Geometrically induced metastability and holography
Energy Technology Data Exchange (ETDEWEB)
Aganagic, Mina; Aganagic, Mina; Beem, Christopher; Seo, Jihye; Vafa, Cumrun
2006-10-23
We construct metastable configurations of branes and anti-branes wrapping 2-spheres inside local Calabi-Yau manifolds and study their large N duals. These duals are Calabi-Yau manifolds in which the wrapped 2-spheres have been replaced by 3-spheres with flux through them, and supersymmetry is spontaneously broken. The geometry of the non-supersymmetric vacuum is exactly calculable to all orders of the't Hooft parameter, and to the leading order in 1/N. The computation utilizes the same matrix model techniques that were used in the supersymmetric context. This provides a novel mechanism for breaking supersymmetry in the context of flux compactifications.
Laser-induced metastable phases in liquids
Nath, Arpita; Sharma, Pooja; Khare, Alika
2018-02-01
Pulsed laser ablation at solid–liquid interfaces is gaining wide acceptance due to the production of functional nanomaterials having potential implications. The complex phenomena involved in the laser ablation process cause extreme pressure and temperature and a highly transient preferential growth of metastable phases is possible. Understanding of the nucleation phenomena of laser-produced nanoparticles in liquid is still limited and more orientated towards exploring the applicability of the nanoparticulates. The current work thus focuses on the nucleation dynamics of the high-pressure phase of TiO2 having an orthorhombic α-PbO2-like structure formed during pulsed laser ablation at the titanium–water interface. The nucleation time (10‑11 to 10‑8 s), growth velocity (maximum of ~100 nm ns‑1) and particle statistics are calculated and compared with experimentally derived particle statistics (3–180 nm). Pulsed laser ablation in liquid is also accompanied by mechanical phenomena known as cavitation bubbles. Insight into the possible role played by cavitation bubbles in the nucleation of nanoparticulates is outlined.
Geometric continuum mechanics and induced beam theories
R Eugster, Simon
2015-01-01
This research monograph discusses novel approaches to geometric continuum mechanics and introduces beams as constraint continuous bodies. In the coordinate free and metric independent geometric formulation of continuum mechanics as well as for beam theories, the principle of virtual work serves as the fundamental principle of mechanics. Based on the perception of analytical mechanics that forces of a mechanical system are defined as dual quantities to the kinematical description, the virtual work approach is a systematic way to treat arbitrary mechanical systems. Whereas this methodology is very convenient to formulate induced beam theories, it is essential in geometric continuum mechanics when the assumptions on the physical space are relaxed and the space is modeled as a smooth manifold. The book addresses researcher and graduate students in engineering and mathematics interested in recent developments of a geometric formulation of continuum mechanics and a hierarchical development of induced beam theories.
Radiation-induced metastable ordered phase in gallium nitride
International Nuclear Information System (INIS)
Ishimaru, Manabu
2010-01-01
Energetic particle irradiation is one of the useful ways for realizing metastable phases far from the equilibrium state. In the present study, we performed electron-beam-irradiation into gallium nitride (GaN) with a wurtzite structure and examined its structural changes using transmission electron microscopy. It was found that superlattice Bragg reflections appear in the electron diffraction patterns of the irradiated GaN. This suggests that the wurtzite GaN transforms to another crystalline structure with atomic ordering.
Field Induced Magnetic Moments in a Metastable Iron-Mercury Alloy
DEFF Research Database (Denmark)
Pedersen, M.S.; Mørup, Steen; Linderoth, Søren
1996-01-01
The magnetic properties of a metastable iron-mercury alloy have been investigated in the temperature range from 5 to 200 K by Mossbauer spectroscopy and magnetization measurements. At low temperature the magnetic moment per iron atom is larger than af alpha-Fe. The effective spontaneous magnetic ....... It was found that the field-induced increase of the magnetic moment in the metastable iron-mecury alloy was about 0.06 Bohr magnetons per iron atom in the temperature range from 5 to 200 K for a field change from 6 to 12 T....
International Nuclear Information System (INIS)
Hausild, P.; Davydov, V.; Drahokoupil, J.; Landa, M.; Pilvin, P.
2010-01-01
Kinetics of deformation-induced martensitic transformation in metastable austenitic steel AISI 301 was characterized by several techniques including classical light metallography, scanning electron microscopy, X-ray diffraction, neutron diffraction and electron back scattered diffraction. In situ monitoring of magnetic properties, acoustic emission and temperature increase during tensile tests at different strain rates was also performed. Results obtained by different methods are compared and discussed.
Ion and laser beam induced metastable alloy formation
International Nuclear Information System (INIS)
Westendorp, J.F.M.
1986-01-01
This thesis deals with ion and laser beam induced thin film mixing. It describes the development of an Ultra High Vacuum apparatus for deposition, ion irradiation and in situ analysis of thin film sandwiches. This chamber has been developed in close collaboration with High Voltage Engineering Europa. Thin films can be deposited by an e-gun evaporator. The atom flux is monitored by a quadrupole mass spectrometer. A comparison is made between ion beam and laser mixing of Cu with Au and Cu with W. The comparison provides a better understanding of the relative importance of purely collisional mixing, the role of thermodynamic effects and the contribution of diffusion due to defect generation and migration. (Auth.)
International Nuclear Information System (INIS)
Ahn, T.-H.; Oh, C.-S.; Kim, D.H.; Oh, K.H.; Bei, H.; George, E.P.; Han, H.N.
2010-01-01
Strain-induced martensitic transformation of metastable austenite was investigated by nanoindentation of individual austenite grains in multi-phase steel. A cross-section prepared through one of these indented regions using focused ion beam milling was examined by transmission electron microscopy. The presence of martensite underneath the indent indicates that the pop-ins observed on the load-displacement curve during nanoindentation correspond to the onset of strain-induced martensitic transformation. The pop-ins can be understood as resulting from the selection of a favorable martensite variant during nanoindentation.
Energy Technology Data Exchange (ETDEWEB)
Ahn, T.-H. [Seoul National University; Oh, C.-S. [Korean Institute of Materials Science; Kim, D. H. [Seoul National University; Oh, K. H. [Seoul National University; Bei, Hongbin [ORNL; George, Easo P [ORNL; Han, H. N. [Seoul National University
2010-01-01
Strain-induced martensitic transformation of metastable austenite was investigated by nanoindentation of individual austenite grains in multi-phase steel. A cross-section prepared through one of these indented regions using focused ion beam milling was examined by transmission electron microscopy. The presence of martensite underneath the indent indicates that the pop-ins observed on the load-displacement curve during nanoindentation correspond to the onset of strain-induced martensitic transformation. The pop-ins can be understood as resulting from the selection of a favorable martensite variant during nanoindentation.
DEFF Research Database (Denmark)
Macieszczak, Katarzyna; Zhou, Yanli; Hofferberth, Sebastian
2017-01-01
We investigate the dynamics of a generic interacting many-body system under conditions of electromagnetically induced transparency (EIT). This problem is of current relevance due to its connection to nonlinear optical media realized by Rydberg atoms. In an interacting system the structure...... of the dynamics and the approach to the stationary state becomes far more complex than in the case of conventional EIT. In particular, we discuss the emergence of a metastable decoherence-free subspace, whose dimension for a single Rydberg excitation grows linearly in the number of atoms. On approach...
DEFF Research Database (Denmark)
Carrotta, R.; Arleth, L.; Pedersen, J.S.
2003-01-01
Small-angle x-ray scattering was used for studying intermediate species, isolated after heat-induced aggregation of the A variant of bovine P-lactoglobulin. The intermediates were separated in two fractions, the heated metastable dimer and heated metastable oligomers larger than the dimer. The pa...
Hyperbolic periodic orbits in nongradient systems and small-noise-induced metastable transitions
Tao, Molei
2018-01-01
Small noise can induce rare transitions between metastable states, which can be characterized by Maximum Likelihood Paths (MLPs). Nongradient systems contrast gradient systems in that MLP does not have to cross the separatrix at a saddle point, but instead possibly at a point on a hyperbolic periodic orbit. A numerical approach for identifying such unstable periodic orbits is proposed based on String method. In a special class of nongradient systems ('orthogonal-type'), there are provably local MLPs that cross such saddle point or hyperbolic periodic orbit, and the separatrix crossing location determines the associated local maximum of transition rate. In general cases, however, the separatrix crossing may not determine a unique local maximum of the rate, as we numerically observed a counter-example in a sheared 2D-space Allen-Cahn SPDE. It is a reasonable conjecture that there are always local MLPs associated with each attractor on the separatrix, such as saddle point or hyperbolic periodic orbit; our numerical experiments did not disprove so.
Geometrically induced surface polaritons in planar nanostructured metallic cavities
Energy Technology Data Exchange (ETDEWEB)
Davids, P. S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Intravia, F [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dalvit, Diego A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
2014-01-14
We examine the modal structure and dispersion of periodically nanostructured planar metallic cavities within the scattering matrix formulation. By nanostructuring a metallic grating in a planar cavity, artificial surface excitations or spoof plasmon modes are induced with dispersion determined by the periodicity and geometric characteristics of the grating. These spoof surface plasmon modes are shown to give rise to new cavity polaritonic modes at short mirror separations that modify the density of modes in nanostructured cavities. The increased modal density of states form cavity polarirons have a large impact on the fluctuation induced electromagnetic forces and enhanced hear transfer at short separations.
International Nuclear Information System (INIS)
Ketzer, B.; Hartmann, F.J.; Egidy, T. von
1996-11-01
Laser resonance transitions between normally metastable states of antiprotonic helium atoms were observed making use of state dependent quenching effects caused by small admixtures of H 2 molecules. By selectively shortening the lifetimes of states with higher principal quantum number n as compared to those of lower n, this method for the first time provides access to all initially populated metastable states of p-bar He + atoms. This was demonstrated by observing the transitions (n,l) = (38,l) → (39,l+1), l 35, 36, 37 and (n,l) = (37,l) → (38,l+1), l = 34, 35, 36. (author)
Ketzer, B; Von Egidy, T; Maierl, C; Pohl, R; Eades, John; Widmann, E; Yamazaki, T; Kumakura, M; Morita, N; Hayano, R S; Hori, Masaki; Ishikawa, T; Torii, H A; Sugai, I; Horváth, D
1997-01-01
Laser resonance transitions between normally metastable states of antiprotonic helium atoms were observed making use of state dependent quenching effects caused by small admixtures of \\htwo\\ molecules. By selectively shortening the lifetimes of states with higher principal quantum number $n$ as compared to those of lower $n$, this method for the first time provides access to all initially populated metastable states of \\pbar\\hep\\ atoms. This was demonstrated by observing the transitions $(n,l)=(38,l)\\rightarrow (39,l+1),\\ l=35,36,37$ and $(n,l)=(37,l)\\rightarrow (38,l+1),\\ l=34,35,36$.
International Nuclear Information System (INIS)
Dose, V.
1982-01-01
This paper deals with the basic physical properties of the metastable 2 2 sub(1/2) state of atomic hydrogen. Applications relying on its special properties, including measurement of the Lamb shift, production of spin-polarized protons and the measurement of molecular electric moments, are discussed. (author)
Metastable primordial germ cell-like state induced from mouse embryonic stem cells by Akt activation
Energy Technology Data Exchange (ETDEWEB)
Yamano, Noriko [Graduate School of Frontier Biosciences, Osaka University, 2-2 Yamada-oka, Suita, Osaka 565-0871 (Japan); Kimura, Tohru, E-mail: tkimura@patho.med.osaka-u.ac.jp [Department of Pathology, Medical School, Osaka University, 2-2 Yamada-oka, Suita, Osaka 565-0871 (Japan); Watanabe-Kushima, Shoko [Graduate School of Frontier Biosciences, Osaka University, 2-2 Yamada-oka, Suita, Osaka 565-0871 (Japan); Shinohara, Takashi [Department of Molecular Genetics, Graduate School of Medicine, Kyoto University, Kyoto 606-8501 (Japan); Nakano, Toru, E-mail: tnakano@patho.med.osaka-u.ac.jp [Graduate School of Frontier Biosciences, Osaka University, 2-2 Yamada-oka, Suita, Osaka 565-0871 (Japan); Department of Pathology, Medical School, Osaka University, 2-2 Yamada-oka, Suita, Osaka 565-0871 (Japan)
2010-02-12
Specification to primordial germ cells (PGCs) is mediated by mesoderm-induction signals during gastrulation. We found that Akt activation during in vitro mesodermal differentiation of embryonic stem cells (ESCs) generated self-renewing spheres with differentiation states between those of ESCs and PGCs. Essential regulators for PGC specification and their downstream germ cell-specific genes were expressed in the spheres, indicating that the sphere cells had commenced differentiation to the germ lineage. However, the spheres did not proceed to spermatogenesis after transplantation into testes. Sphere cell transfer to the original feeder-free ESC cultures resulted in chaotic differentiation. In contrast, when the spheres were cultured on mouse embryonic fibroblasts or in the presence of ERK-cascade and GSK3 inhibitors, reversion to the ESC-like state was observed. These results indicate that Akt signaling promotes a novel metastable and pluripotent state that is intermediate to those of ESCs and PGCs.
Metastability of transient states
Rafailov, Michael K.
2017-05-01
High intensity ultrashort pulse causes dramatic perturbations in electronic structure of condensed matter. In the same time energy in high intensity single pulse may not be sufficient to disrupt sample thermal equilibrium. Interesting experimental results in ultrashort pulse photo-excited solids have been reported recently on transient athermal phenomena induced by ultrashort high intensity low energy pulse - phenomena related to both athermal phase transitions and athermal state changes. Athermal non-equilibrium of electronic system - and induced changes in magnetic and optical states, may exist only for a period of time comparable to excited carriers' relaxation time. That time is not sufficient for emerging application ranging from light induced superconductivity to infrared countermeasures. While single pulse interaction with condensed matter leading to transit state appearance is well observed, documented, and, to some extends, explained, one of the major problem is to maintain meta-stability of such transient states. Metastability of athermal non-equilibrium that could last well beyond electronic system relaxation time. The objective of this paper is to discuss some issues and approaches to meta-stability of transient states induced by ultrashort pulses in condensed matter.
Analyzing Geometric Characteristics of Rainfall-induced Landslides
Chiang, S. H.; Chen, C. F.
2015-12-01
Previous landslide prediction studies have focused on the assessment of location of landslides. Besides location, landslide geometric features (i.e., size and shape) are important factors that influence the distribution and dynamics of landslides. Statistical methods have been used to determine the frequency-size or frequency-volume relationships of landslides, through examining landslide inventories. However, the question of what sets their size and shape is unanswered. In this study, a landslide geometry generating algorithm (LsGA) is developed for quantifying landslide geometric features, including area, perimeter, upper length, lower length, average length and average width, with incorporating an existing landslide inventory and digital elevation model (DEM). The Kaoping watershed in Southern Taiwan is selected as the study area, and the landslide inventory prepared after Typhoon Morakot (August 2009) were applied for LsGA analysis. Landslide geometric features generated by LsGA were then used to correlate to geo-environmental factors, such as slope, contributing area and topographic index (TI), in a logistic regression model. Preliminary findings are: (1) smaller landslides are generally longer than larger landslides, (2) the upper length of small landslides is relatively wider than large landslides, (3) small landslides are more likely to be observed over gentle slopes (channels). Other results will be presented in the meeting.
International Nuclear Information System (INIS)
Perdahcıoğlu, E.S.; Geijselaers, H.J.M.
2012-01-01
Mechanically induced martensitic transformation and the associated transformation plasticity phenomena in austenitic stainless steels are studied. The mechanisms responsible for the transformation are investigated and put into perspective based on experimental evidence. The stress and strain partitioning into the austenite and martensite phases are formulated using a mean-field homogenization approach. At this intermediate length-scale the average stress in the austenite phase is computed and utilized to compute the mechanical driving force resolved in the material. The amount of transformation and the transformation plasticity is derived as a function of the driving force. The mechanical response of the material is obtained by combining the homogenization and the transformation models. The model is verified by mechanical tests under biaxial loading conditions during which different transformation rates are observed. As a final verification of the model, a bending test is used which manifests the stress-state dependency of the transformation.
Conformational changes and metastable states induced in proteins by green light
Comorosan, Sorin; Popescu, Irinel; Polosan, Silviu; Pirvu, Cristian; Ionescu, Elena; Paslaru, Liliana; Apostol, Marian
2015-01-01
In this paper we report conformational changes recorded on a protein molecule (α-amylase) under green light irradiation. In order to explain the experimental results we advanced the hypothesis that green light induces electric dipoles in the protein, which interact with each other, generating conformational modifications toward a more compact design, with different physical properties. The experiments were carried out with un-polarized light (λ = 520 nm) from a light-emitting-diode (1000 lm, 20 W, 105 mW on the target). In view of the character of our hypothesis, and corroborated with all our experimental results, we suggest that this phenomenon may be more extended and general, specific for a larger class of proteins, occurring on the protein macromolecules under the green light. The effects of α-amylase protein irradiation were revealed by circular dichroism, fluorescence, Raman and FTIR-spectroscopies, zeta potential, cyclic voltammetry, electric impedance spectroscopy and atomic force microscopy. Tentatively, we term the novel conformations as P∗ (polarized) proteins.
Kang, Sung; Shan, Sicong; Kosmrlj, Andrej; Noorduin, Wim; Shian, Samuel; Weaver, James; Clarke, David; Bertoldi, Katia
2014-03-01
Geometrical frustration arises when a local order cannot propagate throughout the space due to geometrical constraints. It plays a major role in many natural and synthetic systems including water ice, spin ice, and metallic glasses. All of these geometrically frustrated systems are degenerate and tend to form disordered ground-state configurations. Here, we report a theoretical and experimental study on the behavior of buckling-induced geometrically frustrated triangular cellular structures. To our surprise, we find that mechanical instabilities induce complex ordered patterns with tunability. For structures with low porosity, an ordered symmetric pattern emerges, which shows striking correlations with the ideal spin solid. In contrast, for high porosity systems, an ordered chiral pattern forms with a new spin configuration. Our analysis using a spin-like model reveals that the connected geometry of the cellular structure plays a crucial role in the formation of ordered states in this system. Since in our study geometrical frustration is induced by a mechanical instability that is scale-independent, our findings can be extended to different materials, stimuli, and length scales, providing a general strategy to study and visualize the physics of frustration.
The Molecular Geometric Phase and Light-Induced Conical Intersections
Zak, Emil J.
2017-06-01
Potential energy surfaces for electronic states of molecules in strong electromagnetic fields can be described in the dressed-state formalism, which introduces light-induced potentials. A light-induced conical intersection (LICI) [1] appears when two electronic states intersect due to the presence of an external electric field and when the dipole coupling between the field and the molecule vanishes. There are several aspects of quantum dynamics near LICIs, which still require a thorough investigation. How do non-adiabatic effects manifest themselves in polyatomic molecules in strong electromagnetic fields? Are the natural conical-intersections (NCI) and the light-induced conical intersections identical in nature? Do topological effects (Berry phase) [2] influence the nuclear dynamics around NCIs and LICIs? To answer these questions, a computer code for time-propagation of the ro-vibronic wavefunction on multiple coupled potential energy surfaces has been developed. The time-independent zero-order basis is taken from the DUO suite [3], which solves the full ro-vibronic Schrödinger equation for diatomic molecules. Non-adiabatic nuclear dynamics near LICIs will be presented on the examples of NaH and CaF molecules, with a perspective for extension to polyatomics. G. J. Halász, A Vibók, M. Sindelka, N. Moiseyev, L. S. Cederbaum, 2011 J. Phys. B: At. Mol. Opt. Phys. 44 175102 C. Wittig, Phys. Chem. Chem. Phys., 2012, 14, 6409-6432 S. N. Yurchenko, L. Lodi, J. Tennyson, A. V. Stolyarov, Comput. Phys. Commun., 202, 262, 2016
Hayano, R S; Tamura, H; Torii, H A; Hori, Masaki; Maas, F E; Morita, N; Kumakura, M; Sugai, I; Hartmann, F J; Daniel, H; Von Egidy, T; Ketzer, B; Pohl, R; Horváth, D; Eades, John; Widmann, E; Yamazaki, T
1997-01-01
A new laser-induced resonant transition in the $v=n-l-1=2$ metastable cascade of antiprotonic $^4$He atoms has been found by using a double resonance technique. This was done by setting the first laser to the already known 470.724 nm resonance ($(n,l)=(37,34)\\rightarrow (36,33)$), while the $(38,35)\\rightarrow (37,34)$ transition was searched for with the second laser. The resonant transition was found at wavelength of 529.622$\\pm$0.003 nm, showing excellent agreement with a recent prediction of Korobov.
Consitutive modeling of metastable austenitic stainless steel
Perdahcioglu, Emin Semih; Perdahcioglu, Emin Semih
2008-01-01
Metastable austenitic stainless steels combine high formability and high strength, which are generally opposing properties in materials. This property is a consequence of the martensitic phase transformation that takes place during deformation. This transformation is purely mechanically induced
International Nuclear Information System (INIS)
Batz, Marion
2011-01-01
Advances in metastability exchange optical pumping (MEOP) of 3 He at high laser powers, with its various applications, but also at high gas pressures p 3 and high magnetic field strengths B, have provided strong motivation for revisiting the understanding and for investigating the limitations of this powerful technique. For this purpose, we present systematic experimental and theoretical studies of efficiency and of relaxation mechanisms in B≤30 mT and p 3 =0.63-2.45 mbar. 3 He nuclear polarisation is measured by light absorption in longitudinal configuration where weak light beams at 1083 nm parallel to magnetic field and cell axis with opposite circular polarisations are used to probe the distribution of populations in the metastable state. This method is systematically tested to evaluate potential systematic biases and is shown to be reliable for the study of OP dynamics despite the redistribution of populations by OP light. Nuclear polarisation loss associated to the emission of polarised light by the plasma discharge used for MEOP is found to decrease above 10 mT, as expected, due to hyperfine decoupling in highly excited states. However, this does not lead to improved MEOP efficiency at high laser power. We find clear evidence of additional laser-induced relaxation instead. The strong OP-enhanced polarisation losses, currently limiting MEOP performances, are quantitatively investigated using an angular momentum budget approach and a recently developed comprehensive model that describes the combined effects of OP, ME and relaxation, validated by comparison to experimental results.
Metastability and Rydberg states of triatomic hydrogen
International Nuclear Information System (INIS)
Helm, H.
1991-01-01
The np,nd and nf Rydberg series of H 3 have been studied by one- or two-photon excitation from the lowest metastable state of H 3 :B2p 2 A 2 ''. The lifetime of the metastable state has been measured and the influence of an external electric field on the Rydberg states has been studied under both aspects of dynamics (field-ionization and field-induced predissociation) and structure (Strak effect)
Yang, Guang; Lin, Qingyu; Ding, Yu; Tian, Di; Duan, Yixiang
2015-01-01
A new laser induced breakdown spectroscopy (LIBS) based on single-beam-splitting (SBS) and proper optical geometric configuration has been initially explored in this work for effective signal enhancement. In order to improve the interaction efficiency of laser energy with the ablated material, a laser beam operated in pulse mode was divided into two streams to ablate/excite the target sample in different directions instead of the conventional one beam excitation in single pulse LIBS (SP-LIBS)...
Pasquali, L; Canepa, M; Staicu-Casagrande, E M; Esaulov, V A
2003-01-01
Surface-sensitive spectroscopic techniques, namely metastable deexcitation spectroscopy (MDS) and ultraviolet photoemission (UPS), have been applied to investigate the effects of chlorine chemisorption on the electronic properties (surface density of states and charge density) of Ag(100), Ag(110) and Ag(111) surfaces. Initial stages of chemisorption, up to the formation of a saturated Cl overlayer, have been examined. In particular, MDS permitted us to observe at low Cl gas exposure a progressive depletion of the Ag (5s) charge due to transfer and bonding with Cl atoms. From both MDS and UPS it was possible to observe the development of Cl (3p) bonding and anti-bonding states, the amount of their splitting increasing with coverage. Differences between chemisorption at the three surfaces have been noticed and they have been justified in terms of the different adatom packing and possible formation of small AgCl clusters (especially for the Ag(111) surface).
