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Sample records for hf soluble part

  1. Issues concerning the determination of solubility products of sparingly soluble crystalline solids. Solubility of HfO{sub 2}(cr)

    Energy Technology Data Exchange (ETDEWEB)

    Rai, Dhanpat [Rai Enviro-Chem, LLC, Yachats, OR (United States); Kitamura, Akira [Japan Atomic Energy Agency, Ibaraki (Japan); Rosso, Kevin M. [Pacific Northwest National Laboratory, Richland, WA (United States); Sasaki, Takayuki; Kobayashi, Taishi [Kyoto Univ. (Japan)

    2016-11-01

    Solubility studies were conducted with HfO{sub 2}(cr) solid as a function HCl and ionic strength ranging from 2.0 to 0.004 mol kg{sup -1}. These studies involved (1) using two different amounts of the solid phase, (2) acid washing the bulk solid phase, (3) preheating the solid phase to 1400 C, and (4) heating amorphous HfO{sub 2}(am) suspensions to 90 C to ascertain whether the HfO{sub 2}(am) converts to HfO{sub 2}(cr) and to determine the solubility from the oversaturation direction. Based on the results of these treatments it is concluded that the HfO{sub 2}(cr) contains a small fraction of less crystalline, but not amorphous, material [HfO{sub 2}(lcr)] and this, rather than the HfO{sub 2}(cr), is the solubility-controlling phase in the range of experimental variables investigated in this study. The solubility data are interpreted using both the Pitzer and SIT models and they provide log{sub 10} K{sup 0} values of -(59.75±0.35) and -(59.48±0.41), respectively, for the solubility product of HfO{sub 2}(lcr)[HfO{sub 2}(lcr) + 2H{sub 2}O ↔ Hf{sup 4+} + 4OH{sup -}]. The log{sub 10} of the solubility product of HfO{sub 2}(cr) is estimated to be < -63. The observation of a small fraction of less crystalline higher solubility material is consistent with the general picture that mineral surfaces are often structurally and/or compositionally imperfect leading to a higher solubility than the bulk crystalline solid. This study stresses the urgent need, during interpretation of solubility data, of taking precautions to make certain that the observed solubility behavior for sparingly-soluble solids is assigned to the proper solid phase.

  2. Solubility Part 1

    NARCIS (Netherlands)

    Tantra, Ratna; Bolea, Eduardo; Bouwmeester, H.; Rey-Castro, Carlos; David, C.A.A.; Dogné, Jean Michel; Laborda, Francisco; Laloy, Julie; Robinson, Kenneth N.; Undas, A.K.; Zande, van der M.

    2016-01-01

    This chapter gives an overview of different methods that can potentially be used to determine the solubility of nanomaterials. In general, the methods presented can be broadly divided into four categories: separation methods, methods to quantify free ions, methods to quantify total dissolved

  3. Rules for maximum solid solubility of transition metals in Ti, Zr and Hf solvents

    Institute of Scientific and Technical Information of China (English)

    周自强; 方守狮; 冯锋

    2003-01-01

    Based on the principle of energy change of alloy formation, the rules for the maximum solid solubility (Cmax) of various transition metals in the metals Ti, Zr and Hf were studied. It is deduced that the Cmax of transition metals in the metals Ti, Zr and Hf can be described as a semi-empirical equation using three atomic parameters, i.e., electronegativity difference, atomic diameter and electron concentration. From the equation analysis by using experimental data, it shows that atomic size parameter and electronegativity difference are the main factors that affect the Cmax of the transition metals in the metals Ti, Zr and Hf while electron concentration parameter has the smallest effect on Cmax.

  4. Solid Solubilities of Pu, U, Gd and Hf in Candidate Ceramic Nuclear Wasteforms

    Energy Technology Data Exchange (ETDEWEB)

    Vance, Eric R.; Carter, M. L.; Lumpkin, G. R.; Day, R. A.; Begg, B. D.

    2001-04-02

    This goal of this research project was to determine the solid solubility of Pu, U, Gd, and Hf in candidate ceramics for immobilization of high-level nuclear waste. The experimental approach was to saturate each phase by adding more than the solid solubility limit of the given cation, using a nominated substitution scheme, and then analyzing the candidate phase that formed to evaluate the solid solubility limit under firing conditions. Confirmation that the solid solution limit had been reached insofar as other phases rich in the cation of interest was also required. The candidate phases were monazite, titanite, zirconolite, perovskite, apatite, pyrochlore, and brannerite. The valences of Pu and U were typically deduced from the firing atmosphere, and charge balancing in the candidate phase composition as evaluated from electron microscopy, although in some cases it was measured directly by x-ray absorption and diffuse reflectance spectroscopies (for U). Tetravalent Pu and U have restricted (< 0.1 formula units) solid solubility in apatite, titanite, and perovskite. Trivalent Pu has a larger solubility in apatite and perovskite than Pu4+. U3+ appears to be a credible species in reduced perovskite with a solubility of {approximately} 0.25 f.u. as opposed to {approximately} 0.05 f.u. for U4+. Pu4+ is a viable species in monazite and is promoted at lower firing temperatures ({approximately} 800 C) in an air atmosphere. Hf solubility is restricted in apatite, monazite (< 0.1 f.u.), but is {approximately} 0.2 and 0.5 f.u. in brannerite and titanite, respectively. Gd solubility is extended in all phases except for titanite ({approximately} 0.3 f.u.). U5+ was identified by DRS observations of absorption bands in the visible/near infrared photon energy ranges in brannerite and zirconolite, and U4+ in zirconolite was similarly identified.

  5. Solid Solubilities of Pu, U, Gd and Hf in Candidate Ceramic Nuclear Wasteforms

    Energy Technology Data Exchange (ETDEWEB)

    Vance, Eric R.; Carter, M. L.; Lumpkin, G. R.; Day, R. A.; Begg, B. D.

    2001-04-02

    This goal of this research project was to determine the solid solubility of Pu, U, Gd, and Hf in candidate ceramics for immobilization of high-level nuclear waste. The experimental approach was to saturate each phase by adding more than the solid solubility limit of the given cation, using a nominated substitution scheme, and then analyzing the candidate phase that formed to evaluate the solid solubility limit under firing conditions. Confirmation that the solid solution limit had been reached insofar as other phases rich in the cation of interest was also required. The candidate phases were monazite, titanite, zirconolite, perovskite, apatite, pyrochlore, and brannerite. The valences of Pu and U were typically deduced from the firing atmosphere, and charge balancing in the candidate phase composition as evaluated from electron microscopy, although in some cases it was measured directly by x-ray absorption and diffuse reflectance spectroscopies (for U). Tetravalent Pu and U have restricted (< 0.1 formula units) solid solubility in apatite, titanite, and perovskite. Trivalent Pu has a larger solubility in apatite and perovskite than Pu4+. U3+ appears to be a credible species in reduced perovskite with a solubility of {approximately} 0.25 f.u. as opposed to {approximately} 0.05 f.u. for U4+. Pu4+ is a viable species in monazite and is promoted at lower firing temperatures ({approximately} 800 C) in an air atmosphere. Hf solubility is restricted in apatite, monazite (< 0.1 f.u.), but is {approximately} 0.2 and 0.5 f.u. in brannerite and titanite, respectively. Gd solubility is extended in all phases except for titanite ({approximately} 0.3 f.u.). U5+ was identified by DRS observations of absorption bands in the visible/near infrared photon energy ranges in brannerite and zirconolite, and U4+ in zirconolite was similarly identified.

  6. HF omnidirectional spectral CW auroral radar (HF-OSCAR) at very high latitude. Part 1: Technique

    Science.gov (United States)

    Olesen, J. K.; Jacobsen, K. E.; Stauning, P.; Henriksen, S.

    1983-12-01

    An HF system for studies of very high latitude ionospheric irregularities was described. Radio aurora from field-aligned E-region irregularities of the Slant E Condition type were discussed. The complete system combines an ionosonde, a 12 MHz pulse radar and a 12 MHz bistatic CW Doppler-range set-up. The two latter units use alternately a 360 deg rotating Yagi antenna. High precision oscillators secure the frequency stability of the Doppler system in which the received signal is mixed down to a center frequency of 500 Hz. The Doppler shift range is max + or - 500 Hz. The received signal is recorded in analog form on magnetic tape and may be monitored visually and audibly. Echo range of the CW Doppler signal is obtained by a 150 Hz amplitude modulation of the transmitted signal and phase comparison with the backscattered signal.

  7. The CaO-TiO{sub 2}-ZrO{sub 2} system at 1,200{degree}C and the solubilities of Hf and Gd in zirconolite

    Energy Technology Data Exchange (ETDEWEB)

    Swenson, D.; Nieh, T.G. [Lawrence Livermore National Lab., CA (United States); Fournelle, J.H. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Geology and Geophysics

    1995-12-01

    In recent years, significant technological advancements have been made in the Synroc scheme for the immobilization high-level nuclear waste. However, many basic scientific issues related to Synroc fabrication have yet to be addressed. The CaO-TiO{sub 2}-ZrO{sub 2} system is an integral part of the Synroc formulation. Phase equilibria are established in the CaO-TiO{sub 2}-ZrO{sub 2} system at 1,200 C, using X-ray diffraction and electron probe microanalysis. The existence of two previously reported ternary phases, zirconolite (CaZrTi{sub 2}O{sub 7}) and calzirtite (Ca{sub 2}Zr{sub 5}Ti{sub 2}O{sub 16}), is confirmed. Each of these phases exhibits a significant range of homogeneity between TiO{sub 2} and ZrO{sub 2} while maintaining a nearly constant concentration of CaO. The ternary solubilities of the constituent binary phases are found to be negligible, with the exceptions of the perovskites, which display mutual solubility of at least 22 mol.% and may in fact form a series of continuous solid solutions. The solubilities of Hf and Gd in zirconolite are also investigated. While Hf-bearing samples did not reach thermodynamic equilibrium under the experimental conditions employed, the existence of a Hf analog to zirconolite, CaHfTi{sub 2}O{sub 7}, is conclusively demonstrated. The phase is stable at the stoichiometric composition, and its lattice parameters are very close to those reported in the literature for stoichiometric zirconolite. A Gd-bearing sample of the composition Ca{sub 0.88}Zr{sub 0.88}Gd{sub 9.24}Ti{sub 2}O{sub 7} is found to be essentially single phase zirconolite, in agreement with previous investigations at higher temperatures.

  8. Mid-Latitude Mobile Wideband HF- NVIS Channel Analysis: Part 1

    Science.gov (United States)

    2017-09-14

    communications (SATCOM) for beyond line-of- sight (LOS) links. However, standard HF systems operating over a 3-kHz bandwidth do not provide sufficient...wideband mid-latitude HF channel soundings and three-dimensional (3-D) ray-tracing simulations to develop a statistical model of a particular nearly...46 5 THE HF-NVIS CHANNEL SOUNDING SYSTEM ...................................................................... 47 5.1 TRANSMIT AND RECEIVE HF

  9. The CaO-TiO{sub 2}-ZrO{sub 2} system at 1200 C and the solubilities of Hf and Gd in zirconolite

    Energy Technology Data Exchange (ETDEWEB)

    Swenson, D.; Nieh, T.G. [Lawrence Livermore National Lab., CA (United States). Chemistry and Materials Science; Fournelle, J.H. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Geology and Geophysics

    1996-08-01

    Phase equilibria are established in the CaO-TiO{sub 2}-ZrO{sub 2} system at 1,200 C, using X-ray diffraction and electron probe microanalysis. The existence of two previously reported ternary phases, zirconolite (CaZrTi{sub 2}O{sub 7}) and calzirtite (Ca{sub 2}Zr{sub 5}Ti{sub 2}O{sub 16}), is confirmed. Each of these phases exhibits a significant range of homogeneity between TiO{sub 2} and ZrO{sub 2} while maintaining a nearly constant concentration of CaO. The ternary solubilities of the constituent binary phases are found to be negligible, with the exceptions of the perovskites, which display mutual solubility of at least 22 mol.% and may in fact form a series of continuous solid solutions. The solubilities of Hf and Gd in zirconolite are also investigated. While Hf-bearing samples did not reach thermodynamic equilibrium under the experimental conditions employed, the existence of a Hf analog to zirconolite, CaHfTi{sub 2}O{sub 7}, is conclusively demonstrated. The phase is stable at the stoichiometric composition, and its lattice parameters are very close to those reported in the literature for stoichiometric zirconolite. A Gd-bearing sample of the composition Ca{sub 0.88}Zr{sub 0.88}Gd{sub 0.24}Ti{sub 2}O{sub 7} is found to be essentially single phase zirconolite, in agreement with previous investigations at higher temperatures.

  10. The Hildebrand Solubility Parameters of Ionic Liquids—Part 2

    Directory of Open Access Journals (Sweden)

    Andrzej Marciniak

    2011-06-01

    Full Text Available The Hildebrand solubility parameters have been calculated for eight ionic liquids. Retention data from the inverse gas chromatography measurements of the activity coefficients at infinite dilution were used for the calculation. From the solubility parameters, the enthalpies of vaporization of ionic liquids were estimated. Results are compared with solubility parameters estimated by different methods.

  11. A thermodynamic model for the solubility of HfO2(am) in the aqueous K +– HCO3-– CO32-–O-–H2O system

    Energy Technology Data Exchange (ETDEWEB)

    Rai, Dhanpat; Kitamura, Akira; Rosso, Kevin M.

    2017-01-01

    Solubility of HfO2(am) was determined as a function of KHCO3 concentrations ranging from 0.001 mol·kg-1 to 0.1 mol·kg-1. The solubility of HfO2(am) increased dramatically with the increase in KHCO3 concentrations, indicating that Hf(IV) makes strong complexes with carbonate. Thermodynamic equilibrium constants for the formation of Hf-carbonate complexes were determined using both the Pitzer and SIT models. The dramatic increase in Hf concentrations with the increase in KHCO3 concentrations can best be described by the formation of Hf(OH-)2(CO3)22- and Hf(CO3)56-. The log10 K0 values for the reactions [Hf4++2CO32-+2OH-⇌Hf(OH)2(CO3)22-] and [Hf4++5CO32-⇌Hf(CO3)56-], based on the SIT model, were determined to be 44.53±0.46 and 41.53±0.46, respectively, and based on the Pitzer model they were 44.56±0.48 and 40.20±0.48, respectively.

  12. Zr, Hf, U, Th and REE-Fertile Lower Proterozoic Potassic Granite from Parts of Andhra Pradesh, South India

    Institute of Scientific and Technical Information of China (English)

    Yamuna SINGH

    2004-01-01

    The medium- to coarse-grained and porphyritic granitoid of Dharmawaram, Karimnagar district, Andhra Pradesh, south India is a biotite-hornblende granite with notable contents of rare metal (Zr, Hf, Th) and rare earth (including Y) minerals like zircon, thorite, allanite, monazite and xenotime. Chemically, it is metaluminous (average A/C+N+K = 0.95)-type, potassic (ay. 5% K2O) granite, with dominantly sub-alkaline characters. It shows up to 8 times enrichment of rare metals (Zr, Hf, U, Th) and rare earths (including Y, Sc), with reference to their abundances in normal unevolved granite, and hence, fertile for some of these elements. Field, petrological, geochemical and isotopic data of potassic granite (PG) indicate involvement of silica-rich metasedimentary-basic crustal rocks (amphibole-quartzite,amphibolite, hornblende-biotite gneiss, etc.) in its genesis, at a depth range of 30 km. Further, chondrite-normalized REE patterns demonstrate that low-degree partial melting of source rocks is the major controlling factor in the genesis of PG.Mild negative Eu-anomaiy (av. Eu/Eu* = 0.48), plots of Ba-Rb-Sr in the field of anomalous granite and K/Rb ratios (av.239) in the range that is shown by normal unevolved granite together indicate less fractionated nature of the PG. Limited fractionation of metalumination-type, involving hornblende, led to occasional weak alumina saturation. Interestingly,geochemical and petrogenetic features of the studied PG broadly match with those potassic granites which are already known to host anomalously high enrichment of rare metals and rare earths in other parts of Andhra Pradesh and adjoining Kamataka.

  13. Catalytic para-xylene maximization. Part X: Toluene disproportionation on HF promoted H-ZSM-5 catalysts

    Directory of Open Access Journals (Sweden)

    Ahmed K. Aboul-Gheit

    2012-12-01

    Full Text Available H-ZSM-5 zeolite catalysts were doped with 2%, 3% and 4%HF to be used for investigating their activities and selectivities for xylenes production and for para-xylene maximization at temperatures of 300–500 °C via toluene disproportionation. This doping caused pore size modification of the H-ZSM-5 catalyst. The reaction was carried out in a fixed bed flow type reactor. The ratio of produced para-xylene relative to its thermodynamic composition reached as high as 3.29 at 300 °C on the 4%HF doped H-ZSM-5 catalyst although this catalyst possessed the lowest amount of the largest pores (3.0–5.7 nm and the smallest pores (0.4–1.7 nm. The overall activities of the catalysts were decreased with an increase in HF doping because of diffusion restriction. The kinetics of the reaction were simply treated and found to give Ea and ΔS∗ values compatible with the characterization data of the catalysts.

  14. Sumoylation influences DNA break repair partly by increasing the solubility of a conserved end resection protein.

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    Prabha Sarangi

    2015-01-01

    Full Text Available Protein modifications regulate both DNA repair levels and pathway choice. How each modification achieves regulatory effects and how different modifications collaborate with each other are important questions to be answered. Here, we show that sumoylation regulates double-strand break repair partly by modifying the end resection factor Sae2. This modification is conserved from yeast to humans, and is induced by DNA damage. We mapped the sumoylation site of Sae2 to a single lysine in its self-association domain. Abolishing Sae2 sumoylation by mutating this lysine to arginine impaired Sae2 function in the processing and repair of multiple types of DNA breaks. We found that Sae2 sumoylation occurs independently of its phosphorylation, and the two modifications act in synergy to increase soluble forms of Sae2. We also provide evidence that sumoylation of the Sae2-binding nuclease, the Mre11-Rad50-Xrs2 complex, further increases end resection. These findings reveal a novel role for sumoylation in DNA repair by regulating the solubility of an end resection factor. They also show that collaboration between different modifications and among multiple substrates leads to a stronger biological effect.

  15. Sumoylation Influences DNA Break Repair Partly by Increasing the Solubility of a Conserved End Resection Protein

    Science.gov (United States)

    Sarangi, Prabha; Steinacher, Roland; Altmannova, Veronika; Fu, Qiong; Paull, Tanya T.; Krejci, Lumir; Whitby, Matthew C.; Zhao, Xiaolan

    2015-01-01

    Protein modifications regulate both DNA repair levels and pathway choice. How each modification achieves regulatory effects and how different modifications collaborate with each other are important questions to be answered. Here, we show that sumoylation regulates double-strand break repair partly by modifying the end resection factor Sae2. This modification is conserved from yeast to humans, and is induced by DNA damage. We mapped the sumoylation site of Sae2 to a single lysine in its self-association domain. Abolishing Sae2 sumoylation by mutating this lysine to arginine impaired Sae2 function in the processing and repair of multiple types of DNA breaks. We found that Sae2 sumoylation occurs independently of its phosphorylation, and the two modifications act in synergy to increase soluble forms of Sae2. We also provide evidence that sumoylation of the Sae2-binding nuclease, the Mre11-Rad50-Xrs2 complex, further increases end resection. These findings reveal a novel role for sumoylation in DNA repair by regulating the solubility of an end resection factor. They also show that collaboration between different modifications and among multiple substrates leads to a stronger biological effect. PMID:25569253

  16. Mapping ionospheric backscatter measured by the SuperDARN HF radars – Part 1: A new empirical virtual height model

    Directory of Open Access Journals (Sweden)

    T. K. Yeoman

    2008-05-01

    Full Text Available Accurately mapping the location of ionospheric backscatter targets (density irregularities identified by the Super Dual Auroral Radar Network (SuperDARN HF radars can be a major problem, particularly at far ranges for which the radio propagation paths are longer and more uncertain. Assessing and increasing the accuracy of the mapping of scattering locations is crucial for the measurement of two-dimensional velocity structures on the small and meso-scale, for which overlapping velocity measurements from two radars need to be combined, and for studies in which SuperDARN data are used in conjunction with measurements from other instruments. The co-ordinates of scattering locations are presently estimated using a combination of the measured range and a model virtual height, assuming a straight line virtual propagation path. By studying elevation angle of arrival information of backscatterred signals from 5 years of data (1997–2001 from the Saskatoon SuperDARN radar we have determined the actual distribution of the backscatter target locations in range-virtual height space. This has allowed the derivation of a new empirical virtual height model that allows for a more accurate mapping of the locations of backscatter targets.

  17. Studies in transition metal chemistry ; VI. Soluble Ziegler-type catalysts based on vanadium, part II

    NARCIS (Netherlands)

    Liefde Meijer, H.J. de; Hurk, J.W.G. van den; Kerk, G.J.M. van der

    1966-01-01

    Spectrophotometric measurements in the visible region on soluble catalyst systems prepared from (i) vanadium tetrachloride, aluminium bromide and tetraphenyltin and (ii) vanadium tetrachloride or vanadium oxytrichloride and ethylaluminium dihalides are reported. The formation of hydrocarbonsoluble i

  18. Discussion and improvement of the refined COSMO-SAC parameters for solubility predictions: part 2

    OpenAIRE

    Bouillot, Baptiste; Teychené, Sébastien; Biscans, Béatrice

    2013-01-01

    Solubility of drugs is a key piece of information for the pharmaceutical industry. Despite its importance, particularly at the beginning of a new drug process development, this thermodynamic property of the solid-liquid equilibria (SLE) can hardly be predicted for a given molecule in a given solvent. In our recent works, some thermodynamic models (UNIFAC and its modifications, COSMO-SAC and its refinements, NRTL-SAC) were investigated and compared for solubility prediction. The main drawbacks...

  19. Soluble Antioxidant Compounds Regenerate the Antioxidants Bound to Insoluble Parts of Foods

    NARCIS (Netherlands)

    Celik, E.E.; Gökmen, V.; Fogliano, V.

    2013-01-01

    This study aimed to investigate the regeneration potential of antioxidant capacity of an insoluble food matrix. Investigations were performed in vitro with several food matrices rich in dietary fiber (DF) and bound antioxidants. After removal of the soluble fraction, the antioxidant capacity (AC) of

  20. Soluble antioxidant compounds regenerate the antioxidants bound to insoluble parts of foods.

    Science.gov (United States)

    Çelik, Ecem Evrim; Gökmen, Vural; Fogliano, Vincenzo

    2013-10-30

    This study aimed to investigate the regeneration potential of antioxidant capacity of an insoluble food matrix. Investigations were performed in vitro with several food matrices rich in dietary fiber (DF) and bound antioxidants. After removal of the soluble fraction, the antioxidant capacity (AC) of the insoluble fraction was measured by the QUENCHER procedure using ABTS(•+) or DPPH(•) radicals. After measurement, the insoluble residue was washed out to remove the excess of radicals and treated with pure antioxidant solution or antioxidant-rich beverage to regenerate depleted antioxidants on the fiber. Results revealed that the antioxidant capacity of compounds chemically bound to the insoluble moiety could be reconstituted in the presence of other hydrogen-donating substances in the liquid phase. Regeneration efficiency was found to range between 21.5 and 154.3% depending on the type of insoluble food matrix and regeneration agent. Among the food matrices studied, cereal products were found to have slightly higher regeneration efficiency, whereas antioxidant-rich beverages were more effective than pure antioxidants as regeneration agents. Taking wheat bran as reference insoluble material, the regeneration abilities of beverages were in the following order: green tea > espresso coffee > black tea > instant coffee > orange juice > red wine. These results highlighted the possible physiological relevance of antioxidants bound to the insoluble food material in the gastrointestinal tract. During the digestion process they could react with the free radicals and at the same time they can be regenerated by other soluble antioxidant compounds present in the meal.

  1. Amino acids as co-amorphous stabilizers for poorly water-soluble drugs - Part 2

    DEFF Research Database (Denmark)

    Löbmann, K.; Laitinen, R.; Strachan, C.

    2013-01-01

    The formation of co-amorphous drug-drug mixtures has proved to be a powerful approach to stabilize the amorphous form and at the same time increase the dissolution of poorly water-soluble drugs. Molecular interactions in these co-amorphous formulations can play a crucial role in stabilization...... and dissolution enhancement. In this regard, Fourier-transform infrared spectroscopy (FTIR) is a valuable tool to analyze the molecular near range order of the compounds in the co-amorphous mixtures. In this study, several co-amorphous drugs - low molecular weight excipient blends - have been analyzed with FTIR...... spectroscopy. Molecular interactions of the drugs carbamazepine and indomethacin with the amino acids arginine, phenylalanine, and tryptophan were investigated. The amino acids were chosen from the biological target site of both drugs and prepared as co-amorphous formulations together with the drugs...

  2. Amino acids as co-amorphous stabilizers for poorly water soluble drugs--Part 1

    DEFF Research Database (Denmark)

    Löbmann, Korbinian; Grohganz, Holger; Laitinen, Riikka

    2013-01-01

    . However, this strategy only led to a small number of marketed products usually because of inadequate physical stability of the drug (crystallization). In this study, we investigated a fundamentally different approach to stabilize the amorphous form of drugs, namely the use of amino acids as small...... molecular weight excipients that form specific molecular interactions with the drug resulting in co-amorphous forms. The two poorly water soluble drugs carbamazepine and indomethacin were combined with amino acids from the binding sites of the biological receptors of these drugs. Mixtures of drug...... and the amino acids arginine, phenylalanine, tryptophan and tyrosine were prepared by vibrational ball milling. Solid-state characterization with X-ray powder diffraction (XRPD) and differential scanning calorimetry (DSC) revealed that the various blends could be prepared as homogeneous, single phase co...

  3. Estimating the physicochemical properties of polyhalogenated aromatic and aliphatic compounds using UPPER: part 2. Aqueous solubility, octanol solubility and octanol-water partition coefficient.

    Science.gov (United States)

    Admire, Brittany; Lian, Bo; Yalkowsky, Samuel H

    2015-01-01

    The UPPER (Unified Physicochemical Property Estimation Relationships) model uses additive and non-additive parameters to estimate 20 biologically relevant properties of organic compounds. The model has been validated by Lian and Yalkowsky (2014) on a data set of 700 hydrocarbons. Recently, Admire et al. (2014) expanded the model to predict the boiling and melting points of 1288 polyhalogenated benzenes, biphenyls, dibenzo-p-dioxins, diphenyl ethers, anisoles and alkanes. In this work, 19 new group descriptors are determined and used to predict the aqueous solubilities, octanol solubilities and the octanol-water coefficients.

  4. Para-Xylene Maximization Part VIII: Promotion of H-ZSM-5 Zeolite by Pt and HF Doping for Use as Catalysts in Toluene Alkylation with Methanol

    Institute of Scientific and Technical Information of China (English)

    Ahmed K.ABOUL-GHEIT; Ateyya A.ABOUL-ENEIN; Ahmed E.AWADALLAH; Salwa A.GHONEIM; Eman A.EMAM

    2010-01-01

    Toluene was alkylated with methanol in a flow type reactor at temperatures between 300 and 500℃ using H-ZSM-5 zeolite, 0.2%Pt/H-ZSM-5 and hydrofluorinated 0.2%Pt/H-ZSM-5 with HF concentrations of 1.0%, 2.0%, 3.0%, or 4.0%. Pt primarily enhances toluene conversion, total xylenes production, and p-xylene relative to its thermodynamic equilibrium. As the concentration of HF increases from 1.0% to 3.0%, the catalyst activity increases because of the increase in the number of acid sites and their strength. Additionally, the surface area and Pt dispersion also increases. An advantage of increased HF doping is that the formation of voluminous trimethylbenzene (TMB) byproducts is inhibited. However, at a HF concentration of 4.0%, AI and Si are partially leached and then deposited mostly in the wider catalytic pores. This was determined by evaluating the pore volume distribution and we determined that reactivity inhibition was ob-viously present and was due to diffusion restriction.

  5. Subduction Controls of Hf and Nd Isotopes in Lavas of the Aleutian Island Arc

    Energy Technology Data Exchange (ETDEWEB)

    Yogodzinski, Gene; Vervoort, Jeffery; Brown, Shaun Tyler; Gerseny, Megan

    2010-08-29

    The Hf and Nd isotopic compositions of 71 Quaternary lavas collected from locations along the full length of the Aleutian island arc are used to constrain the sources of Aleutian magmas and to provide insight into the geochemical behavior of Nd and Hf and related elements in the Aleutian subduction-magmatic system. Isotopic compositions of Aleutian lavas fall approximately at the center of, and form a trend parallel to, the terrestrial Hf-Nd isotopic array with {var_epsilon}{sub Hf} of +12.0 to +15.5 and {var_epsilon}{sub Nd} of +6.5 to +10.5. Basalts, andesites, and dacites within volcanic centers or in nearby volcanoes generally all have similar isotopic compositions, indicating that there is little measurable effect of crustal or other lithospheric assimilation within the volcanic plumbing systems of Aleutian volcanoes. Hafnium isotopic compositions have a clear pattern of along-arc increase that is continuous from the eastern-most locations near Cold Bay to Piip Seamount in the western-most part of the arc. This pattern is interpreted to reflect a westward decrease in the subducted sediment component present in Aleutian lavas, reflecting progressively lower rates of subduction westward as well as decreasing availability of trench sediment. Binary bulk mixing models (sediment + peridotite) demonstrate that 1-2% of the Hf in Aleutian lavas is derived from subducted sediment, indicating that Hf is mobilized out of the subducted sediment with an efficiency that is similar to that of Sr, Pb and Nd. Low published solubility for Hf and Nd in aqueous subduction fluids lead us to conclude that these elements are mobilized out of the subducted component and transferred to the mantle wedge as bulk sediment or as a silicate melt. Neodymium isotopes also generally increase from east to west, but the pattern is absent in the eastern third of the arc, where the sediment flux is high and increases from east to west, due to the presence of abundant terrigenous sediment in the

  6. Defensive strategies in Geranium sylvaticum, Part 2: Roles of water-soluble tannins, flavonoids and phenolic acids against natural enemies.

    Science.gov (United States)

    Tuominen, Anu

    2013-11-01

    Geranium sylvaticum is a common herbaceous plant in Fennoscandia, which has a unique phenolic composition. Ellagitannins, proanthocyanidins, galloylglucoses, gallotannins, galloyl quinic acids and flavonoids possess variable distribution in its different organs. These phenolic compounds are thought to have an important role in plant-herbivore interactions. The aim of this study was to quantify these different water-soluble phenolic compounds and measure the biological activity of the eight organs of G. sylvaticum. Compounds were characterized and quantified using HPLC-DAD/MS, in addition, total proanthocyanidins were determined by BuOH-HCl assay and total phenolics by the Folin-Ciocalteau method. Two in vitro biological activity measurements were used: the prooxidant activity was measured by the browning assay and antioxidant activity by the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay. Organ extracts were fractionated using column chromatography on Sephadex LH-20 and the activities of fractions was similarly measured to evaluate which polyphenol groups contributed the most to the biological activity of each organ. The data on the activity of fractions were examined by multivariate data analysis. The water-soluble extracts of leaves and pistils, which contained over 30% of the dry weight as ellagitannins, showed the highest pro-oxidant activity among the organ extracts. Fraction analysis revealed that flavonoids and galloyl quinic acids also exhibited high pro-oxidant activity. In contrast, the most antioxidant active organ extracts were those of the main roots and hairy roots that contained high amounts of proanthocyanidins in addition to ellagitannins. Analysis of the fractions showed that especially ellagitannins and galloyl quinic acids have high antioxidant activity. We conclude that G. sylvaticum allocates a significant amount of tannins in those plant parts that are important to the fitness of the plant and susceptible to natural enemies, i

  7. A single parameter representation of hygroscopic growth and cloud condensation nucleus activity – Part 2: Including solubility

    Directory of Open Access Journals (Sweden)

    M. D. Petters

    2008-10-01

    Full Text Available The ability of a particle to serve as a cloud condensation nucleus in the atmosphere is determined by its size, hygroscopicity and its solubility in water. Usually size and hygroscopicity alone are sufficient to predict CCN activity. Single parameter representations for hygroscopicity have been shown to successfully model complex, multicomponent particles types. Under the assumption of either complete solubility, or complete insolubility of a component, it is not necessary to explicitly include that component's solubility into the single parameter framework. This is not the case if sparingly soluble materials are present. In this work we explicitly account for solubility by modifying the single parameter equations. We demonstrate that sensitivity to the actual value of solubility emerges only in the regime of 2×10−1–5×10−4, where the solubility values are expressed as volume of solute per unit volume of water present in a saturated solution. Compounds that do not fall inside this sparingly soluble envelope can be adequately modeled assuming they are either infinitely soluble in water or completely insoluble.

  8. ExtraHF survey

    DEFF Research Database (Denmark)

    Piepoli, Massimo F; Binno, Simone; Corrà, Ugo

    2015-01-01

    AIMS: In heart failure (HF), exercise training programmes (ETPs) are a well-recognized intervention to improve symptoms, but are still poorly implemented. The Heart Failure Association promoted a survey to investigate whether and how cardiac centres in Europe are using ETPs in their HF patients...... of evidence on safety or benefit was cited. When implemented, an ETP was proposed to all HF patients in only 55% of the centres, with restriction according to severity or aetiology. CONCLUSIONS: With respect to previous surveys, there is evidence of increased availability of ETPs in HF in Europe, although too...

  9. IUPAC-NIST Solubility Data Series. 101. Alcohols + Hydrocarbons + Water Part 3. C1-C3 Alcohols + Aromatic Hydrocarbons

    Science.gov (United States)

    Oracz, Paweł; Góral, Marian; Wiśniewska-Gocłowska, Barbara; Shaw, David G.; Mączyński, Andrzej

    2016-09-01

    The mutual solubilities and related liquid-liquid equilibria for 11 ternary systems of C1-C3 alcohols with aromatic hydrocarbons and water are exhaustively and critically reviewed. Reports of experimental determination of solubility that appeared in the primary literature prior to the end of 2012 are compiled. For nine systems, sufficient data are available (two or more independent determinations) to allow critical evaluation. All new data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, an additional criterion was used for each of the evaluated systems. These systems include one binary miscibility gap in the hydrocarbon + water subsystem. The binary tie lines were compared with the recommended values published previously.

  10. Cell wall polysaccharides of Chinese Wolfberry (Lycium barbarum) : Part 1. Characterisation of soluble and insoluble polymer fractions

    NARCIS (Netherlands)

    Redgwell, Robert J.; Curti, Delphine; Wang, Juankuan; Dobruchowska, Justyna M.; Gerwig, Gerrit J.; Kamerling, Johannis P.; Bucheli, Peter

    2011-01-01

    Water-soluble polysaccharides (WSP) and insoluble cell wall material (CWM) were isolated from Wolfberry fruit (Lycium barbarum). WSP were fractionated by treatment with a quaternary ammonium salt and anion-exchange chromatography. Pectic polysaccharides were major components but a glucan, xylan and

  11. Cell wall polysaccharides of Chinese Wolfberry (Lycium barbarum) : Part 1. Characterisation of soluble and insoluble polymer fractions

    NARCIS (Netherlands)

    Redgwell, Robert J.; Curti, Delphine; Wang, Juankuan; Dobruchowska, Justyna M.; Gerwig, Gerrit J.; Kamerling, Johannis P.; Bucheli, Peter

    2011-01-01

    Water-soluble polysaccharides (WSP) and insoluble cell wall material (CWM) were isolated from Wolfberry fruit (Lycium barbarum). WSP were fractionated by treatment with a quaternary ammonium salt and anion-exchange chromatography. Pectic polysaccharides were major components but a glucan, xylan and

  12. Consideration on thermodynamic data for predicting solubility and chemical species of elements in groundwater. Part 1: Tc, U, Am

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, Tetsuji; Takeda, Seiji [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1999-01-01

    The solubility determines the release of radionuclides from waste form and is used as a source term in radionuclide migration analysis in performance assessment of radioactive waste repository. Complexations of radionuclides by ligands in groundwater affect the interaction between radionuclides and geologic media, thus affect their migration behavior. Thermodynamic data for Tc, Am and U were reviewed and compiled to be used for predicting the solubility and chemical species in groundwater. Thermodynamic data were reviewed with emphasis on the hydrolysis and carbonate complexation that can dominate the speciation in typical groundwater. Thermodynamic data for other species were selected based on existing database. Thermodynamic data for other important elements are under investigation, thus shown in an appendix for temporary use. (author)

  13. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 1 – Aluminum

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Kerry J., E-mail: howe@unm.edu [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Mitchell, Lana, E-mail: lmitchell@alionscience.com [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Kim, Seung-Jun, E-mail: skim@lanl.gov [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Blandford, Edward D., E-mail: edb@unm.edu [University of New Mexico, 210 University Blvd., Albuquerque, NM 87131 (United States); Kee, Ernest J., E-mail: erniekee@gmail.com [South Texas Project Nuclear Operating Company, P.O. Box 270, Wadsworth, TX 77483 (United States)

    2015-10-15

    Highlights: • Trisodium phosphate (TSP) causes aluminum corrosion to cease after 24 h of exposure. • Chloride, iron, and copper have a minimal effect on the rate of aluminum corrosion when TSP is present. • Zinc can reduce the rate of aluminum corrosion when TSP is present. • Aluminum occasionally precipitates at concentrations lower than the calculated solubility for Al(OH){sub 3}. • Corrosion and solubility equations can be used to calculate the solids generated during a LOCA. - Abstract: Bench experiments were conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of aluminum from metallic aluminum surfaces under conditions representative of the containment pool following a postulated loss of coolant accident at a nuclear power generating facility. The experiments showed that TSP is capable of passivating the aluminum surface and preventing continued corrosion after about 24 h at the conditions tested. A correlation that describes the rate of corrosion including the passivation effect was developed from the bench experiments and validated with a separate set of experiments from a different test system. The saturation concentration of aluminum was shown to be well described by the solubility of amorphous aluminum hydroxide for the majority of cases, but instances have been observed when aluminum precipitates at concentrations lower than the calculated aluminum hydroxide solubility. Based on the experimental data and previous literature, an equation was developed to calculate the saturation concentration of aluminum as a function of pH and temperature under conditions representative of a loss of coolant accident (LOCA) in a TSP-buffered pressurized water reactor (PWR) containment. The corrosion equation and precipitation equation can be used in concert with each other to calculate the quantity of solids that would form as a function of time during a LOCA if the temperature and pH profiles were known.

  14. Corrosion and solubility in a TSP-buffered chemical environment following a loss of coolant accident: Part 2 – Zinc

    Energy Technology Data Exchange (ETDEWEB)

    Pease, David; LaBrier, Daniel; Ali, Amir [Department of Nuclear Engineering, University of New Mexico (United States); Blandford, Edward D., E-mail: edb@unm.edu [Department of Nuclear Engineering, University of New Mexico (United States); Howe, Kerry J. [Department of Civil Engineering, University of New Mexico (United States)

    2016-04-15

    Highlights: • Zinc release is limited to less than 1 mg/L in TSP-buffered solution under a variety of conditions (pH, temperature, zinc source). • Zinc release in high-temperature non-TSP-buffered environment is approximately 25 mg/L. • Long-term zinc release is controlled by passivation (without TSP) and zinc solubility (with TSP). • Precipitation and solubility of zinc phosphate limit the release of zinc. - Abstract: Bench experiments were conducted to investigate the effect of the presence of trisodium phosphate (TSP) on the corrosion and release of zinc from metallic zinc-bearing surfaces under conditions representative of the containment pool following a postulated loss of coolant accident (LOCA) at a nuclear power generating facility. The experiments showed that in non-buffered (acidic) environments, measurable quantities of zinc are released from zinc-bearing surfaces. Precipitation and solubility of phosphate-based corrosion products, such as zinc phosphate, limit the release of zinc from zinc-bearing surfaces. These experiments have found that under a variety of conditions, including variations of temperature, pH, and across different zinc-bearing surfaces, the release of zinc into solution is limited to <1 mg/L when phosphate is present. When phosphate is not present, zinc release is instead bounded by a markedly higher saturation limit which is a strong function of the solution temperature.

  15. Amino acids as co-amorphous stabilizers for poorly water soluble drugs--Part 1: preparation, stability and dissolution enhancement.

    Science.gov (United States)

    Löbmann, Korbinian; Grohganz, Holger; Laitinen, Riikka; Strachan, Clare; Rades, Thomas

    2013-11-01

    Poor aqueous solubility of an active pharmaceutical ingredient (API) is one of the most pressing problems in pharmaceutical research and development because up to 90% of new API candidates under development are poorly water soluble. These drugs usually have a low and variable oral bioavailability, and therefore an unsatisfactory therapeutic effect. One of the most promising approaches to increase dissolution rate and solubility of these drugs is the conversion of a crystalline form of the drug into its respective amorphous form, usually by incorporation into hydrophilic polymers, forming glass solutions. However, this strategy only led to a small number of marketed products usually because of inadequate physical stability of the drug (crystallization). In this study, we investigated a fundamentally different approach to stabilize the amorphous form of drugs, namely the use of amino acids as small molecular weight excipients that form specific molecular interactions with the drug resulting in co-amorphous forms. The two poorly water soluble drugs carbamazepine and indomethacin were combined with amino acids from the binding sites of the biological receptors of these drugs. Mixtures of drug and the amino acids arginine, phenylalanine, tryptophan and tyrosine were prepared by vibrational ball milling. Solid-state characterization with X-ray powder diffraction (XRPD) and differential scanning calorimetry (DSC) revealed that the various blends could be prepared as homogeneous, single phase co-amorphous formulations indicated by the appearance of an amorphous halo in the XRPD diffractograms and a single glass transition temperature (Tg) in the DSC measurements. In addition, the Tgs of the co-amorphous mixtures were significantly increased over those of the individual drugs. The drugs remained chemically stable during the milling process and the co-amorphous formulations were generally physically stable over at least 6 months at 40 °C under dry conditions. The

  16. Frederiksberg HF kursus

    DEFF Research Database (Denmark)

    Lindstrøm, Maria Duclos

    2008-01-01

    Notatet bygger på et interviewmateriale med dimitterede HF-kursister 3 måneder efter endt eksamen. Notatet undersøger dels, hvad der har hjulpet til at gennemføre, dels hvad der har været negativt og vanskeligt ved uddannelsen. Endvidere belyser notatet hvad kursisterne oplever at tage med fra de...

  17. HfO2 Gate Dielectrics for Future Generation of CMOS Device Application

    Institute of Scientific and Technical Information of China (English)

    H.Y.Yu; J.F.Kang; Ren Chi; M.F.Li; D.L.Kwong

    2004-01-01

    The material and electrical properties of HfO2 high-k gate dielectric are reported.In the first part,the band alignment of HfO2 and (HfO2)x(Al2O3)1-x to (100)Si substrate and their thermal stability are studied by X-ray photoelectron spectroscopy and TEM.The energy gap of (HfO2)x(Al2O3)1-x,the valence band offset,and the conduction band offset between (HfO2)x(Al2O3)1-x and the Si substrate as functions of x are obtained based on the XPS results.Our XPS results also demonstrate that both the thermal stability and the resistance to oxygen diffusion of HfO2 are improved by adding Al to form Hf aluminates.In the second part,a thermally stable and high quality HfN/HfO2 gate stack is reported.Negligible changes in equivalent oxide thickness (EOT),gate leakage,and work function (close to Si mid-gap) of HfN/HfO2 gate stack are demonstrated even after 1000℃ post-metal annealing(PMA),which is attributed to the superior oxygen diffusion barrier of HfN as well as the thermal stability of the HfN/HfO2 interface.Therefore,even without surface nitridation prior to HfO2 deposition,the EOT of HfN/HfO2 gate stack has been successfully scaled down to less than 1nm after 1000℃ PMA with excellent leakage and long-term reliability.The last part demonstrates a novel replacement gate process employing a HfN dummy gate and sub-1nm EOT HfO2 gate dielectric.The excellent thermal stability of the HfN/HfO2 gate stack enables its use in high temperature CMOS processes.The replacement of HfN with other metal gate materials with work functions adequate for n- and p-MOS is facilitated by a high etch selectivity of HfN with respect to HfO2,without any degradation to the EOT,gate leakage,or TDDB characteristics of HfO2.

  18. Defensive strategies in Geranium sylvaticum. Part 1: organ-specific distribution of water-soluble tannins, flavonoids and phenolic acids.

    Science.gov (United States)

    Tuominen, Anu; Toivonen, Eija; Mutikainen, Pia; Salminen, Juha-Pekka

    2013-11-01

    A combination of high-resolution mass spectrometry and modern HPLC column technology, assisted by diode array detection, was used for accurate characterization of water-soluble polyphenolic compounds in the pistils, stamens, petals, sepals, stems, leaves, roots and seeds of Geranium sylvaticum. The organs contained a large variety of polyphenols, five types of tannins (ellagitannins, proanthocyanidins, gallotannins, galloyl glucoses and galloyl quinic acids) as well as flavonoids and simple phenolic acids. In all, 59 compounds were identified. Geraniin and other ellagitannins dominated in all the green photosynthetic organs. The other organs seem to produce distinctive polyphenol groups: pistils accumulated gallotannins; petals acetylglucose derivatives of galloylglucoses; stamens kaempferol glycosides, and seeds and roots accumulated proanthocyanidins. The intra-plant distribution of the different polyphenol groups may reflect the different functions and importance of various types of tannins as the defensive chemicals against herbivory.

  19. Amino acids as co-amorphous stabilizers for poorly water-soluble drugs--Part 2: molecular interactions.

    Science.gov (United States)

    Löbmann, Korbinian; Laitinen, Riikka; Strachan, Clare; Rades, Thomas; Grohganz, Holger

    2013-11-01

    The formation of co-amorphous drug-drug mixtures has proved to be a powerful approach to stabilize the amorphous form and at the same time increase the dissolution of poorly water-soluble drugs. Molecular interactions in these co-amorphous formulations can play a crucial role in stabilization and dissolution enhancement. In this regard, Fourier-transform infrared spectroscopy (FTIR) is a valuable tool to analyze the molecular near range order of the compounds in the co-amorphous mixtures. In this study, several co-amorphous drugs--low molecular weight excipient blends--have been analyzed with FTIR spectroscopy. Molecular interactions of the drugs carbamazepine and indomethacin with the amino acids arginine, phenylalanine, and tryptophan were investigated. The amino acids were chosen from the biological target site of both drugs and prepared as co-amorphous formulations together with the drugs by vibrational ball milling. A detailed analysis of the FTIR spectra of these formulations revealed specific peak shifts in the vibrational modes of functional groups of drug and amino acid, as long as one amino acid from the biological target site was present in the blends. These peak shifts indicate that the drugs formed specific molecular interactions (hydrogen bonding and π-π interactions) with the amino acids. In the drug-amino acid mixtures that contained amino acids which were not present at the biological target site, no such interactions were identified. This study shows the potential of amino acids as small molecular weight excipients in co-amorphous formulations to stabilize the amorphous form of a poorly water-soluble drug through strong and specific molecular interactions with the drug.

  20. Soluble and insoluble fiber (image)

    Science.gov (United States)

    Dietary fiber is the part of food that is not affected by the digestive process in the body. ... of the stool. There are two types of dietary fiber, soluble and insoluble. Soluble fiber retains water and ...

  1. Soluble guanylate cyclase : a potential therapeutic target for heart failure

    NARCIS (Netherlands)

    Gheorghiade, Mihai; Marti, Catherine N.; Sabbah, Hani N.; Roessig, Lothar; Greene, Stephen J.; Boehm, Michael; Burnett, John C.; Campia, Umberto; Cleland, John G. F.; Collins, Sean P.; Fonarow, Gregg C.; Levy, Phillip D.; Metra, Marco; Pitt, Bertram; Ponikowski, Piotr; Sato, Naoki; Voors, Adriaan A.; Stasch, Johannes-Peter; Butler, Javed

    2013-01-01

    The number of annual hospitalizations for heart failure (HF) and the mortality rates among patients hospitalized for HF remains unacceptably high. The search continues for safe and effective agents that improve outcomes when added to standard therapy. The nitric oxide (NO)-soluble guanylate cyclase

  2. Pulsed inductive HF laser

    Energy Technology Data Exchange (ETDEWEB)

    Razhev, A M; Kargapol' tsev, E S [Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk (Russian Federation); Churkin, D S; Demchuk, S V [Novosibirsk State University, Novosibirsk (Russian Federation)

    2016-03-31

    We report the results of experimentally investigated dependences of temporal, spectral and spatial characteristics of an inductive HF-laser generation on the pump conditions. Gas mixtures H{sub 2} – F{sub 2}(NF{sub 3} or SF6{sub 6}) and He(Ne) – H{sub 2} – F{sub 2}(NF{sub 3} or SF{sub 6}) were used as active media. The FWHM pulse duration reached 0.42 μs. This value corresponded to a pulsed power of 45 kW. For the first time, the emission spectrum of an inductive HF laser was investigated, which consisted of seven groups of bands with centres around the wavelengths of 2732, 2736, 2739, 2835, 2837, 2893 and 2913 nm. The cross section profile of the laser beam was a ring with a diameter of about 20 mm and width of about 5 mm. Parameters of laser operation in the repetitively pulsed regime were sufficiently stable. The amplitude instability of light pulses was no greater than 5% – 6%. (lasers)

  3. HF Interference, Procedures and Tools (Interferences HF, procedures et outils)

    Science.gov (United States)

    2007-06-01

    such sources. The existing HF background noise possibly may be increased via ground wave and/or sky wave propagation. Increase of the existing HF...télécommunications filaires à large bande. Les télécommunications via le réseau électrique courant, dites PowerLine Communications (PLT ou PLC) et diverses...cumulative de nombreuses sources de même type. Le bruit de fond HF existant risque d’être augmenté par propagation de l’onde terrestre et/ou aérienne

  4. The dynamics of acid-soluble phosphorus compounds in the course of winter and spring wheat germination under various thermic conditions. Part II. Labile phosphorus after hydrolysis of the acid-soluble fraction

    Directory of Open Access Journals (Sweden)

    A. Barbaro

    2015-06-01

    Full Text Available The changes in labile phosphorus compounds content during germination of wheat were investigated. These compounds were determined in acid-soluble germ extracts separated into fractions according to the solubility of their barium salts. Low germination temperature was found to raise the labile phosphorus content in the fraction of insoluble barium salts. If we assume that labile P of this fraction consisted mainly of adenosinedi- and triphosphates, it would seem that the rise, in the ATP and ADP level under the influence of low temperature may be essential for initiating flowering in winter varieties.

  5. EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3

    Energy Technology Data Exchange (ETDEWEB)

    Wolery, T.J.

    1992-09-14

    EQ3NR is an aqueous solution speciation-solubility modeling code. It is part of the EQ3/6 software package for geochemical modeling. It computes the thermodynamic state of an aqueous solution by determining the distribution of chemical species, including simple ions, ion pairs, and complexes, using standard state thermodynamic data and various equations which describe the thermodynamic activity coefficients of these species. The input to the code describes the aqueous solution in terms of analytical data, including total (analytical) concentrations of dissolved components and such other parameters as the pH, pHCl, Eh, pe, and oxygen fugacity. The input may also include a desired electrical balancing adjustment and various constraints which impose equilibrium with special pure minerals, solid solution end-member components (of specified mole fractions), and gases (of specified fugacities). The code evaluates the degree of disequilibrium in terms of the saturation index (SI = 1og Q/K) and the thermodynamic affinity (A = {minus}2.303 RT log Q/K) for various reactions, such as mineral dissolution or oxidation-reduction in the aqueous solution itself. Individual values of Eh, pe, oxygen fugacity, and Ah (redox affinity) are computed for aqueous redox couples. Equilibrium fugacities are computed for gas species. The code is highly flexible in dealing with various parameters as either model inputs or outputs. The user can specify modification or substitution of equilibrium constants at run time by using options on the input file.

  6. Marburg Hemorrhagic Fever (Marburg HF)

    Science.gov (United States)

    ... CDC Cancel Submit Search The CDC Marburg hemorrhagic fever (Marburg HF) Note: Javascript is disabled or is ... first recognized in 1967, when outbreaks of hemorrhagic fever occurred simultaneously in laboratories in Marburg and Frankfurt, ...

  7. Hf Transition Probabilities and Abundances

    CERN Document Server

    Lawler, J E; Labby, Z E; Sneden, C; Cowan, J J; Ivans, I I

    2006-01-01

    Radiative lifetimes from laser-induced fluorescence measurements, accurate to about +/- 5 percent, are reported for 41 odd-parity levels of Hf II. The lifetimes are combined with branching fractions measured using Fourier transform spectrometry to determine transition probabilities for 150 lines of Hf II. Approximately half of these new transition probabilities overlap with recent independent measurements using a similar approach. The two sets of measurements are found to be in good agreement for measurements in common. Our new laboratory data are applied to refine the hafnium photospheric solar abundance and to determine hafnium abundances in 10 metal-poor giant stars with enhanced r-process abundances. For the Sun we derive log epsilon (Hf) = 0.88 +/- 0.08 from four lines; the uncertainty is dominated by the weakness of the lines and their blending by other spectral features. Within the uncertainties of our analysis, the r-process-rich stars possess constant Hf/La and Hf/Eu abundance ratios, log epsilon (Hf...

  8. Soluble NCAM

    DEFF Research Database (Denmark)

    Secher, Thomas

    2008-01-01

    The neural cell adhesion molecule (NCAM) is a membrane-bound glycoprotein involved in homophilic interactions that facilitate cell-cell adhesion. In addition to a number of membrane-bound isoforms, NCAM also exists in several soluble isoforms that have been identified in cerebrospinal fluid, bloo...

  9. Seasonal variations in the chemical composition of particulate matter: a case study in the Po Valley. Part II: concentration and solubility of micro- and trace-elements.

    Science.gov (United States)

    Canepari, S; Astolfi, M L; Farao, C; Maretto, M; Frasca, D; Marcoccia, M; Perrino, C

    2014-03-01

    Size distribution (fine and coarse fraction) and solubility distribution (extracted and residual fraction) of 20 elements (As, Ba, Be, Cd, Co, Cu, Fe, Li, Mn, Pb, Ni, Rb, S, Sb, Se, Sn, Sr, Ti, Tl, V) in atmospheric particulate matter (PM) were determined during a 5-year field study carried out in the Po Valley (peri-urban area of Ferrara, in Northern Italy). By studying the contribution of the two size fractions and the two solubility fractions to the atmospheric concentration of each element, it was possible to obtain interesting information about the variability of PM sources, to assess the role played by atmospheric stability in determining pollution episodes, and to obtain an estimate of the bio-accessible fraction. Atmospheric stability is confirmed to be one of the main causes of atmospheric pollution in this area and is to be responsible for the pronounced winter increase in both PM and elemental concentration. Long-range transport of natural and polluted air masses caused temporary increases in PM and elemental concentration, while local industrial emission seemed to play a secondary role. Regulated elements were well below their concentration limit, but many toxic elements were in the form of fine particles and soluble chemical species, more accessible to the environment, and the human body.

  10. Soluble vs. insoluble fiber

    Science.gov (United States)

    Insoluble vs. soluble fiber; Fiber - soluble vs. insoluble ... There are 2 different types of fiber -- soluble and insoluble. Both are important for health, digestion, and preventing diseases. Soluble fiber attracts water and turns to gel during digestion. ...

  11. Environmentally friendly HF (DF) lasers

    Science.gov (United States)

    Apollonov, V. V.

    2016-08-01

    Dedicated to the 100th anniversary of the birth of Academician A M Prokhorov, this paper reviews the physics of self-sustained volume discharge without preionization—self-initiated volume discharge (SIVD)—in the working mixtures of non-chain hydrofluoride HF (deuterofluoride (DF)) lasers. The dynamics of SIVD in discharge gaps with different geometries is thoroughly described. The mechanisms for the restriction of current density in a diffuse channel in electric discharges in SF6 and SF6 based mixtures (which determines whether SIVD is possible) are proposed and analyzed using simple models. The most probable mechanisms are the electron impact dissociation of SF6 and other mixture components, electron-ion recombination and electron attachment to vibrationally excited SF6 molecules. Starting from a comparative analysis of the rate coefficients of these processes, it is shown that electron-ion recombination is capable of compensating for electron detachment from negative ions via electron impact. It is also established that SIVD is not only observed in SF6, but also in other strongly electronegative gases. The factors that determine the uniformity of the active medium in non-chain HF (DF) lasers are analyzed. Some special features of non-chain HF (DF) lasers with different apertures operating are carefully examined. Consideration is given to the problem of increasing the aperture and discharge volume of non-chain HF (DF) lasers. Based on our experimental results, the possibility of increasing the energy of such lasers to ~1 kJ and above is shown.

  12. Radiation grafting of various water-soluble monomers on ultra-high molecular weight polyethylene powder. Part II: Thermal, FTIR and morphological characterisation

    Energy Technology Data Exchange (ETDEWEB)

    Aydinli, Bahattin; Tincer, Teoman E-mail: teotin@metu.edu.tr

    2001-10-01

    Radiation induced grafted polyacrylic acid (PAA), polymethacrylic acid (PMAA), polyacrylamide (PAAm), poly N,N-dimethyl acrylamide (PNDAAm) and poly 1-vinyl-2 pyrrolidone (PVP) on ultra-high molecular weight polyethylene (UHMWPE) were characterised by DSC, FTIR and SEM analysis. While the effect of irradiation on pure UHMWPE was found to increase crystallinity and cause higher enthalpy of crystallisation, grafted UHMWPE powders showed lower crystallinity and enthalpy of crystallisation. In all grafted UHMWPE there existed secondary transitions corresponding to grafting polymers in the first run of DSC above 60 deg. C and they became clearer at a higher grafting level. In the second run of DSC some T{sub g} values appeared to shift to higher temperatures while some were not detected. FTIR analysis indicated the presence of water-soluble polymers in the grafted UHMWPE. The characteristic peaks of water-soluble polymers became sharper in the grafted UHMWPE. SEM analysis revealed that the grafting occurs both on fiber and microparticles of UHMWPE while flowing characteristic of powder is retained.

  13. Exploratory studies on substitutions in the tetrahedrite-tennantite solid solution series Part III. The solubility of bismuth in tetrahedrite-tennantite containing iron and zinc

    DEFF Research Database (Denmark)

    Hansen, K.M.; Karup-Møller, Sven; Makovicky, E.

    2003-01-01

    .f.u., with pure As, resp. Sb, or with As: Sb = 1: 1. They were prepared with one and two atoms of Bi p.f.u., respectively, at all three temperatures. Separate sets of non-stoichiometric compositions were prepared in order to examine the influence of high- and low sulfur fugacity, respectively, on the solubility...... of Bi in tetrahedrite/termantite. Our studies suggest that the solubility of Bi in tetrahedrite-termanite is 0.8 atom p.f.u. at 350 degreesC and I atom p.f.u. at 450 degreesC and 520 degreesC, independent of the Sb/As ratio. It increases with the increase in S fugacity and vice versa. The average...... increment of the cubic lattice parameter a is 0.011 Angstrom/l Bi atom p.f.u. for tetrahedrite, that for termantite is 0.036 Angstrom/l Bi atom p.f.u. in the range investigated. The most prominent associated phases studied were Bi-bearing bornite, cuprobismutite, Phase Z, and wittichenite....

  14. Single layer of Ge quantum dots in HfO2 for floating gate memory capacitors.

    Science.gov (United States)

    Lepadatu, A M; Palade, C; Slav, A; Maraloiu, A V; Lazanu, S; Stoica, T; Logofatu, C; Teodorescu, V S; Ciurea, M L

    2017-04-28

    High performance trilayer memory capacitors with a floating gate of a single layer of Ge quantum dots (QDs) in HfO2 were fabricated using magnetron sputtering followed by rapid thermal annealing (RTA). The layer sequence of the capacitors is gate HfO 2/floating gate of single layer of Ge QDs in HfO 2/tunnel HfO 2/p-Si wafers. Both Ge and HfO2 are nanostructured by RTA at moderate temperatures of 600-700 °C. By nanostructuring at 600 °C, the formation of a single layer of well separated Ge QDs with diameters of 2-3 nm at a density of 4-5 × 10(15) m(-2) is achieved in the floating gate (intermediate layer). The Ge QDs inside the intermediate layer are arranged in a single layer and are separated from each other by HfO2 nanocrystals (NCs) about 8 nm in diameter with a tetragonal/orthorhombic structure. The Ge QDs in the single layer are located at the crossing of the HfO2 NCs boundaries. In the intermediate layer, besides Ge QDs, a part of the Ge atoms is segregated by RTA at the HfO2 NCs boundaries, while another part of the Ge atoms is present inside the HfO2 lattice stabilizing the tetragonal/orthorhombic structure. The fabricated capacitors show a memory window of 3.8 ± 0.5 V and a capacitance-time characteristic with 14% capacitance decay in the first 3000-4000 s followed by a very slow capacitance decrease extrapolated to 50% after 10 years. This high performance is mainly due to the floating gate of a single layer of well separated Ge QDs in HfO2, distanced from the Si substrate by the tunnel oxide layer with a precise thickness.

  15. Radiation grafting of various water-soluble monomers on ultra-high molecular weight polyethylene powder:. Part I. Grafting conditions and grafting yield

    Science.gov (United States)

    Aydinli, Bahattin; Tinçer, Teoman

    2001-02-01

    Monomers of some water-soluble polymers; acrylic acid, methacrylic acid, acrylamide, N, N -dimethyl acrylamide and 1-vinyl-2 pyrrolidone, were grafted on ultra-high molecular weight polyethylene (UHMWPE) powders by a direct grafting method in an aqueous medium in air. Inhibition of homopolymerisation was achieved by adding various concentrations of Fe 2+ or Cu 2+ ions. It was found that the degree of grafting increases linearly with dose till a gelation state is reached, and varies between 40 and 12% depending on the monomer. Four million molecular weight UHMWPE gave a higher per cent grafting than a 6 million counterpart for the monomers used, with the exception of acrylic acid monomer grafting.

  16. Radiation grafting of various water-soluble monomers on ultra-high molecular weight polyethylene powder: Part I. Grafting conditions and grafting yield

    Energy Technology Data Exchange (ETDEWEB)

    Aydinli, Bahattin; Tincer, Teoman E-mail: teotin@metu.edu.tr

    2001-02-01

    Monomers of some water-soluble polymers; acrylic acid, methacrylic acid, acrylamide, N, N-dimethyl acrylamide and 1-vinyl-2 pyrrolidone, were grafted on ultra-high molecular weight polyethylene (UHMWPE) powders by a direct grafting method in an aqueous medium in air. Inhibition of homopolymerisation was achieved by adding various concentrations of Fe{sup 2+} or Cu{sup 2+} ions. It was found that the degree of grafting increases linearly with dose till a gelation state is reached, and varies between 40 and 12% depending on the monomer. Four million molecular weight UHMWPE gave a higher per cent grafting than a 6 million counterpart for the monomers used, with the exception of acrylic acid monomer grafting. (author)

  17. The guanidinium group as a key part of water-soluble polymer carriers for siRNA complexation and protection against degradation.

    Science.gov (United States)

    Tabujew, Ilja; Freidel, Christoph; Krieg, Bettina; Helm, Mark; Koynov, Kaloian; Müllen, Klaus; Peneva, Kalina

    2014-07-01

    Here, the preparation of a novel block copolymer consisting of a statistical copolymer N-(2-hydroxypropyl) methacrylamide-s-N-(3-aminopropyl) methacrylamide and a short terminal 3-guanidinopropyl methacrylamide block is reported. This polymer structure forms neutral but water-soluble nanosized complexes with siRNA. The siRNA block copolymer complexes are first analyzed using agarose gel electrophoresis and their size is determined with fluorescence correlation spectroscopy. The protective properties of the polymer against RNA degradation are investigated by treating the siRNA block copolymer complexes with RNase V1. Heparin competition assays confirm the efficient release of the cargo in vitro. In addition, the utilization of microscale thermophoresis is demonstrated for the determination of the binding strength between a fluorescently labeled polyanion and a polymer molecule.

  18. A thirty second isomer in Hf-171

    NARCIS (Netherlands)

    Campbell, P; Billowes, J; Cochrane, ECA; Cooke, JL; Cooper, TG; Dendooven, P; Evans, DE; Grant, IS; Griffith, JAR; Honkanen, A; Huhta, M; Oinonen, M; Pearson, MR; Penttila, H; Persson, B.L.; Richardson, DS; Tungate, G; Wheeler, PD; Zybert, L; Aysto, J

    1997-01-01

    An isomer has been detected in Hf-171 with a half-life of T-1/2 = 29.5(9) s. The state was populated in the Yb-170(alpha,3n)Hf-171m reaction at a beam energy of E-alpha = 50 MeV in an on-line ion guide isotope separator. The isomeric Hf-17lm(+) beam was extracted from the ion guide, mass-analysed an

  19. The study of multilayers Fe/Hf and Ni/Hf by slow positron beam technique

    Science.gov (United States)

    Tashiro, Mutsumi; Nakajyo, Terunobu; Murashige, Yusuke; Koizumi, Tomoya; Kanazawa, Ikuzo; Komori, Fumio; Soe, We-Hyo; Yamamoto, Ryoichi; Ito, Yasuo

    1997-05-01

    The S-parameters versus the incident positron energy are measured in the Ni/Hf multilayer, thin Hf film, thin Fe film and the bilayer Fe/Hf. We have analyzed the change in vacancy-type defects in these multilayers and thin films with the deposition temperature in the MBE system.

  20. HF radiation emitted by chaotic leader processes

    Science.gov (United States)

    Mäkelä, J. S.; Edirisinghe, M.; Fernando, M.; Montaño, R.; Cooray, V.

    2007-04-01

    This paper presents direct measurements of narrowband 10 MHz HF radiation from so-called “chaotic leaders” associated with subsequent return strokes. Although the term is controversial and poorly defined, we find that more than 30% of subsequent strokes in close lightning flashes contain electric field characteristics that are best described as “chaotic”. In earlier studies, return strokes have consistently been observed to be the strongest sources of HF radiation, but the results for leader processes are less consistent. We also observe return strokes to be the main HF emitter, and the leaders before the first return stroke in a flash sequence also emit HF though somewhat less intensely. The leaders preceding subsequent strokes typically emit little or no HF radiation, whether they are dart or dart-stepped leaders. However, it was observed that the presence of a chaotic component increases the leader HF intensity dramatically Defining the HF intensity unequivocally can be problematic for processes like chaotic leaders which have a combination of continuous and impulsive phenomena. Two time-domain methods were used to measure the HF intensity, the peak energy and the RMS energy. In the frequency domain these correspond to the energy spectral density (ESD) and power spectral density (PSD), respectively. It was found that the methods are not necessarily compatible. Thus, it is suggested that to clarify future work, leader processes should be characterized by the PSD rather than the ESD.

  1. HfS, Hyperfine Structure Fitting Tool

    CERN Document Server

    Estalella, Robert

    2016-01-01

    HfS is a tool to fit the hyperfine structure of spectral lines, with multiple velocity components. The HfS_nh3 procedures included in HfS fit simultaneously the hyperfine structure of the NH$_3$ (J,K)= (1,1) and (2,2) transitions, and perform a standard analysis to derive $T_\\mathrm{ex}$, NH$_3$ column density, $T_\\mathrm{rot}$, and $T_\\mathrm{k}$. HfS uses a Monte Carlo approach for fitting the line parameters. Especial attention is paid to the derivation of the parameter uncertainties. HfS includes procedures that make use of parallel computing for fitting spectra from a data cube.

  2. Water soluble aerosols and gases at a UK background site - Part 1: Controls of PM2.5 and PM10 aerosol composition

    Science.gov (United States)

    Twigg, M. M.; Di Marco, C. F.; Leeson, S.; van Dijk, N.; Jones, M. R.; Leith, I. D.; Morrison, E.; Coyle, M.; Proost, R.; Peeters, A. N. M.; Lemon, E.; Frelink, T.; Braban, C. F.; Nemitz, E.; Cape, J. N.

