Sample records for hot muonic hydrogen

  1. Muonic processes in solid hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, G.M.; Beveridge, J.L. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC (Canada); Bailey, J.M. [Chester Technology, Chester (United Kingdom); Beer, G.A.; Knowles, P.E.; Maier, M.; Mason, G.R.; Olin, A.; Porcelli, T.A. [University of Victoria, Victoria, BC (Canada); Fujiwara, M.C. [University of British Columbia, Vancouver, BC (Canada); Huber, T.M. [Gustavus Adolphus College, St. Peter, Minnesota (United States); Jacot-Guillarmod, R.; Mulhauser, F.; Schaller, L.A. [University of Fribourg, Fribourg (Switzerland); Kammel, P. [Lawrence Berkeley Laboratory, Berkeley, California (United States); Kim, S.K. [Jeonbuk National University, Jeonju City, S. (Korea); Kunselman, A.R. [University of Wyoming, Laramie, Wyoming (United States); Petitjean, C. [PSI, Villigen (Switzerland); Zmeskal, J. [IMEP, Vienna (Austria)


    Muonic hydrogen participates in many different interactions, including muon induced fusion of hydrogen nuclei. Conventional experimental techniques cannot always unravel and separate the processes of interest. Some of the most important measurements may be more reliably accomplished with the use of a unique and versatile target consisting of layers of different solid hydrogen isotope mixtures. {copyright} {ital 1998 American Institute of Physics.}

  2. Scattering of muonic hydrogen atoms

    Energy Technology Data Exchange (ETDEWEB)

    Mulhauser, F. [Universite de Fribourg (Switzerland); Adamczak, A. [Institute of Nuclear Physics (Poland); Beer, G.A. [University of Victoria (Canada); Bystritsky, V.M. [Joint Institute for Nuclear Research (Russian Federation); Filipowicz, M. [Institute of Physics and Nuclear Techniques (Poland); Fujiwara, M.C. [University of British Columbia (Canada); Huber, T.M. [Gustavus Adolphus College (United States); Jacot-Guillarmod, R. [Universite de Fribourg (Switzerland); Kammel, P. [University of California (United States); Kim, S.K. [Jeonbuk National University (Korea, Republic of); Knowles, P. [Universite de Fribourg (Switzerland); Kunselman, A.R. [University of Wyoming (United States); Maier, M. [University of Victoria (Canada); Markushin, V.E. [Paul Scherrer Institute (Switzerland); Marshall, G.M. [TRIUMF (Canada); Olin, A. [University of Victoria (Canada); Petitjean, C. [Paul Scherrer Institute (Switzerland); Porcelli, T.A. [University of Victoria (Canada); Stolupin, V.A. [Joint Institute for Nuclear Research (Russian Federation); Wozniak, J. [Institute of Physics and Nuclear Techniques (Poland)] (and others)


    Our measurement compares the energy dependence of the scattering cross-sections of muonic deuterium and tritium on hydrogen molecules for collisions in the energy range 0.1-45 eV. A time-of-flight method was used to measure the scattering cross-section as a function of the muonic atom beam energy and shows clearly the Ramsauer-Townsend effect. The results are compared with theoretical calculations by using Monte Carlo simulations. The molecular pd{mu} and pt{mu} formation creates background processes. We measure the formation rates in solid hydrogen by detecting the 5.5 MeV (pd{mu}) and 19.8 MeV (pt{mu}) {gamma}-rays emitted during the subsequent nuclear fusion processes.

  3. Muonium/muonic hydrogen formation in atomic hydrogen

    Indian Academy of Sciences (India)

    Abstract. The muonium/muonic hydrogen atom formation in µ±–H collisions is in- vestigated, using a two-state approximation in a time dependent formalism. It is found that muonium cross-section results are similar to the cross-section results obtained for positronium formation in e+–H collision. Muonic hydrogen atom ...

  4. Resonant Scattering of Muonic Hydrogen Atoms and Dynamics of the Muonic Molecular Complex

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, M. C., E-mail: [University of British Columbia (Canada); Adamczak, A. [Institute Nuclear Physics (Poland); Bailey, J. M. [Chester Technology (United Kingdom); Beer, G. A. [University of Victoria (Canada); Beveridge, J. L. [TRIUMF (Canada); Faifman, M. P. [Kurchatov Institute (Russian Federation); Huber, T. M. [Gustavus Adolphus College (United States); Kammel, P. [University of Illinois at Urbana-Champaign (United States); Kim, S. K. [Jeonbuk National University (Korea, Republic of); Knowles, P. E. [Universite de Fribourg (Switzerland); Kunselman, A. R. [University of Wyoming (United States); Markushin, V. E. [Paul Scherrer Institute (Switzerland); Marshal, G. M. [TRIUMF (Canada); Mason, G. R. [University of Victoria (Canada); Mulhauser, F. [Universite de Fribourg (Switzerland); Olin, A. [TRIUMF (Canada); Petitjean, C. [Paul Scherrer Institute (Switzerland); Porcelli, T. A. [University of Northern British Columbia (Canada); Wozniak, J. [Institute Physics and Nuclear Techniques (Poland); Zmeskal, J. [Austrian Academy of Sciences (Austria)


    Resonant scattering of muonic hydrogen atoms via back decay of the molecular complex, a key process in the understanding of epithermal muonic molecular formation, is analyzed. The limitations of the effective rate approximation are discussed and the importance of the explicit treatment of the back decay is stressed. An expression of the energy distribution for the back-decayed atoms is given.

  5. Effective field theories for muonic hydrogen

    Directory of Open Access Journals (Sweden)

    Peset Clara


    Full Text Available Experimental measurements of muonic hydrogen bound states have recently started to take place and provide a powerful setting in which to study the properties of QCD. We profit from the power of effective field theories (EFTs to provide a theoretical framework in which to study muonic hydrogen in a model independent fashion. In particular, we compute expressions for the Lamb shift and the hyperfine splitting. These expressions include the leading logarithmic O(mμα6 terms, as well as the leading O(mμα5mμ2ΛQCD2${\\cal O}\\left( {{m_\\mu }{\\alpha ^5}{{m_\\mu ^2} \\over {\\Lambda _{{\\rm{QCD}}}^2}}} \\right$ hadronic effects. Most remarkably, our analyses include the determination of the spin-dependent and spin-independent structure functions of the forward virtualphoton Compton tensor of the proton to O(p3 in HBET and including the Delta particle. Using these results we obtain the leading hadronic contributions to the Wilson coeffcients of the lepton-proton four fermion operators in NRQED. The spin-independent coeffcient yields a pure prediction for the two-photon exchange contribution to the muonic hydrogen Lamb shift, which is the main source of uncertainty in our computation. The spindependent coeffcient yields the prediction of the hyperfine splitting. The use of EFTs crucially helps us organizing the computation, in such a way that we can clearly address the parametric accuracy of our result. Furthermore, we review in the context of NRQED all the contributions to the energy shift of O(mμα5, as well as those that scale like mrα6× logarithms.

  6. Muonic hydrogen spectroscopy: the proton radius puzzle (United States)

    Antognini, Aldo; Nez, François; Amaro, Fernando D.; Biraben, François; Cardoso, João M. R.; Covita, Daniel S.; Dax, Andreas; Dhawan, Satish; Fernandes, Luis M. P.; Giesen, Adolf; Graf, Thomas; Hänsch, Theodor W.; Indelicato, Paul; Julien, Lucile; Kao, Cheng-Yang; Knowles, Paul; Kottmann, Franz; Le Bigot, Eric-Olivier; Liu, Yi-Wei; Lopes, José A. M.; Ludhova, Livia; Monteiro, Cristina M. B.; Mulhauser, Françoise; Nebel, Tobias; Rabinowitz, Paul; Dos Santos, Joaquim M. F.; Schaller, Lukas A.; Schuhmann, Karsten; Schwob, Catherine; Taqqu, David; Veloso, João F. C. A.; Pohl, Randolf


    By means of pulsed laser spectroscopy applied to muonic hydrogen (μ¯p) we havemeasured the 2S (F=1)/(1/2) - 2P(F=2)/(3/2) transition frequency to be 49881.88(76)GHz.1 By comparing this measurement with its theoretical prediction 2-7 based on bound-state QED we have determined a proton radius value of rP =0.84184(67) fm. This new value differs by 5.0 standard deviations from the CODATA value of 0.8768(69) fm,8 and 3 standard deviation from the e-p scattering results of 0.897(18) fm.9 The observed discrepancy may arise from a computational mistake of the energy levels in μp or H, or a fundamental problem in bound-state QED, an unknown effect related to the proton or the muon, or an experimental error.

  7. Proton structure in the hyperfine splitting of muonic hydrogen


    Hagelstein, Franziska; Pascalutsa, Vladimir


    We present the leading-order prediction of baryon chiral perturbation theory for the proton polarizability contribution to the 2S hyperfine splitting in muonic hydrogen, and compare with the results of dispersive calculations.

  8. The Lamb shift in muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Nebel, Tobias


    The subject of this thesis is the first measurement of the 2S-2P Lamb shift in muonic hydrogen ({mu}p). In this project, which has been performed at the proton-accelerator facility of the Paul-Scherrer-Institute in Switzerland, the exotic analogon to the classical Lamb shift in hydrogen has been examined by laser spectroscopy. Negative muons are produced at a specially developed low-energy muon beam at a rate of 330 s{sup -1} and are stopped in 1 hPa of H{sub 2} gas. In the gas, highly excited {mu}p atoms are formed, most of which promptly cascade to the ground state within {proportional_to}100 ns. Only a fraction of 1.1% forms {mu}p atoms in the long-lived 2S state with a lifetime of 1.0 {mu}s. An elaborate laser system triggered on every incoming muon delivers 0.2 mJ laser pulses at {lambda}{approx_equal}6 {mu}m with 500 s{sup -1} repetition rate. The laser illuminates the {mu}p atoms 900 ns after the prompt muon cascade inducing the 2S-2P transition when on resonance. A 1.9 keV K{sub {alpha}} X-ray is emitted in the subsequent deexcitation to the 1S ground state and is recorded by large area avalanche photodiodes. The laser induced K{sub {alpha}} events are clearly distinguishable from the exponential background. For the 2S{sub 1/2}{sup F=1} - 2P{sub 3/2}{sup F=2} transition in {mu}p, it is given by {nu}{sub 2S-2P}=49 881 695 (711)MHz with a relative accuracy of 1.4 x 10{sup -5}. Assuming the correctness of the bound-state QED calculations of the Lamb shift in {mu}p, a new value for the rms proton charge radius r{sub p} can be derived: r{sub p}=0:84192(65) fm. Using the precisely measured 1S-2S transition frequency in hydrogen (relative accuracy of 1.4 parts in 10{sup 14}) and combining it with our new value of r{sub p}, a new value for the Rydberg constant R{sub {infinity}} can be derived with a relative accuracy of 1.5 parts in 10{sup 12}: R{sub {infinity}}=10 973 731.568 161(16)m{sup -1}. Beside the 2S{sub 1/2}{sup F=1}-2P{sub 3/2}{sup F=2} transition in {mu

  9. Time-of-flight spectroscopy of muonic hydrogen atoms and molecules

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, M.C. [Dept. of Physics and Astronomy, Univ. of British Columbia, Vancouver, BC (Canada)]|[Dept. of Physics, Faculty of Science, Univ. of Tokyo (Japan); Adamczak, A. [Inst. of Nuclear Physics, Krakow (Poland); Bailey, J.M. [Chester Technology, Chester (United Kingdom); Beer, G.A.; Mason, G.R. [Dept. of Physics and Astronomy, Univ. of Victoria, BC (Canada); Beveridge, J.L.; Marshall, G.M.; Olin, A. [TRIUMF, Vancouver, BC (Canada); Faifman, M.P. [Russian Research Center, Kurchatov Inst., Moscow (Russian Federation); Huber, T.M. [Dept. of Physics, Gustavus Adolphus Coll., St. Peter, MN (United States); Kammel, P. [Dept. of Physics and Lawrence Berkeley National Lab., Univ. of California, Berkeley, CA (United States); Kim, S.K. [Dept. of Physics, Jeonbuk National Univ., Jeonju City (Korea); Knowles, P.E.; Mulhauser, F. [Inst. of Physics, Univ. of Fribourg (Switzerland); Kunselman, A.R. [Dept. of Physics and Astronomy, Univ. of Wyoming, Laramie, WY (United States); Markushin, V.E.; Petitjean, C. [Paul Scherrer Inst., Villigen (Switzerland); Porcelli, T.A. [Dept. of Physics, Univ. of Northern British Columbia, Prince George, BC (Canada); Zmeskal, J. [Inst. for Medium Energy Physics, Austrian Academy of Sciences, Vienna (Austria)


    Studies of muonic hydrogen atoms and molecules have been performed traditionally in bulk targets of gas, liquid or solid. At TRIUMF, Canada's meson facility, we have developed a new type of target system using multilayer thin films of solid hydrogen, which provides a beam of muonic hydrogen atoms in vacuum. Using the time-of-flight of the muonic atoms, the energy-dependent information of muonic reactions are obtained in direct manner.We discuss some unique measurements enabled by the new technique, with emphasis on processes relevant to muon catalyzed fusion.

  10. Generation of the Ultracold Muonic Hydrogen Flux

    Energy Technology Data Exchange (ETDEWEB)

    Bystritsky, V. M. [Joint Institute for Nuclear Research (Russian Federation); Adamczak, A. [Institute of Nuclear Physics (Poland); Beer, G. A. [University of Victoria (Canada); Filipowicz, M. [Institute of Physics and Nuclear Techniques (Poland); Fujiwara, M. C. [University of Tokyo (Japan); Huber, T. M. [Gustavus Adolphus College (United States); Jacot-Guillarmod, R. [Universite de Fribourg (Switzerland); Kammel, P. [University of Illinois at Urbana-Champaign (United States); Kim, S. K. [Jeonbuk National University (Korea, Republic of); Knowles, P. [Universite de Fribourg (Switzerland); Kunselman, A. R. [University of Wyoming (United States); Maier, M. [University of Victoria (Canada); Markushin, V. E. [Paul Scherrer Institute (Switzerland); Marshall, G. M. [TRIUMF (Canada); Mulhauser, F. [Universite de Fribourg (Switzerland); Olin, A. [University of Victoria (Canada); Petitjean, C. [Paul Scherrer Institute (Switzerland); Porcelli, T. A. [University of Northen British Columbia (Canada); Stolupin, V. A. [Joint Institute for Nuclear Research (Russian Federation); Wozniak, J. [Institute of Physics and Nuclear Techniques (Poland)


    We present the study of {mu}p atom scattering in solid hydrogen. Anomalously large emission of E{sub p{mu}{<=}1}.9 meV {mu}p's from a solid H{sub 2} layer was observed for the first time. This three times greater {mu}p atom yield is due to non-elastic phonon scattering. As a result, it becomes possible to generate an ultracold flux of {mu}p atoms. The recent calculations of the total and differential cross sections agree with all experimental results of {mu}p atom scattering in solid H{sub 2}.

  11. Measurement of the Formation Rate of Muonic Hydrogen Molecules

    CERN Document Server

    Andreev, V A; Carey, R M; Case, T A; Clayton, S M; Crowe, K M; Deutsch, J; Egger, J; Freedman, S J; Ganzha, V A; Gorringe, T; Gray, F E; Hertzog, D W; Hildebrandt, M; Kammel, P; Kiburg, B; Knaack, S; Kravtsov, P A; Krivshich, A G; Lauss, B; Lynch, K R; Maev, E M; Maev, O E; Mulhauser, F; Petitjean, C; Petrov, G E; Prieels, R; Schapkin, G N; Semenchuk, G G; Soroka, M A; Tishchenko, V; Vasilyev, A A; Vorobyov, A A; Vznuzdaev, M E; Winter, P


    Background: The rate \\lambda_pp\\mu\\ characterizes the formation of pp\\mu\\ molecules in collisions of muonic p\\mu\\ atoms with hydrogen. In measurements of the basic weak muon capture reaction on the proton to determine the pseudoscalar coupling g_P, capture occurs from both atomic and molecular states. Thus knowledge of \\lambda_pp\\mu\\ is required for a correct interpretation of these experiments. Purpose: Recently the MuCap experiment has measured the capture rate \\Lambda_S from the singlet p\\mu\\ atom, employing a low density active target to suppress pp\\mu\\ formation (PRL 110, 12504 (2013)). Nevertheless, given the unprecedented precision of this experiment, the existing experimental knowledge in \\lambda_pp\\mu\\ had to be improved. Method: The MuCap experiment derived the weak capture rate from the muon disappearance rate in ultra-pure hydrogen. By doping the hydrogen with 20 ppm of argon, a competing process to pp\\mu\\ formation was introduced, which allowed the extraction of \\lambda_pp\\mu\\ from the observed t...

  12. Muon transfer from muonic hydrogen to heavier atoms; Transfert de charge muonique

    Energy Technology Data Exchange (ETDEWEB)

    Dupays, A


    This work concerns muon transfer from muonic hydrogen to heavier atoms. Recently, a method of measurement of the hyperfine structure of ground-state muonic hydrogen based on the collision energy dependence of the muon transfer rate to oxygen has been proposed. This proposal is based on measurements which where performed at the Paul Scherrer Institute in the early nineties which indicate that the muon transfer from muonic hydrogen to oxygen increases by a factor of 4 going from thermal to 0.12 eV energies. The motivation of our calculations was to confirm this behaviour. To study the collision energy dependence of the muon transfer rate, we have used a time-independent close-coupling method. We have set up an hyperspherical elliptic formalism valid for nonzero total angular momentum which allows accurate computations of state-to-state reactive and charge exchange processes. We have applied this formalism to muon-transfer process to oxygen and neon. The comparison with experimental results is in both cases excellent. Finally, the neon transfer rate dependence with energy suggests to use neon instead of oxygen to perform a measurement of the hyperfine structure of muonic hydrogen. The results of accurate calculations of the muon transfer rates from muonic protium and deuterium atoms to nitrogen, oxygen and neon are also reported. Very good agreement with measured rates is obtained and for the three systems, the isotopic effect is perfectly reproduced. (author)

  13. Transitions between hyperfine-structure states of the 2s metastable muonic hydrogen in collision processes

    Energy Technology Data Exchange (ETDEWEB)

    Czaplinski, W.


    Hyperfine effects in the symmetric collisions of the 2s metastable muonic hydrogen with hydrogen atoms: (p{mu}){sub 2s} + H, (d{mu}){sub 2s} + D, (t{mu}){sub 2s} + t are presented. Elastic and spin-flip cross sections for the scattering of The 2s muonic atoms are calculated in the two-level approximation as a function of collision energy. The corresponding formulae are derived with inclusion of electron screening and Lamb-shift between 2s and 2p energy levels of the muonic atom. The obtained spin-flip cross sections are about two orders of magnitude higher than their ground state counterparts and are much more influenced by electron screening. The rates of the spin-flip transitions are also calculated and are found to be about three orders of magnitude higher than the decay rate of the 2s state. (author). 65 refs, 15 figs, 4 tabs.

  14. Nuclear radiative recoil corrections to the hyperfine structure of S-states in muonic hydrogen (United States)

    Faustov, R. N.; Martynenko, A. P.; Martynenko, F. A.; Sorokin, V. V.


    Nuclear radiative recoil corrections of order α( Zα)5 to the hyperfine splitting of S-states in muonic hydrogen are calculated on the basis of quasipotential method in quantum electrodynamics. The calculation is performed in the infrared safe Fried-Yennie gauge. Modern experimental data on the proton form factors are used.

  15. Quantum interference effects in laser spectroscopy of muonic hydrogen, deuterium, and helium-3 (United States)

    Amaro, Pedro; Franke, Beatrice; Krauth, Julian J.; Diepold, Marc; Fratini, Filippo; Safari, Laleh; Machado, Jorge; Antognini, Aldo; Kottmann, Franz; Indelicato, Paul; Pohl, Randolf; Santos, José Paulo


    Quantum interference between energetically close states is theoretically investigated, with the state structure being observed via laser spectroscopy. In this work, we focus on hyperfine states of selected hydrogenic muonic isotopes, and on how quantum interference affects the measured Lamb shift. The process of photon excitation and subsequent photon decay is implemented within the framework of nonrelativistic second-order perturbation theory. Due to its experimental interest, calculations are performed for muonic hydrogen, deuterium, and helium-3. We restrict our analysis to the case of photon scattering by incident linear polarized photons and the polarization of the scattered photons not being observed. We conclude that while quantum interference effects can be safely neglected in muonic hydrogen and helium-3, in the case of muonic deuterium there are resonances with close proximity, where quantum interference effects can induce shifts up to a few percent of the linewidth, assuming a pointlike detector. However, by taking into account the geometry of the setup used by the CREMA collaboration, this effect is reduced to less than 0.2% of the linewidth in all possible cases, which makes it irrelevant at the present level of accuracy.

  16. Geneva University - Measurement of the Lamb shift in muonic hydrogen: the proton radius puzzle

    CERN Multimedia


    GENEVA UNIVERSITY École de physique Département de physique nucléaire et corspusculaire 24, quai Ernest-Ansermet 1211 GENEVA 4 Tel: (022) 379 62 73 Fax: (022) 379 69 92 Wednesday 12 May 2010 PARTICLE PHYSICS SEMINAR at 17.00 hrs – Stückelberg Auditorium Measurement of the Lamb shift in muonic hydrogen: the proton radius puzzle Dr Aldo Antogninia , CREMA Collaboration, Max Planck Institute, Germany At the Paul Scherrer Institut, Switzerland, we have measured several 2S-2P transition frequencies in muonic hydrogen (µp) and deuterium (µd) by means of laser spectroscopy. This results in an order of magnitude improvement on the rms charge radius values of the proton and the deuteron. Additionally the Zemach radii and the deuteron polarizability are also inferred. The new proton radius value is deduced with a relative accuracy of 0.1% but strongly disagrees from CODATA. The origin of this discrepancy is not yet known. It may come from theo...

  17. Investigation of muonic hydrogen isotopes scattering from H{sub 2} molecule

    Energy Technology Data Exchange (ETDEWEB)

    Jacot-Guillarmod, R.; Mulhauser, F. [Fribourg Univ. (Switzerland); Adamczak, A. [Institute of Nuclear Physics, Cracow (Poland); Beer, G.A.; Knowles, P.E.; Olin, A. [Victoria Univ., BC (Canada); Bystritsky, V.M.; Stolupin, V.A. [Joint Inst. for Nuclear Research, Dubna (Russian Federation); Czaplinski, W.; Filipowicz, M.; Wozniak, J. [Akademia Gorniczo-Hutnicza, Cracow (Poland). Inst. of Physics and Nuclear Technology; Fujiwara, M.C. [British Columbia Univ., Vancouver, BC (Canada); Huber, T.M. [Gustavus Adolphus Coll., St. Peter, MN (United States); Kammel, P. [California Univ., Berkeley, CA (United States); Kunselman, A.R. [Wyoming Univ., Laramie, WY (United States); Markushin, V.E. [Rossijskij Nauchnyj Tsentr ``Kurchatovskij Inst.``, Moscow (Russian Federation); Marshall, G.M. [British Columbia Univ., Vancouver, BC (Canada). TRIUMF Facility; Petitjean, C. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Rivkis, L.A. [VNIINM, Moscow (Russian Federation). Inst. Inorg. Mat.; Zmeskal, J. [Oesterreichische Akademie der Wissenschaften, Vienna (Austria)


    Knowledge of the cross sections for scattering of {mu}H, {mu}D and {mu}T on molecules of hydrogen isotopes is necessary not only for checking the algorithmic solution of the Coulomb three-body problem but also for a general and correct description of the kinetics of muonic and molecular processes in mixtures of hydrogen isotopes. We plan to measure the scattering cross-section energy dependence of the reactions {mu}x + H{sub 2} {yields} {mu}x + H{sub 2} (x = d, t) in the energy collision range from 0.1 to 45 eV, using a multilayered target system recently developed at TRIUMF. (orig.). 33 refs.

  18. Toward the measurement of the hyperfine splitting in the ground state of muonic hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Bakalov, Dimitar, E-mail: [Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy (Bulgaria); Adamczak, Andrzej [Polish Academy of Sciences, Institute of Nuclear Physics (Poland); Stoilov, Mihail [Bulgarian Academy of Sciences, Institute for Nuclear Research and Nuclear Energy (Bulgaria); Vacchi, Andrea [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste (Italy)


    The recent Lamb shift experiment at PSI and the controversy about proton size revived the interest in measuring the hyperfine splitting in muonic hydrogen and extracting the proton Zemach radius. The efficiency of the experimental method depends on the energy dependence of the muon transfer rate to higher-Z gases in the near epithermal energy range. As long as the available experimental data only give the average transfer rate in the whole epithermal range, and the detailed theoretical calculations have not yet been verified, an experiment has been started for the measurement of the transfer rate in thermalized gas target at different temperatures and extracting from the data an estimate of the transfer rate for arbitrary energies. We outline the underlying mathematical method and estimate its accuracy.

  19. Bound-state field-theory approach to proton-structure effects in muonic hydrogen (United States)

    Mohr, Peter J.; Griffith, J.; Sapirstein, J.


    A bound-state field-theory approach to muonic hydrogen is set up using a variant of the Furry representation in which the lowest-order Hamiltonian describes a muon in the presence of a point Coulomb field, but the origin of the binding field is taken to be three charged quarks in the proton, which are modeled as Dirac particles that move freely within a spherical well. Bound-state field-theory techniques are used to evaluate one- and two-photon effects. Particular attention is paid to two-photon-exchange diagrams, which include the effect of proton polarizability. In addition, the modification of the electromagnetic self energy of the proton by the electric field of the muon is examined. Finally, the model is used to carry out a calculation of the static electric polarizability of the proton.

  20. Hot Hydrogen Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    W. David Swank


    The core in a nuclear thermal rocket will operate at high temperatures and in hydrogen. One of the important parameters in evaluating the performance of a nuclear thermal rocket is specific impulse, ISp. This quantity is proportional to the square root of the propellant’s absolute temperature and inversely proportional to square root of its molecular weight. Therefore, high temperature hydrogen is a favored propellant of nuclear thermal rocket designers. Previous work has shown that one of the life-limiting phenomena for thermal rocket nuclear cores is mass loss of fuel to flowing hydrogen at high temperatures. The hot hydrogen test facility located at the Idaho National Lab (INL) is designed to test suitability of different core materials in 2500°C hydrogen flowing at 1500 liters per minute. The facility is intended to test non-uranium containing materials and therefore is particularly suited for testing potential cladding and coating materials. In this first installment the facility is described. Automated Data acquisition, flow and temperature control, vessel compatibility with various core geometries and overall capabilities are discussed.

  1. Deciphering the "chemical" nature of the exotic isotopes of hydrogen by the MC-QTAIM analysis: the positively charged muon and the muonic helium as new members of the periodic table. (United States)

    Goli, Mohammad; Shahbazian, Shant


    This report is a primarily survey on the chemical nature of some exotic species containing the positively charged muon and the muonic helium, i.e., the negatively charged muon plus helium nucleus, as exotic isotopes of hydrogen, using the newly developed multi-component quantum theory of atoms in molecules (MC-QTAIM) analysis, employing ab initio non-Born-Oppenhiemer wavefunctions. Accordingly, the "atoms in molecules" analysis performed on various asymmetric exotic isotopomers of the hydrogen molecule, recently detected experimentally [Science, 2011, 331, 448], demonstrates that both the exotic isotopes are capable of forming atoms in molecules and retaining the identity of hydrogen atoms. Various derived properties of atomic basins containing the muonic helium cast no doubt that apart from its short life time, it is a heavier isotope of hydrogen while the properties of basins containing the positively charged muon are more remote from those of the orthodox hydrogen basins, capable of appreciable donation of electrons as well as large charge polarization. However, with some tolerance, they may also be categorized as hydrogen basins though with a smaller electronegativity. All in all, the present study also clearly demonstrates that the MC-QTAIM analysis is an efficient approach to decipher the chemical nature of species containing exotic constituents, which are difficult to elucidate by experimental and/or alternative theoretical schemes.

  2. Phase boundary of hot dense fluid hydrogen. (United States)

    Ohta, Kenji; Ichimaru, Kota; Einaga, Mari; Kawaguchi, Sho; Shimizu, Katsuya; Matsuoka, Takahiro; Hirao, Naohisa; Ohishi, Yasuo


    We investigated the phase transformation of hot dense fluid hydrogen using static high-pressure laser-heating experiments in a laser-heated diamond anvil cell. The results show anomalies in the heating efficiency that are likely to be attributed to the phase transition from a diatomic to monoatomic fluid hydrogen (plasma phase transition) in the pressure range between 82 and 106 GPa. This study imposes tighter constraints on the location of the hydrogen plasma phase transition boundary and suggests higher critical point than that predicted by the theoretical calculations.

  3. Emission of muonic tritium into vacuum: An atomic beam for muon experiments

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, M.C. [University of British Columbia (Canada); Bailey, J.M. [Chester Technology (United Kingdom); Beer, G.A. [University of Victoria (Canada); Beveridge, J.L. [TRIUMF (Canada); Douglas, J.L. [University of Victoria (Canada); Huber, T.M. [Gustavus Adolphus College (United States); Jacot-Guillarmod, R. [Universite de Fribourg, CH-1700 (Switzerland); Kammel, P. [University of California (United States); Kim, S.K. [Jeonbuk National University (Korea, Republic of); Knowles, P.E. [University of Victoria (Canada); Kunselman, A.R. [University of Wyoming (United States); Maier, M. [University of Victoria (Canada); Markushin, V.E. [Paul Scherrer Institute (Switzerland); Marshall, G.M. [TRIUMF (Canada); Martoff, C.J. [Temple University (United States); Mason, G.R. [University of Victoria (Canada); Mulhauser, F. [Universite de Fribourg, CH-1700 (Switzerland); Olin, A. [University of Victoria (Canada); Petitjean, C. [Paul Scherrer Institute (Switzerland); Porcelli, T.A. [University of Victoria (Canada)] (and others)


    The emission of muonic tritium atoms from a thin film of hydrogen isotopes into vacuum was observed. The time and position of the muon decays were measured by tracking the decay electron trajectory. The observations are useful both for testing the theoretical cross sections for muonic atomic interactions, and producing an atomic beam of slow {mu}{sup -}t with a controllable energy.

  4. Time-of-flight spectroscopy of muonic tritium

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, M.C. [University of British Columbia, Physics and Astronomy (Canada)], E-mail:; Adamczak, A. [Institute of Nuclear Physics (Poland); Bailey, J.M. [Chester Technology (United Kingdom); Beer, G.A. [University of Victoria, Physics and Astronomy (Canada); Beveridge, J.L. [TRIUMF (Canada); Faifman, M.P. [Kurchatov Institute (Russian Federation); Huber, T.M. [Gustavus Adolphus College, Physics (United States); Jacot-Guillarmod, R. [Universite de Fribourg, Physics Institute (Switzerland); Kammel, P. [University of California, Physics and LBNL (United States); Kim, S.K. [Jeonbuk National University (Korea, Republic of); Knowles, P.E. [Universite de Fribourg, Physics Institute (Switzerland); Kunselman, A.R. [University of Wyoming, Physics (United States); Maier, M. [University of Victoria, Physics and Astronomy (Canada); Markushin, V.E. [PSI (Switzerland); Marshall, G.M. [TRIUMF (Canada); Martoff, C.J. [Temple University, Physics (United States); Mason, G.R. [University of Victoria, Physics and Astronomy (Canada); Mulhauser, F. [Universite de Fribourg, Physics Institute (Switzerland); Olin, A. [TRIUMF (Canada); Petitjean, C. [PSI (Switzerland)] (and others)


    Emission of muonic tritium from a solid hydrogen layer has been studied via imaging of the muon-decay electrons and the time-of-flight distributions have been compared with detailed Monte Carlo calculations. Results are consistent at the 10% level with the theoretical prediction of a Ramsauer-Townsend minimum cross-section energy.

  5. Experimental search for muonic photons

    CERN Document Server

    Vilain, P; Beyer, R; Flegel, Wilfried; Mouthuy, T; Øverås, H; Panman, J; Rozanov, A N; Winter, Klaus; Zacek, G; Zacek, V; Büsser, F W; Foos, C; Gerland, L; Layda, T; Niebergall, F; Rädel, G; Stähelin, P; Voss, T; Favart, D; Grégoire, G; Knoops, E; Lemaître, V; Gorbunov, P; Grigoriev, E A; Ilyin, V A; Khovanskii, V D; Maslennikov, A M; Okun, Lev Borisovich; Lippich, W; Nathaniel, A; Staude, A; Vogt, J; Cocco, A G; Ereditato, A; Fiorillo, G; Marchetti-Stasi, F; Palladino, Vittorio; Strolin, P; Capone, A; De Pedis, D; Dore, U; Frenkel-Rambaldi, A; Loverre, P F; Macina, Daniela; Piredda, G; Santacesaria, R; Di Capua, E; Ricciardi, S; Saitta, B; Akkus, B; Arik, E; Serin-Zeyrek, M; Sever, R; Tolun, P; Hiller, K; Nahnhauer, R; Roloff, H


    We report new limits on the production of muonic photons in the CERN neutrino beam. The results are based on the analysis of neutrino production of dimuons in the CHARM II detector. A $90\\%$ CL limit on the coupling constant of muonic photons, $\\alpha_{\\mu} / \\alpha < (1.5 \\div 3.2) \\times10^{-6}$ is derived for a muon neutrino mass in the range $m_{\

  6. Correlation between muonic levels and nuclear structure in muonic atoms

    Energy Technology Data Exchange (ETDEWEB)

    Dong, J.M., E-mail: [Research Center for Nuclear Science and Technology, Lanzhou University and Institute of Modern Physics of CAS, Lanzhou 730000 (China); Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000 (China); China Institute of Atomic Energy, P.O. Box 275(18), Beijing 102413 (China); Zuo, W., E-mail: [Research Center for Nuclear Science and Technology, Lanzhou University and Institute of Modern Physics of CAS, Lanzhou 730000 (China); Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000 (China); Zhang, H.F. [School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000 (China); Scheid, W. [Institute for Theoretical Physics, Justus-Liebig-University, D-35392 Giessen (Germany); Gu, J.Z., E-mail: [China Institute of Atomic Energy, P.O. Box 275(18), Beijing 102413 (China); Wang, Y.Z. [China Institute of Atomic Energy, P.O. Box 275(18), Beijing 102413 (China)


    A method that deals with the nucleons and the muon unitedly is employed to investigate the muonic lead, with which the correlation between the muon and nucleus can be studied distinctly. A 'kink' appears in the muonic isotope shift at a neutron magic number where the nuclear shell structure plays a key role. This behavior may have very important implications for the experimentally probing the shell structure of the nuclei far away from the {beta}-stable line. We investigate the variations of the nuclear structure due to the interaction with the muon in the muonic atom and find that the nuclear structure remains basically unaltered. Therefore, the muon is a clean and reliable probe for studying the nuclear structure. In addition, a correction that the muon-induced slight change in the proton density distribution in turn shifts the muonic levels is investigated. This correction to muonic level is as important as the Lamb shift and high order vacuum polarization correction, but is larger than anomalous magnetic moment and electron shielding correction.

  7. Hadronic deuteron polarizability contribution the hyperfine structure in muonic deuterium

    Directory of Open Access Journals (Sweden)

    Eskin A.V.


    Full Text Available The calculation of the contribution to the polarizability of the nucleus to hyperfine structure of muonic hydrogen is carried out within the unitary isobar model and on the basis of experimental data on the structure functions of deep inelastic lepton-proton and lepton-deuteron scattering. The calculation of virtual absorption cross sections of transversely and longitudinally polarized photons by nucleons in the resonance region is performed in the framework of the program MAID.

  8. Hot Hydrogen Heat Source Development Project (United States)

    National Aeronautics and Space Administration — The proposed project technology need is evaluating the potential development to provide a capability that will produce high temperature hydrogen, in excess of 2500...

  9. Ionization equilibrium of hot hydrogen plasma

    CERN Document Server

    Potekhin, A Yu


    The hydrogen plasma is studied at temperatures T ~ 10^4 - 10^6 K using the free energy minimization method. A simple analytic free energy model is proposed which is accurate at densities up to 1 g/cc and yields convergent internal partition function of atoms. The occupation probability formalism is modified for solving the ionization equilibrium problem. The ionization degree and equation of state are calculated and compared with the results of other models.

  10. Hot hydrogen testing of metallic turbo pump materials (United States)

    Zee, Ralph; Chin, Bryan; Inamdar, Rohit


    The objectives of this investigation are to expose heat resistant alloys to hydrogen at elevated temperatures and to use various microstructural and analytical techniques to determine the chemical and rate process involved in degradation of these materials due to hydrogen environment. Inconel 718 and NASA-23 (wrought and cast) are candidate materials. The degradation of these materials in the presence of 1 to 5 atmospheric pressure of hydrogen from 450 C to 1100 C was examined. The hydrogen facility at Auburn University was used for this purpose. Control experiments were also conducted wherein the samples were exposed to vacuum so that a direct comparison of the results would separate the thermal contribution from the hydrogen effects. The samples were analyzed prior to and after exposure. A residual gas collection system was used to determine the gaseous species produced by any chemical reaction that may have occurred during the exposure. Analysis of this gas sample shows only the presence of H2 as expected. Analyses of the samples were conducted using optical microscopy, x-ray diffraction, scanning electron microscopy, and weight change. There appears to be no change in weight of the samples as a result of hydrogen exposure. In addition no visible change on the surface structure was detected. This indicates that the materials of interest do not have strong interaction with hot hydrogen. This is consistent with the microstructure results.

  11. Hot hydrogen atom reactions moderated by H2 and He (United States)

    Aronowitz, S.; Scattergood, T.; Flores, J.; Chang, S.


    Photolysis experiments were performed on the H2-CD4-NH3 and He-CD4-NH3 systems. The photolysis (1849 A) involved only NH3. Mixtures of H2:CD4:NH3 included all combinations of the ratios (200,400,800):(10,20,40):4. Two He:CD4:NH3 mixtures were examined where the ratios equalled the combinations 100:(10,20):4. Abstraction of a D from CD4 by the photolytically produced hot hydrogen from ammonia was monitored by mass spectrometric determination of HD. Both experiment and semiempirical hot-atom theory show that H2 is a very poor thermalizer of hot hydrogens with excess kinetic energy of about 2 eV. Applications of the hard-sphere collision model to the H2-CD4-NH3 system resulted in predicted ratios of net HD production to NH3 decomposition that were two orders of magnitude smaller than the experimental ratios. On the other hand, helium is found to be a very efficient thermalizer; here, the classical model yields reasonable agreement with experiments. Application of a semiempirical hot-atom program gave quantitative agreement with experiment for either system.

  12. Muonic Chemistry in Condensed Matter

    CERN Multimedia


    When polarized muons (@m|+) stop in condensed matter, muonic atoms are formed in the final part of their range, and direct measurements of the @m|+-spin polarization are possible via the asymmetric decay into positrons. The hyperfine interaction determines the characteristic precession frequencies of the @m|+ spin in muonium, @w(Mu). Such frequencies can be altered by the interactions of the muonium's electron spin with the surrounding medium. The measurement of @w(Mu) in a condensed system is known often to provide unique information regarding the system. \\\\ \\\\ In particular, the use of muonium atoms as a light isotope of the simple reactive radical H|0 allows the investigation of fast reactions of radicals over a typical time scale 10|-|9~@$<$~t~@$<$~10|-|5~sec, which is determined by the instrumental resolution at one end and by the @m|+ lifetime at the other. \\\\ \\\\ In biological macromolecules transient radicals, such as the constituents of DNA itself, exist on a time scale of sub-microseconds, acco...

  13. Diagnostics for hot plasmas using hydrogen neutral beams

    Energy Technology Data Exchange (ETDEWEB)

    Goldston, R.J.


    Beams of neutral hydrogen atoms have found a number of uses in the diagnosis of hot plasmas. In the most straightforward application, neutral beams have been used to determine plasma line density, based on simple attenuation measurements. This technique has been applied most intensively recently to the study of beam-injected mirror plasmas. Neutral beams have also now been used in a number of tokamaks to supply a local increase of the neutral atom target density for charge exchange. By directing a time-modulated neutral beam across the sight-line of a charge-exchange analyzer, and measuring the modulated neutral particle efflux from the plasma, local measurements of the ion energy distribution function can be made. If a modulated diagnostic neutral beam is directed across the sight-line of an ultra-violet spectrometer, one can also make measurements of the local densities and possibly velocity distributions of fully stripped impurities. The fast hydrogen neutrals charge exchange with fully stripped impurities in the plasma, leaving the impurities in excited hydrogen-like states. In their prompt radiative decay the impurity ions emit characteristic uv lines, which can be detected easily.

  14. Using Thin Film Targets for Muonic Atoms and Muon Catalyzed Fusion Studies


    TRIUMF Munoic Hydrogen Collaboration; Fujiwara, M C; Adamczak, A.; Bailey, J.M.; Beer, G A; Beveridge, J. L.; Faifman, M. P.; Huber, T. M.; Kammel, P; Kim, S. K.; Knowles, P. E.; Kunselman, A. R.; Markushin, V. E.; Marshall, G. M.; Martoff, C. J.


    Studies of muonic atoms and muon catalyzed fusion have been conventionally done in a bulk target of gas, liquid or solid hydrogen isotopes. The use of thin film targets developed at TRIUMF have notable advantages in tackling some of the most important questions in the field, which could be further exploited at future high intensity muon sources. We review the technique of the thin film method with emphasis on recent results and a future proposal.

  15. Analysis of Material Sample Heated by Impinging Hot Hydrogen Jet in a Non-Nuclear Tester (United States)

    Wang, Ten-See; Foote, John; Litchford, Ron


    A computational conjugate heat transfer methodology was developed and anchored with data obtained from a hot-hydrogen jet heated, non-nuclear materials tester, as a first step towards developing an efficient and accurate multiphysics, thermo-fluid computational methodology to predict environments for hypothetical solid-core, nuclear thermal engine thrust chamber. The computational methodology is based on a multidimensional, finite-volume, turbulent, chemically reacting, thermally radiating, unstructured-grid, and pressure-based formulation. The multiphysics invoked in this study include hydrogen dissociation kinetics and thermodynamics, turbulent flow, convective and thermal radiative, and conjugate heat transfers. Predicted hot hydrogen jet and material surface temperatures were compared with those of measurement. Predicted solid temperatures were compared with those obtained with a standard heat transfer code. The interrogation of physics revealed that reactions of hydrogen dissociation and recombination are highly correlated with local temperature and are necessary for accurate prediction of the hot-hydrogen jet temperature.

  16. Hydrogen storage using a hot pressure swing reactor


    Preuster, P.; Dürr, S.; Seidel, A.; Müller, K.; Bösmann, A.; Jorschick, Holger; Wasserscheid, Peter


    Our contribution demonstrates that hydrogen storage in stationary Liquid Organic Hydrogen Carrier (LOHC) systems becomes much simpler and significantly more efficient if both, the LOHC hydrogenation and the LOHC dehydrogenation reaction are carried out in the same reactor using the same catalyst. The finding that the typical dehydrogenation catalyst for hydrogen release from perhydro dibenzyltoluene (H18-DBT), Pt on alumina, turns into a highly active and very selective dibenzyltoluene hydrog...

  17. Toward a muon-specific electronic structure theory: effective electronic Hartree-Fock equations for muonic molecules. (United States)

    Rayka, Milad; Goli, Mohammad; Shahbazian, Shant


    An effective set of Hartree-Fock (HF) equations are derived for electrons of muonic systems, i.e., molecules containing a positively charged muon, conceiving the muon as a quantum oscillator, which are completely equivalent to the usual two-component HF equations used to derive stationary states of the muonic molecules. In these effective equations, a non-Coulombic potential is added to the orthodox coulomb and exchange potential energy terms, which describes the interaction of the muon and the electrons effectively and is optimized during the self-consistent field cycles. While in the two-component HF equations a muon is treated as a quantum particle, in the effective HF equations it is absorbed into the effective potential and practically transformed into an effective potential field experienced by electrons. The explicit form of the effective potential depends on the nature of muon's vibrations and is derivable from the basis set used to expand the muonic spatial orbital. The resulting effective Hartree-Fock equations are implemented computationally and used successfully, as a proof of concept, in a series of muonic molecules containing all atoms from the second and third rows of the Periodic Table. To solve the algebraic version of the equations muon-specific Gaussian basis sets are designed for both muon and surrounding electrons and it is demonstrated that the optimized exponents are quite distinct from those derived for the hydrogen isotopes. The developed effective HF theory is quite general and in principle can be used for any muonic system while it is the starting point for a general effective electronic structure theory that incorporates various types of quantum correlations into the muonic systems beyond the HF equations.

  18. Imaging the Extended Hot Hydrogen Exosphere at Mars to Determine the Water Escape Rate (United States)

    Bhattacharyya, Dolon


    ACS SBC imaging of the extended hydrogen exosphere of Mars is proposed to identify the hot hydrogen population present in the exosphere of Mars. Determining the characteristics of this population and the underlying processes responsible for its production are critical towards constraining the escape flux of H from Mars, which in turn is directly related to the water escape history of Mars. Since the hot atoms appear mainly at high altitudes, these observations will be scheduled when Mars is far from Earth allowing us to image the hot hydrogen atoms at high altitudes where they dominate the population. The altitude coverage by HST will extend beyond 30,000 km or 8.8 Martian radii in this case, which makes it perfect for this study as orbiting spacecraft remain at low altitudes (MAVEN apoapse is 6000 km) and cannot separate hot atoms from the thermal population at those altitudes. The observations will also be carried out when Mars is near aphelion, the atmospheric temperature is low, and the thermal population has a small scale height, allowing the clear characterization of the hot hydrogen layer. Another advantage of conducting this study in this cycle is that the solar activity is near its minimum, allowing us to discriminate between changes in the hot hydrogen population from processes taking place within the atmosphere of Mars and changes due to external drivers like the solar wind, producing this non-thermal population. This proposal is part of the HST UV initiative.

  19. The effect of moderators on the reactions of hot hydrogen atoms with methane

    CERN Document Server

    Estrup, Peder J.


    The reaction of recoil tritium with methane has been examined in further detail. The previous hypothesis that this system involves a hot displacement reaction of high kinetic energy hydrogen to give CH$_{3}$T, CH$_{2}$T and HT is confirmed. The effect of moderator on this process is studied by the addition of noble gases. As predicted these gases inhibit the hot reaction action, their efficiency in this respect being He > Ne > A > Se. The data are quantitatively in accord with a theory of hot atom kinetics. The mechanism of the hot displacement process is briefly discussed.

  20. The physics of laser polarized muonic atoms (United States)

    Cates, G. D.

    This past research period we carried out a successful experiment at LAMPF in collaboration with Syracuse University in which we used lasers to produce polarized muonic He-3. Samples of nuclear polarized He-3 were produced by spin-exchange with optically pumped rubidium vapor. Unpolarized muons were stopped in the gas, and became polarized due to their hyperfine interaction with the He-3 nucleus. We determined that a muon polarization of approximately 8 percent results with a He-3 target polarization of 100 percent. The high statistical accuracy of our result gives us a firm handle on a theoretical question of great importance to future work involving muons and polarized He-3. Currently, we are working toward a new experiment at LAMPF, for which we have just submitted a proposal requesting running time this coming summer. The experiment utilizes a new technique for producing polarized muonic He-3, a technique we believe has the potential for producing practical polarizations that in principle could be as high as 75 percent, and in practice may exceed 25 to 50 percent. We call this new technique direct spin-exchange (DSE) because it is based on spin-exchange collisions between neutral muonic helium and an optically pumped vapor of Rb. It is direct because, in contrast to the technique we used last summer, the He-3 nucleus is not involved in the spin-exchange process. We have proposed the use of DSE to study the induced pseudoscalar form factor of He-3. Finally, we describe an experiment to measure the spin dependent structure function of the neutron at SLAC. Princeton played an important role in the design and proposal of this experiment, including hosting a meeting to explore the technical feasibility of the polarized He-3 target.

  1. Search for Muonic Dark Forces at BABAR

    CERN Document Server

    Godang, Romulus


    Many models of physics beyond Standard Model predict the existence of light Higgs states, dark photons, and new gauge bosons mediating interactions between dark sectors and the Standard Model. Using a full data sample collected with the BABAR detector at the PEP-II $e^+e^-$ collider, we report searches for a light non-Standard Model Higgs boson, dark photon, and a new muonic dark force mediated by a gauge boson ($Z'$) coupling only to the second and third lepton families. Our results significantly improve upon the current bounds and further constrain the remaining region of the allowed parameter space.

  2. Update on nuclear structure effects in light muonic atoms

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez, Oscar Javier, E-mail:; Dinur, Nir Nevo; Ji, Chen; Bacca, Sonia [TRIUMF (Canada); Barnea, Nir [The Hebrew University, Racah Institute of Physics (Israel)


    We present calculations of the nuclear structure corrections to the Lamb shift in light muonic atoms, using state-of-the-art nuclear potentials. We outline updated results on finite nucleon size contributions.

  3. Hot wire deposited hydrogenated amorphous silicon solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Mahan, A.H.; Iwaniczko, E.; Nelson, B.P.; Reedy, R.C. Jr.; Crandall, R.S. [National Renewable Energy Lab., Golden, CO (United States)


    This paper details the results of a study in which low H content, high deposition rate hot wire (HW) deposited amorphous silicon (a-Si:H) has been incorporated into a substrate solar cell. The authors find that the treatment of the top surface of the HW i layer while it is being cooled from its high deposition temperature is crucial to device performance. They present data concerning these surface treatments, and correlate these treatments with Schottky device performance. The authors also present first generation HW n-i-p solar cell efficiency data, where a glow discharge (GD) {mu}c-Si(p) layer was added to complete the partial devices. No light trapping layer was used to increase the device Jsc. Their preliminary investigations have yielded efficiencies of up to 6.8% for a cell with a 4000 {Angstrom} thick HW i-layer, which degrade less than 10% after a 900 hour light soak. The authors suggest avenues for further improvement of their devices.

  4. On-board hydrogen generation for transport applications: the HotSpot™ methanol processor (United States)

    Edwards, Neil; Ellis, Suzanne R.; Frost, Jonathan C.; Golunski, Stanislaw E.; van Keulen, Arjan N. J.; Lindewald, Nicklas G.; Reinkingh, Jessica G.

    In the absence of a hydrogen infrastructure, development of effective on-board fuel processors is likely to be critical to the commercialisation of fuel-cell cars. The HotSpot™ reactor converts methanol, water and air in a single compact catalyst bed into a reformate containing mainly CO2 and hydrogen (and unreacted nitrogen). The process occurs by a combination of exothermic partial oxidation and endothermic steam reforming of methanol, to produce 750 l of hydrogen per hour from a 245-cm3 reactor. The relative contribution of each reaction can be tuned to match the system requirements at a given time. Scale-up is achieved by the parallel combination of the required number of individual HotSpot reactors, which are fed from a central manifold. Using this modular design, the start-up and transient characteristics of a large fuel-processor are identical to that of a single reactor. When vaporised liquid feed and air are introduced into cold reactors, 100% output is achieved in 50 s; subsequent changes in throughput result in instantaneous changes in output. Surplus energy within the fuel-cell powertrain can be directed to the manifold, where it can be used to vaporise the liquid feeds and so promote steam reforming, resulting in high system efficiency. The small amount of CO that is produced by the HotSpot reactions is attenuated to methanol, but are being applied to other organic fuels.

  5. Nuclear parameters from muonic and pionic x rays

    Energy Technology Data Exchange (ETDEWEB)

    Steffen, R M


    In view of the higher precision of the experimental data in measurements of the energies and relative intensities of the muonic and pionic x-ray transitions, the validity of the approximations made in extracting nuclear spectroscopic values from the raw data must be scrutinized more carefully if the reliability of the extracted parameters are to approach the accuracy of the experimental data. (GHT)

  6. Test of quantum-electrodynamical corrections in muonic atoms

    CERN Document Server

    Walter, H K; Böhm, F; Engfer, R; Link, R; Michaelsen, R; Petitjean, C; Schellenberg, L; Schneuwly, H; Schröder, W U; Von Gunten, A H; Vuilleumier, J H; Zehnder, A


    Energies of the 5f-4f muonic X-rays have been measured in /sup nat/Hg and /sup 203/Tl with an accuracy of about 25 eV. They are found to be smaller than theoretical energies including recently revised calculations of higher-order vacuum polarization, by about two standard deviations. (10 refs).

  7. Radiative nonrecoil nuclear finite size corrections of order α(Zα)5 to the Lamb shift in light muonic atoms (United States)

    Faustov, R. N.; Martynenko, A. P.; Martynenko, F. A.; Sorokin, V. V.


    On the basis of quasipotential method in quantum electrodynamics we calculate nuclear finite size radiative corrections of order α(Zα)5 to the Lamb shift in muonic hydrogen and helium. To construct the interaction potential of particles, which gives the necessary contributions to the energy spectrum, we use the method of projection operators to states with a definite spin. Separate analytic expressions for the contributions of the muon self-energy, the muon vertex operator and the amplitude with spanning photon are obtained. We present also numerical results for these contributions using modern experimental data on the electromagnetic form factors of light nuclei.

  8. Hyperfine structure of S-states of muonic tritium

    Directory of Open Access Journals (Sweden)

    Martynenko F.A.


    Full Text Available On the basis of quasipotential method in quantum electrodynamics we carry out a precise calculation of hyperfine splitting of S-states in muonic tritium. The one-loop and two-loop vacuum polarization corrections, relativistic effects, nuclear structure corrections in first and second orders of perturbation theory are taken into account. The contributions to hyperfine structure are obtained in integral form and calculated analytically and numerically. Obtained results for hyperfine splitting can be used for a comparison with future experimental data of CREMA collaboration.

  9. Photo-excited hot carrier dynamics in hydrogenated amorphous silicon imaged by 4D electron microscopy (United States)

    Liao, Bolin; Najafi, Ebrahim; Li, Heng; Minnich, Austin J.; Zewail, Ahmed H.


    Charge carrier dynamics in amorphous semiconductors has been a topic of intense research that has been propelled by modern applications in thin-film solar cells, transistors and optical sensors. Charge transport in these materials differs fundamentally from that in crystalline semiconductors owing to the lack of long-range order and high defect density. Despite the existence of well-established experimental techniques such as photoconductivity time-of-flight and ultrafast optical measurements, many aspects of the dynamics of photo-excited charge carriers in amorphous semiconductors remain poorly understood. Here, we demonstrate direct imaging of carrier dynamics in space and time after photo-excitation in hydrogenated amorphous silicon (a-Si:H) by scanning ultrafast electron microscopy (SUEM). We observe an unexpected regime of fast diffusion immediately after photoexcitation, together with spontaneous electron-hole separation and charge trapping induced by the atomic disorder. Our findings demonstrate the rich dynamics of hot carrier transport in amorphous semiconductors that can be revealed by direct imaging based on SUEM.

