Degradation of the Pesticides Mecoprop and Atrazine in Unpolluted Sandy Aquifers

DEFF Research Database (Denmark)

Klint, Mikala; Arvin, Erik; Jensen, Bjørn K.

1993-01-01

The potential for biodegradation of the pesticides mecoprop ((+/-)-2-(4-chloro-2-methyl-phenoxy)propionic acid) and atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine) in an aerobic aquifer was investigated in laboratory batch experiments. The experiments were performed with groundwater...... the aquifer. Atrazine was not degraded during an incubation period of 539 d in groundwater and 174 d in suspensions of groundwater and aquifer sediment. The addition of nutrients, primary substrates (acetate and naphthalene), and a pH or temperature increase had not effect on the recalcitrance of atrazine....

Attenuation of landfill leachate by UK Triassic sandstone aquifer materials. 1. Fate of inorganic pollutants in laboratory columns

Science.gov (United States)

Thornton, Steven F.; Tellam, John H.; Lerner, David N.

2000-05-01

The attenuation of inorganic contaminants in acetogenic and methanogenic landfill leachate by calcareous and carbonate-deficient, oxide-rich Triassic sandstone aquifer materials from the English Midlands was examined in laboratory columns. Aqueous equilibrium speciation modelling, simple transport modelling and chemical mass balance approaches are used to evaluate the key processes and aquifer geochemical properties controlling contaminant fate. The results indicate that leachate-rock interactions are dominated by ion-exchange processes, acid-base and redox reactions and sorption/precipitation of metal species. Leachate NH 4 is attenuated by cation exchange with the aquifer sediments; however, NH 4 migration could be described with a simple model using retardation factors. Organic acids in the acetogenic leachate buffered the system pH at low levels during flushing of the calcareous aquifer material. In contrast, equilibrium with Al oxyhydroxide phases initially buffered pH (˜4.5) during flushing of the carbonate-deficient sandstone with methanogenic leachate. This led to the mobilisation of sorbed and oxide-bound heavy metals from the aquifer sediment which migrated as a concentrated pulse at the leachate front. Abiotic reductive dissolution of Mn oxyhydroxides on each aquifer material by leachate Fe 2+ maintains high concentrations of dissolved Mn and buffers the leachate inorganic redox system. This feature is analogous to the Mn-reducing zones found in leachate plumes and in the experiments provides a sink for the leachate Fe load and other heavy metals. The availability of reactive solid phase Mn oxyhydroxides limits the duration of redox buffering and Fe attenuation by these aquifer sediments. Aquifer pH and redox buffering capacity exert a fundamental influence on leachate inorganic contaminant fate in these systems. The implications for the assessment of aquifer vulnerability at landfills are discussed and simple measurements of aquifer properties which

Evaluating Impacts of CO2 and CH4 Gas Intrusion into an Unconsolidated Aquifer: Fate of As and Cd

Directory of Open Access Journals (Sweden)

Amanda eLawter

2015-07-01

Full Text Available The sequestration of carbon dioxide (CO2 in deep underground reservoirs has been identified as an important strategy to decrease atmospheric CO2 levels and mitigate global warming, but potential risks on overlying aquifers currently lack a complete evaluation. In addition to CO2, other gases such as methane (CH4 may be present in storage reservoirs. This paper explores for the first time the combined effect of leaking CO2 and CH4 gasses on the fate of major, minor and trace elements in an aquifer overlying a potential sequestration site. Emphasis is placed on the fate of arsenic (As and cadmium (Cd released from the sediments or present as soluble constituents in the leaking brine. Results from macroscopic batch and column experiments show that the presence of CH4 (at a concentration of 1 % in the mixture CO2/CH4 does not have a significant effect on solution pH or the concentrations of most major elements (such as Ca, Ba, and Mg. However, the concentrations of Mn, Mo, Si and Na are inconsistently affected by the presence of CH4 (i.e., in at least one sediment tested in this study. Cd is not released from the sediments and spiked Cd is mostly removed from the aqueous phase most likely via adsorption. The fate of sediment associated As [mainly sorbed arsenite or As(III in minerals] and spiked As [i.e., As5+] is complex. Possible mechanisms that control the As behavior in this system are discussed in this paper. Results are significant for CO2 sequestration risk evaluation and site selection and demonstrate the importance of evaluating reservoir brine and gas stream composition during site selection to ensure the safest site is being chosen.

Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan

Energy Technology Data Exchange (ETDEWEB)

Al Lawati, Wafa M. [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom); Higher College of Technology, Ministry of Manpower, Muscat (Oman); Jean, Jiin-Shuh [Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Kulp, Thomas R. [Department of Earth Sciences and Environmental Studies, State University of New York, Binghamton, NY (United States); Lee, Ming-Kuo [Department of Geology and Geography, Auburn University, Auburn, AL (United States); Polya, David A. [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom); Liu, Chia-Chuan [Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Dongen, Bart E. van, E-mail: Bart.vanDongen@manchester.ac.uk [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom)

2013-11-15

Highlights: ► First lipid analysis of Taiwanese aquifer sediments from groundwater As-prone region. ► Both plant-derived terrestrial and mature hydrocarbon lipid sources identified. ► Organic matter sources similar to those of other high As groundwater aquifers. ► Groundwater arsenic at depth controlled by biotic As mobilisation processes. ► Biotic As mobilisation not controlled by a specific source of analysed organic matter. -- Abstract: Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release.

Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan

International Nuclear Information System (INIS)

Al Lawati, Wafa M.; Jean, Jiin-Shuh; Kulp, Thomas R.; Lee, Ming-Kuo; Polya, David A.; Liu, Chia-Chuan; Dongen, Bart E. van

2013-01-01

Highlights: ► First lipid analysis of Taiwanese aquifer sediments from groundwater As-prone region. ► Both plant-derived terrestrial and mature hydrocarbon lipid sources identified. ► Organic matter sources similar to those of other high As groundwater aquifers. ► Groundwater arsenic at depth controlled by biotic As mobilisation processes. ► Biotic As mobilisation not controlled by a specific source of analysed organic matter. -- Abstract: Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release

Modeling of drainage and hay production over the Crau aquifer for analyzing the impact of global change on aquifer recharge

Science.gov (United States)

Olioso, Albert; Lecerf, Rémi; Baillieux, Antoine; Chanzy, André; Ruget, Françoise; Banton, Olivier; Lecharpentier, Patrice; Alkassem Alosman, Mohamed; Ruy, Stéphane; Gallego Elvira, Belen

2013-04-01

proportion of irrigation water that contributes to the recharge of aquifer was evaluated to 75 %, which represent 80% of the total recharge; - increase in temperature in the future leads to an increase in hay production (+ 10% in 2030 compared to now) - increase in potential evapotranspiration in the future leads to an increase of meadow evapotranspiration by 10% which has a significant impact on the amount of irrigation water required to sustain the level of aquifer recharge and the level of the water table - decrease in irrigated surfaces (-10% forecasted for 2030) results in a significant decrease of aquifer recharge (- 8%) that may affect water resources in the area (amount almost equivalent to water withdrawal for domestic use in the area) - reduction in available water for irrigation directly affect the aquifer recharge: e.g. 30% reduction in irrigation level result in a 35% reduction in drainage at the aquifer scale; however, the production of hay would be just slightly affected. This work was performed in the frame of Astuce et Tic project (French ministries financial support) and Sirrimed project (European FP7 financial support).

Localized sulfate-reducing zones in a coastal plain aquifer

Science.gov (United States)

Brown, C.J.; Coates, J.D.; Schoonen, M.A.A.

1999-01-01

High concentrations of dissolved iron in ground water of coastal plain or alluvial aquifers contribute to the biofouling of public supply wells for which treatment and remediation is costly. Many of these aquifers, however, contain zones in which microbial sulfate reduction and the associated precipitation of iron-sulfide minerals decreases iron mobility. The principal water-bearing aquifer (Magothy Aquifer of Cretaceous age) in Suffolk County, New York, contains localized sulfate-reducing zones in and near lignite deposits, which generally are associated with clay lenses. Microbial analyses of core samples amended with [14C]-acetate indicate that microbial sulfate reduction is the predominant terminal-electron-accepting process (TEAP) in poorly permeable, lignite-rich sediments at shallow depths and near the ground water divide. The sulfate-reducing zones are characterized by abundant lignite and iron-sulfide minerals, low concentrations of Fe(III) oxyhydroxides, and by proximity to clay lenses that contain pore water with relatively high concentrations of sulfate and dissolved organic carbon. The low permeability of these zones and, hence, the long residence time of ground water within them, permit the preservation and (or) allow the formation of iron-sulfide minerals, including pyrite and marcasite. Both sulfate-reducing bacteria (SRB) and iron-reducing bacteria (IRB) are present beneath and beyond the shallow sulfate-reducing zones. A unique Fe(III)-reducing organism, MD-612, was found in core sediments from a depth of 187 m near the southern shore of Long Island. The distribution of poorly permeable, lignite-rich, sulfate-reducing zones with decreased iron concentration is varied within the principal aquifer and accounts for the observed distribution of dissolved sulfate, iron, and iron sulfides in the aquifer. Locating such zones for the placement of production wells would be difficult, however, because these zones are of limited aerial extent.

Investigation of aquifer-system compaction in the Hueco basin, El Paso, Texas, USA

Science.gov (United States)

Heywood, Charles

1995-01-01

The Pleistocene geologic history of the Rio Grande valley in the Hueco basin included a cycle of sediment erosion and re-aggradation, resulting in unconformable stratification of sediment of contrasting compressibility and stress history. Since the 1950s large groundwater withdrawals have resulted in significant water-level declines and associated land subsidence. Knowledge of the magnitude and variation of specific storage is needed for developing predictive models of subsidence and groundwater flow simulations. Analyses of piezometric and extensometric data in the form of stress-strain diagrams from a 16 month period yield in situ measurements of aquifer-system compressibility across two discrete aquifer intervals. The linear elastic behaviour of the deeper interval indicates over-consolidation of basin deposits, probably resulting from deeper burial depth before the middle Pleistocene. By contrast, the shallow aquifer system displays an inelastic component, suggesting pre-consolidation stress not significantly greater than current effective stress levels for a sequence of late Pleistocene clay. Harmonic analyses of the piezometric response to earth tides in two water-level piezometers provide an independent estimate of specific storage of aquifer sands.

The impact of poplar tree plantations for biomass production on the aquifer water budget and base flow in a Mediterranean basin

Energy Technology Data Exchange (ETDEWEB)

Folch, Albert, E-mail: folch.hydro@gmail.com [Hydrogeology Group (UPC-CSIC), Department of Geotechnical Engineering and Geo-sciences, Universitat Politècnica de Catalunya-BarcelonaTech, Barcelona (Spain); Institut de Ciència i Tecnologia Ambientals, Universitat Autònoma de Barcelona, Bellaterra (Spain); Ferrer, Núria [Hydrogeology Group (UPC-CSIC), Department of Geotechnical Engineering and Geo-sciences, Universitat Politècnica de Catalunya-BarcelonaTech, Barcelona (Spain)

2015-08-15

Poplar plantations are used for biomass production in many countries. These plantations are often located in areas where the tree roots can reach the water table of shallow aquifers to reduce irrigation costs and increase evapotranspiration, mainly during the summer. This study aims to assess the effects of these plantations on an aquifer water budget and on the stream flow of a Mediterranean basin (Santa Coloma River, 321.3 km{sup 2} NE Spain). A numerical flow model was constructed to simulate shallow aquifers and to simulate the stream–aquifer interaction for a period of 9 years. Once the model was calibrated, different land use scenarios, such as deciduous forests, dry farming and irrigated farming, were simulated for comparison. The mass balance shows that poplar extracts an average of 2.40 hm{sup 3} from the aquifer, i.e., approximately 18% of the average recharge of the modelled area. This effect reduces the groundwater flow to the main stream and increases the infiltration from the stream to the aquifer. As a result, there is an average reduction in the main stream flow by 46% during the summer, when the lowest flow occurs and when the river is most sensitive. The results indicate that these impacts should be considered in basin management plans and in evaluating the benefits of this type of biomass production. - Highlights: • Poplar plantations can evapotranspirate aquifer groundwater in semiarid areas • A groundwater flow model is presented to quantify poplars’ impact on the water budget • 20% of the aquifer recharge is consumed by poplars • The main stream flow is reduced up to 46% during summer due to plantations uptake • Biomass production impacts must be considered for evaluating water resources planning.

Stochastic Management of Non-Point Source Contamination: Joint Impact of Aquifer Heterogeneity and Well Characteristics

Science.gov (United States)

Henri, C. V.; Harter, T.

2017-12-01

Agricultural activities are recognized as the preeminent origin of non-point source (NPS) contamination of water bodies through the leakage of nitrate, salt and agrochemicals. A large fraction of world agricultural activities and therefore NPS contamination occurs over unconsolidated alluvial deposit basins offering soil composition and topography favorable to productive farming. These basins represent also important groundwater reservoirs. The over-exploitation of aquifers coupled with groundwater pollution by agriculture-related NPS contaminant has led to a rapid deterioration of the quality of these groundwater basins. The management of groundwater contamination from NPS is challenged by the inherent complexity of aquifers systems. Contaminant transport dynamics are highly uncertain due to the heterogeneity of hydraulic parameters controlling groundwater flow. Well characteristics are also key uncertain elements affecting pollutant transport and NPS management but quantifying uncertainty in NPS management under these conditions is not well documented. Our work focuses on better understanding the joint impact of aquifer heterogeneity and pumping well characteristics (extraction rate and depth) on (1) the transport of contaminants from NPS and (2) the spatio-temporal extension of the capture zone. To do so, we generate a series of geostatistically equivalent 3D heterogeneous aquifers and simulate the flow and non-reactive solute transport from NPS to extraction wells within a stochastic framework. The propagation of the uncertainty on the hydraulic conductivity field is systematically analyzed. A sensitivity analysis of the impact of extraction well characteristics (pumping rate and screen depth) is also conducted. Results highlight the significant role that heterogeneity and well characteristics plays on management metrics. We finally show that, in case of NPS contamination, the joint impact of regional longitudinal and transverse vertical hydraulic gradients and

Climate change impact on groundwater levels in the Guarani Aquifer outcrop zone

Science.gov (United States)

Melo, D. D.; Wendland, E.

2013-12-01

The unsustainable use of groundwater in many countries might cause water availability restrictions in the future. Such issue is likely to worsen due to predicted climate changes for the incoming decades. As numerous studies suggest, aquifers recharge rates will be affected as a result of climate change. The Guarani Aquifer System (GAS) is one of the most important transboundary aquifer in the world, providing drinkable water for millions of people in four South American countries (Brazil, Argentina, Uruguay and Paraguay). Considering the GAS relevance and how its recharge rates might be altered by climatic conditions anomalies, the objective of this work is to assess possible climate changes impacts on groundwater levels in this aquifer outcrop zone. Global Climate Models' (GCM) outputs were used as inputs in a transient flux groundwater model created using the software SPA (Simulation of Process in Aquifers), enabling groundwater table fluctuation to be evaluated under distinct climatic scenarios. Six monitoring wells, located in a representative basin (Ribeirão da Onça basin) inside a GAS outcrop zone (ROB), provided water table measurements between 2004 and 2011 to calibrate the groundwater model. Using observed climatic data, a water budget method was applied to estimate recharge in different types of land uses. Statistically downscaled future climate scenarios were used as inputs for that same recharge model, which provided data for running SPA under those scenarios. The results show that most of the GCMs used here predict temperature arises over 275,15 K and major monthly rainfall mean changes to take place in the dry season. During wet seasons, those means might experience around 50% decrease. The transient model results indicate that water table variations, derived from around 70% of the climate scenarios, would vary below those measured between 2004 and 2011. Among the thirteen GCMs considered in this work, only four of them predicted more extreme

Impacts of physical and chemical aquifer heterogeneity on basin-scale solute transport: Vulnerability of deep groundwater to arsenic contamination in Bangladesh

Science.gov (United States)

Michael, Holly A.; Khan, Mahfuzur R.

2016-12-01

Aquifer heterogeneity presents a primary challenge in predicting the movement of solutes in groundwater systems. The problem is particularly difficult on very large scales, across which permeability, chemical properties, and pumping rates may vary by many orders of magnitude and data are often sparse. An example is the fluvio-deltaic aquifer system of Bangladesh, where naturally-occurring arsenic (As) exists over tens of thousands of square kilometers in shallow groundwater. Millions of people in As-affected regions rely on deep (≥150 m) groundwater as a safe source of drinking water. The sustainability of this resource has been evaluated with models using effective properties appropriate for a basin-scale contamination problem, but the extent to which preferential flow affects the timescale of downward migration of As-contaminated shallow groundwater is unknown. Here we embed detailed, heterogeneous representations of hydraulic conductivity (K), pumping rates, and sorptive properties (Kd) within a basin-scale numerical groundwater flow and solute transport model to evaluate their effects on vulnerability and deviations from simulations with homogeneous representations in two areas with different flow systems. Advective particle tracking shows that heterogeneity in K does not affect average travel times from shallow zones to 150 m depth, but the travel times of the fastest 10% of particles decreases by a factor of ∼2. Pumping distributions do not strongly affect travel times if irrigation remains shallow, but increases in the deep pumping rate substantially reduce travel times. Simulation of advective-dispersive transport with sorption shows that deep groundwater is protected from contamination over a sustainable timeframe (>1000 y) if the spatial distribution of Kd is uniform. However, if only low-K sediments sorb As, 30% of the aquifer is not protected. Results indicate that sustainable management strategies in the Bengal Basin should consider impacts of both

Options of sustainable groundwater supply from safe aquifers in areas with elevated arsenic - a case study from Bangladesh

Science.gov (United States)

Jakariya, M.; Bhattacharya, P.; Bromssen, M. V.

2008-05-01

Access to safe drinking water is a basic human right. Several millions of people, mainly in developing countries are affected by arsenic in drinking water and the global impact now makes it a top priority water quality issue. A wide gap between the number of exposed people and the pace of mitigation programmes in rural areas of developing countries is the main problem in providing safe drinking water. The main challenge is to develop a sustainable mitigation option that rural and disadvantaged people can adopt and implement themselves to overcome possible public heath hazards. During the recent years, new approaches have emerged in Bangladesh, primarily emerging out of people's own initiative. The local drillers target presumed safe aquifers on the basis of colour and texture of the sediments. A recent study by our research group revealed a distinct correlation between the colour characteristics of the sediments and the groundwater redox conditions. The coupling between the colour of sediments and the redox characteristics of groundwater may thus be used as a tool to assess the risk for As mobilization from the aquifers. The study showed that it is possible to assess the relative risk of high concentrations of As in aquifers if the colour characteristics of the sediments are known and thus, local drillers may target safe aquifers. For validating the sustainability of this mitigation option geological, hydrogeological and microbiological investigations are needed. The sustainability of the aquifers needs to be assessed by combining results from various field and laboratory investigations and by running predictive models. There is also a need to raise the awareness and thereby create a platform for motivating the local drillers to be educated in installing safe tubewells. Awareness raising and community mobilisation are two top priorities for implementing a sustainable safe water project in rural village areas. Significant preparation, attention, and focus must be

Hydrostratigraphy, soil/sediment chemistry, and water quality, Potomac-Raritan-Magothy aquifer system, Puchack Well Field Superfund site and vicinity, Pennsauken Township, Camden County, New Jersey, 1997-2001

Science.gov (United States)

Barringer, Julia L.; Walker, Richard L.; Jacobsen, Eric; Jankowski, Pamela

2010-01-01

Drinking-water supplies from the Potomac-Raritan-Magothy aquifer system at the Puchack well field in Pennsauken Township, Camden County, New Jersey, have been contaminated by hexavalent chromium-the most toxic and mobile form-at concentrations exceeding the New Jersey maximum contaminant level of 100 micrograms per liter. Also, scattered but widespread instances of volatile organic compounds (primarily trichloroethylene) at concentrations that exceed their respective maximum contaminant levels in the area's ground water have been reported. Because inorganic and organic contaminants are present in the ground water underlying the Puchack well field, no water from there has been withdrawn for public supply since 1998, when the U.S. Environmental Protection Agency (USEPA) added the area that contains the Puchack well field to the National Priorities List. As part of the USEPA's investigation of the Puchack Well Field Superfund site, the U.S. Geological Survey (USGS) conducted a study during 1997-2001 to (1) refine previous interpretations of the hydrostratigraphic framework, hydraulic gradients, and local directions of ground-water flow; (2) describe the chemistry of soils and saturated aquifer sediments; and (3) document the quality of ground water in the Potomac-Raritan-Magothy aquifer system in the area. The four major water-bearing units of the Potomac-Raritan-Magothy aquifer system-the Upper aquifer (mostly unsaturated in the study area), the Middle aquifer, the Intermediate Sand (a local but important unit), and the Lower aquifer-are separated by confining units. The confining units contain areas of cut and fill, resulting in permeable zones that permit water to pass through them. Pumping from the Puchack well field during the past 3 decades resulted in downward hydraulic gradients that moved contaminants into the Lower aquifer, in which the production wells are finished, and caused ground water to flow northeast, locally. A comparison of current (1997

Regeneration of a confined aquifer after redevelopment and decommission of artesian wells, example from Grafendorf aquifer (Styria, Austria)

Science.gov (United States)

Mehmedovski, Nudzejma; Winkler, Gerfried

2016-04-01

Water is essential for life and it is therefore necessary to protect drinking water sustainably. Compared to shallow groundwater, deeper groundwater is especially important due to its characteristic tendency to remain extensively unaffected by environmental impacts. Thus, the uncontrolled waste of this valuable resource has to be avoided. A lot of artesian wells have been established in Grafendorf bei Hartberg (Styria, Austria). Almost all wells were not state-of-the art. As a result the different aquifer horizons began to intermix. Additionally some of the artesian wells had a permanent free overflow and the water was not even used. Consequently, since 1950, where the mean discharge of 37 wells was 0,334 l/s per well, the discharge has decreased to 0,090 l/s until 2013, which means a decline of about 75 %. As a reaction to these declines a decommissioning campaign was conducted where 69 artesian wells have been closed by injecting a cement-bentonite suspension (ratio 3:1). The Grafendorf aquifer is situated in the Styrian Basin and consists of 5 separated artesian horizons in Neogene sediments. These artesian horizons range from 42 m (1st horizon) to 176 m (5th horizon) and mostly consist of sand, partly of fine/medium/coarse gravel and partially with minor clay content. In order to analyse the reaction of the Grafendorf aquifer to these redevelopments, 5 monitoring wells could be used for the analysis. Some monitoring wells include different aquifer horizons and hydraulically short cut them. Thus, in this work the analysis focus on the general trend of the whole aquifer system neglecting the individual interactions between the different aquifers. In a first investigation step the hydraulic properties of the aquifer system has been determined using pumping tests which were analysed with different analytical solutions with the software AQTESOLV. Overall the pumping test solutions hardly differ in the transmissivity and hydraulic conductivity. On the contrary the

Sedimentological analysis of a contaminated groundwater aquifer

International Nuclear Information System (INIS)

Towse, D.

1991-01-01

The use of sedimentological reservoir analysis techniques adapted from standard oilfield practice can improve the efficiency and reduce the costs of the evaluation of groundwater aquifers and the design of restoration programs. An evaluation/restoration program at a site in California drilled over 200 test wells in about 750 ac. All wells were logged lithologically and with wireline. The shallow aquifer is a complex braided alluvial floodplain deposit of Late Quaternary age. Analysis demonstrates depositional and erosional responses to periodic hinterland uplifts and to changing climatic conditions. Channel, overbank, lacustrine, and minor deltaic deposits can be recognized. The aquifer architecture has been interpreted to explain the movement of fuel and halogenated hydrocarbon solvents in the sediments and water. Routine engineering geology techniques and hydrologic tests were used to evaluate contamination and to design experimental restoration processes. As demonstrated here, sedimentological techniques show promise in reducing the costs and time required for this type of study. The abundant detailed data will be used in an attempt to develop a microcomputer-based expert system for rapid preliminary analyses of similar aquifers or reservoirs

Isolating the impact of sediment toxicity in urban streams

International Nuclear Information System (INIS)

Marshall, Stephen; Pettigrove, Vincent; Carew, Melissa; Hoffmann, Ary

2010-01-01

Several factors can contribute to the ecological degradation of stream catchments following urbanization, but it is often difficult to separate their relative importance. We isolated the impact of polluted sediment on the condition of an urban stream in Melbourne, Australia, using two complementary approaches. Using a rapid bioassessment approach, indices of stream condition were calculated based on macroinvertebrate field surveys. Urban stream reaches supported impoverished macroinvertebrate communities, and contained potentially toxic concentrations of heavy metals and hydrocarbons. Using a field microcosm approach, a bioassay was carried out to assess sediment pollution effects on native macroinvertebrates. Sediment from urban sites substantially altered the microcosm macroinvertebrate community, most likely due to elevated heavy metal and hydrocarbon concentrations. Macroinvertebrate surveys combined with a bioassay approach based on field microcosms can help isolate the effect of stream pollutants in degraded ecosystems. - Field microcosms isolate the ecological impact of polluted sediment in an urban stream.

Quantifying differences in the impact of variable chemistry on equilibrium Uranium(VI) adsorption properties of aquifer sediments.

Science.gov (United States)

Stoliker, Deborah L; Kent, Douglas B; Zachara, John M

2011-10-15

Uranium adsorption-desorption on sediment samples collected from the Hanford 300-Area, Richland, WA varied extensively over a range of field-relevant chemical conditions, complicating assessment of possible differences in equilibrium adsorption properties. Adsorption equilibrium was achieved in 500-1000 h although dissolved uranium concentrations increased over thousands of hours owing to changes in aqueous chemical composition driven by sediment-water reactions. A nonelectrostatic surface complexation reaction, >SOH + UO₂²⁺ + 2CO₃²⁻ = >SOUO₂(CO₃HCO₃)²⁻, provided the best fit to experimental data for each sediment sample resulting in a range of conditional equilibrium constants (logK(c)) from 21.49 to 21.76. Potential differences in uranium adsorption properties could be assessed in plots based on the generalized mass-action expressions yielding linear trends displaced vertically by differences in logK(c) values. Using this approach, logK(c) values for seven sediment samples were not significantly different. However, a significant difference in adsorption properties between one sediment sample and the fines (< 0.063 mm) of another could be demonstrated despite the fines requiring a different reaction stoichiometry. Estimates of logK(c) uncertainty were improved by capturing all data points within experimental errors. The mass-action expression plots demonstrate that applying models outside the range of conditions used in model calibration greatly increases potential errors.

The Importance of Microbial Iron Sulfide Oxidation for Nitrate Depletion in Anoxic Danish Sediments

DEFF Research Database (Denmark)

Vaclavkova, Sarka; Jacobsen, Ole Stig; Jørgensen, Christian Juncher

2014-01-01

of organic carbon in the sediment. An apparent salinity limitation to MISON was observed in the most brackish environment. Addition of high surface area synthetically precipitated iron sulfide (FeS x ) to the aquifer sediment with the lowest natural FeS x reactivity increased both the relative fraction of NO......Nitrate (NO3 −) reduction processes are important for depleting the NO3 − load from agricultural source areas before the discharge water reaches surface waters or groundwater aquifers. In this study, we experimentally demonstrate the co-occurrence of microbial iron sulfide oxidation by NO3 − (MISON......) and other NO3 −-depleting processes in a range of contrasting sediment types: sandy groundwater aquifer, non-managed minerotrophic freshwater peat and two brackish muddy sediments. Approximately 1/3 of the net NO3 − reduction was caused by MISON in three of the four environments despite the presence...

Geochemical controls on fluoriferous groundwaters of the Pliocene and the more recent aquifers: The case of Aigion region, Greece

Science.gov (United States)

Katsanou, K.; Siavalas, G.; Lambrakis, N.

2013-12-01

High fluoride concentrations (> 8 mg/L) in the groundwater of the Plio-Pleistocene sediments are rare; however, this is the case around Aigion town, where teeth fluorosis has been detected since the 80s. Aiming to investigate the origin and the mobility mechanism of fluorine in groundwater and sediments a hydrogeological and geochemical research has been conducted. The hydrogeological research revealed that the Na-HCO3 water type of boreholes aligned along a fault and hosted in the confined aquifers display the higher fluoride content. The unconfined aquifer is mostly dominated by Na-Ca-Mg-HCO3-SO4 water, which displays much lower fluoride concentrations. The most permeable sectors of this aquifer host fresh water of Ca-HCO3 type. The geochemical research revealed significant amount of fluorine in the base of a lignite sequence hosted in the Plio-Pleistocene sediments.

The influence of hydrology on lacustrine sediment contaminant records

Science.gov (United States)

Rosen, Michael R.

2015-01-01

The way water flows to a lake, through streams, as runoff, or as groundwater, can control the distribution and mass of sediment and contaminants deposited. Whether a lake is large or small, deep or shallow, open or closed, the movement of water to a lake and the circulation patterns of water within a lake control how and where sediment and contaminants are deposited. Particle-associated contaminants may stay close to the input source of contamination or be transported by currents to bathymetric lows. A complex morphology of the lake bottom or shoreline can also affect how contaminants will be distributed. Dissolved contaminants may be widely dispersed in smaller lakes, but may be diluted in large lakes away from the source. Although dissolved contaminants may not be deposited in lake sediments, the impact of dissolved contaminants (such as nitrogen) may be reflected by the ecosystem. For instance, increased phosphorus and nitrogen may increase organic content or algal biomass, and contribute to eutrophication of the lake over time. Changes in oxidation-reduction potential at the sediment-water interface may either release some contaminants to the water column or conversely deposit other contaminants to the sediment depending on the compound’s chemical characteristics. Changes in land use generally affect the hydrology of the watershed surrounding a lake, providing more runoff if soil binding vegetation is removed or if more impervious cover (roads and buildings) is increased. Groundwater inputs may change if pumping of the aquifer connected to the lake occurs. Even if groundwater is only a small portion of the volume of water entering a lake, if contaminant concentrations in the aquifer are high compared to surface water inputs, the mass of contaminants from groundwater may be as, or more, important than surface water contributions.

Microbial Reduction of Fe(III) and SO42- and Associated Microbial Communities in the Alluvial Aquifer Groundwater and Sediments.

Science.gov (United States)

Lee, Ji-Hoon; Lee, Bong-Joo

2017-11-25

Agricultural demands continuously increased use of groundwater, causing drawdown of water table and need of artificial recharge using adjacent stream waters. River water intrusion into groundwater can alter the geochemical and microbiological characteristics in the aquifer and subsurface. In an effort to investigate the subsurface biogeochemical activities before operation of artificial recharge at the test site, established at the bank of Nakdong River, Changwon, South Korea, organic carbon transported from river water to groundwater was mimicked and the effect on the indigenous microbial communities was investigated with the microcosm incubations of the groundwater and subsurface sediments. Laboratory incubations indicated microbial reduction of Fe(III) and sulfate. Next-generation Illumina MiSeq sequences of V4 region of 16S rRNA gene provided that the shifts of microbial taxa to Fe(III)-reducing and/or sulfate-reducing microorganisms such as Geobacter, Albidiferax, Desulfocapsa, Desulfuromonas, and Desulfovibrio were in good correlation with the sequential flourishment of microbial reduction of Fe(III) and sulfate as the incubations progressed. This suggests the potential role of dissolved organic carbons migrated with the river water into groundwater in the managed aquifer recharge system on the indigenous microbial community composition and following alterations of subsurface biogeochemistry and microbial metabolic activities.

Impacts of Declining Mississippi River Sediment Load on Subaqueous Delta Front Sedimentation and Geomorphology

Science.gov (United States)

Maloney, J. M.; Bentley, S. J.; Xu, K.; Georgiou, I. Y.; Miner, M. D.

2016-02-01

The Mississippi River delta system is undergoing unprecedented changes due to the effects of climate change and anthropogenic alterations to the river and its delta. Since the 1950s, the suspended sediment load of the Mississippi River has decreased by approximately 50% due to the construction of >50,000 dams in the Mississippi basin. The impact of this decreased sediment load has been observed in subaerial environments, but the impact on sedimentation and geomorphology of the subaqueous delta front has yet to be examined. To identify historic trends in sedimentation patterns, we compiled bathymetric datasets, including historical charts, industry and academic surveys, and NOAA data, collected between 1764 and 2009. Sedimentation rates are variable across the delta front, but are highest near the mouth of Southwest Pass, which carries the largest percentage of Mississippi River flow and sediment into the Gulf of Mexico. The progradation rate of Southwest Pass (measured at the 10 m depth contour) has slowed from 67 m/yr between 1764 and 1940 to 26 m/yr between 1940 and 1979, with evidence of further deceleration from 1979-2009. Decreased rates of progradation are also observed at South Pass and Pass A Loutre, with the 10 m contour retreating at rates >20 m/yr at both passes. Advancement of the delta front also decelerated in deeper water (15-90 m) offshore from Southwest Pass. In this area, from 1940-1979, depth contours advanced seaward 30 m/yr, but rates declined from 1979-2005. Furthermore, over the same area, the sediment accumulation rate decreased by 81% for the same period. The Mississippi River delta front appears to be entering a phase of decline, which will likely be accelerated by future upstream management practices. This decline has implications for offshore ecosystems, biogeochemical cycling, pollutant dispersal, mudflow hazard, and the continued use of the delta as an economic and population center.

Retardation of volatile organic compounds in ground water in low organic carbon sediments

International Nuclear Information System (INIS)

Hoffman, F.

1995-04-01

It is postulated that adsorption onto aquifer matrix surfaces is only one of the processes that retard contaminants in ground water in unconsolidated sediments; others include hydrodynamic dispersion, abiotic/biotic degradation, matrix diffusion, partitioning to organic carbon, diffusion into and retention in dead-end pores, etc. This work aims at these processes in defining the K d of VOCs in sediments with low organic carbon content. Experiments performed include an initial column experiment for VOC (TCE and perchloroethylene(PCE)) retardation tests on geological materials, PCE and TCE data from LLNL sediments, and a preliminary multilayer sampler experiment. The VOC K d s in low organic carbon permeable aquifer materials are dependent on the VOC composition and independent of aquifer grain size, indicating that sorption was not operative and that the primary retarding factors are diffusion controlled. The program of future experiments is described

High arsenic (As concentrations in the shallow groundwaters of southern Louisiana: Evidence of microbial controls on As mobilization from sediments

Directory of Open Access Journals (Sweden)

Ningfang Yang

2016-03-01

Full Text Available Study region: The Mississippi Delta in southern Louisiana, United States. Study focus: The probable role that microbial respiration plays in As release from the shallow aquifer sediments. New hydrological insights for the region: Shallow groundwaters in southern Louisiana have been reported to contain elevated As concentrations, whereas mechanisms responsible for As release from sediments have rarely been studied in this region. Microbial respiration is generally considered the main mechanism controlling As release in reducing anoxic aquifers such as the shallow aquifers in southern Louisiana and those of the Bengal basin. This study investigates the role microbial respiration plays in As release from shallow aquifer sediments in southern Louisiana through sediment incubation experiments and porewater analysis. Arsenic concentrations were the lowest in the sterilized control experiments, slightly higher in the un-amended experiments, and the highest in the experiments amended with acetate, and especially those amended with both acetate and AQDS (9,10-anthraquinone-2,6-disulfonic acid. Although Fe and Mn generally decreased at the beginning of all the experiments, they did follow a similar trend to As after the decrease. Porewater analysis showed that As and Fe concentrations were generally positively correlated and were higher in the coarse-grained sediments than in the fine-grained sediments. Results of the investigation are consistent with microbial respiration playing a key role in As release from the shallow aquifers sediments in southern Louisiana. Keywords: Groundwater, Arsenic, Microbial respiration

Geohydrology of the stratified-drift aquifer system in the lower Sixmile Creek and Willseyville Creek trough, Tompkins County, New York

Science.gov (United States)

Miller, Todd S.; Karig, Daniel E.

2010-01-01

In 2002, the U.S. Geological Survey, in cooperation with the Tompkins County Planning Department began a series of studies of the stratified-drift aquifers in Tompkins County to provide geohydrologic data for planners to develop a strategy to manage and protect their water resources. This aquifer study in lower Sixmile Creek and Willseyville Creek trough is the second in a series of aquifer studies in Tompkins County. The study area is within the northern area of the Appalachian Plateau and extends about 9 miles from the boundary between Tompkins County and Tioga County in the south to just south of the City of Ithaca in the north. In lower Sixmile Creek and Willseyville Creek trough, confined sand and gravel aquifers comprise the major water-bearing units while less extensive unconfined units form minor aquifers. About 600 people who live in lower Sixmile Creek and Willseyville Creek trough rely on groundwater from the stratified-drift aquifer system. In addition, water is used by non-permanent residents such as staff at commercial facilities. The estimated total groundwater withdrawn for domestic use is about 45,000 gallons per day (gal/d) or 0.07 cubic foot per second (ft3/s) based on an average water use of 75 gal/d per person for self-supplied water systems in New York. Scouring of bedrock in the preglacial lower Sixmile Creek and Willseyville Creek valleys by glaciers and subglacial meltwaters truncated hillside spurs, formed U-shaped, transverse valley profiles, smoothed valley walls, and deepened the valleys by as much as 300 feet (ft), forming a continuous trough. The unconsolidated deposits in the study area consist mostly of glacial drift, both unstratified drift (till) and stratified drift (laminated lake, deltaic, and glaciofluvial sediments), as well as some post-glacial stratified sediments (lake-bottom sediments that were deposited in reservoirs, peat and muck that were deposited in wetlands, and alluvium deposited by streams). Multiple advances and

[Characteristic of ammonia nitrogen adsorption on karst underground river sediments].

Science.gov (United States)

Guo, Fang; Chen, Kun-Kun; Jiang, Guang-Hui

2011-02-01

Karst aquifers are one of the most important aquifers in Southwestern China. One of the characteristics of karst aquifers is the enhanced permeability permits high flow velocities are capable of transporting suspended and bedload sediments. Mobile sediment in karst may act as a vector for the transport of contaminates. 14 sediment samples were collected from two underground rivers in two typical karst areas in Liuzhou city, Guangxi Autonomous Region, China. According to simulated experiment methods, characteristic of adsorption of ammonia nitrogen on sediment was studied. The results of ammonia nitrogen adsorption dynamics on sediments showed that the maximum adsorption velocity was less than 2 h. The adsorption balance quantity in 5 h accounted for 71% - 98% of the maximum adsorption quantity. The maximum adsorption quantity of ammonia nitrogen was 385.5 mg/kg, which was sediment from a cave in the middle areas of Guancun underground river system. The study of isotherm adsorption indicated adsorption quantity of NH4+ increase followed by incremental balance concentration of NH4+ in the aquatic phase. Adsorption quantity of ammonia nitrogen in sediments has a relative linear relationship with adsorption balance concentrations. Adsorption-desorption balance concentrations were all low, indicating sediments from underground rivers have great adsorption potential. Under the condition of low and high concentrations of ammonia nitrogen in overlying water, Langmuir and Tempkin couldn't simulate or simulate results couldn't reach remarkable level, whilst Linear and Freundlich models could simulate well. Research on different type sediments, sampling times and depths from two underground rivers shows characteristic of ammonia nitrogen adsorption on karst underground river sediments doesn't have good correspondence with the type of sediments. One of the reasons is there is no big difference between sediments in the development of climate, geology, hydrological conditions

Human impacts on sediment in the Yangtze River: A review and new perspectives

Science.gov (United States)

Yang, H. F.; Yang, S. L.; Xu, K. H.; Milliman, J. D.; Wang, H.; Yang, Z.; Chen, Z.; Zhang, C. Y.

2018-03-01

Changes in riverine suspended and riverbed sediments have environmental, ecological and social implications. Here, we provide a holistic review of water and sediment transport and examine the human impacts on the flux, concentration and size of sediment in the Yangtze River in recent decades. We find that most of the fluvial sediment has been trapped in reservoirs, except for the finest portion. Furthermore, soil-conservation since the 1990s has reduced sediment yield. From 1956-1968 (pre-dam period) to 2013-2015 (post-dams and soil-conservation), the sediment discharge from the sub-basins decreased by 91%; in the main river, the sediment flux decreased by 99% at Xiangjiaba (upper reach), 97% at Yichang (transition between upper and middle reaches), 83% at Hankou (middle reach), and 77% at Datong (tidal limit). Because the water discharge was minimally impacted, the suspended sediment concentration decreased to the same extent as the sediment flux. Active erosion of the riverbed and coarsening of surficial sediments were observed in the middle and lower reaches. Fining of suspended sediments was identified along the river, which was counteracted by downstream erosion. Along the 700-km-long Three Gorges Reservoir, which retained 80% of the sediment from upstream, the riverbed gravel or rock was buried by mud because of sedimentation after impoundment. Along with these temporal variations, the striking spatial patterns of riverine suspended and riverbed sediments that were previously exhibited in this large basin were destroyed or reversed. Therefore, we conclude that the human impacts on sediment in the Yangtze River are strong and systematic.

Geochemical processes in a calcareous sandstone aquifer during managed aquifer recharge with desalinated seawater

Science.gov (United States)

Ganot, Yonatan; Russak, Amos; Siebner, Hagar; Bernstein, Anat; Katz, Yoram; Guttman, Jospeh; Kurtzman, Daniel

2017-04-01

In the last three years we monitor Managed Aquifer Recharge (MAR) of post-treated desalinated seawater (PTDES) in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. The PTDES are stabilized with CaCO3 during post-treatment in the desalination plant and their chemical composition differs from those of any other water recharged to the aquifer and of the natural groundwater. We use suction cups in the unsaturated zone, shallow observation wells within the pond and production wells that encircles the MAR Menashe site, to study the geochemical processes during MAR with PTDES. Ion-enrichment (remineralization) of the recharged water was observed in both unsaturated zone and shallow observation wells samples. Enrichment occurs mainly in the first few meters below the pond surface by ion-exchange processes. Mg2+ enrichment is most prominent due to its deficiency in the PTDES. It is explained by ion-exchange with Ca2+, as the PTDES (enriched with Ca2+) infiltrates through a calcareous-sandstone aquifer with various amount of adsorbed Mg2+ (3-27 meq/kg). Hence, the higher concentration of Ca+2 in the PTDES together with its higher affinity to the sediments promotes the release of Mg2+ ions to the recharged water. Water isotopes analysis of the production wells were used to estimate residence time and mixing with local groundwater. At the end of 2016, it was found that the percentage of PTDES in adjacent down-gradient production wells was around 10%, while more distant or up-gradient wells show no mixing with PTDES. The distinct isotope contrast between the recharged desalinated seawater (δ2H=+11.2±0.2‰) and the local groundwater (δ2H ranged from -22.7 to -16.7‰) is a promising tool to evaluate future mixing processes at the Menshae MAR site. Using the Menashe MAR system for remineralization could be beneficial as a primary or complementary post-treatment technique. However, the sustainability of this process is

Monitoring and modeling infiltration–recharge dynamics of managed aquifer recharge with desalinated seawater

OpenAIRE

Ganot, Y.; Ganot, Y.; Holtzman, R.; Weisbrod, N.; Nitzan, I.; Katz, Y.; Kurtzman, D.

2017-01-01

We study the relation between surface infiltration and groundwater recharge during managed aquifer recharge (MAR) with desalinated seawater in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. We monitor infiltration dynamics at multiple scales (up to the scale of the entire pond) by measuring the ponding depth, sediment water content and groundwater levels, using pressure sensors, single-ring infiltrometers, soil senso...

Characterizing a complex aquifer system using geophysics, hydrodynamics and geochemistry: A new distribution of Miocene aquifers in the Zéramdine and Mahdia-Jébéniana blocks (east-central Tunisia)

Science.gov (United States)

Lachaal, Fethi; Bédir, Mourad; Tarhouni, Jamila; Gacha, Ayadi Ben; Leduc, Christian

2011-06-01

The Zéramdine and Mahdia-Jébéniana blocks are located in the Sahel region in east-central Tunisia. Active tectonics have divided the region into numerous sub-units, as result of multiple phases of distension and compression. The Miocene fluvio-deltaic sediment sandy layers have aquiferous capacities but their hydraulic properties are still unknown, due to the lack of investigation wells. This study proposes a new description of the regional hydrogeology of Miocene deposits. Seismic-reflection and wireline logging of petroleum and water wells were used to understand the structure and the geometry of the Miocene reservoirs. The groundwater flow and its relationship to the sedimentary and tectonic context were then identified by studying piezometry and hydrochemistry. Two Miocene deep aquifer systems were identified: (1) Zéramdine-Béni Hassen to the north and (2) Jébéniana-Ksour Essef to the south. These aquifers are separated by the Mahdia graben. Other major tectonic structures, such as the Zéramdine fault corridor, the Moknine graben, and the El-Jem half-graben represent lateral boundaries for these aquifers. Other deeper sandy and clayey-sandy reservoirs were also identified in the area. Their repartition, thickness and depth vary from one block to other. Hydrodynamics of the deep aquifers seems to be controlled by geological structures. Two independent compartments were identified: in the northern block groundwater flows from West to East and from Northwest to Southeast, while in the southern block it flows from Northwest to Southeast. Geochemical facies are of two types: Na-Ca-Cl-SO 4 for the Zéramdine-Béni Hassen deep aquifer and Na-Cl for the Jébéniana-Ksour Essef deep aquifer. The hydrodynamic and geochemical results confirm the sharing of the Miocene sediments into two aquifers.

Basement and alluvial aquifers of Malawi: An overview of ...

African Journals Online (AJOL)

Elizabeth B Mapoma

2014-02-17

Feb 17, 2014 ... Rowland HAL, Gault AG, Lythgoe P, Polya DA (2008) Geochemistry of aquifer sediments and arsenic-rich groundwaters from Kandal. Province, Cambodia. Appl. Geochem. 23: 3029–3046. Sajidu SM, Masumbu FFF, Fabiano E, Ngongondo C (2007). Drinking water quality and identification of fluoritic areas ...

Assessing the impact of managed aquifer recharge on seasonal low flows in a semi-arid alluvial river

Science.gov (United States)

Ronayne, M. J.; Roudebush, J. A.; Stednick, J. D.

2016-12-01

Managed aquifer recharge (MAR) is one strategy that can be used to augment seasonal low flows in alluvial rivers. Successful implementation requires an understanding of spatio-temporal groundwater-surface water exchange. In this study we conducted numerical groundwater modeling to analyze the performance of an existing MAR system in the South Platte River Valley in northeastern Colorado (USA). The engineered system involves a spatial reallocation of water during the winter months; alluvial groundwater is extracted near the river and pumped to upgradient recharge ponds, with the intent of producing a delayed hydraulic response that increases the riparian zone water table (and therefore streamflow) during summer months. Higher flows during the summer are required to improve riverine habitat for threatened species in the Platte River. Modeling scenarios were constrained by surface (streamflow gaging) and subsurface (well data) measurements throughout the study area. We compare two scenarios to analyze the impact of MAR: a natural base case scenario and an active management scenario that includes groundwater pumping and managed recharge. Steady-periodic solutions are used to evaluate the long-term stabilized behavior of the stream-aquifer system with and without pumping/recharge. Streamflow routing is included in the model, which permits quantification of the timing and location of streamflow accretion (increased streamflow associated with MAR). An analysis framework utilizing capture concepts is developed to interpret seasonal changes in head-dependent flows to/from the aquifer, including groundwater-surface water exchange that impacts streamflow. Results demonstrate that accretion occurs during the target low-flow period but is not limited to those months, highlighting an inefficiency that is a function of the aquifer geometry and hydraulic properties. The results of this study offer guidance for other flow augmentation projects that rely on water storage in shallow

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai, southern China

Science.gov (United States)

Li, Qinghua; Zhang, Yanpeng; Chen, Wen; Yu, Shaowen

2018-03-01

Salinization in coastal aquifers is usually related to both seawater intrusion and water-rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl-, Na+, Ca2+, Mg2+ and SO4 2- ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

Monitoring and modeling infiltration-recharge dynamics of managed aquifer recharge with desalinated seawater

OpenAIRE

Ganot, Yonatan; Holtzman, Ran; Weisbrod, Noam; Nitzan, Ido; Katz, Yoram; Kurtzman, Daniel

2016-01-01

We study the relation between surface infiltration and groundwater recharge during managed aquifer recharge (MAR) with desalinated seawater in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. We monitor infiltration dynamics at multiple scales (up to the scale of the entire pond) by measuring the ponding depth, sediment water content and groundwater levels, using pressure sensors, single-ring infiltrometers, soil sensors and observation...

