E.; Amy, Gary L.; Saikaly, Pascal

2015-01-01

Electrically conductive, graphene-coated hollow-fiber porous membranes were used as cathodes in anaerobic electrochemical membrane bioreactors (AnEMBRs) operated at different applied voltages (0.7 V and 0.9 V) using a new rectangular reactor configuration, compared to a previous tubular design (0.7 V). The onset of biofouling was delayed and minimized in rectangular reactors operated at 0.9 V, compared to those at 0.7 V due to higher rates of hydrogen production. Maximum transmembrane pressures for the rectangular reactor were only 0.10 bar (0.7 V) or 0.05 bar (0.9 V) after 56 days of operation, compared to 0.46 bar (0.7 V) for the tubular reactor after 52 days. The thickness of the membrane biofouling layer was approximately 0.4 µm for rectangular reactors and 4 µm for the tubular reactor. Higher permeate quality (TSS = 0.05 mg/L) was achieved in the rectangular AnEMBR than the tubular AnEMBR (TSS = 17 mg/L), likely due to higher current densities that minimized the accumulation of cells in suspension. These results show that the new rectangular reactor design, which had increased rates of hydrogen production, successfully delayed the onset of cathode biofouling and improved reactor performance.

Measurement of Effective Drift Velocities of Electrons and Holes in Shallow Multiple Quantum Well P-I Modulators

Science.gov (United States)

Yang, Ching-Mei

1995-01-01

P-i-n diodes containing multiple quantum wells (MQWs) in the i-region are the building blocks for photonic devices. When we apply electric field across these devices and illuminate it with light, photo-carriers are created in the i-region. These carriers escape from the wells and drift toward the electrodes; thus photo-voltage is created. The rise- and decay-times of photo-voltages are related to the transport of carriers. In this dissertation, we present theoretical and experimental studies on carrier transport mechanisms of three shallow MQW GaAs/Al _{x}Ga_{1-x}As p-i-n diodes (x = 0.02, 0.04, 0.08) at various bias voltages. We start with the description of the sample structures and their package. We then present the characteristics of these samples including their transmission spectra and responsivity. We will demonstrate that the over-all high quality of these samples, including a strong exciton resonant absorption, ~100% internal quantum efficiencies and completely depleted i-region at bias between +0.75 V to -5 V bias. In our theoretical studies, we first discuss the possible carrier sweep-out mechanisms and estimate the response times associated with these mechanisms. Based on our theoretical model, we conclude that only the drift times of carriers and enhanced diffusion times are important for shallow MQW p-i-n diodes: at high bias, the fast drift times of electrons and holes control the rise-times; at low bias, the slow drift times of holes and the enhanced diffusion times control the decay-times. We have performed picosecond time-resolved pump/probe electro-absorption measurements on these samples. We then obtained the drift times, effective drift velocities and effective mobilities of electrons and holes for these devices. We find that the carrier effective drift velocities (especially for holes) seemed insensitive to the Al concentration in the barriers (in the range of x = 2% to 8%), even though the x = 2% sample does show an overall faster response

The Investigation of Field Plate Design in 500 V High Voltage NLDMOS

Directory of Open Access Journals (Sweden)

Donghua Liu

2015-01-01

Full Text Available This paper presents a 500 V high voltage NLDMOS with breakdown voltage (VBD improved by field plate technology. Effect of metal field plate (MFP and polysilicon field plate (PFP on breakdown voltage improvement of high voltage NLDMOS is studied. The coeffect of MFP and PFP on drain side has also been investigated. A 500 V NLDMOS is demonstrated with a 37 μm drift length and optimized MFP and PFP design. Finally the breakdown voltage 590 V and excellent on-resistance performance (Rsp = 7.88 ohm * mm2 are achieved.

Increased cathode performance using a thin film LSM layer on a structured 8YSZ electrolyte surface

Energy Technology Data Exchange (ETDEWEB)

Herbstritt, D.; Weber, A.; Ivers-Tiffee, E. [Karlsruhe Univ. (T.H.) (DE). Inst. fuer Werkstoffkunde der Elektrotechnik (IWE); Guntow, U.; Mueller, G. [Fraunhofer-Institut fuer Silicatforschung (ISC), Wuerzburg (Germany)

2000-07-01

A considerable part of the power losses in a SOFC single cell occurs due to the polarization resistance of the cathode/electrolyte interface. The resulting high cathodic overvoltage corresponds to an enhanced degradation of the cell. In case of a screen printed LSM cathode layer (LSM: La{sub 1-x}Sr{sub x}MnO{sub 3}) on a YSZ electrolyte substrate (YSZ: Y{sub 2}O{sub 3} stabilised ZrO{sub 2}) the cathodic reaction is generally assumed to be restricted to the three phase boundary (tpb) between cathode, oxidant and the electrolyte surface. The electrochemical active area was increased by a modification of the cathode/electrolyte interface. Single cells with a thin film LSM layer on a structured 8YSZ electrolyte showed a power output of about 0.95 W/cm{sup 2} at 0.7 V cell voltage (950 C; oxidant: air, 0.7 1/min; fuel: hydrogen, 0.5 1/min, 15% fuel utilization). (orig.)

Synthesis of Li{sub 2}MnO{sub 3}-stabilized LiCoO{sub 2} cathode material by spray-drying method and its high-voltage performance

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhiguo; Wang, Zhixing, E-mail: zxwang.csu@hotmail.com; Guo, Huajun; Peng, Wenjie; Li, Xinhai

2015-03-25

Highlights: • Li{sub 2}MnO{sub 3} is introduced to stabilize the structure of LiCoO{sub 2} at high voltages. • xLi{sub 2}MnO{sub 3}·(1−x)LiCoO{sub 2} with fine particles prepared by a simple spray-drying method. • The modified sample exhibits enhanced high-voltage electrochemical performance. • Possible kinetic behaviors of the electrode surface are discussed. - Abstract: xLi{sub 2}MnO{sub 3}⋅(1 − x)LiCoO{sub 2} (x = 0, 0.02, 0.05, 0.1) as a cathode material for lithium ion batteries has been prepared by a spray-drying assisted solid-state method. The effects of Li{sub 2}MnO{sub 3} content on crystal structure, morphology, and high-voltage electrochemical performance of LiCoO{sub 2} have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and galvanostatic charge–discharge test. XRD results reveal that all samples have a well-ordered layered structure. SEM and EDS analyses confirm that homogeneous powders with a primary particle size of about 2 μm are observed and the elementals distribute uniformly in the particles. Electrochemical tests demonstrate that the modified samples exhibit obviously enhanced cycling stability in the voltage ranges of 3.0–4.5 V and 3.0–4.6 V, although they deliver somewhat lower discharge capacity. Specifically, 0.02Li{sub 2}MnO{sub 3}⋅0.98LiCoO{sub 2} delivers the initial discharge capacity of 189.0, 216.8 mA h g{sup −1} at 0.1 C in the voltage range of 3.0–4.5 V and 3.0–4.6 V, respectively, and excellent cycling behaviors at 1 C are achieved.

Investigation of Vacuum Arc Voltage Characteristics Under Different Axial Magnetic Field Profiles

International Nuclear Information System (INIS)

Jia Shenli; Song Xiaochuan; Huo Xintao; Shi Zongqian; Wang Lijun

2010-01-01

Characteristics of the arc voltage under different profiles of axial magnetic field were investigated experimentally in a detachable vacuum chamber with five pairs of specially designed electrodes generating both bell-shaped and saddle-shaped magnetic field profile. The arc column and cathode spot images were photographed by a high speed digital camera. The dependence of the arc voltage on arcing evolution is analyzed. It is indicated that the axial magnetic field profile could affect the arc behaviors significantly, and the arc voltage is closely related to the arc light intensity.

Cold-electrode voltage fall for impulse arcs in argon between copper electrodes

Energy Technology Data Exchange (ETDEWEB)

Diaz, O; Cooray, V, E-mail: oscar.diaz@angstrom.uu.se [Lightning Research Group, Division for Electricity, Uppsala University Angstroemlaboratoriet Box 5234, 751 20, Uppsala (Sweden)

2011-06-23

The full electric arc discharge in gases for short gaps in homogeneous electric field and pressure{center_dot}distance (pd) below 150 Torr{center_dot}cm, can be described as a transition between different discharge mechanisms such as: Townsend, glow, and arc. Once the arc is achieved the measured voltage drops to some volts and the current density increases several orders of magnitude. Depending upon the type of gas used, the electrode surface characteristics and type of electrical excitation, the cathode and anode voltage fall might change. The present work is directed to study the electrode fall (sum of anode and cathode falls) during a current impulse arc discharge between copper electrodes in ceramic tubes filled with argon between 0.01 and 6.5 Torr{center_dot}cm. The copper electrodes were cleaned, degassed and hydrogen reduced. The arc voltages were measured with fast/slow rise times and short/long duration current impulses produced by a RLC circuit. An increasing variation of the electrode fall was found at the pressure{center_dot}distance range analyzed.

Measurements of electron drift velocity in isobutane using the pulsed Townsend technique

Energy Technology Data Exchange (ETDEWEB)

Vivaldini, Tulio C.; Lima, Iara B.; Goncalves, Josemary A.C.; Botelho, Suzana; Tobias, Carmen C.B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Ridenti, Marco A.; Pascholati, Paulo R. [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica. Lab. do Acelerador Linear; Fonte, Paulo; Mangiarotti, Alessio [Universidade de Coimbra (Portugal). Dept. de Fisica. Lab. de Instrumentacao e Fisica Experimental de Particulas

2010-07-01

Full text. The electron drift velocity characterizes the electric conductivity of weakly ionized gases and is one of the most important transport parameters for simulation and modeling of radiation detectors and plasma discharges. This work presents the results of electron drift velocity as a function of the reduced electric field obtained in nitrogen and isobutane by the Pulsed Townsend technique. Due to its excellent timing properties, isobutane is a common component of standard mixtures used in RPCs (Resistive Plate Chambers), however, at moderate electric fields strength (50 Td <= E/N <= 200 Td), there are insufficient data available in literature for this gas. In our experimental apparatus, electrons are liberated from an aluminum cathode (40mm diameter) due to the incidence of a nitrogen laser beam (MNL202-LD LTB) and are accelerated by the applied electric field toward the anode, made of a high resistivity glass (2 x 10{sup 10} {Omega}{center_dot}m). The fast electric signals generated is amplified and were digitalized in a 1 GHz bandwidth oscilloscope to measure the electrons transit time and to calculate the electron drift velocity in different gaps between anode and cathode. As the timing information presented in the fast electric signal originated in the anode is significant in our application, the amplifier circuit had to hold special features in order to preserve the signal shape. The linear amplifier used, based on the BGM1013 integrated circuit (Philips R), reaches up to 2.1 GHz bandwidth with 35.5 dB gain and was developed and built at Laboratory of Instrumentation and Experimental Particles Physics/Portugal. In order to validate this method, measurements were initially carried out in pure nitrogen, in reduced electric fields ranging from 148 to 194 Td. These results showed good agreement with those found in the literature for this largely investigated gas. The measurements of electron drift velocities in pure isobutane were performed as a function

Multiplex Outputs ns Grade High-voltage Fast Pulse Generator Study

International Nuclear Information System (INIS)

Wang Xin; Chen Kenan

2009-01-01

Using a double-grid hydrogen thyratron, a fast pulse generator with four outputs, high-voltage, low jitter, was made to use at special occasion.In this paper, the basic structure of pulser, switching theory and double-grid driving of hydrogen thyratron was introduced, and also, the effects of grids driving pulses characteristics, the delay between too grids driving, the reservoir heater voltage and cathode heater voltage on the output are carefully examined in experiments. The pulse generator with four outputs was made to producing pulses with amplitude up to 4 kV, rise-time less than 15 ns and jitter less than 3 ns. (authors)

C-V and G-V characteristics of ion-implanted MOS structures depending upon the geometrical structure of the implanted region

International Nuclear Information System (INIS)

Zohta, Y.

1977-01-01

It is found that the capacitance-voltage (C-V) and conductance-voltage (G-V) characteristics of MOS capacitors, into which ions of the opposite conductivity type are implanted, depend strongly upon the geometrical structure of the ion-implanted region. This phenomenon can be analyzed in terms of lateral current flow which connects an inversion layer formed in the ion-implanted region to a surrounding nonimplanted substrate. On the basis of this model, the C-V and G-V characteristics are calculated using a simple equivalent circuit, and general relationships inherent in this model are obtained. MOS capacitors with an ion-implanted layer of different geometries have been prepared to measure their C-V and G-V characteristics. Comparison of experimental measurements with theory substantiates the lateral current flow model

Effect of Li2O/Al cathode in Alq3 based organic light-emitting diodes.

Science.gov (United States)

Shin, Eun Chul; Ahn, Hui Chul; Han, Wone Keun; Kim, Tae Wan; Lee, Won Jae; Hong, Jin Woong; Chung, Dong Hoe; Song, Min Jong

2008-09-01

An effect of bilayer cathode Li20/Al was studied in Alq3 based organic light-emitting diodes with a variation of Li2O layer thickness. The current-luminance-voltage characteristics of ITO/TPD/Alq3/Li2O/Al device were measured at ambient condition to investigate the effect of Li2O/Al. It was found that when the thickness of Li2O layer is in the range of 0.5-1 nm, there are improvements in luminance, efficiency, and turn-on voltage of the device. A current density and a luminance are increased by about 100 times, a turn-on voltage is lowered from 6 V to 3 V, a maximum current efficiency is improved by a factor of 2.3, and a maximum power efficiency is improved by a factor of 3.2 for a device with a use of thin Li2O layer compared to those of the one without the Li2Otron-barrier height for electron injection from the cathode to the emissive layer.

Smith-Purcell radiation experiment using a field-emission array cathode

International Nuclear Information System (INIS)

Ishizuka, H.; Kawamura, Y.; Yokoo, K.; Shimawaki, H.; Hosono, A.

2000-01-01

We have recently started an experiment on visible Smith-Purcell (SP) radiation to examine practical applicability of a field-emission array (FEA) cathode to compact free electron lasers, placing emphasis on safe operation of the cathode as well as beam quality. The electron beam was generated by a 5 cm long triode which employed either a single- or double-gated FEA. Accelerating voltages of up to -40 and -100 kV were applied to the cathode by a regulated power supply and a small Van der Graaff generator, respectively. A 25 μA beam of up to 45 keV was routinely produced and a 5 μA 80 keV beam was also attained. The beam passed through a 1 mm wide slit in the anode and grazed the surface of a 2.5 cm long replica grating with a period of either 0.56 or 0.83 μm. The SP radiation has not been identified owing to irrelevant luminescence caused by the beam at the grating. Still it was confirmed that the FEA cathode is adequately durable and electron beams generated therefrom are sufficiently stable to be used for systematic measurements of radiation

Performance characteristics of CdTe drift ring detector

Science.gov (United States)

Alruhaili, A.; Sellin, P. J.; Lohstroh, A.; Veeramani, P.; Kazemi, S.; Veale, M. C.; Sawhney, K. J. S.; Kachkanov, V.

2014-03-01

CdTe and CdZnTe material is an excellent candidate for the fabrication of high energy X-ray spectroscopic detectors due to their good quantum efficiency and room temperature operation. The main material limitation is associated with the poor charge transport properties of holes. The motivation of this work is to investigate the performance characteristics of a detector fabricated with a drift ring geometry that is insensitive to the transport of holes. The performance of a prototype Ohmic CdTe drift ring detector fabricated by Acrorad with 3 drift rings is reported; measurements include room temperature current voltage characteristics (IV) and spectroscopic performance. The data shows that the energy resolution of the detector is limited by leakage current which is a combination of bulk and surface leakage currents. The energy resolution was studied as a function of incident X-ray position with an X-ray microbeam at the Diamond Light Source. Different ring biasing schemes were investigated and the results show that by increasing the lateral field (i.e. the bias gradient across the rings) the active area, evaluated by the detected count rate, increased significantly.

Some properties of the gas magnetron; neke osobine gasnog magnetrona

Energy Technology Data Exchange (ETDEWEB)

Miljevic, V [Boris Kidric Institute of nuclear sciences, Vinca, Belgrade (Yugoslavia)

1979-07-01

The cylindrical magnetron diode with directly heated cathode, filled with argon at low pressure, has been studied. In the case of high magnetic fields and low gas pressure the motion of electrons is reduced to the rotation around the cathode with superimposed allow radial drift. It is found that the plasma formation time in in the msec region. The critical magnetic field in the vacuum diode (B{sub c}), and its value increases with the increase of the anode voltage and working pressure. (author)

Sensitivity of hot-cathode ionization vacuum gages in several gases

Science.gov (United States)

Holanda, R.

