Modified Hazard Ranking System/Hazard Ranking System for sites with mixed radioactive and hazardous wastes: Software documentation

International Nuclear Information System (INIS)

Stenner, R.D.; Peloquin, R.A.; Hawley, K.A.

1986-11-01

The mHRS/HRS software package was developed by the Pacific Northwest Laboratory (PNL) under contract with the Department of Energy (DOE) to provide a uniform method for DOE facilities to use in performing their Conservation Environmental Response Compensation and Liability Act (CERCLA) Phase I Modified Hazard Ranking System or Hazard Ranking System evaluations. The program is designed to remove the tedium and potential for error associated with the performing of hand calculations and the interpreting of information on tables and in reference books when performing an evaluation. The software package is designed to operate on a microcomputer (IBM PC, PC/XT, or PC/AT, or a compatible system) using either a dual floppy disk drive or a hard disk storage system. It is written in the dBASE III language and operates using the dBASE III system. Although the mHRS/HRS software package was developed for use at DOE facilities, it has direct applicability to the performing of CERCLA Phase I evaluations for any facility contaminated by hazardous waste. The software can perform evaluations using either the modified hazard ranking system methodology developed by DOE/PNL, the hazard ranking system methodology developed by EPA/MITRE Corp., or a combination of the two. This document is a companion manual to the mHRS/HRS user manual. It is intended for the programmer who must maintain the software package and for those interested in the computer implementation. This manual documents the system logic, computer programs, and data files that comprise the package. Hardware and software implementation requirements are discussed. In addition, hand calculations of three sample situations (problems) with associated computer runs used for the verification of program calculations are included

Safety analysis of exothermic reaction hazards associated with the organic liquid layer in tank 241-C-103

International Nuclear Information System (INIS)

Postma, A.K.; Bechtold, D.B.; Borsheim, G.L.; Grisby, J.M.; Guthrie, R.L.; Kummerer, M.; Turner, D.A.; Plys, M.G.

1994-03-01

Safety hazards associated with the interim storage of a potentially flammable organic liquid in waste Tank C-103 are identified and evaluated. The technical basis for closing the unreviewed safety question (USQ) associated with the floating liquid organic layer in this tank is presented

Safety analysis of exothermic reaction hazards associated with the organic liquid layer in tank 241-C-103

Energy Technology Data Exchange (ETDEWEB)

Postma, A.K.; Bechtold, D.B.; Borsheim, G.L.; Grisby, J.M.; Guthrie, R.L.; Kummerer, M.; Turner, D.A. [Westinghouse Hanford Co., Richland, WA (United States); Plys, M.G. [Fauske and Associates, Inc., Burr Ridge, IL (United States)

1994-03-01

Safety hazards associated with the interim storage of a potentially flammable organic liquid in waste Tank C-103 are identified and evaluated. The technical basis for closing the unreviewed safety question (USQ) associated with the floating liquid organic layer in this tank is presented.

Hazardous Waste Manifest System

Science.gov (United States)

EPA’s hazardous waste manifest system is designed to track hazardous waste from the time it leaves the generator facility where it was produced, until it reaches the off-site waste management facility that will store, treat, or dispose of the waste.

An advanced model for spreading and evaporation of accidentally released hazardous liquids on land

NARCIS (Netherlands)

Trijssenaar-Buhre, I.J.M.; Sterkenburg, R.P.; Wijnant-Timmerman, S.I.

2009-01-01

Pool evaporation modelling is an important element in consequence assessment of accidentally released hazardous liquids. The evaporation rate determines the amount of toxic or flammable gas released into the atmosphere and is an important factor for the size of a pool fire. In this paper a

An advanced model for spreading and evaporation of accidentally released hazardous liquids on land

NARCIS (Netherlands)

Trijssenaar-Buhre, I.J.M.; Wijnant-Timmerman, S.L.

2008-01-01

Pool evaporation modelling is an important element in consequence assessment of accidentally released hazardous liquids. The evaporation rate determines the amount of toxic or flammable gas released into the atmosphere and is an important factor for the size of a pool fire. In this paper a

Containment of solidified liquid hazardous waste in domal salt

International Nuclear Information System (INIS)

Domenico, P.A.; Lerman, A.

1992-01-01

In recent years, the solidification of hazardous liquid waste has become a viable option in waste management. The solidification process results in an increased volume but more stable waste form that must be disposed of or stored in a dry environment. An environment of choice in south central Texas is domal salt. The salt dome currently under investigation has a water content of 0.002 percent by weight and a permeability less than one nanodarcy. A question that must be addressed is whether a salt dome has a particular set of attributes that will prevent the release of contaminants to the environment. From a regulatory perspective, a ''no migration'' petition must be approved by the U.S.E.P.A. for the containment facility. By ''no migration'' it is implied that the waste must be contained for 10,000 years. A demonstration that this condition will be met will require model calculations and such models must be based on the physical and chemical characteristics of the waste form and the geologic environment. In particular, the models must address the rate of brine infiltration into the caverns, providing information on how fast an immobile solid waste form could convert to a more mobile liquid state. Additionally, the potential for migration by both diffusion and advection is of concern. Lastly, given a partially saturated cavern, the question of how far gaseous waste will be transported over the 10,000 year containment period must also be addressed. Results indicate that the containment capabilities of domal salt are exceptional. A nominal volume of brine will seep into the cavern and most voids between the injected solidified waste pellets will remain unsaturated. Very small quantities of hazardous constituents will be leached from the waste pellets

The Coastal Hazard Wheel system for coastal multi-hazard assessment & management in a changing climate

DEFF Research Database (Denmark)

Appelquist, Lars Rosendahl; Halsnæs, Kirsten

2015-01-01

This paper presents the complete Coastal Hazard Wheel (CHW) system, developed for multi-hazard-assessment and multi-hazard-management of coastal areas worldwide under a changing climate. The system is designed as a low-tech tool that can be used in areas with limited data availability...... screening and management. The system is developed to assess the main coastal hazards in a single process and covers the hazards of ecosystem disruption, gradual inundation, salt water intrusion, erosion and flooding. The system was initially presented in 2012 and based on a range of test......-applications and feedback from coastal experts, the system has been further refined and developed into a complete hazard management tool. This paper therefore covers the coastal classification system used by the CHW, a standardized assessment procedure for implementation of multi-hazard-assessments, technical guidance...

The handling, hazards, and maintenance of heavy liquids in the geologic laboratory

Science.gov (United States)

Hauff, Phoebe L.; Airey, Joseph

1980-01-01

In geologic laboratories the organic heavy liquids bromoform, methylene iodide, tetrabromoethane, and clerici compounds have been used for years in mineral separation processes. Because the volume of use of these compounds is low, insufficient data is available on their toxic properties. This report is an attempt to summarize the known data from published and industry sources. The physical properties, hazards of handling,proper storage facilities, and adequate protective Clothing are discussed for each compound as well as for their common and less-common solvents. Toxicity data for these materials is listed along with exposure symptoms and suggested first aid treatments. Safety for the worker is emphasized. Three reclamation methods which recover the solvent used as a dilutant and purify the heavy liquid are discussed and illustrated. These include: the water cascade, re fluxing-distillation-condensation, and flash evaporation methods. Various techniques for restoration and stabilization of these heavy liquids are also included.

Sustainable System for Residual Hazards Management

International Nuclear Information System (INIS)

Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

2004-01-01

Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today's waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous long-term management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by external intrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the long-term success of the prescribed system. In fact

utilization of adsorption and/or liquid membranes techniques in treatment of some hazardous substances

International Nuclear Information System (INIS)

Hussin, L.M.S.

2011-01-01

environmental pollution, as a consequence of the industrialization process, is one of the major problems that has to be solved and controlled. The most important treatment processes for metals and dyes contaminated waste streams include chemical precipitation, membrane, filtration, ion exchange, carbon adsorption and coprecipitation/adsorption. However, all these techniques have their inherent advantages and limitations in applications. These processes usually need expensive facility and high maintenance cost. Therefore, there is a need for more economical alternative technologies for the treatment of metals and dyes contaminated waste streams. The aim of present work is to study the treatment of some hazardous substances such as heavy metals e.g. ( lead, cobalt and strontium) and dyes e.g. ( acid red 73, and acid blue 74 ) using either adsorption or liquid emulsion membrane techniques. The experimental part deals with the application of adsorption and liquid emulsion membrane techniques for removal of some hazardous substances such as metal ions ( lead, cobalt and strontium) and dyes (acid red 73 and acid blue 74). All the apparatus and techniques employed were described.

Geological hazard monitoring system in Georgia

Science.gov (United States)

Gaprindashvili, George

2017-04-01

Georgia belongs to one of world's most complex mountainous regions according to the scale and frequency of Geological processes and damage caused to population, farmlands, and Infrastructure facilities. Geological hazards (landslide, debrisflow/mudflow, rockfall, erosion and etc.) are affecting many populated areas, agricultural fields, roads, oil and gas pipes, high-voltage electric power transmission towers, hydraulic structures, and tourist complexes. Landslides occur almost in all geomorphological zones, resulting in wide differentiation in the failure types and mechanisms and in the size-frequency distribution. In Georgia, geological hazards triggered by: 1. Activation of highly intense earthquakes; 2. Meteorological events provoking the disaster processes on the background of global climatic change; 3. Large-scale Human impact on the environment. The prediction and monitoring of Geological Hazards is a very wide theme, which involves different researchers from different spheres. Geological hazard monitoring is essential to prevent and mitigate these hazards. In past years in Georgia several monitoring system, such as Ground-based geodetic techniques, Debrisflow Early Warning System (EWS) were installed on high sensitive landslide and debrisflow areas. This work presents description of Geological hazard monitoring system in Georgia.

Process equipment waste and process waste liquid collection systems

International Nuclear Information System (INIS)

1990-06-01

The US DOE has prepared an environmental assessment for construction related to the Process Equipment Waste (PEW) and Process Waste Liquid (PWL) Collection System Tasks at the Idaho Chemical Processing Plant. This report describes and evaluates the environmental impacts of the proposed action (and alternatives). The purpose of the proposed action would be to ensure that the PEW and PWL collection systems, a series of enclosed process hazardous waste, and radioactive waste lines and associated equipment, would be brought into compliance with applicable State and Federal hazardous waste regulations. This would be accomplished primarily by rerouting the lines to stay within the buildings where the lined floors of the cells and corridors would provide secondary containment. Leak detection would be provided via instrumented collection sumps locate din the cells and corridors. Hazardous waste transfer lines that are routed outside buildings will be constructed using pipe-in-pipe techniques with leak detection instrumentation in the interstitial area. The need for the proposed action was identified when a DOE-sponsored Resource Conservation and Recovery Act (RCRA) compliance assessment of the ICPP facilities found that singly-contained waste lines ran buried in the soil under some of the original facilities. These lines carried wastes with a pH of less than 2.0, which were hazardous waste according to the RCRA standards. 20 refs., 7 figs., 1 tab

76 FR 4823 - Hazardous Waste Management System; Identifying and Listing Hazardous Waste Exclusion

Science.gov (United States)

2011-01-27

... Waste Management System; Identifying and Listing Hazardous Waste Exclusion AGENCY: Environmental... hazardous wastes. The Agency has decided to grant the petition based on an evaluation of waste-specific... excludes the petitioned waste from the requirements of hazardous waste regulations under the Resource...

Development and design of a high pressure carbon dioxide system for the separation of hazardous contaminants from non-hazardous debris

International Nuclear Information System (INIS)

Adkins, C.L.J.; Russick, E.M.; Smith, H.M.; Olson, R.B.

1995-01-01

Under the Department of Energy (DOE)/United States Air Force (USAF) Memorandum of Understanding, a system is being designed that will use high pressure carbon dioxide for the separation of oils, greases, and solvents from non-hazardous solid waste. The contaminants are dissolved into the high pressure carbon dioxide and precipitated out upon depressurization. The carbon dioxide solvent can then be recycled for continued use. Excellent extraction capability for common manufacturing oils, greases, and solvents has been measured. It has been observed that extraction performance follows the dilution model if a constant flow system is used. The solvents tested are extremely soluble and have been extracted to 100% under both liquid and mild supercritical carbon dioxide conditions. These data are being used to design a 200 liter extraction system

Modified hazard ranking system for sites with mixed radioactive and hazardous wastes. User manual

International Nuclear Information System (INIS)

Hawley, K.A.; Peloquin, R.A.; Stenner, R.D.

1986-04-01

This document describes both the original Hazard Ranking System and the modified Hazard Ranking System as they are to be used in evaluating the relative potential for uncontrolled hazardous substance facilities to cause human health or safety problems or ecological or environmental damage. Detailed instructions for using the mHRS/HRS computer code are provided, along with instructions for performing the calculations by hand. Uniform application of the ranking system will permit the DOE to identify those releases of hazardous substances that pose the greatest hazard to humans or the environment. However, the mHRS/HRS by itself cannot establish priorities for the allocation of funds for remedial action. The mHRS/HRS is a means for applying uniform technical judgment regarding the potential hazards presented by a facility relative to other facilities. It does not address the feasibility, desirability, or degree of cleanup required. Neither does it deal with the readiness or ability of a state to carry out such remedial action, as may be indicated, or to meet other conditions prescribed in CERCLA. 13 refs., 13 figs., 27 tabs

Modified hazard ranking system for sites with mixed radioactive and hazardous wastes. User manual.

Energy Technology Data Exchange (ETDEWEB)

Hawley, K.A.; Peloquin, R.A.; Stenner, R.D.

1986-04-01

This document describes both the original Hazard Ranking System and the modified Hazard Ranking System as they are to be used in evaluating the relative potential for uncontrolled hazardous substance facilities to cause human health or safety problems or ecological or environmental damage. Detailed instructions for using the mHRS/HRS computer code are provided, along with instructions for performing the calculations by hand. Uniform application of the ranking system will permit the DOE to identify those releases of hazardous substances that pose the greatest hazard to humans or the environment. However, the mHRS/HRS by itself cannot establish priorities for the allocation of funds for remedial action. The mHRS/HRS is a means for applying uniform technical judgment regarding the potential hazards presented by a facility relative to other facilities. It does not address the feasibility, desirability, or degree of cleanup required. Neither does it deal with the readiness or ability of a state to carry out such remedial action, as may be indicated, or to meet other conditions prescribed in CERCLA. 13 refs., 13 figs., 27 tabs.

Automated hazard analysis of digital control systems

International Nuclear Information System (INIS)

Garrett, Chris J.; Apostolakis, George E.

2002-01-01

Digital instrumentation and control (I and C) systems can provide important benefits in many safety-critical applications, but they can also introduce potential new failure modes that can affect safety. Unlike electro-mechanical systems, whose failure modes are fairly well understood and which can often be built to fail in a particular way, software errors are very unpredictable. There is virtually no nontrivial software that will function as expected under all conditions. Consequently, there is a great deal of concern about whether there is a sufficient basis on which to resolve questions about safety. In this paper, an approach for validating the safety requirements of digital I and C systems is developed which uses the Dynamic Flowgraph Methodology to conduct automated hazard analyses. The prime implicants of these analyses can be used to identify unknown system hazards, prioritize the disposition of known system hazards, and guide lower-level design decisions to either eliminate or mitigate known hazards. In a case study involving a space-based reactor control system, the method succeeded in identifying an unknown failure mechanism

Plasma-liquid system with rotational gliding discharge with liquid electrode

International Nuclear Information System (INIS)

Nedybaliuk, O.A.; Solomenko, O.V; Martysh, E.V.; Fedirchuk, I.I.

2014-01-01

Plasma-liquid system based on rotational gliding discharge with one liquid electrode was developed. Emission spectra of plasma of rotational gliding discharge with one liquid electrode were investigated. Discovered effective mechanism of controlling non-isothermal level of plasma in dynamic plasma-liquid systems. Major mechanism of expulsion of metal anode material from plasma-liquid systems with rotational discharges was shown.

76 FR 55846 - Hazardous Waste Management System: Identification and Listing of Hazardous Waste: Carbon Dioxide...

Science.gov (United States)

2011-09-09

... carbon dioxide (CO 2 ) streams that are hazardous from the definition of hazardous waste, provided these... management under the Resource Conservation and Recovery Act (RCRA) to conditionally exclude carbon dioxide... 2050-AG60 Hazardous Waste Management System: Identification and Listing of Hazardous Waste: Carbon...

A complete electrical hazard classification system and its application

Energy Technology Data Exchange (ETDEWEB)

Gordon, Lloyd B [Los Alamos National Laboratory; Cartelli, Laura [Los Alamos National Laboratory

2009-01-01

The Standard for Electrical Safety in the Workplace, NFPA 70E, and relevant OSHA electrical safety standards evolved to address the hazards of 60-Hz power that are faced primarily by electricians, linemen, and others performing facility and utility work. This leaves a substantial gap in the management of electrical hazards in Research and Development (R&D) and specialized high voltage and high power equipment. Examples include lasers, accelerators, capacitor banks, electroplating systems, induction and dielectric heating systems, etc. Although all such systems are fed by 50/60 Hz alternating current (ac) power, we find substantial use of direct current (dc) electrical energy, and the use of capacitors, inductors, batteries, and radiofrequency (RF) power. The electrical hazards of these forms of electricity and their systems are different than for 50160 Hz power. Over the past 10 years there has been an effort to develop a method of classifying all of the electrical hazards found in all types of R&D and utilization equipment. Examples of the variation of these hazards from NFPA 70E include (a) high voltage can be harmless, if the available current is sufficiently low, (b) low voltage can be harmful if the available current/power is high, (c) high voltage capacitor hazards are unique and include severe reflex action, affects on the heart, and tissue damage, and (d) arc flash hazard analysis for dc and capacitor systems are not provided in existing standards. This work has led to a comprehensive electrical hazard classification system that is based on various research conducted over the past 100 years, on analysis of such systems in R&D, and on decades of experience. Initially, national electrical safety codes required the qualified worker only to know the source voltage to determine the shock hazard. Later, as arc flash hazards were understood, the fault current and clearing time were needed. These items are still insufficient to fully characterize all types of

Integrated treatment process of hazardous and mixed wastes

International Nuclear Information System (INIS)

Shibuya, M.; Suzuki, K.; Fujimura, Y.; Nakashima, T.; Moriya, Y.

1993-01-01

An integrated waste treatment system was studied based on technologies developed for the treatment of liquid radioactive, organic, and aqueous wastes containing hazardous materials and soils contaminated with heavy metals. The system consists of submerged incineration, metal ion fixing and stabilization, and soil washing treatments. Introduction of this system allows for the simultaneous processing of toxic waste and contaminated soils. Hazardous organic wastes can be decomposed into harmless gases, and aqueous wastes can be converted into a dischargeable effluent. The contaminated soil is backfilled after the removal of toxic materials. Experimental data show that the integration system is practical for complicated toxic wastes

Integrated Geo Hazard Management System in Cloud Computing Technology

Science.gov (United States)

Hanifah, M. I. M.; Omar, R. C.; Khalid, N. H. N.; Ismail, A.; Mustapha, I. S.; Baharuddin, I. N. Z.; Roslan, R.; Zalam, W. M. Z.

2016-11-01

Geo hazard can result in reducing of environmental health and huge economic losses especially in mountainous area. In order to mitigate geo-hazard effectively, cloud computer technology are introduce for managing geo hazard database. Cloud computing technology and it services capable to provide stakeholder's with geo hazards information in near to real time for an effective environmental management and decision-making. UNITEN Integrated Geo Hazard Management System consist of the network management and operation to monitor geo-hazard disaster especially landslide in our study area at Kelantan River Basin and boundary between Hulu Kelantan and Hulu Terengganu. The system will provide easily manage flexible measuring system with data management operates autonomously and can be controlled by commands to collects and controls remotely by using “cloud” system computing. This paper aims to document the above relationship by identifying the special features and needs associated with effective geohazard database management using “cloud system”. This system later will use as part of the development activities and result in minimizing the frequency of the geo-hazard and risk at that research area.

Proceedings of emerging technologies for hazardous waste management

International Nuclear Information System (INIS)

Tedder, D.W.

1992-01-01

This paper contains the proceedings of emergin technologies for hazardous waste management. Topics covered include: advanced transuranic waste managements; remediation of soil/water systems contaminated with nonaqueous pollutants; advances in molten salt oxidation; air treatment and protection; advanced waste minimization strategies; removal of hazardous materials from soils or groundwater; bioremediation of soils and sediment; innovation, monitoring, and asbestos; high-level liquid waste chemistry in the Hanford tanks; biological contributions to soil and groundwater remediation; soil treatment technologies; pollution prevention; incineration and vitrification; current technology; systematic design approaches to hazardous waste management; waste management and environmental restoration at Savannah River; soil washing and flushing for remediation of hazardous wastes

Proportional hazards models of infrastructure system recovery

International Nuclear Information System (INIS)

Barker, Kash; Baroud, Hiba

2014-01-01

As emphasis is being placed on a system's ability to withstand and to recover from a disruptive event, collectively referred to as dynamic resilience, there exists a need to quantify a system's ability to bounce back after a disruptive event. This work applies a statistical technique from biostatistics, the proportional hazards model, to describe (i) the instantaneous rate of recovery of an infrastructure system and (ii) the likelihood that recovery occurs prior to a given point in time. A major benefit of the proportional hazards model is its ability to describe a recovery event as a function of time as well as covariates describing the infrastructure system or disruptive event, among others, which can also vary with time. The proportional hazards approach is illustrated with a publicly available electric power outage data set

75 FR 58346 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste

Science.gov (United States)

2010-09-24

... Waste Management System; Identification and Listing of Hazardous Waste AGENCY: Environmental Protection... Chemical Company-Texas Operations (Eastman) to exclude (or delist) certain solid wastes generated by its Longview, Texas, facility from the lists of hazardous wastes. EPA used the Delisting Risk Assessment...

Hazardous and radioactive waste incineration studies

International Nuclear Information System (INIS)

Vavruska, J.S.; Stretz, L.A.; Borduin, L.C.

1981-01-01

Development and demonstration of a transuranic (TRU) waste volume-reduction process is described. A production-scale controlled air incinerator using commercially available equipment and technology has been modified for solid radioactive waste service. This unit successfully demonstrated the volume reduction of transuranic (TRU) waste with an average TRU content of about 20 nCi/g. The same incinerator and offgas treatment system is being modified further to evaluate the destruction of hazardous liquid wastes such as polychlorinated biphenyls (PCBs) and hazardous solid wastes such as pentachlorophenol (PCP)-treated wood

75 FR 73972 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Removal of...

Science.gov (United States)

2010-11-30

... Waste Management System; Identification and Listing of Hazardous Waste; Removal of Direct Final.... Lists of Subjects in 40 CFR Part 261 Environmental Protection, Hazardous waste, Recycling, Reporting and... follows: PART 261--IDENTIFICATION AND LISTING OF HAZARDOUS WASTE 0 1. The authority citation for part 261...

Bioprocessing scenarios for mixed hazardous waste

International Nuclear Information System (INIS)

Wolfram, J.H.; Rogers, R.D.

1994-01-01

The potential of biological processing of mixed hazardous waste has not been determined. However, the use of selected microorganisms for the degradation and/or detoxification of hazardous organic compounds is gaining wide acceptance as an alternative waste treatment technology. The isolation of a unique strain of Pseudomonas Putida Idaho seems well adapted to withstand the demands of the input stream comprised of liquid scintillation waste. This paper describes the results from the continuous processing of a mixture comprised of p-xylene and surfactant as well as commercial liquid scintillation formulations. The two formulations tested contained xylene and pseudocumene as the solvent base. The process is now at the demonstration phase at one of DOE's facilities which has a substantial amount of stored waste of this type. The system at the DOE facility is comprised of two CSTR units in series

75 FR 17111 - Hazardous Materials Regulations: Combustible Liquids

Science.gov (United States)

2010-04-05

... the probability and quantity of a hazardous material release. Under the HMR, hazardous materials are... present during transportation. The HMR specify appropriate packaging and handling requirements for... hazardous materials in commerce. During our regulatory review process, we look for opportunities that may...

Evaluation of Absorbents for Compatibility with Site Generated Hazardous and Mixed Liquid Wastes

International Nuclear Information System (INIS)

Oji, L.N.

2002-01-01

SRS Solid Waste requested SRTC to perform a literature-based evaluation of sorbents, which are compatible with hazardous mixed waste being generated on site. Polypropylene-based materials and ground corn cob (Toxi-dry), because of their compatibility with the Consolidated Incinerator Facility (CIF) process, are the only two spill stabilization agents which are recommended for use on site (IS manual, Waste Acceptance Criteria 3.18). While ensuring minimal potential for undesired reactions between spills and spill control agents, Solid Waste wants to increase the number of site approved absorbents to give waste generators more flexibility in choosing liquid spill immobilization agents

Investigation of two-phase liquid-metal magnetohydrodynamic power systems

International Nuclear Information System (INIS)

Amend, W.E.; Fabris, G.; Cutting, J.

1975-01-01

A two-phase Liquid-Metal MHD (LMMHD) system is under development at the Argonne National Laboratory, and results are presented for detailed cycle analysis and systems studies, the experimental facility, and the thermal and magneto fluid mechanics problems encountered. The studies indicate that the LMMHD cycle will operate efficiently in the temperature range of 1000-1600 0 F (50 percent efficiency with a maximum cycle temperature of 1600 0 F) and is therefore potentially compatible with many advanced heat sources under development such as the LMFBR, fluidized-bed coal combustor, HTGCR and the fusion reactor. Of special interest is the coupling to the LMFBR thereby eliminating the costly, potentially hazardous liquid-metal/water interface. The results of detailed parametric studies of the heat transfer interfaces between an LMMHD power cycle and an LMFBR and a steam bottoming plant are described. Experimental evaluation of the two-phase LMMHD generator was performed in an ambient temperature NaK--N 2 facility at ANL. Results of these experiments, performed to determine the operating characteristics of the device as a function of the various independent parameters and to investigate two-phase flow, are given. (U.S.)

Liquid waste treatment system. Final report

International Nuclear Information System (INIS)

Baker, M.N.; Houston, H.M.

1999-01-01

Pretreatment of high-level liquid radioactive waste (HLW) at the West Valley Demonstration Project (WVDP) involved three distinct processing operations: decontamination of liquid HLW in the Supernatant Treatment System (STS); volume reduction of decontaminated liquid in the Liquid Waste Treatment System (LWTS); and encapsulation of resulting concentrates into an approved cement waste form in the Cement Solidification System (CSS). Together, these systems and operations made up the Integrated Radwaste Treatment System (IRTS)

Landslide hazards and systems analysis: A Central European perspective

Science.gov (United States)

Klose, Martin; Damm, Bodo; Kreuzer, Thomas

2016-04-01

Part of the problem with assessing landslide hazards is to understand the variable settings in which they occur. There is growing consensus that hazard assessments require integrated approaches that take account of the coupled human-environment system. Here we provide a synthesis of societal exposure and vulnerability to landslide hazards, review innovative approaches to hazard identification, and lay a focus on hazard assessment, while presenting the results of historical case studies and a landslide time series for Germany. The findings add to a growing body of literature that recognizes societal exposure and vulnerability as a complex system of hazard interactions that evolves over time as a function of social change and development. We therefore propose to expand hazard assessments by the framework and concepts of systems analysis (e.g., Liu et al., 2007) Results so far have been promising in ways that illustrate the importance of feedbacks, thresholds, surprises, and time lags in the evolution of landslide hazard and risk. In densely populated areas of Central Europe, landslides often occur in urbanized landscapes or on engineered slopes that had been transformed or created intentionally by human activity, sometimes even centuries ago. The example of Germany enables to correlate the causes and effects of recent landslides with the historical transition of urbanization to urban sprawl, ongoing demographic change, and some chronic problems of industrialized countries today, including ageing infrastructures or rising government debts. In large parts of rural Germany, the combination of ageing infrastructures, population loss, and increasing budget deficits starts to erode historical resilience gains, which brings especially small communities to a tipping point in their efforts to risk reduction. While struggling with budget deficits and demographic change, these communities are required to maintain ageing infrastructures that are particularly vulnerable to

Chemical incidents resulted in hazardous substances releases in the context of human health hazards

Directory of Open Access Journals (Sweden)

Anna Pałaszewska-Tkacz

2017-02-01

Full Text Available Objectives: The research purpose was to analyze data concerning chemical incidents in Poland collected in 1999–2009 in terms of health hazards. Material and Methods: The data was obtained, using multimodal information technology (IT system, from chemical incidents reports prepared by rescuers at the scene. The final analysis covered sudden events associated with uncontrolled release of hazardous chemical substances or mixtures, which may potentially lead to human exposure. Releases of unidentified substances where emergency services took action to protect human health or environment were also included. Results: The number of analyzed chemical incidents in 1999–2009 was 2930 with more than 200 different substances released. The substances were classified into 13 groups of substances and mixtures posing analogous risks. Most common releases were connected with non-flammable corrosive liquids, including: hydrochloric acid (199 cases, sulfuric(VI acid (131 cases, sodium and potassium hydroxides (69 cases, ammonia solution (52 cases and butyric acid (32 cases. The next group were gases hazardous only due to physico-chemical properties, including: extremely flammable propane-butane (249 cases and methane (79 cases. There was no statistically significant trend associated with the total number of incidents. Only with the number of incidents with flammable corrosive, toxic and/or harmful liquids, the regression analysis revealed a statistically significant downward trend. The number of victims reported was 1997, including 1092 children and 18 fatalities. Conclusions: The number of people injured, number of incidents and the high 9th place of Poland in terms of the number of Seveso establishments, and 4 times higher number of hazardous industrial establishments not covered by the Seveso Directive justify the need for systematic analysis of hazards and their proper identification. It is advisable enhance health risk assessment, both qualitative and

Process hazards review of the 904-A trench

International Nuclear Information System (INIS)

Snyder, D.E.

1988-01-01

The 904-A trench is an enclosed underground concrete containment for high level and low level radioactive waste lines between the main Laboratory Building 773-A and waste storage and shipping Building 776-A. The waste generated in laboratories and other facilities in 773-A flows by gravity into the high level and low level drain lines, which proceed from 773-A through the 904-A trench. The trench ends at 776-2A, where the underground was handling tanks for both high level and low level liquids are located. The trench serves to contain any leaks originating in the drain lines. The trench is sloped downward toward the Building 776-2A pipe gallery. Any liquid collected from the sump can be pumped automatically to a waste tank sampled. The review of the 904-A trench system included a study of the trench and piping itself, as well as a study of the high level and low level drain lines from the laboratories to the trench. The present review emphasized on examination of the hazards involved in chemical reactions in the drain lines, misuse of the drains, and criticality. The following items were examined: Process Hazards Review of the Liquid Waste Collection System, Nuclear Criticality Review of the High Level Drain System, Improvements in the 904-A Trench System, Operating Procedures, and Unusual Incidents

The Volcanic Hazards Assessment Support System for the Online Hazard Assessment and Risk Mitigation of Quaternary Volcanoes in the World

Directory of Open Access Journals (Sweden)

Shinji Takarada

2017-12-01

Full Text Available Volcanic hazards assessment tools are essential for risk mitigation of volcanic activities. A number of offline volcanic hazard assessment tools have been provided, but in most cases, they require relatively complex installation procedure and usage. This situation causes limited usage of volcanic hazard assessment tools among volcanologists and volcanic hazards communities. In addition, volcanic eruption chronology and detailed database of each volcano in the world are essential key information for volcanic hazard assessment, but most of them are isolated and not connected to and with each other. The Volcanic Hazard Assessment Support System aims to implement a user-friendly, WebGIS-based, open-access online system for potential hazards assessment and risk-mitigation of Quaternary volcanoes in the world. The users can get up-to-date information such as eruption chronology and geophysical monitoring data of a specific volcano using the direct link system to major volcano databases on the system. Currently, the system provides 3 simple, powerful and notable deterministic modeling simulation codes of volcanic processes, such as Energy Cone, Titan2D and Tephra2. The system provides deterministic tools because probabilistic assessment tools are normally much more computationally demanding. By using the volcano hazard assessment system, the area that would be affected by volcanic eruptions in any location near the volcano can be estimated using numerical simulations. The system is being implemented using the ASTER Global DEM covering 2790 Quaternary volcanoes in the world. The system can be used to evaluate volcanic hazards and move this toward risk-potential by overlaying the estimated distribution of volcanic gravity flows or tephra falls on major roads, houses and evacuation areas using the GIS-enabled systems. The system is developed for all users in the world who need volcanic hazards assessment tools.

Polonium release from an ATW burner system with liquid lead-bismuth coolant

International Nuclear Information System (INIS)

Li, N.; Yefimov, E.; Pankratov, D.

1998-04-01

The authors analyzed polonium release hazards in a conceptual pool-type ATW burner with liquid lead-bismuth eutectic (LBE) coolant. Simplified quantitative models are used based on experiments and real NPP experience. They found little Po contamination outside the burner under normal operating conditions with nominal leakage from the gas system. In sudden gas leak and/or coolant spill accidents, the P contamination level can reach above the regulation limit but short exposure would not lead to severe health consequences. They are evaluating and developing mitigation methods

76 FR 16534 - Hazardous Waste Management System Identification and Listing of Hazardous Waste; Final Exclusion

Science.gov (United States)

2011-03-24

... Waste Management System Identification and Listing of Hazardous Waste; Final Exclusion AGENCY...) on a one-time basis from the lists of hazardous waste, a certain solid waste generated at its Mt... waste is [[Page 16535

75 FR 57686 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste Amendment

Science.gov (United States)

2010-09-22

... Waste Management System; Identification and Listing of Hazardous Waste Amendment AGENCY: Environmental...) 260.20 and 260.22 allows facilities to demonstrate that a specific waste from a particular generating facility should not be regulated as a hazardous waste. Based on waste-specific information provided by the...

Thermal properties of ionic systems near the liquid-liquid critical point.

Science.gov (United States)

Méndez-Castro, Pablo; Troncoso, Jacobo; Pérez-Sánchez, Germán; Peleteiro, José; Romaní, Luis

2011-12-07

Isobaric heat capacity per unit volume, C(p), and excess molar enthalpy, h(E), were determined in the vicinity of the critical point for a set of binary systems formed by an ionic liquid and a molecular solvent. Moreover, and, since critical composition had to be accurately determined, liquid-liquid equilibrium curves were also obtained using a calorimetric method. The systems were selected with a view on representing, near room temperature, examples from clearly solvophobic to clearly coulombic behavior, which traditionally was related with the electric permittivity of the solvent. The chosen molecular compounds are: ethanol, 1-butanol, 1-hexanol, 1,3-dichloropropane, and diethylcarbonate, whereas ionic liquids are formed by imidazolium-based cations and tetrafluoroborate or bis-(trifluromethylsulfonyl)amide anions. The results reveal that solvophobic critical behavior-systems with molecular solvents of high dielectric permittivity-is very similar to that found for molecular binary systems. However, coulombic systems-those with low permittivity molecular solvents-show strong deviations from the results usually found for these magnitudes near the liquid-liquid phase transition. They present an extremely small critical anomaly in C(p)-several orders of magnitude lower than those typically obtained for binary mixtures-and extremely low h(E)-for one system even negative, fact not observed, up to date, for any liquid-liquid transition in the nearness of an upper critical solution temperature. © 2011 American Institute of Physics

Hazardous waste minimization tracking system

International Nuclear Information System (INIS)

Railan, R.

1994-01-01

Under RCRA section 3002 9(b) and 3005f(h), hazardous waste generators and owners/operators of treatment, storage, and disposal facilities (TSDFs) are required to certify that they have a program in place to reduce the volume or quantity and toxicity of hazardous waste to the degree determined to be economically practicable. In many cases, there are environmental, as well as, economic benefits, for agencies that pursue pollution prevention options. Several state governments have already enacted waste minimization legislation (e.g., Massachusetts Toxic Use Reduction Act of 1989, and Oregon Toxic Use Reduction Act and Hazardous Waste Reduction Act, July 2, 1989). About twenty six other states have established legislation that will mandate some type of waste minimization program and/or facility planning. The need to address the HAZMIN (Hazardous Waste Minimization) Program at government agencies and private industries has prompted us to identify the importance of managing The HAZMIN Program, and tracking various aspects of the program, as well as the progress made in this area. The open-quotes WASTEclose quotes is a tracking system, which can be used and modified in maintaining the information related to Hazardous Waste Minimization Program, in a manageable fashion. This program maintains, modifies, and retrieves information related to hazardous waste minimization and recycling, and provides automated report generating capabilities. It has a built-in menu, which can be printed either in part or in full. There are instructions on preparing The Annual Waste Report, and The Annual Recycling Report. The program is very user friendly. This program is available in 3.5 inch or 5 1/4 inch floppy disks. A computer with 640K memory is required

46 CFR 151.03-30 - Hazardous material.

Science.gov (United States)

2010-10-01

... hazardous material means a liquid material or substance that is— (a) Flammable or combustible; (b) Designated a hazardous substance under section 311(b) of the Federal Water Pollution Control Act (33 U.S.C... Agency designates hazardous substances in 40 CFR Table 116.4A. The Coast Guard designates hazardous...

Dual liquid and gas chromatograph system

Science.gov (United States)

Gay, D.D.

A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

Directory of Open Access Journals (Sweden)

Kubiczek Artur

2017-03-01

Full Text Available Room-temperature ionic liquids (RTILs are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.

Hazardous Solvent Substitution Data System tutorial

International Nuclear Information System (INIS)

Twitchell, K.E.; Skinner, N.L.

1993-07-01

This manual is the tutorial for the Hazardous Solvent Substitution Data System (HSSDS), an online, comprehensive system of information on alternatives to hazardous solvents and related subjects. The HSSDS data base contains product information, material safety data sheets, toxicity reports, usage reports, biodegradable data, product chemical element lists, and background information on solvents. HSSDS use TOPIC reg-sign to search for information based on a query defined by the user. TOPIC provides a full text retrieval of unstructured source documents. In this tutorial, a series of lessons is provided that guides the user through basic steps common to most queries performed with HSSDS. Instructions are provided for both window-based and character-based applications

75 FR 71559 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Withdrawal of...

Science.gov (United States)

2010-11-24

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 261 [EPA-R06-RCRA-2010-0066; SW FRL-9231-4] Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Withdrawal of Direct Final Exclusion AGENCY: Environmental Protection Agency (EPA). ACTION: Withdrawal of direct final exclusion...

46 CFR 128.450 - Liquid-mud systems.

Science.gov (United States)

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Liquid-mud systems. 128.450 Section 128.450 Shipping...: EQUIPMENT AND SYSTEMS Design Requirements for Specific Systems § 128.450 Liquid-mud systems. (a) Liquid-mud... this chapter. (b) Tanks for oil-based liquid mud must be fitted with tank vents equipped with flame...

Hydrocarbon-Seeded Ignition System for Small Spacecraft Thrusters Using Ionic Liquid Propellants

Science.gov (United States)

Whitmore, Stephen A.; Merkley, Daniel P.; Eilers, Shannon D.; Taylor, Terry L.

2013-01-01

"Green" propellants based on Ionic-liquids (ILs) like Ammonium DiNitramide and Hydroxyl Ammonium Nitrate have recently been developed as reduced-hazard replacements for hydrazine. Compared to hydrazine, ILs offer up to a 50% improvement in available density-specific impulse. These materials present minimal vapor hazard at room temperature, and this property makes IL's potentially advantageous for "ride-share" launch opportunities where hazards introduced by hydrazine servicing are cost-prohibitive. Even though ILs present a reduced hazard compared to hydrazine, in crystalline form they are potentially explosive and are mixed in aqueous solutions to buffer against explosion. Unfortunately, the high water content makes IL-propellants difficult to ignite and currently a reliable "coldstart" capability does not exist. For reliable ignition, IL-propellants catalyst beds must be pre-heated to greater than 350 C before firing. The required preheat power source is substantial and presents a significant disadvantage for SmallSats where power budgets are extremely limited. Design and development of a "micro-hybrid" igniter designed to act as a "drop-in" replacement for existing IL catalyst beds is presented. The design requires significantly lower input energy and offers a smaller overall form factor. Unlike single-use "squib" pyrotechnic igniters, the system allows the gas generation cycle to be terminated and reinitiated on demand.

75 FR 61356 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Correction

Science.gov (United States)

2010-10-05

... Waste Management System; Identification and Listing of Hazardous Waste; Correction AGENCY: Environmental... thermal desorber residual solids with Hazardous Waste Numbers: F037, F038, K048, K049, K050, and K051. In... and correcting it in Table 1 of appendix IX to part 261--Waste Excluded Under Sec. Sec. 260.20 and 260...

Screening sealed bottles for liquid explosives

Science.gov (United States)

Kumar, Sankaran; McMichael, W. Casey; Kim, Y.-W.; Sheldon, Alan G.; Magnuson, Erik E.; Ficke, L.; Chhoa, T. K.; Moeller, C. R.; Barrall, Geoffrey A.; Burnett, Lowell J.; Czipott, Peter V.; Pence, J. S.; Skvoretz, David C.

1997-01-01

A particularly disturbing development affecting transportation safety and security is the increasing use of terrorist devices which avoid detection by conventional means through the use of liquid explosives and flammables. The hazardous materials are generally hidden in wine or liquor bottles that cannot be opened routinely for inspection. This problem was highlighted by the liquid explosives threat which disrupted air traffic between the US an the Far East for an extended period in 1995. Quantum Magnetics has developed a Liquid Explosives Screening systems capable of scanning unopened bottles for liquid explosives. The system can be operated to detect specific explosives directly or to verify the labeled or bar-coded contents of the container. In this system, magnetic resonance (MR) is used to interrogate the liquid. MR produces an extremely rich data set and many characteristics of the MR response can be determined simultaneously. As a result, multiple MR signatures can be defined for any given set of liquids, and the signature complexity then selected according to the level of threat. The Quantum Magnetics Liquid Explosives Screening System is currently operational. Following extensive laboratory testing, a field trial of the system was carried out at the Los Angeles International Airport.

Robots, systems, and methods for hazard evaluation and visualization

Science.gov (United States)

Nielsen, Curtis W.; Bruemmer, David J.; Walton, Miles C.; Hartley, Robert S.; Gertman, David I.; Kinoshita, Robert A.; Whetten, Jonathan

2013-01-15

A robot includes a hazard sensor, a locomotor, and a system controller. The robot senses a hazard intensity at a location of the robot, moves to a new location in response to the hazard intensity, and autonomously repeats the sensing and moving to determine multiple hazard levels at multiple locations. The robot may also include a communicator to communicate the multiple hazard levels to a remote controller. The remote controller includes a communicator for sending user commands to the robot and receiving the hazard levels from the robot. A graphical user interface displays an environment map of the environment proximate the robot and a scale for indicating a hazard intensity. A hazard indicator corresponds to a robot position in the environment map and graphically indicates the hazard intensity at the robot position relative to the scale.

75 FR 60689 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Proposed Rule

Science.gov (United States)

2010-10-01

... Waste Management System; Identification and Listing of Hazardous Waste; Proposed Rule AGENCY... exclude (or delist) a certain solid waste generated by its Beaumont, Texas, facility from the lists of hazardous wastes. EPA used the Delisting Risk Assessment Software (DRAS) Version 3.0 in the evaluation of...

Hazard ranking system: hierarchical system for polluted soils; El Hazard Ranking System. Un sistema para la jerarquizacion de actuaciones en terrenos contaminados

Energy Technology Data Exchange (ETDEWEB)

Callaba de Roa, A

1998-10-01

To develop cost-effective risk minimization strategies, it is important to carefully select contaminated sites in which future tasks will take place (hierarchy of tasks). A hierarchy of sites must focus on those which really pose a significant environmental hazard. Hierarchical systems have demonstrated their performance as environmental management tools in some US programs facing risk management at contaminated sites. In this paper basic features of the hazard Ranking System, developed by US EPA for Superfund, are described. Advantages and disadvantages are discussed and, finally, the suitability of a system similar to this is considered as a management tool for the Spanish Plan Nacional de Recuperacion de Suelos Contaminados. (Author) 9 refs.

Addition of liquid waste incineration capability to the INEL's low-level waste incinerator

International Nuclear Information System (INIS)

Steverson, E.M.; Clark, D.P.; McFee, J.N.

1986-01-01

A liquid waste system has recently been installed in the Waste Experimental Reduction Facility (WERF) incinerator at the Idaho National Engineering Laboratory (INEL). In this paper, aspects of the incineration system such as the components, operations, capabilities, capital cost, EPA permit requirements, and future plans are discussed. The principal objective of the liquid incineration system is to provide the capability to process hazardous, radioactively contaminated, non-halogenated liquid wastes. The system consists primarily of a waste feed system, instrumentation and controls, and a liquid burner, which were procured at a capital cost of $115,000

High temperature slagging incineration of hazardous waste

International Nuclear Information System (INIS)

Vanbrabant, R.; Van de Voorde, N.

1987-01-01

The SCK/CEN, as the treatment center for the low level radioactive waste in Belgium, develops appropriate treatment systems for different kinds of wastes. The technical concept of the high temperature slagging incineration system has been developed and improved. The construction of the first demonstration plant was initiated in 1974. Since then the system has been operated regularly and further developed with the view to industrial operations. Now it handles about 5 tons of waste in a week. The waste which is treated consists of low level beta/gamma and alpha-contaminated radioactive waste. Because of the special characteristics the system is thought to be an excellent incineration system for industrial hazardous waste as well. Recently the SCK/CEN has received the authorization to treat industrial hazardous waste in the same installation. Preliminary tests have been executed on special waste products, such as PCB-contaminated liquids, with excellent incineration results. Incineration efficiency up to 99.9999% could be obtained. The paper presents the state of the art of this original The SCK/CEN-technology and gives the results of the tests done with special hazard

Use of the X-Band Radar to Support the Detection of In-Flight Icing Hazards by the NASA Icing Remote Sensing System

Science.gov (United States)

Serke, David J.; Politovich, Marcia K.; Reehorst, Andrew L.; Gaydos, Andrew

2009-01-01

The Alliance Icing Research Study-II (AIRS-II) field program was conducted near Montreal, Canada during the winter of 2003. The NASA Icing Remote Detection System (NIRSS) was deployed to detect in-flight icing hazards and consisted of a vertically pointing multichannel radiometer, a ceilometer and an x-band cloud radar. The radiometer was used to derive atmospheric temperature soundings and integrated liquid water, while the ceilometer and radar were used only to define cloud boundaries. The purpose of this study is to show that the radar reflectivity profiles from AIRS-II case studies could be used to provide a qualitative icing hazard.

