Dissolution flowsheet for high flux isotope reactor fuel

Energy Technology Data Exchange (ETDEWEB)

Foster, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-09-27

As part of the Spent Nuclear Fuel (SNF) processing campaign, H-Canyon is planning to begin dissolving High Flux Isotope Reactor (HFIR) fuel in late FY17 or early FY18. Each HFIR fuel core contains inner and outer fuel elements which were fabricated from uranium oxide (U₃O₈) dispersed in a continuous Al phase using traditional powder metallurgy techniques. Fuels fabricated in this manner, like other SNF’s processed in H-Canyon, dissolve by the same general mechanisms with similar gas generation rates and the production of H₂. The HFIR fuel cores will be dissolved and the recovered U will be down-blended into low-enriched U. HFIR fuel was previously processed in H-Canyon using a unique insert in both the 6.1D and 6.4D dissolvers. Multiple cores will be charged to the same dissolver solution maximizing the concentration of dissolved Al. The objective of this study was to identify flowsheet conditions through literature review and laboratory experimentation to safely and efficiently dissolve the HFIR fuel in H-Canyon. Laboratory-scale experiments were performed to evaluate the dissolution of HFIR fuel using both Al 1100 and Al 6061 T6 alloy coupons. The Al 1100 alloy was considered a representative surrogate which provided an upper bound on the generation of flammable (i.e., H₂) gas during the dissolution process. The dissolution of the Al 6061 T6 alloy proceeded at a slower rate than the Al 1100 alloy and was used to verify that the target Al concentration in solution could be achieved for the selected Hg concentration. Mass spectrometry and Raman spectroscopy were used to provide continuous monitoring of the concentration of H₂ and other permanent gases in the dissolution offgas allowing the development of H₂ generation rate profiles. The H₂ generation rates were subsequently used to evaluate if a full HFIR core could be dissolved in an H-Canyon dissolver without exceeding 60% of the

Reclamation of cadmium-contaminated soil using dissolved organic matter solution originating from wine-processing waste sludge

International Nuclear Information System (INIS)

Liu, Cheng-Chung; Chen, Guan-Bu

2013-01-01

Highlights: ► Increases in acidity, washing frequency, and operational temperature enhance the Cd removal. ► Approximately 80% of Cd can be removed from the soil by dissolved organic matter (DOM) washing. ► The DOM washing can moderate the loss of soil fertility. ► The DOM washing will have a great improvement if we employ NaOH, KOH, Ca(OH) 2 , and Mg(OH) 2 to prepare the DOM solution together. -- Abstract: Soil washing using an acid solution is a common practice for removing heavy metals from contaminated soil in Taiwan. However, serious loss of nutrients from soil is a major drawback of the washing. Distillery sludge can be used to prepare a dissolved organic matter (DOM) solution by extracting its organic constituents with alkaline solutions. This study employed DOM solutions to remediate Cd-contaminated soil (with concentrations up to 21.5 mg kg −1 ) and determine the factors affecting removal of Cd, such as pH, initial concentration of DOM solution, temperature, and washing frequency. When washing with pH 3.0 and 1250 mg L −1 DOM solution, about 80% and 81% of Cd were removed from the topsoil at 27 °C and subsoil at 40 °C, respectively. To summarize the changes in fertility during DOM washing with various pH solutions: the increase in organic matter content ranged from 7.7% to 23.7%; cation exchange capacity (CEC) ranged from 4.6% to 13.9%; available ammonium (N-NH 4 ) content ranged from 39.4% to 2175%; and available phosphorus content ranged from 34.5% to 182%. Exchangeable K, Ca, and Mg remained in the topsoil after DOM washing, with concentrations of 1.1, 2.4, and 1.5 times higher than those treated with HCl solution at the same pH, respectively

Reclamation of cadmium-contaminated soil using dissolved organic matter solution originating from wine-processing waste sludge

Energy Technology Data Exchange (ETDEWEB)

Liu, Cheng-Chung, E-mail: ccliu@niu.edu.tw [Department of Environmental Engineering, National Ilan University, Ilan, 260, Taiwan (China); Chen, Guan-Bu [Department of Environmental Engineering, National Ilan University, Ilan, 260, Taiwan (China)

2013-01-15

Highlights: ► Increases in acidity, washing frequency, and operational temperature enhance the Cd removal. ► Approximately 80% of Cd can be removed from the soil by dissolved organic matter (DOM) washing. ► The DOM washing can moderate the loss of soil fertility. ► The DOM washing will have a great improvement if we employ NaOH, KOH, Ca(OH){sub 2}, and Mg(OH){sub 2} to prepare the DOM solution together. -- Abstract: Soil washing using an acid solution is a common practice for removing heavy metals from contaminated soil in Taiwan. However, serious loss of nutrients from soil is a major drawback of the washing. Distillery sludge can be used to prepare a dissolved organic matter (DOM) solution by extracting its organic constituents with alkaline solutions. This study employed DOM solutions to remediate Cd-contaminated soil (with concentrations up to 21.5 mg kg{sup −1}) and determine the factors affecting removal of Cd, such as pH, initial concentration of DOM solution, temperature, and washing frequency. When washing with pH 3.0 and 1250 mg L{sup −1} DOM solution, about 80% and 81% of Cd were removed from the topsoil at 27 °C and subsoil at 40 °C, respectively. To summarize the changes in fertility during DOM washing with various pH solutions: the increase in organic matter content ranged from 7.7% to 23.7%; cation exchange capacity (CEC) ranged from 4.6% to 13.9%; available ammonium (N-NH{sub 4}) content ranged from 39.4% to 2175%; and available phosphorus content ranged from 34.5% to 182%. Exchangeable K, Ca, and Mg remained in the topsoil after DOM washing, with concentrations of 1.1, 2.4, and 1.5 times higher than those treated with HCl solution at the same pH, respectively.

Partly standing internal tides in a dendritic submarine canyon observed by an ocean glider

Science.gov (United States)

Hall, Rob A.; Aslam, Tahmeena; Huvenne, Veerle A. I.

2017-08-01

An autonomous ocean glider is used to make the first direct measurements of internal tides within Whittard Canyon, a large, dendritic submarine canyon system that incises the Celtic Sea continental slope and a site of high benthic biodiversity. This is the first time a glider has been used for targeted observations of internal tides in a submarine canyon. Vertical isopycnal displacement observations at different stations fit a one-dimensional model of partly standing semidiurnal internal tides - comprised of a major, incident wave propagating up the canyon limbs and a minor wave reflected back down-canyon by steep, supercritical bathymetry near the canyon heads. The up-canyon internal tide energy flux in the primary study limb decreases from 9.2 to 2.0 kW m-1 over 28 km (a dissipation rate of 1 - 2.5 ×10-7 Wkg-1), comparable to elevated energy fluxes and internal tide driven mixing measured in other canyon systems. Within Whittard Canyon, enhanced mixing is inferred from collapsed temperature-salinity curves and weakened dissolved oxygen concentration gradients near the canyon heads. It has previously been hypothesised that internal tides impact benthic fauna through elevated near-bottom current velocities and particle resuspension. In support of this, we infer order 20 cm s-1 near-bottom current velocities in the canyon and observe high concentrations of suspended particulate matter. The glider observations are also used to estimate a 1 °C temperature range and 12 μmol kg-1 dissolved oxygen concentration range, experienced twice a day by organisms on the canyon walls, due to the presence of internal tides. This study highlights how a well-designed glider mission, incorporating a series of tide-resolving stations at key locations, can be used to understand internal tide dynamics in a region of complex topography, a sampling strategy that is applicable to continental shelves and slopes worldwide.

Decontamination of Savannah River Plant H-Area hot-canyon crane

International Nuclear Information System (INIS)

Rankin, W.N.; Sims, J.R.

1985-01-01

Decontamination techniques applicable to the remotely operated bridge cranes in canyon buildings at the Savannah River Plant (SRP) were identified and were evaluated in laboratory-scale tests. High pressure Freon blasting was found to be the most attractive process available for this application. Strippable coatings were selected as an alternative technique in selected applications. The ability of high pressure Freon blasting plus two strippable coatings (Quadcoat 100 and Alara 1146) to remove the type of contamination expected on SRP cranes was demonstrated in laboratory-scale tests. Quadrex HPS was given a contract to decontaminate the H-Area hot canyon crane. Decontamination operations were successfully carried out within the specified time-frame window. The radiation level goals specified by SRP were met and decontamination was accomplished with 85% less personnel exposure than estimated by SRP before the job started. This reduction is attributed to the increased efficiency of the new decontamination techniques used. 6 refs., 1 tab

Feasibility of Uranium Concentration Measurements for H Canyon Tank 16.7

International Nuclear Information System (INIS)

Lascola, R.J.

2003-01-01

Savannah River Technology Center (SRTC) evaluated the feasibility of using the H Canyon on-line diode array spectrophotometer to measure uranium concentrations in Tank 16.7. On-line measurements will allow an increase in highly enriched uranium (HEU) production by removing delays associated with off-line measurements. The instrument must be able to measure uranium at concentrations below 1.0 g/L with an uncertainty no greater than 0.3 g/L. SRTC determined that the system has a limit of quantitation of 0.15 g/L. At concentrations of 0.5 and 1.0 g/L, the spectrometer uncertainty is 0.10 g/L. No design changes, such as an increase in flow cell path length, are required to obtain this performance. Expected levels of iron in Tank 16.7 solutions will not interfere with the measurement. The CHEMCHEK method should not be used for confirmatory analysis, as it contributes excessively to the overall uncertainty of the measurement. SRTC expects that the spectrophotometer will meet the measurement requirements for Tank 16.7

A novel bioactive haemodialysis system using dissolved dihydrogen (H2) produced by water electrolysis: a clinical trial.

Science.gov (United States)

Nakayama, Masaaki; Nakano, Hirofumi; Hamada, Hiromi; Itami, Noritomo; Nakazawa, Ryoichi; Ito, Sadayoshi

2010-09-01

Chronic inflammation in haemodialysis (HD) patients indicates a poor prognosis. However, therapeutic approaches are limited. Hydrogen gas (H(2)) ameliorates oxidative and inflammatory injuries to organs in animal models. We developed an HD system using a dialysis solution with high levels of dissolved H(2) and examined the clinical effects. Dialysis solution with H(2) (average of 48 ppb) was produced by mixing dialysate concentrates and reverse osmosis water containing dissolved H(2) generated by a water electrolysis technique. Subjects comprised 21 stable patients on standard HD who were switched to the test HD for 6 months at three sessions a week. During the study period, no adverse clinical signs or symptoms were observed. A significant decrease in systolic blood pressure (SBP) before and after dialysis was observed during the study, and a significant number of patients achieved SBP <140 mmHg after HD (baseline, 21%; 6 months, 62%; P < 0.05). Changes in dialysis parameters were minimal, while significant decreases in levels of plasma monocyte chemoattractant protein 1 (P < 0.01) and myeloperoxidase (P < 0.05) were identified. Adding H(2) to haemodialysis solutions ameliorated inflammatory reactions and improved BP control. This system could offer a novel therapeutic option for control of uraemia.

Method of dissolving metal ruthenium

International Nuclear Information System (INIS)

Tsuno, Masao; Soda, Yasuhiko; Kuroda, Sadaomi; Koga, Tadaaki.

1988-01-01

Purpose: To dissolve and clean metal ruthenium deposited to the inner surface of a dissolving vessel for spent fuel rods. Method: Metal ruthenium is dissolved in a solution of an alkali metal hydroxide to which potassium permanganate is added. As the alkali metal hydroxide used herein there can be mentioned potassium hydroxide, sodium hydroxide and lithium hydroxide can be mentioned, which is used as an aqueous solution from 5 to 20 % concentration in view of the solubility of metal ruthenium and economical merit. Further, potassium permanganate is used by adding to the solution of alkali metal hydroxide at a concentration of 1 to 5 %. (Yoshihara, H.)

Dissolution of powdered spent fuel and U crystallization from actual dissolver solution for 'NEXT' process development

International Nuclear Information System (INIS)

Nomura, Kazunori; Hinai, Hiroshi; Nakahara, Masaumi; Kaji, Naoya; Kamiya, Masayoshi; Ohyama, Koichi; Sano, Yuichi; Washiya, Tadahiro; Komaki, Jun

2008-01-01

The beaker-scale experiments on the effective powdered fuel dissolution and the U crystallization from dissolver solution with the irradiated MOX fuel from the experimental fast reactor 'JOYO' were carried out. The powdered fuel was effectively dissolved into the nitric acid solution. In the U crystallization experiments, U crystal was obtained from the actual dissolver solution without any addition of reagent. (authors)

Pollutant Dilution and Diffusion in Urban Street Canyon Neighboring Streets

Science.gov (United States)

Sun, Z.; Fu, Zh. M.

2011-09-01

In the present study we investigated the airflow patterns and air quality of a series of typical street canyon combinations, developed a mass balance model to determine the local pollutant dilution rate, and discuss the impact of upstream canyon on the air quality of downstream canyon. The results indicated that the geometrical size of upstream and downstream buildings have significant impacts on the ambient airflow patterns. The pollution distribution within the canyons varies with different building combinations and flow patterns. Within the upstream canyon, pollution always accumulates to the low building side for non-symmetrical canyon, and for symmetrical canyon high level of pollution occurs at the leeward side. The height of the middle and downstream buildings can evidently change the pollutant dispersion direction during the transport process. Within the polluted canyon, the pollutant dilution rate (PDR) also varies with different street canyon combinations. The highest PDR is observed when the upstream buildings are both low buildings no matter the height of downstream building. However, the two cases are likely to contribution pollution to the downstream canyon. The H-L-H combination is mostly against local pollution remove, while the L-H-L case is considered the best optimistic building combination with both the ability of diluting local pollution and not remarkably decreasing air quality of downstream canyon. The current work is expected instructive for city designers to optimize traffic patterns under typical existing geometry or in the development of urban geometry modification for air quality control.

Strategic guidelines for street canyon geometry to achieve sustainable street air quality

Energy Technology Data Exchange (ETDEWEB)

Chan, Andy T.; So, Ellen S.P.; Samad, Subash C. [Hong Kong Univ., Dept. of Mechanical Engineering, Hong Kong (China)

2001-08-01

This paper is concerned with the motion of air within the urban street canyon and is directed towards a deeper understanding of pollutant dispersion with respect to various simple canyon geometries and source positions. Taking into account the present days typical urban configurations, three principal flow regimes 'isolated roughness flow', 'skimming flow' and 'wake interference flow' (Boundary Layer Climates, 2nd edition, Methuen, London) and their corresponding pollutant dispersion characteristics are studied for various canopies aspect ratios, namely relative height (h{sub 2}/H{sub 1}), canyon height to width ratio (h/w) and canyon length to height ratio (l/h). A field-size canyon has been analysed through numerical simulations using the standard k-{sup {epsilon}} turbulence closure model. It is found that the pollutant transport and diffusion is strongly dependent upon the type of flow regime inside the canyon and exchange between canyon and the above roof air. Some rules of thumbs have been established to get urban canyon geometries for efficient dispersion of pollutants. (Author)

Impact of solute concentration on the electrocatalytic conversion of dissolved gases in buffered solutions

KAUST Repository

Shinagawa, Tatsuya; Takanabe, Kazuhiro

2015-01-01

. These alterations of the electrolyte properties associated with the solute concentration are universally applicable to other aqueous gas-related electrochemical reactions because the currents are purely determined by mass transfer of the dissolved gases. © 2015

76 FR 8359 - Boulder Canyon Project

Science.gov (United States)

2011-02-14

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area... Western Area Power Administration (Western) is proposing an adjustment to the Boulder Canyon Project (BCP... Reclamation Project Act of 1939 (43 U.S.C. 485h(c)), and other acts that specifically apply to the project...

Mega-solubility of quartz resulting from highly alkaline fluids produced by dissolved albite in H2O at deep crustal conditions

Science.gov (United States)

Makhluf, A. R.; Manning, C. E.

2017-12-01

Models of H2O-rich fluids equilibrated with rocks at high P and T fail to predict the high solubilities observed experimentally, chiefly because thermodynamic data for the most abundant solutes is lacking. We investigated the effects of dissolved albite (Ab) on the solubility of quartz (Qz) at 1.0 GPa and 675-900 °C using a piston-cylinder apparatus to quantify possible mineral buffering or enhancement effects. We found a very large enhancement effect on the solubility of Qz when dissolved in dilute aqueous Ab solutions. SiO2 concentrations are similar to Qz solubility in strongly alkaline KOH solutions. At the highest temperature of 900 °C, we found that the solubility of Qz in 1.0 molal Ab solution increases by of factor of 4.5 over that in pure H2O, which corresponds to 10.7 molal SiO2. The nearly identical solubility of Qz in KOH(aq) and Ab solutions of the same concentration, P, and T, strongly suggest that NaOH(aq) liberated from NaAlSi3O8 in H2O fluids effects SiO2 solubility in a similar manner to that of KOH(aq). The deprotonated silica dimer was found to be a key species responsible for the high solubility of Qz in KOH(aq) and is likely responsible for the high solubility of Qz in Ab solutions. While the binaries Qz-H2O, Ab-H2O, and Qz-Ab are well known at 1.0 GPa, little data exists on the ternary system. The new results help quantify the ternary relations in the Ab-Qz-H2O system, which can be used as a simple model for liquid-vapor immiscibility granitic magmas. In addition, these highly alkaline solute-rich aqueous fluids suggest a mechanism for Ab-Qz metasomatism in subduction zones, such as in the Catalina schist (Bebout and Barton 1993), which provides an alternative to high P-T magmas. Our results show that subduction zone and metasomatic fluids may be much more alkaline and have significantly higher dissolving power than previously thought.

78 FR 7775 - Boulder Canyon Project

Science.gov (United States)

2013-02-04

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area...), is proposing an adjustment to the Boulder Canyon Project (BCP) electric service base charge and rates... subsequent laws, particularly section 9(c) of the Reclamation Project Act of 1939 (43 U.S.C. 485h(c)); and...

77 FR 2533 - Boulder Canyon Project

Science.gov (United States)

2012-01-18

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area...), is proposing an adjustment to the Boulder Canyon Project (BCP) electric service base charge and rates...) of the Reclamation Project Act of 1939 (43 U.S.C. 485h(c)); and other acts that specifically apply to...

[Dissolved aluminum and organic carbon in soil solution under six tree stands in Lushan forest ecosystems].

Science.gov (United States)

Wang, Lianfeng; Pan, Genxing; Shi, Shengli; Zhang, Lehua; Huang, Mingxing

2003-10-01

Different depths of soils under 6 tree stands in Lushan Botany Garden were sampled and water-digested at room temperature. The dissolved aluminum and organic carbon were then determined by colorimetry, using 8-hydroxylquilin and TOC Analyzer, respectively. The results indicated that even derived from a naturally identical soil type, the test soils exhibited a diverse solution chemistry, regarding with the Al speciation. The soil solutions under Japanese cedar, giant arborvitae and tea had lower pH values and higher contents of soluble aluminum than those under Giant dogwood, azalea and bamboo. Under giant arborvitae, the lowest pH and the highest content of total soluble aluminum and monomeric aluminum were found in soil solution. There was a significant correlation between soluble aluminum and DOC, which tended to depress the accumulation of toxic monomeric aluminum. The 6 tree stands could be grouped into 2 categories of solution chemistry, according to aluminum mobilization.

Reclamation of cadmium-contaminated soil using dissolved organic matter solution originating from wine-processing waste sludge.

Science.gov (United States)

Liu, Cheng-Chung; Chen, Guan-Bu

2013-01-15

Soil washing using an acid solution is a common practice for removing heavy metals from contaminated soil in Taiwan. However, serious loss of nutrients from soil is a major drawback of the washing. Distillery sludge can be used to prepare a dissolved organic matter (DOM) solution by extracting its organic constituents with alkaline solutions. This study employed DOM solutions to remediate Cd-contaminated soil (with concentrations up to 21.5 mg kg(-1)) and determine the factors affecting removal of Cd, such as pH, initial concentration of DOM solution, temperature, and washing frequency. When washing with pH 3.0 and 1250 mg L(-1) DOM solution, about 80% and 81% of Cd were removed from the topsoil at 27 °C and subsoil at 40 °C, respectively. To summarize the changes in fertility during DOM washing with various pH solutions: the increase in organic matter content ranged from 7.7% to 23.7%; cation exchange capacity (CEC) ranged from 4.6% to 13.9%; available ammonium (NNH(4)) content ranged from 39.4% to 2175%; and available phosphorus content ranged from 34.5% to 182%. Exchangeable K, Ca, and Mg remained in the topsoil after DOM washing, with concentrations of 1.1, 2.4, and 1.5 times higher than those treated with HCl solution at the same pH, respectively. Copyright © 2012 Elsevier B.V. All rights reserved.

Air Emission Projections During Acid Cleaning of F-Canyon Waste Header No.2

International Nuclear Information System (INIS)

CHOI, ALEXANDER

2004-01-01

The purpose of this study was to develop the air emission projections for the maintenance operation to dissolve and flush out the scale material inside the F-Canyon Waste Header No.2. The chemical agent used for the dissolution is a concentrated nitric acid solution, so the pollutant of concern is the nitric acid vapor. Under the very conservative operating scenarios considered in this study, it was determined that the highest possible rate of nitric acid emission during the acid flush would be 0.048 lb. per hr. It turns out that this worst-case air emission projection is just below the current exemption limit of 0.05 lb. per hr. for permit applications

The effect of probe choice and solution conditions on the apparent photoreactivity of dissolved organic matter.

Science.gov (United States)

Maizel, Andrew C; Remucal, Christina K

2017-08-16

Excited triplet states of dissolved organic matter ( 3 DOM) are quantified directly with the species-specific probes trans,trans-hexadienoic acid (HDA) and 2,4,6-trimethylphenol (TMP), and indirectly with the singlet oxygen ( 1 O 2 ) probe furfuryl alcohol (FFA). Although previous work suggests that these probe compounds may be sensitive to solution conditions, including dissolved organic carbon concentration ([DOC]) and pH, and may quantify different 3 DOM subpopulations, the probes have not been systematically compared. Therefore, we quantify the apparent photoreactivity of diverse environmental waters using HDA, TMP, and FFA. By conducting experiments under ambient [DOC] and pH, with standardized [DOC] and pH, and with solid phase extraction isolates, we demonstrate that much of the apparent dissimilarity in photochemical measurements is attributable to solution conditions, rather than intrinsic differences in 3 DOM production. In general, apparent quantum yields (Φ 1 O 2 ≥ Φ 3 DOM,TMP ≫ Φ 3 DOM,HDA ) and pseudo-steady state concentrations ([ 1 O 2 ] ss > [ 3 DOM] ss,TMP > [ 3 DOM] ss,HDA ) show consistent relationships in all waters under standardized conditions. However, intrinsic differences in 3 DOM photoreactivity are apparent between DOM from diverse sources, as seen in the higher Φ 1 O 2 and lower Φ 3 DOM,TMP of wastewater effluents compared with oligotrophic lakes. Additionally, while conflicting trends in photoreactivity are observed under ambient conditions, all probes observe quantum yields increasing from surface wetlands to terrestrially influenced waters to oligotrophic lakes under standardized conditions. This work elucidates how probe selection and solution conditions influence the apparent photoreactivity of environmental waters and confirms that 3 DOM or 1 O 2 probes cannot be used interchangeably in waters that vary in [DOC], pH, or DOM source.

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction

Energy Technology Data Exchange (ETDEWEB)

Rudisill, T.S.

2000-11-28

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Data from synoptic water-quality studies on the Colorado River in the Grand Canyon, Arizona, November 1990 and June 1991

Science.gov (United States)

Taylor, Howard E.; Peart, D.B.; Antweiler, Ronald C.; Brinton, T.I.; Campbell, W.L.; Barbarino, J.R.; Roth, D.A.; Hart, R.J.; Averett, R.C.

1996-01-01

Two water-quality synoptic studies were made on the Colorado River in the Grand Canyon, Arizona. Field measurements and the collection of water samples for laboratory analysis were made at 10 mainstem and 6 tributary sites every 6 hours for a 48-hour period on November 5-6, 1990, and again on June 18-20, 1991. Field measurements included discharge, alkalinity, water temperature, light penetration, pH, specific conductance, and dissolved oxygen. Water samples were collected for the laboratory analysis of major and minor ions (calcium, magnesium, sodium, potassium, strontium, chloride, sulfate, silica as SiO2), trace elements (aluminum, arsenic, boron, barium, beryllium, cadmium, cobalt, chromium, copper, iron, lead, lithium, manganese, molybdenum, nickel, selenium, thallium, uranium, vanadium and zinc), and nutrients (phosphate, nitrate, ammonium, nitrite, total dissolved nitrogen, total dissolved phosphorus and dissolved organic carbon). Biological measurements included drift (benthic invertebrates and detrital material), and benthic invertebrates from the river bottom.

Methane Flux and Authigenic Carbonate in Shallow Sediments Overlying Methane Hydrate Bearing Strata in Alaminos Canyon, Gulf of Mexico

Directory of Open Access Journals (Sweden)

Joseph P. Smith

2014-09-01

Full Text Available In June 2007 sediment cores were collected in Alaminos Canyon, Gulf of Mexico across a series of seismic data profiles indicating rapid transitions between the presence of methane hydrates and vertical gas flux. Vertical profiles of dissolved sulfate, chloride, calcium, magnesium, and dissolved inorganic carbon (DIC concentrations in porewaters, headspace methane, and solid phase carbonate concentrations were measured at each core location to investigate the cycling of methane-derived carbon in shallow sediments overlying the hydrate bearing strata. When integrated with stable carbon isotope ratios of DIC, geochemical results suggest a significant fraction of the methane flux at this site is cycled into the inorganic carbon pool. The incorporation of methane-derived carbon into dissolved and solid inorganic carbon phases represents a significant sink in local carbon cycling and plays a role in regulating the flux of methane to the overlying water column at Alaminos Canyon. Targeted, high-resolution geochemical characterization of the biogeochemical cycling of methane-derived carbon in shallow sediments overlying hydrate bearing strata like those in Alaminos Canyon is critical to quantifying methane flux and estimating methane hydrate distributions in gas hydrate bearing marine sediments.

Detection of hydrogen dissolved in acrylonitrile butadiene rubber by 1H nuclear magnetic resonance

Science.gov (United States)

Nishimura, Shin; Fujiwara, Hirotada

2012-01-01

Rubber materials, which are used for hydrogen gas seal, can dissolve hydrogen during exposure in high-pressure hydrogen gas. Dissolved hydrogen molecules were detected by solid state 1H NMR of the unfilled vulcanized acrylonitrile butadiene rubber. Two signals were observed at 4.5 ppm and 4.8 ppm, which were assignable to dissolved hydrogen, in the 1H NMR spectrum of NBR after being exposed 100 MPa hydrogen gas for 24 h at room temperature. These signals were shifted from that of gaseous hydrogen molecules. Assignment of the signals was confirmed by quantitative estimation of dissolved hydrogen and peak area of the signals.

Dissolution Flowsheet for High Flux Isotope Reactor Fuel

Energy Technology Data Exchange (ETDEWEB)

Daniel, W. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Rudisill, T. S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); O' Rourke, P. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Karay, N. S [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-09-27

As part of the Spent Nuclear Fuel (SNF) processing campaign, H-Canyon is planning to begin dissolving High Flux Isotope Reactor (HFIR) fuel in late FY17 or early FY18. Each HFIR fuel core contains inner and outer fuel elements which were fabricated from uranium oxide (U₃O₈) dispersed in a continuous Al phase using traditional powder metallurgy techniques. Fuels fabricated in this manner, like other SNF’s processed in H-Canyon, dissolve by the same general mechanisms with similar gas generation rates and the production of H₂. The HFIR fuel cores will be dissolved and the recovered U will be down-blended into low-enriched U. HFIR fuel was previously processed in H-Canyon using a unique insert in both the 6.1D and 6.4D dissolvers. Multiple cores will be charged to the same dissolver solution maximizing the concentration of dissolved Al. The objective of this study was to identify flowsheet conditions through literature review and laboratory experimentation to safely and efficiently dissolve the HFIR fuel in H-Canyon. Laboratory-scale experiments were performed to evaluate the dissolution of HFIR fuel using both Al 1100 and Al 6061 T6 alloy coupons. The Al 1100 alloy was considered a representative surrogate which provided an upper bound on the generation of flammable (i.e., H₂) gas during the dissolution process. The dissolution of the Al 6061 T6 alloy proceeded at a slower rate than the Al 1100 alloy, and was used to verify that the target Al concentration in solution could be achieved for the selected Hg concentration. Mass spectrometry and Raman spectroscopy were used to provide continuous monitoring of the concentration of H₂ and other permanent gases in the dissolution offgas, allowing the development of H₂ generation rate profiles. The H₂ generation rates were subsequently used to evaluate if a full HFIR core could be dissolved in an H-Canyon dissolver without exceeding 60% of the

Trends in soil solution dissolved organic carbon (DOC) concentrations across European forests

NARCIS (Netherlands)

Camino-Serrano, Marta; Graf Pannatier, Elisabeth; Vicca, Sara; Luyssaert, Sebastiaan; Jonard, Mathieu; Ciais, Philippe; Guenet, Bertrand; Gielen, Bert; Peñuelas, Josep; Sardans, Jordi; Waldner, Peter; Sawicka, Kasia

2016-01-01

Dissolved organic carbon (DOC) in surface waters is connected to DOC in soil solution through hydrological pathways. Therefore, it is expected that long-term dynamics of DOC in surface waters reflect DOC trends in soil solution. However, a multitude of site studies have failed so far to establish

Trends in soil solution dissolved organic carbon (DOC) concentrations across European forests

NARCIS (Netherlands)

Camino-Serrano, M.; Graf Pannatier, E.; Vicca, S.; Luyssaert, S.; Jonard, M.; Ciais, P.; Guenet, B.; Gielen, B.; Peñuelas, J.; Sardans, J.; Waldner, P.; Etzold, S.; Cecchini, G.; Clarke, N.; Galić, Z.; Gandois, L.; Hansen, K.; Johnson, J.; Klinck, U.; Lachmanová, Z.; Lindroos, A.J.; Meesenburg, H.; Nieminen, T.M.; Sanders, T.G.M.; Sawicka, K.; Seidling, W.; Thimonier, A.; Vanguelova, E.; Verstraeten, A.; Vesterdal, L.; Janssens, I.A.

2016-01-01

Dissolved organic carbon (DOC) in surface waters is connected to DOC in soil solution through hydrological pathways. Therefore, it is expected that long-term dynamics of DOC in surface waters reflect DOC trends in soil solution. However, a multitude of site studies have failed so far to establish

Macrofaunal Patterns in and around du Couedic and Bonney Submarine Canyons, South Australia.

Directory of Open Access Journals (Sweden)

Kathleen E Conlan

Full Text Available Two South Australian canyons, one shelf-incising (du Couedic and one slope-limited (Bonney were compared for macrofaunal patterns on the shelf and slope that spanned three water masses. It was hypothesized that community structure would (H1 significantly differ by water mass, (H2 show significant regional differences and (H3 differ significantly between interior and exterior of each canyon. Five hundred and thirty-one species of macrofauna ≥ 1 mm were captured at 27 stations situated in depth stratified transects inside and outside the canyons from 100 to 1500 m depth. The macrofauna showed a positive relationship to depth in abundance, biomass, species richness and community composition while taxonomic distinctness and evenness remained high at all depths. Biotic variation on the shelf was best defined by variation in bottom water primary production while sediment characteristics and bottom water oxygen, temperature and nutrients defined biotic variation at greater depth. Community structure differed significantly (p<0.01 among the three water masses (shelf-flowing South Australian current, upper slope Flinders current and lower slope Antarctic Intermediate Water (H1. Although community differences between the du Couedic and Bonney regions were marginally above significance at p = 0.05 (H2, over half of the species captured were unique to each region. This supports the evidence from fish and megafaunal distributions that the du Couedic and Bonney areas are in different bioregions. Overall, the canyon interiors were not significantly different in community composition from the exterior (H3. However, both canyons had higher abundance and/or biomass, increased species dominance, different species composition and coarser sediments near the canyon heads compared to outside the canyons at the same depth (500 m, suggestive of heightened currents within the canyons that influence community composition there. At 1000-1500 m, the canyon interiors were

Modelling the air flow in symmetric and asymmetric street canyons

Energy Technology Data Exchange (ETDEWEB)

Santiago, J.L.; Martin, F. [Research Center for Energy, Environment and Technology (CIEMAT), Madrid (Spain). Fossil Fuels Dept., Numerical Simulation and Modelling Program

2004-07-01

In recent years a large amount of research has been conducted on urban scale and street canyon. Control of air quality inside cities is important for human health. To achieve this objective, street canyon modelling plays a significant role. Pollutant dispersion inside canyons are determined by wind flow around this complex geometry. Experimental investigations have been made by means of field measurements such as Vachon, G. et al. or wind tunnel experiences as Meroney, R.N. et al. or Kastner-Klein, P. and E.J. Plate. In many of these researches, they have used CFD models in several configurations, for instance Assimakopoulos, V.D. et al. or Sini, J.-F. et al. These models are based on a numerical resolution of Navier-Stokes equations with a turbulence closure. In this study, the aim is contribute to the understanding of air circulation inside street canyons. In order to achieve this purpose, several configurations of canyons are investigated. Two-dimensional sequences of real-scale street canyons (order to obstacles height is meters) with different features (symmetric canyons and asymmetric canyons forming step-up and step-down notch configurations) are simulated. These general configurations are modified to investigate some parameters such as aspect ratio, W/H, where W is the width of street and H is the height of buildings. Flows with high Reynolds numbers are modelling. FLUENT CFD software is used. (orig.)

Hydrogeology of Middle Canyon, Oquirrh Mountains, Tooele County, Utah

Science.gov (United States)

Gates, Joseph Spencer

1963-01-01

Geology and climate are the principal influences affecting the hydrology of Middle Canyon, Tooele County, Utah. Reconnaissance in the canyon indicated that the geologic influences on the hydrology may be localized; water may be leaking through fault and fracture zones or joints in sandstone and through solution openings in limestone of the Oquirrh formation of Pennsylvanian and Permian age. Surficial deposits of Quaternary age serve as the main storage material for ground water in the canyon and transmit water from the upper canyon to springs and drains at the canyon mouth. The upper canyon is a more important storage area than the lower canyon because the surficial deposits are thicker, and any zones of leakage in the underlying bedrock of the upper canyon probably would result in greater leakage than would similar outlets in the lower canyon.The total annual discharge from Middle Canyon, per unit of precipitation, decreased between 1910 and 1939. Similar decreases occurred in Parleys Canyon in the nearby Wasatch Range and in other drainage basins in Utah, and it is likely that most of the decrease in discharge from Middle Canyon and other canyons in Utah is due to a change in climate.Chemical analyses of water showed that the high content of sulfate and other constituents in the water from the Utah Metals tunnel, which drains into Middle Canyon, does not have a significant effect on water quality at the canyon mouth. This suggests that much of the tunnel water is lost from the channel by leakage, probably in the upper canyon, during the dry part of the year.Comparison of the 150 acre-feet of water per square mile of drainage area discharged by Middle Canyon in 1947 with the 623 and 543 acre-feet per square mile discharged in 1948 by City Creek and Mill Creek Canyons, two comparable drainage basins in the nearby Wasatch Range, also suggests that there is leakage in Middle Canyon.A hydrologic budget of the drainage basin results in an estimate that about 3,000 acre

The Whittard Canyon - A case study of submarine canyon processes

Science.gov (United States)

Amaro, T.; Huvenne, V. A. I.; Allcock, A. L.; Aslam, T.; Davies, J. S.; Danovaro, R.; De Stigter, H. C.; Duineveld, G. C. A.; Gambi, C.; Gooday, A. J.; Gunton, L. M.; Hall, R.; Howell, K. L.; Ingels, J.; Kiriakoulakis, K.; Kershaw, C. E.; Lavaleye, M. S. S.; Robert, K.; Stewart, H.; Van Rooij, D.; White, M.; Wilson, A. M.

2016-08-01

Submarine canyons are large geomorphological features that incise continental shelves and slopes around the world. They are often suggested to be biodiversity and biomass hotspots, although there is no consensus about this in the literature. Nevertheless, many canyons do host diverse faunal communities but owing to our lack of understanding of the processes shaping and driving this diversity, appropriate management strategies have yet to be developed. Here, we integrate all the current knowledge of one single system, the Whittard Canyon (Celtic Margin, NE Atlantic), including the latest research on its geology, sedimentology, geomorphology, oceanography, ecology, and biodiversity in order to address this issue. The Whittard Canyon is an active system in terms of sediment transport. The net suspended sediment transport is mainly up-canyon causing sedimentary overflow in some upper canyon areas. Occasionally sediment gravity flow events do occur, some possibly the result of anthropogenic activity. However, the role of these intermittent gravity flows in transferring labile organic matter to the deeper regions of the canyon appears to be limited. More likely, any labile organic matter flushed downslope in this way becomes strongly diluted with bulk material and is therefore of little food value for benthic fauna. Instead, the fresh organic matter found in the Whittard Channel mainly arrives through vertical deposition and lateral transport of phytoplankton blooms that occur in the area during spring and summer. The response of the Whittard Canyon fauna to these processes is different in different groups. Foraminiferal abundances are higher in the upper parts of the canyon and on the slope than in the lower canyon. Meiofaunal abundances in the upper and middle part of the canyon are higher than on adjacent slopes, but lower in the deepest part. Mega- and macrofauna abundances are higher in the canyon compared with the adjacent slope and are higher in the eastern than

Mineral resources of the Desolation Canyon, Turtle Canyon, and Floy Canyon Wilderness Study Areas, Carbon Emery, and Grand counties, Utah

International Nuclear Information System (INIS)

Cashion, W.B.; Kilburn, J.E.; Barton, H.N.; Kelley, K.D.; Kulik, D.M.; McDonnell, J.R.

1990-09-01

This paper reports on the Desolation Canyon, Turtle Canyon, and Floy Canyon Wilderness Study Areas which include 242,000 acres, 33,690 acres, and 23,140 acres. Coal deposits underlie all three study areas. Coal zones in the Blackhawk and Nelsen formations have identified bituminous coal resources of 22 million short tons in the Desolation Canyon Study Area, 6.3 million short tons in the Turtle Canyon Study Area, and 45 million short tons in the Floy Canyon Study Area. In-place inferred oil shale resources are estimated to contain 60 million barrels in the northern part of the Desolation Canyon area. Minor occurrences of uranium have been found in the southeastern part of the Desolation Canyon area and in the western part of the Floy Canyon area. Mineral resource potential for the study areas is estimated to be for coal, high for all areas, for oil and gas, high for the northern tract of the Desolation Canyon area and moderate for all other tracts, for bituminous sandstone, high for the northern part of the Desolation Canyon area, and low for all other tracts, for oil shale, low in all areas, for uranium, moderate for the Floy Canyon area and the southeastern part of the Desolation Canyon area and low for the remainder of the areas, for metals other than uranium, bentonite, zeolites, and geothermal energy, low in all areas, and for coal-bed methane unknown in all three areas

Fault tree analysis of Project S-4404, Upgrade Canyon Exhaust System

International Nuclear Information System (INIS)

Browne, E.V.; Low, J.M.; Lux, C.R.

1992-01-01

Project S-4404, Upgrade Canyon Exhaust Systems, is a $177 million project with the purpose of upgrading the Exhaust Systems for both F and H Canyon Facilities. This upgrade will replace major portions of the F and H-Canyon exhaust systems, downstream of their respective sand filters with higher capacity and more reliable systems. Because of the high cost, DOE requested Program Control ampersand Integration (PC ampersand I) to examine specific deletions to the project. PC ampersand I requested Nuclear Processes Safety Research (NPSR) to perform an analysis to compare failure rates for the existing F ampersand H Canyon exhaust systems with the proposed exhaust system and specific proposed exhaust system alternatives. The objective of this work was to perform an analysis and compare failure rates for the existing F ampersand H Canyon exhaust systems with the proposed project exhaust system and proposed project alternatives. Based on fault tree analysis, two conclusions are made. First, D ampersand D activities can be eliminated from the project with no significant decrease to exhaust system safety. Deletion of D ampersand D activities would result in a cost savings of $29 million. Second, deletion of DOE Order 6430.1A requirements regarding DBAs would decrease exhaust system safety by a factor of 12

Passive air exchanges between building and urban canyon via openings in a single facade

International Nuclear Information System (INIS)

Syrios, K.; Hunt, G.R.

2008-01-01

The results of an experimental study examining the steady exchange of air and heat between a building and an urban canyon are presented. The focus is on the effect of the canyon aspect ratio on the airflow through openings made exclusively in one side of the building. The interaction of the external wind flow and the internal thermally-driven flow was shown to depend upon the ratio of the building height H b to the canyon width W (distance between buildings forming the canyons). The trends observed as this aspect ratio (H b /W) was varied allow for identification of canyon geometries that yield reduced or enhanced building ventilation airflow rates

Enzymatic hydrolysis of cellulose dissolved in N-methyl morpholine oxide/water solutions.

Science.gov (United States)

Ramakrishnan, S; Collier, J; Oyetunji, R; Stutts, B; Burnett, R

2010-07-01

In situ hydrolysis of cellulose (dissolving pulp) in N-methyl morpholine oxide (NMMO) solutions by commercially available Accellerase1000 is carried out. The yield of reducing sugars is followed as a function of time at three different temperatures and four different enzyme loadings to study the effect of system parameters on enzymatic hydrolysis. Initial results show that rates of hydrolysis of cellulose and yields of reducing sugars in the presence of NMMO-water is superior initially (ratio of initial reaction rates approximately 4) and comparable to that of regenerated cellulose (for times greater than 5h) when suspended in aqueous solutions. The usage of Accellerase1000 results predominantly in the formation of glucose with minimal amounts of cellobiose. This study proves the ability of cellulases to remain active in NMMO to carry out an in situ saccharification of cellulose thus eliminating the need to recover regenerated cellulose. Thus this work will form the basis for developing a continuous process for conversion of biomass to hydrogen, ethanol and other hydrocarbons. Copyright 2009 Elsevier Ltd. All rights reserved.

Water quality and quantity of selected springs and seeps along the Colorado River corridor, Utah and Arizona: Arches National Park, Canyonlands National Park, Glen Canyon National Recreation Area, and Grand Canyon National Park, 1997-98

Science.gov (United States)

Taylor, Howard E.; Spence, John R.; Antweiler, Ronald C.; Berghoff, Kevin; Plowman, Terry I.; Peart, Dale B.; Roth, David A.

2004-01-01

The U.S. Geological Survey, in cooperation with the National Park Service conducted an intensive assessment of selected springs along the Colorado River Corridor in Arches National Park, Canyonlands National Park, Glen Canyon National Recreation Area, and Grand Canyon National Park in 1997 and 1998, for the purpose of measuring and evaluating the water quality and quantity of the resource. This study was conducted to establish baseline data for the future evaluation of possible effects from recreational use and climate change. Selected springs and seeps were visited over a study period from 1997 to 1998, during which, discharge and on-site chemical measurements were made at selected springs and seeps, and samples were collected for subsequent chemical laboratory analysis. This interdisciplinary study also includes simultaneous studies of flora and fauna, measured and sampled coincidently at the same sites. Samples collected during this study were transported to U.S. Geological Survey laboratories in Boulder, Colorado, where analyses were performed using state-of-the-art laboratory technology. The location of the selected springs and seeps, elevation, geology, aspect, and onsite measurements including temperature, discharge, dissolved oxygen, pH, and specific conductance, were recorded. Laboratory analyses include determinations for alkalinity, aluminum, ammonium (nitrogen), antimony, arsenic, barium, beryllium, bismuth, boron, bromide, cadmium, calcium, cerium, cesium, chloride, chromium, cobalt, copper, dissolved inorganic carbon, dissolved organic carbon, dysprosium, erbium, europium, fluoride, gadolinium, holmium, iodine, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, nitrate (nitrogen), nitrite (nitrogen), phosphate, phosphorus, potassium, praseodymium, rhenium, rubidium, samarium, selenium, silica, silver, sodium, strontium, sulfate, tellurium, terbium, thallium, thorium, thulium, tin, titanium, tungsten

Trees as environmental modifier to improve street canyon for pedestrian activities in Muscat

Science.gov (United States)

Khudhayer, Wael A.; Shaaban, Awni K.; Sukor, Nur Sabahiah Abdul

2017-10-01

Street shading efficiency is a function of orientation and profile proportion of its height to width. Under high sun altitude conditions, minimization of solar irradiance within the urban environment may often be a significant criterion in urban design. This reduction in solar irradiance achieved when the obstruction angle is large (high H/W ratio, H=height, W=width). High H/W values often lessen the solar access to streets. The horizontal sprawl of Muscat region is an example of low H/W ratio represented the remarkable challenge that causes the lack of shading rates in the urban street. This characteristic proliferates the negative impact on the pedestrian activities in the urban street. This research aims to improve the morphology of the street to promote the pedestrian behavior. The amendment based on suggesting different configurations of trees to increase effective shading of the urban street in Muscat. The street canyon abstracted into a virtual elongated channel formed of floor and walls of equal heights on both sides. Four street orientations (E/W, N/S, NE/SW, NW/SE) and three H/W ratio (0.5,1 and 2) are considered sufficient representative of street typologies. A mathematical model developed for calculation of shading efficiency of each street canyon. The trees assumed in this study as canyon's modifier to adjust the low H/W ratio of a street canyon to a higher one. Local trees and other plants in Muscat were studied concerning their morphology. The analysis selected two case study in Muscat to investigate the shading performance of their street canyons subsequently propose the modifications to improve it. The research concluded that the suggested changes of the street canyon by using a particular type of trees could increase the H/W ratio of street canyon significantly.

Reclamation of zinc-contaminated soil using a dissolved organic carbon solution prepared using liquid fertilizer from food-waste composting.

Science.gov (United States)

Chiang, Po-Neng; Tong, Ou-Yang; Chiou, Chyow-San; Lin, Yu-An; Wang, Ming-Kuang; Liu, Cheng-Chung

2016-01-15

A liquid fertilizer obtained through food-waste composting can be used for the preparation of a dissolved organic carbon (DOC) solution. In this study, we used the DOC solutions for the remediation of a Zn-contaminated soil (with Zn concentrations up to 992 and 757 mg kg(-1) in topsoil and subsoil, respectively). We then determined the factors that affect Zn removal, such as pH, initial concentration of DOC solution, and washing frequency. Measurements using a Fourier Transform infrared spectrometer (FT-IR) revealed that carboxyl and amide were the major functional groups in the DOC solution obtained from the liquid fertilizer. Two soil washes using 1,500 mg L(-1) DOC solution with a of pH 2.0 at 25°C removed about 43% and 21% of the initial Zn from the topsoil and subsoil, respectively. Following this treatment, the pH of the soil declined from 5.4 to 4.1; organic matter content slightly increased from 6.2 to 6.5%; available ammonium (NH4(+)-N) content increased to 2.4 times the original level; and in the topsoil, the available phosphorus content and the exchangeable potassium content increased by 1.65 and 2.53 times their initial levels, respectively. Copyright © 2015 Elsevier B.V. All rights reserved.

Influence of roadside hedgerows on air quality in urban street canyons

Science.gov (United States)

Gromke, Christof; Jamarkattel, Nabaraj; Ruck, Bodo

2016-08-01

Understanding pollutant dispersion in the urban environment is an important aspect of providing solutions to reduce personal exposure to vehicle emissions. To this end, the dispersion of gaseous traffic pollutants in urban street canyons with roadside hedges was investigated. The study was performed in an atmospheric boundary layer wind tunnel using a reduced-scale (M = 1:150) canyon model with a street-width-to-building-height ratio of W/H = 2 and a street-length-to-building-height ratio of L/H = 10. Various hedge configurations of differing height, permeability and longitudinal segmentation (continuous over street length L or discontinuous with clearings) were investigated. Two arrangements were examined: (i) two eccentric hedgerows sidewise of the main traffic lanes and (ii) one central hedgerow between the main traffic lanes. In addition, selected configurations of low boundary walls, i.e. solid barriers, were examined. For a perpendicular approach wind and in the presence of continuous hedgerows, improvements in air quality in the center area of the street canyon were found in comparison to the hedge-free reference scenario. The pollutant reductions were greater for the central hedge arrangements than for the sidewise arrangements. Area-averaged reductions between 46 and 61% were observed at pedestrian head height level on the leeward side in front of the building for the centrally arranged hedges and between 18 and 39% for the two hedges arranged sidewise. Corresponding area-averaged reductions ranging from 39 to 55% and from 1 to 20% were found at the bottom of the building facades on the leeward side. Improvements were also found in the areas at the lateral canyon ends next to the crossings for the central hedge arrangements. For the sidewise arrangements, increases in traffic pollutants were generally observed. However, since the concentrations in the end areas were considerably lower compared to those in the center area, an overall improvement remained

Low temperature dissolution flowsheet for plutonium metal

Energy Technology Data Exchange (ETDEWEB)

Daniel, W. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Almond, P. M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Rudisill, T. S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-05-01

The H-Canyon flowsheet used to dissolve Pu metal for PuO₂ production utilizes boiling HNO₃. SRNL was requested to develop a complementary dissolution flowsheet at two reduced temperature ranges. The dissolution and H₂ generation rates of Pu metal were investigated using a dissolving solution at ambient temperature (20-30 °C) and for an intermediate temperature of 50-60 °C. Additionally, the testing included an investigation of the dissolution rates and characterization of the off-gas generated from the ambient temperature dissolution of carbon steel cans and the nylon bags that contain the Pu metal when charged to the dissolver.

Seasonal monitoring of deep-sea megabenthos in Barkley Canyon cold seep by internet operated vehicle (IOV.

Directory of Open Access Journals (Sweden)

Carolina Doya

Full Text Available Knowledge of the processes shaping deep-sea benthic communities at seasonal scales in cold-seep environments is incomplete. Cold seeps within highly dynamic regions, such as submarine canyons, where variable current regimes may occur, are particularly understudied. Novel Internet Operated Vehicles (IOVs, such as tracked crawlers, provide new techniques for investigating these ecosystems over prolonged periods. In this study a benthic crawler connected to the NEPTUNE cabled infrastructure operated by Ocean Networks Canada was used to monitor community changes across 60 m2 of a cold-seep area of the Barkley Canyon, North East Pacific, at ~890 m depth within an Oxygen Minimum Zone (OMZ. Short video-transects were run at 4-h intervals during the first week of successive calendar months, over a 14 month period (February 14th 2013 to April 14th 2014. Within each recorded transect video megafauna abundances were computed and changes in environmental conditions concurrently measured. The responses of fauna to environmental conditions as a proxy of seasonality were assessed through analysis of abundances in a total of 438 video-transects (over 92 h of total footage. 7698 fauna individuals from 6 phyla (Cnidaria, Ctenophora, Arthropoda, Echinodermata, Mollusca, and Chordata were logged and patterns in abundances of the 7 most abundant taxa (i.e. rockfish Sebastidae, sablefish Anoplopoma fimbria, hagfish Eptatretus stoutii, buccinids (Buccinoidea, undefined small crabs, ctenophores Bolinopsis infundibulum, and Scyphomedusa Poralia rufescens were identified. Patterns in the reproductive behaviour of the grooved tanner crab (Chionnecetes tanneri were also indicated. Temporal variations in biodiversity and abundance in megabenthic fauna was significantly influenced by variabilities in flow velocity flow direction (up or down canyon, dissolved oxygen concentration and month of study. Also reported here for the first time are transient mass aggregations of

A Numerical Study on the Effects of Street‒canyon Aspect‒ratio on Reactive Pollutant Dispersion

Science.gov (United States)

Park, S. J.; Kim, J.

2014-12-01

In this study, the effects of street‒canyon aspect‒ratio on reactive pollutant dispersion were investigated using the coupled CFD‒chemistry model. For this, flow characteristics were analyzed first in street canyons with different aspect ratios and flow regimes were classified according to the building height. For each flow regime, dispersion characteristics were investigated in views of reactive pollutant concentration and VOCs‒NOX ratio. Finally, the relations between pollutant concentration and aspect ratio in urban street canyons were investigated. In the case of H/S = 1.0 (H is building height and S is street width), one clockwise‒rotating vortex appeared vertically and the reverse and outward flows were dominant near the street bottom. In the case of H/S = 2.0, two counter‒rotating vortices appeared vertically in the street canyon. The primary (secondary) vortex rotating clockwise (counterclockwise) was formed in upper (lower) layer. The flow patterns affected the reactive pollutant concentration in street canyons. As building height increased, mean concentration of NO decreased when one vortex was generated in street canyons and increased when two vortexes appeared in street canyons. O3 concentration showed almost contrasted tendency with those of NO because O3 was depleted by the NO titration.

Reclamation of zinc-contaminated soil using a dissolved organic carbon solution prepared using liquid fertilizer from food-waste composting

International Nuclear Information System (INIS)

Chiang, Po-Neng; Tong, Ou-Yang; Chiou, Chyow-San; Lin, Yu-An; Wang, Ming-Kuang; Liu, Cheng-Chung

2016-01-01

Highlights: • Nitrogen, phosphorus, and potassium contents in soil are substantially increased after the DOC washing. • The removal of Zn is dominated by proton replacement at pH 2.0, rather than by complexation with DOC. • The removal of Zn is dominated by DOC complexation between pH 3.0 and pH 5.0. - Abstract: A liquid fertilizer obtained through food-waste composting can be used for the preparation of a dissolved organic carbon (DOC) solution. In this study, we used the DOC solutions for the remediation of a Zn-contaminated soil (with Zn concentrations up to 992 and 757 mg kg −1 in topsoil and subsoil, respectively). We then determined the factors that affect Zn removal, such as pH, initial concentration of DOC solution, and washing frequency. Measurements using a Fourier Transform infrared spectrometer (FT-IR) revealed that carboxyl and amide were the major functional groups in the DOC solution obtained from the liquid fertilizer. Two soil washes using 1,500 mg L −1 DOC solution with a of pH 2.0 at 25 °C removed about 43% and 21% of the initial Zn from the topsoil and subsoil, respectively. Following this treatment, the pH of the soil declined from 5.4 to 4.1; organic matter content slightly increased from 6.2 to 6.5%; available ammonium (NH 4 + -N) content increased to 2.4 times the original level; and in the topsoil, the available phosphorus content and the exchangeable potassium content increased by 1.65 and 2.53 times their initial levels, respectively.

Reclamation of zinc-contaminated soil using a dissolved organic carbon solution prepared using liquid fertilizer from food-waste composting

Energy Technology Data Exchange (ETDEWEB)

Chiang, Po-Neng [Experimental Forest, National Taiwan University, Chushan, Nantou County, 55750, Taiwan (China); Tong, Ou-Yang [Department of Environment Engineering, College of the Environment and Ecology, and The Key Laboratory of the Ministry of Education for Coastal and Wetland Ecosystem, Xiamen University, Xiamen (China); Chiou, Chyow-San; Lin, Yu-An [Department of Environmental Engineering, National Ilan University, Ilan 26047, Taiwan (China); Wang, Ming-Kuang [Department of Animal Science, National Ilan University, Ilan 26047, Taiwan (China); Liu, Cheng-Chung, E-mail: ccliu@niu.edu.tw [Department of Agricultural Chemistry, National Taiwan University, Taipei 10617, Taiwan (China)

2016-01-15

Highlights: • Nitrogen, phosphorus, and potassium contents in soil are substantially increased after the DOC washing. • The removal of Zn is dominated by proton replacement at pH 2.0, rather than by complexation with DOC. • The removal of Zn is dominated by DOC complexation between pH 3.0 and pH 5.0. - Abstract: A liquid fertilizer obtained through food-waste composting can be used for the preparation of a dissolved organic carbon (DOC) solution. In this study, we used the DOC solutions for the remediation of a Zn-contaminated soil (with Zn concentrations up to 992 and 757 mg kg{sup −1} in topsoil and subsoil, respectively). We then determined the factors that affect Zn removal, such as pH, initial concentration of DOC solution, and washing frequency. Measurements using a Fourier Transform infrared spectrometer (FT-IR) revealed that carboxyl and amide were the major functional groups in the DOC solution obtained from the liquid fertilizer. Two soil washes using 1,500 mg L{sup −1} DOC solution with a of pH 2.0 at 25 °C removed about 43% and 21% of the initial Zn from the topsoil and subsoil, respectively. Following this treatment, the pH of the soil declined from 5.4 to 4.1; organic matter content slightly increased from 6.2 to 6.5%; available ammonium (NH{sub 4}{sup +}-N) content increased to 2.4 times the original level; and in the topsoil, the available phosphorus content and the exchangeable potassium content increased by 1.65 and 2.53 times their initial levels, respectively.

Effect of Dissolved Oxygen and Immersion Time on the Corrosion Behaviour of Mild Steel in Bicarbonate/Chloride Solution

Directory of Open Access Journals (Sweden)

Gaius Debi Eyu

2016-09-01

Full Text Available The electrochemical behavior of mild steel in bicarbonate solution at different dissolved oxygen (DO concentrations and immersion times has been studied under dynamic conditions using electrochemical techniques. The results show that both DO and immersion times influence the morphology of the corrosion products. In comparative tests, the corrosion rate was systematically found to be lower in solutions with lower DO, lower HCO3− concentrations and longer immersion time. The SEM analyses reveal that the iron dissolution rate was more severe in solutions containing higher DO. The decrease in corrosion rate can be attributed to the formation of a passive layer containing mainly α -FeO (OH and ( γ -Fe2O3/Fe3O4 as confirmed by the X-ray diffractometry (XRD and X-ray photoelectron spectroscopy (XPS. Passivation of mild steel is evident in electrochemical test at ≈ −600 mVSCE at pH ≥ 8 in dearated ( ≤ 0.8 ppm DO chloride bicarbonate solution under dynamic conditions.

Thermal bioclimate in idealized urban street canyons in Campinas, Brazil

Science.gov (United States)

Abreu-Harbich, Loyde V.; Labaki, Lucila C.; Matzarakis, Andreas

2014-01-01

Among several urban design parameters, the height-to-width ratio (H/W) and orientation are important parameters strongly affecting thermal conditions in cities. This paper quantifies changes in thermal comfort due to typical urban canyon configurations in Campinas, Brazil, and presents urban guidelines concerning H/W ratios and green spaces to adapt urban climate change. The study focuses on thermal comfort issues of humans in urban areas and performs evaluation in terms of physiologically equivalent temperature (PET), based on long-term data. Meteorological data of air temperature, relative humidity, wind speed and solar radiation over a 7-year period (2003-2010) were used. A 3D street canyon model was designed with RayMan Pro software to simulate the influence of urban configuration on urban thermal climate. The following configurations and setups were used. The model canyon was 500 m in length, with widths 9, 21, and 44 m. Its height varied in steps of 2.5 m, from 5 to 40 m. The canyon could be rotated in steps of 15°. The results show that urban design parameters such as width, height, and orientation modify thermal conditions within street canyons. A northeast-southwest orientation can reduce PET during daytime more than other scenarios. Forestry management and green areas are recommended to promote shade on pedestrian areas and on façades, and to improve bioclimate thermal stress, in particular for H/W ratio less than 0.5. The method and results can be applied by architects and urban planners interested in developing responsive guidelines for urban climate issues.

The effect of the oxygen dissolved in the adsorption of gold in activated carbon

International Nuclear Information System (INIS)

Navarro, P.; Wilkomirsky, I.