Geochemical Fractionations and Mobility of Arsenic, Lead and Cadmium in Sediments of the Kanto Plain, Japan.

Science.gov (United States)

Hossain, Sushmita; Oguchi, Chiaki T.; Hachinohe, Shoichi; Ishiyama, Takashi; Hamamoto, Hideki

2014-05-01

Lowland alluvial and floodplain sediment play a major role in transferring heavy metals and other elements to groundwater through sediment water interaction in changing environmental conditions. However identification of geochemical forms of toxic elements such as arsenic (As), lead (Pb) and cadmium (Cd) requires risk assessment of sediment and subsequent groundwater pollution. A four steps sequential extraction procedure was applied to characterize the geochemical fractionations of As, Pb and Cd for 44 sediment samples including one peat sample from middle basin area of the Nakagawa river in the central Kanto plain. The studied sediment profile extended from the bottom of the river to 44 m depth; sediment samples were collected at 1m intervals from a bored core. The existing sedimentary facies in vertical profile are continental, transitional and marine. There are two aquifers in vertical profile; the upper aquifer (15-20m) contains fine to medium sand whereas medium to coarse sand and gravelly sand contain in lower aquifer (37-44m). The total As and Pb contents were measured by the X-Ray Fluorescence analysis which ranged from 4 to 23 mg/kg of As and 10 to 27 mg/kg of Pb in sediment profile. The three trace elements and major heavy metals were determined by ICP/MS and ICP/AES, and major ions were measured by an ion chromatograph. The marine sediment is mainly Ca-SO4 type. The Geochemical analysis showed the order of mobility trends to be As > Pb > Cd for all the steps. The geochemical fractionations order was determined to be Fe-Mn oxide bound > carbonate bound > ion exchangeable > water soluble for As and Pb whereas the order for Cd is carbonate bound > Fe-Mn oxide bound > ion exchangeable > water soluble. The mobility tendency of Pb and Cd showed high in fine silty sediment of marine environment than for those from continental and transitional environments. In the case of As, the potential mobility is very high (>60%) in the riverbed sediments and clayey silt

Biofouling potential and material reactivity in a simulated water distribution network supplied with stormwater recycled via managed aquifer recharge.

Science.gov (United States)

Gonzalez, Dennis; Tjandraatmadja, Grace; Barry, Karen; Vanderzalm, Joanne; Kaksonen, Anna H; Dillon, Peter; Puzon, Geoff J; Sidhu, Jatinder; Wylie, Jason; Goodman, Nigel; Low, Jason

2016-11-15

The injection of stormwater into aquifers for storage and recovery during high water demand periods is a promising technology for augmenting conventional water reserves. Limited information exists regarding the potential impact of aquifer treated stormwater in distribution system infrastructure. This study describes a one year pilot distribution pipe network trial to determine the biofouling potential for cement, copper and polyvinyl chloride pipe materials exposed to stormwater stored in a limestone aquifer compared to an identical drinking water rig. Median alkalinity (123 mg/L) and colour (12 HU) in stormwater was significantly higher than in drinking water (82 mg/L and 1 HU) and pipe discolouration was more evident for stormwater samples. X-ray Diffraction and Fluorescence analyses confirmed this was driven by the presence of iron rich amorphous compounds in more thickly deposited sediments also consistent with significantly higher median levels of iron (∼0.56 mg/L) in stormwater compared to drinking water (∼0.17 mg/L). Water type did not influence biofilm development as determined by microbial density but faecal indicators were significantly higher for polyvinyl chloride and cement exposed to stormwater. Treatment to remove iron through aeration and filtration would reduce the potential for sediment accumulation. Operational and verification monitoring parameters to manage scaling, corrosion, colour, turbidity and microbial growth in recycled stormwater distribution networks are discussed. Crown Copyright © 2016. Published by Elsevier Ltd. All rights reserved.

Assessing the mechanisms controlling the mobilization of arsenic in the arsenic contaminated shallow alluvial aquifer in the blackfoot disease endemic area

International Nuclear Information System (INIS)

Liao, Vivian Hsiu-Chuan; Chu, Yu-Ju; Su, Yu-Chen; Lin, Po-Cheng; Hwang, Yaw-Huei; Liu, Chen-Wuing; Liao, Chung-Min; Chang, Fi-John; Yu, Chan-Wei

2011-01-01

Highlights: ► Sedimentary microcosm showed simultaneous microbial reduction of Fe(III) and As(V). ► Addition of acetate caused a further increase in aqueous Fe(II) but not arsenic. ► An As(V)-reducing bacterium (ARS-3) native to aquifer sediments was isolated. ► ARS-3 showed microbial reduction of As(V) to As(III) in pore water in this aquifer. - Abstract: High levels of arsenic in groundwater and drinking water represent a major health problem worldwide. Drinking arsenic-contaminated groundwater is a likely cause of blackfoot disease (BFD) in Taiwan, but mechanisms controlling the mobilization of arsenic present at elevated concentrations within aquifers remain understudied. Microcosm experiments using sediments from arsenic contaminated shallow alluvial aquifers in the blackfoot disease endemic area showed simultaneous microbial reduction of Fe(III) and As(V). Significant soluble Fe(II) (0.23 ± 0.03 mM) in pore waters and mobilization of As(III) (206.7 ± 21.2 nM) occurred during the first week. Aqueous Fe(II) and As(III) respectively reached concentrations of 0.27 ± 0.01 mM and 571.4 ± 63.3 nM after 8 weeks. We also showed that the addition of acetate caused a further increase in aqueous Fe(II) but the dissolved arsenic did not increase. We further isolated an As(V)-reducing bacterium native to aquifer sediments which showed that the direct enzymatic reduction of As(V) to the potentially more-soluble As(III) in pore water is possible in this aquifer. Our results provide evidence that microorganisms can mediate the release of sedimentary arsenic to groundwater in this region and the capacity for arsenic release was not limited by the availability of electron donors in the sediments.

Assessing the mechanisms controlling the mobilization of arsenic in the arsenic contaminated shallow alluvial aquifer in the blackfoot disease endemic area

Energy Technology Data Exchange (ETDEWEB)

Liao, Vivian Hsiu-Chuan, E-mail: vivianliao@ntu.edu.tw [Department of Bioenvironmental Systems Engineering, National Taiwan University, 1 Roosevelt Road, Sec. 4, Taipei 106, Taiwan (China); Chu, Yu-Ju; Su, Yu-Chen; Lin, Po-Cheng [Department of Bioenvironmental Systems Engineering, National Taiwan University, 1 Roosevelt Road, Sec. 4, Taipei 106, Taiwan (China); Hwang, Yaw-Huei [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, 17 Xu-Zhou Road, Taipei 100, Taiwan (China); Liu, Chen-Wuing; Liao, Chung-Min; Chang, Fi-John; Yu, Chan-Wei [Department of Bioenvironmental Systems Engineering, National Taiwan University, 1 Roosevelt Road, Sec. 4, Taipei 106, Taiwan (China)

2011-12-15

Highlights: Black-Right-Pointing-Pointer Sedimentary microcosm showed simultaneous microbial reduction of Fe(III) and As(V). Black-Right-Pointing-Pointer Addition of acetate caused a further increase in aqueous Fe(II) but not arsenic. Black-Right-Pointing-Pointer An As(V)-reducing bacterium (ARS-3) native to aquifer sediments was isolated. Black-Right-Pointing-Pointer ARS-3 showed microbial reduction of As(V) to As(III) in pore water in this aquifer. - Abstract: High levels of arsenic in groundwater and drinking water represent a major health problem worldwide. Drinking arsenic-contaminated groundwater is a likely cause of blackfoot disease (BFD) in Taiwan, but mechanisms controlling the mobilization of arsenic present at elevated concentrations within aquifers remain understudied. Microcosm experiments using sediments from arsenic contaminated shallow alluvial aquifers in the blackfoot disease endemic area showed simultaneous microbial reduction of Fe(III) and As(V). Significant soluble Fe(II) (0.23 {+-} 0.03 mM) in pore waters and mobilization of As(III) (206.7 {+-} 21.2 nM) occurred during the first week. Aqueous Fe(II) and As(III) respectively reached concentrations of 0.27 {+-} 0.01 mM and 571.4 {+-} 63.3 nM after 8 weeks. We also showed that the addition of acetate caused a further increase in aqueous Fe(II) but the dissolved arsenic did not increase. We further isolated an As(V)-reducing bacterium native to aquifer sediments which showed that the direct enzymatic reduction of As(V) to the potentially more-soluble As(III) in pore water is possible in this aquifer. Our results provide evidence that microorganisms can mediate the release of sedimentary arsenic to groundwater in this region and the capacity for arsenic release was not limited by the availability of electron donors in the sediments.

Impact of leachable sulfate on the quality of groundwater in the Pocatello aquifer

International Nuclear Information System (INIS)

Meehan, C.; Welhan, J.

1994-01-01

During the summer of 1993, groundwaters and surface waters were found to have anomalous sulfate concentrations in the Southern Pocatello municipal aquifer in an area known as the Highway Ponds. Leach tests performed on a large pile of road aggregate stockpiled near the Highway Ponds have been identified as the most likely source for the sulfate. Correlating trends of sulfate and chloride concentrations can be found both in the main Pocatello aquifer and in Pocatello Creek groundwaters. The chloride contamination at Pocatello Creek has previously been suggested to be derived from road salt. It is hypothesized that aggregate used in roadbed construction may be responsible for elevated sulfate in the areas groundwater. Chemical modeling has eliminated carbonate precipitation/dissolution reactions in buffering the chemistry of sulfate-impacted groundwater. Ion-exchange with clays is hypothesized to be a more significant process and is being investigated further. 12 refs., 3 figs

Quantification of the impacts of coalmine water irrigation on the underlying aquifers

Energy Technology Data Exchange (ETDEWEB)

Vermeulen, D.; Usher, B.; van Tonder, G. [University of Free State, Bloemfontein (South Africa). Institute of Groundwater Studies

2009-07-15

It is predicted that vast volumes of affected mine water will be produced by mining activities in the Mpumalanga coalfields of South Africa, The potential environmental impact of this excess water is of great concern in a water-scarce country like South Africa. Research over a period of more than 10 years has shown that this water can be used successfully for the irrigation of a range of crops. There is, however, continuing concern from the local regulators regarding the long-term impact that large-scale mine water irrigation may have on groundwater quality and quantity. Detailed research has been undertaken over the last three years to supplement the groundwater monitoring programme at five different pilot sites, on both virgin soils (greenfields) and in coalmining spoils. These sites range from sandy soils to very clayey soils. The research has included soil moisture measurements, collection of in situ soil moisture over time, long-term laboratory studies of the leaching and attenuation properties of different soils and the impact of irrigation on acid rock drainage processes, and in depth determination of the hydraulic properties of the subsurface at each of these sites, including falling head tests, pumping tests and point dilution tests. This has been supported by geochemical modelling of these processes to quantify the impacts. The results indicate that many of the soils have considerable attenuation capacities and that in the period of irrigation, a large proportion of the salts have been contained in the upper portions of the unsaturated zones below each irrigation pivot. The volumes and quality of water leaching through to the aquifers have been quantified at each site. From this mixing ratios have been calculated in order to determine the effect of the irrigation water on the underlying aquifers.

Holocene estuarine sediments as a source of arsenic in Pleistocene groundwater in suburbs of Hanoi, Vietnam

Science.gov (United States)

Kuroda, Keisuke; Hayashi, Takeshi; Funabiki, Ayako; Do, An Thuan; Canh, Vu Duc; Nga, Tran Thi Viet; Takizawa, Satoshi

2017-06-01

Groundwater pollution by arsenic is a major health threat in suburban areas of Hanoi, Vietnam. The present study evaluates the effect of the sedimentary environments of the Pleistocene and Holocene deposits, and the recharge systems, on the groundwater arsenic pollution in Hanoi suburbs distant from the Red River. At two study sites (Linh Dam and Tai Mo communes), undisturbed soil cores identified a Pleistocene confined aquifer (PCA) and Holocene unconfined aquifer (HUA) as major aquifers, and Holocene estuarine and deltaic sediments as an aquitard layer between the two aquifers. The Holocene estuarine sediments (approximately 25-40 m depth, 9.6-4.8 cal ka BP) contained notably high concentrations of arsenic and organic matter, both likely to have been accumulated by mangroves during the Holocene sea-level highstand. The pore waters in these particular sediments exhibited elevated levels of arsenic and dissolved organic carbon. Arsenic in groundwater was higher in the PCA (25-94 μg/L) than in the HUA (5.2-42 μg/L), in both the monitoring wells and neighboring household tubewells. Elevated arsenic concentration in the PCA groundwater was likely due to vertical infiltration through the arsenic-rich and organic-matter-rich overlying Holocene estuarine sediments, caused by massive groundwater abstraction from the PCA. Countermeasures to prevent arsenic pollution of the PCA groundwater may include seeking alternative water resources, reducing water consumption, and/or appropriate choice of aquifers for groundwater supply.

Impact of global change on ground subsidence related to aquifer exploitation. The case of the Vega de Granada aquifer (SE Spain)

Science.gov (United States)

Pulido-Velazquez, David; María Mateos, Rosa; Rueda, Ramon; Pegalajar-Cuellar, Manuel; Ezquerro, Pablo; Béjar, Marta; Herrera, Gerardo; Collados-Lara, Antonio-Juan

2017-04-01

In this research, we intend to develop a methodology to assess the impact of potential global change scenarios on land subsidence. Subsidence rates in wide areas could be estimated by using remote sensing techniques, such as DInSAR and specifically the new radar information obtained by the Sentinel set of satellites from the European Space Agency (ESA). A symbolic regression method will be developed to obtain an explicit quantitative relationship between subsidence, hydraulic head changes and other physical variables (e.g. percentage of clay and silt in the ground, load of buildings and constructions, fill-in works etc.). Different ensemble and downscaling techniques will be used to define potential future global change scenarios for the test-regions based on the data coming from simulations with different Regional Circulation Models (RCMs). Future drawdowns can be estimated from these global change scenarios under different management options. The regression approach will be employed to simulate the impacts of these drawdowns, in terms of land-subsidence, taking into account the estimated hydraulic head changes. It will allow to assess sustainable management of detrital aquifers taking into account subsidence issues. Classic regression analysis attempts to postulate a hypothesis function f, and the regression is reduced to the problem of finding the optimal parameters w of the hypothesis y=f(x, w), to explain a set of dependent variables y from the values of independent variables x, where x and y are known input/output data. Symbolic regression generalizes this process by assuming that f is also unknown in advance, so that the problem is formulated as finding the optimal analytical expression and its parameters that best approximate the data y considering the data in x. To achieve that purpose, in this work Straight Line Programs (SLP) will be used to represent analytical expressions, and a genetic programming approach will be used to find an optimal SLP that

Impact of coal combustion waste on the microbiology of a model aquifer

International Nuclear Information System (INIS)

Brunning, J.S.; Caldwell, D.E.; Lawrence, J.R.; Roberts, R.D.

1994-01-01

The effects of water infiltration into an alkaline coal combustion waste burial site on the chemical and microbiological aspects of a meso-scale (2,44 m diameter x 4.6 m, height, 65 tonne) model aquifer were analyzed. The spatial and temporal effects of the alkaline leachate on microbial activity, numbers and diversity were examined in the model and compared with uncontaminated control materials. Within the saturated zone below the waste there was a pH gradient from 12.4 at the water table, immediately below the waste, to 6.0 at 3.5 meters from the waste, and elevated levels of arsenic and strontium in the pore waters. Microtox testing of the contaminated pore waters indicated high toxicity (a gamma value of 1 at dilutions of 45 to 110 fold). The leachate contamination was associated with a reduction in bacterial ( 3 H) leucine incorporation from a high of 265 fmol g -1 h -1 in sediments below the contaminant plume to undetectable in the contaminated zone. In comparison, leucine incorporation rates in control column sediments were 899 fmol g -1 h -1 . Similar toxic effects were evident in reduced total direct and culturable counts of bacteria. Observations also indicated a reduction in microbial diversity and development of alkaline-tolerant microbial communities. These results indicated that any failure of confinement technologies at disposal sites would adversely affect both the chemistry and microbiology of the underlying saturated zone. 43 refs., 7 figs., 2 tabs

Research on the neutron flux, secular equilibrium of chlorine-36 and groundwater age of the deep quaternary sediments, Hebei plain

International Nuclear Information System (INIS)

Dong Yuean; He Ming; Jiang Songsheng; Wu Shaoyong; Jiang Shan

2001-01-01

For the study of the neutron flux, secular equilibrium of chlorine-36 in the deep quaternary sediments of Hebei plain, the main chemical composition of water sand and confining bed was determined by neutron activation analysis. The mean neutron flux is 2.79 x 10 -5 cm -2 s -1 which was calculated by the chemical composition of the strata. The mean 36 Cl/Cl ratio in secular equilibrium is 1.27 x 10 -14 in the deep quaternary sediments, Hebei Plain. For the study of the groundwater age of the deep Quaternary sediments of Hebei Plain, the 36 Cl/Cl ratio of groundwater samples were determined by tandem accelerator mass spectrometry. The mixed groundwater 36 Cl/Cl ratio of the second and the third aquifer of Quaternary sediments in Baoding district is 247 x 10 -15 , that of the fourth aquifer in Baoding city is 224 x 10 -15 and the third aquifer in Cangzhou district is 40.5 x 10 -15 . The groundwater age of Baoding district was young and that of the third aquifer in Cangzhou was 229.2 ka

Arsenate reduction and mobilization in the presence of indigenous aerobic bacteria obtained from high arsenic aquifers of the Hetao basin, Inner Mongolia

International Nuclear Information System (INIS)

Guo, Huaming; Liu, Zeyun; Ding, Susu; Hao, Chunbo; Xiu, Wei; Hou, Weiguo

2015-01-01

Intact aquifer sediments were collected to obtain As-resistant bacteria from the Hetao basin. Two strains of aerobic As-resistant bacteria (Pseudomonas sp. M17-1 and Bacillus sp. M17-15) were isolated from the aquifer sediments. Those strains exhibited high resistances to both As(III) and As(V). Results showed that both strains had arr and ars genes, and led to reduction of dissolved As(V), goethite-adsorbed As(V), scorodite As(V) and sediment As(V), in the presence of organic carbon as the carbon source. After reduction of solid As(V), As release was observed from the solids to solutions. Strain M17-15 had a higher ability than strain M17-1 in reducing As(V) and promoting the release of As. These results suggested that the strains would mediate As(V) reduction to As(III), and thereafter release As(III), due to the higher mobility of As(III) in most aquifer systems. The processes would play an important role in genesis of high As groundwater. - Highlights: • Two strains of As-resistant bacteria were isolated from high As aquifer sediment. • The strains (M17–1 and M17-15) had an As tolerance under oxic conditions. • The strains had arr and ars genes, and reduced both dissolved As(V) and solid As(V). • Reduction of solid As(V) resulted in As release into solutions. • M17-15 had a higher ability in reducing As(V) and promoting As release than M17-1. - Indigenous aerobic bacteria from the high-As aquifer sediment had arr and ars genes and led to reduction of dissolved As(V), goethite-adsorbed As(V), scorodite As(V) and sedimentary As

The fate of pesticides in soil and aquifers from a small-scale point of view: Does microbial and spatial heterogeneity have an impact?

DEFF Research Database (Denmark)

Aamand, J.; Badawi, N.; Rosenbom, Annette Elisabeth

Millions of tonnes of pesticides are used each year worldwide in agricultural production resulting in pollution of groundwater aquifers. There is, however, a striking contrast between the input levels (up to several kg per hectare) and the contaminant concentrations detected in groundwater, which...... are normally in the microgram to nanogram per litre range. Resent research has revealed a large spatial variation in pesticide mineralisation potentials, but little is known about how these variations/heterogeneities affect the fate of contaminants. We analysed how mineralisation potentials of phenoxy acid...... herbicides (MCPA, 2,4-D) were spatially distributed in soil, subsoil, and groundwater aquifers using a 96-well microplate mineralisation assay. In the top soil, all samples showed rapid mineralisation following Monod mineralisation kinetics. In the subsoil sediments, a more heterogeneous distribution...

Protists from a sewage‐contaminated aquifer on cape cod, Massachusetts

Science.gov (United States)

Novarino, Gianfranco; Warren, Alan; Kinner, Nancy E.; Harvey, Ronald W.

1994-01-01

Several species of flagellates (genera Bodo, Cercomonas, Cryptaulax, Cyathomonas, Goniomonas, Spumella) have been identified in cultures from a plume of organic contamination (treated sewage effluent) within an aquifer on Cape Cod, Massachusetts. Amoebae and numerous unidentifiable 2‐ to 3‐μm flagellates have also been observed. As a rule, flagellates were associated with solid surfaces, or were capable of temporary surface attachment, corroborating earlier observations from in situ and column transport experiments suggesting that protists in the Massachusetts aquifer have a high propensity for association with sediment grain surfaces. Based on the fact that cultures from the uncontaminated part of the aquifer yielded only a few species of protists, it is hypothesized that the greater abundance and variety of food sources in the contaminant plume is capable of supporting a greater number of protistan species.

Protocols for collection of streamflow, water-quality, streambed-sediment, periphyton, macroinvertebrate, fish, and habitat data to describe stream quality for the Hydrobiological Monitoring Program, Equus Beds Aquifer Storage and Recovery Program, city of Wichita, Kansas

Science.gov (United States)

Stone, Mandy L.; Rasmussen, Teresa J.; Bennett, Trudy J.; Poulton, Barry C.; Ziegler, Andrew C.

2012-01-01

The city of Wichita, Kansas uses the Equus Beds aquifer, one of two sources, for municipal water supply. To meet future water needs, plans for artificial recharge of the aquifer have been implemented in several phases. Phase I of the Equus Beds Aquifer Storage and Recovery (ASR) Program began with injection of water from the Little Arkansas River into the aquifer for storage and subsequent recovery in 2006. Construction of a river intake structure and surface-water treatment plant began as implementation of Phase II of the Equus Beds ASR Program in 2010. An important aspect of the ASR Program is the monitoring of water quality and the effects of recharge activities on stream conditions. Physical, chemical, and biological data provide the basis for an integrated assessment of stream quality. This report describes protocols for collecting streamflow, water-quality, streambed-sediment, periphyton, macroinvertebrate, fish, and habitat data as part of the city of Wichita's hydrobiological monitoring program (HBMP). Following consistent and reliable methods for data collection and processing is imperative for the long-term success of the monitoring program.

An Analytic Equation Partitioning Climate Variation and Human Impacts on River Sediment Load

Science.gov (United States)

Zhang, J.; Gao, G.; Fu, B.

2017-12-01

Spatial or temporal patterns and process-based equations could co-exist in hydrologic model. Yet, existing approaches quantifying the impacts of those variables on river sediment load (RSL) changes are found to be severely limited, and new ways to evaluate the contribution of these variables are thus needed. Actually, the Newtonian modeling is hardly achievable for this process due to the limitation of both observations and knowledge of mechanisms, whereas laws based on the Darwinian approach could provide one component of a developed hydrologic model. Since that streamflow is the carrier of suspended sediment, sediment load changes are documented in changes of streamflow and suspended sediment concentration (SSC) - water discharge relationships. Consequently, an analytic equation for river sediment load changes are proposed to explicitly quantify the relative contributions of climate variation and direct human impacts on river sediment load changes. Initially, the sediment rating curve, which is of great significance in RSL changes analysis, was decomposed as probability distribution of streamflow and the corresponding SSC - water discharge relationships at equally spaced discharge classes. Furthermore, a proposed segmentation algorithm based on the fractal theory was used to decompose RSL changes attributed to these two portions. Additionally, the water balance framework was utilized and the corresponding elastic parameters were calculated. Finally, changes in climate variables (i.e. precipitation and potential evapotranspiration) and direct human impacts on river sediment load could be figured out. By data simulation, the efficiency of the segmentation algorithm was verified. The analytic equation provides a superior Darwinian approach partitioning climate and human impacts on RSL changes, as only data series of precipitation, potential evapotranspiration and SSC - water discharge are demanded.

Recharge and Aquifer Response: Manukan Island’s Aquifer, Sabah, Malaysia

Directory of Open Access Journals (Sweden)

Sarva Mangala Praveena

2010-01-01

Full Text Available Manukan Island is a small island located in North-West of Sabah, Malaysia was used as a case study area for numerical modeling of an aquifer response to recharge and pumping rates. The results in this study present the variations of recharge into the aquifer under the prediction simulations. The recharge rate increases the water level as indicated by hydraulic heads. This shows that it can alter groundwater of Manukan Island which has been suffering from an overexploration in its unconfined the aquifer. The increase in recharge rate (from 600 mm/year to 750 mm/year increases the water level indicated by hydraulic heads. A reduction in pumping rate (from 0.072 m3/day to 0.058 m3/day not only increases the amount of water levels in aquifer but also reduces the supply hence a deficit in supply. The increase in hydraulic heads depends on the percentage reduction of pumping and recharges rates. The well water has 1978.3 mg/L chloride with current pumping (0.072 m3/day and recharge rates (600 mm/year. However, with an increased of recharge rate and current pumping rate it has decreased about 1.13%. In addition, reduction in pumping rate made the chloride concentration decreased about 2.8%. In general, a reduction in pumping with an increase in recharge rate leads to a decreased in chloride concentrations within the vicinity of cone of depression. Next, to further develop the numerical model, the model should focus on climate change variables such as consequences of climate change are increase in air temperature, increase in sea surface temperature, and more extreme weather conditions. These parameters are considered critical parameters for climate change impact modeling in aquifers. The behavior of the aquifer and its sustainable pumping rate can be done by applying a computer modeling component.

Spatial variability of hydraulic conductivity of an unconfined sandy aquifer determined by a mini slug test

DEFF Research Database (Denmark)

Bjerg, Poul Løgstrup; Hinsby, Klaus; Christensen, Thomas Højlund

1992-01-01

The spatial variability of the hydraulic conductivity in a sandy aquifer has been determined by a mini slug test method. The hydraulic conductivity (K) of the aquifer has a geometric mean of 5.05 × 10−4 m s−1, and an overall variance of 1n K equal to 0.37 which corresponds quite well to the results...... obtained by two large scale tracer experiments performed in the aquifer. A geological model of the aquifer based on 31 sediment cores, proposed three hydrogeological layers in the aquifer concurrent with the vertical variations observed with respect to hydraulic conductivity. The horizontal correlation......, to be in the range of 0.3–0.5 m compared with a value of 0.42 m obtained in one of the tracer tests performed....

Geologic history and hydrogeologic setting of the Edwards-Trinity aquifer system, west-central Texas

Science.gov (United States)

Barker, R.A.; Bush, P.W.; Baker, E.T.

1994-01-01

The Edwards-Trinity aquifer system underlies about 42,000 square miles of west-central Texas. Nearly flat-lying, mostly Comanche (Lower Cretaceous) strata of the aquifer system thin northwestward atop massive pre-Cretaceous rocks that are comparatively impermeable and structurally complex. From predominately terrigenous clastic sediments in the east and fluvialdeltaic (terrestrial) deposits in the west, the rocks of early Trinitian age grade upward into supratidal evaporitic and dolomitic strata, intertidal limestone and dolostone, and shallow-marine, openshelf, and reefal strata of late Trinitian, Fredericksburgian, and Washitan age. A thick, downfaulted remnant of mostly open-marine strata of Eaglefordian through Navarroan age composes a small, southeastern part of the aquifer system.

Hydro-geological properties of the Savian aquifer in the county Obrenovac

Directory of Open Access Journals (Sweden)

Stojadinović Dušan D.

2005-01-01

Full Text Available The paper presents a description of hydrogeological researches of alluvial layers of the Sava River in the area of the source "Vić Bare" near Obrenovac. This source supplies groundwater to that town. The depth of these layers amounts to 25 m. With regard to collecting capacity, the most significant are gravel-sand sediments of high filtration properties. Their average depth amounts to about 13 m with the underlying layer made of Pleistocene clays. Compact aquifer is formed within these sediments and it refills partly from the Sava River at places where river cuts its channel into the gravel-sand layer. The analysis of the groundwater regime in the riparian area points out that groundwater levels follow stages of the Sava River. Such an influence lessens with the distance. Established hydraulic connection between the river and the aquifer enables its permanent replenishment. On the other hand, due to certain pollutions this river flow might bring along, it represents a potential danger. Those pollutions could enter water-bearing layer of the aquifer as well as the exploitation well of the source. Such presumptions have been confirmed in the experiment of pollution transport carried out in the water-bearing layer. Unabsorbable chloride was used as a tracer whose movement velocity through exploitation well proved that there were real possibilities of intrusion of aggressive pollutants into the water-bearing layer and into the aquifer as well. Therefore, the protection of the source must be in the function of the protection of surface waters.

Subsurface imaging reveals a confined aquifer beneath an ice-sealed Antarctic lake

DEFF Research Database (Denmark)

Dugan, H. A.; Doran, P. T.; Tulaczyk, S.

2015-01-01

Liquid water oases are rare under extreme cold desert conditions found in the Antarctic McMurdo Dry Valleys. Here we report geophysical results that indicate that Lake Vida, one of the largest lakes in the region, is nearly frozen and underlain by widespread cryoconcentrated brine. A ground...... this zone to be a confined aquifer situated in sediments with a porosity of 23-42%. Discovery of this aquifer suggests that subsurface liquid water may be more pervasive in regions of continuous permafrost than previously thought and may represent an extensive habitat for microbial populations. Key Points...... Geophysical survey finds low resistivities beneath a lake in Antarctic Dry Valleys Liquid brine abundant beneath Antarctic lake Aquifer provides microbial refugium in cold desert environment...

Managed Aquifer Recharge Using Treated Wastewater: An Option to Manage a Coastal Aquifer In Oman For Better Domestic Water Supply

Science.gov (United States)

Al-Maktoumi, Ali; Zekri, Slim; ElRawy, Mustafa

2016-04-01

Arid countries, such as the Sultanate of Oman, are facing challenges of water shortages threatening economic development and social stability. Most of those countries are vulnerable to the potential adverse impacts of climate change, the most significant of which are increased average temperatures, less and more erratic precipitation, sea level rise, and desertification. The combined effect of existing adverse conditions and likely impacts of future climate change will make water management even more difficult than what it is today. Tremendous efforts have been devoted to augment the water resources. Managed Aquifer Recharge (MAR) is practiced widely to store water during periods of surpluses and withdraw during deficits from an aquifer. In Muscat, there will be a surplus of >100,000 m3/day of TWW during winter months in the coming few years. The aquifer along the northern coast of Oman (Al-Khawd Aquifer) is conducive for MAR. Data show that TWW volumes will increase from 7.6 Mm3 in 2003 to 70.9 Mm3 in 2035 in Muscat city only. This study assesses, using MODFLOW 2005 numerical code, the impact of MAR using TWW on better management of the Al-Khawd unconfined coastal aquifer for better urban water supply. Specifically, aiming to maximize withdrawals from the domestic wells with minimize adverse effect of seawater intrusion. The model operates under a number of constrains that minimize the loss to the sea and the injected TWW must not migrates upstream (due to developed mound) and reach the wellfields used for domestic supply. The hypothetical injection wells are located downstream the domestic wellfield zone. The results of different managerial scenarios show that MAR produces a hydraulic barrier that decelerates the seawater intrusion which allows higher abstraction of pristine water from the upstream part of the aquifer. MAR along with redistribution/relocation of public wells allows abstraction of 2 times the current abstraction rate (around 6 Mm3/year to 12 Mm3

The fate of benzotriazole pollutants in an urban oxic intergranular aquifer.

Science.gov (United States)

Trček, Branka; Žigon, Dušan; Zidar, Vlasta Kramarič; Auersperger, Primož

2017-12-26

Benzotriazoles (BTs) are considered as Contaminants of Emerging Concern (CECs); however, information about their fate in aquifers continues to be absent. This was the focus of the present study, which provides the first evidence for relevant BTs' degradation products (BTTPs) in urban aquifers that may impact the groundwater quality. The mechanisms and biotransformation pathways of BTs were investigated in an oxic intergranular medium. The BTs and BTTPs were identified and quantified by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS) analytical techniques based on reference standards and internal materials. The major transformation products were identified as 2-methyl-2H-benzotriazole (2-MeBT) for the degradation of 1H-benzotriazole (BT) and as 2,4-dimethyl-2H-benzotriazole (2,4-dMeBT) and 1,4-dimethyl-1H-benzotriazole (1,4-dMeBT) for the degradation of 4-methyl-1H-benzotriazole (4-MeBT), and most probably also 5-methyl-1H-benzotriazole (5-MeBT). The leakage of wastewater pipelines is most probably the source of BTs. Sediments with a lower hydraulic conductivity give rise to perched aquifer conditions that lead to the temporal storage of leaking effluents and presumably the majority of BTs' transformation processes via methylation and tautomerization. The most stable BTTPs entered the saturated zone of the aquifer, where they prevailed. Concentrations up to 1500 ng L -1 were measured for the 2,4-dMeBT, which suggest a contamination risk for groundwater that is or may be used as a source for drinking water in the case of a constant input of pollutant loads from sewer systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

Hopane, sterane and n-alkane distributions in shallow sediments hosting high arsenic groundwaters in Cambodia

International Nuclear Information System (INIS)

Dongen, Bart E. van; Rowland, Helen A.L.; Gault, Andrew G.; Polya, David A.; Bryant, Charlotte; Pancost, Richard D.

2008-01-01

The presence of elevated As in ground waters exploited for drinking water and irrigation in South-East Asia is causing serious impacts on human health. A key mechanism that causes the mobilization of As in these waters is microbially mediated reductive transformation of As-bearing Fe(III) hydrated oxides and the role of degradable organic matter (OM) in this process is widely recognized. A number of different types of OM that drive As release in these aquifers have been suggested, including petroleum derived hydrocarbons naturally seeping into shallow sediments from deeper thermally mature source rocks. However, the amount of information on the characteristics of the OM in South-East Asian aquifers is limited. Here the organic geochemical analyses of the saturated hydrocarbon fractions and radiocarbon analysis, of two additional sites in SE Asia are reported. The results show that the OM in a given sedimentary horizon likely derives from multiple sources including naturally occurring petroleum. The importance of naturally occurring petroleum as one of the sources was clearly indicated by the n-alkane CPI of approximately 1, the presence of an unresolved complex mixture, and hopane (dominated by 17α(H),21β(H) hopanes) and sterane distribution patterns. The results also indicate that the OM in these aquifers varies tremendously in content, character and potential bioavailability. Furthermore, the presence of petroleum derived OM in sediments at both sites doubles the number of locations where their presence has been observed in association with As-rich, shallow aquifers, suggesting that the role of petroleum derived OM in microbially mediated As release might occur over a wider range of geographical locations than previously thought

Analysis of climate change impact on runoff and sediment delivery in a Great Lake watershed using SWAT

Science.gov (United States)

Verma, S.; Bhattarai, R.; Cooke, R.

2011-12-01

The green house gas loading of the atmosphere has been increasing since the mid 19th century which threatens to dramatically change the earth's climate in the 21st Century. Scientific evidences show that earth's global average surface temperature has risen some 0.75°C (1.3°F) since 1850. Third Assessment Report (TAR) from the Intergovernmental Panel on Climate Change (IPCC) concluded that human activities have increased the atmospheric concentration of greenhouse gases (GHGs), which will result in a warming world and other changes in the climate. TAR has projected an increase in globally average surface temperature of 1.4 to 5.8 °C and an increase in precipitation of 5 to 20 % over the period of 1990 to 2100. Assuming a global temperature increase of between 2.8 and 5.2 °C, it was estimated a 7-15% increase in global evaporation and precipitation rates. Global warming and subsequent climate change could raise sea level by several tens of centimeters in the next fifty years. Such a rise may erode beaches, worsen coastal flooding and threaten water quality in estuaries and aquifers. With the climate already changing and further change in climate highly likely to happen, study of impact of climate and the adaptation is a necessary component of any response to climate change. The objective of this study is to analyze the impact of climate change on runoff and sediment delivery in a Great Lake watershed located in Northern Ohio. Maumee River watershed is predominantly an agricultural watershed with an area of 6330 sq mile and drains to Lake Erie. Agricultural area covers about 89.9% of the watershed while wooded area covers 7.3%, 1.2% is urban area and other land uses account for 1.6%. Water Quality Laboratory, Heidelberg College has monitored the watershed for last 25 years. The Soil and Water Assessment Tool (SWAT) model is used for both water quantity and water quality simulations for past and future scenarios. SWAT is a continuous, long-term watershed scale

Petrographic and sedimentological characteristics of drift sediments from the radiotracer experiment array at Drigg, Cumbria

International Nuclear Information System (INIS)

Milodowski, A.E.

1990-11-01

A detailed petrographic, mineralogical and sedimentological study has been made of five drift sediment cores taken from shallow boreholes at Drigg, Cumbria, forming part of the British Geological Survey's migration test borehole array. The cores correspond to the aquifer in which tests are undertaken. The study shows that several discrete units can be recognised within the aquifer but that these may vary laterally by a considerable amount over short distances. The sands and silts comprising the aquifer zone are generally finely laminated and show an upwards coarsening of grain size. They are interpreted as proximal glacial sediments, possibly having been deposited in a lake or ponded basin. Petrographic analysis shows that most of the porosity is lined by detrital ferruginous illitic clay which coats the sand grains. Some evidence of feldspar dissolution is identified. Pyrite is also present as an important detrital component. In the upper part of the aquifer the pyrite has been largely oxidised to form secondary ferric oxide compounds. However, pyrite increases in abundance with depth and its preservation may reflect a variation in redox across the aquifer. (author)

Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system.

Science.gov (United States)

Choung, Sungwook; Zimmerman, Lisa R; Allen-King, Richelle M; Ligouis, Bertrand; Feenstra, Stanley

2014-10-15

This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc=0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen+black carbon was the dominant CM fraction extracted from the sediments and accounted for >60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that >80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM. Copyright © 2014 Elsevier B.V. All rights reserved.

Microbial reductive transformation of phyllosilicate Fe(III) and U(VI) in fluvial subsurface sediments.

Science.gov (United States)

Lee, Ji-Hoon; Fredrickson, James K; Kukkadapu, Ravi K; Boyanov, Maxim I; Kemner, Kenneth M; Lin, Xueju; Kennedy, David W; Bjornstad, Bruce N; Konopka, Allan E; Moore, Dean A; Resch, Charles T; Phillips, Jerry L

2012-04-03

The microbial reduction of Fe(III) and U(VI) was investigated in shallow aquifer sediments collected from subsurface flood deposits near the Hanford Reach of the Columbia River in Washington State. Increases in 0.5 N HCl-extractable Fe(II) were observed in incubated sediments and (57)Fe Mössbauer spectroscopy revealed that Fe(III) associated with phyllosilicates and pyroxene was reduced to Fe(II). Aqueous uranium(VI) concentrations decreased in subsurface sediments incubated in sulfate-containing synthetic groundwater with the rate and extent being greater in sediment amended with organic carbon. X-ray absorption spectroscopy of bioreduced sediments indicated that 67-77% of the U signal was U(VI), probably as an adsorbed species associated with a new or modified reactive mineral phase. Phylotypes within the Deltaproteobacteria were more common in Hanford sediments incubated with U(VI) than without, and in U(VI)-free incubations, members of the Clostridiales were dominant with sulfate-reducing phylotypes more common in the sulfate-amended sediments. These results demonstrate the potential for anaerobic reduction of phyllosilicate Fe(III) and sulfate in Hanford unconfined aquifer sediments and biotransformations involving reduction and adsorption leading to decreased aqueous U concentrations.

Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan.

Science.gov (United States)

Al Lawati, Wafa M; Jean, Jiin-Shuh; Kulp, Thomas R; Lee, Ming-Kuo; Polya, David A; Liu, Chia-Chuan; van Dongen, Bart E

2013-11-15

Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release. Copyright © 2012 Elsevier B.V. All rights reserved.

Impact of coal combustion waste on the microbiology of a model aquifer

Energy Technology Data Exchange (ETDEWEB)

Brunning, J.S.; Caldwell, D.E.; Lawrence, J.R.; Roberts, R.D. (University of Saskatchewan, Saskatoon, SK (Canada). Dept. of Applied Microbiology and Food Science)

1994-03-01

The effects of water infiltration into an alkaline coal combustion waste burial site on the chemical and microbiological aspects of a meso-scale (2,44 m diameter x 4.6 m, height, 65 tonne) model aquifer were analyzed. The spatial and temporal effects of the alkaline leachate on microbial activity, numbers and diversity were examined in the model and compared with uncontaminated control materials. Within the saturated zone below the waste there was a pH gradient from 12.4 at the water table, immediately below the waste, to 6.0 at 3.5 meters from the waste, and elevated levels of arsenic and strontium in the pore waters. Microtox testing of the contaminated pore waters indicated high toxicity (a gamma value of 1 at dilutions of 45 to 110 fold). The leachate contamination was associated with a reduction in bacterial ([sup 3]H) leucine incorporation from a high of 265 fmol g[sup -1]h[sup -1] in sediments below the contaminant plume to undetectable in the contaminated zone. In comparison, leucine incorporation rates in control column sediments were 899 fmol g[sup -1]h[sup -1]. Similar toxic effects were evident in reduced total direct and culturable counts of bacteria. Observations also indicated a reduction in microbial diversity and development of alkaline-tolerant microbial communities. These results indicated that any failure of confinement technologies at disposal sites would adversely affect both the chemistry and microbiology of the underlying saturated zone. 43 refs., 7 figs., 2 tabs.

Estimating the uncertainty of the impact of climate change on alluvial aquifers. Case study in central Italy

Science.gov (United States)

Romano, Emanuele; Camici, Stefania; Brocca, Luca; Moramarco, Tommaso; Pica, Federico; Preziosi, Elisabetta

2014-05-01

There is evidence that the precipitation pattern in Europe is trending towards more humid conditions in the northern region and drier conditions in the southern and central-eastern regions. However, a great deal of uncertainty concerns how the changes in precipitations will have an impact on water resources, particularly on groundwater, and this uncertainty should be evaluated on the basis of that coming from 1) future climate scenarios of Global Circulation Models (GCMs) and 2) modeling chains including the downscaling technique, the infiltration model and the calibration/validation procedure used to develop the groundwater flow model. With the aim of quantifying the uncertainty of these components, the Valle Umbra porous aquifer (Central Italy) has been considered as a case study. This aquifer, that is exploited for human consumption and irrigation, is mainly fed by the effective infiltration from the ground surface and partly by the inflow from the carbonate aquifers bordering the valley. A numerical groundwater flow model has been developed through the finite difference MODFLOW2005 code and it has been calibrated and validated considering the recharge regime computed through a Thornthwaite-Mather infiltration model under the climate conditions observed in the period 1956-2012. Future scenarios (2010-2070) of temperature and precipitation have been obtained from three different GMCs: ECHAM-5 (Max Planck Institute, Germany), PCM (National Centre Atmospheric Research) and CCSM3 (National Centre Atmospheric Research). Each scenario has been downscaled (DSC) to the data of temperature and precipitation collected in the baseline period 1960-1990 at the stations located in the study area through two different statistical techniques (linear rescaling and quantile mapping). Then, stochastic rainfall and temperature time series are generated through the Neyman-Scott Rectangular Pulses model (NSRP) for precipitation and the Fractionally Differenced ARIMA model (FARIMA

Assessing the Impact of Recycled Water Quality and Clogging on Infiltration Rates at A Pioneering Soil Aquifer Treatment (SAT Site in Alice Springs, Northern Territory (NT, Australia

Directory of Open Access Journals (Sweden)

Karen E. Barry

2017-03-01

Full Text Available Infiltration techniques for managed aquifer recharge (MAR, such as soil aquifer treatment (SAT can facilitate low-cost water recycling and supplement groundwater resources. However there are still challenges in sustaining adequate infiltration rates in the presence of lower permeability sediments, especially when wastewater containing suspended solids and nutrients is used to recharge the aquifer. To gain a better insight into reductions in infiltration rates during MAR, a field investigation was carried out via soil aquifer treatment (SAT using recharge basins located within a mixture of fine and coarse grained riverine deposits in Alice Springs, Northern Territory, Australia. A total of 2.6 Mm3 was delivered via five SAT basins over six years; this evaluation focused on three years of operation (2011–2014, recharging 1.5 Mm3 treated wastewater via an expanded recharge area of approximately 38,400 m2. Average infiltration rates per basin varied from 0.1 to 1 m/day due to heterogeneous soil characteristics and variability in recharge water quality. A treatment upgrade to include sand filtration and UV disinfection (in 2013 prior to recharge improved the average infiltration rate per basin by 40% to 100%.

Characteristics of Southern California coastal aquifer systems

Science.gov (United States)

Edwards, B.D.; Hanson, R.T.; Reichard, E.G.; Johnson, T.A.

2009-01-01

Most groundwater produced within coastal Southern California occurs within three main types of siliciclastic basins: (1) deep (>600 m), elongate basins of the Transverse Ranges Physiographic Province, where basin axes and related fluvial systems strike parallel to tectonic structure, (2) deep (>6000 m), broad basins of the Los Angeles and Orange County coastal plains in the northern part of the Peninsular Ranges Physiographic Province, where fluvial systems cut across tectonic structure at high angles, and (3) shallow (75-350 m), relatively narrow fluvial valleys of the generally mountainous southern part of the Peninsular Ranges Physiographic Province in San Diego County. Groundwater pumped for agricultural, industrial, municipal, and private use from coastal aquifers within these basins increased with population growth since the mid-1850s. Despite a significant influx of imported water into the region in recent times, groundwater, although reduced as a component of total consumption, still constitutes a significant component of water supply. Historically, overdraft from the aquifers has caused land surface subsidence, flow between water basins with related migration of groundwater contaminants, as well as seawater intrusion into many shallow coastal aquifers. Although these effects have impacted water quality, most basins, particularly those with deeper aquifer systems, meet or exceed state and national primary and secondary drinking water standards. Municipalities, academicians, and local water and governmental agencies have studied the stratigraphy of these basins intensely since the early 1900s with the goals of understanding and better managing the important groundwater resource. Lack of a coordinated effort, due in part to jurisdictional issues, combined with the application of lithostratigraphic correlation techniques (based primarily on well cuttings coupled with limited borehole geophysics) have produced an often confusing, and occasionally conflicting

Impact of Sediment-Bound Iron on Redox Buffering in a Landfill Leachate Polluted Aquifer (Vejen, Denmark)

DEFF Research Database (Denmark)

Heron, Gorm; Christensen, Thomas Højlund

1995-01-01

Sediments sampled along a central flow line of the leachate pollution plume at the Vejen Landfill, Denmark, were characterized in detail with respect to the forms and pools of Fe(ll) and Fe(lll). After 15 yr of leaching, redox reactions had diminished the pool of iron(ll1) oxides and hydroxides...

Microbiological and environmental effects of aquifer thermal energy storage - studies at the Stuttgart man-made aquifer and a large-scale model system

International Nuclear Information System (INIS)

Adinolfi, M.; Ruck, W.

1993-01-01

The storage of thermal energy, either heat or cold, in natural or artificial aquifers creates local perturbations of the indigenous microflora and the environmental properties. Within an international working group of the International Energy Agency (IEA Annex VI) possible environmental impacts of ATES-systems were recognized and investigated. Investigations of storage systems on natural sites, man-made aquifers and large-scale models of impounded aquifers showed changes in microbial populations, but until now no adverse microbiological processes associated with ATES-systems could be documented. However, examinations with a model system indicate an increased risk of environmental impact. Therefore, the operation of ATES-systems should be accompanied by chemical and biological investigations. (orig.) [de

Water-level altitudes 2016 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973–2015 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Science.gov (United States)

Kasmarek, Mark C.; Ramage, Jason K.; Johnson, Michaela R.

