WorldWideScience

Sample records for high energy oxygen

  1. High-Energy-Density Metal-Oxygen Batteries: Lithium-Oxygen Batteries vs Sodium-Oxygen Batteries.

    Science.gov (United States)

    Song, Kyeongse; Agyeman, Daniel Adjei; Park, Mihui; Yang, Junghoon; Kang, Yong-Mook

    2017-12-01

    The development of next-generation energy-storage devices with high power, high energy density, and safety is critical for the success of large-scale energy-storage systems (ESSs), such as electric vehicles. Rechargeable sodium-oxygen (Na-O2 ) batteries offer a new and promising opportunity for low-cost, high-energy-density, and relatively efficient electrochemical systems. Although the specific energy density of the Na-O2 battery is lower than that of the lithium-oxygen (Li-O2 ) battery, the abundance and low cost of sodium resources offer major advantages for its practical application in the near future. However, little has so far been reported regarding the cell chemistry, to explain the rate-limiting parameters and the corresponding low round-trip efficiency and cycle degradation. Consequently, an elucidation of the reaction mechanism is needed for both lithium-oxygen and sodium-oxygen cells. An in-depth understanding of the differences and similarities between Li-O2 and Na-O2 battery systems, in terms of thermodynamics and a structural viewpoint, will be meaningful to promote the development of advanced metal-oxygen batteries. State-of-the-art battery design principles for high-energy-density lithium-oxygen and sodium-oxygen batteries are thus reviewed in depth here. Major drawbacks, reaction mechanisms, and recent strategies to improve performance are also summarized. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. High energy lithium-oxygen batteries - Transport barriers and thermodynamics

    KAUST Repository

    Das, Shyamal K.

    2012-01-01

    We show that it is possible to achieve higher energy density lithium-oxygen batteries by simultaneously lowering the discharge overpotential and increasing the discharge capacity via thermodynamic variables alone. By assessing the relative effects of temperature and pressure on the cell discharge profiles, we characterize and diagnose the critical roles played by multiple dynamic processes that have hindered implementation of the lithium-oxygen battery. © 2012 The Royal Society of Chemistry.

  3. High Energy Density Lithium Air Batteries for Oxygen Concentrators Project

    Data.gov (United States)

    National Aeronautics and Space Administration — For NASA's Exploration Medical Capabilities mission, extremely high specific energy power sources, with specific energy over 2000 Wh/kg, are urgently sought after....

  4. Search for Fractionally Charged Nuclei in High-Energy Oxygen-Lead Collisions

    CERN Multimedia

    2002-01-01

    We propose to use stacks of CR-39 plastic track detectors to look for fractionally charged projectile fragments produced in collisions of high-energy oxygen, sulfur, and calcium nuclei with a lead target. The expected charge resolution is @s^z~=~0.06e for fragments with 17e/3~@$<$~Z~@$<$~23e/3. We request that two target + stack assemblies be exposed to 1~x~10|5 oxygen nuclei at maximum available energy.

  5. An Ultraflexible Silicon-Oxygen Battery Fiber with High Energy Density.

    Science.gov (United States)

    Zhang, Ye; Jiao, Yiding; Lu, Lijun; Wang, Lie; Chen, Taiqiang; Peng, Huisheng

    2017-10-23

    To satisfy the rapid development of portable and wearable electronics, it is highly desired to make batteries with both high energy densities and flexibility. Although some progress has been made in recent decades, the available batteries share critical problems of poor energy storage capacity and low flexibility. Herein, we have developed a silicon-oxygen battery fiber with high energy density and ultra-high flexibility by designing a coaxial architecture with a lithiated silicon/carbon nanotube hybrid fiber as inner anode, a polymer gel as middle electrolyte and a bare carbon nanotube sheet as outer cathode. The fiber showed a high energy density of 512 Wh kg(-1) and could effectively work after bending for 20 000 cycles. These battery fibers have been further woven into flexible textiles for a large-scale application. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Damage induced by high energy multiply charged oxygen ions in oxide coated silicon

    Energy Technology Data Exchange (ETDEWEB)

    Dhole, S.D. [Department of Physics, University of Pune, Pune 411 007 (India)]. E-mail: sanjay@physics.unipune.ernet.in; Dahiwale, S.S. [Department of Physics, University of Pune, Pune 411 007 (India); Kulkarni, V.R. [Department of Physics, University of Pune, Pune 411 007 (India); Bogle, K.A. [Department of Physics, University of Pune, Pune 411 007 (India); Shinde, N.S. [Ecotopia Science Institute, Division of Energy Science, Nagoya University, Nagoya (Japan); Bhoraskar, V.N. [Department of Physics, University of Pune, Pune 411 007 (India)

    2006-03-15

    P-type oxide coated silicon samples of resistivity 120 {omega} cm were irradiated with 60 MeV oxygen ions of fixed charge states 4{sup +}, 5{sup +}, 6{sup +} and 7{sup +} at an equal fluence of, {phi}, {approx}10{sup 13} ions/cm{sup 2}. The induced damage was estimated by Hall voltage, Hall coefficient, carrier concentration and lifetime of minority carriers. The results indicate that Hall voltage (V {sub H}) and Hall coefficient (R {sub H}) increases, while carrier concentration (n) decreases with the charge state of impinging oxygen ions. The V {sub H} increases from 22 mV to 76.5 mV at typical current of 0.5 mA, R {sub H} from 0.42 x 10{sup 5} cm{sup 3}/C to 2.16 x 10{sup 5} cm{sup 3}/C and n decreases from 9 x 10{sup 13} cm{sup -3} to 2.88 x 10{sup 13} cm{sup -3} for the different charge states. This fact is an evidence that the oxygen ions with an individual fixed charge state passing through very thin 40 A layer of silicon dioxide, induces significant damage at the SiO{sub 2}-Si interface through the mechanism of electronic stopping power. The lifetime of minority charge carriers, {tau} (bulk property), remains constant at around 6 {mu}s for all the charge states of the 60 MeV energy oxygen ion irradiated samples at a constant fluence of, {phi}, 10{sup 13} ions/cm{sup 2}.

  7. High-throughput DFT calculations of formation energy, stability and oxygen vacancy formation energy of ABO3 perovskites

    Science.gov (United States)

    Emery, Antoine A.; Wolverton, Chris

    2017-10-01

    ABO3 perovskites are oxide materials that are used for a variety of applications such as solid oxide fuel cells, piezo-, ferro-electricity and water splitting. Due to their remarkable stability with respect to cation substitution, new compounds for such applications potentially await discovery. In this work, we present an exhaustive dataset of formation energies of 5,329 cubic and distorted perovskites that were calculated using first-principles density functional theory. In addition to formation energies, several additional properties such as oxidation states, band gap, oxygen vacancy formation energy, and thermodynamic stability with respect to all phases in the Open Quantum Materials Database are also made publicly available. This large dataset for this ubiquitous crystal structure type contains 395 perovskites that are predicted to be thermodynamically stable, of which many have not yet been experimentally reported, and therefore represent theoretical predictions. The dataset thus opens avenues for future use, including materials discovery in many research-active areas.

  8. High-throughput DFT calculations of formation energy, stability and oxygen vacancy formation energy of ABO3 perovskites.

    Science.gov (United States)

    Emery, Antoine A; Wolverton, Chris

    2017-10-17

    ABO3 perovskites are oxide materials that are used for a variety of applications such as solid oxide fuel cells, piezo-, ferro-electricity and water splitting. Due to their remarkable stability with respect to cation substitution, new compounds for such applications potentially await discovery. In this work, we present an exhaustive dataset of formation energies of 5,329 cubic and distorted perovskites that were calculated using first-principles density functional theory. In addition to formation energies, several additional properties such as oxidation states, band gap, oxygen vacancy formation energy, and thermodynamic stability with respect to all phases in the Open Quantum Materials Database are also made publicly available. This large dataset for this ubiquitous crystal structure type contains 395 perovskites that are predicted to be thermodynamically stable, of which many have not yet been experimentally reported, and therefore represent theoretical predictions. The dataset thus opens avenues for future use, including materials discovery in many research-active areas.

  9. Energy spectra of geomagnetically trapped oxygen ions

    CERN Document Server

    Leicher, M; Enge, W

    1999-01-01

    In a series of COSMOS satellite flights plastic nuclear track detectors have been exposed in low-earth orbits to monitor anomalous cosmic rays (ACR) at energies below 25 MeV/nuc. The analysis of energy spectra has now been extended to energies up to 40 MeV/nuc for two exposures aboard COSMOS 2260 in 1993 and COSMOS 2311 in 1995. Our data on trapped ACR (TACR) oxygen energy spectra might indicate the influence of energy-dependent stripping probabilities and the presence of multiply charged ACR oxygen at high energies as reported by latest SAMPEX observations.

  10. Low effective activation energies for oxygen release from metal oxides: evidence for mass-transfer limits at high heating rates.

    Science.gov (United States)

    Jian, Guoqiang; Zhou, Lei; Piekiel, Nicholas W; Zachariah, Michael R

    2014-06-06

    Oxygen release from metal oxides at high temperatures is relevant to many thermally activated chemical processes, including chemical-looping combustion, solar thermochemical cycles and energetic thermite reactions. In this study, we evaluated the thermal decomposition of nanosized metal oxides under rapid heating (~10(5) K s(-1)) with time-resolved mass spectrometry. We found that the effective activation-energy values that were obtained using the Flynn-Wall-Ozawa isoconversional method are much lower than the values found at low heating rates, indicating that oxygen transport might be rate-determining at a high heating rate. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling.

    Science.gov (United States)

    Medina-Rodríguez, Santiago; Denisov, Sergey A; Cudré, Yanouk; Male, Louise; Marín-Suárez, Marta; Fernández-Gutiérrez, Alberto; Fernández-Sánchez, Jorge F; Tron, Arnaud; Jonusauskas, Gediminas; McClenaghan, Nathan D; Baranoff, Etienne

    2016-05-10

    A doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived red luminescence in solution (τ = 480 μs). Time-resolved spectroscopic studies afforded determination of pertinent photophysical parameters including rates of energy transfer and energy distribution between constituent chromophores in the equilibrated excited molecule (ca. 98% on the organic chromophores). Incorporation into a nanostructured metal-oxide matrix (AP200/19) gave highly sensitive O2 sensing films, as the detection sensitivity was 200-300% higher than with the commonly used PtTFPP and approaches the sensitivity of the best O2-sensing dyes reported to date.

  12. High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling

    OpenAIRE

    Medina-Rodríguez, Santiago; Denisov, Sergey A.; Cudré, Yanouk; Male, Louise; Marín-Suárez, Marta; Fernández-Gutiérrez, Alberto; Fernández-Sánchez, Jorge F.; Tron, Arnaud,; Jonusauskas, Gediminas; McClenaghan, Nathan D.; Baranoff, Etienne

    2016-01-01

    International audience; A doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived red luminescence in solution (τ = 480 μs). Time-resolved spectroscopic studies afforded determination of pertinent photophysical parameters including rates of energy transfer and energy distribution between constituent chromophores in the equilibrate...

  13. High Selectivity Oxygen Delignification

    Energy Technology Data Exchange (ETDEWEB)

    Arthur J. Ragauskas

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in

  14. High oxygen affinity hemoglobins.

    Science.gov (United States)

    Mangin, O

    2017-02-01

    High oxygen affinity hemoglobins are responsible for rare and heterogeneous autosomic dominant genetic diseases. They cause pure erythrocytosis, sometimes accountable for hyperviscosity and thrombosis, or hemolysis. Differential diagnoses must be first ruled out. The diagnosis is based on the identification of a decreased P50, and their possible characterization by cation exchange-high performance liquid chromatography and capillary electrophoresis. Finally, genetic studies of the responsible globin chain gene will confirm the mutation. The prognosis mainly relies on the P50 decrease rate and on the hemoglobin cooperativity impairment. Disease management should be personalized, and it should primarily depend on smoking cessation and physical activity. Phlebotomy and platelet aggregation inhibitors' prescriptions can be discussed. There is no contraindication to flights, high-altitude conditions, or pregnancy. Nevertheless, blood donation must be prohibited. Copyright © 2016 Société Nationale Française de Médecine Interne (SNFMI). Published by Elsevier SAS. All rights reserved.

  15. High-Resolution Electron Energy Loss Studies of Oxygen, Hydrogen, Nitrogen, Nitric Oxide, and Nitrous Oxide Adsorption on Germanium Surfaces.

    Science.gov (United States)

    Entringer, Anthony G.

    The first high resolution electron energy loss spectroscopy (HREELS) studies of the oxidation and nitridation of germanium surfaces are reported. Both single crystal Ge(111) and disordered surfaces were studied. Surfaces were exposed to H, O_2, NO, N _2O, and N, after cleaning in ultra-high vacuum. The Ge surfaces were found to be non-reactive to molecular hydrogen (H_2) at room temperature. Exposure to atomic hydrogen (H) resulted hydrogen adsorption as demonstrated by the presence of Ge-H vibrational modes. The HREEL spectrum of the native oxide of Ge characteristic of nu -GeO_2 was obtained by heating the oxide to 200^circC. Three peaks were observed at 33, 62, and 106 meV for molecular oxygen (O_2) adsorbed on clean Ge(111) at room temperature. These peaks are indicative of dissociative bonding and a dominant Ge-O-Ge bridge structure. Subsequent hydrogen exposure resulted in a shift of the Ge-H stretch from its isolated value of 247 meV to 267 meV, indicative of a dominant +3 oxidation state. A high density of dangling bonds and defects and deeper oxygen penetration at the amorphous Ge surface result in a dilute bridge structure with a predominant +1 oxidation state for similar exposures. Molecules of N_2O decompose at the surfaces to desorbed N_2 molecules and chemisorbed oxygen atoms. In contrast, both oxygen and nitrogen are detected at the surfaces following exposure to NO molecules. Both NO and N_2O appear to dissociate and bond at the top surface layer. Molecular nitrogen (N_2) does not react with the Ge surfaces, however, a precursor Ge nitride is observed at room temperature following exposure to nitrogen atoms and ions. Removal of oxygen by heating of the NO-exposed surface to 550^circC enabled the identification of the Ge-N vibrational modes. These modes show a structure similar to that of germanium nitride. This spectrum is also identical to that of the N-exposed surface heated to 550^circC. Surface phonon modes of the narrow-gap semiconducting

  16. High Selectivity Oxygen Delignification

    Energy Technology Data Exchange (ETDEWEB)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  17. Effects of High Energy Electron Irradiation on a Yttrium Barium(2) Copper(3) Oxygen(7-delta) High Temperature Superconductor

    Science.gov (United States)

    1991-09-01

    expulsion of magnetic fields from the interior of a superconductor such that B = 0 and is the phenome- non that explains magnetic levitation . From Ohm’s Law...2Cu 30 7 - HIGH TEMPERATURE SUPERCONDUCTOR by Sean Mark Connors September 1991 Thesis Advisor: X. K. Maruyama Approved for public release...if necessary and identify by btock numbe,) FiE GP<P ,€ 5 pCOO HIGH TEMPERATURE SUPERCONDUCTORS , IRRADIATION EFFECTS, ELECTRON IRRADIATION

  18. Energy management study for lunar oxygen production

    Science.gov (United States)

    Fazzolare, R. A.; Wong-Swanson, B. G.

    1989-01-01

    Energy management opportunities in the process of hydrogen reduction of ilmenite for lunar oxygen production are being investigated. An optimal energy system to supply the power requirements for the process will be determined.

  19. Solar Energy Systems for Lunar Oxygen Generation

    Science.gov (United States)

    Colozza, Anthony J.; Heller, Richard S.; Wong, Wayne A.; Hepp, Aloysius F.

    2010-01-01

    An evaluation of several solar concentrator-based systems for producing oxygen from lunar regolith was performed. The systems utilize a solar concentrator mirror to provide thermal energy for the oxygen production process. Thermal energy to power a Stirling heat engine and photovoltaics are compared for the production of electricity. The electricity produced is utilized to operate the equipment needed in the oxygen production process. The initial oxygen production method utilized in the analysis is hydrogen reduction of ilmenite. Utilizing this method of oxygen production a baseline system design was produced. This baseline system had an oxygen production rate of 0.6 kg/hr with a concentrator mirror size of 5 m. Variations were performed on the baseline design to show how changes in the system size and process (rate) affected the oxygen production rate. An evaluation of the power requirements for a carbothermal lunar regolith reduction reactor has also been conducted. The reactor had a total power requirement between 8,320 to 9,961 W when producing 1000 kg/year of oxygen. The solar concentrator used to provide the thermal power (over 82 percent of the total energy requirement) would have a diameter of less than 4 m.

  20. A Metal-Free, Free-Standing, Macroporous Graphene@g-C₃N₄ Composite Air Electrode for High-Energy Lithium Oxygen Batteries.

    Science.gov (United States)

    Luo, Wen-Bin; Chou, Shu-Lei; Wang, Jia-Zhao; Zhai, Yu-Chun; Liu, Hua-Kun

    2015-06-01

    The nonaqueous lithium oxygen battery is a promising candidate as a next-generation energy storage system because of its potentially high energy density (up to 2-3 kW kg(-1)), exceeding that of any other existing energy storage system for storing sustainable and clean energy to reduce greenhouse gas emissions and the consumption of nonrenewable fossil fuels. To achieve high energy density, long cycling stability, and low cost, the air electrode structure and the electrocatalysts play important roles. Here, a metal-free, free-standing macroporous graphene@graphitic carbon nitride (g-C3N4) composite air cathode is first reported, in which the g-C3N4 nanosheets can act as efficient electrocatalysts, and the macroporous graphene nanosheets can provide space for Li2O2 to deposit and also promote the electron transfer. The electrochemical results on the graphene@g-C3N4 composite air electrode show a 0.48 V lower charging plateau and a 0.13 V higher discharging plateau than those of pure graphene air electrode, with a discharge capacity of nearly 17300 mA h g(-1)(composite) . Excellent cycling performance, with terminal voltage higher than 2.4 V after 105 cycles at 1000 mA h g(-1)(composite) capacity, can also be achieved. Therefore, this hybrid material is a promising candidate for use as a high energy, long-cycle-life, and low-cost cathode material for lithium oxygen batteries. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Efficiency evaluation of oxygen enrichment in energy conversion processes

    Energy Technology Data Exchange (ETDEWEB)

    Bomelburg, H.J.

    1983-12-01

    The extent to which energy conversion efficiencies can be increased by using oxygen or oxygen-enriched air for combustion was studied. Combustion of most fuels with oxygen instead of air was found to have five advantages: increases combustion temperature and efficiency, improves heat transfer at high temperatures, reduces nitrous oxide emissions, permits a high ration of exhaust gas recirculation and allows combustion of certain materials not combustible in air. The same advantages, although to a lesser degree, are apparent with oxygen-enriched air. The cost-effectiveness of the process must necessarily be improved by about 10% when using oxygen instead of air before such use could become justifiable on purely economic terms. Although such a modest increase appears to be attainable in real situations, this study ascertained that it is not possible to generally assess the economic gains. Rather, each case requires its own evaluation. For certain processes industry has already proven that the use of oxygen leads to more efficient plant operation. Several ideas for essentially new applications are described. Specifically, when oxygen is used with exhaust gas recirculation in external or internal combustion engines. It appears also that the advantages of pulse combustion can be amplified further if oxygen is used. When burning wet fuels with oxygen, direct steam generation becomes possible. Oxygen combustion could also improve processes for in situ gasification of coals, oil shales, peats, and other wet fuels. Enhanced oil recovery by fire flooding methods might also become more effective if oxygen is used. The cold energy contained in liquid oxygen can be substantially recovered in the low end of certain thermodynamic cycles. Further efforts to develop certain schemes for using oxygen for combustion appear to be justified from both the technical and economic viewpoints.

  2. Energy management analysis of lunar oxygen production

    Science.gov (United States)

    Fazzolari, R.; Wong-Swanson, B. G.

    1990-01-01

    Energy load models in the process of hydrogen reduction of ilmenite for lunar oxygen production are being developed. The load models will be used as a first step to ultimately determine the optimal energy system needed to supply the power requirements for the process. The goal is to determine the energy requirements in the process of hydrogen reduction of ilmenite to produce oxygen. The general approach is shown, and the objectives are to determine the energy loads of the processes in the system. Subsequent energy management studies will be made to minimize the system losses (irreversibilities) and to design optimal energy system power requirements. A number of processes are being proposed as possible candidates for lunar application and some detailed experimental efforts are being conducted within this project at the University of Arizona. Priorities are directed toward developing the energy models for each of the proposed processes being considered. The immediate goals are to identify the variables that would impact energy requirements and energy sources of supply.

  3. High energy oxygen irradiation-induced defects in Fe-doped semi-insulating indium phosphide by positron annihilation technique

    Science.gov (United States)

    Pan, S.; Mandal, A.; Sohel, Md. A.; Saha, A. K.; Das, D.; Sen Gupta, A.

    2017-02-01

    Positron annihilation technique is applied to study the recovery of radiation-induced defects in 140 MeV oxygen (O6+) irradiated Fe-doped semi-insulating indium phosphide during annealing over a temperature region of 25∘C-650∘C. Lifetime spectra of the irradiated sample are fitted with three lifetime components. Trapping model analysis is used to characterize defect states corresponding to the de-convoluted lifetime values. After irradiation, the observed average lifetime of positron τavg = 263 ps at room temperature is higher than the bulk lifetime by 21 ps which reveals the presence of radiation-induced defects in the material. A decrease in τavg occurs during room temperature 25∘C to 200∘C indicating the dissociation of higher order defects, might be due to positron trapping in acceptor-type of defects (VIn). A reverse annealing stage is found at temperature range of 250∘C-425∘C for S-parameter probably due to the migration of vacancies and the formation of vacancy clusters. Increase in R-parameter from 325∘C to 425∘C indicates the change in the nature of predominant positron trapping sites. Beyond 425∘C, τavg, S-parameter and R-parameter starts decreasing and around 650∘C, τavg and S-parameter approached almost the bulk value showing the annealing out of radiation-induced defects.

  4. Innovative oxide materials for electrochemical energy conversion and oxygen separation

    Science.gov (United States)

    Belousov, V. V.

    2017-10-01

    Ion-conducting solid metal oxides are widely used in high-temperature electrochemical devices for energy conversion and oxygen separation. However, liquid metal oxides possessing unique electrochemical properties still remain of limited use. The review demonstrates the potential for practical applications of molten oxides. The transport properties of molten oxide materials are discussed. The emphasis is placed on the chemical diffusion of oxygen in the molten oxide membrane materials for electrochemical energy conversion and oxygen separation. The thermodynamics of these materials is considered. The dynamic polymer chain model developed to describe the oxygen ion transport in molten oxides is discussed. Prospects for further research into molten oxide materials are outlined. The bibliography includes 145 references.

  5. Thermal history effect on the nucleation of oxygen precipitates in germanium doped Cz-silicon studied by high-energy X-ray diffraction

    Science.gov (United States)

    Li, Zhen; Will, Johannes; Dong, Peng; Yang, Deren

    2017-12-01

    The oxygen (O) precipitate growth kinetics from moderate and high germanium (Ge) doped Czochralski-growth silicon (Cz-Si) are in-situ investigated at 1000 °C utilizing high-energy X-ray diffraction and analyzed with respect to precipitate density within a diffusion-driven growth model. Distinct different precipitation kinetics are observed for high Ge doped specimens. From the comparison of three thermal treatments, it was found that even for a high Ge concentration the nucleation rate at 800 °C is not influenced, however it facilitates larger grown-in precipitates of smaller amount as compared to the precipitates in undoped and moderately Ge doped samples. However, those grown-in O precipitates can be erased either by a direct annealing at 1200 °C or 1000 °C , but on the other hand stabilized by an annealing step at 800 °C, which in this manner as a drift step of grown-in precipitates for the high Ge-doped samples. In comparison additional nuclei are formed at 800 °C in the moderate and undoped cases.

  6. High Energy $\

    CERN Multimedia

    2002-01-01

    This experiment is a high statistics exposure of BEBC filled with hydrogen to both @n and &bar.@n beams. The principal physics aims are : \\item a) The study of the production of charmed mesons and baryons using fully constrained events. \\end{enumerate} b) The study of neutral current interactions on the free proton. \\item c) Measurement of the cross-sections for production of exclusive final state N* and @D resonances. \\item d) Studies of hadronic final states in charged and neutral current reactions. \\item e) Measurement of inclusive charged current cross-sections and structure functions. \\end{enumerate}\\\\ \\\\ The neutrino flux is determined by monitoring the flux of muons in the neutrino shield. The Internal Picket Fence and External Muon Identifier of BEBC are essential parts of the experiment. High resolution cameras are used to search for visible decays of short-lived particles.

  7. Effective Potential Energies and Transport Properties for Nitrogen and Oxygen

    Science.gov (United States)

    Stallcop, James R.; Partridge, Harry; Levin, Eugene; Kwak, Dochan (Technical Monitor)

    2001-01-01

    The results of recent theoretical studies for N--N2, O--O2, N2--N2 interactions are applied to the transport properties of nitrogen and oxygen gases. The theoretical results are used to select suitable oxygen interaction energies from previous work for determining the diffusion and viscosity coefficients at high temperatures. A universal formulation is applied to determine the collision integrals for O2--O2 interactions at high temperatures and to calculate certain ratios for determining higher-order collision integrals.

  8. Synthesis, characterization, and properties of peroxo-based oxygen-rich compounds for potential use as greener high energy density materials

    Science.gov (United States)

    Gamage, Nipuni-Dhanesha Horadugoda

    One main aspect of high energy density material (HEDM) design is to obtain greener alternatives for HEDMs that produce toxic byproducts. Primary explosives lead azide, lead styphnate, and mercury fulminate contain heavy metals that cause heavy metal poisoning. Leaching of the widely used tertiary explosive NH4ClO4 into groundwater has resulted in human exposure to ClO4-- ions, which cause disruptions of thyroid related metabolic pathways and even thyroid cancer. Many research efforts to find replacements have gained little success. Thus, there is a need for greener HEDMs. Peroxo-based oxygen-rich compounds are proposed as a potential new class of greener HEDMs due to the evolution of CO2 and/or CO, H2O, and O 2 as the main decomposition products. Currently, triacetone triperoxide (TATP), diacetone diperoxide (DADP), hexamethylene triperoxide diamine (HMTD), and methyl ethyl ketone peroxide (MEKP) are the only well-studied highly energetic peroxides. However, due to their high impact and friction sensitivities, low thermal stabilities, and low detonation velocities they have not found any civil or military HEDM applications. In this dissertation research, we have synthesized and fully characterized four categories of peroxo-based compounds: tert-butyl peroxides, tert-butyl peroxy esters, hydroperoxides, and peroxy acids to perform a systematic study of their sensitivities and the energetic properties for potential use as greener HEDMs. tert-Butyl peroxides were not sensitive to impact, friction, or electrostatic spark. Hence, tert-butyl peroxides can be described as fairly safe peroxo-based compounds to handle. tert-Butyl peroxy esters were all surprisingly energetic (4896--6003 m/s), despite the low oxygen and nitrogen contents. Aromatic tert -butyl peroxy esters were much lower in impact and friction sensitivities with respect to the known peroxo-based explosives. These are among the first low sensitivity peroxo-based compounds that can be categorized as secondary

  9. Atomic Oxygen (ATOX) simulation of Teflon FEP and Kapton H surfaces using a high intensity, low energy, mass selected, ion beam facility

    Science.gov (United States)

    Vered, R.; Grossman, E.; Lempert, G. D.; Lifshitz, Y.

    1994-01-01

    A high intensity (greater than 10(exp 15) ions/sq cm) low energy (down to 5 eV) mass selected ion beam (MSIB) facility was used to study the effects of ATOX on two polymers commonly used for space applications (Kapton H and Teflon FEP). The polymers were exposed to O(+) and Ne(+) fluences on 10(exp 15) - 10(exp 19) ions/sq cm, using 30eV ions. A variety of analytical methods were used to analyze the eroded surfaces including: (1) atomic force microscopy (AFM) for morphology measurements; (2) total mass loss measurements using a microbalance; (3) surface chemical composition using x-ray photoelectron spectroscopy (XPS), and (4) residual gas analysis (RGA) of the released gases during bombardment. The relative significance of the collisional and chemical degradation processes was evaluated by comparing the effects of Ne(+) and O(+) bombardment. For 30 eV ions it was found that the Kapton is eroded via chemical mechanisms while Teflon FEP is eroded via collisional mechanisms. AFM analysis was found very powerful in revealing the evolution of the damage from its initial atomic scale (roughness of approx. 1 nm) to its final microscopic scale (roughness greater than 1 micron). Both the surface morphology and the average roughness of the bombarded surfaces (averaged over 1 micron x 1 micron images by the system's computer) were determined for each sample. For 30 eV a non linear increase of the Kapton roughness with the O(+) fluence was discovered (a slow increase rate for fluences phi less than 5 x 10(exp 17) O(+)/sq cm, and a rapid increase rate for phi greater than 5 x 10(exp 17) O(+)/sq cm). Comparative studies on the same materials exposed to RF and DC oxygen plasmas indicate that the specific details of the erosion depend on the simulation facility emphasizing the advantages of the ion beam facility.

  10. Sorbents Remove Oxygen At High Temperatures

    Science.gov (United States)

    Sharma, Pramod K.

    1995-01-01

    Cobalt-exchanged, platinized zeolites 13X and L found conveniently reducible in hot gaseous mixture of hydrogen and nitrogen and thereafter useful as sorbents of trace amounts of oxygen at high temperatures. Aided by catalytic action of platinum, sorbents exhibit rapid oxygen-sorption kinetics and, according to thermodynamic properties of O2/CoO system, capable of lowering level of oxygen in otherwise inert gaseous atmosphere to less than 1 part per trillion in temperature range of 400 to 800 degrees C. Inert atmospheres with these oxygen levels required for processing of certain materials in semiconductor industry.

  11. Methodology for the assessment of oxygen as an energy carrier

    Science.gov (United States)

    Yang, Ming Wei

    Due to the energy intensity of the oxygen generating process, the electric power grid would benefit if the oxygen generating process was consumed electric power only during low demand periods. Thus, the question to be addressed in this study is whether oxygen production and/or usage can be modified to achieve energy storage and/or transmission objectives at lower cost. The specific benefit to grid would be a leveling, over time, of the demand profile and thus would require less installation capacity. In order to track the availability of electricity, a compressed air storage unit is installed between the cryogenic distillation section and the main air compressor of air separation unit. A profit maximizing scheme for sizing storage inventory and related equipments is developed. The optimum scheme is capable of market responsiveness. Profits of steel maker, oxy-combustion, and IGCC plants with storage facilities can be higher than those plants without storage facilities, especially, at high-price market. Price tracking feature of air storage integration will certainly increase profit margins of the plants. The integration may push oxy-combustion and integrated gasification combined cycle process into economic viability. Since oxygen is used in consumer sites, it may generate at remote locations and transport to the place needed. Energy losses and costs analysis of oxygen transportation is conducted for various applications. Energy consumptions of large capacity and long distance GOX and LOX pipelines are lower than small capacity pipelines. However, transportation losses and costs of GOX and LOX pipelines are still higher than electricity transmission.

  12. Robust high temperature oxygen sensor electrodes

    DEFF Research Database (Denmark)

    Lund, Anders

    reaction kinetics. At oxygen partial pressures below 10-6 bar at 700 C, the mass transport processes dominated the response time. The response time increased with decreasing oxygen partial pressure and inlet gas flow rate. A series of porous platinum electrodes were impregnated with the ionically...... conducting gadolinium-doped cerium oxide (CGO). The addition of CGO was found to decrease the polarisation resistance of the oxygen reaction by up to an order of magnitude compared with a single phase platinum electrode by increasing the effective triple phase boundary (TPB) length. It did not have any......Platinum is the most widely used material in high temperature oxygen sensor electrodes. However, platinum is expensive and the platinum electrode may, under certain conditions, suffer from poisoning, which is detrimental for an oxygen sensor. The objective of this thesis is to evaluate electrode...

  13. Trematode hemoglobins show exceptionally high oxygen affinity.

    Science.gov (United States)

    Kiger, L; Rashid, A K; Griffon, N; Haque, M; Moens, L; Gibson, Q H; Poyart, C; Marden, M C

    1998-08-01

    Ligand binding studies were made with hemoglobin (Hb) isolated from trematode species Gastrothylax crumenifer (Gc), Paramphistomum epiclitum (Pe), Explanatum explanatum (Ee), parasitic worms of water buffalo Bubalus bubalis, and Isoparorchis hypselobagri (Ih) parasitic in the catfish Wallago attu. The kinetics of oxygen and carbon monoxide binding show very fast association rates. Whereas oxygen can be displaced on a millisecond time scale from human Hb at 25 degrees C, the dissociation of oxygen from trematode Hb may require a few seconds to over 20 s (for Hb Pe). Carbon monoxide dissociation is faster, however, than for other monomeric hemoglobins or myoglobins. Trematode hemoglobins also show a reduced rate of autoxidation; the oxy form is not readily oxidized by potassium ferricyanide, indicating that only the deoxy form reacts rapidly with this oxidizing agent. Unlike most vertebrate Hbs, the trematodes have a tyrosine residue at position E7 instead of the usual distal histidine. As for Hb Ascaris, which also displays a high oxygen affinity, the trematodes have a tyrosine in position B10; two H-bonds to the oxygen molecule are thought to be responsible for the very high oxygen affinity. The trematode hemoglobins display a combination of high association rates and very low dissociation rates, resulting in some of the highest oxygen affinities ever observed.

  14. Laboratory investigations involving high-velocity oxygen atoms

    Science.gov (United States)

    Leger, Lubert J.; Koontz, Steven L.; Visentine, James T.; Cross, Jon B.

    1989-01-01

    Facilities for measuring material reactive characteristics have been under development for several years and span the atom energy range from thermal to 5 eV, the orbital collision energy. One of the high-atom energy facilities (The High Intensity/Energy Atomic Oxygen Source) capable of simulating the reactive part of LEO is described, along with results of beam characterization and preliminary material studies. The oxygen atom beam source was a continuous wave plasma produced by focusing a high-power CO2 laser through a lens system into a rare gas/molecular oxygen mixture chamber at elevated temperature. Material samples were exposed to the high velocity beam through an external feedthrough. The facility showed good stability in continued operation for more than 100 hours, producing fluences of 10 to the 21st to 10 to the 22nd atoms/sq cm. Reaction efficiencies and surface morphology have been measured for several materials at energies of 1.5 and 2.8 eV, matching with data generated from previous space flights. Activation energies for carbon and Kapton as measured in this facility were 800 cal/mole.

  15. Controlling the bond scission sequence of oxygenates for energy applications

    Science.gov (United States)

    Stottlemyer, Alan L.

    The so called "Holy Grail" of heterogeneous catalysis is a fundamental understanding of catalyzed chemical transformations which span multidimensional scales of both length and time, enabling rational catalyst design. Such an undertaking is realizable only with an atomic level understanding of bond formation and destruction with respect to intrinsic properties of the metal catalyst. In this study, we investigate the bond scission sequence of small oxygenates (methanol, ethanol, ethylene glycol) on bimetallic transition metal catalysts and transition metal carbide catalysts. Oxygenates are of interest both as hydrogen carriers for reforming to H2 and CO and as fuels in direct alcohol fuel cells (DAFC). To address the so-called "materials gap" and "pressure gap" this work adopted three parallel research approaches: (1) ultra high vacuum (UHV) studies including temperature programmed desorption (TPD) and high-resolution electron energy loss spectroscopy (HREELS) on polycrystalline surfaces; (2) DFT studies including thermodynamic and kinetic calculations; (3) electrochemical studies including cyclic voltammetry (CV) and chronoamperometry (CA). Recent studies have suggested that tungsten monocarbide (WC) may behave similarly to Pt for the electrooxidation of oxygenates. TPD was used to quantify the activity and selectivity of oxygenate decomposition for WC and Pt-modifiedWC (Pt/WC) as compared to Pt. While decomposition activity was generally higher on WC than on Pt, scission of the C-O bond resulted in alkane/alkene formation on WC, an undesired product for DAFC. When Pt was added to WC by physical vapor deposition C-O bond scission was limited, suggesting that Pt synergistically modifies WC to improve the selectivity toward C-H bond scission to produce H2 and CO. Additionally, TPD confirmed WC and Pt/WC to be more CO tolerant than Pt. HREELS results verified that surface intermediates were different on Pt/WC as compared to Pt or WC and evidence of aldehyde

  16. Highly Accurate Sensor for High-Purity Oxygen Determination Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this STTR effort, Los Gatos Research (LGR) and the University of Wisconsin (UW) propose to develop a highly-accurate sensor for high-purity oxygen determination....

  17. Advanced Oxygen Evolution Catalyst for Electrolyzer Energy Storage for Lunar Surface Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Future NASA lunar missions will require a high efficiency, lightweight, long life, maintenance-free water electrolyzer for energy storage. Anodic oxygen evolution...

  18. High energy semiconductor switch

    Science.gov (United States)

    Risberg, R. L.

    1989-02-01

    The objective was a controller for electric motors. By operating standard Nema B induction motors at variable speed a great deal of energy is saved. This is especially true in pumping and air conditioning applications. To allow wider use of variable speed AC drives, and to provide improved performance, a better semiconductor switch was sought. This was termed the High Energy Semiconductor Switch.

  19. High-energy detector

    Science.gov (United States)

    Bolotnikov, Aleksey E [South Setauket, NY; Camarda, Giuseppe [Farmingville, NY; Cui, Yonggang [Upton, NY; James, Ralph B [Ridge, NY

    2011-11-22

    The preferred embodiments are directed to a high-energy detector that is electrically shielded using an anode, a cathode, and a conducting shield to substantially reduce or eliminate electrically unshielded area. The anode and the cathode are disposed at opposite ends of the detector and the conducting shield substantially surrounds at least a portion of the longitudinal surface of the detector. The conducting shield extends longitudinally to the anode end of the detector and substantially surrounds at least a portion of the detector. Signals read from one or more of the anode, cathode, and conducting shield can be used to determine the number of electrons that are liberated as a result of high-energy particles impinge on the detector. A correction technique can be implemented to correct for liberated electron that become trapped to improve the energy resolution of the high-energy detectors disclosed herein.

  20. Impact of Distinct Oxygenators on Pulsatile Energy Indicators in an Adult Cardiopulmonary Bypass Model.

    Science.gov (United States)

    Griep, Lonneke M; van Barneveld, Laurentius J M; Simons, Antoine P; Boer, Christa; Weerwind, Patrick W

    2017-02-01

    The quantification of pulse energy during cardiopulmonary bypass (CPB) post-oxygenator is required prior to the evaluation of the possible beneficial effects of pulsatile flow on patient outcome. We therefore, evaluated the impact of three distinctive oxygenators on the energy indicators energy equivalent pressure (EEP) and surplus hemodynamic energy (SHE) in an adult CPB model under both pulsatile and laminar flow conditions. The pre- and post-oxygenator pressure and flow were measured at room temperature using a 40% glycerin-water mixture at flow rates of 1, 2, 3, 4, 5, and 6 L/min. The pulse settings at frequencies of 40, 50, 60, 70, and 80 beats per minute were according to the internal algorithm of the Sorin CP5 centrifugal pump. The EEP is equal to the mean pressure, hence no SHE is present under laminar flow conditions. The Quadrox-i Adult oxygenator was associated with the highest preservation of pulsatile energy irrespective of flow rates. The low pressure drop-high compliant Quadrox-i Adult oxygenator shows the best SHE performance at flow rates of 5 and 6 L/min, while the intermediate pressure drop-low compliant Fusion oxygenator and the high pressure drop-low compliant Inspire 8F oxygenator behave optimally at flow rates of 5 L/min and up to 4 L/min, respectively. In conclusion, our findings contributed to studies focusing on SHE values post-oxygenator as well as post-cannula in clinical practice. In addition, our findings may give guidance to the clinical perfusionist for oxygenator selection prior to pulsatile CPB based on the calculated flow rate for the individual patient. © 2017 International Center for Artificial Organs and Transplantation and Wiley Periodicals, Inc.

  1. High-Pressure Oxygen Concentrator Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA desires to generate and store gases including oxygen and nitrogen at sub-critical conditions as a part of its lunar and spacecraft atmospheric systems. Oxygen...

  2. Experimental high energy physics

    CERN Document Server

    De Paula, L

    2004-01-01

    A summary of the contributions on experimental high energy physics to the XXIV Brazilian National Meeting on Particle and Fields is presented. There were 5 invited talks and 32 submitted contributions. The active Brazilian groups are involved in several interesting projects but suffer from the lack of funding and interaction with Brazilian theorists.

  3. High Energy Exoplanet Transits

    Science.gov (United States)

    Llama, Joe; Shkolnik, Evgenya L.

    2017-10-01

    X-ray and ultraviolet transits of exoplanets allow us to probe the atmospheres of these worlds. High energy transits have been shown to be deeper but also more variable than in the optical. By simulating exoplanet transits using high-energy observations of the Sun, we can test the limits of our ability to accurately measure the properties of these planets in the presence of stellar activity. We use both disk-resolved images of the Solar disk spanning soft X-rays, the ultraviolet, and the optical and also disk-integrated Sun-as-a-star observations of the Lyα irradiance to simulate transits over a wide wavelength range. We find that for stars with activity levels similar to the Sun, the planet-to-star radius ratio can be overestimated by up to 50% if the planet occults an active region at high energies. We also compare our simulations to high energy transits of WASP-12b, HD 189733, 55 Cnc b, and GJ 436b.

  4. High energy battery. Hochenergiebatterie

    Energy Technology Data Exchange (ETDEWEB)

    Boehm, H.; Beyermann, G.; Bulling, M.

    1992-03-26

    In a high energy battery with a large number of individual cells in a housing with a cooling medium flowing through it, it is proposed that the cooling medium should be guided so that it only affects one or both sides of the cells thermally.

  5. High energy particle astronomy.

    Science.gov (United States)

    Buffington, A.; Muller, R. A.; Smith, L. H.; Smoot, G. F.

    1972-01-01

    Discussion of techniques currently used in high energy particle astronomy for measuring charged and neutral cosmic rays and their isotope and momentum distribution. Derived from methods developed for accelerator experiments in particle physics, these techniques help perform important particle astronomy experiments pertaining to nuclear cosmic ray and gamma ray research, electron and position probes, and antimatter searches.

  6. Theoretical High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Christ, Norman H.; Weinberg, Erick J.

    2014-07-14

    we provide reports from each of the six faculty supported by the Department of Energy High Energy Physics Theory grant at Columbia University. Each is followed by a bibliography of the references cited. A complete list of all of the publications in the 12/1/2010-04/30/2014 period resulting from research supported by this grant is provided in the following section. The final section lists the Ph.D. dissertations based on research supported by the grant that were submitted during this period.

  7. Experimental comparison of laser energy losses in high-quality laser-oxygen cutting of low-carbon steel using radiation from fibre and CO2 lasers

    Science.gov (United States)

    Golyshev, A. A.; Malikov, A. G.; Orishich, A. M.; Shulyat'ev, V. B.

    2015-09-01

    We report a comparative experimental study of laseroxygen cutting of low-carbon steel using a fibre laser with a wavelength of 1.07 μm and a CO2 laser with a wavelength of 10.6 μm at the sheet thickness of 3 - 16 mm. For the two lasers we have measured the dependence of the cutting speed on the radiation power and determined the cutting speed at which the surface roughness is minimal. The coefficient of laser radiation absorption in the laser cutting process is measured for these lasers at different values of the cutting speed and radiation power. It is found that the minimal roughness of the cut surface is reached at the absorbed laser energy per unit volume of the removed material, equal to 11 - 13 J mm-3; this value is the same for the two lasers and does not depend on the sheet thickness.

  8. Hydrogen-Oxygen PEM Regenerative Fuel Cell Energy Storage System

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, Bei-Jiann; Johnson, Donald W.; Garcia, Christopher P.

    2005-01-01

    An introduction to the closed cycle hydrogen-oxygen polymer electrolyte membrane (PEM) regenerative fuel cell (RFC), recently constructed at NASA Glenn Research Center, is presented. Illustrated with explanatory graphics and figures, this report outlines the engineering motivations for the RFC as a solar energy storage device, the system requirements, layout and hardware detail of the RFC unit at NASA Glenn, the construction history, and test experience accumulated to date with this unit.

  9. High Energy Particle Accelerators

    CERN Multimedia

    Audio Productions, Inc, New York

    1960-01-01

    Film about the different particle accelerators in the US. Nuclear research in the US has developed into a broad and well-balanced program.Tour of accelerator installations, accelerator development work now in progress and a number of typical experiments with high energy particles. Brookhaven, Cosmotron. Univ. Calif. Berkeley, Bevatron. Anti-proton experiment. Negative k meson experiment. Bubble chambers. A section on an electron accelerator. Projection of new accelerators. Princeton/Penn. build proton synchrotron. Argonne National Lab. Brookhaven, PS construction. Cambridge Electron Accelerator; Harvard/MIT. SLAC studying a linear accelerator. Other research at Madison, Wisconsin, Fixed Field Alternate Gradient Focusing. (FFAG) Oakridge, Tenn., cyclotron. Two-beam machine. Comments : Interesting overview of high energy particle accelerators installations in the US in these early years. .

  10. Trematode Hemoglobins Show Exceptionally High Oxygen Affinity

    OpenAIRE

    Kiger, Laurent; Rashid, Aftab K.; Griffon, Nathalie; Haque, Masoodul; Moens, Luc; Gibson, Quentin H.; Poyart, Claude; Marden, Michael C.

    1998-01-01

    Ligand binding studies were made with hemoglobin (Hb) isolated from trematode species Gastrothylax crumenifer (Gc), Paramphistomum epiclitum (Pe), Explanatum explanatum (Ee), parasitic worms of water buffalo Bubalus bubalis, and Isoparorchis hypselobagri (Ih) parasitic in the catfish Wallago attu. The kinetics of oxygen and carbon monoxide binding show very fast association rates. Whereas oxygen can be displaced on a millisecond time scale from human Hb at 25 degrees C, the dissociation of ox...

  11. Activation energy for oxygen chemisorption on carbon at low temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Teng, H.; Hsieh, C.T. [National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering

    1999-01-01

    The kinetics of oxygen chemisorption on resin chars were investigated in this study. The Elovich equation was employed to facilitate the interpretation of the chemisorption process. It was found that the activation energy for chemisorption is not constant and varies with surface coverage. This observation can be explained by a distributed kinetic parameter model, here implemented as a distributed activation energy model. The energy distribution model reveals that the amount of mass uptake obtained in a typical chemisorption study does not involve full coverage of all of the active sites on carbon. It is concluded that the information on active sites obtained from low-temperature chemisorption cannot be directly applied to gasification at higher temperatures.

  12. Shielding high energy accelerators

    CERN Document Server

    Stevenson, Graham Roger

    2001-01-01

    After introducing the subject of shielding high energy accelerators, point source, line-of-sight models, and in particular the Moyer model. are discussed. Their use in the shielding of proton and electron accelerators is demonstrated and their limitations noted. especially in relation to shielding in the forward direction provided by large, flat walls. The limitations of reducing problems to those using it cylindrical geometry description are stressed. Finally the use of different estimators for predicting dose is discussed. It is suggested that dose calculated from track-length estimators will generally give the most satisfactory estimate. (9 refs).

  13. High energy cosmic rays

    CERN Document Server

    Stanev, Todor

    2010-01-01

    Offers an accessible text and reference (a cosmic-ray manual) for graduate students entering the field and high-energy astrophysicists will find this an accessible cosmic-ray manual Easy to read for the general astronomer, the first part describes the standard model of cosmic rays based on our understanding of modern particle physics. Presents the acceleration scenario in some detail in supernovae explosions as well as in the passage of cosmic rays through the Galaxy. Compares experimental data in the atmosphere as well as underground are compared with theoretical models

  14. High oxygen levels promote peel spotting in banana fruit

    NARCIS (Netherlands)

    Maneenuam, T.; Ketsa, S.; Doorn, van W.G.

    2007-01-01

    We studied the effect of high oxygen on early peel spotting in `Sucrier¿ bananas held at 25 °C and 90% RH. Fruit first ripened to colour index 3¿4 (about as yellow as green) and were then held in containers with a continuous gas flow of 18 ± 2 kPa (control) or 90 ± 2 kPa oxygen. High oxygen promoted

  15. Rapid hydrogen and oxygen atom transfer by a high-valent nickel-oxygen species

    NARCIS (Netherlands)

    Corona, Teresa; Draksharapu, Apparao; Padamati, Sandeep K; Gamba, Ilaria; Martin-Diaconescu, Vlad; Acuña-Parés, Ferran; Browne, Wesley R; Company, Anna

    2016-01-01

    Terminal high-valent metal-oxygen species are key reaction intermediates in the catalytic cycle of both enzymes (e.g., oxygenases) and synthetic oxidation catalysts. While tremendous efforts have been directed towards the characterization of the biologically relevant terminal manganese-oxygen and

  16. Triplet-triplet energy transfer and protection mechanisms against singlet oxygen in photosynthesis

    Science.gov (United States)

    Kihara, Shigeharu

    In photosynthesis, (bacterio)chlorophylls ((B)Chl) play a crucial role in light harvesting and electron transport. (B)Chls, however, are known to be potentially dangerous due to the formation of the triplet excited state which forms the singlet oxygen (1O2*) when exposed to the sunlight. Singlet oxygen is highly reactive and all modern organisms incorporate special protective mechanisms to minimize the oxidative damage. One of the conventional photoprotective mechanisms used by photosynthetic organisms is by the nearby carotenoids quenching the excess energy and releasing it by heat. In this dissertation, two major aspects of this process are studied. First, based on experimental data and model calculations, the oxygen content in a functioning oxygenic photosynthetic oxygen cell was determined. These organisms perform water splitting and as a result significant amount of oxygen can be formed within the organism itself. It was found, that contrary to some published estimates, the excess oxygen concentration generated within an individual cell is extremely low -- 0.025 ... 0.25 microM, i.e. about 103-104 times lower than the oxygen concentration in air saturated water. Such low concentrations imply that the first oxygenic photosynthetic cells that evolved in oxygen-free atmosphere of the Earth ~2.8 billion years ago might have invented the water splitting machinery (photosystem II) without the need for special oxygen-protective mechanisms, and the latter mechanisms could have evolved in the next 500 million years during slow rise of oxygen in the atmosphere. This result also suggests that proteins within photosynthetic membranes are not exposed to significant O2 levels and thus can be studied in vitro under the usual O2 levels. Second, the fate of triplet excited states in the Fenna Matthew Olson (FMO) pigment-protein complex is studied by means of time-resolved nanosecond spectroscopy and exciton model simulations. For the first time, the properties of several

  17. High oxygen as an additional factor in food preservation

    NARCIS (Netherlands)

    Amanatidou, A.

    2001-01-01

    In this thesis, the efficacy of high oxygen as an additional hurdle for food preservation is studied. At high oxygen conditions and at low temperature, significant impairment of growth and viability of bacterial cells is found to occur as the result of free

  18. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    Energy Technology Data Exchange (ETDEWEB)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable

  19. High energy astrophysical techniques

    CERN Document Server

    Poggiani, Rosa

    2017-01-01

    This textbook presents ultraviolet and X-ray astronomy, gamma-ray astronomy, cosmic ray astronomy, neutrino astronomy, and gravitational wave astronomy as distinct research areas, focusing on the astrophysics targets and the requirements with respect to instrumentation and observation methods. The purpose of the book is to bridge the gap between the reference books and the specialized literature. For each type of astronomy, the discussion proceeds from the orders of magnitude for observable quantities. The physical principles of photon and particle detectors are then addressed, and the specific telescopes and combinations of detectors, presented. Finally the instruments and their limits are discussed with a view to assisting readers in the planning and execution of observations. Astronomical observations with high-energy photons and particles represent the newest additions to multimessenger astronomy and this book will be of value to all with an interest in the field.

  20. High energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    This proposal is for the continuation of the High Energy Physics program at the University of California at Riverside. In hadron collider physics the authors will complete their transition from experiment UA1 at CERN to the DZERO experiment at Fermilab. On experiment UA1 their effort will concentrate on data analysis at Riverside. At Fermilab they will coordinate the high voltage system for all detector elements. They will also carry out hardware/software development for the D0 muon detector. The TPC/Two-Gamma experiment has completed its present phase of data-taking after accumulating 160 pb{sup {minus}}1 of luminosity. The UC Riverside group will continue data and physics analysis and make minor hardware improvement for the high luminosity run. The UC Riverside group is participating in design and implementation of the data acquisition system for the OPAL experiment at LEP. Mechanical and electronics construction of the OPAL hadron calorimeter strip readout system is proceeding on schedule. Data analysis and Monte Carlo detector simulation efforts are proceeding in preparation for the first physics run when IEP operation comenses in fall 1989.

  1. Conjunctival oxygen tension at high altitude.

    Science.gov (United States)

    Mader, T H; Friedl, K E; Mohr, L C; Bernhard, W N

    1987-01-01

    Transconjunctival oxygen tension (PcjO2) was studied using a hypobaric chamber and during mountaineering excursions. Measurements obtained during acute chamber exposures (15-20 min) at sea level, 1829 m (6,000 ft), 3048 m (10,000 ft), 4267 m (14,000 ft) and return to sea level were (means +/- SEM): 60.1 +/- 2.7, 49.1 +/- 1.8, 38.3 +/- 2.4, 27.4 +/- 1.5, and 61.1 +/- 2.8 mm Hg, respectively (n = 13). The ratio of PcjO2 to arterial blood oxygen tension (PaO2) did not change in a consistent manner between sea level and 4267 m; PcjO2 was 74 +/- 6.9% of PaO2. The 16 subjects participating in the mountaineering phase of the study revealed similar means at sea level and 1829 m (57.4 +/- 2.4 and 46.3 +/- 1.9 mm Hg respectively), but a smaller decrement was observed at 3048 m (43.0 +/- 1.6 mm Hg). The difference between mountain and chamber values may be accounted for by a partial acclimatization to altitude brought about by longer exposure on the mountain excursions. A comparison between PcjO2 and transcutaneous oxygen tension during the chamber study suggests that a greater precision and sensitivity is obtained with measurement of oxygen tension at the conjunctival site. PcjO2 measurement is a non-invasive reflection of PaO2 which is suitable for continuous monitoring during hypoxia studies.

  2. Are macroinvertebrates in high altitude streams affected by oxygen deficiency?

    DEFF Research Database (Denmark)

    Jacobsen, Dean; Rostgaard, S.; Vásconez, J. J.

    2003-01-01

    conditions. However, this fails to take into account that oxygen solubility declines with decreasing atmospheric pressure, which may be of importance at high altitudes. 2. Based on samples of macroinvertebrate benthos and in situ measurements of respiratory oxygen demand of macroinvertebrates in small...... of species and aquatic communities. We argue that oxygen deficiency may be a potentially important factor, and that more focus on this topic is likely to produce significant new insights in aquatic community ecology....

  3. High Energy Density Capacitors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA?s future space science missions cannot be realized without the state of the art energy storage devices which require high energy density, high reliability, and...

  4. FSU High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Prosper, Harrison B. [Florida State Univ., Tallahassee, FL (United States); Adams, Todd [Florida State Univ., Tallahassee, FL (United States); Askew, Andrew [Florida State Univ., Tallahassee, FL (United States); Berg, Bernd [Florida State Univ., Tallahassee, FL (United States); Blessing, Susan K. [Florida State Univ., Tallahassee, FL (United States); Okui, Takemichi [Florida State Univ., Tallahassee, FL (United States); Owens, Joseph F. [Florida State Univ., Tallahassee, FL (United States); Reina, Laura [Florida State Univ., Tallahassee, FL (United States); Wahl, Horst D. [Florida State Univ., Tallahassee, FL (United States)

    2014-12-01

    The High Energy Physics group at Florida State University (FSU), which was established in 1958, is engaged in the study of the fundamental constituents of matter and the laws by which they interact. The group comprises theoretical and experimental physicists, who sometimes collaborate on projects of mutual interest. The report highlights the main recent achievements of the group. Significant, recent, achievements of the group’s theoretical physicists include progress in making precise predictions in the theory of the Higgs boson and its associated processes, and in the theoretical understanding of mathematical quantities called parton distribution functions that are related to the structure of composite particles such as the proton. These functions are needed to compare data from particle collisions, such as the proton-proton collisions at the CERN Large Hadron Collider (LHC), with theoretical predictions. The report also describes the progress in providing analogous functions for heavy nuclei, which find application in neutrino physics. The report highlights progress in understanding quantum field theory on a lattice of points in space and time (an area of study called lattice field theory), the progress in constructing several theories of potential new physics that can be tested at the LHC, and interesting new ideas in the theory of the inflationary expansion of the very early universe. The focus of the experimental physicists is the Compact Muon Solenoid (CMS) experiment at CERN. The report, however, also includes results from the D0 experiment at Fermilab to which the group made numerous contributions over a period of many years. The experimental group is particularly interested in looking for new physics at the LHC that may provide the necessary insight to extend the standard model (SM) of particle physics. Indeed, the search for new physics is the primary task of contemporary particle physics, one motivated by the need to explain certain facts, such as the

  5. High energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    This proposal is for the continuation of the High Energy Physics Program at the University of California, Riverside. In 1990, we will concentrate on analysis of LEP data from the OPAL detector. We expect to record 10{sup 5} Z`s by the end of 1989 and 10{sup 6} in 1990. This data will be used to measure the number of quark-lepton families in the universe. In the second half of 1990 we will also be occupied with the installation of the D-Zero detector in the Tevatron Collider and the preparation of software for the 1991 run. A new initiative made possible by generous university support is a laboratory for detector development at UCR. The focus will be on silicon strip tracking detectors both for the D-Zero upgrade and for SSC physics. The theory program will pursue further various mass-generating radiative mechanisms for understanding small quark and lepton masses as well as some novel phenomenological aspects of supersymmetry.

  6. Dosimetry of high energy radiation

    CERN Document Server

    Sahare, P D

    2018-01-01

    High energy radiation is hazardous to living beings and a threat to mankind. The correct estimation of the high energy radiation is a must and a single technique may not be very successful. The process of estimating the dose (the absorbed energy that could cause damages) is called dosimetry. This book covers the basic technical knowledge in the field of radiation dosimetry. It also makes readers aware of the dangers and hazards of high energy radiation.

  7. MEET ISOLDE - High Energy Physics

    CERN Multimedia

    2017-01-01

    Meet ISOLDE - High Energy Physics. ISOLDE is always developing, equipment moves on and off the hall floor, new groups start and end experiments regularly, visiting scientists come and go and experiments evolve. So it was a natural step for ISOLDE to expand from its core low energy science into high-energies.

  8. Energy peaks: A high energy physics outlook

    Science.gov (United States)

    Franceschini, Roberto

    2017-12-01

    Energy distributions of decay products carry information on the kinematics of the decay in ways that are at the same time straightforward and quite hidden. I will review these properties and discuss their early historical applications, as well as more recent ones in the context of (i) methods for the measurement of masses of new physics particle with semi-invisible decays, (ii) the characterization of Dark Matter particles produced at colliders, (iii) precision mass measurements of Standard Model particles, in particular of the top quark. Finally, I will give an outlook of further developments and applications of energy peak method for high energy physics at colliders and beyond.

  9. Charting the relationship between phase type-surface area-interactions between the constituent atoms and oxygen reduction activity of Pd–Cu nanocatalysts inside fuel cells by in operando high-energy X-ray diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Maswadeh, Yazan; Shan, Shiyao; Prasai, Binay; Zhao, Yinguang; Xie, Zhi-Hui; Wu, Zhipeng; Luo, Jin; Ren, Yang; Zhong, Chuan-Jian; Petkov, Valeri

    2017-01-01

    The activity and stability of nanoalloy catalysts for chemical reactions driving devices for clean energy conversion, in particular the oxygen reduction reaction (ORR), depend critically on optimizing major structural characteristics of the nanoalloys, such as the phase composition, surface area and bonding interactions between the constituent atoms, for the harsh operating conditions inside the devices. The effort requires good knowledge of the potential effect of changes in these characteristics on the catalytic functionality of the nanoalloys and, hence, on the devices' performance. We present the results from an in operando high-energy X-ray diffraction (HE-XRD) study on the concurrent changes in the structural characteristics and ORR activity of Pd–Cu nanoalloy catalysts as they function at the cathode of a proton exchange membrane fuel cell (PEMFC). We find that the as-prepared Pd–Cu nanoalloys with a chemical composition close to Pd1Cu1 are better ORR catalysts in comparison with Pd1Cu2, i.e. Pd-poor, and Pd3Cu1, i.e. Pd-rich, nanoalloys. Under operating conditions though, the former suffers a big loss in ORR activity appearing as a slow-mode oscillation in the current output of the PEMFC. Losses in ORR activity suffered by the latter also exhibit sudden drops and rises during the PEMFC operation. Through atomic pair distribution function (PDF) analysis of the in operando HE-XRD data, we identify the structural changes of Pd–Cu alloy NPs that are behind the peculiar decay of their ORR activity. The results uncover the instant link between the ever-adapting structural state of ORR nanocatalysts inside an operating PEMFC and the performance of the PEMFC. Besides, our results indicate that, among others, taking control over the intra-particle diffusion of metallic species in nanoalloy catalysts may improve the performance of PEMFCs significantly and, furthermore, in operando HE-XRD can be an effective tool to guide the effort. Finally, we argue that

  10. Non-equilibrium electron energy distribution in oxygen plasma: observation with optical emission spectroscopy

    Science.gov (United States)

    Boffard, John; Ly, Nathaniel; Wang, Shicong; Swee, Colin; Lin, Chun C.; Wendt, Amy

    2017-10-01

    Partially ionized inductively-coupled RF oxygen plasmas are in widespread use for materials processing, and non-invasive diagnostics are of interest for the optimization and control of the degrees of ionization and dissociation. Our initial study involves a 2-5% admixture of argon for optical emission spectroscopy (OES) of the oxygen plasma glow. The Ar 420.1/419.8 nm line intensity ratio, previously used in other mixtures to compute electron temperature, when 35 eV) electrons; the latter is observed under conditions of low power and high pressure in the oxygen plasma. We tentatively attribute the increase in energetic electrons to a transition to capacitive coupling, leading to electron acceleration to high energy in the sheaths adjacent to the powered electrode, which in this system is a spiral flat antenna separated from the plasma by a dielectric window. Investigations of OES methods involving additional species, including other trace rare gases, O, and O2+,to determine oxygen plasma properties such as non-Maxwellian electron energy distributions will also be described. Supported by NSF Grants PHY-1617602 and PHY-1068670.

