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Sample records for high-aspect ratio si

  1. Nanofabrication of low extinction coefficient and high-aspect-ratio Si structures for metaphotonic applications

    Science.gov (United States)

    Lee, JeongYub; Song, Byonggwon; Kim, Jaekwan; Lee, Chang-Won; Han, Seunghoon; Baik, Chan-Wook; Jeong, Heejeong; Kim, Yongsung; Lee, Chang Seung

    2016-09-01

    We investigated forming of high refractive index (n), low extinction coefficient (k) of Si dielectrics in visible wavelength ranges. To decrease k, pulsed green laser annealing (GLA) with line beam of a 532-nm wavelength was applied in this study for homogeneous melting. By AFM, XRD and TEM analysis, we examined the defect reduction in various conditions during poly-crystallization. We achieved dielectric nanostructures having optical properties of n>4.2, k<0.06 at 550 nm wavelength and fine pitches down to 40 nm (aspect ratio 3:1) and 130 nm (aspect ratio 7:1) with +/-5% size accuracy. Finally, we realized optical metasurfaces for optical band filters, flat lens and beam deflectors.

  2. High aspect ratio tungsten grating on ultrathin Si membranes for extreme UV lithography

    Science.gov (United States)

    Peng, Xinsheng; Ying, Yulong

    2016-09-01

    Extreme ultraviolet lithography is one of the modern lithography tools for high-volume manufacturing with 22 nm resolution and beyond. But critical challenges exist to the design and fabrication of large-scale and highly efficient diffraction transmission gratings, significantly reducing the feature sizes down to 22 nm and beyond. To achieve such a grating, the surface flatness, the line edge roughness, the transmission efficiency and aspect ratio should be improved significantly. Delachat et al (2015 Nanotechnology 26 108262) develop a full process to fabricate a tungsten diffraction grating on an ultrathin silicon membrane with higher aspect ratio up to 8.75 that met all the aforementioned requirements for extreme ultraviolet lithography. This process is fully compatible with standard industrial extreme ultraviolet lithography.

  3. High aspect ratio tungsten grating on ultrathin Si membranes for extreme UV lithography.

    Science.gov (United States)

    Peng, Xinsheng; Ying, Yulong

    2016-09-02

    Extreme ultraviolet lithography is one of the modern lithography tools for high-volume manufacturing with 22 nm resolution and beyond. But critical challenges exist to the design and fabrication of large-scale and highly efficient diffraction transmission gratings, significantly reducing the feature sizes down to 22 nm and beyond. To achieve such a grating, the surface flatness, the line edge roughness, the transmission efficiency and aspect ratio should be improved significantly. Delachat et al (2015 Nanotechnology 26 108262) develop a full process to fabricate a tungsten diffraction grating on an ultrathin silicon membrane with higher aspect ratio up to 8.75 that met all the aforementioned requirements for extreme ultraviolet lithography. This process is fully compatible with standard industrial extreme ultraviolet lithography.

  4. Fabrication of high aspect ratio tungsten nanostructures on ultrathin c-Si membranes for extreme UV applications.

    Science.gov (United States)

    Delachat, F; Le Drogoff, B; Constancias, C; Delprat, S; Gautier, E; Chaker, M; Margot, J

    2016-01-15

    In this work, we demonstrate a full process for fabricating high aspect ratio diffraction optics for extreme ultraviolet lithography. The transmissive optics consists in nanometer scale tungsten patterns standing on flat, ultrathin (100 nm) and highly transparent (>85% at 13.5 nm) silicon membranes (diameter of 1 mm). These tungsten patterns were achieved using an innovative pseudo-Bosch etching process based on an inductively coupled plasma ignited in a mixture of SF6 and C4F8. Circular ultra-thin Si membranes were fabricated through a state-of-the-art method using direct-bonding with thermal difference. The silicon membranes were sputter-coated with a few hundred nanometers (100-300 nm) of stress-controlled tungsten and a very thin layer of chromium. Nanoscale features were written in a thin resist layer by electron beam lithography and transferred onto tungsten by plasma etching of both the chromium hard mask and the tungsten layer. This etching process results in highly anisotropic tungsten features at room temperature. The homogeneity and the aspect ratio of the advanced pattern transfer on the membranes were characterized with scanning electron microscopy after focus ion beam milling. An aspect ratio of about 6 for 35 nm size pattern is successfully obtained on a 1 mm diameter 100 nm thick Si membrane. The whole fabrication process is fully compatible with standard industrial semiconductor technology.

  5. Ultra-high aspect ratio poly-Si FinFET using an improved spacer formation technique

    Science.gov (United States)

    Liu, Libin; Liang, Renrong; Wang, Jing; Xu, Jun

    2017-04-01

    An improved spacer formation technique was proposed and developed to fabricate poly-Si fin field-effect transistors (FinFETs) with an ultra-high aspect ratio. The as-demonstrated FinFETs have a fin channel with a width and height of 22 nm and 230 nm, respectively, corresponding to an aspect ratio of 10.5. The electrical and temperature properties of the FinFETs are described in detail in this paper. The poly-Si FinFETs exhibit a steep subthreshold swing (196 mV/dec), a low leakage current (∼10-14 A), a high on/off current ratio (2.2 × 107 at VDS = 0.1 V), and a low drain-induced barrier lowering effect (0.28 V). The excellent switching characteristics are attributed to the ultrathin channel body and the multi-gate structure combined with high-k Al2O3 dielectric. Furthermore, the electron field-effective mobility increases as the temperature increases. An analytical fitting model was derived and was utilized to account for this phenomenon. The fitting results indicate that the positive temperature coefficient originates from the grain boundary-controlled mechanism in the low gate voltage regime.

  6. High Aspect Ratio Semiconductor Heterojunction Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Redwing, Joan [Pennsylvania State Univ., University Park, PA (United States). Dept. of Material Science and Engineering; Mallouk, Tom [Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemistry; Mayer, Theresa [Pennsylvania State Univ., University Park, PA (United States). Dept. of Electrical Engineering; Dickey, Elizabeth [Pennsylvania State Univ., University Park, PA (United States). Dept. of Materials Science and Engineering; Wronski, Chris [Pennsylvania State Univ., University Park, PA (United States). Dept. of Electrical Engineering

    2013-05-17

    The project focused on the development of high aspect ratio silicon heterojunction (HARSH) solar cells. The solar cells developed in this study consisted of high density vertical arrays of radial junction silicon microwires/pillars formed on Si substrates. Prior studies have demonstrated that vertical Si wire/pillar arrays enable reduced reflectivity and improved light trapping characteristics compared to planar solar cells. In addition, the radial junction structure offers the possibility of increased carrier collection in solar cells fabricated using material with short carrier diffusion lengths. However, the high junction and surface area of radial junction Si wire/pillar array devices can be problematic and lead to increased diode leakage and enhanced surface recombination. This study investigated the use of amorphous hydrogenated Si in the form of a heterojunction-intrinsic-thin layer (HIT) structure as a junction formation method for these devices. The HIT layer structure has widely been employed to reduce surface recombination in planar crystalline Si solar cells. Consequently, it was anticipated that it would also provide significant benefits to the performance of radial junction Si wire/pillar array devices. The overall goals of the project were to demonstrate a HARSH cell with a HIT-type structure in the radial junction Si wire/pillar array configuration and to develop potentially low cost pathways to fabricate these devices. Our studies demonstrated that the HIT structure lead to significant improvements in the open circuit voltage (Voc>0.5) of radial junction Si pillar array devices compared to devices fabricated using junctions formed by thermal diffusion or low pressure chemical vapor deposition (LPCVD). In addition, our work experimentally demonstrated that the radial junction structure lead to improvements in efficiency compared to comparable planar devices for devices fabricated using heavily doped Si that had reduced carrier diffusion

  7. Ultra-high aspect ratio Si nanowires fabricated with plasma etching: plasma processing, mechanical stability analysis against adhesion and capillary forces and oleophobicity.

    Science.gov (United States)

    Zeniou, A; Ellinas, K; Olziersky, A; Gogolides, E

    2014-01-24

    Room-temperature deep Si etching using time-multiplexed deep reactive ion etching (DRIE) processes is investigated to fabricate ultra-high aspect ratio Si nanowires (SiNWs) perpendicular to the silicon substrate. Nanopatterning is achieved using either top-down techniques (e.g. electron beam lithography) or colloidal polystyrene (PS) sphere self-assembly. The latter is a faster and more economical method if imperfections in diameter and position can be tolerated. We demonstrate wire radii from below 100 nm to several micrometers, and aspect ratios (ARs) above 100:1 with etching rates above 1 μm min(-1) using classical mass flow controllers with pulsing rise times of seconds. The mechanical stability of these nanowires is studied theoretically and experimentally against adhesion and capillary forces. It is shown that above ARs of the order of 50:1 for spacing 1 μm, SiNWs tend to bend due to adhesion forces between them. Such large adhesion forces are due to the high surface energy of silicon. Wetting the SiNWs with water and drying also gives rise to capillary forces. We find that capillary forces may be less important for SiNW collapse/bending compared to adhesion forces of dry SiNWs, contrary to what is observed for polymeric nanowires/nanopillars which have a much lower surface energy compared to silicon. Finally we show that SiNW arrays have oleophobic and superoleophobic properties, i.e. they exhibit excellent anti-wetting properties for a wide range of liquids and oils due to the re-entrant profile produced by the DRIE process and the well-designed spacing.

  8. Ultra-high aspect ratio Si nanowires fabricated with plasma etching: plasma processing, mechanical stability analysis against adhesion and capillary forces and oleophobicity

    Science.gov (United States)

    Zeniou, A.; Ellinas, K.; Olziersky, A.; Gogolides, E.

    2014-01-01

    Room-temperature deep Si etching using time-multiplexed deep reactive ion etching (DRIE) processes is investigated to fabricate ultra-high aspect ratio Si nanowires (SiNWs) perpendicular to the silicon substrate. Nanopatterning is achieved using either top-down techniques (e.g. electron beam lithography) or colloidal polystyrene (PS) sphere self-assembly. The latter is a faster and more economical method if imperfections in diameter and position can be tolerated. We demonstrate wire radii from below 100 nm to several micrometers, and aspect ratios (ARs) above 100:1 with etching rates above 1 μm min-1 using classical mass flow controllers with pulsing rise times of seconds. The mechanical stability of these nanowires is studied theoretically and experimentally against adhesion and capillary forces. It is shown that above ARs of the order of 50:1 for spacing 1 μm, SiNWs tend to bend due to adhesion forces between them. Such large adhesion forces are due to the high surface energy of silicon. Wetting the SiNWs with water and drying also gives rise to capillary forces. We find that capillary forces may be less important for SiNW collapse/bending compared to adhesion forces of dry SiNWs, contrary to what is observed for polymeric nanowires/nanopillars which have a much lower surface energy compared to silicon. Finally we show that SiNW arrays have oleophobic and superoleophobic properties, i.e. they exhibit excellent anti-wetting properties for a wide range of liquids and oils due to the re-entrant profile produced by the DRIE process and the well-designed spacing.

  9. Study on Locally Confined Deposition of Si Nanocrystals in High-Aspect-Ratio Si Nano-Pillar Array for Nano-Electronic and Nano-Photonic Applications

    Science.gov (United States)

    2010-02-23

    the applied electric field on the SiOx, mox is the effective electron mass in the SiOx, m is the free electron mass, B is the barrier height at the...compared to other mechanisms. For example, a simulated direct tunneling current with mox /m ratio of 0.26, the barrier height of 3.8, the oxide thickness...transport path,[24] which is give by * 2 exp exp 1Bthermionic q qVJ A T kT kT               , (5) where A* = 4 pqk2m*/h3 = 120 ( mox

  10. Noise of Embedded High Aspect Ratio Nozzles

    Science.gov (United States)

    Bridges, James E.

    2011-01-01

    A family of high aspect ratio nozzles were designed to provide a parametric database of canonical embedded propulsion concepts. Nozzle throat geometries with aspect ratios of 2:1, 4:1, and 8:1 were chosen, all with convergent nozzle areas. The transition from the typical round duct to the rectangular nozzle was designed very carefully to produce a flow at the nozzle exit that was uniform and free from swirl. Once the basic rectangular nozzles were designed, external features common to embedded propulsion systems were added: extended lower lip (a.k.a. bevel, aft deck), differing sidewalls, and chevrons. For the latter detailed Reynolds-averaged Navier-Stokes (RANS) computational fluid dynamics (CFD) simulations were made to predict the thrust performance and to optimize parameters such as bevel length, and chevron penetration and azimuthal curvature. Seventeen of these nozzles were fabricated at a scale providing a 2.13 inch diameter equivalent area throat." ! The seventeen nozzles were tested for far-field noise and a few data were presented here on the effect of aspect ratio, bevel length, and chevron count and penetration. The sound field of the 2:1 aspect ratio rectangular jet was very nearly axisymmetric, but the 4:1 and 8:1 were not, the noise on their minor axes being louder than the major axes. Adding bevel length increased the noise of these nozzles, especially on their minor axes, both toward the long and short sides of the beveled nozzle. Chevrons were only added to the 2:1 rectangular jet. Adding 4 chevrons per wide side produced some decrease at aft angles, but increased the high frequency noise at right angles to the jet flow. This trend increased with increasing chevron penetration. Doubling the number of chevrons while maintaining their penetration decreased these effects. Empirical models of the parametric effect of these nozzles were constructed and quantify the trends stated above." Because it is the objective of the Supersonics Project that

  11. Fabrication of high-aspect ratio SU-8 micropillar arrays

    DEFF Research Database (Denmark)

    Amato, Letizia; Keller, Stephan S.; Heiskanen, Arto

    2012-01-01

    SU-8 is the preferred photoresist for development and fabrication of high aspect ratio (HAR) three dimensional patterns. However, processing of SU-8 is a challenging task, especially when the film thickness as well as the aspect ratio is increasing and the size of the features is close to the res...

  12. Scattering and extinction from high-aspect-ratio trenches

    DEFF Research Database (Denmark)

    Roberts, Alexander Sylvester; Søndergaard, Thomas; Chirumamilla, Manohar;

    2015-01-01

    We construct a semi-analytical model describing the scattering, extinction and absorption properties of a high aspect-ratio trench in a metallic film. We find that these trenches act as highly efficient scatterers of free waves. In the perfect conductor limit, which for many metals is approached...

  13. Injection molding of high aspect ratio sub-100 nm nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels B

    2013-01-01

    with FDTS. Reduced adhesion forces are consistent with lowered friction that reduces the risk of fracturing the nanoscopic pillars during demolding. Optimized mold surface chemistry and associated injection molding conditions permitted the fabrication of square arrays of 40 nm wide and 107 nm high (aspect......We have explored the use of mold coatings and optimized processing conditions to injection mold high aspect ratio nanostructures (height-to-width >1) in cyclic olefin copolymer (COC). Optimizing the molding parameters on uncoated nickel molds resulted in slight improvements in replication quality...

  14. Aeroelastic stability analysis of high aspect ratio aircraft wings

    OpenAIRE

    Banerjee, J. R.; Liu, X.; Kassem, H. I.

    2014-01-01

    Free vibration and flutter analyses of two types of high aspect ratio aircraft wings are presented. The wing is idealised as an assembly of bending-torsion coupled beams using the dynamic stiffness method leading to a nonlinear eigenvalue problem. This problem is solved using the Wattrick-Williams algorithm yielding natural frequencies and mode shapes. The flutter analysis is carried out using the normal mode method in conjunction with generalised coordinates and two-dimensional unsteady aero...

  15. High aspect ratio 3D nanopatterning using Proton Beam Writing

    Science.gov (United States)

    van Kan, Jeroen A.

    2009-03-01

    Proton beam writing (PBW) is a new direct write lithography using MeV protons, and is unique because of its ability to fabricate 3D structures of high aspect ratio structures directly in resist material like PMMA, SU-8 and HSQ. The introduction by CIBA, Singapore of a dedicated PBW facility, capable of writing at the micro- and nano- scale has facilitated high aspect ratio nanostructuring. PBW has demontrated high aspect ratio walls in HSQ down to the 20nm level. In recent experiments details down to sub 20 nm have been achieved in PMMA. Monte-Carlo calculations have shown that structuring down to the nanometer level is feasible. All this is possible because of the virtual absence of proximity effects (unwanted resist exposure by stray secondary electrons). The design and performance of this unique nanoprobe facility will be discussed. Two potential fields of application (eg nanofluidics and nanowire integration) of PBW will be discussed. Currently nanofluidics devices have typically only one critical dimension below 100 nm. Here we will introduce PBW as a powerful technique to fabricate molds for replication of PDMS nanofluidic circuits down to the sub 100 nm level in two dimensions. Initial chips with dimension down to 150 nm have successfully been used to study DNA folding in quasi-1d nanochannels in tandem with fluorescence imaging. Since the size of these PDMS nanochannels is not limited by the PDMS or PBW further miniaturization down to the sub 100 nm level is a realistic goal and initial results will be discussed. Nanowires are a potential building block for nano-electronic devices, and one critical problem is the integration of nanowires to form contacts. Porous alumina templates and high energy ion-tracks have been used for the production of nanowire templates in a random orientation. Since PBW is the only true 3D direct write nanolithographic technique it can be used to fabricate nanowire templates in a controlled manner.

  16. High aspect ratio transmission line circuits micromachined in silicon

    Science.gov (United States)

    Todd, Shane Truman

    The performance of complimentary metal-oxide-semiconductor (CMOS) monolithic microwave integrated circuits (MMICs) fabricated on silicon has improved dramatically. The scaling down of silicon transistors has increased the maximum frequency of transistors to the point where silicon MMICs have become a viable alternative to compound semiconductor MMICs in certain applications. A fundamental problem still exists in silicon MMICs however in that transmission lines fabricated on silicon can suffer from high loss due to the finite conductivity of the silicon substrate. A novel approach for creating low-loss transmission lines on silicon is presented in this work. Low-loss transmission lines are created on low resistivity silicon by using a micromachining method that combines silicon deep reactive ion etching (DRIE), thermal oxidation, electroplating, and planarization. Two types of high aspect ratio transmission lines are created with this method including high aspect ratio coplanar waveguide (hicoplanar) and semi-rectangular coaxial (semicoaxial). Transmission lines with impedances ranging from 20--80 O have been fabricated with minimum measured loss lower than 1 dB/cm at 67 GHz. Low-loss dielectrics are created for the high aspect ratio transmission lines using the mesa merging method. The mesa merging method works by creating silicon mesa arrays using DRIE and then converting and merging the mesa arrays into a solid oxide dielectric using thermal oxidation. The transmission lines are designed so that the fields penetrate the low-loss oxide dielectric and are isolated from the lossy silicon substrate. The mesa merging method has successfully created large volume oxide with depth up to 65 microm and width up to 240 microm in short oxidation times. Other advantages of the high aspect ratio transmission lines are demonstrated including low-loss over a wide impedance range, high isolation, and high coupling for coupled-line circuits. Transmission line models have been

  17. Anomalous dynamic behaviour of optically trapped high aspect ratio nanowires

    CERN Document Server

    Toe, Wen Jun; Angstmann, Christopher; Gao, Qiang; Tan, Hark Hoe; Jagadish, Chennupati; Henry, Bruce; Reece, Peter J

    2015-01-01

    We investigate the dynamics of high aspect ratio nanowires trapped axially in a single gradient force optical tweezers. A power spectrum analysis of the Brownian dynamics reveals a broad spectral resonance of the order of a kHz with peak properties that are strongly dependent on the input trapping power. Modelling of the dynamical equations of motion of the trapped nanowire that incorporate non-conservative effects through asymmetric coupling between translational and rotational degrees of freedom provides excellent agreement with the experimental observations. An associated observation of persistent cyclical motion around the equilibrium trapping position using winding analysis provides further evidence for the influence of non-conservative forces.

  18. High Aspect-Ratio Neural Probes using Conventional Blade Dicing

    Science.gov (United States)

    Goncalves, S. B.; Ribeiro, J. F.; Silva, A. F.; Correia, J. H.

    2016-10-01

    Exploring deep neural circuits has triggered the development of long penetrating neural probes. Moreover, driven by brain displacement, the long neural probes require also a high aspect-ratio shafts design. In this paper, a simple and reproducible method of manufacturing long-shafts neural probes using blade dicing technology is presented. Results shows shafts up to 8 mm long and 200 µm wide, features competitive to the current state-of-art, being its outline simply accomplished by a single blade dicing program. Therefore, conventional blade dicing presents itself as a viable option to manufacture long neural probes.

  19. High-aspect ratio magnetic nanocomposite polymer cilium

    Science.gov (United States)

    Rahbar, M.; Tseng, H. Y.; Gray, B. L.

    2014-03-01

    This paper presents a new fabrication technique to achieve ultra high-aspect ratio artificial cilia micro-patterned from flexible highly magnetic rare earth nanoparticle-doped polymers. We have developed a simple, inexpensive and scalable fabrication method to create cilia structures that can be actuated by miniature electromagnets, that are suitable to be used for lab-on-a chip (LOC) and micro-total-analysis-system (μ-TAS) applications such as mixers and flow-control elements. The magnetic cilia are fabricated and magnetically polarized directly in microfluidic channels or reaction chambers, allowing for easy integration with complex microfluidic systems. These cilia structures can be combined on a single chip with other microfluidic components employing the same permanently magnetic nano-composite polymer (MNCP), such as valves or pumps. Rare earth permanent magnetic powder, (Nd0.7Ce0.3)10.5Fe83.9B5.6, is used to dope polydimethylsiloxane (PDMS), resulting in a highly flexible M-NCP of much higher magnetization and remanence [1] than ferromagnetic polymers typically employed in magnetic microfluidics. Sacrificial poly(ethylene-glycol) (PEG) is used to mold the highly magnetic polymer into ultra high-aspect ratio artificial cilia. Cilia structures with aspect ratio exceeding 8:0.13 can be easily fabricated using this technique and are actuated using miniature electromagnets to achieve a high range of motion/vibration.

  20. Formation of High Aspect Ratio Microcoil Using Dipping Method

    Science.gov (United States)

    Noda, Daiji; Yamashita, Shuhei; Matsumoto, Yoshifumi; Setomoto, Masaru; Hattori, Tadashi

    Coils are used in many electronic devices as inductors in mobile units such as mobile phone, digital cameras, etc. Inductance and quality factor of coils are very important value of the performance. Therefore, the requests for coils are small size, high inductance, low power consumption, etc. However, coils are unsuitable for miniaturization because of its structure. Therefore, we have proposed and developed the microcoils of high aspect ratio with the dipping method and an X-ray lithography technique. In dipping method, centrifugal force and highly viscous photoresist solution were key points to evenly apply resist in the form of thick film on metal bar. The film thickness of resist on bar was achieved about 50 μm after single coating. Using these techniques, we succeeded in creating threaded groove structure with 10 μm lines and spaces on 1 mm brass bar. In this case, the aspect ratio was achieved five. It is very expected the high performance microcoil with high aspect ratio lines could be manufactured in spite of the miniature size.

  1. High aspect ratio channels in glass and porous silicon

    Energy Technology Data Exchange (ETDEWEB)

    Liang, H.D. [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Nanoscience and Nanotechnology Initiative (NNI), National University of Singapore, Singapore 117411 (Singapore); Dang, Z.Y. [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Wu, J.F. [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117583 (Singapore); Kan, J.A. van; Qureshi, S. [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Ynsa, M.D.; Torres-Costa, V. [Department of Applied Physics, Universidad Autónoma de Madrid, Madrid, Campus de Cantoblanco, 28049 Madrid (Spain); Centro de Micro-Análisis de Materiales (CMAM), Universidad Autónoma de Madrid, Campus de Cantoblanco Edif. 22, Faraday 3, E-28049 Madrid (Spain); Maira, A. [Department of Applied Physics, Universidad Autónoma de Madrid, Madrid, Campus de Cantoblanco, 28049 Madrid (Spain); Venkatesan, T.V. [Nanoscience and Nanotechnology Initiative (NNI), National University of Singapore, Singapore 117411 (Singapore); Breese, M.B.H., E-mail: phymbhb@nus.edu.sg [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore, Singapore 117542 (Singapore)

    2017-03-01

    We have developed a micromachining process to produce high-aspect-ratio channels and holes in glass and porous silicon. Our process utilizes MeV proton beam irradiation of silicon using direct writing with a focused beam, followed by electrochemical etching. To increase throughput we have also developed another process for large area ion irradiation based on a radiation-resistant gold surface mask, allowing many square inches to be patterned. We present a study of the achievable channel width, depth and period and sidewall verticality for a range of channels which can be over 100 μm deep or 100 nm wide with aspect ratios up to 80. This process overcomes the difficulty of machining glass on a micro- and nanometer scale which has limited many areas of applications in different fields such as microelectronics and microfluidics.

  2. High aspect ratio channels in glass and porous silicon

    Science.gov (United States)

    Liang, H. D.; Dang, Z. Y.; Wu, J. F.; van Kan, J. A.; Qureshi, S.; Ynsa, M. D.; Torres-Costa, V.; Maira, A.; Venkatesan, T. V.; Breese, M. B. H.

    2017-03-01

    We have developed a micromachining process to produce high-aspect-ratio channels and holes in glass and porous silicon. Our process utilizes MeV proton beam irradiation of silicon using direct writing with a focused beam, followed by electrochemical etching. To increase throughput we have also developed another process for large area ion irradiation based on a radiation-resistant gold surface mask, allowing many square inches to be patterned. We present a study of the achievable channel width, depth and period and sidewall verticality for a range of channels which can be over 100 μm deep or 100 nm wide with aspect ratios up to 80. This process overcomes the difficulty of machining glass on a micro- and nanometer scale which has limited many areas of applications in different fields such as microelectronics and microfluidics.

  3. Improving acousto-optical interaction by high aspect ratio electrodes

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard

    In recent years experiments have shown that optical waves in waveguides can be modulated by mechanical stresses from surface acoustic waves (SAW), which have most of their energy density concentrated at the surface. In these experiments the SAWs are generated in piezoelectric materials...... by conventional interdigital transducers consisting of thin electrodes deposited at the surface. In this work the finite element method is employed to investigate if the acousto-optical interaction can be enhanced by generating the SAWs by interdigital transducers consisting of high aspect ratio electrodes....... With a periodic model it is first shown that these tall electrodes introduce several new confined SAW modes with slow phase velocities because of mechanical energy storage in the electrodes. The periodic model is then extended to a finite model by using perfectly matched layers at the substrate borders...

  4. Dielectric spectroscopy of high aspect ratio graphene-polyurethane nanocomposites

    Science.gov (United States)

    Jan, Rahim; Habib, Amir; Abbassi, Hina; Amir, Shahid

    2015-03-01

    High aspect ratio graphene nanosheets (GNS), prepared via liquid exfoliation, are homogeneously dispersed in thermoplastic polyurethane (TPU). Dielectric spectroscopy results are reported for these nanocomposites (up to 0.55 vol. % GNS) in the frequency range of 100 Hz to 5 MHz. The as-prepared GNS increased the AC conductivity 10-1000 times across the given frequency range. The dielectric constant is increased 5-6 times at 100 Hz for the maximum loading of GNS when compared with the pristine TPU, with subsequently high dielectric loss making them a suitable candidate for high energy dissipation applications such as EMI shielding. The temperature effects on the dielectric characteristics of 0.55 vol. % GNS/TPU nanocomposites beyond 400 K are more pronounced due to the interfacial and orientation polarization. Mechanical characteristics evaluation of GNS/TPU composites shows a marked increase in the ultimate tensile strength without compromising their ductility and stiffness. [Figure not available: see fulltext.

  5. Large eddy simulation of a high aspect ratio combustor

    Science.gov (United States)

    Kirtas, Mehmet

    The present research investigates the details of mixture preparation and combustion in a two-stroke, small-scale research engine with a numerical methodology based on large eddy simulation (LES) technique. A major motivation to study such small-scale engines is their potential use in applications requiring portable power sources with high power density. The investigated research engine has a rectangular planform with a thickness very close to quenching limits of typical hydrocarbon fuels. As such, the combustor has a high aspect ratio (defined as the ratio of surface area to volume) that makes it different than the conventional engines which typically have small aspect ratios to avoid intense heat losses from the combustor in the bulk flame propagation period. In most other aspects, this engine involves all the main characteristics of traditional reciprocating engines. A previous experimental work has identified some major design problems and demonstrated the feasibility of cyclic combustion in the high aspect ratio combustor. Because of the difficulty of carrying out experimental studies in such small devices, resolving all flow structures and completely characterizing the flame propagation have been an enormously challenging task. The numerical methodology developed in this work attempts to complement these previous studies by providing a complete evolution of flow variables. Results of the present study demonstrated strengths of the proposed methodology in revealing physical processes occuring in a typical operation of the high aspect ratio combustor. For example, in the scavenging phase, the dominant flow structure is a tumble vortex that forms due to the high velocity reactant jet (premixed) interacting with the walls of the combustor. Since the scavenging phase is a long process (about three quarters of the whole cycle), the impact of the vortex is substantial on mixture preparation for the next combustion phase. LES gives the complete evolution of this flow

  6. Fabrication of nanopore and nanoparticle arrays with high aspect ratio AAO masks

    Science.gov (United States)

    Li, Z. P.; Xu, Z. M.; Qu, X. P.; Wang, S. B.; Peng, J.; Mei, L. H.

    2017-03-01

    How to use high aspect ratio anodic aluminum oxide (AAO) membranes as an etching and evaporation mask is one of the unsolved problems in the application of nanostructured arrays. Here we describe the versatile utilizations of the highly ordered AAO membranes with a high aspect ratio of more than 20 used as universal masks for the formation of various nanostructure arrays on various substrates. The result shows that the fabricated nanopore and nanoparticle arrays of substrates inherit the regularity of the AAO membranes completely. The flat AAO substrates and uneven AAO frontages were attached to the Si substrates respectively as an etching mask, which demonstrates that the two kinds of replication, positive and negative, represent the replication of the mirroring of Si substrates relative to the flat AAO substrates and uneven AAO frontages. Our work is a breakthrough for the broad research field of surface nano-masking.

  7. Wafer-scale fabrication of high-aspect ratio nanochannels based on edge-lithography technique.

    Science.gov (United States)

    Xie, Quan; Zhou, Qing; Xie, Fei; Sang, Jianming; Wang, Wei; Zhang, Haixia Alice; Wu, Wengang; Li, Zhihong

    2012-03-01

    This paper introduced a wafer-scale fabrication approach for the preparation of nanochannels with high-aspect ratio (the ratio of the channel depth to its width). Edge lithography was used to pattern nanogaps in an aluminum film, which was functioned as deep reactive ion etching mask thereafter to form the nanochannel. Nanochannels with aspect ratio up to 172 and width down to 44 nm were successfully fabricated on a 4-inch Si wafer with width nonuniformity less than 13.6%. A microfluidic chip integrated with nanometer-sized filters was successfully fabricated by utilizing the present method for geometric-controllable nanoparticle packing.

  8. Cryogenic Etching of High Aspect Ratio 400 nm Pitch Silicon Gratings.

    Science.gov (United States)

    Miao, Houxun; Chen, Lei; Mirzaeimoghri, Mona; Kasica, Richard; Wen, Han

    2016-10-01

    The cryogenic process and Bosch process are two widely used processes for reactive ion etching of high aspect ratio silicon structures. This paper focuses on the cryogenic deep etching of 400 nm pitch silicon gratings with various etching mask materials including polymer, Cr, SiO2 and Cr-on-polymer. The undercut is found to be the key factor limiting the achievable aspect ratio for the direct hard masks of Cr and SiO2, while the etch selectivity responds to the limitation of the polymer mask. The Cr-on-polymer mask provides the same high selectivity as Cr and reduces the excessive undercut introduced by direct hard masks. By optimizing the etching parameters, we etched a 400 nm pitch grating to ≈ 10.6 μm depth, corresponding to an aspect ratio of ≈ 53.

  9. Rapid homogeneous endothelialization of high aspect ratio microvascular networks.

    Science.gov (United States)

    Naik, Nisarga; Hanjaya-Putra, Donny; Haller, Carolyn A; Allen, Mark G; Chaikof, Elliot L

    2015-08-01

    Microvascularization of an engineered tissue construct is necessary to ensure the nourishment and viability of the hosted cells. Microvascular constructs can be created by seeding the luminal surfaces of microfluidic channel arrays with endothelial cells. However, in a conventional flow-based system, the uniformity of endothelialization of such an engineered microvascular network is constrained by mass transfer of the cells through high length-to-diameter (L/D) aspect ratio microchannels. Moreover, given the inherent limitations of the initial seeding process to generate a uniform cell coating, the large surface-area-to-volume ratio of microfluidic systems demands long culture periods for the formation of confluent cellular microconduits. In this report, we describe the design of polydimethylsiloxane (PDMS) and poly(glycerol sebacate) (PGS) microvascular constructs with reentrant microchannels that facilitates rapid, spatially homogeneous endothelial cell seeding of a high L/D (2 cm/35 μm; > 550:1) aspect ratio microchannels. MEMS technology was employed for the fabrication of a monolithic, elastomeric, reentrant microvascular construct. Isotropic etching and PDMS micromolding yielded a near-cylindrical microvascular channel array. A 'stretch - seed - seal' operation was implemented for uniform incorporation of endothelial cells along the entire microvascular area of the construct yielding endothelialized microvascular networks in less than 24 h. The feasibility of this endothelialization strategy and the uniformity of cellularization were established using confocal microscope imaging.

  10. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials

    OpenAIRE

    Raluca M Fratila; Rivera-Fernández, Sara; Fuente, Jesús M. de la

    2015-01-01

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In th...

  11. Dielectrophoretically structured piezoelectric composites with high aspect ratio piezoelectric particles inclusions

    NARCIS (Netherlands)

    Ende, D.A. van den; Kempen, S.E. van; Wu, X.; Groen, W.A.; Randall, C.A.; Zwaag, S. van der

    2012-01-01

    Piezoelectric composites were prepared by dielectrophoretic alignment of high aspect ratio piezoelectric particles in a thermosetting polymer matrix. A high level of alignment was achieved in the cured composite from a resin containing randomly oriented high aspect ratio particles. Upon application

  12. Hot punching of high-aspect-ratio 3D polymeric microstructures for drug delivery

    DEFF Research Database (Denmark)

    Petersen, Ritika Singh; Keller, Stephan Sylvest; Boisen, Anja

    2015-01-01

    Hot punching: a highly versatile method of fabricating high-aspect-ratio 3D microstructures for drug delivery with good replication fidelity and yield.......Hot punching: a highly versatile method of fabricating high-aspect-ratio 3D microstructures for drug delivery with good replication fidelity and yield....

  13. Photoimageable Polyimide: A Dielectric Material For High Aspect Ratio Structures

    Science.gov (United States)

    Cech, Jay M.; Oprysko, Modest M.; Young, Peter L.; Li, Kin

    1986-07-01

    Polyimide has been identified as a useful material for microelectronic packaging because of its low dielectric constant and high temperature stability. Difficulties involved with reactive ion etching (RIE), a conventional technique for patterning thick polyimide films (thickness greater than 5 microns) with vertical walls, can be overcome by using photimageable polyimide precursors. The processing steps are similar to those used with negative photoresists. EM Chemical's HTR-3 photosensitive polyimide has been spun on up to a thickness of 12 microns. Exposure with a dose of 780 mJcm-2 of ultraviolet light, followed by spin development produces clean patterns as small as 5 microns corresponding to an aspect ratio of 2.4. When the patterned precursor is heated, an imidization reaction occurs converting the patterned film to polyimide. Baking to ca. 400 degrees C results in substantial loss in the thickness and in line width. However, shrinkage occurs reproducibly so useful rules for mask design can be formulated. Near vertical wall structures can be fabricated by taking advantage of the optical and shrinkage properties of the polyimide precursor. After development, an undercut wall profile can be produced since the bottom of the film receives less exposure and is hence more soluble in the developer. During heating, lateral shrinkage pulls the top of the film inward producing a vertical wall since the bottom is fixed to the substrate by adhesion. As a result, fully cured polyimide structures with straight walls and aspect ratios greater than one can be obtained. Dielectric properties of the fully imidized films were investigated with capacitor test structures. A relative dielectric constant of 3.3 and a loss tangent of .002 were measured at 20 kHz. It was also found that the dielectric constant increases as a linear function of relative humidity.

  14. Noise Measurements of High Aspect Ratio Distributed Exhaust Systems

    Science.gov (United States)

    Bridges, James E.

    2015-01-01

    This paper covers far-field acoustic measurements of a family of rectangular nozzles with aspect ratio 8, in the high subsonic flow regime. Several variations of nozzle geometry, commonly found in embedded exhaust systems, are explored, including bevels, slants, single broad chevrons and notches, and internal septae. Far-field acoustic results, presented previously for the simple rectangular nozzle, showed that increasing aspect ratio increases the high frequency noise, especially directed in the plane containing the minor axis of the nozzle. Detailed changes to the nozzle geometry generally made little difference in the noise, and the differences were greatest at low speed. Having an extended lip on one broad side (bevel) did produce up to 3 decibels more noise in all directions, while extending the lip on the narrow side (slant) produced up to 2 decibels more noise, primarily on the side with the extension. Adding a single, non-intrusive chevron, made no significant change to the noise, while inverting the chevron (notch) produced up to 2decibels increase in the noise. Having internal walls (septae) within the nozzle, such as would be required for structural support or when multiple fan ducts are aggregated, reduced the noise of the rectangular jet, but could produce a highly directional shedding tone from the septae trailing edges. Finally, a nozzle with both septae and a beveled nozzle, representative of the exhaust system envisioned for a distributed electric propulsion aircraft with a common rectangular duct, produced almost as much noise as the beveled nozzle, with the septae not contributing much reduction in noise.

  15. GaN nanowire tip for high aspect ratio nano-scale AFM metrology (Conference Presentation)

    Science.gov (United States)

    Behzadirad, Mahmoud; Dawson, Noel; Nami, Mohsen; Rishinaramangalam, Ashwin K.; Feezell, Daniel F.; Busani, Tito L.

    2016-09-01

    In this study we introduce Gallium Nitride (GaN) nanowire (NW) as high aspect ratio tip with excellent durability for nano-scale metrology. GaN NWs have superior mechanical property and young modulus compare to commercial Si and Carbon tips which results in having less bending issue during measurement. The GaN NWs are prepared via two different methods: i) Catalyst-free selected area growth, using Metal Organic Chemical Vapor Deposition (MOCVD), ii) top-down approach by employing Au nanoparticles as the mask material in dry-etch process. To achieve small diameter tips, the semipolar planes of the NWs grown by MOCVD are etched using AZ400k. The diameter of the NWs fabricated using the top down process is controlled by using different size of nanoparticles and by Inductively Coupled Plasma etching. NWs with various diameters were manipulated on Si cantilevers using Focus Ion Beam (FIB) to make tips for AFM measurement. A Si (110) substrate containing nano-scale grooves with vertical 900 walls were used as a sample for inspection. AFM measurements were carried out in tapping modes for both types of nanowires (top-down and bottom-up grown nanowires) and results are compared with conventional Si and carbon nanotube tips. It is shown our fabricated tips are robust and have improved edge resolution over conventional Si tips. GaN tips made with NW's fabricated using our top down method are also shown to retain the gold nanoparticle at tip, which showed enhanced field effects in Raman spectroscopy.

  16. Ultra-high aspect ratio replaceable AFM tips using deformation-suppressed focused ion beam milling

    DEFF Research Database (Denmark)

    Savenko, Alexey; Yildiz, Izzet; Petersen, Dirch Hjorth;

    2013-01-01

    Fabrication of ultra-high aspect ratio exchangeable and customizable tips for atomic force microscopy (AFM) using lateral focused ion beam (FIB) milling is presented. While on-axis FIB milling does allow high aspect ratio (HAR) AFM tips to be defined, lateral milling gives far better flexibility...... FIB milling strategies for obtaining sharper tips are discussed. Finally, assembly of the HAR tips on a custom-designed probe as well as the first AFM scanning is shown....

  17. High aspect ratio silicon nanowires control fibroblast adhesion and cytoskeleton organization.

    Science.gov (United States)

    Andolfi, Laura; Murello, Anna; Cassese, Damiano; Ban, Jelena; Dal Zilio, Simone; Lazzarino, Marco

    2017-04-18

    Cell-cell and cell-matrix interactions are essential to the survival and proliferation of most cells, and are responsible for triggering a wide range of biochemical pathways. More recently, the biomechanical role of those interactions was highlighted, showing, for instance, that adhesion forces are essential for cytoskeleton organization. Silicon nanowires (Si NWs) with their small size, high aspect ratio and anisotropic mechanical response represent a useful model to investigate the forces involved in the adhesion processes and their role in cellular development. In this work we explored and quantified, by single cell force spectroscopy (SCFS), the interaction of mouse embryonic fibroblasts with a flexible forest of Si NWs. We observed that the cell adhesion forces are comparable to those found on collagen and bare glass coverslip, analogously the membrane tether extraction forces are similar to that on collagen but stronger than that on bare flat glass. Cell survival did not depend significantly on the substrate, although a reduced proliferation after 36 h was observed. On the contrary both cell morphology and cytoskeleton organization revealed striking differences. The cell morphology on Si-NW was characterized by a large number of filopodia and a significant decrease of the cell mobility. The cytoskeleton organization was characterized by the absence of actin fibers, which were instead dominant on collagen and flat glass support. Such findings suggest that the mechanical properties of disordered Si NWs, and in particular their strong asymmetry, play a major role in the adhesion, morphology and cytoskeleton organization processes. Indeed, while adhesion measurements by SCFS provide out-of-plane forces values consistent with those measured on conventional substrates, weaker in-plane forces hinder proper cytoskeleton organization and migration processes.

  18. Etching high aspect ratio structures in silicon using sulfur hexafluoride/oxygen plasma

    Science.gov (United States)

    Belen, Rodolfo Jun

    Plasma etching of high aspect ratio structures in Si is an important step in manufacturing capacitors for memory devices and integrated components of microelectromechanical systems. In these applications, the goal is to etch deep features anisotropically with high etch rates and selectivities to the mask while maintaining good uniformity and reproducibility. This study investigates the etching of deep sub-half-micron diameter holes in Si using SF6/O 2 plasma. Etching experiments and plasma diagnostics are combined with modeling to gain a fundamental understanding of the etching and passivation kinetics and mechanism necessary in developing and scaling-up processes. Etching experiments are conducted in an inductively coupled plasma reactor with a planar coil. The substrate electrode is biased with a separate rf power supply to achieve independent control of the ion flux and energy. The effects of pressure, rf-bias and SF6-to-O2 ratio in the feed gas on the etch rate, selectivity and feature profile shape are studied using Si wafers patterned with 0.35 mum-diameter holes in a SiO2 mask. Visualization of profiles using scanning electron microscopy is complemented by plasma diagnostics such as mass spectrometry and actinometry. Simultaneous with experiments, reactor-scale and feature-scale models are developed to quantify the etching and passivation kinetics and identify the important kinetic parameters that affect feature profile evolution. Information from plasma diagnostics and previously published data are used to reduce the degrees of freedom in the model. Experiments are designed to directly measure kinetic parameters such as the chemical etch rate constant and the incidence angle dependence of the etching yield. Experimentally inaccessible parameters such as the sticking coefficients, etching yield and ion scattering parameters are determined through feature profile simulation. The key internal plasma parameters that affect profile evolution are the F-to-O and F

  19. Fabrication of high aspect ratio nanocell lattices by ion beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, Osamu [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Nitta, Noriko, E-mail: nitta.noriko@kochi-tech.ac.jp [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Center for Nanotechnology, Research Institute, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan); Taniwaki, Masafumi [School of Environmental Science and Technology, Kochi University of Technology, Tosayamada, Kami, Kochi 782-8502 (Japan)

    2016-11-01

    Highlights: • Nanocell lattice with a high aspect ratio on InSb semiconductor surface was fabricated by ion beam irradiation. • The fabrication technique consisting of top-down and bottom-up processes was performed in FIB. • High aspect ratio of 2 was achieved in nanocell lattice with a 100 nm interval. • The intermediate-flux irradiation is favorable for fabrication of nanocell with a high aspect ratio. - Abstract: A high aspect ratio nanocell lattice was fabricated on the InSb semiconductor surface using the migration of point defects induced by ion beam irradiation. The fabrication technique consisting of the top-down (formation of voids and holes) and bottom-up (growth of voids and holes into nanocells) processes was performed using a focused ion beam (FIB) system. A cell aspect ratio of 2 (cell height/cell diameter) was achieved for the nanocell lattice with a 100 nm dot interval The intermediate-flux ion irradiation during the bottom-up process was found to be optimal for the fabrication of a high aspect ratio nanocell.

  20. Synthesis of high aspect ratio ZnO nanowires with an inexpensive handcrafted electrochemical setup

    Science.gov (United States)

    Taheri, Ali; Saramad, Shahyar; Setayeshi, Saeed

    2016-12-01

    In this work, high aspect ratio zinc oxide nanowires are synthesized using templated one-step electrodeposition technique. Electrodeposition of the nanowires is done using a handcrafted electronic system. Nuclear track-etched polycarbonate membrane is used as a template to form the high aspect ratio nanowires. The result of X-ray diffraction and scanning electron microscopy shows that nanowires with a good crystallinity and an aspect ratio of more than 30 can be achieved in a suitable condition. The height of electrodeposited nanowires reaches to about 11 μm. Based on the obtained results, high aspect ratio ZnO nanowires can be formed using inexpensive electrodeposition setup with an acceptable quality.

  1. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials.

    Science.gov (United States)

    Fratila, Raluca M; Rivera-Fernández, Sara; de la Fuente, Jesús M

    2015-05-14

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In this review, we first describe the two main synthetic routes for the preparation of anisotropic magnetic nanomaterials: (i) direct synthesis (in which the anisotropic growth is directed by tuning the reaction conditions or by using templates) and (ii) assembly methods (in which the high aspect ratio is achieved by assembly from individual building blocks). We then provide an overview of the biomedical applications of anisotropic magnetic nanomaterials: magnetic separation and detection, targeted delivery and magnetic resonance imaging.

  2. Development of high-aspect-ratio microchannel heat exchanger based on multi-tool milling process

    Institute of Scientific and Technical Information of China (English)

    潘敏强; 李金恒; 汤勇

    2008-01-01

    A high-aspect-ratio microchannel heat exchanger based on multi-tool milling process was developed. Several slotting cutters were stacked together for simultaneously machining several high-aspect-ratio microchannels with manifold structures. On the basis of multi-tool milling process, the structural design of the manifold side height, microchannel length, width, number, and interval were analyzed. The heat transfer performances of high-aspect-ratio microchannel heat exchangers with two different manifolds were investigated by experiments, and the influencing factors were analyzed. The results indicate that the magnitude of heat transfer area per unit volume dominates the heat transfer performances of plate-type micro heat exchanger, while the velocity distribution between microchannels has little effects on the heat transfer performances.

  3. Shape matters: synthesis and biomedical applications of high aspect ratio magnetic nanomaterials

    Science.gov (United States)

    Fratila, Raluca M.; Rivera-Fernández, Sara; de La Fuente, Jesús M.

    2015-04-01

    High aspect ratio magnetic nanomaterials possess anisotropic properties that make them attractive for biological applications. Their elongated shape enables multivalent interactions with receptors through the introduction of multiple targeting units on their surface, thus enhancing cell internalization. Moreover, due to their magnetic anisotropy, high aspect ratio nanomaterials can outperform their spherical analogues as contrast agents for magnetic resonance imaging (MRI) applications. In this review, we first describe the two main synthetic routes for the preparation of anisotropic magnetic nanomaterials: (i) direct synthesis (in which the anisotropic growth is directed by tuning the reaction conditions or by using templates) and (ii) assembly methods (in which the high aspect ratio is achieved by assembly from individual building blocks). We then provide an overview of the biomedical applications of anisotropic magnetic nanomaterials: magnetic separation and detection, targeted delivery and magnetic resonance imaging.

  4. Fabrication of high aspect ratio nanogrid transparent electrodes via capillary assembly of Ag nanoparticles

    Science.gov (United States)

    Kang, Juhoon; Park, Chang-Goo; Lee, Su-Han; Cho, Changsoon; Choi, Dae-Geun; Lee, Jung-Yong

    2016-05-01

    In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%.In this report, we describe the fabrication of periodic Ag nanogrid electrodes by capillary assembly of silver nanoparticles (AgNPs) along patterned nanogrid templates. By assembling the AgNPs into these high-aspect-ratio nanogrid patterns, we can obtain high-aspect-ratio nanogratings, which can overcome the inherent trade-off between the optical transmittance and the sheet resistance of transparent electrodes. The junction resistance between the AgNPs is effectively reduced by photochemical welding and post-annealing. The fabricated high-aspect-ratio nanogrid structure with a line width of 150 nm and a height of 450 nm has a sheet resistance of 15.2 Ω sq-1 and an optical transmittance of 85.4%. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr01896c

  5. Physical Delivery of Macromolecules using High-Aspect Ratio Nanostructured Materials.

    Science.gov (United States)

    Lee, Kunwoo; Lingampalli, Nithya; Pisano, Albert P; Murthy, Niren; So, Hongyun

    2015-10-28

    There is great need for the development of an efficient delivery method of macromolecules, including nucleic acids, proteins, and peptides, to cell cytoplasm without eliciting toxicity or changing cell behavior. High-aspect ratio nanomaterials have addressed many challenges present in conventional methods, such as cell membrane passage and endosomal degradation, and have shown the feasibility of efficient high-throughput macromolecule delivery with minimal perturbation of cells. This review describes the recent advances of in vitro and in vivo physical macromolecule delivery with high-aspect ratio nanostructured materials and summarizes the synthesis methods, material properties, relevant applications, and various potential directions.

  6. Thermo-mechanical properties of high aspect ratio silica nanofiber filled epoxy composites

    Science.gov (United States)

    Ren, Liyun

    The optimization of thermo-mechanical properties of polymer composites at low filler loadings is of great interest in both engineering and scientific fields. There have been several studies on high aspect ratio fillers as novel reinforcement phase for polymeric materials. However, facile synthesis method of high aspect ratio nanofillers is limited. In this study, a scalable synthesis method of high aspect ratio silica nanofibers is going to be presented. I will also demonstrate that the inclusion of high aspect ratio silica nanofibers in epoxy results in a significant improvement of epoxy thermo-mechanical properties at low filler loadings. With silica nanofiber concentration of 2.8% by volume, the Young's modulus, ultimate tensile strength and fracture toughness of epoxy increased ~23, ~28 and ~50%, respectively, compared to unfilled epoxy. At silica nanofiber volume concentration of 8.77%, the thermal expansion coefficient decreased by ˜40% and the thermal conductivity was improved by ˜95% at room temperature. In the current study, the influence of nano-sized silica filler aspect ratio on mechanical and thermal behavior of epoxy nanocomposites were studied by comparing silica nanofibers to spherical silica nanoparticles (with aspect ratio of one) at various filler loadings. The significant reinforcement of composite stiffness is attributed to the variation of the local stress state in epoxy due to the high aspect ratio of the silica nanofiber and the introduction of a tremendous amount of interfacial area between the nanofillers and the epoxy matrix. The fracture mechanisms of silica nanofiber filled epoxy were also investigated. The existence of high aspect ratio silica nanofiber promotes fracture energy dissipation by crack deflection, crack pinning as well as debonding with fiber pull-out leading to enhanced fracture toughness. High aspect ratio fillers also provide significant reduction of photon scattering due to formation of a continuous fiber network

  7. Modeling and characterization of dielectrophoretically structured piezoelectric composites using piezoceramic particle inclusions with high aspect ratios

    NARCIS (Netherlands)

    Ende, D.A. van den; Maier, R.A.; Neer, P.L.M.J. van; Zwaag, S. van der; Randall, C.A.; Groen, W.A.

    2013-01-01

    In this work, the piezoelectric properties at high electric fields of dielectrophoretically aligned PZT - polymer composites containing high aspect ratio particles (such as short fibers) are presented. Polarization and strain as a function of electric field are evaluated. The properties of the compo

  8. Improving surface acousto-optical interaction by high aspect ratio electrodes

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Laude, Vincent; Khelif, Abdelkrim

    2009-01-01

    The acousto-optical interaction of an optical wave confined inside a waveguide and a surface acoustic wave launched by an interdigital transducer (IDT) at the surface of a piezoelectric material is considered. The IDT with high aspect ratio electrodes supports several acoustic modes that are stro...

  9. Dense high-aspect ratio 3D carbon pillars on interdigitated microelectrode arrays

    DEFF Research Database (Denmark)

    Amato, Letizia; Heiskanen, Arto; Hansen, Rasmus

    2015-01-01

    In this work we present high-aspect ratio carbon pillars (1.4 μm in diameter and ∼11 μm in height) on top of interdigitated electrode arrays to be used for electrochemical applications. For this purpose, different types of 2D and 3D pyrolysed carbon structures were fabricated and characterised...

  10. A 3-dimensional in vitro model of epithelioid granulomas induced by high aspect ratio nanomaterials

    Directory of Open Access Journals (Sweden)

    Hurt Robert H

    2011-05-01

    Full Text Available Abstract Background The most common causes of granulomatous inflammation are persistent pathogens and poorly-degradable irritating materials. A characteristic pathological reaction to intratracheal instillation, pharyngeal aspiration, or inhalation of carbon nanotubes is formation of epithelioid granulomas accompanied by interstitial fibrosis in the lungs. In the mesothelium, a similar response is induced by high aspect ratio nanomaterials, including asbestos fibers, following intraperitoneal injection. This asbestos-like behaviour of some engineered nanomaterials is a concern for their potential adverse health effects in the lungs and mesothelium. We hypothesize that high aspect ratio nanomaterials will induce epithelioid granulomas in nonadherent macrophages in 3D cultures. Results Carbon black particles (Printex 90 and crocidolite asbestos fibers were used as well-characterized reference materials and compared with three commercial samples of multiwalled carbon nanotubes (MWCNTs. Doses were identified in 2D and 3D cultures in order to minimize acute toxicity and to reflect realistic occupational exposures in humans and in previous inhalation studies in rodents. Under serum-free conditions, exposure of nonadherent primary murine bone marrow-derived macrophages to 0.5 μg/ml (0.38 μg/cm2 of crocidolite asbestos fibers or MWCNTs, but not carbon black, induced macrophage differentiation into epithelioid cells and formation of stable aggregates with the characteristic morphology of granulomas. Formation of multinucleated giant cells was also induced by asbestos fibers or MWCNTs in this 3D in vitro model. After 7-14 days, macrophages exposed to high aspect ratio nanomaterials co-expressed proinflammatory (M1 as well as profibrotic (M2 phenotypic markers. Conclusions Induction of epithelioid granulomas appears to correlate with high aspect ratio and complex 3D structure of carbon nanotubes, not with their iron content or surface area. This model

  11. Flow visualization study in high aspect ratio cooling channels for rocket engines

    Science.gov (United States)

    Meyer, Michael L.; Giuliani, James E.

    1993-11-01

    The structural integrity of high pressure liquid propellant rocket engine thrust chambers is typically maintained through regenerative cooling. The coolant flows through passages formed either by constructing the chamber liner from tubes or by milling channels in a solid liner. Recently, Carlile and Quentmeyer showed life extending advantages (by lowering hot gas wall temperatures) of milling channels with larger height to width aspect ratios (AR is greater than 4) than the traditional, approximately square cross section, passages. Further, the total coolant pressure drop in the thrust chamber could also be reduced, resulting in lower turbomachinery power requirements. High aspect ratio cooling channels could offer many benefits to designers developing new high performance engines, such as the European Vulcain engine (which uses an aspect ratio up to 9). With platelet manufacturing technology, channel aspect ratios up to 15 could be formed offering potentially greater benefits. Some issues still exist with the high aspect ratio coolant channels. In a coolant passage of circular or square cross section, strong secondary vortices develop as the fluid passes through the curved throat region. These vortices mix the fluid and bring lower temperature coolant to the hot wall. Typically, the circulation enhances the heat transfer at the hot gas wall by about 40 percent over a straight channel. The effect that increasing channel aspect ratio has on the curvature heat transfer enhancement has not been sufficiently studied. If the increase in aspect ratio degrades the secondary flow, the fluid mixing will be reduced. Analysis has shown that reduced coolant mixing will result in significantly higher wall temperatures, due to thermal stratification in the coolant, thus decreasing the benefits of the high aspect ratio geometry. A better understanding of the fundamental flow phenomena in high aspect ratio channels with curvature is needed to fully evaluate the benefits of this

  12. Growth of high aspect ratio ZnO nanorods by solution process: Effect of polyethyleneimine

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Han-Seok; Vaseem, Mohammad; Kim, Sang Gon; Im, Yeon-Ho [School of Semiconductor and Chemical Engineering, Dept. of BIN Fusion Technology, BK 21 Centre for Future Energy Materials and Devices, and Nanomaterials Processing Research Center, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Hahn, Yoon-Bong, E-mail: ybhahn@chonbuk.ac.kr [School of Semiconductor and Chemical Engineering, Dept. of BIN Fusion Technology, BK 21 Centre for Future Energy Materials and Devices, and Nanomaterials Processing Research Center, Chonbuk National University, Jeonju 561-756 (Korea, Republic of)

    2012-05-15

    High aspect ratio ZnO nanorods were grown vertically on ZnO seed layer deposited silicon, glass and polyimide substrates by a solution process at low-temperature using zinc nitrate hexahydrate and hexamethylenetetramine. We studied the effect of polyethlyeneimine (PEI) on the growth of ZnO nanorods. It was found that PEI has a prominent effect on controlling the aspect ratio of ZnO nanorods in solution. The morphological and photoluminescence properties of the ZnO nanorods were also examined with varying the growth temperature (60-90 Degree-Sign C). - Graphical abstract: With addition of polyehyleneimine (PEI) high aspect-ratio ZnO nanorods were grown. It is believed that during ZnO nanorods growth, protonized form of linear PEI molecules inhibits the lateral growth by being adsorbed on non-polar lateral planes. Thus the vertical growth is favored. Highlights: Black-Right-Pointing-Pointer A controlled growth of high aspect ratio ZnO nanorods on different substrates. Black-Right-Pointing-Pointer A prominent effect of polyethlyeneimine (PEI) on controlling the aspect ratio of ZnO nanorods in solution. Black-Right-Pointing-Pointer Precursor concentration and growth temperature effect for various aspect ratio ZnO nanorods.

  13. Different methods to alter surface morphology of high aspect ratio structures

    Energy Technology Data Exchange (ETDEWEB)

    Leber, M., E-mail: moritz.leber@utah.edu [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, UT (United States); Shandhi, M.M.H. [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, UT (United States); Hogan, A. [Blackrock Microsystems, Salt Lake City, UT (United States); Solzbacher, F. [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, UT (United States); Bhandari, R.; Negi, S. [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, UT (United States); Blackrock Microsystems, Salt Lake City, UT (United States)

    2016-03-01

    Graphical abstract: Surface engineering of high aspect ratio silicon structures. - Highlights: • Multiple roughening techniques for high aspect ratio devices were investigated. • Modification of surface morphology of high aspect ratio silicon devices (1:15). • Decrease of 76% in impedance proves significant increase in surface area. - Abstract: In various applications such as neural prostheses or solar cells, there is a need to alter the surface morphology of high aspect ratio structures so that the real surface area is greater than geometrical area. The change in surface morphology enhances the devices functionality. One of the applications of altering the surface morphology is of neural implants such as the Utah electrode array (UEA) that communicate with single neurons by charge injection induced stimulation or by recording electrical neural signals. For high selectivity between single cells of the nervous system, the electrode surface area is required to be as small as possible, while the impedance is required to be as low as possible for good signal to noise ratios (SNR) during neural recording. For stimulation, high charge injection and charge transfer capacities of the electrodes are required, which increase with the electrode surface. Traditionally, researchers have worked with either increasing the roughness of the existing metallization (platinum grey, black) or other materials such as Iridium Oxide and PEDOT. All of these previously investigated methods lead to more complicated metal deposition processes that are difficult to control and often have a critical impact on the mechanical properties of the metal films. Therefore, a modification of the surface underneath the electrode's coating will increase its surface area while maintaining the standard and well controlled metal deposition process. In this work, the surfaces of the silicon micro-needles were engineered by creating a defined microstructure on the electrodes surface using several

  14. A review on non-linear aeroelasticity of high aspect-ratio wings

    Science.gov (United States)

    Afonso, Frederico; Vale, José; Oliveira, Éder; Lau, Fernando; Suleman, Afzal

    2017-02-01

    Current economic constraints and environmental regulations call for design of more efficient aircraft configurations. An observed trend in aircraft design to reduce the lift induced drag and improve fuel consumption and emissions is to increase the wing aspect-ratio. However, a slender wing is more flexible and subject to higher deflections under the same operating conditions. This effect may lead to changes in dynamic behaviour and in aeroelastic response, potentially resulting in instabilities. Therefore, it is important to take into account geometric non-linearities in the design of high aspect-ratio wings, as well as having accurate computational codes that couple the aerodynamic and structural models in the presence of non-linearities. Here, a review on the state-of-the-art on non-linear aeroelasticity of high aspect-ratio wings is presented. The methodologies employed to analyse high aspect-ratio wings are presented and their applications discussed. Important observations from the state-of-the-art studies are drawn and the current challenges in the field are identified.

  15. An implicit wetting and drying approach for non-hydrostatic flows in high aspect ratio domains

    CERN Document Server

    Candy, Adam S

    2013-01-01

    A wetting and drying approach for free surface flows governed by the three-dimensional, non-hydrostatic Navier-Stokes equations in high aspect ratio domains is developed. This has application in the modelling of inundation processes in geophysical domains, where dynamics takes place over a large horizontal extent relative to vertical resolution, such as in the evolution of a tsunami, or an urban fluvial flooding scenario. The approach is novel in that it solves for three dimensional dynamics in these very high aspect ratio domains, to include non-hydrostatic effects and accurately model dispersive processes. These become important in shallow regions with steep gradients, a particularly acute problem where man-made structures exist such as buildings or flood defences in an urban environment. It is implicit in time to allow efficient time integration over a range of mesh element sizes. Specific regularisation methods are introduced to improve conditioning of the full three-dimensional pressure Poisson problem i...

  16. Light emitting diode with high aspect ratio submicron roughness for light extraction and methods of forming

    Science.gov (United States)

    Li, Ting

    2013-08-13

    The surface morphology of an LED light emitting surface is changed by applying a reactive ion etch (RIE) process to the light emitting surface. High aspect ratio, submicron roughness is formed on the light emitting surface by transferring a thin film metal hard-mask having submicron patterns to the surface prior to applying a reactive ion etch process. The submicron patterns in the metal hard-mask can be formed using a low cost, commercially available nano-patterned template which is transferred to the surface with the mask. After subsequently binding the mask to the surface, the template is removed and the RIE process is applied for time duration sufficient to change the morphology of the surface. The modified surface contains non-symmetric, submicron structures having high aspect ratio which increase the efficiency of the device.

  17. Patterned growth of high aspect ratio silicon wire arrays at moderate temperature

    Science.gov (United States)

    Morin, Christine; Kohen, David; Tileli, Vasiliki; Faucherand, Pascal; Levis, Michel; Brioude, Arnaud; Salem, Bassem; Baron, Thierry; Perraud, Simon

    2011-04-01

    High aspect ratio silicon wire arrays with excellent pattern fidelity over wafer-scale area were grown by chemical vapor deposition at moderate temperature, using a gas mixture of silane and hydrogen chloride. An innovative two-step process was developed for in situ doping of silicon wires by diborane. This process led to high p-type doping levels, up to 10 18-10 19 cm -3, without degradation of the silicon wire array pattern fidelity.

  18. Flight Loads Prediction of High Aspect Ratio Wing Aircraft Using Multibody Dynamics

    Directory of Open Access Journals (Sweden)

    Michele Castellani

    2016-01-01

    Full Text Available A framework based on multibody dynamics has been developed for the static and dynamic aeroelastic analyses of flexible high aspect ratio wing aircraft subject to structural geometric nonlinearities. Multibody dynamics allows kinematic nonlinearities and nonlinear relationships in the forces definition and is an efficient and promising methodology to model high aspect ratio wings, which are known to be prone to structural nonlinear effects because of the high deflections in flight. The multibody dynamics framework developed employs quasi-steady aerodynamics strip theory and discretizes the wing as a series of rigid bodies interconnected by beam elements, representative of the stiffness distribution, which can undergo arbitrarily large displacements and rotations. The method is applied to a flexible high aspect ratio wing commercial aircraft and both trim and gust response analyses are performed in order to calculate flight loads. These results are then compared to those obtained with the standard linear aeroelastic approach provided by the Finite Element Solver Nastran. Nonlinear effects come into play mainly because of the need of taking into account the large deflections of the wing for flight loads computation and of considering the aerodynamic forces as follower forces.

  19. Fabrication of Aspheric Micro-Lens Mold with High Aspect Ratio

    Science.gov (United States)

    Naniwa, Irizo; Kanamaru, Masatoshi; Nakamura, Shigeo; Shimano, Takeshi; Horino, Masaya

    The optical pickup of our Small-Form-Factor Optical Disc Drives (SFFODDs) requires a micro-objective whose profile is composed of two aspheric surfaces. However, it is difficult to fabricate a micro-objective with an arbitrary aspheric surface and high aspect ratio using conventional techniques. We propose here a new method to fabricate an aspheric micro-lens mold with high aspect ratio. This method uses the micro-loading effect in Deep Reactive Ion Etching (DRIE) and isotropic Reactive Ion Etching (RIE). The micro-loading effect is a phenomenon that leads to different etching depths depending on the aperture size of the mask layer used in etching. We fabricated an aspheric micro-lens mold for the prototype by using the proposed method after experimental evaluations of the micro-loading effect for a feasibility study. The profile of the first prototype was slightly different from the designed one according as the distance from the lens center increase. The profile error of the second prototype was reduced by using a mask that had multiple apertures with the smallest aperture located outside the area where the crater was formed. Our proposed method was found to be effective for fabricating a micro-lens mold with an arbitrary aspheric surface and high aspect ratio.

  20. Design and Analyses of High Aspect Ratio Nozzles for Distributed Propulsion Acoustic Measurements

    Science.gov (United States)

    Dippold, Vance F., III

    2016-01-01

    A series of three convergent round-to-rectangular high-aspect ratio nozzles were designed for acoustics measurements. The nozzles have exit area aspect ratios of 8:1, 12:1, and 16:1. With septa inserts, these nozzles will mimic an array of distributed propulsion system nozzles, as found on hybrid wing-body aircraft concepts. Analyses were performed for the three nozzle designs and showed that the flow through the nozzles was free of separated flow and shocks. The exit flow was mostly uniform with the exception of a pair of vortices at each span-wise end of the nozzle.

  1. Proton beam writing and electroplating for the fabrication of high aspect ratio Au microstructures

    Energy Technology Data Exchange (ETDEWEB)

    Yue Weisheng [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Ren Yaping [Singapore Synchrotron Light Source, National University of Singapore, 5 Research Link, Singapore 117603 (Singapore); Kan, Jeroen Anton van; Chiam, S.-Y. [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Jian, Linke; Moser, Herbert O. [Singapore Synchrotron Light Source, National University of Singapore, 5 Research Link, Singapore 117603 (Singapore); Osipowicz, Thomas [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore)], E-mail: phyto@nus.edu.sg; Watt, Frank [Centre for Ion Beam Applications, Department of Physics, National University of Singapore, Singapore 117542 (Singapore)

    2009-07-01

    We present an approach to fabricate tall high aspect ratio Au microstructures by means of proton beam direct writing. Combining proton beam direct writing and electroplating, we successfully produced gold structures with sub-micrometer lateral dimensions, structure heights in excess of 11 {mu}m, and aspect ratios over 28. Sidewall quality of the Au structures was improved by lowering the process temperature to 20 deg. C when developing PMMA patterns with GG developer. The application of such structures as X-ray masks for deep X-ray lithography with synchrotron radiation was demonstrated.

  2. Fabrication of High Aspect Ratio SU-8 Structures for Integrated Spectrometers

    DEFF Research Database (Denmark)

    Anhøj, Thomas Aarøe

    2007-01-01

    of photolithography. Successful fabrication of re ection gratings requires a high degree of precision in the photolithographic process. The fabrication process has thus been optimized by optimizing the photolithographic process for fabrication of high aspect ratio structures, i.e. structures with details...... that are small compared to the height of the structure. A decisive factor is the ability of the process to separate closely- spaced structures. The primary measure of quality is thus the aspect ratio of the narrowest trench which it is possible to resolve in the lithographic process. The optimization...

  3. Electrolytic Manganese Dioxide Coatings on High Aspect Ratio Micro-Pillar Arrays for 3D Thin Film Lithium Ion Batteries

    Directory of Open Access Journals (Sweden)

    Yafa Zargouni

    2017-05-01

    Full Text Available In this work, we present the electrochemical deposition of manganese dioxide (MnO2 thin films on carbon-coated TiN/Si micro-pillars. The carbon buffer layer, grown by plasma enhanced chemical vapor deposition (PECVD, is used as a protective coating for the underlying TiN current collector from oxidation, during the film deposition, while improving the electrical conductivity of the stack. A conformal electrolytic MnO2 (EMD coating is successfully achieved on high aspect ratio C/TiN/Si pillar arrays by tailoring the deposition process. Lithiation/Delithiation cycling tests have been performed. Reversible insertion and extraction of Li+ through EMD structure are observed. The fabricated stack is thus considered as a good candidate not only for 3D micorbatteries but also for other energy storage applications.

  4. Nanometer scale high-aspect-ratio trench etching at controllable angles using ballistic reactive ion etching

    Energy Technology Data Exchange (ETDEWEB)

    Cybart, Shane; Roediger, Peter; Ulin-Avila, Erick; Wu, Stephen; Wong, Travis; Dynes, Robert

    2012-11-30

    We demonstrate a low pressure reactive ion etching process capable of patterning nanometer scale angled sidewalls and three dimensional structures in photoresist. At low pressure the plasma has a large dark space region where the etchant ions have very large highly-directional mean free paths. Mounting the sample entirely within this dark space allows for etching at angles relative to the cathode with minimal undercutting, resulting in high-aspect ratio nanometer scale angled features. By reversing the initial angle and performing a second etch we create three-dimensional mask profiles.

  5. Simulation and Measurement of Neuroelectrodes' Characteristics with Integrated High Aspect Ratio Nano Structures

    Directory of Open Access Journals (Sweden)

    Christoph Nick

    2015-07-01

    Full Text Available Improving the interface between electrodes and neurons has been the focus of research for the last decade. Neuroelectrodes should show small geometrical surface area and low impedance for measuring and high charge injection capacities for stimulation. Increasing the electrochemically active surface area by using nanoporous electrode material or by integrating nanostructures onto planar electrodes is a common approach to improve this interface. In this paper a simulation approach for neuro electrodes' characteristics with integrated high aspect ratio nano structures based on a point-contact-model is presented. The results are compared with experimental findings conducted with real nanostructured microelectrodes. In particular, effects of carbon nanotubes and gold nanowires integrated onto microelectrodes are described. Simulated and measured impedance properties are presented and its effects onto the transfer function between the neural membrane potential and the amplifier output signal are studied based on the point-contact-model. Simulations show, in good agreement with experimental results, that electrode impedances can be dramatically reduced by the integration of high aspect ratio nanostructures such as gold nanowires and carbon nanotubes. This lowers thermal noise and improves the signal-to-noise ratio for measuring electrodes. It also may increase the adhesion of cells to the substrate and thus increase measurable signal amplitudes.

  6. Micro precision casting based on investment casting for micro structures with high aspect ratio

    Institute of Scientific and Technical Information of China (English)

    YANG Chuang; LI Bang-sheng; REN Ming-xing; FU Heng-zhi

    2009-01-01

    Microcasting is one of the significant technologies for the production of metallic micro parts with high aspect ratio (ratio of flow length to diameter). A micro precision casting technology based on investment casting using centrifugal method was investigated. The micro parts of Zn-4%Al alloy with an aspect ratio up to 200 was produced at the centrifugal speed of 1 500 r/min and the mold temperature of 270 ℃. The investigations on the relationship between flow length and rotational speed were carried out. For microcasting, the flow length is not only dependent on the centrifugal speed under the constant centrifugal radius, but also on the preheating temperature of mold. The flow length increases as the rotational speed and the mold temperature increase, and is much higher at a mold temperature of 270 ℃ than at other mold temperatures.

  7. A simple method for fabrication of high-aspect-ratio all-silicon grooves

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Yuncan; Pan, An; Si, Jinhai, E-mail: jinhaisi@mail.xjtu.edu.cn; Chen, Tao; Chen, Feng; Hou, Xun

    2013-11-01

    A simple method using 800-nm femtosecond laser irradiation and chemical selective etching has been proposed for fabrication of high-aspect-ratio all-silicon grooves. Grooves with the maximum aspect ratio of 44 were produced. A scanning electronic microscopy equipped with an energy dispersive X-ray spectroscopy was employed to characterize the morphology and chemical composition of the grooves respectively. The formation mechanism of the grooves was attributed to the chemical reaction of the laser induced refractive index change microstructures and hydrofluoric acid solution. The dependences of the aspect ratio of the grooves on the laser irradiation parameters, such as: the numerical aperture of the microscope objective lens, the laser average power and the laser scanning velocity, are discussed.

  8. Aqueous solution route to high-aspect-ratio zinc oxide nanostructures on indium tin oxide substrates.

    Science.gov (United States)

    Ku, Chen-Hao; Wu, Jih-Jen

    2006-07-06

    High-aspect-ratio ZnO nanowires and nanotubes are formed on indium tin oxide (ITO) substrates using a three-step route at low temperatures. The three steps, including successive ionic layer absorption and reaction (SILAR) deposition of the ZnO seed layer, hydrothermal annealing of the seed layer, and chemical bath deposition (CBD) of the one-dimensional (1D) ZnO nanostructures, are all conducted in aqueous solutions at temperatures below 120 degrees C. Both the hydrothermal annealing of the SILAR seed layer and the low-concentration precursor solution employed in the CBD process are crucial in order to synthesize the uniform and high-aspect-ratio ZnO nanostructures on the ITO substrate. TEM analyses reveal that both the nanowire and the nanotube possess the single-crystal structure and are grown along [001] direction. Room-temperature cathodoluminescence spectrum of the 1D ZnO nanostructures shows a sharp ultraviolet emission at 375 nm and a broad green-band emission.