1972-01-01

Four hot-cathode ionization vacuum gages were calibrated in 12 gases. The relative sensitivities of these gages were compared to several gas properties. Ionization cross section was the physical property which correlated best with gage sensitivity. The effects of gage accelerating voltage and ionization-cross-section energy level were analyzed. Recommendations for predicting gage sensitivity according to gage type were made.

Cathode voltage and discharge current oscillations in HiPIMS

Czech Academy of Sciences Publication Activity Database

Klein, P.; Hnilica, J.; Hubička, Zdeněk; Čada, Martin; Šlapanská, M.; Zemánek, M.; Vašina, P.

2017-01-01

Roč. 26, č. 5 (2017), s. 1-12, č. článku 055015. ISSN 0963-0252 R&D Projects: GA ČR(CZ) GA15-00863S Institutional support: RVO:68378271 Keywords : HiPIMS * voltage and current oscillations * spokes Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 3.302, year: 2016

Gyrocenter Shift of Low-Temperature Plasmas and the Retrograde Motion of Cathode Spots in Arc Discharges

International Nuclear Information System (INIS)

Lee, K. C.

2007-01-01

The gyrocenter shift phenomenon explained the mechanism of radial electric field formation at the high confinement mode transition in fusion devices. This Letter reports that the theory of gyrocenter shift is also applicable to low temperature high collisional plasmas such as arc discharges by the generalization of the theory resulting from a short mean free path compared with the gyroradius. The retrograde motion of cathode spots in the arc discharge is investigated through a model with the expanded formula of gyrocenter shift. It is found that a reversed electric field is formed in front of the cathode spots when they are under a magnetic field, and this reversed electric field generates a rotation of cathode spots opposite to the Amperian direction. The ion drift velocity profiles calculated from the model are in agreement with the experimental results as functions of magnetic flux density and gas pressure

PDC: A wire chamber cathode read-out on 6-bit fast ADC

Energy Technology Data Exchange (ETDEWEB)

De Giorgi, M; Gasparini, F; Meneguzzo, A T; Pitacco, G [Istituto Nazionale di Fisica Nucleare, Padua (Italy); Padua Univ. (Italy). Ist. di Fisica)

1984-06-01

A read-out for MWPC and drift chamber is presented in which the coordinate along the sense wires is obtained by measuring the centre of gravity (CoG) of the charge induced on cathode strips or pads. The peak value of the signals coming from subsets of 8-pad cathodes are recorded by a parallel sample and hold, strobed by their own OR, and then serially digitized by one 6-bit fast ADC (FADC). The basic module of the system is a peak detector and converter (PDC) built in CAMAC cards, which could be an interesting approach to the analog signal acquisition of large particle detectors. The system has been designed to equip the central detector in an experiment at the CERN LEAR facility. A prototype of a card will be described and the results of some tests will be presented.

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

Science.gov (United States)

Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam

2017-01-01

Undesired electrode–electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries. PMID:28443608

Enhanced electrochemical performance of Ti substituted P2-Na2/3Ni1/4Mn3/4O2 cathode material for sodium ion batteries

International Nuclear Information System (INIS)

Zhao, Wenwen; Tanaka, Akinobu; Momosaki, Kyoko; Yamamoto, Shinji; Zhang, Fabi; Guo, Qixin; Noguchi, Hideyuki

2015-01-01

Highlights: • Ti substituted P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 cathode was synthesized. • Structural and electrochemical properties of Na 2/3 Ni 1/4 Ti x Mn 3/4-x O 2 were studied. • Ti substituted cathodes exhibit enhanced cycleability and rate performance. • Ti substitution has impact on stabilizing the P2 structure during cycling. -- Abstract: Ti substituted P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 cathode material with the composition of Na 2/3 Ni 1/4 Ti x Mn 3/4-x O 2 has been synthesized by solid state method. The influence of Ti substitution for Mn on the structure, morphology and electrochemical performances of P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 has been investigated. X-ray diffraction (XRD) results of Ti substituted sample show that they exhibit same diffraction patterns as those of pristine P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 . Progressive change in the lattice parameters of Ti substituted samples suggests that Mn was successfully substituted by Ti. In contrast to P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 which shows step-type voltage profiles, Ti substituted samples show sloping voltage profiles. Drastic capacity fade occurred for P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 cathode, while Ti substituted cathodes still show high capacity retention over 92% after 25 cycles at the voltage range of 2.0-4.3 V. Even cycled at high upper cut-off voltage of 4.5 V, Ti=0.20 sample can deliver a reversible capacity of 140 mAhg −1 with the capacity retention over 92% after 25 cycles. Furthermore, Ti substituted cathodes exhibit enhanced rate capability over pristine P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 cathode. Comparison of the Ex-situ XRD results of the cycled P2-Na 2/3 Ni 1/4 Mn 3/4 O 2 and its substituted samples provides evidence that the improved electrochemical performance of Ti substituted cathodes would be attributed to the stabilization of the structure with Ti substitution

Reducing Pesticide Drift

Science.gov (United States)

Provides information about pesticide spray drift, including problems associated with drift, managing risks from drift and the voluntary Drift Reduction Technology program that seeks to reduce spray drift through improved spray equipment design.

Microwave generation enhancement of X-band CRBWO by use of coaxial dual annular cathodes

OpenAIRE

Yan Teng; Jun Sun; Changhua Chen; Hao Shao

2013-01-01

This paper presents an approach that greatly enhances both the output power and the conversion efficiency of the coaxial relativistic backward wave oscillator (CRBWO) by using coaxial dual annular cathodes, which increases the diode current rather than the diode voltage. The reasons for the maladjustment of CRBWO under a high diode voltage are analyzed theoretically. It is found that by optimization of the diode structure, the shielding effect of the space charge of the outer beams on the inn...

Design, conditioning, and performance of a high voltage, high brightness dc photoelectron gun with variable gap

Energy Technology Data Exchange (ETDEWEB)

Maxson, Jared; Bazarov, Ivan; Dunham, Bruce; Dobbins, John; Liu, Xianghong; Smolenski, Karl [Cornell Laboratory for Accelerator-Based Sciences and Education, Cornell University, Ithaca, New York 14853 (United States)

2014-09-15

A new high voltage photoemission gun has been constructed at Cornell University which features a segmented insulator and a movable anode, allowing the cathode-anode gap to be adjusted. In this work, we describe the gun's overall mechanical and high voltage design, the surface preparation of components, as well as the clean construction methods. We present high voltage conditioning data using a 50 mm cathode-anode gap, in which the conditioning voltage exceeds 500 kV, as well as at smaller gaps. Finally, we present simulated emittance results obtained from a genetic optimization scheme using voltage values based on the conditioning data. These results indicate that for charges up to 100 pC, a 30 mm gap at 400 kV has equal or smaller 100% emittance than a 50 mm gap at 450 kV, and also a smaller core emittance, when placed as the source for the Cornell energy recovery linac photoinjector with bunch length constrained to be <3 ps rms. For 100 pC up to 0.5 nC charges, the 50 mm gap has larger core emittance than the 30 mm gap, but conversely smaller 100% emittance.

Rare earth metal oxides as BH4-tolerance cathode electrocatalysts for direct borohydride fuel cells

Institute of Scientific and Technical Information of China (English)

NI Xuemin; WANG Yadong; GUO Feng; YAO Pei; PAN Mu

2012-01-01

Rare earth metal oxides (REMO) as cathode electrocatalysts in direct borohydride fuel cell (DBFC) were investigated.The REMO electrocatalysts tested showed favorable activity to the oxygen electro-reduction reaction and strong tolerance to the attack of BH4- in alkaline electrolytes.The simple membraneless DBFCs using REMO as cathode electrocatalyst and using hydrogen storage alloy as anodic electrocatalyst exhibited an open circuit of about 1 V and peak power of above 60 mW/cm2.The DBFC using Sm2O3 as cathode electrocatalyst showed a relatively better performance.The maximal power density of 76.2 mW/cm2 was obtained at the cell voltage of 0.52 V.

The feasibility and application of PPy in cathodic polarization antifouling.

Science.gov (United States)

Jia, Meng-Yang; Zhang, Zhi-Ming; Yu, Liang-Min; Wang, Jia; Zheng, Tong-Tong

2018-04-01

Cathodic polarization antifouling deserves attention because of its environmentally friendly nature and good sustainability. It has been proven that cathodic voltages applied on metal substrates exhibit outstanding antifouling effects. However, most metals immersed in marine environment are protected by insulated anticorrosive coatings, restricting the cathodic polarization applied on metals. This study developed a conducting polypyrrole (PPy)/acrylic resin coating (σ = 0.18 Scm -1 ), which can be applied in cathodic polarization antifouling. The good stability and electro-activity of PPy in the negative polarity zone in alkalescent NaCl solution were verified by linear sweep voltammetry (LSV), chronoamperometry (CA), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), demonstrating the feasibility of PPy as cathodic polarization material. Furthermore, the antifouling effects of PPy/acrylicresin coating on 24-h old Escherichia coli bacteria (E. coli) which formed on PPy/acrylic resin-coated plastic plate were measured under different cathodic potentials and treatment time, characterized by fluorescent microscope. The results suggest that at cathodic potential around -0.5 V (vs. saturated calomel electrode (SCE)), there was little trace of attached bacteria on the substrate after 20 min of treatment. PPy/acrylicresin-coated substrates were also subjected to repeated cycles of biofilm formation and electrochemical removal, where high removal efficiencies were maintained throughout the total polarization process. Under these conditions, the generation of hydrogen peroxide is believed to be responsible for the antifouling effects because of causing oxidative damage to cells, suggesting the potential of the proposed technology for application on insulated surfaces in various industrial settings. Copyright © 2018 Elsevier B.V. All rights reserved.

High energy mechano-chemical milling: Convenient approach to synthesis of LiMn1.5Ni0.5O4 high voltage cathode for lithium ion batteries

International Nuclear Information System (INIS)

Datta, Moni Kanchan; Ramanathan, Madhumati; Jampani, Prashanth; Saha, Partha; Epur, Rigved; Kadakia, Karan; Chung, Sung Jae; Patel, Prasad; Gattu, Bharat; Manivannan, Ayyakkannu; Kumta, Prashant N.

2014-01-01

Graphical abstract: Nanostructured high voltage spinel phase of LiMn 1.5 Ni 0.5 O 4 (LMNO) of particle size ∼10–40 nm has been synthesized by a cost effective high energy mechanical milling (HEMM) approach followed by low temperature thermal treatments. High energy mechanical milling of lithium and manganese oxide precursors followed by moderate heat treatment results in the formation of single phase of LMNO, the high voltage spinel phase. The nanostructured LMNO has been studied as a high voltage cathode for lithium ion rechargeable batteries. Cyclic voltammetry as well as the differential capacity plots of nanostructured LMNO show the occurrence of two major reversible reactions occurring in the potential window of ∼2–3.6 V and ∼3.6–5.1 V with an associated specific capacity ∼105 mAh/g and ∼128 mAh/g, respectively. The nanostructured LMNO synthesized by the HEMM process followed by thermal treatments at ∼773 K, ∼873 K and ∼973 K shows a reversible capacity ∼120–110 mAh/g when cycled at a rate of ∼20 mA/g (∼C/6) in the potential window ∼3.6–5.1 V. Furthermore, the nanostructured HEMM derived LMNO shows a moderate rate capability with a capacity retention ∼87 mAh/g when cycled at ∼80 mA/g (∼C) rate. - Highlights: • Generation of LiMn 1.5 Ni 0.5 O 4 (LMNO) spinel by a cost effective HEMM process. • HEMM derived LMNO spinel phase shows a capacity of ∼128 mAh/g. • HEMM derived spinel exhibits a capacity retention of ∼87 mAh/g at ∼1C rate. • SEM analysis shows good structural integrity of the cycled electrode. • Charge transfer resistance increase during cycling causes capacity fade. - Abstract: The high voltage spinel form of LiMn 1.5 Ni 0.5 O 4 (LMNO) with a particle size ∼10–40 nm has been synthesized for the first time using high energy mechanical milling (HEMM) followed by low temperature thermal treatments using Li 2 O, MnO 2 and NiO as the starting precursors. The nanostructured LMNO cathode

Pulsed Current-Voltage-Induced Perturbations of a Premixed Propane/Air Flame

Directory of Open Access Journals (Sweden)

Jacob. B. Schmidt

2011-01-01

Full Text Available The effect of millisecond wide sub-breakdown pulsed voltage-current induced flow perturbation has been measured in premixed laminar atmospheric pressure propane/air flame. The flame equivalence ratios were varied from 0.8 to 1.2 with the flow speeds near 1.1 meter/second. Spatio-temporal flame structure changes were observed through collection of CH (A-X and OH (A-X chemiluminescence and simultaneous spontaneous Raman scattering from N2. This optical collection scheme allows us to obtain a strong correlation between the measured gas temperature and the chemiluminescence intensity, verifying that chemiluminescence images provide accurate measurements of flame reaction zone structure modifications. The experimental results suggest that the flame perturbation is caused by ionic wind originating only from the radial positive space-charge distribution in/near the cathode fall. A net momentum transfer acts along the annular space discharge distribution in the reaction zone at or near the cathode fall which modifies the flow field near the cathodic burner head. This radially inward directed body force appears to enhance mixing similar to a swirl induced modification of the flame structure. The flame fluidic response exhibit a strong dependence on the voltage pulse width ≤10 millisecond.

Influence of process parameters on threshold voltage and leakage current in 18nm NMOS device

Science.gov (United States)

Atan, Norani Binti; Ahmad, Ibrahim Bin; Majlis, Burhanuddin Bin Yeop; Fauzi, Izzati Binti Ahmad

2015-04-01

The process parameters are very crucial factor in the development of transistors. There are many process parameters that influenced in the development of the transistors. In this research, we investigate the effects of the process parameters variation on response characteristics such as threshold voltage (VTH) and sub-threshold leakage current (IOFF) in 18nm NMOS device. The technique to identify semiconductor process parameters whose variability would impact most on the device characteristic is realized through the process by using Taguchi robust design method. This paper presents the process parameters that influenced in threshold voltage (VTH) and sub-threshold leakage current (IOFF) which includes the Halo Implantation, Compensation Implantation, Adjustment Threshold voltage Implantation and Source/Drain Implantation. The design, fabrication and characterization of 18nm HfO2/TiSi2 NMOS device is simulated and performed via a tool called Virtual Wafer Fabrication (VWF) Silvaco TCAD Tool known as ATHENA and ATLAS simulators. These two simulators were combined with Taguchi L9 Orthogonal method to aid in the design and the optimization of the process parameters to achieve the optimum average of threshold voltage (VTH) and sub-threshold leakage current, (IOFF) in 18nm device. Results from this research were obtained; where Halo Implantation dose was identified as one of the process parameter that has the strongest effect on the response characteristics. Whereby the Compensation Implantation dose was identified as an adjustment factor to get the nominal values of threshold voltage VTH, and sub-threshold leakage current, IOFF for 18nm NMOS devices equal to 0.302849 volts and 1.9123×10-16 A/μm respectively. The design values are referred to ITRS 2011 prediction.

Asymmetric anode and cathode extraction structure fast recovery diode

Science.gov (United States)

Xie, Jiaqiang; Ma, Li; Gao, Yong

2018-05-01

This paper presents an asymmetric anode structure and cathode extraction fast and soft recovery diode. The device anode is partial-heavily doped and partial-lightly doped. The P+ region is introduced into the cathode. Firstly, the characteristics of the diode are simulated and analyzed. Secondly, the diode was fabricated and its characteristics were tested. The experimental results are in good agreement with the simulation results. The results show that, compared with the P–i–N diode, although the forward conduction characteristic of the diode is declined, the reverse recovery peak current is reduced by 47%, the reverse recovery time is shortened by 20% and the softness factor is doubled. In addition, the breakdown voltage is increased by 10%. Project supported by the National Natural Science Foundation of China (No. 51177133).

Hot ion plasma production in HIP-1 using water-cooled hollow cathodes

Science.gov (United States)

Reinmann, J. J.; Lauver, M. R.; Patch, R. W.; Layman, R. W.; Snyder, A.

1975-01-01

A steady-state ExB plasma was formed by applying a strong radially inward dc electric field near the mirror throats. Most of the results were for hydrogen, but deuterium and helium plasmas were also studied. Three water-cooled hollow cathodes were operated in the hot-ion plasma mode with the following results: (1) thermally emitting cathodes were not required to achieve the hot-ion mode; (2) steady-state operation (several minutes) was attained; (3) input powers greater than 40 kW were achieved; (4) cathode outside diameters were increased from 1.2 cm (uncooled) to 4.4 cm (water-cooled); (5) steady-state hydrogen plasma with ion temperatures from 185 to 770 eV and electron temperatures from 5 to 21 eV were produced. Scaling relations were empirically obtained for discharge current, ion temperature, electron temperature, and relative ion density as a function of hydrogen gas feed rate, magnetic field, and cathode voltage. Neutrons were produced from deuterium plasma, but it was not established whether thay came from the plasma volume or from the electrode surfaces.

