Sample records for halley ir spectrum

  1. The Acetylene Laboratory IR Spectrum: New Quantitative Studies (United States)

    Jaccquemart, D.; Lacome, N.; Gomez, L.; Mandin, J.


    The acetylene molecule 12C2H2 shows numerous vibration - rotation bands throughout the IR spectrum. Vibrational levels of C2H2 are grouped into clusters almost regularly spaced every 700 cm-1, from the fundamental ν5 band, at 13.6 μm, up to the visible. Several IR spectral regions where C2H2 bands occur have been extensively studied in the past years, mainly in order to obtain absolute individual line intensities and to improve spectroscopic databases as HITRAN or GEISA. This quantitative spectroscopy work is performed with the aid of Fourier transform interferometers to obtain absorption spectra, and using a multispectrum fitting procedure to retrieve line parameters from these spectra. For usual applications, a semi-empirical model based on the Herman-Wallis factor is used to generate line lists dedicated to spectroscopic databases. This poster gives a summary of all the spectral regions studied for acetylene 12C2H2, pointing out the current state of the spectroscopic databases HITRAN/GEISA. Works in progress (around 1300 cm-1) and in project (0 - 500 cm-1) will also be presented. Data available in the literature, or obtained in the recent works, have been compiled to set up line lists usable for applications and dedicated to databases. On the whole the number of transitions is twice compared to the actual HITRAN 2004 database plus the 2007 updates and is ranging from 700 to 9600 cm-1.

  2. Halley's Comet: A Bibliography. (United States)

    Freitag, Ruth S., Comp.

    Included in this bibliography are over 3,200 references to publications on Halley's Comet, its history, orbital motion, and physical characteristics, meteor streams associated with it, preparations for space missions to study it in 1986, and popular reaction to its appearances. Also cited are a few papers that, although they devote little…

  3. Peter Halley / Peter Halley ; interv. Tilman Baumgärtel

    Index Scriptorium Estoniae

    Halley, Peter


    Ameerika maalikunstnikust Peter Halley'st (sünd. 1953) ja tema loomingust, intervjuu kunstnikuga tema New Yorgi ateljees 30. XII 1999. Peter Halley võrgustikke kujutavatest maalidest, elektroonilise teadetetahvli The Thing ja Moodsa Kunsti Muuseumi veebilehekülje jaoks tehtud digitaalsetest töödest ning muust

  4. Near-Ir surface-enhanced Raman spectrum of lignin (United States)

    Umesh P. Agarwal; Richard S. Reiner


    Compacted powders of commercially available nano- and microparticles of silver were used to successfully induce the surface enhanced Raman scattering (SERS) effect in spruce milled-wood lignin (MWL). For the two silver particle sizes used in this investigation, the spectra were mostly similar. Some general characteristics of the lignin SERS spectrum are described. The...

  5. The 2-loop matter power spectrum and the IR-safe integrand

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco, John Joseph M.; Foreman, Simon; Green, Daniel; Senatore, Leonardo, E-mail:, E-mail:, E-mail:, E-mail: [Stanford Institute for Theoretical Physics and Department of Physics, Stanford University, Stanford, CA 94306 (United States)


    Large scale structure surveys are likely the next leading probe of cosmological information. It is therefore crucial to reliably predict their observables. The Effective Field Theory of Large Scale Structures (EFTofLSS) provides a manifestly convergent perturbation theory for the weakly non-linear regime, where dark matter correlation functions are computed in an expansion of the wavenumber k over the wavenumber associated to the non-linear scale k{sub NL}. To push the predictions to higher wavenumbers, it is necessary to compute the 2-loop matter power spectrum. For equal-time correlators, exactly as with standard perturturbation theory, there are IR divergences present in each diagram that cancel completely in the final result. We develop a method by which all 2-loop diagrams are computed as one integral, with an integrand that is manifestly free of any IR divergences. This allows us to compute the 2-loop power spectra in a reliable way that is much less numerically challenging than standard techniques. We apply our method to scaling universes where the linear power spectrum is a single power law of k, and where IR divergences can particularly easily interfere with accurate evaluation of loop corrections if not handled carefully. We show that our results are independent of IR cutoff and, after renormalization, of the UV cutoff, and comment how the method presented here naturally generalizes to higher loops.

  6. The Jet-Cooled High-Resolution IR Spectrum of Formic Acid Cyclic Dimer (United States)

    Goubet, Manuel; Bteich, Sabath; Huet, Therese R.; Pirali, Olivier; Asselin, Pierre; Soulard, Pascale; Jabri, Atef; Roy, P.; Georges, Robert


    As the simplest carboxylic acid, formic acid (FA) is an excellent model molecule to investigate the general properties of carboxylic acids. FA is also an atmospherically and astrophysically relevant molecule. It is well known that its dimeric form is predominant in the gas phase at temperatures below 423 K. The cyclic conformation of the dimer (FACD) is an elementary system to be understood for the concerted hydrogen transfer through equivalent hydrogen bonds, an essential process within biomolecules. The IR range is a crucial spectral region, particularly the far-IR, as it gives a direct access to the intermolecular vibrational modes involved in this process. Moreover, due to its centrosymmetric conformation, the FACD exhibits no pure rotation spectrum and, due to spectral line congestion and Doppler broadening, IR bands cannot be rotationally resolved at room temperature. So far, only parts of the ν_{5}-GS band (C-O stretch) have been observed under jet-cooled conditions using laser techniques. We present here six rotationally resolved IR bands of FACD recorded under jet-cooled conditions using the Jet-AILES apparatus and the QCL spectrometer at MONARIS, including the far-IR ν_{24}-GS band (intermolecular in-plane bending). Splitting due to vibration-rotation-tunneling motions are clearly observed. A full spectral analysis is in progress starting from the GS constants obtained by Goroya et al. and with the support of electronic structure calculations. T. Miyazawa and K. S. Pitzer, J. Am. Chem. Soc. 81, 74, 1959 R. Georges, M. Freytes, D. Hurtmans, I. Kleiner, J. Vander Auwera, M. Herman, Chem. Phys. 305, 187, 2004 M. Ortlieb and M. Havenith, J. Phys. Chem. A 111, 7355, 2007; K. G. Goroya, Y. Zhu, P. Sun and C. Duan, J. Chem. Phys. 140, 164311, 2014 This work is supported by the CaPPA project (Chemical and Physical Properties of the Atmosphere) ANR-11-LABX-0005-01

  7. A fully integrated BPSK amplitude and spectrum tunable transmitter for IR-UWB system (United States)

    Lingli, Xia; Yumei, Huang; Zhiliang, Hong


    A 3-5 GHz low power BPSK modulated impulse radio UWB transmitter is implemented in 0.13 μm CMOS technology. In this design the amplitude and spectrum of the output impulse are both tunable to solve the special problem in IR-UWB, where it is difficult to control the spectrum. Measurement results indicate that, by changing the control bits in the gain control circuit and differential circuit, the 3-step peak-to-peak voltage amplitudes are 240, 170 and 115 mV and the center frequency of the impulse can be tuned from 3.2 to 4.1 GHz. A power controlled output buffer is designed to drive the antenna. The total power consumption is only 4.44 mW when transmitting a baseband signal of 100 MHz. The chip area is 1.2 × 1.4 mm2.

  8. The Comet Halley Handbook: An Observer's Guide. Second Edition. (United States)

    Yeomans, Donald K.

    This handbook contains information on: (1) the orbit of comet Halley; (2) the expected physical behavior of comet Halley in 1985-1986, considering brightness estimates, coma diameters, and tail lengths; (3) observing conditions for comet Halley in 1985-1986; and (4) observing conditions for the dust tail of comet Halley in 1985-1986. Additional…


    National Aeronautics and Space Administration — This data set presents the photometric magnitude measurements of 1P/Halley submitted to the International Halley Watch (IHW) Photometry and Polarimetry Network...


    National Aeronautics and Space Administration — This data set presents the photometry of comet 1P/Halley collected by the International Halley Watch (IHW) Infrared Studies Network (IRSN) over the period September...


    National Aeronautics and Space Administration — This data set presents the fluxes derived from narrow band photometry of Comet 1P/Halley as part of the International Halley Watch (IHW) Photometry and Polarimetry...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the IHW....


    National Aeronautics and Space Administration — Report of spectrograms of comet 1P/Halley taken by amateur astronomers and submitted as part of the International Halley Watch Amateur Network. No digital data are...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...

  20. IHW COMET HALLEY RADAR DATA V1.0 (United States)

    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...

  13. On LAM's and SAM's for Halley's rotation (United States)

    Peale, Stanton J.


    Non principal axis rotation for comet Halley is inferred from dual periodicities evident in the observations. The modes where the spin axis precesses around the axis of minimum moment of inertia (long axis mode or LAM) and where it precesses around the axis of maximum moment of inertia (short axis mode or SAM) are described from an inertial point of view. The currently favored LAM model for Halley's rotation state satisfies observational and dynamical constraints that apparently no SAM can satisfy. But it cannot reproduce the observed post perihelion brightening through seasonal illumination of localized sources on the nucleus, whereas a SAM can easily produce post or pre perihelion brightening by this mechanism. However, the likelihood of a LAM rotation for elongated nuclei of periodic comets such as Halley together with Halley's extreme post perihelion behavior far from the Sun suggest that Halley's post perihelion brightening may be due to effects other than seasonal illumination of localized sources, and therefore such brightening may not constrain its rotation state.

  14. DFT analysis of the structure and IR spectrum of potassium salt of diphenylsulfophthalide - A model compound for polydiphenylenesulfophthalide salts (United States)

    Shishlov, N. M.; Akhmetzyanov, Sh S.; Khursan, S. L.


    Experimental IR spectra of crystalline dried and non-dried potassium diphenylsulfophthalide (TAC-K) as a model compound for polymeric salts are presented. DFT analysis (B3LYP/6-311G(d,p)) of the structure and IR spectra of a series of compounds similar in structure to TAC-K as well as their dimers indicates that the sulfonate group environment strongly affects the positions of absorption bands (ABs) of vibrations of Ssbnd O bonds and demonstrates that information on the exact structure of ion clusters is needed for reliable and unambiguous assignment of the ABs in experimental IR spectra of real sulfonate ion containing systems to particular vibrational modes. Various ways of metal ion coordination with sulfonate ion, as well as their reflection in IR spectra of model compounds, are considered and discussed. Using TAC-K as an example, the effect of an intramolecular hydrogen bond on the vibrational modes of sulfonate group and hydroxy group is considered. The effect of ion aggregation on the shape of the IR spectrum of TAC-K is analyzed for an energetically favorable dimer of this salt as an example. Based on a combination of calculated, literature and reference data, a number of ABs in the IR spectra of TAC-K have been tentatively assigned. In particular, the bands in the region of 3230-3180 cm-1 have been assigned to ν(Osbnd H); those at 1240-1160 cm-1, to νas(SO3-); the AB at 1080 cm-1, to νs(SO3-); that at 616 cm-1, to δ(oop)s(SO3-); and that at 570 cm-1, to δ(ip)as(SO3-).

  15. The Spitzer IRS infrared spectrum and abundances of the planetary nebula IC 2448

    NARCIS (Netherlands)

    Guiles, S.; Bernard-Salas, J.; Pottasch, S. R.; Roellig, T. L.


    We present the mid-infrared spectrum of the planetary nebula IC 2448. In order to determine the chemical composition of the nebula, we use the infrared line fluxes from the Spitzer spectrum along with optical line fluxes from the literature and ultraviolet line fluxes from archival IUE spectra. We


    National Aeronautics and Space Administration — On MARCH 6, 1986, AT 7:20:06 UT, the Vega spacecraft passed the nucleus of comet Halley at a distance of 8,890 km with a relative velocity of 78 km/s. The magnetic...

  17. Experimental Raman and IR spectral and theoretical studies of vibrational spectrum and molecular structure of Pantothenic acid (vitamin B5) (United States)

    Srivastava, Mayuri; Singh, N. P.; Yadav, R. A.


    Vibrational spectrum of Pantothenic acid has been investigated using experimental IR and Raman spectroscopies and density functional theory methods available with the Gaussian 09 software. Vibrational assignments of the observed IR and Raman bands have been proposed in light of the results obtained from computations. In order to assign the observed IR and Raman frequencies the potential energy distributions (PEDs) have also been computed using GAR2PED software. Optimized geometrical parameters suggest that the overall symmetry of the molecule is C1. The molecule is found to possess eight conformations. Conformational analysis was carried out to obtain the most stable configuration of the molecule. In the present paper the vibrational features of the lowest energy conformer C-I have been studied. The two methyl groups have slightly distorted symmetries from C3V. The acidic Osbnd H bond is found to be the smallest one. To investigate molecular stability and bond strength we have used natural bond orbital analysis (NBO). Charge transfer occurs in the molecule have been shown by the calculated highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) energies. The mapping of electron density iso-surface with electrostatic potential (ESP), has been carried out to get the information about the size, shape, charge density distribution and site of chemical reactivity of the molecule.

  18. Near-IR Transmission Spectrum of HAT-P-32b using HST/WFC3 (United States)

    Damiano, M.; Morello, G.; Tsiaras, A.; Zingales, T.; Tinetti, G.


    We report here the analysis of the near-infrared transit spectrum of the hot Jupiter HAT-P-32b, which was recorded with the Wide Field Camera 3 (WFC3) on board the Hubble Space Telescope. HAT-P-32b is one of the most inflated exoplanets discovered, making it an excellent candidate for transit spectroscopic measurements. To obtain the transit spectrum, we have adopted different analysis methods, both parametric and non-parametric (Independent Component Analysis, ICA), and compared the results. The final spectra are all consistent within 0.5σ. The uncertainties obtained with ICA are larger than those obtained with the parametric method by a factor of ˜1.6-1.8. This difference is the trade-off for higher objectivity due to the lack of any assumption about the instrument systematics compared to the parametric approach. The ICA error bars are therefore worst-case estimates. To interpret the spectrum of HAT-P-32b we used { T }-REx, our fully Bayesian spectral retrieval code. As for other hot Jupiters, the results are consistent with the presence of water vapor ({{log}{{H}}}2{{O}}=-{3.45}-1.65+1.83), clouds (top pressure between 5.16 and 1.73 bar). Spectroscopic data over a broader wavelength range are needed to de-correlate the mixing ratio of water vapor from clouds and identify other possible molecular species in the atmosphere of HAT-P-32b.


    National Aeronautics and Space Administration — This data set contains the polarimetric results reported to the International Halley Watch (IHW) Photometry and Polarimetry Network (PPN) by the various...

  20. Quantitative IR Spectrum and Vibrational Assignments for Glycolaldehyde Vapor: Glycolaldehyde Measurements in Biomass Burning Plumes

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Timothy J.; Sams, Robert L.; Profeta, Luisa T.; Akagi, Sheryl; Burling, Ian R.; Yokelson, Robert J.; Williams, Stephen D.


    Glycolaldehyde (GA, 2-hydroxyethanal, C2H4O2) is a semi-volatile molecule of atmospheric importance, recently proposed as a precursor in the formation of aqueous-phase secondary organic aerosol (SOA). There are few methods to measure glycolaldehyde vapor, but infrared spectroscopy has been used successfully. Using vetted protocols we have completed the first assignment of all fundamental vibrational modes and derived quantitative IR absorption band strengths using both neat and pressure-broadened GA vapor. Even though GA is problematic due to its propensity to both dimerize and condense, our intensities agree well with the few previously published values. Using the reference ν10 band Q-branch at 860.51 cm-1, we have also determined GA mixing ratios in biomass burning plumes generated by field and laboratory burns of fuels from the southeastern and southwestern United States, including the first field measurements of glycolaldehyde in smoke. The GA emission factors were anti-correlated with modified combustion efficiency confirming release of GA from smoldering combustion. The GA emission factors (g of GA emitted per kg dry biomass burned on a dry mass basis) had a low dependence on fuel type consistent with the production mechanism being pyrolysis of cellulose. GA was emitted at 0.23 ± 0.13% of CO from field fires and we calculate that it accounts for ~18% of the aqueous-phase SOA precursors that we were able to measure.

  1. CF3CH(ONO)CF3: Synthesis, IR spectrum, and use as OH radical source for kinetic and mechanistic studies

    DEFF Research Database (Denmark)

    Andersen, Mads Peter Sulbæk; Hurley, MD; Ball, JC


    The synthesis, IR spectrum, and first-principles characterization of CF3CH(ONO)CF3 as well as its use as an OH radical source in kinetic and mechanistic studies are reported. CF3CH(ONO)CF3 exists in two conformers corresponding to rotation about the RCO-NO bond. The more prevalent trans conformer...

  2. Review of results on Halley's comet (United States)

    Rahe, Jurgen


    Since its recovery in 1982, Comet Halley has been the focus of an unparalleled global scientific effort of exploration. Remote and in situ measurements were conducted from the ground, from earth orbit, from Venus orbit, from interplanetary space, and from the comet itself. Many discoveries, such as the presence of an unexpectedly large and dark nucleus or the abundance of organic material, have led to major changes in the ideas about the general nature of comets. In this report, results of various studies are summarized.

  3. IR spectrum of the H(5)O(2)(+) cation in the context of proton disolvates L-H(+)-L. (United States)

    Stoyanov, Evgenii S; Reed, Christopher A


    The H(5)O(2)(+) ion has been studied in chlorocarbon, benzene, and weakly coordinating anion environments to bridge the gap between the gas-phase and traditional condensed-phase investigations. Symmetrical cations of the type [H(5)O(2)(+) x 4Solv] are formed via H-bonding with the terminal O-H groups. In the infrared spectrum, the nu(s)OH and nu(as)OH vibrations behave in a manner similar to those of common water molecules: the stronger is the H-bonding interaction with the surroundings, the lower is the frequency shift. A consistent pattern of IR bands from the central O-H(+)-O group is identified, regardless of the strength of the interaction of H(5)O(2)(+) with its environment. Three intense bands develop: a (860-995 cm-1), b (1045-1101 cm(-1)), and c (1672-1700 cm(-1)), as well as two weak bands, d ( approximately 1300 cm(-1)) and e ( approximately 1400-1500 cm(-1)). These fingerprint bands are highly characteristic for vibrations of O-H-O group irrespective of formal charge. They are seen in symmetrical proton disolvates of the type L-H(+)-L, where L is an O-atom donor (alcohol, ether, ketone, phosphate, etc.), and in [A-H-A](-) acid salts (A(-) = oxyanion). The commonality is equivalency of the two O-atoms, a short O...O distance (ca. 2.40 Angstrom), and a flat-bottomed potential well for the bridging proton, that is, a short, strong, low-barrier H-bond. Assignments for bands a-e are suggested in an attempt to resolve inconsistencies between experimental and calculated data.

  4. Mineralogy and Thermal Properties of V-Type Asteroid 956 Elisa: Evidence for Diogenitic Material from the Spitzer IRS (5-35 Micrometers) Spectrum (United States)

    Lim, Lucy F.; Emery, Joshua P.; Moskovitz, Nicholas A.


    We present the thermal infrared (5-35 micrometer) spectrum of 956 Elisa as measured by the Spitzer Infrared Spectrograph ("IRS"; Houck,1.R. et .11. [20041. Astrophys, 1. SuppL 154, 18-24) together with new ground-based lightcurve data and near-IR spectra. From the visible lightcurve photometry, we determine a rotation period of 16.494 +/- 0.001 h, identify the rotational phase of the Spitzer observations, and estimate the visible absolute magnitude (Hv) at that rotational phase to be 12.58 +/- 0.04. From radiometric analysis of the thermal flux spectrum, we find that at the time of observation 956 Elisa had a projected radius of 5.3 +/- 0.4 km with a visible albedo pv = 0.142+/- 0.022, significantly lower than that of the prototype V-type asteroid, 4 Vesta. (This corresponds to a radius of 5.2 +/- 0.4 km at lightcurve mean.) Analysis with the standard thermal model (STM) results in a sub-solar temperature of 292.3 +/- 2.8 K and beaming parameter eta = 1.16 +/- 0.05. Thermophysical modeling places a lower limit of 20 J m(exp -2)K(exp -1)s(exp -1/2) on the thermal inertia of the asteroid's surface layer (if the surface is very smooth) but more likely values fall between 30 and 150 J m(exp -2)K(exp -1)s(exp -1/2) depending on the sense of rotation. The emissivity spectrum, calculated by dividing the measured thermal flux spectrum by the modeled thermal continuum, exhibits mineralogically interpretable spectral features within the 9-12 micrometer reststrahlen band, the 15-16.5 micrometer Si-O-Si stretching region, and the 16-25 micrometer reststrahlen region that are consistent with pyroxene of diogenitic composition: extant diogenitic pyroxenes fall within the narrow compositional range W0(sub 2+/-1)En(sub 74+/-2)Fs(sub 24+/-1). Spectral deconvolution of the 9-12 micrometer reststrahlen features indicates that up to approximately 20% olivine may also be present, suggesting an olivine-diogenite-like mineralogy. The mid-IR spectrum is inconsistent with non

  5. Colour, albedo and nucleus size of Halley's comet (United States)

    Cruikshank, D. P.; Tholen, D. J.; Hartmann, W. K.


    Photometry of Halley's comet in the B, J, V, and K broadband filters during a time when the coma was very weak and presumed to contribute negligibly to the broadband photometry is reported. The V-J and J-K colors suggest that the color of the nucleus of Halley's comet is similar to that of the D-type asteroids, which in turn suggests that the surface of the nucleus has an albedo less than 0.1.

  6. Disentangling the Complex Vibrational Spectrum of the Protonated Water Trimer, H(+)(H2O)3, with Two-Color IR-IR Photodissociation of the Bare Ion and Anharmonic VSCF/VCI Theory. (United States)

    Duong, Chinh H; Gorlova, Olga; Yang, Nan; Kelleher, Patrick J; Johnson, Mark A; McCoy, Anne B; Yu, Qi; Bowman, Joel M


    Vibrational spectroscopy of the protonated water trimer provides a stringent constraint on the details of the potential energy surface (PES) and vibrational dynamics governing excess proton motion far from equilibrium. Here we report the linear spectrum of the cold, bare H(+)(H2O)3 ion using a two-color, IR-IR photofragmentation technique and follow the evolution of the bands with increasing ion trap temperature. The key low-energy features are insensitive to both D2 tagging and internal energy. The D2-tagged D(+)(D2O)3 spectrum is reported for the first time, and the isotope dependence of the band pattern is surprisingly complex. These spectra are reproduced by large-scale vibrational configuration interaction calculations based on a new full-dimensional PES, which treat the anharmonic effects arising from large amplitude motion. The results indicate such extensive mode mixing in both isotopologues that one should be cautious about assigning even the strongest features to particular motions, especially for the absorptions that occur close to the intramolecular bending mode of the water molecule.


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — This data set presents images of the nucleus of comet 1P/Halley obtained by the various contributing observers of the International Halley Watch (IHW) Near-Nucleus...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...


    National Aeronautics and Space Administration — NASA's International Halley Watch (IHW) has created a Comet Halley Archive. The collection of data spans the full wavelength range as submitted by scientists to the...

  19. Spectrum

    DEFF Research Database (Denmark)

    Høgfeldt Hansen, Leif


    The publication functions as a proces description of the development and construction of an urban furniture SPECTRUM in the city of Gwangju, Republic of Korea. It is used as the cataloque for the exhibition of Spectrum.......The publication functions as a proces description of the development and construction of an urban furniture SPECTRUM in the city of Gwangju, Republic of Korea. It is used as the cataloque for the exhibition of Spectrum....

  20. Measurement of the Shape of the Optical-IR Spectrum of Prompt Emission from Gamma-Ray Bursts (United States)

    Grossan, Bruce; Kistaubayev, M.; Smoot, G.; Scherr, L.


    While the afterglow phase of gamma-ray bursts (GRBs) has been extensively measured, detections of prompt emission (i.e. during bright X-gamma emission) are more limited. Some prompt optical measurements are regularly made, but these are typically in a single wide band, with limited time resolution, and no measurement of spectral shape. Some models predict a synchrotron self-absorption spectral break somewhere in the IR-optical region. Measurement of the absorption frequency would give extensive information on each burst, including the electron Lorentz factor, the radius of emission, and more (Shen & Zhang 2008). Thus far the best prompt observations have been explained invoking a variety of models, but often with a non-unique interpretation. To understand this apparently heterogeneous behavior, and to reduce the number of possible models, it is critical to add data on the optical - IR spectral shape.Long GRB prompt X-gamma emission typically lasts ~40-80 s. The Swift BAT instrument rapidly measures GRB positions to within a few arc minutes and communicates them via the internet within a few seconds. We have measured the time for a fast-moving D=700 mm telescope to point and settle to be less than 9 s anywhere on the observable sky. Therefore, the majority of prompt optical-IR emission can be measured responding to BAT positions with this telescope. In this presentation, we describe our observing and science programs, and give our design for the Burst Simultaneous Three-channel Instrument (BSTI), which uses dichroics to send eparate bands to 3 cameras. Two EMCCD cameras, give high-time resolution in B and V; a third camera with a HgCdTe sensor covers H band, allowing us to study extinguished bursts. For a total exposure time of 10 s, we find a 5 sigma sensitivity of 21.3 and 20.3 mag in B and R for 1" seeing and Kitt Peak sky brightness, much fainter than typical previous prompt detections. We estimate 5 sigma H-band sensitivity for an IR optimized telescope to be

  1. Comet Halley Returns. A Teacher's Guide, 1985-1986. (United States)

    Chapman, Robert D.; Bondurant, R. Lynn, Jr.

    This booklet was designed as an aid for elementary and secondary school teachers. It is divided into two distinct parts. Part I is a brief tutorial which introduces some of the most important concepts about comets. Areas addressed include: the historical importance of Comet Halley; how comets are found and names; cometary orbits; what Comet Halley…

  2. Relationship between wave energy and free energy from pickup ions in the Comet Halley environment (United States)

    Huddleston, D. E.; Johnstone, A. D.


    The free energy available from the implanted heavy ion population at Comet Halley is calculated by assuming that the initial unstable velocity space ring distribution of the ions evolves toward a bispherical shell. Ultimately this free energy adds to the turbulence in the solar wind. Upstream and downstream free energies are obtained separately for the conditions observed along the Giotto spacecraft trajectory. The results indicate that the waves are mostly upstream propagating in the solar wind frame. The total free energy density always exceeds the measured wave energy density because, as expected in the nonlinear process of ion scattering, the available energy is not all immediately released. An estimate of the amount which has been released can be obtained from the measured oxygen ion distributions and again it exceeds that observed. The theoretical analysis is extended to calculate the k spectrum of the cometary-ion-generated turbulence.


    Energy Technology Data Exchange (ETDEWEB)

    Rubin, M.; Altwegg, K. [Physikalisches Institut, University of Bern, Sidlerstrasse 5, CH-3012 Bern (Switzerland); Dishoeck, E. F. van [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands); Schwehm, G. [ESA (retired) Science Operations Department, ESTEC, Keplerlaan 1, 2201 AZ Noordwijk (Netherlands)


    Recently, the ROSINA mass spectrometer suite on board the European Space Agency's Rosetta spacecraft discovered an abundant amount of molecular oxygen, O{sub 2}, in the coma of Jupiter family comet 67P/Churyumov–Gerasimenko of O{sub 2}/H{sub 2}O = 3.80 ± 0.85%. It could be shown that O{sub 2} is indeed a parent species and that the derived abundances point to a primordial origin. Crucial questions are whether the O{sub 2} abundance is peculiar to comet 67P/Churyumov–Gerasimenko or Jupiter family comets in general, and also whether Oort cloud comets such as comet 1P/Halley contain similar amounts of molecular oxygen. We investigated mass spectra obtained by the Neutral Mass Spectrometer instrument during the flyby by the European Space Agency's Giotto probe of comet 1P/Halley. Our investigation indicates that a production rate of O{sub 2} of 3.7 ± 1.7% with respect to water is indeed compatible with the obtained Halley data and therefore that O{sub 2} might be a rather common and abundant parent species.

  4. New Image of Comet Halley in the Cold (United States)


    VLT Observes Famous Traveller at Record Distance Summary Seventeen years after the last passage of Comet Halley , the ESO Very Large Telescope at Paranal (Chile) has captured a unique image of this famous object as it cruises through the outer solar system. It is completely inactive in this cold environment. No other comet has ever been observed this far - 4200 million km from the Sun - or that faint - nearly 1000 million times fainter than what can be perceived with the unaided eye. This observation is a byproduct of a dedicated search [1] for small Trans-Neptunian Objects, a population of icy bodies of which more than 600 have been found during the past decade. PR Photo 27a/03 : VLT image (cleaned) of Comet Halley PR Photo 27b/03 : Sky field in which Comet Halley was observed PR Photo 27c/03 : Combined VLT image with star trails and Comet Halley The Halley image ESO PR Photo 27a/03 ESO PR Photo 27a/03 [Preview - JPEG: 546 x 400 pix - 207k] [Normal - JPEG: 1092 x 800 pix - 614k] [FullRes - JPEG: 1502 x 1100 pix - 1.1M] Caption : PR Photo 27a/03 shows the faint, star-like image of Comet Halley (centre), observed with the ESO Very Large Telescope (VLT) at the Paranal Observatory on March 6-8, 2003. 81 individual exposures from three of the four 8.2-m VLT telescopes with a total exposure time of about 9 hours were combined to show the magnitude 28.2 object. At this time, Comet Halley was about 4200 million km from the Sun (28.06 AU) and 4080 million km (27.26 AU) from the Earth. All images of stars and galaxies in the field were removed during the extensive image processing needed to produce this unique image. Due to the remaining, unavoidable "background noise", it is best to view the comet image from some distance. The field measures 60 x 40 arcsec 2 ; North is up and East is left. Remember Comet Halley - the famous "haired star" that has been observed with great regularity - about once every 76 years - during more than two millennia? Which was visited by an

  5. Navigation and guidance of Japanese deepspace probes encountering Halley's comet (United States)

    Nishimura, T.; Matsuo, H.; Takano, T.; Kawaguchi, J.

    The techniques used by ISAS in the guidance of the Sakigake and Suisei probes, which encountered Comet Halley in March 1986, are reviewed. Consideration is given to the guidance of the last rocket stage in the direct ascent phase, midcourse maneuvers, tracking systems and communication links, the tracking strategy, trajectory-generation and orbit-determination software, and orbit-determination accuracy. Diagrams, drawings, graphs, photographs, and tables of numerical data are provided, and the ISAS positions of both probes during the first 10 days after launch are shown to be within 100 km in distance and 1 m/sec in velocity of NASA coordinate estimates.

  6. Measuring the universe cosmic dimensions from Aristarchus to Halley

    CERN Document Server

    Van Helden, Albert


    Measuring the Universe is the first history of the evolution of cosmic dimensions, from the work of Eratosthenes and Aristarchus in the third century B.C. to the efforts of Edmond Halley (1656-1742). ""Van Helden's authoritative treatment is concise and informative; he refers to numerous sources of information, draws on the discoveries of modern scholarship, and presents the first book-length treatment of this exceedingly important branch of science.""-Edward Harrison, American Journal of Physics ""Van Helden writes well, with a flair for clear explanation. I

  7. IR intensity

    DEFF Research Database (Denmark)

    Spanget-Larsen, Jens


    Definitions, formulas, and code for producing epsilon values (molar absorption coefficients) and IR spectral curve from 'Gaussian' FREQ output.......Definitions, formulas, and code for producing epsilon values (molar absorption coefficients) and IR spectral curve from 'Gaussian' FREQ output....

  8. The Optical Stark Spectrum of the A3Φ4-X3Φ4 Band System of Iridium Monofluoride, IrF (United States)

    Zhuang, Xiujuan; Steimle, Timothy C.; Linton, Colan


    Recently the New Brunswick group reported on the field-free detection and analysis of the A3Φ4-X3Φ4 band system of IrF. Here we report on the analysis Q(4)(15922 cm-1) branch feature of the (1,0) band of the 191IrF isotopologue of that system recorded at field strengths of up to 3000 V/cm. The spectra are surprisingly complex at the achieved resolution of 40 MHz due to the presence of both the 191Ir(I=3/2) and 19F(I=1/2) magnetic hyperfine splitting. The determined permanent electric dipole moment, μel, for the X3Φ4 state is compared with that recently determined for the X3Φ4 state of isovalent CoF. The trend in μel amongst the ground states of IrF, IrC and IrN will be discussed. Finally, a simple molecular orbital correlation diagram will be used to rationalize the change in μel upon excitation from the X3Φ4 to A3Φ4 state. A.G. Adam; A.D. Granger; L.E. Downie; D.W. Tokaryk and C. Linton Can.J. Phys. 87 557, 2009. H. Wang; X. Zhaung; and T.C. Steimle J. Chem. Phys. 131 114315, 2009. A.J.Marr; M.E. Flores; and T.C. Steimle J. Chem. Phys. 104 8183, 1996.

  9. Halley comet rendezvous with a SEPS vehicle. [Solar Electric Propulsion System (United States)

    Burrows, R. R.


    An analysis of the performance of a Solar Electric Propulsion System (SEPS) vehicle rendezvousing with Halley's comet just prior to its Frebruary 1986 perihelion is described. A calculus of variations mathematical formulation is used to maximize Halley arrival mass while giving effect to the influence of solar array size, launch date, arrival date, and insertion hyperbolic excess velocity. Numerical sensitivity relief, thrust system modeling, trajectory characteristics and ion engine operating conditions are discussed and illustrated. Results indicate a rendezvous is feasible with a minimal advance in solar cell and ion engine technology.

  10. Synthesis, experimental and theoretical studies on its crystal structure and FT-IR spectrum of new thiosemicarbazone compound E-2-(4-isopropylbenzylidene)thiosemicarbazone (United States)

    Khalaji, Aliakbar Dehno; Mehrani, Sepideh; Eigner, Vaclav; Dusek, Michal


    The title compound E-2-(4-isopropylbenzylidene)thiosemicarbazone (1) derived from the reaction of 4-isopropylbenzaldehyde and thiosemicarbazide in ethanol solution has been synthesized and characterized by elemental analyses, FT-IR and 1H NMR spectroscopy and single-crystal X-ray diffraction. Its optimized geometry together with the theoretical assignment of the vibrational frequencies of the title compound has been computed by using density functional theory (DFT) method. In the gas phase the four conformers of the title compound were found and it was found that the conformer Sn1 is the most stable one. The title compound crystallizes in the monoclinic space group P21/c with unit cell parameters: a = 14.4054(4), b = 5.6832(10), c = 14.4337(3) Å, β = 93.306(2)°, V = 1179.70(5) Å3 and Z = 4.

  11. Early Star Catalogues of the Southern Sky: De Houtman, Kepler (Second and Third Classes), and Halley

    NARCIS (Netherlands)

    Verbunt, F.|info:eu-repo/dai/nl/068970374; van Gent, R. H.|info:eu-repo/dai/nl/074296043

    De Houtman in 1603, Kepler in 1627 and Halley in 1679 published the earliest modern catalogues of the southern sky. We provide machine-readable versions of these catalogues, make some comparisons between them, and briefly discuss their accuracy on the basis of comparison with data from the modern

  12. The origin of chaos in the orbit of comet 1P/Halley (United States)

    Boekholt, T. C. N.; Pelupessy, F. I.; Heggie, D. C.; Portegies Zwart, S. F.


    According to Muñoz-Gutiérrez et al. the orbit of comet 1P/Halley is chaotic with a surprisingly small Lyapunov time-scale of order its orbital period. In this work we analyse the origin of chaos in Halley's orbit and the growth of perturbations, in order to get a better understanding of this unusually short time-scale. We perform N-body simulations to model Halley's orbit in the Solar system and measure the separation between neighbouring trajectories. To be able to interpret the numerical results, we use a semi-analytical map to demonstrate different growth modes, I.e. linear, oscillatory or exponential, and transitions between these modes. We find the Lyapunov time-scale of Halley's orbit to be of order 300 yr, which is significantly longer than previous estimates in the literature. This discrepancy could be due to the different methods used to measure the Lyapunov time-scale. A surprising result is that next to Jupiter, also encounters with Venus contribute to the exponential growth in the next 3000 yr. Finally, we note an interesting application of the sub-linear, oscillatory growth mode to an ensemble of bodies moving through the Solar system. Whereas in the absence of encounters with a third body the ensemble spreads out linearly in time, the accumulation of weak encounters can increase the lifetime of such systems due to the oscillatory behaviour.

  13. La teoria di Halley sul magnetismo terrestre e sulle aurore polari. (United States)

    D'Amico, S.


    This paper contains a brief description of some theories developed by Edmund Halley during the last years of the 17th century and the beginning of the 18th. This theories tried to explain the origin of terrestrial magnetism and its changes during the time, and gives a description of how magnetic force by the Earth could influence polar aurorae.

  14. The kinetics and dynamics of the coma of Halley's comet (United States)

    Combi, Michael R.


    This grant to the University of Michigan supported the efforts of Michael R. Combi to serve as a co-investigator in collaboration with a larger effort by the principal investigator, William Smyth of Atmospheric and Environmental Research, Inc. The overall objective of this project was to analyze in a self-consistent manner unique optical O((sup 1)D) and NH2 ultra-high resolution line profile data of excellent quality and other supporting lower-resolution spectral data for the coma of comet P/Halley by using highly developed and physically-based cometary coma models in order to determine and explain in terms of physical processes the actual dynamics and photochemical kinetics that occur in the coma. The justification for this work is that it provides a valuable and underlying physical base from which to interpret significantly different types of coma observations in a self-consistent manner and hence bring into agreement (or avoid) apparent inconsistencies that arise from non-physically based interpretations. The level of effort for the Michigan component amounted to less than three person-months over a planned period of three years. The period had been extended at no extra cost to four years because the Michigan grant and the AER contract did not have coincident time periods. An effort of somewhat larger scope was undertaken by the PI. The importance of the O((sup 1)D) profiles is that they provide a direct trace of the water distribution in comets. The line profile shape is produced by the convolution of the outflow velocity and thermal dispersion of the parent water molecules with the photokinetic ejection of the oxygen atoms upon photodissociation of the parent water molecules. Our understanding of the NH2 and its precursor ammonia are important for comet-to-comet composition variations as they relate to the cosmo-chemistry of the early solar nebula. Modeling of the distribution of NH2 is necessary in order to infer the ammonia production rates from NH2

  15. A family of Newton-Halley type methods to find simple roots of nonlinear equations and their dynamics

    Directory of Open Access Journals (Sweden)

    Carlos E. Cadenas R.


    Full Text Available In this work a new family of Newton-Halley type methods for solving nonlinear equations is presented. the dynamics of the Newton-Halley family is analyzed for the class of quadratic polynomials and the convergence is established. We find the fixed and critical points. The stable and unstable behaviors are studied. The parameter space associated with the family is studied and finally, some dynamical planes that show different aspects of the dynamics of this family are presented.

  16. Organic Chemistry in Interstellar Ices: Connection to the Comet Halley Results (United States)

    Schutte, W. A.; Agarwal, V. K.; deGroot, M. S.; Greenberg, J. M.; McCain, P.; Ferris, J. P.; Briggs, R.


    Mass spectroscopic measurements on the gas and dust in the coma of Comet Halley revealed the presence of considerable amounts of organic species. Greenberg (1973) proposed that prior to the formation of the comet UV processing of the ice mantles on grains in dense clouds could lead to the formation of complex organic molecules. Theoretical predictions of the internal UV field in dense clouds as well as the discovery in interstellar ices of species like OCS and OCN- which have been formed in simulation experiments by photoprocessing of interstellar ice analogues point to the importance of such processing. We undertook a laboratory simulation study of the formation of organic molecules in interstellar ices and their possible relevance to the Comet Halley results.

  17. La comète de Halley une révolution scientifique

    CERN Document Server

    Maffei, Paolo


    Mars-avril 1986: la comète de Halley est de retour, passant au plus près de la Terre.Rarement un événement à l'origine strictement astronomique aura à ce point été un événement scientifique. Pas moins de cinq sondes spatiales, en effet, ont été lancées pour rencontrer la comète et effectuer en mars 1986 la première exploration de son atmosphère. Rien, pourtant, ne semblait à l'origine militer pour un tel déploiement de moyens scientifiques: la comète ne dépasse pas en éclat les comètes non périodiques les plus brillantes; sa période de révolution _ 76 ans _ est longue; sa trajectoire est telle que le temps d'observation, lors du survol par les sondes, ne dure que quelques heures.Mais la comète de Halley _ du nom de l'astronome anglais Edmund Halley qui, appliquant les lois de la gravitation de Newton, en détermina les éléments orbitaux et prévit la réapparition de 1758 _ est la seule comète brillante et jeune dont la trajectoire soit parfaitement connue à l'avance. Grâce à s...

  18. Comet Halley passes the halfway mark. Very distant image obtained with the ESO NTT. (United States)


    Eight years after the passage of Comet Halley in early 1986, astronomers at the European Southern Observatory have succeeded in obtaining an image [1] of this famous object at a distance of no less than 2,820 million km from the Sun. The comet is now about as far away as giant planet Uranus. It recently passed the halfway mark towards the most distant point of its very elongated 76-year orbit. The image shows the 6 x 15 km avocado-shaped nucleus as an extremely faint point of light without any surrounding dust cloud. It appears that the surface is now completely frozen and the comet has ceased to emit dust and gas. This observation was made with the ESO 3.58 metre New Technology Telescope (NTT). It is by far the faintest and most distant image ever recorded of this comet. A DIFFICULT OBSERVATION The new Halley image was obtained in the course of an observational programme by a small group of astronomers [2], aimed at the investigation of distant solar system objects. The observation was difficult to perform and is close to the limit of what is possible, even with the NTT, one of the technologically most advanced astronomical telescopes. In fact, this observation may be compared to viewing a black golfball, used during a late evening game, from a distance of 12,000 km. At Halley's present, very large distance from the Sun, the intensity of the solar light is over 350 times fainter than here on Earth. The surface of the cometary nucleus is very dark; it reflects only 4 % of the infalling sunlight. The amount of light received from Halley is therefore extremely small: the recorded star-like image of the nucleus is about 160 million times fainter than the faintest star that can be seen with the unaided eye. A long exposure was needed to catch enough light to show the object; even with the very sensitive SuSI CCD camera at the NTT, the shutter had to be kept open for a total of 3 hours 45 minutes. During this time, of the order of 9000 photons from Comet Halley were

  19. Scientists of the Gwansang-gam. 1: Observers of Comet 1P/Halley in 1759 (United States)

    Nha, Il-Seong; Oh, Wan-Tak; Oh, Yong-Hae; Nha, Sarah


    A project on researching the scientists of the Joseon Dynasty (Korea) has been carried out by the authors in the last decade by focusing mainly on the officials of the Gwansang-gam, the Bureau of Astronomy and Meteorology. This paper presents research that relies on the 1759 Seongbyeon Deungrok (Compilation of Daily Observational Records of Celestial Events) of the Gwansang-gam, and reviews the records of observations and observers of Comet IP/Halley during its 1759 apparition. This record includes a series of archival sketches of the comet. In order to describe this work, the Seongbyeon Deungrok is first introduced, and then the observations of Comet 1P/Halley in the 1759 Deungrok are presented. The observers on duty each night during this series of observations from 1 to 14 April 1759 are also introduced, and there is a brief biographical investigation of five hereditary astronomers who made important contributions at the Gwansang-gam during the mid-eighteenth century, both as observers and calendrical researchers.

  20. FT-IR and DFT study of lemon peel (United States)

    Berezin, K. V.; Likhter, A. M.; Shagautdinova, I. T.; Chernavina, M. L.; Novoselova, A. V.


    Experimental FT-IR spectra of lemon peel are registered in the 650 - 3800 cm-1 range. The influence of peel artificial and natural dehydration on its vibrational spectrum is studied. The colored outer surface of lemon peel is proved not to have a significant impact on FT-IR spectrum. It is determined that only dehydration processes affect the FT-IR vibrational spectrum of the peel when a lemon is stored for 28 days under natural laboratory conditions. Polymer molecule models for dietary fibers, such as cellulose, hemicellulose, pectin, lignin, as well as hesperidin - flavonoid glycoside, and free moisture cluster are developed within the framework of DFT/B3LYP/6-31G(d) theoretical method. By implementing supramolecular approach, modeling of the vibrational FT-IR spectrum of lemon peel is carried out and its detailed theoretical interpretation is presented.

  1. Applicability of NASA Polar Technologies to British Antarctic Survey Halley VI Research Station (United States)

    Flynn, Michael


    From 1993 through 1997 NASA and the National Science Foundation (NSF), developed a variety of environmental infrastructure technologies for use at the Amundsen-Scott South Pole Station. The objective of this program was to reduce the cost of operating the South Pole Station, reduce the environmental impact of the Station, and to increase the quality of life for Station inhabitants. The result of this program was the development of a set of sustainability technologies designed specifically for Polar applications. In the intervening eight years many of the technologies developed through this program have been commercialized and tested in extreme environments and are now available for use throughout Antarctica and circumpolar north. The objective of this document is to provide information covering technologies that might also be applicable to the British Antarctic Survey s (BAS) proposed new Halley VI Research Station. All technologies described are commercially available.

  2. Produccion Gaseosa del Cometa Halley: Erupciones Y Fotodisociacion del Radical OH (United States)

    Silva, A. M.; Mirabel, I. F.


    RESUMEN:En este trabajo informamos la detecci6n de 20 erupciones en la li'nea de =18cm (1667MHz) del radical OH en el Cometa Halley.Las observaciones incluyen todos los monitoreos existentes y se extienden desde 120 dias antes del perihelio hasta 90 dias despues.Se detectan bruscos crecimientos en el flujo medido,hasta un factor 1O,seguidos por decaimientos lentos asociados con la fotodisociaci6n del OH. Se obtuvieron valores para el tiempo de vida fotoquimico del OH y del H2O basandose en el modelo desarrollado previamente por Silva(1988). Esos tiempos de vida estan de acuerdo con predicciones teoricas y con las observaciones en el Ultravioleta, y los resultados, los que son fuertemente dependientes de la velocidad heliocentrica del Coineta (variando hasta un factor 6), han sido calculados para varios rangos de velocidad entre +28 y -28 km/seg. Key wo'L :

  3. Comet Halleys Legacy: SUNA, Astronomy from Universidad Central de Venezuela (U.C.V.) (United States)

    Romero, Gabriel; Fernandez, Nelson


    The Sociedad Universitaria de Astronomia (SUNA) is a group of astronomy amateurs which works inside the Universidad Central de Venezuela (Venezuelas Central University)s campus. The initiative is originated during the path through the perihelion of Comet Halley in 1986, and since then their goals are promotion of astronomical information to all the university community. Observational works are also carried out, such as: registration and investigation of astronomical events, with the purpose to offer the opportunity to all public, mostly students o the University, to enjoy a spectacle, and at the same time to motivate the students to continue professional studies of astronomy. Being this last goal one of the most gratifying in the society.

  4. Eventos de Desconexao na Cauda de Plasma do Cometa P/Halley (United States)

    Voelzke, M. R.; Fahr, H. J.


    Observacoes cometárias e de vento solar sao comparadas com o propósito de determinar-se as condicoes do vento solar associadas aos eventos de desconexao (DEs) observados em caudas de plasma cometárias. Os dados cometários sao provenientes do The International Halley Watch Atlas of Large-Scale Phenomena. A análise visual sistemática das imagens do atlas revelou, entre outras estruturas morfológicas, 47 DEs ao longo da cauda de plasma do P/Halley. Estes 47 DEs registrados em 47 imagens distintas permitiram a descoberta de 19 origens de DEs, ou seja, o tempo em que as desconexoes iniciaram foi calculado. Os dados do vento solar sao provenientes de medidas feitas in situ pela sonda espacial IMP-8, as quais foram usadas para elaborar a variacao da velocidade do vento solar, densidade e pressao dinâmica durante o intervalo analisado. O presente trabalho compara as atuais teorias conflitantes, baseadas nos mecanismos de formacao, com o intuito de explicar o fenômeno cíclico dos DEs, ou seja, os efeitos de producao iônica, os efeitos de pressao e os efeitos de reconexao magnética sao analisados. Para cada uma das 19 origens de DEs comparou-se a densidade com a respectiva velocidade do vento solar com o intuito de determinar-se uma possível correlacao entre estas origens e os efeitos de pressao dinâmica. Quando da ocorrência de 6 origens de DEs o IMP-8 nao realizou medidas, nos outros 13 casos 10 origens (77%) mostraram uma anticorrelacao entre velocidade e densidade e apenas 3 (23%) revelaram uma tendência similar entre velocidade e densidade. Portanto, a análise inicial demonstra uma fraca correlacao entre as origens dos DEs e os efeitos de pressao.

  5. IOT Overview: IR Instruments (United States)

    Mason, E.

    In this instrument review chapter the calibration plans of ESO IR instruments are presented and briefly reviewed focusing, in particular, on the case of ISAAC, which has been the first IR instrument at VLT and whose calibration plan served as prototype for the coming instruments.

  6. IR Hot Wave

    Energy Technology Data Exchange (ETDEWEB)

    Graham, T. B.


    The IR Hot Wave{trademark} furnace is a breakthrough heat treatment system for manufacturing metal components. Near-infrared (IR) radiant energy combines with IR convective heating for heat treating. Heat treatment is an essential process in the manufacture of most components. The controlled heating and cooling of a metal or metal alloy alters its physical, mechanical, and sometimes chemical properties without changing the object's shape. The IR Hot Wave{trademark} furnace offers the simplest, quickest, most efficient, and cost-effective heat treatment option for metals and metal alloys. Compared with other heat treatment alternatives, the IR Hot Wave{trademark} system: (1) is 3 to 15 times faster; (2) is 2 to 3 times more energy efficient; (3) is 20% to 50% more cost-effective; (4) has a {+-}1 C thermal profile compared to a {+-}10 C thermal profile for conventional gas furnaces; and (5) has a 25% to 50% smaller footprint.

  7. The infrared spectrum of the benzene-Ar cation

    NARCIS (Netherlands)

    Satink, R. G.; Piest, H.; von Helden, G.; Meijer, G.


    The infrared (IR) absorption spectra of the jet-cooled C6H6 and C6D6 cations, complexed with Ar, are measured throughout the 450-1500 cm(-1) region via IR-laser-induced vibrational dissociation spectroscopy. The IR spectrum of the C6H6-Ar cation is dominated by a Fermi resonance between the IR

  8. Análise Temporal da Coma de CO+ no Cometa P/Halley (United States)

    Voelzke, M. R.; Schlosser, W.; Schmidt-Kaler, Th.


    Observações fotográficas e fotoelétricas da coma de gás ionizado do cometa P/Halley a nível de CO+ em 4250 angstroms fizeram parte do programa de Monitoramento do Halley desenvolvido pela Universidade de Bochum (Ruhr-Universitaet Bochum) na Alemanha, realizado de 17 de fevereiro a 17 de abril de 1986 no European Southern Observatory (ESO) em La Silla (Chile). Nesta faixa espectral é possível observar a contínua formação, bem como o movimento e expansão das estruturas de plasma. Para observar a morfologia destas estruturas foram analisadas 32 placas fotográficas de CO+ (placas de vidro) do cometa P/Halley. Tais placas possuem um campo de visão de 28,6 por 28,6 graus sendo obtidas entre 29 de março e 17 de abril de 1986 com tempos de exposição entre 20 e 120 minutos. Todas as placas foram digitadas com o auxílio de um microdensitômetro PDS 2020 GM (Photometric Data System) do Instituto Astronómico da Westfaelischen Wilhelms-Universitaet em Muenster, Alemanha (um pixel = 25 por 25 micrômetros correspondendo aproximadamente a 46,88 por 46,88 segundos de arco). Após a digitação os dados foram reduzidos à intensidades relativas, sendo que os posssíveis de calibração também foram reduzidos à intensidades absolutas, expressas em termos de densidade colunar utilizando-se dos sistemas de tratamento de imagens MIDAS (Munich Image Data Analysis System; ESO - Image Processing Group, 1988) e IHAP (Image Handling And Processing; Middleburg, 1983). Com o auxílio do método de teta mínimo de Stellingwerf (Stellingwerf, 1978) obteve-se um período de 2,22 +/- 0,09 dias a partir da análise de estruturas na coma de plasma através da subtração de imagens subsequentes. Este método foi comparado com o método de Fourier. Provavelmente exista um segundo ciclo com período aproximado de 3,6 dias. A idéia de subtrair imagens subsequentes é devido ao fato de que os efeitos de rotação são apenas 10% dos fenômenos de distribuição gasosa. Portanto as

  9. Human seasonal and circadian studies in Antarctica (Halley, 75°S). (United States)

    Arendt, Josephine; Middleton, Benita


    Living for extended periods in Antarctica exposes base personnel to extremes of daylength (photoperiod) and temperature. At the British Antarctic Survey base of Halley, 75°S, the sun does not rise for 110 d in the winter and does not set for 100 d in summer. Photoperiod is the major time cue governing the timing of seasonal events such as reproduction in many species. The neuroendocrine signal providing photoperiodic information to body physiology is the duration of melatonin secretion which reflects the length of the night: longer in the short days of winter and shorter in summer. Light of sufficient intensity and spectral composition serves to suppress production of melatonin and to set the circadian timing and the duration of the rhythm. In humans early observations suggested that bright (>2000 lux) white light was needed to suppress melatonin completely. Shortly thereafter winter depression (Seasonal Affective Disorder or SAD) was described, and its successful treatment by an artificial summer photoperiod of bright white light, sufficient to shorten melatonin production. At Halley dim artificial light intensity during winter was measured, until 2003, at a maximum of approximately 500 lux in winter. Thus a strong seasonal and circadian time cue was absent. It seemed likely that winter depression would be common in the extended period of winter darkness and could be treated with an artificial summer photoperiod. These observations, and predictions, inspired a long series of studies regarding human seasonal and circadian status, and the effects of light treatment, in a small overwintering, isolated community, living in the same conditions for many months at Halley. We found little evidence of SAD, or change in duration of melatonin production with season. However the timing of the melatonin rhythm itself, and/or that of its metabolite 6-sulphatoxymelatonin (aMT6s), was used as a primary marker of seasonal, circadian and treatment changes. A substantial phase

  10. Ion acceleration at the contact surface of Comet P/Halley (United States)

    Gurgiolo, C.; Winningham, J. D.


    Suprathermal ions form a major component of the plasma within the inner coma of Comet P/Halley. A close inspection of these ions shows them to contain at least two separate populations: one population covers the energy range below about 400 eV, and a second population exists in a narrow energy band centered between 3 and 4 keV. Similar distributions are found in two regions upstream of the contact surface. It is postulated that the suprathermal ions observed upstream of the contact surface were created at the contact surface. Sudden movements of the contact surface, in the cometary frame of reference, in response to changes in the magnetic field pressure, or cometary production rate, give rise to an induction electric field able to accelerate the local thermal cometary ions up into the tens of electron volts range. Higher energies can be attained with the reacceleration of these ions in subsequent movements of the contact surface. Besides creating the ion enhancements observed upstream of the contact surface, this acceleration mechanism wil release large amounts of suprathermal ions into the inner coma.

  11. Comet 1P/Halley multifluid MHD model for the Giotto fly-by

    Energy Technology Data Exchange (ETDEWEB)

    Rubin, M.; Altwegg, K. [Physikalisches Institut, University of Bern, Sidlerstrasse 5, CH-3012 Bern (Switzerland); Combi, M. R.; Daldorff, L. K. S.; Gombosi, T. I.; Hansen, K. C.; Shou, Y.; Tenishev, V. M.; Tóth, G.; Van der Holst, B. [Atmospheric, Oceanic and Space Sciences, University of Michigan, 2455 Hayward Street, Ann Arbor, MI 48109 (United States)


    The interaction of comets with the solar wind has been the focus of many studies including numerical modeling. We compare the results of our multifluid MHD simulation of comet 1P/Halley to data obtained during the flyby of the European Space Agency's Giotto spacecraft in 1986. The model solves the full set of MHD equations for the individual fluids representing the solar wind protons, the cometary light and heavy ions, and the electrons. The mass loading, charge-exchange, dissociative ion-electron recombination, and collisional interactions between the fluids are taken into account. The computational domain spans over several million kilometers, and the close vicinity of the comet is resolved to the details of the magnetic cavity. The model is validated by comparison to the corresponding Giotto observations obtained by the Ion Mass Spectrometer, the Neutral Mass Spectrometer, the Giotto magnetometer experiment, and the Johnstone Plasma Analyzer instrument. The model shows the formation of the bow shock, the ion pile-up, and the diamagnetic cavity and is able to reproduce the observed temperature differences between the pick-up ion populations and the solar wind protons. We give an overview of the global interaction of the comet with the solar wind and then show the effects of the Lorentz force interaction between the different plasma populations.