1999-01-01

The effect of the oxygen dissolved on the adsorption of gold in a activated carbon such as these used for carbon in pulp (CIP) and carbon in leach (CIL) processes were studied. The research was oriented to dilucidate the effect of the oxygen dissolved in the gold solution on the kinetics and distribution of the gold adsorbed in the carbon under different conditions of ionic strength, pH and gold concentration. It was found that the level of the oxygen dissolved influences directly the amount of gold adsorbed on the activated carbon, being this effect more relevant for low ionic strength solutions. The pH and initial gold concentration has no effect on this behavior. (Author) 16 refs

Pollutant Concentrations in Street Canyons of Different Aspect Ratio with Avenues of Trees for Various Wind Directions

Science.gov (United States)

Gromke, Christof; Ruck, Bodo

2012-07-01

This study summarizes the effects of avenues of trees in urban street canyons on traffic pollutant dispersion. We describe various wind-tunnel experiments with different tree-avenue models in combination with variations in street-canyon aspect ratio W/ H (with W the street-canyon width and H the building height) and approaching wind direction. Compared to tree-free street canyons, in general, higher pollutant concentrations are found. Avenues of trees do not suppress canyon vortices, although the air ventilation in canyons is hindered significantly. For a perpendicular wind direction, increases in wall-average and wall-maximum concentrations at the leeward canyon wall and decreases in wall-average concentrations at the windward wall are found. For oblique and perpendicular wind directions, increases at both canyon walls are obtained. The strongest effects of avenues of trees on traffic pollutant dispersion are observed for oblique wind directions for which also the largest concentrations at the canyon walls are found. Thus, the prevailing assumption that attributes the most harmful dispersion conditions to a perpendicular wind direction does not hold for street canyons with avenues of trees. Furthermore, following dimensional analysis, an estimate of the normalized wall-maximum traffic pollutant concentration in street canyons with avenues of trees is derived.

Diablo Canyon

International Nuclear Information System (INIS)

Bindon, F.J.L.

1986-01-01

The paper traces the history of Diablo Canyon nuclear power station, California, which took 18 years to reach full-power testing from the planning stage. The major delays during the construction are outlined, as well as the costs of Diablo Canyon. (UK)

The effect of dissolved oxygen on water radiolysis behaviour

International Nuclear Information System (INIS)

Yakabuskie, P.A.; Joseph, J.M.; Wren, J.C.; Stuart, C.R.

2012-09-01

A quantitative understanding of the chemical or redox environments generated in water by ionizing radiation is important for material selection, development of maintenance programs, and safety assessments for water-cooled nuclear power reactors. The highly reactive radicals (·OH, ·H, ·e aq - , ·HO 2 , and ·O 2 - ) and molecular species (H 2 and H 2 O 2 ) generated by water radiolysis can compete in reactions with other dissolved compounds and impose changes to the system chemistry by altering the steady-state concentrations of water radiolysis products, which could impact the degradation of materials in contact with the aqueous phase. Understanding in detail how a given chemical additive changes the long-term radiolysis kinetics can help us to determine what chemistry control steps may be required to return the system to an optimal redox condition, and in turn, enhance the lifetime of reactor components. This study outlines the effect of dissolved oxygen gas, which could be introduced due to air ingress, on long-term water radiolysis behaviour. The effects of solution pH and initial dissolved O 2 concentration on the radiolytic production of molecular H 2 and H 2 O 2 have been investigated by performing experiments with three different O 2 concentrations at pH 6.0 and 10.6 under steady-state radiolysis conditions. The aqueous and gas phase analyses were performed using UV-Vis spectrophotometry and gas-chromatography equipped with electron capture and thermal conductivity detectors. The experimental results were compared with kinetic model calculations of steady-state radiolysis and were found to be in good agreement. The concentrations of water radiolysis products, H 2 O 2 and H 2 , were found to increase in the presence of dissolved oxygen, but the degree of increase was shown to depend on the solution pH. Furthermore, the steady-state concentration of H 2 did not increase as greatly as that of H 2 O 2 at either pH studied. The kinetic analyses have shown

Supersaturation of dissolved H(2) and CO (2) during fermentative hydrogen production with N(2) sparging.

Science.gov (United States)

Kraemer, Jeremy T; Bagley, David M

2006-09-01

Dissolved H(2) and CO(2) were measured by an improved manual headspace-gas chromatographic method during fermentative H(2) production with N(2) sparging. Sparging increased the yield from 1.3 to 1.8 mol H(2)/mol glucose converted, although H(2) and CO(2) were still supersaturated regardless of sparging. The common assumption that sparging increases the H(2) yield because of lower dissolved H(2) concentrations may be incorrect, because H(2) was not lowered into the range necessary to affect the relevant enzymes. More likely, N(2) sparging decreased the rate of H(2) consumption via lower substrate concentrations.

Water chemistry of surface waters affected by the Fourmile Canyon wildfire, Colorado, 2010-2011

Science.gov (United States)

McCleskey, R. Blaine; Writer, Jeffrey H.; Murphy, Sheila F.

2012-01-01

In September 2010, the Fourmile Canyon fire burned about 23 percent of the Fourmile Creek watershed in Boulder County, Colo. Water-quality sampling of Fourmile Creek began within a month after the wildfire to assess its effects on surface-water chemistry. Water samples were collected from five sites along Fourmile Creek (above, within, and below the burned area) monthly during base flow, twice weekly during snowmelt runoff, and at higher frequencies during storm events. Stream discharge was also monitored. Water-quality samples were collected less frequently from an additional 6 sites on Fourmile Creek, from 11 tributaries or other inputs, and from 3 sites along Boulder Creek. The pH, electrical conductivity, temperature, specific ultraviolet absorbance, total suspended solids, and concentrations (dissolved and total) of major cations (calcium, magnesium, sodium, and potassium), anions (chloride, sulfate, alkalinity, fluoride, and bromide), nutrients (nitrate, ammonium, and phosphorus), trace metals (aluminum, arsenic, boron, barium, beryllium, cadmium, cobalt, chromium, copper, iron, mercury, lithium, manganese, molybdenum, nickel, lead, rubidium, antimony, selenium, strontium, vanadium, and zinc), and dissolved organic carbon are here reported for 436 samples collected during 2010 and 2011.

Dissolving method for nuclear fuel oxide

International Nuclear Information System (INIS)

Tomiyasu, Hiroshi; Kataoka, Makoto; Asano, Yuichiro; Hasegawa, Shin-ichi; Takashima, Yoichi; Ikeda, Yasuhisa.

1996-01-01

In a method of dissolving oxides of nuclear fuels in an aqueous acid solution, the oxides of the nuclear fuels are dissolved in a state where an oxidizing agent other than the acid is present together in the aqueous acid solution. If chlorate ions (ClO 3 - ) are present together in the aqueous acid solution, the chlorate ions act as a strong oxidizing agent and dissolve nuclear fuels such as UO 2 by oxidation. In addition, a Ce compound which generates Ce(IV) by oxidation is added to the aqueous acid solution, and an ozone (O 3 ) gas is blown thereto to dissolve the oxides of nuclear fuels. Further, the oxides of nuclear fuels are oxidized in a state where ClO 2 is present together in the aqueous acid solution to dissolve the oxides of nuclear fuels. Since oxides of the nuclear fuels are dissolved in a state where the oxidizing agent is present together as described above, the oxides of nuclear fuels can be dissolved even at a room temperature, thereby enabling to use a material such as polytetrafluoroethylene and to dissolve the oxides of nuclear fuels at a reduced cost for dissolution. (T.M.)

Analysis of the Momentum and Pollutant Transport at the Roof Level of 2D Idealized Street Canyons: a Large-Eddy Simulation Solution

Science.gov (United States)

Cheng, Wai Chi; Liu, Chun-Ho

2010-05-01

transport and mixing near the windward facade. Budget analyses of the velocity variance, shear stress, pollutant concentration and pollutant flux were also performed. A sharp peak of TKE production is developed at the roof level. Owing to the strong gradient of streamwise velocity, the streamwise velocity fluctuation is promoted first. The TKE is then transferred from the streamwise to the spanwise and vertical velocity fluctuations via the pressure-rate-of-strain tensor. Analogous to the quadrant analyses, the TKE production grows from a sharp peak (~0.1h width, where h is the building height) on the leeward side to a broad one (~0.5h width) on the windward side. This pattern is partly attributed to the growth of the flow instability and the enhanced turbulent processes along the roof of the street canyon in the streamwise direction. The pollutant removal mechanism is clearly illustrated by the budget analysis of the pollutant concentration. The pollutant is carried by the primary recirculation from the ground level to the roof level of the street canyon. The vertical turbulent pollutant flux dominates the pollutant removal in the region right below the roof level (0.8hpollutant removal in the shear layer (hpollutant is initially removed vertically from the street canyon to the shear layer by turbulence before being carried away by the prevalent wind. Moreover, the roof-level flow instability was found to play a major role so a more efficient pollutant removal was observed on the windward side.

Photoproduction of hydrogen peroxide in aqueous solution from model compounds for chromophoric dissolved organic matter (CDOM)

International Nuclear Information System (INIS)

Clark, Catherine D.; Bruyn, Warren de; Jones, Joshua G.

2014-01-01

Highlights: • CDOM produces hydrogen peroxide in sunlit surface waters. • Quinone moieties have been proposed as the photo-active chromophore in CDOM. • Hydrogen peroxide is produced in irradiated aqueous quinone solutions. • Concentrations and production rates are comparable to humic and fulvic acids. • Optical properties post-irradiation were similar to CDOM. - Abstract: To explore whether quinone moieties are important in chromophoric dissolved organic matter (CDOM) photochemistry in natural waters, hydrogen peroxide (H 2 O 2 ) production and associated optical property changes were measured in aqueous solutions irradiated with a Xenon lamp for CDOM model compounds (dihydroquinone, benzoquinone, anthraquinone, napthoquinone, ubiquinone, humic acid HA, fulvic acid FA). All compounds produced H 2 O 2 with concentrations ranging from 15 to 500 μM. Production rates were higher for HA vs. FA (1.32 vs. 0.176 mM h −1 ); values ranged from 6.99 to 0.137 mM h −1 for quinones. Apparent quantum yields (Θ app ; measure of photochemical production efficiency) were higher for HA vs. FA (0.113 vs. 0.016) and ranged from 0.0018 to 0.083 for quinones. Dihydroquinone, the reduced form of benzoquinone, had a higher production rate and efficiency than its oxidized form. Post-irradiation, quinone compounds had absorption spectra similar to HA and FA and 3D-excitation–emission matrix fluorescence spectra (EEMs) with fluorescent peaks in regions associated with CDOM

Predicting nitrogen and acidity effects on long-term dynamics of dissolved organic matter

International Nuclear Information System (INIS)

Rowe, E.C.; Tipping, E.; Posch, M.; Oulehle, F.; Cooper, D.M.; Jones, T.G.; Burden, A.; Hall, J.; Evans, C.D.

2014-01-01

Increases in dissolved organic carbon (DOC) fluxes may relate to changes in sulphur and nitrogen pollution. We integrated existing models of vegetation growth and soil organic matter turnover, acid–base dynamics, and organic matter mobility, to form the ‘MADOC’ model. After calibrating parameters governing interactions between pH and DOC dissolution using control treatments on two field experiments, MADOC reproduced responses of pH and DOC to additions of acidifying and alkalising solutions. Long-term trends in a range of acid waters were also reproduced. The model suggests that the sustained nature of observed DOC increases can best be explained by a continuously replenishing potentially-dissolved carbon pool, rather than dissolution of a large accumulated store. The simulations informed the development of hypotheses that: DOC increase is related to plant productivity increase as well as to pH change; DOC increases due to nitrogen pollution will become evident, and be sustained, after soil pH has stabilised. -- Highlights: • A model of dissolved organic carbon (DOC) was developed by integrating simple models • MADOC simulates effects of sulphur and nitrogen deposition and interactions with pH. • Responses of DOC and pH to experimental acidification and alkalisation were reproduced. • The persistence of DOC increases will depend on continued supply of potential DOC. • DOC fluxes are likely determined by plant productivity as well as soil solution pH. -- Effects of changes in sulphur and nitrogen pollution on dissolved organic carbon fluxes are predicted by simulating soil organic matter cycling, the release of potentially-dissolved carbon, and interactions with soil pH

Evaluation of turbulence from traffic using experimental data obtained in a street canyon

Energy Technology Data Exchange (ETDEWEB)

Mazzeo, N.A.; Venegas, L.E. [Univ. of Buenos Aires, Buenos Aires (Argentina). Dept. of Atmospheric and Oceanic Sciences, National Scientific and Technological Research Council

2004-07-01

High air pollution levels have been observed in street canyons. Within these streets, pedestrians, cyclists, drivers and residents are likely to be exposed to pollutant concentrations exceeding current air quality standards. Airflow and dispersion in street canyons are very complicated. Depending on the synoptic wind three main dispersion conditions can be identified: a) low wind conditions, b) perpendicular or near perpendicular flow for winds over 1.5-2.0 m/s blowing at an angle of more than 30 to the canyon axes, c) parallel or near parallel flow for winds over 1.5-2.0 m/s blowing from all other directions. Under condition b), airflow in canyons with H/W{approx}1 (H is the height and W is the width of the canyon) is characterised by the formation of a single vortex within the canyon. The dispersion of gaseous pollutants in a street canyon depends generally on the rate at which the street exchanges air vertically with the above roof-level atmosphere and laterally with connecting streets. There is evidence that when the synoptic wind speed is low, the mechanical traffic-produced turbulence (TPT) might place a significant role in dispersion of traffic-generated pollutants. In this paper, we analyse interactions between wind and traffic induced dispersive air motions. Data from full-scale measurements in Goettinger Strasse (Hannover, Germany) are used for application of parameterisation proposed by Di Sabatino, S. et al. (2003) and Kastner-Klein, P. et al. (2003). (orig.)

Selection of dissolution process for spent fuels and preparation of corrosion test solution simulated to dissolver (contract research)

International Nuclear Information System (INIS)

Motooka, Takafumi; Terakado, Shogo; Koya, Toshio; Hamada, Shozo; Kiuchi, Kiyoshi

2001-03-01

In order to evaluate the reliability of reprocessing equipment materials used in the Rokkasho Reprocessing Plant, we have proceeded a mock-up test and laboratory tests for getting corrosion parameters. In a dissolver made of zirconium, the simulation of test solutions to the practical solution which includes the high concentration of radioactive elements such as FP and TRU is one of the important issues with respect to the life prediction. On this experiment, the dissolution process of spent fuels and the preparation of test solution for evaluating the corrosion resistance of dissolver materials were selected. These processes were tested in the No.3 cell of WASTEF. The test solution for corrosion tests was prepared by adjusting the uranium and nitric acid concentrations. (author)

Tectonic activity and the evolution of submarine canyons: The Cook Strait Canyon system, New Zealand

Science.gov (United States)

Micallef, Aaron; Mountjoy, Joshu; Barnes, Philip; Canals, Miquel; Lastras, Galderic

2016-04-01

Submarine canyons are Earth's most dramatic erosional features, comprising steep-walled valleys that originate in the continental shelf and slope. They play a key role in the evolution of continental margins by transferring sediments into deep water settings and are considered important biodiversity hotspots, pathways for nutrients and pollutants, and analogues of hydrocarbon reservoirs. Although comprising only one third of continental margins worldwide, active margins host more than half of global submarine canyons. We still lack of thorough understanding of the coupling between active tectonics and submarine canyon processes, which is necessary to improve the modelling of canyon evolution in active margins and derive tectonic information from canyon morphology. The objectives of this study are to: (i) understand how tectonic activity influences submarine canyon morphology, processes, and evolution in an active margin, and (2) formulate a generalised model of canyon development in response to tectonic forcing based on morphometric parameters. We fulfil these objectives by analysing high resolution geophysical data and imagery from Cook Strait Canyon system, offshore New Zealand. Using these data, we demonstrate that tectonic activity, in the form of major faults and structurally-generated tectonic ridges, leaves a clear topographic signature on submarine canyon location and morphology, in particular their dendritic and sinuous planform shapes, steep and linear longitudinal profiles, and cross-sectional asymmetry and width. We also report breaks/changes in canyon longitudinal slope gradient, relief and slope-area regression models at the intersection with faults. Tectonic activity gives rise to two types of knickpoints in the Cook Strait Canyon. The first type consists of low slope gradient, rounded and diffusive knickpoints forming as a result of short wavelength folds or fault break outs and being restored to an equilibrium profile by upstream erosion and

Fluid mechanical dispersion of airborne pollutants inside urban street canyons subjecting to multi-component ventilation and unstable thermal stratifications.

Science.gov (United States)

Mei, Shuo-Jun; Liu, Cheng-Wei; Liu, Di; Zhao, Fu-Yun; Wang, Han-Qing; Li, Xiao-Hong

2016-09-15

The pedestrian level pollutant transport in street canyons with multiple aspect ratios (H/W) is numerically investigated in the present work, regarding of various unstable thermal stratification scenarios and plain surrounding. Non-isothermal turbulent wind flow, temperature field and pollutant spread within and above the street canyons are solved by the realizable k-ε turbulence model along with the enhanced wall treatment. One-vortex flow regime is observed for shallow canyons with H/W=0.5, whereas multi-vortex flow regime is observed for deep canyons with H/W=2.0. Both one-vortex and multi-vortex regimes could be observed for the street canyons with H/W=1.0, where the secondary vortex could be initiated by the flow separation and intensified by unstable thermal stratification. Air exchange rate (AER) and pollutant retention time are adopted to respectively evaluate the street canyon ventilation and pollutant removal performance. A second-order polynomial functional relationship is established between AER and Richardson number (Ri). Similar functional relationship could be established between retention time and Ri, and it is only valid for canyons with one-vortex flow regime. In addition, retention time could be prolonged abruptly for canyons with multi-vortex flow regime. Very weak secondary vortex is presented at the ground level of deep canyons with mild stratification, where pollutants are highly accumulated. However, with the decrease of Ri, pollutant concentration adjacent to the ground reduces accordingly. Present research could be applied to guide the urban design and city planning for enhancing pedestrian environment. Copyright © 2016 Elsevier B.V. All rights reserved.

pH-Dependent dissolving nano- and microparticles for improved peroral delivery of a highly lipophilic compound in dogs.

Science.gov (United States)

De Jaeghere, F; Allémann, E; Cerny, R; Galli, B; Steulet, A F; Müller, I; Schütz, H; Doelker, E; Gurny, R

2001-01-01

RR01, a new highly lipophilic drug showing extremely low water solubility and poor oral bioavailability, has been incorporated into pH-dependent dissolving particles made of a poly(methacrylic acid-co-ethylacrylate) copolymer. The physicochemical properties of the particles were determined using laser-light-scattering techniques, scanning electron microscopy, high-performance liquid chromatography, and x-ray powder diffraction. Suspension of the free drug in a solution of hydroxypropylcellulose (reference formulation) and aqueous dispersions of pH-sensitive RR01-loaded nanoparticles or microparticles were administered orally to Beagle dogs according to a 2-block Latin square design (n = 6). Plasma samples were obtained over the course of 48 hours and analyzed by gas chromatography/mass spectrometry. The administration of the reference formulation resulted in a particularly high interindividual variability of pharmacokinetic parameters, with low exposure to compound RR01 (AUC0-48h of 6.5 microg x h/mL and coefficient of variation (CV) of 116%) and much higher Tmax, as compared to both pH-sensitive formulations. With respect to exposure and interindividual variability, nanoparticles were superior to microparticles (AUC0-48h of 27.1 microg x h/mL versus 17.7 microg x h/mL with CV of 19% and 40%, respectively), indicating that the particle size may play an important role in the absorption of compound RR01. The performance of pH-sensitive particles is attributed to their ability to release the drug selectively in the upper part of the intestine in a molecular or amorphous form. In conclusion, pH-dependent dissolving particles have a great potential as oral delivery systems for drugs with low water solubility and acceptable permeation properties.

Geomorphic process fingerprints in submarine canyons

Science.gov (United States)

Brothers, Daniel S.; ten Brink, Uri S.; Andrews, Brian D.; Chaytor, Jason D.; Twichell, David C.

2013-01-01

Submarine canyons are common features of continental margins worldwide. They are conduits that funnel vast quantities of sediment from the continents to the deep sea. Though it is known that submarine canyons form primarily from erosion induced by submarine sediment flows, we currently lack quantitative, empirically based expressions that describe the morphology of submarine canyon networks. Multibeam bathymetry data along the entire passive US Atlantic margin (USAM) and along the active central California margin near Monterey Bay provide an opportunity to examine the fine-scale morphology of 171 slope-sourced canyons. Log–log regression analyses of canyon thalweg gradient (S) versus up-canyon catchment area (A) are used to examine linkages between morphological domains and the generation and evolution of submarine sediment flows. For example, canyon reaches of the upper continental slope are characterized by steep, linear and/or convex longitudinal profiles, whereas reaches farther down canyon have distinctly concave longitudinal profiles. The transition between these geomorphic domains is inferred to represent the downslope transformation of debris flows into erosive, canyon-flushing turbidity flows. Over geologic timescales this process appears to leave behind a predictable geomorphic fingerprint that is dependent on the catchment area of the canyon head. Catchment area, in turn, may be a proxy for the volume of sediment released during geomorphically significant failures along the upper continental slope. Focused studies of slope-sourced submarine canyons may provide new insights into the relationships between fine-scale canyon morphology and down-canyon changes in sediment flow dynamics.

Impacts of shape and height of upstream roof on airflow and pollutant dispersion inside an urban street canyon.

Science.gov (United States)

Huang, Yuan-Dong; He, Wen-Rong; Kim, Chang-Nyung

2015-02-01

A two-dimensional numerical model for simulating flow and pollutant dispersion in an urban street canyon is firstly developed using the FLUENT code and then validated against the wind tunnel results. After this, the flow field and pollutant dispersion inside an urban street canyon with aspect ratio W/H = 1 are examined numerically considering five different shapes (vaulted, trapezoidal, slanted, upward wedged, and downward wedged roofs) as well as three different roof height to building height ratios (Z H /H = 1/6, 1/3, and 1/2) for the upstream building roof. The results obtained reveal that the shape and height of an upstream roof have significant influences on flow pattern and pollutant distribution in an urban canyon. A large single clockwise vortex is generated in the canyon for the vaulted upstream roof at Z H /H = 1/6, 1/3, and 1/2, the trapezoidal and downward wedged roofs at Z H /H = 1/6 and 1/3, and the slanted and upward wedged roofs at Z H /H = 1/6, while a main clockwise vortex and a secondary counterclockwise vortex are established for the trapezoidal and downward wedged roofs at Z H /H = 1/2 and the slanted and upward wedged roofs at Z H /H = 1/3 and 1/2. In the one-vortex flow regime, the clockwise vortex moves upward and grows in size with increasing upstream roof height for the vaulted, trapezoidal, and downward wedged roofs. In the two-vortex flow regime, the size and rotational velocity of both upper clockwise and lower counterclockwise vortices increase with the upstream roof height for the slanted and upward wedged roofs. At Z H /H = 1/6, the pollution levels in the canyon are close among all the upstream roof shapes studied. At Z H /H = 1/3, the pollution levels in the canyon for the upward wedged roof and slanted roof are much higher than those for the vaulted, trapezoidal, and downward wedged roofs. At Z H /H = 1/2, the lowest pollution level appears in the canyon for the vaulted upstream roof, while

Photoproduction of hydrogen peroxide in aqueous solution from model compounds for chromophoric dissolved organic matter (CDOM).

Science.gov (United States)

Clark, Catherine D; de Bruyn, Warren; Jones, Joshua G

2014-02-15

To explore whether quinone moieties are important in chromophoric dissolved organic matter (CDOM) photochemistry in natural waters, hydrogen peroxide (H2O2) production and associated optical property changes were measured in aqueous solutions irradiated with a Xenon lamp for CDOM model compounds (dihydroquinone, benzoquinone, anthraquinone, napthoquinone, ubiquinone, humic acid HA, fulvic acid FA). All compounds produced H2O2 with concentrations ranging from 15 to 500 μM. Production rates were higher for HA vs. FA (1.32 vs. 0.176 mM h(-1)); values ranged from 6.99 to 0.137 mM h(-1) for quinones. Apparent quantum yields (Θ app; measure of photochemical production efficiency) were higher for HA vs. FA (0.113 vs. 0.016) and ranged from 0.0018 to 0.083 for quinones. Dihydroquinone, the reduced form of benzoquinone, had a higher production rate and efficiency than its oxidized form. Post-irradiation, quinone compounds had absorption spectra similar to HA and FA and 3D-excitation-emission matrix fluorescence spectra (EEMs) with fluorescent peaks in regions associated with CDOM. Copyright © 2014 Elsevier Ltd. All rights reserved.

[Effects of nitrogen deposition on the concentration and spectral characteristics of dissolved organic matter in soil solution in a young Cunninghamia lanceolata plantation.

Science.gov (United States)

Yuan, Xiao Chun; Chen, Yue Min; Yuan, Shuo; Zheng, Wei; Si, You Tao; Yuan, Zhi Peng; Lin, Wei Sheng; Yang, Yu Sheng

2017-01-01

To study the effects of nitrogen deposition on the concentration and spectral characteristics of dissolved organic matter (DOM) in the forest soil solution from the subtropical Cunninghamia lanceolata plantation, using negative pressure sampling method, the dynamics of DOM in soil solutions from 0-15 and 15-30 cm soil layer was monitored for two years and the spectroscopic features of DOM were analyzed. The results showed that nitrogen deposition significantly reduced the concentration of dissolved organic carbon (DOC), and increased the aromatic index (AI) and the humic index (HIX), but had no significant effect on dissolved organic nitrogen (DON) concentration in both soil layers. There was obvious seasonal variation in DOM concentration of the soil solution, which was prominently higher in summer and autumn than in spring and winter.Fourier-transform infrared (FTIR) absorption spectrometry indicated that the DOM in forest soil solution had absorption peaks in the similar position of six regions, being the highest in wave number of 1145-1149 cm -1 . Three-dimensional fluorescence spectra indicated that DOM was mainly consisted of protein-like substances (Ex/Em=230 nm/300 nm) and microbial degradation products (Ex/Em=275 nm/300 nm). The availability of protein-like substances from 0-15 cm soil layer was reduced in the nitrogen treatments. Nitrogen deposition significantly reduced the concentration of DOC in soil solution, maybe largely by reducing soil pH, inhibiting soil carbon mineralization and stimulating plant growth. In particular, the decline of DOC concentration in the surface layer was due to the production inhibition of the protein-like substances and carboxylic acids. Short-term nitrogen deposition might be beneficial to the maintenance of soil fertility, while the long-term accumulation of nitrogen deposition might lead to the hard utilization of soil nutrients.

Flow in bedrock canyons.

Science.gov (United States)

Venditti, Jeremy G; Rennie, Colin D; Bomhof, James; Bradley, Ryan W; Little, Malcolm; Church, Michael

2014-09-25

Bedrock erosion in rivers sets the pace of landscape evolution, influences the evolution of orogens and determines the size, shape and relief of mountains. A variety of models link fluid flow and sediment transport processes to bedrock incision in canyons. The model components that represent sediment transport processes are increasingly well developed. In contrast, the model components being used to represent fluid flow are largely untested because there are no observations of the flow structure in bedrock canyons. Here we present a 524-kilometre, continuous centreline, acoustic Doppler current profiler survey of the Fraser Canyon in western Canada, which includes 42 individual bedrock canyons. Our observations of three-dimensional flow structure reveal that, as water enters the canyons, a high-velocity core follows the bed surface, causing a velocity inversion (high velocities near the bed and low velocities at the surface). The plunging water then upwells along the canyon walls, resulting in counter-rotating, along-stream coherent flow structures that diverge near the bed. The resulting flow structure promotes deep scour in the bedrock channel floor and undercutting of the canyon walls. This provides a mechanism for channel widening and ensures that the base of the walls is swept clear of the debris that is often deposited there, keeping the walls nearly vertical. These observations reveal that the flow structure in bedrock canyons is more complex than assumed in the models presently used. Fluid flow models that capture the essence of the three-dimensional flow field, using simple phenomenological rules that are computationally tractable, are required to capture the dynamic coupling between flow, bedrock erosion and solid-Earth dynamics.

2010 Pacific Gas and Electric Diablo Canyon Power Plant (DCPP): Diablo Canyon, CA Central Coast

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The Diablo Canyon Power Plant (DCPP) LiDAR and Imagery datasets are comprised of three separate LiDAR surveys: Diablo Canyon (2010), Diablo Canyon (2010), and San...

The effects of salinity, pH, and dissolved organic matter on acute copper toxicity to the rotifer, Brachionus plicatilis ("L" strain).

Science.gov (United States)

Arnold, W R; Diamond, R L; Smith, D S

2010-08-01

This paper presents data from original research for use in the development of a marine biotic ligand model and, ultimately, copper criteria for the protection of estuarine and marine organisms and their uses. Ten 48-h static acute (unfed) copper toxicity tests using the euryhaline rotifer Brachionus plicatilis ("L" strain) were performed to assess the effects of salinity, pH, and dissolved organic matter (measured as dissolved organic carbon; DOC) on median lethal dissolved copper concentrations (LC50). Reconstituted and natural saltwater samples were tested at seven salinities (6, 11, 13, 15, 20, 24, and 29 g/L), over a pH range of 6.8-8.6 and a range of dissolved organic carbon of <0.5-4.1 mg C/L. Water chemistry analyses (alkalinity, calcium, chloride, DOC, hardness, magnesium, potassium, sodium, salinity, and temperature) are presented for input parameters to the biotic ligand model. In stepwise multiple regression analysis of experimental results where salinity, pH, and DOC concentrations varied, copper toxicity was significantly related only to the dissolved organic matter content (pH and salinity not statistically retained; alpha=0.05). The relationship of the 48-h dissolved copper LC50 values and dissolved organic carbon concentrations was LC50 (microg Cu/L)=27.1xDOC (mg C/L)1.25; r2=0.94.

Surface Complexation Modeling of Fluoride Adsorption by Soil and the Role of Dissolved Aluminum on Adsorption

Science.gov (United States)

Padhi, S.; Tokunaga, T.

2017-12-01

Adsorption of fluoride (F) on soil can control the mobility of F and subsequent contamination of groundwater. Hence, accurate evaluation of adsorption equilibrium is a prerequisite for understanding transport and fate of F in the subsurface. While there have been studies for the adsorption behavior of F with respect to single mineral constituents based on surface complexation models (SCM), F adsorption to natural soil in the presence of complexing agents needs much investigation. We evaluated the adsorption processes of F on a natural granitic soil from Tsukuba, Japan, as a function of initial F concentration, ionic strength, and initial pH. A SCM was developed to model F adsorption behavior. Four possible surface complexation reactions were postulated with and without including dissolved aluminum (Al) and Al-F complex sorption. Decrease in F adsorption with the increase in initial pH was observed in between the initial pH range of 4 to 9, and a decrease in the rate of the reduction of adsorbed F with respect to the increase in the initial pH was observed in the initial pH range of 5 to 7. Ionic strength variation in the range of 0 to 100mM had insignificant effect on F removal. Changes in solution pH were observed by comparing the solution before and after F adsorption experiments. At acidic pH, the solution pH increased, whereas at alkaline pH, the solution pH decreased after equilibrium. The SCM including dissolved Al and the adsorption of Al-F complex can simulate the experimental results quite successfully. Also, including dissolved Al and the adsorption of Al-F complex to the model explained the change in solution pH after F adsorption.

pH : a key control of the nature and distribution of dissolved organic matter and associated trace metals in soil

Science.gov (United States)

Pédrot, M.; Dia, A.; Davranche, M.

2009-04-01

Dissolved organic matter is ubiquitous at the Earth's surface and plays a prominent role in controlling metal speciation and mobility from soils to hydrosystems. Humic substances (HS) are usually considered to be the most reactive fraction of organic matter. Humic substances are relatively small and formed by chemically diverse organic molecules, bearing different functional groups that act as binding sites for cations and mineral surfaces. Among the different environmental physicochemical parameters controlling the metal speciation, pH is likely to be the most important one. Indeed, pH affect the dissociation of functional groups, and thus can influence the HS structure, their ability to complex metals, their solubility degree allowing the formation of aggregates at the mineral surface. In this context, soil/water interactions conducted through batch system experiments, were carried out with a wetland organic-rich soil to investigate the effect of pH on the release of dissolved organic carbon (DOC) and associated trace elements. The pH was regulated between 4 and 7.5 using an automatic pH stat titrator. Ultrafiltration experiments were performed to separate the dissolved organic pool following decreasing pore sizes (30 kDa, 5 kDa and 2 kDa with 1 Da = 1 g.mol-1). The pH increase induced a significant DOC release, especially in heavy organic molecules (size >5 kDa) with a high aromaticity (>30 %). These were probably humic acids (HA). This HA release influenced (i) directly the trace element concentrations in soil solution since HA were enriched in several trace elements such as Th, REE, Y, U, Cr and Cu; and (ii) indirectly by the breaking of clay-humic complexes releasing Fe- and Al-rich nanoparticles associated with V, Pb and Ti. By contrast, at acid pH, most HS were complexed onto mineral surfaces. They also sequestered iron nanoparticles. Therefore, at low pH, most part of DOC molecules had a size pH and ionic strength .The molecular size and shape of HS is

Carbon transport in Monterey Submarine Canyon

Science.gov (United States)

Barry, J.; Paull, C. K.; Xu, J. P.; Clare, M. A.; Gales, J. A.; Buck, K. R.; Lovera, C.; Gwiazda, R.; Maier, K. L.; McGann, M.; Parsons, D. R.; Simmons, S.; Rosenberger, K. J.; Talling, P. J.

2017-12-01

Submarine canyons are important conduits for sediment transport from continental margins to the abyss, but the rate, volume, and time scales of material transport have been measured only rarely. Using moorings with current meters, sediment traps (10 m above bottom) and optical backscatter sensors, we measured near-bottom currents, suspended sediment concentrations, and sediment properties at 1300 m depth in Monterey Canyon and at a non-canyon location on the continental slope at the same depth. Flow and water column backscatter were used to characterize "ambient" conditions when tidal currents dominated the flow field, and occasional "sediment transport events" when anomalously high down-canyon flow with sediment-laden waters arrived at the canyon mooring. The ambient sediment flux measured in sediment traps in Monterey Canyon was 350 times greater than measured at the non-canyon location. Although the organic carbon content of the canyon sediment flux during ambient periods was low (1.8 %C) compared to the slope location (4.9 %C), the ambient carbon transport in the canyon was 130 times greater than at the non-canyon site. Material fluxes during sediment transport events were difficult to measure owing to clogging of sediment traps, but minimal estimates indicate that mass transport during events exceeds ambient sediment fluxes through the canyon by nearly 3 orders of magnitude, while carbon transport is 380 times greater. Estimates of the instantaneous and cumulative flux of sediment and carbon from currents, backscatter, and sediment properties indicated that: 1) net flux is down-canyon, 2) flux is dominated by sediment transport events, and 3) organic carbon flux through 1300 m in Monterey Canyon was ca. 1500 MT C per year. The injection of 1500 MTCy-1 into the deep-sea represents ca. 260 km2 of the sediment C flux measured at the continental slope station (5.8 gCm-2y-1) and is sufficient to support a benthic community carbon demand of 5 gCm-2y-1 over 300 km2.

Experimental simulation of air quality in street canyon under changes of building orientation and aspect ratio.

Science.gov (United States)

Yassin, Mohamed F; Ohba, Masaake

2012-09-01

To assist validation of numerical simulations of urban pollution, air quality in a street canyon was investigated using a wind tunnel as a research tool under neutral atmospheric conditions. We used tracer gas techniques from a line source without buoyancy. Ethylene (C(2)H(4)) was used as the tracer gas. The street canyon model was formed of six parallel building rows of the same length. The flow and dispersion field was analyzed and measured using a hot-wire anemometer with split fiber probe and fast flame ionization detector. The diffusion flow field in the boundary layer within the street canyon was examined at different locations, with varying building orientations (θ=90°, 112.5°, 135° and 157.5°) and street canyon aspect ratios (W/H=1/2, 3/4 and 1) downwind of the leeward side of the street canyon model. Results show that velocity increases with aspect ratio, and with θ>90°. Pollutant concentration increases as aspect ratio decreases. This concentration decreases exponentially in the vertical direction, and decreases as θ increases from 90°. Measured pollutant concentration distributions indicate that variability of building orientation and aspect ratio in the street canyon are important for estimating air quality in the canyon. The data presented here can be used as a comprehensive database for validation of numerical models.

Method for separation of Cs from acid solution dissolving radionuclides and microanalysis of solution with ICP-AES

International Nuclear Information System (INIS)

Kanazawa, Toru; Hidaka, Akihide; Kudo, Tamotsu; Nakamura, Takehiko; Fuketa, Toyoshi

2004-06-01

The VEGA (Verification Experiments of radionuclides Gas/Aerosol release) program is being performed at JAERI to understand mechanisms of radionuclides release from irradiated fuel during severe accidents. As a part of evaluation in the program, the mass balances of released and deposited FP (Fission Products) onto the test apparatus are estimated from gamma ray measurement for acid solution leached from the apparatus, but short-life nuclides are difficult to be measured because those in the VEGA fuel have been mostly depleted due to cooling for several years. Moreover, the radionuclides without emitting gamma rays and very small quantity of elements cannot be quantified by gamma ray measurement. Therefore, a microanalysis by ICP-AES (Inductively Coupled Plasma - Atomic Emission Spectrometry) for the acid solution leached from VEGA apparatuses is being applied to evaluate the released and deposited masses for those elements. Since Cs-134 and -137, which are major FP dissolved in the solution, have high intensity of gamma ray spectrum, they have to be removed from the solution before the microanalysis in order to avoid contamination of ICP system and to decrease exposure to gamma ray. In this report, methods for separation of Cs from acid solution were reviewed and the applicability of them to the ICP-AES analysis was discussed. The method for Cs separation using the inorganic ion exchanger, AMP (Ammonium Molybdate Phosphate) was applied to the solutions of cold and hot test and the effectiveness was examined. The results showed that more than 99.9% of Cs could be removed from the test solutions, and once removed Sb by AMP was recovered by using a complexing agent such as citric acid. Next, the method was applied to an acid solution leached from VEGA-3 apparatus, and ICP-AES analysis was performed for it. The analysis showed that amount of U, Sr and Zr were successfully quantified. Most of elements to be analyzed were measurable except for Sb, Ag and Sn, although

Formative flow in bedrock canyons

Science.gov (United States)

Venditti, J. G.; Kwoll, E.; Rennie, C. D.; Church, M. A.

2017-12-01

In alluvial channels, it is widely accepted that river channel configuration is set by a formative flow that represents a balance between the magnitude and frequency of flood flows. The formative flow is often considered to be one that is just capable of filling a river channel to the top of its banks. Flows much above this formative flow are thought to cause substantial sediment transport and rearrange the channel morphology to accommodate the larger flow. This idea has recently been extended to semi-alluvial channels where it has been shown that even with bedrock exposed, the flows rarely exceed that required to entrain the local sediment cover. What constitutes a formative flow in a bedrock canyon is not clear. By definition, canyons have rock walls and are typically incised vertically, removing the possibility of the walls being overtopped, as can occur in an alluvial channel at high flows. Canyons are laterally constrained, have deep scour pools and often have width to maximum depth ratios approaching 1, an order of magnitude lower than alluvial channels. In many canyons, there are a sequence of irregularly spaced scour pools. The bed may have intermittent or seasonal sediment cover, but during flood flows the sediment bed is entrained leaving a bare bedrock channel. It has been suggested that canyons cut into weak, well-jointed rock may adjust their morphology to the threshold for block plucking because the rock bed is labile during exceptionally large magnitude flows. However, this hypothesis does not apply to canyons cut into massive crystalline rock where abrasion is the dominant erosion process. Here, we argue that bedrock canyon morphology is adjusted to a characteristic flow structure developed in bedrock canyons. We show that the deeply scoured canyon floor is adjusted to a velocity inversion that is present at low flows, but gets stronger at high flows. The effect is to increase boundary shear stresses along the scour pool that forms in constricted

Let's Bet on Sediments! Hudson Canyon Cruise--Grades 9-12. Focus: Sediments of Hudson Canyon.

Science.gov (United States)

National Oceanic and Atmospheric Administration (DOC), Rockville, MD.

These activities are designed to teach about the sediments of Hudson Canyon. Students investigate and analyze the patterns of sedimentation in the Hudson Canyon, observe how heavier particles sink faster than finer particles, and learn that submarine landslides are avalanches of sediment in deep ocean canyons. The activity provides learning…

Distributions of 14 elements on 60 selected absorbers from two simulant solutions (acid-dissolved sludge and alkaline supernate) for Hanford HLW Tank 102-SY

International Nuclear Information System (INIS)

Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

1993-10-01

Sixty commercially available or experimental absorber materials were evaluated for partitioning high-level radioactive waste. These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. The distributions of 14 elements onto each absorber were measured from simulated solutions that represent acid-dissolved sludge and alkaline supernate solutions from Hanford high-level waste (HLW) Tank 102-SY. The selected elements, which represent fission products (Ce, Cs, Sr, Tc, and Y); actinides (U, Pu, and Am); and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr), were traced by radionuclides and assayed by gamma spectrometry. Distribution coefficients for each of the 1680 element/absorber/solution combinations were measured for dynamic contact periods of 30 min, 2 h, and 6 h to provide sorption kinetics information for the specified elements from these complex media. More than 5000 measured distribution coefficients are tabulated

Transport and fluxes of terrestrial polycyclic aromatic hydrocarbons in a small mountain river and submarine canyon system.

Science.gov (United States)

Lin, Bing-Sian; Lee, Chon-Lin; Brimblecombe, Peter; Liu, James T

2016-08-01

Polycyclic aromatic hydrocarbon (PAH) concentrations in the Gaoping River were investigated in the wet and dry seasons. PAH characteristics allowed us to trace the particulate matter transported in a river-sea system containing a small mountain river, continental shelf, and submarine canyon. PAH signatures of the Gaoping River showed that particles were rapidly transported from the high mountain to the Gaoping coastal areas in the wet season, even arriving at the deep ocean via the Gaoping Submarine Canyon. By contrast, in the dry season, the particles were delivered quite slowly and included mostly pyrogenic contaminants. The annual riverine flux estimates for PAHs were 2241 kg in the Gaoping river-sea system. Only 18.0 kg were associated with the dissolved phase; the rest was bound onto particles. The fluxes caused by typhoons and their effects accounted for 20.2% of the dissolved and 68.4% of the particulate PAH fluxes from the river. Normalized partition coefficients for organic carbon suggested that PAHs were rigid on the particles. Distinct source characteristics were evident for PAHs on riverine suspended particles and coastal surface sediments: the particles in the wet season (as background signals) were similar to petrogenic sources, whereas the particles in the dry season had characteristics of coal burning and vehicular emissions. The sediments in the northwestern shelf were similar to pyrogenic sources (including vehicular emissions and coal and biomass burning), whereas the sediments in the canyon and southeastern shelf arose from mixed sources, although some diesel signature was also evident. Copyright © 2016 Elsevier Ltd. All rights reserved.

Grand Canyon Monitoring and Research Center

Science.gov (United States)

Hamill, John F.

2009-01-01

The Grand Canyon of the Colorado River, one of the world's most spectacular gorges, is a premier U.S. National Park and a World Heritage Site. The canyon supports a diverse array of distinctive plants and animals and contains cultural resources significant to the region's Native Americans. About 15 miles upstream of Grand Canyon National Park sits Glen Canyon Dam, completed in 1963, which created Lake Powell. The dam provides hydroelectric power for 200 wholesale customers in six western States, but it has also altered the Colorado River's flow, temperature, and sediment-carrying capacity. Over time this has resulted in beach erosion, invasion and expansion of nonnative species, and losses of native fish. Public concern about the effects of Glen Canyon Dam operations prompted the passage of the Grand Canyon Protection Act of 1992, which directs the Secretary of the Interior to operate the dam 'to protect, mitigate adverse impacts to, and improve values for which Grand Canyon National Park and Glen Canyon National Recreation Area were established...' This legislation also required the creation of a long-term monitoring and research program to provide information that could inform decisions related to dam operations and protection of downstream resources.

Lightning protection for the process canyons at the Savannah River site

International Nuclear Information System (INIS)

McAfee, D.E.

1995-01-01

Westinghouse Savannah River Company (WSRC) has performed Lightning Studies for the existing Process Canyons at the Savannah River Site (SRS). These studies were initiated to verify the lightning protection systems for the facilities and to compare the installations to the National Fire Protection (NFPA) Standard 780, Lighting Protection Code, 1992. The original study of the F-Canyon was initiated to develop answers to concerns raised by the Defense Nuclear Facility Safety Board (DNFSB). Once this study was completed it was determined that a similar study for H-Canyon would be prudent; followed by an evaluation of the Defense Waste Processing Facility (DWPF) Vitrification Building (S-Canyon). This paper will provide an overview of the nature of lightning and the principals of lightning protection. This will provide the reader with a basic understanding of the phenomena of lighting and its potential for damaging structures, components, and injuring personnel in or near the structure

Resin bead-thermal ionization mass spectrometry for determination of plutonium concentration in irradiated fuel dissolver solution

International Nuclear Information System (INIS)

Paul, Sumana; Shah, R.V.; Aggarwal, S.K.; Pandey, A.K.

2015-01-01

Determination of isotopic composition (IC) and concentration of plutonium (Pu) is necessary at various stages of nuclear fuel cycle which involves analysis of complex matrices like dissolver solution of irradiated fuel, nuclear waste stream etc. Mass spectrometry, e.g. thermal ionization mass spectrometry (TIMS) and inductively coupled plasma mass spectrometry (ICP-MS) are commonly used for determination of IC and concentration of plutonium. However, to circumvent matrix interferences, efficient separation as well as preconcentration of Pu is required prior to mass spectrometric analysis. Purification steps employing ion-exchange resins are widely used for the separation of Pu from dissolver solution or from mixture of other actinides e.g. U, Am. However, an alternative way is to selectively preconcentrate Pu on a resin bead, followed by direct loading of the bead on the filament of thermal ionization mass spectrometer

Wintertime Boundary Layer Structure in the Grand Canyon.

Science.gov (United States)

Whiteman, C. David; Zhong, Shiyuan; Bian, Xindi

1999-08-01

Wintertime temperature profiles in the Grand Canyon exhibit a neutral to isothermal stratification during both daytime and nighttime, with only rare instances of actual temperature inversions. The canyon warms during daytime and cools during nighttime more or less uniformly through the canyon's entire depth. This weak stability and temperature structure evolution differ from other Rocky Mountain valleys, which develop strong nocturnal inversions and exhibit convective and stable boundary layers that grow upward from the valley floor. Mechanisms that may be responsible for the different behavior of the Grand Canyon are discussed, including the possibility that the canyon atmosphere is frequently mixed to near-neutral stratification when cold air drains into the top of the canyon from the nearby snow-covered Kaibab Plateau. Another feature of canyon temperature profiles is the sharp inversions that often form near the canyon rims. These are generally produced when warm air is advected over the canyon in advance of passing synoptic-scale ridges.Wintertime winds in the main canyon are not classical diurnal along-valley wind systems. Rather, they are driven along the canyon axis by the horizontal synoptic-scale pressure gradient that is superimposed along the canyon's axis by passing synoptic-scale weather disturbances. They may thus bring winds into the canyon from either end at any time of day.The implications of the observed canyon boundary layer structure for air pollution dispersion are discussed.

Contemporary sediment-transport processes in submarine canyons.

Science.gov (United States)

Puig, Pere; Palanques, Albert; Martín, Jacobo

2014-01-01

Submarine canyons are morphological incisions into continental margins that act as major conduits of sediment from shallow- to deep-sea regions. However, the exact mechanisms involved in sediment transfer within submarine canyons are still a subject of investigation. Several studies have provided direct information about contemporary sedimentary processes in submarine canyons that suggests different modes of transport and various triggering mechanisms. Storm-induced turbidity currents and enhanced off-shelf advection, hyperpycnal flows and failures of recently deposited fluvial sediments, dense shelf-water cascading, canyon-flank failures, and trawling-induced resuspension largely dominate present-day sediment transfer through canyons. Additionally, internal waves periodically resuspend ephemeral deposits within canyons and contribute to dispersing particles or retaining and accumulating them in specific regions. These transport processes commonly deposit sediments in the upper- and middle-canyon reaches for decades or centuries before being completely or partially flushed farther down-canyon by large sediment failures.

Compatibility of Polyvinyl Alcohol with the 241-F/H Tank Farm Liquid Waste

International Nuclear Information System (INIS)

Oji, L.N.

1998-01-01

This report describes results from laboratory-scale oxidative mineralization of polyvinyl alcohol (PVA), and the evaluation of the F/H Tank Farms as a storage/disposal option for PVA waste solution generated in the Canyons and B-line decontamination operations

Compatibility of Polyvinyl Alcohol with the 241-F/H Tank Farm Liquid Waste

Energy Technology Data Exchange (ETDEWEB)

Oji, L.N.

1998-11-25

This report describes results from laboratory-scale oxidative mineralization of polyvinyl alcohol (PVA), and the evaluation of the F/H Tank Farms as a storage/disposal option for PVA waste solution generated in the Canyons and B-line decontamination operations.

Formation and dissolution of zeolite during burial diagenesis - Examples from glauconitic sandstones in the Palaeogene Siri Canyon, Danish North Sea

DEFF Research Database (Denmark)

Kazerouni, Afsoon Moatari; Friis, Henrik; Svendsen, Johan B

or diagenetic alteration of volcanic glass. Authigenic zeolites are uncommon constituents in most sandstones. However, authigenic zeolites are common in some of the glauconitic sandstones from the Siri Canyon, where it is generally associated with thick coatings of opal/microquartz on the detrital framework...... reflecting dissolution of an early phase with different chemical composition. In many samples, zeolites have been totally dissolved, leaving impression marks in the opal/microquartz coating. The textural relation demonstrates that zeolite was dissolved after microquartz precipitation. In most case...

Removal of radium from aqueous sulphate solutions

International Nuclear Information System (INIS)

Weir, D.R.; Masters, J.T.; Neven, M.

1983-01-01

Radium is often present in ores and an aqueous solution associated with the ore may consequently contain dissolved radium. It is frequently necessary to remove radium from such solutions to reduce the total radium content to a prescribed low level before the solution can be returned to the environment. The present invention is based on the discovery that the total radium content can be reduced to a satisfactory level within a reasonable time by adding a soluble barium salt to a radium-containing sulphate solution which also contains dissolved magnesium at a pH not greater than about 0 to precipitate radium as barium radium sulphate, raising the pH to at least 11 to precipitate an insoluble magnesium compound which collects the barium radium sulphate precipitate, and separating substantially all of the precipitates from the solution

Street canyon aerosol pollutant transport measurements.

Science.gov (United States)

Longley, I D; Gallagher, M W; Dorsey, J R; Flynn, M; Bower, K N; Allan, J D

2004-12-01

Current understanding of dispersion in street canyons is largely derived from relatively simple dispersion models. Such models are increasingly used in planning and regulation capacities but are based upon a limited understanding of the transport of substances within a real canyon. In recent years, some efforts have been made to numerically model localised flow in idealised canyons (e.g., J. Appl. Meteorol. 38 (1999) 1576-89) and stepped canyons (Assimakopoulos V. Numerical modelling of dispersion of atmospheric pollution in and above urban canopies. PhD thesis, Imperial College, London, 2001) but field studies in real canyons are rare. To further such an understanding, a measurement campaign has been conducted in an asymmetric street canyon with busy one-way traffic in central Manchester in northern England. The eddy correlation method was used to determine fluxes of size-segregated accumulation mode aerosol. Measurements of aerosol at a static location were made concurrently with measurements on a platform lift giving vertical profiles. Size-segregated measurements of ultrafine and coarse particle concentrations were also made simultaneously at various heights. In addition, a small mobile system was used to make measurements of turbulence at various pavement locations within the canyon. From this data, various features of turbulent transport and dispersion in the canyon will be presented. The concentration and the ventilation fluxes of vehicle-related aerosol pollutants from the canyon will be related to controlling factors. The results will also be compared with citywide ventilation data from a separate measurement campaign conducted above the urban canopy.

Geohydrology of White Rock Canyon of the Rio Grande from Otowi to Frijoles Canyon

International Nuclear Information System (INIS)

Purtymun, W.D.; Peters, R.J.; Owens, J.W.

1980-12-01

Twenty-seven springs discharge from the Totavi Lentil and Tesuque Formation in White Rock Canyon. Water generally acquires its chemical characteristics from rock units that comprise the spring aquifer. Twenty-two of the springs are separated into three groups of similar aquifer-related chemical quality. The five remaining springs make up a fourth group with a chemical quality that differs due to localized conditions in the aquifer. Localized conditions may be related to recharge or discharge in or near basalt intrusion or through faults. Streams from Pajarito, Ancho, and Frijoles Canyons discharge into the Rio Grande in White Rock Canyon. The base flow in the streams is from springs. Sanitary effluent in Mortandad Canyon from the treatment plant at White Rock also reaches the Rio Grande

78 FR 48670 - Boulder Canyon Project

Science.gov (United States)

2013-08-09

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area... Canyon Project (BCP) electric service provided by the Western Area Power Administration (Western). The... INFORMATION: Hoover Dam, authorized by the Boulder Canyon Project Act (45 Stat. 1057, December 21, 1928), sits...

77 FR 48151 - Boulder Canyon Project

Science.gov (United States)

2012-08-13

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area... Canyon Project (BCP) electric service provided by the Western Area Power Administration (Western). The... INFORMATION: Hoover Dam, authorized by the Boulder Canyon Project Act (45 Stat. 1057, December 21, 1928), sits...

New York Canyon Stimulation

Energy Technology Data Exchange (ETDEWEB)

Raemy, Bernard

2012-06-21

The New York Canyon Stimulation Project was to demonstrate the commercial application of Enhanced Geothermal System techniques in Buena Vista Valley area of Pershing County, Nevada. From October 2009 to early 2012, TGP Development Company aggressively implemented Phase I of Pre-Stimulation and Site/Wellbore readiness. This included: geological studies; water studies and analyses and procurement of initial permits for drilling. Oversubscription of water rights and lack of water needed for implementation of EGS were identified and remained primary obstacles. Despite extended efforts to find alternative solutions, the water supply circumstances could not be overcome and led TGP to determine a "No Go" decision and initiate project termination in April 2012.

Recovery of uranium from sulphate solutions containing molybdenum

International Nuclear Information System (INIS)

Weir, D.R.; Genik-Sas-Berezowsky, R.M.

1983-01-01

A process for recovering uranium from a sulphate solution containing dissolved uranium and molybdenum includes reacting the solution with ammonia (pH 8 to 10), the pH of the original solution must not exceed 5.5 and after the addition of ammonia the pH must not be in the vicinity of 7 for a significant time. The resultant uranium precipitate is relatively uncontaminated by molybdenum. The precipitate is then separated from the remaining solution while the pH is maintained within the stated range

Durable terrestrial bedrock predicts submarine canyon formation

Science.gov (United States)

Smith, Elliot; Finnegan, Noah J.; Mueller, Erich R.; Best, Rebecca J.

2017-01-01

Though submarine canyons are first-order topographic features of Earth, the processes responsible for their occurrence remain poorly understood. Potentially analogous studies of terrestrial rivers show that the flux and caliber of transported bedload are significant controls on bedrock incision. Here we hypothesize that coarse sediment load could exert a similar role in the formation of submarine canyons. We conducted a comprehensive empirical analysis of canyon occurrence along the West Coast of the contiguous United States which indicates that submarine canyon occurrence is best predicted by the occurrence of durable crystalline bedrock in adjacent terrestrial catchments. Canyon occurrence is also predicted by the flux of bed sediment to shore from terrestrial streams. Surprisingly, no significant correlation was observed between canyon occurrence and the slope or width of the continental shelf. These findings suggest that canyon incision is promoted by greater yields of durable terrestrial clasts to the shore.

Algal and water-quality data for Rapid Creek and Canyon Lake near Rapid City, South Dakota, 2007

Science.gov (United States)

Hoogestraat, Galen K.; Putnam, Larry D.; Graham, Jennifer L.

2008-01-01

This report summarizes the results of algae and water-quality sampling on Rapid Creek and Canyon Lake during May and September 2007. The overall purpose of the study was to determine the algal community composition of Rapid Creek and Canyon Lake in relation to organisms that are known producers of unwanted tastes and odors in drinking-water supplies. Algal assemblage structure (phytoplankton and periphyton) was examined at 16 sites on Rapid Creek and Canyon Lake during May and September 2007, and actinomycetes bacteria were sampled at the Rapid City water treatment plant intake in May 2007, to determine if taste-and-odor producing organisms were present. During the May 2007 sampling, 3 Rapid Creek sites and 4 Canyon Lake sites were quantitatively sampled for phytoplankton in the water column, 7 Rapid Creek sites were quantitatively sampled for attached periphyton, and 4 lake and retention pond sites were qualitatively sampled for periphyton. Five Rapid Creek sites were sampled for geosmin and 2-methylisoborneol, two common taste-and-odor causing compounds known to affect water supplies. During the September 2007 sampling, 4 Rapid Creek sites were quantitatively sampled for attached periphyton, and 3 Canyon Lake sites were qualitatively sampled for periphyton. Water temperature, dissolved oxygen, pH, and specific conductance were measured during each sampling event. Methods of collection and sample analysis are presented for the various types of biological and chemical constituent samples. Diatoms comprised 91-100 percent of the total algal biovolume in periphyton samples collected during May and September. Cyanobacteria (also called blue-green algae) were detected in 7 of the 11 quantitative periphyton samples and ranged from 0.01 to 2.0 percent of the total biovolume. Cyanobacteria were present in 3 of the 7 phytoplankton samples collected in May, but the relative biovolumes were small (0.01-0.2 percent). Six of seven qualitative samples collected from Canyon Lake

A Study on the Oxidative-dissolution Leaching of Fission Product Oxides in the carbonate solution

International Nuclear Information System (INIS)

Lee, Eil Hee; Kim, Kwang Wook; Lim, Jae Gwan; Chung, Dong Yong; Yang, Han Beom; Joe, Kih Soo; Seo, Heui Seung; Kim, Yeon Hwa; Lee, Se Yoon

2009-07-01

This study was carried out to investigate the characteristics of an oxidativedissolution leaching of FP co-dissolved with U in a carbonate solution of Na 2 CO 3 - H 2 O 2 and (NH 4 ) 2 CO 3 -H 2 O 2 , respectively. Simulated FP-oxides which contained 12 components have been added to the solution to examine their oxidative dissolution characteristics. It was found that H 2 O 2 was an effective oxidant to minimize the dissolution of FP in a carbonate solution. In 0.5M Na 2 CO 3 -0.5M H 2 O 2 and 0.5M (NH 4 ) 2 CO 3 -0.5M H 2 O 2 solution, some elements such as Re, Te, Cs and Mo seem to be dissolved together with U. It is revealed that dissolution rates of Re, Te and Cs are high (completely dissolved within 10∼20 minutes) due to their high solubility in Na 2 CO 3 and (NH 4 ) 2 CO 3 solution regardless of the addition of H 2 O 2 , and independent of the concentrations of Na 2 CO 3 and H 2 O 2 . However, Mo was slowly dissolved by an oxidative dissolution with H 2 O 2 . It is found that the most important factor for the oxidative dissolution of FP is the pH of the solution and an effective oxidative dissolution is achieved at a pH between 10∼12 for Na 2 CO 3 and a pH between 9∼10 for (NH 4 ) 2 CO 3 , respectively, in order to minimize the dissolution of FP

Numerical study on the impact of ground heating and ambient wind speed on flow fields in street canyons

Science.gov (United States)

Li, Lei; Yang, Lin; Zhang, Li-Jie; Jiang, Yin

2012-11-01

The impact of ground heating on flow fields in street canyons under different ambient wind speed conditions was studied based on numerical methods. A series of numerical tests were performed, and three factors including height-to-width (H/W) ratio, ambient wind speed and ground heating intensity were taken into account. Three types of street canyon with H/W ratios of 0.5, 1.0 and 2.0, respectively, were used in the simulation and seven speed values ranging from 0.0 to 3.0 m s-1 were set for the ambient wind speed. The ground heating intensity, which was defined as the difference between the ground temperature and air temperature, ranged from 10 to 40 K with an increase of 10 K in the tests. The results showed that under calm conditions, ground heating could induce circulation with a wind speed of around 1.0 m s-1, which is enough to disperse pollutants in a street canyon. It was also found that an ambient wind speed threshold may exist for street canyons with a fixed H/W ratio. When ambient wind speed was lower than the threshold identified in this study, the impact of the thermal effect on the flow field was obvious, and there existed a multi-vortex flow pattern in the street canyon. When the ambient wind speed was higher than the threshold, the circulation pattern was basically determined by dynamic effects. The tests on the impact of heating intensity showed that a higher ground heating intensity could strengthen the vortical flow within the street canyon, which would help improve pollutant diffusion capability in street canyons.