  11. Dependence of Initial Oxygen Concentration on Ozone Yield Using Inductive Energy Storage System Pulsed Power Generator

    Science.gov (United States)

    Go, Tomio; Tanaka, Yasushi; Yamazaki, Nobuyuki; Mukaigawa, Seiji; Takaki, Koichi; Fujiwara, Tamiya

    Dependence of initial oxygen concentration on ozone yield using streamer discharge reactor driven by an inductive energy storage system pulsed power generator is described in this paper. Fast recovery type diodes were employed as semiconductor opening switch to interrupt a circuit current within 100 ns. This rapid current change produced high-voltage short pulse between a secondary energy storage inductor. The repetitive high-voltage short pulse was applied to a 1 mm diameter center wire electrode placed in a cylindrical pulse corona reactor. The streamer discharge successfully occurred between the center wire electrode and an outer cylinder ground electrode of 2 cm inner diameter. The ozone was produced with the streamer discharge and increased with increasing pulse repetition rate. The ozone yield changed in proportion to initial oxygen concentration contained in the injected gas mixture at 800 ns forward pumping time of the current. However, the decrease of the ozone yield by decreasing oxygen concentration in the gas mixture at 180 ns forward pumping time of the current was lower than the decrease at 800 ns forward pumping time of the current. This dependence of the initial oxygen concentration on ozone yield at 180 ns forward pumping time is similar to that of dielectric barrier discharge reactor.

  12. Comparison of oxygen transfer parameters and oxygen demands in bioreactors operated at low and high dissolved oxygen levels.

    Science.gov (United States)

    Mines, Richard O; Callier, Matthew C; Drabek, Benjamin J; Butler, André J

    2017-03-21

    The proper design of aeration systems for bioreactors is critical since it can represent up to 50% of the operational and capital cost at water reclamation facilities. Transferring the actual amount of oxygen needed to meet the oxygen demand of the wastewater requires α- and β-factors, which are used for calculating the actual oxygen transfer rate (AOTR) under process conditions based on the standard oxygen transfer rate (SOTR). The SOTR is measured in tap water at 20°C, 1 atmospheric pressure, and 0 mg L -1 of dissolved oxygen (DO). In this investigation, two 11.4-L bench-scale completely mixed activated process (CMAS) reactors were operated at various solid retention times (SRTs) to ascertain the relationship between the α-factor and SRT, and between the β-factor and SRT. The second goal was to determine if actual oxygen uptake rates (AOURs) are equal to calculated oxygen uptake rates (COURs) based on mass balances. Each reactor was supplied with 0.84 L m -1 of air resulting in SOTRs of 14.3 and 11.5 g O 2 d -1 for Reactor 1 (R-1) and Reactor 2 (R-2), respectively. The estimated theoretical oxygen demands of the synthetic feed to R-1 and R-2 were 6.3 and 21.9 g O 2 d -1 , respectively. R-2 was primarily operated under a dissolved oxygen (DO) limitation and high nitrogen loading to determine if nitrification would be inhibited from a nitrite buildup and if this would impact the α-factor. Nitrite accumulated in R-2 at DO concentrations ranging from 0.50 to 7.35 mg L -1 and at free ammonia (FA) concentrations ranging from 1.34 to 7.19 mg L -1 . Nonsteady-state reaeration tests performed on the effluent from each reactor and on tap water indicated that the α-factor increased as SRT increased. A simple statistical analysis (paired t-test) between AOURs and COURs indicated that there was a statistically significant difference at 0.05 level of significance for both reactors. The ex situ BOD bottle method for estimating AOUR appears to be invalid in

  13. High Energy Materials

    Indian Academy of Sciences (India)

    IAS Admin

    sition giving out heat, light, sound and large volumes of gases. The amount of energy released varies with the ... Explosives are classified according to applications either for. 2 Pyrotechnics is the art of manu- facturing or .... rockets are based on Newton's Third Law: an action will always have an equal and opposite reaction.

  14. High energy neutrinos from GRBs

    CERN Document Server

    De Paolis, F; Orlando, D; Perrone, L

    2001-01-01

    It is by now recognized that GRBs can accelerate protons to relativistic energies and that high density media may be present nearby the source. We compute the high-energy gamma-ray and neutrino fluxes from the decay of pions produced through the interaction of accelerated protons with nucleons in the surrounding medium. Then, we estimate the flux of high-energy muons induced on a detector by upward-going neutrinos interacting through charge current processes with the surrounding matter.

  15. HIGH PERFORMANCE CERIA BASED OXYGEN MEMBRANE

    DEFF Research Database (Denmark)

    2014-01-01

    The invention describes a new class of highly stable mixed conducting materials based on acceptor doped cerium oxide (CeO2-8 ) in which the limiting electronic conductivity is significantly enhanced by co-doping with a second element or co- dopant, such as Nb, W and Zn, so that cerium and the co-...... thin film membrane devices using these materials....

  16. Free energy changes and components implicit in the MWC allosteric model for the cooperative oxygen binding of hemoglobin.

    Science.gov (United States)

    Bucci, Enrico; Pucciarelli, Stefania; Angeletti, Mauro

    2013-06-18

    Hill's plots of oxygen binding isotherms reveal the presence of a transition between two different oxygen affinities at the beginning and end of the isotherm. They correspond to the two conformations anticipated by the MWC model, namely, the T and R conformations at the beginning and end of oxygen binding, when the lower affinity of the T form develops into the higher affinity of the R form. The difference between the binding Gibbs free energy changes of the two affinities (Δ G(L)) is the free energy of binding cooperativity. Notably, Δ G(L) is positive in favor of the T form, which moves to a higher energy level upon oxygen release. Osmotic stress reveals a higher volume/surface ratio of deoxyhemoglobin, with a positive Δ G(W) also in favor of the T form. An increasing protein concentration shifts the isotherms to the right, indicating the formation of intermediate polymeric forms. The enthalpy of the intermediates shows a strong absorption of heat at the third oxygenation step because of polymer formation with quinary, and higher-order, structures. The disassembly of intermediate polymers releases energy with a negative Δ G that compensates and allows the positive values of Δ G(L). High-energy polymers are the barrier preventing the relaxation of the T and R conformations into one another. The MWC allosteric model is the best justification of oxygen binding cooperativity.

  17. Free energy changes and components implicit in the MWC allosteric model for the cooperative oxygen binding of hemoglobin.#

    Science.gov (United States)

    Bucci, Enrico

    2013-01-01

    Hill’s plots of oxygen binding isotherms reveal the presence of a transition between two different oxygen affinities at the beginning and end of the isotherm. They correspond to the two conformations anticipated by the MWC model, namely the T and R conformations at the beginning and end of oxygen binding, when the lower affinity of the T form develops into the higher affinity of the R form. The difference between the binding Gibbs free energies changes of the two affinities (ΔGL) is the free energy of binding cooperativity. Notably ΔGL is positive in favor of the T form, that moves to a higher energy level upon oxygen release. Osmotic stress reveals a higher volume/surface ratio of deoxyHb, with a positive ΔGW also in favor of the T form . Increasing protein concentration shifts the isotherms to the right indicating the formation of intermediate polymeric forms. Enthalpy of the intermediates show a strong absorption of heat at the third oxygenation step due to polymers formation with quinary, and above, structures. The disassembly of intermediate polymers releases energy with a negative ΔG that compensates and allow the positivity of ΔGL. High energy polymers are the barrier preventing the relaxation of the T and R conformations into one another. The MWC allosteric model is the best justification of oxygen binding cooperativity . PMID:23710673

  18. High-energy communication

    CERN Multimedia

    CERN Communication Group

    2015-01-01

    On Wednesday at 10.40 a.m., the LHC operators declared “stable beams” after two years of technical stop and a few months of commissioning. It was an exciting day for all the teams involved, including those who worked on communicating the news to the public and the media on multiple platforms.   CERN’s most successful tweet on 3 June featured collision images from ALICE, ATLAS, CMS and LHCb and was shared 800 times by the Twitter audience. Live blogging, social media posts, a live webcast, and a constant outpouring of photos and videos: Wednesday morning was a crazy time for the communication teams from CERN, the experiments and various institutes around the world. Even though the event started very early in the morning (the live CCC blog started at 7 a.m. and the live webcast at 8.20 a.m.), the public and the media tuned in to follow and generously cover the start of the LHC’s physics run at an unprecedented energy of 13 TeV. The statistics showed th...

  19. High energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Kernan, A.; Shen, B.C.; Ma, E.

    1997-07-01

    Hadron collider studies will focus on: (i) the search for the top quark with the newly installed D0 detector at the Fermilab Tevatron collider, (ii) the upgrade of the D0 detector to match the new main injector luminosity and (iii) R&D on silicon microstrip tracking devices for the SSC. High statistics studies of Z{sup 0} decay will continue with the OPAL detector at LEP. These studies will include a direct measurement of Z decay to neutrinos, the search for Higgs and heavy quark decays of Z. Preparations for the Large Scintillation Neutrino Detector (LSND) to measure neutrino oscillations at LAMPF will focus on data acquisition and testing of photomultiplier tubes. In the theoretical area E. Ma will concentrate on mass-generating radiative mechanisms for light quarks and leptons in renormalizable gauge field theories. J. Wudka`s program includes a detailed investigation of the magnetic-flip approach to the solar neutrino.

  20. Oxygen at high pressures: a theoretical approach to monoatomic phases.

    Science.gov (United States)

    Oda, T; Sugimori, K; Nagao, H; Hamada, I; Kagayama, S; Geshi, M; Nagara, H; Kusakabe, K; Suzuki, N

    2007-09-12

    We have studied the ζ-phase of solid oxygen using the generalized gradient approximation in the density functional approach. Calculations of total energies and pressures have been carried out for the prototype of diatomic ζ-phase and other hypothetical monoatomic crystal structures. The diatomic phase was found to be stable over a wide range of pressure (100-2000 GPa). The stacking of molecular layers is discussed in comparison with the available experimental data.

  1. High energy physics

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-10

    The Counter Group continues to work on data analysis for Fermilab Experiment E653. Altogether, they expect several thousand reconstructed charm events and approximately 25 B pair events of which 12 have been observed thus far. Preparation continue for Fermilab Experiment E781, a high statistics study of charm baryon production. In the Theory Group, Cutkosky and collaborators study hadron phenomenology and non-perturbative QCD calculations. Levine has a long standing program in computational QED to obtain improved theoretical values for g-2 of the electron. Wolfenstein, Li, and their collaborators have worked on areas of weak interaction phenomenology that may yield insights beyond the standard model, e.g. CP violation and non-zero neutrino masses. Holman has been concerned with phase transitions in gauge theories relevant to cosmological problems. During 1991 most of the group effort was concentrated on the L3 experiment at CERN. Highlights of the results from the analysis of the Z[degrees] resonance include (a) a measurement of the strong coupling constant [alpha][sub s] for b quarks (b) a precision measurement of the average time of B hadrons and (c) a direct determination of the number of light neutrino faculties from the reaction e[sup +]e[sup [minus

  2. Sorbent-based Oxygen Production for Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Sethi, Vijay [Western Research Inst. (WRI), Laramie, WY (United States)

    2017-01-31

    Project DE-FE0024075 deals with the development of a moderate-temperature sorbent-based oxygen production technology. Sorbent-based oxygen production process utilizes oxygen-storage properties of Perovskites to (1) adsorb oxygen from air in a solid sorbent, and (2) release the adsorbed oxygen into a sweep gas such as CO2 and/or steam for gasification systems or recycled flue gas for oxy-combustion systems. Pure oxygen can be produced by the use of vacuum instead of a sweep gas to affect the pressure swing. By developing more efficient and stable, higher sorption capacity, newer class of materials operating at moderate temperatures this process represents a major advancement in air separation technology. Newly developed perovskite ceramic sorbent materials with order-disorder transition have a higher O2 adsorption capacity, potentially 200 °C lower operating temperatures, and up to two orders of magnitude faster desorption rates than those used in earlier development efforts. The performance advancements afforded by the new materials lead to substantial savings in capital investment and operational costs. Cost of producing oxygen using sorbents could be as much as 26% lower than VPSA and about 13% lower than a large cryogenic air separation unit. Cost advantage against large cryogenic separation is limited because sorbent-based separation numbers up sorbent modules for achieving the larger capacity.

  3. High energy physics

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-10

    The Counter Group continues to work on data analysis for Fermilab Experiment E653. Altogether, they expect several thousand reconstructed charm events and approximately 25 B pair events of which 12 have been observed thus far. Preparation continue for Fermilab Experiment E781, a high statistics study of charm baryon production. In the Theory Group, Cutkosky and collaborators study hadron phenomenology and non-perturbative QCD calculations. Levine has a long standing program in computational QED to obtain improved theoretical values for g-2 of the electron. Wolfenstein, Li, and their collaborators have worked on areas of weak interaction phenomenology that may yield insights beyond the standard model, e.g. CP violation and non-zero neutrino masses. Holman has been concerned with phase transitions in gauge theories relevant to cosmological problems. During 1991 most of the group effort was concentrated on the L3 experiment at CERN. Highlights of the results from the analysis of the Z{degrees} resonance include (a) a measurement of the strong coupling constant {alpha}{sub s} for b quarks (b) a precision measurement of the average time of B hadrons and (c) a direct determination of the number of light neutrino faculties from the reaction e{sup +}e{sup {minus}} {yields} {nu}{bar {nu}}{gamma}. We also began a major upgrade of the L3 luminosity monitor by replacing PWC chamber by a Si strip system in front of the BGO calorimeters. Finally we have continued our SSC R&D work on BaF{sub 2} by joining the GEM collaboration.

  4. Developments in high energy theory

    Indian Academy of Sciences (India)

    It provides a panoramic view of the main theoretical developments in high energy physics since its inception more than half a century ago, a period in which experiments have spanned an enormous range of energies, theories have been developed leading up to the Standard Model, and proposals – including the radical ...

  5. CPAP and High-Flow Nasal Cannula Oxygen in Bronchiolitis.

    Science.gov (United States)

    Sinha, Ian P; McBride, Antonia K S; Smith, Rachel; Fernandes, Ricardo M

    2015-09-01

    Severe respiratory failure develops in some infants with bronchiolitis because of a complex pathophysiologic process involving increased airways resistance, alveolar atelectasis, muscle fatigue, and hypoxemia due to mismatch between ventilation and perfusion. Nasal CPAP and high-flow nasal cannula (HFNC) oxygen may improve the work of breathing and oxygenation. Although the mechanisms behind these noninvasive modalities of respiratory support are not well understood, they may help infants by way of distending pressure and delivery of high concentrations of warmed and humidified oxygen. Observational studies of varying quality have suggested that CPAP and HFNC may confer direct physiologic benefits to infants with bronchiolitis and that their use has reduced the need for intubation. No trials to our knowledge, however, have compared CPAP with HFNC in bronchiolitis. Two randomized trials compared CPAP with oxygen delivered by low-flow nasal cannula or face mask and found some improvements in blood gas results and some physiologic parameters, but these trials were unable to demonstrate a reduction in the need for intubation. Two trials evaluated HFNC in bronchiolitis (one comparing it with headbox oxygen, the other with nebulized hypertonic saline), with the results not seeming to suggest important clinical or physiologic benefits. In this article, we review the pathophysiology of respiratory failure in bronchiolitis, discuss these trials in detail, and consider how future research studies may be designed to best evaluate CPAP and HFNC in bronchiolitis.

  6. Plant respirometer enables high resolution of oxygen consumption rates

    Science.gov (United States)

    Foster, D. L.

    1966-01-01

    Plant respirometer permits high resolution of relatively small changes in the rate of oxygen consumed by plant organisms undergoing oxidative metabolism in a nonphotosynthetic state. The two stage supply and monitoring system operates by a differential pressure transducer and provides a calibrated output by digital or analog signals.

  7. High Energy Density Laboratory Astrophysics

    CERN Document Server

    Lebedev, Sergey V

    2007-01-01

    During the past decade, research teams around the world have developed astrophysics-relevant research utilizing high energy-density facilities such as intense lasers and z-pinches. Every two years, at the International conference on High Energy Density Laboratory Astrophysics, scientists interested in this emerging field discuss the progress in topics covering: - Stellar evolution, stellar envelopes, opacities, radiation transport - Planetary Interiors, high-pressure EOS, dense plasma atomic physics - Supernovae, gamma-ray bursts, exploding systems, strong shocks, turbulent mixing - Supernova remnants, shock processing, radiative shocks - Astrophysical jets, high-Mach-number flows, magnetized radiative jets, magnetic reconnection - Compact object accretion disks, x-ray photoionized plasmas - Ultrastrong fields, particle acceleration, collisionless shocks. These proceedings cover many of the invited and contributed papers presented at the 6th International Conference on High Energy Density Laboratory Astrophys...

  8. High-energy astroparticle physics

    CERN Document Server

    Semikoz, A

    2010-01-01

    In these three lectures I discuss the present status of high-energy astroparticle physics including Ultra-High-Energy Cosmic Rays (UHECR), high-energy gamma rays, and neutrinos. The first lecture is devoted to ultra-high-energy cosmic rays. After a brief introduction to UHECR I discuss the acceleration of charged particles to highest energies in the astrophysical objects, their propagation in the intergalactic space, recent observational results by the Auger and HiRes experiments, anisotropies of UHECR arrival directions, and secondary gamma rays produced by UHECR. In the second lecture I review recent results on TeV gamma rays. After a short introduction to detection techniques, I discuss recent exciting results of the H.E.S.S., MAGIC, and Milagro experiments on the point-like and diffuse sources of TeV gamma rays. A special section is devoted to the detection of extragalactic magnetic fields with TeV gammaray measurements. Finally, in the third lecture I discuss Ultra-High-Energy (UHE) neutrinos. I review t...

  9. Portable High Sensitivity and High Resolution Sensor to Determine Oxygen Purity Levels Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of this Phase I STTR project is to develop a highly sensitive oxygen (O2) sensor, with high accuracy and precision, to determine purity levels of high...

  10. Assessing high wind energy penetration

    DEFF Research Database (Denmark)

    Tande, J.O.

    1995-01-01

    In order to convincingly promote installing wind power capacity as a substantial part of the energy supply system, a set of careful analyses must be undertaken. This paper applies a case study concentrated on assessing the cost/benefit of high wind energy penetration. The case study considers...... expanding the grid connected wind power capacity in Praia, the capital of Cape Verde. The currently installed 1 MW of wind power is estimated to supply close to 10% of the electric energy consumption in 1996. Increasing the wind energy penetration to a higher level is considered viable as the project...... with the existing wind power, supply over 30% of the electric consumption in 1996. Applying the recommended practices for estimating the cost of wind energy, the life-cycle cost of this 2.4 MW investment is estimated at a 7% discount rate and a 20 year lifetime to 0.26 DKK/kW h....

  11. Heart rate during basketball game play and volleyball drills accurately predicts oxygen uptake and energy expenditure.

    Science.gov (United States)

    Scribbans, T D; Berg, K; Narazaki, K; Janssen, I; Gurd, B J

    2015-09-01

    There is currently little information regarding the ability of metabolic prediction equations to accurately predict oxygen uptake and exercise intensity from heart rate (HR) during intermittent sport. The purpose of the present study was to develop and, cross-validate equations appropriate for accurately predicting oxygen cost (VO2) and energy expenditure from HR during intermittent sport participation. Eleven healthy adult males (19.9±1.1yrs) were recruited to establish the relationship between %VO2peak and %HRmax during low-intensity steady state endurance (END), moderate-intensity interval (MOD) and high intensity-interval exercise (HI), as performed on a cycle ergometer. Three equations (END, MOD, and HI) for predicting %VO2peak based on %HRmax were developed. HR and VO2 were directly measured during basketball games (6 male, 20.8±1.0 yrs; 6 female, 20.0±1.3yrs) and volleyball drills (12 female; 20.8±1.0yrs). Comparisons were made between measured and predicted VO2 and energy expenditure using the 3 equations developed and 2 previously published equations. The END and MOD equations accurately predicted VO2 and energy expenditure, while the HI equation underestimated, and the previously published equations systematically overestimated VO2 and energy expenditure. Intermittent sport VO2 and energy expenditure can be accurately predicted from heart rate data using either the END (%VO2peak=%HRmax x 1.008-17.17) or MOD (%VO2peak=%HRmax x 1.2-32) equations. These 2 simple equations provide an accessible and cost-effective method for accurate estimation of exercise intensity and energy expenditure during intermittent sport.

  12. High-energy scissors mode

    Energy Technology Data Exchange (ETDEWEB)

    Nojarov, R.; Faessler, A.; Dingfelder, M. [Institut fuer Theoretische Physik, Universitaet Tuebingen, Auf der Morgenstelle 14, D-72076 Tuebingen (Germany)

    1995-05-01

    All the orbital {ital M}1 excitations, at both low and high energies, obtained from a rotationally invariant quasiparticle random-phase approximation, represent the fragmented scissors mode. The high-energy {ital M}1 strength is almost purely orbital and resides in the region of the isovector giant quadrupole resonance. In heavy deformed nuclei the high-energy scissors model is strongly fragmented between 17 and 25 MeV (with uncertainties arising from the poor knowledge of the isovector potential). The coherent scissors motion is hindered by the fragmentation and {ital B}({ital M}1){lt}0.25{mu}{sub {ital N}}{sup 2} for single transitions in this region. The ({ital e},{ital e}{prime}) cross sections for excitations above 17 MeV are one order of magnitude larger for {ital E}2 than for {ital M}1 excitations even at backward angles.

  13. High-Efficiency, High-Capacity, Low-NOx Aluminum Melting Using Oxygen-Enhanced Combustion

    Energy Technology Data Exchange (ETDEWEB)

    D' Agostini, M.D.

    2000-06-02

    This report describes the development and application of a novel oxygen enhanced combustion system with an integrated vacuum swing adsorption (VSA) oxygen supply providing efficient, low NOx melting in secondary aluminum furnaces. The mainstay of the combustion system is a novel air-oxy-natural gas burner that achieves high productivity and energy efficiency with low NOx emissions through advanced mixing concepts and the use of separate high- and low-purity oxidizer streams. The technology was installed on a reverberatory, secondary aluminum melting plant at the Wabash Aluminum Alloy's Syracuse, N.Y. plant, where it is currently in operation. Field testing gave evidence that the new burner technology meets the stringent NOx emissions target of 0.323 lb NO2/ton aluminum, thus complying with regulations promulgated by Southern California's South Coast Air Quality Management District (SCAQMD). Test results also indicated that the burner technology exceeded fuel efficiency and melting capacity goals. Economic modeling showed that the novel air-oxy-fuel (ADF) combustion technology provides a substantial increase in furnace profitability relative to air-fuel operation. Model results also suggest favorable economics for the air-oxy-fuel technology relative to a full oxy-fuel conversion of the furnace.

  14. High energy astrophysics. An introduction

    Energy Technology Data Exchange (ETDEWEB)

    Courvoisier, Thierry J.L. [Geneva Univ., Versoix (Switzerland). ISDC, Data Centre for Astrophysics

    2013-07-01

    Based on observational examples this book reveals and explains high-energy astrophysical processes. Presents the theory of astrophysical processes in a didactic approach by deriving equations step by step. With several attractive astronomical pictures. High-energy astrophysics has unveiled a Universe very different from that only known from optical observations. It has revealed many types of objects in which typical variability timescales are as short as years, months, days, and hours (in quasars, X-ray binaries, and other objects), and even down to milli-seconds in gamma ray bursts. The sources of energy that are encountered are only very seldom nuclear fusion, and most of the time gravitation, a paradox when one thinks that gravitation is, by many orders of magnitude, the weakest of the fundamental interactions. The understanding of these objects' physical conditions and the processes revealed by high-energy astrophysics in the last decades is nowadays part of astrophysicists' culture, even of those active in other domains of astronomy. This book evolved from lectures given to master and PhD students at the University of Geneva since the early 1990s. It aims at providing astronomers and physicists intending to be active in high-energy astrophysics a broad basis on which they should be able to build the more specific knowledge they will need. While in the first part of the book the physical processes are described and derived in detail, the second part studies astrophysical objects in which high-energy astrophysics plays a crucial role. This two-pronged approach will help students recognise physical processes by their observational signatures in contexts that may differ widely from those presented here.

  15. A Lithium-Air Battery with a High Energy Air Cathode Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This project will advance an efficient and lightweight energy storage device for Oxygen Concentrators by developing a high specific energy lithium-air cell....

  16. High-energy atomic physics

    CERN Document Server

    Drukarev, Evgeny G

    2016-01-01

    This self-contained text introduces readers to the field of high-energy atomic physics - a new regime of photon-atom interactions in which the photon energies significantly exceed the atomic or molecular binding energies, and which opened up with the recent advent of new synchrotron sources. From a theoretical point of view, a small-parameter characteristic of the bound system emerged, making it possible to perform analytic perturbative calculations that can in turn serve as benchmarks for more powerful numerical computations. The first part of the book introduces readers to the foundations of this new regime and its theoretical treatment. In particular, the validity of the small-parameter perturbation expansion and of the lowest-order approximation is critically reviewed. The following chapters then apply these insights to various atomic processes, such as photoionization as a many-body problem, dominant mechanisms for the production of ions at higher energies, Compton scattering and ionization accompanied b...

  17. Energy and materials flows in the production of liquid and gaseous oxygen

    Energy Technology Data Exchange (ETDEWEB)

    Shen, S.; Wolsky, A.M.

    1980-08-01

    Liquid and gaseous oxygen is produced in an energy-intensive air separation processo that also generates nitrogen. More than 65% of the cost of oxygen is attributable to energy costs. Energy use and materials flows are analyzed for various air separation methods. Effective approaches to energy and material conservation in air separation plants include efficient removal of contaminants (carbon dioxide and water), centralization of air products user-industries so that large air separation plants are cost-effective and the energy use in transportation is minimized, and increased production of nitrogen. Air separation plants can produce more than three times more nitrogen than oxygen, but present markets demand, at most, only 1.5 times more. Full utlization of liquid and gaseous nitrogen should be encouraged, so that the wasted separation energy is minimized. There are potential markets for nitrogen in, for example, cryogenic separation of metallic and plastic wastes, cryogenic particle size reduction, and production of ammonia for fertilizer.

  18. High performance platinum single atom electrocatalyst for oxygen reduction reaction

    Science.gov (United States)

    Liu, Jing; Jiao, Menggai; Lu, Lanlu; Barkholtz, Heather M.; Li, Yuping; Wang, Ying; Jiang, Luhua; Wu, Zhijian; Liu, Di-Jia; Zhuang, Lin; Ma, Chao; Zeng, Jie; Zhang, Bingsen; Su, Dangsheng; Song, Ping; Xing, Wei; Xu, Weilin; Wang, Ying; Jiang, Zheng; Sun, Gongquan

    2017-07-01

    For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/methanol tolerance for the cathodic oxygen reduction reaction. The acidic single-cell with such a catalyst as cathode delivers high performance, with power density up to 680 mW cm-2 at 80 °C with a low platinum loading of 0.09 mgPt cm-2, corresponding to a platinum utilization of 0.13 gPt kW-1 in the fuel cell. Good fuel cell durability is also observed. Theoretical calculations reveal that the main effective sites on such platinum single-atom electrocatalysts are single-pyridinic-nitrogen-atom-anchored single-platinum-atom centres, which are tolerant to carbon monoxide/methanol, but highly active for the oxygen reduction reaction.

  19. High performance platinum single atom electrocatalyst for oxygen reduction reaction

    Science.gov (United States)

    Liu, Jing; Jiao, Menggai; Lu, Lanlu; Barkholtz, Heather M.; Li, Yuping; Wang, Ying; Jiang, Luhua; Wu, Zhijian; Liu, Di-jia; Zhuang, Lin; Ma, Chao; Zeng, Jie; Zhang, Bingsen; Su, Dangsheng; Song, Ping; Xing, Wei; Xu, Weilin; Wang, Ying; Jiang, Zheng; Sun, Gongquan

    2017-01-01

    For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/methanol tolerance for the cathodic oxygen reduction reaction. The acidic single-cell with such a catalyst as cathode delivers high performance, with power density up to 680 mW cm−2 at 80 °C with a low platinum loading of 0.09 mgPt cm−2, corresponding to a platinum utilization of 0.13 gPt kW−1 in the fuel cell. Good fuel cell durability is also observed. Theoretical calculations reveal that the main effective sites on such platinum single-atom electrocatalysts are single-pyridinic-nitrogen-atom-anchored single-platinum-atom centres, which are tolerant to carbon monoxide/methanol, but highly active for the oxygen reduction reaction. PMID:28737170

  20. Developments in high energy theory

    Indian Academy of Sciences (India)

    High-energy physics; gauge theories; Standard Model; physics beyond the ... elusive goal. The Standard Model describes the electromagnetic, weak and strong interactions, but only unifies the first two. Despite its spectacular success in ex ..... Towards the end of the 1960s, a path-breaking new 'deep inelastic' electron scat-.

  1. Are there ecological implications for the proposed energetic restrictions on photosynthetic oxygen evolution at high oxygen concentrations?

    Science.gov (United States)

    Raven, J A; Larkum, A W D

    2007-10-01

    It has recently been shown that, in subthylakoid particles prepared using detergent, there is inhibition of oxygen production reactions in photosynthesis by thermodynamic feedback from oxygen build-up, with 50% inhibition at 230 kPa partial pressure of oxygen. This article presents a comprehensive analysis of laboratory data on the effects of high oxygen partial pressures on photosynthesis, and on photo-lithotrophic and chemo-organotrophic growth, of oxygen-producing organisms. The article also contains an analysis of the extent to which high oxygen concentrations occur at the site of photosystem II (PSII) activity under natural conditions today and in the past. The conclusion is that the oxygen concentrations found in nature are very unlikely to reach that needed to cause 50% inhibition of the photosynthetic oxygen production reaction in subthylakoid particles, but that it is just possible that a small part of the inhibition of photosynthesis and of photo-lithotrophic growth by oxygen can be attributed to inhibition of oxygen production by PSII.

  2. High energy density aluminum battery

    Science.gov (United States)

    Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

    2016-10-11

    Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

  3. A high energy physics perspective

    Energy Technology Data Exchange (ETDEWEB)

    Marciano, W.J.

    1997-01-13

    The status of the Standard model and role of symmetry in its development are reviewed. Some outstanding problems are surveyed and possible solutions in the form of additional {open_quotes}Hidden Symmetries {close_quotes} are discussed. Experimental approaches to uncover {open_quotes}New Physics{close_quotes} associated with those symmetries are described with emphasis on high energy colliders. An outlook for the future is given.

  4. Quantum chromodynamics at high energy

    CERN Document Server

    Kovchegov, Yuri V

    2012-01-01

    Filling a gap in the current literature, this book is the first entirely dedicated to high energy QCD including parton saturation. It presents groundbreaking progress on the subject and describes many of the problems at the forefront of research, bringing postgraduate students, theorists and advanced experimentalists up to date with the current status of the field. A broad range of topics in high energy QCD are covered, most notably on the physics of parton saturation and the Color Glass Condensate (CGC). The material is presented in a pedagogical way, with numerous examples and exercises. Discussion ranges from the quasi-classical McLerran–Venugopalan model to the linear and non-linear BFKL/BK/JIMWLK small-x evolution equations. The authors adopt both a theoretical and experimental outlook and present the physics of strong interactions in a universal way, making it useful to physicists from various sub-communities and applicable to processes studied at high energy accelerators around the world.

  5. Cerebral oxygenation and energy metabolism in bacterial meningitis

    DEFF Research Database (Denmark)

    Larsen, Lykke

    Introduction: In a recent retrospective study of patients with severe bacterial meningitis we demonstrated that cerebral oxidative metabolism was affected in approximately 50% of the cases. An increase of lactate/pyruvate (LP) ratio above the upper normal limit, defined according to according...... bacterial meningitis; secondly to examine whether it is correct to separate the diagnosis of cerebral ischemia from mitochondrial dysfunction based exclusively on the biochemical pattern obtained during intracerebral microdialysis. Method: A prospective clinical study including patients with severe...... community acquired bacterial meningitis admitted to the Department of Infectious Diseases, Odense University Hospital, during the period January 2014 to June 2016. We relate data from measurements of brain tissue oxygen tension (PbtO2) to simultaneously recorded data reflecting cerebral cytoplasmic redox...

  6. Oxygen pathway modeling estimates high reactive oxygen species production above the highest permanent human habitation.

    Directory of Open Access Journals (Sweden)

    Isaac Cano

    Full Text Available The production of reactive oxygen species (ROS from the inner mitochondrial membrane is one of many fundamental processes governing the balance between health and disease. It is well known that ROS are necessary signaling molecules in gene expression, yet when expressed at high levels, ROS may cause oxidative stress and cell damage. Both hypoxia and hyperoxia may alter ROS production by changing mitochondrial Po2 (PmO2. Because PmO2 depends on the balance between O2 transport and utilization, we formulated an integrative mathematical model of O2 transport and utilization in skeletal muscle to predict conditions to cause abnormally high ROS generation. Simulations using data from healthy subjects during maximal exercise at sea level reveal little mitochondrial ROS production. However, altitude triggers high mitochondrial ROS production in muscle regions with high metabolic capacity but limited O2 delivery. This altitude roughly coincides with the highest location of permanent human habitation. Above 25,000 ft., more than 90% of exercising muscle is predicted to produce abnormally high levels of ROS, corresponding to the "death zone" in mountaineering.

  7. NOx emissions from high swirl turbulent spray flames with highly oxygenated fuels

    KAUST Repository

    Bohon, Myles

    2013-01-01

    Combustion of fuels with fuel bound oxygen is of interest from both a practical and a fundamental viewpoint. While a great deal of work has been done studying the effect of oxygenated additives in diesel and gasoline engines, much less has been done examining combustion characteristics of fuels with extremely high mass fractions of fuel bound oxygen. This work presents an initial investigation into the very low NOx emissions resulting from the combustion of a model, high oxygen mass fraction fuel. Glycerol was chosen as a model fuel with a fuel bound oxygen mass fraction of 52%, and was compared with emissions measured from diesel combustion at similar conditions in a high swirl turbulent spray flame. This work has shown that high fuel bound oxygen mass fractions allow for combustion at low global equivalence ratios with comparable exhaust gas temperatures due to the significantly lower concentrations of diluting nitrogen. Despite similar exhaust gas temperatures, NOx emissions from glycerol combustion were up to an order of magnitude lower than those measured using diesel fuel. This is shown to be a result not of specific burner geometry, but rather is influenced by the presence of higher oxygen and lower nitrogen concentrations at the flame front inhibiting NOx production. © 2012 The Combustion Institute.

  8. Blue whales (Balaenoptera musculus) optimize foraging efficiency by balancing oxygen use and energy gain as a function of prey density.

    Science.gov (United States)

    Hazen, Elliott Lee; Friedlaender, Ari Seth; Goldbogen, Jeremy Arthur

    2015-10-01

    Terrestrial predators can modulate the energy used for prey capture to maximize efficiency, but diving animals face the conflicting metabolic demands of energy intake and the minimization of oxygen depletion during a breath hold. It is thought that diving predators optimize their foraging success when oxygen use and energy gain act as competing currencies, but this hypothesis has not been rigorously tested because it has been difficult to measure the quality of prey that is targeted by free-ranging animals. We used high-resolution multisensor digital tags attached to foraging blue whales (Balaenoptera musculus) with concurrent acoustic prey measurements to quantify foraging performance across depth and prey density gradients. We parameterized two competing physiological models to estimate energy gain and expenditure based on foraging decisions. Our analyses show that at low prey densities, blue whale feeding rates and energy intake were low to minimize oxygen use, but at higher prey densities feeding frequency increased to maximize energy intake. Contrary to previous paradigms, we demonstrate that blue whales are not indiscriminate grazers but instead switch foraging strategies in response to variation in prey density and depth to maximize energetic efficiency.

  9. A new water energy dissipater for efficient energy dissipation and enriching the flow with dissolved oxygen content

    Directory of Open Access Journals (Sweden)

    Ashour Mohamed A.

    2014-03-01

    Full Text Available One of the most important problems Egypt is facing nowadays is saving and controlling the limited available quantity of water and its quality for irrigation and other purposes. Such goals may be achieved through different types of diversion head structures across the river and in the entrance of other carrying canals. The construction of diversion head structures, which usually causes many technical problems, should have the objective of solving and overcoming to protect the structure from failure. The main problem occurs downstream. Such structures have the harmful effect of converting the potential energy gained in the upstream side to a kinetic energy in the downstream side. This energy must be dissipated shortly and safely as near as possible to the head structure to avoid its destructive effect. The hydraulic jump is the most effective tool for the dissipation of water energy, accelerating the forming of the hydraulic jump downstream such structures became essential for achieving our main goal. Using energy dissipaters on the soled apron in the downstream side of the structures was the main technique for accelerating the hydraulic jump formation and dissipating great amount of the residual harmful kinetic energy occurring downstream head structures. So early, many researchers investigated different types, shapes, and arrangements of such dissipaters to evaluate its efficiency in dissipating the water energy and accelerating the forming of the hydraulic jump. In fact, in our present study we will try to investigate some other shapes of energy dissipaters, which have not been studied enough, by evaluating its positive technical impact on: (i percentage value of dissipating kinetic water energy; (ii percentage value of increasing the dissolved oxygen (DO content in the irrigation water, and improving its quality. The study is proposed to be held in the irrigation and hydraulic laboratory of the Civil department, Faculty of Engineering, Assiut

  10. Solubility of zinc ferrite in high-temperature oxygenated water

    Science.gov (United States)

    Hanzawa, Yukiko; Hiroishi, Daisuke; Matsuura, Chihiro; Ishigure, Kenkichi

    1998-02-01

    The solubility of zinc ferrite was measured at 423 K, 473 K, and 523 K in an oxygenated water system, which is rather similar to the chemical condition of boiling water reactors. Thermodynamic analysis was performed by a procedure minimizing standard Gibbs free energy of the system at the final state. From both the analysis and the experimental results it was concluded that the dissolution process of ZnFe 2O 4 in conditions where no redox reaction occurs is described by combination of ZnFe 2O 4 dissolution and Fe 2O 3 precipitation equilibria. By fitting to the experimental results, thermodynamic data of ZnFe 2O 4 are re-analyzed at 423 K, 473 K, and 523 K.

  11. Photoproduction at high energy and high intensity

    CERN Multimedia

    2002-01-01

    The photon beam used for this programme is tagged and provides a large flux up to very high energies (150-200 GeV). It is also hadron-free, since it is obtained by a two-step conversion method. A spectrometer is designed to exploit this beam and to perform a programme of photoproduction with a high level of sensitivity (5-50 events/picobarn).\\\\ \\\\ Priority will be given to the study of processes exhibiting the point-like behaviour of the photon, especially deep inelastic Compton scattering. The spectrometer has two magnets. Charged tracks are measured by MWPC's located only in field-free regions. Three calorimeters provide a large coverage for identifying and measuring electrons and photons. An iron filter downstream identifies muons. Most of the equipment is existing and recuperated from previous experiments.

  12. Normocapnic high frequency oscillatory hyperventilation increases oxygenation in pigs.

    Science.gov (United States)

    Roubík, K; Pachl, J; Zábrodský, V

    2011-01-01

    High frequency oscillatory ventilation (HFOV), contrary to conventional ventilation, enables a safe increase in tidal volume (V(T)) without endangering alveoli by volutrauma or barotrauma. The aim of the study is to introduce the concept of normocapnic high frequency oscillatory hyperventilation and to assess its effect upon oxygen gain under experimental conditions. Laboratory pigs (n = 9) were investigated under total intravenous anesthesia in three phases. Phase 1: Initial volume controlled HFOV period. Phase 2: Hyperventilation--V(T) was increased by (46 +/- 12) % when compared to normocapnic V(T) during phase 1. All other ventilatory parameters were unchanged. A significant increase in PaO(2) (by 3.75 +/- 0.52 kPa, p hyperventilation was achieved by an iterative increase in the CO(2) fraction in the inspiratory gas by a CO(2) admixture. All ventilatory parameters were unchanged. A significant increase in PaO(2) (by 3.79 +/- 0.73 kPa, p hyperventilation offers a lung protective strategy that significantly improves oxygenation whilst preserving normocapnia.

  13. Duke University high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Fortney, L.R.; Goshaw, A.T.; Walker, W.D.

    1992-07-01

    This Progress Report presents a review of the research done in 1992 by the Duke High Energy Physics Group. This is the first year of a three-year grant which was approved by the Office of High Energy Physics at DOE after an external review of our research program during the summer of 1991. Our research is centered at Fermilab where we are involved with two active experiments, one using the Tevatron collider (CDF, the Collider Detector Facility) and the other using a proton beam in the high intensity laboratory (E771, study of beauty production). In addition to these running experiments we are continuing the analysis of data from experiments E735 (collider search for a quark-gluon plasma), E705 (fixed target study of direct photon and {sub {Chi}} meson production) and E597 (particle production from hadron-nucleus collisions). Finally, this year has seen an expansion of our involvement with the design of the central tracking detector for the Solenoidal Detector Collaboration (SDC) and an increased role in the governance of the collaboration. Descriptions of these research activities are presented in this report.

  14. Spatial control of the energy metabolism of yeast cells through electrolytic generation of oxygen.

    Science.gov (United States)

    Warnke, Christian; Mair, Thomas; Witte, Hartmut; Reiher, Antje; Hauser, Marcus J B; Krost, Alois

    2009-11-03

    The metabolic dynamics of yeast cells is controlled by electric pulses delivered through a spatially extended yeast cell/Au electrode interface. Concomitant with voltage pulses, oxygen is generated electrolytically at the electrode surface and delivered to the cells. The generation of oxygen was investigated in dependence of the applied voltage, width of the voltage pulses and temperature of the electrolytic solution. The local oxygen pulses at the electrodes lead to a transient activation of the aerobic energy metabolism of the yeast cells causing a perturbation in their energy balance. The effect of these local perturbations on the temporal dynamics of glycolysis in yeast cells is quantified in dependence of the energy state of cells.

  15. Spatial control of the energy metabolism of yeast cells through electrolytic generation of oxygen

    Science.gov (United States)

    Warnke, Christian; Mair, Thomas; Witte, Hartmut; Reiher, Antje; Hauser, Marcus J. B.; Krost, Alois

    2009-12-01

    The metabolic dynamics of yeast cells is controlled by electric pulses delivered through a spatially extended yeast cell/Au electrode interface. Concomitant with voltage pulses, oxygen is generated electrolytically at the electrode surface and delivered to the cells. The generation of oxygen was investigated in dependence of the applied voltage, width of the voltage pulses and temperature of the electrolytic solution. The local oxygen pulses at the electrodes lead to a transient activation of the aerobic energy metabolism of the yeast cells causing a perturbation in their energy balance. The effect of these local perturbations on the temporal dynamics of glycolysis in yeast cells is quantified in dependence of the energy state of cells.

  16. Oxygen deficient ZnO 1-x nanosheets with high visible light photocatalytic activity.

    Science.gov (United States)

    Guo, Hong-Li; Zhu, Qing; Wu, Xi-Lin; Jiang, Yi-Fan; Xie, Xiao; Xu, An-Wu

    2015-04-28

    Zinc oxide is one of the most important wide-band-gap (3.2 eV) materials with versatile properties, however, it can not be excited by visible light. In this work, we have developed an exquisite and simple way to prepare oxygen-deficient ZnO 1-x nanosheets with a gray-colored appearance and excellent visible light photocatalytic activity. Detailed analysis based on UV-Vis absorption spectra, X-band electron paramagnetic resonance (EPR) spectra, and photoluminescence (PL) spectra confirms the existence of oxygen vacancies in ZnO 1-x. The incorporation of oxygen defects could effectively extend the light absorption of ZnO 1-x into the visible-light region due to the fact that the energy of the localized state is located in the forbidden gap. Thus, our obtained ZnO 1-x shows a higher photodegradation of methyl orange (MO) compared to defect-free ZnO under visible light illumination. Additionally, the high content of ˙OH radicals with a strong photo-oxidation capability over the ZnO 1-x nanosheets significantly contributes to the improvement in the photocatalytic performance. Our oxygen deficient ZnO 1-x sample shows a very high photocatalytic activity for the degradation of MO even after 5 cycles without any obvious decline. The results demonstrate that defect engineering is a powerful tool to enhance the optoelectronic and photocatalytic performances of nanomaterials.

  17. Investigation on the improved radiation hardness of silicon detectors with high oxygen concentration

    CERN Document Server

    Moll, Michael; Lindström, G

    2000-01-01

    We present an investigation on the influence of the oxygen concentration on radiation-induced changes in the effective doping concentration of silicon detectors. Diodes fabricated from silicon with interstitial oxygen content ranging from below 2*10/sup 14/ to 9*10/sup 17/ cm/sup -3/ have been irradiated with fast neutrons up to a fluence of 2*10/sup 15/ cm/sup -2/. Our main interest focused on the so-called stable damage component in the change of the effective doping concentration being of prime importance for the application of silicon detectors in high-energy physics experiments. We demonstrate, that with a high oxygen enrichment the donor removal is appreciably reduced, reaching a value of only 10601130f the initial doping concentration for [O/sub i/]=9*10/sup 17/ cm/sup -3/, while for normal detector grade material with [O/sub i/] below 5*10/sup 16/ cm /sup -3/ that value is 60-90Furthermore, we show that the fluence proportional introduction of stable acceptors is independent of the oxygen concentratio...

  18. High altitude may alter oxygen availability and renal metabolism in diabetics as measured by hyperpolarized [1-1C]pyruvate magnetic resonance imaging

    DEFF Research Database (Denmark)

    Laustsen, Christoffer; Lycke, Sara; Palm, Fredrik

    2014-01-01

    . The importance of deranged oxygen metabolism is further supported by deterioration of kidney function in patients with diabetes living at high altitude. Thus, we argue that reduced oxygen availability alters renal energy metabolism. Here, we introduce a novel magnetic resonance imaging (MRI) approach to monitor...... of nephropathy in patients with diabetes at high altitudes may originate from the increased sensitivity toward inspired oxygen. This increased lactate production shifts the metabolic routs toward hypoxic pathways....

  19. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    Science.gov (United States)

    Jujasz, Albert J.; Burkhart, James A.; Greenberg, Ralph

    1988-01-01

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  20. Experimental High Energy Physics Research

    Energy Technology Data Exchange (ETDEWEB)

    Hohlmann, Marcus [Florida Inst. of Technology, Melbourne, FL (United States). Dept. of Physics and Space Sciences

    2016-01-13

    This final report summarizes activities of the Florida Tech High Energy Physics group supported by DOE under grant #DE-SC0008024 during the period June 2012 – March 2015. We focused on one of the main HEP research thrusts at the Energy Frontier by participating in the CMS experiment. We were exploiting the tremendous physics opportunities at the Large Hadron Collider (LHC) and prepared for physics at its planned extension, the High-Luminosity LHC. The effort comprised a physics component with analysis of data from the first LHC run and contributions to the CMS Phase-2 upgrades in the muon endcap system (EMU) for the High-Luminosity LHC. The emphasis of our hardware work was the development of large-area Gas Electron Multipliers (GEMs) for the CMS forward muon upgrade. We built a production and testing site for such detectors at Florida Tech to complement future chamber production at CERN. The first full-scale CMS GE1/1 chamber prototype ever built outside of CERN was constructed at Florida Tech in summer 2013. We conducted two beam tests with GEM prototype chambers at CERN in 2012 and at FNAL in 2013 and reported the results at conferences and in publications. Principal Investigator Hohlmann served as chair of the collaboration board of the CMS GEM collaboration and as co-coordinator of the GEM detector working group. He edited and authored sections of the detector chapter of the Technical Design Report (TDR) for the GEM muon upgrade, which was approved by the LHCC and the CERN Research Board in 2015. During the course of the TDR approval process, the GEM project was also established as an official subsystem of the muon system by the CMS muon institution board. On the physics side, graduate student Kalakhety performed a Z' search in the dimuon channel with the 2011 and 2012 CMS datasets that utilized 20.6 fb⁻¹ of p-p collisions at √s = 8 TeV. For the dimuon channel alone, the 95% CL lower limits obtained on the mass of a Z' resonance are 2770 Ge

  1. Highly oxygenated antiausterity agents from the leaves of Uvaria dac.

    Science.gov (United States)

    Awale, Suresh; Tawila, Ahmed M; Dibwe, Dya Fita; Ueda, Jun-Ya; Sun, Sijia; Athikomkulchai, Sirivan; Balachandran, Chandrashaker; Saiki, Ikuo; Matsumoto, Kinzo; Esumi, Hiroyasu

    2017-05-01

    From the chloroform extract of the leaves of Uvaria dac, four new highly-oxygenated cyclohexene derivatives named uvaridacols I-L (1-4) were isolated together with nine previously reported compounds (5-13). Their structures were determined based on the extensive NMR spectroscopic data and circular dichroism spectroscopic analysis. Among the new compounds, uvaridacol L (4) displayed strong preferential cytotoxicity in the nutrient deprived medium against five different tested pancreatic cancer cell lines, PANC-1 (PC50, 20.1μM), PSN-1 (PC50, 9.7μM), MIA PaCa-2 (PC50, 29.1μM), Capan-1 (73.0μM) and KLM-1 (25.9μM). Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Tactical high-energy laser

    Science.gov (United States)

    Shwartz, Josef; Wilson, Gerald T.; Avidor, Joel M.

    2002-06-01

    The Nautilus Project was started in 1995 as a joint US-Israel feasibility study for using laser systems to defend against short-range artillery rockets. It has now matured into a successful laser weapon demonstration program - the Tactical High Energy Laser (THEL) Advanced Concept Technology Demonstration (ACTD) Program. By now the THEL Demonstrator has engaged and destroyed a large number of artillery rockets in mid-flight in an extended series of demonstration tests at the US Army's White Sands Missile Range in New Mexico. The THEL ACTD hardware and development process are described in this paper, as well as the major test results. The paper also describes the operational concept for a deployed THEL weapon system and some possible growth paths for the THEL ACTD Program.

  3. High temperature thermoelectric energy conversion

    Science.gov (United States)

    Wood, Charles

    1987-01-01

    The theory and current status of materials research for high-temperature thermoelectric energy conversion are reviewed. Semiconductors are shown to be the preferred class of materials for this application. Optimization of the figure of merit of both broadband and narrow-band semiconductors is discussed as a function of temperature. Phonon scattering mechanisms are discussed, and basic material guidelines are given for reduction of thermal conductivity. Two general classes of materials show promise for high temperature figure of merit (Z) values, namely the rare earth chalcogenides and the boron-rich borides. The electronic transport properties of the rare earth chalcogenides are explicable on the basis of degenerate or partially degenerate n-type semiconductors. Boron and boron-rich borides exhibit p-type hopping conductivity, with detailed explanations proposed for the transport differing from compound to compound. Some discussion is presented on the reasons for the low thermal conductivities in these materials. Also, ZTs greater than one appear to have been realized at high temperature in many of these compounds.

  4. Effect of High Inspiratory Oxygen Fraction on Endothelial Dysfunction in Healthy Volunteers

    DEFF Research Database (Denmark)

    Larsen, Mikkel Hjordt Holm; Ekeløf, Sara; Kokotovic, Dunja

    2017-01-01

    It has been suggested that high inspiratory oxygen concentrations during anesthesia may be associated with higher postoperative mortality due to endothelial dysfunction. A randomized controlled crossover study was conducted with 25 healthy male volunteers. They inhaled an oxygen concentration of ...... unaffected. Inhalation of a high oxygen fraction in healthy volunteers did not result in a significant reduction of endothelial function....

  5. Fluorine-functionalized ionic liquids with high oxygen solubility

    OpenAIRE

    Vanhoutte, Gijs; Hojniak, Sandra; Bardé, Fanny; Binnemans, Koen; Fransaer, Jan

    2018-01-01

    Eight fluorine-functionalized ionic liquids were synthesized and the oxygen solubility was compared to commercial ionic liquids without the extra fluorinated chain. The concentration of dissolved oxygen increased with the fluorine content of the alkyl chain, which can be attached either to the cation or the anion. This approach maintains the freedom to design an ionic liquid for a specific application, while at the same time the oxygen solubility is increased.

  6. Comparison Between Cerebral Tissue Oxygen Tension and Energy Metabolism in Experimental Subdural Hematoma

    DEFF Research Database (Denmark)

    Nielsen, Troels Halfeld; Engell, Susanne I; Johnsen, Rikke Aagaard

    2011-01-01

    BACKGROUND: An experimental swine model (n = 7) simulating an acute subdural hematoma (ASDH) was employed (1) to explore the relation between the brain tissue oxygenation (PbtO(2)) and the regional cerebral energy metabolism as obtained by microdialysis, and (2) to define the lowest level of PbtO...

  7. The energy spectra of anomalous oxygen at the time of two successive solar minima

    CERN Document Server

    Kondratyeva, M A; Tretyakova, S P; Zhuravlev, D A

    1999-01-01

    The energy spectra of anomalous oxygen have been determined from nuclear track detectors exposed aboard the Earth-orbiting satellites at altitudes ranging from approx 250-400 km in two consecutive solar minimum periods of 1986-1987 and 1994-1995 with opposite polarity of the solar magnetic field. A comparison of the spectra shows no contradiction to current drift models.

  8. Luciferase-Rose Bengal conjugates for singlet oxygen generation by bioluminescence resonance energy transfer.

    Science.gov (United States)

    Kim, Seonghoon; Jo, HyeongChan; Jeon, Mijeong; Choi, Myung-Gyu; Hahn, Sei Kwang; Yun, Seok-Hyun

    2017-04-20

    Conjugates of Rose Bengal and Renilla luciferase generated singlet oxygen upon binding with coelenterazine via bioluminescence resonance energy transfer (BRET). Since the applications of conventional PDT have been limited to superficial lesions due to the limited light penetration in tissue, BRET activated PDT which does not require external light illumination may overcome the limitations of conventional PDT.

  9. Enzymatic versus Inorganic Oxygen Reduction Catalysts: Comparison of the Energy Levels in a Free-Energy Scheme

    DEFF Research Database (Denmark)

    Kjærgaard, Christian Hauge; Rossmeisl, Jan; Nørskov, Jens Kehlet

    2010-01-01

    In this paper, we present a method to directly compare the energy levels of intermediates in enzymatic and inorganic oxygen reduction catalysts. We initially describe how the energy levels of a Pt(111) catalyst, operating at pH = 0, are obtained. By a simple procedure, we then convert the energy...... overpotential of each system, which is shown to be significantly lower for the enzymatic catalysts compared to the inorganic Pt(111) catalyst. Finally, we construct theoretical polarization curves for the CcO models, in order to illustrate the effect of the low overpotentials on turnover rates per site....

  10. Silver nanoparticles induced reactive oxygen species via photosynthetic energy transport imbalance in an aquatic plant.

    Science.gov (United States)

    Jiang, Hong Sheng; Yin, Li Yan; Ren, Na Na; Zhao, Su Ting; Li, Zhi; Zhi, Yongwei; Shao, Hui; Li, Wei; Gontero, Brigitte

    2017-03-01

    The rapid growth in silver nanoparticles (AgNPs) commercialization has increased environmental exposure, including aquatic ecosystem. It has been reported that the AgNPs have damaging effects on photosynthesis and induce oxidative stress, but the toxic mechanism of AgNPs is still a matter of debate. In the present study, on the model aquatic higher plant Spirodela polyrhiza, we found that AgNPs affect photosynthesis and significantly inhibit Photosystem II (PSII) maximum quantum yield (F v /F m ) and effective quantum yield (Φ PSII ). The changes of non-photochemical fluorescence quenching (NPQ), light-induced non-photochemical fluorescence quenching [Y(NPQ)] and non-light-induced non-photochemical fluorescence quenching [Y(NO)] showed that AgNPs inhibit the photo-protective capacity of PSII. AgNPs induce reactive oxygen species (ROS) that are mainly produced in the chloroplast. The activity of ribulose-1, 5-bisphosphate carboxylase-oxygenase (Rubisco) was also very sensitive to AgNPs. The internalized Ag, regardless of whether the exposure was Ag +  or AgNPs had the same capacity to generate ROS. Our results support the hypothesis that intra-cellular AgNP dissociate into high toxic Ag + . Rubisco inhibition leads to slowing down of CO 2 assimilation. Consequently, the solar energy consumption decreases and then the excess excitation energy promotes ROS generation in chloroplast.

  11. Highly Efficient Oxygen Reduction Reaction Electrocatalysts Synthesized under Nanospace Confinement of Metal-Organic Framework.

    Science.gov (United States)

    Guo, Jianing; Li, Yang; Cheng, Yuanhui; Dai, Liming; Xiang, Zhonghua

    2017-08-22

    The output energy capacity of green electrochemical devices, e.g., fuel cells, depends strongly on the sluggish oxygen reduction reaction (ORR), which requires catalysts. One of the desired features for highly efficient ORR electrocatalytic materials is the richness of well-defined activate sites. Herein, we developed a facile approach to prepare highly efficient nonprecious metal and nitrogen-doped carbon-based ORR catalysts based on covalent organic polymers (COPs) synthesized in situ in the nanoconfined space of highly ordered metal organic frameworks (MOFs). The MOF templet ensured the developed electrocatalysts possess a high surface area with homogeneously distributed small metal/nitrogen active sites, as confirmed by X-ray absorption fine structure measurements and first-principles calculations, leading to highly efficient ORR electrocatalytic activity. Notably, the developed COP-TPP(Fe)@MOF-900 exhibits a 16 mV positive half-wave potential compared with the benchmarked Pt/C.

  12. High energy chemical laser system

    Science.gov (United States)

    Gregg, D.W.; Pearson, R.K.

    1975-12-23

    A high energy chemical laser system is described wherein explosive gaseous mixtures of a reducing agent providing hydrogen isotopes and interhalogen compounds are uniformly ignited by means of an electrical discharge, flash- photolysis or an electron beam. The resulting chemical explosion pumps a lasing chemical species, hydrogen fluoride or deuterium fluoride which is formed in the chemical reaction. The generated lasing pulse has light frequencies in the 3- micron range. Suitable interhalogen compounds include bromine trifluoride (BrF$sub 3$), bromine pentafluoride (BrF$sub 5$), chlorine monofluoride (ClF), chlorine trifluoride (ClF$sub 3$), chlorine pentafluoride (ClF$sub 5$), iodine pentafluoride (IF$sub 5$), and iodine heptafluoride (IF$sub 7$); and suitable reducing agents include hydrogen (H$sub 2$), hydrocarbons such as methane (CH$sub 4$), deuterium (D$sub 2$), and diborane (B$sub 2$H$sub 6$), as well as combinations of the gaseous compound and/or molecular mixtures of the reducing agent.

  13. Radii and Binding Energies in Oxygen Isotopes: A Challenge for Nuclear Forces.

    Science.gov (United States)

    Lapoux, V; Somà, V; Barbieri, C; Hergert, H; Holt, J D; Stroberg, S R

    2016-07-29

    We present a systematic study of both nuclear radii and binding energies in (even) oxygen isotopes from the valley of stability to the neutron drip line. Both charge and matter radii are compared to state-of-the-art ab initio calculations along with binding energy systematics. Experimental matter radii are obtained through a complete evaluation of the available elastic proton scattering data of oxygen isotopes. We show that, in spite of a good reproduction of binding energies, ab initio calculations with conventional nuclear interactions derived within chiral effective field theory fail to provide a realistic description of charge and matter radii. A novel version of two- and three-nucleon forces leads to considerable improvement of the simultaneous description of the three observables for stable isotopes but shows deficiencies for the most neutron-rich systems. Thus, crucial challenges related to the development of nuclear interactions remain.

  14. The reactivity of high oxygen coverages on Pd(110) in catalytic CO oxidation

    Science.gov (United States)

    Ladas, S.; Imbihl, R.; Ertl, G.

    1993-01-01

    The catalytic oxidation of CO on a Pd(110) surface has been investigated in CO titration experiments and under steady-state conditions in the 10 -4 Torr range. The reaction was followed by means of video-LEED, work function and rate measurements. The titration experiments with the oxygen-saturated Pd(110) surface revealed a change in the reaction mechanism from a uniform reduction of the oxygen coverage at high temperature ( T ≈ 500 K) to a hole-eating mechanism at low temperature ( T production. This effect, which presumably is associated with the formation of subsurface oxygen, can be attributed to a lowering of the CO residence time caused by a decrease in the adsorption energy of CO and to a reduction of the CO sticking coefficient. Under steady-state conditions this inhibiting effect leads to the appearance of a hysteresis in the high rate branch of the kinetics of catalytic CO oxidation upon cyclic variation of the CO pressure.

  15. Low-Energy Electron Diffraction Determination of the Structure of the Zeta Phase of Oxygen Physisorbed on Graphite

    DEFF Research Database (Denmark)

    Toney, Michael; Fain, S.C.

    1984-01-01

    Low-energy electron diffraction measurements on the ζ phase of diatomic oxygen physisorbed on the basal plane of graphite single crystals are reported for 12......Low-energy electron diffraction measurements on the ζ phase of diatomic oxygen physisorbed on the basal plane of graphite single crystals are reported for 12...

  16. Highly Oxygenated Flavonoids from the Leaves of Nicotiana plumbaginifolia (Solanaceae

    Directory of Open Access Journals (Sweden)

    Md. Shafiullah Shajib

    2017-11-01

    Full Text Available Nicotiana plumbaginifolia Viv. is an annual herb of the family Solanaceae, which grows abundantly in the weedy lands of Bangladesh . This plant possesses analgesic, antibacterial, anti-anxiety and hepatoprotective properties, and produces various phenolic compounds including flavonoids. The present study afforded determination of total phenolic and flavonoid contents, and for the first time, the isolation and characterization of highly oxygenated flavonoids, e.g., 3,3' ,5,6,7,8-hexamethoxy- 4',5'-methylenedioxyflavone (1, 3,3' ,4' ,5',5,6,7,8-octamethoxyflavone (2, exoticin, 6,7,4',5'-dimethylenedioxy-3,5,3'-trimethoxyflavone (3 and ( 3,3' ,4',5,5',8-hexamethoxy-6,7-methylenedioxyflavone (4 from the leaves of N. plumbaginifolia . All these flavonoids are rather rare natural products, and only found in a few genera, e.g.,Polygonum and Murraya. The structures of the isolated flavonoids were elucidated by comprehensive spectroscopic analyses, e.g., UV, 1H, 13C NMR, DEPT, HSQC, HMBC and MS.

  17. Formation of highly oxygenated organic molecules from aromatic compounds

    Directory of Open Access Journals (Sweden)

    U. Molteni

    2018-02-01

    Full Text Available Anthropogenic volatile organic compounds (AVOCs often dominate the urban atmosphere and consist to a large degree of aromatic hydrocarbons (ArHCs, such as benzene, toluene, xylenes, and trimethylbenzenes, e.g., from the handling and combustion of fuels. These compounds are important precursors for the formation of secondary organic aerosol. Here we show that the oxidation of aromatics with OH leads to a subsequent autoxidation chain reaction forming highly oxygenated molecules (HOMs with an O : C ratio of up to 1.09. This is exemplified for five single-ring ArHCs (benzene, toluene, o-/m-/p-xylene, mesitylene (1,3,5-trimethylbenzene and ethylbenzene, as well as two conjugated polycyclic ArHCs (naphthalene and biphenyl. We report the elemental composition of the HOMs and show the differences in the oxidation patterns of these ArHCs. A potential pathway for the formation of these HOMs from aromatics is presented and discussed. We hypothesize that AVOCs may contribute substantially to new particle formation events that have been detected in urban areas.