  12. Spitzer IRS Analysis of Neptune (United States)

    Line, Michael R.; Orton, G. S.; Fletcher, L. N.; Mahmud, A.; Moses, J. I.; Mainzer, A. K.; Yung, Y. L.


    Recent (2005) Spitzer Infrared Spectrometer (IRS) data of Neptune between 5 and 20 um contain a wealth of information about the chemical composition and temperature structure of its cold atmospheres. Emission features in its spectrum arise from many hydrocarbons, including ethane, acetylene and methane, and they appear to be superimposed on top of a collision-induced H2 continuum. As the derivation of all other parameters depends on the assumed temperature profile, special efforts were taken to ensure that the stratospheric profile between 1 bar and 0.3 mbar matched the H2 continuum and the H2 S(1) quadrupole feature at 17 um. Additionally we matched the methane v4 feature at 7.7 um in order to constrain the stratospheric temperature profile above the 0.3-mbar level as well as the methane stratospheric volume mixing ratios (VMRs). After the determination of the temperature profile and methane VMRs, the VMRs for several species were then determined through fitting their corresponding features in the spectrum, initially by scaling existing photochemical models (see Mahmud et al., this conference). These species include methylacetylene, diacetylene, benzene, acetylene, ethane, methyl radical, ethylene and carbon dioxide which are all derived from methane photochemistry. I would like to acknowledge the NASA USRP program for supporting this work.

  13. Callisto III e la Cometa di Halley: la ricerca di Johan Stein SJ tra leggenda e storia (United States)

    Sigismondi, Costantino

    The Dutch Jesuit astronomer Johan Stein published in 1909 a text about the legend on a papal bull of Pope Callixtus III against the comet of 1456. This comet happened to be the Halley's one. The original documents, either chronicles and observations, and coeval testimonies are deeply investigated by Stein and the falsity of that legend is clearly demonstrated. In the occasion of the 200 years of the restoration of the Societas Jesu made in 1814 by Pope Pius VII an Italian edition of the full text of Johan Stein is here presented.

  14. Dust-acoustic shock waves in a charge varying electronegative magnetized dusty plasma with nonthermal ions: Application to Halley Comet plasma

    Energy Technology Data Exchange (ETDEWEB)

    Tribeche, Mouloud; Bacha, Mustapha [Plasma Physics Group (PPG), Theoretical Physics Laboratory (TPL), Faculty of Physics, University of Bab-Ezzouar, USTHB, B. P. 32, El Alia, Algiers 16111 (Algeria)


    Weak dust-acoustic waves (DAWs) are addressed in a nonthermal charge varying electronegative magnetized dusty plasmas with application to the Halley Comet. A weakly nonlinear analysis is carried out to derive a Korteweg-de Vries-Burger equation. The positive ion nonthermality, the obliqueness, and magnitude of the magnetic field are found to modify the dispersive and dissipative properties of the DA shock structure. Our results may aid to explain and interpret the nonlinear oscillations that may occur in the Halley Comet Plasma.

  15. Radio-Observaciones del OH EN la Coma del Cometa Halley Desde EL Hemisferio Sur (United States)

    Silva, A. M.; Bajaja, E.; Morras, R.; Cersosimo, J. C.; Martin, M. C.; Arnal, E. M.; Poppel, W. G. L.; Colomb, F. R.; Mazzaro, J.; Olalde, J. C.; Boriakoff, V.; Mirabel, I. F.


    Se utilizó una antena de 30 metros del Instituto Argentino de Radioastronomía para observaciones diarias Cf ebrero a abril de 1986) de la transición en 1667 MHz ( λ = 18 cm) del OH en la coma del cometa Halley. De las observaciones realizadas se concluye: 1) El número promedio de moléculas de OH en la coma durante 37 días de observación fue de (8.9±3.5)x1034 moléculas, lo que implica una tasa de producción promedio de OH de 1.8x1029 moléculas seg-1 y consecuentemente una pérdida de masa promedio de 17±6 toneladas seg-1 . Este valor está de acuerdo con las mediciones realizadas por las sondas Vega y Giotto. 2) El monitoreo desde el lAR revela la existencia de variaciones bruscas en los flujos de absorción del OH. Estas variaciones son consistentes con los modelos que representan la producción gaseosa a partir de ejecciones y/o desprendimientos discretos de materia congelada del núcleo. 3) Las variaciones en la densidad de flujo son consistentes con las estimaciones de los tiem- pos de vida medios del H2O y del OH en presencia del campo de radiación solar. 4) Se encuentra una correlación entre la intensidad del flujo absorbido y anisotropías en Ia dinamica de la coma.

  16. The Future IR Office. (United States)

    Sanders, Liz


    Discusses three emerging trends on the affect of information technology on institutional research (IR), examining the following: information technology as a catalyst for change; pressures of access and accountability and challenges of open access to information, and the new informational professional. Offers a vision of technology's…

  17. Broadband Near IR Laser Hazard Filters. Phase 1 (United States)


    In order to provide the Army’s requirements for ocular and system protection in the near IR region (690 nm to 1100 nm), a filter should have for the...coated onto transparent glass substrates, glass mirrors and plastic substrates. The plastic substrates used in Phase I were polycarbonate, PMMA , Mylar, TPX...transparent in the visible to near IR spectrum including polycarbonate (PC), polymethyl methacrylate ( PMMA ), polystyrene (PS), polyvinyl-chloride (PVC

  18. IR spectroscopy of gaseous fluorocarbon ions: The perfluoroethyl anion (United States)

    Crestoni, Maria Elisa; Chiavarino, Barbara; Lemaire, Joel; Maitre, Philippe; Fornarini, Simonetta


    The first IR spectrum of a perfluorinated carbanion has been obtained in the gas phase by IRMPD spectroscopy. Quantum chemical calculations at the MP2/cc-pVTZ level were performed yielding the optimized geometries and IR spectra for a covalently bound C2F5- species and for conceivable loosely bound F-(C2F4) complexes. Both the computational results and the IR characterization point to a covalent structure for the assayed species in agreement with the reactivity pattern displayed with selected neutrals.

  19. HWIL IR imaging testing (United States)

    Vinson, R. J.; Passwater, R. D.


    The Army simulator facilities are presently configured to conduct hardware-in-the-loop mission tasks on the HELLFIRE and COPPERHEAD missile systems. These systems presently use a LASER seeker. The facility is an ideal candidate to be converted to include infrared (IR) seekers used on the TGSM system. This study investigates the possibility and impact of a facility update. This report documents the feasibility of developing a hardware-in-the-loop (HWIL) hybrid simulation incorporating infrared IR seekers used for the Assault Breaker program. Other hardware to be considered are the autopilot, signal conditioning, signal processing, and actuators which may be integrated into the system simulation. Considerations are given to replacing all or elements of hardware while substituting math models in the system simulation.

  20. The VISTA IR camera (United States)

    Dalton, Gavin B.; Caldwell, Martin; Ward, Kim; Whalley, Martin S.; Burke, Kevin; Lucas, John M.; Richards, Tony; Ferlet, Marc; Edeson, Ruben L.; Tye, Daniel; Shaughnessy, Bryan M.; Strachan, Mel; Atad-Ettedgui, Eli; Leclerc, Melanie R.; Gallie, Angus; Bezawada, Nagaraja N.; Clark, Paul; Bissonauth, Nirmal; Luke, Peter; Dipper, Nigel A.; Berry, Paul; Sutherland, Will; Emerson, Jim


    The VISTA IR Camera has now completed its detailed design phase and is on schedule for delivery to ESO"s Cerro Paranal Observatory in 2006. The camera consists of 16 Raytheon VIRGO 2048x2048 HgCdTe arrays in a sparse focal plane sampling a 1.65 degree field of view. A 1.4m diameter filter wheel provides slots for 7 distinct science filters, each comprising 16 individual filter panes. The camera also provides autoguiding and curvature sensing information for the VISTA telescope, and relies on tight tolerancing to meet the demanding requirements of the f/1 telescope design. The VISTA IR camera is unusual in that it contains no cold pupil-stop, but rather relies on a series of nested cold baffles to constrain the light reaching the focal plane to the science beam. In this paper we present a complete overview of the status of the final IR Camera design, its interaction with the VISTA telescope, and a summary of the predicted performance of the system.

  1. Development of IR Transmitting Chalcogenide Windows (United States)


    8217’ transmission with no sample in the sample beam. A typical spectrum of an oxide-free AsiSej glass is shown in fig. 1. Tiic absorption coefficient a was...val- ues. ’■ _ 17< C. 7’. Muynilian et al./lnfrsrcj §btorptk>n 14. impurity band as obMrved on ihe IR ipectri (iw f^s. 4 and 7). Tiic a valuos...of table 3 decrease in Ihe same order, and it seems elear that the hHier values of cy ob- served at tiic CO lasei w;;veleii"ilis are due to the low

  2. IR and the Earth

    DEFF Research Database (Denmark)

    Corry, Olaf; Stevenson, Hayley


    , in the end, one finite interconnected space. Together these two starting points make for the basic conundrum of Inter- national Relations and the Earth: how does a divided world live on a single globe? This introduction first provides an overview of the recent rise of ‘the environment’ in international......, ‘what has the environment ever done for IR?’, before the plan for the rest of the book sketches the content and direction of the ensuing chapters that explore the problematique of International Relations and the Earth....

  3. Detailed IR aperture measurements

    CERN Document Server

    Bruce, Roderik; Garcia Morales, Hector; Giovannozzi, Massimo; Hermes, Pascal Dominik; Mirarchi, Daniele; Quaranta, Elena; Redaelli, Stefano; Rossi, Carlo; Skowronski, Piotr Krzysztof; Wretborn, Sven Joel; CERN. Geneva. ATS Department


    MD 1673 was carried out on October 5 2016, in order to investigate in more detail the available aperture in the LHC high-luminosity insertions at 6.5 TeV and β∗=40 cm. Previous aperture measurements in 2016 during commissioning had shown that the available aperture is at the edge of protection, and that the aperture bottleneck at β∗=40 cm in certain cases is found in the separation plane instead of in the crossing plane. Furthermore, the bottlenecks were consistently found in close to the upstream end of Q3 on the side of the incoming beam, and not in Q2 on the outgoing beam as expected from calculations. Therefore, this MD aimed at measuring IR1 and IR5 separately (at 6.5 TeV and β∗=40 cm, for 185 µrad half crossing angle), to further localize the bottlenecks longitudinally using newly installed BLMs, investigate the difference in aperture between Q2 and Q3, and to see if any aperture can be gained using special orbit bumps.

  4. IR study of Pb–Sr titanate borosilicate glasses

    Indian Academy of Sciences (India)


    to study their structure systematically. IR spectrum of each glass composition shows a number of absorption bands. These bands are strongly influenced by the increasing substitution of SrO for PbO. Various bands shift with composition. Absorption peaks occur due to the vibrational mode of the borate network in these ...

  5. IRS View of a Planetary Collision in the Pleiades (United States)

    Song, Inseok; Lisse, Carey; Rhee, Joseph; Zuckerman, Ben


    Recently, we identified a sun-like Pleiades member, HD 23514, hosting a huge quantity of warm dust grains. Next to BD+20 307 (a field sun-like star), HD 23514 is currently the second dustiest, adolescent-age, star known with warm excess IR emission. Very short removal timescales of warm dust grains and adolescent ages of these two stars (>~100 Myr) indicate that the very dusty, warm excess, phenomenon is a transient event. A catastrophic collision between planetary embryos or planets is the most plausible origin of so much warm dust and such a collision mimics the postulated Moon-creation event in our terrestrial system. But the N-band spectra of BD+20 307 and HD 23514 appear very different, with peculiar emission at HD 23514 peaking at ~9 microns, a peak wavelength hardly seen among young stars and other main sequence excess stars. The strange N-band spectrum may point to an extra-ordinary condition around HD 23514 such as a very thick crust of a planet, a freakish chemical composition, or shocked silicates from a planetary collision. An IRS spectrum covering the 5-35um spectral range, rather than the highly restricted ground-based N-band spectrum will provide much stronger and clearer constraints on the dusty environment of HD 23514. We propose IRS observations with all four low resolution modules to obtain a diagnostic mid-IR spectrum of this rare, fascinating star.

  6. Olivine Composition of the Mars Trojan 5261 Eureka: Spitzer IRS Data

    NARCIS (Netherlands)

    Lim, L. F.; Emery, J. P.; Mueller, M.; Rivkin, A. S.; Trilling, D.; Burt, B. J.


    The largest Mars trojan, 5261 Eureka, is one of two prototype "Sa" asteroids in the Bus-Demeo taxonomy [1]. Analysis of its visible/near-IR spectrum [2] led to the conclusion that it might represent either an angritic analog or an olivine-rich composition such as an R chondrite. Spitzer IRS data

  7. Zellweger Spectrum (United States)

    ... Us Donate The Zellweger Spectrum Zellweger Syndrome, Neonatal Adrenoleukodystrophy (NALD), and Infantile Refsum’s Disease (IRD) The disorders ... of the Zellweger spectrum: Zellweger syndrome (ZS), neonatal adrenoleukodystrophy (NALD), and infantile Refsum disease (IRD). While these ...

  8. Olivine Composition of the Mars Trojan 5261 Eureka: Spitzer IRS Data (United States)

    Lim, L. F.; Burt, B. J.; Emery, J. P.; Mueller, M.; Rivkin, A. S.; Trilling, D.


    The largest Mars trojan, 5261 Eureka, is one of two prototype "Sa" asteroids in the Bus-Demeo taxonomy. Analysis of its visible/near-IR spectrum led to the conclusion that it might represent either an angritic analog or an olivine-rich composition such as an R chondrite. Spitzer IRS data (5-30 micrometers) have enabled us to resolve this ambiguity. The thermal-IR spectrum exhibits strong olivine reststrahlen features consistent with a composition of approximately equals Fo60-70. Laboratory spectra of R chondrites, brachinites, and chassignites are dominated by similar features.

  9. MMW/IR beam combiner with graphene IR window for MMW/IR compact range compound test (United States)

    Chen, Dong; Li, Yanhong; Pang, Xudong; Zhu, Weihua; Wang, Liquan; Liu, Zhigang; Wang, Tailei; Zhu, Shouzheng


    A millimeter wave (MMW)/infrared (IR) beam combiner with a graphene IR window for the MMW/IR compact range (CR) compound test is creatively proposed with comprehensive analysis and simulation. Graphene is used as the IR window material to transfer the IR feed signal behind a perforated MMW CR reflector for it has the unique property of high IR transmissivity and high MMW conductivity. This research shows that graphene IR windows have better IR transmissivity than conducting inductive mesh IR windows when the beam combiner meets the MMW CR test demanding. Graphene IR windows also show a better MMW test bandwidth than dielectric IR windows. Meanwhile, the graphene IR window MMW/IR beam combiner has a circular aperture test zone with which it is sufficient to test a cylindrical unit under test according to the requirement.

  10. Re-analysis of the Giotto mission data obtained by the Halley Multicolour Camera (HMC) with aim of large particles detection in the inner coma of comet 1P/Halley (United States)

    Shalygina, O. S.; Keller, H. U.; Blum, J.


    The Giotto spacecraft (SC) mission was the ESA's first interplanetary mission, that made close-up observations of a comet. The Giotto spaceprobe passed the nucleus of comet Halley at a fly-by distance of only 596 km early on 14 March 1986. During the approach, 2304 images of the comet were taken by the Halley Multicolour Camera (HMC) through different filters. The HMC experiment was a high-resolution imaging system onboard the spin-stabilized SC. Its spin axis was closely aligned with the SC-comet relative-velocity vector. Pointing of the camera was achieved by the spinning motion of the SC for one dimension and by rotation about an axis perpendicular to the spin of the SC for the other dimension. The spin period was about 4 seconds and the nominal imaging resolution was 22 m at 1000 km distance [1, 2]. HMC was taking images in the so-called Time Delay and Integration mode [2]. In this mode, only a narrow part of the CCD detector was uncovered, and vertical scan-out was provided by the spacecraft (and therefore the camera) spinning. During this spinning charges were transferred line-by-line in the same direction. The slit was made wider than 1 pixel, which increased exposure time but degraded the sharpness to some extent. The portion of the sky swept by the exposed lines during image acquisition was a section of an annulus resulting in over-sampling at the end of the exposed lines nearest the SC spin axis and under-sampling at the other end [2]. Several impacts of dust particles on the spacecraft were detected during the fly-by by the analysis of the changes in the SC attitude and spin period [1]. The changes occurred in large steps, requiring many impacts of massive dust particles well above an effective mass of 10 mg, which implies that a significant part of the cometary dust mass is contained in rather large particles. Moreover, since the time of the Giotto mission, large dust particles have been detected in the inner coma of other comets. The coma of comet 103P

  11. IR spectral analysis for the diagnostics of crust earthquake precursors

    Directory of Open Access Journals (Sweden)

    R. M. Umarkhodgaev


    Full Text Available Some possible physical processes are analysed that cause, under the condition of additional ionisation in a pre-breakdown electric field, emissions in the infrared (IR interval. The atmospheric transparency region of the IR spectrum at wavelengths of 7–15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analyzed. For daytime conditions, modifications of the adsorption spectra of the scattered solar emissions are studied; for nighttime, variations of emission spectra may be used for the analysis.

  12. IR spectroscopy of gaseous fluorocarbon ions: The perfluoroethyl anion

    Energy Technology Data Exchange (ETDEWEB)

    Crestoni, Maria Elisa; Chiavarino, Barbara [Dipartimento di Chimica e Tecnologie del Farmaco, Universita di Roma ' La Sapienza' , P. le A. Moro 5, I-00185 Roma (Italy); Lemaire, Joel; Maitre, Philippe [Universite Paris Sud, Laboratoire de Chimie Physique - UMR8000 CNRS, Faculte des Sciences - Batiment 350, 91405 Orsay Cedex (France); Fornarini, Simonetta, E-mail: [Dipartimento di Chimica e Tecnologie del Farmaco, Universita di Roma ' La Sapienza' , P. le A. Moro 5, I-00185 Roma (Italy)


    Highlights: Black-Right-Pointing-Pointer C{sub 2}F{sub 5}{sup -} ions are formed by dissociative electron capture in perfluoropropane. Black-Right-Pointing-Pointer Both their reactivity towards neutrals and IRMPD spectroscopy are investigated. Black-Right-Pointing-Pointer The sampled C{sub 2}F{sub 5}{sup -} ions are best described as covalently bound pentafluoroethyl anions. - Abstract: The first IR spectrum of a perfluorinated carbanion has been obtained in the gas phase by IRMPD spectroscopy. Quantum chemical calculations at the MP2/cc-pVTZ level were performed yielding the optimized geometries and IR spectra for a covalently bound C{sub 2}F{sub 5}{sup -} species and for conceivable loosely bound F{sup -}(C{sub 2}F{sub 4}) complexes. Both the computational results and the IR characterization point to a covalent structure for the assayed species in agreement with the reactivity pattern displayed with selected neutrals.

  13. Yearly variation and annual cycle of total column ozone over New Delhi (29°N, 77°E), India and Halley Bay (76°S, 27°W), British Antarctic Survey Station and its effect on night airglow intensity of OH(8, 3) for the period 1979–2005

    National Research Council Canada - National Science Library



    ...) concentration at New Delhi (29°N, 77°E), India and Halley Bay (76°S, 27°W), a British Antarctic Service Station reveals more decline in yearly mean ozone concentration at Halley Bay than at New...

  14. #Occupy IR: Exposing the Orthodoxy

    Directory of Open Access Journals (Sweden)

    Ivan Manokha


    Full Text Available The #occupy IR/IPE initiative was created in response to the #occupy movement, whose own roots can be traced backed to the latest crisis of global finance. In this contribution, we link #occupy and the crisis in a different way. We argue that we must occupy IR/IPE because of the discipline’s failure to apprehend and acknowledge the crisis itself, just as the Occupy movement is calling for their overarching authorities to notice and help address the social and economic inequalities produced by this crisis. More precisely, we argue that the dominant academic orthodoxy, via a series of continuously reproduced dichotomies, has rendered IR/IPE incapable of dealing with a phenomenon as complex as the financial crisis...

  15. Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/−-IRS-1+/− Double Heterozygous (IR-IRS1dh Mice

    Directory of Open Access Journals (Sweden)

    Andras Franko


    Full Text Available Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR+/−-insulin receptor substrate-1 (IRS-1+/− double heterozygous (IR-IRS1dh mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

  16. Detection of IR target by fusing multispectral IR data (United States)

    Li, Liya; Qi, Meng; Gao, Xuhui


    Detection of the small target in clutter, usually regarded as singular points in the infrared image, is an important issue in infrared searching and tracking (IRST) system. Because of the far range of the target to the sensor, the stealth technology, the effects of inherent sensor noise and the phenomena of nature, the target is more difficult to be detected. Multispectral sensor system has been proved it could greatly improve detection of the small, hard-to-find targets by multispectral processing techniques (such as sensor or image fusion). Aiming at the problem of multispectral IR Target Detection, a kind method of the multispectral IR target detection is proposed, based on the existed detection systems. In this method, the image registration is done firstly to make the different sensors have a same scene. Then, a fusion rule, named as adaptive weighted voting theory, is developed to combine the target detection results from the different spectral sensors. The adaptive weighted voting theory can give the different weights, based on the different spectral IR characteristics, and these weights decide the detected target is identified as real target or background. The experimental results show that the proposed method can reduce the detection uncertainty and improve the detection performance. Compared with the single spectral detection results and the others fusion detection methods, it can decrease the lost alarm rate and the false alarm rate effectively. The proposed method has been employed in our IR surveillance system, and it is easy to be used in the various circumstances.

  17. Short-range structure in (partially) crystalline potato starch determined with attenuated total reflectance Fourier-transform IR spectroscopy

    NARCIS (Netherlands)

    Vliegenthart, J.F.G.; Soest, J.J.G. van; Tournois, H.; Wit, D. de


    A fast and direct method, based on infrared spectroscopy, for quantitative determination of starch short-range structure has been developed. The IR spectrum of starch is sensitive to changes in short-range structure in the C—C and C—O stretching region at 1300-800 cm−1. The IR absorbance band at

  18. Rethinking IR from the Amazon

    Directory of Open Access Journals (Sweden)

    Manuela Picq

    Full Text Available Abstract This article proposes Amazonia as a site to think world politics. The Amazon is invisible in the study International Relations (IR, yet its experiences are deeply global. I present the international dynamics at play in Amazonia at different historical moments to posit that this periphery has contributed to forging the political-economy of what is refer to as the core. The Amazon's absence from the study of IR speaks about the larger inequality in processes of knowledge production. Serious engagements with Amazonia are one way to invite a plurality of worlds in the production of theories, disrupting global divisions of labor in knowledge production ally.

  19. The introduction of Copyright Law in England and its effect on the dispute between Newton, Halley and Flamsteed concerning the 'pirated' Historia Coelestis 1712 (United States)

    Birks, J. L.


    In 1712 Sir Isaac Newton and Dr Edmund Halley, acting on behalf of the Royal Society, printed some 400 copies of the star catalogue Historia Coelestis under the name of John Flamsteed, including his observations of the positions of nearly 3000 stars made at Greenwich from 1676. Flamsteed had not been allowed to check the proofs of this work before it was published, and he was enraged to see what he considered to be a travesty of his life's work. This became a great scientific scandal of the early eighteenth century, which echoes down to the present day.

  20. Behavioral Characteristics and CO+CO2 Production Rates of Halley-Type Comets Observed by NEOWISE (United States)

    Rosser, Joshua David; Bauer, James M.; Mainzer, Amy K.; Kramer, Emily A.; Masiero, Joseph R.; Nugent, Carrie; Sonnett, Sarah M.; Fernandez, Yanga R.; Wright, Edward L.; WISE, NEOWISE


    From the NEOWISE dataset of comet images, 11 different Halley-Type Comets (HTCs) were identified and analyzed for dust production rates (Afρ), CO+CO2 production rates (QCO2), and nucleus size. The objects considered ranged in heliocentric distance from 1.21 AU to 2.66 AU and were only considered when showing signs of reasonable activity. When multiple epochs were included and when combined with data from previous WISE and NEOWISE studies, our dataset totaled to 21 observations; 13 of which included active comets, and 7 for which we calculated upper limits of production. Comet P/2010 JC81 was removed from consideration due to clear inactivity. For this study, active comets are defined as those which exhibit excess signal of at least 3σ in the 4.6 μm detection band, while comets for which upper limits were calculated demonstrated excess signal of 1σ in the 4.6 μm detection band. Furthermore, we confirmed the nucleus size of 27P, P/2006 HR30, C/2010 L5, P/2012 NJ, C/2016 S1. We found that given the range in heliocentric distance for this sample of HTCs, Afρ ranged from 0.790 ± 0.036 to 2.64 ± 0.14, and QCO2 ranged from 25.08 ± 0.08 to 26.71 ± 0.12. No significant correlation between dust production and heliocentric distance, nor CO+CO2 production with heliocentric distance was found for this population. This poster will display production rates and other physical properties of these HTCs, as well as place the ensemble of HTC production rate properties into context.

  1. Compact IR synchrotron beamline design. (United States)

    Moreno, Thierry


    Third-generation storage rings are massively evolving due to the very compact nature of the multi-bend achromat (MBA) lattice which allows amazing decreases of the horizontal electron beam emittance, but leaves very little place for infrared (IR) extraction mirrors to be placed, thus prohibiting traditional IR beamlines. In order to circumvent this apparent restriction, an optimized optical layout directly integrated inside a SOLEIL synchrotron dipole chamber that delivers intense and almost aberration-free beams in the near- to mid-IR domain (1-30 µm) is proposed and analyzed, and which can be integrated into space-restricted MBA rings. Since the optics and chamber are interdependent, the feasibility of this approach depends on a large part on the technical ability to assemble mechanically the optics inside the dipole chamber and control their resulting stability and thermo-mechanical deformation. Acquiring this expertise should allow dipole chambers to provide almost aberration-free IR synchrotron sources on current and `ultimate' MBA storage rings.

  2. The characteristics of the lower stratospheric gravity wavefield above Halley (75°S, 26°W), Antarctica, from radiosonde observations (United States)

    Moffat-Griffin, T.; Colwell, S. R.


    Daily radiosonde observations between 2003 and 2013 from Halley research station, Antarctica (75°S, 26°W), are used to determine climatologies of gravity wave properties in the lower stratosphere (between 15 km and 22 km altitude). Individual waves are extracted from the radiosonde profile using wavelet analysis and separated into upward and downward propagating waves. An increase in the percentage of downward propagating waves ( 30% of the waves) is seen during the winter months. For the upward and downward propagating waves, their horizontal and vertical wavelength, intrinsic frequency, energy density, pseudomomentum flux, and direction of propagation are determined. The upward propagating wavefield is found to be dominated by waves with short vertical wavelength ( 1 km) and low intrinsic frequency (ω f). The downward propagating wavefield is composed of a wider distribution of vertical wavelength waves and has a larger proportion of higher-frequency waves present. The upward propagating waves show an increase in total energy density in autumn and spring; the larger increase occurs during spring (up to 1.7 J kg-1 in September). The downward propagating waves increase in total energy density occurs during wintertime (up to 0.7 J kg-1 in June). During winter the contributions of the upward and downward propagating waves to the total energy density and pseudomomentum flux are almost equal. This paper details the first study of individual gravity wave properties combined into upward and downward propagating wave climatologies in the lower stratosphere above Halley.

  3. Quantitative IR microscopy and spectromics open the way to 3D digital pathology. (United States)

    Bobroff, Vladimir; Chen, Hsiang-Hsin; Delugin, Maylis; Javerzat, Sophie; Petibois, Cyril


    Currently, only mass-spectrometry (MS) microscopy brings a quantitative analysis of chemical contents of tissue samples in 3D. Here, the reconstruction of a 3D quantitative chemical images of a biological tissue by FTIR spectro-microscopy is reported. An automated curve-fitting method is developed to extract all intense absorption bands constituting IR spectra. This innovation benefits from three critical features: (1) the correction of raw IR spectra to make them quantitatively comparable; (2) the automated and iterative data treatment allowing to transfer the IR-absorption spectrum into a IR-band spectrum; (3) the reconstruction of an 3D IR-band matrix (x, y, z for voxel position and a 4th dimension with all IR-band parameters). Spectromics, which is a new method for exploiting spectral data for tissue metadata reconstruction, is proposed to further translate the related chemical information in 3D, as biochemical and anatomical tissue parameters. An example is given with oxidative stress distribution and the reconstruction of blood vessels in tissues. The requirements of IR microscopy instrumentation to propose 3D digital histology as a clinical routine technology is briefly discussed. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. WFC3 IR subarray anomaly (United States)

    Bushouse, Howard


    Certain combinations of WFC3 IR subarray size and sample sequence yield images that show a sharp change in background level that exactly bi-sects each detector amplifier quadrant. The change in level has an amplitude of a few DN per pixel. The cause of this anomaly and its apparent correlation with subarray size and sample sequence is not understood. Given the 4 available subarray sizes and 11 available readout sample sequences, there are a total of 44 possible subarray mode readout combinations. To date, 14 of those combinations have been used on-orbit in either calibration and GO programs. Of those, 3 combinations show the anomaly. This program will obtain IR dark exposures in the remaining 30 readout combinations that have not yet been explored. This will add to our knowledge of which combinations show the anomaly and will therefore help us to understand its origin.

  5. Optimized IR synchrotron beamline design. (United States)

    Moreno, Thierry


    Synchrotron infrared beamlines are powerful tools on which to perform spectroscopy on microscopic length scales but require working with large bending-magnet source apertures in order to provide intense photon beams to the experiments. Many infrared beamlines use a single toroidal-shaped mirror to focus the source emission which generates, for large apertures, beams with significant geometrical aberrations resulting from the shape of the source and the beamline optics. In this paper, an optical layout optimized for synchrotron infrared beamlines, that removes almost totally the geometrical aberrations of the source, is presented and analyzed. This layout is already operational on the IR beamline of the Brazilian synchrotron. An infrared beamline design based on a SOLEIL bending-magnet source is given as an example, which could be useful for future IR beamline improvements at this facility.

  6. Spectrum war

    DEFF Research Database (Denmark)

    Henten, Anders; Tadayoni, Reza; Windekilde, Iwona Maria

    a conflict in accessing to the valuable spectrum resources allocated to TV broadcast that has been there for many years and which has been intensified in different phases of technological development and the second being an obvious conflict of interest between the different stake holders within the mobile...

  7. FT-IR spectroscopy of lipoproteins—A comparative study (United States)

    Krilov, Dubravka; Balarin, Maja; Kosović, Marin; Gamulin, Ozren; Brnjas-Kraljević, Jasminka


    FT-IR spectra, in the frequency region 4000-600 cm -1, of four major lipoprotein classes: very low density lipoprotein (VLDL), low density lipoprotein (LDL) and two subclasses of high density lipoproteins (HDL 2 and HDL 3) were analyzed to obtain their detailed spectral characterization. Information about the protein domain of particle was obtained from the analysis of amide I band. The procedure of decomposition and curve fitting of this band confirms the data already known about the secondary structure of two different apolipoproteins: apo A-I in HDL 2 and HDL 3 and apo B-100 in LDL and VLDL. For information about the lipid composition and packing of the particular lipoprotein the well expressed lipid bands in the spectra were analyzed. Characterization of spectral details in the FT-IR spectrum of natural lipoprotein is necessary to study the influence of external compounds on its structure.

  8. Applications of FT-IR spectrophotometry in cancer diagnostics. (United States)

    Bunaciu, Andrei A; Hoang, Vu Dang; Aboul-Enein, Hassan Y


    This review provides a brief background to the application of infrared spectroscopy, including Fourier transform-infrared spectroscopy, in biological fluids. It is not meant to be complete or exhaustive but to provide the reader with sufficient background for selected applications in cancer diagnostics. Fourier transform-infrared spectroscopy (FT-IR) is a fast and nondestructive analytical method. The infrared spectrum of a mixture serves as the basis to quantitate its constituents, and a number of common clinical chemistry tests have proven to be feasible using this approach. This review focuses on biomedical FT-IR applications, published in the period 2009-2013, used for early detection of cancer through qualitative and quantitative analysis.

  9. Climate Prediction Center IR 4km Dataset (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — CPC IR 4km dataset was created from all available individual geostationary satellite data which have been merged to form nearly seamless global (60N-60S) IR...

  10. Dust Shells around OH/IR Stars

    Directory of Open Access Journals (Sweden)

    Kyung-Won Suh


    Full Text Available We have made new models for mass-losing OH/IR stars to explain the properties of the dust shells around them using more accurate information about the material in the shell and the physical processes including pulsations. We have applied our dust opacity which has been deduced from observations and experimental data to various density distributions, calculated the model emergent spectra, and compared with observations. Contrary to previous suggestions, we could fit observations fairly well using density distribution ρ∝r-2, which is physically plausible, with proper choice of opacities. The time scales for dust formation, growth, and movement are calculated to be compared with pulsation periods. The change of the emergent spectrum depending of the phase of pulsation can be explained fairly well by changing dust condensation radius(for fixed dust condensation temperature in step with the change in stellar luminosity. The effects of stellar wind models and pulsation models on dust shells with attention to emergent spectra are discussed.

  11. Isolated Gramicidin Peptides Probed by IR Spectroscopy

    NARCIS (Netherlands)

    Rijs, A. M.; Kabelac, M.; Abo-Riziq, A.; Hobza, P.; de Vries, M. S.


    We report double-resonant IR/UV ion-dip spectroscopy of neutral gramicidin peptides in the gas phase. The IR spectra of gramicidin A and C, recorded in both the 1000 cm(-1) to 1800 cm(-1) and the 2700 to 3750 cm(-1) region, allow structural analysis. By studying this broad IR range, various local

  12. IR spectral analysis for the diagnostics of crust earthquake precursors (United States)

    Umarkhodgaev, R. M.; Liperovsky, V. A.; Mikhailin, V. V.; Meister, C.-V.; Naumov, D. Ju


    In regions of future earthquakes, a few days before the seismic shock, the emanation of radon and hydrogen is being observed, which causes clouds of increased ionisation in the atmosphere. In the present work the possible diagnostics of these clouds using infrared (IR) spectroscopy is considered, which may be important and useful for the general geophysical system of earthquake prediction and the observation of industrial emissions of radioactive materials into the atmosphere. Some possible physical processes are analysed, which cause, under the condition of additional ionisation in a pre-breakdown electrical field, emissions in the IR interval. In doing so, the transparency region of the IR spectrum at wavelengths of 7-15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analysed. The laboratory equipment for the investigation of the IR absorption spectrum is constructed for the cases of normal and decreased atmospheric pressures. The syntheses of ozone and nitrous oxides are performed in the barrier discharge. It is studied if the products of the syntheses may be used to model atmospheric processes where these components take part. Spectra of products of the syntheses in the wavelength region of 2-10 μm are observed and analysed. A device is created for the syntheses and accumulation of nitrous oxides. Experiments to observe the IR-spectra of ozone and nitrous oxides during the syntheses and during the further evolution of these molecules are performed. For the earthquake prediction, practically, the investigation of emission spectra is most important, but during the laboratory experiments, the radiation of the excited molecules is shifted by a

  13. Carbon nanotube IR detectors (SV)

    Energy Technology Data Exchange (ETDEWEB)

    Leonard, F. L.


    Sandia National Laboratories (Sandia) and Lockheed Martin Corporation (LMC) collaborated to (1) evaluate the potential of carbon nanotubes as channels in infrared (IR) photodetectors; (2) assemble and characterize carbon nanotube electronic devices and measure the photocurrent generated when exposed to infrared light;(3) compare the performance of the carbon nanotube devices with that of traditional devices; and (4) develop and numerically implement models of electronic transport and opto-electronic behavior of carbon nanotube infrared detectors. This work established a new paradigm for photodetectors.

  14. Laboratory IR spectroscopy of PAHs

    NARCIS (Netherlands)

    Oomens, J.; Pirali, O.; Tielens, A.G.G.M.; Schlemmer, S.; Giesen, T.; Mutschke, H.; Jäger, C.


    Written by leading scientists in the field and intended for a broader readership, this is an ideal starting point for an overview of current research and developments. As such, the book covers a broad spectrum of laboratory astrophysics and chemistry, describing recent advances in experiments, as

  15. Coprates Chasma Landslides in IR (United States)


    [figure removed for brevity, see original site] Today's daytime IR image is of a portion of Coprates Chasma, part of Valles Marineris. As with yesterday's image, this image shows multiple large landslides. Image information: IR instrument. Latitude -8.2, Longitude 300.2 East (59.8 West). 100 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  16. Optoelectronic sensors of gazes on the base of multi-element sources of IR-radiation

    Directory of Open Access Journals (Sweden)

    Kabatsiy V. N.


    Full Text Available The constructions of optoelectronic sensors to methane and carbon dioxide, taking into account the peculiarities of spectral characteristics of sources and receivers of medium IR-diapason spectrum are proposed. The possibility of use of optoelectronic sensors for the measuring of CH4 and CO2 concentration in diapason 0—3 vol.% is demonstrated.

  17. Discovery and Classification of DES15C2ir by SALT (United States)

    Kasai, E.; Bassett, B.; Crawford, S.; Vaisanen, P.; Smith, M.; Barbary, K.; Bloom, J. S.; Goldstein, D.; Nugent, P.; Perlmutter, S.; Foley, R. J.; Castander, F. J.; Desai, S.; Paech, K.; Smith, R. C.; Schubnell, M.; Kessler, R.; Scolnic, D.; Covarrubias, R. A.; Brout, D. J.; Fischer, J. A.; Gladney, L.; March, M.; Sako, M.; Wolf, R. C.; Brown, P. J.; Krisciunas, K.; Suntzeff, N.; Nichol, R.; Papadopoulos, A.; D'Andrea, C.; Sullivan, M.; Maartens, R.; Gupta, R.; Kovacs, E.; Kuhlmann, S.; Spinka, H.; Ahn, E.; Finley, D. A.; Frieman, J.; Marriner, J.; Wester, W.; Aldering, G.; Kim, A. G.; Thomas, R. C.


    We report optical spectroscopy of a supernova candidate discovered by the Dark Energy Survey (ATel #4668). The spectrum (400-850nm) of DES15C2ir was obtained using the Robert Stobie Spectrograph (RSS) on the Southern African Large Telescope (SALT).

  18. Optical and near-IR spectroscopy of nova Oph 2017 (TCP J17394608-2457555) (United States)

    Raj, Ashish; Pavana, M.; Anupama, G. C.; Bhowmick, Anirban; Dar, Rahul; Kumar, S. Pramod


    We report optical and near-IR spectroscopic observations of the nova Oph 2017 (ATel #10366, #10367, #10369). The optical spectrum on May 11, 2017 was obtained using the HFOSC instrument mounted on the 2m Himalayan Chandra Telescope (HCT) of the Indian Astronomical Observatory, Hanle, India, in the 380-800nm wavelength range.

  19. IR and Raman spectroscopic studies of sol–gel derived alkaline ...

    Indian Academy of Sciences (India)

    from 50–3300 cm. −1 in Stokes-shifted Raman region, all in one spectrum. For Fourier transform infrared measurements (FTIR) sol– gel derived glasses were crushed with pestle in an agate mor- tar. The crushed material was mixed with potassium bro- mide (Merck IR spectroscopy grade) in 1:100 proportion and dried at 40.

  20. A salt-bridge structure in solution revealed by 2D-IR spectroscopy. (United States)

    Huerta-Viga, Adriana; Domingos, Sérgio R; Amirjalayer, Saeed; Woutersen, Sander


    Salt bridges are important interactions for the stability of protein conformations, but up to now it has been difficult to determine salt-bridge geometries in solution. Here we characterize the spatial structure of a salt bridge between guanidinium (Gdm(+)) and acetate (Ac(-)) using two-dimensional vibrational (2D-IR) spectroscopy. We find that as a result of salt bridge formation there is a significant change in the infrared response of Gdm(+) and Ac(-), and cross peaks between them appear in the 2D-IR spectrum. From the 2D-IR spectrum we determine the relative orientation of the transition-dipole moments of the vibrational modes of Gdm(+) and Ac(-), as well as the coupling between them.

  1. Observacoes do Cometa de Halley no Continuo de 22 GHz E 44 GHz, E NA Raia Maser de Vapor de H20 EM 22.2 GHz (United States)

    Abraham, Z.; Scalise, E., Jr.; Botti, L. C. L.; Cancoro, A. C. O.; Monteiro Do Vale, J. L.; del Ciampo, L. F.; Tateyama, C. E.; Vilas Boas, J. W. S.; Homor, J. L.; Kaufmann, P.


    0 cometa de Halley foi observado no contínuo nas frequencias de 22 GHz e 44 GHz no Observatório de Itapetinga, Brasil, no período Fevereiro-Abril de 1986. 0 cometa foi detetado em ambas frequẽncias, apresentando variabilidade corn escalas de tempo de horas. Cálculos teóricos mostram que a radicão não pode ser devida a transicões livre-livre na região ionizada resultante da interacão do cometa corn 0 vento solar. A emissão seria então devida à radiacão térmica dos gráos da coma do cometa, cuja densidade também foi variável em intervalo de horas. Não foi detetada emissão maser de H2O maior que 4 Jy.

  2. The Spectral Energy Distribution of HH 100 IRS (United States)

    Siebenmorgen, Ralf


    Recent progress in the modeling of the radiative transfer in star forming regions has lead to improved dusty envelope models. Such models can now explain in great detail the observed infrared spectrum. The success of such models suggests that input parameters correspond to the true physical situation of the environment of the young stellar object. However, so far only minor attention has been given to models which include the spectroscopic signature of ice bands. Such models are applied to the Herbig-Haro energy source HH100 IRS. Calculations have been performed to interpret the spectral energy distribution as a function of dust parameters such as the grain size, the ice volume fraction, and the 'fluffiness' of the particles. The infrared spectrum together with the strength of the water ice band of HH 100 IRS is successfully reproduced if an upper limit of the grain size below 1 micron is used. Comet-like grains, with sizes above 1 micron, result in a poor fit of the observations.

  3. IR Thermography NDE of ISS Radiator Panels (United States)

    Koshti, Ajay; Winfree, William; Morton, Richard; Wilson, Walter; Reynolds, Gary


    The presentation covers an active and a passive infrared (IR) thermography for detection of delaminations in the radiator panels used for the International Space Station (ISS) program. The passive radiator IR data was taken by a NASA astronaut in an extravehicular activity (EVA) using a modified FLIR EVA hand-held camera. The IR data could be successfully analyzed to detect gross facesheet disbonds. The technique used the internal hot fluid tube as the heat source in analyzing the IR data. Some non-flight ISS radiators were inspected using an active technique of IR flash thermography to detect disbond of face sheet with honeycomb core, and debonds in facesheet overlap areas. The surface temperature and radiated heat emission from flight radiators is stable during acquisition of the IR video data. This data was analyzed to detect locations of unexpected surface temperature gradients. The flash thermography data was analyzed using derivative analysis and contrast evolutions. Results of the inspection are provided.

  4. Atmospheric Entry Experiments at IRS (United States)

    Auweter-Kurtz, M.; Endlich, P.; Herdrich, G.; Kurtz, H.; Laux, T.; Löhle, S.; Nazina, N.; Pidan, S.


    Entering the atmosphere of celestial bodies, spacecrafts encounter gases at velocities of several km/s, thereby being subjected to great heat loads. The thermal protection systems and the environment (plasma) have to be investigated by means of computational and ground facility based simulations. For more than a decade, plasma wind tunnels at IRS have been used for the investigation of TPS materials. Nevertheless, ground tests and computer simulations cannot re- place space flights completely. Particularly, entry mission phases encounter challenging problems, such as hypersonic aerothermodynamics. Concerning the TPS, radiation-cooled materials used for reuseable spacecrafts and ablator tech- nologies are of importance. Besides the mentioned technologies, there is the goal to manage guidance navigation, con- trol, landing technology and inflatable technologies such as ballutes that aim to keep vehicles in the atmosphere without landing. The requirement to save mass and energy for planned interplanetary missions such as Mars Society Balloon Mission, Mars Sample Return Mission, Mars Express or Venus Sample Return mission led to the need for manoeuvres like aerocapture, aero-breaking and hyperbolic entries. All three are characterized by very high kinetic vehicle energies to be dissipated by the manoeuvre. In this field flight data are rare. The importance of these manoeuvres and the need to increase the knowledge of required TPS designs and behavior during such mission phases point out the need of flight experiments. As result of the experience within the plasma diagnostic tool development and the plasma wind tunnel data base, flight experiments like the PYrometric RE-entry EXperiment PYREX were developed, fully qualified and successfully flown. Flight experiments such as the entry spectrometer RESPECT and PYREX on HOPE-X are in the conceptual phase. To increase knowledge in the scope of atmospheric manoeuvres and entries, data bases have to be created combining both

  5. Electron paramagnetic resonance, optical absorption, IR and Raman spectral studies on pelecypod shell (United States)

    Lakshmi Reddy, S.; Reddy, K. N. M.; Siva Reddy, G.; Reddy, B. J.; Frost, R. L.; Endo, Tamio


    Pelecypod shell originated from Kolleru lake of Andhra Pradesh is used in the present work. It contains Mn(II) and Fe(III) in traces. The EPR spectrum of the compound is due to Mn(II) which is in three independent sites. The three g values are evaluated with slight differences. The hyperfine component varies from 9.33 to 9.49 mT. The zero field splitting parameter is also ranges from 43.8(1) to 44.1(1) mT. Using the covalence parameter the number of ligands around metal is estimated as 20. In EPR spectrum Fe(III) is identified. The optical absorption spectrum is attributed to Mn(II) in octahedral geometry. Further 10 Dq band is attributed to Fe(II) in the optical absorption spectrum. NIR spectral results are due to water fundamentals, whereas IR and Raman spectrum is due to carbonate ion fundamentals.

  6. Analysis of Gasolines by FT-IR Spectroscopy. (United States)

    Fodor, G E; Kohl, K B; Mason, R L


    An experimental and computational protocol was established for the simultaneous determination of several key gasoline properties from a single Fourier transform infrared (FT-IR) spectrum. The study has shown that midband FT-IR spectroscopy combined with multivariate calibration analysis is a versatile, efficient, and accurate technique for the simultaneous estimation of key gasoline properties within about 1 min with less than 2 mL of sample. The FT-IR-derived values of gasoline properties include research and motor octane numbers, aromatic, olefinic, and saturated hydrocarbon content, benzene content, and concentrations of ethanol, methyl tert-butyl ether, and total oxygen. Concentrations of other oxygenated compounds are expected to be equally predictable. However, since these oxygen-containing species have not been adequately represented among the currently commercially available gasoline samples, their calibration may only be achieved using laboratory fuel blends. Midrange boiling point data may also be estimated. Fuel properties determined by minor concentrations of fuel components, e.g., flash point, sulfur content, etc., may not be modeled because the corresponding FT-IR signals are below detection limits of presented experimental protocol. The precision of this procedure was shown to be comparable to reproducibility of the standard laboratory analyses used for direct measurement of specific fuel properties, with squared correlation coefficient (R(2)) ranging from 0.94 to 0.99 between the two sets of measurements. This new methodology could increase the corresponding output of the petroleum laboratories by a factor of over 200 to 1 while maintaining data integrity and minimizing sample requirements, environmental hazards, and cost.

  7. High-definition Fourier Transform Infrared (FT-IR) spectroscopic imaging of human tissue sections towards improving pathology. (United States)

    Sreedhar, Hari; Varma, Vishal K; Nguyen, Peter L; Davidson, Bennett; Akkina, Sanjeev; Guzman, Grace; Setty, Suman; Kajdacsy-Balla, Andre; Walsh, Michael J


    High-definition Fourier Transform Infrared (FT-IR) spectroscopic imaging is an emerging approach to obtain detailed images that have associated biochemical information. FT-IR imaging of tissue is based on the principle that different regions of the mid-infrared are absorbed by different chemical bonds (e.g., C=O, C-H, N-H) within cells or tissue that can then be related to the presence and composition of biomolecules (e.g., lipids, DNA, glycogen, protein, collagen). In an FT-IR image, every pixel within the image comprises an entire Infrared (IR) spectrum that can give information on the biochemical status of the cells that can then be exploited for cell-type or disease-type classification. In this paper, we show: how to obtain IR images from human tissues using an FT-IR system, how to modify existing instrumentation to allow for high-definition imaging capabilities, and how to visualize FT-IR images. We then present some applications of FT-IR for pathology using the liver and kidney as examples. FT-IR imaging holds exciting applications in providing a novel route to obtain biochemical information from cells and tissue in an entirely label-free non-perturbing route towards giving new insight into biomolecular changes as part of disease processes. Additionally, this biochemical information can potentially allow for objective and automated analysis of certain aspects of disease diagnosis.

  8. High-definition Fourier Transform Infrared (FT-IR) Spectroscopic Imaging of Human Tissue Sections towards Improving Pathology (United States)

    Nguyen, Peter L.; Davidson, Bennett; Akkina, Sanjeev; Guzman, Grace; Setty, Suman; Kajdacsy-Balla, Andre; Walsh, Michael J.


    High-definition Fourier Transform Infrared (FT-IR) spectroscopic imaging is an emerging approach to obtain detailed images that have associated biochemical information. FT-IR imaging of tissue is based on the principle that different regions of the mid-infrared are absorbed by different chemical bonds (e.g., C=O, C-H, N-H) within cells or tissue that can then be related to the presence and composition of biomolecules (e.g., lipids, DNA, glycogen, protein, collagen). In an FT-IR image, every pixel within the image comprises an entire Infrared (IR) spectrum that can give information on the biochemical status of the cells that can then be exploited for cell-type or disease-type classification. In this paper, we show: how to obtain IR images from human tissues using an FT-IR system, how to modify existing instrumentation to allow for high-definition imaging capabilities, and how to visualize FT-IR images. We then present some applications of FT-IR for pathology using the liver and kidney as examples. FT-IR imaging holds exciting applications in providing a novel route to obtain biochemical information from cells and tissue in an entirely label-free non-perturbing route towards giving new insight into biomolecular changes as part of disease processes. Additionally, this biochemical information can potentially allow for objective and automated analysis of certain aspects of disease diagnosis. PMID:25650759

  9. Quantitative gas analysis with FT-IR

    DEFF Research Database (Denmark)

    Bak, J.; Larsen, A.


    Calibration spectra of CO in the 2.38-5100 ppm concentration range (22 spectra) have been measured with a spectral resolution of 4 cm(-1), in the mid-IR (2186-2001 cm(-1)) region, with a Fourier transform infrared (FT-IR) instrument. The multivariate calibration method partial least-squares (PLS1...

  10. How to remedy Eurocentrism in IR?

    DEFF Research Database (Denmark)

    Bilgin, Pinar


    While IR's Eurocentric limits are usually acknowledged, what those limits mean for theorizing about the international is seldom clarified. In The Global Transformation, Buzan and Lawson offer a 'composite approach' that goes some way towards addressing IR's Eurocentrism, challenging existing myths...

  11. Biochemical applications of FT-IR spectroscopy

    NARCIS (Netherlands)

    Pistorius, A.M.A.


    This thesis describes the use of (FT-)IR spectroscopy in general biochemical research. In chapter 3, IR spectroscopy is used in the quantitation of residual detergent after reconstitution of an integral membrane protein in a pre-defined lipid matrix. This chapter discusses the choice of the

  12. In vivo dosimetry thermoluminescence dosimeters during brachytherapy with a 370 GBq {sup 192}Ir source

    Energy Technology Data Exchange (ETDEWEB)

    Cuepers, S.; Piessens, M.; Verbeke, L.; Roelstraete, A. [Onze-Lieve-Vrouw Hospitaal, Aalst (Belgium). Dept. of Radiotherapy and Oncology


    When using LiF thermoluminescence dosimeters in brachytherapy, we have to take into account the properties of a high dose rate {sup 192}Ir source (energy spectrum ranging form 9 to 885 keV, steep dose gradient in the vicinity of the source) and these of the dosimeters themselves (supralinearity, reproducibility, size). All these characteristics combine into a set of correction factors which have been determined during in phantom measurements. These results have then been used to measure the dose delivered to organs at risk (e.g. rectum, bladder, etc.) during high dose rate brachytherapy with a 370 GBq {sup 192}Ir source for patients with gynaecological tumors.

  13. Modelling the physical multiphase interactions of HNO3 between snow and air on the Antarctic Plateau (Dome C and coast (Halley

    Directory of Open Access Journals (Sweden)

    H. G. Chan


    Full Text Available Emissions of nitrogen oxide (NOx  =  NO + NO2 from the photolysis of nitrate (NO3− in snow affect the oxidising capacity of the lower troposphere especially in remote regions of high latitudes with little pollution. Current air–snow exchange models are limited by poor understanding of processes and often require unphysical tuning parameters. Here, two multiphase models were developed from physically based parameterisations to describe the interaction of nitrate between the surface layer of the snowpack and the overlying atmosphere. The first model is similar to previous approaches and assumes that below a threshold temperature, To, the air–snow grain interface is pure ice and above To a disordered interface (DI emerges covering the entire grain surface. The second model assumes that air–ice interactions dominate over all temperatures below melting of ice and that any liquid present above the eutectic temperature is concentrated in micropockets. The models are used to predict the nitrate in surface snow constrained by year-round observations of mixing ratios of nitric acid in air at a cold site on the Antarctic Plateau (Dome C; 75°06′ S, 123°33′ E; 3233 m a.s.l. and at a relatively warm site on the Antarctic coast (Halley; 75°35′ S, 26°39′ E; 35 m a.s.l. The first model agrees reasonably well with observations at Dome C (Cv(RMSE  =  1.34 but performs poorly at Halley (Cv(RMSE  =  89.28 while the second model reproduces with good agreement observations at both sites (Cv(RMSE  =  0.84 at both sites. It is therefore suggested that in winter air–snow interactions of nitrate are determined by non-equilibrium surface adsorption and co-condensation on ice coupled with solid-state diffusion inside the grain, similar to Bock et al. (2016. In summer, however, the air–snow exchange of nitrate is mainly driven by solvation into liquid micropockets following Henry's law with

  14. Eventos de Desconexão no Cometa P/Halley sob a Ótica do Modelo de Reconexão Magnética (United States)

    Voelzke, M. R.; Matsuura, O. T.