Improved Cathode Structure for a Direct Methanol Fuel Cell

Science.gov (United States)

Valdez, Thomas; Narayanan, Sekharipuram

2005-01-01

An improved cathode structure on a membrane/electrode assembly has been developed for a direct methanol fuel cell, in a continuing effort to realize practical power systems containing such fuel cells. This cathode structure is intended particularly to afford better cell performance at a low airflow rate. A membrane/electrode assembly of the type for which the improved cathode structure was developed (see Figure 1) is fabricated in a process that includes brush painting and spray coating of catalyst layers onto a polymer-electrolyte membrane and onto gas-diffusion backings that also act as current collectors. The aforementioned layers are then dried and hot-pressed together. When completed, the membrane/electrode assembly contains (1) an anode containing a fine metal black of Pt/Ru alloy, (2) a membrane made of Nafion 117 or equivalent (a perfluorosulfonic acid-based hydrophilic, proton-conducting ion-exchange polymer), (3) a cathode structure (in the present case, the improved cathode structure described below), and (4) the electrically conductive gas-diffusion backing layers, which are made of Toray 060(TradeMark)(or equivalent) carbon paper containing between 5 and 6 weight percent of poly(tetrafluoroethylene). The need for an improved cathode structure arises for the following reasons: In the design and operation of a fuel-cell power system, the airflow rate is a critical parameter that determines the overall efficiency, cell voltage, and power density. It is desirable to operate at a low airflow rate in order to obtain thermal and water balance and to minimize the size and mass of the system. The performances of membrane/electrode assemblies of prior design are limited at low airflow rates. Methanol crossover increases the required airflow rate. Hence, one way to reduce the required airflow rate is to reduce the effect of methanol crossover. Improvement of the cathode structure - in particular, addition of hydrophobic particles to the cathode - has been

High-voltage pixel sensors for ATLAS upgrade

Energy Technology Data Exchange (ETDEWEB)

Perić, I., E-mail: ivan.peric@ziti.uni-heidelberg.de [Heidelberg University, Institute of Computer Engineering, Mannheim (Germany); Kreidl, C.; Fischer, P. [Heidelberg University, Institute of Computer Engineering, Mannheim (Germany); Bompard, F.; Breugnon, P.; Clemens, J.-C.; Fougeron, D.; Liu, J.; Pangaud, P.; Rozanov, A.; Barbero, M. [CPPM, Marseille (France); Feigl, S.; Capeans, M.; Ferrere, D.; Pernegger, H.; Ristic, B. [CERN, Geneve (Switzerland); Muenstermann, D.; Gonzalez Sevilla, S.; La Rosa, A.; Miucci, A. [University of Geneve (Switzerland); and others

2014-11-21

The high-voltage (HV-) CMOS pixel sensors offer several good properties: a fast charge collection by drift, the possibility to implement relatively complex CMOS in-pixel electronics and the compatibility with commercial processes. The sensor element is a deep n-well diode in a p-type substrate. The n-well contains CMOS pixel electronics. The main charge collection mechanism is drift in a shallow, high field region, which leads to a fast charge collection and a high radiation tolerance. We are currently evaluating the use of the high-voltage detectors implemented in 180 nm HV-CMOS technology for the high-luminosity ATLAS upgrade. Our approach is replacing the existing pixel and strip sensors with the CMOS sensors while keeping the presently used readout ASICs. By intelligence we mean the ability of the sensor to recognize a particle hit and generate the address information. In this way we could benefit from the advantages of the HV sensor technology such as lower cost, lower mass, lower operating voltage, smaller pitch, smaller clusters at high incidence angles. Additionally we expect to achieve a radiation hardness necessary for ATLAS upgrade. In order to test the concept, we have designed two HV-CMOS prototypes that can be readout in two ways: using pixel and strip readout chips. In the case of the pixel readout, the connection between HV-CMOS sensor and the readout ASIC can be established capacitively.

Argon discharge characteristics in cold cathode penning ion source. Vol. 2

Energy Technology Data Exchange (ETDEWEB)

Abd El-Baki, M M; Abd El-Rahman, M M; Basal, N I [Ion Sources and Accelerators Department, Nuclear Research Center, Atomic energy Authority, Cairo, (Egypt)

1996-03-01

This study includes the production of argon discharge inside cold cathode penning ion source with axial d.c. extraction. The arc characteristics are investigated under the influence of the discharge parameters such as the pressure, axial magnetic field. At zero magnetic field and pressure 4.2 x 10{sup -4} torr, the arc voltage which is needed for arc initiation is relatively large V{sub arc} = 430 V, and I{sub arc} = 0.3 A. The application of the magnetic field helps the appearance of argon arc at lower voltage, e.g. at I{sub B} = 0.8 A, the arc voltage V{sub arc} = 320 V, and I{sub arc} = 0.3 A. It is found that the arc current increase with the increase of pressure, i.e. the increase of gas flow inside the source, while the arc voltage decreases. 7 fig.

Study of properties of helium-based gas mixtures for use of low momentum and high precision measurement in drift chambers

International Nuclear Information System (INIS)

Chen Chang; Zhang Qinjian; Ma Jimao; Huang Xiuping; Yi Kai; Zheng Shuchen

1998-01-01

Measured drift velocities using an uniform field drift chamber and multiplication factors obtained with proportional tubes in He-based gas mixtures He + CH 4 (80/20, 70/30) and He + iC 4 H 10 (85/15, 80/20, 70/30) are reported. The results are good agreement with calculations by Garfield Code. The Saturated drift velocity is V d ≅ 2.7 cm/μs and multiplication factor of M ≅ 10 4 -10 5 at certain working voltage is manageable in He/CH 4 (80/20) gas mixture, and it is good candidate of working gas for use of low momentum and high precision measurement in the drift chambers

Experimental investigation of a 1 kA/cm² sheet beam plasma cathode electron gun.

Science.gov (United States)

Kumar, Niraj; Pal, Udit Narayan; Pal, Dharmendra Kumar; Prajesh, Rahul; Prakash, Ram

2015-01-01

In this paper, a cold cathode based sheet-beam plasma cathode electron gun is reported with achieved sheet-beam current density ∼1 kA/cm(2) from pseudospark based argon plasma for pulse length of ∼200 ns in a single shot experiment. For the qualitative assessment of the sheet-beam, an arrangement of three isolated metallic-sheets is proposed. The actual shape and size of the sheet-electron-beam are obtained through a non-conventional method by proposing a dielectric charging technique and scanning electron microscope based imaging. As distinct from the earlier developed sheet beam sources, the generated sheet-beam has been propagated more than 190 mm distance in a drift space region maintaining sheet structure without assistance of any external magnetic field.

Implantable biochemical fuel cell

Energy Technology Data Exchange (ETDEWEB)

Richter, G; Rao, J R

1978-01-05

Implantable biochemical fuel cells for the operation of heart pacemakers or artificial hearts convert oxidisable body substances such as glucose on the anode side and reduce the oxygen contained in body fluids at the cathode. The anode and cathode are separated by membranes which are impermeable to albumen and blood corpuscles in body fluids. A chemical shortcircuit cannot occur in practice if, according to the invention, one or more selective oxygen electrodes with carbon as catalyst are arranged so that the mixture which diffuses into the cell from body fluids during operation reaches the fuel cell electrode through the porous oxygen electrode. The membranes used must be permeable to water. Cellulose, polymerised polyvinyl alcohol or an ion exchanger with a buffering capacity between pH5 and 8 act as permeable materials.

Numerical Study on Open-Circuit Voltage of Single Layer Organic Solar Cells with Schottky Contacts: Effects of Molecular Energy Levels, Temperature and Thickness

International Nuclear Information System (INIS)

Rong-Hua, Li; Ying-Quan, Peng; Chao-Zhu, Ma; Run-Sheng, Wang; Hong-Wei, Xie; Ying, Wang; Wei-Min, Meng

2010-01-01

We numerically investigate the effects of the exciton generation rate G, temperature T, the active layer thickness d and the position of LUMO level E L related to the cathode work function W c at a given energy gap on the open-circuit voltage V oc of single layer organic solar cells with Schottky contact. It is demonstrated that open-circuit voltage increases concomitantly with the decreasing cathode work function W c for given anode work functions and exciton generation rates. In the case of given cathode and anode work functions, the open-circuit voltage first increases with the exciton generation rate and then reaches a saturation value, which equals to the built-in voltage. Additionally, it is worth noting that a significant improvement to V oc could be made by selecting an organic material which has a relative high LUMO level (low |E L | value). However, V oc decreases as the temperature increases, and the decreasing rate reduces with the enhancement of exciton generation rate. Our study also shows that it is of no benefit to improve the open-circuit voltage by increasing the device thickness because of an enhanced charge recombination in thicker devices. (cross-disciplinary physics and related areas of science and technology)

A beam test of a prototype of the BESIII drift chamber in magnetic field

International Nuclear Information System (INIS)

Liu, J.B.; Qin, Z.H.; Wu, L.H.; Chen, C.; Zhuang, B.A.; Chen, Y.B.; Jin, Y.; Liu, R.G.; Ma, X.Y.; Ma, Y.Y.; Tang, X.; Wang, L.; Xu, M.H.; Zhang, G.F.; Zhu, M.X.; Zhu, Q.M.

2006-01-01

A prototype of the BESIII drift chamber was tested with He/C 3 H 8 (60/40) gas mixture in a 1T magnetic field at the π-2 beam line of KEK 12GeV PS. The drift distance-time relationship was extracted for various conditions. The performance of the chamber, such as the spatial resolution, the dE/dx resolution and the cell efficiency, was studied in detail. The dE/dx was measured as a function of βγ to calculate the particle separation power. Based on the test results, the operating voltage of the BESIII drift chamber is optimized to be 2200V, resulting in a spatial resolution better than 110μm, a cell efficiency over 98%, a dE/dx resolution better than 5% and the 3σπ/K separation at a momentum exceeding 700MeV/c. These results confirm the validation of the physics design of the BESIII drift chamber

Development of a drift tissue equivalent proportional counter for radiation protection personnel dosimetry

International Nuclear Information System (INIS)

Bordy, J.M.

1992-04-01

A new multicellular geometry for proportional counter has been developed. It is made of several drift regions which are some holes drilled in the cathode in front of anodes wires. The present work is made of 3 parts: 1) A theoretical evaluation of the multicellular counter characteristics: the sensitivity increases by a factor 15 vs the Tinelli Merlin-Gerin counter; the chord length distribution study shows the possibility to use a Dirac function for the dosimetry calculations; a tissue equivalent gas mixture based on argon and propane is designed. 2) The production of a monocellular prototype made of a hole and a needle shaped anode. 3) An experimental study of the prototype electrical characteristics and a computation of the electrical field in the counter. The focalization and the electron drift into the hole, the proportional operating mode are shown. Irradiations in front of photon and neutron sources verify these results

Two types of photomultiplier voltage dividers for high and changing count rates

International Nuclear Information System (INIS)

Reiter, W.L.; Stengl, G.

1980-01-01

We report on the design of two types of voltage distribution circuits for high stability photomultiplier operation. 'Type A' voltage divider is an ohmic voltage divider with high bleeder current (up to 10 mA) and the resistor chain split at one of the last dynodes, usually the dynode where the analog signal is derived from. This simple constructive measure improves the stability of the dynode voltage by a factor of 5 compared with an unsplit conventional resistor chain. 'Type B' is a novel active voltage divider using cold cathode tubes ar regulating elements. This voltage divider exhibits excellent temperature stability (about 10 -4 / 0 C). With 'type B' an equal stability compared with conventional ohmic dividers can be achieved at a bleeder current smaller by one order of magnitude. Of course both concepts, 'type A' and 'type B', can be combined. (orig.)

Evaluation of dual-tip micromanometers during 21-day implantation in goats

Science.gov (United States)

Reister, C. A.; Koenig, S. C.; Schaub, J. D.; Ewert, D. L.; Swope, R. D.; Latham, R. D.; Fanton, J. W.; Convertino, V. A. (Principal Investigator)

1998-01-01

Investigative research efforts using a cardiovascular model required the determination of central circulatory haemodynamic and arterial system parameters for the evaluation of cardiovascular performance. These calculations required continuous beat-to-beat measurement of pressure within the four chambers of the heart and great vessels. Sensitivity and offset drift, longevity, and sources of error for eight 3F dual-tipped micromanometers were determined during 21 days of implantation in goats. Subjects were instrumented with pairs of chronically implanted fluid-filled access catheters in the left and right ventricles, through which dual-tipped (test) micromanometers were chronically inserted and single-tip (standard) micromanometers were acutely inserted. Acutely inserted sensors were calibrated daily and measured pressures were compared in vivo to the chronically inserted sensors. Comparison of the pre- and post-gain calibration of the chronically inserted sensors showed a mean sensitivity drift of 1.0 +/- 0.4% (99% confidence, n = 9 sensors) and mean offset drift of 5.0 +/- 1.5 mmHg (99% confidence, n = 9 sensors). Potential sources of error for these drifts were identified, and included measurement system inaccuracies, temperature drift, hydrostatic column gradients, and dynamic pressure changes. Based upon these findings, we determined that these micromanometers may be chronically inserted in high-pressure chambers for up to 17 days with an acceptable error, but should be limited to acute (hours) insertions in low-pressure applications.

The influence of defect drift in external electric field on green luminescence of ZnO single crystals

International Nuclear Information System (INIS)

Korsunska, N.O.; Borkovska, L.V.; Bulakh, B.M.; Khomenkova, L.Yu.; Kushnirenko, V.I.; Markevich, I.V.

2003-01-01

In nominally undoped Zn O single crystals, the influence of electric field on photoluminescence in visible wavelength range was investigated. A well-known broad unstructured band consisting of green and orange ones was observed. It was found that the action of direct electric field of about 100 V/cm at 600-700 deg. C resulted in the increase of green band intensity near the cathode and its decrease near the anode, while orange band intensity was not influenced by this treatment. The redistribution of green band intensity along the sample under electric field is accounted for by drift of zinc interstitials from the anode to the cathode. It is supposed that emitting centres responsible for green luminescence are complex defects including zinc interstitials

A liquid-nitrogen monitor for lithium-drifted germanium detectors

International Nuclear Information System (INIS)

Andeweg, A.H.

1977-11-01

An instrument has been developed that makes use of a load cell to monitor the liquid nitrogen in the Dewar flask of a lithium-drifted germaniun detector. The contents are recorded on a chart recorder, and an alarm is sounded when the previously set content has been reached. A signal switches off the high-voltage power supply 30 minutes after the alarm is triggered. The calibration of the load-cell monitor is described in an appendix [af

Ion energy distributions in bipolar pulsed-dc discharges of methane measured at the biased cathode

Energy Technology Data Exchange (ETDEWEB)

Corbella, C; Rubio-Roy, M; Bertran, E; Portal, S; Pascual, E; Polo, M C; Andujar, J L, E-mail: corbella@ub.edu [FEMAN Group, IN2UB, Departament de Fisica Aplicada i Optica, Universitat de Barcelona, c/ MartI i Franques 1, 08028 Barcelona (Spain)

2011-02-15

The ion fluxes and ion energy distributions (IED) corresponding to discharges in methane (CH{sub 4}) were measured in time-averaged mode with a compact retarding field energy analyser (RFEA). The RFEA was placed on a biased electrode at room temperature, which was powered by either radiofrequency (13.56 MHz) or asymmetric bipolar pulsed-dc (250 kHz) signals. The shape of the resulting IED showed the relevant populations of ions bombarding the cathode at discharge parameters typical in the material processing technology: working pressures ranging from 1 to 10 Pa and cathode bias voltages between 100 and 200 V. High-energy peaks in the IED were detected at low pressures, whereas low-energy populations became progressively dominant at higher pressures. This effect is attributed to the transition from collisionless to collisional regimes of the cathode sheath as the pressure increases. On the other hand, pulsed-dc plasmas showed broader IED than RF discharges. This fact is connected to the different working frequencies and the intense peak voltages (up to 450 V) driven by the pulsed power supply. This work improves our understanding in plasma processes at the cathode level, which are of crucial importance for the growth and processing of materials requiring controlled ion bombardment. Examples of industrial applications with these requirements are plasma cleaning, ion etching processes during fabrication of microelectronic devices and plasma-enhanced chemical vapour deposition of hard coatings (diamond-like carbon, carbides and nitrides).