  9. High aspect ratio MEMS capacitor for high frequency impedance matching applications

    DEFF Research Database (Denmark)

    Yalcinkaya, Arda Deniz; Jensen, Søren; Hansen, Ole

    2003-01-01

    We present a microelectromechanical tunable capacitor with a low control voltage, a wide tuning range and adequate electrical quality factor. The device is fabricated in a single-crystalline silicon layer using deep reactive ion etching (DRIE) for obtaining high-aspect ratio (> 20) parallel comb-...... response and it was found that the device is a suitable passive component to be used in impedance matching applications, band-pass filtering or voltage controlled oscillators in the Very High Frequency (VHF) and Ultra High Frequency (UHF) bands.......We present a microelectromechanical tunable capacitor with a low control voltage, a wide tuning range and adequate electrical quality factor. The device is fabricated in a single-crystalline silicon layer using deep reactive ion etching (DRIE) for obtaining high-aspect ratio (> 20) parallel comb......-drive structures with vertical sidewalls. The process sequence for fabrication of the devices uses only one lithographic masking step and can be completed in a short time. The fabricated device was characterized with respect to electrical quality factor, tuning range, self-resonance frequency and transient...

  10. Combined AFM nano-machining and reactive ion etching to fabricate high aspect ratio structures.

    Science.gov (United States)

    Peng, Ping; Shi, Tielin; Liao, Guanglan; Tang, Zirong

    2010-11-01

    In this paper, a new combined method of sub-micron high aspect ratio structure fabrication is developed which can be used for production of nano imprint template. The process includes atomic force microscope (AFM) scratch nano-machining and reactive ion etching (RIE) fabrication. First, 40 nm aluminum film was deposited on the silicon substrate by magnetron sputtering, and then sub-micron grooves were fabricated on the aluminum film by nano scratch using AFM diamond tip. As aluminum film is a good mask for etching silicon, high aspect ratio structures were finally fabricated by RIE process. The fabricated structures were studied by SEM, which shows that the grooves are about 400 nm in width and 5 microm in depth. To obtain sub-micron scale groove structures on the aluminum film, experiments of nanomachining on aluminum films under various machining conditions were conducted. The depths of the grooves fabricated using different scratch loads were also studied by the AFM. The result shows that the material properties of the film/substrate are elastic-plastic following nearly a bilinear law with isotropic strain hardening. Combined AFM nanomachining and RIE process provides a relative lower cost nano fabrication technique than traditional e-beam lithography, and it has a good prospect in nano imprint template fabrication.

  11. Planarization of High Aspect Ratio P-I-N Diode Pillar Arrays for Blanket Electrical Contacts

    Energy Technology Data Exchange (ETDEWEB)

    Voss, L F; Shao, Q; Reinhardt, C E; Graff, R T; Conway, A M; Nikolic, R J; Deo, N; Cheung, C L

    2009-03-05

    Two planarization techniques for high aspect ratio three dimensional pillar structured P-I-N diodes have been developed in order to enable a continuous coating of metal on the top of the structures. The first technique allows for coating of structures with topography through the use of a planarizing photoresist followed by RIE etch back to expose the tops of the pillar structure. The second technique also utilizes photoresist, but instead allows for planarization of a structure in which the pillars are filled and coated with a conformal coating by matching the etch rate of the photoresist to the underlying layers. These techniques enable deposition using either sputtering or electron beam evaporation of metal films to allow for electrical contact to the tops of the underlying pillar structure. These processes have potential applications for many devices comprised of 3-D high aspect ratio structures. Two separate processes have been developed in order to ensure a uniform surface for deposition of an electrode on the {sup 10}Boron filled P-I-N pillar structured diodes. Each uses S1518 photoresist in order to achieve a relatively uniform surface despite the non-uniformity of the underlying detector. Both processes allow for metallization of the final structure and provide good electrical continuity over a 3D pillar structure.

  12. Diffusion of dilute gas in arrays of randomly distributed, vertically aligned, high-aspect-ratio cylinders

    Science.gov (United States)

    Guerra, Carlos

    2017-01-01

    In this work we modelled the diffusive transport of a dilute gas along arrays of randomly distributed, vertically aligned nanocylinders (nanotubes or nanowires) as opposed to gas diffusion in long pores, which is described by the well-known Knudsen theory. Analytical expressions for (i) the gas diffusion coefficient inside such arrays, (ii) the time between collisions of molecules with the nanocylinder walls (mean time of flight), (iii) the surface impingement rate, and (iv) the Knudsen number of such a system were rigidly derived based on a random-walk model of a molecule that undergoes memoryless, diffusive reflections from nanocylinder walls assuming the molecular regime of gas transport. It can be specifically shown that the gas diffusion coefficient inside such arrays is inversely proportional to the areal density of cylinders and their mean diameter. An example calculation of a diffusion coefficient is delivered for a system of titanium isopropoxide molecules diffusing between vertically aligned carbon nanotubes. Our findings are important for the correct modelling and optimisation of gas-based deposition techniques, such as atomic layer deposition or chemical vapour deposition, frequently used for surface functionalisation of high-aspect-ratio nanocylinder arrays in solar cells and energy storage applications. Furthermore, gas sensing devices with high-aspect-ratio nanocylinder arrays and the growth of vertically aligned carbon nanotubes need the fundamental understanding and precise modelling of gas transport to optimise such processes. PMID:28144565

  13. Characterization of the optical parameters of high aspect ratio polymer micro-optical components

    Science.gov (United States)

    Krajewski, Rafal; Van Erps, Jurgen; Wissmann, Markus; Kujawinska, Malgorzata; Parriaux, Olivier; Tonchev, S.; Mohr, Jurgen; Thienpont, Hugo

    2008-04-01

    Over the last decades the significant grow of interest of photonics devices is observed in various fields of applications. Due to the market demands, the current research studies are focused on the technologies providing miniaturized, reliable low-cost micro-optical systems, particularly the ones featuring the fabrication of high aspect ratio structures. A high potential of these technologies comes from the fact that fabrication process is not limited to single optical components, but entire systems integrating sets of elements could be fabricated. This could in turn result in a significant saving on the assembly and packaging costs. We present a brief overview of the most common high aspect ratio fabrication technologies for micro-optical components followed by some characterization studies of these techniques. The sidewall quality and internal homogeneity will be considered as the most crucial parameters, having an impact on the wavefront propagation in the fabricated components. We show the characterization procedure and measurement results for components prototyped with Deep Proton Writing and glass micromachining technology replicated with Hot Embossing and Elastomeric Mould Vacuum Casting technology. We discuss the pros and cons for using these technologies for the production of miniaturized interferometers blocks. In this paper we present the status of our research on the new technology chain and we show the concept of microinterferometers to be fabricated within presented technology chain.

  14. A sub-atmospheric chemical vapor deposition process for deposition of oxide liner in high aspect ratio through silicon vias.

    Science.gov (United States)

    Lisker, Marco; Marschmeyer, Steffen; Kaynak, Mehmet; Tekin, Ibrahim

    2011-09-01

    The formation of a Through Silicon Via (TSV) includes a deep Si trench etching and the formation of an insulating layer along the high-aspect-ratio trench and the filling of a conductive material into the via hole. The isolation of the filling conductor from the silicon substrate becomes more important for higher frequencies due to the high coupling of the signal to the silicon. The importance of the oxide thickness on the via wall isolation can be verified using electromagnetic field simulators. To satisfy the needs on the Silicon dioxide deposition, a sub-atmospheric chemical vapor deposition (SA-CVD) process has been developed to deposit an isolation oxide to the walls of deep silicon trenches. The technique provides excellent step coverage of the 100 microm depth silicon trenches with the high aspect ratio of 20 and more. The developed technique allows covering the deep silicon trenches by oxide and makes the high isolation of TSVs from silicon substrate feasible which is the key factor for the performance of TSVs for mm-wave 3D packaging.

  15. Hybrid UV Lithography for 3D High-Aspect-Ratio Microstructures

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sungmin; Nam, Gyungmok; Kim, Jonghun; Yoon, Sang-Hee [Inha Univ, Incheon (Korea, Republic of)

    2016-08-15

    Three-dimensional (3D) high-aspect-ratio (HAR) microstructures for biomedical applications (e.g., microneedle, microadhesive, etc.) are microfabricated using the hybrid ultraviolet (UV) lithography in which inclined, rotational, and reverse-side UV exposure processes are combined together. The inclined and rotational UV exposure processes are intended to fabricate tapered axisymmetric HAR microstructures; the reverse-side UV exposure process is designed to sharpen the end tip of the microstructures by suppressing the UV reflection on a bottom substrate which is inevitable in conventional UV lithography. Hybrid UV lithography involves fabricating 3D HAR microstructures with an epoxy-based negative photoresist, SU-8, using our customized UV exposure system. The effects of hybrid UV lithography parameters on the geometry of the 3D HAR microstructures (aspect ratio, radius of curvature of the end tip, etc.) are measured. The dependence of the end-tip shape on SU-8 soft-baking condition is also discussed.

  16. Maintaining high-Q in an optical microresonator coated with high-aspect-ratio gold nanorods

    Science.gov (United States)

    Ganta, D.; Dale, E. B.; Rosenberger, A. T.

    2013-10-01

    We report methods to coat fused-silica microresonators with solution-grown high-aspect-ratio (AR) gold nanorods (NRs). Microresonators coated using our method maintain an optical quality factor (Q) greater than 107 after coating. The more successful method involves silanization of the surface of the microresonator with 3-mercaptopropylmethyldimethoxysilane (MPMDMS), to enable the adhesion of gold NRs. The high-AR NR-coated microresonator combines the field enhancement of localized surface plasmon resonances with the cavity-enhanced evanescent components of high-Q whispering-gallery modes, making it useful for plasmonic sensing applications in the infrared. By coating with NRs having a different aspect ratio, the enhancement regime can be selected within a wide range of wavelengths.

  17. Pilot Study of Inhaled Aerosols Targeted via Magnetic Alignment of High Aspect Ratio Particles in Rabbits

    Directory of Open Access Journals (Sweden)

    Gillian E. S. Redman

    2011-01-01

    Full Text Available Recently, inhaled pharmaceutical aerosols have seen increased investigation in the treatment of lung cancer, where the inability to deliver adequate therapeutic drug concentrations to tumour sites may be overcome with improved targeted delivery to the site of the tumour. In this study, the feasibility of magnetically targeted delivery of high aspect ratio particles loaded with iron oxide nanoparticles was studied in 19 New Zealand White rabbits. Half of the exposed rabbits had a magnetic field placed externally over their right lung. Iron sensitive magnetic resonance images of the lungs were acquired to determine the iron concentrations in the right and left lung of each animal. The right/left ratio increased in the middle and basal regions of the lung where, due to the morphology of the rabbit lung, this method of targeting is most effective. With further optimization, this technique could be an effective method for increasing the dose of drug delivered to a specific site within the lung.

  18. Multiscale Domain Decomposition Methods for Elliptic Problems with High Aspect Ratios

    Institute of Scientific and Technical Information of China (English)

    Jфrg Aarnes; Thomas Y. Hou

    2002-01-01

    In this paper we study some nonoverlapping domain decomposition methods for solving a class of elliptic problems arising from composite materials and flows in porous media which contain many spatial scales. Our preconditioner differs from traditional domain decomposition preconditioners by using a coarse solver which is adaptive to small scale heterogeneous features. While the convergence rate of traditional domain decomposition algorithms using coarse solvers based on linear or polynomial interpolations may deteriorate in the presence of rapid small scale oscillations or high aspect ratios, our preconditioner is applicable to multiplescale problems without restrictive assumptions and seems to have a convergence rate nearly independent of the aspect ratio within the substructures. A rigorous convergence analysis based on the Schwarz framework is carried out, and we demonstrate the efficiency and robustness of the proposed preconditioner through numerical experiments which include problems with multiple-scale coefficients, as well problems with continuous scales.

  19. Different methods to alter surface morphology of high aspect ratio structures

    Science.gov (United States)

    Leber, M.; Shandhi, M. M. H.; Hogan, A.; Solzbacher, F.; Bhandari, R.; Negi, S.

    2016-03-01

    In various applications such as neural prostheses or solar cells, there is a need to alter the surface morphology of high aspect ratio structures so that the real surface area is greater than geometrical area. The change in surface morphology enhances the devices functionality. One of the applications of altering the surface morphology is of neural implants such as the Utah electrode array (UEA) that communicate with single neurons by charge injection induced stimulation or by recording electrical neural signals. For high selectivity between single cells of the nervous system, the electrode surface area is required to be as small as possible, while the impedance is required to be as low as possible for good signal to noise ratios (SNR) during neural recording. For stimulation, high charge injection and charge transfer capacities of the electrodes are required, which increase with the electrode surface. Traditionally, researchers have worked with either increasing the roughness of the existing metallization (platinum grey, black) or other materials such as Iridium Oxide and PEDOT. All of these previously investigated methods lead to more complicated metal deposition processes that are difficult to control and often have a critical impact on the mechanical properties of the metal films. Therefore, a modification of the surface underneath the electrode's coating will increase its surface area while maintaining the standard and well controlled metal deposition process. In this work, the surfaces of the silicon micro-needles were engineered by creating a defined microstructure on the electrodes surface using several methods such as laser ablation, focused ion beam, sputter etching, reactive ion etching (RIE) and deep reactive ion etching (DRIE). The surface modification processes were optimized for the high aspect ratio silicon structures of the UEA. The increase in real surface area while maintaining the geometrical surface area was verified using scanning electron

  20. High yield polyol synthesis of round- and sharp-end silver nanowires with high aspect ratio

    Energy Technology Data Exchange (ETDEWEB)

    Nekahi, A.; Marashi, S.P.H., E-mail: pmarashi@aut.ac.ir; Fatmesari, D. Haghshenas

    2016-12-01

    Long silver nanowires (average length of 28 μm, average aspect ratio of 130) with uniform diameter along their length were produced by polyol synthesis of AgNO{sub 3} in ethylene glycol in the presence of PVP as preferential growth agent. Nanowires were produced with no addition of chloride salts such as NaCl or CuCl{sub 2} (or other additives such as Na{sub 2}S) which are usually used for lowering reduction rate of Ag ions by additional etchant of O{sub 2}/Cl{sup −}. Lower reduction rate was obtained by increasing the injection time of PVP and AgNO{sub 3} solutions, which was the significant factor in the formation of nanowires. Therefore, there was enough time for reduced Ag atoms to be deposited preferentially in the direction of PVP chains, resulting in high yield (the fraction of nanowires in the products) of nanowires (more than 95%) with high aspect ratio. The produced nanowires had both round- and sharp-ends with pentagonal cross section. Higher energy level of Ag atoms in borders of MTPs, which increases the dissolution rate of precipitated atoms, in addition to partial melting of MTPs at high synthesis temperatures, leads to the curving of the surfaces of exposed (111) crystalline planes in some MTPs and the formation of round-end silver nanowires. - Highlights: • Long silver nanowires with high aspect ratio of 130 were produced. • More than 95% nanowires were produced in products. • The produced nanowires had round- and sharp-ends with pentagonal cross section. • Additives were needed neither for high yield synthesis nor for round-end nanowires. • Melting and etching of MTPs in high energy borders resulted to round-end nanowires.

  1. Gust response analysis and wind tunnel test for a high-aspect ratio wing

    Directory of Open Access Journals (Sweden)

    Liu Yi

    2016-02-01

    Full Text Available A theoretical nonlinear aeroelastic response analysis for a flexible high-aspect ratio wing excited by harmonic gust load is presented along with a companion wind tunnel test. A multidisciplinary coupled numerical calculation is developed to simulate the flexible model wing undergoing gust load in the time domain via discrete nonlinear finite element structural dynamic analysis and nonplanar unsteady vortex lattice aerodynamic computation. A dynamic perturbation analysis about a nonlinear static equilibrium is also used to determine the small perturbation flutter boundary. A novel noncontact 3-D camera measurement analysis system is firstly used in the wind tunnel test to obtain the spatial large deformation and responses. The responses of the flexible wing under different static equilibrium states and frequency gust loads are discussed. The fair to good quantitative agreements between the theoretical and experimental results demonstrate that the presented analysis method is an acceptable way to predict the geometrically nonlinear gust response for flexible wings.

  2. The Capabilities of Electrodischarge Microdrilling of High Aspect Ratio Holes in Ceramic Materials

    Directory of Open Access Journals (Sweden)

    Skoczypiec Sebastian

    2015-09-01

    Full Text Available In the first part of the article the review of ceramic materials drilling possibilities was presented. Among the described methods special attention is paid to electrodischarge drilling. This process have especially been predicted for machining difficult-to-cut electrically conductive materials. The second part consist of the results analysis of electrodischarge microdrilling of siliconized silicon carbide. The experiment involves the impact of current amplitude, discharge voltage and pulse time on the hole depth, side gap, linear tool wear and mean drilling speed. The results shows that electrodischarge drilling is a good alternative when machining inhomogeneous ceramic materials and gives possibility to drill high aspect ratio holes with relatively high efficiency (the drilling speed >2 mm/min.

  3. Measurement and simulation of jet mass caused by a high-aspect ratio pertubation

    Energy Technology Data Exchange (ETDEWEB)

    Keiter, Paul A [Los Alamos National Laboratory; Cooley, James [Los Alamos National Laboratory; Kyrala, George [Los Alamos National Laboratory; Wilson, Doug [Los Alamos National Laboratory; Blue, Brent [LLNL/GA; Elliott, Jim [LLNL; Edwards, John [LLNL; Robey, Harry [LLNL; Spears, Brian [LLNL

    2009-01-01

    Inertial confinement fusion (ICF) capsule performance can be negatively impacted by the presence of hydrodynamic instabilities. To perform a gas fill on an ICF capsule current plans involve drilling a small hole and inserting a fill tube to inject the gas mixture into the capsule. This introduces a perturbation on the capsule, which can seed hydrodynamic instabilities. The small hole can cause jetting of the shell material into the gas, which might adversely affect the capsule performance. We have performed simulations and experiments to study the hydrodynamic evolution of jets from high-aspect ratio holes, such as the fill tube hole. Although simulations using cold materials over predict the amount of mass in the jet, when a reasonable amount of preheat (< 1 eV) is introduced, the simulations are in better agreement with the experiment.

  4. Measurement and simulation of jet mass caused by a high-aspect ratio hole perturbation

    Energy Technology Data Exchange (ETDEWEB)

    Keiter, Paul A [Los Alamos National Laboratory; Cooley, James H [Los Alamos National Laboratory; Wilson, D C [Los Alamos National Laboratory; Kyrala, George A [Los Alamos National Laboratory; Blue, Brent E [LLNL; Edwards, J [LLNL; Elliott, James B [LLNL; Robey, H F [LLNL; Spears, B [Los Alamos National Laboratory

    2009-01-01

    Inertial confinement fusion (ICF) capsule performance can be negatively impacted by the presence of hydrodynamic instabilities. To perform a gas fill on an ICF capsule, current plans involve drilling a small hole and inserting a fill tube to inject the gas mixture into the capsule. This introduces a perturbation on the capsule, which can seed hydrodynamic instabilities. The small hole can cause jetting of the shell material into the gas, which might adversely affect the capsule performance. We have performed simulations and experiments to study the hydrodynamic evolution of jets from high-aspect ratio holes, such as the fill tube hole. Although simulations using cold materials overpredict the amount of mass in the jet, when a reasonable amount of preheat (<1 eV) is introduced, the simulations are in better agreement with the experiment.

  5. A new multifunctional platform based on high aspect ratio interdigitated NEMS structures

    Energy Technology Data Exchange (ETDEWEB)

    Ghatnekar-Nilsson, S; Karlsson, I; Kvennefors, A; Luo, G; Zela, V; Parker, T; Litwin, A [NEMS AB, Solvegatan 16, S-223 62 Lund (Sweden); Arlelid, M [Electrical and Information Technology, Lund University, PO Box 118, S-221 00 Lund (Sweden); Montelius, L [Solid State Physics/The Nanometer Structure Consortium, Lund University, PO Box 118, S-221 00 Lund (Sweden)], E-mail: andrej.litwin@nems.se

    2009-04-29

    A multifunctional NEMS platform based on a mass-producible, surface relief grating has been developed and fabricated directly in polymer materials. The pattern consists of high aspect ratio interdigitated nanometer-sized pairs of walls and can be produced in a low-complexity one-step patterning process with nanoimprint lithography. In this paper, we demonstrate the usefulness of the platform primarily by showing an application as a high-sensitivity mass sensor in air. The sensors, which are based on the high frequency resonant response of around 200 MHz, show a mass responsivity of the order of 0.1 Hz/zg per wall at room temperature and in ambient air. Their ability to selectively adsorb airborne target molecules, such as thiols, is also demonstrated. We also show that the same device can function as a varactor for electronic circuits based on its large tunable capacitive range.

  6. A new multifunctional platform based on high aspect ratio interdigitated NEMS structures.

    Science.gov (United States)

    Ghatnekar-Nilsson, S; Karlsson, I; Kvennefors, A; Luo, G; Zela, V; Arlelid, M; Parker, T; Montelius, L; Litwin, A

    2009-04-29

    A multifunctional NEMS platform based on a mass-producible, surface relief grating has been developed and fabricated directly in polymer materials. The pattern consists of high aspect ratio interdigitated nanometer-sized pairs of walls and can be produced in a low-complexity one-step patterning process with nanoimprint lithography. In this paper, we demonstrate the usefulness of the platform primarily by showing an application as a high-sensitivity mass sensor in air. The sensors, which are based on the high frequency resonant response of around 200 MHz, show a mass responsivity of the order of 0.1 Hz/zg per wall at room temperature and in ambient air. Their ability to selectively adsorb airborne target molecules, such as thiols, is also demonstrated. We also show that the same device can function as a varactor for electronic circuits based on its large tunable capacitive range.

  7. Dynamics of polymer nanoparticles through a single artificial nanopore with a high-aspect-ratio.

    Science.gov (United States)

    Cabello-Aguilar, Simon; Chaaya, Adib Abou; Bechelany, Mikhael; Pochat-Bohatier, Céline; Balanzat, Emmanuel; Janot, Jean-Marc; Miele, Philippe; Balme, Sébastien

    2014-11-14

    The development of nanometric Coulter counters for nanoparticle detection is an attractive and promising field of research. In this work, we have studied the influence of the nanopore surface state on charged polymer nanoparticle translocations. To make this, the translocation of carboxylate modified polystyrene microspheres (diameter 40, 70 and 100 nm) has been investigated through two kinds of high aspect ratio nanopores (negative and uncharged). The latter were tailored by a single track-etched and atomic layer deposition technique. It was shown that the mobility and the energy barrier are strongly dependent on nanopore surface charge. Typically if the latter exhibits negative surface charge, the microsphere mobility increases and the global energy barrier of entrance inside the nanopore decreases with its diameter, converse to the uncharged nanopore.

  8. Surface-diffusion-driven decay of high-aspect-ratio gratings: existence of morphologically related classes.

    Science.gov (United States)

    Madrid, Marcos A; Salvarezza, Roberto C; Castez, Marcos F

    2013-06-01

    We present numerical and theoretical results concerning the technologically important process of evolution of high-aspect-ratio profiles due to surface diffusion under thermal treatment. We show how a broad class of initial gratings adopt, after a short transient stage, a typical shape that can be accurately described as a curve whose curvature has only two single Fourier modes as a function of the arc-length parameter. Moreover, we introduce a set of evolution equations for the relevant parameters that accounts very accurately for both morphological and kinetic aspects of the transformation processes for these curves in a wide region in parameter space. Regarding the decay of rectangular gratings, our numerical results show the existence of geometrically related classes that asymptotically approach to the same trajectory in parameter space. Gratings belonging to the same class pass through the same sequence of morphologies before reaching the final equilibrium state.

  9. A wearable, highly stable, strain and bending sensor based on high aspect ratio graphite nanobelts

    Science.gov (United States)

    Alaferdov, A. V.; Savu, R.; Rackauskas, T. A.; Rackauskas, S.; Canesqui, M. A.; de Lara, D. S.; Setti, G. O.; Joanni, E.; de Trindade, G. M.; Lima, U. B.; de Souza, A. S.; Moshkalev, S. A.

    2016-09-01

    A simple and scalable method was developed for the fabrication of wearable strain and bending sensors, based on high aspect ratio (length/thickness ˜103) graphite nanobelt thin films deposited by a modified Langmuir-Blodgett technique onto flexible polymer substrates. The sensing mechanism is based on the changes in contact resistance between individual nanobelts upon substrate deformation. Very high sensor response stability for more than 5000 strain-release cycles and a device power consumption as low as 1 nW were achieved. The device maximum stretchability is limited by the metal electrodes and the polymer substrate; the maximum strain that could be applied to the polymer used in this work was 40%. Bending tests carried out for various radii of curvature demonstrated distinct sensor responses for positive and negative curvatures. The graphite nanobelt thin flexible films were successfully tested for acoustic vibration and heartbeat sensing.

  10. Design and Simulation of BTT Missile with High-Aspect-Ratio Wing Robust H∞ Autopilot

    Institute of Scientific and Technical Information of China (English)

    CUI Sheng-wang; LIU Li; MA Chun-yan

    2007-01-01

    For the strong coupling among the channels of bank-to-turn (BTT) missile with high-aspect-ratio wing,an autopilot is designed with a two loop control structure robust autopilot design methods.By the inner loop design,the question of pole-zero cancellation is solved,and the stabilization of structured uncertainty is achieved.Through the outer loop of H∞ controller design,the flying performance and robustness can be guaranteed.The nonlinear simulation results show that the autopilot designed has perfect time domain response,and can suppress bad influence of the inertial and kinematics couplings.It can make the missile fly stably in the large flying areas.The control is very effective.

  11. Large-area thermoelectric high-aspect-ratio nanostructures by atomic layer deposition

    Science.gov (United States)

    Ruoho, Mikko; Juntunen, Taneli; Tittonen, Ilkka

    2016-09-01

    We report on the thermoelectric properties of large-area high-aspect-ratio nanostructures. We fabricate the structures by atomic layer deposition of conformal ZnO thin films on track-etched polycarbonate substrate. The resulting structure consists of ZnO tubules which continue through the full thickness of the substrate. The electrical and thermal properties of the structures are studied both in-plane and out-of-plane. They exhibit very low out-of-plane thermal conductivity down to 0.15 W m-1 K-1 while the in-plane sheet resistance of the films was found to be half that of the same film on glass substrate, allowing material-independent doubling of output power of any planar thin-film thermoelectric generator. The wall thickness of the fabricated nanotubes was varied within a range of up to 100 nm. The samples show polycrystalline nature with (002) preferred crystal orientation.

  12. Tailoring femtosecond 1.5-μm Bessel beams for manufacturing high-aspect-ratio through-silicon vias.

    Science.gov (United States)

    He, Fei; Yu, Junjie; Tan, Yuanxin; Chu, Wei; Zhou, Changhe; Cheng, Ya; Sugioka, Koji

    2017-01-18

    Three-dimensional integrated circuits (3D ICs) are an attractive replacement for conventional 2D ICs as high-performance, low-power-consumption, and small-footprint microelectronic devices. However, one of the major remaining challenges is the manufacture of high-aspect-ratio through-silicon vias (TSVs), which is a crucial technology for the assembly of 3D Si ICs. Here, we present the fabrication of high-quality TSVs using a femtosecond (fs) 1.5-μm Bessel beam. To eliminate the severe ablation caused by the sidelobes of a conventional Bessel beam, a fs Bessel beam is tailored using a specially designed binary phase plate. We demonstrate that the tailored fs Bessel beam can be used to fabricate a 2D array of approximately ∅10-μm TSVs on a 100-μm-thick Si substrate without any sidelobe damage, suggesting potential application in the 3D assembly of 3D Si ICs.

  13. Tailoring femtosecond 1.5-μm Bessel beams for manufacturing high-aspect-ratio through-silicon vias

    Science.gov (United States)

    He, Fei; Yu, Junjie; Tan, Yuanxin; Chu, Wei; Zhou, Changhe; Cheng, Ya; Sugioka, Koji

    2017-01-01

    Three-dimensional integrated circuits (3D ICs) are an attractive replacement for conventional 2D ICs as high-performance, low-power-consumption, and small-footprint microelectronic devices. However, one of the major remaining challenges is the manufacture of high-aspect-ratio through-silicon vias (TSVs), which is a crucial technology for the assembly of 3D Si ICs. Here, we present the fabrication of high-quality TSVs using a femtosecond (fs) 1.5-μm Bessel beam. To eliminate the severe ablation caused by the sidelobes of a conventional Bessel beam, a fs Bessel beam is tailored using a specially designed binary phase plate. We demonstrate that the tailored fs Bessel beam can be used to fabricate a 2D array of approximately ∅10-μm TSVs on a 100-μm-thick Si substrate without any sidelobe damage, suggesting potential application in the 3D assembly of 3D Si ICs. PMID:28098250

  14. Plasma-assisted atomic layer deposition of conformal Pt films in high aspect ratio trenches

    Science.gov (United States)

    Erkens, I. J. M.; Verheijen, M. A.; Knoops, H. C. M.; Keuning, W.; Roozeboom, F.; Kessels, W. M. M.

    2017-02-01

    To date, conventional thermal atomic layer deposition (ALD) has been the method of choice to deposit high-quality Pt thin films grown typically from (MeCp)PtMe3 vapor and O2 gas at 300 °C. Plasma-assisted ALD of Pt using O2 plasma can offer several advantages over thermal ALD, such as faster nucleation and deposition at lower temperatures. In this work, it is demonstrated that plasma-assisted ALD at 300 °C also allows for the deposition of highly conformal Pt films in trenches with high aspect ratio ranging from 3 to 34. Scanning electron microscopy inspection revealed that the conformality of the deposited Pt films was 100% in trenches with aspect ratio (AR) up to 34. These results were corroborated by high-precision layer thickness measurements by transmission electron microscopy for trenches with an aspect ratio of 22. The role of the surface recombination of O-radicals and the contribution of thermal ALD reactions is discussed.

  15. Wet Etched High Aspect Ratio Microstructures on Quartz for MEMS Applications

    Science.gov (United States)

    Liang, Jinxing; Kohsaka, Fusao; Matsuo, Takahiro; Ueda, Toshitsugu

    Z cut α-quartz wafers were etched in saturated ammonium bifluoride solution at 87 degrees C. The side wall profiles were observed using the scanning electron microscopy (SEM) and plotted dependent on the polar direction. This research focused on investigating high aspect ratio trench and through-hole, which were dependent on the polar direction to the crystal axis. Aspect ratio in dependence on polar direction was also plotted and microchannels with aspect ratio > 3 could be achieved at the polar angle between 30° to 60°. The possibility of application for microcapillary was discussed, and the trench at 45° was considered best. Double-sided etching technique was used for manufacturing through-hole structures. Through-hole at 0° was demonstrated effective for fabrication of capacitive MEMS tilt sensor. Through-holes at 15° and 105° were proposed for fabrication of 90°-arranged two axis capactive tilt sensor, taking advantage of the twofold symmetry property around X axis and threefold symmetry property around Z axis.

  16. Nanofabrication of high aspect ratio structures using an evaporated resist containing metal

    Science.gov (United States)

    Con, Celal; Zhang, Jian; Cui, Bo

    2014-05-01

    Organic electron beam resists are typically not resistant to the plasma etching employed to transfer the pattern into the underlying layer. Here, the authors present the incorporation of a metal hard mask material into negative resist polystyrene by co-evaporation of the polystyrene and the metal onto a substrate. With a volume ratio of 1:15 between Cr and polystyrene, this nanocomposite resist showed an etching selectivity to silicon one order higher than pure polystyrene resist. Silicon structures of 100 nm width and 3.5 μm height (aspect ratio 1:35) were obtained using a non-switching deep silicon etching recipe with SF6 and C4F8 gas. Moreover, unlike the common spin coating method, evaporated nanocomposite resist can be coated onto irregular and non-flat surfaces such as optical fibers and AFM cantilevers. As a proof of concept, we fabricated high aspect ratio structures on top of an AFM cantilever. Nanofabrication on non-flat surfaces may find applications in the fields of (AFM) tip enhanced Raman spectroscopy for chemical analysis and lab-on-fiber technology.

  17. Etching of Silicon in HBr Plasmas for High Aspect Ratio Features

    Science.gov (United States)

    Hwang, Helen H.; Meyyappan, M.; Mathad, G. S.; Ranade, R.

    2002-01-01

    Etching in semiconductor processing typically involves using halides because of the relatively fast rates. Bromine containing plasmas can generate high aspect ratio trenches, desirable for DRAM and MEMS applications, with relatively straight sidewalk We present scanning electron microscope images for silicon-etched trenches in a HBr plasma. Using a feature profile simulation, we show that the removal yield parameter, or number of neutrals removed per incident ion due to all processes (sputtering, spontaneous desorption, etc.), dictates the profile shape. We find that the profile becomes pinched off when the removal yield is a constant, with a maximum aspect ratio (AR) of about 5 to 1 (depth to height). When the removal yield decreases with increasing ion angle, the etch rate increases at the comers and the trench bottom broadens. The profiles have ARs of over 9:1 for yields that vary with ion angle. To match the experimentally observed etched time of 250 s for an AR of 9:1 with a trench width of 0.135 microns, we find that the neutral flux must be 3.336 x 10(exp 17)sq cm/s.

  18. Measuring ion velocity distribution functions through high-aspect ratio holes in inductively coupled plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Cunge, G., E-mail: gilles.cunge@cea.fr; Darnon, M.; Dubois, J.; Bezard, P.; Mourey, O.; Petit-Etienne, C.; Vallier, L.; Despiau-Pujo, E.; Sadeghi, N. [Laboratoire des Technologies de la Microélectronique, CNRS, 17 rue des Martyrs, 38054 Grenoble (France)

    2016-02-29

    Several issues associated with plasma etching of high aspect ratio structures originate from the ions' bombardment of the sidewalls of the feature. The off normal angle incident ions are primarily due to their temperature at the sheath edge and possibly to charging effects. We have measured the ion velocity distribution function (IVDF) at the wafer surface in an industrial inductively coupled plasma reactor by using multigrid retarding field analyzers (RFA) in front of which we place 400 μm thick capillary plates with holes of 25, 50, and 100 μm diameters. The RFA then probes IVDF at the exit of the holes with Aspect Ratios (AR) of 16, 8, and 4, respectively. The results show that the ion flux dramatically drops with the increase in AR. By comparing the measured IVDF with an analytical model, we concluded that the ion temperature is 0.27 eV in our plasma conditions. The charging effects are also observed and are shown to significantly reduce the ion energy at the bottom of the feature but only with a “minor” effect on the ion flux and the shape of the IVDF.

  19. Large-Area High Aspect Ratio Plasmonic Interference Lithography Utilizing a Single High-k Mode.

    Science.gov (United States)

    Chen, Xi; Yang, Fan; Zhang, Cheng; Zhou, Jing; Guo, L Jay

    2016-04-26

    Plasmonic lithography, which utilizes subwavelength confinement of surface plasmon polartion (SPP) waves, has the capability of breaking the diffraction limit and delivering high resolution. However, all previously reported results suffer from critical issues, such as shallow pattern depth and pattern nonuniformity even over small exposure areas, which limit the application of the technology. In this work, periodic patterns with high aspect ratios and a half-pitch of about 1/6 of the wavelength were achieved with pattern uniformity in square centimeter areas. This was accomplished by designing a special mask and photoresist (PR) system to select a single high spatial frequency mode and incorporating the PR into a waveguide configuration to ensure uniform light exposure over the entire depth of the photoresist layer. In addition to the experimental progress toward large-scale applications of plasmonic interference lithography, the general criteria of designing such an exposure system is also discussed, which can be used for nanoscale fabrication in this fashion for various applications with different requirements for wavelength, pitch, aspect ratio, and structure.

  20. Aerodynamic Properties of Rough Surfaces with High Aspect-Ratio Roughness Elements: Effect of Aspect Ratio and Arrangements

    Science.gov (United States)

    Sadique, Jasim; Yang, Xiang I. A.; Meneveau, Charles; Mittal, Rajat

    2017-05-01

    We examine the effect of varying roughness-element aspect ratio on the mean velocity distributions of turbulent flow over arrays of rectangular-prism-shaped elements. Large-eddy simulations (LES) in conjunction with a sharp-interface immersed boundary method are used to simulate spatially-growing turbulent boundary layers over these rough surfaces. Arrays of aligned and staggered rectangular roughness elements with aspect ratio >1 are considered. First the temporally- and spatially-averaged velocity profiles are used to illustrate the aspect-ratio effects. For aligned prisms, the roughness length (z_o) and the friction velocity (u_*) increase initially with an increase in the roughness-element aspect ratio, until the values reach a plateau at a particular aspect ratio. The exact value of this aspect ratio depends on the coverage density. Further increase in the aspect ratio changes neither z_o, u_* nor the bulk flow above the roughness elements. For the staggered cases, z_o and u_* continue to increase for the surface coverage density and the aspect ratios investigated. To model the flow response to variations in roughness aspect ratio, we turn to a previously developed phenomenological volumetric sheltering model (Yang et al., in J Fluid Mech 789:127-165, 2016), which was intended for low to moderate aspect-ratio roughness elements. Here, we extend this model to account for high aspect-ratio roughness elements. We find that for aligned cases, the model predicts strong mutual sheltering among the roughness elements, while the effect is much weaker for staggered cases. The model-predicted z_o and u_* agree well with the LES results. Results show that the model, which takes explicit account of the mutual sheltering effects, provides a rapid and reliable prediction method of roughness effects in turbulent boundary-layer flows over arrays of rectangular-prism roughness elements.

  1. A small perturbation based optimization approach for the frequency placement of high aspect ratio wings

    Science.gov (United States)

    Goltsch, Mandy

    Design denotes the transformation of an identified need to its physical embodiment in a traditionally iterative approach of trial and error. Conceptual design plays a prominent role but an almost infinite number of possible solutions at the outset of design necessitates fast evaluations. The corresponding practice of empirical equations and low fidelity analyses becomes obsolete in the light of novel concepts. Ever increasing system complexity and resource scarcity mandate new approaches to adequately capture system characteristics. Contemporary concerns in atmospheric science and homeland security created an operational need for unconventional configurations. Unmanned long endurance flight at high altitudes offers a unique showcase for the exploration of new design spaces and the incidental deficit of conceptual modeling and simulation capabilities. Structural and aerodynamic performance requirements necessitate light weight materials and high aspect ratio wings resulting in distinct structural and aeroelastic response characteristics that stand in close correlation with natural vibration modes. The present research effort evolves around the development of an efficient and accurate optimization algorithm for high aspect ratio wings subject to natural frequency constraints. Foundational corner stones are beam dimensional reduction and modal perturbation redesign. Local and global analyses inherent to the former suggest corresponding levels of local and global optimization. The present approach departs from this suggestion. It introduces local level surrogate models to capacitate a methodology that consists of multi level analyses feeding into a single level optimization. The innovative heart of the new algorithm originates in small perturbation theory. A sequence of small perturbation solutions allows the optimizer to make incremental movements within the design space. It enables a directed search that is free of costly gradients. System matrices are decomposed

  2. High aspect ratio AFM Probe processing by helium-ion-beam induced deposition.

    Science.gov (United States)

    Onishi, Keiko; Guo, Hongxuan; Nagano, Syoko; Fujita, Daisuke

    2014-11-01

    A Scanning Helium Ion Microscope (SHIM) is a high resolution surface observation instrument similar to a Scanning Electron Microscope (SEM) since both instruments employ finely focused particle beams of ions or electrons [1]. The apparent difference is that SHIMs can be used not only for a sub-nanometer scale resolution microscopic research, but also for the applications of very fine fabrication and direct lithography of surfaces at the nanoscale dimensions. On the other hand, atomic force microscope (AFM) is another type of high resolution microscopy which can measure a three-dimensional surface morphology by tracing a fine probe with a sharp tip apex on a specimen's surface.In order to measure highly uneven and concavo-convex surfaces by AFM, the probe of a high aspect ratio with a sharp tip is much more necessary than the probe of a general quadrangular pyramid shape. In this paper we report the manufacture of the probe tip of the high aspect ratio by ion-beam induced gas deposition using a nanoscale helium ion beam of SHIM.Gas of platinum organic compound was injected into the sample surface neighborhood in the vacuum chamber of SHIM. The decomposition of the gas and the precipitation of the involved metal brought up a platinum nano-object in a pillar shape on the normal commercial AFM probe tip. A SHIM system (Carl Zeiss, Orion Plus) equipped with the gas injection system (OmniProbe, OmniGIS) was used for the research. While the vacuum being kept to work, we injected platinum organic compound ((CH3)3(CH3C5H4)Pt) into the sample neighborhood and irradiated the helium ion beam with the shape of a point on the apex of the AFM probe tip. It is found that we can control the length of the Pt nano-pillar by irradiation time of the helium ion beam. The AFM probe which brought up a Pt nano-pillar is shown in Figure 1. It is revealed that a high-aspect-ratio Pt nano-pillar of ∼40nm diameter and up to ∼2000 nm length can be grown. In addition, for possible heating

  3. Nanoscale tomographic reconstruction of the subsurface mechanical properties of low-k high-aspect ratio patterns

    Science.gov (United States)

    Stan, Gheorghe; Mays, Ebony; Yoo, Hui Jae; King, Sean W.

    2016-12-01

    In this work, intermittent contact resonance atomic force microscopy (ICR-AFM) was performed on high-aspect ratio a-SiOC:H patterned fins (100 nm in height and width from 20 to 90 nm) to map the depth and width dependencies of the material stiffness. The spatial resolution and depth sensitivity of the measurements were assessed from tomographic cross-sections over various regions of interest within the 3D space of the measurements. Furthermore, the depth-dependence of the measured contact stiffness over the scanned area was used to determine the sub-surface variation of the elastic modulus at each point in the scan. This was achieved by iteratively adjusting the local elastic profile until the depth dependence of the resulted contact stiffness matched the depth dependence of the contact stiffness measured by ICR-AFM at that location. The results of this analysis were assembled into nanoscale sub-surface tomographic images of the elastic modulus of the investigated SiOC:H patterns. A new 3D structure-property representation emerged from these tomographic images with direct evidence for the alterations sustained by the structures during processing.

  4. Gust response analysis and wind tunnel test for a high-aspect ratio wing

    Institute of Scientific and Technical Information of China (English)

    Liu Yi; Xie Changchuan; Yang Chao; Cheng Jialin

    2016-01-01

    A theoretical nonlinear aeroelastic response analysis for a flexible high-aspect ratio wing excited by harmonic gust load is presented along with a companion wind tunnel test. A multidisci-plinary coupled numerical calculation is developed to simulate the flexible model wing undergoing gust load in the time domain via discrete nonlinear finite element structural dynamic analysis and nonplanar unsteady vortex lattice aerodynamic computation. A dynamic perturbation analysis about a nonlinear static equilibrium is also used to determine the small perturbation flutter bound-ary. A novel noncontact 3-D camera measurement analysis system is firstly used in the wind tunnel test to obtain the spatial large deformation and responses. The responses of the flexible wing under different static equilibrium states and frequency gust loads are discussed. The fair to good quanti-tative agreements between the theoretical and experimental results demonstrate that the presented analysis method is an acceptable way to predict the geometrically nonlinear gust response for flex-ible wings.

  5. Dimensional measurement of micro parts with high aspect ratio in HIT-UOI

    Science.gov (United States)

    Dang, Hong; Cui, Jiwen; Feng, Kunpeng; Li, Junying; Zhao, Shiyuan; Zhang, Haoran; Tan, Jiubin

    2016-11-01

    Micro parts with high aspect ratios have been widely used in different fields including aerospace and defense industries, while the dimensional measurement of these micro parts becomes a challenge in the field of precision measurement and instrument. To deal with this contradiction, several probes for the micro parts precision measurement have been proposed by researchers in Center of Ultra-precision Optoelectronic Instrument (UOI), Harbin Institute of Technology (HIT). In this paper, optical fiber probes with structures of spherical coupling(SC) with double optical fibers, micro focal-length collimation (MFL-collimation) and fiber Bragg grating (FBG) are described in detail. After introducing the sensing principles, both advantages and disadvantages of these probes are analyzed respectively. In order to improve the performances of these probes, several approaches are proposed. A two-dimensional orthogonal path arrangement is propounded to enhance the dimensional measurement ability of MFL-collimation probes, while a high resolution and response speed interrogation method based on differential method is used to improve the accuracy and dynamic characteristics of the FBG probes. The experiments for these special structural fiber probes are given with a focus on the characteristics of these probes, and engineering applications will also be presented to prove the availability of them. In order to improve the accuracy and the instantaneity of the engineering applications, several techniques are used in probe integration. The effectiveness of these fiber probes were therefore verified through both the analysis and experiments.

  6. Tunable Ultra-high Aspect Ratio Nanorod Architectures grown on Porous Substrate via Electromigration.

    Science.gov (United States)

    Mansourian, Ali; Paknejad, Seyed Amir; Wen, Qiannan; Vizcay-Barrena, Gema; Fleck, Roland A; Zayats, Anatoly V; Mannan, Samjid H

    2016-02-29

    The interplay between porosity and electromigration can be used to manipulate atoms resulting in mass fabrication of nanoscale structures. Electromigration usually results in the accumulation of atoms accompanied by protrusions at the anode and atomic depletion causing voids at the cathode. Here we show that in porous media the pattern of atomic deposition and depletion is altered such that atomic accumulation occurs over the whole surface and not just at the anode. The effect is explained by the interaction between atomic drift due to electric current and local temperature gradients resulting from intense Joule heating at constrictions between grains. Utilizing this effect, a porous silver substrate is used to mass produce free-standing silver nanorods with very high aspect ratios of more than 200 using current densities of the order of 10(8) A/m(2). This simple method results in reproducible formation of shaped nanorods, with independent control over their density and length. Consequently, complex patterns of high quality single crystal nanorods can be formed in-situ with significant advantages over competing methods of nanorod formation for plasmonics, energy storage and sensing applications.

  7. Analysis of Interrupted Rectangular Microchannel Heat Sink with High Aspect Ratio

    Directory of Open Access Journals (Sweden)

    Harshin Kamal

    2017-01-01

    Full Text Available A computational modelling of microchannel heat sinks with high aspect ratio has been performed to compare the geometrical features in the plane parallel to the heating surface and to determine the optimum configuration for the best heat transfer characteristics. A periodic thermal development of flow can cause significant heat transfer enhancement. A consensus on a particular geometrical configuration that provides the best heat transfer characteristics has not been reached in the literature, although many novel ideas have been proposed recently. Firstly the validity and applicability of microchannel sink modelling is presented followed by an optimization of parameters of interrupted microchannel heat sink. Consequences of the multichannel effect due to the introduction of transverse microchamber are also presented. It has been shown that the average Nusselt number of the microchannel heat sink increases by the introduction of a transverse microchamber with the additional advantage of a lower pressure drop. There exists an optimum width for the transverse microchamber for which the interrupted microchannel heat sink shows optimum characteristics.

  8. High-speed microprobe for roughness measurements in high-aspect-ratio microstructures

    Science.gov (United States)

    Doering, Lutz; Brand, Uwe; Bütefisch, Sebastian; Ahbe, Thomas; Weimann, Thomas; Peiner, Erwin; Frank, Thomas

    2017-03-01

    Cantilever-type silicon microprobes with an integrated tip and a piezoresistive signal read out have successfully proven to bridge the gap between scanning force microscopy and stylus profilometry. Roughness measurements in high-aspect-ratio microstructures (HARMS) with depths down to 5 mm and widths down to 50 µm have been demonstrated. To improve the scanning speed up to 15 mm s‑1, the wear of the tip has to be reduced. The atomic layer deposition (ALD) technique with alumina (Al2O3) has been tested for this purpose. Repeated wear measurements with coated and uncoated microprobe cantilevers have been carried out on a roughness standard at a speed of 15 mm s‑1. The tip shape and the wear have been measured using a new probing tip reference standard containing rectangular silicon grooves with widths from 0.3 µm to 3 µm. The penetration depth of the microprobe allows one to measure the wear of the tip as well as the tip width and the opening angle of the tip. The roughness parameters obtained on the roughness standard during wear experiments agree well with the reference values measured with a calibrated stylus instrument, nevertheless a small amount of wear still is observable. Further research is necessary in order to obtain wear resistant microprobe tips for non-destructive inspection of microstructures in industry and microform measurements, for example in injection nozzles.

  9. Gas-Assisted Heating Technology for High Aspect Ratio Microstructure Injection Molding

    Directory of Open Access Journals (Sweden)

    Shia-Chung Chen

    2013-01-01

    Full Text Available A hot gas is used for heating the cavity surface of a mold. Different mold gap sizes were designed. The mold surface temperature was heated to above the glass transition temperature of the plastic material, and the mold then closed for melt filling. The cavity surface can be heated to 130°C to assist the melt filling of the microfeatures. Results show that hot gas heating can improve the filling process and achieve 91% of the high aspect ratio microgrooves (about 640.38 μm of the maximum of 700 μm. The mold gap size strongly affects the heating speed and heating uniformity. Without surface preheating, the center rib is the highest. When the heating target temperature is 90°C or 100°C, the three microribs have a good uniformity of height. However, when the target temperature exceeds 100°C, the left side rib is higher than the other ribs.

  10. Bosch-like method for creating high aspect ratio poly(methyl methacrylate) (PMMA) structures

    KAUST Repository

    Haiducu, Marius

    2012-02-02

    This paper presents a method for etching millimetre-deep trenches in commercial grade PMMA using deep-UV at 254 nm. The method is based on consecutive cycles of irradiation and development of the exposed areas, respectively. The exposure segment is performed using an inexpensive, in-house built irradiation box while the development part is accomplished using an isopropyl alcohol (IPA):H2O developer. The method was tested and characterized by etching various dimension square test structures in commercial grade, mirrored acrylic. The undercut of the sidewalls due to the uncollimated nature of the irradiation light was dramatically alleviated by using a honeycomb metallic grid in between the irradiation source and the acrylic substrate and by rotating the latter using a direct current (DC) motor-driven stage. By using an extremely affordable set-up and non-toxic, environmentally friendly materials and substances, this process represents an excellent alternative to microfabricating microfluidic devices in particular and high aspect ratio structures in general using PMMA as substrate. © 2012 SPIE.

  11. Ultra-high aspect ratio copper nanowires as transparent conductive electrodes for dye sensitized solar cells

    Science.gov (United States)

    Zhu, Zhaozhao; Mankowski, Trent; Shikoh, Ali Sehpar; Touati, Farid; Benammar, Mohieddine A.; Mansuripur, Masud; Falco, Charles M.

    2016-09-01

    We report the synthesis of ultra-high aspect ratio copper nanowires (CuNW) and fabrication of CuNW-based transparent conductive electrodes (TCE) with high optical transmittance (>80%) and excellent sheet resistance (Rs zinc oxide (AZO) thin-film coatings, or platinum thin film coatings, or nickel thin-film coatings. Our hybrid transparent electrodes can replace indium tin oxide (ITO) films in dye-sensitized solar cells (DSSCs) as either anodes or cathodes. We highlight the challenges of integrating bare CuNWs into DSSCs, and demonstrate that hybridization renders the solar cell integrations feasible. The CuNW/AZO-based DSSCs have reasonably good open-circuit voltage (Voc = 720 mV) and short-circuit current-density (Jsc = 0.96 mA/cm2), which are comparable to what is obtained with an ITO-based DSSC fabricated with a similar process. Our CuNW-Ni based DSSCs exhibit a good open-circuit voltage (Voc = 782 mV) and a decent short-circuit current (Jsc = 3.96 mA/cm2), with roughly 1.5% optical-to-electrical conversion efficiency.

  12. Atomic Layer Deposition for Coating of High Aspect Ratio TiO2 Nanotube Layers

    Science.gov (United States)

    2016-01-01

    We present an optimized approach for the deposition of Al2O3 (as a model secondary material) coating into high aspect ratio (≈180) anodic TiO2 nanotube layers using the atomic layer deposition (ALD) process. In order to study the influence of the diffusion of the Al2O3 precursors on the resulting coating thickness, ALD processes with different exposure times (i.e., 0.5, 2, 5, and 10 s) of the trimethylaluminum (TMA) precursor were performed. Uniform coating of the nanotube interiors was achieved with longer exposure times (5 and 10 s), as verified by detailed scanning electron microscopy analysis. Quartz crystal microbalance measurements were used to monitor the deposition process and its particular features due to the tube diameter gradient. Finally, theoretical calculations were performed to calculate the minimum precursor exposure time to attain uniform coating. Theoretical values on the diffusion regime matched with the experimental results and helped to obtain valuable information for further optimization of ALD coating processes. The presented approach provides a straightforward solution toward the development of many novel devices, based on a high surface area interface between TiO2 nanotubes and a secondary material (such as Al2O3). PMID:27643411

  13. High-Aspect Ratio Bio-Metallic Nanocomposites for Cellular Interactions

    Science.gov (United States)

    Deodhar, Sneha; Huckaby, Justin; Delahoussaye, Miles; DeCoster, Mark A.

    2014-08-01

    We synthesized high aspect ratio composites with biological and metal components. Scanning electron microscopy (SEM) and Transmission Electron Microscopy (TEM) revealed linear morphology and smooth surface texture. SEM, TEM and light microscopy showed that composites have scalable dimensions from nano- to micro-, with diameters as low as 60 nm, lengths exceeding 150 pm, and average aspect ratio of 100. The structures are stable, remaining intact for over one year in dried form and in liquid, and did not aggregate, in contrast to metal nanoparticles such as iron and copper. Many metal nanoparticles are toxic to cells, limiting their use for biological applications. The bio-metallic composites characterized here showed lower toxicity compared to their precursor metal nanoparticles in brain tumor cell cultures. Due to these more biocompatible properties, we tested the ability of the composites to interact with cells. Zeta potential analysis indicated that composites carry a net negative charge (-24.3 ± 2.2 mV), while the starting metal nanoparticles measured (43.3 ± 2.4 mV). We labeled the composites with poly-l-lysine fluorescein isothiocyanate (PLL-FITC), which shifted the potential to 3.5 ± 2.9 mV. It was observed by fluorescence microscopy that composites smaller than cells were internalized by some cells and larger composites remained outside. Cells became fluorescent over time due to leakage of PLL-FITC from the composites which lost fluorescence over time. Higher biocompatibility, low aggregation, and ability to control size distribution of the linear composites may make them ideal vehicles to deliver drugs or other materials to cells, and may be used as a scaffolding material for cells.

  14. Geometrical Nonlinear Aeroelastic Stability Analysis of a Composite High-Aspect-Ratio Wing

    Directory of Open Access Journals (Sweden)

    Chang Chuan Xie

    2008-01-01

    Full Text Available A composite high-aspect-ratio wing of a high-altitude long-endurance (HALE aircraft was modeled with FEM by MSC/NASTRAN, and the nonlinear static equilibrium state is calculated under design load with follower force effect, but without load redistribution. Assuming the little vibration amplitude of the wing around the static equilibrium state, the system is linearized and the natural frequencies and mode shapes of the deformed structure are obtained. Planar doublet lattice method is used to calculate unsteady aerodynamics in frequency domain ignoring the bending effect of the deflected wing. And then, the aeroelastic stability analysis of the system under a given load condition is successively carried out. Comparing with the linear results, the nonlinear displacement of the wing tip is higher. The results indicate that the critical nonlinear flutter is of the flap/chordwise bending type because of the chordwise bending having quite a large torsion component, with low critical speed and slowly growing damping, which dose not appear in the linear analysis. Furthermore, it is shown that the variation of the nonlinear flutter speed depends on the scale of the load and on the chordwise bending frequency. The research work indicates that, for the very flexible HALE aircraft, the nonlinear aeroelastic stability is very important, and should be considered in the design progress. Using present FEM software as the structure solver (e.g. MSC/NASTRAN, and the unsteady aerodynamic code, the nonlinear aeroelastic stability margin of a complex system other than a simple beam model can be determined.

  15. Jet noise of high aspect-ratio rectangular nozzles with application to pneumatic high-lift devices

    Science.gov (United States)

    Munro, Scott Edward

    Circulation control wings are a type of pneumatic high-lift device that have been extensively researched as to their aerodynamic benefits. However, there has been little research into the possible airframe noise reduction benefits. The key element of noise is the jet noise associated with the jet sheet emitted from the blowing slot. This jet sheet is essentially a high aspect-ratio rectangular jet. This study directly compared far-field noise emissions from a state-of-the-art circulation control wing high lift configuration, and a conventional wing also configured for high lift. Results indicated that a circulation control wing had a significant acoustic advantage over a conventional wing for identical lift performance. A high aspect-ratio nozzle was fabricated to study the general characteristics of high aspect-ratio jets with aspect ratios from 100 to 3000. The results of this study provided the basic elements in understanding how to reduce the noise from a circulation control wing. High aspect-ratio nozzle results showed that the jet noise of this type of jet was proportional to the 8th power of the jet velocity. It was also found that the jet noise was proportional to the slot height to the 3/2 power and slot width to the 1/2 power. Fluid dynamic experiments were also performed on the high aspect-ratio nozzle. Single hot-wire experiments indicated that the jet exhaust from the high aspect-ratio nozzle was similar to a 2-d turbulent jet. Two-wire space-correlation experiments were performed to attempt to find a relationship between the slot height of the jet and the length-scale of the flow noise generating turbulence structure. The turbulent eddy convection velocity was also calculated, and was found to vary with the local centerline velocity, and also as a function of the frequency of the eddy.

  16. BisGMA/TEGDMA dental composite containing high aspect-ratio hydroxyapatite nanofibers

    Science.gov (United States)

    Chen, Liang; Yu, Qingsong; Wang, Yong; Li, Hao

    2011-01-01

    Objectives The objectives of this study are to investigate the properties of high aspect-ratio hydroxyapatite (HAP) nanofibers and the reinforcing effect of such fibers on bisphenol A glycidyl methacrylate (BisGMA)/triethylene glycol dimethacrylate (TEGDMA) dental resins (without silica microparticle filler) and dental composites (with silica microparticle filler) with various mass fractions (loading rates). Methods HAP nanofibers were synthesized using a wet-chemical method and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and thermal gravimetric analysis (TGA). Biaxial flexural strength (BFS) of the HAP nanofibers reinforced dental resins without any microsized filler and dental composites with silica microparticle filler was tested and analysis of variance (ANOVA) was used for the statistically analysis of acquired data. The morphology of fracture surface of tested dental composite samples was examined by SEM. Results The HAP nanofibers with aspect-ratios of 600 to 800 can be successfully fabricated with a simple wet-chemical method in aqueous solution. Impregnation of small mass fractions of the HAP nanofibers (5 wt% or 10 wt%) into the BisGMA/TEGDMA dental resins or impregnation of small mass fractions of the HAP nanofibers (2 wt% or 3 wt%) into the dental composites can substantially improve the biaxial flexural strength of the resulting dental resins and composites. A percolation threshold of HAP nanofibers, beyond which more nanofibers will no longer further increase the mechanical properties of dental composites containing HAP nanofibers, was observed for the dental composites with or without silica microparticle filler. Our mechanical testing and fractographic analysis indicated that the relatively good dispersion of HAP nanofibers at low mass fraction is the key reason for the significantly improved biaxial flexural strength, while higher mass fraction of HAP nanofibers tends to lead to bundles that cannot effectively

  17. Fabrication of micro-pin array with high aspect ratio on stainless steel using nanosecond laser beam machining

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Se Won [School of Mechanical and Aerospace Engineering, Seoul National University, Gwanak 599 Gwanak-ro, Gwanak-Gu, Seoul, 151-744 (Korea, Republic of); Shin, Hong Shik, E-mail: shinhs05@ut.ac.kr [Department of Energy System Engineering, Korea National University of Transportation, Chungju, Chungbuk, 380-702 (Korea, Republic of); Chu, Chong Nam [School of Mechanical and Aerospace Engineering, Seoul National University, Gwanak 599 Gwanak-ro, Gwanak-Gu, Seoul, 151-744 (Korea, Republic of)

    2013-01-01

    Highlights: Black-Right-Pointing-Pointer A high aspect ratio micro-pin array was fabricated by laser beam machining using the piling of a recast layer. Black-Right-Pointing-Pointer The recast layer could be piled due to the chromium oxide with high surface tension and viscosity of chromium oxide. Black-Right-Pointing-Pointer The machining characteristics for a high aspect ratio micro-pin array were investigated according to laser beam parameters. Black-Right-Pointing-Pointer Experiments for attaching force relative to the surface roughness of the subject plane were carried out. Black-Right-Pointing-Pointer The developed micro-pin array was successfully attached to vertical wall. - Abstract: In this paper, a micro-pin array with a high aspect ratio was fabricated on AISI 304 using laser beam ablation for attachment to a vertical wall. In recent times, there has been research in various fields, including robotics and bio-MEMS, regarding attachment to vertical walls, and micro-pin arrays may offer the best solution. For vertical wall attachment, the micro-pin should have a high aspect ratio, long length, and sharp tip. The recast layer could be piled due to the chromium oxide with high surface tension and viscosity of chromium oxide, and it composed the micro-pins with high aspect ratio. X-ray photoelectron spectroscopy (XPS) was used to identify the characteristics of the piled recast layer. The machining characteristics for a high aspect ratio micro-pin array were investigated according to laser beam machining parameters. In addition, experiments for attaching force relative to the surface roughness of the subject plane were carried out.

  18. Engineered high aspect ratio vertical nanotubes as a model system for the investigation of catalytic methanol synthesis over Cu/ZnO.

    Science.gov (United States)

    Güder, Firat; Frei, Elias; Kücükbayrak, Umut M; Menzel, Andreas; Thomann, Ralf; Luptak, Roman; Hollaender, Bernd; Krossing, Ingo; Zacharias, Margit

    2014-02-12

    Catalytically synthesized methanol from H2 and CO2 using porous Cu/ZnO aggregates is a promising, carbon neutral, and renewable alternative to replace fossil fuel based transport fuels. However, the absence of surface-engineered model systems to understand and improve the industrial Cu/ZnO catalyst poses a big technological gap in efforts to increase industrial methanol conversion efficiency. In this work, we report a novel process for the fabrication of patterned, vertically aligned high aspect ratio 1D nanostructures on Si that can be used as an engineered model catalyst. The proposed strategy employs near-field phase shift lithography (NF-PSL), deep reactive ion etching (DRIE), and atomic layer deposition (ALD) to pattern, etch, and coat Si wafers to produce high aspect ratio 1D nanostructures. Using this method, we produced a model system consisting of high aspect ratio Cu-decorated ZnO nanotubes (NTs) to investigate the morphological effects of ZnO catalyst support in comparison to the planar Cu/ZnO catalyst in terms of the catalytic reactions. The engineered catalysts performed 70 times better in activating CO2 than the industrial catalyst. In light of the obtained results, several important points are highlighted, and recommendations are made to achieve higher catalytic performance.

  19. Fabrication of Ni stamp with high aspect ratio, two-leveled, cylindrical microstructures using dry etching and electroplating

    DEFF Research Database (Denmark)

    Petersen, Ritika Singh; Keller, Stephan Sylvest; Hansen, Ole;

    2015-01-01

    We describe a process for the fabrication of a Ni stamp that is applied to the microstructuring of polymers by hot embossing. The target devices are microcontainers that have a potential application in oral drug delivery. Each container is a 3D, cylindrical, high aspect ratio microstructure...

  20. Highly Manufacturable Deep (Sub-Millimeter) Etching Enabled High Aspect Ratio Complex Geometry Lego-Like Silicon Electronics

    KAUST Repository

    Ghoneim, Mohamed T.

    2017-02-01

    A highly manufacturable deep reactive ion etching based process involving a hybrid soft/hard mask process technology shows high aspect ratio complex geometry Lego-like silicon electronics formation enabling free-form (physically flexible, stretchable, and reconfigurable) electronic systems.

  1. Fabrication of novel AFM probe with high-aspect-ratio ultra-sharp three-face silicon nitride tips

    NARCIS (Netherlands)

    Vermeer, Rolf; Berenschot, Erwin; Sarajlic, Edin; Tas, Niels; Jansen, Henri

    2014-01-01

    In this paper we present the wafer-scale fabrication of molded AFM probes with high aspect ratio ultra-sharp three-plane silicon nitride tips. Using (111) silicon wafers a dedicated process is developed to fabricate molds in the silicon wafer that have a flat triangular bottom surface enclosed by th

  2. High aspect ratio micro tool manufacturing for polymer replication using mu EDM of silicon, selective etching and electroforming

    DEFF Research Database (Denmark)

    Tosello, Guido; Bissacco, Giuliano; Tang, Peter Torben

    2008-01-01

    Mass fabrication of polymer micro components with high aspect ratio micro-structures requires high performance micro tools allowing the use of low cost replication processes such as micro injection moulding. In this regard an innovative process chain, based on a combination of micro electrical di...

  3. High aspect ratio iridescent three-dimensional metal–insulator–metal capacitors using atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Burke, Micheal, E-mail: micheal.burke@tyndall.ie; Blake, Alan; Djara, Vladimir; O' Connell, Dan; Povey, Ian M.; Cherkaoui, Karim; Monaghan, Scott; Scully, Jim; Murphy, Richard; Hurley, Paul K.; Pemble, Martyn E.; Quinn, Aidan J., E-mail: aidan.quinn@tyndall.ie [Tyndall National Institute, University College Cork, Cork (Ireland)

    2015-01-01

    The authors report on the structural and electrical properties of TiN/Al{sub 2}O{sub 3}/TiN metal–insulator–metal (MIM) capacitor structures in submicron three-dimensional (3D) trench geometries with an aspect ratio of ∼30. A simplified process route was employed where the three layers for the MIM stack were deposited using atomic layer deposition (ALD) in a single run at a process temperature of 250 °C. The TiN top and bottom electrodes were deposited via plasma-enhanced ALD using a tetrakis(dimethylamino)titanium precursor. 3D trench devices yielded capacitance densities of 36 fF/μm{sup 2} and quality factors >65 at low frequency (200 Hz), with low leakage current densities (<3 nA/cm{sup 2} at 1 V). These devices also show strong optical iridescence which, when combined with the covert embedded capacitance, show potential for system in package (SiP) anticounterfeiting applications.

  4. Framework to model neutral particle flux in convex high aspect ratio structures using one-dimensional radiosity

    Science.gov (United States)

    Manstetten, Paul; Filipovic, Lado; Hössinger, Andreas; Weinbub, Josef; Selberherr, Siegfried

    2017-02-01

    We present a computationally efficient framework to compute the neutral flux in high aspect ratio structures during three-dimensional plasma etching simulations. The framework is based on a one-dimensional radiosity approach and is applicable to simulations of convex rotationally symmetric holes and convex symmetric trenches with a constant cross-section. The framework is intended to replace the full three-dimensional simulation step required to calculate the neutral flux during plasma etching simulations. Especially for high aspect ratio structures, the computational effort, required to perform the full three-dimensional simulation of the neutral flux at the desired spatial resolution, conflicts with practical simulation time constraints. Our results are in agreement with those obtained by three-dimensional Monte Carlo based ray tracing simulations for various aspect ratios and convex geometries. With this framework we present a comprehensive analysis of the influence of the geometrical properties of high aspect ratio structures as well as of the particle sticking probability on the neutral particle flux.

  5. The field emission properties of high aspect ratio diamond nanocone arrays fabricated by focused ion beam milling

    Directory of Open Access Journals (Sweden)

    Z.L. Wang, Q. Wang, H.J. Li, J.J. Li, P. Xu, Q. Luo, A.Z. Jin, H.F. Yang and C.Z. Gu

    2005-01-01

    Full Text Available High aspect ratio diamond nanocone arrays are formed on freestanding diamond film by means of focused ion beam (FIB milling technology and hot-filament chemical vapor deposition (HFCVD method. The structure and phase purity of an individual diamond nanocone are characterized by scanning electron microscopy (SEM and micro-Raman spectroscopy. The result indicates that the diamond cones with high aspect ratio and small tip apex radius can be obtained by optimizing the parameters of FIB milling and diamond growth. The diamond nanocone arrays were also used to study the electron field emission properties and electric field shielding effect, finding high emission current density, low threshold and weak shielding effect, all attributable to the high field enhancement factor and suitable cone density of the diamond nanocone emitter

  6. High aspect ratio microstructuring of transparent dielectrics using femtosecond laser pulses: method for optimization of the machining throughput

    Science.gov (United States)

    Hendricks, F.; der Au, J. Aus; Matylitsky, V. V.

    2014-10-01

    High average power, high repetition rate femtosecond lasers with μJ pulse energies are increasingly used for material processing applications. The unique advantage of material processing with sub-picosecond lasers is efficient, fast and localized energy deposition, which leads to high ablation efficiency and accuracy in nearly all kinds of solid materials. This work focuses on the machining of high aspect ratio structures in transparent dielectrics, in particular chemically strengthened Xensation™ glass from Schott using multi-pass ablative material removal. For machining of high aspect ratio structures, among others needed for cutting applications, a novel method to determine the best relation between kerf width and number of overscans is presented. The importance of this relation for optimization of the machining throughput will be demonstrated.

  7. Magnetic field alignment of randomly oriented, high aspect ratio silicon microwires into vertically oriented arrays.

    Science.gov (United States)

    Beardslee, Joseph A; Sadtler, Bryce; Lewis, Nathan S

    2012-11-27

    External magnetic fields have been used to vertically align ensembles of silicon microwires coated with ferromagnetic nickel films. X-ray diffraction and image analysis techniques were used to quantify the degree of vertical orientation of the microwires. The degree of vertical alignment and the minimum field strength required for alignment were evaluated as a function of the wire length, coating thickness, magnetic history, and substrate surface properties. Nearly 100% of 100 μm long, 2 μm diameter, Si microwires that had been coated with 300 nm of Ni could be vertically aligned by a 300 G magnetic field. For wires ranging from 40 to 60 μm in length, as the length of the wire increased, a higher degree of alignment was observed at lower field strengths, consistent with an increase in the available magnetic torque. Microwires that had been exposed to a magnetic sweep up to 300 G remained magnetized and, therefore, aligned more readily during subsequent magnetic field alignment sweeps. Alignment of the Ni-coated Si microwires occurred at lower field strengths on hydrophilic Si substrates than on hydrophobic Si substrates. The magnetic field alignment approach provides a pathway for the directed assembly of solution-grown semiconductor wires into vertical arrays, with potential applications in solar cells as well as in other electronic devices that utilize nano- and microscale components as active elements.

  8. Numerical studies of the reversed-field pinch at high aspect ratio

    Science.gov (United States)

    Sätherblom, H.-E.; Drake, J. R.

    1998-10-01

    The reversed field pinch (RFP) configuration at an aspect ratio of 8.8 is studied numerically by means of the three-dimensional magnetohydrodynamic code DEBS [D. D. Schnack et al., J. Comput. Phys. 70, 330 (1987)]. This aspect ratio is equal to that of the Extrap T1 experiment [S. Mazur et al., Nucl. Fusion 34, 427 (1994)]. A numerical study of a RFP with this level of aspect ratio requires extensive computer achievements and has hitherto not been performed. The results are compared with previous studies [Y. L. Ho et al., Phys. Plasmas 2, 3407 (1995)] of lower aspect ratio RFP configurations. In particular, an evaluation of the extrapolation to the aspect ratio of 8.8 made in this previous study shows that the extrapolation of the spectral spread, as well as most of the other findings, are confirmed. An important exception, however, is the magnetic diffusion coefficient, which is found to decrease with aspect ratio. Furthermore, an aspect ratio dependence of the magnetic energy and of the helicity of the RFP is found.

  9. Single-pulse femtosecond laser Bessel beams drilling of high-aspect-ratio microholes based on electron dynamics control

    Science.gov (United States)

    Zhao, Weiwei; Li, Xiaowei; Xia, Bo; Yan, Xueliang; Han, Weina; Lu, Yongfeng; Jiang, Lan

    2014-11-01

    Microholes drilling has attracted extensive research efforts for its broad applications in photonics, microfluidics, optical fibers and many other fields. A femtosecond (fs) laser is a promising tool for high-precision materials processing with reduced recast/microcracks and minimized heat affected zones. But there remain many challenges in hole drilling using conventional fs laser with Gaussian beams, such as low aspect ratio and taper effects. We report small-diameter and high-aspect-ratio microholes with taper free drilling in PMMA (polymethyl methacrylate) using single-pulse fs laser Bessel beams. Axicon is used to transform Gaussian beams into Bessel beams, which then irradiate in the sample by a telescope consisting of plano-convex lens and microscope objective. Using this technique, we enhance the aspect ratio of microholes by 55 times as compared with Gaussian beams. We attribute this high aspect ratio and high quality microholes formation to the unique spatial intensity distribution and propagation stability of Bessel beams, which can effectively adjust the transient localized electron density distribution leading to a long and uniform localized-interacted zone. By using the optimized pulse energy and focal depth position, the microholes diameter ranges between 1.4-2.1 μm and the aspect ratio can exceed 460. This efficient technique is of great potentials for fabrication of microphotonics devices and microfluidics.

  10. Patterning of periodic high-aspect-ratio nanopores in anatase titanium dioxide from titanium fluoride hydrolysis.

    Science.gov (United States)

    Tevis, Ian D; Stupp, Samuel I

    2011-05-01

    We report straight pores in titanium dioxide produced by a pattern transfer method with titanium fluoride hydrolysis. The resulting films on fluorine-doped tin oxide had pores with diameters of 30 nm and depths of 500 nm, corresponding to aspect ratios of 1:17.

  11. Key Techniques on Preparing High Aspect Ratio Micro and Nano Structures

    DEFF Research Database (Denmark)

    Jian, Zhao; Lianhe, Dong; Xiaoli, Zhu

    2016-01-01

    effectively. The mechanism of action between NaCl and HSQ was analyzed. The collapse and adhesion of resist structure due to the effect of gas-liquid interfacial capillary surface tension were suppressed by the CO2 supercritical drying method. Large-area dense nano-structures with the aspect ratio of 12...

  12. Nanoimprinting ultrasmall and high-aspect-ratio structures by using rubber-toughened UV cured epoxy resist

    Science.gov (United States)

    Shin, Young Jae; Wu, Yi-Kuei; Guo, L. Jay

    2013-06-01

    A simple and robust scheme is proposed for the fabrication of nanoscale (20 nm line width) and high-aspect-ratio (9:1) structures by using modulus-tunable UV curable epoxy resists. Additionally, the ability to control the Young’s modulus of the imprinted material from hard to rigiflex using these epoxy resists is demonstrated. The physical properties of the new epoxy resists were controlled by adjusting the ratio of bisphenol F-type epoxy resin and acrylonitrile-butadiene rubber-based epoxy resin in the formulation of the resist. The mechanical properties of the resist were tuned to obtain various aspect ratios as well as mold flexibility for conformal contact over non-planar surfaces and large areas. In order to reduce the line width of the imprinted patterns, a process to conformally coat the mold structure by atomic layer deposition of alumina was also developed. Narrow lines with high-aspect-ratio features and with very low defect density were achieved via the new approach and the high mechanical strength of the new resist formulation.

