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Sample records for glass radioactive waste

  1. Glass containing radioactive nuclear waste

    International Nuclear Information System (INIS)

    Boatner, L.A.; Sales, B.C.

    1985-01-01

    Lead-iron phosphate glasses containing a high level of Fe 2 O 3 for use as a storage medium for high-level-radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste, a highly corrosion resistant, homogeneous, easily processed glass can be formed. For corroding solutions at 90 C, with solution pH values in the range between 5 and 9, the corrosion rate of the lead-iron phosphate nuclear waste glass is at least 10 2 to 10 3 times lower than the corrosion rate of a comparable borosilicate nuclear waste glass. The presence of Fe 2 O 3 in forming the lead-iron phosphate glass is critical. Lead-iron phosphate nuclear waste glass can be prepared at temperatures as low as 800 C, since they exhibit very low melt viscosities in the 800 to 1050 C temperature range. These waste-loaded glasses do not readily devitrify at temperatures as high as 550 C and are not adversely affected by large doses of gamma radiation in H 2 O at 135 C. The lead-iron phosphate waste glasses can be prepared with minimal modification of the technology developed for processing borosilicate glass nuclear waste forms. (author)

  2. Immobilization of radioactive waste in glass matrices

    International Nuclear Information System (INIS)

    Wicks, G.G.

    1978-01-01

    A promising process for long-term management of high-level radioactive waste is to immobilize the waste in a borosilicate glass matrix. Among the most important criteria characterizing the integrity of the large-scale glass-waste forms are that they possess good chemical stability (including low leachability), thermal stability, mechanical integrity, and high radiation stability. Fulfillment of these criteria ensures the maximum margin of safety of glass-waste products, following solidification, handling, transportation, and long-term storage

  3. Control of radioactive waste-glass melters

    International Nuclear Information System (INIS)

    Bickford, D.F.; Smith, P.K.; Hrma, P.; Bowan, B.W.

    1987-01-01

    Radioactive waste-glass melters require physical control limits and redox control of glass to assure continuous operation, and maximize production rates. Typical waste-glass melter operating conditions, and waste-glass chemical reaction paths are discussed. Glass composition, batching and melter temperature control are used to avoid the information of phases which are disruptive to melting or reduce melter life. The necessity and probable limitations of control for electric melters with complex waste feed compositions are discussed. Preliminary control limits, their bases, and alternative control methods are described for use in the Defense Waste Processing Facility (DWPF) at the US Department of Energy's Savannah River Plant (SRP), and at the West Valley Demonstration Project (WVDP). Slurries of simulated high level radioactive waste and ground glass frit or glass formers have been isothermally reacted and analyzed to identify the sequence of the major chemical reactions in waste vitrification, and their effect on waste-glass production rates. Relatively high melting rates of waste batches containing mixtures of reducing agents (formic acid, sucrose) and nitrates are attributable to exothermic reactions which occur at critical stages in the vitrification process. The effect of foaming on waste glass production rates is analyzed, and limits defined for existing waste-glass melters, based upon measurable thermophysical properties. Through balancing the high nitrate wastes of the WVDP with reducing agents, the high glass melting rates and sustained melting without foaming required for successful WVDP operations have been demonstrated. 65 refs., 4 figs., 15 tabs

  4. Storage and disposal of radioactive waste as glass in canisters

    International Nuclear Information System (INIS)

    Mendel, J.E.

    1978-12-01

    A review of the use of waste glass for the immobilization of high-level radioactive waste glass is presented. Typical properties of the canisters used to contain the glass, and the waste glass, are described. Those properties are used to project the stability of canisterized waste glass through interim storage, transportation, and geologic disposal

  5. Ceramic and glass radioactive waste forms

    Energy Technology Data Exchange (ETDEWEB)

    Readey, D.W.; Cooley, C.R. (comps.)

    1977-01-01

    This report contains 14 individual presentations and 6 group reports on the subject of glass and polycrystalline ceramic radioactive waste forms. It was the general consensus that the information available on glass as a waste form provided a good basis for planning on the use of glass as an initial waste form, that crystalline ceramic forms could also be good waste forms if much more development work were completed, and that prediction of the chemical and physical stability of the waste form far into the future would be much improved if the basic synergistic effects of low temperature, radiation and long times were better understood. Continuing development of the polycrystalline ceramic forms was recommended. It was concluded that the leach rate of radioactive species from the waste form is an important criterion for evaluating its suitability, particularly for the time period before solidified waste is permanently placed in the geologic isolation of a Federal repository. Separate abstracts were prepared for 12 of the individual papers; the remaining two were previously abstracted.

  6. Glasses used for the high level radioactive wastes storage

    International Nuclear Information System (INIS)

    Sombret, C.

    1983-06-01

    High level radioactive wastes generated by the reprocessing of spent fuels is an important concern in the conditioning of radioactive wastes. This paper deals with the status of the knowledge about glasses used for the treatment of these liquids [fr

  7. Chemical durability of glasses containing radioactive fission product waste

    International Nuclear Information System (INIS)

    Mendel, J.E.; Ross, W.A.

    1974-04-01

    Measurements made to determine the chemical durability of glasses for disposal of radioactive waste are discussed. The term glass covers materials varying from true glass with only minute quantities of crystallites, such as insoluble RuO 2 , to quasi glass-ceramics which are mostly crystalline. Chemical durability requirements and Soxhlet extractor leach tests are discussed

  8. Glasses and ceramics for immobilisation of radioactive wastes for disposal

    International Nuclear Information System (INIS)

    Johnson, K.D.B.; Marples, J.A.C.

    1979-05-01

    The U.K. Research Programme on Radioactive Waste Management includes the development of processes for the conversion of high level liquid reprocessing wastes from thermal and fast reactors to borosilicate glasses. The properties of these glasses and their behaviour under storage and disposal conditions have been examined. Methods for immobilising activity from other wastes by conversion to glass or ceramic forms is described. The U.K. philosophy of final solutions to waste management and disposal is presented. (author)

  9. Immobilization of hazardous and radioactive waste into glass structures

    International Nuclear Information System (INIS)

    Wicks, G.G.

    1997-01-01

    As a result of more than three decades of international research, glass has emerged as the material of choice for immobilization of a wide range of potentially hazardous radioactive and non-radioactive materials. The ability of glass structures to incorporate and then immobilize many different elements into durable, high integrity, waste glass products is a direct function of the unique random network structure of the glassy state. Every major country involved with long-term management of high-level radioactive waste (HLW) has either selected or is considering glass as the matrix of choice for immobilizing and ultimately, disposing of the potentially hazardous, high-level radioactive material. There are many reasons why glass is preferred. Among the most important considerations are the ability of glass structures to accommodate and immobilize the many different types of radionuclides present in HLW, and to produce a product that not only has excellent technical properties, but also possesses good processing features. Good processability allows the glass to be fabricated with relative ease even under difficult remote-handling conditions necessary for vitrification of highly radioactive material. The single most important property of the waste glass produced is its ability to retain hazardous species within the glass structure and this is reflected by its excellent chemical durability and corrosion resistance to a wide range of environmental conditions. In addition to immobilization of HLW glass matrices are also being considered for isolation of many other types of hazardous materials, both radioactive as well as nonradioactive. This includes vitrification of various actinides resulting from clean-up operations and the legacy of the cold war, as well as possible immobilization of weapons grade plutonium resulting from disarmament activities. Other types of wastes being considered for immobilization into glasses include transuranic wastes, mixed wastes, contaminated

  10. Fixation of radioactive waste in glass

    International Nuclear Information System (INIS)

    Chapman, C.C.; Mendel, J.E.

    1976-08-01

    After a brief review of the source of high level wastes and the specific requirements and desirable characteristics of glass used as a storage vehicle, the development work done on two vitrification systems is outlined. One is an in-can melter system and the second is a ceramic melter. Primary emphasis has been placed on the in-can melter system for use in the near future. Both systems are capable of converting high level waste to a glass which possesses low release potential

  11. Volumetric change of simulated radioactive waste glass irradiated by electron accelerator. [Silica glass

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Seichi; Furuya, Hirotaka; Inagaki, Yaohiro; Kozaka, Tetsuo; Sugisaki, Masayasu

    1987-11-01

    Density changes of simulated radioactive waste glasses, silica glass and Pyrex glass irradiated by an electron accelerator were measured by a ''sink-float'' technique. The density changes of the waste and silica glasses were less than 0.05 %, irradiated at 2.0 MeV up to the fluence of 1.7 x 10/sup 17/ ecm/sup 2/, while were remarkably smaller than that of Pyrex glass of 0.18 % shrinkage. Precision of the measurements in the density changes of the waste glass was lower than that of Pyrex glass possibly because of the inhomogeneity of the waste glass

  12. Development Of Glass Matrices For HLW Radioactive Wastes

    International Nuclear Information System (INIS)

    Jantzen, C.

    2010-01-01

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc 99 , Cs 137 , and I 129 . Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  13. DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES

    Energy Technology Data Exchange (ETDEWEB)

    Jantzen, C.

    2010-03-18

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  14. Radioactive wastes immobilization in glasses and ceramics

    International Nuclear Information System (INIS)

    Zanotto, E.D.

    1983-01-01

    A review on the several options available for encapsulation and disposal of high level radioactive liquid wastes is presented, along with the relative merits and disadvantages of each material to be encapsulated. Some of the main fields requiring further advancements in both scientific and technological research are discussed and a few suggestions for the solution of the brazilian problem are given. (Author) [pt

  15. High-level radioactive waste glass and storage canister design

    International Nuclear Information System (INIS)

    Slate, S.C.; Ross, W.A.

    1979-01-01

    Management of high-level radioactive wastes is a primary concern in nuclear operations today. The main objective in managing these wastes is to convert them into a solid, durable form which is then isolated from man. A description is given of the design and evaluation of this waste form. The waste form has two main components: the solidified waste and the storage canister. The solid waste form discussed in this study is glass. Waste glasses have been designed to be inert to water attack, physically rugged, low in volatility, and stable over time. Two glass-making processes are under development at PNL. The storage canister is being designed to provide high-integrity containment for solidified wastes from processing to terminal storage. An outline is given of the steps in canister design: material selection, stress and thermal analyses, quality verification, and postfill processing. Examples are given of results obtained from actual nonradioactive demonstration tests. 14 refs

  16. Immobilization of radioactive wastes in glasses and ceramics

    International Nuclear Information System (INIS)

    Zanotto, E.D.

    1983-01-01

    A large amount of radioactive liquid wastes arises from the reprocessing of spent nuclear fuels to recover uranium and plutonium. Immobilization of such wastes in solid form and disposal of the solidified wastes in safe places, to prevent contamination of the human environment, are topics of considerable interest for both the scientific community and the public in general. The great majority of materials candidate for the encapsulation of radioactive wastes are inorganic non-metalic, such as glasses, glass-ceramics, special cements, calcined ceramics and few more. Among these materials, certain glasses have received special attention, and are being studied for over twenty years. It is estimated that about US$2 billion have already been spent in these studies. The disposal (long term storage) of these solid wastes may be possible in deep geological formations, salt mines, the ocean bed, by evacuation to the outer space, etc. A brief review on the several options avaiable for encapsulation and disposal of high level radioactive liquid wastes is presented, along with the relative merits and disadvantages of the candidate materials for encapsulation. A few suggestions for the solution of the Brazilian problem are advanced. (Author) [pt

  17. Ceramics and glasses for radioactive waste storage

    International Nuclear Information System (INIS)

    Baudin, G.

    1984-06-01

    Borosilicate glasses are mainly choosen for the confinement of fission products; industrial plants are either in operation (AVM) or in construction. Studies of ceramics as a matrix haven't received real application [fr

  18. Method and apparatus for glass solidification porcessing for radioactive liquid waste

    International Nuclear Information System (INIS)

    Torada, Shin-ichiro; Masaki, Toshio; Sakai, Akira.

    1989-01-01

    Glass material supplied to a glass melting furnace is made in the form of a glass container. Then, radioactive liquid wastes are directly injected into the glass vessel and the glass vessel injected with the radioactive liquid wastes is charged into the glass melting furnace. The glass material and the radioactive liquid wastes are supplied simultaneously to the glass melting furnace. Then, corresponding to the amount of the glass material used for the glass vessel, the amount of the radioactive liquid wastes injected to the inside thereof is controlled to thereby set the mixing ratio between the glass material and the radioactive liquid wastes. Further, by controlling the number of the glass vessels injected with the radioactive liquid wastes to be charged into the glass melting furnace, the amount of supplying the radioactive liquid wastes and the glass material is controlled. This can easily maintain constant the amount of the glass material and the radioacative liquid wastes supplied to the glass melting furnace and the mixing ratio thereof. (T.M.)

  19. Control of high level radioactive waste-glass melters

    International Nuclear Information System (INIS)

    Bickford, D.F.; Choi, A.S.

    1991-01-01

    Slurry Fed Melters (SFM) are being developed in the United States, Europe and Japan for the conversion of high-level radioactive waste to borosilicate glass for permanent disposal. The high transition metal, noble metal, nitrate, organic, and sulfate contents of these wastes lead to unique melter redox control requirements. Pilot waste-glass melter operations have indicated the possibility of nickel sulfide or noble-metal fission-product accumulation on melter floors, which can lead to distortion of electric heating patterns, and decrease melter life. Sulfide formation is prevented by control of the redox chemistry of the melter feed. The redox state of waste-glass melters is determined by balance between the reducing potential of organic compounds in the feed, and the oxidizing potential of gases above the melt, and nitrates and polyvalent elements in the waste. Semiquantitative models predicting limitations of organic content have been developed based on crucible testing. Computerized thermodynamic computations are being developed to predict the sequence and products of redox reactions and is assessing process variations. Continuous melter test results have been compared to improved computer staged-thermodynamic-models of redox behavior. Feed chemistry control to prevent sulfide and moderate noble metal accumulations are discussed. 17 refs., 3 figs

  20. Low sintering temperature glass waste forms for sequestering radioactive iodine

    Science.gov (United States)

    Nenoff, Tina M.; Krumhansl, James L.; Garino, Terry J.; Ockwig, Nathan W.

    2012-09-11

    Materials and methods of making low-sintering-temperature glass waste forms that sequester radioactive iodine in a strong and durable structure. First, the iodine is captured by an adsorbant, which forms an iodine-loaded material, e.g., AgI, AgI-zeolite, AgI-mordenite, Ag-silica aerogel, ZnI.sub.2, CuI, or Bi.sub.5O.sub.7I. Next, particles of the iodine-loaded material are mixed with powdered frits of low-sintering-temperature glasses (comprising various oxides of Si, B, Bi, Pb, and Zn), and then sintered at a relatively low temperature, ranging from 425.degree. C. to 550.degree. C. The sintering converts the mixed powders into a solid block of a glassy waste form, having low iodine leaching rates. The vitrified glassy waste form can contain as much as 60 wt % AgI. A preferred glass, having a sintering temperature of 500.degree. C. (below the silver iodide sublimation temperature of 500.degree. C.) was identified that contains oxides of boron, bismuth, and zinc, while containing essentially no lead or silicon.

  1. Leach rate studies on glass containing actual radioactive waste

    International Nuclear Information System (INIS)

    Walker, D.D.; Wiley, J.R.; Dukes, M.D.; LeRoy, J.H.

    1980-01-01

    Borosilicate glass containing radioactive wastes from the Savannah River Plant have been leached for 900 days. The International Standards Organization's (ISO) static leach test procedure was used on glass buttons in various leachants. Leach rates based on 90 Sr and 137 Cs analyses were similar: 2 x 10 -8 to 3 x 10 -8 g/(cm 2 )(d) in distilled water, 1 x 10 -8 to 3 x 10 -7 g/(cm 2 )(d) in pH 7 buffer, 3 x 10 -7 to 7 x 10 -7 g/(cm 2 )(d) in pH 9 buffer, and 7 x 10 -6 to 8 x 10 -5 g/(cm 2 )(d) in pH 4 buffer. Rates based on Pu analyses were the same as above in distilled water and pH 9 buffer, but were lower by an order of magnitude in pH 4 and pH 7 buffers. Almost all leach rates remained constant between 200 and 900 days of leaching. Increasing the concentration of the buffering agents had no effect on the leach rates at pH 7 (phosphate) and pH 9 (carbonate), but dramatically increased the rates at pH 4 (acetate). Leach rates did not differ significantly between high aluminum and high iron waste glasses

  2. Control of high-level radioactive waste-glass melters

    International Nuclear Information System (INIS)

    Bickford, D.F.; Coleman, C.J.

    1990-01-01

    The Defense Waste Processing Facility (DWPF) will immobilize Savannah River Site High Level Waste as a durable borosilicate glass for permanent disposal in a repository. The DWPF will be controlled based on glass composition. The following discussion is a preliminary analysis of the capability of the laboratory methods that can be used to control the glass composition, and the relationships between glass durability and glass properties important to glass melting. The glass durability and processing properties will be controlled by controlling the chemical composition of the glass. The glass composition will be controlled by control of the melter feed transferred from the Slurry Mix Evaporator (SME) to the Melter Feed Tank (MFT). During cold runs, tests will be conducted to demonstrate the chemical equivalence of glass sampled from the pour stream and glass removed from cooled canisters. In similar tests, the compositions of glass produced from slurries sampled from the SME and MFT will be compared to final product glass to determine the statistical relationships between melter feed and glass product. The total error is the combination of those associated with homogeneity in the SME or MFT, sampling, preparation of samples for analysis, instrument calibration, analysis, and the composition/property model. This study investigated the sensitivity of estimation of property data to the combination of variations from sampling through analysis. In this or a similar manner, the need for routine glass product sampling will be minimized, and glass product characteristics will be assured before the melter feed is committed to the melter

  3. UK program: glasses and ceramics for immobilization of radioactive wastes for disposal

    International Nuclear Information System (INIS)

    Johnson, K.D.B.

    1979-01-01

    The UK Research Program on Radioactive Waste Management includes the development of processes for the conversion of high-level-liquid-reprocessing wastes from thermal and fast reactors to borosilicate glasses. The properties of these glasses and their behavior under storage and disposal conditions have been examined. Methods for immobilizing activity from other wastes by conversion to glass or ceramic forms are described. The UK philosophy of final solutions to waste management and disposal is presented

  4. Volume reduction and solidification of radioactive waste incineration ash with waste glass

    International Nuclear Information System (INIS)

    Koyama, Hidemi; Kobayashi, Masayuki

    2007-01-01

    The low-level radioactive waste generated from research institutions and hospitals etc. is packed into a container and is kept. The volume reduced state or the unprocessed state by incineration or compression processing are used because neither landfill sites nor disposal methods have been fixed. Especially, because the bulk density is low, and it is easy to disperse, the low-level radioactive waste incineration ash incinerated for the volume reduction is a big issue in security, safety, stability in the inventory location. A safe and appropriate disposal processing method is desired. When the low temperature sintering method in the use of the glass bottle cullet was examined, volume reduction and stabilization of low-level radioactive waste incineration ash were verified. The proposed method is useful for the easy treatment of the low-level radioactive waste incineration ash. (author)

  5. Defense Waste Processing Facility radioactive operations -- Part 2, Glass making

    International Nuclear Information System (INIS)

    Carter, J.T.; Rueter, K.J.; Ray, J.W.; Hodoh, O.

    1996-01-01

    The Savannah River Site's Defense Waste Processing Facility (DWPF) near Aiken, SC is the nation's first and world's largest vitrification facility. Following a ten year construction period and nearly 3 year non-radioactive test program, the DWPF began radioactive operations in March, 1996. The results of the first 8 months of radioactive operations are presented. Topics include facility production from waste preparation batching to canister filling

  6. Glass-solidification method for high level radioactive liquid waste

    International Nuclear Information System (INIS)

    Kawamura, Kazuhiro; Kometani, Masayuki; Sasage, Ken-ichi.

    1996-01-01

    High level liquid wastes are removed with precipitates mainly comprising Mo and Zr, thereafter, the high level liquid wastes are mixed with a glass raw material comprising a composition having a B 2 O 3 /SiO 2 ratio of not less than 0.41, a ZnO/Li 2 O ratio of not less than 1.00, and an Al 2 O 3 /Li 2 O ratio of not less than 2.58, and they are melted and solidified into glass-solidification products. The liquid waste content in the glass-solidification products can be increased up to about 45% by using the glass raw material having such a predetermined composition. In addition, deposition of a yellow phase does not occur, and a leaching rate identical with that in a conventional case can be maintained. (T.M.)

  7. Application of a glass furnace system to low-level radioactive and mixed waste disposal

    International Nuclear Information System (INIS)

    Klinger, L.; Armstrong, K.

    1986-01-01

    In 1981 Mound began a study to determine the feasibility of using an electrically heated glass furnace for the treatment of low-level radioactive wastes generated at commercial nuclear power facilities. Experiments were designed to determine: Whether the technology offered solutions to industry waste disposal problems, and if so; whether is could meet what were thought to be critical requirements for radioactive thermal waste processing. These requirements include: high quality combustion of organic constituents, capture and immobilization of radioactivity, integrity of final waste form, and cost effectiveness. To address these questions a variety of wastes typical of the types generated by nuclear power facilities, including not only standard trash but also wastes of high aqueous and/or inorganic content, were spiked with waste radioisotopes predominant in plant wastes and processed in the glass furnace. The results of this study indicate that the unit is capable of fully meeting the addressed needs of the nuclear industry for power plant waste processing

  8. Chemical durability of soda-lime-aluminosilicate glass for radioactive waste vitrification

    International Nuclear Information System (INIS)

    Eppler, F.H.; Yim, M.S.

    1998-01-01

    Vitrification has been identified as one of the most viable waste treatment alternatives for nuclear waste disposal. Currently, the most popular glass compositions being selected for vitrification are the borosilicate family of glasses. Another popular type that has been around in glass industry is the soda-lime-silicate variety, which has often been characterized as the least durable and a poor candidate for radioactive waste vitrification. By replacing the boron constituent with a cheaper substitute, such as silica, the cost of vitrification processing can be reduced. At the same time, addition of network intermediates such as Al 2 O 3 to the glass composition increases the environmental durability of the glass. The objective of this study is to examine the ability of the soda-lime-aluminosilicate glass as an alternative vitrification tool for the disposal of radioactive waste and to investigate the sensitivity of product chemical durability to variations in composition

  9. Chemical states of molybdenum in radioactive waste glass

    International Nuclear Information System (INIS)

    Ishiguro, Katsuhiko; Kawanishi, Nobuo; Nagaki, Hiroshi; Naito, Aritsune

    1982-01-01

    In order to confirm an expectation that the chemical state of molybdenum in glass reflects the phase separation tendency of the yellow solid from the melt of borosilicate glass, simulated waste glasses were prepared, and ESCA analysis was performed using a commercially available electron spectrometer (PHI550 E) with an excitation source consisting of Mg Kα-ray. The effects of the concentration of Mo and FE 2 O 3 and the melting atmosphere (oxidizing or reducing) in which the samples were prepared on the chemical state of Mo and the solubility of MoO 3 were examined. From the observation of Mo spectra, it was shown that Mo in waste glass had several valencies, e.g., Mo(3), Mo(4), Mo(5) and Mo(6), while Mo in the yellow solid separated from the melts exhibited hexa-valent state, the peak intensity of higher valencies increased relatively with the increase of MoO 3 concentration, but the chemical state of Mo did not change remarkably around the solubility limit of MoO 3 , the melting atmosphere influenced on the Mo state in the waste glass, the peak intensity of Mo(6) increased relatively with the increasing Fe 2 O 3 concentration, and Mo in devitrified glass exhibited hexa-valent state. (Yoshitake, I.)

  10. Letter report: Minor component study for low-level radioactive waste glasses

    International Nuclear Information System (INIS)

    Li, H.

    1996-03-01

    During the waste vitrification process, troublesome minor components in low-level radioactive waste streams could adversely affect either waste vitrification rate or melter life-time. Knowing the solubility limits for these minor components is important to determine pretreatment options for waste streams and glass formulation to prevent or to minimize these problems during the waste vitrification. A joint study between Pacific Northwest Laboratory and Rensselaer Polytechnic Institute has been conducted to determine minor component impacts in low-level nuclear waste glass

  11. Performance of a buried radioactive high level waste (HLW) glass after 24 years

    International Nuclear Information System (INIS)

    Jantzen, Carol M.; Kaplan, Daniel I.; Bibler, Ned E.; Peeler, David K.; John Plodinec, M.

    2008-01-01

    A radioactive high level waste glass was made in 1980 with Savannah River Site (SRS) Tank 15 waste. This glass was buried in a lysimeter in the SRS burial ground for 24 years. Lysimeter leachate data was available for the first 8 years. The glass was exhumed in 2004. The glass was predicted to be very durable and laboratory tests confirmed this. Scanning electron microscopy of the glass burial surface showed no significant glass alteration consistent with results of other laboratory and field tests. Radionuclide profiling for alpha, beta, and 137 Cs indicated that Pu was not enriched in the soil while 137 Cs and 9 deg. C Sr were enriched in the first few centimeters surrounding the glass. Lysimeter leachate data indicated that 9 deg. C Sr and 137 Cs leaching from the glass was diffusion controlled

  12. Development and radiation stability of glasses for highly radioactive wastes

    International Nuclear Information System (INIS)

    Hall, A.R.; Dalton, J.T.; Hudson, B.; Marples, J.A.C.

    1976-01-01

    The variation of formation temperature, crystallizing behaviour and leach resistance with composition changes for sodium-lithium borosilicate glasses suitable for vitrifying Magnox waste are discussed. Viscosities have been measured between 400 and 1050 0 C. The principal crystal phases which occur have been identified as magnesium silicate, magnesium borate and ceria. The leach rate of polished discs in pure water at 100 0 C does not decrease with time if account is taken of the fragile siliceous layer that is observed to occur. The effect of 100 years' equivalent α- and β-irradiation on glass properties is discussed. Stored energy release experiments demonstrated that energy is released over a wide temperature range so that it cannot be triggered catastrophically. Temperatures required to release energy are dependent upon the original storage temperature. Helium release is by Fick's diffusion law up to at least 30% of the total inventory, with diffusion coefficients similar to those for comparable borosilicate glasses. Leach rates were not measurably affected by α-radiation. β-radiation in a Van de Graaff accelerator did not change physical properties, but irradiation in an electron microscope caused minute bubbles in lithium-containing glasses above 200 0 C. (author)

  13. Product consistency leach tests of Savannah River Site radioactive waste glasses

    International Nuclear Information System (INIS)

    Bibler, N.E.; Bates, J.K.

    1990-01-01

    The product consistency test (PCT) is a glass leach test developed at the Savannah River Site (SRS) to confirm the durability of radioactive nuclear waste glasses that will be produced in the Defense Waste Processing Facility. The PCT is a seven day, crushed glass leach test in deionized water at 90C. Final leachates are filtered and acidified prior to analysis. To demonstrate the reproducibility of the PCT when performed remotely, SRS and Argonne National Laboratory have performed the PCT on samples of two radioactive glasses. The tests were also performed to compare the releases of the radionuclides with the major nonradioactive glass components and to determine if radiation from the glass was affecting the results of the PCT. The test was performed in triplicate at each laboratory. For the major soluble elements, B, Li, Na, and Si, in the glass, each investigator obtained relative precisions in the range 2-5% in the triplicate tests. This range indicates good precision for the PCT when performed remotely with master slave manipulators in a shielded cell environment. When the results of the two laboratories were compared to each other, the agreement was within 20%. Normalized concentrations for the nonradioactive and radioactive elements in the PCT leachates measured at both facilities indicated that the radionuclides were released from the glass slower than the major soluble elements in the glass. For both laboratories, the normalized releases for both glasses were in the general order Li ∼ B ∼ Na > Si > Cs - 137 > Sb - 125 < Sr - 90. The normalized releases for the major soluble elements and the final pH values in the tests with radioactive glass are consistent with those for nonradioactive glasses with similar compositions. This indicates that there was no significant effect of radiation on the results of the PCT

  14. X-ray spectrometric determination of glass content of melts incorporating radioactive waste: a feasibility study

    International Nuclear Information System (INIS)

    Slates, R.V.

    1978-09-01

    X-ray fluorescence spectrometry was evaluated for the determination of glass content and homogeneity of glass incorporating high-level radioactive waste. Accuracy and precision were determined for analyses of Al 2 O 3 , SiO 2 , CaO, TiO 2 , MnO, Fe 2 O 3 , and NiO in specimens of known composition. These specimens were prepared by fusing powdered glass with nonradioactive synthetic waste. Matrix effects of sodium on these analyses were specifically evaluated. X-ray fluorescence spectrometry was shown to be applicable to the proposed determinations by comparing the known glass contents of 14 glass waste compositions with those calculated from experimentally determined concentrations of SiO or TiO 2

  15. Glass and nuclear wastes

    International Nuclear Information System (INIS)

    Sombret, C.

    1982-10-01

    Glass shows interesting technical and economical properties for long term storage of solidified radioactive wastes by vitrification or embedding. Glass composition, vitrification processes, stability under irradiation, thermal stability and aqueous corrosion are studied [fr

  16. Direct conversion of radioactive and chemical waste containing metals, ceramics, amorphous solids, and organics to glass

    International Nuclear Information System (INIS)

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

    1994-01-01

    The Glass Material Oxidation and Dissolution System (CMODS) is a new process for direct conversion of radioactive, mixed, and chemical wastes to glass. The wastes can be in the chemical forms of metals, ceramics, amorphous solids, and organics. GMODS destroys organics and it incorporates heavy metals and radionuclides into a glass. Processable wastes may include miscellaneous spent fuels (SF), SF hulls and hardware, plutonium wastes in different forms, high-efficiency particulate air (HEPA) filters, ion-exchange resins, failed equipment, and laboratory wastes. Thermodynamic calculations indicate theoretical feasibility. Small-scale laboratory experiments (< 100 g per test) have demonstrated chemical laboratory feasibility for several metals. Additional work is needed to demonstrate engineering feasibility

  17. Method for calcining radioactive wastes

    International Nuclear Information System (INIS)

    Bjorklund, W.J.; McElroy, J.L.; Mendel, J.E.

    1979-01-01

    A method for the preparation of radioactive wastes in a low leachability form involves calcining the radioactive waste on a fluidized bed of glass frit, removing the calcined waste to melter to form a homogeneous melt of the glass and the calcined waste, and then solidifying the melt to encapsulate the radioactive calcine in a glass matrix

  18. Glass as a medium for the ultimate disposal of highly radioactive waste

    International Nuclear Information System (INIS)

    Sombret, C.

    1983-09-01

    The conversion of high level radioactive liquid wastes into glass is now considered in every nuclear country. The glass composition must take into account the components of the solutions and be formulated in order to meet certain requirements, mainly those necessary for safe further disposal. The compositions of these glasses, all borosilicates, are consequently unusual. Heat due to β γ decay generates some devitrification but it has not yet been demonstrated that this is detrimental. β irradiation has minor effects on the glass structure but the effect of α emitters is not presently totally investigated. If stored energy consequenses are negligible, further experiments must be carried out to ascertain the effect of helium build up or the behaviour of the mechanical properties. Processes of industrial interest have been developped and a plant has already produced radioactive glass blocks for 5 years

  19. Development of a glass matrix for vitrification of sulphate bearing high level radioactive liquid waste

    International Nuclear Information System (INIS)

    Kaushik, C.P.; Mishra, R.K.; Thorat, Vidya; Ramchandran, M.; Amar Kumar; Ozarde, P.D.; Raj, Kanwar; Das, D.

    2004-07-01

    High level radioactive liquid waste (HLW) is generated during reprocessing of spent nuclear fuel. In the earlier reprocessing flow sheet ferrous sulphamate has been used for valancy adjustment of Pu from IV to III for effective separation. This has resulted in generation of HLW containing significance amount of sulphate. Internationally borosilicate glass matrix has been adopted for vitrification of HLW. The first Indian vitrification facility at Waste Immobilislition Plant (WIP), Tarapur a five component borosilicate matrix (SiO 2 :B 2 O 3 :Na 2 O : MnO : TiO 2 ) has been used for vitrification of waste. However at Trombay HLW contain significant amount of sulphate which is not compatible with standard borosilicate formulation. Extensive R and D efforts were made to develop a glass formulation which can accommodate sulphate and other constituents of HLW e.g., U, Al, Ca, etc. This report deals with development work of a glass formulations for immobilization of sulphate bearing waste. Different glass formulations were studied to evaluate the compatibility with respect to sulphate and other constituents as mentioned above. This includes sodium, lead and barium borosilicate glass matrices. Problems encountered in different glass matrices for containment of sulphate have also been addressed. A glass formulation based on barium borosilicate was found to be effective and compatible for sulphate bearing high level waste. (author)

  20. Infrared and Raman investigation of rare-earth phosphate glasses for potential use as radioactive waste forms

    International Nuclear Information System (INIS)

    Morgan, S.H.

    1989-01-01

    This project was designed to investigate the properties of the rare-earth phosphate glass systems CeO 2 -P 2 O 5 and Pr 2 O 3 -P 2 O 5 for potential use as radioactive waste glasses. The glass-forming region and optimum processing parameters of these glass systems were investigated. The structure of the host glasses and glassed loaded with simulated waste elements was investigated using Raman and infrared spectroscopy. Because of the radical differences in the spectra of the molybdenum-loaded glasses, the structure of the MoO 3 -P 2 O 5 glass system was also investigated. 29 refs., 8 figs., 2 tabs

  1. Use of glass-ceramic materials for the fixation of radioactive wastes

    International Nuclear Information System (INIS)

    Minaev, A.A.; Oziraner, S.N.; Prokhorova, N.P.

    1979-01-01

    This paper is concerned with the study of the crystallization of phosphate and silicate glasses. It was shown that temperature and time of storage influence considerably the crystallization of glasses and that crystallization very often increases their rates of leaching to a great extent. However, there are glasses in which crystallization does not result in leaching rate increase. It seems reasonable to use these materials for the fixation of radioactive wastes. The main reasons for the increase in the leaching rate during crystallization are the formation of porosity and soluble crystal phases

  2. Development of an ASTM standard glass durability test, the Product Consistency Test (PCT), for high level radioactive waste glass

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Bibler, N.E.; Beam, D.C.; Ramsey, W.G.

    1994-01-01

    The nation's first, and the world's largest, facility to immobilize high-level nuclear waste in durable borosilicate glass has started operation at the Savannah River Site (SRS) in Aiken, South Carolina. The product specifications on the glass wasteform produced in the Defense Waste Processing Facility (DWPF) required extensive characterization of the glass product before actual production began and for continued characterization during production. To aid in this characterization, a glass durability (leach) test was needed that was easily reproducible, could be performed remotely on highly radioactive samples, and could yield results rapidly. Several standard leach tests were examined with a variety of test configurations. Using existing tests as a starting point, the DWPF Product Consistency Test (PCT was developed in which crushed glass samples are exposed to 90 ± 2 degree C deionized water for seven days. Based on extensive testing, including a seven-laboratory round robin and confirmatory testing with radioactive samples, the PCT is very reproducible, yields reliable results rapidly, and can be performed in shielded cell facilities with radioactive samples

  3. Alteration of national glass in radioactive waste repository host rocks: A conceptional review

    International Nuclear Information System (INIS)

    Apps, J.A.

    1987-01-01

    The storage of high-level radioactive wastes in host rocks containing natural glass has potential chemical advantages, especially if the initial waste temperatures are as high as 250 0 C. However, it is not certain how natural glasses will decompose when exposed to an aqueous phase in a repository environment. The hydration and devitrification of both rhyolitic and natural basaltic natural glasses are reviewed in the context of hypothetical thermodynamic phase relations, infrared spectroscopic data and laboratory studies of synthetic glasses exposed to steam. The findings are compared with field observations and laboratory studies of hydrating and devitrifying natural glasses. The peculiarities of the dependence of hydration and devitrification behavior on compositional variation is noted. There is substantial circumstantial evidence to support the belief that rhyolitic glasses differ from basaltic glasses in their thermodynamic stability and their lattice structure, and that this is manifested by a tendency of the former to hydrate rather than devitrify when exposed to water. Further research remains to be done to confirm the differences in glass structure, and to determine both physically and chemically dependent properties of natural glasses as a function of composition

  4. Immobilization of simulated high-level radioactive waste in borosilicate glass: Pilot scale demonstrations

    International Nuclear Information System (INIS)

    Ritter, J.A.; Hutson, N.D.; Zamecnik, J.R.; Carter, J.T.

    1991-01-01

    The Integrated DWPF Melter System (IDMS), operated by the Savannah River Laboratory, is a pilot scale facility used in support of the start-up and operation of the Department of Energy's Defense Waste Processing Facility. The IDMS has successfully demonstrated, on an engineering scale (one-fifth), that simulated high level radioactive waste (HLW) sludge can be chemically treated with formic acid to adjust both its chemical and physical properties, and then blended with simulated precipitate hydrolysis aqueous (PHA) product and borosilicate glass frit to produce a melter feed which can be processed into a durable glass product. The simulated sludge, PHA and frit were blended, based on a product composition program, to optimize the loading of the waste glass as well as to minimize those components which can cause melter processing and/or glass durability problems. During all the IDMS demonstrations completed thus far, the melter feed and the resulting glass that has been produced met all the required specifications, which is very encouraging to future DWPF operations. The IDMS operations also demonstrated that the volatile components of the melter feed (e.g., mercury, nitrogen and carbon, and, to a lesser extent, chlorine, fluorine and sulfur) did not adversely affect the melter performance or the glass product

  5. Product consistency leach tests of Savannah River Site radioactive waste glasses

    International Nuclear Information System (INIS)

    Bibler, N.E.; Bates, J.K.

    1989-01-01

    The Product Consistency Test (PCT) is a glass leach test that was developed at the Savannah River Site (SRS) to routinely confirm the durability of nuclear waste glasses that will be produced in the Defense Waste Processing Facility. The PCT is a 7 day, crushed glass leach test in deionized water at 90 degree C. Final leachates are filtered and acidified prior to analysis. To demonstrate the reproducibility of the PCT when performed remotely, SRS and Argonne National Laboratory have performed the PCT on samples of two radioactive glasses. The tests were also performed to compare the releases of the radionuclides with the major nonradioactive glass components and to determine if radiation from the glass was affecting the results of the PCT. The test was performed in triplicate at each laboratory. For the major soluble elements, B, Li, Na, and Si, in the glass, each investigator obtained relative precisions in the range 2--5% in the triplicate tests. This range indicates good precision for the PCT when performed remotely with master slave manipulators in a shielded cell environment

  6. Alpha spectrum profiling of plutonium in leached simulated high-level radioactive waste-glass

    International Nuclear Information System (INIS)

    Diamond, H.; Friedman, A.M.

    1981-01-01

    Low-geometry X-ray spectra from /sup 239/Pu and /sup 237/Np, incorporated into simulated high-level radioactive waste-glass, were transformed into depth distributions for these elements. Changes in the depth profiles were observed for a series of static leachings in 75/degree/C water. Radiochemical assay of the leach solutions revealed that little neptunium or plutonium was leached, and that the amount leached was independent of leaching time. The depth profiles of the leached specimens showed that there was selective leaching of nonradioactive components of the glass, concentrating the remaining neptunium and plutonium in a broad zone near (but not at) the glass surface. Eventual redeposition of nonradioactive material onto the glass surface inhibited further leaching

  7. Radioactive wastes

    International Nuclear Information System (INIS)

    Teillac, J.

    1988-01-01

    This study of general interest is an evaluation of the safety of radioactive waste management and consequently the preservation of the environment for the protection of man against ionizing radiations. The following topics were developed: radiation effects on man; radioactive waste inventory; radioactive waste processing, disposal and storage; the present state and future prospects [fr

  8. Crystal-Tolerant Glass Approach For Mitigation Of Crystal Accumulation In Continuous Melters Processing Radioactive Waste

    International Nuclear Information System (INIS)

    Kruger, Albert A.; Rodriguez, Carmen P.; Lang, Jesse B.; Huckleberry, Adam R.; Matyas, Josef; Owen, Antoinette T.

    2012-01-01

    High-level radioactive waste melters are projected to operate in an inefficient manner as they are subjected to artificial constraints, such as minimum liquidus temperature (T L ) or maximum equilibrium fraction of crystallinity at a given temperature. These constraints substantially limit waste loading, but were imposed to prevent clogging of the melter with spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr) 2 O 4 ]. In the melter, the glass discharge riser is the most likely location for crystal accumulation during idling because of low glass temperatures, stagnant melts, and small diameter. To address this problem, a series of lab-scale crucible tests were performed with specially formulated glasses to simulate accumulation of spinel in the riser. Thicknesses of accumulated layers were incorporated into empirical model of spinel settling. In addition, T L of glasses was measured and impact of particle agglomeration on accumulation rate was evaluated. Empirical model predicted well the accumulation of single crystals and/or smallscale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ∼14.9 +- 1 nm/s determined for this glass will result in ∼26 mm thick layer in 20 days of melter idling

  9. Synthesis of recent investigations on corrosion behaviour of radioactive waste glasses

    International Nuclear Information System (INIS)

    Grauer, R.

    1985-03-01

    Work which has appeared since the earlier report (EIR--477) on the corrosion behaviour of borosilicate glasses as a solidification matrix for high-level radioactive waste has been evaluated. Many works have confirmed that for a particular glass, besides temperature and pH-value, the silicate concentration of the solution exerts the strongest influence on corrosion rate. The effect of silicate can be described in terms of simple reaction kinetics models which provides a more sound basis for prediction of long-term behaviour of glasses than previously existed. Meanwhile, the effects of backfill- and canister-materials and their corrosion products have been given the attention they merit. These materials affect glass corrosion primarily through regulation of silicic acid concentration. A particular finding which is of interest is the strong inhibition of glass corrosion by lead ions. Stationary corrosion rates in the order of magnitude of 10 -5 g/cm 2 .d can be derived from long-term corrosion experiments in stagnant water at 90 0 C. At the envisaged repository temperature of 55 0 C they will be one to two orders of magnitude less. The effects of radioactive decay on corrosion rate are either very small or not detectable at all. (Auth.)

  10. Permanent disposal by burial of highly radioactive wastes incorporated into glass

    International Nuclear Information System (INIS)

    Merritt, W.F.

    1967-01-01

    A method has been developed at Chalk River for incorporating high-level fission product wastes from nuclear fuel processing into glass blocks for ultimate disposal. Nitric acid solutions of fission products were mixed with nepheline-syenite and lime in crucibles and fired in a kiln to a temperature of 1350 o C to form a glass with high resistance to leaching. Two test disposals of glass blocks were made into the ground below the water table. The first, in August 1958, contained about 300 Ci in 25 blocks of a highly resistant glass. The second, in May 1960, contained about 1100 Ci in 25 blocks of a less resistant formulation. Monitoring of the two tests has continued for eight and six years respectively. A soil sampling programme has indicated that the leaching rate tended to decrease with time and is now less than 10 -10 g/cm 2 per day, or two orders of magnitude lower than that predicted from laboratory leaching tests. These results indicate that the method is suitable for permanent disposal of high-level nuclear wastes and that the blocks could be buried unprotected in a controlled area, even in saturated sand of low exchange capacity. Burial above the saturated zone in an and region would result in even less release of radioactivity from the glass. (author)

  11. Radioactive wastes

    International Nuclear Information System (INIS)

    Grass, F.

    1982-01-01

    Following a definition of the term 'radioactive waste', including a discussion of possible criteria allowing a delimitation of low-level radioactive against inactive wastes, present techniques of handling high-level, intermediate-level and low-level wastes are described. The factors relevant for the establishment of definitive disposals for high-level wastes are discussed in some detail. Finally, the waste management organization currently operative in Austria is described. (G.G.)

  12. Predictive modeling of crystal accumulation in high-level waste glass melters processing radioactive waste

    Science.gov (United States)

    Matyáš, Josef; Gervasio, Vivianaluxa; Sannoh, Sulaiman E.; Kruger, Albert A.

    2017-11-01

    The effectiveness of high-level waste vitrification at Hanford's Waste Treatment and Immobilization Plant may be limited by precipitation/accumulation of spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr)2O4] in the glass discharge riser of Joule-heated ceramic melters during idling. These crystals do not affect glass durability; however, if accumulated in thick layers, they can clog the melter and prevent discharge of molten glass into canisters. To address this problem, an empirical model was developed that can predict thicknesses of accumulated layers as a function of glass composition. This model predicts well the accumulation of single crystals and/or small-scale agglomerates, but excessive agglomeration observed in high-Ni-Fe glass resulted in an underprediction of accumulated layers, which gradually worsened over time as an increased number of agglomerates formed. The accumulation rate of ∼53.8 ± 3.7 μm/h determined for this glass will result in a ∼26 mm-thick layer after 20 days of melter idling.

  13. The chemical durability of glasses suitable for the storage of high level radioactive wastes, (1)

    International Nuclear Information System (INIS)

    Terai, Ryohei; Hara, Shigeo; Kawamoto, Takamichi; Nanbu, Tadahiko; Nakamura, Takao.

    1975-01-01

    To develop the glassy materials suitable for the long-term storage of high level radioactive wastes, the chemical durability of the glasses of borax-alumina-silica system has been investigated. The test was carried out by the following three ways, (1) glass-disk immersion method, (2) continuous leach method and (3) method prescribed in JIS-R3502. In the continuous leach method, glass grains were exposed to circulating water at a constant temperature for a week to obtain the leach factor or leach rate. It was found from the experimental results that, as the silica content increased, the melting temperature of the glasses progressively increased and the chemical durability was considerably improved, and that B 2 O 3 and Na 2 O constituents were preferentially dissolved in water leaving relatively insoluble components such as SiO 2 and Al 2 O 3 . The rate at which B 2 O 3 and Na 2 O in glass are leached out is governed by three processes, that is, (1) the boundary reaction on the glass surface, (2) the diffusion process through the hydrated layer, and (3) the disintegration of hydrated layer. The first process probably corresponds to the hydration of boric oxides on the glass surface or to the ion exchange between protons in solution and Na + ions in glass, and the second process seems to correspond to the diffusion of protons through the hydrated layer on the glass surface. Although the ratio of [Na-BO 4 ]/[BO 3 ] in the borax-silica glasses was determined to be 0.5 by means of NMR measurement, Na 2 O/B 2 O 3 ratio in leached solution was less than 0.5, indicating that [BO 3 ] groups in glass were more soluble than [Na-BO 4 ] groups. From the viewpoint of appreciation of safety, the chemical durability of the glasses of borax-aluminasilica system was rather unsatisfactory, but that of the glasses containing silica in quantities was comparable to the soda-lime silicate sheet glasses. (auth.)

  14. Synthesis of recent investigations on corrosion behaviour of radioactive waste glasses

    International Nuclear Information System (INIS)

    Grauer, R.

    1985-03-01

    By way of a supplement to an earlier report (NTB 83-01, EIR-Report Nr. 477), work which has appeared in the meantime on the corrosion behaviour of borosilicate glasses as a solidification matrix for high-level radioactive waste has been evaluated. Many works have confirmed that for a particular glass, besides temperature and pH-value, the silicate concentration of the solution exerts the strongest influence on corrosion rate. The effect of silicate can be described in terms of simple reaction kinetic models which provides a more sound basis for prediction of longterm behaviour of glasses than previously existed. Meanwhile, the effects of backfill- and canister-materials and their corrosion products have been given the attention they merit. These materials affect glass corrosion primarily through regulation of silicic acid concentration. A particular finding which is of interest is the strong inhibition of glass corrosion by lead ions. Stationary corrosion rates in the order of magnitude of 10 -5 g/cm 2 ·d can be derived from long-term corrosion experiments in stagnant water at 90 C. At the envisaged repository temperature of 55 C they will be one to two orders of magnitude less. The effects of radioactive decay on corrosion rate are either very small or not detectable at all. No further new viewpoints have been put forward with regard to a possible thermal re-structuring of glasses under repository conditions: re-crystallisation (devitrification) is not to be feared. With regard to future experiments, further work on quantification of the effects of canister- and backfill-materials and experiments with corrosion inhibitors would be of primary interest. (author)

  15. An empirical modeling tool and glass property database in development of US-DOE radioactive waste glasses

    International Nuclear Information System (INIS)

    Muller, I.; Gan, H.

    1997-01-01

    An integrated glass database has been developed at the Vitreous State Laboratory of Catholic University of America. The major objective of this tool was to support glass formulation using the MAWS approach (Minimum Additives Waste Stabilization). An empirical modeling capability, based on the properties of over 1000 glasses in the database, was also developed to help formulate glasses from waste streams under multiple user-imposed constraints. The use of this modeling capability, the performance of resulting models in predicting properties of waste glasses, and the correlation of simple structural theories to glass properties are the subjects of this paper. (authors)

  16. Characteristics of borosilicate waste glass form for high-level radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seung Soo; Chun, Kwan Sik; Choi, Jong Won; Kang, Chul Hyung

    2001-03-01

    Basic data, required for the design and the performance assessment of a repository of HLW, suchas the chemical composition and the characteristics of the borosilicate waste glass have been identified according to the burn-ups of spent PWR fuels. The diemnsion of waste canister is 430mm in diameter and 1135mm in length, and the canister should hold less than 2kwatts of heat from their decay of radionuclides contained in the HLW. Based on the reprocessing of 5 years-cooled spent fuel, one canister could hold about 11.5wt.% and 10.8wt.% of oxidized HLW corresponding to their burn-ups of 45,000MWD/MTU and 55,000MWD/MTU, respectively. These waste forms have been recommanded as the reference waste forms of HLW. The characteristics of these wastes as a function of decay time been evaluated. However, after a specific waste form and a specific site for the disposal would be selected, the characteristics of the waste should be reevaluated under the consideration of solidification period, loaded waste, storage condition and duration, site circumstances for the repository system and its performance assessment.

  17. Barium borosilicate glass - a potential matrix for immobilization of sulfate bearing high-level radioactive liquid waste

    International Nuclear Information System (INIS)

    Kaushik, C.P.; Mishra, R.K.; Sengupta, P.; Kumar, Amar; Das, D.; Kale, G.B.; Raj, Kanwar

    2006-01-01

    Borosilicate glass formulations adopted worldwide for immobilization of high-level radioactive liquid waste (HLW) is not suitable for sulphate bearing HLW, because of its low solubility in such glass. A suitable glass matrix based on barium borosilicate has been developed for immobilization of sulphate bearing HLW. Various compositions based on different glass formulations were made to examine compatibility with waste oxide with around 10 wt% sulfate content. The vitrified waste product obtained from barium borosilicate glass matrix was extensively evaluated for its characteristic properties like homogeneity, chemical durability, glass transition temperature, thermal conductivity, impact strength, etc. using appropriate techniques. Process parameters like melt viscosity and pour temperature were also determined. It is found that SB-44 glass composition (SiO 2 : 30.5 wt%, B 2 O 3 : 20.0 wt%, Na 2 O: 9.5 wt% and BaO: 19.0 wt%) can be safely loaded with 21 wt% waste oxide without any phase separation. The other product qualities of SB-44 waste glass are also found to be on a par with internationally adopted waste glass matrices. This formulation has been successfully implemented in plant scale

  18. Glass to contain wastes

    International Nuclear Information System (INIS)

    Moncouyoux, M.; Jacquet-Francillon, M.