Series asymmetric supercapacitors based on free-standing inner-connection electrodes for high energy density and high output voltage

Science.gov (United States)

Tao, Jiayou; Liu, Nishuang; Rao, Jiangyu; Ding, Longwei; Al Bahrani, Majid Raissan; Li, Luying; Su, Jun; Gao, Yihua

2014-11-01

Asymmetric supercapacitors (ASCs) based on free-standing membranes with high energy density and high output voltage are reported. MnO2 nanowire/carbon nanotube (CNT) composites and MoO3 nanobelt/CNT composites are selected as the anode and the cathode materials of the devices, respectively. The ASC has a high volumetric capacitance of 50.2 F cm-3 at a scan rate of 2 mV s-1 and a high operation voltage window of 2.0 V. Especially, after a middle layer with an inner-connection structure was inserted between the anode and the cathode, the output voltage of the whole device can achieve 4.0 V. The full cell of series ASCs (SASC) with an inner-connection middle layer has a high energy density of 28.6 mW h cm-3 at a power density of 261.4 mW cm-3, and exhibits excellent cycling performance of 99.6% capacitance retention over 10 000 cycles. This strategy of designing the hybridized structure for SASCs provides a promising route for next-generation SCs with high energy density and high output voltage.Asymmetric supercapacitors (ASCs) based on free-standing membranes with high energy density and high output voltage are reported. MnO2 nanowire/carbon nanotube (CNT) composites and MoO3 nanobelt/CNT composites are selected as the anode and the cathode materials of the devices, respectively. The ASC has a high volumetric capacitance of 50.2 F cm-3 at a scan rate of 2 mV s-1 and a high operation voltage window of 2.0 V. Especially, after a middle layer with an inner-connection structure was inserted between the anode and the cathode, the output voltage of the whole device can achieve 4.0 V. The full cell of series ASCs (SASC) with an inner-connection middle layer has a high energy density of 28.6 mW h cm-3 at a power density of 261.4 mW cm-3, and exhibits excellent cycling performance of 99.6% capacitance retention over 10 000 cycles. This strategy of designing the hybridized structure for SASCs provides a promising route for next-generation SCs with high energy density and high

Characteristics of atmospheric pressure air discharges with a liquid cathode and a metal anode

Czech Academy of Sciences Publication Activity Database

Bruggeman, P.; Ribežl, E.; Degroote, J.; Malesevic, A.; Rego, R.; Vierendeels, J.; Leys, C.; Mašláni, Alan

2008-01-01

Roč. 17, č. 2 (2008), s. 1-11 ISSN 0963-0252 Institutional research plan: CEZ:AV0Z20430508 Keywords : atmospheric pressure air discharge * liquid cathode * voltage drop * optical emission spectroscopy Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.685, year: 2008

Fabrication and characterization of a cathode-supported tubular solid oxide fuel cell

Energy Technology Data Exchange (ETDEWEB)

Zhao, Chunhua; Liu, Renzhu; Wang, Shaorong; Wang, Zhenrong; Qian, Jiqin; Wen, Tinglian [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China)

2009-07-15

A cathode-supported tubular solid oxide fuel cell (CTSOFC) with the length of 6.0 cm and outside diameter of 1.0 cm has been successfully fabricated via dip-coating and co-sintering techniques. A crack-free electrolyte film with a thickness of {proportional_to}14 {mu}m was obtained by co-firing of cathode/cathode active layer/electrolyte/anode at 1250 C. The relative low densifying temperature for electrolyte was attributed to the large shrinkage of the green tubular which assisted the densification of electrolyte. The assembled cell was electrochemically characterized with humidified H{sub 2} as fuel and O{sub 2} as oxidant. The open circuit voltages (OCV) were 1.1, 1.08 and 1.06 V at 750, 800 and 850 C, respectively, with the maximum power densities of 157, 272 and 358 mW cm{sup -2} at corresponding temperatures. (author)

High energy density battery lithium thionyl chloride improved reverse voltage design

Science.gov (United States)

Zolla, A. E.

1981-12-01

A test program was conducted to demonstrate safety under voltage reversal conditions of the Altus 1400 AH HEDB cell. Eight cells of an improve Anode Grid Design, all cathode (carbon) limited, were forced discharged for 150% of their normal capacity. Minor design variations were tested at 6 amp, 20 C and 12 amp, 0 C with a lithium reference electrode and separate monitoring of current through the internal reverse voltage current shunt feature. There were no ventings and no appreciable increase in cell temperature or internal pressure.

Conceptual design report for the SDC barrel and intermediate muon detectors based on a jet-type drift chamber

International Nuclear Information System (INIS)

Arai, Y.; Funahashi, Y.; Higashi, Y.

1992-04-01

We propose a jet-type drift chamber for the barrel and intermediate muon detectors of SDC. The chamber system consists of large multiwire drift chambers having a simple box-type frame structure: 2. 5 x 0.4 m 2 in cross section and maximum 9 m in length. A chamber module consists of double layers of small jet cells. The drift cell is composed of a wire plane, including 3 sense wires, and cathode plates parallel to the wire plane. The two layers in a chamber are staggered to each other by half a cell width. The jet cell is tilted such that its principle axis points to the interaction point. Such an arrangement, together with a constant drift velocity of the jet cell, allows us to design a simple and powerful trigger system for high momentum muons utilizing a drift time sum between a pair of staggered cells. The multi-hit capability will be helpful to distinguish high momentum muon tracks from associated electromagnetic debris as has been demonstrated by the Fermilab beam test T816. The maximum drift time fulfills the SDC requirement. A preliminary FEM analysis of the chamber module verified the excellent structural stiffness. It makes the support structure and the alignment system relatively simple. These features will reduce the total cost as well as ensure a good performance of the chamber system. (J.P.N.)

An all-organic rechargeable battery using bipolar polyparaphenylene as a redox-active cathode and anode.

Science.gov (United States)

Zhu, L M; Lei, A W; Cao, Y L; Ai, X P; Yang, H X

2013-01-21

An all-organic rechargeable battery is realized by use of polyparaphenylene as both cathode- and anode-active material. This new battery can operate at a high voltage of 3.0 V with fairly high capacity, offering a renewable and cheaper alternative to conventional batteries.

Measurements of the drift velocity using a small gas chamber for monitoring of the CMS muon system

CERN Document Server

Frangenheim, J

This diploma thesis presents measurements of the drift velocity of electrons in gas. A small gas detector (VDC1 ) is used. This chamber is intended for measurement and monitoring of the drift velocity in the gas of the muon chambers of the gas detector system in the barrel area of the CMS-detector2 at the European Research Center for Particle Physics CERN near Geneva. The drift velocity is, together with the drift time, a key parameter for measurements with drift chambers. The aim of this thesis is to perform test measurements to determine parameters of the chamber and also to estimate systematic errors. Beside the drift velocity, further parameters of the gas like the pressure and the temperature are measured and accounted for. For the further work with the VDCs, analysis software has been created which is used for the analysis of the measurements. Parallel to this work, necessary improvements, e.g. for the high voltage robustness, were also implemented and tested. In addition, studies and test measurements ...

A Hall-current model of electron loss after POS opening into high-impedance loads

International Nuclear Information System (INIS)

Greenly, J.B.

1989-01-01

The author discusses how a self-consistent relativistic model of laminar Hall (E x B) electron flow across a POS plasma allows a loss mechanism after opening even in a strongly magnetically-insulated line, downstream of the remaining POS plasma. Opening is assumed to occur at the cathode, either by erosion or push-back. The loss results only when a large voltage appears after opening into a high impedance load. Then the difference in potential between the plasma, which is near anode potential, and the cathode results in an axial component of E at the load end of the plasma, which supports an E x B drift of electrons across the gap. The analytic model predicts that this loss should increase with higher voltage after opening, and could be eliminated only by removing the plasma from the gap, or eliminating cathode electron emission (both difficult), or by confining this downstream electron flow with an applied magnetic field

Electron drift time in silicon drift detectors: A technique for high precision measurement of electron drift mobility

International Nuclear Information System (INIS)

Castoldi, A.; Rehak, P.

1995-01-01

This paper presents a precise absolute measurement of the drift velocity and mobility of electrons in high resistivity silicon at room temperature. The electron velocity is obtained from the differential measurement of the drift time of an electron cloud in a silicon drift detector. The main features of the transport scheme of this class of detectors are: the high uniformity of the electron motion, the transport of the signal electrons entirely contained in the high-purity bulk, the low noise timing due to the very small anode capacitance (typical value 100 fF), and the possibility to measure different drift distances, up to the wafer diameter, in the same semiconductor sample. These features make the silicon drift detector an optimal device for high precision measurements of carrier drift properties. The electron drift velocity and mobility in a 10 kΩ cm NTD n-type silicon wafer have been measured as a function of the electric field in the range of possible operation of a typical drift detector (167--633 V/cm). The electron ohmic mobility is found to be 1394 cm 2 /V s. The measurement precision is better than 1%. copyright 1995 American Institute of Physics

Drift Degradation Analysis

Energy Technology Data Exchange (ETDEWEB)

Dwayne C. Kicker

2001-09-28

A statistical description of the probable block sizes formed by fractures around the emplacement drifts has been developed for each of the lithologic units of the repository host horizon. A range of drift orientations with the drift azimuth varied in 15{sup o} increments has been considered in the static analysis. For the quasi-static seismic analysis, and the time-dependent and thermal effects analysis, two drift orientations have been considered: a drift azimuth of 105{sup o} and the current emplacement drift azimuth of 75{sup o}. The change in drift profile resulting from progressive deterioration of the emplacement drifts has been assessed both with and without backfill. Drift profiles have been determined for four different time increments, including static (i.e., upon excavation), 200 years, 2,000 years, and 10,000 years. The effect of seismic events on rock fall has been analyzed. Block size distributions and drift profiles have been determined for three seismic levels, including a 1,000-year event, a 5,000-year event, and a 10,000-year event. Data developed in this modeling and analysis activity have been entered into the TDMS (DTN: MO0109RDDAAMRR.003). The following conclusions have resulted from this drift degradation analysis: (1) The available fracture data are suitable for supporting a detailed key block analysis of the repository host horizon rock mass. The available data from the north-south Main Drift and the east-west Cross Drift provide a sufficient representative fracture sample of the repository emplacement drift horizon. However, the Tptpln fracture data are only available from a relatively small section of the Cross Drift, resulting in a smaller fracture sample size compared to the other lithologic units. This results in a lower degree of confidence that the key block data based on the Tptpln data set is actually representative of the overall Tptpln key block population. (2) The seismic effect on the rock fall size distribution for all events

Ionization chamber

International Nuclear Information System (INIS)

1977-01-01

An improved ionization chamber type X-ray detector comprises a heavy gas at high pressure disposed between an anode and a cathode. An open grid structure is placed next to the anode and is maintained at a voltage intermediate between the cathode and anode potentials. The electric field which is produced by positive ions drifting towards the cathode is thus shielded from the anode. Current measuring circuits connected to the anode are, therefore, responsive only to electron current flow within the chamber and the recovery time of the chamber is shortened. The grid structure also serves to shield the anode from electrical currents which might otherwise be induced by mechanical vibrations in the ionization chamber structure

Effect of cathode electron-receiver on the performance of microbial fuel cells

Energy Technology Data Exchange (ETDEWEB)

Kong, Xiaoying; Li, Dong [Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640 (China); Graduate School of Chinese Academy of Sciences, Beijing 100039 (China); Sun, Yongming; Yuan, Zhenhong; Li, Lianhua; Li, Yin [Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640 (China)

2010-07-15

Performance of cathode electron receivers has direct effect on the voltage and power density of MFC. This paper explored the electrical performance of MFC with potassium permanganate, ferricyanide solution and dissolved oxygen (DO) as cathode electron receivers. The results showed that the internal resistance of MFC with DO depends on catalyst and is higher than that of MFC with potassium permanganate and potassium ferricyanide solution. The maximum volume power density is 4.35 W/m{sup 3}, and the smallest internal resistance is only about 54 {omega}. In case of DO, the internal resistance and power density is different depending on the catalyst and is not too much related to the membranes. (author)

Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries

Science.gov (United States)

Mohanty, Debasish; Dahlberg, Kevin; King, David M.; David, Lamuel A.; Sefat, Athena S.; Wood, David L.; Daniel, Claus; Dhar, Subhash; Mahajan, Vishal; Lee, Myongjai; Albano, Fabio

2016-05-01

The energy density of current lithium-ion batteries (LIBs) based on layered LiMO2 cathodes (M = Ni, Mn, Co: NMC; M = Ni, Co, Al: NCA) needs to be improved significantly in order to compete with internal combustion engines and allow for widespread implementation of electric vehicles (EVs). In this report, we show that atomic layer deposition (ALD) of titania (TiO2) and alumina (Al2O3) on Ni-rich FCG NMC and NCA active material particles could substantially improve LIB performance and allow for increased upper cutoff voltage (UCV) during charging, which delivers significantly increased specific energy utilization. Our results show that Al2O3 coating improved the NMC cycling performance by 40% and the NCA cycling performance by 34% at 1 C/-1 C with respectively 4.35 V and 4.4 V UCV in 2 Ah pouch cells. High resolution TEM/SAED structural characterization revealed that Al2O3 coatings prevented surface-initiated layered-to-spinel phase transitions in coated materials which were prevalent in uncoated materials. EIS confirmed that Al2O3-coated materials had significantly lower increase in the charge transfer component of impedance during cycling. The ability to mitigate degradation mechanisms for Ni-rich NMC and NCA illustrated in this report provides insight into a method to enable the performance of high-voltage LIBs.

Formation of 1.4 MeV runaway electron flows in air using a solid-state generator with 10 MV/ns voltage rise rate

Science.gov (United States)

Mesyats, G. A.; Pedos, M. S.; Rukin, S. N.; Rostov, V. V.; Romanchenko, I. V.; Sadykova, A. G.; Sharypov, K. A.; Shpak, V. G.; Shunailov, S. A.; Ul'masculov, M. R.; Yalandin, M. I.

2018-04-01

Fulfillment of the condition that the voltage rise time across an air gap is comparable with the time of electron acceleration from a cathode to an anode allows a flow of runaway electrons (REs) to be formed with relativistic energies approaching that determined by the amplitude of the voltage pulse. In the experiment described here, an RE energy of 1.4 MeV was observed by applying a negative travelling voltage pulse of 860-kV with a maximum rise rate of 10 MV/ns and a rise time of 100-ps. The voltage pulse amplitude was doubled at the cathode of the 2-cm-long air gap due to the delay of conventional pulsed breakdown. The above-mentioned record-breaking voltage pulse of ˜120 ps duration with a peak power of 15 GW was produced by an all-solid-state pulsed power source utilising pulse compression/sharpening in a multistage gyromagnetic nonlinear transmission line.

Field dependence of the electron drift velocity along the hexagonal axis of 4H-SiC

Energy Technology Data Exchange (ETDEWEB)

Ivanov, P. A., E-mail: Pavel.Ivanov@mail.ioffe.ru; Potapov, A. S.; Samsonova, T. P.; Grekhov, I. V. [Russian Academy of Sciences, Ioffe Physical–Technical Institute (Russian Federation)

2016-07-15

The forward current–voltage characteristics of mesa-epitaxial 4H-SiC Schottky diodes are measured in high electric fields (up to 4 × 10{sup 5} V/cm) in the n-type base region. A semi-empirical formula for the field dependence of the electron drift velocity in 4H-SiC along the hexagonal axis of the crystal is derived. It is shown that the saturated drift velocity is (1.55 ± 0.05) × 10{sup 7} cm/s in electric fields higher than 2 × 10{sup 5} V/cm.

Atomic-Resolution Visualization of Distinctive Chemical Mixing Behavior of Ni, Co and Mn with Li in Layered Lithium Transition-Metal Oxide Cathode Materials

Energy Technology Data Exchange (ETDEWEB)

Yan, Pengfei; Zheng, Jianming; Lv, Dongping; Wei, Yi; Zheng, Jiaxin; Wang, Zhiguo; Kuppan, Saravanan; Yu, Jianguo; Luo, Langli; Edwards, Danny J.; Olszta, Matthew J.; Amine, Khalil; Liu, Jun; Xiao, Jie; Pan, Feng; Chen, Guoying; Zhang, Jiguang; Wang, Chong M.

2015-07-06

Capacity and voltage fading of layer structured cathode based on lithium transition metal oxide is closely related to the lattice position and migration behavior of the transition metal ions. However, it is scarcely clear about the behavior of each of these transition metal ions. We report direct atomic resolution visualization of interatomic layer mixing of transition metal (Ni, Co, Mn) and lithium ions in layer structured oxide cathodes for lithium ion batteries. Using chemical imaging with aberration corrected scanning transmission electron microscope (STEM) and DFT calculations, we discovered that in the layered cathodes, Mn and Co tend to reside almost exclusively at the lattice site of transition metal (TM) layer in the structure or little interlayer mixing with Li. In contrast, Ni shows high degree of interlayer mixing with Li. The fraction of Ni ions reside in the Li layer followed a near linear dependence on total Ni concentration before reaching saturation. The observed distinctively different behavior of Ni with respect to Co and Mn provides new insights on both capacity and voltage fade in this class of cathode materials based on lithium and TM oxides, therefore providing scientific basis for selective tailoring of oxide cathode materials for enhanced performance.