International Nuclear Information System (INIS)
Pasquali, L; Nannarone, S; Canepa, M; Staicu-Casagrande, E M; Esaulov, V A
2003-01-01
Surface-sensitive spectroscopic techniques, namely metastable deexcitation spectroscopy (MDS) and ultraviolet photoemission (UPS), have been applied to investigate the effects of chlorine chemisorption on the electronic properties (surface density of states and charge density) of Ag(100), Ag(110) and Ag(111) surfaces. Initial stages of chemisorption, up to the formation of a saturated Cl overlayer, have been examined. In particular, MDS permitted us to observe at low Cl gas exposure a progressive depletion of the Ag (5s) charge due to transfer and bonding with Cl atoms. From both MDS and UPS it was possible to observe the development of Cl (3p) bonding and anti-bonding states, the amount of their splitting increasing with coverage. Differences between chemisorption at the three surfaces have been noticed and they have been justified in terms of the different adatom packing and possible formation of small AgCl clusters (especially for the Ag(111) surface)
International Nuclear Information System (INIS)
Tie Zuo-Xiu; Qin Meng; Zou Da-Wei; Cao Yi; Wang Wei
2011-01-01
The diphenylalanine (FF) motif has been widely used in the design of peptides that are capable of forming various ordered structures, such as nanotubes, nanospheres and hydrogels. In these assemblies, FF based peptides adopt an antiparallel structure and are stabilized by π — π stacking among the phenyl groups. Here we show that assembly of FF-based peptides can be controlled by their geometric restrictions. Using tripeptide FFY (L-Phe-L-Phe-L-Tyr) as an example, we demonstrate that photo-crosslinking of C-terminal tyrosine can impose a geometric restriction to the formation of an antiparallel structure, leading to a structural change of the assemblies from nanosphere to amorphous. This finding is confirmed using far-UV circular dichroism, Fourier transform infrared spectroscopy and atomic force microscopy. Based on such a mechanism, we are able to control the gel-sol transition of Fmoc-FFY using the geometric restriction induced by photo-crosslinking of C-terminal tyrosine groups. We believe that geometric restriction should be considered as an important factor in the design of peptide-based materials. It can also be implemented as a useful strategy for the construction of environment-responsive 'smart' materials. (cross-disciplinary physics and related areas of science and technology)
International Nuclear Information System (INIS)
Tie Zuoxiu; Qin Meng; Zou Dawei; Cao Yi; Wang Wei
2011-01-01
The diphenylalanine (FF) motif has been widely used in the design of peptides that are capable of forming various ordered structures, such as nanotubes, nanospheres and hydrogels. In these assemblies, FF based peptides adopt an antiparallel structure and are stabilized by π-π stacking among the phenyl groups. Here we show that assembly of FF-based peptides can be controlled by their geometric restrictions. Using tripeptide FFY (L-Phe-L-Phe-L-Tyr) as an example, we demonstrate that photo-crosslinking of C-terminal tyrosine can impose a geometric restriction to the formation of an antiparallel structure, leading to a structural change of the assemblies from nanosphere to amorphous. This finding is confirmed using far-UV circular dichroism, Fourier transform infrared spectroscopy and atomic force microscopy. Based on such a mechanism, we are able to control the gel-sol transition of Fmoc-FFY using the geometric restriction induced by photo-crosslinking of C-terminal tyrosine groups. We believe that geometric restriction should be considered as an important factor in the design of peptide-based materials. It can also be implemented as a useful strategy for the construction of environment-responsive 'smart' materials. (authors)
DEFF Research Database (Denmark)
Coffey, Francis; Lee, Sang-Yun; Buus, Terkild B
2014-01-01
cells, suggesting this is a common occurrence during development. Moreover, CD73 induction appears to mark a metastable intermediate stage before acquisition of effector function, suggesting that γδ lineage and effector fate are specified sequentially. These findings have important implications......Numerous studies indicate that γδ T cell receptor (γδTCR) expression alone does not reliably mark commitment of early thymic progenitors to the γδ fate. This raises the possibility that the γδTCR is unable to intrinsically specify fate and instead requires additional environmental factors......, including TCR-ligand engagement. We use single cell progenitor assays to reveal that ligand acts instructionally to direct adoption of the γδ fate. Moreover, we identify CD73 as a TCR ligand-induced cell surface protein that distinguishes γδTCR-expressing CD4(-)CD8(-) progenitors that have committed...
Directory of Open Access Journals (Sweden)
Simon Sauvé
Full Text Available A peptide encompassing the conserved hydrophobic region and the first β-strand of the prion protein (PrP(110-136 shown to interact with the surface of dodecylphosphocholine micelles adopts an α-helical conformation that is localized below the head-group layer. This surface-bound peptide has a half-life of one day, and readily initiates the formation of amyloid fibrils. The presence of the latter was confirmed using birefringence microscopy upon Congo red binding and thioflavin T-binding induced fluorescence. The observation of this metastable α-helical conformer provides a unique snapshot of the early steps of the inter-conversion pathway. These findings together with the body of evidence from the prion literature allowed us to propose a mechanism for the conversion of PrPC to amyloid material.
Energy Technology Data Exchange (ETDEWEB)
Batz, Marion
2011-07-08
Advances in metastability exchange optical pumping (MEOP) of {sup 3}He at high laser powers, with its various applications, but also at high gas pressures p{sub 3} and high magnetic field strengths B, have provided strong motivation for revisiting the understanding and for investigating the limitations of this powerful technique. For this purpose, we present systematic experimental and theoretical studies of efficiency and of relaxation mechanisms in B{<=}30 mT and p{sub 3}=0.63-2.45 mbar. {sup 3}He nuclear polarisation is measured by light absorption in longitudinal configuration where weak light beams at 1083 nm parallel to magnetic field and cell axis with opposite circular polarisations are used to probe the distribution of populations in the metastable state. This method is systematically tested to evaluate potential systematic biases and is shown to be reliable for the study of OP dynamics despite the redistribution of populations by OP light. Nuclear polarisation loss associated to the emission of polarised light by the plasma discharge used for MEOP is found to decrease above 10 mT, as expected, due to hyperfine decoupling in highly excited states. However, this does not lead to improved MEOP efficiency at high laser power. We find clear evidence of additional laser-induced relaxation instead. The strong OP-enhanced polarisation losses, currently limiting MEOP performances, are quantitatively investigated using an angular momentum budget approach and a recently developed comprehensive model that describes the combined effects of OP, ME and relaxation, validated by comparison to experimental results.
Is Geometric Frustration-Induced Disorder a Recipe for High Ionic Conductivity?
Düvel, Andre; Heitjans, Paul; Fedorov, Pavel; Scholz, Gudrun; Cibin, Giannantonio; Chadwick, Alan V; Pickup, David M; Ramos, Silvia; Sayle, Lewis W L; Sayle, Emma K L; Sayle, Thi X T; Sayle, Dean C
2017-04-26
Ionic conductivity is ubiquitous to many industrially important applications such as fuel cells, batteries, sensors, and catalysis. Tunable conductivity in these systems is therefore key to their commercial viability. Here, we show that geometric frustration can be exploited as a vehicle for conductivity tuning. In particular, we imposed geometric frustration upon a prototypical system, CaF 2 , by ball milling it with BaF 2 , to create nanostructured Ba 1-x Ca x F 2 solid solutions and increased its ionic conductivity by over 5 orders of magnitude. By mirroring each experiment with MD simulation, including "simulating synthesis", we reveal that geometric frustration confers, on a system at ambient temperature, structural and dynamical attributes that are typically associated with heating a material above its superionic transition temperature. These include structural disorder, excess volume, pseudovacancy arrays, and collective transport mechanisms; we show that the excess volume correlates with ionic conductivity for the Ba 1-x Ca x F 2 system. We also present evidence that geometric frustration-induced conductivity is a general phenomenon, which may help explain the high ionic conductivity in doped fluorite-structured oxides such as ceria and zirconia, with application for solid oxide fuel cells. A review on geometric frustration [ Nature 2015 , 521 , 303 ] remarks that classical crystallography is inadequate to describe systems with correlated disorder, but that correlated disorder has clear crystallographic signatures. Here, we identify two possible crystallographic signatures of geometric frustration: excess volume and correlated "snake-like" ionic transport; the latter infers correlated disorder. In particular, as one ion in the chain moves, all the other (correlated) ions in the chain move simultaneously. Critically, our simulations reveal snake-like chains, over 40 Å in length, which indicates long-range correlation in our disordered systems. Similarly
Yang, Guang; Lin, Qingyu; Ding, Yu; Tian, Di; Duan, Yixiang
2015-01-05
A new laser induced breakdown spectroscopy (LIBS) based on single-beam-splitting (SBS) and proper optical geometric configuration has been initially explored in this work for effective signal enhancement. In order to improve the interaction efficiency of laser energy with the ablated material, a laser beam operated in pulse mode was divided into two streams to ablate/excite the target sample in different directions instead of the conventional one beam excitation in single pulse LIBS (SP-LIBS). In spatial configuration, the laser beam geometry plays an important role in the emission signal enhancement. Thus, an adjustable geometric configuration with variable incident angle between the two splitted laser beams was constructed for achieving maximum signal enhancement. With the optimized angles of 60° and 70° for Al and Cu atomic emission lines at 396.15 nm and 324.75 nm respectively, about 5.6- and 4.8-folds signal enhancements were achieved for aluminum alloy and copper alloy samples compared to SP-LIBS. Furthermore, the temporal analysis, in which the intensity of atomic lines in SP-LIBS decayed at least ten times faster than the SBS-LIBS, proved that the energy coupling efficiency of SBS-LIBS was significantly higher than that of SP-LIBS.
Yang, Guang; Lin, Qingyu; Ding, Yu; Tian, Di; Duan, Yixiang
2015-01-01
A new laser induced breakdown spectroscopy (LIBS) based on single-beam-splitting (SBS) and proper optical geometric configuration has been initially explored in this work for effective signal enhancement. In order to improve the interaction efficiency of laser energy with the ablated material, a laser beam operated in pulse mode was divided into two streams to ablate/excite the target sample in different directions instead of the conventional one beam excitation in single pulse LIBS (SP-LIBS). In spatial configuration, the laser beam geometry plays an important role in the emission signal enhancement. Thus, an adjustable geometric configuration with variable incident angle between the two splitted laser beams was constructed for achieving maximum signal enhancement. With the optimized angles of 60° and 70° for Al and Cu atomic emission lines at 396.15 nm and 324.75 nm respectively, about 5.6- and 4.8-folds signal enhancements were achieved for aluminum alloy and copper alloy samples compared to SP-LIBS. Furthermore, the temporal analysis, in which the intensity of atomic lines in SP-LIBS decayed at least ten times faster than the SBS-LIBS, proved that the energy coupling efficiency of SBS-LIBS was significantly higher than that of SP-LIBS. PMID:25557721
Chalcogenides Metastability and Phase Change Phenomena
Kolobov, Alexander V
2012-01-01
A state-of-the-art description of metastability observed in chalcogenide alloys is presented with the accent on the underlying physics. A comparison is made between sulphur(selenium)-based chalcogenide glasses, where numerous photo-induced phenomena take place entirely within the amorphous phase, and tellurides where a reversible crystal-to-amorphous phase-change transformation is a major effect. Applications of metastability in devices¿optical memories and nonvolatile electronic phase-change random-access memories among others are discussed, including the latest trends. Background material essential for understanding current research in the field is also provided.
Metastable and bistable defects in silicon
International Nuclear Information System (INIS)
Mukashev, Bulat N; Abdullin, Kh A; Gorelkinskii, Yurii V
2000-01-01
Existing data on the properties and structure of metastable and bistable defects in silicon are analyzed. Primary radiation-induced defects (vacancies, self-interstitial atoms, and Frenkel pairs), complexes of oxygen, carbon, hydrogen, and other impurity atoms and defects with negative correlation energy are considered. (reviews of topical problems)
Phase Transformation of Metastable Austenite in Steel during Nano indentation
International Nuclear Information System (INIS)
Ahn, Taehong; Lee, Sung Bo; Han, Heung Nam; Park, Kyungtae
2013-01-01
These can produce geometrical softening accompanied by a sudden displacement excursion during load-controlled nanoindentation, which referred to in the literature as a pop-in. In this study, phase transformation of metastable austenite to stress-induced ε martensite which causes pop-ins during nanoindentation of steel will be reported and discussed. This study investigated the relationship between pop-in behavior of austenite in the early stage of nanoindentation and formation of ε martensite based on microstructural analyses. The load-displacement curve obtained from nanoindentation revealed stepwise pop-ins in the early stage of plastic deformation. From analyses of high resolution TEM images, a cluster of banded structure under the indent turned out a juxtaposition of (111) planes of γ austenite and (0001) planes of ε martensite. The calculation of displacement along indentation axis for (111) slip system by formation of ε martensite showed that geometrical softening can also occur by ε martensite formation when considering that the stress-induced ε martensite transformation is the predominant deformation mode in the early stage of plastic deformation and its monopartial nature as well. These microstructural investigations strongly suggest that the pop-in behavior in the early stage of plastic deformation of austenite is closely related to the formation of ε martensite
Phase Transformation of Metastable Austenite in Steel during Nano indentation
Energy Technology Data Exchange (ETDEWEB)
Ahn, Taehong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Lee, Sung Bo; Han, Heung Nam [Seoul National Univ., Seoul (Korea, Republic of); Park, Kyungtae [Hanbat National Univ., Daejeon (Korea, Republic of)
2013-05-15
These can produce geometrical softening accompanied by a sudden displacement excursion during load-controlled nanoindentation, which referred to in the literature as a pop-in. In this study, phase transformation of metastable austenite to stress-induced ε martensite which causes pop-ins during nanoindentation of steel will be reported and discussed. This study investigated the relationship between pop-in behavior of austenite in the early stage of nanoindentation and formation of ε martensite based on microstructural analyses. The load-displacement curve obtained from nanoindentation revealed stepwise pop-ins in the early stage of plastic deformation. From analyses of high resolution TEM images, a cluster of banded structure under the indent turned out a juxtaposition of (111) planes of γ austenite and (0001) planes of ε martensite. The calculation of displacement along indentation axis for (111) slip system by formation of ε martensite showed that geometrical softening can also occur by ε martensite formation when considering that the stress-induced ε martensite transformation is the predominant deformation mode in the early stage of plastic deformation and its monopartial nature as well. These microstructural investigations strongly suggest that the pop-in behavior in the early stage of plastic deformation of austenite is closely related to the formation of ε martensite.
Czech Academy of Sciences Publication Activity Database
Schaniel, D.; Woike, T.; Schefer, J.; Petříček, Václav
2005-01-01
Roč. 71, č. 17 (2005), 174112/1-174112/7 ISSN 1098-0121 R&D Projects: GA ČR(CZ) GA202/03/0430 Grant - others:DFG(DE) Wo618/5-1 Institutional research plan: CEZ:AV0Z10100521 Keywords : neutron structure analysis * light-induced metastable state Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.185, year: 2005
Measuring the arterial-induced skin vibration by geometrical moiré fringe
Chiu, Shih-Yung; Wang, Chun-Hsiung; Lee, Shu-Sheng; Wu, Wen-Jong; Hsu, Yu-Hsiang; Lee, Chih-Kung
2018-02-01
The demand for self-measured blood pressure self-monitoring device has much increased due to cardiovascular diseases have become leading causes of death for aging population. Currently, the primary non-invasive blood pressure monitoring method is cuff-based. It is well developed and accurate. However, the measuring process is not comfortable, and it cannot provide a continuous measurement. To overcome this problem, methods such as tonometry, volume clamp method, photoplethysmography, pulse wave velocity, and pulse transit time are reported. However, the limited accuracy hindered its application for diagnostics. To perform sequential blood pressure measurement with a high accuracy and long-term examination, we apply moiré interferometry to measure wrist skin vibration induced by radial artery. To achieve this goal, we developed a miniaturized device that can perform moiré interferometry around the wrist region. The 0.4-mm-pitched binary grating and tattoo sticker with 0.46 mm-pitched stripe pattern are used to perform geometric moiré. We demonstrated that the sensitivity and accuracy of this integrated system were sufficient to monitor arterialinduced skin vibration non-invasively. Our developed system was validated with ECG signals collected by a commercial system. According to our studies from measurement, the repeatability of wrist pulsation measurement was achieved with an accuracy of 99.1% in heart rate. A good repeatability of wrist pulse measurement was achieved. Simulations and experiments are both conducted in this paper and prove of geometrical moiré method a suitable technique for arterial-induced skin vibration monitoring.
DEFF Research Database (Denmark)
Bisdom, Kevin; Bertotti, Giovanni; Nick, Hamid
2016-01-01
a geometrically based method for calculating the shear-induced hydraulic aperture, that is, an aperture of up to 0.5 mm (0.02 in.) that can result from shear displacement along irregular fracture walls. The geometrically based method does not require numerical simulations, but it can instead be directly applied...... to DFNs using the fracture orientation and spacing distributions in combination with an estimate of the regional stress tensor and orientation. The frequency distribution of hydraulic aperture from the geometrically based method is compared with finite-element models constructed from five real fracture...... networks, digitized from outcropping pavements. These networks cover a wide range of possible geometries and spatial distributions. The geometrically based method predicts the average hydraulic aperture and equivalent permeability of fractured porous media with error margins of less than 5%....
Metastable superconducting alloys
International Nuclear Information System (INIS)
Johnson, W.L.
1978-07-01
The study of metastable metals and alloys has become one of the principal activities of specialists working in the field of superconducting materials. Metastable crystalline superconductors such as the A15-type materials have been given much attention. Non-crystalline superconductors were first studied over twenty years ago by Buckel and Hilsch using the technique of thin film evaporation on a cryogenic substrate. More recently, melt-quenching, sputtering, and ion implantation techniques have been employed to produce a variety of amorphous superconductors. The present article presents a brief review of experimental results and a survey of current work on these materials. The systematics of superconductivity in non-crystalline metals and alloys are described along with an analysis of the microscopic parameters which underlie the observed trends. The unique properties of these superconductors which arise from the high degree of structural disorder in the amorphous state are emphasized
International Nuclear Information System (INIS)
Valance, Antoine.
1974-01-01
The production, detection and destruction of the 2S1/2 metastable state of the hydrogen atom were studied. The quasi-resonant charge exchange processes between fast protons and cesium target, in the total cross sections for production of metastable H(2s) atoms and radiative H(2p) atoms showed structures hitherto unobserved. The theoretical study is based on calculation of the adiabatic molecular potential terms of the ionic quasi-molecule (CsH) + , taking a Helmann type pseudopotential to describe the electron with respect to the core of the cesium ion. The probabilities of transition towards the output channels are calculated using a stationary state perturbation method. From the data obtained the interferece phenomena of excited quasi-molecular states can be interpreted coherently in slow collision. The probability of transition along the inelastic output channels displays characteristics of a harmonic oscillatory function inversely proportional to the speed of approach of the particles. The frequency of these oscillations depends very slightly on the impact parameter. The theory proposed involves three Σ states. During detection of the metastable ions the Lyman-α radiation induced in the de-excitation electric field by Stark effect present anisotropic features. The degree of polarization measured as a function of the field strength oscillates around a slow decay toward a limit-1 at strong electric field. A theory not accounting for the hyperfine structure of states mixed by Stark effect showed a double oscillatory structure containing the two frequencies correlated to the 2P1/2 and 2P3/2 states from the 2S1/2 state. Finally the results on the electron detachment reaction between fast metastable atoms and hydroiodic acid target have contributed towards research on polarized proton sources [fr
Topodynamics of metastable brains
Tozzi, Arturo; Peters, James F.; Fingelkurts, Andrew A.; Fingelkurts, Alexander A.; Marijuán, Pedro C.
2017-07-01
The brain displays both the anatomical features of a vast amount of interconnected topological mappings as well as the functional features of a nonlinear, metastable system at the edge of chaos, equipped with a phase space where mental random walks tend towards lower energetic basins. Nevertheless, with the exception of some advanced neuro-anatomic descriptions and present-day connectomic research, very few studies have been addressing the topological path of a brain embedded or embodied in its external and internal environment. Herein, by using new formal tools derived from algebraic topology, we provide an account of the metastable brain, based on the neuro-scientific model of Operational Architectonics of brain-mind functioning. We introduce a ;topodynamic; description that shows how the relationships among the countless intertwined spatio-temporal levels of brain functioning can be assessed in terms of projections and mappings that take place on abstract structures, equipped with different dimensions, curvatures and energetic constraints. Such a topodynamical approach, apart from providing a biologically plausible model of brain function that can be operationalized, is also able to tackle the issue of a long-standing dichotomy: it throws indeed a bridge between the subjective, immediate datum of the naïve complex of sensations and mentations and the objective, quantitative, data extracted from experimental neuro-scientific procedures. Importantly, it opens the door to a series of new predictions and future directions of advancement for neuroscientific research.
Digital Synchronizer without Metastability
Simle, Robert M.; Cavazos, Jose A.
2009-01-01
A proposed design for a digital synchronizing circuit would eliminate metastability that plagues flip-flop circuits in digital input/output interfaces. This metastability is associated with sampling, by use of flip-flops, of an external signal that is asynchronous with a clock signal that drives the flip-flops: it is a temporary flip-flop failure that can occur when a rising or falling edge of an asynchronous signal occurs during the setup and/or hold time of a flip-flop. The proposed design calls for (1) use of a clock frequency greater than the frequency of the asynchronous signal, (2) use of flip-flop asynchronous preset or clear signals for the asynchronous input, (3) use of a clock asynchronous recovery delay with pulse width discriminator, and (4) tying the data inputs to constant logic levels to obtain (5) two half-rate synchronous partial signals - one for the falling and one for the rising edge. Inasmuch as the flip-flop data inputs would be permanently tied to constant logic levels, setup and hold times would not be violated. The half-rate partial signals would be recombined to construct a signal that would replicate the original asynchronous signal at its original rate but would be synchronous with the clock signal.
Yamashita, Tadahiro; Kollmannsberger, Philip; Mawatari, Kazuma; Kitamori, Takehiko; Vogel, Viola
2016-11-01
Despite of the progress made to engineer structured microtissues such as BioMEMS and 3D bioprinting, little control exists how microtissues transform as they mature, as the misbalance between cell-generated forces and the strength of cell-cell and cell-substrate contacts can result in unintended tissue deformations and ruptures. To develop a quantitative perspective on how cellular contractility, scaffold curvature and cell-substrate adhesion control such rupture processes, human aortic smooth muscle cells were grown on glass substrates with submillimeter semichannels. We quantified cell sheet detachment from 3D confocal image stacks as a function of channel curvature and cell sheet tension by adding different amounts of Blebbistatin and TGF-β to inhibit or enhance cell contractility, respectively. We found that both higher curvature and higher contractility increased the detachment probability. Variations of the adhesive strength of the protein coating on the substrate revealed that the rupture plane was localized along the substrate-extracellular matrix interface for non-covalently adsorbed adhesion proteins, while the collagen-integrin interface ruptured when collagen I was covalently crosslinked to the substrate. Finally, a simple mechanical model is introduced that quantitatively explains how the tuning of substrate curvature, cell sheet contractility and adhesive strength can be used as tunable parameters as summarized in a first semi-quantitative phase diagram. These parameters can thus be exploited to either inhibit or purposefully induce a collective detachment of sheet-like microtissues for the use in tissue engineering and regenerative therapies. Despite of the significant progress in 3D tissue fabrication technologies at the microscale, there is still no quantitative model that can predict if cells seeded on a 3D structure maintain the imposed geometry while they form a continuous microtissue. Especially, detachment or loss of shape control of growing
Studying Thermodynamics of Metastable States
Kornyushin, Yuri
2007-01-01
Simple classical thermodynamic approach to the general description of metastable states is presented. It makes it possible to calculate the explicit dependence of the Gibbs free energy on temperature, to calculate the heat capacity, the thermodynamic barrier, dividing metastable and more stable states, and the thermal expansion coefficient. Thermodynamic stability under mechanical loading is considered. The influence of the heating (cooling) rate on the measured dynamic heat capacity is inves...
Srivastava, Vandana; Jarzembski, Maurice A.
1991-01-01
This paper uses Mie theory to treat electromagnetic scattering and to evaluate field enhancement in the forward direction of a small droplet irradiated by a high-energy beam and compares the results of calculations with the field-enhancement evaluation obtained via geometrical optics treatment. Results of this comparison suggest that the field enhancement located at the critical ring region encircling the axis in the forward direction of the droplet can support laser-induced Raman scattering. The results are supported by experimental observations of the interaction of a 120-micron-diam water droplet with a high-energy Nd:YAG laser beam.
Kravets, Nina; Brasselet, Etienne
2018-01-01
We propose to couple the optical orientational nonlinearities of liquid crystals with their ability to self-organize to tailor them to control space-variant-polarized optical fields in a nonlinear manner. Experimental demonstration is made using a liquid crystal light valve that behaves like a light-driven geometric phase optical element. We also unveil two original nonlinear optical processes, namely self-induced separability and nonseparability. These results contribute to the advancement of nonlinear singular optics that is still in its infancy despite 25 years of effort, which may foster the development of nonlinear protocols to manipulate high-dimensional optical information both in the classical and quantum regimes.
Errandonea, Daniel; Achary, S Nagabhusan; Pellicer-Porres, Julio; Tyagi, Avesh K
2013-05-06
Zircon-type PrVO4 and SmVO4 have been studied by high-pressure Raman spectroscopy up to 17 GPa. The occurrence of phase transitions has been detected when compression exceeds 6 GPa. The transformations are not reversible. Raman spectra of the high-pressure phases show similarities with those expected for a monazite-type phase in PrVO4 and a scheelite-type phase in SmVO4.The high-pressure phases have been also synthesized using a large-volume press and recovered at ambient conditions. X-ray diffraction measurements of the metastable products recovered after decompression confirms the monazite (PrVO4) and scheelite (SmVO4) structures of the high-pressure phases. Based upon optical properties of the reported new polymorphs, novel applications for rare-earth vanadates are proposed, including photocatalytic hydrogen production.
A metastable liquid melted from a crystalline solid under decompression
Lin, Chuanlong; Smith, Jesse S.; Sinogeikin, Stanislav V.; Kono, Yoshio; Park, Changyong; Kenney-Benson, Curtis; Shen, Guoyin
2017-01-01
A metastable liquid may exist under supercooling, sustaining the liquid below the melting point such as supercooled water and silicon. It may also exist as a transient state in solid-solid transitions, as demonstrated in recent studies of colloidal particles and glass-forming metallic systems. One important question is whether a crystalline solid may directly melt into a sustainable metastable liquid. By thermal heating, a crystalline solid will always melt into a liquid above the melting point. Here we report that a high-pressure crystalline phase of bismuth can melt into a metastable liquid below the melting line through a decompression process. The decompression-induced metastable liquid can be maintained for hours in static conditions, and transform to crystalline phases when external perturbations, such as heating and cooling, are applied. It occurs in the pressure-temperature region similar to where the supercooled liquid Bi is observed. Akin to supercooled liquid, the pressure-induced metastable liquid may be more ubiquitous than we thought.