  10. Production and Consumption of Hydrogen in Hot Spring Microbial Mats Dominated by a Filamentous Anoxygenic Photosynthetic Bacterium (United States)

    Otaki, Hiroyo; Everroad, R. Craig; Matsuura, Katsumi; Haruta, Shin


    Microbial mats containing the filamentous anoxygenic photosynthetic bacterium Chloroflexus aggregans develop at Nakabusa hot spring in Japan. Under anaerobic conditions in these mats, interspecies interaction between sulfate-reducing bacteria as sulfide producers and C. aggregans as a sulfide consumer has been proposed to constitute a sulfur cycle; however, the electron donor utilized for microbial sulfide production at Nakabusa remains to be identified. In order to determine this electron donor and its source, ex situ experimental incubation of mats was explored. In the presence of molybdate, which inhibits biological sulfate reduction, hydrogen gas was released from mat samples, indicating that this hydrogen is normally consumed as an electron donor by sulfate-reducing bacteria. Hydrogen production decreased under illumination, indicating that C. aggregans also functions as a hydrogen consumer. Small amounts of hydrogen may have also been consumed for sulfur reduction. Clone library analysis of 16S rRNA genes amplified from the mats indicated the existence of several species of hydrogen-producing fermentative bacteria. Among them, the most dominant fermenter, Fervidobacterium sp., was successfully isolated. This isolate produced hydrogen through the fermentation of organic carbon. Dispersion of microbial cells in the mats resulted in hydrogen production without the addition of molybdate, suggesting that simultaneous production and consumption of hydrogen in the mats requires dense packing of cells. We propose a cyclic electron flow within the microbial mats, i.e., electron flow occurs through three elements: S (elemental sulfur, sulfide, sulfate), C (carbon dioxide, organic carbon) and H (di-hydrogen, protons). PMID:22446313

  11. High-efficiency hydrogen production by an anaerobic, thermophilic enrichment culture from an Icelandic hot spring. (United States)

    Koskinen, Perttu E P; Lay, Chyi-How; Puhakka, Jaakko A; Lin, Ping-Jei; Wu, Shu-Yii; Orlygsson, Jóhann; Lin, Chiu-Yue


    Dark fermentative hydrogen production from glucose by a thermophilic culture (33HL), enriched from an Icelandic hot spring sediment sample, was studied in two continuous-flow, completely stirred tank reactors (CSTR1, CSTR2) and in one semi-continuous, anaerobic sequencing batch reactor (ASBR) at 58 degrees C. The 33HL produced H2 yield (HY) of up to 3.2 mol-H2/mol-glucose along with acetate in batch assay. In the CSTR1 with 33HL inoculum, H2 production was unstable. In the ASBR, maintained with 33HL, the H2 production enhanced after the addition of 6 mg/L of FeSO4 x H2O resulting in HY up to 2.51 mol-H2/mol-glucose (H2 production rate (HPR) of 7.85 mmol/h/L). The H2 production increase was associated with an increase in butyrate production. In the CSTR2, with ASBR inoculum and FeSO4 supplementation, stable, high-rate H2 production was obtained with HPR up to 45.8 mmol/h/L (1.1 L/h/L) and HY of 1.54 mol-H2/mol-glucose. The 33HL batch enrichment was dominated by bacterial strains closely affiliated with Thermobrachium celere (99.8-100%). T. celere affiliated strains, however, did not thrive in the three open system bioreactors. Instead, Thermoanaerobacterium aotearoense (98.5-99.6%) affiliated strains, producing H2 along with butyrate and acetate, dominated the reactor cultures. This culture had higher H2 production efficiency (HY and specific HPR) than reported for mesophilic mixed cultures. Further, the thermophilic culture readily formed granules in CSTR and ASBR systems. In summary, the thermophilic culture as characterized by high H2 production efficiency and ready granulation is considered very promising for H2 fermentation from carbohydrates.

  12. Lamb shift in muonic ions of lithium, beryllium and boron

    CERN Document Server

    Krutov, A A; Martynenko, F A; Sukhorukova, O S


    We present a precise calculation of the Lamb shift $(2P_{1/2}-2S_{1/2})$ in muonic ions $(\\mu ^6_3Li)^{2+},~(\\mu ^7_3Li)^{2+}$, $(\\mu ^9_4Be)^{3+},~(\\mu ^{10}_4Be)^{3+}$, $(\\mu ^{10}_5B)^{4+},~(\\mu ^{11}_5B)^{4+}$. The contributions of orders $\\alpha^3\\div\\alpha^6$ to the vacuum polarization, nuclear structure and recoil, relativistic effects are taken into account. Our numerical results are consistent with previous calculations and improve them due to account of new corrections. The obtained results can be used for the comparison with future experimental data, and extraction more accurate values of nuclear charge radii.

  13. A search for effects on chemical isomerism in muonic X-ray spectra of propyl alcohol

    CERN Document Server

    Brandão d'Oliveira, A; Von Egidy, T


    The intensities of muonic X-ray transitions in n-propyl alcohol and isopropyl alcohol were measured. The experiment was performed at the muon channel of the 600 MeV synchrocyclotron at CERN. The spectra were evaluated by means of a standard computer program and by a technique to observe small differences between the propyl-alcohol spectra. No differences in the muonic spectra were observed within rather small experimental errors. (16 refs).

  14. Experimental and numerical studies of the effects of hydrogen addition on the structure of a laminar methane-nitrogen jet in hot coflow under MILD conditions

    NARCIS (Netherlands)

    Sepman, Alexey; Abtahizadeh, Ebrahim; Mokhov, Anatoli; van Oijen, Jeroen; Levinsky, Howard; de Goey, Philip


    In this work we investigate the effects of hydrogen addition on the flame structure of MILD combustion both experimentally and numerically using a laminar-jet-in-hot-coflow (LJHC) geometry. The addition of hydrogen appreciably decreases the flame height (similar to 25%), however only modestly

  15. Effect of Nb on hydrogen-induced delayed fracture in high strength hot stamping steels

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shiqi [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); College of Mechanical Engineering, Yangtze University, Jingzhou 434023 (China); Huang, Yunhua, E-mail: [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Sun, Bintang, E-mail: [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Liao, Qingliang [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Lu, Hongzhou [CITIC Metal Co. Ltd., Room 1901, Capital Mansion 6, Xin Yuan Nanlu, Chaoyang District, Beijing 100004 (China); The School of Resources and Environmental Engineering, East China University of Science and Technology, Meilong road 130, Xujiahui District, Shanghai 200237 (China); Jian, Bian [Niobium Tech Asia, 068898 Singapore (Singapore); Mohrbacher, Hardy [NiobelCon bvba, 2970 Schilde (Belgium); Zhang, Wei; Guo, Aimin [CITIC Metal Co. Ltd., Room 1901, Capital Mansion 6, Xin Yuan Nanlu, Chaoyang District, Beijing 100004 (China); Zhang, Yue [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); The State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China)


    The effect of Nb addition (0.022, 0.053, 0.078 wt%) on the hydrogen-induced delayed fracture resistance of 22MnB5 was studied by constant load test and electrochemical hydrogen permeation method. It is shown that the appropriate addition of Nb is beneficial to the improvement of the delayed fracture resistance of tested steel, especially when the steel contains high concentration of hydrogen, and the maximum delayed fracture resistance is obtained at a Nb content of 0.053%.The result of hydrogen permeation test shows that the diffusion coefficient of hydrogen in the steel containing niobium is lower than that in steel without niobium, which indicates that it is harder for hydrogen in the steels containing niobium to diffuse and aggregate. In addition, the reason for Nb improving the delayed fracture resistance of steels is discussed from two aspects: hydrogen trap effect and grain refinement effect. The analysis shows that the main reason leading to the improvement of the delayed fracture resistance is the hydrogen trapping effect of NbC while the grain refinement effect of Nb(C,N) secondary.

  16. Formation of the weakly bound muonic molecule (4Heμt) 01 2 + in the three-body (tμ) 1 s +4He +4He collision (United States)

    Czapliński, Wilhelm; Rybski, Michał


    Formation of the weakly bound muonic molecule (4He μt)012+ in the excited rotational-vibrational state (J , ν) = (0 , 1) due to the three-body collision (tμ)1 s +4He +4He is considered for the first time. It is assumed that the process occurs in T-4He gaseous mixture in thermal equilibrium containing thermalized muonic tritium atoms. The corresponding reaction rate is calculated in the frame of the distorted wave Born approximation (DWBA) method using the dipole approximation for the interaction of tμ +4He system with the incoming helium atom. The obtained formation rate (normalized to helium density equal to the liquid hydrogen density) increases with temperature from 7.8 ṡ106 s-1 for 1000 K to 4.8 ṡ107 s-1 for 3000 K.

  17. Evidence of a liquid–liquid phase transition in hot dense hydrogen


    Dzyabura, Vasily; Zaghoo, Mohamed; Silvera, Isaac F.


    We use pulsed-laser heating of hydrogen at static pressures in the megabar pressure region to search for the plasma phase transition to liquid atomic metallic hydrogen. We heat our samples substantially above the melting line and observe a plateau in a temperature vs. laser power curve that otherwise increases with power. This anomaly in the heating curve appears correlated with theoretical predictions for the plasma phase transition.

  18. The interplay between the electromagnetic and the muonic longitudinal profile at production

    Directory of Open Access Journals (Sweden)

    Cazon Lorenzo


    Full Text Available The electromagnetic and the muonic longitudinal profile at production enclosure important information about the primary particle and the hadronic interactions that rule the shower development. In fact, these two profiles provide two different insights of the shower: the electromagnetic component gives a measurement of the energy and the strength of the neutral pion channel; while the muonic profile, being intimately related with the charged mesons decays, can be used as a direct probe for the high energy hadronic interactions. In this work we explore the interplay between the electromagnetic and muonic profiles, by analysing their phenomenologic behaviour for different primary masses and energies, zenith angles, and also different high energy hadronic interaction models. We have found that the muonic longitudinal profile at production displays universal features similar to what is known for the electromagnetic one. Moreover, we show that both profiles have new primary mass composition variables which are fairly independent of the high energy hadronic interaction model. Finally we discuss how the information in the electromagnetic and the muonic longitudinal profile can be combined to break the degeneracy between the primary masscomposition and the high energy hadronic physics.

  19. Muonic atoms in super-intense laser fields

    Energy Technology Data Exchange (ETDEWEB)

    Shahbaz, Atif


    Nuclear effects in hydrogenlike muonic atoms exposed to intense high-frequency laser fields have been studied. Systems of low nuclear charge number are considered where a nonrelativistic description applies. By comparing the radiative response for different isotopes we demonstrate characteristic signatures of the finite nuclear mass, size and shape in the high-harmonic spectra. Cutoff energies in the MeV domain can be achieved, offering prospects for the generation of ultrashort coherent {gamma}-ray pulses. Also, the nucleus can be excited while the laser-driven muon moves periodically across it. The nuclear transition is caused by the time-dependent Coulomb field of the oscillating charge density of the bound muon. A closed-form analytical expression for electric multipole transitions is derived within a fully quantum mechanical approach and applied to various isotopes. The excitation probabilities are in general very small. We compare the process with other nuclear excitation mechanisms through coupling with atomic shells and discuss the prospects to observe it in experiment. (orig.)

  20. Ramsauer-Townsend Effect in Solid Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Mulhauser, F. [Universite de Fribourg (Switzerland); Adamczak, A. [Institute of Nuclear Physics (Poland); Beer, G. A. [University of Victoria (Canada); Bystritsky, V. M. [Joint Institute for Nuclear Research (Russian Federation); Filipowicz, M. [Institute of Physics and Nuclear Techniques (Poland); Fujiwara, M. C. [University of Tokyo (Japan); Huber, T. M. [Gustavus Adolphus College (United States); Jacot-Guillarmod, R. [Universite de Fribourg (Switzerland); Kammel, P. [University of Illinois at Urbana-Champaign (United States); Kim, S. K. [Jeonbuk National University (Korea, Republic of); Knowles, P. [Universite de Fribourg (Switzerland); Kunselman, A. R. [University of Wyoming (United States); Maier, M. [University of Victoria (Canada); Markushin, V. E. [Paul Scherrer Institute (Switzerland); Marshall, G. M. [TRIUMF (Canada); Olin, A. [University of Victoria (Canada); Petitjean, C. [Paul Scherrer Institute (Switzerland); Porcelli, T. A. [University of Northen British Columbia (Canada); Stolupin, V. A. [Joint Institute for Nuclear Research (Russian Federation); Wozniak, J. [Institute of Physics and Nuclear Techniques (Poland)


    The TRIUMF E742 experiment has measured the energy dependence of the scattering cross-sections of muonic deuterium and tritium on hydrogen molecules for collisions in the energy range 0.1-45 eV. The experimental setup permits the creation of muonic atom ({mu}d or {mu}t) beams. The multilayered target system gives the possibility to choose the type of interactions to study and to isolate a particular interaction. The scattering of {mu}d or {mu}t beams on H{sub 2} is analyzed via the muon transfer reaction to neon. The time-of-flight method is used to measure the scattering cross section as a function of the energy of the muonic atom beam. The results are compared, using Monte Carlo simulations, with theoretical calculations which have been recently performed with high accuracy.

  1. Stress corrosion cracking mechanisms of Fe-based alloys in hydrogenated hot water

    Energy Technology Data Exchange (ETDEWEB)

    Coull, Z. [Univ. of Toronto, Dept. of Chemical Engineering and Applied Chemistry, Toronto, Ontario (Canada)]. E-mail:


    It is generally accepted that carbon steel resists Stress Corrosion Cracking (SCC) in hot water provided the oxygen content is low enough; however, isolated cracking events have occurred, apparently in fully reducing conditions, and these may or may not be true SCC. There are also occasional reports of SCC of austenitic stainless steel in reducing conditions where cold work may play a critical role. SCC though originally seen in sensitized material at oxidizing potentials persists to low potentials and in cold-worked but unsensitized material. We suspect from the literature that alloying with Ni introduces a susceptibility to SCC in reducing hot water as well as in caustic solution. Our hypothesis is that Ni causes SCC, and Cr retards it; so stainless steel has just enough Cr to protect against SCC under most conditions. We are examining this using model Fe-based materials and environments designed to separate the effects of different parameters. Early results suggest that Fe-Ni alloys and austenitic SS both undergo de-alloying and SCC in reducing caustic solutions. It is hypothesised that if these alloys are indeed susceptible to dealloying (and hence to SCC) in this environment then we can reasonably project that their behaviour in reducing, hot pure water may be similar. This is pertinent to understanding recent failures in high temperature, high pressure aqueous systems. As a first step we have investigated the surface reactions that occur in caustic solutions and in hot water. (author)

  2. Muon cycling rate in D/T mixture including doubly muonic molecule formation

    Directory of Open Access Journals (Sweden)

    M. R. Eskandari


    Full Text Available   In the present work, the fundamental behavior of four body molecule formations of pt μμ , pd μμ , dt μμ , tt μμ , and pp μμ in a D/T fusion are considered. Their higher fusion rate, specially the available data for dt μμ , encouraged us to study the muon cycling rate in D/T fusion in the temperature range of (100-1400 K, density and deuterium-tritium concentration ratio. For this purpose, various values for the doubly muonic molecule formation are chosen and with the comparison to the experimental results, the doubly muonic formation rate of 109 s-1 is predicted theoretically. Our calculated cycling rate has shown that having not considered the doubly muonic formation in previous calculations had made no serious changes in the previously calculated values.

  3. Communication: Hot-atom abstraction dynamics of hydrogen from tungsten surfaces: The role of surface structure (United States)

    Galparsoro, Oihana; Busnengo, Heriberto Fabio; Juaristi, Joseba Iñaki; Crespos, Cédric; Alducin, Maite; Larregaray, Pascal


    Adiabatic and non-adiabatic quasiclassical molecular dynamics simulations are performed to investigate the role of the crystal face on hot-atom abstraction of H adsorbates by H scattering from covered W(100) and W(110). On both cases, hyperthermal diffusion is strongly affected by the energy dissipated into electron-hole pair excitations. As a result, the hot-atom abstraction is highly reduced in favor of adsorption at low incidence energy and low coverages, i.e., when the mean free path of the hyperthermal H is typically larger. Qualitatively, this reduction is rather similar on both surfaces, despite at such initial conditions, the abstraction process involves more subsurface penetration on W(100) than on W(110).

  4. In situ hydrogen dynamics in a hot spring microbial mat during a diel cycle

    DEFF Research Database (Denmark)

    Revsbech, Niels Peter; Trampe, Erik Christian Løvbjerg; Lichtenberg, Mads


    Microbes can produce molecular hydrogen (H2) via fermentation, dinitrogen fixation, or direct photolysis, yet the H2 dynamics in cyanobacterial communities has only been explored in a few natural systems and mostly in the laboratory. In this study, we investigated the diel in situ H2 dynamics...... in a hot spring microbial mat, where various ecotypes of unicellular cyanobacteria (Synechococcus sp.) are the only oxygenic phototrophs. In the evening, H2 accumulated rapidly after the onset of darkness, reaching peak values of up to 30 mol H2 liter1 at about 1-mm depth below the mat surface, slowly...... that nitrogenase activity was an important source of H2 during the morning. This is in accordance with earlier findings of a distinct early morning peak in N2 fixation and expression of Synechococcus nitrogenase genes in mat samples from the same location. Fermentation might have contributed to the formation of H2...

  5. $\\Delta(1232)$-Resonance in the Hydrogen Spectrum


    Hagelstein, Franziska


    The electromagnetic excitation of the $\\Delta(1232)$-resonance plays an appreciable role in the Lamb shift and hyperfine structure of muonic and electronic hydrogen. Its effect appears at the subleading order $\\mathcal{O}(\\alpha^5)$, together with other proton-polarizability contributions from forward two-photon exchange. We use the large-$N_c$ relations for the nucleon-to-delta transition form factors to compute the effect of the $\\Delta(1232)$ in the hydrogen spectrum. We pay particular att...

  6. Spectral analysis of four surprisingly similar hot hydrogen-rich subdwarf O stars (United States)

    Latour, M.; Chayer, P.; Green, E. M.; Irrgang, A.; Fontaine, G.


    suggests that the system is a physical binary. However, the lack of radial velocity variations points towards a low inclination and/or long orbital period. Spectroscopic and Hipparcos distances are in good agreement for our three brightest stars. Conclusions: We performed a spectroscopic analysis of four hot sdO stars that are very similar in terms of atmospheric parameters and chemical compositions. The rotation velocities of our stars are significantly higher than what is observed in their immediate progenitors on the EHB, suggesting that angular momentum may be conserved as the stars evolve away from the EHB.

  7. Delignification of disposable wooden chopsticks waste for fermentative hydrogen production by an enriched culture from a hot spring. (United States)

    Phummala, Kanthima; Imai, Tsuyoshi; Reungsang, Alissara; Chairattanamanokorn, Prapaipid; Sekine, Masahiko; Higuchi, Takaya; Yamamoto, Koichi; Kanno, Ariyo


    Hydrogen (H2) production from lignocellulosic materials may be enhanced by removing lignin and increasing the porosity of the material prior to enzymatic hydrolysis. Alkaline pretreatment conditions, used to delignify disposable wooden chopsticks (DWC) waste, were investigated. The effects of NaOH concentration, temperature and retention time were examined and it was found that retention time had no effect on lignin removal or carbohydrate released in enzymatic hydrolysate. The highest percentage of lignin removal (41%) was obtained with 2% NaOH at 100°C, correlated with the highest carbohydrate released (67 mg/g pretreated DWC) in the hydrolysate. An enriched culture from a hot spring was used as inoculum for fermentative H2 production, and its optimum initial pH and temperature were determined to be 7.0 and 50°C, respectively. Furthermore, enzymatic hydrolysate from pretreated DWC was successfully demonstrated as a substrate for fermentative H2 production by the enriched culture. The maximum H2 yield and production rate were achieved at 195 mL H2/g total sugars consumed and 116 mL H2/(L·day), respectively. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

  8. Investigation of hydrogen recycling in long-duration discharges and its modification with a hot wall in the spherical tokamak QUEST (United States)

    Hanada, K.; Yoshida, N.; Honda, T.; Wang, Z.; Kuzmin, A.; Takagi, I.; Hirata, T.; Oya, Y.; Miyamoto, M.; Zushi, H.; Hasegawa, M.; Nakamura, K.; Fujisawa, A.; Idei, H.; Nagashima, Y.; Watanabe, O.; Onchi, T.; Kuroda, K.; Long, H.; Watanabe, H.; Tokunaga, K.; Higashijima, A.; Kawasaki, S.; Nagata, T.; Takase, Y.; Fukuyama, A.; Mitarai, O.


    Fully non-inductive plasma maintenance was achieved by a microwave of 8.2 GHz and 40 kW for more than 1 h 55 min with a well-controlled plasma-facing wall (PFW) temperature of 393 K, using a hot wall in the middle-sized spherical tokamak QUEST, until the discharge was finally terminated by the uncontrollability of the density. The PFW was composed of atmospheric plasma-sprayed tungsten and stainless steel. The hot wall plays an essential role in reducing the amount of wall-stored hydrogen and facilitates hydrogen recycling. The behaviour of fuel hydrogen in the PFW was investigated by monitoring the injection and evacuation of hydrogen into and from the plasma-producing vessel. A fuel particle balance equation based on the presence of a hydrogen transport barrier between the deposited layer and the substrate was applied to the long-duration discharges. It was found that the model could readily predict the observed behaviour in which a higher wall temperature likely gives rise to faster wall saturation.

  9. Applying hot-wire anemometry to directly measure the water balance in a proton exchange membrane fuel cell for a pre-humidified hydrogen stream

    DEFF Research Database (Denmark)

    Berning, Torsten; Shakhshir, Saher Al


    In a recent publication it has been shown how the water balance in a proton exchange membrane fuel cell can be determined employing hot wire anemometry. The hot wire sensor has to be placed into the anode outlet pipe of the operating fuel cell, and the voltage signal E that is read from the sensor....... Finally, it will be shown how previously developed dew point diagrams for the anode side in a fuel cell can be corrected for a humidified hydrogen inlet stream....... has to be divided by a pre-determined voltage signal E0 that has been obtained for a stream of dry hydrogen where the molar flow rate corresponds to a total current I of the fuel cell stack and a stoichiometric flow ratio, ξ. Because the last two properties are usually continuously known in fuel cell...

  10. Method of investigation of nuclear reactions in charge-nonsymmetrical muonic complexes

    CERN Document Server

    Bystritsky, V M; Penkov, F M


    A method for experimental determination of the nuclear fusion rates in the d mu He molecules in the states with J=0 and J=1 (J is the orbital moment of the system) and of the effective rate of transition between these states (rotational transition 1-0) is proposed. It is shown that information on the desired characteristics can be found from joint analysis of the time distribution and yield of products of nuclear fusion reactions in deuterium-helium muonic molecules and muonic X-ray obtained in experiments with the D sub 2 +He mixture at three (and more) appreciably different densities. The planned experiments with the D sub 2 +He mixture at the meson facility PSI (Switzerland) are optimized to gain more accurate information about the desired parameters on the assumption that different mechanisms for the 1-0 transition of the d mu He complex are realized. (author)

  11. Understanding the proton radius puzzle: Nuclear structure effects in light muonic atoms

    Directory of Open Access Journals (Sweden)

    Ji Chen


    Full Text Available We present calculations of nuclear structure effects to the Lamb shift in light muonic atoms. We adopt a modern ab-initio approach by combining state-of-the-art nuclear potentials with the hyperspherical harmonics method. Our calculations are instrumental to the determination of nuclear charge radii in the Lamb shift measurements, which will shed light on the proton radius puzzle.

  12. Theoretical and computational study of the energy dependence of the muon transfer rate from hydrogen to higher-Z gases

    Energy Technology Data Exchange (ETDEWEB)

    Bakalov, Dimitar, E-mail: [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Tsarigradsko chaussée 72, Sofia 1784 (Bulgaria); Adamczak, Andrzej [Institute of Nuclear Physics, Polish Academy of Sciences, ul. Radzikowskiego 152, 31-342 Krakow (Poland); Stoilov, Mihail [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Tsarigradsko chaussée 72, Sofia 1784 (Bulgaria); Vacchi, Andrea [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, Via A. Valerio 2, 34127 Trieste (Italy)


    The recent PSI Lamb shift experiment and the controversy about proton size revived the interest in measuring the hyperfine splitting in muonic hydrogen as an alternative possibility for comparing ordinary and muonic hydrogen spectroscopy data on proton electromagnetic structure. This measurement critically depends on the energy dependence of the muon transfer rate to heavier gases in the epithermal range. The available data provide only qualitative information, and the theoretical predictions have not been verified. We propose a new method by measurements of the transfer rate in thermalized target at different temperatures, estimate its accuracy and investigate the optimal experimental conditions. - Highlights: • Method for measuring the energy dependence of muon transfer rate to higher-Z gases. • Thermalization and depolarization of muonic hydrogen studied by Monte Carlo method. • Optimal experimental conditions determined by Monte Carlo simulations. • Mathematical model and for estimating the uncertainty of the experimental results.

  13. Theory of the n = 2 levels in muonic helium-3 ions (United States)

    Franke, Beatrice; Krauth, Julian J.; Antognini, Aldo; Diepold, Marc; Kottmann, Franz; Pohl, Randolf


    The present knowledge of Lamb shift, fine-, and hyperfine structure of the 2S and 2P states in muonic helium-3 ions is reviewed in anticipation of the results of a first measurement of several 2S → 2P transition frequencies in the muonic helium-3 ion, μ3He+. This ion is the bound state of a single negative muon μ- and a bare helium-3 nucleus (helion), 3He++. A term-by-term comparison of all available sources, including new, updated, and so far unpublished calculations, reveals reliable values and uncertainties of the QED and nuclear structure-dependent contributions to the Lamb shift and the hyperfine splitting. These values are essential for the determination of the helion rms charge radius and the nuclear structure effects to the hyperfine splitting in μ3He+. With this review we continue our series of theory summaries in light muonic atoms [see A. Antognini et al., Ann. Phys. 331, 127 (2013); J.J. Krauth et al., Ann. Phys. 366, 168 (2016); and M. Diepold et al.">arXiv:1606.05231 (2016)].

  14. Nanofabrication of super-high-aspect-ratio structures in hydrogen silsesquioxane from direct-write e-beam lithography and hot development.

    Energy Technology Data Exchange (ETDEWEB)

    Ocola, L. E.; Tirumala, V. R.; Center for Nanoscale Materials; NIST


    Super-high-aspect-ratio structures (>10) in hydrogen silsesquioxane resist using direct write electron beam lithography at 100 kV and hot development and rinse are reported. Posts of 100 nm in width and 1.2 {micro}m tall have been successfully fabricated without the need of supercritical drying. Hot rinse solution with isopropyl alcohol has been used to reduce surface tension effects during drying. Dose absorption effects have been observed and modeled using known Monte Carlo models. These results indicate that for e-beam exposures of thick negative resists (>1 {micro}m), the bottom of the structures will have less cross-link density and therefore will be less stiff than the top. These results will have impact in the design of high-aspect-ratio structures that can be used in microelectromechanical system devices and high-aspect-ratio Fresnel zone plates.

  15. Hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Pier, M.


    A transcript is presented of a speech on the history of the development of hydrogenation of coal and tar. Apparently the talk had been accompanied by the showing of photographic slides, but none of the pictures were included with the report. In giving the history, Dr. Pier mentioned the dependence of much of the development of hydrogenation upon previous development in the related areas of ammonia and methanol syntheses, but he also pointed out several ways in which equipment appropriate for hydrogenation differed considerably from that used for ammonia and methanol. Dr. Pier discussed the difficulties encountered with residue processing, design of the reaction ovens, manufacture of ovens and preheaters, heating of reaction mixtures, development of steels, and development of compressor pumps. He described in some detail his own involvement in the development of the process. In addition, he discussed the development of methods of testing gasolines and other fuels. Also he listed some important byproducts of hydrogenation, such as phenols and polycyclic aromatics, and he discussed the formation of iso-octane fuel from the butanes arising from hydrogenation. In connection with several kinds of equipment used in hydrogenation (whose pictures were being shown), Dr. Pier gave some of the design and operating data.

  16. Gas doping ratio effects on p-type hydrogenated nanocrystalline silicon thin films grown by hot-wire chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Luo, P.Q. [Solar Energy Institute, Department of Physics, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China)], E-mail:; Zhou, Z.B. [Solar Energy Institute, Department of Physics, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China)], E-mail:; Chan, K.Y. [Thin Film Laboratory, Faculty of Engineering, Multimedia University, Jalan Multimedia, Cyberjaya 63100, Selangor (Malaysia); Tang, D.Y.; Cui, R.Q.; Dou, X.M. [Solar Energy Institute, Department of Physics, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China)


    Hydrogenated nanocrystalline silicon (nc-Si:H) grown by hot-wire chemical vapor deposition (HWCVD) has recently drawn significant attention in the area of thin-film large area optoelectronics due to possibility of high deposition rate. We report on the effects of diborane (B{sub 2}H{sub 6}) doping ratio on the microstructural and optoelectrical properties of the p-type nc-Si:H thin films grown by HWCVD at low substrate temperature of 200 deg. C and with high hydrogen dilution ratio of 98.8%. An attempt has been made to elucidate the boron doping mechanism of the p-type nc-Si:H thin films deposited by HWCVD and the correlation between the B{sub 2}H{sub 6} doping ratio, crystalline volume fraction, optical band gap and dark conductivity.

  17. Determination of diffusion coefficients of hydrogen and deuterium in Zr–2.5%Nb pressure tube material using hot vacuum extraction-quadrupole mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Shrivastava, Komal Chandra, E-mail: [Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Kulkarni, A.S.; Ramanjaneyulu, P.S. [Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Sunil, Saurav [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Saxena, M.K. [Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Singh, R.N. [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Tomar, B.S.; Ramakumar, K.L. [Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)


    The diffusion coefficients of hydrogen and deuterium in Zr–2.5%Nb alloy were measured in the temperature range 523 to 673 K, employing hot vacuum extraction-quadrupole mass spectrometry (HVE-QMS). One end of the Zr–2.5%Nb alloy specimens was charged electrolytically with the desired hydrogen isotope. After annealing at different temperatures for a predetermined time, the specimens were cut into thin slices, which were analyzed for their H{sub 2}/D{sub 2} content using the HVE-QMS technique. The depth profile data were fitted into the equation representing the solution of Fick’s second law of diffusion. The activation energy of hydrogen/deuterium diffusion was obtained from the Arrhenius relation between the diffusion coefficient and temperature. The temperature dependent diffusion coefficient can be represented as D{sub H} = 1.41 × 10{sup −7} exp(−36,000/RT) and D{sub D} = 6.16 × 10{sup −8} exp(−35,262/RT) for hydrogen and deuterium, respectively.

  18. Effects of hydrogen on the structural and optical properties of MoSe2 grown by hot filament chemical vapor deposition (United States)

    Wang, B. B.; Zhu, M. K.; Levchenko, I.; Zheng, K.; Gao, B.; Xu, S.; Ostrikov, K.


    The role of reactive environment and hydrogen specifically in growth and structure of molybdenum selenide (MoSe2) nanomaterials is presently debated, and it is not clear whether hydrogen can promote the growth of MoSe2 sheets and alter their electronic properties. To find efficient, convenient methods for controlling the nucleation, growth and resultant properties of MoSe2 nanomaterials, MoSe2 nanoflakes were synthesized on silicon substrates by hot filament chemical vapor deposition using molybdenum trioxide and selenium powders in pure hydrogen, nitrogen gases and hydrogen-nitrogen mixtures. The structures and composition of synthesized MoSe2 nanoflakes were studied using the advanced characterization instruments including field emission scanning electron microscopy, micro-Raman spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy and energy dispersive X-ray spectrometry. The analysis of the growth process indicates that hydrogen can improve the formation of MoSe2 nanoflakes and significantly alter their properties due to the high reduction capacity of hydrogen and the creation of more nucleation centers of MoSe2 nanoflakes on the silicon surface. The study of photoluminescent (PL) properties reveals that the MoSe2 nanoflakes can generate a strong PL band at about 631 nm, differently from the plain MoSe2 nanoflakes. The major difference in the PL properties may be related to the edges of MoSe2 nanoflakes. These results can be used to control the growth and structure of MoSe2-based nanomaterials and contribute to the development of advanced MoSe2-based optoelectronic devices.

  19. Full Annulus Numerical Study of Hot Streaks Propagation in a Hydrogen-rich Syngas-Fired Heavy Duty Axial Turbine


    Ioannou, E.; Sayma, A. I.


    This paper presents a study of the effect of fuel composition on hot streaks propagation in a high-pressure turbine using a full annulus unsteady computational fluid dynamics analysis of the first two stages. Hot streaks result from the inherent non-uniformities of temperature profiles at the exit of the combustion chamber. Variations in composition arise from current challenges requiring gas turbines to adapt to fuel variations driven by the need to reduce CO2 emissions through the use of sy...

  20. Hydrogen. (United States)

    Bockris, John O'M


    The idea of a "Hydrogen Economy" is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  1. Enhanced hot-electron production and strong-shock generation in hydrogen-rich ablators for shock ignition (United States)

    Theobald, W.; Bose, A.; Yan, R.; Betti, R.; Lafon, M.; Mangino, D.; Christopherson, A. R.; Stoeckl, C.; Seka, W.; Shang, W.; Michel, D. T.; Ren, C.; Nora, R. C.; Casner, A.; Peebles, J.; Beg, F. N.; Ribeyre, X.; Llor Aisa, E.; Colaïtis, A.; Tikhonchuk, V.; Wei, M. S.


    Experiments were performed with CH, Be, C, and SiO2 ablators interacting with high-intensity UV laser radiation (5 × 1015 W/cm2, λ = 351 nm) to determine the optimum material for hot-electron production and strong-shock generation. Significantly more hot electrons are produced in CH (up to ˜13% instantaneous conversion efficiency), while the amount is a factor of ˜2 to 3 lower in the other ablators. A larger hot-electron fraction is correlated with a higher effective ablation pressure. The higher conversion efficiency in CH is attributed to stronger damping of ion-acoustic waves because of the presence of light H ions.

  2. Hydrogen

    Directory of Open Access Journals (Sweden)

    John O’M. Bockris


    Full Text Available The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer. Methanol made with CO2 from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan. Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  3. Hot-Fire Test of Liquid Oxygen/Hydrogen Space Launch Mission Injector Applicable to Exploration Upper Stage (United States)

    Barnett, Greg; Turpin, Jason; Nettles, Mindy


    This task is to hot-fire test an existing Space Launch Mission (SLM) injector that is applicable for all expander cycle engines being considered for the exploration upper stage. The work leverages investment made in FY 2013 that was used to additively manufacture three injectors (fig. 1) all by different vendors..

  4. Performance of carbon-based hot frit substrates. 2, Coating performance studies in hydrogen at atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Barletta, R.; Vanier, P.; Adams, J.; Svandrlik, J.; Powell, J.R.


    Erosion tests were conducted on coated graphite and 2D, 3D carbon- carbons in 1 atm hydrogen at high temperatures. Refractory NbC, TaC coatings were used. It was found that the most effective combination of coating and substrate was TaC deposited by chemical vapor reaction method on AXF-5QI graphite.

  5. Study of structural and electronic environments of hydrogenated amorphous silicon carbonitride (a-SiCN:H) films deposited by hot wire chemical vapor deposition (United States)

    Swain, Bibhu P.; Hwang, Nong M.


    Hydrogenated amorphous silicon carbon nitride (a-SiCN:H) thin films were deposited by hot wire chemical vapor deposition (HWCVD) using SiH 4, CH 4, NH 3 and H 2 as precursors. The effects of the H 2 dilution on structural and chemical bonding of a-SiCN:H has been investigated by Raman and X-ray photoelectron spectroscopy (XPS). Increasing the H 2 flow rate in the precursor gas more carbon is introduced into the a-SiCN:H network resulting in decrease of silicon content in the film from 41 at.% to 28.8 at.% and sp 2 carbon cluster increases when H 2 flow rate is increased from 0 to 20 sccm.

  6. Study of structural and electronic environments of hydrogenated amorphous silicon carbonitride (a-SiCN:H) films deposited by hot wire chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Swain, Bibhu P. [National Research Laboratory of Charged Nanoparticles, School of Materials Science and Engineering, Seoul National University, Seoul (Korea, Republic of)], E-mail:; Hwang, Nong M. [National Research Laboratory of Charged Nanoparticles, School of Materials Science and Engineering, Seoul National University, Seoul (Korea, Republic of)


    Hydrogenated amorphous silicon carbon nitride (a-SiCN:H) thin films were deposited by hot wire chemical vapor deposition (HWCVD) using SiH{sub 4}, CH{sub 4}, NH{sub 3} and H{sub 2} as precursors. The effects of the H{sub 2} dilution on structural and chemical bonding of a-SiCN:H has been investigated by Raman and X-ray photoelectron spectroscopy (XPS). Increasing the H{sub 2} flow rate in the precursor gas more carbon is introduced into the a-SiCN:H network resulting in decrease of silicon content in the film from 41 at.% to 28.8 at.% and sp{sup 2} carbon cluster increases when H{sub 2} flow rate is increased from 0 to 20 sccm.

  7. Self-ignition of hydrocarbons/hydrogen mixtures in a supersonic hot co-flow of air; Auto-allumage de Melanges Hydrocarbures/Hydrogene dans un Ecoulement Supersonique Confine d'Air Chaud

    Energy Technology Data Exchange (ETDEWEB)

    Erwin George; Philippe Magre; Vladimir Sabel' nikov [Office National d' Etudes et Recherches Aerospatiales, ONERA - DEFA / EFCA, Chemin de la Huniere, 91761 Palaiseau Cedex (France)


    The aim of this paper is the study of the self-ignition of hydrocarbons/hydrogen mixtures (or pure hydrogen) in a confined supersonic flow. Hydrocarbon fuels are here the methane and the ethylene. This study is linked to the hypersonic vehicle program, called LEA and developed jointly by ONERA and MBDA France since 2003. The flight envelope of LEA will be in the range of Mach 4 to 8. The studied case is a jet of fuel outgoing from a cylindrical injector at Mach 2 and discharging in a hot co-flow of air at Mach 2. First, we present the operating conditions of the study and the obtained experimental results. A mono dimensional analysis of the flow is proposed in order to explain the different modes of combustion obtained in the experience. A physical model based on PLIF visualizations of the flow is proposed. We will see thus, that with physical assumptions, the experimental ignition delays can be correctly predicted by calculation. (authors)

  8. Experimental study of muonic x-ray transitions in mercury isotopes. [Fermi distribution, B(E2)

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, A.A.; Miller, J.P.; Powers, R.J.; Zehnder, A.; Rushton, A.M.; Welsh, R.E.; Kunselman, A.R.; Roberson, P.; Walter, H.K.


    Muonic x-ray spectra were measured for /sup 198/ /sup 199/ /sup 200/ /sup 201/ /sup 202/ and /sup 204/Hg. These data were interpreted in terms of a two parameter Fermi distribution for the charge density. The spectroscopic quadrupole moments (Q/sub s/) of some of the 2/sup +/ nuclear states were inferred. For /sup 199/Hg the spectroscopic quadrupole moments of the first two excited states and the B(E2)'s connecting these states to the ground state were determined. For /sup 201/Hg the ground state quadrupole moment was obtained as well as several other E2 moments but the interpretation of the data was hampered by a possible incomplete knowledge of the nuclear scheme of this nucleus. The muonic isotope shifts were measured and interpreted in terms of deltaR/sub k/ and are compared to electronic x-ray and optical isotope shift measurements. 41 references

  9. The influence of charge effect on the growth of hydrogenated amorphous silicon by the hot-wire chemical vapor deposition technique

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Q.; Nelson, B.P.; Iwaniczko, E.; Mahan, A.H.; Crandall, R.S.; Benner, J. [National Renewable Energy Lab., Golden, CO (United States)


    The authors observe at lower substrate temperatures that the scatter in the dark conductivity on hydrogenated amorphous silicon (a-Si:H) films grown on insulating substrates (e.g., Corning 7059 glass) by the hot-wire chemical vapor deposition technique (HWCVD) can be five orders of magnitude or more. This is especially true at deposition temperatures below 350 C. However, when the authors grow the same materials on substrates with a conductive grid, virtually all of their films have acceptable dark conductivity (< 5 {times} 10{sup {minus}10} S/cm) at all deposition temperatures below 425 C. This is in contrast to only about 20% of the materials grown in this same temperature range on insulating substrates having an acceptable dark conductivity. The authors estimated an average energy of 5 eV electrons reaching the growing surface in vacuum, and did additional experiments to see the influence of both the electron flux and the energy of the electrons on the film growth. Although these effects do not seem to be important for growing a-Si:H by HWCVD on conductive substrates, they help better understand the important parameters for a-Si:H growth, and thus, to optimize these parameters in other applications of HWCVD technology.

  10. Observation of electric quadrupole X-ray transitions in muonic thallium, lead and bismuth

    CERN Document Server

    Schneuwly, H; Engfer, R; Jahnke, U; Kankeleit, E; Lindenberger, K H; Pearce, R M; Petitjean, C; Schellenberg, L; Schröder, W U; Walter, H K; Zehnder, A


    Electric quadrupole X-ray transitions (5g to 3d, 4f to 2p, and 3d to 1s) have been observed in muonic Tl, Pb and Bi. From the 3 to 1 transitions, energy splittings of the n=3 levels were deduced. From a comparison of the relative intensities of E1 and E2 transitions the population ratios 5g/5f, 4f/4d, and 3d/3p were deduced. These ratios are well reproduced by a cascade calculation assuming a statistical initial population at n=20, including K, L and M shell conversion. In the case of /sup 205/Tl discrepancies between the experimental and the calculated 3d-1s/3p-is intensity ratio can be explained by nuclear excitation. From the 3p/sub 3/2/ to 1s/sub 1/2/ intensity in /sup 209 /Bi one can deduce the ratio of the radiationless to the X-ray transition width and give limits for prompt neutron emission from the 3d level. (23 refs).

  11. Measurement of topological muonic branching ratios of charmed hadrons produced in neutrino-induced charged-current interactions

    CERN Document Server

    Kayis-Topaksu, A; Van Dantzig, R; De Jong, M; Oldeman, R G C; Güler, M; Köse, U; Tolun, P; Catanesi, M G; Muciaccia, M T; Winter, Klaus; Van de Vyver, B; Vilain, P; Wilquet, G; Saitta, B; Di Capua, E; Ogawa, S; Shibuya, H; Hristova, I R; Kawamura, T; Kolev, D; Meinhard, H; Panman, J; Rozanov, A; Tsenov, R V; Uiterwijk, J W E; Zucchelli, P; Goldberg, J; Chikawa, M; Song, J S; Yoon, C S; Kodama, K; Ushida, N; Aoki, S; Hara, T; Delbar, T; Favart, D; Grégoire, G; Kalinin, S; Makhlyoueva, I V; Artamonov, A V; Gorbunov, P; Khovanskii, V D; Shamanov, V V; Tsukerman, I; Bruski, N; Frekers, D; Hoshino, K; Kawada, J; Komatsu, M; Myanishi, M; Nakamura, M; Nakano, T; Narita, K; Niu, K; Niwa, K; Nonaka, N; Sato, O; Toshito, T; Buontempo, S; Cocco, A G; D'Ambrosio, N; De Lellis, G; De Rosa, G; Di Capua, F; Fiorillo, G; Marotta, A; Messina, M; Migliozzi, P; Scotto-Lavina, L; Strolin, P; Tioukov, V; Okusawa, T; Dore, U; Loverre, P F; Ludovici, L; Rosa, G; Santacesaria, R; Satta, A; Spada, F R; Barbuto, E; Bozza, C; Grella, G; Romano, G; Sirignano, C; Sorrentino, S; Sato, Y; Tezuka, I


    From 1994 to 1997, the emulsion target of the CHORUS detector was exposed to the wideband neutrino beam of the CERN SPS. In total about 100 000 charged-current neutrino interactions were located in the nuclear emulsion target and fully reconstructed. From this sample of events based on the data acquired by new automatic scanning systems, 2013 charm-decay events were selected by a pattern recognition program. They were confirmed as decays through visual inspection. Based on these events, the effective branching ratio of charmed particles into muons was determined to be Bμ = [7.3 ± 0.8 (stat) ± 0.2 (syst)] × 10âˆ'2. In addition, the muonic branching ratios are presented for dominating charm decay topologies. Normalization of the muonic decays to chargedcurrent interactions provides _μâˆ'μ+/_cc = [3.16 ± 0.34 (stat) ± 0.09 (syst)] × 10âˆ'3. Selecting only events with visible energy greater than 30 GeV gives a value of Bμ that is less affected by the charm production threshold ...

  12. Vii. New Kr IV - VII Oscillator Strengths and an Improved Spectral Analysis of the Hot, Hydrogen-deficient Do-type White Dwarf RE 0503-289 (United States)

    Rauch, T.; Quinet, P.; Hoyer, D.; Werner, K.; Richter, P.; Kruk, J. W.; Demleitner, M.


    For the spectral analysis of high-resolution and high signal-to-noise (SN) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Krivvii oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTEmodel-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Krivvii oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high SN ultraviolet (UV)observations of the hot white dwarf RE 0503.

  13. Dark hydrogen fermentations

    NARCIS (Netherlands)

    Vrije, de G.J.; Claassen, P.A.M.


    The production of hydrogen is a ubiquitous, natural phenomenon under anoxic or anaerobic conditions. A wide variety of bacteria, in swamps, sewage, hot springs, the rumen of cattle etc. is able to convert organic matter to hydrogen, CO2 and metabolites like acetic acid, lactate, ethanol and alanine.

  14. Hot Flashes (United States)

    ... Risk factors Not all women who go through menopause have hot flashes, and it's not clear why some women do have them. Factors that may increase your risk include: Smoking. Women who smoke are more likely to get hot flashes. Obesity. A high body mass index (BMI) is associated ...

  15. Hot flushes

    African Journals Online (AJOL)

    without thermoregulatory homeostatic mechanisms, such as sweating, being triggered. Small fluctuations in core body. Abstract. Vasomotor symptoms, such as hot flushes and night sweats, are considered to be the cardinal symptoms of menopause, and are experienced by most women. The physiology of hot flushes is not ...

  16. Open heavy-flavour and electroweak boson measurements via the (di-)muonic decay channel with ALICE at the LHC (United States)

    Johnson Senosi, Kgotlaesele; ALICE Collaboration


    Heavy flavours (charm and beauty) and electroweak bosons (W and Z) are produced in initial hard partonic scatterings. The former interact strongly with the medium formed in ultra-relativistic heavy-ion collisions throughout its evolution, thus making them well suited to investigate its properties. Furthermore, heavy-flavour measurements in proton-nucleus collisions can be used to investigate initial-state effects whereas in proton-proton (pp) collisions they are considered an important test for perturbative Quantum ChromoDynamics (pQCD) predictions. In addition, open heavy-flavour measurements in pp collisions are used as a reference for proton-lead (p-Pb) and lead-lead (Pb-Pb) collisions. On the other hand, electroweak bosons and their leptonic decay products only interact weakly with the QCD matter and thus are suitable probes to test the validity of binary-collision scaling of hard processes. Moreover, their measurements in p-Pb collisions could help to constrain nuclear parton distribution functions. The ALICE muon spectrometer allows the measurement of open heavy flavour, W- and Z-boson production at forward rapidity (-4.0 < η < -2.5) exploiting their (di)muonic decay channel. In this talk the results obtained with the LHC Run I data in pp, p-Pb and Pb-Pb collisions will be discussed and compared with theoretical predictions.

  17. Inclusive Production of the $\\omega$ and $\\eta$ Mesons in Z Decays, and the Muonic Branching Ratio of the $\\omega$

    CERN Document Server

    Heister, A.; Barate, R.; De Bonis, I.; Decamp, D.; Goy, C.; Lees, J.P.; Merle, E.; Minard, M.N.; Pietrzyk, B.; Boix, G.; Bravo, S.; Casado, M.P.; Chmeissani, M.; Crespo, J.M.; Fernandez, E.; Fernandez-Bosman, M.; Garrido, L.; Grauges, E.; Martinez, M.; Merino, G.; Miquel, R.; Mir, L.M.; Pacheco, A.; Ruiz, H.; Colaleo, A.; Creanza, D.; de Palma, M.; Iaselli, G.; Maggi, G.; Maggi, M.; Nuzzo, S.; Ranieri, A.; Raso, G.; Ruggieri, F.; Selvaggi, G.; Silvestris, L.; Tempesta, P.; Tricomi, A.; Zito, G.; Huang, X.; Lin, J.; Ouyang, Q.; Wang, T.; Xie, Y.; Xu, R.; Xue, S.; Zhang, J.; Zhang, L.; Zhao, W.; Abbaneo, D.; Azzurri, P.; Buchmuller, O.; Cattaneo, M.; Cerutti, F.; Clerbaux, B.; Drevermann, H.; Forty, R.W.; Frank, M.; Gianotti, F.; Greening, T.C.; Hansen, J.B.; Harvey, J.; Hutchcroft, D.E.; Janot, P.; Jost, B.; Kado, M.; Mato, P.; Moutoussi, A.; Ranjard, F.; Rolandi, Gigi; Schlatter, D.; Schneider, O.; Sguazzoni, G.; Tejessy, W.; Teubert, F.; Valassi, A.; Videau, I.; Ward, J.; Badaud, F.; Falvard, A.; Gay, P.; Henrard, P.; Jousset, J.; Michel, B.; Monteil, S.; Montret, J-C.; Pallin, D.; Perret, P.; Hansen, J.D.; Hansen, J.R.; Hansen, P.H.; Nilsson, B.S.; Waananen, A.; Kyriakis, A.; Markou, C.; Simopoulou, E.; Vayaki, A.; Zachariadou, K.; Blondel, A.; Bonneaud, G.; Brient, J.-C.; Rouge, A.; Rumpf, M.; Swynghedauw, M.; Verderi, M.; Videau, H.; Ciulli, V.; Focardi, E.; Parrini, G.; Antonelli, A.; Antonelli, M.; Bencivenni, G.; Bologna, G.; Bossi, F.; Campana, P.; Capon, G.; Chiarella, V.; Laurelli, P.; Mannocchi, G.; Murtas, F.; Murtas, G.P.; Passalacqua, L.; Pepe-Altarelli, M.; Spagnolo, P.; Halley, A.; Lynch, J.G.; Negus, P.; O'Shea, V.; Raine, C.; Thompson, A.S.; Wasserbaech, S.; Cavanaugh, R.; Dhamotharan, S.; Geweniger, C.; Hanke, P.; Hansper, G.; Hepp, V.; Kluge, E.E.; Putzer, A.; Sommer, J.; Tittel, K.; Werner, S.; Wunsch, M.; Beuselinck, R.; Binnie, D.M.; Cameron, W.; Dornan, P.J.; Girone, M.; Marinelli, N.; Sedgbeer, J.K.; Thompson, J.C.; Ghete, V.M.; Girtler, P.; Kneringer, E.; Kuhn, D.; Rudolph, G.; Bouhova-Thacker, E.; Bowdery, C.K.; Finch, A.J.; Foster, F.; Hughes, G.; Jones, R.W.L.; Pearson, M.R.; Robertson, N.A.; Jakobs, K.; Kleinknecht, K.; Quast, G.; Renk, B.; Sander, H.G.; Wachsmuth, H.; Zeitnitz, C.; Bonissent, A.; Carr, J.; Coyle, P.; Leroy, O.; Payre, P.; Rousseau, D.; Talby, M.; Ragusa, F.; David, A.; Dietl, H.; Ganis, G.; Huttmann, K.; Lutjens, G.; Mannert, C.; Manner, W.; Moser, H.G.; Settles, R.; Stenzel, H.; Wiedenmann, W.; Wolf, G.; Boucrot, J.; Callot, O.; Davier, M.; Duflot, L.; Grivaz, J.F.; Heusse, P.; Jacholkowska, A.; Lefrancois, J.; Veillet, J.J.; Yuan, C.; Bagliesi, Giuseppe; Boccali, T.; Foa, L.; Giammanco, A.; Giassi, A.; Ligabue, F.; Messineo, A.; Palla, F.; Sanguinetti, G.; Sciaba, A.; Tenchini, R.; Venturi, A.; Verdini, P.G.; Blair, G.A.; Cowan, G.; Green, M.G.; Medcalf, T.; Misiejuk, A.; Strong, J.A.; Teixeira-Dias, P.; von Wimmersperg-Toeller, J.H.; Clifft, R.W.; Edgecock, T.R.; Norton, P.R.; Tomalin, I.R.; Bloch-Devaux, Brigitte; Colas, P.; Emery, S.; Kozanecki, W.; Lancon, E.; Lemaire, M.C.; Locci, E.; Perez, P.; Rander, J.; Renardy, J.F.; Roussarie, A.; Schuller, J.P.; Schwindling, J.; Trabelsi, A.; Vallage, B.; Konstantinidis, N.; Litke, A.M.; Taylor, G.; Beddall, A.; Booth, C.N.; Cartwright, S.; Combley, F.; Lehto, M.; Thompson, L.F.; Affholderbach, K.; Boehrer, Armin; Brandt, S.; Grupen, C.; Ngac, A.; Prange, G.; Sieler, U.; Giannini, G.; Rothberg, J.; Armstrong, S.R.; Berkelman, Karl; Cranmer, K.; Ferguson, D.P.S.; Gao, Y.; Gonzalez, S.; Hayes, O.J.; Hu, H.; Jin, S.; Kile, J.; McNamara, P.A., III; Nielsen, J.; Pan, Y.B.; von Wimmersperg-Toeller, J.H.; Wiedenmann, W.; Wu, J.; Wu, Sau Lan; Wu, X.; Zobernig, G.


    The inclusive production of the omega(782) vector meson in hadronic Z decays is measured and compared to model predictions. The analysis is based on 4 million hadronic Z decays recorded by the ALEPH detector between 1991 and 1995. The production rate for x_p = p_meson/p_beam > 0.05 is measured in the omega -> pi^+ pi^- pi^0 decay mode and found to be 0.585 +- 0.019_stat +- 0.033_sys per event. Inclusive eta meson production is also measured in the same decay channel for x_p > 0.10, obtaining 0.355 +- 0.011_stat +- 0.024_sys per event. The branching ratio for omega -> mu^+ mu^- is investigated. A total of 18.1 +- 5.9 events are observed, from which the muonic branching ratio is measured for the first time to be BR(omega -> mu^+ mu^-) = (9.0 +- 2.9_stat +- 1.1_sys)*10^-5.


    Energy Technology Data Exchange (ETDEWEB)

    Shaikhislamov, I. F.; Prokopov, P. A.; Berezutsky, A. G.; Zakharov, Yu. P.; Posukh, V. G. [Institute of Laser Physics SB RAS, Novosibirsk (Russian Federation); Khodachenko, M. L.; Lammer, H.; Kislyakova, K. G.; Fossati, L. [Space Research Institute, Austrian Acad. Sci., Graz (Austria); Johnstone, C. P., E-mail: [Department of Astrophysics, University of Vienna, Vienna (Austria)


    The interaction of escaping the upper atmosphere of a hydrogen-rich non-magnetized analog of HD 209458b with a stellar wind (SW) of its host G-type star at different orbital distances is simulated with a 2D axisymmetric multi-fluid hydrodynamic (HD) model. A realistic Sun-like spectrum of X-ray and ultraviolet radiation, which ionizes and heats the planetary atmosphere, together with hydrogen photochemistry, as well as stellar-planetary tidal interaction are taken into account to generate self-consistently an atmospheric HD outflow. Two different regimes of the planetary and SW interaction have been modeled. These are: (1) the “ captured by the star ” regime, when the tidal force and pressure gradient drive the planetary material beyond the Roche lobe toward the star, and (2) the “ blown by the wind ” regime, when sufficiently strong SW confines the escaping planetary atmosphere and channels it into the tail. The model simulates in detail the HD interaction between the planetary atoms, protons and the SW, as well as the production of energetic neutral atoms (ENAs) around the planet due to charge exchange between planetary atoms and stellar protons. The revealed location and shape of the ENA cloud, either as a paraboloid shell between the ionopause and bowshock (for the “ blown by the wind ” regime), or a turbulent layer at the contact boundary between the planetary stream and SW (for the “ captured by the star ” regime) are of importance for the interpretation of Ly α absorption features in exoplanetary transit spectra and characterization of the plasma environments.