2016-10-07

Most of the land-surface subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction of the aquifer sediments, mostly in the fine-grained silt and clay layers. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured cumulative compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. The report contains regional-scale maps depicting approximate 2016 water-level altitudes (represented by measurements made during December 2015–March 2016) for the Chicot, Evangeline, and Jasper aquifers; maps depicting 1-year (2015–16) water-level changes for each aquifer; maps depicting approximate contoured 5-year (2011–16) water-level changes for each aquifer; maps depicting approximate contoured long-term (1990–2016 and 1977–2016) water-level changes for the Chicot and Evangeline aquifers; a map depicting approximate contoured long-term (2000–16) water-level changes for the Jasper aquifer; a map depicting locations of borehole-extensometer sites; and graphs depicting measured long-term cumulative compaction of subsurface sediments at the extensometers during 1973–2015. Tables listing the water-level data used to construct each water-level map for each aquifer and the measured long-term cumulative compaction data for each extensometer site are included. Graphs depicting water-level measurement data also are included; these graphs can be used to approximate

Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh

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Ahmed Kazi M

2008-01-01

Full Text Available Abstract Background The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh. Results Variations in surface geomorphology mapped by electromagnetic conductivity indicate that permeable sandy soils are associated with underlying aquifers that are moderately reducing to a depth of 10–30 m, as indicated by acid-leachable Fe(II/Fe ratios 5 mg L-1. More reducing aquifers are typically capped with finer-grained soils. The patterns suggest that vertical recharge through permeable soils is associated with a flux of oxidants on the banks of the Hooghly River and, further inland, in both Chakdaha and Araihazar. Moderately reducing conditions maintained by local recharge are generally associated with low As concentrations in Araihazar, but not systematically so in Chakdaha. Unlike Araihazar, there is also little correspondence in Chakdaha between dissolved As concentrations in groundwater and the P-extractable As content of aquifer particles, averaging 191 ± 122 ug As/L, 1.1 ± 1.5 mg As kg-1 (n = 43 and 108 ± 31 ug As/L, 3.1 ± 6.5 mg As kg-1 (n = 60, respectively. We tentatively attribute these differences to a combination of younger floodplain sediments, and therefore possibly more than one mechanism of As release, as well as less reducing conditions in Chakdaha compared to Araihazar. Conclusion Systematic dating of groundwater and sediment, combined with detailed mapping of the composition of aquifer solids and groundwater, will be needed to identify the various mechanisms underlying the complex distribution of As in aquifers of the Bengal Basin.

Assessing Sea Level Rise Impacts on the Surficial Aquifer in the Kennedy Space Center Region

Science.gov (United States)

Xiao, H.; Wang, D.; Hagen, S. C.; Medeiros, S. C.; Warnock, A. M.; Hall, C. R.

2014-12-01

Global sea level rise in the past century due to climate change has been seen at an average rate of approximately 1.7-2.2 mm per year, with an increasing rate over the next century. The increasing SLR rate poses a severe threat to the low-lying land surface and the shallow groundwater system in the Kennedy Space Center in Florida, resulting in saltwater intrusion and groundwater induced flooding. A three-dimensional groundwater flow and salinity transport model is implemented to investigate and evaluate the extent of floods due to rising water table as well as saltwater intrusion. The SEAWAT model is chosen to solve the variable-density groundwater flow and salinity transport governing equations and simulate the regional-scale spatial and temporal evolution of groundwater level and chloride concentration. The horizontal resolution of the model is 50 m, and the vertical domain includes both the Surficial Aquifer and the Floridan Aquifer. The numerical model is calibrated based on the observed hydraulic head and chloride concentration. The potential impacts of sea level rise on saltwater intrusion and groundwater induced flooding are assessed under various sea level rise scenarios. Based on the simulation results, the potential landward movement of saltwater and freshwater fringe is projected. The existing water supply wells are examined overlaid with the projected salinity distribution map. The projected Surficial Aquifer water tables are overlaid with data of high resolution land surface elevation, land use and land cover, and infrastructure to assess the potential impacts of sea level rise. This study provides useful tools for decision making on ecosystem management, water supply planning, and facility management.

Fate of nine recycled water trace organic contaminants and metal(loid)s during managed aquifer recharge into a anaerobic aquifer: Column studies.

Science.gov (United States)

Patterson, B M; Shackleton, M; Furness, A J; Pearce, J; Descourvieres, C; Linge, K L; Busetti, F; Spadek, T

2010-03-01

Water quality changes associated with the passage of aerobic reverse osmosis (RO) treated recycled water through a deep anaerobic pyritic aquifer system was evaluated in sediment-filled laboratory columns as part of a managed aquifer recharge (MAR) strategy. The fate of nine recycled water trace organic compounds along with potential negative water quality changes such as the release of metal(loid)s were investigated in large-scale columns over a period of 12 months. The anaerobic geochemical conditions provided a suitable environment for denitrification, and rapid (half-life 100 days). High retardation coefficients (R) determined for many of the trace organics (R 13 to 67) would increase aquifer residence time and be beneficial for many of the slow degrading compounds. However, for the trace organics with low R values (1.1-2.6) and slow degradation rates (half-life > 100 days), such as N-nitrosodimethylamine, N-nitrosomorpholine and iohexol, substantial biodegradation during aquifer passage may not occur and additional investigations are required. Only minor transient increases in some metal(loid) concentrations were observed, as a result of either pyrite oxidation, mineral dissolution or pH induced metal desorption, followed by metal re-sorption downgradient in the oxygen depleted zone. Crown Copyright 2009. Published by Elsevier Ltd. All rights reserved.

Ancient aqueous sedimentation on Mars

International Nuclear Information System (INIS)

Goldspiel, J.M.; Squyres, S.W.

1991-01-01

Viking orbiter images are presently used to calculate approximate volumes for the inflow valleys of the ancient cratered terrain of Mars; a sediment-transport model is then used to conservatively estimate the amount of water required for the removal of this volume of debris from the valleys. The results obtained for four basins with well-developed inflow networks indicate basin sediment thicknesses of the order of tens to hundreds of meters. The calculations further suggest that the quantity of water required to transport the sediment is greater than that which could be produced by a single discharge of the associated aquifer, unless the material of the Martian highlands was very fine-grained and noncohesive to depths of hundreds of meters. 48 refs

Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia.

Science.gov (United States)

Guo, Huaming; Zhang, Bo; Li, Yuan; Berner, Zsolt; Tang, Xiaohui; Norra, Stefan; Stüben, Doris

2011-04-01

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO₄²⁻ concentrations and δ³⁴S values indicates that bacterial reduction of SO₄²⁻ occurs in reducing aquifers. Due to high concentrations of Fe (> 0.5 mg L⁻¹), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. Copyright © 2011 Elsevier Ltd. All rights reserved.

Investigation of ground water aquifer at Karangrowo Site, Undaan District, Kudus Sub Province Central Java

International Nuclear Information System (INIS)

Lilik Subiantoro; Priyo Sularto; Slamet Sudarto

2009-01-01

Kudus is one of sub province in central Java with have the fresh water availability problem Condition of insufficiency 'Standard Water has been recognized in some part of regional area, those are Karangrowo area, Undaan District The problem of clean water in this area is caused by sea water trapped in sedimentary material during sedimentation process; due the ground water trapped character is briny or brackish. One of the alternatives to overcome water problem is election or delineated of prospect area fur exploiting of ground water. Referring to that problem ''Pusbang Geologi Nuklir BATAN'' means to conduct investigation of ground water in some location problem of clean water. The ground investigation activity is to get information about the geology, geohydrology and sub surface geophysical characterize, which is needed to identification of ground water aquifer. To obtain that target, conducted by topographic measurement in 1:5000 scale maps, measurement of soil radioactivity, geology and hydrogeology mapping, geo electrical 2-D image measurement Base on the result of analyze, evaluation and discussion was identified the existence of potential aquifer that happened at layer of sand sedimentary, in form of lens trapped in impermeable layer of clay sediment The layer of aquifer pattern follows of Old River in North-South and East-West direction. Potency of aquifer with the best condition from bad, there are placed on geophysical measurement GF. A 4-14, AB 4-11 and B4. Physical characterized of aquifer, resistivity 9-19 Ωm with charge ability 13-53 milliseconds. (author)

Karst Aquifer Recharge: A Case History of over Simplification from the Uley South Basin, South Australia

Directory of Open Access Journals (Sweden)

Nara Somaratne

2015-02-01

Full Text Available The article “Karst aquifer recharge: Comments on ‘Characteristics of Point Recharge in Karst Aquifers’, by Adrian D. Werner, 2014, Water 6, doi:10.3390/w6123727” provides misrepresentation in some parts of Somaratne [1]. The description of Uley South Quaternary Limestone (QL as unconsolidated or poorly consolidated aeolianite sediments with the presence of well-mixed groundwater in Uley South [2] appears unsubstantiated. Examination of 98 lithological descriptions with corresponding drillers’ logs show only two wells containing bands of unconsolidated sediments. In Uley South basin, about 70% of salinity profiles obtained by electrical conductivity (EC logging from monitoring wells show stratification. The central and north central areas of the basin receive leakage from the Tertiary Sand (TS aquifer thereby influencing QL groundwater characteristics, such as chemistry, age and isotope composition. The presence of conduit pathways is evident in salinity profiles taken away from TS water affected areas. Pumping tests derived aquifer parameters show strong heterogeneity, a typical characteristic of karst aquifers. Uley South QL aquifer recharge is derived from three sources; diffuse recharge, point recharge from sinkholes and continuous leakage of TS water. This limits application of recharge estimation methods, such as the conventional chloride mass balance (CMB as the basic premise of the CMB is violated. The conventional CMB is not suitable for accounting chloride mass balance in groundwater systems displaying extreme range of chloride concentrations and complex mixing [3]. Over simplification of karst aquifer systems to suit application of the conventional CMB or 1-D unsaturated modelling as described in Werner [2], is not suitable use of these recharge estimation methods.

Evidence for Microbial Iron Reduction in a Landfill Leachate-Polluted Aquifer (Vejen, Denmark)

DEFF Research Database (Denmark)

Albrechtsen, Hans-Jørgen; Christensen, Thomas Højlund

1994-01-01

Aquifer sediment samples obtained from the anaerobic part of a landfill leachate plume in Vejen, Denmark, were suspended in groundwater or in an artificial medium and incubated. The strictly anaerobic suspensions were tested for reduction of ferric iron (Fe(III)) oxides, which was measured...

Fluvial sediment inputs to upland gravel bed rivers draining forested catchments: potential ecological impacts

Directory of Open Access Journals (Sweden)

S. D. Marks

1997-01-01

Full Text Available As identified by the detailed long-term monitoring networks at Plynlimon, increased sediment supply to upland fluvial systems is often associated with forestry land-use and practice. Literature is reviewed, in the light of recent results from Plynlimon sediment studies, to enable identification of the potential ecological impacts of fluvial particulate inputs to upland gravel bed rivers draining forested catchments similar to the headwaters of the River Severn. Both sediment transport and deposition can have significant impacts upon aquatic vertebrates, invertebrates and plants.

Distribution of moisture, tritium, and plutonium in the alluvium, aquifer, and underlying tuff in Mortandad Canyon

International Nuclear Information System (INIS)

Purtymun, W.D.; Maes, M.N.; Peters, R.

1985-01-01

A study of the distribution of moisture, tritium, and plutonium in the Mortandad Canyon aquifer indicates some infiltration of water into the underlying tuff. This infiltration was accompanied by similar movement of tritium. The concentrations of plutonium on the sediments in the aquifer were low when compared with the high concentrations in solution in an ionic complex that does not readily exchange or is adsorbed by clay minerals in the alluvium. 2 references, 4 figures, 2 tables

Impact of pH on hydrogen oxidizing redox processes in aquifers due to gas intrusions

Science.gov (United States)

Metzgen, Adrian; Berta, Marton; Dethlefsen, Frank; Ebert, Markus; Dahmke, Andreas

2017-04-01

Hydrogen production from excess energy and its storage can help increasing the efficiency of solar and wind in the energy mix. Therefore, hydrogen needs large-scale intermediate storage independent of the intended later use as hydrogen gas or as reactant to produce methane in the Sabatier process. A possible storage solution is using the geological subsurface such as caverns built in salt deposits or aquifers that are not used for drinking water production. However, underground storage of hydrogen gas potentially leads to accidental gas leakages into near-surface potable aquifers triggering subsequent geochemical processes. These leakages pose potential risks that are currently not sufficiently understood. To close this gap in knowledge, a high-pressure laboratory column system was used to simulate a hydrogen gas intrusion into a shallow aquifer. Water and sediment were gained from a sandy Pleistocene aquifer near Neumünster, Germany. In the first stage of the experiment, 100% hydrogen gas was used to simulate dissolved hydrogen concentrations between 800 and 4000 µM by varying pH2 between 2 and 15 bars. pH values rose to between 7.9 and 10.4, partly due to stripping CO2 from the groundwater used during H2 gas addition. In a second stage, the pH was regulated in a range of 6.7 to 7.9 by using a gas mixture of 99% H2 and 1% CO2 at 5 bars of total gas pressure. Observed processes included hydrogen oxidation, sulfate reduction, acetogenesis, formate production, and methanogenesis, which were independent of the hydrogen concentration. Hydrogen oxidation and sulfate reduction showed zeroth order reaction rates and rate constants (106 to 412 µM/h and 12 to 33 µM/h, respectively) in the pH range between 8 and 10. At pH levels between 7 and 8, both reactions started out faster near the column's inflow but then seemed limited towards the columns outflow, suggesting the dependence of sulfate reduction on the pH-value. Acetogenesis dominated the pH range between 8 and 10

Review: Recharge rates and chemistry beneath playas of the High Plains aquifer, USA

Science.gov (United States)

Gurdak, Jason J.; Roe, Cassia D.

2010-12-01

Playas are ephemeral, closed-basin wetlands that are hypothesized as an important source of recharge to the High Plains aquifer in central USA. The ephemeral nature of playas, low regional recharge rates, and a strong reliance on groundwater from the High Plains aquifer has prompted many questions regarding the contribution and quality of recharge from playas to the High Plains aquifer. As a result, there has been considerable scientific debate about the potential for water to infiltrate the relatively impermeable playa floors, travel through the unsaturated zone sediments that are tens of meters thick, and subsequently recharge the High Plains aquifer. This critical review examines previously published studies on the processes that control recharge rates and chemistry beneath playas. Reported recharge rates beneath playas range from less than 1.0 to more than 500 mm/yr and are generally 1-2 orders of magnitude higher than recharge rates beneath interplaya settings. Most studies support the conceptual model that playas are important zones of recharge to the High Plains aquifer and are not strictly evaporative pans. The major findings of this review provide science-based implications for management of playas and groundwater resources of the High Plains aquifer and directions for future research.

Nitrate bioreduction in redox-variable low permeability sediments

Energy Technology Data Exchange (ETDEWEB)

Yan, Sen [China University of Geosciences, Wuhan 430074 (China); Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Liu, Yuanyuan [Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Liu, Chongxuan, E-mail: chongxuan.liu@pnnl.gov [China University of Geosciences, Wuhan 430074 (China); Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Shi, Liang; Shang, Jianying [Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Shan, Huimei [China University of Geosciences, Wuhan 430074 (China); Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Zachara, John; Fredrickson, Jim; Kennedy, David; Resch, Charles T.; Thompson, Christopher; Fansler, Sarah [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)

2016-01-01

Low permeability zone (LPZ) can play an important role as a sink or secondary source in contaminant transport in groundwater system. This study investigated the rate and end product of nitrate bioreduction in LPZ sediments. The sediments were from the U.S. Department of Energy's Hanford Site, where nitrate is a groundwater contaminant as a by-product of radionuclide waste discharges. The LPZ at the Hanford site consists of two layers with an oxidized layer on top and reduced layer below. The oxidized layer is directly in contact with the overlying contaminated aquifer, while the reduced layer is in contact with an uncontaminated aquifer below. The experimental results showed that nitrate bioreduction rate and end-product differed significantly in the sediments. The bioreduction rate in the oxidized sediment was significantly faster than that in the reduced one. A significant amount of N{sub 2}O was accumulated in the reduced sediment; while in the oxidized sediment, N{sub 2}O was further reduced to N{sub 2}. RT-PCR analysis revealed that nosZ, the gene that codes for N{sub 2}O reductase, was below detection limit in the reduced sediment. Batch experiments and kinetic modeling were performed to provide insights into the role of organic carbon bioavailability, biomass growth, and competition between nitrate and its reducing products for electrons from electron donors. The results revealed that it is important to consider sediment redox conditions and functional genes in understanding and modeling nitrate bioreduction in subsurface sediments. The results also implied that LPZ sediments can be important sink of nitrate and a potential secondary source of N{sub 2}O as a nitrate bioreduction product in groundwater. - Highlights: • Low permeability zones (LPZ) can microbially remove nitrate in groundwater. • The rate and end product of nitrate bioreduction vary within LPZ. • Greenhouse gas N{sub 2}O can be the end product of nitrate bioreduction in LPZ. �

Impacts of large dams on the complexity of suspended sediment dynamics in the Yangtze River

Science.gov (United States)

Wang, Yuankun; Rhoads, Bruce L.; Wang, Dong; Wu, Jichun; Zhang, Xiao

2018-03-01

The Yangtze River is one of the largest and most important rivers in the world. Over the past several decades, the natural sediment regime of the Yangtze River has been altered by the construction of dams. This paper uses multi-scale entropy analysis to ascertain the impacts of large dams on the complexity of high-frequency suspended sediment dynamics in the Yangtze River system, especially after impoundment of the Three Gorges Dam (TGD). In this study, the complexity of sediment dynamics is quantified by framing it within the context of entropy analysis of time series. Data on daily sediment loads for four stations located in the mainstem are analyzed for the past 60 years. The results indicate that dam construction has reduced the complexity of short-term (1-30 days) variation in sediment dynamics near the structures, but that complexity has actually increased farther downstream. This spatial pattern seems to reflect a filtering effect of the dams on the on the temporal pattern of sediment loads as well as decreased longitudinal connectivity of sediment transfer through the river system, resulting in downstream enhancement of the influence of local sediment inputs by tributaries on sediment dynamics. The TGD has had a substantial impact on the complexity of sediment series in the mainstem of the Yangtze River, especially after it became fully operational. This enhanced impact is attributed to the high trapping efficiency of this dam and its associated large reservoir. The sediment dynamics "signal" becomes more spatially variable after dam construction. This study demonstrates the spatial influence of dams on the high-frequency temporal complexity of sediment regimes and provides valuable information that can be used to guide environmental conservation of the Yangtze River.

Combined geophysical methods for mapping infiltration pathways at the Aurora Water Aquifer recharge and recovery site

Science.gov (United States)

Jasper, Cameron A.

Although aquifer recharge and recovery systems are a sustainable, decentralized, low cost, and low energy approach for the reclamation, treatment, and storage of post- treatment wastewater, they can suffer from poor infiltration rates and the development of a near-surface clogging layer within infiltration ponds. One such aquifer recharge and recovery system, the Aurora Water site in Colorado, U.S.A, functions at about 25% of its predicted capacity to recharge floodplain deposits by flooding infiltration ponds with post-treatment wastewater extracted from river bank aquifers along the South Platte River. The underwater self-potential method was developed to survey self-potential signals at the ground surface in a flooded infiltration pond for mapping infiltration pathways. A method for using heat as a groundwater tracer within the infiltration pond used an array of in situ high-resolution temperature sensing probes. Both relatively positive and negative underwater self-potential anomalies are consistent with observed recovery well pumping rates and specific discharge estimates from temperature data. Results from electrical resistivity tomography and electromagnetics surveys provide consistent electrical conductivity distributions associated with sediment textures. A lab method was developed for resistivity tests of near-surface sediment samples. Forward numerical modeling synthesizes the geophysical information to best match observed self- potential anomalies and provide permeability distributions, which is important for effective aquifer recharge and recovery system design, and optimization strategy development.

Groundwater arsenic content in Raigon Aquifer System (San Jose, Uruguay)

International Nuclear Information System (INIS)

Manay, N.; Piston, M.; Goso, C.; Fernnandez, T.; Rejas, M.; Garcia Valles, M.

2013-01-01

As a Medical Geology research issue, an environmental arsenic risk assessment study in the most important sedimentary aquifer in southern Uruguay is presented. The Raigon Aquifer System is the most exploited in Uruguay. It has a surface extent of about 1,800 square kilometres and 10,000 inhabitants in San Jose Department, where it was studied. Agriculture and cattle breeding are the main economic activities and this aquifer is the basic support. The groundwater sampling was done on 37 water samples of PRENADER (Natural Resources Management and Irrigation Development Program) wells. Outcropping sediments of Raigon Formation and the overlying Libertad Formation were also sampled in the Kiyu region. The analyses were performed by inductively coupled plasma-optical emission spectrometry (ICP-OES) and inductively coupled plasma-mass spectrometry (ICP-MS). The results showed 80% samples with arsenic levels exceeding the 10 μg/l of WHO as limit for waters, and 11% exceeds the 20 μg/l limit of uruguayan regulation. The median, maximum and minimum water arsenic concentrations determined have been 14.24, 24.19 and 1.44 μg/l, respectively. On the other hand, nine sediment samples of Raigon and Libertad Formations in Kiyu region were analysed and yielded median, maximum and minimum arsenic concentrations of 5.03, 9.82 and 1.18 ppm, respectively. This issue leads to the supposition that the population, as well as industrial and agricultural activities, are consuming water with arsenic concentrations over the national and international maximum recommended limit.

Hydrogeology and water quality of the Nanticoke Creek stratified-drift aquifer, near Endicott, New York

Science.gov (United States)

Kreitinger, Elizabeth A.; Kappel, William M.

2014-01-01

The Village of Endicott, New York, is seeking an alternate source of public drinking water with the potential to supplement their current supply, which requires treatment due to legacy contamination. The southerly-draining Nanticoke Creek valley, located north of the village, was identified as a potential water source and the local stratified-drift (valley fill) aquifer was investigated to determine its hydrogeologic and water-quality characteristics. Nanticoke Creek and its aquifer extend from the hamlet of Glen Aubrey, N.Y., to the village of Endicott, a distance of about 15 miles, where it joins the Susquehanna River and its aquifer. The glacial sediments that comprise the stratified-drift aquifer vary in thickness and are generally underlain by glacial till over Devonian-aged shale and siltstone. Groundwater is more plentiful in the northern part of the aquifer where sand and gravel deposits are generally more permeable than in the southern part of the aquifer where less-permeable unconsolidated deposits are found. Generally there is enough groundwater to supply most homeowner wells and in some cases, supply small public-water systems such as schools, mobile-home parks, and small commercial/industrial facilities. The aquifer is recharged by precipitation, runoff, and tributary streams. Most tributary streams flowing across alluvial deposits lose water to the aquifer as they flow off of their bedrock-lined channels and into the more permeable alluvial deposits at the edges of the valley. The quality of both surface water and groundwater is generally good. Some water wells do have water-quality issues related to natural constituents (manganese and iron) and several homeowners noted either the smell and (or) taste of hydrogen sulfide in their drinking water. Dissolved methane concentrations from five drinking-water wells were well below the potentially explosive value of 28 milligrams per liter. Samples from surface and groundwater met nearly all State and Federal

The integrated impacts of natural processes and human activities on the origin and processes of groundwater salinization in the coastal aquifers of Beihai, Southern China

Science.gov (United States)

Li, Q.; Zhan, Y., , Dr; Chen, W. Ms; Yu, S., , Dr

2017-12-01

Salinization in coastal aquifers usually is the results of contamination related to both seawater intrusion and water-rock interaction. The chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai. The concentrations of the major ions that dominate in sea water (Cl-, Na+, Ca2+, Mg2+ and SO2- 4), as well as the isotopic ratios (2H, 18O, 87Sr/86Sr and 13C) suggest that the salinization occurring in the aquifer water of the coastal plain is related to seawater and the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization occurred in parts of the area, which is significantly influenced by the land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds is identified in the confined aquifer I at site BBW2. In consequence, the leakage from this polluted aquifer causes the salinization of groundwater in the confined aquifer II. At site BBW3, the confined aquifer I and lower confined aquifer II are remarkably contaminated by seawater intrusion. The weak connectivity with upper aquifers and seaward movement of freshwater prevents saltwater from encroaching the confined aquifer III. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for sustainable planning and management of groundwater resources in this region.

Iron isotope constraints on arsenic release from Mekong Delta sediments, Cambodia

Science.gov (United States)

Matsumoto, T.; Yamaguchi, K. E.; Hirata, T.; Yamagata, Y.; Yamaguchi, A.; Abe, G.

2017-12-01

Arsenic-contaminated groundwater is a world-wide environmental problem and threatens more than 100 million people living in delta areas of South, SE and East Asia. It is typically associated with reducing aquifers with organic-rich alluvial sediments, little thermal gradients, low sulfate concentrations, and slow flushing rates. Such conditions are typical for low-lying countries in Asian deltas; however, compared to Bangladesh, Cambodia has received far less attention. Upon reductive dissolution of Fe-(oxyhydr)oxides that adsorbed As, Fe and As are released into solution as dissolved Fe2+ and arsenate, respectively. Following the oxidation of dissolved Fe2+, newly-formed Fe-(oxyhydr)oxides adsorb As again. Thus, in anoxic waters, concentrations of As correlate with those of dissolved Fe2+. Fluctuating redox conditions in the aquifer are control As release, although inhibition of adsorption of arsenate and arsenite onto the Fe-(oxyhydr)oxides occurs when the concentrations of phosphate, bicarbonate, silicate, and/or organic matter become sufficiently high. Biogeochemical redox reactions of Fe result in significant isotope fractionation (e.g., Johnson et al., 2008). We hypothesized that magnitude of isotope fractionation of Fe in the aquifer sediments, reflecting repeated (incomplete) redox reactions of Fe, may be proportional to the amount of total As release. We aim to calibrate the As release from aquifer sediment by Fe isotope analysis. As a preliminary study, series of sediment samples were collected from the Mekong Delta, Cambodia, in September 2016. Based on measurements by XRF, ICP-AES and ICP-MS, concentrations of As varied significantly covering the range from 4.5 to 15.5 µg/g with a median value of 11 µg/g (higher than the average crustal value of 5 µg/g), and those of Fe is from 2.6 to 9.7 wt.% with a median value of 7.1 wt.%. Concentrations of As and Fe show positive correlation (R2 = 0.72), indicating an effective redox cycling of Fe and As as

Aquifer Sampling Tube Completion Report: 100 Area and Hanford Townsite Shorelines

International Nuclear Information System (INIS)

Peterson, R.E.; Borghese, J.V.; Erb, D.B.

1998-02-01

Groundwater contamination is known or suspected along the Hanford Site shoreline of the Columbia River adjacent to the retired reactor areas. Along the shoreline away from the reactor areas, where contamination is presumed to be absent, monitoring sites are frequently widely spaced or unavailable to confirm the presumption. Previous characterizations of contamination near the river have relied on data from a limited number of near-river wells, contaminant plume migration predictions, and river bank seepage sampling to anticipate shoreline conditions. In recent years, new methods have been developed to obtain groundwater samples from the aquifer near the groundwater/river water interface. These methods include using (1) divers to obtain samples of pore water from riverbed sediment and (2) sampling tubes that are driven into the aquifer at the shoreline. The latter method also permits sampling the aquifer at multiple depths, which helps to determine the thickness of the potentially contaminated groundwater layer that discharges into the river

Human impact on sediment fluxes within the Blue Nile and Atbara River basins

Science.gov (United States)

Balthazar, Vincent; Vanacker, Veerle; Girma, Atkilt; Poesen, Jean; Golla, Semunesh

2013-01-01

A regional assessment of the spatial variability in sediment yields allows filling the gap between detailed, process-based understanding of erosion at field scale and empirical sediment flux models at global scale. In this paper, we focus on the intrabasin variability in sediment yield within the Blue Nile and Atbara basins as biophysical and anthropogenic factors are presumably acting together to accelerate soil erosion. The Blue Nile and Atbara River systems are characterized by an important spatial variability in sediment fluxes, with area-specific sediment yield (SSY) values ranging between 4 and 4935 t/km2/y. Statistical analyses show that 41% of the observed variation in SSY can be explained by remote sensing proxy data of surface vegetation cover, rainfall intensity, mean annual temperature, and human impact. The comparison of a locally adapted regression model with global predictive sediment flux models indicates that global flux models such as the ART and BQART models are less suited to capture the spatial variability in area-specific sediment yields (SSY), but they are very efficient to predict absolute sediment yields (SY). We developed a modified version of the BQART model that estimates the human influence on sediment yield based on a high resolution composite measure of local human impact (human footprint index) instead of countrywide estimates of GNP/capita. Our modified version of the BQART is able to explain 80% of the observed variation in SY for the Blue Nile and Atbara basins and thereby performs only slightly less than locally adapted regression models.

Sedimentation Impacts Modeling for the Lower Elwha River

Science.gov (United States)

Beggs, M.; Kosaka, M.; Sigel, A.; Vandermause, R.; Lauer, J. W.

2012-12-01

questions regarding the validity of our 1-D HEC-RAS results and motivated our second approach, which involved developing an independent 2-D hydraulic model using the U.S. Bureau of Reclamation SRH-2d program. This model had the added benefit of being able to utilize more recently surveyed bathymetric and topographic data. The 2-D model was used to improve the representation of spatial variability of likely floodplain sedimentation. For this, we used a preliminary run of the program to characterize the water surface elevation for a typical flood event. We then used the modeled water surface as an input for an eight direction pour point determination of flow direction in ArcGIS. This allowed us to approximate the flow distance from the main channel along streamlines crossing the floodplain. Using observed levee morphology, we developed an ad-hoc exponential function for overbank sedimentation as a function of flow distance from the channel. This tended to focus deposition on natural levees at the upstream side of point bars or meander necks. Despite the more narrowly focused zone of floodplain sedimentation, however, the results were consistent with the 1-D result that in-channel sedimentation is like to have a greater relative impact on system-wide hydraulics than does overbank sedimentation.

Studying the impact of climate change on coastal aquifers and adjacent wetlands

Science.gov (United States)

Stigter, Tibor; Ribeiro, Luís.; Oliveira, Rodrigo; Samper, Javier; Fakir, Younes; Fonseca, Luís.; Monteiro, José Paulo; Nunes, João. Pedro; Pisani, Bruno

2010-05-01

program, assessing the impact of climate change on coastal groundwater resources and dependent ecosystems. These resources are often intensively exploited, potentially leading to saltwater intrusion and the degradation of groundwater and dependent wetlands. Climate change may increase this problem in Mediterranean regions, due to the combined effect of rising sea levels and decreasing aquifer recharge. CLIMWAT aims to address this problem by employing a multimethodological approach involving climate scenarios, surface and groundwater flow and transport modeling, as well as hydrochemical indicator and ecological diversity indices. Research is performed in three coastal areas: the Central Algarve in Portugal, the Ebro delta in Spain and the Atlantic Sahel in Morocco. The mean annual temperatures are 17.4 ° C, 17.2 ° C and 17.5 ° C, respectively, whereas mean annual rainfall is lower in the Atlantic Sahel (390 mm) than in the Ebro Delta (520 mm) and the Central Algarve (660 mm). Work package (WP) 1 involves the collection of existing data (in a GIS environment), baseline characterization and the selection of monitoring locations. These include wells and springs of official (water level/quality) monitoring networks, as well as additional observation points selected at strategic locations, including the wetlands receiving groundwater and adjacent aquifer sectors. In WP2 the climate scenarios are selected and integrated in hydrological models (SWAT, GISBALAN), which are developed and calibrated with existing data, prior to scenario modeling. The main focus of this WP is to estimate the evolution of surface runoff and groundwater recharge under climate change. Data on climate change scenarios and model projections are compiled from: (i) the PRUDENCE project; (ii) the ENSEMBLES project; (iii) IPCC scenarios and projections, AR4; (iv) AEMet (Spanish Meteorological Agency) for generation of regional scenarios of climate change in Spain. For Morocco, where runoff is

[Impacts of Asian clams (Corbicula fluminea) on lake sediment properties and phosphorus movement].

Science.gov (United States)

Zhang, Lei; Gu, Xiao-Zhi; Shao, Shi-Guang; Hu, Hai-Yan; Zhong, Ji-Cheng; Fan, Cheng-Xin

2011-01-01

To examine the impact of Corbicula fluminea on sediment properties and phosphorus dynamics across sediment-water interface in lake, the microcosm experiment was carried out with sediment and lake water from the estuary of Dapu River, a eutrophic area in Taihu Lake. Rhizon samplers were used to acquire pore water, and soluble reactive phosphorus (SRP) flux across sediment-water interface and sediment properties were determined. The activity of C. fluminea destroyed the initial sediment structure, mixed sediment in different depths, increased oxygen penetration depth, sediment water content, and total microbial activity in sediment. The downward movement of overlying water was enhanced by the activity of C. fluminea, which decreased Fe2+ in pore water by oxidation. The production of ferric iron oxyhydroxide adsorbed SRP from pore water and decreased SRP concentration in pore water, and this increased iron bound phosphorus in corresponding sediment. The emergence of C. fluminea accelerated SRP release from sediment to overlying water, and enhanced SRP flux increased with the rise of introduced C. fluminea density. Metabolization of C. fluminea might play an important role in accelerating SRP release.

Assessing the mechanisms controlling the mobilization of arsenic in the arsenic contaminated shallow alluvial aquifer in the blackfoot disease endemic area.

Science.gov (United States)

Liao, Vivian Hsiu-Chuan; Chu, Yu-Ju; Su, Yu-Chen; Lin, Po-Cheng; Hwang, Yaw-Huei; Liu, Chen-Wuing; Liao, Chung-Min; Chang, Fi-John; Yu, Chan-Wei

2011-12-15

High levels of arsenic in groundwater and drinking water represent a major health problem worldwide. Drinking arsenic-contaminated groundwater is a likely cause of blackfoot disease (BFD) in Taiwan, but mechanisms controlling the mobilization of arsenic present at elevated concentrations within aquifers remain understudied. Microcosm experiments using sediments from arsenic contaminated shallow alluvial aquifers in the blackfoot disease endemic area showed simultaneous microbial reduction of Fe(III) and As(V). Significant soluble Fe(II) (0.23±0.03 mM) in pore waters and mobilization of As(III) (206.7±21.2 nM) occurred during the first week. Aqueous Fe(II) and As(III) respectively reached concentrations of 0.27±0.01 mM and 571.4±63.3 nM after 8 weeks. We also showed that the addition of acetate caused a further increase in aqueous Fe(II) but the dissolved arsenic did not increase. We further isolated an As(V)-reducing bacterium native to aquifer sediments which showed that the direct enzymatic reduction of As(V) to the potentially more-soluble As(III) in pore water is possible in this aquifer. Our results provide evidence that microorganisms can mediate the release of sedimentary arsenic to groundwater in this region and the capacity for arsenic release was not limited by the availability of electron donors in the sediments. Copyright © 2011 Elsevier B.V. All rights reserved.

Isotopic and hydro geochemistry study of the granular aquifer from Comarca Lagunera, Mexico

International Nuclear Information System (INIS)

Gonzalez Hita, Luis; Sanchez Diaz, Luis Felipe

1994-01-01

The Comarca Lagunera is one of Mexico's biggest agricultural regions. Its water sources are the Nazas and Aguanaval Rivers and a quaternary granular aquifer. The over exploitation of the aquifer has led to deteriorated groundwater quality due to the presence of arsenic. This study aims to determine the origin and evolution of the arsenic and to update the system's hydrogeochemical information. The methodology used is based on an analysis of the physical framework and on the hydrogeochemical and isotope characterization of the groundwater. An interpretation of the results shows that the arsenic could have originated in two geological events: first, the magmatic processes that generated the region's intrusive and extrusive igneous rocks, and second, the sedimentation of alluvial-lacustrine materials bearing arsenic, which were transported by the Nazas and Aguanaval Rivers during the aquifer's formation. (author)

Human deforestation outweighs future climate change impacts of sedimentation on coral reefs.

Science.gov (United States)

Maina, Joseph; de Moel, Hans; Zinke, Jens; Madin, Joshua; McClanahan, Tim; Vermaat, Jan E

2013-01-01

Near-shore coral reef systems are experiencing increased sediment supply due to conversion of forests to other land uses. Counteracting increased sediment loads requires an understanding of the relationship between forest cover and sediment supply, and how this relationship might change in the future. Here we study this relationship by simulating river flow and sediment supply in four watersheds that are adjacent to Madagascar's major coral reef ecosystems for a range of future climate change projections and land-use change scenarios. We show that by 2090, all four watersheds are predicted to experience temperature increases and/or precipitation declines that, when combined, result in decreases in river flow and sediment load. However, these climate change-driven declines are outweighed by the impact of deforestation. Consequently, our analyses suggest that regional land-use management is more important than mediating climate change for influencing sedimentation of Malagasy coral reefs.

Anoxic nitrate reduction coupled with iron oxidation and attenuation of dissolved arsenic and phosphate in a sand and gravel aquifer

Science.gov (United States)

Smith, Richard L.; Kent, Douglas B.; Repert, Deborah A.; Böhlke, J.K.

2017-01-01

weeks. Additionally, Fe(II)-oxidizing, nitrate-reducing microbial enrichment cultures were obtained from aquifer sediments. Growth experiments with the cultures sequentially produced nitrite and nitrous oxide from nitrate while simultaneously oxidizing Fe(II). Field and culture results suggest that nitrogen oxide reduction and Fe(II) oxidation in the aquifer are a complex interaction of coupled biotic and abiotic reactions. Overall, the results of this study demonstrate that anoxic nitrate-dependent iron oxidation can occur in groundwater; that it could control iron speciation; and that the process can impact the mobility of other chemical species (e.g., phosphate and arsenic) not directly involved in the oxidation–reduction reaction.

Origin and availability of organic matter leading to arsenic mobilisation in aquifers of the Red River Delta, Vietnam

International Nuclear Information System (INIS)

Eiche, Elisabeth; Berg, Michael; Hönig, Sarah-Madeleine; Neumann, Thomas; Lan, Vi Mai; Pham, Thi Kim Trang; Pham, Hung Viet

2017-01-01

Groundwater arsenic (As) concentrations in the Red River Delta (Vietnam) are often patchy and related to the microbially induced reduction of Fe oxy-hydroxides. In this study, we explored the influence of the origin, composition and availability of natural organic matter on the hydrochemical variability in the aquifers of Van Phuc. Carbon isotope signatures (δ"1"3C_o_r_g) and C/N ratios were assessed in combination with lithology, geochemistry, hydrochemistry, hydrology and the distribution of specific biomarkers. The elationship of C/N ratios and δ"1"3C_o_r_g distinguished four groups of sediment types that differ in their organic carbon sources. This includes organic carbon originating predominantly from vascular C_3 plants (C/N: 15.4–21.0, δ"1"3C_o_r_g: −28.6 to −26.7‰), C_4 plants (C/N: 10.6; δ"1"3C_o_r_g: −14.8‰), freshwater derived particulate organic carbon (C/N: ≤8; δ"1"3C_o_r_g:≤−24‰) as well as mixtures incorporating both sources. At the high As sites, we found particulate organic carbon (POC) being 1–2‰ less depleted in δ"1"3C_o_r_g than at low As sites. More importantly, however, our assessment shows that, the availability of organic matter has to be considered decisive with regard to groundwater As contamination. Fine-grained clayey sediments overlaying sands generally protect organic matter from substantial degradation and its leaching into an adjacent aquifer. However, at the sites that are high in dissolved As in Van Phuc, sediment layers rich in organic matter are hydraulically connected to the underlying aquifer. Here, soluble organic matter seeping into the aquifer can induce and/or enhance reducing conditions, thereby mobilising As from Fe oxy-hydroxides. Our study shows that both the clay content as well as the origin of organic matter are largely controlled by the depositional environment of the sediments. - Highlights: • Particulate organic carbon (POC) from C_3/C_4 plants and freshwater is a main source of

Cation exchange and CaCO 3 dissolution during artificial recharge of effluent to a calcareous sandstone aquifer

Science.gov (United States)

Goren, Orly; Gavrieli, Ittai; Burg, Avihu; Lazar, Boaz

2011-03-01

SummaryThis research describes a field study and laboratory simulations of the geochemical evolution of groundwater following a recharge of effluent into aquifers. The study was conducted in the soil aquifer treatment (SAT) system of the Shafdan sewage reclamation plant, Israel. The SAT system recharges secondary effluent into the calcareous sandstone sediments of the Israeli Coastal Aquifer as a tertiary treatment. The reclaimed effluent is recovered ca. 500 m off the recharge basin and is used for unlimited irrigation. The laboratory simulations in which effluent was pumped through experimental columns packed with pristine Shafdan sediment showed that the chemical composition of the outflowing water was controlled mainly by cation exchange and CaCO 3 dissolution. Na +, K + and Mg 2+ were adsorbed and Ca 2+ was desorbed during the initial stage of recharge. The equilibrium distribution of the adsorbed cations was: Ca 2+ ˜ 60%, Mg 2+ ˜ 20%, and Na + and K + ˜ 10% each. The Ca 2+ in the Shafdan production wells and in the experimental columns outflow (˜5 meq L -1) was always higher than the Ca 2+ in the recharged effluent (˜3.5 meq L -1), indicating continuous CaCO 3 dissolution. This study demonstrates that besides mixing, a suite of geochemical processes should be considered when assessing groundwater quality following artificial recharge of aquifers.

Geothermal characterization of the coastal aquifer near Ravenna (Italy

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M. Antonellini

2012-12-01

Full Text Available The coastal aquifer near Ravenna (Italy contains a large volume of groundwater (2,5x109 m3 whose quality has been compromised by sea-water intrusion. Today, the phreatic groundwater is mostly brackish with some lenses of freshwater floating on top of more saline water. This water, although impossible to use as drink-water or for irrigation, is still important to guarantee the health of wetland habitats and especially of the roman historical and coastal pine forests of Ravenna. With the objective of defining the flow pattern within the aquifer and the exchange between surface and ground water, we characterized the temperature distribution in the shallow subsurface by means of a dense network of piezometers. At the same time we had the opportunity to characterize the phreatic aquifer from the geothermal point of view, so that it could eventually be considered for use as a “low enthalpy” heat source. Heat pumps are able to extract heat during the winter and dissipate it during the summer. The temperature of the groundwater in the top layer of the aquifer (surficial zone is sensitive to the changes in atmospheric temperature throughout the year whereas the temperature of the deeper groundwater follows the geothermal gradient (geothermal zone. One of the scopes of the project is to discover at what depth is located the geothermal zone, so that the aquifer has a constant temperature throughout the year. A constant temperature is needed for storage of heat at low enthalpy. The thickness of the surficial zone and the temperature at the top of the geothermal zone are essentially related to land use, distance from the sea, sediment type, and amount of interaction between surface and groundwater. A knowledge of these factors allows to better exploit the geothermal potential of the aquifer when choosing the optimal placement of the heat pumps.

AMS radiocarbon dating of lacustrine sediment from an impact crater in northeastern China

Energy Technology Data Exchange (ETDEWEB)

Liu, K.X. [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Chen, M., E-mail: mchen@gig.ac.cn [Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Ding, X.F.; Fu, D.P. [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Ding, P. [State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Shen, C.D., E-mail: cdshen@gig.ac.cn [State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Xiao, W.S. [Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China)

2013-01-15

In order to investigate the origin and age of a bowl-shaped crater with 1.8 km diameter in northeastern China, a core drilling about 110 m in total was carried out in 2009 at the center of the crater. A 106-m-thick unit of lacustrine sediment is revealed under a surface layer of about 1 m of yellow soil. The impact origin has been confirmed based on geological analysis. In this paper, we report the AMS {sup 14}C dating results of lacustrine sediment. The data suggest that the meteorite impact in Xiuyan happened more than 50,000 years ago and a two-section linear relationship of {sup 14}C ages with the depth shows a stable sediment environment through the two time stages.

Both Phosphorus Fertilizers and Indigenous Bacteria Enhance Arsenic Release into Groundwater in Arsenic-Contaminated Aquifers.

Science.gov (United States)

Lin, Tzu-Yu; Wei, Chia-Cheng; Huang, Chi-Wei; Chang, Chun-Han; Hsu, Fu-Lan; Liao, Vivian Hsiu-Chuan

2016-03-23

Arsenic (As) is a human carcinogen, and arsenic contamination in groundwater is a worldwide public health concern. Arsenic-affected areas are found in many places but are reported mostly in agricultural farmlands, yet the interaction of fertilizers, microorganisms, and arsenic mobilization in arsenic-contaminated aquifers remains uncharacterized. This study investigates the effects of fertilizers and bacteria on the mobilization of arsenic in two arsenic-contaminated aquifers. We performed microcosm experiments using arsenic-contaminated sediments and amended with inorganic nitrogenous or phosphorus fertilizers for 1 and 4 months under aerobic and anaerobic conditions. The results show that microcosms amended with 100 mg/L phosphorus fertilizers (dipotassium phosphate), but not nitrogenous fertilizers (ammonium sulfate), significantly increase aqueous As(III) release in arsenic-contaminated sediments under anaerobic condition. We also show that concentrations of iron, manganese, potassium, sodium, calcium, and magnesium are increased in the aqueous phase and that the addition of dipotassium phosphate causes a further increase in aqueous iron, potassium, and sodium, suggesting that multiple metal elements may take part in the arsenic release process. Furthermore, microbial analysis indicates that the dominant microbial phylum is shifted from α-proteobacteria to β- and γ-proteobacteria when the As(III) is increased and phosphate is added in the aquifer. Our results provide evidence that both phosphorus fertilizers and microorganisms can mediate the release of arsenic to groundwater in arsenic-contaminated sediments under anaerobic condition. Our study suggests that agricultural activity such as the use of fertilizers and monitoring phosphate concentration in groundwater should be taken into consideration for the management of arsenic in groundwater.

Groundwater vulnerability mapping of Qatar aquifers

Science.gov (United States)

Baalousha, Husam Musa

2016-12-01

Qatar is one of the most arid countries in the world with limited water resources. With little rainfall and no surface water, groundwater is the only natural source of fresh water in the country. Whilst the country relies mainly on desalination of seawater to secure water supply, groundwater has extensively been used for irrigation over the last three decades, which caused adverse environmental impact. Vulnerability assessment is a widely used tool for groundwater protection and land-use management. Aquifers in Qatar are carbonate with lots of fractures, depressions and cavities. Karst aquifers are generally more vulnerable to contamination than other aquifers as any anthropogenic-sourced contaminant, especially above a highly fractured zone, can infiltrate quickly into the aquifer and spread over a wide area. The vulnerability assessment method presented in this study is based on two approaches: DRASTIC and EPIK, within the framework of Geographical Information System (GIS). Results of this study show that DRASTIC vulnerability method suits Qatar hydrogeological settings more than EPIK. The produced vulnerability map using DRASTIC shows coastal and karst areas have the highest vulnerability class. The southern part of the country is located in the low vulnerability class due to occurrence of shale formation within aquifer media, which averts downward movement of contaminants.

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam.

Science.gov (United States)

Postma, Dieke; Mai, Nguyen Thi Hoa; Lan, Vi Mai; Trang, Pham Thi Kim; Sø, Helle Ugilt; Nhan, Pham Quy; Larsen, Flemming; Viet, Pham Hung; Jakobsen, Rasmus

2017-01-17

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium-helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO 2 (P CO 2 ) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L.