    1994-01-01

    Here are the tables and figures presented during the conference on the glass to confine high level radioactive wastes: definition, fabrication, storage and disposal. The composition of glasses are detailed, their properties and the vitrification proceeding. The behaviour of these glasses in front of water, irradiation and heat are shown. The characteristics of parcels are given according to the radiation protection rule, ALARA principle, the concept of multi-barriers and the geological stability

  19. Radioactive Waste.

    Science.gov (United States)

    Blaylock, B. G.

    1978-01-01

    Presents a literature review of radioactive waste disposal, covering publications of 1976-77. Some of the studies included are: (1) high-level and long-lived wastes, and (2) release and burial of low-level wastes. A list of 42 references is also presented. (HM)

  20. Radioactive wastes

    International Nuclear Information System (INIS)

    Devarakonda, M.S.; Melvin, J.M.

    1994-01-01

    This paper is part of the Annual Literature Review issue of Water Environment Research. The review attempts to provide a concise summary of important water-related environmental science and engineering literature of the past year, of which 40 separate topics are discussed. On the topic of radioactive wastes, the present paper deals with the following aspects: national programs; waste repositories; mixed wastes; waste processing and decommissioning; environmental occurrence and transport of radionuclides; and remedial actions and treatment. 178 refs

  1. Turning nuclear waste into glass

    Energy Technology Data Exchange (ETDEWEB)

    Pegg, Ian L.

    2015-02-15

    Vitrification has emerged as the treatment option of choice for the most dangerous radioactive waste. But dealing with the nuclear waste legacy of the Cold War will require state-of-the-art facilities and advanced glass formulations.

  2. Effects of crystallization on thermal properties and chemical durability of the glasses containing simulated high level radioactive wastes

    International Nuclear Information System (INIS)

    Kawamoto, Takamichi; Terai, Ryohei; Hara, Shigeo

    1978-01-01

    In order to improve the thermodynamic stability of the glasses containing high level radioactive wastes, the conversion to glass-ceramics by the heat-treatment was carried out with two kinds of glasses, and the change of thermal properties and chemical durability by crystallization was investigated. One of the glasses has a composition of SiO 2 -Al 2 O 3 -ZnO-TiO 2 system, and another one has a composition which could grow the nephelite crystals from Na 2 O in wastes and Al 2 O 3 and SiO 2 added as glass-forming materials. Transition and yield points shifted to higher temperatures by the conversion and the glass-ceramics were found to be more stable than the original glasses. The glass-ceramics of the composition of SiO 2 -Al 2 O 3 -ZnO-TiO 2 showed poor durability, whereas the chemical durability of the glass-ceramics containing nephelite crystals was considerably improved. In the latter case, improvement of the durability is attributable to that some parts of glass are converted to nephelite crystals and the crystals are more durable than glass under most conditions. (auth.)

  3. Radioactive wastes

    International Nuclear Information System (INIS)

    Dupuis, M.C.

    2007-01-01

    Managing radioactive wastes used to be a peripheral activity for the French atomic energy commission (Cea). Over the past 40 years, it has become a full-fledged phase in the fuel cycle of producing electricity from the atom. In 2005, the national radioactive waste management agency (ANDRA) presented to the government a comprehensive overview of the results drawn from 15 years of research. This landmark report has received recognition beyond France's borders. By broadening this agency's powers, an act of 28 June 2006 acknowledges the progress made and the quality of the results. It also sets an objective for the coming years: work out solutions for managing all forms of radioactive wastes. The possibility of recovering wastes packages from the disposal site must be assured as it was asked by the government in 1998. The next step will be the official demand for the creation of a geological disposal site in 2016

  4. Radioactive waste management

    International Nuclear Information System (INIS)

    2013-01-01

    This eighth chapter presents the radioactive wastes and waste disposal; classification of radioactive wastes; basis requests of the radioactive waste management; conditions for a radioactive waste disposal; registers and inventories; transport of radioactive wastes from a facility to another and the radioactive waste management plan

  5. Disposal of radioactive wastes

    International Nuclear Information System (INIS)

    Dlouhy, Z.

    1982-01-01

    This book provides information on the origin, characteristics and methods of processing of radioactive wastes, as well as the philosophy and practice of their storage and disposal. Chapters are devoted to the following topics: radioactive wastes, characteristics of radioactive wastes, processing liquid and solid radioactive wastes, processing wastes from spent fuel reprocessing, processing gaseous radioactive wastes, fixation of radioactive concentrates, solidification of high-level radioactive wastes, use of radioactive wastes as raw material, radioactive waste disposal, transport of radioactive wastes and economic problems of radioactive wastes disposal. (C.F.)

  6. Demonstration of the Defense Waste Processing Facility vitrification process for Tank 42 radioactive sludge -- Glass preparation and characterization

    International Nuclear Information System (INIS)

    Bibler, N.E.; Fellinger, T.L.; Marshall, K.M.; Crawford, C.L.; Cozzi, A.D.; Edwards, T.B.

    1999-01-01

    The Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) is currently processing and immobilizing the radioactive high level waste sludge at SRS into a durable borosilicate glass for final geological disposal. The DWPF has recently finished processing the first radioactive sludge batch, and is ready for the second batch of radioactive sludge. The second batch is primarily sludge from Tank 42. Before processing this batch in the DWPF, the DWPF process flowsheet has to be demonstrated with a sample of Tank 42 sludge to ensure that an acceptable melter feed and glass can be made. This demonstration was recently completed in the Shielded Cells Facility at SRS. An earlier paper in these proceedings described the sludge composition and processes necessary for producing an acceptable melter fee. This paper describes the preparation and characterization of the glass from that demonstration. Results substantiate that Tank 42 sludge after mixing with the proper amount of glass forming frit (Frit 200) can be processed to make an acceptable glass

  7. The role of ceramics, cement and glass in the immobilization of radioactive wastes

    International Nuclear Information System (INIS)

    Glasser, F.P.

    1985-01-01

    A brief account is given of the constitution and origin of nuclear waste. The immobilization of wastes is discussed: borosilicate glasses are considered as possible matrices; ceramic forms are dealt with in more detail. The principles of the use of ceramics are explained, with examples of different ceramic structures; cements are mentioned as being suitable for wet, medium- to low-active wastes. The effects of radiation on cement, ceramic and glass waste forms are indicated. The account concludes with 'summary and future progress'. (U.K.)

  8. Radioactive waste material disposal

    Science.gov (United States)

    Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

    1995-01-01

    The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide.

  9. Predictive modeling of crystal accumulation in high-level waste glass melters processing radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Matyáš, Josef; Gervasio, Vivianaluxa; Sannoh, Sulaiman E.; Kruger, Albert A.

    2017-11-01

    The effectiveness of HLW vitrification is limited by precipitation/accumulation of spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr)2O4] in the glass discharge riser of Joule-heated ceramic melters during idling. These crystals do not affect glass durability; however, if accumulated in thick layer, they can clog the melter and prevent discharge of molten glass into canisters. To address this problem, an empirical model was developed that can predict thicknesses of accumulated layers as a function of glass composition. This model predicts well the accumulation of single crystals and/or small-scale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ~53.8 ± 3.7 µm/h determined for this glass will result in ~26 mm thick layer in 20 days of melter idling.

  10. Joule-heated glass-furnace system for the incineration of low-level radioactive wastes

    International Nuclear Information System (INIS)

    Armstrong, K.M.; Klingler, L.M.; Doty, J.W.; Kramer, D.P.

    1982-01-01

    For the past 1-1/2 years, Mound has been preparing and evaluating a commercially available joule-heated glass furnace unit, coupled with a wet scrubbing system. The purpose of the glass furnace evaluation is to advance and document incinerator technology for such combustibles as solids, resins, and sludges, and to develop a stable waste form for subsequent disposal. Four (4) waste nonradioactive types were selected to determine the combustion efficiency of the furnace unit: (1) dry solid waste composed of paper, plastics, rubber, and cloth, (2) ion exchange resin of both the anionic and cationic type, (3) filter sludge composed of diatomaceous earth, organic cellulosic filter aid, and powdered ion exchange resin, and (4) cartridge filters having glass and plastic filter surfaces and nonmetallic cores. When completed, the combustion efficiency experiments for the proposed nonradioactive waste-types revealed the ability of the furnace to easily incinerate waste at feedrates of up to 150 lb/hr. During the course of the experiments, combustibles in the offgas remained consistently low, suggesting excellent combustion efficiency. Furthermore, ash produced by the combustion process was effectively incorporated into the melt by convective currents in the glass. Future work on the glass furnace incinerator will include spiking the waste to determine radioisotope behavior in the furnace

  11. Radioactive waste

    International Nuclear Information System (INIS)

    Berkhout, F.

    1991-01-01

    Focusing on radioactive waste management and disposal policies in the United Kingdom, Sweden and the Federal Republic of Germany, this book gives a detailed historical account of the policy process in these three countries, and draws out the implications for theory and public policy. This comparative approach underlines how profoundly different the policy process has been in different countries. By comparing the evolution of policy in three countries, fundamental questions about the formation and resolution of technical decisions under uncertainty are clarified. The analysis of nuclear strategy, the politics of nuclear power, and the shifting emphasis of government regulation redefines the issue of radwaste management and sets it at the heat of the current debate about power, the environment and society. The combination of up-to-date technological assessment with an account of the social and political implications of radwaste management makes'Radioactive Waste'particularly useful to students of environmental studies, geography and public administration. (author)

  12. Radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Berkhout, F

    1991-01-01

    Focusing on radioactive waste management and disposal policies in the United Kingdom, Sweden and the Federal Republic of Germany, this book gives a detailed historical account of the policy process in these three countries, and draws out the implications for theory and public policy. This comparative approach underlines how profoundly different the policy process has been in different countries. By comparing the evolution of policy in three countries, fundamental questions about the formation and resolution of technical decisions under uncertainty are clarified. The analysis of nuclear strategy, the politics of nuclear power, and the shifting emphasis of government regulation redefines the issue of radwaste management and sets it at the heat of the current debate about power, the environment and society. The combination of up-to-date technological assessment with an account of the social and political implications of radwaste management makes'Radioactive Waste'particularly useful to students of environmental studies, geography and public administration. (author).

  13. Comparison of costs for solidification of high-level radioactive waste solutions: glass monoliths vs metal matrices

    International Nuclear Information System (INIS)

    Jardine, L.J.; Carlton, R.E.; Steindler, M.J.

    1981-05-01

    A comparative economic analysis was made of four solidification processes for liquid high-level radioactive waste. Two processes produced borosilicate glass monoliths and two others produced metal matrix composites of lead and borosilicate glass beads and lead and supercalcine pellets. Within the uncertainties of the cost (1979 dollars) estimates, the cost of the four processes was about the same, with the major cost component being the cost of the primary building structure. Equipment costs and operating and maintenance costs formed only a small portion of the building structure costs for all processes

  14. Chemical reactivity of precursor materials during synthesis of glasses used for conditioning high-level radioactive waste: Experiments and models

    International Nuclear Information System (INIS)

    Monteiro, A.

    2012-01-01

    The glass used to store high-level radioactive waste is produced by reaction of a solid waste residue and a glassy precursor (glass frit). The waste residue is first dried and calcined (to lose water and nitrogen respectively), then mixed with the glass frit to enable vitrification at high temperature. In order to obtain a good quality glass of constant composition upon cooling, the chemical reactions between the solid precursors must be complete while in the liquid state, to enable incorporation of the radioactive elements into the glassy matrix. The physical and chemical conditions during glass synthesis (e.g. temperature, relative proportions of frit and calcine, amount of radioactive charge) are typically empirically adjusted to obtain a satisfactory final product. The aim of this work is to provide new insights into the chemical and physical interactions that take place during vitrification and to provide data for a mathematical model that has been developed to simulate the chemical reactions. The consequences of the different chemical reactions that involve solid, liquid and gaseous phases are described (thermal effects, changes in crystal morphology and composition, variations in melt properties and structure). In a first series of experiments, a simplified analogue of the calcine (NaNO 3 -Al 2 O 3 ± MoO 3 /Nd 2 O 3 ) has been studied. In a second series of experiments, the simplified calcines have been reacted with a simplified glass frit (SiO 2 -Na 2 O-B 2 O 3 -Al 2 O 3 ) at high temperature. The results show that crystallization of the calcine may take place before interaction with the glass frit, but that the reactivity with the glass at high temperature is a function of the nature and stoichiometry of the crystalline phases which form at low temperature. The results also highlight how the mixing of the starting materials, the physical properties of the frit (viscosity, glass transition temperature) and the Na 2 O/Al 2 O 3 of the calcine but also its

  15. Glasses and nuclear waste vitrification

    International Nuclear Information System (INIS)

    Ojovan, Michael I.

    2012-01-01

    Glass is an amorphous solid material which behaves like an isotropic crystal. Atomic structure of glass lacks long-range order but possesses short and most probably medium range order. Compared to crystalline materials of the same composition glasses are metastable materials however crystallisation processes are kinetically impeded within times which typically exceed the age of universe. The physical and chemical durability of glasses combined with their high tolerance to compositional changes makes glasses irreplaceable when hazardous waste needs immobilisation for safe long-term storage, transportation and consequent disposal. Immobilisation of radioactive waste in glassy materials using vitrification has been used successfully for several decades. Nuclear waste vitrification is attractive because of its flexibility, the large number of elements which can be incorporated in the glass, its high corrosion durability and the reduced volume of the resulting wasteform. Vitrification involves melting of waste materials with glass-forming additives so that the final vitreous product incorporates the waste contaminants in its macro- and micro-structure. Hazardous waste constituents are immobilised either by direct incorporation into the glass structure or by encapsulation when the final glassy material can be in form of a glass composite material. Both borosilicate and phosphate glasses are currently used to immobilise nuclear wastes. In addition to relatively homogeneous glasses novel glass composite materials are used to immobilise problematic waste streams. (author)

  16. Radioactive wastes

    International Nuclear Information System (INIS)

    Straub, C.P.

    1975-01-01

    A review is presented on the environmental behavior of radioactive wastes. The management of high-level wastes and waste disposal methods were discussed. Some topics included were ore processing, coagulation, absorption and ion exchange, fixation, ground disposal, flotation, evaporation, transmutation and extraterrestrial disposal. Reports were given of the 226 Ra, 224 Ra and tritium activity in hot springs, 90 Sr concentrations in the groundwater and in White Oak Creek, radionuclide content of algae, grasses and plankton, radionuclides in the Danube River, Hudson River, Pacific Ocean, Atlantic Ocean, Lake Michigan, Columbia River and other surface waters. Analysis showed that 239 Pu was scavenged from Lake Michigan water by phytoplankton and algae by a concentration factor of up to 10,000. Benthic invertebrates and fish showed higher 239 Pu concentrations than did their pelagic counterparts. Concentration factors are also given for 234 Th, 60 Co, Fe and Mr in marine organisms. Two models for predicting the impact of radioactivity in the food chain on man were mentioned. In an accidental release from a light-water power reactor to the ocean, the most important radionuclides discharged were found to be 90 Sr, 137 Cs, 239 Pu and activation products 65 Zr, 59 Fe, and 95 Zr

  17. Glasses used in the solidification of high level radioactive waste: their behaviour in aqueous solutions

    International Nuclear Information System (INIS)

    Grauer, R.

    1983-02-01

    Because of their amorphous structure, glasses are particularly suitable matrixes for the solidification of the mixture of radionuclides included in the high level wastes from reactor fuel reprocessing. They are not sensitive to variations in the fractions present of different waste oxides and are resistent to the effects of irradiation. In particular, borosilicate glasses have been investigated for around 25 years and the vitrification techniques have been tested on the technological scale. The environmental conditions within a final waste repository are expected to be such that the chemical resistance of glasses to attack by groundwaters is of special interest. In the present report the corrosion behaviour is described, with emphasis being placed upon the most significant controlling parameters. Since experimental determination of corrosion rates must be done in relatively short-time experiments, the results of which can depend strongly upon the measurement methods employed, it is necessary to carry out a critical assessment of the techniques commonly used in laboratory work. Experimental results are illustrated by means of selected examples. Particular emphasis is placed upon the effects of increased temperatures and of irradiation. The models which have been proposed for the estimation of the long-term corrosion behaviour of glasses are not yet fully sufficient and improvements are required. Furthermore, the actual corrosion rates which are fed into such models must be replaced by values more appropriate for the actual environmental conditions to which the glasses are most likely to be exposed within high level waste repositories. It should be noted, however, that even with current conservative input data on corrosion rates, typical estimated lifetimes for vitrified waste blocks are of the order of 10 5 years. The report concludes with recommendations concerning the most useful areas for further investigations. (author)

  18. Glasses for the solidification of high-level radioactive waste: their behavior in the presence of water

    International Nuclear Information System (INIS)

    Grauer, R.

    1983-02-01

    Because of their amorphous structure, glasses are particularly suitable for the solidification of the mixture of high-level radioactive wastes resulting from reactor fuel reprocessing: they are not sensitive to variations in the compositions of waste oxides and are resistant to the damaging effects of radiation. The borosilicate glasses used for this purpose have been investigated for about 25 years, and waste vitrification techniques have been tested on a commercial scale. In view of possible accidents in a final waste repository, the chemical resistance of this type of glasses to attack by groundwaters is of special interest. The present report deals with the corrosion behaviour of glasses and discusses the most significant controlling parameters. The dissolution rates needed for safety analysis must be determined in relatively short-term experiments. Since the results can depend strongly on the type of test procedures used, a critical assessment of these techniques is necessary. Experimental results are illustrated by means of selected examples. Particular emphasis is placed upon the effects of increased temperatures and of nuclear radiation. The models which have been proposed for the estimation of the long-term behavior of vitrified waste are not yet fully complete and require improvement. Furthermore, the actual dissolution rates which are used in such models should be revised: to be desired are values which take into account the actual environmental conditions at the storage site. It should be noted, however, that even with current conservative input data on corrosion rates, a lifetime on the order of 10 5 years can be expected for the glass blocks to be deposited. The report concludes with recommendations fo further investigations

  19. Disposal of radioactive wastes

    International Nuclear Information System (INIS)

    Blomeke, J.O.

    1979-01-01

    Radioactive waste management and disposal requirements options available are discussed. The possibility of beneficial utilization of radioactive wastes is covered. Methods of interim storage of transuranium wastes are listed. Methods of shipment of low-level and high-level radioactive wastes are presented. Various methods of radioactive waste disposal are discussed

  20. Radioactive Waste Management Strategy

    International Nuclear Information System (INIS)

    2002-01-01

    This strategy defines methods and means how collect, transport and bury radioactive waste safely. It includes low level radiation waste and high level radiation waste. In the strategy are foreseen main principles and ways of storage radioactive waste

  1. PROCESSING OF RADIOACTIVE WASTE

    Science.gov (United States)

    Johnson, B.M. Jr.; Barton, G.B.

    1961-11-14

    A process for treating radioactive waste solutions prior to disposal is described. A water-soluble phosphate, borate, and/or silicate is added. The solution is sprayed with steam into a space heated from 325 to 400 deg C whereby a powder is formed. The powder is melted and calcined at from 800 to 1000 deg C. Water vapor and gaseous products are separated from the glass formed. (AEC)

  2. Standard practices for dissolving glass containing radioactive and mixed waste for chemical and radiochemical analysis

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2000-01-01

    1.1 These practices cover techniques suitable for dissolving glass samples that may contain nuclear wastes. These techniques used together or independently will produce solutions that can be analyzed by inductively coupled plasma atomic emission spectroscopy (ICP-AES), inductively coupled plasma mass spectrometry (ICP-MS), atomic absorption spectrometry (AAS), radiochemical methods and wet chemical techniques for major components, minor components and radionuclides. 1.2 One of the fusion practices and the microwave practice can be used in hot cells and shielded hoods after modification to meet local operational requirements. 1.3 The user of these practices must follow radiation protection guidelines in place for their specific laboratories. 1.4 Additional information relating to safety is included in the text. 1.5 The dissolution techniques described in these practices can be used for quality control of the feed materials and the product of plants vitrifying nuclear waste materials in glass. 1.6 These pr...

  3. Control of high level radioactive waste-glass melters - Part 5: Modeling of complex redox effects

    International Nuclear Information System (INIS)

    Bickford, D.F.; Choi, A.S.

    1991-01-01

    Computerized thermodynamic computations are useful in predicting the sequence and products of redox reactions and in assessing process variations. The redox state of waste-glass melters is determined by balance between the reducing potential of organic compounds in the feed, and the oxidizing potential of gases above the melt, and nitrates and polyvalent elements in the waste. Semiquantitative models predicting limitations of organic content have been developed based on crucible testing. Continuous melter test results have been compared to this improved staged-thermodynamic model of redox behavior

  4. Radionuclide content of simulated and fully radioactive SRLLL waste glasses: comparison of results from ICP-MS, gamma spectrometry and alpha spectrometry

    International Nuclear Information System (INIS)

    Wolf, S.F.; Bates, J.K.

    1995-01-01

    We have measured the transuranic content of two transuranic=doped, simulated waste glasses, using inductively coupled plasma-mass spectrometry (ICP-MS), γ-spectrometry, and α-spectrometry. Average concentrations measured by each technique were within ± 10% of the as-doped concentrations. We also report the transuranic content of three fully radioactive SRL waste glasses that were determined using γ- and α-spectrometry measurements to deconvolute isobaric interferences present in the ICP-MS analyses

  5. Modelling the dissolution of borosilicate glasses for radioactive waste disposal with the PHREEQE/GLASSOL code: theory and practice

    International Nuclear Information System (INIS)

    Curti, E.

    1991-02-01

    A model describing the corrosion kinetics of silicate glasses has been developed by Grambow in recent years. In this report, the theoretical background of the model is thoroughly discussed, and its practical use demonstrated. The main objectives were: 1) to test the validity of the basic assumptions on which the model relies, and 2) to assess whether it can be applied to the safety analysis of a Swiss final repository for high-level radioactive waste. Transition State Theory, a tool based on quantum mechanical principles, has been used by Grambow to derive a general kinetic equation for the corrosion of silicate glasses. This equation predicts successfully the observed dependence of the corrosion rate on the silicic acid concentration in solution according to a first order kinetics law. However, some parameters required by this equation are determined on the base of questionable assumptions. In particular, the simplistic surface complexation model used for the calculation of the free energy of the glass-water reaction yields, for the protonation of silicon on the glass surface, results which are not consistent with the experimental findings. Further, although the model predicts a unique value, common to all silicate glasses, for the activation energy of the rate-determining elementary reaction, leaching experiments conducted on a wide variety of glasses suggest that this quantity may vary by a factor 2. In its present form, the model is judged to be unsuitable for the safety analysis of the Swiss final repository. The reasons include: 1) the model neglects the potential effects of diffusive transport and silica sorption in a bentonite backfill on the glass corrosion kinetics, 2) the release of radionuclides can be only modelled assuming congruent dissolution, and 3) the magnitude of the final rates of corrosion, the parameter defining the maximal lifetime of the glass matrix, is still not known with sufficient precision. (author) figs., tabs., 27 refs

  6. Preparation and characterization of an improved borosilicate glass matrix for the incorporation of high level radioactive waste (HAW). Pt. 1

    International Nuclear Information System (INIS)

    Guber, W.; Hussain, M.; Kahl, L.; Ondracek, G.; Saidl, J.; Dippel, T.

    1979-08-01

    On the basis of laboratory and technical experience with the preparation and the characterization of borosilicate glasses as solidification matrix for high level radioactive waste solution (HAW), a borosilicate glass composition with optimum properties has been developed. Keeping in view the technical and final storage requirements, a number of glass compositions with varying proportions of influential components as Al, Mg, Na were prepared and thoroughly investigated for certain parameters as specific gravity, thermal conductivity, impact resistance, thermal expansion, viscosity, characteristic temperature points, specific heat, evaporation losses from the melt, electrical conductivity, leach resistance, tendency toward recrystallization and second phase formation. All the compositions (some with different amounts of Gd 2 O 3 , an expected neutron poision) contained 15 wt. % simulated HAW oxides. Samples for investigation were fabricated very close to the actual process conditions of vitrification. Two glass products GP12 and GP26 (3.7% Gd 2 O 3 ) have been selected out of 25 glasses as the optimised products for further thorough investigations. Leach resistance, viscosity at 1420 K, tendency towards recrystallization and second phase formation were the most important deciding factors. (orig.) [de

  7. Immersed radioactive wastes

    International Nuclear Information System (INIS)

    2017-03-01

    This document presents a brief overview of immersed radioactive wastes worldwide: historical aspects, geographical localization, type of wastes (liquid, solid), radiological activity of immersed radioactive wastes in the NE Atlantic Ocean, immersion sites and monitoring

  8. Design and operation of small-scale glass melters for immobilizing radioactive waste

    International Nuclear Information System (INIS)

    Plodinec, M.J.; Chismar, P.H.

    1980-01-01

    A small-scale (3-kg), joule-heated, continuous melter has been designed to study vitrification of Savannah River Plant radioactive waste. The first melter built has been in nonradioactive service for nearly three years. This melter had Inconel 690 electrodes and uses Monofrax K-3 for the contact refractory. Several problems seem in this melter have had an impact on the design of a full-scale system. Problems include uncontrolled electric currents passing through the throat, and formation of a slag layer at the bottom of the melter. The performance of a similar melter in a low-maintenance, radioactive environment is also described. Problems such as halide refluxing, and hot streaking, first observed in this melter, are also discussed

  9. Radioactive waste management

    International Nuclear Information System (INIS)

    Kawakami, Yutaka

    2008-01-01

    Radioactive waste generated from utilization of radioisotopes and each step of the nuclear fuel cycle and decommissioning of nuclear facilities are presented. On the safe management of radioactive waste management, international safety standards are established such as ''The Principles of Radioactive Waste Management (IAEA)'' and T he Joint Convention on the Safety of Radioactive Waste Management . Basic steps of radioactive waste management consist of treatment, conditioning and disposal. Disposal is the final step of radioactive waste management and its safety is confirmed by safety assessment in the licensing process. Safety assessment means evaluation of radiation dose rate caused by radioactive materials contained in disposed radioactive waste. The results of the safety assessment are compared with dose limits. The key issues of radioactive waste disposal are establishment of long term national strategies and regulations for safe management of radioactive waste, siting of repository, continuity of management activities and financial bases for long term, and security of human resources. (Author)

  10. Management of radioactive waste

    International Nuclear Information System (INIS)

    Neerdael, B.; Marivoet, J.; Put, M.; Van Iseghem, P.; Volckaert, G.; Wacquier, W.

    1998-09-01

    The document gives an overview of of different aspects of radioactive waste management in Belgium. The document discusses the radioactive waste inventory in Belgium, the treatment and conditioning of radioactive waste as well as activities related to the characterisation of different waste forms. A separate chapter is dedicated to research and development regarding deep geological disposal of radioactive waste. In the Belgian waste management programme, particular emphasis is on studies for disposal in clay. Main results of these studies are highlighted and discussed

  11. Apatite and sodalite based glass-bonded waste forms for immobilization of 129I and mixed halide radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Goel, Ashutosh [Rutgers Univ., New Brunswick, NJ (United States); McCloy, John S. [Washington State Univ., Pullman, WA (United States); Riley, Brian J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Matyas, Josef [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2017-12-30

    The goal of the project was to utilize the knowledge accumulated by the team, in working with minerals for chloride wastes and biological apatites, toward the development of advanced waste forms for immobilizing 129I and mixed-halide wastes. Based on our knowledge, experience, and thorough literature review, we had selected two minerals with different crystal structures and potential for high chemical durability, sodalite and CaP/PbV-apatite, to form the basis of this project. The focus of the proposed effort was towards: (i) low temperature synthesis of proposed minerals (iodine containing sodalite and apatite) leading to the development of monolithic waste forms, (ii) development of a fundamental understanding of the atomic-scale to meso-scale mechanisms of radionuclide incorporation in them, and (iii) understanding of the mechanism of their chemical corrosion, alteration mechanism, and rates. The proposed work was divided into four broad sections. deliverables. 1. Synthesis of materials 2. Materials structural and thermal characterization 3. Design of glass compositions and synthesis glass-bonded minerals, and 4. Chemical durability testing of materials.

  12. Aspects of radioactive waste management

    International Nuclear Information System (INIS)

    Cutoiu, Dan

    2003-01-01

    The origin and types of radioactive waste, the objective and the fundamental principles of radioactive waste management and the classification of radioactive waste are presented. Problems of the radioactive waste management are analyzed. (authors)

  13. Vitrification of hazardous and radioactive wastes

    International Nuclear Information System (INIS)

    Bickford, D.F.; Schumacher, R.

    1995-01-01

    Vitrification offers many attractive waste stabilization options. Versatility of waste compositions, as well as the inherent durability of a glass waste form, have made vitrification the treatment of choice for high-level radioactive wastes. Adapting the technology to other hazardous and radioactive waste streams will provide an environmentally acceptable solution to many of the waste challenges that face the public today. This document reviews various types and technologies involved in vitrification

  14. Transport of radioactive wastes

    International Nuclear Information System (INIS)

    Stuller, C.

    2003-01-01

    In this article author describes the system of transport and processing of radioactive wastes from nuclear power of Slovenske elektrarne, plc. It is realized the assurance of transport of liquid and solid radioactive wastes to processing links from places of their formation, or of preliminary storage and consistent transports of treated radioactive wastes fixed in cement matrix of fibre-concrete container into Rebublic storage of radioactive wastes in Mochovce

  15. Radioactive waste management

    International Nuclear Information System (INIS)

    Balek, V.

    1994-01-01

    This booklet is a publication by International Atomic Energy Agency for general awareness of citizens and policy-makers to clarify their concept of nuclear wastes. In a very simple way it tells what is radioactivity, radiations and radioactive wastes. It further hints on various medial and industrial uses of radiations. It discusses about different types of radioactive wastes and radioactive waste management. Status of nuclear power plants in Central and Eastern European countries are also discussed

  16. Radioactive waste disposal

    International Nuclear Information System (INIS)

    Cluchet, J.; Roger, B.

    1975-10-01

    After mentioning the importance of the problem of the disposal of wastes produced in the electro-nuclear industry, a short reminder on a few laws of radioactivity (nature and energy of radiations, half-life) and on some basic dosimetry is given. The conditioning and storage procedures are then indicated for solid wastes. The more active fractions of liquid wastes are incorporated into blocks of glass, whereas the less active are first concentrated by chemical treatments or by evaporation. The concentrates are then embedded into concrete, asphalt or resins. Storage is done according to the nature of each type of wastes: on a hard-surfaced area or inside concrete-lined trenches for the lowest radioactivity, in pits for the others. Transuranium elements with very long half-lives are buried in very deep natural cavities which can shelter them for centuries. From the investigations conducted so far and from the experience already gained, it can be concluded that safe solutions are within our reach [fr

  17. Elaboration and experimental study of the Borosilicate glass GP 98/12 for the vitrification of the radioactive wastes of KfKarlsruhe Centre (R.F.A.)

    International Nuclear Information System (INIS)

    Ghezal, A.

    1987-09-01

    The transformation into a vitrified block of highly radioactive liquid wastes is actually the best solution for the storage in long run. In West Germany, the research institute in the field of nuclear energy (KfK) has been oriented in this way by developing industrial processes of vitrification and by following studies on the behaviour of the final products. For the fission products, the chosen glasses present good stability characteristics and are used as a first barrier during confinement. Our work, which is part of the research program on radioactive waste vitrification, consists of preparing borosilicate glass GP 98/12 and studying physical and chemical characteristics. We have also contributed to the development and the realization of glass blocks sampling system prepared at pilot scale

  18. Characterization of borosilicate glasses containing simulated high-level radioactive wastes from PNC

    International Nuclear Information System (INIS)

    Terai, R.; Eguchi, K.; Yamanaka, H.

    1979-01-01

    The characterization of borosilicate glasses containing simulated HLW from PNC has been carried out. Phase separation of molybdates, volatilization, viscosity, electrical resistivity, thermal conductivity, elastic modulus, chemical durability, and devitrification of these glasses have been measured, and the suitability of the glasses for the vitrified solidification processes is discussed from the viewpoint of safety

  19. Radioactive wastes and discharges

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    The guide sets out the radiation safety requirements and limits for the treatment of radioactive waste. They shall be observed when discharging radioactive substances into the atmosphere or sewer system, or when delivering solid, low-activity waste to a landfill site without a separate waste treatment plan. The guide does not apply to the radioactive waste resulting from the utilisation of nuclear energy or natural resources.

  20. Radioactive wastes and discharges

    International Nuclear Information System (INIS)

    2000-01-01

    The guide sets out the radiation safety requirements and limits for the treatment of radioactive waste. They shall be observed when discharging radioactive substances into the atmosphere or sewer system, or when delivering solid, low-activity waste to a landfill site without a separate waste treatment plan. The guide does not apply to the radioactive waste resulting from the utilisation of nuclear energy or natural resources

  1. Disposal of radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1960-01-15

    The problem of disposal can be tackled in two ways: the waste can be diluted and dispersed so that the radiation to which any single individual would be subjected would be negligible, or it can be concentrated and permanently isolated from man and his immediate environment. A variety of methods for the discharge of radioactive waste into the ground were described at the Monaco conference. They range from letting liquid effluent run into pits or wells at appropriately chosen sites to the permanent storage of high activity material at great depth in geologically suitable strata. Another method discussed consists in the incorporation of high level fission products in glass which is either buried or stored in vaults. Waste disposal into rivers, harbours, outer continental shelves and the open sea as well as air disposal are also discussed. Many of the experts at the Monaco conference were of the view that most of the proposed, or actually applied, methods of waste disposal were compatible with safety requirements. Some experts, felt that certain of these methods might not be harmless. This applied to the possible hazards of disposal in the sea. There seemed to be general agreement, however, that much additional research was needed to devise more effective and economical methods of disposal and to gain a better knowledge of the effects of various types of disposal operations, particularly in view of the increasing amounts of waste material that will be produced as the nuclear energy industry expands

  2. Radioactive waste processing

    International Nuclear Information System (INIS)

    Dejonghe, P.

    1978-01-01

    This article gives an outline of the present situation, from a Belgian standpoint, in the field of the radioactive wastes processing. It estimates the annual quantity of various radioactive waste produced per 1000 MW(e) PWR installed from the ore mining till reprocessing of irradiated fuels. The methods of treatment concentration, fixation, final storable forms for liquid and solid waste of low activity and for high level activity waste. The storage of radioactive waste and the plutonium-bearing waste treatement are also considered. The estimated quantity of wastes produced for 5450 MW(e) in Belgium and their destination are presented. (A.F.)

  3. Method of processing radioactive wastes

    International Nuclear Information System (INIS)

    Nomura, Ichiro; Hashimoto, Yasuo.

    1984-01-01

    Purpose: To improve the volume-reduction effect, as well as enable simultaneous procession for the wastes such as burnable solid wastes, resin wastes or sludges, and further convert the processed materials into glass-solidified products which are much less burnable and stable chemically and thermally. Method: Auxiliaries mainly composed of SiO 2 such as clays, and wastes such as burnable solid wastes, waste resins and sludges are charged through a waste hopper into an incinerating melting furnace comprising an incinerating and a melting furnace, while radioactive concentrated liquid wastes are sprayed from a spray nozzle. The wastes are burnt by the heat from the melting furnace and combustion air, and the sprayed concentrated wastes are dried by the hot air after the combustion into solid components. The solid matters from the concentrated liquid wastes and the incinerating ashes of the wastes are melted together with the auxiliaries in the melting furnace and converted into glass-like matters. The glass-like matters thus formed are caused to flow into a vessel and gradually cooled to solidify. (Horiuchi, T.)

  4. Technological and organizational aspects of radioactive waste management

    International Nuclear Information System (INIS)

    2005-01-01

    This document comprises collected lecture on radioactive waste management which were given by specialists of the Radioactive Waste Management Section of the IAEA, scientific-industrial enterprise 'Radon' (Moscow, RF) and A.A. Bochvar's GNTs RF VNIINM (Moscow, RF) on various courses, seminars and conferences. These lectures include the following topics: basic principles and national systems of radioactive waste management; radioactive waste sources and their classification; collection, sorting and initial characterization of radioactive wastes; choice of technologies of radioactive waste processing and minimization of wastes; processing and immobilization of organic radioactive wastes; thermal technologies of radioactive waste processing; immobilization of radioactive wastes in cements, asphalts, glass and polymers; management of worked out closed radioactive sources; storage of radioactive wastes; deactivation methods; quality control and assurance in radioactive waste management

  5. Radioactive waste management solutions

    International Nuclear Information System (INIS)

    Siemann, Michael

    2015-01-01

    One of the more frequent questions that arise when discussing nuclear energy's potential contribution to mitigating climate change concerns that of how to manage radioactive waste. Radioactive waste is produced through nuclear power generation, but also - although to a significantly lesser extent - in a variety of other sectors including medicine, agriculture, research, industry and education. The amount, type and physical form of radioactive waste varies considerably. Some forms of radioactive waste, for example, need only be stored for a relatively short period while their radioactivity naturally decays to safe levels. Others remain radioactive for hundreds or even hundreds of thousands of years. Public concerns surrounding radioactive waste are largely related to long-lived high-level radioactive waste. Countries around the world with existing nuclear programmes are developing longer-term plans for final disposal of such waste, with an international consensus developing that the geological disposal of high-level waste (HLW) is the most technically feasible and safe solution. This article provides a brief overview of the different forms of radioactive waste, examines storage and disposal solutions, and briefly explores fuel recycling and stakeholder involvement in radioactive waste management decision making

  6. Geological storage of radioactive waste

    International Nuclear Information System (INIS)

    Barthoux, A.

    1983-01-01

    Certain radioactive waste contains substances which present, although they disappear naturally in a progressive manner, a potential risk which can last for very long periods, of over thousands of years. To ensure a safe long-term handling, provision has been made to bury it deep in stable geological structures which will secure its confinement. Radioactive waste is treated and conditioned to make it insoluble and is then encased in matrices which are to immobilize them. The most radioactive waste is thus incorporated in a matrix of glass which will ensure the insulation of the radioactive substances during the first thousands of years. Beyond that time, the safety will be ensured by the properties of the storage site which must be selected from now on. Various hydrogeological configurations have been identified. They must undergo detailed investigations, including even the creation of an underground laboratory. This document also presents examples of underground storage installations which are due to be built [fr

  7. Decontamination processes for waste glass canisters

    International Nuclear Information System (INIS)

    Rankin, W.N.

    1982-01-01

    A Defense Waste Processing Facility (DWPF) is currently being designed to convert Savannah River Plant liquid, high-level radioactive waste into a solid form, such as borosilicate glass. To prevent the spread of radioactivity, the outside of the canisters of waste glass must have very low levels of smearable radioactive contamination before they are removed from the DWPF. Several techniques were considered for canister decontamination: high-pressure water spray, electropolishing, chemical dissolution, and abrasive blasting. An abrasive blasting technique using a glass frit slurry has been selected for use in the DWPF. No additional equipment is needed to process waste generated from decontamination. Frit used as the abrasive will be mixed with the waste and fed to the glass melter. In contrast, chemical and electrochemical techniques require more space in the DWPF, and produce large amounts of contaminated by-products, which are difficult to immobilize by vitrification

  8. Radioactive Waste Management Basis

    International Nuclear Information System (INIS)

    Perkins, B.K.

    2009-01-01

    The purpose of this Radioactive Waste Management Basis is to describe the systematic approach for planning, executing, and evaluating the management of radioactive waste at LLNL. The implementation of this document will ensure that waste management activities at LLNL are conducted in compliance with the requirements of DOE Order 435.1, Radioactive Waste Management, and the Implementation Guide for DOE Manual 435.1-1, Radioactive Waste Management Manual. Technical justification is provided where methods for meeting the requirements of DOE Order 435.1 deviate from the DOE Manual 435.1-1 and Implementation Guide.

  9. Objectives for radioactive waste packaging

    International Nuclear Information System (INIS)

    Flowers, R.H.

    1982-04-01

    The report falls under the headings: introduction; the nature of radioactive wastes; how to manage radioactive wastes; packaging of radioactive wastes (supervised storage; disposal); waste form evaluation and test requirements (supervised storage; disposal); conclusions. (U.K.)

  10. Understanding radioactive waste

    International Nuclear Information System (INIS)

    Murray, R.L.

    1981-12-01

    This document contains information on all aspects of radioactive wastes. Facts are presented about radioactive wastes simply, clearly and in an unbiased manner which makes the information readily accessible to the interested public. The contents are as follows: questions and concerns about wastes; atoms and chemistry; radioactivity; kinds of radiation; biological effects of radiation; radiation standards and protection; fission and fission products; the Manhattan Project; defense and development; uses of isotopes and radiation; classification of wastes; spent fuels from nuclear reactors; storage of spent fuel; reprocessing, recycling, and resources; uranium mill tailings; low-level wastes; transportation; methods of handling high-level nuclear wastes; project salt vault; multiple barrier approach; research on waste isolation; legal requiremnts; the national waste management program; societal aspects of radioactive wastes; perspectives; glossary; appendix A (scientific American articles); appendix B (reference material on wastes)

  11. Understanding radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Murray, R.L.

    1981-12-01

    This document contains information on all aspects of radioactive wastes. Facts are presented about radioactive wastes simply, clearly and in an unbiased manner which makes the information readily accessible to the interested public. The contents are as follows: questions and concerns about wastes; atoms and chemistry; radioactivity; kinds of radiation; biological effects of radiation; radiation standards and protection; fission and fission products; the Manhattan Project; defense and development; uses of isotopes and radiation; classification of wastes; spent fuels from nuclear reactors; storage of spent fuel; reprocessing, recycling, and resources; uranium mill tailings; low-level wastes; transportation; methods of handling high-level nuclear wastes; project salt vault; multiple barrier approach; research on waste isolation; legal requiremnts; the national waste management program; societal aspects of radioactive wastes; perspectives; glossary; appendix A (scientific American articles); appendix B (reference material on wastes). (ATT)

  12. Mechanical properties of nuclear waste glasses

    International Nuclear Information System (INIS)

    Connelly, A.J.; Hand, R.J.; Bingham, P.A.; Hyatt, N.C.

    2011-01-01

    The mechanical properties of nuclear waste glasses are important as they will determine the degree of cracking that may occur either on cooling or following a handling accident. Recent interest in the vitrification of intermediate level radioactive waste (ILW) as well as high level radioactive waste (HLW) has led to the development of new waste glass compositions that have not previously been characterised. Therefore the mechanical properties, including Young's modulus, Poisson's ratio, hardness, indentation fracture toughness and brittleness of a series of glasses designed to safely incorporate wet ILW have been investigated. The results are presented and compared with the equivalent properties of an inactive simulant of the current UK HLW glass and other nuclear waste glasses from the literature. The higher density glasses tend to have slightly lower hardness and indentation fracture toughness values and slightly higher brittleness values, however, it is shown that the variations in mechanical properties between these different glasses are limited, are well within the range of published values for nuclear waste glasses, and that the surveyed data for all radioactive waste glasses fall within relatively narrow range.

  13. Radioactive wastes. Management

    International Nuclear Information System (INIS)

    Guillaumont, R.

    2001-01-01

    Many documents (journal articles, book chapters, non-conventional documents..) deal with radioactive wastes but very often this topic is covered in a partial way and sometimes the data presented are contradictory. The aim of this article is to precise the definition of radioactive wastes and the proper terms to describe this topic. It describes the main guidelines of the management of radioactive wastes, in particular in France, and presents the problems raised by this activity: 1 - goal and stakes of the management; 2 - definition of a radioactive waste; 3 - radionuclides encountered; 4 - radio-toxicity and radiation risks; 5 - French actors of waste production and management; 6 - French classification and management principles; 7 - wastes origin and characteristics; 8 - status of radioactive wastes in France per categories; 9 - management practices; 10 - packages conditioning and fabrication; 11 - storage of wastes; 12 - the French law from December 30, 1991 and the opportunities of new ways of management; 13 - international situation. (J.S.)

  14. Physical-chemical model for the mechanism of glass corrosion with particular consideration of simulated radioactive waste glasses

    International Nuclear Information System (INIS)

    Grambow, B.

    1985-01-01

    A physical-chemical model for the mechanism of glass corrosion is described. This model can be used for predicting, interpreting, and extrapolating experimental results. In static leaching tests the rate of corrosion generally decreases with time. Some authors assume that the surface layer, which grows during the course of the reaction, protects the underlying glass from further attack by the aqueous phase. Other authors assume that the saturation effects in solution are responsible for reducing the rate of the reaction. It is demonstrated within the scope of this work that examples can be found for both concepts; however, transport processes in the surface layer and/or in solution can be excluded as rate-determining processes within a majority of the examined cases. The location of the corrosion reaction is the boundary surface between the surface layer and the not yet attacked glass (transition zone)

  15. Radioactive Wastes. Revised.

    Science.gov (United States)

    Fox, Charles H.

    This publication is one of a series of information booklets for the general public published by the United States Atomic Energy Commission. This booklet deals with the handling, processing and disposal of radioactive wastes. Among the topics discussed are: The Nature of Radioactive Wastes; Waste Management; and Research and Development. There are…

  16. Radioactive waste management policy

    International Nuclear Information System (INIS)

    Morrison, R.W.

    1983-06-01

    The speaker discusses the development of government policy regarding radioactive waste disposal in Canada, indicates overall policy objectives, and surveys the actual situation with respect to radioactive wastes in Canada. He also looks at the public perceptions of the waste management situation and how they relate to the views of governmental decision makers

  17. Predisposal Radioactive Waste Management

    International Nuclear Information System (INIS)

    2014-01-01

    Recognition of the importance of the safe management of radioactive waste means that, over the years, many well-established and effective techniques have been developed, and the nuclear industry and governments have gained considerable experience in this field. Minimization of waste is a fundamental principle underpinning the design and operation of all nuclear operations, together with waste reuse and recycling. For the remaining radioactive waste that will be produced, it is essential that there is a well defined plan (called a waste treatment path) to ensure the safe management and ultimately the safe disposal of radioactive waste so as to guarantee the sustainable long term deployment of nuclear technologies

  18. Radioactive Waste in Perspective

    International Nuclear Information System (INIS)

    2011-01-01

    Large volumes of hazardous wastes are produced each year, however only a small proportion of them are radioactive. While disposal options for hazardous wastes are generally well established, some types of hazardous waste face issues similar to those for radioactive waste and also require long-term disposal arrangements. The objective of this NEA study is to put the management of radioactive waste into perspective, firstly by contrasting features of radioactive and hazardous wastes, together with their management policies and strategies, and secondly by examining the specific case of the wastes resulting from carbon capture and storage of fossil fuels. The study seeks to give policy makers and interested stakeholders a broad overview of the similarities and differences between radioactive and hazardous wastes and their management strategies. Contents: - Foreword; - Key Points for Policy Makers; - Executive Summary; - Introduction; - Theme 1 - Radioactive and Hazardous Wastes in Perspective; - Theme 2 - The Outlook for Wastes Arising from Coal and from Nuclear Power Generation; - Risk, Perceived Risk and Public Attitudes; - Concluding Discussion and Lessons Learnt; - Strategic Issues for Radioactive Waste; - Strategic Issues for Hazardous Waste; - Case Studies - The Management of Coal Ash, CO 2 and Mercury as Wastes; - Risk and Perceived Risk; - List of Participants; - List of Abbreviations. (authors)

  19. Radioactive waste management in West Germany

    Energy Technology Data Exchange (ETDEWEB)

    Krause, H [Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.)

    1978-01-01

    The technologies developed in West Germany for radioactive waste management are widely reviewed. The first topic in this review paper is the disposal of low- and middle-level radioactive liquid wastes. Almost all these liquid wastes are evaporated, and the typical decontamination factor attained is 10/sup 4/ -- 10/sup 6/. The second topic is the solidification of residuals. Short explanation is given to bituminization and some new processes. The third topic is high-level liquid wastes. Degradation of glass quality due to various radiation is discussed. Embedding of small glass particles containing radioactive wastes into metal is also explained. Disposals of low-level solid wastes and the special wastes produced from reprocessing and mixed oxide fuel fabrication are explained. Final disposal of radioactive wastes in halite is discussed as the last topic. Many photographs are used to illustrate the industrial or experimental use of those management methods.

  20. Natural analogues of nuclear waste glass corrosion

    International Nuclear Information System (INIS)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-01

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses

  1. Natural analogues of nuclear waste glass corrosion.

    Energy Technology Data Exchange (ETDEWEB)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  2. Radioactive waste management

    International Nuclear Information System (INIS)

    2003-01-01

    Almost all IAEA Member States use radioactive sources in medicine, industry, agriculture and scientific research, and countries remain responsible for the safe handling and storage of all radioactively contaminated waste that result from such activities. In some cases, waste must be specially treated or conditioned before storage and/or disposal. The Department of Technical Co-operation is sponsoring a programme with the support of the Nuclear Energy Department aimed at establishing appropriate technologies and procedures for managing radioactive wastes. (IAEA)

  3. Handling of radioactive waste

    International Nuclear Information System (INIS)

    Sanhueza Mir, Azucena

    1998-01-01

    Based on characteristics and quantities of different types of radioactive waste produced in the country, achievements in infrastructure and the way to solve problems related with radioactive waste handling and management, are presented in this paper. Objectives of maintaining facilities and capacities for controlling, processing and storing radioactive waste in a conditioned form, are attained, within a great range of legal framework, so defined to contribute with safety to people and environment (au)

  4. Controlling radioactive waste

    International Nuclear Information System (INIS)

    Wurtinger, W.

    1992-01-01

    The guideline of the Ministry for Environmental Protection for controlling radioactive waste with a negligible development of heat defines in detail what data are relevant to the control of radioactive waste and should be followed up on and included in a system of documentation. By introducing the AVK (product control system for tracing the course of waste disposal) the operators of German nuclear power plants have taken the requirements of this guideline into account. In particular, possibilities for determining the degree of radioactivity of radioactive waste, which the BMU-guidelines call for, were put into practice by means of the programming technology of the product control system's module MOPRO. (orig.) [de

  5. Radioactive mixed waste disposal

    International Nuclear Information System (INIS)

    Jasen, W.G.; Erpenbeck, E.G.