    531 imagens contidas no The International Halley Watch Atlas of Large-Scale Phenomena (Brandt et al., 1992) cobrindo o período de setembro de 1985 a julho de 1986 foram analisadas visando identificar, caracterizar as propriedades e correlacionar estruturas morfológicas da cauda de plasma do cometa P/Halley. A análise revelou 47 eventos de desconexão (DEs) (Niedner & Brandt, 1979; Jockers, 1985; Celnik et al., 1988; Delva et al., 1991). A análise completa de todas as imagens encontra-se publicada em Voelzke & Matsuura, 1998. A distribuição dos DEs na distância heliocêntrica apresenta um caráter bimodal possivelmente associado com a distribuição espacial das fronteiras de setor magnético do meio interplanetário. Os 47 DEs fotografados em 47 imagens distintas permitiram determinar 19 origens de DEs, ou seja, o instante em que supostamente o cometa cruzou a fronteira entre setores magnéticos do vento solar. Tais dados cometários foram comparados com dados do vento solar provenientes de medidas realizadas in situ pelas sondas IMP-8, ICE e PVO, que mediram a variação da velocidade do vento solar, da densidade e da pressão dinâmica durante o intervalo analisado. Os dados destas sondas espaciais em conjunto com os da sonda Vega 1 foram usados para determinar o tempo das passagens do lençol de corrente. Com base nos dados das sondas foram calculadas as coordenadas heliográficas retroativas do lençol de corrente na "superfície fonte" dos mapas sinóticos do campo magnético de Hoeksema, 1989. O cálculo retroativo é feito através de um modelo simples de expressão do vento solar com velocidade uniforme, sendo considerada a co-rotação da magnetosfera com o Sol. Este trabalho apresenta os resultados desta comparação e a análise cinemática da origem dos DEs, determinada sob a hipótese que o plasma desconectado de um dado DE afasta-se com velocidade constante do núcleo cometário (Voelzke & Matsuura, 1998) e compara esta análise com outras que

  15. A Comparative Study of the Dust Environment near the Nuclei of Comets 1P/Halley, 19P/Borrelly, 81P/Wild 2 & 9P/Tempel1 (United States)

    Ho, Tra-Mi; Knollenberg, Joerg; Hoekzema, N.; Boice, Daniel; Kuehrt, Ekkehard; Schulz, Rita; Stuewe, J.; Thomas, Nicolas

    There have been four comets imaged by spacecrafts: 19P/Halley (HMC on Giotto); 19P/Borrelly (MICAS on DS1); 81P/Wild 2 (NavCam on Stardust); and 9P/Tempel 1 (MIR & HIR on Deep Impact). This paper presents a comparative studies of the dust emission within the first 30 - 40 km of the nuclei of these four comets. On March 14, 1986, Giotto encountered comet 1P/Halley's nucleus at a distance of 596km carrying the Halley Multicolour Camera (HMC) [1]. Five years later, Deep Space 1 obtained images of the nucleus of comet 19P/Borrelly with the Miniature Integrated Camera and Spectrometer (MICAS) at a closest distance of 2174km [2]. The next cometary flyby occurred when Stardust approached comet 81P/Wild 2 at 236km on January 2, 2004, tracking its nucleus with its optical navigation camera (NavCam) [3]. The latest close encounter occurred in July 4, 2005, when Deep Impact flew by 9P/Tempel 1 at 500km [4] carrying the Medium Resolution Instrument (MIR). Since the nuclei of 1P/Halley, 19P/Borrelly, 81P/Wild 2 and 9P/Tempel 1 have been observed under similar phase angles (108° , 88° , 73° , and 63° , respectively), we can do a comparative analysis of the inner dust environment of these data sets. The inner dust coma morphology, particularly dust jets and broader fans, of these four comets has been investigated by several authors [5]-[8]. We concentrate on the comparative study of their dust emission. The outflow of dust particles is force-free at large radial distance from the comet nucleus. Thus, integrating the intensity Ids [9] around a comet results in constant Ids. However, the integrated intensities of comets 1P/Halley and 19P/Borrelly indicate deviation from the expected behavior within the first 50 km from their nuclei [10]. 1P/Halley's Ids decreases near the nucleus surface whereas comet 19P/Borrelly's Ids increases. But at large distances, they both converge to constant values. These opposite effects in the first 50km indicate that different mechanisms dominate

  16. Fourier transform two-dimensional electronic-vibrational spectroscopy using an octave-spanning mid-IR probe. (United States)

    Gaynor, James D; Courtney, Trevor L; Balasubramanian, Madhumitha; Khalil, Munira


    The development of coherent Fourier transform two-dimensional electronic-vibrational (2D EV) spectroscopy with acousto-optic pulse-shaper-generated near-UV pump pulses and an octave-spanning broadband mid-IR probe pulse is detailed. A 2D EV spectrum of a silicon wafer demonstrates the full experimental capability of this experiment, and a 2D EV spectrum of dissolved hexacyanoferrate establishes the viability of our 2D EV experiment for studying condensed phase molecular ensembles.

  17. Tidal Distortion of the Envelope of an AGB Star IRS 3 near Sgr A{sup *}

    Energy Technology Data Exchange (ETDEWEB)

    Yusef-Zadeh, F.; Royster, M. J.; Roberts, D. A. [Department of Physics and Astronomy, Northwestern University, Evanston, IL 60208 (United States); Wardle, M. [Department of Physics and Astronomy and Research Center for Astronomy, Astrophysics and Astrophotonics, Macquarie University, Sydney NSW 2109 (Australia); Cotton, W.; Kunneriath, D. [National Radio Astronomy Observatory, Charlottesville, VA 22903 (United States); Schödel, R. [Instituto de Astfisica de Andalucia (CSIC), Glorieta de la Astronomia S/N, E-18008 Granada (Spain)


    We present radio and millimeter continuum observations of the Galactic center taken with the Very Large Array (VLA) and ALMA at 44 and 226 GHz, respectively. We detect radio and millimeter emission from IRS 3, lying ∼4.″5 NW of Sgr A*, with a spectrum that is consistent with the photospheric emission from an AGB star at the Galactic center. Millimeter images reveal that the envelope of IRS 3, the brightest and most extended 3.8 μ m Galactic center stellar source, consists of two semicircular dust shells facing the direction of Sgr A*. The outer circumstellar shell, at a distance of 1.6 × 10{sup 4} au, appears to break up into “fingers” of dust directed toward Sgr A*. These features coincide with molecular CS (5–4) emission and a near-IR extinction cloud distributed between IRS 3 and Sgr A*. The NE–SW asymmetric shapes of the IRS 3 shells seen at 3.8 μ m and radio are interpreted as structures that are tidally distorted by Sgr A*. Using the kinematics of CS emission and the proper motion of IRS 3, the tidally distorted outflowing material from the envelope after 5000 yr constrains the distance of IRS 3 to ∼0.7 pc in front of or ∼0.5 pc behind Sgr A*. This suggests that the mass loss by stars near Sgr A* can supply a reservoir of molecular material near Sgr A*. We also present dark features in radio continuum images coincident with the envelope of IRS 3. These dusty stars provide examples in which high-resolution radio continuum images can identify dust-enshrouded stellar sources embedded in an ionized medium.

  18. The FT-IR spectrometric analysis of the changes of polyphenol oxidase II secondary structure (United States)

    Shi, Chunhua; Dai, Ya; Liu, Qingliang; Xie, Yongshu; Xu, Xiaolong


    Polyphenol oxidase II is a novel protein purified from tobacco, which acts as a key role in plant defense system. From the analysis of FT-IR spectrums, Fourier self-deconvolution (FSD) spectrums and second-derivative spectrums of PPO II at different pH and peroxide PPO II adduct, the secondary structure fractions are analyzed. PPO II at low pH (pH=3.0) and peroxide PPO II adduct almost keep the same secondary structure of native PPO II. The percentages of β-turn and random coil increase rapidly and the percentages of α-helix and anti-parallel β-sheet decrease rapidly at high pH (pH=10.0) comparing with that of native PPO II. All these conclusions are proved by the secondary structure calculations of circular dichroism spectrums in different states.

  19. 30 years of the Vega mission: Comparison of some properties of the 1P/Halley and 67P/Churyumov-Gerasimenko comets (United States)

    Ksanfomality, L. V.


    On March 6 and 9, 1986, for the first time in the history of science, the Russian spacecraft Vega-1 and Vega-2 approached and closely passed by the nucleus of Halley’s comet (1P/Halley). A few days later, on March 14, 1986, the same was done by the European Space Agency’s (ESA) Giotto spacecraft. These missions, together with the Japanese Suisei (JAXA), marked a successful start to spacecraft exploration of cometary nuclei. Subsequent missions to other comets have been aimed at directly studying cometary bodies carrying signs of the formation of the Solar System. The Rosetta spacecraft, inserted into a low orbit around the nucleus of the 67P/Churyumov-Gerasimenko comet, performed its complex measurements from 2014 to September 2016. In this review, some of the data from these missions are compared. The review draws on the proceedings of the Vega 30th anniversary conference held at the Space Research Institute (IKI) of the Russian Academy of Sciences in March 2016 and is not meant to be exhaustive in describing mission results and problems in the physics of comets.

  20. Comparison of some characteristics of comets 1P/Halley and 67P/Churyumov-Gerasimenko from the Vega and Rosetta mission data (United States)

    Ksanfomality, L. V.


    On March 6 and 9, 1986, for the first time in the history of science, the Russian spacecraft Vega-1 and -2 approached the nucleus of comet 1P/Halley and flew by at a small distance. A while later, on March 14, 1986, the Giotto spacecraft (European Space Agency (ESA)) followed them. Together with the Japanese spacecraft Suisei (Japan Aerospace Exploration Agency (JAXA)), they obtained spaceborne investigations of cometary nuclei. Direct studies of cometary bodies that bear traces of the Solar System formation were continued in the next missions to comets. Starting from 2014 and up to 2016 September, the Rosetta spacecraft (ESA), being in a low orbit around the nucleus of comet 67P/Churyumov-Gerasimenko, has performed extremely sophisticated investigations of this comet. Here, we compare some results of these missions. The paper is based on the reports presented at the memorial conference dedicated to the 30th anniversary of the Vega mission, which took place at the Space Research Institute of the Russian Academy of Sciences in March, 2016, and does not pretend to comprehensively cover the problems of cometary physics.

  1. Solid CO_2 towards NGC7538 IRS1 (United States)

    Strazzulla, G.; Nisini, B.; Leto, G.; Palumbo, M. E.; Saraceno, P.


    We report the observation of the young infrared source NGC7538 IRS1 with the Short Wavelength Spectrometer (SWS) onboard the ISO satellite in the 2.4-45 mu m range. The spectrum exhibits several absorption features due to silicates and to molecular species frozen on the refractory dust. In particular the stretching and bending mode of solid CO_2 have been identified. In this paper we present a comparison of the observed absorption band at about 15.1 mu m (660 cm(-1) ) attributed to the bending mode of solid CO_2 with laboratory spectra of ion irradiated ice mixtures. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, the Netherlands and the United Kingdom) with the participation of ISAS and NASA.

  2. IR aperture measurement at β*=40 cm

    CERN Document Server

    Bruce, Roderik; Hermes, Pascal Dominik; Kwee-Hinzmann, Regina; Mereghetti, Alessio; Mirarchi, Daniele; Redaelli, Stefano; Salvachua Ferrando, Belen Maria; Skowronski, Piotr Krzysztof; Valentino, Gianluca; Valloni, Alessandra; CERN. Geneva. ATS Department


    This note summarizes MD 307, performed on August 27 2015, during which we measured with beam the global apertures at 6.5 TeV with IR1 and IR5 squeezed to β* =40 cm and a half crossing angle of 205 rad. The measurement technique involved opening collimators in steps, while inducing beam losses at each step, until the main loss location moved from the collimators to the global bottleneck in one of the triplets. Measurements were performed in both beams and planes, and each measurement gave the minimum triplet aperture over IR1 and IR5. The results are in very good agreement with theoretical predictions. At the end of the MD, an asynchronous beam dump test was performed with all collimators moved in to so-called 2-σ retraction settings. This MD is one in a series meant to address various open points for the reach in β* in Run II.

  3. Looking at Art in the IR and UV (United States)

    Falco, Charles


    Starting with the very earliest cave paintings art has been created to be viewed by the unaided eye and, until very recently, it wasn't even possible to see it at wavelengths outside the visible spectrum. However, it is now possible to view paintings, sculptures, manuscripts, and other cultural artifacts at wavelengths from the x-ray, through the ultraviolet (UV), to well into the infrared (IR). Further, thanks to recent advances in technology, this is becoming possible with hand-held instruments that can be used in locations that were previously inaccessible to anything but laboratory-scale image capture equipment. But, what can be learned from such ``non-visible'' images? In this talk I will briefly describe the characteristics of high resolution UV and IR imaging systems I developed for this purpose by modifying high resolution digital cameras. The sensitivity of the IR camera makes it possible to obtain images of art ``in situ'' with standard museum lighting, resolving features finer than 0.35 mm on a 1.0x0.67 m painting. I also have used both it and the UV camera in remote locations with battery-powered illumination sources. I will illustrate their capabilities with images of various examples of Western, Asian, and Islamic art in museums on three continents, describing how these images have revealed important new information about the working practices of artists as famous as Jan van Eyck. I also will describe what will be possible for this type of work with new capabilities that could be developed within the next few years. This work is based on a collaboration with David Hockney, and benefitted from image analys research supported by ARO grant W911NF-06-1-0359-P00001.

  4. Nuclear Data Sheets for 179Ir (United States)

    Baglin, Coral M.


    Nuclear structure data pertaining to 179Ir have been compiled and evaluated, and incorporated into the ENSDF data file. This evaluation of 179Ir supersedes the previous publication (C. Baglin, Nuclear Data Sheets 72,617 (1994) (literature cutoff date September 1994)), and includes literature available by 8 October 1998. The newly incorporated references are: 96Ji04 (which supersedes 93JiZW), 95Au04, 95Bi01 and 94Mu18.

  5. On IR solutions in Horava gravity theories


    Nastase, Horatiu


    In this note we search for large distance solutions of Horava gravity. In the case of the "detailed balance" action, gravity solutions asymptote to IR only above the cosmological constant ($\\sim$horizon) scale. However, if one adds IR dominant terms $\\alpha R^{(3)}+\\beta \\Lambda_W$, one can recover general relativity solutions on usual scales in the real Universe, provided one fine-tunes the cosmological constant, reobtaining the usual cosmological constant problem. We comment on pp wave solu...

  6. Octave-spanning coherent mid-IR generation via adiabatic difference frequency conversion. (United States)

    Suchowski, Haim; Krogen, Peter R; Huang, Shu-Wei; Kärtner, Franz X; Moses, Jeffrey


    We demonstrate efficient downconversion of a near-IR broadband optical parametric chirped pulse amplifier (OPCPA) pulse to a 1.1-octave-spanning mid-IR pulse (measured at -10 dB of peak) via a single nonlinearly and adiabatically chirped quasi-phase-matching grating in magnesium oxide doped lithium niobate. We report a spectrum spanning from 2 to 5 μm and obtained by near full photon number conversion of μJ-energy OPCPA pulses spanning 680-870 nm mixed with a narrowband 1047-nm pulse. The conversion process is shown to be robust for various input broadband OPA pulses and suitable for post-amplification conversion for many near-IR systems.

  7. The study of chromium borate CrBO3 by optical and IR spectroscopy (United States)

    Molchanova, A. D.; Dobretsova, E. A.; Kuzmin, N. N.; Boldyrev, K. N.


    A complex study of the CrBO3 single crystal has been performed by optical and IR spectroscopy methods over a broad temperature range. Factor-group and correlation analyses of the phonon modes are presented. All IR active phonons and their frequencies are experimentally identified by way of attenuated total reflectance. A magnetic phase transition at a temperature of 6 K is detected. In the magnetically ordered state, an anisotropy of the optical spectrum was observed during polarization studies in the isotropic ab-plane of the crystal. A study of the temperature dependences of the phonon spectrum did not show any anomalies over the course of magnetic ordering, which indicates that there is an absence of an appreciable spin-lattice interaction in CrBO3.

  8. Narcissus analysis for cooled staring IR system (United States)

    He, Feng-Yun; Cui, Ji-Cheng; Feng, Shu-Long; Zhang, Xin


    Narcissus can have a deleterious effect on image quality for cooled infrared imaging systems. Therefore, analysis of narcissus is important for designing both scanning and staring optics. Narcissus is generally assumed to be negligible in staring IR optical designs because the shading effects can be removed by calibration of the detector array data. However, the calibration usually decreases sensitiveness of the system and Narcissus variation may be noticeable for sensors when the conditions changes as follows: 1. warming and cooling the optical housing, 2. zooming optical elements, 3. movement of lenses for focus. In that case, it will result in shading and other image defects even after calibration. To minimize these effects, narcissus should be assessed and controlled during the design of staring array IR system. We provided a direct and fast method for analyzing the narcissus variation in the presence of software such as LightTools, TracePro and ASAP, and proposed the principles in optical design of staring IR systems to reduce narcissus. A cooled staring IR system with serious narcissus was estimated and reoptimized. Narcissus analysis of this IR system confirmed the efficiency of the analysis method.

  9. Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+ for catalytic water oxidation

    NARCIS (Netherlands)

    Dzik, W.I.; Calvo, S.E.; Reek, J.N.H.; Lutz, M.; Ciriano, M.A.; Tejel, C.; Hetterscheid, D.G.H.; de Bruin, B.


    The binuclear iridium complex [(cod)(Cl)Ir(bpi)Ir(cod)]PF6 (bpi = (pyridin-2-ylmethyl)(pyridin-2-ylmethylene)amine; cod = 1,5-cyclooctadiene) reveals a noteworthy asymmetric binuclear coordination geometry, wherein the bpi ligand acts as a heteroditopic ligand and has an unusual π-coordinated imine

  10. Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+ for Catalytic Water Oxidation

    NARCIS (Netherlands)

    Dzik, W.I.; Calvo, S.E.; Reek, J.N.H.; Lutz, M.; Ciriano, M.A.; Tejel, C.; Hetterscheid, D.G.H.; de Bruin, B.


    The binuclear iridium complex [(cod)(Cl)Ir(bpi)Ir(cod)]PF6 (bpi = (pyridin-2-ylmethyl)(pyridin-2-ylmethylene)amine; cod = 1,5-cyclooctadiene) reveals a noteworthy asymmetric binuclear coordination geometry, wherein the bpi ligand acts as a heteroditopic ligand and has an unusual π-coordinated imine

  11. Single-nucleotide polymorphism of INS, INSR, IRS1, IRS2, PPAR-G ...

    Indian Academy of Sciences (India)

    Polycystic ovary syndrome (PCOS) is the most common and a complex female endocrine disorder, and is one of the leading cause of female infertility. Here, we aimed to investigate the association of single-nucleotide polymorphism of INS, INSR, IRS1, IRS2, PPAR-G and CAPN10 gene in the pathogenesis of PCOS.

  12. Single-nucleotide polymorphism of INS, INSR, IRS1, IRS2, PPAR-G ...

    Indian Academy of Sciences (India)


    Taylor 1997). Levels of both IRS-1 and IRS-2 are increased in theca cells of women with PCOS, which leads to proliferation and increased androgen synthe- sis (Yen et al. 2004). The Ala variant of rs1801282 of PPAR-G gene ...

  13. Intelligent multi-spectral IR image segmentation (United States)

    Lu, Thomas; Luong, Andrew; Heim, Stephen; Patel, Maharshi; Chen, Kang; Chao, Tien-Hsin; Chow, Edward; Torres, Gilbert


    This article presents a neural network based multi-spectral image segmentation method. A neural network is trained on the selected features of both the objects and background in the longwave (LW) Infrared (IR) images. Multiple iterations of training are performed until the accuracy of the segmentation reaches satisfactory level. The segmentation boundary of the LW image is used to segment the midwave (MW) and shortwave (SW) IR images. A second neural network detects the local discontinuities and refines the accuracy of the local boundaries. This article compares the neural network based segmentation method to the Wavelet-threshold and Grab-Cut methods. Test results have shown increased accuracy and robustness of this segmentation scheme for multi-spectral IR images.

  14. Spitzer IRS spectroscopy of planetary nebulae (United States)

    Ramos-Larios, G.; Guerrero, M. A.; Mata, H.; Fang, X.; Nigoche-Netro, A.; Toalá, J. A.; Rubio, G.


    We present Spitzer Space Telescope archival mid-infrared (mid-IR) spectroscopy of a sample of eleven planetary nebulae (PNe). The observations, acquired with the Spitzer Infrared Spectrograph (IRS), cover the spectral range 5.2-14.5 μm that includes the H2 0-0 S(2) to S(7) rotational emission lines. This wavelength coverage has allowed us to derive the Boltzmann distribution and calculate the H2 rotational excitation temperature (Tex). The derived excitation temperatures have consistent values ~= 900 +/-70 K for different sources despite their different structural components. We also report the detection of mid-IR ionic lines of [Ar III], [S IV], and [Ne II] in most objects, and polycyclic aromatic hydrocarbon (PAH) features in a few cases.

  15. Autism Spectrum Disorder (United States)

    Autism spectrum disorder (ASD) is a neurological and developmental disorder that begins early in childhood and lasts throughout a person's life. ... be known as Asperger syndrome and pervasive developmental disorders. It is called a "spectrum" disorder because people ...

  16. Venus - The 17- to 38-micron spectrum. [atmospheric thermal emission spectrum (United States)

    Reed, R. A.; Forrest, W. J.; Houck, J. R.; Pollack, J. B.


    A far-IR emission spectrum of Venus covering the wavelength range from 17 to 38 microns is examined which was obtained on five nights at an altitude of 14 km with the 30-cm telescope of the NASA Lear Jet. The spectrum is found to be characterized by an overall continuum level with noticeable absorption shortward of 20 microns and longward of 30 microns as compared with a 245-K blackbody. The continuum level is taken as implying a continuous source of opacity in the Venusian atmosphere over the entire range from 17 to 38 microns with increased opacity shortward of 20 microns and longward of 30 microns. It is shown that a haze of sulfuric acid droplets can provide the necessary opacity and explain the observed depressions. A pressure level of roughly 200 mb is deduced for this spectrum.

  17. Temperature dependent equilibrium native to unfolded protein dynamics and properties observed with IR absorption and 2D IR vibrational echo experiments. (United States)

    Chung, Jean K; Thielges, Megan C; Bowman, Sarah E J; Bren, Kara L; Fayer, M D


    Dynamic and structural properties of carbonmonoxy (CO)-coordinated cytochrome c(552) from Hydrogenobacter thermophilus (Ht-M61A) at different temperatures under thermal equilibrium conditions were studied with infrared absorption spectroscopy and ultrafast two-dimensional infrared (2D IR) vibrational echo experiments using the heme-bound CO as the vibrational probe. Depending on the temperature, the stretching mode of CO shows two distinct bands corresponding to the native and unfolded proteins. As the temperature is increased from low temperature, a new absorption band for the unfolded protein grows in and the native band decreases in amplitude. Both the temperature-dependent circular dichroism and the IR absorption area ratio R(A)(T), defined as the ratio of the area under the unfolded band to the sum of the areas of the native and unfolded bands, suggest a two-state transition from the native to the unfolded protein. However, it is found that the absorption spectrum of the unfolded protein increases its inhomogeneous line width and the center frequency shifts as the temperature is increased. The changes in line width and center frequency demonstrate that the unfolding does not follow simple two-state behavior. The temperature-dependent 2D IR vibrational echo experiments show that the fast dynamics of the native protein are virtually temperature independent. In contrast, the fast dynamics of the unfolded protein are slower than those of the native protein, and the unfolded protein fast dynamics and at least a portion of the slower dynamics of the unfolded protein change significantly, becoming faster as the temperature is raised. The temperature dependence of the absorption spectrum and the changes in dynamics measured with the 2D IR experiments confirm that the unfolded ensemble of conformers continuously changes its nature as unfolding proceeds, in contrast to the native state, which displays a temperature-independent distribution of structures. © 2011

  18. Effect of IRS4 levels on PI 3-kinase signalling.

    Directory of Open Access Journals (Sweden)

    Gerta Hoxhaj

    Full Text Available Insulin receptor substrate 1 (IRS1 and IRS2 are well-characterized adapter proteins that relay signals from receptor tyrosine kinases to downstream components of signalling pathways. In contrast, the function of IRS4 is not well understood. IRS4 overexpression has been associated with acute lymphoblastic leukaemia and subungual exostosis, while point mutations of IRS4 have been found in melanomas. Here, we show that while IRS4 expression is low in most cancer cell lines, IRS4 mRNA and protein levels are markedly elevated in certain cells including the NCI-H720, DMS114, HEK293T and HEK293AAV lines. Surprisingly, IRS4 expression was also strongly induced when HEK293 cells were infected with retroviral particles and selected under puromycin, making IRS4 expression a potential off-target effect of retroviral expression vectors. Cells with high expression of IRS4 displayed high phosphatidylinositol (3,4,5-trisphosphate (PIP3 levels, as well as elevated Akt and p70 S6 kinase activities, even in the absence of growth factors. PI 3-kinase (PI3K signalling in these cells depends on IRS4, even though these cells also express IRS1/2. Knockdown of IRS4 also inhibited cell proliferation in cells with high levels of IRS4. Together, these findings suggest IRS4 as a potential therapeutic target for cancers with high expression of this protein.

  19. Effect of IRS4 Levels on PI 3-Kinase Signalling (United States)

    Hoxhaj, Gerta; Dissanayake, Kumara; MacKintosh, Carol


    Insulin receptor substrate 1 (IRS1) and IRS2 are well-characterized adapter proteins that relay signals from receptor tyrosine kinases to downstream components of signalling pathways. In contrast, the function of IRS4 is not well understood. IRS4 overexpression has been associated with acute lymphoblastic leukaemia and subungual exostosis, while point mutations of IRS4 have been found in melanomas. Here, we show that while IRS4 expression is low in most cancer cell lines, IRS4 mRNA and protein levels are markedly elevated in certain cells including the NCI-H720, DMS114, HEK293T and HEK293AAV lines. Surprisingly, IRS4 expression was also strongly induced when HEK293 cells were infected with retroviral particles and selected under puromycin, making IRS4 expression a potential off-target effect of retroviral expression vectors. Cells with high expression of IRS4 displayed high phosphatidylinositol (3,4,5)-trisphosphate (PIP3) levels, as well as elevated Akt and p70 S6 kinase activities, even in the absence of growth factors. PI 3-kinase (PI3K) signalling in these cells depends on IRS4, even though these cells also express IRS1/2. Knockdown of IRS4 also inhibited cell proliferation in cells with high levels of IRS4. Together, these findings suggest IRS4 as a potential therapeutic target for cancers with high expression of this protein. PMID:24039912

  20. Encapsulated thermopile detector array for IR microspectrometer

    NARCIS (Netherlands)

    Wu, H.; Emadi, A.; De Graaf, G.; Wolffenbuttel, R.F.


    The miniaturized IR spectrometer discussed in this paper is comprised of: slit, planar imaging diffraction grating and Thermo-Electric (TE) detector array, which is fabricated using CMOS compatible MEMS technology. The resolving power is maximized by spacing the TE elements at an as narrow as

  1. IR and OLAP in XML document warehouses

    DEFF Research Database (Denmark)

    Perez, Juan Manuel; Pedersen, Torben Bach; Berlanga, Rafael


    In this paper we propose to combine IR and OLAP (On-Line Analytical Processing) technologies to exploit a warehouse of text-rich XML documents. In the system we plan to develop, a multidimensional implementation of a relevance modeling document model will be used for interactively querying...

  2. IR sensors and imagers in networked operations (United States)

    Breiter, Rainer; Cabanski, Wolfgang


    "Network-centric Warfare" is a common slogan describing an overall concept of networked operation of sensors, information and weapons to gain command and control superiority. Referring to IR sensors, integration and fusion of different channels like day/night or SAR images or the ability to spread image data among various users are typical requirements. Looking for concrete implementations the German Army future infantryman IdZ is an example where a group of ten soldiers build a unit with every soldier equipped with a personal digital assistant (PDA) for information display, day photo camera and a high performance thermal imager for every unit. The challenge to allow networked operation among such a unit is bringing information together and distribution over a capable network. So also AIM's thermal reconnaissance and targeting sight HuntIR which was selected for the IdZ program provides this capabilities by an optional wireless interface. Besides the global approach of Network-centric Warfare network technology can also be an interesting solution for digital image data distribution and signal processing behind the FPA replacing analog video networks or specific point to point interfaces. The resulting architecture can provide capabilities of data fusion from e.g. IR dual-band or IR multicolor sensors. AIM has participated in a German/UK collaboration program to produce a demonstrator for day/IR video distribution via Gigabit Ethernet for vehicle applications. In this study Ethernet technology was chosen for network implementation and a set of electronics was developed for capturing video data of IR and day imagers and Gigabit Ethernet video distribution. The demonstrator setup follows the requirements of current and future vehicles having a set of day and night imager cameras and a crew station with several members. Replacing the analog video path by a digital video network also makes it easy to implement embedded training by simply feeding the network with

  3. Scanning tunneling microscopy and spectroscopy study of the patchwork structure in Pt doped IrTe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Fujisawa, Y., E-mail: [Department of Physics, Tokyo University of Science, Shinjuku, Tokyo 162-8601 (Japan); Machida, T. [RIKEN Center for Emergent Matter Science, Wako, Saitama 351-0198 (Japan); Igarashi, K.; Kaneko, A. [Department of Physics, Tokyo University of Science, Shinjuku, Tokyo 162-8601 (Japan); Mochiku, T.; Ooi, S.; Tachiki, M.; Komori, K.; Hirata, K. [Superconducting Materials Center, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Sakata, H. [Department of Physics, Tokyo University of Science, Shinjuku, Tokyo 162-8601 (Japan)


    Highlights: • We performed STS measurements on patchwork structure in Ir{sub 0.93}Pt{sub 0.07}Te{sub 2}. • Patchwork structure has similar electronic features to those of IrTe{sub 2}. • Patchwork structure is caused by strain due to the dopant Pt. - Abstract: We report on the scanning tunneling microscopy (STM) and spectroscopy (STS) study on a newly discovered superconductor, Ir{sub 1−x}Pt{sub x}Te{sub 2}. We previously found that the sample which shows superconductivity forms so called “patchwork structure (PS)”. To obtain the spatial evolution of electronic structure on the PS, we performed STM/STS measurements on the PS. STS measurements revealed that an averaged spectrum shows the same energy asymmetry as that in the low temperature phase in the parent material, IrTe{sub 2}. Furthermore, the spectrum at the trough on the PS is more asymmetric than that at the crest. This tendency is similar to that observed on the supermodulation in the low temperature phase in IrTe{sub 2}.

  4. Metal-Mesh Optical Filter Technology for Mid IR, Far IR, and Submillimeter Project (United States)

    National Aeronautics and Space Administration — The innovative, high transmission band-pass filter technology proposed here is an improvement in multilayer metal-mesh filter design and manufacture for the far IR...

  5. Metal-Mesh Optical Filter Technology for Mid IR, Far IR, and Submillimeter Project (United States)

    National Aeronautics and Space Administration — This SBIR Phase I proposal describes a method of fabrication of far IR and THZ range multilayer metal-mesh filters. This type of filter consists of alternative...

  6. Vilniaus universiteto medicinos ir filosofijos studentų požiūrio į eutanaziją ir jos įteisinimą Lietuvoje tyrimas ir vertinimas


    Markevič, Artur Adam


    Vilniaus universiteto medicinos ir filosofijos studentų požiūrio į eutanaziją ir jos įteisinimą Lietuvoje tyrimas ir vertinimas Apie eutanaziją Europoje kalbama vis dažniau. Nėra paprasta vertinti eutanaziją, kadangi šis reiškinys paliečia skirtingus aspektus. Lietuvoje kai kurie politikai stengiasi įteisinti aktyvią savanoriškos eutanazijos formą. Skirtingų sričių specialistai ir visuomenės nariai diskutuoja apie skirtingus eutanazijos aspektus ir jos įteisinimą. Nemažai svarbi yra jaunosios...

  7. Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

    KAUST Repository

    Wu, B. L.


    Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

  8. Tax-deferred annuity plans: meeting the IRS audit challenge. (United States)

    Schussler, M


    A growing number of nonprofit organizations are being fined for violations of IRS regulations following IRS audits of their tax-deferred annuity (TDA) plans. To ensure that their organizations can withstand the scrutiny of an IRS audit, TDA plan administrators must ensure that plans meet IRS regulations and be prepared for IRS audits. Documentation--particularly of the TDA plan itself, and procedures related to salary reduction programs, compensation limits, excess deferrals and other excess contributions, loans, and distributions--must be comprehensive and in compliance with IRS regulations.

  9. Perfect Blackbody Spectra for JWST and Next Generation UV-Opt-IR Standard Star Network (United States)

    Suzuki, Nao


    We propose to observe 18-19th magnitude objects with nearly perfect blackbody spectra discovered by the Sloan Digital Sky Survey. Follow-up observation by Keck/LRIS and Subaru/FOCAS confirmed no signs of absorption lines, and SDSS multi-epoch observation shows no time variation. With WFC3 (UVES/IR), we will establish a new network of Opt-IR Standards at 0.1% precision in magnitude from 0.1 micron through 5 micron. The identify of these objects are yet to be known. We conduct precise parallax measurements and find distances to these objects that enables us to infer the radius of these stars, and we may have a potential discovery of new type of objects.Only two parameters (Effective Temperature and Normlization) are needed to describe the blackbody spectra, and we can predict magnitudes in any band from UV through IR with high precision. We will advance the way we peform the photometry by introducing the covariance matrix between the filter bands. This covariance matrix would reduce the errors in color and propagate systematic errors in an appropriate way, and we can reduce the systematic errors in SNIa cosmology today. The perfect blackbody spectrum is the most elegant solution for JWST photometric standards and next generation UV-Opt-IR photometry.

  10. VizieR Online Data Catalog: IR-bright MSX sources in the SMC with Spitzer/IRS (Kraemer+, 2017) (United States)

    Kraemer, K. E.; Sloan, G. C.; Wood, P. R.; Jones, O. C.; Egan, M. P.


    Our original set of infrared spectra of MSX SMC sources was obtained in Spitzer Cycle 1 (Program ID 3277, P.I. M. Egan). This program included 35 targets from the MSX SMC catalog. 24 targets were discussed in previous papers; this paper examines the remaining 11 sources in the sample. We also selected 4 objects in the MSX SMC catalog with similar photometric characteristics in an effort to uncover additional sources with crystalline dust. We observed these targets in Spitzer Cycle 3 (Program ID 30355, P.I. J. Houck). See tables 1 and 2 for observation data and basic properties of the targets. Table 3 lists 20 additional MSX SMC sources that were observed by other Spitzer IRS programs. Overall, 59 MSX SMC sources were observed with the IRS. The spectra were observed using the low-resolution modules of the IRS, Short-Low (SL) and Long-Low (LL), which provided spectra in the 5-14 and 14-37um ranges, respectively, at a resolution between ~60 and 120. For 10 evolved stars with oxygen-rich dust in our Cycle 1 program, we obtained spectra from 0.45 to 1.03um with the Double-Beam Spectrograph at the 2.3m telescope of the Australian National University at Siding Spring Observatory. A 0.45-0.89um spectrum for one of the stars in program 30355 was also observed. These spectra have a resolution of 10Å. Tables 5-7: catalog based on the 243 sources detected in the MSX survey of the SMC, updated with positions and photometry from more recent space-based missions and ground-based surveys. See the Appendix section for more details. The SMC catalog from MSX consists of the 243 sources in the main MSX catalog (Egan+ 2003, see V/114) that lie within the region 7°

  11. Tumor diagnostics using fiber optical IR spectroscopy (United States)

    Winter, Harald; Bindig, Uwe; Waesche, Wolfgang; Liebold, K.; Roggan, Andre; Frege, P.; Gross, U. M.; Mueller, G.


    Aim of the project is the development of an in vivo endoscopic method to differentiate between cancerous from healthy tissue. The method is based on IR spectra in which each diseased state of the tissue has its own characteristic pattern as already shown in previous experiments. Two regions (1245 - 1195) cm-1 and (1045 - 995) cm-1 within the fingerprint (less than 1500 cm-1) region were selected for analysis. This paper will present the technical design of the laboratory set up and outcome of the development as well as the experiments. Two lead-salt diode lasers were used as excitation sources. The IR-radiation was transmitted via silverhalide fibers to the tissue to be investigated. On the detection side another IR fiber was used to transmit the signal to an MCT-detector (Mercury-Cadmium-Telluride). Measurement modes are Attenuated Total Reflectance (ATR) and diffuse Reflection/Remission. Spatial resolution was 100 X 100 micrometer2. The tissue used for these experiments was human colon carcinoma under humidity conditions. Samples were mapped using a stepper motor powered x/y/z-translation stage with a resolution of 1 micrometer. Results were compared with measurements carried out using a FTIR-interferometer and an FTIR-microscope in the region from 4000 - 900 cm-1. Soft- and Hardware control of the experiment is done using Labwindows/CVI (National Instruments, USA).

  12. ODYSSEY THEMIS IR PBT V2.0 (United States)

    National Aeronautics and Space Administration — The THEMIS IR-PBT data set contains the spatially registered, infrared brightness temperature images derived from the projected radiance (IR-GEO) products. Each...

  13. Supplemental Security Income (SSI) / Internal Revenue Service (IRS) 1099 (United States)

    Social Security Administration — A finder file from SSA's Title XVI database is provided to the IRS. The IRS discloses 1099 information to SSA for use in verifying eligibility, amount, and benefits...

  14. Expression of insulin receptor (IR) A and B isoforms, IGF-IR, and IR/IGF-IR hybrid receptors in vascular smooth muscle cells and their role in cell migration in atherosclerosis. (United States)

    Beneit, N; Fernández-García, C E; Martín-Ventura, J L; Perdomo, L; Escribano, Ó; Michel, J B; García-Gómez, G; Fernández, S; Díaz-Castroverde, S; Egido, J; Gómez-Hernández, A; Benito, M


    Abnormal proliferation and migration of vascular smooth muscle cells (VSMCs) is a major contributor to the development of atherosclerotic process. In a previous work, we demonstrated that the insulin receptor isoform A (IRA) and its association with the insulin-like growth factor-I receptor (IGF-IR) confer a proliferative advantage to VSMCs. However, the role of IR and IGF-IR in VSMC migration remains poorly understood. Wound healing assays were performed in VSMCs bearing IR (IRLoxP+/+ VSMCs), or not (IR-/- VSMCs), expressing IRA (IRA VSMCs) or expressing IRB (IRB VSMCs). To study the role of IR isoforms and IGF-IR in experimental atherosclerosis, we used ApoE-/- mice at 8, 12, 18 and 24 weeks of age. Finally, we analyzed the mRNA expression of total IR, IRB isoform, IGF-IR and IGFs by qRT-PCR in the medial layer of human aortas. IGF-I strongly induced migration of the four cell lines through IGF-IR. In contrast, insulin and IGF-II only caused a significant increase of IRA VSMC migration which might be favored by the formation of IRA/IGF-IR receptors. Additionally, a specific IGF-IR inhibitor, picropodophyllin, completely abolished insulin- and IGF-II-induced migration in IRB, but not in IRA VSMCs. A significant increase of IRA and IGF-IR, and VSMC migration were observed in fibrous plaques from 24-week-old ApoE-/- mice. Finally, we observed a marked increase of IGF-IR, IGF-I and IGF-II in media from fatty streaks as compared with both healthy aortas and fibrolipidic lesions, favoring the ability of medial VSMCs to migrate into the intima. Our data suggest that overexpression of IGF-IR or IRA isoform, as homodimers or as part of IRA/IGF-IR hybrid receptors, confers a stronger migratory capability to VSMCs as might occur in early stages of atherosclerotic process.

  15. Near-IR Spectral Variability of Be Stars (United States)

    Cole, Austin; Eisner, J. A.; Rudolph, A. L.


    Be class stars exhibit variability across the electromagnetic spectrum, including in both the visible and infrared regions. While variability in the optical range has been explored previously, spectroscopic variability in the near-IR has not been investigated as thoroughly. This study is focused on tracking the spectral variability of K Dra, one of the Be stars for which we collected data. We observed our sample using the FSPEC instrument on the 90-inch Bok telescope at Kitt Peak. The data were collected during four five-night runs, two in 2010 separated by one month and two in 2011 also separated by one month. A reduction pipeline written in Interactive Data Language (IDL) was used to produce emission spectra of the star from these data. Here we present spectra from these epochs that show emission from the Brackett Gamma hydrogen transition. We use changes in these features to constrain variability in the Hydrogen gas comprising the disk of this star as a function of time.

  16. IGF-IR targeted therapy: Past, present and future

    NARCIS (Netherlands)

    J.A.M.J.L. Janssen (Joseph); A.J. Varewijck (Aimee)


    textabstractThe IGF-I receptor (IGF-IR) has been studied as an anti-cancer target. However, monotherapy trials with IGF-IR targeted antibodies or with IGF-IR specific tyrosine kinase inhibitors have, overall, been very disappointing in the clinical setting. This review discusses potential reasons

  17. Arbitrage Rebate Compliance: Recent IRS Scrutiny of School Districts. (United States)

    Given, Lynda K.; Gurrola, George E.; Richardson, James R.


    Describes rules and procedures school districts must follow to comply with IRS arbitrage and rebate rules and exceptions on profits derived from investing yields of tax-exempt bonds in a higher yielding account. Describes consequences of noncompliance and seven ways to be prepared for an IRS audit--for example, answering the IRS promptly. (PKP)

  18. Supercontinuum based mid-IR imaging spectroscopy for cancer detection

    DEFF Research Database (Denmark)

    Bang, Ole; Møller, Uffe Visbech; Kubat, Irnis


    The mid-infrared (IR) spectral region is of significant technical and scientific interest because most molecules display fundamental vibrational absorptions in this region, leaving distinct spectral fingerprints. To date, the limitations of mid-IR light sources, such as thermal emitters, low...... cancer detection with mid-IR imaging spectroscopy....

  19. IR Cards: Inquiry-Based Introduction to Infrared Spectroscopy (United States)

    Bennett, Jacqueline; Forster, Tabetha


    As infrared spectroscopy (IR) is frequently used in undergraduate organic chemistry courses, an inductive introduction to IR spectroscopy that uses index cards printed with spectra, structures, and chemical names is described. Groups of students are given an alphabetized deck of these "IR cards" to sort into functional groups. The students then…

  20. Global Least-Squares Analysis of the IR Rotation-Vibration Spectrum of HCI (United States)

    Tellinghuisen, Joel


    Several data-analysis problems could be addressed in different ways, ranging from a series of related "local" fitting problems to a single comprehensive "global analysis". The approach has become a powerful one for fitting data to moderately complex models by using library functions and the methods are illustrated for the analysis of HCI-IR…

  1. Detection Method of Skin Region by Near-IR Spectrum Multi-Band (United States)

    Suzuki, Yasuhiro; Yamamoto, Kazuhiko; Kato, Kunihito; Andoh, Michinori; Kojima, Shinichi

    Many active safety technologies for the driver support system are developing. Most of the traffic accidents are caused by driver's inattentive or drowsy. We are developing a driver support system that protects from traffic accidents by these causes. Our purpose is to detect the driver's face region by using a camera. A lot of face detection methods are proposed, but there is not a technique addressing every environment inside the car. For example, skin color segmentation can not detect the skin region in the night, because it has to light up the driver by bright light. In this paper, we propose a skin detection method by the unique reflection characteristics of the materials. Our method is very simple algorithm. We developed a skin detection system, and confirmed effectiveness by the evaluation experiment in indoor environment, and showed the effectiveness by a driving experiment in the night.

  2. 5G Spectrum Sharing


    Nekovee, Maziar; Rudd, Richard


    In this paper an overview is given of the current status of 5G industry standards, spectrum allocation and use cases, followed by initial investigations of new opportunities for spectrum sharing in 5G using cognitive radio techniques, considering both licensed and unlicensed scenarios. A particular attention is given to sharing millimeter-wave frequencies, which are of prominent importance for 5G.

  3. Spectrally resolved confocal microscopy using lanthanide centred near-IR emission. (United States)

    Liao, Zhiyu; Tropiano, Manuel; Mantulnikovs, Konstantins; Faulkner, Stephen; Vosch, Tom; Sørensen, Thomas Just


    The narrow, near infrared (NIR) emission from lanthanide ions has attracted great interest, particularly with regard to developing tools for bioimaging, where the long lifetimes of lanthanide excited states can be exploited to address problems arising from autofluorescence and sample transparency. Despite the promise of lanthanide-based probes for near-IR imaging, few reports on their use are present in the literature. Here, we demonstrate that images can be recorded by monitoring NIR emission from lanthanide complexes using detectors, optical elements and a microscope that were primarily designed for the visible part of the spectrum.

  4. X-ray magnetic circular dichroism at IrL 2, 3 edges in Fe 100- Ir ...

    Indian Academy of Sciences (India)

    3, 10 and 17) and Co100-Ir (=5, 17, 25 and 32) alloys has been investigated by X-ray magnetic circular dichroism (XMCD) at Ir L2,3 absorption edges. Sum rule analysis of the XMCD data show that the orbital moment of Ir is in the range of ...

  5. Types of Research Bias Encountered in IR. (United States)

    Gabr, Ahmed; Kallini, Joseph Ralph; Desai, Kush; Hickey, Ryan; Thornburg, Bartley; Kulik, Laura; Lewandowski, Robert J; Salem, Riad


    Bias is a systemic error in studies that leads to inaccurate deductions. Relevant biases in the field of IR and interventional oncology were identified after reviewing articles published in the Journal of Vascular and Interventional Radiology and CardioVascular and Interventional Radiology. Biases cited in these articles were divided into three categories: preinterventional (health care access, participation, referral, and sample biases), periinterventional (contamination, investigator, and operator biases), and postinterventional (guarantee-time, lead time, loss to follow-up, recall, and reporting biases). Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.

  6. Controlling Hydrogenation of Graphene on Ir(111)

    DEFF Research Database (Denmark)

    Balog, Richard; Andersen, Mie; Jørgensen, Bjarke


    Combined fast X-ray photoelectron spectroscopy and density functional theory calculations reveal the presence of two types of hydrogen adsorbate structures at the graphene/ Ir(111) interface, namely, graphane-like islands and hydrogen dimer structures. While the former give rise to a periodic...... pattern, dimers tend to destroy the periodicity. Our data reveal distinctive growth rates and stability of both types of structures, thereby allowing one to obtain well-defined patterns of hydrogen clusters. The ability to control and manipulate the formation and size of hydrogen structures on graphene...

  7. IR laser ablation of dental enamel (United States)

    Fried, Daniel


    An overview of the basic mechanisms of IR laser ablation of dental enamel is presented. Enamel is a highly structured tissue consisting of an heterogeneous distribution of water, mineral, protein and lipid. Absorption bands of water and carbonated hydroxyapatite can be selectively targeted from 2.7 to 11-micrometer via several laser wavelengths. Mechanistic differences in the nature of ablation and the varying surface morphology produced can be explained by the microstructure of the tissue. Suggested criteria for the choice of the optimum laser parameters for clinical use, the influence of plasma shielding and the role of exogenous water on the mechanism of ablation are discussed.

  8. Ir-192 Plesiocurietherapy using silicone elastomer plates

    Energy Technology Data Exchange (ETDEWEB)

    Michel-Langlet, P.; Housset, M.; Alapetite, C.; Boisserie, G.; Dessard-Diana, B.; Baillet, F.


    Corrective treatment of certain superficial lesions (permeation nodules, budding or ulcerated tumor recurrences, etc.) is sometimes difficult and may, in certain cases, benefit from plesiocurietherapy. A device intended for this purpose which is easy to handle, easy to use and inexpensive is presented: it consists of silicone elastomer plates in which are inserted vector plastic tubes which, like any type of curietherapy, can be used with estimated dosimetry and delayed loading (Ir 192). These flexible plates can be adapted to all anatomical variations and very accurately inserted.

  9. Stringy horizons and UV/IR mixing

    Energy Technology Data Exchange (ETDEWEB)

    Ben-Israel, Roy [Physics Department, Tel-Aviv University Israel,Ramat-Aviv, 69978 (Israel); Giveon, Amit [Racah Institute of Physics, The Hebrew University,Jerusalem, 91904 (Israel); Itzhaki, Nissan; Liram, Lior [Physics Department, Tel-Aviv University Israel,Ramat-Aviv, 69978 (Israel)


    The target-space interpretation of the exact (in α{sup ′}) reflection coefficient for scattering from Euclidean black-hole horizons in classical string theory is studied. For concreteness, we focus on the solvable SL(2,ℝ){sub k}/U(1) black hole. It is shown that it exhibits a fascinating UV/IR mixing, dramatically modifying the late-time behavior of general relativity. We speculate that this might play an important role in the black-hole information puzzle, as well as in clarifying features related with the non-locality of Little String Theory.

  10. FT-IR and FT-NIR Raman spectroscopy in biomedical research (United States)

    Naumann, D.


    FT-IR and FT-NIR Raman spectra of intact microbial, plant animal or human cells, tissues, and body fluids are highly specific, fingerprint-like signatures which can be used to discriminate between diverse microbial species and strains, characterize growth-dependent phenomena and cell-drug interactions, and differentiate between various disease states. The spectral information potentially useful for biomedical characterizations may be distributed over the entire infrared region of the electromagnetic spectrum, i.e. over the near-, mid-, and far-infrared. It is therefore a key problem how the characteristic vibrational spectroscopic information can be systematically extracted from the infrared spectra of complex biological samples. In this report these questions are addressed by applying factor and cluster analysis treating the classification problem of microbial infrared spectra as a model task. Particularly interesting applications arise by means of a light microscope coupled to the FT-IR spectrometer. FT-IR spectra of single microcolonies of less than 40 μm in diameter can be obtained from colony replica applying a stamping technique that transfers the different, spatially separated microcolonies from the culture plate to a special IR-sample holder. Using a computer controlled x,y-stage together with mapping and video techniques, the fundamental tasks of microbiological analysis, namely detection, enumeration, and differentiation of micro-organisms can be integrated in one single apparatus. Since high quality, essentially fluorescence free Raman spectra may now be obtained in relatively short time intervals on previously intractable biological specimens, FT-IR and NIR-FT-Raman spectroscopy can be used in tandem to characterize biological samples. This approach seems to open up new horizons for biomedical characterizations of complex biological systems.

  11. Gallium-doped zinc oxide plasmonic nanostructures for mid-IR applications (Conference Presentation) (United States)

    Dev, Sukrith U.; Look, David C.; Leedy, Kevin D.; Yu, Lan; Walker, Dennis E.; Wenner, Brett R.; Allen, Jeffery W.; Allen, Monica S.; Wasserman, Daniel M.


    The mid-infrared (mid-IR) region of the electromagnetic spectrum has a range of applications in defense, sensing, and free space optical communications. However, most mid-IR sources, particularly incoherent emitters, are practically limited as a result of significant non-radiative losses such as Auger and Shockley-Read-Hall recombination as well as phonon-assisted scattering. Recently, plasmonic materials have been a topic of interest due to their ability to overcome traditional limitations of light confinement as well as enhance light-matter interactions. For inherently inefficient sources, such as many mid-IR emitters, coupling of the emitting element to a plasmonic structure could enhance emission efficiency. In this work, we propose and experimentally evaluate the use of plasmon-mediated photoluminescence as a potential method for improving efficiency in mid-IR emitters. We assess the effectiveness of 3% gallium-doped zinc oxide (G3ZO) as a mid-IR plasmonic material. We design, simulate, fabricate, and characterize a two-dimensional periodic array of bow-tie nanoantennas (nantennas). Our structures are designed to enhance the overlap of the nantenna optical field with underlying In(Ga)Sb/InAs quantum well structures emitting at λ ≈ 4.0μm. Thin films of G3ZO are grown by pulsed laser deposition and are characterized electrically and optically, with the extracted material parameters used as inputs in our simulations. G3ZO plasmonic nantennas are then fabricated by electron-beam lithography and dry-etching. The spectral response of the patterned nantennas is characterized using Fourier transform infrared reflection spectroscopy. Samples are then characterized by temperature and polarization dependent photoluminescence spectroscopy in order to determine the extent to which the emission efficiency improves as a result of coupling to the nanostructures.

  12. Near-IR absorbing phthalocyanine derivatives as materials for organic solar cells (United States)

    Mayukh, Mayank


    Phthalocyanines (Pcs) are highly conjugated synthetic porphyrin analogs that exhibit high extinction coefficients and hole mobilities, and strong pi-pi interactions. We have developed a general method for the synthesis of peripherally functionalized Pc chromophores using 'click' chemistry, wherein an alkynyl substituted Pc is reacted with an azide, providing an elegant route to the creation of a library of numerous Pcs. We have also developed a simple route to the synthesis of tri- and tetravalent metal Pc derivatives such as titanyl phthalocyanine (TiO Pc) involving solvent-free conditions. Solvent-free conditions are environmentally friendly and industrially economical, and in the present context effectively eliminate the formation of non-metallated phthalocyanine (H 2Pc), a side product often seen in other routes that interferes with their purification. We have also prepared and characterized thin-films of some of these Pcs, TiOPcs in particular, wherein we have developed an easy route to various TiO Pc polymorphs exhibiting different near-IR sensitivities via spin-coating whose optical properties are reminiscent of Phase-I and Phase-II polymorphs of the unmodified TiOPc. Phase-II is particularly interesting as it is photoelectrically active in the near-IR region with a Q-band maximum at ca. 890 nm. We have also fabricated and characterized organic solar cells in both planar heterojunction (PHJ) and bulk heterojunction (BHJ) architectures based on one of these materials, which exhibited good near-IR photoactivity with the absorption spectrum extending up to 1 micrometer in the near-IR. The incident and absorbed photon to current efficiency (IPCE and APCE) spectra showed contributions from the TiOPc in the near-IR region with local maxima around 680 nm and 920 nm, corresponding to the Frenkel and the charge-transfer (CT) bands of the TiOPc, respectively.

  13. IR Spectroscopic signs of malignant neoplasms in the thyroid gland (United States)

    Tolstorozhev, G. B.; Skornyakov, I. V.; Butra, V. A.


    We use Fourier transform IR spectroscopy to study thyroid tumor tissues which were removed during surgery. The IR spectra of the tissues with pathological foci are compared with data from histologic examination. In the region of N-H, C-H, and C = O stretching vibrations, the IR spectra of the tissues for thyroid cancer are different from the IR spectra of tissues without malignant formations. We identify the spectral signs of thyroid cancer. We show that IR analysis is promising for identification of thyroid pathology at the molecular level.

  14. Mesoporous silica nanoparticle supported PdIr bimetal catalyst for selective hydrogenation, and the significant promotional effect of Ir

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Hui; Huang, Chao; Yang, Fan [The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China); Yang, Xu [Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou (China); Du, Li [The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China); Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou (China); Liao, Shijun, E-mail: [The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China); Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou (China)


    Graphical abstract: A mesoporous silica nanoparticle (MSN) supported bimetal catalyst, PdIr/MSN, was prepared by a facile impregnation and hydrogen reduction method. The strong promotional effect of Ir was observed and thoroughly investigated. At the optimal molar ratio of Ir to Pd (N{sub Ir}/N{sub Pd} = 0.1), the activity of PdIr{sub 0.1}/MSN was up to eight times and 28 times higher than that of monometallic Pd/MSN and Ir/MSN, respectively. The catalysts were characterized comprehensively by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and hydrogen temperature programmed reduction, which revealed that the promotional effect of Ir may be due to the enhanced dispersion of active components on the MSN, and to the intensified Pd–Ir electronic interaction caused by the addition of Ir. - Highlights: • Mesoporous nanoparticles were synthesized and used as support for metal catalyst. • PdIr bimetallic catalyst exhibited significantly improved hydrogenation activity. • The strong promotion of Ir was recognized firstly and investigated intensively. • PdIr exhibits 18 times higher activity than Pd to the hydrogenation of nitrobenzene. - Abstract: A mesoporous silica nanoparticle (MSN) supported bimetal catalyst, PdIr/MSN, was prepared by a facile impregnation and hydrogen reduction method. The strong promotional effect of Ir was observed and thoroughly investigated. At the optimal molar ratio of Ir to Pd (N{sub Ir}/N{sub Pd} = 0.1), the activity of PdIr{sub 0.1}/MSN was up to eight times and 28 times higher than that of monometallic Pd/MSN and Ir/MSN, respectively. The catalysts were characterized comprehensively by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and hydrogen temperature programmed reduction, which revealed that the promotional effect of Ir may be due to the enhanced dispersion of active components on the MSN, and to the intensified Pd–Ir electronic interaction

  15. Interactions of fish gelatin and chitosan in uncrosslinked and crosslinked with EDC films: FT-IR study (United States)

    Staroszczyk, Hanna; Sztuka, Katarzyna; Wolska, Julia; Wojtasz-Pająk, Anna; Kołodziejska, Ilona


    Films based on fish gelatin, chitosan and blend of fish gelatin and chitosan before and after cross-linking with EDC have been characterized by FT-IR spectroscopy. The FT-IR spectrum of fish gelatin film showed the characteristic amide I, amide II and amide III bands, and the FT-IR spectrum of chitosan film confirmed that the polymer was only a partially deacetylated product, and included CH3sbnd Cdbnd O and NH2 groups, the latter both in their free -NH2 and protonated -NH3+ form. Analysis of FT-IR spectra of two-component, fish gelatin-chitosan film revealed the formation not only of hydrogen bonds within and between chains of polymers, but also of electrostatic interactions between -COO- of gelatin and -NH3+ of chitosan. Modification with EDC provided cross-linking of composites of the film. New iso-peptide bonds formed between activated carboxylic acid groups of glutamic or aspartic acid residue of gelatin and amine groups of gelatin or/and chitosan.