Canyons off northwest Puerto Rico

International Nuclear Information System (INIS)

Gardner, W.D.; Glover, L.K.; Hollister, C.D.

1980-01-01

The Nuclear-Research Submarine NR-1 was used to study morphoplogy, sediment, and sediment-water interactions off the northwest coast of Puerto Rico. New detailed bathymetry from the surface-support ship, USS Portland, shows several submarine canyons in the area, some of them unreported previously. The north coast canyons, Arecibo, Tiberones and Quebradillas, are primarily erosional features although no recent turbidity-current evidence is seen. The canyons are presently filling with river-transported sediments. (orig./ME)

K Basin Sludge Conditioning Process Testing Partitioning of PCBs in Dissolver Solution After Neutralization/Precipitation (Caustic Adjustment)

International Nuclear Information System (INIS)

Schmidt, A.J.; Thornton, B.M.; Hoppe, E.W.; Mong, G.M.; Silvers, K.L.; Slate, S.O.

1999-01-01

The purpose of the work described in this report was to gain a better understanding of how PCB congeners present in a simulated K Basin sludge dissolver solution will partition upon neutralization and precipitation (i.e., caustic adjustment). In a previous study (Mong et al. 1998),the entire series of sludge conditioning steps (acid dissolution, filtration, and caustic adjustment) were examined during integrated testing. In the work described here, the caustic adjustment step was isolated to examine the fate of PCBs in more detail within this processing step. For this testing, solutions of dissolver simulant (containing no solids) with a known initial concentration of PCB congeners were neutralized with caustic to generate a clarified supernatant and a settled sludge phase. PCBs were quantified in each phase (including the PCBs associated with the test vessel rinsates), and material balance information was collected

Contribution of solution pH and buffer capacity to suppress intergranular stress corrosion cracking of sensitized type 304 stainless steel at 95 C

International Nuclear Information System (INIS)

Zhang, S.; Shibata, T.; Haruna, T.

1999-01-01

Controlling pH of high-temperature water to ∼pH 7 at 300 C by adding lithium hydroxide (LiOH) into the coolant system of a pressurized water reactor (PWR) successfully has been mitigating the corrosion of PWR component materials. The effects of solution pH and buffer capacity on intergranular stress corrosion cracking (IGSCC) of sensitized type 304 stainless steel ([SS] UNS S30400) was examined at 95 C by slow strain rate technique (SSRT) with an in-situ cracking observation system. It was found that an increase in solution pH or buffer capacity increased crack initiation time and decreased mean crack initiation frequency, but exerted almost no effect on crack propagation. This inhibition effect on IGSCC initiation was explained as resulting from a retarding effect of solution pH and buffer capacity on the decrease in pH at crack nuclei caused by the hydrolysis of metal ions dissolved when the passive film was ruptured by strain in SSRT

Removal of actinides from dissolved ORNL MVST sludge using the TRUEX process

International Nuclear Information System (INIS)

Spencer, B.B.; Egan, B.Z.; Chase, C.W.

1997-07-01

Experiments were conducted to evaluate the transuranium extraction process for partitioning actinides from actual dissolved high-level radioactive waste sludge. All tests were performed at ambient temperature. Time and budget constraints permitted only two experimental campaigns. Samples of sludge from Melton Valley Storage Tank W-25 were rinsed with mild caustic (0.2 M NaOH) to reduce the concentrations of nitrates and fission products associated with the interstitial liquid. In one campaign, the rinsed sludge was dissolved in nitric acid to produce a solution containing total metal concentrations of ca. 1.8 M with a nitric acid concentration of ca. 2.9 M. About 50% of the dry mass of the sludge was dissolved. In the other campaign, the sludge was neutralized with nitric acid to destroy the carbonates, then leached with ca. 2.6 M NaOH for ca. 6 h before rinsing with the mild caustic. The sludge was then dissolved in nitric acid to produce a solution containing total metal concentrations of ca. 0.6 M with a nitric acid concentration of ca. 1.7 M. About 80% of the sludge dissolved. The dissolved sludge solution form the first campaign began gelling immediately, and a visible gel layer was observed after 8 days. In the second campaign, the solution became hazy after ca. 8 days, indicating gel formation, but did not display separated gel layers after aging for 20 days. Batch liquid-liquid equilibrium tests of both the extraction and stripping operations were conducted. Chemical analyses of both phases were used to evaluate the process. Evaluation was based on two metrics: the fraction of TRU elements removed from the dissolved sludge and comparison of the results with predictions made with the Generic TRUEX Model (GTM). The fractions of Eu, Pu, Cm, Th, and U species removed from aqueous solution in only one extraction stage were > 95% and were close to the values predicted by the GTM. Mercury was also found to be strongly extracted, with a one-stage removal of > 92%

Distributions of 14 elements on 63 absorbers from three simulant solutions (acid-dissolved sludge, acidified supernate, and alkaline supernate) for Hanford HLW Tank 102-SY

International Nuclear Information System (INIS)

Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

1994-08-01

As part of the Hanford Tank Waste Remediation System program at Los Alamos, we evaluated 63 commercially available or experimental absorber materials for their ability to remove hazardous components from high-level waste (HLW). These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. We tested these absorbers with three solutions prepared to simulate acid-dissolved sludge (pH 0.6), acidified supernate (pH 3.5), and alkaline supernate (pH 13.9) from underground storage tank 102-SY at the Hanford Reservation near Richland, Washington. To these simulants we added the appropriate radionuclides and used gamma spectrometry to measure fission products (Ce, Cs, Sr, Tc, and Y), actinides (U, Pu, and Am), and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr). For each of more than 2500 element/absorber/solution combinations, we measured distribution coefficients for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. Because we measured the sorption of many different elements, the tabulated results indicate those elements most likely to interfere with the sorption of elements of greater interest. On the basis of nearly 7500 measured distribution coefficients, we determined that many of these absorbers appear suitable for processing HLW. This study supersedes the previous version of LA-12654, in which results attributed to a solution identified as an alkaline supernate simulant were misleading because that solution contained insufficient hydroxide

Quasi-three-dimensional analysis of ground water flow and dissolved multicomponent solute transport in saturated porous media

International Nuclear Information System (INIS)

Tang, Yi.

1991-01-01

A computational procedure was developed in this study to provide flexibility needed in the application of three-dimensional groundwater flow and dissolved multicomponent solute transport simulations. In the first part of this study, analytical solutions were proposed for the dissolved single-component solute transport problem. These closed form solutions were developed for homogeneous but stratified porous media. This analytical model took into account two-dimensional diffusion-advection in the main aquifer layer and one-dimensional diffusion-advection in the adjacent aquitards, as well as first order radioactive decay and linear adsorption isotherm in both aquifer and aquitards. The associated analytical solutions for solute concentration distributions in the aquifer and aquitards were obtained using Laplace Transformation and Method of Separation of Variables techniques. Next, in order to analyze the problem numerically, a quasi-three-dimensional finite element algorithm was developed based on the multilayer aquifer concept. In this phase, advection, dispersion, adsorption and first order multi-species chemical reaction terms were included to the analysis. Employing this model, without restriction on groundwater flow pattern in the multilayer aquifer system, one may analyze the complex behavior of the groundwater flow and solute movement pattern in the system. These numerical models may be utilized as calibration tools in site characterization studies, or as predictive models during the initial stages of a typical site investigation study. Through application to several test and field problems, the usefulness, accuracy and efficiency of the proposed models were demonstrated. Comparison of results with analytical solution, experimental data and other numerical methods were also discussed

Aerial radiological survey of the Diablo Canyon Nuclear Power Plant and surrounding area, Diablo Canyon, California. Date of survey: September-October 1984

International Nuclear Information System (INIS)

1985-03-01

An aerial radiological survey was conducted over the area surrounding the Diablo Canyon Nuclear Power Plant in Diablo Canyon, California. The survey was conducted between 20 September and 3 October 1984. A series of flight lines parallel to the coastline were flown at an altitude of 91 meters (300 feet) and were spaced 152 meters (500 feet) apart. The survey covered an area of 250 square kilometers (100 square miles). The resulting background exposure rates over the survey area ranged from 5 to 21 microroentgens per hour (μR/h). The reported exposure rate values include an estimated cosmics ray contribution of 3.6 μR/h. Soil samples were also collected at several locations within the survey areas and analyzed in the laboratory for isotopic composition. The results of the survey showed only the presence of naturally occurring background radiation. No man-made radioactivity was detected. 4 refs., 4 figs., 4 tabs

Thermotransport in interstitial solid solutions

International Nuclear Information System (INIS)

Fogel'son, R.L.

1982-01-01

On the basis of literature data the problem of thermotransport of impurities (H, N, O, C) in interstitial solid solutions is considered. It is shown that from experimental data on the thermotransport an important parameter of dissolved atoms can be found which characterizes atom state in these solutions-enthalpy of transport

Environmental assessment: Davis Canyon site, Utah

International Nuclear Information System (INIS)

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has fond that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of five sites suitable for characterization. 181 figs., 175 tabs

Environmental assessment: Davis Canyon site, Utah

Energy Technology Data Exchange (ETDEWEB)

none,

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high- level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has found that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of the five sites suitable for characterization.

Environmental assessment: Davis Canyon site, Utah

Energy Technology Data Exchange (ETDEWEB)

none,

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has fond that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of five sites suitable for characterization. 181 figs., 175 tabs.

Environmental assessment: Davis Canyon site, Utah

Energy Technology Data Exchange (ETDEWEB)

none,

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considering for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has found that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of five sites suitable for characterization.

Environmental assessment: Davis Canyon site, Utah

International Nuclear Information System (INIS)

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considering for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has found that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of five sites suitable for characterization

Environmental assessment: Davis Canyon site, Utah

International Nuclear Information System (INIS)

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high- level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. These evaluations were reported in draft environmental assessments (EAs), which were issued for public review and comment. After considering the comments received on the draft EAs, the DOE prepared the final EA. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site -- the Lavender Canyon site. Although the Lavender Canyon site is suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. Furthermore, the DOE has found that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of the five sites suitable for characterization

Sonolytic Oxidation of Tc(IVO2nH2O Nanoparticles to Tc(VIIO4 in Aqueous Solution

Directory of Open Access Journals (Sweden)

M. Zakir

2010-04-01

Full Text Available Sonolysis of a hydrosol of TcO2nH2O was investigated in the Ar- or He- atmosphere. Colloidal TcO2nH2O nanoparticles were irradiated with a 200 kHz and 1.25 W/cm2 ultrasound. It was found that the TcO2nH2O colloids dispersed in an aqueous solution (under Ar or He atmosphere was completely dissolved by ultrasonic irradiation (200 kHz, 200 W. The original brownish black color of the suspension slowly disappeared leaving behind a colorless solution. This change suggests that oxidation of Tc(IV to Tc(VII takes place. The oxidation was almost complete during 30 minutes sonication time under argon atmosphere for initial concentration of 6.0E-5 M. Addition of t-butyl alcohol, an effective radical scavenger which readily reacts with OH radicals, supressed the dissolution of TcO2nH2O colloids. This reaction indicates that TcO2nH2O molecules are oxidized by OH radicals produced in cavitation bubbles.

Late Holocene earthquake history of the Brigham City segment of the Wasatch fault zone at the Hansen Canyon, Kotter Canyon, and Pearsons Canyon trench sites, Box Elder County, Utah

Science.gov (United States)

DuRoss, Christopher B.; Personius, Stephen F.; Crone, Anthony J.; McDonald, Greg N.; Briggs, Richard W.

2012-01-01

Of the five central segments of the Wasatch fault zone (WFZ) having evidence of recurrent Holocene surface-faulting earthquakes, the Brigham City segment (BCS) has the longest elapsed time since its most recent surface-faulting event (~2.1 kyr) compared to its mean recurrence time between events (~1.3 kyr). Thus, the BCS has the highest time-dependent earthquake probability of the central WFZ. We excavated trenches at three sites––the Kotter Canyon and Hansen Canyon sites on the north-central BCS and Pearsons Canyon site on the southern BCS––to determine whether a surface-faulting earthquake younger than 2.1 ka occurred on the BCS. Paleoseismic data for Hansen Canyon and Kotter Canyon confirm that the youngest earthquake on the north-central BCS occurred before 2 ka, consistent with previous north-central BCS investigations at Bowden Canyon and Box Elder Canyon. At Hansen Canyon, the most recent earthquake is constrained to 2.1–4.2 ka and had 0.6–2.5 m of vertical displacement. At Kotter Canyon, we found evidence for two events at 2.5 ± 0.3 ka and 3.5 ± 0.3 ka, with an average displacement per event of 1.9–2.3 m. Paleoseismic data from Pearsons Canyon, on the previously unstudied southern BCS, indicate that a post-2 ka earthquake ruptured this part of the segment. The Pearsons Canyon earthquake occurred at 1.2 ± 0.04 ka and had 0.1–0.8 m of vertical displacement, consistent with our observation of continuous, youthful scarps on the southern 9 km of the BCS having 1–2 m of late Holocene(?) surface offset. The 1.2-ka earthquake on the southern BCS likely represents rupture across the Weber–Brigham City segment boundary from the penultimate Weber-segment earthquake at about 1.1 ka. The Pearsons Canyon data result in a revised length of the BCS that has not ruptured since 2 ka (with time-dependent probability implications), and provide compelling evidence of at least one segment-boundary failure and multi-segment rupture on the central WFZ. Our

The release of dissolved nutrients and metals from coastal sediments due to resuspension

Science.gov (United States)

Kalnejais, Linda H.; Martin, William R.; Bothner, Michael H.

2010-01-01

Coastal sediments in many regions are impacted by high levels of contaminants. Due to a combination of shallow water depths, waves, and currents, these sediments are subject to regular episodes of sediment resuspension. However, the influence of such disturbances on sediment chemistry and the release of solutes is poorly understood. The aim of this study is to quantify the release of dissolved metals (iron, manganese, silver, copper, and lead) and nutrients due to resuspension in Boston Harbor, Massachusetts, USA. Using a laboratory-based erosion chamber, a range of typical shear stresses was applied to fine-grained Harbor sediments and the solute concentration at each shear stress was measured. At low shear stress, below the erosion threshold, limited solutes were released. Beyond the erosion threshold, a release of all solutes, except lead, was observed and the concentrations increased with shear stress. The release was greater than could be accounted for by conservative mixing of porewaters into the overlying water, suggesting that sediment resuspension enhances the release of nutrients and metals to the dissolved phase. To address the long-term fate of resuspended particles, samples from the erosion chamber were maintained in suspension for 90. h. Over this time, 5-7% of the particulate copper and silver was released to the dissolved phase, while manganese was removed from solution. Thus resuspension releases solutes both during erosion events and over a longer timescale due to reactions of suspended particles in the water column. The magnitude of the annual solute release during erosion events was estimated by coupling the erosion chamber results with a record of bottom shear stresses simulated by a hydrodynamic model. The release of dissolved copper, lead, and phosphate due to resuspension is between 2% and 10% of the total (dissolved plus particulate phase) known inputs to Boston Harbor. Sediment resuspension is responsible for transferring a significant

Measurements of the Activity of dissolved H2O in an Andesite Melt

Science.gov (United States)

Moore, G. M.; Touran, J. P.; Pu, X.; Kelley, K. A.; Cottrell, E.; Ghiorso, M. S.

2016-12-01

The large effect of dissolved H2O on the physical and chemical nature of silicate melts, and its role in driving volcanism, is well known and underscores the importance of this volatile component. A complete understanding of the chemical behavior of dissolved H2O in silicate melts requires the quantification of its thermodynamic activity as a function of pressure, temperature, and melt composition, particularly at low H2O contents (i.e. at under-saturated conditions). Knowledge of the activity of H2O in silicate melts at H2O-undersaturated conditions will improve our understanding of hydrous phase equilibria, as well as our models of physical melt properties. Measurement of the activity of any silicate melt component, much less that of a volatile component such as H2O, is a difficult experimental task however. By using a modified double capsule design (Matjuschkin et al, 2015) to control oxygen fugacity in piston cylinder experiments, along with high precision X-ray absorption techniques (XANES) to measure iron oxidation state in silicate glasses (Cottrell et al, 2009), we are able to constrain the H2O activity in silicate melts at under-saturated conditions. Preliminary results on an andesite melt with low H2O content (3 wt%) have been shown (Moore et al, 2016) to match predicted H2O activity values calculated using the H2O equation of state of Duan and Zhang (1996) and the H2O solubility model of Ghiorso and Gualda (2015). More recent results on the same andesite melt containing approximately 5 wt% H2O however show a large negative deviation from the predicted values. Reversal experiments involving an oxidized starting material are ongoing, as well as further characterization of the samples to detect the presence of possible contaminants that would induce reduction of the melt beyond that related to the H2O activity (e.g. graphite contamination).

Validation of a two-dimensional pollutant dispersion model in an isolated street canyon

Energy Technology Data Exchange (ETDEWEB)

Chan, T.L.; Dong, G.; Leung, C.W.; Cheung, C.S. [The Hong Kong Polytechnic University, Kowloon (Hong Kong). Research Centre for Combustion and Pollution Control, Department of Mechanical Engineering; Hung, W.T. [The Hong Kong Polytechnic University, Kowloon (Hong Kong). Department of Civil and Structural Engineering

2002-07-01

A two-dimensional numerical model based on Reynolds-averaged Navier-Stokes equations coupled with a series of standard, Renormalization Group (RNG) and realizable k-{epsilon} turbulence models was developed to simulate the fluid-flow development and pollutant dispersion within an isolated street canyon using the FLUENT code. In the present study, the validation of the numerical model was evaluated using an extensive experimental database obtained from the atmospheric boundary layer wind tunnel at the Meteorological Institute of Hamburg University, Germany (J. Wind Eng. Ind. Aerodyn. 62 (1996) 37). Among the studied turbulence models, the RNG k-{epsilon} turbulence model was found to be the most optimum turbulence model coupled with the two-dimensional street canyon model developed in the present study. Both the calculated and measured dimensionless pollutant concentrations have been shown to be less dependent on the variation of wind speed and source strength conditions for the studied street canyon aspect ratio of the B/H=1 case. However, the street canyon configuration has significant influence on the pollutant dispersion. The wider street and lower height of the buildings are favorable to pollutant dilution within the street canyon. The fluid-flow development has demonstrated that the rotative vortex or vortices generated within the urban street canyon can transport the pollutants from a line source to the wall surfaces of the buildings. (author)

Density of simulated americium/curium melter feed solution

International Nuclear Information System (INIS)

Rudisill, T.S.

1997-01-01

Vitrification will be used to stabilize an americium/curium (Am/Cm) solution presently stored in F-Canyon for eventual transport to Oak Ridge National Laboratory and use in heavy isotope production programs. Prior to vitrification, a series of in-tank oxalate precipitation and nitric/oxalic acid washes will be used to separate these elements and lanthanide fission products from the bulk of the uranium and metal impurities present in the solution. Following nitric acid dissolution and oxalate destruction, the solution will be denitrated and evaporated to a dissolved solids concentration of approximately 100 g/l (on an oxide basis). During the Am/Cm vitrification, an airlift will be used to supply the concentrated feed solution to a constant head tank which drains through a filter and an in-line orifice to the melter. Since the delivery system is sensitive to the physical properties of the feed, a simulated solution was prepared and used to measure the density as a function of temperature between 20 to 70 degrees C. The measured density decreased linearly at a rate of 0.0007 g/cm3/degree C from an average value of 1.2326 g/cm 3 at 20 degrees C to an average value of 1.1973g/cm 3 at 70 degrees C

Density of simulated americium/curium melter feed solution

Energy Technology Data Exchange (ETDEWEB)

Rudisill, T.S.

1997-09-22

Vitrification will be used to stabilize an americium/curium (Am/Cm) solution presently stored in F-Canyon for eventual transport to Oak Ridge National Laboratory and use in heavy isotope production programs. Prior to vitrification, a series of in-tank oxalate precipitation and nitric/oxalic acid washes will be used to separate these elements and lanthanide fission products from the bulk of the uranium and metal impurities present in the solution. Following nitric acid dissolution and oxalate destruction, the solution will be denitrated and evaporated to a dissolved solids concentration of approximately 100 g/l (on an oxide basis). During the Am/Cm vitrification, an airlift will be used to supply the concentrated feed solution to a constant head tank which drains through a filter and an in-line orifice to the melter. Since the delivery system is sensitive to the physical properties of the feed, a simulated solution was prepared and used to measure the density as a function of temperature between 20 to 70{degrees} C. The measured density decreased linearly at a rate of 0.0007 g/cm3/{degree} C from an average value of 1.2326 g/cm{sup 3} at 20{degrees} C to an average value of 1.1973g/cm{sup 3} at 70{degrees} C.

The Black Canyon of the Gunnison: Today and Yesterday

Science.gov (United States)

Hansen, Wallace R.

1965-01-01

Since the early visit of Captain John William Gunnison in the middle of the last century, the Black Canyon of the Gunnison has stirred mixed apprehension and wonder in the hearts of its viewers. It ranks high among the more awesome gorges of North America. Many great western canyons are as well remembered for their brightly colored walls as for their airy depths. Not so the Black Canyon. Though it is assuredly not black, the dark-gray tones of its walls and the hazy shadows of its gloomy depths join together to make its name well deserved. Its name conveys an impression, not a picture. After the first emotional impact of the canyon, the same questions come to the minds of most reflective viewers and in about the following order: How deep is the Black Canyon, how wide, how does it compare with other canyons, what are the rocks, how did it form, and how long did it take? Several western canyons exceed the Black Canyon in overall size. Some are longer; some are deeper; some are narrower; and a few have walls as steep. But no other canyon in North American combines the depth, narrowness, sheerness, and somber countenance of the Black Canyon. In many places the Black Canyon is as deep as it is wide. Between The Narrows and Chasm View in the Black Canyon of the Gunnison National Monument (fig. 15) it is much deeper than wide. Average depth in the monument is about 2,000 feet, ranging from a maximum of about 2,700 feet, north of Warner Point (which also is the greatest depth anywhere in the canyon), to a minimum of about 1,750 feet at The Narrows. The stretch of canyon between Pulpit Rock and Chasm View, including The Narrows, though the shallowest in the monument, is also the narrowest, has some of the steepest walls, and is, therefore, among the most impressive segments of the canyon (fig. 3). Profiles of several well-known western canyons are shown in figure 1. Deepest of these by far is Hells Canyon of the Snake, on the Idaho-Oregon border. Clearly, it dwarfs the

Separations canyon decontamination facilities

International Nuclear Information System (INIS)

Hershey, J.H.

1975-01-01

Highly radioactive process equipment is decontaminated at the Savannah River Plant in specially equipped areas of the separations canyon building so that direct mechanical repairs or alterations can be made. Using these facilities it is possible to decontaminate and repair equipment such as 10- x 11-ft storage tanks, 8- x 8-ft batch evaporator pots and columns, 40-in. Bird centrifuges, canyon pumps and agitators, and various canyon piping systems or ''jumpers.'' For example, centrifuge or evaporator pots can be decontaminated and rebuilt for about 60 percent of the 1974 replacement cost. The combined facilities can decontaminate and repair 6 to 10 pieces of major equipment per year. Decontamination time varies with type of equipment and radioactivity levels encountered

Separations canyon decontamination facilities

International Nuclear Information System (INIS)

Hershey, J.H.

1975-05-01

Highly radioactive process equipment is decontaminated at the Savannah River Plant in specially equipped areas of the separations canyon buildings so that direct mechanical repairs or alterations can be made. Using these facilities it is possible to decontaminate and repair equipment such as 10- x 11-ft storage tanks, 8- x 8-ft batch evaporator pots and columns, 40-in. Bird centrifuges, canyon pumps and agitators, and various canyon piping systems or ''jumpers.'' For example, centrifuge or evaporator pots can be decontaminated and rebuilt for about 60 percent of the 1974 replacement cost. The combined facilities can decontaminate and repair 6 to 10 pieces of major equipment per year. Decontamination time varies with type of equipment and radioactivity levels encountered. (U.S.)

Actinide speciation in the shallow aquifer of Mortandad Canyon

International Nuclear Information System (INIS)

Nelson, D.M.; Polzer, W.L.

1983-01-01

Treated waste effluent at Los Alamos has been released to the environment in Mortandad Canyon since 1963. A study has been initiated to investigate the relative mobilities of the actinides in the shallow aquifer of Mortandad Canyon. Speciation of radionuclides and their adsorption by sediment are important parameters in the evaluation of those mobilities. Plutonium concentrations and oxidation states were measured in water collected from four test wells (MCO 4, 5, 6, 7.5). A regular decrease in 239 240 Pu concentration was observed with increasing distance from the discharge point. The large difference between the concentrations discharged (30 to 1000 pCi/l for period 1977-1982) and those in the wells (0.02 to 5.4 pCi/l) suggests that progressive loss of plutonium from the water as it moves through the alluvium is probably more important in regulating the concentrations than the variability of concentrations in the discharged effluent. The K/sub D/s for 228 Th were also determined and found to be similar to those for plutonium. The factors regulating the concentration of dissolved plutonium are probably the same as those regulating 228 Th. In contrast the K/sub D/s of 241 Am decrease regularly with distance from the discharge point and are about 100 times lower than those of plutonium and thorium for water in wells farthest from the discharge point

A Layered Solution Crystal Growth Technique and the Crystal Structure of (C 6H 5C 2H 4NH 3) 2PbCl 4

Science.gov (United States)

Mitzi, D. B.

1999-07-01

Single crystals of the organic-inorganic perovskite (C6H5C2H4NH3)2PbCl4 have been grown at room temperature using a layered solution approach. The bottom solution layer, contained within a long straight tube, consists of PbCl2 dissolved in concentrated aqueous HCl. A less dense layer of methanol is carefully placed on top of the HCl/PbCl2 solution using a syringe. Finally, a stoichiometric quantity of C6H5C2H4NH2 (relative to the PbCl2) is added to the top of the column. As the layers slowly diffuse together, well-formed crystals of (C6H5C2H4NH3)2PbCl4 appear near the interface between the HCl/PbCl2 and C6H5C2H4NH2 solutions. The thick, plate-like crystals are well suited for X-ray crystallography studies. Room temperature intensity data were refined using a triclinic (Poverline1) cell (a=11.1463(3) Å, b=11.2181(3) Å, c=17.6966(5) Å, α= 99.173(1)°, β=104.634(1)°, γ=89.999(1)°, V=2111.8(1) Å3, Z=4, Rf/Rw=0.031/0.044). The organic-inorganic layered perovskite structure features well-ordered sheets of corner-sharing distorted PbCl6 octahedra separated by bilayers of phenethylammonium cations. Tilting and rotation of the PbCl6 octahedra within the perovskite sheets, coupled with organic cation ordering, leads to the unusual in-sheet 2ap×2ap superstructure, where ap is the lattice constant for the ideal cubic perovskite.

Feasibility of processing the experimental breeder reactor-II driver fuel from the Idaho National Laboratory through Savannah River Site's H-Canyon facility

Energy Technology Data Exchange (ETDEWEB)

Magoulas, V. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-07-28

Savannah River National Laboratory (SRNL) was requested to evaluate the potential to receive and process the Idaho National Laboratory (INL) uranium (U) recovered from the Experimental Breeder Reactor II (EBR-II) driver fuel through the Savannah River Site’s (SRS) H-Canyon as a way to disposition the material. INL recovers the uranium from the sodium bonded metallic fuel irradiated in the EBR-II reactor using an electrorefining process. There were two compositions of EBR-II driver fuel. The early generation fuel was U-5Fs, which consisted of 95% U metal alloyed with 5% noble metal elements “fissium” (2.5% molybdenum, 2.0% ruthenium, 0.3% rhodium, 0.1% palladium, and 0.1% zirconium), while the later generation was U-10Zr which was 90% U metal alloyed with 10% zirconium. A potential concern during the H-Canyon nitric acid dissolution process of the U metal containing zirconium (Zr) is the explosive behavior that has been reported for alloys of these materials. For this reason, this evaluation was focused on the ability to process the lower Zr content materials, the U-5Fs material.

Simultaneous determination of uranium and plutonium in dissolver solution of irradiated fuel, using ID-TIMS. IRP-11

International Nuclear Information System (INIS)

Shah, Raju; Sasi Bhushan, K.; Govindan, R.; Alamelu, D.; Khodade, P.S.; Aggarwal, S.K.

2007-01-01

A simple sample preparation and simultaneous analysis method to determine uranium and plutonium from dissolver solution, employing the technique of Isotope Dilution Mass spectrometry has been demonstrated. The method used, co-elusion of Uranium and Plutonium from anion exchanger column after initial elution of major part of uranium in 1:5 HNO 3 in order to reduce the initial U/Pu ratio from 1000 to about 100-200 in the co-eluted fraction. Due to the availability of variable multi-collector system, different Faraday cups were adjusted to collect the different ion intensities corresponding to the different masses, during the simultaneous analysis of Uranium and Plutonium, loaded on Re double filament assembly. 233 U and PR grade Plutonium were used as spikes to determine Uranium and Plutonium from dissolver solution of irradiated fuel from research reactor. The possibility of getting the isotopic composition of uranium from the simultaneous analysis of co-eluted purified fraction of U and Pu from spiked aliquots is also explained. (author)

Hudson Canyon benthic habitats characterization and mapping by integrated analysis of multidisciplinary data

Science.gov (United States)

Pierdomenico, Martina; Guida, Vincent G.; Rona, Peter A.; Macelloni, Leonardo; Scranton, Mary I.; Asper, Vernon; Diercks, Arne

2013-04-01

Hudson Canyon, about 180 km SE of New York City, is the largest eastern U.S. submarine canyon and is under consideration for HAPC (Habitat Area of Particular Concern) status, representing a fisheries and biodiversity hot spot. Interest in the area, within the perspective of ecosystem based management, marine spatial planning, habitat and species conservation, led to a joint project between NOAA Northeast Fisheries, U.S. Geological Survey (USGS), Mississippi Mineral Research Institute (MMRI), National Institute for Undersea Science and Technology (NIUST), Stony Brook and Rutgers Universities for the study of benthic habitats, that includes the assembly of existing data with newly collected ones: acoustic mapping, visual ground-truthing, hydrographic, sedimentological, and trawl data collections. Acoustic mapping, performed using AUV-mounted multibeam sonar, provided ultra-high resolution bathymetric and backscatter imagery (3m and 1m respectively) at all water depths for identification of geomorphological features and for the characterization of surficial sediments along the two thirds of the shelf portion of the canyon. Identification of benthic and demersal communities was accomplished by visual ground thruthing with underwater vehicle video and still cameras, and from trawl catch data. A CTD-rosette sampler provided water column salinity-temperature profiles and water samples for dissolved methane analysis in the vicinity of suspected bottom sources. Analysis of data revealed a complex of topographic structures and hydrological patterns that provide a wide range of physical habitats in a relatively small area. A mosaic of sandy and muddy substrates, gravel beds, rock outcrops, and semilithified clay outcrops host rich and varied faunal assemblages, including deepwater corals and sponge communities. Pockmark fields, occurring below 300 m depth, suggest that methane-based chemosynthetic carbonate deposition contributes to creation of specific hard bottom habitats

An intercomparison experiment on isotope dilution thermal ionisation mass spectrometry using plutonium-239 spike for the determination of plutonium concentration in dissolver solution of irradiated fuel

International Nuclear Information System (INIS)

Aggarwal, S.K.; Shah, P.M.; Saxena, M.K.; Jain, H.C.; Gurba, P.B.; Babbar, R.K.; Udagatti, S.V.; Moorthy, A.D.; Singh, R.K.; Bajpai, D.D.

1996-01-01

Determination of plutonium concentration in the dissolver solution of irradiated fuel is one of the key measurements in the nuclear fuel cycle. This report presents the results of an intercomparison experiment performed between Fuel Chemistry Division (FCD) at BARC and PREFRE, Tarapur for determining plutonium concentration in dissolver solution of irradiated fuel using 239 Pu spike in isotope dilution thermal ionisation mass spectrometry (ID-TIMS). The 239 Pu spike method was previously established at FCD as viable alternative to the imported enriched 242 Pu or 244 Pu; the spike used internationally for plutonium concentration determination by IDMS in dissolver solution of irradiated fuel. Precision and accuracy achievable for determining plutonium concentration are compared under the laboratory and the plant conditions using 239 Pu spike in IDMS. For this purpose, two different dissolver solutions with 240 Pu/ 239 Pu atom ratios of about 0.3 and 0.07 corresponding, respectively, to high and low burn-up fuels, were used. The results of the intercomparison experiment demonstrate that there is no difference in the precision values obtained under the laboratory and the plant conditions; with mean precision values of better than 0.2%. Further, the plutonium concentration values determined by the two laboratories agreed within 0.3%. This exercise, therefore, demonstrates that ID-TIMS method using 239 Pu spike can be used for determining plutonium concentration in dissolver solution of irradiated fuel, under the plant conditions. 7 refs., 8 tabs

Flow dynamics around downwelling submarine canyons

Directory of Open Access Journals (Sweden)

J. M. Spurgin

2014-10-01

Full Text Available Flow dynamics around a downwelling submarine canyon were analysed with the Massachusetts Institute of Technology general circulation model. Blanes Canyon (northwestern Mediterranean was used for topographic and initial forcing conditions. Fourteen scenarios were modelled with varying forcing conditions. Rossby and Burger numbers were used to determine the significance of Coriolis acceleration and stratification (respectively and their impacts on flow dynamics. A new non-dimensional parameter (χ was introduced to determine the significance of vertical variations in stratification. Some simulations do see brief periods of upwards displacement of water during the 10-day model period; however, the presence of the submarine canyon is found to enhance downwards advection of density in all model scenarios. High Burger numbers lead to negative vorticity and a trapped anticyclonic eddy within the canyon, as well as an increased density anomaly. Low Burger numbers lead to positive vorticity, cyclonic circulation, and weaker density anomalies. Vertical variations in stratification affect zonal jet placement. Under the same forcing conditions, the zonal jet is pushed offshore in more uniformly stratified domains. The offshore jet location generates upwards density advection away from the canyon, while onshore jets generate downwards density advection everywhere within the model domain. Increasing Rossby values across the canyon axis, as well as decreasing Burger values, increase negative vertical flux at shelf break depth (150 m. Increasing Rossby numbers lead to stronger downwards advection of a passive tracer (nitrate, as well as stronger vorticity within the canyon. Results from previous studies are explained within this new dynamic framework.

Assesment of longwave radiation effects on air quality modelling in street canyons

Science.gov (United States)

Soucasse, L.; Buchan, A.; Pain, C.

2016-12-01

Computational Fluid Dynamics is widely used as a predictive tool to evaluate people's exposure to pollutants in urban street canyons. However, in low-wind conditions, flow and pollutant dispersion in the canyons are driven by thermal effects and may be affected by longwave (infrared) radiation due to the absorption and emission of water vapor contained in the air. These effects are mostly ignored in the literature dedicated to air quality modelling at this scale. This study aims at quantifying the uncertainties due to neglecting thermal radiation in air quality models. The Large-Eddy-Simulation of air flow in a single 2D canyon with a heat source on the ground is considered for Rayleigh and Reynolds numbers in the range of [10e8-10e10] and [5.10e3-5.10e4] respectively. The dispersion of a tracer is monitored once the statistically steady regime is reached. Incoming radiation is computed for a mid-latitude summer atmosphere and canyon surfaces are assumed to be black. Water vapour is the only radiating molecule considered and a global model is used to treat the spectral dependancy of its absorption coefficient. Flow and radiation fields are solved in a coupled way using the finite element solvers Fluidity and Fetch which have the capability of adapting their space and angular resolution according to an estimate of the solution error. Results show significant effects of thermal radiation on flow patterns and tracer dispersion. When radiation is taken into account, the air is heated far from the heat source leading to a stronger natural convection flow. The tracer is then dispersed faster out of the canyon potentially decreasing people's exposure to pollution within the street canyon.

236-Z canyon utilization study

International Nuclear Information System (INIS)

Dixon, D.R.

1977-01-01

The 236-Z canyon contains equipment for repurification of plutonium and recovery of plutonium from scrap material. To meet production requirements of Fast Flux Test Facility/Clinch River Breeder Reactor oxide with the existing plant, several new pieces of equipment will be needed in the future. More storage space and a better accountability system are needed to support this increased production. The available canyon space needs to be utilized to its fullest in order to accommodate the new equipment. The purpose of this document is to identify the new pieces of equipment, show how they fit into the flowsheet, and locate them in the canyon

Ventilation Processes in a Three-Dimensional Street Canyon

Science.gov (United States)

Nosek, Štěpán; Kukačka, Libor; Kellnerová, Radka; Jurčáková, Klára; Jaňour, Zbyněk

2016-05-01

The ventilation processes in three different street canyons of variable roof geometry were investigated in a wind tunnel using a ground-level line source. All three street canyons were part of an urban-type array formed by courtyard-type buildings with pitched roofs. A constant roof height was used in the first case, while a variable roof height along the leeward or windward walls was simulated in the two other cases. All street-canyon models were exposed to a neutrally stratified flow with two approaching wind directions, perpendicular and oblique. The complexity of the flow and dispersion within the canyons of variable roof height was demonstrated for both wind directions. The relative pollutant removals and spatially-averaged concentrations within the canyons revealed that the model with constant roof height has higher re-emissions than models with variable roof heights. The nomenclature for the ventilation processes according to quadrant analysis of the pollutant flux was introduced. The venting of polluted air (positive fluctuations of both concentration and velocity) from the canyon increased when the wind direction changed from perpendicular to oblique, irrespective of the studied canyon model. Strong correlations (>0.5) between coherent structures and ventilation processes were found at roof level, irrespective of the canyon model and wind direction. This supports the idea that sweep and ejection events of momentum bring clean air in and detrain the polluted air from the street canyon, respectively.

Evaluation method of iodine re-evolution from an in-containment water pool after a loss of coolant accident, Part I: pH estimation of a solution with various chemicals

International Nuclear Information System (INIS)

Kim, Tae Hyeon; Jeong, Ji Hwan

2016-01-01

Highlights: • It is required to evaluate re-evolved iodine from sump water after LOCA. • pH evaluation based on Gibbs free energy minimization. • Program was developed to evaluate chemical equilibrium and pH solutions. • Predictions are in good agreement with experimental data. - Abstract: Radioactive iodine, which is released into the atmosphere of the containment building, is absorbed into the containment spray water and dissolved to be ionized. This iodine-rich water is then transported to the in-containment refueling water storage tank (IRWST) in APR1400 nuclear power plants. When the pH of the water is below 7, the dissolved iodine converts to molecular iodine and re-evolves from the water and returns to the atmosphere. A series of studies have been conducted in order to evaluate the iodine re-evolution from the IRWST. This study consists of two parts: the pH evaluation method and the evaluation of the iodine re-evolution. This paper presents the first part, i.e. the pH evaluation method. The equilibrium concentrations of various chemicals in a solution are determined at the minimum Gibbs’ free energy. This method is useful for complex reactant problems rather than equilibrium constants method because the latter method requires numerous equilibrium constants and there might be missing equilibrium constants associated with the solution. The calculated pH values of solutions are compared with the experimental measurements in order to validate this method and the thermodynamic data of the chemicals incorporated into the program. The estimated values for solutions are in good agreement with the experimental measurements within a difference of less than 3.3%.

A reconnaissance of the effects of a forest fire on water quality in Kings Canyon National Park, California

Science.gov (United States)

Hoffman, Ray J.; Ferreira, Rodger F.

1976-01-01

Following two forest fires in the Roaring River drainage basin, Kings Canyon National Park, Calif., water samples were collected from May to July 1974 to determine water-quality changes resulting from the fires. Field measurements included alkalinity , pH, specific conductance, temperature, and discharge. Samples were analyzed in the laboratory for major dissolved chemical constituents, selected plant nutrients, trace metals, suspended sediment, total organic carbon, and seston. Periphytic algae and benthic invertebrate samples were collected. A noticeable increase in the concentration of nitrogen was found in Roaring River immediately downstream from the Moraine Creek fire. The increase in the concentration of inorganic nitrogen compounds, however, was not great enough to pose a serious threat to the aquatic ecosystem. High total organic nitrogen concentrations may have been due, in part, to factors other than the effect of fire. The results of other water-quality measurements were typical of dilute Sierra Nevada streams and indicate that Roaring River was not adversely affected by the fires. (Woodard-USGS)

VOLATILECALC: A silicate melt-H2O-CO2 solution model written in Visual Basic for excel

Science.gov (United States)

Newman, S.; Lowenstern, J. B.

2002-01-01

We present solution models for the rhyolite-H2O-CO2 and basalt-H2O-CO2 systems at magmatic temperatures and pressures below ~ 5000 bar. The models are coded as macros written in Visual Basic for Applications, for use within MicrosoftR Excel (Office'98 and 2000). The series of macros, entitled VOLATILECALC, can calculate the following: (1) Saturation pressures for silicate melt of known dissolved H2O and CO2 concentrations and the corresponding equilibrium vapor composition; (2) open- and closed-system degassing paths (melt and vapor composition) for depressurizing rhyolitic and basaltic melts; (3) isobaric solubility curves for rhyolitic and basaltic melts; (4) isoplethic solubility curves (constant vapor composition) for rhyolitic and basaltic melts; (5) polybaric solubility curves for the two end members and (6) end member fugacities of H2O and CO2 vapors at magmatic temperatures. The basalt-H2O-CO2 macros in VOLATILECALC are capable of calculating melt-vapor solubility over a range of silicate-melt compositions by using the relationships provided by Dixon (American Mineralogist 82 (1997) 368). The output agrees well with the published solution models and experimental data for silicate melt-vapor systems for pressures below 5000 bar. ?? 2002 Elsevier Science Ltd. All rights reserved.

Morphodynamic Model of Submarine Canyon Incision by Sandblasting

Science.gov (United States)

Zhang, L.; Parker, G.; Izumi, N.; Cartigny, M.; Li, T.; Wang, G.

2017-12-01

Submarine canyons are carved by turbidity currents under the deep sea. As opposed to subaerial canyons, the relevant processes are not easy to observe directly. Turbidity currents are bottom-hugging sediment gravity flows of that can incise or deposit on the seafloor to create submarine canyons or fans. The triggers of turbidity currents can be storms, edge waves, internal waves, canyon wall sapping, delta failure, breaching and hyperpycnal flows. The formation and evolution mechanisms of submarine canyons are similar to those of subaerial canyons, but have substantial differences. For example, sandblasting, rather than wear due to colliding gravel clasts is more likely to be the mechanism of bedrock incision. Submarine canyons incise downward, and often develop meander bends and levees within the canyon, so defining "fairways". Here we propose a simple model for canyon incision. The starting point of our model is the Macro Roughness Saltation Abrasion Alluviation model of Zhang et al. [2015], designed for bedrock incision by gravel clasts in mixed bedrock-alluvial rivers. We adapt this formulation to consider sandblasting as a means of wear. We use a layer-averaged model for turbidity current dynamics. The current contains a mixture of mud, which helps drive the flow but which does not cause incision, and sand, which is the agent of incision. We show that the model can successfully model channel downcutting, and indeed illustrate the early formation of net incisional cyclic steps, i.e. upstream-migrating undulations on the bed associated with transcritical (in the Froude sense) flow. These steps can be expected to abet the process of incision.

Environmental assessment overview, Davis Canyon site, Utah

International Nuclear Information System (INIS)

1986-05-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah as one of the nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for the Nuclear Waste Repositories. The Davis Canyon site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. On the basis of the evaluations reported in this EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. On the basis of these findings, the DOE is nominating the Davis Canyon site as one of five sites suitable for characterization. 3 figs

The effect of the oxygen dissolved in the adsorption of gold in activated carbon; Efecto del oxigeno disuelto en la adsorcion de oro en carbon activado

Energy Technology Data Exchange (ETDEWEB)

Navarro, P. [Universidad de Santiago. Chile (Chile); Wilkomirsky, I. [Universidad de Concepcion. Chile (Chile)

1999-07-01

The effect of the oxygen dissolved on the adsorption of gold in a activated carbon such as these used for carbon in pulp (CIP) and carbon in leach (CIL) processes were studied. The research was oriented to dilucidate the effect of the oxygen dissolved in the gold solution on the kinetics and distribution of the gold adsorbed in the carbon under different conditions of ionic strength, pH and gold concentration. It was found that the level of the oxygen dissolved influences directly the amount of gold adsorbed on the activated carbon, being this effect more relevant for low ionic strength solutions. The pH and initial gold concentration has no effect on this behavior. (Author) 16 refs.

Examination of hydrogen-bonding interactions between dissolved solutes and alkylbenzene solvents based on Abraham model correlations derived from measured enthalpies of solvation

Energy Technology Data Exchange (ETDEWEB)

Varfolomeev, Mikhail A.; Rakipov, Ilnaz T. [Chemical Institute, Kazan Federal University, Kremlevskaya 18, Kazan 420008 (Russian Federation); Acree, William E., E-mail: acree@unt.edu [Department of Chemistry, 1155 Union Circle # 305070, University of North Texas, Denton, TX 76203-5017 (United States); Brumfield, Michela [Department of Chemistry, 1155 Union Circle # 305070, University of North Texas, Denton, TX 76203-5017 (United States); Abraham, Michael H. [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)

2014-10-20

Highlights: • Enthalpies of solution measured for 48 solutes dissolved in mesitylene. • Enthalpies of solution measured for 81 solutes dissolved in p-xylene. • Abraham model correlations derived for enthalpies of solvation of solutes in mesitylene. • Abraham model correlations derived for enthalpies of solvation of solutes in p-xylene. • Hydrogen-bonding enthalpies reported for interactions of aromatic hydrocarbons with hydrogen-bond acidic solutes. - Abstract: Enthalpies of solution at infinite dilution of 48 organic solutes in mesitylene and 81 organic solutes in p-xylene were measured using isothermal solution calorimeter. Enthalpies of solvation for 92 organic vapors and gaseous solutes in mesitylene and for 130 gaseous compounds in p-xylene were determined from the experimental and literature data. Abraham model correlations are determined from the experimental enthalpy of solvation data. The derived correlations describe the experimental gas-to-mesitylene and gas-to-p-xylene solvation enthalpies to within average standard deviations of 1.87 kJ mol{sup −1} and 2.08 kJ mol{sup −1}, respectively. Enthalpies of X-H⋯π (X-O, N, and C) hydrogen bond formation of proton donor solutes (alcohols, amines, chlorinated hydrocarbons etc.) with mesitylene and p-xylene were calculated based on the Abraham solvation equation. Obtained values are in good agreement with the results determined using conventional methods.

Modeling the Effect of Wider Canyons on Urban Heating

Directory of Open Access Journals (Sweden)

Rizwan Ahmed Memon

2011-04-01

Full Text Available The k-? turbulence model is adopted in this study to simulate the impact of street canyon AR (Aspect Ratios on heating within street canyon. The two-dimensional model was validated for RANS (Reynolds Averaged Navier Stokes and energy transport equations. The validation process confirms that the results of the model for airtemperature and wind speed could be trusted. The application of the said model is carried out to ideal street canyons of ARs (ratio of building-height-to-street-width from 0.4 to 2 with the same boundary conditions. Notably, street canyon aspect ratio was calculated by varying the street width while keeping the building height constant. Results show that the weighted-average-air-temperature within AR 0.4 was around 0.8% (i.e. 2.4K higher than that within AR 2.0. Conversely, there was strong correlation (i.e., R2>0.9 between air temperature within the street canyon and street canyon AR. Results demonstrate stronger influence of vertical velocity on heating within street canyon. Evidently, increased vertical velocity decreased the temperatures. Conversely, temperatures were higher along the leeward side of the canyon in lower ARs.

Dually Fluorescent Sensing of pH and Dissolved Oxygen Using a Membrane Made from Polymerizable Sensing Monomers.

Science.gov (United States)

Tian, Yanqing; Shumway, Bradley R; Youngbull, A Cody; Li, Yongzhong; Jen, Alex K-Y; Johnson, Roger H; Meldrum, Deirdre R

2010-06-03

Using a thermal polymerization approach and polymerizable pH and oxygen sensing monomers with green and red emission spectra, respectively, new pH, oxygen, and their dual sensing membranes were prepared using poly(2-hydroxyethyl methacrylate)-co-poly(acrylamide) as a matrix. The sensors were grafted on acrylate-modified quartz glass and characterized under different pH values, oxygen concentrations, ion strengths, temperatures and cell culture media. The pH and oxygen sensors were excited using the same excitation wavelength and exhibited well-separated emission spectra. The pH-sensing films showed good response over the pH range 5.5 to 8.5, corresponding to pK(a) values in the biologically-relevant range between 6.9 and 7.1. The oxygen-sensing films exhibited linear Stern-Volmer quenching responses to dissolved oxygen. As the sensing membranes were prepared using thermally initiated polymerization of sensing moiety-containing monomers, no leaching of the sensors from the membranes to buffers or medium was observed. This advantageous characteristic accounts in part for the sensors' biocompatibility without apparent toxicity to HeLa cells after 40 hours incubation. The dual-sensing membrane was used to measure pH and dissolved oxygen simultaneously. The measured results correlated with the set-point values.

Plutonium recovery from carbonate wash solutions

International Nuclear Information System (INIS)

Gray, J.H.; Reif, D.J.; Chostner, D.F.; Holcomb, H.P.

1991-01-01

540Periodically higher than expected levels of plutonium are found in carbonate solutions used to wash second plutonium cycle solvent. The recent accumulation of plutonium in carbonate wash solutions has led to studies to determine the cause of that plutonium accumulation, to evaluate the quality of all canyon solvents, and to develop additional criteria needed to establish when solvent quality is acceptable. Solvent from three canyon solvent extraction cycles was used to evaluate technology required to measure tributyl phosphate (TBP) degradation products and was used to evaluate solvent quality criteria during the development of plutonium recovery processes. 1 fig

Oxygen isotope exchange rate between dissolved sulfate and water at hydrothermal temperatures

International Nuclear Information System (INIS)

Chiba, H.; Sakai, H.

1985-01-01

Oxygen isotope exchange rate between dissolved sulfate and water was experimentally determined at 100, 200 and 300 deg C. The isotope exchange rate is strongly dependent on temperature and pH of the solution. Combining the temperature and pH dependence of the reaction rate, the exchange reaction was estimated to be first-order with respect to sulfate. The logarithm of apparent rate constant of exchange reaction at a given temperature is a function of the pH calculated at the experimental temperatures. From the pH dependence of the apparent rate constant, it was deduced that the isotope exchange reaction between dissolved sulfate and water proceeds through collision between H 2 SO 4 0 and H 2 O at low pH, and between HSO 4 - and H 2 O at intermediate pH. The isotope exchange rate obtained indicates that oxygen isotope geothermometry utilizing the studied isotope exchange is suitable for temperature estimation of geothermal reservoirs. The extrapolated half-life of this reaction to oceanic temperature is about 10 9 years, implying that exchange between oceanic sulfate and water cannot control the oxygen isotope ratio of oceanic sulfates. (author)

Anatomy of La Jolla submarine canyon system; offshore southern California

Science.gov (United States)

Paull, C.K.; Caress, D.W.; Lundsten, E.; Gwiazda, R.; Anderson, K.; McGann, M.; Conrad, J.; Edwards, B.; Sumner, E.J.

2013-01-01

An autonomous underwater vehicle (AUV) carrying a multibeam sonar and a chirp profiler was used to map sections of the seafloor within the La Jolla Canyon, offshore southern California, at sub-meter scales. Close-up observations and sampling were conducted during remotely operated vehicle (ROV) dives. Minisparker seismic-reflection profiles from a surface ship help to define the overall geometry of the La Jolla Canyon especially with respect to the pre-canyon host sediments. The floor of the axial channel is covered with unconsolidated sand similar to the sand on the shelf near the canyon head, lacks outcrops of the pre-canyon host strata, has an almost constant slope of 1.0° and is covered with trains of crescent shaped bedforms. The presence of modern plant material entombed within these sands confirms that the axial channel is presently active. The sand on the canyon floor liquefied during vibracore collection and flowed downslope, illustrating that the sediment filling the channel can easily fail even on this gentle slope. Data from the canyon walls help constrain the age of the canyon and extent of incision. Horizontal beds of moderately cohesive fine-grained sediments exposed on the steep canyon walls are consistently less than 1.232 million years old. The lateral continuity of seismic reflectors in minisparker profiles indicate that pre-canyon host strata extend uninterrupted from outside the canyon underneath some terraces within the canyon. Evidence of abandoned channels and point bar-like deposits are noticeably absent on the inside bend of channel meanders and in the subsurface of the terraces. While vibracores from the surface of terraces contain thin (art seafloor mapping and exploration tools provides a uniquely detailed view of the morphology within an active submarine canyon.

76 FR 56430 - Boulder Canyon Project

Science.gov (United States)

2011-09-13

... DEPARTMENT OF ENERGY Western Area Power Administration Boulder Canyon Project AGENCY: Western Area... Project (BCP) electric service provided by the Western Area Power Administration (Western). The Rates will... by the Boulder Canyon Project Act (45 Stat. 1057, December 21, 1928), sits on the Colorado River...

Lowering of the critical concentration for micelle formation in aqueous soap solutions by action of truly dissolved hydrocarbon at various temperatures

Energy Technology Data Exchange (ETDEWEB)

Markina, Z.N.; Kostova, N.Z.; Rebinder, P.A.

1970-03-01

The effect of dissolved hydrocarbons (octane, benzene, and ethylbenzene) on critical micelle concentration of aqueous solutions of sodium salts of fatty acids from caproate to sodium myristate at various temperatures was studied. Experimental results showed that formation of micelles is promoted by presence of hydrocarbons dissolved in the water phase. Such solutions have below normal critical micelle concentration. The change in critical micelle concentration decreases with increase in length of hydrocarbon chain in the soap molecule and with decrease of hydrocarbon solubility in pure water. The nature of the hydrocarbon also affects the forms and dimension of the micelle. Aromatic hydrocarbons increase micelle volume and greatly decrease C.M.C., while aliphatic hydrocarbons decrease C.M.C. slightly. (12 refs.)

Impact of height and shape of building roof on air quality in urban street canyons

Science.gov (United States)

Yassin, Mohamed F.

2011-09-01

A building's roof shape and roof height play an important role in determining pollutant concentrations from vehicle emissions and its complex flow patterns within urban street canyons. The impact of the roof shape and height on wind flow and dispersion of gaseous pollutants from vehicle exhaust within urban canyons were investigated numerically using a Computational Fluid Dynamics (CFD) model. Two-dimensional flow and dispersion of gaseous pollutants were analyzed using standard κ- ɛ turbulence model, which was numerically solved based on Reynolds Averaged Navier-Stokes (RANS) equations. The diffusion fields in the urban canyons were examined with three roof heights ( Z H/ H = 0.17, 0.33 and 0.5) and five roof shapes: (1) flat-shaped roof, (2) slanted-shaped roof, (3) downwind wedge-shaped roof, (4) upwind wedge-shaped roof, and (5) trapezoid-shaped roof. The numerical model was validated against the wind tunnels results in order to optimize the turbulence model. The numerical simulations agreed reasonably with the wind tunnel results. The results obtained indicated that the pollutant concentration increased as the roof height decreases. It also decreased with the slanted and trapezoid-shaped roofs but increased with the flat-shaped roof. The pollutant concentration distributions simulated in the present work, indicated that the variability of the roof shapes and roof heights of the buildings are important factors for estimating air quality within urban canyons.

Anatomy of La Jolla submarine canyon system; offshore southern California

Science.gov (United States)

Paull, C.K.; Caress, D.W.; Lundsten, E.; Gwiazda, R.; Anderson, K.; McGann, M.; Conrad, J.; Edwards, B.; Sumner, E.J.

2013-01-01

An autonomous underwater vehicle (AUV) carrying a multibeam sonar and a chirp profiler was used to map sections of the seafloor within the La Jolla Canyon, offshore southern California, at sub-meter scales. Close-up observations and sampling were conducted during remotely operated vehicle (ROV) dives. Minisparker seismic-reflection profiles from a surface ship help to define the overall geometry of the La Jolla Canyon especially with respect to the pre-canyon host sediments. The floor of the axial channel is covered with unconsolidated sand similar to the sand on the shelf near the canyon head, lacks outcrops of the pre-canyon host strata, has an almost constant slope of 1.0° and is covered with trains of crescent shaped bedforms. The presence of modern plant material entombed within these sands confirms that the axial channel is presently active. The sand on the canyon floor liquefied during vibracore collection and flowed downslope, illustrating that the sediment filling the channel can easily fail even on this gentle slope. Data from the canyon walls help constrain the age of the canyon and extent of incision. Horizontal beds of moderately cohesive fine-grained sediments exposed on the steep canyon walls are consistently less than 1.232 million years old. The lateral continuity of seismic reflectors in minisparker profiles indicate that pre-canyon host strata extend uninterrupted from outside the canyon underneath some terraces within the canyon. Evidence of abandoned channels and point bar-like deposits are noticeably absent on the inside bend of channel meanders and in the subsurface of the terraces. While vibracores from the surface of terraces contain thin (< 10 cm) turbidites, they are inferred to be part of a veneer of recent sediment covering pre-canyon host sediments that underpin the terraces. The combined use of state of the art seafloor mapping and exploration tools provides a uniquely detailed view of the morphology within an active submarine canyon.

Aerodynamic effects of trees on pollutant concentration in street canyons.

Science.gov (United States)

Buccolieri, Riccardo; Gromke, Christof; Di Sabatino, Silvana; Ruck, Bodo

2009-09-15

This paper deals with aerodynamic effects of avenue-like tree planting on flow and traffic-originated pollutant dispersion in urban street canyons by means of wind tunnel experiments and numerical simulations. Several parameters affecting pedestrian level concentration are investigated, namely plant morphology, positioning and arrangement. We extend our previous work in this novel aspect of research to new configurations which comprise tree planting of different crown porosity and stand density, planted in two rows within a canyon of street width to building height ratio W/H=2 with perpendicular approaching wind. Sulfur hexafluoride was used as tracer gas to model the traffic emissions. Complementary to wind tunnel experiments, 3D numerical simulations were performed with the Computational Fluid Dynamics (CFD) code FLUENT using a Reynolds Stress turbulence closure for flow and the advection-diffusion method for concentration calculations. In the presence of trees, both measurements and simulations showed considerable larger pollutant concentrations near the leeward wall and slightly lower concentrations near the windward wall in comparison with the tree-less case. Tree stand density and crown porosity were found to be of minor importance in affecting pollutant concentration. On the other hand, the analysis indicated that W/H is a more crucial parameter. The larger the value of W/H the smaller is the effect of trees on pedestrian level concentration regardless of tree morphology and arrangement. A preliminary analysis of approaching flow velocities showed that at low wind speed the effect of trees on concentrations is worst than at higher speed. The investigations carried out in this work allowed us to set up an appropriate CFD modelling methodology for the study of the aerodynamic effects of tree planting in street canyons. The results obtained can be used by city planners for the design of tree planting in the urban environment with regard to air quality issues.