Hazardous waste systems analysis at Los Alamos National Laboratory

International Nuclear Information System (INIS)

Urioste, J.

1997-01-01

Los Alamos National Laboratory produces routine and non-routine hazardous waste as a by-product of mission operations. Hazardous waste commonly generated at the Laboratory includes many types of laboratory research chemicals, solvents, acids, bases, carcinogens, compressed gases, metals, and other solid waste contaminated with hazardous waste. The Los Alamos National Laboratory Environmental Stewardship Office has established a Hazardous Waste Minimization Coordinator to specifically focus on routine and non-routine RCRA, TSCA, and other administratively controlled wastes. In this process, the Waste Minimization Coordinator has developed and implemented a systems approach to define waste streams, estimate waste management costs and develop plans to implement avoidance practices, and develop projects to reduce or eliminate the waste streams at the Laboratory. The paper describes this systems approach

Mapping liquid hazardous waste migration in ground water with electromagnetic terrain conductivity measurement

International Nuclear Information System (INIS)

Ketelle, R.H.; Pin, F.G.

1984-01-01

Electromagnetic conductivity measurements were used to map apparent ground conductivity in the vicinity of a liquid hazardous waste disposal site. Approximately 600 conductivity measurements were obtained to prepare a conductivity map of the site which includes an area of 12 ha (30 acres). Conductivity measurements in the area correlate with specific conductance measurements of surface and ground water samples. Contouring of the conductivity data located contaminant migration pathways in the subsurface. A complex contaminant plume was defined by the conductivity survey. Conductivity values obtained reflected anisotropic characteristics related to local bedrock structure. Anisotropic characteristics of measurements and the use of different instrument configurations indicated semiquantitatively the depth of the high conductivity zone and the direction of flow. 4 references, 2 figures

Binary liquid-liquid equilibria of aniline-paraffin and furfural-paraffin systems

Energy Technology Data Exchange (ETDEWEB)

Sen, S.C.; Maity, S.; Ganguli, K.; Ray, P. (Calcutta Univ., (India))

1991-12-01

Liquid-liquid-equilibria (L-L-E) of hydrocarbon containing systems are of considerable commercial importance to refineries. But prediction of L-L-E of such systems is extremely difficult owing to the complex nature of the petroleum fluids. For treating such complex mixtures, a continuous component method is appropriate and for representing such liquids, a group contribution model like the UNIFAC is extremely convenient. It is, however, necessary to determine the appropriate group interaction parameters, and also to test the applicability of the UNIFAC method to these cases. Binary liquid-liquid-equilibria data for several aniline-paraffin and furfural-paraffin systems have been taken. These data along with data for other aniline-hydrocarbon and furfural-hydrocarbon systems from literature have been correlated using the UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH{sub 2} groups in cyclo and non-cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons. 13 refs., 12 figs., 5 tabs.

PEP liquid level system

International Nuclear Information System (INIS)

Lauritzen, T.; Sah, R.C.

1981-03-01

A liquid level system has been installed in the accelerator housing of the PEP storage ring. This instrument spans the entire 2.2 km circumference of the PEP project, and over one hundred readouts provide reference elevations which are used for the accurate alignment of accelerator components. The liquid level has proven to be extremely precise (+-0.10 mm) and quick to use, and it has contributed to the accurate alignment of PEP before beam turn-on. Since the liquid level readouts are rigidly attached to the accelerator housing, the liquid level has been a convenient means to monitor the settling of the accelerator housing

A RULE-BASED SYSTEM APPROACH FOR SAFETY MANAGEMENT IN HAZARDOUS WORK SYSTEMS

Directory of Open Access Journals (Sweden)

Ercüment N. DİZDAR

1998-03-01

Full Text Available Developments in technology increased the importance of safety management in work life. These improvements also resulted in a requirement of more investment and assignment on human in work systems. Here we face this problem: Can we make it possible to forecast the possible accidents that workers can face, and prevent these accidents by taking necessary precautions? In this study made, we aimed at developing an rule-based system to forecast the occupational accidents in coming periods at the departments of the facilities in hazardous work systems. The validity of the developed system was proved by implementing it into practice in hazardous work systems in manufacturing industry.

Superfund Hazard Ranking System Training Course

Science.gov (United States)

The Hazard Ranking System (HRS) training course is a four and ½ day, intermediate-level course designed for personnel who are required to compile, draft, and review preliminary assessments (PAs), site inspections (SIs), and HRS documentation records/packag

Rapid deployable global sensing hazard alert system

Science.gov (United States)

Cordaro, Joseph V; Tibrea, Steven L; Shull, Davis J; Coleman, Jerry T; Shuler, James M

2015-04-28

A rapid deployable global sensing hazard alert system and associated methods of operation are provided. An exemplary system includes a central command, a wireless backhaul network, and a remote monitoring unit. The remote monitoring unit can include a positioning system configured to determine a position of the remote monitoring unit based on one or more signals received from one or more satellites located in Low Earth Orbit. The wireless backhaul network can provide bidirectional communication capability independent of cellular telecommunication networks and the Internet. An exemplary method includes instructing at least one of a plurality of remote monitoring units to provide an alert based at least in part on a location of a hazard and a plurality of positions respectively associated with the plurality of remote monitoring units.

75 FR 4134 - Pipeline Safety: Leak Detection on Hazardous Liquid Pipelines

Science.gov (United States)

2010-01-26

... safety study on pipeline Supervisory Control and Data Acquisition (SCADA) systems (NTSB/SS-05/02). The... indications of a leak on the SCADA interface was the impetus for this study. The NTSB examined 13 hazardous... pipelines, the line balance technique for leak detection can often be performed with manual calculations...

Using an information system to meet Hazardous Waste Management needs

International Nuclear Information System (INIS)

Stewart, J.J. Jr.; Howe, R.E.; Townsend, S.L.; Maloy, D.T.; Kochhar, R.K.

1995-02-01

Lawrence Livermore National Laboratory (LLNL) is a large quantity RCRA hazardous waste generator. LLNL also generates low level and transuranic radioactive waste that is managed in accordance with the Department of Energy (DOE) orders. The mixed low level and mixed transuranic waste generated must be managed to comply with both RCRA regulations and DOE orders. LLNL's hazardous and radioactive waste generation is comprised of 900 generators who contribute to nearly two hundred waste streams. LLNL has a permitted EPA treatment and storage (TSD) facility for handling RCRA hazardous waste that is operated by LLNL's Hazardous Waste Management (HWM) division. In HWM we have developed an information system, the Total Waste Management System (TWMS), to replace an inadequate ''cradle to grave'' tracking of all the waste types described above. The goals of this system are to facilitate the safe handling and storage of these hazardous wastes, provide compliance with the regulations and serve as an informational tool to help HWM manage and dispose of these wastes in a cost effective manner

Robotics and remote systems for hazardous environments

International Nuclear Information System (INIS)

Jamshidi, M.; Eicker, P.

1993-01-01

This is the first volume in a series of books to be published by Prentice Hall on Environmental and Intelligent Manufacturing Systems. The editors have assembled an interdisciplinary collection of authors from industry, government, and academia, that provide a broad range of expertise on robotics and remote systems. Readily accessible to practicing engineers, the book provides case studies and introduces new technology applicable to remote operations in unstructured and/or hazardous environments. Chapter 1 gives an overview of the US Environmental Protection Agency's efforts to apply robotic technology to assist in the operations at hazardous waste sites. The next chapter focuses on the theory and implementation of robust impedance control for robotic manipulators. Chapter 3 presents a discussion on the integration of failure tolerance into robotic systems. The next two chapters address the issue of sensory feedback and its indispensable role in remote and/or hazardous environments. Chapter 6 presents numerous examples of robots and telemanipulators that have been applied for various tasks at the DOE's Savannah River Site. The following chapter picks up on this theme and discusses the fundamental paradigm shifts that are required in artificial intelligence for robots to deal with hazardous, unstructured, and dynamic environments. Chapter 8 returns to the issue of impedance control first raised in Chapter 2. While the majority of the applications discussed in this book are related to the nuclear industry, chapter 9 considers applying telerobotics for the control of traditional heavy machinery that is widely used in forestry, mining, and construction. The final chapter of the book returns to the topic of artificial intelligence's role in producing increased autonomy for robotic systems and provides an interesting counterpoint to the philosophy of reactive control discussed earlier

78 FR 9311 - Hazard Communication; Corrections and Technical Amendment

Science.gov (United States)

2013-02-08

....1044, Appendix Reference to ``Class IIIA combustible B. liquid'' is corrected to ``Category 4 flammable..., Fire prevention, Hazard communication, Hazardous substances, Occupational safety and health. 29 CFR... Asbestos, Construction industry, Fire prevention, Hazardous substances, Occupational safety and health...

Hazardous Solvent Substitution Data System reference manual

International Nuclear Information System (INIS)

Branham-Haar, K.A.; Twitchell, K.E.

1993-07-01

Concern for the environment, in addition to Federal regulation, mandate the replacement of hazardous solvents with safer cleaning agents. Manufacturers are working to produce these replacement solvents. As these products are developed, potential users need to be informed of their availability. To promote the use of these new products instead of traditional solvents, the Idaho National Engineering Laboratory (INEL) has developed the Hazardous Solvent Substitution Data System (HSSDS). The HSSDS provides a comprehensive system of information on alternatives to hazardous solvents and related subjects, and it makes that information available to solvent users, industrial hygienists, and process engineers. The HSSDS uses TOPIC reg-sign, a text retrieval system produced by Verity, Inc., to allow a user to search for information on a particular subject. TOPIC reg-sign produces a listing of the retrieved documents and allows the use to examine the documents individually and to use the information contained in them. This reference manual does not replace the comprehensive TOPIC reg-sign user documentation (available from Verity, Inc.), or the HSSDS Tutorial (available from the INEL). The purpose of this reference manual is to provide enough instruction on TOPIC reg-sign so the user may begin accessing the data contained in the HSSDS

Probabilistic Approaches for Multi-Hazard Risk Assessment of Structures and Systems

Science.gov (United States)

Kwag, Shinyoung

Performance assessment of structures, systems, and components for multi-hazard scenarios has received significant attention in recent years. However, the concept of multi-hazard analysis is quite broad in nature and the focus of existing literature varies across a wide range of problems. In some cases, such studies focus on hazards that either occur simultaneously or are closely correlated with each other. For example, seismically induced flooding or seismically induced fires. In other cases, multi-hazard studies relate to hazards that are not dependent or correlated but have strong likelihood of occurrence at different times during the lifetime of a structure. The current approaches for risk assessment need enhancement to account for multi-hazard risks. It must be able to account for uncertainty propagation in a systems-level analysis, consider correlation among events or failure modes, and allow integration of newly available information from continually evolving simulation models, experimental observations, and field measurements. This dissertation presents a detailed study that proposes enhancements by incorporating Bayesian networks and Bayesian updating within a performance-based probabilistic framework. The performance-based framework allows propagation of risk as well as uncertainties in the risk estimates within a systems analysis. Unlike conventional risk assessment techniques such as a fault-tree analysis, a Bayesian network can account for statistical dependencies and correlations among events/hazards. The proposed approach is extended to develop a risk-informed framework for quantitative validation and verification of high fidelity system-level simulation tools. Validation of such simulations can be quite formidable within the context of a multi-hazard risk assessment in nuclear power plants. The efficiency of this approach lies in identification of critical events, components, and systems that contribute to the overall risk. Validation of any event or

Liquid Effluent Monitoring Information System (LEMIS) System Construction

International Nuclear Information System (INIS)

Adams, R.T.

1994-01-01

The liquid effluent sampling program is part of the effort to minimize adverse environmental impact during the cleanup operation at the Hanford Site. Of the 33 Phase I and Phase II liquid effluents, all streams actively discharged to the soil column will be sampled. The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Construction document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

Investigating the presence of hazardous materials in buildings

International Nuclear Information System (INIS)

Gustitus, D.A.; Blaisdell, P.M.

1996-01-01

Environmental hazards in buildings can be found in the air, on exposed surfaces, or hidden in roofs, walls, and systems. They can exist in buildings in solid, liquid, and gaseous states. A sound methodology for investigating the presence of environmental hazards in buildings should include several components. The first step in planning an investigation of environmental hazards in buildings is to ascertain why the investigation is to be performed. Research should be performed to review available documentation on the building. Next, a visual inspection of the building should be performed to identify and document existing conditions, and all suspect materials containing environmental hazards. Lastly, samples of suspect materials should be collected for testing. It is important to sample appropriate materials, based on the information obtained during the previous steps of the investigation. It is also important to collect the samples using standard procedures. Pollutants of concern include asbestos, lead, PCBs, and radon

Learn about the Hazardous Waste Electronic Manifest System (e-Manifest)

Science.gov (United States)

This webpage provides information on EPA's work toward developing a hazardous waste electronic manifest system. Information on the Hazardous Waste Electronic Manifest Establishment Act, progress on the project and frequent questions are available.

Use of electromagnetic terrain conductivity measurements to map liquid hazardous waste migration in groundwater

International Nuclear Information System (INIS)

Ketelle, R.H.; Pin, F.G.

1983-11-01

Electromagnetic conductivity measurements have been used to map apparent ground conductivity in the vicinity of a liquid hazardous waste disposal site. An area of approximately 12 ha (30 acres) was surveyed. Approximately 600 conductivity measurements were obtained to prepare a conductivity map of the site. Conductivity measurments in the area correlate with specific conductance measurements of surface and groundwater samples. Contouring of the conductivity data showed the precise location of contaminant migration pathways in the subsurface. A complex contaminant plume was defined by the conductivity survey. Conductivity values obtained reflected anisotropic characteristics related to local bedrock structure. Anisotropy characteristics and the use of different instrument configurations indicated semiquantitatively the depth of the high conductivity zone and the direction of flow

Detection based on rainbow refractometry of droplet sphericity in liquid-liquid systems.

Science.gov (United States)

Lohner, H; Lehmann, P; Bauckhage, K

1999-03-01

The shape of droplets in liquid-liquid systems influences their mass and momentum transfer processes. The deviation from sphericity of rising droplets in liquid-liquid systems was investigated for different droplet sizes. Rainbow refractometry permits one to test, in this case, whether the use of laser-optical particle sizing will be correct or faulty. Since the assumption of spherical particle geometry is a general basis of laser-optical particle-sizing techniques such as rainbow refractometry or phase Doppler anemometry, deviation from the spherical shape results in a measuring error. A sphericity check based on rainbow refractometry is introduced.

Development of a Liquid Scintillator-Based Active Interrogation System for LEU Fuel Assemblies

International Nuclear Information System (INIS)

Lavietes, Anthony D.; Plenteda, Romano; Mascahrenas, Nicholas; Cronholm, L. Marie; Aspinall, Michael; Joyce, Malcolm; Tomanin, Alice; Peerani, Paolo

2013-06-01

The IAEA, in collaboration with the Joint Research Center (Ispra, IT) and Hybrid Instruments (Lancaster, UK), has developed a full scale, liquid scintillator-based active interrogation system to determine uranium (U) mass in fresh fuel assemblies. The system implements an array of moderate volume (∼1000 ml) liquid scintillator detectors, a multichannel pulse shape discrimination (PSD) system, and a high-speed data acquisition and signal processing system to assess the U content of fresh fuel assemblies. Extensive MCNPX-PoliMi modelling has been carried out to refine the system design and optimize the detector performance. These measurements, traditionally performed with 3 He-based assay systems (e.g., Uranium Neutron Coincidence Collar [UNCL], Active Well Coincidence Collar [AWCC]), can now be performed with higher precision in a fraction of the acquisition time. The system uses a high-flash point, non-hazardous scintillating fluid (EJ309) enabling their use in commercial nuclear facilities and achieves significantly enhanced performance and capabilities through the combination of extremely short gate times, adjustable energy detection threshold, real-time PSD electronics, and high-speed, FPGA-based data acquisition. Given the possible applications, this technology is also an excellent candidate for the replacement of select 3 He-based systems. Comparisons to existing 3 He-based active interrogation systems are presented where possible to provide a baseline performance reference. This paper will describe the laboratory experiments and associated modelling activities undertaken to develop and initially test the prototype detection system. (authors)

Kinetics of glycoalkaloid hydrolysis and solanidine extraction in liquid-liquid systems

Directory of Open Access Journals (Sweden)

Stanković Mihajlo Z.

2002-01-01

Full Text Available The kinetics of glycoalkaloid hydrolysis and solanidine extraction in Analyzed in this study. obtained from dried and milled potato haulm to to which hydrochlotic acid was added is the first liquid phase, while chloroform trichloroethylene or carbon tetrachlondeisthe second organic, liquid phase. The purpose of this paper was to combine the processes of glycoalkaloid hydrolysis to solanidine and solanidine extraction into one step, and to find the optimal liquid-liquid system for such a process.

Management, treatment and final disposal of solid hazardous hospital wastes

International Nuclear Information System (INIS)

Sebiani Serrano, T.

2000-01-01

Medical Waste is characterized by its high risk to human health and the environment. The main risk is biological, due to the large amount of biologically contaminated materials present in such waste. However, this does not mean that the chemical and radioactive wastes are less harmful just because they represent a smaller part of the total waste. Hazardous wastes from hospitals can be divided in 3 main categories: Solid Hazardous Hospital Wastes (S.H.H.W.), Liquid Hazardous Hospital Wastes (L.H.H.W.) and Gaseous Hazardous Hospital Wastes (G.H.H.W.) Most gaseous and liquid hazardous wastes are discharged to the environment without treatment. Since this inappropriate disposal practice, however, is not visible to society, there is no societal reaction to such problem. On the contrary, hazardous solid wastes (S.H.H.W.) are visible to society and create worries in the population. As a result, social and political pressures arise, asking for solutions to the disposal problems of such wastes. In response to such pressures and legislation approved by Costa Rica on waste handling and disposal, the Caja Costarricense de Seguro Social developed a plan for the handling, treatment, and disposal of hazardous solid wastes at the hospitals and clinics of its system. The objective of the program is to reduce the risk to society of such wastes. In this thesis a cost-effectiveness analysis was conducted to determine the minimum cost at which it is possible to reach a maximum level of reduction in hazardous wastes, transferring to the environment the least possible volume of solid hazardous wastes, and therefore, reducing risk to a minimum. It was found that at the National Children's Hospital the internal handling of hazard solid wastes is conducted with a high level of effectiveness. However, once out of the hospital area, the handling is not effective, because hazardous and common wastes are all mixed together creating a larger amount of S.H.H.W. and reducing the final efficiency

Liquid Level Sensing System

Science.gov (United States)

Korman, Valentin (Inventor); Wiley, John T. (Inventor); Duffell, Amanda G. (Inventor)

2014-01-01

A liquid level sensing system includes waveguides disposed in a liquid and distributed along a path with a gap between adjacent waveguides. A source introduces electromagnetic energy into the waveguides at a first end of the path. A portion of the electromagnetic energy exits the waveguides at a second end of the path. A detector measures the portion of the electromagnetic energy exiting the second end of the path.

Cryogenic system for liquid hydrogen polarimeter

International Nuclear Information System (INIS)

Kitami, T.; Chiba, M.; Hirabayashi, H.; Ishii, T.; Kato, S.

1979-01-01

A cryogenic system has been constructed for a liquid hydrogen polarimeter in order to measure polarization of high energy proton at the 1.3 GeV electron synchrotron of Institute for Nuclear Study, University of Tokyo. The system principally consists of a cryogenerator with a cryogenic transfer line, a liquid hydrogen cryostat, and a 14.5 l target container of thin aluminum alloy where liquid hydrogen is served for the experiment. The refrigeration capacity is about 54 W at 20.4 K without a target container. (author)

Practicality for Software Hazard Analysis for Nuclear Safety I and C System

International Nuclear Information System (INIS)

Kim, Yong-Ho; Moon, Kwon-Ki; Chang, Young-Woo; Jeong, Soo-Hyun

2016-01-01

We are using the concept of system safety in engineering. It is difficult to make any system perfectly safe and probably a complete system may not easily be achieved. The standard definition of a system from MIL-STD- 882E is: “The organization of hardware, software, material, facilities, personnel, data, and services needed to perform a designated function within a stated environment with specified results.” From the perspective of the system safety engineer and the hazard analysis process, software is considered as a subsystem. Regarding hazard analysis, to date, methods for identifying software failures and determining their effects is still a research problem. Since the success of software development is based on rigorous test of hardware and software, it is necessary to check the balance between software test and hardware test, and in terms of efficiency. Lessons learned and experience from similar systems are important for the work of hazard analysis. No major hazard has been issued for the software developed and verified in Korean NPPs. In addition to hazard analysis, software development, and verification and validation were thoroughly performed. It is reasonable that the test implementation including the development of the test case, stress and abnormal conditions, error recovery situations, and high risk hazardous situations play a key role in detecting and preventing software faults

Practicality for Software Hazard Analysis for Nuclear Safety I and C System

Energy Technology Data Exchange (ETDEWEB)

Kim, Yong-Ho; Moon, Kwon-Ki; Chang, Young-Woo; Jeong, Soo-Hyun [KEPCO Engineering and Construction Co., Deajeon (Korea, Republic of)

2016-10-15

We are using the concept of system safety in engineering. It is difficult to make any system perfectly safe and probably a complete system may not easily be achieved. The standard definition of a system from MIL-STD- 882E is: “The organization of hardware, software, material, facilities, personnel, data, and services needed to perform a designated function within a stated environment with specified results.” From the perspective of the system safety engineer and the hazard analysis process, software is considered as a subsystem. Regarding hazard analysis, to date, methods for identifying software failures and determining their effects is still a research problem. Since the success of software development is based on rigorous test of hardware and software, it is necessary to check the balance between software test and hardware test, and in terms of efficiency. Lessons learned and experience from similar systems are important for the work of hazard analysis. No major hazard has been issued for the software developed and verified in Korean NPPs. In addition to hazard analysis, software development, and verification and validation were thoroughly performed. It is reasonable that the test implementation including the development of the test case, stress and abnormal conditions, error recovery situations, and high risk hazardous situations play a key role in detecting and preventing software faults.

Hazardous constituent source term. Revision 2

International Nuclear Information System (INIS)

1994-01-01

The Department of Energy (DOE) has several facilities that either generate and/or store transuranic (TRU)-waste from weapons program research and production. Much of this waste also contains hazardous waste constituents as regulated under Subtitle C of the Resource Conservation and Recovery Act (RCRA). Toxicity characteristic metals in the waste principally include lead, occurring in leaded rubber gloves and shielding. Other RCRA metals may occur as contaminants in pyrochemical salt, soil, debris, and sludge and solidified liquids, as well as in equipment resulting from decontamination and decommissioning activities. Volatile organic compounds (VOCS) contaminate many waste forms as a residue adsorbed on surfaces or occur in sludge and solidified liquids. Due to the presence of these hazardous constituents, applicable disposal regulations include land disposal restrictions established by Hazardous and Solid Waste Amendments (HSWA). The DOE plans to dispose of TRU-mixed waste from the weapons program in the Waste Isolation Pilot Plant (WIPP) by demonstrating no-migration of hazardous constituents. This paper documents the current technical basis for methodologies proposed to develop a post-closure RCRA hazardous constituent source term. For the purposes of demonstrating no-migration, the hazardous constituent source term is defined as the quantities of hazardous constituents that are available for transport after repository closure. Development of the source term is only one of several activities that will be involved in the no-migration demonstration. The demonstration will also include uncertainty and sensitivity analyses of contaminant transport

Preliminary hazards analysis of thermal scrap stabilization system. Revision 1

International Nuclear Information System (INIS)

Lewis, W.S.

1994-01-01

This preliminary analysis examined the HA-21I glovebox and its supporting systems for potential process hazards. Upon further analysis, the thermal stabilization system has been installed in gloveboxes HC-21A and HC-21C. The use of HC-21C and HC-21A simplified the initial safety analysis. In addition, these gloveboxes were cleaner and required less modification for operation than glovebox HA-21I. While this document refers to glovebox HA-21I for the hazards analysis performed, glovebox HC-21C is sufficiently similar that the following analysis is also valid for HC-21C. This hazards analysis document is being re-released as revision 1 to include the updated flowsheet document (Appendix C) and the updated design basis (Appendix D). The revised Process Flow Schematic has also been included (Appendix E). This Current revision incorporates the recommendations provided from the original hazards analysis as well. The System Design Description (SDD) has also been appended (Appendix H) to document the bases for Safety Classification of thermal stabilization equipment

Liquid over-feeding air conditioning system and method

Science.gov (United States)

Mei, Viung C.; Chen, Fang C.

1993-01-01

A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

Experimental measurement and prediction of (liquid + liquid + liquid) equilibrium for the system (n-hexadecane + water + triacetin)

International Nuclear Information System (INIS)

Revellame, Emmanuel D.; Holmes, William E.; Hernandez, Rafael; French, W. Todd; Forks, Allison; Ashe, Taylor; Estévez, L. Antonio

2016-01-01

Highlights: • Phase diagram for the system n-hexadecane + water + triacetin was established at T = 296.15 K and atmospheric pressure (0.1 MPa). • Both NRTL and UNIQUAC activity coefficient model adequately predicts the LLLE of the ternary system. • The phase equilibrium of the system is predominantly dictated by enthalpic contributions to the activity coefficient. - Abstract: The phase diagram for the ternary system containing (n-hexadecane + water + triacetin) was obtained experimentally at T = 296.15 K and ambient pressure. Results show that this system is of Type 3 according to the Treybal classification of ternary system. NRTL and UNIQUAC interaction parameters were calculated from binary phase equilibrium values and were used to predict the (liquid + liquid + liquid) equilibrium (LLLE) region. Results indicated that both NRTL and UNIQUAC could predict the LLLE region of the system with similar precision as indicated by the comparable standard deviations. This indicates that the enthalpic contribution to the activity coefficient is predominant and entropic contributions can be neglected.

National information network and database system of hazardous waste management in China

Energy Technology Data Exchange (ETDEWEB)

Ma Hongchang [National Environmental Protection Agency, Beijing (China)

1996-12-31

Industries in China generate large volumes of hazardous waste, which makes it essential for the nation to pay more attention to hazardous waste management. National laws and regulations, waste surveys, and manifest tracking and permission systems have been initiated. Some centralized hazardous waste disposal facilities are under construction. China`s National Environmental Protection Agency (NEPA) has also obtained valuable information on hazardous waste management from developed countries. To effectively share this information with local environmental protection bureaus, NEPA developed a national information network and database system for hazardous waste management. This information network will have such functions as information collection, inquiry, and connection. The long-term objective is to establish and develop a national and local hazardous waste management information network. This network will significantly help decision makers and researchers because it will be easy to obtain information (e.g., experiences of developed countries in hazardous waste management) to enhance hazardous waste management in China. The information network consists of five parts: technology consulting, import-export management, regulation inquiry, waste survey, and literature inquiry.

Management and hazardous waste characterization in Central for Isotop and Radiation Application based on potential dangers

International Nuclear Information System (INIS)

Niken Hayudanti Anggarini; Megi Stefanus; Prihatiningsih

2014-01-01

Separating and storing hazardous waste have been done based on the physical, chemical, and based on potential dangers due to safety hazardous waste temporary storage warehouse. From the results of data collection in 2014 found that the most dominant hazardous waste is organic liquid waste which reaches 61 %, followed by inorganic liquid waste 33 % while organic solid waste and inorganic solid waste has a small portion. When viewed from potential danger, flammable liquid waste has the greatest volume percentage it is 47 % and is followed by a corrosive liquid waste 26 %, while the liquid waste that has not been identified is quite large, which is 9 %. From the highest hazard potential data, hazardous waste storage warehouse is required to have good air circulation and waste storage shelf protected from direct solar heat. Cooperation of lab workers and researchers are also indispensable in providing identification of each waste generated to facilitate the subsequent waste management. (author)

Liquid over-feeding air conditioning system and method

Science.gov (United States)

Mei, V.C.; Chen, F.C.

1993-09-21

A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

Application of systems and control theory-based hazard analysis to radiation oncology.

Science.gov (United States)

Pawlicki, Todd; Samost, Aubrey; Brown, Derek W; Manger, Ryan P; Kim, Gwe-Ya; Leveson, Nancy G

2016-03-01

Both humans and software are notoriously challenging to account for in traditional hazard analysis models. The purpose of this work is to investigate and demonstrate the application of a new, extended accident causality model, called systems theoretic accident model and processes (STAMP), to radiation oncology. Specifically, a hazard analysis technique based on STAMP, system-theoretic process analysis (STPA), is used to perform a hazard analysis. The STPA procedure starts with the definition of high-level accidents for radiation oncology at the medical center and the hazards leading to those accidents. From there, the hierarchical safety control structure of the radiation oncology clinic is modeled, i.e., the controls that are used to prevent accidents and provide effective treatment. Using STPA, unsafe control actions (behaviors) are identified that can lead to the hazards as well as causal scenarios that can lead to the identified unsafe control. This information can be used to eliminate or mitigate potential hazards. The STPA procedure is demonstrated on a new online adaptive cranial radiosurgery procedure that omits the CT simulation step and uses CBCT for localization, planning, and surface imaging system during treatment. The STPA procedure generated a comprehensive set of causal scenarios that are traced back to system hazards and accidents. Ten control loops were created for the new SRS procedure, which covered the areas of hospital and department management, treatment design and delivery, and vendor service. Eighty three unsafe control actions were identified as well as 472 causal scenarios that could lead to those unsafe control actions. STPA provides a method for understanding the role of management decisions and hospital operations on system safety and generating process design requirements to prevent hazards and accidents. The interaction of people, hardware, and software is highlighted. The method of STPA produces results that can be used to improve

Global early warning systems for natural hazards: systematic and people-centred.

Science.gov (United States)

Basher, Reid

2006-08-15

To be effective, early warning systems for natural hazards need to have not only a sound scientific and technical basis, but also a strong focus on the people exposed to risk, and with a systems approach that incorporates all of the relevant factors in that risk, whether arising from the natural hazards or social vulnerabilities, and from short-term or long-term processes. Disasters are increasing in number and severity and international institutional frameworks to reduce disasters are being strengthened under United Nations oversight. Since the Indian Ocean tsunami of 26 December 2004, there has been a surge of interest in developing early warning systems to cater to the needs of all countries and all hazards.

Ranking system for mixed radioactive and hazardous waste sites

International Nuclear Information System (INIS)

Hawley, K.A.; Napier, B.A.

1985-01-01

The Environmental Protection Agency's Hazard Ranking System (HRS) is a simplified management decision tool that provides a common basis for evaluating a multitude of hazardous waste sites. A deficiency in the HRS for application to Department of Energy mixed radioactive and hazardous waste sites is its inability to explicitly handle radioactive material. A modification to the basic HRS to add the capability to consider radioactivity is described. The HRS considers the exposure routes of direct contact, fire/explosion, atmospheric release, surface-water release, and ground-water release. Each exposure route is further divided into release, route, containment, waste, and target characteristics. To maintain the basic HRS structure, only the waste characteristics section of each exposure route was modified. A ranking system was developed, using radiation dose pathway analysis, to group radionuclides by dose factors. For mixed waste sites, the ranking factor derived for radionuclides is compared with the ranking factor obtained for hazardous chemicals and the most restrictive is used in the overall ranking. The modified HRS has the advantages of being compatible with the original HRS, has reasonable information requirements, and provides scientifically defensible conclusions. 17 references, 2 figures, 6 tables

INEL RCRA [Resource Conservation and Recovery Act] permit for incineration of hazardous waste: Status report

International Nuclear Information System (INIS)

McFee, J.N.; Dalton, J.D.; Bohrer, H.A.

1987-01-01

The Waste Experimental Reduction Facility (WERF) was constructed to reduce the volume of low-level radioactive waste at the Idaho National Engineering Laboratory (INEL). To address the problem of radioactively contaminated ignitable hazardous waste resulting from INEL activities, a development program was carried out to evaluate WERF's ability to meet the regulated criteria for incinerating liquid and solid ignitable waste. Concurrently, INEL submitted its hazardous waste Part B application under the Resource Conservation and Recovery Act (RCRA). As required, and as a major step in the permitting process, the WERF incinerator portion of the permit application included a proposed trial burn, which is a demonstration test of the incinerator's ability to destroy hazardous materials. The trial burn plan was designed to demonstrate the system performance for liquid and solid ignitable wastes at three operating conditions, using a prepared mix of materials representative of waste to be processed. EPA Region X reviewed and commented on the plan prior to the trial burn. Results of the liquid feed trial burn showed a greater than 97% probability of meeting the RCRA-dictated DRE value for chlorinated solvents and a greater than 99% probability for nonchlorinated solvents. Nonchlorinated solid waste results were calculated at a 93% probability of meeting the required DRE, with a 75% probability for chlorinated solid wastes. In addition, the incinerator DRE continued to improve long after the assumed pre-test equilibrium period had ended. The trial burn demonstrates that the WERF incinerator can safely and adequately destroy ignitable hazardous and mixed waste and provides a significant enhancement of the INEL's waste management system

ODH, oxygen deficiency hazard cryogenic analysis

International Nuclear Information System (INIS)

Augustynowicz, S.D.

1994-01-01

An oxygen deficiency exists when the concentration of oxygen, by volume, drops to a level at which atmosphere supplying respiratory protection must be provided. Since liquid cryogens can expand by factors of 700 (LN 2 ) to 850 (LH e ), the uncontrolled release into an enclosed space can easily cause an oxygen-deficient condition. An oxygen deficiency hazard (ODH) fatality rate per hour (OE) is defined as: OE = Σ N i P i F i , where N i = number of components, P i = probability of failure or operator error, and F i = fatality factor. ODHs range from open-quotes unclassifiedclose quotes (OE -9 1/h) to class 4, which is the most hazardous (OE>10 -1 1/h). For Superconducting Super Collider Laboratory (SSCL) buildings where cryogenic systems exist, failure rate, fatality factor, reduced oxygen ratio, and fresh air circulation are examined

The Bevatron liquid nitrogen circulation system

International Nuclear Information System (INIS)

Hunt, D.; Stover, G.

1987-03-01

A nitrogen liquefier and computer controlled valving system have been added to the Bevatron cryoliner vacuum system to cut operating costs by reducing liquid nitrogen consumption. The computer and interface electronic systems, which control the temperatures of twenty-eight liquid nitrogen circuits, have been chosen and designed to operate in the Bevatron's pulsating magnetic field. The nitrogen exhaust is routed back to a liquefier, of about five kilowatt capacity, liquefied, and rerouted through the cooling circuits. A description of the system and operating results are presented

On the hazard rate process for imperfectly monitored multi-unit systems

International Nuclear Information System (INIS)

Barros, A.; Berenguer, C.; Grall, A.

2005-01-01

The aim of this paper is to present a stochastic model to characterize the failure distribution of multi-unit systems when the current units state is imperfectly monitored. The definition of the hazard rate process existing with perfect monitoring is extended to the realistic case where the units failure time are not always detected (non-detection events). The so defined observed hazard rate process gives a better representation of the system behavior than the classical failure rate calculated without any information on the units state and than the hazard rate process based on perfect monitoring information. The quality of this representation is, however, conditioned by the monotony property of the process. This problem is mainly discussed and illustrated on a practical example (two parallel units). The results obtained motivate the use of the observed hazard rate process to characterize the stochastic behavior of the multi-unit systems and to optimize for example preventive maintenance policies

On the hazard rate process for imperfectly monitored multi-unit systems

Energy Technology Data Exchange (ETDEWEB)

Barros, A. [Institut des Sciences et Techonologies de l' Information de Troyes (ISTIT-CNRS), Equipe de Modelisation et Surete des Systemes, Universite de Technologie de Troyes (UTT), 12, rue Marie Curie, BP2060, 10010 Troyes cedex (France)]. E-mail: anne.barros@utt.fr; Berenguer, C. [Institut des Sciences et Techonologies de l' Information de Troyes (ISTIT-CNRS), Equipe de Modelisation et Surete des Systemes, Universite de Technologie de Troyes (UTT), 12, rue Marie Curie, BP2060, 10010 Troyes cedex (France); Grall, A. [Institut des Sciences et Techonologies de l' Information de Troyes (ISTIT-CNRS), Equipe de Modelisation et Surete des Systemes, Universite de Technologie de Troyes (UTT), 12, rue Marie Curie, BP2060, 10010 Troyes cedex (France)

2005-12-01

The aim of this paper is to present a stochastic model to characterize the failure distribution of multi-unit systems when the current units state is imperfectly monitored. The definition of the hazard rate process existing with perfect monitoring is extended to the realistic case where the units failure time are not always detected (non-detection events). The so defined observed hazard rate process gives a better representation of the system behavior than the classical failure rate calculated without any information on the units state and than the hazard rate process based on perfect monitoring information. The quality of this representation is, however, conditioned by the monotony property of the process. This problem is mainly discussed and illustrated on a practical example (two parallel units). The results obtained motivate the use of the observed hazard rate process to characterize the stochastic behavior of the multi-unit systems and to optimize for example preventive maintenance policies.

Liquid-liquid phase transition and glass transition in a monoatomic model system.

Science.gov (United States)

Xu, Limei; Buldyrev, Sergey V; Giovambattista, Nicolas; Stanley, H Eugene

2010-01-01

We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System

Directory of Open Access Journals (Sweden)

Nicolas Giovambattista

2010-12-01

Full Text Available We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

Boiling water reactor liquid radioactive waste processing system

International Nuclear Information System (INIS)

Anon.

1977-01-01

The standard sets forth minimum design, construction and performance requirements with due consideration for operation of the liquid radioactive waste processing system for boiling water reactor plants for routine operation including design basis fuel leakage and design basis occurrences. For the purpose of this standard, the liquid radioactive waste processing system begins at the interfaces with the reactor coolant pressure boundary, at the interface valve(s) in lines from other systems and at those sumps and floor drains provided for liquid waste with the potential of containing radioactive material. The system terminates at the point of controlled discharge to the environment, at the point of interface with the waste solidification system and at the point of recycle back to storage for reuse. The standard does not include the reactor coolant clean-up system, fuel pool clean-up system, sanitary waste system, any nonaqueous liquid system or controlled area storm drains

Water-saving liquid-gas conditioning system

Science.gov (United States)

Martin, Christopher; Zhuang, Ye

2014-01-14

A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

Systemic Liquidity Shocks and Banking Sector Liquidity Characteristics on the Eve of Liquidity Coverage Ratio Application - The Case of the Czech Republic1

Directory of Open Access Journals (Sweden)

Brůna Karel

2016-01-01

Full Text Available The paper contains an analysis of the economic and regulatory concept of bank liquidity in the context of systemic liquidity shock. A formal model analysis shows that the application of liquidity coverage ratio (LCR based on Basel III will lead to a significant adaptation of banks liquidity management. LCR causes a change in bank’s liquidity allocation and funding to be less effective and more costly and restrictive for providing credits comparing with economic determinants. It is demonstrated that the application of LCR underestimates actual liquidity position of a bank and leads to allocation ineffectiveness. The empirical part contains simulation of impacts of systemic liquidity shock on the banking sector’s ability to withstand the unfavourable credit shock while solvency is maintained. The results confirm the robustness of the Czech banking system ensuing from the systemic surplus of liquidity, high volume of bank capital and its high profitability. The estimations of the VAR model show that the relations between liquidity characteristics of banks, sources of aggregate liquidity shock, interbank market illiquidity and the credit facilities of the Czech National Bank are relatively weak, supporting the conclusion that the banks face liquidity shocks of non-persistent character.

Hazardous-materials-management system: a guide for local emergency managers

International Nuclear Information System (INIS)

Lee, M.T.; Roe, P.G.

1981-07-01

An increase in the manufacture, storage, and transportation of hazardous materials is occurring across the nation. Local jurisdictions have realized that they have the responsibility to assure a reasonable level of safety to their community members and visitors alike. Such a responsibility can be met by developing methods of preventing hazardous materials incidents; enforcing laws related to transporting and storing hazardous materials; the initiating of an appropriate first response, and activating available resources of government agencies and commercial organizations that deal with containment and cleanup. This manual has been written to help in the development of a total Hazardous Material Management System. The manual describes one approach but allows for variations as may be appropriate for the specific jurisdiction

Preliminary fire hazards analysis for W-211, Initial Tank Retrieval Systems

International Nuclear Information System (INIS)

Huckfeldt, R.A.

1995-01-01

A fire hazards analysis (FHA) was performed for Project W-211, Initial Tank Retrieval System (ITRS), at the Department of Energy (DOE) Hanford site. The objectives of this FHA was to determine (1) the fire hazards that expose the Initial Tank Retrieval System or are inherent in the process, (2) the adequacy of the fire-safety features planned, and (3) the degree of compliance of the project with specific fire safety provisions in DOE orders and related engineering codes and standards. The scope included the construction, the process hazards, building fire protection, and site wide fire protection. The results are presented in terms of the fire hazards present, the potential extent of fire damage, and the impact on employees and public safety. This study evaluated the ITRS with respect to its use at Tank 241-SY-101 only

Controlled air incineration of hazardous chemical waste at the Los Alamos National Laboratory

International Nuclear Information System (INIS)

Stretz, L.A.; Borduin, L.C.; Draper, W.E.; Koenig, R.A.; Vavruska, J.S.

1982-01-01

An incineration system, originally demonstrated as a transuranic (TRU) waste volume-reduction process, is described. The production-scale controlled air incinerator using commercially available equipment and technology was modified for solid radioactive waste service. The same incinerator and offgas treatment system has been modified further for use in evaluating the destruction of hazardous liquid wastes such as polychlorinated biphenyls (PCBs) and hazardous solid wastes such as pentachlorophenol (PCP)-treated wood. Results of a PCP-treated wood incineration test show a PCP destruction efficiency of greater than 99.99% in the primary chamber for the operating conditions investigated. Conditions and results for this test are described

Systems and methods for analyzing liquids under vacuum

Science.gov (United States)

Yu, Xiao-Ying; Yang, Li; Cowin, James P.; Iedema, Martin J.; Zhu, Zihua

2013-10-15

Systems and methods for supporting a liquid against a vacuum pressure in a chamber can enable analysis of the liquid surface using vacuum-based chemical analysis instruments. No electrical or fluid connections are required to pass through the chamber walls. The systems can include a reservoir, a pump, and a liquid flow path. The reservoir contains a liquid-phase sample. The pump drives flow of the sample from the reservoir, through the liquid flow path, and back to the reservoir. The flow of the sample is not substantially driven by a differential between pressures inside and outside of the liquid flow path. An aperture in the liquid flow path exposes a stable portion of the liquid-phase sample to the vacuum pressure within the chamber. The radius, or size, of the aperture is less than or equal to a critical value required to support a meniscus of the liquid-phase sample by surface tension.

A smartphone controlled handheld microfluidic liquid handling system.

Science.gov (United States)

Li, Baichen; Li, Lin; Guan, Allan; Dong, Quan; Ruan, Kangcheng; Hu, Ronggui; Li, Zhenyu

2014-10-21

Microfluidics and lab-on-a-chip technologies have made it possible to manipulate small volume liquids with unprecedented resolution, automation and integration. However, most current microfluidic systems still rely on bulky off-chip infrastructures such as compressed pressure sources, syringe pumps and computers to achieve complex liquid manipulation functions. Here, we present a handheld automated microfluidic liquid handling system controlled by a smartphone, which is enabled by combining elastomeric on-chip valves and a compact pneumatic system. As a demonstration, we show that the system can automatically perform all the liquid handling steps of a bead-based HIV1 p24 sandwich immunoassay on a multi-layer PDMS chip without any human intervention. The footprint of the system is 6 × 10.5 × 16.5 cm, and the total weight is 829 g including battery. Powered by a 12.8 V 1500 mAh Li battery, the system consumed 2.2 W on average during the immunoassay and lasted for 8.7 h. This handheld microfluidic liquid handling platform is generally applicable to many biochemical and cell-based assays requiring complex liquid manipulation and sample preparation steps such as FISH, PCR, flow cytometry and nucleic acid sequencing. In particular, the integration of this technology with read-out biosensors may help enable the realization of the long-sought Tricorder-like handheld in vitro diagnostic (IVD) systems.

Application of a Novel Liquid Nitrogen Control Technique for Heat Stress and Fire Prevention in Underground Mines.

Science.gov (United States)

Shi, Bobo; Ma, Lingjun; Dong, Wei; Zhou, Fubao

2015-01-01

With the continually increasing mining depths, heat stress and spontaneous combustion hazards in high-temperature mines are becoming increasingly severe. Mining production risks from natural hazards and exposures to hot and humid environments can cause occupational diseases and other work-related injuries. Liquid nitrogen injection, an engineering control developed to reduce heat stress and spontaneous combustion hazards in mines, was successfully utilized for environmental cooling and combustion prevention in an underground mining site named "Y120205 Working Face" (Y120205 mine) of Yangchangwan colliery. Both localized humidities and temperatures within the Y120205 mine decreased significantly with liquid nitrogen injection. The maximum percentage drop in temperature and humidity of the Y120205 mine were 21.9% and 10.8%, respectively. The liquid nitrogen injection system has the advantages of economical price, process simplicity, energy savings and emission reduction. The optimized heat exchanger used in the liquid nitrogen injection process achieved superior air-cooling results, resulting in considerable economic benefits.