  13. Deposition of a-C:H films on inner surface of high-aspect-ratio microchannel

    Science.gov (United States)

    Hirata, Yuki; Choi, Junho

    2016-08-01

    Hydrogenated amorphous carbon (a-C:H) films were prepared on inner surface of 100-μm-width microchannel by using a bipolar-type plasma based ion implantation and deposition. The microchannel was fabricated using a silicon plate, and two kinds of microchannels were prepared, namely, with a bottom layer (open at one end) and without a bottom layer (open at both ends). The distribution of thickness and hardness of films was evaluated by SEM and nanoindentation measurements, respectively, and the microstructures of films were evaluated by Raman spectroscopy. Furthermore, the behavior of ions and radicals was analyzed simultaneously by combining the calculation methods of Particle-In-Cell/Monte Carlo Collision and Direct Simulation Monte Carlo to investigate the coating mechanism for the microchannel. It was found that the film thickness decreased as the depth of the coating position increased in the microchannels where it is open at one end. The uniformity of the film thickness improved by increasing the negative pulse voltage because ions can arrive at the deeper part of the microchannel. In addition, the hardness increased as the depth of the coating position increased. This is because the radicals do not arrive at the deeper part of the microchannel, and the incident proportion of ions relative to that of radicals increases, resulting in a high hardness due to the amorphization of the film. The opening area of the microchannel where the aspect ratio is very small, radicals dominate the incident flux, whereas ions prevail over radicals above an aspect ratio of about 7.5. On the other hand, in the microchannels that are open at both ends, there were great improvements in uniformity of the film thickness, hardness, and the film structure. The a-C:H films were successfully deposited on the entire inner surface of a microchannel with an aspect ratio of 20.

  14. Dispersion and Polarization of Surface Waves Trapped in High Aspect Ratio Electrode Arrays

    DEFF Research Database (Denmark)

    Laude, Vincent; Dühring, Maria Bayard; Moubchir, Hanane

    2007-01-01

    .Phys., 90(5):2492, 2001; Appl. Phys. Lett., 89:083515, 2006.) an experimental and theoretical analysis of the transduction of SAW under a metallic array of electrodes with a large aspect ratio on a piezoelectric substrate, whereby allowing the electrode height to become larger than one wavelength....... The multimode character of SAW propagation was observed and the explicit dependence of the SAW velocities as a function of the electrode height was obtained experimentally. Up to a 10-fold slowing of surface waves was observed, with the phase velocity dropping from 4000 m/s down to 450 m/s. We present...

  15. Hot embossing of photonic crystal polymer structures with a high aspect ratio

    DEFF Research Database (Denmark)

    Schelb, Mauno; Vannahme, Christoph; Kolew, Alexander;

    2011-01-01

    Hot embossing is a promising approach for mass production of photonic crystal structures. This paper describes the fabrication of a replication tool for two-dimensional photonic crystal patterns and its replication in substrates of poly(methylmethacrylate) (PMMA) and cyclic olefin copolymer (COC......). A nickel tool for the replication of structures with lateral dimensions of 110 nm and heights of approximately 370 nm is fabricated via electroplating of a nanostructured sample resulting in an aspect ratio of approximately 3.5. The structures are subsequently hot embossed into PMMA and COC substrates....

  16. Highly sensitive glucose biosensor based on Au-Ni coaxial nanorod array having high aspect ratio.

    Science.gov (United States)

    Hsu, Che-Wei; Wang, Gou-Jen

    2014-06-15

    An effective glucose biosensor requires a sufficient amount of GOx immobilizing on the electrode surface. An electrode of a 3D nanorod array, having a larger surface-to-volume ratio than a 2D nanostructure, can accommodate more GOx molecules to immobilize onto the surface of the nanorods. In this study, a highly sensitive Au-Ni coaxial nanorod array electrode fabricated through the integration of nano electroforming and immersion gold (IG) method for glucose detection was developed. The average diameter of the as-synthesized Ni nanorods and that of the Au-Ni nanorods were estimated to be 150 and 250 nm, respectively; both had a height of 30 μm. The aspect ratio was 120. Compared to that of a flat Au electrode, the effective sensing area was enhanced by 79.8 folds. Actual glucose detections demonstrated that the proposed Au-Ni coaxial nanorod array electrode could operate in a linear range of 27.5 μM-27.5mM with a detection limit of 5.5μM and a very high sensitivity of 769.6 μA mM(-1)cm(-2). Good selectivity of the proposed sensing device was verified by sequential injections of uric acid (UA) and ascorbic acid (AA). Long-term stability was examined through successive detections over a period of 30 days.

  17. Subsonic and transonic pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Watson, J. J.

    1981-01-01

    A high aspect ratio supercritical wing with oscillating control surfaces is described. The semispan wing model was instrumented with 252 static orifices and 164 in situ dynamic pressure gases for studying the effects of control surface position and sinusoidal motion on steady and unsteady pressures. Data from the present test (this is the second in a series of tests on this model) were obtained in the Langley Transonic Dynamics Tunnel at Mach numbers of 0.60 and 0.78 and are presented in tabular form.

  18. Designs and processes toward high-aspect-ratio nanostructures at the deep nanoscale: unconventional nanolithography and its applications

    Science.gov (United States)

    Lee, Sori; Park, Byeonghak; Kim, Jun Sik; Kim, Tae-il

    2016-11-01

    The patterning of high-resolution-featured deep-nanoscale structures with a high aspect ratio (AR) has received increasing attention in recent years as a promising technique for a wide range of applications, including electrical, optical, mechanical and biological systems. Despite extensive efforts to develop viable nanostructure fabrication processes, a superior technique enabling defect-free, high-resolution control over a large area is still required. In this review, we focus on recent important advances in the designs and processes of high-resolution nanostructures possessing a high AR, including hierarchical and 3D patterns. The unique applications of these materials are also discussed.

  19. Large-scale high aspect ratio Al-doped ZnO nanopillars arrays as anisotropic metamaterials

    DEFF Research Database (Denmark)

    Shkondin, Evgeniy; Takayama, Osamu; Panah, Mohammad Esmail Aryaee

    2017-01-01

    High aspect ratio free-standing Al-doped ZnO (AZO) nanopillars and nanotubes were fabricated using a combination of advanced reactive ion etching and atomic layer deposition (ALD) techniques. Prior to the pillar and tube fabrication, AZO layers were grown on flat silicon and glass substrates...... plasma frequency. During pillar fabrication, AZO conformally passivates the silicon template, which is characteristic of typical ALD growth conditions. The last step of fabrication is heavily dependent on the selective chemistry of the SF6 plasma. It was shown that silicon between AZO structures can...

  20. Shrink film patterning by craft cutter: complete plastic chips with high resolution/high-aspect ratio channel.

    Science.gov (United States)

    Taylor, Douglas; Dyer, David; Lew, Valerie; Khine, Michelle

    2010-09-21

    This paper presents a rapid, ultra-low-cost approach to fabricate microfluidic devices using a polyolefin shrink film and a digital craft cutter. The shrinking process (with a 95% reduction in area) results in relatively uniform and consistent microfluidic channels with smooth surfaces, vertical sidewalls, and high aspect ratio channels with lateral resolutions well beyond the tool used to cut them. The thermal bonding of the layers results in strongly bonded devices. Complex microfluidic designs are easily designed on the fly and protein assays are also readily integrated into the device. Full device characterization including channel consistency, optical properties, and bonding strength are assessed in this technical note.

  1. Real time ablation rate measurement during high aspect-ratio hole drilling with a 120-ps fiber laser.

    Science.gov (United States)

    Mezzapesa, Francesco P; Sibillano, Teresa; Di Niso, Francesca; Ancona, Antonio; Lugarà, Pietro M; Dabbicco, Maurizio; Scamarcio, Gaetano

    2012-01-02

    We report on the instantaneous detection of the ablation rate as a function of depth during ultrafast microdrilling of metal targets. The displacement of the ablation front has been measured with a sub-wavelength resolution using an all-optical sensor based on the laser diode self-mixing interferometry. The time dependence of the laser ablation process within the depth of aluminum and stainless steel targets has been investigated to study the evolution of the material removal rate in high aspect-ratio micromachined holes.

  2. Fabrication of high-aspect-ratio polymer microstructures and hierarchical textures using carbon nanotube composite master molds.

    Science.gov (United States)

    Copic, Davor; Park, Sei Jin; Tawfick, Sameh; De Volder, Michael F L; Hart, A John

    2011-05-21

    Scalable and cost effective patterning of polymer structures and their surface textures is essential to engineer material properties such as liquid wetting and dry adhesion, and to design artificial biological interfaces. Further, fabrication of high-aspect-ratio microstructures often requires controlled deep-etching methods or high-intensity exposure. We demonstrate that carbon nanotube (CNT) composites can be used as master molds for fabrication of high-aspect-ratio polymer microstructures having anisotropic nanoscale textures. The master molds are made by growth of vertically aligned CNT patterns, capillary densification of the CNTs using organic solvents, and capillary-driven infiltration of the CNT structures with SU-8. The composite master structures are then replicated in SU-8 using standard PDMS transfer molding methods. By this process, we fabricated a library of replicas including vertical micro-pillars, honeycomb lattices with sub-micron wall thickness and aspect ratios exceeding 50:1, and microwells with sloped sidewalls. This process enables batch manufacturing of polymer features that capture complex nanoscale shapes and textures, while requiring only optical lithography and conventional thermal processing.

  3. Surface tension-induced high aspect-ratio PDMS micropillars with concave and convex lens tips

    KAUST Repository

    Li, Huawei

    2013-04-01

    This paper reports a novel method for the fabrication of 3-dimensional (3D) Polydimethylsiloxane (PDMS) micropillars with concave and convex lens tips in a one-step molding process, using a CO2 laser-machined Poly(methyl methacrylate) (PMMA) mold with through holes. The PDMS micropillars are 4 mm high and have an aspect ratio of 251. The micropillars are formed by capillary force drawing up PDMS into the through hole mold. The concave and convex lens tips of the PDMS cylindrical micropillars are induced by surface tension and are controllable by changing the surface wetting properties of the through holes in the PMMA mold. This technique eliminates the requirements of expensive and complicated facilities to prepare a 3D mold, and it provides a simple and rapid method to fabricate 3D PDMS micropillars with controllable dimensions and tip shapes. © 2013 IEEE.

  4. Millijoule femtosecond micro-Bessel beams for ultra-high aspect ratio machining.

    Science.gov (United States)

    Mitra, Sambit; Chanal, Margaux; Clady, Raphaël; Mouskeftaras, Alexandros; Grojo, David

    2015-08-20

    We report on a functional experimental design for Bessel beam generation capable of handling high-energy ultrashort pulses (up to 1.2 mJ per pulse of 50 fs duration). This allows us to deliver intensities exceeding the breakdown threshold for air or any dielectric along controlled micro-filaments with lengths exceeding 4 mm. It represents an unprecedented upscaling in comparison to recent femtosecond Bessel beam micromachining experiments. We produce void microchannels through glass substrates to demonstrate that aspect ratios exceeding 1200∶1 can be achieved by using single high-intensity pulses. This demonstration must lead to new methodologies for deep-drilling and high-speed cutting applications.

  5. Fabrication of High Aspect Ratio Micro-Penning-Malmberg Gold Plated Silicon Trap Arrays

    CERN Document Server

    Narimannezhad, Alireza; Weber, Marc H; Lynn, Kelvin G

    2013-01-01

    Acquiring a portable high density charged particles trap might consist of an array of micro-Penning-Malmberg traps (microtraps) with substantially lower end barriers potential than conventional Penning-Malmberg traps [1]. We report on the progress of the fabrication of these microtraps designed for antimatter storage such as positrons. The fabrication of large length to radius aspect ratio (1000:1) microtrap arrays involved advanced techniques including photolithography, deep reactive ion etching (DRIE) of silicon wafers to achieve through-vias, gold sputtering of the wafers on the surfaces and inside the vias, and thermal compression bonding of the wafers. This paper describes the encountered issues during fabrication and addresses geometry errors and asymmetries. In order to minimize the patch effects on the lifetime of the trapped positrons, the bonded stacks were gold electroplated to achieve a uniform gold surface. We show by simulation and analytical calculation that how positrons confinement time depen...

  6. Photoablation characteristics of novel polyimides synthesized for high-aspect-ratio excimer laser LIGA process

    Science.gov (United States)

    Yang, Chii-Rong; Hsieh, Yu-Sheng; Hwang, Guang-Yeu; Lee, Yu-Der

    2004-04-01

    The photoablation properties of two soluble polyimides DMDB/6FDA and OT/6FDA with thicknesses of over 300 µm, synthesized by the polycondensation of a hexafluoropropyl group contained in a dianhydride with two kinds of diamines, are investigated using a 248 nm krypton fluoride (KrF) laser. The incorporation of the hexafluoropropyl group into the chemical structure gives these two polyimides higher etching rates than Kapton (a commercial polyimide film which is difficult to dissolve). The etching rates of synthesized polyimides are about 0.1-0.5 µm/pulse over a fluence range of 0.25-2.25 J cm-2. The photothermal mechanism for DMDB/6FDA contributes about 19% of etching depth at a laser fluence of 0.82 J cm-2. Moreover, the number of laser pulses seriously affects the taper angle of microstructures, especially at low fluence. Near-vertical side-wall structures can be built at high fluence (~2 J cm-2). Fresnel patterns with a thickness of 300 µm and a linewidth of 10 µm were fabricated, with an attainable aspect ratio of around 30. After photoablation, the complementary metallic microstructures were also fabricated by a sequential electroplating procedure. Then, those two new polyimides could be dissolved easily in most common solvents (such as THF, DMSO, NMP and DMF). These results indicate that these two soluble polyimides are highly suitable for use in the KrF laser LIGA process.

  7. High-aspect-ratio photoresist processing for fabrication of high resolution and thick micro-windings

    Science.gov (United States)

    Anthony, Ricky; Laforge, Elias; Casey, Declan P.; Rohan, James F.; O'Mathuna, Cian

    2016-10-01

    DC winding losses remain a major roadblock in realizing high efficiency micro-magnetic components (inductors/transformers). This paper reports an optimized photoresist process using negative tone and acrylic based THB-151N (from JSR Micro), to achieve one of the highest aspect ratio (17:1) and resolution (~5 µm) resist patterns for fabrication of thick (~80 µm) micro-winding using UV lithography. The process was optimized to achieve photoresist widths from 5 µm to 20 µm with resist thickness of ~85 µm in a single spin step. Unlike SU-8, this resist can be readily removed and shows a near-vertical (~91°) electroplated Cu side-wall profile. Moreover, the high resolution compared to available resist processes enables a further reduction in the footprint area and can potentially increase the number of winding thereby increasing the inductance density for micro-magnetic components. Resistance measurements of electroplated copper winding of air-core micro-inductors within the standard 0402 size (0.45 mm2 footprint area) suggested a 42% decrease in resistance (273 mΩ-159 mΩ) with the increase in electroplated Cu thickness (from 50 µm to 80 µm). Reduction of the spacings (from 10 µm to 5 µm) enabled further miniaturisation of the device footprint area (from 0.60 mm2 to 0.45 mm2) without significant increase in resistance.

  8. Jet-Surface Interaction Noise from High-Aspect Ratio Nozzles: Test Summary

    Science.gov (United States)

    Brown, Clifford; Podboy, Gary

    2017-01-01

    Noise and flow data have been acquired for a 16:1 aspect ratio rectangular nozzle exhausting near a simple surface at the NASA Glenn Research Center as part of an ongoing effort to understand, model, and predict the noise produced by current and future concept aircraft employing a tightly integrated engine airframe designs. The particular concept under consideration in this experiment is a blended-wing-body airframe powered by a series of electric fans exhausting through slot nozzle over an aft deck. The exhaust Mach number and surface length were parametrically varied during the test. Far-field noise data were acquired for all nozzle surface geometries and exhaust flow conditions. Phased-array noise source localization data and in-flow pressure data were also acquired for a subset of the isolated (no surface) and surface configurations; these measurements provide data that have proven useful for modeling the jet-surface interaction noise source and the surface effect on the jet-mixing noise in round jets. A summary of the nozzle surface geometry, flow conditions tested, and data collected are presented.

  9. HIGH ASPECT RATIO ION EXCHANGE RESIN BED - HYDRAULIC RESULTS FOR SPERICAL RESIN BEADS

    Energy Technology Data Exchange (ETDEWEB)

    Duignan, M; Charles Nash, C; Timothy Punch, T

    2007-09-27

    A principal role of the DOE Savannah River Site is to safely dispose of a large volume of liquid nuclear waste held in many storage tanks. An in-tank ion exchange unit is being considered for cesium removal to accelerate waste processing. This unit is planned to have a relatively high bed height to diameter ratio (10:1). Complicating the design is the need to cool the ion exchange media; therefore, the ion exchange column will have a central cooling core making the flow path annular. To separate cesium from waste the media being considered is made of resorcinol formaldehyde resin deposited on spherical plastic beads and is a substitute for a previously tested resin made of crystalline silicotitanate. This spherical media not only has an advantage of being mechanically robust, but, unlike its predecessor, it is also reusable, that is, loaded cesium can be removed through elution and regeneration. Resin regeneration leads to more efficient operation and less spent resin waste, but its hydraulic performance in the planned ion exchange column was unknown. Moreover, the recycling process of this spherical resorcinol formaldehyde causes its volume to significantly shrink and swell. To determine the spherical media's hydraulic demand a linearly scaled column was designed and tested. The waste simulant used was prototypic of the wastes' viscosity and density. This paper discusses the hydraulic performance of the media that will be used to assist in the design of a full-scale unit.

  10. Filling high aspect ratio trenches by superconformal chemical vapor deposition: Predictive modeling and experiment

    Science.gov (United States)

    Wang, Wenjiao B.; Abelson, John R.

    2014-11-01

    Complete filling of a deep recessed structure with a second material is a challenge in many areas of nanotechnology fabrication. A newly discovered superconformal coating method, applicable in chemical vapor deposition systems that utilize a precursor in combination with a co-reactant, can solve this problem. However, filling is a dynamic process in which the trench progressively narrows and the aspect ratio (AR) increases. This reduces species diffusion within the trench and may drive the component partial pressures out of the regime for superconformal coating. We therefore derive two theoretical models that can predict the possibility for filling. First, we recast the diffusion-reaction equation for the case of a sidewall with variable taper angle. This affords a definition of effective AR, which is larger than the nominal AR due to the reduced species transport. We then derive the coating profile, both for superconformal and for conformal coating. The critical (most difficult) step in the filling process occurs when the sidewalls merge at the bottom of the trench to form the V shape. Experimentally, for the Mg(DMADB)2/H2O system and a starting AR = 9, this model predicts that complete filling will not be possible, whereas experimentally we do obtain complete filling. We then hypothesize that glancing-angle, long-range transport of species may be responsible for the better than predicted filling. To account for the variable range of species transport, we construct a ballistic transport model. This incorporates the incident flux from outside the structure, cosine law re-emission from surfaces, and line-of-sight transport between internal surfaces. We cast the transport probability between all positions within the trench into a matrix that represents the redistribution of flux after one cycle of collisions. Matrix manipulation then affords a computationally efficient means to determine the steady-state flux distribution and growth rate for a given taper angle. The

  11. The Space-Time CESE Method Applied to Viscous Flow Computations with High-Aspect Ratio Triangular or Tetrahedral Meshes

    Science.gov (United States)

    Chang, Chau-Lyan; Venkatachari, Balaji

    2016-11-01

    Flow physics near the viscous wall is intrinsically anisotropic in nature, namely, the gradient along the wall normal direction is much larger than that along the other two orthogonal directions parallel to the surface. Accordingly, high aspect ratio meshes are employed near the viscous wall to capture the physics and maintain low grid count. While such arrangement works fine for structured-grid based methods with dimensional splitting that handles derivatives in each direction separately, similar treatments often lead to numerical instability for unstructured-mesh based methods when triangular or tetrahedral meshes are used. The non-splitting treatment of near-wall gradients for high-aspect ratio triangular or tetrahedral elements results in an ill-conditioned linear system of equations that is closely related to the numerical instability. Altering the side lengths of the near wall tetrahedrons in the gradient calculations would make the system less unstable but more dissipative. This research presents recent progress in applying numerical dissipation control in the space-time conservation element solution element (CESE) method to reduce or alleviate the above-mentioned instability while maintaining reasonable solution accuracy.

  12. Single phase flow characteristics of FC-72 and ethanol in high aspect ratio rectangular mini- and micro-channels

    Science.gov (United States)

    Wang, Yuan; Wang, Zhen-guo

    2016-11-01

    Single phase flow friction factor of FC-72 and ethanol in mini-and micro-channels are experimentally investigated in the present study. High aspect ratio3 rectangular channels are selected, the hydraulic diameters of which are 571 µm, 762 µm and 1454 µm, and the aspect ratios are 20, 20 and 10 respectively. Degassed ethanol and FC-72 are used as working fluids. All the friction factors acquired in the 571 µm and 762 µm channels agree with the conventional friction theory within  ±20%-±25%. In the 1454 µm channel, however, deviations from the conventional theory occur and a modified empirical correlation of friction factor as a function of Reynolds number is proposed. Early transition from laminar to transitional flow is captured. Besides, effects of liquid physical properties are discussed. Lower viscosity and higher liquid density are responsible for the higher friction factor of FC-72. The influence of liquid properties weakens as the Reynolds number increases.

  13. The fluid mechanics of a high aspect ratio slot with an impressed pressure gradient and secondary injection

    Science.gov (United States)

    Sobanik, John Bertram

    1993-01-01

    A high aspect ratio slot flow (which emulates the gas leakage path in a gas turbine engine outer turbine air seal) is studied by use of a high aspect ratio slot using water as the working fluid. The cross section of the geometry is similar to a 'T', the slot being the vertical stroke and the main flow being the cross bar. A pressure gradient in the axial direction is created by blocking the main flow at a discreet location with an orifice plate (or blade tip simulator), located above the slot. Seven individually metered secondary flow injectors are located periodically along the bottom of the wall of the slot. Two slot widths, 1/8 and 1/4 inch, were investigated for length to width aspect ratios of 384 and 192 and height to width aspect ratios 33.2 and 16.6 respectively. Orifice plate pressure drops sufficient to give Reynolds numbers based upon half width of the slot, without secondary injection turned on, of 2350 and 4700 in the 1/8 inch slot and 4700 and 9400 in the 1/4 inch slot were run. Various secondary injection scenarios were added to the flow, the cases most studied being the no-injection and the all injectors flowing equal mass rates. Total injection rates for all seven injectors of 3.78 and 7.56 slot volumes per second were run. Laser velocimetry data and flow visualization pictures using fluorescein dye in the secondary flow are compared with computational results form the TEACH 3-D computer code. Major features and trends of the flow are captured by the computational model. Recommendations for further improvement of the numerical accuracy involves modification of the TEACH 3-D code to allow the 'slip condition' on all confining boundaries of the flow, or using a code which permits the 'slip condition' on all boundaries as a built-in option.

  14. High fidelity replication of surface texture and geometric form of a high aspect ratio aerodynamic test component

    Science.gov (United States)

    Walton, Karl; Fleming, Leigh; Goodhand, Martin; Racasan, Radu; Zeng, Wenhan

    2016-06-01

    This paper details, assesses and validates a technique for the replication of a titanium wind tunnel test aerofoil in polyurethane resin. Existing resin replication techniques are adapted to overcome the technical difficulties associated with casting a high aspect ratio component. The technique is shown to have high replication fidelity over all important length-scales. The blade chord was accurate to 0.02%, and the maximum blade thickness was accurate to 2.5%. Important spatial and amplitude areal surface texture parameter were accurate to within 2%. Compared to an existing similar system using correlation areal parameters the current technique is shown to have lower fidelity and this difference is discussed. The current technique was developed for the measurement of boundary layer flow ‘laminar to turbulent’ transition for gas turbine compressor blade profiles and this application is illustrated.

  15. Hydrothermal Synthesis of ZnO Structures Formed by High-Aspect-Ratio Nanowires for Acetone Detection.

    Science.gov (United States)

    Cao, Zhen; Wang, Yong; Li, Zhanguo; Yu, Naisen

    2016-12-01

    Snowflake-like ZnO structures originating from self-assembled nanowires were prepared by a low-temperature aqueous solution method. The as-grown hierarchical ZnO structures were investigated by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM). The results showed that the snowflake-like ZnO structures were composed of high-aspect-ratio nanowires. Furthermore, gas-sensing properties to various testing gases of 10 and 50 ppm were measured, which confirms that the ZnO structures were of good selectivity and response to acetone and could serve for acetone sensor to detect low-concentration acetone.

  16. pH-Dependent Toxicity of High Aspect Ratio ZnO Nanowires in Macrophages Due to Intracellular Dissolution

    KAUST Repository

    H. Müller, Karin

    2010-11-23

    High-aspect ratio ZnO nanowires have become one of the most promising products in the nanosciences within the past few years with a multitude of applications at the interface of optics and electronics. The interaction of zinc with cells and organisms is complex, with both deficiency and excess causing severe effects. The emerging significance of zinc for many cellular processes makes it imperative to investigate the biological safety of ZnO nanowires in order to guarantee their safe economic exploitation. In this study, ZnO nanowires were found to be toxic to human monocyte macrophages (HMMs) at similar concentrations as ZnCl2. Confocal microscopy on live cells confirmed a rise in intracellular Zn2+ concentrations prior to cell death. In vitro, ZnO nanowires dissolved very rapidly in a simulated body fluid of lysosomal pH, whereas they were comparatively stable at extracellular pH. Bright-field transmission electron microscopy (TEM) showed a rapid macrophage uptake of ZnO nanowire aggregates by phagocytosis. Nanowire dissolution occurred within membrane-bound compartments, triggered by the acidic pH of the lysosomes. ZnO nanowire dissolution was confirmed by scanning electron microscopy/energy-dispersive X-ray spectrometry. Deposition of electron-dense material throughout the ZnO nanowire structures observed by TEM could indicate adsorption of cellular components onto the wires or localized zinc-induced protein precipitation. Our study demonstrates that ZnO nanowire toxicity in HMMs is due to pH-triggered, intracellular release of ionic Zn2+ rather than the high-aspect nature of the wires. Cell death had features of necrosis as well as apoptosis, with mitochondria displaying severe structural changes. The implications of these findings for the application of ZnO nanowires are discussed. © 2010 American Chemical Society.

  17. Ionic transport through sub-10 nm diameter hydrophobic high-aspect ratio nanopores: experiment, theory and simulation

    Science.gov (United States)

    Balme, Sébastien; Picaud, Fabien; Manghi, Manoel; Palmeri, John; Bechelany, Mikhael; Cabello-Aguilar, Simon; Abou-Chaaya, Adib; Miele, Philippe; Balanzat, Emmanuel; Janot, Jean Marc

    2015-01-01

    Fundamental understanding of ionic transport at the nanoscale is essential for developing biosensors based on nanopore technology and new generation high-performance nanofiltration membranes for separation and purification applications. We study here ionic transport through single putatively neutral hydrophobic nanopores with high aspect ratio (of length L = 6 μm with diameters ranging from 1 to 10 nm) and with a well controlled cylindrical geometry. We develop a detailed hybrid mesoscopic theoretical approach for the electrolyte conductivity inside nanopores, which considers explicitly ion advection by electro-osmotic flow and possible flow slip at the pore surface. By fitting the experimental conductance data we show that for nanopore diameters greater than 4 nm a constant weak surface charge density of about 10−2 C m−2 needs to be incorporated in the model to account for conductance plateaus of a few pico-siemens at low salt concentrations. For tighter nanopores, our analysis leads to a higher surface charge density, which can be attributed to a modification of ion solvation structure close to the pore surface, as observed in the molecular dynamics simulations we performed. PMID:26036687

  18. Direct investigation of the ablation rate evolution during laser drilling of high-aspect-ratio micro-holes

    Science.gov (United States)

    Mezzapesa, Francesco P.; Sibillano, Teresa; Columbo, Lorenzo L.; Di Niso, Francesca; Ancona, Antonio; Dabbicco, Maurizio; De Lucia, Francesco; Lugarà, Pietro M.; Scamarcio, Gaetano

    2012-03-01

    The recent development of ultrafast laser ablation technology in precision micromachining has dramatically increased the demand for reliable and real-time detection systems to characterize the material removal process. In particular, the laser percussion drilling of metals is lacking of non-invasive techniques able to monitor into the depth the spatial- and time-dependent evolution all through the ablation process. To understand the physical interaction between bulk material and high-energy light beam, accurate in-situ measurements of process parameters such as the penetration depth and the removal rate are crucial. We report on direct real time measurements of the ablation front displacement and the removal rate during ultrafast laser percussion drilling of metals by implementing a contactless sensing technique based on optical feedback interferometry. High aspect ratio micro-holes were drilled onto steel plates with different thermal properties (AISI 1095 and AISI 301) and Aluminum samples using 120-ps/110-kHz pulses delivered by a microchip laser fiber amplifier. Percussion drilling experiments have been performed by coaxially aligning the diode laser probe beam with the ablating laser. The displacement of the penetration front was instantaneously measured during the process with a resolution of 0.41 μm by analyzing the sawtooth-like induced modulation of the interferometric signal out of the detector system.

  19. Optimization of laser energy deposition for single-shot high aspect-ratio microstructuring of thick BK7 glass

    Energy Technology Data Exchange (ETDEWEB)

    Garzillo, Valerio; Grigutis, Robertas [Dipartimento di Scienza e Alta Tecnologia, University of Insubria, Via Valleggio 11, I-22100 Como (Italy); Jukna, Vytautas [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); LOA, ENSTA-ParisTech, CNRS, Ecole Polytechnique, Université Paris Saclay, F-91762 Palaiseau (France); Couairon, Arnaud [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); Di Trapani, Paolo [Dipartimento di Scienza e Alta Tecnologia, University of Insubria and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy); Jedrkiewicz, Ottavia, E-mail: ottavia.jedrkiewicz@ifn.cnr.it [Istituto di Fotonica e Nanotecnologie, CNR and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy)

    2016-07-07

    We investigate the generation of high aspect ratio microstructures across 0.7 mm thick glass by means of single shot Bessel beam laser direct writing. We study the effect on the photoinscription of the cone angle, as well as of the energy and duration of the ultrashort laser pulse. The aim of the study is to optimize the parameters for the writing of a regular microstructure due to index modification along the whole sample thickness. By using a spectrally resolved single pulse transmission diagnostics at the output surface of the glass, we correlate the single shot material modification with observations of the absorption in different portions of the retrieved spectra, and with the absence or presence of spectral modulation. Numerical simulations of the evolution of the Bessel pulse intensity and of the energy deposition inside the sample help us interpret the experimental results that suggest to use picosecond pulses for an efficient and more regular energy deposition. Picosecond pulses take advantage of nonlinear plasma absorption and avoid temporal dynamics effects which can compromise the stationarity of the Bessel beam propagation.

  20. Optimization of laser energy deposition for single-shot high aspect-ratio microstructuring of thick BK7 glass

    Science.gov (United States)

    Garzillo, Valerio; Jukna, Vytautas; Couairon, Arnaud; Grigutis, Robertas; Di Trapani, Paolo; Jedrkiewicz, Ottavia

    2016-07-01

    We investigate the generation of high aspect ratio microstructures across 0.7 mm thick glass by means of single shot Bessel beam laser direct writing. We study the effect on the photoinscription of the cone angle, as well as of the energy and duration of the ultrashort laser pulse. The aim of the study is to optimize the parameters for the writing of a regular microstructure due to index modification along the whole sample thickness. By using a spectrally resolved single pulse transmission diagnostics at the output surface of the glass, we correlate the single shot material modification with observations of the absorption in different portions of the retrieved spectra, and with the absence or presence of spectral modulation. Numerical simulations of the evolution of the Bessel pulse intensity and of the energy deposition inside the sample help us interpret the experimental results that suggest to use picosecond pulses for an efficient and more regular energy deposition. Picosecond pulses take advantage of nonlinear plasma absorption and avoid temporal dynamics effects which can compromise the stationarity of the Bessel beam propagation.

  1. Ionic transport through sub-10 nm diameter hydrophobic high-aspect ratio nanopores: experiment, theory and simulation.

    Science.gov (United States)

    Balme, Sébastien; Picaud, Fabien; Manghi, Manoel; Palmeri, John; Bechelany, Mikhael; Cabello-Aguilar, Simon; Abou-Chaaya, Adib; Miele, Philippe; Balanzat, Emmanuel; Janot, Jean Marc

    2015-06-03

    Fundamental understanding of ionic transport at the nanoscale is essential for developing biosensors based on nanopore technology and new generation high-performance nanofiltration membranes for separation and purification applications. We study here ionic transport through single putatively neutral hydrophobic nanopores with high aspect ratio (of length L = 6 μm with diameters ranging from 1 to 10 nm) and with a well controlled cylindrical geometry. We develop a detailed hybrid mesoscopic theoretical approach for the electrolyte conductivity inside nanopores, which considers explicitly ion advection by electro-osmotic flow and possible flow slip at the pore surface. By fitting the experimental conductance data we show that for nanopore diameters greater than 4 nm a constant weak surface charge density of about 10(-2) C m(-2) needs to be incorporated in the model to account for conductance plateaus of a few pico-siemens at low salt concentrations. For tighter nanopores, our analysis leads to a higher surface charge density, which can be attributed to a modification of ion solvation structure close to the pore surface, as observed in the molecular dynamics simulations we performed.

  2. Mechanisms involved in the hydrothermal growth of ultra-thin and high aspect ratio ZnO nanowires

    Science.gov (United States)

    Demes, Thomas; Ternon, Céline; Morisot, Fanny; Riassetto, David; Legallais, Maxime; Roussel, Hervé; Langlet, Michel

    2017-07-01

    Hydrothermal synthesis of ZnO nanowires (NWs) with tailored dimensions, notably high aspect ratios (AR) and small diameters, is a major concern for a wide range of applications and still represents a challenging and recurring issue. In this work, an additive-free and reproducible hydrothermal procedure has been developed to grow ultra-thin and high AR ZnO NWs on sol-gel deposited ZnO seed layers. Controlling the substrate temperature and using a low reagent concentration (1 mM) has been found to be essential for obtaining such NWs. We show that the NW diameter remains constant at about 20-25 nm with growth time contrary to the NW length that can be selectively increased leading to NWs with ARs up to 400. On the basis of investigated experimental conditions along with thermodynamic and kinetic considerations, a ZnO NW growth mechanism has been developed which involves the formation and growth of nuclei followed by NW growth when the nuclei reach a critical size of about 20-25 nm. The low reagent concentration inhibits NW lateral growth leading to ultra-thin and high AR NWs. These NWs have been assembled into electrically conductive ZnO nanowire networks, which opens attractive perspectives toward the development of highly sensitive low-cost gas- or bio-sensors.

  3. Sharp-Tip Silver Nanowires Mounted on Cantilevers for High-Aspect-Ratio High-Resolution Imaging.

    Science.gov (United States)

    Ma, Xuezhi; Zhu, Yangzhi; Kim, Sanggon; Liu, Qiushi; Byrley, Peter; Wei, Yang; Zhang, Jin; Jiang, Kaili; Fan, Shoushan; Yan, Ruoxue; Liu, Ming

    2016-11-09

    Despite many efforts to fabricate high-aspect-ratio atomic force microscopy (HAR-AFM) probes for high-fidelity, high-resolution topographical imaging of three-dimensional (3D) nanostructured surfaces, current HAR probes still suffer from unsatisfactory performance, low wear-resistivity, and extravagant prices. The primary objective of this work is to demonstrate a novel design of a high-resolution (HR) HAR AFM probe, which is fabricated through a reliable, cost-efficient benchtop process to precisely implant a single ultrasharp metallic nanowire on a standard AFM cantilever probe. The force-displacement curve indicated that the HAR-HR probe is robust against buckling and bending up to 150 nN. The probes were tested on polymer trenches, showing a much better image fidelity when compared with standard silicon tips. The lateral resolution, when scanning a rough metal thin film and single-walled carbon nanotubes (SW-CNTs), was found to be better than 8 nm. Finally, stable imaging quality in tapping mode was demonstrated for at least 15 continuous scans indicating high resistance to wear. These results demonstrate a reliable benchtop fabrication technique toward metallic HAR-HR AFM probes with performance parallel or exceeding that of commercial HAR probes, yet at a fraction of their cost.

  4. Real time ablation rate measurement during high aspect-ratio hole drilling with a 120-ps fiber laser

    National Research Council Canada - National Science Library

    Mezzapesa, Francesco P; Sibillano, Teresa; Di Niso, Francesca; Ancona, Antonio; Lugarà, Pietro M; Dabbicco, Maurizio; Scamarcio, Gaetano

    2012-01-01

    .... The time dependence of the laser ablation process within the depth of aluminum and stainless steel targets has been investigated to study the evolution of the material removal rate in high aspect...

  5. Fabrication of high aspect ratio TiO2 and Al2O3 nanogratings by atomic layer deposition

    DEFF Research Database (Denmark)

    Shkondin, Evgeniy; Takayama, Osamu; Michael-Lindhard, Jonas

    2016-01-01

    followed by ALD of TiO2 or Al2O3. Then, the template was etched away using SF6 in an inductively coupled plasma tool, which resulted in the formation of isolated ALD coatings, thereby achieving high aspect ratio grating structures. SF6 plasma removes silicon selectively without any observable influence......The authors report on the fabrication of TiO2 and Al2O3 nanostructured gratings with an aspect ratio of up to 50. The gratings were made by a combination of atomic layer deposition (ALD) and dry etch techniques. The workflow included fabrication of a Si template using deep reactive ion etching...... in a gradual change in the pitch value of the structures. The pitch on top of the gratings is 400 nm, and it gradually reduces to 200 nm at the bottom. The form of the bending can be reshaped by Arþ ion beam etching. The chemical purity of the ALD grown materials was analyzed by x-ray photoelectron...

  6. Fabrication of high aspect ratio TiO{sub 2} and Al{sub 2}O{sub 3} nanogratings by atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Shkondin, Evgeniy, E-mail: eves@fotonik.dtu.dk [Department of Photonics Engineering, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark and Danish National Center for Micro- and Nanofabrication (DANCHIP), DK-2800 Kongens Lyngby (Denmark); Takayama, Osamu; Lavrinenko, Andrei V. [Department of Photonics Engineering, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark); Lindhard, Jonas Michael; Larsen, Pernille Voss; Mar, Mikkel Dysseholm; Jensen, Flemming [Danish National Center for Micro- and Nanofabrication (DANCHIP), DK-2800 Kongens Lyngby (Denmark)

    2016-05-15

    The authors report on the fabrication of TiO{sub 2} and Al{sub 2}O{sub 3} nanostructured gratings with an aspect ratio of up to 50. The gratings were made by a combination of atomic layer deposition (ALD) and dry etch techniques. The workflow included fabrication of a Si template using deep reactive ion etching followed by ALD of TiO{sub 2} or Al{sub 2}O{sub 3}. Then, the template was etched away using SF{sub 6} in an inductively coupled plasma tool, which resulted in the formation of isolated ALD coatings, thereby achieving high aspect ratio grating structures. SF{sub 6} plasma removes silicon selectively without any observable influence on TiO{sub 2} or Al{sub 2}O{sub 3}, thus revealing high selectivity throughout the fabrication. Scanning electron microscopy was used to analyze every fabrication step. Due to nonreleased stress in the ALD coatings, the top parts of the gratings were observed to bend inward as the Si template was removed, thus resulting in a gradual change in the pitch value of the structures. The pitch on top of the gratings is 400 nm, and it gradually reduces to 200 nm at the bottom. The form of the bending can be reshaped by Ar{sup +} ion beam etching. The chemical purity of the ALD grown materials was analyzed by x-ray photoelectron spectroscopy. The approach presented opens the possibility to fabricate high quality optical metamaterials and functional nanostructures.

  7. FFT-impedance spectroscopy analysis of the growth of magnetic metal nanowires in ultra-high aspect ratio InP membranes

    Science.gov (United States)

    Gerngross, M.-D.; Carstensen, J.; Föll, H.; Adelung, R.

    2016-01-01

    This paper reports on the characterization of the electrochemical growth process of magnetic nanowires in ultra-high-aspect ratio InP membranes via in situ fast Fourier transform impedance spectroscopy in a typical frequency range from 75 Hz to 18.5 kHz. The measured impedance data from the Ni, Co, and FeCo can be very well fitted using the same electric equivalent circuit consisting of a series resistance in serial connection to an RC-element and a Maxwell element. The impedance data clearly indicate the similarities in the growth behavior of Ni, Co and FeCo nanowires in ultra-high aspect ratio InP membranes—the beneficial impact of boric acid on the metal deposition in ultra-high aspect ratio membranes and the diffusion limitation of boric acid, as well as differences such as passivation or side reactions.

  8. Electrodeposition of Gold to Conformally Fill High Aspect Ratio Nanometric Silicon Grating Trenches: A Comparison of Pulsed and Direct Current Protocols

    OpenAIRE

    Znati, Sami A.; Chedid, Nicholas; Miao, Houxun; Chen,Lei; Bennett, Eric E.; Wen, Han

    2015-01-01

    Filling high-aspect-ratio trenches with gold is a frequent requirement in the fabrication of x-ray optics as well as micro-electronic components and other fabrication processes. Conformal electrodeposition of gold in sub-micron-width silicon trenches with an aspect ratio greater than 35 over a grating area of several square centimeters is challenging and has not been described in the literature previously. A comparison of pulsed plating and constant current plating led to a gold electroplatin...

  9. Sharp high-aspect-ratio AFM tips fabricated by a combination of deep reactive ion etching and focused ion beam techniques.

    Science.gov (United States)

    Caballero, David; Villanueva, Guillermo; Plaza, Jose Antonio; Mills, Christopher A; Samitier, Josep; Errachid, Abdelhamid

    2010-01-01

    The shape and dimensions of an atomic force microscope tip are crucial factors to obtain high resolution images at the nanoscale. When measuring samples with narrow trenches, inclined sidewalls near 90 degrees or nanoscaled structures, standard silicon atomic force microscopy (AFM) tips do not provide satisfactory results. We have combined deep reactive ion etching (DRIE) and focused ion beam (FIB) lithography techniques in order to produce probes with sharp rocket-shaped silicon AFM tips for high resolution imaging. The cantilevers were shaped and the bulk micromachining was performed using the same DRIE equipment. To improve the tip aspect ratio we used FIB nanolithography technique. The tips were tested on narrow silicon trenches and over biological samples showing a better resolution when compared with standard AFM tips, which enables nanocharacterization and nanometrology of high-aspect-ratio structures and nanoscaled biological elements to be completed, and provides an alternative to commercial high aspect ratio AFM tips.

  10. Numerical design of X-ray tabletop Talbot interferometer using polycapillary optics as two-dimensional gratings with high aspect ratio

    Science.gov (United States)

    Sun, Weiyuan; Liu, Zhiguo; Sun, Tianxi; Sun, Xuepeng; Li, Fangzuo; Jiang, Bowen; Ding, Xunliang

    2015-12-01

    The polycapillary optics was proposed to be used as two-dimensional X-ray gratings with high aspect ratios for high energy X-rays. The X-ray Talbot interferometer was designed numerically using the polycapillary X-ray gratings and a conventional X-ray source. The simulation showed that it was available to get a high-aspect-ratio pattern of the polycapillary X-ray gratings for higher energies than 60 keV. Moreover, this design of polycapillary gratings decreased the requirement for high power of the X-ray source. The polycapillary X-ray gratings had potential applications in X-ray imaging technology for medical fields, industrial nondestructive tests, public security, physical science, chemical analysis, life science, nanoscience biology and energy science.

  11. Electrically conducting, ultra-sharp, high aspect-ratio probes for AFM fabricated by electron-beam-induced deposition of platinum

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Jason, E-mail: jason.brown@physics.ox.ac.uk [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Kocher, Paul; Ramanujan, Chandra S; Sharp, David N [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Torimitsu, Keiichi [NTT Basic Research Laboratories, NTT Corporation, Atsugi, 243-0198 (Japan); Ryan, John F [Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom)

    2013-10-15

    We report on the fabrication of electrically conducting, ultra-sharp, high-aspect ratio probes for atomic force microscopy by electron-beam-induced deposition of platinum. Probes of 4.0 ±1.0 nm radius-of-curvature are routinely produced with high repeatability and near-100% yield. Contact-mode topographical imaging of the granular nature of a sputtered gold surface is used to assess the imaging performance of the probes, and the derived power spectral density plots are used to quantify the enhanced sensitivity as a function of spatial frequency. The ability of the probes to reproduce high aspect-ratio features is illustrated by imaging a close-packed array of nanospheres. The electrical resistance of the probes is measured to be of order 100 kΩ. - Highlights: • Electrically conducting, ultra-sharp, high aspect-ratio probes for AFM with radius-of-curvature 4.0±±1.0 nm. • AFM probe fabrication by electron-beam-induced deposition of platinum. • Enhanced spatial resolution demonstrated through AFM of sputtered gold grains. • AFM imaging of deep clefts and recesses on a close-packed array of nanospheres.

  12. Electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes: FFT-impedance spectroscopy of the growth process and magnetic properties

    Science.gov (United States)

    2014-01-01

    The electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes has been investigated by fast Fourier transform-impedance spectroscopy (FFT-IS) in the frequency range from 75 Hz to 18.5 kHz. The impedance data could be fitted very well using an electric circuit equivalent model with a series resistance connected in series to a simple resistor-capacitor (RC) element and a Maxwell element. Based on the impedance data, the Co deposition in ultra-high aspect ratio InP membranes can be divided into two different Co deposition processes. The corresponding share of each process on the overall Co deposition can be determined directly from the transfer resistances of the two processes. The impedance data clearly show the beneficial impact of boric acid on the Co deposition and also indicate a diffusion limitation of boric acid in ultra-high aspect ratio InP membranes. The grown Co nanowires are polycrystalline with a very small grain size. They show a narrow hysteresis loop with a preferential orientation of the easy magnetization direction along the long nanowire axis due to the arising shape anisotropy of the Co nanowires. PMID:25050088

  13. Electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes: FFT-impedance spectroscopy of the growth process and magnetic properties

    Science.gov (United States)

    Gerngross, Mark-Daniel; Carstensen, Jürgen; Föll, Helmut

    2014-06-01

    The electrochemical growth of Co nanowires in ultra-high aspect ratio InP membranes has been investigated by fast Fourier transform-impedance spectroscopy (FFT-IS) in the frequency range from 75 Hz to 18.5 kHz. The impedance data could be fitted very well using an electric circuit equivalent model with a series resistance connected in series to a simple resistor-capacitor ( RC) element and a Maxwell element. Based on the impedance data, the Co deposition in ultra-high aspect ratio InP membranes can be divided into two different Co deposition processes. The corresponding share of each process on the overall Co deposition can be determined directly from the transfer resistances of the two processes. The impedance data clearly show the beneficial impact of boric acid on the Co deposition and also indicate a diffusion limitation of boric acid in ultra-high aspect ratio InP membranes. The grown Co nanowires are polycrystalline with a very small grain size. They show a narrow hysteresis loop with a preferential orientation of the easy magnetization direction along the long nanowire axis due to the arising shape anisotropy of the Co nanowires.

  14. A study of high-altitude manned research aircraft employing strut-braced wings of high-aspect-ratio

    Science.gov (United States)

    Smith, P. M.; Deyoung, J.; Lovell, W. A.; Price, J. E.; Washburn, G. F.

    1981-01-01

    The effect of increased wing aspect ratio of subsonic aircraft on configurations with and without strut bracing. Results indicate that an optimum cantilever configuration, with a wing aspect ratio of approximately 26, has a 19% improvement in cruise range when compared to a baseline concept with a wing aspect ratio of approximately 10. An optimum strut braced configuration, with a wing aspect ratio of approximately 28, has a 31% improvment in cruise range when compared to the same baseline concept. This improvement is mainly due to the estimated reduction in wing weight resulting from use of lifting struts. All configurations assume the same mission payload and fuel. The drag characteristics of the wings are enhanced with the use of laminar flow airfoils. A method for determining the extent of attainable natural laminar flow, and methods for preliminary structural design and for aerodynamic analysis of wings lifting struts are presented.

  15. Narrow conductive structures with high aspect ratios through single-pass inkjet printing and evaporation-induced dewetting

    NARCIS (Netherlands)

    Abbel, R.; Teunissen, P.; Michels, J.; Groen, W.A.

    2015-01-01

    Inkjet printed silver lines contract to widths below 20-μm during drying on an organic planarization coating. Aspect ratios previously unprecedented with single pass inkjet printing on isotropic homogeneous substrates are obtained. This effect is caused by the subsequent evaporation of solvents from

  16. Fabrication of high-aspect-ratio microstructures in polymer microfluid chips for in vitro single-cell analysis

    Science.gov (United States)

    Bukatin, A. S.; Mukhin, I. S.; Malyshev, E. I.; Kukhtevich, I. V.; Evstrapov, A. A.; Dubina, M. V.

    2016-10-01

    Technologies and methods of prototyping microfluidic devices are widely used in solving many biological problems and testing of operability of new microanalytic systems. This study is devoted to analyzing the features of the formation of microstructures in SU-8 photoresist and the preparation of replicas in polydimethyl siloxane by the soft lithography method. It has been shown that the aspect ratio of the resultant microstructures is determined by their shape, size, and the force of resist adhesion to the silicon substrate and the efficiency of the circulation of the developer around microstructures. In the replication of complex microstructures, an aspect ratio of 25 is attained. The technology considered here is used to prepare microfluidic chips with mechanical traps for fixation and the in vitro analysis of living cells.

  17. Conductivity and methanol permeability of Nafion-zirconium phosphate composite membranes containing high aspect ratio filler particles

    Energy Technology Data Exchange (ETDEWEB)

    Bagnasco, G.; Micoli, L.; Turco, M. [Dipartimento di Ingegneria Chimica, Universita di Napoli Federico II, P.le V. Tecchio 80, 80125 - Napoli (Italy); Donnadio, A.; Pica, M.; Sganappa, M. [Dipartimento di Chimica, Universita di Perugia, via Elce di Sotto 8, 06123 - Perugia (Italy); Casciola, M.

    2009-08-15

    Gels of exfoliated {alpha}-zirconium phosphate (ZrP{sub exf}) in dimethylformamide (DMF) were used to prepare Nafion/ZrP{sub exf} composite membranes with filler loadings up to 7 wt.-% by casting mixtures of Nafion 1100 solutions in DMF and suitable amounts of 2 wt.-% ZrP gels in DMF. TEM pictures showed that the ZrP{sub exf} particles had aspect ratio of at least 20. All samples were characterised by methanol permeability (P) and through-plane ({sigma}{sub thp}) and in-plane ({sigma}{sub inp}) conductivity measurements at 40 C and 100% RH. The methanol permeability of Nafion membranes containing in situ grown ZrP particles with low aspect ratio (Nafion/ZrP{sub isg}) was also determined. The methanol permeability and the swelling behaviour of the composite membranes turned out to be strongly dependent on the filler morphology. As a general trend, both permeability and swelling decreased according to the sequence: Nafion/ZrP{sub isg} > Nafion > Nafion/ZrP{sub exf}. The maximum selectivity ({sigma}{sub thp}/P = 1.4 x 10{sup 5} S cm{sup -3} s) was found for the membrane filled with 1 wt.-% ZrP{sub exf}: this value is seven times higher than that of Nafion. For the Nafion/ZrP{sub exf} membranes, the ratio {sigma}{sub inp}/{sigma}{sub thp} increases with the filler loading, thus indicating that the preferred orientation of the ZrP sheets is parallel to the membrane surface. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  18. High aspect ratio, nanostructured, platinum based electrodes for proton exchange membrane fuel cells: Design, development and ionic conduction of the proposed structures

    Science.gov (United States)

    Paschos, Odysseas

    High aspect ratio nanostructures can provide substantial benefits when used as fuel cell electrodes since they can alleviate problems associated with conventional carbon supports. In this work the potential of incorporating high aspect ratio nanostructures as electrodes for fuel cells was studied. Moreover, a model was created that demonstrated the potential for the nanostructures to yield high performance. The creation of Pt nanorods using anodic aluminum oxide templates was investigated and experiments showed complete utilization of the electrodes surface area. However, the Pt nanorod structure was found to not be effective in terms of Pt mass utilization, since only the outer surface of the rod is utilized for catalytic activity. An alternate method was developed to coat (with Pt) high aspect ratio structures made from a cost-effective support material. Thus far, methods used to conformally coat Pt either cannot be used directly on several materials or tend not to be cost-effective. A non-vacuum method based on an Aerosol Assisted Deposition (AAD) technique was developed and optimized. Initial experiments showed feasibility of the technique to coat a large variety of substrates. Dimensions of the particles were controlled by the deposition parameters and ranged from 4 nm up to several hundreds of nm in diameter. Experiments where Pt nanoparticles were deposited on gas diffusion layer substrates, showed higher electrochemical performance compared to commercial catalyst. The need for electrolyte coating on the high aspect ratio structures was also investigated. Initial experiments were performed by splitting an MEA in half and using an intermediate Pt film. These experiments showed that ionic conduction on Pt surface is possible. Moreover these studies indicated that ionic conduction on Pt could result from hydrophilic groups that can exist on its surface. Since these groups can either be physisorbed due to presence of water or chemisorbed on the oxidized Pt

  19. Internal Laser Writing of High-Aspect-Ratio Microfluidic Structures in Silicate Glasses for Lab-on-a-Chip Applications

    Directory of Open Access Journals (Sweden)

    Ya Cheng

    2017-02-01

    Full Text Available Femtosecond laser direct writing is unique in allowing for fabrication of 3D micro- and nanofluidic structures, thereby enabling rapid and efficient manipulation of fluidic dynamics in 3D space to realize innovative functionalities. Here, I discuss the challenges in producing fully functional and highly integrated 3D micro- and nanofluidic systems with potential applications ranging from chemical and biological analyses to investigations of nanofluidic behaviors. In particular, I review the achievements we have made in the past decade, which have led to 3D microchannels with controllable cross-sectional profiles and large aspect ratios, 3D nanofluidic channels with widths of several tens of nanometers, and smooth inner walls with roughness on the order of ~1 nm. Integration of the microfluidics with other functional microcomponents including microoptics and microelectrodes will also be discussed, followed by conclusions and the future perspective.

  20. Application of Self-Assembled Monolayers to the Electroless Metallization of High Aspect Ratio Vias for Microelectronics

    Science.gov (United States)

    Bernasconi, R.; Molazemhosseini, A.; Cervati, M.; Armini, S.; Magagnin, L.

    2016-10-01

    All-wet electroless metallization of through-silicon vias (TSVs) with a width of 5 μm and a 1:10 aspect ratio was carried out. Immersion in a n-(2-aminoethyl) 3-aminopropyl-trimethoxysilane (AEAPTMS) self-assembled monolayer (SAM) was used to enhance the adhesion between the metal film and substrate. Contact angle variation and atomic force microscopy were used to verify the formation of a SAM layer. A PdCl2 solution was later used to activate the silanized substrates, exploiting the affinity of the -NH3 functional group of AEAPTMS to palladium. A nickel-phosphorus-boron electroless bath was employed to deposit the first barrier layer onto silicon. The NiPB growth rate was evaluated on flat silicon wafers, while the structure of the coating obtained was investigated via glow discharge optical emission spectroscopy. Cross-sectional scanning electron microscope observations were carried out on metallized TSVs to characterize the NiPB seed, the Cu seed layer deposited with a second electroless step, and the Cu superfilling obtained with a commercial solution. Complete filling of TSV was achieved.

  1. An implicit wetting and drying approach for non-hydrostatic baroclinic flows in high aspect ratio domains

    Science.gov (United States)

    Candy, A. S.

    2017-04-01

    A new approach to modelling free surface flows is developed that enables, for the first time, 3D consistent non-hydrostatic baroclinic physics that wets and drys in the large aspect ratio spatial domains that characterise geophysical systems. This is key in the integration of physical models to permit seamless simulation in a single consistent arbitrarily unstructured multiscale and multi-physics dynamical model. A high order continuum representation is achieved through a general Galerkin finite element formulation that guarantees local and global mass conservation, and consistent tracer advection. A flexible spatial discretisation permits conforming domain bounds and a variable spatial resolution, whilst atypical use of fully implicit time integration ensures computational efficiency. Notably this brings the natural inclusion of non-hydrostatic baroclinic physics and a consideration of vertical inertia to flood modelling in the full 3D domain. This has application in improving modelling of inundation processes in geophysical domains, where dynamics proceeds over a large range of horizontal extents relative to vertical resolution, such as in the evolution of a tsunami, or in urban environments containing complex geometric structures at a range of scales.

  2. A high aspect ratio SU-8 fabrication technique for hollow microneedles for transdermal drug delivery and blood extraction

    Science.gov (United States)

    Chaudhri, Buddhadev Paul; Ceyssens, Frederik; De Moor, Piet; Van Hoof, Chris; Puers, Robert

    2010-06-01

    Protein drugs, e.g. hormonal drugs, cannot be delivered orally to a patient as they get digested in the gastro-intestinal (GI) tract. Thus, it is imperative that these kinds of drugs are delivered transdermally through the skin. To provide for real-time feedback as well as to test independently for various substances in the blood, we also need a blood sampling system. Microneedles can perform both these functions. Further, microneedles made of silicon or metal have the risk of breaking inside the skin thereby leading to complications. SU-8, being approved of as being biocompatible by the Food and Drug Agency (FDA) of the United States, is an attractive alternative because firstly it is a polymer material, thereby reducing the chances of breakages inside the skin, and secondly it is a negative photoresist, thereby leading to ease of fabrication. Thus, here we present very tall (around 1600 µm) SU-8 polymer-based hollow microneedles fabricated by a simple and repeatable process, which are a very good candidate for transdermal drug delivery as well as blood extraction. The paper elaborates on the details that allow the fabrication of such extreme aspect ratios (>100).

  3. Solution Process Synthesis of High Aspect Ratio ZnO Nanorods on Electrode Surface for Sensitive Electrochemical Detection of Uric Acid

    Science.gov (United States)

    Ahmad, Rafiq; Tripathy, Nirmalya; Ahn, Min-Sang; Hahn, Yoon-Bong

    2017-04-01

    This study demonstrates a highly stable, selective and sensitive uric acid (UA) biosensor based on high aspect ratio zinc oxide nanorods (ZNRs) vertical grown on electrode surface via a simple one-step low temperature solution route. Uricase enzyme was immobilized on the ZNRs followed by Nafion covering to fabricate UA sensing electrodes (Nafion/Uricase-ZNRs/Ag). The fabricated electrodes showed enhanced performance with attractive analytical response, such as a high sensitivity of 239.67 μA cm-2 mM-1 in wide-linear range (0.01-4.56 mM), rapid response time (~3 s), low detection limit (5 nM), and low value of apparent Michaelis-Menten constant (Kmapp, 0.025 mM). In addition, selectivity, reproducibility and long-term storage stability of biosensor was also demonstrated. These results can be attributed to the high aspect ratio of vertically grown ZNRs which provides high surface area leading to enhanced enzyme immobilization, high electrocatalytic activity, and direct electron transfer during electrochemical detection of UA. We expect that this biosensor platform will be advantageous to fabricate ultrasensitive, robust, low-cost sensing device for numerous analyte detection.

  4. Protein-enabled layer-by-layer syntheses of aligned, porous-wall, high-aspect-ratio TiO{sub 2} nanotube arrays

    Energy Technology Data Exchange (ETDEWEB)

    Berrigan, John D.; Cai, Ye; Sandhage, Kenneth H. [School of Materials Science and Engineering, Air Force Center of Excellence on Bio-Nano-Enabled Inorganic/Organic Nanocomposites and Improved Cognition (BIONIC), Georgia Institute of Technology, 771 Ferst Drive, Atlanta, Georgia 30332-0400 (United States); Kang, Tae-Sik; Deneault, James R.; Durstock, Michael F. [Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio, 45433-7702 (United States)

    2011-05-10

    An aqueous, protein-enabled (biomimetic), layer-by-layer titania deposition process is developed, for the first time, to convert aligned-nanochannel templates into high-aspect-ratio, aligned nanotube arrays with thin (34 nm) walls composed of co-continuous networks of pores and titania nanocrystals (15 nm ave. size). Alumina templates with aligned open nanochannels are exposed in an alternating fashion to aqueous protamine-bearing and titania precursor-bearing (Ti(IV) bis-ammonium-lactato-dihydroxide, TiBALDH) solutions. The ability of protamine to bind to alumina and titania, and to induce the formation of a Ti-O-bearing coating upon exposure to the TiBALDH precursor, enables the layer-by-layer deposition of a conformal protamine/Ti-O-bearing coating on the nanochannel surfaces within the porous alumina template. Subsequent protamine pyrolysis yields coatings composed of co-continuous networks of pores and titania nanoparticles. Selective dissolution of the underlying alumina template through the porous coating then yields freestanding, aligned, porous-wall titania nanotube arrays. The interconnected pores within the nanotube walls allow enhanced loading of functional molecules (such as a Ru-based N719 dye), whereas the interconnected titania nanoparticles enable the high-aspect-ratio, aligned nanotube arrays to be used as electrodes (as demonstrated for dye-sensitized solar cells with power conversion efficiencies of 5.2 {+-} 0.4%). (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. High-Yield Synthesis of Uniform Ag Nanowires with High Aspect Ratios by Introducing the Long-Chain PVP in an Improved Polyol Process

    Directory of Open Access Journals (Sweden)

    Jie-Jun Zhu

    2011-01-01

    Full Text Available Polyvinyl pyrrolidone (PVP with different molecular weights was used as capping agent to synthesize silver nanowires through a polyol process. The results indicated that the yields and aspect ratios of silver nanowires were controlled by the chain length of PVP and increased with increasing the molecular weight (MW of PVP. When the long-chain PVP-K90 (MW = 800,000 was used, the product was uniform in size and was dominated by nanowires with high aspect ratios. The growth mechanism of the nanowires was studied. It is proposed that the chemical adsorption of Ag+ on the PVP chains at the initial stage promotes the growth of Ag nanowires.

  6. Fabrication of high aspect ratio TiOsub>2sub> and Alsub>2sub>O>3sub> nanogratings by atomic layer deposition

    DEFF Research Database (Denmark)

    Shkondin, Evgeniy; Takayama, Osamu; Michael-Lindhard, Jonas

    2016-01-01

    The authors report on the fabrication of TiO2 and Al2O3 nanostructured gratings with an aspect ratio of up to 50. The gratings were made by a combination of atomic layer deposition (ALD) and dry etch techniques. The workflow included fabrication of a Si template using deep reactive ion etching...

  7. Low-temperature plasma etching of high aspect-ratio densely packed 15 to sub-10 nm silicon features derived from PS-PDMS block copolymer patterns.

    Science.gov (United States)

    Liu, Zuwei; Gu, Xiaodan; Hwu, Justin; Sassolini, Simone; Olynick, Deirdre L

    2014-07-18

    The combination of block copolymer (BCP) lithography and plasma etching offers a gateway to densely packed sub-10 nm features for advanced nanotechnology. Despite the advances in BCP lithography, plasma pattern transfer remains a major challenge. We use controlled and low substrate temperatures during plasma etching of a chromium hard mask and then the underlying substrate as a route to high aspect ratio sub-10 nm silicon features derived from BCP lithography. Siloxane masks were fabricated using poly(styrene-b-siloxane) (PS-PDMS) BCP to create either line-type masks or, with the addition of low molecular weight PS-OH homopolymer, dot-type masks. Temperature control was essential for preventing mask migration and controlling the etched feature's shape. Vertical silicon wire features (15 nm with feature-to-feature spacing of 26 nm) were etched with aspect ratios up to 17 : 1; higher aspect ratios were limited by the collapse of nanoscale silicon structures. Sub-10 nm fin structures were etched with aspect ratios greater than 10 : 1. Transmission electron microscopy images of the wires reveal a crystalline silicon core with an amorphous surface layer, just slightly thicker than a native oxide.

  8. High Aspect Ratio Silver Conductive Tracks in Inkjet Printing%喷墨打印制备高“高宽比”银导线工艺

    Institute of Scientific and Technical Information of China (English)

    张磊; 朱云龙; 程晓鼎; 王驰远

    2016-01-01

    传统丝网印刷技术因其接触式印刷工艺难以提高金属导线的精度和“高宽比”,为实现高“高宽比”的金属导线制造,以低黏度纳米银墨水为喷墨材料,采用自主研发的喷墨打印设备在多种基材表面打印银导线.通过喷墨打印实验方法研究了喷墨打印过程的“咖啡环”及“马鞍型”缺陷产生原理及影响因素,通过在Teslin、Kapton、多晶硅硅片及高光相纸4种基材上多层打印及改变基板温度制备银导线,研究了银导线“高宽比”及三维形貌的变化关系.实验结果表明:基板温度在60℃时,打印的银导线呈“拱型”;基板温度在80℃时,打印的银导线“高宽比”最佳且受基材影响减弱.打印层数为20层时,导线边缘出现波浪纹;打印层数为80层时,波浪纹消失,导线形貌均匀.烧结温度为200℃时,银导线导电能力得到极大提升,Teslin基材形成的银导线电阻率最低至2.13μΩ·cm.%It' s difficult to improve the accuracy and aspect ratio of conductive tracks for the traditional screen printing technology. In order to achieve high aspect ratio of conductive tracks, an ink jet printing method for fabrication of high aspect ratio silver tracks was described. The mechanisms and influence factors of coffee-ring and M-type effect were revealed by experiments. The experiments of multi-pass inkjet printing on Teslin, Kapton, Polycrystalline silicon, glossy photo paper and altering substrates temperature procedure were carried out. The results show that when the substrate temperature is 60℃, the arch-type silver tracks are formed. When the substrate temperature is 80 ℃, the optimized aspect ratio of silver tracks is formed and the influence by different substrates is weak. As inkjet printing runs 20 pass, wave form on the edge of silver tracks comes out. When inkjet printing runs 80 pass, wave form fades away and high aspect ratio silver tracks are fabricated instead. When

  9. Design, fabrication and characterization of high-stroke high-aspect ratio micro electro mechanical systems deformable mirrors for adaptive optics

    Science.gov (United States)

    Fernandez Rocha, Bautista

    Adaptive optic (AO) systems for next generation of extremely large telescopes (30--50 meter diameter primary mirrors) require high-stroke (10 microns), high-order (100x100) deformable mirrors at lower-cost than current technology. The required specifications are achievable with Micro Electro Mechanical Systems (MEMS) devices fabricated with high-aspect ratio processing techniques. This dissertation will review simulation results compared with displacement measurements of actuators utilizing a white-light interferometer. It will also review different actuator designs, materials and post-processing procedures fabricated in three different high-aspect ratio processes, Microfabrica's Electrochemical Fabrication (EFAB(TM)), HT-Micro's Precision Fabrication Technology (HTPF(TM)), and Innovative Micro Technologies (IMT) fabrication process. These manufacturing processes allow high-precision multilayer fabrication and their sacrificial layer thicknesses can be specified by the designer, rather than by constraints of the fabrication process. Various types of high-stroke gold actuators for AO consisting of folded springs with rectangular and circular membranes as well as X-beam actuators supported diagonally by beams were designed, simulated, fabricated, and tested individually and as part of a continuous facesheet DM system. The design, modeling and simulation of these actuators are compared to experimental measurements of their pull-in voltages, which characterizes their stiffness and maximum stroke. Vertical parallel plate ganged actuators fabricated with the EFAB(TM) process have a calculated pull-in voltage of 95V for a 600mum size device. In contrast, the pull-in voltages for the comb-drive actuators ranged from 55V for the large actuator, to 203V for the smallest actuator. Simulations and interferometer scans of actuator designs fabricated with HT-Micro's Precision Fabrication (HTPF(TM)) two wafer bonded process with different spring supports have shown the ability of

  10. 高厚径比HDI板电镀能力研究%Plating ability Of HDI with high aspect ratio item

    Institute of Scientific and Technical Information of China (English)

    班向东

    2013-01-01

    With the development of information technology, more layers, thickness, aperture smaller, thicker wiring denser PCB needs PCB manufacturers put forward higher requirements. High aspect ratio and BMV plating are two different processing direction of PCB plating, and the two requirements of both the product processing is the dififculty of electroplating. So to ifnd a balance between the two is very important. Through the experiment, we found the electroplating parameters, achieved the balance of the blind holes.%随着信息技术的不断发展,层数更多、板厚更厚、孔径更小、布线更密的PCB需求给PCB生产厂家提出的更高的要求。高纵横比与盲孔电镀是PCB电镀的两个不同的加工方向,而这两种要求并存的产品加工是电镀的难点,因此找到两者之间的平衡点至关重要。本文通过实验,找到两者兼顾的电镀参数,达到通盲孔兼顾的效果。

  11. Fabrication of high-aspect-ratio double-slot photonic crystal waveguide in InP heterostructure by inductively coupled plasma etching using ultra-low pressure

    Directory of Open Access Journals (Sweden)

    Kaiyu Cui

    2013-02-01

    Full Text Available Double-slot photonic crystal waveguide (PCW in InP heterostructure is fabricated by inductively coupled plasma (ICP etching. Due to using an ultra-low pressure of 0.05 Pa, etch depths up to 3.5 μm for holes with diameter of 200 nm and 1.8 μm for slots of ∼40 nm are achieved, which indicate a record-high aspect-ratio, i.e. 45, for such narrow slots in InP heterostructure. Moreover, etching quality is evaluated based on both the transmission performance and the linewidth of micro-photoluminescence (μ-PL. In our measurement, a structure-dependent transmission-dip about 17 dB is obtained from a 17-μm-long W3 PCW, and a PL widening as small as 19 nm compared to the corresponding wafer is observed. These promising experimental results evidence the high etching quality realized in this work and confirm the feasibility of etching small-feature-size patterns by ICP technology for InP based devices in future mono-/hetero-integrated photonic circuits.

  12. Catalytic Synthesis of Substrate-Free, Aligned and Tailored High Aspect Ratio Multiwall Carbon Nanotubes in an Ultrasonic Atomization Head CVD Reactor

    Directory of Open Access Journals (Sweden)

    Fahad Ali Rabbani

    2016-01-01

    Full Text Available Chemical vapor deposition (CVD method has proven its benchmark, over other methods, for the production of different types of carbon nanotubes (CNT on commercial and lab scale. In this study, an injection vertical CVD reactor fitted with an ultrasonic atomization head was used in a pilot-plant scale (height 274 cm, radius 25 cm for semicontinuous production of multiwall carbon nanotubes (MWCNTs. p-Xylene was used as a hydrocarbon precursor in which ferrocene was dissolved and provided the cracking catalyst. Atomization of the feed solution resulted in full and even dispersion of the catalytic solution. This dispersion led to the production of high aspect ratio MWCNTs (ranging from 8,000 to 12,000 at 850°C. Different experimental parameters affecting the quality and quantity of the produced CNTs were investigated. These included temperature, reaction time, and flow rate of the reaction and carrier gases. Different properties of the produced CNTs were characterized using SEM and TEM, while TGA was used to evaluate their purity. Specific surface area of selected samples was calculated by BET.

  13. Self-organization and FORC-based magnetic characterization of ultra-high aspect ratio epitaxial Co nanostrips produced by oblique deposition on an ordered step-bunched silicon surface

    Science.gov (United States)

    Ognev, A. V.; Ermakov, K. S.; Samardak, A. Yu; Kozlov, A. G.; Sukovatitsina, E. V.; Davydenko, A. V.; Chebotkevich, L. A.; Stancu, A.; Samardak, A. S.

    2017-03-01

    Further development of microelectronics requires novel or improved technological approaches for device nanofabrication and functional properties characterization. In this paper, we studied the crystal structure and magnetic properties of epitaxial Co nanostrips with the average width of 32.6, 45.3, and 62.6 nm grown on a step-bunched Si(111)5.55 × 5.55-Cu/Cu surface. Technological conditions, under which the ultra-high aspect ratio (˜104) structurally solid, straight nanostrips of hcp-Co with crystallographic axis [0001] oriented along their long side can be grown, were determined. The dependence of the coercive force on the width of the nanostrips was demonstrated. Magnetization reversal through the transverse domain-wall nucleation and propagation in a Co nanostrip was defined with an analytical approach based on the Stoner-Wohlfarth model. Using the first-order reversal curve method, we analyzed the effect of nanostrip uniformity degree on magnetic behavior and the influence of the magnetostatic interactions on the coercive force of individual nanostrips.

  14. Enhancing the Wettability of High Aspect-Ratio Through-Silicon Vias Lined with LPCVD Silicon Nitride or PE-ALD Titanium Nitride for Void-Free Bottom-Up Copper Electroplating

    NARCIS (Netherlands)

    Saadaoui, M.; van Zeijl, H.; Wien, W. H. A.; Pham, H. T. M.; Kwakernaak, C.; Knoops, H. C. M.; Kessels, W. M. M.; R. van de Sanden,; Voogt, F. C.; Roozeboom, F.; Sarro, P. M.

    2011-01-01

    One of the critical steps toward producing void-free and uniform bottom-up copper electroplating in high aspect-ratio (AR) through-silicon vias (TSVs) is the ability of the copper electrolyte to spontaneously flow through the entire depth of the via. This can be accomplished by reducing the concentr

  15. Transonic steady- and unsteady-pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

    Science.gov (United States)

    Sandford, M. C.; Ricketts, R. H.; Cazier, F. W., Jr.

    1980-01-01

    A supercritical wing with an aspect ratio of 10.76 and with two trailing-edge oscillating control surfaces is described. The semispan wing is instrumented with 252 static orifices and 164 in situ dynamic-pressure gages for studying the effects of control-surface position and motion on steady- and unsteady-pressures at transonic speeds. Results from initial tests conducted in the Langley Transonic Dynamics Tunnel at two Reynolds numbers are presented in tabular form.

  16. 大展弦比飞翼布局飞机的三轴稳定特性%Three-axis stability characteristics of flying wing with high aspect ratio

    Institute of Scientific and Technical Information of China (English)

    张子军; 王磊; 王立新; 王晋军

    2012-01-01

    飞翼布局飞机取消了平尾和垂尾,构型的改变和阻力方向舵的使用使其呈现出与常规布局飞机不同的三轴稳定特性.以大展弦比飞翼布局飞机为研究对象,开展了其三轴静、动稳定特性的研究;通过与常规大展弦比飞机进行对比,揭示了飞翼构型参数、典型飞行状态对其稳定性的影响规律;分析了阻力方向舵的偏转对此类飞机稳定性的影响.研究结果表明,大展弦比飞翼布局飞机的本体稳定性存在诸多的不足.%A flying wing cancels horizontal and vertical tails, but the changes of configuration and the use of drag rudder make it differ much from the conventional configuration aircraft in three-axis stability characteristics. The aircraft chosen for the study is a flying wing with high aspect ratio. Its three-axis static and dynamic stability characteristics are studied. Comparing with the conventional configuration aircraft with high aspect ratio, the effects of configuration parameters and typical flight condition on the stabilities of the flying wing are discussed. The impact of the drag rudder on the stabilities of such aircraft types is also analyzed. Results show that there are many deficiencies in the inherent three-axis stabilities of the high aspect ratio flying wing.