  16. IR-Raman-VCD study of R-(+)-Pulegone: Influence of the solvent (United States)

    Aviles-Moreno, Juan Ramón; Ureña Horno, Elena; Partal Ureña, Francisco; López González, Juan Jesús


    R-(+)-Pulegone is a natural monoterpene obtained from the essential oils of a variety of plants. It is used in flavouring agents, perfumery and aromatherapy. In this work, a study of the molecular structure and the infrared and Raman spectra of this chemical is presented. Theoretical calculations reveal the existence of two conformers depending on the position of the methyl group (axial and equatorial), being the equatorial conformer the most stable. A complete and reliable assignment of the IR and Raman spectra of the title compound is made, and the results are used to carry out a detailed interpretation of the VCD spectrum of this compound in the 4000-900 cm -1 region. Finally, the influence of the solvent in the VCD bands (intensity and sign) has been tested comparing the neat liquid spectrum with the VCD spectra recorded with four solvents.

  17. An IR Navigation System for Pleural PDT. (United States)

    Zhu, Timothy C; Liang, Xing; Kim, Michele M; Finlay, Jarod C; Dimofte, Andreea; Rodriguez, Carmen; Simone, Charles B; Friedberg, Joseph S; Cengel, Keith A


    Pleural photodynamic therapy (PDT) has been used as an adjuvant treatment with lung-sparing surgical treatment for malignant pleural mesothelioma (MPM). In the current pleural PDT protocol, a moving fiber-based point source is used to deliver the light. The light fluences at multiple locations are monitored by several isotropic detectors placed in the pleural cavity. To improve the delivery of light fluence uniformity, an infrared (IR) navigation system is used to track the motion of the light source in real-time at a rate of 20 - 60 Hz. A treatment planning system uses the laser source positions obtained from the IR camera to calculate light fluence distribution to monitor the light fluence uniformity on the surface of the pleural cavity. A novel reconstruction algorithm is used to determine the pleural cavity surface contour. A dual-correction method is used to match the calculated fluences at detector locations to the detector readings. Preliminary data from a phantom shows superior light uniformity using this method. Light fluence uniformity from patient treatments is also shown with and without the correction method.

  18. QWIP and third-generation IR imagers (United States)

    Costard, E.; Bois, Ph.; Marcadet, X.; Nedelcu, A.


    Standard GaAs/AlGaAs Quantum Well Infrared Photodetectors (QWIP) are from now seriously considered for the 3rd generation of IR imagers for military markets. Since 2002, the THALES Group has been manufacturing sensitive arrays using QWIP technology based on AsGa techniques through THALES Research and Technology Laboratory. This QWIP technology allows the realization of large staring arrays for Thermal Imagers (TI) working in the IR band III (8-12 μm). A review of the current QWIP products is presented. In the past researchers claimed many advantages of QWIPs. Uniformity was one of these and is the key parameter for the production start. By presenting our first results of a 640x512 LWIR FPA at a pitch of 20μm we also demonstrate that very high performances can be achieved even with small pixels which opens the field for the realization of usable and affordable megapixel FPAs. Another advantage widely claimed in the past for QWIPs was the so-called band-gap engineering and versatility of the III-V processing allowing the custom design of quantum structure to fulfill the requirements of specific applications like very long wavelength (VLWIR) or multispectral detection. In this presentation, we present the performances of our first 256x256 MWIR / LWIR two color FPA at a pitch of 25 μm, and also the current status of QWIPs for VLWIR arrays (>15μm).

  19. An IR Navigation System for Pleural PDT

    Directory of Open Access Journals (Sweden)

    Timothy C Zhu


    Full Text Available Pleural photodynamic therapy (PDT has been used as an adjuvant treatment with lung-sparing surgical treatment for malignant pleural mesothelioma (MPM. In the current pleural PDT protocol, a moving fiber-based point source is used to deliver the light. The light fluences at multiple locations are monitored by several isotropic detectors placed in the pleural cavity. To improve the delivery of light fluence uniformity, an infrared (IR navigation system is used to track the motion of the light source in real-time at a rate of 20 - 60 Hz. A treatment planning system uses the laser source positions obtained from the IR camera to calculate light fluence distribution to monitor the light dose uniformity on the surface of the pleural cavity. A novel reconstruction algorithm is used to determine the pleural cavity surface contour. A dual-correction method is used to match the calculated fluences at detector locations to the detector readings. Preliminary data from a phantom shows superior light uniformity using this method. Light fluence uniformity from patient treatments is also shown with and without the correction method.

  20. Irène Jacob visits CERN

    CERN Document Server

    CERN Bulletin


    French actress Irène Jacob, the daughter of physicist Maurice Jacob, visited the ATLAS and CMS control rooms on Monday 17 May together with Italian theatre actor-director Pippo Delbono, in search of inspiration for a short film. The film will be screened at the “nuit des particules” event accompanying this year’s ICHEP.   Pippo Delbono et Irène Jacob discussing their project. “La nuit des particules” (night of the particles) is an event open to the general public that is being organised for the evening of Tuesday, 27 July, to accompany the 35th International Conference on High Energy Physics (ICHEP). ICHEP is a major highlight in every physicist’s calendar, and this year’s edition is being held in Paris from 22 to 28 July. The short film will be screened during the evening, which will include a lecture and a show at the legendary Parisian cinema Le Grand Rex, with a colossal seating capacity of 2 700 spe...

  1. An IR Navigation System for Pleural PDT (United States)

    Zhu, Timothy; Liang, Xing; Kim, Michele; Finlay, Jarod; Dimofte, Andreea; Rodriguez, Carmen; Simone, Charles; Friedberg, Joseph; Cengel, Keith


    Pleural photodynamic therapy (PDT) has been used as an adjuvant treatment with lung-sparing surgical treatment for malignant pleural mesothelioma (MPM). In the current pleural PDT protocol, a moving fiber-based point source is used to deliver the light. The light fluences at multiple locations are monitored by several isotropic detectors placed in the pleural cavity. To improve the delivery of light fluence uniformity, an infrared (IR) navigation system is used to track the motion of the light source in real-time at a rate of 20 - 60 Hz. A treatment planning system uses the laser source positions obtained from the IR camera to calculate light fluence distribution to monitor the light dose uniformity on the surface of the pleural cavity. A novel reconstruction algorithm is used to determine the pleural cavity surface contour. A dual-correction method is used to match the calculated fluences at detector locations to the detector readings. Preliminary data from a phantom shows superior light uniformity using this method. Light fluence uniformity from patient treatments is also shown with and without the correction method.

  2. Wafer level test solutions for IR sensors (United States)

    Giessmann, Sebastian; Werner, Frank-Michael


    Wafer probers provide an established platform for performing electrical measurements at wafer level for CMOS and similar process technologies. For testing IR sensors, the requirements are beyond the standard prober capabilities. This presentation will give an overview about state of the art IR sensor probing systems reaching from flexible engineering solutions to automated production needs. Cooled sensors typically need to be tested at a target temperature below 80 K. Not only is the device temperature important but also the surrounding environment is required to prevent background radiation from reaching the device under test. To achieve that, a cryogenic shield is protecting the movable chuck. By operating that shield to attract residual gases inside the chamber, a completely contamination-free test environment can be guaranteed. The use of special black coatings are furthermore supporting the removal of stray light. Typically, probe card needles are operating at ambient (room) temperature when connecting to the wafer. To avoid the entrance of heat, which can result in distorted measurements, the probe card is fully embedded into the cryogenic shield. A shutter system, located above the probe field, is designed to switch between the microscope view to align the sensor under the needles and the test relevant setup. This includes a completely closed position to take dark current measurements. Another position holds a possible filter glass with the required aperture opening. The necessary infrared sources to stimulate the device are located above.

  3. IR1 and IR5 aperture at 3.5 TeV

    CERN Document Server

    Alabau Pons, C; Bruce, R; Giovannozzi, M; Maclean, EH; Mueller, G; Redaelli, S; Schmidt, F; Tomas, R; Wenninger, J


    This note summarises the 3.5 TeV aperture measurements in the interaction regions (IRs) IR1 and IR5. The goal of these measurements is to determine the local aperture in the triplet area with optics squeezed to 1.5 m and nominal crossing and separation bumps in order to determine the β∗ reach. Aperture measurements were performed at injection energy with a different machine optics and with different configurations for crossing and separation schemes. Direct measurements at 3.5 TeV provide better estimates of the aperture in the conditions for physics and will be used for updated estimates of β∗ reach. Based on these measurements, the decision of squeezing β∗ down to 1 m in IR1 and 5 was taken and successfully put in operation for the last part of the 2011 proton physics run, for a peak luminosity reach of more than 3.5 × 1033 cm−2s−1 . Thanks to the larger available aperture, this improvement was achieved with minimum re-commissioning time, i.e. without changing the collimator settings and with...

  4. HOMA1-IR and HOMA2-IR indexes in identifying insulin resistance and metabolic syndrome: Brazilian Metabolic Syndrome Study (BRAMS). (United States)

    Geloneze, Bruno; Vasques, Ana Carolina Junqueira; Stabe, Christiane França Camargo; Pareja, José Carlos; Rosado, Lina Enriqueta Frandsen Paez de Lima; Queiroz, Elaine Cristina de; Tambascia, Marcos Antonio


    To investigate cut-off values for HOMA1-IR and HOMA2-IR to identify insulin resistance (IR) and metabolic syndrome (MS), and to assess the association of the indexes with components of the MS. Nondiabetic subjects from the Brazilian Metabolic Syndrome Study were studied (n = 1,203, 18 to 78 years). The cut-off values for IR were determined from the 90th percentile in the healthy group (n = 297) and, for MS, a ROC curve was generated for the total sample. In the healthy group, HOMA-IR indexes were associated with central obesity, triglycerides and total cholesterol (p 2.7 and HOMA2-IR > 1.8; and, for MS were: HOMA1-IR > 2.3 (sensitivity: 76.8%; specificity: 66.7%) and HOMA2-IR > 1.4 (sensitivity: 79.2%; specificity: 61.2%). The cut-off values identified for HOMA1-IR and HOMA2-IR indexes have a clinical and epidemiological application for identifying IR and MS in Westernized admixtured multi-ethnic populations.

  5. Modeling the vibrational spectrum of 4,4'-diphenylmethane- bis(methyl)carbamate (United States)

    Shundalau, M. B.; Pitsevich, G. A.; Ksenofontov, M. A.; Umreiko, D. S.


    We present results of ab initio calculations of the structure and vibrational IR spectrum for 4,4'-diphenylmethane-bis(methyl)carbamate (DPMC). Calculations were carried out in the HF/6-311G approximation with subsequent force-field scaling. The calculated characteristics of the vibrational spectrum of DPMC show satisfactory agreement with experimental values, which permits them to be used in spectral and structural analysis

  6. Mid-IR Plasmonics, Cavity Coupled Excitations, and IR Spectra of Individual Airborne Particulate Matter (United States)

    Luthra, Antriksh

    With the advances in plasmonics, new fields have evolved involving the mixing of light with various states like Surface Plasmons (SPs), Surface Phonons (SPh), molecular emitters or resonators, and wavelength scale cavities. This work concentrates on the interaction of infrared (IR) light with SPs, cavity modes, and molecular vibrations. In the first chapter, the field of Plasmonics is introduced from a classical and a quantum mechanical perspective and a comparison of both is presented. In Chapter 2, the interaction of cavity modes with vibrations is discussed. Briefly, when IR light is illuminated upon an etalon, its fringes disperse as function of angle. If there is a dielectric in a cavity having a vibrational transition in the fringe region, it leads to a strong interaction that gives rise to a Rabi splitting. Data was obtained from collaborators at the U.S. Naval Research Laboratory (NRL) and a derivation for the dispersion of etalon cavity modes was carried out to model the peak positions of the fringes. In Chapter 3, the excitation of Surface Plasmons Polaritons (SPPs) on metal bi-gratings is discussed. The resonance condition occurs when the momentum of the IR light parallel to the surface plus the grating vector match the momentum of the SPP. Experiments were performed in the GammaX space (ky=0) and the resonance peak positions were modeled with SPP momentum matching equations. In Chapter 4, the application of plasmonics in the mid-IR frequency range that overlaps with the frequencies of molecular vibrations is explored. The plasmonic mesh has interesting optical properties, it focuses more light in the holes and that leads to an enhancement of the IR spectra of a particle trapped in the mesh hole. In this work, plasmonic mesh is used to study airborne particles that are usually difficult to study using FTIR spectroscopy due to strong Mie scattering effect. Respiring dust particles of 4 microns size has significant negative health consequences. Different

  7. The marine diversity spectrum

    DEFF Research Database (Denmark)

    Reuman, Daniel C.; Gislason, Henrik; Barnes, Carolyn


    of taxonomy (all the species in a region regardless of clade) are much less studied but are equally important and will illuminate a different set of ecological and evolutionary processes. We develop and test a mechanistic model of how diversity varies with body mass in marine ecosystems. The model predicts...... the form of the diversity spectrum', which quantifies the distribution of species' asymptotic body masses, is a species analogue of the classic size spectrum of individuals, and which we have found to be a new and widely applicable description of diversity patterns. The marine diversity spectrum...... is predicted to be approximately linear across an asymptotic mass range spanning seven orders of magnitude. Slope -0 center dot 5 is predicted for the global marine diversity spectrum for all combined pelagic zones of continental shelf seas, and slopes for large regions are predicted to lie between -0 center...

  8. Fetal Alcohol Spectrum Disorders (United States)

    Alcohol can harm your baby at any stage during a pregnancy. That includes the earliest stages, before ... can cause a group of conditions called fetal alcohol spectrum disorders (FASDs). Children who are born with ...

  9. Fast Spectrum Reactors

    CERN Document Server

    Todd, Donald; Tsvetkov, Pavel


    Fast Spectrum Reactors presents a detailed overview of world-wide technology contributing to the development of fast spectrum reactors. With a unique focus on the capabilities of fast spectrum reactors to address nuclear waste transmutation issues, in addition to the well-known capabilities of breeding new fuel, this volume describes how fast spectrum reactors contribute to the wide application of nuclear power systems to serve the global nuclear renaissance while minimizing nuclear proliferation concerns. Readers will find an introduction to the sustainable development of nuclear energy and the role of fast reactors, in addition to an economic analysis of nuclear reactors. A section devoted to neutronics offers the current trends in nuclear design, such as performance parameters and the optimization of advanced power systems. The latest findings on fuel management, partitioning and transmutation include the physics, efficiency and strategies of transmutation, homogeneous and heterogeneous recycling, in addit...

  10. Autism Spectrum Disorder (ASD) (United States)

    ... Español (Spanish) Recommend on Facebook Tweet Share Compartir Autism spectrum disorder (ASD) is a developmental disability that ... interview about being fathers of sons who have autism. Watch more Autism videos COMMUNITY REPORT The Community ...

  11. Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds

    Energy Technology Data Exchange (ETDEWEB)

    Laguna-Marco, M. A.; Kayser, P.; Alonso, J. A.; Martínez-Lope, M. J.; van Veenendaal, M.; Choi, Y.; Haskel, D.


    Element- and orbital-selective x-ray absorption and magnetic circular dichroism measurements are carried out to probe the electronic structure and magnetism of Ir 5d electronic states in double perovskite Sr2MIrO6 (M = Mg, Ca, Sc, Ti, Ni, Fe, Zn, In) and La2NiIrO6 compounds. All the studied systems present a significant influence of spin-orbit interactions in the electronic ground state. In addition, we find that the Ir 5d local magnetic moment shows different character depending on the oxidation state despite the net magnetization being similar for all the compounds. Ir carries an orbital contribution comparable to the spin contribution for Ir4+ (5d(5)) and Ir5+ (5d(4)) oxides, whereas the orbital contribution is quenched for Ir6+ (5d(3)) samples. Incorporation of a magnetic 3d atom allows getting insight into the magnetic coupling between 5d and 3d transition metals. Together with previous susceptibility and neutron diffractionmeasurements, the results indicate that Ir carries a significant local magnetic moment even in samples without a 3d metal. The size of the (small) net magnetization of these compounds is a result of predominant antiferromagnetic interactions between local moments coupled with structural details of each perovskite structure

  12. Spectrum and network measurements

    CERN Document Server

    Witte, Robert A


    This new edition of Spectrum and Network Measurements enables readers to understand the basic theory, relate it to measured results, and apply it when creating new designs. This comprehensive treatment of frequency domain measurements successfully consolidates all the pertinent theory into one text. It covers the theory and practice of spectrum and network measurements in electronic systems. It also provides thorough coverage of Fourier analysis, transmission lines, intermodulation distortion, signal-to-noise ratio and S-parameters.

  13. The Introduction of an Undergraduate Interventional Radiology (IR) Curriculum: Impact on Medical Student Knowledge and Interest in IR

    Energy Technology Data Exchange (ETDEWEB)

    Shaikh, M. [Bradford Royal Infirmary, Department of Radiology, Bradford Teaching Hospital Foundation Trust (United Kingdom); Shaygi, B. [Royal Devon and Exeter Hospital, Interventional Radiology Department (United Kingdom); Asadi, H., E-mail:; Thanaratnam, P.; Pennycooke, K.; Mirza, M.; Lee, M., E-mail: [Beaumont Hospital, Interventional Radiology Service, Department of Radiology (Ireland)


    IntroductionInterventional radiology (IR) plays a vital role in modern medicine, with increasing demand for services, but with a shortage of experienced interventionalists. The aim of this study was to determine the impact of a recently introduced IR curriculum on perception, knowledge, and interest of medical students regarding various aspects of IR.MethodsIn 2014, an anonymous web-based questionnaire was sent to 309 4th year medical students in a single institution within an EU country, both before and after delivery of a 10-h IR teaching curriculum.ResultsSeventy-six percent (236/309) of the respondents participated in the pre-IR module survey, while 50 % (157/309) responded to the post-IR module survey. While 62 % (147/236) of the respondents reported poor or no knowledge of IR compared to other medical disciplines in the pre-IR module survey, this decreased to 17 % (27/157) in the post-IR module survey. The correct responses regarding knowledge of selected IR procedures improved from 70 to 94 % for venous access, 78 to 99 % for uterine fibroid embolization, 75 to 97 % for GI bleeding embolization, 60 to 92 % for trauma embolization, 71 to 92 % for tumor ablation, and 81 to 94 % for angioplasty and stenting in peripheral arterial disease. With regard to knowledge of IR clinical roles, responses improved from 42 to 59 % for outpatient clinic review of patients and having inpatient beds, 63–76 % for direct patient consultation, and 43–60 % for having regular ward rounds. The number of students who would consider a career in IR increased from 60 to 73 %.ConclusionDelivering an undergraduate IR curriculum increased the knowledge and understanding of various aspects of IR and also the general enthusiasm for pursuing this specialty as a future career choice.

  14. Autism spectrum disorder - Asperger syndrome (United States)

    ... part of the larger developmental disorder category of autism spectrum disorder . ... American Psychiatric Association. Autism spectrum disorder. ... VA: American Psychiatric Publishing: 2013;50-59. Raviola GJ, ...

  15. Ultrafast vibrational population transfer dynamics in 2-acetylcyclopentanone studied by 2D IR spectroscopy. (United States)

    Park, Sungnam; Ji, Minbiao


    2-Acetylcyclopentanone (2-ACP), which is a β-dicarbonyl compound, undergoes keto-enol isomerization, and its enol tautomers are stabilized by a cyclic intramolecular hydrogen bond. 2-ACP (keto form) has symmetric and asymmetric vibrational modes of the two carbonyl groups at 1748 and 1715 cm(-1) , respectively, which are well separated from the carbonyl modes of its enol tautomers in the FTIR spectrum. We have investigated 2-ACP dissolved in carbon tetrachloride by 2D IR spectroscopy and IR pump-probe spectroscopy. Vibrational population transfer dynamics between the two carbonyl modes were observed by 2D IR spectroscopy. To extract the population exchange dynamics (i.e., the down- and uphill population transfer rate constants), we used the normalized volumes of the cross-peaks with respect to the diagonal peaks at the same emission frequency and the survival and conditional probability functions. As expected, the downhill population transfer time constant (3.2 ps) was measured to be smaller than the uphill population transfer time constant (3.8 ps). In addition, the vibrational population relaxation dynamics of the two carbonyl modes were observed to be the same within the experimental error and were found to be much slower than vibrational population transfer between two carbonyl modes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


    Directory of Open Access Journals (Sweden)

    A. S. Saushkina


    Full Text Available A serious threat to the health of the population is falsified medicines. In a number of cases, they are identified in the process of incoming quality control for compliancewith the requirements of regulatory documents for indicators “Description”, “Packaging”, “Marking”. However, in order to identify sophisticated counterfeits, only a visual assessment of the drug is not enough. Purpose screening evaluation of potentiallycounterfeited or poor-quality drugs using the IR spectrometry along the total spectrum.Materials and methods. The objects of research were available in freely availablecommercially available tablets produced by domestic and foreign manufacturers“Paracetamol Extratab”, “Solpadein fast”, “Citrapac”, “Citramon P”, “Ascofen-P”,  corresponding to the requirements of the current regulatory documents. The studies were carried out on a Fourier-Spectrophotometer infrared “FSM 1201”. Results and discussion. On the example of the tablets “Citramon P”, “Ascophen-P”, “Citrapac”, “Paracetamol Extratab”, “Solpadein Fast” the possibility of using the total IR spectra as a primary screening index of authenticity is shown. It was established that the total IR spectra of medicines of similar composition reflect the similarity of serial samples of the products ofone manufacturer and the difference in serial samples of products of different manufacturers.


    Directory of Open Access Journals (Sweden)

    MUTLU Mehmet Mete


    Full Text Available Black coloured materials and consumer goods are known to be heating up more, because they absorb sun radiation more than light colours. This heating is a problem for the users for black automotive or motorcycle leathers and also for dark shoes and boots which are exposed to sun heat. Human vision system can distinguish visible colours between the wavelengths of 390-700 nm. So reflecting the sun radiation in the infrared area of radiation spectrum higher than 700nm, is a solution for heating problem without affecting the visible colour. For this reason IR reflective dyes and pigments are designed. A leading Leather Chemical Company has developed an IR reflecting dyeing system for leather keeping the dark coloured leathers cooler under sun radiation. Additionally in theory, fat and water content of leather affects its heating properties. In this study, effect of natural, synthetic and waterproof fatliquoring systems on heating properties of leathers coloured with IR reflective dyes and pigments are investigated.

  18. Saturn’s rings in the near-IR: a new view from Cassini-VIMS (United States)

    Nicholson, Philip D.; Hedman, Matthew M.; Le Mouélic, Stephane; Filacchione, Gianrico; Ciarniello, Mauro; Clark, Roger Nelson; Cassini VIMS Team


    The reflectance spectrum of Saturn’s rings in the UV, visible and near-IR regions is dominated by fine-grained crystalline water ice with relatively small amounts of non-icy material, generally proposed to be space-weathered silicates, organics, nano-phase iron oxides or carbon. Previous observations by the VIMS instrument on Cassini have revealed significant spatial variations in the rings’ near-IR spectrum, with higher levels of contamination by non-icy material in the Cassini Division and C ring and larger ice grain sizes in the A and B rings (Nicholson et al. [2008], Cuzzi et al. [2009], Hedman & Nicholson [2013], Filacchione et al. [2012, 2014]). Over the past 12 months, with the Cassini spacecraft passing ever closer to Saturn, VIMS has obtained the best-ever complete spectral scans of both the sunlit and dark sides of the main rings in the 0.35-5.1 micron range, with radial resolutions of 50-120 km. The observations were made at a uniform emission angle of ~15 degrees and a constant phase angle of 60 or 130 degrees so as to minimize extraneous photometric variations. In addition to confirming previous results, the new data clearly show significant smaller-scale spectral variations between the C ring plateaux and their background, within the inner B ring, across several density wave halos and in the trans-Keeler region in the outer A ring.

  19. IR sensor for monitoring of burner flame; IR sensor foer oevervakning av braennarflamma

    Energy Technology Data Exchange (ETDEWEB)

    Svanberg, Marcus; Funkquist, Jonas; Clausen, Soennik; Wetterstroem, Jonas


    To obtain a smooth operation of the coal-fired power plants many power plant managers have installed online mass flow measurement of coal to all burners. This signal is used to monitor the coal mass flow to the individual burner and match it with appropriate amount of air and also to monitor the distribution of coal between the burners. The online mass flow measurement system is very expensive (approximately 150 kEUR for ten burners) and is not beneficial for smaller plants. The accuracy of the measurement and the sample frequency are also questionable. The idea in this project has been to evaluate a cheaper system that can present the same information and may also provide better accuracy and faster sample frequency. The infrared sensor is a cheap narrow banded light emission sensor that can be placed in a water cooed probe. The sensor was directed at the burner flame and the emitted light was monitored. Through calibration the mass flow of coal can be presented. Two measurement campaigns were performed. Both campaigns were carried out in Nordjyllandsverket in Denmark even though the second campaign was planned to be in Uppsala. Due to severe problems in the Uppsala plant the campaign was moved to Nordjyllandsverket. The pre-requisites for the test plant were that online measurement of coal flow was installed. In Nordjyllandsverket 4 out of 16 burners have the mass flow measurement installed. Risoe Laboratories has vast experiences in the IR technology and they provided the IR sensing equipment. One IR sensor was placed in the flame guard position just behind the flame directed towards the ignition zone. A second sensor was placed at the boiler wall directed towards the flame. The boiler wall position did not give any results and the location was not used during the second campaign. The flame-guard-positioned-sensor- signal was thoroughly evaluated and the results show that there is a clear correlation between the coal mass flow and the IR sensor signal. Tests were

  20. New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Daria L. [Department of Chemistry, Yale University, 225; Beltrán-Suito, Rodrigo [Department of Chemistry, Yale University, 225; Thomsen, Julianne M. [Department of Chemistry, Yale University, 225; Hashmi, Sara M. [Department of Chemical and Environmental; Materna, Kelly L. [Department of Chemistry, Yale University, 225; Sheehan, Stafford W. [Catalytic Innovations LLC, 70 Crandall; Mercado, Brandon Q. [Department of Chemistry, Yale University, 225; Brudvig, Gary W. [Department of Chemistry, Yale University, 225; Crabtree, Robert H. [Department of Chemistry, Yale University, 225


    This paper introduces IrI(CO)2(pyalc) (pyalc = (2-pyridyl)-2-propanoate) as an atom-efficient precursor for Ir-based homogeneous oxidation catalysis. This compound was chosen to simplify analysis of the water oxidation catalyst species formed by the previously reported Cp*IrIII(pyalc)OH water oxidation precatalyst. Here, we present a comparative study on the chemical and catalytic properties of these two precursors. Previous studies show that oxidative activation of Cp*Ir-based precursors with NaIO4 results in formation of a blue IrIV species. This activation is concomitant with the loss of the placeholder Cp* ligand which oxidatively degrades to form acetic acid, iodate, and other obligatory byproducts. The activation process requires substantial amounts of primary oxidant, and the degradation products complicate analysis of the resulting IrIV species. The species formed from oxidation of the Ir(CO)2(pyalc) precursor, on the other hand, lacks these degradation products (the CO ligands are easily lost upon oxidation) which allows for more detailed examination of the resulting Ir(pyalc) active species both catalytically and spectroscopically, although complete structural analysis is still elusive. Once Ir(CO)2(pyalc) is activated, the system requires acetic acid or acetate to prevent the formation of nanoparticles. Investigation of the activated bis-carbonyl complex also suggests several Ir(pyalc) isomers may exist in solution. By 1H NMR, activated Ir(CO)2(pyalc) has fewer isomers than activated Cp*Ir complexes, allowing for advanced characterization. Future research in this direction is expected to contribute to a better structural understanding of the active species. A diol crystallization agent was needed for the structure determination of 3.

  1. Įvairialyčiai lantano ir mangano oksido ir multiferoinio bismuto ferito heterodariniai

    Directory of Open Access Journals (Sweden)

    Bonifacas VENGALIS


    Full Text Available Pastaruoju metu naujų elektronikos prietaisų gamyboje buvo pasiekta didelė pažanga auginant, tyrinėjant ir pritaikant plonasluoksnes struktūras, sudarytas iš įvairių daugiakomponenčių funkcinių oksidų. Šiai oksidų grupei priklauso superlaidieji kupratai, mangano oksidai (manganitai, pasižymintys magnetovaržos reiškiniu, taip pat kiti feromagnetiniai, feroelektriniai, multiferoiniai oksidai. Manganitams (jų bendra formulė Ln1-xAxMnO3, kur Ln = La, Nd,..., o A - dvivalentis katijonas, toks kaip Ba, Sr ar Ca skiriama daug dėmesio dėl jų įdomių elektrinių savybių bei tinkamumo įvairiems spintronikos prietaisams kurti. Multiferoikai  (feroelektriniai feromagnetai pasižymi magnetoelektriniu efektu, duodančiu unikalią galimybę elektrinėms ir magnetinėms medžiagos savybėms valdyti panaudoti elektrinius ir magnetinius laukus. Bismuto feritas BiFeO3 (BFO, turintis romboedriškai deformuotą perovskito struktūrą, šiuo metu yra vienas labiausiai tyrinėjamų šios klasės junginių. Organiniai puslaidininkiai (OP taip pat atveria daug naujų galimybių elektronikai. Jų pranašumas yra didelė organinių junginių įvairovė ir palyginti paprasta ir pigi plonų sluoksnių gamybos technologija. Be to, OP pasižymi neįprastai didelėmis sukinių relaksacijos laiko vertėmis, todėl ateityje jie gali būti naudojami naujiems spintronikos prietaisams gaminti. Šiame straipsnyje apžvelgiami pastarųjų metų darbo autorių ir jų kolegų atlikti anksčiau minėtų medžiagų tyrimai. Daugiausia dėmesio skiriama magnetovaržinėmis savybėmis pasižyminčių lantano ir mangano oksidų (manganitų bei multiferoinio  BiFeO3 (BFO junginio plonųjų sluoksnių ir heterodarinių auginimui, tarpfazinių ribų tarp minėtų oksidų, laidžiojo SrTiO3 ir organinio puslaidininkio (Alq3 sudarymui, taip pat elektrinėms heterodarinių savybėms. Plonieji La2/3A1/3MnO3 (A = Ca, Sr, Ba, Ce sluoksniai, kurių storis d

  2. Spitzer IRS Observations of Uranus and Neptune: Implications for Temperature Structure and Composition (United States)

    Orton, Glenn; Fletcher, Leigh; Hines, Dean; Hammel, Heidi; Burgdorf, Martin; Merlet, Cecile; Line, Michael; Moses, Julianne

    We overview the results of the sensitive Spitzer Infrared Spectrometer (IRS) on the atmospheres of Uranus and Neptune, covering in some detail the observations of Uranus shortly after its equinox. IRS observations of Neptune in the Spitzer cycles 1 and 2 and Uranus in Cycle 1 and DD time near its equinox (2007 December 17) used the IRS in several modes. The low-resolution (R 90) spectral modes covered wavelengths between 5 and 21.5 microns, and its high-resolution (R 600) modes covered wavelengths between 10 and 36.5 microns. Spectral features arising from methane, ethane, acetylene, diacetylene and methylacetylene are easily detectable in both planets, and features of CH3 were detected for Neptune. For Uranus, sufficient coverage of the spectrum which is dominated by the opacity provided by the collision-induced absorption of molecular hydrogen allowed disk-averaged temperatures to be determined between 100 and 600 mbar pressure. An upward extension of this coverage to the lower stratosphere was facilitated by matching discrete hydrogen quadrupole S(1) and S(2) lines, which also provided constraints on the para-vs. ortho-hydrogen ratio. These constraints were merged with those at lower pressures derived from Voyager-2 occultation experiments. Regular and deuterated methane absorption and emission are consistent with vapor-pressure-limited mixing of methane in the stratosphere, an upper-tropospheric abundance which is 40 percent of its fully saturated value, and a D/H ratio consistent with one derived from earlier measurements by ISO. Observations of the disk-averaged spectrum over different longitudes imply substantial spatial variability of stratospheric temperatures at pressures below 1 mbar, but no variability above the 3 percent noise level of the spectra for deeper levels. These spectra are consistent with the somewhat noisier Cycle-1 observations taken on 6-7 July 2005.

  3. Plant Sunscreens in Nature: UV and IR Spectroscopy of Sinapate Derivatives (United States)

    Dean, Jacob C.; Walsh, Patrick S.; Zwier, Timothy S.; Allais, Florent


    Plants are exposed to prolonged amounts of UV radiation, with elevated levels of UV-B (280-320 nm) as the ozone layer is depleted. When UV-B radiation penetrates the leaf epidermis, substantial oxidative damage can occur to plant tissues and plant growth can be inhibited. Sinapate esters, particularly sinapoyl malate, have been shown to efficiently prevent such damaging effects. By studying a series of molecules in this unique class under the isolated, cold conditions of a supersonic expansion, the fundamental UV-spectroscopic properties and photophysical aspects following UV absorption can be interrogated in detail. Sinapic acid and neutral sinapoyl malate were brought into the gas phase by laser desorption and detected via resonant two-photon ionization (R2PI). IR-UV double resonance methods were employed to obtain single-conformation UV and IR spectra. As the UV chromophore of interest is the sinapoyl moiety, sinapic acid served as the simplest model to compare directly to the more functionalized sinapoyl malate. It has a spectrum much like most aromatics, with a strong {ππ}^* origin, and well-resolved vibronic structure. By contrast, the spectrum for sinapoyl malate displays a large, broad absorption with little resolved vibronic structure, reflecting its role in nature as a pivotal and efficient UV protectant for plants, serving as the plant's sunscreen. Using conformer-specific IR spectroscopy, the individual conformations of both species were assigned and used as the basis for further ab initio calculations of the excited states that give rise to the observed behavior. Landry, L.G.; Chapple, C.S.; Last, R.L. Plant Physiol. {1995}, 109, 1159-1166.

  4. Medicare Modernization Act (MMA) IRS Medicare Part D (United States)

    Social Security Administration — SSA uses the Internal Revenue Service (IRS) information in determing the eligibility of Medicare recipients to receive subsidy payments for Medicare premiums. SSA...

  5. Comparative Effectiveness of Two Sight-Word Reading Interventions for a Student with Autism Spectrum Disorder (United States)

    Mulé, Christina M.; Volpe, Robert J.; Fefer, Sarah; Leslie, Laurel K.; Luiselli, Jim


    Traditional drill and practice (TDP) and incremental rehearsal (IR) are flashcard drill techniques for teaching sight words to students. Although both have extensive research support, no study to date has compared these methods with children who have autism spectrum disorder (ASD). Utilizing an adaptive alternating treatments design, the present…

  6. 2D IR spectra of cyanide in water investigated by molecular dynamics simulations (United States)

    Lee, Myung Won; Carr, Joshua K.; Göllner, Michael; Hamm, Peter; Meuwly, Markus


    Using classical molecular dynamics simulations, the 2D infrared (IR) spectroscopy of CN− solvated in D2O is investigated. Depending on the force field parametrizations, most of which are based on multipolar interactions for the CN− molecule, the frequency-frequency correlation function and observables computed from it differ. Most notably, models based on multipoles for CN− and TIP3P for water yield quantitatively correct results when compared with experiments. Furthermore, the recent finding that T 1 times are sensitive to the van der Waals ranges on the CN− is confirmed in the present study. For the linear IR spectrum, the best model reproduces the full widths at half maximum almost quantitatively (13.0 cm−1 vs. 14.9 cm−1) if the rotational contribution to the linewidth is included. Without the rotational contribution, the lines are too narrow by about a factor of two, which agrees with Raman and IR experiments. The computed and experimental tilt angles (or nodal slopes) α as a function of the 2D IR waiting time compare favorably with the measured ones and the frequency fluctuation correlation function is invariably found to contain three time scales: a sub-ps, 1 ps, and one on the 10-ps time scale. These time scales are discussed in terms of the structural dynamics of the surrounding solvent and it is found that the longest time scale (≈10 ps) most likely corresponds to solvent exchange between the first and second solvation shell, in agreement with interpretations from nuclear magnetic resonance measurements.

  7. Improved designs of Si-based quantum wells and Schottky diodes for IR detection

    Energy Technology Data Exchange (ETDEWEB)

    Moeen, M., E-mail: [School of Information and Communication Technology, KTH Royal Institute of Technology, Stockholm, 16640, Kista (Sweden); Kolahdouz, M. [School of Electrical and Computer Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Salemi, A.; Abedin, A.; Östling, M. [School of Information and Communication Technology, KTH Royal Institute of Technology, Stockholm, 16640, Kista (Sweden); Radamson, H.H., E-mail: [School of Information and Communication Technology, KTH Royal Institute of Technology, Stockholm, 16640, Kista (Sweden)


    Novel structures of intrinsic or carbon-doped multi quantum wells (MQWs) and intrinsic or carbon-doped Si Schottky diodes (SD), individually or in combination, have been manufactured to detect the infrared (IR) radiation. The carbon concentration in the structures was 5 × 10{sup 20} cm{sup −3} and the MQWs are located in the active part of the IR detector. A Schottky diode was designed and formed as one of the contacts (based on NiSi(C)/TiW) to MQWs where on the other side the structure had an Ohmic contact. The thermal response of the detectors is expressed in terms of temperature coefficient of resistance (TCR) and the quality of the electrical signal is quantified by the signal-to-noise ratio. The noise measurements provide the K{sub 1/f} parameter which is obtained from the power spectrum density. An excellent value of TCR = − 6%/K and K{sub 1/f} = 4.7 × 10{sup −14} was measured for the detectors which consist of the MQWs in series with the SD. These outstanding electrical results indicate a good opportunity to manufacture low cost Si-based IR detectors in the near future. - Highlights: • SiGe (C)/Si(C) multi quantum wells (MQWs) are evaluated to detect IR radiation. • Schottky diodes (SDs), individually or in series with MQWs are also fabricated. • Detectors consisted of MQWs in series with SD show excellent thermal sensing. • The noise values are also extremely low for MQWs in series with SD.

  8. Feeding of the 1 1/2- isomers in stable Ir and Au isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Fotiadis, Nikolaos [Los Alamos National Laboratory; Nelson, Ronald O [Los Alamos National Laboratory; Devlin, Matthew [Los Alamos National Laboratory; Holloway, Shannon T [Los Alamos National Laboratory; Kawano, Toshihiko [Los Alamos National Laboratory; Talou, Patrick [Los Alamos National Laboratory; Chadwick, Mark B [Los Alamos National Laboratory; Becker, John A [LLNL; Garrett, Paul E [U GUELPH, CANADA


    Excited states were studied and absolute partial {gamma}-ray cross sections were measured using the ({eta}, {eta}'{gamma}) reaction in {sup 191}Ir, {sup 193}Ir and {sup 197}Au. A Compton-suppressed germanium-detector array (GEANIE) for {gamma}-ray spectroscopy and the broad-spectrum pulsed neutron source of the Los Alamos Neutron Science Center's WNR facility were used for the measurement. The energy of the incident neutrons was determined using the time-of-flight technique. Absolute partial {gamma}-ray cross sections were measured up to incident neutron energy of 20 MeV for several transitions feeding directly the 1 1/2- isomers and ground states in {sup 191}Ir, {sup 193}Ir and {sup 197}Au. The feeding of the 1 1/2- isomers, which originate from the odd proton occupying the h{sub 1 1/2} orbital, was found for the three targets to be very similar and increasing relative to the feeding of the corresponding ground state with increasing neutron energy up to E{sub n} {approx} 10 MeV. Above this neutron energy the opening of the (n, 2{sub n}) reaction channel strongly affects the population of the isomers and leads to a decrease of their relative population compared to the population of the ground states. The experimental results are compared with theoretical predictions from the GNASH reaction model calculation implementing a version of the spin distribution for the pre-equilibrium reaction piece with either a compound nucleus spin distribution (CN-GNASH) or a Feshbach-Kerman-Koonin (FKK-GNASH) quantum mechanical spin distribution. The effects of the spin cutoff parameter values on the population of states are examined. Evidence is presented that FKK-GNASH provides a description of the experimental data that mitigates the need for adjustment of the level density parameter to fit the data.

  9. Feeding of the 11/2- isomers in stable Ir and Au isotopes (United States)

    Fotiades, N.; Nelson, R. O.; Devlin, M.; Holloway, S.; Kawano, T.; Talou, P.; Chadwick, M. B.; Becker, J. A.; Garrett, P. E.


    Excited states in Ir191, Ir193, and Au197 were studied and absolute partial γ-ray cross sections were measured using the (n,n'γ) reaction. A Compton-suppressed germanium-detector array (GEANIE) for γ-ray spectroscopy was used for the measurement and the broad-spectrum pulsed neutron source of the Los Alamos Neutron Science Center’s WNR facility provided energetic neutrons. The energy of the incident neutrons was determined using the time-of-flight technique. Absolute partial γ-ray cross sections were measured up to incident neutron energy of 20 MeV for several transitions feeding directly the 11/2- isomers and ground states in Ir191, Ir193, and Au197. The feeding of the 11/2- isomers, which originate from the odd proton occupying the h11/2 orbital, was found for the three targets to be very similar and increasing relative to the feeding of the corresponding ground state with increasing neutron energy up to En~10 MeV. Above this neutron energy the opening of the (n,2n) reaction channel strongly affects the population of the isomers and leads to a decrease of their relative population compared to the population of the ground states. The experimental results are compared with theoretical predictions from the GNASH reaction model calculation implementing a version of the spin distribution for the pre-equilibrium reaction piece with either a compound nucleus spin distribution (CN-GNASH) or a Feshbach-Kerman-Koonin (FKK-GNASH) quantum mechanical spin distribution. The effects of the spin cutoff parameter values on the population of states are examined. Evidence is presented that FKK-GNASH provides a description of the experimental data that mitigates the need for adjustment of the level density parameter to fit the data.

  10. Bottomonium spectrum revisited

    CERN Document Server

    Segovia, Jorge; Entem, David R.; Fernández, Francisco


    We revisit the bottomonium spectrum motivated by the recently exciting experimental progress in the observation of new bottomonium states, both conventional and unconventional. Our framework is a nonrelativistic constituent quark model which has been applied to a wide range of hadronic observables from the light to the heavy quark sector and thus the model parameters are completely constrained. Beyond the spectrum, we provide a large number of electromagnetic, strong and hadronic decays in order to discuss the quark content of the bottomonium states and give more insights about the better way to determine their properties experimentally.

  11. Structural, phase stability, electronic, elastic properties and hardness of IrN{sub 2} and zinc blende IrN: First-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Zhaobo [Key Laboratory of Advanced Materials of Yunnan Province & Key Laboratory of Advanced Materials of Non-Ferrous and Precious Rare Metals Ministry of Education, Kunming University of Science and Technology, Kunming 650093 (China); Zhou, Xiaolong, E-mail: [Key Laboratory of Advanced Materials of Yunnan Province & Key Laboratory of Advanced Materials of Non-Ferrous and Precious Rare Metals Ministry of Education, Kunming University of Science and Technology, Kunming 650093 (China); Zhang, Kunhua [State Key Laboratory of Rare Precious Metals Comprehensive Utilization of New Technologies, Kunming Institute of Precious Metals, Kunming 650106 (China)


    First-principle calculations were performed to investigate the structural, phase stability, electronic, elastic properties and hardness of monoclinic structure IrN{sub 2} (m-IrN{sub 2}), orthorhombic structure IrN{sub 2} (o-IrN{sub 2}) and zinc blende structure IrN (ZB IrN). The results show us that only m-IrN{sub 2} is both thermodynamic and dynamic stability. The calculated band structure and density of states (DOS) curves indicate that o-IrN{sub 2} and ZB Ir-N compounds we calculated have metallic behavior while m-IrN{sub 2} has a small band gap of ~0.3 eV, and exist a common hybridization between Ir-5d and N-2p states, which forming covalent bonding between Ir and N atoms. The difference charge density reveals the electron transfer from Ir atom to N atom for three Ir-N compounds, which forming strong directional covalent bonds. Notable, a strong N-N bond appeared in m-IrN{sub 2} and o-IrN{sub 2}. The ratio of bulk to shear modulus (B/G) indicate that three Ir-N compounds we calculated are ductile, and ZB IrN possesses a better ductility than two types IrN{sub 2}. m-IrN{sub 2} has highest Debye temperature (736 K), illustrating it possesses strongest covalent bonding. The hardness of three Ir-N compounds were also calculated, and the results reveal that m-IrN{sub 2} (18.23 GPa) and o-IrN{sub 2} (18.02 GPa) are ultraincompressible while ZB IrN has a negative value, which may be attributed to phase transition at ca. 1.98 GPa.

  12. Polarized IR microscopic imaging of articular cartilage

    Energy Technology Data Exchange (ETDEWEB)

    Ramakrishnan, Nagarajan; Xia Yang; Bidthanapally, Aruna [Department of Physics and Center for Biomedical Research, Oakland University, Rochester, MI 48309 (United States)


    The objective of this spectroscopic imaging study is to understand the anisotropic behavior of articular cartilage under polarized infrared radiation at 6.25 {mu}m pixel resolution. Paraffin embedded canine humeral cartilage-bone blocks were used to obtain 6 {mu}m thick tissue sections. Two wire grid polarizers were used to manipulate the polarization states of IR radiation by setting them for various polarizer/analyzer angles. The characteristics of the major chemical components (amide I, amide II, amide III and sugar) of articular cartilage were investigated using (a) a polarizer and (b) a combination of a polarizer and an analyzer. These results were compared to those obtained using only an analyzer. The infrared anisotropy (variation in infrared absorption as a function of polarization angles) of amide I, amide II and amide III bands correlates with the orientation of collagen fibrils along the tissue depth in different histological zones. An 'anisotropic flipping' region of amide profiles indicates the possibility of using Fourier transform infrared imaging (FTIRI) to determine the histological zones in cartilage. Cross-polarization experiment indicates the resolution of overlapping peaks of collagen triple helix and/or proteoglycan in articular cartilage.

  13. Vertical Crossing Angle in IR8

    CERN Document Server

    Holzer , B J; Alemany, R


    The operation of the LHCb spectrometer dipole has a considerably larger and more challenging impact on the geometry of the LHC beams than the magnets in the high luminosity regions [1]. The integrated dipole field of 4 Tm deflects the beams in the horizontal plane, and using a set of three dipole magnets, called "compensators" a closed horizontal orbit bump is created. This paper summarizes the basic layout of the beam geometry in IR8 under the influence of the LHCb dipole and its compensators and shows the theoretically expected beam orbits, envelopes and aperture needs in the originally designed version. LHCb operation with both field polarities leads to unequal net crossing angles between the two beams and affects the experiment acceptance. It had been proposed therefore to establish a LHC operation mode where the originally designed horizontal crossing angle is shifted at high energy into the vertical plane leading to a vertical crossing scheme at luminosity operation. The new scheme has been successfully...

  14. Spitzer IRS Observations of FU Orionis Objects (United States)

    Green, J. D.; Hartmann, L.; Calvet, N.; Watson, D. M.; Ibrahimov, M.; Furlan, E.; Sargent, B.; Forrest, W. J.


    We present 5-35 μm spectra, taken with the Infrared Spectrograph (IRS) on the Spitzer Space Telescope, of five FU Orionis objects: FU Ori, V1515 Cyg, V1057 Cyg, BBW 76, and V346 Nor. All but V346 Nor reveal amorphous silicate grains in emission at 10 and 20 μm, and show water-vapor absorption bands at 5.8 and 6.8 μm and SiO or possibly methane absorption at 8 μm. These absorption features closely match these bands in model stellar photospheres-signs of the gaseous photospheres of the inner regions of these objects' accretion disks. The continuum emission at 5-8 μm is also consistent with such disks, and, for FU Orionis and BBW 76, longer wavelength emission may be fit by a model that includes moderate disk flaring. V1057 Cyg and V1515 Cyg have much more emission at longer wavelengths than the others, perhaps evidence of a substantial remnant of their natal, infalling envelopes.

  15. Image enhancement and moving target detection in IR image sequences

    NARCIS (Netherlands)

    Beck, W.


    Results are presented of noise reduction by motion compensated temporal filtering in a noisy IR image sequence and of moving target detection in an air-to-ground IR image sequence. In the case of motion compensated temporal filtering our approach consists of estimating the optical flow between

  16. Cross calibration of IRS-P4 OCM satellite sensor

    Digital Repository Service at National Institute of Oceanography (India)

    Suresh, T.; Desa, E.; Mascarenhas, A.A.M.Q.; Matondkar, S.G.P.; Naik, P.; Nayak, S.R.

    The cross calibration of ocean color satellite sensor, IRS-P4 OCM using the radiative transfer code, with SeaWiFS as a reference are presented here. Since the bands of IRS-P4 OCM are identical to those of SeaWiFS and SeaWiFS has been continuously...

  17. Investigation of mid-IR picosecond image upconversion

    DEFF Research Database (Denmark)

    Mathez, Morgan David; Pedersen, Christian; Rodrigo, Peter John


    Imaging and spectroscopy in the mid-infrared (Mid-IR) wavelength region have received considerable attention in recent years. The reason is the high Mid-IR spectral specificity of many gases and complex molecules. In this pilot study we focus on picosecond upconversion imaging exploiting the χ(2...

  18. Microstructures as IR-sensors with Staphylococcus aureus bacteria (United States)

    Baikova, T. V.; Danilov, P. A.; Gonchukov, S. A.; Yermachenko, V. M.; Ionin, A. A.; Khmelnitskii, R. A.; Kudryashov, S. I.; Nguyen, T. T. H.; Rudenko, A. A.; Saraeva, I. N.; Svistunova, T. S.; Zayarny, D. A.


    Using a micro-hole grating in a supported silver film as a laser-fabricated novel optical platform for surface-enhanced IR absoprtion/reflection spectroscopy, characteristic absorption bands of Staphylococcus aureus, especially - its buried carotenoid fragments - were detected in FT-IR spectra with 10-fold analytical enhancement, paving the way to spectral express-identification of the pathogenic microorganisms.

  19. 78 FR 913 - IRS Truncated Taxpayer Identification Numbers (United States)


    ... using a social security number (SSN), IRS individual taxpayer identification number (ITIN), or IRS..., Annuities, Retirement or Profit-Sharing Plans, IRAs, Insurance Contracts, Etc.''), a transferor selling or... individual's social security account number. Section 6109(d) provides that, except as otherwise specified...

  20. Understanding pave-IR : background, use, and advanced techniques (United States)


    Why Has TxDOT Implemented Pave-IR? : Promote more uniform, higher quality pavements : Minimize/eliminate thermal segregation : Expand range of weather conditions for paving : Special Provision 341-024 : Contains option for contractor to use Pave-IR :...

  1. Comparison of simple and chelated amberlite IR-120 for ...

    African Journals Online (AJOL)

    Maximum desorption from IR-8HQ was obtained with a mixture of 4.0 M HCl and 0.5 M HNO3. Furthermore, IR-8HQ was found to be most selective adsorbent among three adsorbents investigated. The developed preconcentration procedure was successfully applied to spiked tap water and real samples. KEY WORDS: ...

  2. Bringing NMR and IR Spectroscopy to High Schools (United States)

    Bonjour, Jessica L.; Hass, Alisa L.; Pollock, David W.; Huebner, Aaron; Frost, John A.


    Development of benchtop, portable Fourier transform nuclear magnetic resonance (NMR) and infrared (IR) spectrometers has opened up opportunities for creating university-high school partnerships that provide high school students with hands-on experience with NMR and IR instruments. With recent changes to the international baccalaureate chemistry…

  3. What is “Vintage” in IR? A writer's note


    Pieczara, Kamila; Eun, Yong-Soo


    The style of writing in international relations (IR) has evolved in recent decades. The lessons of “vintage” IR, to which we return in this article, have been largely forgotten by those writing in the discipline today. A merit will be substantial, we argue, in drawing more heavily from works by previous masters. Several lessons in style follow.

  4. Laboratory experience with the IR-TRACC chest deflection transducer

    NARCIS (Netherlands)

    Rouhana, S.W.; Elhagediab, A.M.; Twisk, D.; Berliner, J.; Baayoun, E.; Dalmotas, D.; Tylko, S.


    In 1998, Rouhana et al. described development of a new device, called the IR-TRACC (InfraRed - Telescoping Rod for Asessment of Chest Compression). Tests have been performed with IR-TRACC units at various labs around the world since 1998. A first-generation was retrofit into a Q3 dummy at TNO.

  5. Autism Spectrum Disorder

    Centers for Disease Control (CDC) Podcasts


    This podcast discusses autism spectrum disorder (ASD), a developmental disability that causes problems with social, communication, and behavioral skills. CDC estimates that one in 68 children has been identified as having ASD.  Created: 4/2/2014 by National Center on Birth Defects and Developmental Disabilities (NCBDDD).   Date Released: 4/2/2014.

  6. Judicious Design of Cationic, Cyclometalated Ir(III) Complexes for Photochemical Energy Conversion and Optoelectronics. (United States)

    Mills, Isaac N; Porras, Jonathan A; Bernhard, Stefan


    The exponential growth in published studies on phosphorescent metal complexes has been triggered by their utilization in optoelectronics, solar energy conversion, and biological labeling applications. Very recent breakthroughs in organic photoredox transformations have further increased the research efforts dedicated to discerning the inner workings and structure-property relationships of these chromophores. Initially, the principal focus was on the Ru(II)-tris-diimine complex family. However, the limited photostability and lack of luminescence tunability discovered in these complexes prompted a broadening of the research to include 5d transition metal ions. The resulting increase in ligand field splitting prevents the population of antibonding e g * orbitals and widens the energy range available for color tuning. Particular attention was given to Ir(III), and its cyclometalated, cationic complexes have now replaced Ru(II) in the vast majority of applications. At the start, this Account documents the initial efforts dedicated to the color tuning of these complexes for their application in light emitting electrochemical cells, an easy to fabricate single-layer organic light emitting device (OLED). Systematic modifications of the ligand sphere of [Ir(ppy) 2 bpy] + (ppy: 2-phenylpyridine, bpy: 2,2'-bipyridine) with electron withdrawing and donating substituents allowed access to complexes with luminescence emission maxima throughout the visible spectrum exhibiting room temperature excited state lifetimes ranging from nanoseconds to dozens of microseconds and quantum yields up to 15 times that of [Ru(bpy) 3 ] 2+ . The diverse photophysical properties were also beneficial when using these Ir(III) complexes for driving solar fuel-producing reactions. For instance, photocatalytic water-reduction systems were explored to gain access to efficient water splitting systems. For this purpose, a variety of water reduction catalysts were paired with libraries of Ir

  7. Distinction of three wood species by Fourier transform infrared spectroscopy and two-dimensional correlation IR spectroscopy (United States)

    Huang, Anmin; Zhou, Qun; Liu, Junliang; Fei, Benhua; Sun, Suqin


    Dalbergia odorifera T. Chen, Pterocarpus santalinus L.F. and Pterocarpus soyauxii are three kinds of the most valuable wood species, which are hard to distinguish. In this paper, differentiation of D. odorifera, P. santalinus and P. soyauxii was carried out by using Fourier transform infrared spectroscopy (FT-IR), second derivative IR spectra and two-dimensional correlation infrared (2D-IR) spectroscopy. The three woods have their characteristic peaks in conventional IR spectra. For example, D. odorifera has obvious absorption peaks at 1640 and 1612 cm -1; P. santalinus has only one peak at 1614 cm -1; and P. soyauxii has one peak at 1619 cm -1 and one shoulder peak at 1597 cm -1. To enhance spectrum resolution and amplify the differences between the IR spectra of different woods, the second derivative technology was adopted to examine the three wood samples. More differences could be observed in the region of 800-1700 cm -1. Then, the thermal perturbation is applied to distinguish different wood samples in an easier way, because of the spectral resolution being enhanced by the 2D correlation spectroscopy. In the region of 1300-1800 cm -1, D. odorifera has five auto-peaks at 1518, 1575, 1594, 1620 and 1667 cm -1; P. santalinus has four auto-peaks at 1469, 1518, 1627 and 1639 cm -1 and P. soyauxii has only two auto-peaks at 1627 and 1639 cm -1. It is proved that the 2D correlation IR spectroscopy can be a new method to distinguish D. odorifera, P. santalinus and P. soyauxii.