Effects of Dissolving Solutions on the Accuracy of an Electronic Apex Locator-Integrated Endodontic Handpiece

Directory of Open Access Journals (Sweden)

Yakup Ustun

2013-01-01

Full Text Available The effects of three dissolving agents on the accuracy of an electronic apex locator- (EAL- integrated endodontic handpiece during retreatment procedures were evaluated. The true lengths (TLs of 56 extracted incisor teeth were determined visually. Twenty teeth were filled with gutta-percha and a resin-based sealer (group A, 20 with gutta-percha and a zinc oxide/eugenol-based sealer (group B, and 16 roots were used as the control group (group C. All roots were prepared to TL. Guttasolv, Resosolv, and Endosolv E were used as the dissolving solutions. Two evaluations of the handpiece were performed: the apical accuracy during the auto reverse function (ARL and the apex locator function (EL alone. The ARL function of the handpiece gave acceptable results. There were significant differences between the EL mode measurements and the TL (P<0.05. In these comparisons, Tri Auto ZX EL mode measurements were significantly shorter than those of the TL.

Recreational impacts on Colorado River beaches in Glen Canyon, Arizona

Science.gov (United States)

Carothers, Steven W.; Johnson, Robert A.; Dolan, Robert

1984-07-01

Recreational impact was measured on eight beaches in Glen Canyon National Recreation Area and 15 beaches in Grand Canyon National Park using permanently located transects and plots. Recreational impact indices included densities of human trash and charcoal and a measure of sand discoloration due to charcoal. Significant increases in the indices occurred on several Glen Canyon beaches over a seven-month period. Sand discoloration became significantly higher over all Glen Canyon beaches during the same time period. All indices were significantly higher in Glen Canyon than on similar Grand Canyon beaches. These differences are probably due to differences in: (a) level of impacts tolerated by the respective management regimes and, (b) in the number of user days among the two National Park Service administrative units. Management alternatives are presented for reversing the present trends of recreational impact on Glen Canyon beaches.

[Effects of forest regeneration patterns on the quantity and chemical structure of soil solution dissolved organic matter in a subtropical forest.

Science.gov (United States)

Yuan, Xiao Chun; Lin, Wei Sheng; Pu, Xiao Ting; Yang, Zhi Rong; Zheng, Wei; Chen, Yue Min; Yang, Yu Sheng

2016-06-01

Using the negative pressure sampling method, the concentrations and spectral characte-ristics of dissolved organic matter (DOM) of soil solution were studied at 0-15, 15-30, 30-60 cm layers in Castanopsis carlesii forest (BF), human-assisted naturally regenerated C. carlesii forest (RF), C. carlesii plantation (CP) in evergreen broad-leaved forests in Sanming City, Fujian Pro-vince. The results showed that the overall trend of dissolved organic carbon (DOC) concentrations in soil solution was RF>CP>BF, and the concentration of dissolved organic nitrogen (DON) was highest in C. carlesii plantation. The concentrations of DOC and DON in surface soil (0-15 cm) were all significantly higher than in the subsurface (30-60 cm). The aromatic index (AI) was in the order of RF>CP>BF, and as a whole, the highest AI was observed in the surface soil. Higher fluorescence intensity and a short wave absorption peak (320 nm) were observed in C. carlesii plantation, suggesting the surface soil of C. carlesii plantation was rich in decomposed substance content, while the degree of humification was lower. A medium wave absorption peak (380 nm) was observed in human-assisted naturally regenerated C. carlesii forest, indicating the degree of humification was higher which would contribute to the storage of soil fertility. In addition, DOM characte-ristics in 30-60 cm soil solution were almost unaffected by forest regeneration patterns.

Predicting nitrogen and acidity effects on long-term dynamics of dissolved organic matter

OpenAIRE

Rowe, E.C.; Tipping, E.; Posch, M.; Oulehle, Filip; Cooper, D.M.; Jones, T.G.; Burden, A.; Hall, J.; Evans, C.D.

2014-01-01

Increases in dissolved organic carbon (DOC) fluxes may relate to changes in sulphur and nitrogen pollution. We integrated existing models of vegetation growth and soil organic matter turnover, acid-base dynamics, and organic matter mobility, to form the ‘MADOC’ model. After calibrating parameters governing interactions between pH and DOC dissolution using control treatments on two field experiments, MADOC reproduced responses of pH and DOC to additions of acidifying and alkalising solutions. ...

Deepwater Canyons 2013: Pathways to the Abyss

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — Leg I focused on biological objectives in Norfolk Canyon, with some sampling in Baltimore Canyon. Leg II focused on archaeological targets in and around the Norfolk...

Capabilities and modification plans for the Savannah River New Special Recovery facilities

International Nuclear Information System (INIS)

Gray, L.W.; Molen, G.F.; Lynn, J.M.

1986-01-01

The Savannah River New Special Recovery (NSR) facility is located in the 200-F Separations Area. This facility was designed and constructed to convert easily dissolvable plutonium oxides and metal from both onsite and offsite residues to plutonium nitrate-nitric acid solution. Capabilities were provided to purify a portion of the clarified dissolver solutions via anion exchange. The primary purification is provided by the 221-F canyon solvent extraction system. Minimal capacity was provided to handle slurries from poorly dissolving materials. The Actinide Technology Division of the Savannah River Laboratory is presently engaged in R and D to enhance both the solids throughput of the dissolvers and the feed clarification methods

Surface micro-dissolve method of imparting self-cleaning property to cotton fabrics in NaOH/urea aqueous solution

Energy Technology Data Exchange (ETDEWEB)

Fan, Tao; Hu, Ruimin; Zhao, Zhenyun [College of Textile & Garment, Southwest University, 400716, Chongqing (China); Liu, Yiping [College of Textile & Garment, Southwest University, 400716, Chongqing (China); Chongqing Engineering Research Center of Biomaterial Fiber and Modern Textile, 400716, Chongqing (China); Lu, Ming, E-mail: lumingswu@163.com [College of Textile & Garment, Southwest University, 400716, Chongqing (China); Chongqing Engineering Research Center of Biomaterial Fiber and Modern Textile, 400716, Chongqing (China)

2017-04-01

Highlights: • A novel micro-dissolved process was carried out to embedding commercial titanium dioxide nanoparticles into cotton fabric with NaOH/urea aqueous solution. • X-ray diffraction pattern of modified fabrics shown that the cellulose structure of modified fabrics had not changed. • Modified cotton fabrics demonstrated favourable photocatalytic self-cleaning performance while tensile strength and whiteness of treated fabrics also expressed an increasement slightly. - Abstract: A simple and economical micro-dissolved process of embedding titanium dioxide (TiO{sub 2}) nanoparticles into surface zone of cotton fabrics was developed. TiO{sub 2} was coated on cotton fabrics in 7% wt NaOH/12% wt urea aqueous solution at low temperature. Photocatalytic efficiency of cotton fabrics treated with TiO{sub 2} nanoparticles was studied upon measuring the photocatalytic decoloration of Rhodamine B (RhB) under ultraviolet irradiation. Self-cleaning property of cotton fabric coated with TiO{sub 2} was evaluated with color depth of samples (K/S value). The treated fabrics were characterized using scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), Fourier transform infrared spectroscopy (FITR), tensile strength, stiffness and whiteness. The results indicated, TiO{sub 2} nanoparticles could be embedded on the surface layer of cotton fabrics throuth surface micro-dissolve method. Treated cotton fabrics possessed distinct photocatalytic efficiency and self-cleaning properties. Tensile strength and whiteness of modified cotton fabrics appeared moderately increasement.

Evaluation of numerical flow and dispersion simulations for street canyons with avenue-like tree planting by comparison with wind tunnel data

OpenAIRE

Gromke, CB Christof; Buccolieri, R; Sabatino, S Di; Ruck, B

2008-01-01

Abstract: Flow and traffic-originated pollutant dispersion in an urban street canyon with avenue-like tree planting have been studied by means of wind tunnel and CFD investigations. The study comprises tree planting of different crown porosity, planted in two rows within a canyon of street width to building height ratio W/H = 2 and street length to building height ratio L/H = 10 exposed to a perpendicular approaching boundary layer flow. Numerical simulations have been performed with...

Effects of canyon geometry on the distribution of traffic-related air pollution in a large urban area: Implications of a multi-canyon air pollution dispersion model

Science.gov (United States)

Fu, Xiangwen; Liu, Junfeng; Ban-Weiss, George A.; Zhang, Jiachen; Huang, Xin; Ouyang, Bin; Popoola, Olalekan; Tao, Shu

2017-09-01

Street canyons are ubiquitous in urban areas. Traffic-related air pollutants in street canyons can adversely affect human health. In this study, an urban-scale traffic pollution dispersion model is developed considering street distribution, canyon geometry, background meteorology, traffic assignment, traffic emissions and air pollutant dispersion. In the model, vehicle exhausts generated from traffic flows first disperse inside street canyons along the micro-scale wind field generated by computational fluid dynamics (CFD) model. Then, pollutants leave the street canyon and further disperse over the urban area. On the basis of this model, the effects of canyon geometry on the distribution of NOx and CO from traffic emissions were studied over the center of Beijing. We found that an increase in building height leads to heavier pollution inside canyons and lower pollution outside canyons at pedestrian level, resulting in higher domain-averaged concentrations over the area. In addition, canyons with highly even or highly uneven building heights on each side of the street tend to lower the urban-scale air pollution concentrations at pedestrian level. Further, increasing street widths tends to lead to lower pollutant concentrations by reducing emissions and enhancing ventilation simultaneously. Our results indicate that canyon geometry strongly influences human exposure to traffic pollutants in the populated urban area. Carefully planning street layout and canyon geometry while considering traffic demand as well as local weather patterns may significantly reduce inhalation of unhealthy air by urban residents.

Characteristics of flow and reactive pollutant dispersion in urban street canyons

Science.gov (United States)

Park, Soo-Jin; Kim, Jae-Jin; Kim, Minjoong J.; Park, Rokjin J.; Cheong, Hyeong-Bin

2015-05-01

In this study, the effects of aspect ratio defined as the ratio of building height to street width on the dispersion of reactive pollutants in street canyons were investigated using a coupled CFD-chemistry model. Flow characteristics for different aspect ratios were analyzed first. For each aspect ratio, six emission scenarios with different VOC-NOX ratios were considered. One vortex was generated when the aspect ratio was less than 1.6 (shallow street canyon). When the aspect ratio was greater than 1.6 (deep street canyon), two vortices were formed in the street canyons. Comparing to previous studies on two-dimensional street canyons, the vortex center is slanted toward the upwind building and reverse and downward flows are dominant in street canyons. Near the street bottom, there is a marked difference in flow pattern between in shallow and deep street canyons. Near the street bottom, reverse and downward flows are dominant in shallow street canyon and flow convergence exists near the center of the deep street canyons, which induces a large difference in the NOX and O3 dispersion patterns in the street canyons. NOX concentrations are high near the street bottom and decreases with height. The O3 concentrations are low at high NO concentrations near the street bottom because of NO titration. At a low VOC-NOX ratio, the NO concentrations are sufficiently high to destroy large amount of O3 by titration, resulting in an O3 concentration in the street canyon much lower than the background concentration. At high VOC-NOX ratios, a small amount of O3 is destroyed by NO titration in the lower layer of the street canyons. However, in the upper layer, O3 is formed through the photolysis of NO2 by VOC degradation reactions. As the aspect ratio increases, NOX (O3) concentrations averaged over the street canyons decrease (increase) in the shallow street canyons. This is because outward flow becomes strong and NOX flux toward the outsides of the street canyons increases

Iron traps terrestrially derived dissolved organic matter at redox interfaces

Science.gov (United States)

Riedel, Thomas; Zak, Dominik; Biester, Harald; Dittmar, Thorsten

2013-01-01

Reactive iron and organic carbon are intimately associated in soils and sediments. However, to date, the organic compounds involved are uncharacterized on the molecular level. At redox interfaces in peatlands, where the biogeochemical cycles of iron and dissolved organic matter (DOM) are coupled, this issue can readily be studied. We found that precipitation of iron hydroxides at the oxic surface layer of two rewetted fens removed a large fraction of DOM via coagulation. On aeration of anoxic fen pore waters, >90% of dissolved iron and 27 ± 7% (mean ± SD) of dissolved organic carbon were rapidly (within 24 h) removed. Using ultra-high-resolution MS, we show that vascular plant-derived aromatic and pyrogenic compounds were preferentially retained, whereas the majority of carboxyl-rich aliphatic acids remained in solution. We propose that redox interfaces, which are ubiquitous in marine and terrestrial settings, are selective yet intermediate barriers that limit the flux of land-derived DOM to oceanic waters. PMID:23733946

The extraction of trace amounts of gold from different aqueous mineral acid solutions by diphenyl-2-pyridylmethane dissolved in chloroform

International Nuclear Information System (INIS)

Iqbal, M.; Ejaz, M.; Chaudhri, S.A.; Zamiruddin

1978-01-01

Diphenyl-2-pyridylmethane, a high-molecular-weight substituted pyridine has been examined. Its behaviour is similar to that of amines in that it forms salts with mineral acids. The acid ionization constant (pKsub(BHsup(+)) is 4.4+-0.06 at 25 deg C. A study of the partition behaviour of trace amounts of gold between mineral acid solutions and 0.1 M diphenyl-2-pyridylmethane dissolved in chloroform indicates that the metal can be quantitatively extracted from dilute mineral acid solutions and also from concentrated hydrochloric acid media in a single extraction. Common anions have little effect on extraction in concentrations up to 1 M. Separation factors of a number of metal ions relative to gold are reported for three mineral acid systems. Gold has been estimated in some synthetic samples using a neutron-activation technique by prior extraction with 0.1 M solution of diphenyl-2-pyridylmethane dissolved in chloroform. Distribution of the test elements between aqueous and organic phase was followed radiometrically. The solutions (usually 1 cm 3 ) were shaken in stoppered vials for 5 minutes using a mechanical shaker. After separation of the layers, 500 μl of each phase were taken for radiochemical analysis. The standard deviation did not exceed 1%. (T.G.)

Inhibitory Effect of Dissolved Silica on the H2O2 Decomposition by Iron(III) and Manganese(IV) Oxides: Implications for H2O2-based In Situ Chemical Oxidation

Science.gov (United States)

Pham, Anh Le-Tuan; Doyle, Fiona M.; Sedlak, David L.

2011-01-01

The decomposition of H2O2 on iron minerals can generate •OH, a strong oxidant that can transform a wide range of contaminants. This reaction is critical to In Situ Chemical Oxidation (ISCO) processes used for soil and groundwater remediation, as well as advanced oxidation processes employed in waste treatment systems. The presence of dissolved silica at concentrations comparable to those encountered in natural waters decreases the reactivity of iron minerals toward H2O2, because silica adsorbs onto the surface of iron minerals and alters catalytic sites. At circumneutral pH values, goethite, amorphous iron oxide, hematite, iron-coated sand and montmorillonite that were pre-equilibrated with 0.05 – 1.5 mM SiO2 were significantly less reactive toward H2O2 decomposition than their original counterparts, with the H2O2 loss rates inversely proportional to the SiO2 concentration. In the goethite/H2O2 system, the overall •OH yield, defined as the percentage of decomposed H2O2 producing •OH, was almost halved in the presence of 1.5 mM SiO2. Dissolved SiO2 also slows the H2O2 decomposition on manganese(IV) oxide. The presence of dissolved SiO2 results in greater persistence of H2O2 in groundwater, lower H2O2 utilization efficiency and should be considered in the design of H2O2-based treatment systems. PMID:22129132

Compilation of PRF Canyon Floor Pan Sample Analysis Results

Energy Technology Data Exchange (ETDEWEB)

Pool, Karl N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Minette, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wahl, Jon H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Greenwood, Lawrence R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Coffey, Deborah S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); McNamara, Bruce K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bryan, Samuel A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Scheele, Randall D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sinkov, Sergey I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Soderquist, Chuck Z. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fiskum, Sandra K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Brown, Garrett N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Clark, Richard A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-06-30

On September 28, 2015, debris collected from the PRF (236-Z) canyon floor, Pan J, was observed to exhibit chemical reaction. The material had been transferred from the floor pan to a collection tray inside the canyon the previous Friday. Work in the canyon was stopped to allow Industrial Hygiene to perform monitoring of the material reaction. Canyon floor debris that had been sealed out was sequestered at the facility, a recovery plan was developed, and drum inspections were initiated to verify no additional reactions had occurred. On October 13, in-process drums containing other Pan J material were inspected and showed some indication of chemical reaction, limited to discoloration and degradation of inner plastic bags. All Pan J material was sealed back into the canyon and returned to collection trays. Based on the high airborne levels in the canyon during physical debris removal, ETGS (Encapsulation Technology Glycerin Solution) was used as a fogging/lock-down agent. On October 15, subject matter experts confirmed a reaction had occurred between nitrates (both Plutonium Nitrate and Aluminum Nitrate Nonahydrate (ANN) are present) in the Pan J material and the ETGS fixative used to lower airborne radioactivity levels during debris removal. Management stopped the use of fogging/lock-down agents containing glycerin on bulk materials, declared a Management Concern, and initiated the Potential Inadequacy in the Safety Analysis determination process. Additional drum inspections and laboratory analysis of both reacted and unreacted material are planned. This report compiles the results of many different sample analyses conducted by the Pacific Northwest National Laboratory on samples collected from the Plutonium Reclamation Facility (PRF) floor pans by the CH2MHill’s Plateau Remediation Company (CHPRC). Revision 1 added Appendix G that reports the results of the Gas Generation Rate and methodology. The scope of analyses requested by CHPRC includes the determination of

Effect of halogen substitution on the enthalpies of solvation and hydrogen bonding of organic solutes in chlorobenzene and 1,2-dichlorobenzene derived using multi-parameter correlations

Energy Technology Data Exchange (ETDEWEB)

Varfolomeev, Mikhail A.; Rakipov, Ilnaz T.; Khachatrian, Artashes A. [Department of Physical Chemistry, Kazan Federal University, Kremlevskaya 18, Kazan 420008 (Russian Federation); Acree, William E., E-mail: acree@unt.edu [Department of Chemistry, 1155 Union Circle # 305070, University of North Texas, Denton, TX 76203-5017 (United States); Brumfield, Michela [Department of Chemistry, 1155 Union Circle # 305070, University of North Texas, Denton, TX 76203-5017 (United States); Abraham, Michael H. [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)

2015-10-10

Graphical abstract: - Highlights: • Enthalpies of solution measured for 43 solutes dissolved in chlorobenzene. • Enthalpies of solution measured for 72 solutes dissolved in 1,2-dichlorobenzene. • Mathematical expressions derived for predicting enthalpies of solvation of solutes in chlorobenzene. • Mathematical expressions derived for predicting enthalpies of solvation of solutes in 1,2-chlorobenzene. - Abstract: Enthalpies of solution at infinite dilution at 298 K, Δ{sub soln}H{sup A/Solvent}, have been measured by isothermal solution calorimetry for 43 and 72 organic solutes dissolved in chlorobenzene and 1,2-dichlorobenzene, respectively. The measured Δ{sub soln}H{sup A/Solvent} data, along with published Δ{sub soln}H{sup A/Solvent} values taken from the published literature for solutes dissolved in both chlorobenzene solvents, were converted to enthalpies of solvation, Δ{sub solv}H{sup A/Solvent}, using standard thermodynamic equations. Abraham model correlations were developed from the experimental Δ{sub solv}H{sup A/Solvent} data. The best derived correlations describe the experimental gas-to-chlorobenzene and gas-to-1,2-dichlorobenzene enthalpies of solvation to within standard deviations of 1.5 kJ mol{sup −1} and 1.9 kJ mol{sup −1}, respectively. Enthalpies of X−H…π (X – O, N, and C) hydrogen bond formation of proton donor solutes (alcohols, amines, chlorinated hydrocarbons, etc.) with chlorobenzene and 1,2-dichlorobenzene were calculated based on the Abraham solvation equation. Obtained values are in good agreement with the results determined using conventional methods.

Complexation with dissolved organic matter and solubility control of heavy metals in sandy soil

NARCIS (Netherlands)

Weng, L.; Temminghoff, E.J.M.; Lofts, S.; Tipping, E.; Riemsdijk, van W.H.

2002-01-01

The complexation of heavy metals with dissolved organic matter (DOM) in the environment influences the solubility and mobility of these metals. In this paper, we measured the complexation of Cu, Cd, Zn, Ni, and Pb with DOM in the soil solution at pH 3.7-6.1 using a Donnan membrane technique. The

Accumulation of dissolved gases at hydrophobic surfaces in water and sodium chloride solutions: Implications for coal flotation

Energy Technology Data Exchange (ETDEWEB)

Hampton, M.A.; Nguyen, A.V. [University of Queensland, Brisbane, Qld. (Australia). Division of Chemical Engineering

2009-08-15

Dissolved gases can preferentially accumulate at the hydrophobic solid-water interface as revealed by neutron reflectivity measurements. In this paper, atomic force microscopy (AFM) was used to examine accumulation of dissolved gases at a hydrophobic surface in water and sodium chloride solutions. The solvent-exchange method was used to artificially form gaseous domains accumulated at the interface suitable for AFM imaging. Smooth graphite surfaces were used as model surfaces to minimize the secondary effect of surface roughness on the imaging. The concentration of NaCl up to 1 M was found to have a negligible influence on the geometry and population of pre-existing nanobubbles, nanopancakes and nanobubble-nanopancake composites. The implications of the findings on coal flotation in saline water are discussed in terms of attraction between hydrophobic surfaces in water, bubble-particle attachment and hydrophobic coagulation between particles.

Marble Canyon 10 x 20 NTMS area Arizona: data report

International Nuclear Information System (INIS)

Heffner, J.D.

1980-07-01

Results of ground water and stream/surface sediment reconnaissance (HSSR) in the National Topographic Map Series (NTMS) Marble Canyon 1 0 x 2 0 quadrangle are presented. The target sampling density for all media collected was one site per 12 square kilometers. This resulted in 884 sediment samples being collected; however, dry conditions and sparse population resulted in the collection of only 2 ground water samples. Grand Canyon National Park, Glen Canyon National Recreation Area, and much Indian tribal land in the southern half of the quadrangle were not sampled. Neutron activation analysis (NAA) results are given for uranium and 16 other elements in sediments, and for uranium and 9 other elements in ground water. Mass spectrometry results are given for helium in ground water. Field measurements for sediment samples are presented in tables and maps. Statistical summaries of data and a brief description of results are given. A generalized geologic map and a summary of the geology of the area are included. Data from ground water include: water chemistry measurements (pH, conductivity, and alkalinity); physical measurements (water temperature, and scintillometer readings); and elemental analyses (U, Al, Br, Cl, Dy, F, He, Mg, Mn, Na, and V). Data from sediment sites include: water chemistry measurements (where available) for pH, conductivity, and alkalinity; and elemental analyses(U, Th, Hf, Al, Ce, Dy, Eu, Fe, La, Lu, Mn, Sc, Sm, Na, Ti, V, and Yb). Sample site descriptors (stream characteristics, vegetation, etc.) are also tabulated. Histograms, cumulative frequency, and areal distribution plots for most elements; Log U/Th, Log U/Hf, and Log U/(Th + Hf) ratios; and scintillometer readings are included

Surface modification of polystyrene with atomic oxygen radical anions-dissolved solution

International Nuclear Information System (INIS)

Wang Lian; Yan Lifeng; Zhao Peitao; Torimoto, Yoshifumi; Sadakata, Masayoshi; Li Quanxin

2008-01-01

A novel approach to surface modification of polystyrene (PS) polymer with atomic oxygen radical anions-dissolved solution (named as O - water) has been investigated. The O - water, generated by bubbling of the O - (atomic oxygen radical anion) flux into the deionized water, was characterized by UV-absorption spectroscopy and electron paramagnetic resonance (EPR) spectroscopy. The O - water treatments caused an obvious increase of the surface hydrophilicity, surface energy, surface roughness and also caused an alteration of the surface chemical composition for PS surfaces, which were indicated by the variety of contact angle and material characterization by atomic force microscope (AFM) imaging, field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), and attenuated total-reflection Fourier transform infrared (ATR-FTIR) measurements. Particularly, it was found that some hydrophilic groups such as hydroxyl (OH) and carbonyl (C=O) groups were introduced onto the polystyrene surfaces via the O - water treatment, leading to the increases of surface hydrophilicity and surface energy. The active oxygen species would react with the aromatic ring molecules on the PS surfaces and decompose the aromatic compounds to produce hydrophilic hydroxyl and carbonyl compounds. In addition, the O - water is also considered as a 'clean solution' without adding any toxic chemicals and it is easy to be handled at room temperature. Present method may suit to the surface modification of polymers and other heat-sensitive materials potentially

77 FR 22801 - Glen Canyon Dam Adaptive Management Work Group

Science.gov (United States)

2012-04-17

... DEPARTMENT OF THE INTERIOR Bureau of Reclamation Glen Canyon Dam Adaptive Management Work Group...). SUMMARY: The Glen Canyon Dam Adaptive Management Work Group (AMWG) makes recommendations to the Secretary..., the AMWG, a technical work group, a Grand Canyon Monitoring and Research Center, and independent...

Versatile common instrumentation for optical detection of pH and dissolved oxygen

Energy Technology Data Exchange (ETDEWEB)

Sardesai, Neha [Department of Computer Science and Electrical Engineering, University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250 (United States); Rao, Govind [Center for Advanced Sensor Technology and Department of Chemical, Biochemical, and Environmental Engineering, University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250 (United States); Kostov, Yordan, E-mail: kostov@umbc.edu [Department of Computer Science and Electrical Engineering, University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250 (United States); Center for Advanced Sensor Technology and Department of Chemical, Biochemical, and Environmental Engineering, University of Maryland Baltimore County, 1000 Hilltop Circle, Baltimore, Maryland 21250 (United States)

2015-07-15

The recent trend toward use of disposable and miniature bioreactors requires the use of appropriate sensors. pH and dissolved oxygen (DO) are often measured using optical chemical sensors due to their small form factor and convenience in use. These sensors are often interrogated using a specialized opto-electronic transducer that is designed around the optical sensor. In this contribution, we are presenting a new class of opto-electronic transducers that are usable with several different chemical sensors without the need to switch the optics or hardware when changing the type of the chemical sensor. This allows flexibility closer to the lab-grade devices while the size is closer to a dedicated sensor. This versatile instrumentation is capable of seamlessly switching between the pH and DO measurement modes and is capable of auto recognition of the sensor type. The principle of ratiometric fluorescence is used for pH measurements, and that of fluorescence lifetime for DO measurements. An approach to obtain identical calibrations between several devices is also presented. The described hardware constitutes common instrumentation for measuring either pH or DO and has been tested in actual bioprocesses. It has been found adequate for continuous bioprocess monitoring.

Versatile common instrumentation for optical detection of pH and dissolved oxygen

International Nuclear Information System (INIS)

Sardesai, Neha; Rao, Govind; Kostov, Yordan

2015-01-01

The recent trend toward use of disposable and miniature bioreactors requires the use of appropriate sensors. pH and dissolved oxygen (DO) are often measured using optical chemical sensors due to their small form factor and convenience in use. These sensors are often interrogated using a specialized opto-electronic transducer that is designed around the optical sensor. In this contribution, we are presenting a new class of opto-electronic transducers that are usable with several different chemical sensors without the need to switch the optics or hardware when changing the type of the chemical sensor. This allows flexibility closer to the lab-grade devices while the size is closer to a dedicated sensor. This versatile instrumentation is capable of seamlessly switching between the pH and DO measurement modes and is capable of auto recognition of the sensor type. The principle of ratiometric fluorescence is used for pH measurements, and that of fluorescence lifetime for DO measurements. An approach to obtain identical calibrations between several devices is also presented. The described hardware constitutes common instrumentation for measuring either pH or DO and has been tested in actual bioprocesses. It has been found adequate for continuous bioprocess monitoring

Enhanced Indirect Photochemical Transformation of Histidine and Histamine through Association with Chromophoric Dissolved Organic Matter.

Science.gov (United States)

Chu, Chiheng; Lundeen, Rachel A; Remucal, Christina K; Sander, Michael; McNeill, Kristopher

2015-05-05

Photochemical transformations greatly affect the stability and fate of amino acids (AAs) in sunlit aquatic ecosystems. Whereas the direct phototransformation of dissolved AAs is well investigated, their indirect photolysis in the presence of chromophoric dissolved organic matter (CDOM) is poorly understood. In aquatic systems, CDOM may act both as sorbent for AAs and as photosensitizer, creating microenvironments with high concentrations of photochemically produced reactive intermediates, such as singlet oxygen (1O2). This study provides a systematic investigation of the indirect photochemical transformation of histidine (His) and histamine by 1O2 in solutions containing CDOM as a function of solution pH. Both His and histamine showed pH-dependent enhanced phototransformation in the CDOM systems as compared to systems in which model, low-molecular-weight 1O2 sensitizers were used. Enhanced reactivity resulted from sorption of His and histamine to CDOM and thus exposure to elevated 1O2 concentrations in the CDOM microenvironment. The extent of reactivity enhancement depended on solution pH via its effects on the protonation state of His, histamine, and CDOM. Sorption-enhanced reactivity was independently supported by depressed rate enhancements in the presence of a cosorbate that competitively displaced His and histamine from CDOM. Incorporating sorption and photochemical transformation processes into a reaction rate prediction model improved the description of the abiotic photochemical transformation rates of His in the presence of CDOM.

Crossing fitness canyons by a finite population

Science.gov (United States)

Saakian, David B.; Bratus, Alexander S.; Hu, Chin-Kun

2017-06-01

We consider the Wright-Fisher model of the finite population evolution on a fitness landscape defined in the sequence space by a path of nearly neutral mutations. We study a specific structure of the fitness landscape: One of the intermediate mutations on the mutation path results in either a large fitness value (climbing up a fitness hill) or a low fitness value (crossing a fitness canyon), the rest of the mutations besides the last one are neutral, and the last sequence has much higher fitness than any intermediate sequence. We derive analytical formulas for the first arrival time of the mutant with two point mutations. For the first arrival problem for the further mutants in the case of canyon crossing, we analytically deduce how the mean first arrival time scales with the population size and fitness difference. The location of the canyon on the path of sequences has a crucial role. If the canyon is at the beginning of the path, then it significantly prolongs the first arrival time; otherwise it just slightly changes it. Furthermore, the fitness hill at the beginning of the path strongly prolongs the arrival time period; however, the hill located near the end of the path shortens it. We optimize the first arrival time by applying a nonzero selection to the intermediate sequences. We extend our results and provide a scaling for the valley crossing time via the depth of the canyon and population size in the case of a fitness canyon at the first position. Our approach is useful for understanding some complex evolution systems, e.g., the evolution of cancer.

Photocatalytic degradation of H2S aqueous media using sulfide nanostructured solid-solution solar-energy-materials to produce hydrogen fuel.

Science.gov (United States)

Lashgari, Mohsen; Ghanimati, Majid

2018-03-05

H 2 S is a corrosive, flammable and noxious gas, which can be neutralized by dissolving in alkaline media and employed as H 2 -source by utilizing inside semiconductor-assisted/photochemical reactors. Herein, through a facile hydrothermal route, a ternary nanostructured solid-solution of iron, zinc and sulfur was synthesized in the absence and presence of Ag-dopant, and applied as efficient photocatalyst of hydrogen fuel production from H 2 S media. The effect of pH on the photocatalyst performance was scrutinized and the maximum activity was attained at pH=11, where HS - concentration is high. BET, diffuse reflectance and photoluminescence studies indicated that the ternary solid-solution photocatalyst, in comparison to its solid-solvent (ZnS), has a greater surface area, stronger photon absorption and less charge recombination, which justify its superiority. Moreover, the effect of silver-dopant on the photocatalyst performance was examined. The investigations revealed that although silver could boost the absorption of photons and increase the surface area, it could not appreciably enhance the photocatalyst performance due to its weak influence on retarding the charge-recombination process. Finally, the phenomenon was discussed in detail from mechanistic viewpoint. Copyright © 2017 Elsevier B.V. All rights reserved.

Formation of Hg(II) Tetrathiolate Complexes with Cysteine at Neutral pH.

Science.gov (United States)

Warner, Thomas; Jalilehvand, Farideh

2016-04-01

Mercury(II) ions precipitate from aqueous cysteine (H 2 Cys) solutions containing H 2 Cys/Hg(II) mole ratio ≥ 2.0 as Hg( S -HCys) 2 . In absence of additional cysteine, the precipitate dissolves at pH ~12 with the [Hg( S,N -Cys) 2 ] 2- complex dominating. With excess cysteine (H 2 Cys/Hg(II) mole ratio ≥ 4.0), higher complexes form and the precipitate dissolves at lower pH values. Previously, we found that tetrathiolate [Hg( S -Cys) 4 ] 6- complexes form at pH = 11.0; in this work we extend the investigation to pH values of physiological interest. We examined two series of Hg(II)-cysteine solutions in which C Hg(II) varied between 8 - 9 mM and 80 - 100 mM, respectively, with H 2 Cys/Hg(II) mole ratios from 4 to ~20. The solutions were prepared in the pH range 7.1 - 8.8, at the pH at which the initial Hg( S -HCys) 2 precipitate dissolved. The variations in the Hg(II) speciation were followed by 199 Hg NMR, X-ray absorption and Raman spectroscopic techniques. Our results show that in the dilute solutions ( C Hg(II) = 8 - 9 mM), mixtures of di-, tri- (major) and tetrathiolate complexes exist at moderate cysteine excess ( C H2Cys ~ 0.16 M) at pH 7.1. In the more concentrated solutions ( C Hg(II) = 80 - 100 mM) with high cysteine excess ( C H2Cys > 0.9 M), tetrathiolate [Hg( S -cysteinate) 4 ] m -6 ( m = 0 - 4) complexes dominate in the pH range 7.3 - 7.8, with lower charge than for the [Hg( S -Cys) 4 ] 6- complex due to protonation of some ( m ) of the amino groups of the coordinated cysteine ligands. The results of this investigation could provide a key to the mechanism of biosorption and accumulation of Hg(II) ions in biological / environmental systems.

[Effect of greenbelt on pollutant dispersion in street canyon].

Science.gov (United States)

Xu, Wei-Jia; Xing, Hong; Yu, Zhi

2012-02-01

The effect feature of greenbelt on flow field and pollutant dispersion in urban street canyon was researched. The greenbelt was assumed as uniform porous media and its aerodynamics property defined by the pressure loss coefficient. Subsequently, the pollutant dispersion in the street canyon of which there was greenbelt in the middle was simulated with the steady-state standard kappa-epsilon turbulence model and species transport equation. The simulated results agreed well with the wind-tunnel data. Compared with the treeless case, it finds that the street canyon contain a clockwise vortex, the pollutant concentration of the leeward was several times than the windward and the growth rate of pollutant concentration was 46.0%. The further simulation for the impact of tree crown position on the airflow and pollutant dispersion finds that the height of major vortex center in the street canyon increases with the height of tree crown and gradually closes the top of windward building This causes that the average wind speed in the street canyon decreases. Especially when the top of tree crown over the roof and hinder the air flow above the street canyon, the average pollutant concentration increases with the height of tree crown rapidly.

Concentration dependences of the density, viscosity, and refraction index of Cu(NO3)2 · 3H2O solutions in DMSO at 298 K

Science.gov (United States)

Mamyrbekova, A. K.

2013-03-01

Physicochemical properties (density, dynamic viscosity, refraction index) of the DMSO-Cu(NO3)2 · 3H2O system are studied in the concentration range of 0.01-2 M at 298 K. The refraction index of a solution of copper(II) nitrate in dimethylsulfoxide (DMSO) is measured at 288-318 K. The excess and partial molar volumes of the solvent and dissolved substance are calculated analytically.

Precipitation of plutonium from acidic solutions using magnesium oxide

International Nuclear Information System (INIS)

Jones, S.A.

1994-01-01

Magnesium oxide will be used as a neutralizing agent for acidic plutonium-containing solutions. It is expected that as the magnesium oxide dissolves, the pH of the solution will rise, and plutonium will precipitate. The resulting solid will be tested for suitability to storage. The liquid is expected to contain plutonium levels that meet disposal limit requirements

Erosion during extreme flood events dominates Holocene canyon evolution in northeast Iceland.

Science.gov (United States)

Baynes, Edwin R C; Attal, Mikaël; Niedermann, Samuel; Kirstein, Linda A; Dugmore, Andrew J; Naylor, Mark

2015-02-24

Extreme flood events have the potential to cause catastrophic landscape change in short periods of time (10(0) to 10(3) h). However, their impacts are rarely considered in studies of long-term landscape evolution (>10(3) y), because the mechanisms of erosion during such floods are poorly constrained. Here we use topographic analysis and cosmogenic (3)He surface exposure dating of fluvially sculpted surfaces to determine the impact of extreme flood events within the Jökulsárgljúfur canyon (northeast Iceland) and to constrain the mechanisms of bedrock erosion during these events. Surface exposure ages allow identification of three periods of intense canyon cutting about 9 ka ago, 5 ka ago, and 2 ka ago during which multiple large knickpoints retreated large distances (>2 km). During these events, a threshold flow depth was exceeded, leading to the toppling and transportation of basalt lava columns. Despite continuing and comparatively large-scale (500 m(3)/s) discharge of sediment-rich glacial meltwater, there is no evidence for a transition to an abrasion-dominated erosion regime since the last erosive event because the vertical knickpoints have not diffused over time. We provide a model for the evolution of the Jökulsárgljúfur canyon through the reconstruction of the river profile and canyon morphology at different stages over the last 9 ka and highlight the dominant role played by extreme flood events in the shaping of this landscape during the Holocene.

Geomorphic Thresholds of Submarine Canyons Along the U.S. Atlantic Continental Margin

Science.gov (United States)

Brothers, D. S.; ten Brink, U. S.; Andrews, B. D.; Chaytor, J. D.

2011-12-01

Vast networks of submarine canyons and associated channels are incised into the U.S. Atlantic continental slope and rise. Submarine canyons form by differential erosion and deposition, primarily from sedimentary turbidity flows. Theoretical and laboratory studies have investigated the initiation of turbidity flows and their capacity to erode and entrain sedimentary material at distances far from the shelf edge. The results have helped understand the nature of turbidite deposits on the continental slope and rise. Nevertheless, few studies have examined the linkages between down-canyon sediment transport and the morphology of canyon/channel networks using mesoscale analyses of swath bathymetry data. We present quantitative analysis of 100-m resolution multibeam bathymetry data spanning ~616,000 km2 of the slope and rise between Georges Banks and the Blake Plateau (New England to North Carolina). Canyons are categorized as shelf-indenting or slope-confined based on spatial scale, vertical relief and connection with terrestrial river systems during sea level low stands. Shelf-indenting canyons usually represent the trunk-canyon of submerged channel networks. On the rise, shelf-indenting canyons have relatively well-developed channel-levees and sharp inner-thalwag incision suggesting much higher frequency and volume of turbidity flows. Because of the similarities between submarine canyon networks and terrestrial river systems, we apply methods originally developed to study fluvial morphology. Along-canyon profiles are extracted from the bathymetry data and the power-law relationship between thalwag gradient and drainage area is examined for more than 180 canyons along an ~1200 km stretch of the US Atlantic margin. We observe distinct thresholds in the power-law relationship between drainage area and gradient. Almost all canyons with heads on the upper slope contain at least two linear segments when plotted in log-log form. The first segment along the upper slope is flat

Modern landscape processes affecting archaeological sites along the Colorado River corridor downstream of Glen Canyon Dam, Glen Canyon National Recreation Area, Arizona

Science.gov (United States)

East, Amy E.; Sankey, Joel B.; Fairley, Helen C.; Caster, Joshua J.; Kasprak, Alan

2017-08-29

The landscape of the Colorado River through Glen Canyon National Recreation Area formed over many thousands of years and was modified substantially after the completion of Glen Canyon Dam in 1963. Changes to river flow, sediment supply, channel base level, lateral extent of sedimentary terraces, and vegetation in the post-dam era have modified the river-corridor landscape and have altered the effects of geologic processes that continue to shape the landscape and its cultural resources. The Glen Canyon reach of the Colorado River downstream of Glen Canyon Dam hosts many archaeological sites that are prone to erosion in this changing landscape. This study uses field evaluations from 2016 and aerial photographs from 1952, 1973, 1984, and 1996 to characterize changes in potential windblown sand supply and drainage configuration that have occurred over more than six decades at 54 archaeological sites in Glen Canyon and uppermost Marble Canyon. To assess landscape change at these sites, we use two complementary geomorphic classification systems. The first evaluates the potential for aeolian (windblown) transport of river-derived sand from the active river channel to higher elevation archaeological sites. The second identifies whether rills, gullies, or arroyos (that is, overland drainages that erode the ground surface) exist at the archaeological sites as well as the geomorphic surface, and therefore the relative base level, to which those flow paths drain. Results of these assessments are intended to aid in the management of irreplaceable archaeological resources by the National Park Service and stakeholders of the Glen Canyon Dam Adaptive Management Program.

Dissolved Divalent Metal and pH Effects on Amino Acid Polymerization: A Thermodynamic Evaluation.

Science.gov (United States)

Kitadai, Norio

2017-03-01

Polymerization of amino acids is a fundamentally important step for the chemical evolution of life. Nevertheless, its response to changing environmental conditions has not yet been well understood because of the lack of reliable quantitative information. For thermodynamics, detailed prediction over diverse combinations of temperature and pH has been made only for a few amino acid-peptide systems. This study used recently reported thermodynamic dataset for the polymerization of the simplest amino acid "glycine (Gly)" to its short peptides (di-glycine and tri-glycine) to examine chemical and structural characteristics of amino acids and peptides that control the temperature and pH dependence of polymerization. Results showed that the dependency is strongly controlled by the intramolecular distance between the amino and carboxyl groups in an amino acid structure, although the side-chain group role is minor. The polymerization behavior of Gly reported earlier in the literature is therefore expected to be a typical feature for those of α-amino acids. Equilibrium calculations were conducted to examine effects of dissolved metals as a function of pH on the monomer-polymer equilibria of Gly. Results showed that metals shift the equilibria toward the monomer side, particularly at neutral and alkaline pH. Metals that form weak interaction with Gly (e.g., Mg 2+ ) have no noticeable influence on the polymerization, although strong interaction engenders significant decrease of the equilibrium concentrations of Gly peptides. Considering chemical and structural characteristics of Gly and Gly peptides that control their interactions with metals, it can be expected that similar responses to the addition of metals are applicable in the polymerization of neutral α-amino acids. Neutral and alkaline aqueous environments with dissolved metals having high affinity with neutral α-amino acids (e.g., Cu 2+ ) are therefore not beneficial places for peptide bond formation on the primitive

Selective removal of Cs and Re by precipitation in a Na2CO3-H2O2 solution

International Nuclear Information System (INIS)

Eil-Hee Lee; Jae-Gwan Lim; Dong-Yong Chung; Han-Beom Yang; Kwang-Wook Kim

2010-01-01

The removal of Cs and Re (as a surrogate for Tc) by selective precipitation from the simulated fission products which were co-dissolved with uranium during the oxidative dissolution of spent fuel in a Na 2 CO 3 -H 2 O 2 solution was investigated in this study. The precipitations of Cs and Re were examined by introducing sodium tetraphenylborate (NaTPB) and tetraphenylohosponium chloride (TPPCl), respectively. The precipitation of Cs by NaTPB and that of Re by TPPCl each took place within 5 min, and an increase in temperature up to 50 deg C and a stirring speed up to 1000 rpm hardly affected their precipitation rates. The most important factor in the precipitation with NaTPB and TPPCl was found to be a pH of the solution after precipitation. Since Mo tends to co-precipitate with Cs or Re at a lower pH, an effective precipitation with NaTPB and TPPCl was done at pH of above 9 without the co-precipitation of Mo. More than 99% of Cs and Re were precipitated when the initial concentration ratio of NaTPB to Cs was above 1 and when that of TPPCl to Re was above 1. The precipitation of Cs and Re was never affected by the concentration of Na 2 CO 3 and H 2 O 2 , even though they were raised up to 1.5 and 1.0 M, respectively. Precipitation yields of Cs and Re in a Na 2 CO 3 -H 2 O 2 solution were found to be dependent on the concentration ratios of [NaTBP]/[Cs] and [TPPCl]/[Re]. (author)

CODASC : a database for the validation of street canyon dispersion models

OpenAIRE

Gromke, C.B.

2013-01-01

CODASC stands for Concentration Data of Street Canyons (CODASC 2008, www.codasc.de). It is a database which provides traffic pollutant concentrations in urban street canyons obtained from wind-tunnel dispersion experiments. CODASC comprises concentration data of street canyons with different aspect ratios subjected to various wind directions and also for street canyons with tree-avenues. The database includes concentration data of tree-avenue configurations of different tree arrangement, tree...

Potential of breccia pipes in the Mohawk Canyon Area, Hualapai Indian Reservation, Arizona

International Nuclear Information System (INIS)

Wenrich, K.J.; Billingsley, G.H.; Van Gosen, B.S.

1990-01-01

The Hualapai Indian Reservation is on the southwestern corner of the Colorado Plateau in northern Arizona. Hundreds of solution-collapse breccia pipes crop out in the canyons and on the plateaus of northern Arizona. The pipes originated in the Mississippian Redwall Limestone and stoped their way upward through the upper Paleozoic strata, locally extending into the Triassic Moenkopi and Chinle Formations. The occurrence of high-grade U ore, associated with potentially economic concentrations of Cu, Ag, Pb, Zn, V, Co, and Ni in some of these pipes, has stimulated mining activity in northern Arizona despite the depressed market for most of these metals. Two breccia pipes, 241, and 242, have significant mineralized rock exposed on the Esplanade erosion surface; unfortunately, their economic potential is questionable because of their inaccessibility at the bottom of Mohawk Canyon. All warrant further exploration

Dispersion and photochemical evolution of reactive pollutants in street canyons

Science.gov (United States)

Kwak, Kyung-Hwan; Baik, Jong-Jin; Lee, Kwang-Yeon

2013-05-01

Dispersion and photochemical evolution of reactive pollutants in street canyons with canyon aspect ratios of 1 and 2 are investigated using a computational fluid dynamics (CFD) model coupled with the carbon bond mechanism IV (CBM-IV). Photochemical ages of NOx and VOC are expressed as a function of the NO2-to-NOx and toluene-to-xylene ratios, respectively. These are found to be useful for analyzing the O3 and OH oxidation processes in the street canyons. The OH oxidation process (O3 oxidation process) is more pronounced in the upper (lower) region of the street canyon with a canyon aspect ratio of 2, which is characterized by more (less) aged air. In the upper region of the street canyon, O3 is chemically produced as well as transported downward across the roof level, whereas O3 is chemically reduced in the lower region of the street canyon. The O3 chemical production is generally favorable when the normalized photochemical ages of NOx and VOC are larger than 0.55 and 0.28, respectively. The sensitivities of O3 chemical characteristics to NOx and VOC emission rates, photolysis rate, and ambient wind speed are examined for the lower and upper regions of the street canyon with a canyon aspect ratio of 2. The O3 concentration and the O3 chemical production rate divided by the O3 concentration increase as the NOx emission rate decreases and the VOC emission rate and photolysis rate increase. The O3 concentration is less sensitive to the ambient wind speed than to other factors considered. The relative importance of the OH oxidation process compared to the O3 oxidation process increases with increasing NOx emission rate and photolysis rate and decreasing VOC emission rate. In this study, both O3 and OH oxidation processes are found to be important in street-canyon scale chemistry. The methodology of estimating the photochemical ages can potentially be adopted to neighborhood scale chemistry.

Populating a Control Point Database: A cooperative effort between the USGS, Grand Canyon Monitoring and Research Center and the Grand Canyon Youth Organization

Science.gov (United States)

Brown, K. M.; Fritzinger, C.; Wharton, E.

2004-12-01

The Grand Canyon Monitoring and Research Center measures the effects of Glen Canyon Dam operations on the resources along the Colorado River from Glen Canyon Dam to Lake Mead in support of the Grand Canyon Adaptive Management Program. Control points are integral for geo-referencing the myriad of data collected in the Grand Canyon including aerial photography, topographic and bathymetric data used for classification and change-detection analysis of physical, biologic and cultural resources. The survey department has compiled a list of 870 control points installed by various organizations needing to establish a consistent reference for data collected at field sites along the 240 mile stretch of Colorado River in the Grand Canyon. This list is the foundation for the Control Point Database established primarily for researchers, to locate control points and independently geo-reference collected field data. The database has the potential to be a valuable mapping tool for assisting researchers to easily locate a control point and reduce the occurrance of unknowingly installing new control points within close proximity of an existing control point. The database is missing photographs and accurate site description information. Current site descriptions do not accurately define the location of the point but refer to the project that used the point, or some other interesting fact associated with the point. The Grand Canyon Monitoring and Research Center (GCMRC) resolved this problem by turning the data collection effort into an educational exercise for the participants of the Grand Canyon Youth organization. Grand Canyon Youth is a non-profit organization providing experiential education for middle and high school aged youth. GCMRC and the Grand Canyon Youth formed a partnership where GCMRC provided the logistical support, equipment, and training to conduct the field work, and the Grand Canyon Youth provided the time and personnel to complete the field work. Two data

The timing of sediment transport down Monterey Submarine Canyon, offshore California

DEFF Research Database (Denmark)

Stevens, Thomas; Paull, C.K.; Ussler, W., III

2014-01-01

luminescence (OSL) ages of quartz sand deposits and accelerator mass spectrometry 14C ages measured on benthic foraminifera to examine the timing of sediment transport through the axial channel of Monterey Submarine Canyon and Fan, offshore California. The OSL ages date the timing of sediment entry...... dates with water depth provides evidence of mixing and temporary storage of sediment as it moves through the canyon system. The ages also indicate that the frequency of sediment transport events decreases with distance down the canyon channel system. The amalgamated sands near the canyon head yield OSL......While submarine canyons are the major conduits through which sediments are transported from the continents out into the deep sea, the time it takes for sediment to pass down through a submarine canyon system is poorly constrained. Here we report on the first study to couple optically stimulated...

Identification of solution products of lanthanoid (3) diethyldithiocarbamatohexamethyl phosphotriamide compounds from IR, electron and sup 1 H, sup 13 C, sup 31 P NMR absorption spectra. Identifikatsiya produktov rastvoreniya diehtilditiokarbamatogeksametil fosfotriamidnykh soedinenij lantanoidov (3) po IK, ehlektronnym i YaMR sup 1 H, sup 13 C, sup 31 P spektram pogloshcheniya

Energy Technology Data Exchange (ETDEWEB)

Skopenko, V V; Savost' yanova, A F; Trachevskij, V V; Gorbalyuk, A D; Sukhan, T A [Kievskij Gosudarstvennyj Univ., Kiev (Ukrainian SSR)

1991-01-01

By the methods of conductometry, IR, electron and {sup 1}H, {sup 13}C, {sup 31}P NMR spectroscopy nonaqueous solutions of the compounds (La(S{sub 2}CNEt{sub 2})Hmpa{sub 5})(BPh{sub 4}){sub 2}, Hmpa=OP(NMe{sub 2}){sub 3}; (Ln(S{sub 2}CNEt{sub 2}){sub 2}Hmpa{sub 3})BPh{sub 4}, Ln=Y, La-Lu; (Ln(S{sub 2}CNEt{sub 2}){sub 3}Hmpa{sub 2}), Ln=La-Gd, have been investigated. It is ascertained that bis-dithiocarbamate compounds are dissolved in all the studied solvents with preservation of composition and structure of lanthanide (3) inner coordination sphere. Tris-dithiocarbamates in nonaqueous solutions are subjected to reactions of ligand redistribution according to schemes depending on the solvent nature. In the process of dissolving of lanthanum monodithiocarbamate bond isomerization of dithiocarbamate groups occurs, which is pronounced in splitting of {sup 1}H and {sup 13}C NMR signals.

Liquid scintillation solutions

International Nuclear Information System (INIS)

Long, E.C.

1976-01-01

The liquid scintillation solution described includes a mixture of: a liquid scintillation solvent, a primary scintillation solute, a secondary scintillation solute, a variety of appreciably different surfactants, and a dissolving and transparency agent. The dissolving and transparency agent is tetrahydrofuran, a cyclic ether. The scintillation solvent is toluene. The primary scintillation solute is PPO, and the secondary scintillation solute is dimethyl POPOP. The variety of appreciably different surfactants is composed of isooctylphenol-polyethoxyethanol and sodium dihexyl sulphosuccinate [fr

Evolution and Submarine Landslide Potential of Monterey Canyon Head, Offshore Central California

Science.gov (United States)

Maier, K. L.; Johnson, S. Y.; Hart, P. E.; Hartwell, S. R.

2016-12-01

Monterey Canyon, offshore central California, incises the shelf from near the shoreline to 30 km seaward where axial water depths approach 2,000 m. It is one of the world's most studied submarine canyons, yet debate continues concerning its age, formation, and associated geologic hazards. To address these issues, the USGS, with partial support from the California Seafloor Mapping Program, collected hundreds of kilometers of high-resolution, mini-sparker, single-channel (2009 and 2011 surveys) and multichannel (2015 survey) seismic-reflection profiles near the canyon head. The seismic data were combined with multibeam bathymetry to generate a geologic map of the proximal canyon, which delineates numerous faults and compound submarine landslide headwall scarps (covering up to 4 km2) along canyon walls. Seismic-reflection data reveal a massive ( 100 km2 lateral extent) paleochannel cut-and-fill complex underlying the proximal canyon. These subsurface cut-and-fill deposits span both sides of the relatively narrow modern canyon head, crop out in canyon walls, and incise into Purisima Formation (late Miocene and Pliocene) bedrock to depths of up to 0.3 s two-way travel time ( 240 m) below the modern shelf. We propose that the paleochannel complex represents previous locations of a migrating canyon head, and attribute its origin to multiple alternating cycles of fluvial and submarine canyon erosion and deposition linked to fluctuating sea levels. Thus, the canyon head imaged in modern bathymetry is a relatively young feature, perhaps forming in the last 20,000 years of sea-level rise. The paleocanyon deposits are significantly less consolidated than bedrock in deeper canyon walls, and therefore, are probably more prone to submarine landsliding. Nearby mapped faults occur within the active, distributed, San Andreas fault system, and earthquake-generated strong ground motions are likely triggers for past and future submarine landslides and potential associated tsunamis.

Removal of phosphate and nitrate from aqueous solution using ...

African Journals Online (AJOL)

sunny t

water, 3.5 g of NaCl were dissolved to obtain 3.5 g/l salinity final solution. When the ... The nitrate adsorption was highly pH dependent, which affects the ... adsorption mechanism that the optimum pH for phosphate removal by .... Biosorption of copper(ii) from aqueous ... Accumulation and detoxification of toxic elements by ...

Lung cancer risk assessment due to traffic-generated particles exposure in urban street canyons: A numerical modelling approach.

Science.gov (United States)

Scungio, M; Stabile, L; Rizza, V; Pacitto, A; Russi, A; Buonanno, G

2018-08-01

Combustion-generated nanoparticles are responsible for negative health effects due to their ability to penetrate in the lungs, carrying toxic compounds with them. In urban areas, the coexistence of nanoparticle sources and particular street-building configurations can lead to very high particle exposure levels. In the present paper, an innovative approach for the evaluation of lung cancer incidence in street canyon due to exposure to traffic-generated particles was proposed. To this end, the literature-available values of particulate matter, PAHs and heavy metals emitted from different kind of vehicles were used to calculate the Excess Lifetime Cancer Risk (ELCR) at the tailpipe. The estimated ELCR was then used as input data in a numerical CFD (Computational Fluid Dynamics) model that solves the mass, momentum, turbulence and species transport equations, in order to evaluate the cancer risk in every point of interest inside the street canyon. Thus, the influence of wind speed and street canyon geometry (H/W, height of building, H and width of the street, W) on the ELCR at street level was evaluated by means of a CFD simulation. It was found that the ELCR calculated on the leeward and windward sides of the street canyon at a breathable height of 1.5 m, for people exposed 15 min per day for 20 years, is equal to 1.5 × 10 -5 and 4.8 × 10 -6 , respectively, for wind speed of 1 m/s and H/W equal to 1. The ELCR at street level results higher on the leeward side for aspect ratios equal to 1 and 3, while for aspect ratio equal to 2 it is higher on the windward side. In addition, the simulations showed that with the increasing of wind speed the ELCR becomes lower everywhere in the street canyon, due to the increased in dispersion. Copyright © 2018 Elsevier B.V. All rights reserved.

Geologic map and upper Paleozoic stratigraphy of the Marble Canyon area, Cottonwood Canyon quadrangle, Death Valley National Park, Inyo County, California

Science.gov (United States)

Stone, Paul; Stevens, Calvin H.; Belasky, Paul; Montañez, Isabel P.; Martin, Lauren G.; Wardlaw, Bruce R.; Sandberg, Charles A.; Wan, Elmira; Olson, Holly A.; Priest, Susan S.

2014-01-01

This geologic map and pamphlet focus on the stratigraphy, depositional history, and paleogeographic significance of upper Paleozoic rocks exposed in the Marble Canyon area in Death Valley National Park, California. Bedrock exposed in this area is composed of Mississippian to lower Permian (Cisuralian) marine sedimentary rocks and the Jurassic Hunter Mountain Quartz Monzonite. These units are overlain by Tertiary and Quaternary nonmarine sedimentary deposits that include a previously unrecognized tuff to which we tentatively assign an age of late middle Miocene (~12 Ma) based on tephrochronologic analysis, in addition to the previously recognized Pliocene tuff of Mesquite Spring. Mississippian and Pennsylvanian rocks in the Marble Canyon area represent deposition on the western continental shelf of North America. Mississippian limestone units in the area (Tin Mountain, Stone Canyon, and Santa Rosa Hills Limestones) accumulated on the outer part of a broad carbonate platform that extended southwest across Nevada into east-central California. Carbonate sedimentation was interrupted by a major eustatic sea-level fall that has been interpreted to record the onset of late Paleozoic glaciation in southern Gondwana. Following a brief period of Late Mississippian clastic sedimentation (Indian Springs Formation), a rise in eustatic sea level led to establishment of a new carbonate platform that covered most of the area previously occupied by the Mississippian platform. The Pennsylvanian Bird Spring Formation at Marble Canyon makes up the outer platform component of ten third-order (1 to 5 m.y. duration) stratigraphic sequences recently defined for the regional platform succession. The regional paleogeography was fundamentally changed by major tectonic activity along the continental margin beginning in middle early Permian time. As a result, the Pennsylvanian carbonate shelf at Marble Canyon subsided and was disconformably overlain by lower Permian units (Osborne Canyon and

Method to Estimate the Dissolved Air Content in Hydraulic Fluid

Science.gov (United States)

Hauser, Daniel M.