  17. Alternative Observers for SI Engine Air/Fuel Ratio Control

    DEFF Research Database (Denmark)

    Hendricks, Elbert; Poulsen, Jannik; Olsen, Mads Bruun

    1996-01-01

    sensors other than a MAP sensor. In this paper it is shown that it is possible to construct a family of alternative nonlinear observers which “naturally” allow the use of any given air mass flow related sensor or a combination of them for A/F ratio control. This new family of observers provides the SI...

  18. 3-D Numerical Simulation and Analysis of Complex Fiber Geometry RaFC Materials with High Volume Fraction and High Aspect Ratio based on ABAQUS PYTHON

    Science.gov (United States)

    Jin, BoCheng

    2011-12-01

    Organic and inorganic fiber reinforced composites with innumerable fiber orientation distributions and fiber geometries are abundantly available in several natural and synthetic structures. Inorganic glass fiber composites have been introduced to numerous applications due to their economical fabrication and tailored structural properties. Numerical characterization of such composite material systems is necessitated due to their intrinsic statistical nature, which renders extensive experimentation prohibitively time consuming and costly. To predict various mechanical behavior and characterizations of Uni-Directional Fiber Composites (UDFC) and Random Fiber Composites (RaFC), we numerically developed Representative Volume Elements (RVE) with high accuracy and efficiency and with complex fiber geometric representations encountered in uni-directional and random fiber networks. In this thesis, the numerical simulations of unidirectional RaFC fiber strand RVE models (VF>70%) are first presented by programming in ABAQUS PYTHON. Secondly, when the cross sectional aspect ratios (AR) of the second phase fiber inclusions are not necessarily one, various types of RVE models with different cross sectional shape fibers are simulated and discussed. A modified random sequential absorption algorithm is applied to enhance the volume fraction number (VF) of the RVE, which the mechanical properties represents the composite material. Thirdly, based on a Spatial Segment Shortest Distance (SSSD) algorithm, a 3-Dimentional RaFC material RVE model is simulated in ABAQUS PYTHON with randomly oriented and distributed straight fibers of high fiber aspect ratio (AR=100:1) and volume fraction (VF=31.8%). Fourthly, the piecewise multi-segments fiber geometry is obtained in MATLAB environment by a modified SSSD algorithm. Finally, numerical methods including the polynomial curve fitting and piecewise quadratic and cubic B-spline interpolation are applied to optimize the RaFC fiber geometries

  19. Influence of Alkyl Trimethyl Ammonium Bromides on Hydrothermal Formation of α-CaSO4·0.5H2O Whiskers with High Aspect Ratios

    Directory of Open Access Journals (Sweden)

    Ruosong Chen

    2017-01-01

    Full Text Available In this paper, the influence of alkyl trimethyl ammonium bromides (CnH2n+1(CH33NBr, n = 10, 12, 14, 16, 18, abbreviated as ATAB on the formation of alpha calcium sulfate hemihydrate (α-CaSO4·0.5H2O whiskers under a hydrothermal condition (135 °C, 3.0 h was analyzed. Specifically, it focuses on cetyl trimethyl ammonium bromide (C16H33(CH33NBr, abbreviated as CTAB. The rising CTAB concentration from 0 to 9.2 × 10−4 mol·L−1 led to the increase of the average aspect ratio of α-CaSO4·0.5H2O whiskers from 80 to 430, since the selective adsorption of CTAB on the negatively-charged side facets of the whiskers inhibited the growth of the whiskers along the direction normal to the lateral facets. The further increase of CTAB concentration above the critical micelle concentration (abbreviated as CMC showed little effect on the morphology of α-CaSO4·0.5H2O whiskers, considering that CTAB tended to form micelles instead of being adsorbed on the whisker surfaces. Similar phenomena were observed in other ATABs (n = 10, 12, 14, 18.

  20. Fractionation and Characterization of High Aspect Ratio Gold Nanorods Using Asymmetric-Flow Field Flow Fractionation and Single Particle Inductively Coupled Plasma Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Thao M. Nguyen

    2015-07-01

    Full Text Available Gold nanorods (GNRs are of particular interest for biomedical applications due to their unique size-dependent longitudinal surface plasmon resonance band in the visible to near-infrared. Purified GNRs are essential for the advancement of technologies based on these materials. Used in concert, asymmetric-flow field flow fractionation (A4F and single particle inductively coupled mass spectrometry (spICP-MS provide unique advantages for fractionating and analyzing the typically complex mixtures produced by common synthetic procedures. A4F fractions collected at specific elution times were analyzed off-line by spICP-MS. The individual particle masses were obtained by conversion of the ICP-MS pulse intensity for each detected particle event, using a defined calibration procedure. Size distributions were then derived by transforming particle mass to length assuming a fixed diameter. The resulting particle lengths correlated closely with ex situ transmission electron microscopy. In contrast to our previously reported observations on the fractionation of low-aspect ratio (AR GNRs (AR < 4, under optimal A4F separation conditions the results for high-AR GNRs of fixed diameter (≈20 nm suggest normal, rather than steric, mode elution (i.e., shorter rods with lower AR generally elute first. The relatively narrow populations in late eluting fractions suggest the method can be used to collect and analyze specific length fractions; it is feasible that A4F could be appropriately modified for industrial scale purification of GNRs.

  1. Injection Molding of High Aspect Ratio Nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels Bent

    We present a process for injection molding of 40 nm wide and >100 nm high pillars (pitch: 200 nm). We explored the effects of mold coatings and injection molding conditions on the replication quality of nanostructures in cyclic olefin copolymer. We found that optimization of molding parameters...

  2. Wind-tunnel investigation of longitudinal and lateral-directional stability and control characteristics of a 0.237-scale model of a remotely piloted research vehicle with a thick, high-aspect-ratio supercritical wing

    Science.gov (United States)

    Byrdsong, T. A.; Brooks, C. W., Jr.

    1980-01-01

    A 0.237-scale model of a remotely piloted research vehicle equipped with a thick, high-aspect-ratio supercritical wing was tested in the Langley 8-foot transonic tunnel to provide experimental data for a prediction of the static stability and control characteristics of the research vehicle as well as to provide an estimate of vehicle flight characteristics for a computer simulation program used in the planning and execution of specific flight-research mission. Data were obtained at a Reynolds number of 16.5 x 10 to the 6th power per meter for Mach numbers up to 0.92. The results indicate regions of longitudinal instability; however, an adequate margin of longitudinal stability exists at a selected cruise condition. Satisfactory effectiveness of pitch, roll, and yaw control was also demonstrated.

  3. Low-speed aerodynamic performance of a high-aspect-ratio supercritical-wing transport model equipped with full-span slat and part-span double-slotted flaps

    Science.gov (United States)

    Morgan, H. L., Jr.; Paulson, J. W., Jr.

    1979-01-01

    An investigation was conducted in the Langley V/STOL tunnel to determine the static longitudinal and lateral-directional aerodynamic characteristics of an advanced high-aspect-ratio supercritical-wing transport model equipped with a full-span leading-edge slat and part-span double-slotted trailing-edge flaps. This wide-body transport model was also equipped with spoiler and aileron control surfaces, flow-through nacelles, landing gear, movable horizontal tails, and interchangeable wing tips with aspect ratios of 10 and 12. The model was tested with leading-edge slat and trailing-edge flap combinations representative of cruise, climb, takeoff, and landing wing configurations. The tests were conducted at free-stream conditions corresponding to Reynolds numbers (based on mean geometric chord) of 0.97 to 1.63 x 10 to the 6th power and corresponding Mach numbers of 0.12 to 0.20, through an angle-of-attack range of -2 deg to 24 deg and a sideslip-angle range of -10 deg to 5 deg.

  4. Study on Static Test Technology for High-Aspect Ratio Wing of Full Scale Aircraft%全尺寸飞机大展弦比机翼静力试验技术研究

    Institute of Scientific and Technical Information of China (English)

    刘兴科; 刘冰; 张建锋

    2014-01-01

    In the bearing capability static test of wing structure,because of the high-aspect ratio, the large deformation will arouse load direction changed.Taking the full scale aircraft structure as research obj ect,a test loading technology is proposed,which can realize the extractive wing loading.The static test of a certain type aircraft structure solves the problems of large deforma-tion loading,which has great realistic significance and application value.%在大展弦比飞机的机翼承载能力试验中,试验加载方向会因其大变形发生变化。本文以全尺寸结构机翼为研究对象,提出一种试验加载技术,最大程度实现机翼载荷的准确施加。通过此静强度试验,很好地解决了机翼试验大变形加载问题,具有较大的现实意义和应用价值。

  5. Aeroelastic response for straight wing with high aspect ratio due to sharp edge gust%锐边突风对大展弦比机翼的气动弹性响应影响

    Institute of Scientific and Technical Information of China (English)

    刘伏虎; 马晓平

    2012-01-01

    基于Theodorsen非定常气动力理论,以大展弦比均匀直机翼为研究对象,建立了系统的气动弹性响应方程.选取二阶弯曲和二阶扭转模态,采用V-g法求解了系统的颤振速度.基于Kussner函数,建立了锐边突风系统模型,并推导了在弯曲和扭转模态阶数为Nw和Na下的系统状态方程,仿真研究了加入突风后系统的气动弹性响应.结果表明,加入突风后翼尖响应振幅增大.%Based on Theodorsen unsteady aerodynamics theory, the equation of aeroelastic response for straight wing with high aspect ratio is established. Flutter speed is determined for two bending modes and two torsional modes using V-g methods. The sharp edge gust system model is established and the system state equations are derived with Nw bending modes and Na torsional modes wing systems based on the function Kussner. The aeroelastic response of system shows that the amplitude oscillation becomes higher. The modeling method may offer reference for research of gust response.

  6. Analysis Si/Al ratio in zeolites type FAU by laser induced breakdown spectroscopy (LIBS)

    Science.gov (United States)

    Contreras, W. A.; Cabanzo, R.; Mejía-Ospino, E.

    2011-01-01

    In this work, Laser Induced Breakdown Spectroscopy (LIBS) is used to determine the Si/Al ratio of Zeolite type Y. The catalytic activity of zeolite is strongly dependent of the Si/Al ratio. We have used Si lines in the spectral region between 245-265 nm to determine temperature of the plasma generated on pelletized sample of zeolite, and stoichiometry relation between Si and Al.

  7. SYNTHESIS OF HIGH SILICA CHA ZEOLITES WITH CONTROLLED Si/Al RATIO

    OpenAIRE

    2008-01-01

    Zeolites with the CHA topology have been synthesized with Si/Al ratios ranging from 15 to 133. ICP-AES analysis shows that the Si/Al ratio in the material is close to linearly related to the Si/Al ratio in the reaction mixture, while powder XRD shows that the unit cell parameters decrease with increasing Si/Al ratio. The difference between the unit cell parameters for the as-synthesized and the calcined samples show that the structure directing agent sterically hinders the contraction in the ...

  8. Preparation and Cytotoxicity of High-aspect-ratio Gold Nanorods at Single Cell Level%大长径比金纳米棒的合成及其单细胞毒性研究

    Institute of Scientific and Technical Information of China (English)

    周海英; 周瑞; 熊斌; 何彦

    2012-01-01

    利用三步晶种生长法合成长径比约为14的大长径比金纳米棒(GNR),利用巯基十一酸(MUDA)对金纳米棒表面进行了生物适应性修饰,并在宏观水平上研究了修饰前后的金纳米棒在对细胞活性的影响.利用单细胞方法分别考察了修饰后的纳米金棒对细胞贴壁过程、增殖速率、细胞内ROS以及骨架排布的影响.虽然MTT细胞活性结果显示内吞后的金纳米棒对细胞无毒,但单细胞毒性分析方法发现,不同浓度纳米金棒对早期贴壁过程有较小的影响,且内吞的纳米金棒在一定程度上促进了细胞的增殖,而高浓度下纳米金棒引起了细胞内ROS含量的升高,并破坏了细胞内骨架纤维排布.本研究建立了用单细胞行为分析纳米颗粒对细胞毒性的方法,证明了以往仅仅利用MTT等宏观手段分析纳米材料生物适应性是不足的.纳米材料在生物医学领域的进一步应用还应考虑单细胞及分子水平上的毒性效应.%We have synthesized high-aspect-ratio gold nanorods (GNR) by using a three-step seed-mediated growth method. The aspect ratio of the GNRs is approximately 14. The modification of the GNRs was achieved by replacing the CTAB molecules on the surface of gold nanorods with the 11-mercaptoundecanoic (MUDA) molecules. The cytotoxicity of the as-prepared GNRs and their effects on endocytosis, adhesion, proliferation, intracellular reactive oxygen species (ROS) level and cytoskeleton of the cells were studied. Interestingly, by using the 3-(4, 5-dimethylthiazol-2-yl) 2,5-diphenyl-tetrazolium bromide (MTT) assay, the GNRs did not show a significant toxicity to HeLa cells. However, single cell viability assays showed that GNR uptake could influence the cell adhesion at the early stage, though the effect was not much, and the cell proliferation was promoted to some degree. Moreover, large amounts of GNR uptake will lead to increased intracellular ROS level and impaired the cell skeleton.

  9. Corrosion characteristics of Al-Si-Mg/SiC{sub p} composites with varying Si/Mg molar ratio in neutral chloride solutions

    Energy Technology Data Exchange (ETDEWEB)

    Escalera-Lozano, R.; Pech-Canul, M.I. [Cinvestav Saltillo (Mexico); Pech-Canul, M.A.; Quintana, P. [Departamento de Fisica Aplicada, Merida, Yuc. (Mexico)

    2009-09-15

    The corrosion resistance of Al-Mg-Si/SiC{sub p} composites produced by the pressureless infiltration method [using SiC{sub p} preforms with 50% porosity containing rice hull ash (RHA) and four custom-made alloys with varying Si/Mg molar ratio] was evaluated in neutral 0.1 M NaCl solutions. The deleterious phase Al{sub 4}C{sub 3} was successfully suppressed in composites with Si/Mg molar ratios of 0.89 and 1.05, but not in those with lower Si/Mg molar ratios (0.12 and 0.49). Results of cyclic polarizations in deareated 0.1 M NaCl solutions showed that with increasing Si/Mg molar ratio, passive current density increased but pitting susceptibility decreased both for reinforced and unreinforced alloys. Immersion tests in aerated 0.1 M NaCl showed that for composites with Si/Mg molar ratios of 0.12 and 0.49 chemical degradation by hydrolysis of Al{sub 4}C{sub 3} was followed by intense anodic dissolution at the matrix-reinforcement interface, while composites corresponding to Si/Mg molar ratios of 0.89 and 1.05 did not exhibit intense localized attack. Possible reasons for the improvement in resistance to localized corrosion are discussed. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  10. 高深宽比金属光栅制备及中红外波段传感特性%Fabrication and application of high aspect ratio metallic gratings for sensing in the mid-infrared region

    Institute of Scientific and Technical Information of China (English)

    郑改革; 陈云云; 徐林华; 赖敏

    2013-01-01

    A method for fabricating high aspect ratio (HAR) metallic gratings using nanoimprint together with sputtering and reactive-ion etching (RIE) was introduced. The reflection spectrum is measured by Fourier transform infrared (FT-IR) spectrometer in the mid-infrared (Mid-IR) region. The reflection peaks will appear just when the p-polarized light incident normally to the grating vector direction, which is very similar to the phenomenon of surface plasmon resonance. This is the so-called spoof surface plasmon resonance (SSPR). Theoretical analysis based on rigorous coupled wave showed that spoof surface plasmon resonance is very sensitive to the change of refractive index in the surface of the metal. Thus this phenomenon has its potential use as a refractive index sensor. In addition, the shift of resonance wavelength with the refractive index of the metal surface is completely linear. The refractive index sensitivity of the Mid-IR SPR sensor are predicted to be 1600 nm per refractive index unit (1600 nm/RIU) and 5000 nm/RIU for the positive and negative order diffractive waves, respectively. The corresponding figure of merits of the whole system is predicted to be 20 RIU -1 and 60 RIU-1, respectively. The list of applicable target materials will certainly expand greatly if mid-IR SPR-based sensors are developed.%利用纳米压印结合溅射和反应离子刻蚀工艺制备了具有高深宽比的金光栅,使用傅里叶变换红外光谱仪测得了反射谱线.测量结果显示,只在p偏振光垂直于光栅矢量方向入射条件下才存在共振反射峰,证明了“伪表面等离子体激元波”的存在.基于严格耦合波分析理论计算了金属光栅的反射率,研究了其作为中红外波段波长调制型表面等离子体共振传感器的可行性.数值计算表明负级次衍射光波对应的共振反射峰的移动能获得较高的波长灵敏度.对于深宽比为10的金光栅结构,+1级次和-3级次衍射光波对应

  11. Mg/Si Mineralogical Ratio of Low-Mass Planet Hosts. Correction for the NLTE Effects

    Science.gov (United States)

    Adibekyan, V.; Gonçalves da Silva, H. M.; Sousa, S. G.; Santos, N. C.; Delgado Mena, E.; Hakobyan, A. A.

    2017-09-01

    Mg/Si and Fe/Si ratios are important parameters that control the composition of rocky planets. In this work we applied non-LTE correction to the Mg and Si abundances of stars with and without planets to confirm/reject our previous findings that [Mg/Si] atmospheric abundance is systematically higher for Super-Earth/Neptune-mass planet hosts than stars without planets. Our results show that the small differences of stellar parameters observed in these two groups of stars are not responsible for the already reported difference in the [Mg/Si] ratio. Thus, the high [Mg/Si] ratio of Neptunian hosts is probably related to the formation efficiency of these planets in such environments.

  12. Theoretically predicted and experimentally determined effects of the Si/(Si + C) gas phase ratio on the growth and character of monocrystalline beta silicon carbide films

    Science.gov (United States)

    Kim, H. J.; Davis, R. F.

    1986-10-01

    The effects of the Si/(Si + C) ratio in the reaction gas stream on the growth and properties of monocrystalline beta-SiC films grown on Si(100) substrates via chemical vapor deposition have been theoretically and experimentally studied. The amounts of condensed phases of beta-SiC and Si, and the partial pressures of the remaining Si and C-containing gases as a function of the Si/(Si + C) ratio in the source gases have been initially obtained from thermodynamic calculations using the 'SOLGASMIX-PV' computer program. Complementary and comparative experimental growth studies have shown that inclusion-free films having maximum values in growth rate and carrier concentration and a minimum value of resistivity were obtained near Si/(Si + C) = 0.5.

  13. 大展弦比机翼非线性颤振剪裁设计新方法%A NEW METHOD ON FLUTTER TAILORING TECHNIQUES OF HIGH-ASPECT-RATIO WINGS

    Institute of Scientific and Technical Information of China (English)

    任智毅; 金海波; 丁运亮

    2014-01-01

    A method was presented to analyze the nonlinear flutter.Based on this method,the flutter character-istics of the high aspect wing were illustrated.The numerical results show that the flutter speed is decreased when the first horizontal bending mode involved.Secondly,this study discussed how the main direction of the compos-ite influenced the character of the nonlinear vibration and flutter,and established the method of the flutter clip-ping to the high aspect wing.And the result shows that the stiffness of structure can be changed by changing the main direction of the composite.It mainly changes the horizontal bending mode,makes the main direction tend to the trailing edge,and then makes the section line move to the leading edge.Further analyzing the nonlinear flut-ter reveals that it is the changing of the horizontal bending mode that causes the flutter speed change obviously. And by the section line of this mode moves ahead,the flutter speed will become larger.In the study,two exam-ples were illustrated to validate its truthiness.%针对大展弦比机翼水平弯曲模态参与耦合颤振问题,首先用考虑几何非线性的颤振分析方法研究了某大展弦比机翼的颤振特性,结果表明水平一弯模态参与耦合降低了机翼传统模式的线性颤振速度;然后研究了复合材料的铺层主刚度方向角对机翼非线性振动特性和颤振特性的影响规律,提出了大展弦比机翼非线性颤振剪裁设计的新方法。结果表明主刚度方向角的变化主要引起了水平一弯模态振型的改变,一般表现为主刚度方向角从机翼后梁向后缘偏转,该阶模态的相对扭转振型节线位置向前缘移动;反之,该节线位置后移。进一步非线性颤振分析,发现水平一弯模态振型的变化引起了该阶模态参与耦合颤振速度的明显改变,主要表现为该颤振型的颤振速度随该阶模态的相对扭转振型节线位置前移量的增加而增

  14. From stellar to planetary composition: Galactic chemical evolution of Mg/Si mineralogical ratio

    CERN Document Server

    Adibekyan, V; Figueira, P; Dorn, C; Sousa, S G; Delgado-Mena, E; Israelian, G; Hakobyan, A A; Mordasini, C

    2015-01-01

    The main goal of this work is to study element ratios that are important for the formation of planets of different masses. We study potential correlations between the existence of planetary companions and the relative elemental abundances of their host stars. We use a large sample of FGK-type dwarf stars for which precise Mg, Si, and Fe abundances have been derived using HARPS high-resolution and high-quality data. A first analysis of the data suggests that low-mass planet host stars show higher [Mg/Si] ratios, while giant planet hosts present [Mg/Si] that is lower than field stars. However, we found that the [Mg/Si] ratio significantly depends on metallicity through Galactic chemical evolution. After removing the Galactic evolution trend only the difference in the [Mg/Si] elemental ratio between low-mass planet hosts and non-hosts was present in a significant way. These results suggests that low-mass planets are more prevalent around stars with high [Mg/Si]. Our results demonstrate the importance of Galactic...

  15. Influence of Si/Al Ratio on Catalytic Performance of (Co)Mo/Saponite Catalysts

    OpenAIRE

    Koningsberger, D.C.; Leliveld, R.G.; Ros, T.G.; van Dillen, A.J.; Geus, John W.

    1999-01-01

    The influence of the Si/Al ratio of the support of (Co)Mo/saponite catalysts on the performance in the hydrodesulfurisation of thiophene and hydrocracking of n-decane has been studied. The initial thiophene HDS activity of the sulfided Co catalysts increased with increasing support acidity, while with the CoMo catalysts the opposite effect was observed. The large drop in activity at lower Si/Al ratios is ascribed to the occurrence of two separate cobalt and molybdenum sulfide phases instead o...

  16. Towards H-infinity Control of an SI Engine's A/F Ratio

    DEFF Research Database (Denmark)

    Vigild, Christian; Struwe, Michael; Andersen, Karsten

    1999-01-01

    Long term stoichiometric Air/Fuel Ratio (AFR) control of an SI engine is at the present mainly maintained by table mapping of the engine's fresh air intake as a function of the engine operating point. In order to reduce a stationary error in the AFR to zero the table based control normally works ...

  17. MEMS acoustic emission transducers designed with high aspect ratio geometry

    Science.gov (United States)

    Saboonchi, H.; Ozevin, D.

    2013-09-01

    In this paper, micro-electro-mechanic systems (MEMS) acoustic emission (AE) transducers are manufactured using an electroplating technique. The transducers use a capacitance change as their transduction principle, and are tuned to the range 50-200 kHz. Through the electroplating technique, a thick metal layer (20 μm nickel + 0.5 μm gold) is used to form a freely moving microstructure layer. The presence of the gold layer reduces the potential corrosion of the nickel layer. A dielectric layer is deposited between the two electrodes, thus preventing the stiction phenomenon. The transducers have a measured quality factor in the range 15-30 at atmospheric pressure and are functional without vacuum packaging. The transducers are characterized using electrical and mechanical tests to identify the capacitance, resonance frequency and damping. Ultrasonic wave generation using a Q-switched laser shows the directivity of the transducer sensitivity. The comparison of the MEMS transducers with similar frequency piezoelectric transducers shows that the MEMS AE transducers have better response characteristics and sensitivity at the resonance frequency and well-defined waveform signatures (rise time and decay time) due to pure resonance behavior in the out-of-plane direction. The transducers are sensitive to a unique wave direction, which can be utilized to increase the accuracy of source localization by selecting the correct wave velocity at the structures.

  18. Downsizing of single crystalline high aspect ratio tungsten nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Milenkovic, Srdjan [IMDEA Materials Institute, Eric Kandel 2, 28906, Getafe (Spain); Drensler, Stefanie [Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University, Altenberger Str. 69, 4040, Linz (Austria); Hassel, Achim Walter [Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University, Altenberger Str. 69, 4040, Linz (Austria); Christian Doppler Laboratory for Combinatorial Oxide Chemistry, Institute for Chemical Technology of Inorganic Materials, Johannes Kepler University Linz, Altenberger Str. 69, 4040, Linz (Austria)

    2015-06-15

    Directional solidification of eutectic NiAl-W alloys offers an intuitive method to produce tungsten nanowires. Through the use of two different methods, the well-established Bridgman method and a newer type floating zone method, the direct influence of process parameters, like the withdrawal rate and the temperature gradient, onto the sample microstructure were studied. The sharp temperature gradient, built up using a four mirror system focusing the light emitted by halogen lamps inside the optical floating zone furnace allows producing nanowires with a diameter as small as 75 nm. Differences in the solid/liquid interface morphology depending on the solidification method used are discussed. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Active Aeroelastic Tailoring of High-Aspect-Ratio Composite Wings

    Science.gov (United States)

    2005-09-01

    34 - 26000 , ......... . . . ...... . . .... .. .......................... ... - - ----------- 21000 ... ........... ~0 50 LOAD... ISO 5: B s mission....f Figure 5: Basic mission profile 7 Figure 6: Baseline single-wing and joined-wing vehicles 3.1 Baseline vehicles Three sets

  20. High aspect ratio template and method for producing same

    Science.gov (United States)

    Sakamoto, Jeff S. (Inventor); Weiss, James R. (Inventor); Fleurial, Jean-Pierre (Inventor); Kisor, Adam (Inventor); Tuszynski, Mark (Inventor); Stokols, Shula (Inventor); Holt, Todd Edward (Inventor); Welker, David James (Inventor); Breckon, Christopher David (Inventor)

    2010-01-01

    Millimeter to nano-scale structures manufactured using a multi-component polymer fiber matrix are disclosed. The use of dissimilar polymers allows the selective dissolution of the polymers at various stages of the manufacturing process. In one application, biocompatible matrixes may be formed with long pore length and small pore size. The manufacturing process begins with a first polymer fiber arranged in a matrix formed by a second polymer fiber. End caps may be attached to provide structural support and the polymer fiber matrix selectively dissolved away leaving only the long polymer fibers. These may be exposed to another product, such as a biocompatible gel to form a biocompatible matrix. The polymer fibers may then be selectively dissolved leaving only a biocompatible gel scaffold with the pores formed by the dissolved polymer fibers.

  1. Metallization of high aspect ratio, out of plane structures

    DEFF Research Database (Denmark)

    Vazquez, Patricia; Dimaki, Maria; Svendsen, Winnie Edith

    2009-01-01

    This work is dedicated to developing a novel three dimensional structure for electrochemical measurements in neuronal studies. The final prototype will allow not only for the study and culture on chip of neuronal cells, but also of brain tissue. The use of out-of-plane electrodes instead of planar......, since the coverage of the side walls of almost vertical pillars is not trivial by standard processes in a clean room facility. This paper will discuss the different steps taken towards this goal and present the results that we have obtained so far....

  2. Synthesis of Zeolite Nanomolecular Sieves of Different Si/Al Ratios

    OpenAIRE

    Pankaj Sharma; Moon Hee Han; Churl-Hee Cho

    2015-01-01

    Nanosized zeolite molecular sieves of different Si/Al ratios have been prepared using microwave hydrothermal reactor (MHR) for their greater application in separation and catalytic science. The as-synthesized molecular sieves belong to four different type zeolite families: MFI (infinite and high silica), FAU (moderate silica), LTA (low silica and high alumina), and AFI (alumina rich and silica-free). The phase purity of molecular sieves has been assessed by X-ray diffraction (XRD) analysis an...

  3. C/O and Mg/Si Ratios of Stars in the Solar Neighborhood

    CERN Document Server

    Brewer, John M

    2016-01-01

    The carbon to oxygen ratio in a protoplanetary disk can have a dramatic influence on the compositions of any terrestrial planets formed. In regions of high C/O, planets form primarily from carbonates and in regions of low C/O, the ratio of magnesium to silicon determines the types of silicates which dominate the compositions. We present C/O and Mg/Si ratios for 849 F, G, and K dwarfs in the solar neighborhood. We find that the frequency of carbon-rich dwarfs in the solar neighborhood is < 0.13% and that 156 known planet hosts in the sample follow a similar distribution as all of the stars as a whole. The cosmic distribution of Mg/Si for these same stars is broader than the C/O distribution and peaks near 1.0 with $\\sim 60$% of systems having $1 \\leq$ Mg/Si $< 2$, leading to rocky planet compositions similar to the Earth. This leaves 40% of systems that can have planets that are silicate rich and may have very different compositions than our own.

  4. Preliminary Study of Polymer Removal in 0.25, 0.3, and 0.5 μm Ruthenium Storage Nodes and 0.11 μm, 10.9:1 High-Aspect-Ratio Trenches by Laser-Induced Etching

    Science.gov (United States)

    Kim, Yong-Gi; Cha, Byung Heon

    2005-07-01

    The demands for new etching technology are increasing because of new materials, such as, ruthenium (Ru), platinum (Pt), and iridium (Ir), that are now being used, and the strict critical dimension (C/D) controls required in today’s ultra large scale integrated (ULSI) circuit technology and dynamic random-access memory (DRAM) fabrication lines. Laser etching technology successfully etched organometallic polymers generated after reactive ion etching and ash processing in 0.25, 0.3, and 0.5 μm Ru storage nodes. In this study, the effects of the incident beam profile on the laser-induced etching of the polymers are investigated. Unevenness of the peak energy in the Gaussian beam profile creates unequal etching and heating effects on the polymer removal depending on the irradiating position of the line beam profile on the sample surface. This article discusses for the first time the preliminary results of laser-induced etching with a KrF laser to remove photoresist (PR) and polymer in 0.11 μm deep contact holes with a high-aspect-ratio 10.9:1 trench hole. How deep can the laser etching technology penetrate and strip the PR at a high aspect ratio (A/R) of 10.9:1 and a 0.11 μm hole size? The penetration depth for the PR removal was approximately 1 μm, which is about a 9.1:1 A/R in a 0.11 μm hole with a 1.2-μm-deep trench. Several promising points are discussed on the basis of laser etching in such a high A/R and small 0.11 μm contact hole. Laser-induced etching technology enabled a very uniform penetration depth without any fluctuations, and it also did not show any attack on the edge of the barrier material TiN.

  5. Preparation and Characterization of Zeolite Beta with Low SiO2/Al2O3 Ratio

    Institute of Scientific and Technical Information of China (English)

    Kang Shanjiao; Gong Yanjun; Dou Tao; Zhang Ying; Zheng Yanying

    2007-01-01

    Zeolite beta with a low SiO2/Al2O3 ratio was synthesized by a novel two-step process. The synthesized sample was characterized with XRD,SEM,FTIR,and N2 adsorption-desorption and solid-state MAS NMR. The results showed that aluminium species were inserted into the framework of zeolite beta. The BET surface area,volume,and particle size of the zeolite beta sample decreased with decreasing SiO2/Al2O3 ratio. Our process was proved an efficient route to synthesize zeolite beta with a low SiO2/Al2O3 ratio.

  6. Proton Adsorption Selectivity of Zeolites in Aqueous Media: Effect of Si/Al Ratio of Zeolites

    Directory of Open Access Journals (Sweden)

    Moses Wazingwa Munthali

    2014-12-01

    Full Text Available In addition to their well-known uses as catalysts, zeolites are utilized to adsorb and remove various cations from aqueous system. The adsorption of the cations is ascribed to the negative charge of zeolites derived from isomorphous substitution of Si by Al. The amount of Na+ adsorption on 4A, X, Y, Na-P1 and mordenite type zeolites were determined in aqueous media, in a two-cation (Na+ and H+ system. Although each zeolite has a constant amount of negative charge, the amount of Na+ adsorption of each zeolite decreased drastically at low pH−pNa values, where pH−pNa is equal to log{(Na+/(H+}. By using the plot of the amount of Na+ adsorption versus pH−pNa, an index of the H+ selectivity, which is similar to the pKa of acids, of each zeolite was estimated, and the index tended to increase with decreasing Si/Al ratio of zeolites. These indicate that zeolites with lower Si/Al and higher negative charge density have higher H+ adsorption selectivity, and in fact, such a zeolite species (4A and X adsorbed considerable amount of H+ even at weakly alkaline pH region. The adsorption of H+ results in the decrease of cation adsorption ability, and may lead to the dissolution of zeolites in aqueous media.

  7. Synthesis of Zeolite Nanomolecular Sieves of Different Si/Al Ratios

    Directory of Open Access Journals (Sweden)

    Pankaj Sharma

    2015-01-01

    Full Text Available Nanosized zeolite molecular sieves of different Si/Al ratios have been prepared using microwave hydrothermal reactor (MHR for their greater application in separation and catalytic science. The as-synthesized molecular sieves belong to four different type zeolite families: MFI (infinite and high silica, FAU (moderate silica, LTA (low silica and high alumina, and AFI (alumina rich and silica-free. The phase purity of molecular sieves has been assessed by X-ray diffraction (XRD analysis and morphological evaluation done by electron microscopy. Broad XRD peaks reveal that each zeolite molecular sieve sample is composed of nanocrystallites. Scanning electron microscopic images feature the notion that the incorporation of aluminum to MFI zeolite synthesis results in morphological change. The crystals of pure silica MFI zeolite (silicalite-1 have hexagon lump/disk-like shape, whereas MFI zeolite particles with Si/Al molar ratios 250 and 100 have distorted hexagonal lump/disk and pseudo spherical shapes, respectively. Furthermore, phase pure zeolite nanocrystals of octahedron (FAU, cubic (LTA, and rod (AFI shape have been synthesized. The average sizes of MFI, FAU, LTA, and AFI zeolite crystals are 250, 150, 50, and 3000 nm, respectively. Although the length of AFI zeolite rods is in micron scale, the thickness and width are of a few nanometers.

  8. Correlation of the Na2SiO3 to NaOH Ratios and Solid to Liquid Ratios to the Kedah’s Soil Strength

    Directory of Open Access Journals (Sweden)

    Nur Hamzah Hazamaah

    2016-01-01

    Full Text Available Geopolymer was used for the soil stabilization of Kedah’s soil at different ratios of solid to liquid and Na2SiO3 to NaOH in order to achieve the desired compressive strength. The geopolymerization process which produces an aluminosilicate gel was occurred due to the mixing of Kedah’s soil and fly ash with Na2SiO3 and NaOH. Soil stabilization by geopolymer was synthesized by the activation of fly ash and Kedah’s soil with Na2SiO3 and NaOH at different ratios of solid to liquid (1.5, 2.0, 2.5 and 3.0 and Na2SiO3 to NaOH (0.5, 1.0, 1.5, 2.0, 2.5 and 3.0 at a specific constant concentration of NaOH solution of 6M. The compressive strength up to 5.12 MPa was obtained at 3.0 of solid to liquid ratio and 2.5 of Na2SiO3 to NaOH ratio in 7 days curing at room temperature.

  9. The influence of Mg/Si ratio on the negative natural aging effect in Al–Mg–Si–Cu alloys

    Energy Technology Data Exchange (ETDEWEB)

    Tao, G.H. [Center for High-Resolution Electron Microscopy, College of Materials Science and Engineering, Hunan University, Changsha, Hunan 410082 (China); Liu, C.H., E-mail: chliu@hnu.edu.cn [Center for High-Resolution Electron Microscopy, College of Materials Science and Engineering, Hunan University, Changsha, Hunan 410082 (China); Chen, J.H. [Center for High-Resolution Electron Microscopy, College of Materials Science and Engineering, Hunan University, Changsha, Hunan 410082 (China); Hunan Province Key Laboratory for Spray Deposition Technology and Application, Hunan University, Changsha, Hunan 410082 (China); Lai, Y.X.; Ma, P.P.; Liu, L.M. [Center for High-Resolution Electron Microscopy, College of Materials Science and Engineering, Hunan University, Changsha, Hunan 410082 (China)

    2015-08-26

    The effects of natural aging (NA) on subsequent artificial aging (AA) at 180 °C in Al–Mg–Si–Cu alloys with varied Mg/Si ratios (0.5, 1 and 2) were systematically studied by Vickers micro-hardness measurements, differential scanning calorimetry and transmission electron microscopy (TEM). The alloy with large Mg/Si ratio possesses a significant negative NA effect on the maximum hardness achieved during AA preceded by an extended NA, while the alloy with small Mg/Si ratio shows a negligible negative NA effect. Though few lath-like Q''/L precipitates exist, needle-like β'' precipitates are the primary hardening precipitates in all the peak-aged alloys. The negative NA effect is demonstrated to be determined by precipitate coarsening, which is manifested microscopically as the broader precipitate length distributions (PLD) and shift of PLD toward larger length range, in AA with the prolonging of NA. Our results suggest the nature of NA clusters is quite different in Al–Mg–Si–Cu alloy varying in Mg/Si ratio. Only a small fraction of NA clusters in alloy with large Mg/Si ratio are stable and could induce preferential growth of precipitates to be considerably coarsened during AA. A large fraction of stable NA clusters in alloy with low Mg/Si ratio lead to synchronous growth of β'' precipitates, thus restricting the preferential growth.

  10. Spectral luminosity indicators in SNe Ia - Understanding the R(SiII) line strength ratio and beyond

    CERN Document Server

    Hachinger, Stephan; Tanaka, Masaomi; Hillebrandt, Wolfgang; Benetti, Stefano

    2008-01-01

    SNe Ia are good distance indicators because the shape of their light curves, which can be measured independently of distance, varies smoothly with luminosity. This suggests that SNe Ia are a single family of events. Similar correlations are observed between luminosity and spectral properties. In particular, the ratio of the strengths of the SiII \\lambda 5972 and \\lambda 6355 lines, known as R(SiII), was suggested as a potential luminosity indicator. Here, the physical reasons for the observed correlation are investigated. A Monte-Carlo code is used to construct a sequence of synthetic spectra resembling those of SNe with different luminosities near B maximum. The influence of abundances and of ionisation and excitation conditions on the synthetic spectral features is investigated. The ratio R(SiII) depends ssentially on the strength of SiII \\lambda 5972, because SiII \\lambda 6355 is saturated. In less luminous objects, SiII \\lambda 5972 is stronger because of a rapidly increasing SiII/SiIII ratio. Thus, the c...

  11. FTIR and electrical characterization of a-Si:H layers deposited by PECVD at different boron ratios

    Energy Technology Data Exchange (ETDEWEB)

    Orduna-Diaz, A., E-mail: abdu@susu.inaoep.mx [Instituto Nacional de Astrofisica, Optica y Electronica, Luis Enrique Erro No. 1, Tonantzintla, Puebla 72840 (Mexico); Trevino-Palacios, C.G. [Instituto Nacional de Astrofisica, Optica y Electronica, Luis Enrique Erro No. 1, Tonantzintla, Puebla 72840 (Mexico); Rojas-Lopez, M.; Delgado-Macuil, R.; Gayou, V.L. [Centro de Investigacion en Biotecnologia Aplicada (CIBA), IPN, Tlaxcala, Tlax. 72197 (Mexico); Torres-Jacome, A. [Instituto Nacional de Astrofisica, Optica y Electronica, Luis Enrique Erro No. 1, Tonantzintla, Puebla 72840 (Mexico)

    2010-10-25

    Hydrogenated amorphous silicon (a-Si:H) has found applications in flat panel displays, photovoltaic solar cell and recently has been employed in boron doped microbolometer array. We have performed electrical and structural characterizations of a-Si:H layers prepared by plasma enhanced chemical vapor deposition (PECVD) method at 540 K on glass substrates at different diborane (B{sub 2}H{sub 6}) flow ratios (500, 250, 150 and 50 sccm). Fourier transform infrared spectroscopy (FTIR) measurements obtained by specular reflectance sampling mode, show Si-Si, B-O, Si-H, and Si-O vibrational modes (611, 1300, 2100 and 1100 cm{sup -1} respectively) with different strengths which are associated to hydrogen and boron content. The current-voltage curves show that at 250 sccm flow of boron the material shows the lowest resistivity, but for the 150 sccm boron flow it is obtained the highest temperature coefficient of resistance (TCR).

  12. The electrochemical effect of various Si/Zr molar ratios on anode materials in lithium-ion batteries.

    Science.gov (United States)

    Choi, DongWoong; Choy, KwangLeong

    2017-10-09

    The aim of this study was to unveil the mechanisms of SiO2/ZrO2 (SSZ) anode materials through electrochemical analysis and to understand the effect of various Si/Zr molar ratios (Si/Zr = 0.5, 1, and 2) on the performance of SSZ anode materials with these mechanisms. The 2-SSZ (Si/Zr = 2) electrode had a much higher capacity than that of the 0.5- or 1-SSZ (Si/Zr = 0.5 or 1) electrode. It exhibited superior cycling performance when compared to commercial graphite (theoretical capacity of 372 mA h g(-1)). The 2-SSZ had a capacity of 461 mA h g(-1) at a high current density of 100 mA g(-1) over 30 cycles. These characteristics are due to the effects from each of the different reversible materials formed by the SSZs. Zr2Si and Zr5Si3, ZrSi, or ZrSi2 were formed by the 0.5-, 1-, and 2-SSZs, respectively, which would affect the reversible storage capacity. ZrSi2 provided an increase in the possible reaction area for the guest species (lithium ions) at the empty interstitial site in the host materials as well as a large area for accommodating a volume change. It was supportive by maintaining the lattice constant and reducing the ratio of the structure distortion. Furthermore, the 2-SSZ structure consisted of an overall amorphous structure with a crystalline structure related to the Zr-O-Si bond unlike the 0.5- and 1-SSZs which had an overall crystalline structure. Such a combined structure of 2-SSZ was advantageous for providing good capacity due to the amorphous structure and an efficient pathway for electron transport and little pulverization due to the crystalline structure. This structure led to its superior performance and long lifespan.

  13. Effect of solid/solution ratio on apatite formation from CaSiO3 ceramics in simulated body fluid.

    Science.gov (United States)

    Iimori, Yusuke; Kameshima, Yoshikazu; Yasumori, Atsuo; Okada, Kiyoshi

    2004-11-01

    The effect of the solid/solution (S/S) ratio on apatite formation from CaSiO3 ceramics in simulated body fluid (SBF) was investigated. CaSiO3 ceramics with a Ca/Si ratio of 0.91 were prepared by sintering CaSiO3 powder coprecipitated from ethanol solutions of Ca(NO3)2. 4H2O and Si(OC2H5)4 using NH4OH as the precipitant. These ceramics were reacted with SBF at S/S ratios of 1.0, 2.5 and 8.3 mg/ml at 36.5 degrees C for various times. Formation of apatite was observed at all the S/S ratios after soaking for 1 day. The amount and microstructure of the apatite obtained at a S/S ratio of 8.3 mg/ml, however, differed largely from the product formed at the other two S/S ratios. The apatite formed at S/S = 8.3 mg/ml was of smaller particle size, formed in smaller amount and with less preferred orientation of the (001) of apatite crystals compared with those formed at S/S = 1.0 and 2.5 mg/ml. An increase of Ca and decrease of the P components occurred in the soaked SBF at S/S = 8.3 mg/ml, the changes being much more marked than with the other two S/S ratios. These differences in the concentration changes in SBF at different S/S ratios are attributed to the difference in the apatite formation from the CaSiO3 ceramics.

  14. Effects of Al and Si addition on the structure and properties of CoFeNi equal atomic ratio alloy

    Energy Technology Data Exchange (ETDEWEB)

    Zuo, T.T., E-mail: zuott1986.520@163.com [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Li, R.B., E-mail: lirb@sdju.edu.cn [School of Mechanical Engineering, Shanghai Dianji University, Shanghai 200245 (China); Ren, X.J., E-mail: X.J.Ren@ljmu.ac.uk [School of Engineering, Liverpool John Moores University, Liverpool 611310 (United Kingdom); Zhang, Y., E-mail: drzhangy@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China)

    2014-12-15

    In this work, a series of Al{sub x}CoFeNi and CoFeNiSi{sub x} high-entropy alloys (HEAs) of different Al and Si molar ratio (x=0, 0.25, 0.5, 0.75 and 1)were designed and, the effects of Al and Si addition on the structure and properties of the materials was investigated by a systematic study on the phase, microstructure, mechanical behavior, electrical and magnetic properties. It was found that the amounts of Al and Si additions strongly influence the phase structures of the alloys; high molar ratio of Al element can change the FCC structure to BCC structure, while more Si addition can lead to new compounds. Both Al and Si addition can increase the yield strength and hardness with the sacrifice of plasticity and, the effect of adding Si on the mechanical properties is more significant than that of adding Al. Characterization of the magnetic properties and hysteresis loops revealed that, all these alloys show typical ferromagnetic behavior. The saturation magnetization decreases from 151.3 emu/g (x=0) to 101.8 emu/g (x=1) when changing the Al content; and decreases from 151.3 emu/g (x=0) to 80.5 emu/g (x=0.75) with changing the Si content. Si addition can decrease the saturation magnetization more significantly than Al addition. The opposite trend can be found in the effects of the alloying element on the electrical resistivity with varying Al or Si content, adding Si can increase the electrical resistivity from 16.7 μΩ cm to 82.89 μΩ cm. It was also found that, the alloys also undergo very small magnetostriction, which is essential to ensure that the materials are not stressed when an external magnetic field is applied (or conversely, that external stresses do not disrupt the magnetic properties). - Highlights: • Multi-component Al{sub x}CoFeNi and CoFeNiSi{sub x} high-entropy alloys are designed. • The Al or Si content strongly influences the phase structure. • Both Al and Si addition can increase the yield strength and reduce the ductility. • The

  15. Synthesis of geopolymer from spent FCC: Effect of SiO2/Al2O<3 and Na2O/SiO2 molar ratios

    Directory of Open Access Journals (Sweden)

    Trochez, J. J.

    2015-03-01

    Full Text Available This paper assesses the feasibility of using a spent fluid catalytic cracking catalyst (SFCC as precursor for the production of geopolymers. The mechanical and structural characterization of alkali-activated SFCC binders formulated with different overall (activator + solid precursor SiO2/Al2O3 and Na2O/SiO2 molar ratios are reported. Formation of an aluminosilicate ‘geopolymer’ gel is observed under all conditions of activation used, along with formation of zeolites. Increased SiO2/Al2O3 induces the formation of geopolymers with reduced mechanical strength, for all the Na2O/SiO2 ratios assessed, which is associated with excess silicate species supplied by the activator. This is least significant at increased alkalinity conditions (higher Na2O/SiO2 ratios, as larger extents of reaction of the spent catalyst are achieved. SiO2/Al2O3 and Na2O/SiO2 ratios of 2.4 and 0.25, respectively, promote the highest compressive strength (67 MPa. This study elucidates the great potential of using SFCC as precursor to produce sustainable ceramic-like materials via alkali-activation.Este artículo estudia la factibilidad de usar un catalizador gastado del proceso de craqueo (SFCC para la producción de geopolímeros. Se evalúan las características mecánicas y estructurales de los geopolímeros producidos con diferentes relaciones molares (activador + precursor solido de SiO2/Al2O3 y Na2O/SiO2. La formación de un gel geopolimérico de tipo aluminosilicato se observa a las diferentes condiciones evaluadas, así como la formación de zeolitas. Un incremento en la relación SiO2/Al2O3 genera geopolímeros de baja resistencia mecánica, a las diferentes relaciones molares Na2O/SiO2 evaluadas, como consecuencia del exceso de especies silicato provenientes del activador. Este efecto es menos significativo al incrementar las condiciones de alcalinidad (mayores relaciones Na2O/SiO2, ya que un mayor grado de reacción del catalizador gastado es alcanzado. Las

  16. Sirolimus inhibits key events of restenosis in vitro/ex vivo: evaluation of the clinical relevance of the data by SI/MPL- and SI/DES-ratio's

    Directory of Open Access Journals (Sweden)

    Kountides Margaratis

    2007-05-01

    Full Text Available Abstract Background Sirolimus (SRL, Rapamycin has been used successfully to inhibit restenosis both in drug eluting stents (DES and after systemic application. The current study reports on the effects of SRL in various human in vitro/ex vivo models and evaluates the theoretical clinical relevance of the data by SI/MPL- and SI/DES-ratio's. Methods Definition of the SI/MPL-ratio: relation between significant inhibitory effects in vitro/ex vivo and the maximal plasma level after systemic administration in vivo (6.4 ng/ml for SRL. Definition of the SI/DES-ratio: relation between significant inhibitory effects in vitro/ex vivo and the drug concentration in DES (7.5 mg/ml in the ISAR drug-eluting stent platform. Part I of the study investigated in cytoflow studies the effect of SRL (0.01–1000 ng/ml on TNF-α induced expression of intercellular adhesion molecule 1 (ICAM-1 in human coronary endothelial cells (HCAEC and human coronary smooth muscle cells (HCMSMC. Part II of the study analysed the effect of SRL (0.01–1000 ng/ml on cell migration of HCMSMC. In part III, IV, and V of the study ex vivo angioplasty (9 bar was carried out in a human organ culture model (HOC-model. SRL (50 ng/ml was added for a period of 21 days, after 21 and 56 days cell proliferation, apoptosis, and neointimal hyperplasia was studied. Results Expression of ICAM-1 was significantly inhibited both in HCAEC (SRL ≥ 0.01 ng/ml and HCMSMC (SRL ≥ 10 ng/ml. SRL in concentrations ≥ 0.1 ng/ml significantly inhibited migration of HCMSMC. Cell proliferation and neointimal hyperplasia was inhibited at day 21 and day 56, significance (p Conclusion SI/MPL-ratio's ≤ 1 (ICAM-1 expression, cell migration characterize inhibitory effects of SRL that can be theoretically expected both after systemic and local high dose administration, a SI/MPL-ratio of 7.81 (cell proliferation represents an effect that was achieved with drug concentrations 7.81-times the MPL. SI/DES-ratio's between 10

  17. Effect of Si/Ge ratio on resistivity and thermopower in Gd{sub 5}Si{sub x}Ge{sub 4-x} magnetocaloric compounds

    Energy Technology Data Exchange (ETDEWEB)

    Raj Kumar, D.M. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500058 (India); Manivel Raja, M., E-mail: mraja@dmrl.drdo.i [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500058 (India); Prabahar, K.; Chandrasekaran, V. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500058 (India); Poddar, Asok; Ranganathan, R. [Saha Institute of Nuclear Physics, Kolkata 700064 (India); Suresh, K.G. [Indian Institute of Technology Bombay, Mumbai 400076 (India)

    2011-07-15

    The effect of Si/Ge ratio on resistivity and thermopower behavior has been investigated in the magnetocaloric ferromagnetic Gd{sub 5}Si{sub x}Ge{sub 4-x} compounds with x=1.7-2.3. Microstructural studies reveal the presence of Gd{sub 5}(Si,Ge){sub 4}-matrix phase (5:4-type) along with traces of secondary phases (5:5 or 5:3-type). The x=1.7 and 2.0 samples display the presence of a first order structural transition from orthorhombic to monoclinic phase followed by a magnetic transition of the monoclinic phase. The alloys with x=2.2 and 2.3 display only magnetic transitions of the orthorhombic phase. A low temperature feature apparent in the AC susceptibility and resistivity data below 100 K reflects an antiferromagnetic transition of secondary phase(s) present in these compounds. The resistivity behavior study correlates with microstructural studies. A large change in thermopower of -8 {mu}V/K was obtained at the magneto-structural transition for the x=2 compound. - Research highlights: Effect of Si/Ge ratio on microstructure, magneto-structural transitions, resistivity ({rho}) and thermopower S(T) behaviour has been investigated in Gd{sub 5}Si{sub x}Ge{sub 4-x} compounds with x=1.7, 2.0, 2.2 and 2.3. Microstructural studies reveal the presence of a Gd{sub 5}(Si,Ge){sub 4} -matrix phase (5:4-type) along with traces of secondary phases (5:5 or 5:3-type). The resistivity behaviour has shown good correlation with the microstructural studies. A large change in thermopower of -8{mu}V/K was obtained at the magneto-structural transition for the x=2 compound. The resistivity and change in thermopower values were high for the alloys with Si/Ge ratio {<=}1 compared to that of the alloys with Si/Ge ratio >1.

  18. Investigation of SiO{sub 2}:Na{sub 2}O ratio as a corrosion inhibitor for metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mohamad, N.; Othman, N. K. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia); Jalar, A. [Institute of Micro Engineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia)

    2013-11-27

    The silicate is one of the potential compounds used as a corrosion inhibitor for metal alloys. The mixture between silica and sodium hydroxide (NaOH) succeeded to produce the silicate product. The formulation of a silicate product normally variable depended by the different ratio of SiO{sub 2}:Na{sub 2}O. This research utilized the agriculture waste product of paddy using its rice husk. In this study, the amorphous silica content in rice husk ash was used after rice husk burnt in a muffle furnace at a certain temperature. The X-ray diffraction (XRD) analysis was done to determine the existence of amorphous phase of silica in the rice husk ash. There are several studies that recognized rice husk as an alternative source that obtained high silica content. The X-ray fluorescence (XRF) analysis was carried out to clarify the percentage amount of Si and O elements, which referred the silica compound in rice husk ash. The preparation of sodium silicate formulation were differ based on the SiO{sub 2}:Na{sub 2}O ratio (SiO{sub 2}:Na{sub 2}O ratio = 1.00, 2.00 and 3.00). These silicate based corrosion inhibitors were tested on several testing samples, which were copper (99.9%), aluminum alloy (AA 6061) and carbon steel (SAE 1045). The purpose of this study is to determine the appropriate SiO{sub 2}:Na{sub 2}O ratio and understand how this SiO{sub 2}:Na{sub 2}O ratio can affect the corrosion rate of each metal alloys immersed in acidic medium. In order to investigate this study, weight loss test was conducted in 0.5 M hydrochloric acid (HCl) for 24 hours at room temperature.

  19. B/Si ratios in cultured and sediment diatoms: proxy of their palaeoenvironment and/or their physiology

    Science.gov (United States)

    Mejia Ramirez, L.; Stoll, H. M.; Isensee, K.; Mendez-Vicente, A.; Shimizu, N.

    2011-12-01

    Diatoms are particularly important in climate modulation, since they account for a large part of the worldwide productivity and ocean CO2 uptake, especially in nutrient-rich areas. Their study provides a long geological record of past productivity, oceanographic conditions and climate. In this work we model and measure B/Si ratios in cultured and fossil diatom opal as a potential proxy of their paleoenvironment and/or physiology. Formation of the diatom frustule by silica polymerization occurs at a very restricted pH range within the silica deposition vesicle (SDV), at an acidic pH of 5, at which boric acid is the predominant species. We infer that B enters the cell as boric acid via passive diffusion across the lipid bilayer. Its abundance in the cell would increase as seawater pH decreases, increasing the fraction of seawater B present as boric acid. Consequently, higher B/Si ratios are expected to be found at decreasing seawater pH, as the amount of transported boric acid increases. Si abundance in the SDV may be transport limited at high growth rates and may decrease at high pCO2. The latter is because CO2 is an important factor controlling Si quotas and ultimately B/Si ratios, since at lower pCO2, carbonic anhydrase activity increases to convert HCO3- into CO2 and this process is buffered by the cell wall. Consequently, higher Si quotas (lower B/Si) should be found at higher pH (low pCO2). An incorporation mechanism for boron in opal is not yet described and for the standard model case we assume B incorporation depends on the total B abundance in the SDV and on incorporated Si. We expect B/Si ratios to increase with decreasing seawater pH due to greater B/Si ratio in the SDV. Diatoms of the species Thalassiosira weissflogii and T. pseudonana were cultured at different light and pH levels. Growth rates as well as carbon system measurements were performed whereas silicon quotas are being measured. After harvesting, frustules were cleaned using oxidation steps in

  20. EFFECT OF SPECIMEN ASPECT RATIO ON FATIGUE LIFE OF CLOSED CELL Al-Si-Ca ALLOY FOAM

    Institute of Scientific and Technical Information of China (English)

    Amkee Kim; Ilhyun Kim

    2008-01-01

    Quasi-static and compressive fatigue tests on the closed cell Al-Si-Ca alloy foam specimens with three different aspect ratios were performed.It turned out that the onset of cyclic shortening of foam with a lower aspect ratio took place earlier and the fatigue strength was lower compared with the specimen with a higher aspect ratio,although aU the dimensions of specimen satisfied the seven times the cell size criterion,while the quasi-static stress-strain curves were almost same having same Young's modulus,yield stress and plateau stress.Therefore,the seven times the cell size criterion for the quasi-static compression behavior was not applicable to the fatigue analysis of Al-Si-Ca alloy foam.

  1. Effect of the Si/Zr molar ratio on the synthesis of Zr-based mesoporous molecular sieves

    Energy Technology Data Exchange (ETDEWEB)

    Salas, P. [Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, Apartado Postal 1-1010, Queretaro 76000 (Mexico)], E-mail: psalas@fata.unam.mx; Wang, J.A. [Escuela Superior de Ingenieria Quimica e Industrias Extractivas, Instituto Politecnico Nacional, Av. Politecnico S/N, Col. Zacatenco, 07738 Mexico D.F. (Mexico); Armendariz, H.; Angeles-Chavez, C. [Instituto Mexicano del Petroleo, Eje Lazaro Cardenas 152, 07730 Mexico D.F. (Mexico); Chen, L.F. [Escuela Superior de Ingenieria Quimica e Industrias Extractivas, Instituto Politecnico Nacional, Av. Politecnico S/N, Col. Zacatenco, 07738 Mexico D.F. (Mexico)

    2009-03-15

    Highly ordered Zr-based mesoporous molecular sieves were synthesized via a surfactant-templated method and the effect of the Si/Zr molar ratio on the crystalline structure, textural properties and surface acidity were studied by XRD, FTIR, TEM and {sup 29}Si MAS-NMR techniques. FTIR spectra show that the intensity of the band around 890 cm{sup -1} which corresponds to the vibration of Si-O-Zr bond was increased with increasing of the zirconium content, therefore, this band may be used as an indicator of the degree of the zirconium incorporation into the Si-framework. When the zirconium content increased in the materials, the Q{sup 3}/Q{sup 4} value obtained from {sup 29}Si MAS-NMR was linearly increased, whereas, the intensity the XRD peaks was gradually reduced; as a result, the pore wall thickness of the resultant materials was gradually increased, the surface area and the structural regularity were diminished. In order to obtain Zr-MCM-41 with highly ordered mesostructure and large surface area, proper Si/Zr molar ratio is a key factor, e.g., Si/Zr should be no less than 10. It was also found that the Bronsted acid sites which resulted from charge unbalance or local structure deformation due to the Zr{sup 4+} incorporation into the vicinity of the hydroxyls carrying silicon were created on the surface of the Zr-MCM-41 solids; strong Bronsted acidity could be formed on the solid with high zirconium content.

  2. Preparation of molecular sieve from natural pyrophyllite and characterization of its Al/Si ratio, crystal structure, and Porosity

    Science.gov (United States)

    Idiawati, Riris; Fuad, Abdulloh; Mufti, Nandang; Hartatiek; Bahtiar, Syamsul; Subakti; Taufiq, Ahmad

    2017-05-01

    Pyrophyllite is one abundant mineral in Indonesia which has not been optimally processed. Hence, this study further processed natural pyrophyllite to be an advanced material usable for industrial sector as a molecular sieve (MS). Natural pyrophyllitewas chosen due to its ability to filter gas or liquid selectively. The MS made from natural pyrophyllite was prepared by using a simple method, in short time and with less cost via leaching process. NaOH was varied to 10 M (MS1), 15 M (MS2), and 20 M (MS3) of molarity. Such solution was subsequently dissolved in distilled water and followed by decantation and filtration processes to obtain the deposit. Eventually, the deposit was drained to form MS powders. The BET characterization showed that the respective surface areas of MS1, MS2, and MS3 are 0.350 m2/g, 2.869 m2/g, and 1.176 m2/g with the pore sizes of 30Å, 542 Å, and 550 Å, respectively. The XRF characterization results showed that the Al/Si ratio of MS10, MS15, and MS20 are 2.4, 2.2, and 2.3, respectively. Meanwhile, the XRD investigation pointed out that the primary phase of MS10 and MS15 samples wassodalite with cubic crystal system, quartz with hexagonal crystal system, and diaspore with orthorhombic crystal system, while the MS20 phase was pure in the form of sodalite phase. Moreover, the results of FITR characterization showed that the synthesized MS has a functional group of Si-O-Si bending, Si-O-Al, Si-O, Si-O normal to the plane stretching, inner surface Al-OH deformation, Si-O-Si siloxine, H-O-H, -OH, C-H stretching, and H-O-H bending water.

  3. Effect of the CO2/SiH4 Ratio in the p-[mu]c-SiO:H Emitter Layer on the Performance of Crystalline Silicon Heterojunction Solar Cells

    National Research Council Canada - National Science Library

    Jaran Sritharathikhun; Taweewat Krajangsang; Apichan Moollakorn; Sorapong Inthisang; Amornrat Limmanee; Aswin Hongsingtong; Nattaphong Boriraksantikul; Tianchai Taratiwat; Nirod Akarapanjavit; Kobsak Sriprapha

    2014-01-01

    .... The reported work focused on the effects of the CO2/SiH4 ratio on the properties of p-μ c-SiO:H films and the effectiveness of the films as an emitter layer of crystalline silicon heterojunction (c-Si-HJ) solar cells. A p-μ c...

  4. Type Ia SNe along redshift: the R(Si II) ratio and the expansion velocities in intermediate z supernovae

    CERN Document Server

    Altavilla, G; Balastegui, A; Méndez, J; Irwin, M; Espana-Bonet, C; Schamaneche, K; Balland, C; Ellis, Richard S; Fabbro, S; Folatelli, G; Goobar, A; Hillebrandt, W; McMahon, R M; Mouchet, M; Mourao, A; Nobili, S; Pain, R; Stanishev, V; Walton, N A

    2006-01-01

    We study intermediate--z SNe Ia using the empirical physical diagrams which enable to learn about those SNe explosions. This information can be very useful to reduce systematic uncertainties of the Hubble diagram of SNe Ia up to high z. The study of the expansion velocities and the measurement of the ratio $\\mathcal{R}$(\\SiII) allow to subtype those SNe Ia as done for nearby samples. The evolution of this ratio as seen in the diagram $\\mathcal{R}$(\\SiII)--(t) together with $\\mathcal{R}$(\\SiII)$_{max}$ versus (B-V)$_{0}$ indicate consistency of the properties at intermediate z compared with local SNe. At intermediate--z, the expansion velocities of Ca II and Si II are similar to the nearby counterparts. This is found in a sample of 6 SNe Ia in the range 0.033$\\leq z \\leq$0.329 discovered within the {\\it International Time Programme} (ITP) of {\\it Cosmology and Physics with SNe Ia} during the spring of 2002. Those supernovae were identified using the 4.2m William Herschel Telescope. Two SNe Ia at intermediate z...

  5. Static synthesis of high-quality MCM-22 zeolite with high SiO2/Al2O3 ratio

    Institute of Scientific and Technical Information of China (English)

    LIU Zhicheng; SHEN Shaodian; TIAN Bozhi; SUN Jinyu; TU Bo; ZHAO Dongyuan

    2004-01-01

    We demonstrate a synthesis method to broaden the range of SiO2/Al2O3 ratio (30-100) of high-silica MCM-22 zeolites by prolonging the aging time of the gel before the crystallization. The synthesis conditions such as silica sources, chemical compositions of initial gel and aging time of gel were investigated in detail. High quality MCM-22products with various morphologies have been synthesized by optimize their synthesis conditions. Our results show that increasing of the aging time can make the gel be homogenization and promote their nucleus formation, which may avoid the formation of impurity phase and thus broaden the range of SiO2/Al2O3 ratio.

  6. Influence of n Si/ n Al ratio of HY zeolite catalysts on alkylation of toluene with tert-butanol

    Science.gov (United States)

    Wang, Yuanyuan; Song, Hua; Sun, Xinglong; Song, HuaLin

    2016-12-01

    The highly selective synthesis of 4- tert-butyltoluene from toluene and tert-butanol over HY zeolites was performed in liquid phase. The effect of Si/Al ratio (6.3, 7.5, 11, 12) of HY zeolites on the alkylation performance was studied. The catalysts were characterized by SEM, XRD, FT-IR, and NH3-TPD methods. With increase of Si/Al ratio, the conversion of toluene and the selectivity towards 4- tert-butyltoluene increased gradually. HY-12 was found to be more suitable for the tert-butylation of toluene. When the alkylation reaction was conducted at 180°C for 4 h using HY-12 catalyst, the conversion and the selectivity of 4- tertbutyltoluene reached 40.74 and 70.91%, respectively.

  7. N:Si:P atomic ratio in the Santa Cruz Channel, Itamaracá-PE (Northeast Brazil: a nyctemeral variation

    Directory of Open Access Journals (Sweden)

    Montes Manuel de Jesús Flores

    2002-01-01

    Full Text Available Studies were carried out on the Inlets of Orange and Catuama at the Santa Cruz Channel, Itamaracá-PE, in the rainy and dry seasons, in a nyctemeral cycle, and in a transversal profile, with intervals of three hours between collections. The objective was to determine the spacial and temporal variation of the N:Si:P atomic ratio, and its possible inter-relations and dependencies, as well as the influence of the hydrodynamism provoked by the variation of the tides at different times of the year. Nitrite-N and nitrate-N were higher in the rainy season, while ammonia-N, phosphate-P and silicate-Si were higher in the dry season, which indicated different results than previous studies. The N:P atomic ratio was lower than 16:1, in all seasons and stations, being highest in the rainy season at Inlet Orange. The Si:P atomic ratio was always high. During the observed nyctemeral cycles, the main factors influencing the composition of the physical, chemical and biological parameters were the tide cycles and the meteorological parameters.

  8. Influence of the Ca/Si ratio of the C–S–H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kunther, Wolfgang [Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry and Interdisciplinary Nanoscience Center (iNANO), Aarhus University, DK-8000 Aarhus C (Denmark); Lothenbach, Barbara [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete/Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Skibsted, Jørgen, E-mail: jskib@chem.au.dk [Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry and Interdisciplinary Nanoscience Center (iNANO), Aarhus University, DK-8000 Aarhus C (Denmark)

    2015-03-15

    The effect of the Ca/Si ratio of the calcium–silicate–hydrate (C–S–H) phase on the interaction with sulfate ions is investigated for C–S–H phases (Ca/Si = 0.83, 1.25, 1.50) and mortar samples of blended Portland cements. It is shown that leaching of calcium from C–S–H and portlandite affects the composition of the pore solution and contributes to the developing crystallization pressure of ettringite. Sulfate profiles show that sulfate binding before cracking is similar for different Ca/Si ratios whereas the highest expansion rates are observed for the mortars with the highest Ca/Si ratios. After leaching in sulfate solutions, the C–S–H samples have been characterized by {sup 29}Si MAS NMR, thermogravimetric analysis, and elemental solution analysis. Generally, the exposure to sulfate solutions results in decalcification of the C–S–H, which increases with decreasing Ca/Si ratio. The data are in good agreement with thermodynamic modeling, indicating that equilibrium is almost achieved in the leached systems. Finally, the expansion of mortar samples exposed to sulfate solutions was much less at lower Ca/Si ratios of the cement blends. This reduced expansion can be related to the decrease of the supersaturation of the pore solution with respect to ettringite at lower Ca/Si ratios of the C–S–H and in the absence of portlandite.

  9. Frequency Ratio of ${}^{199}$Hg and ${}^{87}$Sr Optical Lattice Clocks beyond the SI Limit

    CERN Document Server

    Yamanaka, Kazuhiro; Ushijima, Ichiro; Takamoto, Masao; Katori, Hidetoshi

    2015-01-01

    We report on a frequency ratio measurement of a ${}^{199}$Hg-based optical lattice clock referencing a ${}^{87}$Sr-based clock. Evaluations of lattice light shift, including atomic-motion-dependent shift, enable us to achieve a total systematic uncertainty of $7.2 \\times 10^{-17}$ for the Hg clock. The frequency ratio is measured to be $\

  10. Structural Changes of Y Zeolites with Different Initial SiO2/Al2O3 Ratios during Hydrothermal Treatment

    Institute of Scientific and Technical Information of China (English)

    WangYuchao; ShenBaojian; ZengPenghui

    2005-01-01

    The effects of the initial framework SiO2/Al2O3 ratio and temperature on the structural changes of NaY zeolites during hydrothermal treatments are studied. Two samples with different framework SiO2/Al2O3 ratios are subjected to hydrothermal treatment at four different temperatures. For zeolite with a lower initial SiO2/Al2O3 ratio of 4.2, mesopores are easily formed because more framework aluminum is detached. Moreover, two kinds of mesopores are produced at a higher temperature due to the interconnection of vacancies and smaller mesopores. For zeolite with a higher initial SiO2/Al2O3 ratio of 6.0, there are less mesopores formed as compared with the lower initial SiO2/Al2O3 ratio sample, but there are some macropores formed. This may be attributed to the isolation of vacancies and the different distributions of aluminum in the crystal lattice of the zeolite. The experiment data show that NaY with the SiO2/Al2O3 ratio of 6.0 retains a high relative crystallinity during the hydrothermal treatment. This proves that a high framework SiO2/Al2O3 ratio benefits the stability of zeolite.

  11. Influence of Si/Al ratio on hexane isomers adsorption equilibria

    NARCIS (Netherlands)

    Ferreira, A.F.P.; Mittelmeijer-Hazeleger, M.C.; Bliek, A.; Moulijn, J.A.

    2008-01-01

    In this work we aim to have a better knowledge of the influence of silica/alumina ratio (SAR) on the adsorption equilibrium of hexane isomers on MFI zeolites. With a manometric set-up coupled with a micro-calorimeter we did address adsorption properties and heats of adsorption of n-hexane, 2-methylp

  12. Microcrystalline silicon oxides for silicon-based solar cells: impact of the O/Si ratio on the electronic structure

    Science.gov (United States)

    Bär, M.; Starr, D. E.; Lambertz, A.; Holländer, B.; Alsmeier, J.-H.; Weinhardt, L.; Blum, M.; Gorgoi, M.; Yang, W.; Wilks, R. G.; Heske, C.

    2014-10-01

    using an excitation frequency of 13.56 MHz with a plasma power density of 0.3 W/cm2. Glass (Corning type Eagle) and mono-crystalline silicon wafer substrates were coated in the same run at a substrate temperature of 185°C. The deposition pressure was 4 mbar and the substrate-electrode distance 20 mm. Mixtures of silane (SiH4), 1% TMB (B(CH3)3) diluted in helium, hydrogen (H2), and carbon dioxide (CO2) gases were used at flow rates of 1.25 - 0.18/0.32/500/0 - 1.07) sccm (standard cubic centimeters per minute) for the deposition of μc-SiOx:H(B) layers. By changing the CO2/SiH4 gas flow rate ratio from 0 to 6, μc-SiOx:H(B) layers with a composition of 0 constant sum of SiH4 and CO2. The TMB flow and the H2 flow were kept constant within the series. For more details see Ref. [1]. The oxygen content in the films was determined using Rutherford Backscattering Spectroscopy (RBS). With RBS, the area-related atomic density of oxygen and silicon can be determined (+/- 2% [2]), and thus x can be calculated. This quantity considers only the number of silicon / oxygen atoms and not the number of atoms of other elements, such as hydrogen, which is also incorporated to a considerable extent: up to 20% in μc-SiOx:H (measured using the hydrogen effusion method). To avoid charging effects, the measurements were performed on films deposited on a substrate of mono-crystalline silicon wafers. The electrical conductivity was measured in the planar direction of the film in a vacuum cryostat, using voltages from - 100 V to + 100 V. For that two co-planar Ag contacts were evaporated on the film with a gap of 0.5 mm - 5 mm. In the present study, the optical band E04 is arbitrarily used as a measure for the optical band gap. E04 is defined by the photon energy E for which an optical absorption coefficient of α of 104cm-1 is obtained. The absorption coefficient α(λ) versus the wavelength λ of the films was determined by measuring the transmittance T(λ) and reflectance R(λ), using the

  13. Volcanic SO2 and SiF4 visualization and their ratio monitored using 2-D thermal emission spectroscopy

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2011-09-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a save distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume, animation and determination of its propagation speed. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 which was confirmed from the strong ash emission registered around 01:00 a.m. LST (Local Standard Time) and a pronounced SO2 cloud was registered. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential imagees is used to calculate the emission rates at different distances from the crater.

  14. Relationship between N : P : Si ratio and phytoplankton community composition in a tropical estuarine mangrove ecosystem

    Directory of Open Access Journals (Sweden)

    A. K. Choudhury

    2015-02-01

    Full Text Available The present work aims at understanding the importance of Brzezinski–Redfield ratio (modified Redfield ratio as a determinant of natural phytoplankton community composition in a mangrove ecosystem. Even though this ecoregion has been reported to be mostly eutrophic, localised and anthropogenic influences often result in habitat variability especially with regard to nutrient concentrations at different parts of this ecosystem. Phytoplankton, an important sentinel in aquatic ecosystems may respond differently to such alterations in habitat thereby bringing about significant changes in the community composition. Results show that even though habitat variability does exist at our study area and varied on a spatial and temporal scale, the nutrient concentrations were intricately balanced that never became limited and complemented well with the concept of modified Redfield ratio. However, an integrative approach to study phytoplankton community involving microscopy and rbcL clone library and sequencing approach revealed that it was the functional traits of individual phytoplankton taxa that determined the phytoplankton community composition rather than the nutrient concentrations of the study area. Hence we conclude that the recent concept of functional traits and elemental stoichiometry does not remain restricted to controlled environment of experimental studies only but occur in natural mangrove habitat.

  15. Relationship between N : P : Si ratio and phytoplankton community composition in a tropical estuarine mangrove ecosystem

    Science.gov (United States)

    Choudhury, A. K.; Bhadury, P.