    1993-02-01

    Various types of waste have been generated during the 50-year history of the Hanford Site. Regulatory changes in the last 20 years have provided the emphasis for better management of these wastes. Interpretations of the Atomic Energy Act of 1954 (AEA), the Resource Conservation and Recovery Act of 1976 (RCRA), and the Hazardous and Solid Waste Amendments (HSWA) have led to the definition of radioactive mixed wastes (RMW). The radioactive and hazardous properties of these wastes have resulted in the initiation of special projects for the management of these wastes. Other solid wastes at the Hanford Site include low-level wastes, transuranic (TRU), and nonradioactive hazardous wastes. This paper describes a system for the treatment, storage, and disposal (TSD) of solid radioactive waste

  6. Radioactive waste management

    International Nuclear Information System (INIS)

    1984-07-01

    The purpose of this document is to set out the Government's current strategy for the long term in the management of radioactive wastes. It takes account of the latest developments, and will be subject to review in the light of future developments and studies. The subject is discussed under the headings: what are radioactive wastes; who is responsible; what monitoring takes place; disposal as the objective; low-level wastes; intermediate-level wastes; discharges from Sellafield; heat generating wastes; how will waste management systems and procedures be assessed; how much more waste is there going to be in future; conclusion. (U.K.)

  7. Radioactivity and nuclear waste

    International Nuclear Information System (INIS)

    Saas, A.

    1996-01-01

    Radioactive wastes generated by nuclear activities must be reprocessed using specific treatments before packaging, storage and disposal. This digest paper gives first a classification of radioactive wastes according to their radionuclides content activity and half-life, and the amount of wastes from the different categories generated each year by the different industries. Then, the radiotoxicity of nuclear wastes is evaluated according to the reprocessing treatments used and to their environmental management (surface storage or burial). (J.S.)

  8. Management of Radioactive Wastes

    International Nuclear Information System (INIS)

    Tchokosa, P.

    2010-01-01

    Management of Radioactive Wastes is to protect workers and the public from the radiological risk associated with radioactive waste for the present and future. It application of the principles to the management of waste generated in a radioisotope uses in the industry. Any material that contains or is contaminated with radionuclides at concentrations or radioactivity levels greater than ‘exempt quantities’ established by the competent regulatory authorities and for which no further use is foreseen or intended. Origin of the Radioactive Waste includes Uranium and Thorium mining and milling, nuclear fuel cycle operations, Operation of Nuclear power station, Decontamination and decommissioning of nuclear facilities and Institutional uses of isotopes. There are types of radioactive waste: Low-level Waste (LLW) and High-level Waste. The Management Options for Radioactive Waste Depends on Form, Activity, Concentration and half-lives of the radioactive waste, Storage and disposal methods will vary according to the following; the radionuclides present, and their concentration, and radio toxicity. The contamination results basically from: Contact between radioactive materials and any surface especially during handling. And it may occur in the solid, liquid or gas state. Decontamination is any process that will either reduce or completely remove the amount of radionuclides from a contaminated surface

  9. Radioactive waste management

    International Nuclear Information System (INIS)

    Blomek, D.

    1980-01-01

    The prospects of nuclear power development in the USA up to 2000 and the problems of the fuel cycle high-level radioactive waste processing and storage are considered. The problems of liquid and solidified radioactive waste transportation and their disposal in salt deposits and other geologic formations are discussed. It is pointed out that the main part of the high-level radioactive wastes are produced at spent fuel reprocessing plants in the form of complex aqueous mixtures. These mixtures contain the decay products of about 35 isotopes which are the nuclear fuel fission products, about 18 actinides and their daughter products as well as corrosion products of fuel cans and structural materials and chemical reagents added in the process of fuel reprocessing. The high-level radioactive waste management includes the liquid waste cooling which is necessary for the short and middle living isotope decay, separation of some most dangerous components from the waste mixture, waste solidification, their storage and disposal. The conclusion is drawn that the seccessful solution of the high-level radioactive waste management problem will permit to solve the problem of the fuel cycle radioactive waste management as a whole. The salt deposits, shales and clays are the most suitable for radioactive waste disposal [ru

  10. Radioactive wastes and discharges

    International Nuclear Information System (INIS)

    1993-01-01

    According to the Section 24 of the Finnish Radiation Decree (1512/91), the Finnish Centre for Radiation and Nuclear Safety shall specify the concentration and activity limits and principles for the determination whether a waste can be defined as a radioactive waste or not. The radiation safety requirements and limits for the disposal of radioactive waste are given in the guide. They must be observed when discharging radioactive waste into the atmosphere or sewer system, or when delivering solid low-activity waste to a landfill site without a separate waste disposal plan. The guide does not apply to the radioactive waste resulting from the utilization of nuclear energy of natural resources. (4 refs., 1 tab.)

  11. Functionalized glass beads for the recovery of waste radioactive elements. Final report

    International Nuclear Information System (INIS)

    Geldard, J.F.

    1979-09-01

    Various substituted ethylenediamine tetraacetic acids and their precursors have been prepared and characterized. In addition to containing groups that can chelate metal ions, these substances also contain groups that can be used to bond them to glass beads. Experiments have shown, however, that a large enough number of active sites cannot be achieved by this route. An alternative scheme was devised, whereby trimethoxysilyl groups are incorporated into molecules that have the necessary functional groups. These silyl compounds can be bonded directly to glass beads; the ethylenediamine tetraacetic acid can then be formed in place. The prognosis for this reaction scheme is good, based on the experiments done so far. Stability constants have been measured for some metal ion complexes of the acids mentioned above

  12. Radioactive waste disposal package

    Science.gov (United States)

    Lampe, Robert F.

    1986-11-04

    A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

  13. Understanding radioactive waste

    International Nuclear Information System (INIS)

    Murray, R.L.

    1989-01-01

    This book discusses the sources and health effects of radioactive wastes. It reveals the techniques to concentrate and immobilize radioactivity and examines the merits of various disposal ideas. The book, which is designed for the lay reader, explains the basic science of atoms,nuclear particles,radioactivity, radiation and health effects

  14. ORNL radioactive waste operations

    International Nuclear Information System (INIS)

    Sease, J.D.; King, E.M.; Coobs, J.H.; Row, T.H.

    1982-01-01

    Since its beginning in 1943, ORNL has generated large amounts of solid, liquid, and gaseous radioactive waste material as a by-product of the basic research and development work carried out at the laboratory. The waste system at ORNL has been continually modified and updated to keep pace with the changing release requirements for radioactive wastes. Major upgrading projects are currently in progress. The operating record of ORNL waste operation has been excellent over many years. Recent surveillance of radioactivity in the Oak Ridge environs indicates that atmospheric concentrations of radioactivity were not significantly different from other areas in East Tennesseee. Concentrations of radioactivity in the Clinch River and in fish collected from the river were less than 4% of the permissible concentration and intake guides for individuals in the offsite environment. While some radioactivity was released to the environment from plant operations, the concentrations in all of the media sampled were well below established standards

  15. Radioactive waste treatment

    International Nuclear Information System (INIS)

    Alter, U.

    1988-01-01

    For the Federal Government the safe disposal of waste from nuclear power plants constitutes the precondition for their further operation. The events in the year 1987 about the conditioning and transport of low activity waste and medium activity waste made it clear that it was necessary to intensify state control and to examine the structures in the field of waste disposal. A concept for the control of radioactive waste with negligible heat development (LAW) from nuclear installations is presented. (DG) [de

  16. Waste glass melting stages

    International Nuclear Information System (INIS)

    Anderson, L.D.; Dennis, T.; Elliott, M.L.; Hrma, P.

    1994-01-01

    Three simulated nuclear waste glass feeds, consisting of dried waste and glass frit, were heat treated for 1 hour in a gradient furnace at temperatures ranging from approximately 600 degrees C to 1000 degrees C. Simulated melter feeds from the Hanford Waste Vitrification Plant (HWVP), the Defense Waste Processing Facility (DWPF), and Kernforschungszentru Karlsruhe (KfK) in Germany were used. The samples were thin sectioned and examined by optical microscopy to investigate the stages of the conversion from feed to glass. Various phenomena were seen, such as frit softening, bubble formation, foaming, bubble motion and removal, convective mixing, and homogenization. The behavior of different feeds was similar, although the degree of gas generation and melt homogenization varied. 2 refs., 8 tabs

  17. Waste glass melting stages

    International Nuclear Information System (INIS)

    Anderson, L.D.; Dennis, T.; Elliott, M.L.; Hrma, P.

    1993-04-01

    Three different simulated nuclear waste glass feeds, consisting of dried waste and glass frit, were heat treated for 1 hour in a gradient furnace at temperatures ranging from approximately 600 degrees C--1000 degrees C. Simulated melter feeds from the Hanford Waste Vitrification Plant (HWVP), the Defense Waste Processing Facility (DWPF), and Kernforschungszentrum Karlsruhe (KfK) in Germany were used. The samples were thin-sectioned and examined by optical microscopy to investigate the stages of the conversion from feed to glass. Various phenomena were seen, such as frit softening, bubble formation, foaming, bubble motion and removal, convective mixing, and homogenization. Behavior of different feeds was similar, although the degree of gas generation and melt homogenization varied

  18. Preparation and leaching of radioactive INEL waste forms

    International Nuclear Information System (INIS)

    Schuman, R.P.; Welch, J.M.; Staples, B.A.

    1982-01-01

    The purpose of this study is to prepare and leach test ceramic and glass waste form specimens produced from actual transuranic waste sludges and high-level waste calcines, respectively. Description of wastes, specimen fabrication, leaching procedure, analysis of leachates and results are discussed. The conclusion is that radioactive waste stored at INEL can be readily incorporated in fused ceramic and glass forms. Initial leach testing results indicate that these forms show great promise for safe long-term containment of radioactive wastes

  19. Radioactive waste management

    International Nuclear Information System (INIS)

    Morley, F.

    1980-01-01

    A summary is given of the report of an Expert Group appointed in 1976 to consider the 1959 White Paper 'The Control of Radioactive Wastes' in the light of the changes that have taken place since it was written and with the extended remit of examining 'waste management' rather than the original 'waste disposal'. The Group undertook to; review the categories and quantities present and future of radioactive wastes, recommend the principles for the proper management of these wastes, advise whether any changes in practice or statutory controls are necessary and make recommendations. (UK)

  20. Researching radioactive waste disposal

    International Nuclear Information System (INIS)

    Feates, F.; Keen, N.

    1976-01-01

    At present it is planned to use the vitrification process to convert highly radioactive liquid wastes, arising from nuclear power programme, into glass which will be contained in steel cylinders for storage. The UKAEA in collaboration with other European countries is currently assessing the relative suitability of various natural geological structures as final repositories for the vitrified material. The Institute of Geological Sciences has been commissioned to specify the geological criteria that should be met by a rock structure if it is to be used for the construction of a repository though at this stage disposal sites are not being sought. The current research programme aims to obtain basic geological data about the structure of the rocks well below the surface and is expected to continue for at least three years. The results in all the European countries will then be considered so that the United Kingdom can choose a preferred method for isolating their wastes. It is only at that stage that a firm commitment may be made to select a site for a potential repository, when a far more detailed scientific research study will be instituted. Heat transfer problems and chemical effects which may occur within and around repositories are being investigated and a conceptual design study for an underground repository is being prepared. (U.K.)

  1. Encapsulation of radioactive waste

    International Nuclear Information System (INIS)

    Pordes, O.; Plows, J.P.

    1980-01-01

    A method is described for encapsulating a particular radioactive waste which consists of suspending the waste in a viscous liquid encapsulating material, of synthetic resin monomers or prepolymers, and setting the encapsulating material by addition or condensation polymerization to form a solid material in which the waste is dispersed. (author)

  2. Classification of radioactive waste

    International Nuclear Information System (INIS)

    1994-01-01

    Radioactive wastes are generated in a number of different kinds of facilities and arise in a wide range of concentrations of radioactive materials and in a variety of physical and chemical forms. To simplify their management, a number of schemes have evolved for classifying radioactive waste according to the physical, chemical and radiological properties of significance to those facilities managing this waste. These schemes have led to a variety of terminologies, differing from country to country and even between facilities in the same country. This situation makes it difficult for those concerned to communicate with one another regarding waste management practices. This document revises and updates earlier IAEA references on radioactive waste classification systems given in IAEA Technical Reports Series and Safety Series. Guidance regarding exemption of materials from regulatory control is consistent with IAEA Safety Series and the RADWASS documents published under IAEA Safety Series. 11 refs, 2 figs, 2 tab

  3. Alteration of rhyolitic (volcanic) glasses in natural Bolivian salt lakes. - Natural analogue for the behavior of radioactive waste glasses in rock salt repositories

    International Nuclear Information System (INIS)

    Abdelouas, A.

    1996-06-01

    Alteration experiments with the R7T7 glass in three salt brines, saturated respectively in MgCl 2 , MgCl 2 -CaCl 2 and NaCl, showed that the solubilities of most radionuclides are controlled by the secondary phases. Nd, La, and Pr are trapped in powellite, Ce in cerianite, U in coffinite, and Sr is partially immobilized in barite. There is a good similarity between the secondary phases formed experimentally on volcanic glasses and the R7T7 glass altered in MgCl 2 CaCl 2 -saturated brine (formation of hydrotalcite and chlorite-serpentine at short-term and saponite at long-term). These results support the use of volcanic glasses alteration patterns in Mg-rich solutions (seawater, brines) to understand the long-term behavior of nuclear waste glasses and to evaluate the stability of the secondary phases. The study of the sediments of Uyuni (Bolivia) showed that the corrosion rate of the rhyolitic glass in brines at 10 C is 12 to 30 time lower than those of rhyolitic glasses altered in high dilute conditions. The neoformed phases in the sediments are: Smectite, alunite, pyrite, barite, celestite and cerianite. The low alteration rate of rhyolitic glasses in brines and the formation of secondary phases such as smectite, barite and cerianite (also formed during the experimental alteration of the R7T7 glass), permit us to expect the low alteration of nuclear waste glasses at long-term in brines and the trapping of certain radionuclides in secondary phases. (orig.) [de

  4. Radioactive waste (disposal)

    International Nuclear Information System (INIS)

    Jenkin, P.

    1985-01-01

    The disposal of low- and intermediate-level radioactive wastes was discussed. The following aspects were covered: public consultation on the principles for assessing disposal facilities; procedures for dealing with the possible sites which the Nuclear Industry Radioactive Waste Executive (NIREX) had originally identified; geological investigations to be carried out by NIREX to search for alternative sites; announcement that proposal for a site at Billingham is not to proceed further; NIREX membership; storage of radioactive wastes; public inquiries; social and environmental aspects; safety aspects; interest groups; public relations; government policies. (U.K.)

  5. Heterogeneities in nuclear waste glass

    International Nuclear Information System (INIS)

    Ladirat, Ch.

    1997-01-01

    The industrial vitrification of high level radioactive wastes is a 2 stage process. During the first stage, the concentrated solution is heated in a spinning resistance oven at the temperature of 400 Celsius degrees till evaporation and calcination. The second stage begins when the dry residue falls into a melting pot that is maintained at a temperature of 1100-1150 Celsius degrees. Glass fretting is added and the glass is elaborated through the fusion of the different elements present in the melting pot. Heterogeneities in the glass may be associated to: - the presence in the solution to vitrify of insoluble elements from the dissolution of the fuel (RuO 2 , Rh, Pd), - the presence of minuscule metal scraps (Zr) that have been produced during the cutting of the fuel element, - the failures to conform to the technical specifications of the vitrification process, for instance, temperatures or flow rates when introducing the different elements in the melting pot. (A.C.)

  6. Radioactive wastes of Nuclear Industry

    International Nuclear Information System (INIS)

    1995-01-01

    This conference studies the radioactive waste of nuclear industry. Nine articles and presentations are exposed here; the action of the direction of nuclear installations safety, the improvement of industrial proceedings to reduce the waste volume, the packaging of radioactive waste, the safety of radioactive waste disposal and environmental impact studies, a presentation of waste coming from nuclear power plants, the new waste management policy, the international panorama of radioactive waste management, the international transport of radioactive waste, finally an economic analysis of the treatment and ultimate storage of radioactive waste. (N.C.)

  7. Management of radioactive wastes

    International Nuclear Information System (INIS)

    Hendee, W.R.

    1984-01-01

    The disposal of radioactive wastes is perhaps the most controversial and least understood aspect of the use of nuclear materials in generating electrical power, the investigation of biochemical processes through tracer kinetics, and the diagnosis and treatment of disease. In the siting of nuclear power facilities, the disposal of radioactive wastes is invariably posed as the ultimate unanswerable question. In the fall of 1979, biochemical and physiologic research employing radioactive tracers was threatened with a slowdown resulting from temporary closure of sites for disposal of low-level radioactive wastes (LLW). Radioactive pharmaceuticals used extensively for diagnosis and treatment of human disease have increased dramatically in price, partly as a result of the escalating cost of disposing of radioactive wastes created during production of the labeled pharmaceuticals. These problems have resulted in identification of the disposal of LLW as the most pressing issue in the entire scheme of management of hazardous wastes. How this issue as well as the separate issue of disposal of high-level radioactive wastes (HLW) are being addressed at both national and state levels is the subject of this chapter

  8. Radioactive waste management

    International Nuclear Information System (INIS)

    1992-01-01

    This book highlights the main issues of public concern related to radioactive waste management and puts them into perspective. It provides an overview of radioactive waste management covering, among other themes, policies, implementation and public communication based on national experiences. Its purpose is to assists in increasing the understanding of radioactive waste management issues by public and national authorities, organizations involved in radioactive waste management and the nuclear industry; it may also serve as a source book for those who communicate with the public. Even in the unlikely event that nuclear power does not further develop around the world, the necessity for dealing with nuclear waste from past usages, from uranium mining and milling, decontamination and decommissioning of existing nuclear facilities and from the uses of radioactive materials in medicine, industry and research would still exist. In many countries, radioactive waste management planning involves making effective institutional arrangements in which responsibilities and liabilities are well established for the technical operation and long term surveillance of disposal systems. Financing mechanisms are part of the arrangements. Continuous quality assurance and quality control, at all levels of radioactive waste management, are essential to ensure the required integrity of the system. As with any other human activity, improvements in technology and economics may be possible and secondary problems avoided. Improvements and confirmation of the efficiency of processes and reduction of uncertainties can only be achieved by continued active research, development and demonstration, which are the goals of many national programmes. International co-operation, also in the form of reviews, can contribute to increasing confidence in the ongoing work. The problem of radioactive wastes is not a unique one; it may be compared with other problems of toxic wastes resulting from many other

  9. Final Report for Crucible -Scale Radioactive Vitrification and Product Test of Waste Envelope B (AZ-102) Low-Activity Waste Glass

    International Nuclear Information System (INIS)

    CRAWFORD, CHARLES

    2004-01-01

    A proof-of-technology demonstration for the Hanford River Protection Project (RPP) Waste treatment and Immobilization Plant (WTP) was performed by the Savannah River Technology Center (SRTC). As part of this demonstration, treated AZ-102 Low-Activity Waste supernate was vitrified using a crucible-scale furnace. Initial glass samples were quench-cooled and characterized for metals and radionuclides. The glass was also durability tested using the American Society for Testing and Materials (ASTM) Product Consistency Test (PCT) protocol. These tests used the AZ-102 glass formulation Low Activity Waste (LAW) B88 that targeted AZ-102 waste loading at 5 wt% Na2O. After these initial results were obtained with the quench-cooled LAWB88 glass, a prototypical container centerline cooling (CCC) program was supplied to SRTC by WTP. A portion of the quench-cooled LAWB88 glass was remelted and centerline cooled. Samples from the CCC low-activity AZ-102 glass waste form were durability tested using the PCT and characterized for crystalline phase identification.This final report documents the characterization and durability of this AZ-102 glass

  10. GLASS COMPOSITION-TCLP RESPONSE MODEL FOR WASTE GLASSES

    International Nuclear Information System (INIS)

    Kim, Dong-Sang; Vienna, John D.

    2004-01-01

    A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using data collected from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This paper describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model

  11. Radioactive waste disposal

    International Nuclear Information System (INIS)

    Bohm, H.; Closs, K.D.; Kuhn, K.

    1981-01-01

    The solutions to the technical problem of the disposal of radioactive waste are limited by a) the state of knowledge of reprocessing possibilites, b) public acceptance of the use of those techniques which are known, c) legislative procedures linking licensing of new nuclear power plants to the solution of waste problems, and d) other political constraints. Wastes are generated in the mining and enriching of radioactive elements, and in the operation of nuclear power plants as well as in all fields where radioactive substances may be used. Waste management will depend on the stability and concentration of radioactive materials which must be stored, and a resolution of the tension between numerous small storage sites and a few large ones, which again face problems of public acceptability

  12. Radioactive waste management

    International Nuclear Information System (INIS)

    Syed Abdul Malik Syed Zain

    2005-01-01

    This chapter discussed the basic subjects covered in the radioactive waste management. The subjects are policy and legislation, pre-treatment, classification, segregation, treatment, conditioning, storage, siting and disposal, and quality assurance

  13. The solidification of radioactive waste

    International Nuclear Information System (INIS)

    Nagaya, Kiichi; Fujimoto, Yoshio; Hashimoto, Yasuo; Nomura, Ichiro

    1985-01-01

    A previous paper covered the decomposition and vitrification of Na 2 SO 4 (the primary component of the liquid waste from BWR) with silica. Now, in order to establish an integrated treatment system for the radioactive waste from BWR, this paper examines the effects of combining incinerator ash and other incinerator wastes with radioactive waste on the durability of the final vitrified products. A bench scale test plat consisting of a waiped file evaporator/dryer, a Joule-heated glass melter and SO 2 absorber was therefore put into operation and run safety for a period of 3000 hours. The combination of the radioactive waste with incinerator ash and the secondary waste of the incinerator was found to make no difference on the durability of the final vitrified products effecting no increase or decrease. Durability similar to that displayed in the beaker tests was proven, with the final vitrified products exhibiting a leaching rate less than 3 x 10 -4 g/cm 2 /day at 95 deg C. (author)

  14. Decontamination processes for waste glass canisters

    International Nuclear Information System (INIS)

    Rankin, W.N.

    1981-06-01

    The process which will be used to decontaminate waste glass canisters at the Savannah River Plant consists of: decontamination (slurry blasting); rinse (high-pressure water); and spot decontamination (high-pressure water plus slurry). No additional waste will be produced by this process because glass frit used in decontamination will be mixed with the radioactive waste and fed into the glass melter. Decontamination of waste glass canisters with chemical and abrasive blasting techniques was investigated. The ability of a chemical technique with HNO 3 -HF and H 2 C 2 O 4 to remove baked-on contamination was demonstrated. A correlation between oxide removal and decontamination was observed. Oxide removal and, thus, decontamination by abrasive blasting techniques with glass frit as the abrasive was proposed and demonstrated

  15. Decontamination processes for waste glass canisters

    International Nuclear Information System (INIS)

    Rankin, W.N.

    1981-01-01

    The process which will be used to decontaminate waste glass canisters at the Savannah River Plant consists of: decontamination (slurry blasting); rinse (high-pressure water); and spot decontamination (high-pressure water plus slurry). No additional waste will be produced by this process because glass frit used in decontamination will be mixed with the radioactive waste and fed into the glass melter. Decontamination of waste glass canisters with chemical and abrasive blasting techniques was investigated. The ability of a chemical technique with HNO 3 -HF and H 2 C 2 O 4 to remove baked-on contamination was demonstrated. A correlation between oxide removal and decontamination was observed. Oxide removal and, thus, decontamination by abrasive blasting techniques with glass frit as the abrasive was proposed and demonstrated

  16. K. Radioactive waste management

    International Nuclear Information System (INIS)

    1976-01-01

    Radioactive waste management is a controversial and emotive subject. This report discusses radioactivity hazards which arise from each stage of the fuel cycle and then relates these hazards to the New Zealand situation. There are three appendices, two of which are detailed considerations of a paper by Dr. B.L.Cohen

  17. Effects of alpha radiation on hardness and toughness of the borosilicate glass applied to radioactive wastes immobilization

    International Nuclear Information System (INIS)

    Prado, Miguel Oscar; Bernasconi, Norma B. Messi de; Bevilacqua, Arturo Miguel; Arribere, Maria Angelica; Heredia, Arturo D.; Sanfilippo, Miguel

    1999-01-01

    Borosilicate german glass SG7 samples, obtained by frit sintering, were irradiated with different fluences of thermal neutrons in the nucleus of a nuclear reactor. The nuclear reaction 10 B(n,α) 7 Li, where the 10 B isotope is one of the natural glass components, was used to generate alpha particles throughout the glass volume. The maximum alpha disintegration per unit volume achieved was equivalent to that accumulated in a borosilicate glass with nuclear wastes after 3.8 million years. Through Vickers indentations values for microhardness, stress for 50% fracture probability (Weibull statistics) and estimation of the toughness were obtained as a function of alpha radiation dose. Two counterbalanced effects were found: that due to the disorder created by the alpha particles in the glass and that due to the annealing during irradiation (temperature below 240 deg C). Considering the alpha radiation effect, glasses tend decrease Vickers hardness, and to increase thr 50% fracture probability stress with the dose increase. (author)

  18. Monitoring of radioactive wastes

    International Nuclear Information System (INIS)

    Houriet, J.Ph.

    1982-08-01

    The estimation of risks presented by final disposal of radioactive wastes depends, among other things, on what is known of their radioisotope content. The first aim of this report is to present the current state of possibilities for measuring (monitoring) radionuclides in wastes. The definition of a global monitoring system in the framework of radioactive waste disposal has to be realized, based on the information presented here, in accordance with the results of work to come and on the inventory of wastes to be stored. Designed for direct measurement of unpackaged wastes and for control of wastes ready to be stored, the system would ultimately make it possible to obtain all adaquate information about their radioisotope content with regard to the required disposal safety. The second aim of this report is to outline the definition of such a global system of monitoring. Designed as a workbase and reference source for future work by the National Cooperative for the Storage of Radioactive Waste on the topic of radioactive waste monitoring, this report describes the current situation in this field. It also makes it possible to draw some preliminary conclusions and to make several recommendations. Centered on the possibilities of current and developing techniques, it makes evident that a global monitoring system should be developed. However, it shows that the monitoring of packaged wastes will be difficult, and should be avoided as far as possible, except for control measurements

  19. Radioactive waste management

    International Nuclear Information System (INIS)

    Tang, Y.S.; Saling, J.H.

    1990-01-01

    The purposes of the book are: To create a general awareness of technologies and programs of radioactive waste management. To summarize the current status of such technologies, and to prepare practicing scientists, engineers, administrative personnel, and students for the future demand for a working team in such waste management

  20. Storage of radioactive waste

    International Nuclear Information System (INIS)

    Pittman, F.K.

    1974-01-01

    Four methods for managing radioactive waste in order to protect man from its potential hazards include: transmutation to convert radioisotopes in waste to stable isotopes; disposal in space; geological disposal; and surface storage in shielded, cooled, and monitored containers. A comparison of these methods shows geologic disposal in stable formations beneath landmasses appears to be the most feasible with today's technology. (U.S.)

  1. Radioactive waste management

    International Nuclear Information System (INIS)

    Pahissa Campa, Jaime; Pahissa, Marta H. de

    2000-01-01

    Throughout this century, the application of nuclear energy has produced many benefits, in industry, in research, in medicine, and in the generation of electricity. These activities generate wastes in the same way as do other human activities. The primary objective of radioactive waste management is to protect human health and environment now and in the future without imposing undue burden on future generations, through sound, safe and efficient radioactive waste management. This paper briefly describes the different steps of the management of short lived low and intermediate level wastes, and presents and overview of the state of art in countries involved in nuclear energy, describing their organizations, methodologies used in the processing of these wastes and the final disposal concepts. It also presents the Argentine strategy, its technical and legal aspects. Worldwide experience during the past 50 years has shown that short lived low and intermediate level wastes can be successfully isolated from human and environment in near surface disposal facilities. (author)

  2. Radioactive waste management

    International Nuclear Information System (INIS)

    Tsoulfanidis, N.

    1991-01-01

    The management of radioactive waste is a very important part of the nuclear industry. The future of the nuclear power industry depends to a large extent on the successful solution of the perceived or real problems associated with the disposal of both low-level waste (LLW) and high-level waste (HLW). All the activities surrounding the management of radioactive waste are reviewed. The federal government and the individual states are working toward the implementation of the Nuclear Waste Policy Act and the Low-Level Waste Policy Act. The two congressional acts are reviewed and progress made as of early 1990 is presented. Spent-fuel storage and transportation are discussed in detail as are the concepts of repositories for HLW. The status of state compacts for LLW is also discussed. Finally, activities related to the decommissioning of nuclear facilities are also described

  3. Waste glass weathering

    International Nuclear Information System (INIS)

    Bates, J.K.; Buck, E.C.

    1994-01-01

    The weathering of glass is reviewed by examining processes that affect the reaction of commercial, historical, natural, and nuclear waste glass under conditions of contact with humid air and slowly dripping water, which may lead to immersion in nearly static solution. Radionuclide release data from weathered glass under conditions that may exist in an unsaturated environment are presented and compared to release under standard leaching conditions. While the comparison between the release under weathering and leaching conditions is not exact, due to variability of reaction in humid air, evidence is presented of radionuclide release under a variety of conditions. These results suggest that both the amount and form of radionuclide release can be affected by the weathering of glass

  4. Radioactive wastes management

    International Nuclear Information System (INIS)

    Albert, Ph.

    1999-01-01

    This article presents the French way to deal with nuclear wastes. 4 categories of radioactive wastes have been defined: 1) very low-level wastes (TFA), 2) low or medium-wastes with short or medium half-life (A), 3) low or medium-level wastes with long half-life (B), and 4) high-level wastes with long half-life (C). ANDRA (national agency for the management of radioactive wastes) manages 2 sites of definitive surface storage (La-Manche and Aube centers) for TFA-wastes. The Aube center allows the storage of A-wastes whose half-life is less than 30 years. This site will receive waste packages for 50 years and will require a regular monitoring for 300 years after its decommissioning. No definitive solutions have been taken for B and C wastes, they are temporarily stored at La Hague processing plant. Concerning these wastes the French parliament will have to take a decision by 2006. At this date and within the framework of the Bataille law (1991), scientific studies concerning the definitive or retrievable storage, the processing techniques (like transmutation) will have been achieved and solutions will be proposed. These studies are numerous, long and complex, they involve fresh knowledge in geology, chemistry, physics,.. and they have implied the setting of underground facilities in order to test and validate solutions in situ. This article presents also the transmutation technique. (A.C.)

  5. Radioactive waste management

    International Nuclear Information System (INIS)

    Slansky, C.M.

    1975-01-01

    High-level radioactive waste is produced at Idaho Chemical Processing Plant (ICPP) during the recovery of spent highly enriched nuclear fuels. Liquid waste is stored safely in doubly contained tanks made of steel. The liquid waste is calcined to a solid and stored safely in a retrievable form in doubly contained underground bins. The calcine can be treated further or left untreated in anticipation of ultimate storage. Fluidized bed calcination has been applied to many kinds of high-level waste. The environmental impact of high-level waste management at the ICcP has been negligible and should continue to be negligible. 13 refs

  6. Disposal of radioactive waste

    International Nuclear Information System (INIS)

    Schmude, J.

    1976-01-01

    Speech on the 18th March 1976 in the Bundestag by the parliamentary Secretary of State, Dr. Juergen Schmude, to substantiate the Federal government's draft to a Fourth Act amending the Atomic Energy Act. The draft deals mainly with the final storage of radioactive wastes and interrelated questions concerning waste treatment and waste collection, and with several ordinance empowerments in order to improve licensing and supervisory procedures. (orig./LN) [de

  7. Radioactive waste processing

    International Nuclear Information System (INIS)

    Curtiss, D.H.; Heacock, H.W.

    1976-01-01

    The description is given of a process for treating radioactive waste whereby a mud of radioactive waste and cementing material is formed in a mixer. This mud is then transferred from the mixer to a storage and transport container where it is allowed to harden. To improve transport efficiency an alkali silicate or an alkaline-earth metal silicate is added to the mud. For one hundred parts by weight of radioactive waste in the mud, twenty to one hundred parts by weight of cementing material are added and five to fifty parts by weight of silicate, the amount of waste in the mud exceeding the combined amount of cementing and silicate material [fr

  8. Disposal of Radioactive Waste

    International Nuclear Information System (INIS)

    2011-01-01

    This Safety Requirements publication applies to the disposal of radioactive waste of all types by means of emplacement in designed disposal facilities, subject to the necessary limitations and controls being placed on the disposal of the waste and on the development, operation and closure of facilities. The classification of radioactive waste is discussed. This Safety Requirements publication establishes requirements to provide assurance of the radiation safety of the disposal of radioactive waste, in the operation of a disposal facility and especially after its closure. The fundamental safety objective is to protect people and the environment from harmful effects of ionizing radiation. This is achieved by setting requirements on the site selection and evaluation and design of a disposal facility, and on its construction, operation and closure, including organizational and regulatory requirements.

  9. Security of Radioactive Waste

    International Nuclear Information System (INIS)

    Goldammer, W.

    2003-01-01

    Measures to achieve radioactive waste security are discussed. Categorization of waste in order to implement adequate and consistent security measures based on potential consequences is made. The measures include appropriate treatment/storage/disposal of waste to minimize the potential and consequences of malicious acts; management of waste only within an authorised, regulated, legal framework; management of the security of personnel and information; measures to minimize the acquisition of radioactive waste by those with malicious intent. The specific measures are: deter unauthorized access to the waste; detect any such attempt or any loss or theft of waste; delay unauthorized access; provide timely response to counter any attempt to gain unauthorised access; measures to minimize acts of sabotage; efforts to recover any lost or stolen waste; mitigation and emergency plans in case of release of radioactivity. An approach to develop guidance, starting with the categorisation of sources and identification of dangerous sources, is presented. Dosimetric criteria for internal and external irradiation are set. Different exposure scenarios are considered. Waste categories and security categories based on the IAEA INFCIRC/225/Rev.4 are presented

  10. Method of storing radioactive wastes

    International Nuclear Information System (INIS)

    Adachi, Toshio; Hiratake, Susumu.

    1980-01-01

    Purpose: To reduce the radiation doses externally irradiated from treated radioactive waste and also reduce the separation of radioactive nuclide due to external environmental factors such as air, water or the like. Method: Radioactive waste adhered with radioactive nuclide to solid material is molten to mix and submerge the radioactive nuclide adhered to the surface of the solid material into molten material. Then, the radioactive nuclide thus mixed is solidified to store the waste in solidified state. (Aizawa, K.)

  11. Management on radioactive wastes

    International Nuclear Information System (INIS)

    Balu, K.; Bhatia, S.C.

    1979-01-01

    The basic philosophy governing the radioactive waste management activities in India is to concentrate and contain as much activity as possible and to discharge to the environment only such of these streams that have radioactive content much below the nationally and internationally accepted standards. The concept of ''Zero Release'' is also kept in view. At Tarapur, the effluents are discharged into coastal waters after the radioactivity of the effluents is brought down by a factor 100. The effluents fΩm Rajasthan reactors are discharged into a lake keeping their radioactivity well within permissible limits and a solar evaporation plant is being set up. The plant, when it becomes operational, will be a step towards the concept of ''Zero Release''. At Kalpakkam, the treated wastes are proposed to be diluted by circulating sea water and discharged away from the shore through a long pipe. At Narora, ion exchange followed by chemical precipitation is to be employed to treat effluents and solar evaporation process for total containment. Solid wastes are stored/dispsed in the concrete trenches, underground with the water proofing of external surfaces and the top of the trench is covered with concrete. Highly active wastes are stored/disposed in tile holes which are vaults made of steel-lined, reinforced concrete pipes. Gas cleaning, dilution and dispersion techniques are adopted to treat gaseous radioactive wastes. (M.G.B.)

  12. Fusion reactor radioactive waste management

    International Nuclear Information System (INIS)

    Kaser, J.D.; Postma, A.K.; Bradley, D.J.

    1976-01-01

    Quantities and compositions of non-tritium radioactive waste are estimated for some current conceptual fusion reactor designs, and disposal of large amounts of radioactive waste appears necessary. Although the initial radioactivity of fusion reactor and fission reactor wastes are comparable, the radionuclides in fusion reactor wastes are less hazardous and have shorter half-lives. Areas requiring further research are discussed

  13. Radioactive waste storage issues

    International Nuclear Information System (INIS)

    Kunz, D.E.

    1994-01-01

    In the United States we generate greater than 500 million tons of toxic waste per year which pose a threat to human health and the environment. Some of the most toxic of these wastes are those that are radioactively contaminated. This thesis explores the need for permanent disposal facilities to isolate radioactive waste materials that are being stored temporarily, and therefore potentially unsafely, at generating facilities. Because of current controversies involving the interstate transfer of toxic waste, more states are restricting the flow of wastes into - their borders with the resultant outcome of requiring the management (storage and disposal) of wastes generated solely within a state's boundary to remain there. The purpose of this project is to study nuclear waste storage issues and public perceptions of this important matter. Temporary storage at generating facilities is a cause for safety concerns and underscores, the need for the opening of permanent disposal sites. Political controversies and public concern are forcing states to look within their own borders to find solutions to this difficult problem. Permanent disposal or retrievable storage for radioactive waste may become a necessity in the near future in Colorado. Suitable areas that could support - a nuclear storage/disposal site need to be explored to make certain the health, safety and environment of our citizens now, and that of future generations, will be protected

  14. (Alpha, gamma) irradiation effect on the alteration of high-level radioactive wastes matrices (UO2, hollandite, glass SON68)

    International Nuclear Information System (INIS)

    Suzuki, T.

    2007-06-01

    The aim of this work is to determine the effect of irradiation on the alteration of high level nuclear waste forms matrices. The matrices investigated are UO 2 to simulate the spent fuel, the hollandite for the specific conditioning of Cs, and the inactive glass SON68 representing the nuclear glass R7T7) The alpha irradiation experiments on UO 2 colloids in aqueous carbonate media have enabled to distinguish between the oxidation of UO 2 matrix as initial and dissolution as subsequent step. The simultaneous presence of carbonate and H 2 O 2 (product resulting from water radiolysis) increased the dissolution rate of UO 2 to its maximum value governed by the oxidation rate. ii) The study of hollandite alteration under gamma irradiation confirmed the good retention capacity for Cs and Ba. Gamma irradiation had brought only a little influence on releasing of Cs and Ba in solution. Electronic irradiation had conducted to the amorphization of the hollandite only for a dose 1000 times higher than the auto-induced dose of Ba over millions of years. iii) The experiences of glass irradiation under alpha beam and of helium implantation in the glass SON68 were analyzed by positon annihilation spectroscopy. No effect has been observed on the solid surface for an irradiation dose equal to 1000 years of storage. (author)

  15. Aqueous radioactive waste bituminization

    International Nuclear Information System (INIS)

    Williamson, A.S.

    1980-08-01

    The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container

  16. Radioactive wastes in Oklo

    International Nuclear Information System (INIS)

    Balcazar, M.; Flores R, J.H.; Pena, P.; Lopez, A.

    2006-01-01

    The acceptance of the Nuclear Energy as electric power supply implies to give answer to the population on the two main challenges to conquer in the public opinion: the nuclear accidents and the radioactive wastes. Several of the questions that are made on the radioactive wastes, its are the mobility migration of them, the geologic stability of the place where its are deposited and the possible migration toward the aquifer mantels. Since the half lives of the radioactive waste of a Nuclear Reactor are of several hundred of thousands of years, the technical explanations to the previous questions little convince to the public in general. In this work summary the results of the radioactive waste generated in a natural reactor, denominated Oklo effect that took place in Gabon, Africa, it makes several thousands of millions of years, a lot before the man appeared in the Earth. The identification of at least 17 reactors in Oklo it was carried out thanks to the difference in the concentrations of Uranium 235 and 238 prospective, and to the analysis of the non-mobility of the radioactive waste in the site. It was able by this way to determine that the reactors with sizes of hardly some decimeter and powers of around 100 kilowatts were operating in intermittent and spontaneous form for space of 150,000 years, with operation cycles of around 30 minutes. Recent studies have contributed information valuable on the natural confinement of the radioactive waste of the Oklo reactors in matrixes of minerals of aluminum phosphate that caught and immobilized them for thousands of millions of years. This extracted information from the nature contributes guides and it allows 'to verify' the validity of the current proposals on the immobilization of radioactive wastes of a nuclear reactor. This work presents in clear and accessible form to the public in general on the secure 'design', operation, 'decommissioning' and 'storage' of the radioactive waste of the reactors that the nature put

  17. Radioactive waste processing method

    International Nuclear Information System (INIS)

    Sakuramoto, Naohiko.

    1992-01-01

    When granular materials comprising radioactive wastes containing phosphorus are processed at first in a fluidized bed type furnace, if the granular materials are phosphorus-containing activated carbon, granular materials comprising alkali compound such as calcium hydroxide and barium hydroxide are used as fluidizing media. Even granular materials of slow burning speed can be burnt stably in a fluidizing state by high temperature heat of the fluidizing media, thereby enabling to take a long burning processing time. Accordingly, radioactive activated carbon wastes can be processed by burning treatment. (T.M.)

  18. Radioactive waste processing method

    International Nuclear Information System (INIS)

    Kikuchi, Makoto; Kamiya, Kunio; Yusa, Hideo.

    1976-01-01

    Object: To form radioactive wastes into a pellet-like solid body having high strength. Structure: Liquid waste containing a radioactive material is heated into a powdery body. Granular solid matter such as sand greater in diameter than grain size of the powdery body are mixed into the powdery body, and thereafter the mixture is formed by a granulator into a pellet-like solid body. The thus formed material is introduced into a drum can, into which a thermoplastic material such as asphalt is poured into the can and cooled so that the asphalt is impregnated inside the pellet to obtain a solid having high strength. (Furukawa, Y.)

  19. Radioactive waste processing container

    International Nuclear Information System (INIS)

    Ishizaki, Kanjiro; Koyanagi, Naoaki; Sakamoto, Hiroyuki; Uchida, Ikuo.

    1992-01-01

    A radioactive waste processing container used for processing radioactive wastes into solidification products suitable to disposal such as underground burying or ocean discarding is constituted by using cements. As the cements, calcium sulfoaluminate clinker mainly comprising calcium sulfoaluminate compound; 3CaO 3Al 2 O 3 CaSO 4 , Portland cement and aqueous blast furnace slug is used for instance. Calciumhydroxide formed from the Portland cement is consumed for hydration of the calcium sulfoaluminate clinker. According, calcium hydroxide is substantially eliminated in the cement constituent layer of the container. With such a constitution, damages such as crackings and peelings are less caused, to improve durability and safety. (I.N.)

  20. Radioactive waste containment

    International Nuclear Information System (INIS)

    Beranger, J.-C.

    1978-01-01

    The problem of confining the radioactive wastes produced from the nuclear industry, after the ore concentration stage, is envisaged. These residues being not released into the environment are to be stored. The management policy consists in classifying them in view of adapting to each type of treatment, the suitable conditioning and storage. This classification is made with taking account of the following data: radioactivity (weak, medium or high) nature and lifetime of this radioactivity (transuranians) physical nature and volume. The principles retained are those of volume reduction and shaping into insoluble solids (vitrification) [fr

  1. Prediction of waste glass melt rates

    International Nuclear Information System (INIS)

    Lee, L.

    1987-01-01

    Under contract to the Department of Energy, the Du Pont Company has begun construction of a Defense Waste Processing Facility to immobilize radioactive wastes now stored as liquids at the Department of Energy's Savannah River Plant. The immobilization process solidifies waste sludge by vitrification into a leach-resistant borosilicate glass. Development of this process has been the responsibility of the Savannah River Laboratory. As part of the development, a simple model was developed to predict the melt rates for the waste glass melter. This model is based on an energy balance for the cold cap and gives very good agreement with melt rate data obtained from experimental campaigns in smaller scale waste glass melters

  2. Radioactive waste processing device

    International Nuclear Information System (INIS)

    Seki, Shuji.

    1992-01-01

    Liquid wastes are supplied to a ceramic filter to conduct filtration. In this case, a device for adding a powdery inorganic ion exchanger is disposed to the upstream of the ceramic filter. When the powdery inorganic ion exchanger is charged to the addition device, it is precoated to the surface of the ceramic filter, to conduct separation of suspended matters and separation of ionic nuclides simultaneously. Liquid wastes returned to a collecting tank are condensed while being circulated between the ceramic filter and the tank and then contained in a condensation liquid waste tank. With such a constitution, both of radioactive nuclides accompanied by suspended matters in the radioactive liquid wastes and ionic nuclides can be captured efficiently. (T.M.)

  3. Radioactive waste management

    International Nuclear Information System (INIS)

    Kizawa, Hideo

    1982-01-01

    A system of combining a calciner for concentrated radioactive liquid waste and an incinerator for miscellaneous radioactive solid waste is being developed. Both the calciner and the incinerator are operated by fluidized bed method. The system features the following points: (1) Inflammable miscellaneous solids and concentrated liquid can be treated in combination to reduce the volume. (2) Used ion-exchange resin can be incinerated. (3) The system is applicable even if any final waste disposal method is adopted; calcinated and incinerated solids obtained as intermediate products are easy to handle and store. (4) The system is readily compatible with other waste treatment systems to form optimal total system. The following matters are described: the principle of fluidized-bed furnaces, the objects of treatment, system constitution, the features of the calciner and incinerator, and the current status of development. (J.P.N.)

  4. Disposal of radioactive waste

    International Nuclear Information System (INIS)

    Critchley, R.J.; Swindells, R.J.

    1984-01-01

    A method and apparatus for charging radioactive waste into a disposable steel drum having a plug type lid. The drum is sealed to a waste dispenser and the dispenser closure and lid are withdrawn into the dispenser in back-to-back manner. Before reclosing the dispenser the drum is urged closer to it so that on restoring the dispenser closure to the closed position the lid is pressed into the drum opening

  5. Retention of Halogens in Waste Glass

    Energy Technology Data Exchange (ETDEWEB)

    Hrma, Pavel R.

    2010-05-01

    In spite of their potential roles as melting rate accelerators and foam breakers, halogens are generally viewed as troublesome components for glass processing. Of five halogens, F, Cl, Br, I, and At, all but At may occur in nuclear waste. A nuclear waste feed may contain up to 10 g of F, 4 g of Cl, and ≤100 mg of Br and I per kg of glass. The main concern is halogen volatility, producing hazardous fumes and particulates, and the radioactive iodine 129 isotope of 1.7x10^7-year half life. Because F and Cl are soluble in oxide glasses and tend to precipitate on cooling, they can be retained in the waste glass in the form of dissolved constituents or as dispersed crystalline inclusions. This report compiles known halogen-retention data in both high-level waste (HLW) and low-activity waste (LAW) glasses. Because of its radioactivity, the main focus is on I. Available data on F and Cl were compiled for comparison. Though Br is present in nuclear wastes, it is usually ignored; no data on Br retention were found.

  6. Underground storage of radioactive wastes

    International Nuclear Information System (INIS)

    Dietz, D.N.

    1977-01-01

    An introductory survey of the underground disposal of radioactive wastes is given. Attention is paid to various types of radioactive wastes varying from low to highly active materials, as well as mining techniques and salt deposits

  7. Incineration of radioactive waste

    International Nuclear Information System (INIS)

    Eid, C.

    1985-01-01

    The incineration process currently seems the most appropriate way to solve the problems encountered by the increasing quantities of low and medium active waste from nuclear power generation waste. Although a large number of incinerators operate in the industry, there is still scope for the improvement of safety, throughput capacity and reduction of secondary waste. This seminar intends to give opportunity to scientists working on the different aspects of incineration to present their most salient results and to discuss the possibilities of making headway in the management of LL/ML radioactive waste. These proceedings include 17 contributions ranging over the subjects: incineration of solid β-γ wastes; incineration of other radwastes; measurement and control of wastes; off-gas filtration and release. (orig./G.J.P.)

  8. Radioactive waste management

    International Nuclear Information System (INIS)

    Alfredson, P.G.; Levins, D.M.

    1975-08-01

    Present and future methods of managing radioactive wastes in the nuclear industry are reviewed. In the stages from uranium mining to fuel fabrication, the main purpose of waste management is to limit and control dispersal into the environment of uranium and its decay products, particularly radium and radon. Nuclear reactors produce large amounts of radioactivity but release rates from commercial power reactors have been low and well within legal limits. The principal waste from reprocessing is a high activity liquid containing essentially all the fission products along with the transuranium elements. Most high activity wastes are currently stored as liquids in tanks but there is agreement that future wastes must be converted into solids. Processes to solidify wastes have been demonstrated in pilot plant facilities in the United States and Europe. After solidification, wastes may be stored for some time in man-made structures at or near the Earth's surface. The best method for ultimate disposal appears to be placing solid wastes in a suitable geological formation on land. (author)

  9. REDOX state analysis of platinoid elements in simulated high-level radioactive waste glass by synchrotron radiation based EXAFS

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, Yoshihiro, E-mail: okamoto.yoshihiro@jaea.go.jp [Condensed Matter Chemistry Group, Quantum Beam Science Center, Japan Atomic Energy Agency, Shirakata 2-4, Tokai-mura, Ibaraki 319-1195 (Japan); Shiwaku, Hideaki [Quantum Beam Science Center, Japan Atomic Energy Agency, Kouto 1-1-1, Sayo-cho, Hyogo 679-5143 (Japan); Nakada, Masami [Nuclear Engineering Science Center, Japan Atomic Energy Agency, Shirakata 2-4, Tokai-mura, Ibaraki 319-1195 (Japan); Komamine, Satoshi; Ochi, Eiji [Japan Nuclear Fuel Limited, 4-108 Aza Okitsuke, Oaza Obuchi, Rokkasho-mura, Aomori 030-3212 (Japan); Akabori, Mitsuo [Nuclear Engineering Science Center, Japan Atomic Energy Agency, Shirakata 2-4, Tokai-mura, Ibaraki 319-1195 (Japan)

    2016-04-01

    Extended X-ray Absorption Fine Structure (EXAFS) analyses were performed to evaluate REDOX (REDuction and OXidation) state of platinoid elements in simulated high-level nuclear waste glass samples prepared under different conditions of temperature and atmosphere. At first, EXAFS functions were compared with those of standard materials such as RuO{sub 2}. Then structural parameters were obtained from a curve fitting analysis. In addition, a fitting analysis used a linear combination of the two standard EXAFS functions of a given elements metal and oxide was applied to determine ratio of metal/oxide in the simulated glass. The redox state of Ru was successfully evaluated from the linear combination fitting results of EXAFS functions. The ratio of metal increased at more reducing atmosphere and at higher temperatures. Chemical form of rhodium oxide in the simulated glass samples was RhO{sub 2} unlike expected Rh{sub 2}O{sub 3}. It can be estimated rhodium behaves according with ruthenium when the chemical form is oxide.