    2015-07-01

    There is limited availability of long-term, high temporal resolution, chemically speciated aerosol measurements which can provide further insight into the health and environmental impacts of particulate matter. The Monitor for AeRosols and Gases (MARGA, Applikon B.V., NL) allows for the characterisation of the inorganic components of PM10 and PM2.5 (NH4+, NO3-, SO42-, Cl-, Na+, K+, Ca2+, Mg2+) and inorganic reactive gases (NH3, SO2, HCl, HONO and HNO3) at hourly resolution. The following study presents 6.5 years (June 2006 to December 2012) of quasi-continuous observations of PM2.5 and PM10 using the MARGA at the UK EMEP supersite, Auchencorth Moss, SE Scotland. Auchencorth Moss was found to be representative of a remote European site with average total water soluble inorganic mass of PM2.5 of 3.82 μg m-3. Anthropogenically derived secondary inorganic aerosols (sum of NH4+, NO3- and nss-SO42-) were the dominating species (63 %) of PM2.5. In terms of equivalent concentrations, NH4+ provided the single largest contribution to PM2.5 fraction in all seasons. Sea salt was the main component (73 %) of the PMcoarse fraction (PM10-PM2.5), though NO3- was also found to make a relatively large contribution to the measured mass (17 %) providing evidence of considerable processing of sea salt in the coarse mode. There was on occasions evidence of aerosol from combustion events being transported to the site in 2012 as high K+ concentrations (deviating from the known ratio in sea salt) coincided with increases in black carbon at the site. Pollution events in PM10 (defined as concentrations > 12 μg m-3) were on average dominated by NH4+ and NO3-, where smaller loadings at the site tended to be dominated by sea salt. As with other western European sites, the charge balance of the inorganic components resolved were biased towards cations, suggesting the aerosol was basic or more likely that organic acids contributed to the charge balance. This study demonstrates the UK background

  3. Water soluble aerosols and gases at a UK background site – Part 1: Controls of PM2.5 and PM10 aerosol composition

    Directory of Open Access Journals (Sweden)

    M. M. Twigg

    2015-02-01

    Full Text Available There is limited availability of long-term, high temporal resolution, chemically speciated aerosol measurements, which can lead to further insight into the health and environmental impacts of particulate matter. The Monitor for AeRosols and Gases (MARGA, Applikon B.V., NL allows characterisation of the inorganic components of PM10 and PM2.5 (NH4+, NO3−, SO42−, Cl−, Na+, K+, Ca2+, Mg2+ and inorganic reactive gases (NH3, SO2, HCl, HONO and HNO3 at hourly resolution. The following study presents 6.5 years (June 2006 to December 2012 of quasi-continuous observations of PM2.5 and PM10 using the MARGA at the UK EMEP "Supersite", Auchencorth Moss, SE Scotland. Auchencorth Moss was found to be representative of a remote European site with average total water soluble inorganic mass of PM2.5 of 3.82 μg m−3. Anthropogenically derived secondary inorganic aerosols (sum of NH4+, NO3− and nss-SO42−, were the dominating species (63% of PM2.5. In terms of equivalent concentrations, NH4+ provided the single largest contribution to PM2.5 fraction in all seasons. Sea salt, was the main component (73% of the PMcoarse fraction (PM10–PM2.5, though NO3− was also found to make a relatively large contribution to the measured mass (17% as providing evidence of considerable processing of sea salt in the coarse mode. There was on occasions evidence of aerosol from combustion events being transported to the site in 2012 as high K+ concentrations (deviating from the known ratio in sea salt coincided with increases in black carbon at the site. Pollution events in PM10 (defined as concentrations > 12 μg m−3 were on average dominated by NH4+ and NO3−, where as smaller loadings at the site tended to be dominated by sea salt. As with other Western European sites, the charge balance of the inorganic components resolved were biased towards cations, suggesting the aerosol was basic or more likely, that organic acids

  4. Aspects of HF radio propagation

    Directory of Open Access Journals (Sweden)

    Stephane Saillant

    2009-06-01

    Full Text Available

    radio systems. From the point of view Working Group 2 of the COST 296 Action, interest lies with effects associated

    with propagation via the ionosphere of signals within the HF band. Several aspects are covered in this paper:

    a The directions of arrival and times of flight of signals received over a path oriented along the trough have

    been examined and several types of propagation effects identified. Of particular note, combining the HF observations

    with satellite measurements has identified the presence of irregularities within the floor of the trough that

    result in propagation displaced from the great circle direction. An understanding of the propagation effects that

    result in deviations of the signal path from the great circle direction are of particular relevance to the operation

    of HF radiolocation systems.

    b Inclusion of the results from the above mentioned measurements into a propagation model of the northerly

    ionosphere (i.e. those regions of the ionosphere located poleward of, and including, the mid-latitude trough

    and the use of this model to predict the coverage expected from transmitters where the signals impinge on the

    northerly ionosphere

  5. Grindability of cast Ti-Hf alloys.

    Science.gov (United States)

    Kikuchi, Masafumi; Takahashi, Masatoshi; Sato, Hideki; Okuno, Osamu; Nunn, Martha E; Okabe, Toru

    2006-04-01

    As part of our systematic studies characterizing the properties of titanium alloys, we investigated the grindability of a series of cast Ti-Hf alloys. Alloy buttons with hafnium concentrations up to 40 mass% were made using an argon-arc melting furnace. Each button was cast into a magnesia-based mold using a dental titanium casting machine; three specimens were made for each metal. Prior to testing, the hardened surface layer was removed. The specimens were ground at five different speeds for 1 min at 0.98 N using a carborundum wheel on an electric dental handpiece. Grindability was evaluated as the volume of metal removed per minute (grinding rate) and the volume ratio of metal removed compared to the wheel material lost (grinding ratio). The data were analyzed using ANOVA. A trend of increasing grindability was found with increasing amounts of hafnium, although there was no statistical difference in the grindability with increasing hafnium contents. We also found that hafnium may be used to harden or strengthen titanium without deteriorating the grindability.

  6. Probing Archean lithosphere using the Lu-Hf isotope systematics of peridotite xenoliths from Somerset Island kimberlites, Canada

    Science.gov (United States)

    Schmidberger, Stefanie S.; Simonetti, Antonio; Francis, Don; Gariépy, Clément

    2002-04-01

    A knowledge of the Hf isotopic composition of the subcontinental lithosphere beneath Archean cratons is essential to constrain the Hf isotope budget of the Earth's mantle. Hf isotopic measurements were obtained by MC-ICP-MS for a suite of refractory peridotite xenoliths and constituent garnets from the Nikos kimberlite (100 Ma) on Somerset Island in order to constrain the isotopic composition and age of the lithosphere beneath the northern Canadian craton. The low-temperature Nikos peridotites (Somerset lithosphere, are characterized by higher 176Lu/ 177Hf ratios (0.03-0.05) and Hf isotopic values ( 176Hf/ 177Hf (0.1Ga)=0.28296-0.28419) than the deep-seated high-temperature peridotites (>1100°C; 0.004-0.03, 0.28265-0.28333, respectively). These differences in Hf isotope signatures suggest that shallow and deep subcontinental lithosphere beneath Somerset Island represent isotopically distinct domains and do not share a common petrogenetic history. The Lu-Hf isotope systematics of the shallow low-temperature peridotites define a positively sloped line that plot along a 2.8 Ga reference isochron. A number of these peridotites are characterized by highly radiogenic Hf isotopic compositions suggestive of long-term radiogenic ingrowth (billions of years). These findings are consistent with an interpretation that the shallow Somerset lithosphere (to depths of ˜150 km) stabilized in the Archean. The majority of the high-temperature peridotites plot closer to the composition of the host kimberlite. Although the observed isotopic variation may be attributed in part to kimberlite-related Hf addition, it is possible that these deep-seated xenoliths represent younger mantle. The superchondritic 176Lu/ 177Hf ratios observed for a number of the shallow low-temperature peridotites indicate strong fractionation of Lu and Hf, suggesting mantle root formation in the garnet stability field (depths >80 km). The Hf isotope compositions for the Somerset low-temperature peridotites

  7. HF Transverse Segmentation and Tagging Jet Capability

    CERN Document Server

    Doroshkevich, E A; Kuleshov, Sergey

    1998-01-01

    So called tagging jets and pile-up were simulated for the optimisation of the HF segmentation. The energy resolution, angular resolution and efficiency of jet reconstruction are defined for different calorimeter segmentation.

  8. Collisional quenching of highly rotationally excited HF

    CERN Document Server

    Yang, Benhui; Forrey, R C; Stancil, P C; Balakrishnan, N

    2015-01-01

    Collisional excitation rate coefficients play an important role in the dynamics of energy transfer in the interstellar medium. In particular, accurate rotational excitation rates are needed to interpret microwave and infrared observations of the interstellar gas for nonlocal thermodynamic equilibrium line formation. Theoretical cross sections and rate coefficients for collisional deexcitation of rotationally excited HF in the vibrational ground state are reported. The quantum-mechanical close-coupling approach implemented in the nonreactive scattering code MOLSCAT was applied in the cross section and rate coefficient calculations on an accurate 2D HF-He potential energy surface. Estimates of rate coefficients for H and H$_2$ colliders were obtained from the HF-He collisional data with a reduced-potential scaling approach. The calculation of state-to-state rotational quenching cross sections for HF due to He with initial rotational levels up to $j=20$ were performed for kinetic energies from 10$^{-5}$ to 15000...

  9. Microhardness evaluation alloys Hf-Si-B; Avaliacao de microdureza de ligas Hf-Si-B

    Energy Technology Data Exchange (ETDEWEB)

    Gigolotti, Joao Carlos Janio; Costa, Eliane Fernandes Brasil [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Nunes, Carlos Angelo; Rocha, Elisa Gombio; Coelho, Gilberto Carvalho, E-mail: carlosjanio@uol.com.br, E-mail: eliane-costabrasi@hotmail.com, E-mail: cnunes@demar.eel.usp.br, E-mail: elisarocha@alunos.eel.usp.br, E-mail: coelho@demar.eel.usp.br [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

    2014-08-15

    The technological advance has generated increasing demand for materials that can be used under high temperature, what includes intermetallic MR-Si-B (MR = refractory metal) alloys with multiphase structures, that can also be applied in oxide environments. Thus, this work had for objective the micro hardness study of the Hf-Si-B system alloys, heat treated at 1600 deg C, in the Hf rich region. Hf-Si-B alloys had been produced with blades of Hf (min. 99.8%), Si (min. 99.998%) and B (min. 99.5%), in the voltaic arc furnace and heat treated at 1600 deg C under argon atmosphere. The relationship of the phases had been previously identified by X-ray diffraction and contrast in backscattered electron imaging mode. The alloys had their hardness analyzed by method Vickers (micro hardness) with load of 0.05 kgf and 0.2 kgf and application time of 20 s. The results, obtained from the arithmetic mean of measurements for each alloy on the heterogeneous region, showed a mean hardness of 11.08 GPA, with small coefficient of variation of 3.8%. The borides HfB2 (19.34 GPa) e HfB - 11.76 GPa, showed the hardness higher than the silicides Hf2Si (8.57 GPa), Hf5Si3 (9.63 GPa), Hf3Si2 (11.66 GPa), Hf5Si4 (10.00 GPa), HfSi (10.02 GPa) e HfSi2 (8.61 GPa). (author)

  10. Effect of Vericiguat, a Soluble Guanylate Cyclase Stimulator, on Natriuretic Peptide Levels in Patients With Worsening Chronic Heart Failure and Reduced Ejection Fraction

    DEFF Research Database (Denmark)

    Gheorghiade, Mihai; Greene, Stephen J; Butler, Javed;

    2015-01-01

    IMPORTANCE: Worsening chronic heart failure (HF) is a major public health problem. OBJECTIVE: To determine the optimal dose and tolerability of vericiguat, a soluble guanylate cyclase stimulator, in patients with worsening chronic HF and reduced left ventricular ejection fraction (LVEF). DESIGN, ...

  11. Gas solubilities widespread applications

    CERN Document Server

    Gerrard, William

    1980-01-01

    Gas Solubilities: Widespread Applications discusses several topics concerning the various applications of gas solubilities. The first chapter of the book reviews Henr's law, while the second chapter covers the effect of temperature on gas solubility. The third chapter discusses the various gases used by Horiuti, and the following chapters evaluate the data on sulfur dioxide, chlorine data, and solubility data for hydrogen sulfide. Chapter 7 concerns itself with solubility of radon, thoron, and actinon. Chapter 8 tackles the solubilities of diborane and the gaseous hydrides of groups IV, V, and

  12. Soluble Fermentable Dietary Fibre (Pectin Decreases Caloric Intake, Adiposity and Lipidaemia in High-Fat Diet-Induced Obese Rats.

    Directory of Open Access Journals (Sweden)

    Clare L Adam

    Full Text Available Consumption of a high fat diet promotes obesity and poor metabolic health, both of which may be improved by decreasing caloric intake. Satiety-inducing ingredients such as dietary fibre may be beneficial and this study investigates in diet-induced obese (DIO rats the effects of high or low fat diet with or without soluble fermentable fibre (pectin. In two independently replicated experiments, young adult male DIO rats that had been reared on high fat diet (HF; 45% energy from fat were given HF, low fat diet (LF; 10% energy from fat, HF with 10% w/w pectin (HF+P, or LF with 10% w/w pectin (LF+P ad libitum for 4 weeks (n = 8/group/experiment. Food intake, body weight, body composition (by magnetic resonance imaging, plasma hormones, and plasma and liver lipid concentrations were measured. Caloric intake and body weight gain were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Body fat mass increased in HF, was maintained in LF, but decreased significantly in LF+P and HF+P groups. Final plasma leptin, insulin, total cholesterol and triglycerides were lower, and plasma satiety hormone PYY concentrations were higher, in LF+P and HF+P than in LF and HF groups, respectively. Total fat and triglyceride concentrations in liver were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Therefore, the inclusion of soluble fibre in a high fat (or low fat diet promoted increased satiety and decreased caloric intake, weight gain, adiposity, lipidaemia, leptinaemia and insulinaemia. These data support the potential of fermentable dietary fibre for weight loss and improving metabolic health in obesity.

  13. Soluble Fermentable Dietary Fibre (Pectin) Decreases Caloric Intake, Adiposity and Lipidaemia in High-Fat Diet-Induced Obese Rats

    Science.gov (United States)

    Adam, Clare L.; Thomson, Lynn M.; Williams, Patricia A.; Ross, Alexander W.

    2015-01-01

    Consumption of a high fat diet promotes obesity and poor metabolic health, both of which may be improved by decreasing caloric intake. Satiety-inducing ingredients such as dietary fibre may be beneficial and this study investigates in diet-induced obese (DIO) rats the effects of high or low fat diet with or without soluble fermentable fibre (pectin). In two independently replicated experiments, young adult male DIO rats that had been reared on high fat diet (HF; 45% energy from fat) were given HF, low fat diet (LF; 10% energy from fat), HF with 10% w/w pectin (HF+P), or LF with 10% w/w pectin (LF+P) ad libitum for 4 weeks (n = 8/group/experiment). Food intake, body weight, body composition (by magnetic resonance imaging), plasma hormones, and plasma and liver lipid concentrations were measured. Caloric intake and body weight gain were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Body fat mass increased in HF, was maintained in LF, but decreased significantly in LF+P and HF+P groups. Final plasma leptin, insulin, total cholesterol and triglycerides were lower, and plasma satiety hormone PYY concentrations were higher, in LF+P and HF+P than in LF and HF groups, respectively. Total fat and triglyceride concentrations in liver were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Therefore, the inclusion of soluble fibre in a high fat (or low fat) diet promoted increased satiety and decreased caloric intake, weight gain, adiposity, lipidaemia, leptinaemia and insulinaemia. These data support the potential of fermentable dietary fibre for weight loss and improving metabolic health in obesity. PMID:26447990

  14. Soluble Fermentable Dietary Fibre (Pectin) Decreases Caloric Intake, Adiposity and Lipidaemia in High-Fat Diet-Induced Obese Rats.

    Science.gov (United States)

    Adam, Clare L; Thomson, Lynn M; Williams, Patricia A; Ross, Alexander W

    2015-01-01

    Consumption of a high fat diet promotes obesity and poor metabolic health, both of which may be improved by decreasing caloric intake. Satiety-inducing ingredients such as dietary fibre may be beneficial and this study investigates in diet-induced obese (DIO) rats the effects of high or low fat diet with or without soluble fermentable fibre (pectin). In two independently replicated experiments, young adult male DIO rats that had been reared on high fat diet (HF; 45% energy from fat) were given HF, low fat diet (LF; 10% energy from fat), HF with 10% w/w pectin (HF+P), or LF with 10% w/w pectin (LF+P) ad libitum for 4 weeks (n = 8/group/experiment). Food intake, body weight, body composition (by magnetic resonance imaging), plasma hormones, and plasma and liver lipid concentrations were measured. Caloric intake and body weight gain were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Body fat mass increased in HF, was maintained in LF, but decreased significantly in LF+P and HF+P groups. Final plasma leptin, insulin, total cholesterol and triglycerides were lower, and plasma satiety hormone PYY concentrations were higher, in LF+P and HF+P than in LF and HF groups, respectively. Total fat and triglyceride concentrations in liver were greatest in HF, lower in LF and HF+P, and lowest in the LF+P group. Therefore, the inclusion of soluble fibre in a high fat (or low fat) diet promoted increased satiety and decreased caloric intake, weight gain, adiposity, lipidaemia, leptinaemia and insulinaemia. These data support the potential of fermentable dietary fibre for weight loss and improving metabolic health in obesity.

  15. Self-healing structural properties of thermoplastics in HF field

    Directory of Open Access Journals (Sweden)

    N. G. Filippenko

    2014-01-01

    Full Text Available The article concerns one of the possible ways for safe operation of polymer products with initiating a process of their self-healing. This is especially true for products from polymer materials, used in hard-to-reach areas and units of machines and mechanisms. In this regard, the aim of this study was to develop techniques for a self-healing process of the mechanical properties of products from polymer materials.To achieve this goal, the author has solved problems to define a complex method of HF self-healing of polymer material: damage detection in products from polymer materials, determination of signal initiating the recovery process, determining the efficiency of material regeneration. The present study uses proposed and developed by the author methods for the determination of necessary and sufficient indicators of the strength characteristics of products under realmeteorological and climatic conditions of their operation.To determine the practical results of the developed algorithm for self-healing the polymer products in the HF field, a series of experimental studies has been conducted to regenerate the polyamide cage fatigue destruction of the rolling stock axle equipment of Russian Railways JSC.The obtained results of the strength characteristics of the material under investigation prove the self-healing process of polymer materials in HF field.According to research results, the conclusion is drawn that it is required to provide a technological HF self-healing process of products from polymer materials. The created algorithm of regeneration enables a new approach to study the effects of electromagnetic fields on polymer and polymer-based composite materials when solving the practical tasks to improve the quality of repairing parts from thermoplastics.

  16. Nonzero Solubility Rule

    Institute of Scientific and Technical Information of China (English)

    尉志武; 周蕊; 刘芸

    2002-01-01

    A solubility-related rule, nonzero solubility rule, is introduced in this paper. It is complementary to the existing rules such as the "like dissolves like" rule and can be understood on the basis of classical chemical thermodynamics.

  17. Stabilization of HfB12 in Y1-xHfxB12 under Ambient Pressure.

    Science.gov (United States)

    Akopov, Georgiy; Yeung, Michael T; Turner, Christopher L; Li, Rebecca L; Kaner, Richard B

    2016-05-16

    Alloys of metal dodecaborides-YB12 with HfB12-were prepared via arc-melting in order to stabilize the metastable HfB12 high-pressure phase under ambient pressure. Previously, HfB12 had been synthesized only under high-pressure (6.5 GPa). Powder X-ray diffraction (PXRD) and energy-dispersive X-ray spectroscopy (EDS) were used to confirm the purity and phase composition of the prepared samples. The solubility limit for HfB12 in Y1-xHfxB12 (cubic UB12 structure type) was determined to be ∼35 at. % Hf by PXRD and EDS analysis. The value of the cubic unit cell parameter (a) changed from 7.505 Å (pure YB12) to 7.454 Å across the solid solution range. Vickers hardness increased from 40.9 ± 1.6 GPa for pure YB12 to 45.0 ± 1.9 GPa under an applied load of 0.49 N for the Y1-xHfxB12 solid solution composition with ∼28 at. % Hf, suggesting both solid solution hardening and extrinsic hardening due to the formation of secondary phases of hafnium.

  18. Amyloid Fibril Solubility

    CERN Document Server

    Rizzi, L G

    2015-01-01

    It is well established that amyloid fibril solubility is protein specific, but how solubility depends on the interactions between the fibril building blocks is not clear. Here we use a simple protein model and perform Monte Carlo simulations to directly measure the solubility of amyloid fibrils as a function of the interaction between the fibril building blocks. Our simulations confirms that the fibril solubility depends on the fibril thickness and that the relationship between the interactions and the solubility can be described by a simple analytical formula. The results presented in this study reveal general rules how side-chain side-chain interactions, backbone hydrogen bonding and temperature affect amyloid fibril solubility, which might prove a powerful tool to design protein fibrils with desired solubility and aggregation properties in general.

  19. General concepts of modern HF communications

    Science.gov (United States)

    Aarons, Jules

    Both conceptual and hardware advancements have led to substantial systems developments in military HF communications; the former encompass coding and error correction techniques for security, in order to minimize propagation and interference, while the latter prominently include digital equipment permitting the selection of a frequency for a particular path and propagation mode, as well as modulation selection. Propagation-related advancements involve better statistical models as well as advancements in short-term forecasting methods responsive to changes in solar-geophysical parameters. Adaptive HF systems have been developed for meteor-scatter radio communications.

  20. Research on Multi-Layer Distributed HF Radio Network Structure

    Institute of Scientific and Technical Information of China (English)

    Hui Dai; Chun-Jiang Wang; Quan Yu

    2008-01-01

    High frequency (HF) transmission is an important communication techniques. However, conventional point-to-point transmission can be easily destroyed, which limits its utilization in practice. HF networking communication has the capability against demolishment. The network structure is one of the key factors for HF networking communication. In this paper, a novel analysis method of the network connectedness based on the eigenvalue is derived, and a multi-layer distributed HF radio network structure is proposed. Both the theore tical analysis and the computer simulation results verify that the application of the proposed network structure in the HF radio communication can improve the anti demolishment ability of the HF network efficiently.

  1. Solubility database for TILA-99

    Energy Technology Data Exchange (ETDEWEB)

    Vuorinen, U.; Carlsson, T. [VTT Chemical Technology, Espoo (Finland); Kulmala, S.; Hakanen, M. [Helsinki Univ. (Finland). Lab. of Radiochemistry; Ahonen, L. [Geological Survey of Finland, Espoo (Finland)

    1998-11-01

    The safety assessment of spent fuel disposal requires solubility values for several elements estimated in Finnish disposal conditions. In Finland four sites (Haestholmen, Kivetty, Olkiluoto and Romuvaara) are investigated for the disposal of spent fuel. Haestholmen and OLkiluoto are onshore sites, while Kivetty and Romuvaara are inland sites. Based on groundwater analysis and classification according to salinity at the planned disposal depth mainly fresh groundwater is encountered at Kivetty and Romuvaara, while brackish and saline water-types are met at Haestholmen and Olkiluoto. Very saline, almost brine-type water ({approx}70 g/l) has been found in the deepest parts of the investigated bedrock at one of the sites (Olkiluoto). The reference waters and conditions were chosen according to the water-types. The considered reference conditions incorporated both the near- and far-field, and both oxidizing and reducing conditions were considered. In the reference conditions, the changes in solubilities were also estimated as caused by possible variations in the pH, carbonate content and redox conditions. Uranium, which is the main component of spent fuel is dealt with in a separate report presenting the solubility of uranium and spent fuel dissolution. In this work the solubilities of all the other elements of concern (Am, Cu, Nb, Np, Pa, Pd, Pu, Ra, Se, Sn, Tc, Zr, Cm, Ni, Sr, Th, C, Cl, Cs, Fe, Ho, I, and Sm) in the safety assessment are considered. Some discussion on the corrosion of the spent fuel canister is also presented. For the estimation of solubilities of the elements in question, literature data was collected that mainly comprised experimentally measured concentrations. The sources used were spent fuel experiments, concentrations measured in solubility measurements, natural concentrations and concentrations from natural analogue sites (especially Palmottu and Hyrkkoelae in Finland) as well as the concentrations measured at the Finnish investigation sites

  2. Synthesis and reactivity of fluoro complexes: Part 2. Rhodium(I) fluoro complexes with alkene and phosphine ligands. Synthesis of the first isolated rhodium(I) bifluoride complexes. Structure of [Rh3(mu3-OH)2(COD)(3)](HF2) by X-ray powder diffraction.

    Science.gov (United States)

    Vicente, José; Gil-Rubio, Juan; Bautista, Delia; Sironi, Angelo; Masciocchi, Norberto

    2004-09-01

    The reaction between [Rh(mu-OH)(COD)](2) (COD = 1,5-cyclooctadiene) and 73% HF in THF gives [Rh(3)(mu(3)-OH)(2)(COD)(3)](HF(2)) (1). Its crystal structure, determined by ab initio X-ray powder diffraction methods (from conventional laboratory data), contains complex trimetallic cations linked together in 1D chains by a mu(3)-OH...F-H-F...HO-mu(3) sequence of strong hydrogen bonds. The complex [Rh(mu-F)(COE)(2)](2) (COE = cyclooctene; 2), prepared by reacting [Rh(mu-OH)(COE)(2)](2) with NEt(3).3HF (3:2), has been characterized. Complex 1 reacts with PR(3) (1:3) to give [RhF(COD)(PR(3))] [R = Ph (3), C(6)H(4)OMe-4 (4), (i)Pr (5), Cy (6)] that can be prepared directly by reacting [Rh(mu-OH)(COD)](2) with 73% HF and PR(3) (1:2:2). The reactions of 1 with PPh(3) or Et(3)P have been studied by NMR spectroscopy at different molar ratios. Complexes [RhF(PEt(3))(3)] (7), [RhF(COD)(PEt(3))] (8), and [RhF(PPh(3))(3)] (9) have been detected. The complex [Rh(F)(NBD)(iPr(3)P)] (NBD = norbornadiene; 10) was prepared by the sequential treatment of [Rh(mu-OMe)(NBD)](2) with 1 equiv of NEt(3).3HF and (i)Pr(3)P. The first isolated bifluoride rhodium(I) complexes [Rh(FHF)(COD)(PR(3))] [R = Ph (11), (i)Pr (12), Cy (13)], obtained by reacting fluoro complexes 3, 5, and 6 with NEt(3).3HF (3:1), have been characterized. The crystal structures of 3 and 11 have been determined.

  3. Soluble oil cutting fluid

    Energy Technology Data Exchange (ETDEWEB)

    Rawlinson, A.P.; White, J.

    1987-06-23

    A soluble oil, suitable when diluted with water, for use as a cutting fluid comprises an alkali or alkaline-earth metal alkyl benzene sulphonate, a fatty acid diethanolamide, a mixed alkanolamine borate, a polyisobutenesuccinimide and a major proportion of mineral oil. The soluble oil is relatively stable without the need for a conventional coupling agent and some soluble oil emulsions are bio-static even though conventional biocides are not included.

  4. Stability-enhanced hot-melt extruded amorphous solid dispersions via combinations of Soluplus® and HPMCAS-HF.

    Science.gov (United States)

    Alshahrani, Saad M; Lu, Wenli; Park, Jun-Bom; Morott, Joseph T; Alsulays, Bader B; Majumdar, Soumyajit; Langley, Nigel; Kolter, Karl; Gryczke, Andreas; Repka, Michael A

    2015-08-01

    The aim of this study was to evaluate a novel combination of Soluplus® and hypromellose acetate succinate (HPMCAS-HF) polymers for solubility enhancement as well as enhanced physicochemical stability of the produced amorphous solid dispersions. This was accomplished by converting the poorly water-soluble crystalline form of carbamazepine into a more soluble amorphous form within the polymeric blends. Carbamazepine (CBZ), a Biopharmaceutics Classification System class II active pharmaceutical ingredient (API) with multiple polymorphs, was utilized as a model drug. Hot-melt extrusion (HME) processing was used to prepare solid dispersions utilizing blends of polymers. Drug loading showed a significant effect on the dissolution rate of CBZ in all of the tested ratios of Soluplus® and HPMCAS-HF. CBZ was completely miscible in the polymeric blends of Soluplus® and HPMCAS-HF up to 40% drug loading. The extrudates were characterized by differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and dissolution studies. DSC and XRD data confirmed the formation of amorphous solid dispersions of CBZ in the polymeric blends of Soluplus® and HPMCAS-HF. Drug loading and release of CBZ was increased with Soluplus® (when used as the primary matrix polymer) when formulations contained Soluplus® with 7-21% (w/w) HPMCAS-HF. In addition, this blend of polymers was found to be physically and chemically stable at 40°C, 75% RH over 12 months without any dissolution rate changes.

  5. 75 FR 10186 - Beauveria bassiana HF23; Amendment of Exemption from the Requirement of a Tolerance

    Science.gov (United States)

    2010-03-05

    ... [Federal Register Volume 75, Number 43 (Friday, March 5, 2010)] [Rules and Regulations] [Pages 10186-10190] [FR Doc No: 2010-4544] ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 180 [EPA-HQ-OPP-2005-0316; FRL-8814-6] Beauveria bassiana HF23; Amendment of Exemption from the Requirement of a...

  6. Systematic Comparison of HF CMOS Transconductors

    NARCIS (Netherlands)

    Klumperink, Eric A.M.; Nauta, Bram

    2003-01-01

    Transconductors are commonly used as active elements in high-frequency (HF) filters, amplifiers, mixers, and oscillators. This paper reviews transconductor design by focusing on the V-I kernel that determines the key transconductor properties. Based on bandwidth considerations, simple V-I kernels wi

  7. Electron impact on vibrationally cold {{HF}}^{+}

    Science.gov (United States)

    Cristian Stroe, Marius; Fifirig, Magda

    2016-12-01

    The dissociative recombination and vibrational excitation processes induced by electron impact on vibrationally cold {{HF}}+ are investigated in the framework of the multichannel quantum defect theory for electron energies below 1 eV. The thermal rate coefficients for the electron temperature range from 10 to 5000 K are reported.

  8. ORIGIN OF EXCESS (176)Hf IN METEORITES

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James Norman; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  9. The Solubility of struvite

    DEFF Research Database (Denmark)

    Aage, H. K.; Andersen, Bertel Lohmann; Blom, A.

    1997-01-01

    The solubility of magnesium-amonium-phosphate (struvite) has been studied emloying the radioisotope 32P as tracer. The amount of sample in solution is determined by measuring the Cherenkov radiation due to the beta-particles emitted from this radionuclide. The thermodynamic solubility product...

  10. Phase1 upgrade of the CMS-HF Calorimeter

    CERN Document Server

    Gulmez, Erhan

    2016-01-01

    In this presentation, results of the Phase I upgrade of the CMS Hadron Forward Calorimeter (HF) are discussed. The CMS-HF Calorimeter was using regular PMTs. Cherenkov light produced in the quartz fibers embedded in the iron absorber was read out with the PMTs. However, occasionally, stray muons hitting the PMT windows cause Cherenkov radiation in the PMT itself and produce large signals. These large signals mimic a very high-energy particle and are tagged as important by the trigger. To reduce this problem, PMTs had to be replaced. The four-anode PMTs that were chosen have thinner windows; thereby reducing the Cherenkov radiation in the PMT window. As part of the upgrade, the read-out electronics is to be replaced so that the PMTs are read out in two channels by connecting each pair of anodes to a single channel. Information provided by these two channels will help us reject the false signals due to the stray muons since the Cherenkov radiation in the PMT window is more likely to produce a signal only in one...

  11. REMPI Spectroscopy of HfF

    CERN Document Server

    Loh, Huanqian; Yahn, Tyler S; Looser, Herbert; Field, Robert W; Cornell, Eric A

    2012-01-01

    The spectrum of electronic states at 30000--33000 cm$^{-1}$ in hafnium fluoride has been studied using (1+1) resonance-enhanced multi-photon ionization (REMPI) and (1+1$'$) REMPI. Six $\\Omega' = 3/2$ and ten $\\Pi_{1/2}$ vibronic bands have been characterized. We report the molecular constants for these bands and estimate the electronic energies of the excited states using a correction derived from the observed isotope shifts. When either of two closely spaced $\\Pi_{1/2}$ electronic states is used as an intermediate state to access autoionizing Rydberg levels, qualitatively distinct autoionization spectra are observed. The intermediate state-specificity of the autoionization spectra bodes well for the possibility of using a selected $\\Pi_{1/2}$ state as an intermediate state to create ionic HfF$^+$ in various selected quantum states, an important requirement for our electron electric dipole moment (eEDM) search in HfF$^+$.

  12. Digitally Driven Antenna for HF Transmission

    Science.gov (United States)

    2010-09-01

    the 1-MHz carrier signal. This signal is then fed into the base terminals of an NPN/ PNP transistor pair arranged in a push–pull configura- tion. A dual...negative voltage connected to the collector terminal of the PNP transistor . Since it was not possible to explicitly simulate the radia- tion of the time...complementary pair of switching transistors is driven with a pulsewidth modulated HF signal, eliminating the requirement for a frequency-dependent

  13. RFID UHF i HF w bibliotekach

    Directory of Open Access Journals (Sweden)

    Gładysz Bartłomiej

    2015-06-01

    Full Text Available The potential of the innovative Radio Frequency Identification (RFID technology to be applied for support, acceleration and automation of the circulation process of library collection is presented. Technology basics, and hardware and software components are described. Two different radio standards used in libraries are compared. The goal is to present the potential of RFID technology for libraries, to highlight the differences and to build a basis for further consideration of UHF and HF alternatives.

  14. Optimizing solubility: kinetic versus thermodynamic solubility temptations and risks.

    Science.gov (United States)

    Saal, Christoph; Petereit, Anna Christine

    2012-10-09

    The aim of this study was to assess the usefulness of kinetic and thermodynamic solubility data in guiding medicinal chemistry during lead optimization. The solubility of 465 research compounds was measured using a kinetic and a thermodynamic solubility assay. In the thermodynamic assay, polarized-light microscopy was used to investigate whether the result referred to the crystalline or to the amorphous compound. From the comparison of kinetic and thermodynamic solubility data it was noted that kinetic solubility measurements frequently yielded results which show considerably higher solubility compared to thermodynamic solubility. This observation is ascribed to the fact that a kinetic solubility assay typically delivers results which refer to the amorphous compound. In contrast, results from thermodynamic solubility determinations more frequently refer to a crystalline phase. Accordingly, thermodynamic solubility data--especially when used together with an assessment of the solid state form--are deemed to be more useful in guiding solubility optimization for research compounds.

  15. Soluble CD163

    DEFF Research Database (Denmark)

    Parkner, Tina; Sørensen, L P; Nielsen, A R

    2012-01-01

    Soluble CD163 (sCD163) was recently identified as a strong risk marker for developing type 2 diabetes. We hypothesised that sCD163 independently associates with insulin resistance.......Soluble CD163 (sCD163) was recently identified as a strong risk marker for developing type 2 diabetes. We hypothesised that sCD163 independently associates with insulin resistance....

  16. Facile Routes to NiF(6)(2)(-), AgF(4)(-), AuF(6)(-), and PtF(6)(-) Salts Using O(2)(+) as a Source of O(2)F in Anhydrous HF.

    Science.gov (United States)

    Lucier, G. M.; Shen, C.; Elder, S. H.; Bartlett, N.

    1998-07-27

    O(2)(+) salts dissolved in liquid anhydrous hydrogen fluoride (aHF) at 20 degrees C or below oxidize aHF solutions of PtF(6)(2)(-) to PtF(6)(-). The parent base of O(2)(+) salts in aHF (O(2)F((solv))) generated with alkali fluoride is long-lived below -50 degrees C. An aHF solution of O(2)F((solv)) oxidizes Au(III) to Au(V) below -50 degrees C (2O(2)F((solv)) + AuF(4)(-)((solv)) --> AuF(6)(-)((solv)) +2O(2(g))). In situ generation of O(2)F((solv)) (O(2)(+)((solv)) + F(-)((solv)) --> O(2)F((solv))) with AgF(2) or NiF(2) in suspension in the aHF made basic with alkali fluoride gives AgF(4)(-) and NiF(6)(2)(-)salts. Low solubility of AAsF(6)(A = Cs, K) in aHF provides for the metathetical preparation of (O(2))(2)PdF(6) solutions in aHF. Removal of aHF, even at -60 degrees C, results in some O(2) and F(2) loss, to a composition approaching (O(2))PdF(5).

  17. An experimental study of the solubility and speciation of niobium in fluoride-bearing aqueous solutions at elevated temperature

    Science.gov (United States)

    Timofeev, A.; Migdisov, Art. A.; Williams-Jones, A. E.

    2015-06-01

    The solubility of Nb2O5 and the speciation of niobium in HF-bearing aqueous solutions have been determined at temperatures of 150, 200, and 250 °C and saturated water pressure. At a pH of ∼2 and at low HF concentration, niobium is transported primarily as the species Nb(OH)4+ and at high HF concentration, as the species NbF2(OH)3°. Equilibrium constants for the formation of Nb(OH)4+ range from -11.23 ± 0.26 to -10.86 ± 0.24 and for the formation of NbF2(OH)3° from -3.84 ± 0.20 to -5.08 ± 0.42, at 150 and 250 °C. The results of this study show that the solubility of Nb2O5 (solid) in aqueous fluids increases with increasing HF concentration, but is not strongly affected by temperature. The influence of pH is variable; at low pH and HF concentration, a decrease in pH increases the solubility of Nb2O5 (solid). At higher pH, the reverse may be true. Modeling of the transport and deposition of niobium suggests that simple mixing with a brine is not an effective method for removing niobium from solution. By contrast, interaction of an acidic fluid with carbonate rock results in a rapid reduction in the capacity of the fluid to mobilize niobium.

  18. Improvements on Signal Processing for HF Radar

    Institute of Scientific and Technical Information of China (English)

    LIU Yongtan; SHEN Yiying

    2001-01-01

    In this paper improvements on signalprocessing are achieved to enhance the performancesof H-F radar system, being unobtainable by the con-ventional signal processing. Using the improved sig-nal processing both high range resolution and longcoherent integration time may be obtained for goodbenefit to the target resolution and weak signal de-tection. Modification to the unmatched correspon-dence between range delay samples and range resolu-tion ceils saves an additional accumulation loss in therange processing. Finally, comparisons between theimproved and the conventional signal processing aregiven by numerical simulation.

  19. Solubility of deposited airborne heavy metals

    Science.gov (United States)

    Cizmecioglu, Sibel C.; Muezzinoglu, Aysen

    2008-09-01

    Toxic effects of heavy metals in water and soil environments are important. Quantifying the heavy metal concentrations and their solubilities in dry and wet deposition samples is part of atmospheric research. Soluble fractions of the deposited air pollutants are important in food chain mechanisms as heavy metals may cause ecotoxic impacts. In this study, the solubilities of Cr, Cd, Pb, Cu, Zn, and Ni were investigated in deposition samples for total, dissolved, and suspended fractions after collection in a surrogate, water-surface sampler in Izmir, Turkey, during October 2003 to June 2004. To find overall solubility of each metal in dry and wet deposition samples, concentrations in soluble and suspended phases of aqueous solutions were analyzed separately. Ratios between total and dissolved forms and the metals in the same forms were analyzed and evaluated statistically. It was found that the deposited metal fluxes were significantly correlated in wet deposition with the highest correlation between Cd and Pb in the soluble and total forms. Comparatively smaller correlations were found between these metal fluxes in dry deposition samples. Results of this study showed the importance of metal pollution, especially ecotoxic properties of heavy metals in wet deposition far more than dry deposition.

  20. Systematic Study on Triaxial Superdeformed Bands of Hf Isotopes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Da-Li; DING Bin-Gang

    2009-01-01

    Properties of the triaxial superdeformed (TSD) bands of Hf isotopes are investigated systematically within the supersymmetry scheme including many-body interactions and a perturbation possessing the SO(5) (or SU(5)) symmetry on the rotational symmetry. Quantitatively good results of the γ-ray energies, the dynamical moments of inertia,and the spin of the TSD bands in Hf isotopes are obtained. It shows that this approach is quite powerful in describing the properties of the triaxial superdeformation in Hf isotopes.

  1. Determining Energy Distributions of HF-Accelerated Electrons at HAARP

    Science.gov (United States)

    2015-11-18

    AFRL-AFOSR-VA-TR-2015-0383 Determining energy distributions of HF-accelerated electrons at HAARP Christopher Fallen University of Alaska Fairbanks...2012 - 11/14/2015 4. TITLE AND SUBTITLE Determining energy distributions of HF-accelerated electrons at HAARP 5a. CONTRACT NUMBER FA9550-12-1-0424...transmitted from the High-frequency Active Auroral Research Program ( HAARP ) transmitter in Alaska. For a given fixed HF-plasma interaction altitude

  2. Physics of the Geospace Response to Powerful HF Radio Waves

    Science.gov (United States)

    2012-10-31

    studies of the response of the Earth’s space plasma to high-power HF radio waves from the High-frequency Active Auroral Research Program ( HAARP ...of HF heating and explored to simulate artificial ducts. DMSP- HAARP experiments revealed that HF-created ion outflows and artificial density ducts...in the topside ionosphere appeared faster than predicted by the models, pointing to kinetic (suprathermal) effects. CHAMP/GRACE- HAARP experiments

  3. PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKAN MIXER SETTLER

    Directory of Open Access Journals (Sweden)

    Dwi Biyantoro

    2017-01-01

    Full Text Available ABSTRAK PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKANMIXER SETTLER. Telah dilakukan pemisahanZr – Hf secara sinambung menggunakan pengaduk pengenap (mixer settler 16 stage. Larutan umpan adalah zirkon nitrat dengan kadar Zr = 30786 ppm dan Hf = 499 ppm. Ekstraktan dipakai adalah solven 60 % TBP dalam kerosen dan larutan scrubbingyang dipakai adalah asam nitrat 1 M. Umpan masuk pada stageke 5 dikontakkan secara berlawanan arah dengan solven masuk pada stage ke 16 dan larutan scrubbing masuk pada stage ke 1. Tujuan penelitian ini adalah memisahkan unsur Zr dan Hf dari hasil olah pasir zirkon menggunakan solven TBP dengan alat mixer settler16 stage. Analisis umpan dan hasil proses pemisahan untuk zirkonium (Zr dilakukan dengan menggunakan alat pendar sinar-X, sedangkananalisis unsur hafnium (Hf menggunakan Analisis Pengaktifan Neutron (APN. Parameter penelitian dilakukan dengan variasi keasaman asam nitrat dalam umpan dan variasi waktu pada berbagai laju pengadukan. Hasil penelitian pemisahan unsur Zr dengan Hf diperolehkondisi optimum pada keasaman umpan 4 N HNO3, keseimbangan dicapai setelah 3jam dan laju pengadukan 3300 rpm. Hasil ekstrak  unsur zirkon (Zr diperoleh kadar sebesar 28577 ppm dengan efisiensi 92,76 % serta kadar pengotor hafnium (Hf sebesar 95 ppm. Kata Kunci: pemisahan Zr, Hf, ekstraksi, mixer settler, alat pendar sinar-X, APN. ABSTRACT SEPARATION of Zr - Hf CONTINUOUSLY USE THE MIXER SETTLER. Separation of Zr - Hf continuously using mixer settler 16 stage has been done. The feed solution is zircon nitrate concentration of Zr = 30786 ppm  and Hf = 499 ppm. As the solvent used extractant 60 % TBP in 40 % kerosene. Nitric acid solution used srubbing 1 M. The feed entered into stage to 5 is contacted with solvents direction on the stage to 16 and the scrubbing solution enter the stage to 1. The purpose of this study is to separate Zr and Hf of the results from the process of zircon sand using solvent TBP using 16 stage

  4. Mitigating Doppler shift effect in HF multitone data modem

    Science.gov (United States)

    Sonlu, Yasar

    1989-09-01

    Digital communications over High Frequency (HF) radio channels are getting important in recent years. Current HF requirements are for data transmission at rates 2.4 kbps or more to accommodate computer data links and digital secure voice. HF modems which were produced to meet these speeds are, serial modems and parallel modems. On the other hand, the HF sky-wave communication medium, the ionosphere, has some propagation problems such as multipath and Doppler shift. The effect of Doppler shift in a parallel modem which employs Differential Quadrature Phase Shift Keying (DQPSK) modulation is considered and a correction method to mitigate the Doppler Shift effect is introduced.

  5. Epitaxial Thin Films of Y doped HfO2

    Science.gov (United States)

    Serrao, Claudy; Khan, Asif; Ramamoorthy, Ramesh; Salahuddin, Sayeef

    Hafnium oxide (HfO2) is one of a few metal oxides that is thermodynamically stable on silicon and silicon oxide. There has been renewed interest in HfO2 due to the recent discovery of ferroelectricity and antiferroelectricity in doped HfO2. Typical ferroelectrics - such as strontium bismuth tantalate (SBT) and lead zirconium titanate (PZT) - contain elements that easily react with silicon and silicon oxide at elevated temperatures; therefore, such ferroelectrics are not suited for device applications. Meanwhile, ferroelectric HfO2 offers promise regarding integration with silicon. The stable phase of HfO2 at room temperature is monoclinic, but HfO2 can be stabilized in the tetragonal, orthorhombic or even cubic phase by suitable doping. We stabilized Y-doped HfO2 thin films using pulsed laser deposition. The strain state can be controlled using various perovskite substrates and controlled growth conditions. We report on Y-doped HfO2 domain structures from piezo-response force microscopy (PFM) and structural parameters via X-ray reciprocal space maps (RSM). We hope this work spurs further interest in strain-tuned ferroelectricity in doped HfO2.

  6. Microstructural characterization of as-cast hf-b alloys

    Directory of Open Access Journals (Sweden)

    João Carlos Jânio Gigolotti

    2012-04-01

    Full Text Available An accurate knowledge of several metal-boron phase diagrams is important to evaluation of higher order systems such as metal-silicon-boron ternaries. The refinement and reassessment of phase diagram data is a continuous work, thus the reevaluation of metal-boron systems provides the possibility to confirm previous data from an investigation using higher purity materials and better analytical techniques. This work presents results of rigorous microstructural characterization of as-cast hafnium-boron alloys which are significant to assess the liquid composition associated to most of the invariant reactions of this system. Alloys were prepared by arc melting high purity hafnium (minimum 99.8% and boron (minimum 99.5% slices under argon atmosphere in water-cooled copper crucible with non consumable tungsten electrode and titanium getter. The phases were identified by scanning electron microscopy, using back-scattered electron image mode and X-ray diffraction. In general, a good agreement was found between our data and those from the currently accepted Hafnium-Boron phase diagram. The phases identified are αHfSS and B-RhomSS, the intermediate compounds HfB and HfB2 and the liquide L. The reactions are the eutectic L ⇔ αHfSS + HfB and L ⇔ HfB2 + B-Rhom, the peritectic L + HfB2 ⇔ HfB and the congruent formation of HfB2.

  7. The effect of aluminum additions on the thermal, microstructural, and mechanical behavior of NiTiHf shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Derek Hsen Dai [Department of Materials Science and Engineering, University of Florida, 152 Rhines Hall, P.O. Box 116400, Gainesville, FL 32611 (United States); Hornbuckle, Billy Chad [Department of Metallurgical and Materials Engineering, The University of Alabama, Tuscaloosa, AL 35487 (United States); Valderrama, Billy; Barrie, Fatmata; Henderson, Hunter B. [Department of Materials Science and Engineering, University of Florida, 152 Rhines Hall, P.O. Box 116400, Gainesville, FL 32611 (United States); Thompson, Gregory B. [Department of Metallurgical and Materials Engineering, The University of Alabama, Tuscaloosa, AL 35487 (United States); Manuel, Michele V., E-mail: mmanuel@mse.ufl.edu [Department of Materials Science and Engineering, University of Florida, 152 Rhines Hall, P.O. Box 116400, Gainesville, FL 32611 (United States)

    2015-07-25

    Highlights: • We investigate the effect of aluminum on the thermomechanical properties of NiTiHf alloys. • The nanoscale structure of the alloys are investigated by advanced analytical techniques. • The Al solubility limit in NiTiHf was near 3 at.%. • Precipitation of both Heusler and Han phases are identified. • Al additions significantly affect transformation temperatures. - Abstract: Ni{sub 50}Ti{sub 30−X}Hf{sub 20}Al{sub X} (X = 0, 1, 2, 3, 4, 5 at.%) alloys were investigated using thermal, microstructural, and mechanical analysis. It was found that Al additions to this system decreased the transformation temperatures and thermal cyclic stability of the quaternary alloys. Also, the lenticular Han phase was observed in the aged 3–5% Al alloys in accordance with previous studies in literature performed at a similar aging temperature. Though no transformation was detected after DSC cycling down to −60 °C for the aged 4% and 5% Al alloys, mechanical testing confirmed pseudoelasticity. Additionally, TEM and atom probe analysis confirmed that aging at 600 °C resulted in precipitation of the Ni{sub 2}TiAl Heusler phase and determined the Al solubility limit in the matrix as near 3 at.%. Lastly, precipitation strengthening by the Heusler phase was observed when comparing the solution-treated and aged 4% and 5% Al alloys. Microstructural evolution was further characterized using XRD, SEM and compression testing.

  8. A DFT study of temperature dependent dissociation mechanism of HF in HF(H2O)7 cluster

    Indian Academy of Sciences (India)

    Swatantra K Yadav; Hirdyesh Mishra; Ashwani K Tiwari

    2015-10-01

    We report a Density Functional Theoretical (DFT) study of dissociation of Hydrogen Fluoride (HF) in HF(H2O)7 cluster, using B3LYP functional and empirical exchange correlation functional M06-2X along with 6-31+G(d,p) basis set. Dissociation constant, KRP, of HF dissociation and pKa values of HF in cluster at various temperatures have been reported. It has been found that both KRP and pKa are highly dependent on temperature. The variation of pKa with temperature suggests that HF is strong acid at lower temperatures. Our study also reveals that HF is a stronger acid in water cluster than in bulk water. Further, the results obtained by DFT calculations have been compared with the earlier reported results obtained from Monte Carlo (MC) simulation. It is found that DFT results are qualitatively consistent with the results of MC simulation but quantitatively different.

  9. Hf-W chronometry of primitive achondrites

    Science.gov (United States)

    Schulz, T.; Münker, C.; Mezger, K.; Palme, H.

    2010-03-01

    Metal segregation and silicate melting on asteroids are the most incisive differentiation events in the early evolution of planetary bodies. The timing of these events can be constrained using the short-lived 182Hf- 182W radionuclide system. Here we present new 182Hf- 182W data for major types of primitive achondrites including acapulcoites, winonaites and one lodranite. These meteorites are of particular interest because they show only limited evidence for partial melting of silicates and are therefore intermediate between chondrites and achondrites. For acapulcoites we derived a 182Hf- 182W age of Δ tCAI = 4.1 +1.2/ -1.1 Ma. A model age for winonaite separates calculated from the intercept of the isochron defines an age of Δ tCAI = 4.8 +3.1/ -2.6 Ma (assuming a bulk Hf/W ratio of ˜1.2). Both ages most likely define primary magmatic events on the respective parent bodies, such as melting of metal, although metal stayed in place and did not segregate to form a core. A later thermal event is responsible for resetting of the winonaite isochron, yielding an age of Δ tCAI = 14.3 +2.7/ -2.2 Ma, significantly younger than the model age. Assuming a co-genetic relationship between winonaites and silicates present in IAB iron meteorites (based on oxygen isotope composition) and including data by Schulz et al. (2009), a common parent body chronology can be established. Magmatic activity occurred between ˜1.5 and 5 Ma after CAIs. More than 5 Ma later, intensive thermal metamorphism has redistributed Hf-W. Average cooling rates calculated for the winonaite/IAB parent asteroid range between ˜35 and ˜4 K/Ma, most likely reflecting different burial depths. Cooling rates obtained for acapulcoites were ˜40 K/Ma to ˜720 K and then ˜3 K/Ma to ˜550 K. Accretion and subsequent magmatism on the acapulcoite parent body occurred slightly later if compared to most achondrite parent bodies (e.g., angrites, ureilites and eucrites), in this case supporting the concept of an inverse

  10. Pressure induced novel compounds in the Hf-O system from first-principles calculations

    OpenAIRE

    2015-01-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2, Hf3O2, HfO and HfO3 are discovered to be thermodynamically stable at certain pressure ranges and a new stable high-pressure phase is found for Hf2O with space group Pnnm and anti-CaCl2-type structure. Both P62m-HfO and P4m2-Hf2O3 show semimetallic character. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide...

  11. Ferroelectricity of nondoped thin HfO2 films in TiN/HfO2/TiN stacks

    Science.gov (United States)

    Nishimura, Tomonori; Xu, Lun; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-08-01

    We report on the impact of TiN interfaces on the ferroelectricity of nondoped HfO2. Ferroelectric properties of nondoped HfO2 in TiN/HfO2/TiN stacks are shown in capacitance-voltage and polarization-voltage characteristics. The Curie temperature is also estimated to be around 500 °C. The ferroelectricity of nondoped HfO2 clearly appears by thinning HfO2 film down to ˜35 nm. We directly revealed in thermal treatments that the ferroelectric HfO2 film on TiN was maintained by covering the top surface of HfO2 with TiN, while it was followed by a phase transition to the paraelectric phase in the case of the open surface of HfO2. Thus, it is concluded that the ferroelectricity in nondoped HfO2 in this study was mainly driven by both of top and bottom TiN interfaces.

  12. Synthesis of Freestanding HfO2 Nanostructures

    Science.gov (United States)

    2011-04-05

    Tang J, Fabbri J, Robinson RD, Zhu Y, Herman IP, Steigerwald ML, Brus LE: Solid-solution nanoparticles:use of a nonhydrolytic sol-gel synthesis to...colloidal HfO2 nanorods. Adv Mater 2007, 19:2608-2612. Page 21 5. Qiu X, Howe JY, Cardoso MB, Polat O, Heller W: Size control of highly ordered HfO2

  13. Parametric excitation of whistler waves by HF heater

    Science.gov (United States)

    Kuo, S. P.; Lee, M. C.

    1989-01-01

    Possible generation of whistler waves by Tromso HF heater is investigated. It is shown that the HF heater wave can parametrically decay into a whistler wave and a Langmuir wave. Since whistler waves may have a broad range of frequency, the simultaneously excited Langmuir waves can have a much broader frequency bandwidth than those excited by the parametric decay instability.

  14. Study of {sup 179}Hf{sup m2} excitation

    Energy Technology Data Exchange (ETDEWEB)

    Vishnevsky, I. N.; Zheltonozhsky, V. A., E-mail: zhelton@kinr.kiev.ua; Savrasov, A. N. [National Academy of Sciences of Ukraine, Institute for Nuclear Research (Ukraine); Mazur, V. M. [National Academy of Sciences of Ukraine, Institute of Electronic Physics (Ukraine)

    2016-12-15

    Isomeric ratios of {sup 179}Hf{sup m2,g} yields in the (γ, n) reaction and the cross section for the {sup 179}Hf{sup m2} population in the (α, p) reaction are measured for the first time at the end-point energies of 15.1 and 17.5 MeV for bremsstrahlung photons and 26 MeV for alpha particles. The results are σ = (1.1 ± 0.11) × 10{sup −27} cm{sup 2} for the {sup 176}Lu(α, p){sup 179}Hf{sup m2} reaction and Y{sub m2}/Y{sub g} = (6.1 ± 0.3) × 10{sup −6} and (3.7 ± 0.2) × 10{sup −6} for the {sup 180}Hf(γ, n){sup 179}Hf{sup m22} reaction at E{sub ep} =15.1 and 17.5 MeV, respectively. The experimental data on the relative {sup 179}Hf{sup m2} yield indicate a single-humped shape of the excitation function for the {sup 180}Hf(γ, n){sup 179}Hf{sup m2} reaction. Simulation is performed using the TALYS-1.4 and EMPIRE-3.2 codes.

  15. Diffusion of Hf and Nb in Zr-19%Nb

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [CANMET, Ottawa, Ont. (Canada). Met. Sci. and Technol.

    1996-05-01

    Diffusion of Hf and Nb in large-grained bcc Zr-19%Nb has been studied. Diffusion coefficients of Hf, D(Hf), were measured in the range 620-1173 K and D(Nb) was measured at 920 and 1167 K. The Hf diffusion profiles were determined by SIMS and the Nb profiles by microtome sectioning and radio-tracer counting. The Hf data show a smooth, temperature-dependent behaviour through the monotectoid temperature, 875 K, and may be characterised by D{approx}10{sup -9}.exp-1.4 (eV/kT) m{sup 2}/s. D(Nb) tends to be lower than the corresponding values for D(Hf). Overall, diffusion of Hf and Nb are characteristic of diffusion in bcc Zr. Surface hold-up (oxide film) at low temperatures was overcome by using ion-implanted Hf diffusion sources. The results are compared with earlier work and discussed in terms of diffusion mechanisms and the {beta}-phase transformation of commercial Zr-2.5Nb. (orig.).

  16. Oxygen Recovery in Hf Oxide Films Fabricated by Sputtering

    Institute of Scientific and Technical Information of China (English)

    JIANG Ran; LI Zi-Feng

    2009-01-01

    The chemical structure of ultrathin Hf oxide films (< 10 nm) fabricated by a standard sputtering method is investigated using x-ray spectroscopy and Rutherford backscattering spectroscopy. According to the experiments,oxygen species are impacted to the HfO2/Si interface during the initial sputtering, and then released back to the upper Hf02 region driven by the oxygen concentration grads. A vacuum annealing can greatly enhance this recovery process. Additionally, significant SiO2 reduction in the interface is observed after the vacuum annealing for the thick HfO2 films in our experiment. It might be an effective method to confine the interracial layer thickness by sputtering thick HfO2 in no-oxygen ambient.

  17. Crystal structure of Si-doped HfO2

    Science.gov (United States)

    Zhao, Lili; Nelson, Matthew; Aldridge, Henry; Iamsasri, Thanakorn; Fancher, Chris M.; Forrester, Jennifer S.; Nishida, Toshikazu; Moghaddam, Saeed; Jones, Jacob L.

    2014-01-01

    Si-doped HfO2 was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO2 was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO2) rather than HfSiO4, the latter of which would be expected from existing SiO2-HfO2 phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO2 shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  18. The (178m2)Hf Controversy

    Energy Technology Data Exchange (ETDEWEB)

    Becker, J A; Gemmell, D S; Schiffer, J P; Wilhelmy, J B

    2003-07-24

    Since its discovery in the 1960's the {sup 178m2}Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range {approx}10 to {approx}60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was {approx}7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method for triggering the isomeric deexcitation immediately suggested applications utilizing the explosive or the controlled gradual energy release from a very compact source. The prospect of such applications has focused considerable interest on realizing the promise that is implicit in the reported observations. However, two experiments performed by a group from ANL/LANL/LLNL at the Advanced Photon Source at Argonne (the ''APS collaboration'') reported negative results for the observation of any photon-triggered deexcitation of the {sup 178m2}Hf isomer [3]. This has led to a continued controversy, where both sides have adamantly defended their observations. At this point an outsider has difficulty determining whether there is indeed a triggering effect that should be pursued energetically with substantial resources, or whether the phenomenon consists of overly optimistic interpretation of data.

  19. Cytokine soluble receptors in perinatal and early neonatal life

    Directory of Open Access Journals (Sweden)

    Efthimia Protonotariou

    2003-01-01

    Full Text Available Background: In contrast to cellular receptors, soluble receptors do not enhance the cellular activation because they do not have transmembranic and cytoplasmic parts, acting thereby as endogenous regulatory mechanisms against systemic functions of cytokines.

  20. 3 and 4 oxidation state element solubilities in borosilicate glasses. Implement to actinides in nuclear glasses; Solubilite des elements aux degres d'oxydation (3) et (4) dans les verres de borosilicate. Application aux actinides dans les verres nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Cachia, J.N

    2005-12-15

    In order to ensure optimal radionuclides containment, the knowledge of the actinide loading limits in nuclear waste glasses and also the comprehension of the solubilization mechanisms of these elements are essential. A first part of this manuscript deals with the study of the differences in solubility of the tri and tetravalent elements (actinides and surrogates) particularly in function of the melting temperature. The results obtained indicate that trivalent elements (La, Gd, Nd, Am, Cm) exhibit a higher solubility than tetravalent elements (Hf, Th, Pu). Consequently, it was planned to reduce plutonium at the oxidation state (III), the later being essentially tetravalent in borosilicate glasses. An innovating reduction process of multi-valent elements (cerium, plutonium) using silicon nitride has been developed in a second part of this work. Reduced plutonium-bearing glasses synthesized by Si{sub 3}N{sub 4} addition made it possible to double the plutonium solubility from 2 to 4 wt% at 1200 deg C. A structural approach to investigate the differences between tri and tetravalent elements was finally undertaken. These investigations were carried out by X-rays Absorption Spectroscopy (EXAFS) and NMR. Trivalent rare earth and actinide elements seem to behave as network modifiers while tetravalent elements rather present true intermediaries' behaviour. (author)

  1. Uranyl Oxalate Solubility

    Energy Technology Data Exchange (ETDEWEB)

    Leturcq, G.; Costenoble, S.; Grandjean, S. [CEA Marcoule DEN/DRCP/SCPS/LCA - BP17171 - 30207 Bagnols sur Ceze cedex (France)

    2008-07-01

    The solubility of uranyl oxalate was determined at ambient temperature by precipitation in oxalic-nitric solutions, using an initial uranyl concentration of 0.1 mol/L. Oxalic concentration varied from 0.075 to 0.3 mol/L while nitric concentration ranged between 0.75 and 3 mol/L. Dissolution tests, using complementary oxalic-nitric media, were carried out for 550 hours in order to study the kinetic to reach thermodynamic equilibrium. Similar solubility values were reached by dissolution and precipitation. Using the results, it was possible to draw the solubility surface versus oxalic and nitric concentrations and to determine both the apparent solubility constant of UO{sub 2}C{sub 2}O{sub 4}, 3H{sub 2}O (Ks) and the apparent formation constant of the first uranyl-oxalate complex UO{sub 2}C{sub 2}O{sub 4} (log {beta}1), for ionic strengths varying between 1 and 3 mol/L. Ks and log {beta}1 values were found to vary from 1.9 10{sup -8} to 9.2 10{sup -9} and from 5.95 to 6.06, respectively, when ionic strength varied from 1 to 3 mol/L. A second model may fit our data obtained at an ionic strength of 3 mol/L suggesting as reported by Moskvin et al. (1959) that no complexes are formed for [H{sup +}] at 3 M. The Ks value would then be 1.3 10{sup -8}. (authors)

  2. Microscopic views of drug solubility

    OpenAIRE

    Bondesson, Laban

    2006-01-01

    The development of computational models for predicting drug solubility has increased drastically during the last decades. Nevertheless these models still have diffculties to estimate the aqueous solubility as accurate as desired. In this thesis di erent aspects that are known to have a large impact on the aqueous solubility of a molecule have been studied in detail using various theoretical methods with intension to provide microscopic view on drug solubility. The rst aspect studied is the hy...

  3. Ferroelectricity-modulated resistive switching in Pt/Si:HfO2/HfO2-x /Pt memory

    Science.gov (United States)

    Ran, Jiang; Xianghao, Du; Zuyin, Han

    2016-08-01

    It is investigated for the effect of a ferroelectric Si:HfO2 thin film on the resistive switching in a stacked Pt/Si:HfO2/highly-oxygen-deficient HfO2-x /Pt structure. Improved resistance performance was observed. It was concluded that the observed resistive switching behavior was related to the modulation of the width and height of a depletion barrier in the HfO2-x layer, which was caused by the Si:HfO2 ferroelectric polarization field effect. Reliable switching reproducibility and long data retention were observed in these memory cells, suggesting their great potential in non-volatile memories applications with full compatibility and simplicity. Project supported by the National Natural Science Foundation of China (No. 11374182), the Natural Science Foundation of Shandong Province (No. ZR2012FQ012), and the Jinan Independent Innovation Projects of Universities (No. 201303019).

  4. Solubility studies of inorganic–organic hybrid nanoparticle photoresists with different surface functional groups

    KAUST Repository

    Li, Li

    2016-01-01

    © 2016 The Royal Society of Chemistry. The solubility behavior of Hf and Zr based hybrid nanoparticles with different surface ligands in different concentrations of photoacid generator as potential EUV photoresists was investigated in detail. The nanoparticles regardless of core or ligand chemistry have a hydrodynamic diameter of 2-3 nm and a very narrow size distribution in organic solvents. The Hansen solubility parameters for nanoparticles functionalized with IBA and 2MBA have the highest contribution from the dispersion interaction than those with tDMA and MAA, which show more polar character. The nanoparticles functionalized with unsaturated surface ligands showed more apparent solubility changes after exposure to DUV than those with saturated ones. The solubility differences after exposure are more pronounced for films containing a higher amount of photoacid generator. The work reported here provides material selection criteria and processing strategies for the design of high performance EUV photoresists.

  5. IUPAC-NIST Solubility Data Series. 90. Hydroxybenzoic Acid Derivatives in Binary, Ternary, and Multicomponent Systems. Part I. Hydroxybenzoic Acids, Hydroxybenzoates, and Hydroxybenzoic Acid Salts in Water and Aqueous Systems

    Science.gov (United States)

    Goto, Rensuke; Fukuda, Hiroshi; Königsberger, Erich; Königsberger, Lan-Chi

    2011-03-01

    The solubility data for well-defined binary, ternary, and multicomponent systems of solid-liquid type are reviewed. One component, which is 2-, 3-, and 4-hydroxybenzoic acids, 4-hydroxybenzoate alkyl esters (parabens), or hydroxybenzoic acid salts, is in the solid state at room temperature and another component is liquid water, meaning that all of the systems are aqueous solutions. The ternary or multicomponent systems include organic substances of various classes (hydrocarbons of several structural types, halogenated hydrocarbons, alcohols, acids, ethers, esters, amides, and surfactants) or inorganic substances. Systems reported in the primary literature from 1898 through 2000 are compiled. For seven systems, sufficient binary data for hydroxybenzoic acids or parabens in water are available to allow critical evaluation. Almost all data are expressed as mass and mole fractions as well as the originally reported units, while some data are expressed as molar concentration.

  6. Thermoelectric properties of monolayer MSe2 (M = Zr, Hf): low lattice thermal conductivity and a promising figure of merit

    Science.gov (United States)

    Ding, Guangqian; Gao, G. Y.; Huang, Zhishuo; Zhang, Wenxu; Yao, Kailun

    2016-09-01

    Monolayer transition-metal dichalcogenides (TMDCs) MX2 (M = Mo, W, Zr, Hf, etc; X = S, Se, Te) have become well-known in recent times for their promising applications in thermoelectrics and field effect transistors. In this work, we perform a systematic study on the thermoelectric properties of monolayer ZrSe2 and HfSe2 using first-principles calculations combined with Boltzmann transport equations. Our results point to a competitive thermoelectric figure of merit (close to 1 at optimal doping) in both monolayer ZrSe2 and HfSe2, which is markedly higher than previous explored monolayer TMDCs such as MoS2 and MoSe2. We also reveal that the higher figure of merits arise mainly from their low lattice thermal conductivity, and this is partly due to the strong coupling of acoustic modes with low frequency optical modes. It is found that the figure of merits can be better optimized in n-type than in p-type. In particular, the performance of HfSe2 is superior to ZrSe2 at a higher temperature. Our results suggest that monolayer ZrSe2 and HfSe2 with lower lattice thermal conductivity than usual monolayer TMDCs are promising candidates for thermoelectric applications.

  7. Sr, Nd, Pb and Hf isotopic constraints on mantle sources and crustal contaminants in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina; Holm, Paul Martin; Thirlwall, Matthew F.

    2015-01-01

    The presented Sr, Nd, Hf and double-spike Pb-isotopic analyses of Quaternary basalts from the Payenia volcanic province in southern Mendoza, Argentina, confirm the presence of two distinct mantle types feeding the Payenia volcanism. The southern Payenia mantle source feeding the intraplate-type Río...... is suggested to be caused by step-wise melt extraction due to repeated injections of subduction zone fluids and melts. The lower crustal contamination trends found in the trace element variations of basalt groups from all parts of the Payenia province are also recognized in isotopic space and the dominant...... isotope assimilation trends indicate lower crustal contaminants with more unradiogenic Pb, lower 143Nd/144Nd and 176Hf/177Hf and higher or similar 87Sr/86Sr as the mantle melts. These characteristics are similar to those found in lower crustal xenoliths from the northern Proterozoic Cuyania terrane...

  8. A small shoulder of optical absorption in polycrystalline HfO2 by LDA+U approach

    Science.gov (United States)

    Qin, Liyuan; Li, Jinping; Meng, Songhe; Lu, Hantao; Tohyama, Takami

    2016-10-01

    The dielectric function of the wide-gap optical material HfO2 is investigated by the local density approximation (LDA)+U approach. We focus on the origin of the shoulder-like structure near the edge of the band gap in the imaginary part of the dielectric function, which has been observed on the thin films of monoclinic HfO2. A comparison study on the three polymorphs of hafnia shows that regardless of the underlying crystal structure, the existence of the shoulder is mainly controlled by the value of the shortest length of Hf-O bonds. The proposition is further supported by the numerical simulations of isostatic pressing. A possible implication in high-pressure measurements is suggested accordingly.

  9. First-principles phase diagram calculations for the rocksalt-structure quasibinary systems TiN-ZrN, TiN-HfN and ZrN-HfN

    Science.gov (United States)

    Liu, Z. T. Y.; Burton, B. P.; Khare, S. V.; Gall, D.