Studies for the requirements of automatic and remotely controlled shutoff valves on hazardous liquids and natural gas pipelines with respect to public and environmental safety

Energy Technology Data Exchange (ETDEWEB)

Oland, C. Barry [XCEL Engineering, Inc. (United States); Rose, Simon D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering Science and Technology Div.; Grant, Herb L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Fabrication, Hoisting and Rigging Div.; Lower, Mark D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Fabrication, Hoisting and Rigging Div.; Spann, Mark A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Facility Management Div.; Kirkpatrick, John R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Computational Sciences and Engineering Div.; Sulfredge, C. David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Computational Sciences and Engineering Div.

2012-12-01

This study assesses the effectiveness of block valve closure swiftness in mitigating the consequences of natural gas and hazardous liquid pipeline releases on public and environmental safety. It also evaluates the technical, operational, and economic feasibility and potential cost benefits of installing automatic shutoff valves (ASVs) and remote control valves (RCVs) in newly constructed and fully replaced transmission lines. Risk analyses of hypothetical pipeline release scenarios are used as the basis for assessing: (1) fire damage to buildings and property in Class 1, Class 2, Class 3, and Class 4 high consequence areas (HCAs) caused by natural gas pipeline releases and subsequent ignition of the released natural gas; (2) fire damage to buildings and property in HCAs designated as high population areas and other populated areas caused by hazardous liquid pipeline releases and subsequent ignition of the released propane; and (3) socioeconomic and environmental damage in HCAs caused by hazardous liquid pipeline releases of crude oil. These risk analyses use engineering principles and fire science practices to characterize thermal radiation effects on buildings and humans and to quantify the total damage cost of socioeconomic and environmental impacts. The risk analysis approach used for natural gas pipelines is consistent with risk assessment standards developed by industry and incorporated into Federal pipeline safety regulations. Feasibility evaluations for the hypothetical pipeline release scenarios considered in this study show that installation of ASVs and RCVs in newly constructed and fully replaced natural gas and hazardous liquid pipelines is technically, operationally, and economically feasible with a positive cost benefit. However, these results may not apply to all newly constructed and fully replaced pipelines because site-specific parameters that influence risk analyses and feasibility evaluations often vary significantly from one pipeline segment to

Liquid level control system for vapour generator

International Nuclear Information System (INIS)

Singh, G.

1984-01-01

A system for regulating the liquid level in a vapor generator, in which the incoming flow of feed liquid is regulated in response to the difference between the measured liquid level and a reference level, the difference between the exiting vapor mass flow rate and the incoming liquid mass flow rate, and a function of the measured incoming liquid temperature. The temperature function produces a gain value, which increases in response to decreasing incoming liquid temperature. The purpose of the temperature function is to stabilize the level control under transient conditions (e.g. sudden lose of load). (author)

77 FR 60935 - Hazardous Materials: Minor Editorial Corrections and Clarifications (RRR)

Science.gov (United States)

2012-10-05

... flammable cryogenic liquid is not received by the consignee within 20 days from the date of shipment.... * * * * * Container ship * * * * * * * * Hazardous material means a substance or material that the Secretary of... transportation law (49 U.S.C. 5103). The term includes hazardous substances, hazardous wastes, marine pollutants...

Historical analysis of US pipeline accidents triggered by natural hazards

Science.gov (United States)

Girgin, Serkan; Krausmann, Elisabeth

2015-04-01

Natural hazards, such as earthquakes, floods, landslides, or lightning, can initiate accidents in oil and gas pipelines with potentially major consequences on the population or the environment due to toxic releases, fires and explosions. Accidents of this type are also referred to as Natech events. Many major accidents highlight the risk associated with natural-hazard impact on pipelines transporting dangerous substances. For instance, in the USA in 1994, flooding of the San Jacinto River caused the rupture of 8 and the undermining of 29 pipelines by the floodwaters. About 5.5 million litres of petroleum and related products were spilled into the river and ignited. As a results, 547 people were injured and significant environmental damage occurred. Post-incident analysis is a valuable tool for better understanding the causes, dynamics and impacts of pipeline Natech accidents in support of future accident prevention and mitigation. Therefore, data on onshore hazardous-liquid pipeline accidents collected by the US Pipeline and Hazardous Materials Safety Administration (PHMSA) was analysed. For this purpose, a database-driven incident data analysis system was developed to aid the rapid review and categorization of PHMSA incident reports. Using an automated data-mining process followed by a peer review of the incident records and supported by natural hazard databases and external information sources, the pipeline Natechs were identified. As a by-product of the data-collection process, the database now includes over 800,000 incidents from all causes in industrial and transportation activities, which are automatically classified in the same way as the PHMSA record. This presentation describes the data collection and reviewing steps conducted during the study, provides information on the developed database and data analysis tools, and reports the findings of a statistical analysis of the identified hazardous liquid pipeline incidents in terms of accident dynamics and

Auditable safety analysis and final hazard classification for Buildings 1310-N and 1314-N

International Nuclear Information System (INIS)

Kloster, G.L.

1997-05-01

This document is a graded auditable safety analysis (ASA) of the deactivation activities planned for the 100-N facility segment comprised of the Building 1310-N pump silo (part of the Liquid Radioactive Waste Treatment Facility) and 1314-N Building (Liquid Waste Disposal Building).The ASA describes the hazards within the facility and evaluates the adequacy of the measures taken to reduce, control, or mitigate the identified hazards. This document also serves as the Final Hazard Classification (FHC) for the 1310-N pump silo and 1314-N Building segment. The FHC is radiological based on the Preliminary Hazard Classification and the total inventory of radioactive and hazardous materials in the segment

77 FR 43002 - Hazardous Waste Management System: Identification and Listing of Hazardous Waste Amendment

Science.gov (United States)

2012-07-23

... ConocoPhillips filter press processing of storm water Billings Refinery). tank sludge (F037) generated at... residual solids from the processed storm water tank sludge meet the delisting levels in 40 CFR 261 Appendix... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 261 [FRL 9704-1] Hazardous Waste Management System...

Hazard analysis of Clostridium perfringens in the Skylab Food System

Science.gov (United States)

Bourland, C. T.; Huber, C. S.; Kiser, P. R.; Heidelbaugh, N. D.; Rowley, D. B.

1974-01-01

The Skylab Food System presented unique microbiological problems because food was warmed in null-gravity and because the heat source was limited to 69.4 C (to prevent boiling in null-gravity). For these reasons, the foods were manufactured using critical control point techniques of quality control coupled with appropriate hazard analyses. One of these hazard analyses evaluated the threat from Clostridium perfringens. Samples of food were inoculated with C. perfringens and incubated for 2 h at temperatures ranging from 25 to 55 C. Generation times were determined for the foods at various temperatures. Results of these tests were evaluated taking into consideration: food-borne disease epidemiology, the Skylab food manufacturing procedures, and the performance requirements of the Skylab Food System. Based on this hazard analysis, a limit for C. perfringens of 100/g was established for Skylab foods.

PRO-ELICERE: A Hazard Analysis Automation Process Applied to Space Systems

Directory of Open Access Journals (Sweden)

Tharcius Augusto Pivetta

2016-07-01

Full Text Available In the last decades, critical systems have increasingly been developed using computers and software even in space area, where the project approach is usually very conservative. In the projects of rockets, satellites and its facilities, like ground support systems, simulators, among other critical operations for the space mission, it must be applied a hazard analysis. The ELICERE process was created to perform a hazard analysis mainly over computer critical systems, in order to define or evaluate its safety and dependability requirements, strongly based on Hazards and Operability Study and Failure Mode and Effect Analysis techniques. It aims to improve the project design or understand the potential hazards of existing systems improving their functions related to functional or non-functional requirements. Then, the main goal of the ELICERE process is to ensure the safety and dependability goals of a space mission. The process, at the beginning, was created to operate manually in a gradual way. Nowadays, a software tool called PRO-ELICERE was developed, in such a way to facilitate the analysis process and store the results for reuse in another system analysis. To understand how ELICERE works and its tool, a small example of space study case was applied, based on a hypothetical rocket of the Cruzeiro do Sul family, developed by the Instituto de Aeronáutica e Espaço in Brazil.

Hazards analysis of TNX Large Melter-Off-Gas System

International Nuclear Information System (INIS)

Randall, C.T.

1982-03-01

Analysis of the potential safety hazards and an evaluation of the engineered safety features and administrative controls indicate that the LMOG System can be operated without undue hazard to employees or the public, or damage to equipment. The safety features provided in the facility design coupled with the planned procedural and administrative controls make the occurrence of serious accidents very improbable. A set of recommendations evolved during this analysis that was judged potentially capable of further reducing the probability of personnel injury or further mitigating the consequences of potential accidents. These recommendations concerned areas such as formic acid vapor hazards, hazard of feeding water to the melter at an uncontrolled rate, prevention of uncontrolled glass pours due to melter pressure excursions and additional interlocks. These specific suggestions were reviewed with operational and technical personnel and are being incorporated into the process. The safeguards provided by these recommendations are discussed in this report

Ferrofluids in liquid crystalline systems

International Nuclear Information System (INIS)

Figueiredo Neto, A.M.; Liebert, L.

1989-08-01

It is a well-known fact that intermediate or mesomorphic phase may exist between the crystalline and the isotropic liquid phases. The symmetry properties of these mesophases are intermediate between those of a crystal and a liquid. In this paper, some aspects of the use of ferrofluids in thermotropic and lyotropic systems are studied both the experimental difficulties as well as the fundamental phypical phenomena involved. (A.C.A.S.) [pt

Fire Hazard Analysis for the Cold Neutron Source System

Energy Technology Data Exchange (ETDEWEB)

Choi, Jung Won; Kim, Young Ki; Wu, Sang Ik; Park, Young Cheol; Kim, Bong Soo; Kang, Mee Jin; Oh, Sung Wook

2006-04-15

As the Cold Neutron Source System for its installation in HANARO has been designing, the fire hazard analysis upon the CNS system becomes required under No. 2003-20 of the MOST notice, Technical Standard about the Fire Hazard Analysis. As a moderator, the strongly flammable hydrogen is filled in the hydrogen system of CNS. Against the fire or explosion in the reactor hall, accordingly, the physical damage on the reactor safety system should be evaluated in order to reflect the safety protection precaution in the design of CNS system. For the purpose of fire hazard analysis, the accident scenarios were divided into three: hydrogen leak during the hydrogen charging in the system, hydrogen leak during the normal operation of CNS, explosion of hydrogen buffer tank by the external fire. The analysis results can be summarized as follows. First, there is no physical damage threatening the reactor safety system although all hydrogen gas came out of the system then ignited as a jet fire. Second, since the CNS equipment island (CEI) is located enough away from the reactor, no physical damage caused by the buffer tank explosion is on the reactor in terms of the overpressure except the flying debris so that the light two-hour fireproof panel is installed in an one side of hydrogen buffer tank. Third, there are a few combustibles on the second floor of CEI so that the fire cannot be propagated to other areas in the reactor hall; however, the light two-hour fireproof panel will be built on the second floor against the external or internal fire so as to play the role of a fire protection area.

Fire Hazard Analysis for the Cold Neutron Source System

International Nuclear Information System (INIS)

Choi, Jung Won; Kim, Young Ki; Wu, Sang Ik; Park, Young Cheol; Kim, Bong Soo; Kang, Mee Jin; Oh, Sung Wook

2006-04-01

As the Cold Neutron Source System for its installation in HANARO has been designing, the fire hazard analysis upon the CNS system becomes required under No. 2003-20 of the MOST notice, Technical Standard about the Fire Hazard Analysis. As a moderator, the strongly flammable hydrogen is filled in the hydrogen system of CNS. Against the fire or explosion in the reactor hall, accordingly, the physical damage on the reactor safety system should be evaluated in order to reflect the safety protection precaution in the design of CNS system. For the purpose of fire hazard analysis, the accident scenarios were divided into three: hydrogen leak during the hydrogen charging in the system, hydrogen leak during the normal operation of CNS, explosion of hydrogen buffer tank by the external fire. The analysis results can be summarized as follows. First, there is no physical damage threatening the reactor safety system although all hydrogen gas came out of the system then ignited as a jet fire. Second, since the CNS equipment island (CEI) is located enough away from the reactor, no physical damage caused by the buffer tank explosion is on the reactor in terms of the overpressure except the flying debris so that the light two-hour fireproof panel is installed in an one side of hydrogen buffer tank. Third, there are a few combustibles on the second floor of CEI so that the fire cannot be propagated to other areas in the reactor hall; however, the light two-hour fireproof panel will be built on the second floor against the external or internal fire so as to play the role of a fire protection area

Development of prototype liquid scintillator system for monitoring liquid radioactive waste

International Nuclear Information System (INIS)

Nam, Uk Won; Seon, Kwang Il; Kong, Kyoung Nam; Kim, Chang Kyu; Lee, Dong Myung; Lee, Sang Kook

2003-01-01

A prototype liquid scillatillator system for measurement of multiple beta-labeled mixtures was developed and its characteristic was investigated. The signal processing system consists of two photomultiplier tubes and the coincident count circuit. The characteristic of the system was analyzed using 4 beta-labeled samples ( 3 H, 14 C, 36 Cl and 90 Sr). Beta spectra from the samples were obtained without radiation shielding, and the detection limits for each nuclides were estimated based on the spectra. The estimated detection limits were compared to the legal regulation values. It is found that the liquid radioactive nuclides are detectable well below the legal regulation values

Hazards and operability study for the surface moisture monitoring system

International Nuclear Information System (INIS)

Board, B.D.

1996-01-01

The Hanford Nuclear Reservation Tank Farms' underground waste tanks have been used to store liquid radioactive waste from defense materials production since the 1940's. Waste in certain of the tanks may contain material in the form of ferrocyanide or various organic compounds which could potentially be susceptible to condensed phase chemical reactions. Because of the presence of oxidizing materials (nitrate compounds) and heat sources (radioactive decay and chemical reactions), the ferrocyanide or organic material could potentially fuel a propagating exothermic reaction with undesirable consequences. Analysis and experiments indicate that the reaction propagation and/or initiation may be prevented by the presence of sufficient moisture in the waste. Because the reaction would probably be initiated at the surface of the waste, evidence of sufficient moisture concentration would help provide evidence that the tank waste can continue to be safely stored. The Surface Moisture Measurement System (SMMS) was developed to collect data on the surface moisture in the waste by inserting two types of probes (singly) into a waste tank-a neutron probe and an electromagnetic inductance (EMI) probe. The sensor probes will be placed on the surface of the waste utilizing a moveable deployment arm to lower them through an available riser. The movement of the SMMS within the tank will be monitored by a camera lowered through an adjacent riser. The SMMS equipment is the subject of this study. Hazards and Operability Analysis (HAZOP) is a systematic technique for assessing potential hazards and/or operability problems for a new activity. It utilizes a multidiscipline team of knowledgeable individuals in a systematic brainstorming effort. The results of this study will be used as input to an Unreviewed Safety Question determination

High-throughput liquid-liquid extraction in 96-well format: Parallel artificial liquid membrane extraction

DEFF Research Database (Denmark)

Gjelstad, Astrid; Andresen, Alf Terje; Dahlgren, Anders

2017-01-01

, highly efficient sample cleanup, and direct compatibility with liquid chromatography–mass spectrometry (LC–MS). The consumption of hazardous organic solvents is also almost eliminated using PALME as the sample preparation technique. This article summarizes current experiences with PALME, based on work...

Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for soybean biodiesel

International Nuclear Information System (INIS)

Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Oliveira, J. Vladimir

2013-01-01

Highlights: ► (Liquid + liquid) equilibrium data for the systems of biodiesel production. ► LLE data for multicomponent FAME and FAEE from (303.15 to 333.15) K. ► Experimental data correlated using the UNIQUAC model. -- Abstract: This work reports (liquid + liquid) equilibrium (LLE) data for the systems of interest in soybean biodiesel production. Numerical data for LLE were obtained for binary, ternary and quaternary systems comprising fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) from soybean oil, water, glycerol, methanol, and ethanol at temperatures of (303.15, 318.15, and 333.15) K. Quantification of compounds in equilibrium in both phases was determined by analytical methods whereas solubility curves (binodal) were obtained by the cloud-point method. For all systems investigated, good alignments were obtained between phase compositions and the initial as well as overall compositions hence indicating low deviations from the mass balance. Experimental results were correlated using the UNIQUAC model with satisfactory agreement between experiment and theory

75 FR 62040 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Proposed Exclusion

Science.gov (United States)

2010-10-07

... the lists of hazardous waste listed at 40 CFR 261.31, both past and currently generated sludge... water production waste treatment system. Once- through non-contact cooling water does not require... grease, sulfide, water content, corrosivity and ignitability. The sludge characterization included...

(Vapour + liquid) equilibria of ternary systems with ionic liquids using headspace gas chromatography

International Nuclear Information System (INIS)

Mokhtarani, Babak; Gmehling, Juergen

2010-01-01

(Vapour + liquid) equilibrium (VLE) data for the ternary systems (hexane + benzene), (hexane + cyclohexane), (benzene + cyclohexane), and (ethanol + water) with an ionic liquid as entrainer for extractive distillation were measured by headspace gas chromatography. As ionic liquids, 1-hexyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [HMIM][BTI], 1-octyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [OMIM][BTI], 1-octyl-3-methyl-imidazolium trifluoro-methanesulfonate [OMIM][OTF], and 1-butyl-3-methyl-imidazolium trifluoro-methanesulfonate [BMIM][OTF] were used. The experimental data show that the ionic liquids investigated have a great influence on the separation factors of the systems (hexane + benzene), (hexane + cyclohexane), and (benzene + cyclohexane). The experimental data were compared with the predicted results using mod. UNIFAC (Do). The predicted results are in good agreement with the experimental data.

(Vapour + liquid) equilibria of ternary systems with ionic liquids using headspace gas chromatography

Energy Technology Data Exchange (ETDEWEB)

Mokhtarani, Babak [Chemistry and Chemical Engineering Research Center of Iran, P.O. Box 14335-186, Tehran (Iran, Islamic Republic of); Gmehling, Juergen, E-mail: gmehling@tech.chem.uni-oldenburg.d [Carl von Ossietzky Universitaet Oldenburg, Technische Chemie, D-26111 Oldenburg (Germany)

2010-08-15

(Vapour + liquid) equilibrium (VLE) data for the ternary systems (hexane + benzene), (hexane + cyclohexane), (benzene + cyclohexane), and (ethanol + water) with an ionic liquid as entrainer for extractive distillation were measured by headspace gas chromatography. As ionic liquids, 1-hexyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [HMIM][BTI], 1-octyl-3-methyl-imidazolium bis (trifluoromethyl-sulfonyl) imide [OMIM][BTI], 1-octyl-3-methyl-imidazolium trifluoro-methanesulfonate [OMIM][OTF], and 1-butyl-3-methyl-imidazolium trifluoro-methanesulfonate [BMIM][OTF] were used. The experimental data show that the ionic liquids investigated have a great influence on the separation factors of the systems (hexane + benzene), (hexane + cyclohexane), and (benzene + cyclohexane). The experimental data were compared with the predicted results using mod. UNIFAC (Do). The predicted results are in good agreement with the experimental data.

JANNAF 17th Propulsion Systems Hazards Subcommittee Meeting. Volume 1

Science.gov (United States)

Cocchiaro, James E. (Editor); Gannaway, Mary T. (Editor); Rognan, Melanie (Editor)

1998-01-01

Volume 1, the first of two volumes is a compilation of 16 unclassified/unlimited technical papers presented at the 17th meeting of the Joint Army-Navy-NASA-Air Force (JANNAF) Propulsion Systems Hazards Subcommittee (PSHS) held jointly with the 35th Combustion Subcommittee (CS) and Airbreathing Propulsion Subcommittee (APS). The meeting was held on 7 - 11 December 1998 at Raytheon Systems Company and the Marriott Hotel, Tucson, AZ. Topics covered include projectile and shaped charge jet impact vulnerability of munitions; thermal decomposition and cookoff behavior of energetic materials; damage and hot spot initiation mechanisms with energetic materials; detonation phenomena of solid energetic materials; and hazard classification, insensitive munitions, and propulsion systems safety.

Probabilistic risk assessment framework for structural systems under multiple hazards using Bayesian statistics

Energy Technology Data Exchange (ETDEWEB)

Kwag, Shinyoung [North Carolina State University, Raleigh, NC 27695 (United States); Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of); Gupta, Abhinav, E-mail: agupta1@ncsu.edu [North Carolina State University, Raleigh, NC 27695 (United States)

2017-04-15

Highlights: • This study presents the development of Bayesian framework for probabilistic risk assessment (PRA) of structural systems under multiple hazards. • The concepts of Bayesian network and Bayesian inference are combined by mapping the traditionally used fault trees into a Bayesian network. • The proposed mapping allows for consideration of dependencies as well as correlations between events. • Incorporation of Bayesian inference permits a novel way for exploration of a scenario that is likely to result in a system level “vulnerability.” - Abstract: Conventional probabilistic risk assessment (PRA) methodologies (USNRC, 1983; IAEA, 1992; EPRI, 1994; Ellingwood, 2001) conduct risk assessment for different external hazards by considering each hazard separately and independent of each other. The risk metric for a specific hazard is evaluated by a convolution of the fragility and the hazard curves. The fragility curve for basic event is obtained by using empirical, experimental, and/or numerical simulation data for a particular hazard. Treating each hazard as an independently can be inappropriate in some cases as certain hazards are statistically correlated or dependent. Examples of such correlated events include but are not limited to flooding induced fire, seismically induced internal or external flooding, or even seismically induced fire. In the current practice, system level risk and consequence sequences are typically calculated using logic trees to express the causative relationship between events. In this paper, we present the results from a study on multi-hazard risk assessment that is conducted using a Bayesian network (BN) with Bayesian inference. The framework can consider statistical dependencies among risks from multiple hazards, allows updating by considering the newly available data/information at any level, and provide a novel way to explore alternative failure scenarios that may exist due to vulnerabilities.

Probabilistic risk assessment framework for structural systems under multiple hazards using Bayesian statistics

International Nuclear Information System (INIS)

Kwag, Shinyoung; Gupta, Abhinav

2017-01-01

Highlights: • This study presents the development of Bayesian framework for probabilistic risk assessment (PRA) of structural systems under multiple hazards. • The concepts of Bayesian network and Bayesian inference are combined by mapping the traditionally used fault trees into a Bayesian network. • The proposed mapping allows for consideration of dependencies as well as correlations between events. • Incorporation of Bayesian inference permits a novel way for exploration of a scenario that is likely to result in a system level “vulnerability.” - Abstract: Conventional probabilistic risk assessment (PRA) methodologies (USNRC, 1983; IAEA, 1992; EPRI, 1994; Ellingwood, 2001) conduct risk assessment for different external hazards by considering each hazard separately and independent of each other. The risk metric for a specific hazard is evaluated by a convolution of the fragility and the hazard curves. The fragility curve for basic event is obtained by using empirical, experimental, and/or numerical simulation data for a particular hazard. Treating each hazard as an independently can be inappropriate in some cases as certain hazards are statistically correlated or dependent. Examples of such correlated events include but are not limited to flooding induced fire, seismically induced internal or external flooding, or even seismically induced fire. In the current practice, system level risk and consequence sequences are typically calculated using logic trees to express the causative relationship between events. In this paper, we present the results from a study on multi-hazard risk assessment that is conducted using a Bayesian network (BN) with Bayesian inference. The framework can consider statistical dependencies among risks from multiple hazards, allows updating by considering the newly available data/information at any level, and provide a novel way to explore alternative failure scenarios that may exist due to vulnerabilities.

Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for castor oil biodiesel

International Nuclear Information System (INIS)

Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Oliveira, J. Vladimir

2013-01-01

Highlights: ► (Liquid + liquid) equilibrium data for multicomponent castor oil FAME and FAEE castor oil. ► Tie-lines and solubility curves (binodal) by cloud-point method for FAME and FAEE systems. ► Experimental data correlated using the UNIQUAC model. -- Abstract: This work reports new liquid–liquid solubility values (binodal curves) as well as (liquid + liquid) equilibrium data for, ternary and quaternary systems containing fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) from castor oil, water, glycerol, methanol and anhydrous ethanol at T = (303.15, 318.15, and 333.15) K. Solubility curves (binodal) were also obtained by the cloud-point method for binary systems containing FAME, FAEE, water, or glycerol. All results obtained can be considered of good quality. The experimental values were correlated using the UNIQUAC model, whose results presented good performance and satisfactory fitting of equilibrium values

Mobile liquid VR system: a cost effective alternative

International Nuclear Information System (INIS)

Soto, R.; Harkins, R.; HPD, Inc., Naperville, IL)

1985-01-01

The need for cost effective alternatives to treat large volumes of liquid radwaste has never been more evident. As part of a continuing effort to introduce such alternatives, HPD, Inc., and Chem-Nuclear Systems, Inc., have integrated two proven state-of-the-art technologies to offer a mobile liquid volume reduction system that satisfies nuclear industry requirements, with respect to liquid radwaste handling. This system optimizes proven technology by employing a crystallizer unit to concentrate the waste liquids to 50 weight percent solids, thereby reducing the volume to be solidified by factors of 40, while using only 20 percent of the energy required by conventional evaporative systems. In addition, the system employs a field proven cement solidification process which has been accepted in a Topical Report by the US NRC and which offers the highest waste to container volume ratios for stable waste forms in the industry. This volume reduction-solidification system is able to reduce over 7000 gallons of liquid waste per day to less than 30 cubic feet of 10CFR61 certified stable solidified waste for ultimate disposal or on-site storage. This document describes the GEODE System; its applicability; economics; volume reduction; scope of responsibility and experience. Major benefits include higher VR factors; assurance of continual regulatory compliance; and no capital investment

Software safety hazard analysis

International Nuclear Information System (INIS)

Lawrence, J.D.

1996-02-01

Techniques for analyzing the safety and reliability of analog-based electronic protection systems that serve to mitigate hazards in process control systems have been developed over many years, and are reasonably well understood. An example is the protection system in a nuclear power plant. The extension of these techniques to systems which include digital computers is not well developed, and there is little consensus among software engineering experts and safety experts on how to analyze such systems. One possible technique is to extend hazard analysis to include digital computer-based systems. Software is frequently overlooked during system hazard analyses, but this is unacceptable when the software is in control of a potentially hazardous operation. In such cases, hazard analysis should be extended to fully cover the software. A method for performing software hazard analysis is proposed in this paper

Lime treatment of liquid waste containing heavy metals, radionuclides and organics

International Nuclear Information System (INIS)

DuPont, A.

1990-01-01

This paper reports on lime treatment of liquid waste containing heavy metals, radio nuclides and organics. Lime is wellknown for its use in softening drinking water the treatment of municipal wastewaters. It is becoming important in the treatment of industrial wastewater and liquid inorganic hazardous waste; however, there are many questions regarding the use of lime for the treatment of liquid hazardous waste

Liquidity in Retirement Savings Systems: An International Comparison

OpenAIRE

Beshears, John Leonard; Choi, James J.; Hurwitz, Joshua Bayard; Laibson, David I.; Madrian, Brigitte

2015-01-01

What is the socially optimal level of liquidity in a retirement savings system? Liquid retirement savings are desirable because liquidity enables agents to flexibly respond to pre-retirement events that raise the marginal utility of consumption. On the other hand, pre-retirement liquidity is undesirable when it leads to under-saving arising from, for example, planning mistakes or self-control problems. This paper compares the liquidity that six developed economies have built into their employ...

Development of an expert system for transportation of hazardous and radioactive materials

International Nuclear Information System (INIS)

Ferrada, J.J.; Michelhaugh, R.D.; Rawl, R.R.

1994-01-01

Under the sponsorship of the US Department of Energy's (DOE's) Transportation Management Division (EM-261), the Transportation Technologies Group at Oak Ridge National Laboratory (ORNL) has designed and developed an expert system prototype application of the hazardous materials transportation regulations. The objective of this task was to provide a proof-of-concept for developing a computerized expert system that will ensure straightforward, consistent, and error-free application of the hazardous materials transportation regulations. The expert system prototype entailed the analysis of what an expert in hazardous materials shipping information could/should do. From the analysis of the different features required for the expert system prototype, it was concluded that the developmental efforts should be directed to a Windows trademark 3.1 hypermedia environment. Hypermedia technology usually works as an interactive software system that gives personal computer users the ability to organize, manage, and present information in a number of formats--text, graphics, sound, and full-motion video

Application of system safety engineering techniques for hazard prevention at the Superconducting Super Collider

International Nuclear Information System (INIS)

Hendrix, B.L.

1991-01-01

A primary goal of the Superconducting Super Collider Laboratory (SSCL) is to establish an exemplary safety program. Achieving this goal requires leadership, planning, coordination, and technical know-how. To ensure that safety is an inherent part of the design, the Environment, Safety and Health Office employs a systems engineering discipline and process known as System Safety. The goal of System Safety - hazard prevention - is accomplished by analyzing systems to identify hazards and to evaluate design and procedural options and countermeasures to prevent, eliminate, mitigate, or control hazards and risks. Establishment of safety and human factors design criteria at the outset of the project prevents unsafe designs and safety violations, reduces risks, and helps in avoiding costly design changes later. This process requires a considerable amount of coordination with a variety of technical disciplines and safety professionals to integrate methods of hazard prevention, mitigation, and risk reduction throughout the system life-cycle

Software hazard analysis for nuclear digital protection system by Colored Petri Net

International Nuclear Information System (INIS)

Bai, Tao; Chen, Wei-Hua; Liu, Zhen; Gao, Feng

2017-01-01

Highlights: •A dynamic hazard analysis method is proposed for the safety-critical software. •The mechanism relies on Colored Petri Net. •Complex interactions between software and hardware are captured properly. •Common failure mode in software are identified effectively. -- Abstract: The software safety of a nuclear digital protection system is critical for the safety of nuclear power plants as any software defect may result in severe damage. In order to ensure the safety and reliability of safety-critical digital system products and their applications, software hazard analysis is required to be performed during the lifecycle of software development. The dynamic software hazard modeling and analysis method based on Colored Petri Net is proposed and applied to the safety-critical control software of the nuclear digital protection system in this paper. The analysis results show that the proposed method can explain the complex interactions between software and hardware and identify the potential common cause failure in software properly and effectively. Moreover, the method can find the dominant software induced hazard to safety control actions, which aids in increasing software quality.

An analysis of land use planning and equity issues surrounding hazardous liquid and natural gas transmission pipelines in North Carolina

Science.gov (United States)

Osland, Anna Christine

Hazardous liquid and natural gas transmission pipelines have received limited attention by planning scholars even though local development decisions can have broad consequences if a rupture occurs. In this dissertation, I evaluated the implications of land-use planning for reducing risk to transmission pipeline hazards in North Carolina via three investigations. First, using a survey of planning directors in jurisdictions with transmission pipeline hazards, I investigated the land use planning tools used to mitigate pipeline hazards and the factors associated with tool adoption. Planning scholars have documented the difficulty of inducing planning in hazardous areas, yet there remain gaps in knowledge about the factors associated with tool adoption. Despite the risks associated with pipeline ruptures, I found most localities use few mitigation tools, and the adoption of regulatory and informational tools appear to be influenced by divergent factors. Whereas risk perception, commitment, capacity, and community context were associated with total tool and information tool use, only risk perception and capacity factors were associated with regulatory tool use. Second, using interviews of emergency managers and planning directors, I examined the role of agency collaboration for building mitigation capacity. Scholars have highlighted the potential of technical collaboration, yet less research has investigated how inter-agency collaboration shapes mitigation capacity. I identify three categories of technical collaboration, discuss how collaborative spillovers can occur from one planning area to another, and challenge the notion that all technical collaborations result in equal mitigation outcomes. Third, I evaluated characteristics of the population near pipelines to address equity concerns. Surprisingly, I did not find broad support for differences in exposure of vulnerable populations. Nonetheless, my analyses uncovered statistically significant clusters of vulnerable

Process safety management for highly hazardous chemicals

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-02-01

Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

Radioactive liquid waste processing system

International Nuclear Information System (INIS)

Noda, Tetsuya; Kuramitsu, Kiminori; Ishii, Tomoharu.

1997-01-01

The present invention provides a system for processing radioactive liquid wastes containing laundry liquid wastes, shower drains or radioactive liquid wastes containing chemical oxygen demand (COD) ingredients and oil content generated from a nuclear power plant. Namely, a collecting tank collects radioactive liquid wastes. A filtering device is connected to the exit of the collective tank. A sump tank is connected to the exit of the filtering device. A powdery active carbon supplying device is connected to the collecting tank. A chemical fluid tank is connected to the collecting tank and the filtering device by way of chemical fluid injection lines. Backwarding pipelines connect a filtered water flowing exit of the filtering device and the collecting tank. The chemical solution is stored in the chemical solution tank. Then, radioactive materials in radioactive liquid wastes generated from a nuclear power plant are removed by the filtering device. The water quality standard specified in environmental influence reports can be satisfied. In the filtering device, when the filtering flow rate is reduced, the chemical fluid is supplied from the chemical fluid tank to the filtering device to recover the filtering flow rate. (I.S.)

75 FR 11002 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Final Rule

Science.gov (United States)

2010-03-10

... Waste Management System; Identification and Listing of Hazardous Waste; Final Rule AGENCY: Environmental... and specific types of management of the petitioned waste, the quantities of waste generated, and waste... wastes. This final rule responds to a petition submitted by Valero to delist F037 waste. The F037 waste...

76 FR 59960 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Withdrawal of...

Science.gov (United States)

2011-09-28

... Waste Management System; Identification and Listing of Hazardous Waste; Withdrawal of proposed rule... Permitting Division, Corrective Action and Waste Minimization Section (6PD-C), 1445 Ross Avenue, Dallas, TX... petition. A new petition will be required for this waste stream. List of Subjects in 40 CFR Part 261...

76 FR 5110 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Proposed Rule

Science.gov (United States)

2011-01-28

... will dispose of the leachate at a publicly owned treatment works or at an industrial waste disposal... classification of listed waste pursuant to Sec. Sec. 261.31 and 261.32. Specifically, in its petition, Gulf West... Waste Management System; Identification and Listing of Hazardous Waste; Proposed Rule AGENCY...

Transportation of hazardous goods

CERN Multimedia

TS Department

2008-01-01

A general reminder: any transportation of hazardous goods by road is subject to the European ADR rules. The goods concerned are essentially the following: Explosive substances and objects; Gases (including aerosols and non-flammable gases such as helium and nitrogen); Flammable substances and liquids (inks, paints, resins, petroleum products, alcohols, acetone, thinners); Toxic substances (acids, thinners); Radioactive substances; Corrosive substances (paints, acids, caustic products, disinfectants, electrical batteries). Any requests for the transport of hazardous goods must be executed in compliance with the instructions given at this URL: http://ts-dep.web.cern.ch/ts-dep/groups/he/HH/adr.pdf Heavy Handling Section TS-HE-HH 73793 - 160364

FDA-iRISK--a comparative risk assessment system for evaluating and ranking food-hazard pairs: case studies on microbial hazards.

Science.gov (United States)

Chen, Yuhuan; Dennis, Sherri B; Hartnett, Emma; Paoli, Greg; Pouillot, Régis; Ruthman, Todd; Wilson, Margaret

2013-03-01

Stakeholders in the system of food safety, in particular federal agencies, need evidence-based, transparent, and rigorous approaches to estimate and compare the risk of foodborne illness from microbial and chemical hazards and the public health impact of interventions. FDA-iRISK (referred to here as iRISK), a Web-based quantitative risk assessment system, was developed to meet this need. The modeling tool enables users to assess, compare, and rank the risks posed by multiple food-hazard pairs at all stages of the food supply system, from primary production, through manufacturing and processing, to retail distribution and, ultimately, to the consumer. Using standard data entry templates, built-in mathematical functions, and Monte Carlo simulation techniques, iRISK integrates data and assumptions from seven components: the food, the hazard, the population of consumers, process models describing the introduction and fate of the hazard up to the point of consumption, consumption patterns, dose-response curves, and health effects. Beyond risk ranking, iRISK enables users to estimate and compare the impact of interventions and control measures on public health risk. iRISK provides estimates of the impact of proposed interventions in various ways, including changes in the mean risk of illness and burden of disease metrics, such as losses in disability-adjusted life years. Case studies for Listeria monocytogenes and Salmonella were developed to demonstrate the application of iRISK for the estimation of risks and the impact of interventions for microbial hazards. iRISK was made available to the public at http://irisk.foodrisk.org in October 2012.

Ionic liquid and solid HF equivalent amine-poly(hydrogen fluoride) complexes effecting efficient environmentally friendly isobutane-isobutylene alkylation.

Science.gov (United States)

Olah, George A; Mathew, Thomas; Goeppert, Alain; Török, Béla; Bucsi, Imre; Li, Xing-Ya; Wang, Qi; Marinez, Eric R; Batamack, Patrice; Aniszfeld, Robert; Prakash, G K Surya

2005-04-27

Isoparaffin-olefin alkylation was investigated using liquid as well as solid onium poly(hydrogen fluoride) catalysts. These new immobilized anhydrous HF catalysts contain varied amines and nitrogen-containing polymers as complexing agents. The liquid poly(hydrogen fluoride) complexes of amines are typical ionic liquids, which are convenient media and serve as HF equivalent catalysts with decreased volatility for isoparaffin-olefin alkylation. Polymeric solid amine:poly(hydrogen fluoride) complexes are excellent solid HF equivalents for similar alkylation acid catalysis. Isobutane-isobutylene or 2-butene alkylation gave excellent yields of high octane alkylates (up to RON = 94). Apart from their excellent catalytic performance, the new catalyst systems significantly reduce environmental hazards due to the low volatility of complexed HF. They represent a new, "green" class of catalyst systems for alkylation reactions, maintaining activity of HF while minimizing its environmental hazards.

Intelligent systems for remote decommissioning in hazardous environments

International Nuclear Information System (INIS)

Drotning, W.D.; Bennett, P.C.

1991-01-01

Investigation of advanced technologies utilizing intelligent machines is being supported jointly by the US Department of Energy Offices of Civilian Radioactive Waste Management (DOE/RW) and Environmental Restoration and Waste Management (DOE/EM) for automation of transportation package handling operations at nuclear facilities and of nuclear waste site remediation efforts. Handling operation requirements include identification, location, and health physics operation, followed by bolting/unbolting operations and package disassembly. To accommodate these operations and the diversity of packages, fast model-based automated programming and force feedback control of a robotic cask handling system were developed. In addition, sensor-directed model-based robotic control has been demonstrated for application to hazardous material cleanup. In this application, a graphical interface is used to simulate and evaluate operator-controlled motions and provide telerobotic control of the system. Remote automated handling technologies developed through these programs have the potential to decrease worker exposure and increase efficiency during decommissioning activities in hazardous environments. 8 refs., 4 figs

System implementation of hazard analysis and critical control points (HACCP) in a nitrogen production plant

International Nuclear Information System (INIS)

Barrantes Salazar, Alexandra

2014-01-01

System of hazard analysis and critical control points are deployed in a production plant of liquid nitrogen. The fact that the nitrogen has become a complement to food packaging to increase shelf life, or provide a surface that protect it from manipulation, has been the main objective. Analysis of critical control points for the nitrogen production plant has been the adapted methodology. The knowledge of both the standard and the production process, as well as the on site verification process, have been necessary. In addition, all materials and/or processing units that are found in contact with the raw material or the product under study were evaluated. Such a way that the intrinsic risks of each were detected, from the physical, chemical and biological points of view according to the origin or pollution source. For each found risk was evaluated the probability of occurrence according to the frequency and gravity of it, with these variables determined was achieved the definition of the type of risk detected. In the cases that was presented a greater risk or critical, these were subjected decision tree; with which is concluded the non determination of critical control points. However, for each one of them were established the maximum permitted limits. To generate each of the results it has literature or scientific reference of reliable provenance, where is indicated properly the support of the evaluated matter. In a general way, the material matrix and the process matrix are found without critical control points; so that the project is concluded in the analysis, and it has to generate without the monitoring system and verification. To increase this project is suggested in order to cover the packaging system of gaseous nitrogen, due to it was delimited to liquid nitrogen. Furthermore, the liquid nitrogen is a 100% automated and closed process so the introduction of contaminants is very reduced, unlike the gaseous nitrogen process. (author) [es

Lithium-thionyl chloride cell system safety hazard analysis

Science.gov (United States)

Dampier, F. W.

1985-03-01

This system safety analysis for the lithium thionyl chloride cell is a critical review of the technical literature pertaining to cell safety and draws conclusions and makes recommendations based on this data. The thermodynamics and kinetics of the electrochemical reactions occurring during discharge are discussed with particular attention given to unstable SOCl2 reduction intermediates. Potentially hazardous reactions between the various cell components and discharge products or impurities that could occur during electrical or thermal abuse are described and the most hazardous conditions and reactions identified. Design factors influencing the safety of Li/SOCl2 cells, shipping and disposal methods and the toxicity of Li/SOCl2 battery components are additional safety issues that are also addressed.

The development of the globally harmonized system (GHS) of classification and labelling of hazardous chemicals

International Nuclear Information System (INIS)

Winder, Chris; Azzi, Rola; Wagner, Drew

2005-01-01

The hazards of chemicals can be classified using classification criteria that are based on physical, chemical and ecotoxicological endpoints. These criteria may be developed be iteratively, based on scientific or regulatory processes. A number of national and international schemes have been developed over the past 50 years, and some, such as the UN Dangerous Goods system or the EC system for hazardous substances, are in widespread use. However, the unnecessarily complicated multiplicity of existing hazard classifications created much unnecessary confusion at the user level, and a recommendation was made at the 1992 Rio Earth summit to develop a globally harmonized chemical hazard classification and compatible labelling system, including material safety data sheets and easily understandable symbols, that could be used for manufacture, transport, use and disposal of chemical substances. This became the globally harmonized system for the Classification and Labelling of Chemicals (GHS). The developmental phase of the GHS is largely complete. Consistent criteria for categorising chemicals according to their toxic, physical, chemical and ecological hazards are now available. Consistent hazard communication tools such as labelling and material safety data sheets are also close to finalisation. The next phase is implementation of the GHS. The Intergovernmental Forum for Chemical Safety recommends that all countries implement the GHS as soon as possible with a view to have the system fully operational by 2008. When the GHS is in place, the world will finally have one system for classification of chemical hazards

Efficient energy storage in liquid desiccant cooling systems

Energy Technology Data Exchange (ETDEWEB)

Hublitz, Astrid

2008-07-18

Liquid Desiccant Cooling Systems (LDCS) are open loop sorption systems for air conditioning that use a liquid desiccant such as a concentrated salt solution to dehumidify the outside air and cool it by evaporative cooling. Thermochemical energy storage in the concentrated liquid desiccant can bridge power mismatches between demand and supply. Low-flow LDCS provide high energy storage capacities but are not a state-of-the-art technology yet. The key challenge remains the uniform distribution of the liquid desiccant on the heat and mass transfer surfaces. The present research analyzes the factors of influence on the energy storage capacity by simulation of the heat and mass transfer processes and specifies performance goals for the distribution of the process media. Consequently, a distribution device for the liquid desiccant is developed that reliably meets the performance goals. (orig.)

Systems and methods for monitoring a solid-liquid interface

Science.gov (United States)

Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

2013-06-11

Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

Prediction of (liquid + liquid) equilibrium for binary and ternary systems containing ionic liquids with the bis[(trifluoromethyl)sulfonyl]imide anion using the ASOG method

International Nuclear Information System (INIS)

Robles, Pedro A.; Cisternas, Luis A.

2015-01-01

Highlights: • ASOG model was used to predict LLE data for ionic liquid systems. • Twenty five binary and seven ternary systems that include the NTf 2 anion were used. • New group interaction parameters were determined. • The results are satisfactory, with rms deviations of about 3%. - Abstract: Ionic liquids are neoteric, environmentally friendly solvents (as they do not produce emissions) composed of large organic cations and relatively small inorganic anions. They have favorable physical properties, such as negligible volatility and a wide range of liquid existence. (Liquid + liquid) equilibrium (LLE) data for systems including ionic liquids, although essential for the design, optimization and operation of separation processes, remain scarce. However, some recent studies have presented ternary LLE data involving several ionic liquids and organic compounds such as alkanes, alkenes, alkanols, ethers and aromatics, as well as water. In this work, the ASOG model for the activity coefficient is used to predict LLE data for 25 binary and 07 ternary systems at 101.3 kPa and several temperatures; all the systems are formed by ionic liquids including the bis[(trifluoromethyl)sulfonyl]imide (NTf 2 ) anion plus alkanes, alkenes, cycloalkanes, alkanols, water, thiophene and aromatics. New group interaction parameters were determined using a modified Simplex method, minimizing a composition-based objective function of experimental data obtained from the literature. The results are satisfactory, with rms deviations of approximately 3%

An integrated risk communication system for the transport of hazardous materials

International Nuclear Information System (INIS)

Minor, J.W. IV; Abkowitz, M.D.

2004-01-01

This paper describes the development and implementation of the prototype of an an internet-based, risk communication system prototype for the transport of hazardous materials. The system was designed with the objectives of: (1) incorporating functionality and features that are useful for meeting a variety of risk communication needs, and (2) demonstrating a high degree of interaction among system components, enabling customisation to meet the specific transport risk communication needs requirements of the host organisation. To demonstrate 'proof of concept', the system is applied to two scenarios: 1) building knowledge and awareness, focusing on how information can be entered, organised and disseminated to the public and other transport stakeholders, and 2) emergency management, utilising the system for securely managing information in responding to a transport incident involving hazardous materials transport incident. The effectiveness of the system in these applications is subsequently discussed. (author)

Examination of the haemostatic system in radiation and combination hazards

International Nuclear Information System (INIS)

Boegelein, K.