  10. Dynamics of radioactive waste generation

    International Nuclear Information System (INIS)

    Dogaru, Daniela; Virtopeanu, Cornelia; Ivan, Alexandrina

    2008-01-01

    In Romania there are in operation three facilities licensed for collection, treatment and storage of radioactive waste resulted from industry, research, medicine, and agriculture, named institutional radioactive waste. The repository, which is of near surface type, is designed for disposing institutional radioactive waste. The institutional radioactive wastes generated are allowed to be disposed into repository according to the waste acceptance criteria, defined for the disposal facility. The radioactive wastes which are not allowed for disposal are stored on the site of each facility which is special authorised for this. The paper describes the dynamics of generation of institutional waste in Romania, both for radioactive waste which are allowed to be disposed into repository and for radioactive waste which are not allowed to be disposed of. (authors)

  11. Radioactive waste management and regulation

    International Nuclear Information System (INIS)

    Willrich, M.

    1976-12-01

    The following conclusions are reached: (1) safe management of post-fission radioactive waste is already a present necessity and an irreversible long-term commitment; (2) basic goals of U.S. radioactive waste policy are unclear; (3) the existing organization for radioactive waste management is likely to be unworkable if left unchanged; and (4) the existing framework for radioactive waste regulation is likely to be ineffective if left unchanged

  12. Radioactive waste processing field

    International Nuclear Information System (INIS)

    Ito, Minoru.

    1993-01-01

    Storing space for radioactive wastes (storage tunnels) are formed underground of the sea bottom along coast. A plurality of boreholes through which sea water flows are pored vertically in a direction intersecting underground streams of brine in the ground between the tunnels and seaside. Sea water introduction pipes are joined to the upper side walls of the boreholes. The sea water introduction pipes have introduction ports protruded under the sea level of the coastal sea area region. Since sea water flows from the introduction ports to the boreholes passing through the sea water introduction pipes, sea water is always filled in the boreholes. Therefore, brine is sufficiently supplied toward the land by sea water from the boreholes, the underground stream of brine is negligibly small. This can prevent radioactive contamination due to flow of the underground water when radioactive wastes are buried in the underground near coast. (I.N.)

  13. Radioactive waste processing device

    International Nuclear Information System (INIS)

    Ikeda, Takashi; Funabashi, Kiyomi; Chino, Koichi.

    1992-01-01

    In a waste processing device for solidifying, pellets formed by condensing radioactive liquid wastes generated from a nuclear power plant, by using a solidification agent, sodium chloride, sodium hydroxide or sodium nitrate is mixed upon solidification. In particular, since sodium sulfate in a resin regenerating liquid wastes absorbs water in the cement upon cement solidification, and increases the volume by expansion, there is a worry of breaking the cement solidification products. This reaction can be prevented by the addition of sodium chloride and the like. Accordingly, integrity of the solidification products can be maintained for a long period of time. (T.M.)

  14. Radioactive waste management glossary

    International Nuclear Information System (INIS)

    1988-01-01

    The Waste Management Glossary defines over 300 terms in the English language that have special meanings when they are used in the context of radioactive waste management. The Glossary is intended to provide a consistent reference for these terms for specialists in this field. It also will assist non-specialists who read IAEA reports dealing with waste management. This is the second edition of the Glossary. It is intended to update and replace its predecessor, TECDOC-264, that was issued in 1982. (author)

  15. Radioactive waste management in Mexico

    International Nuclear Information System (INIS)

    Paredes, L.; Reyes L, J.; Jimenez D, J.

    2000-01-01

    This paper describes the radioactive waste management in Mexico, particularly the activities that the National Institute of Nuclear Research (NINR) is undertaking in this field. Classification and annual generation of radioactive waste, together with practices and facilities relating to the management of radioactive waste are addressed. The respective national legal framework and policy are outlined. (author)

  16. Nuclear waste glass corrosion mechanisms

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    1987-04-01

    Dissolution of nuclear waste glass occurs by corrosion mechanisms similar to those of other solids, e.g., metallurgical and mineralogic systems. Metallurgical phenomena such as active corrosion, passivation and immunity have been observed to be a function of the glass composition and the solution pH. Hydration thermodynamics was used to quantify the role of glass composition and its effect on the solution pH during dissolution. A wide compositional range of natural, lunar, medieval, and nuclear waste glasses, as well as some glass-ceramics were investigated. The factors observed to affect dissolution in deionized water are pertinent to the dissolution of glass in natural environments such as the groundwaters anticipated to interact with nuclear waste glass in a geologic repository. The effects of imposed pH and oxidation potential (Eh) conditions existing in natural environments on glass dissolution is described in the context of Pourbaix diagrams, pH potential diagrams, for glass

  17. Radioactive waste management

    International Nuclear Information System (INIS)

    1982-07-01

    In response to the Sixth Report of the Royal Commission on Environmental Pollution, a White Paper was published in 1977, announcing a number of steps to deal with the problems presented by wastes from the nuclear industry and setting out the position of the then government. The present White paper is in four sections. i. A brief description of the nature of radioactive wastes, and the general objectives of waste management. ii. What has been achieved, the role of the Radioactive Waste Management Advisory Committee, the expansion of research, and the conclusions from the review of existing controls. iii. The present position for each major category of waste, including relevant current action and research, transport and decommissioning. iv. The next steps. Research and development must continue; shallow land burial and the carefully controlled disposal of certain wastes to the sea will continue to play a role; and, for some wastes, new disposal facilities are needed at an early date. For others, the appropriate course of action at the moment is properly controlled storage. New developments are also required in organisation. Throughout, the public must be kept fully informed about what is being done, and there must be proper scope for public discussion. (U.K.)

  18. Radioactive waste management profiles

    International Nuclear Information System (INIS)

    1991-10-01

    In 1989, the International Atomic Energy Agency began development of the Waste Management Data Base (WMDB) to, primarily, establish a mechanism for the collection, integration, storage, and retrieval of information relevant to radioactive waste management in Member States. This report is a summary and compilation of the information contained in the data base. The WMDB contains information and data on several aspects of waste management and offer a ready source of information on such activities as R and D efforts, waste disposal plans and programmes, important programme milestones, waste volume projections, and national and regulatory policies. This report is divided into two parts. Part one describes the Waste Management Data Base system and the type of information it contains. The second part contains data provided by Member States between August 1989 and December 1990 in response to a questionnaire sent by the Agency. However, if a Member State did not respond to the questionnaire, data from IAEA sources, such as technical assistance mission reports, were used - where such data exist. The WMDB system became operational in January 1991. The type of information contained in the data base includes radioactive waste management plans, policies and activities in Member States

  19. Defense radioactive waste management

    International Nuclear Information System (INIS)

    Hindman, T.B. Jr.

    1988-01-01

    The Office of Defense Programs (DP), U.S. Department of Energy, is responsible for the production of nuclear weapons and materials for national defense. Pursuant to this mission, DP operates a large industrial complex that employs over 60,000 people at various installations across the country. As a byproduct of their activities, these installations generate radioactive, hazardous, or mixed wastes that must be managed in a safe and cost-effective manner in compliance with all applicable Federal and STate environmental requirements. At the Federal level such requirements derive primarily from the Atomic Energy Act, the Resource Conservation and Recovery Act (RCRA), the comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the Superfund Amendments and Reauthorization Act (SARA). Responsibility for DP activities in connection with the disposal of defense wastes is consolidated within the Office of Defense Waste and Transportation Management (DWTM). This paper discusses these activities which consist of five principal elements: the environmental restoration of inactive DP facilities and sites, the processing storage and disposal of wastes associated with ongoing operations at active DP facilities, research and development directed toward the long-term disposal of radioactive, hazardous, mixed wastes, technology development directly supporting regulatory compliance, and the development of policies, procedures, and technologies for assuring the safe transportation of radioactive and hazardous materials

  20. Radioactive wastes handling facility

    International Nuclear Information System (INIS)

    Hirose, Emiko; Inaguma, Masahiko; Ozaki, Shigeru; Matsumoto, Kaname.

    1997-01-01

    There are disposed an area where a conveyor is disposed for separating miscellaneous radioactive solid wastes such as metals, on area for operators which is disposed in the direction vertical to the transferring direction of the conveyor, an area for receiving the radioactive wastes and placing them on the conveyor and an area for collecting the radioactive wastes transferred by the conveyor. Since an operator can conduct handling while wearing a working cloth attached to a partition wall as he wears his ordinary cloth, the operation condition can be improved and the efficiency for the separating work can be improved. When the area for settling conveyors and the area for the operators is depressurized, cruds on the surface of the wastes are not released to the outside and the working clothes can be prevented from being involved. Since the wastes are transferred by the conveyor, the operator's moving range is reduced, poisonous materials are fallen and moved through a sliding way to an area for collecting materials to be separated. Accordingly, the materials to be removed can be accumulated easily. (N.H.)

  1. Management of hospital radioactive wastes

    International Nuclear Information System (INIS)

    Mantrana, D.

    1986-01-01

    The general structure of a regulatory scheme for the management of hospital radioactive wastes is presented. The responsabilities of an institution in the radioactive waste management, and storage conditions are defined. The radioactive wastes are classified in physical terms, and the criteria for evaluating the activity of solid wastes are described. The container characteristics and, the types of treatments given to the wastes are specified. (M.C.K.) [pt

  2. Radioactive waste solidification material

    International Nuclear Information System (INIS)

    Nishihara, Yukio; Wakuta, Kuniharu; Ishizaki, Kanjiro; Koyanagi, Naoaki; Sakamoto, Hiroyuki; Uchida, Ikuo.

    1992-01-01

    The present invention concerns a radioactive waste solidification material containing vermiculite cement used for a vacuum packing type waste processing device, which contains no residue of calcium hydroxide in cement solidification products. No residue of calcium hydroxide means, for example, that peak of Ca(OH) 2 is not recognized in an X ray diffraction device. With such procedures, since calcium sulfoaluminate clinker and Portland cement themselves exhibit water hardening property, and slugs exhibit hydration activity from the early stage, the cement exhibits quick-hardening property, has great extension of long term strength, further, has no shrinking property, less dry- shrinkage, excellent durability, less causing damages such as cracks and peeling as processing products of radioactive wastes, enabling to attain highly safe solidification product. (T.M.)

  3. Treatment of radioactive wastes

    International Nuclear Information System (INIS)

    Machida, Chuji

    1976-01-01

    Japan Atomic Energy Research Institute (JAERI) is equipped with such atomic energy facilities as a power test reactor, four research reactors, a hot laboratory, and radioisotope-producing factory. All the radioactive wastes but gas generated from these facilities are treated by the waste treatment facilities established in JAERI. The wastes carried into JAERI through Japan Radioisotope Association are also treated there. Low level water solution is treated with an evaporating apparatus, an ion-exchange apparatus, and a cohesive precipitating apparatus, while medium level solution is treated with an evaporating apparatus, and low level combustible solid is treated with an incinerating apparatus. These treated wastes and sludges are mixed with Portland cement in drum cans to solidify, and stored in a concrete pit. The correct classification and its indication as well as the proper packing for the wastes are earnestly demanded by the treatment facilities. (Kobatake, H.)

  4. Method for solidifying powdery radioactive wastes

    International Nuclear Information System (INIS)

    Yasumura, Keijiro; Matsuura, Hiroyuki; Tomita, Toshihide.

    1978-01-01

    Purpose: To solidify powdery radioactive wastes through polymerization in a vessel at a high impregnation speed with no cloggings in pipes. Method: A drum can is lined with an inner liner layer of a predetermined thickness made of inflammable material such as glass fiber. A plurality of pipes for supplying liquid plastic monomer are provided in adjacent to the upper end face of the inflammable material or inserted between the vessel and the inflammable material. Then powdery radioactive wastes are filled in the vessel and the liquid plastic monomer dissolving therein a polymerization initiator is supplied through the pipes. The liquid plastic monomer impregnates through the inflammable material layer into the radioactive wastes and the plastic monomer is polymerized by the aid of the polymerization initiator after a predetermined of time to produce solidified plastic products of radioactive wastes. (Seki, T.)

  5. Nanoporous Glasses for Nuclear Waste Containment

    Directory of Open Access Journals (Sweden)

    Thierry Woignier

    2016-01-01

    Full Text Available Research is in progress to incorporate nuclear waste in new matrices with high structural stability, resistance to thermal shock, and high chemical durability. Interactions with water are important for materials used as a containment matrix for the radio nuclides. It is indispensable to improve their chemical durability to limit the possible release of radioactive chemical species, if the glass structure is attacked by corrosion. By associating high structural stability and high chemical durability, silica glass optimizes the properties of a suitable host matrix. According to an easy sintering stage, nanoporous glasses such as xerogels, aerogels, and composite gels are alternative ways to synthesize silica glass at relatively low temperatures (≈1,000–1,200°C. Nuclear wastes exist as aqueous salt solutions and we propose using the open pore structure of the nanoporous glass to enable migration of the solution throughout the solid volume. The loaded material is then sintered, thereby trapping the radioactive chemical species. The structure of the sintered materials (glass ceramics is that of nanocomposites: actinide phases (~100 nm embedded in a vitreous silica matrix. Our results showed a large improvement in the chemical durability of glass ceramic over conventional nuclear glass.

  6. International trends of radioactive waste management

    International Nuclear Information System (INIS)

    Luo Shanggeng

    1989-01-01

    The new trends of radioactive waste management in the world such as focusing on decreasing the amount of radioactive wastes, developing decontamination and decommissioning technology, conscientious solution for radiactive waste disposal, carrying out social services of waste treatment and quality assurance are reviewed. Besides, comments and suggestions are presented. Key words Radioactive waste management, Radioactive waste treatment, Radioactive waste disposal

  7. Perspectives concerning radioactive waste management

    International Nuclear Information System (INIS)

    Noynaert, L.

    2013-01-01

    The article presents a general overview of the principles of radioactive waste management as established by the International Atomic Energy Agency. Subsequently, research and development related to radioactive waste management at the Belgian Nuclear Research Center SCK·CEN is discussed. Different topical areas are treated including radioactive waste characterisation, decontamination and the long-term management of radioactive waste. The decommissioning of the BR3 reactor and the construction and the exploitation of the underground research laboratory HADES are cited as examples of the pioneering role that SCK·CEN has played in radioactive waste management.

  8. Radioactive waste computerized management

    International Nuclear Information System (INIS)

    Communaux, M.; Lantes, B.

    1993-01-01

    Since December 31, 1990, the management of the nuclear wastes for all the power stations has been computerized, using the DRA module of the Power Generation and Transmission Group's data processing master plan. So now EDF has a software package which centralizes all the data, enabling it to declare the characteristics of the nuclear wastes which are to be stored on the sites operated by the National Radioactive Waste Management Agency (ANDRA). Among other uses, this application makes it possible for EDF, by real time data exchange with ANDRA, to constitute an inventory of validated, shippable packs. It also constitutes a data base for all the wastes produced on the various sites. This application was developed to meet the following requirements: give the producers of radioactive waste a means to fully manage all the characteristics and materials that are necessary to condition their waste correctly; guarantee the traceability and safety of data and automatically assure the transmission of this data in real time between the producers and the ANDRA; give the Central Services of EDF an operation and statistical tool permitting an experienced feed-back based on the complete national production (single, centralized data base); and integrate the application within the products of the processing master plan in order to assure its maintenance and evolution

  9. Radioactive waste management

    International Nuclear Information System (INIS)

    Strohl, P.

    1985-01-01

    The OECD Nuclear Energy Agency (NEA) attaches considerable importance to its cooperation with Japan. It was said in the annual conference in 1977 that the presentation of the acceptable policy regarding radioactive waste management is the largest single factor for gaining public confidence when nuclear power is adopted with assurance. The risk connected with radioactive wastes was often presented as the major obstacle to the development of nuclear energy, however, an overall impression of optimism and confidence prevailed by the technical appraisal of the situation in this field by the committee of the NEA. This evolution can be easily explained by the significant progress achieved in radioactive waste management both at the technical level and with respect to the implementation of special legislation and the establishment of specialized institutions and financing schemes. More research will focus on the optimization of the technical, safety and economic aspects of specific engineering designs at specific sites on the long term isolation of wastes, and the NEA contributes to this general effort. The implementation of disposal programs is also in progress. (Kako, I.)

  10. Radioactive waste vitrification offgas analysis proposal

    International Nuclear Information System (INIS)

    Nelson, C.W.; Morrey, E.V.

    1993-11-01

    Further validation of the Hanford Waste Vitrification Plant (HWVP) feed simulants will be performed by analyzing offgases during crucible melting of actual waste glasses and simulants. The existing method of vitrifying radioactive laboratory-scale samples will be modified to allow offgas analysis during preparation of glass for product testing. The analysis equipment will include two gas chromatographs (GC) with thermal conductivity detectors (TCD) and one NO/NO x analyzer. This equipment is part of the radioactive formating offgas system. The system will provide real-time analysis of H 2 , O 2 , N 2 , NO, N 2 O, NO 2 , CO, CO 2 , H 2 O, and SO 2 . As with the prior melting method, the product glass will be compatible with durability testing, i.e., Product Consistency Test (PCT) and Material Characterization Center (MCC-1), and crystallinity analysis. Procedures have been included to ensure glass homogeneity and quenching. The radioactive glass will be adaptable to Fe +2 /ΣFe measurement procedures because the atmosphere above the melt can be controlled. The 325 A-hot cell facility is being established as the permanent location for radioactive offgas analysis during formating, and can be easily adapted to crucible melt tests. The total costs necessary to set up and perform offgas measurements on the first radioactive core sample is estimated at $115K. Costs for repeating the test on each additional core sample are estimated to be $60K. The schedule allows for performing the test on the next available core sample

  11. Categorizing operational radioactive wastes

    International Nuclear Information System (INIS)

    2007-04-01

    The primary objective of this publication is to improve communications among waste management professionals and Member States relative to the properties and status of radioactive waste. This is accomplished by providing a standardized approach to operational waste categorization using accepted industry practices and experience. It is a secondary objective to draw a distinction between operational waste categorization and waste disposal classification. The approach set forth herein is applicable to waste generation by mature (major, advanced) nuclear programmes, small-to-medium sized nuclear programmes, and programmes with waste from other nuclear applications. It can be used for planning, developing or revising categorization methodologies. For existing categorization programmes, the approach set forth in this publication may be used as a validation and evaluation tool for assessing communication effectiveness among affected organizations or nations. This publication is intended for use by waste management professionals responsible for creating, implementing or communicating effective categorization, processing and disposal strategies. For the users of this publication, it is important to remember that waste categorization is a communication tool. As such, the operational waste categories are not suitable for regulatory purposes nor for use in health and safety evaluations. Following Section 1 (Introduction) Section 2 of this publication defines categorization and its relationship to existing waste classification and management standards, regulations and practices. It also describes the benefits of a comprehensive categorization programme and fundamental record considerations. Section 3 provides an overview of the categorization process, including primary categories and sub-categories. Sections 4 and 5 outline the specific methodology for categorizing unconditioned and conditioned wastes. Finally, Section 6 provides a brief summary of critical considerations that

  12. Characterization of HLW glass samples Task 3 Characterization of radioactive waste forms a series of final reports (1985-89) No 20

    International Nuclear Information System (INIS)

    Malow, G.; Behrend, U.; Schubert, P.

    1991-01-01

    Due to a delay in the melting of the highly radioactive SON68 glass, a short-term post-investigation of the highly radioactive glass from the Pamela plant in Mol (Belgium) has been carried out, the aim being a check-up of the active LEWC glass SM 513 LW11. The results were compared with those obtained for non-radioactive glass samples. The final report of the present CEC programme shortly describes the planned investigations of the glass R7T7 for the whole period of the research contract and the results of the short-term post-investigation of the Pamela glass. 11 refs.; 9 figs.; 4 tabs

  13. Chapter 7. Radioactive wastes

    International Nuclear Information System (INIS)

    2000-01-01

    The inspection and assessment activities of Nuclear Regulatory Authority of the Slovak Republic (UJD) focused on minimization of activity and the quantity of produced radioactive waste (RAW), and on increasing safety of waste management. The general scheme of rad-waste management in the Slovak Republic is presented. The radioactive wastes produced during the operation of NPP V-1, NPP V-2 and NPP Mochovce in 1999 are listed.Liquid RAW was treated and conditioned into a solid form at the nuclear facility Technology for treatment and conditioning of RAW. In 1999 combustible solid waste was treated at the nuclear facility Incinerator of VUJE Trnava. Produced liquid and solid RAW are stored at designed equipment at individual nuclear installations (in case of NPP V-1, NPP V-2 Bohunice and NPP Mochovce in compliance with the Regulation No. 67/1987 Coll. law).The status of free capacity of these storages as of 31.121999 is presented. Storage solidified product built the SE-VYZ was fully filled at the end of 1999. In 1999 there was a significant improvement in the process of radioactive waste management by: (A) issuing approval for commissioning the National Repository for RAW, (B) issuing approval for commissioning the Treatment and Conditioning Center for RAW, (C) having the application for approval to transport conditioned RAW to the National repository Mochovce in the final stage of evaluation. At the beginning of 2000 it is realistic to expect that RAW conditioned in the Conditioning center of RAW will start to be disposed at the National repository of RAW in Mochovce

  14. Radioactive wastes eliminating device

    International Nuclear Information System (INIS)

    Mitsutsuka, Norimasa.

    1979-01-01

    Purpose: To eliminate impurities and radioactive wastes by passing liquid sodium in a cold trap and an adsorption device. Constitution: Heated sodium is partially extracted from the core of a nuclear reactor by way of a pump, flown into and cooled in heat exchangers and then introduced into a cold trap for removal of impurities. The liquid sodium eliminated with impurities is introduced into an adsorption separator and purified by the elimination of radioactive wastes. The purified sodium is returned to the nuclear reactor. A heater is provided between the cold trap and the adsorption separator, so that the temperature of the liquid sodium introduced into the adsorption separator is not lower than the minimum temperature in the cold trap to thereby prevent deposition of impurities in the adsorption separator. (Kawakami, Y.)

  15. Radioactive wastes - inventories and classification

    International Nuclear Information System (INIS)

    Brennecke, P.; Hollmann, A.

    1992-01-01

    A survey is given of the origins, types, conditioning, inventories, and expected abundance of radioactive wastes in the future in the Federal Republic of Germany. The Federal Government's radioactive waste disposal scheme provides that radioactive wastes be buried in deep geological formations which are expected to ensure a maintenance-free, unlimited and safe disposal without intentional excavation of the wastes at a later date. (orig./BBR) [de

  16. Disposal of radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1960-11-15

    A discussion on the disposal of radioactive wastes was held in Vienna on 20 September 1960. The three scientists who participated in the discussion were Mr. Harry Brynielsson (Sweden), Head of the Swedish Atomic Energy Company; Mr. H. J. Dunster (United Kingdom), Health Physics Adviser to the United Kingdom Atomic Energy Authority; and Mr. Leslie Silverman (United States), Professor of Harvard University, and Chairman of the US AEC Advisory Committee on Reactor Safeguards, as well as consultant on air cleaning

  17. Radioactive waste management glossary

    International Nuclear Information System (INIS)

    1982-04-01

    Terminology used in documents published by the IAEA is frequently defined in glossaries in the separate documents so that understanding is enhanced, particularly for terms having unique meanings in the field of radioactive waste management. This has been found to be a good practice but frequently a burdensome one, too. In addition, terms in various documents occasionally were used differently. Thus, a common glossary of terms for radioactive waste management documents is believed to have merit. This glossary has been developed for use in IAEA documentation on radioactive waste management topics. The individual items have been compiled by selecting terms and definitions from thirty sources, listed on the next page, and numerous people. An effort has been made to use the definitions in internationally-accepted glossaries (e.g. ICRP, ICRU, ISO), with minimum modification; similarly, definitions in recently published IAEA documents have been respected. Nevertheless, when modifications were believed appropriate, they have been made. The glossary, stored on magnetic tape, is intended to be used as a standard for terminology for IAEA use; it is hoped that some benefits of common international terminology may result from its use in IAEA documentation

  18. Radioactive waste equivalence

    International Nuclear Information System (INIS)

    Orlowski, S.; Schaller, K.H.

    1990-01-01

    The report reviews, for the Member States of the European Community, possible situations in which an equivalence concept for radioactive waste may be used, analyses the various factors involved, and suggests guidelines for the implementation of such a concept. Only safety and technical aspects are covered. Other aspects such as commercial ones are excluded. Situations where the need for an equivalence concept has been identified are processes where impurities are added as a consequence of the treatment and conditioning process, the substitution of wastes from similar waste streams due to the treatment process, and exchange of waste belonging to different waste categories. The analysis of factors involved and possible ways for equivalence evaluation, taking into account in particular the chemical, physical and radiological characteristics of the waste package, and the potential risks of the waste form, shows that no simple all-encompassing equivalence formula may be derived. Consequently, a step-by-step approach is suggested, which avoids complex evaluations in the case of simple exchanges

  19. Argentina's radioactive waste disposal policy

    International Nuclear Information System (INIS)

    Palacios, E.

    1986-01-01

    The Argentina policy for radioactive waste disposal from nuclear facilities is presented. The radioactive wastes are treated and disposed in confinement systems which ensure the isolation of the radionucles for an appropriate period. The safety criteria adopted by Argentina Authorities in case of the release of radioactive materials under normal conditions and in case of accidents are analysed. (M.C.K.) [pt

  20. Thermal Predictions of the Cooling of Waste Glass Canisters

    Energy Technology Data Exchange (ETDEWEB)

    Donna Post Guillen

    2014-11-01

    Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

  1. Radioactive waste management and regulation

    International Nuclear Information System (INIS)

    Willrich, M.; Lester, R.K.; Greenberg, S.C.; Mitchell, H.C.; Walker, D.A.

    1977-01-01

    Purpose of this book is to assist in developing public policy and institutions for the safe management of radioactive waste, currently and long term. Both high-level waste and low-level waste containing transuranium elements are covered. The following conclusions are drawn: the safe management of post-fission radioactive waste is already a present necessity and an irreversible long-term commitment; the basic goals of U.S. radioactive waste policy are unclear; the existing organization for radioactive waste management is likely to be unworkable if left unchanged; and the existing framework for radioactive waste regulation is likely to be ineffective if left unchanged. The following recommendations are made: a national Radioactive Waste Authority should be established as a federally chartered public corporation; with NRC as the primary agency, a comprehensive regulatory framework should be established to assure the safety of all radioactive waste management operations under U.S. jurisdiction or control; ERDA should continue to have primary government responsibility for R and D and demonstration of radioactive waste technology; and the U.S. government should propose that an international Radioactive Waste Commission be established under the IAEA

  2. Decontamination of Savannah River Plant waste glass canisters

    International Nuclear Information System (INIS)

    Rankin, W.N.

    1982-01-01

    A Defense Waste Processing Facility (DWPF) is currently being designed to convert Savannah River Plant (SRP) liquid, high-level radioactive waste into a solid form, such as borosilicate glass. The outside of the canisters of waste glass must have very low levels of smearable radioactive contamination before they are removed from the DWPF to prevent the spread of radioactivity. Several techniques were considered for canister decontamination: high-pressure water spray, electropolishing, chemical dissolution, and abrasive blasting. An abrasive blasting technique using a glass frit slurry has been selected for use in the DWPF. No additional equipment is needed to process waste generated from decontamination. Frit used as the abrasive will be mixed with the waste and fed to the glass melter. In contrast, chemical and electrochemical techniques require more space in the DWPF, and produce large amounts of contaminated byproducts which are difficult to immobilize by vitrification

  3. Storage of radioactive wastes

    International Nuclear Information System (INIS)

    1992-07-01

    Even if the best waste minimization measures are undertaken throughout radioisotope production or usage, significant radioactive wastes arise to make management measures essential. For developing countries with low isotope usage and little or no generation of nuclear materials, it may be possible to handle the generated waste by simply practicing decay storage for several half-lives of the radionuclides involved, followed by discharge or disposal without further processing. For those countries with much larger facilities, longer lived isotopes are produced and used. In this situation, storage is used not only for decay storage but also for in-process retention steps and for the key stage of interim storage of conditioned wastes pending final disposal. The report will serve as a technical manual providing reference material and direct step-by-step know-how to staff in radioisotope user establishments and research centres in the developing Member States without nuclear power generation. Considerations are limited to the simpler storage facilities. The restricted quantities and low activity associated with the relevant wastes will generally permit contact-handling and avoid the need for shielding requirements in the storage facilities or equipment used for handling. A small quantity of wastes from some radioisotope production cells and from reactor cooling water treatment may contain sufficient short lived activity from activated corrosion products to require some separate decay storage before contact-handling is suitable. 16 refs, 12 figs, 8 tabs

  4. Radioactive liquid waste filtering device

    International Nuclear Information System (INIS)

    Inami, Ichiro; Tabata, Masayuki; Kubo, Koji.

    1988-01-01

    Purpose: To prevent clogging in filter materials and improve the filtration performance for radioactive liquid wastes without increasing the amount of radioactive wastes. Constitution: In a radioactive waste filtering device, a liquid waste recycling pipe and a liquid recycling pump are disposed for recycling the radioactive liquid wastes in a liquid wastes vessel. In this case, the recycling pipe and the recycling pump are properly selected so as to satisfy the conditions capable of making the radioactive liquid wastes flowing through the pipe to have the Reynolds number of 10 4 - 10 5 . By repeating the transportation of radioactive liquid wastes in the liquid waste vessel through the liquid waste recycling pipe by the liquid waste recycling pump and then returning them to the liquid waste vessel again, particles of fine grain size in the suspended liquids are coagulated with each other upon collision to increase the grain size of the suspended particles. In this way, clogging of the filter materials caused by the particles of fine grain size can be prevented, thereby enabling to prevent the increase in the rising rate of the filtration differential pressure, reduce the frequency for the occurrence of radioactive wastes such as filter sludges and improve the processing performance. (Kamimura, M.)

  5. radioactive waste disposal standards abroad

    International Nuclear Information System (INIS)

    Lu Yan; Xin Pingping; Wu Jian; Zhang Xue

    2012-01-01

    With the world focus on human health and environmental protection, the problem of radioactive waste disposal has gradually become a global issue, and the focus of attention of public. The safety of radioactive waste disposal, is not only related to human health and environmental safety, but also an important factor of affecting the sustainable development of nuclear energy. In recent years the formulation of the radioactive waste disposal standards has been generally paid attention to at home and abroad, and it has made great progress. In China, radioactive waste management standards are being improved, and there are many new standards need to be developed. The revised task of implement standards is very arduous, and there are many areas for improvement about methods and procedures of the preparation of standards. This paper studies the current situation of radioactive waste disposal standards of the International Atomic Energy Agency, USA, France, Britain, Russia, Japan, and give some corresponding recommendations of our radioactive waste disposal standards. (authors)

  6. Disposal facility for radioactive wastes

    International Nuclear Information System (INIS)

    Utsunomiya, Toru.

    1985-01-01

    Purpose: To remove heat generated from radioactive wastes thereby prevent the working circumstances from being worsened in a disposal-facility for radioactive wastes. Constitution: The disposal-facility comprises a plurality of holes dug out into the ground inside a tunnel excavated for the storage of radioactive wastes. After placing radioactive wastes into the shafts, re-filling materials are directly filled with a purpose of reducing the dosage. Further, a plurality of heat pipes are inserted into the holes and embedded within the re-filling materials so as to gather heat from the radioactive wastes. The heat pipes are connected to a heat exchanger disposed within the tunnel. As a result, heating of the solidified radioactive wastes itself or the containing vessel to high temperature can be avoided, as well as thermal degradation of the re-filling materials and the worsening in the working circumstance within the tunnel can be overcome. (Moriyama, K.)

  7. Measurements of natural radioactivity in historical glasses

    International Nuclear Information System (INIS)

    Kierzek, J.; Kunicki-Goldfinger, J.J.; Kasprzak, A.J.

    2000-01-01

    Natural radioactive components of historical glasses and two methods of the respective measurement of the radioactivity are discussed. The evaluation of radioactivity of glass objects using a Geiger-Mueller counter and high-resolution gamma ray spectrometry is presented. A survey of the Warsaw National Museum glass collection with a Geiger-Mueller counter allowed distinguishing the vessels made of potassium and sodium glass by their level of natural radioactivity. Gamma spectrometry, on the other hand, enables estimating a specific radionuclide content. Special attention is given to uranium glasses. One 19th century Bohemian vessel, coloured with a uranium compound, was carefully examined using gamma spectrometry. K 2 O and U content were estimated to be 16.2 and 0.33%, respectively. (orig.)

  8. Evolution in radioactive waste countermeasures

    International Nuclear Information System (INIS)

    Moriguchi, Yasutaka

    1984-01-01

    The establishment of radioactive waste management measures is important to proceed further with nuclear power development. While the storage facility projects by utilities are in progress, large quantity of low level wastes are expected to arise in the future due to the decommissioning of nuclear reactors, etc. An interim report made by the committee on radioactive waste countermeasures to the Atomic Energy Commission is described as follows: the land disposal measures of ultra-low level and low level radioactive wastes, that is, the concept of level partitioning, waste management, the possible practice of handling wastes, etc.; the treatment and disposal measures of high level radioactive wastes and transuranium wastes, including task sharing among respective research institutions, the solidification/storage and the geological formation disposal of high level wastes, etc. (Mori, K.)

  9. The transport of radioactive waste

    International Nuclear Information System (INIS)

    Appleton, P.R.; Poulter, D.R.

    1989-01-01

    Regulations have been developed to ensure the safe transport of all radioactive materials by all modes (road, rail, sea and air). There are no features of radioactive waste which set it aside from other radioactive materials for transport, and the same regulations control all radioactive material transport. These regulations and their underlying basis are described in this paper, and their application to waste transport is outlined. (author)

  10. Radioactive waste in Federal Germany

    International Nuclear Information System (INIS)

    Brennecke, P.; Schumacher, J.; Warnecke, E.

    1988-01-01

    The Physikalisch-Technische Bundesanstalt (PTB) is responsible for the long-term storage and disposal of radioactive waste according to the Federal Atomic Energy Act. On behalf of the Federal Minister of the Environment, Nature Conservation and Nuclear Safety, since 1985, the PTB has been carrying out annual inquiries into the amounts of radioactive waste produced in the Federal Republic of Germany. Within the scope of this inquiry performed for the preceding year, the amounts of unconditioned and conditioned waste are compiled on a producer- and plant-specific basis. On the basis of the inquiry for 1986 and of data presented to the PTB by the waste producers, future amounts of radioactive waste have been estimated up to the year 2000. The result of this forecast is presented. In the Federal Republic of Germany two sites are under consideration for disposal of radioactive waste. In the abandoned Konrad iron mine in Salzgitter-Bleckenstedt it is intended to dispose of such radioactive waste which has a negligible thermal influence upon the host rock. The Gorleben salt dome is being investigated for its suitability for the disposal of all kinds of solid and solidified radioactive wastes, especially of heat-generating waste. Comparing the estimated amount of radioactive wastes with the capacity of both repositories it may be concluded that the Konrad and Gorleben repositories will provide sufficient capacity to ensure the disposal of all kinds of radioactive waste on a long-term basis in the Federal Republic of Germany. 1 fig., 2 tabs

  11. Overpack for processing radioactive waste

    International Nuclear Information System (INIS)

    Asano, Hidekazu.

    1997-01-01

    A glass solidification material in which radioactive wastes are sealed and solidified in glass is covered by an inner layer vessel made of corrosion resistant materials, and the outer side thereof is covered with an outer layer vessel made of a reinforced material. The inner layer vessel made of corrosion materials comprises corrosion materials such as titanium, copper, stainless steel and nickel based alloy, and the outer layer vessel made of a reinforced material comprises a reinforced material such as carbon steel. If it is constituted by using carbon steel having a thickness as much as of from 50 to 200mm, it is durable sufficiently under ground of about 1000m. Although the outer layer vessel made of the reinforced material is corroded by oxidation by oxygen contained in underwater after lapse of time of several years, it is endurable sufficiently to initial oxidative corrosion by determined the thickness to 50mm or more, and after oxygen is consumed, reductive corrosion with extremely slow progressing speed begins. Since the inner vessel made of the corrosion resistant material is formed, the lifetime is extended, and the glass solidification materials can be confined stably for a long period of time. (N.H.)

  12. Radioactive wastes processing and disposing container

    International Nuclear Information System (INIS)

    Wada, Jiro; Kato, Hiroaki.

    1987-01-01

    Purpose: To obtain a processing and disposing container at low level radioactive wastes, excellent in corrosion and water resistance, as well as impact shock resistance for the retrieval storage over a long period of time. Constitution: The container is constituted with sands and pebbles as aggregates and glass fiber-added unsaturated polyester resins as binders. The container may entirely be formed with such material or only the entire inner surface may be formed with the material as liners. A container having excellent resistance to water, chemicals, freezing or melting, whether impact shock, etc. can be obtained, thereby enabling retrieval storage for radioactive wastes at the optimum low level. (Takahashi, M.)

  13. Radioactive waste management policy

    International Nuclear Information System (INIS)

    Werthamer, N.R.

    1977-01-01

    The State of New York, some 15 years ago, became a party to an attempt to commercialize the reprocessing and storage of spent nuclear fuels at the West Valley Reprocessing Facility operated by Nuclear Fuel Services, Inc. (NFS). That attempted commercialization, and the State of New York, have fallen victim to changing Federal policies in the United States, leaving an outstanding and unique radioactive waste management problem unresolved. At the beginning of construction in 1963, the AEC assured both NFS and New York State of the acceptability of long-term liquid tank storage for high level wastes, and New York State ERDA therefore agreed to become the responsible long-lived stable institution whose oversight was needed. It was understood that perpetual care and maintenance of the wastes, as liquid, in on-site underground tanks, would provide for safe and secure storage in perpetuity. All that was thought to be required was the replacement of the tanks near the end of their 40-year design life, and the transferring of the contents; for this purpose, a perpetual care trust fund was established. In March of 1972, NFS shut West Valley down for physical expansion, requiring a new construction permit from the AEC. After four years of administrative proceedings, NFS concluded that changes in Federal regulations since the original operating license had been issued would require about 600 million dollars if operations were to resume. In the fall of 1976, NFS informed the NRC, of its intention of closing the reprocessing business. The inventories of wastes left are listed. The premises upon which the original agreements were based are no longer valid. Federal responsibilities for radioactive wastes require Federal ownership of the West Valley site. The views of New York State ERDA are discussed in detail

  14. Stigma and radioactive waste

    International Nuclear Information System (INIS)

    Mitchell, R.C.

    1988-01-01

    Stigma is a special impact of radioactive waste disposal resulting from the perceptions of risk people have of nuclear waste. In this case, stigma is the devaluing or discrediting of a person, group, or geographical area because of proximity to a nuclear waste disposal site, resulting in negative consequences for the individual and collective (e.g., local economy, community relations, perceived quality of life). As part of a social and economic impact assessment of the proposed HLWR at Hanford Site, WA for Washington State, focus groups were conducted in the Tri-Cities near Hanford to identify stigma effects. Results from the groups showed strong evidence of individual impacts of stigmatization: local residents described prejudice towards them because they live near Hanford which appeared to affect their self-respect, the use of the phrase glowing in the dark by outsiders to symbolize the stigma, and showed concern about the possibility that local products might suffer from reduced demand because of products becoming associated with radioactivity in the public's mind. These results indicate that stigma effects are real and should be studied in research and assessments

  15. Management of radioactive wastes

    International Nuclear Information System (INIS)

    2005-01-01

    The law from December 30, 1991, precisely defines 3 axes of researches for the management of high level and long-lived radioactive wastes: separation/transmutation, surface storage and underground disposal. A global evaluation report about these researches is to be supplied in 2006 by the French government to the Parliament. A first synthesis of the knowledge gained after 14 years of research has led the national commission of the public debate (CNDP) to organize a national debate about the general options of management of high-level and long-lived radioactive wastes before the 2006 date line. The debate comprises 4 public hearings (September 2005: Bar-le-Duc, Saint-Dizier, Pont-du-Gard, Cherbourg), 12 round-tables (October and November 2005: Paris, Joinville, Caen, Nancy, Marseille), a synthesis meeting (December 2005, Dunkerque) and a closing meeting (January 2006, Lyon). This document is the synthesis of the round table debates which took place at Joinville, i.e. in the same area as the Bure underground laboratory of Meuse/Haute-Marne. Therefore, the discussion focuses more on the local impacts of the setting up of a waste disposal facility (environmental aspects, employment, economic development). (J.S.)

  16. Radioactive waste processing device

    International Nuclear Information System (INIS)

    Inaguma, Masahiko; Takahara, Nobuaki; Hara, Satomi.

    1996-01-01

    In a processing device for filtering laundry liquid wastes and shower drains incorporated with radioactive materials, a fiber filtration device is disposed and an activated carbon filtration device is also disposed subsequent to the fiber filtration device. In addition, a centrifugal dewatering device is disposed for dewatering spent granular activated carbon in the activated carbon filtration device, and a minute filtering device is disposed for filtering the separated dewatering liquid. Filtrates filtered by the minute filtration device are recovered in a collecting tank. Namely, at first, suspended solid materials in laundry liquid wastes and shower drains are captured, and then, ingredients concerning COD are adsorbed in the activated carbon filtration device. The radioactive liquid wastes of spent granular activated carbon in the activated carbon filtration device are reduced by dewatering them by the centrifugal dewatering device, and then the granular activated carbon is subjected to an additional processing. Further, it is separated by filtration using the minute filtration device and removed as cakes. Since the filtrates are recovered to the collecting tank and filtered again, the water quality of the drains is not degraded. (N.H.)

  17. National inventory of radioactive wastes

    International Nuclear Information System (INIS)

    1997-01-01

    There are in France 1064 sites corresponding to radioactive waste holders that appear in this radioactive waste inventory. We find the eighteen sites of E.D.F. nuclear power plants, The Cogema mine sites, the Cogema reprocessing plants, The Cea storages, the different factories and enterprises of nuclear industry, the sites of non nuclear industry, the Andra centers, decommissioned installations, disposals with low level radioactive wastes, sealed sources distributors, national defence. (N.C.)

  18. Vitrification of radioactive waste. Application to other kinds of waste

    International Nuclear Information System (INIS)

    Jouan, A.

    1993-01-01

    The containment by vitrification of radioactive waste is applied to concentrate solutions of fission products coming from the spent fuel reprocessing. By the way of liquid state to solid state, it is possible to reduce the volume of waste, to get a material with safety guarantees necessary to long storage and the glass by its chemical resistance, its thermal stability and its well resistance to irradiation answers particularly well to these necessities

  19. Regulation of radioactive waste management

    International Nuclear Information System (INIS)

    2002-01-01

    This bulletin contains information about activities of the Nuclear Regulatory Authority of the Slovak Republic (UJD). In this leaflet the regulation of radioactive waste management of the UJD are presented. Radioactive waste (RAW) is the gaseous, liquid or solid material that contains or is contaminated with radionuclides at concentrations or activities greater than clearance levels and for which no use is foreseen. The classification of radioactive waste on the basis of type and activity level is: - transition waste; - short lived low and intermediate level waste (LlLW-SL); - long lived low and intermediate level waste (LlLW-LL); - high level waste. Waste management (in accordance with Act 130/98 Coll.) involves collection, sorting, treatment, conditioning, transport and disposal of radioactive waste originated by nuclear facilities and conditioning, transport to repository and disposal of other radioactive waste (originated during medical, research and industrial use of radioactive sources). The final goal of radioactive waste management is RAW isolation using a system of engineered and natural barriers to protect population and environment. Nuclear Regulatory Authority of the Slovak Republic regulates radioactive waste management in accordance with Act 130/98 Coll. Inspectors regularly inspect and evaluate how the requirements for nuclear safety at nuclear facilities are fulfilled. On the basis of safety documentation evaluation, UJD issued permission for operation of four radioactive waste management facilities. Nuclear facility 'Technologies for treatment and conditioning contains bituminization plants and Bohunice conditioning centre with sorting, fragmentation, evaporation, incineration, supercompaction and cementation. Final product is waste package (Fibre reinforced container with solidified waste) acceptable for near surface repository in Mochovce. Republic repository in Mochovce is built for disposal of short lived low and intermediate level waste. Next

  20. Radioactive waste management in Korea

    International Nuclear Information System (INIS)

    Lee, Ik Hwan

    1997-01-01

    In order to meet the increasing energy demand in Korea, continuous promotion of nuclear power program will be inevitable in the future. However, the use of nuclear energy eventually requires effective and reliable radioactive waste management. For the safe and economical management of radioactive waste, first of all, volume reduction is essentially required and hence the development of related technologies continuously be pursued. A site for overall radioactive waste management has to be secured in Korea. KEPCO-NETEC will improve public understanding by reinforcing PA and will maintain transparency of radioactive waste management. (author). 1 fig

  1. Radioactive Waste Repositories Administration - SURAO

    International Nuclear Information System (INIS)

    Kucerka, M.

    1998-01-01

    The Atomic Act specifies, among other things, responsibilities of the government in the field of safe disposal of radioactive wastes. To satisfy this responsibility, the Ministry of Industry and Trade has established the Radioactive Waste Repositories Administration (SURAO). SURAO's major responsibilities include: (a) the preparation, construction, commissioning, operation, and decommissioning of radioactive waste repositories and the monitoring of their environmental impacts; (b) radioactive waste management; (c) spent or irradiated nuclear fuel processing into a form suitable for storage/disposal or reuse; (d) record-keeping of received radioactive wastes and their producers; (e) administration of fund transfers as stipulated by the Atomic Act, Article 27; (f) development of proposals for specification of fees to be paid to the Nuclear Account; (g) responsibility for and coordination of research and development in the field of radioactive waste handling and management; (h) supervision of licensees' margin earmarked for the decommissioning of their facilities; (i) providing services in radioactive waste handling and management; (j) handling and management of radioactive wastes that have been transferred to the Czech Republic from abroad and cannot be sent back; (k) interim administration of radioactive wastes that have become state property. The Statute of the Administration is reproduced in full. (P.A.)

  2. Solid and liquid radioactive wastes

    International Nuclear Information System (INIS)

    Cluchet, J.; Desroches, J.

    1977-01-01

    The problems raised by the solid and liquid radioactive wastes from the CEA nuclear centres are briefly exposed. The processing methods developed at the Saclay centre are described together with the methods for the wastes from nuclear power plants and reprocessing plants. The different storage techniques used at the La Hague centre are presented. The production of radioactive wastes by laboratories, hospitals and private industry is studied for the sealed sources and the various radioactive substances used in these plants. The cost of the radioactive wastes is analysed: processing, transport, long term storage [fr

  3. Glass forms for immobilization of Hanford wastes

    International Nuclear Information System (INIS)

    Schulz, W.W.; Dressen, A.L.; Hobbick, C.W.; Babad, H.

    1975-03-01

    Approximately 140 million liters of solid salt cake (mainly NaNO 3 ), produced by evaporation of aged alkaline high-level liquid wastes, will be stored in underground tanks when the present Hanford Waste Management Program is completed in the early 1980's. At this time also, large volumes of various other solid radioactive wastes (sludges, excavated Pu-contaminated soil, and doubly encapsulated 137 CsCl and 90 SrF 2 ) will be stored on the Hanford Reservation. All these solid wastes can be converted to immobile silicate and aluminosilicate glasses of low water leachability by melting them at 1100 0 to 1400 0 C with appropriate amounts of basalt (or sand) and other glass-formers such as B 2 O 3 or CaO. Reviewed in this paper are formulations and other melt conditions used successfully in batch tests to make glasses from actual and synthetic wastes; leachability and other properties of these glasses show them to be satisfactory vehicles for immobilization of the Hanford wastes. (U.S.)

  4. Radioactive waste management

    International Nuclear Information System (INIS)

    Anon.

    1988-01-01

    The dossier published in this issue deals with all matters relating to radioactive waste management. It describes in detail the guidelines implemented by France in this field and provides a general overview of actions carried out at international level. The articles are assembled in several chapters, treating the following subjects: I. Upstream storage management. II. Storage (surface and underground). III. Research to back up the management program. There then follows a description of various processes and equipment developed by research laboratories and industrialists to provide, at the different stages, a number of operations required by the management programs [fr

  5. Low-Activity Radioactive Wastes

    Science.gov (United States)

    In 2003 EPA published an Advance Notice of Proposed Rulemaking (ANPR) to collect public comment on alternatives for disposal of waste containing low concentrations of radioactive material ('low-activity' waste).

  6. Radioactive waste management in Canada

    International Nuclear Information System (INIS)

    Hawley, N.J.

    1979-09-01

    Reports and other Canadian literature on radioactive waste processing and disposal covering the period 1953-1979 are listed. A selected list of international conferences relating to waste management (1959-1979) is attached. (LL)

  7. Radioactive waste treatment apparatus

    International Nuclear Information System (INIS)

    Abrams, R.F.; Chellis, J.G.

    1983-01-01

    Radioactive waste treatment apparatus is disclosed in which the waste is burned in a controlled combustion process, the ash residue from the combustion process is removed and buried, the gaseous effluent is treated in a scrubbing solution the pH of which is maintained constant by adding an alkaline compound to the solution while concurrently extracting a portion of the scrubbing solution, called the blowdown stream. The blowdown stream is fed to the incinerator where it is evaporated and the combustibles in the blowdown stream burned and the gaseous residue sent to the scrubbing solution. Gases left after the scrubbing process are treated to remove iodides and are filtered and passed into the atmosphere

  8. Radioactive wastes processing device

    International Nuclear Information System (INIS)

    Takamura, Yoshiyuki; Fukujoji, Seiya.

    1986-01-01

    Purpose: To exactly recognize the deposition state of mists into conduits thereby effectively conduct cleaning. Constitution: A drier for performing drying treatment of liquid wastes, a steam decontaminating tower for decontaminating the steams generated from the drier and a condenser for condensating the decontaminating steams are connected with each other by means of conduits to constitute a radioactive wastes processing apparatus. A plurality of pressure detectors are disposed to the conduits, the pressure loss within the conduits is determined based on the detector output and the clogged state in the conduits due to the deposition of mists is detected by the magnitude of the pressure loss. If the clogging exceeds a certain level, cleaning water is supplied to clean-up the conduits thereby keep the operation to continue always under sound conditions. (Sekiya, K.)