  8. Simulation of Wakefield Effect in ILC IR Chamber

    Energy Technology Data Exchange (ETDEWEB)

    Pei, S; Seryi, A.; Raubenheimer, T.O.; /SLAC


    To achieve super high luminosity, high current beams with very short bunch length are needed, which carry high intensity EM fields. For ILC, two bunch trains with bunch length of 300 {micro}m and bunch charge of 3.2nC are needed to collide at the IR to achieve the ILC luminosity goals. When the 300 {micro}m bunches pass through the IR chamber, wakefields will be excited, which will cause HOM power flowing through the IR chamber beam pipe to the final doublets due to the high frequency characteristic of the induced wakefields. Since superconducting technology is adopted for the final doublets of ILC BDS, whose operation stability might be affected by the HOM power produced at the IR chamber, quench might happen. In this paper, we did some analytical estimation and numerical simulation on the wakefield effects in ILC IR chamber.

  9. Co-Ir interface alloying induced by thermal annealing (United States)

    Carlomagno, I.; Drnec, J.; Scaparro, A. M.; Cicia, S.; Vlaic, S.; Felici, R.; Meneghini, C.


    Using angular resolved X-ray Photoelectron Spectroscopy (XPS), Magneto Optic Kerr Effect (MOKE) and X-ray Absorption Spectroscopy (XAS), we characterize the structural and magnetic evolution upon annealing of two thin Co films (8 and 9 Monolayers) deposited on Ir(111). The XAS data collected in the near Co K edge region (XANES), interpreted with ab-initio simulations, show that intermixing takes place at the Co-Ir interface. Using a linear combination analysis, we follow the intermixing during the thermally driven diffusion process. At 500 °C, the interface between Co and Ir(111) roughens slightly, but no alloy formation is detected. At 600 °C, the Co film loses integrity and MOKE data show a rearrangement of the magnetic domains. Annealing to higher temperatures results in CoxIr1 - x alloy formation and Ir segregation on the surface.

  10. Current Diagnosis and Management of Immune Related Adverse Events (irAEs Induced by Immune Checkpoint Inhibitor Therapy

    Directory of Open Access Journals (Sweden)

    Vivek Kumar


    Full Text Available The indications of immune checkpoint inhibitors (ICIs are set to rise further with the approval of newer agent like atezolimumab for use in patients with advanced stage urothelial carcinoma. More frequent use of ICIs has improved our understanding of their unique side effects, which are known as immune-related adverse events (irAEs. The spectrum of irAEs has expanded beyond more common manifestations such as dermatological, gastrointestinal and endocrine effects to rarer presentations involving nervous, hematopoietic and urinary systems. There are new safety data accumulating on ICIs in patients with previously diagnosed autoimmune conditions. It is challenging for clinicians to continuously update their working knowledge to diagnose and manage these events successfully. If diagnosed timely, the majority of events are completely reversible, and temporary immunosuppression with glucocorticoids, infliximab or other agents is warranted only in the most severe grade illnesses. The same principles of management will possibly apply as newer anti- cytotoxic T lymphocytes-associated antigen 4 (CTLA-4 and programmed cell death protein 1 (PD-1/PD-L1 antibodies are introduced. The current focus of research is for prophylaxis and for biomarkers to predict the onset of these toxicities. In this review we summarize the irAEs of ICIs and emphasize their growing spectrum and their management algorithms, to update oncology practitioners.

  11. SERS Characterization of the Indocyanine-Type Dye IR-820 on Gold and Silver Nanoparticles in the Near Infrared

    Directory of Open Access Journals (Sweden)

    Tatiana B. V. Neves


    Full Text Available The Raman spectrum of the indocyanine-type dye IR-820 has been assigned for both solid and solution. SERS spectra of IR-820 on both silver and gold nanoparticles suspensions excited at 1064 nm were obtained. AgNPs allowed the detection of the dye through SERS down to 0.1 micromoles per liter; for the AuNPs the lowest concentration of the dye detectable was 10 micromoles per liter. Changes in the SERS relative intensities compared to the Raman spectrum in solution are subtle, mostly due to the preresonance effect of the dye. However, a perpendicular orientation relative to the metallic surface was inferred for the dye on both AgNPs and AuNPs. The easily distinguishable SERS spectra of the dye excited at 1064 nm, together with the high biological compatibility of cyanine dyes, are both indicative that IR-820 could be used as a high-performance probe molecule for SERS.

  12. 2-10 μm supercontinuum broadening using a highly nonlinear chalcogenide microfiber for mid-IR applications (United States)

    Baili, A.; Cherif, R.; Saini, T. S.; Kumar, A.; Sinha, R. K.; Zghal, M.


    A new design of the As2Se3 microfiber has been presented. With the optimized geometric parameters: pitch Λ= 0.8 μm and five different air filling ratios varying from 0.4 to 0.95, the structure exhibits an all normal dispersion with a flat top equal to -2.3 [ps/(], a confinement loss less than 10-2 dB/km, and a large nonlinear coefficient equal to 7250 (w. km)-1. Using the generalized nonlinear Schrödinger equation, we generate a very broadband supercontinuum (SC) in the mid-infrared region. By pumping the fiber at λp=5.24 μm with a femtosecond laser having 50 fs as a width with a relatively low energy of E=80 pJ, we generate a large spectrum extending from 2 μm to 10 μm in only 2 mm fiber length. The generated SC demonstrates perfect coherence property over the entire bandwidth. SC generation extended into the mid-infrared (IR) spectral region have potential usefulness in a variety of applications requiring a broad mid-IR spectrum such as fiber sensing, IR spectroscopy, fiber laser, optical tomography coherence.

  13. Communication: nanosecond folding dynamics of an alpha helix: time-dependent 2D-IR cross peaks observed using polarization-sensitive dispersed pump-probe spectroscopy. (United States)

    Panman, Matthijs R; van Dijk, Chris N; Meuzelaar, Heleen; Woutersen, S


    We present a simple method to measure the dynamics of cross peaks in time-resolved two-dimensional vibrational spectroscopy. By combining suitably weighted dispersed pump-probe spectra, we eliminate the diagonal contribution to the 2D-IR response, so that the dispersed pump-probe signal contains the projection of only the cross peaks onto one of the axes of the 2D-IR spectrum. We apply the method to investigate the folding dynamics of an alpha-helical peptide in a temperature-jump experiment and find characteristic folding and unfolding time constants of 260 ± 30 and 580 ± 70 ns at 298 K.

  14. Adaptive spectrum decision framework for heterogeneous dynamic spectrum access networks

    CSIR Research Space (South Africa)

    Masonta, M


    Full Text Available Spectrum decision is the ability of a cognitive radio (CR) system to select the best available spectrum band to satisfy dynamic spectrum access network (DSAN) users¿ quality of service (QoS) requirements without causing harmful interference...


    Energy Technology Data Exchange (ETDEWEB)

    Byard D. Wood


    This RD&D project is a three year team effort to develop a hybrid solar lighting (HSL) system that transports solar light from a paraboloidal dish concentrator to a luminaire via a large core polymer fiber optic. The luminaire can be a device to distribute sunlight into a space for the production of algae or it can be a device that is a combination of solar lighting and electric lighting. A benchmark prototype system has been developed to evaluate the HSL system. Sunlight is collected using a one-meter paraboloidal concentrator dish with two-axis tracking. A secondary mirror consisting of eight planar-segmented mirrors directs the visible part of the spectrum to eight fibers (receiver) and subsequently to eight luminaires. This results in about 8,200 lumens incident at each fiber tip. Each fiber can illuminate about 16.7 m{sup 2} (180 ft{sup 2}) of office space. The IR spectrum is directed to a thermophotovoltaic (TPV) array to produce electricity. During this reporting period, the project team made advancements in the design of the second generation (Alpha) system. For the Alpha system, the eight individual 12 mm fibers have been replaced with a centralized bundle of 3 mm fibers. The TRNSYS Full-Spectrum Solar Energy System model has been updated and new components have been added. The TPV array and nonimaging device have been tested and progress has been made in the fiber transmission models. A test plan was developed for both the high-lumen tests and the study to determine the non-energy benefits of daylighting. The photobioreactor team also made major advancements in the testing of model scale and bench top lab-scale systems.

  16. Raman spectrum of asphaltene

    KAUST Repository

    Abdallah, Wael A.


    Asphaltenes extracted from seven different crude oils representing different geological formations from around the globe were analyzed using the Raman spectroscopic technique. Each spectrum is fitted with four main peaks using the Gaussian function. On the basis of D1 and G bands of the Raman spectrum, asphaltene indicated an ordered structure with the presence of boundary defected edges. The average aromatic sheet size of the asphaltene molecules is estimated within the range of 1.52-1.88 nm, which represents approximately seven to eight aromatic fused rings. This estimation is based on the integrated intensity of D1 and G bands, as proposed by Tunistra and Koenig. The results here are in perfect agreement with so many other used techniques and indicate the potential applicability of Raman measurements to determine the average aromatic ring size and its boundary. © 2012 American Chemical Society.

  17. Radio frequency spectrum management (United States)

    Sujdak, E. J., Jr.


    This thesis is a study of radio frequency spectrum management as practiced by agencies and departments of the Federal Government. After a brief introduction to the international agency involved in radio frequency spectrum management, the author concentrates on Federal agencies engaged in frequency management. These agencies include the National Telecommunications and Information Administration (NTIA), the Interdepartment Radio Advisory Committee (IRAC), and the Department of Defense (DoD). Based on an analysis of Department of Defense frequency assignment procedures, recommendations are given concerning decentralizing military frequency assignment by delegating broader authority to unified commanders. This proposal includes a recommendation to colocate the individual Service frequency management offices at the Washington level. This would result in reduced travel costs, lower manpower requirements, and a common tri-Service frequency management data base.

  18. Near-IR imaging of occlusal dental decay (United States)

    Buehler, Christopher M.; Fried, Daniel


    Dental enamel manifests high transparency in the near-IR. Previous work demonstrated that near-IR light at 1310-nm is ideally suited for the transillumination of interproximal dental caries (dental decay in between teeth) [1]. However, most new dental decay occurs in the pits and fissures of the occlusal (biting) surfaces of posterior teeth. These caries lesions cannot be detected by x-rays during the early stages of decay due to the overlapping topography of the crown of the tooth. In this study, a near-IR imaging system operating at 1310-nm was used to acquire occlusal images by launching the near-IR light into the buccal surface of the tooth just above the gingival margin (gum-line). The near-IR light diffuses through the highly scattering dentin providing uniform back illumination of the enamel of the crowns allowing imaging of the occlusal surfaces. The near-IR images show high contrast between sound and demineralized areas. Demineralization (decay) can be easily differentiated from stains and pigmentation. Moreover, the high transparency of the enamel enables imaging at greater depth for the detection of subsurface decay hidden under the enamel. These early images suggest that the near-IR offers significant advantages over conventional visual, tactile and radiographic caries detection methods.

  19. Spectrum Utilization Concepts (United States)


    bands and space services since it accounts for carrier types , modulation and multiple access techniques, and regenerative repeaters that are not... TYPE OF REPORT 13b. TIME COVERED 14. DATE OF REPORT (Yeaw, Mont, Day) 15. PAGE COUNT Final FROM Dec87 TO Nov 88 1988 November 30 240 16. SUPPLEMENTARY...MILSATCOM, WARC, Spectrum Use 19,ABSTRACT (Continue on reverse it necessary and Identify by blod number) The objective of this task was to provide



    Middha Akanksha; Kataria Sahil; Sandhu Premjeet; Kapoor Bhawna


    Autism or Autism Spectrum Disorders (ASD) is a serious neurological disorder affecting communication skills, social interactions, adaptability in an individual, and also causes dramatic changes in behavioral patterns. This condition typically lasts throughout one’s lifetime and affects both, children as well as adults. Research has shown a tenfold increase in autism cases over the past decade and still rising at an alarming pace. The origins of autism are not known even to modern science. Aut...

  1. Energetic electrons, hard x-ray emission and MHD activity studies in the IR-T1 tokamak. (United States)

    Agah, K Mikaili; Ghoranneviss, M; Elahi, A Salar


    Determinations of plasma parameters as well as the Magnetohydrodynamics (MHD) activity, energetic electrons energy and energy confinement time are essential for future fusion reactors experiments and optimized operation. Also some of the plasma information can be deduced from these parameters, such as plasma equilibrium, stability, and MHD instabilities. In this contribution we investigated the relation between energetic electrons, hard x-ray emission and MHD activity in the IR-T1 Tokamak. For this purpose we used the magnetic diagnostics and a hard x-ray spectroscopy in IR-T1 tokamak. A hard x-ray emission is produced by collision of the runaway electrons with the plasma particles or limiters. The mean energy was calculated from the slope of the energy spectrum of hard x-ray photons.

  2. An add-on cap for ATR-IR spectroscopy studies

    DEFF Research Database (Denmark)


    The invention relates to a cap (300B) for an attenuated total reflectance infrared (ATR-IR) spectrometer, the ATR-IR spectrometer comprising an ATR-IR plate (200). The cap (300B) comprises an ATR- IR plate facing cap surface. When the ATR-IR plate facing cap surface is placed on the sample surface...

  3. Patient Safety in Interventional Radiology: A CIRSE IR Checklist.

    LENUS (Irish Health Repository)


    Interventional radiology (IR) is an invasive speciality with the potential for complications as with other invasive specialities. The World Health Organization (WHO) produced a surgical safety checklist to decrease the morbidity and mortality associated with surgery. The Cardiovascular and Interventional Society of Europe (CIRSE) set up a task force to produce a checklist for IR. Use of the checklist will, we hope, reduce the incidence of complications after IR procedures. It has been modified from the WHO surgical safety checklist and the RAD PASS from Holland.

  4. Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

    CERN Document Server

    Kolev, Tsonko


    A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

  5. Novel IR coating designs with improved environmental durability (United States)

    Yalamanchi, R. S.; Thutupalli, G. K. M.; Harshavardhan, K. S.


    A new way of imparting protection to IR optical components by the use of amorphous materials in metastable equilibrium, so-called microstructure engineering, is examined. Thin film designs in the IR band were experimentally realized with sputtered Ge and plasma-deposited amorphous hydrogenated carbon (a-C:H or DLC) as the terminating layer. All the optical components survived highly stressful environmental durability tests, such as cycling/thermal shock and acid immersion. It is shown that the grain boundary-free nature together with the inherent chemical inertness of a sealing diamondlike carbon layer imparts environmental ruggedness to the IR optical components, improving their performance.

  6. Chlorination of (PheboxIr(mesityl(OAc by Thionyl Chloride

    Directory of Open Access Journals (Sweden)

    Meng Zhou


    Full Text Available Pincer (PheboxIr(mesityl(OAc (2 (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene using (PheboxIr(OAc2OH2 (1, was treated with thionyl chloride to rapidly form 1-(chloromethyl-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash column chromatography to form (PheboxIrCl2OH2 in 87% yield.

  7. Spectrum Services 2007 (United States)

    Dobos, L.; Budavári, T.; Csabai, I.; Szalay, A. S.


    We present the Filter and Spectrum Services consisting of easy-to-use web applications and web services for searching, plotting and managing large collections of spectral energy distribution data and filter profiles as well as for performing various scientific operations on spectra in a unified framework. The services provide keyword search, advanced query forms and SQL query possibilities for selecting spectra or bandpass curves which may be retrieved in a variety of file formats including XML, VOTable and ASCII. All SDSS DR1-DR5 spectra had been loaded into a database as well as the entire 2dF catalog that adds up to more than 2.5 million SEDs of about a million spatial objects, but registered users can upload their own data making it available for the rest of the community and are free to modify or delete them at any time. Theoretical catalogs, such as the Bruzual-Charlot stochastic burst model spectrum library (100k spectra) and the BaSeL stellar library are also available. Scientific services allow building rest-frame composite spectra out of selected spectra; calculating synthetic magnitudes by convolving spectra with an arbitrary set of bandpass curves of optical instrument filters to generate simulated photometric catalogs on-the-fly; galactic extinction correction, fitting of the continuum using different set of templates (Bruzual-Charlot '03 templates, SDSS eigenspectra), line fitting. All scientific functionalities are available from the web user interface and via the SOAP web services for programmers. MySpectrum is a cross-platform version of the spectrum web service for setting up your own spectrum repository. It integrates into the main service allowing easy access to your data for the whole VO community. The main idea behind our web services is to move scientific functionalities physically close to the database in order to spare network bandwidth. This way scientists may do research without setting up expensive hardware, downloading large datasets

  8. Imaging with electromagnetic spectrum applications in food and agriculture

    CERN Document Server

    Jayasuriya, Hemantha


    This book demonstrates how imaging techniques, applying different frequency bands from the electromagnetic spectrum, are used in scientific research. Illustrated with numerous examples this book is structured according to the different radiation bands: From Gamma-rays over UV and IR to radio frequencies. In order to ensure a clear understanding of the processing methodologies, the text is enriched with descriptions of how digital images are formed, acquired, processed and how to extract information from them. A special emphasis is given to the application of imaging techniques in food and agriculture research.

  9. High-repetition rate, picosecond-pulse, tunable, mid-IR PPLN OPG source (United States)

    Isyanova, Yelena; Tian, Wenyan; Moulton, Peter F.


    We report here on the performance of a narrow-line, mid-IR source based on a PPLN-crystal optical parametric generator (OPG). The crystal was pumped by a pulsed, 20-MHz-rate, 1064-nm Yb:fiber-based source operating with 20- psec pulses. The OPG produced a broad spectrum between 2027 nm and 2239 nm. By placing a band-pass filter after the OPG we were able to select a 30-nm bandwidth output, and we achieved further line reduction (0.7 nm) and 4.5 mW of average power at 2039 nm, using a reflective Volume Bragg Grating (VBG). Devices such as piezo-controlled etalons can provide rapidly tunable, narrow-linewidth power from this system.

  10. Intracavity laser absorption spectroscopy using mid-IR quantum cascade laser (United States)

    Medhi, G.; Muravjov, A. V.; Saxena, H.; Fredricksen, C. J.; Brusentsova, T.; Peale, R. E.; Edwards, O.


    Intracavity Laser Absorption Spectroscopy (ICLAS) at IR wavelengths offers an opportunity for spectral sensing with sufficient sensitivity to detect vapors of low vapor pressure compounds such as explosives. Reported here are key enabling technologies for this approach, including multi-mode external-cavity quantum cascade lasers and a scanning Fabry-Perot spectrometer to analyze the laser mode spectrum in the presence of a molecular intracavity absorber. Reported also is the design of a compact integrated data acquisition and control system. Applications include military and commercial sensing for threat compounds, chemical gases, biological aerosols, drugs, and banned or invasive plants or animals, bio-medical breath analysis, and terrestrial or planetary atmosphere science.

  11. FT-IR, FT-Raman and Computational Study of Ethyl Methyl Ketone Semicarbazone

    Directory of Open Access Journals (Sweden)

    P. S. Binil


    Full Text Available FT-IR and FT-Raman spectra of ethyl methyl ketone semicarbazone were recorded and analyzed. The vibrational wavenumbers were computed using HF/6-31G*, B3PW91/6-31G* and B3LYP/6-31G* basis and compared with experimental data. The first hyperpolarizability, infrared intensities and Raman activities are reported. The calculated first hyperpolarizability is comparable with the reported values of similar derivatives and is an attractive object for future studies of non-linear optics. The extended π-electron delocalization over the carbazone moiety is responsible for the nonlinearity of the molecule. The geometrical parameters of the title compound are in agreement with that of similar derivatives. The red shift of the NH stretching wavenumber in the infrared spectrum from the computed wavenumber indicates the weakening of the NH bond resulting in proton transfer to the neighboring oxygen atom.


    African Journals Online (AJOL)

    aminoethoxy)propane (baep) were examined both experimentally and theoretically including FT-IR and Raman spectroscopic methods. Among the possible structural configurations, 30 of them were handled in the framework of this study.

  13. Passive IR sensor performance analysis using Mathcad modeling (United States)

    Wan, William


    This paper presents an end-to-end physics based performance model for a passive infrared (IR) sensor using the Mathcad® spreadsheet. This model will calculate both temporal and spatial noise of a staring focal plane array (FPA) IR sensor, the signal-to-noise ratio (SNR) of the sensor against different targets at different ranges (with atmospheric effects, both turbulence and extinction considered). Finally, probability of detection (Pd) based on SNR results, against these targets, are also discussed. This model will allow the user to easily define basic sensor parameters such as spectral band, detector FPA format & size, field of view (FOV), optics F/#, etc. In addition, target and environmental parameters are also considered for the analyses. This performance model will allow the user to determine if a particular IR sensor design would meet the requirements of its operational specifications, and would help the user to refine the various parameters of the IR sensor at the early design stage.

  14. Šeimos turtas ir jo teisinis statusas


    Kutkaitė-Žemaitienė, Aušrinė


    SANTRAUKA Šis magistro darbas skirtas šeimos turto instituto ir jo teisinio statuso analizei. Įsigaliojus naujajam Civiliniam kodeksui 2001 m. liepos 1 dieną, kaip viena iš naujovių buvo įtvirtintas šeimos turto institutas. Tą lėmė Lietuvos Respublikos prisiimti tarptautiniai įsipareigojimai nepilnamečių vaikų teisių ir teisėtų interesų apsaugos srityje. Taigi šeimos turto instituto tikslas – apsaugoti nepilnamečių vaikų ir ekonominiu požiūriu silpnesnio sutuoktinio teisių ir teisėtų interesų...

  15. A Modified Harris Corner Detection for Breast IR Image

    Directory of Open Access Journals (Sweden)

    Chia-Yen Lee


    Full Text Available Harris corner detectors, which depend on strong invariance and a local autocorrelation function, display poor detection performance for infrared (IR images with low contrast and nonobvious edges. In addition, feature points detected by Harris corner detectors are clustered due to the numerous nonlocal maxima. This paper proposes a modified Harris corner detector that includes two unique steps for processing IR images in order to overcome the aforementioned problems. Image contrast enhancement based on a generalized form of histogram equalization (HE combined with adjusting the intensity resolution causes false contours on IR images to acquire obvious edges. Adaptive nonmaximal suppression based on eliminating neighboring pixels avoids the clustered features. Preliminary results show that the proposed method can solve the clustering problem and successfully identify the representative feature points of IR breast images.

  16. Dynamic IR Scene Projector Based Upon the Digital Micromirror Device

    National Research Council Canada - National Science Library

    Beasley, D. B; Bender, Matt; Crosby, Jay; Messer, Tim; Saylor, Daniel A


    ...). The MAPS is based upon the Texas Instruments Digital Micromirror Device (DMD) which has been modified to project images which are suitable for testing sensor and seekers operating in the UV, visible, and IR wavebands...

  17. Do lower IRS collection stats warrant aggressive strategies?

    National Research Council Canada - National Science Library

    George G Jones; Mark A Luscombe


    ... the first 6 months of fiscal year 1999. The IRS National Office is sure to try to boost its collection enforcement numbers in the future to counteract any public perception that no one needs to pay taxes anymore...

  18. IR fixed points in SU(3 gauge theories

    Directory of Open Access Journals (Sweden)

    K.-I. Ishikawa


    Full Text Available We propose a novel RG method to specify the location of the IR fixed point in lattice gauge theories and apply it to the SU(3 gauge theories with Nf fundamental fermions. It is based on the scaling behavior of the propagator through the RG analysis with a finite IR cutoff, which we cannot remove in the conformal field theories in sharp contrast to the confining theories. The method also enables us to estimate the anomalous mass dimension in the continuum limit at the IR fixed point. We perform the program for Nf=16,12,8 and Nf=7 and indeed identify the location of the IR fixed points in all cases.

  19. One-Dimensional Tunable Photonic-Crystal IR Filter Project (United States)

    National Aeronautics and Space Administration — MetroLaser proposes to design and develop an innovative narrowband tunable IR filter based on the properties of a one-dimensional photonic crystal structure with a...

  20. IceBridge KT19 IR Surface Temperature V001 (United States)

    National Aeronautics and Space Administration — The NASA IceBridge KT19 IR Surface Temperature data set contains surface temperature measurements of Arctic and Antarctic sea ice and land ice acquired using the...

  1. Fleet Protection Using a Small UAV Based IR Sensor

    National Research Council Canada - National Science Library

    Buss, James R; Ax, Jr, George R


    A study was performed to define candidate electro-optical and infrared (EO/IR) sensor configurations and assess their potential utility as small UAV-based sensors surveilling a perimeter around surface fleet assets...

  2. Upconversion applied for mid-IR hyperspectral image acquisition

    DEFF Research Database (Denmark)

    Tidemand-Lichtenberg, Peter; Kehlet, Louis Martinus; Sanders, Nicolai Højer


    Different schemes for upconversion mid-IR hyperspectral imaging is implemented and compared in terms of spectral coverage, spectral resolution, speed and noise. Phasematch scanning and scanning of the object within the field of view is considered....

  3. Effect of Water on HEMA Conversion by FT-IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    TS. Jafarzadeh Kashi


    Full Text Available Objective: The use of HEMA as a biocompatible material in dentin bonding systems and its potential for clinical applications has been well established. Excess water can affect conversion of bonding resins. The aim of this study was to survey the effect of water on the degree of conversion of HEMA by Fourier Transform Infra-red Spectroscopy (FT-IR.Materials and Methods: In this experimental study, distilled water was added in amounts of 0, 0.05, 0.1, 0.2, and 0.4 ml to 1 ml of curable HEMA solution. Six repetitions per wa-ter ratio were made and investigated. Each sample was polymerized for 60 seconds. De-gree of conversion was obtained from the absorbance IR-Spectrum of the materials before and after polymerization by FT-IR spectroscopy. One way ANOVA and Tukey-HSD were carried out to compare and detect any differences among groups.Results: Statistical analysis indicates highly significant difference between pairs of groups at level (P<0.001. The results showed a trend of decreasing in HEMA conversion with increasing water. Degree of conversion changes significantly within the 0.05 ml to 0.2 ml water range. However, degree of conversion did not change after reaching 0.02 ml and before 0.05.Conclusion: Degree of conversion of HEMA decreased by increasing water. The most dramatic effect of water on the polymerization process occurs within a range which exists under clinical conditions. The reason that the degree of conversion did not show signifi-cant result before 0.05 ml may be related to the hydrophilic nature of HEMA.

  4. MID-IR emission of the interstellar medium (United States)

    Boulanger, F.; Perault, M.; Puget, J. L.


    IRAS observations of the local interstellar medium and the galactic plane are presented; for all components, the radiation observed at 12 microns represents a large fraction of the far-IR emission. The 12/25 microns color of the diffuse IR emission of the galactic plane increases from the inner to the outer parts while the 60/100 microns ratio decreases, a color-color anticorrelation also observed for giant H II regions. The implications of these observations are discussed.

  5. Structural Changes in Cooked Rice Treated with Cooling-Reheating Process and Coconut Milk Addition as Observed With FT-IR and 13C NMR

    Directory of Open Access Journals (Sweden)

    Nuri Arum Anugrahati


    Full Text Available The molecular structural changes of food could be observed by the technique of FT-IR and 13C NMR spectroscopy. This research was aimed to study the structural changes in cooked rice treated with cooling-reheating process and coconut milk addition using FT-IR and 13C NMR. It was found that the cooling-reheating process and addition of coconut milk cause several structural changes of cooked rice. The IR analysis showed the bands at 3,400, 2,900, 1,018 and 856 cm-1 changed due to the retrogradation during cooling process. The spectrum of 13C NMR showed the change of peaks at 100.28 and 100.10 ppm. These changes may be related to the addition of coconut milk during rice cooking.


    Energy Technology Data Exchange (ETDEWEB)

    Arnold, L. A.; Watson, Dan M.; Kim, K. H.; Manoj, P.; Remming, I.; Sheehan, P.; Forrest, W. J.; Mamajek, E. [Department of Physics and Astronomy, University of Rochester, Rochester, NY 14627 (United States); Adame, L.; McClure, M. [Department of Astronomy, University of Michigan, 500 Church Street, Dennison Building, Ann Arbor, MI 48109 (United States); Furlan, E. [Jet Propulsion Laboratory, California Institute of Technology, Mail Stop 264-723, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Espaillat, C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-78, Cambridge, MA 02138 (United States); Ausfeld, K.; Rapson, V. A., E-mail:, E-mail: [Center for Imaging Science, Rochester Institute of Technology, 54 Lomb Memorial Drive, Rochester, NY 14623 (United States)


    We report on the {lambda} = 5-36 {mu}m Spitzer Infrared Spectrograph (IRS) spectra of 79 young stellar objects in the very young nearby cluster NGC 1333. NGC 1333's youth enables the study of early protoplanetary disk properties, such as the degree of settling and the formation of gaps and clearings. We construct spectral energy distributions (SEDs) using our IRS data as well as published photometry and classify our sample into SED classes. Using 'extinction-free' spectral indices, we determine whether the disk, envelope, or photosphere dominates the spectrum. We analyze the dereddened spectra of objects that show disk-dominated emission using spectral indices and properties of silicate features in order to study the vertical and radial structure of protoplanetary disks in NGC 1333. At least nine objects in our sample of NGC 1333 show signs of large (several AU) radial gaps or clearings in their inner disk. Disks with radial gaps in NGC 1333 show more nearly pristine silicate dust than their radially continuous counterparts. We compare properties of disks in NGC 1333 to those in three other well-studied regions, Taurus-Auriga, Ophiuchus, and Chamaeleon I, and find no difference in their degree of sedimentation and dust processing.

  7. FT-IR microspectroscopy in rapid identification of bacteria in pure and mixed culture (United States)

    Fontoura, Inglid; Belo, Ricardo; Sakane, Kumiko; Cardoso, Maria Angélica Gargione; Khouri, Sônia; Uehara, Mituo; Raniero, Leandro; Martin, Airton A.


    In recent years FT-IR microspectroscopy has been developed for microbiology analysis and applied successfully in pure cultures of microorganisms to rapidly identify strains of bacteria, yeasts and fungi. The investigation and characterization of microorganism mixed cultures is also of growing importance, especially in hospitals where it is common to poly-microbial infections. In this work, the rapid identification of bacteria in pure and mixed cultures was studied. The bacteria were obtained from the Institute Oswaldo Cruz culture collection at Brazil. Escherichia coli ATCC 10799 and Staphylococcus aureus ATCC 14456 were analyzed, 3 inoculations were examined in triplicate: Escherichia coli, Staphylococcus aureus and a mixed culture of them. The inoculations were prepared according to McFarland 0.5, incubated at 37 ° C for 6 hours, diluted in saline, placed in the CaF2 window and store for one hour at 50°C to obtain thin film. The measurement was performed by Spectrum Spotlight 400 (Perkin-Elmer) equipment in the range of 4000-900 cm-1, with 32 scans using a transmittance technique with point and image modes. The data were processed (baseline, normalization, calculation of first derivate followed by smoothing with 9 point using a Savitzky-Golay algorithm) and a cluster analysis were done by Ward's algorithm and an excellent discrimination between pure and mixed culture was obtained. Our preliminary results indicate that the FT-IR microspectroscopy associated with cluster analysis can be used to discriminate between pure and mixed culture.

  8. Experimental and theoretical studies on IR, Raman, and UV-Vis spectra of quinoline-7-carboxaldehyde. (United States)

    Kumru, M; Küçük, V; Kocademir, M; Alfanda, H M; Altun, A; Sarı, L


    Spectroscopic properties of quinoline-7-carboxaldehyde (Q7C) have been studied in detail both experimentally and theoretically. The FT-IR (4000-50 cm(-1)), FT-Raman (4000-50 cm(-1)), dispersive-Raman (3500-50 cm(-1)), and UV-Vis (200-400 nm) spectra of Q7C were recorded at room temperature (25 °C). Geometry parameters, potential energy surface about CCH(O) bond, harmonic vibrational frequencies, IR and Raman intensities, UV-Vis spectrum, and thermodynamic characteristics (at 298.15K) of Q7C were computed at Hartree-Fock (HF) and density functional B3LYP levels employing the 6-311++G(d,p) basis set. Frontier molecular orbitals, molecular electrostatic potential, and Mulliken charge analyses of Q7C have also been performed. Q7C has two stable conformers that are energetically very close to each other with slight preference to the conformer that has oxygen atom of the aldehyde away from the nitrogen atom of the quinoline. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Multi-octave supercontinuum generation with IR radiation filamentation in transparent solid-state media (United States)

    Frolov, S. A.; Trunov, V. I.; Leshchenko, V. E.; Pestryakov, E. V.


    Supercontinuum generation from the near to far IR during radiation filamentation in solid-state media in an anomalous dispersion region is theoretically investigated. The initial search for appropriate media with the use of an interference model showed that the widest IR spectrum is generated in media with high values of zero group velocity dispersion wavelength with the pump wavelength located not far from it. Halides belong to one of such media groups. The possibility of generation of a very wide supercontinuum in calcium fluoride (0.52-3.35 μm, which corresponds to 2.7 octaves), sodium chloride (0.7-7.6 μm, 3.5 octaves), and potassium iodide (0.66-22 μm, 5.1 octaves) is demonstrated by numerical simulation. Also, pulse self-compression down to 13 fs at the 5-μm central wavelength (about single period) has been observed in potassium iodide. The mechanisms of multi-octave supercontinuum generation are discussed.

  10. Calibration of Surface Brightness Fluctuations for WFC3/IR (United States)

    Blakeslee, John


    We aim to characterize galaxy surface brightness fluctuations {SBF}, and calibrate the SBF distance method, in the F110W and F160W filters of the Wide Field Camera 3 IR channel. Because of the very high throughput of F110W and the good match of F160W to the standard H band, we anticipate that both of these filters will be popular choices for galaxy observations with WFC3/IR. The SBF signal is typically an order of magnitude brighter in the near-IR than in the optical, and the characterisitics {sensitivity, FOV, cosmetics} of the WFC3/IR channel will be enormously more efficient for SBF measurements than previously available near-IR cameras. As a result, our proposed SBF calibration will allow accurate distance derivation whenever an early-type or bulge-dominated galaxy is observed out to a distance of 150 Mpc or more {i.e., out to the Hubble flow} in the calibrated passbands. For individual galaxy observations, an accurate distance is useful for establishing absolute luminosities, black hole masses, linear sizes, etc. Eventually, once a large number of galaxies have been observed across the sky with WFC3/IR, this SBF calibration will enable accurate mapping of the total mass density distribution in the local universe using the data available in the HST archive. The proposed observations will have additional important scientific value; in particular, we highlight their usefulness for understanding the nature of multimodal globular cluster color distributions in giant elliptical galaxies.

  11. Serial removal of caries lesions from tooth occlusal surfaces using near-IR image-guided IR laser ablation (United States)

    Chan, Kenneth H.; Tom, Henry; Darling, Cynthia L.; Fried, Daniel


    Previous studies have established that caries lesions can be imaged with high contrast without the interference of stains at near-IR wavelengths greater than 1300-nm. It has been demonstrated that computer controlled laser scanning systems utilizing IR lasers operating at high pulse repetition rates can be used for serial imaging and selective removal of caries lesions. In this study, we report our progress towards the development of algorithms for generating rasterized ablation maps from near-IR reflectance images for the removal of natural lesions from tooth occlusal surfaces. An InGaAs camera and a filtered tungsten-halogen lamp producing near-IR light in the range of 1500-1700-nm were used to collect crosspolarization reflectance images of tooth occlusal surfaces. A CO2 laser operating at a wavelength of 9.3- μm with a pulse duration of 10-15-μs was used for image-guided ablation.

  12. Multispectral IR detection modules and applications (United States)

    Münzberg, M.; Breiter, R.; Cabanski, W.; Lutz, H.; Wendler, J.; Ziegler, J.; Rehm, R.; Walther, M.


    managed to realize first most promising SL based detectors. Fully integrated IDCAs with a MWIR SL single color device with 256x256 pixels in 40 μm pitch have been integrated and tested. In the next step the pitch was reduced to 24μm in a 384x288 pixel configuration. With this design and further improved technology a very good pixel operabilities with very low cluster sizes (color device based on SL technology on the existing 384x288 read-out circuit (ROIC) as used in the dual band QWIP device is available. It combines spectral selective detection in the 3-4.1 μm wavelength range and 4.1-5 μm wavelength range in each pixel with coincident integration in a 384x288x2 format and 40 μm pitch. Excellent thermal resolution with NETD colors. The spectral cross talk of the red band to the blue band is estimated below 1%o which is important to reduce significantly the false alarm rate in missile approach warning systems as the primarily intended use of the dual color detector is. Real time analysis of gases, i.e. the detection of toxic or agent gases, by multi spectral detection in the IR used the characteristic infrared emission or absorption lines of different gas types. Spectroscopic systems consisting of a spectrometer with the need for large linear MCT array with small pixel sizes are used in this case. Possibilities are outlined to use long linear arrays, such as the 576x7 MCT detector, to perform spectral selective measurements in the 2-11μm wavelength range. For these applications a 576x7 MCT FPA is integrated in an open dewar cooler assy without window able to operate directly coupled in an evacuated and cooled spectrometer. The sensitivity of the array is consequently not limited by the transmission of a window for vacuum conservation in the full sensitive wavelength range of MCT up to the cut-off of 10.5 μm.

  13. The marine diversity spectrum (United States)

    Reuman, Daniel C; Gislason, Henrik; Barnes, Carolyn; Mélin, Frédéric; Jennings, Simon


    Distributions of species body sizes within a taxonomic group, for example, mammals, are widely studied and important because they help illuminate the evolutionary processes that produced these distributions. Distributions of the sizes of species within an assemblage delineated by geography instead of taxonomy (all the species in a region regardless of clade) are much less studied but are equally important and will illuminate a different set of ecological and evolutionary processes. We develop and test a mechanistic model of how diversity varies with body mass in marine ecosystems. The model predicts the form of the ‘diversity spectrum’, which quantifies the distribution of species' asymptotic body masses, is a species analogue of the classic size spectrum of individuals, and which we have found to be a new and widely applicable description of diversity patterns. The marine diversity spectrum is predicted to be approximately linear across an asymptotic mass range spanning seven orders of magnitude. Slope −0·5 is predicted for the global marine diversity spectrum for all combined pelagic zones of continental shelf seas, and slopes for large regions are predicted to lie between −0·5 and −0·1. Slopes of −0·5 and −0·1 represent markedly different communities: a slope of −0·5 depicts a 10-fold reduction in diversity for every 100-fold increase in asymptotic mass; a slope of −0·1 depicts a 1·6-fold reduction. Steeper slopes are predicted for larger or colder regions, meaning fewer large species per small species for such regions. Predictions were largely validated by a global empirical analysis. Results explain for the first time a new and widespread phenomenon of biodiversity. Results have implications for estimating numbers of species of small asymptotic mass, where taxonomic inventories are far from complete. Results show that the relationship between diversity and body mass can be explained from the dependence of predation behaviour

  14. Stoppage in Autism Spectrum Disorders

    DEFF Research Database (Denmark)

    Grønborg, Therese Koops; Hansen, Stefan Nygaard; Nielsen, Svend V


    of bias in sibling recurrence risk estimation. This study investigated whether stoppage occurs in Danish families with a firstborn child diagnosed with autism spectrum disorders, and if stoppage was differential. We found that stoppage occurs moderately in Danish families affected by autism spectrum...... disorders, and that stoppage is differential. However, differential stoppage is a minor source of estimation bias in Danish sibling recurrence risk studies of autism spectrum disorders....

  15. Rotational spectrum of tryptophan

    Energy Technology Data Exchange (ETDEWEB)

    Sanz, M. Eugenia, E-mail:; Cabezas, Carlos, E-mail:; Mata, Santiago, E-mail:; Alonso, Josè L., E-mail: [Grupo de Espectroscopia Molecular (GEM), Edificio Quifima, Laboratorios de Espectroscopia y Bioespectroscopia, Unidad Asociada CSIC, Parque Científico Uva, Universidad de Valladolid, 47011 Valladolid (Spain)


    The rotational spectrum of the natural amino acid tryptophan has been observed for the first time using a combination of laser ablation, molecular beams, and Fourier transform microwave spectroscopy. Independent analysis of the rotational spectra of individual conformers has conducted to a definitive identification of two different conformers of tryptophan, with one of the observed conformers never reported before. The analysis of the {sup 14}N nuclear quadrupole coupling constants is of particular significance since it allows discrimination between structures, thus providing structural information on the orientation of the amino group. Both observed conformers are stabilized by an O–H···N hydrogen bond in the side chain and a N–H···π interaction forming a chain that reinforce the strength of hydrogen bonds through cooperative effects.

  16. Electromagnetic spectrum management system (United States)

    Seastrand, Douglas R.


    A system for transmitting a wireless countermeasure signal to disrupt third party communications is disclosed that include an antenna configured to receive wireless signals and transmit wireless counter measure signals such that the wireless countermeasure signals are responsive to the received wireless signals. A receiver processes the received wireless signals to create processed received signal data while a spectrum control module subtracts known source signal data from the processed received signal data to generate unknown source signal data. The unknown source signal data is based on unknown wireless signals, such as enemy signals. A transmitter is configured to process the unknown source signal data to create countermeasure signals and transmit a wireless countermeasure signal over the first antenna or a second antenna to thereby interfere with the unknown wireless signals.

  17. Autism Spectrum Disorders

    Directory of Open Access Journals (Sweden)

    Rebecca E. Rosenberg


    Full Text Available We used a national online registry to examine variation in cumulative prevalence of community diagnosis of psychiatric comorbidity in 4343 children with autism spectrum disorders (ASD. Adjusted multivariate logistic regression models compared influence of individual, family, and geographic factors on cumulative prevalence of parent-reported anxiety disorder, depression, bipolar disorder, and attention deficit/hyperactivity disorder or attention deficit disorder. Adjusted odds of community-assigned lifetime psychiatric comorbidity were significantly higher with each additional year of life, with increasing autism severity, and with Asperger syndrome and pervasive developmental disorder—not otherwise specified compared with autistic disorder. Overall, in this largest study of parent-reported community diagnoses of psychiatric comorbidity, gender, autistic regression, autism severity, and type of ASD all emerged as significant factors correlating with cumulative prevalence. These findings could suggest both underlying trends in actual comorbidity as well as variation in community interpretation and application of comorbid diagnoses in ASD.

  18. Electromagnetic spectrum management system

    Energy Technology Data Exchange (ETDEWEB)

    Seastrand, Douglas R.


    A system for transmitting a wireless countermeasure signal to disrupt third party communications is disclosed that include an antenna configured to receive wireless signals and transmit wireless counter measure signals such that the wireless countermeasure signals are responsive to the received wireless signals. A receiver processes the received wireless signals to create processed received signal data while a spectrum control module subtracts known source signal data from the processed received signal data to generate unknown source signal data. The unknown source signal data is based on unknown wireless signals, such as enemy signals. A transmitter is configured to process the unknown source signal data to create countermeasure signals and transmit a wireless countermeasure signal over the first antenna or a second antenna to thereby interfere with the unknown wireless signals.

  19. Identification and classification of textile fibres using ATR-FT-IR spectroscopy with chemometric methods. (United States)

    Peets, Pilleriin; Leito, Ivo; Pelt, Jaan; Vahur, Signe


    The possibility of classification of single- and two-component textile materials using ATR-FT-IR spectra and chemometric methods, principal component analysis (PCA) and discriminant analysis, was assessed. Altogether 89 textile samples belonging to 26 different types (11 one- and 15 two-component textiles) were investigated. It was found that PCA classification using only two or three principal components (PCs) enables identifying different one- and two-component textiles, although with two important limitations: it was not always possible to distinguish between the cellulose-based fibres (cotton, linen and in some cases viscose) and it was only partly possible to distinguish between silk and wool. The statistical discriminant analysis can use as many PCs as there are sample classes and due to that can discriminate between single-component fibres, including viscose from linen and cotton as well as silk from wool. Besides that, in both of these cases, involving optical microscopy as an additional technique enabled unequivocal identification of the fibres. The possibilities of semi-quantitative analysis of mixed fibres (cotton-polyester, wool-polyester and wool-polyamide) with PCA were investigated and it was found that approximate quantitative composition is obtainable if for the mixed fibre sample a number of spectra are averaged in order to minimize the effect of structural inhomogeneity. For approximate content determination 25 spectra of selected two-component samples were registered for calibration and the averaged spectrum for each sample was computed. Due to the structural inhomogeneity of mixed textiles, obtaining accurate quantitative composition from real samples is not possible with ATR-FT-IR. The main problems with ATR-FT-IR-PCA classification are (1) difficulties in getting high quality spectra from some textiles (e.g. polyacrylic), (2) inhomogeneity of the textile fibres in the case of two-component fibres and (3) intrinsic similarity between the

  20. High resolution IR spectroscopy of acetylene-furan in ultracold helium nanodroplets. (United States)

    Metzelthin, Anja; Birer, Ozgür; Sánchez-García, Elsa; Havenith, Martina


    We have measured the IR spectrum of the acetylene-furan complex in ultracold helium nanodroplets in the region of the nu(3) CH(asym)-stretch vibration of the acetylene (between 3240 and 3300 cm(-1)). We have observed eight bands that can be attributed to acetylene-furan complexes. Two of these bands are assigned to two different isomers of the 1:1 acetylene-furan complex. The vibrational band at 3267.4 cm(-1) is assigned to the CH(asym)-stretch vibration of the dimer structure with the C-H of the acetylene being attached to the pi-system of the furan. The peak at 3272.1 cm(-1) is assigned to the CH(asym)-stretch vibration of the dimer structure with the C-H of the acetylene being attached to the oxygen atom of the furan. These assignments are confirmed by additional measurements of the spectrum of the (13)C-acetylene-furan complex.


    Directory of Open Access Journals (Sweden)

    Nur Said


    Full Text Available Penelitian ini difokuskan pada tiga hal: (1 Apakah karakteristik lingkup isi Syi’ir Muslimat?, (2 Bagai-manakah kondisi sosial budaya pada saat naskah ditulis oleh penulis?, (3 Apa nilai-nilai pendidikan moral bagi perempuan Muslim di isi Syi’ir Muslimat dalam perspektif gender?. Penelitian ini menggunakan pendekatan filologi dengan meningkatkan penggunaan analisis gender. Hasil dari penelitian ini adalah: Pertama, Syi’ir Muslimat ditulis oleh Nyai Wanifah, seorang wanita yang hidup pada zaman kolonial Belanda dipesantren tradisi di Kudus, Jawa Tengah. Kedua, beberapa nilai pendidikan moral di Syi’ir Muslimatantara lain: (1 Pentingnya pendidikan moral, (2 Bahaya perempuan bodoh; (3 Pentingnya belajar bagi perempuan di usia dini, (4 Etika menghias diri; (5 Bahaya materialisme, (6 Etika hubungan keluarga; (7 Dari rumah untuk mencapai surga; (8 Berhati-hatilah dengan tipu iblis; (9 Hindari perzinahan; (10 yang penting dari penutupan aurot; (11 yang ditujukan kepada orang tua. Ketiga, meskipun ada beberapa senyawa yang bias gender dalam Syi’ir Muslimat misalnya: (a Ada penjelasan yang menunjukkan bahwa perempuan lebih rendah dibandingkan laki-laki dalam derajat, (2 Pernyataan bahwa wanita bicara dibandingkan laki-laki, (3 wanita hanya cocok di wilayah domestik; Namun secara umum nasihat di syi’ir masih sangat relafen dalam konteks sekarang, terutama untuk memberikan solusi alternatif dalam merespon krisis moral bangsa terutama pada wanita generasi muda. Kata kunci: Syi’ir Muslimat, Pendidikan Karakter, Analisis Gender. This study focused on three things: (1 What is the characteristics of the scope of contents of Syi’ir Muslimat?, (2 What is the socio-cultural conditions at the time the manuscript was written by the author?, (3 What are the moral education values for Muslim women in the content of Syi’ir Muslimat in the perspective of gender?. This research uses a philological approach with enhanced use of gender analysis. The

  2. GPCR and IR genes in Schistosoma mansoni miracidia. (United States)

    Liang, Di; Zhao, Min; Wang, Tianfang; McManus, Donald P; Cummins, Scott F


    Schistosoma species are responsible for the disease schistosomiasis, a highly prevalent helminthic disease that requires a freshwater snail as intermediate host. The S. mansoni free-living miracidium must utilize olfaction to find a suitable snail host, and certain types of rhodopsin G protein-coupled receptors (GPCRs) and ionotropic receptors (IRs) have been identified as olfactory receptors in other animal phyla. The Schistosoma genome project, together with the recent availability of proteomic databases, allowed for studies to explore receptors within S. mansoni, some of which may contribute to host finding. We have identified 17 rhodopsin-type GPCR sequences in S. mansoni belonging to four subclasses, including ligand-specific GPCRs (i.e. neuropeptide and opsin). RT-PCR demonstrated the expression of nine out of the 17 GPCRs in the free-living miracidia, each of which have been characterized for homology to S. haematobium. Among the nine GPCRs, two are predicted as Gq-opsins. We also describe the characterization of a Schistosoma-encoded IR based on similarity with other species IR and conservation of IR-like domains. Schistosoma mansoni IR is expressed in miracidia at 3 and 6 h post-hatch. The identification of receptors in S. mansoni miracidia, presented here, contributes not only to further understanding of Schistosoma biology and signal transduction but also provides a basis for approaches that may modify parasite behaviour.

  3. A Predictive WFC3/IR Dark Current Model (United States)

    Sunnquist, Ben; Baggett, Sylvia; Long, Knox S.


    The dark current in the WFC3/IR detector has remained stable at about 0.021 DN/s (0.049 e-/s) since launch; there are no long term increases or decreases. However, image-to-image variations in the full-frame dark current levels as high as 0.014 DN/s (0.032 e-/s) exist that have yet to be explained. These variations limit the accuracy of the dark calibration carried out by the CALWF3 pipeline. In an attempt to address this issue, we have examined the relationships of hundreds of HST telemetry parameters to the dark current level. We find that the dark variations depend on where HST is in relation to the Sun and that the rate of change of certain telemetry parameters, such as the input voltage to WFC3 and the IR detector electronics board temperature, throughout this day/night cycle correlate with the IR dark rate. Using reference pixel and input voltage information, we construct a full-frame WFC3/IR dark current model capable of predicting the dark rate in WFC3/IR observations. Tests show that this model reduces the error in the mean dark rate by more than a factor of two compared to the current superdark calibration method carried out by the CALWF3 pipeline. The shape of the dark current image is calibrated similarly using either of these calibration methods.

  4. Evaluasi Integritas Sistem Struktur Jembatan Dr. Ir. Soekarno

    Directory of Open Access Journals (Sweden)

    Ady Wijayanto


    Full Text Available Dr. Ir. Soekarno Bridge is the long span bridge which to be the Manado city landmark. To calculate the Dr. Ir. Soekarno Bridge’s feasibility, integrated evaluation need to know the bridge physical condition reliability. The purpose of this analysis is for reviewing and evaluating the entire Dr. Ir. Soekarno Bridge integrity. Every structure has natural frequency characteristic, which describes the structure strength, stiffness and integrity. The vibration record data sources are dynamic loading test and accelerometer sensor records. Perception and comfortable level the bridge users evaluated by the vibration record data. Perception and comfortable level the bridge users evaluated by the vibration record data. The accelerometer sensors records on X, Y, and Z directions. The Fast Fourier Transform (FFT analysis carries out to exchange time domain to frequency domain. The frequency domain graphics filtered by ISO 2631-1 formula. Perception and comfortable level the Dr. Ir. Soekarno Bridge users are still in the comfort condition, so this bridge is proper to pass through the vehicles. Based on the Weibull Distribution, Dr. Ir. Soekarno Bridge has service life until 100 years as long as the plan service life.

  5. Room temperature mid-IR single photon spectral imaging

    CERN Document Server

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter


    Spectral imaging and detection of mid-infrared (mid-IR) wavelengths are emerging as an enabling technology of great technical and scientific interest; primarily because important chemical compounds display unique and strong mid-IR spectral fingerprints revealing valuable chemical information. While modern Quantum cascade lasers have evolved as ideal coherent mid-IR excitation sources, simple, low noise, room temperature detectors and imaging systems still lag behind. We address this need presenting a novel, field-deployable, upconversion system for sensitive, 2-D, mid-IR spectral imaging. Measured room temperature dark noise is 0.2 photons/spatial element/second, which is a billion times below the dark noise level of cryogenically cooled InSb cameras. Single photon imaging and up to 200 x 100 spatial elements resolution is obtained reaching record high continuous wave quantum efficiency of about 20 % for polarized incoherent light at 3 \\mum. The proposed method is relevant for existing and new mid-IR applicat...

  6. Rapid discrimination of cultivated Codonopsis lanceolata in different ages by FT-IR and 2DCOS-IR (United States)

    Zhu, Yun; Xu, Chang-hua; Huang, Jian; Li, Guo-yu; Liu, Xin-Hu; Sun, Su-qin; Wang, Jin-hui


    Deodeok (Codonopsis lanceolata) root, a traditional Chinese herbal medicine, has been used to treat lung ailments, rheumatism, menstrual disturbance and bruises with a long history in China and some other Asian countries. In this study, four types of Deodeok with different growth years were discriminated and identified by a Tri-step infrared spectroscopy method (Fourier transform-infrared spectroscopy (conventional FT-IR) coupled with second derivative infrared spectroscopy (SD-IR) and two dimensional correlation infrared spectroscopy(2DCOS-IR) under thermal perturbation. Although only small differences were found in the FT-IR spectra of the samples, the positions and intensities of peaks around 1736, 1634, 1246, 1055, 1033, 818, 779 cm-1 could be considered as the key factors for discriminating them. The differences among them were amplified by their SD-IR spectra. The 2DCOS-IR spectra provided obvious dynamic chemical structure information of Deodeok samples, which present different particular auto peak clusters in the range of 875-1130 cm-1 and 1170-1630 cm-1, respectively. It was demonstrated that the content of triterpene were decreasing when C. lanceolata were growing older, but the relative content of saccharides initially increased and decreased significantly afterwards. It indicated a general trend that the content of polysaccharides accumulated with increasing years. Specifically, the content of polysaccharides accumulated in the root of 2-year-old plant was the lowest, 4-years-old was the highest, and then the content decreased gradually. Furthermore, according to the differences of locations and intensities of auto-peaks in 2D-IR spectra, the integral changes of components were revealed. This study offers a promising method inherent with cost-effective and time-saving to characterize and discriminate the complicated system like Deodeok.

  7. Determination of effective resonance energy for the 193Ir(n,γ)194Ir reaction by the cadmium ratio method (United States)

    Budak, Mustafa Guray; Karadag, Mustafa; Yücel, Haluk


    In this work, the effective resonance energy, Ebarr -value for the 193Ir(n,γ)194Ir reaction was measured using cadmium ratio method. A dual monitor (197Au-98Mo), which has convenient resonance properties, was employed for characterization of the irradiation sites. Then analytical grade iridium oxide samples diluted with CaCO3 to lower neutron self-shielding effect stacked in small cylindrical Teflon boxes were irradiated once with a 1 mm thick Cd cylindrical box placed in a thermalized neutron field of an 241Am-Be neutron source then without it. The activities produced in samples during 193Ir(n,γ)194Ir reaction were measured using a p-type HPGe detector γ-ray spectrometer with a 44.8% relative efficiency. The correction factors for thermal, epithermal neutron self-shielding (Gth, Gepi), true coincidence summing (Fcoi) and gamma-ray self-absorption (Fs) effects were determined with appropriate approaches and programs. Thus, the experimental Ebarr -value was determined to be 2.65 ± 0.61 eV for 193Ir target nuclide. The recent data for Q0 and FCd values for Ebarr determination were based on k0-NAA online database. The present experimental Ebarr value was calculated and compared with more recent values for Q0 and FCd for 193Ir. Additionally, the Ebarr -values was theoretically calculated from the up-to-date resonance data obtained from ENDF/B VII library using two different approaches. Since there is no experimentally determined Ebarr -value for the 193Ir isotope, the results are compared with the calculated ones given in the literature.

  8. Impact and radiation influence on solid hydrocarbon transformation and structuring (by IR-spectroscopy) (United States)

    Kovaleva, O.