2011-01-01

In order to verify the air content in hydraulic fluid, an instrument was needed to measure the dissolved air content before the fluid was loaded into the system. The instrument also needed to measure the dissolved air content in situ and in real time during the de-aeration process. The current methods used to measure the dissolved air content require the fluid to be drawn from the hydraulic system, and additional offline laboratory processing time is involved. During laboratory processing, there is a potential for contamination to occur, especially when subsaturated fluid is to be analyzed. A new method measures the amount of dissolved air in hydraulic fluid through the use of a dissolved oxygen meter. The device measures the dissolved air content through an in situ, real-time process that requires no additional offline laboratory processing time. The method utilizes an instrument that measures the partial pressure of oxygen in the hydraulic fluid. By using a standardized calculation procedure that relates the oxygen partial pressure to the volume of dissolved air in solution, the dissolved air content is estimated. The technique employs luminescent quenching technology to determine the partial pressure of oxygen in the hydraulic fluid. An estimated Henry s law coefficient for oxygen and nitrogen in hydraulic fluid is calculated using a standard method to estimate the solubility of gases in lubricants. The amount of dissolved oxygen in the hydraulic fluid is estimated using the Henry s solubility coefficient and the measured partial pressure of oxygen in solution. The amount of dissolved nitrogen that is in solution is estimated by assuming that the ratio of dissolved nitrogen to dissolved oxygen is equal to the ratio of the gas solubility of nitrogen to oxygen at atmospheric pressure and temperature. The technique was performed at atmospheric pressure and room temperature. The technique could be theoretically carried out at higher pressures and elevated

CODASC : a database for the validation of street canyon dispersion models

NARCIS (Netherlands)

Gromke, C.B.

2013-01-01

CODASC stands for Concentration Data of Street Canyons (CODASC 2008, www.codasc.de). It is a database which provides traffic pollutant concentrations in urban street canyons obtained from wind-tunnel dispersion experiments. CODASC comprises concentration data of street canyons with different aspect

Is Canyon Width a Diagnostic Indicator of the Discharge of Megafloods on Earth and Mars?

Science.gov (United States)

Lapotre, M. G.; Lamb, M. P.

2013-12-01

On Earth, large floods have carved steep-walled and amphitheater-headed canyons from the Pleistocene (e.g. Box Canyon, ID) through the Holocene (e.g. Asbyrgi Canyon, Iceland), to historic times (e.g. Canyon Lake Gorge, TX). The geologic record on Mars suggests that similar floods have carved canyons by waterfall retreat about 3.5 billion years ago, when the red planet was wetter and possibly warmer. We currently lack robust paleo-hydraulic tools to reconstruct the discharge of ancient floods, especially on Mars where sediment sizes are obscured from observation. To address this issue, we hypothesize that the width of canyon escarpment is controlled by the hydraulics of the canyon-carving flood due to focusing of the flood into the canyon head. We compiled field data from multiple canyons and floods on Earth and Mars and show that there is a correlation between estimated flood discharge and canyon headwall width. To explore what sets this relationship, we identified five important parameters using dimensional analysis: the Froude number, the ratio of backwater length to canyon length, the ratio of backwater length to flood width, the ratio of canyon width to flood width, and the topographic slope upstream of the canyon. We used the hydraulic numerical modeling suite ANUGA to simulate overland flow over different canyon geometries and flood parameters to systematically explore the relative bed shear stresses along the canyon rim as a metric for flow focusing. Results show that canyons that exceed a certain length, scaling with the hydraulic backwater length, have shear stresses at their heads that are significantly higher than near the canyon mouth. Shear stresses along the rim of the canyon sidewalls are limited, in comparison to stresses along the canyon head, when the flood width is of the order of the backwater length. Flow focusing only occurs for subcritical flow. Together, these results suggest that canyons may only grow from a perturbation that is large

DIissolution of low enriched uranium from the experimental breeder reactor-II fuel stored at the Idaho National Laboratory

Energy Technology Data Exchange (ETDEWEB)

Daniel, G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Rudisill, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Almond, P. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); O' Rourke, P. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-06-28

The Idaho National Laboratory (INL) is actively engaged in the development of electrochemical processing technology for the treatment of fast reactor fuels using irradiated fuel from the Experimental Breeder Reactor-II (EBR-II) as the primary test material. The research and development (R&D) activities generate a low enriched uranium (LEU) metal product from the electrorefining of the EBR-II fuel and the subsequent consolidation and removal of chloride salts by the cathode processor. The LEU metal ingots from past R&D activities are currently stored at INL awaiting disposition. One potential disposition pathway is the shipment of the ingots to the Savannah River Site (SRS) for dissolution in H-Canyon. Carbon steel cans containing the LEU metal would be loaded into reusable charging bundles in the H-Canyon Crane Maintenance Area and charged to the 6.4D or 6.1D dissolver. The LEU dissolution would be accomplished as the final charge in a dissolver batch (following the dissolution of multiple charges of spent nuclear fuel (SNF)). The solution would then be purified and the ²³⁵U enrichment downblended to allow use of the U in commercial reactor fuel. To support this potential disposition path, the Savannah River National Laboratory (SRNL) developed a dissolution flowsheet for the LEU using samples of the material received from INL.

Groundwater flow and its effect on salt dissolution in Gypsum Canyon watershed, Paradox Basin, southeast Utah, USA

Science.gov (United States)

Reitman, Nadine G.; Ge, Shemin; Mueller, Karl

2014-09-01

Groundwater flow is an important control on subsurface evaporite (salt) dissolution. Salt dissolution can drive faulting and associated subsidence on the land surface and increase salinity in groundwater. This study aims to understand the groundwater flow system of Gypsum Canyon watershed in the Paradox Basin, Utah, USA, and whether or not groundwater-driven dissolution affects surface deformation. The work characterizes the groundwater flow and solute transport systems of the watershed using a three-dimensional (3D) finite element flow and transport model, SUTRA. Spring samples were analyzed for stable isotopes of water and total dissolved solids. Spring water and hydraulic conductivity data provide constraints for model parameters. Model results indicate that regional groundwater flow is to the northwest towards the Colorado River, and shallow flow systems are influenced by topography. The low permeability obtained from laboratory tests is inconsistent with field observed discharges, supporting the notion that fracture permeability plays a significant role in controlling groundwater flow. Model output implies that groundwater-driven dissolution is small on average, and cannot account for volume changes in the evaporite deposits that could cause surface deformation, but it is speculated that dissolution may be highly localized and/or weaken evaporite deposits, and could lead to surface deformation over time.

Mathematical modeling of dissolved oxygen in fish ponds ...

African Journals Online (AJOL)

Mathematical modeling of dissolved oxygen in fish ponds. WJS Mwegoha, ME Kaseva, SMM Sabai. Abstract. A mathematical model was developed to predict the effects of wind speed, light, pH, Temperature, dissolved carbon dioxide and chemical oxygen demand (COD) on Dissolved Oxygen (DO) in fish ponds. The effects ...

Canyon transfer neutron absorber to fissile material ratio analysis. Revision 1

International Nuclear Information System (INIS)

Clemmons, J.S.

1994-01-01

Waste tank fissile material and non-fissile material estimates are used to evaluate criticality safety for the existing sludge inventory and batches of sludge sent to Extended Sludge Processing (ESP). This report documents the weight ratios of several non-fissile waste constituents to fissile waste constituents from canyon reprocessing waste streams. Weight ratios of Fe, Mn, Al, Mi, and U-238 to fissile material are calculated from monthly loss estimates from the F and H Canyon Low Heat Waste (LHW) and High Heat Waste (HHW) streams. The monthly weight ratios for Fe, Mn and U-238 are then compared to calculated minimum safe weight ratios. Documented minimum safe weight ratios for Al and Ni to fissile material are currently not available. Total mass data for the subject sludge constituents is provided along with scatter plots of the monthly weight ratios for each waste stream

Large eddy simulation of fire-induced buoyancy driven plume dispersion in an urban street canyon under perpendicular wind flow

Energy Technology Data Exchange (ETDEWEB)

Hu, L.H., E-mail: hlh@ustc.edu.cn [State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui 230026 (China); Huo, R.; Yang, D. [State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2009-07-15

The dispersion of fire-induced buoyancy driven plume in and above an idealized street canyon of 18 m (width) x 18 m (height) x 40 m (length) with a wind flow perpendicular to its axis was investigated by Fire Dynamics Simulator (FDS), Large Eddy Simulation (LES). Former studies, such as that by Oka [T.R. Oke, Street design and urban canopy layer climate, Energy Build. 11 (1988) 103-113], Gayev and Savory [Y.A. Gayev, E. Savory, Influence of street obstructions on flow processes within street canyons. J. Wind Eng. Ind. Aerodyn. 82 (1999) 89-103], Xie et al. [S. Xie, Y. Zhang, L. Qi, X. Tang, Spatial distribution of traffic-related pollutant concentrations in street canyons. Atmos. Environ. 37 (2003) 3213-3224], Baker et al. [J. Baker, H. L. Walker, X. M. Cai, A study of the dispersion and transport of reactive pollutants in and above street canyons-a large eddy simulation, Atmos. Environ. 38 (2004) 6883-6892] and Baik et al. [J.-J. Baik, Y.-S. Kang, J.-J. Kim, Modeling reactive pollutant dispersion in an urban street canyon, Atmos. Environ. 41 (2007) 934-949], focus on the flow pattern and pollutant dispersion in the street canyon with no buoyancy effect. Results showed that with the increase of the wind flow velocity, the dispersion pattern of a buoyant plume fell into four regimes. When the wind flow velocity increased up to a certain critical level, the buoyancy driven upward rising plume was re-entrained back into the street canyon. This is a dangerous situation as the harmful fire smoke will accumulate to pollute the environment and thus threaten the safety of the people in the street canyon. This critical re-entrainment wind velocity, as an important parameter to be concerned, was further revealed to increase asymptotically with the heat/buoyancy release rate of the fire.

Large eddy simulation of fire-induced buoyancy driven plume dispersion in an urban street canyon under perpendicular wind flow.

Science.gov (United States)

Hu, L H; Huo, R; Yang, D

2009-07-15

The dispersion of fire-induced buoyancy driven plume in and above an idealized street canyon of 18 m (width) x 18 m (height) x 40 m (length) with a wind flow perpendicular to its axis was investigated by Fire Dynamics Simulator (FDS), Large Eddy Simulation (LES). Former studies, such as that by Oka [T.R. Oke, Street design and urban canopy layer climate, Energy Build. 11 (1988) 103-113], Gayev and Savory [Y.A. Gayev, E. Savory, Influence of street obstructions on flow processes within street canyons. J. Wind Eng. Ind. Aerodyn. 82 (1999) 89-103], Xie et al. [S. Xie, Y. Zhang, L. Qi, X. Tang, Spatial distribution of traffic-related pollutant concentrations in street canyons. Atmos. Environ. 37 (2003) 3213-3224], Baker et al. [J. Baker, H. L. Walker, X. M. Cai, A study of the dispersion and transport of reactive pollutants in and above street canyons--a large eddy simulation, Atmos. Environ. 38 (2004) 6883-6892] and Baik et al. [J.-J. Baik, Y.-S. Kang, J.-J. Kim, Modeling reactive pollutant dispersion in an urban street canyon, Atmos. Environ. 41 (2007) 934-949], focus on the flow pattern and pollutant dispersion in the street canyon with no buoyancy effect. Results showed that with the increase of the wind flow velocity, the dispersion pattern of a buoyant plume fell into four regimes. When the wind flow velocity increased up to a certain critical level, the buoyancy driven upward rising plume was re-entrained back into the street canyon. This is a dangerous situation as the harmful fire smoke will accumulate to pollute the environment and thus threaten the safety of the people in the street canyon. This critical re-entrainment wind velocity, as an important parameter to be concerned, was further revealed to increase asymptotically with the heat/buoyancy release rate of the fire.

Large eddy simulation of fire-induced buoyancy driven plume dispersion in an urban street canyon under perpendicular wind flow

International Nuclear Information System (INIS)

Hu, L.H.; Huo, R.; Yang, D.

2009-01-01

The dispersion of fire-induced buoyancy driven plume in and above an idealized street canyon of 18 m (width) x 18 m (height) x 40 m (length) with a wind flow perpendicular to its axis was investigated by Fire Dynamics Simulator (FDS), Large Eddy Simulation (LES). Former studies, such as that by Oka [T.R. Oke, Street design and urban canopy layer climate, Energy Build. 11 (1988) 103-113], Gayev and Savory [Y.A. Gayev, E. Savory, Influence of street obstructions on flow processes within street canyons. J. Wind Eng. Ind. Aerodyn. 82 (1999) 89-103], Xie et al. [S. Xie, Y. Zhang, L. Qi, X. Tang, Spatial distribution of traffic-related pollutant concentrations in street canyons. Atmos. Environ. 37 (2003) 3213-3224], Baker et al. [J. Baker, H. L. Walker, X. M. Cai, A study of the dispersion and transport of reactive pollutants in and above street canyons-a large eddy simulation, Atmos. Environ. 38 (2004) 6883-6892] and Baik et al. [J.-J. Baik, Y.-S. Kang, J.-J. Kim, Modeling reactive pollutant dispersion in an urban street canyon, Atmos. Environ. 41 (2007) 934-949], focus on the flow pattern and pollutant dispersion in the street canyon with no buoyancy effect. Results showed that with the increase of the wind flow velocity, the dispersion pattern of a buoyant plume fell into four regimes. When the wind flow velocity increased up to a certain critical level, the buoyancy driven upward rising plume was re-entrained back into the street canyon. This is a dangerous situation as the harmful fire smoke will accumulate to pollute the environment and thus threaten the safety of the people in the street canyon. This critical re-entrainment wind velocity, as an important parameter to be concerned, was further revealed to increase asymptotically with the heat/buoyancy release rate of the fire.

A Numerical Study of the Temperature Reduction by Water Spray Systems within Urban Street Canyons

Directory of Open Access Journals (Sweden)

Ying-Chen Lee

2018-04-01

Full Text Available To reduce energy demand (both fossil fuel and renewable energy for cooling the urban heat island environment, some solutions have been studied. Among these methods, the water spray system is considered more flexible due to its dynamic controls. This study investigated the cooling effect of water spray systems in the street canyon under different aspect ratios and high relative humidity environments using a computational fluid dynamics model. This model was validated with water channel and wind tunnel experiments. The results showed that the most effective cooling area was the area just under the spray nozzles. However, in a narrow street canyon, people in the middle of the street may feel the cooling effect because of the dispersion and accumulation of the cooled air. Our simulations demonstrated that air under the nozzles was saturated and this revealed that under drier conditions the water spray systems will have higher cooling performance. We also found that using large water droplets created a wider cooling area in the middle of the street canyon, and this phenomenon was not changed much if the nozzle height was increased from 2.5 m to 3.5 m.

Seasonal Changing Effect on Airflow and Pollutant Dispersion Characteristics in Urban Street Canyons

Directory of Open Access Journals (Sweden)

Jingliang Dong

2017-02-01

Full Text Available In this study, the effect of seasonal variation on air flow and pollutant dispersion characteristics was numerically investigated. A three-dimensional urban canopy model with unit aspect ratio (H/D = 1 was used to calculate surface temperature distribution in the street canyon. Four representative time events (1000 LST, 1300 LST, 1600 LST and 2000 LST during typical clear summer and winter days were selected to examine the air flow diurnal variation. The results revealed the seasonal variation significantly altered the street canyon microclimate. Compared with the street canyon surface temperature distribution in summer, the winter case showed a more evenly distributed surface temperature. In addition, the summer case showed greater daily temperature fluctuation than that of the winter case. Consequently, distinct pollutant dispersion patterns were observed between summer and winter scenarios, especially for the afternoon (1600 LST and night (2000 LST events. Among all studied time events, the pollutant removal performance of the morning (1000 LST and the night (2000 LST events were more sensitive to the seasonal variation. Lastly, limited natural ventilation performance was found during the summer morning and the winter night, which induced relatively high pollutant concentration along the pedestrian height level.

Preparation of Atomically Flat Si(111)-H Surfaces in Aqueous Ammonium Fluoride Solutions Investigated by Using Electrochemical, In Situ EC-STM and ATR-FTIR Spectroscopic Methods

International Nuclear Information System (INIS)

Bae, Sang Eun; Oh, Mi Kyung; Min, Nam Ki; Paek, Se Hwan; Hong, Suk In; Lee, Chi-Woo J.

2004-01-01

Electrochemical, in situ electrochemical scanning tunneling microscope (EC-STM), and attenuated total reflectance-FTIR (ATR-FTIR) spectroscopic methods were employed to investigate the preparation of atomically flat Si(111)-H surface in ammonium fluoride solutions. Electrochemical properties of atomically flat Si(111)-H surface were characterized by anodic oxidation and cathodic hydrogen evolution with the open circuit potential (OCP) of ca. .0.4 V in concentrated ammonium fluoride solutions. As soon as the natural oxide-covered Si(111) electrode was immersed in fluoride solutions, OCP quickly shifted to near .1 V, which was more negative than the flat band potential of silicon surface, indicating that the surface silicon oxide had to be dissolved into the solution. OCP changed to become less negative as the oxide layer was being removed from the silicon surface. In situ EC-STM data showed that the surface was changed from the initial oxide covered silicon to atomically rough hydrogen-terminated surface and then to atomically flat hydrogen terminated surface as the OCP moved toward less negative potentials. The atomically flat Si(111)-H structure was confirmed by in situ EC-STM and ATR-FTIR data. The dependence of atomically flat Si(111)-H terrace on mis-cut angle was investigated by STM, and the results agreed with those anticipated by calculation. Further, the stability of Si(111)-H was checked by STM in ambient laboratory conditions

Preparation of encapsulated proteins dissolved in low viscosity fluids

International Nuclear Information System (INIS)

Ehrhardt, Mark R.; Flynn, Peter F.; Wand, A. Joshua

1999-01-01

The majority of proteins are too large to be comprehensively examined by solution NMR methods, primarily because they tumble too slowly in solution. One potential approach to making the NMR relaxation properties of large proteins amenable to modern solution NMR techniques is to encapsulate them in a reverse micelle which is dissolved in a low viscosity fluid. Unfortunately, promising low viscosity fluids such as the short chain alkanes, supercritical carbon dioxide, and various halocarbon refrigerants all require the application of significant pressure to be kept liquefied at room temperature. Here we describe the design and use of a simple cost effective NMR tube suitable for the preparation of solutions of proteins encapsulated in reverse micelles dissolved in such fluids

Canyon formation constraints on the discharge of catastrophic outburst floods of Earth and Mars

Science.gov (United States)

Lapotre, Mathieu G. A.; Lamb, Michael P.; Williams, Rebecca M. E.

2016-07-01

Catastrophic outburst floods carved amphitheater-headed canyons on Earth and Mars, and the steep headwalls of these canyons suggest that some formed by upstream headwall propagation through waterfall erosion processes. Because topography evolves in concert with water flow during canyon erosion, we suggest that bedrock canyon morphology preserves hydraulic information about canyon-forming floods. In particular, we propose that for a canyon to form with a roughly uniform width by upstream headwall retreat, erosion must occur around the canyon head, but not along the sidewalls, such that canyon width is related to flood discharge. We develop a new theory for bedrock canyon formation by megafloods based on flow convergence of large outburst floods toward a horseshoe-shaped waterfall. The model is developed for waterfall erosion by rock toppling, a candidate erosion mechanism in well fractured rock, like columnar basalt. We apply the model to 14 terrestrial (Channeled Scablands, Washington; Snake River Plain, Idaho; and Ásbyrgi canyon, Iceland) and nine Martian (near Ares Vallis and Echus Chasma) bedrock canyons and show that predicted flood discharges are nearly 3 orders of magnitude less than previously estimated, and predicted flood durations are longer than previously estimated, from less than a day to a few months. Results also show a positive correlation between flood discharge per unit width and canyon width, which supports our hypothesis that canyon width is set in part by flood discharge. Despite lower discharges than previously estimated, the flood volumes remain large enough for individual outburst floods to have perturbed the global hydrology of Mars.

California State Waters Map Series—Monterey Canyon and vicinity, California

Science.gov (United States)

Dartnell, Peter; Maier, Katherine L.; Erdey, Mercedes D.; Dieter, Bryan E.; Golden, Nadine E.; Johnson, Samuel Y.; Hartwell, Stephen R.; Cochrane, Guy R.; Ritchie, Andrew C.; Finlayson, David P.; Kvitek, Rikk G.; Sliter, Ray W.; Greene, H. Gary; Davenport, Clifton W.; Endris, Charles A.; Krigsman, Lisa M.; Dartnell, Peter; Cochran, Susan A.

2016-06-10

IntroductionIn 2007, the California Ocean Protection Council initiated the California Seafloor Mapping Program (CSMP), designed to create a comprehensive seafloor map of high-resolution bathymetry, marine benthic habitats, and geology within the 3-nautical-mile limit of California’s State Waters. The CSMP approach is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath bathymetry data, acoustic backscatter, seafloor video, seafloor photography, high-resolution seismic-reflection profiles, and bottom-sediment sampling data. The map products display seafloor morphology and character, identify potential marine benthic habitats, and illustrate both the surficial seafloor geology and shallow subsurface geology.The Monterey Canyon and Vicinity map area lies within Monterey Bay in central California. Monterey Bay is one of the largest embayments along the west coast of the United States, spanning 36 km from its northern to southern tips (in Santa Cruz and Monterey, respectively) and 20 km along its central axis. Not only does it contain one of the broadest sections of continental shelf along California’s coast, it also contains Monterey Canyon, one of the largest and deepest submarine canyons in the world. Note that the California’s State Waters limit extends farther offshore between Santa Cruz and Monterey so that it encompasses all of Monterey Bay.The coastal area within the map area is lightly populated. The community of Moss Landing (population, 204) hosts the largest commercial fishing fleet in Monterey Bay in its harbor. The map area also includes parts of the cities of Marina (population, about 20,000) and Castroville (population, about 6,500). Fertile lowlands of the Salinas River and Pajaro River valleys largely occupy the inland part of the map area, and land use is primarily agricultural.The offshore part of the map area lies completely within the Monterey Bay National Marine Sanctuary. The

Submarine canyons as coral and sponge habitat on the eastern Bering Sea slope

Directory of Open Access Journals (Sweden)

Robert J. Miller

2015-07-01

Full Text Available Submarine canyons have been shown to positively influence pelagic and benthic biodiversity and ecosystem function. In the eastern Bering Sea, several immense canyons lie under the highly productive “green belt” along the continental slope. Two of these, Pribilof and Zhemchug canyons, are the focus of current conservation interest. We used a maximum entropy modeling approach to evaluate the importance of these two canyons, as well as canyons in general, as habitat for gorgonian (alcyonacean corals, pennatulacean corals, and sponges, in an area comprising most of the eastern Bering Sea slope and outer shelf. These invertebrates create physical structure that is a preferred habitat for many mobile species, including commercially important fish and invertebrates. We show that Pribilof canyon is a hotspot of structure-forming invertebrate habitat, containing over 50% of estimated high-quality gorgonian habitat and 45% of sponge habitat, despite making up only 1.7% of the total study area. The amount of quality habitat for gorgonians and sponges varied in other canyons, but canyons overall contained more high-quality habitat for structure-forming invertebrates compared to other slope areas. Bottom trawling effort was not well correlated with habitat quality for structure-forming invertebrates, and bottom-contact fishing effort in general, including longlining and trawling, was not particularly concentrated in the canyons examined. These results suggest that if conserving gorgonian coral habitat is a management goal, canyons, particularly Pribilof Canyon, may be a prime location to do this without excessive impact on fisheries.

Facies and depositional model of Almada Canyon, Almada Basin, Bahia, Brazil; Facies e modelo deposicional do Canyon de Almada, Bacia de Almada, Bahia

Energy Technology Data Exchange (ETDEWEB)

D' Avila, Roberto Salvador Francisco; Souza Cruz, Carlos Emanoel de; Oliveira Filho, Jose Souto; Jesus, Candida Menezes de; Cesero, Pedro de; Dias Filho, Dorval Carvalho; Lima, Claudio Coelho de; Queiroz, Claudia Lima de; Santos, Saulo Ferreira; Ferreira, Eduardo Araripe [PETROBRAS, Santos, SP (Brazil). Unidade de Negocio de Exploracao]. E-mail: rdavila@petrobras.com.br

2004-11-01

In the continental portion of the Almada Basin outcrops of canyon filling deposits are represented by turbidite channels and associated facies from Urucutuca Formation. The canyon - semi-exhumated - eroded basement and pre-Cenomanian sedimentary rocks. The field study of the outcrops and cores obtained in adjacent perforations lead to the understanding of the facies and processes that controlled the deposition of these channeled turbidite that can be compared to the reservoirs of many oil fields in Brazil. The Almada canyon is a submarine conduct of tectonic origin that was enlarged by the repeated passing of turbidity currents. During the rift phase and the Albian period, compressive events reactivated old N E and N W faults in the basement as trans current fault systems. The continuation of these stresses, from the Cenomanian to the Maastrichtian, developed normal faults that controlled a submarine canyon that connected the continent, where an estuary was formed between the mountains, to the deep marine region of the basin. The canyon has received sediments brought by catastrophic fluvial floods coming from the surrounding mountains, which formed hyperpicnal flows that have evolved as turbidity currents, thus causing erosion of the substrate and carrying a huge volume of sediments to the basin. A part of that load was deposited in the canyon and formed turbidite channels filled by conglomerates, sandstones and shales. These moderately to highly efficient turbidite are intercalated to pro delta pelites and low density turbid plumes deposits, which have mostly been re mobilized as slump and debris flows (chaotic deposits). Pelites were accumulated mainly in the normal fluvial sedimentation phases, when the sandy sediment was retained next to the canyon head and were reworked by the tides on the upper part of the estuary. (author)

Fast dissolving strips: A novel approach for the delivery of verapamil

Directory of Open Access Journals (Sweden)

S Kunte

2010-01-01

Full Text Available Objective: Fast dissolving drug delivery system offers a solution for those patients having difficulty in swallowing tablets/capsules etc. Verapamil is a calcium channel blocker used as an antianginal, antiarrhythmic, and antihypertensive agent with extensive first pass metabolism which results in less bioavailability. This work investigated the possibility of developing verapamil fast dissolving strips allowing fast, reproducible drug dissolution in the oral cavity; thus bypassing first pass metabolism. Materials and methods: The fast dissolving strips were prepared by solvent casting technique with the help of HPMC E6 and maltodextrin. The strips were evaluated for drug content uniformity, film thickness, folding endurance, in vitro disintegration time, in vitro dissolution studies, surface pH study, and palatability study. Results: Official criteria for evaluation parameters were fulfilled by all formulations. Disintegration time showed by formulations was found to be in range of 20.4-28.6 sec. Based on the evaluation parameters, the formulation containing 2% HPMC E6 and 3.5% maltodextrin showed optimum performance against other formulations. Conclusion: It was concluded that the fast dissolving strips of verapamil can be made by solvent casting technique with enhanced dissolution rate, taste masking, and hence better patient compliance and effective therapy

Red Rock Canyon National Conservation Area Transportation Feasibility Study

Science.gov (United States)

2012-07-31

Red Rock Canyon National Conservation Area is a popular Bureau of Land Management natural area located near Las Vegas, Nevada. Red Rock Canyon experiences heavy congestion on its Scenic Drive and associated parking areas, due to high volumes of visit...

Environmental analysis of Lower Pueblo/Lower Los Alamos Canyon, Los Alamos, New Mexico

International Nuclear Information System (INIS)

Ferenbaugh, R.W.; Buhl, T.E.; Stoker, A.K.; Becker, N.M.; Rodgers, J.C.; Hansen, W.R.

1994-12-01

The radiological survey of the former radioactive waste treatment plant site (TA-45), Acid Canyon, Pueblo Canyon, and Los Alamos Canyon found residual contamination at the site itself and in the channel and banks of Acid, Pueblo, and lower Los Alamos Canyons all the way to the Rio Grande. The largest reservoir of residual radioactivity is in lower Pueblo Canyon, which is on DOE property. However, residual radioactivity does not exceed proposed cleanup criteria in either lower Pueblo or lower Los Alamos Canyons. The three alternatives proposed are (1) to take no action, (2) to construct a sediment trap in lower Pueblo Canyon to prevent further transport of residual radioactivity onto San Ildefonso Indian Pueblo land, and (3) to clean the residual radioactivity from the canyon system. Alternative 2, to cleanup the canyon system, is rejected as a viable alternative. Thousands of truckloads of sediment would have to be removed and disposed of, and this effort is unwarranted by the low levels of contamination present. Residual radioactivity levels, under either present conditions or projected future conditions, will not result in significant radiation doses to persons exposed. Modeling efforts show that future transport activity will not result in any residual radioactivity concentrations higher than those already existing. Thus, although construction of a sediment trap in lower Pueblo Canyon is a viable alternative, this effort also is unwarranted, and the no-action alternative is the preferred alternative

Environmental analysis of Lower Pueblo/Lower Los Alamos Canyon, Los Alamos, New Mexico

Energy Technology Data Exchange (ETDEWEB)

Ferenbaugh, R.W.; Buhl, T.E.; Stoker, A.K.; Becker, N.M.; Rodgers, J.C.; Hansen, W.R.

1994-12-01

The radiological survey of the former radioactive waste treatment plant site (TA-45), Acid Canyon, Pueblo Canyon, and Los Alamos Canyon found residual contamination at the site itself and in the channel and banks of Acid, Pueblo, and lower Los Alamos Canyons all the way to the Rio Grande. The largest reservoir of residual radioactivity is in lower Pueblo Canyon, which is on DOE property. However, residual radioactivity does not exceed proposed cleanup criteria in either lower Pueblo or lower Los Alamos Canyons. The three alternatives proposed are (1) to take no action, (2) to construct a sediment trap in lower Pueblo Canyon to prevent further transport of residual radioactivity onto San Ildefonso Indian Pueblo land, and (3) to clean the residual radioactivity from the canyon system. Alternative 2, to cleanup the canyon system, is rejected as a viable alternative. Thousands of truckloads of sediment would have to be removed and disposed of, and this effort is unwarranted by the low levels of contamination present. Residual radioactivity levels, under either present conditions or projected future conditions, will not result in significant radiation doses to persons exposed. Modeling efforts show that future transport activity will not result in any residual radioactivity concentrations higher than those already existing. Thus, although construction of a sediment trap in lower Pueblo Canyon is a viable alternative, this effort also is unwarranted, and the no-action alternative is the preferred alternative.

Dissolving Microneedle Patch for Transdermal Delivery of Human Growth Hormone

Science.gov (United States)

Lee, Jeong Woo; Choi, Seong-O; Felner, Eric I.

2014-01-01

Clinical impact of biotechnology has been constrained by the limitations of traditional hypodermic injection of biopharmaceuticals. Microneedle patches have been proposed as a minimally invasive alternative. In this study, we assess the translation of a dissolving microneedle patch designed for simple, painless self-administration of biopharmacetucials that generates no sharp biohazardous waste. To study pharmacokinetics and safety of this approach, human growth hormone (hGH) was encapsulated in 600 μm long dissolving microneedles composed of carboxymethylcellulose and trehalose using an aqueous, moderate-temperature process that maintained complete hGH activity after encapsulation and retained most activity after storage for up to 15 months at room temperature and humidity. After manual insertion into the skin of hairless rats, hGH pharmacokinetics were similar to conventional subcutaneous injection. After patch removal, the microneedles had almost completely dissolved, leaving behind only blunt stubs. The dissolving microneedle patch was well tolerated, causing only slight, transient erythema. This study suggests that a dissolving microneedle patch can deliver hGH and other biopharmaceuticals in a manner suitable for self-administration without sharp biohazardous waste. PMID:21360810

Urban air quality management : effects of trees on air pollution concentration in urban street canyon

NARCIS (Netherlands)

Salim, S.M.; Buccolieri, R.; Chan, A.; Sabatino, Di S.; Gromke, C.

2009-01-01

The aerodynamic effects of avenue-like tree planting on air flow and traffic-originated pollutant dispersion in urban built-up areas (i.e. street canyons of width to height ratio, W/H=1) are investigated using computational fluid dynamics techniques and complemented with extensive wind tunnel

Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition

Science.gov (United States)

Tripati, Aradhna K.; Hill, Pamela S.; Eagle, Robert A.; Mosenfelder, Jed L.; Tang, Jianwu; Schauble, Edwin A.; Eiler, John M.; Zeebe, Richard E.; Uchikawa, Joji; Coplen, Tyler B.; Ries, Justin B.; Henry, Drew

2015-10-01

;Clumped-isotope; thermometry is an emerging tool to probe the temperature history of surface and subsurface environments based on measurements of the proportion of 13C and 18O isotopes bound to each other within carbonate minerals in 13C18O16O22- groups (heavy isotope ;clumps;). Although most clumped isotope geothermometry implicitly presumes carbonate crystals have attained lattice equilibrium (i.e., thermodynamic equilibrium for a mineral, which is independent of solution chemistry), several factors other than temperature, including dissolved inorganic carbon (DIC) speciation may influence mineral isotopic signatures. Therefore we used a combination of approaches to understand the potential influence of different variables on the clumped isotope (and oxygen isotope) composition of minerals. We conducted witherite precipitation experiments at a single temperature and at varied pH to empirically determine 13C-18O bond ordering (Δ47) and δ18O of CO32- and HCO3- molecules at a 25 °C equilibrium. Ab initio cluster models based on density functional theory were used to predict equilibrium 13C-18O bond abundances and δ18O of different DIC species and minerals as a function of temperature. Experiments and theory indicate Δ47 and δ18O compositions of CO32- and HCO3- ions are significantly different from each other. Experiments constrain the Δ47-δ18O slope for a pH effect (0.011 ± 0.001; 12 ⩾ pH ⩾ 7). Rapidly-growing temperate corals exhibit disequilibrium mineral isotopic signatures with a Δ47-δ18O slope of 0.011 ± 0.003, consistent with a pH effect. Our theoretical calculations for carbonate minerals indicate equilibrium lattice calcite values for Δ47 and δ18O are intermediate between HCO3- and CO32-. We analyzed synthetic calcites grown at temperatures ranging from 0.5 to 50 °C with and without the enzyme carbonic anhydrase present. This enzyme catalyzes oxygen isotopic exchange between DIC species and is present in many natural systems. The two

Unsaturated Groundwater Flow Beneath Upper Mortandad Canyon, Los Alamos, New Mexico

Energy Technology Data Exchange (ETDEWEB)

Dander, David Carl [Univ. of Arizona, Tucson, AZ (United States)

1998-10-15

Mortandad Canyon is a discharge site for treated industrial effluents containing radionuclides and other chemicals at Los Alamos National Laboratory, New Mexico. This study was conducted to develop an understanding of the unsaturated hydrologic behavior below the canyon floor. The main goal of this study was to evaluate the hypothetical performance of the vadose zone above the water table. Numerical simulations of unsaturated groundwater flow at the site were conducted using the Finite Element Heat and Mass Transfer (FEHM) code. A two-dimensional cross-section along the canyon's axis was used to model flow between an alluvial groundwater system and the regional aquifer approximately 300 m below. Using recharge estimated from a water budget developed in 1967, the simulations showed waters from the perched water table reaching the regional aquifer in 13.8 years, much faster than previously thought. Additionally, simulations indicate that saturation is occurring in the Guaje pumice bed an d that the Tshirege Unit 1B is near saturation. Lithologic boundaries between the eight materials play an important role in flow and solute transport within the system. Horizontal flow is shown to occur in three thin zones above capillary barriers; however, vertical flow dominates the system. Other simulations were conducted to examine the effects of changing system parameters such as varying recharge inputs, varying the distribution of recharge, and bypassing fast-path fractured basalt of uncertain extent and properties. System sensitivity was also explored by changing model parameters with respect to size and types of grids and domains, and the presence of dipping stratigraphy.

Water-quality conditions near the confluence of the Snake and Boise Rivers, Canyon County, Idaho

Science.gov (United States)

Wood, Molly S.; Etheridge, Alexandra

2011-01-01

Total Maximum Daily Loads (TMDLs) have been established under authority of the Federal Clean Water Act for the Snake River-Hells Canyon reach, on the border of Idaho and Oregon, to improve water quality and preserve beneficial uses such as public consumption, recreation, and aquatic habitat. The TMDL sets targets for seasonal average and annual maximum concentrations of chlorophyll-a at 14 and 30 micrograms per liter, respectively. To attain these conditions, the maximum total phosphorus concentration at the mouth of the Boise River in Idaho, a tributary to the Snake River, has been set at 0.07 milligrams per liter. However, interactions among chlorophyll-a, nutrients, and other key water-quality parameters that may affect beneficial uses in the Snake and Boise Rivers are unknown. In addition, contributions of nutrients and chlorophyll-a loads from the Boise River to the Snake River have not been fully characterized. To evaluate seasonal trends and relations among nutrients and other water-quality parameters in the Boise and Snake Rivers, a comprehensive monitoring program was conducted near their confluence in water years (WY) 2009 and 2010. The study also provided information on the relative contribution of nutrient and sediment loads from the Boise River to the Snake River, which has an effect on water-quality conditions in downstream reservoirs. State and site-specific water-quality standards, in addition to those that relate to the Snake River-Hells Canyon TMDL, have been established to protect beneficial uses in both rivers. Measured water-quality conditions in WY2009 and WY2010 exceeded these targets at one or more sites for the following constituents: water temperature, total phosphorus concentrations, total phosphorus loads, dissolved oxygen concentration, pH, and chlorophyll-a concentrations (WY2009 only). All measured total phosphorus concentrations in the Boise River near Parma exceeded the seasonal target of 0.07 milligram per liter. Data collected

Geomorphic characterization of four shelf-sourced submarine canyons along the U.S. Mid-Atlantic continental margin

Science.gov (United States)

Obelcz, Jeffrey; Brothers, Daniel S.; Chaytor, Jason D.; ten Brink, Uri S.; Ross, Steve W.; Brooke, Sandra

2013-01-01

Shelf-sourced submarine canyons are common features of continental margins and are fundamental to deep-sea sedimentary systems. Despite their geomorphic and geologic significance, relatively few passive margin shelf-breaching canyons worldwide have been mapped using modern geophysical methods. Between 2007 and 2012 a series of geophysical surveys was conducted across four major canyons of the US Mid-Atlantic margin: Wilmington, Baltimore, Washington, and Norfolk canyons. More than 5700 km2 of high-resolution multibeam bathymetry and 890 line-km of sub-bottom CHIRP profiles were collected along the outer shelf and uppermost slope (depths of 80-1200 m). The data allowed us to compare and contrast the fine-scale morphology of each canyon system. The canyons have marked differences in the morphology and orientation of canyon heads, steepness and density of sidewall gullies, and the character of the continental shelf surrounding canyon rims. Down-canyon axial profiles for Washington, Baltimore and Wilmington canyons have linear shapes, and each canyon thalweg exhibits morphological evidence for recent, relatively small-scale sediment transport. For example, Washington Canyon displays extremely steep wall gradients and contains ~100 m wide, 5–10 m deep, v-shaped incisions down the canyon axis, suggesting modern or recent sediment transport. In contrast, the convex axial thalweg profile, the absence of thalweg incision, and evidence for sediment infilling at the canyon head, suggest that depositional processes strongly influence Norfolk Canyon during the current sea-level high-stand. The north walls of Wilmington, Washington and Norfolk canyons are steeper than the south walls due to differential erosion, though the underlying cause for this asymmetry is not clear. Furthermore, we speculate that most of the geomorphic features observed within the canyons (e.g., terraces, tributary canyons, gullies, and hanging valleys) were formed during the Pleistocene, and show only

Effect of asymmetrical street canyons on pedestrian thermal comfort in warm-humid climate of Cuba

Science.gov (United States)

Rodríguez-Algeciras, José; Tablada, Abel; Matzarakis, Andreas

2017-07-01

Walkability and livability in cities can be enhanced by creating comfortable environments in the streets. The profile of an urban street canyon has a substantial impact on outdoor thermal conditions at pedestrian level. This paper deals with the effect of asymmetrical street canyon profiles, common in the historical centre of Camagüey, Cuba, on outdoor thermal comfort. Temporal-spatial analyses are conducted using the Heliodon2 and the RayMan model, which enable the generation of accurate predictions about solar radiation and thermal conditions of urban spaces, respectively. On these models, urban settings are represented by asymmetrical street canyons with five different height-to-width ratios and four street axis orientations (N-S, NE-SW, E-W, SE-NW). Results are evaluated for daytime hours across the street canyon, by means of the physiologically equivalent temperature (PET index) which allows the evaluation of the bioclimatic conditions of outdoor environments. Our findings revealed that high profiles (façades) located on the east-facing side of N-S streets, on the southeast-facing side of NE-SW streets, on the south-facing side of E-W street, and on the southwest-facing side of SE-NW streets, are recommended to reduce the total number of hours under thermal stress. E-W street canyons are the most thermally stressed ones, with extreme PET values around 36 °C. Deviating from this orientation ameliorates the heat stress with reductions of up to 4 h in summer. For all analysed E-W orientations, only about one fifth of the street can be comfortable, especially for high aspect ratios (H/W > 3). Optimal subzones in the street are next to the north side of the E-W street, northwest side of the NE-SW street, and southwest side of the SE-NW street. Besides, when the highest profile is located on the east side of N-S streets, then the subzone next to the east-facing façade is recommendable for pedestrians. The proposed urban guidelines enable urban planners to create

Influence of dissolved organic matter and manganese oxides on metal speciation in soil solution: A modelling approach.

Science.gov (United States)

Schneider, Arnaud R; Ponthieu, Marie; Cancès, Benjamin; Conreux, Alexandra; Morvan, Xavier; Gommeaux, Maxime; Marin, Béatrice; Benedetti, Marc F

2016-06-01

Trace element (TE) speciation modelling in soil solution is controlled by the assumptions made about the soil solution composition. To evaluate this influence, different assumptions using Visual MINTEQ were tested and compared to measurements of free TE concentrations. The soil column Donnan membrane technique (SC-DMT) was used to estimate the free TE (Cd, Cu, Ni, Pb and Zn) concentrations in six acidic soil solutions. A batch technique using DAX-8 resin was used to fractionate the dissolved organic matter (DOM) into four fractions: humic acids (HA), fulvic acids (FA), hydrophilic acids (Hy) and hydrophobic neutral organic matter (HON). To model TE speciation, particular attention was focused on the hydrous manganese oxides (HMO) and the Hy fraction, ligands not considered in most of the TE speciation modelling studies in soil solution. In this work, the model predictions of free ion activities agree with the experimental results. The knowledge of the FA fraction seems to be very useful, especially in the case of high DOM content, for more accurately representing experimental data. Finally, the role of the manganese oxides and of the Hy fraction on TE speciation was identified and, depending on the physicochemical conditions of the soil solution, should be considered in future studies. Copyright © 2016 Elsevier Ltd. All rights reserved.

Rapidly-Dissolving Silver-Containing Bioactive Glasses for Cariostatic Applications

Directory of Open Access Journals (Sweden)

Omar Rodriguez

2018-04-01

Full Text Available A novel bioactive glass series containing incremental amounts of silver oxide was synthesized, ground down, and subsequently incorporated into a dentifrice for the purpose of reducing the incidence of dental caries and lesion formation. Three glasses were synthesized using the melt quench route: Si-Control (70SiO2–12CaO–3P2O5–15Na2O, mol %, Si-02 and Si-05, where 0.2 and 0.5 mol % Ag2O were substituted, respectively, for SiO2 in Si-Control. The glasses were then ground, sieved, characterized, and dissolved in Tris buffer solution (pH = 7.30 for 6, 12, and 24 h, with the pH of the resultant solution being recorded and the ions that were released into solution quantified. Samples of each glass were subsequently embedded into a non-fluoridated, commercially available toothpaste which was then used to brush resin-mounted lamb molars which, up to the point of testing, had been stored in a 1.0 M HCl solution. Knoop microhardness measurements of the molars were recorded before and after brushing to determine the presence of remineralization on the surface of the teeth (surface hardness loss of 37%, 35%, and 34% for Si-Control, Si-02 and Si-05, respectively, after 24 h. Four oral cavity bacterial strains were isolated through swabs of the inner cheek, gums, and teeth surfaces of three volunteers, and placed on agar discs. Of each glass, 0.5 g was placed onto the discs, and the resultant inhibition zones were measured after 6, 12, and 24 h. Si-05 performed better than Si-02 on two strains after 24 h, while exhibiting similar behavior for the remaining two strains after 24 h; the largest inhibition zone measured was 2.8 mm, for Si-05 after 12 h. Si-Control exhibited no antibacterial effect at any time point, providing evidence for the role of silver oxide as the antibacterial component of these glasses.

On the escape of pollutants from urban street canyons

Energy Technology Data Exchange (ETDEWEB)

Baik, J.J.; Kim, J.J. [Kwangju Inst. of Science and Technology (Korea). Dept. of Environmental Science and Engineering

2002-07-01

Pollutant transport from urban street canyons is numerically investigated using a two-dimensional flow and dispersion model. The ambient wind blows perpendicular to the street and passive pollutants are released at the street level. Results from the control experiment with a street aspect ratio of 1 show that at the roof level of the street canyon, the vertical turbulent flux of pollutants is upward everywhere and the vertical flux of pollutants by mean flow is upward or downward. The horizontally integrated vertical flux of pollutants by mean flow at the roof level of the street canyon is downward and its magnitude is much smaller than that by turbulent process. These results indicate that pollutants escape from the street canyon mainly by turbulent process and that the net effect of mean flow is to make some escaped pollutants reenter the street canyon. Further experiments with different inflow turbulence intensities, inflow wind speeds, and street aspect ratio confirm the findings from the control experiment. In the case of two isolated buildings, the horizontally integrated vertical flux of pollutants by mean flow is upward due to flow separation but the other main results are the same as those from the control experiment. (author)

Effects of solution heat treatment on the microstructure and hardness of Mg-5Li-3Al-2Zn-2Cu alloy

Energy Technology Data Exchange (ETDEWEB)

Li Jiqing; An Jiangmin; Qu Zhikun [Key Laboratory of Superlight Materials and Surface Technology (Harbin Engineering University), Ministry of Education, Harbin 150001 (China); Wu Ruizhi, E-mail: Ruizhiwu2006@yahoo.com [Key Laboratory of Superlight Materials and Surface Technology (Harbin Engineering University), Ministry of Education, Harbin 150001 (China); Zhang Jinghuai; Zhang Milin [Key Laboratory of Superlight Materials and Surface Technology (Harbin Engineering University), Ministry of Education, Harbin 150001 (China)

2010-10-15

The microstructure and hardness of Mg-5Li-3Al-2Zn-2Cu alloy were investigated both in the as-cast condition and after solution heat treatment at 330-390 deg. C for 5 h. The as-cast alloy contains a microstructure consisting of {alpha}-Mg matrix, AlLi phase, AlCuMg phase and Al{sub 2}Cu phase. After the solution heat treament, the AlLi phase was dissolved into the matrix, however, the AlCuMg and Al{sub 2}Cu phases were not dissolved. With the increase of solution temperature, almost all the AlLi phase was dissolved, and the effects of solution strengthening of Al and Li atoms in the alloy increase, which results in the gradual increase of the Brinell hardness of the solution-treated alloy.

Degradation and detoxification of aqueous nitrophenol solutions by electron beam irradiation

International Nuclear Information System (INIS)

Song Weihua; Zheng Zheng; Rami, Abual-Suud; Zhou Tao; Hang Desheng

2002-01-01

The goal of this research was to study the degradation of nitrophenol solutions by high-energy electron beam irradiation. The results showed that the degradation processes obey an apparent first-order degradation. At the higher irradiation doses the pH of solutions decreased; however, the dissolved organic carbon of the solutions was essentially unchanged. To investigate the toxicity of the radiolytic products the oxygen uptake rate of activated sludge was determined. The toxicity of irradiated nitrophenol solutions decreased from the initial non-irradiated solutions

The timing of sediment transport down Monterey Submarine Canyon, offshore California

Science.gov (United States)

Stevens, Thomas; Paull, Charles K.; Ussler, William III; McGann, Mary; Buylaert, Jan-Pieter; Lundsten, Eve M.

2013-01-01

While submarine canyons are the major conduits through which sediments are transported from the continents out into the deep sea, the time it takes for sediment to pass down through a submarine canyon system is poorly constrained. Here we report on the first study to couple optically stimulated luminescence (OSL) ages of quartz sand deposits and accelerator mass spectrometry 14C ages measured on benthic foraminifera to examine the timing of sediment transport through the axial channel of Monterey Submarine Canyon and Fan, offshore California. The OSL ages date the timing of sediment entry into the canyon head while the 14C ages of benthic foraminifera record the deposition of hemipelagic sediments that bound the sand horizons. We use both single-grain and small (∼2 mm area) single-aliquot regeneration approaches on vibracore samples from fining-upward sequences at various water depths to demonstrate relatively rapid, decadal-scale sand transport to at least 1.1 km depth and more variable decadal- to millennial-scale transport to a least 3.5 km depth on the fan. Significant differences between the time sand was last exposed at the canyon head (OSL age) and the timing of deposition of the sand (from 14C ages of benthic foraminifera in bracketing hemipelagic sediments) are interpreted as indicating that the sand does not pass through the entire canyon instantly in large individual events, but rather moves multiple times before emerging onto the fan. The increased spread in single-grain OSL dates with water depth provides evidence of mixing and temporary storage of sediment as it moves through the canyon system. The ages also indicate that the frequency of sediment transport events decreases with distance down the canyon channel system. The amalgamated sands near the canyon head yield OSL ages that are consistent with a sub-decadal recurrence frequency while the fining-upward sand sequences on the fan indicate that the channel is still experiencing events with a 150�

Computer model of hydroponics nutrient solution pH control using ammonium.

Science.gov (United States)

Pitts, M; Stutte, G

1999-01-01

A computer simulation of a hydroponics-based plant growth chamber using ammonium to control pH was constructed to determine the feasibility of such a system. In nitrate-based recirculating hydroponics systems, the pH will increase as plants release hydroxide ions into the nutrient solution to maintain plant charge balance. Ammonium is an attractive alternative to traditional pH controls in an ALSS, but requires careful monitoring and control to avoid overdosing the plants with ammonium. The primary advantage of using NH4+ for pH control is that it exploits the existing plant nutrient uptake charge balance mechanisms to maintain solution pH. The simulation models growth, nitrogen uptake, and pH of a l-m2 stand of wheat. Simulation results indicated that ammonium-based control of nutrient solution pH is feasible using a proportional integral controller. Use of a 1 mmol/L buffer (Ka = 1.6 x 10(-6)) in the nutrient solution is required.

Hydraulics of outburst floods spilling over a steep-walled canyon: Implications for paleo-discharges on Mars

Science.gov (United States)

Lapotre, Mathieu; Lamb, Michael

2013-04-01

Canyons carved by outburst floods are common landforms on Earth and Mars. These canyons are generally found in fractured basalts and jointed sedimentary rocks. Flood-carved canyons commonly have steep headwalls and a roughly constant width, and are often thought to have formed from upstream headwall propagation due to waterfall erosion. Because morphology is readily available from satellite imagery, these canyons offer a unique opportunity to quantify the discharge of rare, catastrophic paleo-floods on Earth and Mars. However, mechanistic relationships that relate canyon size to flood discharge have yet to be developed. We propose that the width of a canyon headwall in fractured rock is set by the spatial distribution of erosion around the rim of the canyon, which is controlled by the distribution of shear stresses induced by the overflowing water as it is focused into the canyon head. We test this hypothesis by performing a series of numerical simulations of flood-water focusing using ANUGA Hydro, a 2D-depth averaged, fully turbulent, hydraulic numerical modeling suite allowing for Froude-number transitions. The numerical simulations were designed to explore five dimensionless variables: the aspect ratio of the canyon (length normalized by width), the canyon width to flood-water width ratio, the canyon width to normal-flow depth ratio, the Froude number, and the topographic gradient upstream of the canyon. Preliminary results show that flow focusing leads to increased shear stresses at the canyon head compared to the sides of the canyon for subcritical floods and higher canyon aspect ratios. This suggests that proto-canyons start growing from a topographic defect in all directions until they reach a critical length for the side walls to dry. Once this critical length is attained, canyons focus most of the flood waters into their heads, and propagate upstream only, maintaining roughly constant widths. Preliminary results suggest that canyon width may be used to

Natural dissolved organic matter mobilizes Cd but does not affect the Cd uptake by the green algae Pseudokirchneriella subcapitata (Korschikov) in resin buffered solutions

Energy Technology Data Exchange (ETDEWEB)

Verheyen, Liesbeth, E-mail: verheyenliesbeth@gmail.com; Versieren, Liske, E-mail: liske.versieren@ees.kuleuven.be; Smolders, Erik, E-mail: erik.smolders@ees.kuleuven.be

2014-09-15

Highlights: • Different DOM samples were added to solutions with a resin buffered Cd{sup 2+} activity. • This increased total dissolved Cd by factors 3–16 due to complexation reactions. • Cd uptake in algae was unaffected or increased maximally 1.6 fold upon addition. • Free Cd{sup 2+} is the main bioavailable form of Cd for algae in well buffered solutions. - Abstract: Natural dissolved organic matter (DOM) can have contrasting effects on metal bioaccumulation in algae because of complexation reactions that reduce free metal ion concentrations and because of DOM adsorption to algal surfaces which promote metal adsorption. This study was set up to reveal the role of different natural DOM samples on cadmium (Cd) uptake by the green algae Pseudokirchneriella subcapitata (Korschikov). Six different DOM samples were collected from natural freshwater systems and isolated by reverse osmosis. In addition, one {sup 13}C enriched DOM sample was isolated from soil to trace DOM adsorption to algae. Algae were exposed to standardized solutions with or without these DOM samples, each exposed at equal DOM concentrations and at equal non-toxic Cd{sup 2+} activity (∼4 nM) that was buffered with a resin. The DOM increased total dissolved Cd by factors 3–16 due to complexation reactions at equal Cd{sup 2+} activity. In contrast, the Cd uptake was unaffected by DOM or increased maximally 1.6 fold ({sup 13}C enriched DOM). The {sup 13}C analysis revealed that maximally 6% of algal C was derived from DOM and that this can explain the small increase in biomass Cd. It is concluded that free Cd{sup 2+} and not DOM-complexed Cd is the main bioavailable form of Cd when solution Cd{sup 2+} is well buffered.

Composition characteristics and regularities of dissolving of hydroxyapatite materials obtained in water solutions with varied content of silicate ions

Science.gov (United States)

Solonenko, A. P.

2018-01-01

Research aimed at developing new bioactive materials for the repair of defects in bone tissues, do not lose relevance due to the strengthening of the regenerative approach in medicine. From this point of view, materials based on calcium phosphates, including silicate ions, consider as one of the most promising group of substances. Methods of synthesis and properties of hydroxyapatite doped with various amounts of SiO4 4- ions are described in literature. In the present work synthesis of a solid phase in the systems Ca(NO3)2 - (NH4)2HPO4 - Na2SiO3 - NH4OH - H2O (Cca/CP = 1.70) performed with a wide range of sodium silicate additive concentration (y = CSi/CP = 0 ÷ 5). It is established that under the studied conditions at y ≥ 0.3 highly dispersed poorly crystallized apatite containing isomorphic impurities of CO3 2- and SiO4 4- precipitates in a mixture with calcium hydrosilicate and SiO2. It is shown that the resulting composites can gradually dissolve in physiological solution and initiate passive formation of the mineral component of hard tissues.

Regional economic impacts of Grand Canyon river runners.

Science.gov (United States)

Hjerpe, Evan E; Kim, Yeon-Su

2007-10-01

Economic impact analysis (EIA) of outdoor recreation can provide critical social information concerning the utilization of natural resources. Outdoor recreation and other non-consumptive uses of resources are viewed as environmentally friendly alternatives to extractive-type industries. While outdoor recreation can be an appropriate use of resources, it generates both beneficial and adverse socioeconomic impacts on rural communities. The authors used EIA to assess the regional economic impacts of rafting in Grand Canyon National Park. The Grand Canyon region of northern Arizona represents a rural US economy that is highly dependent upon tourism and recreational expenditures. The purpose of this research is twofold. The first is to ascertain the previously unknown regional economic impacts of Grand Canyon river runners. The second purpose is to examine attributes of these economic impacts in terms of regional multipliers, leakage, and types of employment created. Most of the literature on economic impacts of outdoor recreation has focused strictly on the positive economic impacts, failing to illuminate the coinciding adverse and constraining economic impacts. Examining the attributes of economic impacts can highlight deficiencies and constraints that limit the economic benefits of recreation and tourism. Regional expenditure information was obtained by surveying non-commercial boaters and commercial outfitters. The authors used IMPLAN input-output modeling to assess direct, indirect, and induced effects of Grand Canyon river runners. Multipliers were calculated for output, employment, and income. Over 22,000 people rafted on the Colorado River through Grand Canyon National Park in 2001, resulting in an estimated $21,100,000 of regional expenditures to the greater Grand Canyon economy. However, over 50% of all rafting-related expenditures were not captured by the regional economy and many of the jobs created by the rafting industry are lower-wage and seasonal. Policy

Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition

Science.gov (United States)

Tripati, Aradhna K.; Hill, Pamela S.; Eagle, Robert A.; Mosenfelder, Jed L.; Tang, Jianwu; Schauble, Edwin A.; Eiler, John M.; Zeebe, Richard E.; Uchikawa, Joji; Coplen, Tyler B.; Ries, Justin B.; Henry, Drew

2015-01-01

“Clumped-isotope” thermometry is an emerging tool to probe the temperature history of surface and subsurface environments based on measurements of the proportion of 13C and 18O isotopes bound to each other within carbonate minerals in 13C18O16O22- groups (heavy isotope “clumps”). Although most clumped isotope geothermometry implicitly presumes carbonate crystals have attained lattice equilibrium (i.e., thermodynamic equilibrium for a mineral, which is independent of solution chemistry), several factors other than temperature, including dissolved inorganic carbon (DIC) speciation may influence mineral isotopic signatures. Therefore we used a combination of approaches to understand the potential influence of different variables on the clumped isotope (and oxygen isotope) composition of minerals.We conducted witherite precipitation experiments at a single temperature and at varied pH to empirically determine 13C-18O bond ordering (Δ47) and δ18O of CO32- and HCO3- molecules at a 25 °C equilibrium. Ab initio cluster models based on density functional theory were used to predict equilibrium 13C-18O bond abundances and δ18O of different DIC species and minerals as a function of temperature. Experiments and theory indicate Δ47 and δ18O compositions of CO32- and HCO3- ions are significantly different from each other. Experiments constrain the Δ47-δ18O slope for a pH effect (0.011 ± 0.001; 12 ⩾ pH ⩾ 7). Rapidly-growing temperate corals exhibit disequilibrium mineral isotopic signatures with a Δ47-δ18O slope of 0.011 ± 0.003, consistent with a pH effect.Our theoretical calculations for carbonate minerals indicate equilibrium lattice calcite values for Δ47 and δ18O are intermediate between HCO3− and CO32−. We analyzed synthetic calcites grown at temperatures ranging from 0.5 to 50 °C with and without the enzyme carbonic anhydrase present. This enzyme catalyzes oxygen isotopic exchange between DIC species and is present in many

The Jurassic section along McElmo Canyon in southwestern Colorado

Science.gov (United States)

O'Sullivan, Robert B.

1997-01-01

In McElmo Canyon, Jurassic rocks are 1500-1600 ft thick. Lower Jurassic rocks of the Glen Canyon Group include (in ascending order) Wingate Sandstone, Kayenta Formation and Navajo Sandstone. Middle Jurassic rocks are represented by the San Rafael Group, which includes the Entrada Sandstone and overlying Wanakah Formation. Upper Jurassic rocks comprise the Junction Creek Sandstone overlain by the Morrison Formation. The Burro Canyon Formation, generally considered to be Lower Cretaceous, may be Late Jurassic in the McElmo Canyon area and is discussed with the Jurassic. The Upper Triassic Chinle Formation in the subsurface underlies, and the Upper Cretaceous Dakota Sandstone overlies, the Jurassic section. An unconformity is present at the base of the Glen Canyon Group (J-0), at the base of the San Rafael Group (J-2), and at the base of the Junction Creek Sandstone (J-5). Another unconformity of Cretaceous age is at the base of the Dakota Sandstone. Most of the Jurassic rocks consist of fluviatile, lacustrine and eolian deposits. The basal part of the Entrada Sandstone and the Wanakah Formation may be of marginal marine origin.