1980-01-01

Female mice of the NMRI-lineage were exposed to irradiation and, additionally, to an open wound in the back skin. The coagulation and the fibrinolysis were examined, comparing them with those of animals who had either been irradiated or had an open back skin wound, and the thrombocytes were counted. Here, no pathological values of the plasmatic coagulation system were found. In the first days, only after combined radiation damage, an increased coagulation potential could be found. Also indications to a reduction of the fibrinolytic activity were found. At the same time, the circulating thrombocytes were increased in most cases. With the radiation-induced thrombocytopenia, the coagulation was reduced; the thrombo-elasticity was reduced, the coagulation time was elongated. The significance and duration of the coagulation disturbances varied with the radiation dose of the combination hazards. During the haemorrhagic phase, in the animals with combined hazards the fibrinolytic potential was increased. The possible causes and the peculiarities of the elongations in the coagulation and fibrinolysis system by combined radiation hazards and possible therapies are discussed. (orig./MG) [de

Superfund Hazard Ranking System Training Course: Table of Contents

Science.gov (United States)

The Hazard Ranking System (HRS) training course is a four and ½ day, intermediate-level course designed for personnel who are required to compile, draft, and review preliminary assessments (PAs), site inspections (SIs), and HRS documentation records/packag

Recent developments in biocatalysis in multiphasic ionic liquid reaction systems.

Science.gov (United States)

Meyer, Lars-Erik; von Langermann, Jan; Kragl, Udo

2018-06-01

Ionic liquids are well known and frequently used 'designer solvents' for biocatalytic reactions. This review highlights recent achievements in the field of multiphasic ionic liquid-based reaction concepts. It covers classical biphasic systems including supported ionic liquid phases, thermo-regulated multi-component solvent systems (TMS) and polymerized ionic liquids. These powerful concepts combine unique reaction conditions with a high potential for future applications on a laboratory and industrial scale. The presence of a multiphasic system simplifies downstream processing due to the distribution of the catalyst and reactants in different phases.

Hazard interactions and interaction networks (cascades) within multi-hazard methodologies

Science.gov (United States)

Gill, Joel C.; Malamud, Bruce D.

2016-08-01

This paper combines research and commentary to reinforce the importance of integrating hazard interactions and interaction networks (cascades) into multi-hazard methodologies. We present a synthesis of the differences between multi-layer single-hazard approaches and multi-hazard approaches that integrate such interactions. This synthesis suggests that ignoring interactions between important environmental and anthropogenic processes could distort management priorities, increase vulnerability to other spatially relevant hazards or underestimate disaster risk. In this paper we proceed to present an enhanced multi-hazard framework through the following steps: (i) description and definition of three groups (natural hazards, anthropogenic processes and technological hazards/disasters) as relevant components of a multi-hazard environment, (ii) outlining of three types of interaction relationship (triggering, increased probability, and catalysis/impedance), and (iii) assessment of the importance of networks of interactions (cascades) through case study examples (based on the literature, field observations and semi-structured interviews). We further propose two visualisation frameworks to represent these networks of interactions: hazard interaction matrices and hazard/process flow diagrams. Our approach reinforces the importance of integrating interactions between different aspects of the Earth system, together with human activity, into enhanced multi-hazard methodologies. Multi-hazard approaches support the holistic assessment of hazard potential and consequently disaster risk. We conclude by describing three ways by which understanding networks of interactions contributes to the theoretical and practical understanding of hazards, disaster risk reduction and Earth system management. Understanding interactions and interaction networks helps us to better (i) model the observed reality of disaster events, (ii) constrain potential changes in physical and social vulnerability

Sludge Treatment Project Engineered Container Retrieval And Transfer System Preliminary Design Hazard Analysis Supplement 1

International Nuclear Information System (INIS)

Franz, G.R.; Meichle, R.H.

2011-01-01

This 'What/If' Hazards Analysis addresses hazards affecting the Sludge Treatment Project Engineered Container Retrieval and Transfer System (ECRTS) NPH and external events at the preliminary design stage. In addition, the hazards of the operation sequence steps for the mechanical handling operations in preparation of Sludge Transport and Storage Container (STSC), disconnect STSC and prepare STSC and Sludge Transport System (STS) for shipping are addressed.

Water-washable ink system reduces printers' hazardous emissions

Energy Technology Data Exchange (ETDEWEB)

Kratch, K.

1994-08-01

Printing industry solvents contain large quantities of volatile organic compounds (VOCs), a major contributor to air pollution in that industry. Because most printing inks contain non-water-soluble petroleum, organic solvents have been necessary to clean presses using those inks. However, under proposed control technique guidelines for lithographic printers issued by the Environmental Protection Agency (EPA), printing-press wash solutions could contain no more than 30% VOCs. Deluxe Corp., a St. Paul, Minn.-based lithographic printer, recognized that stiffer emissions rules could mean harsh penalties for non-compliance and, in 1990, began developing a water-based press wash that would meet the guidelines. Deluxe last year introduced a 100% vegetable oil-based ink that becomes water-washable when exposed to the company's water-based press-wash solution. The solvent-free system eliminates VOCs and hazardous wastes associated with printing, contains no chemicals considered hazardous by EPA, uses no non-renewable resources, and works with existing printing equipment and processes. The system also eliminates water and soil contamination risks associated with laundering or landfilling solvent-saturated shop towels, saves money by eliminating the need to pay for hazardous waste disposal and provides relief to employees who complain about the strong odors of traditional press-wash solvents.

49 CFR 172.312 - Liquid hazardous materials in non-bulk packagings.

Science.gov (United States)

2010-10-01

... offered or intended for transportation by aircraft, packages containing flammable liquids in inner... offered or intended for transportation by aircraft, packages containing flammable liquids in inner... hermetically sealed inner packagings. (6) Packages containing liquid infectious substances in primary...

Control Decisions for Flammable Gas Hazards in Waste Transfer Systems

International Nuclear Information System (INIS)

KRIPPS, L.J.

2000-01-01

This report describes the control decisions for flammable gas hazards in waste transfer systems (i.e., waste transfer piping and waste transfer-associated structures) made at control decision meetings on November 30, 1999a and April 19, 2000, and their basis. These control decisions, and the analyses that support them, will be documented in an amendment to the Final Safety Analysis Report (FSAR) (CHG 2000a) and Technical Safety Requirements (TSR) (CHG 2000b) to close the Flammable Gas Unreviewed Safety Question (USQ) (Bacon 1996 and Wagoner 1996). Following the Contractor Tier I review of the FSAR and TSR amendment, it will be submitted to the US. Department of Energy (DOE), Office of River Protection (ORP) for review and approval. The control decision meeting on November 30, 1999 to address flammable gas hazards in waste transfer systems followed the control decision process and the criteria for control decisions described in Section 3.3.1.5 of the FSAR. The control decision meeting agenda, attendance list, and introductory and background presentations are included in Attachments 1 through 4. The control decision discussions on existing and other possible controls for flammable gas hazards in waste transfer systems and the basis for selecting or not selecting specific controls are summarized in this report

A Cloud-Based System for Automatic Hazard Monitoring from Sentinel-1 SAR Data

Science.gov (United States)

Meyer, F. J.; Arko, S. A.; Hogenson, K.; McAlpin, D. B.; Whitley, M. A.

2017-12-01

Despite the all-weather capabilities of Synthetic Aperture Radar (SAR), and its high performance in change detection, the application of SAR for operational hazard monitoring was limited in the past. This has largely been due to high data costs, slow product delivery, and limited temporal sampling associated with legacy SAR systems. Only since the launch of ESA's Sentinel-1 sensors have routinely acquired and free-of-charge SAR data become available, allowing—for the first time—for a meaningful contribution of SAR to disaster monitoring. In this paper, we present recent technical advances of the Sentinel-1-based SAR processing system SARVIEWS, which was originally built to generate hazard products for volcano monitoring centers. We outline the main functionalities of SARVIEWS including its automatic database interface to Sentinel-1 holdings of the Alaska Satellite Facility (ASF), and its set of automatic processing techniques. Subsequently, we present recent system improvements that were added to SARVIEWS and allowed for a vast expansion of its hazard services; specifically: (1) In early 2017, the SARVIEWS system was migrated into the Amazon Cloud, providing access to cloud capabilities such as elastic scaling of compute resources and cloud-based storage; (2) we co-located SARVIEWS with ASF's cloud-based Sentinel-1 archive, enabling the efficient and cost effective processing of large data volumes; (3) we integrated SARVIEWS with ASF's HyP3 system (http://hyp3.asf.alaska.edu/), providing functionality such as subscription creation via API or map interface as well as automatic email notification; (4) we automated the production chains for seismic and volcanic hazards by integrating SARVIEWS with the USGS earthquake notification service (ENS) and the USGS eruption alert system. Email notifications from both services are parsed and subscriptions are automatically created when certain event criteria are met; (5) finally, SARVIEWS-generated hazard products are now

Vulnerability and risk of deltaic social-ecological systems exposed to multiple hazards.

Science.gov (United States)

Hagenlocher, Michael; Renaud, Fabrice G; Haas, Susanne; Sebesvari, Zita

2018-08-01

Coastal river deltas are hotspots of global change impacts. Sustainable delta futures are increasingly threatened due to rising hazard exposure combined with high vulnerabilities of deltaic social-ecological systems. While the need for integrated multi-hazard approaches has been clearly articulated, studies on vulnerability and risk in deltas either focus on local case studies or single hazards and do not apply a social-ecological systems perspective. As a result, vulnerabilities and risks in areas with strong social and ecological coupling, such as coastal deltas, are not fully understood and the identification of risk reduction and adaptation strategies are often based on incomplete assumptions. To overcome these limitations, we propose an innovative modular indicator library-based approach for the assessment of multi-hazard risk of social-ecological systems across and within coastal deltas globally, and apply it to the Amazon, Ganges-Brahmaputra-Meghna (GBM), and Mekong deltas. Results show that multi-hazard risk is highest in the GBM delta and lowest in the Amazon delta. The analysis reveals major differences between social and environmental vulnerability across the three deltas, notably in the Mekong and the GBM deltas where environmental vulnerability is significantly higher than social vulnerability. Hotspots and drivers of risk vary spatially, thus calling for spatially targeted risk reduction and adaptation strategies within the deltas. Ecosystems have been identified as both an important element at risk as well as an entry point for risk reduction and adaptation strategies. Copyright © 2018. Published by Elsevier B.V.

Lyotropic liquid crystalline phase behaviour in amphiphile-protic ionic liquid systems.

Science.gov (United States)

Chen, Zhengfei; Greaves, Tamar L; Fong, Celesta; Caruso, Rachel A; Drummond, Calum J

2012-03-21

Approximate partial phase diagrams for nine amphiphile-protic ionic liquid (PIL) systems have been determined by synchrotron source small angle X-ray scattering, differential scanning calorimetry and cross polarised optical microscopy. The binary phase diagrams of some common cationic (hexadecyltrimethyl ammonium chloride, CTAC, and hexadecylpyridinium bromide, HDPB) and nonionic (polyoxyethylene (10) oleyl ether, Brij 97, and Pluronic block copolymer, P123) amphiphiles with the PILs, ethylammonium nitrate (EAN), ethanolammonium nitrate (EOAN) and diethanolammonium formate (DEOAF), have been studied. The phase diagrams were constructed for concentrations from 10 wt% to 80 wt% amphiphile, in the temperature range 25 °C to >100 °C. Lyotropic liquid crystalline phases (hexagonal, cubic and lamellar) were formed at high surfactant concentrations (typically >50 wt%), whereas at thermal stability of the phases formed by these surfactants persisted to temperatures above 100 °C. The phase behaviour of amphiphile-PIL systems was interpreted by considering the PIL cohesive energy, liquid nanoscale order, polarity and ionicity. For comparison the phase behaviour of the four amphiphiles was also studied in water.

Desicion Support System For Natural Hazards

Science.gov (United States)

Vyazilov, E.

2009-04-01

recommendations should be reasonable. To resolve the above problems or to make them less significant it is necessary to develop decision support systems (DSS). DMs need not tables with initial data, analytical, forecasting and climatic information, but messages containing warnings on critical value accidence, information on probability of hazards, information on potential losses, and information on hazardous impacts and recommendations on decision making. DSS can do the following: take into account impacts on specific points and on the total area under consideration; allow for the effects of the environment on economic entities (objects) in any geographical region to be analyzed; distinguish impacts and changes caused both by different phenomena and by their combination; signal when objects are or can be in adverse environmental conditions, e.g. in the area affected by fog, storm, tropical cyclone or in the area where the probability of hazardous ice events is very high, etc. The main component of DSS is a knowledge base based on the following concept: if we know environmental conditions it is possible to predict potential impacts on the economy; if we know impacts it is possible to give a set of recommendations on how to prevent (reduce) losses or how to use natural resources most efficiently. Decision making criteria are safety of people and property, reduction of losses, increase of profit, materials saving, etc. Knowledge base is a set of rules formulated in a formalized way using if, that, else. If "Water level in S.-Petersburg >150 cm" that "To give out warning information "Hazards for building on coastal river Neva is possible" and recommendations "The valuable goods carry out in second floor" else "To switch another rule". To have a knowledge base in place it is necessary to: develop tools of identifying and getting knowledge from experts; arrange the information flow from available information systems (operational data, analyses, forecasts, climatic information) through

A system extinguishing a fire by insulating a liquid fuel

International Nuclear Information System (INIS)

Colome, Jacques; Duchene, Alain; Regnier, Jean.

1975-01-01

The invention refers to a system for quickly extinguishing a liquid fuel body on fire by insulating it completely from the ambient air. It applies particularly to the case of a high temperature liquid sodium sheet flowing accidentally from a circuit belonging to a fast neutron reactor. The system in question includes a lower receptacle for collecting the liquid fuel and a top cover shutting off the receptacle. This cover has inclined channels to take the liquid fuel flow and openings to allow this liquid through at the bottom end of the channels. These openings are closed by retractable shutters moving away under the pressure of the liquid in the channels and closing automatically after the liquid has flowed into the receptacle [fr

Using systems gaming to explore decision-making under uncertainty in natural hazard crises

Science.gov (United States)

McCaughey, Jamie W.; Finnigan, David

2017-04-01

Faced with uncertain scientific forecasts of a potential hazard, it is perhaps natural to wait and see. As we wait, uncertainties do decrease, but so do our options to minimise impacts of the hazard. This tradeoff is fundamental to preparing for natural hazards, yet difficult to communicate. Interactive systems gaming is one promising way forward. We are developing in-person interactive games, drawing on role-playing and other table-top scenario exercises in natural hazards, as well as on game-based modeling of complex systems. Our games model an unfolding natural hazard crisis (such as volcanic unrest or an approaching typhoon) as a complex social-physical system. Participants take on the roles of diverse stakeholder groups (including government, scientists, media, farmers, city residents, and others) with differing expertise, responsibilities, and priorities. Interactions among these groups play out in a context of decreasing scientific uncertainty and decreasing options for actions to reduce societal risk. Key design challenges are (1) to engage players without trivialising the real-world context; (2) to provide the right level of guidance for players to navigate the system; and (3) to enable players to face realistic tradeoffs and see realistic consequences of their choices, without feeling frustrated that the game is set up for them to fail. We will first prototype the games with general public and secondary-school participants, then adjust this for specialist groups working in disaster management. We will illustrate participatory systems gaming techniques in our presentation 'A toolkit of systems gaming techniques' in the companion EGU session EOS6: 'Perform! A platform to discuss art & science projects with live presentation'.

Base catalyzed decomposition of toxic and hazardous chemicals

International Nuclear Information System (INIS)

Rogers, C.J.; Kornel, A.; Sparks, H.L.

1991-01-01

There are vast amounts of toxic and hazardous chemicals, which have pervaded our environment during the past fifty years, leaving us with serious, crucial problems of remediation and disposal. The accumulation of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), ''dioxins'' and pesticides in soil sediments and living systems is a serious problem that is receiving considerable attention concerning the cancer-causing nature of these synthetic compounds.US EPA scientists developed in 1989 and 1990 two novel chemical Processes to effect the dehalogenation of chlorinated solvents, PCBs, PCDDs, PCDFs, PCP and other pollutants in soil, sludge, sediment and liquids. This improved technology employs hydrogen as a nucleophile to replace halogens on halogenated compounds. Hydrogen as nucleophile is not influenced by steric hinderance as with other nucleophile where complete dehalogenation of organohalogens can be achieved. This report discusses catalyzed decomposition of toxic and hazardous chemicals

Los Alamos Controlled Air Incinerator for hazardous chemical and mixed radioactive wastes

International Nuclear Information System (INIS)

Vavruska, J.S.; Borduin, L.C.; Hutchins, D.A.; Koenig, R.A.; Warner, C.L.

1986-01-01

The Los Alamos Controlled Air Incinerator (CAI) is currently the only radioactive waste incineration facility in the US permitted to treat polychlorinated biphenyls (PCBs). The CAI was developed in the mid-1970's as a demonstration system for volume reduction of transuranic (TRU) contaminated combustible solid wastes. It has since undergone additions and modifications to accommodate hazardous chemical wastes in response to a need within the Department of Energy (DOE) to treat mixed radioactive/chemical wastes. An overview of these additions which include a liquid feed system, a high intensity liquid injection burner, and an activated carbon adsorption unit is presented here. Also included is a discussion of the procedures required for Toxic Substances Control Act (TSCA) and Resource Conservation and Recovery Act (RCRA) permitting of the CAI

Passive versus active hazard detection and avoidance systems

Science.gov (United States)

Neveu, D.; Mercier, G.; Hamel, J.-F.; Simard Bilodeau, V.; Woicke, S.; Alger, M.; Beaudette, D.

2015-06-01

Upcoming planetary exploration missions will require advanced guidance, navigation and control technologies to reach landing sites with high precision and safety. Various technologies are currently in development to meet that goal. Some technologies rely on passive sensors and benefit from the low mass and power of such solutions while others rely on active sensors and benefit from an improved robustness and accuracy. This paper presents two different hazard detection and avoidance (HDA) system design approaches. The first architecture relies only on a camera as the passive HDA sensor while the second relies, in addition, on a Lidar as the active HDA sensor. Both options use in common an innovative hazard map fusion algorithm aiming at identifying the safest landing locations. This paper presents the simulation tools and reports the closed-loop software simulation results obtained using each design option. The paper also reports the Monte Carlo simulation campaign that was used to assess the robustness of each design option. The performance of each design option is compared against each other in terms of performance criteria such as percentage of success, mean distance to nearest hazard, etc. The applicability of each design option to planetary exploration missions is also discussed.

Review of Exploration Systems Development (ESD) Integrated Hazard Development Process. Appendices; Volume 2

Science.gov (United States)

Smiles, Michael D.; Blythe, Michael P.; Bejmuk, Bohdan; Currie, Nancy J.; Doremus, Robert C.; Franzo, Jennifer C.; Gordon, Mark W.; Johnson, Tracy D.; Kowaleski, Mark M.; Laube, Jeffrey R.

2015-01-01

The Chief Engineer of the Exploration Systems Development (ESD) Office requested that the NASA Engineering and Safety Center (NESC) perform an independent assessment of the ESD's integrated hazard development process. The focus of the assessment was to review the integrated hazard analysis (IHA) process and identify any gaps/improvements in the process (e.g. missed causes, cause tree completeness, missed hazards). This document contains the outcome of the NESC assessment.

Review of Exploration Systems Development (ESD) Integrated Hazard Development Process. Volume 1; Appendices

Science.gov (United States)

Smiles, Michael D.; Blythe, Michael P.; Bejmuk, Bohdan; Currie, Nancy J.; Doremus, Robert C.; Franzo, Jennifer C.; Gordon, Mark W.; Johnson, Tracy D.; Kowaleski, Mark M.; Laube, Jeffrey R.

2015-01-01

The Chief Engineer of the Exploration Systems Development (ESD) Office requested that the NASA Engineering and Safety Center (NESC) perform an independent assessment of the ESD's integrated hazard development process. The focus of the assessment was to review the integrated hazard analysis (IHA) process and identify any gaps/improvements in the process (e.g., missed causes, cause tree completeness, missed hazards). This document contains the outcome of the NESC assessment.

Systemic Liquidity Crisis with Dynamic Haircuts

OpenAIRE

Sever, Can

2014-01-01

In this paper, using network tools, I analyse systemic impacts of liquidity shocks in interbank market in case of endogenous haircuts. Gai, Haldane and Kapadia (2011) introduce a benchmark for liquidity crisis following haircut shocks, and Gorton and Metrick (2010) reveal the evidence from 2007-09 crisis for increasing haircuts with banking panic. In the benchmark model, I endogenize and update haircuts dynamically during the period of stress. The results significantly differ from...

Liquid hydrogen transfer pipes and level regulation systems

International Nuclear Information System (INIS)

Marquet, M.; Prugne, P.; Roubeau, P.

1961-01-01

Describes: 1) Transfer pipes - Plunging rods in liquid hydrogen Dewars; transfer pipes: knee-joint system for quick and accurate positioning of plunging Dewar rods; system's rods: combined valve and rod; valves are activated either by a bulb pressure or by a solenoid automatically or hand controlled. The latter allows intermittent filling. 2) Level regulating systems: Level bulbs: accurate to 1 or 4 m; maximum and minimum level bulbs: automatic control of the liquid hydrogen valve. (author) [fr

JANNAF 18th Propulsion Systems Hazards Subcommittee Meeting. Volume 1

Science.gov (United States)

Cocchiaro, James E. (Editor); Gannaway, Mary T. (Editor)

1999-01-01

This volume, the first of two volumes is a compilation of 18 unclassified/unlimited-distribution technical papers presented at the Joint Army-Navy-NASA-Air Force (JANNAF) 18th Propulsion Systems Hazards Subcommittee (PSHS) meeting held jointly with the 36th Combustion Subcommittee (CS) and 24th Airbreathing Propulsion Subcommittee (APS) meetings. The meeting was held 18-21 October 1999 at NASA Kennedy Space Center and The DoubleTree Oceanfront Hotel, Cocoa Beach, Florida. Topics covered at the PSHS meeting include: shaped charge jet and kinetic energy penetrator impact vulnerability of gun propellants; thermal decomposition and cookoff behavior of energetic materials; violent reaction; detonation phenomena of solid energetic materials subjected to shock and impact stimuli; and hazard classification, insensitive munitions, and propulsion systems safety.

Potential hazards in smoke-flavored fish

Science.gov (United States)

Lin, Hong; Jiang, Jie; Li, Donghua

2008-08-01

Smoking is widely used in fish processing for the color and flavor. Smoke flavorings have evolved as a successful alternative to traditional smoking. The hazards of the fish products treated by liquid-smoking process are discussed in this review. The smoke flavoring is one important ingredient in the smoke-flavored fish. This paper gives the definition of smoke flavorings and the hazard of polycyclic aromatic hydrocarbons (PAHs) residue in the smoke flavorings on the market. It gives also an assessment of chemical hazards such as carcinogenic PAHs, especially Benzo-[ a]pyrene, as well as biological hazards such as Listeria monocytogenes, Clostridium botulinum, histamine and parasites in smoke-flavored fish. The limitations in regulations or standards are discussed. Smoke flavored fish have lower content of PAHs as compared with the traditional smoking techniques if the PAHs residue in smoke flavorings is controlled by regulations or standards.

System-level hazard analysis using the sequence-tree method

International Nuclear Information System (INIS)

Huang, H.-W.; Shih Chunkuan; Yih Swu; Chen, M.-H.

2008-01-01

A system-level PHA using the sequence-tree method is presented to perform safety-related digital I and C system SSA. The conventional PHA involves brainstorming among experts on various portions of the system to identify hazards through discussions. However, since the conventional PHA is not a systematic technique, the analysis results depend strongly on the experts' subjective opinions. The quality of analysis cannot be appropriately controlled. Therefore, this study presents a system-level sequence tree based PHA, which can clarify the relationship among the major digital I and C systems. This sequence-tree-based technique has two major phases. The first phase adopts a table to analyze each event in SAR Chapter 15 for a specific safety-related I and C system, such as RPS. The second phase adopts a sequence tree to recognize the I and C systems involved in the event, the working of the safety-related systems and how the backup systems can be activated to mitigate the consequence if the primary safety systems fail. The defense-in-depth echelons, namely the Control echelon, Reactor trip echelon, ESFAS echelon and Monitoring and indicator echelon, are arranged to build the sequence-tree structure. All the related I and C systems, including the digital systems and the analog back-up systems, are allocated in their specific echelons. This system-centric sequence-tree analysis not only systematically identifies preliminary hazards, but also vulnerabilities in a nuclear power plant. Hence, an effective simplified D3 evaluation can also be conducted

Experimental study on desulfurization efficiency and gas-liquid mass transfer in a new liquid-screen desulfurization system

International Nuclear Information System (INIS)

Sun, Zhongwei; Wang, Shengwei; Zhou, Qulan; Hui, Shi'en

2010-01-01

This paper presents a new liquid-screen gas-liquid two-phase flow pattern with discarded carbide slag as the liquid sorbent of sulfur dioxide (SO 2 ) in a wet flue gas desulfurization (WFGD) system. On the basis of experimental data, the correlations of the desulfurization efficiency with flue gas flow rate, slurry flow rate, pH value of slurry and liquid-gas ratio were investigated. A non-dimensional empirical model was developed which correlates the mass transfer coefficient with the liquid Reynolds number, gas Reynolds number and liquid-gas ratio (L/G) based on the available experimental data. The kinetic reaction between the SO 2 and the carbide slag depends on the pressure distribution in this desulfurizing tower, gas liquid flow field, flue gas component, pH value of slurry and liquid-gas ratio mainly. The transient gas-liquid mass transfer involving with chemical reaction was quantified by measuring the inlet and outlet SO 2 concentrations of flue gas as well as the characteristics of the liquid-screen two-phase flow. The mass transfer model provides a necessary quantitative understanding of the hydration kinetics of sulfur dioxide in the liquid-screen flue gas desulfurization system using discarded carbide slag which is essential for the practical application. (author)

Goal-oriented failure analysis - a systems analysis approach to hazard identification

International Nuclear Information System (INIS)

Reeves, A.B.; Davies, J.; Foster, J.; Wells, G.L.

1990-01-01

Goal-Oriented Failure Analysis, GOFA, is a methodology which is being developed to identify and analyse the potential failure modes of a hazardous plant or process. The technique will adopt a structured top-down approach, with a particular failure goal being systematically analysed. A systems analysis approach is used, with the analysis being organised around a systems diagram of the plant or process under study. GOFA will also use checklists to supplement the analysis -these checklists will be prepared in advance of a group session and will help to guide the analysis and avoid unnecessary time being spent on identifying obvious failure modes or failing to identify certain hazards or failures. GOFA is being developed with the aim of providing a hazard identification methodology which is more efficient and stimulating than the conventional approach to HAZOP. The top-down approach should ensure that the analysis is more focused and the use of a systems diagram will help to pull the analysis together at an early stage whilst also helping to structure the sessions in a more stimulating way than the conventional techniques. GOFA will be, essentially, an extension of the HAZOP methodology. GOFA is currently being computerised using a knowledge-based systems approach for implementation. The Goldworks II expert systems development tool is being used. (author)

Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for Jatropha curcas biodiesel

International Nuclear Information System (INIS)

Silva, Juliana R.F.; Mazutti, Marcio A.; Voll, Fernando A.P.; Cardozo-Filho, Lúcio; Corazza, Marcos L.; Lanza, Marcelo; Priamo, Wagner L.; Vladimir Oliveira, J.

2013-01-01

Highlights: ► (Liquid + liquid) equilibrium data for multicomponent Jatropha curcas FAME and FAEE. ► Tie-lines, solubility curves (binodal curves) with low deviations from mass balance. ► Experimental data correlated with the UNIQUAC model. -- Abstract: Reported in this study are (liquid + liquid) equilibrium data for binary, ternary, and quaternary systems formed by fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) of Jatropha curcas oil, water, glycerol, methanol, and ethanol at temperatures of (303.15, 318.15, and 333.15) K. In general, all the systems investigated resulted in good agreement between phase compositions of crunodes of tie-lines, solubility curves (binodal curves) and overall compositions, hence indicating low deviations from mass balance. Experimental results were correlated with the UNIQUAC model, showing low deviations among experimental and calculated values

Glove corrosive liquid immersion and permeability study

International Nuclear Information System (INIS)

Middleton, H.W.

1977-01-01

The Occupational Safety and Health Administration's requirement for protective equipment for personnel working with chemical hazards resulted in a study of gloves used in work with corrosive liquids. Gloves of different materials and weights were tested using ASTM methods, in various corrosive liquids. Results show the best material for gloves used for different lengths of time in the liquids

Supercooled Liquid Water Content Instrument Analysis and Winter 2014 Data with Comparisons to the NASA Icing Remote Sensing System and Pilot Reports

Science.gov (United States)

King, Michael C.

2016-01-01

The National Aeronautics and Space Administration (NASA) has developed a system for remotely detecting the hazardous conditions leading to aircraft icing in flight, the NASA Icing Remote Sensing System (NIRSS). Newly developed, weather balloon-borne instruments have been used to obtain in-situ measurements of supercooled liquid water during March 2014 to validate the algorithms used in the NIRSS. A mathematical model and a processing method were developed to analyze the data obtained from the weather balloon soundings. The data from soundings obtained in March 2014 were analyzed and compared to the output from the NIRSS and pilot reports.

Application of salting-out effect equation to modelling of liquid-liquid distribution systems

International Nuclear Information System (INIS)

Pitsch, H.K.

1986-03-01

Physicochemical interpretation of salting-out is reviewed and effects of the medium on liquid-liquid distribution equilibria are described by two non-specific parameters of salting-out agents: total concentration of species in the aqueous phase and water activity. Thus extraction of a given constituent in various media can be forecasted with few data. Different uranyl and technetium (VII) extraction systems are analyzed to show the potentiality of the method. Coextraction of nitric acid and uranyl nitrate by tributyl phosphate is used to show the possibility of modelling complex distribution systems in industrial conditions [fr

Hazard Analysis Database Report

Energy Technology Data Exchange (ETDEWEB)

GAULT, G.W.

1999-10-13

The Hazard Analysis Database was developed in conjunction with the hazard analysis activities conducted in accordance with DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, for the Tank Waste Remediation System (TWRS) Final Safety Analysis Report (FSAR). The FSAR is part of the approved TWRS Authorization Basis (AB). This document describes, identifies, and defines the contents and structure of the TWRS FSAR Hazard Analysis Database and documents the configuration control changes made to the database. The TWRS Hazard Analysis Database contains the collection of information generated during the initial hazard evaluations and the subsequent hazard and accident analysis activities. The database supports the preparation of Chapters 3,4, and 5 of the TWRS FSAR and the USQ process and consists of two major, interrelated data sets: (1) Hazard Evaluation Database--Data from the results of the hazard evaluations; and (2) Hazard Topography Database--Data from the system familiarization and hazard identification.

21 CFR 862.2250 - Gas liquid chromatography system for clinical use.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Gas liquid chromatography system for clinical use... Instruments § 862.2250 Gas liquid chromatography system for clinical use. (a) Identification. A gas liquid chromatography system for clinical use is a device intended to separate one or more drugs or compounds from a...

75 FR 63774 - Pipeline Safety: Safety of On-Shore Hazardous Liquid Pipelines

Science.gov (United States)

2010-10-18

... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration 49 CFR Part... Pipelines AGENCY: Pipeline and Hazardous Materials Safety Administration (PHMSA), Department of... Gas Pipeline Safety Act of 1968, Public Law 90-481, delegated to DOT the authority to develop...

75 FR 60632 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Direct Final Rule

Science.gov (United States)

2010-10-01

... Waste Management System; Identification and Listing of Hazardous Waste; Direct Final Rule AGENCY... management and treatment of several F- and K-waste codes. These waste codes are F037, F038, K048, K049, K051... released from the waste, plausible and specific types of management of the petitioned waste, the quantities...

(Liquid + liquid), (solid + liquid), and (solid + liquid + liquid) equilibria of systems containing cyclic ether (tetrahydrofuran or 1,3-dioxolane), water, and a biological buffer MOPS

International Nuclear Information System (INIS)

Altway, Saidah; Taha, Mohamed; Lee, Ming-Jer

2015-01-01

Graphical abstract: - Highlights: • MOPS buffer induced liquid phase splitting for mixtures of water with THF or 1,3-dioxolane. • Phase boundaries of LLE, SLE, and SLLE were determined experimentally. • Tie-lines at LLE and at SLLE were also measured. • Phase diagrams of MOPS + water + THF or 1,3-dioxolane are prepared. • LLE tie-line data are correlated satisfactorily with the NRTL model. - Abstract: Two liquid phases were formed as the addition of a certain amount of biological buffer 3-(N-morpholino)propane sulfonic acid (MOPS) in the aqueous solutions of tetrahydrofuran (THF) or 1,3-dioxolane. To evaluate the feasibility of recovering the cyclic ethers from their aqueous solutions with the aid of MOPS, we determined experimentally the phase diagrams of the ternary systems of {cyclic ether (THF or 1,3-dioxolane) + water + MOPS} at T = 298.15 K under atmospheric pressure. In this study, the solubility data of MOPS in water and in the mixed solvents of water/cyclic ethers were obtained from the results of a series of density measurements, while the (liquid + liquid) and the (solid + liquid + liquid) phase boundaries were determined by visually inspection. Additionally, the tie-line results for (liquid + liquid) equilibrium (LLE) and for (solid + liquid + liquid) equilibrium (SLLE) were measured using an analytical method. The reliability of the experimental LLE tie-line results data was validated by using the Othmer–Tobias correlation. These LLE tie-line values were correlated well with the NRTL model. The phase diagrams obtained from this study reveal that MOPS is a feasible green auxiliary agent to recover the cyclic ethers from their aqueous solutions, especially for 1,3-dioxolane

Determination of triazine herbicides in juice samples by microwave-assisted ionic liquid/ionic liquid dispersive liquid-liquid microextraction coupled with high-performance liquid chromatography.

Science.gov (United States)

Su, Rui; Li, Dan; Wu, Lijie; Han, Jing; Lian, Wenhui; Wang, Keren; Yang, Hongmei

2017-07-01

A novel microextraction method, termed microwave-assisted ionic liquid/ionic liquid dispersive liquid-liquid microextraction, has been developed for the rapid enrichment and analysis of triazine herbicides in fruit juice samples by high-performance liquid chromatography. Instead of using hazardous organic solvents, two kinds of ionic liquids, a hydrophobic ionic liquid (1-hexyl-3-methylimidazolium hexafluorophosphate) and a hydrophilic ionic liquid (1-butyl-3-methylimidazolium tetrafluoroborate), were used as the extraction solvent and dispersion agent, respectively, in this method. The extraction procedure was induced by the formation of cloudy solution, which was composed of fine drops of 1-hexyl-3-methylimidazolium hexafluorophosphate dispersed entirely into sample solution with the help of 1-butyl-3-methylimidazolium tetrafluoroborate. In addition, an ion-pairing agent (NH 4 PF 6 ) was introduced to improve recoveries of the ionic liquid phase. Several experimental parameters that might affect the extraction efficiency were investigated. Under the optimum experimental conditions, the linearity for determining the analytes was in the range of 5.00-250.00 μg/L, with the correlation coefficients of 0.9982-0.9997. The practical application of this effective and green method is demonstrated by the successful analysis of triazine herbicides in four juice samples, with satisfactory recoveries (76.7-105.7%) and relative standard deviations (lower than 6.6%). In general, this method is fast, effective, and robust to determine triazine herbicides in juice samples. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

One- and zero-dimensional electron systems over liquid helium (Review article)

CERN Document Server

Kovdrya, Y Z

2003-01-01

Experimental and theoretical investigations of one-dimensional and zero-dimensional electron systems near the liquid helium surface are surveyed. The properties of electron states over the plane surface of liquid helium including thin layers of helium are considered. The methods of realization of one- and zero-dimensional electron systems are discussed, and the results of experimental and theoretical investigations of their properties are given. The experiments with localization processes in a quasi-one-dimensional electron systems on liquid helium are described. The collective effects in one-dimensional and quasi-one-dimensional electron systems are considered, and the point of possible application of low-dimensional electron systems on liquid helium in electron devices and quantum computers is discussed.

Quaternary isobaric (vapor + liquid + liquid) equilibrium and (vapor + liquid) equilibrium for the system (water + ethanol + cyclohexane + heptane) at 101.3 kPa

International Nuclear Information System (INIS)

Pequenin, Ana; Asensi, Juan Carlos; Gomis, Vicente

2011-01-01

Highlights: → Water-ethanol-cyclohexane-heptane and water-cyclohexane-heptane isobaric VLLE. → Isobaric experimental data were determined at 101.3 kPa. → A dynamic recirculating still with an ultrasonic homogenizer was used. → The quaternary system does not present quaternary azeotropes. - Abstract: Experimental isobaric (vapor + liquid + liquid) and (vapor + liquid) equilibrium data for the ternary system {water (1) + cyclohexane (2) + heptane (3)} and the quaternary system {water (1) + ethanol (2) + cyclohexane (3) + heptane (4)} were measured at 101.3 kPa. An all-glass, dynamic recirculating still equipped with an ultrasonic homogenizer was used to determine the VLLE. The results obtained show that the system does not present quaternary azeotropes. The point-by-point method by Wisniak for testing the thermodynamic consistency of isobaric measurements was used to test the equilibrium data.

(Liquid + liquid) equilibria of four alcohol–water systems containing 1,8-cineole at T = 298.15 K

International Nuclear Information System (INIS)

Li, Hengde; Feng, Zhangni; Wan, Li; Huang, Cheng; Zhang, Tianfei; Fang, Yanxiong

2016-01-01

Graphical abstract: (Liquid + liquid) equilibria of C_1–C_4 alcohol–water systems containing 1,8-cineole are presented. Distribution ratios of alcohol in the mixtures are examined. The immiscible region of the LLE systems is evaluated and discussed. - Highlights: • Ternary (liquid + liquid) equilibria containing 1,8-cineole are presented. • Distribution ratios of C_1–C_4 alcohol in the mixtures are examined. • The LLE values were correlated using the NRTL and UNIQUAC models. - Abstract: As an eco-friendly compound from essential oils, 1,8-cineole (cineole, eucalyptol) has the potential to replace the ozone depleting industrial solvents. This paper presents experimental (liquid + liquid) equilibrium (LLE) data for four alcohol–water systems containing 1,8-cineole. To evaluate the phase equilibrium properties of 1,8-cineole in aqueous alcohol mixtures, LLE values for the ternary systems (water + methanol or ethanol or 1-propanol or 1-butanol + 1,8-cineole) were determined with a tie-line method at T = 298.15 K under atmospheric pressure. The well-known Hand, Bachman and Othmer–Tobias equations were used to test the reliability of the experimental results. The binodal curves and distribution ratios of alcohol in the mixtures are shown and discussed. The experimental LLE values were satisfactorily correlated by the NRTL and UNIQUAC models.

Estimating hurricane hazards using a GIS system

Directory of Open Access Journals (Sweden)

A. Taramelli

2008-08-01

Full Text Available This paper develops a GIS-based integrated approach to the Multi-Hazard model method, with reference to hurricanes. This approach has three components: data integration, hazard assessment and score calculation to estimate elements at risk such as affected area and affected population. First, spatial data integration issues within a GIS environment, such as geographical scales and data models, are addressed. Particularly, the integration of physical parameters and population data is achieved linking remotely sensed data with a high resolution population distribution in GIS. In order to assess the number of affected people, involving heterogeneous data sources, the selection of spatial analysis units is basic. Second, specific multi-hazard tasks, such as hazard behaviour simulation and elements at risk assessment, are composed in order to understand complex hazard and provide support for decision making. Finally, the paper concludes that the integrated approach herein presented can be used to assist emergency management of hurricane consequences, in theory and in practice.

WE-G-BRA-06: Application of Systems and Control Theory-Based Hazard Analysis to Radiotherapy

Energy Technology Data Exchange (ETDEWEB)

Pawlicki, T [UC San Diego, La Jolla, CA (United States); Samost, A; Leveson, N [Massachusetts Institute of Technology, Cambridge, MA (United States)

2015-06-15

Purpose: The process of delivering radiation occurs in a complex socio-technical system heavily reliant on human operators. Furthermore, both humans and software are notoriously challenging to account for in traditional hazard analysis models. High reliability industries such as aviation have approached this problem through using hazard analysis techniques grounded in systems and control theory. The purpose of this work is to apply the Systems Theoretic Accident Model Processes (STAMP) hazard model to radiotherapy. In particular, the System-Theoretic Process Analysis (STPA) approach is used to perform a hazard analysis of a proposed on-line adaptive cranial radiosurgery procedure that omits the CT Simulation step and uses only CBCT for planning, localization, and treatment. Methods: The STPA procedure first requires the definition of high-level accidents and hazards leading to those accidents. From there, hierarchical control structures were created followed by the identification and description of control actions for each control structure. Utilizing these control structures, unsafe states of each control action were created. Scenarios contributing to unsafe control action states were then identified and translated into system requirements to constrain process behavior within safe boundaries. Results: Ten control structures were created for this new CBCT-only process which covered the areas of hospital and department management, treatment design and delivery, and vendor service. Twenty three control actions were identified that contributed to over 80 unsafe states of those control actions resulting in over 220 failure scenarios. Conclusion: The interaction of people, hardware, and software are highlighted through the STPA approach. STPA provides a hierarchical model for understanding the role of management decisions in impacting system safety so that a process design requirement can be traced back to the hazard and accident that it is intended to mitigate. Varian

Data liquidity in health information systems.

Science.gov (United States)

Courtney, Paul K

2011-01-01

In 2001, the Institute of Medicine report Crossing the Quality Chasm and the National Committee on Vital and Health Statistics report Information for Health were released, and they provided the context for the development of information systems used to support health-supporting processes. Both had as their goals, implicit or explicit, to ensure the right data are provided to the right person at the right time, which is one definition of "data liquidity." This concept has had some traction in recent years as a shorthand way to express a system property for health information technology, but there is not a well-defined characterization of what properties of a system or of its components give it better or worse data liquidity. This article looks at some recent work that help to identify those properties and perhaps can help to ground the concept with metrics that are assessable.

Expert systems for assisting the analysis of hazards

International Nuclear Information System (INIS)

Evrard, J.M.; Martinez, J.M.; Souchet, Y.

1990-01-01

The advantage of applying expert systems in the analysis of safety in the operation of nuclear power plants is discussed. Expert systems apply a method based on a common representation of nuclear power plants. The main steps of the method are summarized. The applications given concern in the following fields: the analysis of hazards in the electric power supplies of a gas-graphite power plant; the evaluation of the availability of safety procedures in a PWR power plant; the search for the sources of leakage in a PWR power plant. The analysis shows that expert systems are a powerful tool in the study of safety of nuclear power plants [fr

Development of a test system for high level liquid waste partitioning

Directory of Open Access Journals (Sweden)

Duan Wu H.

2015-01-01

Full Text Available The partitioning and transmutation strategy has increasingly attracted interest for the safe treatment and disposal of high level liquid waste, in which the partitioning of high level liquid waste is one of the critical technical issues. An improved total partitioning process, including a tri-alkylphosphine oxide process for the removal of actinides, a crown ether strontium extraction process for the removal of strontium, and a calixcrown ether cesium extraction process for the removal of cesium, has been developed to treat Chinese high level liquid waste. A test system containing 72-stage 10-mm-diam annular centrifugal contactors, a remote sampling system, a rotor speed acquisition-monitoring system, a feeding system, and a video camera-surveillance system was successfully developed to carry out the hot test for verifying the improved total partitioning process. The test system has been successfully used in a 160 hour hot test using genuine high level liquid waste. During the hot test, the test system was stable, which demonstrated it was reliable for the hot test of the high level liquid waste partitioning.

performance liquid chromatography

African Journals Online (AJOL)

user

2010-11-22

Nov 22, 2010 ... ISSN 1684–5315 © 2010 Academic Journals. Full Length Research Paper. Determination ... Key words: Processed food, high-performance liquid chromatography, acrylamide, health hazard. INTRODUCTION. In the year 2002, the ... potatoes, breakfast cereals etc. It was thus confirmed that acrylamide has ...

(Liquid + liquid) equilibrium for binary systems of N-formylmorpholine with alkanes

International Nuclear Information System (INIS)

Wang Zhengrong; Xia Shuqian; Ma Peisheng; Liu Tao; Han Kewei

2012-01-01

Highlights: ► The LLE data of four binary systems containing N-formylmorpholine were measured. ► Both NRTL and UNIQUAC models can fit the experimental data well. ► The new group interaction parameters of UNIFAC (Do) were regressed from the LLE data. ► The estimated result shows that the group interaction parameters and methods are reliable. - Abstract: (Liquid + liquid) equilibrium (LLE) data were determined for four binary systems containing N-formylmorpholine (NFM) and alkanes (3-methylpentane, heptane, nonane, and 2,2,4-trimethylpentane) over the temperature range from around 300 K to near 420 K using a set of newly designed equilibrium equipment. The compositions of both light and heavy phases were analyzed by gas chromatography. The mutual solubility increased as the temperature increased for all these systems. The binary (liquid + liquid) equilibrium data were correlated by the NRTL and UNIQUAC equations with temperature-dependent parameters. Both models correlate the experimental results well. Furthermore, the UNIFAC (Do) group contribution model was used to correlate and estimate the LLE data for NFM containing systems. Two methods of group division for NFM were used. NFM is treated as a single group: NFM group (method I) or divided into two groups: CHO and C 4 H 8 NO (method II), respectively. The group interaction parameters for CH 2 –NFM, or CH 2 –CHO and CH 2 –C 4 H 8 NO were fitted from the experimental LLE data. The UNIFAC (Do) model correlates the experimental data well. In addition, in order to develop UNIFAC (Do) group contribution model to estimate the LLE data of (NFM + cycloalkane) systems, some literature LLE data were used. The group interaction parameters for c-CH 2 –NFM, c-CH 2 –CHO and c-CH 2 –C 4 H 8 NO were correlated. Then these group interaction parameters were used to estimate the phase equilibrium data of binary systems in the literature by the UNIFAC (Do) model. The results showed that the estimated values are in

CANDU 6 liquid injection shutdown system waterhammer analysis using PTRAN

International Nuclear Information System (INIS)

Ko, Deuk Yoon; Kim, Eun Ki; Ko, Yong Sang; Park, Byung Ho; Kim, Seok Bum

1996-06-01

An in-core LOCA could result in flooding of the helium header in the liquid injection shutdown system. Flooding of the helium header will result in severe pressure transients (waterhammer) in the liquid injection shutdown system when the shutdown signal is initiated. To evaluate the impact of the dynamic effects of this event, a pressure transient analysis has been performed. This analysis is performed using PTRAN, which is a computer program based on the method of characteristics. The results of this analysis are used in the stress analysis of the piping and pipe supports to ensure that the liquid injection shutdown system can withstand the pressure transient loadings. This analysis report documents the results of waterhammer analysis performed for the liquid injection shutdown system for the Wolsung nuclear power plant unit 2, 3 and 4. 4 tabs., 11 figs., 15 refs. (Author)

CANDU 6 liquid injection shutdown system waterhammer analysis using PTRAN

Energy Technology Data Exchange (ETDEWEB)

Ko, Deuk Yoon; Kim, Eun Ki; Ko, Yong Sang; Park, Byung Ho; Kim, Seok Bum [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

1996-06-01

An in-core LOCA could result in flooding of the helium header in the liquid injection shutdown system. Flooding of the helium header will result in severe pressure transients (waterhammer) in the liquid injection shutdown system when the shutdown signal is initiated. To evaluate the impact of the dynamic effects of this event, a pressure transient analysis has been performed. This analysis is performed using PTRAN, which is a computer program based on the method of characteristics. The results of this analysis are used in the stress analysis of the piping and pipe supports to ensure that the liquid injection shutdown system can withstand the pressure transient loadings. This analysis report documents the results of waterhammer analysis performed for the liquid injection shutdown system for the Wolsung nuclear power plant unit 2, 3 and 4. 4 tabs., 11 figs., 15 refs. (Author).