  9. Radioactive Waste SECURITY

    International Nuclear Information System (INIS)

    Brodowski, R.; Drapalik, M.; Gepp, C.; Gufler, K.; Sholly, S.

    2010-01-01

    The purpose of this work is to investigate the safety requirements for a radioactive waste repository, the fundamental problems involved and the legislative rules and arrangements for doing so. As the title already makes clear, the focus of this work is on aspects that can be assigned to the security sector - ie the security against the influence of third parties - and are to be distinguished from safety measures for the improvement of the technical safety aspects. In this context, mention is made of events such as human intrusion into guarded facilities, whereas e.g. a geological analysis on seismic safety is not discussed. For a variety of reasons, the consideration of security nuclear waste repositories in public discussions is increasingly taking a back seat, as ia. Terrorist threats can be considered as negligible risk or well calculable. Depending on the type of storage, different security aspects still have to be considered. (roessner)

  10. Fabrication and evaluation of hybrid materials from A-zeolite and ground glass powders for vitrified radioactive waste

    International Nuclear Information System (INIS)

    Kamitani, Masataka; Kondo, Mitsunori; Hiki, Tomonori; Tagami, Toru; Nakahira, Atsushi; Wakihara, Toru

    2014-01-01

    The samples from A-type zeolite and ground soda-lime glass powders were solidified by calcinations at 600 to 800°C in air atmosphere. These hybrid zeolite/glass samples at 700°C were in part insufficiently densified and hybrid samples were fully densified at 800°C, although the densification was not generated at 600°C. A-zeolites were still stable in glass melt at 800°C for hybrid zeolite/glass samples. These hybrid zeolite/glass samples had the ion exchange ability of 20% against Sr 2+ and the high ability over 80% against Cs + as well as A-zeolite. Microstructures of obtained hybrid zeolite/glass samples were evaluated. (author)

  11. Regulation on radioactive waste management

    International Nuclear Information System (INIS)

    1999-01-01

    A national calculator control system for the metropolitan radioactive waste banks was developed in 1999. The NNSA reviewed by the regulations the feasibility of some rectification projects for uranium ore decommissioning and conducted field inspections on waste treating systems and radioactive waste banks at the 821 plant. The NNSA realized in 1999 the calculator control for the disposal sites of low and medium radioactive waste. 3 routine inspections were organized on the reinforced concrete structures for disposal units and their pouring of concrete at waste disposal site and specific requirements were put forth

  12. Radioactive waste engineering and management

    CERN Document Server

    Nakayama, Shinichi

    2015-01-01

    This book describes essential and effective management for reliably ensuring public safety from radioactive wastes in Japan. This is the first book to cover many aspects of wastes from the nuclear fuel cycle to research and medical use, allowing readers to understand the characterization, treatment and final disposal of generated wastes, performance assessment, institutional systems, and social issues such as intergenerational ethics. Exercises at the end of each chapter help to understand radioactive waste management in context.

  13. The management of radioactive wastes

    International Nuclear Information System (INIS)

    1998-01-01

    This educative booklet describes the role and missions of the ANDRA, the French national agency for the management of radioactive wastes, and the different aspects of the management of radioactive wastes: goal, national inventory, classification, transport (organisation, regulation, safety), drumming, labelling, surface storage of short life wastes, environmental control, management of long life wastes (composition, research, legal aspects) and the underground research laboratories (description, public information, projects, schedules). (J.S.)

  14. Nanoporous Glasses for Nuclear Waste Containment

    OpenAIRE

    Woignier, Thierry; Primera, Juan; Reynes, Jerôme

    2016-01-01

    Research is in progress to incorporate nuclear waste in new matrices with high structural stability, resistance to thermal shock, and high chemical durability. Interactions with water are important for materials used as a containment matrix for the radio nuclides. It is indispensable to improve their chemical durability to limit the possible release of radioactive chemical species, if the glass structure is attacked by corrosion. By associating high structural stability and high chemical dura...

  15. Characterization and vitrification of Hanford radioactive high level wastes

    International Nuclear Information System (INIS)

    Tingey, J.M.; Elliott, M.L.; Larson, D.E.; Morrey, E.V.

    1991-01-01

    Radioactive Neutralized Current Acid Waste (NCAW) samples from the Hanford waste tanks have been chemically, radiochemically and physically characterized. The wastes were processed according to the Hanford Waste vitrification Plant (HWVP) flowsheet, and characterized after each process step. The waste glasses were sectioned and leach tested. Chemical, radiochemical and physical properties of the waste will be presented and compared to nonradioactive simulant data and the HWVP reference composition and properties

  16. Low-level Radioactive waste Management

    International Nuclear Information System (INIS)

    1991-01-01

    This meeting describes low-level radioactive waste management problems and contains 8 papers: 1 Low-level radioactive waste management: exemption concept and criteria used by international organizations. 2 Low-level radioactive waste management: french and foreign regulations 3 Low-level radioactive waste management in EDF nuclear power plants (FRANCE) 4 Low-level radioactive waste management in COGEMA (FRANCE) 5 Importance of low-level radioactive wastes in dismantling strategy in CEA (FRANCE) 6 Low-level radioactive waste management in hospitals 7 Low-level radioactive waste disposal: radiation protection laws 8 Methods of low-level radioactive materials measurements during reactor dismantling or nuclear facilities demolition (FRANCE)

  17. Radioactive waste processing method

    International Nuclear Information System (INIS)

    Ando, Ken-ichi; Kawamura, Hideki; Takeuchi, Kunifumi.

    1997-01-01

    Base rock is dug in a substantially cylindrical shape, bentonite blocks in an amount for a predetermined lift are disposed on the inner side of the dug wall surfaces. Concrete blocks constituting a structure of an underground silo are disposed at the inner side. Barrier blocks are disposed to the inner side thereof, and vessels incorporated with radioactive wastes are disposed to the inner side. The bentonite disposed to the inner side of the dug wall surfaces, the concrete structure of the underground silo and the barrier members are divided in the vertical direction into a plurality of blocks, and these blocks are stacked successively from the lowermost layer together with the containing vessels of the radioactive wastes, and after stacking them to a predetermined height, a filler is filled up to the circumference of the vessels. With such a constitution, the underground silo is not fallen down or vibrated even upon occurrence of an earthquake. In addition, bending stresses are scarcely caused thereby making reinforcement of iron reinforcing materials unnecessary. Accordingly, the sealing performance is improved, and processing cost is reduced. (T.M.)

  18. High-Level Radioactive Waste.

    Science.gov (United States)

    Hayden, Howard C.

    1995-01-01

    Presents a method to calculate the amount of high-level radioactive waste by taking into consideration the following factors: the fission process that yields the waste, identification of the waste, the energy required to run a 1-GWe plant for one year, and the uranium mass required to produce that energy. Briefly discusses waste disposal and…

  19. Radioactive waste management for reactors

    International Nuclear Information System (INIS)

    Rodger, W.A.

    1974-01-01

    Radioactive waste management practices at nuclear power plants are summarized. The types of waste produced and methods for treating various types of wastes are described. The waste management systems, including simplified flow diagrams, for typical boiling water reactors and pressurized water reactors are discussed. (U.S.)

  20. Packaging radioactive wastes for geologic disposal

    International Nuclear Information System (INIS)

    Benton, H.A.

    1996-01-01

    The M ampersand O contractor for the DOE Office of Civilian Radioactive Waste Management is developing designs of waste packages that will contain the spent nuclear fuel assemblies from commercial and Navy reactor plants and various civilian and government research reactor plants, as well as high-level wastes vitrified in glass. The safe and cost effective disposal of the large and growing stockpile of nuclear waste is of national concern and has generated political and technical debate. This paper addresses the technical aspects of disposing of these wastes in large and robust waste packages. The paper discusses the evolution of waste package design and describes the current concepts. In addition, the engineering and regulatory issues that have governed the development are summarized and the expected performance in meeting the requirements are discussed

  1. Glass composition development for plasma processing of Hanford high sodium content low-level radioactive liquid waste

    International Nuclear Information System (INIS)

    Marra, J.C.

    1995-02-01

    To assess the acceptability of prospective compositions, response criteria based on durability, homogeneity, viscosity and volatility were defined. Response variables were weighted: durability 35%, homogeneity 25%, viscosity 25%, volatility 15%. A Plackett-Burman experimental design was used to define the first twelve glass formulations. Glass former additives included Al2O3, B2O3, CaO, Li2O, ZrO2 and SiO2. Lithia was added to facilitate fritting of the additives. The additives were normalized to silica content to ease experimental matrix definition and glass formulation. Preset high and low values of these ratios were determined for the initial twelve melts. Based on rankings of initial compositions, new formulations for testing were developed based on a simplex algorithm. Rating and ranking of subsequent compositions continued until no apparent improvement in glass quality was achieved in newly developed formulations. An optimized composition was determined by averaging the additive component values of the final best performing compositions. The glass former contents to form the optimized glass were: 16.1 wt % Al2O3, 12.3 wt % B2O3, 5.5 wt % CaO, 1.7 wt % Li2O, 3.3 wt % ZrO2, 61.1 wt % SiO2. An optimized composition resulted after only 25 trials despite studying six glass additives. A vitrification campaign was completed using a small-scale Joule heated melter. 80 lbs of glass was produced over 96 hours of continuous operation. Several salt compounds formed and deposited on melter components during the run and likely caused the failure of several pour chamber heaters. In an attempt to minimize sodium volatility, several low or no boron glasses were formulated. One composition containing no boron produced a homogeneous glass worthy of additional testing

  2. Method for ultimate disposition of borate containing radioactive wastes by vitrification

    International Nuclear Information System (INIS)

    Bege, D.; Faust, H.J.; Puthawala, A.; Stunkel, H.

    1984-01-01

    Method for the ultimate disposition of radioactive wastes by vitrification, in which weak to medium radioactive waste concentrates from borate-containing radioactive liquids are mixed with added glass-forming materials, maximally in a ratio of 1:3, and the mixture heated to obtain a glass-forming melt

  3. Radioactive waste processing apparatus

    Science.gov (United States)

    Nelson, R.E.; Ziegler, A.A.; Serino, D.F.; Basnar, P.J.

    1985-08-30

    Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container. The chamber may be formed by placing a removable extension over the top of the container. The extension communicates with the apparatus so that such vapors are contained within the container, extension and solution feed apparatus. A portion of the chamber includes coolant which condenses the vapors. The resulting condensate is returned to the container by the force of gravity.

  4. Radioactive wastes. Their industrial management

    International Nuclear Information System (INIS)

    Lavie, J.M.

    1982-01-01

    This paper introduces a series that will review the present situation in the field of long-term management of radioactive wastes. Both the meaning and the purposes of an industrial management of radioactive wastes are specified. This short introduction is complemented by outline of data on the French problem [fr

  5. Public debate - radioactive wastes management

    International Nuclear Information System (INIS)

    2005-01-01

    Between September 2005 and January 2006 a national debate has been organized on the radioactive wastes management. This debate aimed to inform the public and to allow him to give his opinion. This document presents, the reasons of this debate, the operating, the synthesis of the results and technical documents to bring information in the domain of radioactive wastes management. (A.L.B.)

  6. High content silicate porous glasses used for radioactive wastes storage: preparation and characterization of the spinodal decomposition

    International Nuclear Information System (INIS)

    Ventura, P.C.S.

    1983-01-01

    The phase separation behavior via spinodal decomposition of two sodium borosilicate glasses has been studied having the following compositions in weight %: Glass A: 8% Na 2 O - 32% B 2O3 - 60% Si O 2 Glass 8% B: Na 2 O -27% B 2 O 3 - 65% Si O 2 . The growth of the mean size r of the minor phase microstructure has been determined as a function of both the time length (0-100 hours) and the heat treatment by analyzing temperature 580, 600 0 C of the glass sample images obtained with a Scanning Electron Microscope. The results are in good agreement with the theory of Lifshitz-Slyozov which predict a growth of the minor phase microstructure via a diffusion controlled process through the insoluble phase such that r-bar = A o t e - ΔE/R T. The activation energy ΔE and the pre-exponential factor A o of the diffusion process were found ΔE = 58,8 kCal/mol; A o = 8,42 x 10 21 Angstrom 3 /h for the glass A and ΔE = 92,6 kCal/mol; A o = 4,84 x 10 29 Angstrom 3 /h for the glass B. The distribution curves of the microstructure size allowed to suggest for the glasses under study the most adequate heat treatments to absorbs after the leaching of the soluble phase. (author)

  7. Disposal method of radioactive wastes

    International Nuclear Information System (INIS)

    Uetake, Naoto; Fukazawa, Tetsuo.

    1986-01-01

    Purpose: To improve the safety of underground disposal of radioactive wastes for a long period of time by surrounding the periphery of the radioactive wastes with materials that can inhibit the migration of radioactive nuclides and are physically and chemically stable. Method: Hardening products prepared from a water-hardenable calcium silicate compound and an aqueous solution of alkali silicate have compression strength as comparable with that of concretes, high water tightness and adsorbing property to radioactive isotopes such as cobalt similar to that of concretes and they also show adsorption to cesium which is not adsorbed to concretes. Further, the kneaded slurry thereof is excellent in the workability and can be poured even into narrow gaps. Accordingly, by alternately charging granular radioactive wastes and this slurry before hardening into the ground, the radioactive wastes can be put to underground disposal stably with simple procedures. (Kamimura, M.)

  8. Management situation and prospect of radioactive waste

    International Nuclear Information System (INIS)

    Han, Pil Jun

    1985-04-01

    This book tell US that management situation and prospect of radioactive waste matter, which includes importance of energy, independence, limitation of fossil fuel energy, density of nuclear energy, strategy of supply of energy resource in Korea, nuclear energy development and radioactive waste matter, summary of management of radioactive waste, statistics of radioactive waste, disposal principle of radioactive waste, management on radioactive waste after using, disposal of Trench, La Marche in French, and Asse salt mine in Germany.

  9. Developing radioactive waste management policy

    International Nuclear Information System (INIS)

    Gichana, Z.

    2012-04-01

    A policy for radioactive waste management with defined goals and requirements is needed as a basis for the preparation of legislation, review or revision of related legislation and to define roles and responsibilities for ensuring the safe management of radioactive waste. A well defined policy and associated strategies are useful in promoting consistency of emphasis and direction within all of the sectors involved in radioactive waste management. The absence of policy and strategy can lead to confusion or lack of coordination and direction. A policy and/or strategy may sometimes be needed to prevent inaction on a particular waste management issue or to resolve an impasse. (author)

  10. Radioactive waste cementation

    International Nuclear Information System (INIS)

    Soriano B, A.

    1996-01-01

    This research was carried out to develop the most adequate technique to immobilize low and medium-activity radioactive waste. different brands of national cement were used, portland and pozzolanic cement. Prismatic and cylindrical test tubes were prepared with different water/cement (W/C) relationship. Additives such a as clay and bentonite were added in some other cases. Later, the properties of these test tubes were evaluated. Properties such as: mechanical resistance, immersion resistance, lixiviation and porosity resistance. Cement with the highest mechanical resistance values, 62,29 MPa was pozzolanic cement for a W/C relationship of 0,35. It must be mentioned that the other types of cements reached a mechanical resistance over 10 MPa, a value indicated by the international standards for transportation and storage of low and medium-activity radioactive waste at a superficial level. However, in the case of immersion resistance, Sol cement (portland type I) with a W/C relationship of 0,35 reached a compression resistance over 61,92 MPa; as in the previous cases, the other cements reached a mechanical resistance > 10 MPa. Regarding porosity, working with W/C relationships = 0,35 0,40 and 0,45, without additives and with additives, the percentage of porosity found for all cements is lower than 40% percentage indicated by international standards. With regard to the lixiviation test, pozzolanic cement best retained Cesium-137 and Cobalt-60, and increased its advantages when bentonite was added, obtaining a lixiviation rate of 2,02 x E-6 cm/day. Sol cement also improved its properties when bentonite was added and obtained a lixiviation rate of 2,84 x E-6 cm/day for Cesium-137. However, Cobalt-60 is almost completely retained with the 3 types of cement with or without additives, reaching the limits indicated by the international standards for the lixiviation rate of beta-gamma emitter < 5,00E-4 cm/day. Characterizing the final product involves the knowledge of its

  11. Radioactive waste management at AECL

    International Nuclear Information System (INIS)

    Gadsby, R.D.; Allan, C.J.

    2003-01-01

    AECL has maintained an active program in radioactive waste management since 1945, when the Canadian nuclear program commenced activities at the Chalk River Laboratories (CRL). Waste management activities have included operation of waste management storage and processing facilities at AECL's CRL and Whiteshell Laboratories (WL); operation of the Low Level Radioactive Waste Management Office on behalf of Natural Resources Canada to resolve historic radioactive waste problems (largely associated with radioactive ore recovery, transport and processing operations) that are the responsibility of the Federal Government; development of the concept and related technology for geological disposal of Canada's nuclear fuel waste; development of the Intrusion-Resistant Underground Structure (IRUS) disposal concept for low-level nuclear waste; development of dry storage technology for the interim storage of used fuel; and development and assessment of waste processing technology for application in CANDU nuclear power plants and at CRL and WL. Today these activities are continuing. In addition, AECL is: preparing to decommission the nuclear facilities at WL; carrying out a number of smaller decommissioning projects at CRL; putting in place projects to upgrade the low-level liquid waste processing capabilities of the CRL Waste Treatment Centre, recover and process highly active liquid wastes currently in storage, and recover, condition and improve the storage of selected fuel wastes currently stored in below-ground standpipes in the CRL waste management areas; and assessing options for additional remediation projects to improve the management of other wastes currently in storage and to address environmental contamination from past practices. (author)

  12. CEA and its radioactive wastes

    International Nuclear Information System (INIS)

    Marano, S.

    1999-01-01

    CEA annually produces about 3500 tons of radioactive wastes in its 43 basic nuclear installations. CEA ranks third behind EDF and Cogema. Low-level wastes (A wastes) are sent to ANDRA (national agency for the management of nuclear wastes)whereas medium-level wastes (B wastes) are stored by CEA itself. CEA has checked off its storing places and has set up an installation Cedra to process and store ancient and new nuclear wastes. 3 other installations are planned to operate within 6 years: Agate (Cadarache) will treat liquid effluents, Stella (Saclay) will process liquid wastes that are beta or gamma emitters, and Atena (Marcoule) will treat and store radioactive sodium coming from Phenix reactor and IPSN laboratories. The use of plasma torch for vitrifying wastes is detailed, the management of all the nuclear wastes produced by CEA laboratories and installations is presented. (A.C.)

  13. Radioactive waste sealing container

    International Nuclear Information System (INIS)

    Tozawa, S.; Kitamura, T.; Sugimoto, S.

    1984-01-01

    A low- to medium-level radioactive waste sealing container is constructed by depositing a foundation coating consisting essentially of zinc, cadmium or a zinc-aluminum alloy over a steel base, then coating an organic synthetic resin paint containing a metal phosphate over the foundation coating, and thereafter coating an acryl resin, epoxy resin, and/or polyurethane paint. The sealing container can consist of a main container body, a lid placed over the main body, and fixing members for clamping and fixing the lid to the main body. Each fixing member may consist of a material obtained by depositing a coating consisting essentially of cadmium or a zinc-aluminum alloy over a steel base

  14. Formulation of special glass frit and its use for decontamination of Joule melter employed for vitrification of high level and radioactive liquid waste

    International Nuclear Information System (INIS)

    Valsala, T.P.; Mishra, P.K.; Thakur, D.A.; Ghongane, D.E.; Jayan, R.V.; Dani, U.; Sonavane, M.S.; Kulkarni, Y.

    2012-01-01

    Advanced vitrification system at TWMP Tarapur was used for successful vitrification of large volume of HLW stored in waste tank farm. After completion of the operational life of the joule melter, dismantling was planned. Prior to the dismantling, the hold up inventory of active glass product from the melter was flushed out using specially formulated inactive glass frit to reduce the air activity buildup in the cell during dismantling operations. The properties of the special glass frit prepared are comparable with that of the regular product glass. More than 94% of holdup activity was flushed out from the joule melter prior to the dismantling of the melter. (author)

  15. The disposal of radioactive waste

    International Nuclear Information System (INIS)

    Ormai, P.

    2006-01-01

    The first part shows different ways of 'producing' radioactive wastes, defines the wastes of small, medium and high activity and gives estimation on the quantity of the necessary capacities of waste disposal facilities. The modern radioactive waste disposal that is the integrated processing of the form of waste, the package, the technical facility and the embedding geological environment that guarantee the isolation together. Another factor is the lifetime of radioactive waste which means that any waste containing long lifetime waste in higher concentration than 400-4000 kBq/kg should be disposed geologically. Today the centre of debate disposal of radioactive waste is more social than technical. For this reason not only geological conditions and technical preparations, but social discussions and accepting communities are needed in selecting place of facilities. Now, the focus is on long term temporary disposal of high activity wastes, like burnt out heating elements. The final part of the paper summarizes the current Hungarian situation of disposal of radioactive wastes. (T-R.A.)

  16. Final disposal of radioactive waste

    Directory of Open Access Journals (Sweden)

    Freiesleben H.

    2013-06-01

    Full Text Available In this paper the origin and properties of radioactive waste as well as its classification scheme (low-level waste – LLW, intermediate-level waste – ILW, high-level waste – HLW are presented. The various options for conditioning of waste of different levels of radioactivity are reviewed. The composition, radiotoxicity and reprocessing of spent fuel and their effect on storage and options for final disposal are discussed. The current situation of final waste disposal in a selected number of countries is mentioned. Also, the role of the International Atomic Energy Agency with regard to the development and monitoring of international safety standards for both spent nuclear fuel and radioactive waste management is described.

  17. Incineration of radioactive waste

    International Nuclear Information System (INIS)

    Caramelle, D.; Florestan, J.; Waldura, C.

    1990-01-01

    This paper reports that one of the methods used to reduce the volume of radioactive wastes is incineration. Incineration also allows combustible organic wastes to be transformed into inert matter that is stable from the physico-chemical viewpoint and ready to be conditioned for long-term stockage. The quality of the ashes obtained (low carbon content) depends on the efficiency of combustion. A good level of efficiency requires a combustion yield higher than 99% at the furnace door. Removal efficiency is defined as the relation between the CO 2 /CO + CO 2 concentrations multiplied by 100. This implies a CO concentration of the order of a few vpm. However, the gases produced by an incineration facility can represent a danger for the environment especially if toxic or corrosive gases (HCL,NO x ,SO 2 , hydrocarbons...) are given off. The gaseous effluents must therefore be checked after purification before they are released into the atmosphere. The CO and CO 2 measurement gives us the removal efficiency value. This value can also be measured in situ at the door of the combustion chamber. Infrared spectrometry is used for the various measurements: Fourier transform infrared spectrometry for the off-gases, and diode laser spectrometry for combustion

  18. Radioactive wastes. Management prospects

    International Nuclear Information System (INIS)

    Guillaumont, R.

    2003-01-01

    This article describes the perspectives of management of radioactive wastes as defined in the French law from December 30, 1991. This law defines three ways of research: abatement of the radiotoxicity of wastes (first way), reversible geological storage (second way) or long duration geological disposal (third way). This article develops these three solutions: 1 - strategic perspectives; 2 - separation, transmutation and specific conditioning: isotopes to be separated (evolution of the radio-toxicity inventory of spent fuels, migration of long-living radionuclides, abatement of radio-toxicity), research on advanced separation (humid and dry way), research on transmutation of separate elements (transmutation and transmutation systems, realistic scenarios of Pu consumption and actinides transmutation, transmutation performances), research on materials (spallation targets, fuels and transmutation targets), research on conditioning matrices for separated elements; 3 - long-term storage: principles and problems, containers, surface and subsurface facilities; 4 - disposal: reversibility and disposal, geological disposal (principle and problems, site and concept selection), adaptation to reversibility, research on materials (bentonite and cements for geologic barrier, metals for containers), underground research and qualification laboratories, quantity of containers to be stored. (J.S.)

  19. Glasses obtained from industrial wastes

    International Nuclear Information System (INIS)

    Bortoluzzi, D.; Oliveira Fillho, J.; Uggioni, E.; Bernardin, A.M.

    2009-01-01

    This paper deals with the study of the vitrification mechanism as an inertization method for industrial wastes contaminated with heavy metals. Ashes from coal (thermoelectric), wastes from mining (fluorite and feldspar) and plating residue were used to compose vitreous systems planed by mixture design. The chemical composition of the wastes was determined by XRF and the formulations were melted at 1450 deg C for 2h using 10%wt of CaCO 3 (fluxing agent). The glasses were poured into a mold and annealed (600 deg C). The characteristic temperatures were determined by thermal analysis (DTA, air, 20 deg C/min) and the mechanical behavior by Vickers microhardness. As a result, the melting temperature is strongly dependent on silica content of each glass, and the fluorite residue, being composed mainly by silica, strongly affects Tm. The microhardness of all glasses is mainly affected by the plating residue due to the high iron and zinc content of this waste. (author)

  20. Method and techniques of radioactive waste treatment

    International Nuclear Information System (INIS)

    Ghafar, M.; Aasi, N.

    2002-04-01

    This study illustrates the characterization of radioactive wastes produced by the application of radioisotopes in industry and research. The treatment methods of such radioactive wastes, chemical co-precipitation and ion exchange depending on the technical state of radioactive waste management facility in Syria were described. The disposal of conditioned radioactive wastes, in a safe way, has been discussed including the disposal of the radioactive sources. The characterizations of the repository to stock conditioned radioactive wastes were mentioned. (author)

  1. Management of radioactive waste: A review

    OpenAIRE

    Luis Paulo Sant'ana; Taynara Cristina Cordeiro

    2016-01-01

    The issue of disposal of radioactive waste around the world is not solved by now and the principal reason is the lack of an efficient technologic system. The fact that radioactive waste decays of radioactivity with time are the main reasons for setting nuclear or radioactive waste apart from the other common hazardous wastes management. Radioactive waste can be classified according to the state of matter and level of radioactivity and this classification can be differently interpreted from co...

  2. Management of radioactive wastes

    International Nuclear Information System (INIS)

    Mawson, C.A.

    1967-01-01

    When I first became concerned with radioactive waste management, in the early 1950's, very little was really known about the subject. There was a general feeling that it was a serious 'problem'. Articles were appearing in the press and talks were being given on the radio suggesting that the wastes generated by the proposed nuclear power reactors might be a serious menace to humanity. The prophets pointed with alarm to the enormous quantities of fission products that would accumulate steadily over the years in tank farms associated with reactor fuel reprocessing plants, and calculations were made of the possible results from rupture of the tanks due to corrosion, earthquakes or enemy attack. Responsible people suggested seriously that the waste disposal problem might be fatal to the development of a nuclear power industry, and this attitude was reinforced by the popular outcry that arose from experience with fallout from nuclear weapons testing. The Canadian nuclear power industry was not critically involved in this controversy because our heavy-water reactors are fuelled with natural uranium, and reprocessing of the fuel is not necessary. The spent fuel contains plutonium, a potential fuel, but the cost of recovering it was such that it was not competitive with natural uranium, which is not in short supply in Canada. Our spent fuel is not dissolved in acid - it is stored. still in its zirconium cladding, under water at the reactor site, or placed in sealed concrete-and-steel pipes below ground. If the price of uranium rises sufficiently it will become profitable to recover the plutonium, and only then shall we have an appreciable amount of waste from this source. However. during the first five or six years of research and development at Chalk River we did investigate fuel processing methods, and like everybody else we grad stainless steel tanks containing high and medium level wastes. These were located quite close to the Ottawa River, and we worried about what

  3. Radioactive waste disposal

    International Nuclear Information System (INIS)

    Petit, J.C.

    1998-04-01

    A deep gap, reflecting a persisting fear, separates the viewpoints of the experts and that of the public on the issue of the disposal of nuclear WASTES. The history of this field is that of the proliferation with time of spokesmen who pretend to speak in the name of the both humans and non humans involved. Three periods can be distinguished: 1940-1970, an era of contestation and confusion when the experts alone represents the interest of all; 1970-1990, an era of contestation and confusion when spokespersons multiply themselves, generating the controversy and the slowing down of most technological projects; 1990-, an era of negotiation, when viewpoints, both technical and non technical, tend to get closer and, let us be optimistic, leading to the overcome of the crisis. We show that, despite major differences, the options and concepts developed by the different actors are base on two categories of resources, namely Nature and Society, and that the consensus is built up through their 'hydridation'. we show in this part that the perception of nuclear power and, in particular of the underground disposal of nuclear wastes, involves a very deep psychological substrate. Trying to change mentalities in the domain by purely scientific and technical arguments is thus in vain. The practically instinctive fear of radioactivity, far from being due only to lack of information (and education), as often postulated by scientists and engineers, is rooted in archetypical structures. These were, without doubt, reactivated in the 40 s by the traumatizing experience of the atomic bomb. In addition, anthropological-linked considerations allow us to conclude that he underground disposal of wastes is seen as a 'rape' and soiling of Mother Earth. This contributes to explaining, beyond any rationality, the refusal of this technical option by some persons. However, it would naturally be simplistic and counter-productive to limit all controversy in this domain to these psychological aspects

  4. Radioactive waste material melter apparatus

    Science.gov (United States)

    Newman, D.F.; Ross, W.A.

    1990-04-24

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.

  5. Method of solidifying radioactive waste

    International Nuclear Information System (INIS)

    Hasegawa, Akira; Mihara, Shigeru; Yamashita, Koji; Sauda, Kenzo.

    1988-01-01

    Purpose: To obtain satisfactory plastic solidification products rapidly and more conveniently from radioactive wastes. Method: liquid wastes contain, in addition to sodium sulfate as the main ingredient, nitrates hindering the polymerizing curing reactions and various other unknown ingredients, while spent resins contain residual cationic exchange groups hindering the polymerizing reaction. Generally, as the acid value of unsaturated liquid polyester resins is lower, the number of terminal alkyd resins is small, formation of nitrates is reduced and the polymerizing curing reaction is taken place more smoothly. In view of the above, radioactive wastes obtained by dry powderization or dehydration of radioactive liquid wastes or spent resins are polymerized with unsaturated liquid polyester resins with the acid value of less than 13 to obtain plastic solidification. Thus, if the radioactive wastes contain a great amount of polymerization hindering material such as NaNO 2 , they can be solidified rapidly and conveniently with no requirement for pre-treatment. (Kamimura, Y.)

  6. Gaseous radioactive waste processing system

    International Nuclear Information System (INIS)

    Onizawa, Hideo.

    1976-01-01

    Object: To prevent explosion of hydrogen gas within gaseous radioactive waste by removing the hydrogen gas by means of a hydrogen absorber. Structure: A coolant extracted from a reactor cooling system is sprayed by nozzle into a gaseous phase (hydrogen) portion within a tank, thus causing slipping of radioactive rare gas. The gaseous radioactive waste rich in hydrogen, which is purged in the tank, is forced by a waste gas compressor into a hydrogen occlusion device. The hydrogen occlusion device is filled with hydrogen occluding agents such as Mg, Mg-Ni alloy, V-Nb alloy, La-Ni alloy and so forth, and hydrogen in the waste gas is removed through reaction to produce hydrogen metal. The gaseous radioactive waste, which is deprived of hydrogen and reduced in volume, is stored in an attenuation tank. The hydrogen stored in the hydrogen absorber is released and used again as purge gas. (Horiuchi, T.)

  7. Radioactive waste material melter apparatus

    International Nuclear Information System (INIS)

    Newman, D.F.; Ross, W.A.

    1990-01-01

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs

  8. Radioactive waste: show time? - 16309

    International Nuclear Information System (INIS)

    Codee, Hans; Verhoef, Ewoud

    2009-01-01

    Time will render radioactive waste harmless. How can we manage the time radioactive substances remain harmful? Just 'wait and see' or 'marking time' is not an option. We need to isolate the waste from our living environment and control it as long as necessary. For the situation in the Netherlands, it is obvious that a period of long term storage is needed. Both the small volume of waste and the limited financial possibilities are determining factors. Time is needed to let the volume of waste grow and to let the money, needed for disposal, grow in a capital growth fund. An organisation such as COVRA - the radioactive waste organisation in the Netherlands - can only function when it has good, open and transparent relationship with the public and particularly with the local population. If we tell people that we safely store radioactive waste for 100 years, they often ask: 'That long?' How can we explain the long-term aspect of radioactive waste management in a way people can relate to? In this paper, an overview is given of the activities of COVRA on the communication of radioactive waste management. (authors)

  9. Characterization of the Italian glasses and their interaction with clay Task 3 Characterization of radioactive waste forms a series of final reports (1985-89) No 23

    International Nuclear Information System (INIS)

    Cantale, C.; Castelli, S.; Donato, A.; Traverso, D.M.

    1991-01-01

    The objective of this research work was the selection of a borosilicate glass composition suitable for the solidification of the HLW stream coming from the treatment of all the high-level wastes stored in Italy (MTR, Candu and Elk River) and the characterization of this glass with reference to the geological disposal. This research work was part of an Italian research project named 'Ulisse project', whose goal was the development and the demonstration of an integrated treatment of all the HLW stored in Italy, after their mixing (resulting waste: MCE waste). The main concept is to carry out a pre-treatment of the wastes, in order to concentrate the HLW fraction and to simplify the vitrification process, separating the most part of the inert salts. The research work concerning the separation process and pilot plant demonstration of the pre-treatment process were carried out in the framework of the CEC R and D programme (Contract No Fl1W-0011-lS). The laboratory studies concerning the vitrification of the resulting HLW streams and the vitrification demonstration in the Italian full-scale, inactive IVET plant complete the 'Ulisse project'. Some glass compositions were prepared and preliminarily characterized. The glass named BAZ was finally selected. A complete characterization of this glass was carried out in order to evaluate its mechanical, physical and physico-chemical properties. The chemical durability was evaluated by the MCC-1 static leach test at 90 0 C, using three different leachants and two surface-area to leachant-volume ratios. The same characterization programme was applied to the BAZ glass produced in the IVET plant during the plant vitrification demonstration programme. A comparison between the two glasses and a critical evaluation of their performances with respect to other nuclear waste glasses' durability was performed. 25 refs.; 46 figs.; 20 tabs

  10. Vitrification of high-level radioactive and hazardous wastes

    International Nuclear Information System (INIS)

    Lutze, W.

    1993-12-01

    The main objective is to summarize work conducted on glasses as waste forms for high-level radioactive fission product solutions up to the late 1980's (section I and II). Section III addresses the question, whether waste forms designed for the immobilization of radioactive residues can be used for the same purpose for hazardous wastes. Of particular interest are those types of hazardous wastes, e.g., fly ashes from municipal combustion plants, easy to convert into glasses or ceramic materials. A large number of base glass compositions has been studied to vitrify waste from reprocessing but only borosilicate glasses with melting temperatures between 1100 C and 1200 C and very good hydrolytic stability is used today. (orig./HP) [de

  11. Radioactive waste programme in Latvia

    International Nuclear Information System (INIS)

    Salmins, A.

    2000-01-01

    An overview is made on the use of radioactive sources and waste management in Latvia. Brief overview of the development of national legal documents - the framework law of environmental protection; international agreements; the new law on radiation safety and nuclear safety; regulation of the Cabinet of Ministers - is given. The regulatory infrastructure in the nearest future is outlined. The institutional framework for radioactive waste management is described. Basic design of the repository and radioactive waste inventory are also given. The activities on the EU DG Environment project CASIOPEE are reported

  12. Krsko NPP radioactive waste characteristics

    International Nuclear Information System (INIS)

    Skanata, D.; Kroselj, V.; Jankovic, M.

    2007-01-01

    In May 2005 Krsko NPP initiated the Radioactive Waste Characterization Project and commissioned its realization to the consulting company Enconet International, Zagreb. The Agency for Radwaste Management was invited to participate on the Project. The Project was successfully closed out in August 2006. The main Project goal consisted of systematization the existing and gathering the missing radiological, chemical, physical, mechanical, thermal and biological information and data on radioactive waste. In a general perspective, the Project may also be considered as a part of broader scope of activities to support state efforts to find a disposal solution for radioactive waste in Slovenia. The operational low and intermediate level radioactive waste has been structured into 6 waste streams that contain evaporator concentrates and tank sludges, spent ion resins, spent filters, compressible and non-compressible waste as well as specific waste. For each of mentioned waste streams, process schemes have been developed including raw waste, treatment and conditioning technologies, waste forms, containers and waste packages. In the paper the main results of the Characterization Project will be briefly described. The results will indicate that there are 17 different types of raw waste that have been processed by applying 9 treatment/conditioning technologies. By this way 18 different waste forms have been produced and stored into 3 types of containers. Within each type of container several combinations should be distinguished. Considering all of this, there are 34 different types of waste packages altogether that are currently stored in the Solid Radwaste Storage Facility at the Krsko NPP site. Because of these findings a new identification system has been recommended and consequently the improvement of the existing database on radioactive waste has been proposed. The potential areas of further in depth characterization are indicated. In the paper a brief description on the

  13. Radioactive waste management in Tanzania

    International Nuclear Information System (INIS)

    Banzi, F.P.; Bundala, F.M.; Nyanda, A.M.; Msaki, P.

    2002-01-01

    Radioactive waste, like many other hazardous wastes, is of great concern in Tanzania because of its undesirable health effects. The stochastic effects due to prolonged exposure to ionizing radiation produce cancer and hereditary effects. The deterministic effects due to higher doses cause vomiting, skin reddening, leukemia, and death to exposed victims. The aim of this paper is to give an overview of the status of radioactive wastes in Tanzania, how they are generated and managed to protect humans and the environment. As Tanzania develops, it is bound to increase the use of ionizing radiation in research and teaching, industry, health and agriculture. Already there are more than 42 Centers which use one form of radioisotopes or another for these purposes: Teletherapy (Co-60), Brach-therapy (Cs-137, Sr-89), Nuclear Medicine (P-32, Tc-99m, 1-131, 1-125, Ga-67, In-111, Tl-206), Nuclear gauge (Am-241, Cs- 137, Sr-90, Kr-85), Industrial radiography (Am-241, C-137, Co-60, lr-92), Research and Teaching (1-125, Am241/Be, Co-60, Cs-137, H-3 etc). According to IAEA definition, these radioactive sources become radioactive waste if they meet the following criteria: if they have outlived their usefulness, if they have been abandoned, if they have been displaced without authorization, and if they contaminate other substances. Besides the origin of radioactive wastes, special emphasis will also be placed on the existing radiation regulations that guide disposal of radioactive waste, and the radioactive infrastructure Tanzania needs for ultimate radioactive waste management. Specific examples of incidences (theft, loss, abandonment and illegal possession) of radioactive waste that could have led to serious deterministic radiation effects to humans will also be presented. (author)

  14. Treatment of Radioactive Gaseous Waste

    International Nuclear Information System (INIS)

    2014-07-01

    Radioactive waste, with widely varying characteristics, is generated from the operation and maintenance of nuclear power plants, nuclear fuel cycle facilities, research laboratories and medical facilities. The waste needs to be treated and conditioned as necessary to provide waste forms acceptable for safe storage and disposal. Although radioactive gaseous radioactive waste does not constitute the main waste flow stream at nuclear fuel cycle and radioactive waste processing facilities, it represents a major source for potential direct environmental impact. Effective control and management of gaseous waste in both normal and accidental conditions is therefore one of the main issues of nuclear fuel cycle and waste processing facility design and operation. One of the duties of an operator is to take measures to avoid or to optimize the generation and management of radioactive waste to minimize the overall environmental impact. This includes ensuring that gaseous and liquid radioactive releases to the environment are within authorized limits, and that doses to the public and the effects on the environment are reduced to levels that are as low as reasonably achievable. Responsibilities of the regulatory body include the removal of radioactive materials within authorized practices from any further regulatory control — known as clearance — and the control of discharges — releases of gaseous radioactive material that originate from regulated nuclear facilities during normal operation to the environment within authorized limits. These issues, and others, are addressed in IAEA Safety Standards Series Nos RS-G-1.7, WS-G-2.3 and NS-G-3.2. Special systems should be designed and constructed to ensure proper isolation of areas within nuclear facilities that contain gaseous radioactive substances. Such systems consist of two basic subsystems. The first subsystem is for the supply of clean air to the facility, and the second subsystem is for the collection, cleanup and

  15. Disposal of radioactive wastes. Chapter 11

    International Nuclear Information System (INIS)

    Skitt, J.

    1979-01-01

    An account is given of the history and present position of legislation in the United Kingdom on the disposal of radioactive wastes. The sections are headed: introduction and definitions; history; the Radioactive Substances Act 1960; disposal of solid radioactive wastes through Local Authority services; function of Local Authorities; exemptions; national radioactive waste disposal service; incidents involving radioactivity. (U.K.)

  16. Startup and operation of a plant-scale continuous glass melter for vitrification of Savannah River Plant simulated waste

    International Nuclear Information System (INIS)

    Willis, T.A.

    1980-01-01

    The reference process for disposal of radioactive waste from the Savannah River Plant is vitrification of the waste in borosilicate glass in a continuous glass melter. Design, startup, and operation of a plant-scale developmental melter system are discussed

  17. Radioactive Waste Management Objectives

    International Nuclear Information System (INIS)

    2011-01-01

    considered and the specific goals to be achieved at different stages of implementation, all of which are consistent with the Basic Principles. The four Objectives publications include Nuclear General Objectives, Nuclear Power Objectives, Nuclear Fuel Cycle Objectives, and Radioactive Waste Management and Decommissioning Objectives. This publication sets out the objectives that need to be achieved in the area of radioactive waste management, including decommissioning and environmental remediation, to ensure that the Nuclear Energy Basic Principles are satisfied.

  18. Radioactive waste management and disposal

    International Nuclear Information System (INIS)

    Kaluzny, Y.

    1994-01-01

    The public has demonstrated interest and even concern for radioactive waste. A fully demonstrated industrial solution already exists for 90% of the waste generated by the nuclear industry. Several solutions are currently under development for long-term management of long-lived waste. They could be implemented on an industrial scale within twenty years. The low volumes of this type of waste mean there is plenty of time to adopt a solution. (author). 5 photos

  19. Entrapment process of radioactive gaseous wastes

    International Nuclear Information System (INIS)

    Gagneraud, Francis; Gagneraud, Michel.

    1981-01-01

    Process for collecting chemically inert gaseous radioactive waste in melted substances, whereby the gaseous waste is injected under pressure in a molten substance to its saturation point followed by fast cooling. This substance is constituted of glass, ceramics, metallurgical drosses and slag masses in fusion. Its cooling is carried out by quenching by means of running water or a gas fluid, or by casting into vessels with great thermal inertia such as cast iron or similar, before recovery and confinement in receptacles for storage [fr

  20. The radioactive waste management conference

    International Nuclear Information System (INIS)

    Fareeduddin, S.; Hirling, J.

    1983-01-01

    The international conference on radioactive waste management was held in Seattle, Washington, from 16 to 20 May 1983. The response was gratifying, reflecting world-wide interest: it was attended by 528 participants from 29 Member States of the IAEA and eight international organizations. The conference programme was structured to permit reviews and presentation of up-to-date information on five major topics: - waste management policy and its implementation: national and international approaches; legal, economic, environmental, and social aspects (four sessions with 27 papers from 16 countries and four international organizations); - handling, treatment, and conditioning of wastes from nuclear facilities, nuclear power plants and reprocessing plants, including the handling and treatment of gaseous wastes and wastes of specific types (five sessions with 35 papers); - storage and underground disposal of radioactive wastes: general, national concepts, underground laboratories, and designs of repositories for high-level, and low- and intermediate-level waste disposal (five sessions with 35 papers); - environmental and safety assessment of waste management systems: goals methodologies, assessments for geological repositories, low- and intermediate-level wastes, and mill tailings (four sessions with 26 papers); - radioactive releases to the environment from nuclear operations: status and perspectives, environmental transport processes, and control of radioactive waste disposal into the environment (three sessions with 23 papers)

  1. Radioactive waste mangement in Canada

    International Nuclear Information System (INIS)

    Didyk, J.P.

    1976-01-01

    The objectives of the Canadian radioactive waste management program are to manage the wastes so that the potential hazards of the material are minimized, and to manage the wastes in a manner which places the minimum possible burden on future generations. The Atomic Energy Control Board regulates all activities in the nuclear field in Canada, including radioactive waste management facility licensing. The Atomic Energy Control Act authorizes the Board to make rules for regulating its proceedings and the performance of its functions. The Atomic Energy Control Regulations define basic regulatory requirements for the licensing of facilities, equipment and materials, including requirements for records and inspection, for security and for health and safety

  2. Low-level radioactive wastes

    International Nuclear Information System (INIS)

    Garbay, H.; Chapuis, A.M.

    1988-01-01

    During dismantling operations of nuclear facilities radioctive and non radioactive wastes are produced. The distinction between both kinds of wastes is not easy. In each dismantling operation special care and rules are defined for the separation of wastes. Each case must be separately studied. The volume and the surface activites are analyzed. Part of the wastes had been disposed in a public environment. The regulations, the international recommendations, thetheoretical and experimental investigations in this field are presented. A regulation principle and examples of radioactivity limits, on the basis of international recommendations, are provided. Those limits are calculated from individual radiation dose that may reach human beings [fr

  3. Progress on Radioactive Waste Treatment Facilities Construction

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    In 2011, five projects were undertaken by radioactive waste projects management department, which are "Cold Commissioning of the Pilot Project on Radioactive Waste Retrieval and Conditioning (abbreviation 'Pilot Project')", "Radioactive Ventilation Project Construction (abbreviation 'Ventilation

  4. Radioactive waste management - with evidence

    International Nuclear Information System (INIS)

    1988-01-01

    The select committee was appointed to report on the present (1988) situation and future prospects in the field of radioactive waste management in the European Community. The report covers all aspects of the subject. After an introduction the parts of the report are concerned with the control of radiation hazards, the nuclear fuel cycle and radioactive waste, the control of radioactive effluents, storage and disposal of solid radioactive wastes, research programmes, surface storage versus deep geological disposal of long-term wastes, the future of reprocessing and the public debate. Part 10 is a resume of the main conclusions and recommendations. It is recommended that the House of Lords debate the issue. The oral and written evidence presented to the committee is included in the report. (U.K.)

  5. Geological Disposal of Radioactive Waste

    International Nuclear Information System (INIS)

    Dody, A.; Klein, Ben; David, O.

    2014-01-01

    Disposal of radioactive waste imposes complicated constrains on the regulator to ensure the isolation of radioactive elements from the biosphere. The IAEA (1995) states that T he objective of radioactive waste management is to deal with radioactive waste in a manner that protects human health and the environment now and the future without imposing undue burdens on future generation . The meaning of this statement is that the operator of the waste disposal facilities must prove to the regulator that in routine time and in different scenarios the dose rate to the public will not exceed 0.3 mSv/y in the present and in the future up to 10,000 years

  6. Radioactive waste management in France

    International Nuclear Information System (INIS)

    Pradel, J.

    1975-01-01

    The different stages of radioactive waste production are examined: ore production, reactor operation, reprocessing plants. The treatment and storage methods used and the French realizations relative to these problems are described [fr

  7. Radioactive waste management in Belgium

    International Nuclear Information System (INIS)

    Detilleux, E.

    1984-01-01

    The first part of this paper briefly describes the nuclear industry in Belgium and the problem of radioactive wastes with regard to their quality and quantity. The second part emphasizes the recent guidelines regarding the management of the nuclear industry in general and the radioactive wastes in particular. In this respect, important tasks are the reinforcement of administrative structures with regard to the supervision and the control of nuclear activities, the establishment of a mixed company entrusted with the covering of the needs of nuclear plants in the field of nuclear fuels and particularly the setting up of a public autonomous and specialized organization, the 'Public Organization for the Management of Radioactive Waste and Fissile Materials', in short 'O.N.D.R.A.F.'. This organization is in charge of the management of the transport, the conditioning, the storage and the disposal of radioactive wastes. (Auth.)

  8. World ocean and radioactive wastes

    International Nuclear Information System (INIS)

    Kiknadze, O.E.; Sivintsev, Yu.V.

    2000-01-01

    The radioecological situation that took shape in the Arctic, North Atlantic Ocean and Far East regions as a result of radioactive waste marine disposal was assessed. Accurate account of radionuclides formation and decay in submerged water-water reactors of nuclear submarines suggests that total activity of radioactive waste disposed near the Novaya Zemlya amounted to 107 kCi by the end of 1999. Activity of radioactive waste disposed in the North Atlantic currently is not in excess of 430 kCi. It is pointed out that the Far East region heads the list in terms of total activity disposed (529 kCi). Effective individual dose for critical groups of population in the Arctic, North Atlantic and Far East regions was determined. The conclusion was made that there is no detrimental effect of the radioactive waste disposed on radioecological situation in the relevant areas [ru

  9. Method of solidifying radioactive wastes

    International Nuclear Information System (INIS)

    Fukazawa, Tetsuo; Ootsuka, Masaharu; Uetake, Naoto; Ozawa, Yoshihiro.

    1984-01-01

    Purpose: To prepare radioactive solidified wastes excellent in strength, heat resistance, weather-proof, water resistance, dampproof and low-leaching property. Method: A hardening material reactive with alkali silicates to form less soluble salts is used as a hardener for alkali silicates which are solidification filler for the radioactive wastes, and mixed with cement as a water absorbent and water to solidify the radioactive wastes. The hardening agent includes, for example, CaCO 3 , Ca(ClO 4 ) 2 , CaSiF 6 and CaSiO 3 . Further, in order to reduce the water content in the wastes and reduce the gap ratio in the solidification products, the hardener adding rate, cement adding rate and water content are selected adequately. As the result, solidification products can be prepared with no deposition of easily soluble salts to the surface thereof, with extremely low leaching of radioactive nucleides. (Kamimura, M.)

  10. Radioactive waste processing and disposal

    International Nuclear Information System (INIS)

    1980-01-01

    This compilation contains 4144 citations of foreign and domestic reports, journal articles, patents, conference proceedings, and books pertaining to radioactive waste processing and disposal. Five indexes are provided: Corporate Author, Personal Author, Subject, Contract Number, and Report Number

  11. Radioactive waste management in perspective

    International Nuclear Information System (INIS)

    1996-01-01

    This report drafted by the Nuclear Energy Agency (NEA) deals with the basic principles and the main stages of radioactive waste management. The review more precisely focuses on what relates to environment protection, safety assessment, financing, social issues, public concerns and international co-operation. An annex finally summarises the radioactive waste management programs that are implemented in 15 of the NEA countries. (TEC). figs

  12. Method of solidifying radioactive wastes

    International Nuclear Information System (INIS)

    Tomita, Toshihide; Minami, Yuji; Matsuura, Hiroyuki; Kageyama, Hisashi; Kobori, Junzo.