Plasma Ion Source with an Internal Evaporator

International Nuclear Information System (INIS)

Turek, M.; Drozdziel, A.; Pyszniak, K.; Prucnal, S.; Maczka, D.

2011-01-01

A new construction of a hollow cathode ion source equipped with an internal evaporator heated by a spiral cathode filament and arc discharge is presented. The source is especially suitable for production of ions from solids. The proximity of arc discharge region and extraction opening enables production of intense ion beams even for very low discharge current (I a = 1.2 A). The currents of 50 μA (Al + ) and 70 μA (Bi + ) were obtained using the extraction voltage of 25 kV. The source is able to work for several tens of hours without maintenance breaks, giving possibility of high dose implantations. The paper presents the detailed description of the ion source as well as its experimental characteristics like dependences of extracted currents and anode voltage on anode and cathode currents. (author)

DC photoemission electron guns as ERL sources

International Nuclear Information System (INIS)

Sinclair, Charles K.

2006-01-01

Very-high-voltage DC electron guns, delivering moderate duration bunches from photoemission cathodes, and followed by conventional drift bunching and acceleration, offer a practical solution for an ERL injector. In a variant of this scheme, a DC gun is placed in close proximity to a superconducting RF accelerator cavity, with few or no active elements between the gun and cavity. The principal technical challenge with such electron guns arises from field emission from the cathode electrode and its support structure. Field emission may result in voltage breakdown across the cathode-anode gap, or a punch-through failure of the insulator holding off the cathode potential, as well as lesser though still serious problems. Various means to mitigate these problems are described. The operational lifetime of high quantum efficiency photocathodes in these guns is determined by the vacuum conditions, through phenomena such as chemical poisoning and ion back-bombardment. Minimization of the field strength on electrode structures pushes high-voltage DC guns toward large dimensions and, correspondingly, large outgassing loads, but it is also true that these guns offer many opportunities for achieving excellent vacuum conditions. Good solutions to vacuum problems that had previously limited cathode lifetime have been demonstrated in recent years. Designs for DC guns presently in use and planned for the near future will be described. The parameters necessary for a 100 mA average current, very-high-voltage DC gun with a photocathode operational lifetime greater than 100 h appear to be within reach, but have yet to be demonstrated. A 1 A average current source with good cathode operational lifetime will require developments beyond the present state-of-the-art

Effects of errors in velocity tilt on maximum longitudinal compression during neutralized drift compression of intense beam pulses: II. Analysis of experimental data of the Neutralized Drift Compression eXperiment-I (NDCX-I)

International Nuclear Information System (INIS)

Massidda, Scott; Kaganovich, Igor D.; Startsev, Edward A.; Davidson, Ronald C.; Lidia, Steven M.; Seidl, Peter; Friedman, Alex

2012-01-01

Neutralized drift compression offers an effective means for particle beam focusing and current amplification with applications to heavy ion fusion. In the Neutralized Drift Compression eXperiment-I (NDCX-I), a non-relativistic ion beam pulse is passed through an inductive bunching module that produces a longitudinal velocity modulation. Due to the applied velocity tilt, the beam pulse compresses during neutralized drift. The ion beam pulse can be compressed by a factor of more than 100; however, errors in the velocity modulation affect the compression ratio in complex ways. We have performed a study of how the longitudinal compression of a typical NDCX-I ion beam pulse is affected by the initial errors in the acquired velocity modulation. Without any voltage errors, an ideal compression is limited only by the initial energy spread of the ion beam, ΔΕ b . In the presence of large voltage errors, δU⪢ΔE b , the maximum compression ratio is found to be inversely proportional to the geometric mean of the relative error in velocity modulation and the relative intrinsic energy spread of the beam ions. Although small parts of a beam pulse can achieve high local values of compression ratio, the acquired velocity errors cause these parts to compress at different times, limiting the overall compression of the ion beam pulse.

SOI detector with drift field due to majority carrier flow - an alternative to biasing in depletion

Energy Technology Data Exchange (ETDEWEB)

Trimpl, M.; Deptuch, G.; Yarema, R.; /Fermilab

2010-11-01

This paper reports on a SOI detector with drift field induced by the flow of majority carriers. It is proposed as an alternative method of detector biasing compared to standard depletion. N-drift rings in n-substrate are used at the front side of the detector to provide charge collecting field in depth as well as to improve the lateral charge collection. The concept was verified on a 2.5 x 2.5 mm{sup 2} large detector array with 20 {micro}m and 40 {micro}m pixel pitch fabricated in August 2009 using the OKI semiconductor process. First results, obtained with a radioactive source to demonstrate spatial resolution and spectroscopic performance of the detector for the two different pixel sizes will be shown and compared to results obtained with a standard depletion scheme. Two different diode designs, one using a standard p-implantation and one surrounded by an additional BPW implant will be compared as well.

SOI detector with drift field due to majority carrier flow - an alternative to biasing in depletion

International Nuclear Information System (INIS)

Trimpl, M.; Deptuch, G.; Yarema, R.

2010-01-01

This paper reports on a SOI detector with drift field induced by the flow of majority carriers. It is proposed as an alternative method of detector biasing compared to standard depletion. N-drift rings in n-substrate are used at the front side of the detector to provide charge collecting field in depth as well as to improve the lateral charge collection. The concept was verified on a 2.5 x 2.5 mm 2 large detector array with 20 (micro)m and 40 (micro)m pixel pitch fabricated in August 2009 using the OKI semiconductor process. First results, obtained with a radioactive source to demonstrate spatial resolution and spectroscopic performance of the detector for the two different pixel sizes will be shown and compared to results obtained with a standard depletion scheme. Two different diode designs, one using a standard p-implantation and one surrounded by an additional BPW implant will be compared as well.

Characterizing the structural degradation in a PEMFC cathode catalyst layer : carbon corrosion

Energy Technology Data Exchange (ETDEWEB)

Young, A.; Stumper, J. [Ballard Power Systems, Burnaby, BC (Canada); Gyenge, E. [British Columbia Univ., Vancouver, BC (Canada). Dept. of Chemical and Biological Engineering

2009-07-01

The structural degradation resulting from carbon corrosion of a cathode catalyst layer in a polymer electrolyte membrane fuel cell (PEMFC) was investigated in this study. In order to oxidize the catalyst carbon support, the PEMFC catalyst layer was subjected to a 30 hour accelerated stress test that cycled the cathode potential from 0.1 to 1.5 VRHE at 30 and 150 second intervals. The rate and amount of carbon loss was determined by measuring the carbon dioxide in the exhaust gas. The structural degradation of the catalyst layer was characterized and correlated to the PEMFC performance using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and polarization analyses. This analysis revealed a clear thinning of the cathode catalyst layer and gas diffusion layer carbon sub-layer, and a reduction in the effective platinum surface area due to the carbon support oxidation. The thinned cathode catalyst layer changed the water management, and increased the voltage loss associated with the oxygen mass transport and catalyst layer ohmic resistance. In order to further develop and verify this methodology for other degradation mechanisms, emphasis was placed on EIS measurements.

Dike/Drift Interactions

Energy Technology Data Exchange (ETDEWEB)

E.S. Gaffney

2003-10-08

This report documents the model of events associated with a potential intrusion of magma from a volcanic dike into a drift or drifts in the Yucca Mountain Nuclear Waste Repository. The following topics are included in this report: (1) A discussion of dike propagation, which provides the basis for describing the path that a representative dike, or swarm of dikes, would follow during an event. (2) A discussion of magma flow, which evaluates the interaction at the junction of the propagating dike with the drift and the movement of magmatic products into and down drifts and, potentially, through a drift to the surface by way of access drift or a secondary dike opened up along the drift. (3) A discussion of gas flow and conductive cooling of a magma-filled drift, describing how an adjacent drift that has not been intersected by a dike could be affected by post-intrusion phenomena. Note that a gas flow analysis is also addressed in ''Igneous Intrusion Impacts on Waste Form and Waste Packages'' (BSC 2003 [DIRS 161810]), and those results are consistent with the results presented in this report.

Dike/Drift Interactions

International Nuclear Information System (INIS)

E.S. Gaffney

2003-01-01

This report documents the model of events associated with a potential intrusion of magma from a volcanic dike into a drift or drifts in the Yucca Mountain Nuclear Waste Repository. The following topics are included in this report: (1) A discussion of dike propagation, which provides the basis for describing the path that a representative dike, or swarm of dikes, would follow during an event. (2) A discussion of magma flow, which evaluates the interaction at the junction of the propagating dike with the drift and the movement of magmatic products into and down drifts and, potentially, through a drift to the surface by way of access drift or a secondary dike opened up along the drift. (3) A discussion of gas flow and conductive cooling of a magma-filled drift, describing how an adjacent drift that has not been intersected by a dike could be affected by post-intrusion phenomena. Note that a gas flow analysis is also addressed in ''Igneous Intrusion Impacts on Waste Form and Waste Packages'' (BSC 2003 [DIRS 161810]), and those results are consistent with the results presented in this report

Space and time dependent properties of the virtual cathode in a reflex-type pulsed ion diode

International Nuclear Information System (INIS)

Matsumoto, Yoshio; Kitamura, Akira; Yano, Syukuro

1981-01-01

Properties of a virtual cathode in a pulsed ion diode composed of and insulator-mesh anode and a metal-mesh cathode were studied experimentally at anode voltages below 35o kV. Potential distribution in the virtual cathode side was measured with an insulated electrostatic potential probe, and ion beam currents in virtual and real cathode sides were measured with biased ion collectors. Experimental results are given for the space and time behaviors of the anode plasma and the virtual cathode which starts to grow first from a region near a periphery of the metal anode frame and extends over the central region near the anode surface. A loss parameter for the electron current accompanied with the ion beam at the virtual cathode was evaluated from the measured electron current values by using relations derived from the one-dimensional Child-Langmuir theory applied to the reflex triode. The ion beam accompanies a considerable amount of electron current, and this influences the stability of the virtual cathode; this perturbation results in variations of ion current with time. Experimental results for space potentials in the emitted ion beam and the total current flowing in the space of the virtual cathode side are also given, suggesting an existence of high energy electrons of several keV accelerated by positive space potential of the ion beam. (author)

Drift velocity monitoring of the CMS muon drift chambers

CERN Document Server

Sonnenschein, Lars

2010-01-01

The drift velocity in drift tubes of the CMS muon chambers is a key parameter for the muon track reconstruction and trigger. It needs to be monitored precisely in order to detect any deviation from its nominal value. A change in absolute pressure, a variation of the gas admixture or a contamination of the chamber gas by air affect the drift velocity. Furthermore the temperature and magnetic field influence its value. First data, taken with a dedicated Velocity Drift Chamber (VDC) built by RWTH Aachen IIIA are presented.

High-efficiency AlxGa1-xAs/GaAs cathode for photon-enhanced thermionic emission solar energy converters

Science.gov (United States)

Feng, Cheng; Zhang, Yijun; Qian, Yunsheng; Wang, Ziheng; Liu, Jian; Chang, Benkang; Shi, Feng; Jiao, Gangcheng

2018-04-01

A theoretical emission model for AlxGa1-xAs/GaAs cathode with complex structure based on photon-enhanced thermionic emission is developed by utilizing one-dimensional steady-state continuity equations. The cathode structure comprises a graded-composition AlxGa1-xAs window layer and an exponential-doping GaAs absorber layer. In the deduced model, the physical properties changing with the Al composition are taken into consideration. Simulated current-voltage characteristics are presented and some important factors affecting the conversion efficiency are also illustrated. Compared with the graded-composition and uniform-doping cathode structure, and the uniform-composition and uniform-doping cathode structure, the graded-composition and exponential-doping cathode structure can effectively improve the conversion efficiency, which is ascribed to the twofold built-in electric fields. More strikingly, this graded bandgap structure is especially suitable for photon-enhanced thermionic emission devices since a higher conversion efficiency can be achieved at a lower temperature.

Durability and performance optimization of cathode materials for fuel cells

Science.gov (United States)

Colon-Mercado, Hector Rafael

The primary objective of this dissertation is to develop an accelerated durability test (ADT) for the evaluation of cathode materials for fuel cells. The work has been divided in two main categories, namely high temperature fuel cells with emphasis on the Molten Carbonate Fuel Cell (MCFC) cathode current collector corrosion problems and low temperature fuel cells in particular Polymer Electrolyte Fuel Cell (PEMFC) cathode catalyst corrosion. The high operating temperature of MCFC has given it benefits over other fuel cells. These include higher efficiencies (>50%), faster electrode kinetics, etc. At 650°C, the theoretical open circuit voltage is established, providing low electrode overpotentials without requiring any noble metal catalysts and permitting high electrochemical efficiency. The waste heat is generated at sufficiently high temperatures to make it useful as a co-product. However, in order to commercialize the MCFC, a lifetime of 40,000 hours of operation must be achieved. The major limiting factor in the MCFC is the corrosion of cathode materials, which include cathode electrode and cathode current collector. In the first part of this dissertation the corrosion characteristics of bare, heat-treated and cobalt coated titanium alloys were studied using an ADT and compared with that of state of the art current collector material, SS 316. PEMFCs are the best choice for a wide range of portable, stationary and automotive applications because of their high power density and relatively low-temperature operation. However, a major impediment in the commercialization of the fuel cell technology is the cost involved due to the large amount of platinum electrocatalyst used in the cathode catalyst. In an effort to increase the power and decrease the cathode cost in polymer electrolyte fuel cell (PEMFC) systems, Pt-alloy catalysts were developed to increase its activity and stability. Extensive research has been conducted in the area of new alloy development and

Modeling the cathode region of noble gas mixture discharges using Monte Carlo simulation

International Nuclear Information System (INIS)

Donko, Z.; Janossy, M.

1992-10-01

A model of the cathode dark space of DC glow discharges was developed in order to study the effects caused by mixing small amounts (≤2%) of other noble gases (Ne, Ar, Kr and Xe) to He. The motion of charged particles was described by Monte Carlo simulation. Several discharge parameters (electron and ion energy distribution functions, electron and ion current densities, reduced ionization coefficients, and current density-voltage characteristics) were obtained. Small amounts of admixtures were found to modify significantly the discharge parameters. Current density-voltage characteristics obtained from the model showed good agreement with experimental data. (author) 40 refs.; 14 figs

Inductive voltage adder (IVA) for submillimeter radius electron beam

International Nuclear Information System (INIS)

Mazarakis, M.G.; Poukey, J.W.; Maenchen, J.E.

1996-01-01

The authors have already demonstrated the utility of inductive voltage adder accelerators for production of small-size electron beams. In this approach, the inductive voltage adder drives a magnetically immersed foilless diode to produce high-energy (10--20 MeV), high-brightness pencil electron beams. This concept was first demonstrated with the successful experiments which converted the linear induction accelerator RADLAC II into an IVA fitted with a small 1-cm radius cathode magnetically immersed foilless diode (RADLAC II/SMILE). They present here first validations of extending this idea to mm-scale electron beams using the SABRE and HERMES-III inductive voltage adders as test beds. The SABRE experiments are already completed and have produced 30-kA, 9-MeV electron beams with envelope diameter of 1.5-mm FWHM. The HERMES-III experiments are currently underway

Mechanism of Reaction in NaAlCl4 Molten Salt Batteries with Nickel Felt Cathodes and Aluminum Anodes. Part I: Modelling of the Battery Properties at Thermodynamic Equilibrium

DEFF Research Database (Denmark)

Knutz, B.C.; Hjuler, Hans Aage; Berg, Rolf W.

1993-01-01

corresponding Variation of anode potential, cathode potential, and cell voltage as a function of electrolyte composition. For sulfide containing cells the plateau of lowest potential has been found to be associated with essentially pure nickel sulfide, NiySz. A procedure for model fitting to the cathode...

Advanced AEM by Comprehensive Analysis and Modeling of System Drift

Science.gov (United States)

Schiller, Arnulf; Klune, Klaus; Schattauer, Ingrid

2010-05-01

as in flight - show a clear correlation between the drift in raw voltage data and temperatures of critical system components, especially in the transmitter and receiver sections. Further, the correlation with air pressure, humidity, structure geometry and static electricity has been investigated. It shows that in case of a tuned system the dependency of signal phase and amplitude on system component temperatures prevails by far and can explain most of the system drift in the voltage domain. Post-processing for compensating for the drift of HEM-data is done by two different approaches: In the first, temperature dependent transfer functions of the transmitter- and receiver section are modeled on the basis of system temperature data and a correction is derived. In an advanced approach the drift of the system is analyzed by multivariate analysis including a broader set of data (HEM-signal, transmitter-reference signal, system temperatures, humidity, air pressure, height, dynamic loads) and based on an extended model. It proves that such an analysis is able to identify residual drift sources. As a result an integrated modeling scheme is depicted which enables a better separation of signal variations caused by the system or by changes in the measurement geometry from signal variations caused by the source distribution in the ground if critical system parameters are incorporated.