  18. Differential Diode Laser Sensor for High-Purity Oxygen Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A compact portable sensor for determining the purity of oxygen concentrations near 100 percent is proposed based on differential absorption of two beams from a diode...

  19. High Pressure Oxygen Generation for Future Exploration Missions Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is the development of a cathode feed electrolysis cell stack capable of generating 3600 psia oxygen at a relevant scale for future...

  20. Topical hyperbaric oxygen and low energy laser for the treatment of diabetic foot ulcers.

    Science.gov (United States)

    Landau, Z

    1998-01-01

    Fifty patients with chronic diabetic foot ulcers in whom conventional therapy had failed were treated with topical hyperbaric oxygen alone (15 patients) or in combination with a low energy laser (35 patients). Eleven of these patients were treated on an ambulatory basis with topical hyperbaric oxygen. The mean time the ulcer was present before therapy was 9+/-6.6 months. The mean number of treatments was 25+/-13, and the mean duration of therapy was 3+/-1.8 months. Forty-three of the 50 patients were cured. No adverse reactions were noted. Our impression is that topical hyperbaric oxygen alone or in combination with a low power laser are valuable adjuvants to conventional therapy for diabetic foot ulcers.

  1. Effect of high-oxygen and oxygen-free modified atmosphere packaging on the spoilage process of poultry breast fillets.

    Science.gov (United States)

    Rossaint, Sonja; Klausmann, Sonja; Kreyenschmidt, Judith

    2015-01-01

    A comparison was made of the effect of atmospheres containing high oxygen (70% O2 and 30% CO2) or high nitrogen (70% N2 and 30% CO2) on the spoilage process during storage (at 4°C) of poultry fillets. Four samples of each gas atmosphere were analyzed at 7 sample points during storage. For this analysis, the growth of typical spoilage organisms (Brochothrix thermosphacta, Pseudomonas spp., Enterobacteriaceae, and Lactobacilli spp.) and total viable count (TVC) were analyzed and modeled by using the Gompertz function. Sensory analyses of the poultry samples were carried out by trained sensory panelists to analyze color, odor, texture, drip loss, and general appearance. The composition of the spoilage flora differed between the oxygen-free atmosphere and the high-oxygen atmosphere. Anaerobic conditions favored the growth of Lactobacilli spp., whereas aerobic gas composition favored the growth of B. thermosphacta. However, no significant difference (Patmosphere in comparison to a high-nitrogen atmosphere. These results indicate that high-oxygen packaging has no additional beneficial effect on the quality maintenance and shelf life of fresh poultry fillets. © 2014 Poultry Science Association Inc.

  2. The production of low-energy neutral oxygen beams by grazing-incidence neutralization

    Science.gov (United States)

    Albridge, R. G.; Haglund, R. F.; Tolk, N. H.; Daech, A. F.

    1987-01-01

    The Vanderbilt University neutral oxygen facility produces beams of low-energy neutral oxygen atoms by means of grazing-incidence collisions between ion beams and metal surfaces. Residual ions are reflected by applied electric fields. This method can utilize initial ion beams of either O(+) or O2(+) since a very large percentage of molecular oxygen ions are dissociated when they undergo grazing-incidence neutralization. The method of neutralization is applicable to low-energy beams and to all ions. Particular emphasis is on O and N2 beams for simulation of the low Earth orbit space environment. Since the beam is a pure O-neutral beam and since measurements of the interaction of the beam with solid surfaces are made spectroscopically, absolute reaction rates can be determined. The technique permits the beams to be used in conjunction with electron and photon irradiation for studies of synergistic effects. Comparisons of optical spectra of Kapton excited by 2.5-keV O, O(+), and O2(+) show significant differences. Optical spectra of Kapton excited by neutral oxygen beams of less than 1 keV have been recorded.

  3. Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems.

    Science.gov (United States)

    Zhang, Wei; Lai, Wenzhen; Cao, Rui

    2017-02-22

    Globally increasing energy demands and environmental concerns related to the use of fossil fuels have stimulated extensive research to identify new energy systems and economies that are sustainable, clean, low cost, and environmentally benign. Hydrogen generation from solar-driven water splitting is a promising strategy to store solar energy in chemical bonds. The subsequent combustion of hydrogen in fuel cells produces electric energy, and the only exhaust is water. These two reactions compose an ideal process to provide clean and sustainable energy. In such a process, a hydrogen evolution reaction (HER), an oxygen evolution reaction (OER) during water splitting, and an oxygen reduction reaction (ORR) as a fuel cell cathodic reaction are key steps that affect the efficiency of the overall energy conversion. Catalysts play key roles in this process by improving the kinetics of these reactions. Porphyrin-based and corrole-based systems are versatile and can efficiently catalyze the ORR, OER, and HER. Because of the significance of energy-related small molecule activation, this review covers recent progress in hydrogen evolution, oxygen evolution, and oxygen reduction reactions catalyzed by porphyrins and corroles.

  4. High Energy Density Electrolytic Capacitor

    Science.gov (United States)

    Evans, David A.

    1996-01-01

    A new type of electrolytic capacitor which combines an electrolytic capacitor anode with an electrochemical capacitor cathode was developed. The resulting capacitor has a four time higher energy density than standard electrolytic capacitors, with comparable electric performance. The prototype, a 480 microFarad, 200 V device, has an energy density exceeding 4 J/cc. Now a 680 microFarad 50 V, MIL-style all tantalum device has been constructed and is undergoing qualification testing. Pending a favorable outcome, work will begin on other ratings. The potential for commercially significant development exists in applying this technology to aluminum-based electrolytic capacitors. It is possible to at least double the energy density of aluminum electrolytics, while using existing manufacturing methods, and without adding material expense. Data presented include electrical characteristics and performance measurements of the 200 V and 50 V hybrid capacitors and results from ongoing qualification testing of the MIL-style tantalum capacitors.

  5. Carbon monoxide production in low energy oxygen ion bombardment of pyrolytic graphite and Kapton surfaces

    Science.gov (United States)

    Horton, C. C.; Eck, T. G.; Hoffman, R. W.

    1986-01-01

    The results of an investigtion of the interaction of low energy oxygen ions with pyrolytic graphite and Kapton surface are reported. CO molecules emitted from the surface as a result of the ion bombardment were detected by a mass spectrometer. Because the ion-induced signals were small compared to that arising from the CO background pressure in the vacuum system, the ion beam was modulated and the modulated component of the CO signal measured with a lock-in amplifier. The quantum yield (CO molecules emitted per incident oxygen ion) for graphite rose from 1.9 at 4.5 eV ion energy to 6.6 at 465 eV. Comparable yields were obtained for Kapton. The large size of the yields suggests contributions to the reaction process from the background O2 molecules in the vacuum system.

  6. Systemic oxygen extraction during exercise at high altitude

    Science.gov (United States)

    Martin, D. S.; Cobb, A.; Meale, P.; Mitchell, K.; Edsell, M.; Mythen, M. G.; Grocott, M. P. W.; Adams, Tom; Biseker, Lindsay; Booth, Adam; Burdall, Oliver; Cobb, Alexandra; Cumpstey, Andrew; Dauncey, Steve; Edsell, Mark; Farrant, James; Feelisch, Martin; Fernandez, Bernadette; Firth, Oliver; Gilbert, Edward; Grant, Daniel; Grocott, Michael; Hennis, Phil; Jackson, Laura; Jenner, Will; van der Kaaij, Jildou; Khosravi, Maryam; Kortekaas, Edith; Levett, Denny; Mahomed, Zeyn; Martin, Daniel; Meale, Paula; Milledge, Jim; Mitchell, Kay; Mole, Damian; Moses, Oliver; Mythen, Michael; Rigat, Fabio; O'Doherty, Alasdair; Salam, Alex; Sanborn, Matt; Sheperdigian, Adam; Shrubb, Fiona; Simpson, Jo; Talbot, Nick; Wandrag, Liesel; Wijesingha, Savini; Williamson, Wilby; Woolley, Tom; Yow, Heng

    2015-01-01

    Background Classic teaching suggests that diminished availability of oxygen leads to increased tissue oxygen extraction yet evidence to support this notion in the context of hypoxaemia, as opposed to anaemia or cardiac failure, is limited. Methods At 75 m above sea level, and after 7–8 days of acclimatization to 4559 m, systemic oxygen extraction [C(a−v)O2] was calculated in five participants at rest and at peak exercise. Absolute [C(a−v)O2] was calculated by subtracting central venous oxygen content (CcvO2) from arterial oxygen content (CaO2) in blood sampled from central venous and peripheral arterial catheters, respectively. Oxygen uptake (V˙O2) was determined from expired gas analysis during exercise. Results Ascent to altitude resulted in significant hypoxaemia; median (range) SpO2 87.1 (82.5–90.7)% and PaO2 6.6 (5.7–6.8) kPa. While absolute C(a−v)O2 was reduced at maximum exercise at 4559 m [83.9 (67.5–120.9) ml litre−1 vs 99.6 (88.0–151.3) ml litre−1 at 75 m, P=0.043], there was no change in oxygen extraction ratio (OER) [C(a−v)O2/CaO2] between the two altitudes [0.52 (0.48–0.71) at 4559 m and 0.53 (0.49–0.73) at 75 m, P=0.500]. Comparison of C(a−v)O2 at peak V˙O2 at 4559 m and the equivalent V˙O2 at sea level for each participant also revealed no significant difference [83.9 (67.5–120.9) ml litre1 vs 81.2 (73.0–120.7) ml litre−1, respectively, P=0.225]. Conclusion In acclimatized individuals at 4559 m, there was a decline in maximum absolute C(a−v)O2 during exercise but no alteration in OER calculated using central venous oxygen measurements. This suggests that oxygen extraction may have become limited after exposure to 7–8 days of hypoxaemia. PMID:25501722

  7. Systemic oxygen extraction during exercise at high altitude.

    Science.gov (United States)

    Martin, D S; Cobb, A; Meale, P; Mitchell, K; Edsell, M; Mythen, M G; Grocott, M P W

    2015-04-01

    Classic teaching suggests that diminished availability of oxygen leads to increased tissue oxygen extraction yet evidence to support this notion in the context of hypoxaemia, as opposed to anaemia or cardiac failure, is limited. At 75 m above sea level, and after 7-8 days of acclimatization to 4559 m, systemic oxygen extraction [C(a-v)O2] was calculated in five participants at rest and at peak exercise. Absolute [C(a-v)O2] was calculated by subtracting central venous oxygen content (CcvO2) from arterial oxygen content [Formula: see text] in blood sampled from central venous and peripheral arterial catheters, respectively. Oxygen uptake [Formula: see text] was determined from expired gas analysis during exercise. Ascent to altitude resulted in significant hypoxaemia; median (range) [Formula: see text] 87.1 (82.5-90.7)% and [Formula: see text] 6.6 (5.7-6.8) kPa. While absolute C(a-v)O2 was reduced at maximum exercise at 4559 m [83.9 (67.5-120.9) ml litre(-1) vs 99.6 (88.0-151.3) ml litre(-1) at 75 m, P=0.043], there was no change in oxygen extraction ratio (OER) [C(a-v)O2/CaO2] between the two altitudes [0.52 (0.48-0.71) at 4559 m and 0.53 (0.49-0.73) at 75 m, P=0.500]. Comparison of C(a-v)O2 at peak [Formula: see text] at 4559 m and the equivalent [Formula: see text] at sea level for each participant also revealed no significant difference [83.9 (67.5-120.9) ml litre(1) vs 81.2 (73.0-120.7) ml litre(-1), respectively, P=0.225]. In acclimatized individuals at 4559 m, there was a decline in maximum absolute C(a-v)O2 during exercise but no alteration in OER calculated using central venous oxygen measurements. This suggests that oxygen extraction may have become limited after exposure to 7-8 days of hypoxaemia. © The Author 2014. Published by Oxford University Press on behalf of the British Journal of Anaesthesia.

  8. Generation of High Pressure Oxygen via Electrochemical Pumping in a Multi-Stage Electrolysis Stack

    Science.gov (United States)

    Setlock, John A (Inventor); Green, Robert D (Inventor); Farmer, Serene (Inventor)

    2017-01-01

    An oxygen pump can produce high-purity high-pressure oxygen. Oxygen ions (O(2-)) are electrochemically pumped through a multi-stage electrolysis stack of cells. Each cell includes an oxygen-ion conducting solid-state electrolyte between cathode and anode sides. Oxygen dissociates into the ions at the cathode side. The ions migrate across the electrolyte and recombine at the anode side. An insulator is between adjacent cells to electrically isolate each individual cell. Each cell receives a similar volt potential. Recombined oxygen from a previous stage can diffuse through the insulator to reach the cathode side of the next stage. Each successive stage similarly incrementally pressurizes the oxygen to produce a final elevated pressure.

  9. Generation of High Pressure Oxygen via Electrochemical Pumping in a Multi-stage Electrolysis Stack

    Science.gov (United States)

    Setlock, John A (Inventor); Green, Robert D (Inventor); Farmer, Serene (Inventor)

    2016-01-01

    An oxygen pump can produce high-purity high-pressure oxygen. Oxygen ions (O.sup.2-) are electrochemically pumped through a multi-stage electrolysis stack of cells. Each cell includes an oxygen-ion conducting solid-state electrolyte between cathode and anode sides. Oxygen dissociates into the ions at the cathode side. The ions migrate across the electrolyte and recombine at the anode side. An insulator is between adjacent cells to electrically isolate each individual cell. Each cell receives a similar volt potential. Recombined oxygen from a previous stage can diffuse through the insulator to reach the cathode side of the next stage. Each successive stage similarly incrementally pressurizes the oxygen to produce a final elevated pressure.

  10. High Energy Density Regenerative Fuel Cell Systems for Terrestrial Applications

    Science.gov (United States)

    Burke, Kenneth A.

    1999-01-01

    Regenerative Fuel Cell System (RFCS) technology for energy storage has been a NASA power system concept for many years. Compared to battery-based energy storage systems, RFCS has received relatively little attention or resources for development because the energy density and electrical efficiency were not sufficiently attractive relative to advanced battery systems. Even today, RFCS remains at a very low technology readiness level (TRL of about 2 indicating feasibility has been demonstrated). Commercial development of the Proton Exchange Membrane (PEM) fuel cells for automobiles and other terrestrial applications and improvements in lightweight pressure vessel design to reduce weight and improve performance make possible a high energy density RFCS energy storage system. The results from this study of a lightweight RFCS energy storage system for a remotely piloted, solar-powered, high altitude aircraft indicate an energy density up to 790 w-h/kg with electrical efficiency of 53.4% is attainable. Such an energy storage system would allow a solar-powered aircraft to carry hundreds of kilograms of payload and remain in flight indefinitely for use in atmospheric research, earth observation, resource mapping. and telecommunications. Future developments in the areas of hydrogen and oxygen storage, pressure vessel design, higher temperature and higher- pressure fuel cell operation, unitized regenerative fuel cells, and commercial development of fuel cell technology will improve both the energy density and electrical efficiency of the RFCS.

  11. High-CHO diet increases post-exercise oxygen consumption after a supramaximal exercise bout

    Science.gov (United States)

    Ferreira, G.A.; Bertuzzi, R.; De-Oliveira, F.R.; Pires, F.O.; Lima-Silva, A.E.

    2016-01-01

    We investigated if carbohydrate (CHO) availability could affect the excess post-exercise oxygen consumption (EPOC) after a single supramaximal exercise bout. Five physically active men cycled at 115% of peak oxygen uptake (V̇O2 peak) until exhaustion with low or high pre-exercise CHO availability. The endogenous CHO stores were manipulated by performing a glycogen-depletion exercise protocol 48 h before the trial, followed by 48 h consuming either a low- (10% CHO) or a high-CHO (80% CHO) diet regime. Compared to the low-CHO diet, the high-CHO diet increased time to exhaustion (3.0±0.6 min vs 4.4±0.6, respectively, P=0.01) and the total O2 consumption during the exercise (6.9±0.9 L and 11.3±2.1, respectively, P=0.01). This was accompanied by a higher EPOC magnitude (4.6±1.8 L vs 6.2±2.8, respectively, P=0.03) and a greater total O2 consumption throughout the session (exercise+recovery: 11.5±2.5 L vs 17.5±4.2, respectively, P=0.01). These results suggest that a single bout of supramaximal exercise performed with high CHO availability increases both exercise and post-exercise energy expenditure. PMID:27783812

  12. Developments in high energy theory

    Indian Academy of Sciences (India)

    them aimed at a final unification of all fundamental forces including gravity. Attempts have been made to extend the reach of some of these theories, based on an underlying string-theory picture, all the way to the Planck energy scale MPl = (8πGN). −1/2,. GN being Newton's gravitational constant. MPl is. Keywords.

  13. Split School of High Energy Physics 2015

    CERN Document Server

    2015-01-01

    Split School of High Energy Physics 2015 (SSHEP 2015) was held at the Faculty of Electrical Engineering, Mechanical Engineering and Naval Architecture (FESB), University of Split, from September 14 to September 18, 2015. SSHEP 2015 aimed at master and PhD students who were interested in topics pertaining to High Energy Physics. SSHEP 2015 is the sixth edition of the High Energy Physics School. Previous five editions were held at the Department of Physics, University of Sarajevo, Bosnia and Herzegovina.

  14. High-energy electron diffraction and microscopy

    CERN Document Server

    Peng, L M; Whelan, M J

    2011-01-01

    This book provides a comprehensive introduction to high energy electron diffraction and elastic and inelastic scattering of high energy electrons, with particular emphasis on applications to modern electron microscopy. Starting from a survey of fundamental phenomena, the authors introduce the most important concepts underlying modern understanding of high energy electron diffraction. Dynamical diffraction in transmission (THEED) and reflection (RHEED) geometries is treated using ageneral matrix theory, where computer programs and worked examples are provided to illustrate the concepts and to f

  15. Taurus Littrow Pyroclastic Deposit: High-Yield Feedstock for Lunar Oxygen

    Science.gov (United States)

    Allen, Carlton C.

    2015-01-01

    Future human habitation of the Moon will likely require the use of locally derived materials because of the high cost of transportation from Earth. Oxygen, extracted from oxides and silicates, is a potentially abundant lunar resource vital for life support and spacecraft propulsion. The anticipated costs of supplying all oxygen needs for a lunar base from Earth are high enough to warrant serious study of oxygen production from local resources.

  16. Combustion, respiration and intermittent exercise: a theoretical perspective on oxygen uptake and energy expenditure.

    Science.gov (United States)

    Scott, Christopher B

    2014-03-28

    While no doubt thought about for thousands of years, it was Antoine Lavoisier in the late 18th century who is largely credited with the first "modern" investigations of biological energy exchanges. From Lavoisier's work with combustion and respiration a scientific trend emerges that extends to the present day: the world gains a credible working hypothesis but validity goes missing, often for some time, until later confirmed using proper measures. This theme is applied to glucose/glycogen metabolism where energy exchanges are depicted as conversion from one form to another and, transfer from one place to another made by both the anaerobic and aerobic biochemical pathways within working skeletal muscle, and the hypothetical quantification of these components as part of an oxygen (O2) uptake measurement. The anaerobic and aerobic energy exchange components of metabolism are represented by two different interpretations of O2 uptake: one that contains a glycolytic component (1 L O2 = 21.1 kJ) and one that does not (1 L O2 = 19.6 kJ). When energy exchange transfer and oxygen-related expenditures are applied separately to exercise and recovery periods, an increased energy cost for intermittent as compared to continuous exercise is hypothesized to be a direct result.

  17. High Energy Astrophysics Science Archive Research Center

    Data.gov (United States)

    National Aeronautics and Space Administration — The High Energy Astrophysics Science Archive Research Center (HEASARC) is the primary archive for NASA missions dealing with extremely energetic phenomena, from...

  18. High Energy Solid State Laser Research Facility

    Data.gov (United States)

    Federal Laboratory Consortium — A suite of laboratories with advanced spectroscopic and laser equipment, this facility develops materials and techniques for advanced solid state high energy lasers....

  19. Scalable Self-Supported Graphene Foam for High-Performance Electrocatalytic Oxygen Evolution.

    Science.gov (United States)

    Zhu, Yun-Pei; Ran, Jingrun; Qiao, Shi-Zhang

    2017-12-06

    Developing efficient electrocatalysts consisting of earth-abundant elements for oxygen evolution reaction (OER) is crucial for energy devices and technologies. Herein, we report self-supported highly porous nitrogen-doped graphene foam synthesized through the electrochemical expansion of carbon-fiber paper and subsequent nitrogen plasma treatment. A thorough characterization, such as electron microscopy and synchrotron-based near-edge X-ray absorption fine structure, indicates the well-developed porous structures featuring homogeneously doped nitrogen heteroatoms. These merits ensure enriched active sites, an enlarged active surface area, and improved mass/electron transport within the continuous graphene framework, thus leading to an outstanding capability toward electrocatalyzing OER in alkaline media, even competitive with the state-of-the-art noble-/transition-metal and nonmetal electrocatalysts reported to date, from the perspectives of the sharp onset potential, a small Tafel slope, and remarkable durability. Furthermore, a rechargeable Zn-air battery with this self-supported electrocatalyst directly used as the air cathode renders a low charge/discharge overpotential and considerable life span. The finding herein suggests that a rational methodology to synthesize graphene-based materials can significantly enhance the oxygen electrocatalysis, thereby promoting the overall performance of the energy-related system.

  20. The interaction region of high energy protons

    CERN Document Server

    Dremin, I.M.

    2016-01-01

    The spatial view of the interaction region of colliding high energy protons (in terms of impact parameter) is considered. It is shown that the region of inelastic collisions has a very peculiar shape. It saturates for central collisions at an energy of 7 TeV. We speculate on the further evolution with energy, which is contrasted to the "black disk" picture.

  1. URBox : High tech energy and informal housing

    NARCIS (Netherlands)

    Cuperus, Y.J.; Smets, D.

    2011-01-01

    This paper reports on the URBox concept encompassing the high tech end of solar energy and informal low cost and affordable housing. It aims to contribute to solving the global energy crisis by building solar energy settlements in deserts where land is affordable and sunshine in abundance. First the

  2. Acetazolamide improves cerebral oxygenation during exercise at high altitude

    NARCIS (Netherlands)

    Vuyk, J.; Bos, J. van den; Terhell, K.; Bos, R. de; Vletter, A.; Valk, P.; Beuzekom, M. van; Kleef, J. van; Dahan, A.

    2006-01-01

    Acute mountain sickness is thought to be triggered by cerebral hypoxemia and be prevented by acetazolamide (Actz). The effect of Actz on cerebral oxygenation at altitude remains unknown. In 16 members of the 2005 Dutch Cho Oyu (8201 m, Tibet) expedition, the influence of Actz and exercise (750 mg PO

  3. Amorphous Cobalt Vanadium Oxide as a Highly Active Electrocatalyst for Oxygen Evolution.

    Science.gov (United States)

    Liardet, Laurent; Hu, Xile

    2018-01-05

    The water-splitting reaction provides a promising mechanism to store renewable energies in the form of hydrogen fuel. The oxidation half-reaction, the oxygen evolution reaction (OER), is a complex four-electron process that constitutes an efficiency bottleneck in water splitting. Here we report a highly active OER catalyst, cobalt vanadium oxide. The catalyst is designed on the basis of a volcano plot of metal-OH bond strength and activity. The catalyst can be synthesized by a facile hydrothermal route. The most active pure-phase material ( a- CoVO x ) is X-ray amorphous and provides a 10 mA cm -2 current density at an overpotential of 347 mV in 1 M KOH electrolyte when immobilized on a flat substrate. The synthetic method can also be applied to coat a high-surface-area substrate such as nickel foam. On this three-dimensional substrate, the a- CoVO x catalyst is highly active, reaching 10 mA cm -2 at 254 mV overpotential, with a Tafel slope of only 35 mV dec -1 . This work demonstrates a- CoVO x as a promising electrocatalyst for oxygen evolution and validates M-OH bond strength as a practical descriptor in OER catalysis.

  4. Gold-doped graphene: A highly stable and active electrocatalysts for the oxygen reduction reaction.

    Science.gov (United States)

    Stolbov, Sergey; Alcántara Ortigoza, Marisol

    2015-04-21

    In addressing the growing need of renewable and sustainable energy resources, hydrogen-fuel-cells stand as one of the most promising routes to transform the current energy paradigm into one that integrally fulfills environmental sustainability. Nevertheless, accomplishing this technology at a large scale demands to surpass the efficiency and enhance the cost-effectiveness of platinum-based cathodes, which catalyze the oxygen reduction reaction (ORR). In this work, our first-principles calculations show that Au atoms incorporated into graphene di-vacancies form a highly stable and cost-effective electrocatalyst that is, at the same time, as or more (dependently of the dopant concentration) active toward ORR than the best-known Pt-based electrocatalysts. We reveal that partial passivation of defected-graphene by gold atoms reduces the reactivity of C dangling bonds and increases that of Au, thus optimizing them for catalyzing the ORR and yielding a system of high thermodynamic and electrochemical stabilities. We also demonstrate that the linear relation among the binding energies of the reaction intermediates assumed in computational high-throughput material screening does not hold, at least for this non-purely transition-metal material. We expect Au-doped graphene to finally overcome the cathode-related challenge hindering the realization of hydrogen-fuel cells as the leading means of powering transportation and portable devices.

  5. Polarizing Oxygen Vacancies in Insulating Metal Oxides under a High Electric Field

    Science.gov (United States)

    Youssef, Mostafa; Van Vliet, Krystyn J.; Yildiz, Bilge

    2017-09-01

    We demonstrate a thermodynamic formulation to quantify defect formation energetics in an insulator under a high electric field. As a model system, we analyzed neutral oxygen vacancies (color centers) in alkaline-earth-metal binary oxides using density functional theory, Berry phase calculations, and maximally localized Wannier functions. The work of polarization lowers the field-dependent electric Gibbs energy of formation of this defect. This is attributed mainly to the ease of polarizing the two electrons trapped in the vacant site, and secondarily to the defect induced reduction in bond stiffness and softening of phonon modes. The formulation and analysis have implications for understanding the behavior of insulating oxides in electronic, magnetic, catalytic, and electrocaloric devices under a high electric field.

  6. High-Energy Neutrino Interactions

    CERN Multimedia

    2002-01-01

    This experiment studies neutrino interactions in iron at the highest available energies using the narrow-band neutrino beam N3 and the wide-band neutrino beam N1. The basis of the detector is a massive target-calorimeter in which the energy deposited by a neutrino (or antineutrino) is measured by electronic techniques and the momentum of outgoing muons is determined by magnetic deflection. The detector is constructed in the form of a 20 m long iron-cored toroidal magnet, composed of modules of length 70~cm and 90~cm, and of 3.75~m diameter. Drift chambers placed in between each module measure the trajectory of muons from the neutrino interactions. The modules are of three types. The first ten modules are constructed of 2.5~cm iron plates with 20~scintillator planes inserted between the plates. The next five modules are constructed of 5~cm plates with 15~planes of scintillator and the last six modules are constructed of 15~cm plates with 5~planes of scintillators. The total mass of the detector is @=~1400 tons...

  7. High Energy Particles from the Universe

    CERN Document Server

    Ong, R A

    2000-01-01

    The field of high energy particle astronomy is exciting and rapidly developing. In the last few years, we have detected extragalactic sources of intense TeV gamma radiation and individual cosmic ray particles with energies exceeding 25 Joules. Understanding the workings of astrophysics under extreme conditions is the primary goal of this field. Also important is the possibility of using high energy particles from space to probe beyond the standard models of particle physics and cosmology. This paper presents a review of high energy particle astronomy using photons, cosmic rays, and neutrinos.

  8. High Energy Density Capacitors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Capacitor size and reliability are often limiting factors in pulse power, high speed switching, and power management and distribution (PMAD) systems. T/J...

  9. Nanocatalysis for Primary and Secondary High Energy Lithium Oxygen Cells

    Science.gov (United States)

    2011-04-01

    DEGME-DMFA PC-DEGME-DMFA AC BDEFGH A B C D E F G H 1.5 2.0 2.5 3.0 0 100 200 300 400 500 600 700 C el l V ol ta ge , V Capacity, mAh/g, Carbon Imide/LiBOB...cells. A Celgard 2400 propylene microporous film (facing the lithium side) in contact with a nonwoven glass fiber paper and soaked with the

  10. High energy interactions of cosmic ray particles

    Science.gov (United States)

    Jones, L. W.

    1986-01-01

    The highlights of seven sessions of the Conference dealing with high energy interactions of cosmic rays are discussed. High energy cross section measurements; particle production-models of experiments; nuclei and nuclear matter; nucleus-nucleus collision; searches for magnetic monopoles; and studies of nucleon decay are covered.

  11. Graphene Oxide Bionanocomposite Coatings with High Oxygen Barrier Properties

    Directory of Open Access Journals (Sweden)

    Ilke Uysal Unalan

    2016-12-01

    Full Text Available In this work, we present the development of bionanocomposite coatings on poly(ethylene terephthalate (PET with outstanding oxygen barrier properties. Pullulan and graphene oxide (GO were used as main polymer phase and nanobuilding block (NBB, respectively. The oxygen barrier performance was investigated at different filler volume fractions (ϕ and as a function of different relative humidity (RH values. Noticeably, the impermeable nature of GO was reflected under dry conditions, in which an oxygen transmission rate (OTR, mL·m−2·24 h−1 value below the detection limit of the instrument (0.01 mL·m−2·24 h−1 was recorded, even for ϕ as low as 0.0004. A dramatic increase of the OTR values occurred in humid conditions, such that the barrier performance was totally lost at 90% RH (the OTR of coated PET films was equal to the OTR of bare PET films. Modelling of the experimental OTR data by Cussler’s model suggested that the spatial ordering of GO sheets within the main pullulan phase was perturbed because of RH fluctuations. In spite of the presence of the filler, all the formulations allowed the obtainment of final materials with haze values below 3%, the only exception being the formulation with the highest loading of GO (ϕ ≈ 0.03. The mechanisms underlying the experimental observations are discussed.

  12. Surface strontium enrichment on highly active perovskites for oxygen electrocatalysis in solid oxide fuel cells

    KAUST Repository

    Crumlin, Ethan J.

    2012-01-01

    Perovskite oxides have high catalytic activities for oxygen electrocatalysis competitive to platinum at elevated temperatures. However, little is known about the oxide surface chemistry that influences the activity near ambient oxygen partial pressures, which hampers the design of highly active catalysts for many clean-energy technologies such as solid oxide fuel cells. Using in situ synchrotron-based, ambient pressure X-ray photoelectron spectroscopy to study the surface chemistry changes, we show that the coverage of surface secondary phases on a (001)-oriented La 0.8Sr 0.2CoO 3-δ (LSC) film becomes smaller than that on an LSC powder pellet at elevated temperatures. In addition, strontium (Sr) in the perovskite structure enriches towards the film surface in contrast to the pellet having no detectable changes with increasing temperature. We propose that the ability to reduce surface secondary phases and develop Sr-enriched perovskite surfaces of the LSC film contributes to its enhanced activity for O 2 electrocatalysis relative to LSC powder-based electrodes. © 2012 The Royal Society of Chemistry.

  13. High energy physics at UCR

    Energy Technology Data Exchange (ETDEWEB)

    Kernan, A.; Shen, B.C.

    1997-07-01

    The hadron collider group is studying proton-antiproton interactions at the world`s highest collision energy 2 TeV. Data-taking with the D0 detector is in progress at Fermilab and the authors have begun the search for the top quark. S. Wimpenny is coordinating the effort to detect t{bar t} decaying to two leptons, the most readily identifiable channel. At UC Riverside design and testing for a silicon tracker for the D0 upgrade is in progress; a parallel development for the SDC detector at SSC is also underway. The major group effort of the lepton group has been devoted to the OPAL experiment at LEP. They will continue to focus on data-taking to improve the quality and quantity of their data sample. A large number of papers have been published based on approximately 500,000 events taken so far. The authors will concentrate on physics analysis which provides stringent tests of the Standard Model. The authors are continuing participation in the RD5 experiment at the SPS to study muon triggering and tracking. The results of this experiment will provide critical input for the design of the Compact Muon Solenoid experiment being proposed for the LHC. The theory group has been working on problems concerning the possible vilation of e-{mu}-{tau} universality, effective Lagrangians, neutrino physics, as well as quark and lepton mass matrices.

  14. A Facile Synthesis of Nitrogen-Doped Highly Porous Carbon Nanoplatelets: Efficient Catalysts for Oxygen Electroreduction

    Science.gov (United States)

    Zhang, Yaqing; Zhang, Xianlei; Ma, Xiuxiu; Guo, Wenhui; Wang, Chunchi; Asefa, Tewodros; He, Xingquan

    2017-01-01

    The oxygen reduction reaction (ORR) is of great importance for various renewable energy conversion technologies such as fuel cells and metal-air batteries. Heteroatom-doped carbon nanomaterials have proven to be robust metal-free electrocatalysts for ORR in the above-mentioned energy devices. Herein, we demonstrate the synthesis of novel highly porous N-doped carbon nanoplatelets (N-HPCNPs) derived from oatmeal (or a biological material) and we show the materials’ high-efficiency as electrocatalyst for ORR. The obtained N-HPCNPs hybrid materials exhibit superior electrocatalytic activities towards ORR, besides excellent stability and good methanol tolerance in both basic and acidic electrolytes. The unique nanoarchitectures with rich micropores and mesopores, as well as the high surface area-to-volume ratios, present in the materials significantly increase the density of accessible catalytically active sites in them and facilitate the transport of electrons and electrolyte within the materials. Consequently, the N-HPCNPs catalysts hold a great potential to serve as low-cost and highly efficient cathode materials in direct methanol fuel cells (DMFCs). PMID:28240234

  15. A Facile Synthesis of Nitrogen-Doped Highly Porous Carbon Nanoplatelets: Efficient Catalysts for Oxygen Electroreduction

    Science.gov (United States)

    Zhang, Yaqing; Zhang, Xianlei; Ma, Xiuxiu; Guo, Wenhui; Wang, Chunchi; Asefa, Tewodros; He, Xingquan

    2017-02-01

    The oxygen reduction reaction (ORR) is of great importance for various renewable energy conversion technologies such as fuel cells and metal-air batteries. Heteroatom-doped carbon nanomaterials have proven to be robust metal-free electrocatalysts for ORR in the above-mentioned energy devices. Herein, we demonstrate the synthesis of novel highly porous N-doped carbon nanoplatelets (N-HPCNPs) derived from oatmeal (or a biological material) and we show the materials’ high-efficiency as electrocatalyst for ORR. The obtained N-HPCNPs hybrid materials exhibit superior electrocatalytic activities towards ORR, besides excellent stability and good methanol tolerance in both basic and acidic electrolytes. The unique nanoarchitectures with rich micropores and mesopores, as well as the high surface area-to-volume ratios, present in the materials significantly increase the density of accessible catalytically active sites in them and facilitate the transport of electrons and electrolyte within the materials. Consequently, the N-HPCNPs catalysts hold a great potential to serve as low-cost and highly efficient cathode materials in direct methanol fuel cells (DMFCs).

  16. High energy density lithium batteries

    CERN Document Server

    Aifantis, Katerina E; Kumar, R Vasant

    2010-01-01

    Cell phones, portable computers and other electronic devices crucially depend on reliable, compact yet powerful batteries. Therefore, intensive research is devoted to improving performance and reducing failure rates. Rechargeable lithium-ion batteries promise significant advancement and high application potential for hybrid vehicles, biomedical devices, and everyday appliances. This monograph provides special focus on the methods and approaches for enhancing the performance of next-generation batteries through the use of nanotechnology. Deeper understanding of the mechanisms and strategies is

  17. Highly Efficient Oxygen-Storage Material with Intrinsic Coke Resistance for Chemical Looping Combustion-Based CO2 Capture.

    Science.gov (United States)

    Imtiaz, Qasim; Kurlov, Alexey; Rupp, Jennifer Lilia Marguerite; Müller, Christoph Rüdiger

    2015-06-22

    Chemical looping combustion (CLC) and chemical looping with oxygen uncoupling (CLOU) are emerging thermochemical CO2 capture cycles that allow the capture of CO2 with a small energy penalty. Here, the development of suitable oxygen carrier materials is a key aspect to transfer these promising concepts to practical installations. CuO is an attractive material for CLC and CLOU because of its high oxygen-storage capacity (20 wt %), fast reaction kinetics, and high equilibrium partial pressure of oxygen at typical operating temperatures (850-1000 °C). However, despite its promising characteristics, its low Tammann temperature requires the development of new strategies to phase-stabilize CuO-based oxygen carriers. In this work, we report a strategy based on stabilization by co-precipitated ceria (CeO2-x ), which allowed us to increase the oxygen capacity, coke resistance, and redox stability of CuO-based oxygen carriers substantially. The performance of the new oxygen carriers was evaluated in detail and compared to the current state-of-the-art materials, that is, Al2 O3 -stabilized CuO with similar CuO loadings. We also demonstrate that the higher intrinsic oxygen uptake, release, and mobility in CeO2-x -stabilized CuO leads to a three times higher carbon deposition resistance compared to that of Al2 O3 -stabilized CuO. Moreover, we report a high cyclic stability without phase intermixing for CeO2-x -supported CuO. This was accompanied by a lower reduction temperature compared to state-of-the-art Al2 O3 -supported CuO. As a result of its high resistance towards carbon deposition and fast oxygen uncoupling kinetics, CeO2-x -stabilized CuO is identified as a very promising material for CLC- and CLOU-based CO2 capture architectures. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. High-Flow Nasal Cannula Oxygen in Adults: An Evidence-based Assessment.

    Science.gov (United States)

    Drake, Matthew G

    2018-02-01

    High-flow nasal cannula oxygenation has distinct advantages over other oxygen devices because of its unique effects on respiratory physiology. In particular, adjustable oxygen delivery and flow-dependent carbon dioxide clearance reduce work of breathing and better match inspiratory demand during respiratory distress. Historically, few studies had evaluated whether the physiologic effects of these devices translated into clinical benefit. However, recent publications have begun to address this knowledge gap. High-flow nasal cannula oxygenation has been shown to have similar, and in some cases superior clinical efficacy compared with conventional low-flow oxygen supplementation and noninvasive positive pressure ventilation in acute hypoxemic respiratory failure. High-flow nasal cannula oxygenation also prevents reintubations in medical and postoperative surgical populations, provides preoxygenation for laryngoscopy, and supports oxygenation during bronchoscopy. This review examines the evidence for high-flow nasal cannula oxygenation use in adults, including a focus on the unique effects of high flow on respiratory physiology and keys for tailoring flow for specific clinical scenarios.

  19. Observation of yielding and strain hardening in a titanium alloy having high oxygen content

    Energy Technology Data Exchange (ETDEWEB)

    Geng, F., E-mail: iamgengfang@gmail.com [Institute for Materials Research, Tohoku University, Sendai 850-8577 (Japan); Niinomi, M.; Nakai, M. [Institute for Materials Research, Tohoku University, Sendai 850-8577 (Japan)

    2011-06-25

    Highlights: {yields} TNTZ with high oxygen content indicates special mechanical properties. {yields} The phenomenon was explained by the interaction between oxygen atoms and dislocations. {yields} The deformation behavior changes with the addition of oxygen in TNTZ. {yields} There is a specific compositional area of oxygen in TNTZ exhibits good property. - Abstract: Plastic deformation behavior and its relation to tensile properties were investigated in an attractive {beta}-type titanium alloy (Ti-29Nb-13Ta-4.6Zr) with the oxygen content of 0.1-0.7 mass% subjected to hot rolling and solution treatment after hot rolling. Hereafter, Ti-29Nb-13Ta-4.6Zr is abbreviated to TNTZ. With the increase of oxygen content, the tensile strength and 0.2% proof stress of all the samples increase, however, their elongation indicates special change, which is contradictory to that reported conventionally. The elongation firstly decreases and then increases with the increase in the oxygen content. Therefore, TNTZ with high strength and high ductility due to the addition of high oxygen content (0.7 mass%) is obtained. Remarkable yielding phenomenon and strain hardening are observed in TNTZ, which can be explained by the interaction between oxygen atoms and a lot of screw and edge dislocations leading to the easy activation of the multiple slip systems. The deformation behavior changes with the addition of oxygen in TNTZ. The plastic deformation mode changes from the deformation-induced martensite transformation to slip mechanism. It is realized that there is a specific compositional area of oxygen in which the TNTZ exhibits strain hardening and high strength, and appropriate Young's modulus value.

  20. Encapsulated iron-based oxygen reduction electrocatalysts by high pressure pyrolysis

    DEFF Research Database (Denmark)

    Zhong, Lijie; Hu, Yang; Cleemann, Lars Nilausen

    2017-01-01

    the nitrogen containing precursors and can be improved by post treatment in ammonia. These results indicate the contribution to the catalysis from surface nitrogen functionalities and encapsulated metal-containing nanoparticles. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights......Non-precious metal catalysts (NPMCs) are candidate materials to replace platinum for proton exchange membrane fuel cells (PEMFCs). Herein we reported a type of iron-based NPMCs prepared by high pressure pyrolysis for the oxygen reduction reaction (ORR) in acidic media. The catalysts are in form...... of carbon microspheres in a sub-microscale consisting of iron-containing nanoparticles encapsulated by graphitic layers. By tailoring temperatures and duration of pyrolysis, the best ORR catalyst was achieved at 700 degrees C and 75 min, which exhibits an onset potential of 0.85 V at 0.1 mA cm(-2...

  1. A high-performance mesoporous carbon supported nitrogen-doped carbon electrocatalyst for oxygen reduction reaction

    Science.gov (United States)

    Xu, Jingjing; Lu, Shiyao; Chen, Xu; Wang, Jianan; Zhang, Bo; Zhang, Xinyu; Xiao, Chunhui; Ding, Shujiang

    2017-12-01

    Investigating low-cost and highly active electrocatalysts for oxygen reduction reactions (ORR) is of crucial importance for energy conversion and storage devices. Herein, we design and prepare mesoporous carbon supported nitrogen-doped carbon by pyrolysis of polyaniline coated on CMK-3. This electrocatalyst exhibits excellent performance towards ORR in alkaline media. The optimized nitrogen-doped mesoporous electrocatalyst show an onset potential (E onset) of 0.95 V (versus reversible hydrogen electrode (RHE)) and half-wave potential (E 1/2) of 0.83 V (versus RHE) in 0.1 M KOH. Furthermore, the as-prepared catalyst presents superior durability and methanol tolerance compared to commercial Pt/C indicating its potential applications in fuel cells and metal–air batteries.

  2. Pt Monolayer Shell on Nitrided Alloy Core—A Path to Highly Stable Oxygen Reduction Catalyst

    Directory of Open Access Journals (Sweden)

    Jue Hu

    2015-07-01

    Full Text Available The inadequate activity and stability of Pt as a cathode catalyst under the severe operation conditions are the critical problems facing the application of the proton exchange membrane fuel cell (PEMFC. Here we report on a novel route to synthesize highly active and stable oxygen reduction catalysts by depositing Pt monolayer on a nitrided alloy core. The prepared PtMLPdNiN/C catalyst retains 89% of the initial electrochemical surface area after 50,000 cycles between potentials 0.6 and 1.0 V. By correlating electron energy-loss spectroscopy and X-ray absorption spectroscopy analyses with electrochemical measurements, we found that the significant improvement of stability of the PtMLPdNiN/C catalyst is caused by nitrogen doping while reducing the total precious metal loading.

  3. Long term high flow heated oxygen treatment in COPD – lung function and physical ability

    DEFF Research Database (Denmark)

    Weinreich, Ulla; Storgaard, Line; Hockey, Hans

    2017-01-01

    Introduction: Long term oxygen therapy (LTOT) improves survival in patients with COPD with resting hypoxemia. Despite this, a progressive loss of lung function and physical ability is expected in COPD. The AIRVO device delivers nasal high flow (NHF) warmed and humidified oxygen-enriched air, 20...

  4. Long-term nasal high flow treatment with oxygen in COPD - exacerbations, admissions and mortality

    DEFF Research Database (Denmark)

    Weinreich, Ulla; Storgaard, Line; Hockey, Hans

    2017-01-01

    Introduction: Long term oxygen therapy (LTOT) improves survival in patients with COPD with resting hypoxemia. Exacerbations (AECOPD) and hospital admissions are prevalent and have a negative impact on prognosis. The AIRVO device delivers nasal high flow (NHF) heated, humidified oxygenated air, 20...

  5. High-accuracy oxygen polarograph for photosynthetic systems

    Science.gov (United States)

    Meunier, P. C.; Popovic, R.

    1988-03-01

    A new system is presented here, whose design is based on the electrochemical phenomena occurring on the platinum electrode that we examined before [P. Meunier and R. Popovic (unpublished)]. The architecture of the system is articulated around an IBM-PC computer which controls the polarization of the electrodes, the triggering of the flash lamp, and the acquisition of data. The potentiostat circuit and new electrode design improve the response of the electrode to a rise time of 4 ms and a decay time constant of 21 ms, without the signal being distorted by filters and without using the first derivative of the signal. This polarograph shows a 50-dB signal-to-noise ratio (0.3% error) during experiments with the motile algae Dunaliella tertiolecta. The determination of amplitudes of oxygen production is performed with third-order cubic spline interpolations, after subtraction of the current base line. The resulting accuracy and reproducibility will enable researchers to attain a higher degree of refinement in the quantification of properties of the oxygen evolving complex.

  6. Study on Oxygen Supply Standard for Physical Health of Construction Personnel of High-Altitude Tunnels

    Directory of Open Access Journals (Sweden)

    Chun Guo

    2015-12-01

    Full Text Available The low atmospheric pressure and low oxygen content in high-altitude environment have great impacts on the functions of human body. Especially for the personnel engaged in complicated physical labor such as tunnel construction, high altitude can cause a series of adverse physiological reactions, which may result in multiple high-altitude diseases and even death in severe cases. Artificial oxygen supply is required to ensure health and safety of construction personnel in hypoxic environments. However, there are no provisions for oxygen supply standard for tunnel construction personnel in high-altitude areas in current tunnel construction specifications. As a result, this paper has theoretically studied the impacts of high-altitude environment on human bodies, analyzed the relationship between labor intensity and oxygen consumption in high-altitude areas and determined the critical oxygen-supply altitude values for tunnel construction based on two different standard evaluation systems, i.e., variation of air density and equivalent PIO2. In addition, it has finally determined the oxygen supply standard for construction personnel in high-altitude areas based on the relationship between construction labor intensity and oxygen consumption.

  7. Energy resolved actinometry for simultaneous measurement of atomic oxygen densities and local mean electron energies in radio-frequency driven plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Greb, Arthur, E-mail: ag941@york.ac.uk; Niemi, Kari; O' Connell, Deborah; Gans, Timo [York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom)

    2014-12-08

    A diagnostic method for the simultaneous determination of atomic oxygen densities and mean electron energies is demonstrated for an atmospheric pressure radio-frequency plasma jet. The proposed method is based on phase resolved optical emission measurements of the direct and dissociative electron-impact excitation dynamics of three distinct emission lines, namely, Ar 750.4 nm, O 777.4 nm, and O 844.6 nm. The energy dependence of these lines serves as basis for analysis by taking into account two line ratios. In this frame, the method is highly adaptable with regard to pressure and gas composition. Results are benchmarked against independent numerical simulations and two-photon absorption laser-induced fluorescence experiments.

  8. Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres.

    Science.gov (United States)

    Franz, Robert; Polcik, Peter; Anders, André

    2015-06-25

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr2+ ions were dominating in Ar and N2 and Cr+ in O2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.

  9. High Energy Physics Research at Louisiana Tech

    Energy Technology Data Exchange (ETDEWEB)

    Sawyer, Lee [Louisiana State Univ., Baton Rouge, LA (United States); Greenwood, Zeno [Louisiana State Univ., Baton Rouge, LA (United States); Wobisch, Marcus [Louisiana State Univ., Baton Rouge, LA (United States)

    2013-06-28

    The goal of this project was to create, maintain, and strengthen a world-class, nationally and internationally recognized experimental high energy physics group at Louisiana Tech University, focusing on research at the energy frontier of collider-based particle physics, first on the DØ experiment and then with the ATLAS experiment, and providing leadership within the US high energy physics community in the areas of jet physics, top quark and charged Higgs decays involving tau leptons, as well as developing leadership in high performance computing.

  10. New accelerators in high-energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Blewett, J.P.

    1982-01-01

    First, I should like to mention a few new ideas that have appeared during the last few years in the accelerator field. A couple are of importance in the design of injectors, usually linear accelerators, for high-energy machines. Then I shall review some of the somewhat sensational accelerator projects, now in operation, under construction or just being proposed. Finally, I propose to mention a few applications of high-energy accelerators in fields other than high-energy physics. I realize that this is a digression from my title but I hope that you will find it interesting.

  11. CERN and the high energy frontier

    Directory of Open Access Journals (Sweden)

    Tsesmelis Emmanuel

    2014-04-01

    Full Text Available This paper presents the particle physics programme at CERN at the high-energy frontier. Starting from the key open questions in particle physics and the large-scale science facilities existing at CERN, concentrating on the Large Hadron Collider(LHC, this paper goes on to present future possibilities for global projects in high energy physics. The paper presents options for future colliders, all being within the framework of the recently updated European Strategy for Particle Physics, and all of which have a unique value to add to experimental particle physics. The paper concludes by outlining key messages for the way forward for high-energy physics research.

  12. How cytochrome c oxidase can pump four protons per oxygen molecule at high electrochemical gradient.

    Science.gov (United States)

    Blomberg, Margareta R A; Siegbahn, Per E M

    2015-03-01

    Experiments have shown that the A-family cytochrome c oxidases pump four protons per oxygen molecule, also at a high electrochemical gradient. This has been considered a puzzle, since two of the reduction potentials involved, Cu(II) and Fe(III), were estimated from experiments to be too low to afford proton pumping at a high gradient. The present quantum mechanical study (using hybrid density functional theory) suggests a solution to this puzzle. First, the calculations show that the charge compensated Cu(II) potential for CuB is actually much higher than estimated from experiment, of the same order as the reduction potentials for the tyrosyl radical and the ferryl group, which are also involved in the catalytic cycle. The reason for the discrepancy between theory and experiment is the very large uncertainty in the experimental observations used to estimate the equilibrium potentials, mainly caused by the lack of methods for direct determination of reduced CuB. Second, the calculations show that a high energy metastable state, labeled EH, is involved during catalytic turnover. The EH state mixes the low reduction potential of Fe(III) in heme a3 with another, higher potential, here suggested to be that of the tyrosyl radical, resulting in enough exergonicity to allow proton pumping at a high gradient. In contrast, the corresponding metastable oxidized state, OH, is not significantly higher in energy than the resting state, O. Finally, to secure the involvement of the high energy EH state it is suggested that only one proton is taken up via the K-channel during catalytic turnover. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Redox-Active Metal-Organic Composites for Highly Selective Oxygen Separation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Wen [Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA; Banerjee, Debasis [Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA; Liu, Jian [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Schaef, Herbert T. [Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA; Crum, Jarrod V. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Fernandez, Carlos A. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Kukkadapu, Ravi K. [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA; Nie, Zimin [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Nune, Satish K. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Motkuri, Radha K. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Chapman, Karena W. [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL 60439 USA; Engelhard, Mark H. [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA; Hayes, James C. [National Security Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA; Silvers, Kurt L. [National Security Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA; Krishna, Rajamani [Van' t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904 1098 XH Amsterdam The Netherlands; McGrail, B. Peter [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Liu, Jun [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA; Thallapally, Praveen K. [Physical & Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99352 USA

    2016-03-08

    Incorporating, a redox active organometallic molIncorporating, a redox active organometallic molecule within a porous matrix is a useful strategy to form redox active composite materials for emerging applications such as energy storage, electro-catalysis and electro-magnetic separation. Herein we report a new class of stable, redox active metal organic composites for oxygen/air separation with exceptional efficiency. In particular, Ferrocene impregnated in a thermally stable hierarchical porous framework showed a saturation uptake capacity of >51 mg/g for oxygen at a very low relative saturation pressure (P/Po) of 0.06. The material shows excellent O2 selectivity from air as evident from experimental and simulated breakthrough experiments. In detail structural analysis using 57Fe-Mössbauer, X-ray photoelectron spectroscopy (XPS) and pair distribution function (PDF) analysis show that of O2 adsorption affinity and selectivity originates by the formation Fe3+-O oxide due to the highly reactive nature of the organometallics imbedded in the porous matrix.

  14. Use of a High-Flow Oxygen Delivery System in a Critically Ill Patient with Dementia

    Science.gov (United States)

    2008-12-01

    facial mask. We saw a 92-year-old woman with delirium and dementia in the intensive care unit for multi-lobar pneumonia with severe hypoxemia. Attempts to...a high oxygen concentration. Key words: high-flow oxygen, palliative care , hypoxemia. [Respir Care 2008;53(12):1739–1743] Introduction We have...Fig. 2. Radiograph on hospital day 4. HIGH-FLOW OXYGEN IN A CRITICALLY ILL PATIENT WITH DEMENTIA 1740 RESPIRATORY CARE • DECEMBER 2008 VOL 53 NO 12

  15. A strategy for oxygen conditioning at high altitude: comparison with air conditioning.

    Science.gov (United States)

    West, John B

    2015-09-15

    Large numbers of people live or work at high altitude, and many visit to trek or ski. The inevitable hypoxia impairs physical working capacity, and at higher altitudes there is also cognitive impairment. Twenty years ago oxygen enrichment of room air was introduced to reduce the hypoxia, and this is now used in dormitories, hotels, mines, and telescopes. However, recent advances in technology now allow large amounts of oxygen to be obtained from air or cryogenic oxygen sources. As a result it is now feasible to oxygenate large buildings and even institutions such as hospitals. An analogy can be drawn between air conditioning that has improved the living and working conditions of millions of people who live in hot climates and oxygen conditioning that can do the same at high altitude. Oxygen conditioning is similar to air conditioning except that instead of cooling the air, the oxygen concentration is raised, thus reducing the equivalent altitude. Oxygen conditioning on a large scale could transform living and working conditions at high altitude, where it could be valuable in homes, hospitals, schools, dormitories, company headquarters, banks, and legislative settings. Copyright © 2015 the American Physiological Society.

  16. Studies In Theoretical High Energy Particle Physics

    Energy Technology Data Exchange (ETDEWEB)

    Keung, Wai Yee [Univ. of Illinois, Chicago, IL (United States)

    2017-07-01

    This is a final technical report for grant no. DE-SC0007948 describing research activities in theoretical high energy physics at University of Illinois at Chicago for the whole grant period from July 1, 2012 to March 31, 2017.

  17. Research in High Energy Physics. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Conway, John S.

    2013-08-09

    This final report details the work done from January 2010 until April 2013 in the area of experimental and theoretical high energy particle physics and cosmology at the University of California, Davis.

  18. The evolution of high energy accelerators

    Energy Technology Data Exchange (ETDEWEB)

    Courant, E.D.

    1989-10-01

    In this lecture I would like to trace how high energy particle accelerators have grown from tools used for esoteric small-scale experiments to gigantic projects being hotly debated in Congress as well as in the scientific community.

  19. 1570 nm High Energy Fiber Laser Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR phase I project proposes a single frequency high energy fiber laser for remote sensing. Current state-of-art technologies can not provide all features of...

  20. High Energy Single Frequency Resonant Amplifier Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR phase I project proposes a single frequency high energy resonant amplifier for remote sensing. Current state-of-art technologies can not provide all...

  1. Experiment to measure oxygen opacity at high density and temperature

    Science.gov (United States)

    Keiter, Paul; Mussack, Katie; Orban, Chris; Colgan, James; Ducret, Jean-Eric; Fontes, Christopher J.; Guzik, Joyce Ann; Heeter, Robert F.; Kilcrease, Dave; Le Pennec, Maelle; Mancini, Roberto; Perry, Ted; Turck-Chièze, Sylvaine; Trantham, Matt

    2017-06-01

    In recent years, there has been a debate over the abundances of heavy elements (Z >2) in the solar interior. Recent solar atmosphere models [Asplund 2009] find a significantly lower abundance for C, N, and O compared to models used roughly a decade ago. This discrepancy has led to an investigation of opacities through laboratory experiments and improved opacity models for many of the larger contributors to the sun’s opacity, including iron and oxygen. Recent opacity measurements of iron disagree with opacity model predictions [Bailey et al, 2015]. Although these results are still controversial, repeated scrutiny of the experiment and data has not produced a conclusive reason for the discrepancy. New models have been implemented in the ATOMIC opacity code for C, O and Fe to address the solar abundance issue [Colgan, 2013]. Armstrong et al [2014] have also implemented changes in the ATOMIC code for low-Z elements. However, no data currently exists to test the low-Z material models in the regime relevant to the solar convection zone. We present an experimental design using the opacity platform developed at the National Ignition Facility to study the oxygen opacity at densities and temperatures near the solar convection zone conditions.This work is funded by the U.S. DOE, through the NNSA-DS and SC-OFES Joint Program in HEDPLP, grant No. DE-NA0001840, and the NLUF Program, grant No. DE-NA0000850, and through LLE, University of Rochester by the NNSA/OICF under Agreement No. DE-FC52-08NA28302.

  2. Role of Reactive Oxygen Species in Hypothalamic Regulation of Energy Metabolism

    Directory of Open Access Journals (Sweden)

    Sabrina Diano

    2013-03-01

    Full Text Available To understand the etiology of metabolic disorders, including obesity and type II diabetes, it is essential to gain better insight into how stored and available energy sources are monitored by the central nervous system. In particular, a comprehension of the fine cellular interplay and intracellular mechanisms that enable appropriate hypothalamic and consequent endocrine and behavioral responses to both circulating hormonal and nutrient signals remains elusive. Recent data, including those from our laboratories, raised the notion that reactive oxygen species (ROS generation is not merely a by-product of substrate oxidation, but it plays a crucial role in modulating cellular responses involved in the regulation of energy metabolism. These review summarizes the published recent data on the effect of ROS levels in the regulation of neuronal function, including that of hypothalamic melanocortin neurons, pro-opiomelanocortin and neuropeptide Y-/agouti related peptide-neurons, in the modulation of food intake.

  3. High-energy cosmic-ray acceleration

    CERN Document Server

    Bustamante, M; de Paula, W; Duarte Chavez, J A; Gago, A M; Hakobyan, H; Jez, P; Monroy Montañez, J A; Ortiz Velasquez, A; Padilla Cabal, F; Pino Rozas, M; Rodriguez Patarroyo, D J; Romeo, G L; Saldaña-Salazar , U J; Velasquez, M; von Steinkirch, M

    2010-01-01

    We briefly review the basics of ultrahigh-energy cosmic-ray acceleration. The Hillas criterion is introduced as a geometrical criterion that must be fulfilled by potential acceleration sites, and energy losses are taken into account in order to obtain a more realistic scenario. The different available acceleration mechanisms are presented, with special emphasis on Fermi shock acceleration and its prediction of a power-law cosmic-ray energy spectrum. We conclude that first-order Fermi acceleration, though not entirely satisfactory, is the most promising mechanism for explaining the ultra-high-energy cosmic-ray flux.

  4. European School of High-Energy Physics

    CERN Document Server

    2007-01-01

    The European School of High-Energy Physics is intended to give young experimental and phenomenological physicists an introduction to the theoretical aspects of recent advances in elementary particle physics. These proceedings contain lecture notes on the Standard Model of electroweak interactions, Monte Carlo generators, relativistic heavy-ion physics, the flavour dynamics and CP violation in the Standard Model, cosmology, and high-energy neutrino astronomy with IceCube.

  5. Future of high energy physics some aspects

    CERN Document Server

    Prokofiev, Kirill

    2017-01-01

    This book comprises 26 carefully edited articles with well-referenced and up-to-date material written by many of the leading experts. These articles originated from presentations and dialogues at the second HKUST Institute for Advanced Study Program on High Energy Physics are organized into three aspects, Theory, Accelerator, and Experiment, focusing on in-depth analyses and technical aspects that are essential for the developments and expectations for the future high energy physics.

  6. New developments in high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Neal, H.A.

    1977-01-01

    Some of the important developments in the field of high energy physics are reviewed. Starting from the status of knowledge of the structure of matter the details of experiments leading to the discovery of charmed particles and psi resonances are emphasized. Also some of the areas of activity of the Indiana University High Energy group are reviewed and related to the principal unsolved problems in the field. (JFP)

  7. Heavy Quark Production at High Energy

    CERN Document Server

    Ball, R D

    2001-01-01

    We report on QCD radiative corrections to heavy quark production valid at high energy. The formulae presented will allow a matched calculation of the total cross section which is correct at $O(\\as^3)$ and includes resummation of all terms of order $\\as^3 [\\as \\ln (s/m^2)]^n$. We also include asymptotic estimates of the effect of the high energy resummation. A complete description of the calculation of the heavy quark impact factor is included in an appendix.

  8. Elementary particle physics and high energy phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Barker, A.R.; Cumalat, J.P.; de Alwis, S.P.; DeGrand, T.A.; Ford, W.T.; Mahanthappa, K.T.; Nauenberg, U.; Rankin, P.; Smith, J.G.

    1992-06-01

    This report discusses the following research in high energy physics: the properties of the z neutral boson with the SLD detector; the research and development program for the SDC muon detector; the fixed-target k-decay experiments; the Rocky Mountain Consortium for HEP; high energy photoproduction of states containing heavy quarks; and electron-positron physics with the CLEO II and Mark II detectors. (LSP).

  9. Institute for High Energy Density Science

    Energy Technology Data Exchange (ETDEWEB)

    Wootton, Alan [Univ. of Texas, Austin, TX (United States)

    2017-01-13

    The project objective was for the Institute of High Energy Density Science (IHEDS) at the University of Texas at Austin to help grow the High Energy Density (HED) science community, by connecting academia with the Z Facility (Z) and associated staff at Sandia National Laboratories (SNL). IHEDS was originally motivated by common interests and complementary capabilities at SNL and the University of Texas System (UTX), in 2008.

  10. Segregation under low-energy oxygen bombardment in the near-surface region

    Science.gov (United States)

    Tada, Y.; Suzuki, K.; Kataoka, Y.