    2017-01-01

    We have studied the phase equilibria of three ceramic quasibinary systems Ti1-x Zr x N, Ti1-x Hf x N and Zr1-x Hf x N (0  ⩽  x  ⩽  1) with density functional theory, cluster expansion and Monte Carlo simulations. We predict consolute temperatures (T C), at which miscibility gaps close, for Ti1-x Zr x N to be 1400 K, for Ti1-x Hf x N to be 700 K, and below 200 K for Zr1-x Hf x N. The asymmetry of the formation energy ΔE f(x) is greater for Ti1-x Hf x N than Ti1-x Zr x N, with less solubility on the smaller cation TiN-side, and similar asymmetries were predicted for the corresponding phase diagrams. We also analyzed different energetic contributions: ΔE f of the random solid solutions were decomposed into a volume change term, Δ {{E}\\text{vc}} , and a chemical exchange and relaxation term, Δ {{E}\\text{xc\\text{-rlx}}} . These two energies partially cancel one another. We conclude that Δ {{E}\\text{vc}} influences the magnitude of T C and Δ {{E}\\text{xc\\text{-rlx}}} influences the asymmetry of ΔE f(x) and phase boundaries. We also conclude that the absence of experimentally observed phase separation in Ti1-x Zr x N and Ti1-x Hf x N is due to slow kinetics at low temperatures. In addition, elastic constants and mechanical properties of the random solid solutions were studied with the special quasirandom solution approach. Monotonic trends, in the composition dependence, of shear-related mechanical properties, such as Vickers hardness between 18 to 23 GPa, were predicted. Trends for Ti1-x Zr x N and Ti1-x Hf x N exhibit down-bowing (convexity). It shows that mixing nitrides of same group transition metals does not lead to hardness increase from an electronic origin, but through solution hardening mechanism. The mixed thin films show consistency and stability with little phase separation, making them desirable coating choices.

  10. Solubility studies of inorganic-organic hybrid nanoparticle photoresists with different surface functional groups

    Science.gov (United States)

    Li, Li; Chakrabarty, Souvik; Jiang, Jing; Zhang, Ben; Ober, Christopher; Giannelis, Emmanuel P.

    2016-01-01

    The solubility behavior of Hf and Zr based hybrid nanoparticles with different surface ligands in different concentrations of photoacid generator as potential EUV photoresists was investigated in detail. The nanoparticles regardless of core or ligand chemistry have a hydrodynamic diameter of 2-3 nm and a very narrow size distribution in organic solvents. The Hansen solubility parameters for nanoparticles functionalized with IBA and 2MBA have the highest contribution from the dispersion interaction than those with tDMA and MAA, which show more polar character. The nanoparticles functionalized with unsaturated surface ligands showed more apparent solubility changes after exposure to DUV than those with saturated ones. The solubility differences after exposure are more pronounced for films containing a higher amount of photoacid generator. The work reported here provides material selection criteria and processing strategies for the design of high performance EUV photoresists.The solubility behavior of Hf and Zr based hybrid nanoparticles with different surface ligands in different concentrations of photoacid generator as potential EUV photoresists was investigated in detail. The nanoparticles regardless of core or ligand chemistry have a hydrodynamic diameter of 2-3 nm and a very narrow size distribution in organic solvents. The Hansen solubility parameters for nanoparticles functionalized with IBA and 2MBA have the highest contribution from the dispersion interaction than those with tDMA and MAA, which show more polar character. The nanoparticles functionalized with unsaturated surface ligands showed more apparent solubility changes after exposure to DUV than those with saturated ones. The solubility differences after exposure are more pronounced for films containing a higher amount of photoacid generator. The work reported here provides material selection criteria and processing strategies for the design of high performance EUV photoresists. Electronic supplementary

  11. Power-Stepped HF Cross Modulation Experiments at HAARP

    Science.gov (United States)

    Greene, S.; Moore, R. C.; Langston, J. S.

    2013-12-01

    High frequency (HF) cross modulation experiments are a well established means for probing the HF-modified characteristics of the D-region ionosphere. In this paper, we apply experimental observations of HF cross-modulation to the related problem of ELF/VLF wave generation. HF cross-modulation measurements are used to evaluate the efficiency of ionospheric conductivity modulation during power-stepped modulated HF heating experiments. The results are compared to previously published dependencies of ELF/VLF wave amplitude on HF peak power. The experiments were performed during the March 2013 campaign at the High Frequency Active Auroral Research Program (HAARP) Observatory. HAARP was operated in a dual-beam transmission format: the first beam heated the ionosphere using sinusoidal amplitude modulation while the second beam broadcast a series of low-power probe pulses. The peak power of the modulating beam was incremented in 1-dB steps. We compare the minimum and maximum cross-modulation effect and the amplitude of the resulting cross-modulation waveform to the expected power-law dependence of ELF/VLF wave amplitude on HF power.

  12. Investigating a TELEmedicine solution to improve MEDication adherence in chronic Heart Failure (TELEMED-HF: study protocol for a randomized controlled trial

    Directory of Open Access Journals (Sweden)

    Widdershoven Jos

    2011-10-01

    Full Text Available Abstract Background Frequent rehospitalisations and poorer survival chances in heart failure (HF patients may partly be explained by poor medication adherence. There are multiple medication-related reasons for suboptimal adherence, but psychological reasons may also be important. A novel TELEmonitoring device may improve MEDication adherence in HF patients (TELEMED-HF. TELEMED-HF is a randomized, controlled clinical intervention trial designed to examine (1 the efficacy and cost-efficiency of an electronic medication adherence support system in improving and monitoring HF patients' medication adherence; (2 the effect of medication adherence on hospitalizations and health care consumption; as well as on (3 clinical characteristics, and Quality of Life (QoL; and (4 clinical, sociodemographic, and psychological determinants of medication adherence. Methods/Design Consecutive patients with chronic, systolic HF presenting to the outpatient clinic of the TweeSteden Hospital, The Netherlands, will be approached for study participation and randomly assigned (1:1 following blocked randomization procedures to the intervention (n = 200 or usual care arm (n = 200. Patients in the intervention arm use the medication support device for six months in addition to usual care. Post-intervention, patients return to usual care only and all patients participate in four follow-up occasions over 12 months. Primary endpoints comprise objective and subjective medication adherence, healthcare consumption, number of hospitalizations, and cost-effectiveness. Secondary endpoints include disease severity, physical functioning, and QoL. Discussion The TELEMED-HF study will provide us a comprehensive understanding of medication adherence in HF patients, and will show whether telemonitoring is effective and cost-efficient in improving adherence and preventing hospitalization in HF patients. Trial registration number NCT01347528.

  13. Mechanistic Insight into the Stability of HfO2-Coated MoS2 Nanosheet Anodes for Sodium Ion Batteries

    KAUST Repository

    Ahmed, Bilal

    2015-06-01

    It is demonstrated for the first time that surface passivation of 2D nanosheets of MoS2 by an ultrathin and uniform layer of HfO2 can significantly improve the cyclic performance of sodium ion batteries. After 50 charge/discharge cycles, bare MoS2 and HfO2 coated MoS2 electrodes deliver the specific capacity of 435 and 636 mAh g-1, respectively, at current density of 100 mA g-1. These results imply that batteries using HfO2 coated MoS2 anodes retain 91% of the initial capacity; in contrast, bare MoS2 anodes retain only 63%. Also, HfO2 coated MoS2 anodes show one of the highest reported capacity values for MoS2. Cyclic voltammetry and X-ray photoelectron spectroscopy results suggest that HfO2 does not take part in electrochemical reaction. The mechanism of capacity retention with HfO2 coating is explained by ex situ transmission electron microscope imaging and electrical impedance spectroscopy. It is illustrated that HfO2 acts as a passivation layer at the anode/electrolyte interface and prevents structural degradation during charge/discharge process. Moreover, the amorphous nature of HfO2 allows facile diffusion of Na ions. These results clearly show the potential of HfO2 coated MoS2 anodes, which performance is significantly higher than previous reports where bulk MoS2 or composites of MoS2 with carbonaceous materials are used. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. HF dissociation in water clusters by computer simulations

    OpenAIRE

    Elena, Alin Marin

    2013-01-01

    We perform Restrained hybrid Monte Carlo simulations to compute the equilibrium constant of the dissociation reaction of HF in HF(H2O)7. We find that, like in the bulk, hydrofluoric acid, is a weak acid also in the cubic HF(H2O)7 cluster, and that its acidity is higher at lower T. This latter phenomenon has a (vibrational) entropic origin, namely it is due to the reduction of the (negative) T∆S contribution to the variation of free energy between the reactant and product. We found also ...

  15. Soluble porphyrin polymers

    Science.gov (United States)

    Gust, Jr., John Devens; Liddell, Paul Anthony

    2015-07-07

    Porphyrin polymers of Structure 1, where n is an integer (e.g., 1, 2, 3, 4, 5, or greater) ##STR00001## are synthesized by the method shown in FIGS. 2A and 2B. The porphyrin polymers of Structure 1 are soluble in organic solvents such as 2-MeTHF and the like, and can be synthesized in bulk (i.e., in processes other than electropolymerization). These porphyrin polymers have long excited state lifetimes, making the material suitable as an organic semiconductor for organic electronic devices including transistors and memories, as well as solar cells, sensors, light-emitting devices, and other opto-electronic devices.

  16. Ionospheric heating with oblique HF waves

    Science.gov (United States)

    Field, Edward C., Jr.; Bloom, Ron M.

    1990-10-01

    Calculations of ionospheric electron density perturbations and ground-level signal changes produce by intense oblique high frequency (HF) transmitters are presented. This analysis considers radio field focusing at caustics, the consequent joule-heating of the surrounding plasma, heat conduction, diffusion, and recombination processes: these being the effects of a powerful oblique 'modifying' wave. It neglects whatever plasma instabilities might occur. Then effects on a secondary 'test' wave that is propagated along the same path as the first are investigated. Calculations predict ground-level field-strength reductions of several dB in the test wave for modifying waves having ERP in the 85 to 90 dBW range. These field-strength changes are similar in sign, magnitude, and location to ones measured in Soviet experiments. The results are sensitive to the model ionosphere assumed, so future experiments should employ the widest possible range of frequencies and propagation conditions. An effective power of 90 dBW seems to be a sort of threshold that, if exceeded, results in substantial rather than small signal changes. The conclusions are based solely on joule-heating and subsequent defocusing of waves passing through caustic regions.

  17. Process Simulation Analysis of HF Stripping

    Directory of Open Access Journals (Sweden)

    Thaer A. Abdulla

    2013-05-01

    Full Text Available    HYSYS process simulator is used for the analysis of existing HF stripping column in LAB plant (Arab Detergent Company, Baiji-Iraq. Simulated column performance and profiles curves are constructed. The variables considered are the thermodynamic model option, bottom temperature, feed temperature, and column profiles for the temperature, vapor flow rate, liquid flow rate and composition. The five thermodynamic models options used (Margules, UNIQUAC, van laar, Antoine, and Zudkevitch-Joffee, affecting the results within (0.1-58% variation for the most cases.        The simulated results show that about 4% of paraffin (C10 & C11 presents at the top stream, which may cause a problem in the LAB production plant. The major variations were noticed for the total top vapor flow rate with bottom temperature and with feed composition. The column profiles maintain fairly constants from tray 5 to tray 18. The study gives evidence about a successful simulation with HYSYS because the results correspond with the real plant operation data.

  18. The (178m2) Hf Controversy

    CERN Document Server

    Becker, J A; Schiffer, J P; Wilhelmy, J

    2003-01-01

    Since its discovery in the 1960's the sup 1 sup 7 sup 8 sup m sup 2 Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range approx 10 to approx 60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was approx 7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method fo...

  19. Use of the soluble form of AXL in the diagnosis and/or prognosis of heart failure syndrome

    OpenAIRE

    Battle Perales, Montserrat; García de Frutos, Pablo

    2012-01-01

    [EN] The present invention refers to a method for diagnosing and/or prognosing a heart failure syndrome (HF), which comprises the step of measuring, in vitro, the amount of the soluble form of AXL (sAXL) in a test sample. The invention furthermore provides methods for deciding or recommending whether to initiate a medical regimen, as well as for determining the efficacy of said medical regimen. The invention also provides the use of sAXL as a marker for the diagnosis and/or prognosis of HF sA...

  20. Role of Soluble ST2 as a Prognostic Marker in Patients with Acute Heart Failure and Renal Insufficiency.

    Science.gov (United States)

    Kim, Min-Seok; Jeong, Tae-Dong; Han, Seung-Bong; Min, Won-Ki; Kim, Jae-Joong

    2015-05-01

    This study sought to assess the relationship between serum concentrations of the soluble ST2 (sST2) and B-type natriuretic peptide (BNP) and investigate the role of sST2 as a prognosticator in patients hospitalized with acute heart failure (HF) and renal insufficiency. sST2 was measured at admission and discharge in 66 patients hospitalized with acute decompensated HF and renal insufficiency (estimated glomerular filtration rate [eGFR] renal insufficiency (eGFR renal function, even though BNP level was much higher in patients with severe renal insufficiency. During 3 month follow-up, 9 (13.6%) died and 16 (24.2%) were readmitted due to HF aggravation.On multivariate analysis, sST2 at discharge was independently associated with death or HF readmission during 3 months after discharge (hazard ratio, 1.038; 95% confidence interval, 1.011-1.066, P = 0.006). In conclusion, sST2 is not affected by renal function compared with BNP in acute HF patients. The measurement of predischarge sST2 can be helpful in predicting short-term outcomes in acute decompensated HF patients with renal insufficiency.

  1. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    OpenAIRE

    Muto, S.; Stone, N. J.; Bingham, C. R.; STONE, J.R; Walker, P. M.; Audi, G.; Gaulard, C.; Köster, U.(Institut Laue-Langevin (ILL), Grenoble, France); Nikolov, J.; Nishimura,K; Ohtsubo, T.; Podolyak, Z.; Risegari, L.; Simpson, G.S.; Veskovic, M.

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV ...

  2. A thirty second isomer in {sup 171}Hf

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, P.; Billowes, J.; Cooper, T.G.; Grant, I.S.; Pearson, M.R.; Wheeler, P.D. [Schuster Laboratory, University of Manchester, M13 9PL (United Kingdom); Cochrane, E.C.A.; Cooke, J.L.; Evans, D.E.; Griffith, J.A.R.; Persson, J.R.; Richardson, D.S.; Tungate, G.; Zybert, L. [School of Physics and Space Research, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom); Dendooven, P.; Honkanen, A.; Huhta, M.; Oinonen, M.; Penttilae, H.; Aeystoe, J. [Accelerator Laboratory, University of Jyvaeskylae, PL 35 Jyvaeskylae SF-403 51 (Finland)

    1997-09-01

    An isomer has been detected in {sup 171}Hf with a half-life of T{sub 1/2} 29.5(9) s. The state was populated in the {sup 170}Yb({alpha},3n){sup 171m}Hf reaction at a beam energy of E{sub {alpha}} = 50 MeV in an on-line ion guide isotope separator. The isomeric {sup 171m}Hf{sup +} beam was extracted from the ion guide, mass-analysed and implanted in the surface of a microchannel-plate. The half-life of the collected activity was measured from the decay of the microchannel-plate count rate. We associate the isomer with the first excited state in {sup 171}Hf with spin 1/2{sup -} at an excitation energy of 22(2) keV. (author)

  3. HF fiber stuffing in building 186 at CERN

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    Each of the 36 HF wedges comprise ca 12000 quartz fibers which are the active element of the calorimeter. The fibers are produced by Polymicro (USA), cleaved and bundled at KFKI, Budapest, Hungary and inserted at CERN.

  4. Low-Frequency Waves in HF Heating of the Ionosphere

    Science.gov (United States)

    Sharma, A. S.; Eliasson, B.; Milikh, G. M.; Najmi, A.; Papadopoulos, K.; Shao, X.; Vartanyan, A.

    2016-02-01

    Ionospheric heating experiments have enabled an exploration of the ionosphere as a large-scale natural laboratory for the study of many plasma processes. These experiments inject high-frequency (HF) radio waves using high-power transmitters and an array of ground- and space-based diagnostics. This chapter discusses the excitation and propagation of low-frequency waves in HF heating of the ionosphere. The theoretical aspects and the associated models and simulations, and the results from experiments, mostly from the HAARP facility, are presented together to provide a comprehensive interpretation of the relevant plasma processes. The chapter presents the plasma model of the ionosphere for describing the physical processes during HF heating, the numerical code, and the simulations of the excitation of low-frequency waves by HF heating. It then gives the simulations of the high-latitude ionosphere and mid-latitude ionosphere. The chapter also briefly discusses the role of kinetic processes associated with wave generation.

  5. Near-infrared LIF spectroscopy of HfF

    CERN Document Server

    Grau, Matt; Loh, Huanqian; Sinclair, Laura C; Stutz, Russel P; Yahn, Tylser S; Cornell, Eric A

    2012-01-01

    The molecular ion HfF$^+$ is the chosen species for a JILA experiment to measure the electron electric dipole moment (eEDM). Detailed knowledge of the spectrum of HfF is crucial to prepare HfF$^+$ in a state suitable for performing an eEDM measurement\\cite{Leanhardt}. We investigated the near-infrared electronic spectrum of HfF using laser-induced fluorescence (LIF) of a supersonic molecular beam. We discovered eight unreported bands, and assign each of them unambiguously, four to vibrational bands belonging to the transition $[13.8]0.5 \\leftarrow X1.5$, and four to vibrational bands belonging to the transition $[14.2]1.5 \\leftarrow X1.5$. Additionally, we report an improved measurement of vibrational spacing of the ground state, as well as anharmonicity $\\omega_e x_e$.

  6. Theoretical Assessment of 178m2Hf De-Excitation

    Energy Technology Data Exchange (ETDEWEB)

    Hartouni, E P; Chen, M; Descalle, M A; Escher, J E; Loshak, A; Navratil, P; Ormand, W E; Pruet, J; Thompson, I J; Wang, T F

    2008-10-06

    This document contains a comprehensive literature review in support of the theoretical assessment of the {sup 178m2}Hf de-excitation, as well as a rigorous description of controlled energy release from an isomeric nuclear state.

  7. Integrated magnetics design for HF-link power converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the integrated magnetic components do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation...... of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs....

  8. Integrated magnetics design for HF-link power converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, Michael A.E.

    2005-07-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the two integrated magnetic components on the same core do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs. (au)

  9. Surface state of carbon nanotubes and Hansen solubility parameters.

    Science.gov (United States)

    Detriche, S; Nagy, J B; Mekhalif, Z; Delhalle, J

    2009-10-01

    Carbon nanotubes (CNTs) are often described as insoluble or poorly soluble in organic solvents. In a recent study, we have reported that nonfunctionalized CNTs can be solubilized in suitably chosen organic solvents. Furthermore, their solubility could be understood in terms of the Hansen Solubility Parameters (HSPs). The present work addresses further the question of the CNTs solubility by considering a larger range of solvents. A second part is devoted to the application of the HSPs to two types of functionalized CNTs: oxidized and silanized. These results stress the critical role played by the surface state of the CNTs, on the one hand, and the interest in using the HSPs to guide solubility investigations, on the other hand.

  10. Lattice Thermal Conductivity from Atomistic Simulations: ZrB2 and HfB2

    Science.gov (United States)

    Lawson, John W.; Daw, Murray S.; Bauschlicher, Charles W.

    2012-01-01

    Ultra high temperature ceramics (UHTC) including ZrB2 and HfB2 have a number of properties that make them attractive for applications in extreme environments. One such property is their high thermal conductivity. Computational modeling of these materials will facilitate understanding of fundamental mechanisms, elucidate structure-property relationships, and ultimately accelerate the materials design cycle. Progress in computational modeling of UHTCs however has been limited in part due to the absence of suitable interatomic potentials. Recently, we developed Tersoff style parameterizations of such potentials for both ZrB2 and HfB2 appropriate for atomistic simulations. As an application, Green-Kubo molecular dynamics simulations were performed to evaluate the lattice thermal conductivity for single crystals of ZrB2 and HfB2. The atomic mass difference in these binary compounds leads to oscillations in the time correlation function of the heat current, in contrast to the more typical monotonic decay seen in monoatomic materials such as Silicon, for example. Results at room temperature and at elevated temperatures will be reported.

  11. Synthesis of freestanding HfO2 nanostructures

    Directory of Open Access Journals (Sweden)

    Boyle Kayla

    2011-01-01

    Full Text Available Abstract Two new methods for synthesizing nanostructured HfO2 have been developed. The first method entails exposing HfTe2 powders to air. This simple process resulted in the formation of nanometer scale crystallites of HfO2. The second method involved a two-step heating process by which macroscopic, freestanding nanosheets of HfO2 were formed as a byproduct during the synthesis of HfTe2. These highly two-dimensional sheets had side lengths measuring up to several millimeters and were stable enough to be manipulated with tweezers and other instruments. The thickness of the sheets ranged from a few to a few hundred nanometers. The thinnest sheets appeared transparent when viewed in a scanning electron microscope. It was found that the presence of Mn enhanced the formation of HfO2 by exposure to ambient conditions and was necessary for the formation of the large scale nanosheets. These results present new routes to create freestanding nanostructured hafnium dioxide. PACS: 81.07.-b, 61.46.Hk, 68.37.Hk.

  12. The isobutylene-isobutane alkylation process in liquid HF revisited.

    Science.gov (United States)

    Esteves, P M; Araújo, C L; Horta, B A C; Alvarez, L J; Zicovich-Wilson, C M; Ramírez-Solís, A

    2005-07-07

    Details on the mechanism of HF catalyzed isobutylene-isobutane alkylation were investigated. On the basis of available experimental data and high-level quantum chemical calculations, a detailed reaction mechanism is proposed taking into account solvation effects of the medium. On the basis of our computational results, we explain why the density of the liquid media and stirring rates are the most important parameters to achieve maximum yield of alkylate, in agreement with experimental findings. The ab initio Car-Parrinello molecular dynamics calculations show that isobutylene is irreversibly protonated in the liquid HF medium at higher densities, leading to the ion pair formation, which is shown to be a minimum on the potential energy surface after optimization using periodic boundary conditions. The HF medium solvates preferentially the fluoride anion, which is found as solvated [FHF](-) or solvated F(-.)(HF)(3). On the other hand, the tert-butyl cation is weakly solvated, where the closest HF molecules appear at a distance of about 2.9 Angstrom with the fluorine termination of an HF chain.

  13. Hf impurity and defect interactions in helium-implanted NiHf

    Energy Technology Data Exchange (ETDEWEB)

    Govindaraj, R. E-mail: govind@igcar.ernet.in; Gopinathan, K.P.; Viswanathan, B

    2001-07-01

    TDPAC measurements on the reference and untreated sample indicate a loss in anisotropy which is attributed mainly to the association of probe atoms with defects produced by (n,{gamma}) reactions with isotopes of Ni and experiencing combined magnetic and quadrupole interactions of comparable strengths. Evolution of defect free and substitutional fraction of probe atoms experiencing Larmor frequency characteristic of Ni matrix has been studied as a function of isochronal annealing temperature in helium free {alpha}-irradiated and homogeneously helium-implanted samples. No defect associated Larmor precession frequency and/or quadrupole frequency could be deduced in these uncorrelated damage studies. Comparison of recovery stages in {alpha}-irradiated and helium-implanted samples indicates the binding of helium associated defects by Hf impurities. Segregation of Hf atoms is observed in the helium free {alpha}-irradiated sample for annealing treatment at 973 K, while no such effect is observed in the helium-implanted sample for isochronal annealing treatments up to 1273 K.

  14. HF-based etching processes for improving laser damage resistance of fused silica optical surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Suratwala, T I; Miller, P E; Bude, J D; Steele, R A; Shen, N; Monticelli, M V; Feit, M D; Laurence, T A; Norton, M A; Carr, C W; Wong, L L

    2010-02-23

    The effect of various HF-based etching processes on the laser damage resistance of scratched fused silica surfaces has been investigated. Conventionally polished and subsequently scratched fused silica plates were treated by submerging in various HF-based etchants (HF or NH{sub 4}F:HF at various ratios and concentrations) under different process conditions (e.g., agitation frequencies, etch times, rinse conditions, and environmental cleanliness). Subsequently, the laser damage resistance (at 351 or 355 nm) of the treated surface was measured. The laser damage resistance was found to be strongly process dependent and scaled inversely with scratch width. The etching process was optimized to remove or prevent the presence of identified precursors (chemical impurities, fracture surfaces, and silica-based redeposit) known to lead to laser damage initiation. The redeposit precursor was reduced (and hence the damage threshold was increased) by: (1) increasing the SiF{sub 6}{sup 2-} solubility through reduction in the NH4F concentration and impurity cation impurities, and (2) improving the mass transport of reaction product (SiF{sub 6}{sup 2-}) (using high frequency ultrasonic agitation and excessive spray rinsing) away from the etched surface. A 2D finite element crack-etching and rinsing mass transport model (incorporating diffusion and advection) was used to predict reaction product concentration. The predictions are consistent with the experimentally observed process trends. The laser damage thresholds also increased with etched amount (up to {approx}30 {micro}m), which has been attributed to: (1) etching through lateral cracks where there is poor acid penetration, and (2) increasing the crack opening resulting in increased mass transport rates. With the optimized etch process, laser damage resistance increased dramatically; the average threshold fluence for damage initiation for 30 {micro}m wide scratches increased from 7 to 41 J/cm{sup 2}, and the statistical

  15. Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics

    Science.gov (United States)

    Bast, Rebecca; Scherer, Erik E.; Sprung, Peter; Mezger, Klaus; Fischer-Gödde, Mario; Taetz, Stephan; Böhnke, Mischa; Schmid-Beurmann, Hinrich; Münker, Carsten; Kleine, Thorsten; Srinivasan, Gopalan

    2017-09-01

    The long-lived 176Lu-176Hf and 147Sm-143Nd radioisotope systems are commonly used chronometers, but when applied to meteorites, they can reveal disturbances. Specifically, Lu-Hf isochrons commonly yield dates up to ∼300 Myr older than the solar system and varying initial 176Hf/177Hf values. We investigated this problem by attempting to construct mineral and whole rock isochrons for eucrites and angrites. Meteorites from different parent bodies exhibit similar disturbance features suggesting that a common process is responsible. Minerals scatter away from isochron regressions for both meteorite classes, with low-Hf phases such as plagioclase and olivine typically being most displaced above (or left of) reference isochrons. Relatively Hf-rich pyroxene is less disturbed but still to the point of steepening Lu-Hf errorchrons. Using our Lu-Hf and Sm-Nd data, we tested various Hf and Lu redistribution scenarios and found that decoupling of Lu/Hf from 176Hf/177Hf must postdate the accumulation of significant radiogenic 176Hf. Therefore early irradiation or diffusion cannot explain the excess 176Hf. Instead, disturbed meteorite isochrons are more likely caused by terrestrial weathering, contamination, or common laboratory procedures. The partial dissolution of phosphate minerals may predominantly remove rare earth elements including Lu, leaving relatively immobile and radiogenic Hf behind. Robust Lu-Hf (and improved Sm-Nd) meteorite geochronology will require the development of chemical or physical methods for removing unsupported radiogenic Hf and silicate-hosted terrestrial contaminants without disturbing parent-daughter ratios.

  16. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    Energy Technology Data Exchange (ETDEWEB)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions

  17. Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons: An example from the Spirit Mountain batholith, Nevada

    Science.gov (United States)

    Lowery, Claiborne L.E.; Miller, C.F.; Walker, B.A.; Wooden, J.L.; Mazdab, F.K.; Bea, F.

    2006-01-01

    Zirconium and Hf are nearly identical geochemically, and therefore most of the crust maintains near-chondritic Zr/Hf ratios of ???35-40. By contrast, many high-silica rhyolites and granites have anomalously low Zr/Hf (15-30). As zircon is the primary reservoir for both Zr and Hf and preferentially incorporates Zr, crystallization of zircon controls Zr/ Hf, imprinting low Zr/Hf on coexisting melt. Thus, low Zr/Hf is a unique fingerprint of effective magmatic fractionation in the crust. Age and compositional zonation in zircons themselves provide a record of the thermal and compositional histories of magmatic systems. High Hf (low Zr/ Hf) in zircon zones demonstrates growth from fractionated melt, and Ti provides an estimate of temperature of crystallization (TTiZ) (Watson and Harrison, 2005). Whole-rock Zr/Hf and zircon zonation in the Spirit Mountain batholith, Nevada, document repeated fractionation and thermal fluctuations. Ratios of Zr/Hf are ???30-40 for cumulates and 18-30 for high-SiO2 granites. In zircons, Hf (and U) are inversely correlated with Ti, and concentrations indicate large fluctuations in melt composition and TTiZ (>100??C) for individual zircons. Such variations are consistent with field relations and ion-probe zircon geochronology that indicate a >1 million year history of repeated replenishment, fractionation, and extraction of melt from crystal mush to form the low Zr/Hf high-SiO2 zone. ?? 2006 The Mineralogical Society.

  18. Determination of isothermal section of Ni-Re-Hf ternary system at 1173 K

    Institute of Scientific and Technical Information of China (English)

    王日初; 柳春雷; 金展鹏

    2002-01-01

    The phase equilibriua in the Ni-Re-Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary intermetallics (α and β) and five binary intermetallics (Ni3Hf, Ni10Hf7, Ni11Hf9, NiHf and NiHf2) exist in the Ni-Re-Hf system at 1173 K. A tentative isothermal section of this system at 1173 K was constructed on the basis of experimental results. The isothermal section consists of nine three-phase regions, five of which are supported by the experimental data.

  19. Water-soluble cavitands - synthesis, solubilities and binding properties

    NARCIS (Netherlands)

    Middel, Oskar; Verboom, Willem; Reinhoudt, David N.

    2002-01-01

    Water-soluble cavitand receptors have been obtained by the introduction of ionizable groups (5, 21-28, 39) and neutral hydrophilic tetraethylene glycol based dendritic wedges (19, 20). The synthesis of these cavitands and a study of their water solubilities and binding properties toward neutral orga

  20. Decoupling of whole-rock Nd-Hf and zircon Hf-O isotopic compositions of a 284 Ma mafic-ultramafic intrusion in the Beishan Terrane, NW China

    Science.gov (United States)

    Su, Ben-Xun; Qin, Ke-Zhang; Lu, Ying-Huai; Sun, He; Sakyi, Patrick Asamoah

    2015-10-01

    Abundant Permian mafic-ultramafic intrusions in the Beishan Terrane, NW China, are parts of the Tarim large igneous province. Among these intrusions, Luodong intrusion is composed of dunite, wehrlite and gabbro. These rocks have whole-rock Sr-Nd-Hf and zircon Hf-O isotope compositions that display significant decoupling. The decoupling of these generally well-correlated systems demonstrates contrasting evolving trends. Systematic compositional and mineralogical controls on decoupling have been investigated. Wehrlites and gabbros show MORB-like trace element patterns with negligible crustal contamination. They have high initial 143Nd/144Nd [ɛNd(t) = +6.6 to +11.2] and 176Hf/177HfHf(t) = +12.2 to +16.9] and low initial 87Sr/86Sr [(87Sr/86Sr)i = 0.702949-0.704098] ratios and plot within the MORB field, indicating that their parental magmas were derived from a depleted mantle source. The enrichment features are present in the zircon crystals separated from the gabbro. These homogeneously unzoned zircon crystals have high U concentrations, low Th/U ratios and a U-Pb age of 284.0 ± 2.3 Ma. They are therefore interpreted as having formed rapidly in a highly fractionated/evolved magma. Their ɛHf(t) and δ18O values range from -9.3 to -6.7 and +10.25 ‰ to +11.42 ‰, respectively. The decoupling is linked with crustal contamination by ancient crust (probably Proterozoic schist in the Beishan Terrane) that occurred during zircon crystallization. However, the contamination signature in the whole-rock composition was soon overprinted by magma mixing process. The inference is evidenced by zoning textures preserved in plagioclase, clinopyroxene, spinel and particularly olivine, and the presence of coeval diabase dykes cutting through the intrusion. The isotope decoupling observed in this mantle-plume-related mafic-ultramafic intrusion supports the idea that Nd-Hf decoupling and Lu/Hf and Sm/Nd parent/daughter variations exist only on a small hand-size scale in a

  1. Soluble tumour necrosis factor receptor release after anti-CD3 monoclonal antibody treatment in mice is independent of tumour necrosis factor-alpha release.

    NARCIS (Netherlands)

    Vossen, A.C.T.M.; Tibbe, G.J.M.; Buurman, W.A.; Benner, R.; Savelkoul, H.F.J.

    1996-01-01

    Soluble tumour necrosis factor receptor release after anti-CD3 monoclonal antibody treatment in mice is independent of tumour necrosis factor-alpha release. Vossen AC, Tibbe GJ, Buurman WA, Benner R, Savelkoul HF. Department of Immunology, Erasmus University, Rotterdam, The Netherlands. The involvem

  2. Spallation and fission products in the (p+{sup 179}Hf) and (p+{sup nat}Hf) reactions

    Energy Technology Data Exchange (ETDEWEB)

    Karamian, S.A. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Ur, C.A. [Horia Hulubei National Institute of Physics and Nuclear Engineering, P.O. Box MG-6, Bucharest 077125 (Romania); Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)], E-mail: ur@pd.infn.it; Adam, J. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Institute of Nuclear Physics, Rez, Prague CZ-25068 (Czech Republic); Kalinnikov, V.G.; Lebedev, N.A.; Vostokin, G.K. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Collins, C.B. [Center for Quantum Electronics, University of Texas at Dallas, Richardson, TX 75083 (United States); Popescu, I.I. [Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)

    2009-03-01

    Production of Hf and Lu high-spin isomers has been experimentally studied in spallation reactions induced by intermediate energy protons. Targets of enriched {sup 179}Hf (91%) and {sup nat}Hf were bombarded with protons of energy in the range from 90 to 650 MeV provided by the internal beam of the Dubna Phasotron synchrocyclotron. The activation yields of the reaction products were measured by using the {gamma}-ray spectroscopy and radiochemistry methods. The production cross-sections obtained for the {sup 179m2}Hf, {sup 178m2}Hf and {sup 177m}Lu isomers are similar to the previously measured values from the spallation of Ta, Re and W targets. Therefore, the reactions involving emission of only a few nucleons, like (p,p'), (p,p'n) and (p,2pn), can transfer high enough angular momentum to the final residual nuclei with reasonable large cross-sections. A significant gain in the isomeric yields was obtained when enriched {sup 179}Hf targets were used. The mass distribution of the residual nuclei was measured over a wide range of masses and the fission-to-spallation ratio could be deduced as a function of the projectile energy. Features of the reaction mechanism are briefly discussed.

  3. Paleoproterozoic basement beneath the southern Jiangxi Province: Evidence from U-Pb ages and Lu-Hf isotopes in zircons from the Doushui Iamprophyre

    Institute of Scientific and Technical Information of China (English)

    YU JinHai; WANG LiJuan; O'REILLY S Y; SHU LiangShu; UN Tao

    2009-01-01

    This paper presents geochemical analyses of a lamprophyre intruding the Caledonian Doushui granite body in Shangyou County, southern Jiangxi Province. U-Pb dating and Hf-isotope analyses are especially carried out for zircons from it. Petrological and geochemical features show that the lamprophyre belongs to a high-K, weakly alkaline pyroxene-biotite iamprophyre. It is characterized by high Mg# (0.74),Ni (253 μg/g) and Cr (893 μg/g) contents, and also enriched in incompatible elements, such as REE, Rb, Sr, Ba and K. It is suggested that its primitive melt probably derived from enriched mantle metasomatized by non-crust-derived agent. Morphology and LAM-ICPMS dating results of zircons in the lam prophyre indicate that they are xenocrysts captured from deep crustal rocks. Most xenocrystic zircons formed at -1.86 Ga, and a few in different Phanerozoic periods. The Paleoproterozoic zircons are of magmatic origin and have similar 176Hf/177Hf and 176Lu/177Hf ratios, indicating that they probably are from the same igneous basement rock. The ages and Hf-isotope compositions of zircons from this basement rock are similar to those of Paleoproterozoic Danzhu granite in the southern Zhejiang Province, but extremely distinguished from the Nanling basement, suggesting that the study area probably is a westward extension part of Paleoproterozoic Wuyishan terrane in the eastern Cathaysia Block. These Paleoproterozoic zircons have low Hf-isotope compositions, characteristic of crustal source. Hf model ages of these zircons and the presence of older inherited cores within them, coupled with available other data reported by previous studies, suggest that the source of Paleoproterozoic magma is Neoarchaean crust, implying the existence of older basement in the Wuyishan terrane. U-Pb ages and Hf isotopes of five Phanerozoic zircons indicate that Paleoproterozoic basement underwent multi-reworking occurring in Caledonian, Indosinian and early Yanshanian, respectively. The Caledonian

  4. Pure Phase Solubility Limits: LANL

    Energy Technology Data Exchange (ETDEWEB)

    C. Stockman

    2001-01-26

    The natural and engineered system at Yucca Mountain (YM) defines the site-specific conditions under which one must determine to what extent the engineered and the natural geochemical barriers will prevent the release of radioactive material from the repository. Most important mechanisms for retention or enhancement of radionuclide transport include precipitation or co-precipitation of radionuclide-bearing solid phases (solubility limits), complexation in solution, sorption onto surfaces, colloid formation, and diffusion. There may be many scenarios that could affect the near-field environment, creating chemical conditions more aggressive than the conditions presented by the unperturbed system (such as pH changes beyond the range of 6 to 9 or significant changes in the ionic strength of infiltrated waters). For an extended period of time, the near-field water composition may be quite different and more extreme in pH, ionic strength, and CO{sub 2} partial pressure (or carbonate concentration) than waters at some distance from the repository. Reducing conditions, high pH (up to 11), and low carbonate concentration may be present in the near-field after reaction of infiltrating groundwater with engineered barrier systems, such as cementitious materials. In the far-field, conditions are controlled by the rock-mass buffer providing a near-neutral, oxidizing, low-ionic-strength environment that controls radionuclide solubility limits and sorption capacities. There is the need for characterization of variable chemical conditions that affect solubility, speciation, and sorption reactions. Modeling of the groundwater chemistry is required and leads to an understanding of solubility and speciation of the important radionuclides. Because experimental studies cannot be performed under the numerous potential chemical conditions, solubility limitations must rely on geochemical modeling of the radionuclide's chemistry. Fundamental thermodynamic properties, such as solubility

  5. Hf-Nd isotope and trace element constraints on subduction inputs at island arcs: Limitations of Hf anomalies as sediment input indicators

    Science.gov (United States)

    Handley, Heather K.; Turner, Simon; Macpherson, Colin G.; Gertisser, Ralf; Davidson, Jon P.

    2011-04-01

    New Nd-Hf isotope and trace element data for Javanese volcanoes are combined with recently published data to place constraints on subduction inputs at the Sunda arc in Indonesia and assess the value of Hf anomalies (expressed as Hf/Hf* and Sm/Hf ratios) as tracers of such inputs. Hf anomaly does not correlate with Hf isotope ratio in Javanese lavas, however, Hf/Hf* and Sm/Hf ratios do correlate with SiO 2. Contrary to previous work, we show that Hf anomaly variation may be controlled by fractionation of clinopyroxene and/or amphibole during magmatic differentiation and does not represent the magnitude or type of subduction input in some arcs. Correlation of Sm/Hf with indices of differentiation for other arcs (e.g., Vanuatu, New Britain, and Mariana) suggests that differentiation control on Sm/Hf ratios in volcanic arc rocks may be a relatively common phenomenon. This study corroborates the use of Nd-Hf isotope co-variations in arc volcanic rocks to ascertain subduction input characteristics. The trajectories of regional volcano groups (East, Central and West Java) in Nd-Hf isotope space reveal heterogeneity in the subducted sediment input along Java, which reflects present-day spatial variations in sediment compositions on the down-going plate in the Java Trench. The high Sm/Hf ratio required in the sediment end-member for some Javanese basalts suggests that partial melting of subducted sediment occurs in the presence of residual zircon, and is inconsistent with residual monazite or allanite.

  6. Investigation and Development of Data-Driven D-Region Model for HF Systems Impacts

    Science.gov (United States)

    Eccles, J. V.; Rice, D.; Sojka, J. J.; Hunsucker, R. D.

    2002-01-01

    Space Environment Corporation (SEC) and RP Consultants (RPC) are to develop and validate a weather-capable D region model for making High Frequency (HF) absorption predictions in support of the HF communications and radar communities. The weather-capable model will assimilate solar and earth space observations from NASA satellites. The model will account for solar-induced impacts on HF absorption, including X-rays, Solar Proton Events (SPE's), and auroral precipitation. The work plan includes: I . Optimize D-region model to quickly obtain ion and electron densities for proper HF absorption calculations. 2. Develop indices-driven modules for D-region ionization sources for low, mid, & high latitudes including X-rays, cosmic rays, auroral precipitation, & solar protons. (Note: solar spectrum & auroral modules already exist). 3. Setup low-cost monitors of existing HF beacons and add one single-frequency beacon. 4. Use PENEX HF-link database with HF monitor data to validate D-region/HF absorption model using climatological ionization drivers. 5. Develop algorithms to assimilate NASA satellite data of solar, interplanetary, and auroral observations into ionization source modules. 6. Use PENEX HF-link & HF-beacon data for skill score comparison of assimilation versus climatological D-region/HF absorption model. Only some satellites are available for the PENEX time period, thus, HF-beacon data is necessary. 7. Use HF beacon monitors to develop HF-link data assimilation algorithms for regional improvement to the D-region/HF absorption model.

  7. Serpentinization Changes Nd, but not Hf Isotopes of Abyssal Peridotites

    Science.gov (United States)

    Bizimis, M.; Frisby, C. P.; Mallick, S.

    2015-12-01

    Serpentinization of the oceanic lithosphere is a known sink for fluid mobile elements (B, Cl, Li, Sr, etc.), while high field strength elements (HFSE: e.g., Hf, Zr, Ti, Nb) are thought to be unaffected by it. In contrast, the fate of REE during serpentinization is equivocal. Correlations between REE and HFSE concentrations in abyssal peridotites suggest control by magmatic processes (Niu, 2004, J. Pet), while some LREE enrichments in serpentinized peridotites compared to their clinopyroxene (cpx) and Nd, Sr isotope data (Delacour et al., 2008, Chem. Geol.) imply seawater-derived REE addition to the mantle protolith (Paulick et al., 2006, Chem. Geol). To further constrain peridotite-seawater interaction during serpentinization we compare bulk rock and cpx Hf and Nd isotope data in partially (up to ~70%) serpentinized abyssal peridotites (9-16°E South West Indian Ridge). We also present a new method that improves yields in Hf, Nd and Pb separations from depleted (90% of Hf, Zr, Ti are retained in the residue. LA-ICPMS data shows that serpentine after olivine typically has higher LREE/HREE ratios than cpx, pronounced negative Ce anomalies, high U, Sr concentrations and low HFSE, unlike the coexisting cpx. These data are consistent with some seawater-derived LREE addition to peridotite during serpentinization, localized in the serpentine and other secondary phases, while cpx retains the magmatic value. This process will lower the Sm/Nd relative to Lu/Hf ratio in the peridotite and can lead to decoupled radiogenic Hf and unradiogenic Nd isotopes upon recycling and aging. Our data further testifies to the fidelity of Hf isotopes in tracing mantle processes, even in serpentinized rocks.

  8. Joint Efforts Towards European HF Radar Integration

    Science.gov (United States)

    Rubio, A.; Mader, J.; Griffa, A.; Mantovani, C.; Corgnati, L.; Novellino, A.; Schulz-Stellenfleth, J.; Quentin, C.; Wyatt, L.; Ruiz, M. I.; Lorente, P.; Hartnett, M.; Gorringe, P.

    2016-12-01

    During the past two years, significant steps have been made in Europe for achieving the needed accessibility to High Frequency Radar (HFR) data for a pan-European use. Since 2015, EuroGOOS Ocean Observing Task Teams (TT), such as HFR TT, are operational networks of observing platforms. The main goal is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of HFR data access and tools. Particular attention is being paid by HFR TT to converge from different projects and programs toward those common objectives. First, JERICO-NEXT (Joint European Research Infrastructure network for Coastal Observatory - Novel European eXpertise for coastal observaTories, H2020 2015 Programme) will contribute on describing the status of the European network, on seeking harmonization through exchange of best practices and standardization, on developing and giving access to quality control procedures and new products, and finally on demonstrating the use of such technology in the general scientific strategy focused by the Coastal Observatory. Then, EMODnet (European Marine Observation and Data Network) Physics started to assemble HF radar metadata and data products within Europe in a uniform way. This long term program is providing a combined array of services and functionalities to users for obtaining free of charge data, meta-data and data products on the physical conditions of European sea basins and oceans. Additionally, the Copernicus Marine Environment Monitoring Service (CMEMS) delivers from 2015 a core information service to any user related to 4 areas of benefits: Maritime Safety, Coastal and Marine Environment, Marine Resources, and Weather, Seasonal Forecasting and Climate activities. INCREASE (Innovation and Networking for the integration of Coastal Radars into EuropeAn marine SErvices - CMEMS Service Evolution 2016) will set the necessary developments towards the integration of existing European

  9. First-principles study of the Hf-based Heusler alloys: Hf2CoGa and Hf2CoIn

    Science.gov (United States)

    Hu, Yan; Zhang, Jian-Min

    2017-01-01

    The electronic structures and magnetic properties of the new Heusler alloys Hf2CoGa and Hf2CoIn have been studied by using the first-principles projector augmented wave (PAW) potential within the generalized gradient approximation (GGA). Both Hf2CoGa and Hf2CoIn Heusler alloys have the half-metallic character and completely (100%) spin polarization at the Fermi level (EF) and the indirect band gaps of 0.733 eV and 0.654 eV, respectively, in the minority spin channel. The total magnetic moments μt are all 2μB per formula unit, linearly scaled with the total number of valence electrons (Zt) by μt=Zt-18 and the atomic magnetic moments have localized character due to less affected by deformations. The origin of the indirect band gaps for these two new Heusler alloys is well understood. These two new Heusler alloys are the ideal candidates for spintronic devices.

  10. Cloud droplet activation: solubility revisited

    Directory of Open Access Journals (Sweden)

    L. T. Padró

    2007-02-01

    Full Text Available Soluble compounds present in atmospheric aerosol facilitate their transformation into cloud droplets by depressing the equilibrium vapor pressure required for activation. Their impact depends on the amount of dissolved substance in the aerosol aqueous phase, which in turn is controlled by its solubility. This study explores the impact of particle curvature on solubility, expressed in terms of a Kelvin enhancement. The augmented solubility, termed "Curvature Enhanced Solubility" (CES, is then introduced into Köhler theory for assessment of its impact on CCN activity for several organic compounds with a wide range of aqueous solubility. The interfacial energy between solute and aqueous phase required for quantification of CES is determined from existing correlations based on bulk solubility, and concurrent measurements of contact angle and surface tension. A number of important findings arise from this study: i CES can substantially increase solubility and impact CCN activity but only if the aerosol is initially wet, ii CES can stabilize highly supersaturated solutions, and provide a mechanism for retention of an aerosol aqueous phase even at very low relative humidity (RH, and, iii trace amounts of surfactant impurities can magnify the impact of CES.

  11. Determination of solubility parameters for poly(3-hydroxyalkanoates).

    Science.gov (United States)

    Terada, M; Marchessault, R H

    1999-01-01

    The three dimensional solubility parameters defined by Hansen are based on dispersion forces between structural units, interaction between polar groups and hydrogen bonding. For polar polymers such as poly(3-hydroxyalkanoates), P(3HA), this approach was used to obtain the three coordinates of a solubility parameter in terms of: a dispersion part, a polar part and a hydrogen bonding part. Thirty-eight different solvents for poly(3-hydroxybutyrate), PHB, which are mentioned in the literature are examined by this method and the theoretical predictions are compared with the experimental reports. Another overall comparison between PHA polymers provides their Hansen and Hildebrand parameters for side chain lengths up to C13. In this series a linear progression in calculated solubility parameters with side chain length was found. An Appendix provides information and data on calculation of the solubility parameters. While the solubility information is limited and only covers homopolymers, it should help to highlight some of the contradictions regarding PHB solubility. This semi-empirical approach is only valid for amorphous polymers hence crystallinity effects, which are important with PHB, as well as molecular weight effects still require analysis.

  12. Effect of electron-phonon interaction on resistivity of some heavy fermion (HF) systems

    Energy Technology Data Exchange (ETDEWEB)

    Sahoo, J., E-mail: jitendrasahoo2008@gmail.com [Assistant Director, Regional Office of Vocational Education, Sambalpur, Odisha-768004 (India); Shadangi, N. [Dept. of Physics, Silicon Institute of Technology, Sambalpur, Odisha-768200 (India); Nayak, P. [School of Physics, Sambalpur University, Sambalpur, Odisha-768019 (India)

    2014-04-24

    Here, we have analyzed the electron-phonon interaction in the Periodic Anderson Model (PAM) to describe the temperature dependence of resistivity in some heavy fermion (HF) systems for finite wave vector (q) and for finite temperature (T). Since the resistivity is related to the imaginary part of the electron self energy, the expression for the same is evaluated through double time temperature dependant Green function technique of the Zubarev type. The effect of different system parameters namely the position of 4f level, E{sub 0} and the electron - phonon coupling strengths on resistivity have been studied. The results obtained give satisfactory explanations to the experimental observations.

  13. Comparison of HfAlO, HfO2/Al2O3, and HfO2 on n-type GaAs using atomic layer deposition

    Science.gov (United States)

    Lu, Bin; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Liu, Chen

    2016-11-01

    Different high-permittivity (high-k) gate dielectric structures of HfO2, HfAlO, and HfO2/Al2O3 deposited on HF-etched n-GaAs using ALD have been investigated. It has been demonstrated that the stacked structure of HfO2/Al2O3 has the lowest interface state density of 8.12 × 1012eV-1 cm-2 due to the "self-cleaning" reaction process, but the sample of HfAlO shows much better frequency dispersion and much higher dielectric permittivity extracted from the C-V curves. The investigation reveals that the electrical properties of gate dielectrics are improved by introducing alumina into HfO2.

  14. Mechanical properties of cast Ti-Hf alloys.

    Science.gov (United States)

    Sato, Hideki; Kikuchi, Masafumi; Komatsu, Masashi; Okuno, Osamu; Okabe, Toru

    2005-02-15

    This study examined the mechanical properties of a series of Ti-Hf alloys. Titanium alloys with 10 to 40 mass % Hf were made with titanium and hafnium sponge in an argon-arc melting furnace. Specimens cast into magnesia-based investment molds were tested for yield strength, tensile strength, percentage elongation, and modulus of elasticity. Vickers microhardness was determined at 25 to 600 microm from the cast surface. X-ray diffractometry was also performed. Commercially pure Ti (CP Ti) and pure Ti prepared from titanium sponge were used as controls. The data (n = 5) were analyzed with a one-way ANOVA and the Student-Newman-Keuls test (alpha = 0.05). The diffraction peaks of all the metals matched those for alpha Ti; no beta phase peaks were found. Alloys with Hf > or = 25% had significantly (p 0.05) in elongation among all the Ti-Hf alloys and CP Ti, whereas the elongation of alloys with Hf > or = 30% was significantly (p alloys tested can be considered viable alternatives to CP Ti because they were stronger than CP Ti and had similar elongation.

  15. The prognostic value of plasma soluble ST2 in hospitalized Chinese patients with heart failure.

    Directory of Open Access Journals (Sweden)

    Rongcheng Zhang

    Full Text Available BACKGROUND: sST2 has been shown to be a risk predictor in heart failure (HF. Our aim was to explore the characteristics and prognostic value of soluble ST2 (sST2 in hospitalized Chinese patients with HF. METHODS AND RESULTS: We consecutively enrolled 1528 hospitalized patients with HF. Receiver operating characteristic (ROC and multivariable Cox proportional hazards analysis were used to assess the prognostic values of sST2. Adverse events were defined as all-cause death and cardiac transplantation. During a median follow-up of 19.1 months, 325 patients experienced adverse events. Compared with patients free of events, sST2 concentrations were significantly higher in patients with events (P55.6 ng/mL independently predicted events in comparison to the lowest quartile (≤25.2 ng/mL when adjusted by multivariable model. In ROC analysis, the area under the curve for sST2 was not different from that for NT-proBNP in short and longer term. Over time, sST2 also improved discrimination and reclassification of risk beyond NT-proBNP. CONCLUSIONS: sST2 is a strong independent risk predictor in Chinese patients hospitalized with HF and can significantly provide additional prognostic value to NT-proBNP in risk prediction.

  16. Pressure-induced novel compounds in the Hf-O system from first-principles calculations

    Science.gov (United States)

    Zhang, Jin; Oganov, Artem R.; Li, Xinfeng; Xue, Kan-Hao; Wang, Zhenhai; Dong, Huafeng

    2015-11-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2,Hf3O2 , HfO, and HfO3 are discovered to be thermodynamically stable at certain pressure ranges. Two new high-pressure phases are found for Hf2O : one with space group Pnnm and anti-CaCl2-type structure, another with space group I 41/amd. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide O2 - and peroxide [O-O]2 - anions. Remarkably, it is P 6 ¯2 m -HfO rather than OII-HfO2 that exhibits the highest mechanical characteristics among Hf-O compounds. Pnnm-Hf2O , Imm2-Hf5O2 ,P 3 ¯1 m -Hf2O , and P 4 ¯m 2 -Hf2O3 phases also show superior mechanical properties; theoretically these phases become metastable phases to ambient pressure and their properties can be exploited.

  17. Effect of HF leaching on 14C dates of pottery

    Science.gov (United States)

    Goslar, Tomasz; Kozłowski, Janusz; Szmyt, Marzena; Czernik, Justyna

    2013-01-01

    This paper presents the experiments with 14C dating of two potsherds, which contained carbon dispersed rather homogeneously in their clay fabric. After AAA treatment, the potsherds still appeared to be contaminated with young carbon, presumably connected with humic acids. To make removal of humic acids more effective, we treated the sherds with HF acid of different concentration. The 14C results obtained demonstrate that HF treatment indeed helps to remove humic contaminants, but it also mobilizes carbon bound to raw clay, which may make 14C dates too old. We conclude therefore, that using a simple combination of HF and AAA treatment seems insufficient in reliable 14C dating of carbon homogeneously dispersed in the volume of potsherds.

  18. Damping and ferromagnetic resonance linewidth broadening in nanocrystalline soft ferromagnetic Fe-Co-Hf-N films

    Energy Technology Data Exchange (ETDEWEB)

    Seemann, K. [Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft, Institut fuer Material-forschung I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)], E-mail: klaus.seemann@imf.fzk.de; Leiste, H. [Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft, Institut fuer Material-forschung I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Kovacs, A. [Institute of Scientific and Industrial Research, 8-1 Mihogaoka, Ibaraki, Osaka 5670047 (Japan)

    2008-07-15

    In order to describe high-frequency damping mechanisms of ferromagnetic films by means of the imaginary part of the frequency-dependant permeability, CMOS compatible ferromagnetic Fe{sub 36}Co{sub 44}Hf{sub 9}N{sub 11} films were deposited by reactive r.f. magnetron sputtering on oxidised 5x5 mm{sup 2}x380 {mu}m (1 0 0)-silicon substrates with a 6-in. Fe{sub 38}Co{sub 47}Hf{sub 15} target, as well as magnetic field annealing between 300 and 600 deg. C. An in-plane uniaxial anisotropy of around 4.5 mT as well as an excellent soft magnetic behaviour with a saturation polarisation of approximately 1.4 T could be observed after heat treatment at the above-mentioned temperatures, which drives these films to a high-frequency suitability. Ferromagnetic resonance frequencies of approximately up to 2.4 GHz could be obtained. The frequency-dependant permeability was measured with a broadband permeameter. Depending on the heat treatment, an increase of the full-width at half-maximum (FWHM) of the imaginary part of the frequency-dependant permeability is discussed in terms of two-magnon scattering, anisotropy-type competition and local resonance generation through predominant grain growth causing magnetisation and anisotropy inhomogeneities in the magnetic films. The grain size of the films was determined by (HRTEM) imaging and amounts from a few nanometres for films heat treated at 300 deg. C to more than 10 nm at 600 deg. C where the FWHM {delta}f{sub eff} and the Landau-Lifschitz-Gilbert equation damping parameter {alpha}{sub eff} increases with d{sub nm}{sup 2} and d{sub nm} (e.g. d{sub nm} is the grain diameter of the nonmagnetic Hf-N phase), respectively.

  19. Solubility parameter of polysulfone

    Science.gov (United States)

    Wohlfarth, Ch.

    This document is part of Subvolume D2 'Polymer Solutions - Physical Properties and their Relations I (Thermodynamic Properties: PVT -Data and miscellaneous Properties of polymer Solutions) of Volume 6 `Polymers' of Landolt-Börnstein - Group VIII `Advanced Materials and Technologies'.

  20. Solubility parameter of polystyrene

    Science.gov (United States)

    Wohlfarth, Ch.

    This document is part of Subvolume D2 'Polymer Solutions - Physical Properties and their Relations I (Thermodynamic Properties: PVT -Data and miscellaneous Properties of polymer Solutions) of Volume 6 `Polymers' of Landolt-Börnstein - Group VIII `Advanced Materials and Technologies'.

  1. The Status of Rotational Nonequilibrium in HF Chemical Lasers

    Science.gov (United States)

    1986-05-01

    later study from the same laboratory, Copeland et al. 5 3 used a NdYAG dye laser to pump HF into v = 2, j, and an HF pulsed laser to probe various P 2(J... Weston , Jr., J. Chem. Phys. 77, 4776 (1982). 51. J. J. Hinchen and R. H. Hobbs, Appl. Phys. 50, 628 (1979). 52. j. K. Lambert, G. M. Jursich, and F. F...Crim, Chem. Phys. Lett. 71, 258 (1980). 53. R. A. Copeland , D. J. Pearson, and F. F. Crim, Chem. Phys. Lett. 81, 541 (1981). 54. T. J. Foster and F. F

  2. New active load voltage clamp for HF-link converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, M.A.E.

    2005-07-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core. (au)

  3. HF-induced airglow at magnetic zenith: theoretical considerations

    Directory of Open Access Journals (Sweden)

    E. V. Mishin

    2005-01-01

    Full Text Available Observations of airglow at 630nm (red line and 557.7nm (green line during HF modification experiments at the High Frequency Active Auroral Research Program (HAARP heating facility are analyzed. We propose a theoretical framework for understanding the generation of Langmuir and ion acoustic waves during magnetic zenith injections. We show that observations of HF-induced airglow in an underdense ionosphere as well as a decrease in the height of the emitting volume are consistent with this scenario.

  4. HF-hash : Hash Functions Using Restricted HFE Challenge-1

    CERN Document Server

    Dey, Dhananjoy; Gupta, Indranath Sen

    2009-01-01

    Vulnerability of dedicated hash functions to various attacks has made the task of designing hash function much more challenging. This provides us a strong motivation to design a new cryptographic hash function viz. HF-hash. This is a hash function, whose compression function is designed by using first 32 polynomials of HFE Challenge-1 with 64 variables by forcing remaining 16 variables as zero. HF-hash gives 256 bits message digest and is as efficient as SHA-256. It is secure against the differential attack proposed by Chabaud and Joux as well as by Wang et. al. applied to SHA-0 and SHA-1.

  5. Hf--Co--B alloys as permanent magnet materials

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0.ltoreq.X<2 and 0

  6. First HF radar measurements of summer mesopause echoes at SURA

    Directory of Open Access Journals (Sweden)

    A. N. Karashtin

    Full Text Available HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8–9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  7. New active load voltage clamp for HF-link converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path du...... during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core....

  8. First HF radar measurements of summer mesopause echoes at SURA

    Science.gov (United States)

    Karashtin, A. N.; Shlyugaev, Y. V.; Abramov, V. I.; Belov, I. F.; Berezin, I. V.; Bychkov, V. V.; Eryshev, E. B.; Komrakov, G. P.

    1997-07-01

    HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8-9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  9. European coordination for coastal HF radar data in EMODnet Physics

    Science.gov (United States)

    Mader, Julien; Novellino, Antonio; Gorringe, Patrick; Griffa, Annalisa; Schulz-Stellenfleth, Johannes; Montero, Pedro; Montovani, Carlo; Ayensa, Garbi; Vila, Begoña; Rubio, Anna; Sagarminaga, Yolanda

    2015-04-01

    Historically, joint effort has been put on observing open ocean, organizing, homogenizing, sharing and reinforcing the impact of the acquired information based on one technology: ARGO with profilers Argo floats, EuroSites, ESONET-NoE, FixO3 for deep water platforms, Ferrybox for stations in ships of opportunities, and GROOM for the more recent gliders. This kind of networking creates synergies and makes easier the implementation of this source of data in the European Data exchange services like EMODnet, ROOSs portals, or any applied services in the Blue economy. One main targeted improvement in the second phase of EMODnet projects is the assembling of data along coastline. In that sense, further coordination is recommended between platform operators around a specific technology in order to make easier the implementation of the data in the platforms (4th EuroGOOS DATAMEQ WG). HF radar is today recognized internationally as a cost-effective solution to provide high spatial and temporal resolution current maps (depending on the instrument operation frequency, covering from a few kilometres offshore up to 200 km) that are needed for many applications for issues related to ocean surface drift or sea state characterization. Significant heterogeneity still exists in Europe concerning technological configurations, data processing, quality standards and data availability. This makes more difficult the development of a significant network for achieving the needed accessibility to HF Radar data for a pan European use. EuroGOOS took the initiative to lead and coordinate activities within the various observation platforms by establishing a number of Ocean Observing Task Teams such as HF-Radars. The purpose is to coordinate and join the technological, scientific and operational HF radar communities at European level. The goal of the group is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of

  10. Cátions hidrossolúveis na parte aérea de culturas anuais mediante aplicação de calcário e gesso em superfície Water-soluble cations in shoots of annual crops as affected by lime and phosphogypsum surface application

    Directory of Open Access Journals (Sweden)

    Rogério Peres Soratto

    2007-02-01

    Full Text Available A eficiência da calagem superficial pode ser melhorada por meio de compostos orgânicos hidrossolúveis liberados por resíduos vegetais. No entanto, não se sabe se os teores desses compostos nos resíduos das culturas podem ser modificados pela aplicação de calcário e gesso em superfície. O presente trabalho objetivou avaliar os efeitos das aplicações de calcário e gesso em superfície sobre os teores de cátions solúveis nos resíduos vegetais das culturas de arroz, feijão e aveia-preta. O experimento foi realizado em um Latossolo Vermelho distroférrico de Botucatu (SP. O delineamento foi de blocos casualizados com parcelas subdivididas e quatro repetições. As parcelas foram constituídas por quatro doses de calcário dolomítico (0, 1.100, 2.700 e 4.300 kg ha-1 e as subparcelas, pela aplicação ou não de 2.100 kg ha-1 de gesso agrícola. Para as culturas de verão foi utilizado esquema de parcela subsubdividida. As subsubparcelas foram constituídas por dois cultivares de arroz de terras altas (Caiapó e IAC 202, no ano agrícola 2002/03, e dois cultivares de feijão (Pérola e Carioca, em 2003/04. A aveia-preta foi cultivada no inverno dos dois anos, utilizando apenas o cultivar Comum. Os teores de cátions solúveis na parte aérea das culturas de arroz, feijão e aveia-preta foram alterados pela aplicação de calcário e gesso em superfície. A gessagem em superfície aumentou os teores solúveis de Ca e reduziu o de Mg na parte aérea das culturas, principalmente nas primeiras safras após a aplicação. A calagem aumentou os teores de cátions solúveis na parte aérea de todas as culturas. As culturas do feijão e da aveia-preta apresentaram maiores teores de cátions solúveis nos resíduos da parte aérea, avaliados no florescimento.Surface liming efficiency can be increased through water-soluble organic compounds released by plant residues. However, it is unknown if the contents of these compounds in crop residues

  11. Solubility characteristics of nitrogen gas in SMART

    Energy Technology Data Exchange (ETDEWEB)

    Na, J. W.; Sung, K. W.; Chio, M. S.; Lee, E. H.; Kim, W. C.; Chio, B. S.; Lee, D. J. [KAERI, Taejon (Korea, Republic of)

    2001-05-01

    Nitrogen gas is used in a pressurizer to regulate the pressure of the primary system of SMART (System-integrated Modular Advanced ReacTor). Some of the nitrogen gas in the upper part of the pressurizer is dissolved into the coolant water in the pressurizer and then diffused to primary coolant in reactor core. The solubility of nitrogen in the primary coolant at high temperature and pressure, is important to the reliable operation and the management of water chemistry of SMART. Nitrogen solubility was calculated as the function of temperature and pressure by Himmelblau equation based on Henry's law. As a result, nitrogen solubility in water showed a minimum value at about 85 .deg. C and a maximum value at about 280 .deg. C with total system pressure (150 atm). At the operation condition of SMART, the equilibrium concentration of dissolved nitrogen in the core and the concentration change and the bubble formation of nitrogen gas in water with a temperature change were analyzed.

  12. An infrared study of thin-film formation on Si and Ge surfaces treated with aqueous NH4F and HF

    Science.gov (United States)

    Yota, J.; Burrows, V. A.

    1991-05-01

    The surface chemistry of Si and Ge after treatment with hydrofluoric acid buffered with ammonium fluoride (BHF) was studied using surface infrared spectroscopy. For each of these materials, the BHF not only dissolved the native oxide, but also deposited a thin inorganic film comprised of ammonium salts (NH4F and NH4F.HF). Through one or more complex reactions with the substrate, these salts slowly disappear as the thermodynamically very stable hexafluorometallate compounds [(NH4)2SiF6 and (NH4)2GeF6] form. The NH4F.HF disappearance correlates directly with the hexafluorometallate formation. Though the original fluoride and bifluoride salts are quite soluble in alcohols as well as in aqueous solutions, the hexafluorometallates are completely insoluble in alcohols, and can only be removed by thorough water rinse.

  13. Binary systems solubilities of inorganic and organic compounds

    CERN Document Server

    Stephen, H

    1963-01-01

    Solubilities of Inorganic and Organic Compounds, Volume 1: Binary Systems, Part 1 is part of an approximately 5,500-page manual containing a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic and Organic Compounds in Binary, Ternary and Multi-component Systems. A careful survey of the literature in all languages by a panel of scientists specially appointed for the task by the U.S.S.R. Academy of Sciences, Moscow, has made the compilation of this work possible. The complete English edition in five separately bound volumes w

  14. Effects of soluble organic complexants and their degradation products on the removal of selected radionuclides from high-level waste. Part II: Distributions of Sr, Cs, Tc, and Am onto 32 absorbers from four variations of Hanford tank 101-SY simulant solution

    Energy Technology Data Exchange (ETDEWEB)

    Marsh, S.F. [Sandia National Labs., Albuquerque, NM (United States); Svitra, Z.V.; Bowen, S.M. [Los Alamos National Lab., NM (United States)

    1995-04-01

    Many of the radioactive waste storage tanks at U.S. Department of Energy facilities contain organic compounds that have been degraded by radiolysis and chemical reactions during decades of storage. In this second part of our three-part investigation of the effects of soluble organic complexants and their degradation products, we measured the sorption of strontium, cesium, technetium, and americium onto 32 absorbers that offer high sorption of these elements in the absence of organic complexants. The four solutions tested were (1) a simulant for a 3:1 dilution of Hanford Tank 101-SY contents that initially contained ethylenediaminetetraacetic acid (EDTA), (2) this simulant after gamma-irradiation to 34 Mrads, (3) the unirradiated simulant after treatment with a hydrothermal organic-destruction process, and (4) the irradiated simulant after hydrothermal processing. For each of 512 element/absorber/solution combinations, we measured distribution coefficients (Kds) twice for each period for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. On the basis of our 3,072 measured Kd values, the sorption of strontium and americium is significantly decreased by the organic components of the simulant solutions, whereas the sorption of cesium and technetium appears unaffected by the organic components of the simulant solutions.

  15. Evolution of E2 transition strength in deformed hafnium isotopes from new measurements on $^{172}$Hf, $^{174}$Hf, and $^{176}$Hf

    CERN Document Server

    Rudigier, M; Dannhoff, M; Gerst, R-B; Jolie, J; Saed-Samii, N; Stegemann, S; Régis, J-M; Robledo, L M; Rodríguez-Guzmán, R; Blazhev, A; Fransen, Ch; Warr, N; Zell, K O

    2015-01-01

    The available data for E2 transition strengths in the region between neutron-deficient Hf and Pt isotopes are far from complete. More and precise data are needed to enhance the picture of structure evolution in this region and to test state-of-the-art nuclear models. In a simple model, the maximum collectivity is expected at the middle of the major shell. However, for actual nuclei, this picture may no longer be the case, and one should use a more realistic nuclear-structure model. We address this point by studying the spectroscopy of Hf. We remeasure the 2^+_1 half-lives of 172,174,176Hf, for which there is some disagreement in the literature. The main goal is to measure, for the first time, the half-lives of higher-lying states of the rotational band. The new results are compared to a theoretical calculation for absolute transition strengths. The half-lives were measured using \\gamma-\\gamma and conversion-electron-\\gamma delayed coincidences with the fast timing method. For the determination of half-lives i...