Event-driven sediment flux in Hueneme and Mugu submarine canyons, southern California

Science.gov (United States)

Xu, J. P.; Swarzenski, P.W.; Noble, M.; Li, A.-C.

2010-01-01

Vertical sediment fluxes and their dominant controlling processes in Hueneme and Mugu submarine canyons off south-central California were assessed using data from sediment traps and current meters on two moorings that were deployed for 6 months during the winter of 2007. The maxima of total particulate flux, which reached as high as 300+ g/m2/day in Hueneme Canyon, were recorded during winter storm events when high waves and river floods often coincided. During these winter storms, wave-induced resuspension of shelf sediment was a major source for the elevated sediment fluxes. Canyon rim morphology, rather than physical proximity to an adjacent river mouth, appeared to control the magnitude of sediment fluxes in these two submarine canyon systems. Episodic turbidity currents and internal bores enhanced sediment fluxes, particularly in the lower sediment traps positioned 30 m above the canyon floor. Lower excess 210Pb activities measured in the sediment samples collected during periods of peak total particulate flux further substantiate that reworked shelf-, rather than newly introduced river-borne, sediments supply most of the material entering these canyons during storms.

Diablo Canyon: the challenges of the Californian nuclear

International Nuclear Information System (INIS)

Avrin, Anne-Perrine; Zweibaum, Nicolas

2014-01-01

This article addresses the Californian nuclear plant of Diablo Canyon which, due to the shutting down of the two reactors of another plant, could be the last nuclear plant to operate in California as this state voted an interdiction of construction of any new nuclear plant until a permanent solution has been found for radioactive waste storage. It is outlined that this nuclear plant is the most controlled nuclear plant throughout the USA, presents an unchallenged security level despite it is built at the vicinity of seismic fault lines. It outlines that the problem of waste storage is far from being solved in California, and discusses the future role of nuclear energy in California within the context of global warming

A selective and sensitive optical sensor for dissolved ammonia detection via agglomeration of fluorescent Ag nanoclusters and temperature gradient headspace single drop microextraction.

Science.gov (United States)

Dong, Jiang Xue; Gao, Zhong Feng; Zhang, Ying; Li, Bang Lin; Li, Nian Bing; Luo, Hong Qun

2017-05-15

In this paper, a simple sensor platform is presented for highly selective and sensitive detection of dissolved ammonia in aqueous solutions without pretreatment based on temperature gradient headspace single drop microextraction (HS-SDME) technique, and fluorescence and UV-vis spectrophotometry are utilized with the Ag nanoclusters (Ag NCs) functioned by citrate and glutathione as the probe. The sensing mechanism is based on the volatility of ammonia gas and the active response of Ag NCs to pH change caused by the introduction of ammonia. High pH can make the Ag NCs agglomerate and lead to the obvious decrease of fluorescence intensity and absorbance of Ag NCs solution. Moreover, the presented method exhibits a remarkably high selectivity toward dissolved ammonia over most of inorganic ions and amino acid, and shows a good linear range of 10-350μM (0.14-4.9mgNL -1 ) with a low detection limit of 336nM (4.70μgNL -1 ) at a signal-to-noise ratio of 3. In addition, the practical applications of the sensor have been successfully demonstrated by detecting dissolved ammonia in real samples. Copyright © 2016 Elsevier B.V. All rights reserved.

The Porcupine Bank Canyon coral mounds: oceanographic and topographic steering of deep-water carbonate mound development and associated phosphatic deposition

Science.gov (United States)

Mazzini, A.; Akhmetzhanov, A.; Monteys, X.; Ivanov, M.

2012-06-01

The head of a canyon system extending along the western Porcupine Bank (west of Ireland) and which accommodates a large field of giant carbonate mounds was investigated during two cruises (INSS 2000 and TTR-13). Multibeam and sidescan sonar data (600-1,150 m water depth) suggest that the pre-existing seabed topography acts as a significant factor controlling mound distribution and shape. The mounds are concentrated along the edges of the canyon or are associated with a complex fault system traced around the canyon head, comprising escarpments up to 60 m high and several km long. The sampling for geochemical and petrographic analysis of numerous types of authigenic deposits was guided by sidescan sonar and video recordings. Calcite-cemented biogenic rubble was observed at the top and on the flanks of the carbonate mounds, being associated with both living and dead corals ( Lophelia pertusa, Madrepora oculata and occasional Desmophyllum cristagalli). This can plausibly be explained by dissolution of coral debris facilitated by strong currents along the mound tops and flanks. In turn, the dissolved carbon is recycled and precipitated as interstitial micrite. Calcite, dolomite and phosphatic hardgrounds were identified in samples from the escarpment framing the eastern part of the survey area. The laterally extensive phosphatic hardgrounds represent a novel discovery in the region, supplying hard substrata for the establishment of new coral colonies. Based on existing knowledge of regional oceanographic conditions, complemented with new CTD measurements, it is suggested that water column stratification, enhanced bottom currents, and upwelling facilitate the deposition of organic matter, followed by phosphatisation leading to the formation of phosphate-glauconite deposits. The occurrence of strong bottom currents was confirmed by means of video observations combined with acoustic and sampling data, providing circumstantial evidence of fine- to medium-grained sand

Big Canyon Creek Ecological Restoration Strategy.

Energy Technology Data Exchange (ETDEWEB)

Rasmussen, Lynn; Richardson, Shannon

2007-10-01

He-yey, Nez Perce for steelhead or rainbow trout (Oncorhynchus mykiss), are a culturally and ecologically significant resource within the Big Canyon Creek watershed; they are also part of the federally listed Snake River Basin Steelhead DPS. The majority of the Big Canyon Creek drainage is considered critical habitat for that DPS as well as for the federally listed Snake River fall chinook (Oncorhynchus tshawytscha) ESU. The Nez Perce Soil and Water Conservation District (District) and the Nez Perce Tribe Department of Fisheries Resources Management-Watershed (Tribe), in an effort to support the continued existence of these and other aquatic species, have developed this document to direct funding toward priority restoration projects in priority areas for the Big Canyon Creek watershed. In order to achieve this, the District and the Tribe: (1) Developed a working group and technical team composed of managers from a variety of stakeholders within the basin; (2) Established geographically distinct sub-watershed areas called Assessment Units (AUs); (3) Created a prioritization framework for the AUs and prioritized them; and (4) Developed treatment strategies to utilize within the prioritized AUs. Assessment Units were delineated by significant shifts in sampled juvenile O. mykiss (steelhead/rainbow trout) densities, which were found to fall at fish passage barriers. The prioritization framework considered four aspects critical to determining the relative importance of performing restoration in a certain area: density of critical fish species, physical condition of the AU, water quantity, and water quality. It was established, through vigorous data analysis within these four areas, that the geographic priority areas for restoration within the Big Canyon Creek watershed are Big Canyon Creek from stream km 45.5 to the headwaters, Little Canyon from km 15 to 30, the mainstem corridors of Big Canyon (mouth to 7km) and Little Canyon (mouth to 7km). The District and the Tribe

Megabenthic assemblages at the Hudson Canyon head (NW Atlantic margin): Habitat-faunal relationships

Science.gov (United States)

Pierdomenico, Martina; Gori, Andrea; Guida, Vincent G.; Gili, Josep-Maria

2017-09-01

The distribution of megabenthic communities at the head of Hudson Canyon and adjacent continental shelf was studied by means of underwater video transects and still photo imagery collected using a towed camera system. The goal was to explore the relationships between faunal distribution and physical seafloor conditions and to test the hypothesis that increased seafloor heterogeneity in the Hudson Canyon supports a larger diversity of benthic communities, compared with the adjacent continental shelf. Hierarchical cluster analysis was performed to identify benthic assemblages as defined in imagery. The BIO-ENV procedure and the Canonical Correspondence Analysis were carried out to elucidate species groupings in relation to terrain variables extracted from bathymetric data. Species accumulation curves were generated to evaluate species turn over in and out of Hudson Canyon. The results indicate that seafloor morphology is the main physical factor related to benthic community composition and distribution. Assemblages dominated by sponges, zoanthids and cup corals colonized the canyon margins and flanks, and were associated with coarse-grained sediments, while sea pen assemblages were observed along muddy seafloor within the thalweg. An assemblage dominated by sea stars occurred on the shelf, associated with a sandy seafloor. Some assemblages were exclusively observed in the canyon area, suggesting that the increased variability of seafloor composition, together with the oceanographic processes specific to the canyon area, enhance beta diversity. The colonization by benthic suspension feeders within the canyon, in contrast to shelf assemblages, mainly composed of carnivores and detritus feeders could be favored the intense hydrodynamics at the canyon head that increase the availability of suspended organic matter. From the perspective of management and conservation of marine resources, the results obtained support the relevance of Hudson Canyon as a biodiversity hotspot

Marble Canyon spring sampling investigation

International Nuclear Information System (INIS)

McCulley, B.

1985-10-01

The Mississippian Leadville Limestone is the most permeable formation in the lower hydrostratigraphic unit underlying the salt beds of the Paradox Formation in Gibson Dome, Paradox Basin, Utah, which is being considered as a potential nuclear waste repository site. The closest downgradient outcrop of the Mississippian limestone is along the Colorado River in Marble Canyon, Arizona. This report describes the sampling and interpretation of springs in that area to assess the relative contribution of Gibson Dome-type Leadville Limestone ground water to that spring discharge. The high-volume (hundreds of liters per second or thousands of gallons per minute) springs discharging from fault zones in Marble Canyon are mixtures of water recharged west of the Colorado River on the Kaibab Plateau and east of the river in the Kaiparowits basin. No component of Gibson Dome-type Leadville Limestone ground water is evident in major and trace element chemistry or isotopic composition of the Marble Canyon Springs. A low-volume (0.3 liters per second or 5 gallons per minute) spring with some chemical and isotopic characteristics of Gibson Dome-type Leadville Limestone water diluted by Kaiparowits basin-type water issues from a travertine mound in the Bright Angel Shale on the Little Colorado River. However, the stable isotopic composition and bromide levels of that spring discharge, in addition to probable ground-water flow paths, contradict the dilution hypothesis

Submarine canyons represent an essential habitat network for krill hotspots in a Large Marine Ecosystem.

Science.gov (United States)

Santora, Jarrod A; Zeno, Ramona; Dorman, Jeffrey G; Sydeman, William J

2018-05-15

Submarine canyon systems are ubiquitous features of marine ecosystems, known to support high levels of biodiversity. Canyons may be important to benthic-pelagic ecosystem coupling, but their role in concentrating plankton and structuring pelagic communities is not well known. We hypothesize that at the scale of a large marine ecosystem, canyons provide a critical habitat network, which maintain energy flow and trophic interactions. We evaluate canyon characteristics relative to the distribution and abundance of krill, critically important prey in the California Current Ecosystem. Using a geological database, we conducted a census of canyon locations, evaluated their dimensions, and quantified functional relationships with krill hotspots (i.e., sites of persistently elevated abundance) derived from hydro-acoustic surveys. We found that 76% of krill hotspots occurred within and adjacent to canyons. Most krill hotspots were associated with large shelf-incising canyons. Krill hotspots and canyon dimensions displayed similar coherence as a function of latitude and indicate a potential regional habitat network. The latitudinal migration of many fish, seabirds and mammals may be enhanced by using this canyon-krill network to maintain foraging opportunities. Biogeographic assessments and predictions of krill and krill-predator distributions under climate change may be improved by accounting for canyons in habitat models.

B-Plant Canyon Ventilation Control System Description; FINAL

International Nuclear Information System (INIS)

MCDANIEL, K.S.

1999-01-01

Project W-059 installed a new B Plant Canyon Ventilation System. Monitoring and control of the system is implemented by the Canyon Ventilation Control System (CVCS). This document describes the CVCS system components which include a Programmable Logic Controller (PLC) coupled with an Operator Interface Unit (OIU) and application software. This document also includes an Alarm Index specifying the setpoints and technical basis for system analog and digital alarms

Photolysis of 2,4,6-trinitrotoluene in seawater and estuary water: Impact of pH, temperature, salinity, and dissolved organic matter

International Nuclear Information System (INIS)

Luning Prak, Dianne J.; Breuer, James E.T.; Rios, Evelyn A.; Jedlicka, Erin E.; O'Sullivan, Daniel W.

2017-01-01

The influence of salinity, pH, temperature, and dissolved organic matter on the photolysis rate of 2,4,6-trinitrotoluene (TNT) in marine, estuary, and laboratory-prepared waters was studied using a Suntest CPS +® solar simulator equipped with optical filters. TNT degradation rates were determined using HPLC analysis, and products were identified using LC/MS. Minimal or no TNT photolysis occurred under a 395-nm long pass filter, but under a 295-nm filter, first-order TNT degradation rate constants and apparent quantum yields increased with increasing salinity in both natural and artificial seawater. TNT rate constants increased slightly with increasing temperature (10 to 32 °C) but did not change significantly with pH (6.4 to 8.1). The addition of dissolved organic matter (up to 5 mg/L) to ultrapure water, artificial seawater, and natural seawater increased the TNT photolysis rate constant. Products formed by TNT photolysis in natural seawater were determined to be 2,4,6-trinitrobenzaldehyde, 1,3,5-trinitrobenzene, 2,4,6-trinitrobenzoic acid, and 2-amino-4,6-dinitrobenzoic acid. - Highlights: • 2,4,6-trinitrotoluene (TNT) was photolyzed in marine, estuary, & laboratory waters. • TNT photolysis rates increased with increasing salinity & dissolved organic matter. • Temperature and pH had minimal impact on TNT photolysis in marine waters. • In seawater, TNT photolysis produced 1,3,5-trinitrobenzene & trinitrobenzaldehyde. • Polar products were 2,4,6-trinobenzoic acid & 2-amino-4,6-dinitrobenzoic acid.

Rapid formation of a modern bedrock canyon by a single flood event

Science.gov (United States)

Lamb, Michael P.; Fonstad, Mark A.

2010-07-01

Deep river canyons are thought to form slowly over geological time (see, for example, ref. 1), cut by moderate flows that reoccur every few years. In contrast, some of the most spectacular canyons on Earth and Mars were probably carved rapidly during ancient megaflood events. Quantification of the flood discharge, duration and erosion mechanics that operated during such events is hampered because we lack modern analogues. Canyon Lake Gorge, Texas, was carved in 2002 during a single catastrophic flood. The event offers a rare opportunity to analyse canyon formation and test palaeo-hydraulic-reconstruction techniques under known topographic and hydraulic conditions. Here we use digital topographic models and visible/near-infrared aerial images from before and after the flood, discharge measured during the event, field measurements and sediment-transport modelling to show that the flood moved metre-sized boulders, excavated ~7m of limestone and transformed a soil-mantled valley into a bedrock canyon in just ~3days. We find that canyon morphology is strongly dependent on rock type: plucking of limestone blocks produced waterfalls, inner channels and bedrock strath terraces, whereas abrasion of cemented alluvium sculpted walls, plunge pools and streamlined islands. Canyon formation was so rapid that erosion might have been limited by the ability of the flow to transport sediment. We suggest that our results might improve hydraulic reconstructions of similar megafloods on Earth and Mars.

Giant landslides and turbidity currents in the Agadir Canyon Region, NW-Africa

Science.gov (United States)

Krastel, Sebastian; Wynn, Russell B.; Stevenson, Christopher; Feldens, Peter; Mehringer, Lisa; Schürer, Anke

2017-04-01

Coring and drilling of the Moroccan Turbidite System off NW-Africa revealed a long sequence of turbidites, mostly sourced from the Moroccan continental margin and the volcanic Canary Islands. The largest individual flow deposits in the Moroccan Turbidite System contain sediment volumes >100 km3, although these large-scale events are relatively infrequent with a recurrence interval of 10,000 years (over the last 200,000 years). The largest siliciclastic flow in the last 200,000 years was the 'Bed 5 event', which transported 160 km3 of sediment up to 2000 km from the Agadir Canyon region to the southwest Madeira Abyssal Plain. While the Moroccan Turbidite System is extremely well investigated, almost no data from the source region, i.e. the Agadir Canyon, are available. Understanding why some submarine landslides remain as coherent blocks of sediment throughout their passage downslope, while others mix and disintegrate almost immediately after initial failure, is a major scientific challenge, which was addressed in the Agadir Canyon source region during RV Maria S. Merian Cruise MSM32 in late 2013. A major landslide area was identified 200 km south of the Agadir Canyon. A landslide was traced from this failure area to the Agadir Canyon. This landslide entered the canyon in about 2500 m water depth. Despite a significant increase in slope angle, the landslide did not disintegrate into a turbidity current when entering the canyon but moved on as landslide for at least another 200 km down the canyon. The age of the landslide ( 145 ka) does not correspond to any major turbidte deposit in the Moroccan Turbidite System, further supporting the fact that the landslide did not disintegrate into a major turbidity current. A core taken about 350 m above the thalweg in the head region of Agadir Canyon shows a single coarse-grained turbidite, which resembles the composition of the Bed 5 event in the Madeira Abyssal Plain. Hence, the Bed 5 turbidite originated as a failure in the

Implications of tree planting on pollutant dispersion in street canyons

NARCIS (Netherlands)

Gromke, C.B.; Ruck, B.

2009-01-01

Traffic pollutant dispersion processes inside urban street canyons with avenue-like tree planting have been studied in wind tunnel experiments. Tree planting of different crown porosities and their effects on the pollutant concentrations at the canyon walls have been investigated for wind

78 FR 21415 - Glen Canyon Dam Adaptive Management Work Group

Science.gov (United States)

2013-04-10

... DEPARTMENT OF THE INTERIOR Bureau of Reclamation Glen Canyon Dam Adaptive Management Work Group... Adaptive Management Work Group (AMWG) makes recommendations to the Secretary of the Interior concerning... Federal advisory committee, the AMWG, a technical work group, a Grand Canyon Monitoring and Research...

Radiation-chemical degradation of chloroform in water solutions

International Nuclear Information System (INIS)

Ahmadov, S.A.; Gurbanov, M.A.; Iskenderova, Z.I.; Abdullayev, E.T.; Ibadov, N.A.

2006-01-01

Full text: Chloroform is the major chlorine-containing compound forming at chlorination of drinking water. As our basic water resources of Kur and Araz rivers are mostly polluted along the territory of the neighbour republics their chlorination for the purpose of biological purification can result in forming of chloroform. Unfortunately, there are only poor data about containing of chloroform in drinking water in the Republic, however the particular problem is to develop new methods of drinking water purification from chloroform, taking into account the high toxicity of this compounds. Appropriate works indicate that radiation-chemical processing can mostly reduce the concentration of chloroform in drinking water. The purification degree can achieve 95-98 percent. This work studies the tendency of chloroform decomposition at its radiolysis processes in water solutions. The concentration of chloroform changed in the range of 0,03-1 weight percentage. Taking into account the dissolvability of chloroform in water solutions it can be said that examined water solutions are homogeneous. Following advancements are studied: 1) Determination of radiation-chemical yield of chloroform decomposition at its various initial concentrations; 2) Impact of adsorbed dose on pH of solutions; 3) Formation of by-products. It is set that radiation-chemical output of chloroform decomposition is equal to 3 * 10 - 3 - 125 mol/100 ev. The high yield of chloroform decomposition can be connected with the chain process of oxidation with presence of dissolved oxygen. However, taking into account the fact that at its water radiolysis the yield of active particles of OH, e - aq, H-atoms does not exceed 6-7 particles/100 ev, the observed high yield can be explained only with the chain process with presence of dissolved oxygen

Advanced characterization of dissolved organic matter released by bloom-forming marine algae

KAUST Repository

Rehman, Zahid Ur

2017-06-01

Algal organic matter (AOM), produced by marine phytoplankton during bloom periods, may adversely affect the performance of membrane processes in seawater desalination. The polysaccharide fraction of AOM has been related to (bio)fouling in micro-filtration and ultrafiltration, and reverse osmosis membranes. However, so far, the chemical structure of the polysaccharides released by bloom-forming algae is not well understood. In this study, dissolved fraction of AOM produced by three algal species (Chaetoceros affinis, Nitzschia epithemoides and Hymenomonas spp.) was characterized using liquid chromatography–organic carbon detection (LC-OCD) and fluorescence spectroscopy. Chemical structure of polysaccharides isolated from the AOM solutions at stationary phase was analyzed using proton nuclear magnetic resonance (H-NMR). The results showed that production and composition of dissolved AOM varied depending on algal species and their growth stage. AOM was mainly composed of biopolymers (BP; i.e., polysaccharides and proteins [PN]), but some refractory substances were also present.H-NMR spectra confirmed the predominance of carbohydrates in all samples. Furthermore, similar fingerprints were observed for polysaccharides of two diatom species, which differed considerably from that of coccolithophores. Based on the findings of this study,H-NMR could be used as a method for analyzing chemical profiles of algal polysaccharides to enhance the understanding of their impact on membrane fouling.

CORRELATION OF THE PARTITIONING OF DISSOLVED ORGANIC MATTER FRACTIONS WITH THE DESORPTION OF CD, CU, NI, PB AND ZN FROM 18 DUTCH SOILS

Science.gov (United States)

Eighteen Dutch soils were extracted in aqueous solutions at varying pH. Extracts were analyzed for Cd, Cu, Ni, Pb and Zn by ICP-AES. Extract dissolved organic carbon (DOC) was also concentrated onto a macroreticular resin and fractionation into three operationally defined fract...

Corrosion studies of thermally sensitised AGR fuel element brace in pH7 and pH9.2 borate solutions

International Nuclear Information System (INIS)

Tyfield, S.P.; Smith, C.A.

1987-04-01

Brace and cladding of AGR fuel elements sensitised in reactor are susceptible to intergranular and crevice corrosion, which may initiate in the pH7 borate pond storage environment of CEGB/SSEB stations. This report considers the benefit in corrosion control that is provided by raising the pond solution pH to 9.2, whilst maintaining the boron level at 1250 gm -3 . The greater corrosion protection provided by pH9.2 solution compared to the pH7 borate solution is demonstrated by a series of tests with non-active laboratory sensitised brace samples exposed to solutions dosed with chloride or sulphate in order to promote localised corrosion. The corrosion tests undertaken consisted of 5000 hour immersions at 32 0 C and shorter term electrochemically monitored experiments (rest potential, impedance, anodic current) generally conducted at 22 0 C. The pH9.2 solution effectively inhibited the initiation of crevice and intergranular corrosion in the presence of low levels of chloride and sulphate, whereas the pH7 solution did not always do so. However, the pH9.2 solution, dosed with 40 gm -3 chloride, failed to suppress fully crevice corrosion initiated in unborated 40 gm -3 chloride solution at 22 0 C. Fluoride is not deleterious at low levels ∼ 10 gm -3 in the borate solutions. The significant improvement in corrosion control demonstrated for the change from pH7 to pH9.2 borate solution on laboratory sensitised brace samples should ideally be confirmed using complete irradiated AGR fuel elements. (U.K.)

Numerical Study of Traffic Pollutant Dispersion within Different Street Canyon Configurations

Directory of Open Access Journals (Sweden)

Yucong Miao

2014-01-01

Full Text Available The objective of this study is to numerically study flow and traffic exhaust dispersion in urban street canyons with different configurations to find out the urban-planning strategies to ease the air pollution. The Computational Fluid Dynamics (CFD model used in this study—Open Source Field Operation and Manipulation (OpenFOAM software package—was firstly validated against the wind-tunnel experiment data by using three different k-ε turbulence models. And then the patterns of flow and dispersion within three different kinds of street canyon configuration under the perpendicular approaching flow were numerically studied. The result showed that the width and height of building can dramatically affect the pollution level inside the street canyon. As the width or height of building increases, the pollution at the pedestrian level increases. And the asymmetric configuration (step-up or step-down street canyon could provide better ventilation. It is recommended to design a street canyon with nonuniform configurations. And the OpenFOAM software package can be used as a reliable tool to study flows and dispersions around buildings.

Peak distortion in the column liquid chromatographic determination of omeprazole dissolved in borax buffer.

Science.gov (United States)

Arvidsson, T; Collijn, E; Tivert, A M; Rosén, L

1991-11-22

Injection of a sample containing omeprazole dissolved in borax buffer (pH 9.2) into a reversed-phase liquid chromatographic system consisting of a mixture of acetonitrile and phosphate buffer (pH 7.6) as the mobile phase and a C18 surface-modified silica as the solid phase resulted under special conditions in split peaks of omeprazole. The degree of peak split and the retention time of omeprazole varied with the concentration of borax in the sample solution and the ionic strength of the mobile phase buffer as well as with the column used. Borax is eluted from the column in a broad zone starting from the void volume of the column. The retention is probably due to the presence of polyborate ions. The size of the zone varies with the concentration of borax in the sample injected. In the borax zone the pH is increased compared with the pH of the mobile phase, and when omeprazole (a weak acid) is co-eluting in the borax zone its retention is affected. In the front part and in the back part of the borax zone, pH gradients are formed, and these gradients can induce the peak splitting. When the dissolving medium is changed to a phosphate buffer or an ammonium buffer at pH 9 no peak distortion of omeprazole is observed.

Impact of aspect ratio and solar heating on street canyon air temperature

International Nuclear Information System (INIS)

Memon, R.A.; Lal, K.

2011-01-01

The results obtained from RNG (Re-Normalization Group) version of k-and turbulence model are reported in this study. The model is adopted to elucidate the impact of different building aspect ratios (i.e., ratio of building-height-to-street-canyon-width) and solar heating on temperatures in street canyon. The validation of Navier-Stokes and energy an sport equations showed that the model prediction for air-temperature and ambient wind provides reasonable accuracy. The model was applied on AR (Aspect Ratios) one to eight and surface temperature difference (delta and theta/sub s-a/)) of 2 -8. Notably, air-temperatures were higher in high AR street canyons in particular on the leeward side of the street canyon. Further investigation showed that the difference between the air-temperature 'high and low AR street canyons (AR) was positive and high with higher delta and theta/sub s-a/) conversely, the AR become negative and low gradually with lower values of delta and theta(/sub s-a/). These results could be very beneficial for the city and regional planners, civil engineers Id HVAC experts who design street canyons and strive for human thermal comfort with minimum possible energy requirements. (author)

78 FR 7810 - Glen Canyon Dam Adaptive Management Work Group

Science.gov (United States)

2013-02-04

... DEPARTMENT OF THE INTERIOR Bureau of Reclamation Glen Canyon Dam Adaptive Management Work Group... Adaptive Management Work Group (AMWG) makes recommendations to the Secretary of the Interior concerning..., the AMWG, a technical work group (TWG), a Grand Canyon Monitoring and Research Center, and independent...

76 FR 24516 - Glen Canyon Dam Adaptive Management Work Group

Science.gov (United States)

2011-05-02

... DEPARTMENT OF THE INTERIOR Bureau of Reclamation Glen Canyon Dam Adaptive Management Work Group... Adaptive Management Work Group (AMWG) makes recommendations to the Secretary of the Interior concerning..., the AMWG, a technical work group (TWG), a Grand Canyon Monitoring and Research Center, and independent...

Distributions and habitat associations of deep-water corals in Norfolk and Baltimore Canyons, Mid-Atlantic Bight, USA

NARCIS (Netherlands)

Brooke, S.D.; Watts, M.W.; Heil, A.D.; Rhode, M.; Mienis, F.; Duineveld, G.C.A.; Davies, A.J.; Ross, S.W.

2017-01-01

A multi-disciplinary study of two major submarine canyons, Baltimore Canyon and Norfolk Canyon, off the US mid-Atlantic coast focused on the ecology and biology of canyon habitats, particularly those supporting deep-sea corals. Historical data on deep-sea corals from these canyons were sparse with

Comparison of thyroid uptake of 131I capsule and solution in rabbits and graves disease patients

International Nuclear Information System (INIS)

Zhou Xinjian; Li Fang; Lu Jingqiao; Chen Daming; Zhang Ruilin

2002-01-01

Objective: To observe the difference between thyroid uptake rates (TUR) of 131 I capsule and solution in rabbits and Graves disease patients. Methods: Part one: 6 rabbits randomized into two groups received capsule or solution of 131 I 7.4 MBq. Then with SPECT scintigraphy 2,4,6 and 24 h thyroid pure counts in percentage of stomach counts (first frame) were determined. Part two: 1) Measured 131 I capsule standard. 2) 104 patients with Graves disease were administered tracing and therapeutic dose of 131 I capsule (capsule group), 118 of 131 I solution (solution group). Compared the tracing and therapeutic 131 I TUR at 24 h. Results: Part one: There were no significant difference at 2,4,6,24 h TUR between capsule and solution group. For 1 case the maximum TUR was at 6 h in capsule group and 2 cases in solution groups. Part two: 1) For the 131 I capsule administered immediately after being dissolved in 30 mL of water, the activity counts measured were higher by (13.8 +- 2.8)% than it was administered directly, t8.97, P 0.05) and in solution group were (71.3 +- 12.3)% and (65.1 +- 13.0)% (t = 3.82, P 131 I capsule standard should be dissolved before being measured. 3) 131 I capsules can be used as a standard formulation for Graves disease patients. 4) The dose of 131 I should be increased as tracer TUR is larger than 80.0%

33 CFR 165.1171 - Copper Canyon, Lake Havasu, Colorado River-Regulated Navigation Area.

Science.gov (United States)

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Copper Canyon, Lake Havasu... Guard District § 165.1171 Copper Canyon, Lake Havasu, Colorado River—Regulated Navigation Area. (a) Location. The following is a regulated navigation area: (1) In the water area of Copper Canyon, Lake Havasu...

A Numerical Simulation of Traffic-Related Air Pollution Exposures in Urban Street Canyons

Science.gov (United States)

Liu, J.; Fu, X.; Tao, S.

2016-12-01

Urban street canyons are usually associated with intensive vehicle emissions. However, the high buildings successively along both sides of a street block the dispersion of traffic-generated air pollutants, which enhances human exposure and adversely affects human health. In this study, an urban scale traffic pollution dispersion model is developed with the consideration of street distribution, canyon geometry, background meteorology, traffic assignment, traffic emissions and air pollutant dispersion. Vehicle exhausts generated from traffic flows will first disperse inside a street canyon along the micro-scale wind field (generated by computational fluid dynamics (CFD) model) and then leave the street canyon and further disperse over the urban area. On the basis of this model, the effects of canyon geometry on the distribution of NOx and CO from traffic emissions were studied over the center of Beijing, China. We found that an increase of building height along the streets leads to higher pollution levels inside streets and lower pollution levels outside, resulting in higher domain-averaged concentrations over the area. In addition, street canyons with equal (or highly uneven) building heights on two sides of a street tend to lower the urban-scale air pollution concentrations at pedestrian level. Our results indicate that canyon geometry strongly influences human exposure to traffic pollutants in the populated urban area. Carefully planning street layout and canyon geometry in consideration of traffic demand as well as local weather pattern may significantly reduce the chances of unhealthy air being inhaled by urban residents.

Draft environmental assessment: Lavender Canyon site, Utah. Nuclear Waste Policy Act (Section 112)

International Nuclear Information System (INIS)

1984-12-01

In February 1983, the US Department of Energy (DOE) identified the Lavender Canyon site in Utah, as one of nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Lavender Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for Nuclear Waste Repositories. These evaluations are reported in this draft environmental assessment (EA), which is being issued for public review and comment. The DOE findings and determinations that are based on these evaluations are preliminary and subject to public review and comment. A final EA will be prepared after considering the comments received. On the basis of the evaluations contained in this draft EA, the DOE has found that the Lavender Canyon site is not disqualified under the guidelines. The site is contained in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site - the Davis Canyon site. Although the Lavender Canyon site appears to be suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. On the basis of these findings, the DOE is proposing to nominate the Davis Canyon site rather than the Lavender Canyon site as one of the five sites suitable for characterization

Analysis of local scale tree-atmosphere interaction on pollutant concentration in idealized street canyons and application to a real urban junction

Science.gov (United States)

Buccolieri, Riccardo; Salim, Salim Mohamed; Leo, Laura Sandra; Di Sabatino, Silvana; Chan, Andrew; Ielpo, Pierina; de Gennaro, Gianluigi; Gromke, Christof

2011-03-01

This paper first discusses the aerodynamic effects of trees on local scale flow and pollutant concentration in idealized street canyon configurations by means of laboratory experiments and Computational Fluid Dynamics (CFD). These analyses are then used as a reference modelling study for the extension a the neighbourhood scale by investigating a real urban junction of a medium size city in southern Italy. A comparison with previous investigations shows that street-level concentrations crucially depend on the wind direction and street canyon aspect ratio W/H (with W and H the width and the height of buildings, respectively) rather than on tree crown porosity and stand density. It is usually assumed in the literature that larger concentrations are associated with perpendicular approaching wind. In this study, we demonstrate that while for tree-free street canyons under inclined wind directions the larger the aspect ratio the lower the street-level concentration, in presence of trees the expected reduction of street-level concentration with aspect ratio is less pronounced. Observations made for the idealized street canyons are re-interpreted in real case scenario focusing on the neighbourhood scale in proximity of a complex urban junction formed by street canyons of similar aspect ratios as those investigated in the laboratory. The aim is to show the combined influence of building morphology and vegetation on flow and dispersion and to assess the effect of vegetation on local concentration levels. To this aim, CFD simulations for two typical winter/spring days show that trees contribute to alter the local flow and act to trap pollutants. This preliminary study indicates that failing to account for the presence of vegetation, as typically practiced in most operational dispersion models, would result in non-negligible errors in the predictions.

Photochemical Reactivity of Dissolved Organic Matter in Boreal Lakes

Science.gov (United States)

Gu, Y.; Vuorio, K.; Tiirola, M.; Perämäki, S.; Vahatalo, A.

2016-12-01

Boreal lakes are rich in dissolved organic matter (DOM) that terrestrially derived from forest soil and wetland, yet little is known about potential for photochemical transformation of aquatic DOM in boreal lakes. Transformation of chromophoric dissolved organic matter (CDOM) can decrease water color and enhance microbial mineralization, affecting primary production and respiration, which both affect the CO2 balance of the lakes. We used laboratory solar radiation exposure experiments with lake water samples collected from 54 lakes located in Finland and Sweden, representing different catchment composition and watershed location to assess photochemical reactivity of DOM. The pH of water samples ranged from 5.4 to 8.3, and the concentrations of dissolved iron (Fe) were between samples received simulated solar radiation corresponding to a daily dose of sunlight, and photomineralization of dissolved organic carbon (DOC) to dissolved inorganic carbon (DIC) was measured for determination of spectral apparent quantum yields (AQY). During irradiation, photobleaching decreased the absorption coefficients of CDOM at 330 nm between 4.9 and 79 m-1 by 0.5 to 11 m-1. Irradiation generated DIC from 2.8 to 79 μmol C L-1. The AQY at 330 nm ranged between 31 and 273 ×10-6 mol C mol photons-1 h-1, which was correlated positively with concentration of dissolved Fe, and negatively with pH. Further statistical analyze indicated that the interaction between pH and Fe may explain much of the photochemical reactivity of DOM in the examined lakes, and land cover concerns main catchment areas also can have impact on the photoreaction process. This study may suggest how environmental conditions regulate DOM photomineralization in boreal lakes.

Cold-water coral ecosystems in Cassidaigne Canyon: An assessment of their environmental living conditions

OpenAIRE

Fabri, Marie-claire; Bargain, Annaelle; Pairaud, Ivane; Pedel, Laura; Taupier-letage, I.

2017-01-01

The Cassidaigne canyon is one of the two canyons (together with Lacaze-Duthiers) of the French Mediterranean coast in which cold-water corals have settled and formed large colonies, providing a structural habitat for other species. Nevertheless, the communities settled in the Cassidaigne canyon are physically impacted by discharges of bauxite residues. New information on the distribution of the species Madrepora oculata and the associated species diversity in Cassidaigne canyon was provid...

Standardized methods for Grand Canyon fisheries research 2015

Science.gov (United States)

Persons, William R.; Ward, David L.; Avery, Luke A.

2013-01-01

This document presents protocols and guidelines to persons sampling fishes in the Grand Canyon, to help ensure consistency in fish handling, fish tagging, and data collection among different projects and organizations. Most such research and monitoring projects are conducted under the general umbrella of the Glen Canyon Dam Adaptive Management Program and include studies by the U.S. Geological Survey (USGS), U.S. Fish and Wildlife Service (FWS), National Park Service (NPS), the Arizona Game and Fish Department (AGFD), various universities, and private contractors. This document is intended to provide guidance to fieldworkers regarding protocols that may vary from year to year depending on specific projects and objectives. We also provide herein documentation of standard methods used in the Grand Canyon that can be cited in scientific publications, as well as a summary of changes in protocols since the document was first created in 2002.

75 FR 34476 - Glen Canyon Dam Adaptive Management Work Group

Science.gov (United States)

2010-06-17

... DEPARTMENT OF THE INTERIOR Bureau of Reclamation Glen Canyon Dam Adaptive Management Work Group... Management Work Group. The purpose of the Adaptive Management Work Group is to advise and to provide... of the Glen Canyon Dam Adaptive Management Work Group is in the public interest in connection with...

Effects of dissolved oxygen and pH on nitrous oxide production rates in autotrophic partial nitrification granules.

Science.gov (United States)

Rathnayake, Rathnayake M L D; Oshiki, Mamoru; Ishii, Satoshi; Segawa, Takahiro; Satoh, Hisashi; Okabe, Satoshi

2015-12-01

The effects of dissolved oxygen (DO) and pH on nitrous oxide (N2O) production rates and pathways in autotrophic partial nitrification (PN) granules were investigated at the granular level. N2O was primarily produced by betaproteobacterial ammonia-oxidizing bacteria, mainly Nitrosomonas europaea, in the oxic surface layer (production increased with increasing bulk DO concentration owing to activation of the ammonia (i.e., hydroxylamine) oxidation in this layer. The highest N2O emissions were observed at pH 7.5, although the ammonia oxidation rate was unchanged between pH 6.5 and 8.5. Overall, the results of this study suggest that in situ analyses of PN granules are essential to gaining insight into N2O emission mechanisms in a granule. Copyright © 2015 Elsevier Ltd. All rights reserved.

Draft environmental assessment: Davis Canyon site, Utah. Nuclear Waste Policy Act (Section 112)

International Nuclear Information System (INIS)

1984-12-01

In February 1983, the US Department of Energy (DOE) identified the Davis Canyon site in Utah, as one of nine potentially acceptable sites for a mined geologic repository for spent nuclear fuel and high-level radioactive waste. To determine their suitability, the Davis Canyon site and the eight other potentially acceptable sites have been evaluated in accordance with the DOE's General Guidelines for the Recommendation of Sites for Nuclear Waste Repositories. These evaluations are reported in this draft environmental assessment (EA), which is being issued for public review and comment. The DOE findings and determinations that are based on these evaluations are preliminary and subject to public review and comment. A final EA will be prepared after considering the comments received. On the basis of the evaluations reported in this draft EA, the DOE has found that the Davis Canyon site is not disqualified under the guidelines. The site is in the Paradox Basin, which is one of five distinct geohydrologic settings considered for the first repository. This setting contains one other potentially acceptable site - the Lavender Canyon site. Although the Lavender Canyon site appears to be suitable for site characterization, the DOE has concluded that the Davis Canyon site is the preferred site in the Paradox Basin. Furthermore, the DOE finds that the site is suitable for site characterization because the evidence does not support a conclusion that the site will not be able to meet each of the qualifying conditions specified in the guidelines. On the basis of these findings, the DOE is proposing to nominate the Davis Canyon site as one of five sites suitable for characterization. Having compared the Davis Canyon site with the other four sites proposed for nomination, the DOE has determined that the Davis Canyon site is not one of the three preferred sites for recommendation to the President as candidates for characterization

State of bivalent cobalt in solution at microconcentration

International Nuclear Information System (INIS)

Vdovina, E.D.; Davydov, Yu.P.; Radyuk, R.I.

1983-01-01

The first stage of investigations of the state of microamounts of radioactive Co(2) in the 1.0-11.0 pH range by adsorption methods on glass and silica gel, centrifuging, Co (2) migration in the electric field, is performed. 57 Co is used in experiments. It is shown that in the investigated pH range the possibility of formation of pseudocallories is small, Co (2) is in solution in the form of dissolved forms with the positive charge

Assessing the effect of dissolved organic ligands on mineral dissolution rates: An example from calcite dissolution

International Nuclear Information System (INIS)

DeMaio, T.; Grandstaff, D.E.

1997-01-01

Experiments suggest that dissolved organic ligands may primarily modify mineral dissolution rates by three mechanisms: (1) metal-ligand (M-L) complex formation in solution, which increases the degree of undersaturation, (2) formation of surface M-L complexes that attack the surface, and (3) formation of surface complexes which passivate or protect the surface. Mechanisms (1) and (2) increase the dissolution rate and the third decreases it compared with organic-free solutions. The types and importance of these mechanisms may be assessed from plots of dissolution rate versus degree of undersaturation. To illustrate this technique, calcite, a common repository cementing and vein-filling mineral, was dissolved at pH 7.8 and 22 C in Na-Ca-HCO 3 -Cl solutions with low concentrations of three organic ligands. Low citrate concentrations (50 microM) increased the dissolution rate consistent with mechanism (1). Oxalate decreased the rate, consistent with mechanism (3). Low phthalate concentration (<50 microM) decreased calcite dissolution rates; however, higher concentrations increased the dissolution rates, which became faster than in inorganic solutions. Thus, phthalate exhibits both mechanisms (2) and (3) at different concentrations. In such cases linear extrapolations of dissolution rates from high organic ligand concentrations may not be valid

Are amphitheater headed canyons indicative of a particular formative process?

Science.gov (United States)

Ryan, A. J.; Whipple, K. X.; Johnson, J. P.

2012-12-01

Tributary canyons with amphitheater-shaped heads have previously been interpreted as evidence for groundwater seepage erosion, particularly in environments where fluvial processes are assumed to be negligible. However, some have questioned whether this canyon morphology is truly diagnostic of a particular formative process. We seek to determine the relative roles of fluvial and groundwater-related processes and the strength of stratigraphic control on the Colorado Plateau through a combination of fieldwork and GIS analysis. Amphitheater valleys may have overhanging or steep-sided headwalls with a semicircular plan-view pattern. It is reasonable to assume that this form is a result of focused erosion at the base of the headwall (i.e. sapping). Two frequently cited agents may lead to undermining: plunge-pool scour at the base of waterfalls and seepage induced weathering and erosion where the groundwater table intersects the land surface. Both processes are enhanced where weaker, less permeable layers underlie stronger cap rock. We conducted preliminary fieldwork in two locations on the Colorado Plateau, where there are many classic examples of amphitheater headed canyons. The Escalante River landscape is highly variable with a range of canyon and valley-head forms, many of which cut through the thick Navajo Sandstone into the underlying shale and sand of the Kayenta Formation. Northeast of Escalante National Monument, at the base of the Henry Mountains, is Tarantula Mesa. The canyons there are also considerably variable, with nearly all containing at least one abrupt amphitheater knickpoint at the valley head or farther downstream. Our observations are presented here with an analysis of the canyon profiles, surrounding topography, and potential structural controls. We have found that nearly all amphitheaters in both locales show signs of groundwater seepage weathering and plausibly seepage erosion. However, many also contain plunge pools and evidence of substantial

Effects of building roof greening on air quality in street canyons

Science.gov (United States)

Baik, Jong-Jin; Kwak, Kyung-Hwan; Park, Seung-Bu; Ryu, Young-Hee

2012-12-01

Building roof greening is a successful strategy for improving urban thermal environment. It is of theoretical interest and practical importance to study the effects of building roof greening on urban air quality in a systematic and quantitative way. In this study, we examine the effects of building roof greening on air quality in street canyons using a computational fluid dynamics (CFD) model that includes the thermodynamic energy equation and the transport equation of passive, non-reactive pollutants. For simplicity, building roof greening is represented by specified cooling. Results for a simple building configuration with a street canyon aspect ratio of one show that the cool air produced due to building roof greening flows into the street canyon, giving rise to strengthened street canyon flow. The strengthened street canyon flow enhances pollutant dispersion near the road, which decreases pollutant concentration there. Thus, building roof greening improves air quality near the road. The degree of air quality improvement near the road increases as the cooling intensity increases. In the middle region of the street canyon, the air quality can worsen when the cooling intensity is not too strong. Results for a real urban morphology also show that building roof greening improves air quality near roads. The degree of air quality improvement near roads due to building roof greening depends on the ambient wind direction. These findings provide a theoretical foundation for constructing green roofs for the purpose of improving air quality near roads or at a pedestrian level as well as urban thermal environment. Further studies using a CFD model coupled with a photochemistry model and a surface energy balance model are required to evaluate the effects of building roof greening on air quality in street canyons in a more realistic framework.

Near-inertial motions in the DeSoto Canyon during Hurricane Georges

Science.gov (United States)

Jordi, Antoni; Wang, Dong-Ping; Hamilton, Peter

2016-09-01

Hurricane Georges passed directly over an array of 13 moorings deployed in the DeSoto Canyon in the northern Gulf of Mexico on 27-28 September 1998. Current velocity data from the mooring array were analyzed together with a primitive-equation model simulation with realistic hurricane forcing, to characterize the generation and propagation of the hurricane-generated near-inertial waves. The model successfully reproduces the observed mean (sub-inertial) and near-inertial motions. The upper ocean response is strongly impacted by the canyon 'wall': a strong jet is formed along the slope, and the near-inertial motions on the shelf are rapidly suppressed. The model results moreover suggest that strong near-inertial waves in the mixed layer are mostly trapped in an energy flux recirculating gyre around the canyon. This gyre retains the near-inertial energy in the canyon region and enhances the transfer of near-inertial energy below the mixed layer. Additional simulations with idealized topographies show that the presence of a steep slope rather than the canyon is fundamental for the generation of this recirculating gyre. The near-inertial wave energy budget shows that during the study period the wind generated an input of 6.79 × 10-2 Wm-2 of which about 1/3, or 2.43 × 10-2 Wm-2, was transferred below the mixed layer. The horizontal energy flux into and out of the canyon region, in contrast, was relatively weak.

Bedrock Canyons Carved by the Largest Known Floods on Earth and Mars

Science.gov (United States)

Lamb, M. P.; Lapôtre, M. G. A.; Larsen, I. J.; Williams, R. M. E.

2017-12-01

The surface of Earth is a dynamic and permeable interface where the rocky crust is sculpted by ice, wind and water resulting in spectacular mountain ranges, vast depositional basins and environments that support life. These landforms and deposits contain a rich, yet incomplete, record of Earth history that we are just beginning to understand. Some of the most dramatic landforms are the huge bedrock canyons carved by catastrophic floods. On Mars, similar bedrock canyons, known as Outflow Channels, are the most important indicators of large volumes of surface water in the past. Despite their importance and now decades of observations of canyon morphology, we lack a basic understanding of how the canyons formed, which limits our ability to reconstruct flood discharge, duration and water volume. In this presentation I will summarize recent work - using mechanistic numerical models and field observations - that suggests that bedrock canyons carved by megafloods rapidly evolve to a size and shape such that boundary shear stresses just exceed that required to entrain fractured blocks of rock. The threshold shear stress constraint allows for quantitative reconstruction of the largest known floods on Earth and Mars, and implies far smaller discharges than previous methods that assume flood waters fully filled the canyons to high water marks.

Isotope dilution alpha spectrometry for the determination of plutonium concentration in irradiated fuel dissolver solution : IDAS and R-IDAS

International Nuclear Information System (INIS)

Ramaniah, M.V.; Jain, H.C.; Aggarwal, S.K.; Chitambar, S.A.; Kavimandan, V.D.; Almaula, A.I.; Shah, P.M.; Parab, A.R.; Sant, V.L.

1980-01-01

The report presents a new technique, Isotope Dilution Alpha Spectrometry (IDAS) and Reverse Isotope Dilution Alpha Spectrometry (R-IDAS) for determining the concentration of plutonium in the irradiated fuel dissolver solution. The method exploits sup(238)Pu in IDAS and sup(239)Pu in R-IDAS as a spike and provides an alternative method to Isotope Dilution Mass Spectrometry (IDMS) which requires enriched sup(242)Pu as a spike. Depending upon the burn-up of the fuel, sup(238)Pu or sup(239)Pu is used as a spike to change the sup(238)Pu/(sup(239)Pu+sup(240)Pu)α activity ratio in the sample by a factor of 10. This change is determined by α-spectrometry on electrodeposited sources using a solid state silicon surface barrier detector coupled to a multichannel analyser. The validity of a simple method based on the geometric progression (G.P.) decrease for the far tail of the spectrum to correct for the tail contribution of sup(238)Pu peak (5.50 MeV) to the low energy sup(239)Pu + sup(240)Pu peak (5.17 MeV) is established. Results for the plutonium concentration on different irradiated fuel dissolver solutions with burn-uo ranging from J,000 to 100,000 MWD/TU are presented and compared with those obtained by IDMS. The values obtained by IDAS or R-IDAS and IDMS agree within 0.5%. (auth.)

The influence of dissolved H2O content in supercritical carbon dioxide to the inclusion complexes formation of ketoprofen/β-cyclodextrin

Science.gov (United States)

Goenawan, Joshua; Trisanti, P. N.; Sumarno

2015-12-01

This work studies the relation between dissolved H2O content in supercritical carbon dioxide (SC-CO2) with the formation of ketoprofen (KP)/β-cyclodextrin(CD) inclusion complexes. The process involves a physical mixture of these two compounds into contact with the supercritical carbon dioxide which had been previously saturated with H2O over a certain duration. The pressure used for saturation process is 130 bar and saturation temperature was ranged between 30 °C to 50 °C. The inclusion process was achieved by keeping it for 2 hours at 160 bar and 200 bar with inclusion temperature of 50 °C. The results enable us to suggest explanations for the inclusion formation. The inclusion complexes can be formed by contacting the dissolved H2O in SC-CO2 to the physical mixture of KP and CD. An increase in the temperature of saturation process resulted in an increase of dissolved H2O content in the supercritical carbon dioxide. The increasing levels of this water soluble resulted an increase in the inclusion complexes that has been formed. The formation of inclusion complexes includes the water molecules enhancing the emptying of the CD cavities and being replaced by KP, towards a more stable energy state. The drug release used for analyzing the dissolution rate of the KP/CD complexes. The results vary from 79,85% to 99,98% after 45 minutes which is above the rate that has been assigned by Farmakope Indonesia at 70% dissolution rate for KP. The use of SC-CO2 offers a new methods for increasing the rate of dissolution of drugs that are hydrophobic such as KP. CO2 used as a supercritical fluid because of its relatively low cost, easily obtainable supercritical conditions, and lack of toxicity. The material samples were characterized by DSC and Spectrophotometer UV-vis technique.

Submarine canyons off Madras Coast

Digital Repository Service at National Institute of Oceanography (India)

Setty, M.G.A.P.

Submarine canyons off the coast of Madras, Tamil Nadu, India were studied during cruise of @iINS Kistna@@ as part of the IIOE programme They consist of hill-like projections and V-shaped valleys Their other features are also reported...

3D View of Grand Canyon, Arizona

Science.gov (United States)

2000-01-01

The Grand Canyon is one of North America's most spectacular geologic features. Carved primarily by the Colorado River over the past six million years, the canyon sports vertical drops of 5,000 feet and spans a 445-kilometer-long stretch of Arizona desert. The strata along the steep walls of the canyon form a record of geologic time from the Paleozoic Era (250 million years ago) to the Precambrian (1.7 billion years ago).The above view was acquired by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument aboard the Terra spacecraft. Visible and near infrared data were combined to form an image that simulates the natural colors of water and vegetation. Rock colors, however, are not accurate. The image data were combined with elevation data to produce this perspective view, with no vertical exaggeration, looking from above the South Rim up Bright Angel Canyon towards the North Rim. The light lines on the plateau at lower right are the roads around the Canyon View Information Plaza. The Bright Angel Trail, which reaches the Colorado in 11.3 kilometers, can be seen dropping into the canyon over Plateau Point at bottom center. The blue and black areas on the North Rim indicate a forest fire that was smoldering as the data were acquired on May 12, 2000.Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) is one of five Earth-observing instruments launched December 18, 1999, on NASA's Terra satellite. The instrument was built by Japan's Ministry of International Trade and Industry. A joint U.S./Japan science team is responsible for validation and calibration of the instrument and the data products. Dr. Anne Kahle at NASA's Jet Propulsion Laboratory, Pasadena, Calif., is the U.S. Science team leader; Moshe Pniel of JPL is the project manager. ASTER is the only high resolution imaging sensor on Terra. The primary goal of the ASTER mission is to obtain high-resolution image data in 14 channels over the entire land surface, as

Influence of the Nazaré Canyon, central Portuguese margin, on late winter coccolithophore assemblages

NARCIS (Netherlands)

Guerreiro, C.; Sá, C.; de Stigter, H.; Oliveira, A.; Cachão, M.; Cros, L.; Borges, C.; Quaresma, L.; Santos, A.I.; Fortuño, J.-M.; Rodrigez, A.

2014-01-01

This paper presents a first attempt to characterize coccolithophore assemblages occurring in the context of an active submarine canyon. Coccolithophores from the upper-middle sections of the Nazaré Canyon (central Portuguese margin) – one of the largest canyons of the European continental margin –

Removal of uranium from ammonium nitrate solution by nanofiltration

Energy Technology Data Exchange (ETDEWEB)

Wang, Runci; Yuan, Zhongwei; Yan, Taihong; Zheng, Weifang [China Institute of Atomic Energy, Beijing (China). Dept. of Radiochemistry

2017-07-01

Two types of nanofiltration membranes were tested to remove uranium dissolved in ammonium nitrate solution, and the influence of operating parameters as transmembrane pressure, tangential velocity and feed temperature was investigated. Experimental results showed NF270 membrane can reject more than 96% uranium and allow most (90% min) ammonium nitrate solution passed by, and with a permeate flux of 60 L/(m{sup 2}.h). Nanofiltration seems to be a promising technology for the removal of uranium and recovery of ammonium nitrate simultaneously.

Method for improving solution flow in solution mining of a mineral

International Nuclear Information System (INIS)

Moore, T.

1980-01-01

An improved method for the solution mining of a mineral from a subterranean formation containing same in which an injection and production well are drilled and completed within said formation, leach solution and an oxidant are injected through said injection well into said formation to dissolve said mineral, and said dissolved mineral is recovered via said production well, wherein the improvement comprises pretreating said formation with an acid gas to improve the permeabiltiy thereof

THE INFLUENCE OF BUOYANCY ON FLOW AND POLLUTANT DISPERSION IN STREET CANYONS

OpenAIRE

Buccolieri, Riccardo; Pulvirenti, Beatrice; Di Sabatino, Silvana; Britter, Rex

2008-01-01

Abstract: In this paper, the effect of buoyancy on flow and pollutant dispersion within street canyons is studied by means of computational fluid dynamics simulations. We consider a neutral boundary layer approaching a 3D street canyon assuming a wind direction perpendicular to the street canyon. The Boussinesq hypothesis for incompressible fluids is chosen for modelling buoyancy. We distinguish three cases: leeward, ground and windward wall heating. Thermal effects on both the flow ...

Impact of roof height non-uniformity on pollutant transport between a street canyon and intersections

International Nuclear Information System (INIS)

Nosek, Štěpán; Kukačka, Libor; Jurčáková, Klára; Kellnerová, Radka; Jaňour, Zbyněk

2017-01-01

This paper presents an extension of our previous wind-tunnel study (Nosek et al., 2016) in which we highlighted the need for investigation of the removal mechanisms of traffic pollution from all openings of a 3D street canyon. The extension represents the pollution flux (turbulent and advective) measurements at the lateral openings of three different 3D street canyons for the winds perpendicular and oblique to the along-canyon axis. The pollution was simulated by emitting a passive gas (ethane) from a homogeneous ground-level line source positioned along the centreline of the investigated street canyons. The street canyons were formed by courtyard-type buildings of two different regular urban-array models. The first model has a uniform building roof height, while the second model has a non-uniform roof height along each building's wall. The mean flow and concentration fields at the canyons' lateral openings confirm the findings of other studies that the buildings' roof-height variability at the intersections plays an important role in the dispersion of the traffic pollutants within the canyons. For the perpendicular wind, the non-uniform roof-height canyon appreciably removes or entrains the pollutant through its lateral openings, contrary to the uniform canyon, where the pollutant was removed primarily through the top. The analysis of the turbulent mass transport revealed that the coherent flow structures of the lateral momentum transport correlate with the ventilation processes at the lateral openings of all studied canyons. These flow structures coincide at the same areas and hence simultaneously transport the pollutant in opposite directions. - Highlights: • The pollutant transport strongly depends on the roof-height arrangement. • The non-uniform canyons also remove the pollutants through their lateral openings. • The higher the upstream wall, the more pollutant is removed through the top. • The lateral coherent structures correlate

Effect of stable stratification on dispersion within urban street canyons: A large-eddy simulation

Science.gov (United States)

Li, Xian-Xiang; Britter, Rex; Norford, Leslie K.

2016-11-01

This study employs a validated large-eddy simulation (LES) code with high tempo-spatial resolution to investigate the effect of a stably stratified roughness sublayer (RSL) on scalar transport within an urban street canyon. The major effect of stable stratification on the flow and turbulence inside the street canyon is that the flow slows down in both streamwise and vertical directions, a stagnant area near the street level emerges, and the vertical transport of momentum is weakened. Consequently, the transfer of heat between the street canyon and overlying atmosphere also gets weaker. The pollutant emitted from the street level 'pools' within the lower street canyon, and more pollutant accumulates within the street canyon with increasing stability. Under stable stratification, the dominant mechanism for pollutant transport within the street canyon has changed from ejections (flow carries high-concentration pollutant upward) to unorganized motions (flow carries high-concentration pollutant downward), which is responsible for the much lower dispersion efficiency under stable stratifications.

Aquatic macroinvertebrates and water quality in Sandia Canyon

International Nuclear Information System (INIS)

Bennett, K.

1994-05-01

In 1990, field studies of water quality and stream macroinvertebrate communities were initiated in Sandia Canyon at Los Alamos National Laboratory. The studies were designed to establish baseline data and to determine the effects of routine discharges of industrial and sanitary waste. Water quality measurements were taken and aquatic macroinvertebrates sampled at three permanent stations within the canyon. Two of the three sample stations are located where the stream regularly receives industrial and sanitary waste effluents. These stations exhibited a low diversity of macroinvertebrates and slightly degraded water quality. The last sample station, located approximately 0.4 km (0.25 mi) downstream from the nearest wastewater outfall, appears to be in a zone of recovery where water quality parameters more closely resemble those found in natural streams in the Los Alamos area. A large increase in macroinvertebrate diversity was also observed at the third station. These results indicate that effluents discharged into Sandia Canyon have a marked effect on water quality and aquatic macroinvertebrate communities

EFFECTIVENESS OF USING DILUTE OXALIC ACID TO DISSOLVE HIGH LEVEL WASTE IRON BASED SLUDGE SIMULANT

International Nuclear Information System (INIS)

Ketusky, E

2008-01-01

At the Savannah River Site (SRS), near Aiken South Carolina, there is a crucial need to remove residual quantities of highly radioactive iron-based sludge from large select underground storage tanks (e.g., 19,000 liters of sludge per tank), in order to support tank closure. The use of oxalic acid is planned to dissolve the residual sludge, hence, helping in the removal. Based on rigorous testing, primarily using 4 and 8 wt% oxalic acid solutions, it was concluded that the more concentrated the acid, the greater the amount of residual sludge that would be dissolved; hence, a baseline technology on using 8 wt% oxalic acid was developed. In stark contrast to the baseline technology, reports from other industries suggest that the dissolution will most effectively occur at 1 wt% oxalic acid (i.e., maintaining the pH near 2). The driver for using less oxalic acid is that less (i.e., moles) would decrease the severity of the downstream impacts (i.e., required oxalate solids removal efforts). To determine the initial feasibility of using 1 wt% acid to dissolve > 90% of the sludge solids, about 19,000 liters of representative sludge was modeled using about 530,000 liters of 0 to 8 wt% oxalic acid solutions. With the chemical thermodynamic equilibrium based software results showing that 1 wt% oxalic acid could theoretically work, simulant dissolution testing was initiated. For the dissolution testing, existing simulant was obtained, and an approximate 20 liter test rig was built. Multiple batch dissolutions of both wet and air-dried simulant were performed. Overall, the testing showed that dilute oxalic acid dissolved a greater fraction of the stimulant and resulted in a significantly larger acid effectiveness (i.e., grams of sludge dissolved/mole of acid) than the baseline technology. With the potential effectiveness confirmed via simulant testing, additional testing, including radioactive sludge testing, is planned

Assessment of dissolved-solids loading to the Colorado River in the Paradox Basin between the Dolores River and Gypsum Canyon, Utah

Science.gov (United States)

Shope, Christopher L.; Gerner, Steven J.