Fate of Arsenic during Red River Water Infiltration into Aquifers beneath Hanoi, Vietnam

Science.gov (United States)

2016-01-01

Recharge of Red River water into arsenic-contaminated aquifers below Hanoi was investigated. The groundwater age at 40 m depth in the aquifer underlying the river was 1.3 ± 0.8 years, determined by tritium–helium dating. This corresponds to a vertical flow rate into the aquifer of 19 m/year. Electrical conductivity and partial pressure of CO2 (PCO2) indicate that water recharged from the river is present in both the sandy Holocene and gravelly Pleistocene aquifers and is also abstracted by the pumping station. Infiltrating river water becomes anoxic in the uppermost aquifer due to the oxidation of dissolved organic carbon. Further downward, sedimentary carbon oxidation causes the reduction of As-containing Fe-oxides. Because the release of arsenic by reduction of Fe-oxides is controlled by the reaction rate, arsenic entering the solution becomes highly diluted in the high water flux and contributes little to the groundwater arsenic concentration. Instead, the As concentration in the groundwater of up to 1 μM is due to equilibrium-controlled desorption of arsenic, adsorbed to the sediment before river water started to infiltrate due to municipal pumping. Calculations indicate that it will take several decades of river water infiltration to leach arsenic from the Holocene aquifer to below the World Health Organization limit of 10 μg/L. PMID:27958705

Impact of suspended sediments on the survival of seagrass: Halodule pinifolia (Miki den Hartog

Directory of Open Access Journals (Sweden)

Satumanatpan, S.

2006-07-01

Full Text Available The research aimed to study the level of suspended sediments on the survival of Halodule pinifolia (Miki den Hartog. Three experiments were conducted. Broad concentration of suspended sediments covering the level found in nature were employed in the first experiment. The impact concentration of suspended sediments on the survival of H. pinifolia was extended in more detail in the second and third experiments. H. pinifolia was planted by washing off the mud and holding it with a grating. An air pump was used to stir the sediment in suspension during the experiments and necessary water parameters were strictly control. The suspended sediment was spread by siphon and conducted in a period of 30 days for the first and second experiments, and 45 days for the third experiment. The result indicated that suspended sediments with a concentration of 1-64 mg/l had no impact on the survival of H. pinifolia within 30 days. Initially, suspended sediments of 66 mg/l lowered H. pinifolia's survival to 95% at day 30. Concentration of suspended sediments higher than 66 mg/l affected the survival of H. pinifolia. The decreasing survival was noticed during days 20 -25 of the experiment and all died during days 40-45. However, the life span of H. pinifolia, would be very important and might also affect the survival of H. pinifolia after 30 days.

Effects of Subsurface Microbial Ecology on Geochemical Evolution of a Crude-Oil Contaminated Aquifer

Science.gov (United States)

Bekins, B. A.; Cozzarelli, I. M.; Godsy, E. M.; Warren, E.; Hostettler, F. D.

2001-12-01

We have identified several subsurface habitats for microorganisms in a crude oil contaminated located near Bemidji, Minnesota. These aquifer habitats include: 1) the unsaturated zone contaminated by hydrocarbon vapors, 2) the zones containing separate-phase crude oil, and 3) the aqueous-phase contaminant plume. The surficial glacial outwash aquifer was contaminated when a crude oil pipeline burst in 1979. We analyzed sediment samples from the contaminated aquifer for the most probable numbers of aerobes, iron reducers, fermenters, and three types of methanogens. The microbial data were then related to gas, water, and oil chemistry, sediment extractable iron, and permeability. The microbial populations in the various contaminated subsurface habitats each have special characteristics and these affect the aquifer and contaminant chemistry. In the eight-meter-thick, vapor-contaminated vadose zone, a substantial aerobic population has developed that is supported by hydrocarbon vapors and methane. Microbial numbers peak in locations where access to both hydrocarbons and nutrients infiltrating from the surface is maximized. The activity of this population prevents hydrocarbon vapors from reaching the land surface. In the zone where separate-phase crude oil is present, a consortium of methanogens and fermenters dominates the populations both above and below the water table. Moreover, gas concentration data indicate that methane production has been active in the oily zone since at least 1986. Analyses of the extracted separate-phase oil show that substantial degradation of C15 -C35 n-alkanes has occurred since 1983, raising the possibility that significant degradation of C15 and higher n-alkanes has occurred under methanogenic conditions. However, lab and field data suggest that toxic inhibition by crude oil results in fewer acetate-utilizing methanogens within and adjacent to the separate-phase oil. Data from this and other sites indicate that toxic inhibition of

Sediment discharge of the rivers of Catalonia, NE Spain, and the influence of human impacts

Science.gov (United States)

Liquete, Camino; Canals, Miquel; Ludwig, Wolfgang; Arnau, Pedro

2009-03-01

SummaryThe environmental and anthropogenic factors controlling sediment delivery to the sea are numerous, intricate and usually difficult to quantify. Mediterranean watersheds are historically amongst the most heavily impacted by human activities in the world. This study analyzes some of these factors for nine river systems from Catalonia, NE Spain, that open into the Northwestern Mediterranean Sea, and discusses the results obtained from sediment yield models and sediment concentration data series. General models indicate that the natural suspended sediment yield by individual Catalan rivers ranged within a fork from 94 to 621 t km -2 yr -1. Such a sediment yield would be noticeably reduced (moving the fork to 7-148 t km -2 yr -1) because of lithological factors and direct anthropogenic and, possibly, climatic impacts. Damming, water extraction and urbanization appear as the most important direct anthropogenic impacts in Catalonia. Water discharge and sediment concentration measurements by basin authorities provide much lower sediment yield estimations, from 0.4 to 19.8 t km -2 yr -1, which is probably due to the lack of measured sediment loads during flood events, as it is the case in many other Mediterranean rivers. The Catalan watersheds have some of the smallest runoff values amongst Mediterranean rivers. Of the nine river systems studied, water discharge tends to decrease in two and to increase in one. The other six river systems do not show any clear tendency. Related to climatic parameters, temperature raised in all the watersheds between 1961 and 1990, while precipitation did not show significant trends.

Hydrogeochemical and mineralogical effects of sustained CO₂ contamination in a shallow sandy aquifer: A field-scale controlled release experiment

DEFF Research Database (Denmark)

Cahill, Aaron Graham; Marker, Pernille Aabye; Jakobsen, Rasmus

2014-01-01

A shallow aquifer CO2 contamination experiment was performed to investigate evolution of water chemistry and sediment alteration following leakage from geological storage by physically simulating a leak from a hypothetical storage site. In a carbonate-free aquifer, in western Denmark, a total...... of 1600 kg of gas phase CO2 was injected at 5 and 10 m depth over 72 days through four inclined injection wells into aeolian and glacial sands. Water chemistry was monitored for pH, EC, and dissolved element evolution through an extensive network of multilevel sampling points over 305 days. Sediment cores...... were taken pre and postinjection and analyzed to search for effects on mineralogy and sediment properties. Results showed the simulated leak to evolve in two distinct phases; an advective elevated ion pulse followed by increasing persistent acidification. Spatial and temporal differences in evolution...

Carbonate aquifers

Science.gov (United States)

Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen

2012-01-01

Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

Sediment impact assessment of check-dam removal strategies on a mountain river in Taiwan

Science.gov (United States)

Kuo, W.; Wang, H.; Stark, C. P.

2011-12-01

Dam removal is important for reconnecting river habitats and restoring the free flow of water and sediment, so managing accumulated sediments is crucial in dam removal planning as the cost and potential impacts of dam removal can vary substantially depending on local conditions. A key uncertainty in dam removal is the fate of reservoir sediment stored upstream of the dam. Release of impounded sediment could raise downstream bed elevations leading to flooding, increase lateral channel mobility leading to bank erosion, and potentially bury downstream ecologically sensitive habitats if the sediment is fine. The ability to predict the sediment impacts of dam removal in highly sediment-filled systems is thus increasingly important as the number of such dam-removal cases is growing. Due to the safety concerns and the need for habitat restoration for the Formosan landlocked salmon, the Shei-Pa National Park in Taiwan removed the 15m high Chijiawan "No. 1 Check Dam" in late May 2011. During the planning process prior to removal, we conducted field surveys, numerical simulations, and flume experiments to determine sediment impacts and to suggest appropriate dam removal strategies. We collected river-bed topography and sediment bulk samples in 2010 to establish the channel geometry and grain-size distribution for modeling input. The scaled flume experiment was designed to provide insights on how and if the position of a notch location and size would affect the rate and amount of reservoir erosion under particular discharges. Observations indicated that choices of notch location can force the river to migrate differently. For long-term prediction, we used the quasi-two-dimensional numerical model NETSTARS (Network of Stream Tube model for Alluvial River Simulation) to simulate the channel responses. These simulations indicated that high suspended sediment concentrations would be the most likely major concern in the first year, while concerns for downstream sediment deposition

Strontium isotope geochemistry of groundwater in the central part of the Dakota (Great Plains) aquifer, USA

International Nuclear Information System (INIS)

Gosselin, David C.; Edwin Harvey, F.; Frost, Carol; Stotler, Randy; Allen Macfarlane, P.

2004-01-01

The Dakota aquifer of the central and eastern Great Plains of the United States is an important source of water for municipal supplies, irrigation and industrial use. Although the regional flow system can be characterized generally as east to northeasterly from the Rocky Mountains towards the Missouri River, locally the flow systems are hydrologically complex. This study uses Sr isotopic data from groundwater and leached aquifer samples to document the complex subsystems within the Dakota aquifer in Nebraska and Kansas. The interaction of groundwater with the geologic material through which it flows has created spatial patterns in the isotopic measurements that are related to: long-term water-rock interaction, during which varying degrees of isotopic equilibrium between water and rock has been achieved; and the alteration of NaCl fluids by water-rock interaction. Specifically, Sr isotopic data distinguish brines from Kansas and western Nebraska from those in eastern Nebraska: the former are interpreted to reflect interaction with Permian rocks, whereas the latter record interaction with Pennsylvanian rocks. The Sr isotopic composition of groundwater from other parts of Nebraska and Kansas are a function of the dynamic interaction between groundwater and unlithified sediments (e.g., glacial till and loess), followed by interaction with oxidized and unoxidized sediments within the Dakota Formation. This study illustrates the power of combining Sr chemistry with more conventional geochemical data to obtain a more complete understanding of groundwater flow systems within regional aquifer systems where extensive monitoring networks do not exist

Water-level altitudes 2017 and water-level changes in the Chicot, Evangeline, and Jasper Aquifers and compaction 1973–2016 in the Chicot and Evangeline Aquifers, Houston-Galveston region, Texas

Science.gov (United States)

Kasmarek, Mark C.; Ramage, Jason K.

2017-08-16

Most of the land-surface subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction of the aquifer sediments, mostly in the fine-grained silt and clay layers. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured cumulative compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2017 water-level altitudes (represented by measurements made during December 2016 through March 2017) and long-term water-level changes for the Chicot, Evangeline, and Jasper aquifers; a map depicting locations of borehole-extensometer (hereinafter referred to as “extensometer”) sites; and graphs depicting measured long-term cumulative compaction of subsurface sediments at the extensometers during 1973–2016.In 2017, water-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) in two localized areas in southwestern and northwestern Harris County to 200 ft above datum in west-central Montgomery County. The largest water-level-altitude decline (120 ft) depicted by the 1977–2017 water-level-change contours for the Chicot aquifer was in northwestern Harris County. A broad area where water-level altitudes declined in the Chicot aquifer extends from northwestern, north-central, and southwestern Harris County

Assessing the impact of preload on pyrite-rich sediment and groundwater quality.

Science.gov (United States)

Karikari-Yeboah, Ohene; Addai-Mensah, Jonas

2017-02-01

Pyrite-rich sediments would, invariably, undergo redox reactions which would lead to acidic aqueous environment containing solubilized toxic metal species. When such sediments are subjected to preload, a technique employed by geotechnical engineers to improve the load-bearing capacity of highly compressible formation, transient flow of pore water, accompanied by acidity transfer, would occur as a response. Despite the concomitant environmental and socio-economic significance, to date, there has been limited interdisciplinary research on the underpinning geotechnical engineering and geo-environmental science issues for pyrite-rich sediments under preload. In this study, we investigate the effect of pyrite-rich sediment pore water transfer under preload surcharge on the receiving environment and the impact on the groundwater speciation and quality. Sediment samples were obtained at close depth intervals from boreholes established within pristine areas and those subjected to the preload application. Soil and pore water samples were subjected to solid/solution speciation, moisture contents, soil pH and the Atterberg Limits' analyses using standard analytical techniques and methods. Standpipes were also installed in the boreholes for groundwater sampling and in situ monitoring of water quality parameters. It is shown that the imposition of preload surcharge over pyritic sediment created a reducing environment rich in SO 4 2- , iron oxide minerals and organic matter. This reducing environment fostered organic carbon catabolism to generate excess pyrite and bicarbonate alkalinity, which would invariably impact adversely on soil quality and plant growth. These were accompanied by increase in pH, dissolved Al, Ca, Mg and K species beneath the surcharge.

Occurrence and fate of bulk organic matter and pharmaceutically active compounds in managed aquifer recharge: A review

KAUST Repository

Maeng, Sungkyu; Sharma, Saroj K.; Lekkerkerker-Teunissen, Karin; Amy, Gary L.

2011-01-01

Managed aquifer recharge (MAR) is a natural water treatment process that induces surface water to flow in response to a hydraulic gradient through soil/sediment and into a vertical or horizontal well. It is a relatively cost-effective, robust

Conceptual and numerical models of the glacial aquifer system north of Aberdeen, South Dakota

Science.gov (United States)

Marini, Katrina A.; Hoogestraat, Galen K.; Aurand, Katherine R.; Putnam, Larry D.

2012-01-01

This U.S. Geological Survey report documents a conceptual and numerical model of the glacial aquifer system north of Aberdeen, South Dakota, that can be used to evaluate and manage the city of Aberdeen's water resources. The glacial aquifer system in the model area includes the Elm, Middle James, and Deep James aquifers, with intervening confining units composed of glacial till. The Elm aquifer ranged in thickness from less than 1 to about 95 feet (ft), with an average thickness of about 24 ft; the Middle James aquifer ranged in thickness from less than 1 to 91 ft, with an average thickness of 13 ft; and the Deep James aquifer ranged in thickness from less than 1 to 165 ft, with an average thickness of 23 ft. The confining units between the aquifers consisted of glacial till and ranged in thickness from 0 to 280 ft. The general direction of groundwater flow in the Elm aquifer in the model area was from northwest to southeast following the topography. Groundwater flow in the Middle James aquifer was to the southeast. Sparse data indicated a fairly flat potentiometric surface for the Deep James aquifer. Horizontal hydraulic conductivity for the Elm aquifer determined from aquifer tests ranged from 97 to 418 feet per day (ft/d), and a confined storage coefficient was determined to be 2.4x10-5. Estimates of the vertical hydraulic conductivity of the sediments separating the Elm River from the Elm aquifer, determined from the analysis of temperature gradients, ranged from 0.14 to 2.48 ft/d. Average annual precipitation in the model area was 19.6 inches per year (in/yr), and agriculture was the primary land use. Recharge to the Elm aquifer was by infiltration of precipitation through overlying outwash, lake sediments, and glacial till. The annual recharge for the model area, calculated by using a soil-water-balance method for water year (WY) 1975-2009, ranged from 0.028 inch in WY 1980 to 4.52 inches in WY 1986, with a mean of 1.56 inches. The annual potential

Impacts of climate and land use change on reservoir sedimentation

Science.gov (United States)

Impacts of evolving climate and implementation of upstream soil conservation measures on sedimentation of the Fort Cobb Reservoir in West-Central Oklahoma are investigated. Conservation practices before the 1950s were few. Between 1950 and 2008, extensive soil conservation measures were implemented...

Radiological impact of surface water and sediment near uranium mining sites.

Science.gov (United States)

Ivanova, K; Stojanovska, Z; Badulin, V; Kunovska, B; Yovcheva, M

2015-12-01

The aim of this study is to assess the radiological impact of surface water and sediment around uranium mining sites 20 years after their closing. The areas under observations are 31 former classical underground uranium mining and exploratory sites in Bulgaria, named as objects. The extraction and processing of uranium ores in the Republic of Bulgaria were ended in 1992. To assess the radiological impact of radionuclides field expeditions were performed to sample water and bottom sediment. The migration of uranium through surface water was examined as one of the major pathways for contamination spread. The range of uranium concentration in water flowing from the mining sites was from 0.012 to 6.8 mgU l(-1) with a geometric mean of 0.192 mgU l(-1). The uranium concentrations in water downstream the mining sites were approximately 3 times higher than the background value (upstream). The concentrations of Unat, (226)Ra, (210)Pb, and (232)Th in the sediment of downstream river were higher than those upstream by 3.4, 2.6, 2, and 1.7 times, respectively. The distribution coefficient of uranium reflects its high mobility in most of the sites. In order to evaluate the impact on people as well as site prioritization for more detailed assessment and water management, screening dose assessments were done.

SRP baseline hydrogeologic investigation: Aquifer characterization

Energy Technology Data Exchange (ETDEWEB)

Strom, R.N.; Kaback, D.S.

1992-03-31

An investigation of the mineralogy and chemistry of the principal hydrogeologic units and the geochemistry of the water in the principal aquifers at Savannah River Site (SRS) was undertaken as part of the Baseline Hydrogeologic Investigation. This investigation was conducted to provide background data for future site studies and reports and to provide a site-wide interpretation of the geology and geochemistry of the Coastal Plain Hydrostratigraphic province. Ground water samples were analyzed for major cations and anions, minor and trace elements, gross alpha and beta, tritium, stable isotopes of hydrogen, oxygen, and carbon, and carbon-14. Sediments from the well borings were analyzed for mineralogy and major and minor elements.

Building Conceptual Models of Field-Scale Uranium Reactive Transport in a Dynamic Vadose Zone-Aquifer-River System

International Nuclear Information System (INIS)

Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.

2008-01-01

Subsurface simulation is being used to build, test, and couple conceptual process models to better understand controls on a 0.4 km by 1.0 km uranium plume that has persisted above the drinking water standard in the groundwater of the Hanford 300 Area over the last 15 years. At this site, uranium-contaminated sediments in the vadose zone and aquifer are subject to significant variations in water levels and velocities driven by the diurnal, weekly, seasonal, and episodic Columbia River stage dynamics. Groundwater flow reversals typically occur twice a day with significant exchange of river water and groundwater in the near-river aquifer. Mixing of the dilute solution chemistry of the river with the groundwater complicates the uranium sorption behavior as the mobility of U(VI) has been shown experimentally to be a function of pH, carbonate, calcium, and uranium. Furthermore, uranium mass transfer between solid and aqueous phases has been observed to be rate-limited in the context of the high groundwater velocities resulting from the river stage fluctuations and the highly transmissive sediments (hydraulic conductivities ∼1500 m/d). One- and two-dimensional vertical cross-sectional simulations of variably-saturated flow and reactive transport, based on laboratory-derived models of distributed rate mass transfer and equilibrium multicomponent surface complexation, are used to assess uranium transport at the dynamic vadose zone aquifer interface as well as changes to uranium mobility due to incursions of river water into the aquifer

Evaluating the impact of land use changes on the behaviour of shallow aquifers, by quantifying the groundwater mean residence times distribution

Science.gov (United States)

Vincent, Aude; Gillon, Marina; Marc, Vincent; Cognard-Plancq, Anne-Laure; Baillieux, Antoine; Babic, Milanka; Simler, Roland

2017-04-01

two zones, non irrigated/irrigated; - a discretised recharge coming from the STICS crop model outputs. Environmental parameters that greatly influence water residence time in the aquifer could be deduced from this approach by progressive increase of the model complexity. Baillieux, A., Olioso, A., Trolard, F., Chanzy, A., Lecerf, R., Lecharpentier, P., Banton, O., Ruget, F., Ruy, S.(2015) Changements globaux : quels impacts sur l'aquifère de la Crau ? Géologues 187, 85-92 Olioso, A., Lecerf, R., Baillieux, A., Chanzy, A., Ruget, F., Banton, O., Lecharpentier, P., Trolard, F., and Cognard-Plancq, A.L. (2013) Modelling of drainage and hay production over the Crau aquifer for analysing impact of global change on aquifer recharge, Procedia Environmental Sciences, 19, 691-700

Uranium speciation and stability after reductive immobilization in aquifer sediments

Science.gov (United States)

Sharp, Jonathan O.; Lezama-Pacheco, Juan S.; Schofield, Eleanor J.; Junier, Pilar; Ulrich, Kai-Uwe; Chinni, Satya; Veeramani, Harish; Margot-Roquier, Camille; Webb, Samuel M.; Tebo, Bradley M.; Giammar, Daniel E.; Bargar, John R.; Bernier-Latmani, Rizlan

2011-11-01

It has generally been assumed that the bioreduction of hexavalent uranium in groundwater systems will result in the precipitation of immobile uraninite (UO 2). In order to explore the form and stability of uranium immobilized under these conditions, we introduced lactate (15 mM for 3 months) into flow-through columns containing sediments derived from a former uranium-processing site at Old Rifle, CO. This resulted in metal-reducing conditions as evidenced by concurrent uranium uptake and iron release. Despite initial augmentation with Shewanella oneidensis, bacteria belonging to the phylum Firmicutes dominated the biostimulated columns. The immobilization of uranium (˜1 mmol U per kg sediment) enabled analysis by X-ray absorption spectroscopy (XAS). Tetravalent uranium associated with these sediments did not have spectroscopic signatures representative of U-U shells or crystalline UO 2. Analysis by microfocused XAS revealed concentrated micrometer regions of solid U(IV) that had spectroscopic signatures consistent with bulk analyses and a poor proximal correlation (μm scale resolution) between U and Fe. A plausible explanation, supported by biogeochemical conditions and spectral interpretations, is uranium association with phosphoryl moieties found in biomass; hence implicating direct enzymatic uranium reduction. After the immobilization phase, two months of in situ exposure to oxic influent did not result in substantial uranium remobilization. Ex situ flow-through experiments demonstrated more rapid uranium mobilization than observed in column oxidation studies and indicated that sediment-associated U(IV) is more mobile than biogenic UO 2. This work suggests that in situ uranium bioimmobilization studies and subsurface modeling parameters should be expanded to account for non-uraninite U(IV) species associated with biomass.

Geophysical and hydrogeological characterisation of the impacts of on-site wastewater treatment discharge to groundwater in a poorly productive bedrock aquifer

Energy Technology Data Exchange (ETDEWEB)

Donohue, Shane [School of Planning, Architecture and Civil Engineering, Queen' s University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, Northern Ireland (United Kingdom); McCarthy, Valerie; Rafferty, Patrick [Department of Applied Sciences, Dundalk Institute of Technology, Dublin Road, Dundalk (Ireland); Orr, Alison; Flynn, Raymond [School of Planning, Architecture and Civil Engineering, Queen' s University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, Northern Ireland (United Kingdom)

2015-08-01

Contaminants discharging from on-site wastewater treatment systems (OSWTSs) can impact groundwater quality, threatening human health and surface water ecosystems. Risk of negative impacts becomes elevated in areas of extreme vulnerability with high water tables, where thin unsaturated intervals limit vadose zone attenuation. A combined geophysical/hydrogeological investigation into the effects of an OSWTS, located over a poorly productive aquifer (PPA) with thin subsoil cover, aimed to characterise effluent impacts on groundwater. Groundwater, sampled from piezometers down-gradient of the OSWTS percolation area displayed spatially erratic, yet temporally consistent, contaminant distributions. Electrical resistivity tomography identified an area of gross groundwater contamination close to the percolation area and, when combined with seismic refraction and water quality data, indicated that infiltrating effluent reaching the water table discharged to a deeper more permeable zone of weathered shale resting on more competent bedrock. Subsurface structure, defined by geophysics, indicated that elevated chemical and microbiological contaminant levels encountered in groundwater samples collected from piezometers, down-gradient of sampling points with lower contaminant levels, corresponded to those locations where piezometers were screened close to the weathered shale/competent rock interface; those immediately up-gradient were too shallow to intercept this interval, and thus the more impacted zone of the contaminant plume. Intermittent occurrence of faecal indicator bacteria more than 100 m down gradient of the percolation area suggested relatively short travel times. Study findings highlight the utility of geophysics as part of multidisciplinary investigations for OSWTS contaminant plume characterisation, while also demonstrating the capacity of effluent discharging to PPAs to impact groundwater quality at distance. Comparable geophysical responses observed in similar

Geophysical and hydrogeological characterisation of the impacts of on-site wastewater treatment discharge to groundwater in a poorly productive bedrock aquifer

International Nuclear Information System (INIS)

Donohue, Shane; McCarthy, Valerie; Rafferty, Patrick; Orr, Alison; Flynn, Raymond

2015-01-01

Contaminants discharging from on-site wastewater treatment systems (OSWTSs) can impact groundwater quality, threatening human health and surface water ecosystems. Risk of negative impacts becomes elevated in areas of extreme vulnerability with high water tables, where thin unsaturated intervals limit vadose zone attenuation. A combined geophysical/hydrogeological investigation into the effects of an OSWTS, located over a poorly productive aquifer (PPA) with thin subsoil cover, aimed to characterise effluent impacts on groundwater. Groundwater, sampled from piezometers down-gradient of the OSWTS percolation area displayed spatially erratic, yet temporally consistent, contaminant distributions. Electrical resistivity tomography identified an area of gross groundwater contamination close to the percolation area and, when combined with seismic refraction and water quality data, indicated that infiltrating effluent reaching the water table discharged to a deeper more permeable zone of weathered shale resting on more competent bedrock. Subsurface structure, defined by geophysics, indicated that elevated chemical and microbiological contaminant levels encountered in groundwater samples collected from piezometers, down-gradient of sampling points with lower contaminant levels, corresponded to those locations where piezometers were screened close to the weathered shale/competent rock interface; those immediately up-gradient were too shallow to intercept this interval, and thus the more impacted zone of the contaminant plume. Intermittent occurrence of faecal indicator bacteria more than 100 m down gradient of the percolation area suggested relatively short travel times. Study findings highlight the utility of geophysics as part of multidisciplinary investigations for OSWTS contaminant plume characterisation, while also demonstrating the capacity of effluent discharging to PPAs to impact groundwater quality at distance. Comparable geophysical responses observed in similar

Groundwater vulnerability mapping in Guadalajara aquifers system (Western Mexico)

Science.gov (United States)

Rizo-Decelis, L. David; Marín, Ana I.; Andreo, Bartolomé

2016-04-01

Groundwater vulnerability mapping is a practical tool to implement strategies for land-use planning and sustainable socioeconomic development coherent with groundwater protection. The objective of vulnerability mapping is to identify the most vulnerable zones of catchment areas and to provide criteria for protecting the groundwater used for drinking water supply. The delineation of protection zones in fractured aquifers is a challenging task due to the heterogeneity and anisotropy of hydraulic conductivities, which makes difficult prediction of groundwater flow organization and flow velocities. Different methods of intrinsic groundwater vulnerability mapping were applied in the Atemajac-Toluquilla groundwater body, an aquifers system that covers around 1300 km2. The aquifer supplies the 30% of urban water resources of the metropolitan area of Guadalajara (Mexico), where over 4.6 million people reside. Study area is located in a complex neotectonic active volcanic region in the Santiago River Basin (Western Mexico), which influences the aquifer system underneath the city. Previous works have defined the flow dynamics and identified the origin of recharge. In addition, the mixture of fresh groundwater with hydrothermal and polluted waters have been estimated. Two main aquifers compose the multilayer system. The upper aquifer is unconfined and consists of sediments and pyroclastic materials. Recharge of this aquifer comes from rainwater and ascending vertical fluids from the lower aquifer. The lower aquifer consists of fractured basalts of Pliocene age. Formerly, the main water source has been the upper unit, which is a porous and unconsolidated unit, which acts as a semi-isotropic aquifer. Intense groundwater usage has resulted in lowering the water table in the upper aquifer. Therefore, the current groundwater extraction is carried out from the deeper aquifer and underlying bedrock units, where fracture flow predominates. Pollution indicators have been reported in

Soil aquifer treatment using advanced primary effluent

KAUST Repository

Sharma, Saroj K.; Hussen, Mustefa; Amy, Gary L.

2011-01-01

Soil aquifer treatment (SAT) using primary effluent (PE) is an attractive option for wastewater treatment and reuse in many developing countries with no or minimal wastewater treatment. One of the main limitations of SAT of PE is rapid clogging of the infiltration basin due to high suspended solid concentrations. Some pre-treatment of PE before infiltration is likely to reduce this limitation, improve performance of SAT and help to implement this technology effectively. The effects of three pre-treatment options namely sedimentation (SED), coagulation (COAG) and horizontal roughing filtration (HRF) on SAT were analyzed by conducting laboratory-scale batch and soil column experiments. The sedimentation and coagulation pre-treatments led to less head loss development and reduction of clogging effect. The head loss development in soil column using PE + COAG and PE + SED was reduced by 85 and 72%, respectively, compared to PE alone without any pretreatment. The overall dissolved organic carbon (DOC) removal of pre-treatments and soil column collectively were 34, 44, 51 and 43.5% for PE without any pre-treatment, PE + SED, PE+ COAG and PE + HRF, respectively. Coagulation pre-treatment of PE was found to be the most effective option in terms of suspended solids, DOC and nitrogen removal. Sedimentation pre-treatment of PE could be attractive where land is relatively less expensive for the construction of sedimentation basins. © IWA Publishing 2011.

Soil aquifer treatment using advanced primary effluent

KAUST Repository

Sharma, Saroj K.

2011-08-01

Soil aquifer treatment (SAT) using primary effluent (PE) is an attractive option for wastewater treatment and reuse in many developing countries with no or minimal wastewater treatment. One of the main limitations of SAT of PE is rapid clogging of the infiltration basin due to high suspended solid concentrations. Some pre-treatment of PE before infiltration is likely to reduce this limitation, improve performance of SAT and help to implement this technology effectively. The effects of three pre-treatment options namely sedimentation (SED), coagulation (COAG) and horizontal roughing filtration (HRF) on SAT were analyzed by conducting laboratory-scale batch and soil column experiments. The sedimentation and coagulation pre-treatments led to less head loss development and reduction of clogging effect. The head loss development in soil column using PE + COAG and PE + SED was reduced by 85 and 72%, respectively, compared to PE alone without any pretreatment. The overall dissolved organic carbon (DOC) removal of pre-treatments and soil column collectively were 34, 44, 51 and 43.5% for PE without any pre-treatment, PE + SED, PE+ COAG and PE + HRF, respectively. Coagulation pre-treatment of PE was found to be the most effective option in terms of suspended solids, DOC and nitrogen removal. Sedimentation pre-treatment of PE could be attractive where land is relatively less expensive for the construction of sedimentation basins. © IWA Publishing 2011.

Aquifer/aquitard interfaces: mixing zones that enhance biogeochemical reactions

Science.gov (United States)

McMahon, P. B.

2001-01-01

Several important biogeochemical reactions are known to occur near the interface between aquifer and aquitard sediments. These reactions include O2 reduction; denitrification; and Fe3+, SO42-, and CO2 (methanogenesis) reduction. In some settings, these reactions occur on the aquitard side of the interface as electron acceptors move from the aquifer into the electron-donor-enriched aquitard. In other settings, these reactions occur on the aquifer side of the interface as electron donors move from the aquitard into the electron-acceptor-enriched, or microorganism-enriched, aquifer. Thus, the aquifer/aquitard interface represents a mixing zone capable of supporting greater microbial activity than either hydrogeologic unit alone. The extent to which biogeochemical reactions proceed in the mixing zone and the width of the mixing zone depend on several factors, including the abundance and solubility of electron acceptors and donors on either side of the interface and the rate at which electron acceptors and donors react and move across the interface. Biogeochemical reactions near the aquifer/aquitard interface can have a substantial influence on the chemistry of water in aquifers and on the chemistry of sediments near the interface. Résumé. Il se produit au voisinage de l'interface entre les aquifères et les imperméables plusieurs réactions biogéochimiques importantes. Il s'agit des réactions de réduction de l'oxygène, de la dénitrification et de la réduction de Fe3+, SO42- et CO2 (méthanogenèse). Dans certaines situations, ces réactions se produisent du côté imperméable de l'interface, avec des accepteurs d'électrons qui vont de l'aquifère vers l'imperméable riche en donneurs d'électrons. Dans d'autres situations, ces réactions se produisent du côté aquifère de l'interface, avec des donneurs d'électrons qui se déplacent de l'imperméable vers l'aquifère riche en accepteurs d'électrons ou en microorganismes. Ainsi, l'interface aquif

Impacts of ocean acidification on sediment processes in shallow waters of the Arctic Ocean.

Science.gov (United States)

Gazeau, Frédéric; van Rijswijk, Pieter; Pozzato, Lara; Middelburg, Jack J

2014-01-01

Despite the important roles of shallow-water sediments in global biogeochemical cycling, the effects of ocean acidification on sedimentary processes have received relatively little attention. As high-latitude cold waters can absorb more CO2 and usually have a lower buffering capacity than warmer waters, acidification rates in these areas are faster than those in sub-tropical regions. The present study investigates the effects of ocean acidification on sediment composition, processes and sediment-water fluxes in an Arctic coastal system. Undisturbed sediment cores, exempt of large dwelling organisms, were collected, incubated for a period of 14 days, and subject to a gradient of pCO2 covering the range of values projected for the end of the century. On five occasions during the experimental period, the sediment cores were isolated for flux measurements (oxygen, alkalinity, dissolved inorganic carbon, ammonium, nitrate, nitrite, phosphate and silicate). At the end of the experimental period, denitrification rates were measured and sediment samples were taken at several depth intervals for solid-phase analyses. Most of the parameters and processes (i.e. mineralization, denitrification) investigated showed no relationship with the overlying seawater pH, suggesting that ocean acidification will have limited impacts on the microbial activity and associated sediment-water fluxes on Arctic shelves, in the absence of active bio-irrigating organisms. Only following a pH decrease of 1 pH unit, not foreseen in the coming 300 years, significant enhancements of calcium carbonate dissolution and anammox rates were observed. Longer-term experiments on different sediment types are still required to confirm the limited impact of ocean acidification on shallow Arctic sediment processes as observed in this study.

Planning report for the Gulf Coast Regional Aquifer-System Analysis in the Gulf of Mexico coastal plain, United States

Science.gov (United States)

Grubb, Hayes F.

1984-01-01

Large quantities of water for municipal, industrial and agriculture use are supplied from the aquifers in Tertiary and younger sediments over an area of about 225,000 square miles in the Coastal Plain of Alabama, Arkansas, Florida, Illinois, Kentucky, Louisiana, Mississippi, Missouri, Tennessee, and Texas. Three regional aquifer systems, the Mississippi Embayment aquifer system, the Coastal Lowlands aquifer system, and the Texas Coastal Uplands aquifer system have been developed to varying degrees throughout the area. A variety of problems has resulted from development such as movement of the saline-freshwater interface into parts of aquifers that were previously fresh, lowering of the potentiometric surface with resulting increases in pumping lift, and land-surface subsidence due to the compaction of clays within the aquifer. Increased demand for ground water is anticipated to meet the needs of urban growth, expanded energy development, and growth of irrigated agriculture. The U. S. Geological Survey initiated an eightyear study in 1981 to define the geohydrologic framework, describe the chemistry of the ground water, and to analyze the regional ground-water flow patterns. The objectives, plan, and organization of the study are described in this report and the major tasks to be undertaken are outlined.

Climate Change Impacts on Sediment Transport In a Lowland Watershed System: Controlling Processes and Projection

Science.gov (United States)

al Aamery, N. M. H.; Mahoney, D. T.; Fox, J.

2017-12-01

Future climate change projections suggest extreme impacts on watershed hydrologic systems for some regions of the world including pronounced increases in surface runoff and instream flows. Yet, there remains a lack of research focused on how future changes in hydrologic extremes, as well as relative hydrologic mean changes, impact sediment redistribution within a watershed and sediment flux from a watershed. The authors hypothesized that variations in mean and extreme changes in turn may impact sediments in depositional and erosional dominance in a manner that may not be obvious to the watershed manager. Therefore, the objectives of this study were to investigate the inner processes connecting the combined effect of extreme climate change projections on the vegetation, upland erosion, and instream processes to produce changes in sediment redistribution within watersheds. To do so, research methods were carried out by the authors including simulating sediment processes in forecast and hindcast periods for a lowland watershed system. Publically available climate realizations from several climate factors and the Soil Water Assessment Tool (SWAT) were used to predict hydrologic conditions for the South Elkhorn Watershed in central Kentucky, USA to 2050. The results of the simulated extreme and mean hydrological components were used in simulating upland erosion with the connectivity processes consideration and thereafter used in building and simulating the instream erosion and deposition of sediment processes with the consideration of surface fine grain lamina (SFGL) layer controlling the benthic ecosystem. Results are used to suggest the dominance of erosional and depositional redistribution of sediments under different scenarios associated with extreme and mean hydrologic forecasting. The results are discussed in reference to the benthic ecology of the stream system providing insight on how water managers might consider sediment redistribution in a changing climate.

Analytical solutions for recession analyses of sloping aquifers - applicability on relict rock glaciers in alpine catchments

Science.gov (United States)

Pauritsch, Marcus; Birk, Steffen; Hergarten, Stefan; Kellerer-Pirklbauer, Andreas; Winkler, Gerfried

2014-05-01

Rock glaciers as aquifer systems in alpine catchments may strongly influence the hydrological characteristics of these catchments. Thus, they have a high impact on the ecosystem and potential natural hazards such as for example debris flow. Therefore, knowledge of the hydrodynamic processes, internal structure and properties of these aquifers is important for resource management and risk assessment. The investigation of such aquifers often turns out to be expensive and technically complicated because of their strongly limited accessibility. Analytical solutions of discharge recession provide a quick and easy way to estimate aquifer parameters. However, due to simplifying assumptions the validity of the interpretation is often questionable. In this study we compared results of an analytical solution of discharge recessions with results based on a numerical model. This was done in order to analyse the range of uncertainties and the applicability of the analytical method in alpine catchment areas. The research area is a 0.76 km² large catchment in the Seckauer Tauern Range, Austria. The dominant aquifer in this catchment is a rock glacier, namely the Schöneben Rock Glacier. This relict rock glacier (i.e. containing no permafrost at present) covers an area of 0.11 km² and is drained by one spring at the rock glacier front. The rock glacier consists predominantly of gneissic sediments (mainly coarse-grained, blocky at the surface) and extends from 1720 to 1905 m a.s.l.. Discharge of the rock glacier spring is automatically measured since 2002. Electric conductivity and water temperature is monitored since 2008. An automatic weather station was installed in 2011 in the central part of the catchment. Additionally data of geophysical surveys (refraction seismic and ground penetrating radar) have been used to analyse the base slope and inner structure of the rock glacier. The measured data are incorporated into a numerical model implemented in MODFLOW. The numerical

Inherent mineralization of 2,6-dichlorobenzamide (BAM) in unsaturated zone and aquifers – Effect of initial concentrations and adaptation

DEFF Research Database (Denmark)

Janniche, Gry Sander; Clausen, Liselotte; Albrechtsen, Hans-Jørgen

2011-01-01

cores with known dichlobenil application were collected from topsoil to 8.5 m below surface resulting in 57 samples hereof 4 aquifer samples. Mineralization was only substantial (>10%) in the uppermost meter of the unsaturated zone. Microbial adaptation, observed as faster mineralization in pre......, in pre-exposed clay mineralization was stimulated at high concentrations. Furthermore BAM was for the first time mineralized in aerobic aquifer sediments from different BAM-contaminated groundwater locations. BAM mineralization in subsurface and groundwater was demonstrated....

Occurrence and geochemical behavior of arsenic in a coastal aquifer-aquitard system of the Pearl River Delta, China

Energy Technology Data Exchange (ETDEWEB)

Wang, Ya [Department of Earth Sciences, The University of Hong Kong, Hong Kong (China); Jiao, Jiu Jimmy, E-mail: jjiao@hku.hk [Department of Earth Sciences, The University of Hong Kong, Hong Kong (China); Cherry, John A. [School of Engineering, University of Guelph, Guelph, ON, Canada N1G 2W1 (Canada)

2012-06-15

Elevated concentrations of arsenic, up to 161 {mu}g/L, have been identified in groundwater samples from the confined basal aquifer underlying the aquitard of the Pearl River Delta (PRD). Both aquatic arsenic in pore water and solid arsenic in the sediments in the basal aquifer and aquitard were identified. Arsenic speciation of groundwater in the basal aquifer was elucidated on a pH-Eh diagram. In the PRD, arsenic is enriched in groundwater having both low and high salinity, and arsenic enriched groundwater is devoid of dissolved oxygen, has negative Eh values, is slightly alkaline, and has abnormally high concentrations of ammonium and dissolved organic carbon, but low concentrations of nitrate and nitrite. Results of geochemical and hydrochemical analyses and sequential extraction analysis suggest that reductive dissolution of iron oxyhydroxide could be one of the important processes that mobilized solid arsenic. We speculate that mineralization of sedimentary organic matter could also contribute to aquatic arsenic. Scanning electron microscope analysis confirms that abundant authigenic pyrite is present in the sediments. Sulphate derived from paleo-seawater served as the important sulfur source for authigenic pyrite formation. Co-precipitation of arsenic with authigenic pyrite significantly controlled concentrations of aquatic arsenic in the coastal aquifer-aquitard system. - Highlights: Black-Right-Pointing-Pointer Coastal aquifer and aquitard are treated as an integrate system. Black-Right-Pointing-Pointer Both aquatic arsenic and solid arsenic are observed. Black-Right-Pointing-Pointer Aquatic arsenic is derived from reductive dissolution of iron oxyhydroxide. Black-Right-Pointing-Pointer Aquatic arsenic can also derived from mineralization of sedimentary organic matter. Black-Right-Pointing-Pointer Co-precipitation of arsenic with authigenic pyrite is significant in such a system.

Microbial community evolution during simulated managed aquifer recharge in response to different biodegradable dissolved organic carbon (BDOC) concentrations

KAUST Repository

Li, Dong

2013-05-01

This study investigates the evolution of the microbial community in laboratory-scale soil columns simulating the infiltration zone of managed aquifer recharge (MAR) systems and analogous natural aquifer sediment ecosystems. Parallel systems were supplemented with either moderate (1.1 mg/L) or low (0.5 mg/L) biodegradable dissolved organic carbon (BDOC) for a period of six months during which time, spatial (1 cm, 30 cm, 60 cm, 90 cm, and 120 cm) and temporal (monthly) analyses of sediment-associated microbial community structure were analyzed. Total microbial biomass associated with sediments was positively correlated with BDOC concentration where a significant decline in BDOC was observed along the column length. Analysis of 16S rRNA genes indicated dominance by Bacteria with Archaea comprising less than 1 percent of the total community. Proteobacteria was found to be the major phylum in samples from all column depths with contributions from Betaproteobacteria, Alphaproteobacteria and Gammaproteobacteria. Microbial community structure at all the phylum, class and genus levels differed significantly at 1 cm between columns receiving moderate and low BDOC concentrations; in contrast strong similarities were observed both between parallel column systems and across samples from 30 to 120 cm depths. Samples from 1 cm depth of the low BDOC columns exhibited higher microbial diversity (expressed as Shannon Index) than those at 1 cm of moderate BDOC columns, and both increased from 5.4 to 5.9 at 1 cm depth to 6.7-8.3 at 30-120 cm depths. The microbial community structure reached steady state after 3-4 months since the initiation of the experiment, which also resulted in an improved DOC removal during the same time period. This study suggested that BDOC could significantly influence microbial community structure regarding both composition and diversity of artificial MAR systems and analogous natural aquifer sediment ecosystems. © 2013 Elsevier Ltd.

Variable exchange between a stream and an aquifer in the Rio Grande Project Area

Science.gov (United States)

Sheng, Z.; Abudu, S.; Michelsen, A.; King, P.

2016-12-01

Both surface water and groundwater in the Rio Grande Project area in southern New Mexico and Far West Texas have been stressed by natural conditions such as droughts and human activities, including urban development and agricultural irrigation. In some area pumping stress in the aquifer becomes so great that it depletes the river flow especially during the irrigation season, typically from March through October. Therefore understanding such relationship between surface water and groundwater becomes more important in regional water resources planning and management. In this area, stream flows are highly regulated by the upstream reservoirs during the irrigation season and greatly influenced by return flows during non-irrigation season. During a drought additional groundwater pumping to supplement surface water shortage further complicates the surface water and groundwater interaction. In this paper the authors will use observation data and results of numerical models (MODFLOW) to characterize and quantify hydrological exchange fluxes between groundwater in the aquifers and surface water as well as impacts of groundwater pumping. The interaction shows a very interesting seasonal variation (irrigation vs. non-irrigation) as well as impact of a drought. Groundwater has been pumped for both municipal supplies and agricultural irrigation, which has imposed stresses toward both stream flows and aquifer storage. The results clearly show that historic groundwater pumping has caused some reaches of the river change from gaining stream to losing stream. Beyond the exchange between surface water and groundwater in the shallow aquifer, groundwater pumping in a deep aquifer could also enhance the exchanges between different aquifers through leaky confining layers. In the earlier history of pumping, pumping from the shallow aquifer is compensated by simple depletion of surface water, while deep aquifer tends to use the aquifer storage. With continued pumping, the cumulative

Impact of river stage prediction methods on stream-aquifer exchanges in a hydro(geo)logical model at the regional scale

Science.gov (United States)

Saleh, F.; Flipo, N.; de Fouquet, C.

2012-04-01

The main objective of this study is to provide a realistic simulation of river stage in regional river networks in order to improve the quantification of stream-aquifer exchanges and better assess the associated aquifer responses that are often impacted by the magnitude and the frequency of the river stage fluctuations. The study focuses on the Oise basin (17 000 km2, part of the 65 000 km2 Seine basin in Northern France) where stream-aquifer exchanges cannot be assessed directly by experimental methods. Nowadays numerical methods are the most appropriate approaches for assessing stream-aquifer exchanges at this scale. A regional distributed process-based hydro(geo)logical model, Eau-Dyssée, is used, which aims at the integrated modeling of the hydrosystem to manage the various elements involved in the quantitative and qualitative aspects of water resources. Eau-Dyssée simulates pseudo 3D flow in aquifer systems solving the diffusivity equation with a finite difference numerical scheme. River flow is simulated with a Muskingum model. In addition to the in-stream discharge, a river stage estimate is needed to calculate the water exchange at the stream-aquifer interface using the Darcy law. Three methods for assessing in-stream river stages are explored to determine the most appropriate representation at regional scale over 25 years (1980-2005). The first method consists in defining rating curves for each cell of a 1D Saint-Venant hydraulic model. The second method consists in interpolating observed rating curves (at gauging stations) onto the river cells of the hydro(geo)logical model. The interpolation technique is based on geostatistics. The last method assesses river stage using Manning equation with a simplified rectangular cross-section (water depth equals the hydraulic radius). Compared to observations, the geostatistical and the Manning methodologies lead to slightly less accurate (but still acceptable) results offering a low computational cost opportunity

Microbial diversity and impact on carbonate geochemistry across a changing geochemical gradient in a karst aquifer.

Science.gov (United States)

Gray, Cassie J; Engel, Annette S

2013-02-01

Although microbes are known to influence karst (carbonate) aquifer ecosystem-level processes, comparatively little information is available regarding the diversity of microbial activities that could influence water quality and geological modification. To assess microbial diversity in the context of aquifer geochemistry, we coupled 16S rRNA Sanger sequencing and 454 tag pyrosequencing to in situ microcosm experiments from wells that cross the transition from fresh to saline and sulfidic water in the Edwards Aquifer of central Texas, one of the largest karst aquifers in the United States. The distribution of microbial groups across the transition zone correlated with dissolved oxygen and sulfide concentration, and significant variations in community composition were explained by local carbonate geochemistry, specifically calcium concentration and alkalinity. The waters were supersaturated with respect to prevalent aquifer minerals, calcite and dolomite, but in situ microcosm experiments containing these minerals revealed significant mass loss from dissolution when colonized by microbes. Despite differences in cell density on the experimental surfaces, carbonate loss was greater from freshwater wells than saline, sulfidic wells. However, as cell density increased, which was correlated to and controlled by local geochemistry, dissolution rates decreased. Surface colonization by metabolically active cells promotes dissolution by creating local disequilibria between bulk aquifer fluids and mineral surfaces, but this also controls rates of karst aquifer modification. These results expand our understanding of microbial diversity in karst aquifers and emphasize the importance of evaluating active microbial processes that could affect carbonate weathering in the subsurface.