  16. Comparative study of atomic-layer-deposited HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox on N-GaAs

    Science.gov (United States)

    Yu, Xinjiang; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Qin, Zaiyang

    2016-11-01

    Interfacial properties of n-GaAs metal-oxide-semiconductor (MOSCAPs) with the gate dielectrics of HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox are investigated. The results reveal that Hf0.5Al0.5Ox has larger permittivity and lower interface trap density than that of HfO2/Al2O3. In order to explain the result from the physical perspective, the XPS tests of all three samples are performed. It is found that the main reason to form interface trap of three samples treated with 500 °C post-deposition annealing, is attributed to the interfacial component of Ga2O3 and The Hf0.5Al0.5Ox dielectric is beneficial to reducing the formation of Ga2O3.

  17. Pure Phase Solubility Limits: LANL

    Energy Technology Data Exchange (ETDEWEB)

    C. Stockman

    2001-01-26

    The natural and engineered system at Yucca Mountain (YM) defines the site-specific conditions under which one must determine to what extent the engineered and the natural geochemical barriers will prevent the release of radioactive material from the repository. Most important mechanisms for retention or enhancement of radionuclide transport include precipitation or co-precipitation of radionuclide-bearing solid phases (solubility limits), complexation in solution, sorption onto surfaces, colloid formation, and diffusion. There may be many scenarios that could affect the near-field environment, creating chemical conditions more aggressive than the conditions presented by the unperturbed system (such as pH changes beyond the range of 6 to 9 or significant changes in the ionic strength of infiltrated waters). For an extended period of time, the near-field water composition may be quite different and more extreme in pH, ionic strength, and CO{sub 2} partial pressure (or carbonate concentration) than waters at some distance from the repository. Reducing conditions, high pH (up to 11), and low carbonate concentration may be present in the near-field after reaction of infiltrating groundwater with engineered barrier systems, such as cementitious materials. In the far-field, conditions are controlled by the rock-mass buffer providing a near-neutral, oxidizing, low-ionic-strength environment that controls radionuclide solubility limits and sorption capacities. There is the need for characterization of variable chemical conditions that affect solubility, speciation, and sorption reactions. Modeling of the groundwater chemistry is required and leads to an understanding of solubility and speciation of the important radionuclides. Because experimental studies cannot be performed under the numerous potential chemical conditions, solubility limitations must rely on geochemical modeling of the radionuclide's chemistry. Fundamental thermodynamic properties, such as solubility

  18. First 100 ms of HF modification at Tromso, Norway

    Science.gov (United States)

    Djuth, F. T.; Isham, B.; Rietveld, M. T.; Hagfors, T.; La Hoz, C.

    Experiments were performed with the high-power high-frequency HF facility at Troms o Norway to test theoretical predictions for the excitation of ion and Langmuir oscillations in the ionosphere The principal diagnostic of wave-plasma interactions was the VHF radar at the European Incoherent Scatter EISCAT facility High resolution radar techniques were used to monitor the temporal development of the ion and Langmuir oscillations HF pulses 100 ms in duration were periodically transmitted into a smooth background F region plasma Measurements of the radar backscatter spectra show that all key spectral features predicted by strong Langmuir turbulence SLT theory modified Zakharov model are simultaneously present in the plasma and that their evolution is in agreement with theoretical expectations However several new features have been observed that cannot be anticipated by current theory because of limitations in the electric field strength within the simulations The experimental results reinforce the notion that new theoretical developments are needed to accommodate the large HF electric fields produced at Troms o and HAARP Gakona Alaska and to treat the electron acceleration process in a self-consistent fashion The F region response to two HF effective radiated power levels sim 58 MW and sim 125 MW was investigated at Troms o These ERP values include absorptive losses resulting from the sunlit D region In general the results at 58 MW ERP and 125 MW ERP are consistent with many of the SLT

  19. The multilayer Fe/Hf studied with slow positron beam

    Science.gov (United States)

    Murashige, Y.; Tashiro, M.; Nakajyo, T.; Koizumi, T.; Kanazawa, I.; Komori, F.; Ito, Y.

    1997-04-01

    The positron annihilation parameter versus the incident positron energy is measured in the thin Fe films and the Fe/Hf bilayer on silica substrate, by means of the variable energetic slow-positron beam technique. We have analyzed the change in open-volume spaces and vacancy-type defects among the Fe microcrystals in these thin films with the deposition temperature.

  20. A CMOS OTA for HF filters with programmable transfer function

    NARCIS (Netherlands)

    van de Zwan, Eric J.; Klumperink, Eric A.M.; Seevinck, E.; Seevinck, Evert

    1991-01-01

    A CMOS operational transconductance amplifier (OTA) for programmable HF filters is presented. When used in an OTA-C integrator, the unity-gain frequency phase error remains less than 0.3° for frequencies up to more than one tenth of the OTA bandwidth. The OTA has built-in phase compensation, which

  1. Hf isotope evidence for a hidden mantle reservoir

    DEFF Research Database (Denmark)

    Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.

    2002-01-01

    High-precision Hf isotopic analyses and U-Pb ages of carbonatites and kimberlites from Greenland and eastern North America, including Earth's oldest known carbonatite (3 Ga), indicate derivation from an enriched mantle source. This previously unidentified mantle reservoir-marked by an unradiogeni...

  2. Origin of excess 176Hf in meteorites

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  3. Self-diffusion of Er and Hf inpure and HfO/sub 2/-doped polycrystalline Er/sub 2/O/sub 3/. [Hf-175 and Er-169

    Energy Technology Data Exchange (ETDEWEB)

    Scheidecker, R.W.

    1979-01-01

    Using a tracer technique, self-diffusion of Er and Hf was measured over the approximate temperature interval of 1600 to 1970/sup 0/C in pure and HfO/sub 2/-doped polycryatalline Er/sub 2/O/sub 3/. Up to about 10 m/o HfO/sub 2/ dopant level, the Er self-diffusion coefficients followed a relationship based on cation vacancies. Above 10 m/o HfO/sub 2/, deviation from this relationship occurred, apparently due to clustering of cation vacancies and oxygen interstitials around the dopant hafnia ion. The activation energy for the self-diffusion of Er in pure Er/sub 2/O/sub 3/ was 82.2 Kcal/mole and increased with the HfO/sub 2/ dopant level present. Self-diffusion of Hf was measured in pure Er/sub 2/O/sub 3/ having two impurity levels, and a separation of the grain boundary. The volume diffusion of Hf showed both extrinsic and intrinsic behavior with the transition temperature increasing with the impurity level present in Er/sub 2/O/sub 3/. The activation energy for Hf volume diffusion in the intrinsic region was high, i.e. 235 -+ 9.5 Kcal/mole. The grain boundary diffusion was apparently extrinsic over the entire temperature interval Very low Hf self diffusion rates were found in both pure and HfO/sub 2/ doped Er/sub 2/O/sub 3/ compositions. Despite a clustering effect, the HfO/sub 2/ dopant increased the Hf volume diffusion coefficients.

  4. Helium implanted $\\rm\\underline{Al}$Hf as studied by 181Ta TDPAC

    Indian Academy of Sciences (India)

    R Govindaraj; K P Gopinathan; B Viswanathan

    2000-06-01

    Time differential perturbed angular correlation (TDPAC) measurement on $\\rm\\underline{Al}$Hf reference sample has shown that a fraction 0.88 of probe nuclei are defect free and are occupying the substitutional sites in fcc Al matrix, and the remaining are associated with Hf solute clusters. Measurements on helium implanted sample indicate the binding of helium associated defects by Hf solute clusters. Isochronal annealing measurements indicate the dissociation of the helium implantation induced defects from Hf solute clusters for annealing treatments beyond 650 K. On comparison of the present results with that reported in $\\rm\\underline{Cu}$Hf subjected to identical helium implantation, it is inferred that the Hf solute clusters in $\\rm\\underline{Al}$Hf bind less strongly the helium associated defects than in $\\rm\\underline{Cu}$Hf.

  5. Processing and crystallographic structure of non-equilibrium Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Dong; Fancher, Chris M.; Esteves, Giovanni; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Zhao, Lili [School of Information Science and Technology, Northwest University, Xi' an 710127 (China)

    2015-06-28

    Si-doped HfO{sub 2} was confirmed to exist as a non-equilibrium state. The crystallographic structures of Si-doped HfO{sub 2} were studied using high-resolution synchrotron X-ray diffraction and the Rietveld refinement method. Incorporation of Si into HfO{sub 2} and diffusion of Si out of (Hf,Si)O{sub 2} were determined as a function of calcination temperature. Higher thermal energy input at elevated calcination temperatures resulted in the formation of HfSiO{sub 4}, which is the expected major secondary phase in Si-doped HfO{sub 2}. The effect of SiO{sub 2} particle size (nano- and micron-sized) on the formation of Si-doped HfO{sub 2} was also determined. Nano-crystalline SiO{sub 2} was found to incorporate into HfO{sub 2} more readily.

  6. Data of evolutionary structure change: 1CLMA-2HF5A [Confc[Archive

    Lifescience Database Archive (English)

    Full Text Available 1CLMA-2HF5A 1CLM 2HF5 A A LTEEQIAEFKEAFALFDKDGDGTITTKELGTVMRSLGQN...PTEAELQDMINEVDADGNGTIDFPEFLSLMARKMKEQDSEEELIEAFKVFDRDGNGLISAAELRHVMTNLGEKL--TDDEVDEMIREADIDGDGHINYEEFVRMMVS-...ntryChain> 1CLM A 1CLMA LGEKL--TD...ne> 1CLM A 1CLMA

  7. Analysis of one year of HF radar data acquired in the German Bight

    Science.gov (United States)

    Schulz-Stellenfleth, J.; Stanev, E. V.; Seemann, J.

    2012-04-01

    Surface current measurements are taken on a pre-operational basis by three HF radar stations in the German Bight. This area is very shallow and dominated by tides. The HF radar is part of the COSYNA system, which aims at the implementation of an integrated observing system for the North Sea. The radars provide meridional and zonal current components at intervals of 20 minutes in areas where at least two stations overlap and only radial components elswhere. An analysis of the radar observations is performed for a data set of one year. A tidal decompositions is carried out to identify dominating constituents for different areas. Furthermore, the two dimensional surface current dynamics is analysed using tidal ellipses parameters.The generation of overtides in the shallow water areas is demonstrated. Different factors driving this mechanism are discussed. A closer look at the neap/spring tide cycle provides insight into the relative role of bottom friction processes. The relation between the inclination of tidal ellipses and bathymetric features is studied in this context as well. Current, salinity and temperature profile measurements taken at the offshore platform FINO-3 are used in addition to study stratification effects. The impact of the meteo forcing is investigated based on several case studies such as storm events and rapid changes of wind direction. For this purpose residual currents are estimated from the radar data. Finally the divergence of the observed current fields is analysed and the relation to water level dynamics is discussed. The study is meant to support the ongoing work on data assimilation and quality control within COSYNA. The relevance of the presented analysis for this work is explained and illustrated. The work is of value for the optimisation of HF radar system setups in other regions as well.

  8. US Integrated Ocean Observing System HF Radar Network: National Applications and International Implementation

    Science.gov (United States)

    Harlan, J.

    2016-12-01

    The US Integrated Ocean Observing System (IOOS), a partnership of academic institutions and Federal agencies, within NOAA National Ocean Service (NOS), operates the nation's only high-frequency (HF) radar network providing near-real-time 2-D maps of ocean of surface currents speed and direction. This system supports US Coast Guard search and rescue operations, NOAA response to oil spills, port navigation and tracking of harmful algal bloom. In the research realm, the data are helping to understand oceanographic processes such as the warm water mass off of the west coast of the US and are routinely ingested into oceanographic models and are used for research into tsunami detection. A key component of the network is the data management system that ingests and distributes hourly data from radars throughout US coastal areas as well as Canada and Mexico, comprising nearly 150 radars. HF radar operators outside the US have adopted the data file formats that were developed by the US IOOS and these data are displayed publicly in near-real-time. To enhance the utility of HF radar data to end-users in all parts of the globe, operational products are needed. Recently in the US, quasi-operational products have been developed, or are under development, including: 2-D maps in AWIPS-II, tidal analysis and prediction from NOS Center for Operational Oceanographic Products & Services (CO-OPS), tsunami detection algorithms led by National Tsunami Warning Center, and significant wave height pilot project. These products will be highlighted and potential for international use discussed.

  9. Coupled Hf-Nd-Pb isotope co-variations of HIMU oceanic island basalts from Mangaia, Cook-Austral islands, suggest an Archean source component in the mantle transition zone

    Science.gov (United States)

    Nebel, Oliver; Arculus, Richard J.; van Westrenen, Wim; Woodhead, Jon D.; Jenner, Frances E.; Nebel-Jacobsen, Yona J.; Wille, Martin; Eggins, Stephen M.

    2013-07-01

    Although it is widely accepted that oceanic island basalts (OIB) sample geochemically distinct mantle reservoirs including recycled oceanic crust, the composition, age, and locus of these reservoirs remain uncertain. OIB with highly radiogenic Pb isotope signatures are grouped as HIMU (high-μ, with μ = 238U/204Pb), and exhibit unique Hf-Nd isotopic characteristics, defined as ΔɛHf, deviant from a terrestrial igneous rock array that includes all other OIB types. Here we combine new Hf isotope data with previous Nd-Pb isotope measurements to assess the coupled, time-integrated Hf-Nd-Pb isotope evolution of the most extreme HIMU location (Mangaia, French Polynesia). In comparison with global MORB and other OIB types, Mangaia samples define a unique trend in coupled Hf-Nd-Pb isotope co-variations (expressed in 207Pb/206Pb vs. ΔɛHf). In a model employing subducted, dehydrated oceanic crust, mixing between present-day depleted MORB mantle (DMM) and small proportions (˜5%) of a HIMU mantle endmember can re-produce the Hf-Nd-Pb isotope systematics of global HIMU basalts (sensu stricto; i.e., without EM-1/EM-2/FOZO components). An age range of 3.5 to affected by other enriched mantle endmembers (sensu lato). If correct, this requires isolation of parts of the mantle transition zone for >3 Gyr and implies that OIB chemistry can be used to test geodynamic models.

  10. Geographic variations in the PARADIGM-HF heart failure trial.

    Science.gov (United States)

    Kristensen, Søren Lund; Martinez, Felipe; Jhund, Pardeep S; Arango, Juan Luis; Bĕlohlávek, Jan; Boytsov, Sergey; Cabrera, Walter; Gomez, Efrain; Hagège, Albert A; Huang, Jun; Kiatchoosakun, Songsak; Kim, Kee-Sik; Mendoza, Iván; Senni, Michele; Squire, Iain B; Vinereanu, Dragos; Wong, Raymond Ching-Chiew; Gong, Jianjian; Lefkowitz, Martin P; Rizkala, Adel R; Rouleau, Jean L; Shi, Victor C; Solomon, Scott D; Swedberg, Karl; Zile, Michael R; Packer, Milton; McMurray, John J V

    2016-11-01

    The globalization of clinical trials has highlighted geographic variations in patient characteristics, event rates, and treatment effects. We investigated these further in PARADIGM-HF, the largest and most globally representative trial in heart failure (HF) to date. We looked at five regions: North America (NA) 602 (8%), Western Europe (WE) 1680 (20%), Central/Eastern Europe/Russia (CEER) 2762 (33%), Latin America (LA) 1433 (17%), and Asia-Pacific (AP) 1487 (18%). Notable differences included: WE patients (mean age 68 years) and NA (65 years) were older than AP (58 years) and LA (63 years) and had more coronary disease; NA and CEER patients had the worst signs, symptoms, and functional status. North American patients were the most likely to have a defibrillating-device (54 vs. 2% AP) and least likely prescribed a mineralocorticoid receptor antagonist (36 vs. 65% LA). Other evidence-based therapies were used most frequently in NA and WE. Rates of the primary composite outcome of cardiovascular (CV) death or HF hospitalization (per 100 patient-years) varied among regions: NA 13.6 (95% CI 11.7-15.7) WE 9.6 (8.6-10.6), CEER 12.3 (11.4-13.2), LA 11.2 (10.0-12.5), and AP 12.5 (11.3-13.8). After adjustment for prognostic variables, relative to NA, the risk of CV death was higher in LA and AP and the risk of HF hospitalization lower in WE. The benefit of sacubitril/valsartan was consistent across regions. There were many regional differences in PARADIGM-HF, including in age, symptoms, comorbidity, background therapy, and event-rates, although these did not modify the benefit of sacubitril/valsartan. CLINICAL TRIAL REGISTRATION URL: http://www.clinicaltrials.gov. Unique identifier: NCT01035255. © The Author 2016. Published by Oxford University Press on behalf of the European Society of Cardiology.

  11. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2015-01-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  12. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2014-12-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  13. Cross over between ferro and antiferromagnetic order in Fe itinerant electron magnetism: An experimental and theoretical study of the model (Hf,Ta)Fe{sub 2} Laves phases

    Energy Technology Data Exchange (ETDEWEB)

    Diop, L.V.B., E-mail: leopoldbirane@gmail.com [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Benea, D. [Babes-Bolyai University, Faculty of Physics, 400084 Cluj-Napoca (Romania); Mankovsky, S. [Department of Chemistry, University of Munich, Butenandstrasse 5-13, D-81377 München (Germany); Isnard, O. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France)

    2015-09-15

    Highlights: • a lattice parameter is found to drive the change from FM to AF magnetic order. • We demonstrate the strong interplay between crystal structure and magnetic order. • Fe magnetic moment is very sensitive to change of the lattice constant a. • A metamagnetic phase transition has been observed. - Abstract: Band structure calculations are reported to describe the effects of Ta for Hf substitution on the electronic structure of the Laves phase of HfFe{sub 2}. According to experimental results emphasis is put on the investigation of the Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2} composition in comparison with the reference HfFe{sub 2} and TaFe{sub 2} compounds. By investigation of the theoretical interatomic exchange interactions constants, we showed the influence of the magnetovolume effect on the magnetic phase stability for one intermediate composition Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2}, chosen in the most interesting part of the magnetic phase diagram with coexistence of ferromagnetic (FM) and antiferromagnetic (AF) behaviour. Evolution of the a lattice parameter is found to drive the change from FM to AF magnetic order. A detailed study of the interatomic Fe–Fe exchange coupling constants and their lattice dependence reveals that the ferromagnetic interaction with the first shell is strongly reduced upon contraction of the a lattice parameter.

  14. Thermoelectric properties of monolayer MSe2 (M = Zr, Hf): low lattice thermal conductivity and a promising figure of merit.

    Science.gov (United States)

    Ding, Guangqian; Gao, G Y; Huang, Zhishuo; Zhang, Wenxu; Yao, Kailun

    2016-09-16

    Monolayer transition-metal dichalcogenides (TMDCs) MX2 (M = Mo, W, Zr, Hf, etc; X = S, Se, Te) have become well-known in recent times for their promising applications in thermoelectrics and field effect transistors. In this work, we perform a systematic study on the thermoelectric properties of monolayer ZrSe2 and HfSe2 using first-principles calculations combined with Boltzmann transport equations. Our results point to a competitive thermoelectric figure of merit (close to 1 at optimal doping) in both monolayer ZrSe2 and HfSe2, which is markedly higher than previous explored monolayer TMDCs such as MoS2 and MoSe2. We also reveal that the higher figure of merits arise mainly from their low lattice thermal conductivity, and this is partly due to the strong coupling of acoustic modes with low frequency optical modes. It is found that the figure of merits can be better optimized in n-type than in p-type. In particular, the performance of HfSe2 is superior to ZrSe2 at a higher temperature. Our results suggest that monolayer ZrSe2 and HfSe2 with lower lattice thermal conductivity than usual monolayer TMDCs are promising candidates for thermoelectric applications.

  15. SOLUBILITY ENHANCEMENT OF POORLY WATER SOLUBLE DRUGS BY SOLID DISPERSIO

    Directory of Open Access Journals (Sweden)

    Amita Verm

    2012-01-01

    Full Text Available Solid dispersions have been employed to enhance the dissolution rates of poorly water-soluble drugs. Many approaches have been investigated for the preparation of solid dispersions. This paper reports the various solubility enhancement strategies in solid dispersion. The approaches described are fusion (melting, solvent evaporation, lyophilization (freeze drying, melt agglomeration process, extruding method, spray drying technology, use of surfactant, electro static spinning method and super critical fluid technology. This paper also highlights the potential applications and limitations of theseapproaches in solid dispersions.

  16. The stability of the bifluoride ion (HF - 2) in the gas phase

    Science.gov (United States)

    Heni, Martin; Illenberger, Eugen

    1985-12-01

    The bifluoride ion (HF-2) has been generated by dissociative electron attachment to trans-1,2-difluorethylene and cis-1,2-difluoroethylene. Evaluation of the energetics for these reactions leads to ΔH0f (HF-2) ≤-6.9 eV and E. A. (HF2)≥4.8 eV.

  17. Photon strength function in the Hf-181 nucleus by method of two-step cascade

    CERN Document Server

    Le Hong Khiem

    2003-01-01

    The applicability of sum-coincidence measurements of two-step cascade gamma ray spectra determining Photon Strength Function (PSF) of Hf-181 induced from Hf-180 (n,2 gamma) Hf-181 reaction is presented. Up to 80% intensity of the primary gamma ray transitions in a wide energy range have been deduced and compared to model calculation.

  18. Suppression Factor of ~(182)W for ~(182)Hf AMS at CIAE

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Suppression factor of 182W is an important index in the measurement of 182Hf with AMS method. This factor is defined as the value of 182W/180Hf in blank samples divised by the measured value of 182 W/180Hf with AMS method. In order to satisfy a

  19. 40 CFR 180.1273 - Beauveria bassiana HF23; exemption from the requirement of a tolerance.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Beauveria bassiana HF23; exemption... FOOD Exemptions From Tolerances § 180.1273 Beauveria bassiana HF23; exemption from the requirement of a tolerance. Residues of Beauveria bassiana HF23 are exempt from the requirement of a tolerance on all...

  20. Two-dimensional semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures by molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Aretouli, K. E.; Tsipas, P.; Tsoutsou, D.; Marquez-Velasco, J.; Xenogiannopoulou, E.; Giamini, S. A.; Vassalou, E.; Kelaidis, N.; Dimoulas, A., E-mail: a.dimoulas@inn.demokritos.gr [Institute of Nanoscience and Nanotechnology, National Center for Scientific Research “Demokritos,” 15310, Aghia Paraskevi, Athens (Greece)

    2015-04-06

    Using molecular beam epitaxy, atomically thin 2D semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures are grown on AlN(0001)/Si(111) substrates. Details of the electronic band structure of HfSe{sub 2} are imaged by in-situ angle resolved photoelectron spectroscopy indicating a high quality epitaxial layer. High-resolution surface tunneling microscopy supported by first principles calculations provides evidence of an ordered Se adlayer, which may be responsible for a reduction of the measured workfunction of HfSe{sub 2} compared to theoretical predictions. The latter reduction minimizes the workfunction difference between the HfSe{sub 2} and MoSe{sub 2} layers resulting in a small valence band offset of only 0.13 eV at the MoSe{sub 2}/HfSe{sub 2} heterointerface and a weak type II band alignment.

  1. Subduction zone mantle enrichment by fluids and Zr-Hf-depleted crustal melts as indicated by backarc basalts of the Southern Volcanic Zone, Argentina

    Science.gov (United States)

    Holm, Paul M.; Søager, Nina; Alfastsen, Mads; Bertotto, Gustavo W.

    2016-10-01

    We aim to identify the components metasomatizing the mantle above the subducting Nazca plate under part of the Andean Southern Volcanic Zone (SVZ). We present new major and ICP-MS trace element and Sr, Nd and high-precision Pb isotope analyses of primitive olivine-phyric alkali basalts from the Northern Segment Volcanic Field, part of the Payenia province in the backarc of the Transitional SVZ. One new 40Ar-39Ar age determination confirms the Late Pleistocene age of this most northerly part of the province. All analysed rocks have typical subduction zone type incompatible element enrichment, and the rocks of the Northern Segment, together with the neighbouring Nevado Volcanic Field, have isotopic compositions intermediate between adjacent Transitional SVZ arc rocks and southern Payenia OIB-type basaltic rocks. Modelling the Ba-Th-Sm variation we demonstrate that fluids as well as 1-2% melts of upper continental crust (UCC) enriched their mantle sources, and La-Nb-Sm variations additionally indicate that the pre-metasomatic sources ranged from strongly depleted to undepleted mantle. Low Eu/Eu* and Sr/Nd also show evidence for a UCC component in the source. The contribution of Chile Trench sediments to the magmas seems insignificant. The Zr/Sm and Hf/Sm ratios are relatively low in many of the Northern Segment rocks, ranging down to 17 and 0.45, respectively, which, together with relatively high Th/U, is argued to indicate that the metasomatizing crustal melts were derived by partial melting of subducted UCC that had residual zircon, in contrast to the UCC melts added to Transitional SVZ arc magmas. Mixing between depleted and undepleted mantle, enriched by UCC and fluids, is suggested by Sr, Nd and Pb isotopes of the Northern Segment and Nevado magmas. The metasomatized undepleted mantle south of the Northern Segment is suggested to be part of upwelling OIB-type mantle, whereas the pre-metasomatically depleted mantle also can be found as a component in some arc

  2. 40 CFR Table 3 to Subpart Ggg of... - Soluble HAP

    Science.gov (United States)

    2010-07-01

    ... sulfate. Dinitrotoluene. Ethylene glycol dimethyl ether. Ethylene glycol monobutyl ether acetate. Ethylene glycol monomethyl ether acetate. Isophorone. Methanol (methyl alcohol). Nitrobenzene. Toluidene... for Pharmaceuticals Production Pt. 63, Subpt. GGG, Table 3 Table 3 to Subpart GGG of Part 63—Soluble...

  3. A Soluble, Folded Protein without Charged Amino Acid Residues

    DEFF Research Database (Denmark)

    Højgaard, Casper; Kofoed, Christian; Espersen, Roall;

    2016-01-01

    Charges are considered an integral part of protein structure and function, enhancing solubility and providing specificity in molecular interactions. We wished to investigate whether charged amino acids are indeed required for protein biogenesis and whether a protein completely free of titratable ...

  4. The Solubility Rules: Why Are All Acetates Soluble?

    Science.gov (United States)

    van der Sluys, William G.

    2001-01-01

    According to the solubility rules presented in many introductory chemistry texts, all (or most) acetate salts are soluble in aqueous solution. The thermodynamic factors that contribute to the solubility of acetates are compared with those of other slightly basic anions. In particular, the hydration enthalpy of acetate is calculated using the Born-Haber approach, from lattice energies, heats of solution, and the hydration energies of several cations. The hydration enthalpy of acetate (-375 kJ/mol) is similar to that of chloride ({355 kJ/mol), nitrite ({383 kJ/mol), and nitrate ({370 kJ/mol), which are all considerably less exothermic than fluoride ({497 kJ/mol). This was somewhat unexpected, since hydration enthalpies generally correlate well with the acid-base properties of an ion, and acetate is more basic than fluoride. Factors influencing the solubility and acid-base properties of acetates, such as the electron donating and hydrophobic nature of the methyl group, are discussed in light of the thermodynamic data.

  5. Preliminary considerations concerning actinide solubilities

    Energy Technology Data Exchange (ETDEWEB)

    Newton, T.W.; Bayhurst, B.P.; Daniels, W.R.; Erdal, B.R.; Ogard, A.E.

    1980-01-01

    Work at the Los Alamos Scientific Laboratory on the fundamental solution chemistry of the actinides has thus far been confined to preliminary considerations of the problems involved in developing an understanding of the precipitation and dissolution behavior of actinide compounds under environmental conditions. Attempts have been made to calculate solubility as a function of Eh and pH using the appropriate thermodynamic data; results have been presented in terms of contour maps showing lines of constant solubility as a function of Eh and pH. Possible methods of control of the redox potential of rock-groundwater systems by the use of Eh buffers (redox couples) is presented.

  6. Towards the creation of a multi-institutional HF Radar Network in the Gulf of Mexico.

    Science.gov (United States)

    Flores-vidal, X.; Flament, P. J.; Durazo, R.; Navarro, L. F.; Salles, P.; Alvarez, P.; Carrillo, L.; Kurczyn, J. A.; Ulloa, M. J.; Rodriguez, I.; Toro Valencia, V. G.; Marin, M.; Perales, H.; Sanay, R.

    2016-12-01

    The Gulf of Mexico is source of important resources for both Mexico and USA, its beaches and coasts bring economical resources for these countries through the generation of jobs on the fisheries, touristic and industrial sectors. However, systematic monitoring is still necessary to evaluate its health and dynamics. This work is part of a multi-institutional project named "Implementation of oceanographic observational networks (physical, geochemical and ecological) to generate scenarios for possible contingencies related to the exploration and production of hydrocarbons in the deep waters of the Gulf of Mexico" (funded by SENER-CONACyT) which is an unprecedented Mexican joint effort to better understand the dynamics in the Gulf of Mexico. We will present the first actions towards the creation of the Mexican multi-Institutional HF Radar Network, which will allow us to synoptically map in real time the sea surface currents up to 200 km offshore. We expect to attract collaborations with the active or ongoing USA HF radar stations and institutions along the Gulf of Mexico, as well as to share methodologies and to evaluate standard data formats. The Radar Network in the Gulf of Mexico is planned to be active during 2017-2018, and it is expected to be permanent.

  7. 高压下BaHfO3电子结构与光学性质的第一性原理研究%First-principles study on the electronic structures and optical properties of BaHfO3 under high pressure

    Institute of Scientific and Technical Information of China (English)

    顾芳; 王俊锋; 陈云云; 刘清惓; 张加宏

    2012-01-01

    The cubic perovskite-type BaHfO3 has been investigated by the first-principles plane-wave pseudo-potential method based on the density function theory. The electronic structure and optical properties of BaHfO3 are calculated under high pressure. The band structure analysis indicates that BaHfO3 is a direct-band-gap insulator in the case of without pressure and imposing positive pressure, while BaHfO3 is transformed into an indirect-band-gap semiconductor under negative pressure. Besides, the band gap of BaHfO3 decreases with an increase of pressure, and it appears obvious nonlinear relationship. The optical properties calculations show that the absorption edge is blue-shifted when imposing positive pressure, while it is red-shifted and peaks of imaginary part of the dielectric function decrease when imposing negative pressure. Furthermore, the static dielectric constant and static refractive index of BaHfO3under high pressure increase. In a word, the involved results have shown that the high pressure effectively modulates the electronic structure and optical properties of BaHfO3, which will provide a theoretical basis for the design and application of BaHfO3 optoelectronic materials.%从第一性原理出发,在局域密度近似下,采用基于密度泛函理论的平面波超软赝势计算方法系统地研究了高压对BaHfO3电子结构与光学性质的影响.能带结构分析表明:无压强和施加正压强作用时,BaHfO3为直接带隙绝缘体,而施加负压强时,BaHfO3则转变为间接带隙半导体;BaHfO3的带隙随压强增加而减小,且具有明显的非线性关系.对光学性质的分析发现:施加正压强后,光学吸收带边产生蓝移;负压强作用时介电函数虚部尖峰减少,光学吸收带边产生红移;施加压强后BaHfO3的静态介电常数和静态折射率均增大.上述研究表明施加高压有效调制了BaHfO3的电子结构和光学性质,计算结果为BaHfO3光电材料的设计与应用提供了理论依据.

  8. Charge storage characteristics and tunneling mechanism of amorphous Ge-doped HfOx films

    Science.gov (United States)

    Qiu, X. Y.; Zhang, S. Y.; Zhang, T.; Wang, R. X.; Li, L. T.; Zhang, Y.; Dai, J. Y.

    2016-09-01

    Amorphous Ge-doped HfOx films have been deposited on p-Si(100) substrates by means of RF magnetron sputtering. Microstructural investigations reveal the partial oxidation of doped Ge atoms in the amorphous HfOx matrix and the existence of HfSiOx interfacial layer. Capacitance-voltage hysteresis of the Ag-/Ge-doped HfOx/Si/Ag memory capacitor exhibits a memory window of 3.15 V which can maintain for >5 × 104 cycles. Current-voltage characteristics reveal that Poole-Frenkel tunneling is responsible for electron transport in the Ge-doped HfOx film.

  9. Clinical trials update from the Heart Failure Society of America Meeting 2009: FAST, IMPROVE-HF, COACH galectin-3 substudy, HF-ACTION nuclear substudy, DAD-HF, and MARVEL-1.

    Science.gov (United States)

    Lainscak, Mitja; Coletta, Alison P; Sherwi, Nasser; Cleland, John G F

    2010-02-01

    This article presents findings and a commentary on late-breaking trials presented during the meeting of the Heart Failure Society of America in September 2009. Unpublished reports should be considered as preliminary, since analyses may change in the final publication. The FAST trial showed somewhat better performance of intrathoracic impedance for prediction of deterioration in patients with heart failure (HF) when compared with daily weighing. The IMPROVE-HF study reported the benefits of education on the management of patients with systolic HF. Galectin-3 appeared a useful method for improving risk stratification of patients with chronic HF in a substudy of the COACH trial. A nuclear substudy of the HF-ACTION trial failed to demonstrate that resting myocardial perfusion imaging, a measure of myocardial scar and viability, was clinically useful. A small randomized controlled trial (DAD-HF) suggested that the use of low-dose dopamine in patients with acutely decompensated HF was associated with less deterioration in renal function and less hypokalaemia. The MARVEL-1 trial raises further concerns about the safety of myoblast transplantation in ischaemic HF.

  10. The anisotropy of Hf diffusion in {alpha}-Zr

    Energy Technology Data Exchange (ETDEWEB)

    Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Jackman, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada)

    1996-02-01

    Hf diffusion coefficients (D) have been measured ({proportional_to}870-1100 K) in directions parallel (D{sub pa}) and perpendicular (D{sub pe}) to the c-axis of double-faced, single-crystal specimens of both high purity (HP) and nominally pure (NP) {alpha}-Zr. The diffusion profiles were measured by secondary ion mass spectrometry. Hf diffusion in HP {alpha}-Zr is characterised by an activation energy of about 3.0 eV and a pre-exponential factor of about 10{sup -5} m{sup 2}/s. The anisotropy ratio, D{sub pa}/D{sub pe}, is {proportional_to}<1.0 for the HP specimens and mostly >1.0 for the NP specimens. A dependence of D on diffusion time/depth is indicated for some experiments on NP Zr. (orig.).

  11. Photodetachment of HF-in an Electric Field

    Institute of Scientific and Technical Information of China (English)

    WANG De-Hua

    2008-01-01

    @@ Photdetachment of a negative HF-ion in an electric field is studied by using the two-centre model and the closed orbit theory.An analytic formula is presented for the electron flux of HF- in the presence of an electric field.The results show that the oscillation in the electron flux distribution is caused by the rescattering effect of the molecular ion core and the interference betweed the two nuclei.In addition,the interference between the orbits passing through the given spatial point also plays an important role in the electron flux distribution.This study provides a new understanding of the photodetachment of polar molecules in the presence of external field.

  12. Generation of ionospheric ducts by the HAARP HF heater

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J A; Pradipta, R; Burton, L M; Labno, A; Lee, M C [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Watkins, B J; Fallen, C [University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Kuo, S P [New York University, Brooklyn, NY 11201 (United States); Burke, W J [Air Force Research Laboratory, Hanscom AFB, MA 01731 (United States); Mabius, D; See, B Z, E-mail: mclee@mit.edu [Boston University, Boston, MA 02215 (United States)

    2010-12-15

    We report an investigation of ionospheric ducts having the shape of large plasma sheets, generated by vertically transmitted HAARP HF heater waves in several experiments conducted in Gakona, Alaska. Theory predicts that O-mode heater wave-created ionospheric ducts form parallel-plate waveguides within the meridional plane, and those generated by the X-mode heater waves are orthogonal to the meridional plane. Our theoretical prediction is supported by measurements of ionosonde data (namely ionograms), range-time-intensity (RTI) plots of UHF and HF backscatter radars, as well as magnetometer data analyses. When these plasma sheets experienced ExB drifts, they were intercepted by the HAARP UHF radar and seen as slanted stripes in the RTI plots. This striking feature was also observed in our earlier experiments using the Arecibo UHF radar.

  13. Use of GPS network data for HF Doppler measurements interpretation

    CERN Document Server

    Petrova, Inna R; Latypov, Ruslan R

    2014-01-01

    The method of measurement of Doppler frequency shift of ionospheric signal - HF Doppler technique - is one of well-known and widely used methods of ionosphere research. It allows to research various disturbances in the ionosphere. There are some sources of disturbances in the ionosphere. These are geomagnetic storms, solar flashes, metrological effects, atmospheric waves. This method allows to find out the influence of earthquakes, explosions and other processes on the ionosphere, which occur near to the Earth. HF Doppler technique has the high sensitivity to small frequency variations and the high time resolution, but interpretation of results is difficult. In this work we make an attempt to use GPS data for Doppler measurements interpretation. Modeling of Doppler frequency shift variations with use of TEC allows to separate ionosphere disturbances of medium scale.

  14. Imaging HF-induced large-scale irregularities above HAARP

    Science.gov (United States)

    Djuth, Frank T.; Reinisch, Bodo W.; Kitrosser, David F.; Elder, John H.; Snyder, A. Lee; Sales, Gary S.

    2006-02-01

    The University of Massachusetts-Lowell digisonde is used with the HAARP high-frequency (HF), ionospheric modification facility to obtain radio images of artificially-produced, large-scale, geomagnetic field-aligned irregularities. F region irregularities generated with the HAARP beam pointed in the vertical and geomagnetic field-aligned directions are examined in a smooth background plasma. It is found that limited large-scale irregularity production takes place with vertical transmissions, whereas there is a dramatic increase in the number of source irregularities with the beam pointed parallel to the geomagnetic field. Strong irregularity production appears to be confined to within ~5° of the geomagnetic zenith and does not fill the volume occupied by the HF beam. A similar effect is observed in optical images of artificial airglow.

  15. Performance Analysis of HF Band FB-MC-SS

    Energy Technology Data Exchange (ETDEWEB)

    Hussein Moradi; Stephen Andrew Laraway; Behrouz Farhang-Boroujeny

    2016-01-01

    Abstract—In a recent paper [1] the filter bank multicarrier spread spectrum (FB-MC-SS) waveform was proposed for wideband spread spectrum HF communications. A significant benefit of this waveform is robustness against narrow and partial band interference. Simulation results in [1] demonstrated good performance in a wideband HF channel over a wide range of conditions. In this paper we present a theoretical analysis of the bit error probably for this system. Our analysis tailors the results from [2] where BER performance was analyzed for maximum ration combining systems that accounted for correlation between subcarriers and channel estimation error. Equations are give for BER that closely match the simulated performance in most situations.

  16. Solubility limits on radionuclide dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Kerrisk, J.F.

    1984-12-31

    This paper examines the effects of solubility in limiting dissolution rates of a number of important radionuclides from spent fuel and high-level waste. Two simple dissolution models were used for calculations that would be characteristics of a Yucca Mountain repository. A saturation-limited dissolution model, in which the water flowing through the repository is assumed to be saturated with each waste element, is very conservative in that it overestimates dissolution rates. A diffusion-limited dissolution model, in which element-dissolution rates are limited by diffusion of waste elements into water flowing past the waste, is more realistic, but it is subject to some uncertainty at this time. Dissolution rates of some elements (Pu, Am, Sn, Th, Zr, Sm) are always limited by solubility. Dissolution rates of other elements (Cs, Tc, Np, Sr, C, I) are never solubility limited; their release would be limited by dissolution of the bulk waste form. Still other elements (U, Cm, Ni, Ra) show solubility-limited dissolution under some conditions. 9 references, 3 tables.

  17. Investigation of new type Cu-Hf-Al bulk glassy alloys

    Science.gov (United States)

    Nagy, E.; Rontó, V.; Sólyom, J.; Roósz, A.

    2009-01-01

    In the last years new type Cu-Hf-Al ternary alloys were developed with high glass forming ability and ductility. The addition of Al to Cu-Hf alloys results in improvements in glass formation, thermal stability and mechanical properties of these alloys. We have investigated new Cu-based bulk amorphous alloys in Cu-Hf-Al ternary system. The alloys with Cu49Hf42Al9, Cu46Hf45Al9, Cu50Hf42.5Al7.5 and Cu50Hf45Al5 compositions were prepared by arc melting. The samples were made by centrifugal casting and were investigated by X-ray diffraction method. Thermodynamic properties were examined by differential scanning calorimetry and the structure of the crystallising phases by scanning electron microscopy. The determination of liquidus temperatures of alloys were measured by differential thermal analysis.

  18. First-principles studies of HF molecule adsorption on intrinsic graphene and Al-doped graphene

    Science.gov (United States)

    Sun, Yuanyuan; Chen, Li; Zhang, Feiwu; Li, Daoyong; Pan, Hongzhe; Ye, Jun

    2010-10-01

    In the search for a high-sensitivity sensor for HF gas, the adsorption of HF molecules on both intrinsic and Al-doped graphene sheets is studied by first-principles calculations. We find that the adsorption mechanisms of HF molecules are different for intrinsic graphene and Al-doped graphene. Al-doped graphene has higher adsorption energy and shorter connecting distance to the HF molecule than intrinsic graphene. The calculated net electron transfers, electronic density difference images and densities of states give evidence that the adsorption of HF molecules on Al-doped graphene is by chemisorption, while there is weak physisorption on intrinsic graphene. Therefore, Al-doped graphene can be expected to have applications as a novel sensor for the detection of HF gas. The HF molecules adsorbed on Al-doped graphene material can be reactivated by applying an external electric field of 0.013 a.u.

  19. Ferroelectric HfO2 for Emerging Ferroelectric Semiconductor Devices

    Science.gov (United States)

    Florent, Karine

    The spontaneous polarization in ferroelectrics (FE) makes them particularly attractive for non-volatile memory and logic applications. Non-volatile FRAM memories using perovskite structure materials, such as Lead Zirconate Titanate (PZT) and Strontium Bismuth Tantalate (SBT) have been studied for many years. However, because of their scaling limit and incompatibility with CMOS beyond 130 nm node, floating gate Flash memory technology has been preferred for manufacturing. The recent discovery of ferroelectricity in doped HfO2 in 2011 has opened the door for new ferroelectric based devices compatible with CMOS technology, such as Ferroelectric Field Effect Transistor (FeFET) and Ferroelectric Tunnel Junctions (FTJ). This work began with developing ferroelectric hysteresis characterization capabilities at RIT. Initially reactively sputtered aluminum doped HfO 2 films were investigated. It was observed that the composition control using co-sputtering was not achievable within the existing capabilities. During the course of this study, collaboration was established with the NaMLab group in Germany to investigate Si doped HfO2 deposited by Atomic Layer Deposition (ALD). Metal Ferroelectric Metal (MFM) devices were fabricated using TiN as the top and bottom electrode with Si:HfO2 thickness ranging from 6.4 nm to 22.9 nm. The devices were electrically tested for P-E, C-V and I-V characteristics. Structural characterizations included TEM, EELS, XRR, XRD and XPS/Auger spectroscopy. Higher remanant polarization (Pr) was observed for films of 9.3 nm and 13.1 nm thickness. Thicker film (22.9 nm) showed smaller Pr. Devices with 6.4 nm thick films exhibit tunneling behavior showing a memristor like I-V characteristics. The tunnel current and ferroelectricity showed decrease with cycling indicating a possible change in either the structure or the domain configurations. Theoretical simulations using the improved FE model were carried out to model the ferroelectric behavior of

  20. Centrifugal stretching of 170Hf in the interacting boson model

    Directory of Open Access Journals (Sweden)

    Werner V.

    2014-03-01

    Full Text Available We present the results of a recent experiment to deduce lifetimes of members of the ground state rotational band of 170Hf, which show the effect of centrifugal stretching in this deformed isotope. Results are compared to the geometrical confined beta-soft(CBS rotor model, as well as to the interacting boson model (IBM. Two methods to correct for effects due to the finite valence space within the IBM are proposed.

  1. Electrochemical characterization of cast Ti-Hf binary alloys.

    Science.gov (United States)

    Cai, Z; Koike, M; Sato, H; Brezner, M; Guo, Q; Komatsu, M; Okuno, O; Okabe, T

    2005-05-01

    This study characterized the electrochemical behavior of Ti-Hf binary alloys in a simulated oral environment. Ti-Hf alloys (10, 20, 25, 30, 35 and 40 mass% Hf) were prepared by arc-melting titanium sponge and hafnium sponge. Specimens of each alloy (n = 4) were prepared using a dental titanium casting system with a MgO-based investment. Specimens were inspected with X-ray radiography to ensure minimal internal porosity. Castings (n = 4) made from pure titanium and commercially pure titanium were used as controls. The ground flat surface (10 mm x 10 mm) on each specimen where approximately 30 microm was removed was used for the characterization. Sixteen-hour open-circuit potential (OCP) measurement, linear polarization and potentiodynamic cathodic polarization were performed sequentially in aerated (air + 10% CO2) MTZ synthetic saliva at 37 degrees C. Potentiodynamic anodic polarization was conducted in the same medium but deaerated (N2 + 10% CO2) 2 h before and during testing. Polarization resistance (R(P)) and Tafel slopes were determined, as were corrosion current density (I(CORR)) and passive current density (I(PASS)). Results were subjected to nonparametric statistical analysis (alpha = 0.05). The OCP stabilized (mean values -229 mV to -470 mV vs. SCE) for all specimens after the 16-h immersion. Similar passivation was observed for all the metals on their anodic polarization diagrams. The Kruskal-Wallis test showed significant differences in OCP among the test groups (p = 0.006). No significant differences were found in R(P), I(CORR) or I(PASS) among all the metals (p>0.3). Results indicate that the electrochemical behavior of the Ti-Hf alloys examined resembles that of pure titanium.

  2. Hf--Co--B alloys as permanent magnet materials

    Science.gov (United States)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0B.sub.Y, wherein 0.ltoreq.X<2 and 0

  3. Ionizing wave via high-power HF acceleration

    CERN Document Server

    Mishin, Evgeny

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  4. Study on Preparation of 182Hf AMS Standards

    Institute of Scientific and Technical Information of China (English)

    YINXin-yi; JIANGShan; HEMing; ZHANGChun-hua; ZHANGSheng-dong

    2003-01-01

    The neutron-rich isotope 182Hf with its half-life of (9±2)×106 a produced by neutron activation can be used to determine the neutron flux of some places, in order to study the transport of radioactive nuclides and the safe disposal of nuclear waste. AMS is a kind of relative measurement method with high sensitivity (10-15), it requires corresponding standard samples.

  5. Ionizing wave via high-power HF acceleration

    OpenAIRE

    Mishin, Evgeny; Pedersen, Todd

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  6. On the Onset of HF-Induced Airglow at HAARP

    Science.gov (United States)

    2007-11-02

    AFRL-VS-HA-TR-2005-1061 JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 109, A02305, doi:10.1029/2003JA010205, 2004 On the onset of HF-induced airglow at HAARP ...line) during the February 2002 campaign at the High Frequency Active Auroral Research Program ( HAARP ) heating facility are analyzed. We find that... HAARP , J. Geophys. Res., 109, A02305, doi: 10.1029/2003JA010205. 1. Introduction known as the parametric decay (PDI) or oscillating two- [2] A

  7. HF Over-the-Horizon Radar System Performance Analysis

    Science.gov (United States)

    2007-09-01

    target detection technique and radar equations are applied. Chapter V uses PROPLAB model simulation to bring in the principle of raytracing and... RADAR SYSTEM PERFORMANCE ANALYSIS by Bin-Yi Liu September 2007 Thesis Co-Advisors: Phillip E. Pace Jeffrey B. Knorr THIS PAGE...Thesis 4. TITLE AND SUBTITLE HF Over-the-Horizon Radar System Performance Analysis 6. AUTHOR(S) Bin-Yi Liu 5. FUNDING NUMBERS 7. PERFORMING

  8. Wideband high frequency (HF) skywave channel parameters from narrowband measurements

    Science.gov (United States)

    Hausman, Cynthia L.; Uffelman, Donald R.; Walton, Thomas L.

    The HF wideband channel allow the use of spread-spectrum techniques to provide covert communications with low probability of intercept (LPI) and antijam protection. The objective of this work is to determine the extent to which oblique narrowband channel measurements can be used to infer effects in the wideband skywave channel. If oblique narrowband channel measurements can be used as a basis for developing wideband channel models, a large number of existing narrowband measurements can be made available for this task.

  9. Detection of HCl and HF by TTFMS and WMS.

    Science.gov (United States)

    De Luca, Anna Chiara; Pesce, Giuseppe; Rusciano, Giulia; Sasso, Antonio

    2006-04-01

    In this work we discuss on a compact spectrometer based on DFB diode lasers for detection of chloridric and fluoridric acids. HCl and HF concentrations are determined through optical absorption of the P(4) line (lambda=1.7 microm) and the R(3) line (lambda=1.3 microm), respectively. Both lines belong to first overtone vibrational bands and their line strengths are 7.8 x 10(-21)cm/molecule for HCl and 2.8 x 10(-20)cm/molecule for HF. We chose these lines for their relative high intensities and because they are quite far from water vapour lines which represent the main interfering gas for trace-gases analysis. To detect these species we used two different high frequency modulation techniques: two-tone frequency modulation spectroscopy (f(1)=800 MHz and f(2)=804 MHz) was used for HCl while for HF we followed a simpler approach based on wavelength modulation spectroscopy (f=600 kHz). We demonstrate that the two techniques provide comparable detection limit of about 80 ppbV at atmospheric pressure. Positive testing of our spectrometer makes it suitable for in situ measurements of exhaust gases coming from waste incinerators.

  10. Multiple excitation modes in 163Hf

    DEFF Research Database (Denmark)

    Yadav, Rachita; Ma, J.C.; Marsh, J.C.

    2014-01-01

    Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five-quasipar......Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five......-quasiparticle configurations, two γ−vibrational bands coupled to the i13/2 excitation were also observed. The lowest level of a newly identified, negative-parity band is proposed to be the ground state of the nucleus. A systematic delay of the high-spin proton crossing frequency with increasing quadrupole deformation from Hf...

  11. Electronic structures and properties of Ti, Zr and Hf metals

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The electronic structures of pure Ti, Zr and Hf metals with hcp structure were determined by one-atom (OA) theory. According to the electronic structures of these metals,their potential curves, cohesive energies, lattice constants, elasticities and the temperature dependence of linear thermal expansion coefficients were calculated. The electronic structures and characteristic properties of these metals with bcc and fcc structures and liquids were also studied. The results show that the electronic structures of Ti, Zr and Hf metals are respectively [Ar](3dn)0.481 0(3dc)2.085 7(4sc)1.000 0(4sf)0.433 3, [Kr](4dn)0.396 8(4dc)2.142 8(5sc)1.262 0(5sf)0.198 4, [Xe](5dn)0.368 0(5dc)2.041 4(6sc)1.406 6(6sf)0.184 0. It is explained why the pure Ti, Zr and Hf metals with hcp and bcc structures can exist naturally, while those with fcc structure can not.

  12. Lu-Hf and Sm-Nd garnet geochronology

    DEFF Research Database (Denmark)

    Smit, Matthijs Arjen; Scherer, Erik E.; Mezger, Klaus

    2013-01-01

    are similar among grains having radii larger than 1.3 mm (weighted mean: 2714±6 Ma2714±6 Ma; 2 s.d.) and up to 20 Myr younger for finer fractions. In contrast, Sm–Nd dates are equal to or younger than the 2641–2637 Ma age of peak metamorphism. The roles of concurrently digested inclusions and core–rim Lu......To investigate the systematics of the 176Lu–176Hf and 147Sm–143Nd garnet chronometers, we performed REE and isotope analyses on garnet crystals of different size (0.55–3.1 mm radius) from a single granulite specimen (Archean Pikwitonei Granulite Domain, Manitoba, Canada). The Lu–Hf dates....../Sm fractionation are quantitatively evaluated and excluded as causes for the observed age heterogeneity. Instead, the isotope dates are interpreted to reflect partial loss of radiogenic 176Hf and 143Nd, and are used to constrain the systematics of the garnet chronometers at high temperature. The data constrain...

  13. TID measurement using oblique transmissions of HF pulses

    Science.gov (United States)

    Galkin, Ivan; Reinisch, Bodo; Huang, Xueqin; Paznukhov, Vadym; Hamel, Ryan; Kozlov, Alexander; Belehaki, Anna

    2017-04-01

    The Traveling Ionospheric Disturbance (TID), a wave-like signature of moving plasma density modulation in the ionosphere, is widely acknowledged for its utility in backtracking the anomalous events responsible for the TID generation, and as a major inconvenience to high-frequency (HF) operational systems because of its deleterious impact on the accuracy of navigation and geolocation. The pilot project "Net-TIDE" for the real-time detection and evaluation of TIDs began its operation in 2016 based on the remote-sensing data from synchronized, network-coordinated HF sounding between pairs of DPS4D ionosondes at five participating observatories in Europe. Measurement of all signal properties (Doppler frequency, angle of arrival, and time-of-flight from transmitter to receiver) proved to be instrumental in detecting the TID and deducing the TID parameters: amplitude, wavelength, phase velocity, and direction of propagation. Processing of the measured HF signal data required a specialized signal processing technique that is capable of consistently extracting different signals that have propagated along different ionospheric paths. The multi-path signal environment proved to be the greatest challenge for the reliable TID specification by Net-TIDE, demanding the development of an intelligent system for "signal tracking". The intelligent system is based on a neural network model of a pre-attentive vision capable of extracting continuous signal tracks from the multi-path signal ensemble. Specific examples of the Net-TIDE algorithm suite operation and its suitability for a fully automated TID warning service are discussed.

  14. A Soluble, Folded Protein without Charged Amino Acid Residues

    DEFF Research Database (Denmark)

    Højgaard, Casper; Kofoed, Christian; Espersen, Roall

    2016-01-01

    Charges are considered an integral part of protein structure and function, enhancing solubility and providing specificity in molecular interactions. We wished to investigate whether charged amino acids are indeed required for protein biogenesis and whether a protein completely free of titratable...... side chains can maintain solubility, stability, and function. As a model, we used a cellulose-binding domain from Cellulomonas fimi, which, among proteins of more than 100 amino acids, presently is the least charged in the Protein Data Bank, with a total of only four titratable residues. We find...

  15. Rocky core solubility in Jupiter and giant exoplanets

    CERN Document Server

    Wilson, Hugh F

    2011-01-01

    Gas giants are believed to form by the accretion of hydrogen-helium gas around an initial protocore of rock and ice. The question of whether the rocky parts of the core dissolve into the fluid H-He layers following formation has significant implications for planetary structure and evolution. Here we use ab initio calculations to study rock solubility in fluid hydrogen, choosing MgO as a representative example of planetary rocky materials, and find MgO to be highly soluble in H for temperatures in excess of approximately 10000 K, implying significant redistribution of rocky core material in Jupiter and larger exoplanets.

  16. Rocky core solubility in Jupiter and giant exoplanets.

    Science.gov (United States)

    Wilson, Hugh F; Militzer, Burkhard

    2012-03-16

    Gas giants are believed to form by the accretion of hydrogen-helium gas around an initial protocore of rock and ice. The question of whether the rocky parts of the core dissolve into the fluid H-He layers following formation has significant implications for planetary structure and evolution. Here we use ab initio calculations to study rock solubility in fluid hydrogen, choosing MgO as a representative example of planetary rocky materials, and find MgO to be highly soluble in H for temperatures in excess of approximately 10,000 K, implying the potential for significant redistribution of rocky core material in Jupiter and larger exoplanets.

  17. High-spin positive-parity states in 179Hf studied by the 180Hf(τ, α) 179Hf reaction AT 32 MeV

    Science.gov (United States)

    Thorsteinsen, T. F.; Løvhøiden, G.; Vaagen, J. S.; Bjørnberg, A.; Burke, D. G.

    1981-06-01

    Full angular distributions are presented for states populated in the reaction 180Hf(τ, α) 179Hf at 32 MeV beam energy. Positive-parity states associated with the i {13}/{2} unique parity intruder orbital are given special attention. Thus, angular distributions for the five first members of the [624 {9}/{2}] groundstate sequence are given, as well as for a number of more highly excited states, some being new assignments. The distribution of l = 6 transfer strength is quite characteristic, two {13}/{2}+ states being substantially more populated than the rest. The characteristic features of the data are explained by a quasiparticle-rotor calculation employing deformed Woods-Saxon orbitals, but only if the hexadecapole shape parameter of the nuclear potential is β 4 ˜ -0.08. The often anomalous differential cross sections for I π ≠ {13}/{2}+ band members are well accounted for by a rotor model CCBA calculation employing transfer form factors extracted from the orbitals of the deformed Woods-Saxon field, and including non-adiabatic Coriolis mixing effects.

  18. Hf isotopic compositions of the standard zircons for U-Pb dating

    Institute of Scientific and Technical Information of China (English)

    XU Ping; WU Fuyuan; XIE Liewen; YANG Yueheng

    2004-01-01

    Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in either in situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable 176Hf/177Hf isotopic ratios for zircon in either in situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3,CN92-1 and TEMORA, are measured, respectively. The obtained 176Hf/177Hf ratios are 0.282316+4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20,2σ-) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA,respectively, with 176Lu/177Hf ratios of ~0.00031, 0.000036,0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in 176Hf/177Hf and 176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

  19. An experimental study of the solubility and speciation of tantalum in fluoride-bearing aqueous solutions at elevated temperature

    Science.gov (United States)

    Timofeev, A.; Migdisov, Art. A.; Williams-Jones, A. E.

    2017-01-01

    The solubility of Ta2O5 (solid) and the speciation of tantalum in HF-bearing aqueous solutions have been determined at temperatures of 100-250 °C and vapour-saturated water pressure. Tantalum is transported as the species Ta(OH)50 at low HF concentration and pH ∼1-3. At higher HF concentration, tantalum mobility is controlled by the species TaF3(OH)3- and TaF50; the presence of TaF50 is only evident at ⩽150 °C. Equilibrium constants range from -17.4 ± 0.45 to -16.4 ± 0.12 for the formation of Ta(OH)50 from crystalline Ta2O5 and from -8.24 ± 0.64 to -8.55 ± 0.68 for the formation of TaF3(OH)3- at 100 and 250 °C, respectively. For TaF50, they were determined to be 0.13 at 100 °C and -0.35 at 150 °C. In many respects, the behaviour of tantalum in acidic fluoride-bearing solutions is similar to that of niobium. The solubility of Ta2O5 (solid) is not dependent on HF concentration in fluoride-poor fluids, but rises rapidly at higher HF concentration. However, at the conditions of our experiments, namely a pH of ∼2, temperature up to 250 °C, and a wide range of HF concentrations, Ta2O5 (solid) solubility is almost invariably lower than that of Nb2O5 (solid). Modelling of Nb and Ta leaching confirmed the preferential mobility of niobium under most conditions expected in natural fluoride-rich hydrothermal systems. This modelling also demonstrated that both niobium and tantalum are rapidly deposited upon removal of fluoride from an acidic brine. As a result of hydrothermal alteration, the Nb/Ta ratios of secondary minerals may increase relative to those of the primary mineral, or remain largely unaffected, depending on the pH of the fluid.

  20. Increased expression of cytokines, soluble cytokine receptors, soluble apoptosis ligand and apoptosis in dengue.

    Science.gov (United States)

    Arias, Julia; Valero, Nereida; Mosquera, Jesús; Montiel, Milagros; Reyes, Eduardo; Larreal, Yraima; Alvarez-Mon, Melchor

    2014-03-01

    Several studies have been performed to determine biomarkers that define the risk factors to developing severe forms of dengue. In this study, the levels of TNF-α, IL-6, IL-1, IL-17, soluble interleukin-1 receptor like 1 protein (sST2), soluble TNF-related apoptosis-inducing ligand (sTRAIL), IL-12 and soluble receptors for TNF (sTNF-RI and sTNF-RII) were determined by ELISA in dengue patients and monocyte/macrophage cultures. Dengue was classified as dengue without warning symptoms (DNWS), with warning symptoms (DWWS) and severe dengue (SD). High values of IL-6, sTNFRI, sTNFRII and sST2 were observed in DWWS and/or SD and IL-12 and sTRAIL in DNWS. TNF-α and IL-17 were increased not associated to the disease severity. High production of TNF-α, IL-1β, IL-12, IL-17, sST2 and sTRAIL and apoptosis expression were observed in dengue monocyte/macrophage cultures. This study shows that beneficial or deleterious biomarkers can be present in dengue regardless the disease severity and that monocytes may be in part the source of studied molecules.

  1. Electrical characteristics of MOS capacitor with HfTiON gate dielectric and HfTiSiON interlayer

    Institute of Scientific and Technical Information of China (English)

    Chen Wei-Bing; Xu Jing-Ping; Lai Pui-To; Li Yan-Ping; Xu Sheng-Guo; Chan Chu-Lok

    2006-01-01

    The paper reports that HfTiO dielectric is deposited by reactive co-sputtering of Hf and Ti targets in an Ar/O2 ambience, followed by an annealing in different gas ambiences of N2, NO and NHa at 600°C for 2 min. Capacitance-voltage and gate-leakage properties are characterized and compared. The results indicate that the NO-annealed sample exhibits the lowest interface-state and dielectric-charge densities and best device reliability. This is attributed to the fact that nitridation can create strong Si≡N bonds to passivate dangling Si bonds and replace strained Si- O bonds, thus the sample forms a hardened dielectric/Si interface with high reliability.

  2. Nightside studies of coherent HF Radar spectral width behaviour

    Directory of Open Access Journals (Sweden)

    E. E. Woodfield

    Full Text Available A previous case study found a relationship between high spectral width measured by the CUTLASS Finland HF radar and elevated electron temperatures observed by the EISCAT and ESR incoherent scatter radars in the post-midnight sector of magnetic local time. This paper expands that work by briefly re-examining that interval and looking in depth at two further case studies. In all three cases a region of high HF spectral width (>200 ms-1 exists poleward of a region of low HF spectral width (<200 ms-1. Each case, however, occurs under quite different geomagnetic conditions. The original case study occurred during an interval with no observed electrojet activity, the second study during a transition from quiet to active conditions with a clear band of ion frictional heating indicating the location of the flow reversal boundary, and the third during an isolated sub-storm. These case studies indicate that the relationship between elevated electron temperature and high HF radar spectral width appears on closed field lines after 03:00 magnetic local time (MLT on the nightside. It is not clear whether the same relationship would hold on open field lines, since our analysis of this relationship is restricted in latitude. We find two important properties of high spectral width data on the nightside. Firstly the high spectral width values occur on both open and closed field lines, and secondly that the power spectra which exhibit high widths are both single-peak and multiple-peak. In general the regions of high spectral width (>200 ms-1 have more multiple-peak spectra than the regions of low spectral widths whilst still maintaining a majority of single-peak spectra. We also find that the region of ion frictional heating is collocated with many multiple-peak HF spectra. Several mechanisms for the generation of high spectral width have been proposed which would produce multiple-peak spectra, these are discussed in relation to

  3. Age and origin of post collision Baltoro granites, south Karakoram, North Pakistan: Insights from in-situ U-Pb, Hf and oxygen isotopic record of zircons

    Science.gov (United States)

    Mahar, Munazzam Ali; Mahéo, Gweltaz; Goodell, Philip C.; Pavlis, Terry L.

    2014-09-01

    Origin of post collision plutonism is critical to understand the tectonothermal evolution of the over thickened continental crust in collision zones. This has proven difficult to reconcile with the conventional whole rock geochemical and field based studies alone. We report in-situ study of zircon U-Pb, Hf and O isotopes from five samples of the Baltoro Plutonic Unit (BPU) in south Karakoram. The plutonic unit is the western part of the southern Asian margin of the India-Asia convergent zone. Baltoro granites and a biotite-rich enclave yielded similar and overlapping U-Pb ages ranging from 26 to 15 Ma. Hafnium isotopic composition (εHf (0)) is very heterogeneous ranging from - 17.1 to + 4.4 while the oxygen isotopic composition of the granites is homogeneous with mean δ18O ranging from 7.2 to 9.4‰. Based on U-Pb geochronology and Hf-O isotopic composition, the involvement of two main sources is suggested (1) Cretaceous calc-alkaline Karakoram crust and (2) Karakoram gneisses. Moreover, possible involvement of metasomatized Asian lithospheric mantle is supported by elevated oxygen composition of granites and identical Hf composition of biotite-rich enclave to the mantle derived Baltoro lamprophyre. However, direct contribution from juvenile pristine mantle is unlikely as no juvenile mantle type Hf and oxygen values were obtained. This also precludes the involvement of southward juvenile arc related component of Kohistan-Ladakh batholith. Our new U-Pb and Hf data are comparable to the Mesozoic Karakoram batholith, Miocene two-mica leucogranites in the Pangong Range and magmatism from the Lhasa terrane in south Tibet, suggesting a genetic link between the Karakoram and the rocks to the east. This magmatic event is best explained by lower crust partial melting promoted by both thermal equilibration following crustal thickening and heat advection by ultrapotassic magmas associated with the breakoff of the Indian continental margin.

  4. Solubility of sparingly soluble drug derivatives of anthranilic acid.

    Science.gov (United States)

    Domańska, Urszula; Pobudkowska, Aneta; Pelczarska, Aleksandra

    2011-03-24

    This work is a continuation of our systematic study of the solubility of pharmaceuticals (Pharms). All substances here are derivatives of anthranilic acid, and have an anti-inflammatory direction of action (niflumic acid, flufenamic acid, and diclofenac sodium). The basic thermal properties of pure Pharms, i.e., melting and glass-transition temperatures as well as the enthalpy of melting, have been measured with the differential scanning microcalorimetry technique (DSC). Molar volumes have been calculated with the Barton group contribution method. The equilibrium mole fraction solubilities of three pharmaceuticals were measured in a range of temperatures from 285 to 355 K in three important solvents for Pharm investigations: water, ethanol, and 1-octanol using a dynamic method and spectroscopic UV-vis method. The experimental solubility data have been correlated by means of the commonly known G(E) equation: the NRTL, with the assumption that the systems studied here have revealed simple eutectic mixtures. pK(a) precise measurement values have been investigated with the Bates-Schwarzenbach spectrophotometric method.

  5. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    CERN Document Server

    Muto, S; Bingham, C R; Stone, J R; Walker, P M; Audi, G; Gaulard, C; Köster, U; Nikolov, J; Nishimura, K; Ohtsubo, T; Podolyak, Z; Risegari, L; Simpson, G S; Veskovic, M; Walters, W B

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV and on the 9/2$^+$, 0.663 ns, isomer at 321 keV. The new results are discussed in the light of the recently reported finding of systematic dependence of the behavior of the g$_{\\rm R}$ parameter upon the quasi-proton and quasi-neutron make up of high-K isomeric states in this region.

  6. Polarity reversion of the operation mode of HfO2-based resistive random access memory devices by inserting Hf metal layer.

    Science.gov (United States)

    Peng, Ching-Shiang; Chang, Wen-Yuan; Lin, Ming-Ho; Chen, Wei-Su; Chen, Frederick; Tsai, Ming-Jinn

    2013-03-01

    The reversion of polarity within bipolar resistive switching operation occurs in Pt/HfO2/TiN and Pt/Hf/HfO2/TiN resistive random access memory devices. This reversion of voltage polarity is the result of interface generation which induces a conduction mechanism transformation from Poole-Frenkel emission to space charge limited current mechanism. To prove the reversion of polarity, this study uses curve fitting of I-V relations to verify the conduction mechanism theoretically and physical analysis to verify the oxygen ion distribution practically. The proposed Pt/Hf/HfO2/TiN devices exhibit good resistive switching characteristics, such as good uniformity, low voltage operation, robust endurance (10(3) dc sweep), and long retention (3 x 10(4) s at 85 degrees C).

  7. Vertically oriented few-layered HfS2 nanosheets: growth mechanism and optical properties

    Science.gov (United States)

    Zheng, Binjie; Chen, Yuanfu; Wang, Zegao; Qi, Fei; Huang, Zhishuo; Hao, Xin; Li, Pingjian; Zhang, Wanli; Li, Yanrong

    2016-09-01

    For the first time, large-area, vertically oriented few-layered hafnium disulfide (V-{{{HfS}}}2) nanosheets have been grown by chemical vapor deposition. The individual {{{HfS}}}2 nanosheets are well [001] oriented, with highly crystalline quality. Far different from conventional van der Waals epitaxial growth mechanism for two-dimensional transition metal dichalcogenides, a novel dangling-bond-assisted self-seeding growth mechanism is proposed to describe the growth of V-{{{HfS}}}2 nanosheets: difficult migration of {{{HfS}}}2 adatoms on substrate surface results in {{{HfS}}}2 seeds growing perpendicularly to the substrate; V-{{{HfS}}}2 nanosheets inherit the growth direction of {{{HfS}}}2 seeds; V-{{{HfS}}}2 nanosheets further expand in the in-plane direction with time evolution. Moreover, the V-{{{HfS}}}2 nanosheets show strong and broadened photons absorption from near infrared to ultraviolet; the V-{{{HfS}}}2-based photodetector exhibits an ultrafast photoresponse time of 24 ms, and a high photosensitivity ca. 103 for 405 nm laser.