    2008-12-01

    We found that a transient region of SIMS profiles was suppressed to less than the native oxide in silicon, with O 2+ bombardment energy of less than 0.2 keV under an incident angle of 0° with respect to the surface normal without oxygen flooding. However, gallium segregated significantly due to oxidation caused by O 2+ bombardment in this condition. We also found that the segregation decreased as the incident angle increased, and that it disappeared at the angle of around 40°, which was verified by comparing SIMS profiles with the HR-RBS profile. These results suggested that the angle of around 40° was the critical angle to prevent segregation. The transient region was almost the same at angles of 0-40°. Therefore, we consider that the energy of 0.2 keV at the angle of around 40° under O 2+ bombardment without oxygen flooding is the optimum SIMS condition for depth profiling in the near-surface region. On the other hand, the profile shift of arsenic depending on the angle was quite different as compared with gallium, but the shift was a minimum at the same critical angle. We expect that more accurate profiles for other impurities can be obtained using this SIMS condition.

  11. Fundamentals of high energy electron beam generation

    Science.gov (United States)

    Turman, B. N.; Mazarakis, M. G.; Neau, E. L.

    High energy electron beam accelerator technology has been developed over the past three decades in response to military and energy-related requirements for weapons simulators, directed-energy weapons, and inertially-confined fusion. These applications required high instantaneous power, large beam energy, high accelerated particle energy, and high current. These accelerators are generally referred to as 'pulsed power' devices, and are typified by accelerating potential of millions of volts (MV), beam current in thousands of amperes (KA), pulse duration of tens to hundreds of nanoseconds, kilojoules of beam energy, and instantaneous power of gigawatts to teffawatts (10(exp 9) to 10(exp 12) watts). Much of the early development work was directed toward single pulse machines, but recent work has extended these pulsed power devices to continuously repetitive applications. These relativistic beams penetrate deeply into materials, with stopping range on the order of a centimeter. Such high instantaneous power deposited in depth offers possibilities for new material fabrication and processing capabilities that can only now be explored. Fundamental techniques of pulse compression, high voltage requirements, beam generation and transport under space-charge-dominated conditions will be discussed in this paper.

  12. Identifying the nature of high energy Astroparticles

    CERN Document Server

    Mora, Karen Salomé Caballero

    2016-01-01

    High energy Astroparticles include Cosmic Ray, gamma ray and neutrinos, all of them coming from the universe. The origin and production, acceleration and propagation mechanisms of ultrahigh-energy CR (up to $10^{20}$ eV) are still unknown. Knowledge on particle interactions taking place at those energies, useful for studying current theories on particle physics, can be obtained only from measurements of high energy astroparticles. In the present document some techniques on data analysis of mass composition of UHECR with the Pierre Auger Observatory are described. The relevance of the muon component of air showers produced by the primary CR, as well as some low energy simulations of that component, are explained.

  13. Identifying the nature of high energy Astroparticles

    Science.gov (United States)

    Salomé Caballero Mora, Karen

    2016-10-01

    High energy Astroparticles include Cosmic Ray (CR), gamma ray and neutrinos, all of them coming from the universe. The origin and production, acceleration and propagation mechanisms of ultrahigh-energy CR (UHECR ∼ 1020 eV) are still unknown. Knowledge on particle interactions taking place at those energies, useful for studying current theories on particle physics, can be obtained only from measurements of high energy astroparticles. In the present document some techniques on data analysis of mass composition of UHECR with the Pierre Auger Observatory are described. The relevance of the muon component of air showers produced by the primary CR, as well as some low energy simulations of that component, are explained.

  14. Ultra-High-Energy Cosmic Rays

    CERN Document Server

    Dova, M.T.

    2015-05-22

    The origin of the ultra high energy cosmic rays (UHECR) with energies above E > 10 17 eV, is still unknown. The discovery of their sources will reveal the engines of the most energetic astrophysical accelerators in the universe. This is a written version of a series of lectures devoted to UHECR at the 2013 CERN-Latin-American School of High-Energy Physics. We present anintroduction to acceleration mechanisms of charged particles to the highest energies in astrophysical objects, their propagation from the sources to Earth, and the experimental techniques for their detection. We also discuss some of the relevant observational results from Telescope Array and Pierre Auger Observatory. These experiments deal with particle interactions at energies orders of magnitude higher than achieved in terrestrial accelerators.

  15. Progress toward high energy electron cooling

    Energy Technology Data Exchange (ETDEWEB)

    Sergei Nagaitsev

    2001-07-20

    All electron cooling systems in operation to date can be classified as low energy systems. The electron beam kinetic energy in such a system is limited to about 0.6-1 MeV by the use of a conventional commercial Cockcroft-Walton high-voltage power supply. This, in turn, bounds the maximum ion kinetic energy, accessible for cooling with today's standard technology, to about 2 GeV/nucleon (about a factor of 2-3 times higher than the electron systems in operation today). Electron cooling systems with kinetic energies above 1 MeV could provide economically justifiable improvements in the performance of many existing and proposed accelerator complexes, such as RHIC, Tevatron and HERA. This paper reviews the status of the development of the technology needed for high energy electron cooling.

  16. [High intensity aerobic interval training improves peak oxygen consumption in patients with metabolic syndrome: CAT].

    Science.gov (United States)

    Espinoza Salinas, Alexis; Aguilera Eguía, Raúl; Cofre Bolados, Cristian; Zafra Santos, Edson; Pavéz Von Martens, Gustavo

    2014-06-06

    A number of cardiovascular risk factors characterizes the metabolic syndrome: insulin resistance (IR), low HDL cholesterol and high triglycerides. The aforementioned risk factors lead to elevated levels of abdominal adipose tissue, resulting in oxygen consumption deficiency. To verify the validity and applicability of using high intensity interval training (HIIT) in subjects with metabolic syndrome and to answer the following question: Can HIIT improve peak oxygen consumption? The systematic review "Effects of aerobic interval training on exercise capacity and metabolic risk factors in individuals with cardiometabolic disorders" was analyzed. Data suggests high intensity aerobic interval training increases peak oxygen consumption by a standardized mean difference of 3.60 mL/kg-1/min-1 (95% confidence interval, 0.28-4.91). In spite of the methodological shortcomings of the primary studies included in the systematic review, we reasonably conclude that implementation of high intensity aerobic interval training in subjects with metabolic syndrome, leads to increases in peak oxygen consumption.

  17. Clinical research on high oxygen permeable contact lens used after photorefractive keratectomy surgery

    Directory of Open Access Journals (Sweden)

    Hao-Jiang Yang

    2013-07-01

    Full Text Available AIM: To evaluate the outcome of high oxygen permeable contact lens used after photorefractive keratectomy(PRKsurgery.METHODS: Totally 95 patients(190 eyesafter PRK were included. Patients were randomly assigned to wear high oxygen permeable contact lens in one eye and normal lens in the fellow eye after surgery. The subjective symptoms and corneal epithelial status after PRK were evaluated. Uncorrected visual acuity(UCVAand haze were assessed at 6 months after PRK.RESULTS: Complaints of blurred vision, pain and photophobia were statistically more among the normal lens group than high oxygen permeable contact lens group(PPP=0.35. There was no difference in UCVA and haze 6 months after surgery(P=0.55. CONCLUSION: High oxygen permeable contact lens can significantly produce less the corneal irritated symptoms, reduce the discomfort feeling and promote healing of corneal epithelium after PRK.

  18. Experiment to measure oxygen opacity at high density and temperature

    Science.gov (United States)

    Keiter, Paul; Butler, Hannah; Trantham, Matt; Mussack, Katie; Colgan, James; Fontes, Chris; Guzik, Joyce; Kilcrease, David; Perry, Ted; Orban, Chris; Ducret, Jean-Eric; La Pennec, Maelle; Turck-Chieze, Sylvaine; Mancini, Roberto; Heeter, Robert

    2017-10-01

    In recent years, there has been a debate over the abundances of heavy elements (Z >2) in the solar interior. Recent solar atmosphere models [Asplund 2009] find a significantly lower abundance for C, N, and O compared to models used roughly a decade ago. Recent opacity measurements of iron disagree with opacity model predictions [Bailey et al., 2015]. Repeated scrutiny of the experiment and data has not produced a conclusive reason for the discrepancy. New models have been implemented in the ATOMIC opacity code for low-Z elements [Colgan, 2013, Armstrong 2014], however no data currently exists to test the low-Z material models in the regime relevant to the solar convection zone. We present an experimental design using the opacity platform developed at the National Ignition Facility to study the oxygen opacity at densities and temperatures near the solar convection zone conditions. This work is funded by the U.S. DOE, through the NNSA-DS and SC-OFES Joint Program in HEDLP, Grant Number DE-NA0002956, and the NLUF Program, Grant Number DE-NA0002719, and through the LLE, University of Rochester by the NNSA/OICF under No. DE-NA0001944.

  19. Oxygen uptake and energy expenditure for children during rock climbing activity.

    Science.gov (United States)

    Watts, Phillip Baxter; Ostrowski, Megan L

    2014-02-01

    The purpose of this study was to measure oxygen uptake and energy expenditure in children during rock climbing activity. 29 children (age = 10.9 ± 1.7 yr) participated in the study. A commercially available rock climbing structure with ample features for submaximal effort climbing provided continuous terrain. Participants were instructed to climb at a comfortable pace. Following an initial 5-min rest, each child climbed one sustained 5-min bout followed by 5-min sitting recovery for a total of 10 min (SUS). This was immediately followed by five 1-min climbing + 1-min recovery intervals for a second total of 10 min (INT). Expired air was analyzed continuously. Energy expenditure (EE) was determined via the Weir method for 10-s intervals throughout the full protocol. The total energy expenditure in kilocalories during the 10-min SUS period was 34.3 ± 11.3 kcal. Energy expenditure during the 10-min INT period averaged 39.3 ± 13.1 kcal and was significantly higher than during SUS (p rock climbing tasks employed in this study produced EE levels similar to what have been reported in children for stair climbing, sports/games activities, and easy jogging.

  20. A Comparison Study of the Oxygen-Rich Side Blow Furnace and the Oxygen-Rich Bottom Blow Furnace for Liquid High Lead Slag Reduction

    Science.gov (United States)

    Chen, Lin; Hao, Zhandong; Yang, Tianzu; Liu, Weifeng; Zhang, Duchao; Zhang, Li; Bin, Shu; Bin, Wanda

    2015-05-01

    This work investigates the characteristics of the oxygen-rich side blow furnace (OSBF) and the oxygen-rich bottom blow furnace (OBBF) as the reductive smelting reactor for molten high lead slag. The slags were collected from different sampling points of these furnaces during a regular high lead slag reduction process and analyzed. It is disclosed that lead content of the melt in the OSBF shows dramatic fluctuations, while melt from different sampling points of the furnace behave similarly, exhibiting the characteristics of batch reactor. An obvious axial lead content gradient is detected in the OBBF, showing the characteristics of a plug flow reactor. The industrial performances of these furnaces are also compared. The results indicate that 1.38% higher lead recovery can be achieved by using the OSBF instead of the OBBF. Unit energy consumptions of the OBBF-OSBF and OBBF-OBBF processes can be reduced to 230 kgce/ t crude lead, which is 70 kgce/ t crude lead less than that of the tradition Shuikoushan (SKS) process.

  1. The ejector flowmeter as air/oxygen mixing device. An apparatus providing gas mixtures with adjustable oxygen content for high-flow humidification systems.

    Science.gov (United States)

    Christensen, K N; Waaben, J; Jørgensen, S

    1980-04-01

    The ejector flowmeter is constructed for continuous removal of excess gas from anaesthetic circuits. This instrument can be used as an air/oxygen mixing device for high-flow humidification systems in wards where compressed air is not available. Pure oxygen is used as driving gas through the ejector. A nomogram has been constructed to show the relationship between oxygen driving pressure, inlet of air to the flowmeter, FIO2 and total outflow.

  2. STACKING FAULT ENERGY IN HIGH MANGANESE ALLOYS

    Directory of Open Access Journals (Sweden)

    Eva Mazancová

    2009-04-01

    Full Text Available Stacking fault energy of high manganese alloys (marked as TWIP and TRIPLEX is an important parameter determining deformation mechanism type realized in above mentioned alloys. Stacking fault energy level can be asserted with a gliding of partial and/or full dislocations, b gliding mechanism and twinning deformation process in connection with increasing of fracture deformation level (deformation elongation and with increasing of simultaneously realized work hardening proces., c gliding mechanism and deformation induced e-martensite formation. In contribution calculated stacking fault energies are presented for various chemical compositions of high manganese alloys. Stacking fault energy dependences on manganese, carbon, iron and alluminium contents are presented. Results are confronted with some accessible papers.The aim of work is to deepen knowledge of presented data. The TWIP and TRIPLEX alloys can be held for promissing new automotive materials.

  3. Opportunities for high wind energy penetration

    DEFF Research Database (Denmark)

    Tande, J.O.; Hansen, J.C.

    1997-01-01

    Wind power is today a mature technology, which at windy locations, is economically competitive to conventional power generation technologies. This and growing global environmental concerns have led governments to encourage and plan for wind energy development, a typical aim being 10% of electricity...... consumption. The successful operation of the three major power systems of Cape Verde, with a total wind energy penetration of about 15% since December 1994, demonstrates that power systems can be operated with high penetration of wind energy by adding simple control and monitoring systems only. Thorough...... analyses conclude that expanding to even above 15% wind energy penetration in the Cape Verde power systems is economical. Worldwide, numerous locations with favorable wind conditions and power systems similar to the Capeverdean provide good opportunities for installing wind farms and achieving high wind...

  4. Rhizosphere anode model explains high oxygen levels during operation of a Glyceria maxima PMFC

    NARCIS (Netherlands)

    Timmers, R.A.; Strik, D.P.B.T.B.; Arampatzoglou, C.; Buisman, C.J.N.; Hamelers, H.V.M.

    2012-01-01

    In this paper, the effect of root oxygen loss on energy recovery of the plant microbial fuel cell (PMFC) is described. In this manner, advanced understanding of competing processes within the rhizosphere-anode interface was provided. A microscopic model was developed on the basis of exudation,

  5. Utilization of Wind Energy at High Altitude

    OpenAIRE

    Bolonkin, Alexander

    2007-01-01

    Ground based, wind energy extraction systems have reached their maximum capability. The limitations of current designs are: wind instability, high cost of installations, and small power output of a single unit. The wind energy industry needs of revolutionary ideas to increase the capabilities of wind installations. This article suggests a revolutionary innovation which produces a dramatic increase in power per unit and is independent of prevailing weather and at a lower cost per unit of energ...

  6. Unraveling the structure and chemical mechanisms of highly oxygenated intermediates in oxidation of organic compounds

    KAUST Repository

    Wang, Zhandong

    2017-11-28

    Decades of research on the autooxidation of organic compounds have provided fundamental and practical insights into these processes; however, the structure of many key autooxidation intermediates and the reactions leading to their formation still remain unclear. This work provides additional experimental evidence that highly oxygenated intermediates with one or more hydroperoxy groups are prevalent in the autooxidation of various oxygenated (e.g., alcohol, aldehyde, keto compounds, ether, and ester) and nonoxygenated (e.g., normal alkane, branched alkane, and cycloalkane) organic compounds. These findings improve our understanding of autooxidation reaction mechanisms that are routinely used to predict fuel ignition and oxidative stability of liquid hydrocarbons, while also providing insights relevant to the formation mechanisms of tropospheric aerosol building blocks. The direct observation of highly oxygenated intermediates for the autooxidation of alkanes at 500–600 K builds upon prior observations made in atmospheric conditions for the autooxidation of terpenes and other unsaturated hydrocarbons; it shows that highly oxygenated intermediates are stable at conditions above room temperature. These results further reveal that highly oxygenated intermediates are not only accessible by chemical activation but also by thermal activation. Theoretical calculations on H-atom migration reactions are presented to rationalize the relationship between the organic compound’s molecular structure (n-alkane, branched alkane, and cycloalkane) and its propensity to produce highly oxygenated intermediates via extensive autooxidation of hydroperoxyalkylperoxy radicals. Finally, detailed chemical kinetic simulations demonstrate the influence of these additional reaction pathways on the ignition of practical fuels.

  7. High sensitivity and accuracy dissolved oxygen (DO) detection by using PtOEP/poly(MMA-co-TFEMA) sensing film

    Science.gov (United States)

    Zhang, Ke; Zhang, Honglin; Wang, Ying; Tian, Yanqing; Zhao, Jiupeng; Li, Yao

    2017-01-01

    Fluorinated acrylate polymer has received great interest in recent years due to its extraordinary characteristics such as high oxygen permeability, good stability, low surface energy and refractive index. In this work, platinum octaethylporphyrin/poly(methylmethacrylate-co-trifluoroethyl methacrylate) (PtOEP/poly(MMA-co-TFEMA)) oxygen sensing film was prepared by the immobilizing of PtOEP in a poly(MMA-co-TFEMA) matrix and the technological readiness of optical properties was established based on the principle of luminescence quenching. It was found that the oxygen-sensing performance could be improved by optimizing the monomer ratio (MMA/TFEMA = 1:1), tributylphosphate(TBP, 0.05 mL) and PtOEP (5 μg) content. Under this condition, the maximum quenching ratio I0/I100 of the oxygen sensing film is obtained to be about 8.16, Stern-Volmer equation is I0/I = 1.003 + 2.663[O2] (R2 = 0.999), exhibiting a linear relationship, good photo-stability, high sensitivity and accuracy. Finally, the synthesized PtOEP/poly(MMA-co-TFEMA) sensing film was used for DO detection in different water samples.

  8. Comparison of Mask Oxygen Therapy and High-Flow Oxygen Therapy after Cardiopulmonary Bypass in Obese Patients

    Directory of Open Access Journals (Sweden)

    Mazlum Sahin

    2018-01-01

    Full Text Available Background. To clarify the efficiency of mask O2 and high-flow O2 (HFO treatments following cardiopulmonary bypass (CPB in obese patients. Methods. During follow-up, oxygenization parameters including arterial pressure of oxygen (PaO2, peripheral oxygen saturation (SpO2, and arterial partial pressure of carbon dioxide (PaCO2 and physical examination parameters including respiratory rate, heart rate, and arterial pressure were recorded respectively. Presence of atelectasia and dyspnea was noted. Also, comfort scores of patients were evaluated. Results. Mean duration of hospital stay was 6.9 ± 1.1 days in the mask O2 group, whereas the duration was significantly shorter (6.5 ± 0.7 days in the HFO group (p=0.034. The PaO2 values and SpO2 values were significantly higher, and PaCO2 values were significantly lower in patients who received HFO after 4th, 12th, 24th, 36th, and 48th hours. In postoperative course, HFO leads patients to achieve better postoperative FVC (p<0.001. Also, dyspnea scores and comfort scores were significantly better in patients who received HFO in both postoperative day 1 and day 2 (p<0.001,p<0.001 and p=0.002,p=0.001, resp.. Conclusion. Our study demonstrated that HFO following CPB in obese patients improved postoperative PaO2, SpO2, and PaCO2 values and decreased the atelectasis score, reintubation, and mortality rates when compared with mask O2.

  9. Mechanisms of Enhanced Electrocatalytic Activity for Oxygen Reduction Reaction on High-Index Platinum n(111)-(111) Surfaces.

    Science.gov (United States)

    Yue, Jeffrey; Du, Zheng; Shao, Minhua

    2015-09-03

    Oxygen reduction reactions (ORRs) on high-index planes of Pt n(111)-(111) were studied by density functional theory (DFT). The stepped surfaces, where n = 2, 3, and 4, showed that O2, O, and OH exhibited higher binding energies along the step compared to the terrace plane. The Pt atoms along the step can become distorted through the binding of the O and OH, where the shift in position of the Pt atoms is the largest along the stepped sites, hence forming stronger bonds with O atoms. One of the two O atoms produced from the bond dissociation of O2 will push the other one down a step with lower binding energies, consequently reducing the energy required for the protonation reaction (O + H(+) → OH, and OH + H(+) → H2O). The quicker recovery back to the clean Pt surface would therefore improve the catalytic properties of Pt nanoparticles, especially those with exposure to high-indexed facets.

  10. Initiation process of film detonation. Critical initiation energy of kerosene-oxygen-nitrogen mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Oyagi, Shigeharu; Yoshihashi, Teruo; Harigaya, Yasuo

    1988-02-25

    Film detonation(FD) in which kerosene was used as a fuel and oxygen-nitrogen mixtures were used as the oxidizer, was investigated. Oxygen-nitrogen mixture was introduced into the test tube (25x30mm cross section, 3m length) of the detonation tube and kerosene was coated on the inside surface. The pressure wave and combustion wave were studied by initiating the driver tube to form the blast wave and subsequently make combustion in the test tube. The some stoichiometric ratios of oxyhydrogen were used as initiating sources in the driver tube and the initiating energies(IE) were changed by changing initial pressures. In the FD initiating process, lower the dilution ratio of the oxidizer due to nitrogen, faster the FD transition; and smaller the IE, later the FD transion. The critical IE below which detonation was damped as the inactive blast, was obtained at a oxidizer dilution ratio. Nearly steady detonation wave propagating Mach number of 5 was obtained but became lower by increasing the dilution ratio. The critical IE determined with the dilution ratio of 0-3 increased monotonly with the increase of the dilution ratio. (5 figs, 2 tabs, 8 refs)

  11. Free energy changes and components implicit in the MWC allosteric model for the cooperative oxygen binding of hemoglobin.#

    OpenAIRE

    Bucci, Enrico

    2013-01-01

    Hill’s plots of oxygen binding isotherms reveal the presence of a transition between two different oxygen affinities at the beginning and end of the isotherm. They correspond to the two conformations anticipated by the MWC model, namely the T and R conformations at the beginning and end of oxygen binding, when the lower affinity of the T form develops into the higher affinity of the R form. The difference between the binding Gibbs free energies changes of the two affinities (ΔGL) is the free ...

  12. Evaluation of Characteristic Energy Scales of Pressure Stabilized Oxygen Chain States in YBa2Cu3Ox Films

    Science.gov (United States)

    2017-03-14

    TECHNICAL REPORT 3060 March 2016 Evaluation of Characteristic Energy Scales of Pressure Stabilized Oxygen Chain States in YBa2Cu3O∇x...the superconducting effective mass, m∗, and the superconducting penetration depth, λ, we examine the nature of characteristic energy scales of...quantum-like “states” in that they have near integer ratios of the superconducting to normal state carrier densities and condensation energy densities

  13. Oxygen electrodes for energy conversion and storage. Annual report, 1 October 1977-30 September 1978

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-01-15

    Research on the development of high performance, long life O/sub 2/ cathodes for both alkaline and acid electrolytes for a spectrum of applications including industrial electrolysis, fuel cells, and metal-air batteries is described. Oxygen electrocatalysts studied include platinum, silver, underpotential deposited layers and alloy metal layers on noble metal substrates, intercalated graphite, transition metal macrocyclic complexes, and transition metal oxides. Research on gas fed electrodes is also described. Results are presented and discussed in detail. An appendix on the electrodeposition of platinum crystallites on graphite substrates is included. (WHK)

  14. A rechargeable carbon-oxygen battery

    DEFF Research Database (Denmark)

    2014-01-01

    The invention relates to a rechargeable battery and a method to operate a rechargeable battery having high efficiency and high energy density for storing energy. The battery stores electrical energy in the bonds of carbon and oxygen atoms by converting carbon dioxide into solid carbon and oxygen....

  15. Increased long-term mortality after a high perioperative inspiratory oxygen fraction during abdominal surgery

    DEFF Research Database (Denmark)

    Meyhoff, Christian Sylvest; Jorgensen, Lars N; Wetterslev, Jørn

    2012-01-01

    A high perioperative inspiratory oxygen fraction (80%) has been recommended to prevent postoperative wound infections. However, the most recent and one of the largest trials, the PROXI trial, found no reduction in surgical site infection, and 30-day mortality was higher in patients given 80% oxyg....... In this follow-up study of the PROXI trial we assessed the association between long-term mortality and perioperative oxygen fraction in patients undergoing abdominal surgery.......A high perioperative inspiratory oxygen fraction (80%) has been recommended to prevent postoperative wound infections. However, the most recent and one of the largest trials, the PROXI trial, found no reduction in surgical site infection, and 30-day mortality was higher in patients given 80% oxygen...

  16. High energy particles and quanta in astrophysics

    Science.gov (United States)

    Mcdonald, F. B. (Editor); Fichtel, C. E.

    1974-01-01

    The various subdisciplines of high-energy astrophysics are surveyed in a series of articles which attempt to give an overall view of the subject as a whole by emphasizing the basic physics common to all fields in which high-energy particles and quanta play a role. Successive chapters cover cosmic ray experimental observations, the abundances of nuclei in the cosmic radiation, cosmic electrons, solar modulation, solar particles (observation, relationship to the sun acceleration, interplanetary medium), radio astronomy, galactic X-ray sources, the cosmic X-ray background, and gamma ray astronomy. Individual items are announced in this issue.

  17. A Parton Shower for High Energy Jets

    DEFF Research Database (Denmark)

    Andersen, Jeppe Rosenkrantz; Lonnblad, Leif; M. Smillie, Jennifer

    2011-01-01

    We present a method to match the multi-parton states generated by the High Energy Jets Monte Carlo with parton showers generated by the Ariadne program using the colour dipole model. The High Energy Jets program already includes a full resummation of soft divergences. Hence, in the matching...... it is important that the corresponding divergences in the parton shower are subtracted, keeping only the collinear parts. We present a novel, shower-independent method for achieving this, enabling us to generate fully exclusive and hadronized events with multiple hard jets, in hadronic collisions. We discuss...

  18. Strongly Interacting Matter at High Energy Density

    Energy Technology Data Exchange (ETDEWEB)

    McLerran,L.

    2008-09-07

    This lecture concerns the properties of strongly interacting matter (which is described by Quantum Chromodynamics) at very high energy density. I review the properties of matter at high temperature, discussing the deconfinement phase transition. At high baryon density and low temperature, large N{sub c} arguments are developed which suggest that high baryonic density matter is a third form of matter, Quarkyonic Matter, that is distinct from confined hadronic matter and deconfined matter. I finally discuss the Color Glass Condensate which controls the high energy limit of QCD, and forms the low x part of a hadron wavefunction. The Glasma is introduced as matter formed by the Color Glass Condensate which eventually thermalizes into a Quark Gluon Plasma.

  19. Highly Selective TiN-Supported Highly Dispersed Pt Catalyst: Ultra Active toward Hydrogen Oxidation and Inactive toward Oxygen Reduction.

    Science.gov (United States)

    Luo, Junming; Tang, Haibo; Tian, Xinlong; Hou, Sanying; Li, Xiuhua; Du, Li; Liao, Shijun

    2018-01-31

    The severe dissolution of the cathode catalyst, caused by an undesired oxygen reduction reaction at the anode during startup and shutdown, is a fatal challenge to practical applications of polymer electrolyte membrane fuel cells. To address this important issue, according to the distinct structure-sensitivity between the σ-type bond in H 2 and the π-type bond in O 2 , we design a HD-Pt/TiN material by highly dispersing Pt on the TiN surface to inhibit the unwanted oxygen reduction reaction. The highly dispersed Pt/TiN catalyst exhibits excellent selectivity toward hydrogen oxidation and oxygen reduction reactions. With a Pt loading of 0.88 wt %, our catalyst shows excellent hydrogen oxidation reaction activity, close to that of commercial 20 wt % Pt/C catalyst, and much lower oxygen reduction reaction activity than the commercial 20 wt % Pt/C catalyst. The lack of well-ordered Pt facets is responsible for the excellent selectivity of the HD-Pt/TiN materials toward hydrogen oxidation and oxygen reduction reactions. Our work provides a new and cost-effective solution to design selective catalysts toward hydrogen oxidation and oxygen reduction reactions, making the strategy of using oxygen-tolerant anode catalyst to improve the stability of polymer electrolyte membrane fuel cells during startup and shutdown more affordable and practical.

  20. Enhanced energy capacity of lithium-oxygen batteries with ionic liquid electrolytes by addition of ammonium ions

    Science.gov (United States)

    Matsuda, Shoichi; Uosaki, Kohei; Nakanishi, Shuji

    2017-07-01

    Lithium-oxygen (Li-O2) batteries with ionic liquid-based electrolytes have attracted much attention because of their superior battery performance and high safety. However, the practical energy capacities achieved to date are markedly lower than those of Li-ion batteries. A dominant factor that limits the energy capacities of Li-O2 batteries is the insulating characteristics and insolubility of lithium peroxide (Li2O2), which gradually accumulates on the positive electrode as a discharge product. Herein, we report that ammonium ions function as a promoter for the solution-route formation of Li2O2, which results in a significant improvement of the energy capacity of Li-O2 cells. Scanning electron microscopy analyses revealed that the structure of Li2O2 changed from spherical particles to toroidal particles with an increase in the ammonium ions concentration. Ionic additives that have been reported to function as promoters the solution-route formation of Li2O2 in ether-based electrolyte systems do not exhibit a promoting effect in ionic liquid-based electrolytes.

  1. Metal-free and Oxygen-free Graphene as Oxygen Reduction Catalysts for Highly Efficient Fuel Cells

    Science.gov (United States)

    2013-06-30

    L. Science 2009, 323, 760) and nitrogen-doped graphene sheets (Qu, L.; Liu, Y.; Baek, J.-B.; Dai, L. ACS Nano 2010, 4, 1321) as highly efficient...fuel to create heat, fuel cells convert chemical energy directly into electricity. By pumping , for example, hydrogen gas onto one electrode (the anode...760) and nitrogen-doped graphene sheets (Qu, L.; Liu, Y.; Baek, J.-B.; Dai, L. ACS Nano 2010, 4, 1321) as highly efficient ORR, we have developed in

  2. Oxygen-Rich Lithium Oxide Phases Formed at High Pressure for Potential Lithium-Air Battery Electrode.

    Science.gov (United States)

    Yang, Wenge; Kim, Duck Young; Yang, Liuxiang; Li, Nana; Tang, Lingyun; Amine, Khalil; Mao, Ho-Kwang

    2017-09-01

    The lithium-air battery has great potential of achieving specific energy density comparable to that of gasoline. Several lithium oxide phases involved in the charge-discharge process greatly affect the overall performance of lithium-air batteries. One of the key issues is linked to the environmental oxygen-rich conditions during battery cycling. Here, the theoretical prediction and experimental confirmation of new stable oxygen-rich lithium oxides under high pressure conditions are reported. Three new high pressure oxide phases that form at high temperature and pressure are identified: Li2O3, LiO2, and LiO4. The LiO2 and LiO4 consist of a lithium layer sandwiched by an oxygen ring structure inherited from high pressure ε-O8 phase, while Li2O3 inherits the local arrangements from ambient LiO2 and Li2O2 phases. These novel lithium oxides beyond the ambient Li2O, Li2O2, and LiO2 phases show great potential in improving battery design and performance in large battery applications under extreme conditions.

  3. High-energy, high-rate materials processing

    Science.gov (United States)

    Marcus, H. L.; Bourell, D. L.; Eliezer, Z.; Persad, C.; Weldon, W.

    1987-12-01

    The increasingly available range of pulsed-power, high energy kinetic storage devices, such as low-inductance pulse-forming networks, compulsators, and homopolar generators, is presently considered as a basis for industrial high energy/high rate (HEHR) processing to accomplish shock hardening, drilling, rapid surface alloying and melting, welding and cutting, transformation hardening, and cladding and surface melting in metallic materials. Time-temperature-transformation concepts furnish the basis for a fundamental understanding of the potential advantages of this direct pulsed power processing. Attention is given to the HEHR processing of a refractory molybdenum alloy, a nickel-base metallic glass, tungsten, titanium aluminides, and metal-matrix composites.

  4. Impact of hypothalamic reactive oxygen species in the control of energy metabolism and food intake

    Directory of Open Access Journals (Sweden)

    Anne eDrougard

    2015-02-01

    Full Text Available Hypothalamus is a key area involved in the control of metabolism and food intake via the integrations of numerous signals (hormones, neurotransmitters, metabolites from various origins. These factors modify hypothalamic neurons activity and generate adequate molecular and behavioral responses to control energy balance. In this complex integrative system, a new concept has been developed in recent years, that includes reactive oxygen species (ROS as a critical player in energy balance. ROS are known to act in many signaling pathways in different peripheral organs, but also in hypothalamus where they regulate food intake and metabolism by acting on different types of neurons, including proopiomelanocortin (POMC and agouti-related protein (AgRP/neuropeptide Y (NPY neurons. Hypothalamic ROS release is under the influence of different factors such as pancreatic and gut hormones, adipokines (leptin, apelin,..., neurotransmitters and nutrients (glucose, lipids,.... The sources of ROS production are multiple including NADPH oxidase, but also the mitochondria which is considered as the main ROS producer in the brain. ROS are considered as signaling molecules, but conversely impairment of this neuronal signaling ROS pathway contributes to alterations of autonomic nervous system and neuroendocrine function, leading to metabolic diseases such as obesity and type 2 diabetes.In this review we focus our attention on factors that are able to modulate hypothalamic ROS release in order to control food intake and energy metabolism, and whose deregulations could participate to the development of pathological conditions. This novel insight reveals an original mechanism in the hypothalamus that controls energy balance and identify hypothalamic ROS signaling as a potential therapeutic strategy to treat metabolic disorders.

  5. Impact of oxygen stress and energy availability on membrane stability of plant cells.

    Science.gov (United States)

    Rawyler, André; Arpagaus, Silvio; Braendle, Roland

    2002-10-01

    This article reviews the relationship between the energy status of plant cells under O(2) stress (e.g. waterlogging) and the maintenance of membrane intactness, using information largely derived from suspension cultures of anoxia-intolerant potato cells. Energy-related parameters measured were fermentation end-products (ethanol, lactate, alanine), respiratory rate, ATP, adenylate energy charge, nitrate reductase activity and biomass. ATP synthesis rates were calculated from the first four parameters. Reactive oxygen species were estimated from H(2)O(2) and superoxide levels, and the enzymatic detoxification potential from the activity levels of catalase and superoxide dismutase. Structure-related parameters were total fatty acids, free fatty acids (FFAs), lipid hydroperoxides, total phospholipids, N-acylphosphatidylethanolamine (NAPE) and cell viability. The following issues are addressed in this review: (1) what is the impact of anoxia on membrane lipids and how does this relate to energy status; (2) does O(2) per se play a role in these changes; (3) under which conditions and to what extent does lipid peroxidation occur upon re-aeration; and (4) can the effects of re-aeration be distinguished from those of anoxia? The emerging picture is a reappraisal of the relative contributions of anoxia and re-aeration. Two successive phases (pre-lytic and lytic) characterize potato cells under anoxia. They are connected by a threshold in ATP production rate, below which membrane lipids are hydrolysed to FFAs, and NAPE increases. Since lipid peroxidation occurs only when cells are reoxygenated during the lytic phase, its biological relevance in an already damaged system is questionable.

  6. Impact of hypothalamic reactive oxygen species in the regulation of energy metabolism and food intake.

    Science.gov (United States)

    Drougard, Anne; Fournel, Audren; Valet, Philippe; Knauf, Claude

    2015-01-01

    Hypothalamus is a key area involved in the control of metabolism and food intake via the integrations of numerous signals (hormones, neurotransmitters, metabolites) from various origins. These factors modify hypothalamic neurons activity and generate adequate molecular and behavioral responses to control energy balance. In this complex integrative system, a new concept has been developed in recent years, that includes reactive oxygen species (ROS) as a critical player in energy balance. ROS are known to act in many signaling pathways in different peripheral organs, but also in hypothalamus where they regulate food intake and metabolism by acting on different types of neurons, including proopiomelanocortin (POMC) and agouti-related protein (AgRP)/neuropeptide Y (NPY) neurons. Hypothalamic ROS release is under the influence of different factors such as pancreatic and gut hormones, adipokines (leptin, apelin,…), neurotransmitters and nutrients (glucose, lipids,…). The sources of ROS production are multiple including NADPH oxidase, but also the mitochondria which is considered as the main ROS producer in the brain. ROS are considered as signaling molecules, but conversely impairment of this neuronal signaling ROS pathway contributes to alterations of autonomic nervous system and neuroendocrine function, leading to metabolic diseases such as obesity and type 2 diabetes. In this review we focus our attention on factors that are able to modulate hypothalamic ROS release in order to control food intake and energy metabolism, and whose deregulations could participate to the development of pathological conditions. This novel insight reveals an original mechanism in the hypothalamus that controls energy balance and identify hypothalamic ROS signaling as a potential therapeutic strategy to treat metabolic disorders.

  7. High-Performance Pyrochlore-Type Yttrium Ruthenate Electrocatalyst for Oxygen Evolution Reaction in Acidic Media

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jaemin [Department; Shih, Pei-Chieh [Department; Tsao, Kai-Chieh [Department; Pan, Yung-Tin [Department; Yin, Xi [Department; Sun, Cheng-Jun [X-ray; Yang, Hong [Department

    2017-08-17

    Development of acid-stable electrocatalysts with low overpotential for oxygen evolution reaction (OER) is a major challenge for the production of hydrogen directly from water. We report in this paper a pyrochlore yttrium ruthenate (Y2Ru2O7-δ) electrocatalyst that has significantly enhanced performance towards OER in acid media over the best-known catalysts, with an onset overpotential of 190 mV and high stability in 0.1-M perchloric acid solution. X-ray absorption near-edge structure (XANES) indicates Y2Ru2O7-δ electrocatalyst had a low valence state that favors the high OER activity. Density functional theory (DFT) calculation shows this pyrochlore has lower band center energy for the overlap between Ru 4d and O 2p orbitals and therefore more stable Ru-O bond than RuO2, highlighting the effect of yttrium on the enhancement in stability. The Y2Ru2O7-δ pyrochlore is also free of expensive iridium metal, thus a cost-effective candidate for practical applications.

  8. A Gas Calorimeter for High-Energy Experiment and Study of High-Energy Cascade Shower

    Energy Technology Data Exchange (ETDEWEB)

    Miyata, Hitoshi [Tsukuba U.

    1984-01-01

    High energy behavior of the electromagnetic cascade shower has been studied. high energy showers were created by electron and hadron beams with energies between 25 GeV and 150 GeV at Fermi National Accelerator Laboratory. The showers were observed by a shower detector consisting of multi-layer of lead plates and proportional chambers. The experimental results were analyzed with special emphasis on the fluctuation problem of the electromagnetic cascade shower....

  9. Hyperglycaemia modifies energy metabolism and reactive oxygen species formation in endothelial cells in vitro.

    Science.gov (United States)

    Dymkowska, Dorota; Drabarek, Beata; Podszywałow-Bartnicka, Paulina; Szczepanowska, Joanna; Zabłocki, Krzysztof

    2014-01-15

    There is significant evidence for an involvement of reactive oxygen species (ROS) in the pathogenesis of diabetic vascular complications through many metabolic and structural derangements. However, despite the advanced knowledge on the crucial role of ROS in cardiovascular damage, their intracellular source in endothelial cells exposed to high concentrations of glucose has not been precisely defined. Moreover, the molecular mechanism of action of elevated glucose on mitochondria has not been fully elucidated. The main aim of this study was to describe changes in the mitochondrial metabolism of human umbilical vein endothelial cells (HUVECs) treated with high glucose concentrations and to indicate the actual source of ROS in these cells. HUVECs exposed to 30 mM glucose exhibited an increased content of vascular adhesive molecule-1 (VCAM-1) and an excessive ROS production. Faster oxygen consumption and increased abundance of selected respiratory complexes coexist with slightly declined mitochondrial membrane potential and substantially elevated amount of uncoupling protein-2 (UCP2). Inhibition of NADPH oxidase (NOX) and modification of mitochondrial ROS generation with a mitochondrial uncoupler or respiratory chain inhibitors allowed concluding that the major source of ROS in HUVECs exposed to hyperglycaemic conditions is NOX. The mitochondrial respiratory chain seems not to participate in this phenomenon. Copyright © 2013 Elsevier Inc. All rights reserved.

  10. The relationship between energy-dependent phagocytosis and the rate of oxygen consumption in Tetrahymena.

    Science.gov (United States)

    Skriver, L; Nilsson, J R

    1978-12-01

    The induction of high rates of food vacuole formation in Tetrahymena pyriformis increased the rate of respiration in exponentially growing cells by 17% and in starving cells by 47.5%. The increased rate of oxygen uptake was caused by phagocytosis itself, as shown by comparing the rates of respiration of a Tetrahymena mutant exposed to particles at the permissive or restrictive temperatures for food vacuole formation. During cell division, heat-synchronized cells in rich, particle-supplemented medium showed a significant decrease in the rate of respiration. Furthermore, dimethyl sulphoxide, in concentrations sufficient to block food vacuole formation, suppressed the rate of respiration to a level similar to that of starved cells. Cytochalasin B, fowever, did not reduce the rate of oxygen uptake despite the inability of the cells to complete the formation of food vacuoles during treatment; a possible explanation for this finding is discussed. There was a strong correlation between formation of food vacuoles and a high metabolic rate in Tetrahymena.

  11. High-Energy Physics: Exit America?

    CERN Multimedia

    Seife, Charles

    2005-01-01

    Budget cuts and cancellations threaten to end U.S. exploration of the particle frontier. Fermilab's Tevatron, due to shut down around 200, could be the last large particle accelerator in the United States; the Large Hadron Collider in Geneva should ensure European dominance of high-energy physics (3 pages)

  12. Hard scattering in high-energy QCD

    CERN Document Server

    Mangano, Michelangelo L

    2000-01-01

    I review the recent results in the field of QCD at high energy presented to this Conference. In particular, I will concentrate on measurements of $\\as$ from studies of event structures and jet rates, jet production in hadronic collisions, and heavy quark production.

  13. Perspective in high energy physics instrumentation

    Energy Technology Data Exchange (ETDEWEB)

    Rossi, L. [INFN, Genoa (Italy)

    1995-10-01

    The discovery potential of the next generation of particle accelerators, and in particular of the large hadron collider (LHC), can only be fully exploited by very sophisticated particle detectors. The basics of detectors for momentum and energy measurement is here presented together with a recollection of recent developments which are relevant for use at high luminosity accelerators.

  14. Detecting ultra high energy neutrinos with LOFAR

    NARCIS (Netherlands)

    Mevius, M.; Buitink, S.; Falcke, H.; Horandel, J.; James, C. W.; McFadden, R.; Scholten, O.; Singh, K.; Stappers, B.; ter Veen, S.

    2012-01-01

    The NuMoon project aims to detect signals of Ultra High Energy (UHE) Cosmic Rays with radio telescopes on Earth using the Lunar Cherenkov technique at low frequencies (similar to 150 MHz). The advantage of using low frequencies is the much larger effective detecting volume, with as trade-off the

  15. Maximal Entanglement in High Energy Physics

    NARCIS (Netherlands)

    Cervera-Lierta, Alba; Latorre, José I.; Rojo, Juan; Rottoli, Luca

    2017-01-01

    We analyze how maximal entanglement is generated at the fundamental level in QED by studying correlations between helicity states in tree-level scattering processes at high energy. We demonstrate that two mechanisms for the generation of maximal entanglement are at work: i) $s$-channel processes

  16. High energy bosons do not propagate

    Energy Technology Data Exchange (ETDEWEB)

    Kurkov, M.A., E-mail: Kurkov@na.infn.it [Dipartimento di Fisica, Università di Napoli Federico II (Italy); INFN, Sezione di Napoli (Italy); Lizzi, Fedele, E-mail: fedele.lizzi@na.infn.it [Dipartimento di Fisica, Università di Napoli Federico II (Italy); INFN, Sezione di Napoli (Italy); Departament de Estructura i Constituents de la Matèria, Institut de Ciéncies del Cosmos, Universitat de Barcelona, Barcelona, Catalonia (Spain); Vassilevich, Dmitri, E-mail: dvassil@gmail.com [CMCC, Universidade Federal do ABC, Santo André, S.P. (Brazil)

    2014-04-04

    We discuss the propagation of bosons (scalars, gauge fields and gravitons) at high energy in the context of the spectral action. Using heat kernel techniques, we find that in the high-momentum limit the quadratic part of the action does not contain positive powers of the derivatives. We interpret this as the fact that the two-point Green functions vanish for nearby points, where the proximity scale is given by the inverse of the cutoff.

  17. The role of oxygen in yeast metabolism during high cell density brewery fermentations.

    Science.gov (United States)

    Verbelen, P J; Saerens, S M G; Van Mulders, S E; Delvaux, F; Delvaux, F R

    2009-04-01

    The volumetric productivity of the beer fermentation process can be increased by using a higher pitching rate (i.e., higher inoculum size). However, the decreased yeast net growth observed in these high cell density fermentations can have a negative impact on the physiological stability throughout subsequent yeast generations. The use of different oxygen conditions (wort aeration, wort oxygenation, yeast preoxygenation) was investigated to improve the growth yield during high cell density fermentations and yeast metabolic and physiological parameters were assessed systematically. Together with a higher extent of growth (dependent on the applied oxygen conditions), the fermentation power and the formation of unsaturated fatty acids were also affected. Wort oxygenation had a significant decreasing effect on the formation of esters, which was caused by a decreased expression of the alcohol acetyl transferase gene ATF1, compared with the other conditions. Lower glycogen and trehalose levels at the end of fermentation were observed in case of the high cell density fermentations with oxygenated wort and the reference fermentation. The expression levels of BAP2 (encoding the branched chain amino acid permease), ERG1 (encoding squalene epoxidase), and the stress responsive gene HSP12 were predominantly influenced by the high cell concentrations, while OLE1 (encoding the fatty acid desaturase) and the oxidative stress responsive genes SOD1 and CTT1 were mainly affected by the oxygen availability per cell. These results demonstrate that optimisation of high cell density fermentations could be achieved by improving the oxygen conditions, without drastically affecting the physiological condition of the yeast and beer quality.

  18. Effect of a High-intensity Interval Training method on maximum oxygen consumption in Chilean schoolchildren

    Directory of Open Access Journals (Sweden)

    Sergio Galdames-Maliqueo

    2017-12-01

    Full Text Available Introduction: The low levels of maximum oxygen consumption (VO2max evaluated in Chilean schoolchildren suggest the startup of trainings that improve the aerobic capacity. Objective: To analyze the effect of a High-intensity Interval Training method on maximum oxygen consumption in Chilean schoolchildren. Materials and methods: Thirty-two high school students from the eighth grade, who were divided into two groups, were part of the study (experimental group = 16 students and control group = 16 students. The main analyzed variable was the maximum oxygen consumption through the Course Navette Test. A High-intensity Interval training method was applied based on the maximum aerobic speed obtained through the Test. A mixed ANOVA was used for statistical analysis. Results: The experimental group showed a significant increase in the Maximum Oxygen Consumption between the pretest and posttest when compared with the control group (p < 0.0001. Conclusion: The results of the study showed a positive effect of the High-intensity Interval Training on the maximum consumption of oxygen. At the end of the study, it is concluded that High-intensity Interval Training is a good stimulation methodology for Chilean schoolchildren.

  19. New highly active oxygen reduction electrode for PEM fuel cell and Zn/air battery applications (NORA). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Thiele, D.; Zuettel, A.

    2008-04-15

    This illustrated final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project concerning a new, highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications. The goal of this project was, according to the authors, to increase the efficiency of the oxygen reduction reaction by lowering the activation polarisation through the right choice of catalyst and by lowering the concentration polarisation. In this work, carbon nanotubes are used as support material. The use of these nanotubes grown on perovskites is discussed. Theoretical considerations regarding activation polarisation are discussed and alternatives to the use of platinum are examined. The results of experiments carried out are presented in graphical and tabular form. The paper is completed with a comprehensive list of references.

  20. Automatic Energy Schemes for High Performance Applications

    Energy Technology Data Exchange (ETDEWEB)

    Sundriyal, Vaibhav [Iowa State Univ., Ames, IA (United States)

    2013-01-01

    Although high-performance computing traditionally focuses on the efficient execution of large-scale applications, both energy and power have become critical concerns when approaching exascale. Drastic increases in the power consumption of supercomputers affect significantly their operating costs and failure rates. In modern microprocessor architectures, equipped with dynamic voltage and frequency scaling (DVFS) and CPU clock modulation (throttling), the power consumption may be controlled in software. Additionally, network interconnect, such as Infiniband, may be exploited to maximize energy savings while the application performance loss and frequency switching overheads must be carefully balanced. This work first studies two important collective communication operations, all-to-all and allgather and proposes energy saving strategies on the per-call basis. Next, it targets point-to-point communications to group them into phases and apply frequency scaling to them to save energy by exploiting the architectural and communication stalls. Finally, it proposes an automatic runtime system which combines both collective and point-to-point communications into phases, and applies throttling to them apart from DVFS to maximize energy savings. The experimental results are presented for NAS parallel benchmark problems as well as for the realistic parallel electronic structure calculations performed by the widely used quantum chemistry package GAMESS. Close to the maximum energy savings were obtained with a substantially low performance loss on the given platform.

  1. Novel fully-BODIPY functionalized cyclotetraphosphazene photosensitizers having high singlet oxygen quantum yields

    Science.gov (United States)

    Şenkuytu, Elif; Eçik, Esra Tanrıverdi

    2017-07-01

    Novel fully-BODIPY functionalized dendrimeric cyclotetraphosphazenes (FBCP 1 and 2) have been synthesized and characterized by 1H, 13C and 31P NMR spectroscopies. The photophysical and photochemical properties of FBCP 1 and 2 are investigated in dichloromethane solution. The effectiveness of singlet oxygen generation was measured for FBCP 1 and 2 by UV-Vis spectra monitoring of the solution of 1,3-diphenylisobenzofuran (DPBF), which is a well-known trapping molecule used in detection of singlet oxygen. FBCP 1 and 2 show high molar extinction coefficients in the NIR region, good singlet oxygen quantum yields and appropriate photo degradation. The data presented in the work indicate that the dendrimeric cyclotetraphosphazenes are effective singlet oxygen photosensitizers that might be used for various areas of applications such as photodynamic therapy and photocatalysis.

  2. MODELING ENERGY EXPENDITURE AND OXYGEN CONSUMPTION IN HUMAN EXPOSURE MODELS: ACCOUNTING FOR FATIGUE AND EPOC

    Science.gov (United States)

    Human exposure and dose models often require a quantification of oxygen consumption for a simulated individual. Oxygen consumption is dependent on the modeled Individual's physical activity level as described in an activity diary. Activity level is quantified via standardized val...

  3. Photons as Ultra High Energy Cosmic Rays ?

    CERN Document Server

    Kalashev, O E; Semikoz, D V; Tkachev, Igor I

    2001-01-01

    We study spectra of the Ultra High Energy Cosmic Rays assuming primaries are protons and photons, and that their sources are extragalactic. We assume power low for the injection spectra and take into account the influence of cosmic microwave, infrared, optical and radio backgrounds as well as extragalactic magnetic fields on propagation of primaries. Our additional free parameters are the maximum energy of injected particles and the distance to the nearest source. We find a parameter range where the Greisen-Zatsepin-Kuzmin cut-off is avoided.

  4. High Energy Emission From Millisecond Pulsars

    Science.gov (United States)

    Harding, Alice K.

    2003-01-01

    Emission at X-ray and gamma-ray energies has been detected from millisecond pulsars, both isolated and in binary systems. Although these pulsars have low surface magnetic fields, their short periods allow them to have large magnetospheric potential drops, so that high-energy emission from these sources is not unexpected. In fact, several nearby energetic millisecond pulsars that have been detected in X-rays could easily have been detected in gamma-rays by EGRET, but they were not. The reason for this may lie in a high-energy spectrum that is very different in these sources from that of normal pulsars. Both polar cap and outer gap models predict a two-component spectrum, one component peaking in hard X-rays and the other peaking above 1 GeV, with a gap at EGRET peak sensitivity. I will discuss the models for high-energy emission from millisecond pulsars, highlighting the differences between polar cap and outer gap models in spectrum and geometry of the emission.

  5. Proposal for a High Energy Nuclear Database

    Energy Technology Data Exchange (ETDEWEB)

    Brown, David A.; Vogt, Ramona

    2005-03-31

    We propose to develop a high-energy heavy-ion experimental database and make it accessible to the scientific community through an on-line interface. This database will be searchable and cross-indexed with relevant publications, including published detector descriptions. Since this database will be a community resource, it requires the high-energy nuclear physics community's financial and manpower support. This database should eventually contain all published data from Bevalac and AGS to RHIC to CERN-LHC energies, proton-proton to nucleus-nucleus collisions as well as other relevant systems, and all measured observables. Such a database would have tremendous scientific payoff as it makes systematic studies easier and allows simpler benchmarking of theoretical models to a broad range of old and new experiments. Furthermore, there is a growing need for compilations of high-energy nuclear data for applications including stockpile stewardship, technology development for inertial confinement fusion and target and source development for upcoming facilities such as the Next Linear Collider. To enhance the utility of this database, we propose periodically performing evaluations of the data and summarizing the results in topical reviews.

  6. Performances of miniature microstrip detectors made on oxygen enriched p-type substrates after very high proton irradiation

    CERN Document Server

    Casse, G; Lozano, M; Martí i García, S; Turner, P R

    2004-01-01

    Silicon microstrip detectors with n-type implant read-out strips on FZ p-type bulk (n-in-p) show superior charge collection properties, after heavy irradiation, to the more standard p-strips in n-type silicon (p-in-n). It is also well established that oxygen-enriched n- type silicon substrates show better performance, in terms of degradation of the full depletion voltage after charged hadron irradiation, than the standard FZ silicon used for high energy physics detectors. Silicon microstrip detectors combining both the advantages of oxygenation and of n-strip read-out (n-in-n) have achieved high radiation tolerance to charged hadrons. The manufacturing of n-in-n detectors though requires double-sided processing, resulting in more complicated and expensive devices than standard p-in-n. A cheaper single-sided option, that still combines these advantages, is to use n-in-p devices. P-type FZ wafers have been oxygen-enriched by high temperature diffusion from an oxide layer and succesfully used to process miniatur...

  7. Topical hyperbaric oxygen and low-energy laser for the treatment of chronic ulcers.

    Science.gov (United States)

    Landau, Zvi; Sommer, Ahuva; Miller, Edward B

    2006-07-01

    Diabetic foot ulcers (DFU) and chronic venous ulcers (CVU) are persistent cutaneous lesions that are difficult to treat and heal. Topical hyperbaric oxygen (THO) and low-energy laser (LEL) are therapies that have been employed separately for ulcer treatment, but their concomitant use has not been investigated. In this unblinded, open-label non-randomized trial, we treated 374 consecutive patients with treatment-refractory chronic ulcers (218 patients with DFU and 156 individuals with CVU) with a combination of THO and LEL. THO was administered by pumping 100% oxygen into a disposable, sealed polyethylene chamber for 2 h, two to three times weekly. LEL was administered concurrently using a helium-neon laser at 4 J/cm(2) for 20 min. Complete ulcer closure was obtained in 78% of patients in each group (170 patients with DFU and 127 patients with CVU). Treatment failure resulting in amputation in DFU was seen in 48 patients (22%); non-closure of ulcers within 18 months in individuals with CVU was seen in 29 (22%). The length of therapy was also similar in the two groups (3.7+/-3 versus 4.1+/-3 months in DFU and CVU cohorts, respectively). However, the number of treatments required to affect healing was greater in the CVU group than among the DFU patients (40+/-25 versus 31.4+/-20 treatments). THO and LEL therapies are safe, effective, simple and inexpensive therapies for DFU and CVU. Confirmation must await the performance of double-blind, randomized, controlled trials currently under way.

  8. Impact of the renewable oxygenate standard for reformulated gasoline on ethanol demand, energy use, and greenhouse gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Stork, K.C.; Singh, M.K.

    1995-04-01

    To assure a place for renewable oxygenates in the national reformulated gasoline (RFG) program, the US Environmental Protection Agency has promulgated the renewable oxygenate standard (ROS) for RFG. It is assumed that ethanol derived from corn will be the only broadly available renewable oxygenate during Phase I of the RFG program. This report analyzes the impact that the ROS could have on the supply of ethanol, its transported volume, and its displacement from existing markets. It also considers the energy and crude oil consumption and greenhouse gas (GHG) emissions that could result from the production and use of various RFGs that could meet the ROS requirements. The report concludes that on the basis of current and projected near-term ethanol capacity, if ethanol is the only available renewable oxygenate used to meet the requirements of the ROS, diversion of ethanol from existing use as a fuel is likely to be necessary. Year-round use of ethanol and ETBE would eliminate the need for diversion by reducing winter demand for ethanol. On an RFG-program-wide basis, using ethanol and ETBE to satisfy the ROS can be expected to slightly reduce fossil energy use, increase crude oil use, and have essentially no effect on GHG emissions or total energy use relative to using RFG oxygenated only with MTBE.

  9. Energy harvesting in high voltage measuring techniques

    Science.gov (United States)

    Żyłka, Pawel; Doliński, Marcin

    2016-02-01

    The paper discusses selected problems related to application of energy harvesting (that is, generating electricity from surplus energy present in the environment) to supply autonomous ultra-low-power measurement systems applicable in high voltage engineering. As a practical example of such implementation a laboratory model of a remote temperature sensor is presented, which is self-powered by heat generated in a current-carrying busbar in HV- switchgear. Presented system exploits a thermoelectric harvester based on a passively cooled Peltier module supplying micro-power low-voltage dc-dc converter driving energy-efficient temperature sensor, microcontroller and a fibre-optic transmitter. Performance of the model in laboratory simulated conditions are presented and discussed.

  10. High time resolution measurements of the thermosphere from Fabry-Perot Interferometer measurements of atomic oxygen

    Directory of Open Access Journals (Sweden)

    E. A. K. Ford

    2007-06-01

    Full Text Available Recent advances in the performance of CCD detectors have enabled a high time resolution study of the high latitude upper thermosphere with Fabry-Perot Interferometers (FPIs to be performed. 10-s integration times were used during a campaign in April 2004 on an FPI located in northern Sweden in the auroral oval. The FPI is used to study the thermosphere by measuring the oxygen red line emission at 630.0 nm, which emits at an altitude of approximately 240 km. Previous time resolutions have been 4 min at best, due to the cycle of look directions normally observed. By using 10 s rather than 40 s integration times, and by limiting the number of full cycles in a night, high resolution measurements down to 15 s were achievable. This has allowed the maximum variability of the thermospheric winds and temperatures, and 630.0 nm emission intensities, at approximately 240 km, to be determined as a few minutes. This is a significantly greater variability than the often assumed value of 1 h or more. A Lomb-Scargle analysis of this data has shown evidence of gravity wave activity with waves with short periods. Gravity waves are an important feature of mesosphere-lower thermosphere (MLT dynamics, observed using many techniques and providing an important mechanism for energy transfer between atmospheric regions. At high latitudes gravity waves may be generated in-situ by localised auroral activity. Short period waves were detected in all four clear nights when this experiment was performed, in 630.0 nm intensities and thermospheric winds and temperatures. Waves with many periodicities were observed, from periods of several hours, down to 14 min. These waves were seen in all parameters over several nights, implying that this variability is a typical property of the thermosphere.

  11. Current Perspectives in High Energy Astrophysics

    Science.gov (United States)

    Ormes, Jonathan F. (Editor)

    1996-01-01

    High energy astrophysics is a space-age discipline that has taken a quantum leap forward in the 1990s. The observables are photons and particles that are unable to penetrate the atmosphere and can only be observed from space or very high altitude balloons. The lectures presented as chapters of this book are based on the results from the Compton Gamma-Ray Observatory (CGRO) and Advanced Satellite for Cosmology and Astrophysics (ASCA) missions to which the Laboratory for High Energy Astrophysics at NASA's Goddard Space Flight Center made significant hardware contributions. These missions study emissions from very hot plasmas, nuclear processes, and high energy particle interactions in space. Results to be discussed include gamma-ray beaming from active galactic nuclei (AGN), gamma-ray emission from pulsars, radioactive elements in the interstellar medium, X-ray emission from clusters of galaxies, and the progress being made to unravel the gamma-ray burst mystery. The recently launched X-ray Timing Explorer (XTE) and prospects for upcoming Astro-E and Advanced X-ray Astronomy Satellite (AXAF) missions are also discussed.

  12. The High Energy Telescope for STEREO

    Science.gov (United States)

    von Rosenvinge, T. T.; Reames, D. V.; Baker, R.; Hawk, J.; Nolan, J. T.; Ryan, L.; Shuman, S.; Wortman, K. A.; Mewaldt, R. A.; Cummings, A. C.; Cook, W. R.; Labrador, A. W.; Leske, R. A.; Wiedenbeck, M. E.

    2008-04-01

    The IMPACT investigation for the STEREO Mission includes a complement of Solar Energetic Particle instruments on each of the two STEREO spacecraft. Of these instruments, the High Energy Telescopes (HETs) provide the highest energy measurements. This paper describes the HETs in detail, including the scientific objectives, the sensors, the overall mechanical and electrical design, and the on-board software. The HETs are designed to measure the abundances and energy spectra of electrons, protons, He, and heavier nuclei up to Fe in interplanetary space. For protons and He that stop in the HET, the kinetic energy range corresponds to ˜13 to 40 MeV/n. Protons that do not stop in the telescope (referred to as penetrating protons) are measured up to ˜100 MeV/n, as are penetrating He. For stopping He, the individual isotopes 3He and 4He can be distinguished. Stopping electrons are measured in the energy range ˜0.7 6 MeV.

  13. Bosch Reactor Development for High Percentage Oxygen Recovery from Carbon Dioxide

    Science.gov (United States)

    Howard, David; Abney, Morgan

    2015-01-01

    This next Generation Life Support Project entails the development and demonstration of Bosch reaction technologies to improve oxygen recovery from metabolically generated oxygen and/or space environments. A primary focus was placed on alternate carbon formation reactor concepts to improve useful catalyst life for space vehicle applications, and make use of in situ catalyst resources for non-terrestrial surface missions. Current state-of-the-art oxygen recovery systems onboard the International Space Station are able to effectively recover approximately 45 percent of the oxygen consumed by humans and exhausted in the form of carbon dioxide (CO2). Excess CO2 is vented overboard and the oxygen contained in the molecules is lost. For long-duration missions beyond the reaches of Earth for resupply, it will be necessary to recover greater amounts of constituents such as oxygen that are necessary for sustaining life. Bosch technologies theoretically recover 100 percent of the oxygen from CO2, producing pure carbon as the sole waste product. Challenges with this technology revolve around the carbon product fouling catalyst materials, drastically limiting catalyst life. This project successfully demonstrated techniques to extend catalyst surface area exposure times to improve catalyst life for vehicle applications, and demonstrated the use of Martian and lunar regolith as viable catalyst Bosch Reactor Development for High Percentage Oxygen Recovery From Carbon Dioxide materials for surface missions. The Bosch process generates carbon nanotube formation within the regolith, which has been shown to improve mechanical properties of building materials. Production of bricks from post reaction regolith for building and radiation shielding applications were also explored.