    Solid hydrocarbons (bitumens)-typical specimens of natural organic minerals-are one of the most essential objects of petroleum geology and at the same time-one of the least investigated objects of organic mineralogy. Moreover they can be treated as admissible analogs of meteorite carbonaceous materials. According to terrestrial analog of meteoritic organic matter it's possible to estimate the chemical structure of extraterrestrial matter. Further investigation of impact force and radiation influence on the bitumen chemical structure change will make it possible to connect them with extraterrestrial organic matter. This work represents the research of impact influence on the processes of transformation and structuring of asphaltite and changes in the molecular structure of solid bitumens constituting the carbonization series (asphaltite--kerite--anthraxolite), which were subjected to the impact of high radiation doses (10 and 100 Mrad) by infrared spectroscopy (IRS). In percussion experiments peak pressure varied from 10 to 63.4 GPa; temperature - from the first tens degrees to several hundreds degrees Celsius. The radiation experiment was performed in the Arzamas-16 Federal Nuclear Center in line with conditions described in [1]. Asphaltite, which sustained shock load from 17.3 to 23 GPa, didn't undergo considerable changes in its element composition. Though their IR-spectra differ from the spectrum of initial asphaltite by heightened intensity of absorption bands of aromatic groups, as well as by insignificant rise of heterogroups and condensed structures oscillation strength. At the same time the intensity of aliphatic (СН2 and СН3) groups absorption hasn't changed. Probably there've just been the carbon and hydrogen atomic rearrangement. However, shock load up to 26.7 GPa leads to asphaltite transformation into the albertite. There've been observed the intensity decrease of aliphatic groups on its IR-spectrum. Under growth of shock load up to 60 GPa bitumen

  9. Detection of hazelnut oil adulteration using FT-IR spectroscopy. (United States)

    Ozen, Banu F; Mauer, Lisa J


    Fourier transform infrared spectroscopy (FT-IR) was used to detect the adulteration of hazelnut oil with different types of oils and to detect the adulteration of extra-virgin olive oil with hazelnut oil. Spectra of hazelnut oil, seven other types of oils, extra-virgin olive oil, and the adulterated oils were collected with a FT-IR equipped with a ZnSe-ATR accessory and a MCTA detector. Discriminant analysis and partial least-squares analysis were used to analyze the data. Classification of hazelnut oil, olive oil, and the other types of oils was achieved successfully with FT-IR. The detection level for sunflower oil adulteration of hazelnut oil was 2%, and the correlation coefficient for the PLS model was 0.99. Adulteration of virgin olive oil with hazelnut oil could be detected only at levels of 25% and higher.

  10. IR induced photochemistry of glycolaldehyde in nitrogen matrix (United States)

    Duvernay, Fabrice; Butscher, Teddy; Chiavassa, Thierry; Coussan, Stephane


    The conformational equilibria and IR isomerisation processes of glycolaldehyde (HOCH2CHO) conformers have been studied at low temperature in nitrogen cryogenic matrix. The effects of selective IR irradiation, in the νOH and νCH domains, have been followed by FTIR spectroscopy. After deposition the main form is the most stable one, CC (Cis-Cis), which features an intramolecular hydrogen bond. Upon selective IR irradiation, this latter form is able to interconvert into two open forms, those called TT (Trans-Trans), and TG (Trans-Gauche). From TT and TG forms, no recovering (by tunneling, dark process, irradiation, annealing, etc.) of the initial state (i.e. CC regeneration) has been observed. However, a TT ⇌ TG thermal equilibrium is observed with a standard reaction enthalpy about 0.37 kJ mol-1.

  11. IR Spectroscopy of Gasses Evolved During Roasting Coffee Beans (United States)

    Clain, Alexander; Capaldi, Xavier; Amanuel, Samuel


    We measured the IR spectra of the gasses that evolve during roasting of coffee beans. The spectra recorded at different temperature revealed that the intensity of certain IR bands increase as the temperature increases. For instance, the intensity of the CO2 band increased by a factor of four and reached a plateau as the roasting temperature approached 200°C. The intensity further increased as the temperature increased above 200°C, however, in two steps. Similarly the intensity of the OH bands monotonically increased until 200°C and then increased further in two rapid steps above 200°C. The temperature ranges where IR intensities change in two steps coincides with the temperature ranges where typically commercial roasting is done and where the first and second ``cracks'' are heard during roasting.

  12. IR thermography for dynamic detection of laminar-turbulent transition (United States)

    Simon, Bernhard; Filius, Adrian; Tropea, Cameron; Grundmann, Sven


    This work investigates the potential of infrared (IR) thermography for the dynamic detection of laminar-turbulent transition. The experiments are conducted on a flat plate at velocities of 8-14 m/s, and the transition of the laminar boundary layer to turbulence is forced by a disturbance source which is turned on and off with frequencies up to 10 Hz. Three different heating techniques are used to apply the required difference between fluid and structure temperature: a heated aluminum structure is used as an internal structure heating technique, a conductive paint acts as a surface bounded heater, while an IR heater serves as an example for an external heating technique. For comparison of all heating techniques, a normalization is introduced and the frequency response of the measured IR camera signal is analyzed. Finally, the different heating techniques are compared and consequences for the design of experiments on laminar-turbulent transition are discussed.

  13. Causality, Analyticity and an IR Obstruction to UV Completion

    CERN Document Server

    Adams, A; Dubovsky, S; Nicolis, A; Rattazzi, R; Adams, Allan; Arkani-Hamed, Nima; Dubovsky, Sergei; Nicolis, Alberto; Rattazzi, Riccardo


    We argue that certain apparently consistent low-energy effective field theories described by local, Lorentz-invariant Lagrangians, secretly exhibit macroscopic non-locality and cannot be embedded in any UV theory whose S-matrix satisfies canonical analyticity constraints. The obstruction involves the signs of a set of leading irrelevant operators, which must be strictly positive to ensure UV analyticity. An IR manifestation of this restriction is that the "wrong" signs lead to superluminal fluctuations around non-trivial backgrounds, making it impossible to define local, causal evolution, and implying a surprising IR breakdown of the effective theory. Such effective theories can not arise in quantum field theories or weakly coupled string theories, whose S-matrices satisfy the usual analyticity properties. This conclusion applies to the DGP brane-world model modifying gravity in the IR, giving a simple explanation for the difficulty of embedding this model into controlled stringy backgrounds, and to models of...

  14. IR Spectroscopy and Photo-Chemistry of Extraterrestrial Ices (United States)

    Bernstein, Max P.; Mastrapa, Rachel; Elsila, Jamie; Sandford, Scott


    Dense molecular clouds from which planetary systems form and the outer Solar System are both cold environments dominated by ices. Infrared (IR) spectroscopy is used to probe these ices, but the IR absorptions of molecules depend on the conditions. As a result appropriate lab data is needed to correctly fit spectra of extraterrestrial ices. Such fits have shown that most of these ices are composed primarily of H2O, but also contain 1-10 percent of other simple molecules such as CO2, CO, CH4, & NH3;. We shall present near IR spectra of ice mixtures of relevance to icy outer Solar System bodies and show that they still hold surprises, such as the Cheshire cat-like CO2 (2v3) overtone near 2.134 micrometers (4685 cm-1) that is absent from spectra of pure CO2 but present in H2O-CO2 mixtures.

  15. Strong-field physics with mid-IR fields

    CERN Document Server

    Wolter, Benjamin; Baudisch, Matthias; Sclafani, Michele; Hemmer, Michaël; Senftleben, Arne; Schröter, Claus Dieter; Ullrich, Joachim; Moshammer, Robert; Biegert, Jens


    Strong-field physics is currently experiencing a shift towards the use of mid-IR driving wavelengths. This is because they permit conducting experiments unambiguously in the quasi-static regime and enable exploiting the effects related to ponderomotive scaling of electron recollisions. Initial measurements taken in the mid-IR immediately led to a deeper understanding of photo-ionization and allowed a discrimination amongst different theoretical models. Ponderomotive scaling of rescattering has enabled new avenues towards time resolved probing of molecular structure. Essential for this paradigm shift was the convergence of two experimental tools: 1) intense mid-IR sources that can create high energy photons and electrons while operating within the quasi-static regime, and 2) detection systems that can detect the generated high energy particles and image the entire momentum space of the interaction in full coincidence. Here we present a unique combination of these two essential ingredients, namely a 160\\~kHz mi...

  16. Modeling the Frequency and Costs Associated with Postsurgical Gastrointestinal Adverse Events for Tapentadol IR versus Oxycodone IR (United States)

    Paris, Andrew; Kozma, Chris M.; Chow, Wing; Patel, Anisha M.; Mody, Samir H.; Kim, Myoung S.


    Background Few studies have estimated the economic effect of using an opioid that is associated with lower rates of gastrointestinal (GI) adverse events (AEs) than another opioid for postsurgical pain. Objective To estimate the number of postsurgical GI events and incremental hospital costs, including potential savings, associated with lower GI AE rates, for tapentadol immediate release (IR) versus oxycodone IR, using a literature-based calculator. Methods An electronic spreadsheet–based cost calculator was developed to estimate the total number of GI AEs (ie, nausea, vomiting, or constipation) and incremental costs to a hospital when using tapentadol IR 100 mg versus oxycodone IR 15 mg, in a hypothetical cohort of 1500 hospitalized patients requiring short-acting opioids for postsurgical pain. Data inputs were chosen from recently published, well-designed studies, including GI AE rates from a previously published phase 3 clinical trial of postsurgical patients who received these 2 opioids; GI event–related incremental length of stay from a large US hospital database; drug costs using wholesale acquisition costs in 2011 US dollars; and average hospitalization cost from the 2009 Healthcare Cost and Utilization Project database. The base case assumed that 5% (chosen as a conservative estimate) of patients admitted to the hospital would shift from oxycodone IR to tapentadol IR. Results In this hypothetical cohort of 1500 hospitalized patients, replacing 5% of oxycodone IR 15-mg use with tapentadol IR 100-mg use predicted reductions in the total number of GI events from 1095 to 1085, and in the total cost of GI AEs from $2,978,400 to $2,949,840. This cost reduction translates to a net savings of $22,922 after factoring in drug cost. For individual GI events, the net savings were $26,491 for nausea; $12,212 for vomiting; and $7187 for constipation. Conclusion Using tapentadol IR in place of a traditional μ-opioid shows the potential for reduced GI events and

  17. Rapid discrimination of extracts of Chinese propolis and poplar buds by FT-IR and 2D IR correlation spectroscopy (United States)

    Wu, Yan-Wen; Sun, Su-Qin; Zhao, Jing; Li, Yi; Zhou, Qun


    The extract of Chinese propolis (ECP) has recently been adulterated with that of poplar buds (EPB), because most of ECP is derived from the poplar plant, and ECP and EPB have almost identical chemical compositions. It is very difficult to differentiate them by using the chromatographic methods such as high performance liquid chromatography (HPLC) and gas chromatography (GC). Therefore, how to effectively discriminate these two mixtures is a problem to be solved urgently. In this paper, a rapid method for discriminating ECP and EPB was established by the Fourier transform infrared (FT-IR) spectra combined with the two-dimensional infrared correlation (2D IR) analysis. Forty-three ECP and five EPB samples collected from different areas of China were analyzed by the FT-IR spectroscopy. All the ECP and EPB samples tested show similar IR spectral profiles. The significant differences between ECP and EPB appear in the region of 3000-2800 cm -1 of the spectra. Based on such differences, the two species were successfully classified with the soft independent modeling of class analogy (SIMCA) pattern recognition technique. Furthermore, these differences were well validated by a series of temperature-dependent dynamic FT-IR spectra and the corresponding 2D IR plots. The results indicate that the differences in these two natural products are caused by the amounts of long-chain alkyl compounds (including long-chain alkanes, long-chain alkyl esters and long chain alkyl alcohols) in them, rather than the flavonoid compounds, generally recognized as the bioactive substances of propolis. There are much more long-chain alkyl compounds in ECP than those in EPB, and the carbon atoms of the compounds in ECP remain in an order Z-shaped array, but those in EPB are disorder. It suggests that FT-IR and 2D IR spectroscopy can provide a valuable method for the rapid differentiation of similar natural products, ECP and EPB. The IR spectra could directly reflect the integrated chemical


    Energy Technology Data Exchange (ETDEWEB)

    Forbrich, Jan, E-mail: [University of Vienna, Department of Astrophysics, Türkenschanzstraße 17, A-1180 Vienna (Austria); Rodríguez, Luis F.; Palau, Aina; Zapata, Luis A. [Instituto de Radioastronomía y Astrofísica, UNAM, Apdo. Postal 3-72 (Xangari), 58089 Morelia, Michoacán (Mexico); Muzerolle, James [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Gutermuth, Robert A. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States)


    LRLL 54361 is an infrared source located in the star-forming region IC 348 SW. Remarkably, its infrared luminosity increases by a factor of 10 over roughly one week every 25.34 days. To understand the origin of these remarkable periodic variations, we obtained sensitive 3.3 cm JVLA radio continuum observations of LRLL 54361 and its surroundings in six different epochs: three of them during the IR-on state and three during the IR-off state. The radio source associated with LRLL 54361 remained steady and did not show a correlation with the IR variations. We suggest that the IR is tracing the results of fast (with a timescale of days) pulsed accretion from an unseen binary companion, while the radio traces an ionized outflow with an extent of ∼100 AU that smooths out the variability over a period of the order of a year. The average flux density measured in these 2014 observations, 27 ± 5 μJy, is about a factor of two less than that measured about 1.5 years before, 53 ± 11 μJy, suggesting that variability in the radio is present, but over larger timescales than in the IR. We discuss other sources in the field, in particular two infrared/X-ray stars that show rapidly varying gyrosynchrotron emission.

  19. Low Dose IR Creates an Oncogenic Microenvironment by Inducing Premature

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Zhi-Min [Harvard School of Public Health


    Introduction Much of the work addressing ionizing radiation-induced cellular response has been carried out mainly with the traditional cell culture technique involving only one cell type, how cellular response to IR is influenced by the tissue microenvironment remains elusive. By use of a three-dimensional (3D) co-culture system to model critical interactions of different cell types with their neighbors and with their environment, we recently showed that low-dose IR-induced extracellular signaling via the tissue environment affects profoundly cellular responses. This proposal aims at determining the response of mammary epithelial cells in a tissue-like setting.

  20. Room temperature mid-IR single photon spectral imaging

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian


    modern Quantum cascade lasers have evolved as ideal coherent mid-IR excitation sources, simple, low noise, room temperature detectors and imaging systems still lag behind. We address this need presenting a novel, field-deployable, upconversion system for sensitive, 2-D, mid-IR spectral imaging. Measured...... room temperature dark noise is 0.2 photons/spatial element/second, which is a billion times below the dark noise level of cryogenically cooled InSb cameras. Single photon imaging and up to 200 x 100 spatial elements resolution is obtained reaching record high continuous wave quantum efficiency of about...

  1. Feminism and IR and the Conditions for Critical Dialogue


    Nicholls, Esteban


    My objective in this paper is to problematize the call for dialogue and engagement between feminists and non-feminist International Relations (IR) scholars. I will concentrate on two pieces of scholarship to discuss the issue of dialogue: first, Robert Keohane’s “Beyond Dychotomies: Conversations between International Relations and Feminist Theory’s” (Keohane, 1998); and second, Anne Tickner’s (1997) “You Just don’t Understand: Troubled Engagements between Feminists and IR Theorists.” In both...

  2. Nonlinear optical processes for the mid-IR region (United States)

    Schepler, K. L.; Barnes, N. P.


    The 2 - 5 micron (mid-IR) region is of interest for a number of applications. Efficient up-conversion and down-conversion techniques are being developed to obtain optical sources at mid-IR wavelengths. These techniques are reviewed and recent results using AgGaSe2 are reported. Gain in AgGaSe2 as high as 13 has been observed with a pump wavelength of 1.73 microns and a signal wavelength of 3.39 microns. Optical parametric oscillation in the 2.9 - 6.8 micron region has also been demonstrated.

  3. UV, visible and IR laser interaction with gelatine

    Energy Technology Data Exchange (ETDEWEB)

    Oujja, M [Institute of Physical Chemistry Rocasolano, CSIC, Serrano 119, 28006 Madrid (Spain); Rebollar, E [Institute of Physical Chemistry Rocasolano, CSIC, Serrano 119, 28006 Madrid (Spain); Abrusci, C [Institute of Polymer Science and Technology, CSIC, Juan de la Cierva 3, 28006 Madrid (Spain); Amo, A Del [Filmoteca Espanola, Magdalena 10, 28012 Madrid (Spain); Catalina, F [Institute of Polymer Science and Technology, CSIC, Juan de la Cierva 3, 28006 Madrid (Spain); Castillejo, M [Institute of Physical Chemistry Rocasolano, CSIC, Serrano 119, 28006 Madrid (Spain)


    In this work we investigate the effects on gelatine films of nanosecond pulsed laser irradiation at different laser wavelengths from the UV to the IR at 248, 266, 355, 532 and 1064 nm. We compared gelatines differing in gel strength values (Bloom 75 and 225) and in crosslinking degree. Formation of bubbles at the wavelengths in the UV (248 and 266 nm), melting and resolidification at 355 nm, and formation of craters by ablation in the VIS and IR (532 and 1064 nm) are the observed morphological changes. On the other hand, changes of the fluorescence behaviour of the films upon UV irradiation reveal chemical modifications of photolabile chromophores.

  4. Dynamic Spectrum Sharing among Femtocells

    DEFF Research Database (Denmark)

    Da Costa, Gustavo Wagner Oliveira


    The ever-growing demand for mobile broadband is leading to an imminent spectrum scarcity. In order to cope with such situation dynamic spectrum sharing and the widespread deployment of small cells (femtocells) are promising solutions. Delivering such a view is not short of challenges. Massive...

  5. Autism Spectrum Disorder - Multiple Languages (United States)

    ... Supplements Videos & Tools You Are Here: Home → Multiple Languages → All Health Topics → Autism Spectrum Disorder URL of this page: https://medlineplus. ... V W XYZ List of All Topics All Autism Spectrum Disorder - Multiple Languages To use the sharing features on this page, ...

  6. Indecomposable polynomials and their spectrum (United States)

    Bodin, Arnaud; Debes, Pierre; Najib, Salah

    We address some questions concerning indecomposable polynomials and their spectrum. How does the spectrum behave via reduction or specialization, or via a more general ring morphism? Are the indecomposability properties equivalent over a field and over its algebraic closure? How many polynomials are decomposable over a finite field?

  7. Photoluminescence properties of facial- and meridional-Ir(ppy){sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Ide, Noritaka [Department of Physics and Electronics, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531 (Japan)]. E-mail:; Matsusue, Noriyuki [Department of Physics and Electronics, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531 (Japan); Kobayashi, Takashi [Department of Physics and Electronics, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531 (Japan); Naito, Hiroyoshi [Department of Physics and Electronics, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531 (Japan)


    Photoluminescence (PL) properties of tris(2-phenylpyridine) iridium [Ir(ppy){sub 3}] thin films which contain both facial- and meridional-Ir(ppy){sub 3} have been investigated. It is found that the thin films show red-shifted and broader PL spectra in comparison with those of the facial-Ir(ppy){sub 3} [fac-Ir(ppy){sub 3}] thin films. PL quantum efficiency of the meridional-Ir(ppy){sub 3} [mer-Ir(ppy){sub 3}] doped 4,4'-N,N'-dicarbazole-biphenyl (CBP) thin films is estimated to be 30% from PL spectra and PL quantum efficiencies of Ir(ppy){sub 3} [the mixture of fac-Ir(ppy){sub 3} and mer-Ir(ppy){sub 3}] doped CBP thin films. The PL quantum efficiency is much lower than that of fac-Ir(ppy){sub 3} doped CBP thin films.

  8. Rotational Spectrum of Saccharine (United States)

    Alonso, Elena R.; Mata, Santiago; Alonso, José L.


    A significant step forward in the structure-activity relationships of sweeteners was the assignment of the AH-B moiety in sweeteners by Shallenberger and Acree. They proposed that all sweeteners contain an AH-B moiety, known as glucophore, in which A and B are electronegative atoms separated by a distance between 2.5 to 4 Å. H is a hydrogen atom attached to one of the electronegative atom by a covalent bond. For saccharine, one of the oldest artificial sweeteners widely used in food and drinks, two possible B moieties exist ,the carbonyl oxygen atom and the sulfoxide oxygen atom although there is a consensus of opinion among scientists over the assignment of AH-B moieties to HN-SO. In the present work, the solid of saccharine (m.p. 220°C) has been vaporized by laser ablation (LA) and its rotational spectrum has been analyzed by broadband CP-FTMW and narrowband MB-FTMW Fourier transform microwave techniques. The detailed structural information extracted from the rotational constants and ^{14}N nuclear quadrupole coupling constants provided enough information to ascribe the glucophore's AH and B sites of saccharine. R. S. Shallenberger, T. E. Acree. Nature 216, 480-482 Nov 1967. R. S. Shallenberger. Taste Chemistry; Blackie Academic & Professional, London, (1993).

  9. Fetal Alcohol Spectrum Disorders. (United States)

    Williams, Janet F; Smith, Vincent C


    Prenatal exposure to alcohol can damage the developing fetus and is the leading preventable cause of birth defects and intellectual and neurodevelopmental disabilities. In 1973, fetal alcohol syndrome was first described as a specific cluster of birth defects resulting from alcohol exposure in utero. Subsequently, research unequivocally revealed that prenatal alcohol exposure causes a broad range of adverse developmental effects. Fetal alcohol spectrum disorder (FASD) is the general term that encompasses the range of adverse effects associated with prenatal alcohol exposure. The diagnostic criteria for fetal alcohol syndrome are specific, and comprehensive efforts are ongoing to establish definitive criteria for diagnosing the other FASDs. A large and growing body of research has led to evidence-based FASD education of professionals and the public, broader prevention initiatives, and recommended treatment approaches based on the following premises:▪ Alcohol-related birth defects and developmental disabilities are completely preventable when pregnant women abstain from alcohol use.▪ Neurocognitive and behavioral problems resulting from prenatal alcohol exposure are lifelong.▪ Early recognition, diagnosis, and therapy for any condition along the FASD continuum can result in improved outcomes.▪ During pregnancy:◦no amount of alcohol intake should be considered safe;◦there is no safe trimester to drink alcohol;◦all forms of alcohol, such as beer, wine, and liquor, pose similar risk; and◦binge drinking poses dose-related risk to the developing fetus. Copyright © 2015 by the American Academy of Pediatrics.

  10. PINS Spectrum Identification Guide

    Energy Technology Data Exchange (ETDEWEB)

    A.J. Caffrey


    The Portable Isotopic Neutron Spectroscopy—PINS, for short—system identifies the chemicals inside munitions and containers without opening them, a decided safety advantage if the fill chemical is a hazardous substance like a chemical warfare agent or an explosive. The PINS Spectrum Identification Guide is intended as a reference for technical professionals responsible for the interpretation of PINS gamma-ray spectra. The guide is divided into two parts. The three chapters that constitute Part I cover the science and technology of PINS. Neutron activation analysis is the focus of Chapter 1. Chapter 2 explores PINS hardware, software, and related operational issues. Gamma-ray spectral analysis basics are introduced in Chapter 3. The six chapters of Part II cover the identification of PINS spectra in detail. Like the PINS decision tree logic, these chapters are organized by chemical element: phosphorus-based chemicals, chlorine-based chemicals, etc. These descriptions of hazardous, toxic, and/or explosive chemicals conclude with a chapter on the identification of the inert chemicals, e.g. sand, used to fill practice munitions.

  11. The Cu II Spectrum

    Directory of Open Access Journals (Sweden)

    Alexander Kramida


    Full Text Available New wavelength measurements in the vacuum ultraviolet (VUV, ultraviolet and visible spectral regions have been combined with available literature data to refine and extend the description of the spectrum of singly ionized copper (Cu II. In the VUV region, we measured 401 lines using a concave grating spectrograph and photographic plates. In the UV and visible regions, we measured 276 lines using a Fourier-transform spectrometer. These new measurements were combined with previously unpublished data from the thesis of Ross, with accurate VUV grating measurements of Kaufman and Ward, and with less accurate older measurements of Shenstone to construct a comprehensive list of ≈2440 observed lines, from which we derived a revised set of 379 optimized energy levels, complemented with 89 additional levels obtained using series formulas. Among the 379 experimental levels, 29 are new. Intensities of all lines observed in different experiments have been reduced to the same uniform scale by using newly calculated transition probabilities (A-values. We combined our calculations with published measured and calculated A-values to provide a set of 555 critically evaluated transition probabilities with estimated uncertainties, 162 of which are less than 20%.

  12. Comparison of RF spectrum prediction methods for dynamic spectrum access (United States)

    Kovarskiy, Jacob A.; Martone, Anthony F.; Gallagher, Kyle A.; Sherbondy, Kelly D.; Narayanan, Ram M.


    Dynamic spectrum access (DSA) refers to the adaptive utilization of today's busy electromagnetic spectrum. Cognitive radio/radar technologies require DSA to intelligently transmit and receive information in changing environments. Predicting radio frequency (RF) activity reduces sensing time and energy consumption for identifying usable spectrum. Typical spectrum prediction methods involve modeling spectral statistics with Hidden Markov Models (HMM) or various neural network structures. HMMs describe the time-varying state probabilities of Markov processes as a dynamic Bayesian network. Neural Networks model biological brain neuron connections to perform a wide range of complex and often non-linear computations. This work compares HMM, Multilayer Perceptron (MLP), and Recurrent Neural Network (RNN) algorithms and their ability to perform RF channel state prediction. Monte Carlo simulations on both measured and simulated spectrum data evaluate the performance of these algorithms. Generalizing spectrum occupancy as an alternating renewal process allows Poisson random variables to generate simulated data while energy detection determines the occupancy state of measured RF spectrum data for testing. The results suggest that neural networks achieve better prediction accuracy and prove more adaptable to changing spectral statistics than HMMs given sufficient training data.

  13. Momentum-resolved photoelectron absorption in surface barrier scattering on Ir(111) and graphene/Ir(111) (United States)

    Zaporozhchenko-Zymaková, A.; Kutnyakhov, D.; Medjanik, K.; Tusche, C.; Fedchenko, O.; Chernov, S.; Ellguth, M.; Nepijko, S. A.; Elmers, H. J.; Schönhense, G.


    Time-of-flight momentum microscopy reveals sixfold symmetric sharp features of decreased intensity (dark lines) in constant-energy maps for clean Ir(111) and graphene/Ir(111). The dark lines have been observed for p - and s -polarized light in the photon-energy range of 20-27 eV and result from scattering of photoelectrons at the surface potential barrier. The phenomenon is strongly related to threshold effects in low-energy electron diffraction. A quantitative analysis of the dark lines' positions shows that the relevant reciprocal-lattice vector corresponds to the lattice of the topmost layer (in our case graphene and Ir, respectively). The dark lines appear in the momentum patterns only in a certain photon-energy range satisfying the additional condition that the electron wavelength matches the lattice periodicity.

  14. The effect of test dose and first IR stimulation temperature on post-IR IRSL measurements of rock slices

    DEFF Research Database (Denmark)

    Liu, Jinfeng; Murray, Andrew; Sohbati, Reza


    curve saturation (or Do) with test dose size when the regeneration doses are first given in increasing order, and then decreasing order. This trend disappears if these orders are reversed. The reproducibility of dose response curves is dependent on the size of the test dose (poorer for small test dose......). For rock slices given a saturation dose in the laboratory, it is observed that the sensitivity corrected pIRIR290 signal lies close to saturation level of the dose response curve, for first IR stimulation at temperatures between 50 and 250°C. However, the pIRIR290 signal from naturally saturated slices...... lies close to the laboratory saturation levels only for higher first IR stimulation temperatures e.g. 200°C or 250°C. Our data confirm earlier suggestions based on sand-grain measurements that, for older sam-ples, accurate measurements close to saturation require that a higher first IR temperature...

  15. Continuous-wave seeded mid-IR parametric system pumped by the high-average-power picosecond Yb:YAG thin-disk laser (United States)

    Novák, Ondřej; Smrž, Martin; Miura, Taisuke; Turčičová, Hana; Endo, Akira; Mocek, Tomáś


    Mid-IR wavelength range offers variety of interesting applications. Down-conversion in the optical parametric devices is promising to generate high average power mid-IR beam due to inherently low thermal load of the nonlinear crystals if a powerful and high quality pump beam is available. We developed 100 kHz pump laser of 100-W level average power. The stretched pulses of Yb-fiber laser oscillator at 1030 nm wavelength are injected into the regenerative amplifier with an Yb:YAG thin-disk. Diode pumping at zero phonon line at wavelength of 969 nm significantly reduces its thermal load and increases conversion efficiency and stability. We obtained the beam with power of 80 W and 2 ps compressed pulsewidth. We are developing a watt level mid-IR picosecond light source pumped by a beam of the thin disk regenerative amplifier. Part of the beam pumps PPLN, which is seeded by a continuous wave laser diode at 1.94 μm to decrease the generation threshold and determine the amplified spectrum. The 3 W pumping gave output of 30 mW, which is by up to two orders higher compared to unseeded operation. The gain of about 107 was achieved in the PPLN in the temporal window of the pump pulse. The spectrum and beam of the generated idler pulses in the mid-IR was measured. We obtained an amplified signal from the second stage with the KTP crystal. We expect watt level mid-IR output for initial 50-W pumping. The generation of longer wavelengths is discussed.

  16. Protection of p+-n-Si Photoanodes by Sputter-Deposited Ir/IrOxThin Films

    DEFF Research Database (Denmark)

    Mei, Bastian Timo; Seger, Brian; Pedersen, Thomas


    Sputter deposition of Ir/IrOx on p+-n-Si without interfacial corrosion protection layers yielded photoanodes capable of efficient water oxidation (OER) in acidic media (1 M H2SO4). Stability of at least 18 h was shown by chronoamperomety at 1.23 V versus RHE (reversible hydrogen electrode) under ...... the necessary overpotential for OER at realistic device current, but also harvest ∼100 mV of free energy (voltage) which makes them among the best-performing Si-based photoanodes in low-pH media....

  17. Isotope-Labeled Amyloids via Synthesis, Expression, and Chemical Ligation for Use in FTIR, 2D IR, and NMR Studies. (United States)

    Zhang, Tianqi O; Grechko, Maksim; Moran, Sean D; Zanni, Martin T


    This chapter provides protocols for isotope-labeling the human islet amyloid polypeptide (hIAPP or amylin) involved in type II diabetes and γD-crystallin involved in cataract formation. Because isotope labeling improves the structural resolution, these protocols are useful for experiments using Fourier transform infrared (FTIR), two-dimensional infrared (2D IR), and NMR spectroscopies. Our research group specializes in using 2D IR spectroscopy and isotope labeling. 2D IR spectroscopy provides structural information by measuring solvation from 2D diagonal lineshapes and vibrational couplings from cross peaks. Infrared spectroscopy can be used to study kinetics, membrane proteins, and aggregated proteins. Isotope labeling provides greater certainty in the spectral assignment, which enables new structural insights that are difficult to obtain with other methods. For amylin, we provide a protocol for (13)C/(18)O labeling backbone carbonyls at one or more desired amino acids in order to obtain residue-specific structural resolution. We also provide a protocol for expressing and purifying amylin from E. coli, which enables uniform (13)C or (13)C/(15)N labeling. Uniform labeling is useful for measuring the monomer infrared spectrum in an amyloid oligomer or fiber as well as amyloid protein bound to another polypeptide or protein, such as a chaperone or an inhibitor. In addition, our expression protocol results in 2-2.5 mg of amylin peptide per 1 L cell culture, which is a high enough yield to straightforwardly obtain the 2-10 mg needed for high resolution and solid-state NMR experiments. Finally, we provide a protocol to isotope-label either of the two domains of γD-crystallin using expressed protein ligation. Domain labeling makes it possible to resolve the structures of the two halves of the protein in FTIR and 2D IR spectra. With modifications, these strategies and protocols for isotope labeling can be applied to other amyloid polypeptides and proteins.

  18. Visible to IR transducer-based infrared image projection systems (United States)

    Berisset, Philippe; Maurel, Frederic


    DGA/DCE/LRBA (Laboratoire de Recherches Balistiques et Aerodynamiques), the French MoD missiles and navigation evaluation center has developed several HWIL facilities in order to test the IR-autoguidance-loops of tactical missiles. This IR autoguidance laboratory is composed of several IR image projection systems based on a visible to IR transduction principle. A previous paper has presented the 1999 achievements of LRBA in this field of research. This new paper first describes the latest evolutions achieved by LRBA in this domain, and then details the image projection layouts based on these improvements. It consists in two main facilities: a ground target scene projection layout and a much more complex animated air target scene projection system. This second testbed features the simultaneous use of a low temperature scene projection layout and three high temperature channels designed to modelize the hot parts of an aircraft and its environment. This allows the delivery of continuous images (100% fill factor) for anti-aircraft missile evaluation, at a relatively low cost. The optimization of this facility and especially the channels synchronization and spatial superposition is also discussed. As a conclusion, future HWIL facilities are presented.

  19. Upconversion imager measures single mid-IR photons

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian


    The most sensitive IR detectors today are based on exotic semicoductor technology such as indium antimonide or mercury cadmium telluride. High quality detectors of these sorts are expensive and suffer from high dark currents. Dark current can be somewhat alleviated by extreme cooling. Comparing t...

  20. Multi-scale Adaptive Gain Control of IR Images

    NARCIS (Netherlands)

    Schutte, K.


    IR imagery tends to have a higher dynamic range then typical display devices such as a CRT. Global methods such as stretching and histogram equalization improve the visibility of many images, but some information in the images stays hidden for a human operator. This paper reports about the

  1. IRS Releases Tax Questionnaire that Asks Colleges to Disclose More (United States)

    Kelderman, Eric


    Nearly 400 colleges across the United States are about to be asked to disclose intimate financial details of their operations to the Internal Revenue Service. This article reports on a highly detailed financial questionnaire designed by the IRS for the first phase of its Colleges and Universities Compliance Project, which is part of a continuing…


    Energy Technology Data Exchange (ETDEWEB)

    Nikola, T.; Herter, T. L.; Adams, J. D.; Gull, G. E.; Henderson, C. P.; Schoenwald, J.; Stacey, G. [Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States); Vacca, W. D.; De Buizer, J. M. [Universities Space Research Association, NASA Ames Research Center, MS 211-3, Moffett Field, CA 94035 (United States); Keller, L. D. [Department of Physics, Ithaca College, Ithaca, NY 14850 (United States); Morris, M. R. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095-1547 (United States); Tielens, A. [Leiden Observatory, P.O. Box 9513, Leiden, 2300 RA (Netherlands)


    We present 75'' Multiplication-Sign 75'' size maps of M82 at 6.4 {mu}m, 6.6 {mu}m, 7.7 {mu}m, 31.5 {mu}m, and 37.1 {mu}m with a resolution of {approx}4'' that we have obtained with the mid-IR camera FORCAST on SOFIA. We find strong emission from the inner 60'' ({approx}1 kpc) along the major axis, with the main peak 5'' west-southwest of the nucleus and a secondary peak 4'' east-northeast of the nucleus. The detailed morphology of the emission differs among the bands, which is likely due to different dust components dominating the continuum emission at short mid-IR wavelengths and long mid-IR wavelengths. We include Spitzer-IRS and Herschel/PACS 70 {mu}m data to fit spectral energy distribution templates at both emission peaks. The best-fitting templates have extinctions of A{sub V} = 18 and A{sub V} = 9 toward the main and secondary emission peak and we estimated a color temperature of 68 K at both peaks from the 31 {mu}m and 37 {mu}m measurement. At the emission peaks the estimated dust masses are on the order of 10{sup 4} M{sub Sun }.

  3. Active IR System for Projectile Detection and Tracking

    Directory of Open Access Journals (Sweden)



    Full Text Available Reliable detection and tracking of high-speed projectiles is crucial in providing modern battlefield protection or to be used as a forensic tool. Subsonic projectiles fired from silenced weapons are difficult to detect, whereas reliable tracking of the projectile trajectory is hard to accomplish. Contemporary radar based counter-battery systems showed to be valuable in detection of incoming artillery fire, but are unable to provide detection at close ranges. In this paper, an active IR system is proposed that aims to detect and track incoming projectiles at close ranges. Proposed system is able to reconstruct projectile’s trajectory in space, predict impact location and estimate direction of projectile origin. Active detector system is based on a pair of high-speed cameras in stereo-configuration synced with computer and IR illuminator that emits coded IR light bursts. Innovative IR light coding enables automated detection and tracking of a nearby projectile and elimination of false positive alarms caused by distant objects.

  4. ISO-SWS spectra of OH/IR stars

    NARCIS (Netherlands)

    Cami, J; De Jong, T; Justtannont, K; Yamamura, [No Value; Waters, LBFM


    We present the spectra of 5 OH/IR stars observed with the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO). The spectra are dominated by dust features, both in the amorphous and crystalline state and illustrate the influence of the mass loss rate on the observed

  5. Historical Materialism and the Postcolonial Challenge to IR

    DEFF Research Database (Denmark)

    Ougaard, Morten

    This paper addresses one of the “exemplary questions” listed by the panel conveners, namely: “How does the postcolonial perspective enable/disable the rethinking of theories and concepts considered central to critical IR?” This requires an explication of how I see the several parts of the exemplary...

  6. Resonant photothermal IR spectroscopy of picogram samples with microstring resonator

    DEFF Research Database (Denmark)

    Yamada, Shoko; Schmid, Silvan; Boisen, Anja


    an in-situ sampling method and the resonance frequency of the string is measured optically. Resonance frequency shifts, proportional to the absorbed heat, are recorded in real time as monochromatic infrared light is being scanned over the mid-infrared range. These resonant photothermal IR spectroscopy...

  7. Mock Target Window OTR and IR Design and Testing

    Energy Technology Data Exchange (ETDEWEB)

    Wass, Alexander Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    In order to fully verify temperature measurements made on the target window using infrared (IR) optical non-contact methods, actual comparative measurements are made with a real beam distribution as the heat source using Argonne National Laboratory’s (ANL) 35 MeV electron accelerator. Using Monte Carlo N-Particle (MCNP) simulations and thermal Finite Element Analysis (FEA), a cooled mock target window with thermocouple implants is designed to be used in such a test to achieve window temperatures up to 700°C. An uncoated and blackcoated mock window is designed to enhance the IR temperature measurements and verify optical transmitted radiation (OTR) imagery. This allows us to fully verify and characterize our temperature accuracy with our current IR camera method and any future method we may wish to explore using actual production conditions. This test also provides us with valuable conclusions/concerns regarding the calibration method we developed using our IR test stand at TA-53 in MPF-14.

  8. Assessment of the exchange parameters of Amberlite IR-45 (OH ...

    African Journals Online (AJOL)


    ABSTRACT: Simple quantitative technique has been developed for assessing the exchange parameters of Amberlite IR. – 45 (OH) using column chromatographic techniques from the displacement of exchangeable hydroxyl ions of the resin by sulphate ions. The results obtained showed retention time of 33min, retention ...

  9. Isothermal anisotropic magnetoresistance in antiferromagnetic metallic IrMn (United States)

    Galceran, R.; Fina, I.; Cisneros-Fernández, J.; Bozzo, B.; Frontera, C.; López-Mir, L.; Deniz, H.; Park, K.-W.; Park, B.-G.; Balcells, Ll.; Martí, X.; Jungwirth, T.; Martínez, B.


    Antiferromagnetic spintronics is an emerging field; antiferromagnets can improve the functionalities of ferromagnets with higher response times, and having the information shielded against external magnetic field. Moreover, a large list of aniferromagnetic semiconductors and metals with Néel temperatures above room temperature exists. In the present manuscript, we persevere in the quest for the limits of how large can anisotropic magnetoresistance be in antiferromagnetic materials with very large spin-orbit coupling. We selected IrMn as a prime example of first-class moment (Mn) and spin-orbit (Ir) combination. Isothermal magnetotransport measurements in an antiferromagnetic-metal(IrMn)/ferromagnetic-insulator thin film bilayer have been performed. The metal/insulator structure with magnetic coupling between both layers allows the measurement of the modulation of the transport properties exclusively in the antiferromagnetic layer. Anisotropic magnetoresistance as large as 0.15% has been found, which is much larger than that for a bare IrMn layer. Interestingly, it has been observed that anisotropic magnetoresistance is strongly influenced by the field cooling conditions, signaling the dependence of the found response on the formation of domains at the magnetic ordering temperature.

  10. Compressibility of Ir-Os alloys under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Yusenko, Kirill V., E-mail: [Department of Chemistry, Center for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1033, Blindern, NO-0315 Oslo (Norway); Bykova, Elena [Materialphysik und Technologie, Lehrstuhl für Kristallographie, Physikalisches Institut, Universität Bayreuth, D-95440 Bayreuth (Germany); Bayerisches Geoinstitut, Universität Bayreuth, D-95440 Bayreuth (Germany); Bykov, Maxim [Laboratory of Crystallography, University of Bayreuth, D-95440 Bayreuth (Germany); Gromilov, Sergey A. [Department of Physics, Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk (Russian Federation); Department of Crystal Chemistry, Nikolaev Institute of Inorganic Chemistry, Lavrentiev Ave. 3, 630090 Novosibirsk (Russian Federation); Kurnosov, Alexander V. [Bayerisches Geoinstitut, Universität Bayreuth, D-95440 Bayreuth (Germany); Prescher, Clemens; Prakapenka, Vitali B. [Center for Advanced Radiation Sources, University of Chicago, Chicago, IL 60637 (United States); Hanfland, Michael [European Synchrotron Radiation Facility, Polygone Scientifique Louis Neel, 6 rue Jules Horowitz, 38000 Grenoble (France); Smaalen, Sander van [Laboratory of Crystallography, University of Bayreuth, D-95440 Bayreuth (Germany); Margadonna, Serena [Department of Chemistry, Center for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1033, Blindern, NO-0315 Oslo (Norway); Dubrovinsky, Leonid S. [Bayerisches Geoinstitut, Universität Bayreuth, D-95440 Bayreuth (Germany)


    Highlights: • fcc- and hcp-Ir-Os alloys were prepared from single-source precursors. • Their atomic volumes measured at ambient conditions using powder X-ray diffraction follow nearly linear dependence. • Compressibility of alloys have been studied up to 30 GPa at room temperature in diamond anvil cells. • Their bulk moduli increase with increasing osmium content. - Abstract: Several fcc- and hcp-structured Ir-Os alloys were prepared from single-source precursors in hydrogen atmosphere at 873 K. Their atomic volumes measured at ambient conditions using powder X-ray diffraction follow nearly linear dependence as a function of composition. Alloys have been studied up to 30 GPa at room temperature by means of synchrotron-based X-ray powder diffraction in diamond anvil cells. Their bulk moduli increase with increasing osmium content and show a deviation from linearity. Bulk modulus of hcp-Ir{sub 0.20}Os{sub 0.80} is identical to that of pure Os (411 GPa) within experimental errors. Peculiarities on fcc-Ir{sub 0.80}Os{sub 0.20} compressibility curve indicate possible changes of its electronic properties at ∼20 GPa.

  11. Score Region Algebra: Building a Transparent XML-IR Database

    NARCIS (Netherlands)

    Mihajlovic, V.; Blok, H.E.; Hiemstra, Djoerd; Apers, Peter M.G.; Chowdhury, A.; Fuhr, N.; Ronthaler, M.; Schek, H-J.; Teiken, W.


    A unified database framework that will enable better comprehension of ranked XML retrieval is still a challenge in the XML database field. We propose a logical algebra, named score region algebra, that enables transparent specification of information retrieval (IR) models for XML databases. The

  12. IR-REMPI spectroscopy for thermometry of C-60

    NARCIS (Netherlands)

    van Heijnsbergen, D.; von Helden, G.; Sartakov, B.; Meijer, G.


    Gas-phase C-60 molecules are excited with a 30 ps 266 nm Nd:YAG laser, followed by a train of high-power infrared (IR) sub-picosecond pulses from a free electron laser (FEL), which resonantly heats the molecules up to internal energies at which they efficiently undergo delayed ionization. By tuning

  13. Near-IR imaging of cracks in teeth (United States)

    Fried, William A.; Simon, Jacob C.; Lucas, Seth; Chan, Kenneth H.; Darling, Cynthia L.; Staninec, Michal; Fried, Daniel


    Dental enamel is highly transparent at near-IR wavelengths and several studies have shown that these wavelengths are well suited for optical transillumination for the detection and imaging of tooth decay. We hypothesize that these wavelengths are also well suited for imaging cracks in teeth. Extracted teeth with suspected cracks were imaged at several wavelengths in the near-IR from 1300-1700-nm. Extracted teeth were also examined with optical coherence tomography to confirm the existence of suspected cracks. Several teeth of volunteers were also imaged in vivo at 1300-nm to demonstrate clinical potential. In addition we induced cracks in teeth using a carbon dioxide laser and imaged crack formation and propagation in real time using near-IR transillumination. Cracks were clearly visible using near-IR imaging at 1300-nm in both in vitro and in vivo images. Cracks and fractures also interfered with light propagation in the tooth aiding in crack identification and assessment of depth and severity.

  14. Recent advancements in nanoscale IR spectroscopy for materials science (United States)

    Dillon, Eoghan; Yang, Honghua; Kjoller, Kevin; Anasys Instruments Team

    This talk will focus on the advances in measuring the chemical and optical properties of materials with nanometer scale spatial resolution. Conventional infrared spectroscopy is one of the most widely used tools for chemical analysis, but optical diffraction limits its spatial resolution to the scale of many microns. Atomic force microscopy (AFM) enjoys excellent spatial resolution, but has historically lacked the ability to perform robust chemical analysis. This presentation will discuss the advances in two techniques (1) AFM-based infrared spectroscopy (AFM-IR) and (2) scattering scanning near field optical microscopy (s-SNOM). Both of these techniques overcome the diffraction limit, providing the ability to measure and map chemical and optical properties with 10 nanometer spatial resolution. Recent advances including Tapping AFM-IR and increases in laser sweep rates have significantly improved the resolution and sensitivity of AFM-IR. As complementary techniques, AFM-IR and s-SNOM together provide an unrivaled capability to perform nanoscale chemical analysis on a diverse range of organic, inorganic, photonic and electronic materials. This talk will focus on AFM and s-SNOM applications on samples from fields including polymers, life sciences, graphene and nanoantennas.

  15. Assessment of the exchange parameters of Amberlite IR-45 (OH ...

    African Journals Online (AJOL)

    Simple quantitative technique has been developed for assessing the exchange parameters of Amberlite IR – 45 (OH) using column chromatographic techniques from the displacement of exchangeable hydroxyl ions of the resin by sulphate ions. The results obtained showed retention time of 33min, retention volume of ...

  16. The IR-4 Program - how it can benefit nurseries (United States)

    J. Ray Frank


    The Interregional Research Project 4 (IR-4) was initiated in 1963 to obtain national pesticide label regsitrations for use on food and fiber. This program has an emphasis on minor uses or specialty crops. In this arena in the United States today it includes 600 crops.

  17. Probability analysis of position errors using uncooled IR stereo camera (United States)

    Oh, Jun Ho; Lee, Sang Hwa; Lee, Boo Hwan; Park, Jong-Il


    This paper analyzes the random phenomenon of 3D positions when tracking moving objects using the infrared (IR) stereo camera, and proposes a probability model of 3D positions. The proposed probability model integrates two random error phenomena. One is the pixel quantization error which is caused by discrete sampling pixels in estimating disparity values of stereo camera. The other is the timing jitter which results from the irregular acquisition-timing in the uncooled IR cameras. This paper derives a probability distribution function by combining jitter model with pixel quantization error. To verify the proposed probability function of 3D positions, the experiments on tracking fast moving objects are performed using IR stereo camera system. The 3D depths of moving object are estimated by stereo matching, and be compared with the ground truth obtained by laser scanner system. According to the experiments, the 3D depths of moving object are estimated within the statistically reliable range which is well derived by the proposed probability distribution. It is expected that the proposed probability model of 3D positions can be applied to various IR stereo camera systems that deal with fast moving objects.

  18. Quantification of cross-bleaching during infrared (IR) light stimulation

    DEFF Research Database (Denmark)

    Kreutzer, Sebastian; Hülle, Daniela; Thomsen, Kristina Jørkov


    the adjacent position resulting in systematic errors. Previously reported for blue LEDs, such cross-talk (cross-bleaching/illumination) has never been quantified explicitly for the infrared (IR) LEDs, although they are intensively used in IRSL measurements of e.g. feldspar and polymineral samples. In IRSL...

  19. Misaligned disks in the binary protostar IRS 43

    DEFF Research Database (Denmark)

    Brinch, Christian; Jørgensen, Jes Kristian; Hogerheijde, Michiel R.


    Recent high angular resolution (∼ 0\\buildrel{\\prime\\prime}\\over{.} 2) ALMA observations of the 1.1 mm continuum and of HCO+ J = 3–2 and HCN J = 3–2 gas toward the binary protostar IRS 43 reveal multiple Keplerian disks that are significantly misaligned (\\gt 60^\\circ ), both in inclination...


    African Journals Online (AJOL)

    amino acids and peptides were prepared using acyl ferrocenes and investigated in detail [12-15]. Fc-3ppa and ... negative phase. Two-dimensional HETCOR and COSY techniques were measured using standard micro-programs provided by Bruker. FT-IR spectra were recorded in the region of. 400-4000 cm-1 with ...

  1. Strong-Field Physics with Mid-IR Fields

    Directory of Open Access Journals (Sweden)

    Benjamin Wolter


    Full Text Available Strong-field physics is currently experiencing a shift towards the use of mid-IR driving wavelengths. This is because they permit conducting experiments unambiguously in the quasistatic regime and enable exploiting the effects related to ponderomotive scaling of electron recollisions. Initial measurements taken in the mid-IR immediately led to a deeper understanding of photoionization and allowed a discrimination among different theoretical models. Ponderomotive scaling of rescattering has enabled new avenues towards time-resolved probing of molecular structure. Essential for this paradigm shift was the convergence of two experimental tools: (1 intense mid-IR sources that can create high-energy photons and electrons while operating within the quasistatic regime and (2 detection systems that can detect the generated high-energy particles and image the entire momentum space of the interaction in full coincidence. Here, we present a unique combination of these two essential ingredients, namely, a 160-kHz mid-IR source and a reaction microscope detection system, to present an experimental methodology that provides an unprecedented three-dimensional view of strong-field interactions. The system is capable of generating and detecting electron energies that span a 6 order of magnitude dynamic range. We demonstrate the versatility of the system by investigating electron recollisions, the core process that drives strong-field phenomena, at both low (meV and high (hundreds of eV energies. The low-energy region is used to investigate recently discovered low-energy structures, while the high-energy electrons are used to probe atomic structure via laser-induced electron diffraction. Moreover, we present, for the first time, the correlated momentum distribution of electrons from nonsequential double ionization driven by mid-IR pulses.

  2. Visible spectrum of stable sonoluminescence (United States)

    Carlson, Joseph T.


    Synchronous emissions of picosecond pulses of light are observed to originate from a bubble trapped at the pressure antinode of a resonant sound field. The spectrum has been measured using a single slit spectrometer equipped with a linear array CCD detector. Spectra from differing solutions of water and glycerin are compared to the visible blackbody spectrum distribution. Assuming a blackbody model, apparent temperatures of 18,900 Kelvins are observed in pure water. Increasing glycerin concentration appears to correlate with cooler blackbody temperatures. The spectrum is also found to continually change with time, independent of input parameters.

  3. Autism Spectrum Disorder and Fragile X Syndrome (United States)

    ... only after another family member has been diagnosed. Autism Spectrum Disorder and Fragile X Syndrome Fragile X ... known single gene cause of ASD What Is Autism Spectrum Disorder? Autism spectrum disorder (ASD) is a ...

  4. Galaxy Evolution Studies with the SPace IR Telescope for Cosmology and Astrophysics (SPICA): The Power of IR Spectroscopy (United States)

    Spinoglio, L.; Alonso-Herrero, A.; Armus, L.; Baes, M.; Bernard-Salas, J.; Bianchi, S.; Bocchio, M.; Bolatto, A.; Bradford, C.; Braine, J.; Carrera, F. J.; Ciesla, L.; Clements, D. L.; Dannerbauer, H.; Doi, Y.; Efstathiou, A.; Egami, E.; Fernández-Ontiveros, J. A.; Ferrara, A.; Fischer, J.; Franceschini, A.; Gallerani, S.; Giard, M.; González-Alfonso, E.; Gruppioni, C.; Guillard, P.; Hatziminaoglou, E.; Imanishi, M.; Ishihara, D.; Isobe, N.; Kaneda, H.; Kawada, M.; Kohno, K.; Kwon, J.; Madden, S.; Malkan, M. A.; Marassi, S.; Matsuhara, H.; Matsuura, M.; Miniutti, G.; Nagamine, K.; Nagao, T.; Najarro, F.; Nakagawa, T.; Onaka, T.; Oyabu, S.; Pallottini, A.; Piro, L.; Pozzi, F.; Rodighiero, G.; Roelfsema, P.; Sakon, I.; Santini, P.; Schaerer, D.; Schneider, R.; Scott, D.; Serjeant, S.; Shibai, H.; Smith, J.-D. T.; Sobacchi, E.; Sturm, E.; Suzuki, T.; Vallini, L.; van der Tak, F.; Vignali, C.; Yamada, T.; Wada, T.; Wang, L.


    IR spectroscopy in the range 12-230 μm with the SPace IR telescope for Cosmology and Astrophysics (SPICA) will reveal the physical processes governing the formation and evolution of galaxies and black holes through cosmic time, bridging the gap between the James Webb Space Telescope and the upcoming Extremely Large Telescopes at shorter wavelengths and the Atacama Large Millimeter Array at longer wavelengths. The SPICA, with its 2.5-m telescope actively cooled to below 8 K, will obtain the first spectroscopic determination, in the mid-IR rest-frame, of both the star-formation rate and black hole accretion rate histories of galaxies, reaching lookback times of 12 Gyr, for large statistically significant samples. Densities, temperatures, radiation fields, and gas-phase metallicities will be measured in dust-obscured galaxies and active galactic nuclei, sampling a large range in mass and luminosity, from faint local dwarf galaxies to luminous quasars in the distant Universe. Active galactic nuclei and starburst feedback and feeding mechanisms in distant galaxies will be uncovered through detailed measurements of molecular and atomic line profiles. The SPICA's large-area deep spectrophotometric surveys will provide mid-IR spectra and continuum fluxes for unbiased samples of tens of thousands of galaxies, out to redshifts of z 6.

  5. Thermal-to-visible transducer (TVT) for thermal-IR imaging (United States)

    Flusberg, Allen; Swartz, Stephen; Huff, Michael; Gross, Steven


    We have been developing a novel thermal-to-visible transducer (TVT), an uncooled thermal-IR imager that is based on a Fabry-Perot Interferometer (FPI). The FPI-based IR imager can convert a thermal-IR image to a video electronic image. IR radiation that is emitted by an object in the scene is imaged onto an IR-absorbing material that is located within an FPI. Temperature variations generated by the spatial variations in the IR image intensity cause variations in optical thickness, modulating the reflectivity seen by a probe laser beam. The reflected probe is imaged onto a visible array, producing a visible image of the IR scene. This technology can provide low-cost IR cameras with excellent sensitivity, low power consumption, and the potential for self-registered fusion of thermal-IR and visible images. We will describe characteristics of requisite pixelated arrays that we have fabricated.