  8. Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

    Science.gov (United States)

    Shukla, Dhwanil; Noebe, Ronald D.; Stebner Aaron P.

    2013-01-01

    An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

  9. Soluble-oil cutting fluid

    Energy Technology Data Exchange (ETDEWEB)

    Rawlinson, A.P.; Whitby, R.D.; White, J.

    1989-04-11

    A composition for the preparation of a soluble oil for use in a cutting fluid comprises a mineral oil and, as an emuslifier, an effective amount of a sulfonate of a branched polymer of a C/sub 3/ to C/sub 5/ olefin. Preferably the polyolefin chain of the sulphonate has an average molecular weight in the range 275 to 560 and the polyolefin is polyisobutene. A soluble oil can be prepared from the above composition by the addition of a conventional corrosion inhibitor and diluted with water to make a cutting fluid. Advantages of the novel emulsifier are that it is resistant to breakdown by micro-organisms and does not require the addition of a coupling agent.

  10. Effectiveness of fluidized pellet bed for removing soluble contaminants

    Institute of Scientific and Technical Information of China (English)

    WANG Xiaochang; LI Zhihua; WANG Zhen; LI Jinrong; LI Jiayu; CHEN Rong

    2009-01-01

    Fluidized pellet bed (FPB) has been successfully applied in water and wastewater treatment. However, the removal mechanism of contaminants especially the soluble ones, is still unclear. This study aimed to evaluate the effectiveness of FPB reactor for removing soluble contaminants from synthetic wastewater. By only coagulation through jar test operation with addition of polyaluminium chloride (PACl) as primary coagulant and polyacryamide (PAM) as coagulant-aid, the removals of soluble chemical oxygen demand (COD), suspended solids (SS), total phosphorus (TP), and NH4+-N were found to be only 2.2%--7.5%, 5.7%--25.5%, and 9.9%--18.5%, respectively. However, by FPB operation under the same dosage of coagulants, these values increased to 82.7%, 37.2%, and 50%, indicating that the formation of pellets in the FPB effectively enhanced the removal of soluble contaminants. By careful comparison of the settleablility and filterability of the pollutants after coagulation, the originally soluble contaminants could be divided into three groups, namely: (i) coagulated-and-settleable, (ii) coagulated-but-nonsettleable, and (iii) uncoagulable. It was found that not only the first two groups but also a large part of the third group could be effectively removed by FPB operation. However, the mechanism for the removal of the uncoagulable pollutants by FPB operation still needs further investigation.

  11. Effects of HfB2 and HfN Additions on the Microstructures and Mechanical Properties of TiB2-Based Ceramic Tool Materials

    Directory of Open Access Journals (Sweden)

    Jing An

    2017-04-01

    Full Text Available The effects of HfB2 and HfN additions on the microstructures and mechanical properties of TiB2-based ceramic tool materials were investigated. The results showed that the HfB2 additive not only can inhibit the TiB2 grain growth but can also change the morphology of some TiB2 grains from bigger polygons to smaller polygons or longer ovals that are advantageous for forming a relatively fine microstructure, and that the HfN additive had a tendency toward agglomeration. The improvement of flexural strength and Vickers hardness of the TiB2-HfB2 ceramics was due to the relatively fine microstructure; the decrease of fracture toughness was ascribed to the formation of a weaker grain boundary strength due to the brittle rim phase and the poor wettability between HfB2 and Ni. The decrease of the flexural strength and Vickers hardness of the TiB2-HfN ceramics was due to the increase of defects such as TiB2 coarse grains and HfN agglomeration; the enhancement of fracture toughness was mainly attributed to the decrease of the pore number and the increase of the rim phase and TiB2 coarse grains. The toughening mechanisms of TiB2-HfB2 ceramics mainly included crack bridging and transgranular fracture, while the toughening mechanisms of TiB2-HfN ceramics mainly included crack deflection, crack bridging, transgranular fracture, and the core-rim structure.

  12. Crystallography of the NiHfSi Phase in a NiAl (0.5 Hf) Single-Crystal Alloy

    Science.gov (United States)

    Garg, A.; Noebe, R. D.; Darolia, R.

    1996-01-01

    Small additions of Hf to conventionally processed NiAl single crystals result in the precipitation of a high density of cuboidal G-phase along with a newly identified silicide phase. Both of these phases form in the presence of Si which is not an intentional alloying addition but is a contaminant resulting from contact with the ceramic shell molds during directional solidification of the single-crystal ingots. The morphology, crystal structure and Orientation Relationship (OR) of the silicide phase in a NiAl (0.5 at.%Hf) single-crystal alloy have been determined using transmission electron microscopy, electron microdiffraction and energy dispersive X-ray spectroscopy. Qualitative elemental analysis and indexing of the electron microdiffraction patterns from the new phase indicate that it is an orthorhombic NiHfSi phase with unit cell parameters, a = 0.639 nm, b = 0.389 nm and c = 0.72 nm, and space group Pnma. The NiHfSi phase forms as thin rectangular plates on NiAl/111/ planes with an OR that is given by NiHfSi(100))(parallel) NiAl(111) and NiHfSi zone axes(010) (parallel) NiAl zone axes (101). Twelve variants of the NiHfSi phase were observed in the alloy and the number of variants and rectangular morphology of NiHfSi plates are consistent with symmetry requirements. Quenching experiments indicate that nucleation of the NiHfSi phase in NiAI(Hf) alloys is aided by the formation of NiAl group of zone axes (111) vacancy loops that form on the NiAl /111/ planes.

  13. Soluble Precursor Route to Polyanilines

    Science.gov (United States)

    1993-01-01

    condensation were not successful, but further work produced polymer under the following conditions: Synthesis Diketone I (2.40 g, 10.0 mmol) in 10 mL...goal of producing a processible form of the conducting polymer polyaniline (PANI), the Phase I program concentrated on development of the synthesis of...extension of the original research to a Phase II effort. Diketone - Diamine Polycondensation Towards a Soluble PAni Precursor To achieve the

  14. An ab initio study of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF hydrogen-bonded complexes.

    Science.gov (United States)

    Ramos, Mozart N; Lopes, Kelson C; Silva, Washington L V; Tavares, Alessandra M; Castriani, Fátima A; do Monte, Silmar A; Ventura, Elizete; Araújo, Regiane C M U

    2006-02-01

    MP2/6-31++G** and B3LYP/6-31++G** ab initio molecular orbital calculations have been performed in order to obtain molecular geometries, binding energies and vibrational properties of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF H-bonded complexes. As expected, the more pronounced effects on the structural properties of the isolated molecules due to complexation was verified for the C[triple bond]C and H-F bond lengths, which are directly involved in the H-bond formation. These bond distances increased after complexation. BSSE uncorrected B3LYP binding energies are always lower than the corresponding MP2 values. However, the opposite trend has been verified after BSSE correction by the counterpoise method since it is much lower at B3LYP than at MP2 level. The binding energies for these complexes as well as for the HF acid submolecule modes (the HF stretching and vibrational frequency modes) showed an increasing hydrogen-bonding strength with increasing methyl substitution. The splitting in the HF in-plane and out-of-plane bending modes reflects the anisotropy in the hydrogen-bonding interaction with the pi system of the C[triple bond]C bond. The H-F stretching frequency is shifted downward after complexation and it increases with the methyl substitution. The IR intensities of the HF acid submolecule fundamentals are adequately interpreted through the atomic polar tensor of the hydrogen atom using the charge-charge flux-overlap model. The skeletal stretching modes of the Alkyne submolecule are decreased in the complex. The new vibrational modes arising from complexation show several interesting features.

  15. The Solubility Parameters of Ionic Liquids

    Directory of Open Access Journals (Sweden)

    Andrzej Marciniak

    2010-04-01

    Full Text Available The Hildebrand’s solubility parameters have been calculated for 18 ionic liquids from the inverse gas chromatography measurements of the activity coefficients at infinite dilution. Retention data were used for the calculation. The solubility parameters are helpful for the prediction of the solubility in the binary solvent mixtures. From the solubility parameters, the standard enthalpies of vaporization of ionic liquids were estimated.

  16. Development of a novel heart failure risk tool: the barcelona bio-heart failure risk calculator (BCN bio-HF calculator.

    Directory of Open Access Journals (Sweden)

    Josep Lupón

    Full Text Available BACKGROUND: A combination of clinical and routine laboratory data with biomarkers reflecting different pathophysiological pathways may help to refine risk stratification in heart failure (HF. A novel calculator (BCN Bio-HF calculator incorporating N-terminal pro B-type natriuretic peptide (NT-proBNP, a marker of myocardial stretch, high-sensitivity cardiac troponin T (hs-cTnT, a marker of myocyte injury, and high-sensitivity soluble ST2 (ST2, (reflective of myocardial fibrosis and remodeling was developed. METHODS: Model performance was evaluated using discrimination, calibration, and reclassification tools for 1-, 2-, and 3-year mortality. Ten-fold cross-validation with 1000 bootstrapping was used. RESULTS: The BCN Bio-HF calculator was derived from 864 consecutive outpatients (72% men with mean age 68.2 ± 12 years (73%/27% New York Heart Association (NYHA class I-II/III-IV, LVEF 36%, ischemic etiology 52.2% and followed for a median of 3.4 years (305 deaths. After an initial evaluation of 23 variables, eight independent models were developed. The variables included in these models were age, sex, NYHA functional class, left ventricular ejection fraction, serum sodium, estimated glomerular filtration rate, hemoglobin, loop diuretic dose, β-blocker, Angiotensin converting enzyme inhibitor/Angiotensin-2 receptor blocker and statin treatments, and hs-cTnT, ST2, and NT-proBNP levels. The calculator may run with the availability of none, one, two, or the three biomarkers. The calculated risk of death was significantly changed by additive biomarker data. The average C-statistic in cross-validation analysis was 0.79. CONCLUSIONS: A new HF risk-calculator that incorporates available biomarkers reflecting different pathophysiological pathways better allowed individual prediction of death at 1, 2, and 3 years.

  17. Effect of tungsten metal particle sizes on the solubility of molten alloy melt: Experimental observation of Gibbs-Thomson effect in nanocomposites

    Science.gov (United States)

    Lee, M. H.; Das, J.; Sordelet, D. J.; Eckert, J.; Hurd, A. J.

    2012-09-01

    We investigated the effect of tungsten particle sizes on the thermal stability and reactivity of uniformly dispersed W particles in molten Hf-based alloy melt at elevated temperature (1673 K). The solubility of particles less than 100 nm in radius is significantly enhanced. In case of fine W particles with 20 nm diameter, their solubility increases remarkably around 700% compared to that of coarse micrometer-scale particles. The mechanisms and kinetics of this dynamic growth of particle are discussed as well as techniques developed to obtain frozen microstructure of particle-reinforced composites by rapid solidification.

  18. Coalescence of silver clusters by immersion in diluted HF solution

    Energy Technology Data Exchange (ETDEWEB)

    Milazzo, R. G.; Mio, A. M.; D’Arrigo, G.; Spinella, C. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Grimaldi, M. G. [Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy); MATIS IMM-CNR, I-95123 Catania (Italy); Rimini, E. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy)

    2015-07-14

    The galvanic displacement deposition of silver on H-terminated Si (100) in the time scale of seconds is instantaneous and characterized by a cluster density of 10{sup 11}-10{sup 12} cm{sup −2}. The amount of deposited Ag follows a t{sup 1/2} dependence in agreement with a Cottrell diffusion limited mechanism. At the same time, during the deposition, the cluster density reduces by a factor 5. This behavior is in contrast with the assumption of immobile clusters. We show in the present work that coalescence and aggregation occur also in the samples immersed in the diluted hydrofluoric acid (HF) solution without the presence of Ag{sup +}. Clusters agglomerate according to a process of dynamic coalescence, typical of colloids, followed by atomic redistribution at the contact regions with the generation of multiple internal twins and stacking-faults. The normalized size distributions in terms of r/r{sub mean} follow also the prediction of the Smoluchowski ripening mechanism. No variation of the cluster density occurs for samples immersed in pure H{sub 2}O solution. The different behavior might be associated to the strong attraction of clusters to oxide-terminated Si surface in presence of water. The silver clusters are instead weakly bound to hydrophobic H-terminated Si in presence of HF. HF causes then the detachment of clusters and a random movement on the silicon surface with mobility of about 10{sup −13} cm{sup 2}/s. Attractive interaction (probably van der Waals) among particles promotes coarsening.

  19. Strong photoluminescence of the porous silicon with HfO2-filled microcavities

    Science.gov (United States)

    Jiang, Ran; Wu, Zhengran; Du, Xianghao; Han, Zuyin; Sun, Weideng

    2015-06-01

    Greatly enhanced blue emission was observed at room temperature in the single-crystal silicon with HfO2 filled into its microcavities. The broad blue band light was emitted from both the HfO2 dielectric and the porous Si. The ferroelectricity of HfO2 enhances the blue emission from Si by its filling into the microcaivities. At the same time, HfO2 contributes to the light emission for the transitions of the defect levels for oxygen vacancy. The observation of greatly enhanced blue light emission of the porous Si filled with HfO2 dielectric is remarkable as both HfO2 and Si are highly compatible with Si-based electronic industry.

  20. Ozone Treatment Improved the Resistive Switching Uniformity of HfAlO2 Based RRAM Devices

    Directory of Open Access Journals (Sweden)

    Lifeng Liu

    2015-01-01

    Full Text Available HfAlO2 based resistive random access memory (RRAM devices were fabricated using atomic layer deposition by modulating deposition cycles for HfO2 and Al2O3. Effect of ozone treatment on the resistive switching uniformity of HfAlO2 based RRAM devices was investigated. Compared to the as-fabricated devices, the resistive switching uniformity of HfAlO2 based RRAM devices with the ozone treatment is significantly improved. The uniformity improvement of HfAlO2 based RRAM devices is related to changes in compositional and structural properties of the HfAlO2 resistive switching film with the ozone treatment.

  1. Medium-Range Order Structure and Fragility of Superheated Melts of Amorphous CuHf Alloys

    Institute of Scientific and Technical Information of China (English)

    BIAN Xiu-Fang; SUN Bao-An; HU Li-Na

    2006-01-01

    @@ The structural factors of amorphous CuHf alloys at different temperatures are determined by using a high temperature x-ray diffractometer. It is found that not only the short-range order structure but also the medium-range order structure exists in amorphous CuHf alloys. The dynamic viscosities of CuHf alloy melts are measured by a torsional oscillation viscometer. The fragility of superheated melts of CuHf alloys is calculated based on the viscosity data. The experimental results show that the glass-forming ability of the CuHf alloys is closely related to the fragility of their superheated melt. The relationship between the medium-range order structures and the fragility of superheated melts has also been established in amorphous CuHf alloys. In contrast to the fragility of supercooled liquids, the fragility of superheated liquids promises a better approach to reflecting the dynamics of glass forming liquids.

  2. Ionosphere research with a HF/MF cubesat radio instrument

    Science.gov (United States)

    Kallio, Esa; Aikio, Anita; Alho, Markku; Fontell, Mathias; Harri, Ari-Matti; Kauristie, Kirsti; Kestilä, Antti; Koskimaa, Petri; Mäkelä, Jakke; Mäkelä, Miika; Turunen, Esa; Vanhamäki, Heikki; Verronen, Pekka

    2017-04-01

    New technology provides new possibilities to study geospace and 3D ionosphere by using spacecraft and computer simulations. A type of nanosatellites, CubeSats, provide a cost effective possibility to provide in-situ measurements in the ionosphere. Moreover, combined CubeSat observations with ground-based observations gives a new view on auroras and associated electromagnetic phenomena. Especially joint and active CubeSat - ground based observation campaigns enable the possibility of studying the 3D structure of the ionosphere. Furthermore using several CubeSats to form satellite constellations enables much higher temporal resolution. At the same time, increasing computation capacity has made it possible to perform simulations where properties of the ionosphere, such as propagation of the electromagnetic waves in the medium frequency, MF (0.3-3 MHz) and high frequency, HF (3-30 MHz), ranges is based on a 3D ionospheric model and on first-principles modelling. Electromagnetic waves at those frequencies are strongly affected by ionospheric electrons and, consequently, those frequencies can be used for studying the plasma. On the other hand, even if the ionosphere originally enables long-range telecommunication at MF and HF frequencies, the frequent occurrence of spatiotemporal variations in the ionosphere disturbs communication channels, especially at high latitudes. Therefore, study of the MF and HF waves in the ionosphere has both a strong science and technology interests. We introduce recently developed simulation models as well as measuring principles and techniques to investigate the arctic ionosphere by a polar orbiting CubeSat whose novel AM radio instrument measures HF and MF waves. The cubesat, which contains also a white light aurora camera, is planned to be launched in late 2017 (http://www.suomi100satelliitti.fi/eng). The new models are (1) a 3D ray tracing model and (2) a 3D full kinetic electromagnetic simulation. We also introduce how combining of the

  3. HF beacon network for ionospheric specification in Peru

    Science.gov (United States)

    Hysell, D. L.; Milla, M. A.; Vierinen, J.

    2016-12-01

    A growing network of HF beacon transmitters and receivers is being deployed in Peru for specifying the F region ionosphere regionally. The effort is motivated by ionospheric disturbances associated with equatorial spread F (ESF), especially disturbances arising under inauspicious ESF conditions. The beacons use dual frequencies (2.72 and 3.64 MHz). They incorporate PRN coding to afford group-delay measurements. Scatered power, Doppler shift, bearing, and polarization are also measured. An algorithm for inverting the beacon data combined with electron density profiles from Jicamarca is described. Data and representative solutions from recent campaigns will be reviewed.

  4. A SYNCHRONIZATION ALGORITHM FOR HF (HIGH FREQUENCY) BROADBAND OFDM SYSTEM

    Institute of Scientific and Technical Information of China (English)

    Yang Lei; Zhang You'ai

    2008-01-01

    In this letter, a kind of associated synchronization algorithm which is suitable for HF (High Frequency) broadband OFDM (Orthogonal Frequency Division Multiplexing) system is presented based on describing and constructing the GMW (Gorden, Mills and Welch) sequence. The algorithm is based on the Schmidl and Minn's symbol timing principle, the constructed GMW sequence is transmitted and disposed, and the synchronization is adjudicated using the correlation of GMW sequence. The simulation result indicates that this algorithm has high performance synchronization ability under the low SNR (Signal to Noise Ratio) at two different kinds of channel models.

  5. Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Hibiya, Yuki; Amelin, Yuri

    2015-04-28

    Knowledge of planetary differentiation is crucial for understanding the chemical and thermal evolution of terrestrial planets. The (176)Lu-(176)Hf radioactive decay system has been widely used to constrain the timescales and mechanisms of silicate differentiation on Earth, but the data interpretation requires accurate estimation of Hf isotope evolution of the bulk Earth. Because both Lu and Hf are refractory lithophile elements, the isotope evolution can be potentially extrapolated from the present-day (176)Hf/(177)Hf and (176)Lu/(177)Hf in undifferentiated chondrite meteorites. However, these ratios in chondrites are highly variable due to the metamorphic redistribution of Lu and Hf, making it difficult to ascertain the correct reference values for the bulk Earth. In addition, it has been proposed that chondrites contain excess (176)Hf due to the accelerated decay of (176)Lu resulting from photoexcitation to a short-lived isomer. If so, the paradigm of a chondritic Earth would be invalid for the Lu-Hf system. Herein we report the first, to our knowledge, high-precision Lu-Hf isotope analysis of meteorite crystalline zircon, a mineral that is resistant to metamorphism and has low Lu/Hf. We use the meteorite zircon data to define the Solar System initial (176)Hf/(177)Hf (0.279781 ± 0.000018) and further to identify pristine chondrites that contain no excess (176)Hf and accurately represent the Lu-Hf system of the bulk Earth ((176)Hf/(177)Hf = 0.282793 ± 0.000011; (176)Lu/(177)Hf = 0.0338 ± 0.0001). Our results provide firm evidence that the most primitive Hf in terrestrial zircon reflects the development of a chemically enriched silicate reservoir on Earth as far back as 4.5 billion years ago.

  6. Thermodynamic modeling of the Co–Hf system supported by key experiments and first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Xingxu [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Liu, Shuhong, E-mail: shhliu@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Cheng, Kaiming; Tang, Ying [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Ou, Pengfei [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Nash, Philip [Thermal Processing Technology Center, Illinois Institute of Technology (IIT), 10 West 32nd Street, Chicago, IL 60616 (United States); Sundman, Bo [INSTN, CEA Saclay, 91191 Gif-Sur-Yvette Cedex (France); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Zheng, Feng [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China)

    2015-05-20

    Highlights: • Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry. • Enthalpy of formation for Co{sub 23}Hf{sub 6} was computed via first-principles calculations. • Co–Hf system was assessed by means of CALPHAD approach. • Order–disorder model is used to describe B2 (CoHf) and A2 (βHf). • Glass forming range of the Co–Hf amorphous alloys was predicted. - Abstract: Phase equilibria and thermodynamic properties of the Co–Hf system were investigated via calorimetric measurements, first-principles calculations and thermodynamic modeling. Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry from 300 to 1200 °C. The enthalpy of formation for Co{sub 23}Hf{sub 6} at 0 K was computed via first-principles calculations. Based on the experimental measurements and first-principles calculations from the present work and the literature, the Co–Hf system was assessed by means of CALPHAD (CALculation of PHAse Diagram) approach. The excess Gibbs energy of solution phases was modeled with Redlich–Kister polynomial. Sublattice models were employed to describe the homogeneity ranges of Co{sub 2}Hf, CoHf and CoHf{sub 2}. The order–disorder transition between B2 (CoHf) and A2 (βHf) phases was taken into account in the current optimization. Using the optimized parameters, glass forming range (GFR) of the Co–Hf amorphous alloys was predicted to be 15–75 at.% Hf, which is in satisfactory agreement with the experimental observation.

  7. Ionospheric Modification by High Power, Obliquely Propagated HF Radio Wave Transmissions. Part 1. Experimental

    Science.gov (United States)

    1993-07-01

    frequency of the disturbing transmitter is greater than the i.. asma frequency in the ionospheric interaction region. In fact, with many practical radio...NY) lay in the Gulf of Mexico and it was not possible to use an oblique probe system similar to- the technique used by the Soviets in their...using a vertical incidence sounder at Albuquerque, New Mexico (35.11N, 106.8 0W) at the midpoint of the 2400 km path. This technique insures that the

  8. 单轴应变对BaHfO3电子结构与光学性质的调制影响%Effect of the Uniaxial Strain on the Electronic Structures and Optical Properties of BaHfO3

    Institute of Scientific and Technical Information of China (English)

    张加宏; 刘清惓; 顾芳; 李敏; 冒晓莉; 葛益娴

    2013-01-01

    Starting from first-principle within the generalized gradient approximation ( GGA) , the modulation impact of the uniaxial strain on the electronic structure and optical properties of perovskite-type ceramic material BaHfO3 has been investigated by the plane-wave pseudo-potential method based on the density function theory. The band structure analysis indicates that BaHfO3 is a wide band gap insulator in the case of without strain, while BaHfO03 gradually shows the characteristics of the semiconductor material under the uniaxial strain. Besides, the band gap of BaHfO3 linearly decreases with the tensile strain, and it appears obvious nonlinear relationship with the compressive strain. The optical properties calculations show that the spikes of the imaginary part of the dielectric function are increased (decreased) and the optical absorption band edge is blue-shifted ( red-shifted) with the compressive (tensile) strain. Furthermore, the static dielectric constant and static refractive index of BaHfO3 under the uniaxial strain are increased. In a word, the involved results have shown that the uniaxial strain effectively modulates the electronic structure and optical properties of BaHfO3, which will provide a theoretical basis for the design and application of BaHfO3 optoelectronic materials.%从第一性原理出发,在广义梯度近似(GGA)下,采用基于密度泛函理论的平面波超软赝势计算方法,着重研究了单轴应变对钙钛矿型陶瓷材料BaHfO3电子结构与光学性质的调制影响.研究结果表明:无应变作用时,BaHfO3是一种宽禁带绝缘体;施加单轴应变后其逐渐呈现半导体材料的特征.BaHfO3带隙随拉应变增加线性减小,压应变与带隙则具有明显的非线性关系.对光学性质的分析发现:施加压(拉)应变后,介电函数虚部尖峰增多(减小),光学吸收带边产生蓝移(红移).此外,单轴应变作用下BaHfO3的静态介电常数和折射率均变大.上述研究表明施

  9. Description of $^{178}$Hf$^{m2}$ in the constrained relativistic mean field theory

    CERN Document Server

    Wei, Zhang; Shuang-Quan, Zhang

    2009-01-01

    The properties of the ground state of $^{178}$Hf and the isomeric state $^{178}$Hf$^{m2}$ are studied within the adiabatic and diabatic constrained relativistic mean field (RMF) approaches. The RMF calculations reproduce well the binding energy and the deformation for the ground state of $^{178}$Hf. Using the ground state single-particle eigenvalues obtained in the present calculation, the lowest excitation configuration with $K^\\pi=16^+$ is found to be $\

  10. Assembly of the CMS HF (hadron forward) calorimeter, April 2003 to June 2005

    CERN Multimedia

    Tejinder S. Virdee, CERN

    2005-01-01

    The forward calorimeters (HF) of the CMS hadron calorimeter system are located 11.2 m from the interaction point. Each HF module is composed by 18 wedges, made of steel absorbers and radiation-hard quartz fibers. The photogallery shows the wedges (Figs. 1-3, April 2003), the assembly of one HF module (Figs. 4-9, May and June 2004) and the assembly of the other (Figs. 10-11, June 2005)

  11. Far-Field Testing Method of Spurious Emission Produced by HF RFID

    OpenAIRE

    Nikola Gvozdenovic; Ralph Prestros; Mecklenbräuker, Christoph F.

    2016-01-01

    We present measurements of spurious emission produced by high-frequency radio frequency identification (HF RFID) using carrier frequency of 13.56 MHz. HF RFID tags produce unwanted emission due to rectification and more generally due to nonlinearity of analog front end. Depending on the conducting material of an HF RFID coil and surrounding dielectric material, the coil behaves as more or less good antenna on some harmonic frequencies. Exact characterization and analysis of unwanted emission ...

  12. Enhanced resistive switching and multilevel behavior in bilayered HfAlO/HfAlO{sub x} structures for non-volatile memory applications

    Energy Technology Data Exchange (ETDEWEB)

    Faita, F. L., E-mail: fabriciofaita@gmail.com [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Departamento de Física, Universidade Federal de Santa Catarina, Campus Trindade, 88040-900 Florianópolis, SC (Brazil); Silva, J. P. B., E-mail: josesilva@fisica.uminho.pt [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia, Faculdade de Ciências da Universidade do Porto, 4169-007 Porto (Portugal); Pereira, M.; Gomes, M. J. M. [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2015-12-14

    In this work, hafnium aluminum oxide (HfAlO) thin films were deposited by ion beam sputtering deposition technique on Si substrate. The presence of oxygen vacancies in the HfAlO{sub x} layer deposited in oxygen deficient environment is evidenced from the photoluminescence spectra. Furthermore, HfAlO(oxygen rich)/HfAlO{sub x}(oxygen poor) bilayer structures exhibit multilevel resistive switching (RS), and the switching ratio becomes more prominent with increasing the HfAlO layer thickness. The bilayer structure with HfAlO/HfAlO{sub x} thickness of 30/40 nm displays the enhanced multilevel resistive switching characteristics, where the high resistance state/intermediate resistance state (IRS) and IRS/low resistance state resistance ratios are ≈10{sup 2} and ≈5 × 10{sup 5}, respectively. The switching mechanisms in the bilayer structures were investigated by the temperature dependence of the three resistance states. This study revealed that the multilevel RS is attributed to the coupling of ionic conduction and the metallic conduction, being the first associated to the formation and rupture of conductive filaments related to oxygen vacancies and the second with the formation of a metallic filament. Moreover, the bilayer structures exhibit good endurance and stability in time.

  13. Surface circulation patterns at the southeastern Bay of Biscay: new observations from HF radar data

    Science.gov (United States)

    Solabarrieta, L.; Rubio, A.; Medina, R.; Paduan, J. D.; Castanedo, S.; Fontán, A.; Cook, M.; González, M.

    2012-12-01

    A CODAR Seasonde High Frequency (HF) radar network has been operational since the beginning of 2009 for the oceanic region of the Basque Country, Spain (south-eastern Bay of Biscay, Atlantic Ocean). It forms part of the Basque operational data acquisition system, established by the Directorate of Emergency Attention and Meteorology of the Basque Government. It is made up of two antennas, at the capes Higer (43d 23.554' N, 1d 47.745' W) and Matxitxako (43d 7.350' N, 2d 45.163' W), emitting at 4.525 MHz frequency and 30 kHz bandwidth. This system provides hourly surface currents with 5.12 km spatial resolution, covering 10,000 km2. Space- and time-covering measurements have been available in the study area since 2009. The data contribute considerably to the study of surface current patterns and the main physical processes in the area. Additional applications relate to security of navigation, maritime rescue, validation and improvement of numerical models, etc. For comparison with other validation studies and to obtain an estimate of the performance of the Basque system, statistical and spectral analysis of the surface currents obtained through the HF radar and different in-situ platforms have been conducted. The analyses show values of comparison between the different measuring systems consistent with those done by other authors (Paduan and Rosenfeld, 1996; Kaplan et al., 2005). The radar is able to reproduce the time evolution of the currents with a reasonable accuracy; likewise, the main three spectral peaks (inertial, semidiurnal and diurnal) are well resolved. In this context, the aim of this work is to show the HF radar ability to measure accurately the surface currents in the south-eastern Bay of Biscay and to study the ocean circulation in the area (figures 1 and 2). Surface current patterns are analysed and described for the period 2009-2011, for different timescales. A clear seasonality at a large-scale has been observed in accordance with previous work

  14. Ferroelectric phase stabilization of HfO2 by nitrogen doping

    Science.gov (United States)

    Xu, Lun; Nishimura, Tomonori; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-09-01

    We report that nitrogen (N) doping can drive the ferroelectricity of HfO2. It was found that N doping can cause the transition from a monoclinic phase to a highly symmetric phase. The role of N doping is discussed from the viewpoints of charge balance and bond-constraining effects. The former is responsible for the structural transformation from a paraelectric phase to a ferroelectric phase by forming an oxygen vacancy. In addition, Hf-N and N-O bonds with covalent characteristics have strong effects on HfO2 structural and electrical properties, and thus contribute to a marked HfO2 para-/ferroelectric transition.

  15. Efficient noble metal nanocatalysts supported on HfC(001 for O2 dissociation

    Directory of Open Access Journals (Sweden)

    Shiyan Wang

    2017-03-01

    Full Text Available The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt clusters supported on HfC(001 (Hafnium Carbide are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001 (0.26 eV, Pd4/HfC(001 (0.49 eV and Pt4/HfC(001 (0.09 eV are much smaller than those on the clean surfaces of HfC(001 (1.60 eV, Au(111 (1.37 eV, Pd(111 (1.0 and 0.91 eV and Pt(111 (0.27–0.7 eV, respectively. The low dissociation barriers imply that the Pt4/HfC(001 exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001 and Pd4/HfC(001 may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  16. Efficient noble metal nanocatalysts supported on HfC(001) for O2 dissociation

    Science.gov (United States)

    Wang, Shiyan; Zhang, Xilin; Zhang, Yanxing; Mao, Jianjun; Yang, Zongxian

    2017-03-01

    The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt) clusters supported on HfC(001) (Hafnium Carbide) are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001) (0.26 eV), Pd4/HfC(001) (0.49 eV) and Pt4/HfC(001) (0.09 eV) are much smaller than those on the clean surfaces of HfC(001) (1.60 eV), Au(111) (1.37 eV), Pd(111) (1.0 and 0.91 eV) and Pt(111) (0.27-0.7 eV), respectively. The low dissociation barriers imply that the Pt4/HfC(001) exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001) and Pd4/HfC(001) may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  17. Study of Direct-Contact HfO2/Si Interfaces

    Directory of Open Access Journals (Sweden)

    Noriyuki Miyata

    2012-03-01

    Full Text Available Controlling monolayer Si oxide at the HfO2/Si interface is a challenging issue in scaling the equivalent oxide thickness of HfO2/Si gate stack structures. A concept that the author proposes to control the Si oxide interface by using ultra-high vacuum electron-beam HfO2 deposition is described in this review paper, which enables the so-called direct-contact HfO2/Si structures to be prepared. The electrical characteristics of the HfO2/Si metal-oxide-semiconductor capacitors are reviewed, which suggest a sufficiently low interface state density for the operation of metal-oxide-semiconductor field-effect-transistors (MOSFETs but reveal the formation of an unexpected strong interface dipole. Kelvin probe measurements of the HfO2/Si structures provide obvious evidence for the formation of dipoles at the HfO2/Si interfaces. The author proposes that one-monolayer Si-O bonds at the HfO2/Si interface naturally lead to a large potential difference, mainly due to the large dielectric constant of the HfO2. Dipole scattering is demonstrated to not be a major concern in the channel mobility of MOSFETs.

  18. Structural degradation of thin HfO2 film on Ge during the postdeposition annealing

    Science.gov (United States)

    Miyata, Noriyuki; Yasuda, Tetsuji; Abe, Yasuhiro

    2010-05-01

    Securing the thermal robustness of thin hafnium oxide (HfO2) film on the semiconductor surface is an important technical issue in the fabrication of the metal-oxide-semiconductor field-effect transistor devices, as the HfO2-based high-k gate stacks usually undergo high-temperature processes. In this study, the structural development of thin HfO2 film on a Ge surface during postdeposition annealing in an ultrahigh vacuum was examined to explore the origin for the initial degradation of thin HfO2 film. Void nucleation and subsequent two-dimensional void growth take place at 780-840 °C, while the chemical composition of the remaining Hf oxide is virtually stable. Both the void nucleation and growth processes show similar larger activation energy of about 10 eV. Based on the observed manner of void growth and the estimated activation energies, the authors propose that mass transport on the HfO2 surface is responsible for void nucleation in the HfO2 films on Ge. The authors also compare the present results with the previous studies on HfO2/Si structures, and suggest that similar surface process leads to the local Hf silicidation.

  19. The effect of Cu doping concentration on resistive switching of HfO{sub 2} film

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Tingting; Tan, Tingting, E-mail: tantt@nwpu.edu.cn; Liu, Zhengtang

    2015-10-01

    Graphical abstract: - Highlights: • The Cu doped and undoped HfO{sub 2} films were fabricated. • The improved RS behaviors were observed for Cu doped HfO{sub 2} film with BRS. • The 9.7% doped HfO{sub 2}:Cu film showed both BRS and URS behaviors. • The related switching mechanisms were illustrated. - Abstract: The Cu-doped and undoped HfO{sub 2} films were fabricated and the effect of Cu doping concentration on resistive switching (RS) of HfO{sub 2} film was demonstrated. The X-ray photoelectron spectroscopy (XPS) was carried out to investigate the chemical bonding states of Cu in HfO{sub 2}:Cu film. The improved RS behaviors in terms of ON/OFF ratio and switching parameters were observed for Cu-doped HfO{sub 2} film with bipolar resistive switching (BRS) behavior. With the increase of Cu doping concentration, the 9.7% Cu-doped HfO{sub 2} film showed both BRS and unipolar resistive switching (URS) behaviors with large operating voltages. The space charge limited current (SCLC) effect was proposed to interpret the switching mechanism of HfO{sub 2}:Cu films with BRS behavior and the URS behavior can be explained by the migration of Cu ions.

  20. Lu-hf total-rock isochron for the eucrite meteorites

    Science.gov (United States)

    Patchett, P.J.; Tatsumoto, M.

    1980-01-01

    The isotope 176Lu (2.6% of natural lutetium) decays by ??- to 176Hf, with a long half life. We present here the first Lu-Hf isochron. The eucrite meteorites, a suite of planetary igneous rocks of known age, 4,550 Myr, define a 10-point total-rock isochron with a slope of 0.0934 ?? 40, leading to a value of 3.53 ?? 0.14 ??1010yr for the ??--decay half life of 176Lu. The isochron intercept of 0.27973 ?? 12 gives the initial 176Hf/177Hf for the inner Solar System at the time of accretion. ?? 1980 Nature Publishing Group.

  1. Chemical stability and defect formation in CaHfO3

    KAUST Repository

    Alay-E-Abbas, Syed Muhammad

    2014-04-01

    Defects in CaHfO3 are investigated by ab initio calculations based on density functional theory. Pristine and anion-deficient CaHfO 3 are found to be insulating, whereas cation-deficient CaHfO 3 is hole-doped. The formation energies of neutral and charged cation and anion vacancies are evaluated to determine the stability in different chemical environments. Moreover, the energies of the partial and full Schottky defect reactions are computed. We show that clustering of anion vacancies in the HfO layers is energetically favorable for sufficiently high defect concentrations and results in metallicity. © 2014 EPLA.

  2. Anticooperativity of FHF hydrogen bonds in clusters of the type F- × (HF)n, RF × (HF)n and XF × (HF)n, R = alkyl and X = H, Br, Cl, F

    Science.gov (United States)

    Kucherov, S. Yu.; Bureiko, S. F.; Denisov, G. S.

    2016-02-01

    Properties of twenty five hydrogen-bonded complexes, namely, F- × (HF)n (n = 1-6), RF × (HF)n (R = t-Bu, i-Pr, Et, Me; n = 1-3), XF × (HF)n (X = H, Br, Cl; n = 1-2), and FF…HF with the hydrogen bond energy varying in a wide range have been calculated using ab initio methods at the MP2/6-31++G** level. For the first time, the energies, geometrical parameters and vibrational frequencies are obtained for the series of clusters, where the bonding character changes from covalent to van der Waals on the variation of proton-acceptor ability of the base, and the energies are in the range of 45-1 kcal/mol. The mutual influence of multiple hydrogen bonds of F…HF type in clusters, in which a fluorine anion or an atom participates in hydrogen bond formation as the acceptor, is systematically investigated. The relative changes in the values of the considered parameters on the sequential addition of an HF molecule (anticooperativity) were determined. It was shown that non-additivity of the interaction is most strongly pronounced in the energy and vibrational frequency values, geometrical parameters of hydrogen bonds are less sensitive to the mutual influence. The anticooperative effect is more pronounced on the hydrogen bridge length R(F...F) than on the geometry of proton donor r(HF). The hydrogen bond formation and the increase of the number n of ligands lead to successive lengthening of the r(XF) bond adjacent to the hydrogen bridge. The length of an XF bond changes stronger on formation of each hydrogen bond than the HF bond length.

  3. Effects of Hf Incorporation on Negative Bias-Illumination Stress Stability in Hf-In-Zn-O Thin-Film Transistors

    Science.gov (United States)

    Kim, Sangwook; Park, Jae Chul; Kim, Dae Hwan; Lee, Jang-Sik

    2013-04-01

    In this study, highly reliable amorphous oxide semiconductor-based thin-film transistors (TFTs) were developed. The Hf concentration was systematically changed in the Hf-incorporated In-Zn-O (HIZO) TFTs, and Hf played an important role in determining the negative bias-illumination instability. The process parameters were optimized in order to obtain HIZO TFTs with an excellent stability. HIZO can be processed on a 6-in. wafer at low temperatures and is almost transparent in the visible range. Thus this material is promising for use in current TFTs as well as future transparent electronic device components with good electrical performance and excellent stability.

  4. Reversible spin texture in ferroelectric Hf O2

    Science.gov (United States)

    Tao, L. L.; Paudel, Tula R.; Kovalev, Alexey A.; Tsymbal, Evgeny Y.

    2017-06-01

    Spin-orbit coupling effects occurring in noncentrosymmetric materials are known to be responsible for nontrivial spin configurations and a number of emergent physical phenomena. Ferroelectric materials may be especially interesting in this regard due to reversible spontaneous polarization making possible a nonvolatile electrical control of the spin degrees of freedom. Here, we explore a technologically relevant oxide material, Hf O2 , which has been shown to exhibit robust ferroelectricity in a noncentrosymmetric orthorhombic phase. Using theoretical modelling based on density-functional theory, we investigate the spin-dependent electronic structure of the ferroelectric Hf O2 and demonstrate the appearance of chiral spin textures driven by spin-orbit coupling. We analyze these spin configurations in terms of the Rashba and Dresselhaus effects within the k .p Hamiltonian model and find that the Rashba-type spin texture dominates around the valence-band maximum, while the Dresselhaus-type spin texture prevails around the conduction band minimum. The latter is characterized by a very large Dresselhaus constant λD= 0.578 eV Å, which allows using this material as a tunnel barrier to produce tunneling anomalous and spin Hall effects that are reversible by ferroelectric polarization.

  5. Radiation effects in Zr and Hf containing garnets

    Energy Technology Data Exchange (ETDEWEB)

    Whittle, Karl R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Department of Materials Science and Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom); Blackford, Mark G.; Smith, Katherine L. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Zaluzec, Nestor J. [Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 (United States); Weyland, Matthew [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Department of Materials Engineering, Monash University, Victoria 3800 (Australia); Lumpkin, Gregory R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia)

    2015-07-15

    Garnets have been considered as host phases for the safe immobilisation of high-level nuclear waste, as they have been shown to accommodate a wide range of elements across three different cation sites, such as Ca, Y, Mn on the a-site, Fe, Al, U, Zr, and Ti on the b-site, and Si, Fe, Al on the c-site. Garnets, due to their ability to have variable composition, make ideal model materials for the examination of radiation damage and recovery in nuclear materials, including as potential waste forms. Kimzeyite, Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, has been shown naturally to contain up to 30 wt% Zr, and has previously been examined to elucidate both the structure and ordering within the lattice. This study examines the effects of radiation damage and recovery using in-situ ion beam irradiation with 1 MeV Kr ions at the IVEM-TANDEM facility, Argonne National Laboratory. The complementary Hf containing system Ca{sub 3}Hf{sub 2}FeAlSiO{sub 12} was also examined, and found to have a different response to irradiation damage. A sample of irradiated Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, at 1000 K, was characterised using aberration corrected (S)TEM and found to contain discreet, nano-sized, crystalline Fe rich particles, indicating a competing process during recovery is occurring.

  6. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, W. A.; Hysell, D. L.

    2016-12-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  7. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, William; Hysell, David

    2016-07-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  8. Interrogation zone determination in HF RFID systems with multiplexed antennas*

    Directory of Open Access Journals (Sweden)

    Jankowski-Mihułowicz Piotr

    2015-09-01

    Full Text Available The operation of an anti-collision RFID system is characterized by the interrogation zone which should be estimated in any direction of 3D space for a group of electronic transponders. The interrogation zone should be as large as possible. However, the many problems in this area are due to the fact that energy can be transferred to transponders only on a limited distance. The greatest flexibility in developing RFID applications and shaping the interrogation zone can be achieved using the system with an antenna multiplexer. Therefore the problem of the interrogation zone determination in HF RFID systems with two orthogonal RWD antennas is presented in the paper. The perceived issues have been effectively dealt with and the solution has been proposed on the basis of the elaborated model. Conducted studies have been used to develop the software tool JankoRFIDmuxHF in the Mathcad environment. The research results are analysed in an example system configuration. The specialized measuring stand has been used for experimental verification of the identification efficiency. The convergence of the measurements and calculations confirms a practical usefulness of the presented concept of interrogation zone determination in anti-collision systems. It also shows the practical utility of the developed model and software tools.

  9. Beam Forming HF Radar Beam Pattern Measurements and Phase Offset Calibration Using a UAV

    Science.gov (United States)

    Cahl, D.; Voulgaris, G.

    2016-12-01

    It has been shown that measuring antenna patterns for direction finding radars improves surface current measurements. For beam forming radars, the beam pattern of the receive array is assumed to be similar to that derived using theoretical calculations. However, local environmental conditions may lead to deviations (i.e., larger sidelobes and beamwidth) from this idealized beam pattern. This becomes particularly important for wave measurements that are sensitive to interference from sidelobes. Common techniques for beam forming HF radar phase calibration include "cross calibration", using a secondary beam forming site as the signal source, or calibration using a ship. The former method is limited to only one direction; on straight coastlines this is often at a large angle from the radar bore site where the beam width and uncertainty in phase calibration might be large. The latter technique requires chartering a ship with an appropriate reflector or transmitter, or the identification of ships of opportunity. Recent advances in UAV technology combined with an easement of FAA restrictions (Part 107) allows phase calibrations and beam pattern measurements to be completed on an HF radar site using a small transmitter attached to a UAV. This presentation describes the use of a UAV and the development of a method for beam forming phase calibration and beam pattern measurements. This method uses the UAV as a moving signal source to provide true sidelobe and beamwidth measurements. Results are shown from a calibration carried out at a beam forming (WERA) radar site (8.3 MHz) located in Georgetown, SC and are compared with results from a cross calibration. Phase calibrations acquired by the UAV showed a dependence on azimuthal angle from the radar bore site. Also, the beam patterns obtained were found to be narrower than those derived using the stationary source method. The effect of the new phase values derived using this method on the accuracy of radial velocities will be

  10. The role of Upper Hybrid Turbulence on HF Artificial Ionization

    Science.gov (United States)

    Papadopoulos, Konstantinos Dennis; Najmi, Amir; Eliasson, Bengt; Milikh, Gennady

    2016-07-01

    One of the most fascinating and scientifically interesting phenomena of active space experiments is the discovery of artificial ionization by Todd Pedersen when the HAARP ERP reached the GW level. The phenomenon has been well documented experimentally. A theoretical model based on ionization by energetic electrons accelerated by 50-100 V/m localized electric fields due to Strong Langmuir Turbulence (SLT) near the reflection surface of the HF pump wave, reproduced the observed dynamics of the descending plasma layer quite accurately. A major defect of the model was that the electron temperature in the SLT region was a free parameter. When taken as the 2000 K representing the ambient electron temperature the SLT driven electron flux was insufficient to produce ionization. An equivalent electron temperature of 5000 K or higher was necessary to reproduce the observations. The needed electron heating was attributed to the interaction of the HF at the Upper Hybrid (UH) resonant layer, approximately 5 Km below the reflection region where the HF electric field is perpendicular to the ambient magnetic field. The heated electrons expanded upwards along the magnetic field line and interacted with SLT fields near the resonance region. A consequence of this defect was that the theory could not explain the puzzling double resonance effect. Namely the observation that the ionization level was much stronger when the HF frequency and the UH resonance were a multiple of the electron cyclotron frequency. To remedy this we used a series of Vlasov simulations to explore the HF-plasma interaction in the vicinity of the UH resonance. The simulations followed the evolution of the spectral density of the electric field over a 7.5 MHz frequency band and cm scale lengths and of the electron distribution function over one millisecond for both double resonant and non-resonant cases. Many new features were revealed by the analysis of the simulations such as: 1. Broadening of the wave

  11. Electron Microprobe Analysis of Hf in Zircon: Suggestions for Improved Accuracy of a Difficult Measurement

    Science.gov (United States)

    Fournelle, J.; Hanchar, J. M.

    2013-12-01

    It is not commonly recognized as such, but the accurate measurement of Hf in zircon is not a trivial analytical issue. This is important to assess because Hf is often used as an internal standard for trace element analyses of zircon by LA-ICPMS. The issues pertaining to accuracy revolve around: (1) whether the Hf Ma or the La line is used; (2) what accelerating voltage is applied if Zr La is also measured, and (3) what standard for Hf is used. Weidenbach, et al.'s (2004) study of the 91500 zircon demonstrated the spread (in accuracy) of possible EPMA values for six EPMA labs, 2 of which used Hf Ma, 3 used Hf La, and one used Hf Lb, and standards ranged from HfO2, a ZrO2-HfO2 compound, Hf metal, and hafnon. Weidenbach, et al., used the ID-TIMS values as the correct value (0.695 wt.% Hf.), for which not one of the EPMA labs came close to that value (3 were low and 3 were high). Those data suggest: (1) that there is a systematic underestimation error of the 0.695 wt% Hf (ID-TIMS Hf) value if Hf Ma is used; most likely an issue with the matrix correction, as the analytical lines and absorption edges of Zr La, Si Ka and Hf Ma are rather tightly packed in the electromagnetic spectrum. Mass absorption coefficients are easily in error (e.g., Donovan's determination of the MAC of Hf by Si Ka of 5061 differs from the typically used Henke value of 5449 (Donovan et al, 2002); and (2) For utilization of the Hf La line, however, the second order Zr Ka line interferes with Hf La if the accelerating voltage is greater than 17.99 keV. If this higher keV is used and differential mode PHA is applied, only a portion of the interference is removed (e.g., removal of escape peaks), causing an overestimation of Hf content. Unfortunately, it is virtually impossible to apply an interference correction in this case, as it is impossible to locate Hf-free Zr probe standard. We have examined many of the combinations used by those six EPMA labs and concluded that the optimal EPMA is done with Hf

  12. Cloud processing of soluble gases

    Science.gov (United States)

    Laj, P.; Fuzzi, S.; Facchini, M. C.; Lind, J. A.; Orsi, G.; Preiss, M.; Maser, R.; Jaeschke, W.; Seyffer, E.; Helas, G.; Acker, K.; Wieprecht, W.; Möller, D.; Arends, B. G.; Mols, J. J.; Colvile, R. N.; Gallagher, M. W.; Beswick, K. M.; Hargreaves, K. J.; Storeton-West, R. L.; Sutton, M. A.

    Experimental data from the Great Dun Fell Cloud Experiment 1993 were used to investigate interactions between soluble gases and cloud droplets. Concentrations of H 2O 2, SO 2, CH 3COOOH, HCOOH, and HCHO were monitored at different sites within and downwind of a hill cap cloud and their temporal and spatial evolution during several cloud events was investigated. Significant differences were found between in-cloud and out-of-cloud concentrations, most of which could not be explained by simple dissolution into cloud droplets. Concentration patterns were analysed in relation to the chemistry of cloud droplets and the gas/liquid equilibrium. Soluble gases do not undergo similar behaviour: CH 3COOH simply dissolves in the aqueous phase and is outgassed upon cloud dissipation; instead, SO 2 is consumed by its reaction with H 2O 2. The behaviour of HCOOH is more complex because there is evidence for in-cloud chemical production. The formation of HCOOH interferes with the odd hydrogen cycle by enhancing the liquid-phase production of H 2O 2. The H 2O 2 concentration in cloud therefore results from the balance of consumption by oxidation of SO 2 in-cloud production, and the rate by which it is supplied to the system by entrainment of new air into the clouds.

  13. Atomic scale engineering of HfO{sub 2}-based dielectrics for future DRAM applications

    Energy Technology Data Exchange (ETDEWEB)

    Dudek, Piotr

    2011-02-14

    Modern dielectrics in combination with appropriate metal electrodes have a great potential to solve many difficulties associated with continuing miniaturization process in the microelectronic industry. One significant branch of microelectronics incorporates dynamic random access memory (DRAM) market. The DRAM devices scaled for over 35 years starting from 4 kb density to several Gb nowadays. The scaling process led to the dielectric material thickness reduction, resulting in higher leakage current density, and as a consequence higher power consumption. As a possible solution for this problem, alternative dielectric materials with improved electrical and material science parameters were intensively studied by many research groups. The higher dielectric constant allows the use of physically thicker layers with high capacitance but strongly reduced leakage current density. This work focused on deposition and characterization of thin insulating layers. The material engineering process was based on Si cleanroom compatible HfO{sub 2} thin films deposited on TiN metal electrodes. A combined materials science and dielectric characterization study showed that Ba-added HfO{sub 2} (BaHfO{sub 3}) films and Ti-added BaHfO{sub 3} (BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}) layers are promising candidates for future generation of state-of-the-art DRAMs. In especial a strong increase of the dielectric permittivity k was achieved for thin films of cubic BaHfO{sub 3} (k{proportional_to}38) and BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} (k{proportional_to}90) with respect to monoclinic HfO{sub 2} (k{proportional_to}19). Meanwhile the CET values scaled down to 1 nm for BaHfO{sub 3} and {proportional_to}0.8 nm for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} with respect to HfO{sub 2} (CET=1.5 nm). The Hf{sup 4+} ions substitution in BaHfO{sub 3} by Ti{sup 4+} ions led to a significant decrease of thermal budget from 900 C for BaHfO{sub 3} to 700 C for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}. Future studies need to focus

  14. Evolution of continental crust and mantle heterogeneity: Evidence from Hf isotopes

    Science.gov (United States)

    Jonathan, Patchett P.; Kouvo, O.; Hedge, C.E.; Tatsumoto, M.

    1982-01-01

    We present initial 176Hf/177 Hf ratios for many samples of continental crust 3.7-0.3 Gy old. Results are based chiefly on zircons (1% Hf) and whole rocks: zircons are shown to be reliable carriers of essentially the initial Hf itself when properly chosen on the basis of U-Pb studies. Pre-3.0 Gy gneisses were apparently derived from an unfractionated mantle, but both depleted and undepleted mantle are evident as magma sources from 2.9 Gy to present. This mantle was sampled mainly from major crustal growth episodes 2.8, 1.8 and 0.7 Gy ago, all of which show gross heterogeneity of 176Hf/177Hf in magma sources from ??Hf=0 to +14, or about 60% of the variability of the present mantle. The approximate ??Hf=2??Nd relationship in ancient and modern igneous rocks shows that 176Lu/177Hf fractionates in general twice as much as 147Sm/144Nd in mantle melting processes. This allows an estimation of the relative value of the unknown bulk solid/liquid distribution coefficient for Hf. DLu/DHf=??? 2.3 holds for most mantle source regions. For garnet to be an important residual mantle phase, it must hold Hf strongly in order to preserve Hf-Nd isotopic relationships. The ancient Hf initials are consistent with only a small proportion of recycled older cratons in new continental crust, and with quasi-continuous, episodic growth of the continental crust with time. However, recycling of crust less than 150 My old cannot realistically be detected using Hf initials. The mantle shows clearly the general positive ??Hf resulting from a residual geochemical state at least back to 2.9 Gy ago, and seems to have repeatedly possessed a similar degree of heterogeneity, rather than a continuously-developing depletion. This is consistent with a complex dynamic disequilibrium model for the creation, maintenance and destruction of heterogeneity in the mantle. ?? 1981 Springer-Verlag.

  15. What Hf isotopes in zircon tell us about crust-mantle evolution

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Itano, Keita; Hibiya, Yuki; Suzuki, Kazue

    2017-03-01

    The 176Lu-176Hf radioactive decay system has been widely used to study planetary crust-mantle differentiation. Of considerable utility in this regard is zircon, a resistant mineral that can be precisely dated by the U-Pb chronometer and record its initial Hf isotope composition due to having low Lu/Hf. Here we review zircon U-Pb age and Hf isotopic data mainly obtained over the last two decades and discuss their contributions to our current understanding of crust-mantle evolution, with emphasis on the Lu-Hf isotope composition of the bulk silicate Earth (BSE), early differentiation of the silicate Earth, and the evolution of the continental crust over geologic history. Meteorite zircon encapsulates the most primitive Hf isotope composition of our solar system, which was used to identify chondritic meteorites best representative of the BSE (176Hf/177Hf = 0.282793 ± 0.000011; 176Lu/177Hf = 0.0338 ± 0.0001). Hadean-Eoarchean detrital zircons yield highly unradiogenic Hf isotope compositions relative to the BSE, providing evidence for the development of a geochemically enriched silicate reservoir as early as 4.5 Ga. By combining the Hf and O isotope systematics, we propose that the early enriched silicate reservoir has resided at depth within the Earth rather than near the surface and may represent a fractionated residuum of a magma ocean underlying the proto-crust, like urKREEP beneath the anorthositic crust on the Moon. Detrital zircons from world major rivers potentially provide the most robust Hf isotope record of the preserved granitoid crust on a continental scale, whereas mafic rocks with various emplacement ages offer an opportunity to trace the Hf isotope evolution of juvenile continental crust (from εHf[4.5 Ga] = 0 to εHf[present] = + 13). The river zircon data as compared to the juvenile crust composition highlight that the supercontinent cycle has controlled the evolution of the continental crust by regulating the rates of crustal generation and intra

  16. In vitro solubility assays in drug discovery.

    Science.gov (United States)

    Kerns, Edward H; Di, Li; Carter, Guy T

    2008-11-01

    The solubility of a compound depends on its structure and solution conditions. Structure determines the lipophilicity, hydrogen bonding, molecular volume, crystal energy and ionizability, which determine solubility. Solution conditions are affected by pH, co-solvents, additives, ionic strength, time and temperature. Many drug discovery experiments are conducted under "kinetic" solubility conditions. In drug discovery, solubility has a major impact on bioassays, formulation for in vivo dosing, and intestinal absorption. A good goal for the solubility of drug discovery compounds is >60 ug/mL. Equilibrium solubility assays can be conducted in moderate throughput, by incubating excess solid with buffer and agitating for several days, prior to filtration and HPLC quantitation. Kinetic solubility assays are performed in high throughput with shorter incubation times and high throughput analyses using plate readers. The most frequently used of these are the nephelometric assay and direct UV assay, which begin by adding a small volume of DMSO stock solution of each test compound to buffer. In nephelometry, this solution is serially diluted across a microtitre plate and undissolved particles are detected via light scattering. In direct UV, undissolved particles are separated by filtration, after which the dissolved material is quantitated using UV absorption. Equilibrium solubility is useful for preformulation. Kinetic solubility is useful for rapid compound assessment, guiding optimization via structure modification, and diagnosing bioassays. It is often useful to customize solubility experiments using conditions that answer specific research questions of drug discovery teams, such as compound selection and vehicle development for pharmacology and PK studies.

  17. Influence of Hf contents on interface state properties in a-HfInZnO thin-film transistors with SiNx/SiOx gate dielectrics

    Science.gov (United States)

    Choi, Hyun-Sik; Jeon, Sanghun; Kim, Hojung; Shin, Jaikwang; Kim, Changjung; Chung, U.-In

    2011-10-01

    We evaluated the interface properties of amorphous hafnium-indium-zinc-oxide (a-HIZO) thin-film transistors (TFTs) with respect to various Hf contents. To this end, the subthreshold swing and the low-frequency noise (LFN) of the a-HIZO TFTs were measured and compared. From LFNs providing more accurate information, we quantitatively analyzed the interface trap densities and found that they decrease with increasing Hf contents. Although the acceptor-like tail state densities in bulk channel increase with Hf contents, higher Hf contents show lower threshold voltage shift under bias stress, implying that reliability characteristics of a-HIZO TFTs are more sensitive to interface quality rather than bulk property.

  18. Distribution of p-process 174Hf in early solar system materials and the origin of nucleosynthetic Hf and W isotope anomalies in Ca-Al rich inclusions

    Science.gov (United States)

    Peters, Stefan T. M.; Münker, Carsten; Pfeifer, Markus; Elfers, Bo-Magnus; Sprung, Peter

    2017-02-01

    Some nuclides that were produced in supernovae are heterogeneously distributed between different meteoritic materials. In some cases these heterogeneities have been interpreted as the result of interaction between ejecta from a nearby supernova and the nascent solar system. Particularly in the case of the oldest objects that formed in the solar system - Ca-Al rich inclusions (CAIs) - this view is confirm the hypothesis that a nearby supernova event facilitated or even triggered solar system formation. We present Hf isotope data for bulk meteorites, terrestrial materials and CAIs, for the first time including the low-abundance isotope 174Hf (∼0.16%). This rare isotope was likely produced during explosive O/Ne shell burning in massive stars (i.e., the classical "p-process"), and therefore its abundance potentially provides a sensitive tracer for putative heterogeneities within the solar system that were introduced by supernova ejecta. For CAIs and one LL chondrite, also complementary W isotope data are reported for the same sample cuts. Once corrected for small neutron capture effects, different chondrite groups, eucrites, a silicate inclusion of a IAB iron meteorite, and terrestrial materials display homogeneous Hf isotope compositions including 174Hf. Hafnium-174 was thus uniformly distributed in the inner solar system when planetesimals formed at the system composition, and also variable r-process (or s-process) Hf and W contributions. Based on combined Hf and W isotope compositions, we show that CAIs sampled at least one component in which the proportion of r- and s-process derived Hf and W deviates from that of supernova ejecta. The Hf and W isotope anomalies in CAIs are therefore best explained by selective processing of presolar carrier phases prior to CAI formation, and not by a late injection of supernova materials. Likewise, other isotope anomalies in additional elements in CAIs relative to the bulk solar system may reflect the same process. The isotopic

  19. Air sensitivity of MoS2, MoSe2, MoTe2, HfS2, and HfSe2

    Science.gov (United States)

    Mirabelli, Gioele; McGeough, Conor; Schmidt, Michael; McCarthy, Eoin K.; Monaghan, Scott; Povey, Ian M.; McCarthy, Melissa; Gity, Farzan; Nagle, Roger; Hughes, Greg; Cafolla, Attilio; Hurley, Paul K.; Duffy, Ray

    2016-09-01

    A surface sensitivity study was performed on different transition-metal dichalcogenides (TMDs) under ambient conditions in order to understand which material is the most suitable for future device applications. Initially, Atomic Force Microscopy and Scanning Electron Microscopy studies were carried out over a period of 27 days on mechanically exfoliated flakes of 5 different TMDs, namely, MoS2, MoSe2, MoTe2, HfS2, and HfSe2. The most reactive were MoTe2 and HfSe2. HfSe2, in particular, showed surface protrusions after ambient exposure, reaching a height and width of approximately 60 nm after a single day. This study was later supplemented by Transmission Electron Microscopy (TEM) cross-sectional analysis, which showed hemispherical-shaped surface blisters that are amorphous in nature, approximately 180-240 nm tall and 420-540 nm wide, after 5 months of air exposure, as well as surface deformation in regions between these structures, related to surface oxidation. An X-ray photoelectron spectroscopy study of atmosphere exposed HfSe2 was conducted over various time scales, which indicated that the Hf undergoes a preferential reaction with oxygen as compared to the Se. Energy-Dispersive X-Ray Spectroscopy showed that the blisters are Se-rich; thus, it is theorised that HfO2 forms when the HfSe2 reacts in ambient, which in turn causes the Se atoms to be aggregated at the surface in the form of blisters. Overall, it is evident that air contact drastically affects the structural properties of TMD materials. This issue poses one of the biggest challenges for future TMD-based devices and technologies.

  20. Observed and simulated time evolution of HCl, ClONO2, and HF total column abundances

    Directory of Open Access Journals (Sweden)

    B.-M. Sinnhuber

    2012-04-01

    measurement and model time series data, with a focus on the time range 2000–2009. This period is chosen because from most of the measurement sites taking part in this study, data are available during these years. The precision of the trends is estimated with the bootstrap resampling method. The sensitivity of the trend results with respect to the fitting function, the time of year chosen and time series length is investigated, as well as a bias due to the irregular sampling of the measurements. The measurements and model results investigated here agree qualitatively on a decrease of the chlorine species by around 1% yr−1. The models simulate an increase of HF of around 1% yr−1. This also agrees well with most of the measurements, but some of the FTIR series in the Northern Hemisphere show a stabilisation or even a decrease in the last few years. In general, for all three gases, the measured trends vary more strongly with latitude and hemisphere than the modelled trends. Relative to the FTIR measurements, the models tend to underestimate the decreasing chlorine trends and to overestimate the fluorine increase in the Northern Hemisphere. At most sites, the models simulate a stronger decrease of ClONO2 than of HCl. In the FTIR measurements, this difference between the trends of HCl and ClONO2 depends strongly on latitude, especially in the Northern Hemisphere.

  1. Soluble fiber dextrin enhances the satiating power of beverages.

    Science.gov (United States)

    Monsivais, Pablo; Carter, Brett E; Christiansen, Matthew; Perrigue, Martine M; Drewnowski, Adam

    2011-02-01

    This study compared the effects of four types of fiber on satiety and energy intakes at the next meal using a standard double-blinded preload study design. Study participants (14 men and 22 women) each took part in 6 study sessions. Study preloads were a combination of a solid snack and a liquid beverage (energy range 0.78-0.83 MJ) containing four different types of fiber: soluble fiber dextrin (12 g), soluble corn fiber (11.8 g), polydextrose (11.8 g), and resistant starch (11.2g). All four fibers were compared to two control conditions of equal volume: an isoenergetic, low-fiber preload and a lower-energy, low-fiber preload. All preloads were presented twice for a total of 0.35-1.65 MJ and 1-24 g fiber. Satiety ratings were collected for 20 min intervals for 220 min during the morning testing session. A test meal was served at 1200 h and plate waste measured. The five higher-energy preloads led to higher fullness and lower hunger ratings compared to the low-energy control but were not significantly different from each other. Relative to the isoenergetic control, only soluble fiber dextrin significantly suppressed energy intakes (p=0.023). Supplementing beverages with soluble fiber dextrin affects short term energy intake and may have implications for weight control. Copyright © 2010 Elsevier Ltd. All rights reserved.

  2. Comparison between real drifter's trajectories and simulated trajectories using HF radar data, in the Bay of Biscay

    Science.gov (United States)

    Solabarrieta, Lohitzune; Cook, Michael; Paduan, Jeffrey; Sergey, Frolov; Rubio, Anna; Fontán, Almudena; Castanedo, Sonia; Gonzalez, Manuel; Medina, Raúl; Fernández, Vicente; Charria, Guillaume

    2013-04-01

    A High Frequency (HF) radar network is operational since the beginning of 2009 for the oceanic region of the Basque Country, Spain (south-eastern part of the Bay of Biscay, Atlantic Ocean). It forms part of the Basque operational data acquisition system, established by the Directorate of Emergency Attention and Meteorology of the Basque Government. It is made up of two antennas emitting at 40 kHz broadband and 4.5 MHz frequency and covering a 150 km range with 5 km radial and 5° angular resolutions. Hourly space- and time-covering measurements are contributing considerably to the study of surface current patterns and the main physical processes in the area. Additional applications relate, for example, to security of navigation, maritime rescue, validation and improvement of numerical models and trajectories prediction. Since 2009, different drifters have been deployed in the study area. Since the radar has been proved to reproduce the time evolution of the currents through comparison with moored buoys with a reasonable accuracy, the aim of this work is to evaluate the capabilities of the system to reproduce the trajectories of a set of drifters available in the study area. To make trajectory simulations, we will use HF radar total velocities, surface velocities obtained from EOF (Empirical Orthogonal Function) analysis of the whole radar data set, forecast velocities for 48 hours and also OMA (Open-Boundary Modal Analysis) derived current velocities.

  3. Xanthoceraside hollow gold nanoparticles, green pharmaceutics preparation for poorly water-soluble natural anti-AD medicine.

    Science.gov (United States)

    Meng, Da-Li; Shang, Lei; Feng, Xiao-He; Huang, Xing-Fei; Che, Xin

    2016-06-15

    In order to increase the solubility of poorly water-soluble natural product, xanthoceraside, an effective anti-AD compound from Xanthoceras sorbifolia Bunge, and maintain its natural property, the xanthoceraside hollow gold nanoparticles were successively prepared by green ultrasonic method with silica spheres as templates and HF solution as selective etching solvent. Hollow gold nanoparticles and drug-loaded hollow gold nanoparticles were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The solubilities of xanthoceraside loaded on hollow gold nanoparticles were increased obviously from 3.0μg/ml and 2.5μg/ml to 12.7μg/ml and 10.7μg/ml at 25°C and 37°C, respectively. The results of XRD and DSC indicated that the reason for this increase was mainly due to the amorphous state of xanthoceraside loaded on the hollow gold nanoparticles. In summary, the method of loading xanthoceraside onto hollow gold nanoparticles was a green and useful strategy to improve the solubility and dissolution of poorly water-soluble natural products and worth to applying to other natural products. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. EURObservational Research Programme : The Heart Failure Pilot Survey (ESC-HF Pilot)

    NARCIS (Netherlands)

    Maggioni, Aldo P.; Dahlstrom, Ulf; Filippatos, Gerasimos; Chioncel, Ovidiu; Crespo Leiro, Marisa; Drozdz, Jaroslaw; Fruhwald, Friedrich; Gullestad, Lars; Logeart, Damien; Metra, Marco; Parissis, John; Persson, Hans; Ponikowski, Piotr; Rauchhaus, Mathias; Voors, Adriaan A.; Nielsen, Olav Wendelboe; Zannad, Faiez; Tavazzi, Luigi

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating the

  5. EURObservational Research Programme: the Heart Failure Pilot Survey (ESC-HF Pilot)

    DEFF Research Database (Denmark)

    Maggioni, Aldo P; Dahlström, Ulf; Filippatos, Gerasimos;

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating...... the structure, performance, and quality of the data set, for continuing the survey into a permanent registry....