Metastable supersymmetry breaking without scales
Energy Technology Data Exchange (ETDEWEB)
Bruemmer, Felix
2010-11-15
We construct new examples of models of metastable D=4 N=1 supersymmetry breaking in which all scales are generated dynamically. Our models rely on Seiberg duality and on the ISS mechanism of supersymmetry breaking in massive SQCD. Some of the electric quark superfields arise as composites of a strongly coupled gauge sector. This allows us to start with a simple cubic superpotential and an asymptotically free gauge group in the ultraviolet, and end up with an infrared effective theory which breaks supersymmetry dynamically in a metastable state. (orig.)
A model for the origin and properties of flicker-induced geometric phosphenes.
Directory of Open Access Journals (Sweden)
Michael Rule
2011-09-01
Full Text Available We present a model for flicker phosphenes, the spontaneous appearance of geometric patterns in the visual field when a subject is exposed to diffuse flickering light. We suggest that the phenomenon results from interaction of cortical lateral inhibition with resonant periodic stimuli. We find that the best temporal frequency for eliciting phosphenes is a multiple of intrinsic (damped oscillatory rhythms in the cortex. We show how both the quantitative and qualitative aspects of the patterns change with frequency of stimulation and provide an explanation for these differences. We use Floquet theory combined with the theory of pattern formation to derive the parameter regimes where the phosphenes occur. We use symmetric bifurcation theory to show why low frequency flicker should produce hexagonal patterns while high frequency produces pinwheels, targets, and spirals.
Tkach, P. Y.
2017-08-01
The article represents the research results of a centrifugal inducer stage with inducer bush. We determined the optimal inducer bush design that would improve the cavitation erosion characteristics without deteriorating the energy levels and preserving overall dimensions of the centrifugal inducer stage at the same time.
Collisional interaction between metastable neon atoms
Energy Technology Data Exchange (ETDEWEB)
Drunen, Wouter Johannes van
2008-07-07
In this thesis, the study of cold gases of neon atoms in different metastable states is described. It contains measurements of the collisional parameters for both the 3s[3/2]{sub 2} and the 3s'[1/2]{sub 0} metastable state and the dependence of the inelastic loss on external fields. Furthermore, the investigation of frequency dependent laser-induced collisions, and the possibility to excite photoassociation resonances is presented. For the measurements described here, neon atoms have been confined in a magnetooptical trap, in a magnetostatic trap, or in an optical dipole trap, respectively. By laser cooling inside the magnetic trap, atomic samples with more than 95 percent occupation of the magnetic substate m{sub J} = +2 could be prepared. They have a typical temperature of 0.5 mK, central densities up to 10{sup 11} cm{sup -3}, and a central phase-space density of up to 2.2.10{sup -7}. After loading the optical dipole trap from the magnetic trap, 2.5.10{sup 6} atoms with typical temperatures of 0.1 mK, and central densities up to 5.10{sup 10} cm{sup -3} were trapped. By evaporative cooling of the atoms in the magnetic trap we could increase the phase-space density by a factor of 200 to 5.10{sup -5}. Investigating the frequency dependence of laser-induced collisions did not reveal an experimental signature for the excitation of photoassociation resonances. For the {sup 3}D{sub 3} line a frequency dependence of laser enhanced Penning ionization was observed. Measurement of the two-body loss coefficient as function of the magnetic field showed a field dependence of the inelastic loss. These losses increase towards both small and large offset fields. The implementation of an optical dipole trap allowed us to trap the {sup 3}P{sub 0} metastable state. From the trap loss measurements we determined the two-body loss coefficient of the {sup 3}P{sub 0} metastable state for both bosonic isotopes {sup 20}Ne and {sup 22}Ne. For {sup 20}Ne we obtained {beta}=6{sup +5}{sub
International Nuclear Information System (INIS)
Gardes, D.
A systematic study of quasi-elastic transfer reactions induced on bismuth target by heavy ions ( 12 C, 14 N, 16 O, 19 F, 20 Ne, 40 Ar, 40 Ca, 56 Fe, 63 Cu, 84 Kr) was performed. Recoil techniques were applied to the collection of heavy residues of the reaction. These products were identified by their radioactive decay. The experimental data (excitation functions, projected recoil ranges, angular distributions) could be interpreted by the drastic influence of energetical parameters such as optimum Q values, and geometrical factors (minimum distances of approach). Odd-even effects of the atomic number of the projectile on the 2 proton-transfer probability was observed for light projectiles. A theoretical calculation of transfer probability has been developed and the results compared to our experimental data. General shape of excitation functions and angular distributions in the sub-Coulomb energies region have been successfully reproduced [fr
Metastable Phases in Ice Clouds
Weiss, Fabian; Baloh, Philipp; Kubel, Frank; Hoelzel, Markus; Parker, Stewart; Grothe, Hinrich
2014-05-01
Polar Stratospheric Clouds and Cirrus Clouds contain both, pure water ice and phases of nitric acid hydrates. Preferentially for the latter, the thermodynamically stable phases have intensively been investigated in the past (e.g. nitric acid trihydrate, beta-NAT). As shown by Peter et al. [1] the water activity inside clouds is higher than expected, which might be explained by the presence of metastable stable phases (e.g. cubic ice). However, also metastable nitric acid hydrates might be important due to the inherent non-equilibrium freezing conditions in the upper atmosphere. The delta ice theory of Gao et al. [2] presents a model approach to solve this problem by involving both metastable ice and NAT as well. So it is of high interest to investigate the metastable phase of NAT (i.e. alpha-NAT), the structure of which was unknown up to the presence. In our laboratory a production procedure for metastable alpha-NAT has been developed, which gives access to neutron diffraction and X-ray diffraction measurements, where sample quantities of several Gramm are required. The diffraction techniques were used to solve the unknown crystalline structure of metastable alpha-NAT, which in turn allows the calculation of the vibrational spectra, which have also been recorded by us in the past. Rerefences [1] Peter, T., C. Marcolli, P. Spichtinger, T. Corti, M. B. Baker, and T. Koop. When dry air is too humid. Science, 314:1399-1402, 2006. [2] Gao, R., P. Popp, D. Fahey, T. Marcy, R. L. Herman, E. Weinstock, D. Baumgardener, T. Garrett, K. Rosenlof, T. Thompson, T. P. Bui, B. Ridley, S. C. Wofsy, O. B. Toon, M. Tolbert, B. Kärcher, Th. Peter, P. K. Hudson, A. Weinheimer, and A. Heymsfield. Evidence That Nitric Acid Increases Relative Humidity in Low-Temperature Cirrus Clouds, Science, 303:516-520, 2004. [3] Tizek, H., E. Knözinger, and H. Grothe. Formation and phase distribution of nitric acid hydrates in the mole fraction range xHNO3<0.25: A combined XRD and IR study, PCCP, 6
Sharma, Shivani; Shahee, Aga; Yadav, Poonam; da Silva, Ivan; Lalla, N. P.
2017-11-01
Low-temperature high-magnetic field (2 K, 8 T) (LTHM) powder X-ray diffraction (XRD) and time of flight powder neutron diffraction (NPD), low-temperature transmission electron microscopic (TEM), and resistivity and magnetization measurements have been carried out to investigate the re-entrant charge ordering (CO), field induced structural phase transitions, and metastability in phase-separated La0.175Pr0.45Ca0.375MnO3-δ (LPCMO). Low-temperature TEM and XRD studies reveal that on cooling under zero-field, paramagnetic Pnma phase transforms to P21/m CO antiferromagnetic (AFM) insulating phase below ˜233 K. Unlike reported literature, no structural signature of CO AFM P21/m to ferromagnetic (FM) Pnma phase-transition during cooling down to 2 K under zero-field was observed. However, the CO phase was found to undergo a re-entrant transition at ˜40 K. Neutron diffraction studies revealed a pseudo CE type spin arrangement of the observed CO phase. The low-temperature resistance, while cooled under zero-field, shows insulator to metal like transition below ˜105 K with minima at ˜25 K. On application of field, the CO P21/m phase was found to undergo field-induced transition to FM Pnma phase, which shows irreversibility on field removal below ˜40 K. Zero-field warming XRD and NPD studies reveal that field-induced FM Pnma phase is a metastable phase, which arise due to the arrest of kinetics of the first-order phase transition of FM Pnma to CO-AFM P21/m phase, below 40 K. Thus, a strong magneto-structural coupling is observed for this system. A field-temperature (H-T) phase-diagram has been constructed based on the LTHM-XRD, which matches very nicely with the reported H-T phase-diagram constructed based on magnetic measurements. Due to the occurrence of gradual growth of the re-entrant CO phase and the absence of a clear structural signature of phase-separation of CO-AFM P21/m and FM Pnma phases, the H-T minima in the phase-diagram of the present LPCMO sample has been
Electron collisions with metastable helium
International Nuclear Information System (INIS)
Jacka, M.; Kelly, J.; Lohmann, B.; Buckman, S.
1996-01-01
Measurements and theoretical studies of electron scattering from the metastable 2 1,3 S excited states of helium are briefly reviewed. A high resolution hemispherical electron spectrometer with a position sensitive detector, developed for the study of low energy differential scattering from metastable excited states is discussed in detail. This assisted in the measurement of excitation processes characterised by extremely low count rates. The first results of angular distributions for electrons superelastically scattered from the 2 1,3 S states at incident energies of 5, 10 and 30 eV are presented. They have been normalised in magnitude to the convergent close coupling calculation. Cross sections from a 29-state R-matrix calculation and the first order many body theory calculation are also included for comparison. These measurements are in excellent agreement with the convergent close coupling calculations of Bray et al. (1994). 28 refs., 4 figs
Instability of colliding metastable strings
Energy Technology Data Exchange (ETDEWEB)
Hiramatsu, Takashi [Kyoto Univ. (Japan). Yukawa Inst. for Theoretical Physics; Eto, Minoru [Yamagata Univ. (Japan). Dept. of Physics; Kamada, Kohei [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Kobayashi, Tatsuo [Kyoto Univ. (Japan). Dept. of Physics; Ookouchi, Yutaka [Kyoto Univ. (Japan). Dept. of Physics; Kyoto Univ. (Japan). The Hakubi Center for Advanced Research
2013-04-15
We investigate the collision dynamics of two metastable strings which can be viewed as tube-like domain walls with winding numbers interpolating a false vacuum and a true vacuum. We find that depending on the relative angle and speed of two strings, instability of strings increases and the false vacuum is filled out by rapid expansion of the strings or of a remnant of the collision.
Experimental determination of the constitutive behaviour of a metastable austenitic stainless steel
Post, J.; Nolles, H.; Datta, K.; Datta, K.; Geijselaers, Hubertus J.M.
2008-01-01
This article presents measurements to describe the constitutive behaviour of a semi-austenitic precipitation hardenable stainless steel called Sandvik Nanoflex™, during metal forming and hardening. The material is metastable, which causes strain-induced transformation during forming. Depending on
Bray, Hubert L; Mazzeo, Rafe; Sesum, Natasa
2015-01-01
This volume includes expanded versions of the lectures delivered in the Graduate Minicourse portion of the 2013 Park City Mathematics Institute session on Geometric Analysis. The papers give excellent high-level introductions, suitable for graduate students wishing to enter the field and experienced researchers alike, to a range of the most important areas of geometric analysis. These include: the general issue of geometric evolution, with more detailed lectures on Ricci flow and Kähler-Ricci flow, new progress on the analytic aspects of the Willmore equation as well as an introduction to the recent proof of the Willmore conjecture and new directions in min-max theory for geometric variational problems, the current state of the art regarding minimal surfaces in R^3, the role of critical metrics in Riemannian geometry, and the modern perspective on the study of eigenfunctions and eigenvalues for Laplace-Beltrami operators.
Geometrical and profile effects on toroidicity and ellipticity induced Alfven eigenmodes
International Nuclear Information System (INIS)
Villard, L.; Fu, G.Y.
1992-04-01
The wave structures, eigenfrequencies and damping rates of toroidicity and ellipticity induced Alfven eigenmodes (TAE, EAE) of low toroidal mode numbers (n) are calculated in various axisymmetric ideal MHD equilibria with the global wave finite element code LION. The importance of safety factor (q) and density (ρ) profiles on continuum damping rates is analysed. For realistic profiles several continuum gaps exist in the plasma discharge. Frequency misalignment of these gaps yields continuum damping rates γ/ω of the order of a few percent. Finite β pol lowers the TAE eigenfrequency. For β values below the Troyon limit the TAE enters the continuum and can thus be stabilized. Finite elongation allows the EAE to exist but triangularity can have a stabilizing effect through coupling to the continuum. The localization of TAE and EAE eigenfunctions is found to increase with the shear and with n. Therefore large shear, through enhanced Landau and collisional damping, is a stabilizing factor for TAE and EAE modes. (author) 16 figs., 28 refs
Shabanov, S. V.; Gornushkin, I. B.
2018-01-01
Data processing in the calibration-free laser-induced breakdown spectroscopy (LIBS) is usually based on the solution of the radiative transfer equation along a particular line of sight through a plasma plume. The LIBS data processing is generalized to the case when the spectral data are collected from large portions of the plume. It is shown that by adjusting the optical depth and width of the lines the spectra obtained by collecting light from an entire spherical homogeneous plasma plume can be least-square fitted to a spectrum obtained by collecting the radiation just along a plume diameter with a relative error of 10-11 or smaller (for the optical depth not exceeding 0.3) so that a mismatch of geometries of data processing and data collection cannot be detected by fitting. Despite the existence of such a perfect least-square fit, the errors in the line optical depth and width found by a data processing with an inappropriate geometry can be large. It is shown with analytic and numerical examples that the corresponding relative errors in the found elemental number densities and concentrations may be as high as 50% and 20%, respectively. Safe for a few found exceptions, these errors are impossible to eliminate from LIBS data processing unless a proper solution of the radiative transfer equation corresponding to the ray tracing in the spectral data collection is used.
Lee, Woo-Jung; Yu, Hye-Jung; Wi, Jae-Hyung; Cho, Dae-Hyung; Han, Won Seok; Yoo, Jisu; Yi, Yeonjin; Song, Jung-Hoon; Chung, Yong-Duck
2016-08-31
We fabricated Cu(In,Ga)Se2 (CIGS) solar cells with a chemical bath deposition (CBD)-ZnS buffer layer grown with varying ammonia concentrations in aqueous solution. The solar cell performance was degraded with increasing ammonia concentration, due to actively dissolved Zn atoms during CBD-ZnS precipitation. These formed interfacial defect states, such as hydroxide species in the CBD-ZnS film, and interstitial and antisite Zn defects at the p-n heterojunction. After light/UV soaking, the CIGS solar cell performance drastically improved, with a rise in fill factor. With the Zn-based buffer layer, the light soaking treatment containing blue photons induced a metastable state and enhanced the CIGS solar cell performance. To interpret this effect, we suggest a band structure model of the p-n heterojunction to explain the flow of photocarriers under white light at the initial state, and then after light/UV soaking. The determining factor is a p+ defect layer, containing an amount of deep acceptor traps, located near the CIGS surface. The p+ defect layer easily captures photoexcited electrons, and then when it becomes quasi-neutral, attracts photoexcited holes. This alters the barrier height and controls the photocurrent at the p-n junction, and fill factor values, determining the solar cell performance.
Metastable states in magnetic nanorings
DEFF Research Database (Denmark)
Castaño, F. J.; Ross, C. A.; Frandsen, Cathrine
2003-01-01
Magnetization states and hysteresis behavior of small ferromagnetic rings, of diameters 180-520 nm, have been investigated using magnetic force microscopy. In addition to the expected bi-domain ("onion") and flux-closed ("vortex") magnetization states, a metastable state has been found....... This "twisted" state contains a 360degrees domain wall which can exist over a wide range of applied fields. Four possible configurations of the twisted state are possible. Micromagnetic modeling shows that the twisted state is stabilised in small diameter, narrow rings. Additionally, more complex configurations...... such as double twisted states with two 360degrees walls have been observed....
Vacuum metastability with black holes
International Nuclear Information System (INIS)
Burda, Philipp; Gregory, Ruth; Moss, Ian G. annd
2015-01-01
We consider the possibility that small black holes can act as nucleation seeds for the decay of a metastable vacuum, focussing particularly on the Higgs potential. Using a thin-wall bubble approximation for the nucleation process, which is possible when generic quantum gravity corrections are added to the Higgs potential, we show that primordial black holes can stimulate vacuum decay. We demonstrate that for suitable parameter ranges, the vacuum decay process dominates over the Hawking evaporation process. Finally, we comment on the application of these results to vacuum decay seeded by black holes produced in particle collisions.
Muniz Oliva, Waldyr
2002-01-01
Geometric Mechanics here means mechanics on a pseudo-riemannian manifold and the main goal is the study of some mechanical models and concepts, with emphasis on the intrinsic and geometric aspects arising in classical problems. The first seven chapters are written in the spirit of Newtonian Mechanics while the last two ones as well as two of the four appendices describe the foundations and some aspects of Special and General Relativity. All the material has a coordinate free presentation but, for the sake of motivation, many examples and exercises are included in order to exhibit the desirable flavor of physical applications.
International Nuclear Information System (INIS)
Widmann, E.; Eades, J.; Yamazaki, T.
1996-11-01
A precise scan of the previously discovered laser-induced transition (n,l) = (37,35) → (38,34) in p-barHe + revealed a doublet structure with a separation of Δν HF = 1.70 ± 0.05 GHz. This new type of 'hyperfine' splitting is ascribed to the interaction of the antiproton orbital angular momentum and the electron spin. (author)
Cold and trapped metastable noble gases
Vassen, W.; Cohen-Tannoudji, C.; Leduc, M.; Boiron, D.; Westbrook, C.I.; Truscott, A.; Baldwin, K.; Birkl, G.; Cancio, P.; Trippenbach, M.
2012-01-01
Experimental work on cold, trapped metastable noble gases is reviewed. The aspects which distinguish work with these atoms from the large body of work on cold, trapped atoms in general is emphasized. These aspects include detection techniques and collision processes unique to metastable atoms.
Metastable neural dynamics mediates expectation
Mazzucato, Luca; La Camera, Giancarlo; Fontanini, Alfredo
Sensory stimuli are processed faster when their presentation is expected compared to when they come as a surprise. We previously showed that, in multiple single-unit recordings from alert rat gustatory cortex, taste stimuli can be decoded faster from neural activity if preceded by a stimulus-predicting cue. However, the specific computational process mediating this anticipatory neural activity is unknown. Here, we propose a biologically plausible model based on a recurrent network of spiking neurons with clustered architecture. In the absence of stimulation, the model neural activity unfolds through sequences of metastable states, each state being a population vector of firing rates. We modeled taste stimuli and cue (the same for all stimuli) as two inputs targeting subsets of excitatory neurons. As observed in experiment, stimuli evoked specific state sequences, characterized in terms of `coding states', i.e., states occurring significantly more often for a particular stimulus. When stimulus presentation is preceded by a cue, coding states show a faster and more reliable onset, and expected stimuli can be decoded more quickly than unexpected ones. This anticipatory effect is unrelated to changes of firing rates in stimulus-selective neurons and is absent in homogeneous balanced networks, suggesting that a clustered organization is necessary to mediate the expectation of relevant events. Our results demonstrate a novel mechanism for speeding up sensory coding in cortical circuits. NIDCD K25-DC013557 (LM); NIDCD R01-DC010389 (AF); NSF IIS-1161852 (GL).
Modeling the metastable dynamics of correlated structures
Shakirov, Alexey M.; Tsibulsky, Sergey V.; Antipov, Andrey E.; Shchadilova, Yulia E.; Rubtsov, Alexey N.
2015-01-01
Metastable quantum dynamics of an asymmetric triangular cluster that is coupled to a reservoir is investigated. The dynamics is governed by bath-mediated transitions, which in part require a thermal activation process. The decay rate is controlled by tuning the excitation spectrum of the frustrated cluster. We use the master equation approach and construct transition operators in terms of many-body states. We analyze dynamics of observables and reveal metastability of an excited state and of a magnetically polarized ground state.
Metastable fragmentation of silver bromide clusters
International Nuclear Information System (INIS)
L'Hermite, J.M.; Rabilloud, F.; Marcou, L.; Labastie, P.
2001-01-01
The abundance spectra and the fragmentation channels of silver bromide clusters have been measured and analyzed. The most abundant species are Ag n Br n - 1 + and Ag n Br n + 1 - and Ag 14 Br 13 + is a magic number, revealing their ionic nature. However, some features depart from what is generally observed for alkali-halide ionic clusters. From a certain size, Ag n Br n - 1 + is no more the main series, and Ag n Br n - 2, 3 + series become almost as important. The fast fragmentation induced by a UV laser makes the cations lose more bromine than silver ions and lead to more silver-rich clusters. Negative ions mass spectra contain also species with more silver atoms than required by stoichiometry. We have investigated the metastable fragmentation of the cations using a new experimental method. The large majority of the cations release mainly a neutral Ag 3 Br 3 cluster. These decay channels are in full agreement with our recent ab initio DFT calculations, which show that Ag + -Ag + repulsion is reduced due to a globally attractive interaction of their d orbitals. This effect leads to a particularly stable trimer (AgBr) 3 and to quasi-planar cyclic structures of (AgBr) n clusters up to n = 6. We have shown that these two features may be extended to other silver halides, to silver hydroxides (AgOH) n , and to cuprous halide compounds. (orig.)
DEFF Research Database (Denmark)
Andersen, Jørgen Ellegaard; Borot, Gaëtan; Orantin, Nicolas
We propose a general theory whose main component are functorial assignments ∑→Ω∑ ∈ E (∑), for a large class of functors E from a certain category of bordered surfaces (∑'s) to a suitable a target category of topological vector spaces. The construction is done by summing appropriate compositions...... of the initial data over all homotopy classes of successive excisions of embedded pair of pants. We provide sufficient conditions to guarantee these infinite sums converge and as a result, we can generate mapping class group invariant vectors Ω∑ which we call amplitudes. The initial data encode the amplitude...... for pair of pants and tori with one boundary, as well as the "recursion kernels" used for glueing. We give this construction the name of "geometric recursion", abbreviated GR. As an illustration, we show how to apply our formalism to various spaces of continuous functions over Teichmueller spaces, as well...
DEFF Research Database (Denmark)
Bisdom, Kevin; Bertotti, Giovanni; Nick, Hamid
2016-01-01
Modeling of fluid flow in naturally fractured reservoirs is often done through modeling and upscaling of discrete fracture networks (DFNs). The two-dimensional fracture geometry required for DFNs is obtained from subsurface and outcropping analog data. However, these data provide little information...... networks, digitized from outcropping pavements. These networks cover a wide range of possible geometries and spatial distributions. The geometrically based method predicts the average hydraulic aperture and equivalent permeability of fractured porous media with error margins of less than 5%....
Geometric interpretation of the geometric discord
International Nuclear Information System (INIS)
Yao, Yao; Li, Hong-Wei; Yin, Zhen-Qiang; Han, Zheng-Fu
2012-01-01
We investigate the level surfaces of geometric measure of quantum discord, and provide a pictorial interpretation of geometric discord for Bell-diagonal states. We have observed its nonanalytic behavior under decoherence employing this approach and interestingly found if we expect geometric discord to remain constant under phase-flip channel for a finite period, the initial state must be separable. Besides, this geometric understanding can be applied to verify the hierarchical relationships between geometric discord and the original one. The present work makes us conjecture that the incompatibility of these two definitions may originate from the discrepancy of the geometric structures of them. -- Highlights: ► We investigate geometry structure of geometric measure of quantum discord. ► If geometric discord is assumed to remain constant, the initial state must be separable. ► Geometry interpretation can be applied to verify hierarchical relationships between geometric discord and the original one.
Liu, Lu; Kamm, Paul; García-Moreno, Francisco; Banhart, John; Pasini, Damiano
2017-10-01
This paper examines three-dimensional metallic lattices with regular octet and rhombicuboctahedron units fabricated with geometric imperfections via Selective Laser Sintering. We use X-ray computed tomography to capture morphology, location, and distribution of process-induced defects with the aim of studying their role in the elastic response, damage initiation, and failure evolution under quasi-static compression. Testing results from in-situ compression tomography show that each lattice exhibits a distinct failure mechanism that is governed not only by cell topology but also by geometric defects induced by additive manufacturing. Extracted from X-ray tomography images, the statistical distributions of three sets of defects, namely strut waviness, strut thickness variation, and strut oversizing, are used to develop numerical models of statistically representative lattices with imperfect geometry. Elastic and failure responses are predicted within 10% agreement from the experimental data. In addition, a computational study is presented to shed light into the relationship between the amplitude of selected defects and the reduction of elastic properties compared to their nominal values. The evolution of failure mechanisms is also explained with respect to strut oversizing, a parameter that can critically cause failure mode transitions that are not visible in defect-free lattices.
X-ray laser implementation by means of a strong source of high-spin metastable atoms
International Nuclear Information System (INIS)
Helman, J.S.; Rau, C.; Bunge, C.F.