General characteristics of the aquifer system Joanicó (Montevideo, Uruguay)

International Nuclear Information System (INIS)

Gagliardi Urtasun, S.; Montaño, X.; Montaño Gutiérrez, M.; Lacués Parodi, X.

2010-01-01

The work area, comprising the towns of Joanicó, Sauce and N Progress , Canelones province, is a center of intensive agricultural development (viticulture, hortofruticultura, etc), where demand and exploitation of groundwater is common primarily for irrigation supply .The subsoil consists of sedimentary rocks and sediments belonging to the Freedom and Dolores ( Pleistocene), Fray Bentos (Upper Oligocene) (aquitards), Mercedes formations - Asencio (Upper Cretaceous) and Migues (Lower Cretaceous). Permeable levels in the Mercedes and Migues formations make up a significant potential aquifer system , which we call Joanicó Aquifer System. This aquifer is multilayer type and consists of fine to coarse sand and gravel and sand mixture , with the occasional presence of thin matrix. Semi confined and behaves as confined in most area; in the outcrop of the Merc edes training is free. The average transmissivity is approximately the 50m2/día; The average permeability of 5 to 10 m/day. The storage coefficient (confined area) is of the order 10-4 .In the most developed area of the aquifer is where Joanicó are obtained by constructing boreholes higher flows Canelones department: more than 25% of the wells drilled to extract higher flow 15 m3/h y extracted more than 40% flows over 10 m3/h. The production of many agricultural enterprises depends directly on the area irrigated with groundwater, so the deeper knowledge of the exploited resource is paramount

DNA-SIP identifies sulfate-reducing Clostridia as important toluene degraders in tar-oil-contaminated aquifer sediment

Energy Technology Data Exchange (ETDEWEB)

Winderl, C.; Penning, H.; von Netzer, F.; Meckenstock, R.U.; Lueders, T. [Helmholtz Zentrum Munchen, Neuherberg (Germany)

2010-10-15

Global groundwater resources are constantly challenged by a multitude of contaminants such as aromatic hydrocarbons. Especially in anaerobic habitats, a large diversity of unrecognized microbial populations may be responsible for their degradation. Still, our present understanding of the respective microbiota and their ecophysiology is almost exclusively based on a small number of cultured organisms, mostly within the Proteobacteria. Here, by DNA-based stable isotope probing (SIP), we directly identified the most active sulfate-reducing toluene degraders in a diverse sedimentary microbial community originating from a tar-oil-contaminated aquifer at a former coal gasification plant. On incubation of fresh sediments with {sup 13}C{sub 7}-toluene, the production of both sulfide and (CS{sub 2}){sup 13}CO{sub 2} was clearly coupled to the {sup 13}Clabeling of DNA of microbes related to Desulfosporosinus spp. within the Peptococcaceae (Clostridia). The screening of labeled DNA fractions also suggested a novel benzylsuccinate synthase alpha-subunit (bssA) sequence type previously only detected in the environment to be tentatively affiliated with these degraders. However, carbon flow from the contaminant into degrader DNA was only similar to 50%, pointing toward high ratios of heterotrophic CS{sub 2}-fixation during assimilation of acetyl-CoA originating from the contaminant by these degraders. These findings demonstrate that the importance of non-proteobacterial populations in anaerobic aromatics degradation, as well as their specific ecophysiology in the subsurface may still be largely ungrasped.

Arsenic and other oxyanion-forming trace elements in an alluvial basin aquifer: Evaluating sources and mobilization by isotopic tracers (Sr, B, S, O, H, Ra)

Energy Technology Data Exchange (ETDEWEB)

Vinson, David S., E-mail: dsv3@duke.edu [Duke University, Division of Earth and Ocean Sciences, Box 90227, Durham, NC 27708 (United States); McIntosh, Jennifer C. [University of Arizona, Department of Hydrology and Water Resources, 1133 E. James E. Rogers Way, Tucson, AZ 85721 (United States); Dwyer, Gary S.; Vengosh, Avner [Duke University, Division of Earth and Ocean Sciences, Box 90227, Durham, NC 27708 (United States)

2011-08-15

Highlights: > Elevated natural As and F occur in the Willcox Basin aquifer of Arizona. > Oxyanion-forming elements are derived from volcanic-source aquifer sediments. > Sr isotopes trace sediment sources linked to oxyanion-forming trace elements. > {sup 87}Sr/{sup 86}Sr > 0.720 indicates Proterozoic crystalline-source sediment contributing low As. > Both sediment source and hydrogeochemical evolution (Ca/Na) affect As levels. - Abstract: The Willcox Basin is a hydrologically closed basin in semi-arid southeastern Arizona (USA) and, like many other alluvial basins in the southwestern USA, is characterized by oxic, near-neutral to slightly basic groundwater containing naturally elevated levels of oxyanion-forming trace elements such as As. This study evaluates the sources and mobilization of these oxyanionic trace elements of health significance by using several isotopic tracers of water-rock interaction and groundwater sources ({sup 87}Sr/{sup 86}Sr, {delta}{sup 34}S{sub SO4}, {delta}{sup 11}B, {delta}{sup 2}H, {delta}{sup 18}O, {sup 3}H). Values of {delta}{sup 2}H (-85 per mille to -64 per mille) and {delta}{sup 18}O (-11.8 per mille to -8.6 per mille) are consistent with precipitation and groundwater in adjacent alluvial basins, and low to non-detectable {sup 3}H activities further imply that modern recharge is slow in this semi-arid environment. Large variations in {sup 87}Sr/{sup 86}Sr ratios imply that groundwater has interacted with multiple sediment sources that constitute the basin-fill aquifer, including Tertiary felsic volcanic rocks, Paleozoic sedimentary rocks, and Proterozoic crystalline rocks. In general, low concentrations of oxyanion-forming trace elements and F{sup -} are associated with a group of waters exhibiting highly radiogenic values of {sup 87}Sr/{sup 86}Sr (0.72064-0.73336) consistent with waters in Proterozoic crystalline rocks in the mountain blocks (0.73247-0.75010). Generally higher As concentrations (2-29 {mu}g L{sup -1}), other

Groundwater exploration in a Quaternary sediment body by shear-wave reflection seismics

Science.gov (United States)

Pirrung, M.; Polom, U.; Krawczyk, C. M.

2008-12-01

The detailed investigation of a shallow aquifer structure is the prerequisite for choosing a proper well location for groundwater exploration drilling for human drinking water supply and subsequent managing of the aquifer system. In the case of shallow aquifers of some 10 m in depth, this task is still a challenge for high-resolution geophysical methods, especially in populated areas. In areas of paved surfaces, shallow shear-wave reflection seismics is advantageous compared to conventional P-wave seismic methods. The sediment body of the Alfbach valley within the Vulkaneifel region in Germany, partly covered by the village Gillenfeld, was estimated to have a maximum thickness of nearly 60 m. It lies on top of a complicated basement structure, constituted by an incorporated lava flow near the basement. For the positioning of new well locations, a combination of a SH-wave land streamer receiver system and a small, wheelbarrow-mounted SH-wave source was used for the seismic investigations. This equipment can be easily applied also in residential areas without notable trouble for the inhabitants. The results of the 2.5D profiling show a clear image of the sediment body down to the bedrock with high resolution. Along a 1 km seismic profile, the sediment thickness varies between 20 to more than 60 m in the centre of the valley. The reflection behaviour from the bedrock surface corroborates the hypothesis of a basement structure with distinct topography, including strong dipping events from the flanks of the valley and strong diffractions from subsurface discontinuities. The reflection seismic imaging leads to an estimation of the former shape of the valley and a reconstruction of the flow conditions at the beginning of the sedimentation process.

Groundwater Remediation in a Floodplain Aquifer at Shiprock, New Mexico

Energy Technology Data Exchange (ETDEWEB)

Peterson, Dave [Navarro Research and Engineering; Miller, David [Navarro Research and Engineering; Kautsky, Mark [U. S. Department of Energy, Office of Legacy Management; Dander, David [Navarro Research and Engineering; Nofchissey, Joni [Navajo Nation Division of Natural Resources

2016-03-06

A uranium- and vanadium-ore-processing mill operated from 1954 to 1968 within the Navajo Nation near Shiprock, New Mexico. By September 1986, all tailings and structures on the former mill property were encapsulated in a disposal cell built on top of two existing tailings piles on the Shiprock site (the site) [1]. Local groundwater was contaminated by multiple inorganic constituents as a result of the milling operations. The U.S. Department of Energy (DOE) took over management of the site in 1978 as part of the Uranium Mill Tailings Remedial Action (UMTRA) Project. The DOE Office of Legacy Management currently manages ongoing activities at the former mill facility, including groundwater remediation. Remediation activities are designed primarily to reduce the concentrations and total plume mass of the mill-related contaminants sulfate, uranium, and nitrate. In addition to contaminating groundwater in alluvial and bedrock sediments directly below the mill site, ore processing led to contamination of a nearby floodplain bordering the San Juan River. Groundwater in a shallow alluvial aquifer beneath the floodplain is strongly influenced by the morphology of the river channel as well as changing flows in the river, which provides drainage for regional runoff from the San Juan Mountains of Colorado. As part of a recent study of the floodplain hydrology, a revised conceptual model was developed for the alluvial aquifer along with an updated status of contaminant plumes that have been impacted by more than 10 years of groundwater pumping for site remediation purposes. Several findings from the recent study will be discussed here.

Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

Energy Technology Data Exchange (ETDEWEB)

Bencini, A.; Ercolanelli, R.; Sbaragli, A. [Univ. of Florence (Italy)] [and others

1993-11-01

Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

The Impacts of Episodic Storm and Flood Events on Carbon and Sediment Delivery to Gulf of Mexico Sediments

Science.gov (United States)

Schreiner, K. M.; Carlin, J. A.; Sayers, L.; Swenson, J.

2017-12-01

Marine sediments are an important long-term reservoir for both recently fixed organic carbon (OC) and ancient rock derived OC, much of which is delivered by rivers. The ratio between these two sources of OC in turn regulates atmospheric levels of oxygen and carbon dioxide over geologic time, making this riverine delivery of OC, primarily carried by sediments, an important flux in the global carbon cycle. However, while the overall magnitude of these fluxes are relatively well known, it remains to be determined the importance of episodic events, like storms and floods, in the flux of OC from terrestrial to marine environments. Here, we present data from a 34 cm core collected from the Gulf of Mexico at a mid-shelf distal depocenter for the Brazos River in 2015, during a strong El Nino when that area of the country was experiencing 100-year flood events and anomalously high river flow. Based on analysis of the radioactive isotope 7Be, approximately the top 7-8 cm of the sediment in this core was deposited during this flood event. Both bulk elemental (C, N, and stable carbon isotopes) and chemical biomarker (lignin-phenol) data has been combined to provide information of the origin and chemistry of the OC in this core both before and during flooding. C:N and d13C indicate a mixture of marine-sourced and terrestrially-sourced OC throughout the length of the core with very little variation between the flood layer and deeper sediments. However, lignin-phenol concentrations are higher in flood-deposited sediment, indicating that this sediment is likely terrestrially-sourced. Lignin-phenol indicators of OC degradation state (Acid:Aldehyde ratios) indicate that flood sediment is fresher and less degraded than deeper sediments. Taken together, these results indicate that 1. Bulk analyses are not enough to determine OC source and the importance of flood events in OC cycling and 2. Episodic events like floods could have an oversized impact on OC storage in marine sediments.

isotopic characteristics of aquifers in sinai

International Nuclear Information System (INIS)

Al-Gamal, S.A.

2004-01-01

the environmental isotopes data (expressed as δ 2 d and δ 18 O) of different aquifers in sinai were treated using correlation and regression techniques. whereas, rain water isotopic data were treated using empirical orthogonal functions (EOF) techniques. environmental isotopes for different aquifers expressed in terms of O-18 and H-2, were taken to represent the isotopic characteristics. regression equations using the highly correlated variables of δ 2 d and δ 18 O were constructed for each aquifer. the latitudinal variations (of rainwater in sinai and selected climatic stations east mediterranean ) versus rainwater isotopic compositions were analyzed using the normalized variables. it was found that the latitudinal variations of the rainwater isotopic compositions ( δ 2 D, δ 18 O), vapor pressure, and surface temperature occurred in parallel and decreased with latitude. in the east mediterranean, empirical linear relationship between altitude and δ 2 D has indicted that the rate of change of δ 2 D with height is comparable with the dry lapse rate in the atmosphere.The obtained regression equations of environmental isotopes data have impacted on different slopes and different constants expressing the non-homogeneity in the isotopic composition of rainwater recharging the aquifers of sinai , due to the presence of different air masses

Modeling Anthropogenic Impact on Sediment Balance and Relative Sea-Level Rise in Contemporary and Future Deltas

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Tessler, Z. D.; Vorosmarty, C. J.; Overeem, I.; Syvitski, J. P.

2017-12-01

Modern deltas are dependent on human-mediated freshwater and sediment fluxes. Changes to these fluxes impact delta biogeophysical functioning, and affect the long-term sustainability of these landscapes for both human and natural systems. Here we present contemporary estimates of long-term mean sediment balance and relative sea-level rise across 46 global deltas. We model ongoing development and scenarios of future water resource management and hydropower infrastructure in upstream river basins to explore how changing sediment fluxes impact relative sea-level in coastal delta systems. Model results show that contemporary sediment fluxes, anthropogenic drivers of land subsidence, and sea-level rise result in relative sea-level rise rates in deltas that average 6.8 mm/year. Currently planned or under-construction dams can be expected to increase rates of relative sea-level rise on the order of 1 mm/year. Some deltas systems, including the Magdalena, Orinoco, and Indus, are highly sensitive to future impoundment of river basins, with RSLR rates increasing up to 4 mm/year in a high-hydropower-utilization scenario. Sediment fluxes may be reduced by up to 60% in the Danube and 21% in the Ganges-Brahmaputra-Megnha if all currently planned dams are constructed. Reduced sediment retention on deltas due to increased river channelization and local flood controls increases RSLR on average by nearly 2 mm/year. Long-term delta sustainability requires a more complete understanding of how geophysical and anthropogenic change impact delta geomorphology. Strategies for sustainable delta management that focus on local and regional drivers of change, especially groundwater and hydrocarbon extraction and upstream dam construction, can be highly impactful even in the context of global climate-induced sea-level rise.

Origin and distribution of saline groundwaters in the upper Miocene aquifer system, coastal Rhodope area, northeastern Greece

Science.gov (United States)

Petalas, C. P.; Diamantis, I. B.

1999-06-01

This paper describes the origins and distribution of saline groundwaters in the coastal area of Rhodope, Greece. The aquifer system includes two aquifers within coarse-grained alluvial sediments in the coastal part of the study area. Two major water-quality groups occur in the study area, namely Ca2+-rich saline groundwater and Ca2+-poor, almost fresh groundwater. The main process controlling the groundwater chemistry is the exchange of calcium and sodium between the aquifer matrix and intruding seawater. The natural salt water in the study area is probably residual water that infiltrated the aquifer system during repeated marine transgressions in late Pleistocene time. Seawater intrusion into the coastal aquifer system occurs as a result of overpumping in two seawater wedges separated vertically by a low-permeability layer. The rate of intrusion averages 0.8 m/d and is less than expected due to a decline of the aquifer's permeability at the interface with the seawater. The application of several hydrochemical techniques (Piper and Durov diagrams; Na+/Cl-, Ca2+/Cl-, Mg2+/Cl-, and Br-/Cl- molar ratios; Ca2+/Mg2+ weight ratio; and chloride concentrations), combined with field observations, may lead to a better explanation of the origin of the saline groundwater.

Geochemistry and toxicity of sediment porewater in a salt-impacted urban stormwater detention pond

International Nuclear Information System (INIS)

Mayer, T.; Rochfort, Q.; Borgmann, U.; Snodgrass, W.

2008-01-01

A comprehensive study was carried out to investigate the impacts of road salts on the benthic compartment of a small urban detention facility, Rouge River Pond. Although the pond is an engineered water body, it is representative of many small urban lakes, ponds and wetlands, which receive road runoff and are probable high impact areas. Specific objectives of the study were to document the porewater chemistry of an aquatic system affected by elevated salt concentrations and to carry out a toxicological assessment of sediment porewater to determine what factors may cause porewater toxicity. The results indicate that the sediment porewater may itself attain high salt concentrations. The computations show that increased chloride levels have important implications on the Cd complexation, augmenting its concentration in porewater. The toxicity tests suggest that the toxicity in porewater is caused by metals or other toxic chemicals, rather than high levels of chloride. - Effects of chlorides on metal chemistry and toxicity of sediment porewater in a stormwater detention pond impacted by road salts

AQUIFER OF THE WESTERN PART OF THE PRGOVO POLJE ON THE ISLAND OF LASTOVO

Directory of Open Access Journals (Sweden)

Renato Buljan

2006-12-01

Full Text Available Two new-drilled wells in the Prgovo Polje are pumped and additionally tested for the water supply of the island Lastovo. The research works were aimed at finding boundary quantitative and qualitative parameters for their optimal exploitation, desalination and use of the pumped water in the existent water supply system. Collected hydrogeological and hydrogeochemical data indicate the presence of stratified aquifer in the western part of Prgovo Polje consisting of two poorly connected horizons. Water from the shallower part of the aquifer, drilled by the well MZ-2 in the carbonate rocks at the edge of polje, is good enough for desalination. The deeper part of aquifer, drilled by the well MZ-1 in the carbonate cavern below the polje’s clastic sediments, experiences the greater influence of the sea water. Its continuing pumping combined with low quantity of water is the main reason of the ever increasing influence of the sea water (the paper is published in Croatian.

Alluvial aquifers in the Mzingwane catchment: Their distribution, properties, current usage and potential expansion

Science.gov (United States)

Moyce, William; Mangeya, Pride; Owen, Richard; Love, David

The Mzingwane River is a sand filled channel, with extensive alluvial aquifers distributed along its banks and bed in the lower catchment. LandSat TM imagery was used to identify alluvial deposits for potential groundwater resources for irrigation development. On the false colour composite band 3, band 4 and band 5 (FCC 345) the alluvial deposits stand out as white and dense actively growing vegetation stands out as green making it possible to mark out the lateral extent of the saturated alluvial plain deposits using the riverine fringe and vegetation . The alluvial aquifers form ribbon shaped aquifers extending along the channel and reaching over 20 km in length in some localities and are enhanced at lithological boundaries. These alluvial aquifers extend laterally outside the active channel, and individual alluvial aquifers have been measured with area ranging from 45 ha to 723 ha in the channels and 75 ha to 2196 ha on the plains. The alluvial aquifers are more pronounced in the Lower Mzingwane, where the slopes are gentler and allow for more sediment accumulation. Estimated water resources potential ranges between 175,000 m 3 and 5,430,000 m 3 in the channels and between 80,000 m 3 and 6,920,000 m 3 in the plains. Such a water resource potential can support irrigation ranging from 18 ha to 543 ha for channels alluvial aquifers and 8 ha to 692 ha for plain alluvial aquifers. Currently, some of these aquifers are being used to provide water for domestic use, livestock watering and dip tanks, commercial irrigation and market gardening. The water quality of the aquifers in general is fairly good due to regular recharge and flushing out of the aquifers by annual river flows and floodwater. Water salinity was found to increase significantly in the end of the dry season, and this effect was more pronounced in water abstracted from wells on the alluvial plains. During drought years, recharge is expected to be less and if the drought is extended water levels in the

Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia

International Nuclear Information System (INIS)

Guo Huaming; Zhang Bo; Li Yuan; Berner, Zsolt; Tang Xiaohui; Norra, Stefan; Stueben, Doris

2011-01-01

Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO 4 2- concentrations and δ 34 S values indicates that bacterial reduction of SO 4 2- occurs in reducing aquifers. Due to high concentrations of Fe (>0.5 mg L -1 ), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. - Research highlights: → Low As groundwaters occur in alluvial fans. → We find low As groundwaters near irrigation and drainage channels. → Both hydrogeologic conditions and biogeochemical processes control As distribution. - Both hydrogeologic conditions and biogeochemical processes control As distribution of shallow groundwaters, which results in the occurrence of low As groundwater in alluvial fans and near irrigation channels and drainage channels.

Fertilizers mobilization in alluvial aquifer: laboratory experiments

Science.gov (United States)

Mastrocicco, M.; Colombani, N.; Palpacelli, S.

2009-02-01

In alluvial plains, intensive farming with conspicuous use of agrochemicals, can cause land pollution and groundwater contamination. In central Po River plain, paleo-channels are important links between arable lands and the underlaying aquifer, since the latter is often confined by clay sediments that act as a barrier against contaminants migration. Therefore, paleo-channels are recharge zones of particular interest that have to be protected from pollution as they are commonly used for water supply. This paper focuses on fertilizer mobilization next to a sand pit excavated in a paleo-channel near Ferrara (Italy). The problem is approached via batch test leaking and columns elution of alluvial sediments. Results from batch experiments showed fast increase in all major cations and anions, suggesting equilibrium control of dissolution reactions, limited availability of solid phases and geochemical homogeneity of samples. In column experiments, early elution and tailing of all ions breakthrough was recorded due to preferential flow paths. For sediments investigated in this study, dispersion, dilution and chemical reactions can reduce fertilizers at concentration below drinking standards in a reasonable time frame, provided fertilizer loading is halted or, at least, reduced. Thus, the definition of a corridor along paleo-channels is recommended to preserve groundwater quality.

Characterising aquifer treatment for pathogens in managed aquifer recharge.

Science.gov (United States)

Page, D; Dillon, P; Toze, S; Sidhu, J P S

2010-01-01

In this study the value of subsurface treatment of urban stormwater during Aquifer Storage Transfer Recovery (ASTR) is characterised using quantitative microbial risk assessment (QMRA) methodology. The ASTR project utilizes a multi-barrier treatment train to treat urban stormwater but to date the role of the aquifer has not been quantified. In this study it was estimated that the aquifer barrier provided 1.4, 2.6, >6.0 log(10) removals for rotavirus, Cryptosporidium and Campylobacter respectively based on pathogen diffusion chamber results. The aquifer treatment barrier was found to vary in importance vis-à-vis the pre-treatment via a constructed wetland and potential post-treatment options of UV-disinfection and chlorination for the reference pathogens. The risk assessment demonstrated that the human health risk associated with potable reuse of stormwater can be mitigated (disability adjusted life years, DALYs aquifer is integrated with suitable post treatment options into a treatment train to attenuate pathogens and protect human health.

Metagenomic profiles of antibiotic resistance genes (ARGs) between human impacted estuary and deep ocean sediments.

Science.gov (United States)

Chen, Baowei; Yang, Ying; Liang, Ximei; Yu, Ke; Zhang, Tong; Li, Xiangdong

2013-11-19

Knowledge of the origins and dissemination of antibiotic resistance genes (ARGs) is essential for understanding modern resistomes in the environment. The mechanisms of the dissemination of ARGs can be revealed through comparative studies on the metagenomic profiling of ARGs between relatively pristine and human-impacted environments. The deep ocean bed of the South China Sea (SCS) is considered to be largely devoid of anthropogenic impacts, while the Pearl River Estuary (PRE) in south China has been highly impacted by intensive human activities. Commonly used antibiotics (sulfamethazine, norfloxacin, ofloxacin, tetracycline, and erythromycin) have been detected through chemical analysis in the PRE sediments, but not in the SCS sediments. In the relatively pristine SCS sediments, the most prevalent and abundant ARGs are those related to resistance to macrolides and polypeptides, with efflux pumps as the predominant mechanism. In the contaminated PRE sediments, the typical ARG profiles suggest a prevailing resistance to antibiotics commonly used in human health and animal farming (including sulfonamides, fluoroquinolones, and aminoglycosides), and higher diversity in both genotype and resistance mechanism than those in the SCS. In particular, antibiotic inactivation significantly contributed to the resistance to aminoglycosides, β-lactams, and macrolides observed in the PRE sediments. There was a significant correlation in the levels of abundance of ARGs and those of mobile genetic elements (including integrons and plasmids), which serve as carriers in the dissemination of ARGs in the aquatic environment. The metagenomic results from the current study support the view that ARGs naturally originate in pristine environments, while human activities accelerate the dissemination of ARGs so that microbes would be able to tolerate selective environmental stress in response to anthropogenic impacts.

Alluvial Aquifer

Data.gov (United States)

Kansas Data Access and Support Center — This coverage shows the extents of the alluvial aquifers in Kansas. The alluvial aquifers consist of unconsolidated Quaternary alluvium and contiguous terrace...

Seasonal Influences on Ground-Surface Water Interactions in an Arsenic-Affected Aquifer in Cambodia

Science.gov (United States)

Richards, L. A.; Magnone, D.; Van Dongen, B.; Bryant, C.; Boyce, A.; Ballentine, C. J.; Polya, D. A.

2015-12-01

Millions of people in South and Southeast Asia consume drinking water daily which contains dangerous levels of arsenic exceeding health-based recommendations [1]. A key control on arsenic mobilization in aquifers in these areas has been controversially identified as the interaction of 'labile' organic matter contained in surface waters with groundwaters and sediments at depth [2-4], which may trigger the release of arsenic from the solid- to aqueous-phase via reductive dissolution of iron-(hyr)oxide minerals [5]. In a field site in Kandal Province, Cambodia, which is an arsenic-affected area typical to others in the region, there are strong seasonal patterns in groundwater flow direction, which are closely related to monsoonal rains [6] and may contribute to arsenic release in this aquifer. The aim of this study is to explore the implications of the high susceptibility of this aquifer system to seasonal changes on potential ground-surface water interactions. The main objectives are to (i) identify key zones where there are likely ground-surface water interactions, (ii) assess the seasonal impact of such interactions and (iii) quantify the influence of interactions using geochemical parameters (such as As, Fe, NO3, NH4, 14C, 3T/3He, δ18O, δ2H). Identifying the zones, magnitude and seasonal influence of ground-surface water interactions elucidates new information regarding potential locations/pathways of arsenic mobilization and/or transport in affected aquifers and may be important for water management strategies in affected areas. This research is supported by NERC (NE/J023833/1) to DP, BvD and CJB and a NERC PhD studentship (NE/L501591/1) to DM. References: [1] World Health Organization, 2008. [2] Charlet & Polya (2006), Elements, 2, 91-96. [3] Harvey et al. (2002), Science, 298, 1602-1606. [4] Lawson et al. (2013), Env. Sci. Technol. 47, 7085 - 7094. [5] Islam et al. (2004), Nature, 430, 68-71. [6] Benner et al. (2008) Appl. Geochem. 23(11), 3072 - 3087.

Mobilization of arsenic and other naturally occurring contaminants in groundwater of the Main Ethiopian Rift aquifers.

Science.gov (United States)

Rango, Tewodros; Vengosh, Avner; Dwyer, Gary; Bianchini, Gianluca

2013-10-01

This study investigates the mechanisms of arsenic (As) and other naturally occurring contaminants (F(-), U, V, B, and Mo) mobilization from Quaternary sedimentary aquifers of the Main Ethiopian Rift (MER) and their enrichment in the local groundwater. The study is based on systematic measurements of major and trace elements as well as stable oxygen and hydrogen isotopes in groundwater, coupled with geochemical and mineralogical analyses of the aquifer rocks. The Rift Valley aquifer is composed of rhyolitic volcanics and Quaternary lacustrine sediments. X-ray fluorescence (XRF) results revealed that MER rhyolites (ash, tuff, pumice and ignimbrite) and sediments contain on average 72 wt. % and 65 wt. % SiO2, respectively. Petrographic studies of the rhyolites indicate predominance of volcanic glass, sanidine, pyroxene, Fe-oxides and plagioclase. The As content in the lacustrine sediments (mean = 6.6 mg/kg) was higher than that of the rhyolites (mean: 2.5 mg/kg). The lacustrine aquifers of the Ziway-Shala basin in the northern part of MER were identified as high As risk zones, where mean As concentration in groundwater was 22.4 ± 33.5 (range of 0.60-190 μg/L) and 54% of samples had As above the WHO drinking water guideline value of 10 μg/L. Field As speciation measurements showed that most of the groundwater samples contain predominantly (~80%) arsenate-As(V) over arsenite-As(III) species. The As speciation together with field data of redox potential (mean Eh = +73 ± 65 mV) and dissolved-O2 (6.6 ± 2.2 mg/L) suggest that the aquifer is predominantly oxidative. Water-rock interactions, including the dissolution of volcanic glass produces groundwater with near-neutral to alkaline pH (range 6.9-8.9), predominance of Na-HCO3 ions, and high concentration of SiO2 (mean: 85.8 ± 11.3 mg/L). The groundwater data show high positive correlation of As with Na, HCO3, U, B, V, and Mo (R(2) > 0.5; p groundwater indicates that Fe-oxides and oxyhydroxides minerals were saturated

Time to stop mucking around? Impacts of underwater photography on cryptobenthic fauna found in soft sediment habitats.

Science.gov (United States)

De Brauwer, Maarten; Saunders, Benjamin J; Ambo-Rappe, Rohani; Jompa, Jamaluddin; McIlwain, Jennifer L; Harvey, Euan S

2018-07-15

Scuba diving tourism is a sustainable source of income for many coastal communities, but can have negative environmental impacts if not managed effectively. Diving on soft sediment habitats, typically referred to as 'muck diving', is a growing multi-million dollar industry with a strong focus on photographing cryptobenthic fauna. We assessed how the environmental impacts of scuba divers are affected by the activity they are engaged in while diving and the habitat they dive in. To do this, we observed 66 divers on coral reefs and soft sediment habitats in Indonesia and the Philippines. We found diver activity, specifically interacting with and photographing fauna, causes greater environmental disturbances than effects caused by certification level, gender, dive experience or age. Divers touched the substrate more often while diving on soft sediment habitats than on coral reefs, but this did not result in greater environmental damage on soft sediment sites. Divers had a higher impact on the substrate and touch animals more frequently when observing or photographing cryptobenthic fauna. When using dSLR-cameras, divers spent up to five times longer interacting with fauna. With the unknown, long-term impacts on cryptobenthic fauna or soft sediment habitats, and the increasing popularity of underwater photography, we argue for the introduction of a muck diving code of conduct. Copyright © 2018 Elsevier Ltd. All rights reserved.

A novel analytical solution for estimating aquifer properties within a horizontally anisotropic aquifer bounded by a stream

Science.gov (United States)

Huang, Yibin; Zhan, Hongbin; Knappett, Peter S. K.

2018-04-01

Past studies modeling stream-aquifer interaction commonly account for vertical anisotropy in hydraulic conductivity, but rarely address horizontal anisotropy, which may exist in certain sedimentary environments. If present, horizontal anisotropy will greatly impact stream depletion and the amount of recharge a pumped aquifer captures from the river. This scenario requires a different and somewhat more sophisticated mathematical approach to model and interpret pumping test results than previous models used to describe captured recharge from rivers. In this study, a new mathematical model is developed to describe the spatiotemporal distribution of drawdown from stream-bank pumping with a well screened across a horizontally anisotropic, confined aquifer, laterally bounded by a river. This new model is used to estimate four aquifer parameters including the magnitude and directions of major and minor principal transmissivities and storativity based on the observed drawdown-time curves within a minimum of three non-collinear observation wells. In order to approve the efficacy of the new model, a MATLAB script file is programmed to conduct a four-parameter inversion to estimate the four parameters of concern. By comparing the results of analytical and numerical inversions, the accuracy of estimated results from both inversions is acceptable, but the MATLAB program sometimes becomes problematic because of the difficulty of separating the local minima from the global minima. It appears that the new analytical model of this study is applicable and robust in estimating parameter values for a horizontally anisotropic aquifer laterally bounded by a stream. Besides that, the new model calculates stream depletion rate as a function of stream-bank pumping. Unique to horizontally anisotropic and homogeneous aquifers, the stream depletion rate at any given pumping rate depends closely on the horizontal anisotropy ratio and the direction of the principle transmissivities relative to

Potential Impact of Climate Change on Suspended Sediment Yield in NW Spain: A Case Study on the Corbeira Catchment

Directory of Open Access Journals (Sweden)

M. Luz Rodríguez-Blanco

2016-10-01

Full Text Available Soil losses and the subsequent sediment delivery constitute significant environmental threats. Climate change is likely to have an impact on the availability of water and therefore on sediment yield in catchments. In this context, quantifying the sediment response to an increased atmospheric CO2 concentration and climate change is of utmost importance to the proper management of rural catchments. However, quantitative assessment of climate change impact remains a complex task. In this study, the potential medium (2031–2060 and long-term (2069–2098 impacts of projected changes of temperature, rainfall and CO2 concentration on sediment yield in a small rural catchment located in NW Spain were evaluated using the Soil and Water Assessment Tool (SWAT model. Climate change scenarios were created using future climate data projected by regional climate models from the ENSEMBLES project and two CO2 concentration scenarios (550 and 660 ppm. The results showed that climate change would have a noticeable impact on suspended sediment if the forecast temperature, rainfall and CO2 concentration changes included in this study were met. Overall, suspended sediment is expected to decrease (2031–2060: −11%, 2069–2098: −8% compared to the baseline period (1981–2010, mainly due to decreased streamflow. However, an increase in sediment transport in winter is predicted, possibly associated with increased erosion in cultivated areas (11%–17%, suggesting that, at this time of the year, the effect of soil detachment prevails over sediment transport capacity. Consequently, management practices aimed at reducing soil erosion in cultivated areas should be carried out, because these are the main source of sediment in the study area.

Sources, occurrence and predicted aquatic impact of legacy and contemporary pesticides in streams.

Science.gov (United States)

McKnight, Ursula S; Rasmussen, Jes J; Kronvang, Brian; Binning, Philip J; Bjerg, Poul L

2015-05-01

We couple current findings of pesticides in surface and groundwater to the history of pesticide usage, focusing on the potential contribution of legacy pesticides to the predicted ecotoxicological impact on benthic macroinvertebrates in headwater streams. Results suggest that groundwater, in addition to precipitation and surface runoff, is an important source of pesticides (particularly legacy herbicides) entering surface water. In addition to current-use active ingredients, legacy pesticides, metabolites and impurities are important for explaining the estimated total toxicity attributable to pesticides. Sediment-bound insecticides were identified as the primary source for predicted ecotoxicity. Our results support recent studies indicating that highly sorbing chemicals contribute and even drive impacts on aquatic ecosystems. They further indicate that groundwater contaminated by legacy and contemporary pesticides may impact adjoining streams. Stream observations of soluble and sediment-bound pesticides are valuable for understanding the long-term fate of pesticides in aquifers, and should be included in stream monitoring programs. Copyright © 2015 Elsevier Ltd. All rights reserved.

Impact of model complexity and multi-scale data integration on the estimation of hydrogeological parameters in a dual-porosity aquifer

Science.gov (United States)

Tamayo-Mas, Elena; Bianchi, Marco; Mansour, Majdi

2018-03-01

This study investigates the impact of model complexity and multi-scale prior hydrogeological data on the interpretation of pumping test data in a dual-porosity aquifer (the Chalk aquifer in England, UK). In order to characterize the hydrogeological properties, different approaches ranging from a traditional analytical solution (Theis approach) to more sophisticated numerical models with automatically calibrated input parameters are applied. Comparisons of results from the different approaches show that neither traditional analytical solutions nor a numerical model assuming a homogenous and isotropic aquifer can adequately explain the observed drawdowns. A better reproduction of the observed drawdowns in all seven monitoring locations is instead achieved when medium and local-scale prior information about the vertical hydraulic conductivity (K) distribution is used to constrain the model calibration process. In particular, the integration of medium-scale vertical K variations based on flowmeter measurements lead to an improvement in the goodness-of-fit of the simulated drawdowns of about 30%. Further improvements (up to 70%) were observed when a simple upscaling approach was used to integrate small-scale K data to constrain the automatic calibration process of the numerical model. Although the analysis focuses on a specific case study, these results provide insights about the representativeness of the estimates of hydrogeological properties based on different interpretations of pumping test data, and promote the integration of multi-scale data for the characterization of heterogeneous aquifers in complex hydrogeological settings.

Chronic Exposure of Corals to Fine Sediments: Lethal and Sub-Lethal Impacts

Science.gov (United States)

Flores, Florita; Hoogenboom, Mia O.; Smith, Luke D.; Cooper, Timothy F.; Abrego, David; Negri, Andrew P.

2012-01-01

Understanding the sedimentation and turbidity thresholds for corals is critical in assessing the potential impacts of dredging projects in tropical marine systems. In this study, we exposed two species of coral sampled from offshore locations to six levels of total suspended solids (TSS) for 16 weeks in the laboratory, including a 4 week recovery period. Dose-response relationships were developed to quantify the lethal and sub-lethal thresholds of sedimentation and turbidity for the corals. The sediment treatments affected the horizontal foliaceous species (Montipora aequituberculata) more than the upright branching species (Acropora millepora). The lowest sediment treatments that caused full colony mortality were 30 mg l−1 TSS (25 mg cm−2 day−1) for M. aequituberculata and 100 mg l−1 TSS (83 mg cm−2 day−1) for A. millepora after 12 weeks. Coral mortality generally took longer than 4 weeks and was closely related to sediment accumulation on the surface of the corals. While measurements of damage to photosystem II in the symbionts and reductions in lipid content and growth indicated sub-lethal responses in surviving corals, the most reliable predictor of coral mortality in this experiment was long-term sediment accumulation on coral tissue. PMID:22662225

Chronic exposure of corals to fine sediments: lethal and sub-lethal impacts.

Directory of Open Access Journals (Sweden)

Florita Flores

Full Text Available Understanding the sedimentation and turbidity thresholds for corals is critical in assessing the potential impacts of dredging projects in tropical marine systems. In this study, we exposed two species of coral sampled from offshore locations to six levels of total suspended solids (TSS for 16 weeks in the laboratory, including a 4 week recovery period. Dose-response relationships were developed to quantify the lethal and sub-lethal thresholds of sedimentation and turbidity for the corals. The sediment treatments affected the horizontal foliaceous species (Montipora aequituberculata more than the upright branching species (Acropora millepora. The lowest sediment treatments that caused full colony mortality were 30 mg l(-1 TSS (25 mg cm(-2 day(-1 for M. aequituberculata and 100 mg l(-1 TSS (83 mg cm(-2 day(-1 for A. millepora after 12 weeks. Coral mortality generally took longer than 4 weeks and was closely related to sediment accumulation on the surface of the corals. While measurements of damage to photosystem II in the symbionts and reductions in lipid content and growth indicated sub-lethal responses in surviving corals, the most reliable predictor of coral mortality in this experiment was long-term sediment accumulation on coral tissue.

Retoxification by heavy metals at land-sea interface in coastal aquifers

Science.gov (United States)

Fidelibus, Maria Dolores

2014-05-01

Although during the last decades a significant number of countermeasures have been put in place with respect to the release of pollutants into the environment, and emissions of many of these are in fact ceased, the signs of a generalized pollution are found with increasing frequency. The appearance of new signals may surprise, given that common sense leads us to believe that in a period of reduced emissions the environment should be in an improved state rather than in a worse one: however, the environmental effects of previous pollution are clearly appearing after a build-up of pollutants in the environment over the past decades, with a lag with respect to the activities that generated it.In particular, soils are the final receptor (sink) of pollutants as heavy metals, pesticides and fertilizers: the common belief that the heavy metals remain forever locked may, however, give a false sense of security: today it is no longer possible to ignore the fact that the soils involve potential long-term impacts.With this in mind we can open a window on some aspects of the nonlinear behavior of soils and detrital aquifers. Researches on the former are more frequent and help extending some results to the latter. As matter of fact, in response to variations in environmental conditions, sudden releases of pollutants accumulated in soils occur with a considerable delay compared to the input. The attention of the study is on coastal aquifers. The coastal areas in general are dynamic non-linear systems at the land-sea interface in perpetual chemical-physical disequilibrium: these areas are complex with regard to the constituent elements and subject to a set of variable boundary conditions (oscillating borderswith periodic and aperiodic frequency), to cyclic and non-cyclic variations of climatic conditions and anthropogenic forcing (permanent or transient), whose behavior is not easily predictable, and that act on different temporal and spatial scales.The question is: can the

Sources, occurrence and predicted aquatic impact of legacy and contemporary pesticides in streams

International Nuclear Information System (INIS)

McKnight, Ursula S.; Rasmussen, Jes J.; Kronvang, Brian; Binning, Philip J.; Bjerg, Poul L.

2015-01-01

We couple current findings of pesticides in surface and groundwater to the history of pesticide usage, focusing on the potential contribution of legacy pesticides to the predicted ecotoxicological impact on benthic macroinvertebrates in headwater streams. Results suggest that groundwater, in addition to precipitation and surface runoff, is an important source of pesticides (particularly legacy herbicides) entering surface water. In addition to current-use active ingredients, legacy pesticides, metabolites and impurities are important for explaining the estimated total toxicity attributable to pesticides. Sediment-bound insecticides were identified as the primary source for predicted ecotoxicity. Our results support recent studies indicating that highly sorbing chemicals contribute and even drive impacts on aquatic ecosystems. They further indicate that groundwater contaminated by legacy and contemporary pesticides may impact adjoining streams. Stream observations of soluble and sediment-bound pesticides are valuable for understanding the long-term fate of pesticides in aquifers, and should be included in stream monitoring programs. - Highlights: • Findings comprised a range of contemporary and banned legacy pesticides in streams. • Groundwater is a significant pathway for some herbicides entering streams. • Legacy pesticides increased predicted aquatic toxicity by four orders of magnitude. • Sediment-bound insecticides were identified as the primary source for ecotoxicity. • Stream monitoring programs should include legacy pesticides to assess impacts. - Legacy pesticides, particularly sediment-bound insecticides were identified as the primary source for predicted ecotoxicity impacting benthic macroinvertebrates in headwater streams

Porosity and Organic Carbon Controls on Naturally Reduced Zone (NRZ) Formation Creating Microbial ';Hotspots' for Fe, S, and U Cycling in Subsurface Sediments

Science.gov (United States)

Jones, M. E.; Janot, N.; Bargar, J.; Fendorf, S. E.

2013-12-01

Previous studies have illustrated the importance of Naturally Reduced Zones (NRZs) within saturated sediments for the cycling of metals and redox sensitive contaminants. NRZs can provide a source of reducing equivalents such as reduced organic compounds or hydrogen to stimulate subsurface microbial communities. These NRZ's are typically characterized by low permeability and elevated concentrations of organic carbon and trace metals. However, both the formation of NRZs and their importance to the overall aquifer carbon remineralization is not fully understood. Within NRZs the hydrolysis of particulate organic carbon (POC) and subsequent fermentation of dissolved organic carbon (DOC) to form low molecular weight dissolved organic carbon (LMW-DOC) provides electron donors necessary for the respiration of Fe, S, and in the case of the Rifle aquifer, U. Rates of POC hydrolysis and subsequent fermentation have been poorly constrained and rates in excess and deficit to the rates of subsurface anaerobic respiratory processes have been suggested. In this study, we simulate the development of NRZ sediments in diffusion-limited aggregates to investigate the physical and chemical conditions required for NRZ formation. Effects of sediment porosity and POC loading on Fe, S, and U cycling on molecular and nanoscale are investigated with synchrotron-based Near Edge X-ray Absorption Fine Structure Spectroscopy (NEXAFS). Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS) and Fourier Transform Infrared spectroscopy (FTIR) are used to characterize the transformations in POC and DOC. Sediment aggregates are inoculated with the natural microbial biota from the Rifle aquifer and population dynamics are monitored by 16S RNA analysis. Overall, establishment of low permeability NRZs within the aquifer stimulate microbial respiration beyond the diffusion-limited zones and can limit the transport of U through a contaminated aquifer. However, the long-term stability of

Natural and EDTA-complexed lanthanides used as a geochemical probe for aquifers: a case study of Orleans valley's alluvial and karstic aquifers

International Nuclear Information System (INIS)

Le Borgne, F.; Treuil, M.; Joron, J.L.; Lepiller, M.

2005-01-01

The transit of chemical elements within the different parts of Orleans valley's aquifer is studied by two complementary methods. Those methods rely on the fractionation of lanthanides (Ln) during their migration in natural waters. The first method consists in studying natural lanthanides patterns within the watershed, at its entries and exits. second one lies on multi-tracer experiments with Ln-EDTA complexes. This work is completed through an observation network consisting of 52 piezometers set on a sand and gravel quarry, and the natural entries and exits of the aquifer. Orleans valley's aquifer, which is made of an alluvial watershed lying on a karstic aquifer, is mainly fed by Loire river via a large karstic network. At the entries of the aquifer (Loire river at Jargeau), the Ln concentrations in the dissolved fraction ( heavy Ln. On the other hand, the filtration of alluvial groundwater with high colloids content induces no significant Ln fractionation when the solution contains no strong chelating agent. Hence, the transit of natural and artificial Ln in Orleans valley aquifer can be explained by two complementary processes. (I) Decanting/filtering or, on the opposite, stirring of colloids. Those processes induce no important Ln fractionation. (2) Exchanges of Ln between solute complexes, colloids and sediments due to the presence of strong chelating agents. Those exchanges fractionate the Ln in the order of their stability constants. Considering the natural Ln fractionation that occurs in the Loire river and in the studied aquifer, the carbonates, the stability constants of which follow the order light Ln < heavy Ln, are the best candidates as natural strong chelating agents. From the hydrodynamic point of view, both tracer experiments and natural Ln concentrations show that the transfer of elements within the alluvial watershed is pulsed by the Loire river movements. During an ascent phase, the elements migrate away from and perpendicularly to the karstic

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

Directory of Open Access Journals (Sweden)

Robert eDanczak

2016-05-01

Full Text Available Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11 and Parcubacteria (OD1 that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Snowmelt induced hydrologic perturbations drive dynamic microbiological and geochemical behaviors across a shallow riparian aquifer

Science.gov (United States)

Danczak, Robert; Yabusaki, Steven; Williams, Kenneth; Fang, Yilin; Hobson, Chad; Wilkins, Michael

2016-05-01

Shallow riparian aquifers represent hotspots of biogeochemical activity in the arid western US. While these environments provide extensive ecosystem services, little is known of how natural environmental perturbations influence subsurface microbial communities and associated biogeochemical processes. Over a six-month period we tracked the annual snowmelt-driven incursion of groundwater into the vadose zone of an aquifer adjacent to the Colorado River, leading to increased dissolved oxygen (DO) concentrations in the normally suboxic saturated zone. Strong biogeochemical heterogeneity was measured across the site, with abiotic reactions between DO and sulfide minerals driving rapid DO consumption and mobilization of redox active species in reduced aquifer regions. Conversely, extensive DO increases were detected in less reduced sediments. 16S rRNA gene surveys tracked microbial community composition within the aquifer, revealing strong correlations between increases in putative oxygen-utilizing chemolithoautotrophs and heterotrophs and rising DO concentrations. The gradual return to suboxic aquifer conditions favored increasing abundances of 16S rRNA sequences matching members of the Microgenomates (OP11) and Parcubacteria (OD1) that have been strongly implicated in fermentative processes. Microbial community stability measurements indicated that deeper aquifer locations were relatively less affected by geochemical perturbations, while communities in shallower locations exhibited the greatest change. Reactive transport modeling of the geochemical and microbiological results supported field observations, suggesting that a predictive framework can be applied to develop a greater understanding of such environments.

Fluid flow and sediment transport in evolving sedimentary basins

Science.gov (United States)

Swenson, John Bradley

This thesis consists of three studies that focus on groundwater flow and sediment transport in evolving sedimentary basins. The first study considers the subsurface hydrodynamic response to basin-scale transgression and regression and its implications for stratiform ore genesis. I demonstrate that the transgressive sequence focuses marginward-directed, compaction-driven discharge within a basal aquifer during progradation and deposition of the overlying regressive sequence, isolates the basal aquifer from overlying flow systems, and serves as a chemical sink for metal-bearing brines. In the second study, I develop a new theory for the shoreline response to subsidence, sediment supply, and sea level. In this theory, sediment transport in a fluvio-deltaic basin is formally equivalent to heat transfer in a two-phase (liquid and isothermal solid) system: the fluvial system is analogous to a conduction-dominated liquid phase, the shoreline is the melting front, and the water depth at the delta toe is equivalent to the latent heat of fusion. A natural consequence of this theory is that sediment-starved basins do not possess an equilibrium state. In contrast to existing theories, I do not observe either strong phase shifting or attenuation of the shoreline response to low-frequency eustatic forcing; rather, shoreline tracks sea level over a spectrum of forcing frequencies, and its response to low-frequency forcing is amplified relative to the high-frequency response. For the third study, I use a set of dimensionless numbers from the previous study as a mathematical framework for providing a unified treatment of existing stratigraphic theories. In the limit of low-amplitude eustatic forcing, my study suggests that strong phase shifting between shoreline and sea level is a consequence of specifying the sedimentation rate at the shoreline; basins free of this constraint do not develop strong phase shifts.