Excimer fluorescence of liquid crystalline systems

Science.gov (United States)

Sakhno, Tamara V.; Khakhel, Oleg A.; Barashkov, Nikolay N.; Korotkova, Irina V.

1996-04-01

The method of synchronous scanning fluorescence spectroscopy shows a presence of dimers of pyrene in a polymeric matrix. The results suggest that excimer formation takes place with dimers in liquid crystalline systems.

Solid-Liquid and Liquid-Liquid Equilibrium in the Formamide-Acetophenone System.

Czech Academy of Sciences Publication Activity Database

Malijevská, I.; Sedláková, Zuzana; Řehák, K.; Vrbka, P.

2006-01-01

Roč. 71, 9 (2006) , s. 1350-1358 ISSN 0010-0765 Institutional research plan: CEZ:AV0Z40720504 Keywords : solid-liquid equilibria * liquid-liquid equilibria * metastable Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.881, year: 2006

21 CFR 862.2260 - High pressure liquid chromatography system for clinical use.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false High pressure liquid chromatography system for... Clinical Laboratory Instruments § 862.2260 High pressure liquid chromatography system for clinical use. (a) Identification. A high pressure liquid chromatography system for clinical use is a device intended to separate...

Intelligent systems for remote decommissioning in hazardous environments

International Nuclear Information System (INIS)

Drotning, W.D.; Bennett, P.C.

1991-01-01

This paper reports on investigation of advanced handling technologies utilizing intelligent machines being supported jointly by the U.S. Department of Energy Offices of Civilian Radioactive Waste Management and Environmental Restoration and Waste Management for automation of transportation package handling operations at nuclear facilities and of nuclear waste site remediation efforts. Handling operation requirements include identification, location, and health physics operations, followed by bolting/unbolting operations and package disassembly. To accommodate these operations and the diversity of packages, fast model-based automated programming and force feedback control of a robotic control has been demonstrated for application to hazardous material cleanup. In this application, a graphical interface is used to simulate and evaluate operator-controlled motions and provide telerobotic control of the system. Remote automated handling technologies developed through these programs have the potential to decrease worker exposure and increase efficiency during decommissioning activities in hazardous environments

Air conditioning systems as non-infectious health hazards inducing acute respiratory symptoms.

Science.gov (United States)

Gerber, Alexander; Fischer, Axel; Willig, Karl-Heinz; Groneberg, David A

2006-04-01

Chronic and acute exposure to toxic aerosols belongs to frequent causes of airway diseases. However, asthma attacks due to long-distance inhalative exposure to organic solvents, transmitted via an air condition system, have not been reported so far. The present case illustrates the possibility of air conditioning systems as non-infectious health hazards in occupational medicine. So far, only infectious diseases such as legionella pneumophila pneumonia have commonly been associated to air-conditioning exposures but physicians should be alert to the potential of transmission of toxic volatile substances via air conditioning systems. In view of the events of the 11th of September 2001 with a growing danger of large building terrorism which may even use air conditioning systems to transmit toxins, facility management security staff should be alerted to possible non-infectious toxic health hazards arising from air-conditioning systems.

Immobilisation of hazardous waste

International Nuclear Information System (INIS)

Cope, C.B.

1983-01-01

Hazardous waste, e.g. radioactive waste, particularly that containing caesium-137, is immobilised by mixing with cement and solidifiable organic polymeric material. When first mixed, the organic material is preferably liquid and at this time can be polymerisable or already polymerised. The hardening can result from cooling or further polymerisation e.g. cross-linking. The organic material may be wax, or a polyester which may be unsaturated and cross-linkable by reaction with styrene. (author)

Bireactor Electronuclear Systems with Liquid Cadmium Valve

CERN Document Server

Bznuni, S A; Zhamkochyan, V M; ASosnin, A N; Polanski, A; Khudaverdyan, A H

2002-01-01

Three main types of bireactor electronuclear systems are discussed. From the point of view of assuring high level of functional characteristics and safety bireactor electronuclear systems with booster using enriched uranium (20 %) and with a liquid cadmium valve appears to be the most effective. It is shown by means of Monte-Carlo modeling that such operation conditions can be achieved which lead to the destruction of the intermediate cadmium layer making the systems supercritical (k_{eff}>1). One can avoid the problem by using a special design of the liquid cadmium valve. In comparison with other nuclear systems (critical reactors, one-reactor electronuclear systems) cascade electronuclear systems have essential advantages allowing the decrease of the proton beam current by one order of magnitude and providing at same time the necessary level of power generation and neutron flux. Availability of both the thermal and fast cones allows one to transmute not only transuranics but also the fission products - cesi...

Review of Current Nuclear Vacuum System Technologies

International Nuclear Information System (INIS)

Carroll, M.; McCracken, J.; Shope, T.

2003-01-01

Nearly all industrial operations generate unwanted dust, particulate matter, and/or liquid wastes. Waste dust and particulates can be readily tracked to other work locations, and airborne particulates can be spread through ventilation systems to all locations within a building, and even vented outside the building - a serious concern for processes involving hazardous, radioactive, or nuclear materials. Several varieties of vacuum systems have been proposed and/or are commercially available for clean up of both solid and liquid hazardous and nuclear materials. A review of current technologies highlights both the advantages and disadvantages of the various systems, and demonstrates the need for a system designed to address issues specific to hazardous and nuclear material cleanup. A review of previous and current hazardous/nuclear material cleanup technologies is presented. From simple conventional vacuums modified for use in industrial operations, to systems specifically engineered for such purposes, the advantages and disadvantages are examined in light of the following criteria: minimal worker exposure; minimal secondary waste generation;reduced equipment maintenance and consumable parts; simplicity of design, yet fully compatible with all waste types; and ease of use. The work effort reviews past, existing and proposed technologies in light of such considerations. Accomplishments of selected systems are presented, including identified areas where technological improvements could be suggested

Liquid gating elastomeric porous system with dynamically controllable gas/liquid transport.

Science.gov (United States)

Sheng, Zhizhi; Wang, Honglong; Tang, Yongliang; Wang, Miao; Huang, Lizhi; Min, Lingli; Meng, Haiqiang; Chen, Songyue; Jiang, Lei; Hou, Xu

2018-02-01

The development of membrane technology is central to fields ranging from resource harvesting to medicine, but the existing designs are unable to handle the complex sorting of multiphase substances required for many systems. Especially, the dynamic multiphase transport and separation under a steady-state applied pressure have great benefits for membrane science, but have not been realized at present. Moreover, the incorporation of precisely dynamic control with avoidance of contamination of membranes remains elusive. We show a versatile strategy for creating elastomeric microporous membrane-based systems that can finely control and dynamically modulate the sorting of a wide range of gases and liquids under a steady-state applied pressure, nearly eliminate fouling, and can be easily applied over many size scales, pressures, and environments. Experiments and theoretical calculation demonstrate the stability of our system and the tunability of the critical pressure. Dynamic transport of gas and liquid can be achieved through our gating interfacial design and the controllable pores' deformation without changing the applied pressure. Therefore, we believe that this system will bring new opportunities for many applications, such as gas-involved chemical reactions, fuel cells, multiphase separation, multiphase flow, multiphase microreactors, colloidal particle synthesis, and sizing nano/microparticles.

Non-conventional solvents in liquid phase microextraction and aqueous biphasic systems.

Science.gov (United States)

An, Jiwoo; Trujillo-Rodríguez, María J; Pino, Verónica; Anderson, Jared L

2017-06-02

The development of rapid, convenient, and high throughput sample preparation approaches such as liquid phase microextraction techniques have been continuously developed over the last decade. More recently, significant attention has been given to the replacement of conventional organic solvents used in liquid phase microextraction techniques in order to reduce toxic waste and to improve selectivity and/or extraction efficiency. With these objectives, non-conventional solvents have been explored in liquid phase microextraction and aqueous biphasic systems. The utilized non-conventional solvents include ionic liquids, magnetic ionic liquids, and deep eutectic solvents. They have been widely used as extraction solvents or additives in various liquid phase microextraction modes including dispersive liquid-liquid microextraction, single-drop microextraction, hollow fiber-liquid phase microextraction, as well as in aqueous biphasic systems. This review provides an overview into the use of non-conventional solvents in these microextraction techniques in the past 5 years (2012-2016). Analytical applications of the techniques are also discussed. Copyright © 2017 Elsevier B.V. All rights reserved.

Microcontroller based automatic liquid poison addition control system

International Nuclear Information System (INIS)

Kapatral, R.S.; Ananthakrishnan, T.S.; Pansare, M.G.

1989-01-01

Microcontrollers are finding increasing applications in instrumentation where complex digital circuits can be substituted by a compact and simple circuit, thus enhancing the reliability. In addition to this, intelligence and flexibility can be incorporated. For applications not requiring large amount of read/write memory (RAM), microcontrollers are ideally suited since they contain programmable memory (Eprom), parallel input/output lines, data memory, programmable timers and serial interface ports in one chip. This paper describes the design of automatic liquid poison addition control system (ALPAS) using intel's 8 bit microcontroller 8751, which is used to generate complex timing control sequence signals for liquid poison addition to the moderator in a nuclear reactor. ALPAS monitors digital inputs coming from protection system and regulating system of a nuclear reactor and provides control signals for liquid poison addition for long term safe shutdown of the reactor after reactor trip and helps the regulating system to reduce the power of the reactor during operation. Special hardware and software features have been incorporated to improve performance and fault detection. (author)

76 FR 74709 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Final Exclusion

Science.gov (United States)

2011-12-01

..., including any sludge, spill residue, ash, emission control dust, or leachate, remains a hazardous waste... water for use as a cleaning agent. The slop oil waste is thereby diluted and hazardous constituents are... separation sludges that are listed as hazardous wastes due to benzene, benzo(a)pyrene, chrysene, lead and...

75 FR 78918 - Hazardous Waste Management System; Identification and Listing of Hazardous Waste; Removal of...

Science.gov (United States)

2010-12-17

... and Community Right-to-Know Act FDA Food and Drug Administration HSWA Hazardous and Solid Waste...(f)), and hazardous substances (40 CFR 302.4) based solely upon the evidence that it is a potential... subsequently identified as hazardous wastes in Sec. 261.33(f) based solely on their potential for carcinogenic...

(Liquid + liquid) equilibrium of {water + phenol + (1-butanol, or 2-butanol, or tert-butanol)} systems

International Nuclear Information System (INIS)

Hadlich de Oliveira, Leonardo; Aznar, Martin

2010-01-01

(Liquid + liquid) equilibrium (LLE) and binodal curve data were determined for the systems (water + phenol + tert-butanol) at T = 298.15 K, (water + phenol + 2-butanol) and (water + phenol + 1-butanol) at T = 298.15 K and T = 313.15 K by the combined techniques of densimetry and refractometry. Type I curve (for tert-butanol) and Type II curves (for 1- and 2-butanol) were found. The data were correlated with the NRTL model and the parameters estimated present root mean square deviations below 2% for the system with tert-butanol and lower than 0.8% for the other systems.

Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

OpenAIRE

Kubiczek Artur; Kamiński Władysław

2017-01-01

Room-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liqu...

Thermodynamic modeling of ternary and quaternary (liquid + liquid) systems containing water, FeCl3, HCl and diisopropyl ether

International Nuclear Information System (INIS)

Milosevic, Miran; Hendriks, Ilse; Smits, Ralph E.R.; Schuur, Boelo; Haan, André B. de

2013-01-01

Highlights: • Literature data from various sources was validated experimentally. • Ternary and quaternary (liquid + liquid) systems were successfully described with the NRTL model. • Some deflection at higher HCl concentrations between model and data. • Additional data verification proved correctness of the literature data. -- Abstract: Liquid–liquid extraction using ethers as solvents is a potentially energy saving alternative for the concentration of aqueous ferric chloride solutions. Adequate thermodynamic models that describe the behavior of the resulting quaternary systems (FeCl 3 , ether, acid and water) are not available in the literature. In this paper, the development of an equilibrium description applying the NRTL-model is presented, including experimental validation and fitting of the NRTL-parameters on the validated data. Equilibrium experiments were performed for the ternary systems (water + HCl + DiPE) and (water + FeCl 3 + DiPE) and the obtained data is in good agreement with the results from Maljkovic et al.[37] and Cambell et al.[39]. Experimental data of the quaternary system is taken from Maljkovic et al.[37]. The obtained binary interaction parameters to describe the (liquid + liquid) quaternary system (water + FeCl 3 + HCl + DiPE) and the constituting ternaries by the NRTL model are presented. Model predictions are in good agreement with the experimental data

J-SHIS - an integrated system for knowing seismic hazard information in Japan

Science.gov (United States)

Azuma, H.; Fujiwara, H.; Kawai, S.; Hao, K. X.; Morikawa, N.

2015-12-01

An integrated system of Japan seismic hazard information station (J-SHIS) was established in 2005 for issuing and exchanging information of the National Seismic Hazard Maps for Japan that are based on seismic hazard assessment (SHA). A simplified app, also named J-SHIS, for smartphones is popularly used in Japan based on the integrated system of http://www.j-shis.bosai.go.jp/map/?lang=en. "Smartphone tells hazard" is realized on a cellphone, a tablet and/or a PC. At a given spot, the comprehensive information of SHA map can be easily obtained as below: 1) A SHA probability at given intensity (JMA=5-, 5+, 6-, 6+) within 30 years. 2) A site amplification factor varies within 0.5 ~ 3.0 and expectation is 1 based on surface geology map information. 3) A depth of seismic basement down to ~3,000m based on deeper borehole and geological structure. 4) Scenario earthquake maps: By choosing an active fault, one got the average case for different parameters of the modeling. Then choose a case, you got the shaking map of intensity with color scale. "Seismic Hazard Karte tells more hazard" is another app based on website of http://www.j-shis.bosai.go.jp/labs/karte/. (1) For every mesh of 250m x 250m, professional service SHA information is provided over national-world. (2) With five ranks for eight items, comprehensive SHA information could be delivered. (3) Site amplification factor with an average index is given. (4) Deeper geologic structure modeling is provided with borehole profiling. (5) A SHA probability is assessed within 30 and/or 50 years for the given site. (6) Seismic Hazard curves are given for earthquake sources from inland active fault, subduction zone, undetermined and their summarization. (7) The JMA seismic intensities are assessed in long-term averaged periods of 500-years to ~100,000 years. The app of J-SHIS can be downloaded freely from http://www.j-shis.bosai.go.jp/app-jshis.

900-L liquid xenon cryogenic system operation for the MEG experiment

CERN Document Server

Haruyama, T; Mihara, S; Hisamatsu, Y; Iawamoto, W; Mori, T; Nishiguchi, H; Otani, W; Sawada, R; Uchiyama, Y; Nishitani, T

2009-01-01

A cryogenic system for the MEG (muon rare decay) experiment has started operation at the Paul Sherrer Institute in Zurich. The main part of the MEG detector is the 900-L liquid xenon calorimeter for gamma ray detection, equipped with 850 photo multipliers directly immersed in liquid xenon. A 200 W pulse tube cryocooler enabled LN2-free operation of this calorimeter. A liquid purification system; using a liquid pump and a zero boil-off 1000-L cryogenic buffer dewar is also included in the system. The first entire engineering run was carried out in November-December 2007 and satisfactory cryogenic performances were confirmed.

Liquid radioactive waste processing system for pressurized water reactor plants

International Nuclear Information System (INIS)

Anon.

1976-01-01

This Standard sets forth design, construction, and performance requirements, with due consideration for operation, of the Liquid Radioactive Waste Processing System for pressurized water reactor plants for design basis inputs. For the purpose of this Standard, the Liquid Radioactive Waste Processing System begins at the interfaces with the reactor coolant pressure boundary and the interface valve(s) in lines from other systems, or at those sumps and floor drains provided for liquid waste with the potential of containing radioactive material; and it terminates at the point of controlled discharge to the environment, at the point of interface with the waste solidification system, and at the point of recycle back to storage for reuse

Estimating inhalation hazards for space nuclear power systems

International Nuclear Information System (INIS)

Hoover, M.D.; Cuddihy, R.G.; Seiler, F.Z.

1989-01-01

Minimizing inhalation hazards is a major consideration in the design, development, transportation, handling, testing, storage, launch, use, and ultimate disposition of nuclear space power systems (NSPSs). An accidental dispersion of 238 Pu is of concern for missions involving the radioisotope thermoelectric generators (RTGs) or lightweight radioisotope heater units. Materials of concern for missions involving a nuclear reactor might include other radionuclides, such as uranium, or chemically toxic materials, such as beryllium or lithium. This paper provides an overview of some of the current approaches and uncertainties associated with estimating inhalation hazards from potential NSPS accidents. The question of whether inhalation risks can be acceptable for nuclear space power systems is still open and active. The inherently low toxicity of the uranium fuel of a space nuclear reactor is a desirable feature of that option. The extensive engineering and testing that have contributed to the current generation of plutonium RTGs provide a measure of confidence that dispersion of the RTG fuel would be unlikely in an accident. The use of nuclear reactors or RTGs in space, however, requires society to assume a risk (albeit low) for dispersion of the fuel material. It can be argued that any additional risks from the use of nuclear power in space are far less than the risks we face daily

Hazard ranking systems for chemical wastes and chemical waste sites

International Nuclear Information System (INIS)

Waters, R.D.; Parker, F.L.; Crutcher, M.R.

1991-01-01

Hazardous materials and substances have always existed in the environment. Mankind has evolved to live with some degree of exposure to toxic materials. Until recently the risk has been from natural toxins or natural background radiation. While rapid technological advances over the past few decades have improved the lifestyle of our society, they have also dramatically increased the availability, volume and types of synthetic and natural hazardous materials. Many of their effects are as yet uncertain. Products and manufacturing by-products that no longer serve a useful purpose are deemed wastes. For some waste products land disposal will always be their ultimate fate. Hazardous substances are often included in the waste products. One needs to classify wastes by degree of hazard (risk). Risk (degree of probability of loss) is usually defined for risk assessment as probability of an occurrence times the consequences of the occurrence. Perhaps even more important than the definition of risk is the choice of a risk management strategy. The choice of strategy will be strongly influenced by the decision criteria used. Those decision criteria could be utility (the greatest happiness of the greatest number), rights or technology based or some combination of the three. It is necessary to make such choices about the definition of risks and criteria for management. It is clear that these are social (i.e., political) and value choices and science has little to say on this matter. This is another example of what Alvin Weinberg has named Transcience where the subject matter is scientific and technical but the choices are social, political and moral. This paper shall deal only with the scientific and technical aspects of the hazardous waste problem to create a hazardous substances classification system

A review of the toxicity of biomass pyrolysis liquids formed at low temperatures

Energy Technology Data Exchange (ETDEWEB)

Diebold, J P [Thermalchemie, Inc., Lakewood, CO (United States)

1997-04-01

The scaleup of biomass fast pyrolysis systems to large pilot and commercial scales will expose an increasingly large number of personnel to potential health hazards, especially during the evaluation of the commercial use of the pyrolysis condensates. Although the concept of fast pyrolysis to optimize liquid products is relatively new, low-temperature pyrolysis processes have been used over the aeons to produce charcoal and liquid by-products, e.g., smoky food flavors, food preservatives, and aerosols containing narcotics, e.g., nicotine. There are a number of studies in the historical literature that concern the hazards of acute and long-term exposure to smoke and to the historical pyrolysis liquids formed at low temperatures. The reported toxicity of smoke, smoke food flavors, and fast pyrolysis oils is reviewed. The data found for these complex mixtures suggest that the toxicity may be less than that of the individual components. It is speculated that there may be chemical reactions that take place that serve to reduce the toxicity during aging. 81 refs.

Hazardous solvent substitution

International Nuclear Information System (INIS)

Twitchell, K.E.

1995-01-01

This article is an overview of efforts at INEL to reduce the generation of hazardous wastes through the elimination of hazardous solvents. To aid in their efforts, a number of databases have been developed and will become a part of an Integrated Solvent Substitution Data System. This latter data system will be accessible through Internet

Liquid Cooling System for CPU by Electroconjugate Fluid

Directory of Open Access Journals (Sweden)

Yasuo Sakurai

2014-06-01

Full Text Available The dissipated power of CPU for personal computer has been increased because the performance of personal computer becomes higher. Therefore, a liquid cooling system has been employed in some personal computers in order to improve their cooling performance. Electroconjugate fluid (ECF is one of the functional fluids. ECF has a remarkable property that a strong jet flow is generated between electrodes when a high voltage is applied to ECF through the electrodes. By using this strong jet flow, an ECF-pump with simple structure, no sliding portion, no noise, and no vibration seems to be able to be developed. And then, by the use of the ECF-pump, a new liquid cooling system by ECF seems to be realized. In this study, to realize this system, an ECF-pump is proposed and fabricated to investigate the basic characteristics of the ECF-pump experimentally. Next, by utilizing the ECF-pump, a model of a liquid cooling system by ECF is manufactured and some experiments are carried out to investigate the performance of this system. As a result, by using this system, the temperature of heat source of 50 W is kept at 60°C or less. In general, CPU is usually used at this temperature or less.

Radiological Hazard of Spallation Products in Accelerator-Driven System

International Nuclear Information System (INIS)

Saito, M.; Stankovskii, A.; Artisyuk, V.; Korovin, Yu.; Shmelev, A.; Titarenko, Yu.

2002-01-01

The central issue underlying this paper is related to elucidating the hazard of radioactive spallation products that might be an important factor affecting the design option of accelerator-driven systems (ADSs). Hazard analysis based on the concept of Annual Limit on Intake identifies alpha-emitting isotopes of rare earths (REs) (dysprosium, gadolinium, and samarium) as the dominant contributors to the overall toxicity of traditional (W, Pb, Pb-Bi) targets. The matter is addressed from several points of view: code validation to simulate their yields, choice of material for the neutron producing targets, and challenging the beam type. The paper quantitatively determines the domain in which the toxicity of REs exceeds that of polonium activation products broadly discussed now in connection with advertising lead-bismuth technology for the needs of ADSs

The Liquid Lithium Limiter control system on FTU

International Nuclear Information System (INIS)

Bertocchi, A.; Panella, M.; Vitale, V.; Sinibaldi, S.

2006-01-01

In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system configuration was installed for testing on the FTU tokamak. The liquid lithium flows through capillaries from a reservoir to the side facing the plasma to form a thin liquid lithium film. The system is composed of three stainless steel sections, which contain two thermocouples each. A heating system brings the Li temperature to about 200 o C allowing the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. [M. Apicella, G. Mazzitelli et al., First experiment with Lithium Limiter on FTU, 17 o International Conference on Plasma Surface Interaction in Controlled Fusion Devices, 22 - 26 May 2006, Hefei Anhui, China]. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22 TM modules and a CORBA/PHP/MySQL software architecture [A. Bertocchi, S. Podda, V. Vitale, Fusion Eng. Des. 74 (2005) 787-791]. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLab and Java environments respectively to monitor the lithium temperature coming from thermocouples - have been also implemented. The control system allows regulating the heater temperature in each section of the LLL to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During plasma operations the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink TM tool - has been realized. (author)

The automatic liquid nitrogen filling system for GDA detectors

Indian Academy of Sciences (India)

. Abstract. An indigenously developed automatic liquid nitrogen (LN2) filling system has been installed in gamma detector array (GDA) facility at Nuclear Science Centre. Electro-pneumatic valves are used for filling the liquid nitrogen into the ...

Application of an adaptive neuro-fuzzy inference system to ground subsidence hazard mapping

Science.gov (United States)

Park, Inhye; Choi, Jaewon; Jin Lee, Moung; Lee, Saro

2012-11-01

We constructed hazard maps of ground subsidence around abandoned underground coal mines (AUCMs) in Samcheok City, Korea, using an adaptive neuro-fuzzy inference system (ANFIS) and a geographical information system (GIS). To evaluate the factors related to ground subsidence, a spatial database was constructed from topographic, geologic, mine tunnel, land use, and ground subsidence maps. An attribute database was also constructed from field investigations and reports on existing ground subsidence areas at the study site. Five major factors causing ground subsidence were extracted: (1) depth of drift; (2) distance from drift; (3) slope gradient; (4) geology; and (5) land use. The adaptive ANFIS model with different types of membership functions (MFs) was then applied for ground subsidence hazard mapping in the study area. Two ground subsidence hazard maps were prepared using the different MFs. Finally, the resulting ground subsidence hazard maps were validated using the ground subsidence test data which were not used for training the ANFIS. The validation results showed 95.12% accuracy using the generalized bell-shaped MF model and 94.94% accuracy using the Sigmoidal2 MF model. These accuracy results show that an ANFIS can be an effective tool in ground subsidence hazard mapping. Analysis of ground subsidence with the ANFIS model suggests that quantitative analysis of ground subsidence near AUCMs is possible.

Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems

Directory of Open Access Journals (Sweden)

Elizabeth D. Kochly

2016-01-01

Full Text Available A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a kΔ process (i.e., a process in which ionization occurs with rearrangement, and the resulting rearranged carbocation intermediate reacts with the alcohol cosolvent via two competing pathways: nucleophilic attack or elimination of a proton. Five different ionic liquids and three different alcohol cosolvents were investigated to give a total of fifteen dual solvent systems. 1H-NMR analysis was used to determine relative amounts of elimination and substitution products. It was found, not surprisingly, that increasing the bulkiness of alcohol cosolvent led to increased elimination product. The change in the amount of elimination product with increasing ionic liquid concentration, however, varied greatly between ionic liquids. These differences correlate strongly, though not completely, to the Kamlet–Taft solvatochromic parameters of the hydrogen bond donating and accepting ability of the solvent systems. An additional factor playing into these differences is the bulkiness of the ionic liquid anion.

Expert system for liquid low-level waste management

International Nuclear Information System (INIS)

Ferrada, J.J.

1992-01-01

An expert system prototype has been developed to support system analysis activities at the Oak Ridge National Laboratory (ORNL) for waste management tasks. This expert system will aid in prioritizing radioactive waste streams for treatment and disposal by evaluating the severity and treatability of the problem as well as the final waste form. The objectives of the expert system development included: (1) collecting information on process treatment technologies for liquid low-level waste (LLLW) that can be incorporated in the knowledge base of the expert system, and (2) producing a prototype that suggests processes and disposal technologies for the ORNL LLLW system. The concept under which the expert system has been designed is integration of knowledge. There are many sources of knowledge (data bases, text files, simulation programs, etc.) that an expert would regularly consult in order to solve a problem of liquid waste management. The expert would normally know how to extract the information from these different sources of knowledge. The general scope of this project would be to include as much pertinent information as possible within the boundaries of the expert system. As a result, the user, who may not be an expert in every aspect of liquid waste management, may be able to apply the content of the information to a specific waste problem. This paper gives the methodological steps to develop the expert system under this general framework

A magnetic suspension system for measuring liquid density

Directory of Open Access Journals (Sweden)

Luz María Centeno González

2013-01-01

Full Text Available Density is a derived quantity of mass and length; it is defined as mass per volume unit and its SI unit is kg/m3. National metrology institutes have been designing and building their own magnetic suspension systems during the last 5 decades for making fluid density measurements; this has allowed them to carry out research into liquids and gases’ physical characteristics. This paper was aimed at designing and developing a magnetic suspension system for a magnetic balance used in determining liquid density to be used in CENAM’s metrology density laboratories.

Liquidity Risk and its Management in Lithuanian Banking System

Directory of Open Access Journals (Sweden)

Erika Bareikaitė

2014-04-01

Full Text Available Banks are the main part of financial sector in each economy and strength of banking system becomes vital for ensuringfavourable economic stability and growth. Recent failure of two commercial banks in Lithuania showed that managershaven’t evaluated liquidity risk or haven’t dealt with it properly. The tasks of the paper are to investigate Lithuanian banksposition towards liquidity risk, analyse what kind of management tools banks use for ensuring favourable position towardsliquidity and to explore the liquidity influence to profitability in Lithuanian banking sector. The article examines liquidity andits management processes in Lithuanian banking sector. Description of liquidity importance is presented. Liquidity risk and itsmeasurement as well as the ways of managing the above mentioned risk is analysed in the article. In order to analyse the relationshipbetween liquidity risk and profitability of banks, analysis of scientific literature, research synthesis and generalizationshave been made.

Refrigeration system with a compressor-pump unit and a liquid-injection desuperheating line

Science.gov (United States)

Gaul, Christopher J.

2001-01-01

The refrigeration system includes a compressor-pump unit and/or a liquid-injection assembly. The refrigeration system is a vapor-compression refrigeration system that includes an expansion device, an evaporator, a compressor, a condenser, and a liquid pump between the condenser and the expansion device. The liquid pump improves efficiency of the refrigeration system by increasing the pressure of, thus subcooling, the liquid refrigerant delivered from the condenser to the expansion device. The liquid pump and the compressor are driven by a single driving device and, in this regard, are coupled to a single shaft of a driving device, such as a belt-drive, an engine, or an electric motor. While the driving device may be separately contained, in a preferred embodiment, the liquid pump, the compressor, and the driving device (i.e., an electric motor) are contained within a single sealable housing having pump and driving device cooling paths to subcool liquid refrigerant discharged from the liquid pump and to control the operating temperature of the driving device. In another aspect of the present invention, a liquid injection assembly is included in a refrigeration system to divert liquid refrigerant from the discharge of a liquid pressure amplification pump to a compressor discharge pathway within a compressor housing to desuperheat refrigerant vapor to the saturation point within the compressor housing. The liquid injection assembly includes a liquid injection pipe with a control valve to meter the volume of diverted liquid refrigerant. The liquid injection assembly may also include a feedback controller with a microprocessor responsive to a pressure sensor and a temperature sensor both positioned between the compressor to operate the control valve to maintain the refrigerant at or near saturation.

(Liquid + liquid) phase behavior for systems containing (aromatic + TBA + methylcyclohexane)

International Nuclear Information System (INIS)

Ghanadzadeh, H.; Ghanadzadeh, A.

2004-01-01

The determination region of solubility of TBA (tert-butanol) with representative compounds of the gasoline was investigated experimentally at temperature of 298.2 K. Type 1 (liquid + liquid) phase diagrams were obtained for (methylcyclohexane + TBA + aromatic compounds). These results were correlated simultaneously by the UNIQUAC model. The values of the interaction parameters between each pair of components in the systems were obtained for the UNIQUAC model using the experimental result. The root mean square deviation (RMSD) between the observed and calculated mole percents was 1.88 for (methylcyclohexane + TBA + benzene), 2.45 for (methylcyclohexane + TBA + toluene) and 2.86 for (methylcyclohexane + TBA + ethylbenzene). The mutual solubility of methylcyclohexane and aromatic compounds (e.g., benzene toluene and ethylbenzene (BTE)) was also investigated by the addition of TBA at temperature of 298.2 K

Improved liquid waste processing system of PWR plant

International Nuclear Information System (INIS)

Suehiro, Kazuyasu

1977-01-01

Mitsubishi Heavy Industries, Ltd. has engaged in the improvement and enhancement of waste-processing facilities for PWR power stations, and recently established the improved processing system. With this system, it becomes possible to contain radioactive waste gas semi-permanently within plants and to recycle waste liquid after the treatment, thus to make the release of radioactive wastes practically zero. The improved system has the following features, namely the recycling system is adopted, drain is separated and each separated drain is treated by specialized process, the reboiler type evaporator and the reverse osmosis equipment are used, and the leakless construction is adopted for the equipments. The radioactive liquid wastes in PWR power stations are classified into coolant drain, drain from general equipments, chemical drain and cleaning water. The outline of the improved processing system and the newly developed equipments such as the reboiler type evaporator and the reverse osmosis equipment are explained. With the evaporator, the concentration rate of waste liquid can be raised to about three times, and foaming waste can be treated efficiently. The decontamination performance is excellent. The reverse osmosis treatment is stable and reliable method, and is useful for the treatment of cleaning water. It is also effective for concentrating treatment. The unmanned automatic operation is possible. (Kako, I.)

Cost optimization of a real-time GIS-based management system for hazardous waste transportation.

Science.gov (United States)

Zhu, Yun; Lin, Che-Jen; Zhong, Yilong; Zhou, Qing; Lin, Che-Jen; Chen, Chunyi

2010-08-01

In this paper, the design and cost analysis of a real-time, geographical information system (GIS) based management system for hazardous waste transportation are described. The implementation of such a system can effectively prevent illegal dumping and perform emergency responses during the transportation of hazardous wastes. A case study was conducted in Guangzhou, China to build a small-scale, real-time management system for waste transportation. Two alternatives were evaluated in terms of system capability and cost structure. Alternative I was the building of a complete real-time monitoring and management system in a governing agency; whereas alternative II was the combination of the existing management framework with a commercial Telematics service to achieve the desired level of monitoring and management. The technological framework under consideration included locating transportation vehicles using a global positioning system (GPS), exchanging vehicle location data via the Internet and Intranet, managing hazardous waste transportation using a government management system and responding to emergencies during transportation. Analysis of the cost structure showed that alternative II lowered the capital and operation cost by 38 and 56% in comparison with alternative I. It is demonstrated that efficient management can be achieved through integration of the existing technological components with additional cost benefits being achieved by streamlined software interfacing.

The Liquid Lithium Limiter control system on FTU

Energy Technology Data Exchange (ETDEWEB)

Bertocchi, A; Panella, M; Vitale, V [Associazione EURATOM- ENEA sulla Fusione, Via Enrico Fermi 45, I-00044 Frascati (RM) (Italy); Sinibaldi, S [Rome University ' ' Tor Vergata ' ' , Informatics, Systems and Production Dept., Via del Politecnico 1, 00133 Rome (Italy)

2006-07-01

In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system configuration was installed for testing on the FTU tokamak. The liquid lithium flows through capillaries from a reservoir to the side facing the plasma to form a thin liquid lithium film. The system is composed of three stainless steel sections, which contain two thermocouples each. A heating system brings the Li temperature to about 200 {sup o}C allowing the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. [M. Apicella, G. Mazzitelli et al., First experiment with Lithium Limiter on FTU, 17{sup o} International Conference on Plasma Surface Interaction in Controlled Fusion Devices, 22 - 26 May 2006, Hefei Anhui, China]. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22{sup TM} modules and a CORBA/PHP/MySQL software architecture [A. Bertocchi, S. Podda, V. Vitale, Fusion Eng. Des. 74 (2005) 787-791]. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLab and Java environments respectively to monitor the lithium temperature coming from thermocouples - have been also implemented. The control system allows regulating the heater temperature in each section of the LLL to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During plasma operations the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink{sup TM} tool - has been realized. (author)

Comparative technical-economical analysis of solar systems with liquid absorbent

International Nuclear Information System (INIS)

Kaloyanov, N.; Popova, I.

2005-01-01

An analyses of solar water heating systems with two types liquid absorbent is presented. A system with classic collector design is used for comparison. The dependence between the value of the collectors active area and the absorbent type, collectors slope and design parameters is discussed. Two economic indexes (payback period and index of actual net value, based on the electricity price) are used for comparison of the different variants of the system. The presented results shown that: 1) the payback period can be reduced twice if the collectors with liquid absorbent are used; 2) the index of actual net value of the systems using the collectors with fluid absorbent is about four times higher than this one with classic collectors; 3) the systems using distilled water like a liquid absorbent can not fulfil the requirements for the positive economic indicators

Liquid formation in the Y-Si-Al-O-N system

Energy Technology Data Exchange (ETDEWEB)

Redington Keely, W.; Redington, M.; Hampshire, S. [Limerick Univ. (Ireland). Materials Research Centre

2000-07-01

Some silicon nitride ceramics are sintered using a combination of Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3} additives to form a Y-Si-Al-O-N liquid that promotes densification and allows the {alpha}{yields}{beta} transformation to take place by solution/precipitation through the liquid which cools as an intergranular phase. The type and amount of additive determines the nature and quantity of the resulting grain boundary phase as indicated and this can affect high temperature strength, creep resistance and oxidation resistance. Thus it is important to understand the phase equilibria in these complex systems and then apply this knowledge to processing, the development of beneficial microstructures and the relationship between these and properties. One difficulty is that, for any particular composition, the quantity and composition of the liquid at the sintering temperature is not known accurately and a full compositional representation has not been achieved. This paper attempts to represent the liquid region at various temperatures in the Jaenecke prism of the Y-Si-Al-O-N system. Published information on liquid compositions, standardised into eq.% format, was combined with experimental data interpolated from the less well defined regions to build a composite picture of liquid in this system. Representation was achieved using a customised graphical environment, AutoCAD trademark. AutoLISP trademark routines combined with this drafting package allow data from multiple sources to be integrated. This results in a series of overlays which indicate the liquid region from its initial formation at 1335 C and its subsequent development at different ''milestone'' temperatures. At 1700 C the orthographic projections of the liquid region are combined to give a volume bounded by nurbs surfaces, using ALIAS trademark software, to enable visualisation of the proposed liquid region. (orig.)

Expert systems for the transportation of hazardous and radioactive materials

International Nuclear Information System (INIS)

Luce, C.E.; Clover, J.C.; Ferrada, J.J.

1994-01-01

Under the supervision of the Transportation Technologies Group which is in the Chemical Technology Division at Oak Ridge National Laboratory, an expert system prototype for the transportation and packaging of hazardous and radioactive materials has been designed and developed. The development of the expert system prototype focused on using the combination of hypermedia elements and the Visual Basic trademark programming language. Hypermedia technology uses software that allows the user to interact with the computing environment through many formats: text, graphics, audio, and full-motion video. With the use of hypermedia, a user-friendly prototype has been developed to sort through numerous transportation regulations, thereby leading to the proper packaging for the materials. The expert system performs the analysis of regulations that an expert in shipping information would do; only the expert system performs the work more quickly. Currently, enhancements in a variety of categories are being made to the prototype. These include further expansion of non-radioactive materials, which includes any material that is hazardous but not radioactive; and the addition of full-motion video, which will depict regulations in terms that are easy to understand and which will show examples of how to handle the materials when packaging them

Development of Liquid Propulsion Systems Testbed at MSFC

Science.gov (United States)

Alexander, Reginald; Nelson, Graham

2016-01-01

As NASA, the Department of Defense and the aerospace industry in general strive to develop capabilities to explore near-Earth, Cis-lunar and deep space, the need to create more cost effective techniques of propulsion system design, manufacturing and test is imperative in the current budget constrained environment. The physics of space exploration have not changed, but the manner in which systems are developed and certified needs to change if there is going to be any hope of designing and building the high performance liquid propulsion systems necessary to deliver crew and cargo to the further reaches of space. To further the objective of developing these systems, the Marshall Space Flight Center is currently in the process of formulating a Liquid Propulsion Systems testbed, which will enable rapid integration of components to be tested and assessed for performance in integrated systems. The manifestation of this testbed is a breadboard engine configuration (BBE) with facility support for consumables and/or other components as needed. The goal of the facility is to test NASA developed elements, but can be used to test articles developed by other government agencies, industry or academia. Joint government/private partnership is likely the approach that will be required to enable efficient propulsion system development. MSFC has recently tested its own additively manufactured liquid hydrogen pump, injector, and valves in a BBE hot firing. It is rapidly building toward testing the pump and a new CH4 injector in the BBE configuration to demonstrate a 22,000 lbf, pump-fed LO2/LCH4 engine for the Mars lander or in-space transportation. The value of having this BBE testbed is that as components are developed they may be easily integrated in the testbed and tested. MSFC is striving to enhance its liquid propulsion system development capability. Rapid design, analysis, build and test will be critical to fielding the next high thrust rocket engine. With the maturity of the

Study of Baffle Boundary and System Parameters on Liquid-Solid Coupling Vibration of Rectangular Liquid-Storage Structure

Directory of Open Access Journals (Sweden)

Wei Jing

2016-01-01

Full Text Available In order to study the vibration problem of liquid-solid coupling of rectangular liquid-storage structure with horizontal elastic baffle, ignoring the influence of surface gravity wave, two different velocity potential functions corresponding to the liquid above and below the elastic baffle are assumed; based on the theory of mathematical equation and energy method, the formulas of basic frequency of liquid-solid coupling vibration system are derived, the baffle joined to the tank wall with 3 kinds of boundary conditions, namely, four edges simply supported, two opposite edges clamped and two opposite edges simply supported, and four edges clamped; the influence rules of baffle length-width ratio, the ratio of baffle height to liquid level, baffle elastic modulus, baffle density, baffle thickness, and liquid density on the coupling vibration performance are studied. The results show that the frequency of the clamped boundary is minimum; the influences of baffle length-width ratio and relative height on the basic frequency are much greater than that of the other system parameters; the relation between baffle length-width ratio and the frequency is exponential, while baffle relative height has a parabola relation with the frequency; the larger the baffle length-width ratio, the closer the baffle to the liquid level; the coupling frequency will be reduced more obviously.

Hazardous materials management using a Cradle-to-Grave Tracking and Information System (CGTIS)

Energy Technology Data Exchange (ETDEWEB)

Kjeldgaard, E.; Fish, J.; Campbell, D.; Freshour, N.; Hammond, B.; Bray, O. [Sandia National Labs., Albuquerque, NM (United States); Hollingsworth, M. [Ogden Environmental & Energy Services Co., Inc., Albuquerque, NM (United States)

1995-03-01

Hazardous materials management includes interactions among materials, personnel, facilities, hazards, and processes of various groups within a DOE site`s environmental, safety & health (ES&H) and line organizations. Although each group is charged with addressing a particular aspect of these properties and interactions, the information it requires must be gathered into a coherent set of common data for accurate and consistent hazardous material management and regulatory reporting. It is these common data requirements which the Cradle-to-Grave Tracking and Information System (CGTIS) is designed to satisfy. CGTIS collects information at the point at which a process begins or a material enters a facility, and maintains that information, for hazards management and regulatory reporting, throughout the entire life-cycle by providing direct on-line links to a site`s multitude of data bases to bring information together into one common data model.

Hazardous materials management using a Cradle-to-Grave Tracking and Information System (CGTIS)

International Nuclear Information System (INIS)

Kjeldgaard, E.; Fish, J.; Campbell, D.; Freshour, N.; Hammond, B.; Bray, O.; Hollingsworth, M.

1995-03-01

Hazardous materials management includes interactions among materials, personnel, facilities, hazards, and processes of various groups within a DOE site's environmental, safety ampersand health (ES ampersand H) and line organizations. Although each group is charged with addressing a particular aspect of these properties and interactions, the information it requires must be gathered into a coherent set of common data for accurate and consistent hazardous material management and regulatory reporting. It is these common data requirements which the Cradle-to-Grave Tracking and Information System (CGTIS) is designed to satisfy. CGTIS collects information at the point at which a process begins or a material enters a facility, and maintains that information, for hazards management and regulatory reporting, throughout the entire life-cycle by providing direct on-line links to a site's multitude of data bases to bring information together into one common data model

Liquid-liquid equilibria for binary and ternary systems containing glycols, aromatic hydrocarbons, and water: Experimental measurements and modeling with the CPA EoS

DEFF Research Database (Denmark)

Folas, Georgios; Kontogeorgis, Georgios; Michelsen, Michael Locht

2006-01-01

Liquid-liquid equilibrium data of four binary glycol + aromatic hydrocarbon systems and three ternary systems containing water have been measured at atmospheric pressure. The measured systems are monoethylene glycol (MEG) + benzene or toluene, triethylene glycol (TEG) + benzene or toluene, MEG...... + water + benzene, MEG + water + toluene, and TEG + water + toluene. The binary systems are correlated with the Cubic-Plus-Association (CPA) equation of state while the ternary systems are predicted from interaction parameters obtained from the binary systems. Very satisfactory liquid-liquid equilibrium...... correlations are obtained for the binary systems using temperature-independent interaction parameters, while adequate predictions are achieved for multicomponent water + glycol + aromatic hydrocarbons systems when accounting for the solvation between the aromatic hydrocarbons and glycols or water....

Laser Safety and Hazard Analysis for the Trailer (B70) Based AURA Laser System

International Nuclear Information System (INIS)

AUGUSTONI, ARNOLD L.