    1984-01-01

    Purpose: To perform the curing sufficiently even when copper hydroxide that interferes the curing reaction is contained in radioactive wastes. Method: Solidification of radioactive wastes containing copper hydroxide using thermoset resins is carried out under the presence of an alkaline material. The thermoset resin used herein is an polyester resin comprising unsaturated polyester and a polymerizable monomer. The alkaline substance usable herein can include powder or an aqueous solution of hydroxides or oxides of sodium, magnesium, calcium or the like. (Yoshino, Y.)

  13. NRI's research on radioactive wastes

    International Nuclear Information System (INIS)

    Alexa, J.; Dlouhy, Z.; Kepak, F.; Kourim, V.; Napravnik, J.; Razga, J.; Ralkova, J.; Uher, E.; Vojtech, O.

    1976-01-01

    A survey is given (including 41 references) of work carried out at the Nuclear Research Institute. Discussed are sorption processes (a selective sorbent for 90 Sr based on BaSO 4 , etc.), sorption on inorganic ion exchangers (heteropolyacid salts, ferrocyanides for 137 Cs capture), on organic cation exchangers (separation of lanthanides), electrocoagulation. The process is described of vitrification of highly radioactive wastes, the arrest of emissions, the deposition of radioactive wastes and surface decontamination. (M.K.)

  14. Radioactive waste problems in Russia

    International Nuclear Information System (INIS)

    Bridges, O.; Bridges, J.W.

    1995-01-01

    The collapse of the former Soviet Union, with the consequent shift to a market driven economy and demilitarisation, has had a profound effect on the nuclear and associated industries. The introduction of tighter legislation to control the disposal of radioactive wastes has been delayed and the power and willingness of the various government bodies responsible for its regulation is in doubt. Previously secret information is becoming more accessible and it is apparent that substantial areas of Russian land and surface waters are contaminated with radioactive material. The main sources of radioactive pollution in Russia are similar to those in many western countries. The existing atomic power stations already face problems in the storage and safe disposal of their wastes. These arise because of limited on site capacity for storage and the paucity of waste processing facilities. Many Russian military nuclear facilities also have had a sequence of problems with their radioactive wastes. Attempts to ameliorate the impacts of discharges to important water sources have had variable success. Some of the procedures used have been technically unsound. The Russian navy has traditionally dealt with virtually all of its radioactive wastes by disposal to sea. Many areas of the Barents, Kola and the Sea of Japan are heavily contaminated. To deal with radioactive wastes 34 large and 257 small disposal sites are available. However, the controls at these sites are often inadequate and illegal dumps of radioactive waste abound. Substantial funding will be required to introduce the necessary technologies to achieve acceptable standards for the storage and disposal of radioactive wastes in Russia. (author)

  15. Development of radioactive waste treatment technique

    International Nuclear Information System (INIS)

    Kikuchi, Makoto; Amamiya, Shigeru; Yusa, Hideo.

    1984-01-01

    The techniques of radioactive waste treatment are generally reviewed, placing emphasis on volume reduction and solidification techniques. After a brief description on the general process of radioactive waste treatment, some special technologies being developed by Hitachi Ltd. are explained. From the viewpoints of the volume reduction, long term management and final disposal of wastes, the pelletization of dried waste and the solidification with inorganic substances are considered. One of the features of the pelletization system is to treat various kinds of wastes such as concentrated liquid wastes and used resins by the same system. The flow diagram of the system and its special features are shown. The volume reduction achieved by this system as compared to the conventional method is about 1/7. The first commercial plant for the treatment of concentrated liquid waste is scheduled to begin operation in June, 1984. As for the solidification technique for waste disposal, the use of cement glass is considered. The solidification system being developed is shortly described. (Aoki, K.)

  16. Conversion of radioactive ferrocyanide compounds to immobile glasses

    International Nuclear Information System (INIS)

    Schulz, W.W.; Dressen, A.L.

    1977-01-01

    Complex radioactive ferrocyanide compounds result from the scavenging of cesium from waste products produced in the chemical reprocessing of nuclear fuel. These ferrocyanides, in accordance with this process, are converted to an immobile glass, resistant to leaching by water, by fusion together with sodium carbonate and a mixture of (a) basalt and boron trioxide (B 2 O 3 ) or (b) silica (SiO 2 ) and lime (CaO). 7 claims

  17. Television systems for radioactive waste management

    International Nuclear Information System (INIS)

    Quartly, J.R.

    1989-01-01

    Radiation-tolerant television cameras, widely used for the inspection of nuclear plants, are now used for monitoring radioactive waste management processes. Two systems are described in this paper that differ in the methods of maintaining the camera equipment. At the British Nuclear Fuels plc (BNFL) Sellafield plant, a major capital investment program is under way that includes plants for spent-fuel reprocessing and radioactive waste management. The Windscale vitrification plant (WVP) will convert highly active liquid waste to a solid glass-like form. The WVP television system was based on in-cell cameras designed to be removable by remote-handling equipment. The plant to encapsulate medium active solid waste, encapsulation plant 1 (EP1) used through-wall and through-roof viewing systems with a glass viewing dome as the biological shield, allowing the camera and optics to be withdrawn to a safe area for maintenance. Both systems used novel techniques to obtain a record of the waste-processing operations. The WVP system used a microcomputer to overlay reference information onto the television picture and a motion detector to automatically trigger the video recording. The television system for EP1 included automatic character recognition to generate a computer data record of drum serial numbers

  18. High Level Radioactive Waste Management

    International Nuclear Information System (INIS)

    1991-01-01

    The proceedings of the second annual international conference on High Level Radioactive Waste Management, held on April 28--May 3, 1991, Las Vegas, Nevada, provides information on the current technical issue related to international high level radioactive waste management activities and how they relate to society as a whole. Besides discussing such technical topics as the best form of the waste, the integrity of storage containers, design and construction of a repository, the broader social aspects of these issues are explored in papers on such subjects as conformance to regulations, transportation safety, and public education. By providing this wider perspective of high level radioactive waste management, it becomes apparent that the various disciplines involved in this field are interrelated and that they should work to integrate their waste management activities. Individual records are processed separately for the data bases

  19. Radioactive wastes and their disposal

    International Nuclear Information System (INIS)

    Neumann, L.

    1984-01-01

    The classification of radioactive wastes is given and the achievements evaluated in the disposal of radioactive wastes from nuclear power plants. An experimental pilot unit was installed at the Jaslovske Bohunice nuclear power plant for the bituminization of liquid radioactive wastes. UJV has developed a mobile automated high-output unit for cementation. In 1985 the unit will be tested at the Jaslovske Bohunice and the Dukovany nuclear power plants. A prototype press for processing solid wastes was manufactured which is in operation at the Jaslovske Bohunice plant. A solidification process for atypical wastes from long-term storage of spent fuel elements has been developed to be used for the period of nuclear power plant decommissioning. (E.S.)

  20. Overview of radioactive waste management

    International Nuclear Information System (INIS)

    Ritter, G.L.

    1980-01-01

    The question of what to do with radioactive wastes is discussed. The need to resolve this issue promptly is pointed out. Two significant events which have occurred during the Carter administration are discussed. An Interagency Review Group (IRG) on waste management was formed to formulate recommendations leading to the establishment of a National policy for managing radioactive wastes. The technical findings in the IRG report are listed. The author points out some issues not addressed by the report. President Carter issued a national policy statement on Radioactive Waste Management in February 1980. The most significant elements of this statement are summarized. The cancellation of the Waste Isolation Pilot Plant is currently meeting opposition in Congress. This and other items in the National Policy Statement are discussed

  1. Handling and disposing of radioactive waste

    International Nuclear Information System (INIS)

    Trauger, D.B.

    1983-01-01

    Radioactive waste has been separated by definition into six categories. These are: commercial spent fuel; high-level wastes; transuranium waste; low-level wastes; decommissioning and decontamination wastes; and mill tailings and mine wastes. Handling and disposing of these various types of radioactive wastes are discussed briefly

  2. Solidification method of radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Baba, Tsutomu; Chino, Koichi; Sasahira, Akira; Ikeda, Takashi

    1992-07-24

    Metal solidification material can completely seal radioactive wastes and it has high sealing effect even if a trace amount of evaporation should be caused. In addition, the solidification operation can be conducted safely by using a metal having a melting point of lower than that of the decomposition temperature of the radioactive wastes. Further, the radioactive wastes having a possibility of evaporation and scattering along with oxidation can be solidified in a stable form by putting the solidification system under an inert gas atmosphere. Then in the present invention, a metal is selected as a solidification material for radioactive wastes, and a metal, for example, lead or tin having a melting point of lower than that of the decomposition temperature of the wastes is used in order to prevent the release of the wastes during the solidification operation. Radioactive wastes which are unstable in air and scatter easily, for example, Ru or the like can be converted into a stable solidification product by conducting the solidification processing under an inert gas atmosphere. (T.M.).

  3. Test plan for glass melter system technologies for vitrification of hign-sodium content low-level radioactive liquid waste, Project No. RDD-43288

    International Nuclear Information System (INIS)

    Higley, B.A.

    1995-01-01

    This document provides a test plan for the conduct of combustion fired cyclone vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System, Low-Level Waste Vitrification Program. The vendor providing this test plan and conducting the work detailed within it is the Babcock ampersand Wilcox Company Alliance Research Center in Alliance, Ohio. This vendor is one of seven selected for glass melter testing

  4. Characterization of glass and glass ceramic nuclear waste forms

    International Nuclear Information System (INIS)

    Lutze, W.; Borchardt, J.; De, A.K.

    1979-01-01

    Characteristics of solidified nuclear waste forms, glass and glass ceramic compositions and the properties (composition, thermal stability, crystallization, phase behavior, chemical stability, mechanical stability, and radiation effects) of glasses and glass ceramics are discussed. The preparation of glass ceramics may be an optional step for proposed vitrification plants if tailored glasses are used. Glass ceramics exhibit some improved properties with respect to glasses. The overall leach resistance is similar to that of glasses. An increased leach resistance may become effective for single radionuclides being hosted in highly insoluble crystal phases mainly when higher melting temperatures are applicable in order to get more leach resistant residual glass phases. The development of glass ceramic is going on. The technological feasibility is still to be demonstrated. The potential gain of stability when using glass ceramics qualifies the material as an alternative nuclear waste form

  5. Wastes based glasses and glass-ceramics

    Directory of Open Access Journals (Sweden)

    Barbieri, L.

    2001-12-01

    Full Text Available Actually, the inertization, recovery and valorisation of the wastes coming from municipal and industrial processes are the most important goals from the environmental and economical point of view. An alternative technology capable to overcome the problem of the dishomogeneity of the raw material chemical composition is the vitrification process that is able to increase the homogeneity and the constancy of the chemical composition of the system and to modulate the properties in order to address the reutilization of the waste. Moreover, the glasses obtained subjected to different controlled thermal treatments, can be transformed in semy-cristalline material (named glass-ceramics with improved properties with respect to the parent amorphous materials. In this review the tailoring, preparation and characterization of glasses and glass-ceramics obtained starting from municipal incinerator grate ash, coal and steel fly ashes and glass cullet are described.

    Realmente la inertización, recuperación y valorización de residuos que proceden de los procesos de incineración de residuos municipales y de residuos industriales son metas importantes desde el punto de vista ambiental y económico. Una tecnología alternativa capaz de superar el problema de la heterogeneidad de la composición química de los materiales de partida es el proceso de la vitrificación que es capaz de aumentar la homogeneidad y la constancia de la composición química del sistema y modular las propiedades a fin de la reutilización del residuo. En este artículo se presentan los resultados de vitrificación en que los vidrios fueron sometidos a tratamientos térmicos controlados diferentes, de manera que se transforman en materiales semicristalinos (también denominados vitrocerámicos con mejores propiedades respecto a los materiales amorfos originales. En esta revisión se muestra el diseño, preparación y caracterización de vidrios y vitrocerámicos partiendo de

  6. Environmental aspects of commercial radioactive waste management

    International Nuclear Information System (INIS)

    1979-05-01

    Volume 2 contains chapters 6 through 10: environmental effects related to radioactive waste management associated with LWR fuel reprocessing - mixed-oxide fuel fabrication plant; environmental effects related to transporting radioactive wastes associated with LWR fuel reprocessing and fabrication; environmental effects related to radioactive waste management associated with LWR fuel reprocessing - retrievable waste storage facility; environmental effects related to geologic isolation of LWR fuel reprocessing wastes; and integrated systems for commercial radioactive waste management

  7. Method of disposing radioactive wastes

    International Nuclear Information System (INIS)

    Isozaki, Kei.

    1983-01-01

    Purpose : To enable safety ocean disposal of radioactive wastes by decreasing the leaching rate of radioactive nucleides, improving the quick-curing nature and increasing the durability. Method : A mixture comprising 2 - 20 parts by weight of alkali metal hydroxide and 100 parts by weight of finely powdered aqueous slags from a blast furnace is added to radioactive wastes to solidify them. In the case of medium or low level radioactive wastes, the solidification agent is added by 200 parts by weight to 100 parts by weight of the wastes and, in the case of high level wastes, the solidification agent is added in such an amount that the wastes occupy about 20% by weight in the total of the wastes and the solidification agent. Sodium hydroxide used as the alkali metal hydroxide is partially replaced with sodium carbonate, a water-reducing agent such as lignin sulfonate is added to improve the fluidity and suppress the leaching rate and the wastes are solidified in a drum can. In this way, corrosions of the vessel can be suppressed by the alkaline nature and the compression strength, heat stability and the like of the product also become excellent. (Sekiya, K.)

  8. Radioactive waste management in Canada

    International Nuclear Information System (INIS)

    Hawley, N.J.

    1986-09-01

    This bibliography is an up-date to AECL-6186(Rev 3), 1952-1982, 'Radioactive Waste Management in Canada AECL Publications and Other Literature' compiled by Dianne Wallace. Canadian publications from outside contractors concerning the Canadian Nuclear Fuel Waste Management Program are included in addition to Atomic Energy of Canada Limited reports and papers. 252 refs

  9. The incineration of radioactive waste

    International Nuclear Information System (INIS)

    Thegerstroem, C.

    1980-03-01

    In this study, made on contract for the Swedish Nuclear Power Inspectorate, different methods for incineration of radioactive wastes are reviewed. Operation experiences and methods under development are also discussed. The aim of incineration of radioactive wastes is to reduce the volume and weight of the wastes. Waste categories most commonly treated by incineration are burnable solid low level wastes like trash wastes consisting of plastic, paper, protective clothing, isolating material etc. Primarily, techniques for the incineration of this type of waste are described but incineration of other types of low level wastes like oil or solvents and medium level wastes like ion-exchange resins is also briefly discussed. The report contains tables with condensed data on incineration plants in different countries. Problems encountered, experiences and new developments are reviewed. The most important problems in incineration of radioactive wastes have been plugging and corrosion of offgas systems, due to incomplete combustion of combustion of materials like rubber and PVC giving rise to corrosive gases, combined with inadequate materials of construction in heat-exchangers, channels and filter housings. (author)

  10. Radioactive waste management and disposal

    International Nuclear Information System (INIS)

    Simon, R.; Orlowski, S.

    1980-01-01

    The first European Community conference on Radioactive Waste Management and Disposal was held in Luxembourg, where twenty-five papers were presented by scientists involved in European Community contract studies and by members of the Commission's scientific staff. The following topics were covered: treatment and conditioning technology of solid intermediate level wastes, alpha-contaminated combustible wastes, gaseous wastes, hulls and dissolver residues and plutonium recovery; waste product evaluation which involves testing of solidified high level wastes and other waste products; engineering storage of vitrified high level wastes and gas storage; and geological disposal in salt, granite and clay formations which includes site characterization, conceptual repository design, waste/formation interactions, migration of radionuclides, safety analysis, mathematical modelling and risk assessment

  11. Method of processing radioactive wastes

    International Nuclear Information System (INIS)

    Takahashi, Toshihiko; Maruko, Morihisa; Takamura, Yoshiyuki.

    1981-01-01

    Purpose: To effectively separate radioactive claddings from the slurry of wasted ion exchange resins containing radioactive claddings. Method: Wasted ion exchange resins having radioactive claddings (fine particles of iron oxides or hydroxide adhered with radioactive cobalt) are introduced into a clad separation tank. Sulfuric acid or sodium hydroxide is introduced to the separation tank to adjust the pH value to 3 - 6. Then, sodium lauryl sulfate is added for capturing claddings and airs are blown from an air supply nozzle to generate air bubbles. The claddings are detached from the ion exchange resins and adhered to the air bubbles. The air bubbles adhered with the claddings float up to the surface of the liquid wastes and then forced out of the separation tank. (Ikeda, J.)

  12. Method of processing radioactive wastes

    International Nuclear Information System (INIS)

    Katada, Katsuo.

    1986-01-01

    Purpose: To improve the management for radioactive wastes containers thereby decrease the amount of stored matters by arranging the radioactive wastes containers in the order of their radioactivity levels. Method: The radiation doses of radioactive wastes containers arranged in the storing area before volume-reducing treatment are previously measured by a dosemeter. Then, a classifying machine is actuated to hoist the containers in the order to their radiation levels and the containers are sent out passing through conveyor, surface contamination gage, weight measuring device and switcher to a volume-reducing processing machine. The volume-reduced products are packed each by several units to the storing containers. Thus, the storing containers after stored for a certain period of time can be transferred in an assembled state. (Kawakami, Y.)

  13. Method for burning radioactive wastes

    International Nuclear Information System (INIS)

    Hattori, Akinori; Tejima, Takaya.

    1987-01-01

    Purpose: To completely process less combustible radioactive wastes with no excess loads on discharge gas processing systems and without causing corrosions to furnace walls. Method: Among combustible radioactive wastes, chlorine-containing less combustible wastes such as chlorine-containing rubbers and vinyl chlorides, and highly heat generating wastes not containing chloride such as polyethylene are selectively packed into packages. While on the other hand, packages of less combustible wastes are charged into a water-cooled jacket type incinerator intermittently while controlling the amount and the interval of charging so that the temperature in the furnace will be kept to lower than 850 deg C for burning treatment. Directly after the completion of the burning, the packed highly heat calorie producing wastes are charged and subjected to combustion treatment. (Yoshihara, H.)

  14. Radioactive waste shredding: Preliminary evaluation

    International Nuclear Information System (INIS)

    Soelberg, N.R.; Reimann, G.A.

    1994-07-01

    The critical constraints for sizing solid radioactive and mixed wastes for subsequent thermal treatment were identified via a literature review and a survey of shredding equipment vendors. The types and amounts of DOE radioactive wastes that will require treatment to reduce the waste volume, destroy hazardous organics, or immobilize radionuclides and/or hazardous metals were considered. The preliminary steps of waste receipt, inspection, and separation were included because many potential waste treatment technologies have limits on feedstream chemical content, physical composition, and particle size. Most treatment processes and shredding operations require at least some degree of feed material characterization. Preliminary cost estimates show that pretreatment costs per unit of waste can be high and can vary significantly, depending on the processing rate and desired output particle size

  15. Nuclear waste disposal: alternatives to solidification in glass proposed

    International Nuclear Information System (INIS)

    Kerr, R.A.

    1979-01-01

    More than a quarter-million cubic meters of liquid radioactive wastes are now being held at government installations awaiting final disposal. During the past 20 years, the disposal plan of choice has been to incorporate the 40 to 50 radioactive elements dissolved in liquid wastes into blocks of glass, seal the glass in metal canisters, and insert the canisters into deep, geologically stable salt beds. Over the last few years, some geologists and materials scientists have become concerned that perhaps not enough is known yet about the interaction of waste, container, and salt (or any rock) to have a reasonable assurance that the hazardous wastes will be contained successfully. The biggest advantage of glass at present is the demonstrated practicality of producing large, highly radioactive blocks of it. The frontrunner as a successor to glass is ceramics, which are nonmetallic crystalline materials formed at high temperature, such as chinaware or natural minerals. An apparent advantage of ceramics is that they already have an ordered atomic structure, whose properties can be tailored to a particular waste element and to conditions of a specific disposal site. A ceramic tailored for waste disposal called supercalcine-ceramic has been developed. It was emphasized that the best minerals for waste solidification may be those that have proved most stable under natural conditions over geologic time. Disadvantage to ceramics are radiation damage and transmutation. However, it is now obvious that some ceramics are more stable than glass under certain conditions. Metal-encapsulated ceramic, called cermet, is being developed as a waste form. Cermets are considerably more resistant at 100 0 C than a borosilicate waste glass. Researchers are now testing prospective waste forms under the most extreme conditions that might prevail in a waste disposal site

  16. Final disposal of radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Kroebel, R [Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Projekt Wiederaufarbeitung und Abfallbehandlung; Krause, H [Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.). Abt. zur Behandlung Radioaktiver Abfaelle

    1978-08-01

    This paper discusses the final disposal possibilities for radioactive wastes in the Federal Republic of Germany and the related questions of waste conditioning, storage methods and safety. The programs in progress in neighbouring CEC countries and in the USA are also mentioned briefly. The autors conclude that the existing final disposal possibilities are sufficiently well known and safe, but that they could be improved still further by future development work. The residual hazard potential of radioactive wastes from fuel reprocessing after about 1000 years of storage is lower that of known inorganic core deposits.

  17. Industrial management of radioactive wastes

    International Nuclear Information System (INIS)

    Lavie, J.M.

    1984-01-01

    This article deals with the present situation in France concerning radioactive waste management. For the short and medium term, that is to say processing and disposal of low and medium level radioactive wastes, there are industrial processes giving all the guarantees for a safe containment, but improvements are possible. For the long term optimization of solution requires more studies of geologic formations. Realization emergency comes less from the waste production than the need to optimize the disposal techniques. An international cooperation exists. All this should convince the public opinion and should develop planning and realization [fr

  18. Radioactive waste below regulatory concern

    International Nuclear Information System (INIS)

    Neuder, S.M.

    1987-01-01

    The U.S. Nuclear Regulatory Commission (NRC) published two notices in the Federal Register concerning radioactive waste below regulatory concern. The first, a Commission Policy Statement and Implementation Plan published August 29, 1986, concerns petition to exempt specific radioactive waste streams from the regulations. The second, an Advanced Notice of Proposed Rulemaking published Decemger 2, 1986, addresses the concept of generic rulemaking by the NRC on radioactive wastes that are below regulatory concern. Radioactive waste determined to be below regulatory concern would not be subject to regulatory control and would not need to go to a licensed low-level radioactive waste disposal site. The Policy Statement and Implementation Plan describe (1) the information a petitioner should file in support of a petition to exempt a specific waste stream, (2) the decision criteria the Commission intends to use for judging the petition, and (3) the internal administrative procedures to use be followed in order to permit the Commission to act upon the petition in an expedited manner

  19. Radioactive Waste Management Program Activities in Croatia

    International Nuclear Information System (INIS)

    Matanic, R.

    2000-01-01

    The concept of radioactive waste management in Croatia comprises three major areas: management of low and intermediate level radioactive waste (LILRW), spent fuel management and decommissioning. All the work regarding radioactive waste management program is coordinated by Hazardous Waste Management Agency (APO) and Croatian Power Utility (HEP) in cooperation with other relevant institutions. Since the majority of work has been done in developing low and intermediate level radioactive waste management program, the paper will focus on this part of radioactive waste management, mainly on issues of site selection and characterization, repository design, safety assessment and public acceptance. A short description of national radioactive waste management infrastructure will also be presented. (author)

  20. CEGB's radioactive waste management strategy

    International Nuclear Information System (INIS)

    Passant, F.H.; Maul, P.R.

    1989-01-01

    The Central Electricity Generating Board (CEGB) produces low-level and intermediate-level radioactive wastes in the process of operating its eight Magnox and five Advanced Gas Cooled Reactor (AGR) nuclear power stations. Future wastes will also arise from a programme of Pressurised Water Reactors (PWRs) and the decommissioning of existing reactors. The paper gives details of how the UK waste management strategy is put into practice by the CEGB, and how general waste management principles are developed into strategies for particular waste streams. (author)

  1. Method of solidifying radioactive wastes

    International Nuclear Information System (INIS)

    Maeda, Masahiko; Kira, Satoshi; Watanabe, Naotoshi; Nagaoka, Takeshi; Akane, Junta.

    1982-01-01

    Purpose: To obtain solidification products of radioactive wastes having sufficient monoaxial compression strength and excellent in water durability upon ocean disposal of the wastes. Method: Solidification products having sufficient strength and filled with a great amount of radioactive wastes are obtained by filling and solidifying 100 parts by weight of chlorinated polyethylene resin and 100 - 500 parts by weight of particular or powderous spent ion exchange resin as radioactive wastes. The chlorinated polyethylene resin preferably used herein is prepared by chlorinating powderous or particulate polyethylene resin in an aqueous suspending medium or by chlorinating polyethylene resin dissolved in an organic solvent capable of dissolving the polyethylene resin, and it is crystalline or non-crystalline chlorinated polyethylene resin comprising 20 - 50% by weight of chlorine, non-crystalline resin with 25 - 40% by weight of chlorine being particularly preferred. (Horiuchi, T.)

  2. Radioactive waste management in Slovenia

    International Nuclear Information System (INIS)

    Fink, K.

    1992-01-01

    The problem of radioactive waste management is both scientifically and technically complex and also deeply emotional issue. In the last twenty years the first two aspects have been mostly resolved up to the point of safe implementation. In the Republic of Slovenia, certain fundamentalist approaches in politics and the use of radioactive waste problem as political marketing tool, make things even more complex. Public involvement in planning and development of radioactive waste management program must be perceived as essential for the success of the program. Education is a precursor to public comprehension and confidence which lead to adequate waste management decisions that will protect the public health, safety and environment without jeopardizing further progress and development. (author) [sl

  3. Standardization of radioactive waste categories

    International Nuclear Information System (INIS)

    1970-01-01

    A large amount of information about most aspects of radioactive waste management has been accumulated and made available to interested nations in recent years. The efficiency of this service has been somewhat hampered because the terminology used to describe the different types of radioactive waste has varied from country to country and indeed from installation to installation within a given country. This publication is the outcome of a panel meeting on Standardization of Radioactive Waste Categories. It presents a simple standard to be used as a common language between people working in the field of waste management at nuclear installations. The purpose of the standard is only to act as a practical tool for increasing efficiency in communicating, collecting and assessing technical and economical information in the common interest of all nations and the developing countries in particular. 20 refs, 1 fig., 3 tabs

  4. Underground radioactive waste disposal concept

    International Nuclear Information System (INIS)

    Frgic, L.; Tor, K.; Hudec, M.

    2002-01-01

    The paper presents some solutions for radioactive waste disposal. An underground disposal of radioactive waste is proposed in deep boreholes of greater diameter, fitted with containers. In northern part of Croatia, the geological data are available on numerous boreholes. The boreholes were drilled during investigations and prospecting of petroleum and gas fields. The available data may prove useful in defining safe deep layers suitable for waste repositories. The paper describes a Russian disposal design, execution and verification procedure. The aim of the paper is to discuss some earlier proposed solutions, and present a solution that has not yet been considered - lowering of containers with high level radioactive waste (HLW) to at least 500 m under the ground surface.(author)

  5. Plastic solidification of radioactive wastes

    International Nuclear Information System (INIS)

    Moriyama, Noboru

    1981-01-01

    Over 20 years have elapsed after the start of nuclear power development, and the nuclear power generation in Japan now exceeds the level of 10,000 MW. In order to meet the energy demands, the problem of the treatment and disposal of radioactive wastes produced in nuclear power stations must be solved. The purpose of the plastic solidification of such wastes is to immobilize the contained radionuclides, same as other solidification methods, to provide the first barrier against their move into the environment. The following matters are described: the nuclear power generation in Japan, the radioactive wastes from LWR plants, the position of plastic solidification, the status of plastic solidification in overseas countries and in Japan, the solidification process for radioactive wastes with polyethylene, and the properties of solidified products, and the leachability of radionuclides in asphalt solids. (J.P.N.)

  6. Research programme on radioactive wastes

    International Nuclear Information System (INIS)

    Eckhardt, A.; Hufschmid, P.; Jordi, S.; Schanne, M.; Vigfusson, J.

    2009-11-01

    This report for the Swiss Federal Department of the Environment, Transport, Energy and Communication (DETEC) takes a look at work done within the framework of the research programme on radioactive wastes. The paper discusses the development of various projects and the associated organisations involved. Both long-term and short-term topics are examined. The long-term aspects of handling radioactive wastes include organisation and financing as well as the preservation of know-how and concepts for marking the repositories. Communication with the general public on the matter is looked at along with public perception, opinion-making and acceptance. Waste storage concepts are looked at in detail and aspects such as environmental protection, monitoring concepts, retrievability and encasement materials are discussed. Finally, ethical and legal aspects of radioactive waste repositories are examined. The paper is completed with appendixes dealing with planning, co-ordination and the responsibilities involved

  7. Radioactive waste repository study

    International Nuclear Information System (INIS)

    1978-11-01

    This is the second part of a report of a preliminary study for AECL. It considers the requirements for an underground waste repository for the disposal of wastes produced by the Canadian Nuclear Fuel Program. The following topics are discussed with reference to the repository: 1) geotechnical assessment, 2) hydrogeology and waste containment, 3) thermal loading and 4) rock mechanics. (author)

  8. Method of volume-reducing processing for radioactive wastes

    International Nuclear Information System (INIS)

    Sato, Koei; Yamauchi, Noriyuki; Hirayama, Toshihiko.

    1985-01-01

    Purpose: To process the processing products of radioactive liquid wastes and burnable solid wastes produced from nuclear facilities into stable solidification products by heat melting. Method: At first, glass fiber wastes of contaminated air filters are charged in a melting furnace. Then, waste products obtained through drying, sintering, incineration, etc. are mixed with a proper amount of glass fibers and charged into the melting furnace. Both of the charged components are heated to a temperature at which the glass fibers are melted. The burnable materials are burnt out to provide a highly volume-reduced products. When the products are further heated to a temperature at which metals or metal oxides of a higher melting point than the glass fiber, the glass fibers and the metals or metal oxides are fused to each other to be combined in a molecular structure into more stabilized products. The products are excellent in strength, stability, durability and leaching resistance at ambient temperature. (Kamimura, M.)

  9. Radioactive liquid waste processing system

    International Nuclear Information System (INIS)

    Noda, Tetsuya; Kuramitsu, Kiminori; Ishii, Tomoharu.

    1997-01-01

    The present invention provides a system for processing radioactive liquid wastes containing laundry liquid wastes, shower drains or radioactive liquid wastes containing chemical oxygen demand (COD) ingredients and oil content generated from a nuclear power plant. Namely, a collecting tank collects radioactive liquid wastes. A filtering device is connected to the exit of the collective tank. A sump tank is connected to the exit of the filtering device. A powdery active carbon supplying device is connected to the collecting tank. A chemical fluid tank is connected to the collecting tank and the filtering device by way of chemical fluid injection lines. Backwarding pipelines connect a filtered water flowing exit of the filtering device and the collecting tank. The chemical solution is stored in the chemical solution tank. Then, radioactive materials in radioactive liquid wastes generated from a nuclear power plant are removed by the filtering device. The water quality standard specified in environmental influence reports can be satisfied. In the filtering device, when the filtering flow rate is reduced, the chemical fluid is supplied from the chemical fluid tank to the filtering device to recover the filtering flow rate. (I.S.)

  10. Classification of solid wastes as non-radioactive wastes

    International Nuclear Information System (INIS)

    Suzuki, Masahiro; Tomioka, Hideo; Kamike, Kozo; Komatu, Junji

    1995-01-01

    The radioactive wastes generally include nuclear fuels, materials contaminated with radioactive contaminants or neutron activation to be discarded. The solid wastes arising from the radiation control area in nuclear facilities are used to treat and stored as radioactive solid wastes at the operation of nuclear facilities in Japan. However, these wastes include many non-radioactive wastes. Especially, a large amount of wastes is expected to generate at the decommissioning of nuclear facilities in the near future. It is important to classify these wastes into non-radioactive and radioactive wastes. The exemption or recycling criteria of radioactive solid wastes is under discussion and not decided yet in Japan. Under these circumstances, the Nuclear Safety Committee recently decided the concept on the category of non-radioactive waste for the wastes arising from decommissioning of nuclear facilities. The concept is based on the separation and removal of the radioactively contaminated parts from radioactive solid wastes. The residual parts of these solid wastes will be treated as non-radioactive waste if no significant difference in radioactivity between the similar natural materials and materials removed the radioactive contaminants. The paper describes the procedures of classification of solid wastes as non-radioactive wastes. (author)

  11. Report on radioactive waste disposal

    International Nuclear Information System (INIS)

    1993-01-01

    The safe management of radioactive wastes constitutes an essential part of the IAEA programme. A large number of reports and conference proceedings covering various aspects of the subject have been issued. The Technical Review Committee on Underground Disposal (February 1988) recommended that the Secretariat issue a report on the state of the art of underground disposal of radioactive wastes. The Committee recommended the need for a report that provided an overview of the present knowledge in the field. This report covers the basic principles associated with the state of the art of near surface and deep geological radioactive waste disposal, including examples of prudent practice, and basic information on performance assessment methods. It does not include a comprehensive description of the waste management programmes in different countries nor provide a textbook on waste disposal. Such books are available elsewhere. Reviewing all the concepts and practices of safe radioactive waste disposal in a document of reasonable size is not possible; therefore, the scope of this report has been limited to cover essential parts of the subject. Exotic disposal techniques and techniques for disposing of uranium mill tailings are not covered, and only brief coverage is provided for disposal at sea and in the sea-bed. The present report provides a list of references to more specialized reports on disposal published by the IAEA as well as by other bodies, which may be consulted if additional information is sought. 108 refs, 22 figs, 2 tabs

  12. Radioactive waste management in Belgium

    International Nuclear Information System (INIS)

    Dejonghe, P.

    1977-01-01

    In 1975 the research association BELGOWASTE was founded in order to prepare a technical and administrative plan for radioactive waste management in Belgium and to take the preliminary steps for establishing an organization which would be responsible for this activity. The association made a survey of all forecasts concerning radioactive waste production by power reactors and the fuel cycle industry based on various schemes of development of the nuclear industry. From the technical point of view, the reference plan for waste management envisages: Purification at the production site of large volumes of low-level effluents; construction of a central facility for the treatment and intermediate storage of process concentrates (slurries, resins, etc.) and medium-level waste; centralization assumes the making of adequate arrangements for transporting waste before final treatment; maximum recovery of plutonium from waste and treatment of resiudal material by incineration at very high temperatures; treatment at the production site of high-level effluents from irradiated fuel reprocessing; construction of an underground long-term storage site for high-level treated waste and plutonium fuel fabrication waste; deep clay formations are at present preferred; disposal of low-level treated waste into the Atlantic ocean. It is intended to entrust the entire responsibility for treatment, disposal and storage of treated waste to a single body with participation by the State, the Nuclear Energy Research Centre (CEN/SCK), the electricity companies and Belgonucleaire. The partners intend to set up their facilities and services in the area of Mol [fr

  13. Radioactive waste gas processing systems

    International Nuclear Information System (INIS)

    Kita, Kaoru; Minemoto, Masaki; Takezawa, Kazuaki.

    1981-01-01

    Purpose: To effectively separate and remove only hydrogen from hydrogen gas-containing radioactive waste gases produced from nuclear power plants without using large scaled facilities. Constitution: From hydrogen gas-enriched waste gases which contain radioactive rare gases (Kr, Xe) sent from the volume control tank of a chemical volume control system, only the hydrogen is separated in a hydrogen separator using palladium alloy membrane and rare gases are concentrated, volume-decreased and then stored. In this case, an activated carbon adsorption device is connected at its inlet to the radioactive gas outlet of the hydrogen separator and opened at its outlet to external atmosphere. In this system, while only the hydrogen gas permeates through the palladium alloy membrane, other gases are introduced, without permeation, into the activated carbon adsorption device. Then, the radioactive rare gases are decayed by the adsorption on the activated carbon and then released to the external atmosphere. (Furukawa, Y.)

  14. Software for radioactive wastes database

    International Nuclear Information System (INIS)

    Souza, Eros Viggiano de; Reis, Luiz Carlos Alves

    1996-01-01

    A radioactive waste database was implemented at CDTN in 1991. The objectives are to register and retrieve information about wastes ge in 1991. The objectives are to register and retrieve information about wastes generated and received at the Centre in order to improve the waste management. Since 1995, the database has being reviewed and a software has being developed aiming at processing information in graphical environment (Windows 95 and Windows NT), minimising the possibility of errors and making the users access more friendly. It was also envisaged to ease graphics and reports edition and to make this database available to other CNEN institutes and even to external organizations. (author)

  15. Public debate on radioactive wastes

    International Nuclear Information System (INIS)

    2005-01-01

    The definition and implementation of safe and perennial solutions for the management of radioactive wastes is a necessity from the point of view of both the nuclear industrialists and the public authorities, but also of the overall French citizens. For the low- or medium-level or short living radioactive wastes, some solutions have been defined are are already implemented. On the other hand, no decision has been taken so far for the long living medium to high-level radioactive wastes. Researches are in progress in this domain according to 3 ways of research defined by the law from December 30, 1991: separation-transmutation, disposal in deep underground, and long duration surface or sub-surface storage. This paper presents in a digest way, the principle, the results obtained so far, and the perspectives of each of the three solutions under study. (J.S.)

  16. Method of processing radioactive wastes

    International Nuclear Information System (INIS)

    Funabashi, Kiyomi; Sugimoto, Yoshikazu; Kikuchi, Makoto; Yusa, Hideo.

    1979-01-01

    Purpose: To obtain solidified radioactive wastes at high packing density by packing radioactive waste pellets in a container and then packing and curing a thermosetting resin therein. Method: Radioactive liquid wastes are dried into power and subjected to compression molding. The pellets thus obtained are supplied in a predetermined amount from the hopper to the inside of a drum can. Then, thermosetting plastic and a curing agent are filled in the drum can. Gas between the pellets is completely expelled by the intrusion of the thermosetting resin and the curing agent among the pellets. Thereafter, the drum can is heated by a heater and curing is effected. After the curing, the drum can is sealed. (Kawakami, Y.)

  17. Old radioactive waste storage sites

    International Nuclear Information System (INIS)

    2008-01-01

    After a recall of the regulatory context for the management of old sites used for the storage of radioactive wastes with respect with their activity, the concerned products, the disposal or storage type, this document describes AREVA's involvement in the radioactive waste management process in France. Then, for the different kinds of sites (currently operated sites having radioactive waste storage, storage sites for uranium mineral processing residues), it indicates their location and name, their regulatory status and their control authority, the reference documents. It briefly presents the investigation on the long term impact of uranium mineral processing residues on health and environment, evokes some aspects of public information transparency, and presents the activities of an expertise group on old uranium mines. The examples of the sites of Bellezane (uranium mineral processing residues) and COMURHEX Malvesi (assessment of underground and surface water quality at the vicinity of this installation) are given in appendix

  18. Radioactive waste repository study

    International Nuclear Information System (INIS)

    1978-11-01

    This is the first part of a report of a preliminary study for Atomic Energy of Canada Limited. It considers the requirements for an underground waste repository for the disposal of wastes produced by the Canadian Nuclear Fuel Program. The following topics are discussed with reference to the repository: 1) underground layout, 2) cost estimates, 3) waste handling, 4) retrievability, decommissioning, sealing and monitoring, and 5) research and design engineering requirements. (author)

  19. Management of Radioactive Wastes in Developing Countries

    International Nuclear Information System (INIS)

    Abdel Ghani, A.H.

    1999-01-01

    The management of radioactive wastes is one area of increasing interest especially in developing countries having more and more activities in the application of radioisotopes in medicine, research and industry. For a better understanding of radioactive waste management in developing countries this work will discuss the following items:Classification of countries with respect to waste management programs. Principal Radionuclides used in medicine, biological research and others and the range of radioactivity commonly used. Estimation of radioactive waste volumes and activities. Management of liquid wastes Collection. Treatment. Management of small volumes of organic liquid waste. Collection Treatment. Packaging and storage of radioactive wastes

  20. Radioactive waste disposal and constitution

    International Nuclear Information System (INIS)

    Stober, R.

    1983-01-01

    The radioactive waste disposal has many dimensions with regard to the constitutional law. The central problem is the corret delimitation between adequate governmental precautions against risks and or the permitted risk which the state can impose on the citizen, and the illegal danger which nobody has to accept. The solution requires to consider all aspects which are relevant to the constitutional law. Therefore, the following analysis deals not only with the constitutional risks and the risks of the nuclear energy, but also with the liberal, overall-economic, social, legal, and democratic aspects of radioactive waste disposal. (HSCH) [de

  1. Radioactive waste integrated management system

    Energy Technology Data Exchange (ETDEWEB)

    Song, D Y; Choi, S S; Han, B S [Atomic Creative Technology, Taejon (Korea, Republic of)

    2003-10-01

    In this paper, we present an integrated management system for radioactive waste, which can keep watch on the whole transporting process of each drum from nuclear power plant temporary storage house to radioactive waste storage house remotely. Our approach use RFID(Radio Frequency Identification) system, which can recognize the data information without touch, GSP system, which can calculate the current position precisely using the accurate time and distance measured from satellites, and the spread spectrum technology CDMA, which is widely used in the area of mobile communication.

  2. Radioactive waste integrated management system

    International Nuclear Information System (INIS)

    Song, D. Y.; Choi, S. S.; Han, B. S.

    2003-01-01

    In this paper, we present an integrated management system for radioactive waste, which can keep watch on the whole transporting process of each drum from nuclear power plant temporary storage house to radioactive waste storage house remotely. Our approach use RFID(Radio Frequency Identification) system, which can recognize the data information without touch, GSP system, which can calculate the current position precisely using the accurate time and distance measured from satellites, and the spread spectrum technology CDMA, which is widely used in the area of mobile communication

  3. Low-level radioactive waste, mixed low-level radioactive waste, and biomedical mixed waste

    International Nuclear Information System (INIS)

    Anon.

    1994-01-01

    This document describes the proceedings of a workshop entitled: Low-Level Radioactive Waste, Mixed Low-Level Radioactive Waste, and Biomedical Mixed Waste presented by the National Low-Level Waste Management Program at the University of Florida, October 17-19, 1994. The topics covered during the workshop include technical data and practical information regarding the generation, handling, storage and disposal of low-level radioactive and mixed wastes. A description of low-level radioactive waste activities in the United States and the regional compacts is presented

  4. Cosmic disposal of radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Y; Morisawa, S [Kyoto Univ. (Japan). Faculty of Engineering

    1975-03-01

    The technical and economical possibility and safety of the disposal of highly radioactive waste into cosmos are reviewed. The disposal of highly radioactive waste is serious problem to be solved in the near future, because it is produced in large amounts by the reprocessing of spent fuel. The promising methods proposed are (i) underground disposal, (ii) ocean disposal, (iii) cosmic disposal and (iv) extinguishing disposal. The final disposal method is not yet decided internationally. The radioactive waste contains very long life nuclides, for example transuranic elements and actinide elements. The author thinks the most perfect and safe disposal method for these very long life nuclides is the disposal into cosmos. The space vehicle carrying radioactive waste will be launched safely into outer space with recent space technology. The selection of orbit for vehicles (earth satellite or orbit around planets) or escape from solar system, selection of launching rocket type pretreatment of waste, launching weight, and the cost of cosmic disposal were investigated roughly and quantitatively. Safety problem of cosmic disposal should be examined from the reliable safety study data in the future.

  5. Radioactive waste. Policy and perspective

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, L E.J. [UKAEA, Harwell. Atomic Energy Research Establishment

    1979-01-01

    The subject is covered in sections as follows: general introduction (volume of waste arising from 1 GW/(e) energy per year); characteristics of highly active waste (output of some important fission products from an AGR, decay of activity with time for PWR and CFR wastes, toxic potential versus time for magnox and fast reactor wastes, toxic potential of unreprocessed magnox fuel); general principles of waste disposal (incorporation of waste into solid matrices, glass containers); design of stores and repositories (heat dissipation, siting and design, packing materials, size of repositories); the geologic barrier (location of repositories, safety analysis of repositories); the option of ocean disposal; status of work and present programme (vitrification, repository siting and design); conclusions.

  6. Radioactive waste management alternatives

    International Nuclear Information System (INIS)

    Baranowski, F.P.

    1976-01-01

    The information in the US ERDA ''Technical Alternatives Document'' is summarized. The first two points show that waste treatment, interim storage and transportation technologies for all wastes are currently available. Third, an assessment of integrated waste management systems is needed. One such assessment will be provided in our expanded waste management environmental statement currently planned for release in about one year. Fourth, geologies expected to be suitable for final geologic storage are known. Fifth, repository system assessment methods, that is a means to determine and assess the acceptability of a terminal storage facility for nonretrievable storage, must and will be prepared. Sixth, alternatives to geologic storage are not now available. Seventh, waste quantities and characteristics are sensitive to technologies and fuel-cycle modes, and therefore an assessment of these technologies and modes is important. Eighth, and most important, it is felt that the LWR fuel cycle can be closed with current technologies

  7. Radioactive waste management in Switzerland

    International Nuclear Information System (INIS)

    Hugi, M.

    2011-01-01

    The Federal Nuclear Safety Inspectorate ENSI is the Supervisory Authority for Nuclear Safety and Security of Swiss Nuclear Facilities. The responsibilities include the evaluation and operational monitoring of the existing five Swiss nuclear power plants, the radioactive waste disposals and the nuclear research facilities. The supervisory area includes project planning, operational issues, and decommissioning of plants. ENSI supervises the formation, handling and storage of radioactive waste, the work on deep geological disposal and the transport of radioactive materials. The disposal of radioactive waste is regulated by the Swiss Nuclear Energy Act (2005) and the Nuclear Energy Ordinance (2005). The protection of humans and the environment must be guaranteed permanently. Waste disposal must be carried out in the own country by deep geological repositories. The licensing procedure for the disposal facilities is concentrated at the federal level, the cooperation of the location canton, neighboring cantons and the neighboring countries is ensured. The general license for the deep geological repository is subject to an optional referendum. The polluter pays principle applies to the disposal of radioactive waste. The waste producers are legally obliged to dispose of them and have founded the National Cooperative for the Storage of Radioactive Waste (Nagra). The federal government is responsible for waste from medicine, industry and research (MIF). The Federal Council approved the waste management certificate for low and intermediate level waste (SMA) in 1988. High-level-waste (HAA) and long-live-intermediate-level-waste (LMA), where approved in 2006. Nagra's disposal concept envisages two separate deep geological repositories for SMA and HAA / LMA in a suitable, tectonically stable, low-permeability rock formation. If a site meets both the SMA and HAA / LMA storage requirements, the selection process may result in a common location for all radioactive waste. Until the

  8. Heat transfer in vitrified radioactive waste

    International Nuclear Information System (INIS)

    Palancar, M.C.; Luis, M.A.; Luis, P.; Aragon, J.M.; Montero, M.A.

    1987-01-01

    An experimental method for measuring the thermal conductivity and convection coefficient of borosilicate glass cylinders, containing a simulated high level radioactive waste, is described. A simulation of the thermal behaviour of matrices of solidified waste during the cooling in air, water and a geological repository has been done. The experimental values of the thermal conductivity are ranging from 0.267 to 0.591 w/m K, for matrices with simulated waste contents of 10 to 40% (the waste is simulated by no radioactive isotopes). The convection coefficient for air/cylinders under the operating conditions used is 116 w/m 2 K. The simulated operation of cooling in air shows that about 1-2 days are enough to cool a solidified waste cylinder 0.6m diameter from 900 to 400 0 C. The cooling under water from 400 to near 80 0 C is faster than in air, but sharp temperature gradients within the matrices could be expected. The simulation of geological repositories lead to some criteria of arranging the matrices for avoiding undesirable high temperature points. (author) 1 fig

  9. Material chemistry challenges in vitrification of high level radioactive waste

    International Nuclear Information System (INIS)

    Kaushik, C.P.

    2008-01-01

    Full text: Nuclear technology with an affective environmental management plan and focused attention on safety measures is a much cleaner source of electricity generation as compared to other sources. With this perspective, India has undertaken nuclear energy program to share substantial part of future need of power. Safe containment and isolation of nuclear waste from human environment is an indispensable part of this programme. Majority of radioactivity in the entire nuclear fuel cycle is high level radioactive liquid waste (HLW), which is getting generated during reprocessing of spent nuclear fuels. A three stage strategy for management of HLW has been adopted in India. This involves (i) immobilization of waste oxides in stable and inert solid matrices, (ii) interim retrievable storage of the conditioned waste product under continuous cooling and (iii) disposal in deep geological formation. Borosilicate glass matrix has been adopted in India for immobilization of HLW. Material issue are very important during the entire process of waste immobilization. Performance of the materials used in nuclear waste management determines its safety/hazards. Material chemistry therefore has a significant bearing on immobilization science and its technological development for management of HLW. The choice of suitable waste form to deploy for nuclear waste immobilization is difficult decision and the durability of the conditioned product is not the sole criterion. In any immobilization process, where radioactive materials are involved, the process and operational conditions play an important role in final selection of a suitable glass formulation. In remotely operated vitrification process, study of chemistry of materials like glass, melter, materials of construction of other equipment under high temperature and hostile corrosive condition assume significance for safe and un-interrupted vitrification of radioactive to ensure its isolation waste from human environment. The present

  10. Removal of radioactive and other hazardous material from fluid waste

    Science.gov (United States)

    Tranter, Troy J [Idaho Falls, ID; Knecht, Dieter A [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Burchfield, Larry A [W. Richland, WA; Anshits, Alexander G [Krasnoyarsk, RU; Vereshchagina, Tatiana [Krasnoyarsk, RU; Tretyakov, Alexander A [Zheleznogorsk, RU; Aloy, Albert S [St. Petersburg, RU; Sapozhnikova, Natalia V [St. Petersburg, RU

    2006-10-03

    Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.

  11. Radioactive waste removing device

    International Nuclear Information System (INIS)

    Sakai, Takuhiko.

    1982-01-01

    Purpose: To cleanup primary coolants for LMFBR type reactors by magnetically generating a high speed rotational flow in the flow of liquid metal, and adsorbing radioactive corrosion products and fission products onto capturing material of a complicated shape. Constitution: Three-phase AC coils for generating a rotational magnetic field are provided to the outside of a container through which liquid sodium is passed to thereby generate a high speed rotational stream in the liquid sodium flowing into the container. A radioactive substance capturing material made of a metal plate such as of nickel and stainless steel in the corrugated shape with shape edges is secured within a flow channel. Magnetic field at a great slope is generated in the flow channel by the capturing material to adsorb radioactive corrosion products and fission products present in the liquid sodium onto the capturing material and removing therefrom. This enables to capture the ferri-magnetic impurities by adsorption. (Moriyama, K.)