  6. IR-based spot weld NDT in automotive applications (United States)

    Chen, Jian; Feng, Zhili


    Today's auto industry primarily relies on destructive teardown evaluation to ensure the quality of the resistance spot welds (RSWs) due to their criticality in crash resistance and performance of vehicles. The destructive teardown evaluation is labor intensive and costly. The very nature of the destructive test means only a few selected welds will be sampled for quality. Most of the welds in a car are never checked. There are significant costs and risks associated with reworking and scrapping the defective welded parts made between the teardown tests. IR thermography as a non-destructive testing (NDT) tool has its distinct advantage — its non-intrusive and non-contact nature. This makes the IR based NDT especially attractive for the highly automated assembly lines. IR for weld quality inspection has been explored in the past, mostly limited to the offline post-processing manner in a laboratory environment. No online real-time RSW inspection using IR thermography has been reported. Typically for postprocessing inspection, a short-pulse heating via xenon flash lamp light (in a few milliseconds) is applied to the surface of a spot weld. However, applications in the auto industry have been unsuccessful, largely due to a critical drawback that cannot be implemented in the high-volume production line - the prerequisite of painting the weld surface to eliminate surface reflection and other environmental interference. This is due to the low signal-to-noise ratio resulting from the low/unknown surface emissivity and the very small temperature changes (typically on the order of 0.1°C) induced by the flash lamp method. An integrated approach consisting of innovations in both data analysis algorithms and hardware apparatus that effectively solved the key technical barriers for IR NDT. The system can be used for both real-time (during welding) and post-processing inspections (after welds have been made). First, we developed a special IR thermal image processing method that

  7. Family Process - Autism Spectrum Disorders


    Benson, Mark


    Slides for a talk about family process and the importance of parenting dimensions in adolescent development. The slides list findings to date, and propose research into the influence of family on outcomes for those diagnosed with an autism spectrum disorder.

  8. Extending the Range of Beer's Law in Ft-Ir Spectrometry (United States)

    Zhu, Changjiang


    investigated. These include whether the interferogram is acquired in the double- or single-sided mode, the length of the array used for phase correction and the effect of a gain-ranging amplifier. A means of testing the photometric accuracy of FT-IR spectrometers based on the correspondence of theoretical and measured band intensities is proposed. Sidelobes appearing in the spectrum after the Fourier transform are the main driving force towards a positive deviation from Beer's law behavior while numerical and optical apodization both lead to a negative deviation. The extension of Beer's law to high true peak absorbance is achieved by the balance of those factors giving rise positive and negative deviations.

  9. IR radiation characteristics of rocket exhaust plumes under varying motor operating conditions

    Directory of Open Access Journals (Sweden)

    Qinglin NIU


    Full Text Available The infrared (IR irradiance signature from rocket motor exhaust plumes is closely related to motor type, propellant composition, burn time, rocket geometry, chamber parameters and flight conditions. In this paper, an infrared signature analysis tool (IRSAT was developed to understand the spectral characteristics of exhaust plumes in detail. Through a finite volume technique, flow field properties were obtained through the solution of axisymmetric Navier-Stokes equations with the Reynolds-averaged approach. A refined 13-species, 30-reaction chemistry scheme was used for combustion effects and a k-ε-Rt turbulence model for entrainment effects. Using flowfield properties as input data, the spectrum was integrated with a line of sight (LOS method based on a single line group (SLG model with Curtis-Godson approximation. The model correctly predicted spectral distribution in the wavelengths of 1.50–5.50 μm and had good agreement for its location with imaging spectrometer data. The IRSAT was then applied to discuss the effects of three operating conditions on IR signatures: (a afterburning; (b chamber pressure from ignition to cutoff; and (c minor changes in the ratio of hydroxyl-terminated polybutadiene (HTPB binder to ammonium perchlorate (AP oxidizer in propellant. Results show that afterburning effects can increase the size and shape of radiance images with enhancement of radiation intensity up to 40%. Also, the total IR irradiance in different bands can be characterized by a non-dimensional chamber pressure trace in which the maximum discrepancy is less than 13% during ignition and engine cutoff. An increase of chamber pressure can lead to more distinct diamonds, whose distance intervals are extended, and the position of the first diamond moving backwards. In addition, an increase in HTPB/AP causes a significant jump in spectral intensity. The incremental rates of radiance intensity integrated in each band are linear with the increase of HTPB

  10. Theoretical characterization of quaternary iridium based hydrides NaAeIrH{sub 6} (Ae = Ca, Ba and Sr)

    Energy Technology Data Exchange (ETDEWEB)

    Bouras, S. [Laboratory of Studies Surfaces and Interfaces of Solids Materials, Department of Physics, Faculty of Science, University of Setif 1, 19000 (Algeria); Ghebouli, B., E-mail: [Laboratory of Studies Surfaces and Interfaces of Solids Materials, Department of Physics, Faculty of Science, University of Setif 1, 19000 (Algeria); Benkerri, M. [Laboratory of Studies Surfaces and Interfaces of Solids Materials, Department of Physics, Faculty of Science, University of Setif 1, 19000 (Algeria); Ghebouli, M.A., E-mail: [Microelectronic Laboratory (LMSE), University of Bachir Ibrahimi, Bordj-Bou-Arreridj 34000 (Algeria); Research Unit on Emerging Materials (RUEM), University of Setif 1, 19000 (Algeria); Choutri, H. [Microelectronic Laboratory (LMSE), University of Bachir Ibrahimi, Bordj-Bou-Arreridj 34000 (Algeria); Louail, L.; Chihi, T.; Fatmi, M. [Research Unit on Emerging Materials (RUEM), University of Setif 1, 19000 (Algeria); Bouhemadou, A. [Laboratory for Developing New Materials and Their Characterization, Department of Physics, Faculty of Science, University of Setif 1, 19000 (Algeria); Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451 (Saudi Arabia); Khenata, R.; Khachai, H. [Laboratoire de Physique Quantique et de Modélisation Mathématique, Université de Mascara, 29000 (Algeria)


    The quaternary iridium based hydrides NaAeIrH{sub 6} (Ae = Ca, Ba and Sr) are promising candidates as hydrogen storage materials. We have studied the structural, elastic, electronic, optical and thermodynamic properties of NaAeIrH{sub 6} (Ae = Ca, Ba and Sr) within the generalized gradient approximation, the local density approximation (LDA) and mBj in the frame of density functional perturbation theory. These alloys have a large indirect Γ–X band gap. The thermodynamic functions were computed using the phonon density of states. The origin of the possible transitions from valence band to conduction band was illustrated. By using the complex dielectric function, the optical properties such as absorption, reflectivity, loss function, refractive index and optical conductivity have been obtained. - Graphical abstract: Real and imaginary parts of the dielectric function, the absorption spectrum α(ω), reflectivity R(ω) and energy-loss spectrum L(ω). - Highlights: • NaAeIrH{sub 6} (Ae = Ca, Ba and Sr) alloys have been investigated. • The elastic moduli, energy gaps are predicted. • The optical and thermal properties were studied.

  11. Autism spectrum disorder - childhood disintegrative disorder (United States)

    ... part of the larger developmental disorder category of autism spectrum disorder . ... American Psychiatric Association. Autism spectrum disorder. ... ed. Arlington, VA: American Psychiatric Publishing: 2013;50-59. ...

  12. Are far-IR fluxes good measures of cloud mass? (United States)

    Wagle, Gururaj; Ferland, G. J.; Troland, T. H.; Abel, N.


    It is commonly assumed that the Herschel far-IR fluxes are a measure of column density, hence, mass of interstellar clouds. The Polaris Flare, a high galactic latitude cirrus cloud, with several starless molecular cores, has been previously observed with the Herschel Space Telescope. We used Cloudy version 13.02 to model a molecular cloud MCLD 123.5+24.9, one of the denser regions of the Polaris Flare. These models include a detailed calculation of far-IR grain opacities, subject to various assumptions about grain composition, and predict far-IR fluxes. The models suggest that the observed fluxes reflect the incident stellar UV radiation field rather than the column density, if N(H) > a few times 1021 cm2 (AV > 1). For higher column densities, the models show that dust temperatures decline rapidly into the cloud. Therefore, the cloud interiors contribute very little additional far-IR flux, and column densities based upon far-IR fluxes can be significantly underestimated. The Polaris Flare, 150 pc distant, is well within the Galactic disc. There are no nearby hot stars. Therefore, the stellar UV radiation field incident on the cloud should be close to the mean interstellar radiation field (ISRF). In addition, the calculated grain opacities required to reproduce the far-IR fluxes in the Cloudy models are a few factors larger than that calculated for standard ISM graphite and silicate grains. This result suggests that the grains in dense regions are coated with water and ammonia ices, increasing their sizes and opacities. The Cloudy models also predict mm-wavelength CO line strengths for comparison with published observations at the IRAM 30-m telescope. In order to reproduce the observed CO line strengths for cores in MCLD 123.5+24.9, the models require that CO molecules be partially frozen out onto the grains. This result places age constraints upon the cores. We have also modeled CO emission from inter-core regions in MCLD 123.5+24.9. For these regions, the models

  13. Beyond the Spectrum: Rethinking Autism

    Directory of Open Access Journals (Sweden)

    Heather Thomas


    Full Text Available The "spectrum" has become the dominant metaphor for conceptualizing autism, with fundamental consequences for notions of disability, diversity, and normality. In this article, we draw on ethnographic research with autistic communities to explore how the notion of the autism spectrum has become a focus of explicit identification, reflection, and contestation. To further this inquiry, we place these debates into conversation with earlier debates regarding another spectrum—the Kinsey Scale, a "spectrum" for conceptualizing sexual orientation that first appeared in 1948 but has been critiqued since the 1970s. How might responses to the Kinsey Scale (like the Klein Grid contribute to rethinking the autism spectrum? This is a question about the cultural and political implications of metaphors and conceptual models. It is of broad importance because the spectrum metaphor is being extended to a range of conditions beyond autism itself. Our goal is thus to build on insights from sexuality studies as well as the insights of autistic persons, advocates, and researchers who wish to forestall the naturalization of "the spectrum." In doing so, we seek to contribute to a discussion of what alternative frameworks might bring to questions of social justice, ability, and human flourishing.

  14. FT-IR study of the proton polarizability of hydrogen bonds and of the hydrogen-bonded systems in a di-Mannich base of 5,5'-dimethoxy-2,2'-biphenol (United States)

    Brzezinski, Bogumil; Wojciechowski, Grzegorz; Urjasz, Hanna; Zundel, Georg


    The mono- as well as the di-Mannich bases of 5,5'-dimethoxy-2,2'-biphenol are studied by FT-IR spectroscopy. It is shown that in these bases the protons remain localized at the phenol O atom. This result is in contrast to those obtained earlier for more acidic biphenols in which the protons are not localized but fluctuate and the relevant hydrogen bonds show large polarizability. An intense infrared continuum in the FT-IR spectrum of the mono-protonated di-Mannich base of 5,5'-dimethoxy-2,2'-biphenol demonstrates that the intramolecular hydrogen bond in this compound shows large proton polarizability.

  15. The structure of salt bridges between Arg(+) and Glu(-) in peptides investigated with 2D-IR spectroscopy: Evidence for two distinct hydrogen-bond geometries. (United States)

    Huerta-Viga, Adriana; Amirjalayer, Saeed; Domingos, Sérgio R; Meuzelaar, Heleen; Rupenyan, Alisa; Woutersen, Sander


    Salt bridges play an important role in protein folding and in supramolecular chemistry, but they are difficult to detect and characterize in solution. Here, we investigate salt bridges between glutamate (Glu(-)) and arginine (Arg(+)) using two-dimensional infrared (2D-IR) spectroscopy. The 2D-IR spectrum of a salt-bridged dimer shows cross peaks between the vibrational modes of Glu(-) and Arg(+), which provide a sensitive structural probe of Glu(-)⋯Arg(+) salt bridges. We use this probe to investigate a β-turn locked by a salt bridge, an α-helical peptide whose structure is stabilized by salt bridges, and a coiled coil that is stabilized by intra- and intermolecular salt bridges. We detect a bidentate salt bridge in the β-turn, a monodentate one in the α-helical peptide, and both salt-bridge geometries in the coiled coil. To our knowledge, this is the first time 2D-IR has been used to probe tertiary side chain interactions in peptides, and our results show that 2D-IR spectroscopy is a powerful method for investigating salt bridges in solution.

  16. Rapid authentication of different ages of tissue-cultured and wild Dendrobium huoshanense as well as wild Dendrobium henanense using FTIR and 2D-COS IR (United States)

    Chen, Nai-Dong; Chen, Nai-Fu; Li, Jun; Cao, Cai-Yun; Wang, Jin-Mei


    The accumulating of pharmaceutical chemicals in medicinal plants would greatly be affected by their ages and establishing a fast quality-identification method to evaluate the similarity of medicinal herbs at different cultivated ages is a critical step for assurance of quality and safety in the TCM industry. In this work, tri-step IR macro-fingerprinting and 2D-COS IR spectrum techniques combined with statistical pattern recognition were applied for discrimination and similarity evaluation of different ages of tissue-cultured and wild Dendrobium huoshanense C. Z. Tang et S. J. Cheng as well as Dendrobium henanense J.L.Lu et L.X Gao. Both tissue-cultured and wild D. huoshanense were easily differentiated from D. henanense by FTIR and SD-IR spectra, while it's quite difficult to discriminate different cultivated years of the three investigated Dendrobiums. In 2D-COS IR spectra, 1-5 auto-peaks with different indensity and positions were located in the region 1160-1030 cm-1 of the twelve Dendrobium samples and thus could be used to identify Dendrobium samples at different ages. Principle component analysis (PCA) of synchronous 2D-COS data showed that the twelve samples were effectively identified and evaluated. The results indicated that the tri-step infrared macro-fingerprinting combined with PCA method was suitable to differentiate the cultivated ages of Dendrobiums with species and orgins rapidly and nondestructively.

  17. Obstacle-avoiding robot with IR and PIR motion sensors (United States)

    Ismail, R.; Omar, Z.; Suaibun, S.


    Obstacle avoiding robot was designed, constructed and programmed which may be potentially used for educational and research purposes. The developed robot will move in a particular direction once the infrared (IR) and the PIR passive infrared (PIR) sensors sense a signal while avoiding the obstacles in its path. The robot can also perform desired tasks in unstructured environments without continuous human guidance. The hardware was integrated in one application board as embedded system design. The software was developed using C++ and compiled by Arduino IDE 1.6.5. The main objective of this project is to provide simple guidelines to the polytechnic students and beginners who are interested in this type of research. It is hoped that this robot could benefit students who wish to carry out research on IR and PIR sensors.

  18. Photonics in nature: Yellowstone National Park in IR (United States)

    Vollmer, Michael; Shaw, Joseph A.; Nugent, Paul W.; Harris, Wilson; Gillis, Kendra; Weiss, William; Carpenter, Logan; Carpenter, Amy; Scherrer, Bryan


    Infrared thermal imaging is a valuable tool not only in science but also in optics and photonics education and outreach activities. Observing natural optical phenomena in a different spectral region like the thermal infrared often offers new insights. The commonly used false color images not only allow extraction of useful information about thermal properties of objects, but they can also provide aesthetic sights and are thus an excellent tool for public outreach activities. Recently we have pursued this kind of study using IR imaging within Yellowstone National Park, complementing earlier work on thermal pool colors and spectroscopy. We will discuss and compare images of a variety of VIS and IR cameras of hot springs, geysers, mud pools and other natural phenomena recorded in the park during 2012 and 2016.

  19. A Non-Conventional IR Approach to India's Foreign Policy

    DEFF Research Database (Denmark)

    Schmidt, Johannes Dragsbæk

    that an alternative Critical IPE approach (CPE) contributes to a more nuanced understanding of India's foreign policy. In generic terms, shifting governments have a variety of options both in defining and refining what 'national interest' means, how security and threats are perceived, and which factors shape geo...... structure. The aim then is to explore the boundaries of the state in its current conjunctures, its historical dynamic and the process of social change. In this way, the paper seeks an understanding of the underlying and prevailing tensions between geo-politics and geo-economics in foreign policy......Paper presentation for the Panel 'India's international relations: empirical and theoretical perspectives'. EISA Pan-Euro Conference in Warsaw, 18 - 21st September, 2013 Abstract The paper elaborates on a critique of mainstream IR theory - neo-realism and liberal IR - and suggests...

  20. Imperija ir globalizacija naujoje pasaulinėje tvarkoje


    Šerpetis, Kęstutis


    Šaltojo karo pabaiga ir dvipolės pasaulinės tvarkos žlugimas esmingai keičia tarptautinės sistemos konfigūraciją bei funkcinę jos paskirtį. Kita vertus, globalinės politikos tapsmas sąlygoja adekvačių viršnacionalinio valdymo struktūrų formavimo būtinybę. Egzistuojančių tarptautinių organizacijų funkcinė redukcija ir nacionalinių valstybių galių erozija įsakmiai kelia naujų struktūrinių politinių formų paieškos uždavinius. Plačiame politologinių tyrimų lauke pastarąjį dešimtmetį išsiskiria im...

  1. Ir catalysts: Preventing CH3COOH formation in ethanol oxidation (United States)

    Miao, Bei; Wu, Zhipeng; Xu, Han; Zhang, Minhua; Chen, Yifei; Wang, Lichang


    Current catalysts used for ethanol oxidation reaction (EOR) cannot effectively prevent CH3COOH formation, and thus become a major hindrance for direct ethanol fuel cell applications. We report an Ir catalyst that shows great promise for a complete EOR based on density functional theory calculations using PBE functional. The reaction barrier on Ir(1 0 0) was found to be 2.10 eV for CH3COOH formation, which is much higher than currently used Pd and Pt, and 0.57 eV for Csbnd C bond cleavage in CHCO species, which are comparable to Pd and Pt. The result suggests future directions for studying optimal complete EOR catalysts.

  2. IR-laser assisted additive freeform optics manufacturing. (United States)

    Hong, Zhihan; Liang, Rongguang


    Computer-controlled additive manufacturing (AM) processes, also known as three-dimensional (3D) printing, create 3D objects by the successive adding of a material or materials. While there have been tremendous developments in AM, the 3D printing of optics is lagging due to the limits in materials and tight requirements for optical applicaitons. We propose a new precision additive freeform optics manufacturing (AFOM) method using an pulsed infrared (IR) laser. Compared to ultraviolet (UV) curable materials, thermally curable optical silicones have a number of advantages, such as strong UV stability, non-yellowing, and high transmission, making it particularly suitable for optical applications. Pulsed IR laser radiation offers a distinct advantage in processing optical silicones, as the high peak intensity achieved in the focal region allows for curing the material quickly, while the brief duration of the laser-material interaction creates a negligible heat-affected zone.

  3. Relativistic Electron Acceleration with Ultrashort Mid-IR Laser Pulses (United States)

    Feder, Linus; Woodbury, Daniel; Shumakova, Valentina; Gollner, Claudia; Miao, Bo; Schwartz, Robert; Pugžlys, Audrius; Baltuška, Andrius; Milchberg, Howard


    We report the first results of laser plasma wakefield acceleration driven by ultrashort mid-infrared laser pulses (λ = 3.9 μm , pulsewidth 100 fs, energy width, as well as trends in the accelerated beam profiles, charge and energy spectra which are supported by 3D particle-in-cell simulations. These results extend earlier work with sub-TW self-modulated laser wakefield acceleration using near IR drivers to the Mid-IR, and enable us to capture time-resolved images of relativistic self-focusing of the laser pulse. This work supported by DOE (DESC0010706TDD, DESC0015516); AFOSR(FA95501310044, FA95501610121); NSF(PHY1535519); DHS.

  4. Photothermal IR spectroscopy with perforated membrane micromechanical resonators

    DEFF Research Database (Denmark)

    Kurek, Maksymilian

    and temperature sensor. The string could be considered as a single filter-fiber and guaranteed relatively high overall sampling efficiency through impaction of airborne nanoparticles on the resonator surface. When the analyte, collected by the sensor, is exposed to IR radiation it absorbs light at a certain......-IR method. In order to overcome them, string resonators were replaced by membranes. A reliable sampling technique was maintained by adding perforation to membranes and thereby essentially getting membrane porous filters. Membranes gave also access to fully integrated magnetic transduction that allowed...... for significant shrinkage and simplification of the system. An analytical model of a locally heated membrane was developed and confirmed through FEM simulations. Then, low stress silicon nitride perforated membranes were fabricated and characterized using two different experimental setups that employed optical...

  5. Divertor IR thermography on Alcator C-Moda) (United States)

    Terry, J. L.; LaBombard, B.; Brunner, D.; Payne, J.; Wurden, G. A.


    Alcator C-Mod is a particularly challenging environment for thermography. It presents issues that will similarly face ITER, including low-emissivity metal targets, low-Z surface films, and closed divertor geometry. In order to make measurements of the incident divertor heat flux using IR thermography, the C-Mod divertor has been modified and instrumented. A 6° toroidal sector has been given a 2° toroidal ramp in order to eliminate magnetic field-line shadowing by imperfectly aligned divertor tiles. This sector is viewed from above by a toroidally displaced IR camera and is instrumented with thermocouples and calorimeters. The camera provides time histories of surface temperatures that are used to compute incident heat-flux profiles. The camera sensitivity is calibrated in situ using the embedded thermocouples, thus correcting for changes and nonuniformities in surface emissivity due to surface coatings.

  6. Near diffraction limited mid-IR spectromicroscopy using frequency upconversion

    DEFF Research Database (Denmark)

    Sanders, Nicolai Højer; Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter


    Mid-infrared microscopy and spectroscopy is interesting due to its medical, biological and chemical applications. Spectromicroscopy can be used for histopathology, sample analysis and diagnosis. The ability to do spectromicroscopy in the 2.5 to 4.5 μm wavelength range where many organic molecules...... have their fundamental vibrations, with the addition of sufficient spectroscopic resolution to resolve these bands, cane.g.potentially allow for diagnostics without the need for staining of the sample. On a longer timeframe, mid-IR spectromicroscopy has the potential for in-vivo diagnostics, combining...... morphological and spectral imaging. Recent developments in nonlinear frequency upconversion, have demonstrated the potential to perform both imaging and spectroscopy in the mid-IR range at unparalleled low levels of illumination, the low upconversion detector noise being orders of magnitude below competing...

  7. First lasing of the IR upgrade FEL at Jefferson lab

    Energy Technology Data Exchange (ETDEWEB)

    Christopher Behre; Stephen Benson; George Biallas; James Boyce; Christopher Curtis; David Douglas; H. Dylla; L. Dillon-townes; Richard Evans; Albert Grippo; Joseph Gubeli; David Hardy; John Heckman; Carlos Hernandez-Garcia; Tommy Hiatt; Kevin Jordan; Nikolitsa Merminga; George Neil; Joseph Preble; Harvey Rutt; Michelle D. Shinn; Timothy Siggins; Hiroyuki Toyokawa; David W. Waldman; Richard Walker; Neil Wilson; Byung Yunn; Shukui Zhang


    We report initial lasing results from the IR Upgrade FEL at Jefferson Lab[1]. The electron accelerator was operated with low average current beam at 80 MeV. The time structure of the beam was 120 pC bunches at 4.678 MHz with up to 750 {micro}sec pulses at 2Hz. Lasing was established over the entire wavelength range of the mirrors (5.5-6.6 {micro}m). The detuning curve length, turn-on time, and power were in agreement with modeling results assuming a 1 psec FWHM micropulse. The same model predicts over 10 kW of power output with 10 mA of beam and 10% output coupling, which is the ultimate design goal of the IR Upgrade FEL. The behavior of the laser while the dispersion section strength was varied was found to qualitatively match predictions. Initial CW lasing results also will be presented.

  8. GPCR and IR genes in Schistosoma mansoni miracidia


    Liang, Di; Zhao, Min; Wang, Tianfang; McManus, Donald P.; Cummins, Scott F.


    Background Schistosoma species are responsible for the disease schistosomiasis, a highly prevalent helminthic disease that requires a freshwater snail as intermediate host. The S. mansoni free-living miracidium must utilize olfaction to find a suitable snail host, and certain types of rhodopsin G protein-coupled receptors (GPCRs) and ionotropic receptors (IRs) have been identified as olfactory receptors in other animal phyla. The Schistosoma genome project, together with the recent availabili...

  9. Physics and Applications of Unipolar Barriers in Infrared (IR) Detectors (United States)


    APPLIED PHYSICS LETTERS 106, 173505 (2015) 0003-6951/2015/106(17)/173505/4/$30.00 CV 2015 AIP Publishing LLC This article is copyrighted as... Physics Letters 106, 173505 (2015); doi: 10.1063/1.4919450 View online: View Table of Contents: http...AFRL-RV-PS- TR-2016-0120 AFRL-RV-PS- TR-2016-0120 PHYSICS AND APPLICATIONS OF UNIPOLAR BARRIERS IN INFRARED (IR) DETECTORS Gary Wicks University

  10. Adaptive IR Sensing Based on Advanced Nanostructures with Tunable Kinetics (United States)


    growth and processing technologies of semiconductor and graphene structures, and comprehensive analysis of the test structures and devices allowed the...based on traditional semiconductor heterostructures. 4.6.3 Graphene vertical cascade IR photodetectors We have proposed and evaluated the vertical...the single graphene layer, graphene bi-layers, graphene nano-ribbon, and multiple graphene layer structures opens up prospects of further enhancement

  11. Visible and IR spectroscopy of ablative ytterbium nanoparticles (United States)

    Tcibulnikova, Anna V.; Borkunov, Rodion Y.; Bryukhanov, Valery V.; Slezhkin, Vasiliy A.; Zyubin, Andrey Y.; Samusev, Ilya G.


    The presence of plasmon resonance in the region of 375 nm for ytterbium nanoparticles obtained by laser ablation in the stabilizer of AOT in heptane is established in the work. The dimensions of the ytterbium nanoparticles are determined by the dynamic scattering method. Raman spectra and absorption spectra were measured in the IR region. Characteristic vibration frequencies for ytterbium nanoparticles and scattering bands for a pure ytterbium metal surface are determined.

  12. Army PM UAS Spectrum Update (United States)


    assessment Raven RQ-11B Provide dedicated mission configured, UAV support to the Combat Aviation Brigade, Division Fires and Battlefield...Production buyout of 2358 systems (FY15) • Raven Surge on schedule • Gimbaled Payload production begins 3QFY12 • All DDL retrofit kits procured • Working...EO/IR/LI Gimbaled Payloads System Configuration Purpose Status Characteristics Characteristics/Description System Overview: RQ-11B Raven 6

  13. The electronic mechanism of the gamma/gamma' interface strength of Ir-based alloys

    CERN Document Server

    Chen, K; Tse, J S


    The electronic structures of the gamma/gamma' interface for two-phase Ir-based alloys (Ir/Ir sub 3 Ta and Ir/Ir sub 3 Ti) have been investigated by performing first-principles quantum mechanics DMol3 (a type of density functional theory for molecules) calculations. The Mayer bond order (MBO) is used to represent the shear and cohesion strengths of the interface by a local sum of the horizontal and vertical MBOs. By comparison with those for single-crystal Ir, the results show that both the cohesive and shear strengths of the gamma/gamma' interface for the Ir/Ir sub 3 Ta alloy increase. The cohesive strength of the interface for the Ir/Ir sub 3 Ti alloy increases, whereas the shear strength of the interface for Ir/Ir sub 3 Ti decreases. The electron charge density, the Hirshfeld charge, and orbital charge transfers are also calculated and analysed. An electronic mechanism for the gamma/gamma' interface strength of Ir-based alloys is then suggested.

  14. Power-Law Template for IR Point Source Clustering (United States)

    Addison, Graeme E.; Dunkley, Joanna; Hajian, Amir; Viero, Marco; Bond, J. Richard; Das, Sudeep; Devlin, Mark; Halpern, Mark; Hincks, Adam; Hlozek, Renee; hide


    We perform a combined fit to angular power spectra of unresolved infrared (IR) point sources from the Planck satellite (at 217,353,545 and 857 GHz, over angular scales 100 clustered power over the range of angular scales and frequencies considered is well fit by a simple power law of the form C_l\\propto I(sup -n) with n = 1.25 +/- 0.06. While the IR sources are understood to lie at a range of redshifts, with a variety of dust properties, we find that the frequency dependence of the clustering power can be described by the square of a modified blackbody, nu(sup beta) B(nu,T_eff), with a single emissivity index beta = 2.20 +/- 0.07 and effective temperature T_eff= 9.7 K. Our predictions for the clustering amplitude are consistent with existing ACT and South Pole Telescope results at around 150 and 220 GHz, as is our prediction for the effective dust spectral index, which we find to be alpha_150-220 = 3.68 +/- 0.07 between 150 and 220 GHz. Our constraints on the clustering shape and frequency dependence can be used to model the IR clustering as a contaminant in Cosmic Microwave Background anisotropy measurements. The combined Planck and BLAST data also rule out a linear bias clustering model.

  15. Blackbody radiation sources for the IR spectral range (United States)

    Ogarev, S. A.; Morozova, S. P.; Katysheva, A. A.; Lisiansky, B. E.; Samoylov, M. L.


    Metrological radiometric facilities for optoelectronic instruments calibration utilize in terms of standards as radiation detectors in a form of cryogenic radiometers (CR), so as radiation sources. However in practice, there are no CR working within IR spectral range. An alternative way of radiometric calibration in middle and far IR ranges is to develop a parametric series of standard radiation sources - blackbody (BB) models. The paper describes some of BBs developed at VNIIOFI for the last time [1] from cryogenic (80 K to 200 K), to low (about 200 K to 400 K) and medium (400 K to 700 K) temperature regions for calibration of the IR instruments under cryogenic-vacuum conditions. These BBs are presented by models of both types: variable-temperature and based on fixed points of Ga or In. BBs are characterized with high temperature uniformity and stability. Copper and aluminum alloys are used as the radiation cavity materials. The required value of emissivity ɛλ is achieved by using different black coatings. Low-temperature and cryogenic BBs are based on the principles of indirect multi-zone electric heating (with heat isolation from LN2 cooling loop, or by using an external liquid thermostat with circulating heat-transfer agent. The principles of operation, design and test results of BBs are described.

  16. Blackbody radiation sources for the IR spectral range

    Energy Technology Data Exchange (ETDEWEB)

    Ogarev, S. A.; Morozova, S. P.; Katysheva, A. A.; Lisiansky, B. E.; Samoylov, M. L. [All-Russian Research Institute for Optical and Physical Measurements (VNIIOFI), Moscow (Russian Federation)


    Metrological radiometric facilities for optoelectronic instruments calibration utilize in terms of standards as radiation detectors in a form of cryogenic radiometers (CR), so as radiation sources. However in practice, there are no CR working within IR spectral range. An alternative way of radiometric calibration in middle and far IR ranges is to develop a parametric series of standard radiation sources - blackbody (BB) models. The paper describes some of BBs developed at VNIIOFI for the last time [1] from cryogenic (80 K to 200 K), to low (about 200 K to 400 K) and medium (400 K to 700 K) temperature regions for calibration of the IR instruments under cryogenic-vacuum conditions. These BBs are presented by models of both types: variable-temperature and based on fixed points of Ga or In. BBs are characterized with high temperature uniformity and stability. Copper and aluminum alloys are used as the radiation cavity materials. The required value of emissivity ε{sub λ} is achieved by using different black coatings. Low-temperature and cryogenic BBs are based on the principles of indirect multi-zone electric heating (with heat isolation from LN2 cooling loop, or by using an external liquid thermostat with circulating heat-transfer agent. The principles of operation, design and test results of BBs are described.

  17. The IR Sector – Opening new horizons for CERN

    CERN Multimedia


    Last week saw the CERN family grow by one, as we welcomed Cyprus as an Associate Member in the pre-stage to Membership. This gives me a good opportunity, three months into the job, to share the vision for the new International Relations (IR) Sector. CERN is and always has been an incredible example of successful, inclusive international collaboration and exchange in the pursuit of common goals. The IR Sector continues and builds on that tradition and spirit.   In the 60-plus years of CERN’s existence, our world has been transformed at all levels. And over the last decade or so, the world of particle physics has evolved beyond recognition. CERN is now a global lab, with a European core, and particle physics is a field that is increasingly planned and coordinated around the world. It is for these reasons that CERN needs to develop its International Relations so we can respond to and navigate these changes. The establishment by the Director-General of the IR Sector is a sign of her commitm...

  18. A query suggestion workflow for life science IR-systems. (United States)

    Esch, Maria; Chen, Jinbo; Weise, Stephan; Hassani-Pak, Keywan; Scholz, Uwe; Lange, Matthias


    Information Retrieval (IR) plays a central role in the exploration and interpretation of integrated biological datasets that represent the heterogeneous ecosystem of life sciences. Here, keyword based query systems are popular user interfaces. In turn, to a large extend, the used query phrases determine the quality of the search result and the effort a scientist has to invest for query refinement. In this context, computer aided query expansion and suggestion is one of the most challenging tasks for life science information systems. Existing query front-ends support aspects like spelling correction, query refinement or query expansion. However, the majority of the front-ends only make limited use of enhanced IR algorithms to implement comprehensive and computer aided query refinement workflows. In this work, we present the design of a multi-stage query suggestion workflow and its implementation in the life science IR system LAILAPS. The presented workflow includes enhanced tokenisation, word breaking, spelling correction, query expansion and query suggestion ranking. A spelling correction benchmark with 5,401 queries and manually selected use cases for query expansion demonstrate the performance of the implemented workflow and its advantages compared with state-of-the-art systems.

  19. Weathering of tin oxide coated glass with low IR emissivity

    Energy Technology Data Exchange (ETDEWEB)

    Raedlein, E.; Buksak, A.; Heide, G.; Glaeser, H.J.; Frischat, G.H. [Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany). Inst. fuer Nichtmetallische Werkstoffe


    The weathering of K-glass has been studied by measuring transmission and reflection in the visible (VIS), near infrared (NIR) and infrared (IR) wavelength ranges, by chemical depth profiling with secondary neutral mass spectrometry (SNMS) and by atomic force microscopy (AFM) imaging. K-glass is a commercial tin oxide coated glass with low IR emissivity. The SnO{sub 2}:F-coated side has been exposed to atmospheric conditions for up to 32 weeks and for up to two years. It could be shown that the optical properties are only affected in the VIS range, but the visible contamination does not influence the high IR reflection. This means that the heat-insulating properties of window glazings with the K-glass coating on the surface do not degrade under atmospheric conditions. Chemical depth profiles did not reveal major changes, except for an increase in the signals of minor elements on the surface, namely sodium, carbon and silicon. AFM showed that after 32 weeks the deep valleys of the rather rough crystalline SnO{sub 2}:F are partially filled up. The high transmission of new K-glass can be regained since contamination or corrosion products can be removed by washing. The coating itself is chemically stable. (orig.)

  20. Anisotropic Magnetoresistance in Antiferromagnetic Sr_{2}IrO_{4}

    Directory of Open Access Journals (Sweden)

    C. Wang


    Full Text Available We report point-contact measurements of anisotropic magnetoresistance (AMR in a single crystal of antiferromagnetic Mott insulator Sr_{2}IrO_{4}. The point-contact technique is used here as a local probe of magnetotransport properties on the nanoscale. The measurements at liquid nitrogen temperature reveal negative magnetoresistances (up to 28% for modest magnetic fields (250 mT applied within the IrO_{2} a-b plane and electric currents flowing perpendicular to the plane. The angular dependence of magnetoresistance shows a crossover from fourfold to twofold symmetry in response to an increasing magnetic field with angular variations in resistance from 1% to 14%. We tentatively attribute the fourfold symmetry to the crystalline component of AMR and the field-induced transition to the effects of applied field on the canting of antiferromagnetic-coupled moments in Sr_{2}IrO_{4}. The observed AMR is very large compared to the crystalline AMRs in 3d transition metal alloys or oxides (0.1%–0.5% and can be associated with the large spin-orbit interactions in this 5d oxide while the transition provides evidence of correlations between electronic transport, magnetic order, and orbital states. The finding of this work opens an entirely new avenue to not only gain a new insight into physics associated with spin-orbit coupling but also to better harness the power of spintronics in a more technically favorable fashion.

  1. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    Energy Technology Data Exchange (ETDEWEB)

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A. [and others


    Uncooled pyroelectric IR imaging systems, such as night vision goggles, offer important strategic advantages in battlefield scenarios and reconnaissance surveys. Until now, the current technology for fabricating these devices has been limited by low throughput and high cost which ultimately limit the availability of these sensor devices. We have developed and fabricated an alternative design for pyroelectric IR imaging sensors that utilizes a multilayered thin film deposition scheme to create a monolithic thin film imaging element on an active silicon substrate for the first time. This approach combines a thin film pyroelectric imaging element with a thermally insulating SiO{sub 2} aerogel thin film to produce a new type of uncooled IR sensor that offers significantly higher thermal, spatial, and temporal resolutions at a substantially lower cost per unit. This report describes the deposition, characterization and optimization of the aerogel thermal isolation layer and an appropriate pyroelectric imaging element. It also describes the overall integration of these components along with the appropriate planarization, etch stop, adhesion, electrode, and blacking agent thin film layers into a monolithic structure. 19 refs., 8 figs., 6 tabs.

  2. Revenue Potential for Inpatient IR Consultation Services: A Financial Model. (United States)

    Misono, Alexander S; Mueller, Peter R; Hirsch, Joshua A; Sheridan, Robert M; Siddiqi, Assad U; Liu, Raymond W


    Interventional radiology (IR) has historically failed to fully capture the value of evaluation and management services in the inpatient setting. Understanding financial benefits of a formally incorporated billing discipline may yield meaningful insights for interventional practices. A revenue modeling tool was created deploying standard financial modeling techniques, including sensitivity and scenario analyses. Sensitivity analysis calculates revenue fluctuation related to dynamic adjustment of discrete variables. In scenario analysis, possible future scenarios as well as revenue potential of different-size clinical practices are modeled. Assuming a hypothetical inpatient IR consultation service with a daily patient census of 35 patients and two new consults per day, the model estimates annual charges of $2.3 million and collected revenue of $390,000. Revenues are most sensitive to provider billing documentation rates and patient volume. A range of realistic scenarios-from cautious to optimistic-results in a range of annual charges of $1.8 million to $2.7 million and a collected revenue range of $241,000 to $601,000. Even a small practice with a daily patient census of 5 and 0.20 new consults per day may expect annual charges of $320,000 and collected revenue of $55,000. A financial revenue modeling tool is a powerful adjunct in understanding economics of an inpatient IR consultation service. Sensitivity and scenario analyses demonstrate a wide range of revenue potential and uncover levers for financial optimization. Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.

  3. Infrared spectrum of ruthenium tetroxide isotopomers in an argon matrix (United States)

    Green, David W.; Kay, Jack G.; Zimmerman, George L.; Balko, Barbara A.


    RuO 4 isotopomer mixtures were synthesized with the natural abundances of Ru isotopes and mixtures of 16O and 18O. The bond-stretching region of the IR spectrum was examined using Fourier transform spectroscopy and in an argon matrix at 14 K. Wilson FG-matrix calculations permitted identification of all stretching frequencies except forbidden ν1 vibrations of Ru 16O 4 and Ru 18O 4 and confirmed undistorted tetrahedral geometry. Calculated and observed frequencies agreed with a mean deviation of 0.56 cm -1. Values compared well with gas values and with an average matrix shift of -3.2 ± 0.4 cm -1. Relative intensities were well matched using the simple classical concept of additive bond dipole moments. Intense UV irradiation of the mixture did not dissociate the RuO 4 into smaller fragments, contrary to the behavior of the gas.

  4. Chemical imaging of the surface of self-assembled polystyrene-b-poly(methyl methacrylate) diblock copolymer films using apertureless near-field IR microscopy. (United States)

    Mueller, Kerstin; Yang, Xiujuan; Paulite, Melissa; Fakhraai, Zahra; Gunari, Nikhil; Walker, Gilbert C


    The nanoscale chemical composition variations of the surfaces of thin films of polystyrene- b-poly(methyl methacrylate) (PS- b-PMMA) diblock copolymers are investigated using apertureless near-field IR microscopy. The scattering of the incident infrared beam from a modulated atomic force microscopy (AFM) tip is probed using homodyne detection and demodulation at the tip oscillation frequency. An increase in the IR attenuation is observed in the PMMA-rich domains with a wavenumber dependence that is consistent with the bulk absorption spectrum. The results indicate that even though a small topography-induced artifact can be observed in the near-field images, the chemical signature of the sample is detected clearly.

  5. The Biokinetic Spectrum for Temperature (United States)

    Corkrey, Ross; McMeekin, Tom A.; Bowman, John P.; Ratkowsky, David A.; Olley, June; Ross, Tom


    We identify and describe the distribution of temperature-dependent specific growth rates for life on Earth, which we term the biokinetic spectrum for temperature. The spectrum has the potential to provide for more robust modeling in thermal ecology since any conclusions derived from it will be based on observed data rather than using theoretical assumptions. It may also provide constraints for systems biology model predictions and provide insights in physiology. The spectrum has a Δ-shape with a sharp peak at around 42°C. At higher temperatures up to 60°C there was a gap of attenuated growth rates. We found another peak at 67°C and a steady decline in maximum rates thereafter. By using Bayesian quantile regression to summarise and explore the data we were able to conclude that the gap represented an actual biological transition between mesophiles and thermophiles that we term the Mesophile-Thermophile Gap (MTG). We have not identified any organism that grows above the maximum rate of the spectrum. We used a thermodynamic model to recover the Δ-shape, suggesting that the growth rate limits arise from a trade-off between activity and stability of proteins. The spectrum provides underpinning principles that will find utility in models concerned with the thermal responses of biological processes. PMID:27088362

  6. Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR. (United States)

    Perkins, W. D.


    This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)

  7. Detectors with Improved Near-to-Mid IR Performance and Reduced Cooling Requirements Project (United States)

    National Aeronautics and Space Administration — This STTR Phase I proposal addresses a NASA need for improved near-to-mid IR detectors for imaging and spectroscopy. High performance IR detectors with cutoff...

  8. Tax Administration: Information on Selected IRS Tax Enforcement and Collection Efforts

    National Research Council Canada - National Science Library


    ...) in enforcing the nation's tax laws. These two topics will be discussed: (1) the relationship between IRS audits of taxpayers and other programs IRS uses to ensure that taxpayers returns are accurate, and (2...

  9. Impact of amorphization on the electronic properties of Zn-Ir-O systems (United States)

    Muñoz Ramo, David; Bristowe, Paul D.


    We analyze the geometry and electronic structure of a series of amorphous Zn-Ir-O systems using classical molecular dynamics followed by density functional theory taking into account two different charge states of Ir (+3 and  +4). The structures obtained consist of a matrix of interconnected metal-oxygen polyhedra, with Zn adopting preferentially a coordination of 4 and Ir a mixture of coordinations between 4 and 6 that depend on the charge state of Ir and its concentration. The amorphous phases display reduced band gaps compared to crystalline ZnIr2O4 and exhibit localized states near the band edges, which harm their transparency and hole mobility. Increasing amounts of Ir in the Ir4+ phases decrease the band gap further while not altering it significantly in the Ir3+ phases. The results are consistent with recent transmittance and resistivity measurements.

  10. Can the tinnitus spectrum identify tinnitus subgroups?

    NARCIS (Netherlands)

    Heijneman, Karin M.; de Kleine, Emile; Wiersinga-Post, Esther; van Dijk, Pim


    The tinnitus spectrum is a psycho-acoustic metric of tinnitus. Previous work found a tight relation between the spectrum and the tone audiogram. This suggests that the spectrum and the audiogram provide essentially the same information, and the added value of the spectrum is limited. In order to

  11. Quantitative vapor-phase IR intensities and DFT computations to predict absolute IR spectra based on molecular structure: I. Alkanes (United States)

    Williams, Stephen D.; Johnson, Timothy J.; Sharpe, Steven W.; Yavelak, Veronica; Oates, R. P.; Brauer, Carolyn S.


    Recently recorded quantitative IR spectra of a variety of gas-phase alkanes are shown to have integrated intensities in both the C3H stretching and C3H bending regions that depend linearly on the molecular size, i.e. the number of C3H bonds. This result is well predicted from CH4 to C15H32 by density functional theory (DFT) computations of IR spectra using Becke's three parameter functional (B3LYP/6-31+G(d,p)). Using the experimental data, a simple model predicting the absolute IR band intensities of alkanes based only on structural formula is proposed: For the C3H stretching band envelope centered near 2930 cm-1 this is given by (km/mol) CH_str=(34±1)×CH-(41±23) where CH is number of C3H bonds in the alkane. The linearity is explained in terms of coordinated motion of methylene groups rather than the summed intensities of autonomous -CH2-units. The effect of alkyl chain length on the intensity of a C3H bending mode is explored and interpreted in terms of conformer distribution. The relative intensity contribution of a methyl mode compared to the total C3H stretch intensity is shown to be linear in the number of methyl groups in the alkane, and can be used to predict quantitative spectra a priori based on structure alone.

  12. IrOx core-shell nanocatalysts for cost- and energy-efficient electrochemical water splitting


    Nong, H; Gan, L; Willinger, E.; Teschner, D.; Strasser, P.


    A family of dealloyed metal–oxide hybrid (M1M2@M1Ox) core@shell nanoparticle catalysts is demonstrated to provide substantial advances toward more efficient and less expensive electrolytic water splitting. IrNi@IrOx nanoparticles were synthesized from IrNix precursor alloys through selective surface Ni dealloying and controlled surface oxidation of Ir. Detailed depth-resolved insight into chemical structure, composition, morphology, and oxidation state was obtained using spectroscopic, diffra...

  13. Nanomechanical IR Spectroscopy for the fast analysis of picogram samples of engineered nanomaterials

    DEFF Research Database (Denmark)

    Andersen, Alina Joukainen; Ek, Pramod Kumar; Andresen, Thomas Lars


    The proliferation of engineered nanomaterials (ENMs), e.g. in nanomedicine, demands for novel sensitive techniques allowing for the analysis of minute samples. We present nanoelectromechanical system-based IR spectroscopy (NEMS-IR) of picograms of polymeric micelles. The micelles are nebulized......, compared to 2 days for analysis by ATR-FT-IR. NEMS-IR constitutes a promising technique for the fast analysis of ENMs....

  14. Noncryogenic quantum detection in the mid-IR using InAsSb photovoltaic structures (United States)

    Rakovska, Anna; Berger, Vincent; Marcadet, Xavier; Glastre, Genevieve; Vinter, Borge


    We describe a mid-IR photovoltaic detector using InAsSb as active material, grown by MBE on a GaSb substrate. The purpose of this study is to show that quantum detectors can offer an alternative to thermal detectors (pyroelectric or resistive bolometers) for high temperature (near room temperature) operation. With a 9% Sb content, InAsSb is lattice matched to GaSb and thus provides an excellent material quality, with Shockley-Read lifetimes of the order of 200 ns as measured by photoconductive gain measurements as well as time resolved photoconductivity experiments. The band gap of InAsSb corresponds to a wavelength of 5 microns at room temperature. This makes InAsSb an ideal candidate for room temperature detection in the 3-5 microns atmospheric window. Photovoltaic structures are characterized by current voltage characteristics as a function of temperature. Using the absorption value obtained on the test samples, a detectivity of 7X109 Jones at 3.5 micrometers is estimated at a temperature of 250 K, which can easily be reached with Peltier cooling. Considering the photovoltaic spectrum, this leads to a NETD lower than 80 mK.

  15. Provision of IR-UWB wireless and baseband wired services over a WDM-PON. (United States)

    Pan, Shilong; Yao, Jianping


    A simple scheme to simultaneously generate an on-off keying or bi-phase modulation (BPM) impulse radio ultra wideband (IR-UWB) signal and a baseband wired signal in the optical domain using a dual-drive modulator is proposed and demonstrated. Although the two signals have spectral overlap in the optical spectrum, they are located at different frequency bands when converted to electrical signals at a photodetector (PD), which can be well separated by an electrical filter. An experiment is carried out. Eye diagrams, electrical spectra and BER measurements show that the co-channel interference between the UWB and the wired signals is small for a single-channel 36-km fiber link to provide 1.25-Gb/s UWB wireless and 1.25-Gb/s baseband wired services. The inter-channel interference is also small and negligible when the link is operated together with two other 1.25 Gb/s baseband wired links, which demonstrates that a conventional WDM-PON can be upgraded to provide additional UWB services without affecting the existing services by modifying the modulators in the center office and inserting UWB antennas in the optical network units. © 2011 Optical Society of America

  16. Laser- and gamma-ray induced crystallization of IR-transmitting calcium gallate glass (United States)

    Nishida, T.; Kubuki, S.; Takashima, Y.; Mikami, M.; Yagi, T.


    Ar+-laser ( λ=488 nm) irradiation of calcium gallate (CG) glass with the composition of 60CaO·39Ga2O3·Fe2O3 resulted in a distinct decrease in the IR transmittance ( T) due to the formation of crystalline CaGa2O4 and CaGa4O9 phases. The Mössbauer spectrum of non-irradiated glass comprised a broad doublet due to distorted Fe3+(Td) with δ, Δ, and Γ of 0.20, 1.33, and 1.00 mm s-1, respectively. An additional doublet due to Fe3+(Td) was observed in the Ar+-irradiated glass and δ, Δ, and Γ were 0.17, 1.32, and 0.75 mm s-1, respectively. A decrease in T was also observed after the60Co γ-ray irradiation with doses ≥105Gy, and the precipitation of CaO, Ga2O3, and CaGa4O7 phases was confirmed by X-ray diffraction.

  17. Luminosity Spectrum Reconstruction at Linear Colliders

    CERN Document Server

    Poss, Stéphane


    A good knowledge of the luminosity spectrum is mandatory for many measurements at future e+e- colliders. As the beam-parameters determining the luminosity spectrum cannot be measured precisely, the luminosity spectrum has to be measured through a gauge process with the detector. The measured distributions, used to reconstruct the spectrum, depend on Initial State Radiation, cross-section, and Final State Radiation. To extract the basic luminosity spectrum, a parametric model of the luminosity spectrum is created, in this case the spectrum at the 3 TeV Compact Linear Collider (CLIC). The model is used within a reweighting technique to extract the luminosity spectrum from measured Bhabha event observables, taking all relevant effects into account. The centre-of-mass energy spectrum is reconstructed within 5% over the full validity range of the model. The reconstructed spectrum does not result in a significant bias or systematic uncertainty in the exemplary physics benchmark process of smuon pair production.

  18. Dynamic spectrum auction in wireless communication

    CERN Document Server

    Chen, Yanjiao


    This brief explores current research on dynamic spectrum auctions, focusing on fundamental auction theory, characteristics of the spectrum market, spectrum auction architecture and possible auction mechanisms. The brief explains how dynamic spectrum auctions, which enable new users to gain spectrum access and existing spectrum owners to obtain financial benefits, can greatly improve spectrum efficiency by resolving the artificial spectrum shortage. It examines why operators and users face significant challenges due to specialty of the spectrum market and the related requirements imposed on the auction mechanism design. Concise and up-to-date, Dynamic Spectrum Auction in Wireless Communication is designed for researchers and professionals in computer science or electrical engineering. Students studying networking will also find this brief a valuable resource.

  19. The phase system Fe-Ir-S at 1100, 1000 and 800 degree C

    DEFF Research Database (Denmark)

    Makovicky, Emil; Karup-Møller, Sven


    Phase relations in the dry condensed Fe-Ir-S system were determined at 1100, 1000 and 800 degrees C. Orientational runs were performed at 500 degrees C. Between 1100 and 800 degrees C, the system comprises five sulphides and an uninterrupted field of gamma(Fe, Ir). Fe1-xS dissolves 5.8 at.% Ir...... at 1100 degrees C, 3.4 at.% Ir at 1000 degrees C and 1.0 at.% Ir at 800 degrees C. The solubility of Fe in Ir2S3, IrS2 and IrSsimilar to 3 increases with decreasing temperature, reaching 2.5 at.% in the latter two sulphides at 800 degrees C. Thiospinel 'FeIr2S4' is nonstoichiometric, from Fe22.3Ir19.8S58.......0 to Fe18.9Ir23.1S58.0, depending on a(S) and a(Fe) i.e. on a phase association. Thiospinel is absent at 800 and 500 degrees C....

  20. Semiclassical relations and IR effects in de Sitter and slow-roll space-times

    DEFF Research Database (Denmark)

    B. Giddings, Steven; Sloth, Martin Snoager


    We calculate IR divergent graviton one-loop corrections to scalar correlators in de Sitter space, and show that the leading IR contribution may be reproduced via simple semiclassical consistency relations. One can likewise use such semiclassical relations to calculate leading IR corrections to co...... with a sharp perturbative calculation of "missing information" in Hawking radiation....

  1. Isolation of site-specific anharmonicities of individual water molecules in the I-·(H2O)2 complex using tag-free, isotopomer selective IR-IR double resonance (United States)

    Yang, Nan; Duong, Chinh H.; Kelleher, Patrick J.; Johnson, Mark A.; McCoy, Anne B.


    We reveal the microscopic mechanics of iodide ion microhydration by recording the isotopomer-selective vibrational spectra of the I-·(H2O)·(D2O), I-·(HOD)·(D2O), and I-·(DOH)·(H2O) isotopologues using a new class of ion spectrometer that is optimized to carry out two-color, IR-IR photodissociation in a variety of pump-probe schemes. Using one of these, we record the linear absorption spectrum of a cryogenically cooled cluster without the use of a messenger ;tag;. In another protocol, we reveal the spectra of individual H2O and D2O molecules embedded in each of the two possible binding sites in the iodide dihydrate, as well as the bands due to individual OH and OD groups in each of the four local binding environments. Finally, we demonstrate how temperature dependent isotopic scrambling among the spectral features can be used to monitor the onset of large amplitude motion, heretofore inferred from changes in the envelope of the OH stretching vibrational manifold.

  2. On formation mechanism of Pd-Ir bimetallic nanoparticles through thermal decomposition of [Pd(NH{sub 3}){sub 4}][IrCl{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Asanova, Tatyana I., E-mail:; Asanov, Igor P. [Nikolaev Institute of Inorganic Chemistry SB RAS (Russian Federation); Kim, Min-Gyu [Pohang University of Science and Technology, Beamline Research Division (Korea, Republic of); Gerasimov, Evgeny Yu. [Boreskov Institute of Catalysis SB RAS (Russian Federation); Zadesenets, Andrey V.; Plyusnin, Pavel E.; Korenev, Sergey V. [Nikolaev Institute of Inorganic Chemistry SB RAS (Russian Federation)


    The formation mechanism of Pd-Ir nanoparticles during thermal decomposition of double complex salt [Pd(NH{sub 3}){sub 4}][IrCl{sub 6}] has been studied by in situ X-ray absorption (XAFS) and photoelectron (XPS) spectroscopies. The changes in the structure of the Pd and Ir closest to the surroundings and chemical states of Pd, Ir, Cl, and N atoms were traced in the range from room temperature to 420 Degree-Sign C in inert atmosphere. It was established that the thermal decomposition process is carried out in 5 steps. The Pd-Ir nanoparticles are formed in pyramidal/rounded Pd-rich (10-200 nm) and dendrite Ir-rich (10-50 nm) solid solutions. A d charge depletion at Ir site and a gain at Pd, as well as the intra-atomic charge redistribution between the outer d and s and p electrons of both Ir and Pd in Pd-Ir nanoparticles, were found to occur.Graphical Abstract.

  3. Autism Spectrum Disorders in Iran


    Mohammadi, Mohammad Reza; Salmanian, Maryam; AKHONDZADEH, Shahin


    How to Cite this Article: Mohammadi MR, Salmanian M, Akhondzadeh Sh. Autism Spectrum Disorders in Iran. Iranian Journal of Child Neurology2011;5(4):1-9.ObjectiveAutistic disorder, Asperger syndrome, and PDD-Not Otherwise Specified are subsets of autism spectrum disorders (ASDs), which are characterized by impairments in social communication and stereotyped behavior. This article reviews the prevalence, etiology, diagnosis, and treatment of ASDs in Iran.Materials & MethodsWe searched PubMe...

  4. Determination of the Ability to Measure Traces of Water in Dehydrated Residues of Waste Water by IR Diffuse Reflectance Spectra (United States)

    Pratsenka, S. V.; Voropai, E. S.; Belkin, V. G.


    Rapid measurement of the moisture content of dehydrated residues is a critical problem, the solution of which will increase the efficiency of treatment facilities and optimize the process of applying flocculants. The ability to determine the moisture content of dehydrated residues using a meter operating on the IR reflectance principle was confirmed experimentally. The most suitable interference filters were selected based on an analysis of the obtained diffuse reflectance spectrum of the dehydrated residue in the range 1.0-2.7 μm. Calibration curves were constructed and compared for each filter set. A measuring filter with a transmittance maximum at 1.19 μm and a reference filter with a maximum at 1.3 μm gave the best agreement with the laboratory measurements.