  6. Effects of sol aging on resistive switching behaviors of HfO{sub x} resistive memories

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Chih-Chieh, E-mail: cchsu@yuntech.edu.tw [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Department of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting [Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China)

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfO{sub x} resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfO{sub x} surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfO{sub x} film can be avoided. Under this circumstance, effects of sol aging time on the HfO{sub x} films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfO{sub x} RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfO{sub x} layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfO{sub x} film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfO{sub x} resistive switching characteristic induced by sol aging.

  7. The effects of composition on mechanical properties of W-4Re-Hf-C alloys

    Science.gov (United States)

    Witzke, W. R.

    1974-01-01

    Studies were made of the effects of alloy composition on the mechanical behavior of as-worked W-4Re-Hf-C alloys containing up to about 0.8 mol % Hfc. Extracted second-phase particles were analyzed and related to alloy composition and creep strength. While strengthening is attributed to HfC particles, the presence of excess hafnium or carbon (above the calculated amounts for stoichiometric HfC) in swaged W-4Re-Hf-C alloys generally causes a reduction of the high-temperature (1930 C) tensile strength; maximum creep strength is, however, indicated for alloys with a slight (about 0.05 to 0.1 at. %) excess of hafnium. Particle strengthening is reduced by WC in solid solution with HfC for allow compositions with an excess of carbon. The low-temperature ductility of worked W-4Re-Hf-C alloys appears to be far more dependent on the amount of excess C or Hf present than on the HfC particle content in the range studies.

  8. First results on the sorption behaviour of Rutherfordium from HCl/HF containing aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Schumann, D.; Nitsche, H. [Technische Univ. Dresden (Germany); Taut, S. [Forschungszentrum Rossendorf e.V. (FZR), Dresden (Germany); Jost, D.T.; Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Yakushev, A.B.; Buklanov, G.V.; Domanov, V.P.; Lien Din Thi [Joint Inst. for Nuclear Research, Dubna (Russian Federation); Kubica, B.; Misiak, R.; Szeglowski, Z. [NINP Cracow (Poland)

    1997-09-01

    Rutherfordium shows strong sorption on the cation exchanger DOWEX 50x8 at a concentration of 0.1 M HCl/10{sup -2} M HF. This shows that Rf behaves under these conditions differently from Hf and Zr and more like Th under these conditions. (author) 1 fig., 5 refs.

  9. Effects of sol aging on resistive switching behaviors of HfOx resistive memories

    Science.gov (United States)

    Hsu, Chih-Chieh; Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfOx resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfOx surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfOx film can be avoided. Under this circumstance, effects of sol aging time on the HfOx films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfOx RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfOx layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfOx film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfOx resistive switching characteristic induced by sol aging.

  10. The Modulation of Ionospheric Alfven Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    NiBin-bin; ZhaoZheng-yu; XieShu-guo

    2003-01-01

    The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature varia-tions on the Alfven resonant field, We discuss the mechanism of the modulation effect and lucubrate possible reasons for the Doppler effect. The results show that the Alfven resonant field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR on HF waves has a quasi-quadratic relation with the Alfven field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase vari-ation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  11. New PWM method and commutation strategy for HF-link converters for fuel cells and photovoltaics

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper presents a new PWM method and commutation strategy for HF-link converters, which leads to safe commutation of the load current in the output bidirectional bridge. The proposed implementation is independent of the particular HF-link converter topology and bidirectional switch selection...

  12. The first HF table, after heat treatment and ready to be machined in HEPCO, Arak (IRAN)

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    The first HF support table 'load' tested by the team of people who have contributed to it from design to welding. This table will support the 240 tons of 1 HF detector and will integrate the raisers which will push it up to the beam line level. It is the first Iranian contribution to an HEP experiment.

  13. 47 CFR 73.758 - System specifications for digitally modulated emissions in the HF broadcasting service.

    Science.gov (United States)

    2010-10-01

    ... emissions in the HF broadcasting service. 73.758 Section 73.758 Telecommunication FEDERAL COMMUNICATIONS... § 73.758 System specifications for digitally modulated emissions in the HF broadcasting service. (a... digital audio broadcasting and datacasting are authorized. The RF requirements for the DRM system...

  14. Computed tomographic coronary angiography for patients with heart failure (CTA-HF): a randomized controlled trial (IMAGE HF Project 1-C).

    Science.gov (United States)

    Chow, Benjamin J W; Green, Rachel E; Coyle, Doug; Laine, Mika; Hanninen, Helena; Leskinen, Hanna; Rajda, Miroslav; Larose, Eric; Hartikainen, Juha; Hedman, Marja; Mielniczuk, Lisa; O'Meara, Eileen; deKemp, Robert A; Klein, Ran; Paterson, Ian; White, James A; Yla-Herttuala, Seppo; Leber, Alex; Tandon, Vikas; Lee, Ting; Al-Hesayen, Abdul; Hessian, Renee; Dowsley, Taylor; Kass, Malek; Kelly, Cathy; Garrard, Linda; Tardif, Jean-Claude; Knuuti, Juhani; Beanlands, Rob S; Wells, George A

    2013-12-26

    The prevalence of heart failure (HF) is rising in industrialized and developing countries. Though invasive coronary angiography (ICA) remains the gold standard for anatomical assessment of coronary artery disease in HF patients, alternatives are being sought. Computed tomographic coronary angiography (CTA) has emerged as an accurate non-invasive diagnostic tool for coronary artery disease (CAD) and has been demonstrated to have prognostic value. Whether or not CTA can be used in HF patients is unknown. Acknowledging the aging population, the growing prevalence of HF and the increasing financial burden of healthcare, we need to identify non-invasive diagnostic tests that are available, safe, accurate and cost-effective. The proposed study aims to provide insight into the efficacy of CTA in HF patients. A multicenter randomized controlled trial will enroll 250 HF patients requiring coronary anatomical definition. Enrolled patients will be randomized to either CTA or ICA (n = 125 per group) as the first test to define coronary anatomy. The primary outcomes will be collected to determine downstream resource utilization. Secondary outcomes will include the composite clinical events and major adverse cardiac events. In addition, the accuracy of CTA for detecting coronary anatomy and obstruction will be assessed in patients who subsequently undergo both CTA and ICA. It is expected that CTA will be a more cost-effective strategy for diagnosis: yielding similar outcomes with fewer procedural risks and improved resource utilization. ClinicalTrials.gov, NCT01283659. Team grant #CIF 99470.

  15. Dye solubility in supercritical carbon dioxide fluid

    Directory of Open Access Journals (Sweden)

    Yan Jun

    2015-01-01

    Full Text Available Supercritical carbon dioxide fluid is an alternative solvent for the water of the traditional dyeing. The solubility of dyestuff affects greatly the dyeing process. A theoretical model for predicting the dye solubility is proposed and verified experimentally. The paper concludes that the pressure has a greater impact on the dyestuff solubility than temperature, and an optimal dyeing condition is suggested for the highest distribution coefficient of dyestuff.

  16. Signal processing technique for randomly discontinuous spectra HF radar waveforms

    Institute of Scientific and Technical Information of China (English)

    张东坡; 刘兴钊

    2004-01-01

    A major problem with all high frequency (HF) radars is a relatively poor range resolution available due to many interference sources. To avoid the interferences in frequency domain and operate with wideband, the randomly discontinuous spectra (RDS) signal is employed. However, it results in high range sidelobes when matching the reflected echo, which is much more difficult for target detection. A new signal processing technique that is radically different from the conventional technique to lower range sidelobes is introduced. This method is based on suppressing the selfclutter of the radar range ambiguity function (AF) by mismatched filtering. An effective algorithm is adopted to solve the filter coefficients. Simulation results show that the peak sidelobe level can be reduced to -30dB and the achievable system bandwidth is about 400KHz. The technique is adaptable to practical radar systems and applicable for other realtime signal processing.

  17. Modification of polarization filtering technique in HF ground wave radar

    Institute of Scientific and Technical Information of China (English)

    Zhang Guoyi; Tan Zhongji; Wang Jiantao

    2006-01-01

    The polarization filter using three orthogonal linear polarization antennas can suppress more disturbances than the polarization filter using two orthogonal linear polarization antennas in HF ground wave radar. But the algorithm of the threedimension filter is relatively complicated and not suitable for real-time processing. It can't use linear and nonlinear polarization vector translation technique directly. A modified polarization filter which is simple and has same suppressing ability as the three-dimension polarization filter is given. It only has half parameters of the primary one. Some problems about estimation of polarization parameters and selection of disturbances are discussed. A method of holding the phase of radar backscatter signal constantly is put forward so that unstationary disturbance signal can be processed.

  18. Toward an european Med HF-radar coastal monitoring

    Science.gov (United States)

    Molcard, A.; Fraunie, P.

    2010-12-01

    The monitoring of coastal areas through HF radar is developping in the european Mediterranean coasts, through national and international projects. Surface current maps may be used for process studies, forecast correction through assimilation, or for practical applications in transport studies (jellyfish, oil-spill, search-and-rescue operations). Results of radar campaigns in the North-western Mediterranean (evidence of mesoscale eddy in the Gulf of Lions and identification of dynamical structures by FSLE in the Ligurian Sea) are shown, as well as techniques for current reconstruction using a single site. A new inter-regional european project started in summer 2010, regrouping 5 countries for an integrated oil-spill coastal awarness network is presented.

  19. Hydrido phosphanido bridged polynuclear complexes obtained by protonation of a phosphinito bridged Pt(I) complex with HBF4 and HF.

    Science.gov (United States)

    Latronico, Mario; Mastrorilli, Piero; Gallo, Vito; Dell'Anna, Maria Michela; Creati, Francesco; Re, Nazzareno; Englert, Ulli

    2011-04-18

    The protonation of the phosphinito-bridged Pt(I) complex [(PHCy(2))Pt(μ-PCy(2)){κ(2)P,O-μ-P(O)Cy(2)}Pt(PHCy(2))](Pt-Pt) (1) by aqueous HBF(4) or hydrofluoric acid leads selectively to the hydrido-bridged solvento species syn-[(PHCy(2))(H(2)O)Pt(μ-PCy(2))(μ-H)Pt(PHCy(2)){κP-P(OH)Cy(2)}](Y)(2)(Pt-Pt) ([2-H(2)O]Y(2)) {Y = BF(4), F(HF)(n)} when an excess of acid was used. On standing in halogenated solvents, complex [2-H(2)O](BF(4))(2) undergoes a slow but complete isomerization to [(PHCy(2))(2)Pt(μ-PCy(2))(μ-H)Pt{κP-P(OH)Cy(2)}(H(2)O)](BF(4))(2)(Pt-Pt) ([4-H(2)O][BF(4)](2)) having the P(OH)Cy(2) ligand trans to the hydride. The water molecule coordinated to platinum in [2-H(2)O][BF(4)](2) is readily replaced by halides, nitriles, and triphenylphosphane, and the acetonitrile complex [2-CH(3)CN][BF(4)](2) was characterized by XRD analysis. Solvento species other than aqua complexes, such as [2-acetone-d(6)](2+) or [2-CD(2)Cl(2)](2+) were obtained in solution by the reaction of excess etherate HBF(4) with 1 in the relevant solvent. The complex [2-H(2)O](Y)(2) [Y = F(HF)(n)] spontaneously isomerizes into the terminal hydrido complexes [(PHCy(2))Pt(μ-PCy(2)){κ(2)P,O-μ-P(O)Cy(2)}Pt(H)(PHCy(2))](Y)(Pt-Pt) ([6](Y)). In the presence of HF, complex [6](Y) transforms into the bis-phosphanido-bridged Pt(II) dinuclear complex [(PHCy(2))(H)Pt(μ-PCy(2))(2)Pt{κP-P(OH)Cy(2)}](Y)(Pt-Pt) ([7](Y)). When the reaction of 1 with HF was carried out with diluted hydrofluoric acid by allowing the HF to slowly diffuse into the dichloromethane solution, the main product was the linear 60e tetranuclear complex [(PHCy(2)){κP-P(O)Cy(2)}Pt(1)(μ-PCy(2))(μ-H)Pt(2)(μ-PCy(2))](2)(Pt(1)-Pt(2)) (8). Insoluble compound 8 is readily protonated by HBF(4) in dichloromethane, forming the more soluble species [(PHCy(2)){κP-P(OH)Cy(2)}Pt(1)(μ-PCy(2))(μ-H)Pt(2)(μ-PCy(2))](2)(BF(4))(2)(Pt(1)-Pt(2)) {[9][BF(4)](2)}. XRD analysis of [9][BF(4)](2)·2CH(2)Cl(2) shows that [9](2+) is comprised of

  20. Telemonitoring Adherence to Medications in Heart Failure Patients (TEAM-HF): A Pilot Randomized Clinical Trial.

    Science.gov (United States)

    Gallagher, Benjamin D; Moise, Nathalie; Haerizadeh, Mytra; Ye, Siqin; Medina, Vivian; Kronish, Ian M

    2017-04-01

    Medication nonadherence contributes to hospitalizations in recently discharged patients with heart failure (HF). We aimed to test the feasibility of telemonitoring medication adherence in patients with HF. We randomized 40 patients (1:1) hospitalized for HF to 30 days of loop diuretic adherence monitoring with telephonic support or to passive adherence monitoring alone. Eighty-three percent of eligible patients agreed to participate. The median age of patients was 64 years, 25% were female, and 45% were Hispanic. Overall, 67% of patients were nonadherent (percentage of days that the correct number of doses were taken telemonitoring was acceptable to most patients with HF. Diuretic nonadherence was common even when patients knew they were being monitored. Future studies should assess whether adherence telemonitoring can improve adherence and reduce readmissions among patients with HF. Copyright © 2016 Elsevier Inc. All rights reserved.

  1. The electronic structure of HfF5- and WF5-

    Science.gov (United States)

    Chen, Hongshan; Andersson, Pontus; Lindahl, Anton O.; Hanstorp, Dag

    2011-08-01

    The electronic structure of HfF5-, WF5- and the related species HfF n and WF n is studied using ab initio methods. Computation reveals that the hafnium fluorides are much more stable than the corresponding tungsten fluorides. The detachment energy of HfF5- is 8.8 eV, whereas the corresponding quantity of WF5- is only 3.9 eV. These results show that WF5- can be photodetached while HfF5- is unaffected, and so it is possible by using photodetachment to suppress the interfering isobar 182W in the ion beam of 182Hf. Such information is the precondition for the successful implementation of a future photodetachment process in Accelerator Mass Spectrometry.

  2. Effect of hydrofluoric acid (HF) concentration to pores size diameter of silicon membrane.

    Science.gov (United States)

    Burham, Norhafizah; Hamzah, Azrul Azlan; Majlis, Burhanuddin Yeop

    2014-01-01

    This paper studies parameters which affect the pore size diameter of a silicon membrane. Electrochemical etching is performed in characterise the parameter involved in this process. The parameter has been studied is volume ratio of hydrofluoric acid (HF) and ethanol as an electrolyte aqueous for electrochemical etch. This electrolyte aqueous solution has been mixed between HF and ethanol with volume ratio 3:7, 5:5, 7:3 and 9:1. As a result, the higher volume of HF in this electrolyte gives the smallest pore size diameter compared to the lower volume of HF. These samples have been dipped into HF and ethanol electrolyte aqueous with supplied 25 mA/cm2 current density for 20, 30, 40, and 50 minutes. The samples will inspect under Scanning Electron Microscope (SEM) to execute the pore formations on silicon membrane surface.

  3. Suspended HfO{sub 2} photonic crystal slab on III-nitride/Si platform

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yongjin; Feng, Jiao; Cao, Ziping; Zhu, Hongbo [Nanjing University of Posts and Telecommunications, Grueenberg Research Centre, Nanjing, Jiang-Su (China)

    2014-06-15

    We present here the fabrication of suspended hafnium oxide (HfO{sub 2}) photonic crystal slab on a III-nitride/Si platform. The calculations are performed to model the suspended HfO{sub 2} photonic crystal slab. Aluminum nitride (AlN) film is employed as the sacrificial layer to form air gap. Photonic crystal patterns are defined by electron beam lithography and transferred into HfO{sub 2} film, and suspended HfO{sub 2} photonic crystal slab is achieved on a III-nitride/Si platform through wet-etching of AlN layer in the alkaline solution. The method is promising for the fabrication of suspended HfO{sub 2} nanostructures incorporating into a III-nitride/Si platform, or acting as the template for epitaxial growth of III-nitride materials. (orig.)

  4. Crystal structure of Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Lili [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); School of Information Science and Technology, Northwest University, Xi' an 710127 (China); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nelson, Matthew; Fancher, Chris M. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Aldridge, Henry [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Iamsasri, Thanakorn; Forrester, Jennifer S.; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nishida, Toshikazu [Department of Electrical and Computer Engineering, University of Florida, Gainesville, Florida 32611 (United States); Moghaddam, Saeed [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2014-01-21

    Si-doped HfO{sub 2} was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO{sub 2} was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO{sub 2}) rather than HfSiO{sub 4}, the latter of which would be expected from existing SiO{sub 2}-HfO{sub 2} phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO{sub 2} shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  5. Tsunami Arrival Detection with High Frequency (HF Radar

    Directory of Open Access Journals (Sweden)

    Donald Barrick

    2012-05-01

    Full Text Available Quantitative real-time observations of a tsunami have been limited to deep-water, pressure-sensor observations of changes in the sea surface elevation and observations of sea level fluctuations at the coast, which are essentially point measurements. Constrained by these data, models have been used for predictions and warning of the arrival of a tsunami, but to date no system exists for local detection of an actual incoming wave with a significant warning capability. Networks of coastal high frequency (HF-radars are now routinely observing surface currents in many countries. We report here on an empirical method for the detection of the initial arrival of a tsunami, and demonstrate its use with results from data measured by fourteen HF radar sites in Japan and USA following the magnitude 9.0 earthquake off Sendai, Japan, on 11 March 2011. The distance offshore at which the tsunami can be detected, and hence the warning time provided, depends on the bathymetry: the wider the shallow continental shelf, the greater this time. We compare arrival times at the radars with those measured by neighboring tide gauges. Arrival times measured by the radars preceded those at neighboring tide gauges by an average of 19 min (Japan and 15 min (USA The initial water-height increase due to the tsunami as measured by the tide gauges was moderate, ranging from 0.3 to 2 m. Thus it appears possible to detect even moderate tsunamis using this method. Larger tsunamis could obviously be detected further from the coast. We find that tsunami arrival within the radar coverage area can be announced 8 min (i.e., twice the radar spectral time resolution after its first appearance. This can provide advance warning of the tsunami approach to the coastline locations.

  6. New Adaptive Data Transmission Scheme Over HF Radio

    Directory of Open Access Journals (Sweden)

    Adil H. Ahmad

    2008-01-01

    Full Text Available Acceptable Bit Error rate can be maintained by adapting some of the design parameters such as modulation, symbol rate, constellation size, and transmit power according to the channel state.An estimate of HF propagation effects can be used to design an adaptive data transmission system over HF link. The proposed system combines the well known Automatic Link Establishment (ALE together with variable rate transmission system. The standard ALE is modified to suite the required goal of selecting the best carrier frequency (channel for a given transmission. This is based on measuring SINAD (Signal plus Noise plus Distortion to Noise plus Distortion, RSL (Received Signal Level, multipath phase distortion and BER (Bit Error Rate for each channel in the frequency list. Channel condition evaluation is done by two arrangements. In the first an FFT analysis is used where a pilot signal is transmitted over the channel, while the data itself is used in the second arrangement. Passive channel assessment is used to avoid bad channels hence limiting the frequency pool size to be used in the point to point communication and the time required for scanning and linking. An exchange of channel information between the transmitting and receiving stations is considered to select the modulation scheme for transmission. Mainly MPSK and MFSK are considered with different levels giving different data rate according to the channel condition. The results of the computer simulation have shown that when transmitting at a fixed channel symbol rate of 1200 symbol/sec, the information rate ranges from 2400 bps using 4FSK up to 3600 bps using 8PSK for SNR ranges from 11dB up to 26dB.

  7. In-situ zircon U-Pb age and Hf-O isotopic constraints on the origin of the Hasan-Robat A-type granite from Sanandaj-Sirjan zone, Iran: implications for reworking of Cadomian arc igneous rocks

    Science.gov (United States)

    Honarmand, Maryam; Li, Xian-Hua; Nabatian, Ghasem; Neubauer, Franz

    2017-01-01

    The Lower Permian Hasan-Robat syenogranite occurs as a single pluton and intruded the Upper Carboniferous-Lower Permian sandstones and dolomitic limestones in the central part of the Sanandaj-Sirjan zone. This syenogranitic intrusion shows A-type granitic affinity and is a good representative of Early Permian igneous activity in Iran. SIMS U-Pb zircon analyses indicate a crystallization age of 294.2 ± 2.5 Ma for the Hasan-Robat A-type granite. In-situ Lu-Hf and oxygen isotope analyses of magmatic zircons were carried out to infer the magma sources and evolution of the Hasan-Robat A-type syenogranite. The Hf-O zircon isotopic compositions are relatively homogeneous, with nearly chondritic ɛHf(t) values of -0.8 to +2.4 corresponding to two-stage zircon Hf model ages of 1.15-1.36 Ga. The δ18O values of zircon range from +7.6 to +8.6‰. The Hf model ages of the Hasan-Robat zircons is within the range of those reported from the Cadomian granitoids in Iran. The isotopic features of the Hasan-Robat syenogranite are in good agreement with Hf isotopic values and Hf and Nd model ages reported from the Cadomian arc magmatic suites in Iran. Thus, partial melting of these Cadomian igneous rocks would be the favorite source for the Hasan-Robat syenogranitic magma during the opening of the Neotethys Ocean and separation of Iranian terranes from the northern margin of Gondwana.

  8. The Thermodynamic Characterization of ZrCo–H, HfCo−H, HfNi−H and Zr{sub 1–x}HfxNi(Co) Alloy–H Systems

    Energy Technology Data Exchange (ETDEWEB)

    Flanagan, Ted B., E-mail: ted.flanagan@uvm.edu; Noh, Hak; Luo, Suifang

    2016-08-25

    ZrCo and HfCo intermetallic compounds have the same cubic (CsCl-type) structure and their ternary (Zr{sub 1−x}Hf{sub x})Co alloys are also cubic. ZrNi and HfNi intermetallic compounds have the orthorhombic structure (CrB-type) and the ternary (Zr{sub 1−x}Hf{sub x})Ni alloys also have this structure. Thermodynamic data for hydride formation and decomposition in ZrCo, HfCo and HfNi intermetallic compounds have been determined from reaction calorimetry and from pressure-composition isotherms. Thermodynamic data have been determined for the three ternary alloys: (Zr{sub 0.75}Hf{sub 0.25})Co, (Zr{sub 0.50}Hf{sub 0.50})Co, and (Zr{sub 0.25}Hf{sub 0.75})Co and the four ternary alloys: (Zr{sub 0.875}Hf{sub 0.125})Ni, (Zr{sub 0.75}Hf{sub 0.25})Ni, (Zr{sub 0.50}Hf{sub 0.50})Ni, and (Zr{sub 0.25}Hf{sub 0.75})Ni. This offers the opportunity to learn how the thermodynamic properties of the ternary alloy-H systems change with the stoichiometry of alloys with the same structure. - Highlights: • Calorimetric enthalpies determined for H absorption by ZrCo, HfCo, HfNi are determined. • Ternary alloys, e.g., Zr{sub 1−x}Hf{sub x}Ni, prepared and characterized by x-ray diffraction. • Isotherms for the ternary alloys give thermodynamic parameters for H solution.

  9. Garnet effect on Nd-Hf isotope decoupling: Evidence from the Jinfosi batholith, Northern Tibetan Plateau

    Science.gov (United States)

    Huang, Hui; Niu, Yaoling; Mo, Xuanxue

    2017-03-01

    The initial Nd and Hf isotope ratios of a 420 Ma post-collisional dioritic-granitic batholith from the Northern Tibetan plateau define a negative trend above and orthogonal to the ԐHf(t)-ԐNd(t) terrestrial array. This uncommon trend offers an insight into the origin of the puzzling Nd-Hf isotope decoupling in the crustal rocks. On this trend, samples depleted in heavy rare earth elements (HREEs, i.e., [Dy/Yb]N ≫ 1) deviate most from the terrestrial array whereas samples with flat HREEs (i.e., [Dy/Yb]N ≥ 1) deviate less or plot within the terrestrial array, pointing to the controlling effect of garnet in the magma source. Ancient garnet-bearing residues after melt extraction will have elevated Lu/Hf ratios and can evolve with time to produce high ԐHf(t) at a low ԐNd(t) value. Mixing of melts derived from such source lithologies (high Lu/Hf) with melts possessing a within-terrestrial array Nd-Hf isotopic composition (low Lu/Hf) best explains the observed trend orthogonal to the terrestrial array. The samples from the Jinfosi batholith with the most decoupled Nd-Hf isotope compositions require a larger degree (> 40%) and ancient (i.e., ≥ 1.8 Gyr) previous melt extraction from their source. It follows that the ancient melts with depleted HREEs complementary to those garnet-bearing residues should have low ԐHf values and plot below the terrestrial array, which is indeed shown by some Archean/Paleoproterozic TTGs.

  10. Hardness and Second Phase Percentage of Ni-Ti-Hf Compounds After Heat Treatment at 700C

    Science.gov (United States)

    Stanford, Malcolm K.

    2017-01-01

    The Vickers hardness and second phase precipitation of three ternary intermetallic Ni-Ti-Hf compounds containing either 1, 3 or 5 at.% Hf were compared to 60-Nitinol (55 at.% Ni - 45 at.% Ti). Heat treatment either at 700 C or with a subsequent aging step, hardened the 3 and 5 at.% Hf-containing ternaries to approximately 620 HV (56 HRC). Heat treatment increased the hardness of the 1 at.% Hf compound by more than 25 percent. Average hardness of the 3 and 5 at.% Hf ternaries, though higher than that of the binary Ni-Ti or the Ni-Ti-Hf compound containing 1 at.% Hf, appeared to be fairly insensitive to the different heat treatments. There was a drastic reduction of fatigue-enhancing second phase precipitates for the 5 at.% Hf ternaries compared to the other compounds. These results should guide materials selection for development of aerospace componentry.

  11. Assessing the isotopic evolution of S-type granites of the Carlos Chagas Batholith, SE Brazil: Clues from U-Pb, Hf isotopes, Ti geothermometry and trace element composition of zircon

    Science.gov (United States)

    Melo, Marilane G.; Lana, Cristiano; Stevens, Gary; Pedrosa-Soares, Antônio C.; Gerdes, Axel; Alkmin, Leonardo A.; Nalini, Hermínio A.; Alkmim, Fernando F.

    2017-07-01

    The Carlos Chagas batholith (CCB) is a very large ( 14,000 km2) S-type granitic body formed during the syn-collisional stage of the Araçuaí orogen (southeastern Brazil). Zircons extracted from the CCB record a wide range of U-Pb ages (from 825 to 490 Ma), indicating a complex history of inheritance, magmatic crystallization and partial melting during the evolution of the orogeny. Magmatic zircons (ca. 578-588 Ma) are marked by similar Hf isotope compositions and REE patterns to those of inherited cores (ca. 825-600 Ma), indicating that these aspects of the chemical signature of the magmatic zircons have likely been inherited from the source. The U-Pb ages and initial 176Hf/177Hf ratios from anatectic and metamorphic zircon domains are consistent with a two-stage metamorphic evolution marked by contrasting mechanisms of zircon growth and recrystallization during the orogeny. Ti-in-zircon thermometry is consistent with the findings of previous metamorphic work and indicates that the two metamorphic events in the batholith reached granulite facies conditions (> 800 °C) producing two generations of garnet via fluid-absent partial melting reactions. The oldest metamorphic episode (ca. 570-550 Ma) is recorded by development of thin anatectic overgrowths on older cores and by growth of new anatectic zircon crystals. Both domains have higher initial 176Hf/177Hf values compared to relict cores and display REE patterns typical of zircon that grew contemporaneously with peritectic garnet through biotite-absent fluid partial melting reactions. Hf isotopic and chemical evidences indicate that a second anatectic episode (ca. 535-500 Ma) is only recorded in parts from the CCB. In these rocks, the growth of new anatectic zircon and/or overgrowths is marked by high initial 176Hf/177Hf values and also by formation of second generation of garnet, as indicated by petrographic observations and REE patterns. In addition, some rocks contain zircon crystals formed by solid

  12. Mixing and melt sources in the Miocene Aztec Wash pluton (Nevada, USA) as revealed by zircon Hf and O and whole rock Sr, Nd, and Hf isotopes

    Science.gov (United States)

    Ryan, M.; Miller, J. S.; Miller, C. F.; Bromley, S.; Davies, G. R.; Schmitt, A. K.

    2011-12-01

    The 15.6 Ma Aztec Wash Pluton (AWP) is one of several Miocene intrusions located within the northern Colorado River extensional corridor. Extensive E-W tilting of fault blocks has exposed the pluton from the roof to 5 km structural depth. Earlier field and petrologic studies subdivided the AWP into two distinct zones: (1) a Granite Zone (GZ) comprised of relatively homogeneous granite with subtle differences in textures and mineralogy; (2) a Heterogeneous Zone (HZ), which interfingers the GZ, contains evidence for mafic and felsic magma input with a wide compositional range (42-78 wt% SiO2), and abundant field evidence for hybridization. Previous whole rock geochemistry and zircon trace element analyses indicated that compositional variation was produced by multi-component mixing between mafic and felsic melts within the HZ. New whole rock Sr, Nd, and Hf isotope data from the HZ show that all rocks (including high-silica granites) formed by mixing Precambrian crust and enriched mantle, with mixtures having a large mantle fraction (≥50%). New Hf (n=189) and O (n=241) isotope analyses of zircon from samples in the HZ confirm these melt sources and provide a broader perspective on hybridization processes within the AWP. Zircon grains from all samples show heterogeneous Hf and O isotopic compositions (-5 to -18 ɛHf; 4.5-7.5% δ18O), but despite the clear signature of Precambrian crust in the whole rock data, obvious Precambrian zircons (or cores) were mostly absent; only one zircon was clearly Precambrian (ɛHf = -25). Resolvable intragrain variability is relatively limited (including the Precambrian grain, which is unzoned). Zircons from hand samples and from compositional groups also show heterogeneous ɛHf and δ18O values, although the spreads are more restricted than in the whole data set (6-10 ɛHf in granites, 5-7 ɛHf in intermediate "hybrids", 5-6 ɛHf in gabbro/diorite sheets). Oxygen isotope values for the zircons also show intra-handsample heterogeneity

  13. Lu-Hf garnet geochronology applied to plate boundary zones: Insights from the (U)HP terrane exhumed within the Woodlark Rift

    Science.gov (United States)

    Zirakparvar, N. A.; Baldwin, S. L.; Vervoort, J. D.

    2011-09-01

    /early Cenozoic time. In order to relate the (U)HP metamorphic rocks to the larger-scale tectonic evolution of the Woodlark Rift, a third Lu-Hf age of 11.2 ± 2.1 Ma was determined for dynamically recrystallized garnet from the southeastern margin of the rift. While the tectonic implications of the Lu-Hf age from the southeastern-rifted margin are not fully known, this result suggests that the eastern and western parts of the Woodlark Rift might have a different metamorphic history. The garnet Lu-Hf results demonstrate that prior to rifting, the Woodlark Rift underwent a complex history of metamorphism involving garnet growth and recrystallization. The ability of the Lu-Hf system to date Late Miocene garnet growth, and at the same time preserve Latest Cretaceous garnets within Pleistocene shear zones in the Woodlark Rift demonstrate that Lu-Hf garnet geochronology is an essential component of investigations where the primary objective is documenting and understanding the full range of plate boundary processes recorded in metamorphic minerals.

  14. Solubility Enhancement of a Poorly Water Soluble Drug by Forming Solid Dispersions using Mechanochemical Activation

    OpenAIRE

    Rojas-Oviedo, I.; Retchkiman-Corona, B.; Quirino-Barreda, C. T.; Cárdenas, J.; Schabes-Retchkiman, P. S.

    2012-01-01

    Mechanochemical activation is a practical cogrinding operation used to obtain a solid dispersion of a poorly water soluble drug through changes in the solid state molecular aggregation of drug-carrier mixtures and the formation of noncovalent interactions (hydrogen bonds) between two crystalline solids such as a soluble carrier, lactose, and a poorly soluble drug, indomethacin, in order to improve its solubility and dissolution rate. Samples of indomethacin and a physical mixture with a weigh...

  15. Computational-Experimental Processing of Boride/Carbide Composites by Reactive Infusion of Hf Alloy Melts into B4C

    Science.gov (United States)

    2015-09-16

    elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the effects of surface tension and viscosity during processing of melts...project primarily investigated computationally the infusion of liquid elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the... effects of surface tension and viscosity during processing of melts with a packed bed of B4C to form boride-carbide precipitates. Although the

  16. Structure, optical properties and thermal stability of HfErO films deposited by simultaneous RF and VHF magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, H.Y. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Nanjing University of Posts and Telecommunications, School of Tongda, Nanjing (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); He, H.J.; Zhang, Z.; Jin, C.G.; Yang, Y.; Wang, Y.Y.; Ye, C. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Zhuge, L.J. [Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Soochow University, Analysis and Testing Center, Suzhou (China); Wu, X.M. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Chinese Academy of Sciences, State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai (China)

    2015-01-23

    HfErO films are deposited on Si substrates by simultaneous radio frequency (RF) and very high frequency (VHF) magnetron sputtering technique. The content of the doped ingredient of Er and the body composition of HfO{sub x} are, respectively, controlled through the VHF and RF powers. Low content of Er doping in the HfErO films can be achieved, because the VHF source of 27.12 MHz has higher ion energy and lower ion flux than the RF source resulting in low sputtering rate in the magnetron sputtering system. The structure, optical properties and thermal stability of the HfErO films are investigated in this work. Results show that the doped content of Er is independently controlled by the VHF power. The oxygen vacancies are created by the Er incorporation. The hafnium in the HfErO films forms mixed valence of Hf{sup 2+} and Hf{sup 4+}. The HfErO films are composed with the structures of HfO{sub 2}, HfO and ErO{sub x}, which can be optimized through the VHF power. At high VHF power, the Hf-Er-O bonds are formed, which demonstrates that the Er atoms are doped into the lattice of HfO{sub 2} in the HfErO films. The HfErO films have bad thermal stability as the crystallization temperature decreases from 900 to 800 C. After thermal annealing, cubic phase of HfO{sub 2} are stabilized, which is ascribed to the oxygen vacancies creation by the Er incorporation. The optical properties such as the refractive index and the optical band gap of the HfErO films are optimized by the VHF power. (orig.)

  17. Archean Lithosphere Beneath Arctic Canada: Lu-Hf Isotope Systematics for Kimberlite-Hosted Garnet-Peridotites From Somerset Island

    Science.gov (United States)

    Schmidberger, S. S.; Simonetti, A.; Francis, D.; Gariepy, C.

    2001-05-01

    Knowledge of the age of lithospheric mantle underlying the continents provides valuable constraints for the timing of formation and stabilization of Archean cratons. This study reports Lu-Hf isotopic data for garnet-peridotites, and their constituent garnets, from the Nikos kimberlite (100 Ma) on Somerset Island in the Canadian Arctic obtained using a Micromass IsoProbe multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at GEOTOP-UQAM. The low temperature peridotites (1100 C; 160-190 km) and their 176Hf/177Hf(0.1Ga) isotopic compositions (0.28265-0.28333; \\epsilonHf(0.1Ga)=-2 to +22) are less radiogenic than those of the shallow xenoliths. A Lu-Hf isochron for six peridotites yields a mid Archean age of 3.4\\pm0.3 Ga and an initial 176Hf/177Hf ratio of 0.28101\\pm24. The remaining peridotites (n=9), in contrast, are characterized by extremely high (+35) initial \\epsilonHf(3.4Ga) values, which correlate negatively with their 176Lu/177Hf ratios, suggesting addition of Hf as a result of metasomatic interaction with the host kimberlite. The garnets from the low temperature (3.4 Ga old) peridotites are characterized by high 176Lu/177Hf ratios and define an errorchron age of 1.4\\pm0.2 Ga, which may reflect re-equilibration of Hf during kimberlite magmatism.

  18. Design for human factors (DfHF): a grounded theory for integrating human factors into production design processes.

    Science.gov (United States)

    Village, Judy; Searcy, Cory; Salustri, Filipo; Patrick Neumann, W

    2015-01-01

    The 'design for human factors' grounded theory explains 'how' human factors (HF) went from a reactive, after-injury programme in safety, to being proactively integrated into each step of the production design process. In this longitudinal case study collaboration with engineers and HF Specialists in a large electronics manufacturer, qualitative data (e.g. meetings, interviews, observations and reflections) were analysed using a grounded theory methodology. The central tenet in the theory is that when HF Specialists acclimated to the engineering process, language and tools, and strategically aligned HF to the design and business goals of the organisation, HF became a means to improve business performance. This led to engineers 'pulling' HF Specialists onto their team. HF targets were adopted into engineering tools to communicate HF concerns quantitatively, drive continuous improvement, visibly demonstrate change and lead to benchmarking. Senior management held engineers accountable for HF as a key performance indicator, thus integrating HF into the production design process. Practitioner Summary: Research and practice lack explanations about how HF can be integrated early in design of production systems. This three-year case study and the theory derived demonstrate how ergonomists changed their focus to align with design and business goals to integrate HF into the design process.

  19. Applications of soluble dietary fibers in beverages

    OpenAIRE

    C. I. Beristain; M. E. Rodríguez-Huezo; C. Lobato-Calleros; F. Cruz-Sosa; R. Pedroza-Islas; J. R. Verde-Calvo

    2006-01-01

    In this work the importance of soluble dietary fibers in the human diet is discussed. Traditional and new sources of soluble dietary fiber are mentioned, and a description of how to apply them in different types of beverages such as energy drinks, sport drinks, carbonated beverages and protein-based beverages in order to achieve enhanced functional properties is given.

  20. A Colorful Solubility Exercise for Organic Chemistry

    Science.gov (United States)

    Shugrue, Christopher R.; Mentzen, Hans H., II; Linton, Brian R.

    2015-01-01

    A discovery chemistry laboratory has been developed for the introductory organic chemistry student to investigate the concepts of polarity, miscibility, solubility, and density. The simple procedure takes advantage of the solubility of two colored dyes in a series of solvents or solvent mixtures, and the diffusion of colors can be easily…

  1. A Colorful Solubility Exercise for Organic Chemistry

    Science.gov (United States)

    Shugrue, Christopher R.; Mentzen, Hans H., II; Linton, Brian R.

    2015-01-01

    A discovery chemistry laboratory has been developed for the introductory organic chemistry student to investigate the concepts of polarity, miscibility, solubility, and density. The simple procedure takes advantage of the solubility of two colored dyes in a series of solvents or solvent mixtures, and the diffusion of colors can be easily…

  2. Solubility Characteristics of PCBM and C60.

    Science.gov (United States)

    Boucher, David; Howell, Jason

    2016-11-10

    Empirical data indicate that several good solvents for C60 and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) have substantial polar and hydrogen-bonding components, which are not intrinsic to the structure of the C60 and PCBM molecules themselves. Functional solubility parameter (FSP) and convex solubility parameter (CSP) computations are performed on C60 and PCBM using solubility data available in the literature. The CSP and FSP results are compared to previously reported Hansen solubility parameters (HSPs) and to the parameters calculated using additive functional group contribution methods. The CSP and FSP methods confirm the anomalously large polar and hydrogen-bonding parameters, δP and δH, obtained experimentally for C60 and PCBM. This behavior, which is quite irregular given the structure of the molecules, is due to the fact that several good solvents have high δP and δH values. Thus, these irregularities are highlighted by the CSP and FSP calculations. Additional contradictory solubility characteristics are disclosed by comparing the experimental solubility parameters to a linear solvation energy relationship (LSER) model, additive functional group calculations, and COSMO-RS computations. The FSP solubility function strongly suggests that the solubility parameters do not accurately represent the cohesive energy density properties of C60 and PCBM, as intended, but rather they manifest the properties of the solvents, e.g., high δP and δH values, that are necessary to accommodate these molecules in the liquid phase.

  3. A framework for API solubility modelling

    DEFF Research Database (Denmark)

    Conte, Elisa; Gani, Rafiqul; Crafts, Peter

    The solubility of solid organic compounds in water and organic solvents is a fundamental thermodynamic property for many purposes such as product-process design and optimization, for the chemical and pharmaceutical industry. Experimental literature solubility data are usually scarce and temperature...

  4. Development and Application of Interatomic Potentials for Ultra High Temperature Ceramics (UHTC): ZrB2 and HfB2

    Science.gov (United States)

    Lawson, John W.; Daw, Murray; Bauschlicher

    2012-01-01

    Ultra high temperature ceramics (UHTC) including ZrB2 and HfB2 are characterized by high melting point, good strength, and reasonable oxidation resistance. These materials are of interest for use as sharp leading edges for hypersonic vehicles among other applications. Progress in computational modeling of UHTCs has been limited in part due to the absence of suitable interatomic potentials. We present a Tersoff style parameterization of such potentials for ZrB2 and HfB2 appropriate for atomistic simulations. Parameters are fit to data generated from ab initio calculations. The accuracy of the potentials is assessed against further ab initio data. As a first non ]trivial application, molecular dynamics simulations are performed to evaluate the thermal conductivity of single crystals and the thermal resistance of high symmetry grain boundaries.

  5. Transport of the Hadronic Forward (HF) calorimeter from building 186 (CERN Meyrin site) to the CMS construction hall at point 5, Cessy, France.

    CERN Multimedia

    Florelle Antoine

    2006-01-01

    The two halves of the Forward Hadronic Calorimeter (HF) were transported from the CERN Meyrin site to the surface assembly hall at LHC Point 5 in Cessy, France, during the first part of July. Transporting these 300 tonne objects involved the construction around them of a 65-metre long trailer, simultaneously pushed and pulled by two trucks at either end. The main road between St. Genis and Cessy was closed during these operations and a police escort was provided for the ~5 hour journeys. The two HF halves will be the first major elements to be lowered by the gantry crane into the underground experimental cavern around the end of July or beginning of August.

  6. Transport of the first half of the CMS hadronic forward calorimeter (HF) from building 186 (CERN Meyrin site) to the CMS construction hall at point 5, Cessy, France.

    CERN Multimedia

    Florelle Antoine

    2006-01-01

    The two halves of the Forward Hadronic Calorimeter (HF) were transported from the CERN Meyrin site to the surface assembly hall at LHC Point 5 in Cessy, France, during the first part of July. Transporting these 300 tonne objects involved the construction around them of a 65-metre long trailer, simultaneously pushed and pulled by two trucks at either end. The main road between St. Genis and Cessy was closed during these operations and a police escort was provided for the ~5 hour journeys. The two HF halves will be the first major elements to be lowered by the gantry crane into the underground experimental cavern around the end of July or beginning of August.

  7. Purification and characterization of a soluble calnexin from human placenta.

    Science.gov (United States)

    Olsen, Dorthe T; Peng, Li; Træholt, Sofie D; Duus, Karen; Højrup, Peter; Houen, Gunnar

    2013-11-01

    Calreticulin (Crt) and calnexin (Cnx) are homologous endoplasmic reticulum (ER) chaperones involved in protein folding and quality control. Crt is a soluble ER luminal Mr 46 kDa protein and Cnx is a Mr 67kDa ER membrane protein. During purification of Crt from human placenta a soluble form of Cnx (sCnx) was consistently identified in a separate ion exchange chromatography peak. The sCnx was further purified and characterised. This showed that the protein had been cleaved after residue 472 (between Gln and Met), thus liberating it from the transmembrane and cytoplasmic parts of Cnx. The extraction and initial purification steps were carried out in the presence of protease inhibitors, thus ruling out that the cleavage was an artefact of the isolation procedure. This indicates that sCnx may have a physiological chaperone function similar to that of Crt.

  8. (Phenylen-carbazolylenes) copolymers: new soluble electroactive materials

    Energy Technology Data Exchange (ETDEWEB)

    Faid, K. (Lab. de Recherches sur les Macromolecules, Univ. Paris-Nord, 93 - Villetaneuse (France)); Ades, D. (Lab. de Recherches sur les Macromolecules, Univ. Paris-Nord, 93 - Villetaneuse (France)); Chevrot, C. (Lab. de Recherches sur les Macromolecules, Univ. Paris-Nord, 93 - Villetaneuse (France)); Siove, A. (Lab. de Recherches sur les Macromolecules, Univ. Paris-Nord, 93 - Villetaneuse (France))

    1993-03-22

    (Phenylen-Carbazolylenes) copolymers with tunable compositions and properties have been prepared by electrocatalyzed dehalogenative polycondensation of 4,4' dihalobiphenyl and 3,6-dibromo-N-alkylcarbazole mixtures in the presence of zero valent nickel catalyst. The polymers are partly soluble in polar solvents and this solubility depends on the proportion of carbazolylen units in the materials. For a given composition, it increases with the length of the aliphatic substituent on the nitrogen. The conductivity upon doping varies between those of the homopolymers and is a function of the length of the alkyl substituents. Thin films of these materials can be prepared either by solvent casting or by direct electrodeposition on various supports. The electrochemical behavior is strongly dependent on the copolymer composition and reveals the existence of two distinct electronic states (two quantum-wells). The first one is related to the presence of the carbazolylen units while the second shows the presence of phenylen moieties. (orig.)

  9. Light extinction method for solubility measurement

    Institute of Scientific and Technical Information of China (English)

    Shui Wang; Jingkang Wang; Qiuxiang Yin; Yongli Wang

    2005-01-01

    A novel measurement method for chemical solubility determination is brought forward, in which the advantages of two kinds of traditional methods are united. The results show that the concentration of unsolved particles suspending in the solution can be determined by measuring I/I0 (ratio of the transmission intensity to the incident intensity) of the laser beam permeating through the solution according to Lamben-Beer law. The biggest relative deviation for the solubility data determined is less than 1.5% for the sparingly soluble substances and 0.3% for the opulently soluble substances. By comparison of the experimental solubility data with previous data, the light extinction method is demonstrated to be stable and reliable.

  10. Photocurrent generation in carbon nanotube/cubic-phase HfO2 nanoparticle hybrid nanocomposites

    Directory of Open Access Journals (Sweden)

    Protima Rauwel

    2016-07-01

    Full Text Available A hybrid material consisting of nonfunctionalized multiwall carbon nanotubes (MWCNTs and cubic-phase HfO2 nanoparticles (NPs with an average diameter of 2.6 nm has been synthesized. Free standing HfO2 NPs present unusual optical properties and a strong photoluminescence emission in the visible region, originating from surface defects. Transmission electron microscopy studies show that these NPs decorate the MWCNTs on topological defect sites. The electronic structure of the C K-edge in the nanocomposites was probed by electron energy loss spectroscopy, highlighting the key role of the MWCNT growth defects in anchoring HfO2 NPs. A combined optical emission and absorption spectroscopy approach illustrated that, in contrast to HfO2 NPs, the metallic MWCNTs do not emit light but instead expose their discrete electronic structure in the absorption spectra. The hybrid material manifests characteristic absorption features with a gradual merger of the MWCNT π-plasmon resonance band with the intrinsic defect band and fundamental edge of HfO2. The photoluminescence of the nanocomposites indicates features attributed to combined effects of charge desaturation of HfO2 surface states and charge transfer to the MWCNTs with an overall reduction of radiative recombination. Finally, photocurrent generation under UV–vis illumination suggests that a HfO2 NP/MWCNT hybrid system can be used as a flexible nanodevice for light harvesting applications.

  11. Superelasticity and Shape Memory Behavior of NiTiHf Alloys

    Science.gov (United States)

    Sehitoglu, H.; Wu, Y.; Patriarca, L.; Li, G.; Ojha, A.; Zhang, S.; Chumlyakov, Y.; Nishida, M.

    2017-06-01

    The NiTiHf high-temperature shape memory alloys represent a significant advancement in extending the functionality of binary NiTi to elevated temperatures above 100 °C. Despite this potential, the previous results in the literature point to a disappointingly low shape memory strains with addition of Hf. On the other hand, based on theoretical analysis using the lattice constants, the transformation strains should increase substantially with increase in Hf content. The present paper addresses this discrepancy, and using atomistic simulations, determination of twinning modes in martensite with transmission electron microscopy, digital image measurements of habit plane orientation, and strains in single-crystal specimens show that the experimental transformation strains in NiTiHf indeed increase with increasing Hf to unprecedented strain levels near 20%. The Hf contents considered were in the range 6.25-25 at.%, and NiTi (0% Hf) results are provided as the baseline. The current work represents more than 60 experiments representing an extremely thorough study on single crystals and polycrystals.

  12. Isolation and Characterization of a Virulent Bacteriophage φPA-HF17 of Pseudomonas aeruginosa

    Directory of Open Access Journals (Sweden)

    Fang Han

    2014-09-01

    Full Text Available Pseudomonas aeruginosa, an important causative agent of nosocomial infection, is found throughout the hospital environment in moist reservoirs, and multidrug-resistant strains of P. aeruginosa have been increasingly reported worldwide. Bacteriophages are often considered potential therapeutic candidates in treating infectious diseases. In this study, a novel virulent bacteriophage φPA-HF17, specific infecting clinical isolates of P. aeruginosa, was isolated and characterized from environmental sewage. Transmission electron microscopy showed that phage φPA-HF17 had an icosahedral head with a very short tail, and exhibited characteristics typical of a podovirus. Restriction analysis indicated that phage φPA-HF17 was a double-stranded DNA virus, which might be digested by some restriction endonucleases. Phage φPA-HF17 was highly infectious with a rapid adsorption (>90% adsorbed in 4 min. In a one-step growth experiment, phage φPA-HF17 was shown having a latent period of 10 minute, with corresponding burst sizes of 200 PFU/cell. Furthermore, when φPA-HF17 alone was incubated at different pHs and different temperatures, the phage was stable over a wide pH range (4 to 10 and at extreme temperature (50°C. These results suggest that φPA-HF17 may be candidate therapeutic phage to control P. aeruginosa infection.

  13. In-situ atomic layer deposition growth of Hf-oxide

    Energy Technology Data Exchange (ETDEWEB)

    Karavaev, Konstantin

    2010-06-17

    We have grown HfO{sub 2} on Si(001) by atomic layer deposition (ALD) using HfCl{sub 4}, TEMAHf, TDMAHf and H{sub 2}O as precursors. The early stages of the ALD were investigated with high-resolution photoelectron spectroscopy and X-ray absorption spectroscopy. We observed the changes occurring in the Si 2p, O 1s, Hf 4f, Hf 4d, and Cl 2p (for HfCl{sub 4} experiment) core level lines after each ALD cycle up to the complete formation of two layers of HfO{sub 2}. The investigation was carried out in situ giving the possibility to determine the properties of the grown film after every ALD cycle or even after a half cycle. This work focused on the advantages in-situ approach in comparison with ex-situ experiments. The study provides to follow the evolution of the important properties of HfO{sub 2}: contamination level, density and stoichiometry, and influence of the experimental parameters to the interface layer formation during ALD. Our investigation shows that in-situ XPS approach for ALD gives much more information than ex-situ experiments. (orig.)

  14. Linear Trimeric Hafnium Clusters in Hf0.86(1I3

    Directory of Open Access Journals (Sweden)

    Jan Beekhuizen

    2011-05-01

    Full Text Available The reduction of hafnium tetraiodide, HfI4, with aluminum at 600 °C or 850 °C in the presence of a NaI flux resulted in black single crystals of Hf0.86(1I3. This composition corresponds well to the upper end of the non-stoichiometry range 0.89 ≤ x ≤ 1.00 previously reported for HfxI3. The crystal structure (a = 1250.3(2, c = 1999.6(3 pm, R-3m, Z = 18 is made up of hexagonal closest packed layers of iodide ions. One third of the octahedral holes would be filled as in TiI3 or ZrI3 if it were Hf1.00I3. In Hf0.86(1I3, one out of six octahedral holes along [001] are, however, only occupied by 16%. In contrast to TiI3-I and ZrI3, one striking structural feature is in the formation of linear hafnium trimers with identical Hf―Hf distances of 318.3(2 pm rather than the formation of dimers. These may be associated with Hf―Hf bonding although only 2.64 electrons are available for one Hf5.16I18 column.

  15. The SPARC Data Initiative: comparisons of CFC-11, CFC-12, HF and SF6 climatologies from international satellite limb sounders

    Science.gov (United States)

    Tegtmeier, S.; Hegglin, M. I.; Anderson, J.; Funke, B.; Gille, J.; Jones, A.; Smith, L.; von Clarmann, T.; Walker, K. A.

    2016-02-01

    A quality assessment of the CFC-11 (CCl3F), CFC-12 (CCl2F2), HF, and SF6 products from limb-viewing satellite instruments is provided by means of a detailed intercomparison. The climatologies in the form of monthly zonal mean time series are obtained from HALOE, MIPAS, ACE-FTS, and HIRDLS within the time period 1991-2010. The intercomparisons focus on the mean biases of the monthly and annual zonal mean fields and aim to identify their vertical, latitudinal and temporal structure. The CFC evaluations (based on MIPAS, ACE-FTS and HIRDLS) reveal that the uncertainty in our knowledge of the atmospheric CFC-11 and CFC-12 mean state, as given by satellite data sets, is smallest in the tropics and mid-latitudes at altitudes below 50 and 20 hPa, respectively, with a 1σ multi-instrument spread of up to ±5 %. For HF, the situation is reversed. The two available data sets (HALOE and ACE-FTS) agree well above 100 hPa, with a spread in this region of ±5 to ±10 %, while at altitudes below 100 hPa the HF annual mean state is less well known, with a spread ±30 % and larger. The atmospheric SF6 annual mean states derived from two satellite data sets (MIPAS and ACE-FTS) show only very small differences with a spread of less than ±5 % and often below ±2.5 %. While the overall agreement among the climatological data sets is very good for large parts of the upper troposphere and lower stratosphere (CFCs, SF6) or middle stratosphere (HF), individual discrepancies have been identified. Pronounced deviations between the instrument climatologies exist for particular atmospheric regions which differ from gas to gas. Notable features are differently shaped isopleths in the subtropics, deviations in the vertical gradients in the lower stratosphere and in the meridional gradients in the upper troposphere, and inconsistencies in the seasonal cycle. Additionally, long-term drifts between the instruments have been identified for the CFC-11 and CFC-12 time series. The evaluations as a

  16. Indomethacin solubility estimation in 1,4-dioxane + water mixtures by the extended hildebrand solubility approach

    Directory of Open Access Journals (Sweden)

    Miller A Ruidiaz

    2011-09-01

    Full Text Available Extended Hildebrand Solubility Approach (EHSA was successfully applied to evaluate the solubility of Indomethacin in 1,4-dioxane + water mixtures at 298.15 K. An acceptable correlation-performance of EHSA was found by using a regular polynomial model in order four of the W interaction parameter vs. solubility parameter of the mixtures (overall deviation was 8.9%. Although the mean deviation obtained was similar to that obtained directly by means of an empiric regression of the experimental solubility vs. mixtures solubility parameters, the advantages of EHSA are evident because it requires physicochemical properties easily available for drugs.

  17. Microstructure and Phase Stability of Single Crystal NiAl Alloyed with Hf and Zr

    Science.gov (United States)

    Locci, I. E.; Dickerson, R. M.; Garg, A.; Noebe, R. D.; Whittenberger, J. D.; Nathal, M. V.; Darolia, R.

    1996-01-01

    Six near stoichiometric, NiAl single-crystal alloys, with 0.05-1.5 at.% of Hf and Zr additions plus Si impurities, were microstructurally analyzed in the as-cast, homogenized, and aged conditions. Hafnium-rich interdendritic regions, containing the Heusler phase (Ni2AlHf), were found in all the as-cast alloys containing Hf. Homogenization heat treatments partially reduced these interdendritic segregated regions. Transmission electron microscopy (TEM) observations of the as-cast and homogenized microstructures revealed the presence of a high density of fine Hf (or Zr) and Si-rich precipitates. These were identified as G-phase, Nil6X6Si7, or as an orthorhombic NiXSi phase, where X is Hf or Zr. Under these conditions the expected Heusler phase (beta') was almost completely absent. The Si responsible for the formation of the G and NiHfSi phases is the result of molten metal reacting with the Si-containing crucible used during the casting process. Varying the cooling rates after homogenization resulted in the refinement or complete suppression of the G and NiHfSi phases. In some of the alloys studied, long-term aging heat treatments resulted in the formation of Heusler precipitates, which were more stable at the aging temperature and coarsened at the expense of the G-phase. In other alloys, long-term aging resulted in the formation of the NiXSi phase. The stability of the Heusler or NiXSi phases can be traced to the reactive element (Hf or Zr) to silicon ratio. If the ratio is high, then the Heusler phase appears stable after long time aging. If the ratio is low, then the NiHfSi phase appears to be the stable phase.

  18. Vibrational relaxation of hydrogen fluoride by HF dimers in a laser excited nozzle beam

    Energy Technology Data Exchange (ETDEWEB)

    Knuth, E.L.; Rubahn, H.; Toennies, J.P.; Wanner, J.

    1986-09-01

    An HF nozzle beam and a cw HF laser beam in a coaxial and antiparallel arrangement facilitated exciting HF molecules vibrationally in v-italic = 1,J-italic up to the saturation limit. A beam consisting exclusively of monomeric HF was generated by heating the beam source to 600 K and was confirmed using a mass spectrometer. Energy-flux measurements made using a bolometer indicate that the vibrational energy distribution initiated by the laser is conserved, confirming that V--T energy transfer to monomers is slow. The maximum measured flux of HF(v-italic = 1,J-italic) molecules was 1.5 x 10/sup 17/ molecules s/sup -1/ sr/sup -1/ at 670 mbar stagnation pressure. Beams consisting of a mixture of monomeric and polymeric HF were generated using appropriate combinations of source temperature and pressure. In the presence of dimers, the excited monomers relax rapidly by a fast V--V transfer and subsequent predissociation of the metastable dimers. The loss of beam energy due to energy transport by the departing dimer fragments was detected bolometrically. The laser-induced depletion of dimers was determined over a wide source pressure range at T-italic/sub 0/ = 300 K using a mass spectrometer. From a kinetic model of these dimer-depletion data, the product of cross section and transfer probability for V--V energy transfer from HF (v-italic = 1) monomers to dimers was deduced to be 14 A-circle/sup 2/. The terminal-dimer-concentration equation for HF nozzle beams was refined. An analysis of the energy fluxes measured by the bolometer with no laser excitation of the beam revealed that, for an HF nozzle beam, the flow from the source to the detector is, in general, nonisenthalpic due to the onset of dimerization. Mach-number focusing enriches the dimer mole fractions detected by the bolometer.

  19. Properties of HfAlO film deposited by plasma enhanced atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Duo [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Cheng, Xinhong, E-mail: xh_cheng@mail.sim.ac.cn [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Jia, Tingting; Zheng, Li; Xu, Dawei; Wang, Zhongjian; Xia, Chao; Yu, Yuehui [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China)

    2013-07-15

    Plasma enhanced atomic layer deposition (PEALD) method can reduce film growing temperature, and allow in situ plasma treatment. In this work, HfAlO and HfO{sub 2} films were deposited with PEALD at 160 °C. Microstructure analysis showed that both films were amorphous after rapid thermal annealing (RTA) treatment, and HfAlO sample showed better interfacial structure than HfO{sub 2}. X-ray photoelectron spectroscopy (XPS) spectra indicated that main component of the interfacial layer of HfAlO sample was Hf–Si–O and Al–Si–O bonds, the valence band offset value between the HfAlO film and Si substrate was calculated to be 2.5 eV. The dominant leakage current mechanism of the samples was Schottky emission at a low electric field (<1.4 MV/cm), and Poole–Frenkel emission mechanism at a higher electric field (>1.4 MV/cm). The equivalent oxide thicknesses (EOT) of the HfAlO samples were 1.0 nm and 1.3 nm, respectively. The density of interface states between dielectric and substrate were calculated to be 1.2 × 10{sup 12} eV{sup −1}cm{sup −2} and 1.3 × 10{sup 12} eV{sup −1}cm{sup −2}, respectively. In comparison with HfO{sub 2} film, HfAlO film has good interfacial structure and electrical performance.

  20. Ti insertion in the MTe5 (M = Zr, Hf structure type: Hf0.78Ti0.22Te5

    Directory of Open Access Journals (Sweden)

    Hoseop Yun

    2012-03-01

    Full Text Available The group 5 mixed-metal telluride, Hf0.78Ti0.22Te5 (hafnium titanium pentatelluride, is isostructural with the binary phases HfTe5 and ZrTe5 and forms a layered structure extending parallel to (010. The layers are made up from chains of bicapped metal-centered trigonal prisms and zigzag Te chains. The metal site (site symmetry m2m is occupied by statistically disordered Hf [78.1 (5%] and Ti [21.9 (5%]. In addition to the regular Te—Te pair [2.7448 (13 Å] forming the short base of the equilateral triangle of the trigonal prism, an intermediate Te...Te separation [2.9129 (9 Å] is also found. The classical charge balance of the compound can be described as [M4+][Te2−][Te22−][Te20] (M = Hf, Ti. The individual metal content can vary in different crystals, apparently forming a random substitutional solid solution (Hf1-xTixTe5, with 0.15 ≤ x ≤ 0.22.

  1. First-principles calculated spin-gapless semiconducting behavior in quaternary VCoHfGa and CrFeHfGa Heusler compounds

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Xiude; Wu, Xiaolin [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); Wu, Bo, E-mail: fqwubo@zync.edu.cn [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); School of Marine Science and Technology, Northwestern Polytechnical University, Xian 710072 (China); Feng, Yu [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Li, Ping [Institute for Clean Energy & Advanced Materials (ICAEM), Southwest University, Chongqing 400715 (China); Huang, Haishen [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China)

    2016-07-15

    Highlights: • Structural, electronic and magnetic properties of quaternary Heusler alloy [VCo,CrFe]HfGa were detected theoretically. • The quaternary Heusler alloy [VCo,CrFe]HfGa are (or are nearly) spin gapless semiconductors at the lowest energy state. • The ferromagnetic coupling plays an important role in magnetism. - Abstract: By using generalized gradient approximation (GGA) scheme within the density functional theory (DFT), the structural, electronic and magnetic properties of LiMgPdSn-type quaternary Heusler alloy CrFeHfGa and VCoHfGa were detected compressively. The results reveal that the two alloys are (or are nearly) potential spin gapless semiconductors with a magnetic moment of 3 μ{sub B} per primitive cell and the minority-spin gap of 0.8 eV and 0.6 eV at Fermi level (ε{sub F}) during the rate of lattice change of about −5%, respectively. We deduce that the ferromagnetic coupling among transitional metals plays an important role in magnetism of Heusler alloy [CrFe,VCo]HfGa.

  2. First-principles study of the (001) surface of cubic PbHfO3 and BaHfO3

    Institute of Scientific and Technical Information of China (English)

    Ni Guang-Xin; Wang Yuan-Xu

    2009-01-01

    Using first-principles techniques, we investigate the (001) surfaces of cubic PbHfO3 (PHO) and BaHfO3 (BHO) terminated with both AO (A=Pb and Ba) and HfO2- Surface structure, partial density of states, band structure, and surface energy are obtained. The BaO surface is found to be similar to its counterpart in BHO. For the HfO2-terminated surface of cubic PHO, the largest relaxation appears on the second-layer atoms but not on the first-layer ones. The analysis of the structure relaxation parameters reveals that the rumpling of the (001) surface for PHO is stronger than that for BHO. The surface thermodynamic stability is explored, and it is found that both the PbO- and the BaO-terminated surfaces are more stable than the HfO2-terminated surfaces for PHO and BHO, respectively. The surface energy calculations show that the (001) surface of PHO is more easily constructed than that of BHO.

  3. Recent progress in AMS measurement of 182Hf at the CIAE

    Institute of Scientific and Technical Information of China (English)

    LI Zhen-Yu; LI Heng; WU Shao-Yong; YUAN Jian; JIANG Shan; HE Ming; DONG Ke-Jun; HE Guo-Zhu; LI Chao-Li; HE Xian-Wen; ZHANG Wei; HU Hao; ZHENG Guo-Wen

    2012-01-01

    In order to improve the accuracy of accelerator mass spectrometry (AMS) measurement for 182Hf/180Hf,a series of measurements have been taken in the AMS laboratory at the China Institute of Atomic Energy (CIAE).The major ones include the instantaneous monitoring of 180HfF-5current,testing the stability of transmission,the alternate measurements of an unknown sample and standard,and the origin identification and minimization of background 182W.The experimental details and the improvement in the measurement accuracy,as well as some useful suggestions for better satisfying the requirements of certain practical applications,are presented in this paper.

  4. Crystal structure of Na2HfSi2O7 by Rietveld refinement

    Directory of Open Access Journals (Sweden)

    Nicolas Massoni

    2016-10-01

    Full Text Available The structure of triclinic disodium hafnium disilicate, Na2HfSi2O7, has been determined by laboratory powder X-ray diffraction and refined by the Rietveld refinement. The structure is a framework made of alternate layers of HfO6 octahedra and SiO4 tetrahedra linked by common O atoms. Sodium atoms are located in the voids of the framework, aligned into tunnels along the [010] direction. Na2HfSi2O7 is isostructural with the parakeldyshite Na2ZrSi2O7 phase.

  5. Structural and thermal properties of Cu-Hf-Ti bulk amorphous alloys

    Science.gov (United States)

    Rontó, V.; Nagy, E.; Svéda, M.; Roósz, A.; Tranta, F.

    2009-01-01

    Cu-Hf-Ti amorphous alloys are high strength and wear resistant materials. Master alloys of Cu57.5Hf27.5Ti15 and Cu57.5Hf25Ti17.5 ternary alloys have been prepared by arc melting, and wedge and rod shaped samples have been cast by centrifugal casting. Liquidus and solidus temperatures of the alloys were determined by DTA. The fully amorphous size was determined by X-ray diffraction. Thermodynamic properties of the amorphous alloys were studied by DSC measurements and Kissinger analyses were performed.

  6. Artificial Ionization and UHF Radar Response Associated with HF Frequencies near Electron Gyro-Harmonics (Invited)

    Science.gov (United States)

    Watkins, B. J.; Fallen, C. T.; Secan, J. A.

    2013-12-01

    We present new results from O-mode ionospheric heating experiments at the HAARP facility in Alaska to demonstrate that the magnitude of artificial ionization production is critically dependent on the choice of HF frequency near gyro-harmonics. For O-mode heating in the lower F-region ionosphere, typically about 200 km altitude, artificial ionization enhancements are observed in the lower ionosphere (about 150 - 220 km) and also in the topside ionosphere above about 500 km. Lower ionosphere density enhancements are inferred from HF-enhanced ion and plasma-line signals observed with UHF radar. Upper ionospheric density enhancements have been observed with TEC (total electron content) experiments by monitoring satellite radio beacons where signal paths traverse the HF-modified ionosphere. Both density enhancements and corresponding upward plasma fluxes have also been observed in the upper ionosphere via in-situ satellite observations. The data presented focus mainly on observations near the third and fourth gyro-harmonics. The specific values of the height-dependent gyro-harmonics have been computed from a magnetic model of the field line through the HF heated volume. Experiments with several closely spaced HF frequencies around the gyro-harmonic frequency region show that the magnitude of the lower-ionosphere artificial ionization production maximizes for HF frequencies about 1.0 - 1.5 MHz above the gyro-harmonic frequency. The response is progressively larger as the HF frequency is increased in the frequency region near the gyro-harmonics. For HF frequencies that are initially greater than the gyro-harmonic value the UHF radar scattering cross-section is relatively small, and non-existent or very weak signals are observed; as the signal returns drop in altitude due to density enhancements the HF interaction region passes through lower altitudes where the HF frequency is less than the gyro-harmonic value, for these conditions the radar scattering cross-section is

  7. Graphene contacts to a HfSe2/SnS2 heterostructure

    Science.gov (United States)

    Su, Shanshan; Das, Protik; Ge, Supeng; Lake, Roger K.

    2017-02-01

    Two-dimensional (2D) heterostructures and all-2D contacts are of high interest for electronic device applications, and the SnS2/HfSe2 bilayer heterostructure with graphene contacts has some unique, advantageous properties. The SnS2/HfSe2 heterostructure is interesting because of the strong intermixing of the two conduction bands and the large work function of the SnS2. The band lineup of the well separated materials indicates a type II heterostructure, but the conduction band minimum of the SnS2/HfSe2 bilayer is a coherent superposition of the orbitals from the two layers with a spectral weight of 60% on the SnS2 and 40% on the HfSe2 for AA stacking. These relative weights can be either increased or reversed by an applied vertical field. A 3 ×3 supercell of graphene and a 2 ×2 supercell of SnS2/HfSe2 have a lattice mismatch of 0.1% and both the SnS2/HfSe2 conduction band at M and the graphene Dirac point at K are zone-folded to Γ . Placing graphene on the SnS2/HfSe2 bilayer results in large n-type charge transfer doping of the SnS2/HfSe2 bilayer, on the order of 1013/cm2, and the charge transfer is accompanied by a negative Schottky barrier contact for electron injection from the graphene into the SnS2/HfSe2 bilayer conduction band. Binding energies and the anti-crossing gaps of the graphene and the SnS2/HfSe2 electronic bands both show that the coupling of graphene to the HfSe2 layer is significantly larger than its coupling to the SnS2 layer. A tunneling Hamiltonian estimate of the contact resistance of the graphene to the SnS2/HfSe2 heterostructure predicts an excellent low-resistance contact.