  14. Evaluation of oxygen administration with a high-flow nasal cannula to clinically normal dogs.

    Science.gov (United States)

    Daly, Jennifer L; Guenther, Christine L; Haggerty, Jamie M; Keir, Iain

    2017-05-01

    OBJECTIVE To evaluate the safety and efficacy of oxygen administration by use of a high-flow nasal cannula (HFNC) in sedated clinically normal dogs. ANIMALS 6 healthy adult dogs undergoing routine dental prophylaxis. PROCEDURES Dogs were sedated with butorphanol tartrate and dexmedetomidine. An esophageal balloon catheter was inserted into the esophagus, a double-pronged nasal cannula was inserted into the nares, and a catheter was inserted into the dorsal pedal artery. Dogs were positioned in right lateral recumbency. After a 6-minute acclimation period, baseline blood gas values and transpulmonary pressure were measured. Dogs then received supplemental oxygen via conventional oxygen therapy (COT) at a rate of 100 mL/kg/min (COT-100 treatment) and an HFNC at a rate of 20 L/min (HF-20 treatment) and 30 L/min (HF-30 treatment). Arterial blood gas and transpulmonary pressure were measured after a 6-minute acclimation period for each oxygen delivery method. Radiographs were obtained before and after oxygen administration to evaluate gastric distension. RESULTS Median Pao2 was significantly higher for HF-20 (519.9 mm Hg) and HF-30 (538.1 mm Hg) treatments, compared with median Pao2 for the COT-100 treatment (202.9 mm Hg). The Pao2 did not differ significantly between the HF-20 and HF-30 treatments. There was no significant difference in Paco2 or change in transpulmonary pressure between baseline and any oxygen delivery method. CONCLUSIONS AND CLINICAL RELEVANCE In this study, HFNC appeared to be a safe and effective method for oxygen delivery to sedated healthy dogs. Further studies are needed to evaluate use of HFNCs for oxygen administration to hypoxemic patients.

  15. High altitude genetic adaptation in Tibetans: no role of increased hemoglobin-oxygen affinity.

    Science.gov (United States)

    Tashi, Tsewang; Feng, Tang; Koul, Parvaiz; Amaru, Ricardo; Hussey, Dottie; Lorenzo, Felipe R; RiLi, Ge; Prchal, Josef T

    2014-01-01

    High altitude exerts selective evolutionary pressure primarily due to its hypoxic environment, resulting in multiple adaptive responses. High hemoglobin-oxygen affinity is postulated to be one such adaptive change, which has been reported in Sherpas of the Himalayas. Tibetans have lived on the Qinghai-Tibetan plateau for thousands of years and have developed unique phenotypes, such as protection from polycythemia which has been linked to PDH2 mutation, resulting in the downregulation of the HIF pathway. In order to see if Tibetans also developed high hemoglobin-oxygen affinity as a part of their genetic adaptation, we conducted this study assessing hemoglobin-oxygen affinity and their fetal hemoglobin levels in Tibetan subjects from 3 different altitudes. We found normal hemoglobin-oxygen affinity in all subjects, fetal hemoglobin levels were normal in all except one and no hemoglobin variants in any of the subjects. We conclude that increased hemoglobin-oxygen affinity or increased fetal hemoglobin are not adaptive phenotypes of the Tibetan highlanders. Published by Elsevier Inc.

  16. High energy electron-positron physics

    CERN Document Server

    Ali, Ahmed

    1988-01-01

    With the termination of the physics program at PETRA, and with the start of TRISTAN and the SLC and later LEP, an era of e+e- physics has come to an end and a new one begins. The field is changing from a field of few specialists, to becoming one of the mainstream efforts of the high energy community. It seems appropriate at this moment to summarize what has been learned over the past years, in a way most useful to any high energy physicists, in particular to newcomers in the e+e- field. This is the purpose of the book. This book should be used as a reference for future workers in the field of

  17. High energy physics at UC Riverside

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-01

    This report discusses progress made for the following two tasks: experimental high energy physics, Task A, and theoretical high energy physics, Task B. Task A1 covers hadron collider physics. Information for Task A1 includes: personnel/talks/publications; D0: proton-antiproton interactions at 2 TeV; SDC: proton-proton interactions at 40 TeV; computing facilities; equipment needs; and budget notes. The physics program of Task A2 has been the systematic study of leptons and hadrons. Information covered for Task A2 includes: personnel/talks/publications; OPAL at LEP; OPAL at LEP200; CMS at LHC; the RD5 experiment; LSND at LAMPF; and budget notes. The research activities of the Theory Group are briefly discussed and a list of completed or published papers for this period is given.

  18. High energy density redox flow device

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, Yet-Ming; Carter, Craig W.; Ho, Bryan Y.; Duduta, Mihai; Limthongkul, Pimpa

    2017-10-10

    Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

  19. New Prospects in High Energy Astrophysics

    Energy Technology Data Exchange (ETDEWEB)

    Blandford, Roger; /KIPAC, Menlo Park

    2011-11-15

    Recent discoveries using TeV, X-ray and radio telescopes as well as Ultra High Energy Cosmic Ray arrays are leading to new insights into longstanding puzzles in high energy astrophysics. Many of these insights come from combining observations throughout the electromagnetic and other spectra as well as evidence assembled from different types of source to propose general principles. Issues discussed in this general overview include methods of accelerating relativistic particles, and amplifying magnetic field, the dynamics of relativistic outflows and the nature of the prime movers that power them. Observational approaches to distinguishing hadronic, leptonic and electromagnetic outflows and emission mechanisms are discussed along with probes of the velocity field and the confinement mechanisms. Observations with GLAST promise to be very prescriptive for addressing these problems.

  20. Maximal Entanglement in High Energy Physics

    Directory of Open Access Journals (Sweden)

    Alba Cervera-Lierta, José I. Latorre, Juan Rojo, Luca Rottoli

    2017-11-01

    Full Text Available We analyze how maximal entanglement is generated at the fundamental level in QED by studying correlations between helicity states in tree-level scattering processes at high energy. We demonstrate that two mechanisms for the generation of maximal entanglement are at work: i $s$-channel processes where the virtual photon carries equal overlaps of the helicities of the final state particles, and ii the indistinguishable superposition between $t$- and $u$-channels. We then study whether requiring maximal entanglement constrains the coupling structure of QED and the weak interactions. In the case of photon-electron interactions unconstrained by gauge symmetry, we show how this requirement allows reproducing QED. For $Z$-mediated weak scattering, the maximal entanglement principle leads to non-trivial predictions for the value of the weak mixing angle $\\theta_W$. Our results are a first step towards understanding the connections between maximal entanglement and the fundamental symmetries of high-energy physics.

  1. High Energy Vibration for Gas Piping

    Science.gov (United States)

    Lee, Gary Y. H.; Chan, K. B.; Lee, Aylwin Y. S.; Jia, ShengXiang

    2017-07-01

    In September 2016, a gas compressor in offshore Sarawak has its rotor changed out. Prior to this change-out, pipe vibration study was carried-out by the project team to evaluate any potential high energy pipe vibration problems at the compressor’s existing relief valve downstream pipes due to process condition changes after rotor change out. This paper covers high frequency acoustic excitation (HFAE) vibration also known as acoustic induced vibration (AIV) study and discusses detailed methodologies as a companion to the Energy Institute Guidelines for the avoidance of vibration induced fatigue failure, which is a common industry practice to assess and mitigate for AIV induced fatigue failure. Such detailed theoretical studies can help to minimize or totally avoid physical pipe modification, leading to reduce offshore plant shutdown days to plant shutdowns only being required to accommodate gas compressor upgrades, reducing cost without compromising process safety.

  2. High-Temperature Thermoelectric Energy Conversion

    Science.gov (United States)

    Wood, C.

    1987-01-01

    Theory of thermoelectric energy conversion at high temperatures and status of research on conversion materials reviewed in report. Shows highest values of thermoelectric figure of merit, Z, found in semiconductor materials. Semiconductors keep wide choice of elements and compounds. Electrical properties tailored to particular application by impurity doping and control of stoichiometry. Report develops definition of Z useful for comparing materials and uses it to evaluate potentials of different classes of materialsmetals, semiconductors, and insulators.

  3. High-Energy Compton Scattering Light Sources

    CERN Document Server

    Hartemann, Fred V; Barty, C; Crane, John; Gibson, David J; Hartouni, E P; Tremaine, Aaron M

    2005-01-01

    No monochromatic, high-brightness, tunable light sources currently exist above 100 keV. Important applications that would benefit from such new hard x-ray sources include: nuclear resonance fluorescence spectroscopy, time-resolved positron annihilation spectroscopy, and MeV flash radiography. The peak brightness of Compton scattering light sources is derived for head-on collisions and found to scale with the electron beam brightness and the drive laser pulse energy. This gamma 2

  4. MASS SEPARATION OF HIGH ENERGY PARTICLES

    Science.gov (United States)

    Marshall, L.

    1962-09-25

    An apparatus and method are described for separating charged, high energy particles of equal momentum forming a beam where the particles differ slightly in masses. Magnetic lenses are utilized to focus the beam and maintain that condition while electrostatic fields located between magnetic lenses are utilized to cause transverse separation of the particles into two beams separated by a sufficient amount to permit an aperture to block one beam. (AEC)

  5. High energy neutrinos from the sun

    Science.gov (United States)

    Masip, Manuel

    2018-01-01

    The Sun is a main source of high energy neutrinos. These neutrinos appear as secondary particles after the Sun absorbs high-energy cosmic rays, that find there a low-density environment (much thinner than our atmosphere) where most secondary pions, kaons and muons can decay before they lose energy. The main uncertainty in a calculation of the solar neutrino flux is due to the effects of the magnetic fields on the absorption rate of charged cosmic rays. We use recent data from HAWC on the cosmic-ray shadow of the Sun to estimate this rate. We evaluate the solar neutrino flux and show that at 1 TeV it is over ten times larger than the atmospheric one at zenith θz =30∘ /150∘ . The flux that we obtain has a distinct spectrum and flavor composition: it is harder and richer in antineutrinos and tau/electron neutrinos than the atmospheric background. This solar flux could be detected in current and upcoming neutrino telescopes. KM3NeT, in particular, looks very promising: it will see the Sun high in the sky (the atmospheric flux is lower there than near the horizon) and expects a very good angular resolution (the Sun's radius is just 0.27°).

  6. Data Preservation in High Energy Physics

    CERN Document Server

    Kogler, Roman; Steder, Michael

    2011-01-01

    Data from high-energy physics experiments are collected with significant financial and human effort and are mostly unique. However, until recently no coherent strategy existed for data preservation and re-use, and many important and complex data sets have simply been lost. While the current focus is on the LHC at CERN, in the current period several important and unique experimental programs at other facilities are coming to an end, including those at HERA, b-factories and the Tevatron. To address this issue, an inter-experimental study group on HEP data preservation and long-term analysis (DPHEP) was convened at the end of 2008. The group now aims to publish a full and detailed review of the present status of data preservation in high energy physics. This contribution summarises the results of the DPHEP study group, describing the challenges of data preservation in high energy physics and the group's first conclusions and recommendations. The physics motivation for data preservation, generic computing and pre...

  7. Salinity-Gradient Energy Driven Microbial Electrosynthesis of Hydrogen Peroxide from Oxygen Reduction

    DEFF Research Database (Denmark)

    Li, Xiaohu; Zhang, Yifeng; Angelidaki, Irini

    2015-01-01

    Hydrogen peroxide (H2O2) is widely used in various chemical industries and environmental remediation. Recently, bioelectrochemical systems (BES) have gained increasing attention for synthesizing H2O2 with simultaneous wastewater treatment[1]. However, in order to get high-yield H2O2 requires...... additional electrical energy to power these BES or control the cathode potential. In this study, we develop an innovative BES called microbial reverse-electrodialysis electrolysis cell (MREC) to produce H2O2 in cathode. In the MREC(See Fig.1), the salinity-gradient energy between seawater and river water can...

  8. Embolism of high energy firearm projectile

    Directory of Open Access Journals (Sweden)

    Jaime Álvarez Soler

    2016-12-01

    Full Text Available The embolism of a projectile is very rare and out of the normal context, so the cor-oner in front of a wound projectile firearm must make a very judicious and careful analysis to recover the projectile and/or its fragments. This case presents evidence how modern military high-velocity weapons have a high kinetic energy which is transferred to body tissues, so including their fragments and parts of the projectile can cause serious injury and embolism, requiring a great effort scientific and in-terdisciplinary to give technical support to justice.

  9. EXTRACTOR FOR HIGH ENERGY CHARGED PARTICLES

    Science.gov (United States)

    Lambertson, G.R.

    1964-04-01

    A particle-extracting apparatus for use with a beam of high-energy charged particles such as travel in an evacuated chamber along a circular equilibrium axis is described. A magnetized target is impacted relatively against the beam whereby the beam particles are deflected from the beam by the magnetic induction in the target. To this end the target may be moved into the beam or the beam may coast into the target and achieve high angular particle deflection and slow extraction. A deflecting septum magnet may additionally be used for deflection at even sharper angles. (AEC)

  10. Quantum Phenomena in High Energy Density Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Murnane, Margaret [Univ. of Colorado, Boulder, CO (United States); Kapteyn, Henry [Univ. of Colorado, Boulder, CO (United States)

    2017-05-10

    The possibility of implementing efficient (phase matched) HHG upconversion of deep- UV lasers in multiply-ionized plasmas, with potentially unprecedented conversion efficiency is a fascinating prospect. HHG results from the extreme nonlinear response of matter to intense laser light:high harmonics are radiated as a result of a quantum coherent electron recollision process that occurs during laser field ionization of an atom. Under current support from this grant in work published in Science in 2015, we discovered a new regime of bright HHG in highly-ionized plasmas driven by intense UV lasers, that generates bright harmonics to photon energies >280eV

  11. Highly Compressed Ion Beams for High Energy Density Science

    CERN Document Server

    Friedman, Alex; Briggs, Richard J; Callahan, Debra; Caporaso, George; Celata, C M; Davidson, Ronald C; Faltens, Andy; Grant-Logan, B; Grisham, Larry; Grote, D P; Henestroza, Enrique; Kaganovich, Igor D; Lee, Edward; Lee, Richard; Leitner, Matthaeus; Nelson, Scott D; Olson, Craig; Penn, Gregory; Reginato, Lou; Renk, Tim; Rose, David; Sessler, Andrew M; Staples, John W; Tabak, Max; Thoma, Carsten H; Waldron, William; Welch, Dale; Wurtele, Jonathan; Yu, Simon

    2005-01-01

    The Heavy Ion Fusion Virtual National Laboratory (HIF-VNL) is developing the intense ion beams needed to drive matter to the High Energy Density (HED) regimes required for Inertial Fusion Energy (IFE) and other applications. An interim goal is a facility for Warm Dense Matter (WDM) studies, wherein a target is heated volumetrically without being shocked, so that well-defined states of matter at 1 to 10 eV are generated within a diagnosable region. In the approach we are pursuing, low to medium mass ions with energies just above the Bragg peak are directed onto thin target "foils," which may in fact be foams or "steel wool" with mean densities 1% to 100% of solid. This approach complements that being pursued at GSI, wherein high-energy ion beams deposit a small fraction of their energy in a cylindrical target. We present the requirements for warm dense matter experiments, and describe suitable accelerator concepts, including novel broadband traveling wave pulse-line, drift-tube linac, RF, and single-gap approa...

  12. A Gibbs Energy Minimization Approach for Modeling of Chemical Reactions in a Basic Oxygen Furnace

    Science.gov (United States)

    Kruskopf, Ari; Visuri, Ville-Valtteri

    2017-12-01

    In modern steelmaking, the decarburization of hot metal is converted into steel primarily in converter processes, such as the basic oxygen furnace. The objective of this work was to develop a new mathematical model for top blown steel converter, which accounts for the complex reaction equilibria in the impact zone, also known as the hot spot, as well as the associated mass and heat transport. An in-house computer code of the model has been developed in Matlab. The main assumption of the model is that all reactions take place in a specified reaction zone. The mass transfer between the reaction volume, bulk slag, and metal determine the reaction rates for the species. The thermodynamic equilibrium is calculated using the partitioning of Gibbs energy (PGE) method. The activity model for the liquid metal is the unified interaction parameter model and for the liquid slag the modified quasichemical model (MQM). The MQM was validated by calculating iso-activity lines for the liquid slag components. The PGE method together with the MQM was validated by calculating liquidus lines for solid components. The results were compared with measurements from literature. The full chemical reaction model was validated by comparing the metal and slag compositions to measurements from industrial scale converter. The predictions were found to be in good agreement with the measured values. Furthermore, the accuracy of the model was found to compare favorably with the models proposed in the literature. The real-time capability of the proposed model was confirmed in test calculations.

  13. A Gibbs Energy Minimization Approach for Modeling of Chemical Reactions in a Basic Oxygen Furnace

    Science.gov (United States)

    Kruskopf, Ari; Visuri, Ville-Valtteri

    2017-08-01

    In modern steelmaking, the decarburization of hot metal is converted into steel primarily in converter processes, such as the basic oxygen furnace. The objective of this work was to develop a new mathematical model for top blown steel converter, which accounts for the complex reaction equilibria in the impact zone, also known as the hot spot, as well as the associated mass and heat transport. An in-house computer code of the model has been developed in Matlab. The main assumption of the model is that all reactions take place in a specified reaction zone. The mass transfer between the reaction volume, bulk slag, and metal determine the reaction rates for the species. The thermodynamic equilibrium is calculated using the partitioning of Gibbs energy (PGE) method. The activity model for the liquid metal is the unified interaction parameter model and for the liquid slag the modified quasichemical model (MQM). The MQM was validated by calculating iso-activity lines for the liquid slag components. The PGE method together with the MQM was validated by calculating liquidus lines for solid components. The results were compared with measurements from literature. The full chemical reaction model was validated by comparing the metal and slag compositions to measurements from industrial scale converter. The predictions were found to be in good agreement with the measured values. Furthermore, the accuracy of the model was found to compare favorably with the models proposed in the literature. The real-time capability of the proposed model was confirmed in test calculations.

  14. The Effects of Hypobaric Hypoxia on Erythropoiesis, Maximal Oxygen Uptake and Energy Cost of Exercise Under Normoxia in Elite Biathletes

    Directory of Open Access Journals (Sweden)

    Milosz Czuba

    2014-12-01

    Full Text Available The aim of the present study was to evaluate the effects of 3 weeks altitude training according to the HiHiLo (live high-base train high-interval train low procedure as described by Chapman et al. (1998, on erythropoiesis, maximal oxygen uptake and energy cost of exercise under normoxia in elite biathletes. Fifteen male elite biathletes randomly divided into an experimental (H group (n = 7; age 27.1 ± 4.6 years; maximal oxygen uptake (VO2max 66.9 ± 3.3 ml·kg–1·min–1; body height (BH 1.81 ± 0.06 m; body mass (BM 73.1 ± 5.4kg, and a control (C group (n = 8; age 23.2 ± 0.9 years; VO2max 68.2 ± 4.1 ml·kg–1·min–1; BH 1.75 ± 0.03 m; BM 63.1 ± 1.5 kg took part in the study. The H group stayed for 3 weeks at an altitude of 2015 m and performed endurance training on skis four times per week at 3000 m. Additionally, the training protocol included three high-intensity interval sessions at an altitude of 1000 m. The C group followed the same training protocol with skirollers in normoxia at an altitude of 600 m. The HiHiLo protocol applied in our study did not change VO2max or maximal workload (WRmax significantly during the incremental treadmill test in group H. However, the energy cost for selected submaximal workloads in group H was significantly (p < 0.01 reduced compared to group C (-5.7%, -4.4%, -6% vs. -3.5%, -2.1%, -2.4%. Also a significant (p < 0.001 increase in serum EPO levels during the first two weeks of HiHiLo training at 2015 m was observed, associated with a significant (p < 0.05 increase in hemoglobin mass, number of erythrocytes, hematocrit value and percent of reticulocytes compared with initial values (by 6.4%, 5%, 4.6% and 16,6%, respectively. In group C, changes in these variables were not observed. These positive changes observed in our study led to a conclusion that the HiHiLo training method could improve endurance in normoxia, since most of the biathlon competitions are performed at submaximal intensities.

  15. Energy metabolism and the high-altitude environment.

    Science.gov (United States)

    Murray, Andrew J

    2016-01-01

    At high altitude the barometric pressure falls, challenging oxygen delivery to the tissues. Thus, whilst hypoxia is not the only physiological stress encountered at high altitude, low arterial P(O2) is a sustained feature, even after allowing adequate time for acclimatization. Cardiac and skeletal muscle energy metabolism is altered in subjects at, or returning from, high altitude. In the heart, energetic reserve falls, as indicated by lower phosphocreatine-to-ATP ratios. The underlying mechanism is unknown, but in the hypoxic rat heart fatty acid oxidation and respiratory capacity are decreased, whilst pyruvate oxidation is also lower after sustained hypoxic exposure. In skeletal muscle, there is not a consensus. With prolonged exposure to extreme high altitude (>5500 m) a loss of muscle mitochondrial density is seen, but this was not observed in a simulated ascent of Everest in hypobaric chambers. At more moderate high altitude, decreased respiratory capacity may occur without changes in mitochondrial volume density, and fat oxidation may be downregulated, although this is not seen in all studies. The underlying mechanisms, including the possible role of hypoxia-signalling pathways, remain to be resolved, particularly in light of confounding factors in the high-altitude environment. In high-altitude-adapted Tibetan natives, however, there is evidence of natural selection centred around the hypoxia-inducible factor pathway, and metabolic features in this population (e.g. low cardiac phosphocreatine-to-ATP ratios, increased cardiac glucose uptake and lower muscle mitochondrial densities) share similarities with those in acclimatized lowlanders, supporting a possible role for the hypoxia-inducible factor pathway in the metabolic response of cardiac and skeletal muscle energy metabolism to high altitude. © 2015 The Authors. Experimental Physiology © 2015 The Physiological Society.

  16. High Energy High Power Battery Exceeding PHEV40 Requirements

    Energy Technology Data Exchange (ETDEWEB)

    Rempel, Jane [TIAX LLC, Lexington, MA (United States)

    2016-03-31

    TIAX has developed long-life lithium-ion cells that can meet and exceed the energy and power targets (200Wh/kg and 800W/kg pulse power) set out by DOE for PHEV40 batteries. To achieve these targets, we selected and scaled-up a high capacity version of our proprietary high energy and high power CAM-7® cathode material. We paired the cathode with a blended anode containing Si-based anode material capable of delivering high capacity and long life. Furthermore, we optimized the anode blend composition, cathode and anode electrode design, and selected binder and electrolyte compositions to achieve not only the best performance, but also long life. By implementing CAM-7 with a Si-based blended anode, we built and tested prototype 18650 cells that delivered measured specific energy of 198Wh/kg total energy and 845W/kg at 10% SOC (projected to 220Wh/kg in state-of-the-art 18650 cell hardware and 250Wh/kg in 15Ah pouch cells). These program demonstration cells achieved 90% capacity retention after 500 cycles in on-going cycle life testing. Moreover, we also tested the baseline CAM-7/graphite system in 18650 cells showing that 70% capacity retention can be achieved after ~4000 cycles (20 months of on-going testing). Ultimately, by simultaneously meeting the PHEV40 power and energy targets and providing long life, we have developed a Li-ion battery system that is smaller, lighter, and less expensive than current state-of-the-art Li-ion batteries.

  17. Molecular dynamics simulations reveal highly permeable oxygen exit channels shared with water uptake channels in photosystem II.

    Science.gov (United States)

    Vassiliev, Serguei; Zaraiskaya, Tatiana; Bruce, Doug

    2013-10-01

    Photosystem II (PSII) catalyzes the oxidation of water in the conversion of light energy into chemical energy in photosynthesis. Water delivery and oxygen removal from the oxygen evolving complex (OEC), buried deep within PSII, are critical requirements to facilitate the reaction and minimize reactive oxygen damage. It has often been assumed that water and oxygen travel through separate channels within PSII, as demonstrated in cytochrome c oxidase. This study describes all-atom molecular dynamics simulations of PSII designed to investigate channels by fully characterizing the distribution and permeation of both water and oxygen. Interestingly, most channels found in PSII were permeable to both oxygen and water, however individual channels exhibited different energetic barriers for the two solutes. Several routes for oxygen diffusion within PSII with low energy permeation barriers were found, ensuring its fast removal from the OEC. In contrast, all routes for water showed significant energy barriers, corresponding to a much slower permeation rate for water through PSII. Two major factors were responsible for this selectivity: (1) hydrogen bonds between water and channel amino acids, and (2) steric restraints. Our results reveal the presence of a shared network of channels in PSII optimized to both facilitate the quick removal of oxygen and effectively restrict the water supply to the OEC to help stabilize and protect it from small water soluble inhibitors. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Theory Summary: Very High Energy Cosmic Rays

    Directory of Open Access Journals (Sweden)

    Sarkar Subir

    2013-06-01

    Full Text Available This is a summary of ISVHECRI 2012 from a theorist’s perspective. A hundred years after their discovery, there is renewed interest in very high energy cosmic raysand their interactions which can provide unique information on new physics well beyond the Standard Model if only we knew how to unambiguously decipher the experimental data. While the observational situation has improved dramatically on the past decade with regard to both improved statistics and better understood systematics, the long standing questions regarding the origin of cosmic rays remain only partially answered, while further questions have been raised by new data. A recent development discussed at this Symposium is the advent of forward physics data from several experiments at the LHC, which have broadly vindicated the air shower simulation Monte Carlos currently in use and reduced their uncertainties further. Nevertheless there is still a major extrapolation required to interpret the highest energy air showers observed which appear to be undergoing a puzzling change in their elemental composition, even casting doubt on whether the much vaunted GZK cutoff has indeedbeen observed. The situation is further compounded by the apparent disagreement between Auger and Telescope Array data. A crucial diagnostic will be provided by the detection of the accompanying ultra-high energy cosmic neutrinos — two intriguing events have recently been recorded by IceCube.

  19. Perspectives on future high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Samios, N.P.

    1996-12-31

    The author states two general ways in which one must proceed in an attempt to forecast the future of high energy physics. The first is to utilize the state of knowledge in the field and thereby provide theoretical and experimental guidance on future directions. The second approach is technical, namely, how well can one do in going to higher energies with present techniques or new accelerator principles. He concludes that the future strategy is straightforward. The present accelerator facilities must be upgraded and run to produce exciting and forefront research. At the same time, the theoretical tools should be sharpened both extrapolating from lower energies (100 GeV) to high (multi TeV) and vice versa. The US should be involved in the LHC, both in the accelerator and experimental areas. There should be an extensive R and D program on accelerators for a multi-TeV capability, emphasizing e{sup +}e{sup {minus}} and {mu}{sup +}{mu}{sup {minus}} colliders. Finally, the international cooperative activities should be strengthened and maintained.

  20. Generation of highly reactive oxygen species by co-adsorption of oxygen and water on metal-supported MgO(100) thinfilms

    CERN Document Server

    Song, Zhenjun

    2015-01-01

    The formation of highly reactive oxygen species (ROS) on metal oxide surfaces have attracted considerable interest due to their diverse applications. In this work, we have performed densi-ty-functional theory calculations to investigate the co-adsorption of oxygen and water on ul-trathin MgO(100) films deposited on Mo(100) substrate. We reveal that the molecular oxygen can be stepwise decomposed completely with the assistance of water. Consequently, a series of highly ROS including superoxide, hydroperoxide, hydroxyl and single oxygen adatom are formed on Mo(100) supported MgO(100) thinfilms. The reaction barriers accompanied by the generation of ROS are reported, and the influence of the thickness of MgO(100) films is also discussed. The most promising routes to produce these fascinating species provide valuable information to understand the importance of synergistic effect, namely the substrate, the co-adorbed species, and the film thickness, in multiphase catalyst design.

  1. Extreme Transients in the High Energy Universe

    Science.gov (United States)

    Kouveliotou, Chryssa

    2013-01-01

    The High Energy Universe is rich in diverse populations of objects spanning the entire cosmological (time)scale, from our own present-day Milky Way to the re-ionization epoch. Several of these are associated with extreme conditions irreproducible in laboratories on Earth. Their study thus sheds light on the behavior of matter under extreme conditions, such as super-strong magnetic fields (in excess of 10^14 G), high gravitational potentials (e.g., Super Massive Black Holes), very energetic collimated explosions resulting in relativistic jet flows (e.g., Gamma Ray Bursts, exceeding 10^53 ergs). In the last thirty years, my work has been mostly focused on two apparently different but potentially linked populations of such transients: magnetars (highly magnetized neutron stars) and Gamma Ray Bursts (strongly beamed emission from relativistic jets), two populations that constitute unique astrophysical laboratories, while also giving us the tools to probe matter conditions in the Universe to redshifts beyond z=10, when the first stars and galaxies were assembled. I did not make this journey alone I have either led or participated in several international collaborations studying these phenomena in multi-wavelength observations; solitary perfection is not sufficient anymore in the world of High Energy Astrophysics. I will describe this journey, present crucial observational breakthroughs, discuss key results and muse on the future of this field.

  2. High energy microlaser and compact MOPA transmitter

    Science.gov (United States)

    Brickeen, Brian K.; Bernot, Dave; Geathers, Eliot; Mosovsky, Joseph

    2011-06-01

    A compact micro-oscillator incorporating a dual-bounce, grazing incidence gain module with a folded resonator cavity is presented. The gain module, previously developed for Nd:YVO4, is embodied in highly doped ceramic Nd:YAG to generate improved Q-switch performance while maintaining localized pump absorption. The cavity design utilizes a doubly folded optics path around the gain crystal to increase the intra-cavity mode for a more optimum overlap with the pump light volume produced by standard lensed laser diode bars. A modified CS-package diode mount is developed to facilitate the reduced size of the oscillator without sacrificing the ability to use a high-energy, side-pumping arrangement. The oscillator is combined with a high gain, high energy extraction VHGM amplifier to generate a transmitter source on the order of 50 mJ. Cooling for both the oscillator and amplifier modules is provided via a conductive path through the base of the package. Both devices are mounted on opposite sides of a phase-change cooling reservoir to enable self-contained, burst-mode operation. Beam shaping of the oscillator output, in preparation for injection into the amplifier, is contained in a small cut-away path on the reservoir side.

  3. Extremely High Current, High-Brightness Energy Recovery Linac

    CERN Document Server

    Ben-Zvi, Ilan; Beavis, Dana; Blaskiewicz, Michael; Bluem, Hans; Brennan, Joseph M; Burger, Al; Burrill, Andrew; Calaga, Rama; Cameron, Peter; Chang, Xiangyun; Cole, Michael; Connolly, Roger; Delayen, Jean R; Favale, Anthony; Gassner, David M; Grimes, Jacob T; Hahn, Harald; Hershcovitch, Ady; Holmes, Douglas; Hseuh Hsiao Chaun; Johnson, Peter; Kayran, Dmitry; Kewisch, Jorg; Kneisel, Peter; Lambiase, Robert; Litvinenko, Vladimir N; McIntyre, Gary; Meng, Wuzheng; Nehring, Thomas; Nicoletti, Tony; Oerter, Brian; Pate, David; Phillips, Larry; Preble, Joseph P; Rank, Jim; Rao, Triveni; Rathke, John; Roser, Thomas; Russo, Thomas; Scaduto, Joseph; Schultheiss, Tom; Segalov, Zvi; Smith, Kevin T; Todd, Alan M M; Warren-Funk, L; Williams, Neville; Wu, Kuo-Chen; Yakimenko, Vitaly; Yip, Kin; Zaltsman, Alex; Zhao, Yongxiang

    2005-01-01

    Next generation ERL light-sources, high-energy electron coolers, high-power Free-Electron Lasers, powerful Compton X-ray sources and many other accelerators were made possible by the emerging technology of high-power, high-brightness electron beams. In order to get the anticipated performance level of ampere-class currents, many technological barriers are yet to be broken. BNL's Collider-Accelerator Department is pursuing some of these technologies for its electron cooling of RHIC application, as well as a possible future electron-hadron collider. We will describe work on CW, high-current and high-brightness electron beams. This will include a description of a superconducting, laser-photocathode RF gun and an accelerator cavity capable of producing low emittance (about 1 micron rms normalized) one nano-Coulomb bunches at currents of the order of one ampere average.

  4. High intensity aerobic interval training improves peak oxygen consumption in patients with metabolic syndrome: CAT

    Directory of Open Access Journals (Sweden)

    Alexis Espinoza Salinas

    2014-06-01

    Full Text Available Introduction A number of cardiovascular risk factors characterizes the metabolic syndrome: insulin resistance (IR, low HDL cholesterol and high triglycerides. The aforementioned risk factors lead to elevated levels of abdominal adipose tissue, resulting in oxygen consumption deficiency. Purpose To verify the validity and applicability of using high intensity interval training (HIIT in subjects with metabolic syndrome and to answer the following question: Can HIIT improve peak oxygen consumption? Method The systematic review "Effects of aerobic interval training on exercise capacity and metabolic risk factors in individuals with cardiometabolic disorders" was analyzed. Results Data suggests high intensity aerobic interval training increases peak oxygen consumption by a standardized mean difference of 3.60 mL/kg-1/min-1 (95% confidence interval, 0.28-4.91. Conclusion In spite of the methodological shortcomings of the primary studies included in the systematic review, we reasonably conclude that implementation of high intensity aerobic interval training in subjects with metabolic syndrome, leads to increases in peak oxygen consumption.

  5. Effect of oxygen supplementation in a hatchery at high altitude and ...

    African Journals Online (AJOL)

    total ventricle (TV) weight and the RV : TV ratio. The plasma T3 level ... The hypoxic conditions that occurred during the embryonic stage . which altered endogenous functions of prenatal chicks and affected several blood parameters, and oxygen supplementation at high altitude . improved chick quality. However, it did not ...

  6. High-concentration oxygen and surgical site infections in abdominal surgery: a meta-analysis.

    Science.gov (United States)

    Patel, Sunil V; Coughlin, Shaun C; Malthaner, Richard A

    2013-08-01

    There has been recent interest in using high-concentration oxygen to prevent surgical site infections (SSIs). Previous meta-analyses in this area have produced conflicting results. With the publication of 2 new randomized controlled trials (RCTs) that were not included in previous meta-analyses, an updated review is warranted. Our objective was to perform a meta-analysis on RCTs comparing high- and low- concentration oxygen in adults undergoing open abdominal surgery. We completed independent literature reviews using electronic databases, bibliographies and other sources of grey literature to identify relevant studies. We assessed the overall quality of evidence using grade guidelines. Statistical analysis was performed on pooled data from included studies. A priori subgroup analyses were planned to explain statistical and clinical heterogeneity. Overall, 6 studies involving a total of 2585 patients met the inclusion criteria. There was no evidence of a reduction in SSIs with high-concentration oxygen (risk ratio 0.77, 95% confidence interval 0.50-1.19, p = 0.24). We observed substantial heterogeneity among studies. There is moderate evidence that high-concentration oxygen does not reduce SSIs in adults undergoing open abdominal surgery.

  7. Burning of forest materials under late Paleozoic high atmospheric oxygen levels

    Science.gov (United States)

    Richard A., Jr. Wildman; Leo J. Hickey; Matthew B. Dickinson; Robert A. Berner; Jennifer M. Robinson; Michael Dietrich; Robert H. Essenhigh; Craig B. Wildman

    2004-01-01

    Theoretical models suggest that atmospheric oxygen reached concentrations as high as 35% O2 during the past 550 m.y. Previous burning experiments using strips of paper have challenged this idea, concluding that ancient wildfires would have decimated plant life if O2 significantly exceeded its present level of 21%. New...

  8. Grid Computing in High Energy Physics

    Science.gov (United States)

    Avery, Paul

    2004-09-01

    Over the next two decades, major high energy physics (HEP) experiments, particularly at the Large Hadron Collider, will face unprecedented challenges to achieving their scientific potential. These challenges arise primarily from the rapidly increasing size and complexity of HEP datasets that will be collected and the enormous computational, storage and networking resources that will be deployed by global collaborations in order to process, distribute and analyze them. Coupling such vast information technology resources to globally distributed collaborations of several thousand physicists requires extremely capable computing infrastructures supporting several key areas: (1) computing (providing sufficient computational and storage resources for all processing, simulation and analysis tasks undertaken by the collaborations); (2) networking (deploying high speed networks to transport data quickly between institutions around the world); (3) software (supporting simple and transparent access to data and software resources, regardless of location); (4) collaboration (providing tools that allow members full and fair access to all collaboration resources and enable distributed teams to work effectively, irrespective of location); and (5) education, training and outreach (providing resources and mechanisms for training students and for communicating important information to the public). It is believed that computing infrastructures based on Data Grids and optical networks can meet these challenges and can offer data intensive enterprises in high energy physics and elsewhere a comprehensive, scalable framework for collaboration and resource sharing. A number of Data Grid projects have been underway since 1999. Interestingly, the most exciting and far ranging of these projects are led by collaborations of high energy physicists, computer scientists and scientists from other disciplines in support of experiments with massive, near-term data needs. I review progress in this

  9. Experimental Facilities at the High Energy Frontier

    CERN Document Server

    Jenni, P.

    2016-01-01

    The main theme of the lectures covered the experimental work at hadron colliders, with a clear focus on the Large Hadron Collider (LHC) and on the roadmap that led finally to the discovery of the Higgs boson. The lectures were not a systematic course on machine and detector technologies, but rather tried to give a physics-motivated overview of many experimental aspects that were all relevant for making the discovery. The actual lectures covered a much broader scope than what is documented here in this write- up. The successful concepts for the experiments at the LHC have benefitted from the experience gained with previous generations of detectors at lower- energy machines. The lectures included also an outlook to the future experimental programme at the LHC, with its machine and experiments upgrades, as well as a short discussion of possible facilities at the high energy frontier beyond LHC.

  10. High energy neutrinos from the Fermi bubbles.

    Science.gov (United States)

    Lunardini, Cecilia; Razzaque, Soebur

    2012-06-01

    Recently the Fermi-LAT data have revealed two gamma-ray emitting bubble-shaped structures at the Galactic center. If the observed gamma rays have hadronic origin (collisions of accelerated protons), the bubbles must emit high energy neutrinos as well. This new, Galactic, neutrino flux should trace the gamma-ray emission in spectrum and spatial extent. Its highest energy part, above 20-50 TeV, is observable at a kilometer-scale detector in the northern hemisphere, such as the planned KM3NeT, while interesting constraints on it could be obtained by the IceCube Neutrino Observatory at the South Pole. The detection or exclusion of neutrinos from the Fermi bubbles will discriminate between hadronic and leptonic models, thus bringing unique information on the still mysterious origin of these objects and on the time scale of their formation.

  11. High Current Energy Recovery Linac at BNL

    CERN Document Server

    Litvinenko, Vladimir N; Ben-Zvi, Ilan; Blaskiewicz, Michael; Bluem, Hans; Brennan, Joseph M; Burger, Al; Burrill, Andrew; Calaga, Rama; Cameron, Peter; Chang, Xiangyun; Cole, Michael; Connolly, Roger; Delayen, Jean R; Favale, Anthony; Gassner, David M; Hahn, Harald; Hershcovitch, Ady; Holmes, Douglas; Hseuh Hsiao Chaun; Johnson, Peter; Kayran, Dmitry; Kewisch, Jorg; Lambiase, Robert; Mahler, George; McIntyre, Gary; Meng, Wuzheng; Nehring, Thomas; Nicoletti, Tony; Oerter, Brian; Pate, David; Phillips, Larry; Preble, Joseph P; Rank, Jim; Rao, Triveni; Rathke, John; Roser, Thomas; Russo, Thomas; Scaduto, Joseph; Schultheiss, Tom; Smith, Kevin T; Todd, Alan M M; Warren Funk, L; Williams, Neville; Wu, Kuo-Chen; Yakimenko, Vitaly; Yip, Kin; Zaltsman, Alex; Zhao, Yongxiang

    2004-01-01

    We present the design and the parameters of a small Energy Recovery Linac (ERL) facility, which is under construction at BNL. This R&D facility has goals to demonstrate CW operation of ERL with average beam current in the range of 0.1 - 1 ampere, combined with very high efficiency of energy recovery. The possibility for future up-grade to a two-pass ERL is being considered. The heart of the facility is a 5-cell 703.75 MHz super-conducting RF linac with HOM damping. Flexible lattice of ERL provides a test-bed for testing issues of transverse and longitudinal instabilities and diagnostics of intense CW e-beam. We present the status and plans for this facility.

  12. QCD and high-energy nuclear collisions

    CERN Multimedia

    CERN. Geneva

    2007-01-01

    Six years ago, Relativistic Heavy Ion Collider at Brookhaven started colliding heavy nuclei at record center-of-mass energies of up to 200 GeV/nucleon. Very soon, the Large Hadron Collider at CERN will push the energy of the ions to an astounding 5 TeV/nucleon. What can be learnt from the experiments at these machines? What do we know about the physics of super--dense matter already? I will argue that heavy ion accelerators bring us to the new frontiers of physical knowledge by creating strong color fields and very high densities of partons, at which qualitatively new phenomena emerge. I will also discuss the cross-disciplinary implications for cosmology, astrophysics, and connections to condensed matter physics.

  13. High-energy neutrinos from AGN

    Energy Technology Data Exchange (ETDEWEB)

    Toschke, Marius [Ruhr-Universitaet Bochum (Germany); TU Dortmund (Germany); Becker Tjus, Julia [Ruhr-Universitaet Bochum (Germany); Rhode, Wolfgang [TU Dortmund (Germany)

    2016-07-01

    In the outer space there are galactic and extragalactic sources like gamma-ray bursts (GRB), active galactic nuclei (AGN), supernovae or other phenomena which produce high-energy neutrinos. In contrast to supernovae, GRBs and AGN are supposed to generate neutrinos at the highest energies. Neutrinos have a tiny cross section as they mainly suffer from the weak interaction. Therefore, they are useful messenger particles providing information about the direction of the source. With observations of the gamma flux from galactic and extragalactic sources, it is possible to make predictions for the neutrino flux. We suppose that neutrinos are predominantly generated by inelastic proton-proton interactions and derive the possible galactic and extragalactic sources. In this talk, first results are presented.

  14. High Current Energy Recovery Linac at BNL

    Energy Technology Data Exchange (ETDEWEB)

    Vladimir N. Litvinenko; Donald Barton; D. Beavis; Ilan Ben-Zvi; Michael Blaskiewicz; J.M. Brennan; A. Burrill; R. Calaga; P. Cameron; X. Chang; Roger Connolly; D. Gassner; H. Hahn; A. Hershcovitch; H.C. Hseuh; P. Johnson; D. Kayran; J. Kewisch; R. Lambiase; G. McIntyre; W. Meng; T. C. Nehring; A. Nicoletti; D. Pate; J. Rank; T. Roser; T. Russo; J. Scaduto; K. Smith; T. Srinivasan-Rao; N. Williams; K.-C. Wu; Vitaly Yakimenko; K. Yip; A. Zaltsman; Y. Zhao; H. Bluem; A. Burger; Mike Cole; A. Favale; D. Holmes; John Rathke; Tom Schultheiss; A. Todd; J. Delayen; W. Funk; L. Phillips; Joe Preble

    2004-08-01

    We present the design, the parameters of a small test Energy Recovery Linac (ERL) facility, which is under construction at Collider-Accelerator Department, BNL. This R&D facility has goals to demonstrate CW operation of ERL with average beam current in the range of 0.1 - 1 ampere, combined with very high efficiency of energy recovery. A possibility for future up-grade to a two-pass ERL is considered. The heart of the facility is a 5-cell 700 MHz super-conducting RF linac with HOM damping. Flexible lattice of ERL provides a test-bed for testing issues of transverse and longitudinal instabilities and diagnostics of intense CW e-beam. ERL is also perfectly suited for a far-IR FEL. We present the status and our plans for construction and commissioning of this facility.

  15. Anaesthesia in a patient with subarachanoidal haemorrhage and high oxygen affinity haemoglobinopathy (HB york: case report

    Directory of Open Access Journals (Sweden)

    Monaca Enrico

    2012-08-01

    Full Text Available Abstract Background Approximately 90 haemoglobinopathies have been identified that result in abnormally high oxygen affinity. One of these is haemoglobinopathy York (HbY, first described in 1976. HbY causes an extreme leftward shift of the oxygen dissociation curve with the P50 value changing to 12.5 - 15.5 mmHg (normal value 26.7 mmHg, indicating that approximately half of the haemoglobin is not available as oxygen carrier. Patients with haemoglobinopathies with increased oxygen affinity could suffer from the risk developing ischaemic complications due to a lack of functional oxygen carriers. This is, to best of our knowledge, the first case report on a patient with HbY published in connection with anesthesia. Case Presentation A 42-year-old female with a severe headache and Glasgow coma scale (GCS of 15 was admitted to the neurosurgical intensive care unit with a ruptured, right sided ICA aneurysm with consecutive subarachnoid haemorrhage [Fisher III, World Federation of Neurosurgical Societies (WFNS I]. The medical history of the patient included an erythrocytosis (Hb 17.5 g/dl on the base of a high-oxygen-affinity haemoglobinopathy, called Hb York (HbY. With no time available to take special preoperative precautions, rapid blood loss occurred during the first attempt to clip the aneurysm. General transfusion procedures, according to the guidelines based on haemoglobin and haematocrit values, could not be applied due to the uncertainty in the oxygen carrier reduction. To maintain tissue oxygen supply, clinical indicators of ischaemia were instead utilized to gauge the appropriate required blood products, crystalloids and colloids replacements. Despite this, the patient survived the neurosurgical intervention without any neurological deficit. Conclusions Family members of patients with HbY (and other haemoglobinopathies with increased oxygen affinity should undergo clinical assessment, particularly if they are polycythaemic. If the diagnosis

  16. Oxygen uptake kinetics and energy system's contribution around maximal lactate steady state swimming intensity.

    Science.gov (United States)

    Pelarigo, Jailton Gregório; Machado, Leandro; Fernandes, Ricardo Jorge; Greco, Camila Coelho; Vilas-Boas, João Paulo

    2017-01-01

    The purpose of this study was to examine the oxygen uptake ([Formula: see text]) kinetics and the energy systems' contribution at 97.5, 100 and 102.5% of the maximal lactate steady state (MLSS) swimming intensity. Ten elite female swimmers performed three-to-five 30 min submaximal constant swimming bouts at imposed paces for the determination of the swimming velocity (v) at 100%MLSS based on a 7 x 200 m intermittent incremental protocol until voluntary exhaustion to find the v associated at the individual anaerobic threshold. [Formula: see text] kinetics (cardiodynamic, primary and slow component phases) and the aerobic and anaerobic energy contributions were assessed during the continuous exercises, which the former was studied for the beginning and second phase of exercise. Subjects showed similar time delay (TD) (mean = 11.5-14.3 s) and time constant (τp) (mean = 13.8-16.3 s) as a function of v, but reduced amplitude of the primary component for 97.5% (35.7 ± 7.3 mL.kg.min-1) compared to 100 and 102.5%MLSS (41.0 ± 7.0 and 41.3 ± 5.4 mL.kg.min-1, respectively), and τp decreased (mean = 9.6-10.8 s) during the second phase of exercise. Despite the slow component did not occur for all swimmers at all swim intensities, when observed it tended to increase as a function of v. Moreover, the total energy contribution was almost exclusively aerobic (98-99%) at 97.5, 100 and 102.5%MLSS. We suggest that well-trained endurance swimmers with a fast TD and τp values may be able to adjust faster the physiological requirements to minimize the amplitude of the slow component appearance, parameter associated with the fatigue delay and increase in exhaustion time during performance, however, these fast adjustments were not able to control the progressive fatigue occurred slightly above MLSS, and most of swimmers reached exhaustion before 30min swam.

  17. Modelling the link amongst fine-pore diffuser fouling, oxygen transfer efficiency, and aeration energy intensity.

    Science.gov (United States)

    Garrido-Baserba, Manel; Sobhani, Reza; Asvapathanagul, Pitiporn; McCarthy, Graham W; Olson, Betty H; Odize, Victory; Al-Omari, Ahmed; Murthy, Sudhir; Nifong, Andrea; Godwin, Johnnie; Bott, Charles B; Stenstrom, Michael K; Shaw, Andrew R; Rosso, Diego

    2017-03-15

    This research systematically studied the behavior of aeration diffuser efficiency over time, and its relation to the energy usage per diffuser. Twelve diffusers were selected for a one year fouling study. Comprehensive aeration efficiency projections were carried out in two WRRFs with different influent rates, and the influence of operating conditions on aeration diffusers' performance was demonstrated. This study showed that the initial energy use, during the first year of operation, of those aeration diffusers located in high rate systems (with solids retention time - SRT-less than 2 days) increased more than 20% in comparison to the conventional systems (2 > SRT). Diffusers operating for three years in conventional systems presented the same fouling characteristics as those deployed in high rate processes for less than 15 months. A new procedure was developed to accurately project energy consumption on aeration diffusers; including the impacts of operation conditions, such SRT and organic loading rate, on specific aeration diffusers materials (i.e. silicone, polyurethane, EPDM, ceramic). Furthermore, it considers the microbial colonization dynamics, which successfully correlated with the increase of energy consumption (r 2 :0.82 ± 7). The presented energy model projected the energy costs and the potential savings for the diffusers after three years in operation in different operating conditions. Whereas the most efficient diffusers provided potential costs spanning from 4900 USD/Month for a small plant (20 MGD, or 74,500 m 3 /d) up to 24,500 USD/Month for a large plant (100 MGD, or 375,000 m 3 /d), other diffusers presenting less efficiency provided spans from 18,000USD/Month for a small plant to 90,000 USD/Month for large plants. The aim of this methodology is to help utilities gain more insight into process mechanisms and design better energy efficiency strategies at existing facilities to reduce energy consumption. Copyright © 2016 Elsevier Ltd. All

  18. University of Oklahoma - High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Skubic, Patrick L. [University of Oklahoma

    2013-07-31

    The High Energy Physics program at the University of Oklahoma, Pat Skubic, Principal Investigator, is attempting to understand nature at the deepest level using the most advanced experimental and theoretical tools. The four experimental faculty, Brad Abbott, Phil Gutierrez, Pat Skubic, and Mike Strauss, together with post-doctoral associates and graduate students, are finishing their work as part of the D0 collaboration at Fermilab, and increasingly focusing their investigations at the Large Hadron Collidor (LHC) as part of the ATLAS Collaboration. Work at the LHC has become even more exciting with the recent discovery by ATLAS and the other collaboration, CMS, of the long-sought Higgs boson, which plays a key role in generating masses for the elementary constituents of matter. Work of the OUHEP group has been in the three areas of hardware, software, and analysis. Now that the Higgs boson has been discovered, completing the Standard Model of fundamental physics, new efforts will focus on finding hints of physics beyond the standard model, such as supersymmetry. The OUHEP theory group (Kim Milton, PI) also consists of four faculty members, Howie Baer, Chung Kao, Kim Milton, and Yun Wang, and associated students and postdocs. They are involved in understanding fundamental issues in formulating theories of the microworld, and in proposing models that carry us past the Standard Model, which is an incomplete description of nature. They therefore work in close concert with their experimental colleagues. One also can study fundamental physics by looking at the large scale structure of the universe; in particular the ``dark energy'' that seems to be causing the universe to expand at an accelerating rate, effectively makes up about 3/4 of the energy in the universe, and yet is totally unidentified. Dark energy and dark matter, which together account for nearly all of the energy in the universe, are an important probe of fundamental physics at the very shortest

  19. A highly accurate method for determination of dissolved oxygen: gravimetric Winkler method.

    Science.gov (United States)

    Helm, Irja; Jalukse, Lauri; Leito, Ivo

    2012-09-05

    A high-accuracy Winkler titration method has been developed for determination of dissolved oxygen concentration. Careful analysis of uncertainty sources relevant to the Winkler method was carried out and the method was optimized for minimizing all uncertainty sources as far as practical. The most important improvements were: gravimetric measurement of all solutions, pre-titration to minimize the effect of iodine volatilization, accurate amperometric end point detection and careful accounting for dissolved oxygen in the reagents. As a result, the developed method is possibly the most accurate method of determination of dissolved oxygen available. Depending on measurement conditions and on the dissolved oxygen concentration the combined standard uncertainties of the method are in the range of 0.012-0.018 mg dm(-3) corresponding to the k=2 expanded uncertainty in the range of 0.023-0.035 mg dm(-3) (0.27-0.38%, relative). This development enables more accurate calibration of electrochemical and optical dissolved oxygen sensors for routine analysis than has been possible before. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. High temperature thermoelectric properties of strontium titanate thin films with oxygen vacancy and niobium doping

    KAUST Repository

    Sarath Kumar, S. R.

    2013-08-14

    We report the evolution of high temperature thermoelectric properties of SrTiO3 thin films doped with Nb and oxygen vacancies. Structure-property relations in this important thermoelectric oxide are elucidated and the variation of transport properties with dopant concentrations is discussed. Oxygen vacancies are incorporated during growth or annealing in Ar/H2 above 800 K. An increase in lattice constant due to the inclusion of Nb and oxygen vacancies is found to result in an increase in carrier density and electrical conductivity with simultaneous decrease in carrier effective mass and Seebeck coefficient. The lattice thermal conductivity at 300 K is found to be 2.22 W m-1 K-1, and the estimated figure of merit is 0.29 at 1000 K. © 2013 American Chemical Society.

  1. Tibiofibula Transposition in High-Energy Fractures

    Directory of Open Access Journals (Sweden)

    Peter R. Loughenbury

    2016-01-01

    Full Text Available We report two cases of failed attempts at closed reduction of high-energy tibial fractures with an associated fibula fracture. The first case was a 39-year-old male involved in high-speed motorbike collision, while the second was a 14-year-old male who injured his leg following a fall of three metres. Emergency medical services at the scenes of the accidents reported a 90-degree valgus deformity of the injured limb and both limbs were realigned on scene and stabilized. Adequate alignment of the tibia could not be achieved by manipulation under sedation or anaesthesia. Open reduction and exposure of the fracture sites revealed that the distal fibula fragment was “transposed” and entrapped in the medulla of the proximal tibial fragment. Reduction required simulation of the mechanism of injury in order to disengage the fragments and allow reduction. Tibiofibula transposition is a rare complication of high-energy lower limb fractures which has not previously been reported and may prevent adequate closed reduction. Impaction of the distal fibula within the tibial medulla occurs as the limb is realigned by paramedic staff before transfer to hospital. We recommend that when this complication is identified the patient is transferred to the operating room for open reduction and stabilization of the fracture.

  2. Conductor of high electrical current at high temperature in oxygen and liquid metal environment

    Science.gov (United States)

    Powell, IV, Adam Clayton; Pati, Soobhankar; Derezinski, Stephen Joseph; Lau, Garrett; Pal, Uday B.; Guan, Xiaofei; Gopalan, Srikanth

    2016-01-12

    In one aspect, the present invention is directed to apparatuses for and methods of conducting electrical current in an oxygen and liquid metal environment. In another aspect, the invention relates to methods for production of metals from their oxides comprising providing a cathode in electrical contact with a molten electrolyte, providing a liquid metal anode separated from the cathode and the molten electrolyte by a solid oxygen ion conducting membrane, providing a current collector at the anode, and establishing a potential between the cathode and the anode.

  3. Effects of anesthetic agents on brain blood oxygenation level revealed with ultra-high field MRI.

    Directory of Open Access Journals (Sweden)

    Luisa Ciobanu

    Full Text Available During general anesthesia it is crucial to control systemic hemodynamics and oxygenation levels. However, anesthetic agents can affect cerebral hemodynamics and metabolism in a drug-dependent manner, while systemic hemodynamics is stable. Brain-wide monitoring of this effect remains highly challenging. Because T(2*-weighted imaging at ultra-high magnetic field strengths benefits from a dramatic increase in contrast to noise ratio, we hypothesized that it could monitor anesthesia effects on brain blood oxygenation. We scanned rat brains at 7T and 17.2T under general anesthesia using different anesthetics (isoflurane, ketamine-xylazine, medetomidine. We showed that the brain/vessels contrast in T(2*-weighted images at 17.2T varied directly according to the applied pharmacological anesthetic agent, a phenomenon that was visible, but to a much smaller extent at 7T. This variation is in agreement with the mechanism of action of these agents. These data demonstrate that preclinical ultra-high field MRI can monitor the effects of a given drug on brain blood oxygenation level in the absence of systemic blood oxygenation changes and of any neural stimulation.

  4. UNIVERSITY OF ARIZONA HIGH ENERGY PHYSICS PROGRAM

    Energy Technology Data Exchange (ETDEWEB)

    Rutherfoord, John P. [University of Arizona; Johns, Kenneth A. [University of Arizona; Shupe, Michael A. [University of Arizona; Cheu, Elliott C. [University of Arizona; Varnes, Erich W. [University of Arizona; Dienes, Keith [University of Arizona; Su, Shufang [University of Arizona; Toussaint, William Doug [University of Arizona; Sarcevic, Ina [University of Arizona

    2013-07-29

    The High Energy Physics Group at the University of Arizona has conducted forefront research in elementary particle physics. Our theorists have developed new ideas in lattice QCD, SUSY phenomenology, string theory phenomenology, extra spatial dimensions, dark matter, and neutrino astrophysics. The experimentalists produced significant physics results on the ATLAS experiment at CERN's Large Hadron Collider and on the D0 experiment at the Fermilab Tevatron. In addition, the experimentalists were leaders in detector development and construction, and on service roles in these experiments.

  5. Data Preservation in High Energy Physics

    CERN Document Server

    Mount, Richard; Le Diberder, Francois; Dubois-Felsmann, Gregory; Neal, Homer; Bellis, Matt; Boehnlein, Amber; Votava, Margaret; White, Vicky; Wolbers, Stephen; Konigsberg, Jacobo; Roser, Robert; Snider, Rick; Lucchesi, Donatella; Denisov, Dmitri; Soldner-Rembold, Stefan; Li, Qizhong; Varnes, Erich; Jonckheere, Alan; Gasthuber, Martin; Gülzow, Volker; Kemp, Yves; Ozerov, Dmitri; Diaconu, Cristinel; South, David; Lobodzinski, Bogdan; Olsson, Jan; Haas, Tobias; Wrona, Krzysztof; Szuba, Janusz; Schnell, Gunar; Sasaki, Takashi; Katayama, Nobu; Hernandez, Fabio; Mele, Salvatore; Holzner, Andre; Hemmer, Frederic; Schroeder, Matthias; Barring, Olof; Brun, Rene; Maggi, Marcello; Igo-Kemenes, Peter; Van Wezel, Jos; Heiss, Andreas; Chen, Gang; Wang, Yifang; Asner, David; Riley, Daniel; Corney, David; Gordon, John

    2009-01-01

    Data from high-energy physics (HEP) experiments are collected with significant financial and human effort and are mostly unique. At the same time, HEP has no coherent strategy for data preservation and re-use. An inter-experimental Study Group on HEP data preservation and long-term analysis was convened at the end of 2008 and held two workshops, at DESY (January 2009) and SLAC (May 2009). This document is an intermediate report to the International Committee for Future Accelerators (ICFA) of the reflections of this Study Group.

  6. Weak interactions at high energies. [Lectures, review

    Energy Technology Data Exchange (ETDEWEB)

    Ellis, J.

    1978-08-01

    Review lectures are presented on the phenomenological implications of the modern spontaneously broken gauge theories of the weak and electromagnetic interactions, and some observations are made about which high energy experiments probe what aspects of gauge theories. Basic quantum chromodynamics phenomenology is covered including momentum dependent effective quark distributions, the transverse momentum cutoff, search for gluons as sources of hadron jets, the status and prospects for the spectroscopy of fundamental fermions and how fermions may be used to probe aspects of the weak and electromagnetic gauge theory, studies of intermediate vector bosons, and miscellaneous possibilities suggested by gauge theories from the Higgs bosons to speculations about proton decay. 187 references. (JFP)

  7. Advanced Analysis Methods in High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Pushpalatha C. Bhat

    2001-10-03

    During the coming decade, high energy physics experiments at the Fermilab Tevatron and around the globe will use very sophisticated equipment to record unprecedented amounts of data in the hope of making major discoveries that may unravel some of Nature's deepest mysteries. The discovery of the Higgs boson and signals of new physics may be around the corner. The use of advanced analysis techniques will be crucial in achieving these goals. The author discusses some of the novel methods of analysis that could prove to be particularly valuable for finding evidence of any new physics, for improving precision measurements and for exploring parameter spaces of theoretical models.

  8. Reclustering of high energy physics data

    CERN Document Server

    Schaller, M

    1999-01-01

    The coming high energy physics experiments will store Petabytes of data into object databases. Analysis jobs will frequently traverse collections containing millions of stored objects. Clustering is one of the most effective means $9 to enhance the performance of these applications. The paper presents a reclustering algorithm for independent objects contained in multiple possibly overlapping collections on secondary storage. The algorithm decomposes the stored $9 objects into a number of independent chunks and then maps these chunks to a traveling salesman problem. Under a set of realistic assumptions, the number of disk seeks is reduced almost to the theoretical minimum. Experimental results $9 obtained from a prototype are included. (17 refs).

  9. Photomask specifications for high energy physics detectors

    CERN Document Server

    Pindo, M

    2002-01-01

    Planar technologies used for radiation detector fabrication imply an extensive use of photomasks whose characteristics are critical in determining final detector performance. Compatibly with their manufacturing process, photomasks must satisfy the application-specific requirements dictated both by wafer manufacturers and detector final users. The design and realization of microstrip and pixel detectors, widely used in high energy physics experiments, ask for intensive scientific effort, advanced technology and important economical investments. Photomask specification definition is one of the fundamental steps to optimize detector fabrication processes and fulfill experimental requirements at the most appropriate cost.

  10. Predictions of High Energy Experimental Results

    Directory of Open Access Journals (Sweden)

    Comay E.

    2010-10-01

    Full Text Available Eight predictions of high energy experimental results are presented. The predictions contain the $Sigma ^+$ charge radius and results of two kinds of experiments using energetic pionic beams. In addition, predictions of the failure to find the following objects are presented: glueballs, pentaquarks, Strange Quark Matter, magnetic monopoles searched by their direct interaction with charges and the Higgs boson. The first seven predictions rely on the Regular Charge-Monopole Theory and the last one relies on mathematical inconsistencies of the Higgs Lagrangian density.

  11. Particle identification methods in High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Va' Vra, J.

    2000-01-27

    This paper deals with two major particle identification methods: dE/dx and Cherenkov detection. In the first method, the authors systematically compare existing dE/dx data with various predictions available in the literature, such as the Particle Data group recommendation, and judge the overall consistency. To my knowledge, such comparison was not done yet in a published form for the gaseous detectors used in High-Energy physics. As far as the second method, there are two major Cherenkov light detection techniques: the threshold and the Ring imaging methods. The authors discuss the recent trend in these techniques.

  12. [Experimental and theoretical high energy physics program

    Energy Technology Data Exchange (ETDEWEB)

    Finley, J.; Gaidos, J.A.; Loeffler, F.J.; McIlwain, R.L.; Miller, D.H.; Palfrey, T.R.; Shibata, E.I.; Shipsey, I.P.