2003-01-01

A laser safety and hazard analysis was performed for the AURA laser system based on the 2000 version of the American National Standards Institute's (ANSI) Standard Z136.1, for ''Safe Use of Lasers'' and the 2000 version of the ANSI Standard Z136.6, for ''Safe Use of Lasers Outdoors''. The trailer based AURA laser system is a mobile platform, which is used to perform laser interaction experiments and tests at various national test sites. The trailer (B70) based AURA laser system is generally operated on the United State Air Force Starfire Optical Range (SOR) at Kirtland Air Force Base (KAFB), New Mexico. The laser is used to perform laser interaction testing inside the laser trailer as well as outside the trailer at target sites located at various distances from the exit telescope. In order to protect personnel, who work inside the Nominal Hazard Zone (NHZ), from hazardous laser emission exposures it was necessary to determine the Maximum Permissible Exposure (MPE) for each laser wavelength (wavelength bands) and calculate the appropriate minimum Optical Density (OD min ) of the laser safety eyewear used by authorized personnel and the Nominal Ocular Hazard Distance (NOHD) to protect unauthorized personnel who may have violated the boundaries of the control area and enter into the laser's NHZ

Information System Hazard Analysis: A Method for Identifying Technology-induced Latent Errors for Safety.

Science.gov (United States)

Weber, Jens H; Mason-Blakley, Fieran; Price, Morgan

2015-01-01

Many health information and communication technologies (ICT) are safety-critical; moreover, reports of technology-induced adverse events related to them are plentiful in the literature. Despite repeated criticism and calls to action, recent data collected by the Institute of Medicine (IOM) and other organization do not indicate significant improvements with respect to the safety of health ICT systems. A large part of the industry still operates on a reactive "break & patch" model; the application of pro-active, systematic hazard analysis methods for engineering ICT that produce "safe by design" products is sparse. This paper applies one such method: Information System Hazard Analysis (ISHA). ISHA adapts and combines hazard analysis techniques from other safety-critical domains and customizes them for ICT. We provide an overview of the steps involved in ISHA and describe.

Hazardous chemical tracking system (HAZ-TRAC)

International Nuclear Information System (INIS)

Bramlette, J.D.; Ewart, S.M.; Jones, C.E.

1990-07-01

Westinghouse Idaho Nuclear Company, Inc. (WINCO) developed and implemented a computerized hazardous chemical tracking system, referred to as Haz-Trac, for use at the Idaho Chemical Processing Plant (ICPP). Haz-Trac is designed to provide a means to improve the accuracy and reliability of chemical information, which enhances the overall quality and safety of ICPP operations. The system tracks all chemicals and chemical components from the time they enter the ICPP until the chemical changes form, is used, or becomes a waste. The system runs on a Hewlett-Packard (HP) 3000 Series 70 computer. The system is written in COBOL and uses VIEW/3000, TurboIMAGE/DBMS 3000, OMNIDEX, and SPEEDWARE. The HP 3000 may be accessed throughout the ICPP, and from remote locations, using data communication lines. Haz-Trac went into production in October, 1989. Currently, over 1910 chemicals and chemical components are tracked on the system. More than 2500 personnel hours were saved during the first six months of operation. Cost savings have been realized by reducing the time needed to collect and compile reporting information, identifying and disposing of unneeded chemicals, and eliminating duplicate inventories. Haz-Trac maintains information required by the Superfund Amendment Reauthorization Act (SARA), the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and the Occupational Safety and Health Administration (OSHA)

Hazardous chemical tracking system (HAZ-TRAC)

Energy Technology Data Exchange (ETDEWEB)

Bramlette, J D; Ewart, S M; Jones, C E

1990-07-01

Westinghouse Idaho Nuclear Company, Inc. (WINCO) developed and implemented a computerized hazardous chemical tracking system, referred to as Haz-Trac, for use at the Idaho Chemical Processing Plant (ICPP). Haz-Trac is designed to provide a means to improve the accuracy and reliability of chemical information, which enhances the overall quality and safety of ICPP operations. The system tracks all chemicals and chemical components from the time they enter the ICPP until the chemical changes form, is used, or becomes a waste. The system runs on a Hewlett-Packard (HP) 3000 Series 70 computer. The system is written in COBOL and uses VIEW/3000, TurboIMAGE/DBMS 3000, OMNIDEX, and SPEEDWARE. The HP 3000 may be accessed throughout the ICPP, and from remote locations, using data communication lines. Haz-Trac went into production in October, 1989. Currently, over 1910 chemicals and chemical components are tracked on the system. More than 2500 personnel hours were saved during the first six months of operation. Cost savings have been realized by reducing the time needed to collect and compile reporting information, identifying and disposing of unneeded chemicals, and eliminating duplicate inventories. Haz-Trac maintains information required by the Superfund Amendment Reauthorization Act (SARA), the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and the Occupational Safety and Health Administration (OSHA).

Systems engineering implementation plan for the liquid effluents services program

International Nuclear Information System (INIS)

Lowe, S.S.

1995-01-01

A graded approach is being taken by the Liquid Effluents Services Program in implementing systems engineering because of the advanced state of the program. The approach is cost-effective and takes credit for related work already completed, yet retains the benefits of systems engineering. This plan describes how the Liquid Effluents Services Program will implement systems engineering so there is a common understanding. Systems engineering work to be performed and the products of that work are identified. The relation to the current planning process and integration with the sitewide systems engineering effort is described

Identification of chemical compounds in a liquid-liquid extraction system

International Nuclear Information System (INIS)

Ramirez C, F de M de la.

1980-01-01

The objective of the present work is to identify the chemical compounds that are distributed in a liquid-liquid extraction system in which the third phase is observed; for this purpose the FeCl 3 (0.12M) - HCl (8.43M) - Diisopropilic ether - system was used, for the quantitative determination of the chemical compounds, FeCl 3 solutions labelled with 59 Fe or witH 38 Cl were used; the Karl Fischer method for the determination of the water concentration at the organic phases was used, the obtained data was used for the calculations of the H + distribution in each phase. The results are that when the distribution equilibrium is reached, the aqueous phase is a 7.5M HCl solution; the light organic phase contains 2 H[FeCl 4 ].6H 2 O and the dense organic phase contains 2 H[FeCl 4 ].6H 2 O.3HCl.12H 2 O. The differences between these compounds are due to a high concentration of water and the HCl in the organic solvent. This causes a heterogeneous physic field, and then the third phase formation. (author)

Implementation of health and safety management system to reduce hazardous potential in PT.XYZ Indonesia

Science.gov (United States)

Widodo, L.; Adianto; Sartika, D. I.

2017-12-01

PT. XYZ is a large automotive manufacturing company that manufacture, assemble as well as a car exporter. The other products are spare parts, jig and dies. PT. XYZ has long been implementing the Occupational Safety and Health Management System (OSHMS) to reduce the potential hazards that cause work accidents. However, this does not mean that OSHMS that has been implemented does not need to be upgraded and improved. This is due to the potential danger caused by work is quite high. This research was conducted in Sunter 2 Plant where its production activities have a high level of potential hazard. Based on Hazard Identification risk assessment, Risk Assessment, and Risk Control (HIRARC) found 10 potential hazards in Plant Stamping Production, consisting of 4 very high risk potential hazards (E), 5 high risk potential hazards (H), and 1 moderate risk potential hazard (M). While in Plant Casting Production found 22 potential hazards findings consist of 7 very high risk potential hazards (E), 12 high risk potential hazards (H), and 3 medium risk potential hazards (M). Based on the result of Fault Tree Analysis (FTA), the main priority is the high risk potential hazards (H) and very high risk potential hazards (E). The proposed improvement are to make the visual display of the importance of always using the correct Personal Protective Equipment (PPE), establishing good working procedures, conducting OSH training for workers on a regular basis, and continuing to conduct safety campaigns.

Ternary (liquid + liquid) equilibria of {trifluorotris(perfluoroethyl)phosphate based ionic liquids + thiophene + heptane}

International Nuclear Information System (INIS)

Marciniak, Andrzej; Królikowski, Marek

2012-01-01

Highlights: ► Ternary (liquid + liquid) equilibria for 3 ionic liquid + thiophene + heptane systems. ► The influence of ionic liquid structure on phase diagrams is discussed. ► High selectivity for separation of heptane/thiophene is observed. - Abstract: Ternary (liquid + liquid) equilibria for three systems containing ionic liquids {(4-(2-methoxyethyl)-4-methylmorpholinium trifluorotris(perfluoroethyl)phosphate, 1-(2-methoxyethyl)-1-methylpiperidinium trifluorotris(perfluoroethyl)phosphate, 1-(2-methoxyethyl)-1-methylpyrrolidinium trifluorotris(perfluoroethyl)phosphate) + thiophene + heptane} have been determined at T = 298.15 K. All systems showed high solubility of thiophene in the ionic liquid and low solubility of heptane. The solute distribution coefficient and the selectivity were calculated for all systems. High values of selectivity were obtained. The experimental results have been correlated using NRTL model. The influence of ionic liquid structure on phase equilibria is discussed.

Evaluation of a contact device type ejector system for liquid-liquid extraction

International Nuclear Information System (INIS)

Schwamback, Niomedes

2002-04-01

The objective of the present work was to evaluate an ejector system, operated simultaneously with two immiscible liquid phases and a gas phase, as a contact device for liquid-liquid extraction processes. The ejector, made of perspex, has a variable geometry, although this feature was not explored in the thesis. Motivated by recent uses of liquid-liquid extraction processes for the removal of traces of heavy metal from waste waters, it was decided to carry out tests with synthetic effluents. This strategy, typical of experimental work under evaluation of technical feasibility, greatly simplifies experiments, since the nature of the chemical species involved and their feed concentrations are known exactly and do not fluctuate. The extractant used was DEHPA (diethyl hexyl phosphoric acid). The metal chosen for tests was iron with oxidation number +3, because of its high extraction coefficient towards DEHPA and also for its chemical behavior similar to americium and other heavy metals. In addition to that, iron forms soluble coloured complexes adequate to spectrophotometric determination analysis, a simple, quick and very reliable analytical technique. The effects of electrolytes of interest, namely NaCl, FeSO 4 and Al(NO 3 ) 3 , upon the extraction process were investigated. The effects resulting from the introduction of a gas phase, actually air (bubbles), in the ejector upon the extraction efficiency were studied. By coupling advanced digital photographic technique and image analysis with microcomputer, the bubble mean size was measured. It was then correlated with equipment's geometrical (characteristic diameters) and operational variables (phases' flow rates and gas hold-ups). To enable scale-up procedures, data were preferably correlated by means of dimensionless groups. For the systems and conditions investigated in this thesis and under the same operational conditions, the introduction of air bubbles by means of an ejector has greatly improved the process

The finite-size effect in thin liquid crystal systems

Science.gov (United States)

Śliwa, I.

2018-05-01

Effects of surface ordering in liquid crystal systems confined between cell plates are of great theoretical and experimental interest. Liquid crystals introduced in thin cells are known to be strongly stabilized and ordered by cell plates. We introduce a new theoretical method for analyzing the effect of surfaces on local molecular ordering in thin liquid crystal systems with planar geometry of the smectic layers. Our results show that, due to the interplay between pair long-range intermolecular forces and nonlocal, relatively short-range, surface interactions, both orientational and translational orders of liquid crystal molecules across confining cells are very complex. In particular, it is demonstrated that the SmA, nematic, and isotropic phases can coexist. The phase transitions from SmA to nematic, as well as from nematic to isotropic phases, occur not simultaneously in the whole volume of the system but begin to appear locally in some regions of the LC sample. Phase transition temperatures are demonstrated to be strongly affected by the thickness of the LC system. The dependence of the corresponding shifts of phase transition temperatures on the layer number is shown to exhibit a power law character. This new type of scaling behavior is concerned with the coexistence of local phases in finite systems. The influence of a specific character of interactions of molecules with surfaces and other molecules on values of the resulting critical exponents is also analyzed.

Mechanically assisted liquid lens zoom system for mobile phone cameras

Science.gov (United States)

Wippermann, F. C.; Schreiber, P.; Bräuer, A.; Berge, B.

2006-08-01

Camera systems with small form factor are an integral part of today's mobile phones which recently feature auto focus functionality. Ready to market solutions without moving parts have been developed by using the electrowetting technology. Besides virtually no deterioration, easy control electronics and simple and therefore cost-effective fabrication, this type of liquid lenses enables extremely fast settling times compared to mechanical approaches. As a next evolutionary step mobile phone cameras will be equipped with zoom functionality. We present first order considerations for the optical design of a miniaturized zoom system based on liquid-lenses and compare it to its mechanical counterpart. We propose a design of a zoom lens with a zoom factor of 2.5 considering state-of-the-art commercially available liquid lens products. The lens possesses auto focus capability and is based on liquid lenses and one additional mechanical actuator. The combination of liquid lenses and a single mechanical actuator enables extremely short settling times of about 20ms for the auto focus and a simplified mechanical system design leading to lower production cost and longer life time. The camera system has a mechanical outline of 24mm in length and 8mm in diameter. The lens with f/# 3.5 provides market relevant optical performance and is designed for an image circle of 6.25mm (1/2.8" format sensor).

Rational approach to solvent system selection for liquid-liquid extraction-assisted sample pretreatment in counter-current chromatography.

Science.gov (United States)

Wang, Jiajia; Gu, Dongyu; Wang, Miao; Guo, Xinfeng; Li, Haoquan; Dong, Yue; Guo, Hong; Wang, Yi; Fan, Mengqi; Yang, Yi

2017-05-15

A rational liquid-liquid extraction approach was established to pre-treat samples for high-speed counter-current chromatography (HSCCC). n-Hexane-ethyl acetate-methanol-water (4:5:4:5, v/v) and (1:5:1:5, v/v) were selected as solvent systems for liquid-liquid extraction by systematically screening K of target compounds to remove low- and high-polarity impurities in the sample, respectively. After liquid-liquid extraction was performed, 1.4g of crude sample II was obtained from 18.5g of crude sample I which was extracted from the flowers of Robinia pseudoacacia L., and then separated with HSCCC by using a solvent system composed of n-hexane-ethyl acetate-methanol-water (1:2:1:2, v/v). As a result, 31mg of robinin and 37mg of kaempferol 7-O-α-l-rhamnopyranoside were isolated from 200mg of crude sample II in a single run of HSCCC. A scale-up separation was also performed, and 160mg of robinin with 95% purity and 188mg of kaempferol 7-O-α-l-rhamnopyranoside with 97% purity were produced from 1.2g of crude sample II. Copyright © 2017 Elsevier B.V. All rights reserved.

The Liquid Annular Reactor System (LARS) propulsion

International Nuclear Information System (INIS)

Powell, J.; Ludewig, H.; Horn, F.; Lenard, R.

1990-01-01

A concept for very high specific impulse (greater than 2000 seconds) direct nuclear propulsion is described. The concept, termed the liquid annular reactor system (LARS), uses liquid nuclear fuel elements to heat hydrogen propellant to very high temperatures (approximately 6000 K). Operating pressure is moderate (approximately 10 atm), with the result that the outlet hydrogen is virtually 100 percent dissociated to monatomic H. The molten fuel is contained in a solid container of its own material, which is rotated to stabilize the liquid layer by centripetal force. LARS reactor designs are described, together with neutronic and thermal-hydraulic analyses. Power levels are on the order of 200 megawatts. Typically, LARS designs use seven rotating fuel elements, are beryllium moderated, and have critical radii of approximately 100 cm (core L/D approximately equal to 1.5)

Environmental risk analysis of hazardous material rail transportation

Energy Technology Data Exchange (ETDEWEB)

Saat, Mohd Rapik, E-mail: mohdsaat@illinois.edu [Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, 1243 Newmark Civil Engineering Laboratory, 205 North Mathews Avenue, Urbana, IL 61801 (United States); Werth, Charles J.; Schaeffer, David [Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, 1243 Newmark Civil Engineering Laboratory, 205 North Mathews Avenue, Urbana, IL 61801 (United States); Yoon, Hongkyu [Sandia National Laboratories, Albuquerque, NM 87123 (United States); Barkan, Christopher P.L. [Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, 1243 Newmark Civil Engineering Laboratory, 205 North Mathews Avenue, Urbana, IL 61801 (United States)

2014-01-15

Highlights: • Comprehensive, nationwide risk assessment of hazardous material rail transportation. • Application of a novel environmental (i.e. soil and groundwater) consequence model. • Cleanup cost and total shipment distance are the most significant risk factors. • Annual risk varies from $20,000 to $560,000 for different products. • Provides information on the risk cost associated with specific product shipments. -- Abstract: An important aspect of railroad environmental risk management involves tank car transportation of hazardous materials. This paper describes a quantitative, environmental risk analysis of rail transportation of a group of light, non-aqueous-phase liquid (LNAPL) chemicals commonly transported by rail in North America. The Hazardous Materials Transportation Environmental Consequence Model (HMTECM) was used in conjunction with a geographic information system (GIS) analysis of environmental characteristics to develop probabilistic estimates of exposure to different spill scenarios along the North American rail network. The risk analysis incorporated the estimated clean-up cost developed using the HMTECM, route-specific probability distributions of soil type and depth to groundwater, annual traffic volume, railcar accident rate, and tank car safety features, to estimate the nationwide annual risk of transporting each product. The annual risk per car-mile (car-km) and per ton-mile (ton-km) was also calculated to enable comparison between chemicals and to provide information on the risk cost associated with shipments of these products. The analysis and the methodology provide a quantitative approach that will enable more effective management of the environmental risk of transporting hazardous materials.

Environmental risk analysis of hazardous material rail transportation

International Nuclear Information System (INIS)

Saat, Mohd Rapik; Werth, Charles J.; Schaeffer, David; Yoon, Hongkyu; Barkan, Christopher P.L.

2014-01-01

Highlights: • Comprehensive, nationwide risk assessment of hazardous material rail transportation. • Application of a novel environmental (i.e. soil and groundwater) consequence model. • Cleanup cost and total shipment distance are the most significant risk factors. • Annual risk varies from $20,000 to $560,000 for different products. • Provides information on the risk cost associated with specific product shipments. -- Abstract: An important aspect of railroad environmental risk management involves tank car transportation of hazardous materials. This paper describes a quantitative, environmental risk analysis of rail transportation of a group of light, non-aqueous-phase liquid (LNAPL) chemicals commonly transported by rail in North America. The Hazardous Materials Transportation Environmental Consequence Model (HMTECM) was used in conjunction with a geographic information system (GIS) analysis of environmental characteristics to develop probabilistic estimates of exposure to different spill scenarios along the North American rail network. The risk analysis incorporated the estimated clean-up cost developed using the HMTECM, route-specific probability distributions of soil type and depth to groundwater, annual traffic volume, railcar accident rate, and tank car safety features, to estimate the nationwide annual risk of transporting each product. The annual risk per car-mile (car-km) and per ton-mile (ton-km) was also calculated to enable comparison between chemicals and to provide information on the risk cost associated with shipments of these products. The analysis and the methodology provide a quantitative approach that will enable more effective management of the environmental risk of transporting hazardous materials

Experimental performance of indirect air–liquid membrane contactors for liquid desiccant cooling systems

International Nuclear Information System (INIS)

Das, Rajat Subhra; Jain, Sanjeev

2013-01-01

Owing to the stringent indoor air quality (IAQ) requirements and high cost of desiccants, one of the major concerns in liquid desiccant technology has been the carryover, which can be eliminated through indirect contact between desiccant and air. Membrane contactors using microporous semipermeable hydrophobic membranes have a great potential in this regard. This communication investigates the performance of semipermeable membrane based indirect contactors as dehumidifiers in liquid desiccant cooling applications. Experiments on different types of membrane contactors are carried out using lithium chloride (LiCl) solution as desiccant. The membrane contactors consist of alternate channels of air and liquid desiccant flowing in cross-flow direction. Hydrophobic membranes form a liquid tight, vapor permeable porous barrier between hygroscopic solution and moist air, thus eliminating carryover of desiccant droplets. In order to provide maximum contact area for air–desiccant interaction, a wicking material is sandwiched between two membranes in the liquid channel. It is observed that vapor flux upto 1300 g/m 2 h can be achieved in a membrane contactor with polypropylene (PP) membranes, although the dehumidification effectiveness remains low. The effect of key parameters on the transmembrane vapor transport is presented in the paper. - Highlights: • Indirect membrane contactors developed to avoid carryover in liquid desiccant system. • Dehumidification effectiveness and vapor flux reported under varying conditions. • Vapor flux upto 1295 g/m 2 h in polypropylene contactor with high area density. • Dehumidification effectiveness with LiCl solution varies within 23% to 45%

Latent hazard related to a hydrogen liquefaction installation

International Nuclear Information System (INIS)

Spoendlin, R.

1961-01-01

In this note, the author reports an attempt of analysis of hazards which could be related to a hydrogen liquefaction installation in order to identify the most appropriate safety measures. In order to do so, experiments have been performed on electrostatic charges born by solid crystals in liquid hydrogen, and explosion tests have been performed on a mixture of solid oxygen and liquid hydrogen. Moreover, the author tried to analyse accidents which occurred in this field by performing a survey among scientists working in laboratories in different countries

Competition, liquidity and stability: international evidence at the bank and systemic levels

OpenAIRE

Nguyen, Thi Ngoc My

2017-01-01

This thesis investigates the impact of market power on bank liquidity; the association between competition and systemic liquidity; and whether the associations between liquidity and stability at both bank- and systemic- levels are affected by competition. The first research question is explored in the context of 101 countries over 1996-2013 while the second and the third, which require listed banks, use a smaller sample of 32 nations during 2001-2013. The Panel Least Squares and the system Ge...

Nuclear-station post-accident liquid-sampling system: developed by Duke Power Company

International Nuclear Information System (INIS)

Burton, D.A.; Birch, M.L.; Orth, W.C.

1981-01-01

The accident at Three Mile Island showed that means must be provided to determine the radioactivity levels in high activity liquid and gaseous systems of a nuclear power plant without undue radiation exposure to personnel. The Duke Power Post Accident Liquid Sampling System provides the means for obtaining diluted liquid samples and diluted dissolved gas samples following a reactor accident involving substantial core damage. Their approach yields a straightforward engineering solution at a fraction of the cost of other systems. A description of the system, general design criteria, and color coded flow diagrams are included

The liquid lithium limiter control system on FTU

Energy Technology Data Exchange (ETDEWEB)

Bertocchi, A. [EURATOM-ENEA Association, Frascati Research Center, Via E. Fermi 45, 00044 Frascati (Rome) (Italy)], E-mail: bertocchi@frascati.enea.it; Di Donna, M [Department of Informatics, Systems and Productions, University of Rome Tor Vergata, Rome (Italy); Panella, M; Vitale, V [EURATOM-ENEA Association, Frascati Research Center, Via E. Fermi 45, 00044 Frascati (Rome) (Italy)

2007-10-15

In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system (CPS) configuration was installed to test on Tokamak FTU. The liquid lithium flows through capillaries from a reservoir to the side faced to the plasma to form a thin lithium film as wall coating. The system includes three stainless steel cases, which contain two thermocouples each one. A heating system brings the Li temperature about 200 deg. C to allow the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22{sup TM} modules and a CORBA/PHP/MySQL software architecture. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLAB{sup TM} and Java environments, respectively, to monitor the lithium temperature coming from thermocouples - have been also implemented. The LLL control system allows to regulate the heater temperature in each unit to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During the plasma shot the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink{sup TM} tool - has been realized.

The liquid lithium limiter control system on FTU

International Nuclear Information System (INIS)

Bertocchi, A.; Di Donna, M.; Panella, M.; Vitale, V.

2007-01-01

In the second half of 2005, a liquid lithium limiter (LLL) with capillary porous system (CPS) configuration was installed to test on Tokamak FTU. The liquid lithium flows through capillaries from a reservoir to the side faced to the plasma to form a thin lithium film as wall coating. The system includes three stainless steel cases, which contain two thermocouples each one. A heating system brings the Li temperature about 200 deg. C to allow the liquid to flow. This temperature, monitored by thermocouples, needs to be controlled. To carry out this experimental procedure, some new features have been introduced in the existent control system based on Opto22 TM modules and a CORBA/PHP/MySQL software architecture. The historical data storage to keep the lithium temperature evolution has been added. Two graphical tools - developed in MATLAB TM and Java environments, respectively, to monitor the lithium temperature coming from thermocouples - have been also implemented. The LLL control system allows to regulate the heater temperature in each unit to reach operational conditions, where the temperature adjustment can be performed either automatically through a specific control law or manually by the operator. During the plasma shot the system switches off the limiter power supply to prevent instruments damage. Moreover, in the same experimental context, a first approach to automatically obtain executable code - starting from control laws designed by Simulink TM tool - has been realized

Probabilistic and deterministic risk assessment for extreme objects and ecologically hazardous systems

Directory of Open Access Journals (Sweden)

Yu. V. Veryuzhsky

2003-06-01

Full Text Available The paper include mostly the results of works of the Research Institute for Mechanics of Quickproceeding Processes united in a general research direction - creation of the methodology for risk assessment and risk management for ecologically hazardous systems, consisting of the set of different technological analyzed objects. The elements of system can be characterized by high level of radiation, toxic, explosion, fire and other hazards. The probalistic and deterministic approach for risk assessment, based on mathematical methods of system analysis, non-liner dynamics and computer simulation, has been developed. Branching in problem definition, as well as diversity of factor and criteria for determination of system status, is also taken into account. The risks caused by both objective and subjective factors (including human factor are examined. In many performed studies, the leading structural element, dominating in determination of the system safety, is the structural part of an object. The methodology is implemented for the safety analysis (risk assessment for Chernobyl NPP Shelton Object and other industrial buildings

Preliminary investigation of liquid phase sintering in ferrous systems

International Nuclear Information System (INIS)

Klein, J.

1975-04-01

Liquid phase sintering was utilized to achieve, by a simple compaction and sintering procedure involving short times and moderate temperatures, a virtually full dense high carbon Fe:C alloy and high boron Fe:B alloy. Parameters such as powder characteristics and mixing, compacting pressure, heating program and the liquid phase fraction were found to influence the sintered density. The response of the Fe:C alloy to a heat treatment is reported along with preliminary experiments in the iron base ternary system Fe:W:C. Residual porosities observed in microstructures of certain liquid phase sintered compacts were accounted for by a proposed capillary flow of the liquid phase and a local densification competing against an overall densification. Some general recommendations are made for liquid phase sintering of powder aggregates. 15 fig., 7 tables

Medical Services: DoD Hazardous Food and Nonprescription Drug Recall System

Science.gov (United States)

1986-08-15

This publication implements policy of the Office of the Under Secretary of Defense for Research and Engineering for the establishment of a hazardous ... food and nonprescription drug recall system. It has been coordinated with and concurred in by the DMSB and the Services.

Surface boiling of superheated liquid

Energy Technology Data Exchange (ETDEWEB)

Reinke, P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1997-01-01

A basic vaporization mechanism that possibly affects the qualitative and quantitative prediction of the consequences of accidental releases of hazardous superheated liquids was experimentally and analytically investigated. The studies are of relevance for the instantaneous failure of a containment vessel filled with liquefied gas. Even though catastrophical vessel failure is a rare event, it is considered to be a major technological hazard. Modeling the initial phase of depressurisation and vaporization of the contents is an essential step for the subsequent analysis of the spread and dispersion of the materials liberated. There is only limited understanding of this inertial expansion stage of the superheated liquid, before gravity and atmospheric turbulence begin to dominate the expansion. This work aims at a better understanding of the vaporization process and to supply more precise source-term data. It is also intended to provide knowledge for the prediction of the behavior of large-scale releases by the investigation of boiling on a small scale. Release experiments with butane, propane, R-134a and water were conducted. The vaporization of liquids that became superheated by sudden depressurisation was studied in nucleation-site-free glass receptacles. Several novel techniques for preventing undesired nucleation and for opening the test-section were developed. Releases from pipes and from a cylindrical geometry allowed both linear one-dimensional, and radial-front two-dimensional propagation to be investigated. Releases were made to atmospheric pressure over a range of superheats. It was found that, above a certain superheat temperature, the free surface of the metastable liquid rapidly broke up and ejected a high-velocity vapor/liquid stream. The zone of intense vaporization and liquid fragmentation proceeded as a front that advanced into the test fluids. No nucleation of bubbles in the bulk of the superheated liquid was observed. (author) figs., tabs., refs.

Surface boiling of superheated liquid

International Nuclear Information System (INIS)

Reinke, P.

1997-01-01

A basic vaporization mechanism that possibly affects the qualitative and quantitative prediction of the consequences of accidental releases of hazardous superheated liquids was experimentally and analytically investigated. The studies are of relevance for the instantaneous failure of a containment vessel filled with liquefied gas. Even though catastrophical vessel failure is a rare event, it is considered to be a major technological hazard. Modeling the initial phase of depressurisation and vaporization of the contents is an essential step for the subsequent analysis of the spread and dispersion of the materials liberated. There is only limited understanding of this inertial expansion stage of the superheated liquid, before gravity and atmospheric turbulence begin to dominate the expansion. This work aims at a better understanding of the vaporization process and to supply more precise source-term data. It is also intended to provide knowledge for the prediction of the behavior of large-scale releases by the investigation of boiling on a small scale. Release experiments with butane, propane, R-134a and water were conducted. The vaporization of liquids that became superheated by sudden depressurisation was studied in nucleation-site-free glass receptacles. Several novel techniques for preventing undesired nucleation and for opening the test-section were developed. Releases from pipes and from a cylindrical geometry allowed both linear one-dimensional, and radial-front two-dimensional propagation to be investigated. Releases were made to atmospheric pressure over a range of superheats. It was found that, above a certain superheat temperature, the free surface of the metastable liquid rapidly broke up and ejected a high-velocity vapor/liquid stream. The zone of intense vaporization and liquid fragmentation proceeded as a front that advanced into the test fluids. No nucleation of bubbles in the bulk of the superheated liquid was observed. (author) figs., tabs., refs

Automated Liquid-Level Control of a Nutrient Reservoir for a Hydroponic System

Science.gov (United States)

Smith, Boris; Asumadu, Johnson A.; Dogan, Numan S.

1997-01-01

A microprocessor-based system for control of the liquid level of a nutrient reservoir for a plant hydroponic growing system has been developed. The system uses an ultrasonic transducer to sense the liquid level or height. A National Instruments' Multifunction Analog and Digital Input/Output PC Kit includes NI-DAQ DOS/Windows driver software for an IBM 486 personal computer. A Labview Full Development system for Windows is the graphical programming system being used. The system allows liquid level control to within 0.1 cm for all levels tried between 8 and 36 cm in the hydroponic system application. The detailed algorithms have been developed and a fully automated microprocessor based nutrient replenishment system has been described for this hydroponic system.

Simulation and economic analysis of a liquid-based solar system with a direct-contact liquid-liquid heat exchanger, in comparison to a system with a conventional heat exchanger

Science.gov (United States)

Brothers, P.; Karaki, S.

Using a solar computer simulation package called TRNSYS, simulations of the direct contact liquid-liquid heat exchanger (DCLLHE) solar system and a system with conventional shell-and-tube heat exchanger were developed, based in part on performance measurements of the actual systems. The two systems were simulated over a full year on an hour-by-hour basis at five locations; Boston, Massachusetts, Charleston, South Carolina, Dodge City, Kansas, Madison, Wisconsin, and Phoenix, Arizona. Typically the direct-contact system supplies slightly more heat for domestic hot water and space heating in all locations and about 5 percentage points more cooling as compared to the conventional system. Using a common set of economic parameters and the appropriate federal and state income tax credits, as well as property tax legislation for solar systems in the corresponding states, the results of the study indicate for heating-only systems, the DCLLHE system has a slight life-cycle cost disadvantage compared to the conventional system. For combined solar heating and cooling systems, the DCLLHE has a slight life-cycle cost advantage which varies with location and amounts to one to three percent difference from the conventional system.

Topographical mapping system for radiological and hazardous environments acceptance testing

International Nuclear Information System (INIS)

Armstrong, G.A.; Dochat, G.R.

1997-01-01

During the summer of 1996, the Topographical Mapping System (TMS) for hazardous and radiological environments and its accompanying three-dimensional (3-D) visualization tool, the Interactive Computer-Enhanced Remote-Viewing System (ICERVS), were delivered to Oak Ridge National Laboratory (ORNL). ORNL and Mechanical Technology, Inc., performed final acceptance testing of the TMS during the next eight months. The TMS was calibrated and characterized during this period. This paper covers the calibration, characterization, and acceptance testing of the TMS. Development of the TMS and ICERVS was initiated by the US Department of Energy (DOE) for the purpose of characterization and remediation of underground storage tanks (USTs) at DOE sites across the country. DOE required a 3-D, topographical mapping system suitable for use in hazardous and radiological environments. The intended application is the mapping of the interior of USTs as part of DOE's waste characterization and remediation efforts and to obtain baseline data on the content of the storage tank interiors as well as data on changes in the tank contents and levels brought about by waste remediation steps. Initially targeted for deployment at the Hanford Washington site, the TMS is designed to be a self-contained, compact, and reconfigurable system that is capable of providing rapid, variable-resolution mapping information in poorly characterized workspaces with a minimum of operator intervention

Topographical mapping system for radiological and hazardous environments acceptance testing

Science.gov (United States)

Armstrong, Gary A.; Dochat, G. R.

1997-09-01

During the summer of 1996, the topographical mapping system (TMS) for hazardous and radiological environments and its accompanying three-dimensional (3-D) visualization tool, the interactive computer-enhanced remote-viewing system (ICERVS), were delivered to Oak Ridge National Laboratory (ORNL). ORNL and Mechanical Technology, Inc., performed final acceptance testing of the TMS during the next eight months. The TMS was calibrated and characterized during this period. This paper covers the calibration, characterization, and acceptance testing of the TMS. Development of the TMS and the ICERVS was initiated by the U.S. Department of Energy (DOE) for the purpose of characterization and remediation of underground storage tanks (USTs) at DOE sites across the country. DOE required a 3-D, topographical mapping system suitable for use in hazardous and radiological environments. The intended application is the mapping of the interior of USTs as part of DOE's waste characterization and remediation efforts and to obtain baseline data on the content of the storage tank interiors as well as data on changes in the tank contents and levels brought about by waste remediation steps. Initially targeted for deployment at the Hanford Washington site, the TMS is designed to be a self-contained, compact, reconfigurable system that is capable of providing rapid, variable-resolution mapping information in poorly characterized workspaces with a minimum of operator intervention.

The radon daughter radiation hazard in controlled recirculation systems

International Nuclear Information System (INIS)

Rolle, R.; Burton, R.C.

1987-01-01

In deep South African gold mines, controlled recirculation systems with air cooling are being used to an increasing extent to improve the thermal environment. Recirculation causes some air to reside in the working area for a longer time than would have occurred without recirculation. Since radon daughters grow spontaneously from radon there is some concern that, with the extended residence time, the potential radiation hazard could increase to an unacceptable level. This paper describes the results obtained from a theoretical model of a controlled recirculation system. Guidelines for the design of recirculation systems to control the radon daughter radiation, and to keep it within acceptable limits are provided. 3 refs., 5 figs

Liquid Effluent Monitoring Information System test plans release 1.2

International Nuclear Information System (INIS)

Adams, R.T.

1994-01-01

The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

Identifying Liquid-Gas System Misconceptions and Addressing Them Using a Laboratory Exercise on Pressure-Temperature Diagrams of a Mixed Gas Involving Liquid-Vapor Equilibrium

Science.gov (United States)

Yoshikawa, Masahiro; Koga, Nobuyoshi

2016-01-01

This study focuses on students' understandings of a liquid-gas system with liquid-vapor equilibrium in a closed system using a pressure-temperature ("P-T") diagram. By administrating three assessment questions concerning the "P-T" diagrams of liquid-gas systems to students at the beginning of undergraduate general chemistry…

Experimental system design of liquid lithium-lead alloy bubbler for DFLL-TBM

International Nuclear Information System (INIS)

Xie Bo; Li Junge; Xu Shaomei; Weng Kuiping

2011-01-01

The liquid lithium-lead alloy bubbler is a very important composition in the tritium unit of Chinese Dual-Functional Lithium Lead Test Blanket Module (DFLL-TBM). In order to complete the construction and run of the bubbler experimental system,overall design of the system, main circuit design and auxiliary system design have been proposed on the basis of theoretical calculations for the interaction of hydrogen isotope with lithium-lead alloy and experiment for hydrogen extraction from liquid lithium-lead alloy by bubbling with rotational jet nozzle. The key of this design is gas-liquid exchange packed column, to achieve the measurement and extraction of hydrogen isotopes from liquid lithium-lead alloy. (authors)

Ternary (liquid + liquid) equilibria of {bis(trifluoromethylsulfonyl)-amide based ionic liquids + butan-1-ol + water}

International Nuclear Information System (INIS)

Marciniak, Andrzej; Wlazło, Michał; Gawkowska, Joanna

2016-01-01

Highlights: • Ternary (liquid + liquid) equilibria for 3 ionic liquid + butanol + water systems. • The influence of ionic liquid structure on phase diagrams is discussed. • Influence of IL structure on S and β for butanol/water separation is discussed. - Abstract: Ternary (liquid + liquid) phase equilibria for 3 systems containing bis(trifluoromethylsulfonyl)-amide ionic liquids (1-buthyl-1-methylpiperidinium bis(trifluoromethylsulfonyl)-amide, 1-(2-methoxyethyl)-1-methylpiperidinium bis(trifluoromethylsulfonyl)-amide, {1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluorylsulfonyl)-amide) + butan-1-ol + water} have been determined at T = 298.15 K. The selectivity and solute distribution ratio were calculated for investigated systems and compared with literature data for other systems containing ionic liquids. In each system total solubility of butan-1-ol and low solubility of water in the ionic liquid is observed. The experimental results have been correlated using NRTL model. The influence of the structure of ionic liquid on phase equilibria, selectivity and solute distribution ratio is shortly discussed.

Liquid chromatography detection unit, system, and method

Science.gov (United States)

Derenzo, Stephen E.; Moses, William W.

2015-10-27

An embodiment of a liquid chromatography detection unit includes a fluid channel and a radiation detector. The radiation detector is operable to image a distribution of a radiolabeled compound as the distribution travels along the fluid channel. An embodiment of a liquid chromatography system includes an injector, a separation column, and a radiation detector. The injector is operable to inject a sample that includes a radiolabeled compound into a solvent stream. The position sensitive radiation detector is operable to image a distribution of the radiolabeled compound as the distribution travels along a fluid channel. An embodiment of a method of liquid chromatography includes injecting a sample that comprises radiolabeled compounds into a solvent. The radiolabeled compounds are then separated. A position sensitive radiation detector is employed to image distributions of the radiolabeled compounds as the radiolabeled compounds travel along a fluid channel.

The designing of launch vehicles with liquid propulsion engines ensuring fire, explosion and environmental safety requirements of worked-off stages

Science.gov (United States)

Trushlyakov, V.; Shatrov, Ya.; Sujmenbaev, B.; Baranov, D.

2017-02-01

The paper addresses the problem of the launch vehicles (LV) with main liquid propulsion engines launch technogenic impact in different environment areas. Therefore, as the study subjects were chosen the worked-off stages (WS) with unused propellant residues in tanks, the cosmodrome ecological monitoring system, the worked-off stage design and construction solutions development system and the unified system with the "WS+the cosmodrome ecological monitoring system+design and construction solutions development system" feedback allowing to form the optimal ways of the WS design and construction parameters variations for its fire and explosion hazard management in different areas of the environment. It is demonstrated that the fire hazard effects of propellant residues in WS tanks increase the ecosystem disorder level for the Vostochny cosmodrome impact area ecosystem. Applying the system analysis, the proposals on the selection of technologies, schematic and WS design and construction solutions aimed to the fire and explosion safety improvement during the LV worked-off stages with the main liquid propulsion engines operation were formulated. Among them are the following: firstly, the unused propellant residues in tanks convective gasification based on the hot gas (heat carrier) supply in WS tanks after main liquid propulsion engines cutoff is proposed as the basic technology; secondly, the obtained unused propellant residues in WS tanks gasification products (evaporated propellant residues + pressurizing agent + heat carrier) are used for WS stabilization and orientation while descending trajectory moving. The applying of the proposed technologies allows providing fire and explosion safety requirements of LV with main liquid propulsion engines practically.

46 CFR 153.280 - Piping system design.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Piping system design. 153.280 Section 153.280 Shipping... BULK LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Design and Equipment Piping Systems and Cargo Handling Equipment § 153.280 Piping system design. (a) Each cargo piping system must meet...

A Monitoring System for Mountain Flood Geological Hazard Based on Internet of Things

Directory of Open Access Journals (Sweden)

HUANGFU Zhong-Min

2014-11-01

Full Text Available In order to avoid the shortcomings of the poor real-time data collection and the insufficient information coverage in the traditional geological hazard disaster monitoring measures, this paper designs a monitoring system for mountain flood geological hazard based on the Internet of Things, in which the overall architecture of the system is built, and the design of hardware combined with its driver program for the remote terminal system is presented in detail. This system uses STC12C5A60S2 MCU as the core controller to handle such data as rainfall, groundwater level and displacement of the mountain which are collected by the sensors, and employs GPS module to get the location information. Then the data processed is encapsulated into TCP/IP data packs by GPRS module. Through GPRS accessing the Internet, these data packs are transmitted to the monitoring center. The experimental results show that the system has good reliability, stability and real-time in communication.

A proposal for performing software safety hazard analysis

International Nuclear Information System (INIS)

Lawrence, J.D.; Gallagher, J.M.

1997-01-01

Techniques for analyzing the safety and reliability of analog-based electronic protection systems that serve to mitigate hazards in process control systems have been developed over many years, and are reasonably understood. An example is the protection system in a nuclear power plant. The extension of these techniques to systems which include digital computers is not well developed, and there is little consensus among software engineering experts and safety experts on how to analyze such systems. One possible technique is to extend hazard analysis to include digital computer-based systems. Software is frequently overlooked during system hazard analyses, but this is unacceptable when the software is in control of a potentially hazardous operation. In such cases, hazard analysis should be extended to fully cover the software. A method for performing software hazard analysis is proposed in this paper. The method concentrates on finding hazards during the early stages of the software life cycle, using an extension of HAZOP

Solid-Liquid and Liquid-Liquid Equilibrium in the Ternary System Acetic Acid-Propanoic Acid-Formamide.

Czech Academy of Sciences Publication Activity Database

Sedláková, Zuzana; Malijevská, I.

2007-01-01

Roč. 261, 1-2 (2007) , s. 129-132 ISSN 0378-3812. [International Conference on Properties and Phase Equilibria for Product and Process Design PPEPPD 2007 /11./. Hersonissos, Crete, 20.05.2007-25.05.2007] Institutional research plan: CEZ:AV0Z40720504 Keywords : solid-liquid equilibrium * ternary system * solid adduct Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.506, year: 2007

Hazardous waste management in research laboratories

International Nuclear Information System (INIS)

Sundstrom, G.

1989-01-01

Hazardous waste management in research laboratories benefits from a fundamentally different approach to the hazardous waste determination from industry's. This paper introduces new, statue-based criteria for identifying hazardous wastes (such as radiological mixed wastes and waste oils) and links them to a forward-looking compliance of laboratories, the overall system integrates hazardous waste management activities with other environmental and hazard communication initiatives. It is generalizable to other waste generators, including industry. Although only the waste identification and classification aspects of the system are outlined in detail here, four other components are defined or supported, namely: routine and contingency practices; waste treatment/disposal option definition and selection; waste minimization, recycling, reuse, and substitution opportunities; and key interfaces with other systems, including pollution prevention

Development and Integration of the Janus Robotic Lander: A Liquid Oxygen-Liquid Methane Propulsion System Testbed

Science.gov (United States)

Ponce, Raul

Initiatives have emerged with the goal of sending humans to other places in our solar system. New technologies are being developed that will allow for more efficient space systems to transport future astronauts. One of those technologies is the implementation of propulsion systems that use liquid oxygen and liquid methane (LO2-LCH4) as propellants. The benefits of a LO2-LCH4 propulsion system are plenty. One of the main advantages is the possibility of manufacturing the propellants at the destination body. A space vehicle which relies solely on liquid oxygen and liquid methane for its main propulsion and reaction control engines is necessary to exploit this advantage. At the University of Texas at El Paso (UTEP) MIRO Center for Space Exploration Technology Research (cSETR) such a vehicle is being developed. Janus is a robotic lander vehicle with the capability of vertical take-off and landing (VTOL) which integrates several LO2-LCH 4 systems that are being devised in-house. The vehicle will serve as a testbed for the parallel operation of these propulsion systems while being fed from common propellant tanks. The following work describes the efforts done at the cSETR to develop the first prototype of the vehicle as well as the plan to move forward in the design of the subsequent prototypes that will lead to a flight vehicle. In order to ensure an eventual smooth integration of the different subsystems that will form part of Janus, requirements were defined for each individual subsystem as well as the vehicle as a whole. Preliminary testing procedures and layouts have also been developed and will be discussed to detail in this text. Furthermore, the current endeavors in the design of each subsystem and the way that they interact with one another within the lander will be explained.

A single-chip computer analysis system for liquid fluorescence

International Nuclear Information System (INIS)

Zhang Yongming; Wu Ruisheng; Li Bin

1998-01-01

The single-chip computer analysis system for liquid fluorescence is an intelligent analytic instrument, which is based on the principle that the liquid containing hydrocarbons can give out several characteristic fluorescences when irradiated by strong light. Besides a single-chip computer, the system makes use of the keyboard and the calculation and printing functions of a CASIO printing calculator. It combines optics, mechanism and electronics into one, and is small, light and practical, so it can be used for surface water sample analysis in oil field and impurity analysis of other materials

Removal of radioactive and other hazardous material from fluid waste

Science.gov (United States)

Tranter, Troy J [Idaho Falls, ID; Knecht, Dieter A [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Burchfield, Larry A [W. Richland, WA; Anshits, Alexander G [Krasnoyarsk, RU; Vereshchagina, Tatiana [Krasnoyarsk, RU; Tretyakov, Alexander A [Zheleznogorsk, RU; Aloy, Albert S [St. Petersburg, RU; Sapozhnikova, Natalia V [St. Petersburg, RU

2006-10-03

Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.