  8. Control of photoassociation reaction F+H→HF with ultrashort laser pulse

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F→HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.

  9. [18F]Fluoride recovery via gaseous [18F]HF

    DEFF Research Database (Denmark)

    Mathiessen, Bente; Jensen, Mikael; Zhuravlev, Fedor

    2011-01-01

    Acidification of target water with H2SO4 in a specially constructed glassy carbon/polyethylene apparatus allowed for recovery of up to 82% of [18F]fluoride as [18F]HF gas. The [18F]HF distillate was found to be acid-free but moist; when passed through a solution of tBuPh2SiOTf, it yielded [18F......]tBuPh2SiF. The multivariate design of experiment showed that the key to high yield of [18F]HF was the efficient degassing of the reaction mixture....

  10. The role of phosphates for the Lu-Hf chronology of meteorites

    Science.gov (United States)

    Debaille, Vinciane; Van Orman, James; Yin, Qing-Zhu; Amelin, Yuri

    2017-09-01

    The 176Lu-176Hf isotopic system is widely used for dating and tracing cosmochemical and geological processes, but still suffers from two uncertainties. First, Lu-Hf isochrons for some early Solar System materials have excess slope of unknown origin that should not be expected for meteorites with ages precisely determined with other isotopic chronometers. This observation translates to an apparent Lu decay constant higher than the one calculated by comparing ages obtained with various dating methods on terrestrial samples. Second, unlike the well constrained Sm/Nd value (to within 2%) for the chondritic uniform reservoir (CHUR), the Lu/Hf ratios in chondrites vary up to 18% when considering all chondrites, adding uncertainty to the Lu/Hf CHUR value. In order to better understand the Lu-Hf systematics of chondrites, we analyzed mineral fractions from the Richardton H5 chondrite to construct an internal Lu-Hf isochron, and set up a numerical model to investigate the effect of preferential diffusion of Lu compared to Hf from phosphate, the phase with the highest Lu-Hf ratio in chondrites, to other minerals. The isochron yields an age of 4647 ± 210 million years (Myr) using the accepted 176Lu decay constant of 1.867 ± 0.008 ×10-11yr-1. Combining this study with the phosphate fractions measured in a previous study yields a slope of 0.08855 ± 0.00072, translating to a 176Lu decay constant of 1.862 ± 0.016 ×10-11yr-1 using the Pb-Pb age previously obtained, in agreement with the accepted value. The large variation of the Lu/Hf phosphates combined with observations in the present study identify phosphates as the key in perturbing Lu-Hf dating and generating the isochron slope discrepancy. This is critical as apatite has substantially higher diffusion rates of rare earth elements than most silicate minerals that comprise stony meteorites. Results of numerical modeling depending of temperature peak, size of the grains and duration of the metamorphic event, show that

  11. Interaction of La2O3 capping layers with HfO2 gate dielectrics

    Science.gov (United States)

    Copel, M.; Guha, S.; Bojarczuk, N.; Cartier, E.; Narayanan, V.; Paruchuri, V.

    2009-11-01

    We report the effect of La2O3 capping layers on HfO2/SiO2/Si dielectrics, proposed for use in threshold voltage tuning of field effect transistors. Depth profiling with medium energy ion scattering shows that an initial surface layer of La2O3 diffuses through the HfO2 at elevated temperatures, ultimately converting some of the thin interfacial SiO2 into a silicate. Core-level photoemission measurements indicate that the additional band-bending induced by the La2O3 only appears after diffusion, and the added charge resides between the HfO2 and the substrate.

  12. CYCLODEXTRIN INCLUSION COMPLEX TO ENHANCE SOLUBILITY OF POORLY WATER SOLUBLE DRUGS: A REVIEW

    Directory of Open Access Journals (Sweden)

    V.B. Chaudhary * 1 and J. K. Patel 2

    2013-01-01

    Full Text Available Low solubility compounds show dissolution rate limited absorption and hence poor absorption, distribution and target organ delivery. Improvement of aqueous solubility in such a case is valuable goal to improve therapeutic efficacy. Complexation with CDs by different methods like physical mixing, melting, kneding, spray drying, freeze drying, co-evaporation has been reported to enhance the solubility, dissolution rate and bioavability of poorly water soluble drugs. The formation of inclusion complex can be confirmed by DSC, FTIR, XRD and SEM study. This review aims to assess the use of cyclodextrines as complexing agents to enhance the solubility of poorly soluble drugs and hence to resolve the many issues associated with developing and commercializing poorly water soluble drugs.

  13. Cultivation Methods for Tomato (Lycopersicon esculentum Mill.) with High Soluble Solids Content Using the Vertically Split Root System

    National Research Council Canada - National Science Library

    HAYASHI, Hiroyuki; TOYOFUKU, Kyoko; TAGUCHI, Takiko; OGAWA, Atsushi

    2014-01-01

    For the cultivation of tomatoes with high soluble solids content, the root system was split vertically and irrigation to the upper part of the root system was stopped to create split vertically (SR treatment...

  14. Insulin-sensitizing and beneficial lipid-metabolic effects of the water-soluble melanin complex extracted from Inonotus obliquus.

    Science.gov (United States)

    Lee, Jung-Han; Hyun, Chang-Kee

    2014-09-01

    Inonotus obliquus has been traditionally used for treatment of metabolic diseases; however, the mechanism remains to be elucidated. In this study, we found that the water-soluble melanin complex extracted from I. obliquus improved insulin sensitivity and reduced adiposity in high fat (HF)-fed obese mice. When the melanin complex was treated to 3T3-L1 adipocytes, insulin-stimulated glucose uptake was increased significantly, and its phosphoinositide 3-kinase-dependent action was proven with wortmannin treatment. Additionally, dose-dependent increases in Akt phosphorylation and glucose transporter 4 translocation into the plasma membrane were observed in melanin complex-treated cells. Adiponectin gene expression in 3T3-L1 cells incubated with melanin complex increased which was corroborated by increased AMP-activated protein kinase phosphorylation in HepG2 and C2C12 cells treated with conditioned media from the 3T3-L1 culture. Melanin complex-treated 3T3-L1 cells showed no significant change in expression of several lipogenic genes, whereas enhanced expressions of fatty acid oxidative genes were observed. Similarly, the epididymal adipose tissue of melanin complex-treated HF-fed mice had higher expression of fatty acid oxidative genes without significant change in lipogenic gene expression. Together, these results suggest that the water-soluble melanin complex of I. obliquus exerts antihyperglycemic and beneficial lipid-metabolic effects, making it a candidate for promising antidiabetic agent.

  15. A first-principles high-pressure study of Hf2PX (X=B, C, N)

    Science.gov (United States)

    Li, Hui; Luo, Zhili; Liu, Zhe; Sun, Guodong; Wang, Zhenjun

    2017-06-01

    New members of MAX family Hf2PX (X=B, C, N) were studied by first-principles calculations under pressure range of 0-100 GPa. Their structural, elastic and electronic properties were reported. The results show that they are energetically stable at zero pressure and mechanically stable under pressure range from 0 to 100 GPa. It reveals that Hf2PB>Hf2PC>Hf2PN for the structural parameters of a and V, and Hf2PBpressure environments.

  16. Fabrication and characteristics of high-K HfO2 gate dielectrics on n-germanium

    Institute of Scientific and Technical Information of China (English)

    Han De-Dong; Kang Jin-Feng; Liu Xiao-Yan; Sun Lei; Luo Hao; Han Ru-Qi

    2007-01-01

    This paper reports that the high-K HfO2 gate dielectrics are fabricated on n-germanium substrates by sputtering Hf on Ge and following by a furnace annealing. The impacts of sputtering ambient, annealing ambient and annealing temperature on the electrical properties of high-K HfO2 gate dielectrics on germanium substrates are investigated.Experimental results indicate that high-K HfO2 gate dielectrics on germanium substrates with good electrical characteristics are obtained, the electrical properties of high-K HfO2 gate dielectrics is strongly correlated with sputtering ambient, annealing ambient and annealing temperature.

  17. Nanohertz Frequency Determination for the Gravity Probe B HF SQUID Signal

    CERN Document Server

    Salomon, M; Kozaczuk, J; Berberian, J E; Santiago, D I; Keiser, G M; Silbergleit, A S; Worden, P

    2011-01-01

    In this paper, we present a method to measure the frequency and the frequency change rate of a digital signal. This method consists of three consecutive algorithms: frequency interpolation, phase differencing, and a third algorithm specifically designed and tested by the authors. The succession of these three algorithms allowed a 5 parts in 10^10 resolution in frequency determination. The algorithm developed by the authors can be applied to a sampled scalar signal such that a model linking the harmonics of its main frequency to the underlying physical phenomenon is available. This method was developed in the framework of the Gravity Probe B (GP-B) mission. It was applied to the High Frequency (HF) component of GP-B's Superconducting QUantum Interference Device (SQUID) signal, whose main frequency fz is close to the spin frequency of the gyroscopes used in the experiment. A 30 nHz resolution in signal frequency and a 0.1 pHz/sec resolution in its decay rate were achieved out of a succession of 1.86 second-long...

  18. Enhanced spin Hall ratios by Al and Hf impurities in Pt thin films

    Science.gov (United States)

    Nguyen, Minh-Hai; Zhao, Mengnan; Ralph, Daniel C.; Buhrman, Robert A.

    The spin Hall effect (SHE) in Pt has been reported to be strong and hence promising for spintronic applications. In the intrinsic SHE mechanism, which has been shown to be dominant in Pt, the spin Hall conductivity σSH is constant, dependent only on the band structure of the spin Hall material. The spin Hall ratio θSH =σSH . ρ , on the other hand, should be proportional to the electrical resistivity ρ of the spin Hall layer. This suggests the possibility of enhancing the spin Hall ratio by introducing additional diffusive scattering to increase the electrical resistivity of the spin Hall layer. Our previous work has shown that this could be done by increasing the surface scattering by growing thinner Pt films in contact with higher resistivity materials such as Ta. In this talk, we discuss another approach: to introduce impurities of metals with negligible spin orbit torque into the Pt film. Our PtAl and PtHf alloy samples exhibit strong enhancement of the spin Hall torque efficiency with impurity concentration due to increased electrical resistivity. Supported in part by Samsung Electronics.

  19. Low modulus Ti-Nb-Hf alloy for biomedical applications.

    Science.gov (United States)

    González, M; Peña, J; Gil, F J; Manero, J M

    2014-09-01

    β-Type titanium alloys with a low elastic modulus are a potential strategy to reduce stress shielding effect and to enhance bone remodeling in implants used to substitute failed hard tissue. For biomaterial application, investigation on the mechanical behavior, the corrosion resistance and the cell response is required. The new Ti25Nb16Hf alloy was studied before and after 95% cold rolling (95% C.R.). The mechanical properties were determined by tensile testing and its corrosion behavior was analyzed by potentiostatic equipment in Hank's solution at 37°C. The cell response was studied by means of cytotoxicity evaluation, cell adhesion and proliferation measurements. The stress-strain curves showed the lowest elastic modulus (42GPa) in the cold worked alloy and high tensile strength, similar to that of Ti6Al4V. The new alloy exhibited better corrosion resistance in terms of open circuit potential (EOCP), but was similar in terms of corrosion current density (iCORR) compared to Ti grade II. Cytotoxicity studies revealed that the chemical composition of the alloy does not induce cytotoxic activity. Cell studies in the new alloy showed a lower adhesion and a higher proliferation compared to Ti grade II presenting, therefore, mechanical features similar to those of human cortical bone and, simultaneously, a good cell response.

  20. Anomalous phenomena on HF radio paths during geomagnetic disturbances

    Science.gov (United States)

    Blagoveshchenskii, D. V.

    2016-07-01

    We analyze ionospheric oblique sounding data on three high-latitude and one high-latitude-midlatitude HF radio paths for February 15 and 16, 2014, when two substorms and one magnetic storm occurred. We investigate cases of anomalous propagation of signals: their reflection from sporadic layer Es, lateral reflections, type "M" or "N" modes, the presence of traveling ionospheric disturbances, and the diffusivity of signals and triplets. The most significant results are the following. In geomagnetically undisturbed times, sporadic Es-layers with reduced maximum observed frequencies (MOF Es) on three high-latitude paths were observed in both days. The values of MOF Es during disturbances are large, which leads to the screening of other oblique sounding signals reflected from the ionosphere. On all four paths, the most frequently traveling ionospheric disturbances due to the terminator were observed in quiet hours from 03:00 to 15:00 UT on the first day and from 06:00 to 13:00 UT on the second day of the experiment. In addition, both the sunset terminator and the magnetic storm on the high-latitude-mid-latitude path were found to generate traveling ionospheric disturbances jointly. No such phenomenon was found on high-latitude paths.

  1. Large ionospheric disturbances produced by the HAARP HF facility

    Science.gov (United States)

    Bernhardt, Paul A.; Siefring, Carl L.; Briczinski, Stanley J.; McCarrick, Mike; Michell, Robert G.

    2016-07-01

    The enormous transmitter power, fully programmable antenna array, and agile frequency generation of the High Frequency Active Auroral Research Program (HAARP) facility in Alaska have allowed the production of unprecedented disturbances in the ionosphere. Using both pencil beams and conical (or twisted) beam transmissions, artificial ionization clouds have been generated near the second, third, fourth, and sixth harmonics of the electron gyrofrequency. The conical beam has been used to sustain these clouds for up to 5 h as opposed to less than 30 min durations produced using pencil beams. The largest density plasma clouds have been produced at the highest harmonic transmissions. Satellite radio transmissions at 253 MHz from the National Research Laboratory TACSat4 communications experiment have been severely disturbed by propagating through artificial plasma regions. The scintillation levels for UHF waves passing through artificial ionization clouds from HAARP are typically 16 dB. This is much larger than previously reported scintillations at other HF facilities which have been limited to 3 dB or less. The goals of future HAARP experiments should be to build on these discoveries to sustain plasma densities larger than that of the background ionosphere for use as ionospheric reflectors of radio signals.

  2. Equatorial ionospheric disturbance observed through a transequatorial HF propagation experiment

    Directory of Open Access Journals (Sweden)

    T. Maruyama

    2006-07-01

    Full Text Available A transequatorial radio-wave propagation experiment at shortwave frequencies (HF-TEP was done between Shepparton, Australia, and Oarai, Japan, using the radio broadcasting signals of Radio Australia. The receiving facility at Oarai was capable of direction finding based on the MUSIC (Multiple Signal Classification algorithm. The results were plotted in azimuth-time diagrams (AT plots. During the daytime, the propagation path was close to the great circle connecting Shepparton and Oarai, thus forming a single line in the AT plots. After sunset, off-great-circle paths, or satellite traces in the AT plot, often appeared abruptly to the west and gradually returned to the great circle direction. However, there were very few signals across the great circle to the east. The off-great-circle propagation was very similar to that previously reported and was attributed to reflection by an ionospheric structure near the equator. From the rate of change in the direction, we estimated the drift velocity of the structure to range mostly from 100 to 300 m/s eastward. Multiple instances of off-great-circle propagation with a quasi-periodicity were often observed and their spatial distance in the east-west direction was within the range of large-scale traveling ionospheric disturbances (LS-TIDs. Off-great-circle propagation events were frequently observed in the equinox seasons. Because there were many morphological similarities, the events were attributed to the onset of equatorial plasma bubbles.

  3. Solubilities of uranium for TILA-99

    Energy Technology Data Exchange (ETDEWEB)

    Ollila, K. [VTT Chemical Technology, Espoo (Finland); Ahonen, L. [Geological Survey of Finland, Espoo (Finland)

    1998-11-01

    This report presents the evaluation of the uranium solubilities in the reference waters of TILA-99. The behaviour of uranium has been discussed separately in the near-field and far-field conditions. The bentonite/groundwater interactions have been considered in the compositions of the fresh and saline near-field reference waters. The far-field groundwaters` compositions include fresh, brackish, saline and very saline, almost brine-type compositions. The pH and redox conditions, as the main parameters affecting the solubilities, are considered. A literature study was made in order to obtain information on the recent dissolution and leaching experiments of UO{sub 2} and spent fuel. The latest literature includes studies on UO{sub 2} solubility under anoxic conditions, in which the methods for simulating the reducing conditions of deep groundwater have been improved. Studies on natural uraninite and its alteration products give a valuable insight into the long-term behaviour of spent fuel. Also the solubility equilibria for some relevant poorly known uranium minerals have been determined. The solubilities of the selected solubility-limiting phases were calculated using the geochemical code, EQ3/6. The NEA database for uranium was the basis for the modelling. The recently extended and updated SR `97 database was used for comparison. The solubility products for uranophane were taken from the latest literature. The recommended values for solubilities were given after a comparison between the calculated solubilities, experimental information and measured concentrations in natural groundwaters. The experiments include several UO{sub 2} dissolution studies in synthetic groundwaters with compositions close to the reference groundwaters. (author) 81 refs.

  4. Combined Sm-Nd and Lu-Hf dating of garnets from the Putomayo foreland basin in south-central Colombia and implications

    Science.gov (United States)

    Bloch, E. M.; Ibanez-mejia, M.; Ganguly, J.

    2013-12-01

    Garnet-whole rock (Grt-WR) ages of metapelites determined by the Lu-Hf decay system are almost always older than those determined by the Sm-Nd system. Unambiguous interpretation of the observed age differences has been hindered by a lack of adequate information about grain size, diffusion data for Hf in garnet, and in many cases about peak metamorphic conditions and cooling rates, all of which affect the closure temperatures of these decay systems. As part of a broader study on basement rocks from the Andean Putomayo foreland basin in south-central Colombia, we have determined the Lu-Hf and Sm-Nd Grt-WR ages of these rocks using painstakingly handpicked garnets of ~50 μm radius, and obtained ages of 1070 × 5.6 and 1007 × 2.9 Ma, respectively. By modeling the retrograde Fe-Mg zoning in garnet adjacent to biotite according to an asymptotic cooling model (1/T = 1/To + ηt) with the diffusion data from [1], an initial cooling rate of ~2-5 °C/Ma is obtained independently of the geochronological data; peak P-T conditions of ~8 kb, 675 °C are imposed by garnet-orthopyroxene thermobarometry. Using the above data in conjunction with the Nd diffusion data from [2] and Hf diffusion data from our recent study, we obtain closure temperatures for the Lu-Hf and Sm-Nd decay systems in garnet of ~545-565 °C and 415-430 °C, respectively. Results from analytical solutions [3, 4] and a more flexible numerical method are found to be in good agreement with one another. The calculated difference of closure temperatures predicts a difference of ~105-40 Ma between the ages determined by the two decay systems, as compared to the observed age difference of 63 × 6 Ma. The predicted peak metamorphic age derived from the measured and calculated resetting ages of the two decay systems is between ~1030 and 1185 Ma, as compared to the Lu-Hf age of 1070 ×1.9 Ma; we are currently working to obtain U-Pb zircon ages to better constrain this peak metamorphic age. In calculating these results

  5. Formation of Al2O3-HfO2 Eutectic EBC Film on Silicon Carbide Substrate

    Directory of Open Access Journals (Sweden)

    Kyosuke Seya

    2015-01-01

    Full Text Available The formation mechanism of Al2O3-HfO2 eutectic structure, the preparation method, and the formation mechanism of the eutectic EBC layer on the silicon carbide substrate are summarized. Al2O3-HfO2 eutectic EBC film is prepared by optical zone melting method on the silicon carbide substrate. At high temperature, a small amount of silicon carbide decomposed into silicon and carbon. The components of Al2O3 and HfO2 in molten phase also react with the free carbon. The Al2O3 phase reacts with free carbon and vapor species of AlO phase is formed. The composition of the molten phase becomes HfO2 rich from the eutectic composition. HfO2 phase also reacts with the free carbon and HfC phase is formed on the silicon carbide substrate; then a high density intermediate layer is formed. The adhesion between the intermediate layer and the substrate is excellent by an anchor effect. When the solidification process finished before all of HfO2 phase is reduced to HfC phase, HfC-HfO2 functionally graded layer is formed on the silicon carbide substrate and the Al2O3-HfO2 eutectic structure grows from the top of the intermediate layer.

  6. Zircon U-Pb age, Hf isotope and geochemistry of Carboniferous intrusions from the Langshan area, Inner Mongolia: Petrogenesis and tectonic implications

    Science.gov (United States)

    Liu, Min; Zhang, Da; Xiong, Guangqiang; Zhao, Hongtao; Di, Yongjun; Wang, Zhong; Zhou, Zhiguang

    2016-04-01

    Late Paleozoic was a critical period for the tectonic evolution of the northern margin of the Alxa-North China craton, but the evolutionary history is not well constrained. The Carboniferous intrusions in the Langshan area in the western part of the northern margin of the Alxa-North China craton are mainly composed of tonalite, quartz diorite, olivine gabbro and pyroxene peridotite. Zircon LA-ICP-MS U-Pb dating indicates that the Langshan Carboniferous intrusions were emplaced at ca. 338-324 Ma. The quartz diorites are characterized by high amounts of compatible trace elements (Cr, Ni and V) and high Mg# values, which may suggest a significant mantle source. The positive Pb and negative Nb-Ta-Ti anomalies, the variable εHf(t) (-6.9 to 2.0) values and the old Hf model ages (1218-1783 Ma) imply some involvement of ancient continental materials in its petrogenesis. The tonalite has relatively high Sr/Y ratios, low Mg#, Yb and Y contents, features of adakite-like rocks, negative εHf(t) values (-9.8 to -0.1) and older Hf model ages (1344-1953 Ma), which suggest significant involvement of ancient crust materials and mantle-derived basaltic component in its petrogenesis. The high Mg# values, high Cr and Ni contents, and low Zr and Hf contents of the mafic-ultramafic rocks show evidence of a mantle source, and the relatively low zircon εHf(t) values (-5.9 to 3.2) might point to an enriched mantle. The trace element characteristics indicate the influence of subducted sediments and slab-derived fluids. In the tectonic discrimination diagrams, all the rocks plot in subduction-related environment, such as volcanic arc and continental arc. Considering the regional geology, we suggest that the Carboniferous intrusions in the Langshan area were likely emplaced during the late stage of the southward subduction of the Paleo-Asian Ocean plate, which formed a continental arc along the northern margin of the Alxa-North China craton.

  7. Molecular Thermodynamic Modeling of Mixed Solvent Solubility

    DEFF Research Database (Denmark)

    Ellegaard, Martin Dela; Abildskov, Jens; O’Connell, John P.

    2010-01-01

    A method based on statistical mechanical fluctuation solution theory for composition derivatives of activity coefficients is employed for estimating dilute solubilities of 11 solid pharmaceutical solutes in nearly 70 mixed aqueous and nonaqueous solvent systems. The solvent mixtures range from...... nearly ideal to strongly nonideal. The database covers a temperature range from 293 to 323 K. Comparisons with available data and other existing solubility methods show that the method successfully describes a variety of observed mixed solvent solubility behaviors using solute−solvent parameters from...

  8. Water Soluble Polymers for Pharmaceutical Applications

    Directory of Open Access Journals (Sweden)

    Veeran Gowda Kadajji

    2011-11-01

    Full Text Available Advances in polymer science have led to the development of novel drug delivery systems. Some polymers are obtained from natural resources and then chemically modified for various applications, while others are chemically synthesized and used. A large number of natural and synthetic polymers are available. In the present paper, only water soluble polymers are described. They have been explained in two categories (1 synthetic and (2 natural. Drug polymer conjugates, block copolymers, hydrogels and other water soluble drug polymer complexes have also been explained. The general properties and applications of different water soluble polymers in the formulation of different dosage forms, novel delivery systems and biomedical applications will be discussed.

  9. Atmospheric deposition of beryllium in Central Europe: comparison of soluble and insoluble fractions in rime and snow across a pollution gradient.

    Science.gov (United States)

    Bohdalkova, Leona; Novak, Martin; Voldrichova, Petra; Prechova, Eva; Veselovsky, Frantisek; Erbanova, Lucie; Krachler, Michael; Komarek, Arnost; Mikova, Jitka

    2012-11-15

    Little is known about atmospheric input of beryllium (Be) into ecosystems, despite its highly toxic behavior. For three consecutive winters (2009-2011), we measured Be concentrations in horizontal deposition (rime) and vertical deposition (snow) at 10 remote mountain-top locations in the Czech Republic, Central Europe. Beryllium was determined both in filtered waters, and in HF digests of insoluble particles. Across the sites, soluble Be concentrations in rime were 7 times higher, compared to snow (6.1 vs. 0.9ng·L(-1)). Rime scavenged the pollution-rich lower segments of clouds. The lowest Be concentrations were detected in the soluble fraction of snow. Across the sites, 34% of total Be deposition occurred in the form of soluble (bioavailable) Be, the rest were insoluble particles. Beryllium fluxes decreased in the order: vertical dry deposition insoluble>vertical dry deposition soluble>horizontal deposition soluble>vertical wet deposition insoluble>vertical wet deposition soluble>horizontal deposition insoluble. The average contributions of these Be forms to total deposition were 56, 21, 8, 7, 5 and 3%, respectively. Sites in the northeast were more Be-polluted than the rest of the country with sources of pollution in industrial Silesia.

  10. Effects of Modified Precursor Solution on Microstructure of (Y,Yb)MnO3/HfO2/Si

    Science.gov (United States)

    Suzuki, Kazuyuki; Kato, Kazumi

    2007-10-01

    Ferroelectric/insulator/silicon structures were prepared using (Y,Yb)MnO3 films as ferroelectrics and HfO2 thin films as insulators through alkoxy-derived precursor solutions. The HfO2 solution was chemically modified in order to decrease the number of heating cycles required. The HfO2 films prepared using a partially hydrolyzed alkoxide solution had a uniform structure. From the results of measurements of the roughness level and refractive index of the HfO2 films, the partial hydrolysis of the HfO2 solution was found to be effective for the formation of a uniform microstructure in a thin insulator film. (Y,Yb)MnO3/HfO2/Si structures were constructed using the resultant HfO2 thin films prepared using the modified solutions.

  11. Effects of C and Hf concentration on phase relations and microstructure of a wrought powder-metallurgy superalloy

    Science.gov (United States)

    Miner, R. V., Jr.

    1977-01-01

    NASA IIB-11, a candidate alloy for advanced temperature turbine engine disks, and four modifications with varying C and Hf concentrations were produced from prealloyed powders. Several notable effects of C and Hf concentration in the alloys were observed. Both the amount of the gamma-prime phase and its solvus temperature increased with decreasing C, but only the gamma-prime solvus was affected by Hf, increasing with increasing Hf. Hf also promoted a cellular gamma-prime precipitation. Hf was, however, about equally distributed between gamma-prime and gamma. Hf and C both affected the carbides formed. Increasing both promoted formation of an MC relative to that of an M6C.

  12. The Modulation of Ionospheric Alfvén Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    Ni Bin-bin; Zhao Zheng-yu; Xie Shu-guo

    2003-01-01

    Abstract: The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature variaof the modulation effect and lucubrate possible reasons for the field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase variation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  13. Determination of water-soluble and insoluble elements in PM2.5 by ICP-MS.

    Science.gov (United States)

    Manousakas, M; Papaefthymiou, H; Eleftheriadis, K; Katsanou, K

    2014-09-15

    The elemental composition of water-soluble and acid-soluble fractions of PM2.5 samples from two different Greek cities (Patras and Megalopolis) was investigated. Patras and Megalopolis represent different environments. Specifically, Patras is an urban environment with proximity to a large port, while Megalopolis is a small city located close to lignite power plants. Both cities can serve as a representative example of European cities with similar characteristics. The concentration of 14 elements (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Fe, Sr, Ti, V and Zn) was determined in each fraction by ICP-MS. Microwave assisted digestion was used to digest the samples using a mixture of HNO3 and HF. For the determination of the water soluble fraction, water was chosen as the simplest and most universal extraction solvent. For the validation of the extraction procedure, the recoveries were tested on two certified reference materials (NIST SRM 1648 Urban Particulate Matter and NIST 1649a Urban Dust). Results showed that Zn has the highest total concentration (273 and 186 ng/m(3)) and Co the lowest (0.48 and 0.23 ng/m(3)) for Patras and Megalopolis samples, respectively. Nickel with 65% for Patras and As with 49% for Megalopolis displayed the highest solubility, whereas Fe (10%) and Ti (2%) the lowest ones, respectively.

  14. Ferroelectric modulation of terahertz waves with graphene/ultrathin-Si:HfO2/Si structures

    Science.gov (United States)

    Jiang, Ran; Han, Zuyin; Sun, Weideng; Du, Xianghao; Wu, Zhengran; Jung, Hyung-Suk

    2015-10-01

    Ferroelectric-field-effect-tunable modulation of terahertz waves in graphene/Si:HfO2/Si stack structure was observed. The modulation shows distinct behaviors when the samples under different gate polarities. At a negative voltage, a transmission modulation depth up to ˜74% was present without depending on the photo illumination power, whereas, at a positive voltage, the modulation of Thz wave shows dependence on the illumination power, which is ascribed to the creation/elimination of an extra barrier in Si layer in response to the polarization in the ferroelectric Si:HfO2 layer. Considering the good compatibility of HfO2 on Si-based semiconductor process, the ferroelectricity layer of Si:HfO2 may open up an avenue for the tunable modulation of Thz wave.

  15. Modulation of auroral electrojet currents using dual HF beams with ELF phase offset

    Science.gov (United States)

    Golkowski, M.; Cohen, M.; Moore, R. C.

    2012-12-01

    The modulation of naturally occuring ionospheric currents with high power radio waves in the high frequency (HF, 3-10 MHz) band is a well known technique for generation of extremely low frequency (ELF, 3-3000 Hz) and very low frequency (VLF, 3-30 kHz) waves. We use the heating facility of the High Frequency Active Auroral Research Program (HAARP) to investigate the effect of using dual HF beams with an ELF/VLF phase offset between the modulation waveforms. Experiments with offset HF beams confirm the model of independent ELF/VLF sources. Experiments with co-located HF beams exhibit interaction between the first and second harmonics of the modulated tones when square and sine wave modulation waveforms are employed. Using ELF/VLF phase offsets for co-loacted beams is also shown to be a potential diagnostic for the D-region ionospheric profile.

  16. Hf diffusion in dilute Fe-free Zr(Nb) alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H.; Hood, G.M.; Roy, J.A.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [Canada Centre for Mineral and Energy Technology, Ottawa, ON (Canada)

    1995-04-01

    Hf diffusion coefficients D have been measured in the {alpha}-phase of the Fe-free binary alloys Zr-1.0 at.% Nb and Zr-2.5 at.% Nb in the temperature range 830-1100 K. The D values for the two alloys are essentially indistinguishable and little different from extant Hf diffusion coefficients measured in Fe-free polycrystalline {alpha}-Zr. The temperature dependence of D in the alloys is characteristic of intrinsic {alpha}-Zr bulk behaviour. The present hf D values are much lower than corresponding values measured in commercial Zr-2.5 Nb. The difference is attributable to the influence of solid-solution Fe. In addition, the absence of a strong enhancement of Hf diffusion in {alpha}-Zr by Nb suggests that intrinsic Nb diffusion in {alpha}-Zr may not be controlled by a normal vacancy mechanism. (author).

  17. HF183/BFDrev and HumM2 qPCR data

    Data.gov (United States)

    U.S. Environmental Protection Agency — Concentration estimates for HF183/BFDrev and HumM2 qPCR genetic markers in raw sewage collected from 54 geographic locations across the United States. This dataset...

  18. Phase Transformation and Thermal Stability of Aged Ti-Ni-Hf High Temperature Shape Memory Alloys

    Institute of Scientific and Technical Information of China (English)

    Xianglong MENG; Wei CAI; K.T.Lau; L.M.Zhou; Liancheng ZHAO

    2006-01-01

    The use of Ni-rich TiNiHf alloys as high temperature shape memory alloys(SMAs)through aging has been presented. For Ni-rich Ti80-xNixHf20 alloys, their phase transformation temperatures are averagely increased more than 100 K by aging at 823 K for 2 h. Especially for the alloys with Ni-content of 50.4 at. pct and 50.6 at. pct, their martensitic transformation start temperatures(Ms)are more than 473 K after aging. TEM observation confirmed that some fine particles precipitate from the matrix during aging. The aged Ni-rich TiNiHf SMAs show the better thermal stability of phase transformation temperatures than the solutiontreated TiNiHf alloys. The fine particles precipitated during aging should be responsible for the increase of phase transformation temperatures and its high stability.

  19. Luminescence and scintillation properties of Rb2HfCl6 crystals

    Science.gov (United States)

    Saeki, Keiichiro; Wakai, Yuki; Fujimoto, Yutaka; Koshimizu, Masanori; Yanagida, Takayuki; Nakauchi, Daisuke; Asai, Keisuke

    2016-11-01

    We developed a scintillator based on a Rb2HfCl6 crystal as a ternary halide crystal with intrinsic luminescence. In the photoluminescence spectra, two emission bands are observed at 383 and 434 nm. The 434 nm emission band for Rb2HfCl6 may be attributed to [HfCl6]2- complex ion or [ZrCl6]2- impurity, since the Rb2HfCl6 contained Zr as impurity at 0.62 mol %. The radioluminescence band is observed at 420 nm and can be attributed to the same origin as the photoluminescence band at 434 nm. The scintillation decay-time constants were 0.84 and 5.4 µs. The light yield was estimated to be 24,100 photons/MeV.

  20. Development of Hf(4+)-immobilized polydopamine-coated magnetic graphene for highly selective enrichment of phosphopeptides.

    Science.gov (United States)

    Lin, Haizhu; Deng, Chunhui

    2016-01-01

    In this work, we first designed and synthesized an IMAC material with Hf(4+) immobilized on polydopamine-coated magnetic graphene and applied it to phosphopeptides enrichment successfully. The newly prepared material gathered the advantages of large specific surface area of graphene, good hydrophilicity and biocompatibility of polydopamine and superparamagnetism of Fe3O4. We investigated the performance of Hf(4+)-immobilized polydopamine-coated magnetic graphene (denoted as magG@PDA-Hf(4+)) in phosphopeptides enrichment and the results showed high selectivity and sensitivity of the new material. Finally, we successfully applied magG@PDA-Hf(4+) to phosphopeptides enrichment from non-fat milk digests and human serum, further demonstrating excellent performance of this new material in phosphopeptides enrichment. Copyright © 2015 Elsevier B.V. All rights reserved.

  1. Solubility prediction of satranidazole in propylene glycol-water mixtures using extended hildebrand solubility approach

    Directory of Open Access Journals (Sweden)

    P B Rathi

    2011-01-01

    Full Text Available Extended Hildebrand solubility approach is used to estimate the solubility of satranidazole in binary solvent systems. The solubility of satranidazole in various propylene glycol-water mixtures was analyzed in terms of solute-solvent interactions using a modified version of Hildebrand-Scatchard treatment for regular solutions. The solubility equation employs term interaction energy (W to replace the geometric mean (δ1δ2 , where δ1 and δ2 are the cohesive energy densities for the solvent and solute, respectively. The new equation provides an accurate prediction of solubility once the interaction energy, W, is obtained. In this case, the energy term is regressed against a polynomial in δ1 of the binary mixture. A quartic expression of W in terms of solvent solubility parameter was found for predicting the solubility of satranidazole in propylene glycol-water mixtures. The expression yields an error in mole fraction solubility of ~3.74%, a value approximating that of the experimentally determined solubility. The method has potential usefulness in preformulation and formulation studies during which solubility prediction is important for drug design.

  2. Effect of Cyclodextrin Types and Co-Solvent on Solubility of a Poorly Water Soluble Drug

    Science.gov (United States)

    Charumanee, Suporn; Okonogi, Siriporn; Sirithunyalug, Jakkapan; Wolschann, Peter; Viernstein, Helmut

    2016-01-01

    The aim of the study was to investigate the solubility of piroxicam (Prx) depending on the inclusion complexation with various cyclodextrins (CDs) and on ethanol as a co-solvent. The phase-solubility method was applied to determine drug solubility in binary and ternary systems. The results showed that in systems consisting of the drug dissolved in ethanol–water mixtures, the drug solubility increased exponentially with a rising concentration of ethanol. The phase solubility measurements of the drug in aqueous solutions of CDs, β-CD and γ-CD exhibited diagrams of AL-type, whereas 2,6-dimethyl-β-CD revealed AP-type. The destabilizing effect of ethanol as a co-solvent was observed for all complexes regardless of the CD type, as a consequence of it the lowering of the complex formation constants. In systems with a higher concentration of ethanol, the drug solubility was increased in opposition to the decreasing complex formation constants. According to this study, the type of CDs played a more important role on the solubility of Prx, and the use of ethanol as a co-solvent exhibited no synergistic effect on the improvement of Prx solubility. The Prx solubility was increased again due to the better solubility in ethanol. PMID:27763573

  3. Solubility prediction of satranidazole in propylene glycol-water mixtures using extended hildebrand solubility approach.

    Science.gov (United States)

    Rathi, P B

    2011-11-01

    Extended Hildebrand solubility approach is used to estimate the solubility of satranidazole in binary solvent systems. The solubility of satranidazole in various propylene glycol-water mixtures was analyzed in terms of solute-solvent interactions using a modified version of Hildebrand-Scatchard treatment for regular solutions. The solubility equation employs term interaction energy (W) to replace the geometric mean (δ(1)δ(2)), where δ(1) and δ(2) are the cohesive energy densities for the solvent and solute, respectively. The new equation provides an accurate prediction of solubility once the interaction energy, W, is obtained. In this case, the energy term is regressed against a polynomial in δ(1) of the binary mixture. A quartic expression of W in terms of solvent solubility parameter was found for predicting the solubility of satranidazole in propylene glycol-water mixtures. The expression yields an error in mole fraction solubility of ~3.74%, a value approximating that of the experimentally determined solubility. The method has potential usefulness in preformulation and formulation studies during which solubility prediction is important for drug design.

  4. Effect of Cyclodextrin Types and Co-Solvent on Solubility of a Poorly Water Soluble Drug

    Directory of Open Access Journals (Sweden)

    Suporn Charumanee

    2016-10-01

    Full Text Available The aim of the study was to investigate the solubility of piroxicam (Prx depending on the inclusion complexation with various cyclodextrins (CDs and on ethanol as a co-solvent. The phase-solubility method was applied to determine drug solubility in binary and ternary systems. The results showed that in systems consisting of the drug dissolved in ethanol–water mixtures, the drug solubility increased exponentially with a rising concentration of ethanol. The phase solubility measurements of the drug in aqueous solutions of CDs, β-CD and γ-CD exhibited diagrams of AL-type, whereas 2,6-dimethyl-β-CD revealed AP-type. The destabilizing effect of ethanol as a co-solvent was observed for all complexes regardless of the CD type, as a consequence of it the lowering of the complex formation constants. In systems with a higher concentration of ethanol, the drug solubility was increased in opposition to the decreasing complex formation constants. According to this study, the type of CDs played a more important role on the solubility of Prx, and the use of ethanol as a co-solvent exhibited no synergistic effect on the improvement of Prx solubility. The Prx solubility was increased again due to the better solubility in ethanol.

  5. Intergrowth Structure in U- and Hf-Bearing Pyrochlore and Zirconolite: TEM Investigation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, H; Wang, Y; Zhao, P; Bourcier, W L; Van Konynenburg, R; Shaw, H F

    2002-12-04

    Transmission electron microscopy results from a sintered ceramics with stoichiometry of Ca(U{sub 0.5}Ce{sub 0.25}Hf{sub 0.25})Ti{sub 2}O{sub 7} show the material contains both pyrochlore and zirconolite phases and structural intergrowth of zirconolite lamellae within pyrochlore. (001) plane of zirconolite is parallel to (111) plane of pyrochlore because of their structural similarities. The pyrochlore is relatively rich in U, Ce, and Ca with respect to the coexisting zirconolite. Average compositions for the coexisting pyrochlore and zirconolite produced by sintering at 1350 C are (Ca{sub 1.01}Ce{sub 0.13}{sup 3+}Ce{sub 0.19}{sup 4+}U{sub 0.52}Hf{sub 0.18})(Ti{sub 1.95}Hf{sub 0.05})O{sub 7} (with U/(U+Hf) (in the AB sites) = 0.74) and (Ca{sub 0.91}Ce{sub 0.09})(Ce{sub 0.08}{sup 3+}U{sub 0.26}Hf{sub 0.66}Ti{sub 0.01})Ti{sub 2.00}O{sub 7} (with U/(U+Hf) = 0.28) respectively. A single pyrochlore ((Ca,U,Hf){sub 2}Ti{sub 2}O{sub 7}) phase may be synthesized at 1350 C if the ratio of U/(U+Hf) is greater than 0.72, and a single zirconolite (Ca(Hf,U)Ti{sub 2}O{sub 7}) phase may be synthesized at 1350 C if the ratio of U/(U+Hf) is less than 0.28. An amorphous leached layer that is rich in Ti and Hf forms on the surface after the ceramics has been leached in pH 4 buffered solution. The thickness of the layer ranges from 5 nm to 15 nm. It is suggested that under these conditions, the leached layer functions as a protective layer, and reduces the leaching rate over time.

  6. Microstructure and Elevated Temperature Properties of a Refractory TaNbHfZrTi Alloy

    Science.gov (United States)

    2012-01-24

    alloy was prepared by vacuum arc melting of the equimolar mixtures of the corresponding elements. Titanium, zirconium, and hafnium were in the form of...AND ELEVATED TEMPERATURE PROPERTIES OF A REFRACTORY TaNbHfZrTi ALLOY (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM...6260-2. 14. ABSTRACT Compression properties of a refractory multicomponent alloy , Ta20Nb20Hf20Zr20Ti20, were determined in the temperature range

  7. The Instagram: A Novel Sounding Technique for Enhanced HF Propagation Advice

    Science.gov (United States)

    2010-05-01

    The Instagram : A Novel Sounding Technique for Enhanced HF Propagation Advice Rod I. Barnes, G. Fred Earl Riverside Research Organization Rosslyn...low transmit powers, is reduced over conventional methods by up to three orders of magnitude leading to the term ‘ Instagram ’. The technique is...TYPE 3. DATES COVERED 00-00-2010 to 00-00-2010 4. TITLE AND SUBTITLE The Instagram : A Novel Sounding Technique for Enhanced HF Propagation Advice

  8. High-reflectivity HfO2/SiO2 ultraviolet mirrors.

    Science.gov (United States)

    Torchio, Philippe; Gatto, Alexandre; Alvisi, Marco; Albrand, Gérard; Kaiser, Norbert; Amra, Claude

    2002-06-01

    High-reflectivity dense multilayer coatings were produced for the ultraviolet spectral region. Thin-film single layers and UV mirrors were deposited by ion plating and plasma ion-assisted deposition high-energetic technologies. Optical characterizations of HfO2 and SiO2 single layers are made. The optical constants obtained for these two materials are presented. HfO2 and SiO2 mirrors with a reflectance of approximately 99% near 250 nm are reported.

  9. Soft Magnetic Thin Films FeCoHfO for High-Frequency Noise Suppression Applications

    Institute of Scientific and Technical Information of China (English)

    LU Guang-Duo; ZHANG Huai-Wu; TANG Xiao-Li

    2010-01-01

    @@ A series of FeCoHfO films were fabricated by dc magnetron reactive sputtering at varying partial pressure of oxygen(Po2)from 0 to 11.7%,and the electrical and magnetic properties of films have been studied.It is shown that optimal Fe43.29 Co19.51 Hf7.49O29.71 films with desired properties can be obtained when the films were prepared under Po2 = 5.1%.

  10. Creation of Artificial Ionospheric Layers Using High-Power HF Waves

    Science.gov (United States)

    2010-01-30

    Program ( HAARP ) transmitter in Gakona, Alaska. The HF- driven ionization process is initiated near the 2nd electron gyroharmonic at 220 km altitude in...the 3.6 MW High-Frequency Active Auroral Program ( HAARP ) transmitter in Gakona, Alaska. The HF-driven ionization process is initiated near the 2nd...Maine. USA. Copyright 2010 by the American Geophysical Union. 0094-8276/I0/2009GLO41895SO5.0O Research Program ( HAARP ) transmitter facility, however

  11. Characterization of Ionosphere Waveguide Propagation by Monitoring HAARP HF Transmissions in Antarctica

    Science.gov (United States)

    2015-04-17

    AFRL-AFOSR-UK-TR-2015-0024 CHARACTERIZATION OF IONOSPHERE WAVEGUIDE PROPAGATION BY MONITORING HAARP HF TRANSMISSIONS IN ANTARCTICA *Yuri M...31 December 2014 4. TITLE AND SUBTITLE CHARACTERIZATION OF IONOSPHERE WAVEGUIDE PROPAGATION BY MONITORING HAARP HF TRANSMISSIONS IN ANTARCTICA 5a...investigating the possibility of exciting the ionospheric interlayer duct channel using powerful radiation from the heaters HAARP (Alaska, USA) and EISCAT

  12. Longitudinal Plasmoid in High-Speed Vortex Gas Flow Created by Capacity HF Discharge

    Science.gov (United States)

    2010-10-28

    instrumentation will be used in this Project to study plasma and gas flow parameters, including new shadow device with excimer KrF laser, MW...vortex decay (attenuation) by HF plasma. The additional experiments with small helium jet injection prove the conclusion about vortex attenuation by a...equilibrium HF plasma. Plasma and airflow parameters are measured by different diagnostic instrumentation including shadow optical device with excimer

  13. Electron scattering cross sections with HF, OH, NH and CH molecules

    Energy Technology Data Exchange (ETDEWEB)

    Joshipura, K.N. [Sardar Patel Univ., Vallabh Vidyanagar (India). Dept. of Physics; Vinodkumar, M. [Sardar Patel Univ., Vallabh Vidyanagar (India). Dept. of Physics

    1997-01-20

    Total cross sections including elastic scattering, electronic excitation-ionisation and the dipole rotational excitation are calculated for electron impact on HF, OH, NH, and CH molecules. The additivity rules as well as single-centre expansion are employed for this purpose. A comparison was possible for the e-HF system only. Our results are expected to be good at intermediate to high energies (>50 eV). (orig.).

  14. Zircon and baddeleyite from the economic ultramafic-mafic Noril'sk-1 intrusion (Russia): Hf-isotope constraints on source composition

    Science.gov (United States)

    Malitch, K. N.; Belousova, E. A.; Badanina, I. Yu.; Griffin, W. L.

    2012-04-01

    of the Noril'sk-1 intrusion, which served as the favorable factor for accumulation of ores of unique scales and concentrations, To test this hypothesis, in situ Hf-isotope data were collected on the dated spots within single zircon grains. The analysis used a New Wave LUV213 laser-ablation microprobe attached to a Nu plasma MC-ICP-MS at GEMOC (Griffin et al. 2002). Hf-isotope results grouped on the basis of lithology show notable differences. Zircons from the unmineralized 'layered rock sequence' (e.g., olivine-free gabbro, olivine-bearing gabbro and olivine gabbro) are characterized by the most 'radiogenic' initial 176Hf/177Hf and some of ɛHf values close to those of the Depleted Mantle. Irrespective of zircon population most radiogenic Hf-isotope compositions are typical for olivine-free gabbro (mean ɛHf 7.3 ± 1.1 for sample N1-4), olivine-bearing gabbro (9.2 ± 3.8, sample N1-5) and olivine gabbro (8.3 ± 2.0, sample N1-6). In contrast, zircons from the leucogabbro that encloses the low-sulphide horizon (N1-3), and plagiowehrlite (N1-7) and taxitic-textured rocks (N1-8 and N1-9) with disseminated sulphide ores have less radiogenic Hf-isotope values (e.g., mean ɛHf6.2 ± 1.4, 5.9 ± 2.3, 6.4 ± 1.2 and 4.9±1.4, respectively). The least radiogenic values (ɛHffrom -2.9 to +2.3, mean ɛHf = 0.1 ± 1.9) are recorded in gabbro-diorite from the upper part of intrusion. The baddeleyite from olivine-free gabbro has the narrowest range of ɛHf values (e.g. 6.8-8.4), with a mean of ɛHfof 7.6 ± 0.8, closely matching that of zircon (mean ɛHf= 7.3 ± 1.1). Zircons from the leucogabbro that hosts the low-sulphide horizon (N1-3), and ultramafic and taxitic-textured lithologies with disseminated sulphide ores (N1-7, N1-8 and N1-9) have less radiogenic ɛHf values than those in barren lithologies. The Hf-isotope data for zircons from ore-bearing rocks thus suggest that the Noril'sk magmas represent mixing between a juvenile source equivalent to the Depleted Mantle and a

  15. Lattice Thermal Conductivity of Ultra High Temperature Ceramics (UHTC) ZrB2 and HfB2 from Atomistic Simulations

    Science.gov (United States)

    Lawson, John W.; Daw, Murray S.; Bauschlicher, Charles W.

    2012-01-01

    Ultra high temperature ceramics (UHTC) including ZrB2 and HfB2 have a number of properties that make them attractive for applications in extreme environments. One such property is their high thermal conductivity. Computational modeling of these materials will facilitate understanding of fundamental mechanisms, elucidate structure-property relationships, and ultimately accelerate the materials design cycle. Progress in computational modeling of UHTCs however has been limited in part due to the absence of suitable interatomic potentials. Recently, we developed Tersoff style parameterizations of such potentials for both ZrB2 and HfB2 appropriate for atomistic simulations. As an application, Green-Kubo molecular dynamics simulations were performed to evaluate the lattice thermal conductivity for single crystals of ZrB2 and HfB2. The atomic mass difference in these binary compounds leads to oscillations in the time correlation function of the heat current, in contrast to the more typical monotonic decay seen in monoatomic materials such as Silicon, for example. Results at room temperature and at elevated temperatures will be reported.

  16. SHRIMP zircon dating and LA-ICPMS Hf analysis of early Precambrian rocks from drill holes into the basement beneath the Central Hebei Basin, North China Craton

    Institute of Scientific and Technical Information of China (English)

    Yusheng Wan; Runlong Fan; Huiyi Sun; Xianzheng Zhao; Zejiu Wang; Dunyi Liu; Alfred Kröner; Chunyan Dong; Hangqian Xie; Yuansheng Geng; Yuhai Zhang

    2014-01-01

    The Central Hebei Basin (CHB) is one of the largest sedimentary basins in the North China Craton, extending in a northeastesouthwest direction with an area of>350 km2. We carried out SHRIMP zircon dating, Hf-in-zircon isotopic analysis and a whole-rock geochemical study on igneous and metasedi-mentary rocks recovered from drill holes that penetrated into the basement of the CHB. Two samples of gneissic granodiorite (XG1-1) and gneissic quartz diorite (J48-1) have magmatic ages of 2500 and 2496 Ma, respectively. Their zircons also record metamorphic ages of 2.41e2.51 and w2.5 Ga, respec-tively. Compared with the gneissic granodiorite, the gneissic quartz diorite has higher SREE contents and lower Eu/Eu* and (La/Yb)n values. Two metasedimentary samples (MG1, H5) mainly contain w2.5 Ga detrital zircons as well as late Paleoproterozoic metamorphic grains. The zircons of different origins haveεHf (2.5 Ga) values and Hf crustal model ages ranging from 0 to 5 and 2.7 to 2.9 Ga, respectively. Therefore, w2.5 Ga magmatic and Paleoproterozoic metasedimentary rocks and late Neoarchean to early Paleoproterozoic and late Paleoproterozoic tectono-thermal events have been identified in the basement beneath the CHB. Based on regional comparisons, we conclude that the early Precambrian basement beneath the CHB is part of the North China Craton.

  17. Hansen Solubility Parameters for Octahedral Oligomeric Silsesquioxanes

    Science.gov (United States)

    2012-08-28

    and thermal and electrical insulation enhancers. The inorganic core is both mechanically robust, resistant to oxidation, and thermally stable, and...Choi, P.; Kavassalis, T. A.; Rudin, A. Estimation of Hansen Solubility Parameters for (Hydroxyethyl)- Cellulose and (Hydroxypropyl) Cellulose through

  18. Changes in protein solubility, fermentative capacity, viscoelasticity ...

    African Journals Online (AJOL)

    SAM

    2014-05-14

    May 14, 2014 ... solubility, fermentative capacity and viscoelasticity of frozen dough. In addition to examining ... A dynamic ... ten protein fractions of higher molecular weight and are .... An SE-HPLC system (Varian ProStar equipment, Model.

  19. Organogel formation rationalized by Hansen solubility parameters.

    Science.gov (United States)

    Raynal, Matthieu; Bouteiller, Laurent

    2011-08-07

    Some organic compounds gelate particular solvents by forming a network of anisotropic fibres. We show that Hansen solubility parameters can be used to predict the range of solvents that are likely to be gelled by any given gelator.

  20. Enhanced dopant solubility in strained silicon

    Energy Technology Data Exchange (ETDEWEB)

    Adey, J [School of Physics, University of Exeter, Exeter EX4 4QL (United Kingdom); Jones, R [School of Physics, University of Exeter, Exeter EX4 4QL (United Kingdom); Briddon, P R [Physics Centre, School of Natural Science, Newcastle upon Tyne NE1 7RU (United Kingdom)

    2004-12-22

    The effect of biaxial strain on the solubility of the common donor arsenic and acceptor boron is calculated using spin-polarized local density functional theory. The change in solubility with strain is considered in terms of contributions from the change in total energy and Fermi energy with strain. The solubility of boron is found to be enhanced by compressive biaxial strain due to a reduction in the total energy of the small substitutional impurity and an increase in the Fermi energy for compressive strain. The solubility of arsenic is shown to be enhanced by tensile strain and this is due entirely to the change in Fermi energy. For boron as well as arsenic the change in Fermi energy with strain is shown to make the dominant contribution.

  1. DEVELOPMENT OF SOLUBILITY PRODUCT VISUALIZATION TOOLS

    Energy Technology Data Exchange (ETDEWEB)

    T.F. Turner; A.T. Pauli; J.F. Schabron

    2004-05-01

    Western Research Institute (WRI) has developed software for the visualization of data acquired from solubility tests. The work was performed in conjunction with AB Nynas Petroleum, Nynashamn, Sweden who participated as the corporate cosponsor for this Jointly Sponsored Research (JSR) task. Efforts in this project were split between software development and solubility test development. The Microsoft Windows-compatible software developed inputs up to three solubility data sets, calculates the parameters for six solid body types to fit the data, and interactively displays the results in three dimensions. Several infrared spectroscopy techniques have been examined for potential use in determining bitumen solubility in various solvents. Reflectance, time-averaged absorbance, and transmittance techniques were applied to bitumen samples in single and binary solvent systems. None of the techniques were found to have wide applicability.

  2. Structure and Metal Loading of a Soluble Periplasm Cuproprotein*

    OpenAIRE

    Waldron, Kevin J.; Firbank, Susan J.; Dainty, Samantha J.; Pérez-Rama, Mónica; Tottey, Steve; Robinson, Nigel J

    2010-01-01

    A copper-trafficking pathway was found to enable Cu2+ occupancy of a soluble periplasm protein, CucA, even when competing Zn2+ is abundant in the periplasm. Here, we solved the structure of CucA (a new cupin) and found that binding of Cu2+, but not Zn2+, quenches the fluorescence of Trp165, which is adjacent to the metal site. Using this fluorescence probe, we established that CucA becomes partly occupied by Zn2+ following exposure to equimolar Zn2+ and Cu2+. Cu2+-CucA is more thermodynamical...

  3. Diagnostic Value of Soluble Suppression of Tumorigenicity-2 for Heart Failure

    Institute of Scientific and Technical Information of China (English)

    Dong-Hui Huang; Hao Sun; Jing-Pu Shi

    2016-01-01

    Background:Many studies have explored the diagnostic performance of soluble suppression of tumorigenicity-2 (sST2) for heart failure (HF),but the results are inconsistent.Here,we performed a meta-analysis to assess the role of sST2 in the diagnosis of HF.Methods:We searched PubMed,Web of Science,Cochrane Library,China National Knowledge Infrastructure,and Wanfang Database from inception to April 2015.Studies that investigated the diagnostic role of sST2 for HF were reviewed.The numbers of true-positive,false-positive,false-negative,and true-negative results were extracted to calculate pooled diagnostic odds ratio (DOR) with 95% confidence interval (CI) and the summary receiver operating characteristic curve and area under the curve (AUC).The Spearman correlation coefficient was used to check the threshold effect.The Cochran Q statistic (P < 0.05) and the inconsistency index (I2 > 50%) were used to assess the nonthreshold effect.Meta-regression was conducted to explore the source of heterogeneity;subgroup analysis showed the results in different subgroups.Finally,the Deeks' test was performed to assess the publication bias.Results:Nine articles including 10 studies were included in the meta-analysis.The pooled sensitivity was 0.84 (95% CI:0.81-0.86),and pooled specificity was 0.74 (95% CI:0.72-0.76).The summary DOR was 8.49 (95% CI:4.54-15.86),and AUC was 0.81 (standard error:0.03).The Spearman correlation coefficient identified the nonsignificant threshold effect (coefficient =0.49,P =0.148),but the nonthreshold effect heterogeneity was significant (Cochran Q =58.52,P < 0.0001;I2 =84.6%).Meta-regression found that characteristics of controls might be the suggestive source ofnonthreshold effect heterogeneity (P =0.095).Subgroup analysis found that DOR was 5.65 and 7.86,respectively for the controls of hospital patients and healthy populations.Deeks' test demonstrated that there was no publication bias (P =0.616).Conclusion:The meta

  4. Binary systems solubilities of inorganic and organic compounds, v.1 pt.2

    CERN Document Server

    Stephen, H

    2013-01-01

    Solubilities of Inorganic and Organic Compounds, Volume 1: Binary Systems, Part 1 is part of an approximately 5,500-page manual containing a selection from the International Chemical Literature on the Solubilities of Elements, Inorganic Compounds, Metallo-organic and Organic Compounds in Binary, Ternary and Multi-component Systems. A careful survey of the literature in all languages by a panel of scientists specially appointed for the task by the U.S.S.R. Academy of Sciences, Moscow, has made the compilation of this work possible. The complete English edition in five separately bound volumes w

  5. Ultrathin Hf0.5Zr0.5O2 Ferroelectric Films on Si.

    Science.gov (United States)

    Chernikova, Anna; Kozodaev, Maksim; Markeev, Andrei; Negrov, Dmitrii; Spiridonov, Maksim; Zarubin, Sergei; Bak, Ohheum; Buragohain, Pratyush; Lu, Haidong; Suvorova, Elena; Gruverman, Alexei; Zenkevich, Andrei

    2016-03-23

    Because of their immense scalability and manufacturability potential, the HfO2-based ferroelectric films attract significant attention as strong candidates for application in ferroelectric memories and related electronic devices. Here, we report the ferroelectric behavior of ultrathin Hf0.5Zr0.5O2 films, with the thickness of just 2.5 nm, which makes them suitable for use in ferroelectric tunnel junctions, thereby further expanding the area of their practical application. Transmission electron microscopy and electron diffraction analysis of the films grown on highly doped Si substrates confirms formation of the fully crystalline non-centrosymmetric orthorhombic phase responsible for ferroelectricity in Hf0.5Zr0.5O2. Piezoresponse force microscopy and pulsed switching testing performed on the deposited top TiN electrodes provide further evidence of the ferroelectric behavior of the Hf0.5Zr0.5O2 films. The electronic band lineup at the top TiN/Hf0.5Zr0.5O2 interface and band bending at the adjacent n(+)-Si bottom layer attributed to the polarization charges in Hf0.5Zr0.5O2 have been determined using in situ X-ray photoelectron spectroscopy analysis. The obtained results represent a significant step toward the experimental implementation of Si-based ferroelectric tunnel junctions.

  6. ELF/VLF wave generation from the beating of two HF ionospheric heating sources

    Science.gov (United States)

    Cohen, M. B.; Moore, R. C.; Golkowski, M.; Lehtinen, N. G.

    2012-12-01

    It is well established that Extremely Low Frequency (ELF, 0.3-3 kHz) and Very Low Frequency (VLF, 3-30 kHz) radio waves can be generated via modulated High Frequency (HF, 3-10 MHz) heating of the lower ionosphere (60-100 km). The ionospheric absorption of HF power modifies the conductivity of the lower ionosphere, which in the presence of natural currents such as the auroral electrojet, creates an `antenna in the sky.' We utilize a theoretical model of the HF to ELF/VLF conversion and the ELF/VLF propagation, and calculate the amplitudes of the generated ELF/VLF waves when two HF heating waves, separated by the ELF/VLF frequency, are transmitted from two adjacent locations. The resulting ELF/VLF radiation pattern exhibits a strong directional dependence (as much as 15 dB) that depends on the physical spacing of the two HF sources. This beat wave source can produce signals 10-20 dB stronger than those generated using amplitude modulation, particularly for frequencies greater than 5-10 kHz. We evaluate recent suggestions that beating two HF waves generates ELF/VLF waves in the F-region (>150 km), and conclude that those experimental results may have misinterpreted, and can be explained strictly by the much more well established D region mechanism.

  7. Superconductivity in HfTe5 across weak to strong topological insulator transition induced via pressures.

    Science.gov (United States)

    Liu, Y; Long, Y J; Zhao, L X; Nie, S M; Zhang, S J; Weng, Y X; Jin, M L; Li, W M; Liu, Q Q; Long, Y W; Yu, R C; Gu, C Z; Sun, F; Yang, W G; Mao, H K; Feng, X L; Li, Q; Zheng, W T; Weng, H M; Dai, X; Fang, Z; Chen, G F; Jin, C Q

    2017-03-16

    Recently, theoretical studies show that layered HfTe5 is at the boundary of weak &strong topological insulator (TI) and might crossover to a Dirac semimetal state by changing lattice parameters. The topological properties of 3D stacked HfTe5 are expected hence to be sensitive to pressures tuning. Here, we report pressure induced phase evolution in both electronic &crystal structures for HfTe5 with a culmination of pressure induced superconductivity. Our experiments indicated that the temperature for anomaly resistance peak (Tp) due to Lifshitz transition decreases first before climbs up to a maximum with pressure while the Tp minimum corresponds to the transition from a weak TI to strong TI. The HfTe5 crystal becomes superconductive above ~5.5 GPa where the Tp reaches maximum. The highest superconducting transition temperature (Tc) around 5 K was achieved at 20 GPa. Crystal structure studies indicate that HfTe5 transforms from a Cmcm phase across a monoclinic C2/m phase then to a P-1 phase with increasing pressure. Based on transport, structure studies a comprehensive phase diagram of HfTe5 is constructed as function of pressure. The work provides valuable experimental insights into the evolution on how to proceed from a weak TI precursor across a strong TI to superconductors.

  8. Resistive switching characteristics of Pt/TaOx/HfNx structure and its performance improvement

    Directory of Open Access Journals (Sweden)

    Qigang Zhou

    2013-03-01

    Full Text Available The refractory transition metal nitride (TMN film Hafnium nitride (HfNx was successfully prepared on silicon-based substrates as bottom electrodes for resistive random access memory (RRAM cells in Pt (top/metal oxide/ HfNx (bottom sandwich structure. The reproducible resistive switching (RS characteristics of the memory cells were studied systematically for RRAM applications. The advantages of adopting HfNx instead of Pt as bottom electrode material were demonstrated, including the improvement of the low resistive state value, the RS endurance and the uniformity of RS parameters. The composition and chemical bonding states of the prepared HfNx was analyzed by X-ray photoelectron spectroscopy (XPS technique. The nitrogen content in the HfNx and the Gibbs free energy of the corresponding metal oxide formation has great influences on the RS properties. The oxygen reservoir ability and diffusion barrier effect of the HfNx play a key role in the RS performance improvement of the RRAM devices.

  9. First-principles calculations of adhesion, bonding and magnetism of the Fe/HfC interface

    Energy Technology Data Exchange (ETDEWEB)

    Si Abdelkader, H., E-mail: hayet.siabdelkader@mail.univ-tlemcen.dz [Laboratoire d' Etude et Prediction des Materiaux, Unite de Recherche Materiaux et Energies Renouvelables. LEPM-URMER. Universite de Tlemcen, Tlemcen 13000 (Algeria); Faraoun, H.I. [Laboratoire d' Etude et Prediction des Materiaux, Unite de Recherche Materiaux et Energies Renouvelables. LEPM-URMER. Universite de Tlemcen, Tlemcen 13000 (Algeria)

    2012-12-15

    First-principles plane-wave pseudopotential calculations of the adhesion, bonding and magnetism of the interface between the ferromagnetic bcc Fe and non-magnetic HfC are performed. The work of adhesion for C- and Hf-site Fe/HfC interfaces is calculated. High adhesion at C-site interface is found and Fe-C polar covalent bonds are formed across the interface. The magnetic moments of Fe atoms at interface are increased in both interfaces. The effect of the magnetism on the electronic structure of Fe/HfC interface is also investigated. It is shown that the change in band of majority-spin leads to enhance the magnetic moment of Fe. - Highlights: Black-Right-Pointing-Pointer Adhesion, electronic and magnetism of Fe(110)/HfC(100) interface are studied. Black-Right-Pointing-Pointer High adhesion at C-site interface is found and Fe-C polar covalent bonds are formed across the interface. Black-Right-Pointing-Pointer The magnetic moments of interfacial Fe atoms are increased in both C-site and Hf-site interfaces.

  10. Hf, Zr, and REE partition coefficients between ilmenite and liquid - Implications for lunar petrogenesis

    Science.gov (United States)

    Nakamura, Y.; Fujimaki, H.; Nakamura, N.; Tatsumoto, M.; Mckay, G. A.

    1986-01-01

    Partition coefficients (D) between ilmenite and coexisting liquid were determined under near-lunar conditions for Hf, Zr, and REE. Through isotope dilution analysis, ilmenite D values of 0.41 and 0.33 were obtained for Hf and Zr respectively, values significantly lower than those of ilmenite from a kimberlite megacryst. Partition coefficients of REE for the synthesized ilmenite are slightly smaller than those of ilmenite from the kimberlite megacryst, and the lunar (Lu) partition coefficient is 0.056. These results suggest that ilmenite was significant in the lunar-Hf evolution of lunar mare basalts. Using lunar and Hf D values for ilmenite, the Lu-Hf evolution of lunar cumulates and the coexisting magma was examined for various crystallization sequences. The Lu-Hf variation trend of most high-Ti mare basalts is explained by a small degree of partial cumulate melting, though a higher degree is required to explain the variation of very low-Ti basalts, green glass, and Apollo 12 low-Ti basalts. Apollo 15 low-Ti basalts may require chromite crystallization as well.

  11. Partition coefficients of Hf, Zr, and REE between phenocrysts and groundmasses

    Science.gov (United States)

    Fujimaki, H.; Tatsumoto, M.; Aoki, K.-I.

    1984-01-01

    Partition coefficients of Hf, Zr, and REE between olivine, orthopyroxene, clinopyroxene, plagioclase, garnet, amphibole, ilmenite, phlogopite, and liquid are presented. Samples consist of megacrysts in kimberlite, phenocrysts in alkaline basalts, tholeiitic basalts and andesitic to dacitic rocks, and synthetic garnet and clinopyroxene in Hawaiian tholeiites. The Hf-Lu and Zr-Lu elemental fractionations are as large as the Lu-Sm or Lu-Nd fractionation. The Hf and Zr partition coefficients between mafic phenocrysts and liquids are smaller than the Lu partition coefficients, but are similar to the Nd or Sm partition coefficients. The Hf and Zr partition coefficients between ilmenite, phlogopite, and liquid are larger than the Lu partition coefficients for these minerals and their corresponding liquids. The Hf-Zr elemental fractionation does not occur except for extreme fractionation involving Zr-minerals and extremely low fO2. These data have an important bearing on chronological and petrogenetic tracer studies involving the Lu-Hf isotopic system.

  12. Power-Stepped HF Cross-Modulation Experiments: Simulations and Experimental Observations

    Science.gov (United States)

    Greene, S.; Moore, R. C.

    2014-12-01

    High frequency (HF) cross modulation experiments are a well established means for probing the HF-modified characteristics of the D-region ionosphere. The interaction between the heating wave and the probing pulse depends on the ambient and modified conditions of the D-region ionosphere. Cross-modulation observations are employed as a measure of the HF-modified refractive index. We employ an optimized version of Fejer's method that we developed during previous experiments. Experiments were performed in March 2013 at the High Frequency Active Auroral Research Program (HAARP) observatory in Gakona, Alaska. During these experiments, the power of the HF heating signal incrementally increased in order to determine the dependence of cross-modulation on HF power. We found that a simple power law relationship does not hold at high power levels, similar to previous ELF/VLF wave generation experiments. In this paper, we critically compare these experimental observations with the predictions of a numerical ionospheric HF heating model and demonstrate close agreement.