  12. Database for waste glass composition and properties

    International Nuclear Information System (INIS)

    Peters, R.D.; Chapman, C.C.; Mendel, J.E.; Williams, C.G.

    1993-09-01

    A database of waste glass composition and properties, called PNL Waste Glass Database, has been developed. The source of data is published literature and files from projects funded by the US Department of Energy. The glass data have been organized into categories and corresponding data files have been prepared. These categories are glass chemical composition, thermal properties, leaching data, waste composition, glass radionuclide composition and crystallinity data. The data files are compatible with commercial database software. Glass compositions are linked to properties across the various files using a unique glass code. Programs have been written in database software language to permit searches and retrievals of data. The database provides easy access to the vast quantities of glass compositions and properties that have been studied. It will be a tool for researchers and others investigating vitrification and glass waste forms

  13. Disposal of radioactive waste material

    International Nuclear Information System (INIS)

    Cairns, W.J.; Burton, W.R.

    1984-01-01

    A method of disposal of radioactive waste consists in disposing the waste in trenches dredged in the sea bed beneath shallow coastal waters. Advantageously selection of the sites for the trenches is governed by the ability of the trenches naturally to fill with silt after disposal. Furthermore, this natural filling can be supplemented by physical filling of the trenches with a blend of absorber for radionuclides and natural boulders. (author)

  14. The limitation of radioactive wastes from hospitals

    International Nuclear Information System (INIS)

    Schuurman, B.; IJtsma, D.; Zwigt, A.

    1987-01-01

    Interviews were made with radiation experts working at hospitals about the treatment and limiting of radioactive wastes. The authors conclude that with the aid of hospital personnel a decrease of the volume of radioactive waste is possible. 25 refs

  15. Effects of composition on waste glass properties

    International Nuclear Information System (INIS)

    Mellinger, G.B.; Chick, L.A.

    1979-01-01

    The electrical conductivity, viscosity, chemical durability, devitrification, and crystallinity of a defense waste glass were measured. Each oxide component in the glass was varied to determine its effect on these properties. A generic study is being developed which will determine the effects of 26 oxides on the above and additional properties of a wide field of possible waste glasses. 5 figures, 2 tables

  16. Management of hospital radioactive wastes

    International Nuclear Information System (INIS)

    Houy, J.C.; Rimbert, J.C.; Bouvet, C.; Laugle, S.

    1997-01-01

    The hospital radioactive wastes are of three types: solid, liquid and gaseous. Prior to final evacuation all these wastes are checked by a detector the threshold of which is lower than the standard. This system allows detecting activities very low under the daily recommended threshold of 37 kBq (1μ Ci), for the group II. In metabolic radiotherapy the unsealed sources of iodine 131 will form mainly the wastes arising from the rooms contaminated by the patient himself. In this service anything touching the patient's room most by systematically checked. All the rooms are provided with toilette with two compartments, one connected traditionally to the sewerage system for faeces and the other coupled to tanks for urine storing. The filled reservoirs waits around 10 month span prior to being emptied, after checking, into the sewerage system. The volume activity most be lower than 7 Bq per liter (standard). For the hot labs, injection room and in-vitro lab, the liquid waste retrieved from dedicated stainless sinks are stored in storage tanks and will waits for 2 years before evacuation. The undies coming from the metabolic radiotherapy service are possible contaminated by the patient sheets, pillow cases, etc. These undies freshly contaminated may be contaminating if the contamination is non fixated. All the undies coming from this service are checked like all the wastes by means of the fixed detector. For the solid wastes two evacuation channels are possible: the urban garbage repository for household wastes and the Brest waste repository for hospital wastes. For the liquid waste arising for urines, used washing water, etc, the evacuation will be done towards city sewerage system after storing or dilution. Concerning the liquid wastes presenting chemical risks, they will be evacuated in cans by NETRA. Concerning the gaseous wastes, trapped on active carbon filters, they will be handled like solid wastes and will be directed to the waste repository of Brest. The other

  17. Conceptual process for conversion of high level waste to glass

    International Nuclear Information System (INIS)

    1975-01-01

    During a ten-year period highly radioactive wastes amounting to 22 million gallons of salt cake and 5 million gallons of wet sludge are to be converted to 1.2 million gallons of glass and 24 million gallons of decontaminated salt cake and placed in the new storage facilities which will provide high assurance of containment with minimal reliance on maintenance and surveillance. The glass will contain nearly all of the radioactivity in a form that is highly resistant to leaching and dispersion. The salt cake will contain a small amount of residual radioactivity. The process is shown in Figure 1 and the facilities may be arranged in seven modules to accomplish seven tasks, (1) remove wastes from tanks, (2) separate sludge and salt, (3) decontaminate salt, (4) solidify and package sludge and 137 Cs, (5) solidify and package decontaminated salt, (6) store high level waste, and (7) store decontaminated salt cake

  18. Disposal options for radioactive waste

    International Nuclear Information System (INIS)

    Olivier, J.P.

    1991-01-01

    On the basis of the radionuclide composition and the relative toxicity of radioactive wastes, a range of different options are available for their disposal. Practically all disposal options rely on confinement of radioactive materials and isolation from the biosphere. Dilution and dispersion into the environment are only used for slightly contaminated gaseous and liquid effluents produced during the routine operation of nuclear facilities, such as power plants. For the bulk of solid radioactive waste, whatever the contamination level and decay of radiotoxicity with time are, isolation from the biosphere is the objective of waste disposal policies. The paper describes disposal approaches and the various techniques used in this respect, such as shallow land burial with minimum engineered barriers, engineered facilities built at/near the surface, rock cavities at great depth and finally deep geologic repositories for long-lived waste. The concept of disposing long-lived waste into seabed sediment layers is also discussed, as well as more remote possibilities, such as disposal in outer space or transmutation. For each of these disposal methods, the measures to be adopted at institutional level to reinforce technical isolation concepts are described. To the extent possible, some comments are made with regard to the applicability of such disposal methods to other hazardous wastes. (au)

  19. Nuclear power and radioactive waste

    International Nuclear Information System (INIS)

    Grimston, M.

    1991-03-01

    The gap between the relative perceptions in the area of nuclear waste is wide. The broad view of the industry is that the disposal of nuclear waste is not a serious technical problem, and that solutions are already available to provide safe disposal of all our waste. The broad view of those who oppose the industry is that radioactive waste is so unpleasant, and will remain lethal for so long, that no acceptable policy will ever be developed, and so production of such waste (except, oddly, the significant amounts arising from uses of radioactive materials in medicine, agriculture, industrial safety research, etc) should stop immediately. This booklet will not attempt to describe in great detail the technicalities of the United Kingdom nuclear industry's current approach to radioactive waste: such issues are described in detail in other publications, especially those by Nirex. It is our intention to outline some of the main issues involved, and to associate these issues with the divergence in perceptions of various parties. (author)

  20. Underground disposal of radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1979-08-15

    Disposal of low- and intermediate-level radioactive wastes by shallow land burial, emplacement in suitable abandoned mines, or by deep well injection and hydraulic fracturing has been practised in various countries for many years. In recent years considerable efforts have been devoted in most countries that have nuclear power programmes to developing and evaluating appropriate disposal systems for high-level and transuranium-bearing waste, and to studying the potential for establishing repositories in geological formations underlaying their territories. The symposium, organized jointly by the IAEA and OECD's Nuclear Energy Agency in cooperation with the Geological Survey of Finland, provided an authoritative account of the status of underground disposal programmes throughout the world in 1979. It was evidence of the experience that has been gained and the comprehensive investigations that have been performed to study various options for the underground disposal of radioactive waste since the last IAEA/NEA symposium on this topic (Disposal of Radioactive Waste into the Ground) was held in 1967 in Vienna. The 10 sessions covered the following topics: National programme and general studies, Disposal of solid waste at shallow depth and in rock caverns, underground disposal of liquid waste by deep well injection and hydraulic fracturing, Disposal in salt formations, Disposal in crystalline rocks and argillaceous sediments, Thermal aspects of disposal in deep geological formations, Radionuclide migration studies, Safety assessment and regulatory aspects.

  1. Long term radioactive waste management

    International Nuclear Information System (INIS)

    Lavie, J.M.

    1984-01-01

    In France, waste management, a sensitive issue in term of public opinion, is developing quickly, and due to twenty years of experience, is now reaching maturity. With the launching of the French nuclear programme, the use of radioactive sources in radiotherapy and industry, waste management has become an industrial activity. Waste management is an integrated system dealing with the wastes from their production to the long term disposal, including their identification, sortage, treatment, packaging, collection and transport. This system aims at guaranteing the protection of present and future populations with an available technology. In regard to their long term management, and the design of disposals, radioactive wastes are divided in three categories. This classification takes into account the different radioisotopes contained, their half life and their total activity. Presently short-lived wastes are stored in the shallowland disposal of the ''Centre de la Manche''. Set up within the French Atomic Energy Commission (CEA), the National Agency for waste management (ANDRA) is responsible within the framework of legislative and regulatory provisions for long term waste management in France [fr

  2. Radioactive waste management regulatory framework in Mexico

    International Nuclear Information System (INIS)

    Barcenas, M.; Mejia, M.

    2001-01-01

    The purpose of this paper is to present an overview of the current regulatory framework concerning the radioactive waste management in Mexico. It is intended to show regulatory historical antecedents, the legal responsibilities assigned to institutions involved in the radioactive waste management, the sources of radioactive waste, and the development and preparation of national standards for fulfilling the legal framework for low level radioactive waste. It is at present the most important matter to be resolved. (author)

  3. Specified radioactive waste final disposal act

    International Nuclear Information System (INIS)

    Yasui, Masaya

    2001-01-01

    Radioactive wastes must be finally and safely disposed far from human activities. Disposal act is a long-range task and needs to be understood and accepted by public for site selection. This paper explains basic policy of Japanese Government for final disposal act of specified radioactive wastes, examination for site selection guidelines to promote residential understanding, general concept of multi-barrier system for isolating the specific radioactive wastes, and research and technical development for radioactive waste management. (S. Ohno)

  4. Radioactive waste management - a safe solution

    International Nuclear Information System (INIS)

    1993-01-01

    This booklet sets out current United Kingdom government policy regarding radioactive waste management and is aimed at reassuring members of the public concerned about the safety of radioactive wastes. The various disposal or, processing or storage options for low, intermediate and high-level radioactive wastes are explained and sites described, and the work of the Nuclear Industry Radioactive Waste Executive (NIREX) is outlined. (UK)

  5. Storage container for radioactive wastes

    International Nuclear Information System (INIS)

    Catalayoud, L.; Gerard, M.

    1990-01-01

    Tightness, shock resistance and corrosion resistance of containers for storage of radioactive wastes it obtained by complete fabrication with concrete reinforced with metal fibers. This material is used for molding the cask, the cover and the joint connecting both parts. Dovetail grooves are provided on the cask and the cover for the closure [fr

  6. Cementation of liquid radioactive waste

    International Nuclear Information System (INIS)

    Efremenkov, V.

    2004-01-01

    The cementation methods for immobilisation of radioactive wastes are discussed in terms of methodology, chemistry and properties of the different types of cements as well as the worldwide experience in this field. Two facilities for cementation - DEWA and MOWA - are described in details

  7. Radioactive wastes in the air

    International Nuclear Information System (INIS)

    1968-01-01

    Methods of preventing the pollution of air by radioactive waste from atomic centres were discussed in an Agency Symposium held in New York at the end of August. It was agreed that the atomic industry has a good safety record, and suggestions were made that there should now be a concerted effort to prevent air pollution by all industries. (author)

  8. Radioactive waste disposal: a survey

    International Nuclear Information System (INIS)

    Bentsen, B.A.

    1974-01-01

    The world's industrial nations are embarking on a major build-up of nuclear electric power generating capacity. Enormous quantities of radioactive waste will be produced in fuel reprocessing operations which must be safeguarded from entering the biosphere for thousands of years. It is an unprecedented problem which has no universally agreed upon solution. (U.S.)

  9. Safe disposal of radioactive wastes

    International Nuclear Information System (INIS)

    Hooker, P.; Metcalfe, R.; Milodowski, T.; Holliday, D.

    1997-01-01

    A high degree of international cooperation has characterized the two studies reported here which aim to address whether radioactive waste can be disposed of safely. Using hydrogeochemical and mineralogical surveying techniques earth scientists from the British Geological Survey have sought to identify and characterise suitable disposal sites. Aspects of the studies are explored emphasising their cooperative nature. (UK)

  10. Chemical decontamination of radioactive waste

    International Nuclear Information System (INIS)

    Mohamed, H.I.

    2006-01-01

    Radioactive wastes are generated in a number of different kinds of facilities and arise in a wide range of concentrations of radioactive materials and in a variety of physical and chemical forms. There is also a variety of alternatives for treatment and conditioning of the wastes prior disposal. The importance of treatment of radioactive waste for protection of human and environment has long been recognized and considerable experience has gained in this field. Generally, the methods used for treatment of radioactive wastes can be classified into three type's biological, physical and chemical treatment this physical treatment it gives good result than biological treatment. Chemical treatment is fewer hazards and gives good result compared with biological and physical treatments. Chemical treatment is fewer hazards and gives good result compared with biological and physical treatments. In chemical treatment there are different procedures, solvent extraction, ion exchange, electro dialysis but solvent extraction is best one because high purity can be optioned on the other hand the disadvantage that it is expensive. Beside the solvent extraction technique one can be used is ion exchange which gives reasonable result, but requires pretreatment that to avoid in closing of column by colloidal and large species. Electro dialysis technique gives quite result but less than solvent extraction and ion exchange technique the advantage is a cheep.(Author)

  11. High-level radioactive wastes

    International Nuclear Information System (INIS)

    Grissom, M.C.

    1982-10-01

    This bibliography contains 812 citations on high-level radioactive wastes included in the Department of Energy's Energy Data Base from January 1981 through July 1982. These citations are to research reports, journal articles, books, patents, theses, and conference papers from worldwide sources. Five indexes are provided: Corporate Author, Personal Author, Subject, Contract Number, and Report Number

  12. Management of small quantities of radioactive waste

    International Nuclear Information System (INIS)

    1998-09-01

    The main objective of this publication is to provide practical guidance primarily to developing Member States on the predisposal management of small quantities of radioactive waste arising from hospitals, laboratories, industries, institutions, research reactors and research centres.The publication covers the management of liquid, solid and gaseous radioactive wastes at the users' premises and gives general guidance on procedures at a centralized waste management facility. Predisposal management of radioactive waste includes handling, treatment, conditioning, storage and transportation. This publication provides information and guidance on the following topics: national waste management framework; origin and characteristics of radioactive waste arising from users generating small quantities of waste; radioactive waste management concepts appropriate for small quantities; local waste management; the documentation and approval necessary for the consignment of waste to a centralized waste management facility; centralized waste management; exemption of radionuclides from the regulatory body; transportation; environmental monitoring; quality assurance for the whole predisposal process; regional co-operation aspects

  13. Apparatus for fixing radioactive waste

    International Nuclear Information System (INIS)

    Murphy, J.D.; Pirro, J. Jr.; Lawrence, M.; Wisla, S.F.

    1975-01-01

    Fixing radioactive waste is disclosed in which the waste is collected as a slurry in aqueous media in a metering tank located within the nuclear facilities. Collection of waste is continued from time to time until a sufficient quantity of material to make up a full shipment to a burial ground has been collected. The slurry is then cast in shipping containers for shipment to a burial ground or the like by metering through a mixer into which fixing materials are simultaneously metered at a rate to yield the desired proportions of materials. (U.S.)

  14. Fixation process for radioactive waste

    International Nuclear Information System (INIS)

    Theysohn, F.

    1977-01-01

    An improvement on the method of solidification of radioactive liquid waste in bitumen with the aid of extruders is described. So far, it has been difficult to remove large amounts of water. The waste sludge, as proposed here, is pre-dried in the extruder and then mixed with the bitumen. The extruder is inclined upward in the transport direction, and its barrel extruders have through holes parallel to the direction of transport in the raised sides of the passages, so that water runs back. Also the waste steam nozzles are arranged before the bitumen inlet. (UWI) [de

  15. Coal combustion ashes: A radioactive Waste?

    International Nuclear Information System (INIS)

    Michetti, F.P.; Tocci, M.

    1992-01-01

    The radioactive substances naturally hold in fossil fuels, such as Uranium and Thorium, after the combustion, are subjected to an increase of concentration in the residual combustion products as flying ashes or as firebox ashes. A significant percentage of the waste should be classified as radioactive waste, while the political strategies seems to be setted to declassify it as non-radioactive waste. (Author)

  16. National Syrian Program for Radioactive Waste Management

    International Nuclear Information System (INIS)

    Othman, I.; Takriti, S.

    2009-06-01

    A national plan for radioactive waste management has been presented. It includes identifying, transport, recording, classifying, processing and disposal. It is an important reference for radioactive waste management for those dealing with radioactive waste, and presents a complete protection to environemnt and people. (author)

  17. Radioactivity measurements for some ophthalmic glasses

    International Nuclear Information System (INIS)

    Badawy, W.M.; Ali, E.M.; Gomaa, M.A.; Hussein, A

    2007-01-01

    The main aim of the present work is to implant the latest ICRP/IAEA recommendations related to exemption and clearness to the Ophthalmic Glass. As consumer product, glass lenses may contain trace quantities of uranium, thorium and potassium. Glass lenses under investigation were monitored for the detection of gamma rays and beta particles using radiation measuring devices. Using high purity germanium detector radioactivity concentration was estimated in Bq/kg. Activity concentration of 226 Ra, Th-232 and K-40 were determined using the energy gamma lines of 2l4 Pb (352 keV), 212 Pb (238 keV) and 1460 keV gamma line for 40 K respectively .Experimental results showed that radioactivity concentration for radium -226 varies from 0.19 to 4.98 Bq/kg of radium-226, from to 0.18 to 2.83 Bq/kg for thorium -232 and from 0.8 to 1.13 Bq/kg for potassium. Implementing new ICRP recommendation of exemption and clearness indicated that several Ophthalmic Glass should not be in use

  18. Radioactive waste management in Belgium

    International Nuclear Information System (INIS)

    Dejonghe, P.

    1977-01-01

    In 1975 the research association BelgoWaste was founded in order to prepare a technical and administrative plan for radioactive waste management in Belgium and to take the preliminary steps for establishing an organization which would be responsible for this activity. The association made a survey of all forecasts concerning radioactive waste production by power reactors and the fuel cycle industry based on various schemes of development of the nuclear industry. From the technical point of view, the reference plan for waste management envisages: purification at the production site of large volumes of low-level effluents; construction of a central facility for the treatment and intermediate storage of process concentrates (slurries, resins, etc.) and medium-level waste, centralization assuming that adequate arrangements are made for transporting waste before final treatment; maximum recovery of plutonium from waste and treatment of residual material by incineration at very high temperatures; treatment at the production site of high-level effluents from irradiated fuel reprocessing; construction of an underground long-term storage site for high-level treated waste and plutonium fuel fabrication waste (deep clay formations are at present preferred); and disposal of low-level treated waste into the Atlantic Ocean. It is intended to entrust the entire responsibility for treatment, disposal and storage of treated waste to a single body with participation by the State, the Nuclear Energy Research Centre (CEN/SCK), the electricity companies and Belgonucleaire. The partners intend to set up their facilities and services in the area of Mol. (author)

  19. Glass: a candidate engineered material for management of high level nuclear waste

    International Nuclear Information System (INIS)

    Mishra, R.K.; Kaushik, C.P.

    2011-01-01

    While the commercial importance of glass is generally recognized, a few people are aware of extremely wide range of glass formulations that can be made and of the versatility of this engineered material. Some of the recent developments in the field of glass leading to various technological applications include glass fiber reinforcement of cement to give new building materials, substrates for microelectronics circuitry in form of semiconducting glasses, nuclear waste immobilization and specific medical applications. The present paper covers fundamental understanding of glass structure and its application for immobilization of high level radioactive liquid waste. High level radioactive liquid waste (HLW) arising during reprocessing of spent fuel are immobilized in sodium borosilicate glass matrix developed indigenously. Glass compositions are modified according to the composition of HLW to meet the criteria of desirable properties in terms. These glass matrices have been characterized for different properties like homogeneity, chemical durability, thermal stability and radiation stability. (author)

  20. Geochemistry of radioactive waste disposal

    International Nuclear Information System (INIS)

    Bird, G.W.

    1979-01-01

    Safe, permanent disposal of radioactive wastes requires isolation of a number of elements including Se, Tc, I, Sr, Cs, Pd, u, Np, Pu and Cm from the environment for a long period of time. The aquatic chemistry of these elements ranges from simple anionic (I - ,IO 3 - ) and cationic (Cs + ,Sr ++ ) forms to multivalent hydrolyzed complexes which can be anionic or cationic (Pu(OH) 2 + ,Pu(OH) 3 + , PuO 2 (CO 3 )(OH) - ,PuO 2 Cl - ,etc.) depending on the chemical environment. The parameters which can affect repository safety are rate of access and composition of grounwater, stability of the waste container, stability of the waste form, rock-water-waste interactons, and dilution and dispersion as the waste moves away from the repository site. Our overall research program on radioactive waste disposal includes corrosion studies of containment systems hydrothermal stability of various waste forms, and geochemical behaviour of various nuclides including solubilities, redox equilibria, hydrolysis, colloid fomation and transport ion exchange equilibria and adsorption on mineral surfaces and irreversible precipitation reactions. This paper discusses the geochemistry of I, Se, Tc, Cs, Sr and the actinide elements and potential mechanisms by which the mobility could be retarded if necessary

  1. Radioactive waste management: Spanish experiences

    International Nuclear Information System (INIS)

    Beceiro, A. R.

    1996-01-01

    Radioactive waste generation began in Spain during the 1950's, in association with the first applications of radioactive isotopes in industry, medicine and research. Spain's first nuclear power plant began its operations in 1968. At present, there are in operation some one thousand installations possessing the administrative authorization required to use radioactive isotopes (small producers), nine nuclear groups and a tenth is now entering the dismantling phase. There are also activities and installations pertaining to the front end of the nuclear fuel cycle (mining, milling and the manufacturing of fuel elements). Until 1985, the research center Junta de Energia Nuclear (now CIEMAT) rendered radioactive waste removal, and subsequent conditioning and temporary storage services to the small producers. Since the beginning of their operations the nuclear power plants and fuel cycle facilities have had the capacity to condition and temporarily store their own radioactive wastes. ENRESA (Empresa Nacional de Residuos Radiactivos, S. A.) began its operations in the second half of 1985. It is a state-owned company created by the Government in accordance with a previous parliamentary resolution and commissioned to establish a system for management of such wastes throughout Spain, being in charge also of the dismantling of nuclear power plants and other major installations at the end of their operating lifetimes. Possibly the most outstanding characteristic of ENRESA's evolution over these last seven years has been the need to bring about a compromise between solving the most immediate and pressing day-to-day problems of operation (the first wastes were removed at the beginning of 1986) and establishing the basic organization, resources, technology and installations required for ENRESA to operate efficiently in the long term. (author)

  2. The management of radioactive wastes in Canada

    International Nuclear Information System (INIS)

    1979-01-01

    Ten papers are presented, dealing with the management and environmental impact of radioactive wastes, environmental considerations related to uranium mining and milling, the management of uranium refining wastes, reactor waste management, proposals for the disposal of low- and intermediate-level wastes, disposal of nuclear fuel wastes, federal government policy on radioactive waste management, licensing requirements, environmental assessment, and internatioal cooperation in wast management. (LL)

  3. Characterization of Savannah River Plant waste glass

    International Nuclear Information System (INIS)

    Plodinec, M.J.

    1985-01-01

    The objective of the glass characterization programs at the Savannah River Laboratory (SRL) is to ensure that glass containing Savannah River Plant high-level waste can be permanently stored in a federal repository, in an environmentally acceptable manner. To accomplish this objective, SRL is carrying out several experimental programs, including: fundamental studies of the reactions between waste glass and water, particularly repository groundwater; experiments in which candidate repository environments are simulated as accurately as possible; burial tests of simulated waste glass in candidate repository geologies; large-scale tests of glass durability; and determination of the effects of process conditions on glass quality. In this paper, the strategy and current status of each of these programs is discussed. The results indicate that waste packages containing SRP waste glass will satisfy emerging regulatory criteria

  4. National Inventory of Radioactive Wastes, Edition 1998

    International Nuclear Information System (INIS)

    Pallard, Bernard; Vervialle, Jean Pierre; Voizard, Patrice

    1998-01-01

    The National Radioactive Waste Inventory is an annual report of French National Agency for Radioactive Waste Management (ANDRA). The issue on 1998 has the following content: 1. General presentation; 2. Location of radioactive wastes in France; 3. Regional file catalogue; 4. Address directory; 5. Annexes. The inventory establishes the producer and owner categories, the French overseas waste sources, location of pollutant sides, spread wastes (hospitals, universities and industrial sector), railways terminals

  5. Ultimate disposal of radioactive wastes

    International Nuclear Information System (INIS)

    Roethemeyer, H.

    1991-01-01

    The activities developed by the Federal Institution of Physical Engineering PTB and by the Federal Office for Radiation Protection (BfS) concentrated, among others, on work to implement ultimate storage facilities for radioactive wastes. The book illuminates this development from site designation to the preliminary evaluation of the Gorleben salt dome, to the preparation of planning documents proving that the Konrad ore mine is suitable for a repository. The paper shows the legal provisions involved; research and development tasks; collection of radioactive wastes ready for ultimate disposal; safety analysis in the commissioning and post-operational stages, and product control. The historical development of waste management in the Federal Republic of Germany and international cooperation in this area are outlined. (DG) [de

  6. Public attitudes about radioactive wastes

    International Nuclear Information System (INIS)

    Bisconti, A.S.

    1992-01-01

    Public attitudes about radioactive waste are changeable. That is the author's conclusion from eight years of social science research which the author has directed on this topic. The fact that public attitudes about radioactive waste are changeable is well-known to the hands-on practitioners who have opportunities to talk with the public and respond to their concerns--practitioners like Ginger King who is sharing the podium with me today. The public's changeability and open-mindedness are frequently overlooked in studies that focus narrowly on fear and dread. Such studies give the impression that the outlook for waste disposal solutions s dismal. The author believes that impression is misleading, and in this paper shares research findings that give a broader perspective

  7. Public attitudes about radioactive waste

    International Nuclear Information System (INIS)

    Bisconti, A.S.

    1992-01-01

    Public attitudes about radioactive waste are changeable. That is my conclusion from eight years of social science research which I have directed on this topic. The fact that public attitudes about radioactive waste are changeable is well-known to the hands-on practitioners who have opportunities to talk with the public and respond to their concerns-practitioners like Ginger King, who is sharing the podium with me today. The public's changeability and open-mindedness are frequently overlooked in studies that focus narrowly on fear and dread. Such studies give the impression that the outlook for waste disposal solutions is dismal. I believe that impression is misleading, and I'd like to share research findings with you today that give a broader perspective

  8. Method of solidifying radioactive wastes

    International Nuclear Information System (INIS)

    Tomita, Toshihide; Minami, Yuji; Matsuura, Hiroyuki

    1984-01-01

    Purpose: To enable complete curing even when radioactive wastes contain those materials hindering the curing reaction, for example, copper hydroxide. Method: After admixing an alkaline substance to radioactive concentrated liquid wastes containing copper hydroxide or other amphoteric substances, they are dried, powderized and then cured with thermosetting resins. The thermosetting resins usable herein include, for example, those prepared by mixing an unsaturated polyester with a monomer such as styrene. When a polymerization initiator such as methyl ethyl ketone peroxide and a polymerization promotor are added to the mixture, it takes places curing reaction at normal temperature. Suitable alkaline substances usable herein are those which are insoluble to the liquid wastes and do not change the chemical form under heating and drying. (Yoshihara, H.)

  9. Radioactive wastes: underground laboratories implantation

    International Nuclear Information System (INIS)

    Bataille, Ch.

    1997-01-01

    This article studies the situation of radioactive waste management, more especially the possible storage in deep laboratories. In front of the reaction of public opinion relative to the nuclear waste question, it was essential to begin by a study on the notions of liability, transparence and democracy. At the beginning, it was a matter of underground researches with a view to doing an eventual storage of high level radioactive wastes. The Parliament had to define, through the law, a behaviour able to come to the fore for anybody. A behaviour which won recognition from authorities, from scientists, from industrial people, which guarantees the rights of populations confronted to a problem whom they were not informed, on which they received only few explanations. (N.C.)

  10. Treatment and conditioning of historical radioactive waste

    International Nuclear Information System (INIS)

    Dogaru, Ghe.; Dragolici, F.; Ionascu, L.; Rotarescu, Ghe.

    2009-01-01

    The paper describes the management of historical radioactive waste from the storage facility of Radioactive Waste Treatment Plant. The historical waste stored into storage facility of IFIN-HH consists of spent sealed radioactive sources, empty contaminated containers, wooden radioactive waste, low specific activity radioactive waste, contaminated waste as well as radioactive waste from operation of WWR-S research reactor. After decommissioning of temporary storage facility about 5000 packages with radioactive waste were produced and transferred to the disposal facility. A large amount of packages have been transferred and disposed of to repository but at the end of 2000 there were still about 800 packages containing cement conditioned radioactive waste in an advanced state of degradation declared by authorities as 'historical waste'. During the management of historical waste campaign there were identified: radium spent radioactive sources, containers containing other spent sealed radioactive sources, packages containing low specific activity waste consist of thorium scrap allow, 30 larger packages (316 L), packages with activity lower than activity limit for disposal, packages with activity higher than activity limit for disposal. At the end of 2008, the whole amount of historical waste which met the waste acceptance criteria has been conditioned and transferred to disposal facility. (authors)

  11. Radioactive Waste Management BasisApril 2006

    Energy Technology Data Exchange (ETDEWEB)

    Perkins, B K

    2011-08-31

    This Radioactive Waste Management Basis (RWMB) documents radioactive waste management practices adopted at Lawrence Livermore National Laboratory (LLNL) pursuant to Department of Energy (DOE) Order 435.1, Radioactive Waste Management. The purpose of this Radioactive Waste Management Basis is to describe the systematic approach for planning, executing, and evaluating the management of radioactive waste at LLNL. The implementation of this document will ensure that waste management activities at LLNL are conducted in compliance with the requirements of DOE Order 435.1, Radioactive Waste Management, and the Implementation Guide for DOE Manual 435.1-1, Radioactive Waste Management Manual. Technical justification is provided where methods for meeting the requirements of DOE Order 435.1 deviate from the DOE Manual 435.1-1 and Implementation Guide.

  12. Croatian radioactive waste management program: Current status

    International Nuclear Information System (INIS)

    Matanic, R.; Lebegner, J.

    2001-01-01

    Croatia has a responsibility to develop a radioactive waste management program partly due to co-ownership of Krsko nuclear power plant (Slovenia) and partly because of its own medical and industrial radioactive waste. The total amount of generated radioactive waste in Croatia is stored in temporary storages located at two national research institutes, while radioactive waste from Krsko remains in temporary storage on site. National power utility Hrvatska Elektroprivreda (HEP) and Hazardous Waste Management Agency (APO) coordinate the work regarding decommissioning, spent fuel management and low and intermediate level radioactive waste (LILRW) management in Croatia. Since the majority of work has been done in developing the LILRW management program, the paper focuses on this part of radioactive waste management. Issues of site selection, repository design, safety assessment and public acceptance are being discussed. A short description of the national radioactive waste management infrastructure has also been presented. (author)

  13. Management of radioactive waste

    International Nuclear Information System (INIS)

    Jahn, P.G.

    1986-01-01

    The text comprises three sections, i.e. theological and moral aspects, scientific and technical aspects, and administrative and political aspects. The book informs on the scientific and legal situation concerning nuclear waste management and intends to give some kind of decision aid from a theological point of view. (PW) [de

  14. Radioactive waste repository study

    International Nuclear Information System (INIS)

    1978-11-01

    This is the third part of a report of a preliminary study for AECL. It summarizes the topics considered in reports AECL-6188-1 and AECL-6188-2 as requirements for an undergpound repository for disposal of wastes produced by the Canadian Nuclear Fuel Program. (author)

  15. Radioactive waste processing vessel

    International Nuclear Information System (INIS)

    Hayashi, Masaru; Suzuki, Osamu; Ishizaki, Kanjiro.

    1987-01-01

    Purpose: To obtain a vessel of a reduced weight and with no external leaching of radioactive materials. Constitution: The vessel main body is constituted, for example, with light weight concretes or foamed concretes, particularly, foamed concretes containing fine closed bubbles in the inside. Then, layers having dense texture made of synthetic resin such as polystylene, vinylchloride resin, etc. or metal plate such as stainless plate are integrally disposed to the inner surface of the vessel main body. The cover member also has the same structure. (Sekiya, K.)

  16. Leaching behavior of glass ceramic nuclear waste forms

    International Nuclear Information System (INIS)

    Lokken, R.O.

    1981-11-01

    Glass ceramic waste forms have been investigated as alternatives to borosilicate glasses for the immobilization of high-level radioactive waste at Pacific Northwest Laboratory (PNL). Three glass ceramic systems were investigated, including basalt, celsian, and fresnoite, each containing 20 wt % simulated high-level waste calcine. Static leach tests were performed on seven glass ceramic materials and one parent glass (before recrystallization). Samples were leached at 90 0 C for 3 to 28 days in deionized water and silicate water. The results, expressed in normalized elemental mass loss, (g/m 2 ), show comparable releases from celsian and fresnoite glass ceramics. Basalt glass ceramics demonstrated the lowest normalized elemental losses with a nominal release less than 2 g/m 2 when leached in polypropylene containers. The releases from basalt glass ceramics when leached in silicate water were nearly identical with those in deionized water. The overall leachability of celsian and fresnoite glass ceramics was improved when silicate water was used as the leachant

  17. Review of glass ceramic waste forms

    International Nuclear Information System (INIS)

    Rusin, J.M.

    1981-01-01

    Glass ceramics are being considered for the immobilization of nuclear wastes to obtain a waste form with improved properties relative to glasses. Improved impact resistance, decreased thermal expansion, and increased leach resistance are possible. In addition to improved properties, the spontaneous devitrification exhibited in some waste-containing glasses can be avoided by the controlled crystallization after melting in the glass-ceramic process. The majority of the glass-ceramic development for nuclear wastes has been conducted at the Hahn-Meitner Institute (HMI) in Germany. Two of their products, a celsian-based (BaAl 3 Si 2 O 8 ) and a fresnoite-based (Ba 2 TiSi 2 O 8 ) glass ceramic, have been studied at Pacific Northwest Laboratory (PNL). A basalt-based glass ceramic primarily containing diopsidic augite (CaMgSi 2 O 6 ) has been developed at PNL. This glass ceramic is of interest since it would be in near equilibrium with a basalt repository. Studies at the Power Reactor and Nuclear Fuel Development Corporation (PNC) in Japan have favored a glass-ceramic product based upon diopside (CaMgSi 2 O 6 ). Compositions, processing conditions, and product characterization of typical commercial and nuclear waste glass ceramics are discussed. In general, glass-ceramic waste forms can offer improved strength and decreased thermal expansion. Due to typcially large residual glass phases of up to 50%, there may be little improvement in leach resistance

  18. First use of in situ vitrification on radioactive wastes

    International Nuclear Information System (INIS)

    Bowlds, L.

    1992-01-01

    A high-temperature method for containing hazardous wastes, which was first developed in the 1980s, is being adapted for the in situ treatment of buried radioactive wastes by the US DOE's Idaho National Engineering Laboratory (INEL), following its recent report on successful preliminary tests. The method, called in situ vitrification (ISV), is an electrically induced thermal process that melts and fuses soil and wastes into a glass-like material at least as strong as natural obsidian or granite. Gases released during the process are captured and treated by an off-gas treatment system. After the wastes are vitrified, they could be left in place, or the mass could be broken up and transported to a disposal site. The glass-like substance would be chemically and physically similar to obsidian and from 4 to 10 times more durable than typical borosilicate glasses used to immobolize high-level nuclear wastes

  19. Conveyor for sorting radioactive waste

    International Nuclear Information System (INIS)

    Prisco, A.J.; Johnson, A.N.

    1987-01-01

    An apparatus is described for detecting radioactive components in dry active waste, the apparatus comprising: means for reducing the waste to pieces of substantially uniform size, first and second conveyors and a housing for the conveyors; means for conveying the pieces from the means for reducing the waste to the first and second conveyors; each of the first and second conveyors includes a receiving portion and a discharge portion; the discharge portion is spaced above and upstream from the receiving portion to disperse the pieces as they are transferred from the first conveyor to the second conveyor so that pieces which are in clusters are separated from each other to increase the likelihood of detecting radiation emanating means for detecting radioactive radiation emanating from the pieces, at least one of radiation detector means is located on each of the conveyors. Each is disposed in close overlying relation to its respective conveyor so that low levels of radiation emanating from the pieces can be detected; each of the conveyors includes means for flattening the pieces of waste before the pieces pass under the radiation detector means; and the means for flattening disposed between the receiving portion of each conveyor and the radiation detector means; the housing is generally closed; and means for providing a generally closed connection between the housing and the means for reducing the waste so that air that is in the housing and in the means for reducing the waste can be controlled

  20. The management of radioactive waste

    International Nuclear Information System (INIS)

    1991-08-01

    One of the key questions asked about nuclear power production is whether the industry can manage its waste safely and economically. Management must take account of long term safety, since some radioisotopes take a very long time to decay. This long term decay, which can take millions of years, focused attention for the first time on the need for some wastes to be managed for a very long time beyond the lifetime of those who generated the waste. This paper reviews what the different types of waste are, what the technical consensus is on the requirements for their safe management, and how the present state of knowledge developed. It describes how radioactive waste management is practised and planned within the fuel cycle and indicates the moderate scale of the costs in relation to the total cost of producing electricity. Country annexes give more information about what is being done in a selection of countries, in order to indicate how radioactive waste management is carried out in practice. (Author)

  1. Studies and implementation of glass-crystal materials as the ecological shells and coatings for storage and disposal of radioactive and toxic wastes

    International Nuclear Information System (INIS)

    Iskakov, T.; Ibraev, Yu.; Garifulin, V.

    1996-01-01

    The ground space and missile systems designed to launch the modern rockets have the launching constructions. These construction are equipped with protection systems for construction units, which are undergoing by high temperature gas dynamic impact. Protective materials are featuring with a high strength, and stability regarding to high temperatures and heat impact. Such materials were obtained in glass-crystal class. Institute for Special Material Science Research has synthesized the glass-crystal materials with high thermal stability, strength, which are also stable regarding to chemical, biological, radioactive, gas dynamic, etc. impacts. The developed materials in form of plates were successfully tested in launching constructions at Baikonur space system. This material is valid for heat protective coatings, constructions of rocket-space system, plates used in airstrips and grounds for aircraft with vertical take-off and landing. These materials were studied to obtain the super strength, wearing-proof, chemically stable and radiation stable materials to be designed for ecological shells on their base. It was established that some types of glass-crystal materials have the properties, which are valid for application as ecological shells

  2. Radioactive liquid waste processing system

    International Nuclear Information System (INIS)

    Inakuma, Masahiko; Takahara, Nobuaki; Hara, Satomi.

    1996-01-01

    Laundry liquid wastes and shower drains containing radioactive materials generated in a nuclear power plant are removed with radioactive materials by a fiber filtration device and an activated carbon filtration device to satisfy standers of water quality described in the environmental effect investigation report. Spent activated carbon is dehydrated together with the back-wash liquid from the fiber filtration device and the activated carbon filtration device using a Nutsche-type filtration dryer. With such procedures, the scale of the facility is minimized, space for devices, maintenance for equipments and radiation dose rate are reduced. (T.M.)

  3. Radioactive liquid waste processing method

    International Nuclear Information System (INIS)

    Nishi, Takashi; Baba, Tsutomu; Fukazawa, Tetsuo; Matsuda, Masami; Chino, Koichi; Ikeda, Takashi.

    1993-01-01

    As an adsorbent used for removing radioactive nuclides such as cesium and strontium from radioactive liquid wastes generated from a reprocessing plant, a silicon compound having siloxane bonds constituted by silicon and oxygen and having silanol groups constituted by silicon, oxygen and hydrogen, or an inorganic material mainly comprising aluminosilicate constituted with silicon, oxygen and aluminum is used. In the adsorbent of the present invention, since silica main skeletons are partially decomposed in an aqueous alkaline solution to newly form silanol groups having a cation adsorbing property, pretreatment such as pH adjustment is not necessary. (T.M.)

  4. Innocuous management of radioactive wastes

    International Nuclear Information System (INIS)

    Vargas, C.

    1997-01-01

    The relations between peaceful uses and bellicose uses of the nuclear energy are complexes in relation to international establishment of norms to control the destiny of the radioactive materials, above all in the context of the existing international legislation of respect to the autonomy of the countries, and in the determination of the institution or institutions upon the ones that would fall on. The nuclear safeguards of materials and the possibilities of performing their function. Important efforts have been done to unify, to help and to impose international measures on the behalf of an environmentally harmless processing of the radioactive wastes [es

  5. Radioactive waste management in Lebanon

    International Nuclear Information System (INIS)

    Assi, Muzna

    2011-01-01

    The disused sealed radioactive sources including orphan sources in Lebanon, along with the growing industry of sealed radioactive sources in medical, industrial and research fields have posed a serious problem for authorities as well as users due to the lack of a national store for disused radioactive sources. Assistance from the International Atomic Energy Agency (IAEA) was requested to condition and store disused radium needles and tubes present at two facilities. The mission took place on July 25, 2001 and was organized by the IAEA in cooperation with the Lebanese Atomic Energy Commission (LAEC). Other disused radioactive sources were kept in the facilities till a safer and securer solution is provided; however orphan sources, found mainly during export control, were brought and stored temporarily in LAEC. The necessity of a safe and secure store became a must. Prior to October 2005, there was no clear legal basis for establishing such store for disused radioactive sources, until the ministerial decree no 15512 dated October 19, 2005 (related to the implementation of decree-law no 105/83) was issued which clearly stated that 'The LAEC shall, in cooperation with the Ministry of Public Health, establish a practical mechanism for safe disposal of radioactive waste'. Following this, the work on inventory of disused sealed sources along with collecting orphan sources and placing them temporarily in LAEC was legally supported. Moreover, several missions were planned to repatriate category I and II sources, one of which was completed specifically in August 2009; other missions are being worked on. In 2008, a national technical cooperation project with the IAEA was launched. Under the Technical Cooperation (TC) project with reference number LEB3002, the project was entitled 'Assistance in the establishment of a safe temporary national storage at the LAEC for orphan sources and radioactive waste' which cycle is 2009-2011. Under this project, a national store for

  6. Radioactive waste vitrification: A review

    International Nuclear Information System (INIS)

    Cole, L.L.; Fields, D.E.

    1989-08-01

    The research and development of an immobilization process for the containment of nuclear high-level liquid waste has been underway for well-over the past four decades. The method that has become the state-of-the-art is the liquid-fed ceramic melter process which converts a mixture of high-level liquid waste and glass forming frit to a borosilicate glass product. This report gives a chronological review of the various vitrification processes starting with the very first reported process in 1960. Information on the early methods of frit selection as well as information on the currently computerized method are presented. The importance of all these parameters is discussed with regard to product durability. 26 refs., 8 figs., 1 tab

  7. Classification of Radioactive Waste. General Safety Guide

    International Nuclear Information System (INIS)

    2009-01-01

    This publication is a revision of an earlier Safety Guide of the same title issued in 1994. It recommends revised waste management strategies that reflect changes in practices and approaches since then. It sets out a classification system for the management of waste prior to disposal and for disposal, driven by long term safety considerations. It includes a number of schemes for classifying radioactive waste that can be used to assist with planning overall national approaches to radioactive waste management and to assist with operational management at facilities. Contents: 1. Introduction; 2. The radioactive waste classification scheme; Appendix: The classification of radioactive waste; Annex I: Evolution of IAEA standards on radioactive waste classification; Annex II: Methods of classification; Annex III: Origin and types of radioactive waste

  8. Classification of Radioactive Waste. General Safety Guide

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-11-15

    This publication is a revision of an earlier Safety Guide of the same title issued in 1994. It recommends revised waste management strategies that reflect changes in practices and approaches since then. It sets out a classification system for the management of waste prior to disposal and for disposal, driven by long term safety considerations. It includes a number of schemes for classifying radioactive waste that can be used to assist with planning overall national approaches to radioactive waste management and to assist with operational management at facilities. Contents: 1. Introduction; 2. The radioactive waste classification scheme; Appendix: The classification of radioactive waste; Annex I: Evolution of IAEA standards on radioactive waste classification; Annex II: Methods of classification; Annex III: Origin and types of radioactive waste.

  9. Role of lead as modifier on the properties of lead iron phosphate nuclear waste glasses

    International Nuclear Information System (INIS)

    Hazra, G.; Mitra, P.; Das, T.

    2011-01-01

    Lead-iron phosphate glasses are a promising new waste form for the safe immobilization of both high level defence and high level commercial radioactive waste for long term disposal. Lead iron phosphate glasses have several advantages such as lower aqueous corrosion rate, lower processing temperature etc. (author)

  10. Radioactive waste management at KANUPP

    International Nuclear Information System (INIS)

    Tahir, Tariq B.; Qamar Ali

    2001-01-01

    This paper describes the existing radioactive waste management scheme of KANUPP. The radioactive wastes generated at KANUPP are in solid, liquid and gaseous forms. The spent fuel of the plant is stored underwater in the Spent Fuel Bay. For long term storage of low and intermediate level solid waste, 3m deep concrete lined trenches have been provided. The non-combustible material is directly stored in these trenches while the combustible material is first burnt in an incinerator and the ash is collected, sealed and also stored in the trenches. The low-level liquid and gaseous effluents are diluted and are discharged into the sea and the atmosphere. The paper also describes a modification carried out in the spent resin collection system in which a locally designed removable tank replaced the old permanent tanks. Presently the low level combustible solid waste is incinerated and stored, but it is planned to replace the present method by using compactor and storing the compacted waste in steel drums underground. (author)

  11. Radioactive waste management in Canada

    International Nuclear Information System (INIS)

    1990-11-01

    This bibliography is a review of the Canadian literature on radioactive waste management from 1953 to the present. It incorporates the references from the previous AECL--6186 revisions, and adds the current data and some of the references that had been omitted. Publications from outside organizations of concern to the Canadian Nuclear Fuel Waste Program are included in addition to AECL Research reports and papers. This report is intended as an aid in the preparation of the Concept Assessment Document and is complementary to AECL Research's internal document-ready references on the MASS-11 word processing systems

  12. Chemical treatment of radioactive wastes

    International Nuclear Information System (INIS)

    Pottier, P.E.

    1968-01-01

    This is the third manual of three commissioned by the IAEA on the three principal techniques used in concentrating radioactive liquid wastes, namely chemical precipitation, evaporation and ion exchange. The present manual deals with chemical precipitation by coagulation-flocculation and sedimentation, commonly called ''chemical treatment'' of low-activity wastes. Topics discussed in the manual are: (i) principles of coagulation on flocculation and sedimentation and associated processes; (ii) process and equipment; (iii) conditioning and disposal of flocculation sludge; (iv) sampling and the equipment required for experiments; and (v) factors governing the selection of processes. 99 refs, 17 figs, 4 tabs

  13. Radioactive waste and public acceptance

    International Nuclear Information System (INIS)

    Perkins, B.

    1977-01-01

    Radioactive waste just happens to be the major issue in the public eye now--it could be replaced by another issue later. A survey is quoted to prove that wastes are not really one of the burning national issues of the day. The people opposing the nuclear program cannot be said to represent the public. The taste of the press for the melodramatic is pointed out. The issue needs to be presented with the proper perspective, in the context of the benefits and risks of nuclear power

  14. Comparative consideration and design of a security depot for high radioactive glass-enclosed materials

    International Nuclear Information System (INIS)

    Jaroni, U.

    1985-01-01

    From the beginning of 1990 the COGEMA shall supply glass-enclosed high radioactive waste of the reprocessing of German fuel elements back to the Federal Republic of Germany. As to this time the final waste storage in the salt stock of Gorleben will not be available the glass cannisters have to be deposited above ground. First a comparison is made out of a number of proposed storage concepts for the deposition of HAW-glass blocks. The safety technical behaviour of the facility is considered. On the basis of the gained results a new facility design is presented, which can take 450 glass cannisters in a discoid built up cast-steel vessel and makes possible the utilization of the resulting radioactive heat of dissociation. During the development of this concept besides a compact, reasonable method of building and the thermodynamic behaviour of the storage the aspect of high security against release of radioactive materials was emphasized. (orig.) [de

  15. Low-level radioactive waste

    International Nuclear Information System (INIS)

    McLaren, L.H.

    1983-03-01

    This bibliography contains information on low-level radioactive waste included in the Department of Energy's Energy Data Base for January through December 1982. The abstracts are grouped by subject category as shown in the table of contents. Entries in the subject index also facilitate access by subject, e.g., Low-Level Radioactive Wastes/Transport. Within each category the arrangement is by report number for reports, followed by nonreports in reverse chronological order. These citations are to research reports, journal articles, books, patents, theses, and conference papers from worldwide sources. Five indexes, each proceded by a brief description, are provided: Corporate Author, Personal Author, Subject, Contract Number, and Report Number. 492 references

  16. Shallow disposal of radioactive waste

    International Nuclear Information System (INIS)

    1985-02-01

    A review and evaluation of computer codes capable of simulating the various processes that are instrumental in determining the dose rate to individuals resulting from the shallow disposal of radioactive waste was conducted. Possible pathways of contamination, as well as the mechanisms controlling radionuclide movement along these pathways have been identified. Potential transport pathways include the unsaturated and saturated ground water systems, surface water bodies, atmospheric transport and movement (and accumulation) in the food chain. Contributions to dose may occur as a result of ingestion of contaminated water and food, inhalation of contaminated air and immersion in contaminated air/water. Specific recommendations were developed regarding the selection and modification of a model to meet the needs associated with the prediction of dose rates to individuals as a consequence of shallow radioactive waste disposal. Specific technical requirements with regards to risk, sensitivity and uncertainty analyses have been addressed

  17. Lead iron phosphate glass as a containment medium for disposal of high-level nuclear waste

    International Nuclear Information System (INIS)

    Boatner, L.A.; Sales, B.C.