    1993-04-01

    Experimental and theoretical high-energy physics research at Purdue is summarized in a number of reports. Subjects treated include the following: the CLEO experiment for the study of heavy flavor physics; gas microstrip detectors; particle astrophysics; affine Kac{endash}Moody algebra; nonperturbative mass bounds on scalar and fermion systems due to triviality and vacuum stability constraints; resonance neutrino oscillations; e{sup +}e{sup {minus}} collisions at CERN; {bar p}{endash}p collisions at FNAL; accelerator physics at Fermilab; development work for the SDC detector at SSC; TOPAZ; D-zero physics; physics beyond the standard model; and the Collider Detector at Fermilab. (RWR)

  13. GEM applications outside high energy physics

    CERN Document Server

    Duarte Pinto, Serge

    2013-01-01

    From its invention in 1997, the Gas Electron Multiplier has been applied in nuclear and high energy physics experiments. Over time however, other applications have also exploited the favorable properties of GEMs. The use of GEMs in these applications will be explained in principle and practice. This paper reviews applications in research, beam instrumentation and homeland security. The detectors described measure neutral radiations such as photons, x-rays, gamma rays and neutrons, as well as all kinds of charged radiation. This paper provides an overview of the still expanding range of possibilities of this versatile detector concept.

  14. Computing support for High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Avery, P.; Yelton, J. [Univ. of Florida, Gainesville, FL (United States)

    1996-12-01

    This computing proposal (Task S) is submitted separately but in support of the High Energy Experiment (CLEO, Fermilab, CMS) and Theory tasks. The authors have built a very strong computing base at Florida over the past 8 years. In fact, computing has been one of the main contributions to their experimental collaborations, involving not just computing capacity for running Monte Carlos and data reduction, but participation in many computing initiatives, industrial partnerships, computing committees and collaborations. These facts justify the submission of a separate computing proposal.

  15. Predicting Induced Radioactivity at High Energy Accelerators

    Energy Technology Data Exchange (ETDEWEB)

    Fasso, Alberto

    1999-08-27

    Radioactive nuclides are produced at high-energy electron accelerators by different kinds of particle interactions with accelerator components and shielding structures. Radioactivity can also be induced in air, cooling fluids, soil and groundwater. The physical reactions involved include spallations due to the hadronic component of electromagnetic showers, photonuclear reactions by intermediate energy photons and low-energy neutron capture. Although the amount of induced radioactivity is less important than that of proton accelerators by about two orders of magnitude, reliable methods to predict induced radioactivity distributions are essential in order to assess the environmental impact of a facility and to plan its decommissioning. Conventional techniques used so far are reviewed, and a new integrated approach is presented, based on an extension of methods used at proton accelerators and on the unique capability of the FLUKA Monte Carlo code to handle the whole joint electromagnetic and hadronic cascade, scoring residual nuclei produced by all relevant particles. The radiation aspects related to the operation of superconducting RF cavities are also addressed.

  16. High-flow oxygen for treatment of cluster headache: a randomized trial.

    Science.gov (United States)

    Cohen, Anna S; Burns, Brian; Goadsby, Peter J

    2009-12-09

    Cluster headache is an excruciatingly painful primary headache syndrome, with attacks of unilateral pain and cranial autonomic symptoms. The current licensed treatment for acute attacks is subcutaneous sumatriptan. To ascertain whether high-flow inhaled oxygen was superior to placebo in the acute treatment of cluster headache. A double-blind, randomized, placebo-controlled crossover trial of 109 adults (aged 18-70 years) with cluster headache as defined by the International Headache Society. Patients treated 4 headache episodes with high-flow inhaled oxygen or placebo, alternately. Patients were randomized to the order in which they received the active treatment or placebo. Patients were recruited and followed up between 2002 and 2007 at the National Hospital for Neurology and Neurosurgery, London, England. Inhaled oxygen at 100%, 12 L/min, delivered by face mask, for 15 minutes at the start of an attack of cluster headache or high-flow air placebo delivered alternately for 4 attacks. The primary end point was to render the patient pain free, or in the absence of a diary to have adequate relief, at 15 minutes. Secondary end points included rendering the patient pain free at 30 minutes, reduction in pain up to 60 minutes, need for rescue medication 15 minutes after treatment, overall response to the treatment and overall functional disability, and effect on associated symptoms. Fifty-seven patients with episodic cluster headache and 19 with chronic cluster headache were available for the analysis. For the primary end point the difference between oxygen, 78% (95% confidence interval, 71%-85% for 150 attacks) and air, 20% (95% confidence interval, 14%-26%; for 148 attacks) was significant (Wald test, chi(5)(2) = 66.7, P Treatment of patients with cluster headache at symptom onset using inhaled high-flow oxygen compared with placebo was more likely to result in being pain-free at 15 minutes. isrctn.org Identifier: ISRCTN94092997.

  17. High altitude genetic adaptation in Tibetans: no role of increased hemoglobin-oxygen affinity

    OpenAIRE

    Tashi, Tsewang; Feng, Tang; Koul, Parvaiz; Amaru, Ricardo; Hussey, Dottie; Lorenzo, Felipe R.; Rili, Ge; Prchal, Josef T.

    2014-01-01

    High altitude exerts selective evolutionary pressure primarily due to its hypoxic environment, resulting in multiple adaptive responses. High hemoglobin-oxygen affinity is postulated to be one such adaptive change, which has been reported in Sherpas of the Himalayas. Tibetans have lived on the Qinghai-Tibetan plateau for thousands of years and have developed unique phenotypes, such as protection from polycythemia which has been linked to PDH2 mutation, resulting in downregulation of HIF pathw...

  18. High intensity aerobic interval training improves peak oxygen consumption in patients with metabolic syndrome: CAT

    OpenAIRE

    Alexis Espinoza Salinas; Raúl Aguilera Eguía; Cristian Cofre Bolados; Edson Zafra Santos; Gustavo Pavéz Von Martens

    2014-01-01

    Introduction A number of cardiovascular risk factors characterizes the metabolic syndrome: insulin resistance (IR), low HDL cholesterol and high triglycerides. The aforementioned risk factors lead to elevated levels of abdominal adipose tissue, resulting in oxygen consumption deficiency. Purpose To verify the validity and applicability of using high intensity interval training (HIIT) in subjects with metabolic syndrome and to answer the following question: Can HIIT improve peak oxyg...

  19. Grid computing in high energy physics

    CERN Document Server

    Avery, P

    2004-01-01

    Over the next two decades, major high energy physics (HEP) experiments, particularly at the Large Hadron Collider, will face unprecedented challenges to achieving their scientific potential. These challenges arise primarily from the rapidly increasing size and complexity of HEP datasets that will be collected and the enormous computational, storage and networking resources that will be deployed by global collaborations in order to process, distribute and analyze them. Coupling such vast information technology resources to globally distributed collaborations of several thousand physicists requires extremely capable computing infrastructures supporting several key areas: (1) computing (providing sufficient computational and storage resources for all processing, simulation and analysis tasks undertaken by the collaborations); (2) networking (deploying high speed networks to transport data quickly between institutions around the world); (3) software (supporting simple and transparent access to data and software r...

  20. High energy gravitational scattering: a numerical study

    CERN Document Server

    Marchesini, Giuseppe

    2008-01-01

    The S-matrix in gravitational high energy scattering is computed from the region of large impact parameters b down to the regime where classical gravitational collapse is expected to occur. By solving the equation of an effective action introduced by Amati, Ciafaloni and Veneziano we find that the perturbative expansion around the leading eikonal result diverges at a critical value signalling the onset of a new regime. We then discuss the main features of our explicitly unitary S-matrix down to the Schwarzschild's radius R=2G s^(1/2), where it diverges at a critical value b ~ 2.22 R of the impact parameter. The nature of the singularity is studied with particular attention to the scaling behaviour of various observables at the transition. The numerical approach is validated by reproducing the known exact solution in the axially symmetric case to high accuracy.

  1. Laboratory high-energy astrophysics on lasers

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, W.H.; Liedahl, D.A.; Walling, R.S.; Foord, M.E.; Osterheld, A.L.; Wilson, B.G.

    1994-12-01

    The tremendous range of temperatures and densities spanned by astrophysical plasmas has significant overlap with conditions attainable using high-power laser facilities. These facilities provide an opportunity to create, control, and characterize plasmas in the laboratory that mirror conditions in some of the most important cosmological systems. Moreover, laboratory experiments can enhance astrophysical understanding by focusing on and isolating important physical processes, without necessarily reproducing the exact conditions of the integral system. Basic study of radiative properties, transport phenomena, thermodynamic response and hydrodynamic evolution in plasmas under properly scaled conditions leads both directly and indirectly to improved models of complex astrophysical systems. In this paper, we will discuss opportunities for current and planned highpower lasers to contribute to the study of high-energy astrophysics.

  2. Supernovae and supernova remnants at high energies

    Science.gov (United States)

    Chevalier, Roger A.

    1990-01-01

    The physical phenomena that are observable with X- and gamma-ray observations of supernovae are discussed with respect to possible high-energy astrophysics experiments. Prompt photospheric emission and its echo are discussed, supernova radioactivity and neutron star effects are examined, and circumstellar and interstellar interaction are reviewed. The primary uncertainties are found to be the hardening of the spectrum by non-LTE effects and the amount of absorption of the radiation from the initial soft X-ray burst. The radioactivity in supernovae is theorized to lead to gamma-ray lines and continuum emission unless the event is low-mass type II. Gamma-ray observations are proposed to examine the efficiency of particle acceleration, and high-resolution spectroscopy can provide data regarding ionization, temperature, composition, and velocities of the X-ray-emitting gas.

  3. High energy laser demonstrators for defense applications

    Science.gov (United States)

    Jung, M.; Riesbeck, Th.; Schmitz, J.; Baumgärtel, Th.; Ludewigt, K.; Graf, A.

    2017-01-01

    Rheinmetall Waffe Munition has worked since 30 years in the area of High Energy Laser (HEL) for defence applications, starting from pulsed CO2 to pulsed glass rods lasers. In the last decade Rheinmetall Waffe Munition changed to diode pumped solid state laser (DPSSL) technology and has successfully developed, realised and tested a variety of versatile HEL weapon demonstrators for air- and ground defence scenarios like countering rocket, artillery, mortar, missile (RAMM), unmanned aerial systems (UAS) and unexploded ordnances clearing. By employing beam superimposing technology and a modular laser weapon concept, the total optical power has been successively increased. Stationary weapon platforms, military vehicles and naval platforms have been equipped with high energy laser effectors. The contribution gives a summary of the most recent development stages of Rheinmetalls HEL weapon program. In addition to the stationary 30 kW laser weapon demonstrator, we present vehicle based HEL demonstrators: the 5 kW class Mobile HEL Effector Track V, the 20 kW class Mobile HEL Effector Wheel XX and the 50 kW class Mobile HEL Effector Container L and the latest 10 kW HEL effector integrated in the naval weapon platform MLG 27. We describe the capabilities of these demonstrators against different potential targets. Furthermore, we will show the capability of the 30 kW stationary Laser Weapon Demonstrator integrated into an existing ground based air defence system to defeat saturated attacks of RAMM and UAS targets.

  4. Ultra-small, highly stable, and membrane-impermeable fluorescent nanosensors for oxygen.

    Science.gov (United States)

    Wang, Xu-Dong; Stolwijk, Judith A; Sperber, Michaela; Meier, Robert J; Wegener, Joachim; Wolfbeis, Otto S

    2013-06-04

    We report on the preparation of ultra-small fluorescent nanosensors for oxygen via a one-pot approach. The nanoparticles have a hydrophobic core capable of firmly hosting hydrophobic luminescent oxygen probes. Their surface is composed of a dense and long-chain poly(ethylene glycol) shell, which renders them cell-membrane impermeable but yet highly sensitive to oxygen, and also highly stable in aqueous solutions and cell culture media. These features make them potentially suitable for sensing oxygen in extracellular fluids such as blood, interstitial and brain fluid, in (micro) bioreactors and micro- or nanoscale fluidic devices. Four kinds of nanosensors are presented, whose excitation spectra cover a wide spectral range (395-630 nm), thus matching many common laser lines, and with emission maxima ranging from 565 to 800 nm, thereby minimizing interference from background luminescence of biomatter. The unquenched lifetimes are on the order of 5.8-234 μs, which-in turn-enables lifetime imaging and additional background separation via time-gated methods.

  5. High oxygen consumption rates in the deep layers of the North Aegean Sea (eastern Mediterranean

    Directory of Open Access Journals (Sweden)

    E. SOUVERMEZOGLOU

    2002-06-01

    Full Text Available Severe winter meteorological conditions promote dense water formation over the shelves of the North Aegean Sea. The newly formed dense water fills the deep basins of the North Aegean Sea, contributing to their ventilation and the downward transport of organic and inorganic material. The great bathymetric variability imposes limitations on the deep circulation and the communication between the various basins and makes the North Aegean Sea an appropriate area for the monitoring of oxygen consumption in the deep layers. Historical hydrographic data suggest that there was extensive production of dense water in the North Aegean Sea on two occasions during the last decade, the winters of 1987 and 1992-1993. Our data series from August 1986 to September 1989 and from March 1997 to February 1999, permitted us to follow, step by step, the oxygen consumption and the nutrient regeneration in the deep basins of the northern Aegean Sea during these periods of isolation. The organic matter reaching the bottom layer just after the deep water formation event is rich in labile and easily oxidizable material and its decomposition leads to a significant oxygen uptake during the first year of stagnation. The further decomposition of the remaining semi-labile and refractory material turns over on greater time scales, by consuming lesser amounts of oxygen. A more significant oxygen decrease is recorded in the eastern basin (Lemnos Basin of the North Aegean Trough, than in the central (Athos Basin and the western (North Sporades Basin ones and is attributed to the irregular contribution of the Black Sea Water (BSW to the water masses formed on the different shelves of the North Aegean Sea. Our results and the existing data on the Turkish straits showed that dissolved organic matter is the major constituent responsible for this high oxygen consumption. The slightly different particulate organic carbon fluxes to these depressions play a secondary role.

  6. Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

    Energy Technology Data Exchange (ETDEWEB)

    Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

    2011-12-22

    The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting

  7. Modeling, simulation, and high-autonomy control of a Martian oxygen production plant

    Science.gov (United States)

    Schooley, L. C.; Cellier, F. E.; Wang, F.-Y.; Zeigler, B. P.

    1992-01-01

    Progress on a project for the development of a high-autonomy intelligent command and control architecture for process plants used to produce oxygen from local planetary resources is reported. A distributed command and control architecture is being developed and implemented so that an oxygen production plant, or other equipment, can be reliably commanded and controlled over an extended time period in a high-autonomy mode with high-level task-oriented teleoperation from one or several remote locations. During the reporting period, progress was made at all levels of the architecture. At the remote site, several remote observers can now participate in monitoring the plant. At the local site, a command and control center was introduced for increased flexibility, reliability, and robustness. The local control architecture was enhanced to control multiple tubes in parallel, and was refined for increased robustness. The simulation model was enhanced to full dynamics descriptions.

  8. UPR/Mayaguez High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Mendez, Hector [Univ. of Puerto Rico, Mayaguez (Puerto Rico)

    2014-10-31

    This year the University of Puerto Rico at Mayaguez (UPRM) High Energy Physics (HEP) group continued with the ongoing research program outlined in the grant proposal. The program is centered on the Compact Muon Solenoid (CMS) experiment at the proton-proton (pp) collisions at the Large Hadron Collider (LHC) at CERN in Geneva, Switzerland. The main research focus is on data analysis and on the preparation for the High Luminosity (HL) LHC or experiment detector upgrade. The physics data analysis included Higgs Doublet Search and measurement of the (1) Λ0b branching fraction, (2) B meson mass, and (3) hyperon θ-b lifetime. The detector upgrade included work on the preparations for the Forward Pixel (FPIX) detector Silicon Sensor Testing in a production run at Fermilab. In addition, the group has taken responsibilities on the Software Release through our former research associate Dr. Eric Brownson who acted until last December as a Level Two Offline Manager for the CMS Upgrade. In support of the CMS data analysis activities carried out locally, the UPRM group has built and maintains an excellent Tier3 analysis center in Mayaguez. This allowed us to analyze large data samples and to continue the development of algorithms for the upgrade tracking robustness we started several years ago, and we plan to resume in the near future. This project involves computer simulation of the radiation damage to be suffered at the higher luminosities of the upgraded LHC. This year we continued to serve as a source of outstanding students for the field of high energy physics. Three of our graduate students finished their MS work in May, 2014, Their theses research were on data analysis of heavy quark b-physics. All of them are currently enrolled at Ph.D. physics program across the nation. One of them (Hector Moreno) at New Mexico University (Hector Moreno), one at University of New Hampshire (Sandra Santiesteban) and one at University of

  9. The Advanced Telescope for High Energy Astrophysics

    Science.gov (United States)

    Guainazzi, Matteo

    2017-08-01

    Athena (the Advanced Telescope for High Energy Astrophysics) is a next generation X-ray observatory currently under study by ESA for launch in 2028. Athena is designed to address the Hot and Energetic Universe science theme, which addresses two key questions: 1) How did ordinary matter evolve into the large scale structures we see today? 2) How do black holes grow and shape the Universe. To address these topics Athena employs an innovative X-ray telescope based on Silicon Pore Optics technology to deliver extremely light weight and high throughput, while retaining excellent angular resolution. The mirror can be adjusted to focus onto one of two focal place instruments: the X-ray Integral Field Unit (X-IFU) which provides spatially-resolved, high resolution spectroscopy, and the Wide Field Imager (WFI) which provides spectral imaging over a large field of view, as well as high time resolution and count rate tolerance. Athena is currently in Phase A and the study status will be reviewed, along with the scientific motivations behind the mission.

  10. New High-Energy Nanofiber Anode Materials

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiangwu [North Carolina State Univ., Raleigh, NC (United States); Fedkiw, Peter [North Carolina State Univ., Raleigh, NC (United States); Khan, Saad [North Carolina State Univ., Raleigh, NC (United States); Huang, Alex [North Carolina State Univ., Raleigh, NC (United States); Fan, Jiang [North Carolina State Univ., Raleigh, NC (United States)

    2013-11-15

    The overall goal of the proposed work was to use electrospinning technology to integrate dissimilar materials (lithium alloy and carbon) into novel composite nanofiber anodes, which simultaneously had high energy density, reduced cost, and improved abuse tolerance. The nanofiber structure allowed the anodes to withstand repeated cycles of expansion and contraction. These composite nanofibers were electrospun into nonwoven fabrics with thickness of 50 μm or more, and then directly used as anodes in a lithium-ion battery. This eliminated the presence of non-active materials (e.g., conducting carbon black and polymer binder) and resulted in high energy and power densities. The nonwoven anode structure also provided a large electrode-electrolyte interface and, hence, high rate capacity and good lowtemperature performance capability. Following are detailed objectives for three proposed project periods. During the first six months: Obtain anodes capable of initial specific capacities of 650 mAh/g and achieve ~50 full charge/discharge cycles in small laboratory scale cells (50 to 100 mAh) at the 1C rate with less than 20 percent capacity fade; In the middle of project period: Assemble, cycle, and evaluate 18650 cells using proposed anode materials, and demonstrate practical and useful cycle life (750 cycles of ~70% state of charge swing with less than 20% capacity fade) in 18650 cells with at least twice improvement in the specific capacity than that of conventional graphite electrodes; At the end of project period: Deliver 18650 cells containing proposed anode materials, and achieve specific capacities greater than 1200 mAh/g and cycle life longer than 5000 cycles of ~70% state of charge swing with less than 20% capacity fade.

  11. Topical hyperbaric oxygen and low energy laser therapy for chronic diabetic foot ulcers resistant to conventional treatment.

    OpenAIRE

    Landau, Z.; Schattner, A.

    2001-01-01

    Chronic foot ulcers are common in long-standing diabetes, may herald severe complications and are often resistant to therapy. To evaluate the effects of adjunctive topical hyperbaric oxygen treatment (THBO) and low energy laser (LEL) irradiation on ulcer healing, a 100 consecutive patients with chronic diabetic foot ulcers (DFU) refractory to 4.5 +/- 1.2 months of comprehensive treatment, were enrolled in a prospective open study. While conventional treatment was continued as necessary, THBO ...

  12. Energy efficiency indicators for high electric-load buildings

    Energy Technology Data Exchange (ETDEWEB)

    Aebischer, Bernard; Balmer, Markus A.; Kinney, Satkartar; Le Strat, Pascale; Shibata, Yoshiaki; Varone, Frederic

    2003-06-01

    Energy per unit of floor area is not an adequate indicator for energy efficiency in high electric-load buildings. For two activities, restaurants and computer centres, alternative indicators for energy efficiency are discussed.

  13. Crystal Structures and Electronic Properties of Oxygen-rich Titanium Oxides at High Pressure.

    Science.gov (United States)

    Zhong, Xin; Yang, Lihua; Qu, Xin; Wang, Yanchao; Yang, Jinghai; Ma, Yanming

    2018-03-02

    Pressure is well-known to significantly change the bonding patterns of materials and lift the reactivity of elements, leading to the synthesis of unconventional compounds with fascinating properties. Titanium-oxygen (Ti-O) compounds (e.g., TiO 2 ) are attracting increasing attention due to their attractive electronic properties and extensive industrial applications (e.g., photocatalysis and solar cells). Using the effective CALYPSO structure searching method combined with first-principles calculations, we theoretically explored various oxygen-rich Ti-O compounds at pressures ranging from 0 to 200 GPa. Our results revealed, unexpectedly, that pressure stabilizes two hitherto unknown stoichiometric oxygen-rich Ti 2 O 5 and TiO 3 compounds. Ti 2 O 5 crystallized in P-42 1 c structure, whose remarkable feature is that it contains a peroxide group (O2 2- ) with an O-O distance of 1.38 Å at 150 GPa. The trioxide TiO 3 is an ionic metal and is the oxygen-richest compound known thus far in the Ti-O system. It adopts a high symmetry (space group Pm-3n) structure consisting of a 12-fold coordinated face-sharing TiO 12 icosahedron, where Ti has the highest coordination number with O among all Ti-O structures. The underlying mechanisms for the stabilization of Ti 2 O 5 and TiO 3 lie in the higher coordination number and denser structure packing. Our current results unravel the unusual oxygen-rich stoichiometry of Ti-O compounds and provide further insight into the diverse electronic properties of Ti oxides under high pressure.

  14. An Exercise Protocol Designed to control Energy Expenditure and to have a Positive Impact on Maximal Oxygen Consumption for Long-Term Space Missions

    Science.gov (United States)

    Matsuo, Tomoaki; Ohkawara, Kazunori; Seino, Satoshi; Shimojo, Nobutake; Yamada, Shin; Ohshima, Hiroshi; Tanaka, Kiyoji; Mukai, Chiaki

    2013-02-01

    Maximal oxygen consumption decreases during spaceflight, and astronauts also experience controversial weight loss. Future space missions require a more efficient exercise program to maintain work efficiency and to control increased energy expenditure (EE). We have been developing two types of original exercise training protocols which are better suited to astronauts’ daily routine exercise during long-term spaceflight: sprint interval training (SIT) and high-intensity interval aerobic training (HIAT). In this study, we compared the total EE, including excess post-exercise energy expenditure (EPEE), induced by our interval cycling protocols with the total EE of a traditional, continuous aerobic training (CAT). In the results, while the EPEEs after the SIT and HIAT were greater than after the CAT, the total EE for an entire exercise/rest session with the CAT was the greatest of our three exercise protocols. The SIT and HIAT would be potential protocols to control energy expenditure for long space missions.

  15. High-Intensity Sweeteners and Energy Balance

    Science.gov (United States)

    Swithers, Susan E.; Martin, Ashley A.; Davidson, Terry L.

    2010-01-01

    Recent epidemiological evidence points to a link between a variety of negative health outcomes (e.g. metabolic syndrome, diabetes and cardiovascular disease) and the consumption of both calorically sweetened beverages and beverages sweetened with high-intensity, non-caloric sweeteners. Research on the possibility that non-nutritive sweeteners promote food intake, body weight gain, and metabolic disorders has been hindered by the lack of a physiologically-relevant model that describes the mechanistic basis for these outcomes. We have suggested that based on Pavlovian conditioning principles, consumption of non-nutritive sweeteners could result in sweet tastes no longer serving as consistent predictors of nutritive postingestive consequences. This dissociation between the sweet taste cues and the caloric consequences could lead to a decrease in the ability of sweet tastes to evoke physiological responses that serve to regulate energy balance. Using a rodent model, we have found that intake of foods or fluids containing non-nutritive sweeteners was accompanied by increased food intake, body weight gain, accumulation of body fat, and weaker caloric compensation, compared to consumption of foods and fluids containing glucose. Our research also provided evidence consistent with the hypothesis that these effects of consuming saccharin may be associated with a decrement in the ability of sweet taste to evoke thermic responses, and perhaps other physiological, cephalic phase, reflexes that are thought to help maintain energy balance. PMID:20060008

  16. Precision timing calorimeter for high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Dustin; Apresyan, Artur [California Institute of Technology, Pasadena, CA 91125 (United States); Bornheim, Adolf, E-mail: bornheim@hep.caltech.edu [California Institute of Technology, Pasadena, CA 91125 (United States); Duarte, Javier; Peña, Cristián; Spiropulu, Maria; Trevor, Jason; Xie, Si [California Institute of Technology, Pasadena, CA 91125 (United States); Ronzhin, Anatoly [Fermi National Accelerator Laboratory, PO Box 500, Batavia, IL 60510-5011 (United States)

    2016-07-11

    Scintillator based calorimeter technology is studied with the aim to achieve particle detection with a time resolution on the order of a few 10 ps for photons and electrons at energies of a few GeV and above. We present results from a prototype of a 1.4×1.4×11.4 cm{sup 3} sampling calorimeter cell consisting of tungsten absorber plates and Cerium-doped Lutetium Yttrium Orthosilicate (LYSO) crystal scintillator plates. The LYSO plates are read out with wave lengths shifting fibers which are optically coupled to fast photo detectors on both ends of the fibers. The measurements with electrons were performed at the Fermilab Test Beam Facility (FTBF) and the CERN SPS H2 test beam. In addition to the baseline setup plastic scintillation counter and a MCP-PMT were used as trigger and as a reference for a time of flight measurement (TOF). We also present measurements with a fast laser to further characterize the response of the prototype and the photo sensors. All data were recorded using a DRS4 fast sampling digitizer. These measurements are part of an R&D program whose aim is to demonstrate the feasibility of building a large scale electromagnetic calorimeter with a time resolution on the order of 10 ps, to be used in high energy physics experiments.

  17. Precision timing calorimeter for high energy physics

    Science.gov (United States)

    Anderson, Dustin; Apresyan, Artur; Bornheim, Adolf; Duarte, Javier; Peña, Cristián; Spiropulu, Maria; Trevor, Jason; Xie, Si; Ronzhin, Anatoly

    2016-07-01

    Scintillator based calorimeter technology is studied with the aim to achieve particle detection with a time resolution on the order of a few 10 ps for photons and electrons at energies of a few GeV and above. We present results from a prototype of a 1.4×1.4×11.4 cm3 sampling calorimeter cell consisting of tungsten absorber plates and Cerium-doped Lutetium Yttrium Orthosilicate (LYSO) crystal scintillator plates. The LYSO plates are read out with wave lengths shifting fibers which are optically coupled to fast photo detectors on both ends of the fibers. The measurements with electrons were performed at the Fermilab Test Beam Facility (FTBF) and the CERN SPS H2 test beam. In addition to the baseline setup plastic scintillation counter and a MCP-PMT were used as trigger and as a reference for a time of flight measurement (TOF). We also present measurements with a fast laser to further characterize the response of the prototype and the photo sensors. All data were recorded using a DRS4 fast sampling digitizer. These measurements are part of an R&D program whose aim is to demonstrate the feasibility of building a large scale electromagnetic calorimeter with a time resolution on the order of 10 ps, to be used in high energy physics experiments.

  18. Energy storage via high temperature superconductivity (SMES)

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, R. [Tampere Univ. of Technology (Finland)

    1998-10-01

    The technology concerning high temperature superconductors (HTS) is matured to enabling different kind of prototype applications including SMES. Nowadays when speaking about HTS systems, attention is focused on the operating temperature of 20-30 K, where the critical current and flux density are fairly close to 4.2 K values. In addition by defining the ratio of the energy content of a novel HTS magnetic system and the required power to keep the system at the desired temperature, the optimum settles to the above mentioned temperature range. In the frame of these viewpoints a 5 kJ HTS SMES system has been designed and tested at Tampere University of Technology with a coil manufactured by American Superconductor (AMSC). The HTS magnet has inside and outside diameters of 252 mm and 317 mm, respectively and axial length of 66 mm. It operates at 160 A and carries a total of 160 kA-turns to store the required amount of energy. The effective magnetic inductance is 0.4 H and the peak axial field is 1.7 T. The magnet is cooled to the operating temperature of 20 K with a two stage Gifford-McMahon type cryocooler with a cooling power of 60 W at 77 K and 8 W at 20 K. The magnetic system has been demonstrated to compensate a short term loss of power of a sensitive consumer

  19. Transverse microanalysis of high energy Ion implants

    Energy Technology Data Exchange (ETDEWEB)

    Dooley, S.P.; Jamieson, D.N.; Nugent, K.W.; Prawer, S. [Melbourne Univ., Parkville, VIC (Australia). School of Physics

    1996-12-31

    High energy ion implants in semiconductor materials have been analyzed by Channeling Contrast Microscopy (CCM) perpendicular to the implant direction, allowing imaging of the entire ion track. The damage produced by Channeled and Random 1.4 MeV H{sup +} implants into the edge of a <100> type IIa diamond wafer were analyzed by channeling into the face of the crystal. The results showed negligible damage in the surface region of the implants, and swelling induced misalignment at the end of range of the implants. Channeled 1.4 MeV H{sup +} implants in diamond had a range only 9% deeper than Random implants, which could be accounted for by dechanneling of the beam. The channeling of H{sup +}{sub 2} ions has been previously found to be identical to that of protons of half energy, however the current experiment has shown a 1% increase in {chi}{sub min} for H{sup +}{sub 2} in diamond compared to H{sup +} at 1,2 MeV per proton. This is due to repulsion between protons within the same channel. 5 refs., 2 figs.

  20. High peak power diode stacks for high energy lasers

    Science.gov (United States)

    Negoita, Viorel C.; Vethake, Thilo; Jiang, John; Roff, Robert; Shih, Ming; Duck, Richard; Bauer, Marc; Mite, Roberto; Boucke, Konstantin; Treusch, Georg

    2015-02-01

    High energy solid state lasers are being developed for fusion experiments and other research applications where high energy per pulse is required but the repetition rate is rather low, around 10Hz. We report our results on high peak power diode laser stacks used as optical pumps for these lasers. The stacks are based on 10 mm bars with 4 mm cavity length and 55% fill factor, with peak power exceeding 500 W per bar. These bars are stacked and mounted on a cooler which provides backside cooling and electrical insulation. Currently we mount 25 bars per cooler for a nominal peak power of 12.5 kW, but in principle the mounting scheme can be scaled to a different number of devices depending on the application. Pretesting of these bars before soldering on the cooler enables us to select devices with similar wavelength and thus we maintain tight control of the spectral width (FWHM less than 6 nm). Fine adjustments of the centroid wavelength can be done by means of temperature of the cooling fluid or bias current. The available wavelength range spans from 880 nm to 1000 nm, and the wavelength of the entire assembly of stacks can be controlled to within 0.5 nm of the target value, which makes these stacks suitable for pumping a variety of gain media. The devices are fast axis collimated, with over 95% power being collimated in 6 mrad (full angle). The slow axis divergence is 9° (full angle) for 95% power content.

  1. Understanding the biological activity of high rate algae ponds through the calculation of oxygen balances.

    Science.gov (United States)

    Arbib, Zouhayr; de Godos Crespo, Ignacio; Corona, Enrique Lara; Rogalla, Frank

    2017-06-01

    Microalgae culture in high rate algae ponds (HRAP) is an environmentally friendly technology for wastewater treatment. However, for the implementation of these systems, a better understanding of the oxygenation potential and the influence of climate conditions is required. In this work, the rates of oxygen production, consumption, and exchange with the atmosphere were calculated under varying conditions of solar irradiance and dilution rate during six months of operation in a real scale unit. This analysis allowed determining the biological response of these dynamic systems. The rates of oxygen consumption measured were considerably higher than the values calculated based on the organic loading rate. The response to light intensity in terms of oxygen production in the bioreactor was described with one of the models proposed for microalgae culture in dense concentrations. This model is based on the availability of light inside the culture and the specific response of microalgae to this parameter. The specific response to solar radiation intensity showed a reasonable stability in spite of the fluctuations due to meteorological conditions. The methodology developed is a useful tool for optimization and prediction of the performance of these systems.

  2. Biomass-oxygen gasification in a high-temperature entrained-flow gasifier.

    Science.gov (United States)

    Zhou, Jinsong; Chen, Qing; Zhao, Hui; Cao, Xiaowei; Mei, Qinfeng; Luo, Zhongyang; Cen, Kefa

    2009-01-01

    The technology associated with indirect biomass liquefaction is currently arousing increased attention, as it could ensure a supply of transportation fuels and reduce the use of petroleum. The characteristics of biomass-oxygen gasification in a bench-scale laminar entrained-flow gasifier were studied in the paper. Experiments were carried out to investigate the influence of some key factors, including reaction temperature, residence time and oxygen/biomass ratio, on the gasification. The results indicated that higher temperature favored H2 and CO production. Cold gas efficiency was improved by N10% when the temperature was increased from 1000 to 1400 degrees C. The carbon conversion increased and the syngas quality was improved with increasing residence time. A shorter residence resulted in incomplete gasification. An optimal residence time of 1.6 s was identified in this study. The introduction of oxygen to the gasifier strengthened the gasification and improved the carbon conversion, but lowered the lower heating value and the H2/CO ratio of the syngas. The optimal oxygen/biomass ratio in this study was 0.4. The results of this study will help to improve our understanding of syngas production by biomass high-temperature gasification.

  3. Nanoporous PtFe alloys as highly active and durable electrocatalysts for oxygen reduction reaction

    Science.gov (United States)

    Duan, Huimei; Hao, Qin; Xu, Caixia

    2014-12-01

    Nanoporous PtFe alloys with two different bimetallic ratios are fabricated by selectively dealloying PtFeAl ternary alloys, characterized by nanoscaled bicontinuous network skeleton with interconnected hollow channels extending in all three dimensions. The reactive components in PtFeAl ternary alloy were sequentially leached out in a highly controllable manner, generating nanoporous architecture with different bimetallic ratios and the typical ligament size as small as 5 nm. These nanoporous PtFe alloys exhibit much enhanced electrocatalytic activity for oxygen reduction reaction compared with the PtFe/C and Pt/C catalysts. The specific and mass activities for oxygen reduction follow the order of nanoporous Pt75Fe25 > nanoporous Pt55Fe45 > PtFe/C > Pt/C. In the absence of any catalyst support, the structure stability of nanoporous PtFe alloys is greatly enhanced with less loss of the electrochemical surface area and the oxygen reduction activity upon long-term potential scan tests compared with PtFe/C and Pt/C catalysts. The as-made nanoporous PtFe alloys thus hold great application potential as promising cathode electrocatalyst in proton exchange membrane fuel cells with the advantages of easy preparation along with superior oxygen reduction activity and durability.

  4. Humidified high-flow nasal cannula oxygen in bronchiolitis reduces need for invasive ventilation but not intensive care admission.

    Science.gov (United States)

    Goh, Chong Tien; Kirby, Lynette J; Schell, David N; Egan, Jonathan R

    2017-09-01

    To describe the changes to paediatric intensive care unit (PICU) admission patterns and ventilation requirements for children with bronchiolitis following the introduction of humidified high-flow nasal cannula oxygen outside the PICU. Retrospective study comparing patients high-flow nasal cannula oxygen use (year 2008) to those immediately following the introduction of humidified high-flow nasal cannula oxygen use (year 2011) and those following further consolidation of humidified high-flow nasal cannula oxygen use outside the PICU (year 2013). Humidified high-flow nasal cannula oxygen use up to 1 L/kg/min in the hospital did not reduce PICU admission. Intubation rates were reduced from 22.2% in 2008 to 7.8% in 2013. There was a non-significant trend towards decreased length of stay in the PICU while hospital length of stay showed a significant decrease following the introduction of humidified high-flow nasal cannula oxygen. Age high-flow nasal cannula oxygen therapy. Humidified high-flow nasal cannula oxygen utilised outside of the PICU in our institution for children with bronchiolitis did not reduce admission rates or length of stay to the PICU but was associated with a decreasing need for invasive ventilation and reduced hospital length of stay. © 2017 Paediatrics and Child Health Division (The Royal Australasian College of Physicians).

  5. FIRST SPECTROSCOPIC EVIDENCE FOR HIGH IONIZATION STATE AND LOW OXYGEN ABUNDANCE IN Ly{alpha} EMITTERS ,

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Kimihiko; Shimasaku, Kazuhiro; Hashimoto, Takuya; Ono, Yoshiaki [Department of Astronomy, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Ouchi, Masami [Kavli Institute for the Physics and Mathematics of the Universe (WPI), University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan); Lee, Janice C., E-mail: nakajima@astron.s.u-tokyo.ac.jp [Space Telescope Science Institute, Baltimore, MD 21218 (United States)

    2013-05-20

    We present results from Keck/NIRSPEC and Magellan/MMIRS follow-up spectroscopy of Ly{alpha} emitters (LAEs) at z = 2.2 identified in our Subaru narrowband survey. We successfully detect H{alpha} emission from seven LAEs, and perform a detailed analysis of six LAEs free from active galactic nucleus activity, two out of which, CDFS-3865 and COSMOS-30679, have [O II] and [O III] line detections. They are the first [O II]-detected LAEs at high-z, and their [O III]/[O II] ratios and R23-indices provide the first simultaneous determinations of ionization parameter and oxygen abundance for LAEs. CDFS-3865 has a very high ionization parameter (q{sub ion}=2.5{sup +1.7}{sub -0.8} Multiplication-Sign 10{sup 8} cm s{sup -1}) and a low oxygen abundance (12+ log (O/H)=7.84{sup +0.24}{sub -0.25}) in contrast with moderate values of other high-z galaxies such as Lyman break galaxies (LBGs). COSMOS-30679 also possesses a relatively high ionization parameter (q{sub ion}=8{sup +10}{sub -4} Multiplication-Sign 10{sup 7} cm s{sup -1}) and a low oxygen abundance (12+ log (O/H)=8.18{sup +0.28}{sub -0.28}). Both LAEs appear to fall below the mass-metallicity relation of z {approx} 2 LBGs. Similarly, a low metallicity of 12 + log (O/H) < 8.4 is independently indicated for typical LAEs from a composite spectrum and the [N II]/H{alpha} index. Such high ionization parameters and low oxygen abundances can be found in local star-forming galaxies, but this extreme local population occupies only {approx}0.06% of the Sloan Digital Sky Survey spectroscopic galaxy sample with a number density {approx}100 times smaller than that of LAEs. With their high ionization parameters and low oxygen abundances, LAEs would represent an early stage of galaxy formation dominated by massive stars in compact star-forming regions. High-q{sub ion} galaxies like LAEs would produce ionizing photons efficiently with a high escape fraction achieved by density-bounded H II regions, which would significantly contribute to

  6. Monolithic pixel detectors for high energy physics

    CERN Document Server

    Snoeys, W

    2013-01-01

    Monolithic pixel detectors integrating sensor matrix and readout in one piece of silicon have revolutionized imaging for consumer applications, but despite years of research they have not yet been widely adopted for high energy physics. Two major requirements for this application, radiation tolerance and low power consumption, require charge collection by drift for the most extreme radiation levels and an optimization of the collected signal charge over input capacitance ratio ( Q / C ). It is shown that monolithic detectors can achieve Q / C for low analog power consumption and even carryout the promise to practically eliminate analog power consumption, but combining suf fi cient Q / C , collection by drift, and integration of readout circuitry within the pixel remains a challenge. An overview is given of different approaches to address this challenge, with possible advantages and disadvantages.

  7. Polarized targets in high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    Cates, G.D. Jr. [Princeton Univ., NJ (United States)

    1994-12-01

    Various approaches are discussed for producing polarized nuclear targets for high energy physics experiments. As a unifying theme, examples are drawn from experiments to measure spin dependent structure functions of nucleons in deep inelastic scattering. This single physics goal has, over roughly two decades, been a driving force in advances in target technology. Actual or planned approaches have included solid targets polarized by dynamic nuclear polarization (DNP), several types of internal targets for use in storage rings, and gaseous {sup 3}He targets polarized by spin-exchange optical pumping. This last approach is the type of target adopted for SLAC E-142, an experiment to measure the spin structure function of the neutron, and is described in detail.

  8. Nonextensive statistical mechanics and high energy physics

    Directory of Open Access Journals (Sweden)

    Tsallis Constantino

    2014-04-01

    Full Text Available The use of the celebrated Boltzmann-Gibbs entropy and statistical mechanics is justified for ergodic-like systems. In contrast, complex systems typically require more powerful theories. We will provide a brief introduction to nonadditive entropies (characterized by indices like q, which, in the q → 1 limit, recovers the standard Boltzmann-Gibbs entropy and associated nonextensive statistical mechanics. We then present somerecent applications to systems such as high-energy collisions, black holes and others. In addition to that, we clarify and illustrate the neat distinction that exists between Lévy distributions and q-exponential ones, a point which occasionally causes some confusion in the literature, very particularly in the LHC literature

  9. High energy physics, past, present and future

    Science.gov (United States)

    Sugawara, Hirotaka

    2017-03-01

    At the beginning of last century we witnessed the emergence of new physics, quantum theory and gravitational theory, which gave us correct understanding of the world of atoms and deep insight into the structure of universe we live in. Towards the end of the century, string theory emerged as the most promising candidate to unify these two theories. In this talk, I would like to assert that the understanding of the origin of physical constants, ℏ (Planck constant) for quantum theory, and G (Newton’s gravitational constant) for gravitational theory within the framework of string theory is the key to understanding string theory. Then, I will shift to experimental high energy physics and discuss the necessity of world-wide collaboration in the area of superconducting technology which is essential in constructing the 100 TeV hadron collider.

  10. Microfluidic Scintillation Detectors for High Energy Physics

    CERN Document Server

    Maoddi, Pietro; Mapelli, Alessandro

    This thesis deals with the development and study of microfluidic scintillation detectors, a technology of recent introduction for the detection of high energy particles. Most of the interest for such devices comes from the use of a liquid scintillator, which entails the possibility of changing the active material in the detector, leading to increased radiation resistance. A first part of the thesis focuses on the work performed in terms of design and modelling studies of novel prototype devices, hinting to new possibilities and applications. In this framework, the simulations performed to validate selected designs and the main technological choices made in view of their fabrication are addressed. The second part of this thesis deals with the microfabrication of several prototype devices. Two different materials were studied for the manufacturing of microfluidic scintillation detectors, namely the SU-8 photosensitive epoxy and monocrystalline silicon. For what concerns the former, an original fabrication appro...

  11. Singlet oxygen triplet energy transfer-based imaging technology for mapping protein-protein proximity in intact cells.

    Science.gov (United States)

    To, Tsz-Leung; Fadul, Michael J; Shu, Xiaokun

    2014-06-06

    Many cellular processes are carried out by large protein complexes that can span several tens of nanometres. Whereas forster resonance energy transfer has a detection range of technology with a detection range of up to several tens of nanometres: singlet oxygen triplet energy transfer. We demonstrate that our method confirms the topology of a large protein complex in intact cells, which spans from the endoplasmic reticulum to the outer mitochondrial membrane and the matrix. This new method is thus suited for mapping protein proximity in large protein complexes.

  12. Maximal exercise and muscle oxygen extraction in acclimatizing lowlanders and high altitude natives

    DEFF Research Database (Denmark)

    Lundby, Carsten; Sander, Mikael; van Hall, Gerrit

    2006-01-01

    The tight relation between arterial oxygen content and maximum oxygen uptake (Vv(o2max)within a given person at sea level is diminished with altitude acclimatization. An explanation often suggested for this mismatch is impairment of the muscle O(2) extraction capacity with chronic hypoxia......, and is the focus of the present study. We have studied six lowlanders during maximal exercise at sea level (SL) and with acute (AH) exposure to 4,100 m altitude, and again after 2 (W2) and 8 weeks (W8) of altitude sojourn, where also eight high altitude native (Nat) Aymaras were studied. Fractional arterial muscle...... O(2) extraction at maximal exercise was 90.0+/-1.0% in the Danish lowlanders at sea level, and remained close to this value in all situations. In contrast to this, fractional arterial O(2) extraction was 83.2+/-2.8% in the high altitude natives, and did not change with the induction of normoxia...

  13. The high energy telescope on EXIST

    Science.gov (United States)

    Hong, J.; Grindlay, J. E.; Allen, B.; Barthelmy, S. D.; Skinner, G. K.; Gehrels, N.

    2009-08-01

    The Energetic X-ray Imaging Survey Telescope (EXIST) is a proposed next generation multi-wavelength survey mission. The primary instrument is a High Energy telescope (HET) that conducts the deepest survey for Gamma-ray Bursts (GRBs), obscured-accreting and dormant Supermassive Black Holes and Transients of all varieties for immediate followup studies by the two secondary instruments: a Soft X-ray Imager (SXI) and an Optical/Infrared Telescope (IRT). EXIST will explore the early Universe using high redshift GRBs as cosmic probes and survey black holes on all scales. The HET is a coded aperture telescope employing a large array of imaging CZT detectors (4.5 m2, 0.6 mm pixel) and a hybrid Tungsten mask. We review the current HET concept which follows an intensive design revision by the HET imaging working group and the recent engineering studies in the Instrument and Mission Design Lab at the Goddard Space Flight Center. The HET will locate GRBs and transients quickly (<10-30 sec) and accurately (< 20") for rapid (< 1-3 min) onboard followup soft X-ray and optical/IR (0.3-2.2 μm) imaging and spectroscopy. The broad energy band (5-600 keV) and the wide field of view (~90° × 70&° at 10% coding fraction) are optimal for capturing GRBs, obscured AGNs and rare transients. The continuous scan of the entire sky every 3 hours will establish a finely-sampled long-term history of many X-ray sources, opening up new possibilities for variability studies.

  14. Numerical analysis of the effects of a high gradient magnetic field on flowing erythrocytes in a membrane oxygenator

    Energy Technology Data Exchange (ETDEWEB)

    Mitamura, Yoshinori, E-mail: ymitamura@par.odn.ne.jp; Okamoto, Eiji, E-mail: okamoto@tspirit.tokai-u.jp

    2015-04-15

    This study was carried out to clarify the effect of a high gradient magnetic field on pressure characteristics of blood in a hollow fiber membrane oxygenator in a solenoid coil by means of numerical analysis. Deoxygenated erythrocytes are paramagnetic, and oxygenated erythrocytes are diamagnetic. Blood changes its magnetic susceptibility depending on whether it is carrying oxygen or not. Motion of blood was analyzed by solving the continuous equation and the Navier–Stokes equation. It was confirmed that oxygenation of deoxygenated blood in the downstream side of the applied magnetic field was effective for pressure rise in a non-uniform magnetic field. The pressure rise was enhanced greatly by an increase in magnetic field intensity. The results suggest that a membrane oxygenator works as an actuator and there is a possibility of self-circulation of blood through an oxygenator in a non-uniform magnetic field. - Highlights: • Effects of a gradient magnetic field on erythrocytes in an oxygenator were analyzed. • Blood changes magnetic susceptibility depending on if it is carrying oxygen or not. • Oxygenation of deoxygenated blood is effective for pressure rise in a magnetic field. • A membrane oxygenator works as an actuator. • There is a possibility of self-circulation of blood through an oxygenator.

  15. High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

    Science.gov (United States)

    Bents, David J.

    1987-01-01

    A hydrogen-oxygen regenerative fuel cell energy storage system based on high temperature solid oxide fuel cell technology is discussed which has application to darkside energy storage for solar photovoltaics. The forward and reverse operating cycles are described, and heat flow, mass, and energy balance data are presented to characterize the system's performance and the variation of performance with changing reactant storage pressure. The present system weighs less than nickel hydrogen battery systems after 0.7 darkside operation, and it maintains a specific weight advantage over radioisotope generators for discharge periods up to 72 hours.

  16. Perioperative high inspired oxygen fraction therapy reduces surgical site infection with Pseudomonas aeruginosa in rats.

    Science.gov (United States)

    Kroin, Jeffrey S; Li, Jinyuan; Goldufsky, Josef W; Gupta, Kajal H; Moghtaderi, Masoomeh; Buvanendran, Asokumar; Shafikhani, Sasha H

    2016-08-01

    Surgical site infection (SSI) remains one of the most important causes of healthcare-associated infections, accounting for ~17 % of all hospital-acquired infections. Although short-term perioperative treatment with high fraction of inspired oxygen (FiO2) has shown clinical benefits in reducing SSI in colorectal resection surgeries, the true clinical benefits of FiO2 therapy in reducing SSI remain unclear because randomized controlled trials on this topic have yielded disparate results and inconsistent conclusions. To date, no animal study has been conducted to determine the efficacy of short-term perioperative treatments with high (FiO2>60 %) versus low (FiO2oxygen in reducing SSI. In this report, we designed a rat model for muscle surgery to compare the effectiveness of short-term perioperative treatments with high (FiO2=80 %) versus a standard low (FiO2=30 %) oxygen in reducing SSI with Pseudomonas aeruginosa - one of the most prevalent Gram-negative pathogens, responsible for nosocomial SSIs. Our data demonstrate that 5 h perioperative treatment with 80 % FiO2 is significantly more effective in reducing SSI with P. aeruginosa compared to 30 % FiO2 treatment. We further show that whilst 80 % FiO2 treatment does not affect neutrophil infiltration into P. aeruginosa-infected muscles, neutrophils in the 80 % FiO2-treated and infected animal group are significantly more activated than neutrophils in the 30 % FiO2-treated and infected animal group, suggesting that high oxygen perioperative treatment reduces SSI with P. aeruginosa by enhancing neutrophil activation in infected wounds.

  17. High-performance platinized carbon electrodes for oxygen reduction in power sources with alkaline electrolytes

    Science.gov (United States)

    Manoharan, R.; Sarma, D. D.; Shukla, A. K.

    A high-performance, oxygen-reducing electrode, made from physically and chemically tailored coconut-shell charcoal substrate catalysed with 7 wt.% platinum, is reported. The electrode can be loaded with current densities of 2000 - 5200 A/m 2, with negligible deterioration, for periods of up to 1200 h. Extensive electron spectroscopic studies have been conducted to characterise the electroactive species present on the surface of the electrodes during service.

  18. UPR/Mayaguez High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    López, Angel M. [Univ. of Puerto Rico, Mayaguez (Puerto Rico)

    2015-10-27

    For the period of sixteen years covered by this report (June 1, 1997 - July 31, 2013) the High Energy Physics Group at the University of Puerto Rico’s Mayaguez Campus (UPRM) carried out an extensive research program that included major experiments at Fermi National Accelerator Laboratory (Fermilab), the Cornell Electron-positron Collider and CERN. In particular, these were E831 (FOCUS) at Fermilab, CLEOc at Cornell and the Compact Muon Solenoid (CMS) at the Large Hadron Collider (LHC) at CERN. The group’s history is one of successful execution and growth. Beginning with one faculty researcher in 1985, it eventually included four faculty researchers, one post-doctoral research associate, two undergraduates and as many as six graduate students at one time working on one of the experiments that discovered the Higgs boson. Some of this expansion was due to the group’s leveraging of funds from the Department of Energy’s core grant to attract funds from National Science Foundation programs not targeted to high energy physics. Besides the group’s research productivity, its other major contribution was the training of a large number of MS students who later went on to successful technical careers in industry as well as academia including many who obtained PhD degrees at US universities. In an attempt to document this history, this final report gives a general description of the Group’s work prior to June 1, 2010, the starting date for the last grant renewal period. Much more detail can, of course, be found in the annual reports submitted up to that date. The work during the last grant period is discussed in detail in a separate section. To summarize the group’s scientific accomplishments, one can point to the results of the experiments. Both FOCUS and CLEOc were designed to carry out precise measurements of processes involving the heavy quarks, charm and bottom. Heavy quarks are particularly interesting because, due to their mass, theoretical calculations

  19. Solid-state reactions to synthesize nanostructured lead selenide semiconductor powders by high-energy milling

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, H., E-mail: uu_gg_oo@yahoo.com.mx [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco (Mexico) and Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada - IPN, Legaria 694, Col. Irrigacion, Del. Miguel Hidalgo (Mexico); Reyes-Carmona, F. [Facultad de Quimica - UNAM, Circuito de la Investigacion Cientifica s/n, C.U. Del. Coyoacan (Mexico); Jaramillo-Vigueras, D. [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco (Mexico)

    2011-10-15

    Highlights: {yields} PbSe synthesized from PbO instead of Pb powder do not require an inert atmosphere. {yields} During high-energy milling oxygen has to be chemically reduced from the lead oxide. {yields} Solid-state and solid-gas chemical reactions promote both solid and gaseous products. -- Abstract: Both solid-solid and gas-solid reactions have been traced during high-energy milling of Se and PbO powders under vial (P, T) conditions in order to synthesize the PbSe phase. Chemical and thermodynamic arguments are postulated to discern the high-energy milling mechanism to transform PbO-Se micropowders onto PbSe-nanocrystals. A set of reactions were evaluated at around room temperature. Therefore an experimental campaign was designed to test the nature of reactions in the PbO-Se system during high-energy milling.

  20. Preservation of high glycolytic phenotype by establishing new acute lymphoblastic leukemia cell lines at physiologic oxygen concentration

    Energy Technology Data Exchange (ETDEWEB)

    Sheard, Michael A., E-mail: msheard@chla.usc.edu [Developmental Therapeutics Program, USC-CHLA Institute for Pediatric Clinical Research, Division of Hematology-Oncology, Children' s Hospital Los Angeles, 4650 Sunset Blvd., Los Angeles, CA 90027 (United States); Ghent, Matthew V., E-mail: mattghent@gmail.com [Department of Pathology, Keck School of Medicine, University of Southern California, Health Sciences Campus, Los Angeles, CA 90089 (United States); Cabral, Daniel J., E-mail: dcabral14@gmail.com [Cancer Center and Departments of Cell Biology & Biochemistry, Pharmacology & Neuroscience, Internal Medicine and Pediatrics, School of Medicine, Texas Tech University Health Sciences Center, Lubbock, TX 79430 (United States); Lee, Joanne C., E-mail: joannebarnhart@gmail.com [Cancer Center and Departments of Cell Biology & Biochemistry, Pharmacology & Neuroscience, Internal Medicine and Pediatrics, School of Medicine, Texas Tech University Health Sciences Center, Lubbock, TX 79430 (United States); Khankaldyyan, Vazgen, E-mail: khangaldian@yahoo.com [Developmental Therapeutics Program, USC-CHLA Institute for Pediatric Clinical Research, Division of Hematology-Oncology, Children' s Hospital Los Angeles, 4650 Sunset Blvd., Los Angeles, CA 90027 (United States); Ji, Lingyun, E-mail: lingyun.ji@med.usc.edu [Developmental Therapeutics Program, USC-CHLA Institute for Pediatric Clinical Research, Division of Hematology-Oncology, Children' s Hospital Los Angeles, 4650 Sunset Blvd., Los Angeles, CA 90027 (United States); Wu, Samuel Q., E-mail: swu@chla.usc.edu [Medical Genetics, Children' s Hospital Los Angeles, 4650 Sunset Blvd., Los Angeles, CA 90027 (United States); Kang, Min H., E-mail: min.kang@ttuhsc.edu [Cancer Center and Departments of Cell Biology & Biochemistry, Pharmacology & Neuroscience, Internal Medicine and Pediatrics, School of Medicine, Texas Tech University Health Sciences Center, Lubbock, TX 79430 (United States); and others

    2015-05-15

    Cancer cells typically exhibit increased glycolysis and decreased mitochondrial oxidative phosphorylation, and they continue to exhibit some elevation in glycolysis even under aerobic conditions. However, it is unclear whether cancer cell lines employ a high level of glycolysis comparable to that of the original cancers from which they were derived, even if their culture conditions are changed to physiologically relevant oxygen concentrations. From three childhood acute lymphoblastic leukemia (ALL) patients we established three new pairs of cell lines in both atmospheric (20%) and physiologic (bone marrow level, 5%) oxygen concentrations. Cell lines established in 20% oxygen exhibited lower proliferation, survival, expression of glycolysis genes, glucose consumption, and lactate production. Interestingly, the effects of oxygen concentration used during cell line initiation were only partially reversible when established cell cultures were switched from one oxygen concentration to another for eight weeks. These observations indicate that ALL cell lines established at atmospheric oxygen concentration can exhibit relatively low levels of glycolysis and these levels are semi-permanent, suggesting that physiologic oxygen concentrations may be needed from the time of cell line initiation to preserve the high level of glycolysis commonly exhibited by leukemias in vivo. - Highlights: • Establishing new ALL cell lines in 5% oxygen resulted in higher glycolytic expression and function. • Establishing new ALL cell lines in 5% oxygen resulted in higher proliferation and lower cell death. • The divergent metabolic phenotypes selected in 5% and 20% oxygen are semi-permanent.

  1. 75 FR 17701 - High Energy Physics Advisory Panel

    Science.gov (United States)

    2010-04-07

    ... Energy Physics Advisory Panel AGENCY: Department of Energy, Office of Science. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the High Energy Physics Advisory Panel (HEPAP.... FOR FURTHER INFORMATION CONTACT: John Kogut, Executive Secretary; High Energy Physics Advisory Panel...

  2. 78 FR 50405 - High Energy Physics Advisory Panel

    Science.gov (United States)

    2013-08-19

    ... Energy Physics Advisory Panel AGENCY: Office of Science, Department of Energy. ACTION: Notice of Intent... hereby given that the High Energy Physics Advisory Panel will be renewed for a two-year period beginning...-range planning and priorities in the national high-energy physics program. Additionally, the renewal of...

  3. The Aer protein and the serine chemoreceptor Tsr independently sense intracellular energy levels and transduce oxygen, redox, and energy signals for Escherichia coli behavior

    Science.gov (United States)

    Rebbapragada, Anuradha; Johnson, Mark S.; Harding, Gordon P.; Zuccarelli, Anthony J.; Fletcher, Hansel M.; Zhulin, Igor B.; Taylor, Barry L.

    1997-01-01

    We identified a protein, Aer, as a signal transducer that senses intracellular energy levels rather than the external environment and that transduces signals for aerotaxis (taxis to oxygen) and other energy-dependent behavioral responses in Escherichia coli. Domains in Aer are similar to the signaling domain in chemotaxis receptors and the putative oxygen-sensing domain of some transcriptional activators. A putative FAD-binding site in the N-terminal domain of Aer shares a consensus sequence with the NifL, Bat, and Wc-1 signal-transducing proteins that regulate gene expression in response to redox changes, oxygen, and blue light, respectively. A double mutant deficient in aer and tsr, which codes for the serine chemoreceptor, was negative for aerotaxis, redox taxis, and glycerol taxis, each of which requires the proton motive force and/or electron transport system for signaling. We propose that Aer and Tsr sense the proton motive force or cellular redox state and thereby integrate diverse signals that guide E. coli to environments where maximal energy is available for growth. PMID:9380671

  4. Long Life, High Energy Cell Development Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA has a need to develop higher energy density battery systems to meet the power requirements of future energy devices. In this proposed Phase I program, PSI will...

  5. Modular, Reconfigurable, High-Energy Technology Development

    Science.gov (United States)

    Carrington, Connie; Howell, Joe

    2006-01-01

    The Modular, Reconfigurable High-Energy (MRHE) Technology Demonstrator project was to have been a series of ground-based demonstrations to mature critical technologies needed for in-space assembly of a highpower high-voltage modular spacecraft in low Earth orbit, enabling the development of future modular solar-powered exploration cargo-transport vehicles and infrastructure. MRHE was a project in the High Energy Space Systems (HESS) Program, within NASA's Exploration Systems Research and Technology (ESR&T) Program. NASA participants included Marshall Space Flight Center (MSFC), the Jet Propulsion Laboratory (JPL), and Glenn Research Center (GRC). Contractor participants were the Boeing Phantom Works in Huntsville, AL, Lockheed Martin Advanced Technology Center in Palo Alto, CA, ENTECH, Inc. in Keller, TX, and the University of AL Huntsville (UAH). MRHE's technical objectives were to mature: (a) lightweight, efficient, high-voltage, radiation-resistant solar power generation (SPG) technologies; (b) innovative, lightweight, efficient thermal management systems; (c) efficient, 100kW-class, high-voltage power delivery systems from an SPG to an electric thruster system; (d) autonomous rendezvous and docking technology for in-space assembly of modular, reconfigurable spacecraft; (e) robotic assembly of modular space systems; and (f) modular, reconfigurable distributed avionics technologies. Maturation of these technologies was to be implemented through a series of increasingly-inclusive laboratory demonstrations that would have integrated and demonstrated two systems-of-systems: (a) the autonomous rendezvous and docking of modular spacecraft with deployable structures, robotic assembly, reconfiguration both during assembly and (b) the development and integration of an advanced thermal heat pipe and a high-voltage power delivery system with a representative lightweight high-voltage SPG array. In addition, an integrated simulation testbed would have been developed

  6. Conversion of zero point energy into high-energy photons

    Energy Technology Data Exchange (ETDEWEB)

    Ivlev, B. I. [Universidad Autonoma de San Luis Potosi, Instituto de Fisica, Av. Manuel Nava No. 6, Zona Universitaria, 78290 San Luis Potosi, SLP (Mexico)

    2016-11-01

    An unusual phenomenon, observed in experiments is studied. X-ray laser bursts of keV energy are emitted from a metal where long-living states, resulting in population inversion, are totally unexpected. Anomalous electron-photon states are revealed to be formed inside the metal. These states are associated with narrow, 10{sup -11} cm, potential well created by the local reduction of zero point electromagnetic energy. In contrast to analogous van der Waals potential well, leading to attraction of two hydrogen atoms, the depth of the anomalous well is on the order of 1 MeV. The states in that well are long-living which results in population inversion and subsequent laser generation observed. The X-ray emission, occurring in transitions to lower levels, is due to the conversion of zero point electromagnetic energy. (Author)

  7. Oxygen therapy via high flow nasal cannula in pediatric intensive care unit.

    Science.gov (United States)

    Oto, Arzu; Erdoğan, Seher; Boşnak, Mehmet

    2016-01-01

    The aim of the present study was to assess the efficacy and safety of oxygen therapy via high flow nasal cannula in pediatric patients with acute respiratory failure. Patients who were admitted to pediatric intensive care unit and were administered high flow nasal cannula (HFNC) therapy between January 2015 and January 2016 were enrolled. Arterial blood gas parameters, respiratory rates (RR), heart rates (HR), systolic, db > iastolic, and mean arterial pressures (SBP, DBP, MAP), dyspnea scores, fractional oxygen indices (FiO 2 ), and oxygen saturations (SatO 2 ) were recorded at baseline, 30 minutes, and 12 hours. The study enrolled a total of 50 patients of whom 24 (48%) were female and 26 (52%) were male. Statistically significant reductions occurred in mean HR and RR values at 30 minutes and 12 hours compared to those at 0 minute (p 2 values at 30 minutes and 12 hours compared to baseline (p 2 , PaO 2 , SBP, and DBP values at 0 minute, 30 minutes, and 12 hours were not significantly different from one another (p > 0.05). No significant correlations were found between treatment failure and age at admission; mean pediatric index of mortality (PIM II), pediatric risk of mortality (PRISM), pediatric logistic organ dysfunction (PELOD) and pediatric multiple organ dysfunction score (P-MODS); and HR, RR, SatO2, pH, PaCO2, PaO2, SBP, DBP, MAP, FiO2 at baseline (p > 0.05). Therapy was successful in 40 (80%) patients whereas there occurred a need for invasive ventilation in 10 (20%) patients. High flow nasal oxygen therapy can be used for patients with acute severe hypoxemic respiratory failure without concurrent hypercapnia when adequate equipment and monitorization tools exist.