  13. Ergonomics action research II: a framework for integrating HF into work system design.

    Science.gov (United States)

    Neumann, W P; Village, J

    2012-01-01

    This paper presents a conceptual framework that can support efforts to integrate human factors (HF) into the work system design process, where improved and cost-effective application of HF is possible. The framework advocates strategies of broad stakeholder participation, linking of performance and health goals, and process focussed change tools that can help practitioners engage in improvements to embed HF into a firm's work system design process. Recommended tools include business process mapping of the design process, implementing design criteria, using cognitive mapping to connect to managers' strategic goals, tactical use of training and adopting virtual HF (VHF) tools to support the integration effort. Consistent with organisational change research, the framework provides guidance but does not suggest a strict set of steps. This allows more adaptability for the practitioner who must navigate within a particular organisational context to secure support for embedding HF into the design process for improved operator wellbeing and system performance. There has been little scientific literature about how a practitioner might integrate HF into a company's work system design process. This paper proposes a framework for this effort by presenting a coherent conceptual framework, process tools, design tools and procedural advice that can be adapted for a target organisation.

  14. Influence of cointercalated HF on the electrochemical behavior of highly fluorinated graphite

    Science.gov (United States)

    Nakajima, Tsuyoshi; Gupta, Vinay; Ohzawa, Yoshimi; Groult, Henri; Mazej, Zoran; Žemva, Boris

    Highly fluorinated graphite was prepared at room temperature using high oxidation state transition metal complex fluoride (K 2PdF 6, K 2MnF 6, K 2NiF 6 or KAgF 4) and elemental fluorine under pressure ((5.9-11.8) ×10 5 Pa) in anhydrous liquid HF (aHF). The composition of the fluorinated graphite samples ranged from C 1.1F to C 1.9F containing small amounts of HF. IR absorption spectra revealed that stage 1 phase of C xF contained several different phases with planar (sp 2) and puckered (sp 3) graphene layers. Electrochemical discharge of the fluorinated graphite showed that profile of discharge potential and discharge capacity varied depending on the amount of cointercalated HF. The C xF samples with less amounts of HF and HF 2δ- had relatively flat discharge potentials and large discharge capacities. The discharge capacity reached 500-600 mAh/g in 1 mol/dm 3 LiClO 4-propylene carbonate solution at 25 °C. Chemical diffusion coefficients of Li + ion in the intermediate discharge products were (4.4-13) ×10 -12 cm 2/s from impedance measurement.

  15. Experimental and numerical investigation of the refinement of Hf by EBM

    Science.gov (United States)

    Donchev, Veliko; Vutova, Katia; Vassileva, Vania

    2014-05-01

    Electron beam melting (EBM) in vacuum is one of the most promising technologies for refining and recycling of metals that react with oxygen when heated. Hf is such a metal. Pure Hf (with a small content of gas and metal impurities) is needed for a variety of applications in the aerospace industry and metallurgy, in the production of components of nuclear reactors, microprocessors, optical components etc. We conducted experiments with the ELIT-60 equipment on Hf ingots at electron beam powers of 12, 15, 17 kW and obtained data about the concentration of impurities by the ICP-MS method. For further understanding and optimizing the Hf refining processes, a non-stationary heat model was applied for numerical simulation of the heat transfer processes. Simulation data about the liquid pool variation during the e-beam treatment was thus obtained. The flatness of the crystallization front shape, which is connected to the structure quality, was investigated by optimization criteria related to the curvature of the liquid/solid boundary curve. We also describe an algorithm for calculation of the criteria. One of the criteria was applied to EBM of Hf for different electron beam powers; the results obtained were confirmed by the experimental data. Combining experimental, theoretical and simulation results, a proper technological regime is proposed for better Hf refining.

  16. A new wideband HF technique for MHz-bandwidth spread-spectrum radio communications

    Science.gov (United States)

    Perry, B. D.

    1983-09-01

    The one-way results are seen as demonstrating that equalized MHz-bandwidth skywave HF channels can be achieved using long-range one-hop F-layer propagation paths. It has thus become possible to use direct-sequence pseudo-noise or coherent fast-frequency-hop signaling at HF with processing gains of several orders of magnitude for teletype data rates. Possibilities are seen for using the spread spectrum in covert and/or jam-resistant communications. What is more, the equalized wideband HF channel is not subject to the fading caused by multiple propagation modes; as a consequence, it is substantially more reliable than the traditional narrow-band HF channel. Conversely, reliability comparable to traditional HF can be attained at greatly reduced signal margins. Since the time stability of the wideband HF channel is of the order of 10 s, very little channel-transmission time is needed for initializing and maintaining the equalizer. It is noted that probe signals similar to the channel-measuring waveform described here or spread-spectrum training sequences at the beginning of each message are adequate. Results from the 1982 two-way experimentation show that N(omega) is not reciprocal between terminals 2000 km apart.

  17. Finland HF and Esrange MST radar observations of polar mesosphere summer echoes

    Directory of Open Access Journals (Sweden)

    T. Ogawa

    Full Text Available Peculiar near range echoes observed in summer with the SuperDARN HF radar in Finland are presented. The echoes were detected at four frequencies of 9, 11, 13 and 15 MHz at slant ranges of 105–250 km for about 100 min. Interferometer measurements indicate that the echoes are returned from 80–100 km altitudes with elevation angles of 20°–60°. Echo power (< 16 dB, Doppler velocity (between –30 and + 30 ms-1 and spectral width (< 60 ms-1 fluctuate with periods of several to 20 min, perhaps due to short–period atmospheric gravity waves. When the HF radar detected the echoes, a vertical incidence MST radar, located at Esrange in Sweden (650 km north of the HF radar site, observed polar mesosphere summer echoes (PMSE at altitudes of 80–90 km. This fact suggests that the near range HF echoes are PMSE at HF band, although both radars did not probe a common volume. With increasing radar frequency, HF echo ranges are closer to the radar site and echo power becomes weaker. Possible mechanisms to explain these features are discussed.

    Key words. Meteorology and atmospheric dynamics (middle atmosphere dynamics; thermospheric dynamics; waves and tides; instruments and techniques

  18. Solubility Products of M(II) - Carbonates

    Energy Technology Data Exchange (ETDEWEB)

    Grauer, Rolf; Berner, Urs [ed.

    1999-01-01

    Many solubility data for M(II) carbonates commonly compiled in tables are contradictory and sometimes obviously wrong. The quality of such data has been evaluated based on the original publications and reliable solubility constants have been selected for the carbonates of Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb with the help of cross-comparisons. (author) translated from a PSI internal report written in German in 1994 (TM-44-94-05). 5 figs., 1 tab., 68 refs.

  19. Correlation of Helium Solubility in Liquid Nitrogen

    Science.gov (United States)

    VanDresar, Neil T.; Zimmerli, Gregory A.

    2012-01-01

    A correlation has been developed for the equilibrium mole fraction of soluble gaseous helium in liquid nitrogen as a function of temperature and pressure. Experimental solubility data was compiled and provided by National Institute of Standards and Technology (NIST). Data from six sources was used to develop a correlation within the range of 0.5 to 9.9 MPa and 72.0 to 119.6 K. The relative standard deviation of the correlation is 6.9 percent.

  20. Low Soluble Syndecan-1 Precedes Preeclampsia.

    Directory of Open Access Journals (Sweden)

    Robin E Gandley

    Full Text Available Syndecan-1 (Sdc1; CD138 is a major transmembrane heparan sulfate proteoglycan expressed on the extracellular, luminal surface of epithelial cells and syncytiotrophoblast, thus comprising a major component of the glycocalyx of these cells. The "soluble" (shed form of Sdc1 has paracrine and autocrine functions and is normally produced in a regulated fashion. We compared plasma soluble Sdc1 concentrations, in relation to placental Sdc1 expression, in uncomplicated (control and preeclamptic pregnancies.We evaluated soluble Sdc1 across uncomplicated pregnancy, and between preeclamptic, gestational hypertensive and control patients at mid-pregnancy (20 weeks and 3rd trimester by ELISA. Placental expression level of Sdc1 was compared between groups in relation to pre-delivery plasma soluble Sdc1. Participants were recruited from Magee-Womens Hospital.In uncomplicated pregnancy, plasma soluble Sdc1 rose significantly in the 1st trimester, and reached an approximate 50-fold increase at term compared to post pregnancy levels. Soluble Sdc1 was lower at mid-pregnancy in women who later developed preeclampsia (P<0.05, but not gestational hypertension, compared to controls, and remained lower at late pregnancy in preeclampsia (P<0.01 compared to controls. Sdc1 was prominently expressed on syncytiotrophoblast of microvilli. Syncytiotrophoblast Sdc1 immunostaining intensities, and mRNA content in villous homogenates, were lower in preeclampsia vs. controls (P<0.05. Soluble Sdc1 and Sdc1 immunostaining scores were inversely associated with systolic blood pressures, and positively correlated with infant birth weight percentile.Soluble Sdc1 is significantly lower before the clinical onset of preeclampsia, with reduced expression of Sdc1 in the delivered placenta, suggesting a role for glycocalyx disturbance in preeclampsia pathophysiology.

  1. Finishing and Commissioning the New Arecibo HF Facility

    Science.gov (United States)

    Sulzer, M. P.; Gonzalez, S. A.

    2011-12-01

    The imminent completion of the major tasks in the construction of the New Arecibo HF facility means that we must verify that the components are working as intended. The antenna system and the transmitters must be separately commissioned before they can be connected together so that we an be sure it will provide 83 dbW at 8.175 MHz, and 80 dbW at 5.1 MHz. The antenna system will be ready for initial testing in September. It Illuminates the 305 meter dish using dipoles near the surface of the dish transmitting upward to a wire mesh sub-reflector. There are three crossed dipoles for each of the two frequencies. The dipoles are supported on towers mounted on concrete pads underneath the dish. Each dipole element is connected to a transmitter through a three inch coax line. The tower foundations are nearly complete, and the towers will be erected in early September, and we expect to have at least one crossed dipole in place for initial testing by the end of September. We will need to make some measurements on the antenna system to ensure that it meets our requirements. One requirement is to match the antenna impedance to the transmission line and the transmitter closely enough to meet the transmitter specifications, the closer, the better. We have additional requirements; for example, it is necessary for efficient use of the facility that the polarization be close to circular. In most experiments, we want O mode excitation. If we were to transmit linear only half the power would reach the reflection height. The symmetry of the system assures that most of the conditions for achieving accurate circular polarization are met, but one condition is not: that exciting the transmitters driving the orthogonal elements at 90 degrees assures 90 degree separation in the corresponding antenna currents. One of the dipoles of each pair points toward the center of the array. If we think of the three crossed dipoles as consisting of a reference and two that are excited relative to it

  2. Low Threshold Voltage and High Mobility N-Channel Metal-Oxide-Semiconductor Field-Effect Transistor Using Hf-Si/HfO2 Gate Stack Fabricated by Gate-Last Process

    Science.gov (United States)

    Ando, Takashi; Hirano, Tomoyuki; Tai, Kaori; Yamaguchi, Shinpei; Yoshida, Shinichi; Iwamoto, Hayato; Kadomura, Shingo; Watanabe, Heiji

    2010-01-01

    Systematic characterization of Hf-Si/HfO2 gate stacks revealed two mobility degradation modes. One is carrier scattering by fixed charges and/or trapped charges induced by the crystallization in the thick HfO2 case (inversion oxide thickness, Tinv> 1.6 nm). The other is the Hf penetration into the interfacial layer with the Si substrate in the thin HfO2 case (Tinv< 1.6 nm) for the Hf-rich electrode. It was demonstrated that careful optimization of the HfO2 thickness and the Hf-Si composition can suppress both modes. As a result, a high electron mobility equivalent to that of n+polycrystalline silicon (poly-Si)/SiO2 (248 cm2 V-1 s-1 at Eeff=1 MV/cm) was obtained at Tinv of 1.47 nm. Moreover, the effective work function of the optimized Hf-Si/HfO2 gate stack is located within 50 mV from the Si band edge (Ec). An extremely high Ion of 1165 µA/µm (at Ioff = 81 nA/µm) at Vdd=1.0 V was demonstrated for a 45 nm gate n-channel metal-oxide-semiconductor field-effect transistor (n-MOSFET) without strain enhanced technology.

  3. Low modulus Ti–Nb–Hf alloy for biomedical applications

    Energy Technology Data Exchange (ETDEWEB)

    González, M., E-mail: Marta.Gonzalez.Colominas@upc.edu [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Materials Science, Elisava Escola Superior de Disseny i Enginyeria de Barcelona, La Rambla 30-32, 08002 Barcelona (Spain); Peña, J. [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Materials Science, Elisava Escola Superior de Disseny i Enginyeria de Barcelona, La Rambla 30-32, 08002 Barcelona (Spain); Gil, F.J.; Manero, J.M. [Department of Materials Science and Metallurgy, Universitat Politècnica de Catalunya (UPC), Avda. Diagonal 647, 08028 Barcelona (Spain); Ciber-BBN (Spain)

    2014-09-01

    β-Type titanium alloys with a low elastic modulus are a potential strategy to reduce stress shielding effect and to enhance bone remodeling in implants used to substitute failed hard tissue. For biomaterial application, investigation on the mechanical behavior, the corrosion resistance and the cell response is required. The new Ti25Nb16Hf alloy was studied before and after 95% cold rolling (95% C.R.). The mechanical properties were determined by tensile testing and its corrosion behavior was analyzed by potentiostatic equipment in Hank's solution at 37 °C. The cell response was studied by means of cytotoxicity evaluation, cell adhesion and proliferation measurements. The stress–strain curves showed the lowest elastic modulus (42 GPa) in the cold worked alloy and high tensile strength, similar to that of Ti6Al4V. The new alloy exhibited better corrosion resistance in terms of open circuit potential (E{sub OCP}), but was similar in terms of corrosion current density (i{sub CORR}) compared to Ti grade II. Cytotoxicity studies revealed that the chemical composition of the alloy does not induce cytotoxic activity. Cell studies in the new alloy showed a lower adhesion and a higher proliferation compared to Ti grade II presenting, therefore, mechanical features similar to those of human cortical bone and, simultaneously, a good cell response. - Highlights: • Presents low elastic modulus and high strength and elastic deformability. • Exhibits good biocompatibility in terms of cytotoxicity and cell response. • Corrosion resistance of this alloy is good, similar to that of Ti grade II. • Potential candidate for implants used to substitute failed hard tissue.

  4. Collapse of the magnetic moment under pressure of AFe{sub 2} (A=Y, Zr, Lu and Hf) in the cubic Laves phase

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Wenxu, E-mail: xwzhang@uestc.edu.cn; Zhang, Wanli

    2016-04-15

    The electronic structures of four Laves phase iron compounds (e.g. YFe{sub 2}, ZrFe{sub 2}, LuFe{sub 2} and HfFe{sub 2}) have been calculated with a state-of-the-art full potential electronic structure code. Our theoretical work predicted that the magnetic moments collapse under hydrostatic pressure. This feature is found to be universal in these materials. Its electronic origin is provided by the sharp peaks in the density of states near the Fermi level. It is shown that a first order quantum phase transition can be expected under pressure in Y(Zr, or Lu)Fe{sub 2}, while a second order one in HfFe{sub 2}. The bonding characteristics are discussed to elucidate the equilibrium lattice constant variation. The large spontaneous volume magnetostriction gives one of the most important characteristics of these compounds. Invar anomalies in these compounds can be partly explained by the current work when the fast continuous magnetic moment decrease with the decrease of the lattice constant was properly considered. This work may be as a first insight into the rich world of quantum phase transition and Invar mechanism in these Laves phase compounds. - Highlights: • Magnetic moment of YFe{sub 2}, ZrFe{sub 2}, LuFe{sub 2} and HfFe{sub 2} collapses under pressure. • The transition in Y(Zr or Lu) Fe{sub 2} under pressure is first order. • The transition in HfFe{sub 2} under pressure is second order. • The Invar effects in the compounds can be put into the magnetostriction model.

  5. Interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1)

    Energy Technology Data Exchange (ETDEWEB)

    Voznyak, I., E-mail: iravoznyak@gmail.com [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine); Tokaychuk, Ya. [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine); Hlukhyy, V.; Faessler, T.F. [Department of Chemistry, Technische Universitaet Muenchen, Lichtenbergstr. 4, 85747 Garching (Germany); Gladyshevskii, R. [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya St. 6, 79005 Lviv (Ukraine)

    2012-01-25

    Highlights: Black-Right-Pointing-Pointer Formation of an interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1) based on the binary compound Hf{sub 5}Sn{sub 3} was established at 600 Degree-Sign C. Black-Right-Pointing-Pointer The Ga atoms occupy [Hf{sub 6}] octahedral interstices (Wyckoff position 2b) up to the composition Hf{sub 5}GaSn{sub 3}, which represents a Hf{sub 5}CuSn{sub 3}-type structure (ordered derivative of Ti{sub 5}Ga{sub 4}). Black-Right-Pointing-Pointer The cell parameters and cell volume increase with increasing gallium content. Black-Right-Pointing-Pointer The coordination number of the hafnium atoms in Wyckoff position 6g is reduced from 15 (Hf1Sn{sub 5}Hf{sub 10} for Hf{sub 5}Sn{sub 3}) to 11 (Hf1Sn{sub 5}Ga{sub 2}Hf{sub 4} for Hf{sub 5}GaSn{sub 3}). - Abstract: Formation of an interstitial solid solution Hf{sub 5}Ga{sub x}Sn{sub 3} (x = 0-1) based on the binary compound Hf{sub 5}Sn{sub 3} (structure type Mn{sub 5}Si{sub 3}, Pearson symbol hP16, space group P6{sub 3}/mcm, a = 8.36562(6), c = 5.70775(4) Angstrom-Sign from X-ray powder diffraction) was established at 600 Degree-Sign C. The crystal structure (structure type Hf{sub 5}CuSn{sub 3}, ordered derivative of Ti{sub 5}Ga{sub 4}, hP18, P6{sub 3}/mcm) was refined on X-ray single-crystal diffraction data for three compositions: Hf{sub 5}Ga{sub 0.16(3)}Sn{sub 3} (a = 8.3288(12), c = 5.6988(11) Angstrom-Sign ), Hf{sub 5}Ga{sub 0.53(2)}Sn{sub 3} (a = 8.4205(12), c = 5.7655(12) Angstrom-Sign ) and Hf{sub 5}GaSn{sub 3} (a = 8.5564(12), c = 5.7859(12) Angstrom-Sign ). The Ga atoms occupy Wyckoff position 2b at the centres of Hf{sub 6} octahedral interstices.

  6. Water solubility of selected C9-C18 alkanes using a slow-stir technique: Comparison to structure - property models.

    Science.gov (United States)

    Letinski, Daniel J; Parkerton, Thomas F; Redman, Aaron D; Connelly, Martin J; Peterson, Brian

    2016-05-01

    Aqueous solubility is a fundamental physical-chemical substance property that strongly influences the distribution, fate and effects of chemicals upon release into the environment. Experimental water solubility was determined for 18 selected C9-C18 normal, branched and cyclic alkanes. A slow-stir technique was applied to obviate emulsion formation, which historically has resulted in significant overestimation of the aqueous solubility of such hydrophobic liquid compounds. Sensitive GC-MS based methods coupled with contemporary sample extraction techniques were employed to enable reproducible analysis of low parts-per billion aqueous concentrations. Water solubility measurements for most of the compounds investigated, are reported for the first time expanding available data for branched and cyclic alkanes. Measured water solubilities spanned four orders of magnitude ranging from 0.3 μg/L to 250 μg/L. Good agreement was observed for selected alkanes tested in this work and reported in earlier literature demonstrating the robustness of the slow-stir water solubility technique. Comparisons of measured alkane water solubilities were also made with those predicted by commonly used quantitative structure-property relationship models (e.g. SPARC, EPIWIN, ACD/Labs). Correlations are also presented between alkane measured water solubilities and molecular size parameters (e.g. molar volume, solvent accessible molar volume) affirming a mechanistic description of empirical aqueous solubility results and prediction previously reported for a more limited set of alkanes.

  7. “ Enhancement of Solubility of poorly water soluble drug by solid dispersion technique”

    Directory of Open Access Journals (Sweden)

    V.R.Tagalpallewar

    2015-02-01

    Full Text Available Atovaquone and Satrinidazole has poor solubility resulting in low oral absorption hence low oral bioavailability. Hence to improve the solubility of poorly Atovaquone and Satrinidazole , hydrophilic polymers were used to enhance the dissolution by solid dispersion technique. Polyehylene Glycol 4000 and PVP k30 used to enhance the dissolution of both the drug by Solubilisation. Many alternative techniques have been used to improve such bioavailability; this study thus employed the simple solid dispersion technique and incorporated excipients which can increase the bioavailability of these drugs directly enhancing the dissolution rate of the drug and indirectly by reducing particle size.The aim of present work is to enhance the dissolution of poorly water soluble drug by using solid dispersion technique. To improve the dissolution rate, by using the various concentration of carrier or matrix with drug and hence ,improve the bioavailability of poorly water soluble drug by formulating solid dispersion.To enhance the solubility of poorly water soluble drug ,by means of solubilising agent. In case of poorly water soluble drug, dissolution may be the rate limiting step in the process of absorption. In such case ,we can improve their solubility and dissolution rate.To study the effect of surfactant on the solid dispersion of poorly water soluble drug.

  8. Synthesis of metallic glasses and metallic glass based composites in the Cu-Mo-Hf system by ion beam mixing

    Institute of Scientific and Technical Information of China (English)

    BAI Xue; WANG TongLe; CUI YuanYuan; DING Ning; LI JiaHao; LIU BaiXin

    2012-01-01

    Single-phase and dual-phase metallic glasses as well as metallic glass based composites were synthesized in the Cu-Mo-Hf ternary metal system by 200 keV xenon ion beam mixing of far-from-equilibrium.It was found that Mo-Hf-based and Cu-Mo-based single-phase metallic glasses could be obtained at compositions around Cu17Mo20Hf63 and Cu34Mo57Hf9,respectively.Interestingly,at the nearly equal-atomic stoichiometry of Cu38Mo31Hf31,a dual-phase Cu-Mo-Hf metallic glass,consisting both of the Mo-Hf-based and Cu-Mo-based phases,was first obtained at relatively low irradiation doses ranging from (1-5)×1015 Xe+/cm2,and a single-phase metallic glass was eventually obtained at a dose of 7×1015 Xe+/cm2.In addition,two glass-based composites were obtained at the compositions of Cu14Mo62Hf24 and Cu77Mo14Hf9,and they consisted of the Mo-Hf based and Cu-Mo based metallic glasses,dissolved with some uniformly distributed BCC Mo-based and FCC Cu-based crystalline solid solutions,respectively.The formation mechanism of the above described non-equilibrium alloy phases was also discussed in terms of the atomic collision theory.

  9. Tracing Proterozoic arc mantle Hf isotope depletion of southern Fennoscandia through coupled zircon U-Pb and Lu-Hf isotopes

    Science.gov (United States)

    Petersson, Andreas; Bjärnborg, Karolina; Scherstén, Anders; Gerdes, Axel; Næraa, Tomas

    2017-07-01

    Constraints on the composition of the depleted mantle Sm-Nd and Lu-Hf crust formation ages have a long history of scientific debate. When calculating mantle extraction ages, and constructing crustal growth models, a linear evolution of incompatible trace elements in a depleted mantle since > 4 Ga is routinely used. Mantle depletion however varies regionally and over time and subduction of sediments and oceanic crust renders a mantle-wedge variously enriched relative to a modelled depleted mantle. Here we show that primitive mantle-derived subduction related gabbroic intrusions from southern Fennoscandia have Hf isotope compositions that are enriched relative to a MORB-like linear depleted mantle evolution curve. Extrapolation of primitive Paleoproterozoic gabbro suites enables the construction of a regional mantle evolution curve, providing improved constraints on model ages, crustal residence times and the fraction of juvenile versus reworked continental crust. Convergent margins are assumed to be one of the main sites of continental crust growth, and using an overly depleted mantle source yield model ages that are too old, and hence cumulative crustal growth models show too much crust generation early in the Earth's history. The approach of using the Hf isotope composition of zircon from primitive subduction related gabbroic intrusions as a proxy for mantle Hf isotope composition, piloted in this study, can be applied to other convergent margins.

  10. HfO{sub 2} dielectric thickness dependence of electrical properties in graphene field effect transistors with double conductance minima

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Cheng; Xie, Dan, E-mail: xiedan@mail.tsinghua.edu.cn; Xu, Jian-Long; Sun, Yi-Lin; Dai, Rui-Xuan; Li, Xian [Institute of Microelectronics, Tsinghua National Laboratory for Information Science and Technology (TNList), Tsinghua University, Beijing 100084 (China); Li, Xin-Ming [National Center for Nanoscience and Technology, Zhongguancun, Beijing 100190 (China); Zhu, Hong-Wei [School of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Key Laboratory of Materials Processing Technology of MOE, Tsinghua University, Beijing 100084 (China); Center for Nano and Micro Mechanics, Tsinghua University, Beijing 100084 (China)

    2015-10-14

    We investigate the electrical properties in back-gated graphene field effect transistors (GFETs) with SiO{sub 2} dielectric and different thickness of high-k HfO{sub 2} dielectric. The results show that transform characteristic (I{sub ds}–V{sub gs}) curves of GFETs are uniquely W-shaped with two charge neutrality point (left and right) in both SiO{sub 2} and HfO{sub 2} dielectric (SiO{sub 2}-GFETs and HfO{sub 2}-GFETs). The gate voltage reduces drastically in HfO{sub 2}-GFETs compared with that in SiO{sub 2}-GFETs, and it becomes much smaller with the decline of HfO{sub 2} thickness. The left charge neutrality point in I{sub d}–V{sub g} curves of all HfO{sub 2}-GFETs is negative, compared to the positive ones in SiO{sub 2}-GFETs, which means that there exists n-doping in graphene with HfO{sub 2} as bottom dielectric. We speculate that this n-doping comes from the HfO{sub 2} layer, which brings fixed charged impurities in close proximity to graphene. The carrier mobility is also researched, demonstrating a decreasing trend of hole mobility in HfO{sub 2}-GFETs contrast to that in SiO{sub 2}-GFETs. In a series of HfO{sub 2}-GFETs with different HfO{sub 2} dielectric thickness, the hole mobility shows a tendency of rise when the thickness decreases to 7 nm. The possible reason might be due to the introduced impurities into HfO{sub 2} film from atomic layer deposition process, the concentration of which varies from the thickness of HfO{sub 2} layer.

  11. Redefining solubility parameters: the partial solvation parameters.

    Science.gov (United States)

    Panayiotou, Costas

    2012-03-21

    The present work reconsiders a classical and universally accepted concept of physical chemistry, the solubility parameter. Based on the insight derived from modern quantum chemical calculations, a new definition of solubility parameter is proposed, which overcomes some of the inherent restrictions of the original definition and expands its range of applications. The original single solubility parameter is replaced by four partial solvation parameters reflecting the dispersion, the polar, the acidic and the basic character of the chemical compounds as expressed either in their pure state or in mixtures. Simple rules are adopted for the definition and calculation of these four parameters and their values are tabulated for a variety of common substances. In contrast, however, to the well known Hansen solubility parameters, their design and evaluation does not rely exclusively on the basic rule of "similarity matching" for solubility but it makes also use of the other basic rule of compatibility, namely, the rule of "complementarity matching". This complementarity matching becomes particularly operational with the sound definition of the acidic and basic components of the solvation parameter based on the third σ-moments of the screening charge distributions of the quantum mechanics-based COSMO-RS theory. The new definitions are made in a simple and straightforward manner, thus, preserving the strength and appeal of solubility parameter stemming from its simplicity. The new predictive method has been applied to a variety of solubility data for systems of pharmaceuticals and polymers. The results from quantum mechanics calculations are critically compared with the results from Abraham's acid/base descriptors.

  12. Early Differentiation of the Crust-Mantle System: a Hf Isotope Perspective

    Science.gov (United States)

    Scherer, E.; Munker, C.; Mezger, K.

    2001-12-01

    The Lu decay constant recently determined by Scherer et al. 2001 (i.e., 1.865 x 10-11 yr-1) agrees with the results of the two latest physical counting experiments (1.86 x 10-11 yr-1; Dalmasso et al 1992, Nir-El and Lavi 1998), but is ca. 4 percent lower than the decay constants that have been used throughout the Hf isotope literature (e.g., 1.94 x 10-11, Tatsumoto et al., 1981; 1.93 x 10-11 Sguigna et al, 1982). In addition to making Lu-Hf ages older by ca. 4 percent, the revised decay constant also shifts the calculated initial epsilon Hf values of early Archean and Hadean rocks and zircons that are used to constrain crust-mantle differentiation in the early Earth. The initial epsilon Hf values for low-Lu/Hf samples such as zircons and evolved felsic rocks shift downward by 2-4 epsilon units, primarily due to the shift in the position of the CHUR evolution curve rather than that of the samples themselves. Mafic rocks, such as komatiites have higher Lu/Hf ratios that are closer to that of CHUR and therefore their initial epsilon Hf values do not shift as much (up to 1.3 epsilon units lower or 0.4 epsilon units higher). Using the old decay constant, some early Archean rocks (e.g., Amitsoq gneisses; Vervoort et al., 1996, Vervoort and Blichert-Toft, 1999) seemed to have very high initial epsilon Hf values (up to +6), implying that the upper mantle was moderately depleted in the early Archean and that a substantial volume of crust was produced in the Hadean. However, when recalculated with the new decay constant, the data suggest that the mantle was only slightly depleted, requiring less early crust extraction, and allowing a later date for the onset of significant crust production. In contrast, the extremely low recalculated epsilon Hf values of Earth's oldest zircons (Amelin et al., 1999, Amelin et al., 2000) indicate that Earth's first crust formed at or before 4.3 Ga, and that this crust remained intact long enough (>200 million years) to evolve to such low

  13. Magnetism of coexisting rhombohedral and orthorhombic Hf{sub 2}Co{sub 11} phases in rapidly quenched Hf{sub 2}Co{sub 11}B

    Energy Technology Data Exchange (ETDEWEB)

    Musiał, A. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland); Nanobiomedical Centre, Adam Mickiewicz University in Poznań, Umultowska 85, Poznań 61-614 (Poland); Śniadecki, Z., E-mail: sniadecki@ifmpan.poznan.pl [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland); Marcin, J.; Kováč, J.; Škorvánek, I. [Institute of Experimental Physics, Slovak Academy of Sciences, Watsonova 47, Košice 040 01 (Slovakia); Idzikowski, B. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Poznań 60-179 (Poland)

    2016-04-25

    Evolution of crystalline structure caused by heat treatment and its influence on magnetic properties of two melt-spun Hf{sub 2}Co{sub 11}B alloys in fully amorphous and partially crystalline states have been investigated. The as-cast ribbons were annealed in order to improve the hard magnetic properties by inducing the formation of nanocrystalline phases with high anisotropy. The X-ray diffraction and magnetic measurements confirmed the coexistence of two Hf{sub 2}Co{sub 11} phases, crystallizing in different structures, with the rhombohedral one showing hard magnetic properties. Annealing of fully amorphous alloy resulted in the lower coercive field in comparison to that of annealed partially crystalline ribbon. From the point of view of exchange coupling between magnetic phases and magnetic hardening, the optimum annealing temperature and time were determined to be 570 °C and 60 min, for partially crystalline sample. Annealing at 650 °C for 1 h leads to excess of the HfCo{sub 3}B{sub 2} phase above the critical value and results in a decrease in the coercive field. Isothermal annealing increases the magnetocrystalline anisotropy constant K{sub 1} from 7.52 for the as-quenched sample to 12.11 Merg/cm{sup 3} for the partially crystalline ribbon. The existence of quenched-in nanocrystals resulted in higher coercive fields, up to 3.23 kOe, after annealing. - Highlights: • Hf{sub 2}Co{sub 11}B rapidly quenched in two states: (i) amorphous, (ii) partially crystalline. • formation of nanocrystalline phases with high magnetic anisotropy. • high magnetocrystalline anisotropy constant K{sub 1} > 10 Merg/cm{sup 3} • coexistence of two Hf{sub 2}Co{sub 11} phases: (i) rhombohedral and (ii) orthorhombic.

  14. Neoproterozoic granitic magmatism along the Ailao Shan-Red River belt: U-Pb zircon geochronology, Lu-Hf isotopes and tectonic implications

    Science.gov (United States)

    Chen, Xiaoyu; Liu, Junlai; Qi, Yinchuan; Fan, Wenkui; Burg, Jean-Pierre

    2017-04-01

    The Neoproterozoic tectonic characteristics of the high grade metamorphic massifs along the Ailao Shan-Red River belt are debated. Controversies are on 1) whether the massifs were parts of the Yangtze block to the northeast or 2) parts of the Indochina block to the southwest and 3) the magmatic rocks represent arc magmatism or rifting linked to break-up of the Rodinia supercontinent. This study presents new and precise LA-ICP-MS U-Pb age dating and geochemical and Hf isotopic analyses of granitic intrusions along the Ailao Shan-Red River belt in an attempt to elucidate the Neoproterozoic magmatic evolution of this belt. In general, zircon U-Pb ages of the studied granitic rocks are between 804 and 724Ma, with a weighted mean of ca. 770 Ma, thus confirming Neoproterozoic magmatism. All samples plot into the peraluminous domain, indicating a major crustal resource. In consistency with these conclusions, most of the Neoproterozoic granitoids show negative ɛHf (t) values near the chondrite line. A few samples possess low positiveɛ Hf (t) values, being signatures of mantle sources. It is therefore concluded that the Neoproterozoic magmatism along the ASRR belt originated from mantle sources with important contributions through anatexis of ancient lower crust. Discrimination diagrams of tectonic settings suggest continental arc magmatism. Neoproterozoic magmatism is widely reported along the margins of the Yangtze block, especially in the northern margin. However, there are fewer reports about Neoproterozoic magmatic activity along the southern and southwestern margins. The geochronology spectrum and geochemisty of the studied Neoproterozoic granitic rocks are similar to those along the western margin of the Yangtze block. The present study, combined with previous results, suggests that oceanic subduction contributed to the generation of the arc magmatisms along the western and southwestern margin of the Yangtze plate and along the ASRR belt (as part of the

  15. Curative effect of HF10 on liver and peritoneal metastasis mediated by host antitumor immunity

    Science.gov (United States)

    Hotta, Yoshihiro; Kasuya, Hideki; Bustos, Itzel; Naoe, Yoshinori; Ichinose, Toru; Tanaka, Maki; Kodera, Yasuhiro

    2017-01-01

    Background HF10 is a highly attenuated type 1 herpes simplex virus (HSV) with proven effective oncolytic effect. Previous investigations have demonstrated that colon cancer mice model treated with HF10 not only had better survival but were also resistant to the reimplantation of the antitumor effect mediated by host antitumor immunity. Importantly, it has also been noted that in mice with antitumors implanted on both sides of the back, an injection of HF10 on only one side strongly restrains not only the injected antitumor but also the non-injected ones. Materials and methods MC26 colon cancer cells were injected subcutaneously into the back, spleen, and intraperitoneal region of metastasis model mice. Antitumor volume and survival rate were monitored. To measure cytotoxic T lymphocytes (CTL) cytotoxicity against MC26, lymphocytes were extracted from the spleens of the peritoneal metastasis model mice as well as from the thymus of the liver metastasis model mice. The expression of interferon gamma was examined by enzyme-linked immunospot assay. Samples from the liver metastasis model mice were subjected to polymerase chain reaction to quantify the level of HSV genomes. Results HF10 was injected only on the back antitumor; however, a antitumor-suppressor effect was observed against liver and peritoneal metastases. When HF10 genome was measured, we observed lower genome on liver metastases compared to back antitumor genome quantity. CTL activity against MC26 was also observed. These results indicate that local administration of HF10 exerts a curative effect on systemic disease, mediated by host antitumor immunity. Conclusion HF10 local administration stimulates antitumor immunity to recognize antitumor-specific antigen, which then improves systemic disease. Metastatic antitumors lysis, on the other hand, appears to be mediated by the host immune system, rather than by virus-mediated direct oncolysis. PMID:28331843

  16. Effects of biased irradiation on charge trapping in HfO2 dielectric thin films

    Science.gov (United States)

    Mu, Yifei; Zhao, Ce Zhou; Lu, Qifeng; Zhao, Chun; Qi, Yanfei; Lam, Sang; Mitrovic, Ivona Z.; Taylor, Stephen; Chalker, Paul R.

    2017-09-01

    This paper reports the low-dose-rate radiation response of Al-HfO2/SiO2-Si MOS devices, in which the gate dielectric was formed by atomic layer deposition (ALD) with 5-nm equivalent oxide thickness. The degradation of the devices was characterized by a pulse capacitance-voltage (CV) and on-site radiation response technique under continuous gamma (γ) ray exposure at a relatively low dose rate of 0.116 rad (HfO2)/s. Compared with conventional CV measurements, the proposed measurements extract significant variations of flat-band voltage shift of the hafnium based MOS devices. The large flat-band voltage shift is mainly attributed to the radiation-induced oxide trapped charges, which are not readily compensated by bias-induced charges produced over the measurement timescales (for timescales less than 5 ms). A negative flat-band voltage shift up to -1.02 V was observed under a positive biased irradiation with the total dose up to 40 krad (HfO2) and with the electric field of 0.5 MV/cm. This is attributed to net positive charge generation in the HfO2 oxide layer. The generated charges are transported towards the HfO2/SiO2 interface, and then form effective trapped holes in the HfO2. Similarly, a positive flat-band voltage shift up to 1.1 V was observed from irradiation under negative bias with an electric field of -0.5 MV/cm. The positive shift is mainly due to the accumulation of trapped electrons. Analyses of the experimental results suggest that both hole and electron trapping can dominate the radiation response performance of the HfO2-based MOS devices depending upon the applied bias. It was also found there was no distinct border traps with irradiation in all cases.

  17. Early Postdischarge STOP-HF-Clinic Reduces 30-day Readmissions in Old and Frail Patients With Heart Failure.

    Science.gov (United States)

    Pacho, Cristina; Domingo, Mar; Núñez, Raquel; Lupón, Josep; Moliner, Pedro; de Antonio, Marta; González, Beatriz; Santesmases, Javier; Vela, Emili; Tor, Jordi; Bayes-Genis, Antoni

    2017-08-01

    Heart failure (HF) is associated with a high rate of readmissions within 30 days postdischarge. Strategies to lower readmission rates generally show modest results. To reduce readmission rates, we developed a STructured multidisciplinary outpatient clinic for Old and frail Postdischarge patients hospitalized for HF (STOP-HF-Clinic). This prospective all-comers study enrolled patients discharged from internal medicine or geriatric wards after HF hospitalization. The intervention involved a face-to-face early visit (within 7 days), HF nurse education, treatment titration, and intravenous medication when needed. Thirty-day readmission risk was calculated using the CORE-HF risk score. We also studied the impact of 30-day readmission burden on regional health care by comparing the readmission rate in the STOP-HF-Clinic Referral Area (∼250000 people) with that of the rest of the Catalan Health Service (CatSalut) (∼7.5 million people) during the pre-STOP-HF-Clinic (2012-2013) and post-STOP-HF-Clinic (2014-2015) time periods. From February 2014 to June 2016, 518 consecutive patients were included (age, 82 years; Barthel score, 70; Charlson index, 5.6, CORE-HF 30-day readmission risk, 26.5%). The observed all-cause 30-day readmission rate was 13.9% (47.5% relative risk reduction) and the observed HF-related 30-day readmission rate was 7.5%. The CatSalut registry included 65131 index HF admissions, with 9267 all-cause and 6686 HF-related 30-day readmissions. The 30-day readmission rate was significantly reduced in the STOP-HF-Clinic Referral Area in 2014-2015 compared with 2012-2013 (P < .001), mainly driven by fewer HF-related readmissions. The STOP-HF-Clinic, an approach that could be promptly implemented elsewhere, is a valuable intervention for reducing the global burden of early readmissions among elder and vulnerable patients with HF. Copyright © 2017 Sociedad Española de Cardiología. Published by Elsevier España, S.L.U. All rights reserved.

  18. Dual HF radar study of the subauroral polarization stream

    Directory of Open Access Journals (Sweden)

    R. A. Makarevich

    2008-01-01

    Full Text Available The dual HF radars comprising the Tasman International Geophysical Environment Radar (TIGER system often observe localized high-velocity F-region plasma flows (≥1500 m/s in the midnight sector (20:00–02:00 MLT at magnetic latitudes as low as Λ=60° S. The flow channels exhibit large variability in the latitudinal extent and electric field strength, and are similar to the subauroral polarization stream or SAPS, a plasma convection feature thought to be related to the polarization electric field due to the charge separation during substorm and storm development. In this study, the 2-D plasma drift velocity within the channel is derived for each of the two TIGER radars from the maximum velocities measured in all 16 radar beams within the latitudinally narrow channel, and the time variation of the subauroral electric field is examined near substorm onset. It is demonstrated that the flow channel often does not have a clear onset, rather it manifests differently in different phases of its evolution and can persist for at least two substorm cycles. During the growth phase the electric fields within the flow channel are difficult to distinguish from those of the background auroral convection but they start to increase near substorm onset and peak during the recovery phase, in contrast to what has been reported previously for auroral convection which peaks just before the substorm onset and falls sharply at the substorm onset. The response times to substorm onset range from −5 to +40 min and show some dependence on the substorm location with longer delays observed for substorms eastward of the radars' viewing area. The propagation velocity of the high-velocity region is also investigated by comparing the observations from the two closely-spaced TIGER radars. The observations are consistent with the notion that the polarization electric field is established with the energetic ions drifting westward and equatorward from the initial substorm

  19. Luminescence and scintillation properties of Tl- and Ce-doped Cs2HfCl6 crystals

    Science.gov (United States)

    Saeki, Keiichiro; Fujimoto, Yutaka; Koshimizu, Masanori; Nakauchi, Daisuke; Tanaka, Hironori; Yanagida, Takayuki; Asai, Keisuke

    2017-02-01

    The luminescence and scintillation properties of Tl- and Ce-doped Cs2HfCl6 crystals were investigated by photoluminescence and radioluminescence spectroscopy. In the photoluminescence spectra, emission bands of the activators were observed at 500 nm for Tl-doped Cs2HfCl6, and at 340 and 380 nm for Ce-doped Cs2HfCl6. The radioluminescence bands were observed at 405 and 430 nm for Tl- and Ce-doped Cs2HfCl6, respectively. Scintillation decay time constants for the Tl- and Ce-doped Cs2HfCl6 were smaller than those for the corresponding undoped crystals. Scintillation light yields for Tl- and Ce-doped Cs2HfCl6 were estimated to be 23,700 and 15,700 photons/MeV, respectively.

  20. The atomic structure and chemical composition of HfOx (x < 2) films prepared by ion-beam sputtering deposition

    Science.gov (United States)

    Aliev, V. S.; Gerasimova, A. K.; Kruchinin, V. N.; Gritsenko, V. A.; Prosvirin, I. P.; Badmaeva, I. A.

    2016-08-01

    Non-stoichiometric HfOx films of different chemical composition (x partial pressure in a chamber. An effect of chemical composition on the atomic structure of the films was studied by reflection high-energy electron diffraction, x-ray photoelectron spectroscopy and field emission scanning electron microscopy methods. The films were found to be amorphous, consisting only of three components: Hf-metal clusters, Hf4O7 suboxide and stoichiometric HfO2. The relative concentration of these components varies with changing x. The surface of the films contains the increased oxygen content compared to the bulk. It was found that the Hf4O7 suboxide concentration is maximal at x = 1.8. The concept of hafnium oxide film growth by the IBSD method is proposed to explain the lack of suboxides variety in the films and the instability of HfO2, when annealed at high temperature.

  1. The study of single station inverting the sea surface current by HF ground wave radar based on adjoint assimilation technology

    Science.gov (United States)

    Han, Shuzong; Yang, Hua; Xue, Wenhu; Wang, Xingchi

    2017-06-01

    This paper introduces the assimilation technology in an ocean dynamics model and discusses the feasibility of inverting the sea surface current in the detection zone by assimilating the sea current radial velocity detected by single station HF ground wave radar in ocean dynamics model. Based on the adjoint assimilation and POM model, the paper successfully inverts the sea surface current through single station HF ground wave radar in the Zhoushan sea area. The single station HF radar inversion results are also compared with the bistatic HF radar composite results and the fixed point measured results by Annderaa current meter. The error analysis shows that acquisition of flow velocity and flow direction data from the single station HF radar based on adjoint assimilation and POM model is viable and the data obtained have a high correlation and consistency with the flow field observed by HF radar.

  2. Microstructure and Corrosion Behavior of Hf-40 Wt Pct Ti Alloy in Nitric Acid Medium for Reprocessing Applications

    Science.gov (United States)

    Jayaraj, J.; Ravi, K. R.; Mallika, C.; Kamachi Mudali, U.

    2016-09-01

    The Hf-40 wt pct Ti (Hf-Ti) alloy was developed for neutron poison application in the spent nuclear fuel reprocessing plant. The furnace-cooled Hf-Ti sample exhibited the microstructure comprising equiaxed-α, lamellar-α, and feathery-α. The water-quenched Hf-Ti sample confirmed the presence of lath and internally twinned martensite. In comparison to the furnace-cooled sample, low corrosion current density and passivation current density values obtained for the water-quenched Hf-Ti in 6 M HNO3 at 298 K (25 °C) indicated better passivation ability. The martensitic structure exhibited high hardness (660 HV) and negligible corrosion rate in 6 M nitric acid at 298 K (25 °C). X-ray photoelectron spectroscopic (XPS) analysis confirmed that passivation behavior of this alloy was due to the protective passive film composed of TiO2 and HfO2.

  3. Ferroelectric-field-effect-enhanced resistance performance of TiN/Si:HfO2/oxygen-deficient HfO2/TiN resistive switching memory cells

    Science.gov (United States)

    Jiang, Ran; Wu, Zhengran; Du, Xianghao; Han, Zuyin; Sun, Weideng

    2015-07-01

    Greatly improved resistance performance, including high resistance ratio between the high resistance state and the low resistance state, long-time retention, and reliable endurance, was observed in TiN/Si:HfO2/oxygen-deficient HfO2/TiN memory cells. The enhanced resistance ratio is ascribed to the creation/elimination of an extra barrier in oxygen-deficient HfO2 layer in response to the polarization reversal in the ferroelectric Si:HfO2 layer. Along with the enhanced resistance ratio, the long retention and good endurance make the proposed device a promising candidate for non-volatile resistive memories.

  4. Soluble ectodomain CD163 and extracellular vesicle-associated CD163 are two differently regulated forms of ‘soluble CD163’ in plasma

    Science.gov (United States)

    Etzerodt, Anders; Berg, Ronan M. G.; Plovsing, Ronni R.; Andersen, Morten N.; Bebien, Magali; Habbeddine, Mohamed; Lawrence, Toby; Møller, Holger J.; Moestrup, Søren K.

    2017-01-01

    CD163 is the macrophage receptor for uptake of hemoglobin-haptoglobin complexes. The human receptor can be shed from the macrophage surface owing to a cleavage site for the inflammation-inducible TACE/ADAM17 enzyme. Accordingly, plasma ‘soluble CD163’ (sCD163) has become a biomarker for macrophage activity and inflammation. The present study disclosed that 10% of sCD163 in healthy persons is actually extracellular vesicle (EV)-associated CD163 not being cleaved and shed. Endotoxin injection of human volunteers caused a selective increase in the ectodomain CD163, while septic patients exhibited high levels of both soluble ectodomain CD163 and extracellular vesicle (EV) CD163, the latter representing up 60% of total plasma CD163. A poor prognosis of septic patients measured as the sequential organ failure assessment (SOFA) score correlated with the increase in membrane-associated CD163. Our results show that soluble ectodomain CD163 and EV CD163 in plasma are part of separate macrophage response in the context of systemic inflammation. While that soluble ectodomain CD163 is released during the acute systemic inflammatory response, this is not the case for EV CD163 that instead may be released during a later phase of the inflammatory response. A separate measurement of the two forms of CD163 constituting ‘soluble CD163’ in plasma may therefore add to the diagnostic and prognostic value. PMID:28084321

  5. Soluble ectodomain CD163 and extracellular vesicle-associated CD163 are two differently regulated forms of 'soluble CD163' in plasma.

    Science.gov (United States)

    Etzerodt, Anders; Berg, Ronan M G; Plovsing, Ronni R; Andersen, Morten N; Bebien, Magali; Habbeddine, Mohamed; Lawrence, Toby; Møller, Holger J; Moestrup, Søren K

    2017-01-13

    CD163 is the macrophage receptor for uptake of hemoglobin-haptoglobin complexes. The human receptor can be shed from the macrophage surface owing to a cleavage site for the inflammation-inducible TACE/ADAM17 enzyme. Accordingly, plasma 'soluble CD163' (sCD163) has become a biomarker for macrophage activity and inflammation. The present study disclosed that 10% of sCD163 in healthy persons is actually extracellular vesicle (EV)-associated CD163 not being cleaved and shed. Endotoxin injection of human volunteers caused a selective increase in the ectodomain CD163, while septic patients exhibited high levels of both soluble ectodomain CD163 and extracellular vesicle (EV) CD163, the latter representing up 60% of total plasma CD163. A poor prognosis of septic patients measured as the sequential organ failure assessment (SOFA) score correlated with the increase in membrane-associated CD163. Our results show that soluble ectodomain CD163 and EV CD163 in plasma are part of separate macrophage response in the context of systemic inflammation. While that soluble ectodomain CD163 is released during the acute systemic inflammatory response, this is not the case for EV CD163 that instead may be released during a later phase of the inflammatory response. A separate measurement of the two forms of CD163 constituting 'soluble CD163' in plasma may therefore add to the diagnostic and prognostic value.

  6. Gas-phase reaction studies of dipositive hafnium and hafnium oxide ions: generation of the peroxide HfO2(2+).

    Science.gov (United States)

    Lourenço, Célia; Michelini, Maria del Carmen; Marçalo, Joaquim; Gibson, John K; Oliveira, Maria Conceição

    2012-12-27

    Fourier transform ion cyclotron resonance mass spectrometry was used to characterize the gas-phase reactivity of Hf dipositive ions, Hf(2+)and HfO(2+), toward several oxidants: thermodynamically facile O-atom donor N(2)O, ineffective donor CO, and intermediate donors O(2), CO(2), NO, and CH(2)O. The Hf(2+) ion exhibited electron transfer with N(2)O, O(2), NO, and CH(2)O, reflecting the high ionization energy of Hf(+). The HfO(2+) ion was produced by O-atom transfer to Hf(2+) from N(2)O, O(2), and CO(2), and the HfO(2)(2+) ion by O-atom transfer to HfO(2+) from N(2)O; these reactions were fairly efficient. Density functional theory revealed the structure of HfO(2)(2+) as a peroxide. The HfO(2)(2+) ion reacted by electron transfer with N(2)O, CO(2), and CO to give HfO(2)(+). Estimates were made for the second ionization energies of Hf (14.5 ± 0.5 eV), HfO (14.3 ± 0.5 eV), and HfO(2) (16.2 ± 0.5 eV), and also for the bond dissociation energies, D[Hf(2+)-O] = 686 ± 69 kJ mol(-1) and D[OHf(2+)-O] = 186 ± 98 kJ mol(-1). The computed bond dissociation energies, 751 and 270 kJ mol(-1), respectively, are within these experimental ranges. Additionally, it was found that HfO(2)(2+) oxidized CO to CO(2) and is thus a catalyst in the oxidation of CO by N(2)O and that Hf(2+) activates methane to produce a carbene, HfCH(2)(2+).

  7. Bonding and Site Preferences in the New Quasi-Binary Zr 2.7Hf 11.3P 9

    Science.gov (United States)

    Kleinke, Holger; Franzen, Hugo F.

    1998-03-01

    The new quasi-binary Zr 2.7Hf 11.3P 9was synthesized by arc-melting of Zr, Hf, Co, and HfP in a ratio corresponding to the initial composition "Zr 2.25Hf 6.75Co 2P 4". Zr 2.7Hf 11.3P 9crystallizes in the Zr 14P 9structure type, which is unknown in the binary Hf/P system. The ideal orthorhombic lattice dimensions (space group Pnnm(No. 58), Z=4) were refined to a=16.640(7) Å, b=27.40(2) Å, c=3.619(1) Å, V=1650(2) Å 3. The structure consists of three-dimensional condensed one-, two-, and three-capped trigonal (Zr, Hf) 6P prisms, occurring with numerous short M- Mbonds ( M=Zr, Hf). Each of the 15 metal sites is statistically occupied by a mixture of Zr and Hf, which varies significantly from site to site. The Hf/Zr ratio in a given site depends on the M- Mand M-P interactions. The systematic increase of this ratio with increasing total bond order, as evaluated via Mulliken overlap populations and Pauling bond orders, can be understood based on the trend that Hf forms stronger M- Mand M-P bonds than Zr. As expected for a metal-rich phosphide, band structure calculations for the hypothetical "Hf 14P 9" carried out with the extended Hückel approximation result in a significant density of states at the Fermi level.

  8. AW-101 entrained solids - Solubility versus temperature

    Energy Technology Data Exchange (ETDEWEB)

    GJ Lumetta; RC Lettau; GF Piepel

    2000-03-31

    This report describes the results of a test conducted by Battelle to assess the solubility of the solids entrained in the diluted AW-101 low-activity waste (LAW) sample. BNFL requested Battelle to dilute the AW-1-1 sample using de-ionized water to mimic expected plant operating conditions. BNFL further requested Battelle to assess the solubility of the solids present in the diluted AW-101 sample versus temperature conditions of 30, 40, and 50 C. BNFL requested these tests to assess the composition of the LAW supernatant and solids versus expected plant-operating conditions. The work was conducted according to test plan BNFL-TP-29953-7, Rev. 0, Determination of the Solubility of LAW Entrained Solids. The test went according to plan, with no deviations from the test plan.

  9. Equilibrium Solubility of CO2 in Alkanolamines

    DEFF Research Database (Denmark)

    Waseem Arshad, Muhammad; Fosbøl, Philip Loldrup; von Solms, Nicolas

    2014-01-01

    Equilibrium solubility of CO2 were measured in aqueous solutions of Monoethanolamine (MEA) and N,N-diethylethanolamine(DEEA). Equilibrium cells are generally used for these measurements. In this study, the equilibrium data were measured from the calorimetry. For this purpose a reaction calorimeter...... (model CPA 122 from ChemiSens AB, Sweden) was used. The advantage of this method is being the measurement of both heats of absorption and equilibrium solubility data of CO2 at the same time. The measurements were performed for 30 mass % MEA and 5M DEEA solutions as a function of CO2 loading at three...... different temperatures 40, 80 and 120 ºC. The measured 30 mass % MEA and 5M DEEA data were compared with the literature data obtained from different equilibrium cells which validated the use of calorimeters for equilibrium solubility measurements....

  10. Characteristics of high-quality HfSiON gate dielectric prepared by physical vapour deposition

    Institute of Scientific and Technical Information of China (English)

    Xu Gao-Bo; Xu Qiu-Xia

    2009-01-01

    This paper presents a method using simple physical vapour deposition to form high-quality hafnium silicon oxyni-tride (HfSiON) on ultrathin SiO2 buffer layer. The gate dielectric with 10A (1/A = 0.1 nm) equivalent oxide thickness is obtained. The experimental results indicate that the prepared HfSiON gate dielectric exhibits good physical and electrical characteristics, including very good thermal stability up to 1000℃, excellent interface properties, high dielec-tric constant (k = 14) and low gate-leakage current (Ig= 1.9×10-3 A/cm2@Vg = Vfb-1V for EOT of 10A). TaN metal gate electrode is integrated with the HfSiON gate dielectric.The effective work function of TaN on HfSiON is 4.3eV, meeting the requirements of NMOS for the metal gate. And, the impacts of sputtering ambient and annealing temperature on the electrical properties of HfSiON gate dielectric are investigated.

  11. Mixed Al and Si doping in ferroelectric HfO2 thin films

    Science.gov (United States)

    Lomenzo, Patrick D.; Takmeel, Qanit; Zhou, Chuanzhen; Chung, Ching-Chang; Moghaddam, Saeed; Jones, Jacob L.; Nishida, Toshikazu

    2015-12-01

    Ferroelectric HfO2 thin films 10 nm thick are simultaneously doped with Al and Si. The arrangement of the Al and Si dopant layers within the HfO2 greatly influences the resulting ferroelectric properties of the polycrystalline thin films. Optimizing the order of the Si and Al dopant layers led to a remanent polarization of ˜20 μC/cm2 and a coercive field strength of ˜1.2 MV/cm. Post-metallization anneal temperatures from 700 °C to 900 °C were used to crystallize the Al and Si doped HfO2 thin films. Grazing incidence x-ray diffraction detected differences in peak broadening between the mixed Al and Si doped HfO2 thin films, indicating that strain may influence the formation of the ferroelectric phase with variations in the dopant layering. Endurance characteristics show that the mixed Al and Si doped HfO2 thin films exhibit a remanent polarization greater than 15 μC/cm2 up to 108 cycles.

  12. Spectroscopic analysis of Al and N diffusion in HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Lysaght, P. S.; Price, J.; Kirsch, P. D. [SEMATECH, 257 Fuller Rd, Albany, New York 12203 (United States); Woicik, J. C.; Weiland, C. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Sahiner, M. A. [Seton Hall University, 400 South Orange Ave, South Orange, New Jersey 07079 (United States)

    2012-09-15

    X-ray photoelectron core level spectroscopy, secondary ion mass spectroscopy, spectroscopic ellipsometry, and extended x-ray absorption fine structure measurements have been employed to distinguish the effects of Al and N diffusion on the local bonding and microstructure of HfO{sub 2} and its interface with the Si substrate in (001)Si/SiO{sub x}/2 nm HfO{sub 2}/1 nm AlO{sub x} film structures. The diffusion of Al from the thin AlO{sub x} cap layer deposited on both annealed and unannealed HfO{sub 2} has been observed following anneal in N{sub 2} and NH{sub 3} ambient. Both N{sub 2} and NH{sub 3} subsequent anneals were performed to decouple incorporated nitrogen from thermal reactions alone. Causal variations in the HfO{sub 2} microstructure combined with the dependence of Al and N diffusion on initial HfO{sub 2} conditions are presented with respect to anneal temperature and ambient.

  13. Height dependence of the observed spectrum of radar backscatter from HF-induced ionospheric Langmuir turbulence

    Science.gov (United States)

    Fejer, J. A.; Sulzer, M. P.; Djuth, F. T.

    1991-09-01

    Results are presented of observations of the spectrum of the 430-MHz radar backscatter from HF-induced Langmuir turbulence with height discrimination. During very stable ionospheric conditions under which the height of the below-threshold backscatter spectrum changed by less than 300 m during a 7-min period, a 20-s-long temporary increase in the HF power from 3 MW ERP to 38-MW-equivalent-radiated HF power is found to result in subsequent strong above-threshold spectra extending to heights up to 1200 m greater than the height of the below-threshold spectrum for more than a minute. The generation of irregularities in the plasma density during the 20 s of enhanced HF power is suggested as a possible cause of this persistence of strong above-threshold spectra at greater heights. The initial temporal evolution of the backscatter spectrum from Langmuir turbulence after the start of HF transmissions is observed for different heights. The observational results are compared with the predictions of existing theories of Langmuir turbulence.

  14. Current Progress of Hf (Zr)-Based High-k Gate Dielectric Thin Films

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    With the continued downscaling of complementary metal-oxide-semiconductor field effect transistor dimensions, high-dielectric constant (high-k) gate materials, as alternatives to SiO2, have been extensively investigated. Hf (Zr)-based high-k gate dielectric thin films have been regarded as the most promising candidates for high-k gate dielectric according to the International Technology Roadmap for Semiconductor due to their excellent physical properties and performance. This paper reviews the recent progress on Hf (Zr)-based high-k gate dielectrics based on PVD (physical vapor deposition) process. This article begins with a survey of various methods developed for generating Hf (Zr)-based high-k gate dielectrics, and then mainly focuses on microstructure, synthesis, characterization, formation mechanisms of interfacial layer, and optical properties of Hf (Zr)-based high-k gate dielectrics. Finally, this review concludes with personal perspectives towards future research on Hf (Zr)-based high-k gate dielectrics.

  15. Efficacy of Experimental Hydrofluoric Acid (HF on Bond Strength and Microleakage of Composite-Porcelain Interface

    Directory of Open Access Journals (Sweden)

    Samaneh Mahvidyzadeh

    2012-09-01

    Full Text Available Background and Aims: The aim of this study was to evaluate the quality of an experimental hydrofluoric acid (HF for preparation of porcelain and to compare it with two commercial hydrofluoric acids in Iranian trademark. Materials and Methods: A- Evaluation of etch pattern of experimental HF using scanning electron microscope (SEM: 6 feldespathic discs were divided into 3 groups. Each group was etched with related HF (experimental, Ultradent and Kimia for 1 minute. SEM images were recorded at 3 magnifications. B- Bond strength test: 18 feldespathic discs were considered for each acidic group. Then the porcelain surfaces were etched and bonded to composite with unfilled resin. Consequently, the microshear test was done. C- Microleakage test: 54 discs were divided into 3 groups (n=18. Then the porcelain surfaces were etched and bonded to composite with unfilled resin and finally observed under stereomicroscope. The data were analyzed with one-way ANOVA and Smirnov tests. Results: SEM analysis showed no difference between groups in terms of etch pattern. Microshear bond strength values for experimental, Kimia, and Ultradent HF were 28.53 (±4.92, 28.21 (±6.61, and 26.14 (±7.61 MPa, respectively. There was no significant difference between the bond strength of test groups (P0.05. Conclusion: Quality of experimental HF in terms of etch pattern, microshear bond strength and microleakage of composite/porcelain interface was similar to that of two commercial hydrofluoric acids.

  16. Synthesis and White-Light Emission of ZnO/HfO2: Eu Nanocables

    Directory of Open Access Journals (Sweden)

    Liu Lixin

    2010-01-01

    Full Text Available Abstract ZnO/HfO2:Eu nanocables were prepared by radio frequency sputtering with electrospun ZnO nanofibers as cores. The well-crystallized ZnO/HfO2:Eu nanocables showed a uniform intact core–shell structure, which consisted of a hexagonal ZnO core and a monoclinic HfO2 shell. The photoluminescence properties of the samples were characterized. A white-light band emission consisted of blue, green, and red emissions was observed in the nanocables. The blue and green emissions can be attributed to the zinc vacancy and oxygen vacancy defects in ZnO/HfO2:Eu nanocables, and the yellow–red emissions are derived from the inner 4f-shell transitions of corresponding Eu3+ ions in HfO2:Eu shells. Enhanced white-light emission was observed in the nanocables. The enhancement of the emission is ascribed to the structural changes after coaxial synthesis.

  17. Mixed Al and Si doping in ferroelectric HfO{sub 2} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Lomenzo, Patrick D.; Nishida, Toshikazu, E-mail: nishida@ufl.edu [Department of Electrical and Computer Engineering, University of Florida, Gainesville, Florida 32611 (United States); Takmeel, Qanit [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Zhou, Chuanzhen [Analytical Instrumentation Center, College of Engineering at North Carolina State University, Raleigh, North Carolina 27696 (United States); Chung, Ching-Chang; Jones, Jacob L. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27696 (United States); Moghaddam, Saeed [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2015-12-14

    Ferroelectric HfO{sub 2} thin films 10 nm thick are simultaneously doped with Al and Si. The arrangement of the Al and Si dopant layers within the HfO{sub 2} greatly influences the resulting ferroelectric properties of the polycrystalline thin films. Optimizing the order of the Si and Al dopant layers led to a remanent polarization of ∼20 μC/cm{sup 2} and a coercive field strength of ∼1.2 MV/cm. Post-metallization anneal temperatures from 700 °C to 900 °C were used to crystallize the Al and Si doped HfO{sub 2} thin films. Grazing incidence x-ray diffraction detected differences in peak broadening between the mixed Al and Si doped HfO{sub 2} thin films, indicating that strain may influence the formation of the ferroelectric phase with variations in the dopant layering. Endurance characteristics show that the mixed Al and Si doped HfO{sub 2} thin films exhibit a remanent polarization greater than 15 μC/cm{sup 2} up to 10{sup 8} cycles.

  18. Thermal evolution of CaO-doped HfO{sub 2} films and powders

    Energy Technology Data Exchange (ETDEWEB)

    Barolin, S A; Sanctis, O A de [Lab. Materiales Ceramicos, FCEIyA, Universidad Nacional de Rosario, IFIR-CONICET (Argentina); Caracoche, M C; Martinez, J A; Taylor, M A; Pasquevich, A F [Departamento de Fisica, FCE, Universidad Nacional de La Plata, IFLP-CONICET (Argentina); Rivas, P C, E-mail: oski@fceia.unr.edu.a [Facultad de Ciencias Agronomicas y Forestales, Universidad Nacional de La Plata, IFLP (Argentina)

    2009-05-01

    Solid solutions of ZrO2 and HfO2 are potential electrolyte materials for intermediate-temperature SOFC because both are oxygen-ion conductors. The main challenge for these compounds is to reduce the relatively high value of the activation energies vacancies diffusion, which is influenced by several factors. In this work the thermal evolution of CaO-HfO{sub 2} materials have been investigated. (CaO)y-Hf(1-y)O(2-y) (y = 0.06, 0.14 y 0.2) coatings and powders were synthesized by chemical solution deposition (CSD). Films were deposited onto alumina substrates by Dip Coating technique, the burning of organic waste was carried out at 500 deg. C under normal atmosphere and then the films were thermally treated at intervals of temperature rising to a maximum temperature of 1250 deg. C. By means Glazing Incidence X-ray Diffraction (rho-2theta configuration) the phases were studied in the annealed films. On the other hand, the thermal evolution and crystallization process of powders were analyzed in-situ by HT-XRD. The phenomena crystallization occurred in films and powders were analyzed. The activation energies of diffusion of oxygen vacancies of HfO2-14 mole% CaO and HfO2-20 mole% CaO films were measured from the thermal evolution of the relaxation constant measured by Perturbed Angular Correlation Technique.

  19. Atomic layer deposition of HfO{sub 2}: Growth initiation study on metallic underlayers

    Energy Technology Data Exchange (ETDEWEB)

    Platt, Christopher L., E-mail: Christopher.L.Platt@seagate.co [Seagate Technology, 47010 Kato Rd, Fremont, CA 94538 (United States); Li Ning; Li Kejing; Klein, Tonya M. [Department of Chemical and Biological Engineering, University of Alabama, A131 Bevill Building, Tuscaloosa, AL 35487-0203 (United States)

    2010-05-31

    The initial stages of HfO{sub 2} film growth by atomic layer deposition (ALD) on Co, Ta, and Pt thin films have been compared by x-ray photoelectron spectroscopy (XPS) and attenuated total reflection Fourier transform infrared spectroscopy. The initial tetrakis-dimethylamido(IV) hafnium (TDMAH) adsorption rate was highest on Co and increased with substrate temperature between 150 {sup o}C and 250 {sup o}C. The initial adsorption rate of TDMAH on Ta was less than on Co or Pt at the same substrate temperatures. The Ta surface also proved to be more stable with regard to TDMAH decomposition as fluctuations of adsorbed Hf and decomposition products were not observed during ALD cycling. Larger amounts of carbon were observed on Pt after TDMAH exposure compared to Co or Ta, suggestive of decomposition products. The XPS Hf(4f) peak measured after initial exposure of TDMAH on Pt showed evidence of two Hf oxidation states at the surface. It is postulated that the reaction of TDMAH and decomposition by-products with available oxygen or hydroxyl molecules at the surface of the various metal underlayers affected the initial growth of HfO{sub 2}.

  20. Properties of Dopants in HfOx for Improving the Performance of Nonvolatile Memory

    Science.gov (United States)

    Duncan, Dan; Magyari-Köpe, Blanka; Nishi, Yoshio

    2017-03-01

    Doping is an increasingly popular technique for improving the characteristics of cutting-edge HfOx nonvolatile memory devices, but relatively few dopant species have been investigated. In this work, the properties of 50 different cation and anion dopants in HfOx are explored using density-functional theory and are corroborated with experimental data. Depending on the atomic species, dopants are found to preferentially form on either substitutional or interstitial lattice sites and to reduce the formation energy of oxygen vacancies in the surrounding oxide. The behavior of cation dopants in HfOx is also found to be well predicted by six properties: dopant valence, atomic radius, native-oxide enthalpy of formation, coordination number, magnetization, and charge transfer with the HfOx lattice. These results can be used to optimize dopant selection for tuning of the switching characteristics of HfOx -based resistance-change random-access-memory and conductive-bridge random-access-memory devices.