1983-01-01
High-spin metastable atomic beams of high density and extremely small divergence can be produced by electron capture during grazing-angle scattering of ion beams at ferromagnetic surfaces. This can be used to generate a long-lived reservoir of Li 1s2s2p 4 P/sub 5/2//sup ts0/ with enough density of metastables so that after laser-induced transfer to Li 1s2p/sup ts2/P strong lasing at 207 A should occur. This novel technique can also be used to produce a variety of other metastables known as potential candidates for lasing at shorter wavelengths
Pathways for Metastable Carbonate Synthesis
Whittaker, Michael L.
the formation of a nucleus changes the system composition. In systems chemically similar to ACC, amorphous strontium carbonate (ASC) is also observed in liposomes, but crystallizes rapidly, while amorphous barium carbonate (ABC) is not. We show that ACC can be made with over 50% barium, forming ACBC, but crystallizes at a dramatically faster rate with increasing barium. I demonstrate that this process dramatically departs from the classical description applied to ACC crystallization. It can be explained by the increasing short- and mid-range order in ACBC with increasing barium, which resembles that of crystalline Ca1-xBaxCO3 and selectively lowers the barrier to its formation relative to lower-energy structures. This Ca1-xBaxCO3 phase has been misidentified as calcite in the literature, but we solve the structure, assign the new spacegroup R3m, and call it balcite. Balcite is only thermodynamically stable above 525°C, and is over 30% harder than calcite. In the absence of calcium, I show that ABC is a highly transient precursor to a previously uncharacterized BaCO3·H2 O phase. This phase forms as very thin (10 nm) and extremely anisotropic platelets, which themselves recrystallize rapidly into witherite (BaCO 3). These examples demonstrate the power of amorphous precursors to enable metastable crystalline materials through thermodynamically downhill transformations, and the ability of confined volumes to reduce the rate of these transformations and enable their quantification.
Entropy-driven metastable defects in silicon
International Nuclear Information System (INIS)
Hamilton, B.; Peaker, A.R.; Pantelides, S.T.
1989-01-01
The known metastable defects are usually describable by a configuration coordinate diagram in which two energy minima are separated by a barrier. This diagram does not change with temperature and each configuration is stable over some temperature range. Here we report the observation of a novel metastability: A configuration change occurs spontaneously and abruptly at a critical temperature, giving rise to a discontinuous DLTS (deep level transient spectroscopy) spectrum. We propose that this phenomenon is a manifestation of entropy variations in the configurational space. (author) 12 refs., 4 figs
Metastable states of small rare gas crystallites
Etters, R. D.; Danilowicz, R.; Kaelberer, J.
1977-01-01
Metastable states of rare gas crystallites containing N atoms are investigated for N = 5,6,7, and 8. In particular, the stability, structures, structural transformation, and binding energy versus temperature are determined using a Monte Carlo method. The square pyramid isomer for N = 5 is found to be unstable at any finite temperature. The other metastable isomers are all found to make spontaneous transitions to the ground state if the temperature is greater than about one half that of meltings. Comparisons with previous work are also made
Stabilization of metastable tetragonal zirconia nanocrystallites by surface modification
DEFF Research Database (Denmark)
Nielsen, Mette Skovgaard; Almdal, Kristoffer; Lelieveld, A. van
2011-01-01
Metastable tetragonal zirconia nanocrystallites were studied in humid air and in water at room temperature (RT). A stabilizing effect of different surfactants on the tetragonal phase was observed. Furthermore, the phase stability of silanized metastable tetragonal zirconia nanocrystallites...
Modelling the material behaviour of metastable stainless
Datta, K.; Geijselaers, Hubertus J.M.; Post, J.; Beyer, J.; Huetink, Han; Cesar de Sa, Jose M.A.; Santos, Abel D.
2007-01-01
Metastable austenitic stainless steels are designed to be thermodynamically unstable such that deformation even at room temperatures can bring about a change in the phase of face centred cubic austenite to either hexagonal close packed martensite and/or to body centred cubic martensite. This solid
Inelastic collision rates of trapped metastable hydrogen
Landhuis, D; Matos, L; Moss, SC; Steinberger, JK; Vant, K; Willmann, L; Greytak, TJ; Kleppner, D
We report the first detailed decay studies of trapped metastable (2S) hydrogen. By two-photon excitation of ultracold H samples, we have produced clouds of at least 5x10(7) magnetically trapped 2S atoms at densities greater than 4x10(10) cm(-3) and temperatures below 100 muK. At these densities and
Angot, E.; Huang, B.; Levelut, C.; Le Parc, R.; Hermet, P.; Pereira, A. S.; Aquilanti, G.; Frapper, G.; Cambon, O.; Haines, J.
2017-08-01
α -Quartz-type gallium phosphate and representative compositions in the AlP O4-GaP O4 solid solution were studied by x-ray powder diffraction and absorption spectroscopy, Raman scattering, and by first-principles calculations up to pressures of close to 30 GPa. A phase transition to a metastable orthorhombic high-pressure phase along with some of the stable orthorhombic C m c m CrV O4 -type material is found to occur beginning at 9 GPa at 320 ∘C in GaP O4 . In the case of the AlP O4-GaP O4 solid solution at room temperature, only the metastable orthorhombic phase was obtained above 10 GPa. The possible crystal structures of the high-pressure forms of GaP O4 were predicted from first-principles calculations and the evolutionary algorithm USPEX. A predicted orthorhombic structure with a P m n 21 space group with the gallium in sixfold and phosphorus in fourfold coordination was found to be in the best agreement with the combined experimental data from x-ray diffraction and absorption and Raman spectroscopy. This method is found to very powerful to better understand competition between different phase transition pathways at high pressure.
Directory of Open Access Journals (Sweden)
Uwe Schneider
Full Text Available When fractionation schemes for hypofractionation and stereotactic body radiotherapy are considered, a reliable cell survival model at high dose is needed for calculating doses of similar biological effectiveness. An alternative to the LQ-model is the track-event theory which is based on the probabilities for one- and two two-track events. A one-track-event (OTE is always represented by at least two simultaneous double strand breaks. A two-track-event (TTE results in one double strand break. Therefore at least two two-track-events on the same or different chromosomes are necessary to produce an event which leads to cell sterilization. It is obvious that the probabilities of OTEs and TTEs must somehow depend on the geometrical structure of the chromatin. In terms of the track-event theory the ratio ε of the probabilities of OTEs and TTEs includes the geometrical dependence and is obtained in this work by simple Monte Carlo simulations.For this work it was assumed that the anchors of loop forming chromatin are most sensitive to radiation induced cell deaths. Therefore two adjacent tetranucleosomes representing the loop anchors were digitized. The probability ratio ε of OTEs and TTEs was factorized into a radiation quality dependent part and a geometrical part: ε = εion ∙ εgeo. εgeo was obtained for two situations, by applying Monte Carlo simulation for DNA on the tetranucleosomes itself and for linker DNA. Low energy electrons were represented by randomly distributed ionizations and high energy electrons by ionizations which were simulated on rays. εion was determined for electrons by using results from nanodosimetric measurements. The calculated ε was compared to the ε obtained from fits of the track event model to 42 sets of experimental human cell survival data.When the two tetranucleosomes are in direct contact and the hits are randomly distributed εgeo and ε are 0.12 and 0.85, respectively. When the hits are simulated on rays
Eon, Jean-Guillaume
2011-01-01
Crystal-structure topologies, represented by periodic nets, are described by labelled quotient graphs (or voltage graphs). Because the edge space of a finite graph is the direct sum of its cycle and co-cycle spaces, a Euclidian representation of the derived periodic net is provided by mapping a basis of the cycle and co-cycle spaces to a set of real vectors. The mapping is consistent if every cycle of the basis is mapped on its own net voltage. The sum of all outgoing edges at every vertex may be chosen as a generating set of the co-cycle space. The embedding maps the cycle space onto the lattice L. By analogy, the concept of the co-lattice L* is defined as the image of the generators of the co-cycle space; a co-lattice vector is proportional to the distance vector between an atom and the centre of gravity of its neighbours. The pair (L, L*) forms a complete geometric descriptor of the embedding, generalizing the concept of barycentric embedding. An algebraic expression permits the direct calculation of fractional coordinates. Non-zero co-lattice vectors allow nets with collisions, displacive transitions etc. to be dealt with. The method applies to nets of any periodicity and dimension, be they crystallographic nets or not. Examples are analyzed: α-cristobalite, the seven unstable 3-periodic minimal nets etc.
Roy, G; Bissonnette, L R
2001-09-20
Backscatter and depolarization lidar measurements from clouds and precipitation are reported as functions of the elevation angle of the pointing lidar direction. We recorded the data by scanning the lidar beam (Nd:YAG) at a constant angular speed of ~3.5 degrees /s while operating at a repetition rate of 10 Hz. We show that in rain there is an evident and at times spectacular dependence on the elevation angle. That dependence appears to be sensitive to raindrop size. We have developed a three-dimensional polarization-dependent ray-tracing algorithm to calculate the backscatter and the depolarization ratio by large nonspherical droplets. We have applied it to raindrop shapes derived from existing static and dynamic (oscillating) models. We show that many of the observed complex backscatter and depolarization features can be interpreted to a good extent by geometrical optics. These results suggest that there is a definite need for more extensive calculations of the scattering phase matrix elements for large deformed raindrops as functions of the direction of illumination. Obvious applications are retrieval of information on the liquid-solid phase of precipitation and on the size and the vibration state of raindrops.
Metastable hydronium ions in UV-irradiated ice
International Nuclear Information System (INIS)
Moon, Eui-Seong; Kang, Heon
2012-01-01
We show that the irradiation of UV light (10−11 eV) onto an ice film produces metastable hydronium (H 3 O + ) ions in the ice at low temperatures (53–140 K). Evidence of the presence of metastable hydronium ions was obtained by experiments involving adsorption of methylamine onto UV-irradiated ice films and hydrogen-deuterium (H/D) isotopic exchange reaction. The methylamine adsorption experiments showed that photogenerated H 3 O + species transferred a proton to the methylamine arriving at the ice surface, thus producing the methyl ammonium ion, which was detected by low energy sputtering method. The H 3 O + species induced the H/D exchange of water, which was monitored through the detection of water isotopomers on the surface by using the Cs + reactive ion scattering method. Thermal and temporal stabilities of H 3 O + and its proton migration activity were examined. The lifetime of the hydronium ions in the amorphized ice was greater than 1 h at ∼53 K and decreased to ∼5 min at 140 K. Interestingly, a small portion of hydronium ions survived for an extraordinarily long time in the ice, even at 140 K. The average migration distance of protons released from H 3 O + in the ice was estimated to be about two water molecules at ∼54 K and about six molecules at 100 K. These results indicate that UV-generated hydronium ions can be efficiently stabilized in low-temperature ice. Such metastable hydronium ions may play a significant role in the acid-base chemistry of ice particles in interstellar clouds.
Effect of pinning and driving force on the metastability effects in ...
Indian Academy of Sciences (India)
electromagnetic response determine the metastability effects seen in the first and the third harmonic response of the AC susceptibility across the temperature ..... matter, which is different from its obvious role in measuring the shielding response from the macroscopic screening currents induced by its imposition on the ...
Metastable Helium Molecules as Tracers in Superfluid 4He
International Nuclear Information System (INIS)
Guo, W.; Wright, J. D.; Cahn, S. B.; Nikkel, J. A.; McKinsey, D. N.
2009-01-01
Metastable helium molecules generated in a discharge near a sharp tungsten tip immersed in superfluid 4 He are imaged using a laser-induced-fluorescence technique. By pulsing the tip, a small cloud of He 2 * molecules is produced. We can determine the normal-fluid velocity in a heat-induced counterflow by tracing the position of a single molecule cloud. As we run the tip in continuous field-emission mode, a normal-fluid jet from the tip is generated and molecules are entrained in the jet. A focused 910 nm pump laser pulse is used to drive a small group of molecules to the first excited vibrational level of the triplet ground state. Subsequent imaging of the tagged molecules with an expanded 925 nm probe laser pulse allows us to measure the flow velocity of the jet. The techniques we developed provide new tools in quantitatively studying the normal fluid flow in superfluid helium.
Isothermal α″ formation in β metastable titanium alloys
Energy Technology Data Exchange (ETDEWEB)
Aeby-Gautier, E., E-mail: Elisabeth.Gautier@mines.inpl-nancy.fr [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Settefrati, A. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Airbus Operations, Materials and Processes, Toulouse (France); Bruneseaux, F. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Appolaire, B. [Laboratoire d’Etudes des Microstructures ONERA – CNRS Chatillon (France); Denand, B.; Dehmas, M.; Geandier, G.; Boulet, P. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France)
2013-11-15
Highlights: ► Isothermal kinetics of orthorhombic α″ formation is characterized by HEXRD. ► Cell parameters of parent and product phases are obtained. ► Partitioning of solutes during the transformation and the ageing is discussed. -- Abstract: Thanks to time resolved high energy X-ray diffraction, isothermal decomposition of β metastable phase was studied, directly after solution treatment in the β temperature range, for temperatures ranging from 300 to 450 °C for two beta metastable alloys (Ti 17 and Ti 5553). The formation of an orthorhombic α″ phase is clearly identified at the beginning of the transformation whatever the alloy studied. If transformation occurs at the higher temperature an evolution of α″ is observed toward the hexagonal α phase. The phase amounts and the mean cell parameters of each phase were quantified by the Rietveld refinement method. The obtained cell parameters evolutions and the orthorhombicity of α″ are discussed. Moreover, the orthorhombicity of α″ compared to that obtained for stress induced martensite may indicate a slight partitioning of solutes in isothermal α″.
Demonstration of a diode-pumped metastable Ar laser.
Han, Jiande; Glebov, Leonid; Venus, George; Heaven, Michael C
2013-12-15
Pulsed lasing from optically pumped rare gas metastable atoms (Ne, Ar, Kr, and Xe) has been demonstrated previously. The laser relies on a three-level scheme, which involves the (n+1)p[5/2](3) and (n+1)p[1/2](1) states from the np(5)(n+1)p electronic configuration and the metastable (n+1)s[3/2](2) level of the np(5)(n+1)s configuration (Racah notation). Population inversions were achieved using relaxation from ((n+1)p[5/2](3) to (n+1)p[1/2](1) induced by collisions with helium or argon at pressures near 1 atm. Pulsed lasing was easily achieved using the high instantaneous pump intensities provided by a pulsed optical parametric oscillator excitation laser. In the present study we examine the potential for the development of a continuous wave (CW) optically pumped Ar laser. We report lasing of the 4p[1/2](1)→4s[3/2](2) (912.547 nm) transition following CW diode laser excitation of the 4p[5/2](3)←4s[3/2](2) line (811.754 nm). A pulsed discharge was used to generate Ar 4s[3/2](2), and the time-resolved lasing kinetics provide insights concerning the radiative and collisional relaxation processes.
Metastable states in amorphous chalcogenide semiconductors
Mikla, Victor I
2009-01-01
This book addresses an interesting and technologically important class of materials, the amorphous chalcogenide semiconductors. Experimental results on the structural and electronic metastable states in Se-rich chalcogenides are presented. Special attention is paid to the states in the mobility gap and their sensitivity to various factors such as irradiation, annealing and composition. Photoinduced changes of structure and physical properties are also considered and structural transformation at photocrystallization is studied in detail. Finally, the authors discuss potential applications of th
Detonation of Meta-stable Clusters
Energy Technology Data Exchange (ETDEWEB)
Kuhl, Allen; Kuhl, Allen L.; Fried, Laurence E.; Howard, W. Michael; Seizew, Michael R.; Bell, John B.; Beckner, Vincent; Grcar, Joseph F.
2008-05-31
We consider the energy accumulation in meta-stable clusters. This energy can be much larger than the typical chemical bond energy (~;;1 ev/atom). For example, polymeric nitrogen can accumulate 4 ev/atom in the N8 (fcc) structure, while helium can accumulate 9 ev/atom in the excited triplet state He2* . They release their energy by cluster fission: N8 -> 4N2 and He2* -> 2He. We study the locus of states in thermodynamic state space for the detonation of such meta-stable clusters. In particular, the equilibrium isentrope, starting at the Chapman-Jouguet state, and expanding down to 1 atmosphere was calculated with the Cheetah code. Large detonation pressures (3 and 16 Mbar), temperatures (12 and 34 kilo-K) and velocities (20 and 43 km/s) are a consequence of the large heats of detonation (6.6 and 50 kilo-cal/g) for nitrogen and helium clusters respectively. If such meta-stable clusters could be synthesized, they offer the potential for large increases in the energy density of materials.
Koningsberger, D.C.; Oudenhuijzen, M.K.; Bitter, J.H.; Ramaker, D.E.
2000-01-01
Geometrical and electronic effects induced by hydrogen chemisorption on supported Pt particles are studied by analysing the PtH anti-bonding shape resonance. The fundamental principles of a new analysis method of the L2 and L3 X-ray absorption edges are summarised. The method is used for studying
Ahmed, Rizwan; Kadashchuk, Andrey; Simbrunner, Clemens; Schwabegger, Günther; Baig, Muhammad Aslam; Sitter, Helmut
2014-09-10
The influence of the nature of interface between organic semiconductor and gate dielectric on bias stress electrical stability of n-type C60-based organic field effect transistors (OFETs) was studied. The bias stress induced threshold voltage (Vth) shift was found to depend critically on the OFET device structure: the direction of V(th) shift in top-gate OFETs was opposite to that in bottom-gate OFETs, while the use of the dual-gate OFET structure resulted in just very small variations in V(th). The opposite direction of Vth shift is attributed to the different nature of interfaces between C60 semiconductor and Parylene dielectric in these devices. The V(th) shift to more positive voltages upon bias stress in bottom-gate C60-OFET was similar to that observed for other n-type semiconductors and rationalized by electron trapping in the dielectric or at the gate dielectric/C60 interface. The opposite direction of Vth shift in top-gate C60-OFETs is attributed to free radical species created in the course of Parylene deposition on the surface of C60 during device fabrication, which produce plenty of hole traps. It was also realized that the dual-gate OFETs gives stable characteristics, which are immune to bias stress effects.
Off-shell M5 brane, perturbed Seiberg-Witten theory, and metastable vacua
International Nuclear Information System (INIS)
Marsano, Joseph; Papadodimas, Kyriakos; Shigemori, Masaki
2008-01-01
We demonstrate that, in an appropriate limit, the off-shell M5-brane worldvolume action effectively captures the scalar potential of Seiberg-Witten theory perturbed by a small superpotential and, consequently, any nonsupersymmetric vacua that it describes. This happens in a similar manner to the emergence from M5's of the scalar potential describing certain type IIB flux configurations [J. Marsano, K. Papadodimas, M. Shigemori, Nonsupersymmetric brane/antibrane configurations in type IIA and M theory, Nucl. Phys. B 789 (2008) 294, (arXiv: 0705.0983 [hep-th])]. We then construct exact nonholomorphic M5 configurations in the special case of SU(2) Seiberg-Witten theory deformed by a degree six superpotential which correspond to the recently discovered metastable vacua of Ooguri, Ookouchi, Park [H. Ooguri, Y. Ookouchi, C.S. Park, Metastable vacua in perturbed Seiberg-Witten theories, (arXiv: 0704.3613 [hep-th])], and Pastras [G. Pastras, Non-supersymmetric metastable vacua in N=2 SYM softly broken to N=1, (arXiv: 0705.0505 [hep-th])]. These solutions take the approximate form of a holomorphic Seiberg-Witten geometry with harmonic embedding along a transverse direction and allow us to obtain geometric intuition for local stability of the gauge theory vacua. As usual, dynamical processes in the gauge theory, such as the decay of nonsupersymmetric vacua, take on a different character in the M5 description which, due to issues of boundary conditions, typically involves runaway behavior in MQCD
PREFACE: Geometrically frustrated magnetism Geometrically frustrated magnetism
Gardner, Jason S.
2011-04-01
Oren Ofer, Amit Keren, Jess H Brewer, Tianheng H Han and Young S Lee Classical topological order in kagome ice Andrew J Macdonald, Peter C W Holdsworth and Roger G Melko Magnetic phase diagrams of classical triangular and kagome antiferromagnets M V Gvozdikova, P-E Melchy and M E Zhitomirsky The ordering of XY spin glasses Hikaru Kawamura Dynamic and thermodynamic properties of the generalized diamond chain model for azurite Andreas Honecker, Shijie Hu, Robert Peters and Johannes Richter Classical height models with topological order Christopher L Henley A search for disorder in the spin glass double perovskites Sr2CaReO6 and Sr2MgReO6 using neutron diffraction and neutron pair distribution function analysis J E Greedan, Shahab Derakhshan, F Ramezanipour, J Siewenie and Th Proffen Order and disorder in the local and long-range structure of the spin-glass pyrochlore, Tb2Mo2O7 Yu Jiang, Ashfia Huq, Corwin H Booth, Georg Ehlers, John E Greedan and Jason S Gardner The magnetic phase diagram of Gd2Sn2O7 R S Freitas and J S Gardner Calculation of the expected zero-field muon relaxation rate in the geometrically frustrated rare earth pyrochlore Gd2Sn2O7 antiferromagnet P A McClarty, J N Cosman, A G Del Maestro and M J P Gingras Magnetic frustration in the disordered pyrochlore Yb2GaSbO7 J A Hodges, P Dalmas de Réotier, A Yaouanc, P C M Gubbens, P J C King and C Baines Titanium pyrochlore magnets: how much can be learned from magnetization measurements? O A Petrenko, M R Lees and G Balakrishnan Local susceptibility of the Yb2Ti2O7 rare earth pyrochlore computed from a Hamiltonian with anisotropic exchange J D Thompson, P A McClarty and M J P Gingras Slow and static spin correlations in Dy2 + xTi2 - xO7 - δ J S Gardner, G Ehlers, P Fouquet, B Farago and J R Stewart The spin ice Ho2Ti2O7 versus the spin liquid Tb2Ti2O7: field-induced magnetic structures A P Sazonov, A Gukasov and I Mirebeau Magnetic monopole dynamics in spin ice L D C Jaubert and P C W Holdsworth
On Geometric Infinite Divisibility
Sandhya, E.; Pillai, R. N.
2014-01-01
The notion of geometric version of an infinitely divisible law is introduced. Concepts parallel to attraction and partial attraction are developed and studied in the setup of geometric summing of random variables.
Federal Laboratory Consortium — Purpose: The mission of the Geometric Design Laboratory (GDL) is to support the Office of Safety Research and Development in research related to the geometric design...
Light activated phase transformation of metastable tetragonal nanocrystalline zirconia
DEFF Research Database (Denmark)
Nielsen, Mette Skovgaard; Almdal, Kristoffer; van Lelieveld, A
2012-01-01
This study searches for small molecules, which can be generated by photoacid generators (PAGs) capable of inducing the tetragonal-to-monoclinic transformation in zirconia nanocrystals. Metastable tetragonal zirconia nanocrystals were exposed in alcohol suspension. X-ray diffraction analysis showed...... that water, HCl, HF, and NH3, all initiate phase transformation of tetragonal zirconia at room temperature, whereas NBu4Cl and NBu4OH do not. 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine) was the most efficient (monoclinic volume fraction reached 0.57) out of the four tested PAGs....... For dispersion in a dimethacrylate matrix together with zirconia crystals, a monoclinic volume fraction of 0.19 was observed after 2 min of exposure to light, increasing to 0.6 after 30 min....
Radiation-sustained nanocluster metastability in oxide dispersion strengthened materials
Energy Technology Data Exchange (ETDEWEB)
Ribis, J., E-mail: joel.ribis@cea.fr [CEA, DEN, SRMA, F-91191 Gif sur Yvette (France); Bordas, E.; Trocellier, P.; Serruys, Y. [CEA, DEN, Service de Recherches de Métallurgie Physique, Laboratoire JANNUS, 91191 Gif sur Yvette (France); Carlan, Y. de [CEA, DEN, SRMA, F-91191 Gif sur Yvette (France); Legris, A. [UMET, CNRS/UMR 8207, Bât. C6, Univ. Lille 1, 59655 Villeneuve d’Ascq (France)
2015-12-15
ODS materials constitute a new promising class of structural materials for advanced fission and fusion energy application. These Fe–Cr based ferritic steels contain ultra-high density of dispersion-strengthening nanoclusters conferring excellent mechanical properties to the alloy. Hence, guarantee the nanocluster stability under irradiation remain a critical issue. Nanoclusters are non-equilibrium multicomponent compounds (YTiCrO) forming through a complex nucleation pathway during the elaboration process. In this paper, it is proposed to observe the response of these nanoclusters when the system is placed far from equilibrium by means of ion beam. The results indicate that the Y, Ti, O and Cr atoms self-organized so that nanoclusters coarsened but maintain their non-equilibrium chemical composition. It is discussed that the radiation-sustained nanocluster metastability emerges from cooperative effects: radiation-induced Ostwald ripening, permanent creation of vacancies in the clusters, and fast Cr diffusion mediated by interstitials.
Directory of Open Access Journals (Sweden)
Götz Pilarczyk
2016-01-01
Full Text Available The present work addresses the question of to what extent a geometrical support acts as a physiological determining template in the setup of artificial cardiac tissue. Surface patterns with alternating concave to convex transitions of cell size dimensions were used to organize and orientate human-induced pluripotent stem cell (hIPSC-derived cardiac myocytes and mouse neonatal cardiac myocytes. The shape of the cells, as well as the organization of the contractile apparatus recapitulates the anisotropic line pattern geometry being derived from tissue geometry motives. The intracellular organization of the contractile apparatus and the cell coupling via gap junctions of cell assemblies growing in a random or organized pattern were examined. Cell spatial and temporal coordinated excitation and contraction has been compared on plain and patterned substrates. While the α-actinin cytoskeletal organization is comparable to terminally-developed native ventricular tissue, connexin-43 expression does not recapitulate gap junction distribution of heart muscle tissue. However, coordinated contractions could be observed. The results of tissue-like cell ensemble organization open new insights into geometry-dependent cell organization, the cultivation of artificial heart tissue from stem cells and the anisotropy-dependent activity of therapeutic compounds.
Interaction of rare gas metastable atoms
International Nuclear Information System (INIS)
Wang, A.Z.F.