  8. Pilot plant demonstration of stable and efficient high rate biological nutrient removal with low dissolved oxygen conditions.

    Science.gov (United States)

    Keene, Natalie A; Reusser, Steve R; Scarborough, Matthew J; Grooms, Alan L; Seib, Matt; Santo Domingo, Jorge; Noguera, Daniel R

    2017-09-15

    Aeration in biological nutrient removal (BNR) processes accounts for nearly half of the total electricity costs at many wastewater treatment plants. Even though conventional BNR processes are usually operated to have aerated zones with high dissolved oxygen (DO) concentrations, recent research has shown that nitrification can be maintained using very low-DO concentrations (e.g., below 0.2 mg O2/L), and therefore, it may be possible to reduce energy use and costs in BNR facilities by decreasing aeration. However, the effect of reduced aeration on enhanced biological phosphorus removal (EBPR) is not understood. In this study, we investigated, at the pilot-scale level, the effect of using minimal aeration on the performance of an EBPR process. Over a 16-month operational period, we performed stepwise decreases in aeration, reaching an average DO concentration of 0.33 mg O2/L with stable operation and nearly 90% phosphorus removal. Under these low-DO conditions, nitrification efficiency was maintained, and nearly 70% of the nitrogen was denitrified, without the need for internal recycling of high nitrate aeration basin effluent to the anoxic zone. At the lowest DO conditions used, we estimate a 25% reduction in energy use for aeration compared to conventional BNR operation. Our improved understanding of the efficiency of low-DO BNR contributes to the global goal of reducing energy consumption during wastewater treatment operations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Low Energy Lorentz Violation from Modified Dispersion at High Energies.

    Science.gov (United States)

    Husain, Viqar; Louko, Jorma

    2016-02-12

    Many quantum theories of gravity propose Lorentz-violating dispersion relations of the form ω=|k|f(|k|/M⋆), with recovery of approximate Lorentz invariance at energy scales much below M⋆. We show that a quantum field with this dispersion predicts drastic low energy Lorentz violation in atoms modeled as Unruh-DeWitt detectors, for any f that dips below unity somewhere. As an example, we show that polymer quantization motivated by loop quantum gravity predicts such Lorentz violation below current ion collider rapidities.

  10. Activation Energy Measurement of Oxygen Ordering in a Nb-Ti Alloy by Anelastic Relaxation

    Directory of Open Access Journals (Sweden)

    Niemeyer T.C.

    2002-01-01

    Full Text Available Metals with bcc structure are able to dissolve large amounts of interstitial element atoms in the form of oxygen. These atoms diffuse through the lattice by jumping into octahedral sites with equivalent symmetry, causing strong alterations in the anelastic behavior. This paper reports on a study of Snoek relaxation in Nb-Ti alloys with oxygen in solid solution, based on internal friction as a function of temperature. The internal friction measurements were taken in a torsion pendulum operating at temperatures in the range of 350 to 650 K, with frequencies varying from 6 to 36 Hz. The results show relaxation spectra in which thermally activated relaxation peaks produced by the stress-induced ordering of oxygen atoms around niobium atoms of the metallic matrix were identified.

  11. Interpreting New Data from the High Energy Frontier

    Energy Technology Data Exchange (ETDEWEB)

    Thaler, Jesse [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

    2016-09-26

    This is the final technical report for DOE grant DE-SC0006389, "Interpreting New Data from the High Energy Frontier", describing research accomplishments by the PI in the field of theoretical high energy physics.

  12. Antennas tune in to high-energy particles

    CERN Document Server

    Gorham, P W

    2001-01-01

    After 40 years of research, physicists met at the first international workshop on the radio detection of high energy particles to discuss the detection of high-energy cosmic rays and neutrinos using radio waves. (0 refs).

  13. Jet Physics at High Energy Colliders

    Science.gov (United States)

    Chien, Yang-Ting

    The future of new physics searches at the LHC will be to look for hadronic signals with jets. In order to distinguish a hadronic signal from its background, it is important to develop advanced collider physics techniques that make accurate theoretical predictions. This work centers on phenomenological and formal studies of Quantum Chromodynamics (QCD), including resummation of hadronic observables using Soft Collinear Effective Theory (SCET), calculating anomalous dimensions of multi-Wilson line operators in AdS, and improving jet physics analysis using multiple event interpretations. Hadronic observables usually involve physics at different energy scales, and the calculations depend on large logarithms of the energy ratios. We can prove factorization theorems of observables and resum large logarithms using renormalization-group techniques. The heavy jet mass distribution for e +e- collisions is calculated at next-to-next-to-next-to leading logarithmic order (N3LL), and we measure the strong coupling constant at 0.3% accuracy. We also calculate the jet-mass distribution at partial N2LL in gamma + jet events at the LHC. The effect of non-global logarithms in resummation estimated, and it is significant only at the peak region. Soft QCD interactions among jets can be described by multi-Wilson line operators, with each Wilson line pointing along one of the jet directions. The anomalous dimensions of these operators are key for higher-order resummation. We study these operators using radial quantization and conformal gauge, which leads to a drastic simplification of the two-loop anomalous dimension calculation. We also find that the anomalous dimension calculation is closely related to a corresponding Witten diagram calculation. Jets are complicated objects to identify in high energy collider experiments. A single interpretation of each event can only extract a limited amount of information. We propose telescoping jet algorithms which give multiple event

  14. Ab initio calculation of the migration free energy of oxygen diffusion in pure and samarium-doped ceria

    Science.gov (United States)

    Koettgen, Julius; Schmidt, Peter C.; Bučko, Tomáš; Martin, Manfred

    2018-01-01

    We have studied the free energy migration barriers Δ F‡ for oxygen diffusion in pure ceria and Sm-doped ceria for the temperatures 300, 700, and 1000 K. We used the density functional theory in the generalized gradient approximation and an additional Hubbard U parameter for the Ce 4 f electronic states. We compare the results for the free energy deduced from three different methods. First, a static harmonic approach is applied in which the temperature dependent vibrational contributions to energy and entropy are deduced from the phonon frequencies of supercells with a fixed volume. Second, a static quasiharmonic approach is used in which a part of the anharmonicity effect is introduced via an implicit dependence of the harmonic frequencies on the thermally expanding cell volume. Third, the free energy barriers are calculated using metadynamics and molecular dynamics in which anharmonicity effects are naturally taken into account. The three methods examined in this study lead to distinctly different results. According to the harmonic approximation, the migration free energy difference Δ F‡ increases with increasing temperature due to an increasing entropic contribution. According to the quasiharmonic approximation, the migration free energy is independent of temperature. Finally, molecular dynamics predicts a thermally induced increase in the migration free energy. We conclude that temperature dependent experimental lattice constants cancel out the increasing entropic contribution with increasing temperature in the static quasiharmonic approach. The full consideration of anharmonicity effects in the metadynamics method again leads to a temperature dependent migration free energy.

  15. High Capacity Cathode Materials for Next Generation Energy Storage

    Science.gov (United States)

    Papandrea, Benjamin John

    Energy storage devices are of increasing importance for applications in mobile electronics, hybrid electric vehicles, and can also play a critical role in renewable energy harvesting, conversion and storage. Since its commercial inception in the 1990's, the lithium-ion battery represents the dominant energy storage technology for mobile power supply today. However, the total capacity of lithium-ion batteries is largely limited by the theoretical capacities of the cathode materials such as LiCoO2 (272 mAh g-1), and LiFePO4 (170 mAh g-1), and cannot satisfy the increasing consumer demand, thus new cathode materials with higher capacities must be explored. Two of the most promising cathode materials with significantly larger theoretical capacities are sulfur (1675 mAh g-1) and air, specifically the oxygen (3840 mAh g-1). However, the usage of either of these cathodic materials is plagued with numerous issues that must be overcome before their commercialization. In the first part of my dissertation, we investigated the usage of a three-dimensional graphene membrane for a high energy density lithium-air (Li-Air) battery in ambient condition. One of the issues with Li-Air batteries is the many side reaction that can occur during discharge in ambient condition, especially with water vapor. Using a hydrophobic tortuous three-dimensional graphene membrane we are able to inhibit the diffusion of water vapor and create a lithium-air battery that cycles over 2000 times with a capacity limited at 140 mAh g-1, over 100 cycles with a capacity limited at 1425 mAh g-1, and over 20 cycles at the high capacity of 5700 mAh g-1. In the second part of my dissertation, we investigate the usage of a three-dimensional graphene aerogel to maximize the loading of sulfur to create a freestanding electrode with high capacity for a lithium-sulfur (Li-S) battery. We demonstrated that our three-dimensional graphene aerogel could sustain a loading of 95% by weight, and we achieved a capacity of

  16. Oxygen adsorption on Cu(111) using low energy ion scattering spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, F.M.; Yao, J.; Shen, Y.G.; King, B.V.; O`Connor, D.J. [Newcastle Univ., NSW (Australia). Dept. of Physics

    1993-12-31

    The surface structure and oxygen adsorption of Cu(l 11) have been studied by 2 keV Li{sup +}, He{sup +} and Ar{sup +} ion scattering . Incident and azimuthal dependences were measured for the clean and O-covered surfaces, and the surface geometry was analysed on the basis of the shadowing features. Experimental results under different oxygen exposures at room temperature showed that the Cu(l 11) surface undergoes a roughening transition and results in a reconstruction where Cu atoms are vertically displaced by about 0.23 Angstroms. 4 refs., 4 figs.

  17. The role of oxygen-increased respirator in humans ascending to high altitude

    Directory of Open Access Journals (Sweden)

    Shen Guanghao

    2012-08-01

    Full Text Available Abstract Background Acute mountain sickness (AMS is common for people who live in low altitude areas ascending to the high altitude. Many instruments have been developed to treat mild cases of AMS. However, long-lasting and portable anti-hypoxia equipment for individual is not yet available. Methods Oxygen-increased respirator (OIR has been designed to reduce the risk of acute mountain sickness in acute exposure to low air pressure. It can increase the density of oxygen by increasing total atmospheric pressure in a mask. Male subjects were screened, and eighty-eight were qualified to perform the experiments. The subjects were divided into 5 groups and were involved in some of the tests at 4 different altitudes (Group 1, 2: 3700 m; Group 3,4,5: 4000 m, 4700 m, 5380 m with and without OIR. These tests include heart rate, saturation of peripheral oxygen (SpO2, malondialdehyde (MDA, superoxide dismutase (SOD, blood lactate (BLA and PWC (physical work capacity -170. Results The results showed that higher SpO2, lower heart rate (except during exercise and better recovery of heart rate were observed from all the subjects ’with OIR’ compared with ’without OIR’ (P Conclusions We suggested that OIR may play a useful role in protecting people ascending to high altitude before acclimatization.

  18. High-Flow Nasal Interface Improves Oxygenation in Patients Undergoing Bronchoscopy

    Directory of Open Access Journals (Sweden)

    Umberto Lucangelo

    2012-01-01

    Full Text Available During bronchoscopy hypoxemia is commonly found and oxygen supply can be delivered by interfaces fed with high gas flows. Recently, the high-flow nasal cannula (HFNC has been introduced for oxygen therapy in adults, but they have not been used so far during bronchoscopy in adults. Forty-five patients were randomly assigned to 3 groups receiving oxygen: 40 L/min through a Venturi mask (V40, N=15, nasal cannula (N40, N=15, and 60 L/min through a nasal cannula (N60, N=15 during bronchoscopy. Gas exchange and circulatory variables were sampled before (FiO2 = 0.21, at the end of bronchoscopy (FiO2 = 0.5, and thereafter (V40, FiO2 = 0.35. In 8 healthy volunteers oxygen was randomly delivered according to V40, N40, and N60 settings, and airway pressure was measured. At the end of bronchoscopy, N60 presented higher PaO2, PaO2/FiO2, and SpO2 than V40 and N40 that did not differ between them. In the volunteers (N60 median airway pressure amounted to 3.6 cmH2O. Under a flow rate of 40 L/min both the Venturi mask and HFNC behaved similarly, but nasal cannula associated with a 60 L/min flow produced the better results, thus indicating its use in mild respiratory dysfunctions.

  19. Industrial glucoamylase fed‐batch benefits from oxygen limitation and high osmolarity

    DEFF Research Database (Denmark)

    Pedersen, Lasse; Hansen, Kim; Nielsen, Jens

    2012-01-01

    The market for glucoamylase is large and very competitive and the production process has been optimized through several decades. So far a thorough characterization of the process has not been published, but previous academic reports suggest that the process suffers from severe byproduct formation...... Periodicals, Inc........ An alternative process with low glucose concentration show that high osmolarity is beneficial for the process, and we conclude that oxygen limitation, high osmolarity, and the associated byproduct metabolism are important for the efficiency of the process. Biotechnol. Bioeng. 2012;109: 116–124. © 2011 Wiley...

  20. A first-principles study of carbon-related energy levels in GaN. II. Complexes formed by carbon and hydrogen, silicon or oxygen

    Science.gov (United States)

    Matsubara, Masahiko; Bellotti, Enrico

    2017-05-01

    This work presents an in-depth investigation of the properties of complexes composed of hydrogen, silicon, or oxygen with carbon, which are the major unintentional impurities in undoped GaN. This manuscript is a complement to our previous work on carbon-carbon and carbon-vacancy complexes. We have employed a first-principles method using Heyd-Scuseria-Ernzerhof hybrid functionals within the framework of generalized Kohn-Sham density functional theory. Two H-C, four Si-C, and five O-C complexes in different charge states have been considered. After full geometry relaxations, formation energies, binding energies, and both thermal and optical transition levels were obtained. The calculated energy levels have been systematically compared with the experimentally observed carbon related trap levels. Furthermore, we computed vibrational frequencies for selected defect complexes and defect concentrations were estimated in the low, mid, and high carbon doping scenarios considering two different cases where electrically active defects: (a) only carbon and vacancies and (b) not only carbon and vacancies but also hydrogen, silicon, and oxygen. We confirmed that CN is a dominant acceptor in GaN. In addition to it, a substantial amount of SiGa-CN complex exists in a neutral form. This complex is a likely candidate for the unknown form of carbon observed in undoped n-type GaN.

  1. Oklahoma Center for High Energy Physics (OCHEP)

    Energy Technology Data Exchange (ETDEWEB)

    Nandi, S; Strauss, M J; Snow, J; Rizatdinova, F; Abbott, B; Babu, K; Gutierrez, P; Kao, C; Khanov, A; Milton, K A; Neaman, H; H Severini, P Skubic

    2012-02-29

    The DOE EPSCoR implementation grant, with the support from the State of Oklahoma and from the three universities, Oklahoma State University, University of Oklahoma and Langston University, resulted in establishing of the Oklahoma Center for High Energy Physics (OCHEP) in 2004. Currently, OCHEP continues to flourish as a vibrant hub for research in experimental and theoretical particle physics and an educational center in the State of Oklahoma. All goals of the original proposal were successfully accomplished. These include foun- dation of a new experimental particle physics group at OSU, the establishment of a Tier 2 computing facility for the Large Hadron Collider (LHC) and Tevatron data analysis at OU and organization of a vital particle physics research center in Oklahoma based on resources of the three universities. OSU has hired two tenure-track faculty members with initial support from the grant funds. Now both positions are supported through OSU budget. This new HEP Experimental Group at OSU has established itself as a full member of the Fermilab D0 Collaboration and LHC ATLAS Experiment and has secured external funds from the DOE and the NSF. These funds currently support 2 graduate students, 1 postdoctoral fellow, and 1 part-time engineer. The grant initiated creation of a Tier 2 computing facility at OU as part of the Southwest Tier 2 facility, and a permanent Research Scientist was hired at OU to maintain and run the facility. Permanent support for this position has now been provided through the OU university budget. OCHEP represents a successful model of cooperation of several universities, providing the establishment of critical mass of manpower, computing and hardware resources. This led to increasing Oklahoma's impact in all areas of HEP, theory, experiment, and computation. The Center personnel are involved in cutting edge research in experimental, theoretical, and computational aspects of High Energy Physics with the research areas ranging

  2. Spin structure in high energy processes

    Science.gov (United States)

    Deporcel, L.; Dunwoodie, C.

    1994-12-01

    This report contains papers of the following topics: Spin, Mass, and Symmetry; physics with polarized Z(sup 0)s; spin and precision electroweak physics; polarized electron sources; polarization phenomena in quantum chromodynamics; polarized lepton-nucleon scattering; polarized targets in high energy physics; spin dynamics in storage rings and linear accelerators; spin formalism and applications to new physics searches; precision electroweak physics at LEP; recent results on heavy flavor physics from LEP experiments using 1990--1992 data; precise measurement of the left-right cross section asymmetry in Z boson production by electron-positron collisions; preliminary results on heavy flavor physics at SLD; QCD tests with SLD and polarized beams; recent results from TRISTAN at KEK; recent B physics results from CLEO; searching for the H dibaryon at Brookhaven; recent results from the compton observatory; the spin structure of the deuteron; spin structure of the neutron ((sup 3)HE) and the Bjoerken sum rule; a consumer's guide to lattice QCD results; top ten models constrained by b yields sy; a review of the Fermilab fixed target program; results from the D0 experiment; results from CDF at FNAL; quantum-mechanical suppression of bremsstrahlung; report from the ZEUS collaboration at HERA; physics from the first year of H1 at HERA, and hard diffraction. These papers have been cataloged separately elsewhere.

  3. Nuclear and High-Energy Astrophysics

    Science.gov (United States)

    Weber, Fridolin

    2003-10-01

    There has never been a more exciting time in the overlapping areas of nuclear physics, particle physics and relativistic astrophysics than today. Orbiting observatories such as the Hubble Space Telescope, Rossi X-ray Timing Explorer (RXTE), Chandra X-ray satellite, and the X-ray Multi Mirror Mission (XMM) have extended our vision tremendously, allowing us to see vistas with an unprecedented clarity and angular resolution that previously were only imagined, enabling astrophysicists for the first time ever to perform detailed studies of large samples of galactic and extragalactic objects. On the Earth, radio telescopes (e.g., Arecibo, Green Bank, Parkes, VLA) and instruments using adaptive optics and other revolutionary techniques have exceeded previous expectations of what can be accomplished from the ground. The gravitational wave detectors LIGO, LISA VIRGO, and Geo-600 are opening up a window for the detection of gravitational waves emitted from compact stellar objects such as neutron stars and black holes. Together with new experimental forefront facilities like ISAC, ORLAND and RIA, these detectors provide direct, quantitative physical insight into nucleosynthesis, supernova dynamics, accreting compact objects, cosmic-ray acceleration, and pairproduction in high energy sources which reinforce the urgent need for a strong and continuous feedback from nuclear and particle theory and theoretical astrophysics. In my lectures, I shall concentrate on three selected topics, which range from the behavior of superdense stellar matter, to general relativistic stellar models, to strange quark stars and possible signals of quark matter in neutron stars.

  4. Automatic keywording of High Energy Physics

    CERN Document Server

    Dallman, David Peter

    1999-01-01

    Bibliographic databases were developed from the traditional library card catalogue in order to enable users to access library documents via various types of bibliographic information, such as title, author, series or conference date. In addition these catalogues sometimes contained some form of indexation by subject, such as the Universal (or Dewey) Decimal Classification used for books. With the introduction of the eprint archives, set up by the High Energy Physics (HEP) Community in the early 90s, huge collections of documents in several fields have been made available on the World Wide Web. These developments however have not yet been followed up from a keywording point of view. We will see in this paper how important it is to attribute keywords to all documents in the area of HEP Grey Literature. As libraries are facing a future with less and less manpower available and more and more documents, we will explore the possibility of being helped by automatic classification software. We will specifically menti...

  5. Spin structure in high energy processes: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    DePorcel, L.; Dunwoodie, C. [eds.

    1994-12-01

    This report contains papers as the following topics: Spin, Mass, and Symmetry; physics with polarized Z{sup 0}s; spin and precision electroweak physics; polarized electron sources; polarization phenomena in quantum chromodynamics; polarized lepton-nucleon scattering; polarized targets in high energy physics; spin dynamics in storage rings and linear accelerators; spin formalism and applications to new physics searches; precision electroweak physics at LEP; recent results on heavy flavor physics from LEP experiments using 1990--1992 data; precise measurement of the left-right cross section asymmetry in Z boson production by electron-positron collisions; preliminary results on heavy flavor physics at SLD; QCD tests with SLD and polarized beams; recent results from TRISTAN at KEK; recent B physics results from CLEO; searching for the H dibaryon at Brookhaven; recent results from the compton observatory; the spin structure of the deuteron; spin structure of the neutron ({sup 3}HE) and the Bjoerken sum rule; a consumer`s guide to lattice QCD results; top ten models constrained by b {yields} sy; a review of the Fermilab fixed target program; results from the D0 experiment; results from CDF at FNAL; quantum-mechanical suppression of bremsstrahlung; report from the ZEUS collaboration at HERA; physics from the first year of H1 at HERA, and hard diffraction. These papers have been cataloged separately elsewhere.

  6. Aspen Winter Conferences on High Energy

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2011-02-12

    The 2011 Aspen Winter Conference on Particle Physics was held at the Aspen Center for Physics from February 12 to February 18, 2011. Ninety-four participants from ten countries, and several universities and national labs attended the workshop titled, "New Data From the Energy Frontier." There were 54 formal talks, and a considerable number of informal discussions held during the week. The week's events included a public lecture ("The Hunt for the Elusive Higgs Boson" given by Ben Kilminster from Ohio State University) and attended by 119 members of the public, and a physics cafe geared for high schoolers that is a discussion with physicists. The 2011 Aspen Winter Conference on Astroparticle physics held at the Aspen Center for Physics was "Indirect and Direct Detection of Dark Matter." It was held from February 6 to February 12, 2011. The 70 participants came from 7 countries and attended 53 talks over five days. Late mornings through the afternoon are reserved for informal discussions. In feedback received from participants, it is often these unplanned chats that produce the most excitement due to working through problems with fellow physicists from other institutions and countries or due to incipient collaborations. In addition, Blas Cabrera of Stanford University gave a public lecture titled "What Makes Up Dark Matter." There were 183 members of the general public in attendance. Before the lecture, 45 people attended the physics cafe to discuss dark matter. This report provides the attendee lists, programs, and announcement posters for each event.

  7. High Energy Electron Detectors on Sphinx

    Science.gov (United States)

    Thompson, J. R.; Porte, A.; Zucchini, F.; Calamy, H.; Auriel, G.; Coleman, P. L.; Bayol, F.; Lalle, B.; Krishnan, M.; Wilson, K.

    2008-11-01

    Z-pinch plasma radiation sources are used to dose test objects with K-shell (˜1-4keV) x-rays. The implosion physics can produce high energy electrons (> 50keV), which could distort interpretation of the soft x-ray effects. We describe the design and implementation of a diagnostic suite to characterize the electron environment of Al wire and Ar gas puff z-pinches on Sphinx. The design used ITS calculations to model detector response to both soft x-rays and electrons and help set upper bounds to the spurious electron flux. Strategies to discriminate between the known soft x-ray emission and the suspected electron flux will be discussed. H.Calamy et al, ``Use of microsecond current prepulse for dramatic improvements of wire array Z-pinch implosion,'' Phys Plasmas 15, 012701 (2008) J.A.Halbleib et al, ``ITS: the integrated TIGER series of electron/photon transport codes-Version 3.0,'' IEEE Trans on Nuclear Sci, 39, 1025 (1992)

  8. Three Decades of High Energy Transients

    Science.gov (United States)

    Kouveliotou, Chryssa

    2012-01-01

    Gamma-Ray Bursts are the most brilliant explosions in space. The first GRB was discovered on 1967, just over 40 years ago. It took several years and multiple generations of space and ground instruments to unravel some of the mysteries of this phenomenon. However, many questions remain open today. I will discuss the history, evolution and current status of the GRB field and its contributions in our understanding of the transient high energy sky. Finally, I will describe how GRBs can be utilized in future missions as tools, to probe the cosmic chemical evolution of the Universe Magnetars are magnetically powered rotating neutron stars with extreme magnetic fields (over 10(exp 14) Gauss). They were discovered in the X- and gamma-rays where they predominantly emit their radiation. Very few sources (roughly 24) have been found since their discovery in 1987. NASA's Fermi Gamma-ray Space Telescope was launched June 11, 2009; since then the Fermi Gamma-ray Burst Monitor (GBM) recorded emission from several magnetar sources. In total, six new sources were discovered between 2008 and 2011, with a synergy between Swift, RXTE, Fermi and the Interplanetary Network (IPN). I will give a short history of magnetars and describe how this, once relatively esoteric field, has emerged as a link between several astrophysical areas including Gamma-Ray Bursts.

  9. Precision probes of QCD at high energies

    Science.gov (United States)

    Alioli, Simone; Farina, Marco; Pappadopulo, Duccio; Ruderman, Joshua T.

    2017-07-01

    New physics, that is too heavy to be produced directly, can leave measurable imprints on the tails of kinematic distributions at the LHC. We use energetic QCD processes to perform novel measurements of the Standard Model (SM) Effective Field Theory. We show that the dijet invariant mass spectrum, and the inclusive jet transverse momentum spectrum, are sensitive to a dimension 6 operator that modifies the gluon propagator at high energies. The dominant effect is constructive or destructive interference with SM jet production. We compare differential next-to-leading order predictions from POWHEG to public 7 TeV jet data, including scale, PDF, and experimental uncertainties and their respective correlations. We constrain a New Physics (NP) scale of 3.5 TeV with current data. We project the reach of future 13 and 100 TeV measurements, which we estimate to be sensitive to NP scales of 8 and 60 TeV, respectively. As an application, we apply our bounds to constrain heavy vector octet colorons that couple to the QCD current. We project that effective operators will surpass bump hunts, in terms of coloron mass reach, even for sequential couplings.

  10. Data Preservation in High Energy Physics

    Energy Technology Data Exchange (ETDEWEB)

    Mount, Richard; Brooks, Travis; /SLAC; Le Diberder, Francois; /Orsay, LAL; Dubois-Felsmann, Gregory; Neal, Homer; /SLAC; Bellis, Matt; /Stanford U.; Boehnlein, Amber; Votava, Margaret; White, Vicky; Wolbers, Stephen; /Fermilab; Konigsberg, Jacobo; /Florida U.; Roser, Robert; Snider, Rick; /Fermilab; Lucchesi, Donatella; /INFN, Padua; Denisov, Dmitri; /Fermilab; Soldner-Rembold, Stefan; /Manchester U.; Li, Qizhong; /Fermilab; Varnes, Erich; /Arizona U.; Jonckheere, Alan; /Fermilab; Gasthuber, Martin; Gulzow, Volker; /DESY /Marseille, CPPM /Dortmund U. /DESY /Gent U. /DESY, Zeuthen /KEK, Tsukuba /CC, Villeurbanne /CERN /INFN, Bari /Gjovik Coll. Engineering /Karlsruhe, Forschungszentrum /Beijing, Inst. High Energy Phys. /Carleton U. /Cornell U. /Rutherford

    2012-04-03

    Data from high-energy physics (HEP) experiments are collected with significant financial and human effort and are mostly unique. At the same time, HEP has no coherent strategy for data preservation and re-use. An inter-experimental Study Group on HEP data preservation and long-term analysis was convened at the end of 2008 and held two workshops, at DESY (January 2009) and SLAC (May 2009). This document is an intermediate report to the International Committee for Future Accelerators (ICFA) of the reflections of this Study Group. Large data sets accumulated during many years of detector operation at particle accelerators are the heritage of experimental HEP. These data sets offer unique opportunities for future scientific studies, sometimes long after the shut-down of the actual experiments: new theoretical input; new experimental results and analysis techniques; the quest for high-sensitivity combined analyses; the necessity of cross checks. In many cases, HEP data sets are unique; they cannot and most likely will not be superseded by data from newer generations of experiments. Once lost, or in an unusable state, HEP data samples cannot be reasonably recovered. The cost of conserving this heritage through a collaborative, target-oriented long-term data preservation program would be small, compared to the costs of past experimental projects or to the efforts to re-do experiments. However, this cost is not negligible, especially for collaborations close or past their end-date. The preservation of HEP data would provide today's collaborations with a secure way to complete their data analysis and enable them to seize new scientific opportunities in the coming years. The HEP community will benefit from preserved data samples through reanalysis, combination, education and outreach. Funding agencies would receive more scientific return, and a positive image, from their initial investment leading to the production and the first analysis of preserved data.

  11. High specific energy, high capacity nickel-hydrogen cell design

    Science.gov (United States)

    Wheeler, James R.

    1993-01-01

    A 3.5 inch rabbit-ear-terminal nickel-hydrogen cell was designed and tested to deliver high capacity at steady discharge rates up to and including a C rate. Its specific energy yield of 60.6 wh/kg is believed to be the highest yet achieved in a slurry-process nickel-hydrogen cell, and its 10 C capacity of 113.9 AH the highest capacity yet of any type in a 3.5 inch diameter size. The cell also demonstrated a pulse capability of 180 amps for 20 seconds. Specific cell parameters and performance are described. Also covered is an episode of capacity fading due to electrode swelling and its successful recovery by means of additional activation procedures.

  12. High Flow Nasal Cannula Oxygen Therapy can be used safely in the general paediatric ward using Paediatric Early Warning Scores

    NARCIS (Netherlands)

    Morsing, IE; Tinnevelt, Marcel; Jansen, Nicolaas J.G.; Koomen, E

    2015-01-01

    High Flow Nasal Cannula oxygen therapy (HFNC) is nowadays widely used at paediatric intensive care units (PICU) to provide a safe and comfortable (warm and humidified) oxygen delivery in children with respiratory distress. At general paediatric wards HFNC is hardly used because intensive observation

  13. Machine Protection and High Energy Density States in Matter for High Energy Hadron Accelerators

    CERN Document Server

    Blanco Sancho, Juan; Schmidt, R

    The Large Hadron Collider (LHC) is the largest accelerator in the world. It is designed to collide two proton beams with unprecedented particle energy of 7TeV. The energy stored in each beam is 362MJ, sufficient to melt 500kg of copper. An accidental release of even a small fraction of the beam energy can result in severe damage to the equipment. Machine protection systems are essential to safely operate the accelerator and handle all possible accidents. This thesis deals with the study of different failure scenarios and its possible consequences. It addresses failure scenarios ranging from low intensity losses on high-Z materials and superconductors to high intensity losses on carbon and copper collimators. Low beam losses are sufficient to quench the superconducting magnets and the stabilized superconducting cables (bus-bars) that connects the main magnets. If this occurs and the energy from the bus-bar is not extracted fast enough it can lead to a situation similar to the accident in 2008 at LHC during pow...

  14. High fluence laser irradiation induces reactive oxygen species generation in human lung adenocarcinoma cells

    Science.gov (United States)

    Wang, Fang; Xing, Da; Chen, Tong-Sheng

    2006-09-01

    Low-power laser irradiation (LPLI) has been used for therapies such as curing spinal cord injury, healing wound et al. Yet, the mechanism of LPLI remains unclear. Our previous study showed that low fluences laser irradiation induces human lung adenocarcinoma cells (ASTC-a-1) proliferation, but high fluences induced apoptosis and caspase-3 activation. In order to study the mechanism of apoptosis induced by high fluences LPLI further, we have measured the dynamics of generation of reactive oxygen species (ROS) using H IIDCFDA fluorescence probes during this process. ASTC-a-1 cells apoptosis was induced by He-Ne laser irradiation at high fluence of 120J/cm2. A confocal laser scanning microscope was used to perform fluorescence imaging. The results demonstrated that high fluence LPLI induced the increase of mitochondria ROS. Our studies contribute to clarify the biological mechanism of high fluence LPLI-induced cell apoptosis.

  15. Crossed Optical Fiber Sensor Arrays for High-Spatial-Resolution Sensing: Application to Dissolved Oxygen Concentration Measurements

    Directory of Open Access Journals (Sweden)

    M. Veronica Rigo

    2012-01-01

    Full Text Available Optical fiber sensors using luminescent probes located along an optical fiber in the cladding of this fiber are of great interest for monitoring physical and chemical properties in their environment. The interrogation of a luminophore with a short laser pulse propagating through the fiber core allows for the measurement of the location of these luminophores. To increase the spatial resolution of such a measurements and to measure multiple analytes and properties in a confined space, a crossed optical fiber sensing platform can be employed. Here we describe the application of this platform to measuring the concentration of dissolved oxygen. The sensor is based on luminescence quenching of a ruthenium complex immobilized in a highly crosslinked film and covalently attached to the optical fibers. Both luminescence-intensity and luminescence-lifetime changes of the sensor molecules in response to changes in the concentration of oxygen dissolved in water are reported. For luminescence-intensity measurements, a second adjacent sensor region is employed as reference to account for laser pulse energy fluctuations. Enhanced quenching response in water is demonstrated by the use of organically modified poly(ethylene glycol precursors, which increase the hydrophobicity of the film surface.

  16. Synthesis of halogen-doped reduced graphene oxide nanosheets as highly efficient metal-free electrocatalyst for oxygen reduction reaction.

    Science.gov (United States)

    Kakaei, Karim; Balavandi, Amin

    2016-02-01

    We demonstrate F-, Cl-, Br- and I-doped reduced graphene oxide (XRGO) as metal-free graphene electro-catalysts for oxygen reduction reaction (ORR) in alkaline media. Reduced graphene oxide (GO) is prepared from graphite electrode using electrochemical exfoliation. In situ doping of halide in a graphene film has many problems. In this technique, different halides individually or all of them were mixed with the RGO and ionic liquids precursor at H2SO4 solution. Then we have evaluated the effectiveness of doping and performed electrochemical measurements of the ORR activity on XRGO. Fourier-transform infrared spectroscopy spectra show a variety of the halogen-containing functional groups. Energy-dispersive X-ray spectroscopy analysis confirmed the presence of doped halogens in RGO. Raman spectroscopy shows a high density of defects in the RGO layer. The electrochemical properties of the XRGO catalysts on carbon paper as a gas diffusion electrode (GDE) are investigated by several electrochemical methods in oxygen saturated alkaline solutions. The catalytic activity of the XRGO and Pt-C electrodes for ORR is 50 and 30mAcm(-2) at -1V in GDEs. This enhanced efficiency is the result of the influence of the nature and percentage of the halogen, especially fluorine presence in the graphene layer. Copyright © 2015 Elsevier Inc. All rights reserved.

  17. Investigation of the storage and release of oxygen in a Cu-Pt element of a high-temperature microcombustor

    Science.gov (United States)

    Khaji, Z.; Sturesson, P.; Hjort, K.; Klintberg, L.; Thornell, G.

    2014-11-01

    A miniature combustor for converting organic samples into CO2 with application in carbon isotopic measurements has been manufactured and evaluated. The combustor was made of High-Temperature Co-fired Ceramic (HTCC) alumina green tapes. The device has a built-in screen printed heater and a temperature sensor made of platinum, co-sintered with the ceramic. A copper oxide oxygen supply was added to the combustor after sintering by in-situ electroplating of copper on the heater pattern followed by thermal oxidation. Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Thermal Gravimetric Analysis (TGA) were used to study electroplating, oxidation and the oxide reduction processes. The temperature sensor was calibrated by use of a thermocouple. It demonstrates a temperature coefficient resistance of 4.66×10-3/°C between 32 and 660 °C. The heat characterization was done up to 1000 °C by using IR thermography, and the results were compared with the data from the temperature sensor. Combustion of starch confirmed the feasibility of using copper oxide as the source of oxygen of combustion.

  18. Formation of Nanocones on Highly Oriented Pyrolytic Graphite by Oxygen Plasma

    Directory of Open Access Journals (Sweden)

    Alenka Vesel

    2014-03-01

    Full Text Available Improvement in hemocompatibility of highly oriented pyrolytic graphite (HOPG by formation of nanostructured surface by oxygen plasma treatment is reported. We have showed that by appropriate fine tuning of plasma and discharge parameters we are able to create nanostructured surface which is densely covered with nanocones. The size of the nanocones strongly depended on treatment time. The optimal results in terms of material hemocompatibility were obtained after treatment with oxygen plasma for 15 s, when both the nanotopography and wettability were the most favorable, since marked reduction in adhesion and activation of platelets was observed on this surface. At prolonged treatment times, the rich surface topography was lost and thus also its antithrombogenic properties. Chemical composition of the surface was always more or less the same, regardless of its morphology and height of the nanocones. Namely, on all plasma treated samples, only a few atomic percent of oxygen was found, meaning that plasma caused mostly etching, leading to changes in the surface morphology. This indicates that the main preventing mechanism against platelets adhesion was the right surface morphology.

  19. High concentrations and photochemical fate of oxygenated hydrocarbons in the global troposphere

    Science.gov (United States)

    Singh, Hanwant B.; Kanakidou, M.; Crutzen, P. J.; Jacob, D. J.

    1995-11-01

    OXYGENATED species in the atmosphere are important sources of free radicals and are intricately linked with the fate of nitrogen oxides (NO x ), which are themselves necessary for tropospheric ozone formation1,2. With the exception of formaldehyde, oxygenated hydrocarbons have rarely been measured in the free troposphere. Here we report airborne measurements indicating the presence of high concentrations (compared to those of routinely measured C2-C6 tropospheric hydrocarbons3,4) of acetone and methanol. We use a three-dimensional model to show that acetone photochemistry provides a quantitatively significant (up to 50%) pathway for sequestering NO x in the form of peroxyacetylnitrate, a relatively unreactive temporary reservoir of NO x . Furthermore, in the dry regions of the upper troposphere, acetone can provide a large primary source of HOx (OH + HO2) radicals, resulting in increased ozone production. This surprisingly significant contribution of such oxygenated hydrocarbons to tropospheric NOx, HO x and ozone cycling is likely to be affected by their changing natural and anthropogenic emissions due to land-use change, biomass burning and alcohol-based biofuel use.

  20. High Precision Oxygen Three Isotope Analysis of Wild-2 Particles and Anhydrous Chondritic Interplanetary Dust Particles

    Science.gov (United States)

    Nakashima, D.; Ushikubo, T.; Zolensky, Michael E.; Weisberg, M. K.; Joswiak, D. J.; Brownlee, D. E.; Matrajt, G.; Kita, N. T.

    2011-01-01

    One of the most important discoveries from comet Wild-2 samples was observation of crystalline silicate particles that resemble chondrules and CAIs in carbonaceous chondrites. Previous oxygen isotope analyses of crystalline silicate terminal particles showed heterogeneous oxygen isotope ratios with delta(sup 18)O to approx. delta(sup 17)O down to -50% in the CAI-like particle Inti, a relict olivine grain in Gozen-sama, and an olivine particle. However, many Wild-2 particles as well as ferromagnesian silicates in anhydrous interplanetary dust particles (IDPs) showed Delta(sup 17)O values that cluster around -2%. In carbonaceous chondrites, chondrules seem to show two major isotope reservoirs with Delta(sup 17)O values at -5% and -2%. It was suggested that the Delta(sup 17)O = -2% is the common oxygen isotope reservoir for carbonaceous chondrite chondrules and cometary dust, from the outer asteroid belt to the Kuiper belt region. However, a larger dataset with high precision isotope analyses (+/-1-2%) is still needed to resolve the similarities or distinctions among Wild-2 particles, IDPs and chondrules in meteorites. We have made signifi-cant efforts to establish routine analyses of small particles (isotope analyses of Wild-2 particles and anhydrous chondritic IDPs, and discuss the relationship between the cometary dust and carbonaceous chondrite chondrules.

  1. Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction

    Science.gov (United States)

    Liang, Hai-Wei; Zhuang, Xiaodong; Brüller, Sebastian; Feng, Xinliang; Müllen, Klaus

    2014-09-01

    Development of efficient, low-cost and stable electrocatalysts as the alternative to platinum for the oxygen reduction reaction is of significance for many important electrochemical devices, such as fuel cells, metal-air batteries and chlor-alkali electrolysers. Here we report a highly active nitrogen-doped, carbon-based, metal-free oxygen reduction reaction electrocatalyst, prepared by a hard-templating synthesis, for which nitrogen-enriched aromatic polymers and colloidal silica are used as precursor and template, respectively, followed by ammonia activation. Our protocol allows for the simultaneous optimization of both porous structures and surface functionalities of nitrogen-doped carbons. Accordingly, the prepared catalysts show the highest oxygen reduction reaction activity (half-wave potential of 0.85 V versus reversible hydrogen electrode with a low loading of 0.1 mg cm-2) in alkaline media among all reported metal-free catalysts. Significantly, when used for constructing the air electrode of zinc-air battery, our metal-free catalyst outperforms the state-of the-art platinum-based catalyst.

  2. Wine evolution and spatial distribution of oxygen during storage in high-density polyethylene tanks.

    Science.gov (United States)

    del Alamo-Sanza, María; Laurie, V Felipe; Nevares, Ignacio

    2015-04-01

    Porous plastic tanks are permeable to oxygen due to the nature of the polymers with which they are manufactured. In the wine industry, these types of tanks are used mainly for storing wine surpluses. Lately, their use in combination with oak pieces has also been proposed as an alternative to mimic traditional barrel ageing. In this study, the spatial distribution of dissolved oxygen in a wine-like model solution, and the oxygen transfer rate (OTR) of high-density polyethylene tanks (HDPE), was analysed by means of a non-invasive opto-luminescence detector. Also, the chemical and sensory evolution of red wine, treated with oak pieces, and stored in HDPE tanks was examined and compared against traditional oak barrel ageing. The average OTR calculated for these tanks was within the commonly accepted amounts reported for new barrels. With regards to wine evolution, a number of compositional and sensory differences were observed between the wines aged in oak barrels and those stored in HDPE tanks with oak barrel alternatives. The use of HDPE tanks in combination with oak wood alternatives is a viable alternative too for ageing wine. © 2014 Society of Chemical Industry.

  3. Fuzzy systems in high-energy physics

    Science.gov (United States)

    Castellano, Marcello; Masulli, Francesco; Penna, Massimo

    1996-06-01

    Decision making is one of the major subjects of interest in physics. This is due to the intrinsic finite accuracy of measurement that leads to the possible results to span a region for each quantity. In this way, to recognize a particle type among the others by a measure of a feature vector, a decision must be made. The decision making process becomes a crucial point whenever a low statistical significance occurs as in space cosmic ray experiments where searching in rare events requires us to reject as many background events as possible (high purity), keeping as many signal events as possible (high efficiency). In the last few years, interesting theoretical results on some feedforward connectionist systems (FFCSs) have been obtained. In particular, it has been shown that multilayer perceptrons (MLPs), radial basis function networks (RBFs), and some fuzzy logic systems (FLSs) are nonlinear universal function approximators. This property permits us to build a system showing intelligent behavior , such as function estimation, time series forecasting, and pattern classification, and able to learn their skill from a set of numerical data. From the classification point of view, it has been demonstrated that non-parametric classifiers based FFCSs holding the universal function approximation property, can approximate the Bayes optimal discriminant function and then minimize the classification error. In this paper has been studied the FBF when applied to a high energy physics problem. The FBF is a powerful neuro-fuzzy system (or adaptive fuzzy logic system) holding the universal function approximation property and the capability of learning from examples. The FBF is based on product-inference rule (P), the Gaussian membership function (G), a singleton fuzzifier (S), and a center average defuzzifier (CA). The FBF can be regarded as a feedforward connectionist system with just one hidden layer whose units correspond to the fuzzy MIMO rules. The FBF can be identified both by

  4. Determination of the relative resistance to ignition of selected turbopump materials in high-pressure, high-temperature, oxygen environments, volume 1

    Science.gov (United States)

    Stoltzfus, Joel M.; Benz, Frank J.

    1986-01-01

    Advances in the design of the liquid oxygen, liquid hydrogen engines for the Space Transportation System call for the use of warm, high-pressure oxygen as the driving gas in the liquid oxygen turbopump. The NASA Lewis Research Center requested the NASA White Sands Test Facility (WSTF) to design a test program to determine the relative resistance to ignition of nine selected turbopump materials: Hastelloy X, Inconel 600, Invar 36, Monel K-500, nickel 200, silicon carbide, stainless steel 316, and zirconium copper. The materials were subjected to particle impact and to frictional heating in high-pressure oxygen.

  5. Innovation development for highly energy-efficient housing

    NARCIS (Netherlands)

    Mlecnik, E.

    2014-01-01

    Buildings account for 40% of EU final energy demand and policy developments like the Energy Performance of Buildings Directive are stimulating the innovation development for nearly zero-energy housing. However, businesses switching to innovative products for highly energy-efficient houses is a

  6. 76 FR 53119 - High Energy Physics Advisory Panel

    Science.gov (United States)

    2011-08-25

    ... Energy Physics Advisory Panel AGENCY: Department of Energy. ACTION: Notice of renewal. SUMMARY: Pursuant... Energy Physics Advisory Panel will be renewed for a two-year period, beginning on August 12, 2011. The... priorities in the national High Energy Physics program. Additionally, the renewal of the HEPAP has been...

  7. Energy Efficient Beam Transfer Channels for High Energy Particle Accelerators

    CERN Document Server

    Gardlowski, Philipp; Ondreka, David

    2016-01-01

    conducting (NC) magnets or high current pulsed (HCP) magnets are an economic solution. For high repetition rates above 1.0 Hz, superconducting Cos(N) (SC) magnets or superferric (SF) magnets are more attractive; at least if they are operated in DC mode and if no dynamic losses occur in the cryogenic system. Unfortunately, a range between these values exist, in which no...

  8. CONSTRAINTS ON THE SOURCE OF ULTRA-HIGH-ENERGY COSMIC RAYS USING ANISOTROPY VERSUS CHEMICAL COMPOSITION

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ruo-Yu; Wang, Xiang-Yu [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Taylor, Andrew M. [Dublin Institute for Advanced Studies, 31 Fitzwilliam Place, Dublin 2 (Ireland); Lemoine, Martin [Institut d' Astrophysique de Paris, CNRS, UPMC, 98 bis Boulevard Arago, F-75014 Paris (France); Waxman, Eli, E-mail: lemoine@iap.fr [Physics Faculty, Weizmann Institute, P.O. Box 26, Rehovot 7600 (Israel)

    2013-10-20

    The joint analysis of anisotropy signals and chemical composition of ultra-high-energy cosmic rays offers strong potential for shedding light on the sources of these particles. Following up on an earlier idea, this paper studies the anisotropies produced by protons of energy >E/Z, assuming that anisotropies at energy >E have been produced by nuclei of charge Z, which share the same magnetic rigidity. We calculate the number of secondary protons produced through photodisintegration of the primary heavy nuclei. Making the extreme assumption that the source does not inject any proton, we find that the source(s) responsible for anisotropies such as reported by the Pierre Auger Observatory should lie closer than ∼20-30, 80-100, and 180-200 Mpc if the anisotropy signal is mainly composed of oxygen, silicon, and iron nuclei, respectively. A violation of this constraint would otherwise result in the secondary protons forming a more significant anisotropy signal at lower energies. Even if the source were located closer than this distance, it would require an extraordinary metallicity ∼> 120, 1600, and 1100 times solar metallicity in the acceleration zone of the source, for oxygen, silicon, and iron, respectively, to ensure that the concomitantly injected protons do not produce a more significant low-energy anisotropy. This offers interesting prospects for constraining the nature and the source of ultra-high-energy cosmic rays with the increase in statistics expected from next-generation detectors.

  9. Size-extensivity-corrected multireference configuration interaction schemes to accurately predict bond dissociation energies of oxygenated hydrocarbons.

    Science.gov (United States)

    Oyeyemi, Victor B; Krisiloff, David B; Keith, John A; Libisch, Florian; Pavone, Michele; Carter, Emily A

    2014-01-28

    Oxygenated hydrocarbons play important roles in combustion science as renewable fuels and additives, but many details about their combustion chemistry remain poorly understood. Although many methods exist for computing accurate electronic energies of molecules at equilibrium geometries, a consistent description of entire combustion reaction potential energy surfaces (PESs) requires multireference correlated wavefunction theories. Here we use bond dissociation energies (BDEs) as a foundational metric to benchmark methods based on multireference configuration interaction (MRCI) for several classes of oxygenated compounds (alcohols, aldehydes, carboxylic acids, and methyl esters). We compare results from multireference singles and doubles configuration interaction to those utilizing a posteriori and a priori size-extensivity corrections, benchmarked against experiment and coupled cluster theory. We demonstrate that size-extensivity corrections are necessary for chemically accurate BDE predictions even in relatively small molecules and furnish examples of unphysical BDE predictions resulting from using too-small orbital active spaces. We also outline the specific challenges in using MRCI methods for carbonyl-containing compounds. The resulting complete basis set extrapolated, size-extensivity-corrected MRCI scheme produces BDEs generally accurate to within 1 kcal/mol, laying the foundation for this scheme's use on larger molecules and for more complex regions of combustion PESs.

  10. Phase conjugation of high energy lasers.

    Energy Technology Data Exchange (ETDEWEB)

    Bliss, David E; Valley, Michael T.; Atherton, Briggs W.; Bigman, Verle Howard; Boye, Lydia Ann; Broyles, Robin Scott; Kimmel, Mark W.; Law, Ryan J.; Yoder, James R.

    2013-01-01

    In this report we explore claims that phase conjugation of high energy lasers by stimulated Brillouin scattering (SBS) can compensate optical aberrations associated with severely distorted laser amplifier media and aberrations induced by the atmosphere. The SBS media tested was a gas cell pressurized up to 300 psi with SF6 or Xe or both. The laser was a 10 Hz, 3J, Q-switched Nd:YAG with 25 ns wide pulses. Atmospheric aberrations were created with space heaters, helium jets and phase plates designed with a Kolmogorov turbulence spectrum characterized by a Fried parameter, ro , ranging from 0.6 6.0 mm. Phase conjugate tests in the laboratory were conducted without amplification. For the strongest aberrations, D/ro ~ 20, created by combining the space heaters with the phase plate, the Strehl ratio was degraded by a factor of ~50. Phase conjugation in SF6 restored the peak focusable intensity to about 30% of the original laser. Phase conjugate tests at the outdoor laser range were conducted with laser amplifiers providing gain in combination with the SBS cell. A large 600,000 BTU kerosene space heater was used to create turbulence along the beam path. An atmospheric structure factor of Cn2 = 5x10-13 m2/3 caused the illumination beam to expand to a diameter 250mm and overfill the receiver. The phase conjugate amplified return could successfully be targeted back onto glints 5mm in diameter. Use of a lenslet arrays to lower the peak focusable intensity in the SBS cell failed to produce a useful phase conjugate beam; The Strehl ratio was degraded with multiple random lobes instead of a single focus. I will review literature results which show how multiple beams can be coherently combined by SBS when a confocal reflecting geometry is used to focus the laser in the SBS cell.

  11. Re-interpreting anaerobic metabolism: an argument for the application of both anaerobic glycolysis and excess post-exercise oxygen comsumption (EPOC) as independent sources of energy expenditure.

    Science.gov (United States)

    Scott, C B

    1998-02-01

    Due to current technical difficulties and changing cellular conditions, the measurement of anaerobic and recovery energy expenditure remains elusive. During rest and low-intensity steady-state exercise, indirect calorimetric measurements successfully represent energy expenditure. The same steady-state O2 uptake methods are often used to describe the O2 deficit and excess post-oxygen consumption (EPOC): 1 l O2 = 5 kcal = 20.9 kJ. However, an O2 deficit plus exercise O2 uptake measurement ignores energy expenditure during recovery, and an exercise O2 uptake plus EPOC measurement misrepresents anaerobic energy expenditure. An alternative solution has not yet been proposed. Anaerobic glycolysis and mitochondrial respiration are construed here as a symbiotic union of metabolic pathways, each contributing independently to energy expenditure and heat production. Care must be taken when using O2 uptake alone to quantify energy expenditure because various high-intensity exercise models reveal that O2 uptake can lag behind estimated energy demands or exceed them. The independent bioenergetics behind anaerobic glycolysis and mitochondrial respiration can acknowledge these discrepancies. Anaerobic glycolysis is an additive component to an exercise O2 uptake measurement. Moreover, it is the assumptions behind steady-state O2 uptake that do not permit proper interpretation of energy expenditure during EPOC; 1 l O2 not = 20.9 kJ. Using both the O2 deficit and a modified EPOC for interpretation, rather than one or the other, leads to a better method of quantifying energy expenditure for higher intensity exercise and recovery.

  12. High energy particle collisions near black holes

    Science.gov (United States)

    Zaslavskii, O. B.

    2016-10-01

    If two geodesic particles collide near a rotating black hole, their energy in the centre of mass frame Ec.m. can become unbound under certain conditions (the so-called BSW effect). The special role is played here by so-called critical geodesics when one of particles has fine-tuned energy and angular momentum. The nature of geodesics reveals itself also in fate of the debris after collisions. One of particles moving to a remote observer is necessarily near-critical. We discuss, when such a collision can give rise not only unboud Ec.m. but also unbound Killing energy E (so-called super-Penrose process).

  13. Neuromuscular blockade of slow twitch muscle fibres elevates muscle oxygen uptake and energy turnover during submaximal exercise in humans

    DEFF Research Database (Denmark)

    Krustrup, Peter; Secher, Niels; Relu, Mihai U.

    2008-01-01

    We tested the hypothesis that a greater activation of fast-twitch (FT) fibres during dynamic exercise leads to a higher muscle oxygen uptake (VO2 ) and energy turnover as well as a slower muscle on-kinetics. Subjects performed one-legged knee-extensor exercise for 10 min at an intensity of 30 W...... fibres, respectively. From 127 s of exercise, muscle VO2 was higher (P muscle VO2 response...... was slower (P muscle homogenate CP was lowered (P muscle lactate production was similar in CUR and CON (37.8 +/- 4.1 versus 35.2 +/- 6.2 mmol). Estimated total muscle ATP turnover was 19...

  14. FLUKA as a new high energy cosmic ray generator

    Energy Technology Data Exchange (ETDEWEB)

    Battistoni, Giuseppe [INFN, Sezione di Milano, Via Celoria 16, I-20133, Milano (Italy); Margiotta, Annarita, E-mail: margiotta@bo.infn.i [Dipartimento di Fisica dell' Universita di Bologna and INFN, Sezione di Bologna, V.le Berti Pichat 6/2, I-40127, Bologna (Italy); Muraro, Silvia [INFN, Sezione di Milano, Via Celoria 16, I-20133, Milano (Italy); Sioli, Maximiliano [Dipartimento di Fisica dell' Universita di Bologna and INFN, Sezione di Bologna, V.le Berti Pichat 6/2, I-40127, Bologna (Italy)

    2011-01-21

    FLUKA is a multipurpose Monte Carlo code, which can transport particles over a wide range of energies in user-defined geometries. Here we present a new FLUKA library, which allows the interaction and propagation of high energy cosmic rays in the Earth atmosphere and the transport of high energy muons in underground/underwater environments.

  15. Novel Lithium Ion High Energy Battery Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Under this SBIR project a new chemistry for Li-ion cells will be developed that will enable a major advance in secondary battery gravimetric and volumetric energy...

  16. Recycling of spent Cu-based oxygen carriers into high-strength ceramic proppants

    OpenAIRE

    Kukurugya, Frantisek; Bergmans, Jef; Snellings, Ruben; Spooren, Jeroen

    2017-01-01

    Chemical-looping combustion (CLC) technology can play a significant role in decreasing costs for CO2 capturing in the future. The technology relies on the use of an oxygen carrier (OC) material, which becomes a solid waste material after it is deactivated. The aim of this study was to verify the possibility to produce high-strength ceramic proppants from a spent Cu-based OC, consisting mainly of α-Al2O3 and a minor content of CuAl2O4. Experiments were carried out with both pure α-Al2O3 and a ...

  17. Ground state atomic oxygen in high-power impulse magnetron sputtering: a quantitative study

    Science.gov (United States)

    Britun, Nikolay; Belosludtsev, Alexandr; Silva, Tiago; Snyders, Rony

    2017-02-01

    The ground state density of oxygen atoms in reactive high-power impulse magnetron sputtering discharges has been studied quantitatively. Both time-resolved and space-resolved measurements were conducted. The measurements were performed using two-photon absorption laser-induced fluorescence (TALIF), and calibrated by optical emission actinometry with multiple Ar emission lines. The results clarify the dynamics of the O ground state atoms in the discharge afterglow significantly, including their propagation and fast decay after the plasma pulse, as well as the influence of gas pressure, O2 admixture, etc.

  18. Energy-rich glyceric acid oxygen esters - Implications for the origin of glycolysis

    Science.gov (United States)

    Weber, Arthur L.; Hsu, Victor

    1990-01-01

    The apparent Gibbs free energy change (GFEC) of hydrolysis (pH 7) of the 2- and 3-O-glyceroyl esters of 2- and 3-O-L-glyceroyl-L-glyceric acid methyl ester were measured at 25 C. The 2- and 3-glyceroyl esters were found to be 'energy-rich' with GFEC values of -9.1 kcal/mol and -7.8 kcal/mol, respectively. This result indicates that the analogous 2- and 3-glyceroyl esters of polyglyceric acid are also energy-rich and, therefore, could have acted as an energy source for primitive phosphoanhydride synthesis.

  19. Effective Construction of High-quality Iron Oxy-hydroxides and Co-doped Iron Oxy-hydroxides Nanostructures: Towards the Promising Oxygen Evolution Reaction Application

    Science.gov (United States)

    Zhang, Xinyu; An, Li; Yin, Jie; Xi, Pinxian; Zheng, Zhiping; Du, Yaping

    2017-01-01

    Rational design of high efficient and low cost electrocatalysts for oxygen evolution reaction (OER) plays an important role in water splitting. Herein, a general gelatin-assisted wet chemistry method is employed to fabricate well-defined iron oxy-hydroxides and transitional metal doped iron oxy-hydroxides nanomaterials, which show good catalytic performances for OER. Specifically, the Co-doped iron oxy-hydroxides (Co0.54Fe0.46OOH) show the excellent electrocatalytic performance for OER with an onset potential of 1.52 V, tafel slope of 47 mV/dec and outstanding stability. The ultrahigh oxygen evolution activity and strong durability, with superior performance in comparison to the pure iron oxy-hydroxide (FeOOH) catalysts, originate from the branch structure of Co0.54Fe0.46OOH on its surface so as to provide many active edge sites, enhanced mass/charge transport capability, easy release oxygen gas bubbles, and strong structural stability, which are advantageous for OER. Meanwhile, Co-doping in FeOOH nanostructures constitutes a desirable four-electron pathway for reversible oxygen evolution and reduction, which is potentially useful for rechargeable metal−air batteries, regenerative fuel cells, and other important clean energy devices. This work may provide a new insight into constructing the promising water oxidation catalysts for practical clean energy application. PMID:28272443

  20. Effective Construction of High-quality Iron Oxy-hydroxides and Co-doped Iron Oxy-hydroxides Nanostructures: Towards the Promising Oxygen Evolution Reaction Application

    Science.gov (United States)

    Zhang, Xinyu; An, Li; Yin, Jie; Xi, Pinxian; Zheng, Zhiping; Du, Yaping

    2017-03-01

    Rational design of high efficient and low cost electrocatalysts for oxygen evolution reaction (OER) plays an important role in water splitting. Herein, a general gelatin-assisted wet chemistry method is employed to fabricate well-defined iron oxy-hydroxides and transitional metal doped iron oxy-hydroxides nanomaterials, which show good catalytic performances for OER. Specifically, the Co-doped iron oxy-hydroxides (Co0.54Fe0.46OOH) show the excellent electrocatalytic performance for OER with an onset potential of 1.52 V, tafel slope of 47 mV/dec and outstanding stability. The ultrahigh oxygen evolution activity and strong durability, with superior performance in comparison to the pure iron oxy-hydroxide (FeOOH) catalysts, originate from the branch structure of Co0.54Fe0.46OOH on its surface so as to provide many active edge sites, enhanced mass/charge transport capability, easy release oxygen gas bubbles, and strong structural stability, which are advantageous for OER. Meanwhile, Co-doping in FeOOH nanostructures constitutes a desirable four-electron pathway for reversible oxygen evolution and reduction, which is potentially useful for rechargeable metal-air batteries, regenerative fuel cells, and other important clean energy devices. This work may provide a new insight into constructing the promising water oxidation catalysts for practical clean energy application.

  1. Ignition Resistance of Polymeric Materials to Particle Impact in High-Pressure Oxygen

    Science.gov (United States)

    Forsyth, Elliot T.; Stolzfus, Joel M.; Fries, Joseph (Technical Monitor)

    2000-01-01

    Particle impact ignition has been the primary cause of numerous fires in oxygen systems. This ignition phenomenon is known to occur where particles are present in high-velocity gas, and where impact occurs on a flammable material. The particle impact ignition behavior of many metals has been widely studied, but the particle impact ignition behavior of polymeric materials is relatively unknown. Particle impact ignition in polymeric materials is a concern as these materials are commonly used in component seat and seal applications, where high-velocity particle impacts can occur. This study evaluates several polymeric materials and compares the minimum temperature required for ignition (threshold temperature) of these materials: Kel-F 81 (CTFE), Teflon (PTFE), PEEK, Vespel SP-21, and Nylon 6/6. The materials were configured as targets in the White Sands Test Facility high-velocity particle impact test system. Gaseous oxygen was flowed at 4000 psi and sonic velocity, and the targets were impacted with 2000-micron aluminum 2017 particles. This paper discusses the results of these tests and ranks the materials according to their threshold temperatures at these conditions.