    2015-02-01

    The present work aims at understanding the importance of Brzezinski-Redfield ratio (modified Redfield ratio) as a determinant of natural phytoplankton community composition in a mangrove ecosystem. Even though this ecoregion has been reported to be mostly eutrophic, localised and anthropogenic influences often result in habitat variability especially with regard to nutrient concentrations at different parts of this ecosystem. Phytoplankton, an important sentinel in aquatic ecosystems may respond differently to such alterations in habitat thereby bringing about significant changes in the community composition. Results show that even though habitat variability does exist at our study area and varied on a spatial and temporal scale, the nutrient concentrations were intricately balanced that never became limited and complemented well with the concept of modified Redfield ratio. However, an integrative approach to study phytoplankton community involving microscopy and rbcL clone library and sequencing approach revealed that it was the functional traits of individual phytoplankton taxa that determined the phytoplankton community composition rather than the nutrient concentrations of the study area. Hence we conclude that the recent concept of functional traits and elemental stoichiometry does not remain restricted to controlled environment of experimental studies only but occur in natural mangrove habitat.

  16. Large-scale synthesis of monodisperse SiC nanoparticles with adjustable size, stoichiometric ratio and properties by fluidized bed chemical vapor deposition

    Science.gov (United States)

    Liu, Rongzheng; Liu, Malin; Chang, Jiaxing

    2017-02-01

    A facile fluidized bed chemical vapor deposition method was proposed for the synthesis of monodisperse SiC nanoparticles by using the single precursor of hexamethyldisilane (HMDS). SiC nanoparticles with average particle size from 10 to 200 nm were obtained by controlling the temperature and the gas ratio. An experimental chemical vapor deposition phase diagram of SiC in the HMDS-Ar-H2 system was obtained and three regions of SiC-Si, SiC and SiC-C can be distinguished. The BET surface area and the photoluminescence properties of the SiC nanoparticles can be adjusted by changing the nanoparticle size. For the SiC nanospheres with free carbon, a novel hierarchical structure with 5 8 nm SiC nanoparticles embedded into the graphite matrix was obtained. The advantages of fluidized bed technology for the preparation of SiC nanoparticles were proposed based on the features of homogenous reaction zone, narrow temperature distribution, ultra-short reactant residence time and mass production.

  17. CO2 capture properties of lithium silicates with different ratios of Li2O/SiO2: an ab initio thermodynamic and experimental approach.

    Science.gov (United States)

    Duan, Yuhua; Pfeiffer, Heriberto; Li, Bingyun; Romero-Ibarra, Issis C; Sorescu, Dan C; Luebke, David R; Halley, J Woods

    2013-08-28

    The lithium silicates have attracted scientific interest due to their potential use as high-temperature sorbents for CO2 capture. The electronic properties and thermodynamic stabilities of lithium silicates with different Li2O/SiO2 ratios (Li2O, Li8SiO6, Li4SiO4, Li6Si2O7, Li2SiO3, Li2Si2O5, Li2Si3O7, and α-SiO2) have been investigated by combining first-principles density functional theory with lattice phonon dynamics. All these lithium silicates examined are insulators with band-gaps larger than 4.5 eV. By decreasing the Li2O/SiO2 ratio, the first valence bandwidth of the corresponding lithium silicate increases. Additionally, by decreasing the Li2O/SiO2 ratio, the vibrational frequencies of the corresponding lithium silicates shift to higher frequencies. Based on the calculated energetic information, their CO2 absorption capabilities were extensively analyzed through thermodynamic investigations on these absorption reactions. We found that by increasing the Li2O/SiO2 ratio when going from Li2Si3O7 to Li8SiO6, the corresponding lithium silicates have higher CO2 capture capacity, higher turnover temperatures and heats of reaction, and require higher energy inputs for regeneration. Based on our experimentally measured isotherms of the CO2 chemisorption by lithium silicates, we found that the CO2 capture reactions are two-stage processes: (1) a superficial reaction to form the external shell composed of Li2CO3 and a metal oxide or lithium silicate secondary phase and (2) lithium diffusion from bulk to the surface with a simultaneous diffusion of CO2 into the shell to continue the CO2 chemisorption process. The second stage is the rate determining step for the capture process. By changing the mixing ratio of Li2O and SiO2, we can obtain different lithium silicate solids which exhibit different thermodynamic behaviors. Based on our results, three mixing scenarios are discussed to provide general guidelines for designing new CO2 sorbents to fit practical needs.

  18. Effect of primary materials ratio and their stirring time on SiC Nanoparticle production efficiency through sol gel process

    Directory of Open Access Journals (Sweden)

    Hassan Nosrati

    2016-08-01

    Full Text Available In this article, SiC (silicon carbide Nanopowder was synthesized by sol-gel method. TEOS and sucrose were used as pricier source. Final gel were prepared by mixing in different stirring times and different ratio in pH=4 and drying. This mixture was heated at 650°C and carbothermal reduction was carried out at 1500 °C. XRD analyses showed that produced powder in this condition are only β-Sic. Investigating SEM and TEM images and PS diagrams for different samples one can realize that in TEOS/sucrose=4 and stirring time, 5 hours, maximum efficiency and minimum grain size and minimum agglomeration occurs. Experiment result indicated that nano silicium carbide along with tetraethoxysilane, ethanol, sucrose and water can be used as carbon supply. Average grain size which has been seen by SEM was less than 100 nm.

  19. Effect of RF power and gas flow ratio on the growth and morphology of the PECVD SiC thin films for MEMS applications

    Indian Academy of Sciences (India)

    Bhavana Peri; Bikash Borah; Raj Kishora Dash

    2015-08-01

    Low-temperature plasma enhanced chemical vapour deposition (PECVD) deposited silicon carbide (SiC) thin films are promising materials for the development of high-temperature working microelectromechanical system (MEMS) owing to their excellent mechanical properties, non-corrosive nature and ability to withstand high temperature. However, the surface roughness of such thin films is the main obstacle to achieve thicker thin films for MEMS applications as the surface becomes more rougher with the increase in the thickness of PECVD SiC thin films. Therefore, in this present study, thicker SiC thin films were deposited by PECVD process by using CH4 and SiH4 as the precursor gases in the presence of Ar as the carrier gas and two process parameters, i.e., radio frequency (RF) power with mixed frequency condition and flow ratio of silane to methane were varied by keeping the temperature and pressure constant to investigate the influence of these parameters on the growth rate, surface roughness and morphology of SiC thin films. It was observed that both the RF power (with the mixed frequency condition) and flow ratio of SiH4/CH4 can control the growth rate, surface roughness and morphology of the PECVD SiC thin films. Higher the carbon content in the thin films the surface became more smoother, whereas the surface became for rougher by increasing the RF power.

  20. Effects of CaO/SiO2 Ratio and Na2O Content on Melting Properties and Viscosity of SiO2-CaO-Al2O3-B2O3-Na2O Mold Fluxes

    Science.gov (United States)

    Wang, Lin; Zhang, Chen; Cai, Dexiang; Zhang, Jianqiang; Sasaki, Yasushi; Ostrovski, Oleg

    2016-09-01

    This paper investigated the effects of CaO/SiO2 ratio (0.8 to 1.5) and Na2O concentration (6 to 9 wt pct) on melting properties and viscosity of SiO2-CaO-Al2O3-B2O3-Na2O mold fluxes with a fixed B2O3 content. Melting properties of fluxes (softening temperature T s, hemispherical temperature T h, and fluidity temperature T f) were determined by the hot-stage microscopy method. Viscosity was measured using rotating cylindrical viscometer, and structure of quenched fluxes was studied using Raman spectroscopy. Equilibrium phases in the SiO2-CaO-Al2O3-B2O3-Na2O system were calculated using FactSage. It was found that T h decreased with increasing CaO/SiO2 ratio from 0.8 to 1.0 and increased with a further increase in the CaO/SiO2 ratio to 1.5. The effect of Na2O content in the range of 6 to 9 wt pct on T h of the flux with a fixed CaO/SiO2 ratio at 1.3 was marginal. Increasing CaO/SiO2 ratio and Na2O content increased the break temperature and reduced the value of viscosity at 1673 K (1400 °C). Viscosity of liquid fluxes was discussed in the relationship with the flux structure. Melting properties and viscosity of boracic fluxes were compared with those of industrial fluorine-containing mold fluxes.

  1. The Effect of Si and Al Concentration Ratios on the Removal of U(VI) under Hanford Site 200 Area Conditions-12115

    Energy Technology Data Exchange (ETDEWEB)

    Katsenovich, Yelena; Gonzalez, Nathan; Moreno-Pastor, Carol; Lagos, Leonel [Applied Research Center, Florida International University, 10555 W. Flagler Street, Miami, FL 33174 (United States)

    2012-07-01

    Injection of reactive gases, such as NH{sub 3}, is an innovative technique to mitigate uranium contamination in soil for a vadose zone (VZ) contaminated with radionuclides. A series of experiments were conducted to examine the effect of the concentration ratio of silicon to aluminum in the presence of various bicarbonate concentrations on the coprecipitation process of U(VI). The concentration of Al in all tests remained unchanged at 2.8 mM. Experiments showed that the removal efficiency of uranium was not significantly affected by the different bicarbonate and U(VI) concentrations tested. For the lower Si:Al molar ratios of 2:1 and 18:1, the removal efficiency of uranium was relatively low (≤ 8%). For the Si:Al molar ratio of 35:1, the removal efficiency of uranium was increased to an average of ∼82% for all bicarbonate concentrations tested. At higher Si:Al molar ratios (53:1 and above), a relatively high removal efficiency of U(VI), approximately 85% and higher, was observed. These results demonstrate that the U(VI) removal efficiency is more affected by the Si:Al molar ratio than by the bicarbonate concentration in solution. The results of this experiment are promising for the potential implementation of NH{sub 3} gas injection for the remediation of U(VI) -contaminated VZ. (authors)

  2. Effect of SiO2/Na2O mole ratio on the properties of foam geopolymers fabricated from circulating fluidized bed fly ash

    Science.gov (United States)

    Liu, Ze; Shao, Ning-ning; Huang, Tian-yong; Qin, Jun-feng; Wang, Dong-min; Yang, Yu

    2014-06-01

    Geopolymers are three-dimensional aluminosilicates formed in a short time at low temperature by geopolymerization. In this paper, alkali-activated foam geopolymers were fabricated from circulating fluidized bed fly ash (CFA), and the effect of SiO2/Na2O mole ratio (0.91-1.68) on their properties was studied. Geopolymerization products were characterized by mechanical testing, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). The results show that SiO2/Na2O mole ratio plays an important role in the mechanical and morphological characteristics of geopolymers. Foam samples prepared in 28 d with a SiO2/Na2O mole ratio of 1.42 exhibit the greatest compressive strength of 2.52 MPa. Morphological analysis reveals that these foam geopolymers appear the relatively optimized pore structure and distribution, which are beneficial to the structure stability. Moreover, a combination of the Si/Al atomic ratio ranging between 1.47 and 1.94 with the Na/Al atomic ratio of about 1 produces the samples with high strength.

  3. Effect of SiO2/Na2O mole ratio on the properties of foam geopolymers fabricated from circulating fluidized bed fly ash

    Institute of Scientific and Technical Information of China (English)

    Ze Liu; Ning-ning Shao; Tian-yong Huang; Jun-feng Qin; Dong-min Wang; Yu Yang

    2014-01-01

    Geopolymers are three-dimensional aluminosilicates formed in a short time at low temperature by geopolymerization. In this pa-per, alkali-activated foam geopolymers were fabricated from circulating fluidized bed fly ash (CFA), and the effect of SiO2/Na2O mole ratio (0.91-1.68) on their properties was studied. Geopolymerization products were characterized by mechanical testing, scanning electron mi-croscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). The results show that SiO2/Na2O mole ratio plays an important role in the mechanical and morphological characteristics of geopolymers. Foam samples prepared in 28 d with a SiO2/Na2O mole ratio of 1.42 exhibit the greatest compressive strength of 2.52 MPa. Morphological analysis reveals that these foam geo-polymers appear the relatively optimized pore structure and distribution, which are beneficial to the structure stability. Moreover, a combina-tion of the Si/Al atomic ratio ranging between 1.47 and 1.94 with the Na/Al atomic ratio of about 1 produces the samples with high strength.

  4. Fabrication of Anti-reflecting Si Nano-structures with Low Asp ect Ratio by Nano-sphere Litho-graphy Technique

    Institute of Scientific and Technical Information of China (English)

    Shenghua Sun; Peng Lu; Jun Xu; Ling Xu; Kunji Chen; Qimin Wang; Yuhua Zuo

    2013-01-01

    Nano-structured photon management is currently an interesting topic since it can enhance the optical absorption and reduce the surface reflection which will improve the performance of many kinds of optoelectronic devices, such as Si-based solar cells and light emitting diodes. Here, we report the fabrication of periodically nano-patterned Si structures by using polystyrene nano-sphere lithography technique. By changing the diameter of nano-spheres and the dry etching parameters, such as etching time and etching power, the morphologies of formed Si nano-structures can be well controlled as revealed by atomic force microscopy. A good broadband antireflection property has been achieved for the formed periodically nano-patterned Si structures though they have the low aspect ratio (<0.53). The reflection can be significantly reduced compared with that of flat Si substrate in a wavelength range from 400 nm to 1200 nm. The weighted mean reflection under the AM1.5 solar spectrum irradiation can be as low as 3.92% and the corresponding optical absorption is significantly improved, which indicates that the present Si periodic nano-structures can be used in Si-based thin film solar cells.

  5. The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer.

    Science.gov (United States)

    Zheng, Lei; Wang, Wei; Shi, Yunchun

    2010-04-01

    The present research explored the application of geopolymerization for the immobilization and solidification of municipal solid waste incineration (MSWI) fly ash. The influence of alkaline activator dosage and Si/Al molar ratio on the compressive strength and microstructure of MSWI fly ash-based geopolymer was investigated. A geopolymer with the highest strength was identified to occur at an intermediate alkaline activator dosage and Si/Al ratio, and the optimal Na/MSWI fly ash and Si/Al molar ratio was close to 2.8 mol kg(-1) and 2.0, respectively. IR spectra showed that higher alkaline activator dosage enhanced the structural disruption of the original aluminosilicate phases and a higher degree of polymerization of the geopolymer networks. At low Si/Al ratio, there was an increasing number of tetrahedral Al incorporating into the silicate backbone. As the Na/MSWI fly ash ratio increased, the microstructure changed from containing large macropores to more mesopores and micropores, indicating that more geopolymers are formed. Furthermore, the pore volume distribution of geopolymers was observed to shift to larger pores as the Si/Al ratio increased, which suggests that the soluble silicon content serves to reduce the amount of geopolymers. Heavy metal leaching was successfully elucidated using the first-order reaction/reaction-diffusion model. Combining the results from the microstructure of samples with the kinetic analysis, the immobilization mechanism of Cr, Cu, and Zn was inferred in this study. The methodologies described could provide a powerful set of tools for the systematic evaluation of element release from geopolymers.

  6. Effect of Na2O/SiO2 mole ratio on the crystal type of zeolite synthesized from coal fly ash

    Directory of Open Access Journals (Sweden)

    PREDRAG LAZIC

    2003-06-01

    Full Text Available Coal fly ash was modified to zeolitic materials by hydrothermal treatment at 90ºC. The zeolite synthesis was studied as a function of the mole ratio of Na2O/SiO2 in the reaction mixtures. The results showed that NaP1 zeolite is obtained when the Na2O/SiO2 mole ratio was 0.7. Hydroxysodalite is the dominant zeolite phase in modified fly ash treated with a higher Na2O concentration solution (Na2O/SiO2 = 1.3. The IR and XRD methods were used to determine the phases present in the starting sample and in the zeolitic materials.

  7. Effect of KOH to Na2SiO3 Ratio on Microstructure and Hardness of Plasma Electrolytic Oxidation Coatings on AA 6061 Alloy

    Science.gov (United States)

    Sharma, Ashutosh; Jang, Yong-Joo; Jung, Jae Pil

    2017-09-01

    In this study, plasma electrolytic oxidation (PEO) process has been employed to fabricate alumina coatings on AA 6061 aluminum alloy from an electrolyte containing water glass (Na2SiO3) and alkali (KOH). The effect of deposition time and the alkali to water glass (KOH: Na2SiO3) composition ratio on the coating morphology and properties are studied. The different phases of the oxide layer and microstructure are investigated by x-ray diffraction, scanning electron microscopy, and atomic force microscopy. The results indicate that initially γ-Al2O3 forms in the coating, and as the processing time is increased from 5 to 60 minutes, α-Al2O3 phase becomes prominent. Further, higher the content of Na2SiO3, higher is the hardness and coating growth rate due to the formation of stable α-Al2O3 and Al-Si-O phase. It has been reported that the optimum properties of the PEO coatings can be obtained at a ratio of KOH: Na2SiO3 ≈ 15:10 followed by 10:10.

  8. The sulfur partition ratio with Fe-CSAT melts and the sulfide capacity of CaO-SiO2-Na2O- (Ai2O3) slags

    Science.gov (United States)

    Chan, A. H.; Fruehan, R. J.

    1989-02-01

    The sulfur partition ratio between slag and carbon saturated iron and the sulfide capacity of CaO-Na2O-SiO2 slags and a 48 pet CaO-45 pet Al2O3-7 pet SiO2-(Na2O) slag have been mea-sured at 1400 °C. The addition of Na2O to a CaO-SiO2 slag increases the sulfur partition ratio and the sulfide capacity; however, Na2O at low concentrations has no measurable effect on the sulfide capacity of a CaO-Al2O3-SiO2 slag. To convert the sulfur partition ratio to the sulfide capacity, the oxygen potential was calculated assuming equilibrium between iron in the alloy and FeO in the slag with the activity of FeO calculated via a regular solution model. The optical basicity may be used to correlate the data, but at high Na2O contents the data do not adhere to the correlation previously developed for CaO-based slags.

  9. Effect of C/Si Ratio on the Electrochemical Behavior of a-SiCx:H Coatings on SS301 Substrate Deposited by PECVD

    Directory of Open Access Journals (Sweden)

    D. Li

    2014-01-01

    Full Text Available Amorphous hydrogenated silicon carbide (a-SiCx:H coatings were deposited on stainless steel 301 (SS301 using plasma enhanced chemical vapor deposition with the methane gas flow ranging from 30 to 90 sccm. XRD spectra confirmed the amorphous structure of these coatings. The as-deposited coatings all exhibited homogenous dense feature, and no porosities were observed in SEM and AFM analysis. The a-SiCx:H coatings remarkably increased the corrosion resistance of the SS301 substrate. With the increase of the C concentration, the a-SiCx:H coatings exhibited significantly enhanced electrochemical behavior. The a-SiCx:H coating with the highest carbon concentration acted as an excellent barrier to charge transfer, with a corrosion current of 3.5×10-12 A/cm2 and a breakdown voltage of 1.36 V, compared to 2.5×10-8 A/cm2 and 0.34 V for the SS301 substrate.

  10. An Automated High Aspect Ratio Mesher for Computational Fluid Dynamics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The work will focus on the 3D implementation of the Phase 1 CHARM mesher, with solution-adaptive iteration for CFD and non-CFD applications. The proposed 3D method...

  11. The flow over a 'high' aspect ratio gothic wing at supersonic speeds

    Science.gov (United States)

    Narayan, K. Y.

    1975-01-01

    Results are presented of an experimental investigation on a nonconical wing which supports an attached shock wave over a region of the leading edge near the vertex and a detached shock elsewhere. The shock detachment point is determined from planform schlieren photographs of the flow field and discrepancies are shown to exist between this and the one calculated by applying the oblique shock equations normal to the leading edge. On a physical basis, it is argued that the shock detachment has to obey the two-dimensional law normal to the leading edges. From this, and from other measurements on conical wings, it is thought that the planform schlieren technique may not be particularly satisfactory for detecting shock detachment. Surface pressure distributions are presented and are explained in terms of the flow over related delta wings which are identified as a vertex delta wing and a local delta wing.

  12. Visualization of cavitating and flashing flows within a high aspect ratio injector

    Science.gov (United States)

    Thompson, Andrew S.

    Thermal management issues necessitate the use of fuel as a heat sink for gas turbine and liquid rocket engines. There are certain benefits to using heated fuels, namely, increased sensible enthalpy, increased combustion efficiency, a decrease in certain emissions, and enhanced vaporization characteristics. However, the thermal and pressure enviornment inside an injector can result in the fuel flashing to vapor. Depending on the injector design, this can have deleterious effects on engine performance. As interest in heated fuels inreases, it is important to understand what occurs in the flow path of an injector under flashing conditions. At the High Pressure Laboratory at Purdue University's Maurice J. Zucrow Laboritories, a test rig was designed and built to give visual access into the flow path of a 2-D slot injector. The rig is capable of pressurizing and heating a liquid to superheated conditions and utilizes a pneumatically actuated piston to pusth the liquid through the slot injector. Methanol was chosen as a surrogate fuel to allow for high levels of superheat at relatively low temperatures. Testing was completed with acrylic and quartz injectors of varying L/DH. Flashing conditions inside the injector flow path were induced via a combination of heating and back pressure adjustments. Volume flow rate, pressure measurements, and temperature measurements were made which allowed the discharge characteristics, the level of superheat, and other parameters to be calculated and compared. To give a basis for comparison the flashing results are compared to the flow through the injector under cavitating conditions. Cavitation and flashing appear to be related phenomena and this relationship is shown. Bubble formation under cavitating or flashing conditions is observed to attenuate the injector's discharge characteristics. High speed videos of the flow field were also collected. Several flow regimes and flow structures, unique to these regimes, were observed. A frequency analysis was also performed on the video files. Bubble formation in the flow field dominates the frequency spectrum, which is confined below 1 kHz. The test campaign was successful. The result is a possible way to predict an injector's performance under flashing conditions without running heated fuel through the injector. These results may be applicable to real world injector design and testing.

  13. High-aspect-ratio silicon-cell metallization technical status report. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    Two features of the silicon concentrator solar cell are addressed which affect output at high concentration levels. The first is the development of narrow but high electroplated grid lines with improved conductivity. The object is a reduction in cell series resistance without increase in shadowing. This goal is accomplished by electroplating through a thick photo resist mask to produce lines .7 mil wide by .7 mil high. Advance pulse plating techniques are combined with pure silver plating baths to produce a deposit conductivity equal to the bulk silver conductivity (a 1.5 to 2 X improvement over conventional silver plating). The second feature is a double diffused selectively textured front surface. This development employs a deep diffusion in the silicon under the grid lines. Only the non grid line open area is selectively texture etched removing the deep junction. This open textured area is then given a second shallow diffusion for optimum cell efficiency. This selective procedure maintains the original highly polished wafer surface under the grid lines so that high resolution narrow grid lines are possible. The double diffusion protects the junction from metal diffusion while enabling the optimum shallow junction in the illuminated regions. Combining these two features has produced a large area concentrator cells (8 cm/sup 2/) with peak efficiency above 16% and exhibiting a broad peak efficiency extending from 50 to 175 suns above 15%.

  14. Light extinction and scattering from individual and arrayed high-aspect-ratio trenches in metal

    DEFF Research Database (Denmark)

    Roberts, Alexander; Søndergaard, Thomas; Chirumamilla, Manohar

    2016-01-01

    for a two-dimensional scatterer. We construct a simple resonator model which predicts the wavelength-dependent extinction, scattering, and absorption cross section of the trench and compare the model findings with full numerical simulations. Both extinction and scattering cross sections are mainly...... determined by the wavelength and can reach highly supergeometric values. At wavelengths where the metal exhibits near perfect electrical conductor behavior, such trenches lend themselves to be used as self-normalizing scatterers, as their scattering cross section is independent of their geometry and depend...... and two-photon luminescence that the resonant behavior of the vertical trenches is preserved....

  15. Nucleation of melting and solidification in confined high aspect ratio thin films

    Science.gov (United States)

    Mastandrea, J. P.; Ager, J. W.; Chrzan, D. C.

    2017-09-01

    Classical nucleation theory is used to consider the solidification of a melt confined between two planar surfaces. The critical nucleus shapes and the associated nucleation energy barriers are computed as a function of the thickness of the film and the film's relevant bulk and interface energies. The analysis is then repeated for the melting transition, and expressions for the depression and elevation of the melting temperature, relative to the thermodynamic bulk melting temperature of the film material, are found. A nucleus morphology diagram is constructed. This diagram presents the lowest energy morphology of the nuclei, as well as melting points, as a function of the system parameters. Using the nucleus morphology diagram, experimental and system parameters that allow for the desired nucleation behavior can be identified. Furthermore, the nucleus morphology diagram illustrates a region of parameter space where the film is predicted to solidify above its thermodynamic bulk melting temperature, a behavior termed presolidification. The theory is used to predict the temperature at which the nucleation of the solid phase and liquid phase is expected for Ge between two glass substrates. Furthermore, a possible route for controlling the orientation of the film is identified. By controlling the growth temperature, certain orientations may not be able to nucleate, thereby reducing the possible number of orientations within a film.

  16. Lecithin blended polyamide-6 high aspect ratio nanofiber scaffolds via electrospinning for human osteoblast cell culture

    Energy Technology Data Exchange (ETDEWEB)

    Nirmala, R. [Bio-nano System Engineering, College of Engineering, Chonbuk National University, Jeonju, 561 756 (Korea, Republic of); Park, Hye-Min [Department of Pharmacology and Toxicology, College of Veterinary Medicine, Chonbuk National University, Jeonju 561 756 (Korea, Republic of); Navamathavan, R. [School of Advanced Materials Engineering, Chonbuk National University, Jeonju 561 756 (Korea, Republic of); Kang, Hyung-Sub [Department of Pharmacology and Toxicology, College of Veterinary Medicine, Chonbuk National University, Jeonju 561 756 (Korea, Republic of); El-Newehy, Mohamed H. [Petrochemical Research Chair, Department of Chemistry, College of Science, King Saud University, Riyadh 11451 (Saudi Arabia); Kim, Hak Yong, E-mail: khy@jbnu.ac.kr [Petrochemical Research Chair, Department of Chemistry, College of Science, King Saud University, Riyadh 11451 (Saudi Arabia); Center for Healthcare Technology and Development, Chonbuk National University, Jeonju, 561 756 (Korea, Republic of)

    2011-03-12

    In this study, we focused on the preparation and characterization of lecithin blended polyamide-6 nanofibers via an electrospinning process for human osteoblastic (HOB) cell culture applications. The morphological, structural characterizations and thermal properties of polyamide-6/lecithin nanofibers were determined by using scanning electron microscopy (SEM), field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC) and thermogravimetry (TGA). SEM images revealed that the nanofibers were well-oriented with good incorporation of lecithin. FT-IR results indicated the presence of amino groups of lecithin in the blended nanofibers. TGA analysis revealed that the onset degradation temperature decreased with increasing lecithin content in the blended nanofibers. The morphological features of cells attached on polyamide-6/lecithin nanofibers were confirmed by SEM. The adhesion, viability and proliferation properties of osteoblast cells on the polyamide-6/lecithin blended nanofibers were analyzed by in vitro cell compatibility test. This study demonstrated the non-cytotoxic behavior of electrospun polyamide-6/lecithin nanofibers for the osteoblast cell culture.

  17. High aspect-ratio MEMS devices for the next generation of THz/MHz passive components

    NARCIS (Netherlands)

    Fiorentino, G.

    2015-01-01

    The realization of efficient passive devices directly on chip represents one of the most intriguing challenges in IC fabrication processes. The performance of such devices are intrinsically determined by physical parameters that cannot be easily scaled, making the on-chip integration of such compone

  18. Ordered and Ultra-High Aspect Ratio Nanocapillary Arrays as a Model System

    Science.gov (United States)

    2015-10-13

    nanocapillaries can be used to synthesize molecularly confined or form quantum confined nanostructures. We have shown these effects benefit to improve...10 3 10-2 10 1 100 101 102 103 104 Page 5 Copyright © 2015 Mainstream Engineering Corporation Thermodynamic • Joule Heating • Uneven...Complex thermal/electrochemical dependence  Rate-inhibiting concentration gradient established  Small environmental gradients effect long-term

  19. Low-energy electron transmission through high aspect ratio Al O nanocapillaries

    DEFF Research Database (Denmark)

    Milosavljević, A.R.; Jureta, J.; Víkor, G.;

    2009-01-01

    Electron transmission through insulating AlO nanocapillaries of different diameters (40 and 270 nm) and 15 μm length has been investigated for low-energy electrons (2-120 V). The total intensity of transmitted current weakly depends on the incident electron energy and tilt angle defined with resp......Electron transmission through insulating AlO nanocapillaries of different diameters (40 and 270 nm) and 15 μm length has been investigated for low-energy electrons (2-120 V). The total intensity of transmitted current weakly depends on the incident electron energy and tilt angle defined...

  20. Injection molding micro patterns with high aspect ratio using a polymeric flexible stamper

    Directory of Open Access Journals (Sweden)

    2011-11-01

    Full Text Available Poor filling occurs during the injection molding process of micro- or nano- scale patterns mainly because the hot polymer melt rapidly cools and its skin quickly solidifies upon contact with the mold surface. In this study, it is proposed to use Polyethylene terephthalate (PET film coated with patterned polyurethane acrylate (PUA as an effective thermal barrier. It can significantly hinder heat transfer into the mold during the molding process and thus may keep the melt viscosity low for longer duration. As a result, the replication would be improved not only during the filling phase but also during the packing phase. In order to verify the validity of the use of polymeric stamper, the melt-film interface temperature was evaluated by numerical simulation. Experimental results indicated that patterns possessing widths within the range of one to tens of micrometers and a height of approximately 10 µm were successfully filled and demolded.

  1. Deep proton writing of high aspect ratio SU-8 micro-pillars on glass

    Science.gov (United States)

    Ebraert, Evert; Rwamucyo, Ben; Thienpont, Hugo; Van Erps, Jürgen

    2016-12-01

    Deep proton writing (DPW) is a fabrication technology developed for the rapid prototyping of polymer micro-structures. We use SU-8, a negative resist, spincoated in a layer up to 720 μm-thick in a single step on borosilicate glass, for irradiation with a collimated 12 MeV energy proton beam. Micro-pillars with a slightly conical profile are irradiated in the SU-8 layer. We determine the optimal proton fluence to be 1.02 × 104 μm-2, with which we are able to repeatably achieve micro-pillars with a top-diameter of 138 ± 1 μm and a bottom-diameter of 151 ± 3 μm. The smallest fabricated pillars have a top-diameter of 57 ± 5 μm. We achieved a root-mean-square sidewall surface roughness between 19 nm and 35 nm for the fabricated micro-pillars, measured over an area of 5 × 63.7 μm. We briefly discuss initial testing of two potential applications of the fabricated micro-pillars. Using ∼100 μm-diameter pillars as waveguides for gigascale integration optical interconnect applications, has shown a 4.7 dB improvement in optical multimode fiber-to-fiber coupling as compared to the case where an air-gap is present between the fibers at the telecom wavelength of 1550 nm. The ∼140 μm-diameter pillars were used for mold fabrication with silicone casting. The resulting mold can be used for hydrogel casting, to obtain hydrogel replicas mimicking human tissue for in vitro bio-chemical applications.

  2. An atmospheric-pressure, high-aspect-ratio, cold micro-plasma.

    Science.gov (United States)

    Lu, X; Wu, S; Gou, J; Pan, Y

    2014-01-01

    An atmospheric pressure nonequilibrium Ar micro-plasma generated inside a micro-tube with plasma radius of 3 μm and length of 2.7 cm is reported. The electron density of the plasma plume estimated from the broadening of the Ar emission line reaches as high as 3 × 10(16) cm(-3). The electron temperature obtained from CR model is 1.5 ev while the gas temperature of the plasma estimated from the N2 rotational spectrum is close to room temperature. The sheath thickness of the plasma could be close to the radius of the plasma. The ignition voltages of the plasma increase one order when the radius of the dielectric tube is decreased from 1 mm to 3 μm.

  3. High Aspect Ratio Microstructures in Flexible Printed Circuit Boards : Process and Applications

    OpenAIRE

    Yousef, Hanna

    2008-01-01

    Flexible printed circuit boards (flex PCBs) are used in a wide range of electronic devices today due to their light weight, bendability, extensive wiring possibilities, and low-cost manufacturing techniques. The general trend in the flex PCB industry is further miniaturization alongside increasing functionality per device and reduced costs. To meet these demands, a new generation of low cost manufacturing technologies is being developed to enable structures with smaller lateral dimensions and...

  4. High-Aspect-Ratio CMOS add-on modules for RF passive components

    NARCIS (Netherlands)

    Sagkol, H.

    2011-01-01

    Commercial wireless communication technologies stemmed mostly from the research done through and after the Second World War as outlined in Chapter 1. Earlier systems were intended for military applications, hence had very high performance and were very expensive and bulky. Later, with the dawn of co

  5. Deep proton writing of high aspect ratio SU-8 micro-pillars on glass

    Energy Technology Data Exchange (ETDEWEB)

    Ebraert, Evert, E-mail: eebraert@b-phot.org; Rwamucyo, Ben; Thienpont, Hugo; Van Erps, Jürgen

    2016-12-15

    Deep proton writing (DPW) is a fabrication technology developed for the rapid prototyping of polymer micro-structures. We use SU-8, a negative resist, spincoated in a layer up to 720 μm-thick in a single step on borosilicate glass, for irradiation with a collimated 12 MeV energy proton beam. Micro-pillars with a slightly conical profile are irradiated in the SU-8 layer. We determine the optimal proton fluence to be 1.02 × 10{sup 4} μm{sup −2}, with which we are able to repeatably achieve micro-pillars with a top-diameter of 138 ± 1 μm and a bottom-diameter of 151 ± 3 μm. The smallest fabricated pillars have a top-diameter of 57 ± 5 μm. We achieved a root-mean-square sidewall surface roughness between 19 nm and 35 nm for the fabricated micro-pillars, measured over an area of 5 × 63.7 μm. We briefly discuss initial testing of two potential applications of the fabricated micro-pillars. Using ∼100 μm-diameter pillars as waveguides for gigascale integration optical interconnect applications, has shown a 4.7 dB improvement in optical multimode fiber-to-fiber coupling as compared to the case where an air–gap is present between the fibers at the telecom wavelength of 1550 nm. The ∼140 μm-diameter pillars were used for mold fabrication with silicone casting. The resulting mold can be used for hydrogel casting, to obtain hydrogel replicas mimicking human tissue for in vitro bio-chemical applications.

  6. Ablative implosion of high-aspect-ratio gas-filled targets

    Energy Technology Data Exchange (ETDEWEB)

    Tomasel, F.G.; Cortazar, O.D. (Universidad Nacional de Mar del Plata (Argentina). Dept. de Fisica); Piriz, A.R. (Buenos Aires Univ. (Argentina). Dept. de Fisica)

    1991-11-01

    A simple analytical mode for the implosion of very thin spherical shell targets filled with fuel gas is developed. The shock trajectory in the fuel is described consistently with the shell acceleration, and two dimensionless parameters which govern the complete dynamics are found. The model applies to recent experiments focused on high neutron yield and provides a simple description of the main physical phenomena, which is in agreement with simulation and experiments. (author).

  7. Mechanical Design of High Lift Systems for High Aspect Ratio Swept Wings

    Science.gov (United States)

    Rudolph, Peter K. C.

    1998-01-01

    The NASA Ames Research Center is working to develop a methodology for the optimization and design of the high lift system for future subsonic airliners with the involvement of two partners. Aerodynamic analysis methods for two dimensional and three dimensional wing performance with flaps and slats deployed are being developed through a grant with the aeronautical department of the University of California Davis, and a flap and slat mechanism design procedure is being developed through a contract with PKCR, Inc., of Seattle, WA. This report documents the work that has been completed in the contract with PKCR on mechanism design. Flap mechanism designs have been completed for seven (7) different mechanisms with a total of twelve (12) different layouts all for a common single slotted flap configuration. The seven mechanisms are as follows: Simple Hinge, Upside Down/Upright Four Bar Linkage (two layouts), Upside Down Four Bar Linkages (three versions), Airbus A330/340 Link/Track Mechanism, Airbus A320 Link/Track Mechanism (two layouts), Boeing Link/Track Mechanism (two layouts), and Boeing 767 Hinged Beam Four Bar Linkage. In addition, a single layout has been made to investigate the growth potential from a single slotted flap to a vane/main double slotted flap using the Boeing Link/Track Mechanism. All layouts show Fowler motion and gap progression of the flap from stowed to a fully deployed position, and evaluations based on spanwise continuity, fairing size and number, complexity, reliability and maintainability and weight as well as Fowler motion and gap progression are presented. For slat design, the options have been limited to mechanisms for a shallow leading edge slat. Three (3) different layouts are presented for maximum slat angles of 20 deg, 15 deg and 1O deg all mechanized with a rack and pinion drive similar to that on the Boeing 757 airplane. Based on the work of Ljungstroem in Sweden, this type of slat design appears to shift the lift curve so that higher lift is achieved with the deployed slat with no increase in angle of attack. The layouts demonstrate that these slat systems can be designed with no need for slave links, and an experimental test program is outlined to experimentally validate the lift characteristics of the shallow slat.

  8. Finite element analysis of surface acoustic waves in high aspect ratio electrodes

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Laude, Vincent; Khelif, Abdelkrim

    2008-01-01

    down the SAWvelocity because of mechanical energy storage. A finite model is furthermore employed to study the acousto-optical interaction and shows that it is possible to get a bigger change in effective refractive index with these surface acoustic waves compared to using conventional interdigital...

  9. High aspect-ratio MEMS devices for the next generation of THz/MHz passive components

    NARCIS (Netherlands)

    Fiorentino, G.

    2015-01-01

    The realization of efficient passive devices directly on chip represents one of the most intriguing challenges in IC fabrication processes. The performance of such devices are intrinsically determined by physical parameters that cannot be easily scaled, making the on-chip integration of such

  10. An Automated High Aspect Ratio Mesher for Computational Fluid Dynamics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Computational fluid dynamics (CFD) simulations are routinely used while designing, analyzing, and optimizing air- and spacecraft. An important component of CFD...

  11. Interaction between photoresist pretreatment and high-aspect-ratio contact and via hole definition

    Science.gov (United States)

    Brown, Kevin C.; Insalaco, Linda J.; Szeto, Elina C.

    1993-09-01

    The relationship between photoresist treatment prior to etch and subsequent oxide sidewall hole profile is investigated. Etched features were examined immediately after resist pattern definition with post-expose bake, then after oven hard bake or deep UV photostabilization. It was observed that taper of the etched oxide profile depends on pre-treatment temperature. Etch chemistry influences the relative change in taper across a range of pre-treatment temperatures. `Bowing,' as well as reticulated or `burnt' resist is eliminated. Profile variation across the wafer is reduced with deep UV photostabilization. Microscopic etch uniformity (RIE lag) also depends on the interaction between resist pre-treatment and oxide etch chemistry.

  12. High precision and high aspect ratio laser drilling: challenges and solutions

    Science.gov (United States)

    Uchtmann, Hermann; He, Chao; Gillner, Arnold

    2016-03-01

    Laser drilling is a very versatile tool to produce high accuracy bores in small and large geometries using different technologies. In large and deep hole drilling laser drilling can be found in drilling cooling holes into turbomachinery components such as turbine blades. In micro drilling, the technology is used for the generation of nozzles and filters. However, especially in macro drilling, the process often causes microstructure changes and induces defects such as recast layers and cracks. The defects are caused by the melt dominated drilling process by using pulse durations in the range of some 100 μm up to a few ms. A solution of this problem is the use of ultrashort pulsed laser radiation with pulse durations in the range of some 100 fs up to a few ps, however with the disadvantage of long drilling times. Thus, the aim of this work is to combine the productive process by using ms pulsed fiber laser radiation with subsequent ablation of existing recast layers at the hole wall by using ultrashort pulsed laser radiation. By using fast scanning techniques the recast layer can be avoided almost completely. With a similar technology also very small hole can be produced. Using a rotating dove prism a circular oscillation of the laser spots is performed and holes are drilled at intervals in 1 mm thick stainless steel (1.4301) by ultra-short laser pulses of 7 ps at 515 nm. The formation of hole and the behavior of energy deposition differ from other drilling strategies due to the helical revolution. The temporal evolution of the hole shape is analyzed by means of SEM techniques from which three drilling phases can be distinguished.

  13. CaO/SiO2和Fe/SiO2比对空气中PbO-ZnO-CaO-SiO2-“Fe2O3”系相平衡的影响%Effect of CaO/SiO2 and Fe/SiO2 ratios on phase equilibria in PbO-ZnO-CaO-SiO2-"Fe2O3" system in air

    Institute of Scientific and Technical Information of China (English)

    M.PEREZ-LABRA; A.ROMERO-SERRANO; A.HERNANDEZ-RAMIREZ; I.ALMAGUER-GUZMAN; R.BENAVIDES-PEREZ

    2012-01-01

    Experimental studies on phase equilibria and liquidus temperature in the PbO-ZnO-CaO-SiO2-"Fe2O3" system,with the mass ratios of CaO/SiO2=1-1.6 and Fe/SiO2=1.3-1.7,and 40% PbO and 8% ZnO,were carried out between 1273 and 1573 K.Slags were equilibrated at 1273 to 1573 K and cooled rapidly by quenching.The XRD and SEM-EDS results showed that the slag compositions are in the franklinite primary phase field.Calcium and lead silicates are formed between 1373 and 1473 K.The Ca/Pb silicate and magnetoplumbite phases are partially formed by an incongruent reaction.The experimental and thermodynamical results showed that the liquidus increased by increasing CaO/SiO2 mass ratio and decreasing Fe/SiO2 mass ratio.%实验测定了CaO/SiO2和Fe/SiO2质量比分别为1~1.6和1.3~1.7、含40% PbO和8%ZnO的PbO-ZnO-CaO-SiO2-"Fe2O3”渣系的相平衡和液相线温度.将该渣系在1273~1573 K达到平衡,然后快速淬火冷却.XRD和SEM-EDS分析结果表明,该渣的成分位于锌铁尖晶石相的初始成相区,在1273~1473K生成硅酸钙/铅,部分硅酸钙/铅和磁铁铅矿相是通过转熔反应生成的.实验结果和热力学计算结果表明,液相线温度随着渣中CaO/SiO2比的增加和Fe/SiO2比的降低而增加.

  14. Precise measurements of half-lives and branching ratios for the β mirror transitions in the decay of {sup 23}Mg and {sup 27}Si

    Energy Technology Data Exchange (ETDEWEB)

    Magron, C.; Alfaurt, P.; Blank, B.; Daudin, L.; Gerbaux, M.; Giovinazzo, J.; Grevy, S.; Guerin, H.; Kurtukian Nieto, T.; Roche, M.; Smirnova, N.; Thomas, B.; Xayavong, L. [Centre d' Etudes Nucleaires de Bordeaux Gradignan, UMR 5797 CNRS/IN2P3 - Universite de Bordeaux, Gradignan (France); Eronen, T.; Gorelov, D.; Hakala, J.; Kolhinen, V.S.; Koponen, J.; Moore, I.D.; Penttilae, H.; Pohjalainen, I.; Reinikainen, J.; Reponen, M.; Rinta-Antila, S.; Voss, A. [University of Jyvaeskylae, Department of Physics (Finland); Roubin, A. de [Centre d' Etudes Nucleaires de Bordeaux Gradignan, UMR 5797 CNRS/IN2P3 - Universite de Bordeaux, Gradignan (France); Max-Planck-Institut fuer Kernphysik, Heidelberg (Germany)

    2017-04-15

    Half-lives and branching ratios for the two mirror β decays of {sup 23}Mg and {sup 27}Si have been measured at the University of Jyvaeskylae with the IGISOL facility. The results obtained, T{sub 1/2} = 11.303(3)s and T{sub 1/2} = 4.112(2)s for the half-lives of {sup 23}Mg and {sup 27}Si, respectively, are 7 and 8 times more precise than the averages of previous measurements. The values obtained for the super-allowed branching ratios of {sup 23}Mg and {sup 27}Si are B.R. = 92.18(8)% and B.R. = 99.74(2)%, respectively. The result for {sup 23}Mg is three times more precise than the average of the previous measurements, while for {sup 27}Si the precision has not been improved, the average of the previous measurements being already very precise. Isospin-symmetry-breaking corrections have been calculated for the two nuclei to determine the corrected Ft value. (orig.)

  15. Effect of nitrogen flow ratio on structure and properties of zirconium nitride films on Si(100) prepared by ion beam sputtering

    Indian Academy of Sciences (India)

    Shahab Norouzian; Majid Mojtahedzadeh Larijani; Reza Afzalzadeh

    2012-10-01

    In this study, zirconium nitride thin films were deposited on Si substrates by ion beam sputtering (IBS). Influence of N2/(N2+Ar) on the structural and physical properties of the films has been investigated with respect to the atomic ratio between nitrogen and zirconium. It was found that the thickness of layers decreased by increasing the F(N2). Moreover, crystalline plane peaks such as (111), (200) and (220) with (111) preferred orientation were observed due to strain energy which associate with (111) orientation in ZrN. Also, the fluctuation in nitrogen flow ratio results in colour and electrical resistivity of films.

  16. Effect of Ni-to-Fe ratio on structure and properties of Ni-Fe-B-Si-Nb coatings fabricated by laser processing

    Energy Technology Data Exchange (ETDEWEB)

    Li Ruifeng [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, No. 800 Dongchuan Road, Shanghai 200240 (China); School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003 (China); Li Zhuguo, E-mail: lrfzj7912@gmail.com [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, No. 800 Dongchuan Road, Shanghai 200240 (China); Huang Jian; Zhang Peilei; Zhu Yanyan [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, No. 800 Dongchuan Road, Shanghai 200240 (China)

    2011-02-01

    Ni-Fe-B-Si-Nb coatings have been deposited on mild steel substrates using high power laser cladding process followed by laser remelting. The influence of Ni-to-Fe concentration ratio in (Ni{sub 100-x}Fe{sub x}){sub 62}B{sub 18}Si{sub 18}Nb{sub 2} (x 55, 50, 45 and 40) powders on the phase composition and microstructure is analyzed by X-ray diffraction, scanning- and transmission-electron microscopies. The microhardness and corrosion resistance properties of the coatings are also measured. The results reveal that amorphous matrix layers are obtained for all coatings. The increase of the Ni-to-Fe ratio can promote the formation of {gamma}(Fe-Ni) phase and decrease the formation of Fe{sub 2}B phase and {alpha}-Fe phase. The coating with 1:1 ratio of Ni-to-Fe exhibits the highest microhardness of 1200 HV{sub 0.5} and superior corrosion resistance property due to its largest volume fraction of amorphous phase in the coating. Higher or lower than 1:1 ratio of Ni-to-Fe may result in lower amorphous forming ability. However, even that the coating with ratio of 3:2, shows a minimum of microhardness, it shows a better corrosion resistance than other two coatings.

  17. Mn(2+)-Ion Site Distribution of Zeolite Y (FAU, Si/Al = 1.56) Depending on the Ion-Exchange Ratio.

    Science.gov (United States)

    Seo, Sung Man; Moon, Dae Jun; Suh, Jeong Min; Zhu, John; Lim, Woo Taik

    2016-05-01

    To investigate the tendency of Mn(2+)-ion exchange into zeolite Y, four single crystals of fully dehydrated Mn2+, Na(+)-exchanged zeolite Y (Si/Al = 1.56) were prepared by the exchange of Na75-Y (INa75I[Si117Al75,O384]-FAU) with aqueous of various concentrations by Mn2+ and Na+ in a total 0.05 M for molar ratios of 1:1 (crystal 1), 1:25 (crystal 2), 1:50 (crystal 3), and 1:100 (crystal 4), respectively, followed by vacuum dehydration at 400 degrees C. Their single-crystal structures were determined by synchrotron X-ray diffraction techniques in the cubic space group Fd3(-)m and were refined to the final error indices R1/wR2 = 0.0440/0.1545, 0.0369/0.1153, 0.0373/0.1091, and 0.0506/0.1667, respectively. Their unit-cell formulas are approximately LMn33.5Na8I[Si117Al75O384]-FAU, IMn20.5Na34I[Si117Al75O384]-FAU, IMn20.5Na34I[Si117Al75O384]-FAU, and IMn16.5Na42I[Si117Al75O384]-FAU, respectively. The degree of Mn2+-ion exchange increases from 44.3% to 89.1% with increasing the initial Mn2+ concentrations as Na+ content and the unit cell constant of the zeolite framework decrease.

  18. Experimental evaluation of the effect of compression ratio on performance and emission of SI engine fuelled with gasoline and n-butanol blend at different loads

    Directory of Open Access Journals (Sweden)

    Rinu Thomas

    2016-09-01

    Full Text Available Never ending demand for efficient and less polluting engines have always inspired newer technologies. Extensive study has been done on variable compression ratio, a promising in-cylinder technology, in the recent past. The present work is an experimental investigation to examine the variation of different parameters such as brake thermal efficiency, exhaust gas temperature and emissions with respect to change in compression ratio in a single-cylinder carbureted SI engine at different loads with two different fuels. Experiments were conducted at three different compression ratios (CR = 7:1, 8.5:1 and 10:1. The fuels used in this study are pure gasoline and 20% n-butanol blend (B20 in gasoline. The results showed that brake thermal efficiency increases with CR at all loads. Further, the experimental results showed the scope of improving the part-load efficiency of SI engine by adopting the concept of variable compression ratio (VCR technology, especially when fuels with better anti-knock characteristics are used. The uncertainty analysis of the experiments based on the specifications of the equipment used is also tabulated.

  19. A transparent diode with high rectifying ratio using amorphous indium-gallium-zinc oxide/SiN{sub x} coupled junction

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Myung-Jea; Kim, Myeong-Ho; Choi, Duck-Kyun, E-mail: duck@hanyang.ac.kr [Department of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

    2015-08-03

    We introduce a transparent diode that shows both high rectifying ratio and low leakage current at process temperature below 250 °C. This device is clearly distinguished from all previous transparent diodes in that the rectifying behavior results from the junction between a semiconductor (amorphous indium-gallium-zinc oxide (a-IGZO)) and insulator (SiN{sub x}). We systematically study the properties of each junction within the device structure and demonstrate that the a-IGZO/SiN{sub x} junction is the source of the outstanding rectification. The electrical characteristics of this transparent diode are: 2.8 A/cm{sup 2} on-current density measured at −7 V; lower than 7.3 × 10{sup −9} A/cm{sup 2} off-current density; 2.53 ideality factor; and high rectifying ratio of 10{sup 8}–10{sup 9}. Furthermore, the diode structure has a transmittance of over 80% across the visible light range. The operating principle of the indium-tin oxide (ITO)/a-IGZO/SiN{sub x}/ITO device was examined with an aid of the energy band diagram and we propose a preliminary model for the rectifying behavior. Finally, we suggest further directions for research on this transparent diode.

  20. Structural properties of liquid aluminosilicate with varying Al2O3/SiO2 ratios: Insight from analysis and visualization of molecular dynamics data

    Science.gov (United States)

    Yen, N. V.; Lan, M. T.; Vinh, L. T.; Hong, N. V.

    2017-02-01

    Molecular dynamics (MD) simulations and visualizations were explored to investigate the changes in structure of liquid aluminosilicates. The models were constructed for four compositions with varying Al2O3/SiO2 ratio. The local structure and network topology was analyzed through the pair of radial distribution functions, bond angle, bond length and coordination number distributions. The results showed that the structure of aluminosilicates mainly consists of the basic structural units TOy (T is Al or Si; y = 3, 4, 5). Two adjacent units TOy are linked to each other through common oxygen atoms and form continuous random network of basic structural units TOy. The bond statistics (corner-, edge- and face- sharing) between two adjacent TOy units are investigated in detail. The self-diffusion coefficients for three atomic types are affected by the degree of polymerization (DOP) of network characterized by the proportions of nonbridging oxygen (NBO) and Qn species in the system. It was found that Q4 and Q3 tetrahedral species (tetrahedron with four and three bridging oxygens, respectively) decreases, while Q0 (with four nonbridging oxygen) increase with increasing Al2O3/SiO2 molar ratio, suggesting that a less polymerized network was formed. The structural and dynamical heterogeneities, micro-phase separation and liquid-liquid phase transition are also discussed in this work.

  1. The sulfur partition ratio and the sulfide capacity of Na2O-SiO2 slags at 1200 °C

    Science.gov (United States)

    Chan, Allen H.; Fruehan, R. J.

    1986-09-01

    The sulfur partition ratio between carbon-saturated iron and Na2O-SiO2 slags and the sulfide capacity of these slags have been measured at 1200 °C. The two measurements are consistent with each other and the results are compared with other investigations. These slags have higher sulfide capacities and partition ratios than equivalent CaO-based slags and are thus attractive desulfurizers. Both the sulfide capacity and the partition ratio increase with increasing Na2O. The activity coefficient of Na2S has been calculated; it also increases with increasing Na2O. The solubility of sulfur in a slag of 0.4 mole fraction Na2O is estimated to be 5 pct.

  2. Manipulating the aspect ratio of Si surface nanopattern with low energy ion sputtering and reactive ion etching

    Energy Technology Data Exchange (ETDEWEB)

    Hofsaess, Hans; Zhang, Kun; Vetter, Ulrich; Bobes, Omar; Bruesewitz, Christoph [II. Physikalisches Institut, Universitaet Goettingen, Friedrich-Hund-Platz 1, 37077 Goettingen (Germany)

    2012-07-01

    A periodic self-forming surface nanostructure can be produced with low energy ion sputtering. The wavelength of such nanopattern can be controlled very well, by varying the energy and the incident angle of ion-beam. A low energy N{sub 2}{sup +} ion beam produces not only nanoripples on Si surface, but also forms a thin silicon nitride layer on the ridges of the ripples. This thin silicon nitride layer has a thickness from some nm to 20 nm (depending on the ion energy and the incident angle) and acts as an inert nanomask for reactive ion etching process, resulting in formation of deep grooves. The depth of the grooves depends on the etching time. By combining the low energy N{sub 2}{sup +} ion beam sputtering and reactive ion etching, the formation of surface nanopattern with controllable average values of wavelength, ridge width and groove depth on Si surface can be realized. This surface nanostructured silicon with controllable features could be widely used in nanotechnology, including so-called black silicon for solar cells. Here, we report on the formation of nanoripple patterns by low energy N{sub 2}{sup +} ion beam ({<=}10 keV), and the modification of these nanopatterns by reactive ion etching. In addition, the optical properties of the nanostructured silicon surfaces are discussed.

  3. Growth of Si Bulk Crystals with Large Diameter Ratio Using Small Crucibles by Creating a Large Low-Temperature Region Inside a Si Melt Contained in an NOC Furnace Developed Using Two Zone Heaters

    Science.gov (United States)

    Nakajima, Kazuo; Ono, Satoshi; Murai, Ryota; Kaneko, Yuzuru

    2016-06-01

    Three zone heaters were generally used for a noncontact crucible (NOC) furnace. For practical reasons a simpler NOC furnace was developed with two zone heaters, which had a carbon heat holder to cover the three roles of each heater. Large low-temperature regions were obtained, and silicon ingots were grown in small crucibles with a large diameter and diameter ratio. Here, the diameter ratio is the ratio of the ingot diameter to the crucible diameter and can be as large as 0.90. The diameter ratio was controlled mainly by the temperature reduction of the first heater. Power changes of the second heater did not have a significant impact on the ingot diameter. Using this NOC furnace, maximum ingot diameters of 28.0, 33.5, and 45.0 cm were obtained using crucibles of 33, 40, and 50 cm in diameter, respectively. The oxygen concentration of the ingots did not strongly depend on the diameter ratio and were always low because convection in the Si melt was markedly suppressed by the carbon heat holder. Moreover, the oxygen concentration of the ingots has a tendency to become lower as the crucible diameter becomes larger.

  4. The influence of high-octane fuel blends on the performance of a two-stroke SI engine with knock-limited-compression ratio

    Science.gov (United States)

    Poola, Ramesh B.; Bhasker, T.; Nagalingam, B.; Gopalakrishnan, K. V.

    The use of alcohol-gasoline blends enables the favorable features of alcohols to be utilized in spark ignition (SI) engines while avoiding the shortcomings of their application as straight fuels. Eucalyptus and orange oils possess high octane values and are also good potential alternative fuels for SI engines. The high octane value of these fuels can enhance the octane value of the fuel when it is blended with low-octane gasoline. In the present work, 20 percent by volume of orange oil, eucalyptus oil, methanol and ethanol were blended separately with gasoline, and the performance, combustion and exhaust emission characteristics were evaluated at two different compression ratios. The phase separation problems arising from the alcohol-gasoline blends were minimized by adding eucalyptus oil as a cosolvent. Test results indicate that the compression ratio can be raised from 7.4 to 9 without any detrimental effect, due to the higher octane rating of the fuel blends. Knock-limited maximum brake output also increases due to extension of the knock limit. The knock limit is extended by methanol-eucalyptus-ethanol-orange oil blends, in descending order.

  5. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy – Part 1: Slant-columns and their ratios

    Directory of Open Access Journals (Sweden)

    M. Grutter

    2012-02-01

    Full Text Available The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006–2009 using a Scanning Infrared Gas Imaging System (SIGIS. The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm−1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2 to calculate the emission rates at different distances from the crater.

  6. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy - Part 1: Slant-columns and their ratios

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2012-02-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time). Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2) to calculate the emission rates at different distances from the crater.

  7. Alleviation of process-induced cracking of the antireflection TiN coating (ARC-TiN) in Al-Cu and Al-Cu-Si films

    CERN Document Server

    Peng, Y C; Yang, Y R; Hsieh, W Y; Hsieh, Y F

    1999-01-01

    The alleviation of cracking of the TiN-ARC layer on Al-Cu and Al-Cu-Si films after the development process has been achieved. For the TiN-ARC/Al-Cu system, the stress-induced defects decreased with increasing TiN-ARC layer thickness. In contrast, for the TiN-ARC/Al-Cu-Si system, Si nodules formed during cooling, thereby inducing poor coverage with high aspect-ratio holes. As a result, the photoresist developer penetrated through the films. Chemical vapor deposition of TiN-ARC or predeposition of a Ti Interposing layer was used to eliminate the formation of Si nodules.

  8. Electromagnetic properties of flake-shaped Fe–Si alloy particles prepared by ball milling

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Lei [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Jiang, Jian-Tang [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Department of Physics, Harbin Institute of Technology, Harbin 150001 (China); Wang, Zeng-Quan [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Gong, Yuan-Xun [Department of Physics, Harbin Institute of Technology, Harbin 150001 (China); Aerospace Research Institute of Special Material and Processing Technology, Beijing 100074 (China); Liu, Chao [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Zhen, Liang, E-mail: lzhen@hit.edu.cn [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); MOE Key Laboratory of Micro-system and Micro-structures Manufacturing, Harbin Institute of Technology, Harbin 150080 (China)

    2014-11-15

    Flake-shaped Fe–Si alloy particles with high aspect ratios were fabricated by ball milling commercially available Fe–Si powder, aiming to fabricate high-performance microwave absorbing fillers for coatings applied in 1–4 GHz range. To compare with spherical particles, higher permittivity and permeability was observed by using flaky particles as fillers. High aspect ratios contributed to an enhanced dielectric relaxation in the 1–4 GHz band, resulting in an increased permittivity. The thin thickness together with the high resistivity of Fe–Si flakes was believed to be helpful for suppressing the effect of eddy current and thus lead to an increase in the permeability. The electromagnetic wave absorbing (EMA) performances were observed to be enhanced. With a thin thickness of 2 mm, a wide absorption band with a minimum reflection loss of −12 dB was achieved in 1–4 GHz range, when using 75 wt% of flaky Fe–Si particles as fillers. The study indicated that flake-shaped Fe–Si particles were a promising candidate for EMA materials in L and S bands. - Highlights: • Flaky Fe–Si alloy particles were prepared in large scale via a simple ball milling method. • Coatings containing flakes Fe–Si particles present excellent EMA performance in L–S band. • The high shape anisotropy and the thin thickness contribute to the excellent EM property.

  9. Formation of copper nanoparticles in mordenite s with variable SiO{sub 2}/Al{sub 2}O{sub 3} molar ratios under redox treatments

    Energy Technology Data Exchange (ETDEWEB)

    Petranovskii, V.; Avalos, M. [UNAM, Centro de Nanociencias y Nanotecnologia, Km 107 Carretera Tijuana-Ensenada, 22800 Ensenada, Baja California (Mexico); Stoyanov, E. [University of California, Department of Chemistry, Riverside, 92521 California (United States); Gurin, V. [Belarusian State University, Research Institute for Physical Chemical Problems, Minsk 220080 (Belarus); Katada, N. [Tottori University, Department of Chemistry and Biotechnology, Tottori 680-8552 (Japan); Hernandez, M. A. [Benemerita Universidad Autonoma de Puebla, Departamento de Investigacion en Zeolitas, Ciudad Universitaria, Puebla (Mexico); Pestryakov, A. [Tomsk Polytechnic University, Tomsk 634050 (Russian Federation); Chavez R, F.; Zamorano U, R. [IPN, Escuela Superior de Fisica y Matematicas, Departamento de Fisica, Zacatenco, 07738 Mexico D. F. (Mexico); Portillo, R., E-mail: vitalii@cnyn.unam.mx [Benemerita Universidad Autonoma de Puebla, Facultad de Ciencias Quimicas, Ciudad Universitaria, Puebla (Mexico)

    2013-05-01

    A series of protonated copper-containing mordenite s with different SiO{sub 2}/Al{sub 2}O{sub 3} molar ratios (MR) in the range of 10{<=}MR{<=}206 was prepared by ion exchange in copper nitrate aqueous solution. The electron paramagnetic resonance of hydrated copper Mordenite s series testifies of several Cu{sup 2+} ion sites. Hydrogen reduction of copper ions incorporated into the mordenite s was shown to lead to different reduced copper species including small metallic particles inter alia. The structural properties and acidity of mordenite s were characterized. The optical appearance of the copper particles showed strong but nonmonotonic dependence on the MR value, in line with the variation in acidity of this series of mordenite s. Correlations between mordenite properties and the formation of different reduced copper species are discussed. (Author)

  10. An FT-IR study of NO adsorption over Cu-exchanged MFI catalysts. Effect of Si/Al ratio, copper loading and catalyst pre-treatment

    Energy Technology Data Exchange (ETDEWEB)

    Henriques, C.; Ribeiro, M.F.; Abreu, C. [Grupo de Zeolitos, Departamento de Engenharia Quimica, Instituto Superior Tecnico, Lisbon (Portugal); Murphy, D.M. [Department of Chemistry, University of Wales Cardiff, Cardiff (United Kingdom); Poignant, F.; Saussey, J.; Lavalley, J.C. [Laboratoire de Catalyse et Spectrochimie - ISMRA, Universite de Caen, URA 414, Caen (France)

    1998-03-06

    NO adsorption, at room temperature, has been studied by infrared spectroscopy on copper MFI catalysts with different Si/Al ratios and copper loadings. The relative amount of the overall Cu{sup 2+}-NO and Cu{sup +}-NO complexes has been evaluated for each catalyst, as well as that of the different Cu{sup 2+}-NO components. ESR spectra have also been recorded in order to check the different Cu{sup 2+} coordinations. It clearly appears that square planar copper sites predominate for high Cu/Al catalysts. A comparison with reactivity data, relative to SCR of NO by propene, under an excess of oxygen, strongly suggests that these sites are involved in the considered reaction

  11. Structure and properties of the slags of continuous converting of copper nickel-containing mattes and concentrates: II. Effect of the SiO2/CaO ratio on the structure and liquidus temperature of the slags

    Science.gov (United States)

    Pigarev, S. P.; Tsymbulov, L. B.; Selivanov, E. N.; Chumarev, V. M.

    2012-03-01

    The structure and liquidus temperature of the SiO2-CaO-Al2O3-FeO x -Cu2O-NiO slags that form during continuous converting of copper mattes and concentrates into blister copper are analyzed. The slag melt compositions are varied over a wide SiO2/CaO range. The slags are studied by X-ray diffraction, scanning electron microscopy, and electron-probe microanalysis. The liquidus temperature of the slags is determined by differential thermal analysis. It is found that, depending on the SiO2/CaO ratio, the structure and liquidus temperature of the slags change and the forms of copper in a slag also change. The SiO2/CaO range in a slag is recommended for the process of continuous converting of a copper nickel-containing sulfide raw materials.

  12. Tailoring the Mechanical Properties of High-Aspect-Ratio Carbon Nanotube Arrays using Amorphous Silicon Carbide Coatings

    NARCIS (Netherlands)

    Poelma, R.H.; Morana, B.; Vollebregt, S.; Schlangen, H.E.J.G.; Van Zeijl, H.W.; Fan, X.; Zhang, G.Q.

    2014-01-01

    The porous nature of carbon nanotube (CNT) arrays allows for the unique opportunity to tailor their mechanical response by the infiltration and deposition of nanoscale conformal coatings. Here, we fabricate novel photo-lithographically defined CNT pillars that are conformally coated with amorphous s

  13. Multi-Objective Flight Control for Drag Minimization and Load Alleviation of High-Aspect Ratio Flexible Wing Aircraft

    Science.gov (United States)

    Nguyen, Nhan; Ting, Eric; Chaparro, Daniel; Drew, Michael; Swei, Sean

    2017-01-01

    As aircraft wings become much more flexible due to the use of light-weight composites material, adverse aerodynamics at off-design performance can result from changes in wing shapes due to aeroelastic deflections. Increased drag, hence increased fuel burn, is a potential consequence. Without means for aeroelastic compensation, the benefit of weight reduction from the use of light-weight material could be offset by less optimal aerodynamic performance at off-design flight conditions. Performance Adaptive Aeroelastic Wing (PAAW) technology can potentially address these technical challenges for future flexible wing transports. PAAW technology leverages multi-disciplinary solutions to maximize the aerodynamic performance payoff of future adaptive wing design, while addressing simultaneously operational constraints that can prevent the optimal aerodynamic performance from being realized. These operational constraints include reduced flutter margins, increased airframe responses to gust and maneuver loads, pilot handling qualities, and ride qualities. All of these constraints while seeking the optimal aerodynamic performance present themselves as a multi-objective flight control problem. The paper presents a multi-objective flight control approach based on a drag-cognizant optimal control method. A concept of virtual control, which was previously introduced, is implemented to address the pair-wise flap motion constraints imposed by the elastomer material. This method is shown to be able to satisfy the constraints. Real-time drag minimization control is considered to be an important consideration for PAAW technology. Drag minimization control has many technical challenges such as sensing and control. An initial outline of a real-time drag minimization control has already been developed and will be further investigated in the future. A simulation study of a multi-objective flight control for a flight path angle command with aeroelastic mode suppression and drag minimization demonstrates the effectiveness of the proposed solution. In-flight structural loads are also an important consideration. As wing flexibility increases, maneuver load and gust load responses can be significant and therefore can pose safety and flight control concerns. In this paper, we will extend the multi-objective flight control framework to include load alleviation control. The study will focus initially on maneuver load minimization control, and then subsequently will address gust load alleviation control in future work.

  14. Oxidative Unzipping and Transformation of High Aspect Ratio Boron Nitride Nanotubes into “White Graphene Oxide” Platelets

    Science.gov (United States)

    Nautiyal, Pranjal; Loganathan, Archana; Agrawal, Richa; Boesl, Benjamin; Wang, Chunlei; Agarwal, Arvind

    2016-07-01

    Morphological and chemical transformations in boron nitride nanotubes under high temperature atmospheric conditions is probed in this study. We report atmospheric oxygen induced cleavage of boron nitride nanotubes at temperatures exceeding 750 °C for the first time. Unzipping is then followed by coalescence of these densely clustered multiple uncurled ribbons to form stacks of 2D sheets. FTIR and EDS analysis suggest these 2D platelets to be Boron Nitride Oxide platelets, with analogous structure to Graphene Oxide, and therefore we term them as “White Graphene Oxide” (WGO). However, not all BNNTs deteriorate even at temperatures as high as 1000 °C. This leads to the formation of a hybrid nanomaterial system comprising of 1D BN nanotubes and 2D BN oxide platelets, potentially having advanced high temperature sensing, radiation shielding, mechanical strengthening, electron emission and thermal management applications due to synergistic improvement of multi-plane transport and mechanical properties. This is the first report on transformation of BNNT bundles to a continuous array of White Graphene Oxide nanoplatelet stacks.

  15. Direct Observation of Two Phase Flow Generated by an Alumina Seeded Grain in High Aspect Ratio Channels

    Science.gov (United States)

    2010-06-01

    and the characteristic length is 44.45 mm. Finally, the convection coefficient is calculated to be 298 W/m2*K. Incropera and Dewitt note that...Advanced Strength and Applied Elasticity (4th ed.). Upper Saddle, NJ: Prentice Hall PTR, 2003. [11] F. P. Incropera and D. P. DeWitt

  16. Fabricating and Tailoring Polyaniline (PANI) Nanofibers with High Aspect Ratio in a Low-Acid Environment in a Magnetic Field.

    Science.gov (United States)

    Ma, Yong; Chen, Yanhui; Mei, Ang; Qiao, Mingtao; Hou, Chunping; Zhang, Hepeng; Zhang, Qiuyu

    2016-01-01

    In a 0.010 m HCl solution, we successfully transformed irregular polyaniline (PANI) agglomerates into uniform PANI nanofibers with a diameter of 46-145 nm and a characteristic length on the order of several microns by the addition of superparamagnetic Fe3 O4 microspheres in a magnetic field. The PANI morphological evolution showed that the PANI nanofibers stemmed from the PANI coating shell synthesized on the surface of the Fe3 O4 microsphere chains. It was found that the magnetic field could optimize the PANI nanofibers with a narrow diameter size distribution, and effectively suppressed secondary growth. When compared with other microspheres (like silica and polystyrene), only the use of superparamagnetic Fe3 O4 microspheres resulted in the appearance of PANI nanofibers. Attempts to form these high-quality PANI nanofibers in other concentrations of HCl solution were unsuccessful. This deficiency was largely attributed to the inappropriate quantity of aniline cations. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. BisGMA/TEGDMA dental nanocomposites containing glyoxylic acid modified high-aspect ratio hydroxyapatite nanofibers with enhanced dispersion

    Science.gov (United States)

    Chen, Liang; Xu, Changqi; Wang, Yong; Shi, Jian; Yu, Qingsong

    2012-01-01

    The purpose of this research was to investigate the influence of the glyoxylic acid (GA) modification of hydroxyapatite (HAP) nanofibers on their dispersion in bisphenol A glycidyl methacrylate (BisGMA)/triethylene glycol dimethacrylate (TEGDMA) dental composites and also investigate the mechanical properties, water absorption, and water solubility of the resulting dental resins and composites. Scanning/Transmission electron microscopy (STEM) images showed that microsized HAP nanofiber bundles could be effectively broken down to individual HAP nanofibers with an average length of ~15 μm after the surface modification process. Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA) characterization confirmed glyoxylic acid was chemically grafted on the HAP nanofiber surface, hypothetically by reacting with the amine group on HAP nanofiber surface. The enhanced dispersion of HAP nanofibers in dental matrix led to increased biaxial flexural strength (BFS) compared with the corresponding dental resins and composites filled with untreated HAP nanofibers. In addition, impregnation of small mass fractions of the glyoxylic acid modified HAP nanofibers into the BisGMA/TEGDMA dental resins (5wt%, 10wt%) or composites (2wt%, 3wt%) could also substantially improve the BFS in comparison with the controls(pure resins or dental composites filled with silica particles alone). Larger mass fractions could not further increase the mechanical property or even degrade the BFS values. Water behavior testing results indicated that the addition of glyoxylic acid modified HAP nanofibers resulted in higher water absorption and water solubility values which is not preferred for clinical application. In summary, well dispersed HAP nanofibers and their dental composites with enhanced mechanical property have been successfully fabricated but the water absorption and water solubility of such dental composites need to be further improved. PMID:22689264

  18. BisGMA/TEGDMA dental nanocomposites containing glyoxylic acid modified high-aspect ratio hydroxyapatite nanofibers with enhanced dispersion

    OpenAIRE

    Chen, Liang; Xu, Changqi; Wang,Yong; Shi, Jian; Yu, Qingsong; Li, Hao

    2012-01-01

    The purpose of this research was to investigate the influence of the glyoxylic acid (GA) modification of hydroxyapatite (HAP) nanofibers on their dispersion in bisphenol A glycidyl methacrylate (BisGMA)/triethylene glycol dimethacrylate (TEGDMA) dental composites and also investigate the mechanical properties, water absorption, and water solubility of the resulting dental resins and composites. Scanning/Transmission electron microscopy (STEM) images showed that microsized HAP nanofiber bundle...

  19. Design and microfabrication of a high-aspect-ratio PDMS microbeam array for parallel nanonewton force measurement and protein printing

    Science.gov (United States)

    Sasoglu, F. M.; Bohl, A. J.; Layton, B. E.

    2007-03-01

    Cell and protein mechanics has applications ranging from cellular development to tissue engineering. Techniques such as magnetic tweezers, optic tweezers and atomic force microscopy have been used to measure cell deformation forces of the order of piconewtons to nanonewtons. In this study, an array of polymeric polydimethylsiloxane (PDMS) microbeams with diameters of 10-40 µm and lengths of 118 µm was fabricated from Sylgard® with curing agent concentrations ranging from 5% to 20%. The resulting spring constants were 100-300 nN µm-1. The elastic modulus of PDMS was determined experimentally at different curing agent concentrations and found to be 346 kPa to 704 kPa in a millimeter-scale array and ~1 MPa in a microbeam array. Additionally, the microbeam array was used to print laminin for the purpose of cell adhesion. Linear and nonlinear finite element analyses are presented and compared to the closed-from solution. The highly compliant, transparent, biocompatible PDMS may offer a method for more rapid throughput in cell and protein mechanics force measurement experiments with sensitivities necessary for highly compliant structures such as axons.

  20. Acoustic Scattering from Sand Dollars (Dendraster excentricus): Modeling as High Aspect Ratio Oblate Objects and Comparison to Experiment

    Science.gov (United States)

    2008-09-01

    naturally occurring dense collections. These benthic echinoderms can form concentrations of up to several hundred per square meter in the sandy, shallow...L. (1972). “A new approach to the shaded picture problem”, Proc ACM National Conf. Nichols, D. (1969). Echinoderms , 4th edition (Hutchinson & Co

  1. Sacrificial structures for deep reactive ion etching of high-aspect ratio kinoform silicon x-ray lenses

    DEFF Research Database (Denmark)

    Stöhr, Frederik; Michael-Lindhard, Jonas; Hübner, Jörg

    2015-01-01

    investigated how sacrificial structures in the form of guarding walls and pillars may be utilized to facilitate accurate control of the etch profile. Unlike other sacrificial structuring approaches, no silicon-on-insulator substrates or multiple lithography steps are required. In addition, the safe removal...