2014-01-01

Salinity loads throughout the Colorado River Basin have been a concern over recent decades due to adverse impacts on population, natural resources, and regional economics. With substantial financial resources and various reclamation projects, the salt loading to Lake Powell and associated total dissolved-solids concentrations in the Lower Colorado River Basin have been substantially reduced. The Colorado River between its confluence with the Dolores River and Lake Powell traverses a physiographic area where saline sedimentary formations and evaporite deposits are prevalent. However, the dissolved-solids loading in this area is poorly understood due to the paucity of water-quality data. From 2003 to 2011, the U.S. Geological Survey in cooperation with the U.S. Bureau of Reclamation conducted four synoptic sampling events to quantify the salinity loading throughout the study reach and evaluate the occurrence and impacts of both natural and anthropogenic sources. The results from this study indicate that under late-summer base-flow conditions, dissolved-solids loading in the reach is negligible with the exception of the Green River, and that variations in calculated loads between synoptic sampling events are within measurement and analytical uncertainties. The Green River contributed approximately 22 percent of the Colorado River dissolved-solids load, based on samples collected at the lower end of the study reach. These conclusions are supported by water-quality analyses for chloride and bromide, and the results of analyses for the stable isotopes of oxygen and deuterium. Overall, no significant sources of dissolved-solids loading from tributaries or directly by groundwater discharge, with the exception of the Green River, were identified in the study area.

Turbid releases from Glen Canyon Dam, Arizona, following rainfall-runoff events of September 2013

Science.gov (United States)

Wildman, Richard A.; Vernieu, William

2017-01-01

Glen Canyon Dam is a large dam on the Colorado River in Arizona. In September 2013, it released turbid water following intense thunderstorms in the surrounding area. Turbidity was >15 nephelometric turbidity units (NTU) for multiple days and >30 NTU at its peak. These unprecedented turbid releases impaired downstream fishing activity and motivated a rapid-response field excursion. At 5 locations upstream from the dam, temperature, specific conductance, dissolved oxygen, chlorophyll a, and turbidity were measured in vertical profiles. Local streamflow and rainfall records were retrieved, and turbidity and specific conductance data in dam releases were evaluated. Profiling was conducted to determine possible sources of turbidity from 3 tributaries nearest the dam, Navajo, Antelope, and Wahweap creeks, which entered Lake Powell as interflows during this study. We discuss 4 key conditions that must have been met for tributaries to influence turbidity of dam releases: tributary flows must have reached the dam, tributary flows must have been laden with sediment, inflow currents must have been near the depth of dam withdrawals, and the settling velocity of particles must have been slow. We isolate 2 key uncertainties that reservoir managers should resolve in future similar studies: the reach of tributary water into the reservoir thalweg and the distribution of particle size of suspended sediment. These uncertainties leave the source of the turbidity ambiguous, although an important role for Wahweap Creek is possible. The unique combination of limnological factors we describe implies that turbid releases at Glen Canyon Dam will continue to be rare.

Fourmile Canyon Fire Findings

Science.gov (United States)

Russell Graham; Mark Finney; Chuck McHugh; Jack Cohen; Dave Calkin; Rick Stratton; Larry Bradshaw; Ned Nikolov

2012-01-01

The Fourmile Canyon Fire burned in the fall of 2010 in the Rocky Mountain Front Range adjacent to Boulder, Colorado. The fire occurred in steep, rugged terrain, primarily on privately owned mixed ponderosa pine and Douglas-fir forests. The fire started on September 6 when the humidity of the air was very dry (¡Ö

Numerical Simulation of Recent Turbidity Currents in the Monterey Canyon System, Offshore California

Science.gov (United States)

Heimsund, S.; Xu, J.; Nemec, W.

2007-12-01

The method of computational fluid dynamics (CFD) has been used, in the form of a 3D numerical model (Flow- 3D®), to perform a full-scale simulation of turbidity currents measured in December 2002 by three moorings in the Soquel and Monterey canyons. The model was verified by simulation of laboratory flows, and was upscaled to the Monterey Canyon system on the basis of high-resolution bathymetric data and flow measurements. The measured velocity profiles were sufficient to assess the flow thickness, initial velocity and duration in the canyon head zone. A computational grid with a highest feasible resolution was used, and both bathymetry and hydrostatic pressure were accounted for. The volumetric sediment concentration and exact grain- size composition of the flows were unknown, and thus a range of values for the initial concentration and bed roughness were assumed and assessed on a trial-and-error basis. The simulations reveal the behavior of a turbidity current along its descent path, including its local hydraulic characteristics (the 3D field of velocity, sediment concentration, shear stress, strain rate, and dynamic viscosity, as well as the magnitude of velocity and turbulent shear). The results confirm that the velocity structure of turbidity current is highly sensitive to variation in seafloor topography. The December 17th flow in the Soquel Canyon appears to have lost capacity by dilution over a relatively short distance and shown significant velocity fluctuations, which is attributed to the rugged topography of the canyon floor. A major loss of momentum occurred when the flow plunged at high angle into the Monterey Canyon, crashing against its bend's southern wall. The December 20th flow in the Monterey Canyon, in contrast, developed a considerably longer body and strongly accelerated towards the canyon's sharp second bend before crashing against its western wall. The mooring data show a down-canyon decline of velocity and suggest gradual waning, but the

Photogeneration of H2O2 in SPEEK/PVA aqueous polymer solutions.

Science.gov (United States)

Little, Brian K; Lockhart, PaviElle; Slaten, B L; Mills, G

2013-05-23

Photolysis of air-saturated aqueous solutions containing sulphonated poly(ether etherketone) and poly(vinyl alcohol) results in the generation of hydrogen peroxide. Consumption of oxygen and H2O2 formation are initially concurrent processes with a quantum yield of peroxide generation of 0.02 in stirred or unstirred solutions within the range of 7 ≤ pH ≤ 9. The results are rationalized in terms of O2 reduction by photogenerated α-hydroxy radicals of the polymeric ketone in competition with radical-radical processes that consume the macromolecular reducing agents. Generation of H2O2 is controlled by the photochemical transformation that produces the polymer radicals, which is most efficient in neutral and slightly alkaline solutions. Quenching of the excited state of the polyketone by both H3O(+) and OH(-) affect the yields of the reducing macromolecular radicals and of H2O2. Deprotonation of the α-hydroxy polymeric radicals at pH > 9 accelerate their decay and contribute to suppressing the peroxide yields in basic solutions. Maxima in [H2O2] are observed when illuminations are performed with static systems, where O2 reduction is faster than diffusion of oxygen into the solutions. Under such conditions H2O2 can compete with O2 for the reducing radicals resulting in a consumption of the peroxide.

Geologic setting and genesis of the Mule Canyon low-sulfidation epithermal gold-silver deposit, north-central Nevada

Science.gov (United States)

John, D.A.; Hofstra, A.H.; Fleck, R.J.; Brummer, J.E.; Saderholm, E.C.

2003-01-01

/or marcasite veins. Ore minerals consist mostly of electrum and Ag sulfide and selenide minerals, with minor to major amounts of pyrite, marcasite, and arsenopyrite, and local stibnite. Both types of ores have similar geochemical signatures, characterized by high Au, Ag, As, Sb, and Se contents, locally high Hg, Mo, Tl, and W contents, and low Cu, Pb, and Zn contents. Stable isotope data indicate that ore fluids consisted dominantly of meteoric water that evolved by deep circulation through Paleozoic sedimentary rocks at low water/rock ratios (about 1) and high temperatures (>200??C). Calculated isotopic compositions of ore fluids are ??18OH2O = -3 to -7 per mil, ??DH2O = -107 to -124 per mil, ??13CCO2 = 0 to -6 per mil, and ??34SH2S = -3 to +8 per mil. The ore fluids obtained much of their H2S and CO2 and probably scavenged ore metals and trace elements from the Paleozoic sedimentary rocks. Some H2S and CO2 may have been derived from degassing Miocene magmas. Mule Canyon formed at shallow depths, probably about 100 m below the paleosurface. Ore fluids were dilute, nearly neutral in pH, reduced, H2S-rich, and CO2-bearing. Peak temperatures in ore zones reached 230?? to 265??C at nearly lithostatic pressures when some crystalline quartz ?? adularia precipitated, but most ore formed at temperatures <200??C at near hydrostatic pressures and was accompanied by precipitation of opaline and chalcedonic silica ?? adularia ?? calcite and dolomite. Deposition of gold in As-rich overgrowths on pyrite and/or marcasite in disseminated ores occurred owing to decreasing H2S in the ore fluids resulting from sulfidation reactions. Later electrum and Ag selenide precipitation in open spaces occurred owing to boiling, loss of H2S to the vapor phase, and cooling. Mule Canyon is similar to most other low-sulfidation Au-Ag deposits associated with Miocene tholeiitic bimodal basalt-rhyolite magmatism in the Great Basin, such as Sleeper, Midas, and Buckhorn. Major differences at Mule Canyon are

Influence of cetane improvers on the air quality in an urban street canyon

International Nuclear Information System (INIS)

Huang, H.; Akutsu, Y.; Arai, M.; Tamura, M.

2000-01-01

The concentration distributions of NO x , PM, HC and CO in an urban street canyon have been estimated using a two-dimensional air quality numerical model based on the k-e turbulent model and the atmospheric convection diffusion equation when various cetane improvers were used in diesel fuels. A wind vortex can be found within the street canyon, and the pollutants emitted from the bottom of the street canyon tend to follow the course of the wind field, moving circularly. The addition of cetane improvers can improve the air quality in a street canyon, all of the pollutants were found to decrease with increasing cetane number. (Author)

Impact of roof height non-uniformity on pollutant transport between a street canyon and intersections.

Science.gov (United States)

Nosek, Štěpán; Kukačka, Libor; Jurčáková, Klára; Kellnerová, Radka; Jaňour, Zbyněk

2017-08-01

This paper presents an extension of our previous wind-tunnel study (Nosek et al., 2016) in which we highlighted the need for investigation of the removal mechanisms of traffic pollution from all openings of a 3D street canyon. The extension represents the pollution flux (turbulent and advective) measurements at the lateral openings of three different 3D street canyons for the winds perpendicular and oblique to the along-canyon axis. The pollution was simulated by emitting a passive gas (ethane) from a homogeneous ground-level line source positioned along the centreline of the investigated street canyons. The street canyons were formed by courtyard-type buildings of two different regular urban-array models. The first model has a uniform building roof height, while the second model has a non-uniform roof height along each building's wall. The mean flow and concentration fields at the canyons' lateral openings confirm the findings of other studies that the buildings' roof-height variability at the intersections plays an important role in the dispersion of the traffic pollutants within the canyons. For the perpendicular wind, the non-uniform roof-height canyon appreciably removes or entrains the pollutant through its lateral openings, contrary to the uniform canyon, where the pollutant was removed primarily through the top. The analysis of the turbulent mass transport revealed that the coherent flow structures of the lateral momentum transport correlate with the ventilation processes at the lateral openings of all studied canyons. These flow structures coincide at the same areas and hence simultaneously transport the pollutant in opposite directions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Trees in urban street canyons and their impact on the dispersion of automobile exhausts

NARCIS (Netherlands)

Gromke, C.B.; Ruck, B.

2007-01-01

The aim of the present study is to clarify the influence of trees on the dispersion of automobile exhausts in urban street canyons. For this purpose, measurements have been performed with a small scale wind tunnel model of an idealized, isolated street canyon with model trees placed along the canyon

Influence of Calcite and Dissolved Calcium on Uranium(VI) Sorption to a Hanford Subsurface Sediment

International Nuclear Information System (INIS)

Dong, Wenming; Ball, William P.; Liu, Chongxuan; Wang, Zheming; Stone, Alan T.; Bai, Jing; Zachara, John M.

2005-01-01

The influence of calcite and dissolved calcium on U(VI) adsorption was investigated using a calcite-containing sandy silt/clay sediment from the U. S. Department of Energy Hanford site. U(VI) adsorption to sediment, treated sediment, and sediment size fractions was studied in solutions that both had and had not been preequilibrated with calcite, at initial [U(VI)] ) 10-7-10-5 mol/L and final pH ) 6.0- 10.0. Kinetic and reversibility studies (pH 8.4) showed rapid sorption (30 min), with reasonable reversibility in the 3-day reaction time. Sorption from solutions equilibrated with calcite showed maximum U(VI) adsorption at pH 8.4 (0.1. In contrast, calcium-free systems showed the greatest adsorption at pH 6.0-7.2. At pH > 8.4, U(VI) adsorption was identical from calcium-free and calcium-containing solutions. For calcite-presaturated systems, both speciation calculations and laser-induced fluorescence spectroscopic analyses indicated that aqueous U(VI) was increasingly dominated by Ca2UO2(CO3)3 0(aq) at pH<8.4 and that formation of Ca2UO2(CO3)3 0(aq) is what suppresses U(VI) adsorption. Above pH 8.4, aqueous U(VI) speciation was dominated by UO2(CO3)3 4- in all solutions. Finally, results also showed that U(VI) adsorption was additive in regard to size fraction but not in regard to mineral mass: Carbonate minerals may have blocked U(VI) access to surfaces of higher sorption affinity

Small Mammal Sampling in Mortandad and Los Alamos Canyons, 2005

International Nuclear Information System (INIS)

Kathy Bennett; Sherri Sherwood; Rhonda Robinson

2006-01-01

As part of an ongoing ecological field investigation at Los Alamos National Laboratory, a study was conducted that compared measured contaminant concentrations in sediment to population parameters for small mammals in the Mortandad Canyon watershed. Mortandad Canyon and its tributary canyons have received contaminants from multiple solid waste management units and areas of concern since establishment of the Laboratory in the 1940s. The study included three reaches within Effluent and Mortandad canyons (E-1W, M-2W, and M-3) that had a spread in the concentrations of metals and radionuclides and included locations where polychlorinated biphenyls and perchlorate had been detected. A reference location, reach LA-BKG in upper Los Alamos Canyon, was also included in the study for comparison purposes. A small mammal study was initiated to assess whether potential adverse effects were evident in Mortandad Canyon due to the presence of contaminants, designated as contaminants of potential ecological concern, in the terrestrial media. Study sites, including the reference site, were sampled in late July/early August. Species diversity and the mean daily capture rate were the highest for E-1W reach and the lowest for the reference site. Species composition among the three reaches in Mortandad was similar with very little overlap with the reference canyon. Differences in species composition and diversity were most likely due to differences in habitat. Sex ratios, body weights, and reproductive status of small mammals were also evaluated. However, small sample sizes of some species within some sites affected the analysis. Ratios of males to females by species of each site (n = 5) were tested using a Chi-square analysis. No differences were detected. Where there was sufficient sample size, body weights of adult small mammals were compared between sites. No differences in body weights were found. Reproductive status of species appears to be similar across sites. However, sample

Small Mammal Sampling in Mortandad and Los Alamos Canyons, 2005

Energy Technology Data Exchange (ETDEWEB)

Bennett, Kathy; Sherwood, Sherri; Robinson, Rhonda

2006-08-15

As part of an ongoing ecological field investigation at Los Alamos National Laboratory, a study was conducted that compared measured contaminant concentrations in sediment to population parameters for small mammals in the Mortandad Canyon watershed. Mortandad Canyon and its tributary canyons have received contaminants from multiple solid waste management units and areas of concern since establishment of the Laboratory in the 1940s. The study included three reaches within Effluent and Mortandad canyons (E-1W, M-2W, and M-3) that had a spread in the concentrations of metals and radionuclides and included locations where polychlorinated biphenyls and perchlorate had been detected. A reference location, reach LA-BKG in upper Los Alamos Canyon, was also included in the study for comparison purposes. A small mammal study was initiated to assess whether potential adverse effects were evident in Mortandad Canyon due to the presence of contaminants, designated as contaminants of potential ecological concern, in the terrestrial media. Study sites, including the reference site, were sampled in late July/early August. Species diversity and the mean daily capture rate were the highest for E-1W reach and the lowest for the reference site. Species composition among the three reaches in Mortandad was similar with very little overlap with the reference canyon. Differences in species composition and diversity were most likely due to differences in habitat. Sex ratios, body weights, and reproductive status of small mammals were also evaluated. However, small sample sizes of some species within some sites affected the analysis. Ratios of males to females by species of each site (n = 5) were tested using a Chi-square analysis. No differences were detected. Where there was sufficient sample size, body weights of adult small mammals were compared between sites. No differences in body weights were found. Reproductive status of species appears to be similar across sites. However, sample

Internal tides affect benthic community structure in an energetic submarine canyon off SW Taiwan

Science.gov (United States)

Liao, Jian-Xiang; Chen, Guan-Ming; Chiou, Ming-Da; Jan, Sen; Wei, Chih-Lin

2017-07-01

Submarine canyons are major conduits of terrestrial and shelf organic matter, potentially benefiting the seafloor communities in the food-deprived deep sea; however, strong bottom currents driven by internal tides and the potentially frequent turbidity currents triggered by storm surges, river flooding, and earthquakes may negatively impact the benthos. In this study, we investigated the upper Gaoping Submarine Canyon (GPSC), a high-sediment-yield canyon connected to a small mountain river (SMR) off southwest (SW) Taiwan. By contrasting the benthic meiofaunal and macrofaunal communities within and outside the GPSC, we examined how food supplies and disturbance influenced the benthic community assemblages. The benthic communities in the upper GPSC were mainly a nested subset of the adjacent slope assemblages. Several meiofaunal (e.g. ostracods) and macrofaunal taxa (e.g. peracarid crustaceans and mollusks) that typically occurred on the slope were lost from the canyon. The polychaete families switched from diverse feeding guilds on the slope to motile subsurface deposit feeders dominant in the canyon. The diminishing of epibenthic peracarids and proliferation of deep burrowing polychaetes in the GPSC resulted in macrofauna occurring largely within deeper sediment horizons in the canyon than on the slope. The densities and numbers of taxa were depressed with distinct and more variable composition in the canyon than on the adjacent slope. Both the densities and numbers of taxa were negatively influenced by internal tide flushing and positively influenced by food availability; however, the internal tides also negatively influenced the food supplies. While the meiofauna and macrofauna densities were both depressed by the extreme physical conditions in the GPSC, only the macrofaunal densities increased with depth in the canyon, presumably related to increased frequency and intensity of disturbance toward the canyon head. The population densities of meiofauna, on the

Resistometric studies of anodic dissolution and passivation of chromium in weakly acid solutions

International Nuclear Information System (INIS)

Shlepakov, M.N.; Sukhotin, A.M.

1984-01-01

The method of calculating the rate of Cr anodic solution according to the change of electric resistance of chromium anodes under the effect of potentiostatic polarization, is applied. The maximum corresponding to ranges of active-passive transition is absent in weakly acid solutions with pH>3. The range of existence of active-passive transition is expanded to pH approximately 5.2. The existence of a dissolving section in Cr in the chemical mechanism is proved. Cr passivation mechanism with the formation of passivating oxide of a complex composition is suggested

Measuring the density and viscosity of H2S-loaded aqueous methyldiethanolamine solution

International Nuclear Information System (INIS)

Shokouhi, Mohammad; Ahmadi, Reza

2016-01-01

Highlights: • Measurement solubility of H 2 S in 46.78 mass% MDEA aqueous solutions. • Measurement density of H 2 S loaded of MDEA aqueous solution. • Measurement viscosity of H 2 S loaded of MDEA aqueous solution. • Correlation of the density and viscosity of H 2 S loaded of MDEA aqueous solution using modified setchenow equation. - Abstract: The density and viscosity of H 2 S-loaded aqueous 46.78 mass% methyldiethanolamine solution were experimentally measured accompanied with the solubility of H 2 S at temperatures (313.15, 328.15 and 343.15) K, pressures from vapor pressure of fresh solution up to 1.0 MPa and loadings up to 1.00 mol of H 2 S per 1 mol of amine. All experimental trials have been carried out using the new setup developed in our laboratory. It was observed that both density and viscosity of mixtures decrease by increasing temperature and density increase by increasing acid gas solubility (loading) by about 4.7%, whereas viscosity has a complicated behavior with H 2 S solubility. Viscosity decreases by increasing acid gas solubility (loading) at 313.15 K by about 20.6% and at 328.15 K by about 15.0%, but it is comparable at 343.15 K in terms of H 2 S solubility. Finally, the experimental density and viscosity data correlated using Modified Setchenow equation.

Savannah River Site: Canyons and associated facilities utilization study

International Nuclear Information System (INIS)

Ellison, D.; Dickenson, J.

1995-01-01

The Westinghouse Savannah River Company was asked by the U.S. Department of Energy (DOE) to study options for utilization of Savannah River Site (SRS) Canyons and Associated Facilities to support existing and potential future material stabilization and/or disposition missions. This report is WSRC's response to that request. It includes: (1) A compilation of pending DOE material stabilization and/or disposition decisions involving utilization of SRS canyons and associated facilities, including discussion of quantities and expected availability of materials for which SRS handling and/or processing capability is a reasonable alternative under consideration. (2) A description of SRS canyons and associated facilities affected by pending DOE material stabilization and/or disposition decisions, including discussion of material handling and/or processing capabilities and capacities. (3) A comparative evaluation of three proposed scenarios for SRS canyon utilization with respect to startup and operating schedules; annual and life cycle costs; impacts on completion of commitments in the DOE Implementation Plan (IP) for Defense Nuclear Facilities Safety Board (DNFSB) Recommendation 94-1; SRS ability to support alternatives under consideration in pending DOE materials stabilization and/or disposition decisions; and timing for potential transition to deactivation. (4) The sensitivity of the comparative evaluation of the three canyon utilization scenarios to the effect of the selection of other alternatives for individual stabilization missions or individual new missions. Briefings on the scope of this study have been presented to key representatives of several SRS public stakeholder groups. Briefings on the major conclusions from this study have been presented to WSRC Management, DOE-SR, EM-60, EM-1, and the DNFSB

Thermal effects on vehicle emission dispersion in an urban street canyon

Energy Technology Data Exchange (ETDEWEB)

Xiaomin Xie; Zhen Huang; Jiasong Wang; Zheng Xie [Shanghai Jiao Tong Univ., School of Mechanical Engineering, Shanghai (China)

2005-05-15

The impact of the thermal effects on vehicle emission dispersion within street canyons is examined. The results show that heating from building wall surfaces and horizontal surfaces lead to strong buoyancy forces close to surfaces receiving direct solar radiation. This thermally induced flow is combined with mechanically induced flows formed in the canyon where there is no solar heating, and affects the transport of pollutants from the canyon to the layer aloft. The relative influence of each of these effects can be estimates by Gr/Re{sup 2}. When the windward wall is warmer than the air, an upward buoyancy flux opposes the downward advection flux along the wall; if Gr/Re{sup 2} > 2, the flow structure is divided into two counter-rotating cells, and pollutants are accumulated on the windward side of the canyon. When the horizontal surface is heated, and Gr/Re{sup 2} > 4, the flow structure is divided into two counter-rotating cells by upward buoyancy flux. Pollutants are accumulated at the windward side of the canyon. When the leeward side is heated, the buoyancy flux adds to the upward advection flux along the wall strengthening the original vortex and pollutant effects of transport compared to the isothermal case. (Author)

Environmental and human impact on the sedimentary dynamic in the Rhone Delta subaquatic canyons (France-Switzerland)

Science.gov (United States)

Arantegui, A.; Corella, J. P.; Loizeau, J. L.; Anselmetti, F. S.; Girardclos, S.

2012-04-01

Deltas are very sensitive environments and highly vulnerable to variations in water discharge and the amount of suspended sediment load provided by the delta-forming currents. Human activities in the watershed, such as building of dams and irrigation ditches, or river bed deviations, may affect the discharge regime and sediment input, thus affecting delta growth. Underwater currents create deeply incised canyons cutting into the delta lobes. Understanding the sedimentary processes in these subaquatic canyons is crucial to reconstruct the fluvial evolution and human impact on deltaic environments and to carry out a geological risk assessment related to mass movements, which may affect underwater structures and civil infractructure. Recently acquired high-resolution multibeam bathymetry on the Rhone Delta in Lake Geneva (Sastre et al. 2010) revealed the complexity of the underwater morphology formed by active and inactive canyons first described by Forel (1892). In order to unravel the sedimentary processes and sedimentary evolution in these canyons, 27 sediment cores were retrieved in the distal part of each canyon and in the canyon floor/levee complex of the active canyon. Geophysical, sedimentological, geochemical and radiometric dating techniques were applied to analyse these cores. Preliminary data show that only the canyon originating at the current river mouth is active nowadays, while the others remain inactive since engineering works in the watershed occurred, confirming Sastre et al. (2010). However, alternating hemipelagic and turbiditic deposits on the easternmost canyons, evidence underflow processes during the last decades as well. Two canyons, which are located close to the Rhone river mouth, correspond to particularly interesting deeply incised crevasse channels formed when the underwater current broke through the outer bend of a meander in the proximal northern levee. In these canyons, turbidites occur in the sediment record indicating ongoing

Influence of dissolved hydrogen on aluminum-lithium alloy fracture behavior

Science.gov (United States)

Rivet, F. C.; Swanson, R. E.

1989-01-01

The objective of this work is to study the effects of dissolved hydrogen on the mechanical properties of 2090 and 2219 alloys. Prior to mechanical testing, potentiostatic and potentiodynamic tests were performed using NaCl/HCl solutions varying in pH from 1.5 to 7.5 (3.5 pct NaCl in deionized water). After analysis of the potentiodynamic curve for each solution, several potentiostatic experiments were conducted for various times (from 10 minutes to several hours) with a cathodic overpotential of 300 mV. These experiments were performed to select charging conditions. It is shown that the fracture of L-S and T-S orientations proceeds via slipping of layers in the S-T direction. The T-S and L-S orientations fractured with substantially higher propagation energy that the L-T and T-L orientations, due in large part to the extensive delamination propagation of the fracture.

Shelf erosion and submarine river canyons: implications for deep-sea oxygenation and ocean productivity during glaciation

Directory of Open Access Journals (Sweden)

I. Tsandev

2010-06-01

Full Text Available The areal exposure of continental shelves during glacial sea level lowering enhanced the transfer of erodible reactive organic matter to the open ocean. Sea level fall also activated submarine canyons thereby allowing large rivers to deposit their particulate load, via gravity flows, directly in the deep-sea. Here, we analyze the effects of shelf erosion and particulate matter re-routing to the open ocean during interglacial to glacial transitions, using a coupled model of the marine phosphorus, organic carbon and oxygen cycles. The results indicate that shelf erosion and submarine canyon formation may significantly lower deep-sea oxygen levels, by up to 25%, during sea level low stands, mainly due to the supply of new material from the shelves, and to a lesser extent due to particulate organic matter bypassing the coastal zone. Our simulations imply that deep-sea oxygen levels can drop significantly if eroded shelf material is deposited to the seafloor. Thus the glacial ocean's oxygen content could have been significantly lower than during interglacial stages. Primary production, organic carbon burial and dissolved phosphorus inventories are all affected by the erosion and rerouting mechanisms. However, re-routing of the continental and eroded shelf material to the deep-sea has the effect of decoupling deep-sea oxygen demand from primary productivity in the open ocean. P burial is also not affected showing a disconnection between the biogeochemical cycles in the water column and the P burial record.

Preliminary Use of the Seismo-Lineament Analysis Method (SLAM) to Investigate Seismogenic Faulting in the Grand Canyon Area, Northern Arizona

Science.gov (United States)

Cronin, V. S.; Cleveland, D. M.; Prochnow, S. J.

2007-12-01

This is a progress report on our application of the Seismo-Lineament Analysis Method (SLAM) to the eastern Grand Canyon area of northern Arizona. SLAM is a new integrated method for identifying potentially seismogenic faults using earthquake focal-mechanism solutions, geomorphic analysis and field work. There are two nodal planes associated with any double-couple focal-mechanism solution, one of which is thought to coincide with the fault that produced the earthquake; the slip vector is normal to the other (auxiliary) plane. When no uncertainty in the orientation of the fault-plane solution is reported, we use the reported vertical and horizontal uncertainties in the focal location to define a tabular uncertainty volume whose orientation coincides with that of the fault-plane solution. The intersection of the uncertainty volume and the ground surface (represented by the DEM) is termed a seismo-lineament. An image of the DEM surface is illuminated perpendicular to the strike of the seismo- lineament to accentuate geomorphic features within the seismo-lineament that may be related to seismogenic faulting. This evaluation of structural geomorphology is repeated for several different azimuths and elevations of illumination. A map is compiled that includes possible geomorphic indicators of faulting as well as previously mapped faults within each seismo-lineament, constituting a set of hypotheses for the possible location of seismogenic fault segments that must be evaluated through fieldwork. A fault observed in the field that is located within a seismo-lineament, and that has an orientation and slip characteristics that are statistically compatible with the fault-plane solution, is considered potentially seismogenic. We compiled a digital elevation model (DEM) of the Grand Canyon area from published data sets. We used earthquake focal-mechanism solutions produced by David Brumbaugh (2005, BSSA, v. 95, p. 1561-1566) for five M > 3.5 events reported between 1989 and 1995

Megafauna of vulnerable marine ecosystems in French mediterranean submarine canyons: Spatial distribution and anthropogenic impacts

Science.gov (United States)

Fabri, M.-C.; Pedel, L.; Beuck, L.; Galgani, F.; Hebbeln, D.; Freiwald, A.

2014-06-01

Vulnerable Marine Ecosystems (VME) in the deep Mediterranean Sea have been identified by the General Fisheries Commission for the Mediterranean as consisting of communities of Scleractinia (Lophelia pertusa and Madrepora oculata), Pennatulacea (Funiculina quadrangularis) and Alcyonacea (Isidella elongata). This paper deals with video data recorded in the heads of French Mediterranean canyons. Quantitative observations were extracted from 101 video films recorded during the MEDSEACAN cruise in 2009 (Aamp/Comex). Qualitative information was extracted from four other cruises (two Marum/Comex cruises in 2009 and 2011 and two Ifremer cruises in 1995 and 2010) to support the previous observations in the Cassidaigne and Lacaze-Duthiers canyons. All the species, fishing impacts and litter recognized in the video films recorded from 180 to 700 m depth were mapped using GIS. The abundances and distributions of benthic fishing resources (marketable fishes, Aristeidae, Octopodidae), Vulnerable Marine Species, trawling scars and litter of 17 canyons were calculated and compared, as was the open slope between the Stoechades and Toulon canyons. Funiculina quadrangularis was rarely observed, being confined for the most part to the Marti canyon and, I. elongata was abundant in three canyons (Bourcart, Marti, Petit-Rhône). These two cnidarians were encountered in relatively low abundances, and it may be that they have been swept away by repeated trawling. The Lacaze-Duthiers and Cassidaigne canyons comprised the highest densities and largest colony sizes of scleractinian cold-water corals, whose distribution was mapped in detail. These colonies were often seen to be entangled in fishing lines. The alcyonacean Callogorgia verticillata was observed to be highly abundant in the Bourcart canyon and less abundant in several other canyons. This alcyonacean was also severely affected by bottom fishing gears and is proposed as a Vulnerable Marine Species. Our studies on anthropogenic

BLANCO MOUNTAIN AND BLACK CANYON ROADLESS AREAS, CALIFORNIA.

Science.gov (United States)

Diggles, Michael F.; Rains, Richard L.

1984-01-01

The mineral survey of the Blanco Mountain and Black Canyon Roadless Areas, California indicated that areas of probable and substantiated mineral-resource potential exist only in the Black Canyon Roadless Area. Gold with moderate amounts of lead, silver, zinc, and tungsten, occurs in vein deposits and in tactite. The nature of the geological terrain indicates little likelihood for the occurrence of energy resources in the roadless areas. Detailed geologic mapping might better define the extent of gold mineralization. Detailed stream-sediment sampling and analysis of heavy-mineral concentrations could better define tungsten resource potential.

ASP project. Dissolved oxygen issues in ASP project

Directory of Open Access Journals (Sweden)

M.Y. Bondar

2018-03-01

Full Text Available The article presents the latest results of studies about the effect of dissolved oxygen on the efficiency of the ASP flooding project implemented by Salym Petroleum Development N.V.. Pilot project on experimental injection of anionic surfactant solutions, soda and polymer into the reservoir for enhanced oil recovery (ASP project has been implemented since 2016. The stability of one of the components of the ASP polymer is strongly dependent on the presence of iron, stiffness cations and dissolved oxygen in the water. Since the polymer is used for injection at two stages of the project, which are essential and the longest, at the design stage of ASP project a whole complex of polymer protection had been established against negative factors, in particular from the influence of oxygen, which causes not only oxygen corrosion but also irreversible destruction polymer chains. In the paper, studies on the stability of polymer solutions are described, an analysis of viscosity loss with time in the presence of iron and oxygen for polymer solutions is carried out. The choice of chemical deoxygenation method for the control of dissolved oxygen is substantiated. The program of laboratory studies of the ASP project and the analytical instruments used are described. The technological scheme of the ASP process is presented, and recommendations for the implementation of the technology are given.

Geology and geomorphology of the Lower Deschutes River Canyon, Oregon.

Science.gov (United States)

Robin A. Beebee; Jim E. O' Connor; Gordon E. Grant

2002-01-01

This field guide is designed for geologists floating the approximately 80 kilometers (50 miles) of the Deschutes River from the Pelton-Round Butte Dam Complex west of Madras to Maupin, Oregon. The first section of the guide is a geologic timeline tracing the formation of the units that compose the canyon walls and the incision of the present canyon. The second section...

Method of continuously regenerating decontaminating electrolytic solution

International Nuclear Information System (INIS)

Sasaki, Takashi; Kobayashi, Toshio; Wada, Koichi.

1985-01-01

Purpose: To continuously recover radioactive metal ions from the electrolytic solution used for the electrolytic decontamination of radioactive equipment and increased with the radioactive dose, as well as regenerate the electrolytic solution to a high concentration acid. Method: A liquid in an auxiliary tank is recycled to a cathode chamber containing water of an electro depositing regeneration tank to render pH = 2 by way of a pH controller and a pH electrode. The electrolytic solution in an electrolytic decontaminating tank is introduced by way of an injection pump to an auxiliary tank and, interlocking therewith, a regenerating solution is introduced from a regenerating solution extracting pump by way of a extraction pipeway to an electrolytic decontaminating tank. Meanwhile, electric current is supplied to the electrode to deposit radioactive metal ions dissolved in the cathode chamber on the capturing electrode. While on the other hand, anions are transferred by way of a partition wall to an anode chamber to regenerate the electrolytic solution to high concentration acid solution. While on the other hand, water is supplied by way of an electromagnetic valve interlocking with the level meter to maintain the level meter constant. This can decrease the generation of the liquid wastes and also reduce the amount of the radioactive secondary wastes. (Horiuchi, T.)

Environmental analysis of Acid/middle Pueblo Canyon, Los Alamos, New Mexico

International Nuclear Information System (INIS)

Ferenbaugh, R.W.; Buhl, T.E.; Stoker, A.K.; Hansen, W.R.

1982-08-01

The radiological survey of the former radioactive waste treatment plant site (TA-45), Acid Canyon, and Pueblo Canyon found residual radioactivity at the site itself and in the channel and banks of Acid, Pueblo, and lower Los Alamos Canyons, all the way to the Rio Grande. The largest reservoir of radioactive material is in lower Pueblo Canyon, which is on DOE property. The only areas where residual radioactivity exceeds the proposed cleanup criteria are at the former vehicle decontamination facility, located between the former treatment plant site and Acid Canyon, around the former untreated waste outfall and for a short distance below, and in two small areas farther down in Acid Canyon. The three alternatives proposed are (1) to take no action, (2) to fence the areas where the residual radioactivity exceeds the proposed criteria (minimal action), and (3) to clean up the former vehicle decontamination facility and around the former untreated waste outfall. Calculations based on actual measurements indicate that the annual dose at the location having the greatest residual radioactivity would be about 12% of the applicable guideline. Most doses are much smaller than that. No environmental impacts are associated with either the no-action or minimal action alternatives. The impact associated with the cleanup alternative is very small. The preferred alternative is to clean up the areas around the former vehicle decontamination facility and the untreated waste outfall. This course of action is recommended not because of any real danger associated with the residual radioactivity, but rather because the cleanup operation is a minor effort and would conform with the ALARA (as low as reasonably achievable) philosophy

Environmental analysis of Acid/middle Pueblo Canyon, Los Alamos, New Mexico

Energy Technology Data Exchange (ETDEWEB)

Ferenbaugh, R.W.; Buhl, T.E.; Stoker, A.K.; Hansen, W.R.

1982-08-01

The radiological survey of the former radioactive waste treatment plant site (TA-45), Acid Canyon, and Pueblo Canyon found residual radioactivity at the site itself and in the channel and banks of Acid, Pueblo, and lower Los Alamos Canyons, all the way to the Rio Grande. The largest reservoir of radioactive material is in lower Pueblo Canyon, which is on DOE property. The only areas where residual radioactivity exceeds the proposed cleanup criteria are at the former vehicle decontamination facility, located between the former treatment plant site and Acid Canyon, around the former untreated waste outfall and for a short distance below, and in two small areas farther down in Acid Canyon. The three alternatives proposed are (1) to take no action, (2) to fence the areas where the residual radioactivity exceeds the proposed criteria (minimal action), and (3) to clean up the former vehicle decontamination facility and around the former untreated waste outfall. Calculations based on actual measurements indicate that the annual dose at the location having the greatest residual radioactivity would be about 12% of the applicable guideline. Most doses are much smaller than that. No environmental impacts are associated with either the no-action or minimal action alternatives. The impact associated with the cleanup alternative is very small. The preferred alternative is to clean up the areas around the former vehicle decontamination facility and the untreated waste outfall. This course of action is recommended not because of any real danger associated with the residual radioactivity, but rather because the cleanup operation is a minor effort and would conform with the ALARA (as low as reasonably achievable) philosophy.

Temperature and pH driven association in uranyl aqueous solutions

Directory of Open Access Journals (Sweden)

M. Druchok

2012-12-01

Full Text Available An association behavior of uranyl ions in aqueous solutions is explored. For this purpose a set of all-atom molecular dynamics simulations is performed. During the simulation, the fractions of uranyl ions involved in dimer and trimer formations were monitored. To accompany the fraction statistics one also collected distributions characterizing average times of the dimer and trimer associates. Two factors effecting the uranyl association were considered: temperature and pH. As one can expect, an increase of the temperature decreases an uranyl capability of forming the associates, thus lowering bound fractions/times and vice versa. The effect of pH was modeled by adding H+ or OH- ions to a "neutral" solution. The addition of hydroxide ions OH- favors the formation of the associates, thus increasing bound times and fractions. The extra H+ ions in a solution produce an opposite effect, thus lowering the uranyl association capability. We also made a structural analysis for all the observed associates to reveal the mutual orientation of the uranyl ions.

Seasonal Changing Effect on Airflow and Pollutant Dispersion Characteristics in Urban Street Canyons

OpenAIRE

Jingliang Dong; Zijing Tan; Yimin Xiao; Jiyuan Tu

2017-01-01

In this study, the effect of seasonal variation on air flow and pollutant dispersion characteristics was numerically investigated. A three-dimensional urban canopy model with unit aspect ratio (H/D = 1) was used to calculate surface temperature distribution in the street canyon. Four representative time events (1000 LST, 1300 LST, 1600 LST and 2000 LST) during typical clear summer and winter days were selected to examine the air flow diurnal variation. The results revealed the seasonal variat...

Morphology and sediment dynamics of the Capbreton canyon (Bay of Biscay, SW France)

Science.gov (United States)

Gaudin, M.; Umr 5805; Ifremer Team

2003-04-01

The Canyon of Capbreton extending in the Bay of Biscay (SW France) is the deepest canyon in the world. Its structure and morphology was studied using new multibeam bathymetry, acoustic imagery and high-resolution seismic data. The canyon head appears only 250 m away from the coast line and runs westward parallel to the north coast of Spain for 160 km due to structural control, then turns northward, widens and abruptly disappears in the continental rise by 3500 m water depth. Its northern margin is flat and progrades clearly westward. Conversely the southern margin is steep and progrades towards the north (i.e. towards the canyon). Down to 800 m water depth, the canyon deeply incises the continental shelf and the axial channel is meandering (sinuosity of 1.9). The canyon shows both major and minor stream beds, perched tributary valleys, nested terraces and abandoned meanders. The terraces have three morphologies: (1) flat, (2) with a raised side or (3) with a horseshoe structure. These morphologies have been interpreted as overbank deposits or nested levees (1 and 2) or as the result of meander abandon (3). Terraces of types (1) and (2) contain mainly fine deposits resulting from decantation of the top of turbulent surges that flow in the canyon. Westward (800 to 2000 m water depth) the main talweg remains sinuous (1.7). On the southern margin, several straight or slightly sinuous S-N tributary valleys are followed by alignments of pockmarks that also indicate a structural control. On the northern margin, a single large tributary valley with a sinuous central talweg, flowing from the upper Aquitaine continental slope, is interpreted as a giant slump scar due to sediment instability. This valley is bordered to the west by a topographic high with sediment waves on the external flank that might be interpreted as a sedimentary levee. The canyon recorded a recent turbidite activity. An 18 cm-thick turbidite was deposited at 650 m water depth by a turbidity current

A sand budget for Marble Canyon, Arizona: implications for long-term monitoring of sand storage change

Science.gov (United States)

Grams, Paul E.

2013-01-01

Recent U.S. Geological Survey research is providing important insights into how best to monitor changes in the amount of tributary-derived sand stored on the bed of the Colorado River and in eddies in Marble Canyon, Arizona. Before the construction of Glen Canyon Dam and other dams upstream, sandbars in Glen, Marble, and Grand Canyons were replenished each year by sediment-rich floods. Sand input into the Colorado River is crucial to protecting endangered native fish, animals, and plants and cultural and recreational resources along the river in Glen Canyon National Recreation Area and Grand Canyon National Park.

Effects of dissolved organic matter from a eutrophic lake on the freely dissolved concentrations of emerging organic contaminants.

Science.gov (United States)

Xiao, Yi-Hua; Huang, Qing-Hui; Vähätalo, Anssi V; Li, Fei-Peng; Chen, Ling

2014-08-01

The authors studied the effects of dissolved organic matter (DOM) on the bioavailability of bisphenol A (BPA) and chloramphenicol by measuring the freely dissolved concentrations of the contaminants in solutions containing DOM that had been isolated from a mesocosm in a eutrophic lake. The abundance and aromaticity of the chromophoric DOM increased over the 25-d mesocosm experiment. The BPA freely dissolved concentration was 72.3% lower and the chloramphenicol freely dissolved concentration was 56.2% lower using DOM collected on day 25 than using DOM collected on day 1 of the mesocosm experiment. The freely dissolved concentrations negatively correlated with the ultraviolent absorption coefficient at 254 nm and positively correlated with the spectral slope of chromophoric DOM, suggesting that the bioavailability of these emerging organic contaminants depends on the characteristics of the DOM present. The DOM-water partition coefficients (log KOC ) for the emerging organic contaminants positively correlated with the aromaticity of the DOM, measured as humic acid-like fluorescent components C1 (excitation/emission=250[313]/412 nm) and C2 (excitation/emission=268[379]/456 nm). The authors conclude that the bioavailability of emerging organic contaminants in eutrophic lakes can be affected by changes in the DOM. © 2014 SETAC.

Safety Evaluation for Packaging (onsite) T Plant Canyon Items

International Nuclear Information System (INIS)

OBRIEN, J.H.

2000-01-01

This safety evaluation for packaging (SEP) evaluates and documents the ability to safely ship mostly unique inventories of miscellaneous T Plant canyon waste items (T-P Items) encountered during the canyon deck clean off campaign. In addition, this SEP addresses contaminated items and material that may be shipped in a strong tight package (STP). The shipments meet the criteria for onsite shipments as specified by Fluor Hanford in HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments

Safety Evaluation for Packaging (onsite) T Plant Canyon Items

Energy Technology Data Exchange (ETDEWEB)

OBRIEN, J.H.

2000-07-14

This safety evaluation for packaging (SEP) evaluates and documents the ability to safely ship mostly unique inventories of miscellaneous T Plant canyon waste items (T-P Items) encountered during the canyon deck clean off campaign. In addition, this SEP addresses contaminated items and material that may be shipped in a strong tight package (STP). The shipments meet the criteria for onsite shipments as specified by Fluor Hanford in HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments.

Solvent wash solution

International Nuclear Information System (INIS)

Neace, J.C.

1986-01-01

This patent describes a process for removing diluent degradation products from a solvent extraction solution comprising an admixture of an organic extractant for uranium and plutonium and a non-polar organic liquid diluent, which has been used to recover uranium and plutonium from spent nuclear fuel. Comprising combining a wash solution consisting of: (a) water; and (b) a positive amount up to about, an including, 50 volume percent of at least one highly-polar water-miscible organic solvent, based on the total volume of the water and the highly-polar organic solvent, with the solvent extraction solution after uranium and plutonium values have been stripped from the solvent extraction solution, the diluent degradation products dissolving in the highly-polar organic solvent and the extractant and diluent of the extraction solution not dissolving in the highly-polar organic solvent, and separating the highly-polar organic solvent and the extraction solution to obtain a purified extraction solution

Data Quality Objectives Summary Report for the 221-U Canyon Disposition Alternatives

International Nuclear Information System (INIS)

Miller, M.S.; Oaces, L.E.; Baxter, J.; Brown, T.M.; Enoke, D.E.; Carlson, D.; Rugg, J.E.

1997-08-01

The 221-U Canyon Disposition Alternatives Data Quality Objective (DQO) Process identifies the sampling and analytical requirements necessary to support future detailed evaluation of alternatives via the CERCLA process, for final disposition of the 221-U Canyon Facility. Viable alternatives for the disposition of the 221-U Facility have been identified in a CERCLA Phase I Feasibility Study (FS) (DOE-RL 1997) for the Canyon Disposition Initiative (CDI). The scope of this DQO Process is limited to the 221-U Process Canyon Building and equipment contained within the facility. Associated stacks, filters, solvent handling, vaults, and storage facilities external to the 221-U Building are not addressed in this DQO. This DQO focuses on the 221-U Building because it provides the greatest potential source of contaminant volumes and concentrations and the physical structure poses the greatest challenge for disposition decisions

On the pollutant removal, dispersion, and entrainment over two-dimensional idealized street canyons

Science.gov (United States)

Liu, Chun-Ho; Wong, Colman C. C.

2014-01-01

Pollutant dispersion over urban areas is not that well understood, in particular at the street canyon scale. This study is therefore conceived to examine how urban morphology modifies the pollutant removal, dispersion, and entrainment over urban areas. An idealized computational domain consisting of 12 two-dimensional (2D) identical street canyons of unity aspect ratio is employed. The large-eddy simulation (LES) is used to calculate the turbulent flows and pollutant transport in the urban boundary layer (UBL). An area source of uniform pollutant concentration is applied on the ground of the first street canyon. A close examination on the roof-level turbulence reveals patches of low-speed air masses in the streamwise flows and narrow high-speed downdrafts in the shear layer. Different from the flows over a smooth surface, the turbulence intensities are peaked near the top of the building roughness. The pollutant is rather uniformly distributed inside a street canyon but disperses quickly in the UBL over the buildings. Partitioning the vertical pollutant flux into its mean and turbulent components demystifies that the pollutant removal is mainly governed by turbulence. Whereas, mean wind carries pollutant into and out of a street canyon simultaneously. In addition to wind speed promotion, turbulent mixing is thus required to dilute the ground-level pollutants, which are then removed from the street canyon to the UBL. Atmospheric flows slow down rapidly after the leeward buildings, leading to updrafts carrying pollutants away from the street canyons (the basic pollutant removal mechanism).

Dissolution of oxalate precipitate and destruction of oxalate ion by hydrogen peroxide in nitric acid solution

International Nuclear Information System (INIS)

Kim, Eung-Ho; Chung, Dong-Yong; Park, Jin-Ho; Yoo, Jae-Hyung

2000-01-01

This study aims at developing an oxalate precipitation process, which is applicable to a partitioning of long-lived radionuclides from the high-level radioactive liquid waste. In order to achieve this, a study for decomposition-reaction of oxalic acid by hydrogen peroxide was first carried out. The decomposition rates of H 2 O 2 and oxalic acid increased with an increase of nitric acid concentration, and especially those decomposition rates steeply increased at more than 2 M HNO 3 . Based on this result, the decomposition kinetics of H 2 O 2 and oxalic acid were suggested in this work. Then, the dissolution of oxalate precipitate and the destruction of oxalate ion in the solution were examined. Oxalate precipitates were prepared by adding oxalic acid into a simulated radioactive waste containing 8 metallic elements. The precipitates obtained thereby were dissolved in various nitric acid concentrations and reacted with H 2 O 2 at 90degC. When the oxalates were completely dissolved, most of the oxalates were decomposed by adding H 2 O 2 , but in a slurry state the decomposition yield of the oxalate decreased with an increase of the slurry density in the solution. Such phenomenon was considered to be due to a catalytic decomposition of H 2 O 2 on a solid surface of oxalate and the decomposition mechanism was explained by a charge transfer from a surface of oxalate solid to H 2 O 2 , producing OH radicals which can destruct H 2 O 2 explosively. Accordingly, the experimental condition for the decomposition of the oxalate precipitates was found to be most favorable at 3 M HNO 3 under the initial concentrations of 0.2 M oxalate and 1 M H 2 O 2 . At 3M HNO 3 , oxalate precipitates could be safely and completely dissolved, and almost decomposed. Additionally, it was observed that the presence of ferric ion in the solution largely affects the decomposition rate of H 2 O 2 . This could be explained by a chain reaction of hydrogen peroxide with ferric ion in the solution

Bell Canyon test summary report

International Nuclear Information System (INIS)

Christensen, C.L.; Peterson, E.W.

1981-04-01

The Bell Canyon Test was an in situ evaluation of the ability of a cement grout plug to seal boreholes. It consisted of a 2-m-long, 20-cm-diameter grout plug in an anhydrite formation at a depth of 1370 m, directly above an aquifer that provided a 12.4 MPa (1800 psi) differential pressure. The aquifer had a production capability of 38,000 l/day (240 bbl/day, 10 4 gal/day). The observed leakage after plug installation was 0.6 l/day, which is equivalent to a 50 microdarcy flow path assuming all flow occurred through the plug cross-sectional area. Laboratory results and analysis of field data indicate that the bulk of the flow occurred through a microstructure at the interface between the plug and the host rock. The Bell Canyon Test demonstrated that a plug could be formulated, emplaced, and tested under actual conditions and provide acceptable performance. When these results are related to the WIPP performance assessment models, they provide additional confidence that borehole plugging can be accomplished satisfactorily. The Bell Canyon results can also be used as basis for future activities in the generic repository sealing program for similar emplacements and performance assessment evaluations. If the observed leakage rates are not acceptable at other sites, the BCT results would indicate that the first step in improving such emplacements should deal with improved bonding of the plug to the rock at these sites. The results obtained from the BCT, when coupled with results from long-term durability assessments, form a plug performance data basis for repository designers at other proposed waste repository sites

Metal extraction from Cetraria islandica (L. Ach. lichen using low pH solutions

Directory of Open Access Journals (Sweden)

ANA A. CUCULOVIC

2008-04-01

Full Text Available Extraction of metals (K, Al, Ca, Mg, Fe, Cu, Ba, Zn, Mn and Sr from dry Cetraria islandica (L. Ach. lichen was performed using solutions similar to acid rain (solution A – H2SO4–HNO3–(NH42SO4 and solution B – H2SO4–HNO3–(NH42SO4–NH4NO3. The pH values of these solutions were 2.00, 2.58, 2.87, 3.28, and 3.75. Five consecutive extractions were performed with each solution. In all solutions, the extracted metal content, except Cu and Ca, was the highest in the first extract. The highest percentage of the metals desorbed in the first extraction was obtained using solutions with low pH values, 2.00, 2.58, and 2.87. The lowest percentage in the first extraction was obtained using solutions with pH 3.28 and 3.75, indicating influence of the H+ ion on the extraction. According to the results obtained, the investigated metals form two groups. The first group includes K, Al, Ca, Mg, and Fe. They were extracted in each of the five extractions at each of the pH values. The second group includes Ba, Zn, Mn, Cu, and Sr, which were not all extracted at each pH value. The first group yielded three types of extraction curves when the logarithms of extracted metal amounts were plotted as a function of the number of successive extractions. These effects indicate that three different positions (centres of metal ion accumulation exist in the lichen (due to sorption, complex formation, or other processes present in the tissues.

75 FR 27550 - Electrical Interconnection of the Juniper Canyon I Wind Project

Science.gov (United States)

2010-05-17

... DEPARTMENT OF ENERGY Bonneville Power Administration Electrical Interconnection of the Juniper Canyon I Wind Project AGENCY: Bonneville Power Administration (BPA), Department of Energy (DOE). ACTION... would be generated from their proposed Juniper Canyon I Wind Energy Project (Wind Project) in Klickitat...

Numerical modeling of the late Cenozoic geomorphic evolution of Grand Canyon, Arizona

Science.gov (United States)

Pelletier, J. D.

2008-12-01

The late Cenozoic geomorphic evolution of Grand Canyon has been influenced by three primary tectonic and drainage adjustment events. First, incision into the Paleozoic strata of the southwestern margin of the Colorado Plateau began at 16 Ma in response to relief production along the Grand Wash Fault. Second, the ancestral Upper Colorado River reversed drainage and became integrated with the Lower Colorado River basin through Grand Canyon between 5.5 and 6 Ma. Third, the Colorado River was influenced by Plio- Quaternary normal faulting along the Hurricane and Toroweap Faults. Despite the relatively firm constraints available on the timing of these events, the geomorphic evolution of Grand Canyon is still not well constrained and many questions remain. For example, was there a deeply-incised gorge in western Grand Canyon before Colorado River integration? How and where was the Colorado River integrated? How have incision rates varied in space and time? In this paper, I describe the results of a numerical modeling study designed to address these questions. The model integrates the stream power model for bedrock channel erosion with cliff retreat and the flexural-isostatic response to erosion. The model honors the structural geology of the Grand Canyon region, including the variable erodibility of rocks in the Colorado Plateau and the occurrence of Plio-Quaternary normal faulting along the Hurricane-Toroweap Fault system. We present the results of two models designed to bracket the possible drainage architectures of the southwestern margin of the Colorado Plateau in Miocene time. In the first model, we assume a 13,000 km2 drainage basin primarily sourced from the Hualapai and Coconino Plateaux. The results of this model indicate that relief production along the Grand Wash fault initiated the formation of a large (700 m) knickpoint that migrated headward at a rate of 15 km/Myr prior to drainage integration at 6 Ma to form a deep gorge in western Grand Canyon. This model

Distribution of moisture, tritium, and plutonium in the alluvium, aquifer, and underlying tuff in Mortandad Canyon

International Nuclear Information System (INIS)

Purtymun, W.D.; Maes, M.N.; Peters, R.

1985-01-01

A study of the distribution of moisture, tritium, and plutonium in the Mortandad Canyon aquifer indicates some infiltration of water into the underlying tuff. This infiltration was accompanied by similar movement of tritium. The concentrations of plutonium on the sediments in the aquifer were low when compared with the high concentrations in solution in an ionic complex that does not readily exchange or is adsorbed by clay minerals in the alluvium. 2 references, 4 figures, 2 tables

Diablo Canyon plant information management system and integrated communication system

International Nuclear Information System (INIS)

Stanley, J.W.; Groff, C.

1990-01-01

The implementation of a comprehensive maintenance system called the plant information management system (PIMS) at the Diablo Canyon plant, together with its associated integrated communication system (ICS), is widely regarded as the most comprehensive undertaking of its kind in the nuclear industry. This paper provides an overview of the program at Diablo Canyon, an evaluation of system benefits, and highlights the future course of PIMS

Diablo Canyon plant information management system and integrated communication system

Energy Technology Data Exchange (ETDEWEB)

Stanley, J.W.; Groff, C.

1990-06-01

The implementation of a comprehensive maintenance system called the plant information management system (PIMS) at the Diablo Canyon plant, together with its associated integrated communication system (ICS), is widely regarded as the most comprehensive undertaking of its kind in the nuclear industry. This paper provides an overview of the program at Diablo Canyon, an evaluation of system benefits, and highlights the future course of PIMS.

Bioavailability of sinking organic matter in the Blanes canyon and the adjacent open slope (NW Mediterranean Sea)

Science.gov (United States)

Lopez-Fernandez, P.; Bianchelli, S.; Pusceddu, A.; Calafat, A.; Sanchez-Vidal, A.; Danovaro, R.

2013-05-01

Submarine canyons are sites of intense energy and material exchange between the shelf and the deep adjacent basins. To test the hypothesis that active submarine canyons represent preferential conduits of available food for the deep-sea benthos, two mooring lines were deployed at 1200 m depth from November 2008 to November 2009 inside the Blanes canyon and on the adjacent open slope (Catalan Margin, NW Mediterranean Sea). We investigated the fluxes, biochemical composition and food quality of sinking organic carbon (OC). OC fluxes in the canyon and the open slope varied among sampling periods, though not consistently in the two sites. In particular, while in the open slope the highest OC fluxes were observed in August 2009, in the canyon the highest OC fluxes occurred in April-May 2009. For almost the entire study period, the OC fluxes in the canyon were significantly higher than those in the open slope, whereas OC contents of sinking particles collected in the open slope were consistently higher than those in the canyon. This result confirms that submarine canyons are effective conveyors of OC to the deep sea. Particles transferred to the deep sea floor through the canyons are predominantly of inorganic origin, significantly higher than that reaching the open slope at a similar water depth. Using multivariate statistical tests, two major clusters of sampling periods were identified: one in the canyon that grouped trap samples collected in December 2008, concurrently with the occurrence of a major storm at the sea surface, and associated with increased fluxes of nutritionally available particles from the upper shelf. Another cluster grouped samples from both the canyon and the open slope collected in March 2009, concurrently with the occurrence of the seasonal phytoplankton bloom at the sea surface, and associated with increased fluxes of total phytopigments. Our results confirm the key ecological role of submarine canyons for the functioning of deep-sea ecosystems

Increases in both acute and chronic temperature potentiate tocotrienol concentrations in wild barley at 'Evolution Canyon'.