    1989-01-01

    This patent describes lead-iron phosphate glasses containing a high level of Fe 2 O 3 for use as a storage medium for high-level radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste, a highly corrosion resistant, homogeneous, easily processed glass can be formed. For corroding solutions at 90 0 C, with solution pH values in the range between 5 and 9, the corrosion rate of the lead-iron phosphate nuclear waste glass is at least 10 2 to 10 3 times lower than the corrosion rate of a comparable borosilicate nuclear waste glass. The presence of Fe 2 O 3 in forming the lead-iron phosphate glass is critical. The lead-iron phosphate waste glasses can be prepared with minimal modification of the technology developed for processing borosilicate glass nuclear wasteforms

  18. Radioactive waste interim storage in Germany

    International Nuclear Information System (INIS)

    2015-12-01

    The short summary on the radioactive waste interim storage in Germany covers the following issues: importance of interim storage in the frame of radioactive waste management, responsibilities and regulations, waste forms, storage containers, transport of vitrified high-level radioactive wastes from the reprocessing plants, central interim storage facilities (Gorleben, Ahaus, Nord/Lubmin), local interim storage facilities at nuclear power plant sites, federal state collecting facilities, safety, radiation exposure in Germany.

  19. Radioactive lightning rods waste treatment

    International Nuclear Information System (INIS)

    Vicente, Roberto; Dellamano, Jose C.; Hiromoto, Goro

    2008-01-01

    Full text: In this paper, we present alternative processes that could be adopted for the management of radioactive waste that arises from the replacement of lightning rods with attached Americium-241 sources. Lightning protectors, with Americium-241 sources attached to the air terminals, were manufactured in Brazil until 1989, when the regulatory authority overthrew the license for fabrication, commerce, and installation of radioactive lightning rods. It is estimated that, during the license period, about 75,000 such devices were set up in public, commercial and industrial buildings, including houses and schools. However, the policy of CNEN in regard to the replacement of the installed radioactive rods, has been to leave the decision to municipal governments under local building regulations, requiring only that the replaced rods be sent immediately to one of its research institutes to be treated as radioactive waste. As a consequence, the program of replacement proceeds in a low pace and until now only about twenty thousand rods have reached the waste treatment facilities The process of management that was adopted is based primarily on the assumption that the Am-241 sources will be disposed of as radioactive sealed sources, probably in a deep borehole repository. The process can be described broadly by the following steps: a) Receive and put the lightning rods in initial storage; b) Disassemble the rods and pull out the sources; c) Decontaminate and release the metal parts to metal recycling; d) Store the sources in intermediate storage; e) Package the sources in final disposal packages; and f) Send the sources for final disposal. Up to now, the disassembled devices gave rise to about 90,000 sources which are kept in storage while the design of the final disposal package is in progress. (author)

  20. Radioactive waste solidifying material

    International Nuclear Information System (INIS)

    Ono, Keiichi; Sakai, Etsuro.

    1989-01-01

    The solidifying material according to this invention comprises cement material, superfine powder, highly water reducing agent, Al-containing rapid curing material and coagulation controller. As the cement material, various kinds of quickly hardening, super quickly hardening and white portland cement, etc. are usually used. As the superfine powder, those having average grain size smaller by one order than that of the cement material are desirable and silica dusts, etc. by-produced upon preparing silicon, etc. are used. As the highly water reducing agent, surface active agents of high decomposing performance and comprising naphthalene sulfonate, etc. as the main ingredient are used. As the Al-containing rapidly curing material, calcium aluminate, etc. is used in an amount of less than 10 parts by weight based on 100 parts by weight of the powdery body. As the coagulation controller, boric acid etc. usually employed as a retarder is used. This can prevent dissolution or collaption of pellets and reduce the leaching of radioactive material. (T.M.)

  1. Incinerator for radioactive wastes

    International Nuclear Information System (INIS)

    Warren, J.H.; Hootman, H.E.

    1981-01-01

    A two-stage incinerator is provided which includes a primary combustion chamber and an afterburn chamber for off-gases. The latter is formed by vertical tubes in combination with associated manifolds which connect the tubes together to form a continuous tortuous path. Electrically-controlled heaters surround the tubes while electrically-controlled plate heaters heat the manifolds. A gravity-type ash removal system is located at the bottom of the first afterburner tube while an air mixer is disposed in that same tube just above the outlet from the primary chamber. A ram injector in combination with rotary a magazine feeds waste to a horizontal tube forming the primary combustion chamber. (author)

  2. What to do with radioactive wastes?

    International Nuclear Information System (INIS)

    2006-01-01

    This power point presentation (82 slides) gives information on what is a radioactive waste, radioactivity and historical review of radioactivity, radioactive period, natural radioactivity (with examples of data), the three main radiation types (α, β, γ), the origin of radioactive wastes (nuclear power, research, defense, other), the proportion of radioactive wastes in the total of industrial wastes in France, the classification of nuclear wastes according to their activity and period, the quantities and their storage means, the 1991 december 30 law (France) related to the radioactive waste management, the situation in other countries (Germany, Belgium, Canada, USA, Finland, Japan, Netherlands, Sweden, Switzerland), volume figures and previsions for the various waste types in 2004, 2010 and 2020, the storage perspectives, the French national debate on radioactive waste management and the objective of perpetuated solutions, the enhancement of the public information, the 15 June 2006 law on a sustainable management of radioactive materials and wastes with three main axis (deep separation and transmutation, deep storage, waste conditioning and long term surface storage), and the development of a nuclear safety and waste culture that could be extended to other types of industry

  3. Radioactive waste inventories and projections

    International Nuclear Information System (INIS)

    McLaren, L.H.

    1982-11-01

    This bibliography contains information on radioactive waste inventories and projections included in the Department of Energy's Energy Data Base from January 1981 through September 1982. The arrangement is by report number for reports, followed by nonreports in reverse chronological order. These citations are to research reports, journal articles, books, patents, theses, and conference papers from worldwide sources. Five indexes, each preceded by a brief description, are provided: Corporate Author, Personal Author, Subject, Contract Number, and Report Number. (25 abstracts)

  4. Management of radioactive medical waste

    International Nuclear Information System (INIS)

    Deschamps, S.; Mathey, J.C.

    1996-01-01

    Hospitals are producers of small amounts of radioactive waste. Current legislation details exactly how hospitals should manage it. Sealed sources are returned to suppliers. Disposal of unsealed sources, liquid or solid, depends upon their half-life: short-lived radioisotopes (half-life less than two months) are stocked on site while they decay; isotopes with longer half-lives (greater than two months) are handled by a specialist organization (ANDRA). (authors). 8 refs

  5. Public Education and Radioactive Waste

    International Nuclear Information System (INIS)

    Sarten, S.

    2009-01-01

    Throughout the country the mention of anything nuclear or the word radiation ignites fear in the minds of many Americans. Political hype, news stories and the lack of basic understanding about nuclear power and radiation causes many people to reject what they do not understand. Often little, if any, thought may have been given to nearby nuclear weapons facilities where family members and neighbors were gainfully employed at these sites. As older nuclear facilities are closed being a result of the end of the Cold War, with indications that radioactive materials might be transported to other parts of the country, the public in expressing concern. It is important that the public have an understanding of how these materials are handled to insure public safety. It becomes important that both the companies handling these materials and the U.S. Department of Energy create an environment that will involve community participation in developing strategies that will promote and support an understanding of how radioactive wastes will be packaged, transported, and disposed. This is being performed in Oak Ridge, TN. through the efforts of the Oak Ridge Site Specific Advisory Board (ORSSAB). The ORSSAB is a DOE sponsored board of private citizens from all walks of life and professionalism's. The objective of this paper is to offer suggestions as to how public confidence, through education about nuclear, radioactive and associated and wastes are effectively handle the problems related to waste disposal, removal or on-site storage. It is essential that the public fully understand and become involved in the need for the reduction of the waste stream volumes and the technical problems being faced in reaching this goal. The effort of gaining public understanding and support of this important task cannot be limited to just those within close proximity to the facility presently housing these materials, but must extend to those outlying areas and along any potential route that might be

  6. Stress and radioactive waste management

    International Nuclear Information System (INIS)

    Williams, R.G.; Olshansky, S.J.

    1987-01-01

    In the Supreme Court case ''People Against Nuclear Energy (PANE) vs Metropolitan Edison,'' one of the conclusions was that the Nuclear Regulatory Commission did not have to consider psychological distress, community cohesiveness and sense of well-being in the supplement to the Environmental Impact Statement (EIS) covering the restart of Three Mile Island (TMI). This decision was based on the assumption that the intention of the National Environmental Policy Act (NEPA) is to focus on the physical environment, and the casual chain between psychological distress and adverse health effects is tenuous. In this paper the authors summarize the literature on the relationship between environmentally-induced stress and its effects on health. They present the results of a new survey research project in which levels of stress were evaluated in West Chicago, Illinois, a community in which radioactive wastes have been present for many years. Explanatory social variables are brought into the evaluation in which stress is evaluated as a function of proximity to the radioactive waste site. In addition, stress is discussed in the context of attitudes on nuclear power, environmental group participation, and knowledge about the health effects associated with radioactive waste. The paper ends with a discussion of the portion of the Supreme Court decision in which psychological distress, community stability, cohesiveness and sense of well being are excluded as variables to address in EISs

  7. Media analysis of radioactive wastes

    International Nuclear Information System (INIS)

    Janowski, M.J.

    1989-01-01

    The radioactive waste cleanup community has not effectively utilized its most powerful communications tool to inform the general public; the print and broadcast media. Environmental interest groups have known of the value of accessing the media for their message for years and have used it effectively. The radioactive waste cleanup community's efforts to date have not been focused on education of the media so that they in turn can inform the public of our cleanup mission. Their focus must be to learn of the importance of the media, develop training programs that train technical people in how to know and respond to the media's needs for information, and then incorporate that training into a comprehensive program of public information in which access to the media is a key communications tool. This paper discusses how media education and access is a cost-effective means of accomplishing community relations goals of public information and public participation in radioactive waste cleanup and has been effectively utilized at the Weldon Spring Site Remedial Action Project

  8. Final storage of radioactive waste

    International Nuclear Information System (INIS)

    Ziehm, Cornelia

    2015-01-01

    As explained in the present article, operators of nuclear power plants are responsible for the safe final disposal of the radioactive wastes they produce on the strength of the polluter pays principle. To shift the burden of responsibility for safe disposal to society as a whole would violate this principle and is therefore not possible. The polluter pays principle follows from more general principles of the fair distribution of benefits and burdens. Instances of its implementation are to be found in the national Atomic Energy Law as well as in the European Radioactive Waste and Spent Fuel Management Directive. The polluters in this case are in particular responsible for financing the installation and operation of final disposal sites. The reserves accumulated so far for the decommissioning and dismantling of nuclear power plants and disposal of radioactive wastes, including the installation and operation of final disposal sites, should be transferred to a public-law fund. This fund should be supplemented by the polluters to cover further foreseeable costs not covered by the reserves accumulated so far, including a realistic cost increase factor, appropriate risk reserves as well as the costs of the site selection procedure and a share in the costs for the safe closure of the final disposal sites of Morsleben and Asse II. This would merely be implementing in the sphere of atomic law that has long been standard practice in other areas of environmental law involving environmental hazards.

  9. Radioactive Waste and Clean-up Division

    International Nuclear Information System (INIS)

    Collard, G.

    2001-01-01

    The main objectives of the Radioactive Waste and Clean-up division of SCK-CEN are outlined. The division's programme consists of research, development and demonstration projects and aims to contribute to the objectives of Agenda 21 on sustainable development in the field of radioactive waste and rehabilitation of radioactively contaminated sites

  10. A method for conditioning radioactive-wastes

    International Nuclear Information System (INIS)

    Cuaz, Daniel; Thiery, Daniel.

    1974-01-01

    Description is given of a method for conditioning radioactive-wastes, according to the main patent. This method is characterized in that the radioactive wastes are constituted by radio-elements incorporated with filtration and/or floculation promoters. This can be applied to radioactive effluent processing [fr

  11. Radioactive Waste Management BasisSept 2001

    International Nuclear Information System (INIS)

    Goodwin, S.S.

    2011-01-01

    This Radioactive Waste Management Basis (RWMB) documents radioactive waste management practices adopted at Lawrence Livermore National Laboratory (LLNL) pursuant to Department of Energy (DOE) Order 435.1, Radioactive Waste Management. The purpose of this RWMB is to describe the systematic approach for planning, executing, and evaluating the management of radioactive waste at LLNL. The implementation of this document will ensure that waste management activities at LLNL are conducted in compliance with the requirements of DOE Order 435.1, Radioactive Waste Management, and the Implementation Guide for DOE manual 435.1-1, Radioactive Waste Management Manual. Technical justification is provided where methods for meeeting the requirements of DOE Order 435.1 deviate from the DOE Manual 435.1-1 and Implementation Guide.

  12. Method of storing radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, M; Kamiya, K; Sugimoto, Y

    1976-01-09

    A method is claimed to decrease the number of storage containers filled with radioactive wastes. A wire-netting containers having a capacity of 67 liters is filled with 60 kg of pellet-like radioactive solid material. The wire-netting container is held in the middle of a drum can, and asphalt is poured between the drum can and the wire-netting container and stored until radioactivity is attenuated. After storage, the stored body is heated to melt the asphalt and the wire-netting container is removed. Thereafter, the pellet-like radioactive solid material is taken out of the wire-netting container and combined with the other pellet-like radioactive solid material similarly taken out of the storage container, and the resultant material is filled into a wire-netting container having a capacity of 167 liters every 150 kg, and inserted again into the same drum can, into which recovered asphalt is poured for final storage.

  13. Radioactive waste management - an educational challenge

    International Nuclear Information System (INIS)

    Tulenko, J.S.

    1991-01-01

    University Radioactive Waste Management educational programs are being actively advanced by the educational support activities of the Offices of Civilian Radioactive Waste Management (OCRWM) and Environmental Restoration and Waste Management (ERWM) of the DOE. The DOE fellowship program formats of funding students and requiring a practical research experience (practicum) at a DOE site has helped to combine the academic process with a practical work experience. Support for faculty in these programs is augmenting the benefits of the fellowship programs. The many job opportunities and funding sources for students which currently exists in the radioactive waste management area are fueling an increase in academic programs seeking recognition of their radioactive waste management curriculums

  14. Waterproofing improvement of radioactive waste asphalt solid

    International Nuclear Information System (INIS)

    Adachi, Katsuhiko; Yamaguchi, Takashi; Ikeoka, Akira.

    1981-01-01

    Purpose: To improve the waterproofing of asphalt solid by adding an alkaline earth metal salt and, further, paraffin, into radioactive liquid waste when processing asphalt solidification of the radioactive liquid waste. Method: Before processing molten asphalt solidification of radioactive liquid waste, soluble salts of alkaline earth metal such as calcium chloride, magnesium chloride, or the like is added to the radioactive liquid waste. Paraffin having a melting point of higher than 60 0 C, for example, is added to the asphalt, and waterproofing can be remarkably improved. The waste asphalt solid thus fabricated can prevent the swelling thereof, and can improve its waterproofing. (Yoshihara, H.)

  15. Radioactive liquid wastes processing device

    International Nuclear Information System (INIS)

    Sauda, Kenzo; Koshiba, Yukihiko; Yagi, Takuro; Yamazaki, Hideki.

    1985-01-01

    Purpose: To carry out optimum photooxidizing procession following after the fluctuation in the density of organic materials in radioactive liquid wastes to thereby realize automatic remote procession. Constitution: A reaction tank is equipped with an ultraviolet lamp and an ozone dispersing means for the oxidizing treatment of organic materials in liquid wastes under the irradiation of UV rays. There are also provided organic material density measuring devices to the inlet and outlet of the reaction tank, and a control device for controlling the UV lamp power adjusting depending on the measured density. The output of the UV lamp is most conveniently adjusted by changing the applied voltage. The liquid wastes in which the radioactivity dose is reduced to a predetermined level are returned to the reaction tank by the operation of a switching valve for reprocession. The amount of the liquid wastes at the inlet is controlled depending on the measured ozone density by the adjusting valve. In this way, the amount of organic materials to be subjected to photolysis can be kept within a certain limit. (Kamimura, M.)

  16. Method of processing radioactive wastes

    International Nuclear Information System (INIS)

    Matagi, Yoshihiko; Takahara, Akira; Ootsuka, Katsuyuki.

    1984-01-01

    Purpose: To avoid the reduction in the atmospheric insulation by preventing the generation of CO 2 , H 2 O, etc. upon irradiation of microwave heat. Method: Radioactive wastes are charged into a hopper, supplied on a conveyor, fed each by a predetermined amount to a microwave furnace and heated by microwaves applied from a microwave guide. Simultaneously, inert gases are supplied from a supply line. The Radioactive wastes to be treated are shielded by the inert gases to prevent the combustion of decomposed gases produced from the wastes upon irradiation of microwave heat to thereby prevent the generation of CO 2 , H 2 , etc., as well as the generated decomposed gases are diluted with the inert gases to decrease the dissociation of the decomposed gases to prevent the reduction in the atmospheric insulation. Since the spent inert gases can be recovered for reuse, the amount of gaseous wastes released to the atmosphere can be decreased and the working life of the high performance air filters can be extended. (Sekiya, K.)

  17. Predicting liquid immiscibility in multicomponent nuclear waste glasses

    International Nuclear Information System (INIS)

    Peeler, D.K.; Hrma, P.R.

    1994-01-01

    Taylor's model for predicting amorphous phase separation in complex, multicomponent systems has been applied to high-level (simulated) radioactive waste glasses at the U.S. Department of Energy's Hanford site. Taylor's model is primarily based on additions of modifying cations to a Na 2 O-B 2 O 3 -SiO 2 (NBS) submixture of the multicomponent glass. The position of the submixture relative to the immiscibility dome defines the development probability of amorphous phase separation. Although prediction of amorphous phase separation in Hanford glasses (via experimental SEM/TEM analysis) is the primary thrust of this work; reported durability data is also provides limited insight into the composition/durability relationship. Using a modified model similar to Taylor's, the results indicate that immiscibility may be predicted for multicomponent waste glasses by the addition of Li 2 O to the open-quotes alkaliclose quotes corner of the NBS submixture

  18. Predicting liquid immiscibility in multicomponent nuclear waste glasses

    International Nuclear Information System (INIS)

    Peeler, D.K.; Hrma, P.R.

    1994-04-01

    Taylor's model for predicting amorphous phase separation in complex, multicomponent systems has been applied to high-level (simulated) radioactive waste glasses at the US Department of Energy's Hanford site. Taylor's model is primarily based on additions of modifying cations to a Na 2 O-B 2 O 3 -SiO 2 (NBS) submixture of the multicomponent glass. The position of the submixture relative to the miscibility dome defines the development probability of amorphous phase separation. Although prediction of amorphous phase separation in Hanford glasses (via experimental SEM/TEM analysis) is the primary thrust of this work; reported durability data is also provides limited insight into the composition/durability relationship. Using a modified model similar to Taylor's, the results indicate that immiscibility may be predicted for multicomponent waste glasses by the addition of Li 2 O to the ''alkali'' corner of the NBS submixture

  19. Law on the management of radioactive waste

    International Nuclear Information System (INIS)

    1999-01-01

    This law regulate the relations of legal persons, enterprises without the rights of legal persons, and natural persons in the management of radioactive waste in Lithuania and establish the legal grounds for the management of radioactive waste. Thirty one article of the law deals with the following subjects: principles of radioactive waste management, competence of the Government, State Nuclear Power Safety Inspectorate, Ministry of Economy, Ministry of Environment and Radiation Protection Center in the sphere of regulation of the radioactive waste management, activities subject to licensing, issue of licences and authorisations, duties and responsibilities of the waste producer, founding of the radioactive waste management agency, its basic status and principles of the activities, functions of the agency, management of the agency, transfer of the radioactive waste to the agency, assessment of the existing waste management facilities and their past practices, siting, design and construction, safety assessment, commissioning and operation of the radioactive waste management facilities, radiation protection, quality assurance, emergency preparedness, decommissioning of radioactive waste storage and other facilities, post-closure surveillance of the repository, disused sealed sources, transportation, export and transit of radioactive waste

  20. Radioactive waste management in France

    International Nuclear Information System (INIS)

    Faussat, A.

    1988-01-01

    Solutions for radioactive waste management are already in existence and applied on an industrial scale for short-lived wastes. France has acquired an aknowledged expertise on the international level and several foreign contemporaries are interested in the relevant techniques developed. An intensive international cooperation has allowed to define bases for an underground deep repository for long-lived wastes. It is therefore important to choose a site which meets the expected storage conditions. This development work has been started in several countries in a similar way and which should be completed by the beginning of the next century. An 'open channel' with the public about this emotional topic can smooth the way for solutions by which mankind can master its technological challenges

  1. Thermal treatment of organic radioactive waste

    International Nuclear Information System (INIS)

    Chrubasik, A.; Stich, W.

    1993-01-01

    The organic radioactive waste which is generated in nuclear and isotope facilities (power plants, research centers and other) must be treated in order to achieve a waste form suitable for long term storage and disposal. Therefore the resulting waste treatment products should be stable under influence of temperature, time, radioactivity, chemical and biological activity. Another reason for the treatment of organic waste is the volume reduction with respect to the storage costs. For different kinds of waste, different treatment technologies have been developed and some are now used in industrial scale. The paper gives process descriptions for the treatment of solid organic radioactive waste of low beta/gamma activity and alpha-contaminated solid organic radioactive waste, and the pyrolysis of organic radioactive waste

  2. United Kingdom government policy towards radioactive waste

    International Nuclear Information System (INIS)

    Pritchard, G.

    1986-01-01

    There are three areas of radioactive waste management which exemplify, beyond any reasonable doubt, that the United Kingdom has in the past (and intends in the future), to pursue a policy of dispersal and disposal of radioactive wastes: These are: (I) dumping of low-level waste in the deep ocean and, on a parallel, seabed emplacement of highly active waste; (II) the liquid discharges from Windscale into the Irish Sea; and (III) land dumping of low- and intermediate-level waste

  3. Note from the Radioactive Waste Section

    CERN Multimedia

    TS Department

    2008-01-01

    The Radioactive Waste Section of the Radiation Protection Group wishes to announce that the radioactive waste treatment centre will be closed on Friday, 19 December. In addition, waste reception will be limited to a strict minimum on Thursday, 18 December. Users of the centre are requested to adjust their plans accordingly. For more information, call 73875.

  4. Instructive for radioactive solid waste management

    International Nuclear Information System (INIS)

    Mora Rodriguez, Patricia

    2014-01-01

    An instructive is established for the management system of radioactive solid residues waste of the Universidad de Costa Rica, ensuring the collection, segregation, storage and disposal of waste. The radioactive solid waste have been segregated and transferred according to features and provisions of the Universidad de Costa Rica and CICANUM [es

  5. Institutional arrangements for radioactive waste management

    International Nuclear Information System (INIS)

    Willrich, M.

    1976-01-01

    The existing organizational structure and regulations for management of high-level and TRU wastes are likely to become ineffective if left unchanged. Recommendations for institutional reforms include the establishment of a National Radioactive Waste Authority in the U.S. and of an International Radioactive Waste Commission under IAEA

  6. Electrical service and controls for Joule heating of a defense waste experimental glass melter

    International Nuclear Information System (INIS)

    Erickson, C.J.; Haideri, A.Q.

    1983-01-01

    Vitrification of radioactive liquid waste in a glass matrix is a leading candidate for long-term storage of high-level waste. This paper describes the electrical service and control system for an experimental electrically heated, nonradioactive glass melter installed at Savannah River Laboratory. Data accumulated, and design/operating experience acquired in operating this melter, are being used to design a modified melter to be installed in a processing area for use with radioactive materials

  7. Operation of the radioactive waste treatment facility

    International Nuclear Information System (INIS)

    Kim, Kil Jeong; Ahn, Seom Jin; Lee, Kang Moo; Lee, Young Hee; Sohn, Jong Sik; Bae, Sang Min; Kang, Kwon Ho; Lim, Kil Sung; Sohn, Young Joon; Kim, Tae Kook; Jeong, Kyung Hwan; Wi, Geum San; Park, Seung Chul; Park, Young Woong; Yoon, Bong Keun.

    1996-12-01

    The radioactive wasted generated at Korea Atomic Energy Research Institute (KAERI) in 1996 are about 118m 3 of liquid waste and 204 drums of solid waste. Liquid waste were treated by the evaporation process, the bituminization process, and the solar evaporation process. In 1996, 100.5m 3 of liquid waste was treated. (author). 84 tabs., 103 figs

  8. Mixed radioactive and chemotoxic wastes (RMW)

    International Nuclear Information System (INIS)

    Dejonghe, I.P.

    1991-01-01

    During the first decades of development of nuclear energy, organizations involved in the management of nuclear wastes had their attention focused essentially on radioactive components. The impression may have prevailed that, considering the severe restrictions on radioactive materials, the protection measured applied for radioactive components of wastes would be more than adequate to cope with potential hazards from non radioactive components associated with radioactive wastes. More recently it was acknowledged that such interpretation is not necessarily justified in all cases since certain radioactive wastes also contain non-negligible amounts of heavy metals or hazardous organic components which, either, do not decay, or are subject to completely different decay (decomposition) mechanisms. The main purposes of the present study are to analyze whether mixed radioactive wastes are likely to occur in Europe and in what form, whether one needs a basis for integration for evaluating various forms of toxicity and by which practical interventions possible problems can be avoided or at least reduced. (au)

  9. The Radioactive Waste Management at Studsvik

    Energy Technology Data Exchange (ETDEWEB)

    Hedlund, R; Lindskog, A

    1966-04-15

    The report was originally prepared as a contribution to the discussions in an IAEA panel on economics of radioactive waste management held in Vienna from 13 - 17 December 1965. It contains the answers and comments to the questions of a questionnaire for the panel concerning the various operations associated with the management (collection, transport, treatment, discharge, storage, and operational monitoring) of: - radioactive liquid wastes, except high-level effluents from reactor fuel recovering operations; - solid wastes, except those produced from treatment of high level wastes; - gaseous wastes produced from treatment of the foregoing liquid and solid wastes; - equipment decontamination facilities and radioactive laundries.

  10. Sponsored research on radioactive waste management

    International Nuclear Information System (INIS)

    1983-01-01

    The report is in chapters entitled: introduction (background, responsibilities, options, structure of the programme); strategy development; disposal of accumulations; disposal of radioactive waste arisings; quality assurance for waste conditioning quality assurance related to radioactive waste disposal (effectiveness of different rock types as natural barriers to the movement of radioactivity, and non-site specific factors in the design of repositories; radiological assessment; environmental studies; research and development to meet requirements specific to UKAEA wastes; long term research (processes for the solidification of highly active liquid wastes); plutonium contamination waste minimisation. (U.K.)

  11. The Radioactive Waste Management at Studsvik

    International Nuclear Information System (INIS)

    Hedlund, R.; Lindskog, A.

    1966-04-01

    The report was originally prepared as a contribution to the discussions in an IAEA panel on economics of radioactive waste management held in Vienna from 13 - 17 December 1965. It contains the answers and comments to the questions of a questionnaire for the panel concerning the various operations associated with the management (collection, transport, treatment, discharge, storage, and operational monitoring) of: - radioactive liquid wastes, except high-level effluents from reactor fuel recovering operations; - solid wastes, except those produced from treatment of high level wastes; - gaseous wastes produced from treatment of the foregoing liquid and solid wastes; - equipment decontamination facilities and radioactive laundries

  12. High level radioactive waste management facility design criteria

    International Nuclear Information System (INIS)

    Sheikh, N.A.; Salaymeh, S.R.

    1993-01-01

    This paper discusses the engineering systems for the structural design of the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS). At the DWPF, high level radioactive liquids will be mixed with glass particles and heated in a melter. This molten glass will then be poured into stainless steel canisters where it will harden. This process will transform the high level waste into a more stable, manageable substance. This paper discuss the structural design requirements for this unique one of a kind facility. A special emphasis will be concentrated on the design criteria pertaining to earthquake, wind and tornado, and flooding

  13. Radioactive liquid waste processing device

    International Nuclear Information System (INIS)

    Murakami, Susumu; Kuroda, Noriko; Matsumoto, Hiroyo.

    1991-01-01

    The present device comprises a radioactive liquid wastes concentration means for circulating radioactive liquid wastes between each of the tank, a pump and a film evaporator thereby obtaining liquid concentrates and a distilled water recovery means for condensing steams separated by the film evaporator by means of a condenser. It further comprises a cyclizing means for circulating the resultant distilled water to the upstream after the concentration of the liquid concentrates exceeds a predetermined value or the quality of the distilled water reaches a predetermined level. Further, a film evaporator having hydrophilic and homogeneous films is used as a film evaporator. Then, the quality of the distilled water discharged from the present device to the downstream can always satisfy the predetermined conditions. Further, by conducting operation at high concentration while interrupting the supply of the processing liquids, high concentration up to the aimed concentration can be attained. Further, since the hydrophilic homogeneous films are used, carry over of the radioactive material accompanying the evaporation is eliminated to reduce the working ratio of the vacuum pump. (T.M.)

  14. Radioactive waste management in Germany

    International Nuclear Information System (INIS)

    Brammer, K.J.

    2011-01-01

    The responsibility for the disposal of radioactive waste is regulated in the Federal Republic of Germany in the Atomic Energy Act. Basically, it is the responsibility of the waste producers to carry out all necessary processing steps up to the delivery to a repository. The Federal Republic reserves the right to select, explore and operate the repository (§ 9a, para. 3 AtG). The costs of all necessary expenditures of this task are borne by the waste producers in accordance with § 21 AtG regulation. The waste quantity forecasts have shown that by the year 2080 a total volume of about 300,000 m3 of low- and intermediate-level (non-heat-generating) waste will be generated in research, industry, medicine and in the production of electricity in nuclear power plants. This waste is to be transported to the ‘Konrad repository’ which is under construction. The Federal Office for Radiation Protection (BfS), which is responsible for the construction and operation, intends to commission the repository at 2019. As a repository for heat-generating wastes, i. Approximately 10.000 tSM spent fuel (BE) 7,500 molds (HAW and MAW, corresponding to about 6000 tSM) returned Waste from reprocessing, the Gorleben salt dome has been explored since 1979. The works were resumed on 01.10.2010 after a 10-year break. Federal Environment Minister Röttgen has made it clear that the Federal Government has proposed a transparent procedure and a dialogue and participation procedure for open-ended exploration. (roessner)

  15. Relative leach behavior of waste glasses and naturally occurring glasses

    International Nuclear Information System (INIS)

    Adams, P.B.

    1979-01-01

    Simulated nuclear waste glasses of the sodium-borosilicate type with a low waste loading and of the zinc-borosilicate type with a high waste loading have been compared with obsidians. The resuls indicate that the waste glasses would corrode in normal natural environments at a rate of about 0.1 μm per year at 30 0 C and about 5 μm per year at 90 0 C, compared with obsidians which seem to corrode at, or less than, about 0.01 μm per year at 30 0 C and less than 1 μm per year at 90 0 C. Activation energies for reactions of the two waste glasses with pure water are about 20 kcal/g-mol. 3 figures, 7 tables

  16. FFTF radioactive solid waste handling and transport

    International Nuclear Information System (INIS)

    Thomson, J.D.

    1982-01-01

    The equipment necessary for the disposal of radioactive solid waste from the Fast Flux Test Facility (FFTF) is scheduled to be available for operation in late 1982. The plan for disposal of radioactive waste from FFTF will utilize special waste containers, a reusable Solid Waste Cask (SWC) and a Disposable Solid Waste Cask (DSWC). The SWC will be used to transport the waste from the Reactor Containment Building to a concrete and steel DSWC. The DSWC will then be transported to a burial site on the Hanford Reservation near Richland, Washington. Radioactive solid waste generated during the operation of the FFTF consists of activated test assembly hardware, reflectors, in-core shim assemblies and control rods. This radioactive waste must be cleaned (sodium removed) prior to disposal. This paper provides a description of the solid waste disposal process, and the casks and equipment used for handling and transport

  17. Neural network analysis of nuclear waste glass composition vs durability

    International Nuclear Information System (INIS)

    Seibel, C.K.

    1994-01-01

    The relationship between the chemical composition of oxide glasses and their physical properties is poorly understood, but it is becoming more important as vitrification (transformation into glass) of high-level nuclear waste becomes the favored method for long-term storage. The vitrified waste will be stored deep in geologic repositories where it must remain intact for at least 10,000 years. A strong resistance to groundwater exposure; i.c. a slow rate of glass dissolution, is of great importance. This project deals specifically with glass samples developed and tested for the nuclear fuel reprocessing facility near West Valley, New York. This facility needs to dispose of approximately 2.2 million liters of high-level radioactive liquid waste currently stored in stainless steel tanks. A self-organizing, artificial neural network was used to analyze the trends in the glass dissolution data for the effects of composition and the resulting durability of borosilicate glasses in an aqueous environment. This durability data can be used to systematically optimize the properties of the complex nuclear glasses and slow the dissolution rate of radionuclides into the environment

  18. Filters for radioactive liquid wastes

    International Nuclear Information System (INIS)

    Koshiba, Yukihiko; Kawashima, Akio

    1980-01-01

    In the crud generated in the reactor cooling water for nuclear power plants, iron oxides (hematite and magnetite) are contained as the main components, and also Co, Mn, Fe, Cr exist as radioactive nuclides. A new filter to separate these cruds, nuclepore membrane filter (NPMF), was investigated for its adaptability, and has been adopted as a practical filter for radioactive liquid wastes. The NPMF has such features as the possibility of complete automation of operation, no generation of secondary wastes, and easy maintenance, because the NPMF has uniform circular holes in poly-carbonate thin films, and shows the properties of stable filtering of particulates, capability of back washing, and others. The elements mounted in a practical system have such construction that the membrane is cut in the form of doughnut, and sandwiched with 100 mesh polyester nets (spacer); the obtained unit filter (cassette) is mounted on the stackable plate of the same size; and 80 pieces of this cassette are formed in a filter of 4 m 2 filtering area. The performance varies with the properties of suspended matters and the turbidity of wastes. For example, the filtered liquid of 0.1 ppm or less can be obtained when the 1 μm filter material is used to treat the liquid waste containing 1 to 100 ppm suspended matters. Usually back washed water is produced by about 1/100 of treated liquid wastes. The lifetime of the membrane is expected to be 1 or 2 years if crud is the main component. (Wakatsuki, Y.)

  19. Radioactive wastes management: what is the situation?

    International Nuclear Information System (INIS)

    2002-01-01

    This presentation takes stock on the situation of the radioactive wastes management in France. It gives information on the deep underground disposal, the public information, the management of the radioactive wastes in France, the researches in the framework of the law of the 30 december 1991, the underground laboratory of Meuse/Haute-Marne, the national agency for the radioactive wastes management (ANDRA) and its sites. (A.L.B.)

  20. Method of processing radioactive liquid wastes

    Energy Technology Data Exchange (ETDEWEB)

    Sugimoto, Y; Kikuchi, M; Funabashi, K; Yusa, H; Horiuchi, S

    1978-12-21

    Purpose: To decrease the volume of radioactive liquid wastes essentially consisting of sodium hydroxide and boric acid. Method: The concentration ratio of sodium hydroxide to boric acid by weight in radioactive liquid wastes essentially consisting of sodium hydroxide and boric acid is adjusted in the range of 0.28 - 0.4 by means of a pH detector and a sodium concentration detector. Thereafter, the radioactive liquid wastes are dried into powder and then discharged.

  1. Financing of radioactive waste disposal

    International Nuclear Information System (INIS)

    Reich, J.

    1989-01-01

    Waste disposal is modelled as a financial calculus. In this connection the particularity is not primarily the dimension to be expected of financial requirement but above all the uncertainty of financial requirement as well as the ecological, socio-economic and especially also the temporal dimension of the Nuclear Waste Disposal project (disposal of spent fuel elements from light-water reactors with and without reprocessing, decommissioning = safe containment and disposal of nuclear power plants, permanent isolation of radioactive waste from the biosphere, intermediate storage). Based on the above mentioned factors the author analyses alternative approaches of financing or financial planning. He points out the decisive significance of the perception of risks or the evaluation of risks by involved or affected persons - i.e. the social acceptance of planned and designed waste disposal concepts - for the achievement and assessment of alternative solutions. With the help of an acceptance-specific risk measure developed on the basis of a mathematical chaos theory he illustrates, in a model, the social influence on the financing of nuclear waste disposal. (orig./HP) [de

  2. Underground disposal of radioactive wastes

    International Nuclear Information System (INIS)

    1981-01-01

    This report is an overview document for the series of IAEA reports dealing with underground waste disposal to be prepared in the next few years. It provides an introduction to the general considerations involved in implementing underground disposal of radioactive wastes. It suggests factors to be taken into account for developing and assessing waste disposal concepts, including the conditioned waste form, the geological containment and possible additional engineered barriers. These guidelines are general so as to cover a broad range of conditions. They are generally applicable to all types of underground disposal, but the emphasis is on disposal in deep geological formations. Some information presented here may require slight modifications when applied to shallow ground disposal or other types of underground disposal. Modifications may also be needed to reflect local conditions. In some specific cases it may be that not all the considerations dealt with in this book are necessary; on the other hand, while most major considerations are believed to be included, they are not meant to be all-inclusive. The book primarily concerns only underground disposal of the wastes from nuclear fuel cycle operations and those which arise from the use of isotopes for medical and research activities

  3. Chemical decontamination method for radioactive metal waste

    International Nuclear Information System (INIS)

    Onuma, Tsutomu; Akimoto, Hidetoshi

    1991-01-01

    The invention relates to a decontamination method for radioactive metal waste products derived from equipment that handles radioactive materials whose surfaces have been contaminated; in particular it concerns a decontamination method that reduces the amount of radioactive waste by decontaminating radioactive waste substances to a level of radioactivity in line with normal waste products. In order to apply chemical decontamination to metal waste products whose surfaces are divided into carbon steel waste and stainless steel waste; the carbon steel waste is treated using only a primary process in which the waste is immersed in a sulfuric acid solution, while the stainless steel waste must be treated with both the primary process and then electrolytically reduces it for a specific length of time and a secondary process that uses a solution of sulfuric acid mixed with oxidizing metal salts. The method used to categorize metal waste into carbon steel waste and stainless steel waste involves determining the presence, or absence, of magnetism. Voltage is applied for a fixed duration; once that has stopped, electrolytic reduction repeats the operative cycle of applying, then stopping voltage until the potential of the radioactive metal waste is retained in the active region. 1 fig. 2 tabs

  4. Elements of a radioactive waste management course

    International Nuclear Information System (INIS)

    Fentiman, A.W.

    1994-01-01

    The demand for scientists, engineers, and technicians with expertise in radioactive waste management is growing rapidly. Many universities, government agencies, and private contractors are developing courses in radioactive waste management. Two such courses have been developed at The Ohio State University. In support of that course development, two surveys were conducted. One survey went to all nuclear engineering programs in the US to determine what radioactive waste management courses are currently being taught. The other went to 600 waste management professionals, asking them to list the topics they think should be included in a radioactive waste management course. Four key elements of a course in radioactive waste management were identified. They are (a) technical information, (b) legal and regulatory framework, (c) communicating with the public, and (d) sources of information on waste management. Contents of each of the four elements are discussed, and results of the surveys are presented

  5. Radioactive waste management - the Indian scenario

    International Nuclear Information System (INIS)

    Raj, Kanwar

    2008-01-01

    In India, nuclear power generation programme and application of radioisotopes for health care and various other application is increasing steadily. With resultant increase in generation of radioactive waste, emphasis is on the minimization of generation of radioactive waste by deploying suitable processes and materials, segregation of waste streams at sources, recycle and re-use of useful components of waste and use of volume reduction techniques. The minimization of the radioactive waste is also essential to facilitate judicious use of the scarce land available for disposal, to reduce impact on the environment due to disposal and, finally to optimize the cost of radioactive waste management. This paper presents a bird's eye view of radioactive waste management programme in the country today

  6. Off-Gas Analysis During the Vitrification of Hanford Radioactive Waste Samples

    International Nuclear Information System (INIS)

    Ha, B.C.; Ferrara, D.M.; Crawford, C.L.; Choi, A.S.; Bibler, N.E.

    1998-01-01

    This paper describes the off-gas analysis of samples collected during the radioactive vitrification experiments. Production and characterization of the Hanford waste-containing LAW and HAW glasses are presented in related reports from this conference

  7. Radioactive gaseous waste processing device

    International Nuclear Information System (INIS)

    Kishi, Tadao.

    1990-01-01

    The present invention concerns a radioactive gaseous waste processing device used in BWR power plants. A heater is disposed to the lower portion of a dryer for dehydrating radioactive off gases. Further, a thermometer is disposed to a coolant return pipeway on the exit side of the cooling portion of the dryer and signals sent from the thermometer are inputted to an automatic temperature controller. If the load on the dryer is reduced, the value of the thermometer is lowered than a set value, then an output signal corresponding to the change is supplied from the automatic temperature controller to the heater to forcively apply loads to the dryer. Therefore, defrosting can be conducted completely without operating a refrigerator, and the refrigerator can be maintained under a constant load by applying a dummy load when the load in the dryer is reduced. (I.N.)

  8. Nuclear energy from radioactive waste

    International Nuclear Information System (INIS)

    Schwarzenberg, M.

    1998-01-01

    The global energy demand is increasing. Sound forecasts indicate that by the year 2020 almost eight thousand million people will be living on our planet, and generating their demand for energy will require conversion of about 20 thousand million tonnes of coal equivalents a year. Against this background scenario, a new concept for energy generation elaborated by nuclear scientists at CERN attracts particular interest. The concept describing a new nuclear energy source and technology intends to meet the following principal requirements: create a new energy source that can be exploited in compliance with extremely stringent safety requirements; reduce the amount of long-lived radioactive waste; substantially reduce the size of required radwaste repositories; use easily available natural fuels that will not need isotopic separation; prevent the risk of proliferation of radioactive materials; process and reduce unwanted actinides as are generated by the operation of current breeder reactors; achieve high efficiency both in terms of technology and economics. (orig./CB) [de

  9. [Microbiological Aspects of Radioactive Waste Storage].

    Science.gov (United States)

    Safonov, A V; Gorbunova, O A; German, K E; Zakharova, E V; Tregubova, V E; Ershov, B G; Nazina, T N

    2015-01-01

    The article gives information about the microorganisms inhabiting in surface storages of solid radioactive waste and deep disposal sites of liquid radioactive waste. It was shown that intensification of microbial processes can lead to significant changes in the chemical composition and physical state of the radioactive waste. It was concluded that the biogeochemical processes can have both a positive effect on the safety of radioactive waste storages (immobilization of RW macrocomponents, a decreased migration ability of radionuclides) and a negative one (biogenic gas production in subterranean formations and destruction of cement matrix).

  10. Shifting paradigms in managing radioactive waste

    International Nuclear Information System (INIS)

    Le Bars, Y.; Pescatore, C.

    2004-01-01

    The Stakeholder involvement in policy making of radioactive waste management, has received considerable attention within the OECD. The Nea forum on Stakeholder confidence (FSC) was set up in 2000. A Nea recent publication entitled ''Learning and adapting to societal requirements for radioactive waste management'' brings together the key FSC findings and experience covering four years of work. Six main areas are targeted in this publication and are briefly described in this document: favourable candidates for issuing radioactive waste management policy, the design of the decision-making process, the social and ethical dimension, trust in the actors, Stakeholder involvement and the local dimension of radioactive waste management. (A.L.B.)

  11. MANAGEMENT OF RADIOACTIVE WASTES IN CHINA

    Institute of Scientific and Technical Information of China (English)

    潘自强

    1994-01-01

    The policy and principles on management of radioactive wastes are stipulated.Cement solidification and bituminization unit has come into trial run.Solid radioactive waste is stored in tentative storage vault built in each of nuclear facilities.Seventeen storages associated with applications of nuclear technology and radioisotopes have been built for provinces.Disposal of low and intermediate level radioactive wastes pursues the policy of “regional disposal”.Four repositories have been planned to be built in northwest.southwest,south and east China respectively.A program for treatment and disposal of high level radioactive waste has been made.

  12. Management of radioactive wastes in China

    International Nuclear Information System (INIS)

    Pan Ziqiang

    1994-01-01

    The policy and principles on management of radioactive wastes are stipulated. Cement solidification and bituminization unit has come into trial run. Solid radioactive waste is stored in tentative storage vault built in each of nuclear facilities. Seventeen storages associated with applications of nuclear technology and radioisotopes have been built for provinces. Disposal of low and intermediate level radioactive wastes pursues the policy of 'regional disposal'. Four repositories have been planned to be built in northwest, southwest, south and east China respectively. A program for treatment and disposal of high level radioactive waste has been made

  13. Systems approach to nuclear waste glass development

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    1986-01-01

    Development of a host solid for the immobilization of nuclear waste has focused on various vitreous wasteforms. The systems approach requires that parameters affecting product performance and processing be considered simultaneously. Application of the systems approach indicates that borosilicate glasses are, overall, the most suitable glasses for the immobilization of nuclear waste. Phosphate glasses are highly durable; but the glass melts are highly corrosive and the glasses have poor thermal stability and low solubility for many waste components. High-silica glasses have good chemical durability, thermal stability, and mechanical stability, but the associated high melting temperatures increase volatilization of hazardous species in the waste. Borosilicate glasses are chemically durable and are stable both thermally and mechanically. The borosilicate melts are generally less corrosive than commercial glasses, and the melt temperature miimizes excessive volatility of hazardous species. Optimization of borosilicate waste glass formulations has led to their acceptance as the reference nuclear wasteform in the United States, United Kingdom, Belgium, Germany, France, Sweden, Switzerland, and Japan

  14. Management of radioactive wastes produced by users of radioactive materials

    International Nuclear Information System (INIS)

    1985-01-01

    This report is intended as a document to provide guidance for regulatory, administrative and technical authorities who are responsible for, or are involved in, planning, approving, executing and reviewing national waste management programmes related to the safe use of radioactive materials in hospitals, research laboratories, industrial and agricultural premises and the subsequent disposal of the radioactive wastes produced. It provides information and guidance for waste management including treatment techniques that may be available to establishments and individual users

  15. Corrosion of simulated nuclear waste glass

    International Nuclear Information System (INIS)

    Music, S.; Ristic, M.; Gotic, M.; Foric, J.

    1988-01-01

    In this study the preparation and characterization of borosilicate glasses of different chemical composition were investigated. Borosilicate glasses were doped with simulated nuclear waste oxides. The chemical corrosion in water of these glasses was followed by measuring the leach rates as a function of time. It was found that a simulated nuclear waste glass with the chemical composition (weight %), 15.61% Na 2 O, 10.39% B 2 O 3 , 45.31% SiO 2 , 13.42% ZnO, 6.61% TiO 2 and 8.66% waste oxides, is characterized by low melting temperature and with good corrosion resistance in water. Influence of passive layers on the leaching behaviour of nuclear waste glasses is discussed. (author) 20 refs.; 7 figs.; 4 tabs

  16. Electrical resistivities of glass melts containing simulated SRP waste sludges

    International Nuclear Information System (INIS)

    Wiley, J.R.

    1978-08-01

    One option for the long-term management of radioactive waste at the Savannah River Plant is to solidify the waste in borosilicate glass by using a continuous, joule-heated, ceramic melter. Electrical resistivities that are needed for melter design were measured for melts of two borosilicate, glass-forming mixtures, each of which was combined with various amounts of several simulated-waste sludges. The simulated sludge spanned the composition range of actual sludges sampled from SRP waste tanks. Resistivities ranged from 6 to 10 ohm-cm at 500 0 C. Melt composition and temperature were correlated with resistivity. Resistivity was not a simple function of viscosity. 15 figures, 4 tables

  17. Small-scale demonstration of high-level radioactive waste processing and solidification using actual SRP waste

    International Nuclear Information System (INIS)

    Okeson, J.K.; Galloway, R.M.; Wilhite, E.L.; Woolsey, G.B.; Ferguson, R.B.

    1980-01-01

    A small-scale demonstration of the high-level radioactive waste solidification process by vitrification in borosilicate glass is being conducted using 5-6 liter batches of actual waste. Equipment performance and processing characteristics of the various unit operations in the process are reported and, where appropriate, are compared to large-scale results obtained with synthetic waste

  18. Radioactive waste processing and disposal

    International Nuclear Information System (INIS)

    1975-07-01

    Reference to 2140 publications related to radioactive waste, announced in Nuclear Science Abstracts (NSA) Volumes 28 (July Dec. 1973), 29 (Jan.--June 1974), and 30 (July--Dec. 1974), are presented. The references are arranged by the original NSA abstract number, which approximately places them in chronological order. Sequence numbers appear beside each reference and the NSA volume and abstract numbers appear at the end of the citations. Three indexes are provided: Personal Author, Subject, and Report Number. This document supplements the preceding six in the TID3311 series. (U.S.)

  19. Investigation of full-scale high-level waste containment glass blocks. Task 3 characterization of radioactive waste forms a series of final reports (1985-89) - no 24

    International Nuclear Information System (INIS)

    Moncouyoux, J.; Aure, A.; Ladirat, C.

    1991-01-01

    A two-year study of the degree of fracturation in full-scale high-level waste glass blocks was undertaken under contract Fl1W-0182. The project included a theoretical investigation of thermal and mechanical stresses arising in the glass and determination of the fracture-inducing stress distribution in the block, as well as an experimental study based on tomographic examinations performed at the BAM in Berlin on full-scale canisters containing glass cast at Marcoule and on water leach tests at 100 0 C to evaluate the fractured leachable surface area. The Castem code system was used to determine the temperature profiles versus time for the glass package. The mechanical study revealed the impact of removing the package from the furnace on the final stress loading. Controlled cooling of glass blocks must be extremely slow (less than 5 0 C per hour) to have a significant effect on the stress loading. Three series of tomographic experiments were carried out: two on a canister as cast, and a third after relieving the canister stresses. Static and dynamic leach tests were conducted to determine the fracturation factor of the glass blocks. Only static leaching provides satisfactory results. Fracturation factors of 10 to 15 were measured on industrial glass blocks. 50 figs.; 20 tabs.; 3 refs

  20. Disposal of radioactive wastes from Czechoslovak nuclear power plants

    International Nuclear Information System (INIS)

    Neumann, L.

    In gaseous radioactive waste disposal, aerosol particles are filtered and gaseous wastes are discharged in the environment. The filters and filter materials used are stored on solid radioactive waste storage sites in the individual power plants. Liquid radioactive wastes are concentrated and the concentrates are stored. Distillates and low-level radioactive waste water are discharged into the hydrosphere. Solid radioactive wastes are stored without treatment in power plant bunkers. Bituminization and cementation of liquid radioactive wastes are discussed. (H.S.)