  2. Fabrication of High Aspect Ratio Through-Wafer Vias in CMOS Wafers for 3-D Packaging Applications

    DEFF Research Database (Denmark)

    Rasmussen, Frank Engel; Frech, J.; Heschel, M.

    2003-01-01

    A process for fabrication of through-wafer vias in CMOS wafers is presented. The process presented offers simple and well controlled fabrication of through-wafer vias using DRIE formation of wafer through-holes, low temperature deposition of through-hole insulation, doubled sided sputtering of Cr....../Au, and electroless deposition of Cu. A novel characteristic of the process is the use of a metal etch stop layer providing perfect control of the etch profile of the wafer through-holes in combination with a remarkably improved etch uniformity across the wafer. Excellent through-hole insulation is provided through...

  3. Fundamentals of figure control and fracture-'free' finishing for high aspect ratio laser optics

    Energy Technology Data Exchange (ETDEWEB)

    Suratwala, Tayyab [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2014-10-01

    The high level objectives of the this work were to: 1) scientifically understand critical phenomena affecting the surface figure during full aperture finishing; 2) utilize these fundamentals to more deterministically control the surface figure during finishing; 3) successfully polish under rogue particle-‘free’ environments during polishing by understanding/preventing key sources of rogue particles.

  4. Effect of ac electrodeposition conditions on the growth of high aspect ratio copper nanowires in porous aluminum oxide templates.

    Science.gov (United States)

    Gerein, Nathan J; Haber, Joel A

    2005-09-22

    The effect of several deposition parameters on the uniformity of copper electrodeposition through the alumina barrier layer into porous aluminum oxide templates grown in sulfuric or oxalic acid was systematically investigated. A fractional factorial design of experiment was conducted to find suitable deposition conditions among the variables: frequency, voltage, pulsed or continuous deposition, electrolyte concentration, and barrier layer thinning voltage. Continuous ac sine wave deposition conditions yielded excellent uniformity of pore-filling but damaged the porous aluminum oxide templates when deposition was continued to grow bulk copper on the surface. Pulsed electrodeposition yielded comparable uniformity of pore-filling and no damage to the porous aluminum oxide templates, even when bulk copper was deposited on them. Further optimization of pulsed deposition conditions was accomplished by comparing square and sine waveforms and pulse polarity. Pulsed square waveforms produced better pore-filling than pulsed sine waveforms. For sine wave depositions, the oxidative/reductive pulse polarity was more efficient than the commonly used reductive/oxidative pulse polarity. For square wave depositions into sulfuric acid grown pores, the reductive/oxidative pulse polarity produces more uniform pore-filling, likely as a result of enhanced resonant tunneling through the barrier layer and reoxidation of copper in faster filling pores.

  5. Opportunities for high aspect ratio micro-electro-magnetic-mechanical systems (HAR-MEMMS) at Lawrence Berkeley Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Hunter, S. [ed.

    1993-10-01

    This report contains viewgraphs on the following topics: Opportunities for HAR-MEMMS at LBL; Industrial Needs and Opportunities; Deep Etch X-ray Lithography; MEMS Activities at BSAC; DNA Amplification with Microfabricated Reaction Chamber; Electrochemistry Research at LBL; MEMS Activities at LLNL; Space Microsensors and Microinstruments; The Advanced Light Source; Institute for Micromaching; IBM MEMS Interests; and Technology Transfer Opportunities at LBL.

  6. Functionalized Nano-Film Microchannel Plate: A Single High Aspect Ratio Device for High Resolution, Low Noise Astronomical Imaging Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is to apply proven nano-film technology to enable Microchannel plate (MCP) devices to be manufactured on a range of insulating substrates and...

  7. Functionalized Nano-Film Microchannel Plate: A Single High Aspect Ratio Device for High Resolution, Low Noise Astronomical Imaging Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Atomic layer deposited functional nano-film technology is used to manufacture Microchannel plate (MCP) devices capable of high gain / low ion feedback operation, on...

  8. Tailoring the Mechanical Properties of High-Aspect-Ratio Carbon Nanotube Arrays using Amorphous Silicon Carbide Coatings

    NARCIS (Netherlands)

    Poelma, R.H.; Morana, B.; Vollebregt, S.; Schlangen, H.E.J.G.; Van Zeijl, H.W.; Fan, X.; Zhang, G.Q.

    2014-01-01

    The porous nature of carbon nanotube (CNT) arrays allows for the unique opportunity to tailor their mechanical response by the infiltration and deposition of nanoscale conformal coatings. Here, we fabricate novel photo-lithographically defined CNT pillars that are conformally coated with amorphous

  9. Monolithic integration of optical grade GaAs on Si (001) substrates deeply patterned at a micron scale

    Energy Technology Data Exchange (ETDEWEB)

    Bietti, Sergio; Scaccabarozzi, Andrea; Bonera, Emiliano; Miglio, Leo; Sanguinetti, Stefano [L-NESS and Dip. di Scienza dei Materiali, Universitá di Milano Bicocca, Via Cozzi 53, I–20125 Milano (Italy); Frigeri, Cesare [CNR-IMEM Institute, Parco Area delle Scienze 37/A, I–43100 Parma (Italy); Bollani, Monica [CNR–IFN, L–NESS, via Anzani 42, I–22100 Como (Italy); Falub, Claudiu V.; Känel, Hans von [Laboratory for Solid State Physics, ETH Zurich, Schafmattstrasse 16, CH-8093 Zurich (Switzerland)

    2013-12-23

    Dense arrays of micrometric crystals, with areal filling up to 93%, are obtained by depositing GaAs in a mask-less molecular beam epitaxy process onto Si substrates. The substrates are patterned into tall, micron sized pillars. Faceted high aspect ratio GaAs crystals are achieved by tuning the Ga adatom for short surface diffusion lengths. The crystals exhibit bulk-like optical quality due to defect termination at the sidewalls. Simultaneously, the thermal strain induced by different thermal expansion parameters of GaAs and Si is fully relieved. This opens the route to thick film applications without crack formation and wafer bowing.

  10. Thermal stability dependence on the stacking order and thickness ratio of the CoPt -TiO2/CoCrPt-SiO2 stacked media

    Science.gov (United States)

    Park, S. H.; Lee, T. D.; Kong, S. H.; Yoon, S. Y.; Lee, H. S.; Kim, H. J.; Oh, H. S.

    2008-04-01

    Thermal stability of the present CoCrPt -SiO2 media becomes a more critical issue as recording density steadily increases. In the present study, thermal stability of the stacked media composed of high Ku CoPt -TiO2 and normal Ku CoCrPt -SiO2 was studied by changing stacking order and thickness of each layer while keeping a constant total thickness. When the CoPt -TiO2 layer was placed under the CoCrPt -SiO2 layer, negative nucleation field and coercivity increased much more than those of the reverse stacking case. Thermal stability of the CoPt -TiO2 bottom group was superior to that of the CoCrPt -SiO2 bottom group when measured by a spin stand.

  11. Optimization of NaOH Molarity, LUSI Mud/Alkaline Activator, and Na2SiO3/NaOH Ratio to Produce Lightweight Aggregate-Based Geopolymer

    Directory of Open Access Journals (Sweden)

    Rafiza Abdul Razak

    2015-05-01

    Full Text Available This paper presents the mechanical function and characterization of an artificial lightweight geopolymer aggregate (ALGA using LUSI (Sidoarjo mud and alkaline activator as source materials. LUSI stands for LU-Lumpur and SI-Sidoarjo, meaning mud from Sidoarjo which erupted near the Banjarpanji-1 exploration well in Sidoarjo, East Java, Indonesia on 27 May 2006. The effect of NaOH molarity, LUSI mud/Alkaline activator (LM/AA ratio, and Na2SiO3/NaOH ratio to the ALGA are investigated at a sintering temperature of 950 °C. The results show that the optimum NaOH molarity found in this study is 12 M due to the highest strength (lowest AIV value of 15.79% with lower water absorption and specific gravity. The optimum LUSI mud/Alkaline activator (LM/AA ratio of 1.7 and the Na2SiO3/NaOH ratio of 0.4 gives the highest strength with AIV value of 15.42% with specific gravity of 1.10 g/cm3 and water absorption of 4.7%. The major synthesized crystalline phases were identified as sodalite, quartz and albite. Scanning Electron Microscope (SEM image showed more complete geopolymer matrix which contributes to highest strength of ALGA produced.

  12. Optimization of NaOH Molarity, LUSI Mud/Alkaline Activator, and Na2SiO3/NaOH Ratio to Produce Lightweight Aggregate-Based Geopolymer.

    Science.gov (United States)

    Razak, Rafiza Abdul; Abdullah, Mohd Mustafa Al Bakri; Hussin, Kamarudin; Ismail, Khairul Nizar; Hardjito, Djwantoro; Yahya, Zarina

    2015-05-21

    This paper presents the mechanical function and characterization of an artificial lightweight geopolymer aggregate (ALGA) using LUSI (Sidoarjo mud) and alkaline activator as source materials. LUSI stands for LU-Lumpur and SI-Sidoarjo, meaning mud from Sidoarjo which erupted near the Banjarpanji-1 exploration well in Sidoarjo, East Java, Indonesia on 27 May 2006. The effect of NaOH molarity, LUSI mud/Alkaline activator (LM/AA) ratio, and Na2SiO3/NaOH ratio to the ALGA are investigated at a sintering temperature of 950 °C. The results show that the optimum NaOH molarity found in this study is 12 M due to the highest strength (lowest AIV value) of 15.79% with lower water absorption and specific gravity. The optimum LUSI mud/Alkaline activator (LM/AA) ratio of 1.7 and the Na2SiO3/NaOH ratio of 0.4 gives the highest strength with AIV value of 15.42% with specific gravity of 1.10 g/cm3 and water absorption of 4.7%. The major synthesized crystalline phases were identified as sodalite, quartz and albite. Scanning Electron Microscope (SEM) image showed more complete geopolymer matrix which contributes to highest strength of ALGA produced.

  13. Preparation and characterization of poly(glycidyl methacrylate)-grafted magnetic nanoparticles: Effects of the precursor concentration on polyol synthesis of Fe3O4 and [PMDETA]0/[CuBr2]0 ratios on SI-AGET ATRP

    Science.gov (United States)

    Jiang, Liping; Zhou, Xuyang; Wei, Guyun; Lu, Xiaoduo; Wei, Weiping; Qiu, Jianhua

    2015-12-01

    Polymer brushes based on poly(glycidyl methacrylate) (PGMA) have been successfully grafted from the surface of silica coated iron oxide (Fe3O4@SiO2) nanoparticles via surface-initiated activators generated by electron transfer atom transfer radical polymerization (SI-AGET ATRP). The size of the nanoparticles could be adjusted from 7.3 to 9.6 nm by varying the precursor concentration of iron(III) acetylacetonate. The Fe3O4 nanoparticles possessed a highly crystalline structure, and the saturation magnetization of the as-prepared magnetite was strongly related to the particle size. Furthermore, the grafted PGMA content on the magnetic nanoparticles could be controlled by varying the ligand to transition metal ratio in a N,N,N‧,N″,N″-pentamethyldiethylenetriamine (PMDETA)/CuBr2 catalyst system. The maximum grafted content was 23.1% at a ratio of [PMDETA]0/[CuBr2]0 = 2:1.

  14. In situ toughened SiC ceramics with Al-B-C additions and oxide-coated SiC platelet/SiC composites

    Energy Technology Data Exchange (ETDEWEB)

    Cao, J. [Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering]|[Lawrence Berkeley National Lab., CA (United States). Materials Sciences Div.

    1996-12-01

    This work aimed at fabrication and characterization of high toughness SiC ceramics through the applications of in situ toughening and SiC platelet reinforcement. The processing-microstructure-property relations of hot pressed SiC with Al, B, and C additions (designated as ABC-SiC) were investigated. Through a liquid phase sintering mechanism, dense SiC was obtained by hot pressing at a temperature as low as 1,700 C with 3 wt% Al, 0.6 wt% B, and 2 wt% C additions. These sintering aids also enhanced the {beta}-to-{alpha} (3C-to-4H) phase transformation, which promoted SiC grains to grow into plate-like shapes. Under optimal processing conditions, the microstructure exhibited high-aspect-ratio plate-shaped grains with a thin (< 1 nm) Al-containing amorphous grain boundary film. The mechanical properties of the toughened SiC and the composites were evaluated in comparison with a commercial Hexoloy SiC under identical test conditions. The C-curve behavior was examined using the strength-indentation load relationship and compared with that directly measured using precracked compact tension specimens. The in situ toughened ABC-SiC exhibited much improved flaw tolerance and a significantly rising R-curve behavior. A steady-state toughness in excess of 9 MPam{sup 1/2} was recorded for the ABC-SiC in comparison to a single valued toughness below 3 MPam{sup 1/2} for the Hexoloy. Toughening in the ABC-SiC was mainly attributed to grain bridging and subsequent pullout of the plate-shaped grains. The high toughness ABC-SiC exhibited a bend strength of 650 MPa with a Weibull modulus of 19; in comparison, the commercial SiC showed a bend strength of 400 MPa with a Weibull modulus of 6. Higher fracture toughness was also achieved by the reinforcement of SiC platelets, encapsulated with alumina, yttria, or silica, in a SiC matrix.

  15. Influence of Na2O/Al2O3 and SiO2/Al2O3 ratios on the immobilization of Pb from electric arc furnace into the fly ash based geopolymers

    Directory of Open Access Journals (Sweden)

    Zejak R.

    2013-04-01

    Full Text Available Electric arc furnace dust (EAFD is by-product of iron and steel scrap remelting in electric arc furnace. This waste is classified as a hazardous material due to the leaching of heavy metals into the environment. Geopolymeryzation of fly ash into construction materials called - geopolymer is a considering as a possible way of immobilization of heavy metals from EAFD. Mechanical properties and chemical stability of geopolymers are mostly determined by the ratio between main oxides, Na2O, Al2O3 and SiO2. In this paper we have investigated possibility of Pb immobilization from EAFD into the fly ash based geopolymer. Geopolymers are synthesized at different Na2O/Al2O3 and SiO2/Al2O3 ratios. Compressive strength and chemical stability of geopolymers with respect to the leaching of Pb in water according to the EN 12457 regulation were tested. The results have shown that Na2O/Al2O3 and SiO2/Al2O3 ratios have influence on the compressive strength of geopolymers and Pb release in the water environment.

  16. Effect of Mg/B{sub 2}O{sub 3} molar ratio and furnace temperature on the phase evaluation and morphology of SiC–B{sub 4}C nanocomposite prepared by MASHS method

    Energy Technology Data Exchange (ETDEWEB)

    Roghani, Hamed [Semiconductor Department, Materials and Energy Research Center, Karaj (Iran, Islamic Republic of); Tayebifard, Seyed Ali, E-mail: a_tayebifard@yahoo.com [Semiconductor Department, Materials and Energy Research Center, Karaj (Iran, Islamic Republic of); Kazemzadeh, Asghar [Semiconductor Department, Materials and Energy Research Center, Karaj (Iran, Islamic Republic of); Nikzad, Leila [Ceramic Department, Materials and Energy Research Center, Karaj (Iran, Islamic Republic of)

    2015-07-01

    In this study, SiC–B{sub 4}C nanocomposite has been synthesized in situ successfully by Mechanical activated combustion synthesis method (MASHS). Initially Si, C, B{sub 2}O{sub 3} and Mg powders as raw materials were weighed according to different molar ratio of Mg to B{sub 2}O{sub 3}. In next step theses materials were milled in a planetary mill under Ar atmosphere. The synthesis step was performed in a tube furnace equipped with controlled atmosphere system. The different furnace temperature was investigated on the phase synthesis and morphology of the products. The specimens in the various steps were studied by XRD analysis for evaluation of the phase compositions and calculation of the average crystallite size of them. The morphology of synthesized products was investigated by scanning and transmission electron microscopes (SEM&TEM). The final product contains main phases MgO, B{sub 4}C and SiC. Also, In this sample byproducts were characterized such as Mg{sub 3}B{sub 2}O{sub 6}, Mg{sub 2}B{sub 2}O{sub 5} and remaining carbon. XRD pattern of synthesized sample showed the considerable effect of increasing Mg to B{sub 2}O{sub 3} molar ratio on reducing the amount of Mg{sub 3}B{sub 2}O{sub 6}, Mg{sub 2}B{sub 2}O{sub 5} and remaining carbon. SiC–B{sub 4}C composite was synthesized with more homogenous morphology by reducing the furnace temperature from 1000 to 900 °C, but reduction of temperature up to 800 °C give rise to uncompleted reaction whereas some unreacted Si remains. Average crystallite sizes of optimal sample were calculated 10.5 and 8 nm for SiC and B{sub 4}C respectively. These values are consisted of the TEM results somehow while grain size was less than 70 nm. Also SEM observation showed fine grains with sizes falling in the nanometer range. - Graphical abstract: Display Omitted - Highlights: • Composite prepared by combustion synthesis method in system of Si, C, B{sub 2}O{sub 3} and Mg. • More than stoichiometric Mg/B{sub 2}O{sub 3

  17. Effects of Zeolite Structure and Si/Al Ratio on Adsorption Thermodynamics and Intrinsic Kinetics of Monomolecular Cracking and Dehydrogenation of Alkanes over Bronsted Acid Sites

    Science.gov (United States)

    Janda, Amber Leigh

    It is well known that the efficacy of acidic zeolite catalysts for the cracking of hydrocarbons originates from the shape and size of the zeolite pores. However, the mechanisms by which changes in pore structure influence cracking kinetics are not well understood or exploited. The aim of this dissertation is to use experiments and simulations to shed light on the ways by which zeolite structure and acid site location affect the apparent and intrinsic kinetics of n-alkane monomolecular cracking and dehydrogenation. In the rate-determining step of these processes, C-C or C-H bonds are cleaved catalytically by Bronsted protons. Thus, the kinetics of monomolecular activation reactions are useful for characterizing the influence of active site structural environment on catalysis. In Chapter 2, the effects of active site distribution on n-butane monomolecular activation kinetics are investigated for commercial samples of MFI having a range of the Si/Al ratio. Based on UV-visible spectroscopic analyses of (Co,Na)-MFI, it is inferred that, with increasing Al concentration, the fraction of Co---and, by extension, Bronsted protons in H-MFI---located at channel intersections increases relative to the fraction located at channels. Concurrently, the first-order rate coefficients (kapp) for cracking and dehydrogenation, the selectivity to terminal cracking versus central cracking, and the selectivity to dehydrogenation versus cracking increase. The stronger dependence of the selectivity to dehydrogenation on Al content is attributed to a product-like transition state, the stability of which is more sensitive to confinement than the stabilities of cracking transition states, which occur earlier along the reaction coordinate. For terminal cracking and dehydrogenation, the intrinsic activation entropy (DeltaS‡int ) increases with Al content, consistent with the larger dimensions of intersections relative to channels. Surprisingly, the rate of dehydrogenation is inhibited by

  18. Reductively Responsive Hydrogel Nanoparticles with Uniform Size, Shape, and Tunable Composition for Systemic siRNA Delivery in Vivo.

    Science.gov (United States)

    Ma, Da; Tian, Shaomin; Baryza, Jeremy; Luft, J Christopher; DeSimone, Joseph M

    2015-10-01

    To achieve the great potential of siRNA based gene therapy, safe and efficient systemic delivery in vivo is essential. Here we report reductively responsive hydrogel nanoparticles with highly uniform size and shape for systemic siRNA delivery in vivo. "Blank" hydrogel nanoparticles with high aspect ratio were prepared using continuous particle fabrication based on PRINT (particle replication in nonwetting templates). Subsequently, siRNA was conjugated to "blank" nanoparticles via a disulfide linker with a high loading ratio of up to 18 wt %, followed by surface modification to enhance transfection. This fabrication process could be easily scaled up to prepare large quantity of hydrogel nanoparticles. By controlling hydrogel composition, surface modification, and siRNA loading ratio, siRNA conjugated nanoparticles were highly tunable to achieve high transfection efficiency in vitro. FVII-siRNA conjugated nanoparticles were further stabilized with surface coating for in vivo siRNA delivery to liver hepatocytes, and successful gene silencing was demonstrated at both mRNA and protein levels.

  19. Coupled Ge/Si and Ge isotope ratios as geochemical tracers of seafloor hydrothermal systems: Case studies at Loihi Seamount and East Pacific Rise 9°50‧N

    Science.gov (United States)

    Escoube, Raphaelle; Rouxel, Olivier J.; Edwards, Katrina; Glazer, Brian; Donard, Olivier F. X.

    2015-10-01

    Germanium (Ge) and Silicon (Si) exhibit similar geochemical behavior in marine environments but are variably enriched in seafloor hydrothermal fluids relative to seawater. In this study, Ge isotope and Ge/Si ratio systematics were investigated in low temperature hydrothermal vents from Loihi Seamount (Pacific Ocean, 18°54‧N, 155°15‧W) and results were compared to high-temperature vents from the East Pacific Rise (EPR) at 9°50‧N. Loihi offers the opportunity to understand contrasting Ge and Si behavior in low temperature seafloor hydrothermal systems characterized by abundant Fe oxyhydroxide deposition at the seafloor. The results show that both Ge/Si and δ74/70Ge in hydrothermal fluids are fractionated relative to the basaltic host rocks. The enrichment in Ge vs. Si relative to fresh basalts, together with Ge isotope fractionation (Δ74/70Gefluid-basalt up to 1.15‰ at EPR 9°50‧N and 1.64‰ at Loihi) are best explained by the precipitation of minerals (e.g. quartz and Fe-sulfides) during higher temperature seawater-rock reactions in the subsurface. The study of Fe-rich hydrothermal deposits at Loihi, largely composed of Fe-oxyhydroxides, shows that Ge isotopes are also fractionated upon mineral precipitation at the seafloor. We obtained an average Ge isotope fractionation factor between Fe-oxyhydroxide (ferrihydrite) and dissolved Ge in the fluid of -2.0 ± 0.6‰ (2sd), and a maximum value of -3.6 ± 0.6‰ (2sd), which is consistent with recent theoretical and experimental studies. The study of a hydrothermal chimney at Bio 9 vent at EPR 9°50‧N also demonstrates that Ge isotopes are fractionated by approximately -5.6 ± 0.6‰ (2sd) during precipitation of metal sulfides under hydrothermal conditions. Using combined Ge/Si and estimated Ge isotope signatures of Ge sinks and sources in seawater, we propose a preliminary oceanic budget of Ge which reveals that an important sink, referred as the "missing Ge sink", may correspond to Ge sequestration

  20. Structural Changes of Y Zeolites with Different Initial SiO2/Al2O3 Ratios during Hydrothermal Treatment%硅铝比及水热温度对Y型分子筛结构变化的影响

    Institute of Scientific and Technical Information of China (English)

    王玉超; 申宝剑; 曾朋晖

    2005-01-01

    The effects of the initial framework SiO2/Al2O3 ratio and temperature on the structural changes of NaY zeolites during hydrothermal treatments are studied. Two samples with different framework SiO2/Al2O3 ratios are subjected to hydrothermal treatment at four different temperatures. For zeolite with a lower initial SiO2/Al2O3 ratio of 4.2, mesopores are easily formed because more framework aluminum is detached. Moreover, two kinds of mesopores are produced at a higher temperature due to the interconnection of vacancies and smaller mesopores. For zeolite with a higher initial SiO2/Al2O3 ratio of 6.0, there are less mesopores formed as compared with the lower initial SiO2/Al2O3 ratio sample, but there are some macropores formed. This may be attributed to the isolation of vacancies and the different distributions of aluminum in the crystal lattice of the zeolite. The experiment data show that NaY with the SiO2/Al2O3 ratio of 6.0 retains a high relative crystallinity during the hydrothermal treatment. This proves that a high framework SiO2/Al2O3 ratio benefits the stability of zeolite.

  1. Improvements in the synthesis of zeolites with low Si/Al ratio from Venezuelan sodium silicate for an environmentally friendly process

    Directory of Open Access Journals (Sweden)

    Adriana Lucía García

    2016-04-01

    Full Text Available LTA and FAU zeolites were successfully synthesized from a Venezuelan sodium silicate solution, by hydrothermal crystallization under autogenous pressure at 100°C, with 2–24h crystallization times. The synthesized materials were characterized by XRD, BET specific surface area and SEM. A series of synthesis tests were performed to study the influence of the molar composition of the starting mixture over zeolites crystallization. The effect of crystallization time for a particular synthesis mixture composition was studied for both zeolites types. The reuse as alkaline medium of the mother liquor separated during filtration, and the effect of the aging before crystallization were additionally studied. The experimental result  are in agreement with the crystallization mechanism proposed for zeolites synthesis in liquid phase. The use of a 2SiO2:Al2O3:6.Na2O:240H2O synthesis mixture composition allows obtaining LTA zeolite within 2h of crystallization. For FAU zeolite, no aging period was needed when starting with a 4SiO2:Al2O3:6.6Na2O:264H2O composition. It was possible to synthesize both zeolites with high purity and crystallinity and with adequate water adsorption properties.

  2. Comparison of the emissions and SFC for 10:1 and 12:1 compression ratio 1.8 litre SI engines using lean mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, G.; Osses, M.; Desai, M.; Haralambidis, E. [Leeds Univ. (United Kingdom); Ounzain, A.; Robertson, G. [Ford Motor Co. Ltd., Dagenham (United Kingdom)

    1996-12-31

    A standard 10:1 compression ratio Ford Zetec engine was modified to a 12:1 compression ratio and investigated over the lean combustion region with a comparison with the base 10:1 compression ratio engine. All the comparisons were carried out at the same power output as for stoichiometric operation, using throttle adjustments to achieve the increased power as the mixture was made leaner. The aim of the higher compression ratio was to increase the power in the lean combustion region and thus to extend the lean burning limit for the same power output. The lean limit was then set as the wide open throttle lean combustion for a desired power output. The power outputs studied were 10 and 15KW at 1500 r/min, which is typical of the low power urban drive cycle in the EC emissions test cycle. Additional reductions in NOx using spark timing control was also investigated for lean mixtures. The lean burning capability at different conditions was investigated at the minimum fuel consumption spark timing and at 5% above the minimum SFC, but still below the SFC for stoichiometric operation. The borderline detonation limit (BLDL) as detected using a cylinder pressure transducer and spark timing loops were limited by the BLDL timing. The higher compression ratio was shown to extend the lean burning limit from 22/1 to 26/1 at constant 10KW power output. This was accompanied by an increase by NOx, hydrocarbons and CO. The extended lean limit was not effectively useable at 10 KW power due to the large increase in hydrocarbons for mixtures leaner than 22/1. Thus the lower NOx emissions in this region could not be exploited and there was little advantage, from a lean combustion viewpoint, of operation at 12/1 compression ratio. However, at the 15KW power output condition there were clear SFC advantages and smaller NOx reductions for the higher CR lean burn engine. (author)

  3. Very high or close to zero thermal expansion by the variation of the Sr/Ba ratio in Ba(1-x)Sr(x)Zn2Si2O7- solid solutions.

    Science.gov (United States)

    Thieme, Christian; Rüssel, Christian

    2016-03-21

    The compound BaZn2Si2O7 shows a highly positive coefficient of thermal expansion. At a temperature of 280 °C, it transforms to a high temperature phase, which exhibits a coefficient of thermal expansion near zero. The partial replacement of Ba(2+) against Sr(2+) leads to a decrease of the phase transition temperature. If more than 10% of Ba(2+) are replaced by Sr(2+), the high-temperature phase is completely stable at room temperature and consequently, the thermal expansion is near zero or negative. The effect of the Sr(2+)/Ba(2+)-ratio on the phase transition temperature and the thermal expansion behavior is measured using high-temperature X-ray diffraction up to 1000 °C. The Sr(2+)/Ba(2+)-ratio strongly affects the overall thermal expansion as well as the anisotropy. The latter increases with decreasing Sr-concentration. The strong differences in the thermal expansion behavior between phases with the structure of the low-temperature phase and the high-temperature phase of BaZn2Si2O7 can be explained by a comparison of the ZnO4-chains inside these two crystal structures.

  4. Crystallization of mordenite zeolite with seed addition in reaction mixtures with different SiO{sub 2}/Al{sub 2}O{sub 3} ratios; Cristalizacao da zeolita mordenita com adicao de sementes em meio reacionais com diferentes razoes SiO{sub 2}/Al{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Cysneiros, O.M.S.; Silva, B.J.B.; Silva, A.O.S.; Alencar, S.L.; Santos, R.B.; Soares, P.F.M.; Mendonca, T.R.D.; Sousa Junior, L.V.; Santos, J.R., E-mail: brunojbarros@hotmail.com [Universidade Federal de Alagoas (UFAL), Maceio (Brazil). Departamento de Engenharia Quimica. Laboratorio de Sintese de Catalisadores

    2016-04-15

    The synthesis of samples of mordenite were performed using the hydrothermal method using two different types of crystallization seed (mordenite and ferrierite), where they were exploited to change some parameters of the synthesis, such as SiO{sub 2}/Al{sub 2}O{sub 3} = 20, 60 and 100 and the ratio OH/SiO{sub 2} = 0.2, 0.3 and 0.4, at different times of crystallization, at a temperature of 170 °C. The samples were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA/DTA), nitrogen adsorption at -196 °C (BET) and temperature programmed desorption of ammonia (NH{sub 3}-TPD). It was found that the use of the ratio OH/SiO{sub 2} = 0.4, together with the seeds of the most MOR and FER crystalline samples were obtained, demonstrating the critical role of mineralizing agent OH{sup -} in the middle. (author)

  5. Efficient Si photovoltaic devices with integrated micro/nano holes

    Science.gov (United States)

    Cansizoglu, Hilal; Gao, Yang; Kaya, Ahmet; Ghandiparsi, Soroush; Polat, Kazim G.; Wang, Yichuan; Zhang, Runzhou; Reggad, Hind; Mayet, Ahmed; Ponizovskaya Devine, Ekaterina; Islam, M. Saif

    2016-09-01

    Efficient light harvesting in a thin layer of crystalline Si can be realized by implementing nanoscale pillars and holes to the device structure. The major drawback of the pillars and holes based photovoltaic devices is high surface to volume ratio, contributing to an increase in surface recombination rate of the photo-generated carriers. The common techniques used in pillars/holes fabrication such as dry etching make the surface even worse by bombarding it with high energy ions. Therefore, such damaged surfaces of high aspect ratio structures need to be effectively passivated. In this study, we demonstrate a hole based thin crystalline Si photovoltaic device with enhanced open circuit voltage and short circuit current after a successful surface passivation process through a wet oxidation. In addition, the effect of passivation layer fabricated by rapid thermal oxide growth on photo response is investigated. A successful fabrication of thin crystalline Si solar cells can lead to the applications of ultra-thin, highly efficient, flexible and wearable energy sources.

  6. 氨铜比对蒸氨法Cu/SiO2催化剂活性组分演变及二氧化碳加氢性能的影响%Effect of ammonia-copper ratio on the structural evolution and catalytic activity of Cu/SiO2 catalysts prepared by ammonia evaporation method in CO2 hydrogenation reaction

    Institute of Scientific and Technical Information of China (English)

    李静; 靳博晗; 岳海荣; 应建康

    2016-01-01

    铜催化剂表面铜活性物种的性质与分散度是影响CO2加氢性能的关键因素。以硅溶胶为载体、铜氨络合物为铜源,采用蒸氨法制备了Cu/SiO2催化剂,考察了氨铜比对Cu/SiO2催化剂表面铜活性物种的形成和CO2加氢制甲醇反应性能的影响。通过N2-physisorption、TEM、XRD、IR和BET等技术对催化剂的结构和性质进行了表征。结果显示,铜氨溶液中适当的氨浓度,有利于铜氨配体的形成和蒸氨过程中铜活性组分的均匀分布,有利于层状硅酸铜和氧化铜双活性组分的形成。在反应温度523 K,反应压力2.5 MPa,进气比V(CO2)∶V(H2)∶V(N2)=10∶30∶4,反应空速1800 mLSTP/( g· h)的条件下,氨铜比为4的Cu/SiO2-N4催化剂获得较优CO2加氢催化性能,CO2的转化率31%,CH3 OH的选择性54.8%,CH3 OH的收率17%。%The nature and distribution of surface copper active species on the copper based catalysts are crucial for the catalytic hydrogenation of CO 2 to methanol .Silica supported copper catalyst Cu /SiO2 was pre-pared by ammonia evaporation ( AE) method with different ammonia-copper molar ratio and characterized by N2-physisorption ,TEM,XRD,IR and BET techniques .Performance of the Cu/SiO2 catalysts on the hy-drogenation of CO2 reaction was also evaluated with a feed gas ratio of V(CO2)∶V(H2)∶V(N2)=10∶30∶4 under 523 K,2.5 MPa.The results indicated that the ammonia-copper molar ratio in the AE method exerted profound effects on the copper loading ,texture properties and surface composition of the Cu /SiO2 catalysts. Catalysts with the proper copper loading ,smaller copper particle size ,larger metallic copper surface area and good dispersion of copper species could be obtained by using a proper ammonia -copper molar ratio .The Cu/SiO2-N4 catalyst with an optimal ratio of ammonia to copper of 4 can achieve CO 2 conversion of 31%,CH3 OH selectivity of 54.8%and CH3 OH

  7. Microwave absorption properties of FeSi flaky particles prepared via a ball-milling process

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chao [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Yuan, Yong [Precision Machinery Research Institute of Shanghai Space Flight Academy, Shanghai 201600 (China); Jiang, Jian-tang [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); Gong, Yuan-xun [Aerospace Research Institute of Special Material and Processing Technology, Beijing 100074 (China); Zhen, Liang, E-mail: lzhen@hit.edu.cn [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China); MOE Key Laboratory of Micro-system and Micro-structures Manufacturing, Harbin Institute of Technology, Harbin 150080 (China)

    2015-12-01

    Flaky FeSi alloy particles with different aspect ratio were produced via ball-milling and a subsequent annealing. The microstructure and the morphology of the particles were examined by XRD and SEM. The dc resistivity, the static magnetization properties and electromagnetic properties were measured. Particles with high aspect ratio were found possess high permittivity and permeability. On the other hand, the variation of grain size and defects density was found influence the permittivity and permeability. High specific area was believed contribute to the intense dielectric loss and the high shape magnetic anisotropy lead to high permeability in the target band. Increased electromagnetic parameters compel the absorption peak’s shift to lower frequency. Coating using flaky FeSi particles milled for 12 h as fillers presented a reflection loss of −10 dB at 2 GHz and a matching thickness of 1.88 mm. The flaky FeSi alloy particles prepared through ball-milling and annealing can be promising candidates for EMA application at 1–4 GHz band. - Highlights: • Large quantity of flakey FeSi particles were produced through a simple way. • Coatings with as-milled FeSi particles exhibit excellent EMA performance in L-S band. • Shape and size of particles can be controlled via adjusting the ball-milling time. • Shape/size along with the microstructure influence the electromagnetic properties. • Shape/size contribute more to the excellent EMA performance compared to microstructure.

  8. Effects of Si/Al Ratio on Cu/SSZ-13 NH3-SCR Catalysts: Implications for the active Cu species and the Roles of Brønsted Acidity

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Feng; Washton, Nancy M.; Wang, Yilin; Kollar, Marton; Szanyi, Janos; Peden, Charles HF

    2015-09-03

    Cu/SSZ-13 catalysts with three Si/Al ratios of 6, 12 and 35 were synthesized with Cu incorporation via solution ion exchange. The implications of varying Si/Al ratios on the nature of the multiple Cu species that can be present in the SSZ-13 zeolite are a major focus of this work, as highlighted by the results of a variety of catalyst characterization and reaction kinetics measurements. Specifically, catalysts were characterized with surface area/pore volume measurements, temperature programmed reduction by H2 (H2-TPR), NH3 temperature programmed desorption (NH3-TPD), and DRIFTS and solid-state nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties were examined using NO oxidation, ammonia oxidation, and standard ammonia selective catalytic reduction (NH3-SCR) reactions on selected catalysts under differential conditions. Besides indicating possible variably active multiple Cu species for these reactions, the measurements are also used to untangle some of the complexities caused by the interplay between redox of Cu ion centers and Brønsted acidity. All three reactions appear to follow a redox reaction mechanism, yet the roles of Brønsted acidity are quite different. For NO oxidation, increasing Si/Al ratio lowers Cu redox barriers, thus enhancing reaction rates. Brønsted acidity appears to play essentially no role for this reaction. For standard NH3-SCR, residual Brønsted acidity plays a significant beneficial role at both low- and high-temperature regimes. For NH3 oxidation, no clear trend is observed suggesting both Cu ion center redox and Brønsted acidity play important and perhaps competing roles. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed in the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of

  9. High Density of Aligned Nanowire Treated with Polydopamine for Efficient Gene Silencing by siRNA According to Cell Membrane Perturbation.

    Science.gov (United States)

    Nair, Baiju G; Hagiwara, Kyoji; Ueda, Motoki; Yu, Hsiao-Hua; Tseng, Hsian-Rong; Ito, Yoshihiro

    2016-07-27

    High aspect ratio nanomaterials, such as vertically aligned silicon nanowire (SiNW) substrates, are three-dimensional topological features for cell manipulations. A high density of SiNWs significantly affects not only cell adhesion and proliferation but also the delivery of biomolecules to cells. Here, we used polydopamine (PD) that simply formed a thin coating on various material surfaces by the action of dopamine as a bioinspired approach. The PD coating not only enhanced cell adhesion, spreading, and growth but also anchored more siRNA by adsorption and provided more surface concentration for substrate-mediated delivery. By comparing plain and SiNW surfaces with the same amount of loaded siRNA, we quantitatively found that PD coating efficiently anchored siRNA on the surface, which knocked down the expression of a specific gene by RNA interference. It was also found that the interaction of SiNWs with the cell membrane perturbed the lateral diffusion of lipids in the membrane by fluorescence recovery after photobleaching. The perturbation was considered to induce the effective delivery of siRNA into cells and allow the cells to carry out their biological functions. These results suggest promising applications of PD-coated, high-density SiNWs as simple, fast, and versatile platforms for transmembrane delivery of biomolecules.

  10. High Aspect Pattern Formation by Integration of Micro Inkjetting and Electroless Plating

    CERN Document Server

    Gian, P W; Liang, Y N; Lok, B K; Lu, C W; Ooi, B L

    2008-01-01

    This paper reports on formation of high aspect micro patterns on low temperature co-fired ceramic (LTCC) substrates by integrating micro inkjetting with electroless plating. Micro inkjetting was realized by using an inkjetting printer that ejects ink droplets from a printhead. This printhead consists of a glass nozzle with a diameter of 50 micrometers and a piezoelectric transducer that is coated on the nozzle. The silver colloidal solution was inkjetted on a sintered CT800 ceramic substrate, followed by curing at 200 degrees C for 60 minutes. As a result, the silver trace with a thickness of 200 nm was obtained. The substrate, with the ejected silver thin film as the seed layer, was then immersed into a preinitiator solution to coat a layer of palladium for enhancing the deposition of nickel. Electroless nickel plating was successfully conducted at a rate of 0.39 micrometers /min, and the thickness of traces was plated up to 84 micrometers. This study demonstrates that the integration of inkjetting with plat...

  11. (1)H relaxivity of water in aqueous suspensions of Gd(3+)-loaded NaY nanozeolites and AlTUD-1 mesoporous material: the influence of Si/Al ratio and pore size.

    Science.gov (United States)

    Norek, Małgorzata; Neves, Isabel C; Peters, Joop A

    2007-07-23

    The results of a (1)H nuclear magnetic relaxation dispersion (NMRD) and EPR study on aqueous suspensions of Gd(3+)-loaded NaY nanozeolites and AlTUD-1 mesoporous material are described. Upon increase of the Si/Al ratio from 1.7 to 4.0 in the Gd(3+)-loaded zeolites, the relaxation rate per mM Gd(3+) (r1) at 40 MHz and 25 degrees C increases from 14 to 27 s(-)1 mM(-1). The NMRD and EPR data were fitted with a previously developed two-step model that considers the system as a concentrated aqueous solution of Gd(3+) in the interior of the zeolite that is in exchange with the bulk water outside the zeolite. The results show that the observed increase in relaxivity can mainly be attributed to the residence lifetime of the water protons in the interior of the material, which decreased from 0.3 to 0.2 micros, upon the increase of the Si/Al ratio. This can be explained by the decreased interaction of water with the zeolite walls as a result of the increased hydrophobicity. The importance of the exchange rate of water between the inside and the outside of the material was further demonstrated by the relatively high relaxivity (33 s(-1) mM(-1) at 40 MHz, 25 degrees C) observed for a suspension of the Gd(3+)-loaded mesoporous material AlTUD-1. Unfortunately, Gd(3+) leaches rather easily from that material, but not from the Gd(3+)-loaded NaY zeolites, which may have potential as contrast agents for magnetic resonance imaging.

  12. Determining solute inputs to soil and stream waters in a seasonally snow-covered mountain catchment in northern New Mexico using Ge/Si and 87Sr/86Sr ratios

    Science.gov (United States)

    Porter, C. M.; McIntosh, J. C.; Derry, L. A.; Meixner, T.; Chorover, J.; Rasmussen, C.; Brooks, P. D.; Perdrial, J. N.

    2011-12-01

    The critical zone is the environment near the Earth's surface in which biological, chemical, and physical processes interact and contribute to the evolution and structure of life on Earth. Mineral dissolution is an important process in the critical zone that supplies essential nutrients, to the biotic foundation of ecosystems. Stream chemical composition reflects the supply through mineral weathering and the loss of these elements through hydrologic transport. This study aims to determine the influence of mineral weathering on stream and soil water composition in a seasonally snow-covered headwater catchment in the Jemez Mountains in northern New Mexico by using a multi-tracer approach including major cations, strontium isotopes, germanium (Ge)/silica (Si) ratios and trace metals. Potential solute sources to stream waters include snowmelt, atmospheric wet and dry deposition, groundwaters and soil waters influenced by mineral weathering. Preliminary base cation, dissolved inorganic carbon (DIC), and dissolved organic carbon (DOC) results show that groundwater dominates stream water composition except during snowmelt in April and May. Furthermore, stream waters are enriched in base cations compared to snowmelt discharge and shallow soil waters suggesting contributions of solutes from mineral weathering along deeper subsurface flowpaths. Dilution trends of base cation concentrations are not observed during snowmelt, however high DOC and low DIC concentrations are present in stream waters indicating shallow soil flushing. Soil solid phase chemistry data shows soils are depleted in Ca, relative to Na, and K whereas stream waters are enriched in Ca, relative to Na, and K, which may be indicative of plagioclase or calcite weathering. Soils deeper in the soil profile are depleted in Ge relative to Si, whereas shallow soils are enriched in Ge. Therefore we hypothesize that shallow soil flushing during snowmelt periods will lead to elevated Ge/Si ratios in stream waters. In

  13. Controlling the Geometries of Si Nanowires through Tunable Nanosphere Lithography.

    Science.gov (United States)

    Li, Luping; Fang, Yin; Xu, Cheng; Zhao, Yang; Wu, Kedi; Limburg, Connor; Jiang, Peng; Ziegler, Kirk J

    2017-02-14

    A tunable nanosphere lithography (NSL) technique is combined with metal-assisted etching of silicon (Si) to fabricate ordered, high-aspect-ratio Si nanowires. Non-close-packed structures are directly prepared via shear-induced ordering of the nanospheres. The spacing between the nanospheres is independent of their diameters and tuned by changing the loading of nanospheres. Nanowires with spacings between 110 and 850 nm are easily achieved with diameters between 100 and 550 nm. By eliminating plasma or heat treatment of the nanospheres, the diameter of the nanowires fabricated is nearly identical to the nanosphere diameter in the suspension. The elimination of this step helps avoid common drawbacks of traditional NSL approaches, leading to the high-fidelity, large-scale fabrication of highly crystalline, nonporous Si nanowires in ordered hexagonal patterns. The ability to simultaneously control the diameter and spacing makes the NSL technique more versatile and expands the range of geometries that can be fabricated by top-down approaches.

  14. Wavelength-sized cavities in high aspect InP/InGaAsP/InP photonic crystals

    NARCIS (Netherlands)

    Kicken, H.H.J.E.; Barbu, I.; Van der Heijden, R.W.; Karouta, F.; Nötzel, R.; Van der Drift, E.; Salemink, H.W.M.

    2009-01-01

    The photonic properties of two classes of wavelength-sized cavities are reported for deeply etched InP/InGaAsP/InP planar photonic crystals. The high aspect, deeply etched structures are studied as potential building blocks for nonmembrane type photonic devices in standard InP photonic integrated ci

  15. 硅/钴摩尔比对MCM-48介孔分子筛结构性能的影响%Effects of Si/Co Molar Ratios on Textural Property of MCM-48 Mesoporous Molecular Sieve

    Institute of Scientific and Technical Information of China (English)

    周旭平; 赵谦; 吴多林; 纪美茹; 姜廷顺

    2011-01-01

    Using tetraethyl orthosilicate (TEOS) as silica source, cetyltrimethyl ammonium bromide (CTAB) as a template and sodium fluoride as a inorganic salt additive, cobalt-incorporated MCM-48 mesoporous materials (Co-MCM-48) were synthesized by the hydrothermal method. Effects of different molar ratios n(Si):n(Co) in synthesis gel on textural property of the MCM-48 mesoporous materials were investigated. The changes in textural properties were evaluated by the X-ray diffraction (XRD), transmission electron microscopy, Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible speetrophotometry (UV-Vis), temperature programmed reduction (TPR), and N2 physical adsorption. Results show that when n(Si):n(Co)=25, the as-synthesized Co-MCM-48 still exhibits a cubic mesoporous framework and has a high specific surface area (1 002.9 m2/g). Characterization by the FTIR, UV-Vis and TPR suggests that cobalt is incorporated into framework of the MCM-48. Specific surface area and pore volume of the synthesized Co-MCM-48 sample gradually decrease with the increase of cobalt content in the synthesis gel; pore size gradually increases and mesoporous ordering begins to deteriorate.%以正硅酸乙酯为硅源、十六烷基三甲基溴化铵为模板、氟化钠为添加剂,水热合成钴掺杂的介孔分子筛(cobalt-containing mesoporous molecular sieve,Co-MCM-48),同时研究合成溶胶中不同摩尔比m(Si):n(Co)对MCM-48介孔材料结构性能的影响.通过X射线粉末衍射、N2吸附-脱附、透射电子显微镜、Fourier变换红外光谱(Fourier transform infrared spectroscopy,FTIR)、紫外-可见光谱(ultraviolet-visible spectrpotometry,UV-Vis)、程序升温还原(temperature programmed reduction,TPR)等方法表征分析样品的结构和性能.结果表明:合成溶胶中n(Si):n(Co)=25时,所得Co-MCM-48仍具有立方介孔结构和较高的比表面积(1 002.9m2/g).FTIR谱、UV-Vis谱及TPR测试等证实:Co已经嵌入MCM-48骨架中,随着

  16. Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios

    DEFF Research Database (Denmark)

    Giordanino, Filippo; Vennestrøm, Peter N. R.; Lundegaard, Lars Fahl

    2013-01-01

    revealed the presence of different Cu2+ species. New data and discussion are devoted to (i) [Cu–OH]+ species likely balanced by one framework Al atom; (ii) mono(μ-oxo)dicopper [Cu2(μ-O)]2+ dimers observed in Cu-ZSM-5 and Cu-β, but not in Cu-SSZ-13. UV-Vis-NIR spectra of O2 activated samples reveal......Cu-SSZ-13 has been characterized by different spectroscopic techniques and compared with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios and prepared by the same ion exchange procedure. On vacuum activated samples, low temperature FTIR spectroscopy allowed us to appreciate a high...... concentration of reduced copper centres, i.e. isolated Cu+ ions located in different environments, able to form Cu+(N2), Cu+(CO)n (n = 1, 2, 3), and Cu+(NO)n (n = 1, 2) upon interaction with N2, CO and NO probe molecules, respectively. Low temperature FTIR, DRUV-Vis and EPR analysis on O2 activated samples...

  17. Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios.

    Science.gov (United States)

    Giordanino, Filippo; Vennestrøm, Peter N R; Lundegaard, Lars F; Stappen, Frederick N; Mossin, Susanne; Beato, Pablo; Bordiga, Silvia; Lamberti, Carlo

    2013-09-21

    Cu-SSZ-13 has been characterized by different spectroscopic techniques and compared with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios and prepared by the same ion exchange procedure. On vacuum activated samples, low temperature FTIR spectroscopy allowed us to appreciate a high concentration of reduced copper centres, i.e. isolated Cu(+) ions located in different environments, able to form Cu(+)(N2), Cu(+)(CO)n (n = 1, 2, 3), and Cu(+)(NO)n (n = 1, 2) upon interaction with N2, CO and NO probe molecules, respectively. Low temperature FTIR, DRUV-Vis and EPR analysis on O2 activated samples revealed the presence of different Cu(2+) species. New data and discussion are devoted to (i) [Cu-OH](+) species likely balanced by one framework Al atom; (ii) mono(μ-oxo)dicopper [Cu2(μ-O)](2+) dimers observed in Cu-ZSM-5 and Cu-β, but not in Cu-SSZ-13. UV-Vis-NIR spectra of O2 activated samples reveal an intense and finely structured d-d quadruplet, unique to Cu-SSZ-13, which is persistent under SCR conditions. This differs from the 22,700 cm(-1) band of the mono(μ-oxo)dicopper species of the O2 activated Cu-ZSM-5, which disappears under SCR conditions. The EPR signal intensity sets Cu-β apart from the others.

  18. Variable Deflection Response of Sensitive CNT-on-Fiber Artificial Hair Sensors from CNT Synthesis in High Aspect Ratio Microcavities (Postprint)

    Science.gov (United States)

    2015-04-01

    microstructures such as tailored hair shapes, micro-antennae, brushes, or filters . The CNT arrays are synthesized in a 1” diameter quartz tube furnace...Microstructure Growth,” ACS Nano, 8(6), 5799-5812 (2014). [17] P. B. Amama, C. L. Pint, L. McJilton et al., “Role of Water in Super Growth of Single...Garcia et al., “High-yield growth and morphology control of aligned carbon nanotubes on ceramic fibers for multifunctional enhancement of structural

  19. Technological and material related challenges for large area, high aspect-ratio, near teradot/inch2 areal density and three-dimensional structuring of polyaniline.

    Science.gov (United States)

    Jedrasik, Piotr; Vlad, Alexandru; Södervall, Ulf

    2011-10-01

    In this manuscript we report on a newly developed technology for the nanoscale processing of the conducting polyaniline (PANI) with an unprecedented areal patterning order and density control exceeding 0.25 teradot/inch2. High resolution electron beam lithography was used to generate ordered 2D and 3D templates. A novel type of resist and dose-modulated 3D-electron beam lithography (RDM-3D-EBL), extensively exploiting the intrinsic properties of resist-electron beam interaction is detailed. Surface initiated and template confined aniline polymerization, through catalytic activity of metallic platinum, was then exploited to provide a genuine method for controlled nanoscale processing of polyaniline, a prototypical conjugated polymer that definitively settled the concept of synthetic metals. Using nanoscale polymerization reactors, ultimate resolution patterning and processing control of single polyaniline nanostructures was feasible. Aspects of the nanoscale polyaniline growth mechanism are discussed and the highly controllable, sub-picogram scale fabrication is emphasized. Near teradot/inch2 pattern transfer technology, complex 3D structuring and physico-chemical functionalization of polyaniline can be subsequently harnessed to build a large variety of architectures with potential for emerging optoelectronic technologies. The method is scalable, can be applied on virtually any type of flexible or rigid substrates and provides a generic approach for nanopatterning surfaces with functional polymers. Technological and material related fabrication challenges are detailed and discussed.

  20. Catalytic Synthesis of Substrate-Free, Aligned and Tailored High Aspect Ratio Multiwall Carbon Nanotubes in an Ultrasonic Atomization Head CVD Reactor

    OpenAIRE

    Fahad Ali Rabbani; Zuhair Omar Malaibari; Muataz Ali Atieh; Ammar Jamie

    2016-01-01

    Chemical vapor deposition (CVD) method has proven its benchmark, over other methods, for the production of different types of carbon nanotubes (CNT) on commercial and lab scale. In this study, an injection vertical CVD reactor fitted with an ultrasonic atomization head was used in a pilot-plant scale (height 274 cm, radius 25 cm) for semicontinuous production of multiwall carbon nanotubes (MWCNTs). p-Xylene was used as a hydrocarbon precursor in which ferrocene was dissolved and provided the ...

  1. Fractionation and Characterization of High Aspect Ratio Gold Nanorods Using Asymmetric-Flow Field Flow Fractionation and Single Particle Inductively Coupled Plasma Mass Spectrometry

    OpenAIRE

    Nguyen, Thao M; Jingyu Liu; Vincent A. Hackley

    2015-01-01

    Gold nanorods (GNRs) are of particular interest for biomedical applications due to their unique size-dependent longitudinal surface plasmon resonance band in the visible to near-infrared. Purified GNRs are essential for the advancement of technologies based on these materials. Used in concert, asymmetric-flow field flow fractionation (A4F) and single particle inductively coupled mass spectrometry (spICP-MS) provide unique advantages for fractionating and analyzing the typically complex mixtur...

  2. Porous, one-dimensional and high aspect ratio nanofibric network of cobalt manganese oxide as a high performance material for aqueous and solid-state supercapacitor (2 V)

    Science.gov (United States)

    Bhagwan, Jai; Sivasankaran, V.; Yadav, K. L.; Sharma, Yogesh

    2016-09-01

    Porous nanofibric network of spinel CoMn2O4 (CMO) are fabricated by facile electrospinning process and characterized by XRD, BET, TGA, FTIR, FESEM, TEM, XPS techniques. CMO nanofibers are employed as supercapacitor electrode for first time which exhibits high specific capacitance (Cs) of 320(±5) F g-1 and 270(±5) F g-1 at 1 A g-1 and 5 A g-1, respectively in 1 M H2SO4. CMO nanofibers exhibit excellent cyclability (till 10,000 cycles @ 5 A g-1). To examine practical performance, solid-state symmetric supercapacitor (SSSC) is also fabricated using PVA-H2SO4 as gel electrolyte. The SSSC evinces high energy density of 75 W h kg-1 (comparable to Pb-acid and Ni-MH battery) along with high power density of 2 kW kg-1. Furthermore, a red colored LED (1.8 V @ current 20 mA) was lit for 5 min using single SSSC device supporting its output voltage of 2 V. This high performance of CMO in both aqueous and SSSC is attributed to one dimensional nanofibers consisting of voids/gaps with minimum inter-particle resistance that facilitates smoother transportation of electrons/ions. These voids/gaps in CMO (structural as well as morphological) act as intercalation/de-intercalation sites for extra storage performance, and also works as buffering space to accommodate stress/strain produced while long term cyclings.

  3. Helimagnetic order in bulk MnSi and CoSi/MnSi superlattices

    Science.gov (United States)

    Loh, G. C.; Khoo, K. H.; Gan, C. K.

    2017-01-01

    Skyrmions are nanoscopic whirls of spins that reside in chiral magnets. It is only fairly recent that a plethora of applications for these quasiparticles emerges, especially in data storage. On the other hand, spin spirals are the periodic analogs of skyrmions, and are equally imperative in the course of exploration to enhance our understanding of helimagnetism. In this study, a new infrastructure based on the B20 compound, MnSi is propounded as a hosting material for spin spirals; alternating thin layers of CoSi and MnSi in the superlattice form provides a facile way of varying the properties of the spin spirals across a continuum. Using first-principles calculations based on full-potential linearized augmented plane-wave (FLAPW)-based density functional theory (DFT), the spin order of bulk MnSi, MnSi film, and the CoSi/MnSi superlattice is investigated. Spin dispersion plots as a function of propagation vectors show that the spiral size changes in the presence of CoSi - we find that the size of the spiral is reduced in the superlattice with thin CoSi layers (CoSi:MnSi=1:1 thickness ratio), whilst at a larger CoSi:MnSi=2:1 thickness ratio, the material behaves as a ferromagnet. In a similar fashion, the spin moment and orbital occupancy depend significantly on the thickness of the CoSi layers. However, the exchange interaction between Mn atoms appears to be generally impervious to the presence of CoSi. Succinctly, the CoSi/MnSi superlattice could be an excellent functional material in data storage applications.

  4. Laser annealing of sputter-deposited -SiC and -SiCN films

    Indian Academy of Sciences (India)

    M A Fraga; M Massi; I C Oliveira; F D Origo; W Miyakawa

    2011-12-01

    This work describes the laser annealing of -SiC and -SiCN films deposited on (100) Si and quartz substrates by RF magnetron sputtering. Two samples of -SiCN thin films were produced under different N2/Ar flow ratios. Rutherford backscattering spectroscopy (RBS), Raman analysis and Fourier transform infrared spectrometry (FTIR) techniques were used to investigate the composition and bonding structure of as-deposited and laser annealed SiC and SiCN films.

  5. Tailoring broadband light trapping of GaAs and Si substrates by self-organised nanopatterning

    Energy Technology Data Exchange (ETDEWEB)

    Martella, C.; Chiappe, D.; Mennucci, C.; Buatier de Mongeot, F. [Dipartimento di Fisica, Università di Genova, via Dodecaneso 33, I-16146 Genova (Italy)

    2014-05-21

    We report on the formation of high aspect ratio anisotropic nanopatterns on crystalline GaAs (100) and Si (100) substrates exploiting defocused Ion Beam Sputtering assisted by a sacrificial self-organised Au stencil mask. The tailored optical properties of the substrates are characterised in terms of total reflectivity and haze by means of integrating sphere measurements as a function of the morphological modification at increasing ion fluence. Refractive index grading from sub-wavelength surface features induces polarisation dependent anti-reflection behaviour in the visible-near infrared (VIS-NIR) range, while light scattering at off-specular angles from larger structures leads to very high values of the haze functions in reflection. The results, obtained for an important class of technologically relevant materials, are appealing in view of photovoltaic and photonic applications aiming at photon harvesting in ultrathin crystalline solar cells.

  6. Realization of optical multimode TSV waveguides for Si-Interposer in 3D-chip-stacks

    Science.gov (United States)

    Killge, S.; Charania, S.; Richter, K.; Neumann, N.; Al-Husseini, Z.; Plettemeier, D.; Bartha, J. W.

    2017-05-01

    Optical connectivity has the potential to outperform copper-based TSVs in terms of bandwidth at the cost of more complexity due to the required electro-optical and opto-electrical conversion. The continuously increasing demand for higher bandwidth pushes the breakeven point for a profitable operation to shorter distances. To integrate an optical communication network in a 3D-chip-stack optical through-silicon vertical VIAs (TSV) are required. While the necessary effort for the electrical/optical and vice versa conversion makes it hard to envision an on-chip optical interconnect, a chip-to-chip optical link appears practicable. In general, the interposer offers the potential advantage to realize electro-optical transceivers on affordable expense by specific, but not necessarily CMOS technology. We investigated the realization and characterization of optical interconnects as a polymer based waveguide in high aspect ratio (HAR) TSVs proved on waferlevel. To guide the optical field inside a TSV as optical-waveguide or fiber, its core has to have a higher refractive index than the surrounding material. Comparing different material / technology options it turned out that thermal grown silicon dioxide (SiO2) is a perfect candidate for the cladding (nSiO2 = 1.4525 at 850 nm). In combination with SiO2 as the adjacent polymer layer, the negative resist SU-8 is very well suited as waveguide material (nSU-8 = 1.56) for the core. Here, we present the fabrication of an optical polymer based multimode waveguide in TSVs proved on waferlevel using SU-8 as core and SiO2 as cladding. The process resulted in a defect-free filling of waveguide TSVs with SU-8 core and SiO2 cladding up to aspect ratio (AR) 20:1 and losses less than 3 dB.

  7. Etching characteristics and mechanism of SiN(x) films for nano-devices in CH2F2/O2/Ar inductively coupled plasma: effect of O2 mixing ratio.

    Science.gov (United States)

    Son, Jinyoung; Efremov, Alexander; Yun, Sun Jin; Yeom, Geun Young; Kwonl, Kwang-ho

    2014-12-01

    Etching characteristics and mechanisms of low-temperature SiN(x) thin films for nano-devices in CH2F2/O2/Ar inductively-coupled plasmas were studied. The etching rates of SiN(x) thin films as well as the etching selectivities over Si and photoresist were measured in the range of 25-75% O2 in a feed gas at fixed CH2F2 content (25%), gas pressure (6 mTorr), input power (900 W), bias power (200 W), and total gas flow rate (40 sccm). Plasma parameters were analyzed using the Langmuir probe diagnostics and optical emission spectroscopy. The chemical states of the etched surfaces were examined by the X-ray photoelectron spectroscopy. It was found that the non-monotonic (with a maximum at about 50-60% O2) SiN(x) etching rate does not correlate with monotonically decreasing F atom flux and ion energy flux. It was proposed that, under the given set of experimental conditions, the SiN(x) etching process is also controlled by the O and H atom fluxes through the destruction of the fluorocarbon polymer layer.

  8. Deep reactive ion etching of 4H-SiC via cyclic SF6/O2 segments

    Science.gov (United States)

    Luna, Lunet E.; Tadjer, Marko J.; Anderson, Travis J.; Imhoff, Eugene A.; Hobart, Karl D.; Kub, Fritz J.

    2017-10-01

    Cycles of inductively coupled SF6/O2 plasma with low (9%) and high (90%) oxygen content etch segments are used to produce up to 46.6 µm-deep trenches with 5.5 µm-wide openings in single-crystalline 4H-SiC substrates. The low oxygen content segment serves to etch deep in SiC whereas the high oxygen content segment serves to etch SiC at a slower rate, targeting carbon-rich residues on the surface as the combination of carbon-rich and fluorinated residues impact sidewall profile. The cycles work in concert to etch past 30 µm at an etch rate of ~0.26 µm min-1 near room temperature, while maintaining close to vertical sidewalls, high aspect ratio, and high mask selectivity. In addition, power ramps during the low oxygen content segment is used to produce a 1:1 ratio of mask opening to trench bottom width. The effect of process parameters such as cycle time and backside substrate cooling on etch depth and micromasking of the electroplated nickel etch mask are investigated.

  9. Study of Ni Metallization in Macroporous Si Using Wet Chemistry for Radio Frequency Cross-Talk Isolation in Mixed Signal Integrated Circuits

    Directory of Open Access Journals (Sweden)

    King-Ning Tu

    2011-05-01

    Full Text Available A highly conductive moat or Faraday cage of through-the-wafer thickness in Si substrate was proposed to be effective in shielding electromagnetic interference thereby reducing radio frequency (RF cross-talk in high performance mixed signal integrated circuits. Such a structure was realized by metallization of selected ultra-high-aspect-ratio macroporous regions that were electrochemically etched in p− Si substrates. The metallization process was conducted by means of wet chemistry in an alkaline aqueous solution containing Ni2+ without reducing agent. It is found that at elevated temperature during immersion, Ni2+ was rapidly reduced and deposited into macroporous Si and a conformal metallization of the macropore sidewalls was obtained in a way that the entire porous Si framework was converted to Ni. A conductive moat was as a result incorporated into p− Si substrate. The experimentally measured reduction of crosstalk in this structure is 5~18 dB at frequencies up to 35 GHz.

  10. Characterization and catalysis performance of mesoporous molecular sieve Al- MCM- 41 with different Si/Al ratio%不同硅铝比Al-MCM-41介孔分子筛的表征及催化合成氯乙酸正辛酯

    Institute of Scientific and Technical Information of China (English)

    宋伟明; 董晓娟; 邓启刚; 赵云鹏

    2011-01-01

    以十六烷基三甲基溴化铵( CTAB)为模板剂,正硅酸乙酯(TEOS)为硅源,乙二胺为碱性介质,当n(TEOS)∶n( NaAl02)∶n(CTAB)∶n(H2NCH2CH2NH2)∶n(H2O)=1∶x∶0.12∶ 3.5∶130,其中x=0.1,0.033,0.02,0.01,0.006 7时,水热法合成了Al - MCM - 41介孔分子筛.通过XRD,N2吸附-脱附,NH3 - TPD和TEM等手段对不同硅铝比(n(Si)/n(Al))的Al - MCM -41介孔分子筛进行了表征.结果表明,当n(Si)/n( Al)由150减小至30时,Al - MCM -41介孔分子筛仍具有典型的六方介孔结构特征,但当n( Si)/n(Al)=10时,样品结构有序性下降.Al - MCM - 41介孔分子筛酸量随着n( Si)/n( Al)减小而增大.将Al - MCM - 41介孔分子筛用于催化合成氯乙酸正辛酯,相同反应条件下,n( Si) /n( Al) =30的Al - MCM - 41介孔分子筛为催化剂时酯化率最高,由此表明,Al - MCM - 41介孔分子筛作为催化剂,反应酯化率不仅取决于样品酸量,也与其晶体结构相关.当Al - MCM - 41介孔分子筛用量为氯乙酸质量的3%,反应温度为120~140℃,n(氯乙酸)∶n(正辛醇)=1∶1.2时,酯化率可达94.34%.%Mesoporous molecular sieve MCM -41 containing Si and Al with Si/Al molar ratio equal to 10,30, 50,100 and 150 were synthesized under hydrothermal conditions using cetyltrimethylammonium bromide (CTAB) as template and tetraethylorthosilicate (TEOS) as silica source and ethylenediamine as alkaline medium. The optimum molar ratio was n(TEOS): n{ NaA102) : n( CTAB) : n( H2NCH2CH2NH2): n( H20) = 1: x: 0. 12: 3. 5: 130, where x = 0. 1,0. 033 ,0. 02,0. 01 and 0. 006 7 respectively. The structure and physical and chemical surface properties of the samples were characterized by XRD, N2 adsorption - desorption, NH3 -TPD,TEM,et al. The results indicated that when Si/Al molar ratio of the samples drops from 150 to 30,the mesoporous molecular sieve MCM - 41 keeps its characteristics of typical hexagonal mesoporous structure. However,as the Si/Al molar ratio declines further to 10, the ordered

  11. Fabrication and characteristics of the nc-Si/c-Si heterojunction MAGFET

    Institute of Scientific and Technical Information of China (English)

    Zhao Xiaofeng; Wen Dianzhong

    2009-01-01

    A MAGFET using an nc-Si/c-Si heterojunction as source and drain was fabricated by CMOS technology, using two ohm-contact electrodes as Hall outputs on double sides of the channel situated 0.7L from the source. The experimental results show that when V_(DS) = -7.0 V, the magnetic sensitivity of the single nc-Si/c-Si heterojunction magnetic metal oxide semiconductor field effect transistor (MAGFET) with an L : W ratio of 2 : 1 is 21.26 mV/T,and that with an L : W ratio of 4 : 1 is 13.88 mV/T. When the outputs of double nc-Si/c-Si heterojunction MAGFETs with an L : W ratio of 4 : 1 are in series, their magnetic sensitivity is 22.74 mV/T, which is an improvement of about 64% compared with that of a single nc-Si/c-Si heterojunction MAGFET.

  12. 不同Si/Al的氢型分子筛催化热解对生物油特性的影响%Effect of HZSM-5 catalyst with different Si/Al ratios on characterization of pyrolysis bio-oil

    Institute of Scientific and Technical Information of China (English)

    李攀; 王贤华; 邵敬爱; 杨海平; 陈汉平

    2014-01-01

    -oil occured, the moisture content of the bio-oil continued to go up, while the content of oxygen-containing compounds and acid aldehydes, esters, ketones, furans further reduced, promoting the formation of hydrocarbons, phenols, alcohols, the maximum percentage of the peak area could be up to 12.57% and 39.36%. Because HZSM-5 zeolite help to provide rich aperture on the surface, which was conducive to the formation of positive carbon ions, then the products of the first thermal decomposition carried on isomerization, cracking formation to convert as small molecules alkanes and alkenes, then go through polymerization reaction, cyclization reaction and a series of reactions to generate aromatic substances and so on. Owing to the above reaction procedure, there was a greater overall increasing in hydrocarbon substances. After the addition ratio was greater than 10%, the changing rate of various components decreased. Comprehensive analysis results of the type and amount of added catalyst showed that HZSM-5 (25) zeolite with the addition ratio of 10% played a more significant role on the catalytic liquefaction control of wood dust.%为考察对于氢型分子筛(HZSM-5)的Si/Al变化和添加量对生物质热解液化的影响,该文通过离子交换法制备HZSM-5催化剂,采用激光粒度分析仪、比表面积及孔径分析仪和X射线衍射仪对催化剂的粒度、孔隙及晶体结构等性质进行表征,并在最佳油产率温度下进行木屑的催化热解。对无催化剂和不同催化条件下得到的生物油进行气相色谱质谱联用分析,结果表明,分子筛作用下,生物油产率明显降低(最大降幅8%),含水率增加。同时,液体产物中醛类、酯类、酮类、呋喃等含氧化合物及酸含量均有所降低,提高了烃类和酚类的含量,峰面积百分比最高达到12.57%和39.36%,对催化剂催化调控改善生物油品质提供了一定的科学依据。

  13. Magnetron-sputter epitaxy of {beta}-FeSi{sub 2}(220)/Si(111) and {beta}-FeSi{sub 2}(431)/Si(001) thin films at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Liu Hongfei; Tan Chengcheh; Chi Dongzhi [Institute of Materials Research and Engineering (IMRE), A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

    2012-07-15

    {beta}-FeSi{sub 2} thin films have been grown on Si(111) and Si(001) substrates by magnetron-sputter epitaxy at 700 Degree-Sign C. On Si(111), the growth is consistent with the commonly observed orientation of [001]{beta}-FeSi{sub 2}(220)//[1-10]Si(111) having three variants, in-plane rotated 120 Degree-Sign with respect to one another. However, on Si(001), under the same growth conditions, the growth is dominated by [-111]{beta}-FeSi{sub 2}(431)//[110]Si(001) with four variants, which is hitherto unknown for growing {beta}-FeSi{sub 2}. Photoelectron spectra reveal negligible differences in the valance-band and Fe2p core-level between {beta}-FeSi{sub 2} grown on Si(111) and Si(001) but an apparent increased Si-oxidization on the surface of {beta}-FeSi{sub 2}/Si(001). This phenomenon is discussed and attributed to the Si-surface termination effect, which also suggests that the Si/Fe ratio on the surface of {beta}-FeSi{sub 2}(431)/Si(001) is larger than that on the surface of {beta}-FeSi{sub 2}(220)/Si(111).

  14. Uniform Silicon Isotope Ratios Across the Milky Way Galaxy

    Science.gov (United States)

    Monson, Nathaniel N.; Morris, Mark R.; Young, Edward D.

    2017-04-01

    We report the relative abundances of the three stable isotopes of silicon, 28Si, 29Si, and 30Si, across the Galaxy using the v=0,J=1\\to 0 transition of silicon monoxide. The chosen sources represent a range in Galactocentric radii ({R}{GC}) from 0 to 9.8 kpc. The high spectral resolution and sensitivity afforded by the Green Bank Telescope permit isotope ratios to be corrected for optical depths. The optical-depth-corrected data indicate that the secondary-to-primary silicon isotope ratios {}29{Si}{/}28{Si} and {}30{Si}{/}28{Si} vary much less than predicted on the basis of other stable isotope ratio gradients across the Galaxy. Indeed, there is no detectable variation in Si isotope ratios with {R}{GC}. This lack of an isotope ratio gradient stands in stark contrast to the monotonically decreasing trend with {R}{GC} exhibited by published secondary-to-primary oxygen isotope ratios. These results, when considered in the context of the expectations for chemical evolution, suggest that the reported oxygen isotope ratio trends, and perhaps those for carbon as well, require further investigation. The methods developed in this study for SiO isotopologue ratio measurements are equally applicable to Galactic oxygen, carbon, and nitrogen isotope ratio measurements, and should prove useful for future observations of these isotope systems.

  15. Low dark current and high speed ZnO metal–semiconductor–metal photodetector on SiO{sub 2}/Si substrate

    Energy Technology Data Exchange (ETDEWEB)

    Çalışkan, Deniz, E-mail: dcaliskan@fen.bilkent.edu.tr [Nanotechnology Research Center, Bilkent University, 06800 Bilkent, Ankara (Turkey); Department of Nanotechnology and Nanomedicine, Hacettepe University, 06800 Beytepe, Ankara (Turkey); Bütün, Bayram; Çakır, M. Cihan [Nanotechnology Research Center, Bilkent University, 06800 Bilkent, Ankara (Turkey); Özcan, Şadan [Department of Physics Engineering, Hacettepe University, 06800 Beytepe, Ankara (Turkey); Özbay, Ekmel [Nanotechnology Research Center, Bilkent University, 06800 Bilkent, Ankara (Turkey); Department of Electrical and Electronics Engineering and Department of Physics, Bilkent University, 06800 Bilkent, Ankara (Turkey)

    2014-10-20

    ZnO thin films are deposited by radio-frequency magnetron sputtering on thermally grown SiO{sub 2} on Si substrates. Pt/Au contacts are fabricated by standard photolithography and lift-off in order to form a metal-semiconductor-metal (MSM) photodetector. The dark current of the photodetector is measured as 1 pA at 100 V bias, corresponding to 100 pA/cm{sup 2} current density. Spectral photoresponse measurement showed the usual spectral behavior and 0.35 A/W responsivity at a 100 V bias. The rise and fall times for the photocurrent are measured as 22 ps and 8 ns, respectively, which are the lowest values to date. Scanning electron microscope image shows high aspect ratio and dense grains indicating high surface area. Low dark current density and high speed response are attributed to high number of recombination centers due to film morphology, deducing from photoluminescence measurements. These results show that as deposited ZnO thin film MSM photodetectors can be used for the applications needed for low light level detection and fast operation.

  16. Range imaging pulsed laser sensor with two-dimensional scanning of transmitted beam and scanless receiver using high-aspect avalanche photodiode array for eye-safe wavelength

    Science.gov (United States)

    Tsuji, Hidenobu; Imaki, Masaharu; Kotake, Nobuki; Hirai, Akihito; Nakaji, Masaharu; Kameyama, Shumpei

    2017-03-01

    We demonstrate a range imaging pulsed laser sensor with two-dimensional scanning of a transmitted beam and a scanless receiver using a high-aspect avalanche photodiode (APD) array for the eye-safe wavelength. The system achieves a high frame rate and long-range imaging with a relatively simple sensor configuration. We developed a high-aspect APD array for the wavelength of 1.5 μm, a receiver integrated circuit, and a range and intensity detector. By combining these devices, we realized 160×120 pixels range imaging with a frame rate of 8 Hz at a distance of about 50 m.