Energy balance of the cathode connection and calculation of the yield of caesium diodes; Bilan des energies dans la connexion de cathode et calcul du rendement dans les diodes a cesium

Energy Technology Data Exchange (ETDEWEB)

Merard, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1964-07-01

The cathode connection is one of the critical elements in the calculation of the yield of caesium diodes. In particular a study is made of the balance of the losses due to the Joule effect, to radiation and to thermal conduction as a function of the shape and the nature of the cathode connection. The internal voltage drop of the diode is obtained from the expression for the total Joule losses of the metallic conductors. The length of the cathode connection is calculated as a function of the losses and the yield is optimized as a function of the relationship existing between the cathodic losses due to thermal conduction and the Joule losses in the connection. The calculations lead to hyper-elliptic integrals which can only be manipulated by series development. The results obtained are approximate. (author) [French] Dans le calcul du rendement des diodes a cesium, la connexion de cathode est l'un des elements critiques. On etudie specialement le bilan des pertes par effet joule, rayonnement et conduction thermique, en fonction de la forme et de la nature de la connexion de cathode. On obtient la chute de tension interne de la diode a partir de l'expression des pertes joules totales dans les conducteurs metalliques. La longueur de la connexion de cathode est calculee en fonction des pertes et l'on optimise le rendement en fonction du rapport qui existe entre les pertes par conduction thermique de la cathode et les pertes joules dans la connexion. Les calculs conduisent a des integrales hyperelliptiques dont la manipulation n'est possible que par des developpements en serie. Les resultats cherches sont approximatifs. (auteur)

Capacity extended bismuth-antimony cathode for high-performance liquid metal battery

Science.gov (United States)

Dai, Tao; Zhao, Yue; Ning, Xiao-Hui; Lakshmi Narayan, R.; Li, Ju; Shan, Zhi-wei

2018-03-01

Li-Bi based liquid metal batteries (LMBs) have attracted interest due to their potential for solving grid scale energy storage problems. In this study, the feasibility of replacing the bismuth cathode with a bismuth-antimony alloy cathode in lithium based LMBs is investigated. The influence of the Bi:Sb ratio on voltage characteristics is evaluated via the constant current discharge method and electrochemical titration. On observing the cross section of the electrode at various stages of discharge, it is determined that both Sb and Bi form solid intermetallics with Li on the cathode. Additionally, the addition of Bi not only reduces the melting temperature of the Bi:Sb intermetallic but also actively contributes to the electrode capacity. Thereafter, a Li|LiCl-LiF|Sb-Bi liquid metal battery with 3 A h nameplate capacity, assembled and cycled at 1 C rate, is found to possess a stable capacity for over 160 cycles. The overall performance of this battery is discussed in the context of cost effectiveness, energy and coulombic efficiencies.

Measurement of the positron-drift time relation of a high-pressure drift chamber

International Nuclear Information System (INIS)

Pruefert, W.

1989-04-01

As a test of its performance, the measurement of the drift time versus drift distance relation of a high pressure drift chamber using cosmic rays is described. Two multiwire proportional chambers, mounted above and below the detector, are used to define the track of the cosmic particle in the drift chamber. The drift chamber is read out by FADCs (Flash Analog to Digital Converter), and the drift time is determined from the FADC signals by the DOS- (Difference Of Samples) method. The measured drift time versus drift distance relation showed good agreement with the relation, which is expected from the spatial dependence of the electric field and the dependence of the drift velocity on this field. (orig.) [de

Plasma source ion implantation

International Nuclear Information System (INIS)

Conrad, J.R.; Forest, C.

1986-01-01

The authors' technique allows the ion implantation to be performed directly within the ion source at higher currents without ion beam extraction and transport. The potential benefits include greatly increased production rates (factors of 10-1000) and the ability to implant non-planar targets without rastering or shadowing. The technique eliminates the ion extractor grid set, beam raster equipment, drift space and target manipulator equipment. The target to be implanted is placed directly within the plasma source and is biased to a large negative potential so that plasma ions gain energy as they accelerate through the potential drop across the sheath that forms at the plasma boundary. Because the sheath surrounds the target on all sides, all surfaces of the target are implanted without the necessity to raster the beam or to rotate the target. The authors have succeeded in implanting nitrogen ions in a silicon target to the depths and concentrations required for surface treatment of materials like stainless steel and titanium alloys. They have performed ESCA measurements of the penetration depth profile of a silicon target that was biased to 30 kV in a nitrogen discharge plasma. Nitrogen ions were implanted to a depth of 700A at a peak concentration of 30% atomic. The measured profile is quite similar to a previously obtained profile in titanium targets with conventional techniques

Measurement of magnetically insulated line voltage using a Thomson Parabola Charged Particle Analyser

International Nuclear Information System (INIS)

Stanley, T.D.; Stinnett, R.W.

1981-01-01

The absence of direct measurements of magnetically insulated line voltage necessitated reliance on inferred voltages based on theoretical calculation and current measurements. This paper presents some of the first direct measurements of magnetically insulated transmission line peak voltages. These measurements were made on the Sandia National Laboratories HydraMITE facility. The peak voltage is measured by observing the energy of negative ions produced at the line cathode and accelerated through the line voltage. The ion energy and the charge-to-mass ratio are measured using the Thomson Parabola mass spectrometry technique. This technique uses parallel E and B fields to deflect the ions. The deflected ions are detected using a microchannel plate coupled to a phosphor screen and photographic film. The Thomson Parabola results are compared to Faraday Cup measurements and to calculated voltages based on current measurements. In addition, the significance of observed positive ions is discussed

Understanding anode and cathode behaviour in high-pressure discharge lamps

Science.gov (United States)

Flesch, P.; Neiger, M.

2005-09-01

High-intensity discharge (HID) lamps have widespread and modern areas of application including general lighting, video/movie projection (e.g. UHP lamp), street/industrial lighting, and automotive headlight lamps (D2/xenon lamp). Even though HID lamps have been known for several decades now, the important plasma-electrode interactions are still not well understood. Because HID lamps are usually operated on ac (electrodes switch alternately from anode to cathode phase), time-dependent simulations including realistic and verified anode and cathode models are essential. Therefore, a recently published investigation of external laser heating of an electrode during anode and cathode phase in an operating HID lamp [28] provided the basis for our present paper. These measurements revealed impressive influences of the external laser heating on electrode fall voltage and electrode temperature. Fortunately, the effects are very different during anode and cathode phase. Thus, by comparing the experimental findings with results from our numerical simulations we can learn much about the principles of electrode behaviour and explain in detail the differences between anode and cathode phase. Furthermore, we can verify our model (which includes plasma column, hot plasma spots in front of the electrodes, constriction zones and near-electrode non-local thermal equilibrium-plasma as well as anode and cathode) that accounts for all relevant physical processes concerning plasma, electrodes and interactions between them. Moreover, we investigate the influence of two different notions concerning ionization and recombination in the near electrode plasma on the numerical results. This improves our physical understanding of near-electrode plasma likewise and further increases the confidence in the model under consideration. These results are important for the understanding and the further development of HID lamps which, due to their small dimensions, are often experimentally inaccessible

Testing a GaAs cathode in SRF gun

International Nuclear Information System (INIS)

Wang, E.; Kewisch, J.; Ben-Zvi, I.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

2011-01-01

RF electron guns with a strained superlattice GaAs cathode are expected to generate polarized electron beams of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface and lower cathode temperature. We plan to install a bulk GaAs:Cs in a SRF gun to evaluate the performance of both the gun and the cathode in this environment. The status of this project is: In our 1.3 GHz 1/2 cell SRF gun, the vacuum can be maintained at nearly 10 -12 Torr because of cryo-pumping at 2K. With conventional activation of bulk GaAs, we obtained a QE of 10% at 532 nm, with lifetime of more than 3 days in the preparation chamber and have shown that it can survive in transport from the preparation chamber to the gun. The beam line has been assembled and we are exploring the best conditions for baking the cathode under vacuum. We report here the progress of our test of the GaAs cathode in the SRF gun. Future particle accelerators, such as eRHIC and the ILC require high-brightness, high-current polarized electrons. Strained superlattice GaAs:Cs has been shown to be an efficient cathode for producing polarized electrons. Activation of GaAs with Cs,O(F) lowers the electron affinity and makes it energetically possible for all the electrons, excited into the conduction band that drift or diffuse to the emission surface, to escape into the vacuum. Presently, all operating polarized electron sources, such as the CEBAF, are DC guns. In these devices, the excellent ultra-high vacuum extends the lifetime of the cathode. However, the low field gradient on the photocathode's emission surface of the DC guns limits the beam quality. The higher accelerating gradients, possible in the RF guns, generate a far better beam. Until recently, most RF guns operated at room temperature, limiting the vacuum to ∼10 -9 Torr. This destroys the GaAs's NEA surface. The SRF guns combine the excellent vacuum conditions of DC guns and the high accelerating

The Impact of Strong Cathodic Polarization on SOC Electrolyte Materials

DEFF Research Database (Denmark)

Kreka, Kosova; Hansen, Karin Vels; Jacobsen, Torben

2016-01-01

One of the most promising reversible energy conversion/storage technologies is that of Solid Oxide Fuel/Electrolysis Cells (SOFC/SOEC, collectively termed SOC). Long term durability is typically required for such devises to become economically feasible, hence considerable amount of work has...... of impurities at the grain boundaries, electrode poisoning, delamination or cracks of the electrolyte etc., have been observed in cells operated at such conditions, lowering the lifetime of the cell1,2. High polarizations are observed at the electrolyte/cathode interface of an electrolysis cell operated at high...... current density. In case of a cell voltage above 1.6 V, p-type and n-type electronic conductivity are often observed at the anode and cathode respectively3. Hence, a considerable part of the current is lost as leakage through the electrolyte, thus lowering the efficiency of the cell considerably....

Current–voltage characteristics of high-voltage 4H-SiC p{sup +}–n{sub 0}–n{sup +} diodes in the avalanche breakdown mode

Energy Technology Data Exchange (ETDEWEB)

Ivanov, P. A., E-mail: Pavel.Ivanov@mail.ioffe.ru; Potapov, A. S.; Samsonova, T. P.; Grekhov, I. V. [Ioffe Physical–Technical Institute (Russian Federation)

2017-03-15

p{sup +}–n{sub 0}–n{sup +} 4H-SiC diodes with homogeneous avalanche breakdown at 1860 V are fabricated. The pulse current–voltage characteristics are measured in the avalanche-breakdown mode up to a current density of 4000 A/cm{sup 2}. It is shown that the avalanche-breakdown voltage increases with increasing temperature. The following diode parameters are determined: the avalanche resistance (8.6 × 10{sup –2} Ω cm{sup 2}), the electron drift velocity in the n{sub 0} base at electric fields higher than 10{sup 6} V/cm (7.8 × 10{sup 6} cm/s), and the relative temperature coefficient of the breakdown voltage (2.1 × 10{sup –4} K{sup –1}).

Drift Degradation Analysis

International Nuclear Information System (INIS)

G.H. Nieder-Westermann

2005-01-01

The outputs from the drift degradation analysis support scientific analyses, models, and design calculations, including the following: (1) Abstraction of Drift Seepage; (2) Seismic Consequence Abstraction; (3) Structural Stability of a Drip Shield Under Quasi-Static Pressure; and (4) Drip Shield Structural Response to Rock Fall. This report has been developed in accordance with ''Technical Work Plan for: Regulatory Integration Modeling of Drift Degradation, Waste Package and Drip Shield Vibratory Motion and Seismic Consequences'' (BSC 2004 [DIRS 171520]). The drift degradation analysis includes the development and validation of rockfall models that approximate phenomenon associated with various components of rock mass behavior anticipated within the repository horizon. Two drift degradation rockfall models have been developed: the rockfall model for nonlithophysal rock and the rockfall model for lithophysal rock. These models reflect the two distinct types of tuffaceous rock at Yucca Mountain. The output of this modeling and analysis activity documents the expected drift deterioration for drifts constructed in accordance with the repository layout configuration (BSC 2004 [DIRS 172801])

Drift velocity and pressure monitoring of the CMS muon drift chambers

CERN Document Server

Sonnenschein, Lars

2011-01-01

The drift velocity in drift tubes of the CMS muon chambers is a key parameter for the muon track reconstruction and trigger. It needs to be monitored precisely in order to detect any deviation from its nominal value. A change in absolute pressure, a variation of the gas admixture or a contamination of the chamber gas by air affect the drift velocity. Furthermore, the temperature and magnetic field influence its value. First data, taken with a dedicated Velocity Drift Chamber (VDC) built by RWTH Aachen IIIA are presented. Another important parameter to be monitored is the pressure inside the muon drift tube chambers. The differential pressure must not exceed a certain value and the absolute pressure has to be kept slightly above ambient pressure to prevent air from entering into the muon drift tube chambers in case of a leak. Latest drift velocity monitoring results are discussed.

A centre-triggered magnesium fuelled cathodic arc thruster uses sublimation to deliver a record high specific impulse

Science.gov (United States)

Neumann, Patrick R. C.; Bilek, Marcela; McKenzie, David R.

2016-08-01

The cathodic arc is a high current, low voltage discharge that operates in vacuum and provides a stream of highly ionised plasma from a solid conducting cathode. The high ion velocities, together with the high ionisation fraction and the quasineutrality of the exhaust stream, make the cathodic arc an attractive plasma source for spacecraft propulsion applications. The specific impulse of the cathodic arc thruster is substantially increased when the emission of neutral species is reduced. Here, we demonstrate a reduction of neutral emission by exploiting sublimation in cathode spots and enhanced ionisation of the plasma in short, high-current pulses. This, combined with the enhanced directionality due to the efficient erosion profiles created by centre-triggering, substantially increases the specific impulse. We present experimentally measured specific impulses and jet power efficiencies for titanium and magnesium fuels. Our Mg fuelled source provides the highest reported specific impulse for a gridless ion thruster and is competitive with all flight rated ion thrusters. We present a model based on cathode sublimation and melting at the cathodic arc spot explaining the outstanding performance of the Mg fuelled source. A further significant advantage of an Mg-fuelled thruster is the abundance of Mg in asteroidal material and in space junk, providing an opportunity for utilising these resources in space.

An AMOLED AC-Biased Pixel Design Compensating the Threshold Voltage and I-R Drop

Directory of Open Access Journals (Sweden)

Ching-Lin Fan

2011-01-01

Full Text Available We propose a novel pixel design and an AC bias driving method for active-matrix organic light-emitting diode (AM-OLED displays using low-temperature polycrystalline silicon thin-film transistors (LTPS-TFTs. The proposed threshold voltage and I-R drop compensation circuit, which comprised three transistors and one capacitor, have been verified to supply uniform output current by simulation work using the Automatic Integrated Circuit Modeling Simulation Program with Integrated Circuit Emphasis (AIM-SPICE simulator. The simulated results demonstrate excellent properties such as low error rate of OLED anode voltage variation (<0.7% and low voltage drop of VDD power line. The proposed pixel circuit effectively enables threshold-voltage-deviation correction of driving TFT and compensates for the voltage drop of VDD power line using AC bias on OLED cathode.

Ways for improvement of the LIU-5/5000 linear induction accelerator parameters

International Nuclear Information System (INIS)

Bobylev, V.I.; Kapchinskij, I.M.; Lapitskij, Yu.Ya.; Plotnikov, V.K.; Chuvilo, I.V.

1987-01-01

The reasons of limitaions to increase the beam current and improve the quality of beam in the electron linear induction accelerator LIU-5/5000 are studied. The necessity to increase the voltage in the gaps of the electron gun, increase the diameter of the cathode and aperture of the drift tube, accuracy of axial symmetry electron gun current-carrying elements and accuracy of gun fabrication are shown. Stabilization of beam parameters require a new high voltage modulators. Different versions of the linac modernization with the use of transformers with cores of 430 and 600 mm are studied. Technical possibilities at several versions of high voltage modulators are discussed

Deposition of diamond-like carbon films by plasma source ion implantation with superposed pulse

International Nuclear Information System (INIS)

Baba, K.; Hatada, R.

2003-01-01

Diamond-like carbon (DLC) films were prepared on silicon wafer substrate by plasma source ion implantation with superposed negative pulse. Methane and acetylene gases were used as working gases for plasma. A negative DC voltage and a negative pulse voltage were superposed and applied to the substrate holder. The DC voltage was changed in the range from 0 to -4 kV and the pulse voltage was changed from 0 to -18 kV. The surface of DLC films was very smooth. The deposition rate of DLC films increased with increasing in superposed DC bias voltage. Carbon ion implantation was confirmed for the DLC film deposited from methane plasma with high pulse voltage. I D /I G ratios of Raman spectroscopy were around 1.5 independent on pulse voltage. The maximum hardness of 20.3 GPa was observed for the film prepared with high DC and high pulse voltage

Ion spectra of the metal vapor vacuum arc ion source with compound and alloy cathodes

Science.gov (United States)

Sasaki, Jun; Brown, Ian G.