  19. Hydrogen sulfide removal from hot coal gas by various mesoporous silica supported Mn{sub 2}O{sub 3} sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z.F.; Liu, B.S., E-mail:; Wang, F.; Wang, W.S.; Xia, C.; Zheng, S.; Amin, R.


    Graphical abstract: - Highlights: • Mn{sub 2}O{sub 3}/KIT-1 presented the best desulfurization performance at 600–850 °C. • High sulfur capacity of Mn{sub 2}O{sub 3}/KIT-1 correlated closely with 3-D channel of KIT-1. • Desulfurization character depended strongly on framework structure of sorbents. • High steam content suppressed greatly the occurrence of sulfidation reaction. - Abstract: A series of 50 wt% Mn{sub 2}O{sub 3} sorbents was prepared using various mesoporous silica, MCM-41, HMS, and KIT-1 as support. The influence of textural parameters of mesoporous silica, especially type of channel on the desulfurization performance of Mn{sub 2}O{sub 3} sorbents was investigated at 600–850 °C using hot coal gas containing 0.33 vol.% H{sub 2}S. The fresh and used sorbents were characterized by means of N{sub 2}-adsorption, x-ray diffraction (XRD), high resolution transmission microscopy (HRTEM) and H{sub 2} temperature- programmed reduction (H{sub 2}-TPR) techniques. The results confirmed that the manganese oxide was dispersed highly in regular pore channel of the mesoporous supports due to high surface area. Compared with the Mn{sub 2}O{sub 3}/diatomite, all mesoporous silica supported Mn{sub 2}O{sub 3} sorbents exhibited high breakthrough sulfur capacity and a sharp deactivation rate after the breakthrough point. Compared to Mn{sub 2}O{sub 3}/MCM-41 and Mn{sub 2}O{sub 3}/HMS sorbent, the Mn{sub 2}O{sub 3}/KIT-1 showed better desulfurization performance because of the 3D wormhole-like channel. The high sulfur capacity of the Mn{sub 2}O{sub 3}/KIT-1 sorbent was maintained during the eight consecutive desulfurization-regeneration cycles. The Mn{sub 2}O{sub 3}/KIT-1 still presented high desulfurization activity when hot coal gas contained low steam (<5%)

  20. Hot Soak


    Goldwater, H.


    The DVD is documentation of Hot Soak, as performed at the Queen’s Hotel, Penzance, Cornwall in an en suite bathroom, for Tract: Live Art Festival, 2006, curated by Art Surgery/ Newlyn Art Gallery. Hot Soak was originally made for home, London, 2005. This piece marries an everyday environment (bathroom) with extraordinary materials (ice cubes/ dress bleeding red into water) creating the surreal. Sontag’s understanding of camp as a love of the unnatural, artifice and exaggeration, can be ci...

  1. Full calculation of μpd and μdt muonic bound levels: Combination of Nikiforov-Uvarov method and variational approach (United States)

    Fatehizadeh, H.; Gheisari, R.; Falinejad, H.


    This paper develops a mathematical approach to calculate the ground state energies of μpd and μdt muonic ions. The calculations have been performed by combination of Nikiforov-Uvarov method and linear variational approach. Basis kets have been introduced to expand terms of wave function using a well definition of vector space in the hyper-spherical coordinates. The full calculations have been performed and compared with other variational calculations in the hyper-spherical harmonic formalism. The results of the variational energies show a fast convergence with a relatively small number of candidate basis functions.

  2. The Rydberg constant and proton size from atomic hydrogen (United States)

    Beyer, Axel; Maisenbacher, Lothar; Matveev, Arthur; Pohl, Randolf; Khabarova, Ksenia; Grinin, Alexey; Lamour, Tobias; Yost, Dylan C.; Hänsch, Theodor W.; Kolachevsky, Nikolai; Udem, Thomas


    At the core of the “proton radius puzzle” is a four–standard deviation discrepancy between the proton root-mean-square charge radii (rp) determined from the regular hydrogen (H) and the muonic hydrogen (µp) atoms. Using a cryogenic beam of H atoms, we measured the 2S-4P transition frequency in H, yielding the values of the Rydberg constant R∞ = 10973731.568076(96) per meterand rp = 0.8335(95) femtometer. Our rp value is 3.3 combined standard deviations smaller than the previous H world data, but in good agreement with the µp value. We motivate an asymmetric fit function, which eliminates line shifts from quantum interference of neighboring atomic resonances.

  3. Experience with hot catchpots

    Energy Technology Data Exchange (ETDEWEB)


    The first part of this report was actually a letter regarding the question, ''could the hot circulating pump be omitted when processing pitch at 700 atm.'' It had been stated that the hot circulation pump could be omitted if the quantity of cold letdown was correspondingly increased. The latest experiences with the catchpot at Poelitz showed the following. When running pitch, tar, or petroleum in the liquid-phase stalls, frequent trouble with the hot catchpot was encountered due to the coking. This coking was caused by irregular letdown yield, which could not be avoided due to small temperature fluctuations in the stall. This caused interruption of the uniform flow in the hot catchpot and the deposition of the solids contained in the letdown, largely catalyst solids, due to the asphalt content. Coking of the product was initiated by this concentration of catalyst solids. A perforated double jacket was inserted in the conical part of the catchpot through which about 3000 m/sup 3/ per hour of cold gas was blown in continuously. By this agitation and cooling in the lowest part of the catchpot, catalyst deposits were prevented from forming and the product received a continuous added supply of hydrogen. Another letter was given discussing the same question and an alternate solution. This second letter described Welheim's design for the hot catchpot. It featured introduction of 5000 to 6000 m/sup 3//hr of cold circulating gas into the lower part of the catchpot, and withdrawal of letdown from a point above the gas inlet. The advantages were continued agitation and cooling of the sludge and constant retention of some cold sludge in the catchpot (which evened out throughput and content fluctuations)

  4. Hot spots

    National Research Council Canada - National Science Library

    Nia, Amir M; Gassanov, Natig; Er, Fikret


    ..., several reddened skin lesions were observed. The obvious ''hot spots'' were located on both sides in the groin and above the bladder, with extension to the genital region, compli- cating the ability to catheterize the patient (Figure 1). The rest of the body surface was not affected, and no infectious source for the skin lesions was evident. After suc...

  5. HOT 2017

    DEFF Research Database (Denmark)

    Hannibal, Sara Stefansen

    HOT er en kvalitativ undersøgelse, der hvert år diskuterer og undersøger en lille udvalgt skare af danskkyndige fagpersoners bud på, hvad de er optagede af på literacyområdet her og nu – altså hvilke emner, de vil vurdere som aktuelle at forholde sig til i deres nuværende praksis....

  6. Hydrogen treatment of titanium based alloys (United States)

    Losertová, M.; Hartmann, M.; Schindler, I.; Drápala, J.


    The positive effect of the hydrogen on hot deformation behaviour at 700 and 750 °C was investigated after thermal hydrogen treatment of Ti6Al4V and Ti26Nb alloys. Comparing the results obtained for the non-hydrogenated and hydrogenated specimens of both alloys, it was found that the hydrogen content as high as 1325 wt. ppm has an obvious benefit effect on high temperature deformation behaviour in the Ti6Al4V alloy by stabilizing beta phase and lowering thermal deformation resistance. In the case of Ti26Nb alloy the hydrogen content of 2572 wt. ppm suppressed stress instabilities during hot compression but slightly increased thermal deformation resistance. The microstructure study was performed before and after the isothermal compression tests on the specimens in hydrogenated as well as in non-hydrogenated condition. The hydrogen amounts in the specimens were measured by means of an analyser LECO RH600.

  7. A new method to induce transitions in muonic atoms using a high-power tunable dye laser coupled to a stopping muon beam

    CERN Document Server

    Bertin, A; Duclos, J; Gastaldi, Ugo; Gorini, G; Neri, G; Picard, J; Pitzurra, O; Placci, A; Polacco, E; Stefanini, G; Torelli, G; Vitale, A; Zavattini, E


    An apparatus is described in which a ruby-pumped dye laser is used to induce transitions from the 2S to the 2P levels of the muonic ion ( mu He)/sup +/. The dye laser supplies infra-red radiation pulses in the wavelengths (8040-8180) AA, at typical repetition rates of 1 pulse every 4 s, with an energy release per pulse of 300 mJ for 1.2 J pumping energy. A special synchronization procedure is followed to trigger the laser in close coupling with the incoming muon beam which is stopped in a helium target at pressures between 40 and 50 atm. The other performances of the device are fully discussed with reference both to the laser facility and to the special high-pressure helium target. (23 refs).


    Energy Technology Data Exchange (ETDEWEB)

    Matthew R. June; John L. Hurley; Mark W. Johnson


    Iron aluminide hot gas filters have been developed using powder metallurgy techniques to form seamless cylinders. Three alloys were short-term corrosion tested in simulated IGCC atmospheres with temperatures between 925 F and 1200 F with hydrogen sulfide concentrations ranging from 783 ppm{sub v} to 78,300 ppm{sub v}. Long-term testing was conducted for 1500 hours at 925 F with 78,300 ppm{sub v}. The FAS and FAL alloys were found to be corrosion resistant in the simulated environments. The FAS alloy has been commercialized.

  9. Hydrogen sensor (United States)

    Duan, Yixiang; Jia, Quanxi; Cao, Wenqing


    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  10. High precision X-ray spectroscopy in hydrogen-like fermionic and bosonic atomic systems

    Energy Technology Data Exchange (ETDEWEB)

    Borchert, G.L.; Anagnostopoulos, D.; Augsburger, M.; Belmiloud, D.; Castelli, C.; Chatellard, D.; Daum, M.; Egger, J.P.; El-Khoury, P.; Elble, M.; Frosch, R.; Gorke, H.; Gotta, D.; Hauser, P.; Indelicato, P.; Kirch, K.; Lenz, S.; Nelms, N.; Rashid, K.; Schult, O.W.B. (and others)


    Some time after its formation an exotic atom may be considered a hydrogen-like system consisting of a nucleus and an exotic particle in a bound state. In this situation it is an ideal tool to study cascade properties, while for the innermost orbits it can be used to probe the interaction with the nucleus. From an extended series of experiments using high resolution X-ray spectroscopy for both aspects typical examples are reported and preliminary results are given: 1. To determine the complex scattering length in p-barH the 3D{yields}2P hyperfine transitions have been measured. 2. To determine the pion mass the 5 {yields} 4 transitions in {pi}{sup 14}N have been studied. In all cases a major contribution to the uncertainty originates from the calibration. Therefore a new method is proposed that will establish a universal set of high precision calibration lines for pionic, muonic and electronic systems.

  11. Studies of b-associated production and muonic decays of neutral Higgs bosons at the ATLAS experiment within the Minimal Supersymmetric Standard Model

    Energy Technology Data Exchange (ETDEWEB)

    Warsinsky, Markus


    This thesis presents a Monte Carlo study of neutral Higgs bosons of the Minimal Supersymmetric Standard Model (MSSM) decaying into muons at the ATLAS experiment at the CERN Large Hadron Collider. Signal and background processes are simulated using novel Monte Carlo generators that incorporate parts of higher order corrections and are expected to give a more accurate prediction than previous programs. The SHERPA Monte Carlo generator is validated for its use in the analysis and compared to results obtained with other programs. Where possible, the Monte Carlo event samples are normalized to higher order calculations. To increase the available Monte Carlo statistics, this study is based on the ATLAS fast detector simulation ATLFAST. Differences between ATLFAST and the detailed detector simulation of ATLAS are examined, and, where possible, correction procedures are devised. A cut based analysis is performed assuming an integrated luminosity of 30 fb{sup -1}, and optimized with respect to the discovery potential for MSSM Higgs bosons. The systematic uncertainties of the event selection and the Monte Carlo predictions are estimated. A method that can be used to estimate the background from data is presented and evaluated. Last, the discovery potential of the ATLAS experiment in the CP conserving benchmark scenarios of the MSSM is evaluated. One or more of the neutral Higgs bosons of the MSSM can be discovered in the muonic decay mode using 30 fb{sup -1} of data for low masses of the pseudoscalar boson A{sup 0}, if the model parameter tan {beta} is at least 20. For higher masses of the A{sup 0}, tan {beta} would need to be significantly higher to ensure a discovery in the studied decay channel. The sensitivity of ATLAS to MSSM Higgs bosons is multiple times larger than the one of previous and currently running experiments. (orig.)

  12. Hydrogen Generator (United States)


    A unit for producing hydrogen on site is used by a New Jersey Electric Company. The hydrogen is used as a coolant for the station's large generator; on-site production eliminates the need for weekly hydrogen deliveries. High purity hydrogen is generated by water electrolysis. The electrolyte is solid plastic and the control system is electronic. The technology was originally developed for the Gemini spacecraft.

  13. Really Hot Stars (United States)


    -2 in the LMC. PR Photo 09c/03: Nebula near the hot binary star BAT99-49 in the LMC. PR Photo 09d/03: The N44C Nebula in the LMC. Four unique images of highly excited nebulae in the Magellanic Clouds ESO PR Photo 09a/03 ESO PR Photo 09a/03 [Preview - JPEG: 400 x 472 pix - 74k [Normal - JPEG: 800 x 943 pix - 720k] [Full-Res - JPEG: 1200 x 1414 pix - 1.2M] ESO PR Photo 09b/03 ESO PR Photo 09b/03 [Preview - JPEG: 400 x 466 pix - 70k [Normal - JPEG: 800 x 931 pix - 928k] [Full-Res - JPEG: 1200 x 1397 pix - 1.8M] ESO PR Photo 09c/03 ESO PR Photo 09c/03 [Preview - JPEG: 400 x 469 pix - 74k [Normal - JPEG: 800 x 937 pix - 1.1M] [Full-Res - JPEG: 1200 x 1405 pix - 2.2M] ESO PR Photo 09d/03 ESO PR Photo 09d/03 [Preview - JPEG: 400 x 473 pix - 28k [Normal - JPEG: 800 x 945 pix - 368k] [Full-Res - JPEG: 1200 x 1418 pix - 600k] Captions: PR Photo 09a/03 is a reproduction of a "near-true" three-colour composite image of the highly excited nebula around the hot double star AB7 in the Small Magellanic Cloud (SMC), obtained in January 2002 with the FORS1 multi-mode instrument at the 8.2-m VLT MELIPAL telescope at the Paranal Observatory (Chile). It is based on three exposures through narrow-band optical (interference) filters that isolate the light from specific atoms and ions. In this rendering, the blue colour represents the light from singly ionized Helium (He II; wavelength 468.6 nm; exposure time 30 min), green corresponds to doubly ionized oxygen ([O III]; 495.7 + 500.7 nm; 5 min) and red to hydrogen atoms (H; H-alpha line at 656.2 nm; 5 min). Of these three ions, He II is the tracer of high excitation, i.e. the bluest areas of the nebula are the hottest. The sky field measures 400 x 400 arcsec2; the original pixel size on the 2k x 2k CCD is 0.23 arcsec. North is up and east to the left. Before combination, the CCD frames were flat-fielded and cleaned of cosmic-rays. Moreover, the stars in the blue (He II) image were removed in order to provide a clearer view of the surrounding

  14. Hot Spot Cosmic Accelerators (United States)


    The Universe is a violent place - as astronomers use increasingly sensitive means and methods to study the diverse processes out there, they become aware of the extraordinary forces acting in the space that surrounds us. With larger telescopes and ever-more sophisticated instruments, new information is gained about remote celestial objects and their behaviour. Among the most intriguing ones are the radio galaxies which emit prodiguous amounts of energy, in the form of fast-moving particles and intense electromagnetic radiation. One of these is known as 3C 445 ; it is located near the celestial equator within the zodiacal constellation Aquarius (The Waterman), at a distance of about 1 billion light-years. It most probably harbours a black hole at its centre, more massive than the one at the centre of our own galaxy, the Milky Way ( ESO PR 19/02 ). This galaxy was first observed from Cambridge (United Kingdom) in the 1950's and was listed as radio source no. 445 in the Third Cambridge Catalogue (1959), hence the name. Later observations revealed a strong outflow from this galaxy's active centre, visible on radio maps as two opposite plasma jets with strong synchrotron radiation ( [2]) originating from rapidly moving electrons in the associated magnetic field (image "a" in PR Photo 26/02 ). Now, a trio of European astronomers [1] have used two advanced instruments, ISAAC and FORS1 on the 8.2-m VLT ANTU telescope at the ESO Paranal Observatory (Chile) to obtain near-infrared images of these jets (images "b" and "c" in PR Photo 26/02 ). As can be clearly seen on the radio picture of 3C 445 obtained with the NRAO Very Large Array (VLA) radio facility ("a"), the plasma jets of fast particles emanating from the galaxy ram into the surrounding intergalactic medium (mostly primordial hydrogen), thereby producing two "shocks" , both at a distance of approximately 1.5 million light-years from the central galaxy and with particularly strong synchrotron emission. With a total

  15. Stellar laboratories. VII. New Kr iv - vii oscillator strengths and an improved spectral analysis of the hot, hydrogen-deficient DO-type white dwarf RE 0503-289 (United States)

    Rauch, T.; Quinet, P.; Hoyer, D.; Werner, K.; Richter, P.; Kruk, J. W.; Demleitner, M.


    Context. For the spectral analysis of high-resolution and high signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims: New Kr iv-vii oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods: We calculated Kr iv-vii oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. Results: We reanalyzed the effective temperature and surface gravity and determined Teff = 70000 ± 2000 K and log (g/ cm s-2) = 7.5 ± 0.1. We newly identified ten Kr v lines and one Kr vi line in the spectrum of RE 0503-289. We measured a Kr abundance of -3.3 ± 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km s-1National Commission for Astronomy.Tables A.9-A.12 are only available via the German Astrophysical Virtual Observatory (GAVO) service TOSS (

  16. Muon molecular formation and transfer rate in solid hydrogen-deuterium mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Jacot-Guillarmod, R. [Fribourg Univ. (Switzerland); Bailey, J.M. [Chester Technology (United Kingdom); Beer, G.A.; Knowles, P.E.; Mason, G.R.; Olin, A. [Victoria Univ., BC (Canada); Beveridge, J.L.; Marshall, G.M.; Mulhauser, F. [British Columbia Univ., Vancouver, BC (Canada). TRIUMF Facility; Fujiwara, M.C. [British Columbia Univ., Vancouver, BC (Canada); Huber, T.M. [Gustavus Adolphus Coll., St. Peter, MN (United States); Kammel, P.; Zmeskal, J. [Oesterreichische Akademie der Wissenschaften, Vienna (Austria); Kunselman, A.R. [Wyoming Univ., Laramie, WY (United States); Martoff, C.J. [Temple Univ., Philadelphia, PA (United States); Petitjean, C. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Wozniak, J. [Akademia Gorniczo-Hutnicza, Cracow (Poland). Inst. of Physics and Nuclear Technology


    In an experiment at TRIUMF to study muon-catalyzed fusion and associated atomic and molecular effects, negative muons were stopped in a solid protium hydrogen layer containing a small amount of deuterium. Most of the resulting {mu}H atoms disappeared by formation of HH{mu} molecules or by muon transfer to a deuteron. The {mu}D can drift almost freely through the hydrogen layer due to the Ramsauer-Townsend effect and may even leave the layer. If a thin neon layer is frozen atop the hydrogen, the exiting muonic atoms will very rapidly release their muon to a neon atom. The analysis of the time structure of the neon X-rays is used to determine the rates of the slower processes involved in the evolution of the {mu}H. This analysis has been performed with the help of Monte Carlo calculations, which simulate the kinetics of both {mu}H and {mu}D atoms in the hydrogen mixtures. (orig.). 23 refs.

  17. Hydrogen Embrittlement (United States)

    Woods, Stephen; Lee, Jonathan A.


    Hydrogen embrittlement (HE) is a process resulting in a decrease in the fracture toughness or ductility of a metal due to the presence of atomic hydrogen. In addition to pure hydrogen gas as a direct source for the absorption of atomic hydrogen, the damaging effect can manifest itself from other hydrogen-containing gas species such as hydrogen sulfide (H2S), hydrogen chloride (HCl), and hydrogen bromide (HBr) environments. It has been known that H2S environment may result in a much more severe condition of embrittlement than pure hydrogen gas (H2) for certain types of alloys at similar conditions of stress and gas pressure. The reduction of fracture loads can occur at levels well below the yield strength of the material. Hydrogen embrittlement is usually manifest in terms of singular sharp cracks, in contrast to the extensive branching observed for stress corrosion cracking. The initial crack openings and the local deformation associated with crack propagation may be so small that they are difficult to detect except in special nondestructive examinations. Cracks due to HE can grow rapidly with little macroscopic evidence of mechanical deformation in materials that are normally quite ductile. This Technical Memorandum presents a comprehensive review of experimental data for the effects of gaseous Hydrogen Environment Embrittlement (HEE) for several types of metallic materials. Common material screening methods are used to rate the hydrogen degradation of mechanical properties that occur while the material is under an applied stress and exposed to gaseous hydrogen as compared to air or helium, under slow strain rates (SSR) testing. Due to the simplicity and accelerated nature of these tests, the results expressed in terms of HEE index are not intended to necessarily represent true hydrogen service environment for long-term exposure, but rather to provide a practical approach for material screening, which is a useful concept to qualitatively evaluate the severity of

  18. Hydrogen Bibliography

    Energy Technology Data Exchange (ETDEWEB)


    The Hydrogen Bibliography is a compilation of research reports that are the result of research funded over the last fifteen years. In addition, other documents have been added. All cited reports are contained in the National Renewable Energy Laboratory (NREL) Hydrogen Program Library.

  19. Hydrogen exchange

    DEFF Research Database (Denmark)

    Jensen, Pernille Foged; Rand, Kasper Dyrberg


    Hydrogen exchange (HX) monitored by mass spectrometry (MS) is a powerful analytical method for investigation of protein conformation and dynamics. HX-MS monitors isotopic exchange of hydrogen in protein backbone amides and thus serves as a sensitive method for probing protein conformation...... and dynamics along the entire protein backbone. This chapter describes the exchange of backbone amide hydrogen which is highly quenchable as it is strongly dependent on the pH and temperature. The HX rates of backbone amide hydrogen are sensitive and very useful probes of protein conformation......, as they are distributed along the polypeptide backbone and form the fundamental hydrogen-bonding networks of basic secondary structure. The effect of pressure on HX in unstructured polypeptides (poly-dl-lysine and oxidatively unfolded ribonuclease A) and native folded proteins (lysozyme and ribonuclease A) was evaluated...

  20. Hot-pressed geopolymer

    DEFF Research Database (Denmark)

    Ranjbar, Navid; Mehrali, Mohammad; Maheri, Mahmoud R.


    /FA, duration of hot-pressing and sodium concentration are studied. Together with detailed experimental studies, our results reveal that the most dominant factor is the induced pressure. The main results indicated that the highest compressive strength of the geopolymer (134 MPa) could be obtained by employing...... the hot pressing, temperature and duration of 41.4 MPa, 350 °C and 20 min, respectively. The microstructure of the hot-pressed specimens showed more developed geopolymer matrix compared with conventional ones leading to higher compressive strength in much shortest time. The improved mechanical properties...

  1. Hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Donath, E.


    This report mentioned that not very severe demands for purity were made on the hydrogen used in hydrogenation of coal or similar raw materials, because the catalysts were not very sensitive to poisoning. However, the hydrogenation plants tried to remove most impurities anyway by means of oil washes. The report included a table giving the amount of wash oil used up and the amount of hydrogen lost by dissolving into the wash oil used up and the amount of hydrogen lost by dissolving into the wash oil in order to remove 1% of various impurities from 1000 m/sup 3/ of the circulating gas. The amounts of wash oil used up were 1.1 m/sup 3/ for removing 1% nitrogen, 0.3 m/sup 3/ for 1% carbon monoxide, 0.03 m/sup 3/ for 1% methane. The amount of hydrogen lost was 28 m/sup 3/ for 1% nitrogen, 9 m/sup 3/ for 1% methane and ranged from 9 m/sup 3/ to 39 m/sup 3/ for 1% carbon monoxide and 1 m/sup 3/ to 41 m/sup 3/ for carbon dioxide depending on whether the removal was done in liquid phase or vapor phase and with or without reduction of the oxide to methane. Next the report listed and described the major processes used in German hydrogenation plants to produce hydrogen. Most of them produced water gas, which then had its carbon monoxide changed to carbon dioxide, and the carbon oxides washed out with water under pressure and copper hydroxide solution. The methods included the Winkler, Pintsch-Hillebrand, and Schmalfeldt-Wintershall processes, as well as roasting of coke in a rotating generator, splitting of gases formed during hydrogenation, and separation of cokery gas into its components by the Linde process.

  2. Are hot-spots occluded from water? (United States)

    Moreira, Irina Sousa; Ramos, Rui Miguel; Martins, Joao Miguel; Fernandes, Pedro Alexandrino; Ramos, Maria João


    Protein-protein interactions are the basis of many biological processes and are governed by focused regions with high binding affinities, the warm- and hot-spots. It was proposed that these regions are surrounded by areas with higher packing density leading to solvent exclusion around them - "the O-ring theory." This important inference still lacks sufficient demonstration. We have used Molecular Dynamics (MD) simulations to investigate the validity of the O-ring theory in the context of the conformational flexibility of the proteins, which is critical for function, in general, and for interaction with water, in particular. The MD results were analyzed for a variety of solvent-accessible surface area (SASA) features, radial distribution functions (RDFs), protein-water distances, and water residence times. The measurement of the average solvent-accessible surface area features for the warm- and hot-spots and the null-spots, as well as data for corresponding RDFs, identify distinct properties for these two sets of residues. Warm- and hot-spots are found to be occluded from the solvent. However, it has to be borne in mind that water-mediated interactions have significant power to construct an extensive and strongly bonded interface. We observed that warm- and hot-spots tend to form hydrogen bond (H-bond) networks with water molecules that have an occupancy around 90%. This study provides strong evidence in support of the O-ring theory and the results show that hot-spots are indeed protected from the bulk solvent. Nevertheless, the warm- and hot-spots still make water-mediated contacts, which are also important for protein-protein binding.

  3. China's 'Hot Money' Problems

    National Research Council Canada - National Science Library

    Martin, Michael F; Morrison, Wayne M


    .... The recent large inflow of financial capital into China, commonly referred to as "hot money," has led some economists to warn that such flows may have a destabilizing effect on China's economy...

  4. Hot Weather Tips (United States)

    ... hot, heavy meals and don’t use the oven. Monitor medications: Find out if the person’s medications ... Photo: By High Contrast (Own work) [CC BY 3.0 de ( ...

  5. Non-thermal hydrogen atoms in the terrestrial upper thermosphere. (United States)

    Qin, Jianqi; Waldrop, Lara


    Model predictions of the distribution and dynamical transport of hydrogen atoms in the terrestrial atmosphere have long-standing discrepancies with ultraviolet remote sensing measurements, indicating likely deficiencies in conventional theories regarding this crucial atmospheric constituent. Here we report the existence of non-thermal hydrogen atoms that are much hotter than the ambient oxygen atoms in the upper thermosphere. Analysis of satellite measurements indicates that the upper thermospheric hydrogen temperature, more precisely the mean kinetic energy of the atomic hydrogen population, increases significantly with declining solar activity, contrary to contemporary understanding of thermospheric behaviour. The existence of hot hydrogen atoms in the upper thermosphere, which is the key to reconciling model predictions and observations, is likely a consequence of low atomic oxygen density leading to incomplete collisional thermalization of the hydrogen population following its kinetic energization through interactions with hot atomic or ionized constituents in the ionosphere, plasmasphere or magnetosphere.

  6. Hot Jupiter Magnetospheres (United States)

    Trammell, George B.; Arras, Phil; Li, Zhi-Yun


    The upper atmospheres of close-in gas giant exoplanets ("hot Jupiters") are subjected to intense heating and tidal forces from their parent stars. The atomic (H) and ionized (H+) hydrogen layers are sufficiently rarefied that magnetic pressure may dominate gas pressure for expected planetary magnetic field strength. We examine the structure of the magnetosphere using a 3D isothermal magnetohydrodynamic model that includes a static "dead zone" near the magnetic equator containing gas confined by the magnetic field, a "wind zone" outside the magnetic equator in which thermal pressure gradients and the magneto-centrifugal-tidal effect give rise to a transonic outflow, and a region near the poles where sufficiently strong tidal forces may suppress transonic outflow. Using dipole field geometry, we estimate the size of the dead zone to be several to tens of planetary radii for a range of parameters. Tides decrease the size of the dead zone, while allowing the gas density to increase outward where the effective gravity is outward. In the wind zone, the rapid decrease of density beyond the sonic point leads to smaller densities relative to the neighboring dead zone, which is in hydrostatic equilibrium. To understand the appropriate base conditions for the 3D isothermal model, we compute a simple 1D thermal model in which photoelectric heating from the stellar Lyman continuum is balanced by collisionally excited Lyα cooling. This 1D model exhibits a H layer with temperature T ~= 5000-10,000 K down to a pressure P ~ 10-100 nbar. Using the 3D isothermal model, we compute maps of the H column density as well as the Lyα transmission spectra for parameters appropriate for HD 209458b. Line-integrated transit depths sime5%-10% can be achieved for the above base conditions, in agreement with the results of Koskinen et al. A deep, warm H layer results in a higher mass-loss rate relative to that for a more shallow layer, roughly in proportion to the base pressure. Strong magnetic

  7. Operation of metal hydride hydrogen storage systems for hydrogen compression using solar thermal energy

    Directory of Open Access Journals (Sweden)

    Naruki Endo


    Full Text Available By using a newly constructed bench-scale hydrogen energy system with renewable energy, ‘Pure Hydrogen Energy System’, the present study demonstrates the operations of a metal hydride (MH tank for hydrogen compression as implemented through the use solar thermal energy. Solar thermal energy is used to generate hot water as a heat source of the MH tank. Thus, 70 kg of LaNi5, one of the most typical alloys used for hydrogen storage, was placed in the MH tank. We present low and high hydrogen flow rate operations. Then, the operations under winter conditions are discussed along with numerical simulations conducted from the thermal point of view. Results show that a large amount of heat (>100 MJ is generated and the MH hydrogen compression is available.

  8. IR Hot Wave

    Energy Technology Data Exchange (ETDEWEB)

    Graham, T. B.


    The IR Hot Wave{trademark} furnace is a breakthrough heat treatment system for manufacturing metal components. Near-infrared (IR) radiant energy combines with IR convective heating for heat treating. Heat treatment is an essential process in the manufacture of most components. The controlled heating and cooling of a metal or metal alloy alters its physical, mechanical, and sometimes chemical properties without changing the object's shape. The IR Hot Wave{trademark} furnace offers the simplest, quickest, most efficient, and cost-effective heat treatment option for metals and metal alloys. Compared with other heat treatment alternatives, the IR Hot Wave{trademark} system: (1) is 3 to 15 times faster; (2) is 2 to 3 times more energy efficient; (3) is 20% to 50% more cost-effective; (4) has a {+-}1 C thermal profile compared to a {+-}10 C thermal profile for conventional gas furnaces; and (5) has a 25% to 50% smaller footprint.

  9. Hydrogen program overview

    Energy Technology Data Exchange (ETDEWEB)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies


    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  10. Hydrogen usage

    Energy Technology Data Exchange (ETDEWEB)


    This short tabular report listed the number of m/sup 3/ of hydrogen required for a (metric) ton of product for various combinations of raw material and product in a hydrogenation procedure. In producing auto gasoline, bituminous coal required 2800 m/sup 3/, brown coal required 2400 m/sup 3/, high-temperature-carbonization tar required 2100 m/sup 3/, bituminous coal distillation tar required 1300 m/sup 3/, brown-coal low-temperature-carbonization tar required 850 m/sup 3/, petroleum residues required 900 m/sup 3/, and gas oil required 500 m/sup 3/. In producing diesel oil, brown coal required 1900 m/sup 3/, whereas petroleum residues required 500 m/sup 3/. In producing diesel oil, lubricants, and paraffin by the TTH (low-temperature-hydrogenation) process, brown-coal low-temperature-carbonization tar required 550 m/sup 3/. 1 table.

  11. Precision spectroscopy of the 2S-4P{sub 1/2} transition in atomic hydrogen on a cold thermal beam of optically excited 2S atoms

    Energy Technology Data Exchange (ETDEWEB)

    Beyer, Axel; Kolachevsky, Nikolai; Alnis, Janis; Yost, Dylan C.; Matveev, Arthur; Parthey, Christian G.; Pohl, Randolf; Udem, Thomas [Max-Planck-Institut fuer Quantenoptik, 85748 Garching (Germany); Khabarova, Ksenia [FSUE ' VNIIFTRI' , 141570 Moscow (Russian Federation); Haensch, Theodor W. [Max-Planck-Institut fuer Quantenoptik, 85748 Garching (Germany); Ludwig-Maximilians-Universitaet, 80799 Muenchen (Germany)


    The 'proton size puzzle', i.e. the discrepancy between the values for the proton r.m.s. charge radius deduced from precision spectroscopy of atomic hydrogen and electron-proton-scattering on one side and the value deduced from muonic hydrogen spectroscopy on the other side, has been persisting for more than two years now. Although huge efforts have been put into trying to resolve this discrepancy from experimental and theoretical side, no convincing argument could be found so far. In this talk, we report on a unique precision spectroscopy experiment on atomic hydrogen, which is aiming to bring some light to the hydrogen part of the puzzle: In contrast to any previous high resolution experiment probing a transition frequency between the meta-stable 2S state and a higher lying nL state (n=3,4,6,8,12, L=S,P,D), our measurement of the 2S-4P{sub 1/2} transition frequency is the first experiment being performed on a cold thermal beam of hydrogen atoms optically excited to the 2S state. We will discuss how this helps to efficiently suppresses leading systematic effects of previous measurements and present the preliminary results we obtained so far.

  12. Versatile Hydrogen

    Indian Academy of Sciences (India)

    Hydrogen is probably the most intriguing ele- ment in the periodic table. Although it is only the seventh most abundant element on earth, it is the most abundant element in the uni- verse. It combines with almost all the ele- ments of the periodic table, except for a few transition elements, to form binary compounds of the type E.

  13. Hydrogen in metals

    CSIR Research Space (South Africa)

    Carter, TJ


    Full Text Available The effects of hydrogen on various metals and the use of metal hydrides for hydrogen storage are discussed. The mechanisms of, and differences between, hydrogen embrittlement and hydrogen attack of ferritic steels are compared, common sources...

  14. Hot Fuel Examination Facility (HFEF) (United States)

    Federal Laboratory Consortium — The Hot Fuel Examination Facility (HFEF) is one of the largest hot cells dedicated to radioactive materials research at Idaho National Laboratory (INL). The nation's...

  15. Measurement of the Rate of Muon Capture in Hydrogen Gas and Determination of the Proton's Pseudoscalar Coupling $g_P$

    CERN Document Server

    Andreev, V A; Case, T A; Chitwood, D B; Clayton, S M; Crowe, K M; Deutsch, J; Egger, J; Freedman, S J; Ganzha, V A; Gorringe, T; Gray, F E; Hertzog, D W; Hildebrandt, M; Kammel, P; Kiburg, B; Knaack, S; Kravtsov, P A; Krivshich, A G; Lauss, B; Lynch, K L; Maev, E M; Maev, O E; Mulhauser, F; Özben, C S; Petitjean, C; Petrov, G E; Prieels, R; Schapkin, G N; Semenchuk, G G; Soroka, M A; Tishchenko, V; Vasilyev, A A; Vorobyov, A A; Vznuzdaev, M E; Winter, P


    The rate of nuclear muon capture by the proton has been measured using a new experimental technique based on a time projection chamber operating in ultra-clean, deuterium-depleted hydrogen gas at 1 MPa pressure. The capture rate was obtained from the difference between the measured $\\mu^-$ disappearance rate in hydrogen and the world average for the $\\mu^+$ decay rate. The target's low gas density of 1% compared to liquid hydrogen is key to avoiding uncertainties that arise from the formation of muonic molecules. The capture rate from the hyperfine singlet ground state of the $\\mu p$ atom is measured to be $\\Lambda_S=725.0 \\pm 17.4 s^{-1}$, from which the induced pseudoscalar coupling of the nucleon, $g_P(q^2=-0.88 m_\\mu^2)=7.3 \\pm 1.1$, is extracted. This result is consistent with theoretical predictions for $g_P$ that are based on the approximate chiral symmetry of QCD.

  16. The hot chocolate effect

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, Frank S. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)


    The "hot chocolate effect" was investigated quantitatively, using water. If a tall glass cylinder is filled nearly completely with water and tapped on the bottom with a softened mallet one can detect the lowest longitudinal mode of the water column, for which the height of the water column is one quarter wavelength. If the cylinder is rapidly filled with hot tap water containing dissolved air the pitch of that mode may descend by nearly three octaves during the first few seconds as the air comes out of solution and forms bubbles. Then the pitch gradually rises as the bubbles float to the top. A simple theoretical expression for the pitch ratio is derived and compared with experiment. The agreement is good to within the ten percent accuracy of the experiments.

  17. Solar Hot Water Heater (United States)


    The solar panels pictured below, mounted on a Moscow, Idaho home, are part of a domestic hot water heating system capable of providing up to 100 percent of home or small business hot water needs. Produced by Lennox Industries Inc., Marshalltown, Iowa, the panels are commercial versions of a collector co-developed by NASA. In an effort to conserve energy, NASA has installed solar collectors at a number of its own facilities and is conducting research to develop the most efficient systems. Lewis Research Center teamed with Honeywell Inc., Minneapolis, Minnesota to develop the flat plate collector shown. Key to the collector's efficiency is black chrome coating on the plate developed for use on spacecraft solar cells, the coating prevents sun heat from "reradiating," or escaping outward. The design proved the most effective heat absorber among 23 different types of collectors evaluated in a Lewis test program. The Lennox solar domestic hot water heating system has three main components: the array of collectors, a "solar module" (blue unit pictured) and a conventional water heater. A fluid-ethylene glycol and water-is circulated through the collectors to absorb solar heat. The fluid is then piped to a double-walled jacket around a water tank within the solar module.

  18. The hydrogen; L'hydrogene

    Energy Technology Data Exchange (ETDEWEB)



    The hydrogen as an energy system represents nowadays a main challenge (in a scientific, economical and environmental point of view). The physical and chemical characteristics of hydrogen are at first given. Then, the challenges of an hydrogen economy are explained. The different possibilities of hydrogen production are described as well as the distribution systems and the different possibilities of hydrogen storage. Several fuel cells are at last presented: PEMFC, DMFC and SOFC. (O.M.)

  19. A Measurement of the Rate of Muon Capture in Hydrogen Gas andDetermination of the Proton's Induced Pseudoscalar Coupling gP

    Energy Technology Data Exchange (ETDEWEB)

    Banks, Thomas Ira [Univ. of California, Berkeley, CA (United States)


    This dissertation describes a measurement of the rate ofnuclear muon capture by the proton, performed by the MuCap Collaborationusing a new technique based on a time projection chamber operating inultraclean, deuterium-depleted hydrogen gas at room temperature and 1 MPapressure. The hydrogen target's low gas density of 1 percent compared toliquid hydrogen is key to avoiding uncertainties that arise from theformation of muonic molecules. The capture rate was obtained from thedifference between the μ- disappearance rate in hydrogen--as determinedfrom data collected in the experiment's first physics run in fall2004--and the world averagefor the μ+ decay rate. After combining theresults of my analysis with the results from another independent analysisof the 2004 data, the muon capture rate from the hyperfine singlet groundstate of the mu-p atom is found to be ΛS = 725.0 ± 17.4 1/s, fromwhich the induced pseudoscalar coupling of the nucleon, gP(q2 = -0.88m$2\\atop{μ}$)= 7.3 ± 1.1, is extracted. This result for gP is consistent withtheoretical predictions that are based on the approximate chiral symmetryof QCD.

  20. Electrochemical Hydrogen Compressor

    Energy Technology Data Exchange (ETDEWEB)

    David P. Bloomfield; Brian S. MacKenzie


    The Electrochemical Hydrogen Compressor EHC was evaluated against DOE applications for compressing hydrogen at automobile filling stations, in future hydrogen pipelines and as a commercial replacement for conventional diaphragm hydrogen compressors. It was also evaluated as a modular replacement for the compressors used in petrochemical refineries. If the EHC can be made inexpensive, reliable and long lived then it can satisfy all these applications save pipelines where the requirements for platinum catalyst exceeds the annual world production. The research performed did not completely investigate Molybdenum as a hydrogen anode or cathode, it did show that photoetched 316 stainless steel is inadequate for an EHC. It also showed that: molybdenum bipolar plates, photochemical etching processes, and Gortex Teflon seals are too costly for a commercial EHC. The use of carbon paper in combination with a perforated thin metal electrode demonstrated adequate anode support strength, but is suspect in promoting galvanic corrosion. The nature of the corrosion mechanisms are not well understood, but locally high potentials within the unit cell package are probably involved. The program produced a design with an extraordinary high cell pitch, and a very low part count. This is one of the promising aspects of the redesigned EHC. The development and successful demonstration of the hydraulic cathode is also important. The problem of corrosion resistant metal bipolar plates is vital to the development of an inexpensive, commercial PEM fuel cell. Our research suggests that there is more to the corrosion process in fuel cells and electrochemical compressors than simple, steady state, galvanic stability. It is an important area for scientific investigation. The experiments and analysis conducted lead to several recommended future research directions. First, we need a better understanding of the corrosion mechanisms involved. The diagnosis of experimental cells with titration to

  1. Calorific efficiency of bituminous coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, H.; Schappert, H.


    The calorific efficiency of coal hydrogenation was the relation between the calories contained in the desired final product, that is, gasoline and liquefied petroleum gas (L.P.G.), and the calories contained in the coal required to produce the desired final product. A table of the efficiency of the power plant was given. Calorific efficiency of hydrogen production was then discussed, with figure 1 showing the heat flow diagram; tables 1 and 2 contained data for the coke plant and the water gas plant, respectively. Calorific efficiency of hydrogenation proper was discussed, with figure 2 showing the heat flow diagram for the production of aviation gasoline, and with the corresponding energy values given in table 3. The next topic of discussion was the possibility of increasing the calorific efficiency of total hydrogenation by: introduction of Linde process, utilization of kiln residues, introduction of paste heat exchange, and recovering the waste heat from the hot letdown and products. Table 4 gave data on the hydrogenation for aviation gasoline. The efficiency of hydrogen production was 26.3% without counting possible improvements or by-products for the process. The efficiency of the hydrogenation process itself was 49.0% for production of aviation gasoline and 51.1% for production of auto gasoline. However, for combined hydrogenation and hydrogen production, the efficiencies became 27.2% and 28.9% respectively. If all of the improvements mentioned above (including hydrogen production by Linde-process decomposition of product gases) were introduced, the efficiencies would rise to about 34.6% and 36.8%, respectively. 5 diagrams, 4 tables

  2. Hot skull: Malignant or feminine

    Energy Technology Data Exchange (ETDEWEB)

    Roos, J.C.; Isslet, J.W. van; Buul, M.M.C. van; Oei, H.Y.; Rijk, P.P. van


    Diffusely increased uptake in the calvarium on bone scintigraphy (a hot skull) is often present in patients with bone metastases and metabolic diseases. Excluding these known facts the prevalence of the hot skull and its relation with malignancy and, more specifically, with breast carcinoma have been studied in 673 patients. In women, the hot skull is clearly related to malignancy and to a lesser extent to breast carcinoma. However, another remarkable feature of the hot skull is its predominance in women in general (compared to men) and, therefore, the data suggest that the hot skull can also represent a normal variant of the female skull. We conclude that the hot skull has no clinical value in screening protocols.

  3. Hot, Dry and Cloudy (United States)


    [figure removed for brevity, see original site] Click on the image for movie of Hot, Dry and Cloudy This artist's concept shows a cloudy Jupiter-like planet that orbits very close to its fiery hot star. NASA's Spitzer Space Telescope was recently used to capture spectra, or molecular fingerprints, of two 'hot Jupiter' worlds like the one depicted here. This is the first time a spectrum has ever been obtained for an exoplanet, or a planet beyond our solar system. The ground-breaking observations were made with Spitzer's spectrograph, which pries apart infrared light into its basic wavelengths, revealing the 'fingerprints' of molecules imprinted inside. Spitzer studied two planets, HD 209458b and HD 189733b, both of which were found, surprisingly, to have no water in the tops of their atmospheres. The results suggest that the hot planets are socked in with dry, high clouds, which are obscuring water that lies underneath. In addition, HD209458b showed hints of silicates, suggesting that the high clouds on that planet contain very fine sand-like particles. Capturing the spectra from the two hot-Jupiter planets was no easy feat. The planets cannot be distinguished from their stars and instead appear to telescopes as single blurs of light. One way to get around this is through what is known as the secondary eclipse technique. In this method, changes in the total light from a so-called transiting planet system are measured as a planet is eclipsed by its star, vanishing from our Earthly point of view. The dip in observed light can then be attributed to the planet alone. This technique, first used by Spitzer in 2005 to directly detect the light from an exoplanet, currently only works at infrared wavelengths, where the differences in brightness between the planet and star are less, and the planet's light is easier to pick out. For example, if the experiment had been done in visible light, the total light from the system would appear to be unchanged, even as the planet

  4. Measurement of dissolved hydrogen in Al alloys and calculation of hydrogen removal efficiency of a degassing system


    *N. Akhtar; S. Javed; 1W. Akhtar


    In this paper we reported the diminution pattern of hydrogen contents in molten aluminium alloys during casting on industrial scale, and estimated the efficiency of inline rotary degassing system. The degassing parameters were tried to set constant in nearly 150 heats, so that other factors which govern the degassing efficiency of inline unit could be in-sighted well. In this study we used Leco RHEN-602 hydrogen determinator based on the principle of hot extraction carrier gas method, for the...

  5. TRUEX hot demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Chamberlain, D.B.; Leonard, R.A.; Hoh, J.C.; Gay, E.C.; Kalina, D.G.; Vandegrift, G.F.


    In FY 1987, a program was initiated to demonstrate technology for recovering transuranic (TRU) elements from defense wastes. This hot demonstration was to be carried out with solution from the dissolution of irradiated fuels. This recovery would be accomplished with both PUREX and TRUEX solvent extraction processes. Work planned for this program included preparation of a shielded-cell facility for the receipt and storage of spent fuel from commercial power reactors, dissolution of this fuel, operation of a PUREX process to produce specific feeds for the TRUEX process, operation of a TRUEX process to remove residual actinide elements from PUREX process raffinates, and processing and disposal of waste and product streams. This report documents the work completed in planning and starting up this program. It is meant to serve as a guide for anyone planning similar demonstrations of TRUEX or other solvent extraction processing in a shielded-cell facility.

  6. Software Simulation of Hot Tearing

    DEFF Research Database (Denmark)

    Andersen, S.; Hansen, P.N.; Hattel, Jesper Henri


    . With this additional information, the criteria can, for the first time, be used to their full potential.The purpose of this paper is to first give an introduction to a stress/strain simulation procedure that can be used in any foundry. Then, some results how to predict the hot cracking tendency in a casting are shown......The brittleness of a solidifying alloy in a temperature range near the solidus temperature has been recognised since the fifties as the mechanism responsible for hot tearing. Due to this brittlenes, the metal will crack under even small amounts of strain in that temperature range. We see these hot...... the solidification rate and the strain rate of the hot tear prone areas. But, until recently it was only possible to simulate the solidification rate, so that the criteria could not be used effectively.Today, with new software developments, it is possible to also simulate the strain rate in the hot tear prone areas...

  7. Hydrogen Annealing Of Single-Crystal Superalloys (United States)

    Smialek, James L.; Schaeffer, John C.; Murphy, Wendy


    Annealing at temperature equal to or greater than 2,200 degrees F in atmosphere of hydrogen found to increase ability of single-crystal superalloys to resist oxidation when subsequently exposed to oxidizing atmospheres at temperatures almost as high. Supperalloys in question are principal constituents of hot-stage airfoils (blades) in aircraft and ground-based turbine engines; also used in other high-temperature applications like chemical-processing plants, coal-gasification plants, petrochemical refineries, and boilers. Hydrogen anneal provides resistance to oxidation without decreasing fatigue strength and without need for coating or reactive sulfur-gettering constituents. In comparison with coating, hydrogen annealing costs less. Benefits extend to stainless steels, nickel/chromium, and nickel-base alloys, subject to same scale-adhesion and oxidation-resistance considerations, except that scale is chromia instead of alumina.

  8. Structural evolution of a Ta-filament during hot-wire chemical vapour deposition of Silicon investigated by electron backscatter diffraction

    CSIR Research Space (South Africa)

    Oliphant, CJ


    Full Text Available In this study we investigate the structural changes of a burnt-out tantalum filament that was operated at typical hydrogenated nanocrystalline silicon synthesis conditions in our hot-wire chemical vapour deposition chamber. Scanning electron...

  9. A hydrogen ice cube

    NARCIS (Netherlands)

    Peters, C.J.; Schoonman, J.; Schrauwers, A.


    Hydrogen is considered to be a highly promising energy carrier. Nonetheless, before hydrogen can become the fuel of choice for the future a number of slight problems will have to be overcome. For example, how can hydrogen be safely stored? Motor vehicles running on hydrogen may be clean in concept

  10. Product selectivity in plasmonic photocatalysis for carbon dioxide hydrogenation

    National Research Council Canada - National Science Library

    Zhang, Xiao; Li, Xueqian; Zhang, Du; Su, Neil Qiang; Yang, Weitao; Everitt, Henry O; Liu, Jie


    ... and selectively producing a desired but kinetically unfavourable product for the important carbon dioxide hydrogenation reaction. Methane is almost exclusively produced when rhodium nanoparticles are mildly illuminated as hot electrons are injected into the anti-bonding orbital of a critical intermediate, while carbon monoxide and methane are equally produce...

  11. Modeling of 1-D Nanowires and analyzing their Hydrogen and ...

    Indian Academy of Sciences (India)


    24–27%) and electrostatic interaction (ca. 17–24%). Keywords. B–B multiple bond; hydrogen storage; noble gas binding; HOMO-LUMO energy gap. 1. Introduction. In recent time, the finding of multiple bonds between boron atoms is a hot topic of research.1 3 A well-known concept in chemistry assigns the bond order of X-Y.

  12. Neptune's 'Hot' South Pole (United States)


    These thermal images show a 'hot' south pole on the planet Neptune. These warmer temperatures provide an avenue for methane to escape out of the deep atmosphere. The images were obtained with the Very Large Telescope in Chile, using an imager/spectrometer for mid-infrared wavelengths on Sept. 1 and 2, 2006. The telescope is operated by the European Organization for Astronomical Research in the Southern Hemisphere (known as ESO). Scientists say Neptune's south pole is 'hotter' than anywhere else on the planet by about 10 degrees Celsius (50 degrees Fahrenheit). The average temperature on Neptune is about minus 200 degrees Celsius (minus 392 degrees Fahrenheit). The upper left image samples temperatures near the top of Neptune's troposphere (near 100 millibar pressure, which is one-tenth the Earth atmospheric pressure at sea level). The hottest temperatures are indicated at the lower part of the image, at Neptune's south pole (see the graphic at the upper right). The lower two images, taken 6.3 hours apart, sample temperatures at higher altitudes in Neptune's stratosphere. They do show generally warmer temperatures near, but not at, the south pole. They also show a distinct warm area which can be seen in the lower left image and rotated completely around the back of the planet and returned to the earth-facing hemisphere in the lower right image.

  13. Solutions for Hot Situations (United States)


    From the company that brought the world an integral heating and cooling food service system after originally developing it for NASA's Apollo Program, comes yet another orbital offshoot: a product that can be as thin as paper and as strong as steel. Nextel Ceramic Textiles and Composites from 3M Company offer space-age protection and innovative solutions for hot situations, ranging from NASA to NASCAR. With superior thermal protection, Nextel fabrics, tape, and sleevings outperform other high temperature textiles such as aramids, carbon, glass, and quartz, permitting engineers and manufacturers to handle applications up to 2,500 F (1,371 C). The stiffness and strength of Nextel Continuous Ceramic Fibers make them a great match for improving the rigidity of aluminum in metal matrix composites. Moreover, the fibers demonstrate low shrinkage at operating temperatures, which allow for the manufacturing of a dimensionally stable product. These novel fibers also offer excellent chemical resistance, low thermal conductivity, thermal shock resistance, low porosity, and unique electrical properties.

  14. Enhancing the hydrogen bond between the bridged hydrogen atom of diborane and ammonia. (United States)

    Gao, Lei; Zhang, Xueying; Meng, Lingpeng; Zeng, Yanli


    The character of the bridged hydrogen atom (Hb) of B2H6 has become a hot issue in recent years. In this work, the complexes B2H6 · · · NH3, B2H2X4 · · · nNH3 (n = 1, 2) and 2HF · · · B2H2X4 · · · 2NH3 (X = Cl, Br, I) were constructed and studied based on the M06-2X calculations to investigate how to enhance the Hb · · · N hydrogen-bonded interaction. When the terminal hydrogen atoms (Ht) of B2H6 were replaced by X (X = Cl, Br, I) atoms, the Hb · · · N hydrogen bond were strengthened. According to the electrostatic potentials in B2H2X4, two HF molecules were added to the interspace of the B-H-B-H four-membered ring of the B2H2X4 · · · 2NH3 complexes, and H · · · X hydrogen bond formed, resulting in further enhancing effect of Hb · · · N hydrogen bond. As a result, the positive cooperative effect of Hb · · · N hydrogen bond and H · · · X hydrogen bond do enhance the interactions of each other. The two measures not only enhance the strength of Hb · · · N hydrogen bond, but also achieve the goal to make the Hb · · · N hydrogen bond perpendicular to B · · · B direction.