Glass and liquid phase diagram of a polyamorphic monatomic system

Science.gov (United States)

Reisman, Shaina; Giovambattista, Nicolas

2013-02-01

We perform out-of-equilibrium molecular dynamics (MD) simulations of a monatomic system with Fermi-Jagla (FJ) pair potential interactions. This model system exhibits polyamorphism both in the liquid and glass state. The two liquids, low-density (LDL) and high-density liquid (HDL), are accessible in equilibrium MD simulations and can form two glasses, low-density (LDA) and high-density amorphous (HDA) solid, upon isobaric cooling. The FJ model exhibits many of the anomalous properties observed in water and other polyamorphic liquids and thus, it is an excellent model system to explore qualitatively the thermodynamic properties of such substances. The liquid phase behavior of the FJ model system has been previously characterized. In this work, we focus on the glass behavior of the FJ system. Specifically, we perform systematic isothermal compression and decompression simulations of LDA and HDA at different temperatures and determine "phase diagrams" for the glass state; these phase diagrams varying with the compression/decompression rate used. We obtain the LDA-to-HDA and HDA-to-LDA transition pressure loci, PLDA-HDA(T) and PHDA-LDA(T), respectively. In addition, the compression-induced amorphization line, at which the low-pressure crystal (LPC) transforms to HDA, PLPC-HDA(T), is determined. As originally proposed by Poole et al. [Phys. Rev. E 48, 4605 (1993)], 10.1103/PhysRevE.48.4605 simulations suggest that the PLDA-HDA(T) and PHDA-LDA(T) loci are extensions of the LDL-to-HDL and HDL-to-LDL spinodal lines into the glass domain. Interestingly, our simulations indicate that the PLPC-HDA(T) locus is an extension, into the glass domain, of the LPC metastability limit relative to the liquid. We discuss the effects of compression/decompression rates on the behavior of the PLDA-HDA(T), PHDA-LDA(T), PLPC-HDA(T) loci. The competition between glass polyamorphism and crystallization is also addressed. At our "fast rate," crystallization can be partially suppressed and the

Manitoba Hazardous Waste Management Corporation system scope and technology study

Energy Technology Data Exchange (ETDEWEB)

1988-01-01

The Manitoba Hazardous Waste Management Corporation is charged with the responsibility of implementing a hazardous waste management system in the province. A review was undertaken of the planning work performed to date and of the Corporation's development strategy. The evaluation was based on a review of the literature and on experience with hazardous waste planning, management, and engineering. To facilitate evaluation, the development strategies were visualized as made up of 3 logical components: the mechanisms or business vehicles used; the rates of development employed; and the geographical locations in which the activities take place. Based on ownership or funding source, 3 business development options were identified: public corporation, private enterprise, and joint venture. The only two options possible in terms of rate of development are incremental and immediate. Three general locations were considered; in Manitoba, outside Manitoba, or a combination of both. Results showed that a joint venture is a good option since it offers a good tradeoff to minimize expenditures between public and private financing, and it enables combining the flexibility and freedom of action of a private corporation with the responsibility of a public corporation. The incremental approach provides more flexibility than immediate development and is the most practical solution to the many uncertainties of the hazardous waste problem. This approach is nominally more costly because it takes longer and cannot capitalize on economies of scale, but it also minimizes the risk of making the wrong capital investment and is therefore a safer investment approach. 108 refs., 28 figs., 15 tabs.

Manitoba Hazardous Waste Management Corporation system scope and technology study

Energy Technology Data Exchange (ETDEWEB)

1988-01-01

The Manitoba Hazardous Waste Management Corporation is charged with the responsibility of implementing a hazardous waste management system in the province. A review was undertaken of the planning work performed to date and of the Corporation's development strategy. The evaluation was based on a review of the literature and on experience with hazardous waste planning, management, and engineering. To facilitate evaluation, the development strategies were visualized as made up of 3 logical components: the mechanisms or business vehicles used; the rates of development employed; and the geographical locations in which the activities take place. Based on ownership or funding source, 3 business development options were identified: public corporation, private enterprise, and joint venture. The only two options possible in terms of rate of development are incremental and immediate. Only 3 general locations were considered: in Manitoba, outside Manitoba, or a combination of both. Results showed that a joint venture is a good option since it offers a good tradeoff to minimize expenditures between public and private financing, and it enables combining the flexibility and freedom of action of a private corporation with the responsibility of a public corporation. The incremental approach provides more flexibility than immediate development and is the most practical solution to the many uncertainties of the hazardous waste problem. This approach is nominally more costly because it takes longer and cannot capitalize on economies of scale, but it also minimizes the risk of making the wrong capital investment and is therefore a safer investment approach. 105 refs. 28 figs., 15 tabs.

Hazards and control of ruthenium in the nuclear fuel cycle

International Nuclear Information System (INIS)

Eichholz, G.G.

1978-01-01

A review is presented of present information on the possible hazards of radioruthenium in the nuclear fuel cycle and its behaviour in nuclear operations and in the environment. The subject is dealt with under the following headings: basic chemical and nuclear properties of ruthenium; chemistry (including the ruthenium-nitric acid system, electrochemistry, extraction processes); ruthenium toxicity; generation of radioruthenium (fallout sources, reactor sources, fuel reprocessing operations); waste treatment (cementation and bitumenization, calcining processes, vitrification); movement in the environment (movement of airborne effluents, liquid effluents and the freshwater environment, marine environment, bottom sediments, marine organisms, terrestrial environments, uptake in vegetation and animals); conclusion. (U.K.)

Development of Automotive Liquid Hydrogen Storage Systems

Science.gov (United States)

Krainz, G.; Bartlok, G.; Bodner, P.; Casapicola, P.; Doeller, Ch.; Hofmeister, F.; Neubacher, E.; Zieger, A.

2004-06-01

Liquid hydrogen (LH2) takes up less storage volume than gas but requires cryogenic vessels. State-of-the-art applications for passenger vehicles consist of double-wall cylindrical tanks that hold a hydrogen storage mass of up to 10 kg. The preferred shell material of the tanks is stainless steel, since it is very resistant against hydrogen brittleness and shows negligible hydrogen permeation. Therefore, the weight of the whole tank system including valves and heat exchanger is more than 100 kg. The space between the inner and outer vessel is mainly used for thermal super-insulation purposes. Several layers of insulation foils and high vacuums of 10-3 Pa reduce the heat entry. The support structures, which keep the inner tank in position to the outer tank, are made of materials with low thermal conductivity, e.g. glass or carbon fiber reinforced plastics. The remaining heat in-leak leads to a boil-off rate of 1 to 3 percent per day. Active cooling systems to increase the stand-by time before evaporation losses occur are being studied. Currently, the production of several liquid hydrogen tanks that fulfill the draft of regulations of the European Integrated Hydrogen Project (EIHP) is being prepared. New concepts of lightweight liquid hydrogen storage tanks will be investigated.

Functions and requirements document, WESF decoupling project, low-level liquid waste system

Energy Technology Data Exchange (ETDEWEB)

Rasmussen, J.H., Fluor Daniel Hanford

1997-02-27

The Waste Encapsulation and Storage Facility (WESF) was constructed in 1974 to encapsulate and store cesium and strontium which were isolated at B Plant from underground storage tank waste. The WESF, Building 225-B, is attached physically to the west end of B Plant, Building 221-B, 200 East area. The WESF currently utilizes B Plant facilities for disposing liquid and solid waste streams. With the deactivation of B Plant, the WESF Decoupling Project will provide replacement systems allowing WESF to continue operations independently from B Plant. Four major systems have been identified to be replaced by the WESF Decoupling Project, including the following: Low Level Liquid Waste System, Solid Waste Handling System, Liquid Effluent Control System, and Deionized Water System.

Influence of radiation on the system liquid radioactive wastes: geologic formation

International Nuclear Information System (INIS)

Spitsyn, V.I.; Balukova, V.D.; Kabakchi, S.A.; Medvedeva, M.L.

1979-01-01

Introduction of liquid radioactive wastes into deep strata-collectors results in a number of physical-chemical processes: precipitation, dissolution, complex formation, sorption, etc. The area occupied by the injected waste and changes in the nature of the liquid phase depend primarily on radiolysis processes in the heterogeneous system of liquid waste-stratal material occurring at elevated temperatures and pressures. Experiments that simulate actual conditions of temperature, pressure and high radiation levels on this system have been performed. Results are presented for radiolytic gas formation and for changes in the liquid phase and sorption capacity of stratal minerals. It is shown that the temperature increase in the stratum-collector significantly enhances waste decomposition processes, promotes sorption of radionuclides and decreases the mobility of the waste in the formation

Liquid / liquid biphasic electrochemistry in ultra-turrax dispersed acetonitrile / aqueous electrolyte systems

International Nuclear Information System (INIS)

Watkins, John D.; Amemiya, Fumihiro; Atobe, Mahito; Bulman-Page, Philip C.; Marken, Frank

2010-01-01

Unstable acetonitrile | aqueous emulsions generated in situ with ultra-turrax agitation are investigated for applications in dual-phase electrochemistry. Three modes of operation for liquid / liquid aqueous-organic electrochemical processes are demonstrated with no intentionally added electrolyte in the organic phase based on (i) the formation of a water-soluble product in the aqueous phase in the presence of the organic phase, (ii) the formation of a product and ion transfer at the liquid / liquid-electrode triple phase boundary, and (iii) the formation of a water-insoluble product in the aqueous phase which then transfers into the organic phase. A three-electrode electrolysis cell with ultra-turrax agitator is employed and characterised for acetonitrile / aqueous 2 M NaCl two phase electrolyte. Three redox systems are employed in order to quantify the electrolysis cell performance. The one-electron reduction of Ru(NH 3 ) 6 3+ in the aqueous phase is employed to determine the rate of mass transport towards the electrode surface and the effect of the presence of the acetonitrile phase. The one-electron oxidation of n-butylferrocene in acetonitrile is employed to study triple phase boundary processes. Finally, the one-electron reduction of cobalticenium cations in the aqueous phase is employed to demonstrate the product transfer from the electrode surface into the organic phase. Potential applications in biphasic electrosynthesis are discussed.

TRADITIONAL CANISTER-BASED OPEN WASTE MANAGEMENT SYSTEM VERSUS CLOSED SYSTEM: HAZARDOUS EXPOSURE PREVENTION AND OPERATING THEATRE STAFF SATISFACTION.

Science.gov (United States)

Horn, M; Patel, N; MacLellan, D M; Millard, N

2016-06-01

Exposure to blood and body fluids is a major concern to health care professionals working in operating rooms (ORs). Thus, it is essential that hospitals use fluid waste management systems that minimise risk to staff, while maximising efficiency. The current study compared the utility of a 'closed' system with a traditional canister-based 'open' system in the OR in a private hospital setting. A total of 30 arthroscopy, urology, and orthopaedic cases were observed. The closed system was used in five, four, and six cases, respectively and the open system was used in nine, two, and four cases, respectively. The average number of opportunities for staff to be exposed to hazardous fluids were fewer for the closed system when compared to the open during arthroscopy and urology procedures. The open system required nearly 3.5 times as much staff time for set-up, maintenance during procedures, and post-procedure disposal of waste. Theatre staff expressed greater satisfaction with the closed system than with the open. In conclusion, compared with the open system, the closed system offers a less hazardous and more efficient method of disposing of fluid waste generated in the OR.

Correlations between phase behaviors and ionic conductivities of (ionic liquid + alcohol) systems

International Nuclear Information System (INIS)

Park, Nam Ku; Bae, Young Chan

2010-01-01

To understand the basic properties of ionic liquids (ILs), we examined the phase behavior and ionic conductivity characteristics using various compositions of different ionic liquids (1-ethyl-3-methylimidazolium hexafluorophosphate [emim] [PF6] and 1-benzyl-3-methylimidazolium hexafluorophosphate [bzmim] [PF6]) in several different alcohols (ethanol, propanol, 1-butanol, 2-butanol, and hexanol). We conducted a systematic study of the impact of different factors on the phase behavior of imidazolium-based ionic liquids in alcohols. Using a new experimental method with a liquid electrolyte system, we observed that the ionic conductivity of the ionic liquid/alcohol was sensitive to the surrounding temperature. We employed Chang et al.'s thermodynamic model [Chang et al. (1997, 1998) ] based on the lattice model. The obtained co-ordinated unit parameter from this model was used to describe the phase behavior and ionic conductivities of the given system. Good agreement with experimental data of various alcohol and ILs systems was obtained in the range of interest.

Resilience to Interacting multi-natural hazards

Science.gov (United States)

Zhuo, Lu; Han, Dawei

2016-04-01

Conventional analyses of hazard assessment tend to focus on individual hazards in isolation. However, many parts of the world are usually affected by multiple natural hazards with the potential for interacting relationships. The understanding of such interactions, their impacts and the related uncertainties, are an important and topical area of research. Interacting multi-hazards may appear in different forms, including 1) CASCADING HAZARDS (a primary hazard triggering one or more secondary hazards such as an earthquake triggering landslides which may block river channels with dammed lakes and ensued floods), 2) CONCURRING HAZARDS (two or more primary hazards coinciding to trigger or exacerbate secondary hazards such as an earthquake and a rainfall event simultaneously creating landslides), and 3) ALTERING HAZARDS (a primary hazard increasing the probability of a secondary hazard occurring such as major earthquakes disturbing soil/rock materials by violent ground shaking which alter the regional patterns of landslides and debris flows in the subsequent years to come). All three types of interacting multi-hazards may occur in natural hazard prone regions, so it is important that research on hazard resilience should cover all of them. In the past decades, great progresses have been made in tackling disaster risk around the world. However, there are still many challenging issues to be solved, and the disasters over recent years have clearly demonstrated the inadequate resilience in our highly interconnected and interdependent systems. We have identified the following weaknesses and knowledge gaps in the current disaster risk management: 1) although our understanding in individual hazards has been greatly improved, there is a lack of sound knowledge about mechanisms and processes of interacting multi-hazards. Therefore, the resultant multi-hazard risk is often significantly underestimated with severe consequences. It is also poorly understood about the spatial and

Open loop, auto reversing liquid nitrogen circulation thermal system for thermo vacuum chamber

International Nuclear Information System (INIS)

Naidu, M C A; Nolakha, Dinesh; Saharkar, B S; Kavani, K M; Patel, D R

2012-01-01

In a thermo vacuum chamber, attaining and controlling low and high temperatures (-100 Deg. C to +120 Deg. C) is a very important task. This paper describes the development of 'Open loop, auto reversing liquid nitrogen based thermal system'. System specifications, features, open loop auto reversing system, liquid nitrogen flow paths etc. are discussed in this paper. This thermal system consists of solenoid operated cryogenic valves, double embossed thermal plate (shroud), heating elements, temperature sensors and PLC. Bulky items like blowers, heating chambers, liquid nitrogen injection chambers, huge pipe lines and valves were not used. This entire thermal system is very simple to operate and PLC based, fully auto system with auto tuned to given set temperatures. This system requires a very nominal amount of liquid nitrogen (approx. 80 liters / hour) while conducting thermo vacuum tests. This system was integrated to 1.2m dia thermo vacuum chamber, as a part of its augmentation, to conduct extreme temperature cycling tests on passive antenna reflectors of satellites.

Degradation of hazardous chemicals in liquid radioactive wastes from biomedical research using a mixed microbial population

International Nuclear Information System (INIS)

Wolfram, J.H.; Radtke, M.; Wey, J.E.; Rogers, R.D.; Rau, E.H.

1997-10-01

As the costs associated with treatment of mixed wastes by conventional methods increase, new technologies will be investigated as alternatives. This study examines the potential of using a selected mixed population of microorganisms to treat hazardous chemical compounds in liquid low level radioactive wastes from biomedical research procedures. Microorganisms were isolated from various waste samples and enriched against compounds known to occur in the wastes. Individual isolates were tested for their ability to degrade methanol, ethanol, phenol, toluene, phthalates, acetonitrile, chloroform, and trichloroacetic acid. Following these tests, the organisms were combined in a media with a mixture of the different compounds. Three compounds: methanol, acetonitrile, and pseudocumene, were combined at 500 microliter/liter each. Degradation of each compound was shown to occur (75% or greater) under batch conditions with the mixed population. Actual wastes were tested by adding an aliquot to the media, determining the biomass increase, and monitoring the disappearance of the compounds. The compounds in actual waste were degraded, but at different rates than the batch cultures that did not have waste added. The potential of using bioprocessing methods for treating mixed wastes from biomedical research is discussed

Hazardous chemical and radioactive wastes at Hanford

International Nuclear Information System (INIS)

Keller, J.F.; Stewart, T.L.

1991-07-01

The Hanford Site was established in 1944 to produce plutonium for defense. During the past four decades, a number of reactors, processing facilities, and waste management facilities have been built at Hanford for plutonium production. Generally, Hanford's 100 Area was dedicated to reactor operation; the 200 Area to fuel reprocessing, plutonium recovery, and waste management; and the 300 Area to fuel fabrication and research and development. Wastes generated from these operations included highly radioactive liquid wastes, which were discharged to single- and double-shell tanks; solid wastes, including both transuranic (TRU) and low-level wastes, which were buried or discharged to caissons; and waste water containing low- to intermediate-level radioactivity, which was discharged to the soil column via near-surface liquid disposal units such as cribs, ponds, and retention basins. Virtually all of the wastes contained hazardous chemical as well as radioactive constituents. This paper will focus on the hazardous chemical components of the radioactive mixed waste generated by plutonium production at Hanford. The processes, chemicals used, methods of disposition, fate in the environment, and actions being taken to clean up this legacy are described by location

Hazardous chemical and radioactive wastes at Hanford

International Nuclear Information System (INIS)

Keller, J.F.; Stewart, T.L.

1993-01-01

The Hanford Site was established in 1944 to produce plutonium for defense. During the past four decades, a number of reactors, processing facilities, and waste management facilities were built at Hanford for plutonium production. Generally, Hanford's 100 Area was dedicated to reactor operation; the 200 Areas to fuel reprocessing, plutonium recovery, and waste management; and the 300 Area to fuel fabrication and research and development. Wastes generated from these operations included highly radioactive liquid wastes, which were discharged to single- and double-shell tanks; solid wastes, including both transuranic and low-level wastes, which were buried or discharged to caissons; and waste water containing low- to intermediate-level radioactivity, which was discharged to the soil column via near-surface liquid disposal units such as cribs, ponds, and retention basins. Virtually all of the wastes contained hazardous chemicals as well as radioactive constituents. This paper focuses on the hazardous chemical components of the radioactive mixed waste generated by plutonium production at Hanford. The processes, chemicals used, methods of disposition, fate in the environment, and actions being taken to clean up this legacy are described by location

Performance analysis of a novel energy storage system based on liquid carbon dioxide

International Nuclear Information System (INIS)

Wang, Mingkun; Zhao, Pan; Wu, Yi; Dai, Yiping

2015-01-01

Due to the intermittence and fluctuation of wind resource, the increasing penetration level of wind power will bring huge challenges to maintain the stability of power system. Integrating compressed air energy storage (CAES) system with wind farms can weaken this negative effect. However CAES system needs large caverns or mines to store compressed air, which is restricted in application. In this paper, a novel energy storage system based on liquid carbon dioxide is presented. The mathematical models of compressed liquid-carbon dioxide energy storage system are developed. The parametric analysis is conducted to examine the effect of some key thermodynamic parameters on the system performance. Compared with AA-CAES, the liquid carbon dioxide energy storage system has advantages such as a high energy density, high EVR. Moreover, the round trip efficiency of this system can reach about 56.64%, which is acceptable in consideration of the storage volume. Therefore, this proposed system has a good potential for storing wind power in large scale and offers an attractive solution to the challenges of the increasing penetration level of wind power. - Highlights: • A novel energy storage system based on liquid carbon dioxide is presented. • The effects of some key parameters on the system performance are studied. • The operation optimization is conducted by genetic algorithm. • Comparative analysis of AA-CAES and liquid carbon dioxide system is studied.

76 FR 65431 - National Pollutant Discharge Elimination System (NPDES) Concentrated Animal Feeding Operation...

Science.gov (United States)

2011-10-21

...). Ducks ( other than a liquid manure 30,000 or more....... 10,000-29,999........ Less than 10,000. handling system). Ducks (liquid manure handling 5,000 or more........ 1,500-4,999 Less than 1,500. system... Summary Feedlots Point Source Category Study, EPA-821-R-99-002 (1999), pp. 26-27. The health hazards that...

Calculation of liquid-liquid phase separation in a ternary system of a polymer in a mixture of a solvent and a nonsolvent

NARCIS (Netherlands)

Altena, Frank W.; Smolders, C.A.

1982-01-01

A numerical method for the calculation of the binodal of liquid-liquid phase separation in a ternary system is described. The Flory-Huggins theory for three-component systems is used. Binodals are calculated for polymer/solvent/nonsolvent systems which are used in the preparation of asymmetric

40 CFR 270.22 - Specific part B information requirements for boilers and industrial furnaces burning hazardous...

Science.gov (United States)

2010-07-01

... requirements for boilers and industrial furnaces burning hazardous waste. 270.22 Section 270.22 Protection of... requirements for boilers and industrial furnaces burning hazardous waste. When an owner or operator of a cement kiln, lightweight aggregate kiln, solid fuel boiler, liquid fuel boiler, or hydrochloric acid...

Extending and automating a Systems-Theoretic hazard analysis for requirements generation and analysis.

Energy Technology Data Exchange (ETDEWEB)

Thomas, John (Massachusetts Institute of Technology)

2012-05-01

Systems Theoretic Process Analysis (STPA) is a powerful new hazard analysis method designed to go beyond traditional safety techniques - such as Fault Tree Analysis (FTA) - that overlook important causes of accidents like flawed requirements, dysfunctional component interactions, and software errors. While proving to be very effective on real systems, no formal structure has been defined for STPA and its application has been ad-hoc with no rigorous procedures or model-based design tools. This report defines a formal mathematical structure underlying STPA and describes a procedure for systematically performing an STPA analysis based on that structure. A method for using the results of the hazard analysis to generate formal safety-critical, model-based system and software requirements is also presented. Techniques to automate both the analysis and the requirements generation are introduced, as well as a method to detect conflicts between the safety and other functional model-based requirements during early development of the system.

Surveillance of hazardous substances releases due to system interruptions, 2002.

Science.gov (United States)

Orr, Maureen F; Ruckart, Perri Zeitz

2007-04-11

The Hazardous Substances Emergency Events Surveillance (HSEES) system collected information on 9014 acute hazardous substance releases in 15 participating states in 2002. There were 3749 fixed-facility manufacturing events, of which 2100 involved "interruptions" to normal processing and 1649 "comparisons" that did not involve interruption. Equipment failure (69%) or intentional acts (20%) were the main root factor. Many events occurred in October and November in three states (Texas, Louisiana, and New Jersey), in three manufacturing industries (industrial and miscellaneous chemicals; petroleum refining; and plastics, synthetics, and resins). In interruption events, the substance categories most often released were mixtures, other inorganic substances, and volatile organic compounds and those most often causing injury were acids, chlorine, bases, and ammonia. Comparison events resulted in more acutely injured persons (408 versus 59) and more evacuees (11,318 versus 335) than interruption events and therefore may receive more public health attention. Because of the large number of interruption events, targeted prevention activities, including management of change procedures, lessons-learned implementation, process hazards analysis, and appropriate protection for workers could be economically advantageous and improve environmental quality. Efforts should focus on the identified areas of greater occurrence. The relationship of weather and equipment failure with interruption events needs further investigation.

Liquidity policies and systemic risk

OpenAIRE

Adrian, Tobias; Boyarchenko, Nina

2013-01-01

The growth of wholesale-funded credit intermediation has motivated liquidity regulations. We analyze a dynamic stochastic general equilibrium model in which liquidity and capital regulations interact with the supply of risk-free assets. In the model, the endogenously time-varying tightness of liquidity and capital constraints generates intermediaries’ leverage cycle, influencing the pricing of risk and the level of risk in the economy. Our analysis focuses on liquidity policies’ implications ...

Extraction Equilibrium of Acrylic Acid by Aqueous Two-Phase Systems Using Hydrophilic Ionic Liquids

International Nuclear Information System (INIS)

Lee, Yong Hwa; Lee, Woo Youn; Kim, Ki-Sub; Hong, Yeon Ki

2014-01-01

As an effective method for extraction of acrylic acid, aqueous two-phase systems based on morpholinium ionic liquids were used in this study. Effects of the alkyl chain length of cation in morpholinium ionic liquids on phase diagram and extraction efficiencies were investigated. Experimental results show that aqueous two phase systems can be formed by adding appropriate amount of morpholinium ionic liquids to aqueous K 2 HPO 4 solutions. It can be found that the ability of morpholinium ionic liquids for phase separation followed the order [HMMor][Br]>[OMMor][Br]>[BMMor][Br]>[EMMor][Br]. There was little difference between binodal curves of imidazolium ionic liquids and those of morpholinium ionic liquids. 50-90% of the extraction efficiency was observed for acrylic acid by aqueous two phase extraction of acrylic acid with morpholinium ionic liquids. It can be concluded that morpholinium ionic liquids/K 2 HPO 4 were effective for aqueous two phases extraction of acrylic acid comparing to imidazolium ionic liquids/K 2 HPO 4 systems because of their lower cost

75 FR 67919 - Hazardous Waste Management System; Proposed Exclusion for Identifying and Listing Hazardous Waste

Science.gov (United States)

2010-11-04

... treatment sludge from the lists of hazardous waste set forth in Title 40 of the Code of Federal Regulations... treatment sludges generated at its facility located in Owosso, Michigan from the list of hazardous wastes... disposed in a Subtitle D landfill and we considered transport of waste constituents through ground water...

Study of open systems with molecules in isotropic liquids

Science.gov (United States)

Kondo, Yasushi; Matsuzaki, Masayuki

2018-05-01

We are interested in dynamics of a system in an environment, or an open system. Such phenomena as crossover from Markovian to non-Markovian relaxation and thermal equilibration are of our interest. Open systems have experimentally been studied with ultra cold atoms, ions in traps, optics, and cold electric circuits because well-isolated systems can be prepared here and thus the effects of environments can be controlled. We point out that some molecules solved in isotropic liquid are well isolated and thus they can also be employed for studying open systems in Nuclear Magnetic Resonance (NMR) experiments. First, we provide a short review on related phenomena of open systems that helps readers to understand our motivation. We, then, present two experiments as examples of our approach with molecules in isotropic liquids. Crossover from Markovian to non-Markovian relaxation was realized in one NMR experiment, while relaxation-like phenomena were observed in approximately isolated systems in the other.

Advanced liquid radwaste decontamination by using a centrifuge system

International Nuclear Information System (INIS)

Tscheschlok, K.; Szukala, M.

1999-01-01

Waste water streams basically include undissolved suspended solids which contain almost the main part of the activated products. The centrifuge system, called LRS (Liquid Radwaste Treatment System), is able to remove these solids from the liquid content and fills the dewatered product into disposal containers. For this purpose a chemical pre-treatment step is often used for selective precipitation of special radionuclides and flocculents to agglomerate smaller sized particles (colloids) to make them separatable with the LRS. The plant arrangement, the process optimization and the collected operational experiences are described. 2 refs., 1 tab., 8 figs

The Daily Liquidity Effect in a Floor System – Empirical Evidence from the Norwegian

OpenAIRE

Syrstad, Olav

2013-01-01

This paper analyses the liquidity effect in Norway by examining the relationship between a range of liquidity variables and five different measures of the short-term interbank premium. The models are estimated on data from January 2007 and up to the end of September 2011, a period in which Norges Bank implemented its liquidity policy within a so-called floor system, and prior to the new liquidity system introduced on 3 October 2011. In a floor system the key policy rate is equal to banks’ dep...

Hazard banding in compliance with the new Globally Harmonised System (GHS) for use in control banding tools.

Science.gov (United States)

Arnone, Mario; Koppisch, Dorothea; Smola, Thomas; Gabriel, Stefan; Verbist, Koen; Visser, Remco

2015-10-01

Many control banding tools use hazard banding in risk assessments for the occupational handling of hazardous substances. The outcome of these assessments can be combined with advice for the required risk management measures (RMMs). The Globally Harmonised System of Classification and Labelling of Chemicals (GHS) has resulted in a change in the hazard communication elements, i.e. Hazard (H) statements instead of Risk-phrases. Hazard banding schemes that depend on the old form of safety information have to be adapted to the new rules. The purpose of this publication is to outline the rationales for the assignment of hazard bands to H statements under the GHS. Based on this, this publication proposes a hazard banding scheme that uses the information from the safety data sheets as the basis for assignment. The assignment of hazard bands tiered according to the severity of the underlying hazards supports the important principle of substitution. Additionally, the set of assignment rules permits an exposure-route-specific assignment of hazard bands, which is necessary for the proposed route-specific RMMs. Ideally, all control banding tools should apply the same assignment rules. This GHS-compliant hazard banding scheme can hopefully help to establish a unified hazard banding strategy in the various control banding tools. Copyright © 2015 Elsevier Inc. All rights reserved.

Frozen soil barriers for hazardous waste confinement

International Nuclear Information System (INIS)

Dash, J.G.; Leger, R.; Fu, H.Y.

1997-01-01

Laboratory and full field measurements have demonstrated the effectiveness of artificial ground freezing for the containment of subsurface hazardous and radioactive wastes. Bench tests and a field demonstration have shown that cryogenic barriers are impenetrable to aqueous and non aqueous liquids. As a result of the successful tests the US Department of Energy has designated frozen ground barriers as one of its top ten remediation technologies

40 CFR 63.1217 - What are the standards for liquid fuel boilers that burn hazardous waste?

Science.gov (United States)

2010-07-01

... boilers that burn hazardous waste? 63.1217 Section 63.1217 Protection of Environment ENVIRONMENTAL... that burn hazardous waste? (a) Emission limits for existing sources. You must not discharge or cause... paragraph (a)(2)(iii) of this section: (i) When you burn hazardous waste with an as-fired heating value less...

Expert assessment of the resilience of drinking water and sanitation systems to climate-related hazards.

Science.gov (United States)

Luh, Jeanne; Royster, Sarah; Sebastian, Daniel; Ojomo, Edema; Bartram, Jamie

2017-08-15

We conducted an expert assessment to obtain expert opinions on the relative global resilience of ten drinking water and five sanitation technologies to the following six climate-related hazards: drought, decreased inter-annual precipitation, flood, superstorm flood, wind damage, and saline intrusion. Resilience scores ranged from 1.7 to 9.9 out of a maximum resilience of 10, with high scores corresponding to high resilience. We find that for some climate-related hazards, such as drought, technologies demonstrated a large range in resilience, indicating that the choice of water and sanitation technologies is important for areas prone to drought. On the other hand, the range of resilience scores for superstorm flooding was much smaller, particularly for sanitation technologies, suggesting that the choice of technology is less of a determinant of functionality for superstorm flooding as compared to other climate-related hazards. For drinking water technologies, only treated piped utility-managed systems that use surface water had resilience scores >6.0 for all hazards, while protected dug wells were found to be one of the least resilient technologies, consistently scoring <5.0 for all hazards except wind damage. In general, sanitation technologies were found to have low to medium resilience, suggesting that sanitation systems need to be adapted to ensure functionality during and after climate-related hazards. The results of the study can be used to help communities decide which technologies are best suited for the climate-related challenges they face and help in future adaptation planning. Copyright © 2017 Elsevier B.V. All rights reserved.

Liquids - vapor and liquids - solids equilibria in the system Th(NO3)4 - UO2(NO3)2 - HNO3 - H2O

International Nuclear Information System (INIS)

Volk, V.I.; Vakhrushin, A.Yu.; Mamaev, S.L.; Zhirnov, Yu.P.

1999-01-01

Liquids - vapor and liquids - solids equilibria in the system Th(NO 3 ) 4 - UO 2 (NO 3 ) 2 - HNO 3 - H 2 O were investigated. It was established that in this system thorium nitrate hexahydrate and uranyl nitrate hexa- and trihydrate are formed. Empiric equations of solubility isotherm at 25 deg C were found. Densities of liquid phases of the system were determined. It was established that uranyl nitrates and thorium nitrates salt out nitric acid in vapor phase just as separately so in the case of mutual presence. Empiric equation fixing relationship between nitric acid concentration in condensed phase and concentrations of all components in liquid phase was found

Spillage detector for liquid chromatography systems

Science.gov (United States)

Jarvis, M. J.; Fulton, D. S. (Inventor)

1986-01-01

A spillage detector device for use in conjunction with fractionation of liquid chromatography systems which includes a spillage recieving enclosure beneath the fractionation area is described. A sensing device having a plurality of electrodes of alternating polarity is mounted within the spillage recieving enclosure. Detection circuitry, responsive to conductivity between electrodes, is operatively connected to the sensing device. The detection circuitry feeds into the output circuitry. The output circuit has relaying and switching circuitry directed to a solenoid, an alarm system and a pump. The solenoid is connected to the pliable conduit of the chromatography system. The alarm system comprises an audio alarm and a visual signal. A 115-volt power system interconnected with the pump, the solenoid, the sensing device, and the detection and output circuitry.

Enhanced electroforced sedimentation of various solid- liquid systems

African Journals Online (AJOL)

GREGORY

2011-12-16

Dec 16, 2011 ... liquid systems. Mohammed S. Jami1* ... significant challenges in wastewater management. ... environmental sludge and biosolids, thereby reducing the volumes to be disposed through landfills, incineration or other means.

Preliminary hazard analysis for the Brayton Isotope Ground Demonstration System (including vacuum test chamber)

International Nuclear Information System (INIS)

Miller, L.G.

1975-01-01

The Preliminary Hazard Analysis (PHA) of the BIPS-GDS is a tabular summary of hazards and undesired events which may lead to system damage or failure and/or hazard to personnel. The PHA reviews the GDS as it is envisioned to operate in the Vacuum Test Chamber (VTC) of the GDS Test Facility. The VTC and other equipment which will comprise the test facility are presently in an early stage of preliminary design and will undoubtedly undergo numerous changes before the design is frozen. The PHA and the FMECA to follow are intended to aid the design effort by identifying areas of concern which are critical to the safety and reliability of the BIPS-GDS and test facility

Conductive properties of switchable photoluminescence thermosetting systems based on liquid crystals.

Science.gov (United States)

Tercjak, Agnieszka; Gutierrez, Junkal; Ocando, Connie; Mondragon, Iñaki

2010-03-16

Conductive properties of different thermosetting materials modified with nematic 4'-(hexyl)-4-biphenyl-carbonitrile (HBC) liquid crystal and rutile TiO(2) nanoparticles were successfully studied by means of tunneling atomic force miscroscopy (TUNA). Taking into account the liquid crystal state of the HBC at room temperature, depending on both the HBC content and the presence of TiO(2) nanoparticles, designed materials showed different TUNA currents passed through the sample. The addition of TiO(2) nanoparticles into the systems multiply the detected current if compared to the thermosetting systems without TiO(2) nanoparticles and simultaneously stabilized the current passed through the sample, making the process reversible since the absolute current values were almost the same applying both negative and positive voltage. Moreover, thermosetting systems modified with liquid crystals with and without TiO(2) nanoparticles are photoluminescence switchable materials as a function of temperature gradient during repeatable heating/cooling cycle. Conductive properties of switchable photoluminescence thermosetting systems based on liquid crystals can allow them to find potential application in the field of photoresponsive devices, with a high contrast ratio between transparent and opaque states.

Introduction: Hazard mapping

Science.gov (United States)

Baum, Rex L.; Miyagi, Toyohiko; Lee, Saro; Trofymchuk, Oleksandr M

2014-01-01

Twenty papers were accepted into the session on landslide hazard mapping for oral presentation. The papers presented susceptibility and hazard analysis based on approaches ranging from field-based assessments to statistically based models to assessments that combined hydromechanical and probabilistic components. Many of the studies have taken advantage of increasing availability of remotely sensed data and nearly all relied on Geographic Information Systems to organize and analyze spatial data. The studies used a range of methods for assessing performance and validating hazard and susceptibility models. A few of the studies presented in this session also included some element of landslide risk assessment. This collection of papers clearly demonstrates that a wide range of approaches can lead to useful assessments of landslide susceptibility and hazard.

Isobaric (vapour + liquid + liquid) equilibrium data for (di-n-propyl ether + n-propyl alcohol + water) and (diisopropyl ether + isopropyl alcohol + water) systems at 100 kPa

International Nuclear Information System (INIS)

Lladosa, Estela; Monton, Juan B.; Burguet, MaCruz; Torre, Javier de la

2008-01-01

Isobaric (vapour + liquid + liquid) equilibria were measured for the (di-n-propyl ether + n-propyl alcohol + water) and (diisopropyl ether + isopropyl alcohol + water) system at 100 kPa. The apparatus used for the determination of (vapour + liquid + liquid) equilibrium data was an all-glass dynamic recirculating still with an ultrasonic homogenizer couple to the boiling flask. The experimental data demonstrated the existence of a heterogeneous ternary azeotrope for both ternary systems. The (vapour + liquid + liquid) equilibria data were found to be thermodynamically consistent for both systems. The experimental data were compared with the estimation using UNIQUAC and NRTL models and the prediction of UNIFAC model

Factors influencing the thermodynamic isotope effect of lithium in polyetherlithium liquid-liquid extraction systems

International Nuclear Information System (INIS)

Fu Lian; Fang Shengqiang; Yao Zhongqi; Gao Zhichang; Tan Ganzhu

1989-01-01

The published data up to now concerning polyether-lithium liquid-liquid extraction systems, can be summarized by the equation, ε p = (α-1)/[1 + 0.46(1-P)], where α denotes the isotope separation factor; P - the ratio of the lithium concentration in the organic phase to the initial concentration of crown ethers; ε p -the enrichment coefficient as P = 100%. Based on the changes in ε p , P, α and D(distribution ratio), the functions of factors such as polyether's structure, polyether's side group, polyether's concentration, organic solvent, negative ion of lithium salt and lithium salt's concentration, are discussed and reported

Hazard identification and risk assessment for biologics targeting the immune system.

Science.gov (United States)

Weir, Andrea B

2008-01-01

Biologic pharmaceuticals include a variety of products, such as monoclonal antibodies, fusion proteins and cytokines. Products in those classes include immunomodulatory biologics, which are intended to enhance or diminish the activity of the immune system. Immunomodulatory biologics have been approved by the U.S. FDA for a variety of indications, including cancer and inflammatory conditions. Prior to gaining approval for marketing, sponsoring companies for all types of products must demonstrate a product's safety in toxicology studies conducted in animals and show safety and efficacy in clinical trials conducted in patients. The overall goal of toxicology studies, which applies to immunomodulatory and other product types, is to identify the hazards that products pose to humans. Because biologics are generally highly selective for specific targets (receptors/epitopes), conducting toxicology studies in animal models with the target is essential. Such animals are referred to as pharmacologically relevant. Endpoints routinely included in toxicology studies, such as hematology, organ weight and histopathology, can be used to assess the effect of a product on the structure of the immune system. Additionally, specialized endpoints, such as immunophenotyping and immune function tests, can be used to define effects of immunomodulatory products on the immune system. Following hazard identification, risks posed to patients are assessed and managed. Risks can be managed through clinical trial design and risk communication, a practice that applies to immunomodulatory and other product types. Examples of risk management in clinical trial design include establishing a safe starting dose, defining the appropriate patient population and establishing appropriate patient monitoring. Risk communication starts during clinical trials and continues after product approval. A combination of hazard identification, risk assessment and risk management allows for drug development to proceed

Liquid Effluent Monitoring Information System (LEMIS) test plans release 1.0

International Nuclear Information System (INIS)

Adams, R.T.

1994-01-01

The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

Liquid Effluent Monitoring Information System (LEMIS) test plans release 1.1

International Nuclear Information System (INIS)

Adams, R.T.

1994-01-01

The Liquid Effluent Monitoring Information System (LEMIS) is being developed as the organized information repository facility in support of the liquid effluent monitoring requirements of the Tri-Party Agreement. It is necessary to provide an automated repository into which the results from liquid effluent sampling will be placed. This repository must provide for effective retention, review, and retrieval of selected sample data by authorized persons and organizations. This System Architecture document is the aggregation of the DMR P+ methodology project management deliverables. Together they represent a description of the project and its plan through four Releases, corresponding to the definition and prioritization of requirements defined by the user

Hazards of Secondary Bromadiolone Intoxications Evaluated using High-performance Liquid Chromatography with Electrochemical Detection

Directory of Open Access Journals (Sweden)

René Kizek

2007-07-01

Full Text Available This study reported on the possibility of intoxications of non-target wild animalsassociated with use of bromadiolone as the active component of rodenticides withanticoagulation effects. A laboratory test was done with earthworms were exposed tobromadiolone-containing granules under the conditions specified in the modified OECD207 guideline. No mortality of earthworms was observed during the fourteen days longexposure. When the earthworms from the above test became a part of the diet of commonvoles in the following experiment, no mortality of consumers was observed too. However,electrochemical analysis revealed higher levels of bromadiolone in tissues fromearthworms as well as common voles compared to control animals. There were determinedcomparable levels of bromadiolone in the liver tissue of common voles after primary(2.34±0.10 μg/g and secondary (2.20±0.53 μg/g intoxication. Therefore, the risk ofsecondary intoxication of small mammalian species feeding on bromadiolone-containing earthworms is the same as of primary intoxication through baited granules. Bromadiolone bio-accumulation in the food chain was monitored using the newly developed analytical procedure based on the use of a liquid chromatography coupled with electrochemical detector (HPLC-ED. The HPLC-ED method allowed to determine the levels of bromadiolone in biological samples and is therefore suitable for examining the environmental hazards of this substance.

The Nature and Assessment of Systemic Risk in Terms of Liquidity of the Banking System

Directory of Open Access Journals (Sweden)

Lavreniuk Vladyslav V.

2016-11-01

Full Text Available The aim of the article is to determine the nature of systemic risk as a threat to the financial stability of the banking system and develop analytical tools to assess its impact on the banking system in terms of its liquidity. To solve the tasks assigned, there used general scientific and specific methods, such as: logical and dialectical method, mathematical and graphical one. Based on the generalization, analysis and comparison of different interpretations, there clarified the concept of «systemic risk» as a risk generated by financial institutions or individual sectors through the implementation of the mechanism of risk transmission, achieving significant scale of distribution and adversely affecting the stability of the financial system and the real sector of economy. There identified key aspects of systemic risk: a systemic risk is not a sum of all individual risks of financial institutions; b spreads through the channels of interconnectedness between financial institutions; c is a result of accumulated structural imbalances; d affects the stability of the financial/banking system, public confidence and the real sector of economy. Analytical tools for estimation of the bank’s contribution to the systemic liquidity risk on the basis of which it is determined that the first place in terms of the effect on the aggregate systemic risk of liquidity of the Ukrainian banking system is occupied by banks of Group I, the second place — by Privatbank, the third, fourth, fifth places — by banks in Group II — Oschadbank, Ukreximbank. It is found that it is systemically important state-owned banks that have a significant impact on systemic liquidity risk. It is determined that the probability of default of a leading systemically important bank could result in considerable cumulative losses for the entire banking system and real economy. The prospects of further research are the development of tools for systemic risk assessment with respect to

Liquid low level waste management expert system

International Nuclear Information System (INIS)

Ferrada, J.J.; Abraham, T.J.; Jackson, J.R.

1991-01-01

An expert system has been developed as part of a new initiative for the Oak Ridge National Laboratory (ORNL) systems analysis program. This expert system will aid in prioritizing radioactive waste streams for treatment and disposal by evaluating the severity and treatability of the problem, as well as the final waste form. The objectives of the expert system development included: (1) collecting information on process treatment technologies for liquid low-level waste (LLLW) that can be incorporated in the knowledge base of the expert system, and (2) producing a prototype that suggests processes and disposal technologies for the ORNL LLLW system. 4 refs., 9 figs

Flight Testing a Real-Time Hazard Detection System for Safe Lunar Landing on the Rocket-Powered Morpheus Vehicle

Science.gov (United States)

Trawny, Nikolas; Huertas, Andres; Luna, Michael E.; Villalpando, Carlos Y.; Martin, Keith E.; Carson, John M.; Johnson, Andrew E.; Restrepo, Carolina; Roback, Vincent E.

2015-01-01

The Hazard Detection System (HDS) is a component of the ALHAT (Autonomous Landing and Hazard Avoidance Technology) sensor suite, which together provide a lander Guidance, Navigation and Control (GN&C) system with the relevant measurements necessary to enable safe precision landing under any lighting conditions. The HDS consists of a stand-alone compute element (CE), an Inertial Measurement Unit (IMU), and a gimbaled flash LIDAR sensor that are used, in real-time, to generate a Digital Elevation Map (DEM) of the landing terrain, detect candidate safe landing sites for the vehicle through Hazard Detection (HD), and generate hazard-relative navigation (HRN) measurements used for safe precision landing. Following an extensive ground and helicopter test campaign, ALHAT was integrated onto the Morpheus rocket-powered terrestrial test vehicle in March 2014. Morpheus and ALHAT then performed five successful free flights at the simulated lunar hazard field constructed at the Shuttle Landing Facility (SLF) at Kennedy Space Center, for the first time testing the full system on a lunar-like approach geometry in a relevant dynamic environment. During these flights, the HDS successfully generated DEMs, correctly identified safe landing sites and provided HRN measurements to the vehicle, marking the first autonomous landing of a NASA rocket-powered vehicle in hazardous terrain. This paper provides a brief overview of the HDS architecture and describes its in-flight performance.

Volatile liquid storage system

International Nuclear Information System (INIS)

Laverman, R.J.; Winters, P.J.; Rinehart, J.K.