1977-11-01
The physical and chemical properties of metastable rare gas atoms are discussed and summarized. This is followed by a detailed examination of the various possible pathways whereby the metastable's excess electronic energy can be dissipated. The phenomenon of chemi-ionization is given special emphasis, and a theoretical treatment based on the use of complex (optical) potential is presented. This is followed by a discussion on the unique advantages offered by elastic differential cross section measurements in the apprehension of the fundamental forces governing the ionization process. The methodology generally adopted to extract information about the interaction potential for scattering data is also systematically outlined. Two widely studied chemi-ionization systems are then closely examined in the light of accurate differential cross section measurements obtained in this work. The first system is He(2 3 S) + Ar for which one can obtain an interaction potential which is in good harmony with the experimental results of other investigators. The validity of using the first-order semiclassical approximation for the phase shifts calculation in the presence of significant opacities is also discussed. The second reaction studied is He*+D 2 for which measurements were made on both spin states of the metastable helium. A self-consistent interaction potential is obtained for the triplet system, and reasons are given for not being able to do likewise for the singlet system. The anomalous hump proposed by a number of laboratories is analyzed. Total elastic and ionization cross sections as well as rate constants are calculated for the triplet case. Good agreement with experimental data is found. Finally, the construction and operation of a high power repetitively pulsed nitrogen laser pumped dye laser system is described in great details. Details for the construction and operation of a flashlamp pumped dye laser are likewise given
Transient cognitive dynamics, metastability, and decision making.
Directory of Open Access Journals (Sweden)
Mikhail I Rabinovich
2008-05-01
Full Text Available The idea that cognitive activity can be understood using nonlinear dynamics has been intensively discussed at length for the last 15 years. One of the popular points of view is that metastable states play a key role in the execution of cognitive functions. Experimental and modeling studies suggest that most of these functions are the result of transient activity of large-scale brain networks in the presence of noise. Such transients may consist of a sequential switching between different metastable cognitive states. The main problem faced when using dynamical theory to describe transient cognitive processes is the fundamental contradiction between reproducibility and flexibility of transient behavior. In this paper, we propose a theoretical description of transient cognitive dynamics based on the interaction of functionally dependent metastable cognitive states. The mathematical image of such transient activity is a stable heteroclinic channel, i.e., a set of trajectories in the vicinity of a heteroclinic skeleton that consists of saddles and unstable separatrices that connect their surroundings. We suggest a basic mathematical model, a strongly dissipative dynamical system, and formulate the conditions for the robustness and reproducibility of cognitive transients that satisfy the competing requirements for stability and flexibility. Based on this approach, we describe here an effective solution for the problem of sequential decision making, represented as a fixed time game: a player takes sequential actions in a changing noisy environment so as to maximize a cumulative reward. As we predict and verify in computer simulations, noise plays an important role in optimizing the gain.
Levy flights: transitions and meta-stability
International Nuclear Information System (INIS)
Imkeller, Peter; Pavlyukevich, Ilya
2006-01-01
We consider Levy flights of stability index α element of (0, 2) in a potential landscape in the limit of a small noise parameter. We give a purely probabilistic description of the random dynamics on the basis of a special decomposition of the driving Levy processes into independent small jumps and compound Poisson parts. We prove that escape times from a potential well are exponentially distributed and their mean values increase as a power ε -α of the noise intensity ε. This allows us to obtain meta-stability results for a jump diffusion in a double-well potential. (letter to the editor)
Bitopic Ligands and Metastable Binding Sites
DEFF Research Database (Denmark)
Fronik, Philipp; Gaiser, Birgit I; Sejer Pedersen, Daniel
2017-01-01
of orthosteric binding sites. Bitopic ligands have been employed to address the selectivity problem by combining (linking) an orthosteric ligand with an allosteric modulator, theoretically leading to high-affinity subtype selective ligands. However, it remains a challenge to identify suitable allosteric binding...... that have been reported to date, this type of bitopic ligands would be composed of two identical pharmacophores. Herein, we outline the concept of bitopic ligands, review metastable binding sites, and discuss their potential as a new source of allosteric binding sites....
Metastable He deexcitation at semiconductor interfaces
International Nuclear Information System (INIS)
Pasquali, L.; Nannarone, S.
2005-01-01
A review is given of the application of metastable deexcitation spectroscopy (MDS) to the study of the interface formation between semiconductors and different materials. In particular we present an overview of the results obtained on nanostructured interfaces, where strain and reaction between the substrate and the overlayer atoms drive the growth mode and the morphology of the system. As prototypical examples we discuss the growth of CaF 2 on silicon and rare earths (Yb, Er) on silicon and gallium arsenide. The mechanisms and chemical reactions which bring to interface formation are examined on the basis of MDS results and their comparison with photoemission
Metastable Layered Cobalt Chalcogenides from Topochemical Deintercalation.
Zhou, Xiuquan; Wilfong, Brandon; Vivanco, Hector; Paglione, Johnpierre; Brown, Craig M; Rodriguez, Efrain E
2016-12-21
We present a general strategy to synthesize metastable layered materials via topochemical deintercalation of thermodynamically stable phases. Through kinetic control of the deintercalation reaction, we have prepared two hypothesized metastable compounds, CoSe and CoS, with the anti-PbO type structure from the starting compounds KCo 2 Se 2 and KCo 2 S 2 , respectively. Thermal stability, crystal structure from X-ray and neutron diffraction, magnetic susceptibility, magnetization, and electrical resistivity are studied for these new layered chalcogenides; both CoSe and CoS are found to be weak itinerant ferromagnets with Curie temperatures close to 10 K. Due to the weak van der Waals forces between the layers, CoSe is found to be a suitable host for further intercalation of guest species such as Li-ethylenediamine. From first-principles calculations, we explain why the Co chalcogenides are ferromagnets instead of superconductors as in their iron analogues. Bonding analysis of the calculated electronic density of states both explains their phase stability and predicts the limits of our deintercalation technique. Our results have broad implications for the rational design of new two-dimensional building blocks for functional materials.
Kinetics of optically pumped Ar metastables.
Han, Jiande; Heaven, Michael C
2014-11-15
Optically pumped lasers that use metastable excited states of Ar have been demonstrated using both pulsed and CW excitation. In terms of Paschen labeling of the states of Ar, the laser system uses excitation of the 2p9-1s5 transition, and lases on the 2p10-1s5 line. Collisional transfer of population from 2p9 to 2p10 is achieved using He as the buffer gas. For the purpose of modeling and developing this laser, rate constants for state-to-state transfer in Ar(2p(i))+Ar/He mixtures are needed. As the 2p10 level can radiate down to 1s4, this lower level also plays a significant role in the laser kinetics. Consequently, rate constants for the relaxation of 1s4 by Ar and He are also required. In the present study we have used pulsed laser excitation techniques to measure rate constants of relevance to the optically pumped metastable Ar laser.
The liquid metastable miscibility gap in Cu-based systems
DEFF Research Database (Denmark)
Curiotto, S.; Greco, R.; Pryds, Nini
2007-01-01
. In order to predict the phase equilibria and the mechanisms of microstructure formation, a determination of the metastable monotectics in the phase diagrams is essential. This paper focuses on the up-to-date findings on the Cu–Co, Cu–Fe and Cu–Co–Fe metastable miscibility gap in the liquid phase...
Lifetime of the metastable 23S1 state in stored Li+ ions
International Nuclear Information System (INIS)
Knight, R.D.
1979-04-01
A laser-induced fluorescence technique combined with the observation of spontaneous magnetic dipole photons from the highly metastable 2 3 S 1 state of Li + was used to measure the radiative lifetime of this state. The ions are created by electron impact on a lithium atomic beam and are subsequently stored for periods of many seconds in an RF-quadrupole ion trap. A tunable dye laser excites the 2 3 S--2 3 P, transition at 5485A, and the intercombination electric dipole transition 2 3 P 1 --1 1 S 0 at 202A is observed. This process depletes the metastable population in a time tau/sub d/ 3 S 1 / and provides a measure of the total number of metastables. Comparison with the rate of 210A spontaneously emitted photons yields a measured value for the 2 3 S 1 radiative lifetime of tau/sub rad/ = 58.6 +- 12.9 sec, where the quoted error represents 95% confidence levels. The theoretical lifetime is tau/sub theory/ = 49.0 sec. The measured value includes data taken with both 6 Li + and 7 Li + isotopes and was corrected for the slightly different detector efficiencies at 202A and 210A. A careful study of nonradiative quenching of the metastable state was necessary to understand observed differences between tau/sub rad/ and tau/sub 3 S 1 /, the total metastable lifetime. Spatial density profiles of the ions within the trap, useful for determining the ion temperature, were obtained by scanning the laser beam horizontally across the ion trap while storing 2 3 P 1 -- 1 S 0 photon counts as a function of the laser beam's position. Agreement with a simple equilibrium model, including space charge effects, is satisfactory. A study of the optical pumping process is necessary to understand the laser-ion interaction, and observational and theoretical data are presented. 47 references
Texture evolution in thin-sheets on AISI 301 metastable stainless steel under dynamic loading
Energy Technology Data Exchange (ETDEWEB)
Kim, K.Y. [Posco Steels, Pohan, South Korea (Korea, Republic of); Kozaczek, K. [Oak Ridge National Lab., TN (United States); Kulkarni, S.M. [TRW Vehicle Safety Systems, Mesa, AZ (United States); Bastias, P.C.; Hahn, G.T. [Vanderbilt Univ., Nashville, TN (United States)
1995-05-08
The evolution of texture in thin sheets of metastable austenitic stainless steel AISI 301 is affected by external conditions such as loading rate and temperature, by inhomogeneous deformation phenomena such as twinning and shear band formation, and by the concurent strain induced phase transformation of the retained austenitc ({gamma}) into martensite ({alpha}). The present paper describes texture measurements on different gauges of AISI 301 prior and after uniaxial stretching under different conditions.
Selective removal of either metastable species from a mixed 3P 0,2 rare-gas metastable beam
Dunning, F. B.; Cook, T. B.; West, W. P.; Stebbings, R. F.
1975-01-01
A tunable CW laser has been used to selectively remove either of the two metastable species, 3P 0,2, which are initially present in a neon metastable beam. The method is applicable to other rare gases and provides the opportunity for separate investigation of effects due to atoms in either the 3P 0 or 3P 2 state.
Geometric phases and quantum computation
International Nuclear Information System (INIS)
Vedral, V.
2005-01-01
Full text: In my lectures I will talk about the notion of the geometric phase and explain its relevance for both fundamental quantum mechanics as well as quantum computation. The phase will be at first introduced via the idea of Pancharatnam which involves interference of three or more light beams. This notion will then be generalized to the evolving quantum systems. I will discuss both pure and mixed states as well as unitary and non-unitary evolutions. I will also show how the concept of the vacuum induced geometric phase arises in quantum optics. A simple measurement scheme involving a Mach Zehnder interferometer will be presented and will be used to illustrate all the concepts in the lecture. Finally, I will expose a simple generalization of the geometric phase to evolving degenerate states. This will be seen to lead to the possibility of universal quantum computation using geometric effects only. Moreover, this contains a promise of intrinsically fault tolerant quantum information processing, whose prospects will be outlined at the end of the lecture. (author)
Metastable electroweak vacuum. Implications for inflation
Energy Technology Data Exchange (ETDEWEB)
Lebedev, Oleg; Westphal, Alexander [DESY Theory Group, Hamburg (Germany)
2012-10-15
Within the Standard Model, the current Higgs and top quark data favor metastability of the electroweak vacuum, although the uncertainties are still significant. The true vacuum is many orders of magnitude deeper than ours and the barrier separating the two is tiny compared to the depth of the well. This raises a cosmological question: how did the Higgs field get trapped in the shallow minimum and why did it stay there during inflation? The Higgs initial conditions before inflation must be fine-tuned to about one part in 10{sup 8} in order for the Higgs field to end up in the right vacuum. In this note, we show that these problems can be resolved if there is a small positive coupling between the Higgs and the inflaton.
The Lotus effect: superhydrophobicity and metastability.
Marmur, Abraham
2004-04-27
To learn how to mimic the Lotus effect, superhydrophobicity of a model system that resembles the Lotus leaf is theoretically discussed. Superhydrophobicity is defined by two criteria: a very high water contact angle and a very low roll-off angle. Since it is very difficult to calculate the latter for rough surfaces, it is proposed here to use the criterion of a very low wet (solid-liquid) contact area as a simple, approximate substitute for the roll-off angle criterion. It is concluded that nature employs metastable states in the heterogeneous wetting regime as the key to superhydrophobicity on Lotus leaves. This strategy results in two advantages: (a) it avoids the need for high steepness protrusions that may be sensitive to breakage and (b) it lowers the sensitivity of the superhydrophobic states to the protrusion distance.
From materials control to astrophysics: metastable superconductors
International Nuclear Information System (INIS)
Waysand, G.
1984-01-01
The basic properties of metastable superconducting materials are reviewed: superheated domain, size of the granules, reading of the change of state. In the case of superheating, the phase transition can occur following two paths: a) increase of temperature (thermal nucleation) which allows an analysis of the calorimetric behavior for particle detection; b) increase of the applied magnetic field which allows the evaluation of surface defects promoting the nucleation of the normal state, and, more generally, the study of the superheated material as a disordered system. The thermal nucleation is useful for X-ray detection in non-destructive control as well as for the solar neutrino detection in real time. The magnetic nucleation is the basis for a proposal of detection of magnetic monopoles by induction [fr
Photoassociative spectroscopy of ultracold metastable argon
International Nuclear Information System (INIS)
Shaffer, M. K.; Ranjit, G.; Sukenik, C. I.; Walhout, M.
2011-01-01
We present results of photoassociative spectroscopy performed on ultracold metastable argon atoms in a magneto-optical trap. Ion spectra are obtained with laser detuning up to a few gigahertz below the 4s[3/2] 2 →4p[5/2] 3 trapping transition at 811 nm and with intensities in a range of ∼(10 2 -10 5 )I Sat . We also compute dipole-dipole potentials for both singly and doubly excited diatomic molecules and use a Leroy-Bernstein analysis to determine the approximate vibrational spacings in the (s+p) and (p+p) manifolds. Based on this theoretical framework, we explain a broad background feature in our data and suggest that double-excitation mechanisms are likely responsible for sharp dips in the ion signal.
Energy Technology Data Exchange (ETDEWEB)
Maciaszek, M.; Zabierowski, P. [Faculty of Physics, Warsaw University of Technology, Koszykowa 75, Warszawa 00 662 (Poland)
2016-06-07
In this contribution, we investigated by means of numerical simulations the influence of relaxation processes related to metastable defects on electrical characteristics of Cu(In,Ga)Se{sub 2}. In particular, we analyzed the relaxation of a metastable state induced by illumination at a fixed temperature as well as the dependence of the hole concentration on the temperature during cooling. The knowledge of these two relaxation processes is crucial in the evaluation of the hole concentration in the relaxed state and after light soaking. We have shown that the distribution of the metastable defects can be considered frozen below 200 K. The hole capture cross section was estimated as ∼3 × 10{sup −15} cm{sup 2}. It was shown that the usually used cooling rates may lead to relevant changes of the hole concentration. We calculated the lower limit of the hole concentration after cooling, and we presented how it depends on densities of shallow acceptors and metastable defects. Moreover, we proposed a method which allows for the evaluation of shallow acceptor and metastable defect densities from two capacitance-voltage profiles measured in the relaxed and light soaking states. Finally, we indicated experimental conditions in which the influence of relaxation processes on the accuracy of this method is the smallest.
Geometric Dimensioning Sentence Structure.
McCuistion, Patrick J.
1991-01-01
Explanations of geometric dimensioning symbols are provided to assist in the comprehension of the implied basic sentence structure of modern geometric dimensioning and tolerance. The proper identification and interpretation of the substantive language within several exemplary engineering drawings, otherwise called feature control frames, is…
Photo-crystallography: from the structure towards the electron density of metastable states
Energy Technology Data Exchange (ETDEWEB)
Legrand, V [Laboratoire de Cristallographie et de Modelisation des Materiaux Mineraux et Biologiques, CNRS UMR 7036, UHP Nancy 1, Faculte des sciences, Boulevard des Aiguillettes, BP 239, 54506 Vandoeuvre-les-Nancy Cedex (France); Carbonera, C [Institut de Chimie de la Matiere Condensee de Bordeaux, UPR CNRS 9048, Universite de Bordeaux 1, Groupe de Sciences Moleculaires, 87 Avenue du Docteur Schweitzer, 33608 Pessac cedex (France); Pillet, S [Laboratoire de Cristallographie et de Modelisation des Materiaux Mineraux et Biologiques, CNRS UMR 7036, UHP Nancy 1, Faculte des sciences, Boulevard des Aiguillettes, BP 239, 54506 Vandoeuvre-les-Nancy Cedex (France); Souhassou, M [Laboratoire de Cristallographie et de Modelisation des Materiaux Mineraux et Biologiques, CNRS UMR 7036, UHP Nancy 1, Faculte des sciences, Boulevard des Aiguillettes, BP 239, 54506 Vandoeuvre-les-Nancy Cedex (France); Letard, J F [Institut de Chimie de la Matiere Condensee de Bordeaux, UPR CNRS 9048, Universite de Bordeaux 1, Groupe de Sciences Moleculaires, 87 Avenue du Docteur Schweitzer, 33608 Pessac cedex (France); Guionneau, P [Institut de Chimie de la Matiere Condensee de Bordeaux, UPR CNRS 9048, Universite de Bordeaux 1, Groupe de Sciences Moleculaires, 87 Avenue du Docteur Schweitzer, 33608 Pessac cedex (France); Lecomte, C [Laboratoire de Cristallographie et de Modelisation des Materiaux Mineraux et Biologiques, CNRS UMR 7036, UHP Nancy 1, Faculte des sciences, Boulevard des Aiguillettes, BP 239, 54506 Vandoeuvre-les-Nancy Cedex (France)
2005-01-01
A photo-crystallographic study of Fe(btr){sub 2}(NCS){sub 2}{center_dot}H{sub 2}O was performed in order to describe the modification of structures and charge densities on going from the ground low spin (LS) state to the metastable high spin (HS) state during the LIESST phenomenon at 15 K. Related photo-magnetic and spectroscopic measurements are also described. We show that at 15 K, the thermally quenched and photo-induced structures of the metastable HS state are identical. For comparison, we also derived the structure of the HS and LS states at 130 K in the hysteresis loop; the thermal spin transition and the LIESST spin transition exhibit similar structural behaviours.
Metastable memristive lines for signal transmission and information processing applications
Slipko, Valeriy A.; Pershin, Yuriy V.
2017-04-01
Traditional studies of memristive devices have mainly focused on their applications in nonvolatile information storage and information processing. Here, we demonstrate that the third fundamental component of information technologies—the transfer of information—can also be employed with memristive devices. For this purpose, we introduce a metastable memristive circuit. Combining metastable memristive circuits into a line, one obtains an architecture capable of transferring a signal edge from one space location to another. We emphasize that the suggested metastable memristive lines employ only resistive circuit components. Moreover, their networks (for example, Y-connected lines) have an information processing capability.
Quantum mechanical metastability: When and why?
International Nuclear Information System (INIS)
Boyanovsky, D.; Willey, R.; Holman, R.
1992-01-01
We study quantum mechanical metastability with an eye towards false vacuum decay. We point out some technical and conceptual problems with the familiar bounce treatment of this process. We illustrate with simple quantum mechanical examples that the bounce formalism fails to account for the correct boundary conditions. It is also shown, that the bounce approach overestimates the time scales for tunneling of localized packets in typical (slightly) biased double well potentials. We present a thorough WKB analysis with particular attention to semiclassical trajectories corresponding to complex saddle points. We point out that the boundary conditions determine the proper choice of saddle points and the bounce approach fails to account for semiclassical trajectories in many physically relevant cases. We recognize that these saddle points account for the matching conditions of the WKB wave functions beyond the barriers and restore unitarity and reality of eigenvalues for self-adjoint boundary conditions. We provide a novel approach to the semiclassical analysis of out of equilibrium decay in real time in quantum statistical mechanics. (orig.)
Investigation of systematic errors of metastable "atomic pair" number
Yazkov, V
2015-01-01
Sources of systematic errors in analysis of data, collected in 2012, are analysed. Esti- mations of systematic errors in a number of “atomic pairs” fr om metastable π + π − atoms are presented.
Influence of radiation on metastability-based TRNG
Wieczorek, Piotr Z.; Wieczorek, Zbigniew
2017-08-01
This paper presents a True Random Number Generator (TRNG) based on Flip-Flops with violated timing constraints. The proposed circuit has been implemented in a Xilinx Spartan 6 device. The TRNG circuit utilizes the metastability phenomenon as a source of randomness. Therefore, in the paper the influence of timing constraints on the flip-flop metastability proximity is discussed. The metastable range of operation enhances the noise influence on a Flip-Flop behavior. Therefore, the influence of an external stochastic source on the flip-flop operation is also investigated. For this purpose a radioactive source of radiation was used. According to the results shown in the paper the radiation increases the unpredictability of the metastable process of flip-flops operating as the randomness source in the TRNG. The statistical properties of TRNG operating in an increased radiation conditions were verified with the NIST battery of statistical tests.
The Importance of Kinetic Metastability: Some Common Everyday Examples
Jensen, William B.
2015-01-01
The importance of kinetic metastability is illustrated in detail using several common household products and recommendations are made for how this important and widespread, but often neglected, phenomenon can be more effectively presented in the introductory chemistry textbook.
Geometric and engineering drawing
Morling, K
2010-01-01
The new edition of this successful text describes all the geometric instructions and engineering drawing information that are likely to be needed by anyone preparing or interpreting drawings or designs with plenty of exercises to practice these principles.
Geometric ghosts and unitarity
International Nuclear Information System (INIS)
Ne'eman, Y.
1980-09-01
A review is given of the geometrical identification of the renormalization ghosts and the resulting derivation of Unitarity equations (BRST) for various gauges: Yang-Mills, Kalb-Ramond, and Soft-Group-Manifold
Differential geometric structures
Poor, Walter A
2007-01-01
This introductory text defines geometric structure by specifying parallel transport in an appropriate fiber bundle and focusing on simplest cases of linear parallel transport in a vector bundle. 1981 edition.
Extension of equilibrium formation criteria to metastable microalloys
International Nuclear Information System (INIS)
Kaufmann, E.N.; Vianden, R.; Chelikowsky, J.R.; Phillips, J.C.
1977-01-01
Metastable microalloys of 25 metallic elements with beryllium have been prepared by ion implantation. The injected atoms have been found to occupy one of three sites available in the solvent lattice. A modified Laudau-Ginsburg expansion using bulk alloy variables proposed by Miedema is completely successful in predicting the observed metastable-site preferences and indicates a broader applicability of these variables than was heretofore anticipated
Defect-related electronic metastabilities in chalcopyrite compounds
Energy Technology Data Exchange (ETDEWEB)
Hammer, Maria S., E-mail: maria.hammer@uni-oldenburg.de [Energy and Semiconductor Research Laboratory, Department of Physics, University of Oldenburg, 26111 Oldenburg (Germany); Neugebohrn, Nils; Riediger, Julia; Neerken, Janet; Ohland, Jörg; Riedel, Ingo [Energy and Semiconductor Research Laboratory, Department of Physics, University of Oldenburg, 26111 Oldenburg (Germany); Kiowski, Oliver; Wischmann, Wiltraud [Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg (ZSW), Industriestr. 6, 70565 Stuttgart (Germany)
2014-04-15
So far, in Cu(In,Ga)Se{sub 2} solar cells the metastable behavior of the key parameters, i.e. open circuit voltage, short circuit current and fill factor, and the corresponding defect physics were typically investigated independently. In order to contribute to this issue, we systematically varied between annealed and light soaked state and investigated the influence of these processes on the solar cell parameters as well as on the defect physics. In this work, we attempt to correlate the key parameters of the solar cells and the defect physics by discussing experimental results obtained from temperature dependent current–voltage measurements (IVT) as well as from capacitance voltage (CV), admittance (AS) and deep-level transient spectroscopy (DLTS). A commonly observed defect contribution in Cu(In,Ga)Se{sub 2} solar cells is the so-called N1 signature. The activation energy of this signature was found to increase upon air-annealing in the dark which goes along with a decrease in the open circuit voltage and the effective doping density. In this paper we will discuss the correlation between annealing-induced shifting of defect energies and the variation of the key parameters.
Metastable enhancement of C+ and O+ capture reactions
International Nuclear Information System (INIS)
Thomas, E.W.
1992-01-01
The project is devoted to the study of charge transfer neutralization of Carbon and oxygen ions in H and H 2 gases at energies from 10 to 500 eV. A major motivation was to provide cross section data to support analysis of edge plasmas in Tokamak Fusion devices. The first objective was to measure cross sections for metastable excited singly charged ions separately from the cross sections for ground state ions. Previously published values are confusing because the beams used included unknown fractions of metastables and these metastables have cross sections greatly different from the ground states. The program was fully accomplished, metastable cross sections were found to be over an order of magnitude greater than ones for the ground state and existing discrepancies in the literature were resolved. Considerable effort was devoted to the design and operation of ion source configurations were the metastable content of the ion beam was known. Subsequently study progressed to the neutralization of multiply charged C and 0 ions in the same targets. First there has been a need to develop ion sources which can produce useful beams of multiply charged species. This has now been accomplished. The intent is to use these sources for the measurement of cross sections with again an attempt to differentiate between the behavior of ground and metastably excited species
International Nuclear Information System (INIS)
He, X.N.; Xie, Z.Q.; Gao, Y.; Hu, W.; Guo, L.B.; Jiang, L.; Lu, Y.F.