  15. Hot-wire assisted ALD of tungsten films: In-situ study of the interplay between CVD, etching, and ALD modes

    NARCIS (Netherlands)

    Yang, Mengdi; Aarnink, Antonius A.I.; Kovalgin, Alexeij Y.; Wolters, Robertus A.M.; Schmitz, Jurriaan


    In this work, we investigated an approach of hot-wire assisted ALD (HWALD), utilizing a hot (up to 2000 8C) tungsten (W) wire. Tungsten films were deposited by this method using alternating pulses of WF6 gas and atomic hydrogen (at-H). The latter was generated by catalytic dissociation of molecular

  16. Optoelectronic properties of hot-wire silicon layers deposited at 100 °C

    NARCIS (Netherlands)

    Brinza, M.|info:eu-repo/dai/nl/304823325; van der Werf, C.H.M.; Rath, J.K.|info:eu-repo/dai/nl/304830585; Schropp, R.E.I.|info:eu-repo/dai/nl/072502584


    Hot-wire chemical vapor deposition is employed for the deposition of amorphous and microcrystalline silicon layers at substrate temperature kept below 100 °C with the aid of active cooling of the substrate holder. The hydrogen dilution is varied in order to investigate films at the

  17. Hot semiworks Redox studies

    Energy Technology Data Exchange (ETDEWEB)

    Evans, T.F.; Tomlinson, R.E.


    The separations Hot Semiworks at the Hanford Atomic Products Operation was built in order to: (1) develop optimum conditions for the economic operation of the Redox and TBP plants, (2) procure engineering design data which would allow the specification of process equipment required for new processes such as Purex, (3) provide facilities for the study of future process and engineering problems on a semiworks scale employing radioactive process solutions, and (4) provide facilities for immediate trouble shooting for urgent separations plant problems. The initial operation of this facility was designed to develop conditions for the economic operation of the Redox Plant. These studies, covering a period from November, 1952 to October, 1953, are described in this report. The Redox process is used at Hanford for the separation of uranium and plutonium from fission products and from each other. The basis of the process is the preferential extraction of uranium and plutonium nitrates from an aqueous phase of high salting strength into an organic solvent (methyl isobutyl ketone) to effect the separation from fission products. This operation is conducted continuously in columns, packed with Raschig rings, through which the phases are passed counter-currently. Uranium and plutonium are separated by converting the plutonium to a lower valence state, in which form it is preferentially extracted back into an aqueous phase of high salting strength in a second column. Uranium is then returned to an aqueous phase of low salting strength in a third column. The products are further decontaminated in similar additional cycles. A detailed description of the process is given in the Redox Technical Manual.

  18. The decay of hot nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Moretto, L.G.; Wozniak, G.J.


    The formation of hot compound nuclei in intermediate-energy heavy ion reactions is discussed. The statistical decay of such compound nuclei is responsible for the abundant emission of complex fragments and high energy gamma rays. 43 refs., 23 figs.

  19. Do scientists trace hot topics?

    CERN Document Server

    Wei, Tian; Wu, Chensheng; Yan, XiaoYong; Fan, Ying; Di, Zengru; Wu, Jinshan


    Do scientists follow hot topics in their scientific investigations? In this paper, by performing analysis to papers published in the American Physical Society (APS) Physical Review journals, it is found that papers are more likely to be attracted by hot fields, where the hotness of a field is measured by the number of papers belonging to the field. This indicates that scientists generally do follow hot topics. However, there are qualitative differences among scientists from various countries, among research works regarding different number of authors, different number of affiliations and different number of references. These observations could be valuable for policy makers when deciding research funding and also for individual researchers when searching for scientific projects.

  20. Why hydrogen; Pourquoi l'hydrogene?

    Energy Technology Data Exchange (ETDEWEB)



    The energy consumption increase and the associated environmental risks, led to develop new energy sources. The authors present the potentialities of the hydrogen in this context of energy supply safety. They detail the today market and the perspectives, the energy sources for the hydrogen production (fossils, nuclear and renewable), the hydrogen transport, storage, distribution and conversion, the application domains, the associated risks. (A.L.B.)

  1. Hydrogen nanobubble at normal hydrogen electrode (United States)

    Nakabayashi, S.; Shinozaki, R.; Senda, Y.; Yoshikawa, H. Y.


    Electrochemically formed hydrogen nanobubbles at a platinum rotating disk electrode (RDE) were detected by re-oxidation charge. The dissolution time course of the hydrogen nanobubbles was measured by AFM tapping topography under open-circuit conditions at stationary platinum and gold single-crystal electrodes. The bubble dissolution at platinum was much faster than that at gold because two types of diffusion, bulk and surface diffusion, proceeded at the platinum surface, whereas surface diffusion was prohibited at the gold electrode. These findings indicated that the electrochemical reaction of normal hydrogen electrode partly proceeded heterogeneously on the three-phase boundary around the hydrogen nanobubble.

  2. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others


    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  3. Coolant-side heat-transfer rates for a hydrogen-oxygen rocket and a new technique for data correlation (United States)

    Schacht, R. L.; Quentmeyer, R. J.


    An experimental investigation was conducted to determine the coolant-side, heat transfer coefficients for a liquid cooled, hydrogen-oxygen rocket thrust chamber. Heat transfer rates were determined from measurements of local hot gas wall temperature, local coolant temperature, and local coolant pressure. A correlation incorporating an integration technique for the transport properties needed near the pseudocritical temperature of liquid hydrogen gives a satisfactory prediction of hot gas wall temperatures.

  4. Neptune's Wandering Hot Pole (United States)

    Orton, Glenn; Fletcher, Leigh; Yanamandra-Fisher, Padma; Geballe, Tom; Hammel, Heidi; Fujiyoshi, Takuya; Encrenaz, Therese; Hofstadter, Mark; Mousis, Olivier; Fuse, Tetsuharu


    Images of stratospheric emission from Neptune obtained in 2006 at ESO's Very Large Telescope (Orton et al., 2007, A&A 473, L5) revealed a near-polar hot spot near 70 deg. S latitude that was detectable in different filters sampling both methane (~7-micron) and ethane (~12-micron) emission from Neptune's stratosphere. Such a feature was not present in 2003 Keck and 2005 Gemini North observations: these showed only a general warming trend towards Neptune's pole that was longitudinally homogeneous. Because of the paucity of longitudinal sampling in the 2003, 2005 and 2006 images, it was not clear whether the failure to see this phenomenon in 2003 and 2005 was simply the result of insufficient longitudinal sampling or whether the phenomenon was truly variable in time. To unravel these two possibilities, we proposed for time on large telescopes that were capable of resolving Neptune at these wavelengths. We were granted time at Gemini South in 2007 using T-Recs, Subaru time in 2008 using the COMICS instrument and VLT time in 2008 and 2009 using VISIR. Two serendipitous T-Recs images of Neptune were also obtained in 2007 using a broad-band N (8-14 micron) filter, whose radiance is dominated by 12-micron ethane emission, and whose primary purpose was navigation of N-band spectroscopy. The feature was re-observed (i) in 2007 in the T-Recs N-band filter and (ii) in 2008 with COMICS in a 12.5-micron image. Unfortunately, none of the telescope time granted was sufficient to sample all longitudes over the 12-hour period of this latitude, and so no definitive separation of the two possibilities was obtained. However, considering the ensemble of images as a random sample of longitudes, it is likely that the phenomenon is ephemeral in time, as it was observed only twice among 9 independent observing epochs. We will continue to request observations to sample all longitudes systematically, but our current sample argues that the phenomenon is truly ephemera, because we most likely

  5. Hydrogen in semiconductors

    CERN Document Server

    Pankove, Jacques I


    Hydrogen plays an important role in silicon technology, having a profound effect on a wide range of properties. Thus, the study of hydrogen in semiconductors has received much attention from an interdisciplinary assortment of researchers. This sixteen-chapter volume provides a comprehensive review of the field, including a discussion of hydrogenation methods, the use of hydrogen to passivate defects, the use of hydrogen to neutralize deep levels, shallow acceptors and shallow donors in silicon, vibrational spectroscopy, and hydrogen-induced defects in silicon. In addition to this detailed cove

  6. Simulated Photoevaporative Mass Loss from Hot Jupiters in 3D (United States)

    Tripathi, Anjali; Kratter, Kaitlin M.; Murray-Clay, Ruth A.; Krumholz, Mark R.


    Ionizing stellar photons heat the upper regions of planetary atmospheres, driving atmospheric mass loss. Gas escaping from several hot, hydrogen-rich planets has been detected using UV and X-ray transmission spectroscopy. Because these planets are tidally locked, and thus asymmetrically irradiated, escaping gas is unlikely to be spherically symmetric. In this paper, we focus on the effects of asymmetric heating on local outflow structure. We use the Athena code for hydrodynamics to produce 3D simulations of hot Jupiter mass loss that jointly model wind launching and stellar heating via photoionization. Our fiducial planet is an inflated, hot Jupiter with radius {R}{{p}}=2.14{R}{Jup} and mass {M}{{p}}=0.53{M}{Jup}. We irradiate the initially neutral, atomic hydrogen atmosphere with 13.6 eV photons and compute the outflow’s ionization structure. There are clear asymmetries in the atmospheric outflow, including a neutral shadow on the planet’s nightside. Given an incident ionizing UV flux comparable to that of the Sun, we find a steady-state mass loss rate of ˜ 2× {10}10 g s-1. The total mass loss rate and the outflow substructure along the substellar ray show good agreement with earlier 1D models, for two different fluxes. Our 3D data cube can be used to generate the outflow’s extinction spectrum during transit. As a proof of concept, we find absorption of stellar Lyα at Doppler-shifted velocities of up to ±50 km s-1. Our work provides a starting point for further 3D models that can be used to predict observable signatures of hot Jupiter mass loss.

  7. 29 CFR 1915.14 - Hot work. (United States)


    ... 29 Labor 7 2010-07-01 2010-07-01 false Hot work. 1915.14 Section 1915.14 Labor Regulations... Dangerous Atmospheres in Shipyard Employment § 1915.14 Hot work. (a) Hot work requiring testing by a Marine Chemist or Coast Guard authorized person. (1) The employer shall ensure that hot work is not performed in...

  8. Solid-phase microextraction may catalize hydrogenation when using hydrogen as carrier in gas chromatography. (United States)

    Fiorini, D; Boarelli, M C


    When hydrogen is used as carrier gas, carbon-carbon double bonds may be hydrogenated in the hot gas chromatograph (GC) injector if introduced by solid-phase microextraction (SPME). SPME fibers coated with polydimethylsiloxane (PDMS)/carboxen/divinylbenzene (DVB), PDMS/carboxen, polyacrylate, PDMS/DVB and PDMS on fused silica, stableflex or metal alloy core have been tested with fatty acid methyl esters (FAMEs) from olive oil. Using coatings containing DVB, hydrogenation took place with high conversion rates (82.0-92.9%) independently of the core material. With all fibers having a metal core, hydrogenation was observed to a certain extent (27.4-85.3%). PDMS, PDMS/carboxen and polyacrylate coated fibers with a fused silica or stableflex core resulted in negligible hydrogenation (0.2-2.5%). The occurrence of hydrogenation was confirmed also with other substances containing carbon-carbon double bonds (n-alkenes, alkenoic acids, mono- and polyunsaturated fatty acid methyl and ethyl esters). Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Handbook of hydrogen energy

    CERN Document Server

    Sherif, SA; Stefanakos, EK; Steinfeld, Aldo


    ""This book provides an excellent overview of the hydrogen economy and a thorough and comprehensive presentation of hydrogen production and storage methods.""-Scott E. Grasman, Rochester Institute of Technology, New York, USA

  10. Center for Hydrogen Storage. (United States)


    The main goals of this project were to (1) Establish a Center for Hydrogen Storage Research at Delaware State University for the preparation and characterization of selected complex metal hydrides and the determination their suitability for hydrogen ...

  11. Hydrogen production by Cyanobacteria

    Directory of Open Access Journals (Sweden)

    Chaudhuri Surabhi


    Full Text Available Abstract The limited fossil fuel prompts the prospecting of various unconventional energy sources to take over the traditional fossil fuel energy source. In this respect the use of hydrogen gas is an attractive alternate source. Attributed by its numerous advantages including those of environmentally clean, efficiency and renew ability, hydrogen gas is considered to be one of the most desired alternate. Cyanobacteria are highly promising microorganism for hydrogen production. In comparison to the traditional ways of hydrogen production (chemical, photoelectrical, Cyanobacterial hydrogen production is commercially viable. This review highlights the basic biology of cynobacterial hydrogen production, strains involved, large-scale hydrogen production and its future prospects. While integrating the existing knowledge and technology, much future improvement and progress is to be done before hydrogen is accepted as a commercial primary energy source.

  12. Hydrogen transport membranes (United States)

    Mundschau, Michael V.


    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  13. Solar hydrogen generator (United States)

    Sebacher, D. I.; Sabol, A. P. (Inventor)


    An apparatus, using solar energy to manufacture hydrogen by dissociating water molecules into hydrogen and oxygen molecules is described. Solar energy is concentrated on a globe containing water thereby heating the water to its dissociation temperature. The globe is pervious to hydrogen molecules permitting them to pass through the globe while being essentially impervious to oxygen molecules. The hydrogen molecules are collected after passing through the globe and the oxygen molecules are removed from the globe.

  14. Hydrogen Technologies Safety Guide

    Energy Technology Data Exchange (ETDEWEB)

    Rivkin, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Burgess, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Buttner, W. [National Renewable Energy Lab. (NREL), Golden, CO (United States)


    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  15. Magnesium for Hydrogen Storage

    DEFF Research Database (Denmark)

    Vigeholm, B.; Kjøller, John; Larsen, Bent


    The reaction of hydrogen with commercially pure magnesium powder (above 99.7%) was investigated in the temperature range 250–400 °C. Hydrogen is readily sorbed above the dissociation pressure. During the initial exposure the magnesium powder sorbs hydrogen slowly below 400 °C but during the second...

  16. Biological hydrogen photoproduction

    Energy Technology Data Exchange (ETDEWEB)

    Nemoto, Y. [Univ. of Miami, FL (United States)


    Following are the major accomplishments of the 6th year`s study of biological hydrogen photoproduction which were supported by DOE/NREL. (1) We have been characterizing a biological hydrogen production system using synchronously growing aerobically nitrogen-fixing unicellular cyanobacterium, Synechococcus sp. Miami BG 043511. So far it was necessary to irradiate the cells to produce hydrogen. Under darkness they did not produce hydrogen. However, we found that, if the cells are incubated with oxygen, they produce hydrogen under the dark. Under 80% argon + 20% oxygen condition, the hydrogen production activity under the dark was about one third of that under the light + argon condition. (2) Also it was necessary so far to incubate the cells under argon atmosphere to produce hydrogen in this system. Argon treatment is very expensive and should be avoided in an actual hydrogen production system. We found that, if the cells are incubated at a high cell density and in a container with minimum headspace, it is not necessary to use argon for the hydrogen production. (3) Calcium ion was found to play an important role in the mechanisms of protection of nitrogenase from external oxygen. This will be a clue to understand the reason why the hydrogen production is so resistant to oxygen in this strain. (4) In this strain, sulfide can be used as electron donor for the hydrogen production. This result shows that waste water can be used for the hydrogen production system using this strain.

  17. Measurement of muon transfer from proton to triton and {ital pp}{mu} molecular formation in solid hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Mulhauser, F.; Beveridge, J.L.; Marshall, G.M. [TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia, V6T 2A3 (CANADA); Bailey, J.M. [Chester Technology, Chester (England); Beer, G.A.; Knowles, P.E.; Mason, G.R.; Olin, A. [University of Victoria, Victoria, British Columbia, V8W 2Y2 (CANADA); Fujiwara, M.C. [University of British Columbia, Vancouver, British Columbia, V6T 2A6 (CANADA); Huber, T.M. [Gustavus Adolphus College, St. Peter, Minnesota 56082 (United States); Jacot-Guillarmod, R. [Institut de Physique, Universite de Fribourg, CH-1700 Fribourg (Switzerland); Kammel, P.; Zmeskal, J. [Austrian Academy of Sciences, A-1090 Vienna (Austria); Kim, S.K. [Jeonbuk National University, Jeonju City 560-756, South (Korea); Kunselman, A.R. [University of Wyoming, Laramie, Wyoming 82071 (United States); Markushin, V.E. [Russian Research Center, Kurchatov Institute, Moscow 123182 (Russia); Martoff, C.J. [Temple University, Philadelphia, Pennsylvania 19122 (United States); Petitjean, C. [Paul Scherrer Institute, PSI, CH-5232 Villigen (Switzerland)


    An alternate approach was used to study the reactions of muonic atoms and molecules in solid layers of hydrogen isotopes. Muons stopped in a protium layer with a small admixture of tritium producing {mu}{ital p} atoms. Muon transfer from a proton to a triton generated {mu}{ital t} atoms, which were emitted into a deuterium layer. Subsequent epithermal {ital dt}{mu} molecular formation followed by {ital dt} fusion gave a prompt signal for the {mu}{ital t} emission. Fusion time spectra at various tritium concentrations were measured by detecting neutrons and {alpha} particles and the {mu}{ital p} disappearance rates were determined. The rates of {mu}{ital p}{r_arrow}{mu}{ital t} transfer and {ital pp}{mu} formation were measured to be {lambda}{sub {ital pt}}=[5.86{plus_minus}(0.10){sub {ital stat}}{plus_minus}(0.15){sub {ital syst}}({sub {minus}0}{sup +0.30}){sub {ital model}}]{times}10{sup 9} s{sup {minus}1} and {lambda}{sub {ital pp}}{sub {mu}}=[3.21 {plus_minus}(0.10){sub {ital stat}}{plus_minus}(0.14){sub {ital syst}}({sub {minus}0.06}{sup +0}){sub {ital model}(}]{times}10{sup 6} s{sup {minus}1}, respectively. Comparisons are made with the most recent theoretical values. {copyright} {ital 1996 The American Physical Society.}

  18. Promethus Hot Leg Piping Concept

    Energy Technology Data Exchange (ETDEWEB)

    AM Girbik; PA Dilorenzo


    The Naval Reactors Prime Contractor Team (NRPCT) recommended the development of a gas cooled reactor directly coupled to a Brayton energy conversion system as the Space Nuclear Power Plant (SNPP) for NASA's Project Prometheus. The section of piping between the reactor outlet and turbine inlet, designated as the hot leg piping, required unique design features to allow the use of a nickel superalloy rather than a refractory metal as the pressure boundary. The NRPCT evaluated a variety of hot leg piping concepts for performance relative to SNPP system parameters, manufacturability, material considerations, and comparison to past high temperature gas reactor (HTGR) practice. Manufacturability challenges and the impact of pressure drop and turbine entrance temperature reduction on cycle efficiency were discriminators between the piping concepts. This paper summarizes the NRPCT hot leg piping evaluation, presents the concept recommended, and summarizes developmental issues for the recommended concept.

  19. Hydrogen separation process (United States)

    Mundschau, Michael [Longmont, CO; Xie, Xiaobing [Foster City, CA; Evenson, IV, Carl; Grimmer, Paul [Longmont, CO; Wright, Harold [Longmont, CO


    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  20. Advantages and Limitations of Solid Layer Experiments in Muon Catalyzed Fusion

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, G. M., E-mail: [TRIUMF (Canada); Adamczak, A. [Institute of Nuclear Physics (Poland); Bailey, J. M. [Chester Technology (United Kingdom); Beveridge, J. L. [TRIUMF (Canada); Beer, G. A. [University of Victoria, Physics and Astronomy (Canada); Brewer, J. H. [University of British Columbia, Physics and Astronomy (Canada); Bystritsky, V. M. [Joint Institute for Nuclear Research (Russian Federation); Faifman, M. P. [Russian Research Center ' , Kurchatov Institute' (Russian Federation); Forster, B. M.; Fujiwara, M. C. [University of British Columbia, Physics and Astronomy (Canada); Huber, T. M. [Gustavus Adolphus College, Physics (United States); Jacot-Guillarmod, R. [University of Fribourg, Physics Department (Switzerland); Kammel, P. [Lawrence Berkeley National Laboratory (United States); Kendall, K. R. [TRIUMF (Canada); Kherani, N. P. [Ontario Hydro (Canada); Kim, S. K. [Jeonbuk National University (Korea, Republic of); Knowles, P. E. [University of Victoria, Physics and Astronomy (Canada); Kunselman, A. R. [Jeonbuk National University (Korea, Republic of); Maier, M. [University of Victoria, Physics and Astronomy (Canada); Markushin, V. E. [Paul Scherrer Institute (Switzerland)


    Since the discovery that muonic deuterium at energies near a few eV could travel distances of the order of 1 mm in condensed hydrogen, and in particular that muonic tritium and muonic deuterium could emerge from the surface of a solid hydrogen layer, the advantages of solid targets have enabled the study of several processes important in muon catalyzed fusion. A review of the results is presented, emphasizing the strengths and limitations of the use of solid hydrogen layer targets.

  1. Safe venting of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, W.F.; Dewart, J.M.; Edeskuty, F.J.


    The disposal of hydrogen is often required in the operation of an experimental facility that contains hydrogen. Whether the vented hydrogen can be discharged to the atmosphere safely depends upon a number of factors such as the flow rate and atmospheric conditions. Calculations have been made that predict the distance a combustible mixture can extend from the point of release under some specified atmospheric conditions. Also the quantity of hydrogen in the combustible cloud is estimated. These results can be helpful in deciding of the hydrogen can be released directly to the atmosphere, or if it must be intentionally ignited. 15 refs., 5 figs., 2 tabs.

  2. Hot conditioning equipment conceptual design report

    Energy Technology Data Exchange (ETDEWEB)

    Bradshaw, F.W., Westinghouse Hanford


    This report documents the conceptual design of the Hot Conditioning System Equipment. The Hot conditioning System will consist of two separate designs: the Hot Conditioning System Equipment; and the Hot Conditioning System Annex. The Hot Conditioning System Equipment Design includes the equipment such as ovens, vacuum pumps, inert gas delivery systems, etc.necessary to condition spent nuclear fuel currently in storage in the K Basins of the Hanford Site. The Hot Conditioning System Annex consists of the facility of house the Hot Conditioning System. The Hot Conditioning System will be housed in an annex to the Canister Storage Building. The Hot Conditioning System will consist of pits in the floor which contain ovens in which the spent nuclear will be conditioned prior to interim storage.

  3. Sustainable Energy - Without the hot air (United States)

    MacIsaac, Dan


    Reader John Roeder writes about a website associated with David MacKay's book Sustainable Energy-Without the hot air. The book is a freely downloadable PDF (or purchasable) book describing an analysis detailing a low-carbon renewable energy transformation route for a large, modern first world industrial country (the United Kingdom). Written for the layman, the work uses vernacular language, e.g., energy consumption and production in a series of bar charts detailing the impacts of necessary strategies such as population reduction, lifestyle changes, and technology changes. MacKay notes that most reasonable plans have large nuclear and ``clean coal'' or other carbon capture components, lots of pumped heat, wind, and much efficiency improvement. He debunks some sacred cows (roof-mounted micro-turbines; hydrogen-powered cars) while pointing out simple effective technologies such as roof-mounted solar water heaters. Similar modest changes in the U.S. (painting roofs white in the southern half of the country) have strong impacts. MacKay claims that he ``doesn't advocate any particular plan or technology,'' but ``tells you how many bricks are in the lego box, and how big each brick is'' so readers can start making planning decisions.

  4. Hydrogen energy for beginners

    CERN Document Server


    This book highlights the outstanding role of hydrogen in energy processes, where it is the most functional element due to its unique peculiarities that are highlighted and emphasized in the book. The first half of the book covers the great natural hydrogen processes in biology, chemistry, and physics, showing that hydrogen is a trend that can unite all natural sciences. The second half of the book is devoted to the technological hydrogen processes that are under research and development with the aim to create the infrastructure for hydrogen energetics. The book describes the main features of hydrogen that make it inalienable player in processes such as fusion, photosynthesis, and metabolism. It also covers the methods of hydrogen production and storage, highlighting at the same time the exclusive importance of nanotechnologies in those processes.

  5. Cyclooctanaminium hydrogen succinate monohydrate

    Directory of Open Access Journals (Sweden)

    Sanaz Khorasani


    Full Text Available In the title hydrated salt, C8H18N+·C4H5O4−·H2O, the cyclooctyl ring of the cation is disordered over two positions in a 0.833 (3:0.167 (3 ratio. The structure contains various O—H.·O and N—H...O interactions, forming a hydrogen-bonded layer of molecules perpendicular to the c axis. In each layer, the ammonium cation hydrogen bonds to two hydrogen succinate anions and one water molecule. Each hydrogen succinate anion hydrogen bonds to neighbouring anions, forming a chain of molecules along the b axis. In addition, each hydrogen succinate anion hydrogen bonds to two water molecules and the ammonium cation.

  6. Hydrogen storage methods (United States)

    Züttel, Andreas

    Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of today's energy consumption. First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water and hydrocarbons. This implies that we have to pay for the energy, which results in a difficult economic dilemma because ever since the industrial revolution we have become used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is its low critical temperature of 33 K (i.e. hydrogen is a gas at ambient temperature). For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage material is crucial. Hydrogen can be stored using six different methods and phenomena: (1) high-pressure gas cylinders (up to 800 bar), (2) liquid hydrogen in cryogenic tanks (at 21 K), (3) adsorbed hydrogen on materials with a large specific surface area (at Tchemically bonded in covalent and ionic compounds (at ambient pressure), or (6) through oxidation of reactive metals, e.g. Li, Na, Mg, Al, Zn with water. The most common storage systems are high-pressure gas cylinders with a maximum pressure of 20 MPa (200 bar). New lightweight composite cylinders have been developed which are able to withstand pressures up to 80 MPa (800 bar) and therefore the hydrogen gas can reach a volumetric density of 36 kg.m-3, approximately half as much as in its liquid state. Liquid hydrogen is stored in cryogenic tanks at 21.2 K and ambient pressure. Due to the low critical temperature of hydrogen (33 K), liquid hydrogen can only be stored in open systems. The volumetric density of liquid hydrogen is 70.8 kg.m-3, and large volumes, where the thermal losses are small, can cause hydrogen to reach a

  7. Dynamics of hydrogen in hydrogenated amorphous silicon

    Indian Academy of Sciences (India)

    bonding configuration due to hydrogen migration have been proposed as a mechanism of defect generation in a-Si:H [6,7]. Thus hydrogen plays a dual role in a-Si:H: (1) acting as a .... the sphere of radius R0 and allows to express. ∆F as a function of localization radius R0. Using eqs (10) and (11), the volume integration.

  8. Hot-spots in tapwaterleidingen

    NARCIS (Netherlands)

    Wolferen, J. van; Sluis, S.M. van der


    ln opdracht van de VNI is een aantal berekeningen uitgevoerd voor het vaststellen van aanvullende richtlijnen in verband met hot-spots in tapwaterleidingen. Hierbij is deels voortgebouwd op berekeningen die reeds eerder in opdracht van Novem zijn uitgevoerd t.b.v. ISSO publicatie 55.1, Handleiding

  9. Hot Corrosion in Gas Turbines. (United States)


    in hot corrosion under some circumstances, because its role seems to be principally through reduction of NagSO, or erosion by pyrolytic graphite...same morphology could be produced either by spray -coating with NaxSO, or by diffusing NIS into the cut- edge region under argon at temperature and then

  10. Detection of Hot Halo Gets Theory Out of Hot Water (United States)


    Scientists using NASA's Chandra X-ray Observatory have detected an extensive halo of hot gas around a quiescent spiral galaxy. This discovery is evidence that galaxies like our Milky Way are still accumulating matter from the gradual inflow of intergalactic gas. "What we are likely witnessing here is the ongoing galaxy formation process," said Kristian Pedersen of the University of Copenhagen, Denmark, and lead author of a report on the discovery. Chandra observations show that the hot halo extends more than 60,000 light years on either side of the disk of the galaxy known as NGC 5746. The detection of such a large halo alleviates a long-standing problem for the theory of galaxy formation. Spiral galaxies are thought to form from enormous clouds of intergalactic gas that collapse to form giant, spinning disks of stars and gas. Chandra X-ray Image of NGC 5746 Chandra X-ray Image of NGC 5746 One prediction of this theory is that large spiral galaxies should be immersed in halos of hot gas left over from the galaxy formation process. Hot gas has been detected around spiral galaxies in which vigorous star formation is ejecting matter from the galaxy, but until now hot halos due to infall of intergalactic matter have not been detected. "Our observations solve the mystery of the missing hot halos around spiral galaxies," said Pedersen. "The halos exist, but are so faint that an extremely sensitive telescope such as Chandra is needed to detect them." DSS Optical Image of NGC 5746 DSS Optical Image of NGC 5746 NGC 5746 is a massive spiral galaxy about a 100 million light years from Earth. Its disk of stars and gas is viewed almost edge-on. The galaxy shows no signs of unusual star formation, or energetic activity from its nuclear region, making it unlikely that the hot halo is produced by gas flowing out of the galaxy. "We targeted NGC 5746 because we thought its distance and orientation would give us the best chance to detect a hot halo caused by the infall of

  11. Hydrogen Filling Station

    Energy Technology Data Exchange (ETDEWEB)

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian


    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen

  12. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies


    In this progress report (covering the period May 1997--May 1998), the authors summarize results from ongoing technical and economic assessments of hydrogen energy systems. Generally, the goal of their research is to illuminate possible pathways leading from present hydrogen markets and technologies toward wide scale use of hydrogen as an energy carrier, highlighting important technologies for RD and D. Over the past year they worked on three projects. From May 1997--November 1997, the authors completed an assessment of hydrogen as a fuel for fuel cell vehicles, as compared to methanol and gasoline. Two other studies were begun in November 1997 and are scheduled for completion in September 1998. The authors are carrying out an assessment of potential supplies and demands for hydrogen energy in the New York City/New Jersey area. The goal of this study is to provide useful data and suggest possible implementation strategies for the New York City/ New Jersey area, as the Hydrogen Program plans demonstrations of hydrogen vehicles and refueling infrastructure. The authors are assessing the implications of CO{sub 2} sequestration for hydrogen energy systems. The goals of this work are (a) to understand the implications of CO{sub 2} sequestration for hydrogen energy system design; (b) to understand the conditions under which CO{sub 2} sequestration might become economically viable; and (c) to understand design issues for future low-CO{sub 2} emitting hydrogen energy systems based on fossil fuels.

  13. Pulsational instabilities in hot pre-horizontal branch stars (United States)

    Battich, Tiara; Miller Bertolami, Marcelo M.; Córsico, Alejandro H.; Althaus, Leandro G.


    The ɛ mechanism is a self-excitation mechanism of pulsations which acts on the regions where nuclear burning takes place. It has been shown that the ɛ mechanism can excite pulsations in models of hot helium-core flash, and that the pulsations of LS IV-14· 116, a He-enriched hot subdwarf star, could be explained that way. We aim to study the ɛmechanism effects on models of hot pre-horizontal branch stars and determine, if possible, a domain of instability in the log g — log Teff plane. We compute non-adiabatic non-radial pulsations on such stellar models, adopting different values of initial chemical abundances and mass of the hydrogen envelope at the time of the main helium flash. We find an instability domain of long-period (400 s ≲ P ≲ 2500 s) g-modes for models with 22000K ≲ Teff ≲ 50000K and 4.67 ≲ log g ≲ 6.15.

  14. Non-LTE line-blanketed model atmospheres of hot stars. 2: Hot, metal-rich white dwarfs (United States)

    Lanz, T.; Hubeny, I.


    We present several model atmospheres for a typical hot metal-rich DA white dwarf, T(sub eff) = 60,000 K, log g = 7.5. We consider pure hydrogen models, as well as models with various abundances of two typical 'trace' elements-carbon and iron. We calculte a number of Local Thermodynamic Equilibrium (LTE) and non-LTE models, taking into account the effect of numerous lines of these elements on the atmospheric structure. We demostrate that while the non-LTE effects are notvery significant for pure hydrogen models, except for describing correctly the central emission in H-alpha they are essential for predicting correctly the ionization balance of metals, such as carbon and iron. Previously reported discrepancies in LTE abundances determinations using C III and C IV lines are easily explained by non-LTE effects. We show that if the iron abundance is larger than 10(exp -5), the iron line opacity has to be considered not only for the spectrum synthesis, but also in the model construction itself. For such metal abundances, non-LTE metal line-blanketed models are needed for detailed abundance studies of hot, metal-rich white dwarfs. We also discuss the predicted Extreme Ultraviolet (EUV) spectrum and show that it is very sensitive to metal abundances, as well as to non-LTE effects.

  15. Constraint on parity-violating muonic forces. (United States)

    Barger, Vernon; Chiang, Cheng-Wei; Keung, Wai-Yee; Marfatia, Danny


    Using the nonobservance of missing mass events in the leptonic kaon decay K→μX, we place a strong constraint on exotic parity-violating gauge interactions of the right-handed muon. By way of illustration, we apply it to an explanation of the proton size anomaly that invokes such a new force; scenarios in which the gauge boson decays invisibly or is long lived are constrained.

  16. Allylammonium hydrogen oxalate hemihydrate

    Directory of Open Access Journals (Sweden)

    Błażej Dziuk


    Full Text Available In the title hydrated molecular salt, C3H8N+·C2HO4−·0.5H2O, the water O atom lies on a crystallographic twofold axis. The C=C—C—N torsion angle in the cation is 2.8 (3° and the dihedral angle between the CO2 and CO2H planes in the anion is 1.0 (4°. In the crystal, the hydrogen oxalate ions are linked by O—H...O hydrogen bonds, generating [010] chains. The allylammonium cations bond to the chains through N—H...O and N—H...(O,O hydrogen bonds. The water molecule accepts two N—H...O hydrogen bonds and makes two O—H...O hydrogen bonds. Together, the hydrogen bonds generate (100 sheets.

  17. Hydrogen Fuelling Stations

    DEFF Research Database (Denmark)

    Rothuizen, Erasmus Damgaard

    This thesis concerns hydrogen fuelling stations from an overall system perspective. The study investigates thermodynamics and energy consumption of hydrogen fuelling stations for fuelling vehicles for personal transportation. For the study a library concerning the components in a hydrogen fuelling...... station has been developed in Dymola. The models include the fuelling protocol (J2601) for hydrogen vehicles made by Society of Automotive Engineers (SAE) and the thermodynamic property library CoolProp is used for retrieving state point. The components in the hydrogen fuelling library are building up....... A system consisting of one high pressure storage tank is used to investigate the thermodynamics of fuelling a hydrogen vehicle. The results show that the decisive parameter for how the fuelling proceeds is the pressure loss in the vehicle. The single tank fuelling system is compared to a cascade fuelling...

  18. OUT Success Stories: Solar Hot Water Technology

    Energy Technology Data Exchange (ETDEWEB)

    Clyne, R.


    Solar hot water technology was made great strides in the past two decades. Every home, commercial building, and industrial facility requires hot water. DOE has helped to develop reliable and durable solar hot water systems. For industrial applications, the growth potential lies in large-scale systems, using flat-plate and trough-type collectors. Flat-plate collectors are commonly used in residential hot water systems and can be integrated into the architectural design of the building.

  19. OUT Success Stories: Solar Hot Water Technology (United States)

    Clyne, R.


    Solar hot water technology was made great strides in the past two decades. Every home, commercial building, and industrial facility requires hot water. DOE has helped to develop reliable and durable solar hot water systems. For industrial applications, the growth potential lies in large-scale systems, using flat-plate and trough-type collectors. Flat-plate collectors are commonly used in residential hot water systems and can be integrated into the architectural design of the building.

  20. Iron losses during desulphurisation of hot metal


    Magnelöv, Marianne


    After injection of calcium carbide and magnesium during desulphurisation of hot metal, the slag is normally solid and contains large amounts of iron. Besides the enclosed iron droplets in the slag, drawn-off hot metal during slag skimming also accounts for iron losses during desulphurisation of hot metal. Iron losses during hot metal desulphurisation using both calcium carbide (mono-injection), and calcium carbide and magnesium (co-injection), have been studied by large-scale investigations o...

  1. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Steinbugler, M.; Dennis, E. [Princeton Univ., NJ (United States)] [and others


    For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

  2. Pathways to Metallic Hydrogen


    Silvera, Isaac F.; Deemyad, Shanti


    The traditional pathway that researchers have used in the goal of producing atomic metallic hydrogen is to compress samples with megabar pressures at low temperature. A number of phases have been observed in solid hydrogen and its isotopes, but all are in the insulating phase. The results of experiment and theory for this pathway are reviewed. In recent years a new pathway has become the focus of this challenge of producing metallic hydrogen, namely a path along the melting line. It has bee...

  3. Hydrogen rich gas generator (United States)

    Houseman, J. (Inventor)


    A process and apparatus is described for producing a hydrogen rich gas by introducing a liquid hydrocarbon fuel in the form of a spray into a partial oxidation region and mixing with a mixture of steam and air that is preheated by indirect heat exchange with the formed hydrogen rich gas, igniting the hydrocarbon fuel spray mixed with the preheated mixture of steam and air within the partial oxidation region to form a hydrogen rich gas.

  4. Hydrogen Fuel Cell Vehicles


    Delucchi, Mark


    Hydrogen is an especially attractive transportation fuel. It is the least polluting fuel available, and can be produced anywhere there is water and a clean source of electricity. A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewably grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional, or global pollution. Hydrogen FCEVs would combine the best features of bat...

  5. Liquid hydrogen in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Yasumi, S. [Iwatani Corp., Osaka (Japan). Dept. of Overseas Business Development


    Japan's Iwatani Corporation has focused its attention on hydrogen as the ultimate energy source in future. Unlike the United States, hydrogen use and delivery in liquid form is extremely limited in the European Union and in Japan. Iwatani Corporation broke through industry stereotypes by creating and building Hydro Edge Co. Ltd., Japan's largest liquid hydrogen plant. It was established in 2006 as a joint venture between Iwatani and Kansai Electric Power Group in Osaka. Hydro Edge is Japan's first combined liquid hydrogen and ASU plant, and is fully operational. Liquid oxygen, liquid nitrogen and liquid argon are separated from air using the cryogenic energy of liquefied natural gas fuel that is used for power generation. Liquid hydrogen is produced efficiently and simultaneously using liquid nitrogen. Approximately 12 times as much hydrogen in liquid form can be transported and supplied as pressurized hydrogen gas. This technology is a significant step forward in the dissemination and expansion of hydrogen in a hydrogen-based economy.

  6. Enhancing hydrogen spillover and storage (United States)

    Yang, Ralph T [Ann Arbor, MI; Li, Yingwel [Ann Arbor, MI; Lachawiec, Jr., Anthony J.


    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  7. Enhancing hydrogen spillover and storage (United States)

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J


    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.


    Energy Technology Data Exchange (ETDEWEB)

    E.S. Connolly; G.D. Forsythe


    Advanced, coal-based power plants will require durable and reliable hot gas filtration systems to remove particulate contaminants from the gas streams to protect downstream components such as turbine blades from erosion damage. It is expected that the filter elements in these systems will have to be made of ceramic materials to withstand goal service temperatures of 1600 F or higher. Recent demonstration projects and pilot plant tests have indicated that the current generation of ceramic hot gas filters (cross-flow and candle configurations) are failing prematurely. Two of the most promising materials that have been extensively evaluated are clay-bonded silicon carbide and alumina-mullite porous monoliths. These candidates, however, have been found to suffer progressive thermal shock fatigue damage, as a result of rapid cooling/heating cycles. Such temperature changes occur when the hot filters are back-pulsed with cooler gas to clean them, or in process upset conditions, where even larger gas temperature changes may occur quickly and unpredictably. In addition, the clay-bonded silicon carbide materials are susceptible to chemical attack of the glassy binder phase that holds the SiC particles together, resulting in softening, strength loss, creep, and eventual failure.

  9. Thermal stability of the optical band gap and structural order in hot-wire-deposited amorphous silicon

    CSIR Research Space (South Africa)

    Arendse, CJ


    Full Text Available The material properties of hydrogenated amorphous silicon (a-Si:H) have been known to change when exposed to elevated temperatures. In this work researchers report on the thermal stability of the optical band gap and structural disorder in hot...

  10. A case of familial hot tub lung

    Directory of Open Access Journals (Sweden)

    Yoshihiro Kitahara


    Full Text Available Hot tub lung is a lung disease caused by Mycobacterium avium complex. We report the first case of familial hot tub lung appearing simultaneously in a husband and wife. Our case supports the consideration that hot tub lung is a hypersensitivity pneumonitis rather than an infectious lung disease. It also suggests that the state of hot tub lung changes seasonally depending on temperature variations, in a manner similar to summer-type hypersensitivity pneumonitis. This case demonstrates similarities between hot tub lung and summer-type hypersensitivity pneumonitis in regards to familial occurrence and seasonal changes in the disease state.

  11. Possibility of hydrogen supply by shared residential fuel cell systems for fuel cell vehicles

    Directory of Open Access Journals (Sweden)

    Ono Yusuke


    Full Text Available Residential polymer electrolyte fuel cells cogeneration systems (residential PEFC systems produce hydrogen from city gas by internal gas-reformer, and generate electricity, the hot water at the same time. From the viewpoint of the operation, it is known that residential PEFC systems do not continuously work but stop for long time, because the systems generate enough hot water for short operation time. In other words, currently residential PEFC systems are dominated by the amount of hot water demand. This study focuses on the idle time of residential PEFC systems. Since their gas-reformers are free, the systems have potential to produce hydrogen during the partial load operations. The authors expect that residential PEFC systems can take a role to supply hydrogen for fuel cell vehicles (FCVs before hydrogen fueling stations are distributed enough. From this perspective, the objective of this study is to evaluate the hydrogen production potential of residential PEFC systems. A residential PEFC system was modeled by the mixed integer linear programming to optimize the operation including hydrogen supply for FCV. The objective function represents annual system cost to be minimized with the constraints of energy balance. It should be noted that the partial load characteristics of the gas-reformer and the fuel cell stack are taken into account to derive the optimal operation. The model was employed to estimate the possible amount of hydrogen supply by a residential PEFC system. The results indicated that the system could satisfy at least hydrogen demand for transportation of 8000 km which is as far as the average annual mileage of a passenger car in Japan. Furthermore, hydrogen production by sharing a residential PEFC system with two households is more effective to reduce primary energy consumption with hydrogen supply for FCV than the case of introducing PEFC in each household.

  12. Hydrogen Storage Tank

    CERN Multimedia


    This huge stainless steel reservoir,placed near an end of the East Hall, was part of the safety equipment connected to the 2 Metre liquid hydrogen Bubble Chamber. It could store all the hydrogen in case of an emergency. The picture shows the start of its demolition.

  13. Metastable ultracondensed hydrogenous materials (United States)

    Nellis, W. J.


    The primary purpose of this paper is to stimulate theoretical predictions of how to retain metastably hydrogenous materials made at high pressure P on release to ambient. Ultracondensed metallic hydrogen has been made at high pressures in the fluid and reported made probably in the solid. Because the long quest for metallic hydrogen is likely to be concluded in the relatively near future, a logical question is whether another research direction, comparable in scale to the quest for metallic H, will arise in high pressure research. One possibility is retention of metastable solid metallic hydrogen and other hydrogenous materials on release of dynamic and static high pressures P to ambient. If hydrogenous materials could be retained metastably on release, those materials would be a new class of materials for scientific investigations and technological applications. This paper is a review of the current situation with the synthesis of metallic hydrogen, potential technological applications of metastable metallic H and other hydrogenous materials at ambient, and general background of published experimental and theoretical work on what has been accomplished with metastable phases in the past and thus what might be accomplished in the future.

  14. Hydrogen evolution reaction catalyst (United States)

    Subbaraman, Ram; Stamenkovic, Vojislav; Markovic, Nenad; Tripkovic, Dusan


    Systems and methods for a hydrogen evolution reaction catalyst are provided. Electrode material includes a plurality of clusters. The electrode exhibits bifunctionality with respect to the hydrogen evolution reaction. The electrode with clusters exhibits improved performance with respect to the intrinsic material of the electrode absent the clusters.

  15. Electrochemical Hydrogen Compressor

    Energy Technology Data Exchange (ETDEWEB)

    Lipp, Ludwig [FuelCell Energy, Inc., Torrington, CT (United States)


    Conventional compressors have not been able to meet DOE targets for hydrogen refueling stations. They suffer from high capital cost, poor reliability and pose a risk of fuel contamination from lubricant oils. This project has significantly advanced the development of solid state hydrogen compressor technology for multiple applications. The project has achieved all of its major objectives. It has demonstrated capability of Electrochemical Hydrogen Compression (EHC) technology to potentially meet the DOE targets for small compressors for refueling sites. It has quantified EHC cell performance and durability, including single stage hydrogen compression from near-atmospheric pressure to 12,800 psi and operation of EHC for more than 22,000 hours. Capital cost of EHC was reduced by 60%, enabling a path to meeting the DOE cost targets for hydrogen compression, storage and delivery ($2.00-2.15/gge by 2020).

  16. Chlorific efficiency of coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Schappert, H.


    In studies on the calorific efficiency of coal hydrogenation, the efficiency for H/sub 2/ production was calculated to be 26%, the efficiency for hydrogenation was calculated to be 49%, and the efficiency of hydrogenation including H/sub 2/ production was 27.2%. The efficiency of hydrogenation plus hydrogen production was almost equal to the efficiency of hydrogen production alone, even though this was not expected because of the total energy calculated in the efficiency of hydrogenation proper. It was entirely possible, but did not affect computations, that the efficiency of one or the other components of hydrogenation process differed somewhat from 49%. The average efficiency for all cases was 49%. However, when hydrogen was not bought, but was produced--(efficiency of hydrogen production was 26%, not 100%-- then the total energy changed and the efficiency of hydrogen production and combination was not 26%, but 13%. This lower value explained the drop of hydrogenation efficiency to 27.2%.

  17. From supernovae to galaxy clusters: observing the chemical enrichment in the hot intra-cluster medium


    Mernier, F.D.M.


    Whereas the extreme conditions of the first minutes after the Big Bang have produced nearly all the hydrogen and helium in the Universe, heavier elements - or metals - are synthesised in the core of stars and in supernova explosions. Currently, however, the behaviour of supernovae (and their stellar progenitors) is not well understood, and could be better constrained by measuring accurately the relative amount of metals they produce. On the other hand, the very hot and diffuse gas - or intra-...

  18. The hydrogen highway

    Energy Technology Data Exchange (ETDEWEB)

    Grigg, A. [Fuel Cells Canada, Vancouver, British Columbia (Canada)


    'Full text:' The Hydrogen Highway in British Columbia, Canada, is a coordinated, large-scale demonstration and deployment program aimed at accelerating the commercialization of hydrogen and fuel cell technologies and products. It will be a showcase for fuel cell vehicles, refuelling stations and stationary power systems leading up to the 2010 Olympic and Paralympic Winter Games in Whistler, BC. The Hydrogen Highway is designed to help address many of the challenges to commercialization identified in the Canadian Fuel Cell Commercialization Roadmap. The project will create an early adopter network of hydrogen and fuel cell microenvironments where technology developers and users can learn about the technical, economic, environmental and social impacts of products. The Hydrogen Highway will give the public and potential purchasers an opportunity to feel, touch and see the new technology, as well as provide the industry with a venue in which to develop industry standards and supply chains of materials and components. While demonstration and deployment programs are a recognized and necessary component in the process to commercialize hydrogen and fuel cell technologies, there is no handbook describing how it should be done. This paper will describe the history, objectives, project details and some of the challenges associated with establishing Canada's Hydrogen Highway. (author)

  19. Photoelectrochemical hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Rocheleau, R.; Misra, A.; Miller, E. [Univ. of Hawaii, Honolulu, HI (United States)


    A significant component of the US DOE Hydrogen Program is the development of a practical technology for the direct production of hydrogen using a renewable source of energy. High efficiency photoelectrochemical systems to produce hydrogen directly from water using sunlight as the energy source represent one of the technologies identified by DOE to meet this mission. Reactor modeling and experiments conducted at UH provide strong evidence that direct solar-to-hydrogen conversion efficiency greater than 10% can be expected using photoelectrodes fabricated from low-cost, multijunction (MJ) amorphous silicon solar cells. Solar-to-hydrogen conversion efficiencies as high as 7.8% have been achieved using a 10.3% efficient MJ amorphous silicon solar cell. Higher efficiency can be expected with the use of higher efficiency solar cells, further improvement of the thin film oxidation and reduction catalysts, and optimization of the solar cell for hydrogen production rather than electricity production. Hydrogen and oxygen catalysts developed under this project are very stable, exhibiting no measurable degradation in KOH after over 13,000 hours of operation. Additional research is needed to fully optimize the transparent, conducting coatings which will be needed for large area integrated arrays. To date, the best protection has been afforded by wide bandgap amorphous silicon carbide films.

  20. Economics of Hot Water Dipping


    P., Maxin; K., Klopp


    Hot water dipping is an appropriate method to protect apples against spoilage caused by gloeosporium rot. Tests on the varieties Topaz and Ingrid Marie at the OVB Jork (Germany) have demonstrated an effective reduction of spoilage from between 80% and 92% in charges by an infection rate of 40%. The result of an intensive R&D process between 2002 and 2003 is the development of a praxis-tested big box (300 kg) dipping station. With the first Bio Dipping systems now on the mark...

  1. Hot moons and cool stars

    Directory of Open Access Journals (Sweden)

    Heller René


    Full Text Available The exquisite photometric precision of the Kepler space telescope now puts the detection of extrasolar moons at the horizon. Here, we firstly review observational and analytical techniques that have recently been proposed to find exomoons. Secondly, we discuss the prospects of characterizing potentially habitable extrasolar satellites. With moons being much more numerous than planets in the solar system and with most exoplanets found in the stellar habitable zone being gas giants, habitable moons could be as abundant as habitable planets. However, satellites orbiting planets in the habitable zones of cool stars will encounter strong tidal heating and likely appear as hot moons.

  2. Hot Flow Anomalies at Venus (United States)

    Collinson, G. A.; Sibeck, David Gary; Boardsen, Scott A.; Moore, Tom; Barabash, S.; Masters, A.; Shane, N.; Slavin, J.A.; Coates, A.J.; Zhang, T. L.; hide


    We present a multi-instrument study of a hot flow anomaly (HFA) observed by the Venus Express spacecraft in the Venusian foreshock, on 22 March 2008, incorporating both Venus Express Magnetometer and Analyzer of Space Plasmas and Energetic Atoms (ASPERA) plasma observations. Centered on an interplanetary magnetic field discontinuity with inward convective motional electric fields on both sides, with a decreased core field strength, ion observations consistent with a flow deflection, and bounded by compressive heated edges, the properties of this event are consistent with those of HFAs observed at other planets within the solar system.

  3. POLI: Polarised hot neutron diffractometer

    Directory of Open Access Journals (Sweden)

    Vladimir Hutanu


    Full Text Available POLI, which is operated by the Institute of Crystallography, RWTH Aachen University in cooperation with JCNS, Forschungszentrum Jülich, is a versatile two axes single crystal diffractometer with broad field of applications. Mostly dedicated to the investigation of magnetic structures in single crystals using neutron spin polarisation, POLI is also used for classical structural investigations under extreme conditions. High intensity hot neutrons flux makes it attractive also for the other applications like study of parity violations phenomena in nuclear physics or BNCT (boron neutron-capture therapy in medicine.

  4. Hydrogen generation from low-temperature water-rock reactions (United States)

    Mayhew, L. E.; Ellison, E. T.; McCollom, T. M.; Trainor, T. P.; Templeton, A. S.


    Hydrogen is commonly produced during the high-temperature hydration of mafic and ultramafic rocks, owing to the oxidation of reduced iron present in the minerals. Hydrothermal hydrogen is known to sustain microbial communities in submarine vent and terrestrial hot-spring systems. However, the rates and mechanisms of hydrogen generation below temperatures of 150°C are poorly constrained. As such, the existence and extent of hydrogen-fuelled ecosystems in subsurface terrestrial and oceanic aquifers has remained uncertain. Here, we report results from laboratory experiments in which we reacted ground ultramafic and mafic rocks and minerals--specifically peridotite, pyroxene, olivine and magnetite--with anoxic fluids at 55 and 100°C, and monitored hydrogen gas production. We used synchrotron-based micro-X-ray fluorescence and X-ray absorption near-edge structure spectroscopy to identify changes in the speciation of iron in the materials. We report a strong correlation between molecular hydrogen generation and the presence of spinel phases--oxide minerals with the general formula [M2+M23+]O4 and a cubic crystal structure--in the reactants. We also identify Fe(III)-(hydr)oxide reaction products localized on the surface of the spinel phases, indicative of iron oxidation. We propose that the transfer of electrons between Fe(II) and water adsorbed to the spinel surfaces promotes molecular hydrogen generation at low temperatures. We suggest that these localized sites of hydrogen generation in ultramafic aquifers in the oceanic and terrestrial crust could support hydrogen-based microbial life.

  5. A green hydrogen economy

    Energy Technology Data Exchange (ETDEWEB)

    Clark, W.W. II [Clark Communications, Beverly Hills, CA (United States). Green Hydrogen Scientific Advisory Committee; Rifkin, J. [The Foundation on Economic Trends (United States)


    This paper is the result of over a dozen scholars and practitioners who strongly felt that a hydrogen economy and hence the future is closer than some American politicians and bureaucrats state. Moreover, when seen internationally, there is strong evidence, the most recent and obvious ones are the proliferation of hybrid vehicles, that for any nation-state to be energy independent it must seek a renewable or green hydrogen future in the near term. The State of California has once again taken the lead in this effort for both an energy-independent future and one linked strongly to the hydrogen economy. Then why a hydrogen economy in the first instance? The fact is that hydrogen most likely will not be used for refueling of vehicles in the near term. The number of vehicles to make hydrogen commercially viable will not be in the mass market by almost all estimates until 2010. However, it is less than a decade away. The time frame is NOT 30-40 years as some argue. The hydrogen economy needs trained people, new ventures and public-private partnerships now. The paper points out how the concerns of today, including higher costs and technologies under development, can be turned into opportunities for both the public and private sectors. It was not too long ago that the size of a mobile phone was that of a briefcase, and then almost 10 years ago, the size of a shoe box. Today, they are not only the size of a man's wallet but also often given away free to consumers who subscribe or contract for wireless services. While hydrogen may not follow this technological commercialization exactly, it certainly will be on a parallel path. International events and local or regional security dictate that the time for a hydrogen must be close at hand. (author)

  6. High-temperature biotrickling filtration of hydrogen sulphide. (United States)

    Datta, Indrani; Fulthorpe, Roberta R; Sharma, Shobha; Allen, D Grant


    Biofiltration of malodorous reduced sulphur compounds such as hydrogen sulphide has been confined to emissions that are at temperatures below 40 degrees C despite the fact that there are many industrial emissions (e.g. in the pulp and paper industry) at temperatures well above 40 degrees C. This paper describes our study on the successful treatment of hydrogen sulphide gas at temperatures of 40, 50, 60 and 70 degrees C using a microbial community obtained from a hot spring. Three biotrickling filter (BTF) systems were set up in parallel for a continuous run of 9 months to operate at three different temperatures, one of which was always at 40 degrees C as a mesophilic control and the other two were for exploring high-temperature operation up to 70 degrees C. The continuous experiment and a series of batch experiments in glass bottles (250 ml) showed that addition of glucose and monosodium glutamate enhanced thermophilic biofiltration of hydrogen sulphide gas and a removal rate of 40 g m(-3) h(-1) was achieved at 70 degrees C. We suggest that the glucose is acting as a carbon source for the existing microbial community in the BTFs, whereas glutamate is acting as a compatible solute. The use of such organic compounds to enhance biodegradation of hydrogen sulphide, particularly at high temperatures, has not been demonstrated to our knowledge and, hence, has opened up a range of possibilities for applying biofiltration to hot gas effluent.