Science.gov (United States)

Shen, Yu; Lansky, Ephraim; Traber, Maret; Nevo, Eviatar

2013-09-01

Biosynthesis of tocols (vitamin E isoforms) is linked to response to temperature in plants. 'Evolution Canyon', an ecogeographical microcosm extending over an average of 200 meters (range 100-400) wide area in the Carmel Mountains of northern Israel, has been suggested as a model for studying global warming. Both domestic (Hordeum vulgare) and wild (Hordeum spontaneum) barley compared with wheat, oat, corn, rice, and rye show high tocotrienol/tocopherol ratios. Therefore, we hypothesized that tocol distribution might change in response to global warming. α-, β-, γ-, and δ-tocopherol, and α-, β-, γ-, and δ-tocotrienol concentrations were measured in wild barley (H. spontaneum) seeds harvested from the xeric (African) and mesic (European) slopes of Evolution Canyon over a six-year period from 2005-2011. Additionally, we examined seeds from areas contiguous to and distant from the part of the Canyon severely burned during the Carmel Fire of December 2010. Increased α-tocotrienol (pslope in contrast to the cooler 'European' slope, and 3) to propinquity to the fire. The study illustrates the role of α-tocotrienol in both chronic and acute temperature adaptation in wild barley and suggests future research into thermoregulatory mechanisms in plants. Copyright © 2013 Verlag Helvetica Chimica Acta AG, Zürich.

Research on Dynamic Dissolving Model and Experiment for Rock Salt under Different Flow Conditions

Directory of Open Access Journals (Sweden)

Xinrong Liu

2015-01-01

Full Text Available Utilizing deep rock salt cavern is not only a widely recognized energy reserve method but also a key development direction for implementing the energy strategic reserve plan. And rock salt cavern adopts solution mining techniques to realize building cavity. In view of this, the paper, based on the dissolving properties of rock salt, being simplified and hypothesized the dynamic dissolving process of rock salt, combined conditions between dissolution effect and seepage effect in establishing dynamic dissolving models of rock salt under different flow quantities. Devices were also designed to test the dynamic dissolving process for rock salt samples under different flow quantities and then utilized the finite-difference method to find the numerical solution of the dynamic dissolving model. The artificial intelligence algorithm, Particle Swarm Optimization algorithm (PSO, was finally introduced to conduct inverse analysis of parameters on the established model, whose calculation results coincide with the experimental data.

Photo-induced degradation of some flavins in aqueous solution

International Nuclear Information System (INIS)

Holzer, W.; Shirdel, J.; Zirak, P.; Penzkofer, A.; Hegemann, P.; Deutzmann, R.; Hochmuth, E.

2005-01-01

The blue-light induced photo-degradation of FMN, FAD, riboflavin, lumiflavin, and lumichrome in aqueous solution at pH 8 is studied by measurement of absorption coefficient spectral changes due to continuous excitation at 428 nm. The quantum yields of photo-degradation determined are φ D (riboflavin, pH 8) ∼ 7.8 x 10 -3 , φ D (FMN, pH 5.6) ∼ 7.3 x 10 -3 , φ D (FMN, pH 8) ∼ 4.6 x 10 -3 , φ D (FAD, pH 8) ∼ 3.7 x 10 -4 , φ D (lumichrome, pH 8) ∼ 1.8 x 10 -4 , and φ D (lumiflavin, pH 8) approx. 1.1 x 10 -5 . In a mass-spectroscopic analysis, the photo-products of FMN dissolved in water (solution pH is 5.6) were identified to be lumichrome and the lumiflavin derivatives dihydroxymethyllumiflavin, formyllumiflavin, and lumiflavin-hydroxy-acetaldehyde. An absorption and emission spectroscopic characterisation of the primary photoproducts of FMN at pH 8 is carried out

Photo-induced degradation of some flavins in aqueous solution

Science.gov (United States)

Holzer, W.; Shirdel, J.; Zirak, P.; Penzkofer, A.; Hegemann, P.; Deutzmann, R.; Hochmuth, E.

2005-01-01

The blue-light induced photo-degradation of FMN, FAD, riboflavin, lumiflavin, and lumichrome in aqueous solution at pH 8 is studied by measurement of absorption coefficient spectral changes due to continuous excitation at 428 nm. The quantum yields of photo-degradation determined are ϕD(riboflavin, pH 8) ≈ 7.8 × 10 -3, ϕD(FMN, pH 5.6) ≈ 7.3 × 10 -3, ϕD(FMN, pH 8) ≈ 4.6 × 10 -3, ϕD(FAD, pH 8) ≈ 3.7 × 10 -4, ϕD(lumichrome, pH 8) ≈ 1.8 × 10 -4, and ϕD(lumiflavin, pH 8) ⩽ 1.1 × 10 -5. In a mass-spectroscopic analysis, the photo-products of FMN dissolved in water (solution pH is 5.6) were identified to be lumichrome and the lumiflavin derivatives dihydroxymethyllumiflavin, formyllumiflavin, and lumiflavin-hydroxy-acetaldehyde. An absorption and emission spectroscopic characterisation of the primary photoproducts of FMN at pH 8 is carried out.

Photo-induced degradation of some flavins in aqueous solution

Energy Technology Data Exchange (ETDEWEB)

Holzer, W. [Institut II-Experimentelle und Angewandte Physik, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany); Shirdel, J. [Institut II-Experimentelle und Angewandte Physik, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany); Zirak, P. [Institut II-Experimentelle und Angewandte Physik, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany); Penzkofer, A. [Institut II-Experimentelle und Angewandte Physik, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany)]. E-mail: alfons.penzkofer@physik.uni-regensburg.de; Hegemann, P. [Institut fuer Biochemie I, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany); Deutzmann, R. [Institut fuer Biochemie I, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany); Hochmuth, E. [Institut fuer Biochemie I, Universitaet Regensburg, Universitaetsstrasse 31, D-93053 Regensburg (Germany)

2005-01-10

The blue-light induced photo-degradation of FMN, FAD, riboflavin, lumiflavin, and lumichrome in aqueous solution at pH 8 is studied by measurement of absorption coefficient spectral changes due to continuous excitation at 428 nm. The quantum yields of photo-degradation determined are {phi}{sub D}(riboflavin, pH 8) {approx} 7.8 x 10{sup -3}, {phi}{sub D}(FMN, pH 5.6) {approx} 7.3 x 10{sup -3}, {phi}{sub D}(FMN, pH 8) {approx} 4.6 x 10{sup -3}, {phi}{sub D}(FAD, pH 8) {approx} 3.7 x 10{sup -4}, {phi}{sub D}(lumichrome, pH 8) {approx} 1.8 x 10{sup -4}, and {phi}{sub D}(lumiflavin, pH 8) approx. 1.1 x 10{sup -5}. In a mass-spectroscopic analysis, the photo-products of FMN dissolved in water (solution pH is 5.6) were identified to be lumichrome and the lumiflavin derivatives dihydroxymethyllumiflavin, formyllumiflavin, and lumiflavin-hydroxy-acetaldehyde. An absorption and emission spectroscopic characterisation of the primary photoproducts of FMN at pH 8 is carried out.

Design of Highly Sensitive C2H5OH Sensors Using Self-Assembled ZnO Nanostructures

Directory of Open Access Journals (Sweden)

Jong-Heun Lee

2011-10-01

Full Text Available Various ZnO nanostructures such as porous nanorods and two hierarchical structures consisting of porous nanosheets or crystalline nanorods were prepared by the reaction of mixtures of oleic-acid-dissolved ethanol solutions and aqueous dissolved Zn-precursor solutions in the presence of NaOH. All three ZnO nanostructures showed sensitive and selective detection of C2H5OH. In particular, ultra-high responses (Ra/Rg = ~1,200, Ra: resistance in air, Rg: resistance in gas to 100 ppm C2H5OH was attained using porous nanorods and hierarchical structures assembled from porous nanosheets, which is one of the highest values reported in the literature. The gas response and linearity of gas sensors were discussed in relation to the size, surface area, and porosity of the nanostructures.

Earthquakes drive large-scale submarine canyon development and sediment supply to deep-ocean basins.

Science.gov (United States)

Mountjoy, Joshu J; Howarth, Jamie D; Orpin, Alan R; Barnes, Philip M; Bowden, David A; Rowden, Ashley A; Schimel, Alexandre C G; Holden, Caroline; Horgan, Huw J; Nodder, Scott D; Patton, Jason R; Lamarche, Geoffroy; Gerstenberger, Matthew; Micallef, Aaron; Pallentin, Arne; Kane, Tim

2018-03-01

Although the global flux of sediment and carbon from land to the coastal ocean is well known, the volume of material that reaches the deep ocean-the ultimate sink-and the mechanisms by which it is transferred are poorly documented. Using a globally unique data set of repeat seafloor measurements and samples, we show that the moment magnitude ( M w ) 7.8 November 2016 Kaikōura earthquake (New Zealand) triggered widespread landslides in a submarine canyon, causing a powerful "canyon flushing" event and turbidity current that traveled >680 km along one of the world's longest deep-sea channels. These observations provide the first quantification of seafloor landscape change and large-scale sediment transport associated with an earthquake-triggered full canyon flushing event. The calculated interevent time of ~140 years indicates a canyon incision rate of 40 mm year -1 , substantially higher than that of most terrestrial rivers, while synchronously transferring large volumes of sediment [850 metric megatons (Mt)] and organic carbon (7 Mt) to the deep ocean. These observations demonstrate that earthquake-triggered canyon flushing is a primary driver of submarine canyon development and material transfer from active continental margins to the deep ocean.

Study of line source characteristics for 2-D physical modelling of pollutant dispersion in street canyons

Energy Technology Data Exchange (ETDEWEB)

Meroney, Robert N. [Fluid Mechanics and Wind Engineering Program, Civil Engineering Department, Colorado State University Fort Collins, CO (United States); Pavageau, Michel; Rafailidis, Stilianos; Schatzmann, Michael [Meteorologisches Institut, Universitaet Hamburg, Hamburg (Germany)

1996-08-01

The University of Hamburg initiated a wind tunnel study of car exhaust dispersion from street canyons in an urban environment to investigate how pollution dispersion is affected by street geometry. Particular emphasis at the beginning of this work was put on the design of a line source to represent traffic exhaust. Pollution dispersion was studied in two dimensions (i.e., infinite-length streets were assumed). The case of an isolated street canyon in open country was examined first. The same street canyon geometry was subsequently studied in an urban environment, i.e., with additional canyons of similar geometry upstream and downstream of the test street. The dynamic and dispersion characteristics of the flow in the two cases were quite different. In the canyon amidst open country we observed better canyon ventilation than in the urban roughness case

Review of the Diablo Canyon probabilistic risk assessment

International Nuclear Information System (INIS)

Bozoki, G.E.; Fitzpatrick, R.G.; Bohn, M.P.; Sabek, M.G.; Ravindra, M.K.; Johnson, J.J.

1994-08-01

This report details the review of the Diablo Canyon Probabilistic Risk Assessment (DCPRA). The study was performed under contract from the Probabilistic Risk Analysis Branch, Office of Nuclear Reactor Research, USNRC by Brookhaven National Laboratory. The DCPRA is a full scope Level I effort and although the review touched on all aspects of the PRA, the internal events and seismic events received the vast majority of the review effort. The report includes a number of independent systems analyses sensitivity studies, importance analyses as well as conclusions on the adequacy of the DCPRA for use in the Diablo Canyon Long Term Seismic Program

Suprabenthic assemblages from the Capbreton area (SE Bay of Biscay). Faunal recovery after a canyon turbidity disturbance

Science.gov (United States)

Frutos, Inmaculada; Sorbe, Jean Claude

2017-12-01

In the Capbreton area, suprabenthic assemblages were sampled with a sledge towed over the bottom, at different sites located within the upper part of a 'gouf-type' canyon (8 hauls between 642 m and 797 m, on the axis of the thalweg or on flat perched flank terraces such as site K), on the northern adjacent open slope (2 hauls between 500 and 567 m) and on the northern adjacent shelf margin (2 hauls between 151 m and 158 m). A multivariate analysis carried on the faunal data discriminated different assemblages in this area: a near-canyon shelf assemblage (55 species, mainly amphipods and decapods; 3496 ind./100 m2, 40% mysids; dominant species: Nyctiphanes couchii, Leptomysis gracilis, Weswoodilla rectirostris, Anchialina agilis, Scopelocheirus hopei and Philocheras bispinosus); an open slope assemblage (111 species, mainly amphipods and isopods; 249 ind./100 m2, 36% amphipods; dominant species: Disconectes phalangium, Munnopsurus atlanticus and Boreomysis arctica); a canyon E assemblage (129 species, mainly amphipods, mysids and cumaceans; 1172 ind./100 m2, 58% amphipods; dominant species: Melphidippa sp. B, Chelator insignis); a canyon E' assemblage (107 species, mainly amphipods and mysids; 507 ind./100 m2, 73% amphipods; dominant species: Cleonardopsis carinata, Bonnierella abyssorum, Rhachotropis caeca and Arcturopsis giardi); and a temporary canyon assemblage at site K (34 species, mainly amphipods and mysids; 899 ind./100 m2, 85% amphipods; dominant species: Tmetomyx similis, Caeconyx caeculus, Nebalia sp. A and Cleonardopsis carinata). Site K was sampled only four months after a turbidity event, detected on sediment cores (18 cm thick Bouma sequence) taken during the same cruise and triggered by the violent storm ('ouragan Martin', wind up to 200 km/h) which affected the French Atlantic coast on 27 December 1999. The corresponding suprabenthic assemblage showed evidence of deep structural changes after this catastrophic event, characterized by relative low

Feral Cattle in the White Rock Canyon Reserve at Los Alamos National Laboratory

Energy Technology Data Exchange (ETDEWEB)

Hathcock, Charles D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Hansen, Leslie A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2014-03-27

At the request of the Los Alamos Field Office (the Field Office), Los Alamos National Security (LANS) biologists placed remote-triggered wildlife cameras in and around the mouth of Ancho Canyon in the White Rock Canyon Reserve (the Reserve) to monitor use by feral cattle. The cameras were placed in October 2012 and retrieved in January 2013. Two cameras were placed upstream in Ancho Canyon away from the Rio Grande along the perennial flows from Ancho Springs, two cameras were placed at the north side of the mouth to Ancho Canyon along the Rio Grande, and two cameras were placed at the south side of the mouth to Ancho Canyon along the Rio Grande. The cameras recorded three different individual feral cows using this area as well as a variety of local native wildlife. This report details our results and issues associated with feral cattle in the Reserve. Feral cattle pose significant risks to human safety, impact cultural and biological resources, and affect the environmental integrity of the Reserve. Regional stakeholders have communicated to the Field Office that they support feral cattle removal.

Sediment transport along the Cap de Creus Canyon flank during a mild, wet winter

Directory of Open Access Journals (Sweden)

J. Martín

2013-05-01

Full Text Available Cap de Creus Canyon (CCC is known as a preferential conduit for particulate matter leaving the Gulf of Lion continental shelf towards the slope and the basin, particularly in winter when storms and dense shelf water cascading coalesce to enhance the seaward export of shelf waters. During the CASCADE (CAscading, Storm, Convection, Advection and Downwelling Events cruise in March 2011, deployments of recording instruments within the canyon and vertical profiling of the water column properties were conducted to study with high spatial-temporal resolution the impact of such processes on particulate matter fluxes. In the context of the mild and wet 2010–2011 winter, no remarkable dense shelf water formation was observed. On the other hand, the experimental setup allowed for the study of the impact of E-SE storms on the hydrographical structure and the particulate matter fluxes in the CCC. The most remarkable feature in terms of sediment transport was a period of dominant E-SE winds from 12 to 16 March, including two moderate storms (maximum significant wave heights = 4.1–4.6 m. During this period, a plume of freshened, relatively cold and turbid water flowed at high speeds along the southern flank of the CCC in an approximate depth range of 150–350 m. The density of this water mass was lighter than the ambient water in the canyon, indicating that it did not cascade off-shelf and that it merely downwelled into the canyon forced by the strong cyclonic circulation induced over the shelf during the storms and by the subsequent accumulation of seawater along the coast. Suspended sediment load in this turbid intrusion recorded along the southern canyon flank oscillated between 10 and 50 mg L−1, and maximum currents speeds reached values up to 90 cm s−1. A rough estimation of 105 tons of sediment was transported through the canyon along its southern wall during a 3-day-long period of storm-induced downwelling. Following the veering of the wind

The importance of dissolved free oxygen during formation of sandstone-type uranium deposits

Science.gov (United States)

Granger, Harry Clifford; Warren, C.G.

1979-01-01

One factor which distinguishes t, he genesis of roll-type uranium deposits from the Uravan Mineral Belt and other sandstone-type uranium deposits may be the presence and concentration of dissolved free oxygen in the ore-forming. solutions. Although dissolved oxygen is a necessary prerequisite for the formation of roll-type deposits, it is proposed that a lack of dissolved oxygen is a prerequisite for the Uravan deposits. Solutions that formed both types of deposits probably had a supergene origin and originated as meteoric water in approximate equilibrium with atmospheric oxygen. Roll-type deposits were formed where the Eh dropped abruptly following consumption of the oxygen by iron sulfide minerals and creation of kinetically active sulfur species that could reduce uranium. The solutions that formed the Uravan deposits, on the other hand, probably first equilibrated with sulfide-free ferrous-ferric detrital minerals and fossil organic matter in the host rock. That is, the uraniferous solutions lost their oxygen without lowering their Eh enough to precipitate uranium. Without oxygen, they then. became incapable of oxidizing iron sulfide minerals. Subsequent localization and formation of ore bodies from these oxygen-depleted solutions, therefore, was not necessarily dependent on large reducing capacities.

Adsorption of Dissolved Gases (CH4, CO2, H2, Noble Gases) by Water-Saturated Smectite Clay Minerals

Science.gov (United States)

Bourg, I. C.; Gadikota, G.; Dazas, B.

2016-12-01

Adsorption of dissolved gases by water-saturated clay minerals plays important roles in a range of fields. For example, gas adsorption in on clay minerals may significantly impact the formation of CH4 hydrates in fine-grained sediments, the behavior of CH4 in shale, CO2 leakage across caprocks of geologic CO2 sequestration sites, H2 leakage across engineered clay barriers of high-level radioactive waste repositories, and noble gas geochemistry reconstructions of hydrocarbon migration in the subsurface. Despite its importance, the adsorption of gases on clay minerals remains poorly understood. For example, some studies have suggested that clay surfaces promote the formation of CH4 hydrates, whereas others indicate that clay surfaces inhibit the formation of CH4 hydrates. Here, we present molecular dynamics (MD) simulations of the adsorption of a range of gases (CH4, CO2, H2, noble gases) on clay mineral surfaces. Our results indicate that the affinity of dissolved gases for clay mineral surfaces has a non-monotone dependence on the hydrated radius of the gas molecules. This non-monotone dependence arises from a combination of two effects: the polar nature of certain gas molecules (in particular, CO2) and the templating of interfacial water structure by the clay basal surface, which results in the presence of interfacial water "cages" of optimal size for intermediate-size gas molecules (such as Ne or Ar).

The impact of traffic-flow patterns on air quality in urban street canyons

International Nuclear Information System (INIS)

Thaker, Prashant; Gokhale, Sharad

2016-01-01

We investigated the effect of different urban traffic-flow patterns on pollutant dispersion in different winds in a real asymmetric street canyon. Free-flow traffic causes more turbulence in the canyon facilitating more dispersion and a reduction in pedestrian level concentration. The comparison of with and without a vehicle-induced-turbulence revealed that when winds were perpendicular, the free-flow traffic reduced the concentration by 73% on the windward side with a minor increase of 17% on the leeward side, whereas for parallel winds, it reduced the concentration by 51% and 29%. The congested-flow traffic increased the concentrations on the leeward side by 47% when winds were perpendicular posing a higher risk to health, whereas reduced it by 17–42% for parallel winds. The urban air quality and public health can, therefore, be improved by improving the traffic-flow patterns in street canyons as vehicle-induced turbulence has been shown to contribute significantly to dispersion. - Highlights: • CFD is used to study impact of traffic-flow patterns on urban air quality. • Facilitating free-flow patterns induce more turbulence in street canyons. • Traffic-generated turbulence alters pollutant levels in urban street canyons. - This study investigates the effect of vehicle-induced-turbulence generated during free-flow traffic pattern in reduction of air pollutant concentrations in urban street canyons.

Vegetative communities, Davis and Lavender Canyons, Paradox Basin, Utah: ecosystem studies

International Nuclear Information System (INIS)

1983-04-01

The major vegetative communities of Davis and Lavender canyons located in southeastern Utah are characterized. The report identifies potential secondary impacts and appropriate mitigation options. The Davis Canyon and Lavender Canyon Study Area contains nine major vegetative communities: galleta-shadscale, juniper-blackbrush, juniper-shadscale-ephedra, shadscale-ephedra, grayia-shadscale, juniper, drywash, greasewood, and riparian. The natural recovery times of these communities are exceedingly long. Natural reinvasion of various species would take from 15 to 100 years. No threatened or endangered plant species were identified in the study area. Davis and Lavender canyons have been subject to off-road vehicle activity and extensive grazing. The plant communities may be subject to additional impacts as a result of increased human activity and off-highway activities such as camping, hiking, and hunting could result in changes in cover, composition, and frequency of plant species. Mitigation options for potential impacts include shuttle-busing workers to the site from the highway and fencing site access roads to prevent vehicles from leaving the roads

Fluctuating helical asymmetry and morphology of snails (Gastropoda in divergent microhabitats at 'Evolution Canyons I and II,' Israel.

Directory of Open Access Journals (Sweden)

Shmuel Raz

Full Text Available Developmental instability of shelled gastropods is measured as deviations from a perfect equiangular (logarithmic spiral. We studied six species of gastropods at 'Evolution Canyons I and II' in Carmel and the Galilee Mountains, Israel, respectively. The xeric, south-facing, 'African' slopes and the mesic, north-facing, 'European' slopes have dramatically different microclimates and plant communities. Moreover, 'Evolution Canyon II' receives more rainfall than 'Evolution Canyon I.'We examined fluctuating asymmetry, rate of whorl expansion, shell height, and number of rotations of the body suture in six species of terrestrial snails from the two 'Evolution Canyons.' The xeric 'African' slope should be more stressful to land snails than the 'European' slope, and 'Evolution Canyon I' should be more stressful than 'Evolution Canyon II.' Only Eopolita protensa jebusitica showed marginally significant differences in fluctuating helical asymmetry between the two slopes. Contrary to expectations, asymmetry was marginally greater on the 'European' slope. Shells of Levantina spiriplana caesareana at 'Evolution Canyon I,' were smaller and more asymmetric than those at 'Evolution Canyon II.' Moreover, shell height and number of rotations of the suture were greater on the north-facing slopes of both canyons.Our data is consistent with a trade-off between drought resistance and thermoregulation in snails; Levantina was significantly smaller on the 'African' slope, for increasing surface area and thermoregulation, while Eopolita was larger on the 'African' slope, for reducing water evaporation. In addition, 'Evolution Canyon I' was more stressful than Evolution Canyon II' for Levantina.

pH tolerance of Daphnia pulex (leydig, emend. , richard)

Energy Technology Data Exchange (ETDEWEB)

Davis, P; Ozburn, G W

1969-01-01

The survival time and reproduction of female Daphnia pulex in solutions varying in pH have been observed. Dilute sodium hydroxide or sulfuric acid solutions were added to four different diluent waters: distilled water, aerated tap water, aerated and filtered tap water from an aquarium containing Dace minnows, and Mcintyre River water. D. Pulex (initially up to 72 hours old) survived for the duration of the experiment (32 hours) in river water within a pH range of 6.1 to 10.3; in aquarium water within a pH range of 4.3 to 10.4; only at pH 6.4 and pH 7.6 in distilled water; and in none of the solutions using aerated tap water. The dissolved oxygen content was measured at the beginning and end of every experiment and was found never to fall below 6.2 p.p.M. Those individuals which survived were cultured in the laboratory and parthenogenesis was observed at pH values between 7.0 and 8.7.

Safety analysis -- 200 Area Savannah River Plant, F-Canyon Operations. Supplement 4

Energy Technology Data Exchange (ETDEWEB)

Beary, M.M.; Collier, C.D.; Fairobent, L.A.; Graham, R.F.; Mason, C.L.; McDuffee, W.T.; Owen, T.L.; Walker, D.H.

1986-02-01

The F-Canyon facility is located in the 200 Separations Area and uses the Purex process to recover plutonium from reactor-irradiated uranium. The irradiated uranium is normally in the form of solid or hollow cylinders called slugs. These slugs are encased in aluminum cladding and are sent to the F-Canyon from the Savannah River Plant (SRP) reactor areas or from the Receiving Basin for Offsite Fuels (RBOF). This Safety Analysis Report (SAR) documents an analysis of the F-Canyon operations and is an update to a section of a previous SAR. The previous SAR documented an analysis of the entire 200 Separations Area operations. This SAR documents an analysis of the F-Canyon and is one of a series of documents for the Separations Area as specified in the Savannah River Implementation Plans. A substantial amount of the information supporting the conclusions of this SAR is found in the Systems Analysis. Some F-Canyon equipment has been updated during the time between the Systems Analysis and this SAR and a complete description of this equipment is included in this report. The primary purpose of the analysis was to demonstrate that the F-Canyon can be operated without undue risk to onsite or offsite populations and to the environment. In this report, risk is defined as the expected frequency of an accident, multiplied by the resulting radiological consequence in person-rem. The units of risk for radiological dose are person-rem/year. Maximum individual exposure values have also been calculated and reported.

The relation between the amount of dissolved water and metals dissolved from stainless steel or aluminum plate in safflower oil

International Nuclear Information System (INIS)

Takasago, Masahisa; Takaoka, Kyo

1986-01-01

The amount of water dissolved in safflower oil at the frying temperature (180 deg C) was 518 ∼ 1012 ppm, allowing water to drop continuously (0.035 g/2 min) into the oil for 1 ∼ 3 h. When the oil was heated with metal plates under the same conditions, the amount of dissolved water in the oil increased more than in the absence of the metal plates. In case of stainless steel, the amount was 1.26 to 1.33 times, and with aluminum plates, 1.06 to 1.13 times the amount without plates. When these metal plates were heated with the oil under the above conditions, the water dissolved the metal of the plates into the oil. In case of stainless steel, iron dissolved from 0.17 to 0.77 ppm, nickel, 0.04 ppm and chromium, from 0.02 to 0.03 ppm. Similarly, the amount of aluminum dissolved from the aluminum plate was from 0.10 to 0.45 ppm. (author)

From proton nuclear magnetic resonance spectra to pH. Assessment of {sup 1}H NMR pH indicator compound set for deuterium oxide solutions

Energy Technology Data Exchange (ETDEWEB)

Tynkkynen, Tuulia, E-mail: tuulia.tynkkynen@uku.fi [Laboratory of Chemistry, Department of Biosciences, University of Kuopio, PO Box 1627, 70211 Kuopio (Finland); Tiainen, Mika; Soininen, Pasi; Laatikainen, Reino [Laboratory of Chemistry, Department of Biosciences, University of Kuopio, PO Box 1627, 70211 Kuopio (Finland)

2009-08-19

In this study, a protocol for pH determination from D{sub 2}O samples using {sup 1}H NMR pH indicator compounds was developed and assessed by exploring the pH-dependency of 13 compounds giving pH-dependent {sup 1}H NMR signals. The indicators cover the pH range from pH* 0 to 7.2. Equations to transform the indicator chemical shifts to pH estimates are given here for acetic acid, formic acid, chloroacetic acid, dichloroacetic acid, creatine, creatinine, glycine, histidine, 1,2,4-triazole, and TSP (2,2,3,3-tetradeutero-3-(trimethylsilyl)-propionic acid). To characterize the method in presence of typical solutes, the effects of common metabolites, albumin and ionic strength were also evaluated. For the ionic strengths, the effects were also modelled. The experiments showed that the use of pH sensitive {sup 1}H NMR chemical shifts allows the pH determination of typical metabolite solutions with accuracy of 0.01-0.05 pH units. Also, when the ionic strength is known with accuracy better than 0.1 mol dm{sup -3} and the solute concentrations are low, pH{sub nmr}{sup *} (the NMR estimate of pH) can be assumed to be within 0.05 pH units from potentiometrically determined pH.

Submarine canyons off the Coromandel coast

Digital Repository Service at National Institute of Oceanography (India)

Varadachari, V.V.R.; Nair, R.R.; Murty, P.S.N.

During the 26th Cruise of I.N.S. `KISTNA', a bathymetric survey was carried out in some detail off the Pondicherry coast. This survey has revealed the existence of three sets of distinctly separate canyons between Cuddalore and Palar River...

Large-Eddy Simulation of Flow and Pollutant Transport in Urban Street Canyons with Ground Heating

Science.gov (United States)

Li, Xian-Xiang; Britter, Rex E.; Koh, Tieh Yong; Norford, Leslie K.; Liu, Chun-Ho; Entekhabi, Dara; Leung, Dennis Y. C.

2010-11-01

Our study employed large-eddy simulation (LES) based on a one-equation subgrid-scale model to investigate the flow field and pollutant dispersion characteristics inside urban street canyons. Unstable thermal stratification was produced by heating the ground of the street canyon. Using the Boussinesq approximation, thermal buoyancy forces were taken into account in both the Navier-Stokes equations and the transport equation for subgrid-scale turbulent kinetic energy (TKE). The LESs were validated against experimental data obtained in wind-tunnel studies before the model was applied to study the detailed turbulence, temperature, and pollutant dispersion characteristics in the street canyon of aspect ratio 1. The effects of different Richardson numbers ( Ri) were investigated. The ground heating significantly enhanced mean flow, turbulence, and pollutant flux inside the street canyon, but weakened the shear at the roof level. The mean flow was observed to be no longer isolated from the free stream and fresh air could be entrained into the street canyon at the roof-level leeward corner. Weighed against higher temperature, the ground heating facilitated pollutant removal from the street canyon.

Analysis of tellurium-silicon alloys. Part 1. Determination of tellurium by the reduction from perchloric acid solution

International Nuclear Information System (INIS)

Teperek, J.

1977-01-01

When 100-150 mg of tellurium is dissolved in the solution containing 20 cm 3 72 wt.% of perchloric acid, the reduction of tellurium to elementary form is possible only after adding 60-100 milimoles of HCl. The reduction is performed by adding 1 cm 3 of saturated sodium pyrosulphite solution (Na 2 S 2 O 5 ) and 10 cm 3 of 10 wt.% hydrazine hydrochloride solution (N 2 H 4 .2HCl) to 80-90 cm 3 of cold solution of Te in HClO 4 -HCl mixture. The reduction is completed after 3-5 min. of boiling. When 150-200 mg sample of Te-Si alloy is dissolved in 20 cm 3 of hot 72% per chloric acid, the separation of components is reached. Tellurium can be determinated in filtrate by proposed procedure with high accuracy and precision. (author)

Hydrogen oxidation on gold electrode in perchloric acid solution

Energy Technology Data Exchange (ETDEWEB)

Sustersic, M.G.; Almeida, N.V.; Von Mengershausen, A.E. [Facultad de Ingenieria y Ciencias Economico Sociales, Universidad Nacional de San Luis, 25 de Mayo N 384, 5730 Villa Mercedes, San Luis (Argentina)

2010-06-15

The aim of this research is to study the interface gold/perchloric acid solution in presence of hydrogen. The reactive is generated by H{sup +} ion reduction and by saturating the electrolyte with the gaseous H{sub 2}. No evidence of H{sub 2} dissociative adsorption is found. In special conditions, a strongly adsorbed layer is formed from the atoms diffusing from inside of the metal. The mass transport occurs in three ways: the diffusion of H atoms inwards, the diffusion of H atoms back to the surface and the dissolved H{sub 2} diffusion from the bulk electrolyte to the surface. When dissolved H{sub 2} reacts, the reaction is kinetically controlled when the H{sub 2} partial pressure is high, and it is diffusionally controlled when the reactive partial pressure is low. Above 0.7 V, (measured vs. RHE), the (100) plane surface reconstruction lifts, and the rate determining step is the H diffusion towards inside of the metal, and the current suddenly falls. The Hydrogen redox reaction on gold shows reversibility with respect to the potential when the reactives are the H diffusing outwards of the metal and the H{sup +} ion present in the electrolyte. However, the absolute current values of oxidation and reduction are different because the reactive sources are different. (author)

77 FR 8895 - Jimbilnan, Pinto Valley, Black Canyon, Eldorado, Ireteba Peaks, Nellis Wash, Spirit Mountain, and...

Science.gov (United States)

2012-02-15

..., Pinto Valley, Black Canyon, Eldorado, Ireteba Peaks, Nellis Wash, Spirit Mountain, and Bridge Canyon..., Eldorado, Ireteba Peaks, Nellis Wash, Spirit Mountain, and Bridge Canyon Wilderness Areas, Lake Mead... wilderness character; providing for reasonable use of Spirit Mountain and adjacent areas in a manner meeting...

Parametric study of the dispersion aspects in a street-canyon area

Energy Technology Data Exchange (ETDEWEB)

Koutsourakis, N.; Neofytou, P.; Venetsanos, A.G.; Bartzis, J.G. [NCSR Demokritos (Greece). Environmental Research Lab.

2004-07-01

Continuously increasing vehicles' fleet is still considered to be the main emission factor in urban environments, despite the enormous progress of modern catalytic technology. Under that perspective, calculation of transportation induced pollutant dispersion is of augmented importance, especially within street canyons, where poor ventilation can result in awkward concentration levels. Computational Fluid Dynamics (CFD) studies have been conducted in the past by Neofytou, P. et al, so as to define appropriate locations for measuring-instrument placement by numerically simulating the flow and pollution dispersion fields in the vicinity of the measuring site taking into account the wind rose of the area and selecting locations of high pollution concentrations so that non-zero indications are assured. Vardoulakis, S. et al, provides a general overview of the street-canyon studies concerning both modelling and experimental investigations and offers plenty of references on air quality within street canyons. Besides air-quality, street canyon CFD studies have also been performed to evaluate accident consequences and hydrogen safety, Venetsanos A. et al. The current study examines a real street canyon in Thessaloniki, Greece. It was performed in order to examine dispersion patterns for different parameters' scenarios and help deciding where to place actual pollutant measurement instruments to better capture traffic pollution data. Various wind directions and speeds are examined and height influence on concentration levels is investigated. Complex area geometry is a key factor of the whole study. (orig.)

On the influence of viaduct and ground heating on pollutant dispersion in 2D street canyons and toward single-sided ventilated buildings

Science.gov (United States)

This paper employs Computational Fluid Dynamic (CFD) simulations to investigate the influence of ground heating intensities and viaduct configurations on gaseous and particle dispersion within two-dimensional idealized street canyons (typical aspect ratio H/W=1) and their transpo...

Carbonaceous aerosol particles from common vegetation in the Grand Canyon

International Nuclear Information System (INIS)

Hallock, K.A.; Mazurek, M.A.; Cass, G.R.

1992-05-01

The problem of visibility reduction in the Grand Canyon due to fine organic aerosol particles in the atmosphere has become an area of increased environmental concern. Aerosol particles can be derived from many emission sources. In this report, we focus on identifying organic aerosols derived from common vegetation in the Grand Canyon. These aerosols are expected to be significant contributors to the total atmospheric organic aerosol content. Aerosol samples from living vegetation were collected by resuspension of surface wax and resin components liberated from the leaves of vegetation common to areas of the Grand Canyon. The samples were analyzed using high-resolution gas chromatography/mass spectrometry (GC/MS). Probable identification of compounds was made by comparison of sample spectra with National Institute of Standards and Technology (NIST) mass spectral references and positive identification of compounds was made when possible by comparison with authentic standards as well as NIST references. Using these references, we have been able to positively identify the presence of n-alkane and n-alkanoic acid homolog series in the surface waxes of the vegetation sampled. Several monoterpenes, sesquiterpenes, and diterpenes were identified also as possible biogenic aerosols which may contribute to the total organic aerosol abundance leading to visibility reduction in the Grand Canyon

The urban canyon and building energy use: Urban density versus daylight and passive solar gains

DEFF Research Database (Denmark)

Strømann-Andersen, Jakob Bjørn; Sattrup, Peter Andreas

2011-01-01

.It was found that the geometry of urban canyons has an impact on total energy consumption in the range of up to +30% for offices and +19% for housing, which shows that the geometry of urban canyons is a key factor in energy use in buildings. It was demonstrated how the reflectivity of urban canyons plays...

Relation between the amount of dissolved water and metals dissolved from stainless steel or aluminum plate in safflower oil

Energy Technology Data Exchange (ETDEWEB)

Takasago, Masahisa; Takaoka, Kyo

1986-12-01

The amount of water dissolved in safflower oil at the frying temperature (180 deg C) was 518 -- 1012 ppM, allowing water to drop continuously (0.035 g/2 min) into the oil for 1 -- 3 h. When the oil was heated with metal plates under the same conditions, the amount of dissolved water in the oil increased more than in the absence of the metal plates. In case of stainless steel, the amount was 1.26 to 1.33 times, and with aluminum plates, 1.06 to 1.13 times the amount without plates. When these metal plates were heated with the oil under the above conditions, the water dissolved the metal of the plates into the oil. In case of stainless steel, iron dissolved from 0.17 to 0.77 ppM, nickel, 0.04 ppM and chromium, from 0.02 to 0.03 ppM. Similarly, the amount of aluminum dissolved from the aluminum plate was from 0.10 to 0.45 ppM.

Effects of Roof-Edge Roughness on Air Temperature and Pollutant Concentration in Urban Canyons

Science.gov (United States)

Aliabadi, Amir A.; Krayenhoff, E. Scott; Nazarian, Negin; Chew, Lup Wai; Armstrong, Peter R.; Afshari, Afshin; Norford, Leslie K.

2017-08-01

The influence of roof-edge roughness elements on airflow, heat transfer, and street-level pollutant transport inside and above a two-dimensional urban canyon is analyzed using an urban energy balance model coupled to a large-eddy simulation model. Simulations are performed for cold (early morning) and hot (mid afternoon) periods during the hottest month of the year (August) for the climate of Abu Dhabi, United Arab Emirates. The analysis suggests that early in the morning, and when the tallest roughness elements are implemented, the temperature above the street level increases on average by 0.5 K, while the pollutant concentration decreases by 2% of the street-level concentration. For the same conditions in mid afternoon, the temperature decreases conservatively by 1 K, while the pollutant concentration increases by 7% of the street-level concentration. As a passive or active architectural solution, the roof roughness element shows promise for improving thermal comfort and air quality in the canyon for specific times, but this should be further verified experimentally. The results also warrant a closer look at the effects of mid-range roughness elements in the urban morphology on atmospheric dynamics so as to improve parametrizations in mesoscale modelling.

Characterization of Tank 16H Annulus Samples Part II: Leaching Results

International Nuclear Information System (INIS)

Hay, M.; Reboul, S.

2012-01-01

contrast to the water leaching results, most constituents continued to dissolve during subsequent cycles of oxalic acid leaching. The somewhat higher dissolution found in the oxalic acid leaching test versus the water leaching test might be offset by the tendency of the oxalic acid solutions to take on a gel-like consistency. The filtered solids left behind after three oxalic acid contacts were sticky and formed large clumps after drying. These two observations could indicate potential processing difficulties with solutions and solids from oxalic acid leaching. The gel formation might be avoided by using larger volumes of the acid. Further testing would be recommended before using oxalic acid to dissolve the Tank 16H annulus waste to ensure no processing difficulties are encountered in the full scale process.

Conformational switching of ethano-bridged Cu,H2-bis-porphyrin induced by aromatic amines.

Science.gov (United States)

Bettini, Simona; Maglie, Emanuela; Pagano, Rosanna; Borovkov, Victor; Inoue, Yoshihisa; Valli, Ludovico; Giancane, Gabriele

2015-01-01

Cu,H2-bis-porphyrin (Cu,H2-Por2), in which copper porphyrin and free-base porphyrin are linked together by an ethano-bridge, was dissolved in chloroform and spread at the air/liquid subphase interface of a Langmuir trough. The bis-porphyrin derivative, floating film was characterized by reflection spectroscopy and the surface pressure of the floating film was studied as a function of the mean area per molecule. When aromatic amines are dissolved in the subphase, an evident interaction between the bis-porphyrin host and the aromatic amine guest is observed. A clear-cut variation of the profile of surface pressure vs area per molecule curve is observed. Reflection spectroscopy highlights that the aromatic amines dissolved in the subphase are able to induce the syn-to-anti conformational switching in the bis-porphyrin derivative. The Langmuir-Schaefer technique has been used to transfer the floating bis-porphyrin film (when using pure water as a subphase) to a surface plasmon resonance (SPR) substrate and the resulting device was able to detect the presence of aniline at concentrations as low as 1 nM in aqueous solution. The high selectivity of the SPR sensing device has been verified by checking the spectral response of the active layer towards other analytes dissolved in the aqueous solutions.

Conformational switching of ethano-bridged Cu,H2-bis-porphyrin induced by aromatic amines

Directory of Open Access Journals (Sweden)

Simona Bettini

2015-11-01

Full Text Available Cu,H2-bis-porphyrin (Cu,H2-Por2, in which copper porphyrin and free-base porphyrin are linked together by an ethano-bridge, was dissolved in chloroform and spread at the air/liquid subphase interface of a Langmuir trough. The bis-porphyrin derivative, floating film was characterized by reflection spectroscopy and the surface pressure of the floating film was studied as a function of the mean area per molecule. When aromatic amines are dissolved in the subphase, an evident interaction between the bis-porphyrin host and the aromatic amine guest is observed. A clear-cut variation of the profile of surface pressure vs area per molecule curve is observed. Reflection spectroscopy highlights that the aromatic amines dissolved in the subphase are able to induce the syn-to-anti conformational switching in the bis-porphyrin derivative. The Langmuir–Schaefer technique has been used to transfer the floating bis-porphyrin film (when using pure water as a subphase to a surface plasmon resonance (SPR substrate and the resulting device was able to detect the presence of aniline at concentrations as low as 1 nM in aqueous solution. The high selectivity of the SPR sensing device has been verified by checking the spectral response of the active layer towards other analytes dissolved in the aqueous solutions.

Viscosity of HI-I2-H2O solution at atmospheric pressure

International Nuclear Information System (INIS)

Chen, Songzhe; Zhang, Ping; Wang, Laijun; Xu, Jingming; Gao, Mengxue

2014-01-01

Iodine-Sulfur thermochemical cycle (IS-cycle) is one of the most promising massive hydrogen production methods. Basic properties data of the HI-I 2 -H 2 O solution involved in the HI decomposition section of IS-cycle are found to be very important. HI, I 2 , and H 2 O make up a highly non-ideal solution system. Viscosity and its variation with the composition/temperature are very essential for the flowsheet work and HI-H 2 O-I 2 solution’s fluid simulation, especially in the distillation and electro-electrodialysis processes. In this paper, viscosity values of HI-H 2 O-I 2 solutions were measured at atmospheric pressure and varying temperatures (from 20 to 125 ºC). As for the composition, the HI/H2O molar ratio of the samples ranged from 1:5.36 to 1:12.00, while the HI/I 2 molar ratio from 1.0 to 1.4.0. Both temperature and composition have dramatic influence on the viscosity. Increasing temperature or H 2 O/HI molar ratio will lead to the reduction of viscosity; while increasing of I 2 /HI molar ratio results in the increase of viscosity. It was also found that I 2 content has a larger and more complex influence on the viscosity of the HI-H 2 O-I 2 solution than H 2 O content does, especially at low temperature (<50 °C). (author)

Captured in Stone: Women in the Rock Art of Canyon de Chelly.

Science.gov (United States)

Travis, Tara

1997-01-01

Describes the pictographs (painted images on stone) and petroglyphs (pecked images on stone) found in the Canyon de Chelly National Monument in Arizona. Canyon de Chelly includes one of the largest concentrations of American Indian rock art in the southwest. Discusses the depiction of women in these images. (MJP)

Liquid scintillation solution

International Nuclear Information System (INIS)

Long, E.C.

1977-01-01

A liquid scintillation solution is described which includes (1) a scintillation solvent (toluene and xylene), (2) a primary scintillation solute (PPO and Butyl PBD), (3) a secondary scintillation solute (POPOP and Dimethyl POPOP), (4) a plurality of substantially different surfactants and (5) a filter dissolving and/or transparentizing agent. 8 claims

Wind tunnel simulation of air pollution dispersion in a street canyon.

Science.gov (United States)

Civis, Svatopluk; Strizík, Michal; Janour, Zbynek; Holpuch, Jan; Zelinger, Zdenek

2002-01-01

Physical simulation was used to study pollution dispersion in a street canyon. The street canyon model was designed to study the effect of measuring flow and concentration fields. A method of C02-laser photoacoustic spectrometry was applied for detection of trace concentration of gas pollution. The advantage of this method is its high sensitivity and broad dynamic range, permitting monitoring of concentrations from trace to saturation values. Application of this method enabled us to propose a simple model based on line permeation pollutant source, developed on the principle of concentration standards, to ensure high precision and homogeneity of the concentration flow. Spatial measurement of the concentration distribution inside the street canyon was performed on the model with reference velocity of 1.5 m/s.

Adsorptive separation of NOsub(x) from dissolver off-gas

International Nuclear Information System (INIS)

Ringel, H.

1984-06-01

After precleaning the dissolver off-gas contains, besides the noble gases Xe and Kr, about 0.5 vol.% each of NOsub(x) and H 2 O. For the removal of these NOsub(x) and H 2 O residues to below 1 ppm, an adsorptive gas cleaning process has been developed and tested on a lab-scale. For the process, an acid resistant molecular sieve was selected and its properties investigated with respect to application; e.g. the dependence of the adsorption capacity on temperature, gas composition and face velocity. By the operation of a lab-scale facility with 400 Nl/h continuous off-gas throughput the suitability of the adsorption process has been demonstrated for off-gas cleaning and recycling of the separated NO 2 and H 2 O to the dissolver. (orig.) [de

Gum-compliant uncertainty propagations for Pu and U concentration measurements using the 1st-prototype XOS/LANL hiRX instrument; an SRNL H-Canyon Test Bed performance evaluation project

Energy Technology Data Exchange (ETDEWEB)

Holland, Michael K. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); O' Rourke, Patrick E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-05-04

An SRNL H-Canyon Test Bed performance evaluation project was completed jointly by SRNL and LANL on a prototype monochromatic energy dispersive x-ray fluorescence instrument, the hiRX. A series of uncertainty propagations were generated based upon plutonium and uranium measurements performed using the alpha-prototype hiRX instrument. Data reduction and uncertainty modeling provided in this report were performed by the SRNL authors. Observations and lessons learned from this evaluation were also used to predict the expected uncertainties that should be achievable at multiple plutonium and uranium concentration levels provided instrument hardware and software upgrades being recommended by LANL and SRNL are performed.

A model for radiolysis of water and aqueous solutions of H2, H2O2 and O2

International Nuclear Information System (INIS)

Ershov, B.G.; Gordeev, A.V.

2008-01-01

Kinetic model for the radiolysis of pure water describing the formation of H 2 , H 2 O 2 and O 2 and the radiation chemical transformations of aqueous solutions containing these compounds over a broad range of concentrations, pH, absorbed doses and dose rates is proposed and substantiated. The model includes a set of chemical reactions with optimized rate constants and the radiation chemical yields of radiolysis products. The model applicability to the description of the whole set of data on the radiation chemical transformations of water and aqueous solutions of H 2 , H 2 O 2 and O 2 is demonstrated

77 FR 59607 - Black Canyon Hydro, LLC; Notice of Environmental Site Review

Science.gov (United States)

2012-09-28

... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Project No. 14110-001] Black Canyon Hydro, LLC; Notice of Environmental Site Review On Wednesday, October 3, 2012, at 3 p.m., Commission staff will be participating in an environmental site review for the proposed Black Canyon Hydroelectric Project. All interested participants should mee...

Electrochemical Studies of Lead Telluride Behavior in Acidic Nitrate Solutions

Directory of Open Access Journals (Sweden)

Rudnik E.

2015-04-01

Full Text Available Electrochemistry of lead telluride stationary electrode was studied in nitric acid solutions of pH 1.5-3.0. E-pH diagram for Pb-Te-H2O system was calculated. Results of cyclic voltammetry of Pb, Te and PbTe were discussed in correlation with thermodynamic predictions. Anodic dissolution of PbTe electrode at potential approx. -100÷50 mV (SCE resulted in tellurium formation, while above 300 mV TeO2 was mainly produced. The latter could dissolve to HTeO+2 under acidic electrolyte, but it was inhibited by increased pH of the bath.

Dissolved inorganic carbon, total alkalinity, pH, dissolved oxygen, and nutrients collected from profile, discrete sampling, and time series observations using CTD, Niskin bottle, and other instruments from R/V Gulf Challenger near a buoy off the coast of New Hampshire, U.S. in the Gulf of Maine from 2011-01-11 to 2015-11-18 (NCEI Accession 0142327)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains discrete measurements of dissolved inorganic carbon, total alkalinity, pH, dissolved oxygen, and nutrients collected at the buoy off...

Effect of Greenhouse Gases Dissolved in Seawater.

Science.gov (United States)

Matsunaga, Shigeki

2015-12-30

A molecular dynamics simulation has been performed on the greenhouse gases carbon dioxide and methane dissolved in a sodium chloride aqueous solution, as a simple model of seawater. A carbon dioxide molecule is also treated as a hydrogen carbonate ion. The structure, coordination number, diffusion coefficient, shear viscosity, specific heat, and thermal conductivity of the solutions have been discussed. The anomalous behaviors of these properties, especially the negative pressure dependence of thermal conductivity, have been observed in the higher-pressure region.

Microstructure and Hardness of Mg - 9Li - 6Al Alloy After Different Variants of Solid Solution Treatment

Science.gov (United States)

Zheng, Haipeng; Fei, Pengfei; Wu, Ruizhi; Hou, Legan; Zhang, Milin

2018-03-01

The microstructure and the hardness of cast magnesium alloy Mg - 9% Li - 6% Al are studied after a treatment for solid solution at 300, 350, and 450°C for 0.5 - 5 h. The phase composition of the alloy is represented by α-Mg, β-Li, thin-plate and faceted particles of an AlLi phase, and particles of a MgLi2Al θ-phase. The θ-phase dissolves in the matrix in the initial stage of the solution treatment, which causes growth in the hardness of the alloy. At a temperature above 350°C the AlLi phase dissolves giving way to short rod-like precipitates of a θ-phase, which remain steady in the process of solution treatment. The hardness of the alloy deceases in this stage for this reason.

Characterizing the correlation between dephosphorization and solution pH in a calcined water treatment plant sludge.

Science.gov (United States)

Zhou, Zhenming; Liu, Qidi; Li, Shuwen; Li, Fei; Zou, Jing; Liao, Xiaobin; Yuan, Baoling; Sun, Wenjie

2018-04-26

This study focused on characterizing the correlation between the dephosphorization process of calcined water treatment plant sludge (C-WTPS) and the solution initial pH in batch experiments. The specific aim was to illustrate the effect of different initial pH on the adsorption and desorption of phosphorous in C-WTPS. In addition, the effects of solution initial pH on the release of ammonia nitrogen and total organic carbon (TOC) from C-WTPS and the change of pH after adsorption were also investigated. The results demonstrated that the initial pH significantly influenced the adsorption of phosphorus on C-WTPS. When initial pH was increased from 3 to 10, the phosphorous absorption capacity reduced by 76.5%. Especially, when the initial pH reached to 11, the phosphorus adsorption capacity became a negative value, indicating that C-WTPS released phosphorus into the solution. The addition of C-WTPS to the solution had little impact on the initial pH of the solution. The absorbed phosphorous on C-WTPS was relatively stable in the pH range of 3 to 10. Nevertheless, when the solution pH was higher than 11, it can be easily released into the solution. Furthermore, by comparison with WTPS, C-WTPS released less ammonia nitrogen and TOC into the solution and adsorbed more phosphorus from the solution in the experimental pH range. Therefore, C-WTPS is more suitable to serve as a cost-effective sorbent for phosphorus removal.

Inorganic speciation of dissolved elements in seawater: the influence of pH on concentration ratios

Directory of Open Access Journals (Sweden)

Byrne Robert H

2002-01-01

Full Text Available Assessments of inorganic elemental speciation in seawater span the past four decades. Experimentation, compilation and critical review of equilibrium data over the past forty years have, in particular, considerably improved our understanding of cation hydrolysis and the complexation of cations by carbonate ions in solution. Through experimental investigations and critical evaluation it is now known that more than forty elements have seawater speciation schemes that are strongly influenced by pH. In the present work, the speciation of the elements in seawater is summarized in a manner that highlights the significance of pH variations. For elements that have pH-dependent species concentration ratios, this work summarizes equilibrium data (S = 35, t = 25°C that can be used to assess regions of dominance and relative species concentrations. Concentration ratios of complex species are expressed in the form log[A]/[B] = pH - C where brackets denote species concentrations in solution, A and B are species important at higher (A and lower (B solution pH, and C is a constant dependent on salinity, temperature and pressure. In the case of equilibria involving complex oxy-anions (MOx(OHy or hydroxy complexes (M(OHn, C is written as pKn = -log Kn or pKn* = -log Kn* respectively, where Kn and Kn* are equilibrium constants. For equilibria involving carbonate complexation, the constant C is written as pQ = -log(K2lKn [HCO3-] where K2l is the HCO3 - dissociation constant, Kn is a cation complexation constant and [HCO3-] is approximated as 1.9 × 10-3 molar. Equilibrium data expressed in this manner clearly show dominant species transitions, ranges of dominance, and relative concentrations at any pH.

Differentiation among Multiple Sources of Anthropogenic Nitrate in a Complex Groundwater System using Dual Isotope Systematics: A case study from Mortandad Canyon, New Mexico

Science.gov (United States)

Larson, T. E.; Perkins, G.; Longmire, P.; Heikoop, J. M.; Fessenden, J. E.; Rearick, M.; Fabyrka-Martin, J.; Chrystal, A. E.; Dale, M.; Simmons, A. M.

2009-12-01

The groundwater system beneath Los Alamos National Laboratory has been affected by multiple sources of anthropogenic nitrate contamination. Average NO3-N concentrations of up to 18.2±1.7 mg/L have been found in wells in the perched intermediate aquifer beneath one of the more affected sites within Mortandad Canyon. Sources of nitrate potentially reaching the alluvial and intermediate aquifers include: (1) sewage effluent, (2) neutralized nitric acid, (3) neutralized 15N-depleted nitric acid (treated waste from an experiment enriching nitric acid in 15N), and (4) natural background nitrate. Each of these sources is unique in δ18O and δ15N space. Using nitrate stable isotope ratios, a mixing model for the three anthropogenic sources of nitrate was established, after applying a linear subtraction of the background component. The spatial and temporal variability in nitrate contaminant sources through Mortandad Canyon is clearly shown in ternary plots. While microbial denitrification has been shown to change groundwater nitrate stable isotope ratios in other settings, the redox potential, relatively high dissolved oxygen content, increasing nitrate concentrations over time, and lack of observed NO2 in these wells suggest minimal changes to the stable isotope ratios have occurred. Temporal trends indicate that the earliest form of anthropogenic nitrate in this watershed was neutralized nitric acid. Alluvial wells preserve a trend of decreasing nitrate concentrations and mixing models show decreasing contributions of 15N-depleted nitric acid. Nearby intermediate wells show increasing nitrate concentrations and mixing models indicate a larger component derived from 15N-depleted nitric acid. These data indicate that the pulse of neutralized 15N-depleted nitric acid that was released into Mortandad Canyon between 1986 and 1989 has infiltrated through the alluvial aquifer and is currently affecting two intermediate wells. This hypothesis is consistent with previous

Trees in urban street canyons and their impact on the dispersion of automobile exhausts

OpenAIRE

Gromke, Christof; Ruck, Bodo

2007-01-01

The aim of the present study is to clarify the influence of trees on the dispersion of automobile exhausts in urban street canyons. For this purpose, measurements have been performed with a small scale wind tunnel model of an idealized, isolated street canyon with model trees placed along the canyon center axis. Sulfur hexafluoride (SF6) was released from a line source embedded in the street surface, simulating vehicle exhaust emissions. The influence of various tree planting arrangements on ...

Crystal-field-driven redox reactions: How common minerals split H2O and CO2 into reduced H2 and C plus oxygen

Science.gov (United States)

Freund, F.; Batllo, F.; Leroy, R. C.; Lersky, S.; Masuda, M. M.; Chang, S.

1991-01-01

It is difficult to prove the presence of molecular H2 and reduced C in minerals containing dissolved H2 and CO2. A technique was developed which unambiguously shows that minerals grown in viciously reducing environments contain peroxy in their crystal structures. The peroxy represent interstitial oxygen atoms left behind when the solute H2O and/or CO2 split off H2 and C as a result of internal redox reactions, driven by the crystal field. The observation of peroxy affirms the presence of H2 and reduced C. It shows that the solid state is indeed an unusual reaction medium.

Ligands Exchange Process on Gold Nanoparticles in Acetone Solution

Science.gov (United States)

Hu, C. L.; Mu, Y. Y.; Bian, Z. C.; Luo, Z. H.; Luo, K.; Huang, A. Z.

2018-05-01

The ligands exchange process on gold nanoparticles (GNPs) was proceeded by using hydrophobic group (PPh3) and hydrophilic group (THPO) in acetone solution. The FTIR and XPS results demonstrated that part of THPO was replaced by PPh3 which was dissolved in polar solution (acetone); the results were in accordance with the electrochemical analysis where the differential capacity decreased with increasing exchange time. After 12 h, the exchange process terminated and the final ratio of PPh3 and THPO was about 1.4: 1. This ratio remained unchanged although the PPh3 and THPO modified GNPs re-dispersed in the PPh3 acetone solution demonstrating the stable adsorption of both ligands after exchanging for 12 h. The TEM images showed that the gold nanoparticles were self-assembled from scattered to arranged morphology due to the existence of hydrophilic and hydrophobic ligands and led to Janus gold nanoparticles.

Recovery and Lithologic Analysis of Sediment from Hole UT-GOM2-1-H002, Green Canyon 955, Northern Gulf of Mexico

Science.gov (United States)

Kinash, N.; Cook, A.; Sawyer, D.; Heber, R.

2017-12-01

In May 2017 the University of Texas led a drilling and pressure coring expedition in the northern Gulf of Mexico, UT-GOM2-01. The holes were located in Green Canyon Block 955, where the Gulf of Mexico Joint Industry Project Leg II identified an approximately 100m thick hydrate-filled course-grained levee unit in 2009. Two separate wells were drilled into this unit: Holes H002 and H005. In Hole H002, a cutting shoe drill bit was used to collect the pressure cores, and only 1 of the 8 cores collected was pressurized during recovery. The core recovery in Hole H002 was generally poor, about 34%, while the only pressurized core had 45% recovery. In Hole H005, a face bit was used during pressure coring where 13 cores were collected and 9 cores remained pressurized. Core recovery in Hole H005 was much higher, at about 75%. The type of bit was not the only difference between the holes, however. Drilling mud was used throughout the drilling and pressure coring of Hole H002, while only seawater was used during the first 80m of pressure cores collected in Hole H005. Herein we focus on lithologic analysis of Hole H002 with the goal of documenting and understanding core recovery in Hole H002 to compare with Hole H005. X-ray Computed Tomography (XCT) images were collected by Geotek on pressurized cores, mostly from Hole H005, and at Ohio State on unpressurized cores, mostly from Hole H002. The XCT images of unpressurized cores show minimal sedimentary structures and layering, unlike the XCT images acquired on the pressurized, hydrate-bearing cores. Only small sections of the unpressurized cores remained intact. The unpressurized cores appear to have two prominent facies: 1) silt that did not retain original sedimentary fabric and often was loose within the core barrel, and 2) dense mud sections with some sedimentary structures and layering present. On the XCT images, drilling mud appears to be concentrated on the sides of cores, but also appears in layers and fractures within