2012-01-01
Mass spectrometry of solid samples in open air was carried out using combined laser ionization and metastable ionization time-of-flight mass spectrometry (LI-MI-TOFMS) in ambient environment for qualitative and semiquantitative (relative analyte information, not absolute information) analysis. Ambient metastable ionization using a direct analysis in realtime (DART) ion source was combined with laser ionization time-of-flight mass spectrometry (LI-TOFMS) to study the effects of combining metastable and laser ionization. A series of metallic samples from the National Institute of Standards and Technology (NIST 494, 495, 498, 499, and 500) and a pure carbon target were characterized using LI-TOFMS in open air. LI-MI-TOFMS was found to be superior to laser-induced breakdown spectroscopy (LIBS). Laser pulse energies between 10 and 200 mJ at the second harmonic (532 nm) of an Nd:YAG laser were applied in the experiment to obtain a high degree of ionization in plasmas. Higher laser pulse energy improves signal intensities of trace elements (such as Fe, Cr, Mn, Ni, Ca, Al, and Ag). Data were analyzed by numerically calculating relative sensitivity coefficients (RSCs) and limit of detections (LODs) from mass spectrometry (MS) and LIBS spectra. Different parameters, such as boiling point, ionization potential, RSC, LOD, and atomic weight, were shown to analyze the ionization and MS detection processes in open air.
Tensorial analysis of the long-range interaction between metastable alkaline-earth-metal atoms
International Nuclear Information System (INIS)
Santra, Robin; Greene, Chris H.
2003-01-01
Alkaline-earth-metal atoms in their lowest (nsnp) 3 P 2 state are exceptionally long lived and can be trapped magnetically. The nonspherical atomic structure leads to anisotropic long-range interactions between two metastable alkaline-earth-metal atoms. The anisotropy affects the rotational motion of the diatomic system and couples states of different rotational quantum numbers. This paper develops a tensorial decomposition of the most important long-range interaction operators, and a systematic inclusion of molecular rotations, in the presence of an external magnetic field. This analysis illuminates the nature of the coupling between the various degrees of freedom. The consequences are illustrated by application to a system of practical interest: metastable 88 Sr. Using atomic parameters determined in a nearly ab initio calculation, we compute adiabatic potential-energy curves. The anisotropic interatomic interaction, in combination with the applied magnetic field, is demonstrated to induce the formation of a long-range molecular potential well. This curve correlates to two fully polarized, low-field seeking atoms in a rotational s-wave state. The coupling among molecular rotational states controls the existence of the potential well, and its properties vary as a function of magnetic-field strength, thus allowing the scattering length in this state to be tuned. The scattering length of metastable 88 Sr displays a resonance at a field of 339 G
Shear response of grain boundaries with metastable structures by molecular dynamics simulations
Zhang, Liang; Lu, Cheng; Shibuta, Yasushi
2018-04-01
Grain boundaries (GBs) can play a role as the favored locations to annihilate point defects, such as interstitial atoms and vacancies. It is thus highly probable that different boundary structures can be simultaneously present in equilibrium with each other in the same GB, and thus the GB achieves a metastable state. However, the structural transition and deformation mechanism of such GBs are currently not well understood. In this work, molecular dynamics simulations were carried out to study the multiple structures of a Σ5(310)/[001] GB in bicrystal Al and to investigate the effect of structural multiplicity on the mechanical and kinetic properties of such a GB. Different GB structures were obtained by changing the starting atomic configuration of the bicrystal model, and the GB structures had significantly different atomic density. For the Σ5(310) GB with metastable structures, GB sliding was the dominant mechanism at a low temperature (T = 10 K) under shear stress. The sliding mechanism resulted from the uncoordinated transformation of the inhomogeneous structural units. The nucleation of voids was observed during GB sliding at the low temperature, and the voids subsequently evolved to a nanocrack at the boundary plane. Increasing the temperature can induce the structural transition of local GB structures and can change their overall kinetic properties. GB migration with occasional GB sliding dominated the deformation mechanism at elevated temperatures (T = 300 and 600 K), and the migration process of the metastable GB structures is closely related to the thermally assisted diffusion mechanism.
WIERIK, GHPT; EISSENS, AC; BESEMER, AC; LERK, CF
The linear dextrin amylodextrin was prepared by enzymatic hydrolysis from waxy maize. Four metastable amylodextrins were prepared by complexation with different volatile organic compounds. All products showed partial dissolution into water at room temperature, because of dissolution of molecules
Matching of the Flux Lattice to Geometrically Frustrated Pinning Arrays
Trastoy, J.; Bernard, R.; Briatico, J.; Villegas, J. E.; Lesueur, J.; Ulysse, C.; Faini, G.
2013-03-01
We use vortex dynamics on artificial nanoscale energy landscapes as a model to experimentally investigate a problem inspired by ``spin ice'' systems. In particular, we study the matching of the flux lattice to pinning arrays in which the geometrical frustration is expected to impede a unique stable vortex configuration and to promote metastability. This is done with YBCO films in which the nanoscale vortex energy landscape is fabricated via masked ion irradiation. Surprisingly, we found that minimal changes in the distance between pinning sites lead to the suppression of some of the magneto-resistance matching effects, that is, for certain well-defined vortex densities. This effect strongly depends on the temperature. We argue that this behavior can be explained considering the arrays' geometrical frustration and the thermally activated reconfiguration of the vortex lattice between isoenergetic states. Work supported by the French ANR via SUPERHYRBIDS-II and ``MASTHER,'' and the Galician Fundacion Barrie
Geometrical optical illusionists.
Wade, Nicholas J
2014-01-01
Geometrical optical illusions were given this title by Oppel in 1855. Variants on such small distortions of visual space were illustrated thereafter, many of which bear the names of those who first described them. Some original forms of the geometrical optical illusions are shown together with 'perceptual portraits' of those who described them. These include: Roget, Chevreul, Fick, Zöllner, Poggendorff, Hering, Kundt, Delboeuf Mach, Helmholtz, Hermann, von Bezold, Müller-Lyer, Lipps, Thiéry, Wundt, Münsterberg, Ebbinghaus, Titchener, Ponzo, Luckiesh, Sander, Ehrenstein, Gregory, Heard, White, Shepard, and. Lingelbach. The illusions are grouped under the headings of orientation, size, the combination of size and orientation, and contrast. Early theories of illusions, before geometrical optical illusions were so named, are mentioned briefly.
Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off.
Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun; Raabe, Dierk; Tasan, Cemal Cem
2016-06-09
Metals have been mankind's most essential materials for thousands of years; however, their use is affected by ecological and economical concerns. Alloys with higher strength and ductility could alleviate some of these concerns by reducing weight and improving energy efficiency. However, most metallurgical mechanisms for increasing strength lead to ductility loss, an effect referred to as the strength-ductility trade-off. Here we present a metastability-engineering strategy in which we design nanostructured, bulk high-entropy alloys with multiple compositionally equivalent high-entropy phases. High-entropy alloys were originally proposed to benefit from phase stabilization through entropy maximization. Yet here, motivated by recent work that relaxes the strict restrictions on high-entropy alloy compositions by demonstrating the weakness of this connection, the concept is overturned. We decrease phase stability to achieve two key benefits: interface hardening due to a dual-phase microstructure (resulting from reduced thermal stability of the high-temperature phase); and transformation-induced hardening (resulting from the reduced mechanical stability of the room-temperature phase). This combines the best of two worlds: extensive hardening due to the decreased phase stability known from advanced steels and massive solid-solution strengthening of high-entropy alloys. In our transformation-induced plasticity-assisted, dual-phase high-entropy alloy (TRIP-DP-HEA), these two contributions lead respectively to enhanced trans-grain and inter-grain slip resistance, and hence, increased strength. Moreover, the increased strain hardening capacity that is enabled by dislocation hardening of the stable phase and transformation-induced hardening of the metastable phase produces increased ductility. This combined increase in strength and ductility distinguishes the TRIP-DP-HEA alloy from other recently developed structural materials. This metastability-engineering strategy should
Energy Technology Data Exchange (ETDEWEB)
Comet, M.; Spitzer, D. [Institut Franco-Allemand de Saint-Louis (ISL) (France)
2006-07-15
Thermites are non-nuclear materials with the highest bulk energetic potential (10-25 kJ.cm{sup -3}). Thermites mixtures are composed of a metal oxide and an oxo-phile metal used as a strong reducer. Contrary to explosive energetic compositions, thermites have a high density, a low kinetic of combustion. Moreover, they have a smaller sensitivity than explosive energetic compositions regarding thermal and mechanical stresses. Finally, they do not detonate and generate small quantities of gaseous products. Decomposition of thermites is an oxido-reduction reaction between two solid phases. The kinetic of combustion is governed by the mass transfer between the oxidant and the reducing phase. That is the reason why nano-structuration dramatically increases the speed of combustion of metastable interstitial composites (MIC) which can reach 895 m.s{sup -1}. This paper aims to describe the experimental methods currently used to elaborate MIC and to point out their limits. (authors)
Geometric Series via Probability
Tesman, Barry
2012-01-01
Infinite series is a challenging topic in the undergraduate mathematics curriculum for many students. In fact, there is a vast literature in mathematics education research on convergence issues. One of the most important types of infinite series is the geometric series. Their beauty lies in the fact that they can be evaluated explicitly and that…
A Geometric Dissection Problem
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 7; Issue 7. A Geometric Dissection Problem. M N Deshpande. Think It Over Volume 7 Issue 7 July 2002 pp 91-91. Fulltext. Click here to view fulltext PDF. Permanent link: https://www.ias.ac.in/article/fulltext/reso/007/07/0091-0091. Author Affiliations.
Geometric statistical inference
International Nuclear Information System (INIS)
Periwal, Vipul
1999-01-01
A reparametrization-covariant formulation of the inverse problem of probability is explicitly solved for finite sample sizes. The inferred distribution is explicitly continuous for finite sample size. A geometric solution of the statistical inference problem in higher dimensions is outlined
The effect of metastability in the process of fatigue of an austenitic stainless steel
International Nuclear Information System (INIS)
Pacheco, D.J.
1977-01-01
The influence of martensitic phase transformation on the process of pulsating tensile stress is studied in a metastable type AISI 316 stainless steel in the temperature range from 25 to -196 0 C. Annealed as well as previously deformed specimens are tested for the typical microstructural characteristics. It is concluded that the fatigue limit as well as the crack mechanisms depend upon the nature of the slip of crystalographic planes. The martensitic transformation previously induced by plastic deformation shows an undesirable fatigue character, in the annealed state and tested at 25 0 C, the type 316 steel will need a plastic deformation equal to or slightly above 9% for pulsating tension fracture [pt
Classification of knotted tori in 2-metastable dimension
Energy Technology Data Exchange (ETDEWEB)
Cencelj, Matija; Repovs, Dusan; Skopenkov, Mihail B
2012-11-30
This paper is devoted to the classical Knotting Problem: for a given manifold N and number m describe the set of isotopy classes of embeddings N{yields}S{sup m}. We study the specific case of knotted tori, that is, the embeddings S{sup p} Multiplication-Sign S{sup q}{yields}S{sup m}. The classification of knotted tori up to isotopy in the metastable dimension range m {>=} p + 3/2q + 2, p{<=}q, was given by Haefliger, Zeeman and A. Skopenkov. We consider the dimensions below the metastable range and give an explicit criterion for the finiteness of this set of isotopy classes in the 2-metastable dimension. Bibliography: 35 titles.
Classification of knotted tori in 2-metastable dimension
Cencelj, Matija
2012-11-30
This paper is devoted to the classical Knotting Problem: for a given manifold N and number m describe the set of isotopy classes of embeddings N → Sm. We study the specific case of knotted tori, that is, the embeddings Sp × Sq → Sm. The classification of knotted tori up to isotopy in the metastable dimension range m > p + 3 2 q + 2, p 6 q, was given by Haefliger, Zeeman and A. Skopenkov. We consider the dimensions below the metastable range and give an explicit criterion for the finiteness of this set of isotopy classes in the 2-metastable dimension: Theorem. Assume that p+ 4 3 q +2 < mp+ 3 2 q +2 and m > 2p+q +2. Then the set of isotopy classes of smooth embeddings Sp × Sq → Sm is infinite if and only if either q + 1 or p + q + 1 is divisible by 4. © 2012 RAS(DoM) and LMS.
Metastable bcc phase formation in the Nb-Cr system
Energy Technology Data Exchange (ETDEWEB)
Thoma, D.J.; Schwarz, R.B. [Los Alamos National Lab., NM (United States); Perepezko, J.H. [Wisconsin Univ., Madison, WI (United States). Dept. of Materials Science and Engineering; Plantz, D.H. [Coast Guard Academy, New London, CT (United States). Dept. of Engineering
1993-08-01
Extended metastable bcc solid solutions of Nb-Xat.%Cr (X = 35, 50, 57, 77, 82, and 94) were synthesized by two-anvil splat-quenching. In addition, bcc (Nb-67at.%Cr) was prepared by mechanically alloying mixtures of niobium and chromium powders. The lattice parameters were measured by X-ray diffraction and the Young`s moduli were measured by low-load microindentation. The composition dependence of the lattice parameters and elastic moduli show a positive deviation with respect to a rule of mixtures. During continuous heating at 15C/min., the metastable precursor bcc phases decomposed at temperatures above 750C to uniformly refined microstructures.
Metastable and scaling regimes of one-dimensional Kawasaki dynamics
Albarracín, F. A. Gómez; Rosales, H. D.; Grynberg, M. D.
2016-04-01
We investigate the large-time scaling regimes arising from a variety of metastable structures in a chain of Ising spins with both first- and second-neighbor couplings while subject to Kawasaki dynamics. Depending on the ratio and sign of these former, different dynamic exponents are suggested by finite-size scaling analyses of relaxation times. At low but nonzero temperatures these are calculated via exact diagonalizations of the evolution operator in finite chains under several activation barriers. In the absence of metastability the dynamics is always diffusive.
Dynamics in geometrical confinement
Kremer, Friedrich
2014-01-01
This book describes the dynamics of low molecular weight and polymeric molecules when they are constrained under conditions of geometrical confinement. It covers geometrical confinement in different dimensionalities: (i) in nanometer thin layers or self supporting films (1-dimensional confinement) (ii) in pores or tubes with nanometric diameters (2-dimensional confinement) (iii) as micelles embedded in matrices (3-dimensional) or as nanodroplets.The dynamics under such conditions have been a much discussed and central topic in the focus of intense worldwide research activities within the last two decades. The present book discusses how the resulting molecular mobility is influenced by the subtle counterbalance between surface effects (typically slowing down molecular dynamics through attractive guest/host interactions) and confinement effects (typically increasing the mobility). It also explains how these influences can be modified and tuned, e.g. through appropriate surface coatings, film thicknesses or pore...
Bestvina, Mladen; Vogtmann, Karen
2014-01-01
Geometric group theory refers to the study of discrete groups using tools from topology, geometry, dynamics and analysis. The field is evolving very rapidly and the present volume provides an introduction to and overview of various topics which have played critical roles in this evolution. The book contains lecture notes from courses given at the Park City Math Institute on Geometric Group Theory. The institute consists of a set of intensive short courses offered by leaders in the field, designed to introduce students to exciting, current research in mathematics. These lectures do not duplicate standard courses available elsewhere. The courses begin at an introductory level suitable for graduate students and lead up to currently active topics of research. The articles in this volume include introductions to CAT(0) cube complexes and groups, to modern small cancellation theory, to isometry groups of general CAT(0) spaces, and a discussion of nilpotent genus in the context of mapping class groups and CAT(0) gro...
Frè, Pietro Giuseppe
2013-01-01
‘Gravity, a Geometrical Course’ presents general relativity (GR) in a systematic and exhaustive way, covering three aspects that are homogenized into a single texture: i) the mathematical, geometrical foundations, exposed in a self consistent contemporary formalism, ii) the main physical, astrophysical and cosmological applications, updated to the issues of contemporary research and observations, with glimpses on supergravity and superstring theory, iii) the historical development of scientific ideas underlying both the birth of general relativity and its subsequent evolution. The book is divided in two volumes. Volume One is dedicated to the development of the theory and basic physical applications. It guides the reader from the foundation of special relativity to Einstein field equations, illustrating some basic applications in astrophysics. A detailed account of the historical and conceptual development of the theory is combined with the presentation of its mathematical foundations. Differe...
Waerden, B
1996-01-01
From the reviews: "... Federer's timely and beautiful book indeed fills the need for a comprehensive treatise on geometric measure theory, and his detailed exposition leads from the foundations of the theory to the most recent discoveries. ... The author writes with a distinctive style which is both natural and powerfully economical in treating a complicated subject. This book is a major treatise in mathematics and is essential in the working library of the modern analyst." Bulletin of the London Mathematical Society.
Geometric theory of information
2014-01-01
This book brings together geometric tools and their applications for Information analysis. It collects current and many uses of in the interdisciplinary fields of Information Geometry Manifolds in Advanced Signal, Image & Video Processing, Complex Data Modeling and Analysis, Information Ranking and Retrieval, Coding, Cognitive Systems, Optimal Control, Statistics on Manifolds, Machine Learning, Speech/sound recognition, and natural language treatment which are also substantially relevant for the industry.
Geometrically Consistent Mesh Modification
Bonito, A.
2010-01-01
A new paradigm of adaptivity is to execute refinement, coarsening, and smoothing of meshes on manifolds with incomplete information about their geometry and yet preserve position and curvature accuracy. We refer to this collectively as geometrically consistent (GC) mesh modification. We discuss the concept of discrete GC, show the failure of naive approaches, and propose and analyze a simple algorithm that is GC and accuracy preserving. © 2010 Society for Industrial and Applied Mathematics.
Formation of N2(A3Σ+u , v = 0–3)metastable species in decaying nitrogen streamer
Czech Academy of Sciences Publication Activity Database
Šimek, Milan; Ambrico, P. F.; Prukner, Václav
2013-01-01
Roč. 46, č. 48 (2013), s. 485205-485205 ISSN 0022-3727 R&D Projects: GA ČR(CZ) GAP205/12/1709 Institutional support: RVO:61389021 Keywords : nitrogen metastable * streamer * optical diagnostics * laser-induced fluorescence * LIF Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.521, year: 2013 http://iopscience.iop.org/0022-3727/46/48/485205/pdf/0022-3727_46_48_485205.pdf
Studies in geometric quantization
International Nuclear Information System (INIS)
Tuynman, G.M.
1988-01-01
This thesis contains five chapters, of which the first, entitled 'What is prequantization, and what is geometric quantization?', is meant as an introduction to geometric quantization for the non-specialist. The second chapter, entitled 'Central extensions and physics' deals with the notion of central extensions of manifolds and elaborates and proves the statements made in the first chapter. Central extensions of manifolds occur in physics as the freedom of a phase factor in the quantum mechanical state vector, as the phase factor in the prequantization process of classical mechanics and it appears in mathematics when studying central extension of Lie groups. In this chapter the connection between these central extensions is investigated and a remarkable similarity between classical and quantum mechanics is shown. In chapter three a classical model is given for the hydrogen atom including spin-orbit and spin-spin interaction. The method of geometric quantization is applied to this model and the results are discussed. In the final chapters (4 and 5) an explicit method to calculate the operators corresponding to classical observables is given when the phase space is a Kaehler manifold. The obtained formula are then used to quantise symplectic manifolds which are irreducible hermitian symmetric spaces and the results are compared with other quantization procedures applied to these manifolds (in particular to Berezin's quantization). 91 refs.; 3 tabs
Perspective: Geometrically frustrated assemblies
Grason, Gregory M.
2016-09-01
This perspective will overview an emerging paradigm for self-organized soft materials, geometrically frustrated assemblies, where interactions between self-assembling elements (e.g., particles, macromolecules, proteins) favor local packing motifs that are incompatible with uniform global order in the assembly. This classification applies to a broad range of material assemblies including self-twisting protein filament bundles, amyloid fibers, chiral smectics and membranes, particle-coated droplets, curved protein shells, and phase-separated lipid vesicles. In assemblies, geometric frustration leads to a host of anomalous structural and thermodynamic properties, including heterogeneous and internally stressed equilibrium structures, self-limiting assembly, and topological defects in the equilibrium assembly structures. The purpose of this perspective is to (1) highlight the unifying principles and consequences of geometric frustration in soft matter assemblies; (2) classify the known distinct modes of frustration and review corresponding experimental examples; and (3) describe outstanding questions not yet addressed about the unique properties and behaviors of this broad class of systems.
Geometric diffusion of quantum trajectories
Yang, Fan; Liu, Ren-Bao
2015-07-01
A quantum object can acquire a geometric phase (such as Berry phases and Aharonov-Bohm phases) when evolving along a path in a parameter space with non-trivial gauge structures. Inherent to quantum evolutions of wavepackets, quantum diffusion occurs along quantum trajectories. Here we show that quantum diffusion can also be geometric as characterized by the imaginary part of a geometric phase. The geometric quantum diffusion results from interference between different instantaneous eigenstate pathways which have different geometric phases during the adiabatic evolution. As a specific example, we study the quantum trajectories of optically excited electron-hole pairs in time-reversal symmetric insulators, driven by an elliptically polarized terahertz field. The imaginary geometric phase manifests itself as elliptical polarization in the terahertz sideband generation. The geometric quantum diffusion adds a new dimension to geometric phases and may have applications in many fields of physics, e.g., transport in topological insulators and novel electro-optical effects.
Isomerization of metastable amine radical cations by dissociation-recombination
DEFF Research Database (Denmark)
Pedersen, Anders Holmen; Nielsen, Christian Benedikt; Bojesen, Gustav
2015-01-01
The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier...
Metastable defect response in CZTSSe from admittance spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Koeper, Mark J.; Hages, Charles J.; Li, Jian V.; Levi, Dean; Agrawal, Rakesh
2017-10-02
Admittance spectroscopy is a useful tool used to study defects in semiconductor materials. However, metastable defect responses in non-ideal semiconductors can greatly impact the measurement and therefore the interpretation of results. Here, admittance spectroscopy was performed on Cu2ZnSn(S,Se)4 where metastable defect response is illustrated due to the trapping of injected carriers into a deep defect state. To investigate the metastable response, admittance measurements were performed under electrically and optically relaxed conditions in comparison to a device following a low level carrier-injection pretreatment. The relaxed measurement demonstrates a single capacitance signature while two capacitance signatures are observed for the device measured following carrier-injection. The deeper level signature, typically reported for kesterites, is activated by charge trapping following carrier injection. Both signatures are attributed to bulk level defects. The significant metastable response observed on kesterites due to charge trapping obscures accurate interpretation of defect levels from admittance spectroscopy and indicates that great care must be taken when performing and interpreting this measurement on non-ideal devices.
Atmospheric instability as a loss of a metastable equilibrium
Kornyushin, Yuri
2007-01-01
General thermodynamic theory of metastable states is used in this short note to try to understand better atmospheric instabilities. It is shown that not only cooling of a cloud can lead to rain, but heating also, especially when there are charged water drops in a cloud (in this case we have rain with lightning). The influence of the global warming on weather is discussed.
Metastability thresholds for anisotropic bootstrap percolation in three dimensions
Van Enter, A.C.D.; Fey, A.
2012-01-01
In this paper we analyze several anisotropic bootstrap percolation models in three dimensions. We present the order of magnitude for the metastability thresholds for a fairly general class of models. In our proofs, we use an adaptation of the technique of dimensional reduction. We find that the
Metastability Thresholds for Anisotropic Bootstrap Percolation in Three Dimensions
Van Enter, A.C.D.; Fey, A.
2012-01-01
In this paper we analyze several anisotropic bootstrap percolation models in three dimensions. We present the order of magnitude for the metastability thresholds for a fairly general class of models. In our proofs, we use an adaptation of the technique of dimensional reduction. We find that the
Metastability Thresholds for Anisotropic Bootstrap Percolation in Three Dimensions
Enter, Aernout C.D. van; Fey, Anne
In this paper we analyze several anisotropic bootstrap percolation models in three dimensions. We present the order of magnitude for the metastability thresholds for a fairly general class of models. In our proofs, we use an adaptation of the technique of dimensional reduction. We find that the
Tumor ocular metastásico Metastatic ocular tumor
Directory of Open Access Journals (Sweden)
Martha G Domínguez Expósito
2004-06-01
Full Text Available El carcinoma metastásico del ojo es considerado la neoplasia maligna que más frecuente se encuentra de forma intraocular. Solo cerca del 10 % de las personas que tienen una o más lesiones metastásicas intraoculares son detectadas clínicamente antes de la muerte. A menudo, el carcinoma metastásico ocular es diagnosticado por el oftalmólogo ante la presencia de síntomas oculares. Las lesiones están localizadas con preferencia en coroides. Nos motivo a realizar la presentación de este caso la presencia de lesiones intraoculares múltiples tumorales metastásicos en un paciente cuyo síntoma de presentación fue la disminución de la agudeza visualThe eye metastatic carcinoma is considered the most frequently found intraocular malignant neoplasia. Only 10 % of the persons with one or more metastatic intraocular injuries are clinically detected before death. The metastatic ocular carcinoma is often diagnosed by the ophthalmologist in the presence of ocular symptoms. The injuries are preferably located in the choroid. The appearance of multiple metastatic intraaocular tumoral injuries in a patient whose chief complaint was the reduction of visual acuity motivated us to presente this case
Colour chemistry - a study of metastable multiquark molecules
International Nuclear Information System (INIS)
Chan, H.-M.; Fukugita, M.; Hansson, T.H.; Hoffman, H.J.; Konishi, K.; Hoegaasen, H.; Tsou, S.T.
1978-03-01
A framework is proposed for treating metastable multiquark states in general, borrowing some of the chemist's concepts and terminology. Lists of 'ions' and 'bonds' are are compiled which allow one in principle to construct models of complex 'molecules' and to predict their masses and decays. (author)
Metastable atom probe for measuring electron beam density profiles
Lockhart, J. M.; Zorn, J. C.