  5. Generation and mid-IR measurement of a gas-phase to predict security parameters of aviation jet fuel. (United States)

    Gómez-Carracedo, M P; Andrade, J M; Calviño, M A; Prada, D; Fernández, E; Muniategui, S


    The worldwide use of kerosene as aviation jet fuel makes its safety considerations of most importance not only for aircraft security but for the workers' health (chronic and/or acute exposure). As most kerosene risks come from its vapours, this work focuses on predicting seven characteristics (flash point, freezing point, % of aromatics and four distillation points) which assess its potential hazards. Two experimental devices were implemented in order to, first, generate a kerosene vapour phase and, then, to measure its mid-IR spectrum. All the working conditions required to generate the gas phase were optimised either in a univariate or a multivariate (SIMPLEX) approach. Next, multivariate prediction models were deployed using partial least squares regression and it was found that both the average prediction errors and precision parameters were satisfactory, almost always well below the reference figures.

  6. Measurement of the water content in oil and oil products using IR light-emitting diode-photodiode optrons (United States)

    Bogdanovich, M. V.; Kabanau, D. M.; Lebiadok, Y. V.; Shpak, P. V.; Ryabtsev, A. G.; Ryabtsev, G. I.; Shchemelev, M. A.; Andreev, I. A.; Kunitsyna, E. V.; Ivanov, E. V.; Yakovlev, Yu. P.


    The feasibility of using light-emitting devices, the radiation spectrum of which has maxima at wavelengths of 1.7, 1.9, and 2.2 μm for determining the water concentration in oil and oil products (gasoline, kerosene, diesel fuel) has been demonstrated. It has been found that the measurement error can be lowered if (i) the temperature of the light-emitting diode is maintained accurate to 0.5-1.0°C, (ii) by using a cell through which a permanently stirred analyte is pumped, and (iii) by selecting the repetition rate of radiation pulses from the light-emitting diodes according to the averaging time. A meter of water content in oil and oil products has been developed that is built around IR light-emitting device-photodiode optrons. This device provides water content on-line monitoring accurate to 1.5%.

  7. Generation and mid-IR measurement of a gas-phase to predict security parameters of aviation jet fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gomez-Carracedo, M.P.; Andrade, J.M.; Calvino, M.A.; Prada, D.; Fernandez, E.; Muniategui, S. [Department of Analytical Chemistry, University of A Coruna, Campus da Zapateira s/n, E-15071, A Coruna (Spain)


    The worldwide use of kerosene as aviation jet fuel makes its safety considerations of most importance not only for aircraft security but for the workers' health (chronic and/or acute exposure). As most kerosene risks come from its vapours, this work focuses on predicting seven characteristics (flash point, freezing point, % of aromatics and four distillation points) which assess its potential hazards. Two experimental devices were implemented in order to, first, generate a kerosene vapour phase and, then, to measure its mid-IR spectrum. All the working conditions required to generate the gas phase were optimised either in a univariate or a multivariate (SIMPLEX) approach. Next, multivariate prediction models were deployed using partial least squares regression and it was found that both the average prediction errors and precision parameters were satisfactory, almost always well below the reference figures.

  8. Characterization of extracellular vesicles by IR spectroscopy: Fast and simple classification based on amide and CH stretching vibrations. (United States)

    Mihály, Judith; Deák, Róbert; Szigyártó, Imola Csilla; Bóta, Attila; Beke-Somfai, Tamás; Varga, Zoltán


    Extracellular vesicles isolated by differential centrifugation from Jurkat T-cell line were investigated by attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR). Amide and CH stretching band intensity ratios calculated from IR bands, characteristic of protein and lipid components, proved to be distinctive for the different extracellular vesicle subpopulations. This proposed 'spectroscopic protein-to-lipid ratio', combined with the outlined spectrum-analysis protocol is valid also for low sample concentrations (0.15-0.05mg/ml total protein content) and can carry information about the presence of other non-vesicular formations such as aggregated proteins, lipoproteins and immune complexes. Detailed analysis of IR data reveals compositional changes of extracellular vesicles subpopulations: second derivative spectra suggest changes in protein composition from parent cell towards exosomes favoring proteins with β-turns and unordered motifs at the expense of intermolecular β-sheet structures. The IR-based protein-to-lipid assessment protocol was tested also for red blood cell derived microvesicles for which similar values were obtained. The potential applicability of this technique for fast and efficient characterization of vesicular components is high as the investigated samples require no further preparations and all the different molecular species can be determined in the same sample. The results indicate that ATR-FTIR measurements provide a simple and reproducible method for the screening of extracellular vesicle preparations. It is hoped that this sophisticated technique will have further impact in extracellular vesicle research. Copyright © 2016 Elsevier B.V. All rights reserved.


    Directory of Open Access Journals (Sweden)

    Roberta de Souza Leone


    Full Text Available EGA (Evolved Gas Analysis is a group of coupled techniques (in this case TG-DSC and FT-IR that was used to provide information about the thermal and calorimetric behavior of standard fructooligosaccharides (FOS from chicory. These FOS are found in several foods (tuber, roots, fruits, leaves, cereals, etc. and have been the subject of several studies. In the present study thermogravimetry (TG allowed the characterization of FOS a standard (Sigma-Aldrich, in which the weight loss can be observed in three stages (m 7.56, 55.53 and 36.53%, respectively. The simultaneous use of DSC showed endo and exothermic events in temperature characteristics and in agreement with TG curves. The enthalpies of the main stages of decomposition were calculated: ΔHdehydr 260 J g-1 and ΔHdec 410 J g-1. From the FT-IR spectrum of the volatiles was possible to characterize the main bands, which confirmed CO and CO2 as a result of thermal decomposition.

  10. Measurement of Gas and Aerosol Phase Absorption Spectra across the Visible and Near-IR Using Supercontinuum Photoacoustic Spectroscopy. (United States)

    Radney, James G; Zangmeister, Christopher D


    We demonstrate a method to measure the absorption spectra of gas and aerosol species across the visible and near-IR (500 to 840 nm) using a photoacoustic (PA) spectrometer and a pulsed supercontinuum laser source. Measurements of gas phase absorption spectra were demonstrated using H2O(g) as a function of relative humidity (RH). The measured absorption intensities and peak shapes were able to be quantified and compared to spectra calculated using the 2012 High Resolution Transmission (HITRAN2012) database. Size and mass selected nigrosin aerosol was used to measure absorption spectra across the visible and near-IR. Spectra were measured as a function of aerosol size/mass and show good agreement to Mie theory calculations. Lastly, we measured the broadband absorption spectrum of flame generated soot aerosol at 5% and 70% RH. For the high RH case, we are able to quantifiably separate the soot and water absorption contributions. For soot, we observe an enhancement in the mass specific absorption cross section ranging from 1.5 at 500 nm (p < 0.01) to 1.2 at 840 nm (p < 0.2) and a concomitant increase in the absorption Ångström exponent from 1.2 ± 0.4 (5% RH) to 1.6 ± 0.3 (70% RH).

  11. FT-IR reflection spectra of single crystals: resolving phonons of different symmetry without using polarised radiation

    Directory of Open Access Journals (Sweden)



    Full Text Available Fourier-transform infrared (FT-IR reflection spectra, asquired at nearnormal incidence, were recorded from single crystals belonging to six crystal systems: CsCr(SO42.12H2O (alum, cubic, K2CuCl2·2H2O (Mitscherlichite, tetragonal, CaCO3 (calcite, hexagonal, KHSO4 (mercallite, orthorhombic, CaSO4·2H2O (gypsum, monoclinic and CuSO4·5H2O (chalcantite, triclinic. The acquired IR reflection spectra were further transformed into absorption spectra, employing the Kramers-Kronig transformation. Except for the cubic alums, the spectra strongly depend on the crystal face from which they were recorded; this is a consequence of anisotropy. Phonons of a given symmetry (E-species, in tetragonal/hexagonal and B-species, in monoclinic crystals may be resolved without using a polariser. The spectrum may be simplified in the case of an orthorhombic crystal, as well. The longitudinal-optical (LO and transversal-optical (TO mode frequencies were calculated in the case of optically isotropic and the simplified spectra of optically uniaxial crystals.

  12. FT-IR analysis of high temperature annealing effects in a-SiC:H thin films (United States)

    Frischmuth, Tobias; Schneider, Michael; Grille, Thomas; Schmid, U.


    Hydrogenated amorphous SiC (a-SiC:H) is an attractive material for MEMS applications where high robustness or operation in harsh environments is targeted. In previous publications, it was demonstrated, that the properties of a-SiC:H thin films can be tailored over a wide range by changing the auxiliary table excitation power of a dual plasma source deposition process using an inductively coupled plasma-enhanced chemical vapour deposition system. In this work, the annealing behavior of dual plasma source deposited a-SiC:H thin films under argon atmosphere is investigated by using Fourier transform infrared (FT-IR) spectroscopy for chemical analysis. All investigated layers show a decrease of hydrogen containing bonds (X-Hx) and an increase of Si-C bonds with increasing annealing temperature in the FT-IR spectrum. This behaviour is directly linked to the effusion of hydrogen from the thin films at elevated temperatures. In addition, films deposited at higher auxiliary plasma power show more X-Hx and less Si-C bonds, indicating a higher hydrogen amount in those films. All layers shrink with increasing annealing temperature due to the effusion of hydrogen with a stronger shrink at higher PT values caused by the increased hydrogen amount. This shrink also leads to a densification of the thin films.

  13. Study on seasonal IR signature change of a ship by considering seasonal marine environmental conditions (United States)

    Kim, Do-Hwi; Han, Kuk-Il; Choi, Jun-Hyuk; Kim, Tae-Kuk


    Infrared (IR) signal emitted from objects over 0 degree Kelvin has been used to detect and recognize the characteristics of those objects. Recently more delicate IR sensors have been applied for various guided missiles and they affect a crucial influence on object's survivability. Especially, in marine environment it is more vulnerable to be attacked by IR guided missiles since there are nearly no objects for concealment. To increase the survivability of object, the IR signal of the object needs to be analyzed properly by considering various marine environments. IR signature of a naval ship consists of the emitted energy from ship surface and the reflected energy by external sources. Surface property such as the emissivity and the absorptivity on the naval ship varies with different paints applied on the surface and the reflected IR signal is also affected by the surface radiative property, the sensor's geometric position and various climatic conditions in marine environment. Since the direct measurement of IR signal using IR camera is costly and time consuming job, computer simulation methods are developing rapidly to replace those experimental tasks. In this study, we are demonstrate a way of analyzing the IR signal characteristics by using the measured background IR signals using an IR camera and the estimated target IR signals from the computer simulation to find the seasonal trends of IR threats of a naval ship. Through this process, measured weather data are used to analyze more accurate IR signal conditions for the naval ship. The seasonal change of IR signal contrast between the naval ship and the marine background shows that the highest contrast radiant intensity (CRI) value is appeared in early summer.

  14. Formation and reactivity of a porphyrin iridium hydride in water: acid dissociation constants and equilibrium thermodynamics relevant to Ir-H, Ir-OH, and Ir-CH2- bond dissociation energetics. (United States)

    Bhagan, Salome; Wayland, Bradford B


    Aqueous solutions of group nine metal(III) (M = Co, Rh, Ir) complexes of tetra(3,5-disulfonatomesityl)porphyrin [(TMPS)M(III)] form an equilibrium distribution of aquo and hydroxo complexes ([(TMPS)M(III)(D(2)O)(2-n)(OD)(n)]((7+n)-)). Evaluation of acid dissociation constants for coordinated water show that the extent of proton dissociation from water increases regularly on moving down the group from cobalt to iridium, which is consistent with the expected order of increasing metal-ligand bond strengths. Aqueous (D(2)O) solutions of [(TMPS)Ir(III)(D(2)O)(2)](7-) react with dihydrogen to form an iridium hydride complex ([(TMPS)Ir-D(D(2)O)](8-)) with an acid dissociation constant of 1.8(0.5) × 10(-12) (298 K), which is much smaller than the Rh-D derivative (4.3 (0.4) × 10(-8)), reflecting a stronger Ir-D bond. The iridium hydride complex adds with ethene and acetaldehyde to form organometallic derivatives [(TMPS)Ir-CH(2)CH(2)D(D(2)O)](8-) and [(TMPS)Ir-CH(OD)CH(3)(D(2)O)](8-). Only a six-coordinate carbonyl complex [(TMPS)Ir-D(CO)](8-) is observed for reaction of the Ir-D with CO (P(CO) = 0.2-2.0 atm), which contrasts with the (TMPS)Rh-D analog which reacts with CO to produce an equilibrium with a rhodium formyl complex ([(TMPS)Rh-CDO(D(2)O)](8-)). Reactivity studies and equilibrium thermodynamic measurements were used to discuss the relative M-X bond energetics (M = Rh, Ir; X = H, OH, and CH(2)-) and the thermodynamically favorable oxidative addition of water with the (TMPS)Ir(II) derivatives. © 2011 American Chemical Society

  15. HST/WFC3-IR Observations in M83 (United States)

    Ferguson, Brian A.; Whitmore, B.; Chandar, R.; Calzetti, D.; Blair, W. P.; Bushouse, H.; Mutchler, M.; Maíz Apellániz, J.; O'Connell, R.; WFC3 SOC Team


    The nearby spiral galaxy M83 has been observed using the Wide Field Camera 3 (WFC3) as part of the Early Release Science (ERS) program. Seven broad-band filters (including the near-IR filters, F110W and F160W) and seven emission-line filters (including the near IR filters, F128N and F164N) have been used to obtain full panchromatic wavelength coverage of M83. In this contribution the near-IR filters are used in concert with the visible and near-UV filters to determine the fraction of "missing" compact star clusters which are still embedded in dust (i.e., Av > 3 magnitudes). A secondary goal is to determine the degree of stochasticity in age and mass estimates introduced by the presence (or absence) of red super giants (RSG) by comparing with extant simulations. A third goal is to study the presence of known SNRs, and identify new reddened SNRs, with the aid of the continuum-subtracted narrowband filters F128N and F164N. Special attention will be paid to the central region and the properties of the nucleus. This paper is based on Early Release Science observations made by the WFC3 Scientific Oversight Committee. We are grateful to the Director of the Space Telescope Science Institute for awarding Director's Discretionary time for this program. Support for program #11360 was provided by NASA through a grant from the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  16. Differentiation of Leishmania species by FT-IR spectroscopy (United States)

    Aguiar, Josafá C.; Mittmann, Josane; Ferreira, Isabelle; Ferreira-Strixino, Juliana; Raniero, Leandro


    Leishmaniasis is a parasitic infectious disease caused by protozoa that belong to the genus Leishmania. It is transmitted by the bite of an infected female Sand fly. The disease is endemic in 88 countries Desjeux (2001) [1] (16 developed countries and 72 developing countries) on four continents. In Brazil, epidemiological data show the disease is present in all Brazilian regions, with the highest incidences in the North and Northeast. There are several methods used to diagnose leishmaniasis, but these procedures have many limitations, are time consuming, have low sensitivity, and are expensive. In this context, Fourier Transform Infrared Spectroscopy (FT-IR) analysis has the potential to provide rapid results and may be adapted for a clinical test with high sensitivity and specificity. In this work, FT-IR was used as a tool to investigate the promastigotes of Leishmaniaamazonensis, Leishmaniachagasi, and Leishmaniamajor species. The spectra were analyzed by cluster analysis and deconvolution procedure base on spectra second derivatives. Results: cluster analysis found four specific regions that are able to identify the Leishmania species. The dendrogram representation clearly indicates the heterogeneity among Leishmania species. The band deconvolution done by the curve fitting in these regions quantitatively differentiated the polysaccharides, amide III, phospholipids, proteins, and nucleic acids. L. chagasi and L. major showed a greater biochemistry similarity and have three bands that were not registered in L. amazonensis. The L. amazonensis presented three specific bands that were not recorded in the other two species. It is evident that the FT-IR method is an indispensable tool to discriminate these parasites. The high sensitivity and specificity of this technique opens up the possibilities for further studies about characterization of other microorganisms.

  17. IR Spectrometer Using 90-degree Off-axis Parabolic Mirrors

    Energy Technology Data Exchange (ETDEWEB)

    Robert M. Malone, Richard, G. Hacking, Ian J. McKenna, and Daniel H. Dolan


    A gated spectrometer has been designed for real-time, pulsed infrared (IR) studies at the National Synchrotron Light ource at the Brookhaven National Laboratory. A pair of 90-degree, off-axis parabolic mirrors are used to relay the light from an entrance slit to an output IR recording camera. With an initial wavelength range of 1500–4500 nm required, gratings could not be used in the spectrometer because grating orders would overlap. A magnesium oxide prism, placed between these parabolic mirrors, serves as the dispersion element. The spectrometer is doubly telecentric. With proper choice of the air spacing between the prism and the second parabolic mirror, any spectral region of interest within the InSb camera array’s sensitivity region can be recorded. The wavelengths leaving the second parabolic mirror are collimated, thereby relaxing the camera positioning tolerance. To set up the instrument, two different wavelength (visible) lasers are introduced at the entrance slit and made collinear with the optical axis via flip mirrors. After dispersion by the prism, these two laser beams are directed to tick marks located on the outside housing of the gated IR camera. This provides first-order wavelength calibration for the instrument. Light that is reflected off the front prism face is coupled into a high-speed detector to verify steady radiance during the gated spectral imaging. Alignment features include tick marks on the prism and parabolic mirrors. This instrument was designed to complement singlepoint pyrometry, which provides continuous time histories of a small collection of spots from shock-heated targets.

  18. The mid-IR silicon photonics sensor platform (Conference Presentation) (United States)

    Kimerling, Lionel; Hu, Juejun; Agarwal, Anuradha M.


    Advances in integrated silicon photonics are enabling highly connected sensor networks that offer sensitivity, selectivity and pattern recognition. Cost, performance and the evolution path of the so-called `Internet of Things' will gate the proliferation of these networks. The wavelength spectral range of 3-8um, commonly known as the mid-IR, is critical to specificity for sensors that identify materials by detection of local vibrational modes, reflectivity and thermal emission. For ubiquitous sensing applications in this regime, the sensors must move from premium to commodity level manufacturing volumes and cost. Scaling performance/cost is critically dependent on establishing a minimum set of platform attributes for point, wearable, and physical sensing. Optical sensors are ideal for non-invasive applications. Optical sensor device physics involves evanescent or intra-cavity structures for applied to concentration, interrogation and photo-catalysis functions. The ultimate utility of a platform is dependent on sample delivery/presentation modalities; system reset, recalibration and maintenance capabilities; and sensitivity and selectivity performance. The attributes and performance of a unified Glass-on-Silicon platform has shown good prospects for heterogeneous integration on materials and devices using a low cost process flow. Integrated, single mode, silicon photonic platforms offer significant performance and cost advantages, but they require discovery and qualification of new materials and process integration schemes for the mid-IR. Waveguide integrated light sources based on rare earth dopants and Ge-pumped frequency combs have promise. Optical resonators and waveguide spirals can enhance sensitivity. PbTe materials are among the best choices for a standard, waveguide integrated photodetector. Chalcogenide glasses are capable of transmitting mid-IR signals with high transparency. Integrated sensor case studies of i) high sensitivity analyte detection in

  19. Molecular spectrum of lanthanide complexes with 2,3-dichlorobenzoic acid and 2,2-bipyridine. (United States)

    He, Shu-Mei; Sun, Shu-Jing; Zheng, Jun-Ru; Zhang, Jian-Jun


    With 2,3-dichlorobenzoic acid as the first ligands and 2,2'-bipyridine as the second ligands, the lanthanide complexes [Ln(2,3-DClBA)3bipy]2 [Ln=Nd(a), Sm(b), Eu(c), Tb(d), Dy(e), Ho(f)] have been synthesized. By using Infrared (IR) and Raman (R) spectra, the characteristics of the groups can be identified. The bands of lanthanide complexes have been analyzed and attributed, and clearly demonstrated with the use of the complementarity of IR and R. The experiment reveals that the bands of complexes are affected by lanthanide elements (Ln). The frequency of stretching vibration and breathing vibration of ring, together with the stretching vibration of the carbonyl group (νCO), tends to be rising as the atomic number of lanthanide increasing. Meanwhile, crystallography data demonstrate that the six carbonyl groups have different bond length and bond angle, which can lead to different vibration frequency. The second derivatives of IR show that there are multiple vibration frequencies existing in the symmetrical stretching vibration of the carbonyl group (νsCO). Therefore the second derivative of IR spectrum is a characteristic band of different coordination modes of carbonyl group. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. IRS issues guidance on tax-exempt bond requirements. (United States)

    Kalick, L


    Enforcing compliance with rules governing facilities financed with tax-exempt bonds recently has become an IRS priority. Integrated delivery systems (IDSs) that include such facilities, therefore, should take steps to ensure that the private business use of those facilities does not exceed the legal threshold amount, thereby jeopardizing the tax-exempt status of the bonds. Management contracts, research agreements, and leases are arrangements with the greatest potential to result in noncompliance. Instituting a compliance program to monitor the use of bond proceeds and minimize the amount of private business use of facilities over the bond term can reduce an organization's risk of penalty.

  1. Disintegration rate measurement of a 192Ir solution. (United States)

    Fonseca, K A; Koskinas, M F; Dias, M S


    The disintegration rate of 192Ir has been measured using the 4pibeta-gamma coincidence technique. This radionuclide decays by electron capture (EC) and beta-emission. Since the EC contribution is low (4.5%), it has been corrected using decay scheme data taken from the literature. This measurement has been performed in collaboration with the Laboratório Nacional de Metrologia das Radiações Ionizantes (IRDDM), in Rio de Janeiro. The results, which were obtained independently and employed different techniques, are compared with the Systéme International Reference (SIR) maintained at the Bureau International des Poids et Mesures.

  2. Study of heating capacity of focused IR light soldering systems. (United States)

    Anguiano, C; Félix, M; Medel, A; Bravo, M; Salazar, D; Márquez, H


    An experimental study about four optical setups used for developing a Focused IR Light Soldering System (FILSS) for Surface Mount Technology (SMT) lead-free electronic devices specifically for Ball Grid Arrays (BGA) is presented. An analysis of irradiance and infrared thermography at BGA surface is presented, as well as heat transfer by radiation and conduction process from the surface of the BGA to the solder balls. The results of this work show that the heating provided by our proposed optical setups, measured at the BGA under soldering process, meets the high temperature and uniform thermal distribution requirements, which are defined by the reflow solder method for SMT devices.

  3. New Material System for 3rd Generation IR Applications (United States)


    misfit dislocations need to be generated somewhere in the thin film stack to alleviate this energy which ultimately propagates into the IR-absorbing...different temperatures. All layers were nucleated on GaSb substrates, except the image shown in figure 4c, which was nucleated on a ZnTe /Si substrate. The...In fact, only one group has ever grown HgCdSe by MBE and that work was done in 1993 (5). Their work used zinc telluride ( ZnTe ) and CdZnTe as

  4. Improved Likelihood Function in Particle-based IR Eye Tracking

    DEFF Research Database (Denmark)

    Satria, R.; Sorensen, J.; Hammoud, R.


    In this paper we propose a log likelihood-ratio function of foreground and background models used in a particle filter to track the eye region in dark-bright pupil image sequences. This model fuses information from both dark and bright pupil images and their difference image into one model. Our...... enhanced tracker overcomes the issues of prior selection of static thresholds during the detection of feature observations in the bright-dark difference images. The auto-initialization process is performed using cascaded classifier trained using adaboost and adapted to IR eye images. Experiments show good...

  5. Dizaino apsaugos sistemos ir jų tarpusavio santykis


    Šablova, Julita Anastazija


    Specifinės dizaino prigimtis lemia tai, kad Lietuvoje ir Europos Sąjungoje dizainas gali būti saugomas pagal skirtingas apsaugos sistemas. Pirma, galima registruoti dizainą pagal Lietuvos Respublikos dizaino įstatymą. Antra, yra galimybė registruoti Bendrijos dizainą pagal 2001 m. gruodžio 12 d. Tarybos reglamentą (EB) Nr. 6/2002 dėl Bendrijos dizainų, kuris vieningai galios visoje ES teritorijoje. Be to šis Reglamentas numato neregistruoto dizaino apsaugą, neapsunkintą jokiais formalumais. T...

  6. IR Thermography of International Space Station Radiator Panels (United States)

    Koshti, Ajay; Winfree, WIlliam; Morton, Richard; Howell, Patricia


    Several non-flight qualification test radiators were inspected using flash thermography. Flash thermography data analysis used raw and second derivative images to detect anomalies (Echotherm and Mosaic). Simple contrast evolutions were plotted for the detected anomalies to help in anomaly characterization. Many out-of-family indications were noted. Some out-of-family indications were classified as cold spot indications and are due to additional adhesive or adhesive layer behind the facesheet. Some out-of-family indications were classified as hot spot indications and are due to void, unbond or lack of adhesive behind the facesheet. The IR inspection helped in assessing expected manufacturing quality of the radiators.

  7. Vibrational microspectroscopy of food. Raman vs. FT-IR

    DEFF Research Database (Denmark)

    Thygesen, Lisbeth Garbrecht; Løkke, Mette Marie; Micklander, Elisabeth


    . The high spatial resolution makes it possible to study areas down to approximately 10x10 mum with FT-IR microspectroscopy and approximately 1 x 1 mum with Raman microspectroscopy. This presentation highlights the advantages and disadvantages of the two microspectroscopic techniques when applied......) the composition of blisters found on the surface of bread, (4) the microstructure of high-lysine barley and (5) the composition of white spots in the shell of frozen shrimps. (C) 2003 Elsevier Science Ltd. All rights reserved....

  8. Hyperspectral IR cloudy radiance simulations : comparison between RTTOV and SARTA (United States)

    Vidot, J.; Desouza-Machado, S. G.; Hocking, J.; Matricardi, M.; Brunel, P.


    Infrared cloudy radiances assimilation is considered as one of the major goal in improving NWP. For such goal, a preliminary step is to include cloud scattering in fast RTM model. The RTTOV model uses the Chou scaling approximation for scattering in order to simulate infrared cloudy observations. This approximation is supposed to be able to simulate IR scattering with few tenth kelvin of error. We compared RTTOV and SARTA simulations to AIRS observations in both clear-sky and cloudy-sky. A database of 7377 atmospheric state test set, including the ECMWF specification of clouds have been used. The results of this intercomparison is presented here.

  9. Determination of Ethanol in Gasoline by FT-IR Spectroscopy (United States)

    Conklin, Alfred, Jr.; Goldcamp, Michael J.; Barrett, Jacob


    Ethanol is the primary oxygenate in gasoline in the United States. Gasoline containing various percentages of ethanol is readily available in the market place. A laboratory experiment has been developed in which the percentage of ethanol in hexanes can easily be determined using the O-H and alkane C-H absorptions in an infrared spectrum. Standard…

  10. Thermal and IR studies on copper doped polyvinyl alcohol

    Indian Academy of Sciences (India)


    as a function of copper concentration shows a strong branching and steric effects in copper doped PVA com- plexes. ... EPR spectroscopy appeared to be an espe- ... (FTIR) spectrum was recorded from 500–4000 cm. –1 by using a JASCO spectrometer. 3. Results and discussion. The DSC thermograms of PVA :x mol% Cu.

  11. Deafness and Autistic Spectrum Disorders (United States)

    Vernon, McCay; Rhodes, Anthony


    An orientation to autistic spectrum disorders (ASD), also known as autism, is provided, and the specific syndrome of autism and deafness is addressed. The two conditions have in common a major problem: communication. Case histories are provided, the development of treatment for autism is discussed, and the separate disorders that make up ASD are…

  12. Neurofeedback in Autism Spectrum Disorders (United States)

    Holtmann, Martin; Steiner, Sabina; Hohmann, Sarah; Poustka, Luise; Banaschewski, Tobias; Bolte, Sven


    Aim: To review current studies on the effectiveness of neurofeedback as a method of treatment of the core symptoms of autism spectrum disorders (ASD). Method: Studies were selected based on searches in PubMed, Ovid MEDLINE, EMBASE, ERIC, and CINAHL using combinations of the following keywords: "Neurofeedback" OR "EEG Biofeedback" OR "Neurotherapy"…

  13. Vision in autism spectrum disorders

    National Research Council Canada - National Science Library

    Simmons, David R; Robertson, Ashley E; McKay, Lawrie S; Toal, Erin; McAleer, Phil; Pollick, Frank E


    ... these two diagnostic groups have come to be known as Autism spectrum disorders (ASDs), although there is ongoing controversy about how distinct they really are (see Volkmar, State, & Klin, 2009 ). A second controversy concerns whether or not the prevalence of ASDs (about 1% in western countries) is increasing ( Charles, Carpenter, Jenner, &...

  14. Phenotypic spectrum of GABRA1

    DEFF Research Database (Denmark)

    Johannesen, Katrine; Marini, Carla; Pfeffer, Siona


    analysis of 4 selected mutations was performed using the Xenopus laevis oocyte expression system. RESULTS: The study included 16 novel probands and 3 additional family members with a disease-causing mutation in the GABRA1 gene. The phenotypic spectrum varied from unspecified epilepsy (1), juvenile...

  15. Autism Spectrum Disorders and Epigenetics (United States)

    Grafodatskaya, Daria; Chung, Brian; Szatmari, Peter; Weksberg, Rosanna


    Objective: Current research suggests that the causes of autism spectrum disorders (ASD) are multifactorial and include both genetic and environmental factors. Several lines of evidence suggest that epigenetics also plays an important role in ASD etiology and that it might, in fact, integrate genetic and environmental influences to dysregulate…

  16. IR-RF dating of sand-sized K-feldspar extracts: A test of accuracy

    DEFF Research Database (Denmark)

    Buylaert, Jan-Pieter; Jain, Mayank; Murray, A.S.


    performance and to test the reproducibility of IR-RF measurements. These experiments illustrate the high sensitivity and dose rate of our RL system, the negligible influence of the turntable movement on IR-RF signals and the effectiveness of the built in 395 nm LED at bleaching IR-RF signals. We measure IR......-RF ages on a set of samples with independent age control using a robust analytical method, which is able to detect any possible sensitivity change. Our IR-RF ages do not agree well with the independent age control; the ages of the younger samples (20–45 ka) are significantly over-estimated while the ages...

  17. “Contrapuntal Reading” as a Method, an Ethos, and a Metaphor for Global IR

    DEFF Research Database (Denmark)

    Bilgin, Pinar


    How to approach Global International Relations (IR)? This is a question asked by students of IR who recognize the limits of our field while expressing their concern that those who strive for a Global IR have been less-than-clear about the “how to?” question. In this article, I point to Edward W...... that focuses on our “intertwined and overlapping histories,” past and present; an ethos for approaching IR through raising the “contrapuntal awareness” of its students and offering an anchor for those who translate the findings of different perspectives; and a metaphor for thinking about Global IR as regional...

  18. Spectrum Trading in India and 5G

    DEFF Research Database (Denmark)

    Tripathi, Purnendu; Prasad, Ramjee


    Currently radio spectrum is largely managed through Command and Control method. Public mobile services require spectrum below 3 GHz for providing cost effective services. The existing method has created artificial shortage of spectrum especially below 3 GHz. Spectrum trading is a new concept...... in which service providers are permitted to purchase spectrum from the market to fulfil their requirements. Spectrum trading has not yet been permitted in India. This paper provides an overview of possibilities of spectrum trading in India and concludes that necessary ingredients are present in India...... for spectrum trading and it could provide a boost to the Indian telecom sector. Further, it will also discuss spectrum issue related with 5G in the direction of millimeter waves....

  19. Generalized eigenvalue based spectrum sensing

    KAUST Repository

    Shakir, Muhammad


    Spectrum sensing is one of the fundamental components in cognitive radio networks. In this chapter, a generalized spectrum sensing framework which is referred to as Generalized Mean Detector (GMD) has been introduced. In this context, we generalize the detectors based on the eigenvalues of the received signal covariance matrix and transform the eigenvalue based spectrum sensing detectors namely: (i) the Eigenvalue Ratio Detector (ERD) and two newly proposed detectors which are referred to as (ii) the GEometric Mean Detector (GEMD) and (iii) the ARithmetic Mean Detector (ARMD) into an unified framework of generalize spectrum sensing. The foundation of the proposed framework is based on the calculation of exact analytical moments of the random variables of the decision threshold of the respective detectors. The decision threshold has been calculated in a closed form which is based on the approximation of Cumulative Distribution Functions (CDFs) of the respective test statistics. In this context, we exchange the analytical moments of the two random variables of the respective test statistics with the moments of the Gaussian (or Gamma) distribution function. The performance of the eigenvalue based detectors is compared with the several traditional detectors including the energy detector (ED) to validate the importance of the eigenvalue based detectors and the performance of the GEMD and the ARMD particularly in realistic wireless cognitive radio network. Analytical and simulation results show that the newly proposed detectors yields considerable performance advantage in realistic spectrum sensing scenarios. Moreover, the presented results based on proposed approximation approaches are in perfect agreement with the empirical results. © 2012 Springer Science+Business Media Dordrecht.

  20. The role of insulin receptor substrate (IRS) proteins in oncogenic transformation. (United States)

    Gorgisen, G; Gulacar, I M; Ozes, O N


    Insulin Receptor Substrate (IRS) proteins are the main cytoplasmic adaptor molecules involved in transducing extracellular signals from receptors to downstream proteins. This protein family have pivotal roles on maintenance, distribution and regulation of signaling networks. Since IRS1/2 interact with and transmits signals from the receptors of insulin, Insulin Like Growth Factor 1 (IGF1), prolactin, growth hormone (GH), leptin, Vascular Endothelial Growth Factor (VEGF), TrkB, ALK and integrins this promoted scientist to think that IRS1 may have functions in cell proliferation, tumorigenesis and metastasis. Therefore, over the past decade, studies on IRS proteins and their functions in cancer has been increased and these studies provided valuable results claiming the involvement of IRS1/2 in cancer development. In this review, we discuss the function and contributions of IRS1 and IRS2 in development of  breast cancer.

  1. AFM-IR: Technology and Applications in Nanoscale Infrared Spectroscopy and Chemical Imaging. (United States)

    Dazzi, Alexandre; Prater, Craig B


    Atomic force microscopy-based infrared spectroscopy (AFM-IR) is a rapidly emerging technique that provides chemical analysis and compositional mapping with spatial resolution far below conventional optical diffraction limits. AFM-IR works by using the tip of an AFM probe to locally detect thermal expansion in a sample resulting from absorption of infrared radiation. AFM-IR thus can provide the spatial resolution of AFM in combination with the chemical analysis and compositional imaging capabilities of infrared spectroscopy. This article briefly reviews the development and underlying technology of AFM-IR, including recent advances, and then surveys a wide range of applications and investigations using AFM-IR. AFM-IR applications that will be discussed include those in polymers, life sciences, photonics, solar cells, semiconductors, pharmaceuticals, and cultural heritage. In the Supporting Information , the authors provide a theoretical section that reviews the physics underlying the AFM-IR measurement and detection mechanisms.

  2. Spectrum Monitoring Using SpectrumAnalysis LabVIEW Software, Nanoceptors, and Various Digitizing Solutions (United States)


    Spectrum Monitoring Using SpectrumAnalysis LabVIEW Software, Nanoceptors, and Various Digitizing Solutions by Joshua Smith ARL-TR-7217...1138 ARL-TR-7217 February 2015 Spectrum Monitoring Using SpectrumAnalysis LabVIEW Software, Nanoceptors, and Various Digitizing Solutions...REPORT TYPE Final 3. DATES COVERED (From - To) 06/2014–07/2014 4. TITLE AND SUBTITLE Spectrum Monitoring Using Spectrum Analysis LabVIEW

  3. Data in support of FSH induction of IRS-2 in human granulosa cells: Mapping the transcription factor binding sites in human IRS-2 promoter

    Directory of Open Access Journals (Sweden)

    Surleen Kaur


    Full Text Available Insulin receptor substrate-2 (IRS-2 plays critical role in the regulation of various metabolic processes by insulin and IGF-1. The defects in its expression and/or function are linked to diseases like polycystic ovary syndrome (PCOS, insulin resistance and cancer. To predict the transcription factors (TFs responsible for the regulation of human IRS-2 gene expression, the transcription factor binding sites (TFBS and the corresponding TFs were investigated by analysis of IRS-2 promoter sequence using MatInspector Genomatix software (Cartharius et al., 2005 [1]. The ibid data is part of author׳s publication (Anjali et al., 2015 [2] that explains Follicle stimulating hormone (FSH mediated IRS-2 promoter activation in human granulosa cells and its importance in the pathophysiology of PCOS. Further analysis was carried out for binary interactions of TF regulatory genes in IRS-2 network using Cytoscape software tool and R-code. In this manuscript, we describe the methodology used for the identification of TFBSs in human IRS-2 promoter region and provide details on experimental procedures, analysis method, validation of data and also the raw files. The purpose of this article is to provide the data on all TFBSs in the promoter region of human IRS-2 gene as it has the potential for prediction of the regulation of IRS-2 gene in normal or diseased cells from patients with metabolic disorders and cancer.

  4. Decontamination and decommissioning of laboratory solutions enriched uranium (IR-01 b); Descontaminacion y desmantelamiento del laboratorio de soluciones de uranio enriquecido (IR-01b)

    Energy Technology Data Exchange (ETDEWEB)

    Diaz Arocas, P. P.; Sama Colao, J.; Garcia Diaz, A.; Torre Rodriguez, J.; Martinez, A.; Argiles, E.; Garrido Delgado, C.


    Completed actions decontamination and decommissioning of the Laboratory of Enriched Uranium Solutions, attached to the Radioactivity lR-0l CIEMAT, was carried out final radiological control of the laboratory. From the documentation generated proceeded to request modification of the IR-01 installation by closing its laboratory IR-01 b.

  5. Limewashed mural paintings as seen by VIS-IR reflectography (United States)

    Fontana, R.; Striova, J.; Barucci, M.; Pampaloni, E.; Raffaelli, M.; Pezzati, L.; Mariotti, P.


    Near-Infrared (NIR) reflectography is a well-established technique for painting diagnostics, offering a fundamental contribution to the conservation of paintings. Since the '80s it has been routinely applied to study the execution technique of the author, as well as the presence of pentimenti, retouches, integrations or underdrawing. In the last decades IR reflectography has been extended to the visible (VIS) spectral range, providing information about the pigment composition. Up to now the multispectral analysis is still applied at an experimental level, as the processing of the image set is not straightforward. Rarely multispectral VIS-IR application has been applied to frescos, probably due to the lack, in most cases, of a scattering background. In this work we present the results provided by a multispectral scanning device based on single sensor acquisition, working in the 380-2500 nm spectral range, that is a laboratory prototype specifically built for research-grade imaging. The technique have been applied on a mock up simulating a mural painting substrate where an underdrawing, made of either carbon or iron-gall ink, was covered by different surface layers of limewash, the so-called scialbo.

  6. Numerical method for IR background and clutter simulation (United States)

    Quaranta, Carlo; Daniele, Gina; Balzarotti, Giorgio


    The paper describes a fast and accurate algorithm of IR background noise and clutter generation for application in scene simulations. The process is based on the hypothesis that background might be modeled as a statistical process where amplitude of signal obeys to the Gaussian distribution rule and zones of the same scene meet a correlation function with exponential form. The algorithm allows to provide an accurate mathematical approximation of the model and also an excellent fidelity with reality, that appears from a comparison with images from IR sensors. The proposed method shows advantages with respect to methods based on the filtering of white noise in time or frequency domain as it requires a limited number of computation and, furthermore, it is more accurate than the quasi random processes. The background generation starts from a reticule of few points and by means of growing rules the process is extended to the whole scene of required dimension and resolution. The statistical property of the model are properly maintained in the simulation process. The paper gives specific attention to the mathematical aspects of the algorithm and provides a number of simulations and comparisons with real scenes.

  7. Lens barrel design of the NIRST IR Camera (United States)

    Côté, Patrice; Leclerc, Mélanie; Châteauneuf, François; Marraco, Hugo


    The use of uncooled microbolometer detectors for space infrared (IR) imaging application requires high optical throughput, which leads to very fast optical design (~f/1). This directly translates into stringent requirements for components, assembly and alignment. The Institut National d'Optique (INO) in Quebec City, Canada, designed such a system for the NIRST IR Camera. The instrument is part of the Aquarius/SAC-D satellite, a cooperative mission conducted jointly by NASA and the Comisión Nacional de Actividades Espaciales (CONAE) of Argentina. Due to the tight volume and mass allocation, the NIRST camera module is an all refractive design. Since the Camera is made of two lens barrels co-registered to cover the same ground area at different wavelength bands, it also adds coregistration alignment constraints. This paper presents the optomechanical solutions and alignment scheme that enabled the successful design and flight qualification. Trade-off study between thermally induced stress and structural stiffness of the lens RTV bond is discussed. Special attention is given to lens subcell alignment integrity under random vibration encountered during launch. Detailed Finite Element Analysis (FEA) is used to check early design assumptions. Test results of the final vibration campaign are also presented.

  8. Multiplexing of spatial modes in the mid-IR region (United States)

    Gailele, Lucas; Maweza, Loyiso; Dudley, Angela; Ndagano, Bienvenu; Rosales-Guzman, Carmelo; Forbes, Andrew


    Traditional optical communication systems optimize multiplexing in polarization and wavelength both trans- mitted in fiber and free-space to attain high bandwidth data communication. Yet despite these technologies, we are expected to reach a bandwidth ceiling in the near future. Communications using orbital angular momentum (OAM) carrying modes offers infinite dimensional states, providing means to increase link capacity by multiplexing spatially overlapping modes in both the azimuthal and radial degrees of freedom. OAM modes are multiplexed and de-multiplexed by the use of spatial light modulators (SLM). Implementation of complex amplitude modulation is employed on laser beams phase and amplitude to generate Laguerre-Gaussian (LG) modes. Modal decomposition is employed to detect these modes due to their orthogonality as they propagate in space. We demonstrate data transfer by sending images as a proof-of concept in a lab-based scheme. We demonstrate the creation and detection of OAM modes in the mid-IR region as a precursor to a mid-IR free-space communication link.

  9. Crosstalk between adiponectin and IGF-IR in breast cancer

    Directory of Open Access Journals (Sweden)

    Loredana eMauro


    Full Text Available Obesity is a chronic and multifactorial disorder that is reaching epidemic proportions. It is characterized by an enlarged mass of adipose tissue caused by a combination of size increase of preexisting adipocytes (hypertrophy and de novo adipocyte differentiation (hyperplasia. Obesity is related to many metabolic disorders like hypertension, type 2 diabetes, metabolic syndrome, cardiovascular disease, and it is associated with an increased risk of cancer development in different tissues including breast. Adipose tissue is now regarded as not just a storage reservoir for excess energy, but rather as an endocrine organ, secreting a large number of bioactive molecules called adipokines. Among these, adiponectin represents the most abundant adipose tissue-excreted protein, which exhibits insulin-sensitizing, anti-inflammatory and antiatherogenic properties. The serum concentrations of adiponectin are inversely correlated with body mass index. Recently, low levels of plasma adiponectin have been associated with an increased risk for obesity-related cancers and development of more aggressive phenotype, concomitantly with alterations in the bioavailability of Insulin-like Growth Factor-I (IGF-I and IGF-I Receptor (IGF-IR signaling pathways. In this review we discuss the cross-talk between adiponectin/AdipoR1 and IGF-I/IGF-IR in breast cancer.

  10. Uncooled IR imager with 5-mK NEDT (United States)

    Amantea, Robert; Knoedler, C. M.; Pantuso, Francis P.; Patel, Vipulkumar; Sauer, Donald J.; Tower, John R.


    The bi-material concept for room-temperature infrared imaging has the potential of reaching an NE(Delta) T approaching the theoretical limit because of its high responsivity and low noise. The approach, which is 100% compatible with silicon IC foundry processing, utilizes a novel combination of surface micromachining and conventional integrated circuits to produce a bimaterial thermally sensitive element that controls the position of a capacitive plate coupled to the input of a low noise MOS amplifier. This approach can achieve the high sensitivity, the low weight, and the low cost necessary for equipment such as helmet mounted IR viewers and IR rifle sights. The pixel design has the following benefits: (1) an order of magnitude improvement in NE(Delta) T due to extremely high sensitivity and low noise, (2) low cost due to 100% silicon IC compatibility, (3) high image quality and increased yield due to ability to do offset and sensitivity corrections on the imager, pixel-by-pixel; (4) no cryogenic cooler and no high vacuum processing; and (5) commercial applications such as law enforcement, home security, and transportation safety. Two designs are presented. One is a 50 micrometer pixel using silicon nitride as the thermal isolation element that can achieve 5 mK NE(Delta) T; the other is a 29 micrometer pixel using silicon carbide that provides much higher thermal isolation and can achieve 10 mK NE(Delta) T.

  11. Monitoring combat wound healing by IR hyperspectral imaging (United States)

    Howle, Chris R.; Spear, Abigail M.; Gazi, Ehsan; Crane, Nicole J.


    In recent conflicts, battlefield injuries consist largely of extensive soft injuries from blasts and high energy projectiles, including gunshot wounds. Repair of these large, traumatic wounds requires aggressive surgical treatment, including multiple surgical debridements to remove devitalised tissue and to reduce bacterial load. Identifying those patients with wound complications, such as infection and impaired healing, could greatly assist health care teams in providing the most appropriate and personalised care for combat casualties. Candidate technologies to enable this benefit include the fusion of imaging and optical spectroscopy to enable rapid identification of key markers. Hence, a novel system based on IR negative contrast imaging (NCI) is presented that employs an optical parametric oscillator (OPO) source comprising a periodically-poled LiNbO3 (PPLN) crystal. The crystal operates in the shortwave and midwave IR spectral regions (ca. 1.5 - 1.9 μm and 2.4 - 3.8 μm, respectively). Wavelength tuning is achieved by translating the crystal within the pump beam. System size and complexity are minimised by the use of single element detectors and the intracavity OPO design. Images are composed by raster scanning the monochromatic beam over the scene of interest; the reflection and/or absorption of the incident radiation by target materials and their surrounding environment provide a method for spatial location. Initial results using the NCI system to characterise wound biopsies are presented here.

  12. IR pyrometry in diamond anvil cell above 400 K. (United States)

    Shuker, P; Melchior, A; Assor, Y; Belker, D; Sterer, E


    Temperature measurements in a laser heated diamond anvil cell (DAC) are currently limited to temperatures above 1000 K using optics and detectors in the visible range. We have built a pyrometer in the IR range and expanded the lower limit of temperature detection to 400 K. The pyrometer is designed for very low thermal radiation intensities, measured sequentially through a set of bandpass filters in the range of 1.2-3.4 microm using very efficient IR photodetectors. The thermal radiation from the center of the cw Nd:YAG laser heated spot is least square fitted to a Planck curve, using a gray body approximation. Melting is detected by changes in the light scattering picture of an auxiliary He-Ne laser from the surface of the hot spot, and by a change in slope in the plot of hot spot temperature versus laser power. In this work we demonstrate measurement of the melting curve of zinc up to 25 GPa. The melting curve is in very good agreement with previous results which were taken up to 6 GPa in a large volume press.

  13. The Dependence of the IR-Radio Correlation on the Metallicity (United States)

    Qiu, Jianjie; Shi, Yong; Wang, Junzhi; Zhang, Zhi-Yu; Zhou, Luwenjia


    We have compiled a sample of 26 metal-poor galaxies with 12 + log(O/H) infrared continuum and 1.4 GHz radio continuum data. By comparing to galaxies at higher metallicity, we have investigated the IR-radio relationship’s dependence on metallicity at the 24, 70, 100, and 160 μm bands, as well as the integrated FIR luminosity. It is found that metal-poor galaxies have on average lower {q}{IR} than metal-rich ones, with larger offsets at longer IR wavelengths, from -0.06 dex in {q}24μ {{m}} to -0.6 dex in {q}160μ {{m}}. The {q}{IR} of all galaxies as a whole at 160 μm show positive trends with the metallicity and IR-to-FUV ratio and negative trends with the IR color, while those at lower IR wavelengths show weaker correlations. We propose a mechanism that invokes the combined effects of low obscured-SFR-to-total-SFR fraction and warm dust temperature at low metallicity to interpret the above behavior of {q}{IR}, with the former reducing the IR radiation and the latter further reducing the IR emission at longer IR wavelengths. Other mechanisms that are related to the radio emission, including the enhanced magnetic field strength and increased thermal radio contribution, are unable to reconcile the IR-wavelength-dependent differences of {q}{IR} between metal-poor and metal-rich galaxies. In contrast to {q}{IR}, the mean total-SFR-to-radio ratio of metal-poor galaxies is the same as that for metal-rich galaxies, indicating the 1.4 GHz radio emission is still an effective tracer of SFRs at low metallicity.

  14. Bright-rimmed molecular cloud around S140 IRS. II. Bipolar outflow from S140 IRS 1

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, M.; Hasegawa, T.; Omodaka, T.; Hayashi, S.S.; Miyawaki, R.


    Radioastronomy maps are presented from 16 arcsec resolution scans of the C-12O J = 1 yields 0 emission from S140 IRS, an H II region that is also associated with star formation. The observed C-12O outflow exhibits clear bipolarity. Integral values are calculated for the total mass, momentum and energy of the outflow, which has a velocity asymmetry that features the lowest velocity in the region of greatest mass outflow. Possible explanations for the velocity/mass outflow asymmetry are considered. 37 references.

  15. A Cognitive Agent for Spectrum Monitoring and Informed Spectrum Access (United States)


    monitoring and access. A cognitive software agent was written in MATLAB to demonstrate some basic capabilities of a cognitive architecture , namely...cognitive software agent was written in MATLAB to demonstrate some basic capabilities of a cognitive architecture , namely, sensing, analysis, learning...behavior with respect to spectrum access. 2. Introduction Many types of cognitive architectures have been investigated to model various aspects of human

  16. Spectrum Efficiency Through Dynamic Spectrum Access Techniques (Briefing Charts) (United States)


    6218 U.S. ARMY PEO STRI Acquisition Center 1 0 0 Email to: Attn: Kaitlin F. Lockett 12350 Research Parkway...Spectrum Access T&E/S&T Program FY2014 End-of-Year Program Execution Review FY14 Accomplishments  Engineering change...Integration Lab (SIL) Key Future Events • Delivery of the final NRES Engineering Design Document • Functional/Stress testing of NRES. COTS V6

  17. Modelling the TSZ power spectrum

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Suman [Los Alamos National Laboratory; Shaw, Laurie D [YALE; Nagai, Daisuke [YALE


    The structure formation in university is a hierarchical process. As universe evolves, tiny density fluctuations that existed in the early universe grows under gravitational instability to form massive large scale structures. The galaxy clusters are the massive viralized objects that forms by accreting smaller clumps of mass until they collapse under their self-gravity. As such galaxy clusters are the youngest objects in the universe which makes their abundance as a function of mass and redshift, very sensitive to dark energy. Galaxy clusters can be detected by measuring the richness in optical waveband, by measuring the X-ray flux, and in the microwave sky using Sunyaev-Zel'dovich (SZ) effect. The Sunyaev-Zel'dovich (SZ) effect has long been recognized as a powerful tool for detecting clusters and probing the physics of the intra-cluster medium. Ongoing and future experiments like Atacama Cosmology Telescope, the South Pole Telescope and Planck survey are currently surveying the microwave sky to develop large catalogs of galaxy clusters that are uniformly selected by the SZ flux. However one major systematic uncertainties that cluster abundance is prone to is the connection between the cluster mass and the SZ flux. As shown by several simulation studies, the scatter and bias in the SZ flux-mass relation can be a potential source of systematic error to using clusters as a cosmology probe. In this study they take a semi-analytic approach for modeling the intra-cluster medium in order to predict the tSZ power spectrum. The advantage of this approach is, being analytic, one can vary the parameters describing gas physics and cosmology simultaneously. The model can be calibrated against X-ray observations of massive, low-z clusters, and using the SZ power spectrum which is sourced by high-z lower mass galaxy groups. This approach allows us to include the uncertainty in gas physics, as dictated by the current observational uncertainties, while measuring the

  18. Dynamics in a Water Interfacial Boundary Layer Investigated with IR Polarization-Selective Pump-Probe Experiments. (United States)

    Yuan, Rongfeng; Yan, Chang; Nishida, Jun; Fayer, Michael D


    The dynamics of water molecules near the surfactant interface in large Aerosol-OT reverse micelles (RMs) (w 0 = 16-25) was investigated with IR polarization-selective pump-probe experiments using the SeCN - anion as a vibrational probe. Linear absorption spectra of RMs (w 0 = 25-2) can be decomposed into the weighted sum of the SeCN - spectra in bulk water and the spectrum of the SeCN - anion interacting with the interfacial sulfonate head groups (w 0 = 1). The spectra of the large RMs, w 0 ≥ 16, are overwhelmingly dominated by the bulk water component. Anisotropy decays (orientational relaxation) of the anion for w 0 ≥ 16 displayed bulk water relaxation (1.4 and 4.5 ps) plus an additional slow decay with a time constant of ∼13 ps. The amplitude of the slow decay was too large to be associated with SeCN - in contact with the interface on the basis of the linear spectrum decomposition. The results indicate that the observed slow components arise from SeCN - in a water boundary layer, in which water molecules are perturbed by the interface but are not directly associated with it. This layer is the transition between water in direct contact with the interface and bulk water in the large RM cores. In the boundary layer, the water dynamics is slow compared to that in bulk water.

  19. IR spectroscopic characteristics of cell cycle and cell death probed by synchrotron radiation based Fourier transform IR spectromicroscopy (United States)

    Holman, H. Y.; Martin, M. C.; Blakely, E. A.; Bjornstad, K.; McKinney, W. R.


    Synchrotron radiation based Fourier transform IR (SR-FTIR) spectromicroscopy allows the study of individual living cells with a high signal to noise ratio. Here we report the use of the SR-FTIR technique to investigate changes in IR spectral features from individual human lung fibroblast (IMR-90) cells in vitro at different points in their cell cycle. Clear changes are observed in the spectral regions corresponding to proteins, DNA, and RNA as a cell changes from the G(1)-phase to the S-phase and finally into mitosis. These spectral changes include markers for the changing secondary structure of proteins in the cell, as well as variations in DNA/RNA content and packing as the cell cycle progresses. We also observe spectral features that indicate that occasional cells are undergoing various steps in the process of cell death. The dying or dead cell has a shift in the protein amide I and II bands corresponding to changing protein morphologies, and a significant increase in the intensity of an ester carbonyl C===O peak at 1743 cm(-1) is observed. Copyright John Wiley & Sons, Inc. Biopolymers (Biospectroscopy) 57: 329-335, 2000.

  20. Radiative Transfer Modeling of the Mid-IR/Far-IR Dust Emissions of the Symbiotic Mira, V* R Aqr (United States)

    Omelian, Eric B.; Sankrit, Ravi; Helton, L. Andrew; Gorti, Uma; Wagner, R. Mark


    We present RADMC-3D models of the symbiotic system V* R Aqr, which consists of a Mira variable and white dwarf. Thermal radiative transfer modeling is performed using RADMC-3D to characterize the mid-IR/far-IR Spectral Energy Distributions (SEDs) of the system at two different phases of the visible light curve. Near maximum visible light (Mira phase of 1.0), we utilize the Infrared Space Observatory (ISO) Short Wave Spectrometer/Long Wave Spectrometer observations (2.3 - 197 mu-m) and contrast them to the recently obtained near minimum visible light (~0.4 Mira phase) observations from the Stratospheric Observatory for Infrared Astronomy (SOFIA)/Faint Object infraRed CAmera for the SOFIA Telescope (FORCAST) (6.4 - 37.1 mu-m). Initial spectra and photometry from the SOFIA/FORCAST observations of the central Mira indicate that flux values are about 50% of that measured by the ISO SWS/LWS observations. Dust models utilizing a spherical shell and amorphous silicates are used to generate synthetic SEDs, which are compared with the ISO and FORCAST observations in order to constrain the properties of the shell (such as its dust mass and temperature) at different phases of the Mira variability. Our proposed monitoring of the V* R Aqr system will establish a characterization baseline of the SEDs as the system approaches its upcoming eclipse and periastron passage.