  7. Photobiological hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Seibert, M; Lien, S; Weaver, P F


    Hydrogen production by phototrophic organisms, which has been known since the 1930's, occurs at the expense of light energy and electron-donating substrates. Three classes of organisms, namely, photosynthetic bacteria, cyanobacteria, and algae carry out this function. The primary hydrogen-producing enzyme systems, hydrogenase and nitrogenase, will be discussed along with the manner in which they couple to light-driven electron transport. In addition, the feasibility of using in vivo and in vitro photobiological hydrogen producing systems in future solar energy conversion applications will be examined.

  8. Photobiological hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Seibert, M.; Lien, S.; Weaver, P.F.


    Hydrogen production by phototrophic organisms, which has been known since the 1930's, occurs at the expense of light energy and electron-donating substrates. Three classes of organisms, namely, photosynthetic bacteria, cyanobacteria, and algae carry out this function. The primary hydrogen-producing enzyme systems, hydrogenase and nitrogenase, will be discussed along with the manner in which they couple to light-driven electron transport. In addition, the feasibility of using in vivo and in vitro photobiological hydrogen producing systems in future solar energy conversion applications will be examined.

  9. Biological hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Benemann, J.R. [Univ. of California, Berkeley, CA (United States)


    Biological hydrogen production can be accomplished by either thermochemical (gasification) conversion of woody biomass and agricultural residues or by microbiological processes that yield hydrogen gas from organic wastes or water. Biomass gasification is a well established technology; however, the synthesis gas produced, a mixture of CO and H{sub 2}, requires a shift reaction to convert the CO to H{sub 2}. Microbiological processes can carry out this reaction more efficiently than conventional catalysts, and may be more appropriate for the relatively small-scale of biomass gasification processes. Development of a microbial shift reaction may be a near-term practical application of microbial hydrogen production.

  10. Chromatographic hydrogen isotope separation (United States)

    Aldridge, Frederick T.


    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  11. Color Changing Hydrogen Sensors (United States)

    Roberson, Luke B.; Williams, Martha; Captain, Janine E.; Mohajeri, Nahid; Raissi, Ali


    During the Space Shuttle Program, one of the most hazardous operation that occurred was the loading of liquid hydrogen (LH2) during fueling operations of the spacecraft. Due to hydrogen's low explosive limit, any amount leaked could lead to catastrophic event. Hydrogen's chemical properties make it ideal as a rocket fuel; however, the fuel is deemed unsafe for most commercial use because of the inability to easily detect the gas leaking. The increased use of hydrogen over traditional fossil fuels would reduce greenhouse gases and America's dependency on foreign oil. Therefore a technology that would improve safety at NASA and in the commercial sector while creating a new economic sector would have a huge impact to NASA's mission. The Chemochromic Detector for sensing hydrogen gas leakage is a color-changing detector that is useful in any application where it is important to know not only the presence but also the location of the hydrogen gas leak. This technology utilizes a chemochromicpigment and polymer matrix that can be molded or spun into rigid or pliable shapes useable in variable temperature environments including atmospheres of inert gas, hydrogen gas, or mixtures of gases. A change in color of the detector material indicates where gaseous hydrogen leaks are occurring. The irreversible sensor has a dramatic color change from beige to dark grey and remains dark grey after exposure. A reversible pigment changes from white to blue in the presence of hydrogen and reverts back to white in the presence of oxygen. Both versions of the sensor's pigments were comprised of a mixture of a metal oxide substrate and a hydro-chromic compound (i.e., the compound that changed color in the presence of hydrogen) and immediately notified the operator of the presence of low levels of hydrogen. The detector can be used in a variety of formats including paint, tape, caulking, injection molded parts, textiles and fabrics, composites, and films. This technology brings numerous

  12. National hydrogen energy roadmap

    Energy Technology Data Exchange (ETDEWEB)

    None, None


    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. Based on the results of the government-industry National Hydrogen Energy Roadmap Workshop, held in Washington, DC on April 2-3, 2002, it displays the development of a roadmap for America's clean energy future and outlines the key barriers and needs to achieve the hydrogen vision goals defined in

  13. Biomimetic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Krassen, Henning


    Hydrogenases catalyze the reduction of protons to molecular hydrogen with outstanding efficiency. An electrode surface which is covered with active hydrogenase molecules becomes a promising alternative to platinum for electrochemical hydrogen production. To immobilize the hydrogenase on the electrode, the gold surface was modified by heterobifunctional molecules. A thiol headgroup on one side allowed the binding to the gold surface and the formation of a self-assembled monolayer. The other side of the molecules provided a surface with a high affinity for the hydrogenase CrHydA1 from Chlamydomonas reinhardtii. With methylviologen as a soluble energy carrier, electrons were transferred from carboxy-terminated electrodes to CrHydA1 and conducted to the active site (H-cluster), where they reduce protons to molecular hydrogen. A combined approach of surface-enhanced infrared absorption spectroscopy, gas chromatography, and surface plasmon resonance allowed quantifying the hydrogen production on a molecular level. Hydrogen was produced with a rate of 85 mol H{sub 2} min{sup -1} mol{sup -1}. On a 1'- benzyl-4,4'-bipyridinum (BBP)-terminated surface, the electrons were mediated by the monolayer and no soluble electron carrier was necessary to achieve a comparable hydrogen production rate (approximately 50% of the former system). The hydrogen evolution potential was determined to be -335 mV for the BBP-bound hydrogenase and -290 mV for the hydrogenase which was immobilized on a carboxy-terminated mercaptopropionic acid SAM. Therefore, both systems significantly reduce the hydrogen production overpotential and allow electrochemical hydrogen production at an energy level which is close to the commercially applied platinum electrodes (hydrogen evolution potential of -270 mV). In order to couple hydrogen production and photosynthesis, photosystem I (PS1) from Synechocystis PCC 6803 and membrane-bound hydrogenase (MBH) from Ralstonia eutropha were bound to each other

  14. Active control of magneto-hydrodynamic instabilities in hot plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Igochine, Valentin (ed.) [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany)


    Written and edited by leading plasma physics researchers. Provides a toolkit for scientists and engineers aiming to optimize plasma performance. Comprehensive treatment of different plasma instabilities. During the past century, world-wide energy consumption has risen dramatically, which leads to a quest for new energy sources. Fusion of hydrogen atoms in hot plasmas is an attractive approach to solve the energy problem, with abundant fuel, inherent safety and no long-lived radioactivity. However, one of the limits on plasma performance is due to the various classes of magneto-hydrodynamic instabilities that may occur. The physics and control of these instabilities in modern magnetic confinement fusion devices is the subject of this book. Written by foremost experts, the contributions will provide valuable reference and up-to-date research reviews for ''old hands'' and newcomers alike.

  15. Active control of magneto-hydrodynamic instabilities in hot plasmas

    CERN Document Server


    During the past century, world-wide energy consumption has risen dramatically, which leads to a quest for new energy sources. Fusion of hydrogen atoms in hot plasmas is an attractive approach to solve the energy problem, with abundant fuel, inherent safety and no long-lived radioactivity.  However, one of the limits on plasma performance is due to the various classes of magneto-hydrodynamic instabilities that may occur. The physics and control of these instabilities in modern magnetic confinement fusion devices is the subject of this book. Written by foremost experts, the contributions will provide valuable reference and up-to-date research reviews for "old hands" and newcomers alike.

  16. An integral equation model for warm and hot dense mixtures

    CERN Document Server

    Starrett, C E; Daligault, J; Hamel, S


    In Starrett and Saumon [Phys. Rev. E 87, 013104 (2013)] a model for the calculation of electronic and ionic structures of warm and hot dense matter was described and validated. In that model the electronic structure of one "atom" in a plasma is determined using a density functional theory based average-atom (AA) model, and the ionic structure is determined by coupling the AA model to integral equations governing the fluid structure. That model was for plasmas with one nuclear species only. Here we extend it to treat plasmas with many nuclear species, i.e. mixtures, and apply it to a carbon-hydrogen mixture relevant to inertial confinement fusion experiments. Comparison of the predicted electronic and ionic structures with orbital-free and Kohn-Sham molecular dynamics simulations reveals excellent agreement wherever chemical bonding is not significant.

  17. Hα features with hot onsets. I. Ellerman bombs (United States)

    Rutten, R. J.


    Ellerman bombs are transient brightenings of the wings of the Balmer lines that uniquely mark reconnection in the solar photosphere. They are also bright in strong Ca II and ultraviolet lines and in ultraviolet continua, but they are not visible in the optical continuum and the Na I D and Mg I b lines. These discordant visibilities invalidate all published Ellerman bomb modeling. I argue that the assumption of Saha-Boltzmann lower-level populations is informative to estimate bomb-onset opacities for these diverse diagnostics, even and especially for Hα, and employ such estimates to gauge the visibilities of Ellerman bomb onsets in all of them. They constrain Ellerman bomb formation to temperatures 10 000-20 000 K and hydrogen densities around 1015 cm-3. Similar arguments likely hold for Hα visibility in other transient phenomena with hot and dense onsets.

  18. Florida Hydrogen Initiative

    Energy Technology Data Exchange (ETDEWEB)

    Block, David L


    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety

  19. Hydrogen Recovery System Project (United States)

    National Aeronautics and Space Administration — Liquid hydrogen is used extensively by NASA to support cryogenic rocket testing. In addition, there are many commercial applications in which delivery and use of...

  20. Hydrogen Recovery System Project (United States)

    National Aeronautics and Space Administration — Rocket test operations at NASA Stennis Space Center (SSC) result in substantial quantities of hydrogen gas that is flared from the facility and helium gas that is...

  1. Photoelectrochemical hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Rocheleau, R.E.; Miller, E.; Misra, A. [Univ. of Hawaii, Honolulu, HI (United States)


    The large-scale production of hydrogen utilizing energy provided by a renewable source to split water is one of the most ambitious long-term goals of the U.S. Department of Energy`s Hydrogen Program. One promising option to meet this goal is direct photoelectrolysis in which light absorbed by semiconductor-based photoelectrodes produces electrical power internally to split water into hydrogen and oxygen. Under this program, direct solar-to-chemical conversion efficiencies as high as 7.8 % have been demonstrated using low-cost, amorphous-silicon-based photoelectrodes. Detailed loss analysis models indicate that solar-to-chemical conversion greater than 10% can be achieved with amorphous-silicon-based structures optimized for hydrogen production. In this report, the authors describe the continuing progress in the development of thin-film catalytic/protective coatings, results of outdoor testing, and efforts to develop high efficiency, stable prototype systems.

  2. Water's Hydrogen Bond Strength

    CERN Document Server

    Chaplin, Martin


    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperature...

  3. Thin film hydrogen sensor (United States)

    Lauf, R.J.; Hoffheins, B.S.; Fleming, P.H.


    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed. 6 figs.

  4. The hydrogen issue. (United States)

    Armaroli, Nicola; Balzani, Vincenzo


    Hydrogen is often proposed as the fuel of the future, but the transformation from the present fossil fuel economy to a hydrogen economy will need the solution of numerous complex scientific and technological issues, which will require several decades to be accomplished. Hydrogen is not an alternative fuel, but an energy carrier that has to be produced by using energy, starting from hydrogen-rich compounds. Production from gasoline or natural gas does not offer any advantage over the direct use of such fuels. Production from coal by gasification techniques with capture and sequestration of CO₂ could be an interim solution. Water splitting by artificial photosynthesis, photobiological methods based on algae, and high temperatures obtained by nuclear or concentrated solar power plants are promising approaches, but still far from practical applications. In the next decades, the development of the hydrogen economy will most likely rely on water electrolysis by using enormous amounts of electric power, which in its turn has to be generated. Producing electricity by burning fossil fuels, of course, cannot be a rational solution. Hydroelectric power can give but a very modest contribution. Therefore, it will be necessary to generate large amounts of electric power by nuclear energy of by renewable energies. A hydrogen economy based on nuclear electricity would imply the construction of thousands of fission reactors, thereby magnifying all the problems related to the use of nuclear energy (e.g., safe disposal of radioactive waste, nuclear proliferation, plant decommissioning, uranium shortage). In principle, wind, photovoltaic, and concentrated solar power have the potential to produce enormous amounts of electric power, but, except for wind, such technologies are too underdeveloped and expensive to tackle such a big task in a short period of time. A full development of a hydrogen economy needs also improvement in hydrogen storage, transportation and distribution

  5. Sanitary hot water; Eau chaude sanitaire

    Energy Technology Data Exchange (ETDEWEB)



    Cegibat, the information-recommendation agency of Gaz de France for building engineering professionals, has organized this conference meeting on sanitary hot water to present the solutions proposed by Gaz de France to meet its clients requirements in terms of water quality, comfort, energy conservation and respect of the environment: quantitative aspects of the hot water needs, qualitative aspects, presentation of the Dolce Vita offer for residential buildings, gas water heaters and boilers, combined solar-thermal/natural gas solutions, key-specifications of hot water distribution systems, testimony: implementation of a gas hot water reservoir and two accumulation boilers in an apartment building for young workers. (J.S.)

  6. Line Heat-Source Guarded Hot Plate (United States)

    Federal Laboratory Consortium — Description:The 1-meter guarded hot-plate apparatus measures thermal conductivity of building insulation. This facility provides for absolute measurement of thermal...

  7. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized......-limbic network with hyper-activity in limbic and ventral prefrontal regions paired with hypo-activity of dorsal prefrontal regions subserve these abnormalities. A cross-talk of 'hot' and 'cold' cognition disturbances in MDD occurs. Disturbances in 'hot cognition' may also contribute to the perpetuation...

  8. Cryogenic hydrogen release research.

    Energy Technology Data Exchange (ETDEWEB)

    LaFleur, Angela Christine [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  9. Purdue Hydrogen Systems Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng


    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up

  10. Cytosinium hydrogen selenite

    Directory of Open Access Journals (Sweden)

    Radhwane Takouachet


    Full Text Available In the crystal structure of the title salt, C4H6N3O+·HSeO3−, systematic name 6-amino-2-methylidene-2,3-dihydropyrimidin-1-ium hydrogen selenite, the hydrogenselenite anions and the cytosinium cations are linked via N—H...O, N—H...Se, O—H...O, O—H··Se and C—H...O hydrogen bonds, forming a three-dimensional framework.

  11. Ash removal by hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Rank, V.; von Hartmann, G.B.


    This method for the production of high-quality electrode coke involved the hydrogenation of coal to a filterable bitumen product. The hydrogenation and splitting processes were carried out to end at high-molecular-weight bitumens with some lighter oils produced. Variations in temperature, pressure, and throughput determined the type and amount of bitumens. Proper conditions allowed sufficient middle oil for recirculation as pasting oil as well as for increasing filterability by dilution. This partial hydrogenation could be performed without the addition of hydrogen, if hydrogen-producing aromatic compounds, such as tetraline or cresol, were used as pasting oils. For 700-atm hydrogenation, it was found that the Upper Silesian coal was the best with respect to yield, filterability, and recovery of the recycle oils. The lower pressures gave a better filterability while sacrificing yield and recycle oil. The more severe the hydrogenating conditions, the lighter the bitumens and the lower the melting point. For the range of 300 to 600 atm, it was found that filterability improved with increased temperature and decreased with a pressure gain. Larger throughputs caused relatively moderate decreases in filterability. The use of iron catalysts decreased filterability while changing gas and pasting-oil content had little effect. The optimum conditions established a pasting-oil equilibrium with the best filterability. Greater degrees of hydrogenation or splitting produced more recycle middle oils but decreased filterability, thus only the necessary paste oil was produced. By selecting proper conditions, an ashfree bituminous binder could be produced, as used in the production of the Soederberg electrode. 2 tables, 2 graphs

  12. Hydrogen Delivery Technical Team Roadmap

    Energy Technology Data Exchange (ETDEWEB)



    The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen.

  13. Hydrogen Sorption and Transport (United States)

    McNeece, C. J.; Hesse, M. A.


    Hydrogen is unique among aqueous ions, both in its importance for geochemical reactions, and in its complex transport behavior through reactive media. The structure of hydrogen reaction fronts can be analyzed in the advective limit of the transport equation. At local chemical equilibrium, sorption of hydrogen onto the media surface (sorption isotherm) controls reaction front morphology. Transport modeling thus necessitates accurate knowledge of surface chemistry. Though motivated by transport, sorption models are often parameterized against batch titration experiments. The validity of these parameterizations, in a transport setting, are seldom tested. The analytic solution to the transport equation gives an algebraic relationship between concentration velocity and equilibrium sorption behavior. In this study, we conduct a suite of column flow experiments through quartz sand. Hydrogen concentration breakthrough curves at the column outlet are used to infer the "transport sorption isotherm." These results are compared to the batch titration derived sorption isotherm. We find excellent agreement between the datasets. Our findings suggest that, for aqueous hydrogen, local chemical equilibrium is a valid assumption. With the goal of a predictive transport model, we parameterize various sorption models against this dataset. Models which incorporate electrostatic effects at the surface predict transport well. Nonelectrostatic models such as the Kd, Langmuir, and Freundlich models fail. These results are particularly compelling as nonelectrostatic models are often employed to predict hydrogen transport in many reactive transport code.

  14. Electrochemical hydrogen Storage Systems

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Digby Macdonald


    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not

  15. Examining hydrogen transitions.

    Energy Technology Data Exchange (ETDEWEB)

    Plotkin, S. E.; Energy Systems


    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  16. An infrared diagnostic for magnetism in hot stars (United States)

    Oksala, M. E.; Grunhut, J. H.; Kraus, M.; Borges Fernandes, M.; Neiner, C.; Condori, C. A. H.; Campagnolo, J. C. N.; Souza, T. B.


    Magnetospheric observational proxies are used for indirect detection of magnetic fields in hot stars in the X-ray, UV, optical, and radio wavelength ranges. To determine the viability of infrared (IR) hydrogen recombination lines as a magnetic diagnostic for these stars, we have obtained low-resolution (R~ 1200), near-IR spectra of the known magnetic B2V stars HR 5907 and HR 7355, taken with the Ohio State Infrared Imager/Spectrometer (OSIRIS) attached to the 4.1 m Southern Astrophysical Research (SOAR) Telescope. Both stars show definite variable emission features in IR hydrogen lines of the Brackett series, with similar properties as those found in optical spectra, including the derived location of the detected magnetospheric plasma. These features also have the added advantage of a lowered contribution of stellar flux at these wavelengths, making circumstellar material more easily detectable. IR diagnostics will be useful for the future study of magnetic hot stars, to detect and analyze lower-density environments, and to detect magnetic candidates in areas obscured from UV and optical observations, increasing the number of known magnetic stars to determine basic formation properties and investigate the origin of their magnetic fields. Based on observations obtained at the Southern Astrophysical Research (SOAR) telescope, which is a joint project of the Ministério da Ciência, Tecnologia, e Inovação (MCTI) da República Federativa do Brasil, the US National Optical Astronomy Observatory (NOAO), the University of North Carolina at Chapel Hill (UNC), and Michigan State University (MSU).

  17. HotSpot Wizard: a web server for identification of hot spots in protein engineering

    National Research Council Canada - National Science Library

    Pavelka, Antonin; Chovancova, Eva; Damborsky, Jiri


    HotSpot Wizard is a web server for automatic identification of 'hot spots' for engineering of substrate specificity, activity or enantioselectivity of enzymes and for annotation of protein structures...

  18. Performance of a Small Gas Generator Using Liquid Hydrogen and Liquid Oxygen (United States)

    Acker, Loren W.; Fenn, David B.; Dietrich, Marshall W.


    The performance and operating problems of a small hot-gas generator burning liquid hydrogen with liquid oxygen are presented. Two methods of ignition are discussed. Injector and combustion chamber design details based on rocket design criteria are also given. A carefully fabricated showerhead injector of simple design provided a gas generator that yielded combustion efficiencies of 93 and 96 percent.

  19. Hydrogen supplies for SPFC vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Hart, D.; Bauen, A.; Fouquet, R.; Leach, M.; Pearson, P.; Anderson, D.


    This report summarises the findings of a study investigating the potential of using hydrogen fuel for fuel cell-powered fleet vehicles based at a depot in a range of counties. An overview of current hydrogen supply and demand is presented, and research already carried out on potential hydrogen refuelling infrastructures, and the costs of producing hydrogen as a transportation fuel are examined. Hydrogen demand modelling, and supplying hydrogen to fleet vehicles, alternative hydrogen supply options, energy and emissions comparison with competing fuels, and health and safety standards are discussed.

  20. Bow Shock Leads the Way for a Speeding Hot Jupiter (United States)

    Kohler, Susanna


    As hot Jupiters whip around their host stars, their speeds can exceed the speed of sound in the surrounding material, theoretically causing a shock to form ahead of them. Now, a study has reported the detection of such a shock ahead of transiting exoplanet HD 189733b, providing a potential indicator of the remarkably strong magnetic field of the planet.Rushing PlanetsDue to their proximity to their hosts, hot Jupiters move very quickly through the stellar wind and corona surrounding the star. When this motion is supersonic, the material ahead of the planet can be compressed by a bow shock and for a transiting hot Jupiter, this shock will cross the face of the host star in advance of the planets transit.In a recent study, a team of researchers by Wilson Cauley of Wesleyan University report evidence of just such a pre-transit. The teams target is exoplanet HD 189733b, one of the closest hot Jupiters to our solar system. When the authors examined high-resolution transmission spectra of this system, they found that prior to the optical transit of the planet, there was a large dip in the transmission of the first three hydrogen Balmer lines. This could well be the absorption of an optically-thick bow shock as it moves past the face of the star.Tremendous MagnetismOperating under this assumption, the authors create a model of the absorption expected from a hot Jupiter transiting with a bow shock ahead of it. Using this model, they show that a shock leading the planet at a distance of 12.75 times the planets radius reproduces the key features of the transmission spectrum.This stand-off distance is surprisingly large. Assuming that the location of the bow shock is set by the point where the planets magnetospheric pressure balances the pressure of the stellar wind or corona that it passes through, the planetary magnetic field would have to be at least 28 Gauss. This is seven times the strength of Jupiters magnetic field!Understanding the magnetic fields of exoplanets is


    Energy Technology Data Exchange (ETDEWEB)

    E.S. Connolly; G.D. Forsythe


    DuPont Lanxide Composites, Inc. undertook a sixty-month program, under DOE Contract DEAC21-94MC31214, in order to develop hot gas candle filters from a patented material technology know as PRD-66. The goal of this program was to extend the development of this material as a filter element and fully assess the capability of this technology to meet the needs of Pressurized Fluidized Bed Combustion (PFBC) and Integrated Gasification Combined Cycle (IGCC) power generation systems at commercial scale. The principal objective of Task 3 was to build on the initial PRD-66 filter development, optimize its structure, and evaluate basic material properties relevant to the hot gas filter application. Initially, this consisted of an evaluation of an advanced filament-wound core structure that had been designed to produce an effective bulk filter underneath the barrier filter formed by the outer membrane. The basic material properties to be evaluated (as established by the DOE/METC materials working group) would include mechanical, thermal, and fracture toughness parameters for both new and used material, for the purpose of building a material database consistent with what is being done for the alternative candle filter systems. Task 3 was later expanded to include analysis of PRD-66 candle filters, which had been exposed to actual PFBC conditions, development of an improved membrane, and installation of equipment necessary for the processing of a modified composition. Task 4 would address essential technical issues involving the scale-up of PRD-66 candle filter manufacturing from prototype production to commercial scale manufacturing. The focus would be on capacity (as it affects the ability to deliver commercial order quantities), process specification (as it affects yields, quality, and costs), and manufacturing systems (e.g. QA/QC, materials handling, parts flow, and cost data acquisition). Any filters fabricated during this task would be used for product qualification tests

  2. The North Galactic Pole Rift and the Local Hot Bubble (United States)

    Snowden, S. L.; Koutroumpa, D.; Kuntz, K. D.; Lallement, R.; Puspitarini, L.


    The North Galactic Pole Rift (NGPR) is one of the few distinct neutral hydrogen clouds at high Galactic latitudes that have well-defined distances. It is located at the edge of the Local Cavity (LC) and provides an important test case for understanding the Local Hot Bubble (LHB), the presumed location for the hot diffuse plasma responsible for much of the observed 1/4 keV emission originating in the solar neighborhood. Using data from the ROSAT All- Sky Survey and the Planck reddening map, we find the path length within the LC (LHB plus Complex of Local Interstellar Clouds) to be 98 plus or minus 27 pc, in excellent agreement with the distance to the NGPR of 98 +/- 6 pc. In addition, we examine another 14 directions that are distributed over the sky where the LC wall is apparently optically thick at 1/4 keV. We find that the data in these directions are also consistent with the LHB model and a uniform emissivity plasma filling most of the LC.

  3. No hot and luminous progenitor for Tycho's supernova (United States)

    Woods, T. E.; Ghavamian, P.; Badenes, C.; Gilfanov, M.


    Type Ia supernovae have proven vital to our understanding of cosmology, both as standard candles and for their role in galactic chemical evolution; however, their origin remains uncertain. The canonical accretion model implies a hot and luminous progenitor that would ionize the surrounding gas out to a radius of 10-100 pc for 100,000 years after the explosion. Here, we report stringent upper limits on the temperature and luminosity of the progenitor of Tycho's supernova (SN 1572), determined using the remnant itself as a probe of its environment. Hot, luminous progenitors that would have produced a greater hydrogen ionization fraction than that measured at the radius of the present remnant ( 3 pc) can thus be excluded. This conclusively rules out steadily nuclear-burning white dwarfs (supersoft X-ray sources), as well as disk emission from a Chandrasekhar-mass white dwarf accreting approximately greater than 10-8 M⊙ yr-1 (recurrent novae; M⊙ is equal to one solar mass). The lack of a surrounding Strömgren sphere is consistent with the merger of a double white dwarf binary, although other more exotic scenarios may be possible.

  4. California Hydrogen Infrastructure Project

    Energy Technology Data Exchange (ETDEWEB)

    Heydorn, Edward C


    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a real-world retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation's hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling

  5. Hydrogen storage and generation system (United States)

    Dentinger, Paul M.; Crowell, Jeffrey A. W.


    A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  6. Hydrogen as an energy vector


    Valenzuela Ortega, Daniel


    Study of the use of the Hydrogen to storage big amounts of energy. In this project there will be an study about the different energies that are profitable to use them to obtain hydrogen, the study of the different technologies to obtain hydrogen (electrolysis, gasification, etc.), the study of the technologies for storage the hydrogen and the study of the different ways to obtain final energy with the hydrogen. There will be also an overall analysis of the efficiency of the process a...

  7. Hot Jupiters around young stars (United States)

    Yu, L. F.; Donati, J.-F.


    This conference paper presents the results of the MaTYSSE (Magnetic Topologies of Young Stars and the Survival of massive close-in Exoplanets) observation programme, regarding the search for giant exoplanets around weak-line T Tauri stars (wTTS), as of early 2017. The discoveries of two hot Jupiters (hJs), around V830 Tau and TAP 26, sun-like stars of respectively ˜2 Myr and ˜17 Myr, are summarized here. Both exoplanets seem to have undergone type-II migration (planet-disc interaction leading the orbit to narrow around the host) based on their low orbital eccentricity. The methods which were used are given more focus in the paper Stellar activity filtering methods for the detection of exoplanets in the present book.

  8. Hot spots of mutualistic networks. (United States)

    Gilarranz, Luis J; Sabatino, Malena; Aizen, Marcelo A; Bascompte, Jordi


    Incorporating interactions into a biogeographical framework may serve to understand how interactions and the services they provide are distributed in space. We begin by simulating the spatiotemporal dynamics of realistic mutualistic networks inhabiting spatial networks of habitat patches. We proceed by comparing the predicted patterns with the empirical results of a set of pollination networks in isolated hills of the Argentinian Pampas. We first find that one needs to sample up to five times as much area to record interactions as would be needed to sample the same proportion of species. Secondly, we find that peripheral patches have fewer interactions and harbour less nested networks - therefore potentially less resilient communities - compared to central patches. Our results highlight the important role played by the structure of dispersal routes on the spatial distribution of community patterns. This may help to understand the formation of biodiversity hot spots. © 2014 The Authors. Journal of Animal Ecology © 2014 British Ecological Society.

  9. TRUEX hot demonstration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chamberlain, D.B.; Leonard, R.A.; Hoh, J.C.; Gay, E.C.; Kalina, D.G.; Vandegrift, G.F.


    In FY 1987, a program was initiated to demonstrate technology for recovering transuranic (TRU) elements from defense wastes. This hot demonstration was to be carried out with solution from the dissolution of irradiated fuels. This recovery would be accomplished with both PUREX and TRUEX solvent extraction processes. Work planned for this program included preparation of a shielded-cell facility for the receipt and storage of spent fuel from commercial power reactors, dissolution of this fuel, operation of a PUREX process to produce specific feeds for the TRUEX process, operation of a TRUEX process to remove residual actinide elements from PUREX process raffinates, and processing and disposal of waste and product streams. This report documents the work completed in planning and starting up this program. It is meant to serve as a guide for anyone planning similar demonstrations of TRUEX or other solvent extraction processing in a shielded-cell facility.

  10. Ceramic hot-gas filter (United States)

    Connolly, Elizabeth Sokolinski; Forsythe, George Daniel; Domanski, Daniel Matthew; Chambers, Jeffrey Allen; Rajendran, Govindasamy Paramasivam


    A ceramic hot-gas candle filter having a porous support of filament-wound oxide ceramic yarn at least partially surrounded by a porous refractory oxide ceramic matrix, and a membrane layer on at least one surface thereof. The membrane layer may be on the outer surface, the inner surface, or both the outer and inner surface of the porous support. The membrane layer may be formed of an ordered arrangement of circularly wound, continuous filament oxide ceramic yarn, a ceramic filler material which is less permeable than the filament-wound support structure, or some combination of continuous filament and filler material. A particularly effective membrane layer features circularly wound filament with gaps intentionally placed between adjacent windings, and a filler material of ceramic particulates uniformly distributed throughout the gap region. The filter can withstand thermal cycling during backpulse cleaning and is resistant to chemical degradation at high temperatures.

  11. Hot Dry Rock; Geothermal Energy

    Energy Technology Data Exchange (ETDEWEB)



    The commercial utilization of geothermal energy forms the basis of the largest renewable energy industry in the world. More than 5000 Mw of electrical power are currently in production from approximately 210 plants and 10 000 Mw thermal are used in direct use processes. The majority of these systems are located in the well defined geothermal generally associated with crustal plate boundaries or hot spots. The essential requirements of high subsurface temperature with huge volumes of exploitable fluids, coupled to environmental and market factors, limit the choice of suitable sites significantly. The Hot Dry Rock (HDR) concept at any depth originally offered a dream of unlimited expansion for the geothermal industry by relaxing the location constraints by drilling deep enough to reach adequate temperatures. Now, after 20 years intensive work by international teams and expenditures of more than $250 million, it is vital to review the position of HDR in relation to the established geothermal industry. The HDR resource is merely a body of rock at elevated temperatures with insufficient fluids in place to enable the heat to be extracted without the need for injection wells. All of the major field experiments in HDR have shown that the natural fracture systems form the heat transfer surfaces and that it is these fractures that must be for geothermal systems producing from naturally fractured formations provide a basis for directing the forthcoming but, equally, they require accepting significant location constraints on HDR for the time being. This paper presents a model HDR system designed for commercial operations in the UK and uses production data from hydrothermal systems in Japan and the USA to demonstrate the reservoir performance requirements for viable operations. It is shown that these characteristics are not likely to be achieved in host rocks without stimulation processes. However, the long term goal of artificial geothermal systems developed by systematic

  12. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...

  13. Hot Blade Cuttings for the Building Industries

    DEFF Research Database (Denmark)

    Brander, David; Bærentzen, Jakob Andreas; Evgrafov, Anton


    . The project aims to reduce the amount of manual labour as well as production time by applying robots to cut expanded polystyrene (EPS) moulds for the concrete to form doubly curved surfaces. The scheme is based upon the so-called Hot Wire or Hot Blade technology where the surfaces are essentially swept out...

  14. Variational Theory of Hot Dense Matter (United States)

    Mukherjee, Abhishek


    We develop a variational theory of hot nuclear matter in neutron stars and supernovae. It can also be used to study charged, hot nuclear matter which may be produced in heavy-ion collisions. This theory is a generalization of the variational theory of cold nuclear and neutron star matter based on realistic models of nuclear forces and pair…


    We studied the effects of organic and synthetic chemical fertilizers on crop growth, yield and associated insect pests for two varieties of hot pepper, Capsicum chinense Jacquin (Solanaceae): “Scotch Bonnet” and “Caribbean Red” in north Florida. Hot peppers were grown under three treatments: poultr...

  16. Solar Energy for Space Heating & Hot Water. (United States)

    Energy Research and Development Administration, Washington, DC. Div. of Solar Energy.

    This pamphlet reviews the direct transfer of solar energy into heat, particularly for the purpose of providing space and hot water heating needs. Owners of buildings and homes are provided with a basic understanding of solar heating and hot water systems: what they are, how they perform, the energy savings possible, and the cost factors involved.…

  17. Basics of Solar Heating & Hot Water Systems. (United States)

    American Inst. of Architects, Washington, DC.

    In presenting the basics of solar heating and hot water systems, this publication is organized from the general to the specific. It begins by presenting functional and operational descriptions of solar heating and domestic hot water systems, outlining the basic concepts and terminology. This is followed by a description of solar energy utilization…

  18. Hot Tub Rash (Pseudomonas Dermatitis/Folliculitis) (United States)

    ... name=”commit” type=”submit” value=”Submit” /> Healthy Water Home Rashes Language: English (US) Español (Spanish) Recommend on ... scrubbing and cleaning? Replacement of the hot tub water filter according to manufacturer’s recommendations? Replacement of hot tub ...

  19. Hot Spot Removal System: System description

    Energy Technology Data Exchange (ETDEWEB)



    Hazardous wastes contaminated with radionuclides, chemicals, and explosives exist across the Department of Energy complex and need to be remediated due to environmental concerns. Currently, an opportunity is being developed to dramatically reduce remediation costs and to assist in the acceleration of schedules associated with these wastes by deploying a Hot Spot Removal System. Removing the hot spot from the waste site will remove risk driver(s) and enable another, more cost effective process/option/remedial alternative (i.e., capping) to be applied to the remainder of the site. The Hot Spot Removal System consists of a suite of technologies that will be utilized to locate and remove source terms. Components of the system can also be used in a variety of other cleanup activities. This Hot Spot Removal System Description document presents technologies that were considered for possible inclusion in the Hot Spot Removal System, technologies made available to the Hot Spot Removal System, industrial interest in the Hot Spot Removal System`s subsystems, the schedule required for the Hot Spot Removal System, the evaluation of the relevant technologies, and the recommendations for equipment and technologies as stated in the Plan section.

  20. The Hot Hand Belief and Framing Effects (United States)

    MacMahon, Clare; Köppen, Jörn; Raab, Markus


    Purpose: Recent evidence of the hot hand in sport--where success breeds success in a positive recency of successful shots, for instance--indicates that this pattern does not actually exist. Yet the belief persists. We used 2 studies to explore the effects of framing on the hot hand belief in sport. We looked at the effect of sport experience and…

  1. Hot-dry-rock feasibility study

    Energy Technology Data Exchange (ETDEWEB)


    The hot-dry-rock project tasks are covered as follows: hot-dry-rock reservoir; generation facilities; water resources; transmission requirements; environmental issues; government and community institutional factors; leasing, ownership and management of facilities; regulations, permits, and laws; and financial considerations. (MHR)


    Energy Technology Data Exchange (ETDEWEB)

    Christie, Duncan; Arras, Phil; Li, Zhi-Yun [Department of Astronomy, University of Virginia, Charlottesville, VA 22904 (United States)


    Gas giant exoplanets orbiting at close distances to the parent star are subjected to large radiation and stellar wind fluxes. In this paper, hydrodynamic simulations of the planetary upper atmosphere and its interaction with the stellar wind are carried out to understand the possible flow regimes and how they affect the Lyα transmission spectrum. Following Tremblin and Chiang, charge exchange reactions are included to explore the role of energetic atoms as compared to thermal particles. In order to understand the role of the tail as compared to the leading edge of the planetary gas, the simulations were carried out under axisymmetry, and photoionization and stellar wind electron impact ionization reactions were included to limit the extent of the neutrals away from the planet. By varying the planetary gas temperature, two regimes are found. At high temperature, a supersonic planetary wind is found, which is turned around by the stellar wind and forms a tail behind the planet. At lower temperatures, the planetary wind is shut off when the stellar wind penetrates inside where the sonic point would have been. In this regime mass is lost by viscous interaction at the boundary between planetary and stellar wind gases. Absorption by cold hydrogen atoms is large near the planetary surface, and decreases away from the planet as expected. The hot hydrogen absorption is in an annulus and typically dominated by the tail, at large impact parameter, rather than by the thin leading edge of the mixing layer near the substellar point.

  3. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...... of negative emotional states in MDD. Limited success in the identification of susceptibility genes in MDD has led to great research interest in identifying vulnerability biomarkers or endophenotypes. Emerging evidence points to the persistence of 'hot' cognition dysfunction during remission and to subtle 'hot......' cognition deficits in healthy relatives of patients with MDD. Taken together, these findings suggest that abnormalities in 'hot' cognition may constitute a candidate neurocognitive endophenotype for depression....

  4. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...... to the perpetuation of negative emotional states in MDD. Limited success in the identification of susceptibility genes in MDD has led to great research interest in identifying vulnerability biomarkers or endophenotypes. Emerging evidence points to the persistence of 'hot' cognition dysfunction during remission...... and to subtle 'hot' cognition deficits in healthy relatives of patients with MDD. Taken together, these findings suggest that abnormalities in 'hot' cognition may constitute a candidate neurocognitive endophenotype for depression....

  5. Chandra Grating Spectroscopy of Three Hot White Dwarfs (United States)

    Adamczak, J.; Werner, K.; Rauch, T.; Schuh, S.; Drake, J. J.; Kruk, J. W.


    High-resolution soft X-ray spectroscopic observations of single hot white dwarfs are scarce. With the Chandra Low-Energy Transmission Grating, we have observed two white dwarfs, one is of spectral type DA (LB1919) and the other is a non-DA of spectral type PG1159 (PG1520+525). The spectra of both stars are analyzed, together with an archival Chandra spectrum of another DA white dwarf (GD246). Aims. The soft X-ray spectra of the two DA white dwarfs are investigated in order to study the effect of gravitational settling and radiative levitation of metals in their photospheres. LB1919 is of interest because it has a significantly lower metallicity than DAs with otherwise similar atmospheric parameters. GD246 is the only white dwarf known that shows identifiable individual iron lines in the soft X-ray range. For the PG1159 star, a precise effective temperature determination is performed in order to confine the position of the blue edge of the GW Vir instability region in the HRD. Methods. The Chandra spectra are analyzed with chemically homogeneous as well as stratified NLTE model atmospheres that assume equilibrium between gravitational settling and radiative acceleration of chemical elements. Archival EUV and UV spectra obtained with EUVE, FUSE, and HST are utilized to support the analysis. Results. No metals could be identified in LB1919. All observations are compatible with a pure hydrogen atmosphere. This is in stark contrast to the vast majority of hot DA white dwarfs that exhibit light and heavy metals and to the stratified models that predict significant metal abundances in the atmosphere. For GD246 we find that neither stratified nor homogeneous models can fit the Chandra spectrum. The Chandra spectrum of PG1520+525 constrains the effective temperature to T(sub eff) = 150 000 +/- 10 000 K. Therefore, this nonpulsating star together with the pulsating prototype of the GWVir class (PG1159-035) defines the location of the blue edge of the GWVir instability region

  6. Hydrogen Contractors Meeting

    Energy Technology Data Exchange (ETDEWEB)

    Fitzsimmons, Tim [Dept. of Energy (DOE), Washington DC (United States). Office of Basic Energy Sciences. Division of Materials Sciences and Engineering


    This volume highlights the scientific content of the 2006 Hydrogen Contractors Meeting sponsored by the Division of Materials Sciences and Engineering (DMS&E) on behalf of the Office of Basic Energy Sciences (BES) of the U. S. Department of Energy (DOE). Hydrogen Contractors Meeting held from May 16-19, 2006 at the Crystal Gateway Marriott Hotel Arlington, Virginia. This meeting is the second in a series of research theme-based Contractors Meetings sponsored by DMS&E held in conjunction with our counterparts in the Office of Energy Efficiency and Renewable Energy (EERE) and the first with the Hydrogen, Fuel Cells and Infrastructure Technologies Program. The focus of this year’s meeting is BES funded fundamental research underpinning advancement of hydrogen storage. The major goals of these research efforts are the development of a fundamental scientific base in terms of new concepts, theories and computational tools; new characterization capabilities; and new materials that could be used or mimicked in advancing capabilities for hydrogen storage.

  7. The hydrogen laminar jet

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Sanz, M. [Departamento de Motopropulsion y Termofluidomecanica, ETSI Aeronauticos, Universidad Politecnica de Madrid, 28040 Madrid (Spain); Rosales, M. [Department Ingenieria Termica y de Fluidos, Universidad Carlos III de Madrid, 28911, Leganes (Spain); Instituto de Innovacion en Mineria y Metalurgia, Avenida del Valle 738, Santiago (Chile); Sanchez, A.L. [Department Ingenieria Termica y de Fluidos, Universidad Carlos III de Madrid, 28911, Leganes (Spain)


    Numerical and asymptotic methods are used to investigate the structure of the hydrogen jet discharging into a quiescent air atmosphere. The analysis accounts in particular for the variation of the density and transport properties with composition. The Reynolds number of the flow R{sub j}, based on the initial jet radius a, the density {rho}{sub j} and viscosity {mu}{sub j} of the jet and the characteristic jet velocity u{sub j}, is assumed to take moderately large values, so that the jet remains slender and stable, and can be correspondingly described by numerical integration of the continuity, momentum and species conservation equations written in the boundary-layer approximation. The solution for the velocity and composition in the jet development region of planar and round jets, corresponding to streamwise distances of order R{sub j}a, is computed numerically, along with the solutions that emerge both in the near field and in the far field. The small value of the hydrogen-to-air molecular weight ratio is used to simplify the solution by considering the asymptotic limit of vanishing jet density. The development provides at leading-order explicit analytical expressions for the far-field velocity and hydrogen mass fraction that describe accurately the hydrogen jet near the axis. The information provided can be useful in particular to characterize hydrogen discharge processes from holes and cracks. (author)

  8. Hydrogen in Martian Meteorites (United States)

    Peslier, A. H.; Hervig, R.; Irving, T.


    Most volatile studies of Mars have targeted its surface via spacecraft and rover data, and have evidenced surficial water in polar caps and the atmosphere, in the presence of river channels, and in the detection of water bearing minerals. The other focus of Martian volatile studies has been on Martian meteorites which are all from its crust. Most of these studies are on hydrous phases like apatite, a late-stage phase, i.e. crystallizing near the end of the differentiation sequence of Martian basalts and cumulates. Moreover, calculating the water content of the magma a phosphate crystallized from is not always possible, and yet is an essential step to estimate how much water was present in a parent magma and its source. Water, however, is primarily dissolved in the interiors of differentiated planets as hydrogen in lattice defects of nominally anhydrous minerals (olivine, pyroxene, feldspar) of the crust and mantle. This hydrogen has tremendous influence, even in trace quantities, on a planet's formation, geodynamics, cooling history and the origin of its volcanism and atmosphere as well as its potential for life. Studies of hydrogen in nominally anhydrous phases of Martian meteorites are rare. Measuring water contents and hydrogen isotopes in well-characterized nominally anhydrous minerals of Martian meteorites is the goal of our study. Our work aims at deciphering what influences the distribution and origin of hydrogen in Martian minerals, such as source, differentiation, degassing and shock.

  9. Microfabricated hydrogen sensitive membranes

    Energy Technology Data Exchange (ETDEWEB)

    Naddaf, A.; Kraetz, L. [Lehrstuhl fuer Thermische Verfahrenstechnik, Technische Universitaet Kaiserslautern (Germany); Detemple, P.; Schmitt, S.; Hessel, V. [Institut fuer Mikrotechnik Mainz GmbH, Mainz (Germany); Faqir, N. [University of Jordan, Amman (Jordan); Bart, H.J.


    Thin, defect-free palladium, palladium/copper and palladium/silver hydrogen absorbing membranes were microfabricated. A dual sputtering technique was used to deposit the palladium alloy membranes of only 1 {mu}m thickness on a nonporous silicon substrate. Advanced silicon etching (ASE) was applied on the backside to create a mechanically stable support structure for the thin films. Performance evaluation was carried out for different gases in a temperature range of 20 C to 298 C at a constant differential pressure of 110 kPa at the two sides of the membrane. The composite membranes show an excellent permeation rate of hydrogen, which appears to be 0.05 Pa m{sup 3} s{sup -1} and 0.01.10{sup -3} Pa m{sup 3} s{sup -1} at 20 C for the microfabricated 23 % silver and the 53 % copper composite membranes, respectively. The selectivity to hydrogen over a gas mixture containing, in addition to hydrogen, carbon monoxide, carbon dioxide and nitrogen was measured. The mass spectrometer did not detect any CO{sub 2} or CO, showing that the membrane is completely hydrogen selective. The microfabricated membranes exhibit both high mechanical strength (they easily withstand pressures up to 4 bar) and high thermal stability (up to 650 C). (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  10. Tetramethylammonium hydrogen terephthalate

    Directory of Open Access Journals (Sweden)

    Leila Dolatyari


    Full Text Available The asymmetric unit of the title salt, C4H12N+·C8H5O4−, contains one half of a tetramethylammonium cation and one half of a hydrogen terephthalate monoanion. The N atom of the ammonium cation lies on a twofold rotation axis and the centre of mass of the terephthalate anion is on a centre of inversion. In the crystal, the centrosymmetric terephthalate ions are linked by a very short symmetric O—H...O hydrogen bond [O...O = 2.4610 (19 Å] into a one-dimensional polymeric chain along [1-12]. The tetramethylammonium cations and terephthalate anions are then connected through a pair of bifurcated acceptor C—H...O hydrogen bonds, generating a three-dimensional supramolecular network. The carboxylate groups at both ends of the terephthalate anion are charge-shared with an equal probability of 0.5.

  11. Hydrogen gas detector card

    Directory of Open Access Journals (Sweden)

    Francisco Sánchez Niño


    Full Text Available A small card used for detecting hydrogen gas in a crystal growth system by the liquid phase epitaxy technique was designed and built. The small size of the card enables its portability to other laboratories where leakage detection of hydrogen or other flammable gas is required. Card dimensions are approximately 10 cm long and 5 cm wide enabling easy transportation. The design is based on a microcontroller which reads the signal from the hydrogen sensor and internally compares the read value with preset values. Depending on the signal voltage a red, yellow or green LED will light to indicate the levels of concentration of the flammable gas. The card is powered by a 9 V battery.

  12. Magnesium for Hydrogen Storage

    DEFF Research Database (Denmark)

    Pedersen, Allan Schrøder; Kjøller, John; Larsen, B.


    A study of the hydrogenation characteristics of fine magnesium powder during repeated cycling has been performed using a high-pressure microbalance facility. No effect was found from the cycling regarding kinetics and storage capacity. The reaction rate of the absorption process was fast at tempe......A study of the hydrogenation characteristics of fine magnesium powder during repeated cycling has been performed using a high-pressure microbalance facility. No effect was found from the cycling regarding kinetics and storage capacity. The reaction rate of the absorption process was fast...... at temperatures around 600 K and above, but the reversed reaction showed somewhat slower kinetics around 600 K. At higher temperatures the opposite was found. The enthalpy and entropy change by the hydrogenation, derived from pressure-concentration isotherms, agree fairly well with those reported earlier....

  13. Hot workability of magnesium alloys (United States)

    Mwembela, Aaron Absalom

    For the alloy AZ91 (Mg-9.OAl-0.7Zn-0.13Mn) die cast specimens were subjected to torsion testing at 150, 180, 240, 300, 420 and 450°C at 0.05 0.5 and 5.0 s--1 The as-cast specimens exhibited hot shortness at 360°C and above; however in that domain, after prior thermomechanical processing (TMP) at 300°C, they showed much improved properties (which were reported along with as-cast properties at 300°C and below). For AZ31-Mn (Mg-3.2Al-1-1Zn-0.34Mn), AZ31 (Mg-2-8Al-0-88Zn-0.01Mn), AZ63 (Mg-5-5Al-2.7Zn-0.34Mn) and ZK60 (Mg-5.7Zn-0.65Zr-O-O1A]), the specimens were subjected to hot torsion testing in the range 180 to 450°C and 0.01, 0.1, and 1.0 s--1. In the temperature range below 300°C flow curves rise to a peak with failure occurring immediately thereafter. Above 300°C the flow curves exhibited a peak and a gradual decline towards steady state. The temperature and strain rate dependence of the strength is described by a sinh-Arrhenius equation with QHW between 125 and 144 kJ/mol; this indicates control by climb in comparison with creep in the range 200--400°C. The alloy strength and activation energy declined in the order AZ63, AZ31-Mn AZ91, AZ31 and ZK60, while ductility increased with decreasing strength. In working of Mg alloys from 150 to 450°C, the flow curves harden to a peak and work soften to a steady state regime above 300°C. At temperatures below 300°C, twinning is observed initially to bring grains into more suitable slip orientations. At high T a substructure develops due to basal and prismatic slip, Forming cells of augmented misorientation first near the grain boundaries and later towards the grain cores. Near the peak, new grains appear along the old boundaries (mantle) as a result of dynamic recrystallization DRX but not in the core of the initial grains. As T rises, the new grains are larger and the mantle broader, enhanced DRX results in higher ductility. At intermediate T, shear bands form through alignment of mantle zones resulting in

  14. Hydrogen vehicle fueling station

    Energy Technology Data Exchange (ETDEWEB)

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A. [Los Alamos National Lab., NM (United States)] [and others


    Hydrogen fueling stations are an essential element in the practical application of hydrogen as a vehicle fuel, and a number of issues such as safety, efficiency, design, and operating procedures can only be accurately addressed by a practical demonstration. Regardless of whether the vehicle is powered by an internal combustion engine or fuel cell, or whether the vehicle has a liquid or gaseous fuel tank, the fueling station is a critical technology which is the link between the local storage facility and the vehicle. Because most merchant hydrogen delivered in the US today (and in the near future) is in liquid form due to the overall economics of production and delivery, we believe a practical refueling station should be designed to receive liquid. Systems studies confirm this assumption for stations fueling up to about 300 vehicles. Our fueling station, aimed at refueling fleet vehicles, will receive hydrogen as a liquid and dispense it as either liquid, high pressure gas, or low pressure gas. Thus, it can refuel any of the three types of tanks proposed for hydrogen-powered vehicles -- liquid, gaseous, or hydride. The paper discusses the fueling station design. Results of a numerical model of liquid hydrogen vehicle tank filling, with emphasis on no vent filling, are presented to illustrate the usefulness of the model as a design tool. Results of our vehicle performance model illustrate our thesis that it is too early to judge what the preferred method of on-board vehicle fuel storage will be in practice -- thus our decision to accommodate all three methods.

  15. Hydrogen: Fueling the Future

    Energy Technology Data Exchange (ETDEWEB)

    Leisch, Jennifer


    As our dependence on foreign oil increases and concerns about global climate change rise, the need to develop sustainable energy technologies is becoming increasingly significant. Worldwide energy consumption is expected to double by the year 2050, as will carbon emissions along with it. This increase in emissions is a product of an ever-increasing demand for energy, and a corresponding rise in the combustion of carbon containing fossil fuels such as coal, petroleum, and natural gas. Undisputable scientific evidence indicates significant changes in the global climate have occurred in recent years. Impacts of climate change and the resulting atmospheric warming are extensive, and know no political or geographic boundaries. These far-reaching effects will be manifested as environmental, economic, socioeconomic, and geopolitical issues. Offsetting the projected increase in fossil energy use with renewable energy production will require large increases in renewable energy systems, as well as the ability to store and transport clean domestic fuels. Storage and transport of electricity generated from intermittent resources such as wind and solar is central to the widespread use of renewable energy technologies. Hydrogen created from water electrolysis is an option for energy storage and transport, and represents a pollution-free source of fuel when generated using renewable electricity. The conversion of chemical to electrical energy using fuel cells provides a high efficiency, carbon-free power source. Hydrogen serves to blur the line between stationary and mobile power applications, as it can be used as both a transportation fuel and for stationary electricity generation, with the possibility of a distributed generation energy infrastructure. Hydrogen and fuel cell technologies will be presented as possible pollution-free solutions to present and future energy concerns. Recent hydrogen-related research at SLAC in hydrogen production, fuel cell catalysis, and hydrogen

  16. Hot melt extrusion versus spray drying: hot melt extrusion degrades albendazole. (United States)

    Hengsawas Surasarang, Soraya; Keen, Justin M; Huang, Siyuan; Zhang, Feng; McGinity, James W; Williams, Robert O


    The purpose of this study was to enhance the dissolution properties of albendazole (ABZ) by the use of amorphous solid dispersions. Phase diagrams of ABZ-polymer binary mixtures generated from Flory-Huggins theory were used to assess miscibility and processability. Forced degradation studies showed that ABZ degraded upon exposure to hydrogen peroxide and 1 N NaOH at 80 °C for 5 min, and the degradants were albendazole sulfoxide (ABZSX), and ABZ impurity A, respectively. ABZ was chemically stable following exposure to 1 N HCl at 80 °C for one hour. Thermal degradation profiles show that ABZ, with and without Kollidon ® VA 64, degraded at 180 °C and 140 °C, respectively, which indicated that ABZ could likely be processed by thermal processing. Following hot melt extrusion, ABZ degraded up to 97.4%, while the amorphous ABZ solid dispersion was successfully prepared by spray drying. Spray-dried ABZ formulations using various types of acids (methanesulfonic acid, sulfuric acid and hydrochloric acid) and polymers (Kollidon ® VA 64, Soluplus ® and Eudragit ® E PO) were studied. The spray-dried ABZ with methanesulfonic acid and Kollidon ® VA 64 substantially improved non-sink dissolution in acidic media as compared to bulk ABZ (8-fold), physical mixture of ABZ:Kollidon ® VA 64 (5.6-fold) and ABZ mesylate salt (1.6-fold). No degradation was observed in the spray-dried product for up to six months and less than 5% after one-year storage. In conclusion, amorphous ABZ solid dispersions in combination with an acid and polymer can be prepared by spray drying to enhance dissolution and shelf-stability, whereas those made by melt extrusion are degraded.

  17. Hydrogen production from microbial strains (United States)

    Harwood, Caroline S; Rey, Federico E


    The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

  18. Polyhydride complexes for hydrogen storage

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, C.M. [Univ. of Hawaii, Honolulu, HI (United States)


    Polyhydride metal complexes are being developed for application in hydrogen storage. Efforts have focused on developing complexes with improved available hydrogen weight percentages. We have explored the possibility that complexes containing aromatic hydrocarbon ligands could store hydrogen at both the metal center and in the ligands. We have synthesized novel indenyl hydride complexes and explored their reactivity with hydrogen. The reversible hydrogenation of [IrH{sub 3}(PPh{sub 3})({eta}{sup 5}-C{sub 10}H{sub 7})]{sup +} has been achieved. While attempting to prepare {eta}{sup 6}-tetrahydronaphthalene complexes, we discovered that certain polyhydride complexes catalyze both the hydrogenation and dehydrogenation of tetrahydronaphthalene.