  17. Preparation of NaP Zeolite with Low Si/Al Molar Ratio from Flying Ash%利用粉煤灰合成低硅铝比NaP分子筛

    Institute of Scientific and Technical Information of China (English)

    陈彦广; 解骢浩; 韩洪晶; 赵法军; 王宝辉

    2015-01-01

    以粉煤灰分级处理获得的硅铝组分Na2 SiO3和NaAlO2为原料,通过水热反应制备了NaP型分子筛.考察了钠盐不同阴离子和有机空间位阻剂对NaP分子筛制备的影响,优化了水热合成NaP分子筛的工艺参数,采用X射线衍射( XRD)、扫描电子显微镜( SEM)和BET方程对NaP分子筛产品的晶型、形貌和孔容进行分析表征,对NaP分子筛吸附水溶液中Ni2+的性能进行了评价.结果表明,合成NaP分子筛的最佳原料摩尔比为n(Na2O):n(SiO2):n(Al2O3):n(H2O)=3.23:1.95:1:226,反应温度为120℃,晶化时间为8 h.当钠盐中阴离子为Br-时,可增大 P型分子筛产率并提高其纯度.添加有机空间位阻剂三乙醇胺( TEA )[n(TEA):n(Al2O3)=1:1]时,合成的P型分子筛粒径较小且具有较大的孔容,此时对应的Ni2+去除率较高,可达96.2%.%Taking Na2 SiO3 and NaAlO2 obtained from flying ash by staged treatment as raw material, NaP zeo-lite was prepared via hydrothermal method. The influences of organic steric agents and sodium salts with differ-ent anions on the preparation of NaP zeolite were investigated. The synthetic parameters of the hydrothermal system for NaP zeolite were optimized. The crystal form, morphology and pore volume of the NaP zeolite were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM) and Brunauer-Emmett-Teller ( BET ) surface analysis, respectively. The adsorption performance of the NaP zeolite in Ni2+-containing solution was evaluated. The results show that the optimal parameters for the preparation NaP zeolite are as following:n(Na2O) : n(SiO2) : n(Al2O3) : n(H2O)= 1.66:1:0.51:116, the reaction temperature is 120 ℃, crystalization time is 8 h. Br- is in favor of improving the purity and increasing the yield of NaP zeolite. With the addition of triethylolamine( TEA) , the grain size of NaP zeolite becomes smaller and the pore volume is enlarged. The maximum removal rate for Ni2+ is about 96.2%.

  18. Fabrication and Mechanical Properties of SiCw(p/SiC-Si Composites by Liquid Si Infiltration using Pyrolysed Rice Husks and SiC Powders as Precursors

    Directory of Open Access Journals (Sweden)

    Dan Zhu

    2014-03-01

    Full Text Available Dense silicon carbide (SiC matrix composites with SiC whiskers and particles as reinforcement were prepared by infiltrating molten Si at 1550 °C into porous preforms composed of pyrolysed rice husks (RHs and extra added SiC powder in different ratios. The Vickers hardness of the composites showed an increase from 18.6 to 21.3 GPa when the amount of SiC added in the preforms was 20% (w/w, and then decreased to 17.3 GPa with the increase of SiC added in the preforms up to 80% (w/w. The values of flexural strength of the composites initially decreased when 20% (w/w SiC was added in the preform and then increased to 587 MPa when the SiC concentration reached 80% (w/w. The refinement of SiC particle sizes and the improvement of the microstructure in particle distribution of the composites due to the addition of external SiC played an effective role in improving the mechanical properties of the composites.

  19. Enhancing the oxidation resistance of graphite by applying an SiC coat with crack healing at an elevated temperature

    Science.gov (United States)

    Park, Jae-Won; Kim, Eung-Seon; Kim, Jae-Un; Kim, Yootaek; Windes, William E.

    2016-08-01

    The potential of reducing the oxidation of the supporting graphite components during normal and/or accident conditions in the Very High Temperature Reactor (VHTR) design has been studied. In this work efforts have been made to slow the oxidation process of the graphite with a thin SiC coating (∼ 10 μm). Upon heating at ≥ 1173 K in air, the spallations and cracks were formed in the dense columnar structured SiC coating layer grown on the graphite with a functionally gradient electron beam physical vapor deposition (EB-PVD. In accordance with the formations of these defects, the sample was vigorously oxidized, leaving only the SiC coating layer. Then, efforts were made to heal the surface defects using additional EB-PVD with ion beam bombardment and chemical vapor deposition (CVD). The EB-PVD did not effectively heal the cracks. But, the CVD was more appropriate for crack healing, likely due to its excellent crack line filling capability with a high density and high aspect ratio. It took ∼ 34 min for the 20% weight loss of the CVD crack healed sample in the oxidation test with annealing at 1173 K, while it took ∼ 8 min for the EB-PVD coated sample, which means it took ∼4 times longer at 1173 K for the same weight reduction in this experimental set-up.

  20. Growth of single-crystal columns of CoSi2 embedded in epitaxial Si on Si(111) by molecular beam epitaxy

    Science.gov (United States)

    Fathauer, R. W.; Nieh, C. W.; Xiao, Q. F.; Hashimoto, Shin

    1989-01-01

    The codeposition of Si and Co on a heated Si(111) substrate is found to result in epitaxial columns of CoSi2 if the Si:Co ratio is greater than approximately 3:1. These columns are surrounded by an Si matrix which shows bulk-like crystalline quality based on transmission electron microscopy and ion channeling. This phenomenon has been studied as functions of substrate temperature and Si:Co ratio. Samples with columns ranging in average diameter from approximately 25 to 130 nm have been produced.

  1. Minimum bar size for flexure testing of irradiated SiC/SiC composite

    Energy Technology Data Exchange (ETDEWEB)

    Youngblood, G.E.; Jones, R.H. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-03-01

    This report covers material presented at the IEA/Jupiter Joint International Workshop on SiC/SiC Composites for Fusion structural Applications held in conjunction with ICFRM-8, Sendai, Japan, Oct. 23-24, 1997. The minimum bar size for 4-point flexure testing of SiC/SiC composite recommended by PNNL for irradiation effects studies is 30 {times} 6 {times} 2 mm{sup 3} with a span-to-depth ratio of 10/1.

  2. Power reduction and the radial limit of stall delay in revolving wings of different aspect ratio

    NARCIS (Netherlands)

    Kruyt, J.W.; Heijst, Van G.F.; Altshuler, D.L.; Lentink, David

    2015-01-01

    Airplanes and helicopters use high aspect ratio wings to reduce the power required to fly, but must operate at low angle of attack to prevent flow separation and stall. Animals capable of slow sustained flight, such as hummingbirds, have low aspect ratio wings and flap their wings at high angle o

  3. Power reduction and the radial limit of stall delay in revolving wings of different aspect ratio

    NARCIS (Netherlands)

    Kruyt, J.W.; Heijst, Van G.F.; Altshuler, D.L.; Lentink, David

    2015-01-01

    Airplanes and helicopters use high aspect ratio wings to reduce the power required to fly, but must operate at low angle of attack to prevent flow separation and stall. Animals capable of slow sustained flight, such as hummingbirds, have low aspect ratio wings and flap their wings at high angle o

  4. Influence of the permeability of networked primary Si on the ejection of hypereutectic Al-Si melts by centrifugation

    Science.gov (United States)

    Youn, Ji Won; Jeon, Je-Beom; Park, Jin Man; Seo, Seok Yong; Lim, Jeon Taik; Kim, Suk Jun; Kim, Ki Young

    2017-02-01

    The separation of high purity Si for solar cells from Al-Si alloy melt in the mushy zone was investigated using an advanced centrifugal technique. The efficiency of separating Si, based on the weight ratio of separated Si to Si in alloy melt, was maximized by optimizing the permeability of a porous structure of Si (Si foam.) For the optimization of the permeability, two fundamental microstructure variables, size and the solid fraction of primary Si platelets, were controlled by adjusting the Si content in the melts and the rotation start temperature, respectively. The best separation efficiency (48.3% with 3N purity) was achieved when Si content in melt was 24% and the solid fraction was 8.7%. The melt with 23% Si led to a higher separation efficiency (69.8%) for a solid fraction of 10.4%, but Al sandwiched between the Si platelets resulted in a decrease in the purity to 2N.

  5. Anisotropic relaxation behavior of InGaAs/GaAs selectively grown in narrow trenches on (001) Si substrates

    Science.gov (United States)

    Guo, W.; Mols, Y.; Belz, J.; Beyer, A.; Volz, K.; Schulze, A.; Langer, R.; Kunert, B.

    2017-07-01

    Selective area growth of InGaAs inside highly confined trenches on a pre-patterned (001) Si substrate has the potential of achieving a high III-V crystal quality due to high aspect ratio trapping for improved device functionalities in Si microelectronics. If the trench width is in the range of the hetero-layer thickness, the relaxation mechanism of the mismatched III-V layer is no longer isotropic, which has a strong impact on the device fabrication and performance if not controlled well. The hetero-epitaxial nucleation of InxGa1-xAs on Si can be simplified by using a binary nucleation buffer such as GaAs. A pronounced anisotropy in strain release was observed for the growth of InxGa1-xAs on a fully relaxed GaAs buffer with a (001) surface inside 20 and 100 nm wide trenches, exploring the full composition range from GaAs to InAs. Perpendicular to the trench orientation (direction of high confinement), the strain release in InxGa1-xAs is very efficiently caused by elastic relaxation without defect formation, although a small compressive force is still induced by the trench side walls. In contrast, the strain release along the trenches is governed by plastic relaxation once the vertical film thickness has clearly exceeded the critical layer thickness. On the other hand, the monolithic deposition of mismatched InxGa1-xAs directly into a V-shaped trench bottom with {111} Si planes leads instantly to a pronounced nucleation of misfit dislocations along the {111} Si/III-V interfaces. In this case, elastic relaxation no longer plays a role as the strain release is ensured by plastic relaxation in both directions. Hence, using a ternary seed layer facilitates the integration of InxGa1-xAs covering the full composition range.

  6. Effect of SiO2/Al2O3 ratio of Co/ZSM-5 catalyst for tunable Fischer-Tropsch synthesis of gasoline selectivity%不同硅铝比Co/ZSM-5催化剂对费托合成汽油馏分烃选择性的调控

    Institute of Scientific and Technical Information of China (English)

    葛秋伟; 肖竹钱; 张金建; 张徐; 申东明; 汤顺杰; 杨瑞芹; 计建炳; 毛建卫

    2016-01-01

    以ZSM-5分子筛为载体,通过等体积浸渍法制备了Co/ZSM-5系列催化剂,用于费托合成反应一步法制汽油馏分烃(C5~C11烷烃)。考察了不同硅铝比(SiO2/Al2O3=25,38,50,80和200)的ZSM-5分子筛对Co/ZSM-5催化剂费托合成汽油馏分选择性的影响。采用氮气物理吸附-脱附、X射线衍射、氢气程序升温还原(H2-TPR)和氨气程序升温脱附(NH3-TPD)等手段对载体和催化剂进行了表征,并在高压固定床反应器上对催化剂的费托合成催化性能进行了测试。结果表明,对比Co/ZSM-5(SiO2/Al2O3=25,38,50和80)催化剂,Co/ZSM-5(SiO2/Al2O3=200)催化剂表现出最高的汽油馏分烃类选择性,高达52.8%,这主要归功于Co/ZSM-5(SiO2/Al2 O3=200)催化剂上较小钴颗粒尺寸、较优的还原性能以及适量弱酸位的协同作用。分子筛的酸性为催化剂的加氢裂解转化提供活性位,促进重质烃产物发生裂解和异构等二次反应,较小的钴颗粒尺寸和较优的还原性能有利于提高C5+烃选择性。%One-step gasoline synthesis from syngas via Fischer-Tropsch synthesis (FTS)reaction was in-vestigated on Co/ZSM-5 (SiO2/Al2O3 =25,38,50,80 and 200)catalysts.The Co/ZSM-5 catalysts were prepared by impregnation method using cobalt nitrate solution in ZSM-5 with varied SiO2/Al2 O3 ratio and characterized by BET,XRD,H2-TPR and NH3-TPD.The Fischer-Tropsch synthesis activity tests were car-ried out in a fixed-bed reactor.The results showed that the Co/ZSM-5 (SiO2/Al2 O3 =200)was found to be superior to the other Co/ZSM-5 catalysts in terms of better gasoline selectivity (C5 ~C11 fraction)due to the formation of small cobalt particles and the presence of larger number of weak acidic sites.It also ex-hibited the highest catalytic activity because of the higher reducibility and the smaller cobalt particle size.

  7. Endotaxial Si nanolines in Si(001):H

    Science.gov (United States)

    Bianco, F.; Owen, J. H. G.; Köster, S. A.; Mazur, D.; Renner, Ch.; Bowler, D. R.

    2011-07-01

    We present a detailed study of the structural and electronic properties of a self-assembled silicon nanoline embedded in the H-terminated silicon (001) surface, known as the Haiku stripe. The nanoline is a perfectly straight and defect-free endotaxial structure of huge aspect ratio; it can grow micrometer long at a constant width of exactly four Si dimers (1.54 nm). Another remarkable property is its capacity to be exposed to air without suffering any degradation. The nanoline grows independently of any step edges at tunable densities from isolated nanolines to a dense array of nanolines. In addition to these unique structural characteristics, scanning tunneling microscopy and density functional theory reveal a one-dimensional state confined along the Haiku core. This nanoline is a promising candidate for the long-sought-after electronic solid-state one-dimensional model system to explore the fascinating quantum properties emerging in such reduced dimensionality.

  8. Growth and photoluminescence of Si-SiOx nanowires by catalyst-free chemical vapor deposition technique

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Yue [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); Luo, Ruiying, E-mail: ryluo@buaa.edu.cn [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); School of Materials Science and Engineering, Shanxi University of Technology, Hanzhong 723000 (China); Shang, Haidong [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China)

    2016-04-15

    Graphical abstract: - Highlights: • The Si-SiOx NWs were successfully synthesized via a one-step catalyst-free CVD method using TEOS as the precursor. • The Si-SiOx NWs had a core–shell structure with Si as the inner crystalline cores and SiOx as the outer amorphous layer. • The formation of Si-SiOx NWs was implemented by the non-classical crystallization mechanism. • The Si-SiOx NWs spontaneously self-assembled from the building block of charged nanoparticles. • The Si-SiOx NWs showed their potential applications in UV emission and visible light emission devices. - Abstract: We developed a one-step catalyst-free chemical vapor deposition process to synthesize Si-SiOx nanowires using tetraethoxysilane as the precursor. Observations using scanning electron microscopy showed that the Si-SiOx nanowires were 20–50 nm in diameter and tens of microns in length. The high-resolution transmission electron microscope analysis and X-ray diffraction demonstrated that the nanowires consisted of crystal silicon and amorphous SiOx. The Si and O with an atomic ratio of the Si-SiOx NWs were 1:1.2 according to the energy dispersion X-ray spectroscope. A systematic study on the effect of the growth conditions, such as reaction temperature, the reaction time, and the TEOS vapor flow rate was performed. The formation of Si-SiOx nanowires was implemented by the non-classical crystallization mechanism. The charged nanoparticles acting as building blocks self-assembled into nanowires. The photoluminescence measurements were carried out and showed that the Si-SiOx nanowires emitted stable ultraviolet and green luminescence excited by ultraviolet light.

  9. Effects of low-temperature Si buffer thickness and SiGe oxidation on sensitivity of Si1-xGex nanowire

    Science.gov (United States)

    Lai, Yi-Lung; Chang, Tai-Yuan; Chang, Kow-Ming; Chen, Chu-Feng; Lai, Chiung-Hui; Chen, Yi-Ming; Jong-Woei Whang, Allen; Lai, Hui-Lung; Chen, Huai-Yi; Wang, Shiu-Yu

    2015-06-01

    Si1-xGex nanowire biosensors are attractive for their high sensitivity due to the large surface-to-volume ratio, high carrier mobility, and silicon compatibility. In this work, we study the effect of the thickness of the low-temperature Si (LT-Si) buffer layer on an insulator on the sensitivity of oxidized Si1-xGex nanowire samples with different Ge contents by increasing the Si buffer thickness from 20 to 60 nm. 3-Aminopropyltrimethoxysilane (APTMS) was used as a biochemical reagent. It was demonstrated that, with the proper Ge content and LT-Si buffer thickness, the sensitivity of the Si1-xGex nanowire is high and it can be further improved by Si1-xGex oxidation. This can be attributed to the reduction of the diameter to the nanometer order, which gives rise to an increased surface-to-volume ratio and further enhances the sensitivity of the biosensor.

  10. Characterization by Sem, EDS and micro-Raman of the influence of the molar ratio SiO{sub 2}/Al{sub 2}O{sub 3} and reduction temperature on the system CuZSM5; Caracterizacion por SEM, EDS y micro-Raman de la influencia de la relacion molar SiO{sub 2}/Al{sub 2}O{sub 3} y temperatura de reduccion sobre el sistema CuZSM5

    Energy Technology Data Exchange (ETDEWEB)

    Chavez R, F. [Instituto Politecnico Nacional, Escuela Superior de Fisica y Matematicas, Departamento de Fisica, 07738 Mexico D. F. (Mexico); Rodriguez I, I. [Universidad de la Habana, Instituto de Ciencia y Tecnologia de Materiales, Zapata y G. s/n, 10400 La Habana (Cuba); Petranovskii, V., E-mail: fchavez@esfm.ipn.mx [UNAM, Centro de Nanociencias y Nanotecnologia, Apdo. Postal 14, 22800 Ensenada, Baja California (Mexico)

    2014-07-01

    The morphological and spectroscopic changes caused by reduction of ion-exchanged CuZSM5 samples with SiO{sub 2}/Al{sub 2}O{sub 3} molar ratios (MR) of 30 and 70 in H{sub 2} flow at 150 and 350 grades C are discussed. the nominal copper loading was of 1% by weight. Scanning electron microscopy of CuZSM5 sample set showed that the treatment in reducing atmosphere at 350 grades C produces particle agglomeration and smoother surface texture that treatment at 150 grades C, this effect was more pronounced for the sample with MR 30. Furthermore, the particles corresponding to the sample with MR 30 are of irregular shape and have rough texture (cubic or rectangular crystals, protrusions) while the particles of the sample with MR 70 are in the majority of spherical smooth texture (leaf-shaped crystals/platelet, reclining). Energy Dispersive X-ray spectroscopy elemental analysis reveals a heterogeneous distribution of copper as well other elements in each sample. The micro-Raman spectroscopy shows some changes in the vibrational modes for the studied samples. (Author)

  11. Fabrication of c-Si:H(p)/c-Si(n) Heterojunction Solar Cells with Microcrystalline Emitters

    Institute of Scientific and Technical Information of China (English)

    ZHOU Bing-Qing; LIU Feng-Zhen; ZHANG Qun-Fang; XU Ying; ZHOU Yu-Qin; LIU Jin-Long; ZHU Mei-Fang

    2006-01-01

    The p-type microcrystalline silicon (fj,c-Si) on n-type crystalline silicon (c-Si) heterojunction solar cells is fabricated by radio-frequency plasma enhanced chemical vapour deposition (rf-PECVD). The effect of the pc-Si:H p-layers on the performance of the heterojunction solar cells is investigated. Optimum μcSi:H p-layer is obtained with hydrogen dilution ratio of 99.65%, rf-power of 0.08 W/cm2, gas phase doping ratio of 0.125%, and the p-layer thickness of 15 nm. We fabricate μc-Si:H(p)/c-Si(n) heterojunction solar cells without texturing and obtained an efficiency of 13.4%. The comparisons of the solar-cell performances using different surface passivation techniques are discussed.

  12. Mass Spectrometric Investigation of Silicon Extremely Enriched in (28)Si: From (28)SiF4 (Gas Phase IRMS) to (28)Si Crystals (MC-ICP-MS).

    Science.gov (United States)

    Pramann, Axel; Rienitz, Olaf

    2016-06-01

    A new generation of silicon crystals even further enriched in (28)Si (x((28)Si) > 0.999 98 mol/mol), recently produced by companies and institutes in Russia within the framework of a project initiated by PTB, were investigated with respect to their isotopic composition and molar mass M(Si). A modified isotope dilution mass spectrometric (IDMS) method treating the silicon as the matrix containing a so-called virtual element (VE) existing of the isotopes (29)Si and (30)Si solely and high resolution multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) were applied in combination. This method succeeds also when examining the new materials holding merely trace amounts of (29)Si (x((29)Si) ≈ 5 × 10(-6) mol/mol) and (30)Si (x((30)Si) ≈ 7 × 10(-7) mol/mol) extremely difficult to detect with lowest uncertainty. However, there is a need for validating the enrichment in (28)Si already in the precursor material of the final crystals, silicon tetrafluoride (SiF4) gas prior to crystal production. For that purpose, the isotopic composition of selected SiF4 samples was determined using a multicollector magnetic sector field gas-phase isotope ratio mass spectrometer. Contaminations of SiF4 by natural silicon due to storing and during the isotope ratio mass spectrometry (IRMS) measurements were observed and quantified. The respective MC-ICP-MS measurements of the corresponding crystal samples show-in contrast-several advantages compared to gas phase IRMS. M(Si) of the new crystals were determined to some extent with uncertainties urel(M) Si)) on the degree of enrichment in (28)Si. This leads to a reduction of urel(M(Si)) during the past decade by almost 3 orders of magnitude and thus further reduces the uncertainty of the Avogadro constant NA which is one of the preconditions for the redefinition of the SI unit kilogram.

  13. Si/SiGe MMIC's

    Science.gov (United States)

    Luy, Johann-Friedrich; Strohm, Karl M.; Sasse, Hans-Eckard; Schueppen, Andreas; Buechler, Josef; Wollitzer, Michael; Gruhle, Andreas; Schaeffler, Friedrich; Guettich, Ulrich; Klaassen, Andreas

    1995-04-01

    Silicon-based millimeter-wave integrated circuits (SIMMWIC's) can provide new solutions for near range sensor and communication applications in the frequency range above 50 GHz. This paper gives a survey on the state-of-the-art performance of this technology and on first applications. The key devices are IMPATT diodes for mm-wave power generation and detection in the self-oscillating mixer mode, p-i-n diodes for use in switches and phase shifters, and Schottky diodes in detector and mixer circuits. The silicon/silicon germanium heterobipolar transistor (SiGe HBT) with f(sub max) values of more than 90 GHz is now used for low-noise oscillators at Ka-band frequencies. First system applications are discussed.

  14. Abiologic silicon isotope fractionation between aqueous Si and Fe(III)-Si gel in simulated Archean seawater: Implications for Si isotope records in Precambrian sedimentary rocks

    Science.gov (United States)

    Zheng, Xin-Yuan; Beard, Brian L.; Reddy, Thiruchelvi R.; Roden, Eric E.; Johnson, Clark M.

    2016-08-01

    Precambrian Si-rich sedimentary rocks, including cherts and banded iron formations (BIFs), record a >7‰ spread in 30Si/28Si ratios (δ30Si values), yet interpretation of this large variability has been hindered by the paucity of data on Si isotope exchange kinetics and equilibrium fractionation factors in systems that are pertinent to Precambrian marine conditions. Using the three-isotope method and an enriched 29Si tracer, a series of experiments were conducted to constrain Si isotope exchange kinetics and fractionation factors between amorphous Fe(III)-Si gel, a likely precursor to Precambrian jaspers and BIFs, and aqueous Si in artificial Archean seawater under anoxic conditions. Experiments were conducted at room temperature, and in the presence and absence of aqueous Fe(II) (Fe(II)aq). Results of this study demonstrate that Si solubility is significantly lower for Fe-Si gel than that of amorphous Si, indicating that seawater Si concentrations in the Precambrian may have been lower than previous estimates. The experiments reached ˜70-90% Si isotope exchange after a period of 53-126 days, and the highest extents of exchange were obtained where Fe(II)aq was present, suggesting that Fe(II)-Fe(III) electron-transfer and atom-exchange reactions catalyze Si isotope exchange through breakage of Fe-Si bonds. All experiments except one showed little change in the instantaneous solid-aqueous Si isotope fractionation factor with time, allowing extraction of equilibrium Si isotope fractionation factors through extrapolation to 100% isotope exchange. The equilibrium 30Si/28Si fractionation between Fe(III)-Si gel and aqueous Si (Δ30Sigel-aqueous) is -2.30 ± 0.25‰ (2σ) in the absence of Fe(II)aq. In the case where Fe(II)aq was present, which resulted in addition of ˜10% Fe(II) in the final solid, creating a mixed Fe(II)-Fe(III) Si gel, the equilibrium fractionation between Fe(II)-Fe(III)-Si gel and aqueous Si (Δ30Sigel-aqueous) is -3.23 ± 0.37‰ (2σ). Equilibrium

  15. NanoSIMS isotopic analysis of small presolar grains : search for Si3N4 grains from AGB stars and Al and Ti isotopic compositions of rare presolar SiC grains

    NARCIS (Netherlands)

    Zinner, E.; Sachiko, A.; Guinness, R.; Jennings, C.; Mertz, A.F.; Nguyen, A.N.; Gallino, R.; Hoppe, P.; Lugaro, M.A.; Nittler, L.R.; Lewis, R.S.

    2007-01-01

    We report isotopic ratio measurements of small SiC and Si3N4grains, with special emphasis on presolar SiC grains of type Z, and new nucleosynthesis models for 26Al/27Al and the Ti isotopic ratios in asymptotic giant branch (AGB) stars. With the NanoSIMS we analyzed 310 SiC grains from Murchison (car

  16. NanoSIMS isotopic analysis of small presolar grains : search for Si3N4 grains from AGB stars and Al and Ti isotopic compositions of rare presolar SiC grains

    NARCIS (Netherlands)

    Zinner, E.; Sachiko, A.; Guinness, R.; Jennings, C.; Mertz, A.F.; Nguyen, A.N.; Gallino, R.; Hoppe, P.; Lugaro, M.A.; Nittler, L.R.; Lewis, R.S.

    2007-01-01

    We report isotopic ratio measurements of small SiC and Si3N4grains, with special emphasis on presolar SiC grains of type Z, and new nucleosynthesis models for 26Al/27Al and the Ti isotopic ratios in asymptotic giant branch (AGB) stars. With the NanoSIMS we analyzed 310 SiC grains from Murchison

  17. Deep ultraviolet photodetectors based on p-Si/ i-SiC/ n-Ga2O3 heterojunction by inserting thin SiC barrier layer

    Science.gov (United States)

    An, Yuehua; Zhi, Yusong; Wu, Zhenping; Cui, Wei; Zhao, Xiaolong; Guo, Daoyou; Li, Peigang; Tang, Weihua

    2016-12-01

    Deep ultraviolet photodetectors based on p-Si/ n-Ga2O3 and p-Si/ i-SiC/ n-Ga2O3 heterojunctions were fabricated by laser molecular beam epitaxial (L-MBE), respectively. In compare with p-Si/ n-Ga2O3 heterostructure-based photodetector, the dark current of p-Si/ i-SiC/ n-Ga2O3-based photodetector decreased by three orders of magnitude, and the rectifying behavior was tuned from reverse to forward. In order to improve the quality of the photodetector, we reduced the oxygen vacancies of p-Si/ i-SiC/ n-Ga2O3 heterostructures by changing the oxygen pressure during annealing. As a result, the rectification ratio ( I F/ I R) of the fabricated photodetectors was 36 at 4.5 V and the photosensitivity was 5.4 × 105% under the 254 nm light illumination at -4.5 V. The energy band structure of p-Si/ n-Ga2O3 and p-Si/ i-SiC/ n-Ga2O3 heterostructures was schematic drawn to explain the physic mechanism of enhancement of the performance of p-Si/ i-SiC/ n-Ga2O3 heterostructure-based deep UV photodetector by introduction of SiC layer.

  18. 与Si工艺兼容的Si/SiGe/Si HBT研究%The Study of Si/SiGe/Si HBT and Its Compatibility with Si Process

    Institute of Scientific and Technical Information of China (English)

    廖小平

    2001-01-01

    我们对Si/SiGe/Si HBT及其Si兼容工艺进行了研究,在研究了一些关键的单项工艺的基础上,提出了五个高速Si/SiGe/Si HBT结构和一个低噪声Si/SiGe/Si HBT结构,并已研制成功台面结构Si/SiGe/Si HBT和低噪声Si/SiGe/Si HBT,为进一步高指标的Si/SiGe/Si HBT的研究建立了基础.

  19. Columnar growth of CoSi2 on Si(111), Si(100) and Si(110) by molecular beam epitaxy

    Science.gov (United States)

    Fathauer, R. W.; Nieh, C. W.; Xiao, Q. F.; Hashimoto, Shin

    1990-01-01

    Codeposition of silicon and cobalt on heated silicon substrates in ratios several times the silicide stoichiometry is found to result in epitaxial columns of CoSi2 surrounded by a matrix of epitaxial silicon. For (111)-oriented wafers, nearly cylindrical columns are formed, where both columns and surrounding silicon are defect free, as deduced from transmission electron microscopy. Independent control of the column diameter and separation is possible, and diameters of 27-135 nm have been demonstrated.

  20. Elastic and inelastic scattering of 50-MeV pions from 28Si and 30Si

    Science.gov (United States)

    Wienands, U.; Hessey, N.; Barnett, B. M.; Rozon, F. M.; Roser, H. W.; Altman, A.; Johnson, R. R.; Gill, D. R.; Smith, G. R.; Wiedner, C. A.; Manley, D. M.; Berman, B. L.; Crawford, H. J.; Grion, N.

    1987-02-01

    Angular distributions of the differential cross section for elastic and inelastic scattering of 50-MeV π+ and π- on 28Si and 30Si have been measured to a relative accuracy of 5-10 We fitted the cross section of elastic π+ and π- scattering from 28Si simultaneously with an optical model using a second-order potential of the Michigan State University form. Our best-fit parameters differ from those given previously. The ratio of the neutron and proton transition-matrix elements for the first Jπ=2+ state in 28Si is found from the inelastic cross section to be 1.13+/-0.09. For 30Si, the ratio is found to be 0.93+/-0.09, which differs significantly from the value derived from lifetime measurements on mirror nuclei.

  1. Absolute Calibration of Si iRMs used for Measurements of Si Paleo-nutrient proxies

    Science.gov (United States)

    Vocke, R. D., Jr.; Rabb, S. A.

    2016-12-01

    Silicon isotope variations (reported as δ30Si and δ29Si, relative to NBS28) in silicic acid dissolved in ocean waters, in biogenic silica and in diatoms are extremely informative paleo-nutrient proxies. The resolution and comparability of such measurements depend on the quality of the isotopic Reference Materials (iRMs) defining the delta scale. We report new absolute Si isotopic measurements on the iRMs NBS28 (RM 8546 - Silica Sand), Diatomite, and Big Batch using the Avogadro measurement approach and comparing them with prior assessments of these iRMs. The Avogadro Si measurement technique was developed by the German Physikalish-Technische Bundesanstalt (PTB) to provide a precise and highly accurate method to measure absolute isotopic ratios in highly enriched 28Si (99.996%) material. These measurements are part of an international effort to redefine the kg and mole based on the Planck constant h and the Avogadro constant NA, respectively (Vocke et al., 2014 Metrologia 51, 361, Azuma et al., 2015 Metrologia 52 360). This approach produces absolute Si isotope ratio data with lower levels of uncertainty when compared to the traditional "Atomic Weights" method of absolute isotope ratio measurement calibration. This is illustrated in Fig. 1 where absolute Si isotopic measurements on SRM 990, separated by 40+ years of advances in instrumentation, are compared. The availability of this new technique does not say that absolute Si isotopic ratios are or ever will be better for normal Si isotopic measurements when seeking isotopic variations in nature, because they are not. However, by determining the absolute isotopic ratios of all the Si iRM scale artifacts, such iRMs become traceable to the metric system (SI); thereby automatically conferring on all the artifact-based δ30Si and δ29Si measurements traceability to the base SI unit, the mole. Such traceability should help reduce the potential of bias between different iRMs and facilitate the replacement of delta

  2. Revision of the Li13Si4 structure

    Directory of Open Access Journals (Sweden)

    Thomas F. Fässler

    2013-12-01

    Full Text Available Besides Li17Si4, Li16.42Si4, and Li15Si4, another lithium-rich representative in the Li–Si system is the phase Li13Si4 (tridecalithium tetrasilicide, the structure of which has been determined previously [Frank et al. (1975. Z. Naturforsch. Teil B, 30, 10–13]. A careful analysis of X-ray diffraction patterns of Li13Si4 revealed discrepancies between experimentally observed and calculated Bragg positions. Therefore, we redetermined the structure of Li13Si4 on the basis of single-crystal X-ray diffraction data. Compared to the previous structure report, decisive differences are (i the introduction of a split position for one Li site [occupancy ratio 0.838 (7:0.162 (7], (ii the anisotropic refinement of atomic displacement parameters for all atoms, and (iii a high accuracy of atom positions and unit-cell parameters. The asymmetric unit of Li13Si4 contains two Si and seven Li atoms. Except for one Li atom situated on a site with symmetry 2/m, all other atoms are on mirror planes. The structure consists of isolated Si atoms as well as Si–Si dumbbells surrounded by Li atoms. Each Si atom is either 12- or 13-coordinated. The isolated Si atoms are situated in the ab plane at z = 0 and are strictly separated from the Si–Si dumbbells at z = 0.5.

  3. Interface structure between epitaxial NiSi2 and Si

    Institute of Scientific and Technical Information of China (English)

    Wei-Long Liu; Wen-Jauh Chen; Ting-Kan Tsai; Hsun-Heng Tsai; Shu-Huei Hsieh

    2006-01-01

    The interface structure between the Si and NiSi2 epitaxially grown on the ((-1)12) Si substrate was studied using high resolution transmission electron microscopy and computer image simulation. The results showed that the interface between Si and NiSi2 epitaxially grown on the ((-1)12) Si substrate has six different types: type A NiSi2 ((-1)11 )/( (-1)11 ) Si, type A NiSi2 (001)/(001) Si, type B NiSi2 (1(-1)(-1))/(1(-1)1) Si, type B NiSi2 ((-1)12)/(1(-1)2) Si, type B NiSi2 (2(-2)1)/(001) Si, and type B NiSi2 (1(-1)(4))/( 1(-1)0 ) Si. And there are one or more different atomic structures for one type of interface.

  4. 射频 Si/SiGe/Si HBT的研究%Studies on RF Si/SiGe/Si HBT

    Institute of Scientific and Technical Information of China (English)

    廖小平; 殷刚毅

    2003-01-01

    Si/SiGe/Si HBT与Si工艺兼容的研究基础上,对射频Si/SiGe/Si HBT的射频特性和制备工艺进行了研究,分析了与器件结构有关的关键参数寄生电容和寄生电阻与Si/SiGe/Si HBT的特征频率fT和最高振荡频率fmax的关系,成功地制备了fT为2.5 GHz、fmax为2.3 GHz的射频Si/SiGe/Si HBT,为具有更好的射频性能的Si/SiGe/Si HBT的研究建立了基础.

  5. Secondary growth mechanism of SiGe islands deposited on a mixed-phase microcrystalline Si by ion beam co-sputtering.

    Science.gov (United States)

    Ke, S Y; Yang, J; Qiu, F; Wang, Z Q; Wang, C; Yang, Y

    2015-11-01

    We discuss the SiGe island co-sputtering deposition on a microcrystalline silicon (μc-Si) buffer layer and the secondary island growth based on this pre-SiGe island layer. The growth phenomenon of SiGe islands on crystalline silicon (c-Si) is also investigated for comparison. The pre-SiGe layer grown on μc-Si exhibits a mixed-phase structure, including SiGe islands and amorphous SiGe (a-SiGe) alloy, while the layer deposited on c-Si shows a single-phase island structure. The preferential growth and Ostwald ripening growth are shown to be the secondary growth mechanism of SiGe islands on μc-Si and c-Si, respectively. This difference may result from the effect of amorphous phase Si (AP-Si) in μc-Si on the island growth. In addition, the Si-Ge intermixing behavior of the secondary-grown islands on μc-Si is interpreted by constructing the model of lateral atomic migration, while this behavior on c-Si is ascribed to traditional uphill atomic diffusion. It is found that the aspect ratios of the preferential-grown super islands are higher than those of the Ostwald-ripening ones. The lower lateral growth rate of super islands due to the lower surface energy of AP-Si on the μc-Si buffer layer for the non-wetting of Ge at 700 °C and the stronger Si-Ge intermixing effect at 730 °C may be responsible for this aspect ratio difference.

  6. Si microchannel plates for image intensification

    Science.gov (United States)

    Smith, Arlynn W.; Beetz, Charles P., Jr.; Boerstler, Robert W.; Winn, D. R.; Steinbeck, John W.

    2000-11-01

    Glass microchannel plates (MCPs) have been in use by numerous manufactuers in a variety of electron multiplication applications. Conventional fabrication of MCPs follow the lines of glass drawing and etching technology. Core and clad glass are drawn together, stacked, drawn again, and finally stacked in the desired pattern. The soluble core is removed with wet chemical processing. These techniques are beginning to run into their feasible limits in terms of channel size, open area ratio, uniformity, and material issues. A strong desire exists to fabricate MCPs with accepted lithographic techniques using Si as the base material to improve uniformity and throughput. Open area ratios of as high as 95% have been achieved using lithography. However, attempts to meet other channel plate characteristics met with little success due to thermal runaway or arcing during operation, high voltage is required for electron gain. Processing improvements have lead to the complete oxidation of the Si matrix eliminating the conducting Si in the channel walls of the Si MCPs allowing high voltages to be supported. Complete oxidation of the Si to silica allows processing temperatures high than conventional glass matrices can withstand. This fact allows for high temperature growth of conductive and secondary emissive materials on the channel walls of the structure. Si MCPs with gain have now been fabricated and tested with voltages comparable to conventional glass MCPs. Channel plate characteristics such as operating voltage, strip current, and gain for Si MCPs will be presented and compared to glass MCPs.

  7. Effect of PECVD SiNx/SiOyNx-Si interface property on surface passivation of silicon wafer

    Science.gov (United States)

    Jia, Xiao-Jie; Zhou, Chun-Lan; Zhu, Jun-Jie; Zhou, Su; Wang, Wen-Jing

    2016-12-01

    It is studied in this paper that the electrical characteristics of the interface between SiOyNx/SiNx stack and silicon wafer affect silicon surface passivation. The effects of precursor flow ratio and deposition temperature of the SiOyNx layer on interface parameters, such as interface state density Dit and fixed charge Qf, and the surface passivation quality of silicon are observed. Capacitance-voltage measurements reveal that inserting a thin SiOyNx layer between the SiNx and the silicon wafer can suppress Qf in the film and Dit at the interface. The positive Qf and Dit and a high surface recombination velocity in stacks are observed to increase with the introduced oxygen and minimal hydrogen in the SiOyNx film increasing. Prepared by deposition at a low temperature and a low ratio of N2O/SiH4 flow rate, the SiOyNx/SiNx stacks result in a low effective surface recombination velocity (Seff) of 6 cm/s on a p-type 1 Ω·cm-5 Ω·cm FZ silicon wafer. The positive relationship between Seff and Dit suggests that the saturation of the interface defect is the main passivation mechanism although the field-effect passivation provided by the fixed charges also make a contribution to it. Project supported by the National High Technology Research and Development Program of China (Grant No. 2015AA050302) and the National Natural Science Foundation of China (Grant No. 61306076).

  8. Privacy and Yin Si

    Institute of Scientific and Technical Information of China (English)

    胡迪

    2007-01-01

    <正>“Privacy” is translated as yin si in Chinese.Traditionally,in the Chinese mind,yin si is associated with something that is closed or unfair.If someone is said to have yin si,meddlers(好事者) will be attracted to pry(打探) into his or her affairs.So people always state that they don’t have yin si.

  9. Electroluminescence of Si Nanocrystal-Doped SiO2

    Institute of Scientific and Technical Information of China (English)

    CHEN Dan; XIE Zhi-Qiang; WU Qian; ZHAO You-Yuan; LU Ming

    2007-01-01

    @@ We perform a comparative study on the electroluminescence (EL) and photoluminescence (PL) of Si nanocrystaldoped SiO2 (nc-Si:SiO2) and SiO2, and clarify whether the contribution from Si nanocrystals in the EL of nc-Si:SiO2 truly exists. The results unambiguously indicate the presence of EL of Si nanocrystals. The difference of peak positions between the EL and PL spectra are discussed. It is found that the normal method of passivation to enhance the PL of Si nanocrystals is not equally effective for the EL, hence new methods need to be explored to promote the EL of Si nanocrystals.

  10. Giant Magneto-Impedance Effect in Sandwiched FeSiB/Cu/FeSiB Films

    Institute of Scientific and Technical Information of China (English)

    ZHOU Yong; YANG Chun-Sheng; YU Jin-Qiang; ZHAO Xiao-Lin; MAO Hai-Ping

    2000-01-01

    Giant magneto-impedance (GMI) effect has been realized in the sandwiched FeSiB/Cu/FeSiB films. With magnetic field Ha and ac current applied along the longitudinal direction of the sample, the GMI ratio increases with the increasing Ha, reaching a positive maximum, value, and then decreases to negative values with further increase of magnetic field. Field dependence of the GMI ratio also indicates that the magnetic field corresponding to the maximum GMI ratio is different for various frequencies. The positive maximum GMI ratio is 17.2% for Ha=1600 A/m and frequency of 3 MHz. In addition, the films display a large negative GMI ratio with a magnetic field applied along the transverse direction and the value of the GMI ratio is about -13.4% for Ha=5600A/m and frequency of 3 MHz.

  11. Toward 17µm pitch heterogeneously integrated Si/SiGe quantum well bolometer focal plane arrays

    Science.gov (United States)

    Ericsson, Per; Fischer, Andreas C.; Forsberg, Fredrik; Roxhed, Niclas; Samel, Björn; Savage, Susan; Stemme, Göran; Wissmar, Stanley; Öberg, Olof; Niklaus, Frank

    2011-06-01

    Most of today's commercial solutions for un-cooled IR imaging sensors are based on resistive bolometers using either Vanadium oxide (VOx) or amorphous Silicon (a-Si) as the thermistor material. Despite the long history for both concepts, market penetration outside high-end applications is still limited. By allowing actors in adjacent fields, such as those from the MEMS industry, to enter the market, this situation could change. This requires, however, that technologies fitting their tools and processes are developed. Heterogeneous integration of Si/SiGe quantum well bolometers on standard CMOS read out circuits is one approach that could easily be adopted by the MEMS industry. Due to its mono crystalline nature, the Si/SiGe thermistor material has excellent noise properties that result in a state-ofthe- art signal-to-noise ratio. The material is also stable at temperatures well above 450°C which offers great flexibility for both sensor integration and novel vacuum packaging concepts. We have previously reported on heterogeneous integration of Si/SiGe quantum well bolometers with pitches of 40μm x 40μm and 25μm x 25μm. The technology scales well to smaller pixel pitches and in this paper, we will report on our work on developing heterogeneous integration for Si/SiGe QW bolometers with a pixel pitch of 17μm x 17μm.

  12. Biogeochemical cycling of Si in a California rice cropping system

    Science.gov (United States)

    Seyfferth, A.; Kocar, B. D.; Lee, J.; Fendorf, S.

    2012-12-01

    Silicon is the second most abundant element in the earth's crust, but the number of studies on the biogeochemical cycling of Si does not reflect its environmental ubiquity. While not an "essential" plant nutrient, Si is important for many plants, particularly monocots, for structural integrity and protection against disease and environmental stress. For rice, Si fertilization with N and P increases yield significantly more than N and P alone. While total Si in soil is high, much of this Si is tied up in the crystal lattice of primary and secondary minerals and is only slowly released through chemical weathering. Thus, plant-available Si may be limited particularly in highly weathered soils in humid environments where long-term chemical weathering has lead to desilicification of the soils (e.g., in Southeast Asia where most rice is grown). In such Si-depleted environments, the biocycling of Si through decaying plant litter (i.e., phytoliths) and subsequent plant uptake has proven an important component of the terrestrial biogeochemical cycling of Si. Here, we investigate the dynamics of Si cycling over a two-year period in a rice paddy in Northern California where soil incorporation of harvested rice straw has impacted the terrestrial biogeochemical cycling of Si. We use Ge/Si ratios in pore-waters to infer the contribution of chemical weathering vs. dissolution of plant phytoliths on the plant-available Si pool. We found that the Ge/Si ratios change over the growing and fallow seasons reflecting different rates of Si release through phytolith dissolution and plant uptake.

  13. Si/SiO2和Si/SiNx/SiO2超晶格的能带结构%Band structure of Si/SiO2 and Si/SiNx/SiO2 superlattices

    Institute of Scientific and Technical Information of China (English)

    魏屹; 董成军; 徐明

    2010-01-01

    利用Kronig-Penney模型从理论上计算了Si/SiO2和Si/Si/SiNx/SiO2多层膜结构中量子阱的能带结构,进一步分析了各亚层薄膜厚度对能带结构和有效质量的影响.结果发现,适当减少亚层的厚度都能使得纳米Si薄膜的带隙发生明显宽化.在Si/SiO2超晶格中,Si量子阱层带隙能量随着Si层厚度的变化符合EPLL(eV)=1.6+0.7/d2关系,与我们的计算结果十分吻合.在Si/SiNdSiO2超晶格系统中,可以通过控制各亚层厚度,尤其是Si和SiNx层厚度,均能够有效地控制发光.

  14. Fabrication and electrical characteristics of Si nanocrystal/c-Si heterojunctions

    Science.gov (United States)

    Song, Dengyuan; Cho, Eun-Chel; Conibeer, Gavin; Huang, Yidan; Green, Martin A.

    2007-09-01

    Heterojunctions (HJs) were fabricated from p-type Si nanocrystals (Si NCs) embedded in a SiC matrix on an n-type crystalline Si substrate. Transmission electron microscopy revealed that Si NCs are clearly established, with sizes in the range of 3-5nm. The HJ diodes showed a good rectification ratio of 1.0×104 at ±1.0V at 298K. The ideality factor, junction built-in potential, and open-circuit voltage are ˜1.24, 0.72V, and 0.48V, respectively. Measurement of temperature-dependent I-V curves in forward conduction suggests that, in the medium voltage range, junction interface recombination can be described as the dominant current transport mechanism.

  15. Financial Key Ratios

    Directory of Open Access Journals (Sweden)

    Tănase Alin-Eliodor

    2014-08-01

    Full Text Available This article focuses on computing techniques starting from trial balance data regarding financial key ratios. There are presented activity, liquidity, solvency and profitability financial key ratios. It is presented a computing methodology in three steps based on a trial balance.

  16. Offer/Acceptance Ratio.

    Science.gov (United States)

    Collins, Mimi

    1997-01-01

    Explores how human resource professionals, with above average offer/acceptance ratios, streamline their recruitment efforts. Profiles company strategies with internships, internal promotion, cooperative education programs, and how to get candidates to accept offers. Also discusses how to use the offer/acceptance ratio as a measure of program…

  17. Compression Ratio Adjuster

    Science.gov (United States)

    Akkerman, J. W.

    1982-01-01

    New mechanism alters compression ratio of internal-combustion engine according to load so that engine operates at top fuel efficiency. Ordinary gasoline, diesel and gas engines with their fixed compression ratios are inefficient at partial load and at low-speed full load. Mechanism ensures engines operate as efficiently under these conditions as they do at highload and high speed.

  18. Specialized ratio analysis.

    Science.gov (United States)

    Wyer, J C; Salzinger, F H

    1983-01-01

    Many common management techniques have little use in managing a medical group practice. Ratio analysis, however, can easily be adapted to the group practice setting. Acting as broad-gauge indicators, financial ratios provide an early warning of potential problems and can be very useful in planning for future operations. The author has gathered a collection of financial ratios which were developed by participants at an education seminar presented for the Virginia Medical Group Management Association. Classified according to the human element, system component, and financial factor, the ratios provide a good sampling of measurements relevant to medical group practices and can serve as an example for custom-tailoring a ratio analysis system for your medical group.

  19. Aperiodic SiSn/Si multilayers for thermoelectric applications

    Science.gov (United States)

    Tonkikh, A. A.; Zakharov, N. D.; Eisenschmidt, C.; Leipner, H. S.; Werner, P.

    2014-04-01

    We report on novel defect-free SiSn/Si heterostructures grown pseudomorphically on Si(001) substrates using temperature-modulated molecular beam epitaxy. This approach results in a sustainable epitaxial growth for SiSn/Si multilayers. Transmission electron microscopy and electron diffraction manifest that SiSn layers possess a diamond lattice structure. X-ray diffraction reveals up to 9.5 at% Sn in the crystal lattice of SiSn layers.

  20. Global Mg/Si and Al/Si Distributions on the Lunar Surface Derived from Chang'E-2 X-ray Spectrometer

    Science.gov (United States)

    Dong, Wu-Dong; Zhang, Xiao-Ping; Zhu, Meng-Hua; Xu, Ao-Ao; Tang, Ze-Sheng

    2016-01-01

    The technique of X-ray fluorescence remote sensing plays a significant role in research related to the chemical compositions of the Moon. Here we describe the data analysis method for China's Chang'E-2 X-ray spectrometer in detail and present the preliminary results about the first global Mg/Si and Al/Si maps of the lunar surface. Our results show that the distributions of Mg/Si and Al/Si correlate well with terrains on the Moon. The higher Mg/Si ratio corresponds to the mare regions while the lower value corresponds to the highland terrains. The map of the Al/Si ratio shows a reversed distribution compared with the map of the Mg/Si ratio.

  1. Global Mg/Si and Al/Si Distributions on Lunar Surface Derived from Chang'E-2 X-ray Spectrometer

    CERN Document Server

    Dong, Wu-Dong; Zhu, Meng-Hua; Xu, Aoao; Tang, Zesheng

    2015-01-01

    X-ray fluorescence remote sensing technique plays a significant role in the chemical compositions research of the Moon. Here we describe the data analysis method for China's Chang'E-2 X-ray spectrometer (CE2XRS) in detail and present the preliminary results: the first global Mg/Si and Al/Si maps on the lunar surface. Our results show that the distributions of Mg/Si and Al/Si correlate well with the terrains of the Moon. The higher Mg/Si ratio corresponding to the mare regions while the lower value corresponding to the highland terrains. The map of Al/Si ratio shows a reverse relationship with the map of Mg/Si ratio.

  2. Tailored Au nanorods: optimizing functionality, controlling the aspect ratio and increasing biocompatibility

    Energy Technology Data Exchange (ETDEWEB)

    Cai Xiaoqing; Wang, Cheng-Liang; Chen, Hsiang-Hsin; Chien, Chia-Chi; Lai Shengfeng; Chen Yiyun; Hua, Tzu-En; Kempson, Ivan M; Hwu, Y [Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan (China); Yang, C S [Center for Nanomedicine, National Health Research Institutes, Miaoli, Taiwan (China); Margaritondo, G, E-mail: phhwu@sinica.edu.tw [Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2010-08-20

    Monodisperse gold nanorods with high aspect ratio were synthesized by x-ray irradiation. Irradiation was first used to stimulate the creation of seeds. Afterward, nanorod growth was stimulated either by chemical reduction or again by x-ray irradiation. In the last case, the entire process took place without reducing agents. The shape of the final products could be controlled by modulating the intensity of the x-ray irradiation during the seed synthesis. In turn, the nanorod aspect ratio determines the absorption wavelength of the nanorods that can thus be optimized for different applications. Likewise, the aspect ratio influences the uptake of the nanorods by HeLa cells.

  3. Correlation between SiH2/SiH and light-induced degradation of p-i-n hydrogenated amorphous silicon solar cells

    Science.gov (United States)

    Keya, Kimitaka; Kojima, Takashi; Torigoe, Yoshihiro; Toko, Susumu; Yamashita, Daisuke; Seo, Hyunwoong; Itagaki, Naho; Koga, Kazunori; Shiratani, Masaharu

    2016-07-01

    We have measured the hydrogen content ratio I SiH2/I SiH associated with Si-H2 and Si-H bonds in p-i-n (PIN) a-Si:H solar cells by Raman spectroscopy. With decreasing I SiH2/I SiH, the efficiency, short-circuit current density, open-circuit voltage, and fill factor of PIN a-Si:H solar cells after light soaking tend to increase. Namely, I SiH2/I SiH correlates well with light-induced degradation of the cells. While a single I-layer has a low I SiH2/I SiH of 0.03-0.09, a PIN cell has I SiH2/I SiH = 0.18 because many Si-H2 bonds exist in the P-layer and at the P/I interface of the PIN solar cells. To realize PIN solar cells with higher stability, we must suppress Si-H2 bond formation in the P-layer and at the P/I interface.

  4. Lattice dislocation in Si nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Omar, M.S., E-mail: dr_m_s_omar@yahoo.co [Department of Physics, College of Science, University of Salahaddin, Arbil, Iraqi Kurdistan (Iraq); Taha, H.T. [Department of Physics, College of Science, University of Salahaddin, Arbil, Iraqi Kurdistan (Iraq)

    2009-12-15

    Modified formulas were used to calculate lattice thermal expansion, specific heat and Bulk modulus for Si nanowires with diameters of 115, 56, 37 and 22 nm. From these values and Gruneisen parameter taken from reference, mean lattice volumes were found to be as 20.03 A{sup 3} for the bulk and 23.63, 29.91, 34.69 and 40.46 A{sup 3} for Si nanowire diameters mentioned above, respectively. Their mean bonding length was calculated to be as 0.235 nm for the bulk and 0.248, 0.269, 0.282 and 0.297 nm for the nanowires diameter mentioned above, respectively. By dividing the nanowires diameter on the mean bonding length, number of layers per each nanowire size was found to be as 230, 104, 65 and 37 for the diameters mentioned above, respectively. Lattice dislocations in 22 nm diameter wire were found to be from 0.00324 nm for the 1st central lattice to 0.2579 nm for the last surface lattice. Such dislocation was smaller for larger wire diameters. Dislocation concentration found to change in Si nanowires according to the proportionalities of surface thickness to nanowire radius ratios.

  5. Difference and ratio plots

    DEFF Research Database (Denmark)

    Svendsen, Anders Jørgen; Holmskov, U; Bro, Peter

    1995-01-01

    hitherto unnoted differences between controls and patients with either rheumatoid arthritis or systemic lupus erythematosus. For this we use simple, but unconventional, graphic representations of the data, based on difference plots and ratio plots. Differences between patients with Burkitt's lymphoma...... and systemic lupus erythematosus from another previously published study (Macanovic, M. and Lachmann, P.J. (1979) Clin. Exp. Immunol. 38, 274) are also represented using ratio plots. Our observations indicate that analysis by regression analysis may often be misleading....

  6. Large area and depth-profiling dislocation imaging and strain analysis in Si/SiGe/Si heterostructures.

    Science.gov (United States)

    Chen, Xin; Zuo, Daniel; Kim, Seongwon; Mabon, James; Sardela, Mauro; Wen, Jianguo; Zuo, Jian-Min

    2014-10-01

    We demonstrate the combined use of large area depth-profiling dislocation imaging and quantitative composition and strain measurement for a strained Si/SiGe/Si sample based on nondestructive techniques of electron beam-induced current (EBIC) and X-ray diffraction reciprocal space mapping (XRD RSM). Depth and improved spatial resolution is achieved for dislocation imaging in EBIC by using different electron beam energies at a low temperature of ~7 K. Images recorded clearly show dislocations distributed in three regions of the sample: deep dislocation networks concentrated in the "strained" SiGe region, shallow misfit dislocations at the top Si/SiGe interface, and threading dislocations connecting the two regions. Dislocation densities at the top of the sample can be measured directly from the EBIC results. XRD RSM reveals separated peaks, allowing a quantitative measurement of composition and strain corresponding to different layers of different composition ratios. High-resolution scanning transmission electron microscopy cross-section analysis clearly shows the individual composition layers and the dislocation lines in the layers, which supports the EBIC and XRD RSM results.

  7. Ultraviolet Emission Lines of Si ii in Quasars: Investigating the "Si ii Disaster"

    Science.gov (United States)

    Laha, Sibasish; Keenan, Francis P.; Ferland, Gary J.; Ramsbottom, Catherine A.; Aggarwal, Kanti M.

    2016-07-01

    The observed line intensity ratios of the Si ii λ1263 and λ1307 multiplets to that of Si ii λ1814 in the broad-line region (BLR) of quasars are both an order of magnitude larger than the theoretical values. This was first pointed out by Baldwin et al., who termed it the “Si ii disaster,” and it has remained unresolved. We investigate the problem in the light of newly published atomic data for Si ii. Specifically, we perform BLR calculations using several different atomic data sets within the CLOUDY modeling code under optically thick quasar cloud conditions. In addition, we test for selective pumping by the source photons or intrinsic galactic reddening as possible causes for the discrepancy, and we also consider blending with other species. However, we find that none of the options investigated resolve the Si ii disaster, with the potential exception of microturbulent velocity broadening and line blending. We find that a larger microturbulent velocity (˜ 500 {km} {{{s}}}-1) may solve the Si ii disaster through continuum pumping and other effects. The CLOUDY models indicate strong blending of the Si ii λ1307 multiplet with emission lines of O i, although the predicted degree of blending is incompatible with the observed λ1263/λ1307 intensity ratios. Clearly, more work is required on the quasar modeling of not just the Si ii lines but also nearby transitions (in particular those of O i) to fully investigate whether blending may be responsible for the Si ii disaster.

  8. Three-dimensional crossbar arrays of self-rectifying Si/SiO2/Si memristors

    Science.gov (United States)

    Li, Can; Han, Lili; Jiang, Hao; Jang, Moon-Hyung; Lin, Peng; Wu, Qing; Barnell, Mark; Yang, J. Joshua; Xin, Huolin L.; Xia, Qiangfei

    2017-06-01

    Memristors are promising building blocks for the next-generation memory and neuromorphic computing systems. Most memristors use materials that are incompatible with the silicon dominant complementary metal-oxide-semiconductor technology, and require external selectors in order for large memristor arrays to function properly. Here we demonstrate a fully foundry-compatible, all-silicon-based and self-rectifying memristor that negates the need for external selectors in large arrays. With a p-Si/SiO2/n-Si structure, our memristor exhibits repeatable unipolar resistance switching behaviour (105 rectifying ratio, 104 ON/OFF) and excellent retention at 300 °C. We further build three-dimensinal crossbar arrays (up to five layers of 100 nm memristors) using fluid-supported silicon membranes, and experimentally confirm the successful suppression of both intra- and inter-layer sneak path currents through the built-in diodes. The current work opens up opportunities for low-cost mass production of three-dimensional memristor arrays on large silicon and flexible substrates without increasing circuit complexity.

  9. Ratios of Normal Variables

    Directory of Open Access Journals (Sweden)

    George Marsaglia

    2006-05-01

    Full Text Available This article extends and amplifies on results from a paper of over forty years ago. It provides software for evaluating the density and distribution functions of the ratio z/w for any two jointly normal variates z,w, and provides details on methods for transforming a general ratio z/w into a standard form, (a+x/(b+y , with x and y independent standard normal and a, b non-negative constants. It discusses handling general ratios when, in theory, none of the moments exist yet practical considerations suggest there should be approximations whose adequacy can be verified by means of the included software. These approximations show that many of the ratios of normal variates encountered in practice can themselves be taken as normally distributed. A practical rule is developed: If a < 2.256 and 4 < b then the ratio (a+x/(b+y is itself approximately normally distributed with mean μ = a/(1.01b − .2713 and variance 2 = (a2 + 1/(b2 + .108b − 3.795 − μ2.

  10. Ratios of Normal Variables

    Directory of Open Access Journals (Sweden)

    George Marsaglia

    2006-05-01

    Full Text Available This article extends and amplifies on results from a paper of over forty years ago. It provides software for evaluating the density and distribution functions of the ratio z/w for any two jointly normal variates z,w, and provides details on methods for transforming a general ratio z/w into a standard form, (a+x/(b+y , with x and y independent standard normal and a, b non-negative constants. It discusses handling general ratios when, in theory, none of the moments exist yet practical considerations suggest there should be approximations whose adequacy can be verified by means of the included software. These approximations show that many of the ratios of normal variates encountered in practice can themselves be taken as normally distributed. A practical rule is developed: If a < 2.256 and 4 < b then the ratio (a+x/(b+y is itself approximately normally distributed with mean μ = a/(1.01b - .2713 and variance σ2 = (a2 + 1/(b2 + .108b - 3.795 μ2.

  11. Transmission electron microscopy study of the formation of epitaxial CoSi2/Si (111) by a room-temperature codeposition technique

    Science.gov (United States)

    D'Anterroches, Cecile; Yakupoglu, H. Nejat; Lin, T. L.; Fathauer, R. W.; Grunthaner, P. J.

    1988-01-01

    Co and Si have been codeposited on Si (111) substrates near room temperature in a stoichiometric 1:2 ratio in a molecular beam epitaxy system. Annealing of these deposits yields high-quality single-crystal CoSi2 layers. Transmission electron microscopy has been used to examine as-deposited layers and layers annealed at 300, 500, and 600 C. Single-crystal epitaxial grains of CoSi2 embedded in a matrix of amorphous Co/Si are observed in as-deposited samples, while the layer is predominantly single-crystal, inhomogeneously strained CoSi2 at 300 C. At 600 C, a homogeneously strained single-crystal layer with a high density of pinholes is observed. In contrast to other solid phase epitaxy techniques used to grow CoSi2 on Si (111), no intermediate silicide phases are observed prior to the formation of CoSi2.

  12. Microstructural and mechanical properties of binary Ni–Si eutectic alloys

    Energy Technology Data Exchange (ETDEWEB)

    Gogebakan, Musa, E-mail: gogebakan@ksu.edu.tr [Department of Physics, Faculty of Art and Sciences, Kahramanmaras Sutcu Imam University, Kahramanmaras 46100 (Turkey); Kursun, Celal [Department of Physics, Faculty of Art and Sciences, Kahramanmaras Sutcu Imam University, Kahramanmaras 46100 (Turkey); Gunduz, Kerem Ozgur; Tarakci, Mehmet; Gencer, Yucel [Department of Materials Science and Engineering, Gebze Institute of Technology, Gebze, 41400 Kocaeli (Turkey)

    2015-09-15

    Highlights: • Ni{sub 80}Si{sub 20}, Ni{sub 70}Si{sub 30}, Ni{sub 55}Si{sub 45} and Ni{sub 45}Si{sub 55} were prepared by arc melting method. • The maximum microhardness value of 1126 HV obtained for Ni{sub 70}Si{sub 30} alloy. • The microhardness values decreases with increase of Si/Ni ratio. • Ni{sub 80}Si{sub 20} and Ni{sub 55}Si{sub 45} are soft ferromagnetic, Ni{sub 70}Si{sub 30} and Ni{sub 45}Si{sub 55} are paramagnetic. - Abstract: In the present work, Ni–Si eutectic alloys with nominal compositions of Ni{sub 80}Si{sub 20}, Ni{sub 70}Si{sub 30}, Ni{sub 55}Si{sub 45} and Ni{sub 45}Si{sub 55} (Ni and Si with the purity of 99.99%) were prepared by arc melting method under vacuum/argon atmosphere. The effects of Si/Ni ratio on the microstructural properties, thermal transformation behavior, micro-hardness and magnetic properties of the Ni–Si eutectic alloys were investigated. These alloys were characterized by X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), differential thermal analysis (DTA), Vickers microhardness measurement and Vibrating Sample Magnetometer (VSM). The phases expected according to Ni–Si phase diagram for conventional solidified eutectic Ni–Si alloys are considerably consistent with phase detected by XRD in this study. The quantitative results confirm that the chemical composition of the alloys very close to eutectic compositions and the microstructures are in typical lamellar eutectic morphology. The maximum microhardness value of 1126 HV obtained for Ni{sub 70}Si{sub 30} alloy which has highest melting temperature amongst Ni–Si eutectics. The microhardness values decreases with increase of Si/Ni ratio. Ni{sub 80}Si{sub 20} and Ni{sub 55}Si{sub 45} alloys are soft ferromagnetic, Ni{sub 70}Si{sub 30} and Ni{sub 45}Si{sub 55} alloys are paramagnetic with no magnetic saturation.

  13. CMOS Compatible Nonvolatile Memory Devices Based on SiO2/Cu/SiO2 Multilayer Films

    Institute of Scientific and Technical Information of China (English)

    WANG Yan; LIU Qi; LV Hang-Bing; LONG Shi-Bing; ZHANG Sen; LI Ying-Tao; LIAN Wen-Tai; YANG Jian-Hong; LIU Ming

    2011-01-01

    We systematically investigate the resistive switching characteristics of SiO2 films with a Cu/SiO2/Cu/SiO2/Pt multilayer structure. The device exhibits good resistive switching performances,including a high ON/OFF resistance ratio (>103),good retention characteristic (>104 s),satisfactory switching endurance (>200cycles),a fast programming speed (<100ns) and a high device yield (~100%).Considering these results,SiO2-based memories have highly promising applications for nonvolatile memory devices.

  14. Delicate Structural Control of Si-SiOx-C Composite via High-Speed Spray Pyrolysis for Li-Ion Battery Anodes.

    Science.gov (United States)

    Lee, Seung Jong; Kim, Hye Jin; Hwang, Tae Hoon; Choi, Sunghun; Park, Sung Hyeon; Deniz, Erhan; Jung, Dae Soo; Choi, Jang Wook

    2017-03-08

    Despite the high theoretical capacity, silicon (Si) anodes in lithium-ion batteries have difficulty in meeting the commercial standards in various aspects. In particular, the huge volume change of Si makes it very challenging to simultaneously achieve high initial Coulombic efficiency (ICE) and long-term cycle life. Herein, we report spray pyrolysis to prepare Si-SiOx composite using an aqueous precursor solution containing Si nanoparticles, citric acid, and sodium hydroxide (NaOH). In the precursor solution, Si nanoparticles are etched by NaOH with the production of [SiO4](4-). During the dynamic course of spray pyrolysis, [SiO4](4-) transforms to SiOx matrix and citric acid decomposes to carbon surface layer with the assistance of NaOH that serves as a decomposition catalyst. As a result, a Si-SiOx composite, in which Si nanodomains are homogeneously embedded in the SiOx matrix with carbon surface layer, is generated by a one-pot process with a residence time of only 3.5 s in a flow reactor. The optimal composite structure in terms of Si domain size and Si-to-O ratio exhibited excellent electrochemical performance, such as reversible capacity of 1561.9 mAh g(-1) at 0.06C rate and ICE of 80.2% and 87.9% capacity retention after 100 cycles at 1C rate.

  15. Prose Writer Si Yu

    Institute of Scientific and Technical Information of China (English)

    1996-01-01

    SI Yu, pen name of Zhan Shaojuan, is well known through her prose works. During the recent more than ten years, Chinese prose writing has developed rapidly, from its previous level to the present flourishing conditions. Si Yu is a distinguished woman writer, whose creative prose alternately displays either

  16. Potential support ratios

    DEFF Research Database (Denmark)

    Kjærgaard, Søren; Canudas-Romo, Vladimir

    2017-01-01

    , the prospective potential support ratio usually focuses on the current mortality schedule, or period life expectancy. Instead, in this paper we look at the actual mortality experienced by cohorts in a population, using cohort life tables. We analyse differences between the two perspectives using mortality models......, historical data, and forecasted data. Cohort life expectancy takes future mortality improvements into account, unlike period life expectancy, leading to a higher prospective potential support ratio. Our results indicate that using cohort instead of period life expectancy returns around 0.5 extra younger...

  17. On the determination of Poisson's ratio of stressed monolayer and bilayer submicron thick films

    CERN Document Server

    Martins, P; Brida, S; Barbier, D

    2008-01-01

    In this paper, the bulge test is used to determine the mechanical properties of very thin dielectric membranes. Commonly, this experimental method permits to determine the residual stress (s0) and biaxial Young's modulus (E/(1-u)). Associating square and rectangular membranes with different length to width ratios, the Poisson's ratio (u) can also be determined. LPCVD Si3N4 monolayer and Si3N4/SiO2 bilayer membranes, with thicknesses down to 100 nm, have been characterized giving results in agreement with literature for Si3N4, E = 212 $\\pm$ 14 GPa, s0 = 420 $\\pm$ 8 and u = 0.29.

  18. High performance amorphous-Si@SiOx/C composite anode materials for Li-ion batteries derived from ball-milling and in situ carbonization

    Science.gov (United States)

    Wang, Dingsheng; Gao, Mingxia; Pan, Hongge; Wang, Junhua; Liu, Yongfeng

    2014-06-01

    Amorphous-Si@SiOx/C composites with amorphous Si particles as core and coated with a double layer of SiOx and carbon are prepared by ball-milling crystal micron-sized silicon powders and carbonization of the citric acid intruded in the ball-milled Si. Different ratios of Si to citric acid are used in order to optimize the electrochemical performance. It is found that SiOx exists naturally at the surfaces of raw Si particles and its content increases to ca. 24 wt.% after ball-milling. With an optimized Si to citric acid weight ratio of 1/2.5, corresponding to 8.4 wt.% C in the composite, a thin carbon layer is coated on the surfaces of a-Si@SiOx particles, moreover, floc-like carbon also forms and connects the carbon coated a-Si@SiOx particles. The composite provides a capacity of 1450 mA h g-1 after 100 cycles at a current density of 100 mA g1, and a capacity of 1230 mA h g-1 after 100 cycles at 500 mA g1 as anode material for lithium-ion batteries. Effects of ball-milling and the addition of citric acid on the microstructure and electrochemical properties of the composites are revealed and the mechanism of the improvement in electrochemical properties is discussed.

  19. Variations of δ 30Si and Ge/Si with weathering and biogenic input in tropical basaltic ash soils under monoculture

    Science.gov (United States)

    Opfergelt, S.; Cardinal, D.; André, L.; Delvigne, C.; Bremond, L.; Delvaux, B.

    2010-01-01

    In soils, silicon released by mineral weathering can be retrieved from soil solution through clay formation, Si adsorption onto secondary oxides and plant uptake, thereby impacting the Si-isotopic signature and Ge/Si ratio of dissolved Si (DSi) exported to rivers. Here we use these proxies to study the contribution of biogenic Si (BSi) in a soil-plant system involving basaltic ash soils differing in weathering degree under intensive banana cropping. δ 30Si and Ge/Si ratios were determined in bulk soils (banana phytoliths and a stable phytolith pool from previous forested vegetation. δ 30Si and Ge/Si values of clay fractions in poorly developed volcanic soils, isotopically heavier and Ge-depleted in surface horizons, support the occurrence of a DSi source from banana phytolith dissolution, available for Si sequestration in clay-sized secondary minerals (clay minerals formation and Si adsorption onto Fe-oxide). In the soil-plant system, δ 30Si and Ge/Si are thus highly relevant to trace weathering and input of DSi from phytoliths in secondary minerals, although not quantifying the net input of BSi to DSi.

  20. Electroluminescence from Si/SiO2 films deposited on p-Si substrates

    Institute of Scientific and Technical Information of China (English)

    马书懿; 萧勇; 陈辉

    2002-01-01

    The structure of Au/Si/SiO2/p-Si has been fabricated using the magnetron sputtering technique. It has a verygood rectifying behaviour. Visible electroluminescence (EL) has been observed from the Au/Si/SiO2/p-Si structureat a forward bias of 5V or larger. A broad band with one peak around 650-660 nm appears in all the EL spectra ofthe structure. The effects of the thickness of the Si layer in the Si/SiO2 films and of the input electrical power on ELspectra are studied systematically.

  1. Influence of Si on Interfacial Combination of SiCp/Al-Mg-Si Composite

    Institute of Scientific and Technical Information of China (English)

    Han Jianmin; Li Ronghua; Li Mingwei; Cui Shihai; Li Weijing; Wang Jinhua

    2004-01-01

    The scanning electron microscopy (SEM) analysis results of Si distribution in the interface between SiC reinforcements and aluminum matrix of a stir casting SiCp/Al-Mg-Si composite were presented. Results show that there is Si precipitation deposit on the interface of the composite and Si connects with SiC reinforcements in one side and connects with aluminum matrix in the other side. Si phase plays as a connecting bridge, which contributes to the interfacial combination of SiCp/Al composite.

  2. Gender Ratio in Dyslexia.

    Science.gov (United States)

    Miles, T. R.; Haslum, M. N.; Wheeler, T. J.

    1998-01-01

    A study involving 11,804 British children (age 10) found that when specified criteria for dyslexia were used, 269 children qualified as dyslexic. These included 223 boys and 46 girls, for a ratio of 4.51 to 1. Difficulties in interpreting these data are discussed and a defense of the criteria is provided. (Author/CR)

  3. The rectilinear Steiner ratio

    Directory of Open Access Journals (Sweden)

    PO de Wet

    2005-06-01

    Full Text Available The rectilinear Steiner ratio was shown to be 3/2 by Hwang [Hwang FK, 1976, On Steiner minimal trees with rectilinear distance, SIAM Journal on Applied Mathematics, 30, pp. 104– 114.]. We use continuity and introduce restricted point sets to obtain an alternative, short and self-contained proof of this result.

  4. Preparation of Si3N4 Form Diatomite via a Carbothermal Reduction-Nitridation Process

    Science.gov (United States)

    Ma, Bin; Huang, Zhaohui; Mei, Lefu; Fang, Minghao; Liu, Yangai; Wu, Xiaowen; Hu, Xiaozhi

    2016-05-01

    Si3N4 was produced using diatomite and sucrose as silicon and carbon sources, respectively. The effect of the C/SiO2 molar ratio, heating temperature and soaking time on the morphology and phase compositions of the final products was investigated by scanning electron microscopy, x-ray diffraction analysis and energy dispersive spectroscopy. The phase equilibrium relationships of the system at different heating temperatures were also investigated based on the thermodynamic analysis. The results indicate that the phase compositions depended on the C/SiO2 molar ratio, heating temperature and soaking time. Fabrication of Si3N4 from the precursor via carbothermal reduction nitridation was achieved at 1550°C for 1-8 h using a C/SiO2 molar ratio of 3.0. The as-prepared Si3N4 contained a low amount of Fe3Si (<1 wt.%).