1990-01-01

In metal vapor vacuum arc (MEVVA) ion sources, vacuum arc plasma with cathodes of single, pure elements has been utilized for the production of metal ions. In this study, we have investigated the charge state distributions of ions produced in vacuum arc plasmas in a MEVVA ion source for the case when the cathode is an alloy or a compound material. The ion charge state spectra were analyzed by means of a time-of-flight apparatus. We have compared the ion spectra for a cathode of an alloy or a compound material with its constituent elements: TiC/TiN/TiO2/Ti/C, SiC/Si/C, WC/W/C U/UN/(UN-ZrC)/Zr/C, and brass/Zn/Cu. We find that the MEVVA produces ions of all constituent elements in the compound and the alloy cathodes. The charge state distribution of each element differs, however, from the charge state distribution obtained in the vacuum arc with a cathode made of the pure, single constituent element. Fractional values of the total ion numbers of each constituent element in the extracted beam depart from the stoichiometry of the elements in the cathode material. In an operation with a TiC cathode, we irradiated a 304 stainless-steel plate with the extracted beam. Results from glow-discharge spectroscopy (GDS) of the surface show that both titanium and carbon are implanted in the substrate after the irradiation.

Stokes drift

Science.gov (United States)

van den Bremer, T. S.; Breivik, Ø.

2017-12-01

During its periodic motion, a particle floating at the free surface of a water wave experiences a net drift velocity in the direction of wave propagation, known as the Stokes drift (Stokes 1847 Trans. Camb. Philos. Soc. 8, 441-455). More generally, the Stokes drift velocity is the difference between the average Lagrangian flow velocity of a fluid parcel and the average Eulerian flow velocity of the fluid. This paper reviews progress in fundamental and applied research on the induced mean flow associated with surface gravity waves since the first description of the Stokes drift, now 170 years ago. After briefly reviewing the fundamental physical processes, most of which have been established for decades, the review addresses progress in laboratory and field observations of the Stokes drift. Despite more than a century of experimental studies, laboratory studies of the mean circulation set up by waves in a laboratory flume remain somewhat contentious. In the field, rapid advances are expected due to increasingly small and cheap sensors and transmitters, making widespread use of small surface-following drifters possible. We also discuss remote sensing of the Stokes drift from high-frequency radar. Finally, the paper discusses the three main areas of application of the Stokes drift: in the coastal zone, in Eulerian models of the upper ocean layer and in the modelling of tracer transport, such as oil and plastic pollution. Future climate models will probably involve full coupling of ocean and atmosphere systems, in which the wave model provides consistent forcing on the ocean surface boundary layer. Together with the advent of new space-borne instruments that can measure surface Stokes drift, such models hold the promise of quantifying the impact of wave effects on the global atmosphere-ocean system and hopefully contribute to improved climate projections. This article is part of the theme issue 'Nonlinear water waves'.

Drift velocity and pressure monitoring of the CMS muon drift chambers

CERN Document Server

Sonnenschein, Lars

2010-01-01

The drift velocity in drift tubes of the CMS muon chambers is a key parameter for the muon track reconstruction and trigger. It needs to be monitored precisely in order to detect any deviation from its nominal value. A change in absolute pressure, a variation of the gas admixture or a contamination of the chamber gas by air affect the drift velocity. Furthermore, the temperature and magnetic field influence its value. First data, taken with a dedicated Velocity Drift Chamber (VDC) built by RWTH Aachen IIIA are presented. Another important parameter to be monitored is the pressure inside the muon drift tube chambers because the drift velocity depends on it. Furthermore the differential pressure must not exceed a certain value and the absolute pressure has to be kept slightly above ambient pressure to prevent air from entering into the muon drift tube chambers in case of a leak. Latest pressure monitoring results are discussed.

Feasibility of Cathode Surface Coating Technology for High-Energy Lithium-ion and Beyond-Lithium-ion Batteries.

Science.gov (United States)

Kalluri, Sujith; Yoon, Moonsu; Jo, Minki; Liu, Hua Kun; Dou, Shi Xue; Cho, Jaephil; Guo, Zaiping

2017-12-01

Cathode material degradation during cycling is one of the key obstacles to upgrading lithium-ion and beyond-lithium-ion batteries for high-energy and varied-temperature applications. Herein, we highlight recent progress in material surface-coating as the foremost solution to resist the surface phase-transitions and cracking in cathode particles in mono-valent (Li, Na, K) and multi-valent (Mg, Ca, Al) ion batteries under high-voltage and varied-temperature conditions. Importantly, we shed light on the future of materials surface-coating technology with possible research directions. In this regard, we provide our viewpoint on a novel hybrid surface-coating strategy, which has been successfully evaluated in LiCoO 2 -based-Li-ion cells under adverse conditions with industrial specifications for customer-demanding applications. The proposed coating strategy includes a first surface-coating of the as-prepared cathode powders (by sol-gel) and then an ultra-thin ceramic-oxide coating on their electrodes (by atomic-layer deposition). What makes it appealing for industry applications is that such a coating strategy can effectively maintain the integrity of materials under electro-mechanical stress, at the cathode particle and electrode- levels. Furthermore, it leads to improved energy-density and voltage retention at 4.55 V and 45 °C with highly loaded electrodes (≈24 mg.cm -2 ). Finally, the development of this coating technology for beyond-lithium-ion batteries could be a major research challenge, but one that is viable. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

MUON DETECTOR: BARREL DRIFT TUBES (DT) AND ALIGNMENT

CERN Multimedia

Marco Dallavalle

After months of cosmics data taking the drift tube (DT) detector is in good shape, ready for LHC beams. Several hundreds of millions of cosmics events have been recorded; out of those, more than 90% were triggered by the DT system. Data integrity analyses have shown a very reliable read-out system, also during high rate tests. With a 98% of the detector operational, only awaiting the arrival of some low voltage modules and for the completion of the DT Track Finder system, data taking is starting to become routine job. These continuous running exercises have been very useful to study performance and reliability of the detector in a medium term period, allowing understanding and fixing failures that have occurred with low frequency. Drift tubes have become a very stable system, becoming a service of muon triggering for the tracker after its final installation. During the last months, major efforts have taken place in synchronization tasks, within the DT system (250 chambers) and also with the rest of the CMS su...

High energy mechano-chemical milling: Convenient approach to synthesis of LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} high voltage cathode for lithium ion batteries

Energy Technology Data Exchange (ETDEWEB)

Datta, Moni Kanchan, E-mail: mkd16@pitt.edu [Bioengineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Center for Complex Engineered Multifunctional Materials, University of Pittsburgh, PA 15261 (United States); Ramanathan, Madhumati [Bioengineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Jampani, Prashanth [Chemical and Petroleum Engineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Saha, Partha [Bioengineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Epur, Rigved [Mechanical Engineering and Materials Science, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Kadakia, Karan [Chemical and Petroleum Engineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Chung, Sung Jae [Mechanical Engineering and Materials Science, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Patel, Prasad; Gattu, Bharat [Chemical and Petroleum Engineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Manivannan, Ayyakkannu [US Department of Energy, National Energy Technology Laboratory, Morgantown, WV 26507 (United States); Kumta, Prashant N., E-mail: pkumta@pitt.edu [Bioengineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Center for Complex Engineered Multifunctional Materials, University of Pittsburgh, PA 15261 (United States); Chemical and Petroleum Engineering, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); Mechanical Engineering and Materials Science, Swanson School of Engineering, University of Pittsburgh, PA 15261 (United States); School of Dental Medicine, University of Pittsburgh, PA 15261 (United States)

2014-12-15

Graphical abstract: Nanostructured high voltage spinel phase of LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} (LMNO) of particle size ∼10–40 nm has been synthesized by a cost effective high energy mechanical milling (HEMM) approach followed by low temperature thermal treatments. High energy mechanical milling of lithium and manganese oxide precursors followed by moderate heat treatment results in the formation of single phase of LMNO, the high voltage spinel phase. The nanostructured LMNO has been studied as a high voltage cathode for lithium ion rechargeable batteries. Cyclic voltammetry as well as the differential capacity plots of nanostructured LMNO show the occurrence of two major reversible reactions occurring in the potential window of ∼2–3.6 V and ∼3.6–5.1 V with an associated specific capacity ∼105 mAh/g and ∼128 mAh/g, respectively. The nanostructured LMNO synthesized by the HEMM process followed by thermal treatments at ∼773 K, ∼873 K and ∼973 K shows a reversible capacity ∼120–110 mAh/g when cycled at a rate of ∼20 mA/g (∼C/6) in the potential window ∼3.6–5.1 V. Furthermore, the nanostructured HEMM derived LMNO shows a moderate rate capability with a capacity retention ∼87 mAh/g when cycled at ∼80 mA/g (∼C) rate. - Highlights: • Generation of LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} (LMNO) spinel by a cost effective HEMM process. • HEMM derived LMNO spinel phase shows a capacity of ∼128 mAh/g. • HEMM derived spinel exhibits a capacity retention of ∼87 mAh/g at ∼1C rate. • SEM analysis shows good structural integrity of the cycled electrode. • Charge transfer resistance increase during cycling causes capacity fade. - Abstract: The high voltage spinel form of LiMn{sub 1.5}Ni{sub 0.5}O{sub 4} (LMNO) with a particle size ∼10–40 nm has been synthesized for the first time using high energy mechanical milling (HEMM) followed by low temperature thermal treatments using Li{sub 2}O, MnO{sub 2} and NiO as the starting

Using elastin protein to develop highly efficient air cathodes for lithium-O2 batteries

International Nuclear Information System (INIS)

Guo, Guilue; Ang, Huixiang; Tan, Huiteng; Zhang, Yu; Guo, Yuanyuan; Fong, Eileen; Yan, Qingyu; Yao, Xin

2016-01-01

Transition metal-nitrogen/carbon (M-N/C, M = Fe, Co) catalysts are synthesized using environmentally friendly histidine-tag-rich elastin protein beads, metal sulfate and water soluble carbon nanotubes followed by post-annealing and acid leaching processes. The obtained catalysts are used as cathode materials in lithium-O 2 batteries. It has been discovered that during discharge, Li 2 O 2 nanoparticles first nucleate and grow around the bead-decorated CNT regions (M-N/C centres) and coat on the catalysts at a high degree of discharge. The Fe-N/C catalyst-based cathodes deliver a capacity of 12 441 mAh g −1 at a current density of 100 mA g −1 . When they were cycled at a limited capacity of 800 mAh g −1 at current densities of 200 or 400 mA g −1 , these cathodes showed stable charge voltages of ∼3.65 or 3.90 V, corresponding to energy efficiencies of ∼71.2 or 65.1%, respectively. These results are considerably superior to those of the cathodes based on bare annealed CNTs, which prove that the Fe-N/C catalysts developed here are promising for use in non-aqueous lithium-O 2 battery cathodes. (paper)

Using elastin protein to develop highly efficient air cathodes for lithium-O2 batteries

Science.gov (United States)

Guo, Guilue; Yao, Xin; Ang, Huixiang; Tan, Huiteng; Zhang, Yu; Guo, Yuanyuan; Fong, Eileen; Yan, Qingyu

2016-01-01

Transition metal-nitrogen/carbon (M-N/C, M = Fe, Co) catalysts are synthesized using environmentally friendly histidine-tag-rich elastin protein beads, metal sulfate and water soluble carbon nanotubes followed by post-annealing and acid leaching processes. The obtained catalysts are used as cathode materials in lithium-O2 batteries. It has been discovered that during discharge, Li2O2 nanoparticles first nucleate and grow around the bead-decorated CNT regions (M-N/C centres) and coat on the catalysts at a high degree of discharge. The Fe-N/C catalyst-based cathodes deliver a capacity of 12 441 mAh g-1 at a current density of 100 mA g-1. When they were cycled at a limited capacity of 800 mAh g-1 at current densities of 200 or 400 mA g-1, these cathodes showed stable charge voltages of ˜3.65 or 3.90 V, corresponding to energy efficiencies of ˜71.2 or 65.1%, respectively. These results are considerably superior to those of the cathodes based on bare annealed CNTs, which prove that the Fe-N/C catalysts developed here are promising for use in non-aqueous lithium-O2 battery cathodes.

Dike/Drift Interactions

Energy Technology Data Exchange (ETDEWEB)

E. Gaffiney

2004-11-23

This report presents and documents the model components and analyses that represent potential processes associated with propagation of a magma-filled crack (dike) migrating upward toward the surface, intersection of the dike with repository drifts, flow of magma in the drifts, and post-magma emplacement effects on repository performance. The processes that describe upward migration of a dike and magma flow down the drift are referred to as the dike intrusion submodel. The post-magma emplacement processes are referred to as the post-intrusion submodel. Collectively, these submodels are referred to as a conceptual model for dike/drift interaction. The model components and analyses of the dike/drift interaction conceptual model provide the technical basis for assessing the potential impacts of an igneous intrusion on repository performance, including those features, events, and processes (FEPs) related to dike/drift interaction (Section 6.1).

Dike/Drift Interactions

International Nuclear Information System (INIS)

Gaffiney, E.

2004-01-01

This report presents and documents the model components and analyses that represent potential processes associated with propagation of a magma-filled crack (dike) migrating upward toward the surface, intersection of the dike with repository drifts, flow of magma in the drifts, and post-magma emplacement effects on repository performance. The processes that describe upward migration of a dike and magma flow down the drift are referred to as the dike intrusion submodel. The post-magma emplacement processes are referred to as the post-intrusion submodel. Collectively, these submodels are referred to as a conceptual model for dike/drift interaction. The model components and analyses of the dike/drift interaction conceptual model provide the technical basis for assessing the potential impacts of an igneous intrusion on repository performance, including those features, events, and processes (FEPs) related to dike/drift interaction (Section 6.1)

Nitrate as an Oxidant in the Cathode Chamber of a Microbial Fuel Cell for Both Power Generation and Nutrient Removal Purposes

DEFF Research Database (Denmark)

Fang, Cheng; Min, Booki; Angelidaki, Irini

2011-01-01

with the operation without catalyst. Nitrate was reduced to nitrite and ammonia in the liquid phase at a ratio of 0.6% and 51.8% of the total nitrate amount. These results suggest that nitrate can be successfully used as an oxidant for power generation without aeration and also nitrate removal from water in MFC......Nitrate ions were used as the oxidant in the cathode chamber of a microbial fuel cell (MFC) to generate electricity from organic compounds with simultaneous nitrate removal. The MFC using nitrate as oxidant could generate a voltage of 111 mV (1,000 Ω) with a plain carbon cathode. The maximum power...... density achieved was 7.2 mW m−2 with a 470 Ω resistor. Nitrate was reduced from an initial concentration of 49 to 25 mg (NO3−−N) L−1 during 42-day operation. The daily removal rate was 0.57 mg (NO3−–N) L−1 day−1 with a voltage generation of 96 mV. In the presence of Pt catalyst dispersed on cathode...

Observation of radio frequency ring-shaped hollow cathode discharge plasma with MgO and Al electrodes for plasma processing

International Nuclear Information System (INIS)

Ohtsu, Yasunori; Matsumoto, Naoki

2014-01-01

Various high-density plasma sources have been proposed for plasma processing. Especially, the hollow cathode discharge is one of the powerful ones. In this work, radio-frequency (RF) driven ring-shaped hollow cathode discharges with high secondary-electron emission have been investigated, using an aluminum (Al) cathode, coated or not with magnesium oxide (MgO). The thickness of MgO thin film is approximately 200 nm. The RF discharge voltage for the coated cathode is almost the same as that for the uncoated one, in a wide range of Ar gas pressure, from 5.3 to 53.2 Pa. The results reveal that the plasma density has a peak at an Ar gas pressure of 10.6 Pa for both cathodes. The plasma density for the coated cathode is about 1.5–3 times higher than that for the uncoated one, at various gas pressures. To the contrary, the electron temperature for the coated cathode is lower than temperature obtained with the uncoated cathode, at various gas pressures. Radial profiles of electron saturation current, which is proportional to plasma flux, are also examined for a wide range of gas pressure. Radial profiles of electron temperature at various axial positions are almost uniform for both cathodes so that the diffusion process due to density gradient is dominant for plasma transport. The secondary electrons emitted from the coated cathode contribute to the improvement of the plasma flux radial profile obtained using the uncoated cathode

Full-color laser cathode ray tube (L-CRT) projector

Science.gov (United States)

Kozlovskiy, Vladimir; Nasibov, Alexander S.; Popov, Yuri M.; Reznikov, Parvel V.; Skasyrsky, Yan K.