A new approach for assessing the future of aquifers supporting irrigated agriculture

Science.gov (United States)

Butler, James J.; Whittemore, Donald O.; Wilson, Blake B.; Bohling, Geoffrey C.

2016-03-01

Aquifers supporting irrigated agriculture are under stress worldwide as a result of large pumping-induced water deficits. To aid in the formulation of more sustainable management plans for such systems, we have developed a water balance approach for assessing the impact of proposed management actions and the prospects for aquifer sustainability. Application to the High Plains aquifer (HPA) in the state of Kansas in the United States reveals that practically achievable reductions in annual pumping (determining the net inflow (capture) component of the water balance. The HPA is similar to many aquifers supporting critically needed agricultural production, so the presented approach should prove of value far beyond the area of this initial application.

Impacts of turbidity on corals: The relative importance of light limitation and suspended sediments

International Nuclear Information System (INIS)

Bessell-Browne, Pia; Negri, Andrew P.; Fisher, Rebecca; Clode, Peta L.; Duckworth, Alan; Jones, Ross

2017-01-01

As part of an investigation of the effects of water quality from dredging/natural resuspension on reefs, the effects of suspended sediment concentrations (SSCs) (0, 30, 100 mg L −1 ) and light (~ 0, 1.1, 8.6 mol photons m −2 d −1 ) were examined alone and in combination, on the corals Acropora millepora, Montipora capricornis and Porites spp. over an extended (28 d) period. No effects were observed at any sediment concentrations when applied alone. All corals in the lowest light treatments lost chlorophyll a and discoloured (bleached) after a week. Coral mortality only occurred in the two lowest light treatments and was higher when simultaneously exposed to elevated SSCs. Compared to water quality data collected during large dredging programs and natural resuspension events (and in the absence of sediment deposition as a cause-effect pathway) these data suggest the light reduction associated with turbidity poses a proportionally greater risk than effects of elevated SSCs alone. - Highlights: • Exposure of corals to low light conditions results in reduced quantum yields followed by bleaching of tissue. • Suspended sediment concentrations, without a reduction in light, have no impact on coral health. • An interaction between elevated suspended sediment concentrations and reduced light result in partial mortality of corals. • Management of dredging should minimise exposure of corals to low light to avoid unnecessary stress and impacts upon health.

REDUCTIVE DEHALOGENATION OF HALOMETHANES IN IRON- AND SULFATE-REDUCING SEDIMENTS. 1. REACTIVITY PATTERN ANALYSIS

Science.gov (United States)

The incorporation of reductive transformations into environmental fate models requires the characterization of natural reductants in well-characterized sediments and aquifer materials. For this purpose, reactivity patterns (i.e., the range and relative order of reactivity) for a...

The Tunisian Jurassic aquifer in the North African Sahara aquifer system: information derived from two-dimensional seismic reflection and well logs

Science.gov (United States)

Ben Lasmar, Rafika; Guellala, Rihab; Garrach, Mohamed; Mahroug, Ali; Sarsar Naouali, Benen; Inoubli, Mohamed Hédi

2017-12-01

Southern Tunisia is an arid area where socio-economic activities are dependent on groundwater resources. The presented study aims to better characterize the Jurassic aquifer based on geological and geophysical data, with a view to develop a rational exploitation program. Well logs are used to precisely determine the position and composition of the known Jurassic aquifer layers and to identify others able to produce good quality water. The logs show that limestones, sandstones and dolomites of the Krachoua, Techout and Foum Tataouine formations are the main Jurassic aquifers. Sixty-eight seismic-reflection sections are integrated within this study. The interpolation between the interpreted sections leads to the construction of isochronous isopach maps and geoseismic sections, and their analysis finds that compressive and extensive tectonic deformations have influenced the Jurassic aquifer geometry. The Hercynian orogeny phase manifestation is remarkable in that there are several stratigraphic gaps in the Jurassic sequence. The E-W, NW-SE, and NNW-SSE accidents, reactivated in normal faults since the Permian to Lower Cretaceous epochs, have generated the structures found in the Jurassic series, such as subsided and raised blocks. Their syn-sedimentary activity has controlled the thickness and facies of these series. The Cretaceous, Tortonian and Post-Villafranchian compressions are responsible for the Jurassic-deposits folding in some localities. The highlighted tectonic and sedimentary events have an important impact on the Jurassic aquifer function by favoring the Jurassic aquifer interconnections and their connections with the Triassic and Cretaceous permeable series.

Constraints of costal aquifer functioning in a deeply antropized area through a multi-isotope fingerprinting (Recife, Brazil)

Science.gov (United States)

Petelet-Giraud, Emmanuelle; Cary, Lise; Bertrand, Guillaume; Hirata, Ricardo; Martins, Veridiana; Montenegro, Suzana; Pauwels, Hélène; Kloppmann, Wolfram; Aquilina, Luc

2014-05-01

The Metropolitan Region of Recife (RMR) went through large changes of water and land uses over the last decades due to an increasing demographic pressure (1.5 M of inhabitants). These evolutions gave rise to numerous environmental consequences, such as a dramatic decline of the water levels, groundwater salinization and contamination. This degradation of natural resources is linked to the increase of water demand that is also punctually amplified by drought periods, inducing the construction of thousands of private wells. Recife city was built on an estuarine area, at the geological limits of the two sedimentary basins of Pernambuco (north of the city) and Paraíba (south of the city) separated by a famous shear zone (the Pernambuco lineament). Tectonic and sedimentary events involved in the genesis and evolution of these basins were mainly controlled by the opening of the Atlantic Ocean leading to the deposition of cretaceous sediments which now constitute the two main exploited aquifers, the Beberibe and Cabo aquifers. These two deep aquiferous formations are topped by the unconfined Boa Viagem aquifer of quaternary sediments. It is the most directly exposed to contamination, since it is connected to mangroves, rivers, estuaries and highly urbanized areas. Both the Beberibe and Cabo aquifers contain large clay levels and are separated by a rather continuous clayed formation which seems to play a consistent role of screen and to interfere in the hydraulic connections between the three aquifers. Previous isotopic studies have shown that recharge processes are similar in the aquifers, suggesting that exchanges may occur and may be modified or amplified by overexploitation. This very complex aquifer system is studied through more than 60 water samples, including some surface water samples from the main rivers. A methodology based on multi-isotopes fingerprinting is applied, including stable isotopes of the water molecule, strontium isotopes, boron isotopes, sulfur

The origins of mercury found in the coastal aquifer of La Plana de Castellon (Eastern Spain)

International Nuclear Information System (INIS)

Lopez Gutierrez, J.; Garcia Menendez, O.; Ballesteros Navarro, B. J.

2010-01-01

Mercury was detected in the Plio-Quaternary detrital coastal aquifer of La Plana de Castellon in the second half of the 1990s in the area of Nules-Moncofar-Vall d'Uixo at concentrations of between 5 and 12 μg/L according to groundwater analysis. The most reliable hypothesis pointed originally to an anthropic origin, although no precise sources were identified. This paper describes the results of investigation undertaken by the Geological Survey of Spain (IGME) to either corroborate or reject this hypothesis. A wide sampling array was set up to collect groundwater, sediments, wastewaters and rainwater together with an exhaustive inventory of possible anthropic and natural sources of mercurial contamination. All these data were integrated into the geological and metallogenic context of the Plio-Quaternary sediments of the aquifer and the Mesozoic formations of its rim. The results have led us to arrive at a new hypothesis that points to a geogenic origin for the mercury, although is mobilisation would still appear be related to the intensive human exploitation of the groundwater in the area. (Author) 30 refs.

Geochemical Processes During Managed Aquifer Recharge With Desalinated Seawater

Science.gov (United States)

Ganot, Y.; Holtzman, R.; Weisbrod, N.; Russak, A.; Katz, Y.; Kurtzman, D.

2018-02-01

We study geochemical processes along the variably-saturated zone during managed aquifer recharge (MAR) with reverse-osmosis desalinated seawater (DSW). The DSW, post-treated at the desalination plant by calcite dissolution (remineralization) to meet the Israeli water quality standards, is recharged into the Israeli Coastal Aquifer through an infiltration pond. Water quality monitoring during two MAR events using suction cups and wells inside the pond indicates that cation exchange is the dominant subsurface reaction, driven by the high Ca2+ concentration in the post-treated DSW. Stable isotope analysis shows that the shallow groundwater composition is similar to the recharged DSW, except for enrichment of Mg2+, Na+, Ca2+, and HCO3-. A calibrated variably-saturated reactive transport model is used to predict the geochemical evolution during 50 years of MAR for two water quality scenarios: (i) post-treated DSW (current practice) and (ii) soft DSW (lacking the remineralization post-treatment process). The latter scenario was aimed to test soil-aquifer-treatment (SAT) as an alternative post-treatment technique. Both scenarios provide an enrichment of ˜2.5 mg L-1 in Mg2+ due to cation exchange, compared to practically zero Mg2+ currently found in the Israeli DSW. Simulations of the alternative SAT scenario provide Ca2+ and HCO3- remineralization due to calcite dissolution at levels that meet the Israeli standard for DSW. The simulated calcite content reduction in the sediments below the infiltration pond after 50 years of MAR was low (<1%). Our findings suggest that remineralization using SAT for DSW is a potentially sustainable practice at MAR sites overlying calcareous sandy aquifers.

impact of vegetation on flow routing and sedimentation patterns : three-dimensional modeling for a tidal marsh

NARCIS (Netherlands)

Temmerman, S.; Bouma, T.J.; De Vries, M.B.; Wang, Z.B.; Govers, G.; Herman, P.M.J.

2005-01-01

A three-dimensional hydrodynamic and sediment transport model was used to study the relative impact of (1) vegetation, (2) micro-topography, and (3) water level fluctuations on the spatial flow and sedimentation patterns in a tidal marsh landscape during single inundation events. The model

Impact of vegetation on flow routing and sedimentation patterns : three-dimensional modeling for a tidal marsh

NARCIS (Netherlands)

Temmerman, S.; Bouma, T.J.; Govers, G.; Wang, Z.B.; de Vries, M.B.; Herman, P.M.J.

2005-01-01

A three-dimensional hydrodynamic and sediment transport model was used to study the relative impact of (1) vegetation, (2) micro-topography, and (3) water level fluctuations on the spatial flow and sedimentation patterns in a tidal marsh landscape during single inundation events. The model

Long-term impacts due to sediment supply changes towards the San Francisco Bay-Delta system

Science.gov (United States)

Achete, F.; Van der Wegen, M. V.; Jaffe, B. E.

2012-12-01

The Sacramento-San Joaquin Delta and Watershed is the main source of fresh water and sediment to San Francisco Bay. Mid 19th century hydraulic mining in the catchment caused an excessive supply of sediment. After mining activities stopped, in the first part of the 20th century several hydraulic structures were built deviating fresh water and trapping sediment upstream. The main purpose of most of these structures is water storage for irrigation and/or water supply Wright and Schoellhamer (2004) show that from 1957 to 2001 the sediment load carried to San Francisco Bay has decreased by about one half. The lack of sediments may lead to a different erosion/deposition pattern in the Bay-Delta system causing problems like mud flat erosion, shift in navigation channel, land subsidence and changing habitat for endemic species. The objective of this work is to identify and quantify morphological shifts in the Bay-Delta system due to variation in fresh water and sediment supply. In this study, we couple the Delta and Bay in a unique model network (the Delta-Bay model). This coupling allows tracking of sediment from Sacramento via the Delta and Bay and through the Golden Gate, making it possible to identify erosion and deposition areas. The numerical model applied is an unstructured, process-based model (D-Flow Flexible Mesh developed by Deltares). It simulates the hydrodynamics and morphodynamics of the area on a detailed, 64000-node mesh (10-200m mesh length scale) on a timescale of minutes. The morphological impact is assessed for multiple scenarios with different input of sediment and fresh water. A statistical analysis is performed to account for uncertainty of model parameters and climate change impacts. The fresh water discharge already has a strong natural seasonal and inter-annual variation. The human impact by foreseen different water pumping strategies due to the peripheral canal will be considered. Jaffe et al. (2007) has shown that substantial morphological

Evaluation of Groundwater Impacts to Support the National Environmental Policy Act Environmental Assessment for the INL Remote-Handled Low-Level Waste Disposal Project

Energy Technology Data Exchange (ETDEWEB)

Annette Schafer; Arthur S. Rood; A. Jeffrey Sondrup

2011-12-01

The groundwater impacts have been analyzed for the proposed RH-LLW disposal facility. A four-step analysis approach was documented and applied. This assessment compared the predicted groundwater ingestion dose to the more restrictive of either the 25 mrem/yr all pathway dose performance objective, or the maximum contaminant limit performance objective. The results of this analysis indicate that the groundwater impacts for either proposed facility location are expected to be less than the performance objectives. The analysis was prepared to support the NEPA-EA for the top two ranking of the proposed RH-LLW sites. As such, site-specific conditions were incorporated for each set of results generated. These site-specific conditions were included to account for the transport of radionuclides through the vadose zone and through the aquifer at each site. Site-specific parameters included the thickness of vadose zone sediments and basalts, moisture characteristics of the sediments, and aquifer velocity. Sorption parameters (Kd) were assumed to be very conservative values used in Track II analysis of CERCLA sites at INL. Infiltration was also conservatively assumed to represent higher rates corresponding to disturbed soil conditions. The results of this analysis indicate that the groundwater impacts for either proposed facility location are expected to be less than the performance objectives.

Evaluation of Groundwater Impacts to Support the National Environmental Policy Act Environmental Assessment for the INL Remote-Handled Low-Level Waste Disposal Project

Energy Technology Data Exchange (ETDEWEB)

Annette Schafer; Arthur S. Rood; A. Jeffrey Sondrup

2011-08-01

The groundwater impacts have been analyzed for the proposed RH-LLW disposal facility. A four-step analysis approach was documented and applied. This assessment compared the predicted groundwater ingestion dose to the more restrictive of either the 25 mrem/yr all pathway dose performance objective, or the maximum contaminant limit performance objective. The results of this analysis indicate that the groundwater impacts for either proposed facility location are expected to be less than the performance objectives. The analysis was prepared to support the NEPA-EA for the top two ranking of the proposed RH-LLW sites. As such, site-specific conditions were incorporated for each set of results generated. These site-specific conditions were included to account for the transport of radionuclides through the vadose zone and through the aquifer at each site. Site-specific parameters included the thickness of vadose zone sediments and basalts, moisture characteristics of the sediments, and aquifer velocity. Sorption parameters (Kd) were assumed to be very conservative values used in Track II analysis of CERCLA sites at INL. Infiltration was also conservatively assumed to represent higher rates corresponding to disturbed soil conditions. The results of this analysis indicate that the groundwater impacts for either proposed facility location are expected to be less than the performance objectives.

Comparison of aquifer characteristics derived from local and regional aquifer tests.

Science.gov (United States)

Randolph, R.B.; Krause, R.E.; Maslia, M.L.

1985-01-01

A comparison of the aquifer parameter values obtained through the analysis of a local and a regional aquifer test involving the same area in southeast Georgia is made in order to evaluate the validity of extrapolating local aquifer-test results for use in large-scale flow simulations. Time-drawdown and time-recovery data were analyzed by using both graphical and least-squares fitting of the data to the Theis curve. Additionally, directional transmissivity, transmissivity tensor, and angle of anisotropy were computed for both tests. -from Authors Georgia drawdown transmissivity regional aquifer tests

Regional Variation of CH4 and N2 Production Processes in the Deep Aquifers of an Accretionary Prism.

Science.gov (United States)

Matsushita, Makoto; Ishikawa, Shugo; Nagai, Kazushige; Hirata, Yuichiro; Ozawa, Kunio; Mitsunobu, Satoshi; Kimura, Hiroyuki

2016-09-29

Accretionary prisms are mainly composed of ancient marine sediment scraped from the subducting oceanic plate at a convergent plate boundary. Large amounts of anaerobic groundwater and natural gas, mainly methane (CH4) and nitrogen gas (N2), are present in the deep aquifers associated with an accretionary prism; however, the origins of these gases are poorly understood. We herein revealed regional variations in CH4 and N2 production processes in deep aquifers in the accretionary prism in Southwest Japan, known as the Shimanto Belt. Stable carbon isotopic and microbiological analyses suggested that CH4 is produced through the non-biological thermal decomposition of organic matter in the deep aquifers in the coastal area near the convergent plate boundary, whereas a syntrophic consortium of hydrogen (H2)-producing fermentative bacteria and H2-utilizing methanogens contributes to the significant production of CH4 observed in deep aquifers in midland and mountainous areas associated with the accretionary prism. Our results also demonstrated that N2 production through the anaerobic oxidation of organic matter by denitrifying bacteria is particularly prevalent in deep aquifers in mountainous areas in which groundwater is affected by rainfall.

Explanation of climate and human impacts on sediment discharge change in Darwinian hydrology: Derivation of a differential equation

Science.gov (United States)

Zhang, Jianjun; Gao, Guangyao; Fu, Bojie; Zhang, Lu

2018-04-01

The assessment for impacts of climate variability and human activities on suspended sediment yield (SSY) change has long been a question of great interest. However, the sediment generation processes are sophisticated with high nonlinearity and great uncertainty, which give rise to extreme complexity for SSY change assessment in Newtonian approach. Consequently, few approaches can be simply but widely applied to decompose impacts of climatic variability and human activities on SSY change. Thus, it is an urgent need to develop advanced methods that are simple and robust. Since that the Newtonian approach is hardly achievable due to limitation of either observations or knowledge of mechanisms, there have been repeated calls to capture the hydrologic system in Darwinian approach for hydrological change prediction or explanation. As streamflow is the carrier of suspended sediment, SSY change are thus documented in changes of sediment concentrated flow and suspended sediment concentration - water discharge (C-Q) relationships. By deduced corollaries, a differential equation of sediment discharge change was derived to explicitly decompose impacts of climate variability and human activities in Darwinian hydrology. Besides, a new form of sediment rating curves was proposed and curved as C-Q relationships and probability distribution of sediment concentrated flow. River sediment flux can be revealed by this representation, which simply elucidates mechanism of SSY generation covering a range of time scales from finer than rainfall-event to long term. By the new sediment rating curves, the differential equation was partly solved using a segmentation algorithm proposed and validated in this paper, and then was submitted to water balance framework expressed by Budyko-type equation. Thus, for catchment management, hydrologists can obtain explicit explanation of how climate variation and human activities propagate through landscape and result in sediment discharge change. The

Impact of climate changes during the last 5 million years on groundwater in basement aquifers.

Science.gov (United States)

Aquilina, Luc; Vergnaud-Ayraud, Virginie; Les Landes, Antoine Armandine; Pauwels, Hélène; Davy, Philippe; Pételet-Giraud, Emmanuelle; Labasque, Thierry; Roques, Clément; Chatton, Eliot; Bour, Olivier; Ben Maamar, Sarah; Dufresne, Alexis; Khaska, Mahmoud; Le Gal La Salle, Corinne; Barbecot, Florent

2015-09-22

Climate change is thought to have major effects on groundwater resources. There is however a limited knowledge of the impacts of past climate changes such as warm or glacial periods on groundwater although marine or glacial fluids may have circulated in basements during these periods. Geochemical investigations of groundwater at shallow depth (80-400 m) in the Armorican basement (western France) revealed three major phases of evolution: (1) Mio-Pliocene transgressions led to marine water introduction in the whole rock porosity through density and then diffusion processes, (2) intensive and rapid recharge after the glacial maximum down to several hundred meters depths, (3) a present-day regime of groundwater circulation limited to shallow depth. This work identifies important constraints regarding the mechanisms responsible for both marine and glacial fluid migrations and their preservation within a basement. It defines the first clear time scales of these processes and thus provides a unique case for understanding the effects of climate changes on hydrogeology in basements. It reveals that glacial water is supplied in significant amounts to deep aquifers even in permafrosted zones. It also emphasizes the vulnerability of modern groundwater hydrosystems to climate change as groundwater active aquifers is restricted to shallow depths.

Modeling the impact of climate change on watershed discharge and sediment yield in the black soil region, northeastern China

Science.gov (United States)

Li, Zhiying; Fang, Haiyan

2017-09-01

Climate change is expected to impact discharge and sediment yield in watersheds. The purpose of this paper is to assess the potential impacts of climate change on water discharge and sediment yield for the Yi'an watershed of the black soil region, northeastern China, based on the newly released Representative Concentration Pathways (RCPs) during 2071-2099. For this purpose, the TETIS model was implemented to simulate the hydrological and sedimentological responses to climate change. The model calibration (1971-1977) and validation (1978-1987) performances were rated as satisfactory. The modeling results for the four RCP scenarios relative to the control scenario under the same land use configuration indicated an increase in discharge of 16.3% (RCP 2.6), 14.3% (RCP 4.5), 36.7% (RCP 6.0) and 71.4% (RCP 8.5) and an increase in the sediment yield of 16.5% (RCP 2.6), 32.4% (RCP 4.5), 81.8% (RCP 6.0) and 170% (RCP 8.5). This implies that the negative impact of climate change on sediment yield is generally greater than that on discharge. At the monthly scale, both discharge and sediment yield increased dramatically in April to June and August to September. A more vigorous hydrological cycle and an increase in high values of sediment yield are also expected. These changes in annual discharge and sediment yield were closely linked with changes in precipitation, whereas monthly changes in late spring and autumn were mainly related to temperature. This study highlights the possible adverse impact of climate change on discharge and sediment yield in the black soil region of northeastern China and could provide scientific basis for adaptive management.

Impact of pre-treatment technologies on soil aquifer treatment

Directory of Open Access Journals (Sweden)

A. Besançon

2017-03-01

Full Text Available This study investigates the impact of pre-treatment options on the performances of soil columns simulating soil aquifer treatment (SAT. For this purpose a conventional activated sludge (CAS process, a membrane bioreactor (MBR and vertical flow reed beds were used as single units or in combination before SAT. The influent and effluent from each treatment train were monitored over three successive 6-month periods, corresponding to changes in the operational conditions of the MBR and CAS units from 6 days' sludge retention time (SRT to 12 and 20 days. All the columns acted as efficient polishing steps for solids and bacteria. The column receiving effluent from the CAS system running at 6 days' SRT also presented high total nitrogen and total phosphorus removals, but this column was also associated with the lowest infiltration rates over that period. While the quality of the effluent from the column following the CAS process increased over 18 months of operation, the effluent quality of the columns receiving MBR effluent degraded. No correlations were found between variations in SRT of the MBR and CAS processes and the columns' performances. Overall, all columns, except the one receiving CAS effluent, underwent a reduction in infiltration rate over 18 months.

Impacts of tracked vehicles on sediment from a desert soil

Science.gov (United States)

Erek H. Fuchs; Karl M. Wood; Tim L. Jones; Brent Racher

2003-01-01

Off-road military vehicle traffic is a major consideration in the management of military lands. The objective of this study was to determine the impacts of military tracked M1A1 heavy combat tank vehicles on sediment loss from runoff, surface plant cover, and surface microtopography in a desert military training environment. A randomized block design was used which had...

Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

Science.gov (United States)

Izbicki, John A.; Petersen, Christen E.; Glotzbach, Kenneth J.; Metzger, Loren F.; Christensen, Allen H.; Smith, Gregory A.; O'Leary, David R.; Fram, Miranda S.; Joseph, Trevor; Shannon, Heather

2010-01-01

About 1.02 x 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94-137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 x 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with freechlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction

Environment tracers application to groundwater circulation assessment in an alluvial aquifer in Central Italy

Science.gov (United States)

Sappa, Giuseppe; Barbieri, Maurizio; Vitale, Stefania

2017-04-01

Groundwater vulnerability assessment is an important tool in order to plan any groundwater protection strategy. The aim of this study is to experiment a specific approach to give a conceptual model about groundwater circulation characterization. This approach has been applied to a suspected contaminated site in a large alluvial plan, made of sediments coming from weathered volcanic rocks, laying on marine sediments, where more than thirty years ago had been built a very important urban waste solid landfill. In referring to this case history it has been pointed out the importance of natural chemical interaction between ground water and rock mass, especially when pyroclastic origin sediments are involved. The landfill had been isolated from the surrounding environment, especially to protect aquifers, by a waterproof diaphragm This land is characterised by intensive agricultural and industrial activities (oil refineries, medical waste incinerators, concrete production, tar factory). The study will highlight the importance of environmental tracers which provide information about the flow and mixing processes of water coming from different sources. They are also useful to point out directions of groundwater flow and to determine origin Environmental tracers are natural chemical and isotopic substances that can be measured in groundwater and used to understand hydrologic properties of aquifers. They may be input into the hydrological system from the atmosphere at recharge and/or are added/lost/exchanged inherently as waters flow over and through materials. Variations in their chemical abundances and isotopic compositions can be used as tracers to determine sources (provenance), pathways (of reaction or interaction) and also timescales (dating) of environmental processes. In combination with these, the basic idea is to use. In this case enviromental tracers have been integrated by temperature and electric conductivity logs, to better investigate different levels of faster

Modelling studies for influence factors of gas bubble in compressed air energy storage in aquifers

International Nuclear Information System (INIS)

Guo, Chaobin; Zhang, Keni; Li, Cai; Wang, Xiaoyu

2016-01-01

CAES (Compressed air energy storage) is credited with its potential ability for large-scale energy storage. Generally, it is more convenient using deep aquifers than employing underground caverns for energy storage, because of extensive presence of aquifers. During the first stage in a typical process of CAESA (compressed air energy storage in aquifers), a large amount of compressed air is injected into the target aquifer to develop an initial space (a gas bubble) for energy storage. In this study, numerical simulations were conducted to investigate the influence of aquifer's permeability, geological structure and operation parameters on the formation of gas bubble and the sustainability for the later cycling operation. The SCT (system cycle times) was designed as a parameter to evaluate the reservoir performance and the effect of operation parameters. Simulation results for pressure and gas saturation results of basic model confirm the feasibility of compressed air energy storage in aquifers. The results of different permeability cases show that, for a certain scale of CAESA system, there is an optimum permeability range for a candidate aquifer. An aquifer within this permeability range will not only satisfy the injectivity requirement but also have the best energy efficiency. Structural impact analysis indicates that the anticline structure has the best performance to hold the bubble under the same daily cycling schedule with the same initial injected air mass. In addition, our results indicate that the SCT shows a logarithmic growth as the injected air mass increase. During the formation of gas bubble, compressed air should be injected into aquifers with moderate rate and the injection can be done in several stages with different injection rate to avoid onset pressure. - Highlights: • Impact of permeability, geological structure, operation parameters was investigated. • With certain air production rate, an optimum permeability exists for performance. �

Quantifying trail erosion and stream sedimentation with sediment tracers

Science.gov (United States)

Mark S. Riedel

2006-01-01

Abstract--The impacts of forest disturbance and roads on stream sedimentation have been rigorously investigated and documented. While historical research on turbidity and suspended sediments has been thorough, studies of stream bed sedimentation have typically relied on semi-quantitative measures such as embeddedness or marginal pool depth. To directly quantify the...

Chlorine isotope investigation of natural attenuation of trichloroethene in an aerobic aquifer

International Nuclear Information System (INIS)

Sturchio, N.C.; Heraty, L.J.; Huang, L.; Holt, B.D.; Abrajano, T.A. Jr.; Clausen, J.L.

1998-01-01

Natural attenuation of chlorinated aliphatic hydrocarbons (CAHs) can be an important mechanism for groundwater remediation. It is difficult to determine the effectiveness of natural CAH attenuation from chemical analyses of groundwater samples because mixing, dispersion, and secondary reactions can mask the chemical evidence of attenuation. In this paper, the authors explore the application of stable chlorine isotope ratio measurements as a new tool for evaluating natural attenuation of CAHs. They report stable isotope ratios of chlorine in both trichloroethene (TCE) and inorganic chloride in groundwater from an aerobic aquifer beneath an extensively contaminated industrial site, the Paducah Gaseous Diffusion Plant in western Kentucky. Variations in the concentrations and chlorine isotope ratios of TCE and chloride in the groundwater are consistent with those expected from natural attenuation. These data support a model in which partial TCE degradation occurred in relatively impermeable, clay-rich sediments above the aquifer, and little or no further degradation of TCE occurred within the aquifer. A record of changing conditions within the TCE source area can be inferred from the spatial variation of chlorine isotope ratios for TCE and chloride within the plume

Hydrology of the Claiborne aquifer and interconnection with the Upper Floridan aquifer in southwest Georgia

Science.gov (United States)

Gordon, Debbie W.; Gonthier, Gerard

2017-04-24

The U.S. Geological Survey conducted a study, in cooperation with the Georgia Environmental Protection Division, to define the hydrologic properties of the Claiborne aquifer and evaluate its connection with the Upper Floridan aquifer in southwest Georgia. The effort involved collecting and compiling hydrologic data from the aquifer in subarea 4 of southwestern Georgia. Data collected for this study include borehole geophysical logs in 7 wells, and two 72-hour aquifer tests to determine aquifer properties.The top of the Claiborne aquifer extends from an altitude of about 200 feet above the North American Vertical Datum of 1988 (NAVD 88) in Terrell County to 402 feet below NAVD 88 in Decatur County, Georgia. The base of the aquifer extends from an altitude of about 60 feet above NAVD 88 in eastern Sumter County to about 750 feet below NAVD 88 in Decatur County. Aquifer thickness ranges from about 70 feet in eastern Early County to 400 feet in Decatur County.The transmissivity of the Claiborne aquifer, determined from two 72-hour aquifer tests, was estimated to be 1,500 and 700 feet squared per day in Mitchell and Early Counties, respectively. The storage coefficient was estimated to be 0.0006 and 0.0004 for the same sites, respectively. Aquifer test data from Mitchell County indicate a small amount of leakage occurred during the test. Groundwater-flow models suggest that the source of the leakage was the underlying Clayton aquifer, which produced about 2.5 feet of drawdown in response to pumping in the Claiborne aquifer. The vertical hydraulic conductivity of the confining unit between the Claiborne and Clayton aquifers was simulated to be about 0.02 foot per day.Results from the 72-hour aquifer tests run for this study indicated no interconnection between the Claiborne and overlying Upper Floridan aquifers at the two test sites. Additional data are needed to monitor the effects that increased withdrawals from the Claiborne aquifer may have on future water resources.

Sediment measurement and transport modeling: impact of riparian and filter strip buffers.

Science.gov (United States)

Moriasi, Daniel N; Steiner, Jean L; Arnold, Jeffrey G

2011-01-01

Well-calibrated models are cost-effective tools to quantify environmental benefits of conservation practices, but lack of data for parameterization and evaluation remains a weakness to modeling. Research was conducted in southwestern Oklahoma within the Cobb Creek subwatershed (CCSW) to develop cost-effective methods to collect stream channel parameterization and evaluation data for modeling in watersheds with sparse data. Specifically, (i) simple stream channel observations obtained by rapid geomorphic assessment (RGA) were used to parameterize the Soil and Water Assessment Tool (SWAT) model stream channel variables before calibrating SWAT for streamflow and sediment, and (ii) average annual reservoir sedimentation rate, measured at the Crowder Lake using the acoustic profiling system (APS), was used to cross-check Crowder Lake sediment accumulation rate simulated by SWAT. Additionally, the calibrated and cross-checked SWAT model was used to simulate impacts of riparian forest buffer (RF) and bermudagrass [ (L.) Pers.] filter strip buffer (BFS) on sediment yield and concentration in the CCSW. The measured average annual sedimentation rate was between 1.7 and 3.5 t ha yr compared with simulated sediment rate of 2.4 t ha yr Application of BFS across cropped fields resulted in a 72% reduction of sediment delivery to the stream, while the RF and the combined RF and BFS reduced the suspended sediment concentration at the CCSW outlet by 68 and 73%, respectively. Effective riparian practices have potential to increase reservoir life. These results indicate promise for using the RGA and APS methods to obtain data to improve water quality simulations in ungauged watersheds. American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.

An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

International Nuclear Information System (INIS)

Jensen, E.J.

1987-10-01

During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides

The occurrence and potential ecological risk assessment of bauxite mine-impacted water and sediments in Kuantan, Pahang,Malaysia.

Science.gov (United States)

Kusin, Faradiella Mohd; Rahman, Muhammad Syazwan Abd; Madzin, Zafira; Jusop, Shamshuddin; Mohamat-Yusuff, Ferdaus; Ariffin, Mariani; Z, Mohd Syakirin Md

2017-01-01

Recent bauxite mining activities in the vicinity of Kuantan, Pahang, have been associated with apparent environmental quality degradation and have raised environmental concerns among the public. This study was carried out to evaluate the overall ecological impacts on water and sediment quality from the bauxite mining activities. Water and sediment samples were collected at seven sampling locations within the bauxite mining areas between June and December 2015. The water samples were analyzed for water quality index (WQI) and distribution of major and trace element geochemistry. Sediment samples were evaluated based on geochemical indices, i.e., the enrichment factor (EF) and geoaccumulation index (I geo ). Potential ecological risk index was estimated to assess the degree to which sediments of the mine-impacted areas have been contaminated with heavy metals. The results showed that WQIs of some locations were classified as slightly polluted and contained metal contents exceeding the recommended guideline values. The EFs indicated minimal to moderate enrichment of metals (Pb, Cu, Zn, Mn, As, Cd, Cr, Ni, Co, and Sr) in the sediments. I geo showed slightly to partially polluted sediments with respect to As at some locations. The potential ecological risk index (RI) showed that As posed the highest potential ecological risk with RI of 52.35-60.92 at two locations, while other locations indicated low risk. The findings from this study have demonstrated the impact of recent bauxite mining activities, which might be of importance to the local communities and relevant authorities to initiate immediate rehabilitation phase of the impacted area.

Diagnosis of the Ghiss Nekor aquifer in order to elaborate the aquifer contract

Science.gov (United States)

Baite, Wissal; Boukdir, A.; Zitouni, A.; Dahbi, S. D.; Mesmoudi, H.; Elissami, A.; Sabri, E.; Ikhmerdi, H.

2018-05-01

The Ghiss-Nekor aquifer, located in the north-east of the action area of the ABHL, plays a strategic role in the drinkable water supply of the city of Al Hoceima and of the neighboring urban areas. It also participates in the irrigation of PMH. However, this aquifer has problems such as over-exploitation and pollution. In the face of these problems, the only Solution is the establishment of a new mode of governance, which privileges the participation, the involvement and the responsibility of the actors concerned in a negotiated contractual framework, namely the aquifer contract. The purpose of this study is to diagnose the current state of the Ghiss Nekor aquifer, the hydrogeological characterization of the aquifer, the use of the waters of the aquifer, the Problem identification and the introduction of the aquifer contract, which aims at the participatory and sustainable management of underground water resources in the Ghiss- Nekor plain, to ensure sustainable development.

Microbial community evolution during simulated managed aquifer recharge in response to different biodegradable dissolved organic carbon (BDOC) concentrations.

Science.gov (United States)

Li, Dong; Alidina, Mazahirali; Ouf, Mohamed; Sharp, Jonathan O; Saikaly, Pascal; Drewes, Jörg E

2013-05-01

This study investigates the evolution of the microbial community in laboratory-scale soil columns simulating the infiltration zone of managed aquifer recharge (MAR) systems and analogous natural aquifer sediment ecosystems. Parallel systems were supplemented with either moderate (1.1 mg/L) or low (0.5 mg/L) biodegradable dissolved organic carbon (BDOC) for a period of six months during which time, spatial (1 cm, 30 cm, 60 cm, 90 cm, and 120 cm) and temporal (monthly) analyses of sediment-associated microbial community structure were analyzed. Total microbial biomass associated with sediments was positively correlated with BDOC concentration where a significant decline in BDOC was observed along the column length. Analysis of 16S rRNA genes indicated dominance by Bacteria with Archaea comprising less than 1 percent of the total community. Proteobacteria was found to be the major phylum in samples from all column depths with contributions from Betaproteobacteria, Alphaproteobacteria and Gammaproteobacteria. Microbial community structure at all the phylum, class and genus levels differed significantly at 1 cm between columns receiving moderate and low BDOC concentrations; in contrast strong similarities were observed both between parallel column systems and across samples from 30 to 120 cm depths. Samples from 1 cm depth of the low BDOC columns exhibited higher microbial diversity (expressed as Shannon Index) than those at 1 cm of moderate BDOC columns, and both increased from 5.4 to 5.9 at 1 cm depth to 6.7-8.3 at 30-120 cm depths. The microbial community structure reached steady state after 3-4 months since the initiation of the experiment, which also resulted in an improved DOC removal during the same time period. This study suggested that BDOC could significantly influence microbial community structure regarding both composition and diversity of artificial MAR systems and analogous natural aquifer sediment ecosystems. Copyright © 2013 Elsevier Ltd

Organic matter accumulation and degradation in subsurface coastal sediments: a model-based comparison of rapid sedimentation and aquifer transport

Directory of Open Access Journals (Sweden)

J. M. Holstein

2010-11-01

Full Text Available The redox succession in shallow marine sediments generally exhibits a predictable pattern. Pore water profiles from a back barrier tidal flat in the German Wadden Sea depart from the expected redox zoning. Instead, a sulfate minimum zone associated with a sulfate-methane-sulfate double interface and a distinct ammonium peak at 1.5 m below sea floor (mbsf is displayed. Such evidence for significant degradation of organic matter (OM in subsurface layers is challenging our understanding of tidal flat biogeochemistry as little is known about processes that relocate reactive OM into layers far distant from the sediment-water interface. The objectives of our model study were to identify possible mechanisms for the rapid transport of organic matter to subsurface layers that cause the reversed redox succession and to constrain several important biogeochemical control parameters. We compared two scenarios for OM transfer: rapid sedimentation and burial of OM as well as lateral advection of suspended POM. Using a diagenetic model, uncertain process parameters, in particular those connected to OM degradation and (vertical or lateral transport, are systematically calibrated using field data.

We found that both scenarios, advection and sedimentation, had solutions consistent with the observed pore water profiles. For this specific site, however, advective transport of particulate material had to be rejected since the reconstructed boundary conditions were rather improbable. In the alternative deposition set-up, model simulations suggested the deposition of the source OM about 60 yrs before cores were taken. A mean sedimentation rate of approximately 2 cm yr⁻¹ indicates substantial changes in near coast tidal flat morphology, since sea level rise is at a much lower pace. High sedimentation rates most probably reflect the progradation of flats within the study area. These or similar morphodynamic features also occur in other coastal areas

Detecting sedimentation impacts to coral reefs resulting from dredging the Port of Miami, Florida USA.

Science.gov (United States)

Miller, Margaret W; Karazsia, Jocelyn; Groves, Carolyn E; Griffin, Sean; Moore, Tom; Wilber, Pace; Gregg, Kurtis

2016-01-01

The federal channel at Port of Miami, Florida, USA, was dredged between late 2013 and early 2015 to widen and deepen the channel. Due to the limited spatial extent of impact-assessment monitoring associated with the project, the extent of the dredging impacts on surrounding coral reefs has not been well quantified. Previously published remote sensing analyses, as well as agency and anecdotal reports suggest the most severe and largest area of sedimentation occurred on a coral reef feature referred to as the Inner Reef, particularly in the sector north of the channel. A confounding regional warm-water mass bleaching event followed by a coral disease outbreak during this same time frame made the assessment of dredging-related impacts to coral reefs adjacent to the federal channel difficult but still feasible. The current study sought to better understand the sedimentation impacts that occurred in the coral reef environment surrounding Port of Miami, to distinguish those impacts from other regional events or disturbances, and provide supplemental information on impact assessment that will inform discussions on compensatory mitigation requirements. To this end, in-water field assessments conducted after the completion of dredging and a time series analysis of tagged corals photographed pre-, during, and post-dredging, are used to discern dredging-related sedimentation impacts for the Inner Reef north. Results indicate increased sediment accumulation, severe in certain times and places, and an associated biological response (e.g., higher prevalence of partial mortality of corals) extended up to 700 m from the channel, whereas project-associated monitoring was limited to 50 m from the channel. These results can contribute to more realistic prediction of areas of indirect effect from dredging projects needed to accurately evaluate proposed projects and design appropriate compliance monitoring. Dredging projects near valuable and sensitive habitats subject to local and

Detecting sedimentation impacts to coral reefs resulting from dredging the Port of Miami, Florida USA

Directory of Open Access Journals (Sweden)

Margaret W. Miller

2016-11-01

Full Text Available The federal channel at Port of Miami, Florida, USA, was dredged between late 2013 and early 2015 to widen and deepen the channel. Due to the limited spatial extent of impact-assessment monitoring associated with the project, the extent of the dredging impacts on surrounding coral reefs has not been well quantified. Previously published remote sensing analyses, as well as agency and anecdotal reports suggest the most severe and largest area of sedimentation occurred on a coral reef feature referred to as the Inner Reef, particularly in the sector north of the channel. A confounding regional warm-water mass bleaching event followed by a coral disease outbreak during this same time frame made the assessment of dredging-related impacts to coral reefs adjacent to the federal channel difficult but still feasible. The current study sought to better understand the sedimentation impacts that occurred in the coral reef environment surrounding Port of Miami, to distinguish those impacts from other regional events or disturbances, and provide supplemental information on impact assessment that will inform discussions on compensatory mitigation requirements. To this end, in-water field assessments conducted after the completion of dredging and a time series analysis of tagged corals photographed pre-, during, and post-dredging, are used to discern dredging-related sedimentation impacts for the Inner Reef north. Results indicate increased sediment accumulation, severe in certain times and places, and an associated biological response (e.g., higher prevalence of partial mortality of corals extended up to 700 m from the channel, whereas project-associated monitoring was limited to 50 m from the channel. These results can contribute to more realistic prediction of areas of indirect effect from dredging projects needed to accurately evaluate proposed projects and design appropriate compliance monitoring. Dredging projects near valuable and sensitive habitats

Runoff and sediment yield model for predicting nuclide transport in watersheds using BIOTRAN

Energy Technology Data Exchange (ETDEWEB)

Gallegos, A.F.; Wenzel, W.J.

1990-09-01

The environmental risk simulation model BIOTRAN was interfaced with a series of new subroutines (RUNOFF, GEOFLX, EROSON, and AQUIFER) to predict the movement of nuclides, elements, and pertinent chemical compounds in association with sediments through lateral and channel flow of runoff water. In addition, the movement of water into and out of segmented portions of runoff channels was modeled to simulate the dynamics of moisture flow through specified aquifers within the watershed. The BIOTRAN soil water flux subroutine, WATFLX, was modified to interface the relationships found in the SPUR model for runoff and sediment transport into channels with the particle sorting relationships to predict radionuclide enrichment and movement in watersheds. The new subroutines were applied specifically to Mortandad Canyon within Los Alamos National Laboratory by simultaneous simulation of eight surface vegetational subdivisions and associated channel and aquifer segments of this watershed. This report focuses on descriptions of the construction and rationale for the new subroutines and on discussing both input characteristics and output relationships to known runoff events from Mortandad Canyon. Limitations of the simplified input on model behavior are also discussed. Uranium-238 was selected as the nuclide for demonstration of the model because it could be assumed to be homogeneously distributed over the watershed surface. 22 refs., 18 figs., 9 tabs.

Hydrology of aquifer systems in the Memphis area, Tennessee

Science.gov (United States)

Criner, James H.; Sun, P-C. P.; Nyman, Dale J.

1964-01-01

The Memphis area as described in .this report comprises about 1,300 square miles of the Mississippi embayment part of the Gulf Coastal Plain. The area is underlain by as much as 3,000 feet of sediments ranging in age from Cretaceous through Quaternary. In 1960, 150 mgd (million gallons per day) of water was pumped from the principal aquifers. Municipal pumpage accounted for almost half of this amount, and industrial pumpage a little more than half. About 90 percent of the water used in the area is derived from the '500-foot' sand, and most of the remainder is from the ?400-foot' sand; both sands are of Eocene age. A small amount of water for domestic use is pumped from the terrace deposits of Pliocene and Pleistocene age. Both the '500-foot' and the '1,400-foot' sands are artesian aquifers except in the southeastern part of the area; there the water level in wells in the '500-foot' sand is now below the overlying confining clay. Water levels in both aquifers have declined almost continuously since pumping began, but the rate of decline has increased rapidly since 1940. Water-level decline in the '1,400-foot' sand has been less pronounced since 1956. The cones of depression in both aquifers have expanded and deepened as a result of the annual increases in pumping, and an increase in hydraulic gradients has induced a greater flow of water into the area. Approximately 135 mgd entered the Memphis area through the '500-foot' sand aquifer in 1960, and, of this amount, 60 mgd originated as inflow from the east and about 75 mgd was derived from leakage from the terrace deposits, from the north, south, and west and from other sources. Of the water entering the '1,400-foot' sand, about 5 mgd was inflow from the east, and about half that amount was from each of the north, south, and west directions. The average rate of movement of water outside the area of heavy withdrawals is about 70 feet per year in the '500-foot' sand and about 40 feet per year in the '1,400-foot' sand

Hydraulic properties of groundwater systems in the saprolite and sediments of the wheatbelt, Western Australia

Science.gov (United States)

George, Richard J.

1992-01-01

Hydraulic properties of deeply weathered basement rocks and variably weathered sedimentary materials were measured by pumping and slug-test methods. Results from over 200 bores in 13 catchments, and eight pumping-test sites across the eastern and central wheatbelt of Western Australia were analysed. Measurements were made in each of the major lithological units, and emphasis placed on a ubiquitous basal saprolite aquifer. Comparisons were made between alternative drilling and analytical procedures to determine the most appropriate methods of investigation. Aquifers with an average hydraulic conductivity of 0.55 m day -1 occur in variably weathered Cainozoic sediments and poorly weathered saprolite grits (0.57 m day -1). These aquifers are separated by an aquitard (0.065 m day -1) comprising the mottled and pallid zones of the deeply weathered profile. Locally higher values of hydraulic conductivity occur in the saprolite aquifer, although after prolonged periods of pumping the values decrease until they are similar to those obtained from the slug-test methods. Hydraulic conductivities measured in bores drilled with rotary auger rigs were approximately an order of magnitude lower than those measured in the same material with bores drilled by the rotary air-blast method. Wheatbelt aquifers range from predominantly unconfined (Cainozoic sediments), to confined (saprolite grit aquifer). The poorly weathered saprolite grit aquifer has moderate to high transmissivities (4-50 m 2 day -1) and is capable of producing from less than 5 to over 230 kl day -1 of ground water, which is often of a quality suitable for livestock. Yields are influenced by the variability in the permeability of isovolumetrically weathered materials from which the aquifer is derived. The overlying aquitard has a low transmissivity (< 1 m 2 day -1), especially when deeply weathered, indurated and silicified. The transmissivity of the variably weathered sedimentary materials ranges from less than 0.5 m

Evaluating chemical extraction techniques for the determination of uranium oxidation state in reduced aquifer sediments

Science.gov (United States)

Stoliker, Deborah L.; Campbell, Kate M.; Fox, Patricia M.; Singer, David M.; Kaviani, Nazila; Carey, Minna; Peck, Nicole E.; Barger, John R.; Kent, Douglas B.; Davis, James A.