  5. Effect of Si on the reversibility of stress-induced martensite in Fe-Mn-Si shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Stanford, N. [Centre for Material and Fibre Innovation, Deakin University, Geelong, Victoria 3217 (Australia); Dunne, D.P., E-mail: druce_dunne@uow.edu.au [Faculty of Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia)

    2010-12-15

    Fe-Mn-Si is a well-characterized ternary shape memory alloy. Research on this alloy has consistently shown that the addition of 5-6 wt.% Si is desirable to enhance the reversibility of stress-induced martensite vis-a-vis shape memory. This paper examines the effect of Si on the morphology and the crystallography of the martensite in the Fe-Mn-Si system. It is concluded that the addition of Si increases the c/a ratio of the martensite, reduces the transformation volume change and decreases the atomic spacing difference between the parallel close-packed directions in the austenite-martensite interface (habit) plane. It is proposed that, in addition to austenite strengthening, Si enhances reversibility by reducing the volume change and the interfacial atomic mismatch between the martensite and the austenite. Although shape memory is improved, transformation reversibility remains limited by the necessary misfit dislocations that accommodate the atomic spacing differences in the interface.

  6. Effect of tip vortices on membrane vibration of flexible wings with different aspect ratios

    Directory of Open Access Journals (Sweden)

    Genç Mustafa Serdar

    2016-01-01

    Full Text Available In this study, the effect of the aspect ratio on the aerodynamics characteristic of flexible membrane wings with different aspect ratios (AR = 1 and AR = 3 is experimentally investigated at Reynolds number of 25000. Time accurate measurements of membrane deformation using Digital Image Correlation system (DIC is carried out while normal forces of the wing will be measured by helping a load-cell system and flow on the wing was visualized by means of smoke wire technic. The characteristics of high aspect ratio wings are shown to be affected by leading edge separation bubbles at low Reynolds number. It is concluded that the camber of membrane wing excites the separated shear layer and this situation increases the lift coefficient relatively more as compared to rigid wings. In membrane wings with low aspect ratio, unsteadiness included tip vortices and vortex shedding, and the combination of tip vortices and vortex shedding causes complex unsteady deformations of these membrane wings. The characteristic of high aspect ratio wings was shown to be affected by leading edge separation bubbles at low Reynolds numbers whereas the deformations of flexible wing with low aspect ratio affected by tip vortices and leading edge separation bubbles.

  7. Introduction of atomic H into Si3N4/SiO2/Si stacks

    Institute of Scientific and Technical Information of China (English)

    JIN Hao; WEBER K.J.; LI Weitang; BLAKERS A.W.

    2006-01-01

    Atomic H generated by a plasma NH3 source at 400 ℃ was demonstrated to passivate dehydrogenated Si3N4/SiO2/Si stacks effectively by bonding with defectsin the Si3N4 film and at the Si-SiO2 interface. A subsequent anneal in N2 after atomic H reintroduction was demonstrated to further improve passivation of the Si-SiO2 interface. Isothermal and isochronal anneals in N2 were carried out in order to determine the optimized annealing conditions.

  8. One-dimensional Si nanolines in hydrogenated Si(001)

    Science.gov (United States)

    François, Bianco; Köster, Sigrun A.; Owen, James G. H.; Renner, Christoph; Bowler, David R.

    2012-02-01

    We present a detailed study of the structural and electronic properties of a self-assembled silicon nanoline embedded in the H-terminated silicon (001) surface, known as the Haiku stripe. The nanoline is a perfectly straight and defect free endotaxial structure of huge aspect ratio; it can grow micrometre long at a constant width of exactly four Si dimers (1.54 nm). Another remarkable property is its capacity to be exposed to air without suffering any degradation. The nanoline grows independently of any step edges at tunable densities, from isolated nanolines to a dense array of nanolines. In addition to these unique structural characteristics, scanning tunnelling microscopy and density functional theory reveal a one-dimensional state confined along the Haiku core. This nanoline is a promising candidate for the long sought after electronic solid-state one-dimensional model system to explore the fascinating quantum properties emerging in such reduced dimensionality. Phys. Rev. B, 84, 035328 (2011)

  9. Electro-physical properties of a Si-based MIS structure with a low-k SiOC(-H) film

    Energy Technology Data Exchange (ETDEWEB)

    Zakirov, Anvar Sagatovich; Navamathavan, Rangaswamy; Kim, Seung Hyun; Jang, Yong Jun; Jung, An Soo; Choi, Chi Kyu [Cheju National University, Jeju (Korea, Republic of)

    2006-09-15

    SiOC(-H) films with low dielectric constants have been prepared by using plasma enhanced chemical vapor deposition with a mixture of methyltriethoxysilane and oxygen precursors. The C-V characteristics of the structures, Al/SiOC(-H)/p-Si(100), were studied in the forward and the reverse directions by applying a polarizing potential. We found that the ratio of the maximum to the minimum capacitance (C{sub ma}x{sub /}C{sub min}) depended on the [MTES/(MTES+O{sub 2})] flow rate ratio. Annealed samples exhibited even greater reductions of the maximum capacitance and the dielectric constant of the SiOC(-H) samples. After annealing at 400 .deg. C, the measurement in the reverse direction revealed an interesting behavior in the form of strongly pronounced 'steps'. The bonds between Si-O and the -CH{sub 3} group reduced the surface charge density, and the distribution of the surface charge density depended on [MTES/(MTES+O{sub 2})] flow rate ratio and the annealing temperature because the fixed positive (Si-CH{sub 3}){sup +} and negative (Si-O){sup -} changed the configuration at the SiOC(-H)/p-Si(100) interface. The SiOC(-H) film had donor (O{sub 2}) and acceptor (Si-CH{sub 3} -groups) levels, and the electronic process at the SiOC(-H)/p-Si(100) interface was defined by the (Si-CH{sub 3}){sup +} and the (Si-O){sup -} bonds.

  10. Photoluminescence Properties of Nanocrystalline 3C-SiC Films

    Institute of Scientific and Technical Information of China (English)

    YU Wei; LU Xue-qin; LU Wan-bing; HAN Li; FU Guang-sheng

    2006-01-01

    Nanocrystalline (nc) 3C-SiC films on the Si substrate were prepared by the helicon wave plasma enhanced chemical vapor deposition (HW-PECVD) technique. With the SiH4-CH4 gas flow ratio changing, the films exhibit different photoluminescence (PL) characteristics. Under the stoichiometric condition, the PL peak redshift from 470 nm to 515 nm is detected with the increase of excitation wavelength, which can be attributed to the quantum confinement effect radiation of 3C-SiC nanocrystals of different sizes. However, the appearance of an additional PL band at 436 nm in Si-rich film might be sourced back to the excess of Si defect centers in it. This is also the case for C-rich film for its PL band lying at 570 nm. The results above quoted indicate an important influence of gas flow ratio on the PL properties of the SiC films providing an effective guidance for analyzing the luminescence mechanism and exploring the high-efficiency light emission of the SiC films.

  11. Breaking the limits of line width and aspect ratio for inkjet printed conductive lines by controlling post-deposition ink contraction

    NARCIS (Netherlands)

    Teunissen, P.; Abbel, R.J.; Michels, J.J.; Groen, P.

    2014-01-01

    Electrically conductive structures comprising both narrow line widths and high aspect ratios are indispensable components of many electronic devices. Producing them reliably on an industrial scale by inkjet printing of metal-based inks is a serious challenge. Firstly, due to spreading of the ink on

  12. Studies on a novel mask technique with high selectivity and aspect-ratio patterns for HgCdTe trenches ICP etching

    Science.gov (United States)

    Ye, Z. H.; Hu, W. D.; Li, Y.; Huang, J.; Yin, W. T.; Lin, C.; Hu, X. N.; Ding, R. J.; Chen, X. S.; Lu, W.; He, L.

    2012-06-01

    A novel mask technique, combining high selectivity silicon dioxide patterns over high aspect-ratio photoresist (PR) patterns has been exploited to perform mesa etching for device delineation and electrical isolation of HgCdTe third-generation infrared focal plane arrays (IRFPAs). High-density silicon dioxide film covering high aspect-ratio PR patterns was deposited at the temperature of 80°C and silicon dioxide film patterns over high aspect-ratio PR patterns of HgCdTe etching samples was developed by standard photolithography and wet chemical etch. Scanning electron microscopy (SEM) shows that the surfaces of inductively coupled plasma (ICP) etched samples are quite clean and smooth. The etching selectivity between the novel mask and HgCdTe of the samples is increased to above 32: 1 while the side-wall impact of etching plasma is suppressed by the high aspect ratio patterns. These results show that the combined patterning of silicon dioxide film and thick PR film is a readily available and promising masking technique for HgCdTe mesa etching.

  13. The corrosion behavior of CVI SiC matrix in SiCf/SiC composites under molten fluoride salt environment

    Science.gov (United States)

    Wang, Hongda; Feng, Qian; Wang, Zhen; Zhou, Haijun; Kan, Yanmei; Hu, Jianbao; Dong, Shaoming

    2017-04-01

    High temperature corrosion behavior and microstructural evolution of designed chemical-vapor-infiltrated SiC matrix in SiC fiber reinforced SiC ceramic matrix composites in 46.5LiF-11.5NaF-42.0KF (mol. %) eutectic salt at 800 °C for various corrosion time was studied. Worse damage was observed as extending the exposure time, with the mass loss ratio increasing from 0.716 wt. % for 50 h to 5.914 wt. % for 500 h. The mass loss rate showed a trend of first decrease and then increase with the extended corrosion exposure. Compared with the near-stoichiometric SiC matrix layers, the O-contained boundaries between deposited matrix layers and the designed Si-rich SiC matrix layers were much less corrosion resistant and preferentially corroded. Liner relationship between the mass loss ratio and the corrosion time obtained from 50 h to 300 h indicated that the corrosion action was reaction-control process. Further corrosion would lead to matrix layer exfoliation and higher mass loss ratio.

  14. Electronic Structure of Si1-xIVx/Si Superlattices on Si(001)

    Institute of Scientific and Technical Information of China (English)

    CHEN Jie; L(U) Tie-Yu; HUANG Mei-Chun

    2007-01-01

    We have preformed systematical ab initio studies of the structural and electronic properties of short-period Si1-xIVx/Si (x = 0.125, 0.25, 0.5,IV=Ge, Sn) superlattices (SLs) grown along the [001] direction on bulk Si. The present calculations reveal that the Si0.875 Ge0.125/Si, Si0.75 Ge0.25/Si and Si0.875Sn0.125/Si axe the Γ-point direct bandgap semiconductors. The technological importance lies in the expectation that the direct gap Si1-xIVx/Si SLs may be used as components in integrated optoelectronic devices, in conjunction with the already well-established and highly advanced silicon technology.

  15. Photoelectric properties of n-SiC/n-Si heterojunctions

    Directory of Open Access Journals (Sweden)

    Semenov A. V.

    2012-10-01

    Full Text Available Photovoltaic effect in isotype heterotructure formed by nanocrystalline silicon carbide films on single crystal n-Si substrates (n-SiC/n-Si heterojunction was studied. The films were produced by direct ionic deposition method. The model that takes into account the quantum wells and potential barriers caused by band offsets was proposed to explain the current-voltage characteristics and photovoltaic properties of the heterostructure n-SiC/n-Si.

  16. Tau hadronic branching ratios

    CERN Document Server

    Buskulic, Damir; De Bonis, I; Décamp, D; Ghez, P; Goy, C; Lees, J P; Lucotte, A; Minard, M N; Odier, P; Pietrzyk, B; Ariztizabal, F; Chmeissani, M; Crespo, J M; Efthymiopoulos, I; Fernández, E; Fernández-Bosman, M; Gaitan, V; Martínez, M; Orteu, S; Pacheco, A; Padilla, C; Palla, Fabrizio; Pascual, A; Perlas, J A; Sánchez, F; Teubert, F; Colaleo, A; Creanza, D; De Palma, M; Farilla, A; Gelao, G; Girone, M; Iaselli, Giuseppe; Maggi, G; Maggi, M; Marinelli, N; Natali, S; Nuzzo, S; Ranieri, A; Raso, G; Romano, F; Ruggieri, F; Selvaggi, G; Silvestris, L; Tempesta, P; Zito, G; Huang, X; Lin, J; Ouyang, Q; Wang, T; Xie, Y; Xu, R; Xue, S; Zhang, J; Zhang, L; Zhao, W; Bonvicini, G; Cattaneo, M; Comas, P; Coyle, P; Drevermann, H; Engelhardt, A; Forty, Roger W; Frank, M; Hagelberg, R; Harvey, J; Jacobsen, R; Janot, P; Jost, B; Kneringer, E; Knobloch, J; Lehraus, Ivan; Markou, C; Martin, E B; Mato, P; Minten, Adolf G; Miquel, R; Oest, T; Palazzi, P; Pater, J R; Pusztaszeri, J F; Ranjard, F; Rensing, P E; Rolandi, Luigi; Schlatter, W D; Schmelling, M; Schneider, O; Tejessy, W; Tomalin, I R; Venturi, A; Wachsmuth, H W; Wiedenmann, W; Wildish, T; Witzeling, W; Wotschack, J; Ajaltouni, Ziad J; Bardadin-Otwinowska, Maria; Barrès, A; Boyer, C; Falvard, A; Gay, P; Guicheney, C; Henrard, P; Jousset, J; Michel, B; Monteil, S; Pallin, D; Perret, P; Podlyski, F; Proriol, J; Rossignol, J M; Saadi, F; Fearnley, Tom; Hansen, J B; Hansen, J D; Hansen, J R; Hansen, P H; Nilsson, B S; Kyriakis, A; Simopoulou, Errietta; Siotis, I; Vayaki, Anna; Zachariadou, K; Blondel, A; Bonneaud, G R; Brient, J C; Bourdon, P; Passalacqua, L; Rougé, A; Rumpf, M; Tanaka, R; Valassi, Andrea; Verderi, M; Videau, H L; Candlin, D J; Parsons, M I; Focardi, E; Parrini, G; Corden, M; Delfino, M C; Georgiopoulos, C H; Jaffe, D E; Antonelli, A; Bencivenni, G; Bologna, G; Bossi, F; Campana, P; Capon, G; Chiarella, V; Felici, G; Laurelli, P; Mannocchi, G; Murtas, F; Murtas, G P; Pepé-Altarelli, M; Dorris, S J; Halley, A W; ten Have, I; Knowles, I G; Lynch, J G; Morton, W T; O'Shea, V; Raine, C; Reeves, P; Scarr, J M; Smith, K; Smith, M G; Thompson, A S; Thomson, F; Thorn, S; Turnbull, R M; Becker, U; Braun, O; Geweniger, C; Graefe, G; Hanke, P; Hepp, V; Kluge, E E; Putzer, A; Rensch, B; Schmidt, M; Sommer, J; Stenzel, H; Tittel, K; Werner, S; Wunsch, M; Beuselinck, R; Binnie, David M; Cameron, W; Colling, D J; Dornan, Peter J; Konstantinidis, N P; Moneta, L; Moutoussi, A; Nash, J; San Martin, G; Sedgbeer, J K; Stacey, A M; Dissertori, G; Girtler, P; Kuhn, D; Rudolph, G; Bowdery, C K; Brodbeck, T J; Colrain, P; Crawford, G; Finch, A J; Foster, F; Hughes, G; Sloan, Terence; Whelan, E P; Williams, M I; Galla, A; Greene, A M; Kleinknecht, K; Quast, G; Raab, J; Renk, B; Sander, H G; Wanke, R; Van Gemmeren, P; Zeitnitz, C; Aubert, Jean-Jacques; Bencheikh, A M; Benchouk, C; Bonissent, A; Bujosa, G; Calvet, D; Carr, J; Diaconu, C A; Etienne, F; Thulasidas, M; Nicod, D; Payre, P; Rousseau, D; Talby, M; Abt, I; Assmann, R W; Bauer, C; Blum, Walter; Brown, D; Dietl, H; Dydak, Friedrich; Ganis, G; Gotzhein, C; Jakobs, K; Kroha, H; Lütjens, G; Lutz, Gerhard; Männer, W; Moser, H G; Richter, R H; Rosado-Schlosser, A; Schael, S; Settles, Ronald; Seywerd, H C J; Saint-Denis, R; Wolf, G; Alemany, R; Boucrot, J; Callot, O; Cordier, A; Courault, F; Davier, M; Duflot, L; Grivaz, J F; Heusse, P; Jacquet, M; Kim, D W; Le Diberder, F R; Lefrançois, J; Lutz, A M; Musolino, G; Nikolic, I A; Park, H J; Park, I C; Schune, M H; Simion, S; Veillet, J J; Videau, I; Abbaneo, D; Azzurri, P; Bagliesi, G; Batignani, G; Bettarini, S; Bozzi, C; Calderini, G; Carpinelli, M; Ciocci, M A; Ciulli, V; Dell'Orso, R; Fantechi, R; Ferrante, I; Foà, L; Forti, F; Giassi, A; Giorgi, M A; Gregorio, A; Ligabue, F; Lusiani, A; Marrocchesi, P S; Messineo, A; Rizzo, G; Sanguinetti, G; Sciabà, A; Spagnolo, P; Steinberger, Jack; Tenchini, Roberto; Tonelli, G; Triggiani, G; Vannini, C; Verdini, P G; Walsh, J; Betteridge, A P; Blair, G A; Bryant, L M; Cerutti, F; Gao, Y; Green, M G; Johnson, D L; Medcalf, T; Mir, L M; Perrodo, P; Strong, J A; Bertin, V; Botterill, David R; Clifft, R W; Edgecock, T R; Haywood, S; Edwards, M; Maley, P; Norton, P R; Thompson, J C; Bloch-Devaux, B; Colas, P; Emery, S; Kozanecki, Witold; Lançon, E; Lemaire, M C; Locci, E; Marx, B; Pérez, P; Rander, J; Renardy, J F; Roussarie, A; Schuller, J P; Schwindling, J; Trabelsi, A; Vallage, B; Johnson, R P; Kim, H Y; Litke, A M; McNeil, M A; Taylor, G; Beddall, A; Booth, C N; Boswell, R; Cartwright, S L; Combley, F; Dawson, I; Köksal, A; Letho, M; Newton, W M; Rankin, C; Thompson, L F; Böhrer, A; Brandt, S; Cowan, G D; Feigl, E; Grupen, Claus; Lutters, G; Minguet-Rodríguez, J A; Rivera, F; Saraiva, P; Smolik, L; Stephan, F; Apollonio, M; Bosisio, L; Della Marina, R; Giannini, G; Gobbo, B; Ragusa, F; Rothberg, J E; Wasserbaech, S R; Armstrong, S R; Bellantoni, L; Elmer, P; Feng, Z; Ferguson, D P S; Gao, Y S; González, S; Grahl, J; Harton, J L; Hayes, O J; Hu, H; McNamara, P A; Nachtman, J M; Orejudos, W; Pan, Y B; Saadi, Y; Schmitt, M; Scott, I J; Sharma, V; Turk, J; Walsh, A M; Wu Sau Lan; Wu, X; Yamartino, J M; Zheng, M; Zobernig, G

    1996-01-01

    From 64492 selected \\tau-pair events, produced at the Z^0 resonance, the measurement of the tau decays into hadrons from a global analysis using 1991, 1992 and 1993 ALEPH data is presented. Special emphasis is given to the reconstruction of photons and \\pi^0's, and the removal of fake photons. A detailed study of the systematics entering the \\pi^0 reconstruction is also given. A complete and consistent set of tau hadronic branching ratios is presented for 18 exclusive modes. Most measurements are more precise than the present world average. The new level of precision reached allows a stringent test of \\tau-\\mu universality in hadronic decays, g_\\tau/g_\\mu \\ = \\ 1.0013 \\ \\pm \\ 0.0095, and the first measurement of the vector and axial-vector contributions to the non-strange hadronic \\tau decay width: R_{\\tau ,V} \\ = \\ 1.788 \\ \\pm \\ 0.025 and R_{\\tau ,A} \\ = \\ 1.694 \\ \\pm \\ 0.027. The ratio (R_{\\tau ,V} - R_{\\tau ,A}) / (R_{\\tau ,V} + R_{\\tau ,A}), equal to (2.7 \\pm 1.3) \\ \\%, is a measure of the importance of Q...

  17. Interfacial reaction of eutectic AuSi solder with Si (100) and Si (111) surfaces

    Science.gov (United States)

    Jang, Jin-Wook; Hayes, Scott; Lin, Jong-Kai; Frear, Darrel R.

    2004-06-01

    The dissolution behavior of Si (100) and (111) dies by eutectic AuSi solder was investigated. On the Si (100) surface, the dissolution primarily occurred by the formation of craters resulting in a rough surface. The dissolution of the Si (111) resulted in a relatively smooth surface. The morphology of the Si (100) surface during a AuSi soldering reaction exhibited more time-dependent behavior and the etching craters on a Si (100) surface grew larger with time whereas Si (111) did not significantly change. This difference was ascribed to the surface energy differences between Si (111) and (100) surfaces that resulted in the two- and three-dimensional dissolution behaviors, respectively. This difference plays an important role in the formation of voids during the AuSi die bonding. The etching craters on Si (100) act as a AuSi solder sink and the regions surrounded by etch pits tend to become voids. For Si (111), flat surfaces were observed in the voided regions. Cross section analysis showed that no solder reaction occurred in the voided region of the Si (111) surface. This suggests the possibility of the formation of a thin inert layer in a potentially voided region prior to assembly. To achieve void-free die bonding, different parameters must be adjusted to the Si (100) and Si (111) surfaces with the AuSi alloy.

  18. Tunneling magnetoresistance in Fe{sub 3}Si/MgO/Fe{sub 3}Si(001) magnetic tunnel junctions

    Energy Technology Data Exchange (ETDEWEB)

    Tao, L. L.; Liang, S. H.; Liu, D. P.; Wei, H. X.; Han, X. F., E-mail: xfhan@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Wang, Jian [Department of Physics and the Center of Theoretical and Computational Physics, The University of Hong Kong, Hong Kong (China)

    2014-04-28

    We present a theoretical study of the tunneling magnetoresistance (TMR) and spin-polarized transport in Fe{sub 3}Si/MgO/Fe{sub 3}Si(001) magnetic tunnel junction (MTJ). It is found that the spin-polarized conductance and bias-dependent TMR ratios are rather sensitive to the structure of Fe{sub 3}Si electrode. From the symmetry analysis of the band structures, we found that there is no spin-polarized Δ{sub 1} symmetry bands crossing the Fermi level for the cubic Fe{sub 3}Si. In contrast, the tetragonal Fe{sub 3}Si driven by in-plane strain reveals half-metal nature in terms of Δ{sub 1} state. The giant TMR ratios are predicted for both MTJs with cubic and tetragonal Fe{sub 3}Si electrodes under zero bias. However, the giant TMR ratio resulting from interface resonant transmission for the former decreases rapidly with the bias. For the latter, the giant TMR ratio can maintain up to larger bias due to coherent transmission through the majority-spin Δ{sub 1} channel.

  19. Correlation between Light Emissions from Amorphous-Si:H/SiO2 and nc-Si/SiO2 Multilayers

    Institute of Scientific and Technical Information of China (English)

    MA Zhong-Yuan; HUANG Xin-Fan; CHEN Kun-Ji; FENG Duan; HAN Pei-Gao; LI Wei; CHEN De-Yuan; WEI De-Yuan; QIAN Bo; LI Wei; XU Jun; XU Ling

    2007-01-01

    We investigate the properties of light emission from amorphous-Si:H/SiO2 and nc-Si/SiO2 multilayers (MLs). The size dependence of light emission is well exhibited when the a-Si:H sublayer thickness is thinner than 4nm and the interface states are well passivated by hydrogen. For the nc-Si/SiO2 MLs, the oxygen modified interface states and nanocrystalline silicon play a predominant role in the properties of light emission. It is found that the light emission from nc-Si/SiO2 is in agreement with the model of interface state combining with quantum confinement when the size of nc-Si is smaller than 4 nm. The role of hydrogen and oxygen is discussed in detail.

  20. Effect of mixing ratio of food waste and rice husk co-digestion and substrate to inoculum ratio on biogas production.

    Science.gov (United States)

    Haider, Muhammad Rizwan; Zeshan; Yousaf, Sohail; Malik, Riffat Naseem; Visvanathan, Chettiyappan

    2015-08-01

    Aim of this study was to find out suitable mixing ratio of food waste and rice husk for their co-digestion in order to overcome VFA accumulation in digestion of food waste alone. Four mixing ratios of food waste and rice husk with C/N ratios of 20, 25, 30 and 35 were subjected to a lab scale anaerobic batch experiment under mesophilic conditions. Highest specific biogas yield of 584L/kgVS was obtained from feedstock with C/N ratio of 20. Biogas yield decreased with decrease in food waste proportion. Further, fresh cow dung was used as inoculum to investigate optimum S/I ratio with the selected feedstock. In experiment 2, feedstock with C/N ratio 20 was subjected to anaerobic digestion at five S/I ratios of 0.25, 0.5, 1.0, 1.5 and 2.0. Specific biogas yield of 557L/kgVS was obtained at S/I ratio of 0.25. However, VFA accumulation occurred at higher S/I ratios due to higher organic loadings.

  1. Fabrication of ZrC/SiC, ZrO2/SiC and ZrO2 powders by carbothermal reduction of ZrSiO4

    Directory of Open Access Journals (Sweden)

    Ljiljana Kljajević

    2011-06-01

    Full Text Available The zirconia/silicon carbide (ZrO2 /SiC and ZrO2 powders are prepared by carbothermal reduction of natural mineral zircon (ZrSiO4. The zircon powder was mixed with activated carbon as a reducing agent and heattreated in a controlled flow atmosphere of Ar. Phase evolution and phase content were followed as a function of temperature (1573–1973 K and C/ZrSiO4 ratio (C/ZrSiO4 = 1, 4, 5 and 7, by means of ex-situ X-ray diffraction and SEM/EDS analysis. By varying the temperature and C/ZrSiO4 ratio, different powder compositions were obtained (m-ZrO2; m-ZrO2/c-ZrO2; c-ZrO2; c-ZrO2/SiC.

  2. A comparative study of electroluminescence from Ge/SiO2 and Si/SiO2 films

    Institute of Scientific and Technical Information of China (English)

    Ma Shu-Yi; Chen Hui; Xiao Yong; Ma Zi-Jun; Sun Ai-Min

    2004-01-01

    Ge/SiO2 and Si/SiO2 films were deposited using the two-target alternation magnetron sputtering technique. The Au/Ge/SiO2/p-Si and Au/Si/SiO2/p-Si structures were fabricated and their electroluminescence (EL) characteristics were comparatively studied. Both Au/Ge/SiO2/p-Si and Au/Si/SiO2/p-Si structures have rectifying property. All the EL spectra from the two types of the structure have peak positions around 650-660 nm. The EL mechanisms of the structures are discussed.

  3. a-Si/c-Si heterojunction solar cells on SiSiC ceramic substrates

    Institute of Scientific and Technical Information of China (English)

    LI Xudong; XU Ying; CHE Xiaoqi

    2006-01-01

    Silicon thin-film solar cells are considered to be one of the most promising cells in the future for their potential advantages, such as low cost, high efficiency, great stability, simple processing, and none-pollution. In this paper, latest progress on poly-crystalline silicon solar cells on ceramic substrates achieved by our group was reported. Rapid thermal chemical vapor deposition (RTCVD) was used to deposited poly-crystalline silicon thin films, and the grains of as-grown film were enlarged by Zone-melting Recrystallization (ZMR). As a great changein cell's structure, traditional diffused pn homojunction was replaced by a-Si/c-Si heterojunction, which lead is to distinct improvement in cell's efficiency.A conversion efficiency of 3.42% has been achieved on 1cm2 a-Si/c-Si heterojunction solar cell ( Isc =16.93 mA, Voc =310.9 mV, FF =06493, AM =1.5 G,24 ℃), while the cell with diffused homojunction only gotan efficiency of 0.6%. It indicates that a-Si emitter formed at low temperature might be more suitable for thin film cell on ceramics.

  4. H2-Ar dilution for improved c-Si quantum dots in P-doped SiNx:H thin film matrix

    Science.gov (United States)

    Liu, Jia; Zhang, Weijia; Liu, Shengzhong (Frank)

    2017-02-01

    Phosphorus-doped hydrogenated silicon nitride (SiNx:H) thin films containing crystalline silicon quantum dot (c-Si QD) was prepared by plasma enhanced chemical vapor deposition (PECVD) using hydrogen-argon mixed dilution. The effects of H2/Ar flow ratio on the structural, electrical and optical characteristics of as-grown P-doped SiNx:H thin films were systematically investigated. Experimental results show that crystallization is promoted by increasing the H2/Ar flow ratio in dilution, while the N/Si atomic ratio is higher for thin film deposited with argon-rich dilution. As the H2/Ar flow ratio varies from 100/100 to 200/0, the samples exhibit excellent conductivity owing to the large volume fraction of c-Si QDs and effective P-doping. By adjusting the H2/Ar ratio to 100/100, P-doped SiNx:H thin film containing tiny and densely distributed c-Si QDs can be obtained. It simultaneously possesses wide optical band gap and high dark conductivity. Finally, detailed discussion has been made to analyze the influence of H2-Ar mixed dilution on the properties of P-doped SiNx:H thin films.

  5. Features of Mg2Si Layer Growth in Si/Mg2Si Multilayers

    Directory of Open Access Journals (Sweden)

    L.E. Konotopskyi

    2016-06-01

    Full Text Available Features of magnesium siliced layer growth in Si/Mg2Si multilayers in initial state and after thermal annealing were studied by methods of transmission electron microscopy and X-Ray scattering. As-deposited magnesium silicide layers are amorphous with nanocrystal inclusions of metastable h-Mg2Si. Formation of Mg2Si in hexagonal modification occurs under the influence of stress produced by silicon layers. At T = 723 К Mg2Si layers finished crystallizes in hexagonal modification, with some coarsening of grains. That is accompanied with 7.3 % reduction in period of the Si/Mg2Si multilayer.

  6. Transport and electroluminescence mechanism in Au/(Si/SiO2)/P-Si film

    Institute of Scientific and Technical Information of China (English)

    ZHANG Kai-biao; MA Shu-yi; MA Zi-jun; CHEN Hai-xia

    2006-01-01

    The samples of Au/(Si/SiO2)/p-Si structure were fabricated by using the R.F magnetron sputtering technique.Its carrier transport and electroluminescence mechanism were studied from the I-V curves and EL spectra by using the Configuration Coordinate as a theoretical model.The result indicates that there are two defect centers in SiO2 films.The electron in Au and the hole in p-Si went into SiO2 film by the Fowler-Nordheim tunneling model at a high bias voltage and recombined through these defect centers in SiO2 film.

  7. Photoreflectance Spectroscopy for Study of Si/SiGe/Si Heterostructure

    Institute of Scientific and Technical Information of China (English)

    Liu Zhihong; Chen Changchun; Lin Huiwang; Xiong Xiaoyi; Dou Weizhi; Tsien Pei-Hsin

    2004-01-01

    UHVCVD-grown Si/Si1- xGex/Si heterostructure was investigated by Photoreflectance spectroscopy (PR). The principle of PR used in semiconductor film was thoroughly described. According to the E1 transition energy in the Si1- xGex alloy, the Ge content in SiGe film with constant composition can be accurately characterized. In this study, determine the composition uniformity of larger diameter SiGe epiwafer by PR mapping technique was determined. These results show PR is very promising for Si1- xGex epilayer characterization with constant Ge content and can provide film measurements for production-worthy line monitor.

  8. Intermediate Gas Phase of CH4/[Si(CH3)2O]5 Plasma and Its Effect on Structure of SiCOH Film

    Institute of Scientific and Technical Information of China (English)

    DU Jie; YE Chao; NING Zhaoyuan; ZHANG Haiyan

    2008-01-01

    This paper investigated the radical behaviour of the plasma of a mixture of methane (CH4) and decamethylcyclopentasiloxane (DMCPS) by optical emission spectroscopy. The plasma was generated by electron cyclotron resonance (ECR) discharge and was used for depositing porous SiCOH low dielectric-constant film. In the ECR discharge plasma, CH, H, H2, C2, Si, O and SiO radicals were obtained. The CH, H and C2radicals were from the dissociation of CH4, while the SiO, Si and O radicals from the dissociation of the Si-O chain. CHx radicals absorbed in the film were thermally unstable and could be removed by annealing. The dissociation of the Si-O chain led to an increase in a ratio of the Si-Ocage to Si-Onetwork. The removed of CHx radicals and the increased Si-Ocage to Si-Onetwork ratio were beneficial for reducing the film density and dielectric constant.

  9. Oxide layer dissolution in Si/SiO{sub x}/Si wafer bonded structures

    Energy Technology Data Exchange (ETDEWEB)

    Pippel, E.; Werner, P.; Goesele, U. [Max-Planck-Institut fuer Mikrostrukturphysik, Halle (Germany); Vdovin, V. [Institute for Chemical Problems of Microelectronics, Moscow (Russian Federation); Institute of Rare Metals Giredmet, Moscow (Russian Federation); Zakharov, N.

    2009-10-15

    The evolution of the interfaces of hydrophilic-bonded Si wafers and the corresponding low-angle twist boundary have been analysed in relation to thermal annealing and their relative crystallographic orientation. Two orientation relationships were investigated: Si<001>/Si<001> and Si<001>/Si<110>, where the interfaces are separated by thin native SiO2 layers. The interfaces were analysed by TEM and STEM/EELS. It is found that the decomposition rate of the intermediate oxide layer and the formation of a Si-Si bonded interface depend very much on the lattice mismatch and on the twist angle. The velocity of the dissolution of the thin oxide layers and the formation of Si-Si bonds at the bonding interface depend on the orientation relations of the corresponding wafers. The processes of interface fusion and the dissolution of oxide layer are discussed. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  10. The property of Si/SiGe/Si heterostructure during thermal budget characterized by HRXRD

    Institute of Scientific and Technical Information of China (English)

    CHEN Chang-Chun; LIU Zhi-Hong; HUANG Wen-Tao; DOU Wei-Zhi; ZHANG Wei; TSIEN Pei-Hsin; ZHU De-Zhang

    2003-01-01

    Si/SiGe/Si heterostructures grown by ultra-high-vacuum chemical vapor deposition (UHVCVD) werecharacterized by Rutherford backscattering/Channeling (RBS/C) together with high resolution X ray diffraction(HRXRD). High quality SiGe base layer was obtained. The Si/SiGe/Si heterostructures were subject to conventionalfurnace annealing and rapid thermal annealing with temperature between 750 ℃ and 910 ℃. Both strain and its re-laxation degree in SiGe layer are calculated by HRXRD combined with elastic theory, which are never reported inother literatures. The rapid thermal annealing at elevated temperature between 880 ℃ and 910 ℃ for very short timehad almost no influence on the strain in Si0.84Ge0. 16 epilayer. However, high temperature (900℃) furnace annealingfor 1h prompted the strain in Si0.84Ge0.16 layer to relax.

  11. Landscape cultivation alters δ30Si signature in terrestrial ecosystems

    Science.gov (United States)

    Vandevenne, Floor; Delvaux, Claire; Hughes, Harold; Ronchi, Benedicta; Clymans, Wim; Barao, Ana Lucia; Govers, Gerard; Cornelis, Jean Thomas; André, Luc; Struyf, Eric

    2015-04-01

    Despite increasing recognition of the importance of biological Si cycling in controlling dissolved Si (DSi) in soil and stream water, effects of human cultivation on the Si cycle remain poorly understood. Sensitive tracer techniques to identify and quantify Si in the soil-plant-water system could be highly relevant in addressing these uncertainties. Stable Si isotopes are promising tools to define Si sources and sinks along the ecosystem flow path, as intense fractionation occurs during chemical weathering and uptake of dissolved Si in plants. Yet they remain underexploited in the end product of the soil-plant system: the soil water. Here, stable Si isotope ratios (δ30Si) of dissolved Si in soil water were measured along a land use gradient (continuous forest, continuous pasture, young cropland and continuous cropland) with similar parent material (loess) and homogenous bulk mineralogical and climatological (Belgium). Soil water δ30Si signatures are clearly separated along the gradient, with highest average signatures in continuous cropland (+1.61%), intermediate in pasture (+1.05%) and young cropland (+0.89%) and lowest in forest soil water (+0.62%). Our data do not allow distinguishing biological from pedogenic/lithogenic processes, but point to a strong interaction of both. We expect that increasing export of light isotopes in disturbed land uses (i.e. through agricultural harvest), and higher recycling of 28Si and elevated weathering intensity (including clay dissolution) in forest systems will largely determine soil water δ30Si signatures of our systems. Our results imply that soil water δ30Si signature is biased through land management before it reaches rivers and coastal zones, where other fractionation processes take over (e.g. diatom uptake and reverse weathering in floodplains). In particular, a direct role of agriculture systems in lowering export Si fluxes towards rivers and coastal systems has been shown. Stable Si isotopes have a large potential

  12. Si/SiGe/Si HBT的直流特性和低频噪声%Si/SiGe/Si HBT's DC Characterization and Its Low-frequency Noise

    Institute of Scientific and Technical Information of China (English)

    廖小平; 张中平

    2003-01-01

    在对Si/SiGe/Si HBT及其Si兼容工艺的研究基础上,研制成功低噪声Si/SiGe/Si HBT,测试和分析了它的直流特性和低频噪声特性,为具有更好的低噪声性能的Si/SiGe/Si HBT的研究建立了基础.

  13. Si/SiO2 quantum dots cause cytotoxicity in lung cells through redox homeostasis imbalance.

    Science.gov (United States)

    Stan, Miruna S; Memet, Indira; Sima, Cornelia; Popescu, Traian; Teodorescu, Valentin S; Hermenean, Anca; Dinischiotu, Anca

    2014-09-05

    Si/SiO2 quantum dots (QDs) are novel particles with unique physicochemical properties that promote them as potential candidates for biomedical applications. Although their interaction with human cells has been poorly investigated, oxidative stress appears to be the main factor involved in the cytotoxicity of these nanoparticles. In this study, we show for the first time the influence of Si/SiO2 QDs on cellular redox homeostasis and glutathione distribution in human lung fibroblasts. The nanoparticles morphology, composition and structure have been investigated using high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), energy-dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) analysis. MRC-5 cells (human lung fibroblasts) were incubated with various concentrations of Si/SiO2 QDs ranging between 25 and 200 μg/mL for up to 72 h. The results of the MTT and sulforhodamine B assays showed that exposure to QDs led to a time-dependent decrease in cell viability and biomass. The increase in reactive oxygen species (ROS) and malondialdehyde (MDA) levels together with the lower glutathione content suggested that the cellular redox homeostasis was altered. Regarding GSH distribution, the first two days of treatment resulted in a localization of GSH mainly in the cytoplasm, while at longer incubation time the nuclear/cytoplasmic ratio indicated a nuclear localization. These modifications of cell redox state also affected the redox status of proteins, which was demonstrated by the accumulation of oxidized proteins and actin S-glutathionylation. In addition, the externalization of phosphatidylserine provided evidence that apoptosis might be responsible for cell death, but necrosis was also revealed. Our results suggest that Si/SiO2 quantum dots exerted cytotoxicity on MRC-5 cells by disturbing cellular homeostasis which had an effect upon protein redox status.

  14. Rapid microwaves synthesis of CoSi{sub x}/CNTs as novel catalytic materials for hydrogenation of phthalic anhydride

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Liangliang [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China); Chen, Xiao; Jin, Shaohua; Guan, Jingchao [Laboratory of Advanced Materials and Catalytic Engineering, Dalian University of Technology, Dalian 116024 (China); Williams, Christopher T. [Department of Chemical Engineering, University of South Carolina, Columbia, SC 29208 (United States); Peng, Zhijian, E-mail: pengzhijian@cugb.edu.cn [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China); Liang, Changhai, E-mail: changhai@dlut.edu.cn [Laboratory of Advanced Materials and Catalytic Engineering, Dalian University of Technology, Dalian 116024 (China)

    2014-09-15

    CoSi{sub x}/CNTs catalysts with different CoSi{sub x} phases (CoSi, CoSi{sub 2}) have been rapidly synthesized via a microwave-assisted route and applied for the liquid phase hydrogenation of phthalic anhydride. The synthesized catalysts were analyzed and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy-energy dispersive X-ray spectroscopy, thermogravimetric/derivative thermogravimetric analysis. The reaction progress of cobalt silicides and the ratio of Co:Si were monitored at different microwave irradiation times by XRD, giving insight into the formation mechanism. Compared to the Co/CNTs catalyst, all the prepared CoSi{sub x}/CNTs catalysts exhibited excellent activity and good selectivity to phthalide under mild reaction conditions (180–220 °C and 4.0 MPa H{sub 2}). This novel methodology can be applied to the synthesis of other transition metal silicides such as FeSi, Ni{sub 2}Si, and Cu{sub 4}Si. - Graphical abstract: CoSi{sub x}/CNTs catalysts with different CoSi{sub x} phases (CoSi{sub 2}, CoSi) have been rapidly synthesized via microwave-assisted route, which involves the vaporization of CoCl{sub 2} and subsequent reaction of CoCl{sub 2} with Si. - Highlights: • CoSi{sub x}/CNTs catalysts have been rapid synthesized via microwave-assisted route. • The phases of CoSi{sub x} were controlled by varying microwave time and Co:Si ratio. • FeSi, Ni{sub 2}Si and Cu{sub 4}Si were also synthesized via microwave-assisted route. • CoSi{sub x}/CNTs catalysts can be applied in hydrogenation of phthalic anhydride.

  15. Molecular dynamics of structural properties of molten CaO-SiO2 with varying composition

    Institute of Scientific and Technical Information of China (English)

    吴永全; 黄世萍; 尤静林; 蒋国昌

    2002-01-01

    Molecular dynamics simulations of the xCaO-(1-x)SiO2 melts (x varying with the composition of melt) were performed to achieve some structural information. It is found that the first peak positions of Si-Si, Si-O and O-O partial radial distribution functions RDFs(3.165, 1.612  and 2.6 )agree very well with those of x-ray diffraction experiments. The discovered relation of coordinate number NSi-Si(r0) with the molar ratio of CaO is linear and the slope is -0.05617. The average bond lengths of Si-Ob and Si-Onb are 1.6275~1.630 and 1.595~1.60, respectively. Both distribution curves of the angles O-Si-O and Si-O-Si show one peak. For the distribution of angle O-Si-O the positions of the peaks are just a little less than the typical tetrahedral angle 109.5°. And for angle Si-O-Si the positions of peaks fluctuate in the range from 148° to 151°. At last, the distribution of five Si-O tetrahedra was obtained and discussed.

  16. Theoretical Investigations of Si-Ge Alloys in P42/ncm Phase: First-Principles Calculations

    Science.gov (United States)

    Ma, Zhenyang; Liu, Xuhong; Yu, Xinhai; Shi, Chunlei; Yan, Fang

    2017-01-01

    The structural, mechanical, anisotropic, electronic and thermal properties of Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase are investigated in this work. The calculations have been performed with an ultra-soft pseudopotential by using the generalized gradient approximation and local density approximation in the framework of density functional theory. The achieved results for the lattice constants and band gaps of P42/ncm-Si and P42/ncm-Ge in this research have good accordance with other results. The calculated elastic constants and elastic moduli of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase are better than that of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/mnm phase. The Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase exhibit varying degrees of mechanical anisotropic properties in Poisson’s ratio, shear modulus, Young’s modulus, and universal anisotropic index. The band structures of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase show that they are all indirect band gap semiconductors with band gap of 1.46 eV, 1.25 eV, 1.36 eV and 1.00 eV, respectively. In addition, we also found that the minimum thermal conductivity κmin of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase exhibit different degrees of anisotropic properties in (001), (010), (100) and (01¯0) planes. PMID:28772964

  17. Theoretical Investigations of Si-Ge Alloys in P42/ncm Phase: First-Principles Calculations

    Directory of Open Access Journals (Sweden)

    Zhenyang Ma

    2017-05-01

    Full Text Available The structural, mechanical, anisotropic, electronic and thermal properties of Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase are investigated in this work. The calculations have been performed with an ultra-soft pseudopotential by using the generalized gradient approximation and local density approximation in the framework of density functional theory. The achieved results for the lattice constants and band gaps of P42/ncm-Si and P42/ncm-Ge in this research have good accordance with other results. The calculated elastic constants and elastic moduli of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase are better than that of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/mnm phase. The Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase exhibit varying degrees of mechanical anisotropic properties in Poisson’s ratio, shear modulus, Young’s modulus, and universal anisotropic index. The band structures of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase show that they are all indirect band gap semiconductors with band gap of 1.46 eV, 1.25 eV, 1.36 eV and 1.00 eV, respectively. In addition, we also found that the minimum thermal conductivity κmin of the Si, Si0.667Ge0.333, Si0.333Ge0.667 and Ge in P42/ncm phase exhibit different degrees of anisotropic properties in (001, (010, (100 and (01¯0 planes.

  18. Matrix-grain-bridging contributions to the toughness of SiC composites with alumina-coated SiC platelets

    Energy Technology Data Exchange (ETDEWEB)

    Cao, J.J.; He, Y.; MoberlyChan, W.J.; De Jonghe, L.C. [Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering]|[Lawrence Berkeley Lab., CA (United States). Materials Science Div.

    1996-05-01

    Silicon carbide composites were fabricated through the incorporation of alumina-coated SiC platelets into a SiC matrix. Mechanical properties were evaluated in direct comparison with a commercial Hexoloy SiC. The fracture toughness of the composite, with a fine grained {beta}-SiC matrix, was twice that of the commercial material. The alumina-coating on the platelets provided a weak interface to promote crack deflection and platelet bridging, as well as easing densification of the composites. On the other hand, a three-fold increase in fracture toughness (9.1 MPa {radical}m) of an in situ toughened monolithic SiC was achieved by processing at higher temperatures, promoting the {beta}-to-{alpha} phase transformation and forming a microstructure containing high-aspect-ration plate-shaped grains. Efforts were made to combine the effects of coated-platelets reinforcement and in situ toughening in the matrix. Moderate high toughness (8 MPa {radical}m) was achieved by coupled toughening. The contribution of matrix-grain-bridging, however, was limited by the processing temperature at which the oxide coating was stable.

  19. Effect of Si/Si1-yCy/Si Barriers on the Characteristics of Si1-xGex/Si Resonant Tunneling Structures

    Institute of Scientific and Technical Information of China (English)

    HAN Ping; CHENG Xue-Mei; Masao Sakuraba; YoungCheon Jeong; Takashi Matsuura; Junichi Murota

    2000-01-01

    P-type double barrier resonant tunneling diodes (RTD) with the single Si0.6Ge0.4 quantum well and double Si0.6 Ge0.4 spacer have been realized by using an ultra clean low-pressure chemical vapor deposition system. The effect of Si1-yCy layer on the characteristics of the devices was shown by comparing the current-voltage (Ⅰ-Ⅴ) characteristics of RTD's of the barriers of Si layers with that of Si/Si1-yCy/Si structures. The peak voltage was gradually increased and the resonant current decreased obviously with increasing C content in the Si/Si1-yCy/Si barriers. The origin of the phenomena above can be attributed to the C related deep acceptor levels in the Si/Si1-yCy/Si barriers. The possible mechanism for the observed Ⅰ-Ⅴcharacteristics was shown more clearly by increasing C content to 3% and changing the thicknesses of Si and Si1-yCy layers in the Si/Si1-yCy/Si barriers.

  20. High-Ratio Gear Train

    Science.gov (United States)

    Lefever, A. E.

    1982-01-01

    Proposed arrangement of two connected planetary differentials results in gear ratio many times that obtainable in conventional series gear assembly of comparable size. Ratios of several thousand would present no special problems. Selection of many different ratios is available with substantially similar gear diameters. Very high gear ratios would be obtained from small mechanism.

  1. Residual stress in thick low-pressure chemical-vapor deposited polycrystalline SiC coatings on Si substrates

    Science.gov (United States)

    Choi, D.; Shinavski, R. J.; Steffier, W. S.; Spearing, S. M.

    2005-04-01

    Residual stress in thick coatings of polycrystalline chemical-vapor deposited SiC on Si substrates is a key variable that must be controlled if SiC is to be used in microelectromechanical systems. Studies have been conducted to characterize the residual stress level as a function of deposition temperature, Si wafer and SiC coating thickness, and the ratios of methyltrichlorosilane to hydrogen and hydrogen chloride. Wafer curvature was used to monitor residual stress in combination with a laminated plate analysis. Compressive intrinsic (growth) stresses were measured with magnitudes in the range of 200-300MPa; however, these can be balanced with the tensile stress due to the thermal-expansion mismatch to leave near-zero stress at room temperature. The magnitude of the compressive intrinsic stress is consistent with previously reported values of surface stress in combination with the competition between grain-boundary energy and elastic strain energy.

  2. Relaxed SiGe-on-insulator fabricated by dry oxidation of sandwiched Si/SiGe/Si structure

    Energy Technology Data Exchange (ETDEWEB)

    Di Zengfeng [Research Center of Semiconductor Functional Film Engineering Technology and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology (SIMIT), Chinese Academy of Sciences (CAS), Shanghai 200050 (China); Department of Physics and Material Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Zhang Miao [Research Center of Semiconductor Functional Film Engineering Technology and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology (SIMIT), Chinese Academy of Sciences (CAS), Shanghai 200050 (China); Liu Weili [Research Center of Semiconductor Functional Film Engineering Technology and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology (SIMIT), Chinese Academy of Sciences (CAS), Shanghai 200050 (China); Zhu Ming [Research Center of Semiconductor Functional Film Engineering Technology and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology (SIMIT), Chinese Academy of Sciences (CAS), Shanghai 200050 (China); Department of Physics and Material Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Lin Chenglu [Research Center of Semiconductor Functional Film Engineering Technology and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology (SIMIT), Chinese Academy of Sciences (CAS), Shanghai 200050 (China); Chu, Paul K. [Department of Physics and Material Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)]. E-mail: paul.chu@cityu.edu.hk

    2005-12-05

    An improved technique is demonstrated to fabricate silicon-germanium on insulator (SGOI) starting with a sandwiched structure of Si/SiGe/Si. After oxidation of the sandwiched structure and successive annealing, a relaxed SiGe-on-insulator (SGOI) structure is produced. Our results indicate that the added Si cap layer is advantageous in suppressing Ge loss at the initial stage of SiGe oxidation and the subsequent annealing process homogenizes the Ge fraction. Raman measurements reveal that the strain in the SiGe layer is fully relaxed at high oxidation temperature ({approx}1150 deg. C) without generating any threading dislocations and crosshatch patterns, which generally exist in the relaxed SiGe layer on bulk Si substrate.

  3. High signal-to-noise ratio quantum well bolometer materials

    Science.gov (United States)

    Wissmar, Stanley; Höglund, Linda; Andersson, Jan; Vieider, Christian; Savage, Susan; Ericsson, Per

    2006-09-01

    Novel single crystalline high-performance temperature sensing materials (quantum well structures) have been developed for the manufacturing of uncooled infrared bolometers. SiGe/Si and AlGaAs/GaAs quantum wells are grown epitaxially on standard Si and GaAs substrates respectively. The former use holes as charge carriers utilizing the discontinuities in the valence band structure, whereas the latter operate in a similar manner with electrons in the conduction band. By optimizing parameters such as the barrier height (by variation of the germanium/aluminium content respectively) and the fermi level E f (by variation of the quantum well width and doping level) these materials provide the potential to engineer layer structures with a very high temperature coefficient of resistance, TCR, as compared with conventional thin film materials such as vanadium oxide and amorphous silicon. In addition, the high quality crystalline material promises very low 1/f-noise characteristics promoting an outstanding signal to noise ratio and well defined and uniform material properties, A comparison between the two (SiGe/Si and AlGaAs/GaAs) quantum well structures and their fundamental theoretical limits are discussed and compared to experimental results. A TCR of 2.0%/K and 4.5%/K have been obtained experimentally for SiGe/Si and AlGaAs/GaAs respectively. The noise level for both materials is measured as being several orders of magnitude lower than that of a-Si and VOx. These uncooled thermistor materials can be hybridized with read out circuits by using conventional flip-chip assembly or wafer level adhesion bonding. The increased bolometer performance so obtained can either be exploited for increasing the imaging system performance, i. e. obtaining a low NETD, or to reduce the vacuum packaging requirements for low cost applications (e.g. automotive).

  4. Dry texturing of mc-Si wafers

    Energy Technology Data Exchange (ETDEWEB)

    Agarwal, Garima [ENEA-Casaccia, Rome (Italy); CNER, 14-Vigyan Bhawan, University of Rajasthan, Jaipur (India); De Iuliis, Simona; Serenelli, Luca; Salza, Enrico; Tucci, Mario [ENEA-Casaccia, Rome (Italy)

    2011-03-15

    Texturing of mc-Si is a prevailing research topic to improve solar cell efficiency in production. Surface texturing for enhanced absorption in Si has been historically obtained by creating randomly distributed pyramids using anisotropic etchants; but this preferential etching works only on single crystalline silicon because of its crystallographic orientations. A low-cost, large area, random, mask-less texturing scheme is expected to significantly impact terrestrial PV technology and reduce the amount of wet-chemical waste. We propose an approach based on randomly etched mc-Si by RIE system using NF{sub 3} instead of SF{sub 6} or CF{sub 4} to reduce the detrimental formation of carbonaceous or sulfurous contamination at the silicon surface, which results in a surface recombination. To obtain a fast process we have investigated the effect of the chemical etching due to the NF{sub 3} radicals and the ion bombardment induced by Ar. We have found that Arions promote a helpful surface pre-conditioning, while fluorine radicals, produced by NF{sub 3} dissociation, are needed to increase the Si etching rate. Different combinations of flux ratios, gas pressures and RF power have been explored. Efforts have been devoted in obtaining a homogeneous texture on large area wafers, which is inescapable for industrialization. After 10 minutes process effective reflectance values have been measured within the range of 12-14%, and with a-Si/SiN{sub x} the value reduced to 7%. Post-processing minority carrier lifetime values in the range of 10 microseconds have been measured without applying any further chemical cleaning. Additionally, microscopic analysis has been performed to evaluate the surface microstructure morphology (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  5. Interstellar SiC: Extended Studies of C, N, and SI Isotopes in Small Single Grains

    Science.gov (United States)

    Hoppe, P.; Strebel, R.; Eberhardt, P.; Amari, S.; Lewis, R. S.

    1993-07-01

    In search of grain-size dependent characteristics of interstellar SiC, we have measured the C, N, and Si isotopes in 596 single grains from Murchison separate KJE (average size 1.14 micrometers) [1]. So far, extended studies of single SiC grains from the Murchison K-series were made on separates KJG (average size 3.02 micrometers) and KJH (average size 4.57 micrometers) [2] and a limited dataset was also obtained for separate KJF (average size 1.86 micrometers) [2,3]. As it is the case for the larger grains, most grains from KJE have heavy carbon and light nitrogen. ^12C/^13C ratios vary between 2.3 and 270. The distribution of ^12C/^13C ratios is almost identical to those observed for the larger-grain separates, with most grains having ^12C/^13C ~40-100 (Fig. 1a-c). ^14N/^15N ratios vary between 48 and >10,000. The distribution of ^14N/^15N ratios clearly differs from those observed for the larger-grain separates (Fig. 1d-f). Grains from separate KJE, on the average, have much higher ^14N/^15N ratios. The median value is 2800 compared to 1250 for KJG and 550 for KJH [2]. As is evident from these numbers, there is a clear trend with the typical ^14N/^15N ratio increasing with decreasing grain size. In close agreement with the larger grains, most grains from KJE have delta^29Si ~ -50 to 200 per mil and delta^30Si ~ 0 to 160 per mil, in a three-isotope-plot lying along a line with slope ~1.1. However, there are 12 grains clearly off this line with 10 of them being depleted in ^29Si and enriched in ^30Si. Nine grains were identified as grains X [4], being charaterized by light C, heavy N, and light Si. Five of them, in addition, show a very high nitrogen content, ~5x higher than that of a typical grain from KJE. Furthermore, one grain has the Si-isotopic signature of grains X, but heavy C. While the observed C-isotopic ratios for the majority of the grains can be explained by standard stellar evolution models for AGB-stars [5], the ^14N/^15N ratios > ~2000, as it is

  6. Ultima Ratio in European Criminal Law

    Directory of Open Access Journals (Sweden)

    Sakari Melander

    2013-01-01

    ón necesariamente tiene que afectar a los principios que legitiman el uso del sistema jurídico penal. Existe la necesidad de desarrollar principios que podrían legitimar el derecho penal (cooperación más allá del ámbito nacional. El artículo, por lo tanto, examina si el principio de ultima ratio puede jugar algún papel en el derecho penal europeo. El artículo se centra en el derecho penal de la Unión Europea. El artículo sugiere que hay varios indicios para reconocer el principio de ultima ratio en el derecho penal de la Unión Europea. El principio es reconocible en el principio de subsidiariedad, en el que el ultima ratio puede tener una dimensión federal. Sobre todo, el principio de proporcionalidad comparte diversas similitudes con el principio de ultima ratio. Si se examinaran y utilizaran estas dimensiones en su totalidad, existiría la posibilidad de formular con cierta profundidad principios de legitimación del derecho criminal a nivel de la Unión Europea. DOWNLOAD THIS PAPER FROM SSRN: http://ssrn.com/abstract=2200871

  7. Maximizing the Performance of Laser Cut Panel by Interaction of Ceiling Geometries and Different Aspect Ratio

    Directory of Open Access Journals (Sweden)

    Ahmed A. Freewan

    2014-12-01

    Full Text Available The interaction between different ceiling geometries with laser cut panels (LCPs is investigated using real experiments and computer simulations to maximize the daylight performance of the LCP. In addition, LCP with different aspect ratios (width to depth ratio is studied using simulation with clear sky conditions in hot climate region. Two main performance parameters are investigated: illuminance level and distribution uniformity in a large space located in a sub-tropical climate region like Jordan. It was found that curved and chamfered ceilings increased the daylight level in the rear part of the studied room by 20% compared to a horizontal flat ceiling and reduce it by 30% in front part that improve the quality of daylight by improving the uniformity. LCP with high aspect ratio of 5:6 performed well in climate with clear sky and high solar angles than LCP with ratio of 4:6.

  8. Raman inspection for the annealing induced evolution of sp{sup 2} and sp{sup 3} bonding behavior in sandwiched Si/C/Si multilayer

    Energy Technology Data Exchange (ETDEWEB)

    Chung, C.K. [Department of Mechanical Engineering, Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan, Taiwan 701 (China)], E-mail: ckchung@mail.ncku.edu.tw; Lai, C.W.; Peng, C.C.; Wu, B.H. [Department of Mechanical Engineering, Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan, Taiwan 701 (China)

    2008-12-01

    The effect of annealing on the sandwiched Si/C/Si multilayer on a Si(100) substrate using ion beam sputtering (IBS) system under ultra-high vacuum (UHV) was investigated. Carbon layer thickness was fixed at 100 nm and a-Si ranged from 10 nm to 25 nm. Rapid thermal annealing was performed to investigate the evolution of sp{sup 2}-sp{sup 3} bonding at annealing temperature from room temperature (RT) to 750 deg. C and annealing time from 0.5 to 2 min. Raman spectroscopy was utilized to characterize bonding behavior of Si/C/Si multilayers for the variation of graphite peak (G-peak), disorder-induced peak (D-peak) of carbon film at specific wavenumbers shift. The higher the integrated intensity ratio (I{sub D}/I{sub G}), the more the sp{sup 2} bonds is. From experimental results, I{sub D}/I{sub G} ratio increases with annealing temperature from RT to 750 deg. C due to graphitization effect for the increased sp{sup 2} bonds. However, I{sub D}/I{sub G} ratio reduces a little with annealing time from 0.5 to 2 min. It implies that a little increase of sp{sup 3} bonds of carbon, which is primarily from the sp{sup 3} Si-C bonds, can be an index of the formation of SiC. Comparing the effect of both annealing temperature and time on the evolution of sp{sup 2}-sp{sup 3} bonds, the annealing temperature dominates more on the sp{sup 2}-sp{sup 3} evolution of a-Si/C/a-Si on the Si(100) under rapid thermal annealing than the annealing time. Also, AES depth profile was used to examine the interdiffusion and reaction between a-Si and C for SiC formation and had a consistent result with Raman.

  9. Effects of Si content on microstructure and mechanical properties of TiAlN/Si{sub 3}N{sub 4}-Cu nanocomposite coatings

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Changjie; Hu, Shuilian [School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang, 330063 (China); Jiang, Yuanfei, E-mail: jyf88889@126.com [School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang, 330063 (China); Wu, Namei [School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang, 330063 (China); Li, Mingsheng [Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang, 330013 (China); Xin, Li; Zhu, Shenglong; Wang, Fuhui [State Key Laboratory for Corrosion and Protection, Institute of Metal Research, The Chinese Academy of Sciences, Shenyang, 110016 (China)

    2014-11-30

    Highlights: • The grain size and surface roughness decreased with the increase of Si content. • The microhardness of these coatings increased with the increasing content of Si. • The ratio H{sup 3}/E{sup 2} of TiAlN/Si3N4-Cu coating of 3.39 at.% Si reached the maximum value of 0.11 GPa. • Indentation morphology of TiAlN/Si3N4-Cu coating contained 3.39 at.% Si has fewer cracks. • TiAlN/Si3N4-Cu coating contained 3.39 at.% Si has good adhesion property and wear resistance. - Abstract: TiAlN/Si{sub 3}N{sub 4}-Cu nanocomposite coatings of various Si content (0–5.09 at.%) were deposited on AISI-304 stainless steel by DC reactive magnetron sputtering technique. The chemical composition, microstructure, mechanical and tribological properties of these coatings were systematically investigated by means of X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), nanoindentation tester, a home-made indentation system, a scratch tester and a wear tester. Results indicated that with increasing Si content in these coatings, a reduction of grain size and surface roughness, a transformation of the (1 1 1) preferred orientation was detected by XRD and FESEM. Furthermore the hardness of these coatings increase from 9.672 GPa to 18.628 GPa, and the elastic modulus reveal the rising trend that increase from 224.654 GPa to 251.933 GPa. However, the elastic modulus of TiAlN/Si{sub 3}N{sub 4}-Cu coating containing 3.39 at.% Si content dropped rapidly and changed to about 180.775 GPa. The H{sup 3}/E{sup 2} ratio is proportional to the film resistance to plastic deformation. The H{sup 3}/E{sup 2} ratio of the TiAlN/Si{sub 3}N{sub 4}-Cu coating containing 3.39 at.% Si content possess of the maximum of 0.11 GPa, and the indentation test indicate that few and fine cracks were observed from its indentation morphologies. The growth pattern of cracks is mainly bending growing. The present results show that the best toughness is obtained for TiAlN/Si{sub 3}N{sub 4

  10. Oxidation of magnetron sputtered La-Si thin films for solide oxide fuel cell electronlytes

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, J.C. [SEG-CEMUC, Mechanical Department, University of Coimbra, Rua Luis Reis Santos, 3030-788 Coimbra (Portugal)], E-mail: joao.oliveira@dem.uc.pt; Horwat, D. [Laboratoire de Science et Genie des Surfaces (UMR 7570), Ecole des Mines, Parc de Saurupt - F 54042 Nancy Cedex (France)], E-mail: david.horwat@mines.inpl-nancy.fr; Billard, A. [Laboratoire d' Etudes et de Recherches sur les Materiaux, les Procedes et les Surfaces, UTBM, Universite de Technologie de Belfort-Montbeliard, 90010 Belfort (France)], E-mail: alain.billard@utbm.fr; Cavaleiro, A. [SEG-CEMUC, Mechanical Department, University of Coimbra, Rua Luis Reis Santos, 3030-788 Coimbra (Portugal)], E-mail: albano.cavaleiro@dem.uc.pt

    2009-01-30

    La-Si thin films were deposited on stainless steel substrates by magnetron sputtering from pure La and Si targets. The Si/(Si + La) atomic ratio in the films was varied from 43.2 to 59.3% by adjusting the discharge current on the La target. The films had a homogeneous chemical composition down to the substrate and sharp interfaces. Annealing the films in air at 1173 K promotes the formation of apatite-structure La{sub 9.33}Si{sub 6}O{sub 26} and the diffusion of different species from the film to the substrate and vice-versa, resulting in broadening the interfaces. X-Ray diffraction showed that all the as-deposited films had an amorphous structure. The formation of the LaSi{sub 2} phase at intermediate temperatures was observed for the films deposited with higher Si contents while the films deposited with lower Si contents remained amorphous up to the start of the apatite structure crystallization process. The lanthanum silicate apatite-like phase (La{sub 9.33}Si{sub 6}O{sub 26}) was obtained only after annealing at 1173 K, excepted for the film with the lower Si content which is already partially crystallized after annealing at 1073 K. Quite pure La{sub 9.33}Si{sub 6}O{sub 26} was obtained only after annealing the film with the highest Si content (Si/(Si + La) = 59.3%) although the theoretical Si/(Si + La) atomic ratio for apatite structure lanthanum silicate is 39%. For the other films, La{sub 2}O{sub 3} was always detected when the lanthanum silicate phase was formed. Both phenomena clearly resulted from the strong diffusion of silicon excess towards the stainless steel substrate.

  11. Si-to-Si wafer bonding using evaporated glass

    DEFF Research Database (Denmark)

    Reus, Roger De; Lindahl, M.

    1997-01-01

    Anodic bonding of Si to Si four inch wafers using evaporated glass was performed in air at temperatures ranging from 300°C to 450°C. Although annealing of Si/glass structures around 340°C for 15 minutes eliminates stress, the bonded wafer pairs exhibit compressive stress. Pull testing revealed...

  12. Annealing Behavior of Si1-xGex/Si Heterostructures

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The behavior of Si1-xGex/Si heterostructures under different annealing conditions has been studied. It is found that while RTA treatment diminishes the point defects, it introduces the misfit dislocations into Si1-xGex layers at same time. Higher annealing temperature will result in the propagation of misfit dislocations and then the total destruction of the crystal quality.

  13. Si nanoparticle interfaces in Si/SiO solar cell materials

    DEFF Research Database (Denmark)

    Kilpeläinen, S.; Kujala, J.; Tuomisto, F.

    2013-01-01

    Novel solar cell materials consisting of Si nanoparticles embedded in SiO2 layers have been studied using positron annihilation spectroscopy in Doppler broadening mode and photoluminescence. Two positron-trapping interface states are observed after high temperature annealing at 1100 °C. One...... of the states is attributed to the (SiO2/Si bulk) interface and the other to the interface between the Si nanoparticles and SiO2. A small reduction in positron trapping into these states is observed after annealing the samples in N2 atmosphere with 5% H2. Enhanced photoluminescence is also observed from...

  14. High extinction ratio bandgap of photonic crystals in LNOI wafer

    Science.gov (United States)

    Zhang, Shao-Mei; Cai, Lu-Tong; Jiang, Yun-Peng; Jiao, Yang

    2017-02-01

    A high-extinction-ratio bandgap of air-bridge photonic crystal slab, in the near infrared, is reported. These structures were patterned in single-crystalline LiNbO3 film bonded to SiO2/LiNbO3 substrate by focused ion beam. To improve the vertical confinement of light, the SiO2 layer was removed by 3.6% HF acid. Compared with photonic crystals sandwiched between SiO2 and air, the structures suspending in air own a robust photonic bandgap and high transmission efficiency at valence band region. The measured results are in good agreement with numerically computed transmission spectra by finite-difference time-domain method. The air-bridge photonic crystal waveguides were formed by removing one line holes. We reveal experimentally the guiding characteristics and calculate the theoretical results for photonic crystal waveguides in LiNbO3 film.

  15. Resonant Tunnelling and Storage of Electrons in Si Nanocrystals within a-SiNx/nc-Si/a-SiNx Structures

    Institute of Scientific and Technical Information of China (English)

    WANG Xiang; HUANG Jian; ZHANG Xian-Gao; DING Hong-Lin; YU Lin-Wei; HUANG Xin-Fan; LI Wei; XU Jun; CHEN Kun-Ji

    2008-01-01

    @@ The a-SiNx/nanocrystalline silicon (nc-Si)/a-SiNx sandwiched structures with asymmetric double-barrier are fabricated in a plasma enhanced chemical vapour deposition (PECVD) system on p-type Si substrates. The nc-Si layer in thickness 5nm is fabricated from a hydrogen-diluted silane gas by the layer-by-layer deposition technique. The thicknesses of tunnel and control SiNx layers are 3nm and 20nm,respectively. Frequency-dependent capacitance spectroscopy is used to study the electron tunnelling and the storage in the sandwiched structures.Distinct frequency-dependent capacitance peaks due to electrons tunnelling into the nc-Si dots and capacitance-voltage (C- V) hysteresis characteristic due to electrons storage in the nc-Si dots are observed with the same sample.

  16. The effects of radiation damage on power VDMOS devices with composite SiO2-Si3N4 films

    Institute of Scientific and Technical Information of China (English)

    Gao Bo; Liu Gang; Wang Li-Xin; Han Zheng-Sheng; Song Li-Mei; Zhang Yan-Fei; Teng Rui

    2013-01-01

    Total dose effects and single event effects on radiation-hardened power vertical double-diffusion metal oxide semiconductor (VDMOS) devices with composite SiO2-Si3N4 film gates are investigated.The relationships among the important electrical parameters of the samples with different thickness SiO2-Si3N4 films,such as threshold voltage,breakdown voltage,and on-state resistance in accumulated dose,are discussed.The total dose experiment results show that the breakdown voltage and the on-state resistance barely change with the accumulated dose.However,the relationships between the threshold voltages of the samples and the accumulated dose are more complex,and not only positively drift,but also negatively drift.At the end of the total dose experiment,we select the group of samples which have the smaller threshold voltage shift to carry out the single event effect studies.We find that the samples with appropriate thickness ratio SiO2-Si3N4 films have a good radiation-hardening ability.This method may be useful in solving both the SEGR and the total dose problems with the composite SiO2-Si3N4 films.

  17. Wafer-scale fabrication of uniform Si nanowire arrays using the Si wafer with UV/Ozone pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Fan; Li, Meicheng, E-mail: mcli@ncepu.edu.cn [Harbin Institute of Technology, School of Materials Science and Engineering (China); Huang, Rui; Yu, Yue; Gu, Tiansheng; Chen, Zhao; Fan, Huiyang; Jiang, Bing [North China Electric Power University, State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy (China)

    2013-09-15

    The electroless etching technique combined with the process of UV/Ozone pretreatment is presented for wafer-scale fabrication of the silicon nanowire (SiNW) arrays. The high-level uniformity of the SiNW arrays is estimated by the value below 0.2 of the relative standard deviation of the reflection spectra on the 4-in. wafer. Influence of the UV/Ozone pretreatment on the formation of SiNW arrays is investigated. It is seen that a very thin SiO{sub 2} produced by the UV/Ozone pretreatment improves the uniform nucleation of Ag nanoparticles (NPs) on the Si surface because of the effective surface passivation. Meanwhile, the SiO{sub 2} located among the adjacent Ag NPs can obstruct the assimilation growth of Ag NPs, facilitating the deposition of the uniform and dense Ag NPs catalysts, which induces the formation of the SiNW arrays with good uniformity and high filling ratio. Furthermore, the remarkable antireflective and hydrophobic properties are observed for the SiNW arrays which display great potential in self-cleaning antireflection applications.

  18. Low Gilbert damping in Co2FeSi and Fe2CoSi films

    Science.gov (United States)

    Sterwerf, Christian; Paul, Soumalya; Khodadadi, Behrouz; Meinert, Markus; Schmalhorst, Jan-Michael; Buchmeier, Mathias; Mewes, Claudia K. A.; Mewes, Tim; Reiss, Günter

    2016-08-01

    Thin highly textured Fe1+xCo2-xSi (0 ≤ x ≤ 1) films were prepared on MgO (001) substrates by magnetron co-sputtering. Magneto-optic Kerr effect (MOKE) and ferromagnetic resonance (FMR) measurements were used to investigate the composition dependence of the magnetization, the magnetic anisotropy, the gyromagnetic ratio, and the relaxation of the films. Both MOKE and FMR measurements reveal a pronounced fourfold anisotropy for all films. In addition, we found a strong influence of the stoichiometry on the anisotropy as the cubic anisotropy strongly increases with increasing Fe concentration. The gyromagnetic ratio is only weakly dependent on the composition. We find low Gilbert damping parameters for all films with values down to 0.0012 ±0.00010.0007 for Fe1.75Co1.25Si. The effective damping parameter for Co2FeSi is found to be 0.0018 ±0.00040.0034 . We also find a pronounced anisotropic relaxation, which indicates significant contributions of two-magnon scattering processes that is strongest along the easy axes of the films. This makes thin Fe1+xCo2-xSi films ideal materials for the application in spin transfer-torque magnetic RAM (STT-MRAM) devices.

  19. Photoluminescence from SiO sub 2 /Si/SiO sub 2 structures

    CERN Document Server

    Photopoulos, P

    2003-01-01

    Si layers were developed on pre-oxidized Si wafers by decomposition of silane in a low pressure chemical vapour deposition reactor. By keeping the deposition time constant (2 min) three sets of samples were fabricated at deposition temperatures equal to 580, 610 and 625 deg C. The deposited Si layers were thinned by high temperature dry oxidation thus forming SiO sub 2 /Si/SiO sub 2 structures. Room temperature photoluminescence (PL) measurements showed that for those samples in which the thickness of the remaining Si layer was greater than approx 6 nm, the spectra exhibited a peak at approx 650 nm. Prolonged oxidations led to the formation of SiO sub 2 /nanocrystalline-Si/SiO sub 2 structures in which the thickness of the remaining nanocrystalline Si (nc-Si) layer was smaller than 3 nm. The PL spectra obtained from these structures were at least ten times stronger compared to the previous ones. The PL peak wavelength exhibited a weak dependence on the nc-Si layer thickness shifting from 800 to 720 nm for nc-...

  20. Ultraviolet emission lines of Si II in quasars --- investigating the "Si II disaster"

    CERN Document Server

    Laha, Sibasish; Ferland, Gary J; Ramsbottom, Catherine A; Aggarwal, Kanti M

    2016-01-01

    The observed line intensity ratios of the Si II 1263 and 1307 \\AA\\ multiplets to that of Si II 1814\\,\\AA\\ in the broad line region of quasars are both an order of magnitude larger than the theoretical values. This was first pointed out by Baldwin et al. (1996), who termed it the "Si II disaster", and it has remained unresolved. We investigate the problem in the light of newly-published atomic data for Si II. Specifically, we perform broad line region calculations using several different atomic datasets within the CLOUDY modeling code under optically thick quasar cloud conditions. In addition, we test for selective pumping by the source photons or intrinsic galactic reddening as possible causes for the discrepancy, and also consider blending with other species. However, we find that none of the options investigated resolves the Si II disaster, with the potential exception of microturbulent velocity broadening and line blending. We find that a larger microturbulent velocity ($\\sim 500 \\rm \\, kms^{-1}$) may solv...