1995-04-01

A full color TV projector based on three laser cathode-ray tubes (L-CRT) is described. A water-cooled laser screen (LS) is the radiation element of the L-CRT. We have produced three main colors (blue, green and red) by using the LS made of three II-VI compounds: ZnSe ((lambda) equals 475 nm), CdS ((lambda) equals 530 nm) and ZnCdSe (630 nm). The total light flow reaches 1500 Lm, and the number of elements per line is not less than 1000. The LS efficiency may be about 10 Lm/W. In our experiments we have tested new electron optics: - (30 - 37) kV are applied to the cathode unit of the electron gun; the anode of the e-gun and the e-beam intensity modulator are under low potential; the LS has a potential + (30 - 37) kV. The accelerating voltage is divided into two parts, and this enables us to diminish the size and weight of the projector.

How the charge-neutrality level of interface states controls energy level alignment in cathode contacts of organic bulk-heterojunction solar cells.

Science.gov (United States)

Guerrero, Antonio; Marchesi, Luís F; Boix, Pablo P; Ruiz-Raga, Sonia; Ripolles-Sanchis, Teresa; Garcia-Belmonte, Germà; Bisquert, Juan

2012-04-24

Electronic equilibration at the metal-organic interface, leading to equalization of the Fermi levels, is a key process in organic optoelectronic devices. How the energy levels are set across the interface determines carrier extraction at the contact and also limits the achievable open-circuit voltage under illumination. Here, we report an extensive investigation of the cathode energy equilibration of organic bulk-heterojunction solar cells. We show that the potential to balance the mismatch between the cathode metal and the organic layer Fermi levels is divided into two contributions: spatially extended band bending in the organic bulk and voltage drop at the interface dipole layer caused by a net charge transfer. We scan the operation of the cathode under a varied set of conditions, using metals of different work functions in the range of ∼2 eV, different fullerene acceptors, and several cathode interlayers. The measurements allow us to locate the charge-neutrality level within the interface density of sates and calculate the corresponding dipole layer strength. The dipole layer withstands a large part of the total Fermi level mismatch when the polymer:fullerene blend ratio approaches ∼1:1, producing the practical alignment between the metal Fermi level and the charge-neutrality level. Origin of the interface states is linked with fullerene reduced molecules covering the metal contact. The dipole contribution, and consequently the band bending, is highly sensitive to the nature and amount of fullerene molecules forming the interface density of states. Our analysis provides a detailed picture of the evolution of the potentials in the bulk and the interface of the solar cell when forward voltage is applied or when photogeneration takes place.

Characteristics of a large vacuum wave precursor on the SABRE voltage adder MITL and extraction ion diode

International Nuclear Information System (INIS)

Cuneo, M.E.; Hanson, D.L.; Menge, P.R.; Poukey, J.W.; Savage, M.E.

1994-01-01

SABRE (Sandia Accelerator and Beam Research Experiment) is a ten-cavity linear induction magnetically insulated voltage adder (6 MV, 300 kA) operated in positive polarity to investigate issues relevant to ion beam production and propagation for inertial confinement fusion. The voltage adder section is coupled to an applied-B extraction ion diode via a long coaxial output transmission line. Observations indicate that the power propagates in a vacuum wave prior to electron emission. After the electron emission threshold is reached, power propagates in a magnetically insulated wave. The precursor is observed to have a dominant impact on he turn-on, impedance history, and beam characteristics of applied-B ion diodes since the precursor voltage is large enough to cause electron emission at the diode from both the cathode feed and cathode tips. The amplitude of the precursor at the load (3--4.5 MV) is a significant fraction of the maximum load voltage (5--6 MV) because (1) the transmission line gaps ( ∼ 9 cm at output) and therefore impedances are relatively large, and hence the electric field threshold for electron emission (200 to 300 kV/cm) is not reached until well into the power pulse rise time; and (2) the rapidly falling forward wave and diode impedance reduces the ratio of main pulse voltage to precursor voltage. Experimental voltage and current data from the transmission line and the ion diode will be presented and compared with TWOQUICK (2-D electromagnetic PIC code) simulations and analytic models

Luminous flux improvement of xenon fluorescent lamps by applying synchronized high-voltage pulse to the auxiliary external electrode

Energy Technology Data Exchange (ETDEWEB)

Motomura, Hideki; Oka, Kojiro; Sogabe, Toru; Jinno, Masafumi, E-mail: hmoto@mayu.ee.ehime-u.ac.jp [Department of Electrical and Electronic Engineering, Ehime University 3 Bunkyo-cho, Matsuyama, Ehime 790-8577 (Japan)

2011-06-08

As the environmental awareness of people becomes stronger, the demand for mercury-free light sources also becomes stronger. The authors have been developing cold cathode fluorescent lamps in which xenon gas is filled as an ultraviolet radiator instead of mercury. Previously the authors reported the luminous flux enhancement method using a grounded auxiliary external electrode (AEE). In this paper, in order to improve the luminous flux much more, a positive voltage pulse which was synchronized to the main driving negative voltage pulse was applied to the AEE. As a result, the maximum input power increased under which the positive column did not constrict and the luminous flux improved by 70% at the xenon filling pressure of 6.7 kPa. It is proved that the positive voltage pulse application to the AEE with the amplitude of more than 2 kV expands the positive column in the radial direction. It is attributed to the phenomenon that the residual ions and electrons, which are generated by dielectric barrier discharge between the AEE and the anode during the falling edge of the negative pulse to the cathode, spread the discharge path from the anode towards the AEE during the cold cathode discharge mode. By increasing the xenon filling pressure, luminous efficacy was improved to 25 lm W{sup -1}.

Laboratory and test beam results from a large-area silicon drift detector

CERN Document Server

Bonvicini, V; Giubellino, P; Gregorio, A; Idzik, M; Kolojvari, A A; Montaño-Zetina, L M; Nouais, D; Petta, C; Rashevsky, A; Randazzo, N; Reito, S; Tosello, F; Vacchi, A; Vinogradov, L I; Zampa, N

2000-01-01

A very large-area (6.75*8 cm/sup 2/) silicon drift detector with integrated high-voltage divider has been designed, produced and fully characterised in the laboratory by means of ad hoc designed MOS injection electrodes. The detector is of the "butterfly" type, the sensitive area being subdivided into two regions with a maximum drift length of 3.3 cm. The device was also tested in a pion beam (at the CERN PS) tagged by means of a microstrip detector telescope. Bipolar VLSI front-end cells featuring a noise of 250 e/sup -/ RMS at 0 pF with a slope of 40 e/sup -//pF have been used to read out the signals. The detector showed an excellent stability and featured the expected characteristics. Some preliminary results will be presented. (12 refs).

Explosive-Emission Plasma Dynamics in Ion Diode in Double-Pulse Mode

International Nuclear Information System (INIS)

Pushkarev, Alexander I.; Isakova, Yulia I.

2011-01-01

The results of an experimental investigation of explosive-emission plasma dynamics in an ion diode with self-magnetic insulation are presented. The investigations were accomplished at the TEMP-4M accelerator set in a mode of double pulse formation. Plasma behaviour in the anode-cathode gap was analyzed according to both the current-voltage characteristics of the diode (time resolution of 0.5 ns) and thermal imprints on a target (spatial resolution of 0.8 mm). It was shown that when plasma formation at the potential electrode was complete, and up until the second (positive) pulse, the explosive-emission plasma expanded across the anode-cathode gap with a speed of 1.3±0.2 cm/μs. After the voltage polarity at the potential electrode was reversed (second pulse), the plasma erosion in the anode-cathode gap (similar to the effect of a plasma opening switch) occurred. During the generation of an ion beam the size of the anode-cathode gap spacing was determined by the thickness of the plasma layer on the potential electrode and the layer thickness of the electrons drifting along the grounded electrode. (15th asian conference on electrical discharge)

Implantable biochemical fuel cell. [German patent

Energy Technology Data Exchange (ETDEWEB)

Richter, G; Rao, J R

1978-09-14

Implantable biochemical fuel cells for the operation of heart pacemakers or artificial hearts convert oxidisable body substances such as glucose on the anode side and reduce the oxygen contained in body fluids at the cathode. The anode and cathode are separated by membranes which are impermeable to albumen and blood corpuscles in body fluids. A chemical shortcircuit cannot occur in practice if, according to the invention, one or more selective oxygen electrodes with carbon as catalyst are arranged so that the mixture which diffuses into the cell from body fluids during operation reaches the fuel cell electrode through the porous oxygen electrode. The membranes used must be permeable to water. Cellulose, polymerised polyvinyl alcohol or an ion exchanger with a buffering capacity between pH5 and 8 act as permeable materials.

A study on the chemical stability and electrode performance of modified NiO cathodes for molten carbonate fuel cells

International Nuclear Information System (INIS)

Kim, Seung-Goo; Yoon, Sung Pil; Han, Jonghee; Nam, Suk Woo; Lim, Tae Hoon; Oh, In-Hwan; Hong, Seong-Ahn

2004-01-01

The chemical stabilities of modified NiO cathodes doped with 1.5 mol% CoO and 1.5 mol% LiCoO 2 fabricated by a conventional tape casting method were evaluated through the real MCFC single cell operation. The heat-treated samples before oxidation had proper porosities and microstructures for a MCFC cathode. At 150 mA cm -2 in current density, the MCFC single cell using a CoO-doped NiO cathode showed stable cell voltages in the range of 0.833-0.843 V for 1000 h. In contrast, the cell using a LiCoO 2 -doped NiO cathode with a maximum of 0.836 V at 500 h degraded to 0.826 V at 1000 h due to a wet seal breakdown at the cathode side. The amounts of nickel precipitated in the electrolytes of the cells using modified NiO cathodes doped with CoO and LiCoO 2 after the operation for 1000 h were 1.2 and 1.4 wt.%, respectively, which were about 60% lower than that of the standard cells using pure NiO cathodes. The enhanced chemical stability of modified NiO cathodes seems to be attributed to the fact that the presence of cobalt increases the lithium content in the cathodes by converting Ni 2+ to Ni 3+ , resulting in stabilizing the layered crystal structure

Decolorization of azo dye and generation of electricity by microbial fuel cell with laccase-producing white-rot fungus on cathode

International Nuclear Information System (INIS)

Lai, Chi-Yung; Wu, Chih-Hung; Meng, Chui-Ting; Lin, Chi-Wen

2017-01-01

Highlights: • A laccase-producing fungus on cathode of MFC was used to enhance degradation of azo dye. • Laccase-producing fungal cathodes performed better than laccase-free control cathodes. • A maximum power density of 13.38 mW/m"2 and an >90% decolorization of acid orange 7 were obtained. • Growing a fungal culture with continuous laccase production improved MFC’s electricity generation. - Abstract: Wood-degrading white-rot fungi produce many extracellular enzymes, including the multi-copper oxidative enzyme laccase (EC 1.10.3.2). Laccase uses atmospheric oxygen as the electron acceptor to catalyze a one-electron oxidation reaction of phenolic compounds and therefore has the potential to simultaneously act as a cathode catalyst in a microbial fuel cell (MFC) and degrade azo dye pollutants. In this study, the laccase-producing white-rot fungus Ganoderma lucidum BCRC 36123 was planted on the cathode surface of a single-chamber MFC to degrade the azo dye acid orange 7 (AO7) synergistically with an anaerobic microbial community in the anode chamber. In a batch culture, the fungus used AO7 as the sole carbon source and produced laccase continuously, reaching a maximum activity of 20.3 ± 0.3 U/L on day 19 with a 77% decolorization of the dye (50 mg/L). During MFC operations, AO7 in the anolyte diffused across a layer of polyvinyl alcohol-hydrogel that separated the cathode membrane from the anode chamber, and served as a carbon source to support the growth of, and production of laccase by, the fungal mycelium that was planted on the cathode. In such MFCs, laccase-producing fungal cathodes outperformed laccase-free controls, yielding a maximum open-circuit voltage of 821 mV, a closed-circuit voltage of 394 mV with an external resistance of 1000 Ω, a maximum power density of 13.38 mW/m"2, a maximum current density of 33 mA/m"2, and a >90% decolorization of AO7. This study demonstrates the feasibility of growing a white-rot fungal culture with continuous

A high-voltage triggered pseudospark discharge experiment

International Nuclear Information System (INIS)

Ramaswamy, K.; Destler, W.W.; Rodgers, J.

1996-01-01

The design and execution of a pulsed high-voltage (350 endash 400 keV) triggered pseudospark discharge experiment is reported. Experimental studies were carried out to obtain an optimal design for stable and reliable pseudospark operation in a high-voltage regime (approx-gt 350 kV). Experiments were performed to determine the most suitable fill gas for electron-beam formation. The pseudospark discharge is initiated by a trigger mechanism involving a flashover between the trigger electrode and hollow cathode housing. Experimental results characterizing the electron-beam energy using the range-energy method are reported. Source size imaging was carried out using an x-ray pinhole camera and a novel technique using Mylar as a witness plate. It was experimentally determined that strong pinching occurred later in time and was associated with the lower-energy electrons. copyright 1996 American Institute of Physics

A heavy ion pre-injector for the ICT-ion implanter

International Nuclear Information System (INIS)

Bhattacharya, P.K.; Gaonkar, S.; Wagh, A.G.; Hattangadi, V.A.; Sarma, N.

1976-01-01

A cheap and versatile hollow cathode electron bombardment ion source system including its ion extraction-cum-focussing assembly for obtaining intense heavy ion beams of solids and gases is described. The extractor region is designed to include more than 15deg total beam angle of extracted beam for producing focused ion current densities upto 60mA/cm 2 to serve as a pre-injector for the ICT(insulated core transformer) type ion implanter. The extraction-cum-focussing lens is a low aberration strong Einzel lens system of all araldite and metal construction with optical elements of proper quality and location to suit low voltage injection and subsequent ion analysis. The injection can be selected anywhere between 2 to 10 keV for singly charged ions with typical extraction currents of 500/μ, using a ring anode and a source aperture of 20 mil. Einzel lens focussing assembly allows continuous adjustment of the beam convergence to about 5deg and the beam size to approximately 5mm in diameter with about 10 KV central electrode potential. Test results of source characteristics for both the accelerating and decelerating model of beam formation have been made. (author)

APPLIED OF IMPRESSED CURRENT CATHODIC PROTECTION DESIGN FOR FUEL PIPELINE NETWORK AT NAVAL BASE

Directory of Open Access Journals (Sweden)

k. Susilo

2017-06-01

Full Text Available Indonesian Navy (TNI AL is the main component for Maritime Security and Defence. Because of that, TNI AL needs Indonesian Warship (KRI to covered Maritime area. The main requirement from KRI is fulfilled by demand. To pock of fuel demand from KRI at Naval Base, it needs a new pipeline of fuel distribution network system. The pipeline network system used for maximum lifetime must be protected from corrosion. Basically, there are five methods of corrosion control such as change to a more suitable material, modification to the environment, use of protective coating, design modification to the system or component, and the application of cathodic or anodic protection. Cathodic protection for pipeline available in two kinds, namely Sacrifice Anode and Impressed Current Cathodic Protection (ICCP. This paper makes analysis from design of Impressed Current Cathodic Protection and total current requirement in the method. This paper showed both experimental from speciment test and theoritical calculation. The result showed that design of Impressed Current Cathodic Protection on fuel distribution pipeline network system requires voltage 33,759 V(DC, protection current 6,6035 A(DC by theoritical calculation and 6,544 A(DC from pipeline specimen test, with 0,25 mpy for corrosion rate. Transformer Rectifier design needs requirements 45 V with 10 A for current. This research result can be made as literature and standardization for Indonesian Navy in designing the Impressed Current Cathodic Protection for fuel distribution pipeline network system.

High voltage high brightness electron accelerators with MITL voltage adder coupled to foilless diodes

International Nuclear Information System (INIS)

Mazarakis, M.G.; Poukey, J.W.; Frost, C.A.; Shope, S.L.; Halbleib, J.A.; Turman, B.N.

1993-01-01

During the last ten years the authors have extensively studied the physics and operation of magnetically-immersed electron foilless diodes. Most of these sources were utilized as injectors to high current, high energy linear induction accelerators such as those of the RADLAC family. Recently they have experimentally and theoretically demonstrated that foilless diodes can be successfully coupled to self-magnetically insulated transmission line voltage adders to produce very small high brightness, high definition (no halo) electron beams. The RADLAC/SMILE experience opened the path to a new approach in high brightness, high energy induction accelerators. There is no beam drifting through the device. The voltage addition occurs in a center conductor, and the beam is created at the high voltage end in an applied magnetic field diode. This work was motivated by the remarkable success of the HERMES-III accelerator and the need to produce small radius, high energy, high current electron beams for air propagation studies and flash x-ray radiography. In this paper they present experimental results compared with analytical and numerical simulations in addition to design examples of devices that can produce multikiloamp electron beams of as high as 100 MV energies and radii as small as 1 mm