2013-01-01

Extraction techniques utilizing high pH and (bi)carbonate concentrations were evaluated for their efficacy in determining the oxidation state of uranium (U) in reduced sediments collected from Rifle, CO. Differences in dissolved concentrations between oxic and anoxic extractions have been proposed as a means to quantify the U(VI) and U(IV) content of sediments. An additional step was added to anoxic extractions using a strong anion exchange resin to separate dissolved U(IV) and U(VI). X-ray spectroscopy showed that U(IV) in the sediments was present as polymerized precipitates similar to uraninite and/or less ordered U(IV), referred to as non-uraninite U(IV) species associated with biomass (NUSAB). Extractions of sediment containing both uraninite and NUSAB displayed higher dissolved uranium concentrations under oxic than anoxic conditions while extractions of sediment dominated by NUSAB resulted in identical dissolved U concentrations. Dissolved U(IV) was rapidly oxidized under anoxic conditions in all experiments. Uraninite reacted minimally under anoxic conditions but thermodynamic calculations show that its propensity to oxidize is sensitive to solution chemistry and sediment mineralogy. A universal method for quantification of U(IV) and U(VI) in sediments has not yet been developed but the chemical extractions, when combined with solid-phase characterization, have a narrow range of applicability for sediments without U(VI).

Secondary environmental impacts of remedial alternatives for sediment contaminated with hydrophobic organic contaminants.

Science.gov (United States)

Choi, Yongju; Thompson, Jay M; Lin, Diana; Cho, Yeo-Myoung; Ismail, Niveen S; Hsieh, Ching-Hong; Luthy, Richard G

2016-03-05

This study evaluates secondary environmental impacts of various remedial alternatives for sediment contaminated with hydrophobic organic contaminants using life cycle assessment (LCA). Three alternatives including two conventional methods, dredge-and-fill and capping, and an innovative sediment treatment technique, in-situ activated carbon (AC) amendment, are compared for secondary environmental impacts by a case study for a site at Hunters Point Shipyard, San Francisco, CA. The LCA results show that capping generates substantially smaller impacts than dredge-and-fill and in-situ amendment using coal-based virgin AC. The secondary impacts from in-situ AC amendment can be reduced effectively by using recycled or wood-based virgin AC as production of these materials causes much smaller impacts than coal-based virgin AC. The secondary environmental impacts are highly sensitive to the dredged amount and the distance to a disposal site for dredging, the capping thickness and the distance to the cap materials for capping, and the AC dose for in-situ AC amendment. Based on the analysis, this study identifies strategies to minimize secondary impacts caused by different remediation activities: optimize the dredged amount, the capping thickness, or the AC dose by extensive site assessments, obtain source materials from local sites, and use recycled or bio-based AC. Copyright © 2015 Elsevier B.V. All rights reserved.

Surveying the anthropogenic impact of the Moldau river sediments and nearby soils using magnetic susceptibility

Czech Academy of Sciences Publication Activity Database

Knab, M.; Hoffmann, V.; Petrovský, Eduard; Kapička, Aleš; Jordanova, N.; Appel, E.

2006-01-01

Roč. 49, č. 4 (2006), s. 527-535 ISSN 0943-0105 Institutional research plan: CEZ:AV0Z3012916 Keywords : Moldau river sediments * magnetic susceptibility * anthropogenic impact Subject RIV: DE - Earth Magnetism, Geodesy, Geography Impact factor: 0.610, year: 2006

Ultramafic-derived arsenic in a fractured bedrock aquifer

International Nuclear Information System (INIS)

Ryan, Peter C.; Kim, Jonathan; Wall, Andrew J.; Moen, Jonathan C.; Corenthal, Lilly G.; Chow, Daniel R.; Sullivan, Colleen M.; Bright, Kevin S.

2011-01-01

Highlights: → Arsenic is elevated in groundwater from a fractured bedrock aquifer system in northern Vermont, USA. → The arsenic source is serpentinized ultramafic rock. → Antigorite, magnetite (MgCO 3 ) and magnetite (Fe 3 O 4 ) appear to be the main mineralogical hosts of arsenic in the ultramafic rock. → Arsenic appears to be introduced to the ultramafic rock when As-bearing fluids are driven out of sediments during subduction. → The occurrence of serpentinized ultramafic rocks in many orogenic belts suggests that similar arsenic anomalies may occur in geologically-similar terranes globally. - Abstract: In the fractured bedrock aquifer of northern Vermont, USA, As concentrations in groundwater range from 3 ) with lesser amounts in magnetite (Fe 3 O 4 ). Hydrochemistry of monitoring wells drilled into fractured ultramafic rock in a groundwater recharge area with no anthropogenic As source reveals above background As (2-9 μg/L) and an Mg-HCO 3 hydrochemical signature that reflects dissolution of antigorite and magnesite, confirming that As in groundwater can be derived from ultramafic rock dissolution. Arsenic mobility in groundwater affected by ultramafic rock dissolution may be enhanced by alkaline pH values and relatively high HCO 3 - concentrations.

Characterizing the Impact of River Barrage Construction on Stream-Aquifer Interactions, Korea

Directory of Open Access Journals (Sweden)

Yun-Yeong Oh

2016-04-01

Full Text Available This study investigated changes in stream–aquifer interactions during the period shortly after the construction of the Changnyeong-Haman River barrage (CHRB on the Nakdong River in South Korea. The hydraulic diffusivity (α and river resistance (R values at the semipervious stream–aquifer interface were estimated by using a one-dimensional (1-D analytical solution with Fourier transform (FT. Prior to the application of the 1-D analytical solution, the noise effects on the groundwater levels were removed by using fast Fourier transform and low-pass filtering techniques. Sinusoidal variation of the river stages was applied to the 1-D analytical solution. For the study period, the R values showed a decreasing trend, while the α values showed an increasing trend, and results showed that the average of the median values of flood duration times (td and flood amplitudes were reduced to 78% and 59%, respectively. Moreover, the ratio of flood peak time to td demonstrated a decreasing tendency after the construction of the CHRB. Hence, it is concluded that the dredging and increase of river-water storage due to CHRB construction enhanced stream–aquifer interactions during the period shortly after the construction of the CHRB.

Investigation of ground water aquifer at Tlogorejo Site Karangawen District, Demak Regency, Central Java

International Nuclear Information System (INIS)

Lilik Subiantoro; Priyo Sularto; Slamet Sudarto

2009-01-01

Demak is one of regency are placed at north beach central Java. Some part of this area especially Tlogorejo site Karangawen have the problem of fresh water availability. Conditions of insufficient Standard Water have been recognized in some part of the region, those are Karangrowo area, Undaan District. The problem of clean water in this area is caused by sea water trapped in sedimentary material during sedimentation process, so the trapped ground water character is brine or brackish. One of the alternatives to overcome water problem is election or delineated of the prospect area for exploiting of ground water. Referring to those problems Pusbang Geologi Nuklir BATAN means to conduct investigation of ground water in some location which has problem of clean water. The ground investigation activity is to get information about the geology, hydrogeology and sub surface geophysical characteristic, which is needed to identification of ground water aquifer. To obtain those targets, conducted by topographic measurement in 1:5000 scale maps, measurement of soil radioactivity, geology and hydrogeology mapping, geo-electrical 2-D image measurement Base on observation, analysis, evaluation and discussion was identified the existence of potential confined aquifer that happened at the layer sand that is trapped in the in impermeable layer of clay, which is potential for confined aquifer. Potency of aquifer with the best condition from bad, there are placed on geophysical measurement is ''Sand Aquifer Layer-1'' are located at RB 1 (TLG-5), RB 2 (TLG-4) and RB 3 (TLG-22). Physical characterized of aquifer: resistivity 22-46 Ωm, the depth of surface water 110 to 146 meter. (author)

Acid groundwater in an anoxic aquifer: Reactive transport modelling of buffering processes

International Nuclear Information System (INIS)

Franken, Gudrun; Postma, Dieke; Duijnisveld, Wilhelmus H.M.; Boettcher, Juergen; Molson, John

2009-01-01

The acidification of groundwater, due to acid rain, was investigated in a Quaternary sandy aquifer in the Fuhrberger Feld, near Hannover, Germany. The groundwater, recharged through an area covered by a coniferous forest, had a pH in the range 4-5 down to a depth of 5 m. The evolution in groundwater chemistry along the flow path was investigated in a transect of multisamplers. A 2D groundwater flow model was established delineating the groundwater flow field and a groundwater flow velocity of around 80 m/a along the flow path was derived. Speciation calculations showed the groundwater to be close to equilibrium with the mineral jurbanite (AlOHSO 4 ) over the pH range 4.0-6.5. This suggests an accumulation of acid rain derived SO 4 2- in the aquifer sediment during the decades with high atmospheric S deposition. The groundwater has a pH of around 4.5 in the upstream part of the flow path increasing to near 6 further downstream. 1D reactive transport modelling, using PHREEQC, was used to analyze different combinations of buffering processes. The first model contains ion exchange in combination with jurbanite dissolution. At the ion exchange front Al 3+ is adsorbed leading to the dissolution of jurbanite and an increase in pH. Comparison with field data showed that the simulated increases in pH and alkalinity are much lower than observed in the field. The second model includes organic matter degradation. In addition to ion exchange and jurbanite dissolution, the model included the reduction of SO 4 2- and Fe-oxides as well as the precipitation of Fe sulfide. This model matches the field data well and illustrates the importance of redox processes for pH buffering in the Fuhrberg aquifer. The current progress of the acidification front is about 4 m/a. This corresponds to an average value of 150 a of acid input, which covers large historical variations. Remediation is expected to take the same time span because it requires desorption and neutralization of adsorbed Al 3

Impact of lateral flow on the transition from connected to disconnected stream-aquifer systems

Science.gov (United States)

Xian, Yang; Jin, Menggui; Liu, Yanfeng; Si, Aonan

2017-05-01

Understanding the mechanisms by which stream water infiltrates through streambeds to recharge groundwater systems is essential to sustainable management of scarce water resources in arid and semi-arid areas. An inverted water table (IWT) can develop under a stream in response to the desaturation between the stream and underlying aquifer as the system changes from a connected to disconnected status. However, previous studies have suggested that the IWT can only occur at the bottom of a low permeability streambed in which only the vertical flow between the stream and groundwater during disconnection was assumed. In the present study, numerical simulations revealed that the lateral flow induced by capillarity or heterogeneity also plays an essential role on interactions between streams and aquifers. Three pathways were identified for the transition from connection to disconnection in homogenous systems; notably, the lowest point of an IWT can develop not only at the bottom of the streambed but also within the streambed or the aquifer in response to the initial desaturation at, above, or below the interface between the streambed and aquifer (IBSA), respectively. A sensitivity analysis indicated that in wide streams, the lowest point of an IWT only occurs at the bottom of the streambed; however, for a stream half width of 1 m above a 6 m thick sandy loam streambed, the lowest point occurs in the streambed as stream depth is less than 0.5 m. This critical stream depth increases with streambed thickness and decreases with stream width. Thus, in narrow streams the lowest point can also develop in a thick streambed under a shallow stream. In narrow streams, the lowest point also forms in the aquifer if the ratio of the hydraulic conductivity of the streambed to that of the aquifer is greater than the ratio of the streambed thickness to the sum of the stream depth and the streambed thickness; correspondingly, the streambed is thin but relatively permeable and the stream is

The Impact of a Check Dam on Groundwater Recharge and Sedimentation in an Ephemeral Stream

Directory of Open Access Journals (Sweden)

Hakan Djuma

2017-10-01

Full Text Available Despite the widespread presence of groundwater recharge check dams, there are few studies that quantify their functionality. The objectives of this study are (i to assess groundwater recharge in an ephemeral river with and without a check dam and (ii to assess sediment build-up in the check-dam reservoir. Field campaigns were carried out to measure water flow, water depth, and check-dam topography to establish water volume, evaporation, outflow, and recharge relations, as well as sediment build-up. To quantify the groundwater recharge, a water-balance approach was applied at two locations: at the check dam reservoir area and at an 11 km long natural stretch of the river upstream. Prediction intervals were computed to assess the uncertainties of the results. During the four years of operation, the check dam (storage capacity of 25,000 m3 recharged the aquifer with an average of 3.1 million m3 of the 10.4 million m3 year−1 of streamflow (30%. The lower and upper uncertainty limits of the check dam recharge were 0.1 and 9.6 million m3 year−1, respectively. Recharge from the upstream stretch was 1.5 million m3 year−1. These results indicate that check dams are valuable structures for increasing groundwater resources in semi-arid regions.

The Transboundary Aquifer Management Challenge: Linking Landscape Patterns and Groundwater Nitrate Concentrations in the Abbotsford-Sumas Aquifer, USA/Canada

Science.gov (United States)

Gallagher, T.; Gergel, S. E.

2015-12-01

Changes in land use and landscape pattern can have an array of impacts on aquatic systems, including impacts which span international waters and borders. Globally, agricultural land use patterns and practices are among the factors responsible for elevated nitrate concentrations in groundwater aquifers. Coordination of landscape monitoring across trans-boundary aquifers is needed to monitor and address contamination issues as landscape patterns can vary widely among different political jurisdictions. Landscape indicators, which quantify the amount and arrangement of land cover (such as proportion and abundance of land cover types), are one such way to improve our understanding of cross-border aquatic system interactions. In Western North America, the Abbotsford-Sumas Aquifer (ASA) spans the US-Canada border and provides drinking water for over 100,000 people. Intensive agriculture combined with high precipitation and well-drained soils make this aquifer susceptible to nitrate leaching. To understand how landscape patterns influence nitrate concentrations, we ask: Which landscape indicators correlate most strongly with elevated nitrate concentrations? A seamless cross-border land cover mosaic was created by harmonizing a variety of US and Canadian geodata. Auxiliary high spatial resolution imagery (e.g., 5m RapidEye and historical Google Earth) were used to quantify fine-scale landscape features (such as number of farm field renovations) with suspected mechanistic links to nitrate sources. We examined groundwater nitrate concentrations in shallow wells (screens Environment Canada. Surrounding each well, terrestrial zones of influence (aligned with the directional flow of groundwater) were delineated within which landscape patterns were characterized. Multiple regression was used to compare the strength of relationships between land use practices and nitrate concentrations. Preliminary results show strong positive correlations between area of raspberry renovations and

The Surface of Venus is Saturated With Ancient Impact Structures, and its Plains are Marine Sediments

Science.gov (United States)

Hamilton, W. B.

2009-05-01

Conventional interpretations of Venus are forced to fit dubious pre-Magellan conjectures that the planet is as active internally as Earth and preserves no ancient surface features. Plate tectonics obviously does not operate, so it is commonly assumed that the surface must record other endogenic processes, mostly unique to Venus. Imaginative systems of hundreds of tiny to huge rising and sinking plumes and diapirs are invoked. That much of the surface in fact is saturated with overlapping large circular depressions with the morphology of impact structures is obscured by postulating plume origins for selected structures and disregarding the rest. Typical structures are rimmed circular depressions, often multiring, with lobate debris aprons; central peaks are common. Marine-sedimentation features are overlooked because dogma deems the plains to be basalt flows despite their lack of source volcanoes and fissures. The unearthly close correlation between geoid and topography at long to moderate wavelengths requires, in conventional terms, dynamic maintenance of topography by up and down plumes of long-sustained precise shapes and buoyancy. A venusian upper mantle much stronger than that of Earth, because it is cooler or poorer in volatiles, is not considered. (The unearthly large so-called volcanoes and tessera plateaus often are related to rimmed circular depressions and likely are products of impact fluidization and melting.) Plains-saturating impact structures (mostly more obvious in altimetry than backscatter) with diameters of hundreds of km are superimposed as cookie-cutter bites, are variably smoothed and smeared by apparent submarine impact and erosion, and are differentially buried by sediments compacted into them. Marine- sedimentation evidence includes this compaction; long sinuous channels and distributaries with turbidite- channel characteristics and turbidite-like lobate flows (Jones and Pickering, JGSL 2003); radar-smooth surfaces and laminated aspect in

EPA Region 1 Sole Source Aquifers

Science.gov (United States)

This coverage contains boundaries of EPA-approved sole source aquifers. Sole source aquifers are defined as an aquifer designated as the sole or principal source of drinking water for a given aquifer service area; that is, an aquifer which is needed to supply 50% or more of the drinking water for the area and for which there are no reasonable alternative sources should the aquifer become contaminated.The aquifers were defined by a EPA hydrogeologist. Aquifer boundaries were then drafted by EPA onto 1:24000 USGS quadrangles. For the coastal sole source aquifers the shoreline as it appeared on the quadrangle was used as a boundary. Delineated boundaries were then digitized into ARC/INFO.

Hydrogeophysics and geochemistry reveal heterogeneity and water quality improvements in aquifer recharge and recovery (ARR) (Invited)

Science.gov (United States)

Parsekian, A.; Regnery, J.; Wing, A.; Knight, R. J.; Drewes, J. E.

2013-12-01

Aquifer recharge and recover (ARR) is the process of infiltrating water into the ground for storage and withdrawal through wells at a later time. Two significant challenges faced during the design of ARR systems are 1) evaluating aquifer heterogeneity and 2) understanding the rock fluid interactions; these knowledge gaps may have profound impacts on the volume of recoverable water and the improvement in water quality in comparison with the source-water. Our objective in this research is to leverage the advantages of hydrogeophysical measurements and geochemical sampling to reveal the properties of an aquifer through which ARR water travels with the goal of informing current operations and future design decisions. Combined geophysical and geochemical investigations reveal subsurface heterogeneity, indicate possible flow paths though the aquifer and quantify specific reductions in contaminant concentrations. Ground penetrating radar (GPR), electromagnetic induction (EMI) and electrical resistivity tomography (ERT) were used to image the subsurface throughout two key infiltration/extraction areas of an ARR site in Colorado, USA. The most valuable results came from 2.5D ERT revealing the structural patterns and suggesting the distribution of textural composition of unconsolidated sediments. Geochemical measurements on transects intersecting the geophysical measurements resolved bulk parameters (i.e. total organic carbon, cations, anions) and trace organic contaminants (e.g. trace organic compounds) and were also used to estimate mixing and water travel times and assess the performance of the ARR site regarding water quality and quantity. Our results indicate that the subsurface is highly heterogeneous at our study site and that the coarse-grained sedimentary units, acting as the best conduit for transporting water, are likely discontinuous. The electrical resistivity measurements indicate certain areas of the infiltration basins may have good hydraulic connections to

Drought risk and climate change impacts on Querença-Silves aquifer and Odelouca watershed (Algarve)

OpenAIRE

Novo, M. E.; Oliveira, L. G. S.

2014-01-01

The evolution aquifer recharge and runoff in Querença-Silves aquifer and Odelouca watershed under three emissions scenarios (IS92a, SRES A2 e SRES B2), for year 2100, was calculated using BALSEQ daily water balance and a methodology developed by Oliveira et al. (2012) to generate the hydrological data required by this model. The results hint at a future drier climate regimes, with significant runoff reductions of 11 to 12% in Odelouca watershed and Querença-Silves aquifer while...

The impacts of land reclamation on suspended-sediment dynamics in Jiaozhou Bay, Qingdao, China

Science.gov (United States)

Gao, Guan Dong; Wang, Xiao Hua; Bao, Xian Wen; Song, Dehai; Lin, Xiao Pei; Qiao, Lu Lu

2018-06-01

A three-dimensional, high-resolution tidal model coupled with the UNSW sediment model (UNSW-Sed) based on Finite Volume Coastal Ocean Model (FVCOM) was set up to study the suspended-sediment dynamics and its change in Jiaozhou Bay (JZB) due to land reclamation over the period 1935 to 2008. During the past decades, a large amount of tidal flats were lost due to land reclamation. Other than modulating the tides, the tidal flats are a primary source for sediment resuspensions, leading to turbidity maxima nearshore. The tidal dynamics are dominant in controlling the suspended-sediment dynamics in JZB and have experienced significant changes with the loss of tidal flats due to the land reclamation. The sediment model coupled with the tide model was used to investigate the changes in suspended-sediment dynamics due to the land reclamation from 1935 to 2008, including suspended-sediment concentrations (SSC) and the horizontal suspended-sediment fluxes. This model can predict the general patterns of the spatial and temporal variation of SSC. The model was applied to investigate how the net transport of suspended sediments between JZB and its adjacent sea areas changed with land reclamation: in 1935 the net movement of suspended sediments was from JZB to the adjacent sea (erosion for JZB), primarily caused by horizontal advection associated with a horizontal gradient in the SSC; This seaward transport (erosion for JZB) had gradually declined from 1935 to 2008. If land reclamation on a large scale is continued in future, the net transport between JZB and the adjacent sea would turn landward and JZB would switch from erosion to siltation due to the impact of land reclamation on the horizontal advection of suspended sediments. We also evaluate the primary physical mechanisms including advection of suspended sediments, settling lag and tidal asymmetry, which control the suspended-sediment dynamics with the process of land reclamation.

Testing the potential for improving quality of sediments impacted by mussel farms using bioturbating polychaete worms

DEFF Research Database (Denmark)

Bergström, Per; Carlsson, Marita S; Lindegarth, Mats

2017-01-01

Biodeposits from farmed mussels severely influence the biogeochemistry of sediments by increasing the levels of organic matter (OM). Mitigation of such negative impacts is important for the development of sustainable aquaculture operations. As a step towards developing methods for remediation...... of coastal sediments affected by mussel farming, the effects of the polychaete, Hediste diversicolor was evaluated experimentally. In a series of field- and laboratory experiments we tested hypotheses about the effects of polychaetes on sediment oxygen consumption, nutrient fluxes and sulphide pools under...... different polychaete densities and sedimentation regimes. The experimental results support the idea that polychaetes can mitigate negative effects on the benthic environment beneath mussel farms. H. diversicolor oxidized the sediment and generally enhanced the oxygen consumption, and thus the decomposition...

Hydrological connectivity of perched aquifers and regional aquifers in semi-arid environments: a case study from Namibia

Science.gov (United States)

Hamutoko, J. T.; Wanke, H.

2017-12-01

Integrated isotopic and hydrological tracers along with standard hydrological data are used to understand complex dry land hydrological processes on different spatial and temporal scales. The objective of this study is to analyse the relationship between the perched aquifers and the regional aquifer using hydrochemical data and isotopic composition in the Cuvelai-Etosha Basin in Namibia. This relation between the aquifers will aid in understanding groundwater recharge processes and flow dynamics. Perched aquifers are discontinuous shallow aquifers with water level ranging from 0 to 30 meters below ground level. The regional aquifer occurs in semi-consolidated sandstone at depths between about 60 and 160 meters below ground level. Water samples were collected from both aquifers in 10 villages and were analysed for major ions and stable isotopes. The results show overlapping hydrochemistry and isotopic compositions of both aquifers in 8 villages which suggest the possibility of perched aquifer water infiltrating into the regional aquifer. In two villages the hydrochemistry and isotopic composition of the aquifers are totally different and this suggests that there is no interaction between this aquifers. Areas where perched aquifers are connected to regional aquifers maybe recharge zones. These finding have important implications for groundwater resource management.

Groundwater reorganization in the Floridan aquifer following Holocene sea-level rise

Science.gov (United States)

Morrissey, Sheila K.; Clark, Jordan F.; Bennett, Michael; Richardson, Emily; Stute, Martin

2010-10-01

Sea-level fluctuations, particularly those associated with glacial-interglacial cycles, can have profound impacts on the flow and circulation of coastal groundwater: the water found at present in many coastal aquifers may have been recharged during the last glacial period, when sea level was over 100m lower than present, and thus is not in equilibrium with present recharge conditions. Here we show that the geochemistry of the groundwater found in the Floridan Aquifer System in south Florida is best explained by a reorganization of groundwater flow following the sea-level rise at the end of the Last Glacial Maximum approximately 18,000 years ago. We find that the geochemistry of the fresh water found in the upper aquifers at present is consistent with recharge from meteoric water during the last glacial period. The lower aquifer, however, consists of post-sea-level-rise salt water that is most similar to that of the Straits of Florida, though with some dilution from the residual fresh water from the last glacial period circulation. We therefore suggest that during the last glacial period, the entire Floridan Aquifer System was recharged with meteoric waters. After sea level rose, the increased hydraulic head reduced the velocity of the groundwater flow. This velocity reduction trapped the fresh water in the upper aquifers and initiated saltwater circulation in the lower aquifer.

The impact of reduction of doublet well spacing on the Net Present Value and the life time of fluvial Hot Sedimentary Aquifer doublets

NARCIS (Netherlands)

Willems, C.J.L.; Maghami Nick, Hamidreza M.; Bruhn, D.F.

This paper evaluates the impact of reduction of doublet well spacing, below the current West Netherlands Basin standard of 1000 to 1500 m, on the Net Present Value (NPV) and the life time of fluvial Hot Sedimentary Aquifer (HSA) doublets. First, a sensitivity analysis is used to show the possible

Considerations in the extraction of uranium from a fresh-water aquifer - Miocene Oakville Sandstone, south Texas

International Nuclear Information System (INIS)

Henry, C.D.; Galloway, W.E.; Smith, G.E.

1982-01-01

The Miocene Oakville Sandstone is a major aquifer and uranium host beneath the Texas Coastal Plain. Present and future uranium mining by either surface or in situ methods could affect the availability and quality of Oakville ground water unless the mining is designed properly. Possible effects of mining, potential natural mitigation of these effects, and approaches to minimizing the impact of mining on the aquifer system are discussed. Both solution and surface mining may affect the availability of ground water by altering recharge characteristics and permeability. Because the volume of the aquifer affected by mining is small compared with its total volume, availability of Oakville ground water will probably not be reduced significantly, except in wells immediately adjacent to a mine. Mining may affect the quality of ground water by introducing chemicals that are not indigenous to the aquifer or by inducing chemical reactions that do not occur naturally or that occur at much slower rates. Most mining companies no longer use concentrated, ammonium-based leaches because of known problems in restoring water to its original chemistry. Natural and induced release of trace elements such as molybdenum is known to occur, but the geochemical controls on mobility and potential mitigating reactions in the aquifer are poorly understood. Because the affected aquifer volume is small, any deterioration of water quality will probably be localized. Observations and recommendations are presented on: regional and local baseline studies, determination of aquifer sensitivity, methods and goals of monitoring during and after mining, and need for research on poorly understood aspects of mining impact. Such impacts include chemical reactions and processes that affect the long-term release of trace elements

OU3 sediment dating and sedimentation rates

International Nuclear Information System (INIS)

Blair, R.B.; Wolaver, H.A.; Burger, V.M.

1994-01-01

Environmental Technologies at Rocky Flats Environmental Technology Site (RFS) investigated the sediment history of Standley Lake, Great Western Reservoir, and Mower Reservoir using 137 Cs and 239,240 Pu global fall-out as dating indicators. These Colorado Front Range reservoirs have been the subject of study by various city, state and national agencies due to suspected Department of Energy Rocky Flats Plant impacts. We performed sediment dating as part of the RCRA Facility Investigation/Remedial Investigation Report for Operable Unit 3. A sediment chronology profile assists scientist in determining the year of sedimentation for a particular peak concentration of contaminants. Radioisotope sediment dating for the three reservoirs indicated sedimentation rates of 0.7 to 0.8 in./yr. for Standley Lake (SL), 0.9 in./yr. for Great Western Reservoir (GWR), and 0.3 in./yr. in Mower Reservoir (MR). RFS sediment dating for Operable Unit 3 compared favorably with the Hardy, Livingston, Burke, and Volchok Standley Lake study. This report describes the cesium/plutonium sediment dating method, estimates sedimentation rates for Operable Unit 3 reservoirs, and compares these results to previous investigations

Impact of Sedimentation hazard at Jor Reservoir, Batang Padang Hydroelectric Scheme in Malaysia

Science.gov (United States)

Luis, Jansen; Mohd Sidek, Lariyah; Jajarmizadeh, Milad

2016-03-01

Sedimentation in reservoir can be treated as a hazard because it affects the overall safety of the dam. It is a growing concern for reservoir operators throughout the world as it impacts the operability of the hydropower plant and its function as flood control. The objective of the study is to carry out reservoir bathymetric survey to determine the storage volume available at Jor reservoir. The paper intends to discuss the results of two successive surveys carried out in year 2007 and 2010 and comparison with historical data in1968 owing to analyse of sedimentation trend. The result showed that the total storage loss is approximately 43% with an estimated deposited sediment volume of 1.4 million m3 in year 2010. The sedimentation rate is estimated at 3.3% for the years surveyed which is greater than the world average of 0.93%. The findings from the survey are used to develop a revised elevation-storage curve which could be used by the operator and engineers to carry out future power generation planning and flood study predictions. The findings are also expected to be used to determine the optimum method for sediment management and hydro-mechanical protection.

Vertical gradients in water chemistry and age in the Northern High Plains Aquifer, Nebraska, 2003

Science.gov (United States)

McMahon, P.B.; Böhlke, J.K.; Carney, C.P.

2007-01-01

and clay-mineral precipitation; organic-carbon and pyrite oxidation; oxygen reduction and denitrification; and cation exchange. Mixing with surface water affected the chemistry of ground water in alluvial sediments of the Platte River Valley. Radiocarbon ages in the aquifer, adjusted for carbon mass transfers, ranged from 1,800 to 15,600 14C years before present. These results have important implications with respect to development of ground-water resources in the Sand Hills. Most of the water in the aquifer predates modern anthropogenic activity so excessive removal of water by pumping is not likely to be replenished by natural recharge in a meaningful timeframe. Vertical gradients in ground-water age were used to estimate long-term average recharge rates in the aquifer. In most areas, the recharge rates ranged from 0.02 to 0.05 foot per year. The recharge rate was 0.2 foot per year in one part of the aquifer characterized by large downward hydraulic gradients.Nitrite plus nitrate concentrations at the water table were 0.13 to 3.13 milligrams per liter as nitrogen, and concentrations substantially decreased with depth in the aquifer. Dissolved-gas and nitrogen-isotope data indicate that denitrification in the aquifer removed 0 to 97 percent (average = 50 percent) of the nitrate originally present in recharge. The average amount of nitrate removed by denitrification in the aquifer north of the Platte River (Sand Hills) was substantially greater than the amount removed south of the river (66 as opposed to 0 percent), and the extent of nitrate removal appears to be related to the presence of thick deposits of sediment on top of the Ogallala Group in the Sand Hills that contained electron donors, such as organic carbon and pyrite, to support denitrification.Apparent rates of dissolved-oxygen reduction and denitrification were estimated on the basis of decreases in dissolved-oxygen concentrations and increases in concentrations of excess nitrogen gas and ground-water ages

Managed aquifer recharge in weathered crystalline basement aquifers in India: Monitoring of the effect of tank infiltration on water quality over several monsoon events

Science.gov (United States)

Alazard, Marina; Boisson, Alexandre; Maréchal, Jean-Christophe; Dewandel, Benoît; Perrin, Jérôme; Pettenati, Marie; Picot-Colbeaux, Géraldine; Ahmed, Shakeel; Thiéry, Dominique; Kloppmann, Wolfram

2015-04-01

Managed aquifer recharge (MAR) structures like percolation tanks are considered by the Indian national and regional governments as major option for tackling declining groundwater levels due to overexploitation for irrigation purposes (Boisson et al., 2014). Their main purpose is to restore groundwater availability under strong climatic and anthropogenic pressure. Furthermore, MAR-induced dilution with fresh surface water is generally expected to improve groundwater quality with respect to both anthropogenic and geogenic contaminants (total mineralisation, nitrates, chlorides, sulphates and fluoride contents). The impact of a percolation tank on groundwater quality was investigated in a context that is typical for hydro-climatic and geological settings in southern and eastern India: fractured crystalline basement aquifers overlain by a weathering zone under semi-arid climate. Water level data and geochemical indicators (stable isotopes and major ions) were monitored for both groundwater and surface water, over several successive monsoon events. In case of high to very high water levels, the groundwater quality is globally improved. However, in a few cases, the quality of the groundwater can be negatively impacted due to leaching of salts under the tank, particularly during the first rain events of the monsoon. Geogenic fluoride contents in groundwater, induced by water-rock interaction and enhanced by recycling of agricultural return flow under paddy fields, is found to be relatively stable over the year. This finding points out that the underlying processes, mainly dissolution of F-bearing phases like fluorapatites combined with Ca/Na cation exchange and calcite precipitation, both limiting the possibility of F-removal via fluorite precipitation (Pettenati et al., 2013, 2014), are not impacted by the hydrological conditions. This work highlights the complexity of the recharge processes in crystalline aquifers, enhanced by the variability of hydrological conditions

A Black Hills-Madison Aquifer origin for Dakota Aquifer groundwater in northeastern Nebraska.

Science.gov (United States)

Stotler, Randy; Harvey, F Edwin; Gosselin, David C

2010-01-01

Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis ((18)O, (2)H, (3)H, (14)C, (13)C, (34)S, (18)O-SO(4), (87)Sr, (37)Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with delta(18)O values (-9.6 per thousand to -12.4 per thousand) similar to local, modern precipitation (-7.4 per thousand to -10 per thousand), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted delta(18)O values (-16 per thousand to -18 per thousand) relative to local, modern precipitation, and (14)C ages 32,000 to more than 47,000 years before present. Sulfate, delta(18)O, delta(2)H, delta(34)S, and delta(18)O-SO(4) concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between (14)C and Darcy age estimates indicate that (14)C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.

Metal impacts on microbial biomass in the anoxic sediments of a contaminated lake

Energy Technology Data Exchange (ETDEWEB)

Gough, Heidi L.; Dahl, Amy L.; Nolan, Melissa A.; Gaillard, Jean-Francois; Stahl, David A.

2008-04-26

Little is known about the long-term impacts of metal contamination on the microbiota of anoxic lake sediments. In this study, we examined microbial biomass and metals (arsenic, cadmium, chromium, copper, iron, lead, manganese, and zinc) in the sediments of Lake DePue, a backwater lake located near a former zinc smelter. Sediment core samples were examined using two independent measures for microbial biomass (total microscopic counts and total phospholipid-phosphate concentrations), and for various fractions of each metal (pore water extracts, sequential extractions, and total extracts of all studied metals and zinc speciation by X-ray absorption fine structure (XAFS). Zinc concentrations were up to 1000 times higher than reported for sediments in the adjacent Illinois River, and ranged from 21,400 mg/kg near the source to 1,680 mg/kg near the river. However, solid metal fractions were not well correlated with pore water concentrations, and were not good predictors of biomass concentrations. Instead, biomass, which varied among sites by as much as two-times, was inversely correlated with concentrations of pore water zinc and arsenic as established by multiple linear regression. Monitoring of other parameters known to naturally influence biomass in sediments (e.g., organic carbon concentrations, nitrogen concentrations, pH, sediment texture, and macrophytes) revealed no differences that could explain observed biomass trends. This study provides strong support for control of microbial abundance by pore water metal concentrations in contaminated freshwater sediments.

Coastal aquifers: Scientific advances in the face of global environmental challenges

Science.gov (United States)

Post, Vincent E. A.; Werner, Adrian D.

2017-08-01

Coastal aquifers embody the subsurface transition between terrestrial and marine systems, and form the almost invisible pathway for tremendous volumes of freshwater that flow to the ocean. Changing conditions of the earth's landscapes and oceans can disrupt the fragile natural equilibrium between fresh and saltwater that exists in coastal zones. Among these, over-abstraction of groundwater is considered the leading man-made cause of seawater intrusion. Moreover, many of the world's largest urban settings, where sources of contamination are profuse, have been built over the freshwater in coastal aquifers. Thus, coastal aquifers are important receptors of human impacts to water on Earth (Michael et al., 2017). This Special Issue on 'Investigation and Management of Coastal Aquifers' contains current scientific advances on the topic, dealing with the storage and quality of water, affected by stressors ranging in scale from point source contamination to global climate change.

Groundwater arsenic concentrations in Vietnam controlled by sediment age

DEFF Research Database (Denmark)

Postma, Dieke; Larsen, Flemming; Thai, Nguyen Thi

2012-01-01

Arsenic contamination of groundwater continues to threaten the health of millions of people in southeast Asia. The oxidation of organic carbon, coupled to the reductive dissolution of arsenic-bearing iron oxides, is thought to control the release of sediment-bound arsenic into groundwater. However......, the cause of the high spatial variability in groundwater arsenic concentrations—which can range from 5 to 500 μg l−1 within distances of a few kilometres—has been uncertain. Here, we combine measurements of sediment age, organic-matter reactivity and water chemistry at four locations along a cross......-section of the arsenic-contaminated Red River floodplain in Vietnam to determine the origin of variations in groundwater arsenic concentrations. The burial age of the aquifer sediments, determined using optical stimulated luminescence, ranged from 460 years near the course of the present-day river to 5,900 years...

Estimating Groundwater Mounding in Sloping Aquifers for Managed Aquifer Recharge.

Science.gov (United States)

Zlotnik, Vitaly A; Kacimov, Anvar; Al-Maktoumi, Ali

2017-11-01

Design of managed aquifer recharge (MAR) for augmentation of groundwater resources often lacks detailed data, and simple diagnostic tools for evaluation of the water table in a broad range of parameters are needed. In many large-scale MAR projects, the effect of a regional aquifer base dip cannot be ignored due to the scale of recharge sources (e.g., wadis, streams, reservoirs). However, Hantush's (1967) solution for a horizontal aquifer base is commonly used. To address sloping aquifers, a new closed-form analytical solution for water table mound accounts for the geometry and orientation of recharge sources at the land surface with respect to the aquifer base dip. The solution, based on the Dupiuit-Forchheimer approximation, Green's function method, and coordinate transformations is convenient for computing. This solution reveals important MAR traits in variance with Hantush's solution: mounding is limited in time and space; elevation of the mound is strongly affected by the dip angle; and the peak of the mound moves over time. These findings have important practical implications for assessment of various MAR scenarios, including waterlogging potential and determining proper rates of recharge. Computations are illustrated for several characteristic MAR settings. © 2017, National Ground Water Association.

Aquifer restoration at uranium in situ leach sites

International Nuclear Information System (INIS)

Anastasi, F.S.; Williams, R.E.

1985-01-01

In situ mining of uranium involves injection of a leaching solution (lixiviant) into an ore-bearing aquifer. Frequently, the ground water in the mined aquifer is a domestic or livestock water supply. As the lixiviant migrates through the ore body, uranium and various associated elements such as arsenic, selenium, molybdenum, vanadium and radium-226 are mobilized in the ground water. Aquifer restoration after in situ mining is not fully understood. Several methods have been developed to restore mined aquifers to pre-mining (baseline) quality. Commonly used methods include ground water sweeping, clean water injection, and treatment by ion exchange and reverse osmosis technologies. Ammonium carbonate lixiviant was used at one RandD in situ mine. Attempts were made to restore the aquifer using a variety of methods. Efforts were successful in reducing concentrations of the majority of contaminants to baseline levels. Concentrations of certain parameters, however, remained at levels above baseline six months after restoration ceased. Relatively large quantities of ground water were processed in the restoration attempt considering the small size of the project (1.25 acre). More thorough characterization of the hydrogeology of the site may have enhanced the effectiveness of restoration and reduced potential environmental impacts associated with the project. This paper presents some of the findings of a research project conducted by the Mineral Resources Waste Management Team at the University of Idaho in Moscow, Idaho. Views contained herein do not reflect U.S. Nuclear Regulatory Commission policy

Sediment processes modelling below hydraulic mining: towards environmental impact mitigation

Science.gov (United States)

Chalov, Sergey R.

2010-05-01

Placer mining sites are located in the river valleys so the rivers are influenced by mining operations. Frequently the existing mining sites are characterized by low contribution to the environmental technologies. Therefore hydraulic mining alters stream hydrology and sediment processes and increases water turbidity. The most serious environmental sequences of the sediment yield increase occur in the rivers populated by salmon fish community because salmon species prefer clean water with low turbidity. For instance, the placer mining in Kamchatka peninsula (Far East of Russia) which is regarded to be the last global gene pool of wild salmon Oncorhynchus threatens the rivers ecosystems. System of man-made impact mitigation could be done through the exact recognition of the human role in hydrological processes and sediment transport especially. Sediment budget of rivers below mining sites is transformed according to the appearance of the man-made non-point and point sediment sources. Non-point source pollution occurs due to soil erosion on the exposed hillsides and erosion in the channel diversions. Slope wash on the hillsides is absent during summer days without rainfalls and is many times increased during rainfalls and snow melting. The nearness of the sources of material and the rivers leads to the small time of suspended load increase after rainfalls. The average time of material intake from exposed hillsides to the rivers is less than 1 hour. The main reason of the incision in the channel diversion is river-channel straightening. The increase of channel slopes and transport capacity leads to the intensive incision of flow. Point source pollution is performed by effluents both from mining site (mainly brief effluents) and from settling ponds (permanent effluents), groundwater seepage from tailing pits or from quarries. High rate of groundwater runoff is the main reason of the technological ponds overfilling. Intensive filtration from channel to ponds because of

Groundwater chemistry and occurrence of arsenic in the Meghna floodplain aquifer, southeastern Bangladesh

Science.gov (United States)

Zahid, A.; Hassan, M.Q.; Balke, K.-D.; Flegr, M.; Clark, D.W.

2008-01-01

Dissolved major ions and important heavy metals including total arsenic and iron were measured in groundwater from shallow (25-33 m) and deep (191-318 m) tube-wells in southeastern Bangladesh. These analyses are intended to help describe geochemical processes active in the aquifers and the source and release mechanism of arsenic in sediments for the Meghna Floodplain aquifer. The elevated Cl- and higher proportions of Na+ relative to Ca2+, Mg2+, and K+ in groundwater suggest the influence by a source of Na+ and Cl-. Use of chemical fertilizers may cause higher concentrations of NH 4+ and PO 43- in shallow well samples. In general, most ions are positively correlated with Cl-, with Na+ showing an especially strong correlation with Cl-, indicating that these ions are derived from the same source of saline waters. The relationship between Cl-/HCO 3- ratios and Cl- also shows mixing of fresh groundwater and seawater. Concentrations of dissolved HCO 3- reflect the degree of water-rock interaction in groundwater systems and integrated microbial degradation of organic matter. Mn and Fe-oxyhydroxides are prominent in the clayey subsurface sediment and well known to be strong adsorbents of heavy metals including arsenic. All five shallow well samples had high arsenic concentration that exceeded WHO recommended limit for drinking water. Very low concentrations of SO 42- and NO 3- and high concentrations of dissolved Fe and PO 43- and NH 4+ ions support the reducing condition of subsurface aquifer. Arsenic concentrations demonstrate negative co-relation with the concentrations of SO 42- and NO 3- but correlate weakly with Mo, Fe concentrations and positively with those of P, PO 43- and NH 4+ ions. ?? 2007 Springer-Verlag.

Nitrogen Fate in a Phreatic Fluviokarst Watershed: a Stable Isotope, Sediment Tracing, and Numerical Modeling Approach

Science.gov (United States)

Husic, A.; Fox, J.; Ford, W. I., III; Agouridis, C.; Currens, J. C.; Taylor, C. J.

2017-12-01

Sediment tracing tools provide an insight into provenance, fate, and transport of sediment and, when coupled to stable isotopes, can elucidate in-stream biogeochemical processes. Particulate nitrogen fate in fluviokarst systems is a relatively unexplored area of research partially due to the complex hydrodynamics at play in karst systems. Karst topography includes turbulent conduits that transport groundwater and contaminants at speeds more typical of open channel flows than laminar Darcian flows. While it is accepted that karst hydro-geomorphology represents a hybrid surface-subsurface system for fluid, further investigation is needed to determine whether, and to what extent, karst systems behave like surface agricultural streams or porous media aquifers with respect to their role in nitrogen cycling. Our objective is to gain an understanding of in-conduit nitrogen processes and their effect on net nitrogen-exports from karst springs to larger waterbodies. The authors apply water, sediment, carbon, and nitrogen tracing techniques to analyze water for nitrate, sediment carbon and nitrogen, and stable sediment nitrogen isotope (δ15N). Thereafter, a new numerical model is formulated that: simulates dissolved inorganic nitrogen and sediment nitrogen transformations in the phreatic karst conduit; couples carbon turnover and nitrogen transformations in the model structure; and simulates the nitrogen stable isotope mass balance for the dissolved and sediment phases. Nitrogen tracing data results show a significant increase in δ15N of sediment nitrogen at the spring outlet relative to karst inputs indicating the potential for isotope fractionation during dissolved N uptake by bed sediments in the conduit and during denitrification within bed sediments. The new numerical modeling structure is then used to reproduce the data results and provide an estimate of the relative dominance of N uptake and denitrification within the surficial sediments of the karst conduit system

The impact of pre-restoration land-use and disturbance on sediment structure, hydrology and the sediment geochemical environment in restored saltmarshes.

Science.gov (United States)

Spencer, Kate L; Carr, Simon J; Diggens, Lucy M; Tempest, James A; Morris, Michelle A; Harvey, Gemma L

2017-06-01

Saltmarshes are being lost or degraded as a result of human activity resulting in loss of critical ecosystem services including the provision of wild species diversity, water quality regulation and flood regulation. To compensate, saltmarshes are being restored or re-created, usually driven by legislative requirements for increased habitat diversity, flood regulation and sustainable coastal defense. Yet, there is increasing evidence that restoration may not deliver anticipated ecosystem services; this is frequently attributed to poor drainage and sediment anoxia. However, physical sediment characteristics, hydrology and the sediment geochemical environment are rarely examined in restoration schemes, despite such factors being critical for plant succession. This study presents the novel integration of 3D-computed X-ray microtomography to quantify sediment structure and porosity, with water level and geochemical data to understand the impact of pre-restoration land use and disturbance on the structure and functioning of restored saltmarshes. The study combines a broad-scale investigation of physical sediment characteristics in nine de-embanked saltmarshes across SE England, with an intensive study at one site examining water levels, sediment structure and the sediment geochemical environment. De-embankment does not restore the hydrological regime, or the physical/chemical framework in the saltmarshes and evidence of disturbance includes a reduction in microporosity, pore connectivity and water storage capacity, a lack of connectivity between the sub-surface environment and overlying floodwaters, and impeded sub-surface water flow and drainage. This has significant consequences for the sediment geochemical environment. This disturbance is evident for at least two decades following restoration and is likely to be irreversible. It has important implications for plant establishment in particular, ecosystem services including flood regulation, nutrient cycling and wild

Hydrogeochemical assessment of mine-impacted water and sediment of iron ore mining

Science.gov (United States)

Nur Atirah Affandi, Fatin; Kusin, Faradiella Mohd; Aqilah Sulong, Nur; Madzin, Zafira

2018-04-01

This study was carried out to evaluate the hydrogeochemical behaviour of mine-impacted water and sediment of a former iron ore mining area. Sampling of mine water and sediment were carried out at selected locations within the mine including the former mining ponds, mine tailings and the nearby stream. The water samples were analysed for their hydrochemical facies, major and trace elements including heavy metals. The water in the mining ponds and the mine tailings was characterised as highly acidic (pH 2.54-3.07), but has near-neutral pH in the nearby stream. Results indicated that Fe and Mn in water have exceeded the recommended guidelines values and was also supported by the results of geochemical modelling. The results also indicated that sediments in the mining area were contaminated with Cd and As as shown by the potential ecological risk index values. The total risk index of heavy metals in the sediment were ranked in the order of Cd>As>Pb>Cu>Zn>Cr. Overall, the extent of potential ecological risks of the mining area were categorised as having low to moderate ecological risk.

Geochemistry and origins of mineralized waters in the Floridan aquifer system, northeastern Florida

Science.gov (United States)

Phelps, G.G.

2001-01-01

Increases in chloride concentration have been observed in water from numerous wells tapping the Floridan aquifer system in northeastern Florida. Although most increases have been in the eastern part of Duval County, Florida, no spatial pattern in elevated chloride concentrations is discernible. Possible sources of the mineralized water include modern seawater intrusion; unflushed Miocene-to-Pleistocene-age seawater or connate water in aquifer sediments; or mineralized water from deeper zones of the aquifer system or from formations beneath the Floridan aquifer system. The purpose of this study was to document the chemical and isotopic characteristics of water samples from various aquifer zones, and from geochemical and hydrogeologic data, to infer the source of the increased mineralization. Water samples were collected from 53 wells in northeastern Florida during 1997-1999. Wells tapped various zones of the aquifer including: the Fernandina permeable zone (FPZ), the upper zone of the Lower Floridan aquifer (UZLF), the Upper Floridan aquifer (UFA), and both the UFA and the UZLF. Water samples were analyzed for major ions and trace constituents and for isotopes of carbon, oxygen, hydrogen, sulfur, strontium, chlorine, and boron. Samples of rock from the aquifer were analyzed for isotopes of oxygen, carbon, and strontium. In general, water from various aquifer zones cannot be differentiated based on chemistry, except for water from FPZ wells. Major-ion concentrations vary as much within the upper zone of the Lower Floridan aquifer and the Upper Floridan aquifer as between these two zones. Simple models of mixing between fresh ground water and either modern seawater or water from the FPZ as a mineralized end member show that many water samples from the UZLF aquifer and the UFA are enriched in bicarbonate, calcium, magnesium, sulfate, fluoride, and silica and are depleted in sodium and potassium (as compared to concentrations predicted by simple mixing). Chemical mass

Simulation climate change impact on runoff and sediment yield in a small watershed in the basque country, northern Spain.