  2. IASCC susceptibility of austenitic stainless steels and alloy 690 in high dissolved oxygen water environment

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y.; Chopra, O.K.; Soppet, W.K. [Argonne National Lab., Nuclear Engineering Div., Argonne, Illinois (United States); Dietz Rago, N.L. [Argonne National Lab., Chemical Engineering Div., Argonne, Illinois (United States); Shack, W.J. [Argonne National Lab., Nuclear Engineering Div., Argonne, Illinois (United States)

    2007-07-01

    The influences of grain boundary engineering, alloying elements, and neutron dose on irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels and Alloy 690 were investigated. Flat dog-bone specimens irradiated in the Halden boiling heavy water reactor to {approx}2 dpa were tested in slow strain rate tensile tests in high dissolved oxygen water at 289 {sup o}C. The area fractions of intergranular or transgranular fracture were measured using a scanning electron microscope. All tested materials showed significant hardening and loss of ductility after irradiation. The area fractions of the intergranular cracking decreased with increase of uniform elongation, and were used to rank IASCC susceptibility. The grain boundary engineering treatment employed in this study does not have a significant impact on IASCC susceptibility for austenitic SSs at {approx}2 dpa, but does affect the cracking behavior of Alloy 690. High-sulfur and low-carbon SSs are more susceptible to IASCC. Oxygen content also contributes to the IASCC susceptibility in high-purity Type 304L SS. (author)

  3. Adventures in high energy theory and phenomenology

    Science.gov (United States)

    Robinson, Dean Jonathan

    Various studies of high energy theory and phenomenology are presented. We first present a mechanism that naturally produces light Dirac neutrinos. The central idea is that the right-handed neutrinos are composite. Any realistic composite model must involve 'hidden flavor' chiral symmetries. In general some of these symmetries may survive confinement, and in particular, if a U(1) survives it must imply an exact B -- L symmetry at low energies. Dirac neutrinos are therefore produced, which are naturally light due to compositeness. In general, elementary keV sterile Dirac neutrinos can be a natural ingredient of this composite neutrino scenario. For a certain class of composite neutrino theories, these sterile neutrinos naturally have the appropriate mixing angles to be resonantly produced warm dark matter (WDM). Alternatively, we show these sterile neutrinos can be WDM produced by an entropy-diluted thermal freeze-out, with the necessary entropy production arising not from an out-of-equilibrium decay, but rather from the confinement of the composite neutrino sector, provided there is sufficient supercooling. We next present a formalism for the flavor oscillation of unstable particles that relies only upon the analytic structure of the time Fourier-transformed two-point function. We derive exact oscillation probability and integrated oscillation probability formulae, and verify that our results reproduce the known results for both neutrino and neutral meson oscillation in the expected regimes of parameter space. The generality of our approach permits us to investigate flavor oscillation in exotic parameter regimes, and present the corresponding oscillation formulae. Kinematic edges in cascade decays provide a probe of the masses of new particles. In some new physics scenarios the decay chain involves intermediate particles of different flavors that can mix and oscillate. We discuss the implication of such oscillation, and in particular its interplay with the non

  4. Energy Design Guidelines for High Performance Schools: Tropical Island Climates

    Energy Technology Data Exchange (ETDEWEB)

    None

    2004-11-01

    Design guidelines outline high performance principles for the new or retrofit design of K-12 schools in tropical island climates. By incorporating energy improvements into construction or renovation plans, schools can reduce energy consumption and costs.

  5. High-energy metal air batteries

    Science.gov (United States)

    Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

    2013-07-09

    Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

  6. Design of high efficiency and energy saving aeration device for aquaculture

    Science.gov (United States)

    Liu, Sibo

    2017-03-01

    Energy efficient aeration device for aquaculture, in line with "by more than a generation, dynamic aeration" train of thought for technical design and improvement. Removable aeration terminal as the core, multi-level water to improve the method, the mobile fading pore aeration, intelligent mobile and open and close as the main function, aimed at solving the existing pond aeration efficiency, low energy consumption is high, the function of a single problem. From energy saving, efficiency, biological bacteria on the three directions, the aquaculture industry of energy conservation and emissions reduction. Device of the main advantages are: 1, original mobile fading aerator on the one hand, to expand the scope of work, playing a micro porous aeration of dissolved oxygen with high efficiency and to achieve "by more than a generation", on the other hand, through the sports equipment, stir the mixture of water, the water surface of photosynthesis of plants rich in dissolved oxygen input parts of the tank, compared to the stillness of the aerator can be more fully dissolved oxygen.2, through the opening of the pressure sensor indirect control device, can make the equipment timely and stop operation, convenient in use at the same time avoid the waste of energy.3, the biofilm suspension in aeration terminal, can be accomplished by nitration of microbial multi-level water improvement, still can make biofilm increase rate of netting in the movement process, the biological and mechanical aerobic promote each other, improve the efficiency of both. In addition, the device has small power consumption, low cost of characteristics. And have a certain degree of technical barriers, have their own intellectual property rights, and high degree of product market demand, easily accepted by customers, has a very high popularization value.

  7. A new highly sensitive method to assess respiration rates and kinetics of natural planktonic communities by use of the switchable trace oxygen sensor and reduced oxygen concentrations.

    Science.gov (United States)

    Tiano, Laura; Garcia-Robledo, Emilio; Revsbech, Niels Peter

    2014-01-01

    Oxygen respiration rates in pelagic environments are often difficult to quantify as the resolutions of our methods for O2 concentration determination are marginal for observing significant decreases during bottle incubations of less than 24 hours. Here we present the assessment of a new highly sensitive method, that combine Switchable Trace Oxygen (STOX) sensors and all-glass bottle incubations, where the O2 concentration was artificially lowered. The detection limit of respiration rate by this method is inversely proportional to the O2 concentration, down to water with an initial O2 concentration of 500 nmol L(-1). The method was tested in Danish coastal waters and in oceanic hypoxic waters. It proved to give precise measurements also with low oxygen consumption rates (∼7 nmol L(-1) h(-1)), and to significantly decrease the time required for incubations (≤14 hours) compared to traditional methods. This method provides continuous real time measurements, allowing for a number of diverse possibilities, such as modeling the rate of oxygen decrease to obtain kinetic parameters. Our data revealed apparent half-saturation concentrations (Km values) one order of magnitude lower than previously reported for marine bacteria, varying between 66 and 234 nmol L(-1) O2. Km values vary between different microbial planktonic communities, but our data show that it is possible to measure reliable respiration rates at concentrations ∼0.5-1 µmol L(-1) O2 that are comparable to the ones measured at full air saturation.

  8. Measurements on the gas desorption yield of the oxygen-free copper irradiated with low-energy Xe10+ and O+

    Science.gov (United States)

    Dong, Z. Q.; Li, P.; Yang, J. C.; Yuan, Y. J.; Xie, W. J.; Zheng, W. H.; Liu, X. J.; Chang, J. J.; Luo, C.; Meng, J.; Wang, J. C.; Wang, Y. M.; Yin, Y.; Chai, Z.

    2017-10-01

    Heavy ion beam lost on the accelerator vacuum wall will release quantity of gas molecules and make the vacuum system deteriorate seriously. This phenomenon is called dynamic vacuum effect, observed at CERN, GSI and BNL, leading to the decrease of beam lifetime when increasing beam intensity. Heavy ion-induced gas desorption, which results in dynamic vacuum effect, becomes one of the most important problems for future accelerators proposed to operate with intermediate charge state beams. In order to investigate the mechanism of this effect and find the solution method for the IMP future project High Intensity heavy-ion Accelerator Facility (HIAF), which is designed to extract 1 × 1011 uranium particles with intermediate charge state per cycle, two dedicated experiment setups have been installed at the beam line of the CSR and the 320 kV HV platform respectively. Recently, experiment was performed at the 320 kV HV platform to study effective gas desorption with oxygen-free copper target irradiated with continuous Xe10+ beam and O+ beam in low energy regime. Gas desorption yield in this energy regime was calculated and the link between gas desorption and electronic energy loss in Cu target was proved. These results will be used to support simulations about dynamic vacuum effect and optimizations about efficiency of collimators to be installed in the HIAF main synchrotron BRing, and will also provide guidance for future gas desorption measurements in high energy regime.

  9. Pilot Plant Demonstration of Stable and Efficient High Rate Biological Nutrient Removal with Low Dissolved Oxygen Conditions

    Science.gov (United States)

    Aeration in biological nutrient removal (BNR) processes accounts for nearly half of the total electricity costs at many wastewater treatment plants. Even though conventional BNR processes are usually operated to have aerated zones with high dissolved oxygen (DO) concentrations, r...

  10. High-performance a -Si/c-Si heterojunction photoelectrodes for photoelectrochemical oxygen and hydrogen evolution

    KAUST Repository

    Wang, Hsin Ping

    2015-05-13

    Amorphous Si (a-Si)/crystalline Si (c-Si) heterojunction (SiHJ) can serve as highly efficient and robust photoelectrodes for solar fuel generation. Low carrier recombination in the photoelectrodes leads to high photocurrents and photovoltages. The SiHJ was designed and fabricated into both photoanode and photocathode with high oxygen and hydrogen evolution efficiency, respectively, by simply coating of a thin layer of catalytic materials. The SiHJ photoanode with sol-gel NiOx as the catalyst shows a current density of 21.48 mA/cm2 at the equilibrium water oxidation potential. The SiHJ photocathode with 2 nm sputter-coated Pt catalyst displays excellent hydrogen evolution performance with an onset potential of 0.640 V and a solar to hydrogen conversion efficiency of 13.26%, which is the highest ever reported for Si-based photocathodes. © 2015 American Chemical Society.

  11. Energy Design Guidelines for High Performance Schools: Tropical Island Climates

    Energy Technology Data Exchange (ETDEWEB)

    2004-11-01

    The Energy Design Guidelines for High Performance Schools--Tropical Island Climates provides school boards, administrators, and design staff with guidance to help them make informed decisions about energy and environmental issues important to school systems and communities. These design guidelines outline high performance principles for the new or retrofit design of your K-12 school in tropical island climates. By incorporating energy improvements into their construction or renovation plans, schools can significantly reduce energy consumption and costs.

  12. High energy particle collisions near black holes

    Directory of Open Access Journals (Sweden)

    Zaslavskii O. B.

    2016-01-01

    Full Text Available If two geodesic particles collide near a rotating black hole, their energy in the centre of mass frame Ec.m. can become unbound under certain conditions (the so-called BSW effect. The special role is played here by so-called critical geodesics when one of particles has fine-tuned energy and angular momentum. The nature of geodesics reveals itself also in fate of the debris after collisions. One of particles moving to a remote observer is necessarily near-critical. We discuss, when such a collision can give rise not only unboud Ec.m. but also unbound Killing energy E (so-called super-Penrose process.

  13. The effects of graded changes in oxygen and carbon dioxide tension on coronary blood velocity independent of myocardial energy demand.

    Science.gov (United States)

    Boulet, Lindsey M; Stembridge, Mike; Tymko, Michael M; Tremblay, Joshua C; Foster, Glen E

    2016-08-01

    In humans, coronary blood flow is tightly regulated by microvessels within the myocardium to match myocardial energy demand. However, evidence regarding inherent sensitivity of the microvessels to changes in arterial partial pressure of carbon dioxide and oxygen is conflicting because of the accompanied changes in myocardial energy requirements. This study aimed to investigate the changes in coronary blood velocity while manipulating partial pressures of end-tidal CO2 (Petco2) and O2 (Peto2). It was hypothesized that an increase in Petco2 (hypercapnia) or decrease in Peto2 (hypoxia) would result in a significant increase in mean blood velocity in the left anterior descending artery (LADVmean) due to an increase in both blood gases and energy demand associated with the concomitant cardiovascular response. Cardiac energy demand was assessed through noninvasive measurement of the total left ventricular mechanical energy. Healthy subjects (n = 13) underwent a euoxic CO2 test (Petco2 = -8, -4, 0, +4, and +8 mmHg from baseline) and an isocapnic hypoxia test (Peto2 = 64, 52, and 45 mmHg). LADVmean was assessed using transthoracic Doppler echocardiography. Hypercapnia evoked a 34.6 ± 8.5% (mean ± SE; P changes in arterial blood gases are important contributors to the observed changes in LADVmean (P metabolic changes within the heart and an inherent sensitivity to arterial blood gases. Copyright © 2016 the American Physiological Society.

  14. Facile synthesis of high strength hot-water wood extract films with oxygen-barrier performance

    Science.gov (United States)

    Chen, Ge-Gu; Fu, Gen-Que; Wang, Xiao-Jun; Gong, Xiao-Dong; Niu, Ya-Shuai; Peng, Feng; Yao, Chun-Li; Sun, Run-Cang

    2017-01-01

    Biobased nanocomposite films for food packaging with high mechanical strength and good oxygen-barrier performance were developed using a hot-water wood extract (HWE). In this work, a facile approach to produce HWE/montmorillonite (MMT) based nanocomposite films with excellent physical properties is described. The focus of this study was to determine the effects of the MMT content on the structure and mechanical properties of nanocomposites and the effects of carboxymethyl cellulose (CMC) on the physical properties of the HWE-MMT films. The experimental results suggested that the intercalation of HWE and CMC in montmorillonite could produce compact, robust films with a nacre-like structure and multifunctional characteristics. This results of this study showed that the mechanical properties of the film designated FCMC0.05 (91.5 MPa) were dramatically enhanced because the proportion of HWE, MMT and CMC was 1:1.5:0.05. In addition, the optimized films exhibited an oxygen permeability below 2.0 cm3 μm/day·m2·kPa, as well as good thermal stability due to the small amount of CMC. These results provide a comprehensive understanding for further development of high-performance nanocomposites which are based on natural polymers (HWE) and assembled layered clays (MMT). These films offer great potential in the field of sustainable packaging.

  15. Electronic kinetics of molecular nitrogen and molecular oxygen in high-latitude lower thermosphere and mesosphere

    Directory of Open Access Journals (Sweden)

    A. S. Kirillov

    2010-01-01

    Full Text Available Total quenching rate coefficients of Herzberg states of molecular oxygen and three triplet states of molecular nitrogen in the collisions with O2 and N2 molecules are calculated on the basis of quantum-chemical approximations. The calculated rate coefficients of electronic quenching of O2* and N2* molecules show a good agreement with available experimental data. An influence of collisional processes on vibrational populations of electronically excited N2 and O2 molecules is studied for the altitudes of high-latitude lower thermosphere and mesosphere during auroral electron precipitation. It is indicated that molecular collisions of metastable nitrogen N2(A3Σu* with O2 molecules are principal mechanism in electronic excitation of both Herzberg states c1Σu&minus, A'3Δu, A3Σu+ and high vibrational levels of singlet states a1Δg and b1Σg+ of molecular oxygen O2 at these altitudes.

  16. Microbial nar-GFP cell sensors reveal oxygen limitations in highly agitated and aerated laboratory-scale fermentors

    Directory of Open Access Journals (Sweden)

    Rao Govind

    2009-01-01

    Full Text Available Abstract Background Small-scale microbial fermentations are often assumed to be homogeneous, and oxygen limitation due to inadequate micromixing is often overlooked as a potential problem. To assess the relative degree of micromixing, and hence propensity for oxygen limitation, a new cellular oxygen sensor has been developed. The oxygen responsive E. coli nitrate reductase (nar promoter was used to construct an oxygen reporter plasmid (pNar-GFPuv which allows cell-based reporting of oxygen limitation. Because there are greater than 109 cells in a fermentor, one can outfit a vessel with more than 109 sensors. Our concept was tested in high density, lab-scale (5 L, fed-batch, E. coli fermentations operated with varied mixing efficiency – one verses four impellers. Results In both cases, bioreactors were maintained identically at greater than 80% dissolved oxygen (DO during batch phase and at approximately 20% DO during fed-batch phase. Trends for glucose consumption, biomass and DO showed nearly identical behavior. However, fermentations with only one impeller showed significantly higher GFPuv expression than those with four, indicating a higher degree of fluid segregation sufficient for cellular oxygen deprivation. As the characteristic time for GFPuv expression (approx 90 min. is much larger than that for mixing (approx 10 s, increased specific fluorescence represents an averaged effect of oxygen limitation over time and by natural extension, over space. Conclusion Thus, the pNar-GFPuv plasmid enabled bioreactor-wide oxygen sensing in that bacterial cells served as individual recirculating sensors integrating their responses over space and time. We envision cell-based oxygen sensors may find utility in a wide variety of bioprocessing applications.

  17. Rosemary and oxygen scavenger in active packaging for prevention of high-pressure induced lipid oxidation in pork patties

    DEFF Research Database (Denmark)

    Bolumar Garcia, Jose Tomas; Lapena Gomez, David; Skibsted, Leif Horsfelt

    2016-01-01

    Three different packaging systems: vacuum packaging, rosemary active packaging, and oxygen scavenger packaging were compared for their ability to counteract lipid oxidation in pork patties upon storage at 5 °C for 60 days following high pressure processing (HPP) (700 MPa, 10 min, 5 °C). Lipid...... oxidation was studied at the surface and the inner part by measuring secondary lipid oxidation products (TBARs) and the tendency to form radicals by electron spin resonance (ESR) spectroscopy. Lipid oxidation was lower in the inner part than at the surface for all three packaging systems. Rosemary active...... packaging was the most effective method to protect pork patties from the HPP-induced lipid oxidation, while oxygen scavenger packaging was not effective since residual oxygen remained in the package in the initial period of storage. The kinetics of the oxygen trapping by oxygen scavengers appears...

  18. Observation of high energy gamma rays in intermediate energy nucleus-nucleus collisions

    NARCIS (Netherlands)

    Beard, K.B.; Benenson, W.; Bloch, C.; Kashy, E.; Stevenson, J.; Morrissey, D.J.; Plicht, J. van der; Sherrill, B.; Winfield, J.S.

    1985-01-01

    High energy electrons and positrons observed in medium energy nucleus-nucleus collisions are shown to be primarily due to the external conversion of high energy gamma rays. The reaction 14N+Cu was studied at E/A=40 MeV, and a magnetic spectrograph was used with a specially constructed multiwire

  19. High energy physics advisory panel`s subpanel on vision for the future of high-energy physics

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    This report was requested by the Secretary of Energy to (1) define a long-term program for pursuing the most important high-energy physics goals since the termination of the Superconducting Super Collider (SSC) project, (2) assess the current US high-energy physics program, and (3) make recommendations regarding the future of the field. Subjects on which recommendations were sought and which the report addresses were: high-energy physics funding priorities; facilitating international collaboration for future construction of large high-energy physics facilities; optimizing uses of the investment made in the SSC; how to encourage displaced scientists and engineers to remain in high-energy physics and to attract young scientists to enter the field in the future. The report includes a description of the state of high-energy physics research in the context of history, a summary of the SSC project, and documentation of the report`s own origins and development.

  20. Influence of exercise duration on cardiorespiratory responses, energy cost and tissue oxygenation within a 6 hour treadmill run.

    Science.gov (United States)

    Kerhervé, Hugo A; McLean, Scott; Birkenhead, Karen; Parr, David; Solomon, Colin

    2017-01-01

    The physiological mechanisms for alterations in oxygen utilization ([Formula: see text]) and the energy cost of running ( C r ) during prolonged running are not completely understood, and could be linked with alterations in muscle and cerebral tissue oxygenation. Eight trained ultramarathon runners (three women; mean ± SD; age 37 ± 7 yr; maximum [Formula: see text] 60 ± 15 mL min -1  kg -1 ) completed a 6 hr treadmill run (6TR), which consisted of four modules, including periods of moderate (3 min at 10 km h -1 , 10-CR) and heavy exercise intensities (6 min at 70% of maximum [Formula: see text], HILL), separated by three, 100 min periods of self-paced running (SP). We measured [Formula: see text], minute ventilation ([Formula: see text]), ventilatory efficiency ([Formula: see text]), respiratory exchange ratio (RER), C r , muscle and cerebral tissue saturation index (TSI) during the modules, and heart rate (HR) and perceived exertion (RPE) during the modules and SP. Participants ran 58.3 ± 10.5 km during 6TR. Speed decreased and HR and RPE increased during SP. Across the modules, HR and [Formula: see text] increased (10-CR), and RER decreased (10-CR and HILL). There were no significant changes in [Formula: see text], [Formula: see text], C r , TSI and RPE across the modules. In the context of positive pacing (decreasing speed), increased cardiac drift and perceived exertion over the 6TR, we observed increased RER and increased HR at moderate and heavy exercise intensity, increased [Formula: see text] at moderate intensity, and no effect of exercise duration on ventilatory efficiency, energy cost of running and tissue oxygenation.

  1. Stimulation of oxygen to bioanode for energy recovery from recalcitrant organic matter aniline in microbial fuel cells (MFCs).

    Science.gov (United States)

    Cheng, Hao-Yi; Liang, Bin; Mu, Yang; Cui, Min-Hua; Li, Kun; Wu, Wei-Min; Wang, Ai-Jie

    2015-09-15

    The challenge of energy generation from biodegradation of recalcitrant organics in microbial fuel cells (MFCs) is mainly attributed to their persistence to degradation under anaerobic condition in anode chamber of MFCs. In this work, we demonstrated that electricity generation from aniline, a typical recalcitrant organic matter under anaerobic condition was remarkably facilitated by employing oxygen into bioanode of MFCs. By exposing bioanode to air, electrons of 47.2 ± 6.9 C were recovered with aniline removal efficiency of 91.2 ± 2.2% in 144 h. Limited oxygen supply (the anodic headspace was initially filled with air and then closed) resulted in the decrease of electrons recovery and aniline removal efficiency by 52.5 ± 9.4% and 74.2 ± 2.1%, respectively, and further decline by respective 64.3 ± 4.5% and 82.7 ± 1.0% occurred under anaerobic condition. Community analysis showed that anode biofilm was predominated by several aerobic aniline degrading bacteria (AADB) and anode-respiration bacteria (ARB), which likely cooperated with each other and finally featured the energy recovery from aniline. Cyclic voltammetry indicated that anodic bacteria transferred electrons to anode mainly through electron shuttle. This study provided a new sight to acquaint us with the positive role of oxygen in biodegradation of recalcitrant organics on anode as well as electricity generation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Experimental and trajectory study on the reaction of protonated methionine with electronically excited singlet molecular oxygen (a1Δg): reaction dynamics and collision energy effects.

    Science.gov (United States)

    Fang, Yigang; Liu, Fangwei; Bennett, Andrew; Ara, Shamim; Liu, Jianbo

    2011-03-24

    The reaction of protonated methionine with the lowest electronically excited state of molecular oxygen O(2)(a(1)Δ(g)) was studied in a guided ion beam apparatus, including the measurement of reaction cross sections over a center-of-mass collision energy (E(col)) range of 0.1-2.0 eV. A series of electronic structure and RRKM calculations were used to examine the properties of various complexes and transition states that might be important along the reaction coordinate. Only one product channel is observed, corresponding to generation of hydrogen peroxide via transfer of two hydrogen atoms (H2T) from protonated methionine to singlet oxygen. At low collision energies, the reaction approaches the collision limit and may be mediated by intermediate complexes. The reaction shows strong inhibition by collision energy, and becomes negligible at E(col) > 1.25 eV. A large set of quasi-classical direct dynamics trajectory simulations were calculated at the B3LYP/6-21G level of theory. Trajectories reproduced experimental results and provided insight into the mechanistic origin of the H2T reaction, how the reaction probability varies with impact parameter, and the suppressing effect of collision energy. Analysis of the trajectories shows that at E(col) = 1.0 eV the reaction is mediated by a precursor and/or hydroperoxide complex, and is sharply orientation-dependent. Only 20% of collisions have favorable reactant orientations at the collision point, and of those, less than half form precursor and hydroperoxide complexes which eventually lead to reaction. The narrow range of reactive collision orientations, together with physical quenching of (1)O(2) via intersystem crossing between singlet and triplet electronic states, may account for the low reaction efficiency observed at high E(col). © 2011 American Chemical Society

  3. High energy nuclear collisions: Theory overview

    Indian Academy of Sciences (India)

    The Universe a few microseconds after the Big Bang was filled with a hot and dense phase of matter. We believe that quarks and gluons at those temperatures, above. 1012 K, were deconfined and existed as a quark gluon plasma (QGP). These ideas can be tested in collisions of nuclei at ultra-relativistic energies.

  4. The high energy source 3C 273

    Science.gov (United States)

    Vonmontigny, Corinna

    1990-01-01

    The properties of 3C 273 are reviewed and an attempt is made to find an answer to the question why 3C 273 is the only extragalactic source so far, which was detected at energies greater than or equal to 50 MeV.

  5. High-energy band structure of gold

    DEFF Research Database (Denmark)

    Christensen, N. Egede

    1976-01-01

    The band structure of gold for energies far above the Fermi level has been calculated using the relativistic augmented-plane-wave method. The calculated f-band edge (Γ6-) lies 15.6 eV above the Fermi level is agreement with recent photoemission work. The band model is applied to interpret...

  6. An fMRI study on variation of visuospatial cognitive performance of young male due to highly concentrated oxygen administration

    Science.gov (United States)

    Chung, Soon Cheol; Kim, Ik Hyeon; Tack, Gye Rae; Sohn, Jin Hun

    2004-04-01

    This study investigated the effects of 30% oxygen administration on the visuospatial cognitive performance using fMRI. Eight college students (right-handed, average age 23.5) were selected as subjects for this study. Oxygen supply equipment which gives 21% and 30% oxygen at a constant rate of 8L/min was developed for this study. To measure the performance of visuospatial cognition, two questionnaires with similar difficulty containing 20 questions each were also developed. Experiment was designed as two runs: run for visuospatial cognition test with normal air (21% of oxygen) and run for visuospatial cognition test with highly concentrated air (30% of oxygen). Run consists of 4 blocks and each block has 8 control problems and 5 visuospatial problems. Functional brain images were taken from 3T MRI using single-shot EPI method. Activities of neural network due to performing visuospatial cognition test were identified using subtraction procedure, and activation areas while performing visuospatial cognition test were extracted using double subtraction procedure. Activities were observed at occipital lobe, parietal lobe, and frontal lobe when performing visuospatial cognition test following both 21% and 30% oxygen administration. But in case of only 30% oxygen administration there were more activities at left precuneus, left cuneus, right postcentral gyrus, bilateral middle frontal gyri, right inferior frontal gyrus, left superior frontal gyrus, bilateral uvula, bilateral pyramis, and nodule compared with 21% oxygen administration. From results of visuospatial cognition test, accuracy rate increased in case of 30% oxygen administration. Thus it could be concluded that highly concentrated oxygen administration has positive effects on the visuospatial cognitive performance.

  7. Deep Nitrate Deficit Observed in the Highly Oxygenated East/Japan Sea and Its Possible Cause

    Directory of Open Access Journals (Sweden)

    Il-Nam Kim

    2012-01-01

    Full Text Available We present evidence of denitrification on the continental slopes of the Ulleung Basin (UB and the Eastern Japan Basin (EJB near the Tatar Strait (TtS in the East/Japan Sea (EJS, despite its high water column dissolved oxygen concentrations. Some nutrient concentration data deviate significantly from the fitted regression line of nitrate (N vs. phosphate (P in deep waters, indicating a loss of nitrate in the region. The EJS has a lower N/P ratio (ca. 12.4 below 300 dbar than a traditional Redfield ratio (16. The N/P ratio and oxygen concentration are substantially lower at several locations whose depths are close to the sediment-water interface, near TtS (500 - 1100 dbar and in UB (1100 - 2200 dbar. The decreased nitrate concentration is smaller than the expected nitrate level (a low N/P ratio of < 12.4, and a secondary nitrite peak near the bottom of these two regions: taken collectively, both indicate the presence of denitrification in the bottom layer. It is speculated that active re-mineralization and denitrification may occur simultaneously along the rich organic matter bottom layer on the slope environment. Denitrification rates are estimated at ~3 - 33 μmol N m-2 d-1. Current estimates do not support the previous idea of basin-wide denitrification in EJS, although the N/P ratio is low like in other hypoxic/anoxic seas. A better understanding of the denitrification process is necessary for predicting future changes of nitrogen cycle in the well-oxygenated EJS considering the decadal-scale physical and biogeochemical changes that have occurred.

  8. Evaluation of Monte Carlo tools for high energy atmospheric physics

    NARCIS (Netherlands)

    C. Rutjes (Casper); D. Sarria (David); A.B. Skeltved (Alexander Broberg); A. Luque (Alejandro); G. Diniz (Gabriel); N. Østgaard (Nikolai); U. Ebert (Ute)

    2016-01-01

    textabstractThe emerging field of high energy atmospheric physics (HEAP) includes terrestrial gamma-ray flashes, electron-positron beams and gamma-ray glows from thunderstorms. Similar emissions of high energy particles occur in pulsed high voltage discharges. Understanding these phenomena requires

  9. Nuclear reactions induced by high-energy alpha particles

    Science.gov (United States)

    Shen, B. S. P.

    1974-01-01

    Experimental and theoretical studies of nuclear reactions induced by high energy protons and heavier ions are included. Fundamental data needed in the shielding, dosimetry, and radiobiology of high energy particles produced by accelerators were generated, along with data on cosmic ray interaction with matter. The mechanism of high energy nucleon-nucleus reactions is also examined, especially for light target nuclei of mass number comparable to that of biological tissue.

  10. Summaries of FY 1977, research in high energy physics

    Energy Technology Data Exchange (ETDEWEB)

    1977-10-01

    The U.S. Department of Energy, through the Office of Energy Research and the Division of High Energy and Nuclear Physics, provides approximately 90% of the total federal support for high energy physics research effort in the United States. The High Energy Physics Program primarily utilizes four major U.S. high energy accelerator facilities and over 50 universities under contract to do experimental and theoretical investigations on the properties, structure and transformation of matter and energy in their most basic forms. This compilation of research summaries is intended to present a convenient report of the scope and nature of high energy physics research presently funded by the U.S. Department of Energy. The areas covered include conception, design, construction, and operation of particle accelerators; experimental research using the accelerators and ancillary equipment; theoretical research; and research and development programs to advance accelerator technology, particle detector systems, and data analysis capabilities. Major concepts and experimental facts in high energy physics have recently been discovered which have the promise of unifying the fundamental forces and of understanding the basic nature of matter and energy. The summaries contained in this document were reproduced in essentially the form submitted by contractors as of January 1977.

  11. Photoexcited ZnO nanoparticles with controlled defects as a highly sensitive oxygen sensor

    Science.gov (United States)

    Goto, Taku; Shimizu, Yoshiki; Yasuda, Hidehiro; Ito, Tsuyohito

    2016-07-01

    Conductance of photoexcited ZnO nanoparticles with various defects has been investigated in oxygen. ZnO nanoparticles, which show strong photoluminescence peaks originating from interstitial zinc atom (Zni) and singly charged oxygen vacancy (VO+), show oxygen-pressure-dependent conductance changes caused by photoexcitation. Herein, a model is proposed to simulate the conductance changes.

  12. Reduced sludge growth at high bulk liquor dissolved oxygen induced by increased secondary cell maintenance.

    Science.gov (United States)

    Khursheed, Anwar; Tyagi, Vinay Kumar; Gaur, Rubia Z; Sharma, Meena Kumari; Khan, Abid Ali; Kazmi, A A

    2017-10-01

    Sludge reduction by physico-chemical methods results in the buildup of chemicals, which may require further treatment. Owing these reasons various biologically sustainable methods of sludge reduction including the application of high oxygenation have been successfully tested. Experiments on actual sewage in two lab-scale sequencing batch reactors (SBRs) were conducted under normal (1.5-2.5 mgDO/L) and high dissolved oxygen (DO) (HDO: 3-6.5 mgDO/L) regimes. It was observed that microorganism allocated substrate between maintenance and growth in the form of maintenance coefficient. Which could be induced by endogenous respiration owing to high solids retention time (SRT), predation on bacteria, chemical toxicity, adverse environment, and viral attack on bacteria. The wastewater treatment process may experience one or more maintenance inducing factors; nevertheless, high SRT and prevailing environmental conditions are imminent and thus considered as primary maintenance (m p ), while remaining are classified as secondary maintenance (m s ). Average yield coefficient reduction at HDO was 32.7% and 28.2% compared to stoichiometric and at normal DO, respectively. The observed primary and secondary maintenance was 0.11gCOD/gVSS.d (±0.01) at an SRT of 25.2 d (±2.0) and 0.096 g 0.1 gCOD/gVSS.d (±0.045) at an SRT of 24.2 d (±3.6d), respectively. The results obtained under the study are not as precise as on pure culture and defined substrate, nevertheless, it gives an idea that how stress factors inducing maintenance need to be addressed more seriously and objectively while managing our efforts on sludge reduction. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Studies of High Energy Particle Astrophysics

    Energy Technology Data Exchange (ETDEWEB)

    Nitz, David F [Michigan Technological University; Fick, Brian E [Michigan Technological University

    2014-07-30

    This report covers the progress of the Michigan Technological University particle astrophysics group during the period April 15th, 2011 through April 30th, 2014. The principal investigator is Professor David Nitz. Professor Brian Fick is the Co-PI. The focus of the group is the study of the highest energy cosmic rays using the Pierre Auger Observatory. The major goals of the Pierre Auger Observatory are to discover and understand the source or sources of cosmic rays with energies exceeding 10**19 eV, to identify the particle type(s), and to investigate the interactions of those cosmic particles both in space and in the Earth's atmosphere. The Pierre Auger Observatory in Argentina was completed in June 2008 with 1660 surface detector stations and 24 fluorescence telescopes arranged in 4 stations. It has a collecting area of 3,000 square km, yielding an aperture of 7,000 km**2 sr.

  14. High-energy particles. [in Jovian magnetosphere

    Science.gov (United States)

    Schardt, A. W.; Goertz, C. K.

    1983-01-01

    It is pointed out that the magnetosphere of Jupiter is in many respects quite different from that of the earth. The energy required to drive the Jovian magnetosphere is apparently extracted from Jupiter's rotational energy rather than from the solar wind. Jupiter is a strong source of energetic charged particles which can be detected as far away as the orbit of Mercury. The structure and dynamics of the energetic particle distribution in the inner magnetosphere is discussed, taking into account observations, transport and losses in the inner magnetosphere, satellite interactions, and electron synchrotron radiation. The subsolar hemisphere is considered, giving attention to particle fluxes in the subsolar magnetosphere, conditions in the middle magnetosphere, and the characteristics of the outer magnetosphere. A description of the predawn magnetosphere is also provided.

  15. High energy physics in cosmic rays

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Lawrence W. [University of Michigan, Ann Arbor, Michigan (United States)

    2013-02-07

    In the first half-century of cosmic ray physics, the primary research focus was on elementary particles; the positron, pi-mesons, mu-mesons, and hyperons were discovered in cosmic rays. Much of this research was carried out at mountain elevations; Pic du Midi in the Pyrenees, Mt. Chacaltaya in Bolivia, and Mt. Evans/Echo Lake in Colorado, among other sites. In the 1960s, claims of the observation of free quarks, and satellite measurements of a significant rise in p-p cross sections, plus the delay in initiating accelerator construction programs for energies above 100 GeV, motivated the Michigan-Wisconsin group to undertake a serious cosmic ray program at Echo Lake. Subsequently, with the succession of higher energy accelerators and colliders at CERN and Fermilab, cosmic ray research has increasingly focused on cosmology and astrophysics, although some groups continue to study cosmic ray particle interactions in emulsion chambers.

  16. Temporal optimization of ultrabroadband high-energy OPCPA

    National Research Council Canada - National Science Library

    Jeffrey Moses; Cristian Manzoni; Shu-Wei Huang; Giulio Cerullo; Franz X. Kaertner

    2009-01-01

    We present general guidelines for the design of ultrabroadband, high-energy optical parametric chirped-pulse amplifiers, where maximization of both conversion efficiency and bandwidth and simultaneous...

  17. Predicting the statistics of high-energy astrophysical backgrounds

    NARCIS (Netherlands)

    Feyereisen, M.R.

    2017-01-01

    This thesis presents improvements to a methodology for predicting the probability distribution of diffuse isotropic astrophysical backgrounds, applied to high-energy extragalactic gamma rays and neutrinos.

  18. Reactive oxygen species-based measurement of the dependence of the Coulomb nanoradiator effect on proton energy and atomic Z value.

    Science.gov (United States)

    Seo, Seung-Jun; Jeon, Jae-Kun; Han, Sung-Mi; Kim, Jong-Ki

    2017-11-01

    The Coulomb nanoradiator (CNR) effect produces the dose enhancement effects from high-Z nanoparticles under irradiation with a high-energy ion beam. To gain insight into the radiation dose and biological significance of the CNR effect, the enhancement of reactive oxygen species (ROS) production from iron oxide or gold NPs (IONs or AuNPs, respectively) in water was investigated using traversing proton beams. The dependence of nanoradiator-enhanced ROS production on the atomic Z value and proton energy was investigated. Two biologically important ROS species were measured using fluorescent probes specific to •OH or [Formula: see text] in a series of water phantoms containing either AuNPs or IONs under irradiation with a 45- or 100-MeV proton beam. The enhanced generation of hydroxyl radicals (•OH) and superoxide anions ([Formula: see text]) was determined to be caused by the dependence on the NP concentration and proton energy. The proton-induced Au or iron oxide nanoradiators exhibited different ROS enhancement rates depending on the proton energy, suggesting that the CNR radiation varied. The curve of the superoxide anion production from the Au-nanoradiator showed strong non-linearity, unlike the linear behavior observed for hydroxyl radical production and the X-ray photoelectric nanoradiator. In addition, the 45-MeV proton-induced Au nanoradiator exhibited an ROS enhancement ratio of 8.54/1.50 ([Formula: see text] / •OH), similar to that of the 100-KeV X-ray photoelectric Au nanoradiator (7.68/1.46). The ROS-based detection of the CNR effect revealed its dependence on the proton beam energy, dose and atomic Z value and provided insight into the low-linear energy transfer (LET) CNR radiation, suggesting that these factors may influence the therapeutic efficacy via chemical reactivities, transport behaviors, and intracellular oxidative stress.

  19. Highly sensitive fiber-optic oxygen sensor based on palladium tetrakis (4-carboxyphenyl)porphyrin doped in ormosil

    Energy Technology Data Exchange (ETDEWEB)

    Chu, Cheng-Shane, E-mail: cschu@mail.mcut.edu.tw; Chuang, Chih-Yung

    2014-10-15

    A simple, low-cost technique for fabrication of highly sensitive fiber-optic oxygen sensor is described. An organically modified silicate (ORMOSIL) as a matrix for the fabrication of oxygen sensing film was produced. The technique is based on coating the end of a plastic optical fiber with ormosil composite xerogel film sequestered with luminophore palladium (II) meso-tetra(4-carboxyphenyl)porphyrin (PdTCPP) prepared by a sol–gel process. The composite xerogel studied is tetraethylorthosilane (TEOS)/n-octyltriethoxysilane (Octyl-triEOS). Result shows that, expect for PdTCPP-doped TEOS/Octyl-triEOS composite xerogel show the high sensitivity and linear Stern–Volmer relationship which indicate the homogenous environment of the luminophore. The sensitivity of the optical oxygen sensor is quantified in terms of the ratio I{sub N2}/I{sub O2}, where I{sub N2} and I{sub O2} represent the detected fluorescence intensities in pure nitrogen and pure oxygen environments, respectively. The experimental result reveals that the PdTCPP-doped TEOS/Octyl-triEOS oxygen sensor has sensitivity of 153. - Highlights: • A simple, low-cost technique for fabrication of highly sensitive fiber-optic oxygen sensor is described. • ORMOSIL was produced to serve as a matrix for the fabrication of oxygen sensing film. • The fiber-optic oxygen sensor has sensitivity of I{sub N2}/I{sub 100O2}=153. • The stable and reproducible signals were obtained with the fiber-optic oxygen sensor.

  20. High-flow warm humidified oxygen versus standard low-flow nasal cannula oxygen for moderate bronchiolitis (HFWHO RCT): an open, phase 4, randomised controlled trial.

    Science.gov (United States)

    Kepreotes, Elizabeth; Whitehead, Bruce; Attia, John; Oldmeadow, Christopher; Collison, Adam; Searles, Andrew; Goddard, Bernadette; Hilton, Jodi; Lee, Mark; Mattes, Joerg

    2017-03-04

    Bronchiolitis is the most common lung infection in infants and treatment focuses on management of respiratory distress and hypoxia. High-flow warm humidified oxygen (HFWHO) is increasingly used, but has not been rigorously studied in randomised trials. We aimed to examine whether HFWHO provided enhanced respiratory support, thereby shortening time to weaning off oxygen. In this open, phase 4, randomised controlled trial, we recruited children aged less than 24 months with moderate bronchiolitis attending the emergency department of the John Hunter Hospital or the medical unit of the John Hunter Children's Hospital in New South Wales, Australia. Patients were randomly allocated (1:1) via opaque sealed envelopes to HFWHO (maximum flow of 1 L/kg per min to a limit of 20 L/min using 1:1 air-oxygen ratio, resulting in a maximum FiO2 of 0·6) or standard therapy (cold wall oxygen 100% via infant nasal cannulae at low flow to a maximum of 2 L/min) using a block size of four and stratifying for gestational age at birth. The primary outcome was time from randomisation to last use of oxygen therapy. All randomised children were included in the primary and secondary safety analyses. This trial is registered with the Australian New Zealand Clinical Trials Registry, number ACTRN12612000685819. From July 16, 2012, to May 1, 2015, we randomly assigned 202 children to either HFWHO (101 children) or standard therapy (101 children). Median time to weaning was 24 h (95% CI 18-28) for standard therapy and 20 h (95% CI 17-34) for HFWHO (hazard ratio [HR] for difference in survival distributions 0·9 [95% CI 0·7-1·2]; log rank p=0·61). Fewer children experienced treatment failure on HFWHO (14 [14%]) compared with standard therapy (33 [33%]; p=0·0016); of these children, those on HFWHO were supported for longer than were those on standard therapy before treatment failure (HR 0·3; 95% CI 0·2-0·6; p<0·0001). 20 (61%) of 33 children who experienced treatment failure on standard

  1. Recombination of atomic oxygen on sintered zirconia at high temperature in non-equilibrium air plasma

    Energy Technology Data Exchange (ETDEWEB)

    Balat-Pichelin, M., E-mail: marianne.balat@promes.cnrs.fr [Laboratoire Procedes, Materiaux et Energie Solaire, PROMES-CNRS, UPR 8521, 7 rue du four solaire, 66120 Font-Romeu Odeillo (France); Passarelli, M.; Vesel, A. [Laboratoire Procedes, Materiaux et Energie Solaire, PROMES-CNRS, UPR 8521, 7 rue du four solaire, 66120 Font-Romeu Odeillo (France)

    2010-09-01

    High temperature ceramic materials are necessary for the design of primary heat shields for future re-usable space vehicles re-entering atmospheric planet at hypersonic velocity. During the re-entry phase on earth, one of the most important phenomena occurring on the heat shield is the recombination of atomic oxygen and this phenomenon is more or less catalyzed by the material of the heat shield. This paper presents some experimental results for the recombination coefficient of atomic oxygen {gamma} based on experiments performed on the MESOX facility using optical emission spectroscopy and actinometry techniques. Experimental results on the recombination coefficient are presented for three types of sintered ZrO{sub 2} in the temperature range 900-2500 K for 200 Pa total air pressure. These three zirconia ceramics differ essentially by the chemical nature of the sintering additives (Y{sub 2}O{sub 3}, CaO or MgO). A great different behavior of the recombination coefficient versus temperature is observed according to the crystalline structure of zirconia (monoclinic and tetragonal phases) and few influence of the additive is shown.

  2. High tonnage harvesting and skidding for loblolly pine energy plantations

    Science.gov (United States)

    Patrick Jernigan; Tom Gallagher; Dana Mitchell; Mathew Smidt; Larry Teeter

    2016-01-01

    The southeastern United States has a promising source for renewable energy in the form of woody biomass. To meet the energy needs, energy plantations will likely be utilized. These plantations will contain a high density of small-stem pine trees. Since the stems are relatively small when compared with traditional product removal, the harvesting costs will increase. The...

  3. Optimization of a neutron dosimeter for the high energy accelerators

    Directory of Open Access Journals (Sweden)

    Sokolov Alexey

    2017-01-01

    Full Text Available In high energy accelerator facilities the neutron radiation should be continuously measured during operation to control the ambient dose. This requires a reliable neutron dosimeter in a wide energy range. In this work we present an optimization of a compact cylindrical passive neutron dosimeter for the usage in wide energy neutron fields.

  4. Oxygen safety

    Science.gov (United States)

    COPD - oxygen safety; Chronic obstructive pulmonary disease - oxygen safety; Chronic obstructive airways disease - oxygen safety; Emphysema - oxygen safety; Heart failure - oxygen-safety; Palliative care - oxygen safety; Hospice - oxygen safety

  5. High-concentration versus titrated oxygen therapy in ST-elevation myocardial infarction: a pilot randomized controlled trial.

    Science.gov (United States)

    Ranchord, Anil M; Argyle, Rachel; Beynon, Rhys; Perrin, Kyle; Sharma, Vishal; Weatherall, Mark; Simmonds, Mark; Heatlie, Grant; Brooks, Nicholas; Beasley, Richard

    2012-02-01

    The optimal approach to oxygen therapy in ST-elevation myocardial infarction (STEMI) is uncertain. A randomized controlled trial was undertaken in which 136 patients presenting with their first STEMI uncomplicated by cardiogenic shock or marked hypoxia were randomized to receive high-concentration (6 L/min via medium concentration mask) or titrated oxygen (to achieve oxygen saturation 93%-96%) for 6 hours after presentation. The main outcome variables were 30-day mortality and infarct size assessed by troponin T level at 72 hours. Secondary outcomes included a meta-analysis of mortality data from this study and previous randomized controlled trials, and infarct size was assessed by magnetic resonance imaging at 4 to 6 weeks. There were 1 of 68 and 2 of 68 deaths in the high-concentration and titrated oxygen groups, respectively; a meta-analysis including these data with those from the 2 previous studies showed an odds ratio for mortality of high-concentration oxygen compared with room air or titrated oxygen of 2.2 (95% CI 0.8-6.0). There was no significant difference between high-concentration versus titrated oxygen in troponin T (ratio of mean levels 0.74, 95% CI 0.50-1.1, P = .14), infarct mass (mean difference -0.8 g, 95% CI -7.6 to 6.1, P = .82), or percent infarct mass (mean difference -0.6%, 95% CI -5.6 to 4.5, P = .83). This study found no evidence of benefit or harm from high-concentration compared with titrated oxygen in initially uncomplicated STEMI. However, our estimates have wide CIs, and as a result, large randomized controlled trials are required to resolve the clinical uncertainty. Copyright © 2012 Mosby, Inc. All rights reserved.

  6. Trajectories of high energy electrons in a plasma focus

    Science.gov (United States)

    Harries, W. L.; Lee, J. H.; Mcfarland, D. R.

    1978-01-01

    Measurements are made of high-energy electron trajectories in a plasma focus as functions of position, time, energy, and angle of emission. The spatial resolution of the X-ray emission shows that low-energy X-rays are emitted from the anode surface. It is also suggested that the highest energy X-rays originate from a small region on the axis. The so-called shadow technique shows that the electron beam is perpendicular to the anode surface. Polar diagrams of medium and high-energy X-rays agree with the bremsstrahlung emission from a relativistic electron beam, the current of which is several 100 A.

  7. Highly Active and Stable Fe-N-C Catalyst for Oxygen Depolarized Cathode Applications.

    Science.gov (United States)

    Li, Jingkun; Jia, Qingying; Ghoshal, Shraboni; Liang, Wentao; Mukerjee, Sanjeev

    2017-09-19

    Anion immunity toward the oxygen reduction reaction (ORR) has tremendous implications in electrocatalysis with applications for fuel cells, metal-air batteries, and oxygen depolarized cathodes (ODCs) in the anodic evolution of chlorine. The necessity of exploring ORR catalysts with immunity to anion adsorption is particularly significant considering that platinum group metal (PGM) catalysts are costly and highly vulnerable to impurities such as halides. Herein, we report a metal organic framework (MOF)-derived Fe-N-C catalyst that exhibits a dramatically improved half-wave potential of 240 mV compared to the state-of-the-art Rh x S y /C catalyst in a rotating disk electrode in the presence of Cl - . The Fe-N 4 active sites in Fe-N-C are intrinsically immune to Cl - poisoning, in contrast to Pt/C, which is severely susceptible to Cl - poisoning. As a result, the activity of Fe-N-C decreases only marginally in the presence of Cl - , far exceeding that of Pt/C. The viability of this catalyst as ODCs is further demonstrated in real-life hydrochloric acid electrolyzers using highly concentrated HCl solution saturated with Cl 2 gas as the electrolyte. The introduction of Fe-N-C materials as ODC catalysts here overcomes the limitations of (i) the low intrinsic ORR activity of Rh x S y /C as the state-of-the-art ODC catalyst; (ii) the vulnerability to Cl - poisoning of Pt/C as the state-of-the-art ORR catalyst; and (iii) the high cost of precious metals in these two materials, resulting in a cost-effective ODC catalyst with the overall performance exceeding that of all previously reported materials.

  8. Changes in the energy spectrum of anomalous oxygen and helium during 1977-1985

    Science.gov (United States)

    Cummings, A. C.; Stone, E. C.; Webber, W. R.

    1985-01-01

    Data was used from the cosmic ray experiment on the Voyager spacecraft to measure the energy spectrum of anomalous O and He during the period 1977 to 1985. These spectra are found to change dramatically after the middle of 1980, with the peak of plateau region of the differential spectrum shifting to a higher energy. This change appears to be related to the reversal of the solar magnetic field and could imply that particle drifts are important to the acceleration of propagation of these particles.

  9. Glycolytic Coupling to Mitochondrial Energy Production Ensures Survival in an Oxygen Rich Environment.

    Science.gov (United States)

    Stefano, George B; Kream, Richard M

    2016-07-20

    The mitochondrion exhibits biochemical and functional variations that emerged by random chance as an evolutionary survival strategy, which include enhanced energy production driven by anaerobic respiratory mechanisms. In invertebrates, this mitochondrial anaerobic respiration permits survival at a lower energy state suited for this type of environment while yielding more ATP than by glycolysis alone. This ability provides a protective existential advantage in naturally occurring hypoxic environments via diminished free radical generation. In the blue mussel Mytilus edulis and other marine organisms, a functionally active mitochondrial anaerobic respiratory mechanism tailored to hypoxic conditions reflects an evolutionary adaptation/reworking of ancient metabolic pathways. Components of these pathways were also discovered and characterized as metabolic intermediates in plant parasites, specifically crown gall tumors. Mechanistic similarities between anaerobically functioning mitochondria in M. edulis and crown gall tissues and metabolic processes in human tumors are known to occur, demonstrating commonalities in diverse life energy processes. Furthermore, cytoplasmic glycolytic processes are now shown also to exhibit a dynamic capacity for enhanced energy generation by increasing its efficiency in hypoxic environments, making it equally dynamic in meeting its cellular survival goal.

  10. Effect of high-oxygen atmosphere packaging on oxidative stability and sensory quality of two chicken muscles during chill storage

    DEFF Research Database (Denmark)

    Jongberg, Sisse; Wen, Jinzhu; Tørngren, Mari Ann

    2014-01-01

    The oxidative stability and sensory quality of chicken breast (m. pectoralis) and thigh (m. peroneus longus) stored in high-oxygen modified atmosphere (MAP-O), non-oxygen modified atmosphere (MAP-N), or vacuum for up to 9 days at 5°C were investigated. Protein thiol concentration in breasts...... in MAP-O than breast, indicating that the negative effect MAP-O may have on the oxidative stability and sensory quality of meat varies between different muscles....

  11. Co-axial, high energy gamma generator

    Science.gov (United States)

    Reijonen, Jani Petteri [Princeton, NJ; Gicquel, Frederic [Pennington, NJ

    2011-08-16

    A gamma ray generator includes an ion source in a first chamber. A second chamber is configured co-axially around the first chamber at a lower second pressure. Co-axially arranged plasma apertures separate the two chambers and provide for restricted passage of ions and gas from the first to the second chamber. The second chamber is formed by a puller electrode having at least one long channel aperture to draw ions from the first chamber when the puller electrode is subject to an appropriate applied potential. A plurality of electrodes rings in the third chamber in third pressure co-axially surround the puller electrode and have at least one channel corresponding to the at least one puller electrode aperture and plasma aperture. The electrode rings increase the energy of the ions to a selected energy in stages in passing between successive pairs of the electrodes by application of an accelerating voltage to the successive pairs of accelerator electrodes. A target disposed co-axially around the plurality of electrodes receives the beam of accelerated ions, producing gamma rays.

  12. ZIF-67 incorporated with carbon derived from pomelo peels: A highly efficient bifunctional catalyst for oxygen reduction/evolution reactions

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hao; Yin, Feng-Xiang; Chen, Biao-Hua; He, Xiao-Bo; Lv, Peng-Liang; Ye, Cai-Yun; Liu, Di-Jia

    2017-05-01

    Developing carbon catalyst materials using natural, abundant and renewable resources as precursors plays an increasingly important role in clean energy generation and environmental protection. In this work, N-doped pomelo-peel-derived carbon (NPC) materials were prepared using a widely available food waste-pomelo peels and melamine. The synthetic NPC exhibits well-defined porosities and a highly doped-N content (e.g. 6.38 at% for NPC-2), therefore affords excellent oxygen reduction reaction (ORR) catalytic activities in alkaline electrolytes. NPC was further integrated with ZIF-67 to form ZIF-67@NPC hybrids through solvothermal reactions. The hybrid catalysts show substantially enhanced ORR catalytic activities comparable to that of commercial 20 wa Pt/C. Furthermore, the catalysts also exhibit excellent oxygen evolution reaction (OER) catalytic activities. Among all prepared ZIF-67@NPC hybrids, the optimal composition with ZIF-67 to NPC ratio of 2:1 exhibits the best ORR and OER bifunctional catalytic performance and the smallest Delta E (E-OER@10 mA cm(-2)-E-ORR@-1 mA cm(-2)) value of 0.79 V. The catalyst also demonstrated desirable 4-electron transfer pathways and superior catalytic stabilities. The Co-N-4 in ZIF-67, electrochemical active surface area, and the strong interactions between ZIF-67 and NPC are attributed as the main contributors to the bifunctional catalytic activities. These factors act synergistically, resulting in substantially enhanced bifunctional catalytic activities and stabilities; consequently, this hybrid catalyst is among the best of the reported bifunctional electrocatalysts and is promising for use in metal-air batteries and fuel cells. (C) 2016 Elsevier B.V. All rights reserved.

  13. Microstructure Characterization of WCCo-Mo Based Coatings Produced Using High Velocity Oxygen Fuel

    Directory of Open Access Journals (Sweden)

    Serkan Islak

    2015-12-01

    Full Text Available The present study has been carried out in order to investigate the microstructural properties of WCCo-Mo composite coatings deposited onto a SAE 4140 steel substrate by high velocity oxygen fuel (HVOF thermal spray. For this purpose, the Mo quantity added to the WCCo was changed as 10, 20, 30 and 40 wt. % percents. The coatings are compared in terms of their phase composition, microstructure and hardness. Phase compound and microstructure of coating layers were examined using X-ray diffractometer (XRD and scanning electron microscope (SEM. XRD results showed that WCCo-Mo composite coatings were mainly composed of WC, W2C, Co3W3C, Mo2C, MoO2, Mo and Co phases. The average hardness of the coatings increased with increasing Mo content.

  14. Tooth enamel oxygen "isoscapes" show a high degree of human mobility in prehistoric Britain.

    Science.gov (United States)

    Pellegrini, Maura; Pouncett, John; Jay, Mandy; Pearson, Mike Parker; Richards, Michael P

    2016-10-07

    A geostatistical model to predict human skeletal oxygen isotope values (δ18Op) in Britain is presented here based on a new dataset of Chalcolithic and Early Bronze Age human teeth. The spatial statistics which underpin this model allow the identification of individuals interpreted as 'non-local' to the areas where they were buried (spatial outliers). A marked variation in δ18Op is observed in several areas, including the Stonehenge region, the Peak District, and the Yorkshire Wolds, suggesting a high degree of human mobility. These areas, rich in funerary and ceremonial monuments, may have formed focal points for people, some of whom would have travelled long distances, ultimately being buried there. The dataset and model represent a baseline for future archaeological studies, avoiding the complex conversions from skeletal to water δ18O values-a process known to be problematic.

  15. Tooth enamel oxygen “isoscapes” show a high degree of human mobility in prehistoric Britain

    Science.gov (United States)

    Pellegrini, Maura; Pouncett, John; Jay, Mandy; Pearson, Mike Parker; Richards, Michael P.

    2016-10-01

    A geostatistical model to predict human skeletal oxygen isotope values (δ18Op) in Britain is presented here based on a new dataset of Chalcolithic and Early Bronze Age human teeth. The spatial statistics which underpin this model allow the identification of individuals interpreted as ‘non-local’ to the areas where they were buried (spatial outliers). A marked variation in δ18Op is observed in several areas, including the Stonehenge region, the Peak District, and the Yorkshire Wolds, suggesting a high degree of human mobility. These areas, rich in funerary and ceremonial monuments, may have formed focal points for people, some of whom would have travelled long distances, ultimately being buried there. The dataset and model represent a baseline for future archaeological studies, avoiding the complex conversions from skeletal to water δ18O values-a process known to be problematic.

  16. Structured back gates for high-mobility two-dimensional electron systems using oxygen ion implantation

    Energy Technology Data Exchange (ETDEWEB)

    Berl, M., E-mail: mberl@phys.ethz.ch; Tiemann, L.; Dietsche, W.; Wegscheider, W. [Solid State Physics Laboratory, ETH Zürich, 8093 Zürich (Switzerland); Karl, H. [Lehrstuhl für Experimentalphysik IV, Universität Augsburg, 86159 Augsburg (Germany)

    2016-03-28

    We present a reliable method to obtain patterned back gates compatible with high mobility molecular beam epitaxy via local oxygen ion implantation that suppresses the conductivity of an 80 nm thick silicon doped GaAs epilayer. Our technique was optimized to circumvent several constraints of other gating and implantation methods. The ion-implanted surface remains atomically flat which allows unperturbed epitaxial overgrowth. We demonstrate the practical application of this gating technique by using magneto-transport spectroscopy on a two-dimensional electron system (2DES) with a mobility exceeding 20 × 10{sup 6} cm{sup 2}/V s. The back gate was spatially separated from the Ohmic contacts of the 2DES, thus minimizing the probability for electrical shorts or leakage and permitting simple contacting schemes.

  17. A graphene quantum dot photodynamic therapy agent with high singlet oxygen generation

    Science.gov (United States)

    Ge, Jiechao; Lan, Minhuan; Zhou, Bingjiang; Liu, Weimin; Guo, Liang; Wang, Hui; Jia, Qingyan; Niu, Guangle; Huang, Xing; Zhou, Hangyue; Meng, Xiangmin; Wang, Pengfei; Lee, Chun-Sing; Zhang, Wenjun; Han, Xiaodong

    2014-08-01

    Clinical applications of current photodynamic therapy (PDT) agents are often limited by their low singlet oxygen (1O2) quantum yields, as well as by photobleaching and poor biocompatibility. Here we present a new PDT agent based on graphene quantum dots (GQDs) that can produce 1O2 via a multistate sensitization process, resulting in a quantum yield of ~1.3, the highest reported for PDT agents. The GQDs also exhibit a broad absorption band spanning the UV region and the entire visible region and a strong deep-red emission. Through in vitro and in vivo studies, we demonstrate that GQDs can be used as PDT agents, simultaneously allowing imaging and providing a highly efficient cancer therapy. The present work may lead to a new generation of carbon-based nanomaterial PDT agents with overall performance superior to conventional agents in terms of 1O2 quantum yield, water dispersibility, photo- and pH-stability, and biocompatibility.

  18. Highly oxygenated lanostane-type triterpenoids and their bioactivity from the fruiting body of Ganoderma gibbosum.

    Science.gov (United States)

    Pu, De-Bing; Zheng, Xi; Gao, Jun-Bo; Zhang, Xing-Jie; Qi, Yan; Li, Xiao-Si; Wang, Yong-Mei; Li, Xiao-Nian; Li, Xiao-Li; Wan, Chun-Ping; Xiao, Wei-Lie

    2017-06-01

    Eight new highly oxygenated lanostane triterpenes, gibbosic acids A-H (1-8), along with three known ones (9-11), were isolated from the fruiting body of Ganoderma gibbosum. The structures of new isolates were assigned by NMR and HRESIMS experiments. The absolute configurations of 1 were further confirmed by single crystal X-ray diffraction data and computational ECD methods. Immunoregulatory effect and anti-inflammatory activities of these compounds were screened in murine lymphocyte proliferation assay and in lipopolysaccharide (LPS)-stimulated RAW-264.7 macrophages, respectively. Compound 2 exhibited immunostimulatory effect both in lymphocyte proliferation assay without any induction and ConA-induced mitogenic activity of T-lymphocyte, and the proportion of lymphocyte proliferation at the concentration of 0.1μM are 20.01% and 21.40%, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. A graphene quantum dot photodynamic therapy agent with high singlet oxygen generation

    Science.gov (United States)

    Ge, Jiechao; Lan, Minhuan; Zhou, Bingjiang; Liu, Weimin; Guo, Liang; Wang, Hui; Jia, Qingyan; Niu, Guangle; Huang, Xing; Zhou, Hangyue; Meng, Xiangmin; Wang, Pengfei; Lee, Chun-Sing; Zhang, Wenjun; Han, Xiaodong

    2014-01-01

    Clinical applications of current photodynamic therapy (PDT) agents are often limited by their low singlet oxygen (1O2) quantum yields, as well as by photobleaching and poor biocompatibility. Here we present a new PDT agent based on graphene quantum dots (GQDs) that can produce 1O2 via a multistate sensitization process, resulting in a quantum yield of ~1.3, the highest reported for PDT agents. The GQDs also exhibit a broad absorption band spanning the UV region and the entire visible region and a strong deep-red emission. Through in vitro and in vivo studies, we demonstrate that GQDs can be used as PDT agents, simultaneously allowing imaging and providing a highly efficient cancer therapy. The present work may lead to a new generation of carbon-based nanomaterial PDT agents with overall performance superior to conventional agents in terms of 1O2 quantum yield, water dispersibility, photo- and pH-stability, and biocompatibility. PMID:25105845

  20. Apparatus for advancing a wellbore using high power laser energy

    Science.gov (United States)

    Zediker, Mark S.; Land, Mark S.; Rinzler, Charles C.; Faircloth, Brian O.; Koblick, Yeshaya; Moxley, Joel F.

    2014-09-02

    Delivering high power laser energy to form a borehole deep into the earth using laser energy. Down hole laser tools, laser systems and laser delivery techniques for advancement, workover and completion activities. A laser bottom hole assembly (LBHA) for the delivery of high power laser energy to the surfaces of a borehole, which assembly may have laser optics, a fluid path for debris removal and a mechanical means to remove earth.