1972-01-01
Metastable atom probe was developed for measuring current density in electron beam as function of two arbitrary coordinates, with spatial resolution better than 0.5 mm. Probe shows effects of space charge, magnetic fields, and other factors which influence electron current density, but operates with such low beam densities that introduced perturbation is very small.
235U isotope enrichment in the metastable levels of UI
International Nuclear Information System (INIS)
Gagne, J.M.; Demers, Y.; Dreze, C.; Pianarosa, P.
1983-01-01
We have used optical pumping to produce a substantial 235 U enrichment in the metastable levels of UI in the discharge afterglow of a hollow-cathode vapor generator. The measured isotope-enrichment factor for the level at 3800 cm -1 is approximately 20
Metastability in spin polarised Fermi gases and quasiparticle decays
DEFF Research Database (Denmark)
Sadeghzadeh, Kayvan; Bruun, Georg; Lobo, Carlos
2011-01-01
We investigate the metastability associated with the first order transition from normal to superfluid phases in the phase diagram of two-component polarised Fermi gases.We begin by detailing the dominant decay processes of single quasiparticles.Having determined the momentum thresholds of each pr...
Tractable Quantification of Metastability for Robust Bipedal Locomotion
2015-06-01
Mathematics GPA 4.0/4.0 2007-2011 Sabanci University, Istanbul B.S. in Mechatronics Engineering Minor in Mathematics GPA 3.88/4.0 Major GPA: 3.96/4.00...on Mechatronics (ICM), pages 997-1002, April 2011. viii Abstract Tractable Quantification of Metastability for Robust Bipedal Locomotion by Cenk Oguz
Tuning the morphology of metastable MnS films by simple chemical bath deposition technique
Energy Technology Data Exchange (ETDEWEB)
Dhandayuthapani, T. [Directorate of Distance Education, Alagappa University, Karaikudi 630004 (India); Girish, M. [Department of Physics, Alagappa University, Karaikudi 630004 (India); Sivakumar, R., E-mail: krsivakumar1979@yahoo.com [Directorate of Distance Education, Alagappa University, Karaikudi 630004 (India); Sanjeeviraja, C. [Department of Physics, Alagappa Chettiar College of Engineering and Technology, Karaikudi 630004 (India); Gopalakrishnan, R. [Department of Physics, Anna University, Chennai 600025 (India)
2015-10-30
Graphical abstract: - Highlights: • MnS films with diverse morphological features were prepared without any complexing agent. • The change in morphology of MnS films may be due to the “oriented aggregation”. • The dual role (as sulfur source and structure directing agent) of thiourea was observed. • Sulfur source concentration induced enhancement in the crystallization of films. - Abstract: In the present investigation, we have prepared the spherical particles, almond-like, and cauliflower-like morphological structures of metastable MnS films on glass substrate by chemical bath deposition technique at low temperature without using any complexing or chelating agent. The morphological change of MnS films with molar ratio may be due to the oriented aggregation of adjacent particles. The compositional purity of deposited film was confirmed by the EDAX study. X-ray diffraction and micro-Raman studies confirm the sulfur source concentration induced enhancement in the crystallization of films with metastable MnS phase (zinc-blende β-MnS, and wurtzite γ-MnS). The shift in PL emission peak with molar ratio may be due to the change in optical energy band gap of the MnS, which was further confirmed by the optical absorbance study. The paramagnetic behavior of the sample was confirmed by the M–H plot.
The Geometric Phase of Stock Trading.
Altafini, Claudio
2016-01-01
Geometric phases describe how in a continuous-time dynamical system the displacement of a variable (called phase variable) can be related to other variables (shape variables) undergoing a cyclic motion, according to an area rule. The aim of this paper is to show that geometric phases can exist also for discrete-time systems, and even when the cycles in shape space have zero area. A context in which this principle can be applied is stock trading. A zero-area cycle in shape space represents the type of trading operations normally carried out by high-frequency traders (entering and exiting a position on a fast time-scale), while the phase variable represents the cash balance of a trader. Under the assumption that trading impacts stock prices, even zero-area cyclic trading operations can induce geometric phases, i.e., profits or losses, without affecting the stock quote.
A metastable helium trap for atomic collision physics
International Nuclear Information System (INIS)
Colla, M.; Gulley, R.; Uhlmann, L.; Hoogerland, M.D.; Baldwin, K.G.H.; Buckman, S.J.
1999-01-01
Full text: Metastable helium in the 2 3 S state is an important species for atom optics and atomic collision physics. Because of its large internal energy (20eV), long lifetime (∼8000s) and large collision cross section for a range of processes, metastable helium plays an important role in atmospheric physics, plasma discharges and gas laser physics. We have embarked on a program of studies on atom-atom and electron-atom collision processes involving cold metastable helium. We confine metastable helium atoms in a magneto-optic trap (MOT), which is loaded by a transversely collimated, slowed and 2-D focussed atomic beam. We employ diode laser tuned to the 1083 nm (2 3 S 1 - 2 3 P2 1 ) transition to generate laser cooling forces in both the loading beam and the trap. Approximately 10 million helium atoms are trapped at temperatures of ∼ 1mK. We use phase modulation spectroscopy to measure the trapped atomic density. The cold, trapped atoms can collide to produce either atomic He + or molecular He 2 + ions by Penning Ionisation (PI) or Associative Ionisation (AI). The rate of formation of these ions is dependant upon the detuning of the trapping laser from resonance. A further laser can be used to connect the 2 3 S 1 state to another higher lying excited state, and variation of the probe laser detuning used to measure interatomic collision potential. Electron-atom collision processes are studied using a monochromatic electron beam with a well defined spatial current distribution. The total trap loss due to electron collisions is measured as a function of electron energy. Results will be presented for these atomic collision physics measurements involving cold, trapped metastable helium atoms. Copyright (1999) Australian Optical Society
Morphing of geometric composites via residual swelling.
Pezzulla, Matteo; Shillig, Steven A; Nardinocchi, Paola; Holmes, Douglas P
2015-08-07
Understanding and controlling the shape of thin, soft objects has been the focus of significant research efforts among physicists, biologists, and engineers in the last decade. These studies aim to utilize advanced materials in novel, adaptive ways such as fabricating smart actuators or mimicking living tissues. Here, we present the controlled growth-like morphing of 2D sheets into 3D shapes by preparing geometric composite structures that deform by residual swelling. The morphing of these geometric composites is dictated by both swelling and geometry, with diffusion controlling the swelling-induced actuation, and geometric confinement dictating the structure's deformed shape. Building on a simple mechanical analog, we present an analytical model that quantitatively describes how the Gaussian and mean curvatures of a thin disk are affected by the interplay among geometry, mechanics, and swelling. This model is in excellent agreement with our experiments and numerics. We show that the dynamics of residual swelling is dictated by a competition between two characteristic diffusive length scales governed by geometry. Our results provide the first 2D analog of Timoshenko's classical formula for the thermal bending of bimetallic beams - our generalization explains how the Gaussian curvature of a 2D geometric composite is affected by geometry and elasticity. The understanding conferred by these results suggests that the controlled shaping of geometric composites may provide a simple complement to traditional manufacturing techniques.
Corrochano, Eduardo Bayro
2010-01-01
This book presents contributions from a global selection of experts in the field. This useful text offers new insights and solutions for the development of theorems, algorithms and advanced methods for real-time applications across a range of disciplines. Written in an accessible style, the discussion of all applications is enhanced by the inclusion of numerous examples, figures and experimental analysis. Features: provides a thorough discussion of several tasks for image processing, pattern recognition, computer vision, robotics and computer graphics using the geometric algebra framework; int
Geometric correlations and multifractals
International Nuclear Information System (INIS)
Amritkar, R.E.
1991-07-01
There are many situations where the usual statistical methods are not adequate to characterize correlations in the system. To characterize such situations we introduce mutual correlation dimensions which describe geometric correlations in the system. These dimensions allow us to distinguish between variables which are perfectly correlated with or without a phase lag, variables which are uncorrelated and variables which are partially correlated. We demonstrate the utility of our formalism by considering two examples from dynamical systems. The first example is about the loss of memory in chaotic signals and describes auto-correlations while the second example is about synchronization of chaotic signals and describes cross-correlations. (author). 19 refs, 6 figs
Ambrosetti, Antonio; Malchiodi, Andrea
2009-01-01
This volume contains lecture notes on some topics in geometric analysis, a growing mathematical subject which uses analytical techniques, mostly of partial differential equations, to treat problems in differential geometry and mathematical physics. The presentation of the material should be rather accessible to non-experts in the field, since the presentation is didactic in nature. The reader will be provided with a survey containing some of the most exciting topics in the field, with a series of techniques used to treat such problems.
Suh, Ga-Young; Choi, Gilwoo; Draney, Mary T; Herfkens, Robert J; Dalman, Ronald L; Cheng, Christopher P
2013-12-01
To quantify renal artery deformation due to respiration using magnetic resonance (MR) image-based geometric analysis. Five males were imaged with contrast-enhanced MR angiography during inspiratory and expiratory breath-holds. From 3D models of the abdominal aorta, left and right renal arteries (LRA and RRA), we quantified branching angle, curvature, peak curve angle, axial length, and locations of branch points. With expiration, maximum curvature changes were 0.054 ± 0.025 mm(-1) (P < 0.01), and curve angle at the most proximal curvature peak increased by 8.0 ± 4.5° (P < 0.05) in the LRA. Changes in maximum curvature and curve angles were not significant in the RRA. The first renal bifurcation point translated superiorly and posteriorly by 9.7 ± 3.6 mm (P < 0.005) and 3.5 ± 2.1 mm (P < 0.05), respectively, in the LRA, and 10.8 ± 6.1 mm (P < 0.05) and 3.6 ± 2.5 mm (P < 0.05), respectively, in the RRA. Changes in branching angle, axial length, and renal ostia locations were not significant. The LRA and RRA deformed and translated significantly. Greater deformation of the LRA as compared to the RRA may be due to asymmetric anatomy and mechanical support by the inferior vena cava. The presented methodology can extend to quantification of deformation of diseased and stented arteries to help renal artery implant development. Copyright © 2013 Wiley Periodicals, Inc.
GEOMETRIC PROGRESSIONS ON ELLIPTIC CURVES.
Ciss, Abdoul Aziz; Moody, Dustin
2017-01-01
In this paper, we look at long geometric progressions on different model of elliptic curves, namely Weierstrass curves, Edwards and twisted Edwards curves, Huff curves and general quartics curves. By a geometric progression on an elliptic curve, we mean the existence of rational points on the curve whose x -coordinate (or y -coordinate) are in geometric progression. We find infinite families of twisted Edwards curves and Huff curves with geometric progressions of length 5, an infinite family of Weierstrass curves with 8 term progressions, as well as infinite families of quartic curves containing 10-term geometric progressions.
Tuning the morphology of metastable MnS films by simple chemical bath deposition technique
Dhandayuthapani, T.; Girish, M.; Sivakumar, R.; Sanjeeviraja, C.; Gopalakrishnan, R.
2015-10-01
In the present investigation, we have prepared the spherical particles, almond-like, and cauliflower-like morphological structures of metastable MnS films on glass substrate by chemical bath deposition technique at low temperature without using any complexing or chelating agent. The morphological change of MnS films with molar ratio may be due to the oriented aggregation of adjacent particles. The compositional purity of deposited film was confirmed by the EDAX study. X-ray diffraction and micro-Raman studies confirm the sulfur source concentration induced enhancement in the crystallization of films with metastable MnS phase (zinc-blende β-MnS, and wurtzite γ-MnS). The shift in PL emission peak with molar ratio may be due to the change in optical energy band gap of the MnS, which was further confirmed by the optical absorbance study. The paramagnetic behavior of the sample was confirmed by the M-H plot.
Evidence of existence of metastable SrFe{sub 12}O{sub 19} nanoparticles
Energy Technology Data Exchange (ETDEWEB)
Martinez Garcia, R., E-mail: rmartinez@fi.uba.ar [Laboratorio de Solidos Amorfos, INTECIN, Facultad de Ingenieria, Universidad de Buenos Aires, Paseo Colon 850, C1063ACV, Buenos Aires (Argentina); Bilovol, V.; Socolovsky, L.M. [Laboratorio de Solidos Amorfos, INTECIN, Facultad de Ingenieria, Universidad de Buenos Aires, Paseo Colon 850, C1063ACV, Buenos Aires (Argentina); Pirota, K. [Laboratorio de Materiais e Baixas Temperaturas, Instituto de Fisica ' Gleb Wataghin' , UNICAMP, 13083-970 Campinas, SP (Brazil)
2011-12-15
The existence of metastable hexaferrite is reported. Synthesis of strontium hexaferrite, SrFe{sub 12}O{sub 19}, at 400 deg. C was realized under controlled oxygen atmosphere. Such technique allows obtaining of SrFe{sub 12}O{sub 19} at lower temperatures than those by traditional methods (above 800 deg. C). Phase transformation occurred during a measurement of magnetization vs. temperature (heating up to 625 deg. C). The heat treatment induces a change from SrFe{sub 12}O{sub 19} to {gamma}-Fe{sub 2}O{sub 3} (as the main phase), and SrFeO{sub 2.74} to Sr{sub 2}Fe{sub 2}O{sub 5}. Together with these phase transformations, an increment in the amount of SrCO{sub 3} is detected. Magnetic study of the samples, before and after the heating, supports the structural analysis conclusions. - Highlights: > SrFe{sub 12}O{sub 19}, as the majority phase, is obtained by heat treatment at 400 deg. C under oxygen flux. > Hexaferrite nanoparticles have crystalline imperfections that make it an unstable phase. > Together with these phase transformations, an increment in the amount of SrCO{sub 3} is detected. > To our knowledge, this is the first report of the existence of metastable SrFe{sub 12}O{sub 19}.
Influences of depletion potential on vapor-liquid critical point metastability
Directory of Open Access Journals (Sweden)
S. Zhou
2016-04-01
Full Text Available Phase behavior of a neutral colloid dispersion is investigated based on an improved Asakura-Oosawa (AO model. Several observations are made: (i an increase of solvent fugacity can enlarge the fluid-solid (FS coexistence region, and this makes fugacity become a powerful factor in tuning a vapor-liquid transition (VLT critical point metastability. (ii A reducing of size ratio of the solvent versus colloid particle can enlarge the FS coexistence region as well as lower the VLT critical temperature, and a combination of the two effects makes the size ratio an extremely powerful factor adjusting the VLT critical point metastability. (iii Existence of a long-range attraction term in the effective colloid potential is not a necessary condition for occurrence of a vapor-solid transition (VST, and short-ranged oscillatory depletion potential also can induce the VST over an even broader temperature range. (iv Sensitivity of the freezing line on the size ratio is disclosed, and one can make use of the sensitivity to prepare mono-disperse colloid of well-controlled diameter by following a fractionated crystallization scheme; moreover, broadening of the FST coexistence region by raising the solvent fugacity and/or lowering the size ratio has important implication for crystallization process.
Metastable phase formation in ion-irradiated nickel-aluminum alloys
International Nuclear Information System (INIS)
Eridon, J.M.
1986-01-01
Phase transformations induced by ion beam mixing of nickel-aluminum alloys with 500-keV krypton ions were investigated over a range of temperatures (80 K to 300K), composition (NiAl 3 , NiAl, Ni 1 Al), initial structures (both nickel-aluminum layers and ordered intermetallic compounds), and doses (ranging from 2 x 10 14 cm -2 to 5 x 10 16 cm -2 ). Samples were formed by alternate evaporation of layers of nickel and aluminum in high vacuum onto copper grids. These samples were check for purity with energy dispersive-x-ray spectroscopy, electron energy-loss spectroscopy, and Rutherford backscattering spectrometry. A portion of these samples was annealed to form the intermetallic compounds appropriate to the given composition. Irradiations were performed at both room temperature (300 K) and 80 K using the 2-MV ion accelerator at Argonne National Laboratory. Phase transformations were observed during both in-situ irradiations in the High Voltage Electron Microscopy at Argonne and also in subsequent electron-diffraction analysis of an array of samples irradiated in a target chamber. Metastable phases formed include disordered crystalline structures at composition s of 25% and 50% aluminum, an amorphous structure at 75% aluminum, and a hexagonal closed-packed structure formed at 25% aluminum. These metastable states were all converted to the stable intermetallic compounds through annealing treatments
The metastable state of nucleocapsids of enveloped viruses as probed by high hydrostatic pressure.
Gaspar, L P; Terezan, A F; Pinheiro, A S; Foguel, D; Rebello, M A; Silva, J L
2001-03-09
Enveloped viruses fuse their membranes with cellular membranes to transfer their genomes into cells at the beginning of infection. What is not clear, however, is the role of the envelope (lipid bilayer and glycoproteins) in the stability of the viral particle. To address this question, we compared the stability between enveloped and nucleocapsid particles of the alphavirus Mayaro using hydrostatic pressure and urea. The effects were monitored by intrinsic fluorescence, light scattering, and binding of fluorescent dyes, including bis(8-anilinonaphthalene-1-sulfonate) and ethidium bromide. Pressure caused a drastic dissociation of the nucleocapsids as determined by tryptophan fluorescence, light scattering, and gel filtration chromatography. Pressure-induced dissociation of the nucleocapsids was poorly reversible. In contrast, when the envelope was present, pressure effects were much less marked and were highly reversible. Binding of ethidium bromide occurred when nucleocapsids were dissociated under pressure, indicating exposure of the nucleic acid, whereas enveloped particles underwent no changes. Overall, our results demonstrate that removal of the envelope with the glycoproteins leads the particle to a metastable state and, during infection, may serve as the trigger for disassembly and delivery of the genome. The envelope acts as a "Trojan horse," gaining entry into the host cell to allow release of a metastable nucleocapsid prone to disassembly.
Energy Technology Data Exchange (ETDEWEB)
Goldberg, P.W.
1993-04-01
In this paper we consider the problem of learning the positions of spheres in metric spaces, given as data randomly drawn points classified according to whether they are internal or external to an unknown sphere. The particular metrics under consideration are geometrical shape metrics, and the results are intended to be applicable to the problem of learning to identify a shape from related shapes classified according to whether they resemble it visually. While it is typically NP-hard to locate a central point for a hypothesis sphere, we find that it is however often possible to obtain a non-spherical hypothesis which can accurately predict whether further random points lie within the unknown sphere. We exhibit algorithms which achieve this, and in the process indicate useful general techniques for computational learning. Finally we exhibit a natural shape metric and show that it defines a class of spheres not predictable in this sense, subject to standard cryptographic assumptions.
Geometrical frustration yields fiber formation in self-assembly.
Lenz, Martin; Witten, Thomas A
2017-11-01
Controlling the self-assembly of supramolecular structures is vital for living cells, and a central challenge for engineering at the nano- and microscales [1, 2]. Nevertheless, even particles without optimized shapes can robustly form well-defined morphologies. This is the case in numerous medical conditions where normally soluble proteins aggregate into fibers [3, 4]. Beyond the diversity of molecular mechanisms involved [5, 6], we propose that fibers generically arise from the aggregation of irregular particles with short-range interactions. Using a minimal model of ill-fitting, sticky particles, we demonstrate robust fiber formation for a variety of particle shapes and aggregation conditions. Geometrical frustration plays a crucial role in this process, and accounts for the range of parameters in which fibers form as well as for their metastable character.
Geometrical frustration yields fibre formation in self-assembly
Lenz, Martin; Witten, Thomas A.
2017-11-01
Controlling the self-assembly of supramolecular structures is vital for living cells, and a central challenge for engineering at the nano- and microscales. Nevertheless, even particles without optimized shapes can robustly form well-defined morphologies. This is the case in numerous medical conditions where normally soluble proteins aggregate into fibres. Beyond the diversity of molecular mechanisms involved, we propose that fibres generically arise from the aggregation of irregular particles with short-range interactions. Using a minimal model of ill-fitting, sticky particles, we demonstrate robust fibre formation for a variety of particle shapes and aggregation conditions. Geometrical frustration plays a crucial role in this process, and accounts for the range of parameters in which fibres form as well as for their metastable character.
Stefanović, I.; Sadeghi, N.; Winter, J.; Sikimić, B.
2017-06-01
Different diagnostic techniques are used to monitor the dynamics of electrons and Ar*(1s5) metastable atoms in the active plasma phase and in the afterglow of a capacitively coupled radio-frequency (RF) discharge operated in different gas mixtures and at different input powers. Diode laser absorption at 772.38 nm is used to measure the time resolved density of Ar*(1s5) atoms in either continuous-wave mode or pulsed RF discharges with 100 Hz pulsing frequency. Simultaneously, microwave interferometry recorded the time dependence of the electron density. Different plasma conditions, namely: (1) pure argon, (2) argon +5.9% acetylene before nanoparticle formation, (3) argon +5.9% acetylene after dust particles have been formed and (4) argon with dust particles remaining in the plasma volume but without acetylene are studied. The measured steady-state Ar*(1s5) density in the middle of the reactor is several times larger in the dusty argon plasma than in the pure argon discharge for the same discharge powers. At the same time, the electron density is several times less in the dusty plasma. These changes are caused by dust formation: the electric field in the bulk plasma is enhanced and thus consequently the electron temperature increases. Laser induced fluorescence (LIF) is used to measure the time and space resolved Ar*(1s5) axial distribution. In the pure argon discharge, the axial Ar*(1s5) metastable distribution has a characteristic saddle-like shape with maxima in the region of the sheaths. With dust particles inside, the axial distribution changes dramatically with the maximum at the discharge mid-plane, revealing an α-γ‧ transition. The spatial distribution and absolute density of metastable atoms are influenced by the formation of a void in the cloud of nanoparticles. Depending on the size of the void, the Ar*(1s5) density reduction inside the void is between 30% and 50%. The high Ar*(1s5) metastable density in the dusty plasma afterglow strongly influences
Metastable state en route to traveling-wave synchronization state
Park, Jinha; Kahng, B.
2018-02-01
The Kuramoto model with mixed signs of couplings is known to produce a traveling-wave synchronized state. Here, we consider an abrupt synchronization transition from the incoherent state to the traveling-wave state through a long-lasting metastable state with large fluctuations. Our explanation of the metastability is that the dynamic flow remains within a limited region of phase space and circulates through a few active states bounded by saddle and stable fixed points. This complex flow generates a long-lasting critical behavior, a signature of a hybrid phase transition. We show that the long-lasting period can be controlled by varying the density of inhibitory/excitatory interactions. We discuss a potential application of this transition behavior to the recovery process of human consciousness.
Block Copolymer Metastability: Scientific Nightmare or Engineering Dream?
Bates, Frank S.
1997-03-01
Most experimental studies and almost all theories that deal with block copolymers, or mixtures of block copolymers and homopolymers, have been designed from an equilibrium perspective. Yet a myriad of factors conspire to retard approach to equilibrium in these systems, including: subtle features in the free energy surface that are controlled by ordered state symmetry; a coupling between microphase separation and entanglement dynamics; complex molecular architectures such as multiblock, starblock, and miktoarm. Even unentangled low molecular weight diblock copolymers, the simplest and dynamically least encumbered materials, exhibit long-lived metastable states that confound attempts to validate equilibrium theories. However, this apparent dilemma can be exploited through clever processing strategies. This lecture will address two opposing consequences of block copolymer metastability. The first is a potential nightmare: Can we ever establish universal block copolymer phase diagrams? The second is the stuff of dreams: Self-assembled thermoset nanocomposites.
Accumulation of chromium metastable atoms into an optical trap
Chicireanu, R.; Beaufils, Q.; Pouderous, A.; Laburthe-Tolra, B.; Maréchal, É.; Vernac, L.; Keller, J.-C.; Gorceix, O.
2007-11-01
We report the fast accumulation of a large number of metastable 52Cr atoms in a mixed trap, formed by the superposition of a strongly confining optical trap and a quadrupolar magnetic trap. The steady state is reached after about 400 ms, providing a cloud of more than one million metastable atoms at a temperature of about 100 μK, with a peak density of 1018 atoms m-3. We have optimized the loading procedure, and measured the light shift of the ^5D4 state by analyzing how the trapped atoms respond to a parametric excitation. We compare this result to a theoretical evaluation based on the available spectroscopic data for chromium atoms.
Planktic foraminifera form their shells via metastable carbonate phases.
Jacob, D E; Wirth, R; Agbaje, O B A; Branson, O; Eggins, S M
2017-11-02
The calcium carbonate shells of planktic foraminifera provide our most valuable geochemical archive of ocean surface conditions and climate spanning the last 100 million years, and play an important role in the ocean carbon cycle. These shells are preserved in marine sediments as calcite, the stable polymorph of calcium carbonate. Here, we show that shells of living planktic foraminifers Orbulina universa and Neogloboquadrina dutertrei originally form from the unstable calcium carbonate polymorph vaterite, implying a non-classical crystallisation pathway involving metastable phases that transform ultimately to calcite. The current understanding of how planktic foraminifer shells record climate, and how they will fare in a future high-CO 2 world is underpinned by analogy to the precipitation and dissolution of inorganic calcite. Our findings require a re-evaluation of this paradigm to consider the formation and transformation of metastable phases, which could exert an influence on the geochemistry and solubility of the biomineral calcite.
Equilibrium and metastable nanoscale domains in ultrathin magnets
Czech Academy of Sciences Publication Activity Database
Kisielewski, M.; Maziewski, A.; Polyakova, T.; Zablotskyy, Vitaliy A.