  19. Electrocatalysts for hydrogen energy

    CERN Document Server

    Losiewicz, Bozena


    This special topic volume deals with the development of novel solid state electrocatalysts of a high performance to enhance the rates of the hydrogen or oxygen evolution. It contains a description of various types of metals, alloys and composites which have been obtained using electrodeposition in aqueous solutions that has been identified to be a technologically feasible and economically superior technique for the production of the porous electrodes. The goal was to produce papers that would be useful to both the novice and the expert in hydrogen technologies. This volume is intended to be us

  20. Hydrogen bonded supramolecular materials

    CERN Document Server

    Li, Zhan-Ting


    This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed

  1. Electrochemical Hydrogen Evolution

    DEFF Research Database (Denmark)

    Laursen, A.B.; Varela Gasque, Ana Sofia; Dionigi, F.


    The electrochemical hydrogen evolution reaction (HER) is growing in significance as society begins to rely more on renewable energy sources such as wind and solar power. Thus, research on designing new, inexpensive, and abundant HER catalysts is important. Here, we describe how a simple experiment....... The curve visually shows students that the best HER catalysts are characterized by an optimal hydrogen binding energy (reactivity), as stated by the Sabatier principle. In addition, students may use this volcano curve to predict the activity of an untested catalyst solely from the catalyst reactivity...

  2. Hydrogen Energy Conversion (United States)


    Schoeppei, R.J. and Gray, C.L., "The Hydrogen Engine in P^srectl^e", Proceedings 7th international Energy Conversion Encrineering C^ference.: San Dxego...Conversion Engineering Conference, San Diego, Sept. 19/^, pp. 1349-1354. 10. Hausz, W., Leeth, G., and Meyer, C., "Eco-Energy", ibid, pp. 1316-1322. II...75114, . 24. ^schütz, R.H., "Hydrogen Burning Engine Experience", presented at Symposium, see Ref. 8. 25. A. Presto filipo (Pnblio Service’Electric S

  3. Hot Leg Piping Materials Issues

    Energy Technology Data Exchange (ETDEWEB)

    V. Munne


    With Naval Reactors (NR) approval of the Naval Reactors Prime Contractor Team (NRPCT) recommendation to develop a gas cooled reactor directly coupled to a Brayton power conversion system as the space nuclear power plant (SNPP) for Project Prometheus (References a and b) the reactor outlet piping was recognized to require a design that utilizes internal insulation (Reference c). The initial pipe design suggested ceramic fiber blanket as the insulation material based on requirements associated with service temperature capability within the expected range, very low thermal conductivity, and low density. Nevertheless, it was not considered to be well suited for internal insulation use because its very high surface area and proclivity for holding adsorbed gases, especially water, would make outgassing a source of contaminant gases in the He-Xe working fluid. Additionally, ceramic fiber blanket insulating materials become very friable after relatively short service periods at working temperatures and small pieces of fiber could be dislodged and contaminate the system. Consequently, alternative insulation materials were sought that would have comparable thermal properties and density but superior structural integrity and greatly reduced outgassing. This letter provides technical information regarding insulation and materials issues for the Hot Leg Piping preconceptual design developed for the Project Prometheus space nuclear power plant (SNPP).

  4. Hydrogen isotope fractionation in methane plasma (United States)

    Robert, François; Derenne, Sylvie; Lombardi, Guillaume; Hassouni, Khaled; Michau, Armelle; Reinhardt, Peter; Duhamel, Rémi; Gonzalez, Adriana; Biron, Kasia


    The hydrogen isotope ratio (D/H) is commonly used to reconstruct the chemical processes at the origin of water and organic compounds in the early solar system. On the one hand, the large enrichments in deuterium of the insoluble organic matter (IOM) isolated from the carbonaceous meteorites are interpreted as a heritage of the interstellar medium or resulting from ion-molecule reactions taking place in the diffuse part of the protosolar nebula. On the other hand, the molecular structure of this IOM suggests that organic radicals have played a central role in a gas-phase organosynthesis. So as to reproduce this type of chemistry between organic radicals, experiments based on a microwave plasma of CH4 have been performed. They yielded a black organic residue in which ion microprobe analyses revealed hydrogen isotopic anomalies at a submicrometric spatial resolution. They likely reflect differences in the D/H ratios between the various CHx radicals whose polymerization is at the origin of the IOM. These isotopic heterogeneities, usually referred to as hot and cold spots, are commensurable with those observed in meteorite IOM. As a consequence, the appearance of organic radicals in the ionized regions of the disk surrounding the Sun during its formation may have triggered the formation of organic compounds.

  5. Liquid Organic Hydrogen Carriers (LOHCs): Toward a Hydrogen-free Hydrogen Economy. (United States)

    Preuster, Patrick; Papp, Christian; Wasserscheid, Peter


    The need to drastically reduce CO 2 emissions will lead to the transformation of our current, carbon-based energy system to a more sustainable, renewable-based one. In this process, hydrogen will gain increasing importance as secondary energy vector. Energy storage requirements on the TWh scale (to bridge extended times of low wind and sun harvest) and global logistics of renewable energy equivalents will create additional driving forces toward a future hydrogen economy. However, the nature of hydrogen requires dedicated infrastructures, and this has prevented so far the introduction of elemental hydrogen into the energy sector to a large extent. Recent scientific and technological progress in handling hydrogen in chemically bound form as liquid organic hydrogen carrier (LOHC) supports the technological vision that a future hydrogen economy may work without handling large amounts of elemental hydrogen. LOHC systems are composed of pairs of hydrogen-lean and hydrogen-rich organic compounds that store hydrogen by repeated catalytic hydrogenation and dehydrogenation cycles. While hydrogen handling in the form of LOHCs allows for using the existing infrastructure for fuels, it also builds on the existing public confidence in dealing with liquid energy carriers. In contrast to hydrogen storage by hydrogenation of gases, such as CO 2 or N 2 , hydrogen release from LOHC systems produces pure hydrogen after condensation of the high-boiling carrier compounds. This Account highlights the current state-of-the-art in hydrogen storage using LOHC systems. It first introduces fundamental aspects of a future hydrogen economy and derives therefrom requirements for suitable LOHC compounds. Molecular structures that have been successfully applied in the literature are presented, and their property profiles are discussed. Fundamental and applied aspects of the involved hydrogenation and dehydrogenation catalysis are discussed, characteristic differences for the catalytic conversion of

  6. A review on hot tearing of magnesium alloys

    Directory of Open Access Journals (Sweden)

    Jiangfeng Song


    Full Text Available Hot tearing is often a major casting defect in magnesium alloys and has a significant impact on the quality of their casting products. Hot tearing of magnesium alloys is a complex solidification phenomenon which is still not fully understood, it is of great importance to investigate the hot tearing behaviour of magnesium alloys. This review attempts to summarize the investigations on hot tearing of magnesium alloys over the past decades. The hot tearing criteria including recently developed Kou's criterion are summarized and compared. The numeric simulation and assessing methods of hot tearing, factors influencing hot tearing, and hot tearing susceptibility (HTS of magnesium alloys are discussed.

  7. Polyakov loop modeling for hot QCD (United States)

    Fukushima, Kenji; Skokov, Vladimir


    We review theoretical aspects of quantum chromodynamics (QCD) at finite temperature. The most important physical variable to characterize hot QCD is the Polyakov loop, which is an approximate order parameter for quark deconfinement in a hot gluonic medium. Additionally to its role as an order parameter, the Polyakov loop has rich physical contents in both perturbative and non-perturbative sectors. This review covers a wide range of subjects associated with the Polyakov loop from topological defects in hot QCD to model building with coupling to the Polyakov loop.

  8. Biofilm formation in a hot water system

    DEFF Research Database (Denmark)

    Bagh, L.K.; Albrechtsen, Hans-Jørgen; Arvin, Erik


    The biofilm formation rate was measured in situ in a hot water system in an apartment building by specially designed sampling equipment, and the net growth of the suspended bacteria was measured by incubation of water samples with the indigeneous bacteria. The biofilm formation rate reached......, in the sludge, or in the water from the distribution system was negligible. This indicated that bacterial growth took place on the inner surfaces in the hot water system and biofilm formation and detachment of bacteria could account for most of the suspended bacteria actually measured in hot water. Therefore...

  9. Nanomaterials for Hydrogen Storage

    Indian Academy of Sciences (India)

    temperature T, by an equation analogous to the ideal gas law: π V=iRT. (1). R is the gas .... vehicular applications. Nanomaterials are a ... development of materials for hydrogen storage are the low rate of bulk hydride sorption and the high temperatures required for gas release. 3.0. Bulk material. <100 nm. Nanoparticles.

  10. Nanomaterials for Hydrogen Storage

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 12; Issue 5. Nanomaterials for Hydrogen Storage - The van't Hoff Connection. C S Sunandana. General Article Volume 12 Issue 5 May 2007 pp 31-36. Fulltext. Click here to view fulltext PDF. Permanent link:

  11. A Simple Hydrogen Electrode (United States)

    Eggen, Per-Odd


    This article describes the construction of an inexpensive, robust, and simple hydrogen electrode, as well as the use of this electrode to measure "standard" potentials. In the experiment described here the students can measure the reduction potentials of metal-metal ion pairs directly, without using a secondary reference electrode. Measurements…

  12. Hydrogen storage for automobiles

    Energy Technology Data Exchange (ETDEWEB)

    Strickland, G.


    Results of an analysis of hydrogen-fueled automobiles are presented as a part of a continuing study conducted by Lawrence Livermore Laboratory (LLL) on Energy Storage Systems for Automobile Propulsion. The hydrogen is stored either as a metal hydride at moderate pressure in TiFe/sub 0/ /sub 9/Mn/sub 0/ /sub 1/H/sub x/ and at low pressure in MgH/sub x/ catalyzed with 10 wt % Ni, or it is stored in hollow glass microspheres at pressures up to about 400 atm. Improved projections are given for the two hydrides, which are used in combination to take advantage of their complementary properties. In the dual-hydride case and in the microsphere case where Ti-based hydride is used for initial operation, hydrogen is consumed in an internal-combustion engine; whereas in the third case, hydrogen from Ti-based hydride is used with air in an alkaline fuel cell/Ni-Zn battery combination which powers an electric vehicle. Each system is briefly described; and the results of the vehicle analysis are compared with those for the conventional automobile and with electric vehicles powered by Pb-acid or Ni-Zn batteries. Comparisons are made on the basis of automobile weight, initial user cost, and life-cycle cost. In this report, the results are limited to those for the 5-passenger vehicle in the period 1985-1990, and are provided as probable and optimistic values.

  13. Economic data on hydrogenation

    Energy Technology Data Exchange (ETDEWEB)


    General information is recorded about hydrogenation plants and their operation up to July 1943. For 12 German plants, there is a table indicating date of beginning construction, start of operation, and production capacity, including gas. Another chart gives the same data for foreign plants, in the United States, England, Italy, Iran and Holland. Domestic and foreign partners and agreements are also listed, as well as license returns from hydrogenation. Extent of I.G. Farben patent ownership is given in a short list. Development of production costs for liquid products is indicated for the years 1927-1941. Data on test costs are also given. Production figures for hydrogenation are shown, as well as the share of Farben synthetics in total German fuel production. The report gives a breakdown for requirements of raw materials, manpower, capital, and construction steels for production of four million metric tons of fuels from hydrogenation. Finally, the report lists the special areas in which Farben was carrying on work related to synthetic fuels. The data are given mostly in tabular form.

  14. Hydrogen Storage Technical Team Roadmap

    Energy Technology Data Exchange (ETDEWEB)



    The mission of the Hydrogen Storage Technical Team is to accelerate research and innovation that will lead to commercially viable hydrogen-storage technologies that meet the U.S. DRIVE Partnership goals.

  15. Onboard hydrogen generation for automobiles (United States)

    Houseman, J.; Cerini, D. J.


    Problems concerning the use of hydrogen as a fuel for motor vehicles are related to the storage of the hydrogen onboard a vehicle. The feasibility is investigated to use an approach based on onboard hydrogen generation as a means to avoid these storage difficulties. Two major chemical processes can be used to produce hydrogen from liquid hydrocarbons and methanol. In steam reforming, the fuel reacts with water on a catalytic surface to produce a mixture of hydrogen and carbon monoxide. In partial oxidation, the fuel reacts with air, either on a catalytic surface or in a flame front, to yield a mixture of hydrogen and carbon monoxide. There are many trade-offs in onboard hydrogen generation, both in the choice of fuels as well as in the choice of a chemical process. Attention is given to these alternatives, the results of some experimental work in this area, and the combustion of various hydrogen-rich gases in an internal combustion engine.

  16. Biomimetic Production of Hydrogen (United States)

    Gust, Devens


    The basic reaction for hydrogen generation is formation of molecular hydrogen from two electrons and two protons. Although there are many possible sources for the protons and electrons, and a variety of mechanisms for providing the requisite energy for hydrogen synthesis, the most abundant and readily available source of protons and electrons is water, and the most attractive source of energy for powering the process is sunlight. Not surprisingly, living systems have evolved to take advantage of these sources for materials and energy. Thus, biology provides paradigms for carrying out the reactions necessary for hydrogen production. Photosynthesis in green plants uses sunlight as the source of energy for the oxidation of water to give molecular oxygen, protons, and reduction potential. Some photosynthetic organisms are capable of using this reduction potential, in the form of the reduced redox protein ferredoxin, to reduce protons and produce molecular hydrogen via the action of an hydrogenase enzyme. A variety of other organisms metabolize the reduced carbon compounds that are ultimately the major products of photosynthesis to produce molecular hydrogen. These facts suggest that it might be possible to use light energy to make molecular hydrogen via biomimetic constructs that employ principles similar to those used by natural organisms, or perhaps with hybrid "bionic" systems that combine biomimetic materials with natural enzymes. It is now possible to construct artificial photosynthetic systems that mimic some of the major steps in the natural process.(1) Artificial antennas based on porphyrins, carotenoids and other chromophores absorb light at various wavelengths in the solar spectrum and transfer the harvested excitation energy to artificial photosynthetic reaction centers.(2) In these centers, photoinduced electron transfer uses the energy from light to move an electron from a donor to an acceptor moiety, generating a high-energy charge-separated state

  17. Detroit Commuter Hydrogen Project

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, Jerry; Prebo, Brendan


    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with

  18. Photovoltaic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Hiser, H.W.; Memory, S.B.; Veziroglu, T.N.; Padin, J. [Univ. of Miami, Coral Gables, FL (United States)


    This is a new project, which started in June 1995, and involves photovoltaic hydrogen production as a fuel production method for the future. In order to increase the hydrogen yield, it was decided to use hybrid solar collectors to generate D.C. electricity, as well as high temperature steam for input to the electrolyzer. In this way, some of the energy needed to dissociate the water is supplied in the form of heat (or low grade energy), to generate steam, which results in a reduction of electrical energy (or high grade energy) needed. As a result, solar to hydrogen conversion efficiency is increased. In the above stated system, the collector location, the collector tracking sub-system (i.e., orientation/rotation), and the steam temperature have been taken as variables. Five locations selected - in order to consider a variety of latitudes, altitudes, cloud coverage and atmospheric conditions - are Atlanta, Denver, Miami, Phoenix and Salt Lake City. Plain PV and hybrid solar collectors for a stationary south facing system and five different collector rotation systems have been analyzed. Steam temperatures have been varied between 200{degrees}C and 1200{degrees}C. During the first year, solar to hydrogen conversion efficiencies have been considered. The results show that higher steam temperatures, 2 dimensional tracking system, higher elevations and dryer climates causes higher conversion efficiencies. Cost effectiveness of the sub-systems and of the overall system will be analyzed during the second year. Also, initial studies will be made of an advanced high efficiency hybrid solar hydrogen production system.

  19. Task D: Hydrogen safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Sievert, B.G. [Univ. of Miami, Coral Gables, FL (United States); Swain, M.N. [Analytical Technologies, Inc., Miami, FL (United States)


    This report covers two topics. The first is a review of codes, standards, regulations, recommendations, certifications, and pamphlets which address safety of gaseous fuels. The second is an experimental investigation of hydrogen flame impingement. Four areas of concern in the conversion of natural gas safety publications to hydrogen safety publications are delineated. Two suggested design criteria for hydrogen vehicle fuel systems are proposed. It is concluded from the experimental work that light weight, low cost, firewalls to resist hydrogen flame impingement are feasible.

  20. Hydrogen Fire Spectroscopy Issues Project (United States)

    Youngquist, Robert C. (Compiler)


    The detection of hydrogen fires is important to the aerospace community. The National Aeronautics and Space Administration (NASA) has devoted significant effort to the development, testing, and installation of hydrogen fire detectors based on ultraviolet, near-infrared, mid-infrared, andor far-infrared flame emission bands. Yet, there is no intensity calibrated hydrogen-air flame spectrum over this range in the literature and consequently, it can be difficult to compare the merits of different radiation-based hydrogen fire detectors.

  1. Safe Replacement For Asbestos In Nickel/Hydrogen Cells (United States)

    Scott, William E.


    Polyethylene fibers and potassium titanate particles perform as well as asbestos. New material for separators of nickel-hydrogen electrochemical cells offers performance similar to that of asbestos separator material without adverse health effects. In one version, separator contains pure polyethylene fibers, and may or may not contain supplementary latices as bonding agents. In standard wet-laying papermaking process, fibers pressed into mat, then dried. Mat used as is or pressed further in hot calender stack to soften and fuse fibers at crossing points. Treatment reduces porosity and increases resistance of mat to passage of air bubbles under pressure. In alternative version, matrix of 20 to 40 percent polyethylene fibers and 60 to 80 percent potassium titanate particles formed on paper machine, then dried. It, too, can be treated by hot calendering.

  2. Magnetic levitation of condensed hydrogen (United States)

    Paine, C. G.; Seidel, G. M.


    Liquid and solid molecular hydrogen has been levitated using a pair of small superconducting solenoids. The hydrogen samples, up to 3 mm in dimension, were trapped in a magnetic potential having either a discrete minimum or a minimum in the form of a ring 1 cm in diameter. The hydrogen could be moved about in the magnetic trap by applying an electric field.


    NARCIS (Netherlands)

    Abd El Keriem, M.S.; van der Werf, D.P.; Pleiter, F


    Vacancy-hydrogen interaction in molybdenum was investigated by means of the perturbed angular correlation technique, using the isotope In-111 as a probe. The complex InV2 turned out to trap up to two hydrogen atoms: trapping of a single hydrogen atom gives rise to a decrease of the quadrupole

  4. Realizing a hydrogen future: Hydrogen Technical Advisory Panel recommendations (brochure)

    Energy Technology Data Exchange (ETDEWEB)

    Cook, G.


    When generated from renewable sources, hydrogen production and use is part of a clean, cyclic process. Hydrogen can be used to generate electricity, heat homes and businesses, fuel vehicles, and produce commodities used every day. The Hydrogen Technical Advisory Panel's (HTAP) primary functions are to advise the Secretary of Energy on the implementation of the U.S.DOE programs in hydrogen RD and D and to review and make recommendations on the economic, technical, and environmental consequences of deploying safe hydrogen energy systems.


    Energy Technology Data Exchange (ETDEWEB)

    Moses, J. I. [Space Science Institute, 4750 Walnut Street, Suite 205, Boulder, CO 80301 (United States); Line, M. R. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Visscher, C. [Southwest Research Institute, Boulder, CO 80302 (United States); Richardson, M. R. [Rice University, Houston, TX 77005-1892 (United States); Nettelmann, N.; Fortney, J. J. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Barman, T. S. [Lowell Observatory, Flagstaff, AZ 86001 (United States); Stevenson, K. B. [Department of Astronomy and Astrophysics, University of Chicago, Chicago, IL 60637 (United States); Madhusudhan, N., E-mail: [Department of Physics and Department of Astronomy, Yale University, New Haven, CT 06520-8101 (United States)


    Neptune-sized extrasolar planets that orbit relatively close to their host stars—often called {sup h}ot Neptunes{sup —}are common within the known population of exoplanets and planetary candidates. Similar to our own Uranus and Neptune, inefficient accretion of nebular gas is expected produce hot Neptunes whose masses are dominated by elements heavier than hydrogen and helium. At high atmospheric metallicities of 10-10,000 times solar, hot Neptunes will exhibit an interesting continuum of atmospheric compositions, ranging from more Neptune-like, H{sub 2}-dominated atmospheres to more Venus-like, CO{sub 2}-dominated atmospheres. We explore the predicted equilibrium and disequilibrium chemistry of generic hot Neptunes and find that the atmospheric composition varies strongly as a function of temperature and bulk atmospheric properties such as metallicity and the C/O ratio. Relatively exotic H{sub 2}O, CO, CO{sub 2}, and even O{sub 2}-dominated atmospheres are possible for hot Neptunes. We apply our models to the case of GJ 436b, where we find that a CO-rich, CH{sub 4}-poor atmosphere can be a natural consequence of a very high atmospheric metallicity. From comparisons of our results with Spitzer eclipse data for GJ 436b, we conclude that although the spectral fit from the high-metallicity forward models is not quite as good as the best fit obtained from pure retrieval methods, the atmospheric composition predicted by these forward models is more physically and chemically plausible in terms of the relative abundance of major constituents. High-metallicity atmospheres (orders of magnitude in excess of solar) should therefore be considered as a possibility for GJ 436b and other hot Neptunes.

  6. Relation between Hydrogen Evolution and Hydrodesulfurization Catalysis

    DEFF Research Database (Denmark)

    Šaric, Manuel; Moses, Poul Georg; Rossmeisl, Jan


    A relation between hydrogen evolution and hydrodesulfurization catalysis was found by density functional theory calculations. The hydrogen evolution reaction and the hydrogenation reaction in hydrodesulfurization share hydrogen as a surface intermediate and, thus, have a common elementary step...

  7. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...... of negative emotional states in MDD. Limited success in the identification of susceptibility genes in MDD has led to great research interest in identifying vulnerability biomarkers or endophenotypes. Emerging evidence points to the persistence of 'hot' cognition dysfunction during remission and to subtle 'hot...... databases in May 2014 augmented by hand searches of reference lists. We included original articles in which MDD participants (or their healthy first-degree relatives) and a healthy control group were compared on standard measures of emotional processing or reward/ punishment processing as well as systematic...

  8. VT New Market Tax Credit - Hot Zones (United States)

    Vermont Center for Geographic Information — (Link to Metadata) The EconOther_NMTC layer delineates New Market Tax Credit (NMTC) "hot zones" and qualified counties and census tracts. This dataset is designed to...

  9. Hydrogen attack - Influence of hydrogen sulfide. [on carbon steel (United States)

    Eliezer, D.; Nelson, H. G.


    An experimental study is conducted on 12.5-mm-thick SAE 1020 steel (plain carbon steel) plate to assess hydrogen attack at room temperature after specimen exposure at 525 C to hydrogen and a blend of hydrogen sulfide and hydrogen at a pressure of 3.5 MN/sq m for exposure times up to 240 hr. The results are discussed in terms of tensile properties, fissure formation, and surface scales. It is shown that hydrogen attack from a high-purity hydrogen environment is severe, with the formation of numerous methane fissures and bubbles along with a significant reduction in the room-temperature tensile yield and ultimate strengths. However, no hydrogen attack is observed in the hydrogen/hydrogen sulfide blend environment, i.e. no fissure or bubble formation occurred and the room-temperature tensile properties remained unchanged. It is suggested that the observed porous discontinuous scale of FeS acts as a barrier to hydrogen entry, thus reducing its effective equilibrium solubility in the iron lattice. Therefore, hydrogen attack should not occur in pressure-vessel steels used in many coal gasification processes.

  10. Electrochemical Hydrogen Peroxide Generator (United States)

    Tennakoon, Charles L. K.; Singh, Waheguru; Anderson, Kelvin C.


    Two-electron reduction of oxygen to produce hydrogen peroxide is a much researched topic. Most of the work has been done in the production of hydrogen peroxide in basic media, in order to address the needs of the pulp and paper industry. However, peroxides under alkaline conditions show poor stabilities and are not useful in disinfection applications. There is a need to design electrocatalysts that are stable and provide good current and energy efficiencies to produce hydrogen peroxide under acidic conditions. The innovation focuses on the in situ generation of hydrogen peroxide using an electrochemical cell having a gas diffusion electrode as the cathode (electrode connected to the negative pole of the power supply) and a platinized titanium anode. The cathode and anode compartments are separated by a readily available cation-exchange membrane (Nafion 117). The anode compartment is fed with deionized water. Generation of oxygen is the anode reaction. Protons from the anode compartment are transferred across the cation-exchange membrane to the cathode compartment by electrostatic attraction towards the negatively charged electrode. The cathode compartment is fed with oxygen. Here, hydrogen peroxide is generated by the reduction of oxygen. Water may also be generated in the cathode. A small amount of water is also transported across the membrane along with hydrated protons transported across the membrane. Generally, each proton is hydrated with 3-5 molecules. The process is unique because hydrogen peroxide is formed as a high-purity aqueous solution. Since there are no hazardous chemicals or liquids used in the process, the disinfection product can be applied directly to water, before entering a water filtration unit to disinfect the incoming water and to prevent the build up of heterotrophic bacteria, for example, in carbon based filters. The competitive advantages of this process are: 1. No consumable chemicals are needed in the process. The only raw materials

  11. Bibliography on Hot Isostatic Pressing (HIP) Technology (United States)


    Carbon Astrology Subjected to Hot Isostatic Pressing Jablonski, D. A. Mater Sci Eng 48 (2), 189-98, 1981 ( AD-D121 615) Key Words: Udimet 700...turbine components, heat treatment, microstructure tensile properties, fractography, porosity 73. Manufacture of Low Carbon Astrology Turbine Disk...Pyromet CTX- 1, Pyromet 3 i, tensile properties, creep rupture, microstructure 119 15. Manufacture of Low Carbon Astrology Turbine Disk Shapes by Hot

  12. Sealed source dismantling hot cell - startup

    Energy Technology Data Exchange (ETDEWEB)

    Dellamano, Jose Claudio; Ferreira, Robson de Jesus, E-mail:, E-mail: [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Gerencia de Rejeitos radioativos


    Sealed radioactive sources are widely used in many applications of nuclear technology and at the end of the useful life, most sources become radioactive waste. In Brazil, this waste is received by the Institutes of the National Nuclear Energy Commission and kept under centralized storage. The Waste Management Department at the Nuclear and Energy Research Institute is the main storage center, having received around 20,000 disused sources. A hot cell was designed and constructed to manage Co-60 spent sealed sources with activity up to 3.7 10{sup 1}0 Bq and other sources with equivalent activities. In the hot cell the sources are withdraw from their original shielding and transferred to a standard shielding for further disposal off. The original shielding disassembling is made outside the hot cell and after opening, it is transferred inside the hot cell and the sealed source is removed remotely. The source is checked in relation to external contamination and its activity is checked. After this, the source is positioned in the standard shielding located inside an overpack at the bottom of the hot cell. This paper describes some pre-operational tests carried out in it, that include: opening and closing doors and locks, checking of all electrical and pneumatic controls, the original shielding movement inside the hot-cell, dose rate measurements outside the hot-cell, insertion of the sealed sources inside the activity meter chamber, transferring the sealed source to the standard shielding, movement of the overpack with the standard shielding to outside of the hot-cell and plugging of the standard shielding. (author)

  13. The interaction between hot and cold gas in early-type galaxies (United States)

    Bregman, Joel N.; Hogg, David E.; Roberts, Morton S.


    SO and Sa galaxies have approximately equal masses of H I and X-ray emitting gas and are ideal sites for studying the interaction between hot and cold gas. An X-ray observation of the Sa galaxy NGC 1291 with the ROSAT position sensitive proportional counter (PSPC) shows a striking spatial anticorrelation between hot and cold gas where X-ray emitting material fills the large central black hole in the H I disk. This supports a previous suggestion that hot gas is a bulge phenomenon and neutral hydrogen is a disk phenomenon. The X-ray luminosity (1.5 x 10(exp 40) ergs/s) and radial surface brightness distribution (beta = 0.51) is the same as for elliptical galaxies with optical luminosities and velocity dispersions like that of the bulge of NGC 1291. Modeling of the X-ray spectrum requires a component with a temperature of 0.15 keV, similar to that expected from the velocity dispersion of the stars, and with a hotter component where kT = 1.07 keV. This hotter component is not due to emission from stars and its origin remains unclear. PSPC observations are reported for the SO NGC 4203, where a nuclear point source dominates the emission, preventing a study of the radial distribution of the hot gas relative to the H I.

  14. Disaggregating Hot Water Use and Predicting Hot Water Waste in Five Test Homes

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, H.; Wade, J.


    While it is important to make the equipment (or 'plant') in a residential hot water system more efficient, the hot water distribution system also affects overall system performance and energy use. Energy wasted in heating water that is not used is estimated to be on the order of 10 to 30 percent of total domestic hot water (DHW) energy use. This field monitoring project installed temperature sensors on the distribution piping (on trunks and near fixtures) and programmed a data logger to collect data at 5 second intervals whenever there was a hot water draw. This data was used to assign hot water draws to specific end uses in the home as well as to determine the portion of each hot water that was deemed useful (i.e., above a temperature threshold at the fixture). Five houses near Syracuse NY were monitored. Overall, the procedures to assign water draws to each end use were able to successfully assign about 50% of the water draws, but these assigned draws accounted for about 95% of the total hot water use in each home. The amount of hot water deemed as useful ranged from low of 75% at one house to a high of 91% in another. At three of the houses, new water heaters and distribution improvements were implemented during the monitoring period and the impact of these improvements on hot water use and delivery efficiency were evaluated.

  15. Disaggregating Hot Water Use and Predicting Hot Water Waste in Five Test Homes

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, Hugh [ARIES Collaborative, New York, NY (United States); Wade, Jeremy [ARIES Collaborative, New York, NY (United States)


    While it is important to make the equipment (or "plant") in a residential hot water system more efficient, the hot water distribution system also affects overall system performance and energy use. Energy wasted in heating water that is not used is estimated to be on the order of 10%-30% of total domestic hot water (DHW) energy use. This field monitoring project installed temperature sensors on the distribution piping (on trunks and near fixtures) in five houses near Syracuse, NY, and programmed a data logger to collect data at 5 second intervals whenever there was a hot water draw. This data was used to assign hot water draws to specific end uses in the home as well as to determine the portion of each hot water that was deemed useful (i.e., above a temperature threshold at the fixture). Overall, the procedures to assign water draws to each end use were able to successfully assign about 50% of the water draws, but these assigned draws accounted for about 95% of the total hot water use in each home. The amount of hot water deemed as useful ranged from low of 75% at one house to a high of 91% in another. At three of the houses, new water heaters and distribution improvements were implemented during the monitoring period and the impact of these improvements on hot water use and delivery efficiency were evaluated.

  16. High-quality Single-walled carbon nanotubes synthesis by hot filament CVD on Ru nanoparticule catalyst


    Bouanis, Fatima Zara; Baraton, Laurent; Huc, Vincent; Pribat, Didier; Cojocaru, Costel Sorin


    International audience; We investigated the single-walled carbon nanotubes (SWCNTs) growth on Ru nanoparticle catalyst via hot filament assisted chemical vapor deposition (HFCVD) with two independent W filaments for the carbon precursor (methane) and the hydrogen dissociation respectively. The Ru nanoparticles were obtained following a two-step strategy. At first the growth substrate is functionalized by silanisation, then a self assembly of a ruthenium porphyrin complex monolayer on pyridine...

  17. Photoresist removal process by hydrogen radicals generated by W catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Takata, M. [Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, 560-8531 (Japan)], E-mail:; Ogushi, K.; Yuba, Y.; Akasaka, Y. [Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, 560-8531 (Japan); Tomioka, K.; Soda, E.; Kobayashi, N. [Semiconductor Leading Edge Technologies Inc., 16-1 Onogawa Tsukuba, Ibaraki, 305-8569 (Japan)


    Hydrogen radical process for photoresist removal by use of hot W catalyst has been investigated for a possible application to advanced Cu/low-k dielectric interconnects in LSI. It is found that etching rates of resists depend critically on sample temperature (T{sub s}) and are higher than 1 {mu}m/min at the optimized condition. H radical irradiation effects on porous methylsilsesquioxane (p-MSQ) have been studied from measurements of k value and capacitance of the advanced interconnect test sample. No radical process is observed to induce the increase in k value of p-MSQ films. These results suggest that the hydrogen radical process for resist removal with W catalyst is promising for production of advanced interconnects.

  18. Hydrogen adsorption on rhodium

    Energy Technology Data Exchange (ETDEWEB)

    Belyaeva, M.E.; Michri, A.A.; Kalish, T.V.; Pshenichnikov, A.G.; Kazarinov, V.E.


    Measurements of thermal desorption and electron work function were used to investigate the mechanism of hydrogen adsorption from the gas phase on rhodium single-crystal faces and on a polycrystalline rhodium sample at room temperatures over the pressure range from 1.3-10/sup -3/ to 1.3 x 10/sup -5/ Pa. It was found that dipoles oriented with their negative ends toward the gas phase (dipoles of type I) form more rapidly than dipoles having the opposite orientation (dipoles of type II). For formation of the latter, a mechanism is proposed according to which the rate-determining step of the overall process is the transition of reversibly adsorbed hydrogen to dipoles of type II (the spillover), which occurs at surface defects. It was shown that the kinetics of this process with respect to the individual defect obeys an equation which is zeroth order in theta/sub H/ and pressure.

  19. Reversible hydrogen storage materials

    Energy Technology Data Exchange (ETDEWEB)

    Ritter, James A [Lexington, SC; Wang, Tao [Columbia, SC; Ebner, Armin D [Lexington, SC; Holland, Charles E [Cayce, SC


    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  20. Offshore Facilities to Produce Hydrogen

    Directory of Open Access Journals (Sweden)

    Pilar Blanco-Fernández


    Full Text Available As a result of international agreements on the reduction of CO2 emissions, new technologies using hydrogen are being developed. Hydrogen, despite being the most abundant element in Nature, cannot be found in its pure state. Water is one of the most abundant sources of hydrogen on the planet. The proposal here is to use energy from the sea in order to obtain hydrogen from water. If plants to obtain hydrogen were to be placed in the ocean, the impact of long submarines piping to the coast will be reduced. Further, this will open the way for the development of ships propelled by hydrogen. This paper discusses the feasibility of an offshore installation to obtain hydrogen from the sea, using ocean wave energy.

  1. Molecular and Metallic Hydrogen (United States)


    Livermore Laboratory, Dr. J. C. Raich of the Colorado State University, and Dr. R. H. Wentorf, Jr., of the General Electric Company for their reviews...investigated by Raich and Etters [8], who have made ground-state energy calculations for hydrogen molecules retaining the orientation dependence of the...consistent with work of Raich and Etters [8], who have made similar calculations during the course of their work on the rotational transition in solid

  2. Coal liquefaction and hydrogenation (United States)

    Schindler, Harvey D.


    The coal liquefaction process disclosed uses three stages. The first stage is a liquefaction. The second and third stages are hydrogenation stages at different temperatures and in parallel or in series. One stage is within F. and optimizes solvent production. The other stage is within F. and optimizes the C.sub.5 F. product.

  3. Massive Warm/Hot Galaxy Coronae as Probed by UV/X-Ray Oxygen Absorption and Emission. I. Basic Model (United States)

    Faerman, Yakov; Sternberg, Amiel; McKee, Christopher F.


    We construct an analytic phenomenological model for extended warm/hot gaseous coronae of L* galaxies. We consider UV O vi Cosmic Origins Spectrograph (COS)-Halos absorption line data in combination with Milky Way (MW) X-ray O vii and O viii absorption and emission. We fit these data with a single model representing the COS-Halos galaxies and a Galactic corona. Our model is multi-phased, with hot and warm gas components, each with a (turbulent) log-normal distribution of temperatures and densities. The hot gas, traced by the X-ray absorption and emission, is in hydrostatic equilibrium in an MW gravitational potential. The median temperature of the hot gas is 1.5× {10}6 K and the mean hydrogen density is ˜ 5× {10}-5 {{cm}}-3. The warm component as traced by the O vi, is gas that has cooled out of the high density tail of the hot component. The total warm/hot gas mass is high and is 1.2× {10}11 {M}⊙ . The gas metallicity we require to reproduce the oxygen ion column densities is 0.5 solar. The warm O vi component has a short cooling time (˜ 2× {10}8 years), as hinted by observations. The hot component, however, is ˜ 80 % of the total gas mass and is relatively long-lived, with {t}{cool}˜ 7× {10}9 years. Our model supports suggestions that hot galactic coronae can contain significant amounts of gas. These reservoirs may enable galaxies to continue forming stars steadily for long periods of time and account for “missing baryons” in galaxies in the local universe.

  4. Phosphorylation in hydrogen bacteria. (United States)

    Bongers, L


    The electron-transport system of cell-free extracts obtained from Hydrogenomonas H-20 has been studied with particular reference to phosphorylation associated with the oxyhydrogen reaction. Cell-free preparations of this organism exhibit oxidative phosphorylation with hydrogen and succinate as electron donors. This activity could be uncoupled with a number of agents. Ratios of phosphorylative activity to oxidative activity observed varied from 0.2 to 0.7. Factors affecting the efficiency of phosphorylation were examined. Inhibitor and spectrophotometric studies indicated that phosphorylation with hydrogen as electron donor occurs exclusively at a site in an abbreviated electron transport chain between H(2) and cytochrome b. The possible occurrence of a cytochrome b oxidase and the requirement for a quinone are discussed, as well as the correlation between the abbreviated pathway and the energy generation by the cell. Evidence is presented which indicates that nicotinamide adenine dinucleotide does not participate in the hydrogen oxidation path which is coupled to adenosine triphosphate formation.

  5. Photoelectrochemical hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Rocheleau, R.E.; Miller, E.; Zhang, Z. [Univ. of Hawaii, Honolulu, HI (United States)


    The large-scale production of hydrogen utilizing energy provided by a renewable source to split water is one of the most ambitious long-term goals of the U.S. Department of Energy`s Hydrogen Program. Photoelectrochemical devices-direct photoconversion systems utilizing a photovoltaic-type structure coated with water-splitting catalysts-represent a promising option to meet this goal. Direct solar-to-chemical conversion efficiencies greater than 7% and photoelectrode lifetimes of up to 30 hours in 1 molar KOH have been demonstrated in our laboratory using low-cost, amorphous-silicon-based photoelectrodes. Loss analysis models indicate that the DOE`s goal of 10% solar-to-chemical conversion can be met with amorphous-silicon-based structures optimized for hydrogen production. In this report, we describe recent progress in the development of thin-film catalytic/protective coatings, improvements in photoelectrode efficiency and stability, and designs for higher efficiency and greater stability.

  6. Emission of Air Pollutants in the Hot Water Production (United States)

    Krzysztof, Nowak; Maria, Bukowska; Danuta, Proszak-Miąsik; Sławomir, Rabczak


    The result of the deteriorating condition of the environment and climate change is to increase the efficient use of fuel and energy and the rational use of energy resources. Great potential for reducing consumption of fossil fuels are stuck in heating systems ranging from generation, transmission and distribution and ending with the recipients rationalize their consumption of heat. Efficient production of heat is obtained during optimal boiler load. The boiler type WR operates with the highest efficiency of 80-85%, the rate of fuel consumption is the lowest, and the process is close to complete combustion. In such conditions to the atmosphere are emitted mainly: SO2, CO2 and NOX. Pollutants such as CO, CH4, HF, HCl, NH3, etc., are the result of incomplete and imperfect combustion, that is, when the boiler is working inefficiently [1-3]. Measurements of pollutant concentrations were performed using an analyzer FTIR Gasmet DX4000. Fourier Transform Infrared Spectroscopy is a technique of measuring that allows a very precise identification of qualitative and quantitative range of compounds, including gaseous pollutants. Device used to measure the concentrations of gaseous pollutants allow determining the amount of carbon, sulphur and nitrogen compounds, which measurement is not defined any rules, including chlorine compounds, hydrogen, methane, ammonia and volatile organic compounds. In this publication presents part of the literature the use of heat for domestic hot water production in summer and heating demand in winter. Described the characteristics of the water boilers WR type used for heating. Presents the results study of the emissions in the production of hot water for the summer and winter seasons.

  7. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons (United States)

    Muradov, Nazim Z [Melbourne, FL


    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  8. Experiments with the hot list strategy

    Energy Technology Data Exchange (ETDEWEB)

    Wos, L.


    Experimentation strongly suggests that, for attacking deep questions and hard problems with the assistance of an automated reasoning program, the more effective paradigms rely on the retention of deduced information. A significant obstacle ordinarily presented by such a paradigm is the deduction and retention of one or more needed conclusions whose complexity sharply delays their consideration. To mitigate the severity of the cited obstacle, the author formulates and features in this report the hot list strategy. The hot list strategy asks the researcher to choose, usually from among the input statements, one or more clauses that are conjectured to play a key role for assignment completion. The chosen clauses - conjectured to merit revisiting, again and again - are placed in an input list of clauses, called the hot list. When an automated reasoning program has decided to retain a new conclusion C - before any other clause is chosen to initiate conclusion drawing - the presence of a nonempty hot list (with an appropriate assignment of the input parameter known as heat) causes each inference rule in use to be applied to C together with the appropriate number of members of the hot list. Members of the hot list are used to complete applications of inference rules and not to initiate applications. The use of the hot list strategy thus enables an automated reasoning program to briefly consider a newly retained conclusion whose complexity would otherwise prevent its use for perhaps many CPU-hours. To give evidence of the value of the strategy, the author focuses on four contexts: (1) dramatically reducing the CPU time required to reach a desired goal; (2) finding a proof of a theorem that had previously resisted all but the more inventive automated attempts; (3) discovering a proof that is more elegant than previously known; and (4) answering a question that had steadfastly eluded researchers relying on an automated reasoning program.


    Directory of Open Access Journals (Sweden)



    Full Text Available In this study, I examine the characteristics of U.S. corporate borrowers (public debt, private placement, and syndicated loan firms in HOT versus COLD equity markets. My main objective is to see the characteristics of firms that choose debt financing even when the equity market is HOT. HOT equity markets are defined as the top twenty percent of the months in terms of the de-trended number of equity offerings. I find that the HOT equity market borrowers generally have higher market-to-book ratios compared to the COLD market borrowers. Also, in HOT equity markets, the public debt firms (i.e. the corporate bond issuers tend to have fewer tangible assets, the private placement firms tend to be smaller and highly levered, and the syndicated loan firms tend to be smaller, more profitable, and less levered compared to the COLD market firms. When I look at the number of transactions in each market, I find that when the equity market is active (i.e. HOT, the syndicated loan market is even more active. During these periods, the public debt market is also active (although not as much as the equity or the syndicated loan markets. When I look at the sizes of the transactions in each market, I find that the private placements tend to be significantly larger in HOT markets compared to COLD markets. I conclude that while the equity, the public debt, and the syndicated loan markets move together in terms of market activity, the equity market and the private placement markets move together in terms of the size of the transaction.

  10. Molecular Beam Studies of Hot Atom Chemical Reactions: Reactive Scattering of Energetic Deuterium Atoms (United States)

    Continetti, R. E.; Balko, B. A.; Lee, Y. T.


    A brief review of the application of the crossed molecular beams technique to the study of hot atom chemical reactions in the last twenty years is given. Specific emphasis is placed on recent advances in the use of photolytically produced energetic deuterium atoms in the study of the fundamental elementary reactions D + H{sub 2} -> DH + H and the substitution reaction D + C{sub 2}H{sub 2} -> C{sub 2}HD + H. Recent advances in uv laser and pulsed molecular beam techniques have made the detailed study of hydrogen atom reactions under single collision conditions possible.

  11. Molecular beam studies of hot atom chemical reactions: Reactive scattering of energetic deuterium atoms

    Energy Technology Data Exchange (ETDEWEB)

    Continetti, R.E.; Balko, B.A.; Lee, Y.T.


    A brief review of the application of the crossed molecular beams technique to the study of hot atom chemical reactions in the last twenty years is given. Specific emphasis is placed on recent advances in the use of photolytically produced energetic deuterium atoms in the study of the fundamental elementary reactions D + H/sub 2/ /minus/> DH + H and the substitution reaction D + C/sub 2/H/sub 2/ /minus/> C/sub 2/HD + H. Recent advances in uv laser and pulsed molecular beam techniques have made the detailed study of hydrogen atom reactions under single collision conditions possible. 18 refs., 9 figs.

  12. The atomic hydrogen cloud in the saturnian system (United States)

    Tseng, W.-L.; Johnson, R. E.; Ip, W.-H.


    The importance of Titan's H torus shaped by solar radiation pressure and of hydrogen atoms flowing out of Saturn's atmosphere in forming the broad hydrogen cloud in Saturn's magnetosphere is still debated. Since the Saturnian system also contains a water product torus which originates from the Enceladus plumes, the icy ring particles, and the inner icy satellites, as well as Titan's H2 torus, we have carried out a global investigation of the atomic hydrogen cloud taking into account all sources. We show that the velocity and angle distributions of the hot H ejected from Saturn's atmosphere following electron-impact dissociation of H2 are modified by collisions with the ambient atmospheric H2 and H. This in turn affects the morphology of the escaping hydrogen from Saturn, as does the morphology of the ionospheric electron distribution. Although an exact agreement with the Cassini observations is not obtained, our simulations show that H directly escaping from Titan is the dominant contributor in the outer magnetosphere. Of the total number of H observed by Cassini from 1 to 5RS, ∼5.7×1034, our simulations suggest ∼20% is from dissociation in the Enceladus torus, ∼5-10% is from dissociation of H2 in the atmosphere of the main rings, and ∼50% is from Titan's H torus, implying that ∼20% comes from Saturn atmosphere.

  13. A Mechanistic Model of a Passive Autocatalytic Hydrogen Recombiner

    Directory of Open Access Journals (Sweden)

    Rożeń Antoni


    Full Text Available : A passive autocatalytic hydrogen recombiner (PAR is a self-starting device, without operator action or external power input, installed in nuclear power plants to remove hydrogen from the containment building of a nuclear reactor. A new mechanistic model of PAR has been presented and validated by experimental data and results of Computational Fluid Dynamics (CFD simulations. The model allows to quickly and accurately predict gas temperature and composition, catalyst temperature and hydrogen recombination rate. It is assumed in the model that an exothermic recombination reaction of hydrogen and oxygen proceeds at the catalyst surface only, while processes of heat and mass transport occur by assisted natural and forced convection in non-isothermal and laminar gas flow conditions in vertical channels between catalyst plates. The model accounts for heat radiation from a hot catalyst surface and has no adjustable parameters. It can be combined with an equation of chimney draft and become a useful engineering tool for selection and optimisation of catalytic recombiner geometry.

  14. 10 CFR 431.102 - Definitions concerning commercial water heaters, hot water supply boilers, and unfired hot water... (United States)


    ... 10 Energy 3 2010-01-01 2010-01-01 false Definitions concerning commercial water heaters, hot water supply boilers, and unfired hot water storage tanks. 431.102 Section 431.102 Energy DEPARTMENT OF ENERGY... Water Heaters, Hot Water Supply Boilers and Unfired Hot Water Storage Tanks § 431.102 Definitions...

  15. Metamaterial perfect absorber based hot electron photodetection. (United States)

    Li, Wei; Valentine, Jason


    While the nonradiative decay of surface plasmons was once thought to be only a parasitic process that limits the performance of plasmonic devices, it has recently been shown that it can be harnessed in the form of hot electrons for use in photocatalysis, photovoltaics, and photodetectors. Unfortunately, the quantum efficiency of hot electron devices remains low due to poor electron injection and in some cases low optical absorption. Here, we demonstrate how metamaterial perfect absorbers can be used to achieve near-unity optical absorption using ultrathin plasmonic nanostructures with thicknesses of 15 nm, smaller than the hot electron diffusion length. By integrating the metamaterial with a silicon substrate, we experimentally demonstrate a broadband and omnidirectional hot electron photodetector with a photoresponsivity that is among the highest yet reported. We also show how the spectral bandwidth and polarization-sensitivity can be manipulated through engineering the geometry of the metamaterial unit cell. These perfect absorber photodetectors could open a pathway for enhancing hot electron based photovoltaic, sensing, and photocatalysis systems.

  16. Handheld hydrogen - a new concept for hydrogen storage

    DEFF Research Database (Denmark)

    Johannessen, Tue; Sørensen, Rasmus Zink


    A method of hydrogen storage using metal ammine complexes in combination with an ammonia decomposition catalyst is presented. This dense hydrogen storage material has high degree of safety compared to all the other available alternatives. This technology reduces the safety hazards of using liquid...... ammonia and benefits from the properties of ammonia as a fuel. The system can be used as a safe, reversible, low-cost hydrogen carrier....

  17. Aerobic and Anaerobic Oxidation of Organic Acids in Yellowstone Hot Spring Ecosystems (United States)

    Windman, T. O.; Zolotova, N.; Shock, E.


    Thermodynamic analysis of energy supply based on samples collected from continental hot spring ecosystems at Yellowstone show that aerobic reactions yield the greatest energy. In terms of energy per mole of electrons transferred, aerobic oxidation of organic acids rivals or exceeds the energy supply from aerobic oxidation of hydrogen, CO, hydrogen sulfide, pyrite, sulfur or ammonia. This analysis is derived from samples collected where hot spring fluid are in contact with the atmosphere. It is likely that oxygen will be present at lower concentrations deeper in the system, which will place hard constraints on aerobic lifestyles. If so, which metabolisms could be supported deeper in the system? How will other oxidants be used to release energy? What characterizes the transition from aerobic to anaerobic oxidation? To answer these questions, pH, temperature, and alkalinity were measured in the field while measurements of dissolved oxygen and other redox-sensitive species (nitrate, ammonia, ferrous iron, and sulfide) were made with field-portable spectrophotometers and samples were taken for analysis of organic and inorganic ions by ion chromatography. Conditions in the subsurface can be predicted by starting from measured oxygen concentrations and calculating the effect of decreasing the concentration on the overall energetics of the system. Depending on hot spring composition, the amount of energy from aerobic oxidation of organic acid anions like succinate matches that from anaerobic oxidation (by nitrate or sulfate) once the log of the activity of dissolved oxygen drops to -6 to -8. These activities are 1 to 4 orders of magnitude lower that values determined for surface water in the hot springs. At lower oxygen activities aerobic oxidation gives way to anaerobic oxidation, and organic oxidation is more likely to involve nitrate and sulfate. Preliminary estimates indicate that these changes may occur at shallow depths in hot spring sediments (perhaps within the

  18. Formation and fate of fermentation products in hot spring cyanobacterial mats

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, K.L.; Tayne, T.A.; Ward, D.M.


    The fate of representative fermentation products (acetate, propionate, butyrate, lactate, and ethanol) in hot spring cyanobacterial mats was investigated. The major fate during incubations in the light was photoassimilation by filamentous bacteria resembling Chloroflexus aurantiacus. Some metabolism of all compounds occurred under dark aerobic conditions. Under dark anaerobic conditions, only lactate was oxidized extensively to carbon dioxide. Extended preincubation under dark anaerobic conditions did not enhance anaerobic catabolism of acetate, propionate, or ethanol. Acetogenesis of butyrate was suggested by the hydrogen sensitivity of butyrate conversion to acetate and by the enrichment of butyrate-degrading acetogenic bacteria. Accumulation of fermentation products which were not catabolized under dark anaerobic conditions revealed their importance. Acetate and propionate were the major fermentation products which accumulated in samples collected at temperatures ranging from 50 to 70/sup 0/C. Other organic acids and alcohols accumulated to a much lesser extent. Fermentation occurred mainly in the top 4 mm of the mat. Exposure to light decreased the accumulation of acetate and presumably of other fermentation products. The importance of interspecies hydrogen transfer was investigated by comparing fermentation product accumulation at a 65/sup 0/C site, with naturally high hydrogen levels, and a 55/sup 0/C site, where active methanogenesis prevented significant hydrogen accumulation. There was a greater relative accumulation of reduced products, notably ethanol, in the 65/sup 2/C mat.

  19. Hydrogen application dynamics and networks

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, E. [Air Liquide Large Industries, Champigny-sur-Marne (France)


    The Chemical Industry consumes large volumes of hydrogen as raw material for the manufacture of numerous products (e.g. polyamides and polyurethanes account for 60% of hydrogen demand). The hydrogen demand was in the recent past and will continue to be driven by the polyurethane family. China will host about 60% of new hydrogen needs over the period 2010-2015 becoming the first hydrogen market next year and reaching 25% of market share by 2015 (vs. only 4% in 2001). Air Liquide supplies large volumes of Hydrogen (and other Industrial Gases) to customers by on-site plants and through pipeline networks which offer significant benefits such as higher safety, reliability and flexibility of supply. Thanks to its long term strategy and heavy investment in large units and pipeline networks, Air Liquide is the Industrial Gas leader in most of the world class Petrochemical basins (Rotterdam, Antwerp, US Gulf Coast, Yosu, Caojing,..) (orig.)

  20. Hydrogen ICE Vehicle Testing Activities

    Energy Technology Data Exchange (ETDEWEB)

    J. Francfort; D. Karner


    The Advanced Vehicle Testing Activity teamed with Electric Transportation Applications and Arizona Public Service to develop and monitor the operations of the APS Alternative Fuel (Hydrogen) Pilot Plant. The Pilot Plant provides 100% hydrogen, and hydrogen and compressed natural gas (H/CNG)-blended fuels for the evaluation of hydrogen and H/CNG internal combustion engine (ICE) vehicles in controlled and fleet testing environments. Since June 2002, twenty hydrogen and H/CNG vehicles have accumulated 300,000 test miles and 5,700 fueling events. The AVTA is part of the Department of Energy’s FreedomCAR and Vehicle Technologies Program. These testing activities are managed by the Idaho National Laboratory. This paper discusses the Pilot Plant design and monitoring, and hydrogen ICE vehicle testing methods and results.

  1. Preparation of slightly hydrogenated coal

    Energy Technology Data Exchange (ETDEWEB)

    Rank, V.


    Processes serving as producers of slightly hydrogenated coal are discussed. It was established that the working process of an extracting hydrogenation from coal alone did not present optimal conditions for production of slightly hydrogenated coal, and therefore led to unfavorably high costs. More favorable operating costs were expected with the use of larger amounts of gas or with simultaneous production of asphalt-free oils in larger quantity. The addition of coal into the hydrogenation of low temperature carbonization tars made it possible to produce additional briquetting material (slightly hydrogenated coal) in the same reaction space without impairment of the tar hydrogenation. This was to lower the cost still more. For reasons of heat exchange, the process with a cold separator was unfavorable, and consideration of the residue quality made it necessary to investigate how high the separator temperature could be raised. 3 tables.