Science.gov (United States)

Zabaleta, Ane; Meaurio, Maite; Ruiz, Estilita; Antigüedad, Iñaki

2014-01-01

Climate change is likely to have an impact on runoff and fluvial sediments in watersheds. These factors are among those used to characterize water bodies in relation to the European Water Framework Directive (WFD). Hence, it is important to investigate the extent to which climate change may hinder the achievement of the objectives of the WFD. We explored the potential impact of climate change on runoff and sediment yield for the Aixola watershed using the Soil and Water Assessment Tool (SWAT). The model calibration (2007-2010) and validation (2005-2006) results were rated as satisfactory. Subsequently, simulations were run for four climate change model-scenario combinations based on two general circulation models (CGCM2 and ECHAM4) under two emissions scenarios (A2 and B2) from 2011 to 2100. All combinations predicted that runoff and sediment yield would decrease compared with baseline (1961-1990). Three combinations suggested that runoff and sediments would decrease by 0.13 to 0.45 m s and 0.11 to 0.43 t every year from 2011 to 2100. However, the CGCM2-B2 scenario resulted in an "extremely likely" increase in runoff and sediments of 0.94 m s and 0.57 t every year. These variations in annual sediment yield are closely related to changes in precipitation. The high degree of uncertainty in the results must be considered when assessing potential impacts and making decisions about adaptation measures. Nevertheless, this first attempt to estimate future sediment yields in our region could be a useful starting point to explore future hydrological impacts in the area. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

The main microelements and phosphorus content of sediments formed in a drinking water supply system

OpenAIRE

Marina Valentukeviciene; Ramune Zurauskiene; Jonas Satkunas

2016-01-01

Groundwater is the only source for drinking water supply in Lithuania. Twenty water intakes exploiting Quaternary aquifers are operating in Vilnius City. The main aim of this study was to characterize the heavy metal content of internal pipeline sediments in the water supply network. It also provides a new insight into the accumulation of phosphorus and its variation in pipeline sediments in the study area. The results of this research reflect the level of heavy metals that accumulated during...

Aquifer thermal-energy-storage modeling

Science.gov (United States)

Schaetzle, W. J.; Lecroy, J. E.

1982-09-01

A model aquifer was constructed to simulate the operation of a full size aquifer. Instrumentation to evaluate the water flow and thermal energy storage was installed in the system. Numerous runs injecting warm water into a preconditioned uniform aquifer were made. Energy recoveries were evaluated and agree with comparisons of other limited available data. The model aquifer is simulated in a swimming pool, 18 ft by 4 ft, which was filled with sand. Temperature probes were installed in the system. A 2 ft thick aquifer is confined by two layers of polyethylene. Both the aquifer and overburden are sand. Four well configurations are available. The system description and original tests, including energy recovery, are described.

Groundwater reorganization in the Floridan aquifer following Holocene sea-level rise

OpenAIRE

Morrissey, SK; Clark, JF; Bennett, M; Richardson, E; Stute, M

2010-01-01

Sea-level fluctuations, particularly those associated with glacial-interglacial cycles, can have profound impacts on the flow and circulation of coastal groundwater: the water found at present in many coastal aquifers may have been recharged during the last glacial period, when sea level was over 100 m lower than present, and thus is not in equilibrium with present recharge conditions. Here we show that the geochemistry of the groundwater found in the Floridan Aquifer System in south Florida ...

Sediment Budgets and Sources Inform a Novel Valley Bottom Restoration Practice Impacted by Legacy Sediment: The Big Spring Run, PA, Restoration Experiment

Science.gov (United States)

Walter, R. C.; Merritts, D.; Rahnis, M. A.; Gellis, A.; Hartranft, J.; Mayer, P. M.; Langland, M.; Forshay, K.; Weitzman, J. N.; Schwarz, E.; Bai, Y.; Blair, A.; Carter, A.; Daniels, S. S.; Lewis, E.; Ohlson, E.; Peck, E. K.; Schulte, K.; Smith, D.; Stein, Z.; Verna, D.; Wilson, E.

2017-12-01

Big Spring Run (BSR), a small agricultural watershed in southeastern Pennsylvania, is located in the Piedmont Physiographic Province, which has the highest nutrient and sediment yields in the Chesapeake Bay watershed. To effectively reduce nutrient and sediment loading it is important to monitor the effect of management practices on pollutant reduction. Here we present results of an ongoing study, begun in 2008, to understand the impact of a new valley bottom restoration strategy for reducing surface water sediment and nutrient loads. We test the hypotheses that removing legacy sediments will reduce sediment and phosphorus loads, and that restoring eco-hydrological functions of a buried Holocene wetland (Walter & Merritts 2008) will improve surface and groundwater quality by creating accommodation space to trap sediment and process nutrients. Comparisons of pre- and post-restoration gage data show that restoration lowered the annual sediment load by at least 118 t yr-1, or >75%, from the 1000 m-long restoration reach, with the entire reduction accounted for by legacy sediment removal. Repeat RTK-GPS surveys of pre-restoration stream banks verified that >90 t yr-1 of suspended sediment was from bank erosion within the restoration reach. Mass balance calculations of 137Cs data indicate 85-100% of both the pre-restoration and post-restoration suspended sediment storm load was from stream bank sources. This is consistent with trace element data which show that 80-90 % of the pre-restoration outgoing suspended sediment load at BSR was from bank erosion. Meanwhile, an inventory of fallout 137Cs activity from two hill slope transects adjacent to BSR yields average modern upland erosion rates of 2.7 t ha-1 yr-1 and 5.1 t ha-1 yr-1, showing modest erosion on slopes and deposition at toe of slopes. We conclude that upland farm slopes contribute little soil to the suspended sediment supply within this study area, and removal of historic valley bottom sediment effectively

Understanding Kendal aquifer system: a baseline analysis for sustainable water management proposal

Science.gov (United States)

Lukman, A.; Aryanto, M. D.; Pramudito, A.; Andhika, A.; Irawan, D. E.

2017-07-01

North coast of Java has been grown as the center of economic activities and major connectivity hub for Sumatra and Bali. Sustainable water management must support such role. One of the basis is to understand the baseline of groundwater occurrences and potential. However the complex alluvium aquiver system has not been well-understood. A geoelectric measurements were performed to determine which rock layer has a good potential as groundwater aquifers in the northern coast of Kaliwungu Regency, Kendal District, Central Java province. Total of 10 vertical electrical sounding (VES) points has been performed, using a Schlumberger configuration with the current electrode spacing (AB/2) varies between 200 - 300 m and the potential difference electrode spacing (MN/2) varies between 0.5 to 20 m with depths target ranging between 150 - 200 m. Geoelectrical data processing is done using Ip2win software which generates resistivity value, thickness and depth of subsurface rock layers. Based on the correlation between resistivity value with regional geology, hydrogeology and local well data, we identify three aquifer layers. The first layer is silty clay with resistivity values vary between 0 - 10 ohm.m, then the second layer is tuffaceous claystone with resistivity value between 10 - 60 ohm.m. Both layers serve as impermeable layer. The third layer is sandy tuff with resistivity value between 60 - 100 ohm.m which serves as a confined aquifer layer located at 70 - 100 m below surface. Its thickness is vary between 70 to 110 m. The aquifer layer is a mixing of volcanic and alluvium sediment, which is a member of Damar Formation. The stratification of the aquifer system may change in short distance and depth. This natural setting prevent us to make a long continuous correlation between layers. Aquifer discharge is estimated between 5 - 71 L/s with the potential deep well locations lies in the west and southeast part of the study area. These hydrogeological settings should be used

Isotopes to Study the coastal aquifer plain, Cap Bon, Tunisia

International Nuclear Information System (INIS)

Ben Hamouda, M. F.; Zouari, Kamel; Tarhouni, J.; Gaye, C.B.; Oueslati, M.N.

2005-01-01

The study area is located in the northeastern part of Tunisia about 60 km south of the Tunis city. It is bounded by the Gulf of Haematite in the East, Djebel Sidi Aberahmane in the West, The town of Nabeul in the south and the area of the town Kelibia in the north. The landscape is a coastal plain slightly sloping (3%) towards the sea. The groundwater of the Oriental coast aquifer system occurs mainly at two levels, a shallow aquifer up to depths of about 50 m whose reservoir is consisted by sediments of the Plio quaternary and a deep aquifer between about 150 and 400 m located in the sand stone formations of Miocene of the anticline of Djebel Sidi Abderrahmene. The climate of the region is semi-arid to sub-humid and of Mediterranean type. There are no perennial rivers in this region; but intense storms occasionally cause surface runoff, which is discharged by the oueds. The study is related to a technical cooperation project with the International Atomic Energy Agency, Vienna, Austria, aimed at the use of isotope techniques to study the seawater intrusion into the coastal aquifers of Cap Bon in Tunisia. In this regard, a better understanding of the recharge and flow regime as well as the origin or salinity of the groundwater was required. To reach this goal, isotope and geochemical investigations were carried out. Water samples were taken from wells, boreholes from deep and shallow aquifer of the Oriental coastal aquifer located between Beni Khiar in the south and Kelibia in the north. The samples were analysed for their chemical and isotopic compositions (18O, 2H, 3H, 13C, 14C, 34S). In the following, the results of these analyses are presented and discussed in terms of the recharge and flow regime of the groundwater and the origin and evolution of its salinity. The results of geochemical and isotopic studies have shown that the groundwater is very eterogeneous and suggest the aquifer is replenished by recent water coming from direct infiltration from rain. At

Using geochemical indicators to distinguish high biogeochemical activity in floodplain soils and sediments

Energy Technology Data Exchange (ETDEWEB)

Kenwell, Amy [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Navarre-Sitchler, Alexis, E-mail: asitchle@mines.edu [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Prugue, Rodrigo [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Spear, John R. [Department of Civil and Environmental Engineering, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Hering, Amanda S. [Department of Applied Mathematics and Statistics, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Maxwell, Reed M. [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Carroll, Rosemary W.H. [Desert Research Institute, Division of Hydrologic Sciences, 2215 Raggio Parkway, Reno, NV 89512 (United States); Williams, Kenneth H. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

2016-09-01

A better understanding of how microbial communities interact with their surroundings in physically and chemically heterogeneous subsurface environments will lead to improved quantification of biogeochemical reactions and associated nutrient cycling. This study develops a methodology to predict potential elevated rates of biogeochemical activity (microbial “hotspots”) in subsurface environments by correlating microbial DNA and aspects of the community structure with the spatial distribution of geochemical indicators in subsurface sediments. Multiple linear regression models of simulated precipitation leachate, HCl and hydroxylamine extractable iron and manganese, total organic carbon (TOC), and microbial community structure were used to identify sample characteristics indicative of biogeochemical hotspots within fluvially-derived aquifer sediments and overlying soils. The method has been applied to (a) alluvial materials collected at a former uranium mill site near Rifle, Colorado and (b) relatively undisturbed floodplain deposits (soils and sediments) collected along the East River near Crested Butte, Colorado. At Rifle, 16 alluvial samples were taken from 8 sediment cores, and at the East River, 46 soil/sediment samples were collected across and perpendicular to 3 active meanders and an oxbow meander. Regression models using TOC and TOC combined with extractable iron and manganese results were determined to be the best fitting statistical models of microbial DNA (via 16S rRNA gene analysis). Fitting these models to observations in both contaminated and natural floodplain deposits, and their associated alluvial aquifers, demonstrates the broad applicability of the geochemical indicator based approach. - Highlights: • Biogeochemical characterization of alluvial floodplain soils and sediments was performed to investigate parameters that may indicate microbial hot spot formation. • A correlation between geochemical parameters (total organic carbon and

Using geochemical indicators to distinguish high biogeochemical activity in floodplain soils and sediments

International Nuclear Information System (INIS)

Kenwell, Amy; Navarre-Sitchler, Alexis; Prugue, Rodrigo; Spear, John R.; Hering, Amanda S.; Maxwell, Reed M.; Carroll, Rosemary W.H.; Williams, Kenneth H.

2016-01-01

A better understanding of how microbial communities interact with their surroundings in physically and chemically heterogeneous subsurface environments will lead to improved quantification of biogeochemical reactions and associated nutrient cycling. This study develops a methodology to predict potential elevated rates of biogeochemical activity (microbial “hotspots”) in subsurface environments by correlating microbial DNA and aspects of the community structure with the spatial distribution of geochemical indicators in subsurface sediments. Multiple linear regression models of simulated precipitation leachate, HCl and hydroxylamine extractable iron and manganese, total organic carbon (TOC), and microbial community structure were used to identify sample characteristics indicative of biogeochemical hotspots within fluvially-derived aquifer sediments and overlying soils. The method has been applied to (a) alluvial materials collected at a former uranium mill site near Rifle, Colorado and (b) relatively undisturbed floodplain deposits (soils and sediments) collected along the East River near Crested Butte, Colorado. At Rifle, 16 alluvial samples were taken from 8 sediment cores, and at the East River, 46 soil/sediment samples were collected across and perpendicular to 3 active meanders and an oxbow meander. Regression models using TOC and TOC combined with extractable iron and manganese results were determined to be the best fitting statistical models of microbial DNA (via 16S rRNA gene analysis). Fitting these models to observations in both contaminated and natural floodplain deposits, and their associated alluvial aquifers, demonstrates the broad applicability of the geochemical indicator based approach. - Highlights: • Biogeochemical characterization of alluvial floodplain soils and sediments was performed to investigate parameters that may indicate microbial hot spot formation. • A correlation between geochemical parameters (total organic carbon and

Modelling the impact of dam removal on geomorphic channel response and sediment delivery: an Austrian case study

Science.gov (United States)

Pöppl, Ronald; Coulthard, Tom; Keesstra, Saskia; Keiler, Margreth

2015-04-01

Dams are often considered to have the most significant impact on rivers as dam construction generally reduces downstream sediment fluxes which further involves geomorphic changes in the affected river reaches. Since many dams no longer fulfill their intended purpose (e.g. due to siltation), are dangerous (e.g. catastrophic dam failures) and/or are ecologically damaging (e.g. habitat destruction), within the last two decades several dams have been removed and many more are already proposed for removal. Unfortunately, there is still only little empirical knowledge about the geomorphic consequences of dam removals and the related sediment release which represents a big challenge for river management. Modelling is one way to approach this problem. In the presented study we modelled the impacts of dam removal on geomorphic channel processes, channel morphology and sediment delivery further considering the role of channel engineering measures and reservoir excavation within a river reach impacted by a series of dams using the landscape evolution model CAESAR-Lisflood. The model was run with data from a small catchment located in Lower Austria. Modelled geomorphic channel changes and sediment fluxes were spatio-temporally analyzed, related to real-world data and are discussed in the context of river management issues.

Effects of a Reservoir Water on the GW Quality in a Coastal Aquifer of Semi-arid Region, North-east of Tunisia

Science.gov (United States)

Uchida, C.; Kawachi, A.; Tsujimura, M.; Tarhouni, J.

2015-12-01

This study investigated effects of a reservoir water in a salinized shallow aquifer based on spatial distribution of geochemical properties in groundwater (GW). In many coastal shallow aquifers of arid and semi-arid regions, groundwater table (GWT) depression and salinization have occurred due to GW overexploitation. In Korba aquifer, north-east of Tunisia, after a dam reservoir has been constructed in order to assure a water resource for irrigation, improvement of GW level and quality have been observed in the downstream area of the dam (area-A), while the GW in the other area (area-B) still has high salinity. This study, therefore, aimed to investigate the effects of the reservoir water on the GW quality. In June 2013, water quality survey and sampling were carried out at 60 wells (GW), a dam reservoir, river and the sea. Major ions, boron, bromide, and oxygen-18 and deuterium in collected samples were analyzed. From the results, in the area-B, the GWT was lower than the sea level and the high salinity were observed. The Br- concentration of the GW was correlated with the Cl- concentration, and the values of B/Cl- and Br-/Cl- of the GW were similar to the seawater. Since the GWT depression allowed the seawater to intrude into the aquifer, the GW salinization occurred in this area. On the other hand, in the area-A, GWT was higher than the seawater level, and the Na+ and Cl- concentrations were lower than the area-B. Especially, in the irrigated areas by using the reservoir water, the isotopic values, B/Cl- and Br-/Cl- of the GW were relatively higher than the others. The reservoir water has high isotopic values due to evaporation effect, and the B/Cl- and Br-/Cl- values become higher due to organic matters in sediment of the reservoir or soil in the filtration process. Thus, in addition to the direct infiltration from the reservoir into the aquifer, irrigation using a reservoir water probably has a positive impact on the GW quality in this area.

Investigating geochemical aspects of managed aquifer recharge by column experiments with alternating desalinated water and groundwater.

Science.gov (United States)

Ronen-Eliraz, Gefen; Russak, Amos; Nitzan, Ido; Guttman, Joseph; Kurtzman, Daniel

2017-01-01

Managed aquifer recharge (MAR) events are occasionally carried out with surplus desalinated seawater that has been post-treated with CaCO 3 in infiltration ponds overlying the northern part of the Israeli Coastal Aquifer. This water's chemical characteristics differ from those of any other water recharged to the aquifer and of the natural groundwater. As the MAR events are short (hours to weeks), the sediment under the infiltration ponds will intermittently host desalinated and natural groundwater. As part of comprehensive research on the influence of those events, column experiments were designed to simulate the alternation of the two water types: post-treated desalinated seawater (PTDES) and natural groundwater (GW). Each experiment included three stages: (i) saturation with GW; (ii) inflow of PTDES; (iii) inflow of GW. Three runs were conducted, each with different sediments extracted from the field and representing a different layer below the infiltration pond: (i) sand (<1% CaCO 3 ), (ii) sand containing 7% CaCO 3 , and (iii) crushed calcareous sandstone (35% CaCO 3 ). The results from all columns showed enrichment of K + and Mg 2+ (up to 0.4meq/L for 20 pore volumes) when PTDES replaced GW, whereas an opposite trend of Ca 2+ depletion (up to 0.5meq/L) was observed only in the columns that contained a high percentage of CaCO 3 . When GW replaced PTDES, depletion of Mg 2+ and K + was noted. The results indicated that adsorption/desorption of cations are the main processes causing the observed enrichment/depletion. It was concluded that the high concentration of Ca 2+ (relative to the total concentration of cations) and the low concentration of Mg 2+ in the PTDES relative to natural GW are the factors controlling the main sediment-water interaction. The enrichment of PTDES with Mg 2+ may be viewed as an additional post-treatment. Copyright © 2016 Elsevier B.V. All rights reserved.

Environmental Impact Of The Use Of Contaminated Sediments As Partial Replacement Of The Aggregate Used In Road Construction

Science.gov (United States)

The Indiana Harbor Canal (IHC) is a waterway extensively polluted with heavy metals and petroleum. Since there are limited disposal options for the petroleum-contaminated sediments (PCSs) of the canal, the environmental impact of IHC dewatered sediment when used as partial repla...

Tidal and Seasonal River Stage Fluctuations Impact the Formation of Permeable Natural Reactive Barriers in Riverbank Sediments

Science.gov (United States)

Shuai, P.; Myers, K.; Knappett, P.; Cardenas, M. B.

2017-12-01

River stage fluctuations, induced by ocean tides and rainfall, enhance the exchange between oxic river water and reducing groundwater. When mixing occurs within riverbank aquifers high in dissolved iron (Fe) and arsenic (As), the timing and extent of mixing likely control the accumulation and mobility of arsenic (As) within the hyporheic zone. Here we analyzed the impact of tidal and seasonal water level fluctuations on the formation of a Permeable Natural Reactive Barrier (PNRB) within an aquifer adjacent to the Meghna River, Bangladesh and its impact on As mobility. We found that the periodicity and amplitude of river stage fluctuations strongly control the spatial and temporal distribution of the PNRB, comprised of rapidly precipitated iron oxides, in this riverbank along a relatively straight reach of the Meghna River. The PNRB forms much faster and with higher concentration of Fe-oxide under semi-diurnal (12 hr) tidal fluctuations compared to simulations run assuming only neap-spring tides (14 day). As tidal amplitude increases, a larger contact area between oxic river water and reducing groundwater results which in turn leads to the horizontal expansion of the PNRB into the riverbank. Seasonal fluctuations expand the PNRB up to 60 m horizontally and 5 m vertically. In contrast neap-spring tidal fluctuations result in a smaller PNRB that is 10 and 3 m in the horizontal and vertical dimensions. The predicted changes in the spatial distribution of iron oxides within the riverbank would trap and release As at different times of the year. The PNRB could act as a secondary source of As to drinking water aquifers under sustained groundwater pumping scenarios near the river.

Estimation of uranium migration parameters in sandstone aquifers.

Science.gov (United States)

Malov, A I

2016-03-01

The chemical composition and isotopes of carbon and uranium were investigated in groundwater samples that were collected from 16 wells and 2 sources in the Northern Dvina Basin, Northwest Russia. Across the dataset, the temperatures in the groundwater ranged from 3.6 to 6.9 °C, the pH ranged from 7.6 to 9.0, the Eh ranged from -137 to +128 mV, the total dissolved solids (TDS) ranged from 209 to 22,000 mg L(-1), and the dissolved oxygen (DO) ranged from 0 to 9.9 ppm. The (14)C activity ranged from 0 to 69.96 ± 0.69 percent modern carbon (pmC). The uranium content in the groundwater ranged from 0.006 to 16 ppb, and the (234)U:(238)U activity ratio ranged from 1.35 ± 0.21 to 8.61 ± 1.35. The uranium concentration and (234)U:(238)U activity ratio increased from the recharge area to the redox barrier; behind the barrier, the uranium content is minimal. The results were systematized by creating a conceptual model of the Northern Dvina Basin's hydrogeological system. The use of uranium isotope dating in conjunction with radiocarbon dating allowed the determination of important water-rock interaction parameters, such as the dissolution rate:recoil loss factor ratio Rd:p (a(-1)) and the uranium retardation factor:recoil loss factor ratio R:p in the aquifer. The (14)C age of the water was estimated to be between modern and >35,000 years. The (234)U-(238)U age of the water was estimated to be between 260 and 582,000 years. The Rd:p ratio decreases with increasing groundwater residence time in the aquifer from n × 10(-5) to n × 10(-7) a(-1). This finding is observed because the TDS increases in that direction from 0.2 to 9 g L(-1), and accordingly, the mineral saturation indices increase. Relatively high values of R:p (200-1000) characterize aquifers in sandy-clayey sediments from the Late Pleistocene and the deepest parts of the Vendian strata. In samples from the sandstones of the upper part of the Vendian strata, the R:p value is ∼ 24, i.e., sorption processes are

New extractive technologies for unconventional hydrocarbon exploitation and potential environmental hazards to the Guarani aquifer

International Nuclear Information System (INIS)

Meroni, E.; Pineiro, G.

2014-01-01

This investigation presents a scientific approach about the impact of hydraulic fracturing (f racking) in North America. We focus on the impacts to groundwater, to ascertain whether this technology would produce a similar impact if applied to Norte Basin of Uruguay and a possible impact on the Guarani aquifer. The non- conventional methodologies for hydrocarbon exploitation are described and analysed, taking into account in particular, the characteristics and the profitability of the geological formations that might be potential sources in the Norte Basin of Uruguay. By several in-depth interviews to academic, technic and politic personalities we explored the amount and quality of information that Uruguayan people have about the presence of shale oil and gas resources in the country, as well as on the current normative for their eventual exploitation, and on the contracts that the Uruguayan government has already signed with international oil companies pending the studies required by the current pertinent environmental regulation. The risks for the Guarani Aquifer System if applying hydraulic fracture in rocks directly related to those containing the aquifer, is also analysed

Conceptual and numerical modeling approach of the Guarani Aquifer System

Science.gov (United States)

Rodríguez, L.; Vives, L.; Gomez, A.

2013-01-01

In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormous volume of water; however, it is not well known, being difficult to assess the impact of exploitation currently used to supply over 25 million inhabitants. This is a sensitive issue because the aquifer is shared by four countries. Moreover, an integrated groundwater model, and therefore a global water balance, were not available. In this work, a transient regional scale model for the entire aquifer based upon five simplified, equally plausible conceptual models represented by different hydraulic conductivity parametrizations is used to analyze the flow system and water balance components. Combining an increasing number of hydraulic conductivity zones and an appropriate set of boundary conditions, the hypothesis of a continuous sedimentary unit yielded errors within the calibration target in a regional sense. The magnitude of the water budget terms resulted very similar for all parametrizations. Recharge and stream/aquifer fluxes were the dominant components representing, on average, 84.2% of total inflows and 61.4% of total outflows, respectively. However, leakage was small compared to stream discharges of main rivers. For instance, the simulated average leakage for the Uruguay River was 8 m3 s-1 while the observed absolute minimum discharge was 382 m3 s-1. Streams located in heavily pumped regions switched from a gaining condition in early years to a losing condition over time. Water is discharged through the aquifer boundaries, except at the eastern boundary. On average

Glacial recharge, salinisation and anthropogenic contamination in the coastal aquifers of Recife (Brazil)

Energy Technology Data Exchange (ETDEWEB)

Chatton, E., E-mail: eliot.chatton@gmail.com [Géosciences Rennes, Université Rennes 1-CNRS, UMR 6118, adress: 263 av du général Leclerc, Campus de Beaulieu, bat 15, 35042 Rennes Cedex (France); Aquilina, L., E-mail: luc.aquilina@univ-rennes1.fr [Géosciences Rennes, Université Rennes 1-CNRS, UMR 6118, adress: 263 av du général Leclerc, Campus de Beaulieu, bat 15, 35042 Rennes Cedex (France); Pételet-Giraud, E., E-mail: e.petelet@brgm.fr [Bureau de Recherches Géologiques et Minières (BRGM), adress: 3 avenue Claude-Guillemin, BP 36009, 45060 Orléans Cedex 2 (France); Cary, L., E-mail: l.cary@brgm.fr [Bureau de Recherches Géologiques et Minières (BRGM), adress: 3 avenue Claude-Guillemin, BP 36009, 45060 Orléans Cedex 2 (France); Bertrand, G., E-mail: guillaume353@gmail.com [Instituto de Geociências, CEPAS (Groundwater Research Center), University of São Paulo, adress: Rua do lago 562, 05508-080 Sao Paulo (Brazil); Labasque, T., E-mail: thierry.labasque@univ-rennes1.fr [Géosciences Rennes, Université Rennes 1-CNRS, UMR 6118, adress: 263 av du général Leclerc, Campus de Beaulieu, bat 15, 35042 Rennes Cedex (France); and others

2016-11-01

Implying large residence times and complex water origins deep coastal aquifers are of particular interest as they are remarkable markers of climate, water use and land use changes. Over the last decades, the Metropolitan Region of Recife (Brazil) went through extensive environmental changes increasing the pressure on water resources and giving rise to numerous environmental consequences on the coastal groundwater systems. We analysed the groundwater of the deep aquifers Cabo and Beberibe that are increasingly exploited. The processes potentially affecting groundwater residence times and flow paths have been studied using a multi-tracer approach (CFCs, SF6, noble gases, 14C, 2H and 18O). The main findings of these investigations show that: (1) Groundwaters of the Cabo and Beberibe aquifers have long residence times and were recharged about 20,000 years ago. (2) Within these old groundwaters we can find palaeo-climate evidences from the last glacial period at the tropics with lower temperatures and dryer conditions than the present climate. (3) Recently, the natural slow dynamic of these groundwater systems was significantly affected by mixing processes with contaminated modern groundwater coming from the shallow unconfined Boa Viagem aquifer. (4) The large exploitation of these aquifers leads to a modification of the flow directions and causes the intrusion through palaeo-channels of saline water probably coming from the Capibaribe River and from the last transgression episodes. These observations indicate that the current exploitation of the Cabo and Beberibe aquifers is unsustainable regarding the long renewal times of these groundwater systems as well as their ongoing contamination and salinisation. The groundwater cycle being much slower than the human development rhythm, it is essential to integrate the magnitude and rapidity of anthropogenic impacts on this extremely slow cycle to the water management concepts. - Highlights: • Study of anthropogenic impacts

Glacial recharge, salinisation and anthropogenic contamination in the coastal aquifers of Recife (Brazil)

International Nuclear Information System (INIS)

Chatton, E.; Aquilina, L.; Pételet-Giraud, E.; Cary, L.; Bertrand, G.; Labasque, T.

2016-01-01

Implying large residence times and complex water origins deep coastal aquifers are of particular interest as they are remarkable markers of climate, water use and land use changes. Over the last decades, the Metropolitan Region of Recife (Brazil) went through extensive environmental changes increasing the pressure on water resources and giving rise to numerous environmental consequences on the coastal groundwater systems. We analysed the groundwater of the deep aquifers Cabo and Beberibe that are increasingly exploited. The processes potentially affecting groundwater residence times and flow paths have been studied using a multi-tracer approach (CFCs, SF6, noble gases, 14C, 2H and 18O). The main findings of these investigations show that: (1) Groundwaters of the Cabo and Beberibe aquifers have long residence times and were recharged about 20,000 years ago. (2) Within these old groundwaters we can find palaeo-climate evidences from the last glacial period at the tropics with lower temperatures and dryer conditions than the present climate. (3) Recently, the natural slow dynamic of these groundwater systems was significantly affected by mixing processes with contaminated modern groundwater coming from the shallow unconfined Boa Viagem aquifer. (4) The large exploitation of these aquifers leads to a modification of the flow directions and causes the intrusion through palaeo-channels of saline water probably coming from the Capibaribe River and from the last transgression episodes. These observations indicate that the current exploitation of the Cabo and Beberibe aquifers is unsustainable regarding the long renewal times of these groundwater systems as well as their ongoing contamination and salinisation. The groundwater cycle being much slower than the human development rhythm, it is essential to integrate the magnitude and rapidity of anthropogenic impacts on this extremely slow cycle to the water management concepts. - Highlights: • Study of anthropogenic impacts

Pollutant sources in an arsenic-affected multilayer aquifer in the Po Plain of Italy: Implications for drinking-water supply.

Science.gov (United States)

Rotiroti, Marco; McArthur, John; Fumagalli, Letizia; Stefania, Gennaro A; Sacchi, Elisa; Bonomi, Tullia

2017-02-01

In aquifers 160 to 260m deep that used for public water-supply in an area ~150km 2 around the town of Cremona, in the Po Plain of Northern Italy, concentrations of arsenic (As) are increasing with time in some wells. The increase is due to drawdown of As-polluted groundwater (As ≤144μg/L) from overlying aquifers at depths 65 to 150m deep in response to large-scale abstraction for public supply. The increase in As threatens drinking-water quality locally, and by inference does so across the entire Po Plain, where natural As-pollution of groundwater (As >10μg/L) is a basin-wide problem. Using new and legacy data for Cl/Br, δ 18 O/δ 2 H and other hydrochemical parameters with groundwater from 32 wells, 9 surface waters, a sewage outfall and rainwater, we show that the deep aquifer (160-260m below ground level), which is tapped widely for public water-supply, is partly recharged by seepage from overlying aquifers (65-150m below ground level). Groundwater quality in deep aquifers appears free of anthropogenic influences and typically water in some, not all, areas are affected by anthropogenic contamination and natural As-pollution (As >10μg/L). Outfalls from sewage-treatment plants and black water from septic tanks firstly affect surface waters, which then locally infiltrate shallow aquifers under high channel-stages. Wastewater permeating shallow aquifers carries with it NO 3 and SO 4 which suppress reduction of iron oxyhydroxides in the aquifer sediments and so suppress the natural release of As to groundwater. Copyright © 2016 Elsevier B.V. All rights reserved.

Impact assessment of rainfall-vegetation on sedimentation and predicting erosion-prone region by GIS and RS

Directory of Open Access Journals (Sweden)

Mahboob Alam

2016-03-01

Full Text Available Water reservoirs are facing universal sedimentation problems worldwide. Land covers, whether natural or manmade, eventually change, and the vegetation cover and rainfall have a great effect on the sediment load. Traditional techniques for analysing this problem are time-consuming and spatially limited. Remote sensing (RS provides a convenient way to observe land cover changes, and geographic information system (GIS provides tools for geographic analysis. This study demonstrates a GIS-based methodology for calculating the impact of vegetation and rainfall on the sediment load using remotely sensed data. Moderate resolution imaging spectroradiometer data were used to observe temporal changes in the vegetation-cover area of the watershed surface. The total drainage area for the reservoir was calculated from shuttle radar topographic mission data. The annual rainfall amount was used to compute the annual available rainwater for the watershed, and the impact of the annual available rainwater on the vegetation-covered area was determined. In addition, areas that were adding sedimentation to the reservoir were identified. An inverse relationship between the rainfall and vegetation cover was observed, clearly showing the triggering of erosion.

Water withdrawals and trends from the Floridan aquifer system in the southeastern United States, 1950-2000

Science.gov (United States)

Marella, Richard L.; Berndt, Marian P.

2005-01-01

The Floridan aquifer system in the southeastern United States is one of the most productive aquifers in the world (Miller, 1990). This aquifer system underlies an area of about 100,000 square miles in southern Alabama, eastern and southern Georgia, southeastern Mississippi, southern South Carolina, and all of Florida. The Floridan aquifer system is the primary source of water for nearly 10 million people and supports agriculture, industry, and tourism throughout most of the region. In most areas, water from this aquifer is potable and needs very little treatment before use. However, in southern Florida (south of Lake Okeechobee), northwestern Florida and southern Alabama and Mississippi (Pensacola and westward), and eastern South Carolina, water in the aquifer system generally is not potable. The purpose of this report is to: Provide a general description of the Floridan aquifer system; Discuss water withdrawals by category for 2000; Highlight trends in water withdrawals between 1950 and 2000; and Provide a brief summary on the effects that human impacts have on the Floridan aquifer system.

Regional Sediment Analysis of Mississippi River Sediment Transport and Hydrographic Survey Data

National Research Council Canada - National Science Library

Thorne, Colin

2002-01-01

...s. Sediments generated through channel instability are carried downstream to cause sedimentation problems in flood control channels, destroy wetlands and lakes, adversely impact fish and wildlife...

Aquifer test to determine hydraulic properties of the Elm aquifer near Aberdeen, South Dakota

Science.gov (United States)

Schaap, Bryan D.

2000-01-01

The Elm aquifer, which consists of sandy and gravelly glacial-outwash deposits, is present in several counties in northeastern South Dakota. An aquifer test was conducted northeast of Aberdeen during the fall of 1999 to determine the hydraulic properties of the Elm aquifer in that area. An improved understanding of the properties of the aquifer will be useful in the possible development of the aquifer as a water resource. Historical water-level data indicate that the saturated thickness of the Elm aquifer can change considerably over time. From September 1977 through November 1985, water levels at three wells completed in the Elm aquifer near the aquifer test site varied by 5.1 ft, 9.50 ft, and 11.1 ft. From June 1982 through October 1999, water levels at five wells completed in the Elm aquifer near the aquifer test site varied by 8.7 ft, 11.4 ft, 13.2 ft, 13.8 ft, and 19.7 ft. The water levels during the fall of 1999 were among the highest on record, so the aquifer test was affected by portions of the aquifer being saturated that might not be saturated during drier times. The aquifer test was conducted using five existing wells that had been installed prior to this study. Well A, the pumped well, has an operating irrigation pump and is centrally located among the wells. Wells B, C, D, and E are about 70 ft, 1,390 ft, 2,200 ft, and 3,100 ft, respectively, in different directions from Well A. Using vented pressure transducers and programmable data loggers, water-level data were collected at the five wells prior to, during, and after the pumping, which started on November 19, 1999, and continued a little over 72 hours. Based on available drilling logs, the Elm aquifer near the test area was assumed to be unconfined. The Neuman (1974) method theoretical response curves that most closely match the observed water-level changes at Wells A and B were calculated using software (AQTESOLV for Windows Version 2.13-Professional) developed by Glenn M. Duffield of Hydro

Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

Science.gov (United States)

Gonthier, Gerard; Clarke, John S.

2016-06-02

Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer.Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface.A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow.Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of

Water-level altitudes 2011 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2010 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Science.gov (United States)

Johnson, Michaela R.; Ramage, Jason K.; Kasmarek, Mark C.

2011-01-01

Most of the subsidence in the Houston–Galveston region has occurred as a direct result of groundwater withdrawals for municipal supply, industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers causing compaction of the clay layers of the aquifer sediments. This report, prepared by the U.S. Geological Survey, in cooperation with the Harris–Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, and Lone Star Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction in the Chicot and Evangeline aquifers in the Houston–Galveston region. The report contains maps showing 2011 water-level altitudes for the Chicot, Evangeline, and Jasper aquifers; maps showing 1-year (2010–11) water-level-altitude changes for each aquifer; maps showing 5-year (2006–11) water-level-altitude changes for each aquifer; maps showing long-term (1990–2011 and 1977–2011) water-level-altitude changes for the Chicot and Evangeline aquifers; a map showing long-term (2000–11) water-level-altitude change for the Jasper aquifer; a map showing locations of borehole extensometer sites; and graphs showing measured compaction of subsurface material at the extensometers from 1973, or later, through 2010. Tables listing the data used to construct each aquifer-data map and the compaction graphs are included.Water levels in the Chicot, Evangeline, and Jasper aquifers were measured during December 2010–February 2011. In 2011, water-level-altitude contours for the Chicot aquifer ranged from 200 feet below North American Vertical Datum of 1988 (hereinafter, datum) in a small area in southwestern Harris County to 200 feet above datum in central to southwestern Montgomery County. Water-level-altitude changes in the Chicot aquifer ranged from a 40-foot decline to a 33-foot rise (2010–11), from a 10-foot

Water-level altitudes 2010 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2009 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Science.gov (United States)

Kasmarek, Mark C.; Johnson, Michaela R.; Ramage, Jason K.

2010-01-01

Most of the subsidence in the Houston-Galveston region has occurred as a direct result of groundwater withdrawals for municipal supply, industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers causing compaction of the clay layers of the aquifer sediments. This report, prepared by the U.S. Geological Survey, in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, and Lone Star Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction in the Chicot and Evangeline aquifers in the Houston-Galveston region. The report contains maps showing 2010 water-level altitudes for the Chicot, Evangeline, and Jasper aquifers, respectively; maps showing 1-year (2009-10) water-level-altitude changes for each aquifer; maps showing 5-year (2005-10) water-level-altitude changes for each aquifer; maps showing long-term (1990-2010 and 1977-2010) water-level-altitude changes for the Chicot and Evangeline aquifers; a map showing long-term (2000-10) water-level-altitude change for the Jasper aquifer; a map showing locations of borehole extensometer sites; and graphs showing measured compaction of subsurface material at the extensometers from 1973, or later, through 2009. Tables listing the data used to construct each aquifer-data map and the compaction graphs are included. Water levels in the Chicot, Evangeline, and Jasper aquifers were measured during December 2009-March 2010. In 2010, water-level-altitude contours for the Chicot aquifer ranged from 200 feet below National Geodetic Vertical Datum of 1929 or North American Vertical Datum of 1988 (hereinafter, datum) in a small area in southwestern Harris County to 200 feet above datum in central to southwestern Montgomery County. Water-level-altitude changes in the Chicot aquifer ranged from a 49-foot decline to a 67

Impact of methane flow through deformable lake sediments on atmospheric release

Science.gov (United States)

Scandella, B.; Juanes, R.

2010-12-01

Methane is a potent greenhouse gas that is generated geothermally and biologically in lake and ocean sediments. Free gas bubbles may escape oxidative traps and contribute more to the atmospheric source than dissolved methane, but the details of the methane release depend on the interactions between the multiple fluid phases and the deformable porous medium. We present a model and supporting laboratory experiments of methane release through “breathing” dynamic flow conduits that open in response to drops in the hydrostatic load on lake sediments, which has been validated against a high-resolution record of free gas flux and hydrostatic pressure in Upper Mystic Lake, MA. In contrast to previous linear elastic fracture mechanics analysis of gassy sediments, the evolution of gas transport in a deformable compliant sediment is presented within the framework of multiphase poroplasticity. Experiments address how strongly the mode and rate of gas flow, captured by our model, impacts the size of bubbles released into the water column. A bubble's size in turn determines how efficiently it transports methane to the atmosphere, and integrating this effect will be critical to improving estimates of the atmospheric methane source from lakes. Cross-sectional schematic of lake sediments showing two venting sites: one open at left and one closed at right. The vertical release of gas bubbles (red) at the open venting site creates a local pressure drop, which drives both bubble formation from the methane-rich pore water (higher concentrations shaded darker red) and lateral advection of dissolved methane (purple arrows). Even as bubbles in the open site escape, those at the closed site remain trapped.

Climate change and the impact of increased rainfall variability on sediment transport and catchment scale water quality

Science.gov (United States)

Hancock, G. R.; Willgoose, G. R.; Cohen, S.

2009-12-01

Recently there has been recognition that changing climate will affect rainfall and storm patterns with research directed to examine how the global hydrological cycle will respond to climate change. This study investigates the effect of different rainfall patterns on erosion and resultant water quality for a well studied tropical monsoonal catchment that is undisturbed by Europeans in the Northern Territory, Australia. Water quality has a large affect on a range of aquatic flora and fauna and a significant change in sediment could have impacts on the aquatic ecosystems. There have been several studies of the effect of climate change on rainfall patterns in the study area with projections indicating a significant increase in storm activity. Therefore it is important that the impact of this variability be assessed in terms of catchment hydrology, sediment transport and water quality. Here a numerical model of erosion and hydrology (CAESAR) is used to assess several different rainfall scenarios over a 1000 year modelled period. The results show that that increased rainfall amount and intensity increases sediment transport rates but predicted water quality was variable and non-linear but within the range of measured field data for the catchment and region. Therefore an assessment of sediment transport and water quality is a significant and complex issue that requires further understandings of the role of biophysical feedbacks such as vegetation as well as the role of humans in managing landscapes (i.e. controlled and uncontrolled fire). The study provides a robust methodology for assessing the impact of enhanced climate variability on sediment transport and water quality.

The microbial nitrogen cycling potential in marine sediments is impacted by polyaromatic hydrocarbon pollution

Directory of Open Access Journals (Sweden)

Nicole M Scott

2014-03-01

Full Text Available During petroleum hydrocarbon exposure the composition and functional dynamics of marine microbial communities are altered, favoring bacteria that can utilize this rich carbon source. Initial exposure of high levels of hydrocarbons in aerobic surface sediments can enrich growth of heterotrophic microorganisms having hydrocarbon degradation capacity. As a result, there can be a localized reduction in oxygen potential, if the sediments are aerobic, within the surface layer of marine sediments resulting in anaerobic zones. We hypothesized that increasing exposure to elevated hydrocarbon concentrations would positively correlate with an increase in denitrification processes and the net accumulation of dinitrogen. This hypothesis was tested by comparing the relative abundance of genes associated with nitrogen metabolism and nitrogen cycling identified in 6 metagenomes from sediments contaminated by polyaromatic hydrocarbons from the Deepwater Horizon oil spill in the Gulf of Mexico, and 3 metagenomes from sediments associated with natural oil seeps in the Santa Barbara Channel. An additional 8 metagenomes from uncontaminated sediments from the Gulf of Mexico were analyzed for comparison. We predicted relative changes in metabolite turnover as a function of the differential microbial gene abundances, which showed predicted accumulation of metabolites associated with denitrification processes, including anammox, in the contaminated samples compared to uncontaminated sediments, with the magnitude of this change being positively correlated to the hydrocarbon concentration and exposure duration. These data highlight the potential impact of hydrocarbon inputs on N cycling processes in marine sediments and provide information relevant for system scale models of nitrogen metabolism in affected ecosystems.

Vertical variability of arsenic concentrations under the control of iron-sulfur-arsenic interactions in reducing aquifer systems

Science.gov (United States)

Pi, Kunfu; Wang, Yanxin; Postma, Dieke; Ma, Teng; Su, Chunli; Xie, Xianjun

2018-06-01

High spatial variability of arsenic (As) concentration in geogenic As-contaminated groundwater has been commonly observed worldwide, but the underlying reasons remain not well understood. Selecting a sulfate-containing, As-affected aquifer at the Datong Basin, northern China as the study area and combining hydrogeochemical investigation and sediment extraction with reactive transport modeling, this work elucidated the roles of Fe-S-As interactions in regulating the vertical variation of As concentration in the groundwater. Dissolved As concentration varied between 0.05 and 18 μmol/L, but generally increased in the depth of 20-25 m and then decreased in 25-30 m. The high-As groundwater contained low Fe(II) (groundwater devoid of sulfate reduction. The reductive dissolution of As-bearing Fe(III) oxides coupled to the degradation of organic matter with an estimated maximum rate of 0.22 mmol C/L/yr, mainly accounted for the depth-dependent increase of As concentration in the upper part of the shallow aquifer (groundwater but also probably co-precipitated As to prompt As decrease in the depth of 25-30 m. Arsenite adsorbed on remaining Fe(III) oxides and newly-formed Fe(II) sulfides is another important pool of As in the aquifer, which varies in response to the extents of Fe(III)-oxide and sulfate reduction and consequently alters As distribution coefficient between the solid and the aqueous phases. This study highlights the importance of coupled geochemical cycling of Fe, S and As for As mobilization and reveals how it regulates As partitioning between groundwater and sediments.

Guarani aquifer hydrogeological synthesis of the Guarani aquifer system. Edicion bilingue

International Nuclear Information System (INIS)

2009-01-01

This work represents the synthesis of current knowledge of the Guarani Aquifer System, based on technical products made by different companies and consultants who participated in the framework of the Project for Environmental Protection and Sustainable Development of the Guarani Aquifer.

Global assessment of coastal aquifer state and its vulnerability respect to Sea Water Intrusion. Application to several Mediterranean Coastal Aquifers.

Science.gov (United States)

Baena, Leticia; Pulido-Velazquez, David; Renau-Pruñonosa, Arianna; Morell, Ignacio

2017-04-01

In this research we propose a method for a global assessment of coastal aquifer state and its vulnerability to Sea Water Intrusion (SWI). It is based on two indices, the MART index, which summarize the global significance of the SWI phenomenon, and the L_GALDIT for a lumped assessment of the vulnerability to SWI. Both of them can be useful as a tool to assess coastal groundwater bodies in risk of not achieving good status in accordance with the Water Framework Directive (WFD, 2000) and to identify possible management alternative to reduce existing impacts. They can be obtained even from a reduced number of data (in the MART case only depend on the geometry and available aquifer state data) with simple calculations, which have been implemented in a general GIS tool that can be easily applied to other case studies. The MART index in an aquifer is related with the total mass of chloride in the aquifer due to sea water intrusion and can be obtained by simple linear operations of volume and concentrations that can be deduced from a schematic conceptual cross-section approach (orthogonal to the shore line) defined to summarize the intrusion volume in the aquifer. At a certain historical time, this representative aquifer cross-section can be defined in a systhematic way from the aquifer geometry, the specific yield, and the hydraulic head and chloride concentration fields that can be deduced from the available information by using appropriate interpolation methods. Following the proposed procedure we will finally obtain a summary of the historical significance of the SWI in an aquifer at different spatial resolution: 3D salinity concentration maps, 2D representative conceptual cross-section of intrusion and the MART lumped significance index. The historical evolution of the MART can be employed to perform a global assessment of the resilience and trends of global significance of the SWI in an aquifer. It can be useful to compare the significance of intrusion problems in