1992-01-01

This patent describes a method of collecting and abating emission from a volatile liquid in an above ground storage tank. It comprises the liquid storage tank having a bottom, a vertical cylindrical circular wall having a lower edge portion joined to the bottom, and an external fixed roof, the tank having an internal floating roof floating on a volatile liquid stored in the tank, and air vent means in the tank in communication with a vapor space in the tank constituting at least the space above the floating roof when the floating roof floats on a predetermined maximum volume of volatile liquid in the tank; permitting ambient air; pumping emission laden air from the tank vapor space above the floating roof; and by means of the emissions abatement apparatus eliminating most of the emission from the emissions laden air with formation of a gaseous effluent and then discharging the resulting gaseous effluent to the atmosphere

Modeling and Hazard Analysis Using STPA

Science.gov (United States)

Ishimatsu, Takuto; Leveson, Nancy; Thomas, John; Katahira, Masa; Miyamoto, Yuko; Nakao, Haruka

2010-09-01

A joint research project between MIT and JAXA/JAMSS is investigating the application of a new hazard analysis to the system and software in the HTV. Traditional hazard analysis focuses on component failures but software does not fail in this way. Software most often contributes to accidents by commanding the spacecraft into an unsafe state(e.g., turning off the descent engines prematurely) or by not issuing required commands. That makes the standard hazard analysis techniques of limited usefulness on software-intensive systems, which describes most spacecraft built today. STPA is a new hazard analysis technique based on systems theory rather than reliability theory. It treats safety as a control problem rather than a failure problem. The goal of STPA, which is to create a set of scenarios that can lead to a hazard, is the same as FTA but STPA includes a broader set of potential scenarios including those in which no failures occur but the problems arise due to unsafe and unintended interactions among the system components. STPA also provides more guidance to the analysts that traditional fault tree analysis. Functional control diagrams are used to guide the analysis. In addition, JAXA uses a model-based system engineering development environment(created originally by Leveson and called SpecTRM) which also assists in the hazard analysis. One of the advantages of STPA is that it can be applied early in the system engineering and development process in a safety-driven design process where hazard analysis drives the design decisions rather than waiting until reviews identify problems that are then costly or difficult to fix. It can also be applied in an after-the-fact analysis and hazard assessment, which is what we did in this case study. This paper describes the experimental application of STPA to the JAXA HTV in order to determine the feasibility and usefulness of the new hazard analysis technique. Because the HTV was originally developed using fault tree analysis

Science and Systems in Support of Multi-hazard Early Warnings and Decisions

Science.gov (United States)

Pulwarty, R. S.

2015-12-01

The demand for improved climate knowledge and information is well documented. As noted in the IPCC (SREX, AR5), the UNISDR Global Assessment Reports and other assessments, this demand has increased pressure for information to support planning under changing rates and emergence of multiple hazards including climate extremes (drought, heat waves, floods). "Decision support" is now a popular term in the climate applications research community. While existing decision support activities can be identified in many disparate settings (e.g. federal, academic, private), the challenge of changing environments (coupled physical and social) is actually one of crafting implementation strategies for improving decision quality (not just meeting "user needs"). This includes overcoming weaknesses in co-production models, moving beyond DSSs as simply "software", coordinating innovation mapping and diffusion, and providing fora and gaming tools to identify common interests and differences in the way risks are perceived and managed among the affected groups. We outline the development and evolution of multi-hazard early warning systems in the United States and elsewhere, focusing on climate-related hazards. In particular, the presentation will focus on the climate science and information needed for (1) improved monitoring and modeling, (2) generating risk profiles, (3) developing information systems and scenarios for critical thresholds, (4) the net benefits of using new information (5) characterizing and bridging the "last mile" in the context of longer-term risk management.

Assessment of the candidate markets for liquid boiler fuels

Energy Technology Data Exchange (ETDEWEB)

None

1979-12-01

Liquid fuels can be produced from coal in a number of indirect and direct liquefaction processes. While indirect coal liquefaction has been proved commercially outside the United States, most attention in this country has focused on the direct liquefaction processes, which include the processes under examination in this report; namely, the Exxon Donor Solvent (EDS), the H-Coal, and the Solvent Refined Coal (SRC) II processes. The objectives of the study were to: compare the boiler fuels of direct coal liquefaction with residual fuel oil (No. 6 fuel oil) including physical characteristics and environmental hazards, such as carcinogenic characteristics and toxic hazard characteristics; determine whether a boiler fuel market would exist for the coal liquefaction products given their physical characteristics and potential environmental hazards; determine the advantages of utilizing methanol as a boiler fuel on a continuous basis in commercial boilers utilizing existing technology; identify the potential regional candidate markets for direct coal liquefaction products as liquid boiler fuels; determine the distributing and handling costs associated with marketing coal liquefaction products as liquid boiler fuels; determine the current regulatory issues associated with the marketing of coal liquefaction products as boiler fuels; and determine and evaluate other institutional issues associated with the marketing of direct coal liquefaction products as boiler fuels.

Autonomous Soil Assessment System: A Data-Driven Approach to Planetary Mobility Hazard Detection

Science.gov (United States)

Raimalwala, K.; Faragalli, M.; Reid, E.

2018-04-01

The Autonomous Soil Assessment System predicts mobility hazards for rovers. Its development and performance are presented, with focus on its data-driven models, machine learning algorithms, and real-time sensor data fusion for predictive analytics.

77 FR 6857 - Pipeline Safety: Notice of Public Meetings on Improving Pipeline Leak Detection System...

Science.gov (United States)

2012-02-09

... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration [Docket ID... installed to lessen the volume of natural gas and hazardous liquid released during catastrophic pipeline... p.m. Panel 3: Considerations for Natural Gas Pipeline Leak Detection Systems 3:30 p.m. Break 3:45 p...

Distributed Health Monitoring System for Reusable Liquid Rocket Engines

Science.gov (United States)

Lin, C. F.; Figueroa, F.; Politopoulos, T.; Oonk, S.

2009-01-01

The ability to correctly detect and identify any possible failure in the systems, subsystems, or sensors within a reusable liquid rocket engine is a major goal at NASA John C. Stennis Space Center (SSC). A health management (HM) system is required to provide an on-ground operation crew with an integrated awareness of the condition of every element of interest by determining anomalies, examining their causes, and making predictive statements. However, the complexity associated with relevant systems, and the large amount of data typically necessary for proper interpretation and analysis, presents difficulties in implementing complete failure detection, identification, and prognostics (FDI&P). As such, this paper presents a Distributed Health Monitoring System for Reusable Liquid Rocket Engines as a solution to these problems through the use of highly intelligent algorithms for real-time FDI&P, and efficient and embedded processing at multiple levels. The end result is the ability to successfully incorporate a comprehensive HM platform despite the complexity of the systems under consideration.

Simple and Rapid Dual-Dispersive Liquid-Liquid Microextraction as an Innovative Extraction Method for Uranium in Real Water Samples Prior to the Determination of Uranium by a Spectrophotometric Technique.

Science.gov (United States)

Khan, Naeemullah; Tuzen, Mustafa; Kazi, Tasneem Gul

2017-11-01

An innovative, rapid, and simple dual-dispersive liquid-liquid microextraction (DDLL-ME) approach was used to extract uranium from real samples for the first time. The main objective of this study was to disperse extraction solvent by using an air-agitated syringe system to overcome matrix effects and avoid dispersion of hazardous dispersive organic solvents by using heat. The DDLL-ME method consisted of two dispersive liquid-liquid extraction steps with chloroform as the extracting solvent. Uranium formed complexes with 4-(2-thiazolylazo) resorcinol in the aqueous phase and was extracted in extracting solvent (chloroform) after the first dispersive liquid-liquid process. Uranium was then back-extracted in the acidic aqueous phase in a second dispersive liquid-liquid process. Finally, uranium was determined by a spectrophotometric detection technique. The variables that played a key role in the proposed method were studied and optimized. The LOD and sensitivity enhancement factor for uranium were found to be 0.60 µg/L and 45, respectively, under optimized conditions. Calibration graphs were found to be linear in the range of 5.0-600 µg/L. The RSD was 2.5%. Reliability of the proposed method was verified by analyzing certified reference material TM-28.3.

A comparison of various modes of liquid-liquid based microextraction techniques: determination of picric acid.

Science.gov (United States)

Burdel, Martin; Šandrejová, Jana; Balogh, Ioseph S; Vishnikin, Andriy; Andruch, Vasil

2013-03-01

Three modes of liquid-liquid based microextraction techniques--namely auxiliary solvent-assisted dispersive liquid-liquid microextraction, auxiliary solvent-assisted dispersive liquid-liquid microextraction with low-solvent consumption, and ultrasound-assisted emulsification microextraction--were compared. Picric acid was used as the model analyte. The determination is based on the reaction of picric acid with Astra Phloxine reagent to produce an ion associate easily extractable by various organic solvents, followed by spectrophotometric detection at 558 nm. Each of the compared procedures has both advantages and disadvantages. The main benefit of ultrasound-assisted emulsification microextraction is that no hazardous chlorinated extraction solvents and no dispersive solvent are necessary. Therefore, this procedure was selected for validation. Under optimized experimental conditions (pH 3, 7 × 10(-5) mol/L of Astra Phloxine, and 100 μL of toluene), the calibration plot was linear in the range of 0.02-0.14 mg/L and the LOD was 7 μg/L of picric acid. The developed procedure was applied to the analysis of spiked water samples. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Liquid-liquid equilibrium of water + PEG 8000 + magnesium sulfate or sodium sulfate aqueous two-phase systems at 35°C: experimental determination and thermodynamic modeling

Directory of Open Access Journals (Sweden)

B. D. Castro

2005-09-01

Full Text Available Liquid-liquid extraction using aqueous two-phase systems is a highly efficient technique for separation and purification of biomolecules due to the mild properties of both liquid phases. Reliable data on the phase behavior of these systems are essential for the design and operation of new separation processes; several authors reported phase diagrams for polymer-polymer systems, but data on polymer-salt systems are still relatively scarce. In this work, experimental liquid-liquid equilibrium data on water + polyethylene glycol 8000 + magnesium sulfate and water + polyethylene glycol 8000 + sodium sulfate aqueous two-phase systems were obtained at 35°C. Both equilibrium phases were analyzed by lyophilization and ashing. Experimental results were correlated with a mass-fraction-based NRTL activity coefficient model. New interaction parameters were estimated with the Simplex method. The mean deviations between the experimental and calculated compositions in both equilibrium phases is about 2%.

Thermodynamic characteristics of a novel wind-solar-liquid air energy storage system

Science.gov (United States)

Ji, W.; Zhou, Y.; Sun, Y.; Zhang, W.; Pan, C. Z.; Wang, J. J.

2017-12-01

Due to the nature of fluctuation and intermittency, the utilization of wind and solar power will bring a huge impact to the power grid management. Therefore a novel hybrid wind-solar-liquid air energy storage (WS-LAES) system was proposed. In this system, wind and solar power are stored in the form of liquid air by cryogenic liquefaction technology and thermal energy by solar thermal collector, respectively. Owing to the high density of liquid air, the system has a large storage capacity and no geographic constraints. The WS-LAES system can store unstable wind and solar power for a stable output of electric energy and hot water. Moreover, a thermodynamic analysis was carried out to investigate the best system performance. The result shows that the increases of compressor adiabatic efficiency, turbine inlet pressure and inlet temperature all have a beneficial effect.

Performance investigation on the ultrasonic atomization liquid desiccant regeneration system

International Nuclear Information System (INIS)

Yang, Zili; Zhang, Kaisheng; Hwang, Yunho; Lian, Zhiwei

2016-01-01

Highlights: • We applied ultrasonic atomization technology to boost liquid desiccant regeneration. • We established a novel UARS and made a thorough study on its performance. • We developed a performance prediction model for UARS and validated its accuracy. • The necessary regeneration temperature dropped significantly (4.4 °C) in UARS. • Energy consumption for regenerating desiccant was reduced greatly (60.4%) in UARS. - Abstract: Liquid desiccant dehumidification systems have accumulated considerable research interest in recent years for their great energy saving potential in buildings. Within the system, the regenerator recovering liquid desiccant plays a major role in its performance. When the ultrasonic atomization technology is applied to atomize the desiccant solution into numerous tiny droplets with diameters around 50 μm, the regeneration process could be greatly enhanced. To validate this approach, a novel ultrasonic atomization liquid desiccant regeneration system (UARS) was studied in this work. An Ideal Regeneration Model (IRM) was developed to predict the regeneration performance of the UARS. Additionally, thorough experiments were carried out to validate the model under different operating conditions of the desiccant solution and air stream. The model predicted values and the experimental results coincided, with the average deviation less than 7.9%. The performance of UARS was compared with other regeneration systems from the open literature, while a case study was conducted for the power consumption and energy saving potential of UARS. It was found that the ultrasonic atomization technology enabled utilization of lower-grade energy for desiccant regeneration with the regeneration temperature lowered as much as 4.4 °C. In addition, a considerable energy saving potential of up to 23.4% could be achieved by the UARS for regenerating per unit mass flow of desiccant solution, while the power consumption of the ultrasonic atomization system

Liquid Effluent Retention Facility/Effluent Treatment Facility Hazards Assessment

International Nuclear Information System (INIS)

Simiele, G.A.

1994-01-01

This document establishes the technical basis in support of Emergency Planning activities for the Liquid Effluent Retention Facility and Effluent Treatment Facility the Hanford Site. The document represents an acceptable interpretation of the implementing guidance document for DOE ORDER 5500.3A. Through this document, the technical basis for the development of facility specific Emergency Action Levels and the Emergency Planning Zone is demonstrated

removal of hazardous pollutants from industrial waste solutions using membrane techniques

International Nuclear Information System (INIS)

Selim, Y.T.M.

2001-01-01

the removal of hazardous pollutants from industrial waste solutions is of essential demand field for both scientific and industrial work. the present work includes detailed studies on the possible use of membrane technology especially liquid emulsion membrane for the removal of hazardous pollutants such as; cadmium , cobalt , lead, copper and uranium from different industrial waste solution . this research can be applied for mixed waste problems. the work carried out in this thesis is presented in three main chapters, namely introduction, experimental and results and discussion

Droplet-Sizing Liquid Water Content Sensor, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Icing is one of the most significant hazards to aircraft. A sizing supercooled liquid water content (SSLWC) sonde is being developed to meet a directly related need...

Fire hazard analysis for the K basin fuel transfer system anneses project A-15

International Nuclear Information System (INIS)

BARILO, N.F.

2001-01-01

The purpose of the Fuel Transfer System (FTS) is to move the spent nuclear fuel currently stored in the K East (KE) Basin and transfer it by shielded cask to the K West (KW) Basin. The fuel will then be processed through the existing fuel cleaning and loading system prior to being loaded into Multi-Canister Overpacks (MCO). The FTS operation is considered an intra-facility transfer because the spent fuel will stay within the 100 K area and between the K Basins. This preliminary Fire Hazards Analysis (FHA) for the K Basin FTS Annexes addresses fire hazards or fire-related concerns in accordance with U.S. Department of Energy (DOE) 420.1 (DOE 2000), and RLID 420.1 (DOE 1999), resulting from or related to the processes and equipment. It is intended to assess the risk from fire associated within the FTS Annexes to ensure that there are no undue fire hazards to site personnel and the public; the potential for the occurrence of a fire is minimized; process control and safety systems are not damaged by fire or related perils; and property damage from fire and related perils does not exceed an acceptable level. Consistent with the preliminary nature of the design information, this FHA is performed on a graded approach

Waste Issues Associated with the Safe Movement of Hazardous Chemicals

International Nuclear Information System (INIS)

Dare, J. H.; Cournoyer, M. E.

2002-01-01

Moving hazardous chemicals presents the risk of exposure for workers engaged in the activity and others that might be in the immediate area. Adverse affects are specific to the chemicals and can range from minor skin, eye, or mucous membrane irritation, to burns, respiratory distress, nervous system dysfunction, or even death. A case study is presented where in the interest of waste minimization; original shipping packaging was removed from a glass bottle of nitric acid, while moving corrosive liquid through a security protocol into a Radiological Control Area (RCA). During the transfer, the glass bottle broke. The resulting release of nitric acid possibly exposed 12 employees with one employee being admitted overnight at a hospital for observation. This is a clear example of administrative controls to reduce the generation of suspect radioactive waste being implemented at the expense of employee health. As a result of this event, material handling procedures that assure the safe movement of hazardous chemicals through a security protocol into a radiological control area were developed. Specifically, hazardous material must be transferred using original shipping containers and packaging. While this represents the potential to increase the generation of suspect radioactive waste in a radiological controlled area, arguments are presented that justify this change. Security protocols for accidental releases are also discussed. In summary, the 12th rule of ''Green Chemistry'' (Inherently Safer Chemistry for Accident Prevention) should be followed: the form of a substance used in a chemical process (Movement of Hazardous Chemicals) should be chosen to minimize the potential for chemical accidents, including releases

Waste Issues Associated with the Safe Movement of Hazardous Chemicals

Energy Technology Data Exchange (ETDEWEB)

Dare, J. H.; Cournoyer, M. E.

2002-02-26

Moving hazardous chemicals presents the risk of exposure for workers engaged in the activity and others that might be in the immediate area. Adverse affects are specific to the chemicals and can range from minor skin, eye, or mucous membrane irritation, to burns, respiratory distress, nervous system dysfunction, or even death. A case study is presented where in the interest of waste minimization; original shipping packaging was removed from a glass bottle of nitric acid, while moving corrosive liquid through a security protocol into a Radiological Control Area (RCA). During the transfer, the glass bottle broke. The resulting release of nitric acid possibly exposed 12 employees with one employee being admitted overnight at a hospital for observation. This is a clear example of administrative controls to reduce the generation of suspect radioactive waste being implemented at the expense of employee health. As a result of this event, material handling procedures that assure the safe movement of hazardous chemicals through a security protocol into a radiological control area were developed. Specifically, hazardous material must be transferred using original shipping containers and packaging. While this represents the potential to increase the generation of suspect radioactive waste in a radiological controlled area, arguments are presented that justify this change. Security protocols for accidental releases are also discussed. In summary, the 12th rule of ''Green Chemistry'' (Inherently Safer Chemistry for Accident Prevention) should be followed: the form of a substance used in a chemical process (Movement of Hazardous Chemicals) should be chosen to minimize the potential for chemical accidents, including releases.

System Design Package for SIMS Prototype System 3, Solar Heating and Domestic Hot Water

Science.gov (United States)

1978-01-01

A collation of documents and drawings are presented that describe a prototype solar heating and hot water system using liquid flat plate collectors and a gas or electric furnace energy subsystem. The system was designed for installation into a single-family dwelling. The description, performance specification, subsystem drawings, verification plan/procedure, and hazard analysis of the system are packaged for evaluation of the system with information sufficient to assemble a similar system.

Optical Mass Gauging System for Measuring Liquid Levels in a Reduced Gravity Environment

Science.gov (United States)

Sullenberger, Ryan M.; Munoz, Wesley M.; Lyon, Matt P.; Vogel, Kenny; Yalin, Azer P.; Korman, Valentin; Polzin, Kurt A.

2010-01-01

A compact and rugged fiber-coupled liquid volume sensor designed for flight on a sounding rocket platform is presented. The sensor consists of a Mach-Zehnder interferometer capable of measuring the amount of liquid contained in a tank under any gravitational conditions, including a microgravity environment, by detecting small changes in the index of refraction of the gas contained within a sensing region. By monitoring changes in the interference fringe pattern as the system undergoes a small compression provided by a piston, the ullage volume of a tank can be directly measured allowing for a determination of the liquid volume. To demonstrate the technique, data are acquired using two tanks containing different volumes of liquid, which are representative of the levels of liquid in a tank at different time periods during a mission. The two tanks are independently exposed to the measurement apparatus, allowing for a determination of the liquid level in each. In a controlled, laboratory test of the unit, the system demonstrated a capability of measuring a liquid level in an individual tank of 10.53 mL with a 2% error. The overall random uncertainty for the flight system is higher than that one test, at +/- 1.5 mL.

Liquid metal MHD generator systems

International Nuclear Information System (INIS)

Satyamurthy, P.; Dixit, N.S.; Venkataramani, N.; Rohatgi, V.K.

1985-01-01

Liquid Metal MHD (LMMHD) Generator Systems are becoming increasingly important in space and terrestrial applications due to their compactness and versatility. This report gives the current status and economic viability of LMMHD generators coupled to solar collectors, fast breeder reactors, low grade heat sources and conventional high grade heat sources. The various thermodynamic cycles in the temperatures range of 100degC-2000degC have been examined. The report also discusses the present understanding of various loss mechanisms inherent in LMMHD systems and the techniques for overcoming these losses. A small mercury-air LMMHD experimental facility being set up in Plasma Physics Division along with proposals for future development of this new technology is also presented in this report. (author)

Notification: Audit of Security Categorization for EPA Systems That Handle Hazardous Material Information

Science.gov (United States)

Project #OA-FY18-0089, January 8, 2018. The OIG plans to begin preliminary research to determine whether the EPA classified the sensitivity of data for systems that handle hazardous waste material information as prescribed by NIST.

Destructive Interactions Between Mitigation Strategies and the Causes of Unexpected Failures in Natural Hazard Mitigation Systems

Science.gov (United States)

Day, S. J.; Fearnley, C. J.

2013-12-01

Large investments in the mitigation of natural hazards, using a variety of technology-based mitigation strategies, have proven to be surprisingly ineffective in some recent natural disasters. These failures reveal a need for a systematic classification of mitigation strategies; an understanding of the scientific uncertainties that affect the effectiveness of such strategies; and an understanding of how the different types of strategy within an overall mitigation system interact destructively to reduce the effectiveness of the overall mitigation system. We classify mitigation strategies into permanent, responsive and anticipatory. Permanent mitigation strategies such as flood and tsunami defenses or land use restrictions, are both costly and 'brittle': when they malfunction they can increase mortality. Such strategies critically depend on the accuracy of the estimates of expected hazard intensity in the hazard assessments that underpin their design. Responsive mitigation strategies such as tsunami and lahar warning systems rely on capacities to detect and quantify the hazard source events and to transmit warnings fast enough to enable at risk populations to decide and act effectively. Self-warning and voluntary evacuation is also usually a responsive mitigation strategy. Uncertainty in the nature and magnitude of the detected hazard source event is often the key scientific obstacle to responsive mitigation; public understanding of both the hazard and the warnings, to enable decision making, can also be a critical obstacle. Anticipatory mitigation strategies use interpretation of precursors to hazard source events and are used widely in mitigation of volcanic hazards. Their critical limitations are due to uncertainties in time, space and magnitude relationships between precursors and hazard events. Examples of destructive interaction between different mitigation strategies are provided by the Tohoku 2011 earthquake and tsunami; recent earthquakes that have impacted

Liquid Nitrogen (Oxygen Simulant) Thermodynamic Vent System Test Data Analysis

Science.gov (United States)

Hedayat, A.; Nelson, S. L.; Hastings, L. J.; Flachbart, R. H.; Tucker, S. P.

2005-01-01

In designing systems for the long-term storage of cryogens in low-gravity (space) environments, one must consider the effects of thermal stratification on tank pressure that will occur due to environmental heat leaks. During low-gravity operations, a Thermodynamic Vent System (TVS) concept is expected to maintain tank pressure without propellant resettling. A series of TVS tests was conducted at NASA Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a liquid oxygen (LO2) simulant. The tests were performed at tank til1 levels of 90%, 50%, and 25%, and with a specified tank pressure control band. A transient one-dimensional TVS performance program is used to analyze and correlate the test data for all three fill levels. Predictions and comparisons of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented.

Homogeneous Liquid–Liquid Extraction of Rare Earths with the Betaine—Betainium Bis(trifluoromethylsulfonyl)imide Ionic Liquid System

Science.gov (United States)

Hoogerstraete, Tom Vander; Onghena, Bieke; Binnemans, Koen

2013-01-01

Several fundamental extraction parameters such as the kinetics and loading were studied for a new type of metal solvent extraction system with ionic liquids. The binary mixture of the ionic liquid betainium bis(trifluoromethylsulfonyl)imide and water shows thermomorphic behavior with an upper critical solution temperature (UCST), which can be used to avoid the slower mass transfer due to the generally higher viscosity of ionic liquids. A less viscous homogeneous phase and mixing on a molecular scale are obtained when the mixture is heated up above 55 °C. The influence of the temperature, the heating and cooling times, were studied for the extraction of neodymium(III) with betaine. A plausible and equal extraction mechanism is proposed in bis(trifluoromethylsulfonyl)imide, nitrate, and chloride media. After stripping of the metals from the ionic liquid phase, a higher recovery of the ionic liquid was obtained by salting-out of the ionic liquid fraction lost by dissolution in the aqueous phase. The change of the upper critical solution temperature by the addition of HCl or betaine was investigated. In addition, the viscosity was measured below and above the UCST as a function of the temperature. PMID:24169434

Effect of Liquid Crystalline Systems Containing Antimicrobial Compounds on Infectious Skin Bacteria.

Science.gov (United States)

Souza, Carla; Watanabe, Evandro; Aires, Carolina Patrícia; Lara, Marilisa Guimarães

2017-08-01

This study aimed (i) to prepare liquid crystalline systems (LCS) of glyceryl monooleate (GMO) and water containing antibacterial compounds and (ii) to evaluate their potential as drug delivery systems for topical treatment of bacterial infections. Therefore, LCS containing CPC (cetylpyridinium chloride) (LCS/CPC) and PHMB (poly(hexamethylene biguanide) hydrochloride) (LCS/PHMB) were prepared and the liquid crystalline phases were identified by polarizing light microscopy 24 h and 7 days after preparation. The in vitro drug release profile and in vitro antibacterial activity of the systems were assessed using the double layer agar diffusion method against Staphylococcus aureus, methicillin-resistant S. aureus, Staphylococcus epidermidis, Escherichia coli, and Enterococcus faecalis. The interaction between GMO and the drugs was evaluated by a drug absorption study. Stable liquid crystalline systems containing CPC and PHMB were obtained. LCS/PHMB decreased the PHMB release rate and exerted strong antibacterial activity against all the investigated bacteria. In contrast, CPC interacted with GMO so strongly that it became attached to the system; the amount released was not sufficient to exert antibacterial activity. Therefore, the studied liquid crystalline systems were suitable to deliver PHMB, but not CPC. Accordingly, it was demonstrated that GMO interacts with each drug differently, which may interfere in the final efficiency of GMO/water LCS.

An Integrated GIS-Expert System Framework for Live Hazard Monitoring and Detection

Directory of Open Access Journals (Sweden)

Steven M. Rozic

2008-02-01

Full Text Available In the context of hazard monitoring, using sensor web technology to monitor anddetect hazardous conditions in near-real-time can result in large amounts of spatial data thatcan be used to drive analysis at an instrumented site. These data can be used for decisionmaking and problem solving, however as with any analysis problem the success ofanalyzing hazard potential is governed by many factors such as: the quality of the sensordata used as input; the meaning that can be derived from those data; the reliability of themodel used to describe the problem; the strength of the analysis methods; and the ability toeffectively communicate the end results of the analysis. For decision makers to make use ofsensor web data these issues must be dealt with to some degree. The work described in thispaper addresses all of these areas by showing how raw sensor data can be automaticallytransformed into a representation which matches a predefined model of the problem context.This model can be understood by analysis software that leverages rule-based logic andinference techniques to reason with, and draw conclusions about, spatial data. These toolsare integrated with a well known Geographic Information System (GIS and existinggeospatial and sensor web infrastructure standards, providing expert users with the toolsneeded to thoroughly explore a problem site and investigate hazards in any domain.

Risk assessments for energy systems and role of preliminary degree-of-hazard evaluations

International Nuclear Information System (INIS)

Habegger, L.J.; Fingleton, D.J.

1985-11-01

The appropriate approach to risk or hazard assessment can vary considerably, depending on various factors, including the intended application of the results and the time other resources available to conduct the assessment. This paper illustrates three types of interrelated assessments. Although they can be mutually supportive, they have fundamentally different objectives, which require major differences in approach. The example of the overall risk assessment of alternative major energy technologies illustrates the compilation of a wide range of available risk data applicable to these systems. However, major uncertainties exist in the assessments, and public perception of their importance could play an important role in final system evaluations. A more narrowly defined risk assessment, often focusing on an individual component of a larger system, is the most commonly used approach in regulatory applications. The narrow scope allows in-depth analysis of risks and associated uncertainties, but it may also contribute to a loss of perspective on the magnitude of the assessed risk relative to that of the unassessed risks. In some applications, it is useful to conduct semiquantitative degree-of-hazard evaluations as a means of setting priorities for detailed risk assessment. The MAHAS procedure described in this paper provides a means of rapidly ranking relative hazards from various sources using easily accessible data. However, these rankings should not be used as definitive input for selecting technology alternatives or developing regulations. 25 refs., 6 tabs

The Daily Liquidity Effect in a Floor System – Empirical Evidence from the Norwegian Market

OpenAIRE

Syrstad, Olav

2012-01-01

This paper analyses the liquidity effect in Norway by examining the relationship between a range of liquidity variables and five different measures of the short-term interbank premium. The models are estimated on data from January 2007 and up to the end of September 2011, a period in which Norges Bank implemented its liquidity policy within a so-called floor system, and prior to the new liquidity system introduced on 3 October 2011. In a floor system the key policy rate is equal to banks' dep...

Chemical Warfare Agent Operational Exposure Hazard Assessment Research: FY07 Report and Analysis

Science.gov (United States)

2010-07-01

agent migration rates. As stated by Armour and Sturgeon (1992), the extent of the contact hazard depends on the initial degree of contamination, the...with a contaminated surface. 2.1.5 Literature Cited 1. Armour , S.J; Sturgeon, W.R. Liquid Hazard from Chemical Warfare Agents for Pilots of High...the neck area was clipped and prepped with betadine, and the animal covered with a sterile surgical drape . The planned incision areas in the

Creation of a common information system on the Republic of Kazakhstan radiation hazardous objects

International Nuclear Information System (INIS)

Kadyrzhanov, K.K.; Kuterbekov, K.A.; Lukashenko, S.N.; Morenko, V.S.; Glushchenko, V.N.

2005-01-01

Works on creation of a common information system on the Republic of Kazakhstan territory radiation hazardous objects for providing of radiation situation control and stewardship decision making under nature-conservative measures conducting are considered. The information system is forming on the base of up-to-date GIS system - ArcGIS - and incorporates two databases - geographical and attributive

Interfacial transport phenomena and stability in liquid-metal/water systems: scaling considerations

International Nuclear Information System (INIS)

Abdulla, S.; Liu, X.; Anderson, M.; Bonazza, R.; Corradini, M.; Cho, D.

2001-01-01

One concept being considered for steam generation in innovative nuclear reactor applications, involves water coming into direct contact with a circulating molten metal. The vigorous agitation of the two fluids, the direct liquid-liquid contact and the consequent large interfacial area give rise to very high heat transfer coefficients and rapid steam generation. For an optimum design of such direct contact heat exchange and vaporization systems, detailed knowledge is necessary of the various flow regimes, interfacial transport phenomena, heat transfer and operational stability. In this paper we describe current results from the first year of this research that studies the transport phenomena involved with the injection of water into molten metals (e.g., lead alloys). In particular, this work discusses scaling considerations related to direct contact heat exchange, our experimental plans for investigation and a test plan for the important experimental parameters; i.e., the water and liquid metal mass flow rates, the liquid metal pool temperature and the ambient pressure of the direct contact heat exchanger. Past experimental work and initial scaling results suggest that our experiments can directly represent the proper liquid metal pool temperature and the water subcooling. The experimental variation in water and liquid metal flow rates and system pressure (1-10 bar), although smaller than the current conceptual system designs, is sufficient to verify the expected scale effects to demonstrate the phenomena. (authors)

VOC and HAP recovery using ionic liquids

Energy Technology Data Exchange (ETDEWEB)

Michael R. Milota : Kaichang Li

2007-05-29

During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200°C (almost 400°F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120°C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy

(Liquid + liquid) equilibrium of {l_brace}water + phenol + (1-butanol, or 2-butanol, or tert-butanol){r_brace} systems

Energy Technology Data Exchange (ETDEWEB)

Hadlich de Oliveira, Leonardo [School of Chemical Engineering, State University of Campinas, UNICAMP, P.O. Box 6066, 13083-970 Campinas-SP (Brazil); Aznar, Martin, E-mail: maznar@feq.unicamp.b [School of Chemical Engineering, State University of Campinas, UNICAMP, P.O. Box 6066, 13083-970 Campinas-SP (Brazil)

2010-11-15

(Liquid + liquid) equilibrium (LLE) and binodal curve data were determined for the systems (water + phenol + tert-butanol) at T = 298.15 K, (water + phenol + 2-butanol) and (water + phenol + 1-butanol) at T = 298.15 K and T = 313.15 K by the combined techniques of densimetry and refractometry. Type I curve (for tert-butanol) and Type II curves (for 1- and 2-butanol) were found. The data were correlated with the NRTL model and the parameters estimated present root mean square deviations below 2% for the system with tert-butanol and lower than 0.8% for the other systems.

Fluorescent optical liquid-level sensor

International Nuclear Information System (INIS)

Weiss, Jonathan D.

2000-01-01

An optical method of detecting a liquid level is presented that uses fluorescence radiation generated in an impurity-doped glass or plastic slab. In operation, the slab is inserted into the liquid and pump light is coupled into it so that the light is guided by the slab-air interface above the liquid and escapes into the liquid just below its surface. Since the fluorescence is generated only in that section of the slab above the liquid, the fluorescence power will monotonically decrease with increasing liquid level. Thus, a relationship can be established between any signal proportional to it and the liquid level. Because optical fibers link the pump source and the detector of fluorescence radiation to the sensor, no electrical connections are needed in or near the liquid. Their absence vastly decreases the hazard associated with placing a liquid-level sensor in a potentially explosive environment. A laboratory prototype, consisting of a methyl styrene slab doped with an organic dye, has been built and successfully tested in water. Its response to liquid level when pumped by a tunable argon-ion laser at 476, 488, and 496 nm, and by a blue LED, is presented and shown to be consistent with theory. The fluorescence spectra, optical efficiency, temperature, and other effects are also presented and discussed. (c) 2000 Society of Photo-Optical Instrumentation Engineers

An overview of natural hazard impacts to railways and urban transportation systems

Science.gov (United States)

Bíl, Michal; Nezval, Vojtěch; Bílová, Martina; Andrášik, Richard; Kubeček, Jan

2017-04-01

We present an overview and two case studies of natural hazard impacts on rail transportation systems in the Czech Republic. Flooding, landsliding, heavy snowfall, windstorms and glaze (black ice) are the most common natural processes which occur in this region. Whereas flooding and landsliding usually cause direct damage to the transportation infrastructure, other hazards predominantly cause indirect losses. Railway and urban tramline networks are almost fully dependent on electricity which is provided by a system of overhead lines (electric lines above the tracks). These lines are extremely susceptible to formation of glaze which blocks conduction of electric current. A December 2014 glaze event caused significant indirect losses in the largest Czech cities and railways due to the above-mentioned process. Details of this event will be provided during the presentation. Windstorms usually cause tree falls which can affect overhead lines and physically block railway tracks. Approximately 30 % of the Czech railway network is closer than 50 m from the nearest forest. This presents significant potential for transport interruption due to falling trees. Complicated legal relations among the owners of the plots of land along railways, the environment (full-grown trees and related habitat), and the railway administrator are behind many traffic interruptions due to falling trees. We have registered 2040 tree falls between 2012 and 2015 on the railway network. A model of the fallen tree hazard was created for the entire Czech railway network. Both above-mentioned case studies provide illustrative examples of the increased fragility of the modern transportation systems which fully rely on electricity. Natural processes with a low destructive power are thereby able to cause network wide service cut-offs.

European protection principles against external hazards by means of Emergency Power Supply and Control Safety System Building in Nuclear Power Plants

Energy Technology Data Exchange (ETDEWEB)

Gallinat, Dipl Ing [Max Aicher Engineering GmbH, Freilassing (Germany)

2016-10-15

One of the most important nuclear power plant safety requirements is a redundant and independent power system. This requires such a design of emergency power systems that failure of one will not adversely impact the other. External hazards of natural origin or linked to human activity could potentially affect plant safety. The general objective of the design provisions is to ensure that the safety functions of the systems and components required to return the plant to a safe shutdown state and to prevent and limit radioactive release are not adversely affected. As external hazards are site dependent, Technical Guidelines specify that 'it is not necessary to take all of the hazards in a standardized design; such external hazards as external flooding, drought, ice formation and toxic, corrosive or combustible gases may be dealt with only for a specific plant, on a plant specific basis'. In accordance with the Technical Guidelines, external hazards are taken into consideration at the design stage consistently with internal events or hazards. The basic design principle is to protect against external hazards in accordance with the Technical Guidelines using a 'load case' procedure.

Extension of nano-scaled exploration into solution/liquid systems using tip-enhanced Raman scattering

Science.gov (United States)

Pienpinijtham, Prompong; Vantasin, Sanpon; Kitahama, Yasutaka; Ekgasit, Sanong; Ozaki, Yukihiro

2017-08-01

This review shows updated experimental cases of tip-enhanced Raman scattering (TERS) operated in solution/liquid systems. TERS in solution/liquid is still infancy, but very essential and challenging because crucial and complicated biological processes such as photosynthesis, biological electron transfer, and cellular respiration take place and undergo in water, electrolytes, or buffers. The measurements of dry samples do not reflect real activities in those kinds of systems. To deeply understand them, TERS in solution/liquid is needed to be developed. The first TERS experiment in solution/liquid is successfully performed in 2009. After that time, TERS in solution/liquid has gradually been developed. It shows a potential to study structural changes of biomembranes, opening the world of dynamic living cells. TERS is combined with electrochemical techniques, establishing electrochemical TERS (EC-TERS) in 2015. EC-TERS creates an interesting path to fulfil the knowledge about electrochemical-related reactions or processes. TERS tip can be functionalized with sensitive molecules to act as a "surface-enhanced Raman scattering (SERS) at tip" for investigating distinct properties of systems in solution/liquid e.g., pH and electron transfer mechanism. TERS setup is continuously under developing. Versatile geometry of the setup and a guideline of a systematic implementation for a setup of TERS in solution/liquid are proposed. New style of setup is also reported for TERS imaging in solution/liquid. From all of these, TERS in solution/liquid will expand a nano-scaled exploration into solution/liquid systems of various fields e.g., energy storages, catalysts, electronic devices, medicines, alternative energy sources, and build a next step of nanoscience and nanotechnology.

Thaw flow control for liquid heat transport systems

Science.gov (United States)

Kirpich, Aaron S.

1989-01-01

In a liquid metal heat transport system including a source of thaw heat for use in a space reactor power system, the thaw flow throttle or control comprises a fluid passage having forward and reverse flow sections and a partition having a plurality of bleed holes therein to enable fluid flow between the forward and reverse sections. The flow throttle is positioned in the system relatively far from the source of thaw heat.

The Daya Bay antineutrino detector filling system and liquid mass measurement

Science.gov (United States)

Band, H. R.; Cherwinka, J. J.; Draeger, E.; Heeger, K. M.; Hinrichs, P.; Lewis, C. A.; Mattison, H.; McFarlane, M. C.; Webber, D. M.; Wenman, D.; Wang, W.; Wise, T.; Xiao, Q.

2013-09-01

The Daya Bay Reactor Neutrino Experiment has measured the neutrino mixing angle θ13 to world-leading precision. The experiment uses eight antineutrino detectors filled with 20-tons of gadolinium-doped liquid scintillator to detect antineutrinos emitted from the Daya Bay nuclear power plant through the inverse beta decay reaction. The precision measurement of sin22θ13 relies on the relative antineutrino interaction rates between detectors at near (400 m) and far (roughly 1.8 km) distances from the nuclear reactors. The measured interaction rate in each detector is directly proportional to the number of protons in the liquid scintillator target. A precision detector filling system was developed to simultaneously fill the three liquid zones of the antineutrino detectors and measure the relative target mass between detectors to < 0.02%. This paper describes the design, operation, and performance of the system and the resulting precision measurement of the detectors' target liquid masses.

78 FR 41496 - Pipeline Safety: Meetings of the Gas and Liquid Pipeline Advisory Committees

Science.gov (United States)

2013-07-10

... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration [Docket No. PHMSA-2013-0156] Pipeline Safety: Meetings of the Gas and Liquid Pipeline Advisory Committees AGENCY: Pipeline and Hazardous Materials Safety Administration (PHMSA), DOT. ACTION: Notice of advisory committee...

Experimental investigation of liquid-liquid system drop size distribution in Taylor-Couette flow and its application in the CFD simulation

Science.gov (United States)

Farzad, Reza; Puttinger, Stefan; Pirker, Stefan; Schneiderbauer, Simon

Liquid-liquid systems are widely used in the several industries such as food, pharmaceutical, cosmetic, chemical and petroleum. Drop size distribution (DSD) plays a key role as it strongly affects the overall mass and heat transfer in the liquid-liquid systems. To understand the underlying mechanisms single drop breakup experiments have been done by several researchers in the Taylor-Couette flow; however, most of those studies concentrate on the laminar flow regime and therefore, there is no sufficient amount of data in the case of in turbulent flows. The well-defined pattern of the Taylor-Couette flow enables the possibility to investigate DSD as a function of the local fluid dynamic properties, such as shear rate, which is in contrast to more complex devices such as stirred tank reactors. This paper deals with the experimental investigation of liquid-liquid DSD in Taylor-Couette flow. From high speed camera images we found a simple correlation for the Sauter mean diameter as a function of the local shear employing image processing. It is shown that this correlation holds for different oil-in-water emulsions. Finally, this empirical correlation for the DSD is used as an input data for a CFD simulation to compute the local breakup of individual droplets in a stirred tank reactor.

Prediction of liquid-liquid equilibria for polyethylene glycol based aqueous two-phase system by ASOG and UNIFAC method

Directory of Open Access Journals (Sweden)

M. Perumalsamy

2009-03-01

Full Text Available Liquid-Liquid equilibrium data were obtained for the polyethylene glycol2000(PEG2000-sodium citrate-water system at 298.15, 308.15 and 318.15 K. The effect of temperature on binodal and tie line data was studied and published in a previous article (Murugesan and Perumalsamy, 2005. The interaction parameters of ASOG and UNIFAC models were estimated using the LLE data of PEG2000-sodium citrate-water system and are used to predict the LLE data for PEG6000-sodium citrate-water system at 298.15, 308.15 and 318.15 K (literature data. The predicted LLE data by both ASOG and UNIFAC models showed good agreement with the experimental and literature data.

Ionic Liquids for Utilization of Waste Heat from Distributed Power Generation Systems

Energy Technology Data Exchange (ETDEWEB)

Joan F. Brennecke; Mihir Sen; Edward J. Maginn; Samuel Paolucci; Mark A. Stadtherr; Peter T. Disser; Mike Zdyb

2009-01-11

The objective of this research project was the development of ionic liquids to capture and utilize waste heat from distributed power generation systems. Ionic Liquids (ILs) are organic salts that are liquid at room temperature and they have the potential to make fundamental and far-reaching changes in the way we use energy. In particular, the focus of this project was fundamental research on the potential use of IL/CO2 mixtures in absorption-refrigeration systems. Such systems can provide cooling by utilizing waste heat from various sources, including distributed power generation. The basic objectives of the research were to design and synthesize ILs appropriate for the task, to measure and model thermophysical properties and phase behavior of ILs and IL/CO2 mixtures, and to model the performance of IL/CO2 absorption-refrigeration systems.

Bioprocessing of a stored mixed liquid waste

Energy Technology Data Exchange (ETDEWEB)

Wolfram, J.H.; Rogers, R.D. [Idaho National Engineering Lab., Idaho Falls, ID (United States); Finney, R. [Mound Applied Technologies, Miamisburg, OH (United States)] [and others

1995-12-31

This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is an unique microbial strain which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for the processing of stored liquid scintillation wastes. During the past year a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSC). Based on data obtained from this demonstration, the Ohio EPA granted the Mound Applied Technologies Lab a treatability permit allowing the limited processing of actual mixed waste. Since August 1994, the system has been successfully processing stored, {open_quotes}hot{close_quotes} LSC waste. The initial LSC waste fed into the system contained 11% pseudocumene and detectable quantities of plutonium. Another treated waste stream contained pseudocumene and tritium. Data from this initial work shows that the hazardous organic solvent, and pseudocumene have been removed due to processing, leaving the aqueous low level radioactive waste. Results to date have shown that living cells are not affected by the dissolved plutonium and that 95% of the plutonium was sorbed to the biomass. This paper discusses the bioprocess, rates of processing, effluent, and the implications of bioprocessing for mixed waste management.

Radianttrademark Liquid Radioisotope Intravascular Radiation Therapy System

International Nuclear Information System (INIS)

Eigler, N.; Whiting, J.; Chernomorsky, A.; Jackson, J.; Knapp, F.F. Jr.; Litvack, F.

1998-01-01

RADIANTtrademark is manufactured by United States Surgical Corporation, Vascular Therapies Division, (formerly Progressive Angioplasty Systems). The system comprises a liquid β-radiation source, a shielded isolation/transfer device (ISAT), modified over-the-wire or rapid exchange delivery balloons, and accessory kits. The liquid β-source is Rhenium-188 in the form of sodium perrhenate (NaReO 4 ), Rhenium-188 is primarily a β-emitter with a physical half-life of 17.0 hours. The maximum energy of the β-particles is 2.1 MeV. The source is produced daily in the nuclear pharmacy hot lab by eluting a Tungsten-188/Rhenium-188 generator manufactured by Oak Ridge National Laboratory (ORNL). Using anion exchange columns and Millipore filters the effluent is concentrated to approximately 100 mCi/ml, calibrated, and loaded into the (ISAT) which is subsequently transported to the cardiac catheterization laboratory. The delivery catheters are modified Championtrademark over-the-wire, and TNTtrademark rapid exchange stent delivery balloons. These balloons have thickened polyethylene walls to augment puncture resistance; dual radio-opaque markers and specially configured connectors

Advanced liquid metal reactor plant control system