  2. Hydrogen-enriched fuels

    Energy Technology Data Exchange (ETDEWEB)

    Roser, R. [NRG Technologies, Inc., Reno, NV (United States)


    NRG Technologies, Inc. is attempting to develop hardware and infrastructure that will allow mixtures of hydrogen and conventional fuels to become viable alternatives to conventional fuels alone. This commercialization can be successful if the authors are able to achieve exhaust emission levels of less than 0.03 g/kw-hr NOx and CO; and 0.15 g/kw-hr NMHC at full engine power without the use of exhaust catalysts. The major barriers to achieving these goals are that the lean burn regimes required to meet exhaust emissions goals reduce engine output substantially and tend to exhibit higher-than-normal total hydrocarbon emissions. Also, hydrogen addition to conventional fuels increases fuel cost, and reduces both vehicle range and engine output power. Maintaining low emissions during transient driving cycles has not been demonstrated. A three year test plan has been developed to perform the investigations into the issues described above. During this initial year of funding research has progressed in the following areas: (a) a cost effective single-cylinder research platform was constructed; (b) exhaust gas speciation was performed to characterize the nature of hydrocarbon emissions from hydrogen-enriched natural gas fuels; (c) three H{sub 2}/CH{sub 4} fuel compositions were analyzed using spark timing and equivalence ratio sweeping procedures and finally; (d) a full size pick-up truck platform was converted to run on HCNG fuels. The testing performed in year one of the three year plan represents a baseline from which to assess options for overcoming the stated barriers to success.

  3. Microbial ecology of hot desert edaphic systems. (United States)

    Makhalanyane, Thulani P; Valverde, Angel; Gunnigle, Eoin; Frossard, Aline; Ramond, Jean-Baptiste; Cowan, Don A


    A significant proportion of the Earth's surface is desert or in the process of desertification. The extreme environmental conditions that characterize these areas result in a surface that is essentially barren, with a limited range of higher plants and animals. Microbial communities are probably the dominant drivers of these systems, mediating key ecosystem processes. In this review, we examine the microbial communities of hot desert terrestrial biotopes (including soils, cryptic and refuge niches and plant-root-associated microbes) and the processes that govern their assembly. We also assess the possible effects of global climate change on hot desert microbial communities and the resulting feedback mechanisms. We conclude by discussing current gaps in our understanding of the microbiology of hot deserts and suggest fruitful avenues for future research. © FEMS 2015. All rights reserved. For permissions, please e-mail:

  4. A Case of Hot Foot Syndrome

    Directory of Open Access Journals (Sweden)

    Mutlu Çayırlı


    Full Text Available Hot foot syndrome (HFS is a benign, self-limited disorder, which is apparently caused by Pseudomonas aeruginosa infection. The disease is characterized by the acute onset in children with painful plantar nodules which generally does not require antibiotic therapy. Particularly, the mechanically stressed areas of the foot are affected after contact with contaminated water from saunas, swimming pools or hot tubs. HFS is a potentially important public health hazard that may causes outbreaks. In search of literature we detected three published reports to date of outbreaks of pseudomonas hot foot syndrome associated with the use of community whirlpools. Here we present a four-year old girl presented with painful plantar erythematous nodules localized in heels that developed one day after contacting with contaminated water from bath tub. According to data of literature we able to reach, our case is the first HFS case presented in Turkey. (Turk J Dermatol 2012; 6: 111-3

  5. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...... to the perpetuation of negative emotional states in MDD. Limited success in the identification of susceptibility genes in MDD has led to great research interest in identifying vulnerability biomarkers or endophenotypes. Emerging evidence points to the persistence of 'hot' cognition dysfunction during remission...... databases in May 2014 augmented by hand searches of reference lists. We included original articles in which MDD participants (or their healthy first-dregree relatives) and a healthy control group were compared on standard measures of emotional processing or reward/ punishment processing as well...

  6. Kepler constraints on planets near hot Jupiters. (United States)

    Steffen, Jason H; Ragozzine, Darin; Fabrycky, Daniel C; Carter, Joshua A; Ford, Eric B; Holman, Matthew J; Rowe, Jason F; Welsh, William F; Borucki, William J; Boss, Alan P; Ciardi, David R; Quinn, Samuel N


    We present the results of a search for planetary companions orbiting near hot Jupiter planet candidates (Jupiter-size candidates with orbital periods near 3 d) identified in the Kepler data through its sixth quarter of science operations. Special emphasis is given to companions between the 21 interior and exterior mean-motion resonances. A photometric transit search excludes companions with sizes ranging from roughly two-thirds to five times the size of the Earth, depending upon the noise properties of the target star. A search for dynamically induced deviations from a constant period (transit timing variations) also shows no significant signals. In contrast, comparison studies of warm Jupiters (with slightly larger orbits) and hot Neptune-size candidates do exhibit signatures of additional companions with these same tests. These differences between hot Jupiters and other planetary systems denote a distinctly different formation or dynamical history.

  7. Hot interstellar matter in elliptical galaxies

    CERN Document Server

    Kim, Dong-Woo


    Based on a number of new discoveries resulting from 10 years of Chandra and XMM-Newton observations and corresponding theoretical works, this is the first book to address significant progress in the research of the Hot Interstellar Matter in Elliptical Galaxies. A fundamental understanding of the physical properties of the hot ISM in elliptical galaxies is critical, because they are directly related to the formation and evolution of elliptical galaxies via star formation episodes, environmental effects such as stripping, infall, and mergers, and the growth of super-massive black holes. Thanks to the outstanding spatial resolution of Chandra and the large collecting area of XMM-Newton, various fine structures of the hot gas have been imaged in detail and key physical quantities have been accurately measured, allowing theoretical interpretations/predictions to be compared and tested against observational results. This book will bring all readers up-to-date on this essential field of research.

  8. Seeded hot dark matter models with inflation (United States)

    Gratsias, John; Scherrer, Robert J.; Steigman, Gary; Villumsen, Jens V.


    We examine massive neutrino (hot dark matter) models for large-scale structure in which the density perturbations are produced by randomly distributed relic seeds and by inflation. Power spectra, streaming velocities, and the Sachs-Wolfe quadrupole fluctuation are derived for this model. We find that the pure seeded hot dark matter model without inflation produces Sachs-Wolfe fluctuations far smaller than those seen by COBE. With the addition of inflationary perturbations, fluctuations consistent with COBE can be produced. The COBE results set the normalization of the inflationary component, which determines the large-scale (about 50/h Mpc) streaming velocities. The normalization of the seed power spectrum is a free parameter, which can be adjusted to obtain the desired fluctuations on small scales. The power spectra produced are very similar to those seen in mixed hot and cold dark matter models.

  9. Kepler constraints on planets near hot Jupiters

    Energy Technology Data Exchange (ETDEWEB)

    Steffen, Jason H.; /Fermilab; Ragozzine, Darin; /Harvard-Smithsonian Ctr. Astrophys.; Fabrycky, Daniel C.; /UC, Santa Cruz, Astron. Astrophys.; Carter, Joshua A.; /Harvard-Smithsonian Ctr. Astrophys.; Ford, Eric B.; /Florida U.; Holman, Matthew J.; /Harvard-Smithsonian Ctr. Astrophys.; Rowe, Jason F.; /NASA, Ames; Welsh, William F.; /San Diego State U., Astron. Dept.; Borucki, William J.; /NASA, Ames; Boss, Alan P.; /Carnegie Inst., Wash., D.C., DTM; Ciardi, David R.; /Caltech /Harvard-Smithsonian Ctr. Astrophys.


    We present the results of a search for planetary companions orbiting near hot Jupiter planet candidates (Jupiter-size candidates with orbital periods near 3 d) identified in the Kepler data through its sixth quarter of science operations. Special emphasis is given to companions between the 2:1 interior and exterior mean-motion resonances. A photometric transit search excludes companions with sizes ranging from roughly two-thirds to five times the size of the Earth, depending upon the noise properties of the target star. A search for dynamically induced deviations from a constant period (transit timing variations) also shows no significant signals. In contrast, comparison studies of warm Jupiters (with slightly larger orbits) and hot Neptune-size candidates do exhibit signatures of additional companions with these same tests. These differences between hot Jupiters and other planetary systems denote a distinctly different formation or dynamical history.

  10. Hot carrier degradation in semiconductor devices

    CERN Document Server


    This book provides readers with a variety of tools to address the challenges posed by hot carrier degradation, one of today’s most complicated reliability issues in semiconductor devices.  Coverage includes an explanation of carrier transport within devices and book-keeping of how they acquire energy (“become hot”), interaction of an ensemble of colder and hotter carriers with defect precursors, which eventually leads to the creation of a defect, and a description of how these defects interact with the device, degrading its performance. • Describes the intricacies of hot carrier degradation in modern semiconductor technologies; • Covers the entire hot carrier degradation phenomenon, including topics such as characterization, carrier transport, carrier-defect interaction, technological impact, circuit impact, etc.; • Enables detailed understanding of carrier transport, interaction of the carrier ensemble with the defect precursors, and an accurate assessment of how the newly created defects imp...

  11. Tetraphenylphosphonium hydrogen oxalate

    Directory of Open Access Journals (Sweden)

    Philip A. W. Dean


    Full Text Available In the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxylate COO planes are unusually large, viz. 72.5 (1 and 82.1 (1°.

  12. Recirculating cryogenic hydrogen maser

    Energy Technology Data Exchange (ETDEWEB)

    Huerlimann, M.D.; Hardy, W.N.; Berlinsky, A.J.; Cline, R.W.


    We report on the design and initial testing of a new type of hydrogen maser, operated at dilution refrigerator temperatures, in which H atoms circulate back and forth between a microwave-pumped state selector and the maser cavity. Other novel design features include liquid-/sup 4/He-coated walls, He-cooled electronics, and the use of microscopic magnetic particles to relax the two lowest hyperfine levels in the state selector. Stabilities at least as good as that of a Rb clock and a high-stability quartz oscillator are observed for measuring times between 1 and 300 s.

  13. Hydrogen storage development

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, G.J.; Guthrie, S.E. [Sandia National Labs., Livermore, CA (United States)


    A summary of the hydride development efforts for the current program year (FY98) are presented here. The Mg-Al-Zn alloy system was studied at low Zn levels (2--4 wt%) and midrange Al contents (40--60 wt%). Higher plateau pressures were found with Al and Zn alloying in Mg and, furthermore, it was found that the hydrogen desorption kinetics were significantly improved with small additions of Zn. Results are also shown here for a detailed study of the low temperature properties of Mg{sub 2}NiH{sub 4}, and a comparison made between conventional melt cast alloy and the vapor process material.

  14. National Hydrogen Roadmap Workshop Proceedings

    Energy Technology Data Exchange (ETDEWEB)



    This document summarizes the presentations and suggestions put forth by officials, industry experts and policymakers in their efforts to come together to develop a roadmap for America''s clean energy future and outline the key barriers and needs to achieve the hydrogen vision. The National Hydrogen Roadmap Workshop was held April 2-3, 2002. These proceedings were compiled into a formal report, The National Hydrogen Energy Roadmap, which is also available online.

  15. The Montreal hydrogen airport project

    Energy Technology Data Exchange (ETDEWEB)

    Bose, T.K. [Hydrogen Research Inst., Trois-Rivieres, Quebec (Canada)


    'Full text:' The transition to a hydrogen economy presents a unique opportunity for Canada. It spells growth and investment opportunities for Canadian industry and offers a sustainable solution to climate change and pollution, particularly in our cities. The H{sub 2}EA program set forth by the government of Canada fosters the development and early introduction into the market place in Canada of multiple hydrogen technologies that support the transition to a hydrogen economy. A group of leading suppliers, manufacturers and users of hydrogen and hydrogen compatible technologies intend to demonstrate various applications for hydrogen in the area of power generation and transportation. The project will take place at the Pierre-Elliot-Trudeau Airport in Montreal in collaboration with Aeroport de Montreal (ADM). ADM has already invested approximately $50 million in environment related initiatives and The Montreal Hydrogen Airport project will further demonstrate its leadership in this area. The project will be divided into 14 sub-projects, which are: 1. Hydrogen internal combustion engine (HICE) shuttle buses. 2. Fuel cell shuttle bus. 3. Air terminal people movers powered by H2 fuel cell technologies. 4. HICE powered tugs and luggage carts. 5. H2 fuelling station. 6. H2 filling station. 7. Mobile hydrogen auxiliary power units for ADM vehicles. 8. Stationary hydrogen auxiliary power units for airport facilities. 9. ADM truck conversion to HICE. 10. Maintenance and certification centre. 11. Project promotion. 12. Training. 13. Compliance testing and project impact analysis. 14. Project management. This project is undoubtedly ambitious and yet realistic. Set in the second largest airport in the country, it can play the double role of showcasing the Canadian hydrogen industry to the entire world while implementing the strategic elements of the hydrogen economy in the second largest population centre in Canada. (author)

  16. An integrated modular hot gas conditioning technology

    Energy Technology Data Exchange (ETDEWEB)

    Abatzoglou, N.; Bangala, D.; Chornet, E. [Kemestrie Inc., Sherbrooke, Quebec (Canada)


    Hot gas conditioning is considered the most scientific and technological challenge on the road towards commercialization of large biomass and waste gasification units. The modular hot gas conditioning system presented in this paper is designed to be integrated into any gasification unit regardless of feedstock type and operation pressure. It comprises a mobile granular bed filtration system and an in-series multi-tubular fixed-bed downdraft steam catalytic reformer. In this work we discuss the concept, the design, the methodology and our results. (author)

  17. 'Hot' cognition in major depressive disorder

    DEFF Research Database (Denmark)

    Miskowiak, Kamilla W; Carvalho, Andre F


    Major depressive disorder (MDD) is associated with significant cognitive dysfunction in both 'hot' (i.e. emotion-laden) and 'cold' (non-emotional) domains. Here we review evidence pertaining to 'hot' cognitive changes in MDD. This systematic review searched the PubMed and PsycInfo computerized...... as systematic reviews and meta-analyses. A total of 116 articles met the inclusion criteria of which 97 were original studies. Negative biases in perception, attention and memory for emotional information, and aberrant reward/punishment processing occur in MDD. Imbalanced responses to negative stimuli...

  18. Thermal tides on a hot Jupiter

    Directory of Open Access Journals (Sweden)

    Hsieh H.-F.


    Full Text Available Following the linear analysis laid out by Gu & Ogilvie 2009 (hereafter GO09, we investigate the dynamical response of a non-synchronized hot Jupiter to stellar irradiation. Besides the internal and Rossby waves considered by GO09, we study the Kelvin waves excited by the diurnal Fourier harmonic of the prograde stellar irradiation. We also present a 2-dimensional plot of internal waves excited by the semi-diurnal component of the stellar irradiation and postulate that thermal bulges may arise in a hot Jupiter. Whether our postulation is valid and is consistent with the recent results from Arras & Socrates (2009b requires further investigation.

  19. Hot-carrier effects in MOS devices

    CERN Document Server

    Takeda, Eiji; Miura-Hamada, Akemi


    The exploding number of uses for ultrafast, ultrasmall integrated circuits has increased the importance of hot-carrier effects in manufacturing as well as for other technological applications. They are rapidly movingout of the research lab and into the real world.This book is derived from Dr. Takedas book in Japanese, Hot-Carrier Effects, (published in 1987 by Nikkei Business Publishers). However, the new book is much more than a translation. Takedas original work was a starting point for developing this much more complete and fundamental text on this increasingly important topic. The new work

  20. Hot dry rock venture risks investigation:

    Energy Technology Data Exchange (ETDEWEB)


    This study assesses a promising resource in central Utah as the potential site of a future commerical hot dry rock (HDR) facility for generating electricity. The results indicate that, if the HDR reservoir productivity equals expectations based on preliminary results from research projects to date, a 50 MWe HDR power facility at Roosevelt Hot Springs could generate power at cost competitive with coal-fired plants. However, it is imperative that the assumed productivity be demonstrated before funds are committed for a commercial facility. 72 refs., 39 figs., 38 tabs.

  1. Hydrogen production costs -- A survey

    Energy Technology Data Exchange (ETDEWEB)

    Basye, L.; Swaminathan, S.


    Hydrogen, produced using renewable resources, is an environmentally benign energy carrier that will play a vital role in sustainable energy systems. The US Department of Energy (DOE) supports the development of cost-effective technologies for hydrogen production, storage, and utilization to facilitate the introduction of hydrogen in the energy infrastructure. International interest in hydrogen as an energy carrier is high. Research, development, and demonstration (RD and D) of hydrogen energy systems are in progress in many countries. Annex 11 of the International Energy Agency (IEA) facilitates member countries to collaborate on hydrogen RD and D projects. The United States is a member of Annex 11, and the US representative is the Program Manager of the DOE Hydrogen R and D Program. The Executive Committee of the Hydrogen Implementing Agreement in its June 1997 meeting decided to review the production costs of hydrogen via the currently commercially available processes. This report compiles that data. The methods of production are steam reforming, partial oxidation, gasification, pyrolysis, electrolysis, photochemical, photobiological, and photoelectrochemical reactions.

  2. Hydrogen fracture toughness tester completion

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, Michael J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)


    The Hydrogen Fracture Toughness Tester (HFTT) is a mechanical testing machine designed for conducting fracture mechanics tests on materials in high-pressure hydrogen gas. The tester is needed for evaluating the effects of hydrogen on the cracking properties of tritium reservoir materials. It consists of an Instron Model 8862 Electromechanical Test Frame; an Autoclave Engineering Pressure Vessel, an Electric Potential Drop Crack Length Measurement System, associated computer control and data acquisition systems, and a high-pressure hydrogen gas manifold and handling system.

  3. Catalyzed borohydrides for hydrogen storage (United States)

    Au, Ming [Augusta, GA


    A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

  4. Hydrogen storage in carbon nanotubes. (United States)

    Hirscher, M; Becher, M


    The article gives a comprehensive overview of hydrogen storage in carbon nanostructures, including experimental results and theoretical calculations. Soon after the discovery of carbon nanotubes in 1991, different research groups succeeded in filling carbon nanotubes with some elements, and, therefore, the question arose of filling carbon nanotubes with hydrogen by possibly using new effects such as nano-capillarity. Subsequently, very promising experiments claiming high hydrogen storage capacities in different carbon nanostructures initiated enormous research activity. Hydrogen storage capacities have been reported that exceed the benchmark for automotive application of 6.5 wt% set by the U.S. Department of Energy. However, the experimental data obtained with different methods for various carbon nanostructures show an extreme scatter. Classical calculations based on physisorption of hydrogen molecules could not explain the high storage capacities measured at ambient temperature, and, assuming chemisorption of hydrogen atoms, hydrogen release requires temperatures too high for technical applications. Up to now, only a few calculations and experiments indicate the possibility of an intermediate binding energy. Recently, serious doubt has arisen in relation to several key experiments, causing considerable controversy. Furthermore, high hydrogen storage capacities measured for carbon nanofibers did not survive cross-checking in different laboratories. Therefore, in light of today's knowledge, it is becoming less likely that at moderate pressures around room temperature carbon nanostructures can store the amount of hydrogen required for automotive applications.

  5. Regional warming of hot extremes accelerated by surface energy fluxes (United States)

    Donat, M. G.; Pitman, A. J.; Seneviratne, S. I.


    Strong regional differences exist in how hot temperature extremes increase under global warming. Using an ensemble of coupled climate models, we examine the regional warming rates of hot extremes relative to annual average warming rates in the same regions. We identify hot spots of accelerated warming of model-simulated hot extremes in Europe, North America, South America, and Southeast China. These hot spots indicate where the warm tail of a distribution of temperatures increases faster than the average and are robust across most Coupled Model Intercomparison Project Phase 5 models. Exploring the conditions on the specific day when the hot extreme occurs demonstrates that the hot spots are explained by changes in the surface energy fluxes consistent with drying soils. However, the model-simulated accelerated warming of hot extremes appears inconsistent with observations, except over Europe. The simulated acceleration of hot extremes may therefore be unreliable, a result that necessitates a reevaluation of how climate models resolve the relevant terrestrial processes.

  6. Method for Hot Real-Time Sampling of Gasification Products

    Energy Technology Data Exchange (ETDEWEB)

    Pomeroy, Marc D [National Renewable Energy Laboratory (NREL), Golden, CO (United States)


    The Thermochemical Process Development Unit (TCPDU) at the National Renewable Energy Laboratory (NREL) is a highly instrumented half-ton/day pilot scale plant capable of demonstrating industrially relevant thermochemical technologies from lignocellulosic biomass conversion, including gasification. Gasification creates primarily Syngas (a mixture of Hydrogen and Carbon Monoxide) that can be utilized with synthesis catalysts to form transportation fuels and other valuable chemicals. Biomass derived gasification products are a very complex mixture of chemical components that typically contain Sulfur and Nitrogen species that can act as catalysis poisons for tar reforming and synthesis catalysts. Real-time hot online sampling techniques, such as Molecular Beam Mass Spectrometry (MBMS), and Gas Chromatographs with Sulfur and Nitrogen specific detectors can provide real-time analysis providing operational indicators for performance. Sampling typically requires coated sampling lines to minimize trace sulfur interactions with steel surfaces. Other materials used inline have also shown conversion of sulfur species into new components and must be minimized. Sample line Residence time within the sampling lines must also be kept to a minimum to reduce further reaction chemistries. Solids from ash and char contribute to plugging and must be filtered at temperature. Experience at NREL has shown several key factors to consider when designing and installing an analytical sampling system for biomass gasification products. They include minimizing sampling distance, effective filtering as close to source as possible, proper line sizing, proper line materials or coatings, even heating of all components, minimizing pressure drops, and additional filtering or traps after pressure drops.

  7. Memorandum on coal hydrogenation

    Energy Technology Data Exchange (ETDEWEB)



    The first test facility was built in Ludwigshafen in Building 35 in 1924. During the Technical Committee meeting of February 4, 1926, Carl Bosch reported briefly for the first time on the status of coal hydrogenation and promised a comprehensive report to follow. Next, in connection with the Technical Committee meeting of July 13, 1926, Bosch arranged for the Committee to tour the test facility. Subsequently, the first industrial facility, for a yearly output of 100,000 tons, was built in Leuna with great speed and began production in April 1927. For this facility RM 26.6 million in credit was appropriated during 1926 and 1927 (the costs, including associated units, were estimated at RM 46 million; the RM 26.6 million covered only erection of the plant). A further RM 264 million was written off to hydrogenation in the years 1926 to 1931 on tests in new areas. At the end of 1929 the large scale tests at Merseburg were interrupted. On April 7, 1932, in the Nitrogen Branch discussion at Ludwigshafen, Dr. Schneider reported on the improvement in coal decomposition percentage which had meanwhile been achieved: from 60% to 95%. He proposed a last large-scale test, which was to require RM 375,000 up to the starting point and RM 170,000 per month during the six-month test period. This last test then led to definitive success in 1933.

  8. Versatile Hydrogen-Hydrogen Bond with a Difference

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 1; Issue 6. Versatile Hydrogen-Hydrogen Bond with a Difference. A G Samuelson. Research News Volume 1 Issue 6 June 1996 pp 87-89. Fulltext. Click here to view fulltext PDF. Permanent link: ...

  9. Hydrogen and fuel cells; Hydrogene et piles a combustible

    Energy Technology Data Exchange (ETDEWEB)



    This road-map proposes by the Group Total aims to inform the public on the hydrogen and fuel cells. It presents the hydrogen technology from the production to the distribution and storage, the issues as motor fuel and fuel cells, the challenge for vehicles applications and the Total commitments in the domain. (A.L.B.)

  10. Novel developments in hydrogen storage, hydrogen activation and ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Doroodian, Amir


    This dissertation is divided into three chapters. Recently, metal-free hydrogen activation using phosphorous compounds has been reported in science magazine. We have investigated the interaction between hydrogen and phosphorous compounds in presence of strong Lewis acids (chapter one). A new generation of metal-free hydrogen activation, using amines and strong Lewis acids with sterically demanding nature, was already developed in our group. Shortage of high storage capacity using large substitution to improve sterical effect led us to explore the amine borane derivatives, which are explained in chapter two. Due to the high storage capacity of hydrogen in aminoborane derivatives, we have explored these materials to extend hydrogen release. These compounds store hydrogen as proton and hydride on adjacent atoms or ions. These investigations resulted in developing hydrogen storage based on ionic liquids containing methyl guanidinium cation. Then we have continued to develop ionic liquids based on methyl guanidinium cation with different anions, such as tetrafluoro borate (chapter three). We have replaced these anions with transition metal anions to investigate hydrogen bonding and catalytic activity of ionic liquids. This chapter illustrates the world of ionic liquid as a green solvent for organic, inorganic and catalytic reactions and combines the concept of catalysts and solvents based on ionic liquids. The catalytic activity is investigated particularly with respect to the interaction with CO{sub 2}. (orig.)

  11. Hydrogen vacancies facilitate hydrogen transport kinetics in sodium hydride nanocrystallites

    NARCIS (Netherlands)

    Singh, S.; Eijt, S.W.H.


    We report ab initio calculations based on density-functional theory, of the vacancy-mediated hydrogen migration energy in bulk NaH and near the NaH(001) surface. The estimated rate of the vacancy mediated hydrogen transport, obtained within a hopping diffusion model, is consistent with the reaction

  12. Hydrogen purifier module with membrane support (United States)

    A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.


    A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.

  13. Too hot to handle? Hot water bottle injuries in Sydney, Australia. (United States)

    Goltsman, David; Li, Zhe; Bruce, Eleanor; Darton, Anne; Thornbury, Kelly; Maitz, Peter K M; Kennedy, Peter


    Hot water bottles are frequently used in the community as a source of warmth, and to alleviate a number of medical symptoms. In Australia it is believed that over 500,000 water bottles are sold annually (Whittam et al., 2010). This simple treatment is known to result in significant burns and has led to mandatory labeling requirements on hot water bottles in Australia. Despite this, few published studies have documented the incidence and nature of burns sustained through their use. This study aimed to assess the incidence, causation and outcome of hot water bottle burns presenting to a major burn trauma unit in Sydney (Australia). The New South Wales Agency for Clinical Innovation Statewide Burn Injury database and admission data to the Concord Hospital Burns Injury Unit (major treatment unit) provided information on hot water bottle burns occurring between 2005 and 2013. Demographic details, cause of burn, burn depth, total burn surface area (%TBSA), and outcome of burn were ascertained. In order to assess the burn potential of hot water bottles, a separate study examined the thermic properties of hot water bottles in 'real life' scenarios. There were 155 hot water bottle burn presentations resulting in 41 admissions and 24 grafts. The majority of patients were female, and most burns resulted from appliance rupture when used for local pain relief. Patients had an average TBSA of 2.4%. Burns patients were slightly more likely to reside in areas with greater socio-economic disadvantage. In real life scenarios, hot water bottles were shown to retain heat over 50°C for at least 3 hours (h). Hot water bottles are a source of common and preventable burns in the community, with women being more at risk than men. Hot water bottles may retain harmful levels of heat over an extended period of time. Additional labeling requirements pertaining to the longevity of hot water bottles and their use among people especially at risk of burns (i.e. children, the elderly, patients who

  14. The Norwegian hydrogen guide 2010

    Energy Technology Data Exchange (ETDEWEB)


    Hydrogen technologies are maturing at rapid speed, something we experience in Norway and around the globe every day as demonstration projects for vehicles and infrastructure expand at a rate unthinkable of only a few years ago. An example of this evolution happened in Norway in 2009 when two hydrogen filling stations were opened on May the 11th, making it possible to arrange the highly successful Viking Rally from Oslo to Stavanger with more than 40 competing teams. The Viking Rally demonstrated for the public that battery and hydrogen-electric vehicles are technologies that exist today and provide a real alternative for zero emission mobility in the future. The driving range of the generation of vehicles put into demonstration today is more than 450 km on a full hydrogen tank, comparable to conventional vehicles. As the car industry develops the next generation of vehicles for serial production within the next 4-5 years, we will see vehicles that are more robust, more reliable and cost effective. Also on the hydrogen production and distribution side progress is being made, and since renewable hydrogen from biomass and electrolysis is capable of making mobility basically emission free, hydrogen can be a key component in combating climate change and reducing local emissions. The research Council of Norway has for many years supported the development of hydrogen and fuel cell technologies, and The Research Council firmly believes that hydrogen and fuel cell technologies play a crucial role in the energy system of the future. Hydrogen is a flexible transportation fuel, and offers possibilities for storing and balancing intermittent electricity in the energy system. Norwegian companies, research organisations and universities have during the last decade developed strong capabilities in hydrogen and fuel cell technologies, capabilities it is important to further develop so that Norwegian actors can supply high class hydrogen and fuel cell technologies to global markets

  15. Hydrogen and OUr Energy Future

    Energy Technology Data Exchange (ETDEWEB)

    Rick Tidball; Stu Knoke


    In 2003, President George W. Bush announced the Hydrogen Fuel Initiative to accelerate the research and development of hydrogen, fuel cell, and infrastructure technologies that would enable hydrogen fuel cell vehicles to reach the commercial market in the 2020 timeframe. The widespread use of hydrogen can reduce our dependence on imported oil and benefit the environment by reducing greenhouse gas emissions and criteria pollutant emissions that affect our air quality. The Energy Policy Act of 2005, passed by Congress and signed into law by President Bush on August 8, 2005, reinforces Federal government support for hydrogen and fuel cell technologies. Title VIII, also called the 'Spark M. Matsunaga Hydrogen Act of 2005' authorizes more than $3.2 billion for hydrogen and fuel cell activities intended to enable the commercial introduction of hydrogen fuel cell vehicles by 2020, consistent with the Hydrogen Fuel Initiative. Numerous other titles in the Act call for related tax and market incentives, new studies, collaboration with alternative fuels and renewable energy programs, and broadened demonstrations--clearly demonstrating the strong support among members of Congress for the development and use of hydrogen fuel cell technologies. In 2006, the President announced the Advanced Energy Initiative (AEI) to accelerate research on technologies with the potential to reduce near-term oil use in the transportation sector--batteries for hybrid vehicles and cellulosic ethanol--and advance activities under the Hydrogen Fuel Initiative. The AEI also supports research to reduce the cost of electricity production technologies in the stationary sector such as clean coal, nuclear energy, solar photovoltaics, and wind energy.

  16. Hot-spot tectonics on Io (United States)

    Mcewen, A. S.


    The thesis is that extensional tectonics and low-angle detachment faults probably occur on Io in association with the hot spots. These processes may occur on a much shorter timescale on Ion than on Earth, so that Io could be a natural laboratory for the study of thermotectonics. Furthermore, studies of heat and detachment in crustal extension on Earth and the other terresrial planets (especially Venus and Mars) may provide analogs to processes on Io. The geology of Io is dominated by volcanism and hot spots, most likely the result of tidal heating. Hot spots cover 1 to 2% of Io's surface, radiating at temperatures typically from 200 to 400 K, and occasionally up to 700K. Heat loss from the largest hot spots on Io, such as Loki Patera, is about 300 times the heat loss from Yellowstone, so a tremendous quantity of energy is available for volcanic and tectonic work. Active volcanism on Io results in a resurfacing rate as high as 10 cm per year, yet many structural features are apparent on the surface. Therefore, the tectonics must be highly active.

  17. Hot flushes in breast cancer patients

    NARCIS (Netherlands)

    Mom, CH; Buijs, C; Willemse, PHB; Mourits, MJE; de Vries, EGE

    Objective : A literature search was conducted to gather information concerning the pathophysiologic mechanisms leading to hot flushes, their prevelence and severity in breast cancer patients, their influence on quality of life, and the best therapeutic option. Methods: Relevant studies in English

  18. Viscosity: From air to hot nuclei

    Indian Academy of Sciences (India)


    Oct 9, 2014 ... After a brief review of the history of viscosity from classical to quantal fluids, a discussion of how the shear viscosity of a finite hot nucleus is calculated directly from the width and energy of the giant dipole resonance (GDR) of the nucleus is given in this paper. The ratio / with s being the entropy volume ...

  19. Hot-dry-rock geothermal resource 1980

    Energy Technology Data Exchange (ETDEWEB)

    Heiken, G.; Goff, F.; Cremer, G. (ed.)


    The work performed on hot dry rock (HDR) geothermal resource evaluation, site characterization, and geophysical exploration techniques is summarized. The work was done by region (Far West, Pacific Northwest, Southwest, Rocky Mountain States, Midcontinent, and Eastern) and limited to the conterminous US.

  20. Solar-powered hot-water system (United States)

    Collins, E. R.


    Hot-water system requires no external power except solar energy. System is completely self-controlling. It includes solar-powered pump, solar-thermally and hydrothermally operated valves, and storage tank filled with open-celled foam, to maintain thermal stratification in stored water.

  1. High Temperature Chemistry at NASA: Hot Topics (United States)

    Jacobson, Nathan S.


    High Temperature issues in aircraft engines Hot section: Ni and Co based Superalloys Oxidation and Corrosion (Durability) at high temperatures. Thermal protection system (TPS) and RCC (Reinforced Carbon-Carbon) on the Space Shuttle Orbiter. High temperatures in other worlds: Planets close to their stars.

  2. Esophageal thermal injury by hot adlay tea. (United States)

    Go, Hoon; Yang, Hyeon Woong; Jung, Sung Hee; Park, Young A; Lee, Jung Yun; Kim, Sae Hee; Lim, Sin Hyung


    Reversible thermal injury to the esophagus as the result of drinking hot liquids has been reported to generate alternating white and red linear mucosal bands, somewhat reminiscent of a candy cane. This phenomenon is associated with chest pain, dysphagia, odynophagia, and epigastric pain. Here, we report a case of thermal injury to the esophageal and oral cavity due to the drinking of hot tea, including odynophagia and dysphagia. A 69-year-old man was referred due to a difficulty in swallowing which had begun a week prior to referral. The patient, at the time of admission, was unable to swallow even liquids. He had recently suffered from hiccups, and had consumed five cups of hot adlay tea one week prior to admission, as a folk remedy for the hiccups. Upon physical examination, the patient's oral cavity evidenced mucosal erosion, hyperemia, and mucosa covered by a whitish pseudomembrane. Nonspecific findings were detected on the laboratory and radiological exams. Upper endoscopy revealed diffuse hyperemia, and erosions with thick and whitish pseudomembraneous mucosa on the entire esophagus. The stomach and duodenum appeared normal. We diagnosed the patient with thermal esophageal injury inflicted by the hot tea. He was treated with pantoprazole, 40 mg/day, for 14 days, and evidenced significant clinical and endoscopic improvement.

  3. Hot topics in flavor physics at CDF

    Energy Technology Data Exchange (ETDEWEB)

    Jun, Soon Yung; /Carnegie Mellon U.


    Hot topics in flavor physics at CDF are reviewed. Selected results of top, beauty, charm physics and exotic states in about 200 pb{sup -1} data collected by the CDF II detector in p{bar p} collisions at {radical}s = 1.96 TeV at the Fermilab Tevatron are presented.

  4. Hot Flashes amd Night Sweats (PDQ) (United States)

    ... that it is only slightly better than a placebo (pill that has no effect). Most studies of soy and black cohosh show they are no better than a placebo in reducing hot flashes. Soy contains estrogen -like substances; the effect of soy on the risk of breast cancer ...

  5. Evaluation of hot in-place recycle. (United States)


    This report documents the construction of hot in-place recycled (HIPR) pavement on SR 542. : HIPR is a process by which rehabilitation of the existing HMA pavement occurs on site in one : operation. HIPR project selection, mix design, construction an...

  6. Advances in hot gas filtration technology

    Energy Technology Data Exchange (ETDEWEB)

    Weber, C.

    The past decade has seen the introduction of new filter media specifically designed for 'hot-gas' filtration. These media are available as woven or knitted fabrics and as non-wovens, i.e. needled felts. Needlefelted fabrics have proven so highly successful in the dedusting of hot gases that they are widely used nowadays in this new and necessary technology. Hot-gas filtration offers advantages in, for example, the saving or recycling of energy, the elimination of the cooling process, and the short-circuiting of process steps. This paper gives a survey of the types of textile fibres available for hot-gas filtration from the more recently developed organic fibres to refractory fibres. It describes, compares and contrasts their salient properties and lists the uses to which they may be put. It concentrates on such fibres which are generally referred to as 'high performance materials', since they are expected to provide satisfactory performance under extreme conditions of temperature, chemical environment and mechanical stress. It touches on filtration theory governing the collection mechanism. 9 refs., 7 figs., 3 tabs.

  7. Extracting hot carriers from photoexcited semiconductor nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Xiaoyang


    This research program addresses a fundamental question related to the use of nanomaterials in solar energy -- namely, whether semiconductor nanocrystals (NCs) can help surpass the efficiency limits, the so-called “Shockley-Queisser” limit, in conventional solar cells. In these cells, absorption of photons with energies above the semiconductor bandgap generates “hot” charge carriers that quickly “cool” to the band edges before they can be utilized to do work; this sets the solar cell efficiency at a limit of ~31%. If instead, all of the energy of the hot carriers could be captured, solar-to-electric power conversion efficiencies could be increased, theoretically, to as high as 66%. A potential route to capture this energy is to utilize semiconductor nanocrystals. In these materials, the quasi-continuous conduction and valence bands of the bulk semiconductor become discretized due to confinement of the charge carriers. Consequently, the energy spacing between the electronic levels can be much larger than the highest phonon frequency of the lattice, creating a “phonon bottleneck” wherein hot-carrier relaxation is possible via slower multiphonon emission. For example, hot-electron lifetimes as long as ~1 ns have been observed in NCs grown by molecular beam epitaxy. In colloidal NCs, long lifetimes have been demonstrated through careful design of the nanocrystal interfaces. Due to their ability to slow electronic relaxation, semiconductor NCs can in principle enable extraction of hot carriers before they cool to the band edges, leading to more efficient solar cells.

  8. "Hot Tub Rash" and "Swimmer's Ear" (Pseudomonas) (United States)

    ... Hot Tub Rash > Remove swimsuits and shower with soap after getting out of the water. > Clean swimsuits after getting out of the water. ... in locations that have been closed because of pollution. Pseudomonas can multiply quickly when water disinfectant levels drop, so testing your pool or ...

  9. Cycling the Hot CNO: A Teaching Methodology (United States)

    Frost-Schenk, J. W.; Diget, C. Aa.; Bentley, M. A.; Tuff, A.


    An interactive activity to teach the hot Carbon, Nitrogen and Oxygen (HCNO) cycle is proposed. Justification for why the HCNO cycle is important is included via an example of x-ray bursts. The activity allows teaching and demonstration of half-life, nuclear isotopes, nuclear reactions, protons and a-particles, and catalytic processes. Whilst the…

  10. Integrated Micro-Machined Hydrogen Gas Sensor. Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Frank DiMeo, Jr.


    This report details our recent progress in developing novel MEMS (Micro-Electro-Mechanical Systems) based hydrogen gas sensors. These sensors couple novel thin films as the active layer on a device structure known as a Micro-HotPlate. This coupling has resulted in a gas sensor that has several unique advantages in terms of speed, sensitivity, stability and amenability to large scale manufacture. This Phase-I research effort was focused on achieving the following three objectives: (1) Investigation of sensor fabrication parameters and their effects on sensor performance. (2) Hydrogen response testing of these sensors in wet/dry and oxygen-containing/oxygen-deficient atmospheres. (3) Investigation of the long-term stability of these thin film materials and identification of limiting factors. We have made substantial progress toward achieving each of these objectives, and highlights of our phase I results include the demonstration of signal responses with and without oxygen present, as well as in air with a high level of humidity. We have measured response times of <0.5 s to 1% H{sub 2} in air, and shown the ability to detect concentrations of <200 ppm. These results are extremely encouraging and suggest that this technology has substantial potential for meeting the needs of a hydrogen based economy. These achievements demonstrate the feasibility of using micro-hotplates structures in conjunction with palladium+coated metal-hydride films for sensing hydrogen in many of the environments required by a hydrogen based energy economy. Based on these findings, they propose to continue and expand the development of this technology in Phase II.

  11. Distance criterion for hydrogen bond

    Indian Academy of Sciences (India)

    First page Back Continue Last page Overview Graphics. Distance criterion for hydrogen bond. In a D-H ...A contact, the D...A distance must be less than the sum of van der Waals Radii of the D and A atoms, for it to be a hydrogen bond.

  12. Hydrogen production through biocatalyzed electrolysis

    NARCIS (Netherlands)

    Rozendal, R.A.


    cum laude graduation (with distinction) To replace fossil fuels, society is currently considering alternative clean fuels for transportation. Hydrogen could be such a fuel. In theory, large amounts of renewable hydrogen can be produced from organic contaminants in wastewater. During his PhD research

  13. Hydrogen Technology Education Workshop Proceedings

    Energy Technology Data Exchange (ETDEWEB)



    This document outlines activities for educating key target audiences, as suggested by workshop participants. Held December 4-5, 2002, the Hydrogen Technology Education Workshop kicked off a new education effort coordinated by the Hydrogen, Fuel Cells, & Infrastructure Technologies Program of the Office of Energy Efficiency and Renewable Energy.

  14. Hydrogen effects in corrosion: discussion (United States)

    Stopher, Miles A.; Simpson, E. Luke


    This session contained talks on the characterization of hydrogen-enhanced corrosion of steels and nickel-based alloys, emphasizing the different observations across length scales, from atomic-scale spectrographic to macro-scale fractographic examinations. This article is part of the themed issue 'The challenges of hydrogen and metals'.

  15. Hydrogen Production by Thermophilic Fermentation

    NARCIS (Netherlands)

    Niel, van E.W.J.; Willquist, K.; Zeidan, A.A.; Vrije, de T.; Mars, A.E.; Claassen, P.A.M.


    Of the many ways hydrogen can be produced, this chapter focuses on biological hydrogen production by thermophilic bacteria and archaea in dark fermentations. The thermophiles are held as promising candidates for a cost-effective fermentation process, because of their relatively high yields and broad

  16. Hydrogen manufacturing using plasma reformers

    Energy Technology Data Exchange (ETDEWEB)

    Bromberg, L.; Cohn, D.R.; Rabinovich, A.; Hochgreb, S.; O`Brien, C. [Massachusetts Institute of Technology, Cambridge, MA (United States)


    Manufacturing of hydrogen from hydrocarbon fuels is needed for a variety of applications. These applications include fuel cells used in stationary electric power production and in vehicular propulsion. Hydrogen can also be used for various combustion engine systems. There is a wide range of requirements on the capacity of the hydrogen manufacturing system, the purity of the hydrogen fuel, and capability for rapid response. The overall objectives of a hydrogen manufacturing facility are to operate with high availability at the lowest possible cost and to have minimal adverse environmental impact. Plasma technology has potential to significantly alleviate shortcomings of conventional means of manufacturing hydrogen. These shortcomings include cost and deterioration of catalysts; limitations on hydrogen production from heavy hydrocarbons; limitations on rapid response; and size and weight requirements. In addition, use of plasma technology could provide for a greater variety of operating modes; in particular the possibility of virtual elimination of CO{sub 2} production by pyrolytic operation. This mode of hydrogen production may be of increasing importance due to recent additional evidence of global warming.


    NARCIS (Netherlands)



    Hydrogen-vacancy interaction in tungsten was investigated by means of the perturbed angular correlation technique, using the isotope In-111 as a probe. Hydrogen trapping at an In-111-vacancy cluster manifests itself as a change of the local electric field gradient, which gives rise to an observable

  18. Performance of Existing Hydrogen Stations

    Energy Technology Data Exchange (ETDEWEB)

    Sprik, Samuel [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kurtz, Jennifer M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Ainscough, Christopher D [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Saur, Genevieve [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Peters, Michael C [National Renewable Energy Laboratory (NREL), Golden, CO (United States)


    In this presentation, the National Renewable Energy Laboratory presented aggregated analysis results on the performance of existing hydrogen stations, including performance, operation, utilization, maintenance, safety, hydrogen quality, and cost. The U.S. Department of Energy funds technology validation work at NREL through its National Fuel Cell Technology Evaluation Center (NFCTEC).

  19. Geothermal Exploration in Hot Springs, Montana

    Energy Technology Data Exchange (ETDEWEB)

    Toby McIntosh, Jackola Engineering


    The project involves drilling deeper in the Camp Aqua well dri lled in June 1982 as part of an effort to develop an ethanol plant. The purpose of the current drill ing effort is to determine if water at or above 165°F exists for the use in low temperature resource power generation. Previous geothermal resource study efforts in and around Hot Springs , MT and the Camp Aqua area (NE of Hot Springs) have been conducted through the years. A confined gravel aquifer exists in deep alluvium overlain by approximately 250 of si lt and c lay deposits from Glacial Lake Missoula. This gravel aquifer overlies a deeper bedrock aquifer. In the Camp Aqua area several wel l s exist in the gravel aquifer which receives hot water f rom bedrock fractures beneath the area. Prior to this exploration, one known well in the Camp Aqua area penetrated into the bedrock without success in intersecting fractures transporting hot geothermal water. The exploration associated with this project adds to the physical knowledge database of the Camp Aqua area. The dri l l ing effort provides additional subsurface information that can be used to gain a better understanding of the bedrock formation that i s leaking hot geothermal water into an otherwise cold water aquifer. The exi s t ing well used for the explorat ion is located within the center of the hottest water within the gravel aquifer. This lent i t sel f as a logical and economical location to continue the exploration within the existing well. Faced with budget constraints due to unanticipated costs, changing dril l ing techniques stretched the limited project resources to maximize the overa l l well depth which f e l l short of original project goals. The project goal of finding 165°F or hotter water was not achieved; however the project provides additional information and understanding of the Camp Aqua area that could prove valuable in future exploration efforts

  20. Suprathermal oxygen atoms in the Martian upper atmosphere: Contribution of the proton and hydrogen atom precipitation (United States)

    Shematovich, V. I.


    This is a study of the kinetics and transport of hot oxygen atoms in the transition region (from the thermosphere to the exosphere) of the Martian upper atmosphere. It is assumed that the source of the hot oxygen atoms is the transfer of momentum and energy in elastic collisions between thermal atmospheric oxygen atoms and the high-energy protons and hydrogen atoms precipitating onto the Martian upper atmosphere from the solar-wind plasma. The distribution functions of suprathermal oxygen atoms by the kinetic energy are calculated. It is shown that the exosphere is populated by a large number of suprathermal oxygen atoms with kinetic energies up to the escape energy 2 eV; i.e., a hot oxygen corona is formed around Mars. The transfer of energy from the precipitating solar-wind plasma protons and hydrogen atoms to the thermal oxygen atoms leads to the formation of an additional nonthermal escape flux of atomic oxygen from the Martian atmosphere. The precipitation-induced escape flux of hot oxygen atoms may become dominant under the conditions of extreme solar events, such as solar flares and coronal mass ejections, as shown by recent observations onboard NASA's MAVEN spacecraft (Jakosky et al., 2015).

  1. Advanced Hydrogen Turbine Development

    Energy Technology Data Exchange (ETDEWEB)

    Marra, John [Siemens Energy, Inc., Orlando, FL (United States)


    Under the sponsorship of the U.S. Department of Energy (DOE) National Energy Technology Laboratories, Siemens has completed the Advanced Hydrogen Turbine Development Program to develop an advanced gas turbine for incorporation into future coal-based Integrated Gasification Combined Cycle (IGCC) plants. All the scheduled DOE Milestones were completed and significant technical progress was made in the development of new technologies and concepts. Advanced computer simulations and modeling, as well as subscale, full scale laboratory, rig and engine testing were utilized to evaluate and select concepts for further development. Program Requirements of: A 3 to 5 percentage point improvement in overall plant combined cycle efficiency when compared to the reference baseline plant; 20 to 30 percent reduction in overall plant capital cost when compared to the reference baseline plant; and NOx emissions of 2 PPM out of the stack. were all met. The program was completed on schedule and within the allotted budget

  2. Hydrogen in semiconductors II

    CERN Document Server

    Nickel, Norbert H; Weber, Eicke R; Nickel, Norbert H


    Since its inception in 1966, the series of numbered volumes known as Semiconductors and Semimetals has distinguished itself through the careful selection of well-known authors, editors, and contributors. The "Willardson and Beer" Series, as it is widely known, has succeeded in publishing numerous landmark volumes and chapters. Not only did many of these volumes make an impact at the time of their publication, but they continue to be well-cited years after their original release. Recently, Professor Eicke R. Weber of the University of California at Berkeley joined as a co-editor of the series. Professor Weber, a well-known expert in the field of semiconductor materials, will further contribute to continuing the series' tradition of publishing timely, highly relevant, and long-impacting volumes. Some of the recent volumes, such as Hydrogen in Semiconductors, Imperfections in III/V Materials, Epitaxial Microstructures, High-Speed Heterostructure Devices, Oxygen in Silicon, and others promise that this tradition ...

  3. Metallization of fluid hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Nellis, W.J.; Louis, A.A.; Ashcroft, N.W.


    The electrical activity of liquid hydrogen has been measured at the high dynamic pressures, and temperatures that can be achieved with a reverberating shock wave. The resulting data are most naturally interpreted in terms of a continuous transition from a semiconducting to a metallic, largely diatomic fluid, the latter at 140 CPa, (ninefold compression) and 3000 K. While the fluid at these conditions resembles common liquid metals by the scale of its resistivity of 500 micro-ohm-cm, it differs by retaining a strong pairing character, and the precise mechanism by which a metallic state might be attained is still a matter of debate. Some evident possibilities include (i) physics of a largely one-body character, such as a band-overlap transition, (ii) physics of a strong-coupling or many-body character,such as a Mott-Hubbard transition, and (iii) process in which structural changes are paramount.

  4. Sampling the Hydrogen Atom

    Directory of Open Access Journals (Sweden)

    Graves N.


    Full Text Available A model is proposed for the hydrogen atom in which the electron is an objectively real particle orbiting at very near to light speed. The model is based on the postulate that certain velocity terms associated with orbiting bodies can be considered as being af- fected by relativity. This leads to a model for the atom in which the stable electron orbits are associated with orbital velocities where Gamma is n /α , leading to the idea that it is Gamma that is quantized and not angular momentum as in the Bohr and other models. The model provides a mechanism which leads to quantization of energy levels within the atom and also provides a simple mechanical explanation for the Fine Struc- ture Constant. The mechanism is closely associated with the Sampling theorem and the related phenomenon of aliasing developed in the mid-20th century by engineers at Bell labs.

  5. Magnetic refrigerator for hydrogen liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, K; Kondo, T [Department of Physics, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan); Yoshioka, S; Kamiya, K; Numazawa, T [Tsukuba Magnet Laboratory, National Institute for Materials Science, 3-13 Sakura, Tsukuba 305-0003 (Japan)], E-mail:


    Magnetic refrigeration which is based on the magnetocaloric effect of solids has the potential to achieve high thermal efficiency for hydrogen liquefaction. We have been developing a magnetic refrigerator for hydrogen liquefaction which cools down hydrogen gas from liquid natural gas temperature and liquefies at 20 K. The magnetic liquefaction system consists of two magnetic refrigerators: Carnot magnetic refrigerator (CMR) and active magnetic regenerator (AMR) device. CMR with Carnot cycle succeeded in liquefying hydrogen at 20K. Above liquefaction temperature, a regenerative refrigeration cycle should be necessary to precool hydrogen gas, because adiabatic temperature change of magnetic material is reduced due to a large lattice specific heat of magnetic materials. We have tested an AMR device as the precooling stage. It was confirmed for the first time that AMR cycle worked around 20 K.

  6. Hydrogen production from solar energy (United States)

    Eisenstadt, M. M.; Cox, K. E.


    Three alternatives for hydrogen production from solar energy have been analyzed on both efficiency and economic grounds. The analysis shows that the alternative using solar energy followed by thermochemical decomposition of water to produce hydrogen is the optimum one. The other schemes considered were the direct conversion of solar energy to electricity by silicon cells and water electrolysis, and the use of solar energy to power a vapor cycle followed by electrical generation and electrolysis. The capital cost of hydrogen via the thermochemical alternative was estimated at $575/kW of hydrogen output or $3.15/million Btu. Although this cost appears high when compared with hydrogen from other primary energy sources or from fossil fuel, environmental and social costs which favor solar energy may prove this scheme feasible in the future.

  7. WESF hot cells waste minimization criteria hot cells window seals evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Walterskirchen, K.M.


    WESF will decouple from B Plant in the near future. WESF is attempting to minimize the contaminated solid waste in their hot cells and utilize B Plant to receive the waste before decoupling. WESF wishes to determine the minimum amount of contaminated waste that must be removed in order to allow minimum maintenance of the hot cells when they are placed in ''laid-up'' configuration. The remaining waste should not cause unacceptable window seal deterioration for the remaining life of the hot cells. This report investigates and analyzes the seal conditions and hot cell history and concludes that WESF should remove existing point sources, replace cerium window seals in F-Cell and refurbish all leaded windows (except for A-Cell). Work should be accomplished as soon as possible and at least within the next three years.

  8. Hot-Carrier Seebeck Effect: Diffusion and Remote Detection of Hot Carriers in Graphene. (United States)

    Sierra, Juan F; Neumann, Ingmar; Costache, Marius V; Valenzuela, Sergio O


    We investigate hot carrier propagation across graphene using an electrical nonlocal injection/detection method. The device consists of a monolayer graphene flake contacted by multiple metal leads. Using two remote leads for electrical heating, we generate a carrier temperature gradient that results in a measurable thermoelectric voltage V(NL) across the remaining (detector) leads. Due to the nonlocal character of the measurement, V(NL) is exclusively due to the Seebeck effect. Remarkably, a departure from the ordinary relationship between Joule power P and V(NL), V(NL) ∼ P, becomes readily apparent at low temperatures, representing a fingerprint of hot-carrier dominated thermoelectricity. By studying V(NL) as a function of bias, we directly determine the carrier temperature and the characteristic cooling length for hot-carrier propagation, which are key parameters for a variety of new applications that rely on hot-carrier transport.

  9. Laboratory spectra of hot molecules: Data needs for hot super-Earth exoplanets (United States)

    Tennyson, Jonathan; Yurchenko, Sergei N.


    The majority of stars are now thought to support exoplanets. Many of those exoplanets discovered thus far are categorized as rocky objects with an atmosphere. Most of these objects are however hot due to their short orbital period. Models suggest that water is the dominant species in their atmospheres. The hot temperatures are expected to turn these atmospheres into a (high pressure) steam bath containing remains of melted rock. The spectroscopy of these hot rocky objects will be very different from that of cooler objects or hot gas giants. Molecules suggested to be important for the spectroscopy of these objects are reviewed together with the current status of the corresponding spectroscopic data. Perspectives of building a comprehensive database of linelist/cross sections applicable for atmospheric models of rocky super-Earths as part of the ExoMol project are discussed. The quantum-mechanical approaches used in linelist productions and their challenges are summarized.

  10. High capacity hydrogen storage nanocomposite materials

    Energy Technology Data Exchange (ETDEWEB)

    Zidan, Ragaiy; Wellons, Matthew S.


    A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about C.

  11. Storage of liquid hydrogen in natural zeolite

    National Research Council Canada - National Science Library

    Pavol Rybár; Carsten Drebenstedt; Mário Molokáč; Ladislav Hvizdák; Ľubomír Štrba


    .... Therefore, the storage of hydrogen is relatively dangerous. A storage of liquid hydrogen in the natural zeolite, which is placed in large capacity battery, appears to be a suitable hydrogen storage method...

  12. High capacity hydrogen storage nanocomposite materials (United States)

    Zidan, Ragaiy; Wellons, Matthew S


    A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about C.

  13. Hydrogen sulfide intoxication. (United States)

    Guidotti, Tee L


    Hydrogen sulfide (H2S) is a hazard primarily in the oil and gas industry, agriculture, sewage and animal waste handling, construction (asphalt operations and disturbing marshy terrain), and other settings where organic material decomposes under reducing conditions, and in geothermal operations. It is an insoluble gas, heavier than air, with a very low odor threshold and high toxicity, driven by concentration more than duration of exposure. Toxicity presents in a unique, reliable, and characteristic toxidrome consisting, in ascending order of exposure, of mucosal irritation, especially of the eye ("gas eye"), olfactory paralysis (not to be confused with olfactory fatigue), sudden but reversible loss of consciousness ("knockdown"), pulmonary edema (with an unusually favorable prognosis), and death (probably with apnea contributing). The risk of chronic neurcognitive changes is controversial, with the best evidence at high exposure levels and after knockdowns, which are frequently accompanied by head injury or oxygen deprivation. Treatment cannot be initiated promptly in the prehospital phase, and currently rests primarily on supportive care, hyperbaric oxygen, and nitrite administration. The mechanism of action for sublethal neurotoxicity and knockdown is clearly not inhibition of cytochrome oxidase c, as generally assumed, although this may play a role in overwhelming exposures. High levels of endogenous sulfide are found in the brain, presumably relating to the function of hydrogen sulfide as a gaseous neurotransmitter and immunomodulator. Prevention requires control of exposure and rigorous training to stop doomed rescue attempts attempted without self-contained breathing apparatus, especially in confined spaces, and in sudden release in the oil and gas sector, which result in multiple avoidable deaths. © 2015 Elsevier B.V. All rights reserved.

  14. Advanced Hydrogen Turbine Development

    Energy Technology Data Exchange (ETDEWEB)

    Joesph Fadok


    Siemens has developed a roadmap to achieve the DOE goals for efficiency, cost reduction, and emissions through innovative approaches and novel technologies which build upon worldwide IGCC operational experience, platform technology, and extensive experience in G-class operating conditions. In Phase 1, the technologies and concepts necessary to achieve the program goals were identified for the gas turbine components and supporting technology areas and testing plans were developed to mitigate identified risks. Multiple studies were conducted to evaluate the impact in plant performance of different gas turbine and plant technologies. 2015 gas turbine technologies showed a significant improvement in IGCC plant efficiency, however, a severe performance penalty was calculated for high carbon capture cases. Thermodynamic calculations showed that the DOE 2010 and 2015 efficiency targets can be met with a two step approach. A risk management process was instituted in Phase 1 to identify risk and develop mitigation plans. For the risks identified, testing and development programs are in place and the risks will be revisited periodically to determine if changes to the plan are necessary. A compressor performance prediction has shown that the design of the compressor for the engine can be achieved with additional stages added to the rear of the compressor. Tip clearance effects were studied as well as a range of flow and pressure ratios to evaluate the impacts to both performance and stability. Considerable data was obtained on the four candidate combustion systems: diffusion, catalytic, premix, and distributed combustion. Based on the results of Phase 1, the premixed combustion system and the distributed combustion system were chosen as having the most potential and will be the focus of Phase 2 of the program. Significant progress was also made in obtaining combustion kinetics data for high hydrogen fuels. The Phase 1 turbine studies indicate initial feasibility of the

  15. Liquid hydrogen: back to basics

    Energy Technology Data Exchange (ETDEWEB)

    Sherif, S.A. [Dept. of Mechanical and Aerospace Engineering, Univ. of Florida, Florida (United States)


    'Full text': Liquid hydrogen is primarily used as a rocket fuel and is predestined for supersonic and hypersonic space vehicles to a large extent because it has the lowest boiling point density and the highest specific thrust of any known fuel. Its favorable characteristics include its high heating value per unit mass, its wide ignition range in hydrogen/oxygen or air mixtures, as well as its large flame speed and cooling capacity due to its high specific heat which permits very effective engine cooling and cooling the critical parts of the outer skin. Liquid hydrogen has some other important uses such as in high-energy nuclear physics and bubble chambers. The transport of hydrogen is vastly more economical when it is in liquid form even though cryogenic refrigeration and special Dewar vessels are required. Although liquid hydrogen can provide a lot of advantages, its uses are restricted in part because liquefying hydrogen by existing conventional methods consumes a large amount of energy (around 30% of its heating value). Liquefying 1 kg of hydrogen in a medium-size plant requires 10 to 13 kWh of electric energy. In addition, boil-off losses associated with the storage, transportation, and handling of liquid hydrogen can consume up to 40% of its available combustion energy. It is therefore important to search for ways that can improve the efficiency of the liquefiers and diminish the boil-off losses. This lecture gives an overview of the main issues associated with the production, storage, and handling of liquid hydrogen. Some discussion of promising ways of hydrogen liquefaction will also be presented. (author)

  16. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... Share this! Home » Health Tips » Holiday and Seasonal Children in Hot Cars Result in Fatal Consequences Emergency ... the overwhelming dangers associated with leaving anyone, especially children in hot, unventilated vehicles during the summer. Children ...

  17. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... hot outside for it to be brutally hot inside the car. Be especially careful if you are ... act like a greenhouse, trapping sunlight and heat inside with no ventilation. A car parked in direct ...

  18. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... of Emergency Phycisians Toggle navigation Emergency 101 Is it an Emergency? Emergency Care or Urgent Care? When ... being left alone in a hot vehicle. “Putting it bluntly, leaving your child in a hot car ...

  19. Cancer treatment: dealing with hot flashes and night sweats (United States)

    ... Cancer treatment: dealing with hot flashes and night sweats To use ... stress reduction. Learning how to decrease stress and anxiety may help relieve hot flashes in some people. ...

  20. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... Health Tips » Holiday and Seasonal Children in Hot Cars Result in Fatal Consequences Emergency physicians are warning ... it bluntly, leaving your child in a hot car is like leaving your child in a lit ...

  1. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... each year as a direct result of being left alone in a hot vehicle. “Putting it bluntly, ... reach from children. If you see a child left alone in a hot vehicle, call the police. ...

  2. Children in Hot Cars Result in Fatal Consequences

    Medline Plus

    Full Text Available ... Tips » Holiday and Seasonal Children in Hot Cars Result in Fatal Consequences Emergency physicians are warning the ... the country die each year as a direct result of being left alone in a hot vehicle. “ ...

  3. Storage of liquid hydrogen in natural zeolite


    Pavol Rybár; Carsten Drebenstedt; Mário Molokáč; Ladislav Hvizdák; Ľubomír Štrba


    When producing and utilizing hydrogen, its storage is one of the biggest problems. Hydrogen, as a gas, is extremely fluid with very low specific weight. Moreover, at a certain rate, the hydrogen-oxygen mixture is explosive. Therefore, the storage of hydrogen is relatively dangerous. A storage of liquid hydrogen in the natural zeolite, which is placed in large capacity battery, appears to be a suitable hydrogen storage method. Proposed and constructed pressure tank, large cap...

  4. Hot-Film and Hot-Wire Anemometry for a Boundary Layer Active Flow Control Test (United States)

    Lenahan, Keven C.; Schatzman, David M.; Wilson, Jacob Samuel


    Unsteady active flow control (AFC) has been used experimentally for many years to minimize bluff-body drag. This technology could significantly improve performance of rotorcraft by cleaning up flow separation. It is important, then, that new actuator technologies be studied for application to future vehicles. A boundary layer wind tunnel was constructed with a 1ft-x-3ft test section and unsteady measurement instrumentation to study how AFC manipulates the boundary layer to overcome adverse pressure gradients and flow separation. This unsteady flow control research requires unsteady measurement methods. In order to measure the boundary layer characteristics, both hot-wire and hot-film Constant Temperature Anemometry is used. A hot-wire probe is mounted in the flow to measure velocity while a hot-film array lays on the test surface to measure skin friction. Hot-film sensors are connected to an anemometer, a Wheatstone bridge circuit with an output that corresponds to the dynamic flow response. From this output, the time varying flow field, turbulence, and flow reversal can be characterized. Tuning the anemometers requires a fan test on the hot-film sensors to adjust each output. This is a delicate process as several variables drastically affect the data, including control resistance, signal input, trim, and gain settings.

  5. Hydrogen storage in nanostructured materials

    Energy Technology Data Exchange (ETDEWEB)

    Assfour, Bassem


    Hydrogen is an appealing energy carrier for clean energy use. However, storage of hydrogen is still the main bottleneck for the realization of an energy economy based on hydrogen. Many materials with outstanding properties have been synthesized with the aim to store enough amount of hydrogen under ambient conditions. Such efforts need guidance from material science, which includes predictive theoretical tools. Carbon nanotubes were considered as promising candidates for hydrogen storage applications, but later on it was found to be unable to store enough amounts of hydrogen under ambient conditions. New arrangements of carbon nanotubes were constructed and hydrogen sorption properties were investigated using state-of-the-art simulation methods. The simulations indicate outstanding total hydrogen uptake (up to 19.0 wt.% at 77 K and 5.52wt.% at 300 K), which makes these materials excellent candidates for storage applications. This reopens the carbon route to superior materials for a hydrogen-based economy. Zeolite imidazolate frameworks are subclass of MOFs with an exceptional chemical and thermal stability. The hydrogen adsorption in ZIFs was investigated as a function of network geometry and organic linker exchange. Ab initio calculations performed at the MP2 level to obtain correct interaction energies between hydrogen molecules and the ZIF framework. Subsequently, GCMC simulations are carried out to obtain the hydrogen uptake of ZIFs at different thermodynamic conditions. The best of these materials (ZIF-8) is found to be able to store up to 5 wt.% at 77 K and high pressure. We expected possible improvement of hydrogen capacity of ZIFs by substituting the metal atom (Zn{sup 2+}) in the structure by lighter elements such as B or Li. Therefore, we investigated the energy landscape of LiB(IM)4 polymorphs in detail and analyzed their hydrogen storage capacities. The structure with the fau topology was shown to be one of the best materials for hydrogen storage. Its

  6. High efficiency stationary hydrogen storage

    Energy Technology Data Exchange (ETDEWEB)

    Hynek, S.; Fuller, W.; Truslow, S. [Arthur D. Little, Inc., Cambridge, MA (United States)


    Stationary storage of hydrogen permits one to make hydrogen now and use it later. With stationary hydrogen storage, one can use excess electrical generation capacity to power an electrolyzer, and store the resultant hydrogen for later use or transshipment. One can also use stationary hydrogen as a buffer at fueling stations to accommodate non-steady fueling demand, thus permitting the hydrogen supply system (e.g., methane reformer or electrolyzer) to be sized to meet the average, rather than the peak, demand. We at ADL designed, built, and tested a stationary hydrogen storage device that thermally couples a high-temperature metal hydride to a phase change material (PCM). The PCM captures and stores the heat of the hydriding reaction as its own heat of fusion (that is, it melts), and subsequently returns that heat of fusion (by freezing) to facilitate the dehydriding reaction. A key component of this stationary hydrogen storage device is the metal hydride itself. We used nickel-coated magnesium powder (NCMP) - magnesium particles coated with a thin layer of nickel by means of chemical vapor deposition (CVD). Magnesium hydride can store a higher weight fraction of hydrogen than any other practical metal hydride, and it is less expensive than any other metal hydride. We designed and constructed an experimental NCM/PCM reactor out of 310 stainless steel in the form of a shell-and-tube heat exchanger, with the tube side packed with NCMP and the shell side filled with a eutectic mixture of NaCL, KCl, and MgCl{sub 2}. Our experimental results indicate that with proper attention to limiting thermal losses, our overall efficiency will exceed 90% (DOE goal: >75%) and our overall system cost will be only 33% (DOE goal: <50%) of the value of the delivered hydrogen. It appears that NCMP can be used to purify hydrogen streams and store hydrogen at the same time. These prospects make the NCMP/PCM reactor an attractive component in a reformer-based hydrogen fueling station.

  7. 21 CFR 880.6085 - Hot/cold water bottle. (United States)


    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Hot/cold water bottle. 880.6085 Section 880.6085... Devices § 880.6085 Hot/cold water bottle. (a) Identification. A hot/cold water bottle is a device intended for medical purposes that is in the form of a container intended to be filled with hot or cold water...

  8. Venlafaxine hydrochloride for the treatment of hot flashes. (United States)

    Schober, Christina E; Ansani, Nicole T


    To review the literature evaluating venlafaxine for the treatment of hot flashes. Clinical literature accessed through MEDLINE (1966-August 2002), PubMed, Harrison's Online, and references of reviewed articles. Key terms used were venlafaxine, Effexor, hot flashes, and vasomotor symptoms. Not all patients experiencing hot flashes are candidates for traditional hormonal therapy. Nonhormonal alternatives have long been explored, but conflicting evidence of efficacy exists. Venlafaxine is an effective nonhormonal alternative for relief from uncontrolled hot flashes.

  9. Investigation of Usibor 1500 Formability in a Hot Forming Operation


    Güler, Hande


    The hot forming process included heating metals to a temperature in the austenite range, transferring the austenitized sheet from the furnace to a press, forming and simultaneously quenched. In this work, Usibor 1500 steel was hot stamped using water-cooled prototype mould. Micro structural analyses as well as tensile tests and hardness measurements of hot stamped samples were performed. The results showed that most of austenite microstructure was changed into martensite by the hot forming. T...

  10. Hydrogen-Based Energy Conservation System Project (United States)

    National Aeronautics and Space Administration — Sustainable Innovations is developing a technology for efficient separation and compression of hydrogen gas. The electrochemical hydrogen separator and compressor...

  11. Composition and method for hydrogen storage (United States)

    Mao, Wendy L. (Inventor); Mao, Ho-Kwang (Inventor)


    A method for hydrogen storage includes providing water and hydrogen gas to a containment volume, reducing the temperature of the water and hydrogen gas to form a hydrogen clathrate at a first cryogenic temperature and a first pressure and maintaining the hydrogen clathrate at second cryogenic temperature within a temperature range of up to 250 K to effect hydrogen storage. The low-pressure hydrogen hydrate includes H.sub.2 O molecules, H.sub.2 molecules and a unit cell including polyhedron cages of hydrogen-bonded frameworks of the H.sub.2 O molecules built around the H.sub.2 molecules.

  12. New instability strip for hot degenerates

    Energy Technology Data Exchange (ETDEWEB)

    Starrfield, S.G.; Cox, A.N.; Hodson, S.W.


    A new kind of variable star, designated as PG1159-035 is distinguished not only by the complete lack of hydrogen in its spectrum but also by an effective temperature that exceeds 8 x 10/sup 4/ K. The star does not fall near any of the known regions of instability in the HR diagram which suggests that the instability mechanism will not be helium and hydrogen ionization as in the Cepheid variables. The more unusual compositions are examined in order to discover the cause of the instability in PG1159-035. (GHT)

  13. Hot Electron Injection into Uniaxially Strained Silicon (United States)

    Kim, Hyun Soo

    In semiconductor spintronics, silicon attracts great attention due to the long electron spin lifetime. Silicon is also one of the most commonly used semiconductor in microelectronics industry. The spin relaxation process of diamond crystal structure such as silicon is dominant by Elliot-Yafet mechanism. Yafet shows that intravalley scattering process is dominant. The conduction electron spin lifetime measured by electron spin resonance measurement and electronic measurement using ballistic hot electron method well agrees with Yafet's theory. However, the recent theory predicts a strong contribution of intervalley scattering process such as f-process in silicon. The conduction band minimum is close the Brillouin zone edge, X point which causes strong spin mixing at the conduction band. A recent experiment of electric field-induced hot electron spin relaxation also shows the strong effect of f-process in silicon. In uniaxially strained silicon along crystal axis [100], the suppression of f-process is predicted which leads to enhance electron spin lifetime. By inducing a change in crystal structure due to uniaxial strain, the six fold degeneracy becomes two fold degeneracy, which is valley splitting. As the valley splitting increases, intervalley scattering is reduced. A recent theory predicts 4 times longer electron spin lifetime in 0.5% uniaxially strained silicon. In this thesis, we demonstrate ballistic hot electron injection into silicon under various uniaxial strain. Spin polarized hot electron injection under strain is experimentally one of the most challenging part to measure conduction electron spin lifetime in silicon. Hot electron injection adopts tunnel junction which is a thin oxide layer between two conducting materials. Tunnel barrier, which is an oxide layer, is only 4 ˜ 5 nm thick. Also, two conducting materials are only tens of nanometer. Therefore, under high pressure to apply 0.5% strain on silicon, thin films on silicon substrate can be easily

  14. Directly calculating electrical conductivities of dense hydrogen from molecular dynamics (United States)

    Ma, Qian; Kang, Dongdong; Dai, Jiayu


    The transport properties are important in warm and hot dense matter in which the Coulomb interaction is dominated in the scattering process. Density functional theory (DFT) is considered as an effective method to investigate the transport properties, but the dynamical collisions between particles are missed. Here we use an electron force field (eFF) method based molecular dynamics (MD) to include the electronic quantum effects to investigate the transport properties of warm dense hydrogen. The eFF method can be regarded as the development of wave packets molecular dynamics and it has been successfully used to describe the thermodynamics of hydrogen, Auger process in diamondoids, the equation of states for dense lithium. The most important point of eFF method is assuming that each electron is considered as a Gaussian wave packet controlled by position and size while ions are still charged points. The electrical conductivity is calculated via the correlation of electrical current. The results show that electronic quantum effects are important for the transport properties in warm dense hydrogen such as diffusion coefficient and electrical conductivity, which are much smaller than the results from DFT calculations.

  15. 7 CFR 305.22 - Hot water immersion treatment schedules. (United States)


    ... 7 Agriculture 5 2010-01-01 2010-01-01 false Hot water immersion treatment schedules. 305.22... Hot water immersion treatment schedules. (a) T102-d. (1) Fruit must be grown and treated in Hawaii. (2) Fruit must be submerged at least 4 inches below the water's surface in a hot water immersion treatment...

  16. 29 CFR 1915.503 - Precautions for hot work. (United States)


    ... 29 Labor 7 2010-07-01 2010-07-01 false Precautions for hot work. 1915.503 Section 1915.503 Labor... Employment § 1915.503 Precautions for hot work. (a) General requirements—(1) Designated Areas. The employer may designate areas for hot work in sites such as vessels, vessel sections, fabricating shops, and...

  17. Hot Pepper Reaction to Field Diseases | Nsabiyera | African Crop ...

    African Journals Online (AJOL)

    Diseases are major constraints to hot pepper (Capsicum annum L.) production in sub-Saharan Africa. The search for cultivars resistant to the major diseases of hot pepper has been limited. This study was conducted in Uganda to evaluate exotic and local hot pepper genotypes for disease resistance. Viral diseases and ...

  18. Hydrogen-storing hydride complexes (United States)

    Srinivasan, Sesha S [Tampa, FL; Niemann, Michael U [Venice, FL; Goswami, D Yogi [Tampa, FL; Stefanakos, Elias K [Tampa, FL


    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around C. and the other around C., with the main hydrogen release temperature reduced from C. to C., while hydrogen is first reversibly released at temperatures as low as C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  19. Extensive analysis of hydrogen costs

    Energy Technology Data Exchange (ETDEWEB)

    Guinea, D.M.; Martin, D.; Garcia-Alegre, M.C.; Guinea, D. [Consejo Superior de Investigaciones Cientificas, Arganda, Madrid (Spain). Inst. de Automatica Industrial; Agila, W.E. [Acciona Infraestructuras, Alcobendas, Madrid (Spain). Dept. I+D+i


    Cost is a key issue in the spreading of any technology. In this work, the cost of hydrogen is analyzed and determined, for hydrogen obtained by electrolysis. Different contributing partial costs are taken into account to calculate the hydrogen final cost, such as energy and electrolyzers taxes. Energy cost data is taken from official URLs, while electrolyzer costs are obtained from commercial companies. The analysis is accomplished under different hypothesis, and for different countries: Germany, France, Austria, Switzerland, Spain and the Canadian region of Ontario. Finally, the obtained costs are compared to those of the most used fossil fuels, both in the automotive industry (gasoline and diesel) and in the residential sector (butane, coal, town gas and wood), and the possibilities of hydrogen competing against fuels are discussed. According to this work, in the automotive industry, even neglecting subsidies, hydrogen can compete with fossil fuels. Hydrogen can also compete with gaseous domestic fuels. Electrolyzer prices were found to have the highest influence on hydrogen prices. (orig.)

  20. Technical Analysis of Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Ali T-Raissi


    The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

  1. Nanoporous polymers for hydrogen storage. (United States)

    Germain, Jonathan; Fréchet, Jean M J; Svec, Frantisek


    The design of hydrogen storage materials is one of the principal challenges that must be met before the development of a hydrogen economy. While hydrogen has a large specific energy, its volumetric energy density is so low as to require development of materials that can store and release it when needed. While much of the research on hydrogen storage focuses on metal hydrides, these materials are currently limited by slow kinetics and energy inefficiency. Nanostructured materials with high surface areas are actively being developed as another option. These materials avoid some of the kinetic and thermodynamic drawbacks of metal hydrides and other reactive methods of storing hydrogen. In this work, progress towards hydrogen storage with nanoporous materials in general and porous organic polymers in particular is critically reviewed. Mechanisms of formation for crosslinked polymers, hypercrosslinked polymers, polymers of intrinsic microporosity, and covalent organic frameworks are discussed. Strategies for controlling hydrogen storage capacity and adsorption enthalpy via manipulation of surface area, pore size, and pore volume are discussed in detail.

  2. Solar hydrogen for urban trucks

    Energy Technology Data Exchange (ETDEWEB)

    Provenzano, J.: Scott, P.B.; Zweig, R. [Clean Air Now, Northridge, CA (United States)


    The Clean Air Now (CAN) Solar Hydrogen Project, located at Xerox Corp., El Segundo, California, includes solar photovoltaic powered hydrogen generation, compression, storage and end use. Three modified Ford Ranger trucks use the hydrogen fuel. The stand-alone electrolyzer and hydrogen dispensing system are solely powered by a photovoltaic array. A variable frequency DC-AC converter steps up the voltage to drive the 15 horsepower compressor motor. On site storage is available for up to 14,000 standard cubic feet (SCF) of solar hydrogen, and up to 80,000 SCF of commercial hydrogen. The project is 3 miles from Los Angeles International airport. The engine conversions are bored to 2.9 liter displacement and are supercharged. Performance is similar to that of the Ranger gasoline powered truck. Fuel is stored in carbon composite tanks (just behind the driver`s cab) at pressures up to 3600 psi. Truck range is 144 miles, given 3600 psi of hydrogen. The engine operates in lean burn mode, with nil CO and HC emissions. NO{sub x} emissions vary with load and rpm in the range from 10 to 100 ppm, yielding total emissions at a small fraction of the ULEV standard. Two trucks have been converted for the Xerox fleet, and one for the City of West Hollywood. A public outreach program, done in conjunction with the local public schools and the Department of Energy, introduces the local public to the advantages of hydrogen fuel technologies. The Clean Air Now program demonstrates that hydrogen powered fleet development is an appropriate, safe, and effective strategy for improvement of urban air quality, energy security and avoidance of global warming impact. Continued technology development and cost reduction promises to make such implementation market competitive.

  3. Hydrogenation of zirconium film by implantation of hydrogen ions (United States)

    Liu, Yang; Fang, Kaihong; Lv, Huiyi; Liu, Jiwei; Wang, Boyu


    In order to understand the drive-in target in a D-D type neutron generator, it is essential to study the mechanism of the interaction between hydrogen ion beams and the hydrogen-absorbing metal film. The present research concerns the nucleation of hydride within zirconium film implanted with hydrogen ions. Doses of 30 keV hydrogen ions ranging from 4.30 × 1017 to 1.43 × 1018 ions cm-2 were loaded into the zirconium film through the ion beam implantation technique. Features of the surface morphology and transformation of phase structures were investigated with scanning electron microscopy, atomic force microscopy and x-ray diffraction. Confirmation of the formation of δ phase zirconium hydride in the implanted samples was first made by x-ray diffraction, and the different stages in the gradual nucleation and growth of zirconium hydride were then observed by atomic force microscope and scanning electron microscopy.

  4. Alternatives to estrogen to manage hot flushes. (United States)

    Albertazzi, Paola


    Hot flushes are probably the most common symptom resulting in medical consultation in relation to the menopause and, when severe, they can affect quite dramatically women's quality of life. Hormone (estrogen) replacement therapy (HRT) is the most effective treatment for this symptom and in the ideal setting of clinical trials, under optimal selection of patients and compliance, it reduces hot flushes by about 70-80%. Recently, however, a series of 'scares' has had large resonance in the lay press about possible adverse effects of HRT. These have undermined both doctors' and women's confidence in the use of these compounds. This has been witnessed by the recent fall in HRT sales. A number of compounds, both pharmacological and herbal in origin, have been used for the treatment of neurovegetative symptoms in menopausal women. The present article critically reviews evidence of the efficacy of some of the most commonly used compounds and assesses their effect in relation to that of HRT.

  5. Hot Electron Nanoscopy and Spectroscopy (HENs)

    KAUST Repository

    Giugni, Andrea


    This chapter includes a brief description of different laser coupling methods with guided surface plasmon polariton (SPP) modes at the surface of a cone. It shows some devices, their electromagnetic simulations, and their optical characterization. A theoretical section illustrates the optical and quantum description of the hot charge generation rate as obtained for the SPP propagation along the nanocone in adiabatic compression. The chapter also shows some experimental results concerning the application of the hot electron nanoscopy and spectroscopy (HENs) in the so-called Schottky configuration, highlighting the sensitivity and the nanoscale resolution of the technique. The comparison with Kelvin probe and other electric atomic force microscopy (AFM) techniques points out the intrinsic advantages of the HENs. In the end, some further insights are given about the possibility of exploiting HENs with a pulsed laser at the femtosecond time scale without significant pulse broadening and dispersion.

  6. Mathematical modeling of deformation during hot rolling

    Energy Technology Data Exchange (ETDEWEB)

    Jin, D.; Stachowiak, R.G.; Samarasekera, I.V.; Brimacombe, J.K. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Centre for Metallurgical Processing Engineering


    The deformation that occurs in the roll bite during the hot rolling of steel, particularly the strain-rate and strain distribution, has been mathematically modeled using finite-element analysis. In this paper three different finite-element models are compared with one another and with industrial measurements. The first model is an Eulerian analysis based on the flow formulation method, while the second utilizes an Updated Lagrangian approach. The third model is based on a commercially available program DEFORM which also utilizes a Lagrangian reference frame. Model predictions of strain and strain-rate distribution, particularly near the surface of the slab, are strongly influenced by the treatment of friction at the boundary and the magnitude of the friction coefficient or shear factor. Roll forces predicted by the model have been compared with industrial rolling loads from a seven-stand hot-strip mill.

  7. Archaeal diversity in Icelandic hot springs

    DEFF Research Database (Denmark)

    Kvist, Thomas; Ahring, Birgitte Kiær; Westermann, Peter


    of Archaea by analysis of amplified 16S rRNA genes. In addition to the three solfataras and the neutral hot spring, 10 soil samples in transects of the soil adjacent to the solfataras were analysed using terminal restriction fragment length polymorphism (t-RFLP). The sequence data from the clone libraries...... in combination with 14 t-RFLP profiles revealed a high abundance of clones clustering together with sequences from the nonthermophilic I.1b group of Crenarchaeota. The archaeal diversity in one solfatara was high; 26 different RFLP patterns were found using double digestion of the PCR products with restriction......Whole-cell density gradient extractions from three solfataras (pH 2.5) ranging in temperature from 81 to 90 degrees C and one neutral hot spring (81 degrees C, pH 7) from the thermal active area of Hveragerethi (Iceland) were analysed for genetic diversity and local geographical variation...

  8. The hot γ Doradus and Maia stars (United States)

    Balona, L. A.; Engelbrecht, C. A.; Joshi, Y. C.; Joshi, S.; Sharma, K.; Semenko, E.; Pandey, G.; Chakradhari, N. K.; Mkrtichian, David; Hema, B. P.; Nemec, J. M.


    The hot γ Doradus stars have multiple low frequencies characteristic of γ Dor or SPB variables, but are located between the red edge of the SPB and the blue edge of the γ Dor instability strips where all low-frequency modes are stable in current models of these stars. Though δ Sct stars also have low frequencies, there is no sign of high frequencies in hot γ Dor stars. We obtained spectra to refine the locations of some of these stars in the H-R diagram and conclude that these are, indeed, anomalous pulsating stars. The Maia variables have multiple high frequencies characteristic of β Cep and δ Sct stars, but lie between the red edge of the β Cep and the blue edge of the δ Sct instability strips. We compile a list of all Maia candidates and obtain spectra of two of these stars. Again, it seems likely that these are anomalous pulsating stars which are currently not understood.

  9. Hot Blade Cuttings for the Building Industries

    DEFF Research Database (Denmark)

    Brander, David; Bærentzen, Jakob Andreas; Evgrafov, Anton


    variability in the (economically allowed) designs - i.e., to allow them to think out of the box. To address this challenge The Danish National Advanced Technology Foundation (now InnovationsFonden) is currently supporting the BladeRunner project that involves several Danish companies and public institutions....... The project aims to reduce the amount of manual labour as well as production time by applying robots to cut expanded polystyrene (EPS) moulds for the concrete to form doubly curved surfaces. The scheme is based upon the so-called Hot Wire or Hot Blade technology where the surfaces are essentially swept out...... are mainly concerned with the rationalization of the architects’ CAD drawings into surfaces that can be created via this particular sweeping and cutting technology....

  10. Hot subdwarf formation: Confronting theory with observation

    Directory of Open Access Journals (Sweden)

    Geier S.


    Full Text Available The formation of hot subdwarf stars is still unclear. Both single-star and binary scenarios have been proposed to explain the properties of these evolved stars situated at the extreme blue end of the horizontal branch. The observational evidence gathered in the last decade, which revealed high fractions of binaries, shifted the focus from the single-star to the binary formation scenarios. Common envelope ejection, stable Roche lobe overflow and the merger of helium white dwarfs seemed to be sufficient to explain the formation of both the binary as well as the remaining single hot subdwarfs. However, most recent and rather unexpected observations challenge the standard binary evolution scenarios.

  11. 4-Chloroanilinium hydrogen oxalate hemihydrate

    Directory of Open Access Journals (Sweden)

    Hajer Rahmouni


    Full Text Available In the title hydrated molecular salt, C6H7ClN+·C2HO4−·0.5H2O, the water O atom lies on a crystallographic twofold axis. In the crystal, the anions are linked by O—H...O hydrogen bonds, forming chains propagating along the b axis. These chains are interconnected through O—H...O hydrogen bonds from the water molecules and N—H...O hydrogen bonds from the cations, building layers parallel to the ab plane.

  12. Fusion Energy for Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Fillo, J. A.; Powell, J. R.; Steinberg, M.; Salzano, F.; Benenati, R.; Dang, V.; Fogelson, S.; Isaacs, H.; Kouts, H.; Kushner, M.; Lazareth, O.; Majeski, S.; Makowitz, H.; Sheehan, T. V.


    The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and supplement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Depending on design, electric generation efficiencies of approximately 40 to 60% and hydrogen production efficiencies by high temperature electrolysis of approximately 50 to 70% are projected for fusion reactors using high temperature blankets.

  13. Solar powered hydrogen generating facility and hydrogen powered vehicle fleet (United States)

    Provenzano, J. J.


    Clean Air Now (CAN), a non-profit corporation, acting under U.S. Department of Energy Cooperative Agreement will build a Solar Hydrogen Generating Facility at the Xerox Corp. Facility in El Segundo, CA. An integral component of this system is an electrolyzer and related equipment for compression and storage of the produced hydrogen gas. CAN has selected The Electrolyser Corporation (T.E.C) to fulfill this requirement.

  14. Hot carriers in a bipolar graphene


    Balev, Oleg G.; Vasko, Fedir T.


    Hot carriers in a doped graphene under dc electric field is described taking into account the intraband energy relaxation due to acoustic phonon scattering and the interband generation-recombination transitions caused by thermal radiation. The consideration is performed for the case when the intercarrier scattering effectively establishes the quasiequilibrium electron-hole distributions, with effective temperature and concentrations of carriers. The concentration and energy balance equations ...


    Directory of Open Access Journals (Sweden)



    Full Text Available The questions of consolidation of nanopowders concerning hot compaction by pressing activated by electric current action are considered. Mechanisms of grain boundary creep-sliding which are sequentially prevalent in a forming of compacted structures under influence of temperature factor and in the presence of a direct electric heating are discussed. Structural-transformational sources and conditions of forming of high physical-mechanical properties of nanopowder refractory solid-state products are described.

  16. Physiologically assessed hot flashes and endothelial function among midlife women. (United States)

    Thurston, Rebecca C; Chang, Yuefang; Barinas-Mitchell, Emma; Jennings, J Richard; von Känel, Roland; Landsittel, Doug P; Matthews, Karen A


    Hot flashes are experienced by most midlife women. Emerging data indicate that they may be associated with endothelial dysfunction. No studies have tested whether hot flashes are associated with endothelial function using physiologic measures of hot flashes. We tested whether physiologically assessed hot flashes were associated with poorer endothelial function. We also considered whether age modified associations. Two hundred seventy-two nonsmoking women reporting either daily hot flashes or no hot flashes, aged 40 to 60 years, and free of clinical cardiovascular disease, underwent ambulatory physiologic hot flash and diary hot flash monitoring; a blood draw; and ultrasound measurement of brachial artery flow-mediated dilation to assess endothelial function. Associations between hot flashes and flow-mediated dilation were tested in linear regression models controlling for lumen diameter, demographics, cardiovascular disease risk factors, and estradiol. In multivariable models incorporating cardiovascular disease risk factors, significant interactions by age (P women in the sample (age 40-53 years), the presence of hot flashes (beta [standard error] = -2.07 [0.79], P = 0.01), and more frequent physiologic hot flashes (for each hot flash: beta [standard error] = -0.10 [0.05], P = 0.03, multivariable) were associated with lower flow-mediated dilation. Associations were not accounted for by estradiol. Associations were not observed among the older women (age 54-60 years) or for self-reported hot flash frequency, severity, or bother. Among the younger women, hot flashes explained more variance in flow-mediated dilation than standard cardiovascular disease risk factors or estradiol. Among younger midlife women, frequent hot flashes were associated with poorer endothelial function and may provide information about women's vascular status beyond cardiovascular disease risk factors and estradiol.

  17. Estimation of energy consumption for domestic hot water in hospitals

    Energy Technology Data Exchange (ETDEWEB)

    Katsanis, J.S.; Tsarabaris, P.T.; Bourkas, P.D. [National Technical Univ. of Athens, Athens (Greece). Dept. of Electrical and Computer Engineering; Halaris, P.G. [Asklepieon Voulas General Hospital, Athens (Greece). Electrical Engineering Dept. of Biomedical Technology; Malahias, G.N. [Hellenic Naval Academy, Athens (Greece)


    Hospitals are among the largest energy consumers in the building sector, with hot water constituting the largest part of the base load which consists of partial loads for heating, sanitary hot water, sterilization, disinfection, kitchen thermal load and laundry thermal load. This study estimated the energy consumption for domestic hot water (DHW) for Greek hospitals. The purpose was to evaluate the feasibility of using cogeneration systems in hospitals, which would combine electric and thermal energy from the same energy source. In this study, only the data for the consumption of DHW was presented. DHW in Greek hospitals is 45 degrees C except for the kitchen, laundry and anatomic room supply where hot water reaches 65 degrees C. Water consumption varies considerably depending on the condition of the hospital and extent of outpatients and clinical provisions. Hot water production is typically achieved in thermal substations through hot water production centres that include hot water storage tanks; heat exchangers; heating medium circuits; pipework for domestic hot water and connection with cold water supply. This presentation described the sizing of the DHW system and estimated the simultaneity factor for hot and cold water in hospitals. The hot water demand curve was used to estimate the energy consumption per day for hot water based on 18 hours of operation. Assuming that the hot water demand curve is typical, the energy consumption was estimated for sanitary hot water per day as a function of the specific water consumption for hospital with different number of beds. The hot water energy use was nearly 50 kWh per cubic meter water. The thermal losses in the hot water piping network were not considered in this study. 17 refs., 6 tabs., 6 figs.

  18. Hot corrosion of the B2 nickel aluminides (United States)

    Ellis, David L.


    The hot corrosion behavior of the B2 nickel aluminides was studied to determine the inherent hot corrosion resistance of the beta nickel aluminides and to develop a mechanism for the hot corrosion of the beta nickel aluminides. The effects of the prior processing of the material, small additions of zirconium, stoichiometry of the materials, and preoxidation of the samples were also examined. Additions of 2, 5, and 15 w/o chromium were used to determine the effect of chromium on the hot corrosion of the beta nickel aluminides and the minimum amount of chromium necessary for good hot corrosion resistance. The results indicate that the beta nickel aluminides have inferior inherent hot corrosion resistance despite their excellent oxidation resistance. Prior processing and zirconium additions had no discernible effect on the hot corrosion resistance of the alloys. Preoxidation extended the incubation period of the alloys only a few hours and was not considered to be an effective means of stopping hot corrosion. Stoichiometry was a major factor in determining the hot corrosion resistance of the alloys with the higher aluminum alloys having a definitely superior hot corrosion resistance. The addition of chromium to the alloys stopped the hot corrosion attack in the alloys tested. From a variety of experimental results, a complex hot corrosion mechanism was proposed. During the early stages of the hot corrosion of these alloys the corrosion is dominated by a local sulphidation/oxidation form of attack. During the intermediate stages of the hot corrosion, the aluminum depletion at the surface leads to a change in the oxidation mechanism from a protective external alumina layer to a mixed nickel-aluminum spinel and nickel oxide that can occur both externally and internally. The material undergoes extensive cracking during the later portions of the hot corrosion.

  19. Hot forming of composite prepreg : Experimental study (United States)

    Tardif, Xavier; Duthille, Bertrand; Bechtel, Stephane; le Pinru, Louis; Campagne, Benjamin; Destombes, Gautier; Deshors, Antoine; Marchand, Christophe; Azzouzi, Khalid El; Moro, Tanguy


    The hot forming of thermoset prepreg consists in bending an uncured composite part by applying a mechanical constrain on the hot laminate. Most of the time, the mold is inserted in a vacuum box and the mechanical constrain is applied on the composite laminate by a single membrane or a double-membrane. But the performance improvement products resulted in forming increasingly complex parts with advanced materials having a less formability. These new complex parts require a finer comprehension of the process and an optimization of the key parameters to get acceptable quality. In this work, an experimental study has been carried out to identify the process conditions that do not lead to unacceptable defaults: undulations of fibers. In the present study, downward-bending has been evaluated with an original light mechanical forming concept, for a given stacking sequence. The influence of the part's temperature and the part's bending speed are investigated. To carry this study out, a hot forming test bench has been designed and manufactured to have a precise supervision of the process conditions. It is able to bend parts of 1500 mm length x 600 mm width x 20 mm thick.

  20. Nuclear track radiography of 'hot' aerosol particles

    CERN Document Server

    Boulyga, S F; Kievets, M K; Lomonosova, E M; Zhuk, I V; Yaroshevich, O I; Perelygin, V P; Petrova, R I; Brandt, R; Vater, P


    Nuclear track radiography was applied to identify aerosol 'hot' particles which contain elements of nuclear fuel and fallout after Chernobyl NPP accident. For the determination of the content of transuranium elements in radioactive aerosols the measurement of the alpha-activity of 'hot' particles by SSNTD was used in this work, as well as radiography of fission fragments formed as a result of the reactions (n,f) and (gamma,f) in the irradiation of aerosol filters by thermal neutrons and high energy gamma quanta. The technique allowed the sizes and alpha-activity of 'hot' particles to be determined without extracting them from the filter, as well as the determination of the uranium content and its enrichment by sup 2 sup 3 sup 5 U, sup 2 sup 3 sup 9 Pu and sup 2 sup 4 sup 1 Pu isotopes. Sensitivity of determination of alpha activity by fission method is 5x10 sup - sup 6 Bq per particle. The software for the system of image analysis was created. It ensured the identification of track clusters on an optical imag...

  1. Hot Dry Rock Geothermal Energy Development Program

    Energy Technology Data Exchange (ETDEWEB)

    Smith, M.C.; Hendron, R.H.; Murphy, H.D.; Wilson, M.G.


    During Fiscal Year 1987, emphasis in the Hot Dry Rock Geothermal Energy Development Program was on preparations for a Long-Term Flow Test'' of the Phase II'' or Engineering'' hot dry rock energy system at Fenton Hill, New Mexico. A successful 30-day flow test of the system during FY86 indicated that such a system would produce heat at a temperature and rate that could support operation of a commercial electrical power plant. However, it did not answer certain questions basic to the economics of long-term operation, including the rate of depletion of the thermal reservoir, the rate of water loss from the system, and the possibility of operating problems during extended continuous operation. Preparations for a one-year flow test of the system to answer these and more fundamental questions concerning hot dry rock systems were made in FY87: design of the required surface facilities; procurement and installation of some of their components; development and testing of slimline logging tools for use through small-diameter production tubing; research on temperature-sensitive reactive chemical tracers to monitor thermal depletion of the reservoir; and computer simulations of the 30-day test, extended to modeling the planned Long-Term Flow Test. 45 refs., 34 figs., 5 tabs.

  2. Residential hot water distribution systems: Roundtablesession

    Energy Technology Data Exchange (ETDEWEB)

    Lutz, James D.; Klein, Gary; Springer, David; Howard, Bion D.


    Residential building practice currently ignores the lossesof energy and water caused by the poor design of hot water systems. Theselosses include: combustion and standby losses from water heaters, thewaste of water (and energy) while waiting for hot water to get to thepoint of use; the wasted heat as water cools down in the distributionsystem after a draw; heat losses from recirculation systems and thediscarded warmth of waste water as it runs down the drain. Severaltechnologies are available that save energy (and water) by reducing theselosses or by passively recovering heat from wastewater streams and othersources. Energy savings from some individual technologies are reported tobe as much as 30 percent. Savings calculations of prototype systemsincluding bundles of technologies have been reported above 50 percent.This roundtable session will describe the current practices, summarizethe results of past and ongoing studies, discuss ways to think about hotwater system efficiency, and point to areas of future study. We will alsorecommend further steps to reduce unnecessary losses from hot waterdistribution systems.

  3. Adhesion of Zinc Hot-dip Coatings

    Directory of Open Access Journals (Sweden)

    Michal Černý


    Full Text Available The work is focused on verification of quality adhesion of zinc coating. It describes elements which affect quality and adhesive solidity within the coating. For assessment itself it will be neccessary to get know the basic elements which can affect adhesion of hot-dip coating which will be essential for choosing suitable samples for verification itself. These elements characterise acoustic responses during delamination coating. They affect elements influencing progress of signal. In research there is also a summary of existing methods for testing adhesion of coatings. As a result a new proposal of a new method comes out for purpose of quality testing of adhesion zinc hot-dip coating. The results of verification of this method are put to scientific analysis and findings lead to assessment of proposed method and its application in technical practise.The goal of this contribution is also include to proposed methodology testing adhesion zinc coating by nondestructive diagnostic method of acoustic emission (AE, which would monitor characterise progress of coating delamination of hot-dip zinc from basic material in way to adhesion tests would be practicable in situ. It can be enabled by analysis and assessment of results acquired by method AE and its application within verification of new method of adhesion anti-corrosive zinc coating.

  4. Ionization of hydrogen and hydrogenic ions by antiprotons (United States)

    Schultz, D. R.; Krstić, P. S.; Reinhold, C. O.; Wells, J. C.


    Motivated by earlier theoretical studies which utilized simplified models and by a very recent experiment regarding antiproton-impact of hydrogen, we present a description (D.R. Schultz, P.S. Krstić, C.O. Reinhold, and J.C. Wells, Phys. Rev. Lett. (1996) submitted.) of ionization of hydrogen and hydrogenic ions based on very large scale numerical solutions of the time-dependent Schrödinger equation in three spatial dimensions and on analysis of the topology of the electronic eigenenergy surfaces in the plane of complex internuclear distance. It is illustrated how ionization of atomic hydrogen and hydrogenic ions by antiprotons is quite different from that for impact by positively charged particles at low energies. Most significantly, for hydrogen targets, the quasi-molecular electronic eigenenergies approach close to and ultimately merge with the continuum at small distances, leading to a plateau of the low energy ionization cross section. Work supported by US DOE Office of BES through contract No. DE-AC05-84OR21400 managed by Lockheed Martin Energy Research Corp.

  5. Breath Hydrogen Produced by Ingestion of Commercial Hydrogen Water and Milk


    Shimouchi, Akito; Nose, Kazutoshi; Yamaguchi, Makoto; Ishiguro, Hiroshi; Kondo, Takaharu


    Objective: To compare how and to what extent ingestion of hydrogen water and milk increase breath hydrogen in adults.Methods: Five subjects without specific diseases, ingested distilled or hydrogen water and milk as a reference material that could increase breath hydrogen. Their end-alveolar breath hydrogen was measured.Results: Ingestion of hydrogen water rapidly increased breath hydrogen to the maximal level of approximately 40 ppm 10–15 min after ingestion and thereafter rapidly decrease...

  6. Modeling Mars' Hydrogen Exosphere (United States)

    Holmstrom, M.


    Traditionally, exospheric densities and velocity distributions are modelled by spherical symmetric analytical Chamberlain functions, assuming gravity is the only force acting on the neutrals. Planetary exospheres are however not spherical symmetric to any good approximation, as evident from observations, due to non- uniformexobase conditions and effects such as photoionization, radiation pressure, charge exchange, recombination and planetary rotation. To account for these effects numerical simulations are needed. Using Monte Carlo test particle simulations it is possible to account for the above effects (if ion distributions are assumed). Even though neutrals in the exospheres by definition do not collide often, collisions occur. Especially near the exobase the transition is gradual from collision dominated regions at lower heights (with Maxwellian velocity distributions) to essentially collisionless regions at greater heights. We present exospheric simulations that include collisions self consistently using the direct simulation Monte Carlo (DSMC) approach. The code is three dimensional, parallel and uses an adaptive grid, allowing many particles to be included in the simulations, leading to accurate results. In particular, we here study Mars' hydrogen exosphere and the effects of the above processes, including thermal escape rates.

  7. Fiber optic hydrogen sensor (United States)

    Buchanan, B.R.; Prather, W.S.


    Apparatus and method for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading, by a single spectrophotometer.

  8. TWRS tank waste pretreatment process development hot test siting report

    Energy Technology Data Exchange (ETDEWEB)

    Howden, G.F.; Banning, D.L.; Dodd, D.A.; Smith, D.A.; Stevens, P.F. [Westinghouse Hanford Co., Richland, WA (United States); Hansen, R.I.; Reynolds, B.A. [Pacific Northwest Lab., Richland, WA (United States)


    This report is the sixth in a series that have assessed the hot testing requirements for TWRS pretreatment process development and identified the hot testing support requirements. This report, based on the previous work, identifies specific hot test work packages, matches those packages to specific hot cell facilities, and provides recommendations of specific facilities to be employed for the pretreatment hot test work. Also identified are serious limitations in the tank waste sample retrieval and handling infrastructure. Recommendations are provided for staged development of 500 mL, 3 L, 25 L and 4000 L sample recovery systems and specific actions to provide those capabilities.

  9. Biological hydrogen production from phytomass

    Energy Technology Data Exchange (ETDEWEB)

    Bartacek, J.; Zabranska, J. [Inst. of Chemical Technology, Prague (Czech Republic). Dept. of Water Technology and Environmental Engineering


    Renewable sources of energy have received wide attention lately. One candidate is hydrogen which has the added advantage of involving no greenhouse gases. Biological hydrogen production from wastewater or biowastes is a very attractive production technique. So far, most studies have concentrated on the use of photosynthetic bacteria. However, dark fermentation has recently become a popular topic of research as it has the advantage of not requiring light energy input, something that limits the performance of the photosynthetic method. While pure cultures have been used in most of the investigations to date, in industrial situations mixed cultures will probably be the norm because of unavoidable contamination. In this investigation the phytomass of amaranth (Amaranthus cruentus L) was used to produce hydrogen. Specific organic loading, organic loading, and pH were varied to study the effect on hydrogen production. 18 refs., 1 tab., 6 figs.

  10. Hydrogen-powered lawn mower

    Energy Technology Data Exchange (ETDEWEB)

    Yvon, K.; Lorenzoni, J.-L. (Geneva Univ. (Switzerland). Lab. de Cristallographie)


    We present a hydrogen-powered lawn mower which was adapted from a commercial model running on gasoline. The necessary modifications include adjustments to the carburettor and the insulation of a hydrogen reservoir containing about 5 kg of a metal hydride powder. Hydrogen is obtained by desorption of that powder at ambient temperature and 2 - 20 bar pressure. The reservoir is rechargeable at a hydrogen pressure of about 25 bar within less than 1 h. One charge lasts about 40 min. corresponding to about 800 m[sup 2] of cut lawn. The engine shows a reduced noise level and no tendency to backfiring. The prototype has run successfully for more than 1 year. (Author)

  11. Complex Hydrides for Hydrogen Storage

    Energy Technology Data Exchange (ETDEWEB)

    Slattery, Darlene; Hampton, Michael


    This report describes research into the use of complex hydrides for hydrogen storage. The synthesis of a number of alanates, (AIH4) compounds, was investigated. Both wet chemical and mechano-chemical methods were studied.

  12. Hydrogen Fire Spectroscopy Issues Project (United States)

    National Aeronautics and Space Administration — This one year effort had four aspects; complete and document the calibrated spectral intensity of a hydrogen flame, understand the role of atmospheric attenuation on...

  13. Hydrogen bonding in tight environments

    DEFF Research Database (Denmark)

    Pirrotta, Alessandro; Solomon, Gemma C.; Franco, Ignacio


    The single-molecule force spectroscopy of a prototypical class of hydrogen-bonded complexes is computationally investigated. The complexes consist of derivatives of a barbituric acid and a Hamilton receptor that can form up to six simultaneous hydrogen bonds. The force-extension (F-L) isotherms...... of the host-guest complexes are simulated using classical molecular dynamics and the MM3 force field, for which a refined set of hydrogen bond parameters was developed from MP2 ab initio computations. The F-L curves exhibit peaks that signal conformational changes during elongation, the most prominent...... of which is in the 60-180 pN range and corresponds to the force required to break the hydrogen bonds. These peaks in the F-L curves are shown to be sensitive to relatively small changes in the chemical structure of the host molecule. Thermodynamic insights into the supramolecular assembly were obtained...

  14. 1. European Hydrogen Energy Conference

    Energy Technology Data Exchange (ETDEWEB)



    This conference is the first of a series of EHA (European Hydrogen Association) conferences that will take place every two years in Europe with the collaboration of the national European Hydrogen Associations. EHEC 2003 takes place within the context of the debates on long term energy strategies organized by the international authorities and the governments of many countries. Under the patronage of the European Commission and the French government, the conference will aim at providing a comprehensive picture of the research work and demonstrations on hydrogen and fuel cells that the currently being carried out all over the globe. EHEC 2003 will provide an opportunity to define the role that hydrogen will have in tomorrow's energy landscape and, in particular, the benefits with regard to: 1)sustainable development of energy 2)control of climate change 3)development of renewable energy 4)increase demand for ground transport. (O.M.)

  15. Nearby Hot Stars May Change Our View of Distant Sources (United States)

    Kohler, Susanna


    As if it werent enough that quasars distant and bright nuclei of galaxies twinkle of their own accord due to internal processes, nature also provides another complication: these distant radio sources can also appear to twinkle because of intervening material between them and us. A new study has identified a possible source for the material getting in the way.Unexplained VariabilityA Spitzer infrared view of the Helix nebula, which contains ionized streamers of gas extending radially outward from the central star. [NASA/JPL-Caltech/Univ. of Ariz.]Distant quasars occasionally display extreme scintillation, twinkling with variability timescales shorter than a day. This intra-day variability is much greater than we can account for with standard models of the interstellar medium lying between the quasar and us. So what could cause this extreme scattering instead?The first clue to this mystery came from the discovery of strong variability in the radio source PKS 1322110. In setting up follow-up observations of this object, Mark Walker (Manly Astrophysics, Australia) and collaborators noticed that, in the plane of the sky, PKS 1322110 lies very near the bright star Spica. Could this be coincidence, or might this bright foreground star have something to do with the extreme scattering observed?Diagram explaining the source of the intra-day radio source variability as intervening filaments surrounding a hot star. [M. Walker/CSIRO/Manly Astrophysics]Swarms of ClumpsWalker and collaborators put forward a hypothesis: perhaps the ultraviolet photons of nearby hot stars ionize plasma around them, which in turn causes the extreme scattering of the distant background sources.As a model, the authors consider the Helix Nebula, in which a hot, evolved star is surrounded by cool globules of molecular hydrogen gas. The radiation from the star hits these molecular clumps, dragging them into long radial streamers and ionizing their outer skins.Though the molecular clumps in the Helix

  16. Hydrogen Production Technical Team Roadmap

    Energy Technology Data Exchange (ETDEWEB)



    The Hydrogen Production Technical Team Roadmap identifies research pathways leading to hydrogen production technologies that produce near-zero net greenhouse gas (GHG) emissions from highly efficient and diverse renewable energy sources. This roadmap focuses on initial development of the technologies, identifies their gaps and barriers, and describes activities by various U.S. Department of Energy (DOE) offices to address the key issues and challenges.

  17. Hydrogen storage in nanotubes & nanostructures


    Froudakis, George E.


    Over the last several years, a significant share of the scientific community has focused its attention on the hydrogen storage problem. Since 1997, when carbon nanotubes appeared to be a promising storage material, many theoretical and experimental groups have investigated the hydrogen storage capacity of these carbon nanostructures. These efforts were not always successful and consequently, the results obtained were often controversial. In the current review we attempt to summarize some the ...

  18. Chemical utilization of hydrogen from fluctuating energy sources – Catalytic transfer hydrogenation from charged Liquid Organic Hydrogen Carrier systems


    Geburtig, Denise; Preuster, Patrick; Bösmann, Andreas; Müller, Karsten; Wasserscheid, Peter


    Liquid Organic Hydrogen Carrier (LOHC) systems offer a very attractive way for storing and distributing hydrogen from electrolysis using excess energies from solar or wind power plants. In this contribution, an alternative, high-value utilization of such hydrogen is proposed namely its use in steady-state chemical hydrogenation processes. We here demonstrate that the hydrogen-rich form of the LOHC system dibenzyltoluene/perhydro-dibenzyltoluene can be directly applied as sole source of hydrog...

  19. 29 CFR 1910.103 - Hydrogen. (United States)


    ... 29 Labor 5 2010-07-01 2010-07-01 false Hydrogen. 1910.103 Section 1910.103 Labor Regulations... OCCUPATIONAL SAFETY AND HEALTH STANDARDS Hazardous Materials § 1910.103 Hydrogen. (a) General—(1) Definitions. As used in this section (i) Gaseous hydrogen system is one in which the hydrogen is delivered, stored...

  20. Hydrogen in the Methanol Production Process (United States)

    Kralj, Anita Kovac; Glavic, Peter


    Hydrogen is a very important industrial gas in chemical processes. It is very volatile; therefore, it can escape from the process units and its mass balance is not always correct. In many industrial processes where hydrogen is reacted, kinetics are often related to hydrogen pressure. The right thermodynamic properties of hydrogen can be found for…