2006-01-01
Roč. 3, č. 5 (2006), s. 1333-1338 ISSN 1610-1634. [International Conference on Nanoscale Magnetism ICNM-2005. Istanbul, 03.07.2005-07.07.2005] Grant - others:Polish State Committee for Sci. Research(PL) 4 T11B 006 24; Marie Curie Fondation(PL) NANOMAG-LAB, N 2004-003177 Institutional research plan: CEZ:AV0Z10100520 Keywords : ultrathin films * metastable domains * thermodynamics. Subject RIV: BM - Solid Matter Physics ; Magnetism
Decadal variability and metastability in the Southern Hemisphere
O'Kane, Terence; Risbey, James; Franzke, Christian; Horenko, Illia; Monselesan, Didier
2014-05-01
An examination of systematic changes in the metastability of the southern hemisphere 500hPa circulation is performed using both cluster analysis techniques and split flow blocking indices. The cluster methodology is a purely data-driven approach for parametrisation whereby a multi-scale approximation to non-stationary dynamical processes is achieved through optimal sequences of locally stationary fast Vector Auto-Regressive Factor (VARX) processes and some slow (or persistent) hidden process switching between them. Comparison is made with blocking indices commonly used in weather forecasting and climate analysis to identify dynamically relevant metastable regimes in the 500hPa circulation in both reanalysis and AMIP model data sets. Our analysis characterises the metastable regime in both reanalysis and model data sets prior to 1978 as positive and negative phases of a hemispheric mid-latitude blocking state with the Southern Annular Mode (SAM) associated with a transition state. Post 1978, SAM emerges as a true metastable state replacing the negative phase of the hemispheric blocking pattern. The hidden state frequency of occurrences exhibits strong trends. The blocking pattern dominates in the early 1980s then gradually decreases. There is a corresponding increase in the SAM frequency of occurrence. This trend is largely evident in the reanalysis summer and spring but was not evident in the AMIP data set. Non-stationary cluster analysis was then further used to identify the Southern Oceans response to the systematic changes in the mid-latitude atmospheric circulation and identify dynamical regimes associated with subsurface thermocline anomalies which were found to teleconnect the Pacific and Atlantic regions of the Antarctic Circumpolar Current (ACC).
Automatic acquisition and shape analysis of metastable peaks
International Nuclear Information System (INIS)
Maendli, H.; Robbiani, R.; Kuster, Th.; Seibl, J.
1979-01-01
A method for automatic acquisition and evaluation of metastable peaks due to transitions in the first field-free region of a double focussing mass spectrometer is presented. The data are acquired by computer-controlled repetitive scanning of the accelerating voltage and concomitant accumulation, the evaluation made by a mathematical derivatization of the resulting curve. Examples for application of the method are given. (Auth.)
Investigations of Shock Wave Synthesis of Metastable Compounds.
1997-01-01
Institute of Chemical Physics in Chernogolovka, Russian Academy of Science 8. 705 Chernogolovka, Moscow Region, 142432, Russia Phone: 7-096-5171930 Fax...materials etc. The development of metastable state physics and chemistry is intimately connected with the elaboration of special production methods...of Sci., Inorgan. mat., 19968, V. 22, No 6, p. 966 5. Nekrasov, B.V. Principles of General Chemestry , Moscow, "Khimiya", 1979, V. 2, p. 309 6. Dremin
Modeling of diode pumped metastable rare gas lasers.
Yang, Zining; Yu, Guangqi; Wang, Hongyan; Lu, Qisheng; Xu, Xiaojun
2015-06-01
As a new kind of optically pumped gaseous lasers, diode pumped metastable rare gas lasers (OPRGLs) show potential in high power operation. In this paper, a multi-level rate equation based model of OPRGL is established. A qualitative agreement between simulation and Rawlins et al.'s experimental result shows the validity of the model. The key parameters' influences and energy distribution characteristics are theoretically studied, which is useful for the optimized design of high efficient OPRGLs.
Metastable states in NO2+ probed with Auger spectroscopy
Czech Academy of Sciences Publication Activity Database
Püttner, R.; Sekushin, V.; Fukuzawa, H.; Uhlíková, T.; Špirko, Vladimír; Asahina, T.; Kuze, N.; Kato, H.; Hoshino, M.; Tanaka, H.; Thomas, T. D.; Kukk, E.; Tamenori, Y.; Kaindl, G.; Ueda, K.
2011-01-01
Roč. 13, č. 41 (2011), s. 18436-18446 ISSN 1463-9076 Grant - others:GA ČR(CZ) GP203/09/P306; GA AV ČR(CZ) IAA400400504; GA MŠk(CZ) LC06071 Program:IA; LC Institutional research plan: CEZ:AV0Z40550506 Keywords : NO2+metastable states * Auger spectroscopy * vibrational energies Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.573, year: 2011
Trapping metastable chromium atoms in a crossed optical dipole trap
Beaufils, Q.; Chicireanu, R.; Pouderous, A.; Laburthe-Tolra, B.; Maréchal, E.; Vernac, L.; Keller, J.-C.; Gorceix, O.
We report the fast accumulation of up to 1 million 52Cr metastable atoms in a mixed trap formed by the superposition of a quadrupolar magnetic trap and a strongly confining optical trap. The cloud is at a temperature of 100 μK with a peak density of 1018 atoms/m3, which is a promising starting point to reach quantum degeneracy by forced evaporation in an optical trap.
International Nuclear Information System (INIS)
Pacheco, D.J; Sousa e Silva, A.S. de; Monteiro, S.N.
The influence of the martensitic transformation on the process of pulse tension fatigue of a AISI type 316 metastable stainless steel was studied at 25 0 and 196 0 c. The fatigue tests were performed on annealed and cold worked specimens in order to separate the effects of static transformation, dynamic transformation and work hardening. The fatigue limits obtained from the corresponding Wohler curves were compared for the different test conditions. The results showed that the fatigue is not affected by the dynamically induced martensite. On the other hand the static martensite, previously induced, appears to decrease the resistance to fatigue. The reasons for these effects are discussed. (Author) [pt
International Nuclear Information System (INIS)
Lagus, M.E.; Boffard, J.B.; Anderson, L.W.; Lin, C.C.
1996-01-01
Absolute direct cross sections for electron excitation out of the 2 3 S level and into the 3 3 D, 4 3 D, and 3 3 S levels of the helium atom from threshold to 500 eV and into the 3 3 P level over a more limited energy range have been measured using a fast metastable atomic beam target. We produce the metastable atoms via near-resonant charge exchange between a 1.6-keV He + ion beam and Cs vapor. Because this reaction is highly nonresonant with the ground state of helium, the charge-transfer process yields a primarily metastable beam. We use a thermal detector which we calibrate with ions to measure absolutely the neutral beam flux. The atomic beam is crossed by an electron beam, and we collect the resulting fluorescence at right angles to both the electron and atomic beams. We obtain the cross sections for excitation out of the 2 3 S level into the various excited levels by monitoring the emission out of the excited level of interest. copyright 1996 The American Physical Society
Harmonic and geometric analysis
Citti, Giovanna; Pérez, Carlos; Sarti, Alessandro; Zhong, Xiao
2015-01-01
This book presents an expanded version of four series of lectures delivered by the authors at the CRM. Harmonic analysis, understood in a broad sense, has a very wide interplay with partial differential equations and in particular with the theory of quasiconformal mappings and its applications. Some areas in which real analysis has been extremely influential are PDE's and geometric analysis. Their foundations and subsequent developments made extensive use of the Calderón–Zygmund theory, especially the Lp inequalities for Calderón–Zygmund operators (Beurling transform and Riesz transform, among others) and the theory of Muckenhoupt weights. The first chapter is an application of harmonic analysis and the Heisenberg group to understanding human vision, while the second and third chapters cover some of the main topics on linear and multilinear harmonic analysis. The last serves as a comprehensive introduction to a deep result from De Giorgi, Moser and Nash on the regularity of elliptic partial differen...
Fargas, Gemma; Zapata, Ana; Roa, Joan Josep; Sapezanskaia, Ina; Mateo, Antonio
2015-12-01
Reversion treatments are a way to improve the mechanical response of metastable austenitic stainless steels by means of grain refinement. To effectively apply those treatments, the steel must be previously deformed to induce a significant amount of martensitic transformation. In this work, the effect of reversion treatments was studied on a commercial AISI 301LN grade subjected to an industrial cold rolling process, with thickness reductions not higher than 40 pct. Microstructural changes and evolution of both monotonic and cyclic mechanical properties were investigated after cold rolling and upon reversion treatments. Results revealed that the finer austenitic microstructure obtained after reversion leads to an interesting combination of properties, with strong increments in hardness and yield strength, and also fatigue limit improvement, as compared to the initial annealed condition.
Correction for Metastability in the Quantification of PID in Thin-film Module Testing: Preprint
Energy Technology Data Exchange (ETDEWEB)
Hacke, Peter L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Johnston, Steven [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Spataru, Sergiu [Aalborg University
2017-10-01
A fundamental change in the analysis for the accelerated stress testing of thin-film modules is proposed, whereby power changes due to metastability and other effects that may occur due to the thermal history are removed from the power measurement that we obtain as a function of the applied stress factor. The power of reference modules normalized to an initial state - undergoing the same thermal and light- exposure history but without the applied stress factor such as humidity or voltage bias - is subtracted from that of the stressed modules. For better understanding and appropriate application in standardized tests, the method is demonstrated and discussed for potential-induced degradation testing in view of the parallel-occurring but unrelated physical mechanisms that can lead to confounding power changes in the module.
International Nuclear Information System (INIS)
Efremenko, Vasily; Pastukhova, Tatiana; Chabak, Yuliia; Efremenko, Alexey; Shimizu, Kazumichi; Kusumoto, Kenta; Brykov, Michail
2018-01-01
The effect of heat treatment and chromium contents (up to 9.1 wt.%) on the wear resistance of spheroidal carbide cast iron (9.5 wt.% V) was studied using optical and scanning electron microscopy, X-ray diffractometry, dilatometry and three-body abrasive testing. It was found that quenching from 760 C and 920 C improved the alloys' wear resistance compared to the as-cast state due to the formation of metastable austenite transforming into martensite under abrasion. The wear characteristics of alloys studied are 1.6 - 2.3 times higher than that of reference cast iron (12 wt.% V) having stable austenitic matrix. Chromium addition decreases surface damage due to the formation of M_7C_3 carbides, while it reduces wear resistance owing to austenite stabilization to abrasion-induced martensite transformation. The superposition of these factors results in decreasing the alloys' wear behaviour with chromium content increase.
Metastable Phase Separation and Concomitant Solute Redistribution of Liquid Fe-Cu-Sn Ternary Alloy
International Nuclear Information System (INIS)
Xiao-Mei, Zhang; Wei-Li, Wang; Ying, Ruan; Bing-Bo, Wei
2010-01-01
Liquid Fe-Cu-Sn ternary alloys with lower Sn contents are usually assumed to display a peritectic-type solidification process under equilibrium condition. Here we show that liquid Fe 47.5 Cu 47.5 Sn 5 ternary alloy exhibits a metastable immiscibility gap in the undercooling range of 51–329 K (0.19T L ). Macroscopic phase separation occurs once undercooling exceeds 196 K and causes the formation of a floating Fe-rich zone and a descending Cu-rich zone. Solute redistribution induces the depletion of Sn concentration in the Fe-rich zone and its enrichment in the Cu-rich zone. The primary Fe phase grows dendritically and its growth velocity increases with undercooling until the appearance of notable macrosegregation, but will decrease if undercooling further increases beyond 236 K. The microsegregation degrees of both solutes in Fe and Cu phases vary only slightly with undercooling. (condensed matter: structure, mechanical and thermal properties)
International Nuclear Information System (INIS)
Grosse, M.; Kalkhof, D.; Niffenegger, M.
2000-01-01
The microstructural changes in the pre-crack stage of low-cycle fatigue (LCF) damage in austenitic pipework steels have been characterised by neutron and X-ray diffraction. The LCF damage evolution in the meta-stable austenitic steel causes a deformation-induced phase transformation from austenite to martensite. Thresholds exist for the formation of martensite as a function of both the load amplitude and the number of LCF cycles. Magnetic stray field and eddy-current measurements were chosen to transfer the results of material characterisation to an on-line monitoring non destructive testing (NDT) method. The density and distribution of martensite obtained from neutron diffraction experiments were used for the calibration of these methods. Both techniques were able to detect the very low amount of martensite in the different-aged specimens (0.5 - 3.1 vol % martensite, usage factors from 0 to 1). (authors)
Geometric curvature and phase of the Rabi model
Energy Technology Data Exchange (ETDEWEB)
Mao, Lijun; Huai, Sainan; Guo, Liping; Zhang, Yunbo, E-mail: ybzhang@sxu.edu.cn
2015-11-15
We study the geometric curvature and phase of the Rabi model. Under the rotating-wave approximation (RWA), we apply the gauge independent Berry curvature over a surface integral to calculate the Berry phase of the eigenstates for both single and two-qubit systems, which is found to be identical with the system of spin-1/2 particle in a magnetic field. We extend the idea to define a vacuum-induced geometric curvature when the system starts from an initial state with pure vacuum bosonic field. The induced geometric phase is related to the average photon number in a period which is possible to measure in the qubit–cavity system. We also calculate the geometric phase beyond the RWA and find an anomalous sudden change, which implies the breakdown of the adiabatic theorem and the Berry phases in an adiabatic cyclic evolution are ill-defined near the anti-crossing point in the spectrum.
Metastable Features of Economic Networks and Responses to Exogenous Shocks.
Directory of Open Access Journals (Sweden)
Ali Hosseiny
Full Text Available It is well known that a network structure plays an important role in addressing a collective behavior. In this paper we study a network of firms and corporations for addressing metastable features in an Ising based model. In our model we observe that if in a recession the government imposes a demand shock to stimulate the network, metastable features shape its response. Actually we find that there exists a minimum bound where any demand shock with a size below it is unable to trigger the market out of recession. We then investigate the impact of network characteristics on this minimum bound. We surprisingly observe that in a Watts-Strogatz network, although the minimum bound depends on the average of the degrees, when translated into the language of economics, such a bound is independent of the average degrees. This bound is about 0.44ΔGDP, where ΔGDP is the gap of GDP between recession and expansion. We examine our suggestions for the cases of the United States and the European Union in the recent recession, and compare them with the imposed stimulations. While the stimulation in the US has been above our threshold, in the EU it has been far below our threshold. Beside providing a minimum bound for a successful stimulation, our study on the metastable features suggests that in the time of crisis there is a "golden time passage" in which the minimum bound for successful stimulation can be much lower. Hence, our study strongly suggests stimulations to arise within this time passage.
Spin dynamics in tunneling decay of a metastable state
Ban, Yue; Sherman, E. Ya.
2012-01-01
We analyze spin dynamics in the tunneling decay of a metastable localized state in the presence of spin-orbit coupling. We find that the spin polarization at short time scales is affected by the initial state while at long time scales both the probability- and the spin density exhibit diffraction-in-time phenomenon. We find that in addition to the tunneling time the tunneling in general can be characterized by a new parameter, the tunneling length. Although the tunneling length is independent...
Austenite stability in the high strength metastable stainless steels
S.J. Pawlak
2007-01-01
Purpose: The aim of the present paper was to study the peculiarities of the austenite to martensite phase transformation (A-M), which is an essential step in the production technology of the high strength metastable stainless steels.Design/methodology/approach: The desired control over A-M transformation have been achieved by proper design of the steel chemistry, cold working and heat treatment.Findings: For a range of steel compositions, it was shown that severe cold working leads to fully m...
Simple model for the dynamics towards metastable states
International Nuclear Information System (INIS)
Meijer, P.H.E.; Keskin, M.; Bodegom, E.
1986-01-01
Circumstances under which a quenched system will freeze in a metastable state are studied in simple systems with long-range order. The model used is the time-dependent pair approximation, based on the most probable path (MPP) method. The time dependence of the solution is shown by means of flow diagrams. The fixed points and other features of the differential equations in time are independent of the choice of the rate constants. It is explained qualitatively how the system behaves under varying descending temperatures: the role of the initial conditions, the dependence on the quenching rate, and the response to precooling
Investigating the Metastability of Clathrate Hydrates for Energy Storage
Energy Technology Data Exchange (ETDEWEB)
Koh, Carolyn Ann [Colorado School of Mines, Golden, CO (United States)
2014-11-18
Important breakthrough discoveries have been achieved from the DOE award on the key processes controlling the synthesis and structure-property relations of clathrate hydrates, which are critical to the development of clathrate hydrates as energy storage materials. Key achievements include: (i) the discovery of key clathrate hydrate building blocks (stable and metastable) leading to clathrate hydrate nucleation and growth; (ii) development of a rapid clathrate hydrate synthesis route via a seeding mechanism; (iii) synthesis-structure relations of H2 + CH4/CO2 binary hydrates to control thermodynamic requirements for energy storage and sequestration applications; (iv) discovery of a new metastable phase present during clathrate hydrate structural transitions. The success of our research to-date is demonstrated by the significant papers we have published in high impact journals, including Science, Angewandte Chemie, J. Am. Chem. Soc. Intellectual Merits of Project Accomplishments: The intellectual merits of the project accomplishments are significant and transformative, in which the fundamental coupled computational and experimental program has provided new and critical understanding on the key processes controlling the nucleation, growth, and thermodynamics of clathrate hydrates containing hydrogen, methane, carbon dioxide, and other guest molecules for energy storage. Key examples of the intellectual merits of the accomplishments include: the first discovery of the nucleation pathways and dominant stable and metastable structures leading to clathrate hydrate formation; the discovery and experimental confirmation of new metastable clathrate hydrate structures; the development of new synthesis methods for controlling clathrate hydrate formation and enclathration of molecular hydrogen. Broader Impacts of Project Accomplishments: The molecular investigations performed in this project on the synthesis (nucleation & growth)-structure-stability relations of clathrate
Metastable carbon in two chondritic porous interplanetary dust particles
International Nuclear Information System (INIS)
Rietmeijer, F.J.M.; Mackinnon, I.D.R.
1987-01-01
An analytical electron microscope study is presented on carbonaceous material in two chondritic porous aggregates, W7029* A and W7010* A2, from the Johnson Space Center Cosmic Dust Collection. The finding of well-ordered carbon-2H (lonsdaleite) in the two aggregates suggests that a record of hydrocarbon carbonization may be preserved in these materials. This carbon is a metastable phase resulting from hydrous pyrolysis below 300-350 0 C and may be a precursor to poorly graphitized carbons in primitive extra terrestrial materials. (UK)
Numerical transfer-matrix study of a model with competing metastable states
DEFF Research Database (Denmark)
Fiig, T.; Gorman, B.M.; Rikvold, P.A.
1994-01-01
The Blume-Capel model, a three-state lattice-gas model capable of displaying competing metastable states, is investigated in the limit of weak, long-range interactions. The methods used are scalar field theory, a numerical transfer-matrix method, and dynamical Monte Carlo simulations...... 'metastable free-energy density This transfer-matrix approach gives a free-energy cost of nucleation that supports the proportionality relation for the decay rate of the metastable phase T proportional to\\Imf alpha\\, even in cases where two metastable states compete. The picture that emerges from this study...
Directory of Open Access Journals (Sweden)
Geun Woo Lee
2017-10-01
Full Text Available The formation mechanism of metastable crystals from metastable liquids still remains elusive, although controlling the metastability of crystals and liquids already plays a crucial role in designing new materials in physics, chemistry, biology, and materials science. This review article describes how metastable phases can be obtained by controlling temperature, concentration, and pressure. In particular, I show the role of crystal-liquid interfacial free energy in the formation of metastable crystals from metastable liquids at a given driving force. In a microscopic viewpoint, local structure similarity between the metastable crystals and liquid determines the crystal-liquid interfacial free energy, and thus the nucleation barrier for the metastable crystals. The effect of the interfacial free energy on the formation of metastable crystals from supercooled, supersaturated, and supercompressed liquids will be demonstrated with metallic liquids, aqueous solutions, and water.
Geometrical method of decoupling
Directory of Open Access Journals (Sweden)
C. Baumgarten
2012-12-01
Full Text Available The computation of tunes and matched beam distributions are essential steps in the analysis of circular accelerators. If certain symmetries—like midplane symmetry—are present, then it is possible to treat the betatron motion in the horizontal, the vertical plane, and (under certain circumstances the longitudinal motion separately using the well-known Courant-Snyder theory, or to apply transformations that have been described previously as, for instance, the method of Teng and Edwards. In a preceding paper, it has been shown that this method requires a modification for the treatment of isochronous cyclotrons with non-negligible space charge forces. Unfortunately, the modification was numerically not as stable as desired and it was still unclear, if the extension would work for all conceivable cases. Hence, a systematic derivation of a more general treatment seemed advisable. In a second paper, the author suggested the use of real Dirac matrices as basic tools for coupled linear optics and gave a straightforward recipe to decouple positive definite Hamiltonians with imaginary eigenvalues. In this article this method is generalized and simplified in order to formulate a straightforward method to decouple Hamiltonian matrices with eigenvalues on the real and the imaginary axis. The decoupling of symplectic matrices which are exponentials of such Hamiltonian matrices can be deduced from this in a few steps. It is shown that this algebraic decoupling is closely related to a geometric “decoupling” by the orthogonalization of the vectors E[over →], B[over →], and P[over →], which were introduced with the so-called “electromechanical equivalence.” A mathematical analysis of the problem can be traced down to the task of finding a structure-preserving block diagonalization of symplectic or Hamiltonian matrices. Structure preservation means in this context that the (sequence of transformations must be symplectic and hence canonical. When
Geometric Mixing, Peristalsis, and the Geometric Phase of the Stomach
Arrieta, Jorge; Cartwright, Julian H.E.; Gouillart, Emmanuelle; Piro, Nicolas; Piro, Oreste; Tuval, Idan
2015-01-01
International audience; Mixing fluid in a container at low Reynolds number— in an inertialess environment—is not a trivial task. Reciprocating motions merely lead to cycles of mixing and unmixing, so continuous rotation, as used in many technological applications, would appear to be necessary. However, there is another solution: movement of the walls in a cyclical fashion to introduce a geometric phase. We show using journal-bearing flow as a model that such geometric mixing is a general tool...
Geometric inequalities for black holes
Energy Technology Data Exchange (ETDEWEB)
Dain, Sergio [Universidad Nacional de Cordoba (Argentina)
2013-07-01
Full text: A geometric inequality in General Relativity relates quantities that have both a physical interpretation and a geometrical definition. It is well known that the parameters that characterize the Kerr-Newman black hole satisfy several important geometric inequalities. Remarkably enough, some of these inequalities also hold for dynamical black holes. This kind of inequalities, which are valid in the dynamical and strong field regime, play an important role in the characterization of the gravitational collapse. They are closed related with the cosmic censorship conjecture. In this talk I will review recent results in this subject. (author)
Geometric inequalities for black holes
International Nuclear Information System (INIS)
Dain, Sergio
2013-01-01
Full text: A geometric inequality in General Relativity relates quantities that have both a physical interpretation and a geometrical definition. It is well known that the parameters that characterize the Kerr-Newman black hole satisfy several important geometric inequalities. Remarkably enough, some of these inequalities also hold for dynamical black holes. This kind of inequalities, which are valid in the dynamical and strong field regime, play an important role in the characterization of the gravitational collapse. They are closed related with the cosmic censorship conjecture. In this talk I will review recent results in this subject. (author)
Geometric Computing for Freeform Architecture
Wallner, J.
2011-06-03
Geometric computing has recently found a new field of applications, namely the various geometric problems which lie at the heart of rationalization and construction-aware design processes of freeform architecture. We report on our work in this area, dealing with meshes with planar faces and meshes which allow multilayer constructions (which is related to discrete surfaces and their curvatures), triangles meshes with circle-packing properties (which is related to conformal uniformization), and with the paneling problem. We emphasize the combination of numerical optimization and geometric knowledge.
Sarakinos, K.; Greczynski, G.; Elofsson, V.; Magnfält, D.; Högberg, H.; Alling, B.
2016-03-01
Metastable solid solutions are phases that are synthesized far from thermodynamic equilibrium and offer a versatile route to design materials with tailor-made functionalities. One of the most investigated classes of metastable solid solutions with widespread technological implications is vapor deposited ternary transition metal ceramic thin films (i.e., nitrides, carbides, and borides). The vapor-based synthesis of these ceramic phases involves complex and difficult to control chemical interactions of the vapor species with the growing film surface, which often makes the fundamental understanding of the composition-properties relations a challenging task. Hence, in the present study, we investigate the phase stability within an immiscible binary thin film system that offers a simpler synthesis chemistry, i.e., the Ag-Mo system. We employ magnetron co-sputtering to grow Ag1-xMox thin films over the entire composition range along with x-ray probes to investigate the films structure and bonding properties. Concurrently, we use density functional theory calculations to predict phase stability and determine the effect of chemical composition on the lattice volume and the electronic properties of Ag-Mo solid solutions. Our combined theoretical and experimental data show that Mo-rich films (x ≥ ˜0.54) form bcc Mo-Ag metastable solid solutions. Furthermore, for Ag-rich compositions (x ≤ ˜0.21), our data can be interpreted as Mo not being dissolved in the Ag fcc lattice. All in all, our data show an asymmetry with regards to the mutual solubility of Ag and Mo in the two crystal structures, i.e., Ag has a larger propensity for dissolving in the bcc-Mo lattice as compared to Mo in the fcc-Ag lattice. We explain these findings in light of isostructural short-range clustering that induces energy difference between the two (fcc and bcc) metastable phases. We also suggest that the phase stability can be explained by the larger atomic mobility of Ag atoms as compared to that
International Nuclear Information System (INIS)
Zafari, A; Wei, X S; Xu, W; Xia, K
2015-01-01
A Ti-5553 metastable β alloy was subjected to high pressure torsion (HPT) to obtain a nano β grain structure. The β grains were dramatically refined from an initial size of ∼1 mm to < 50 nm during HPT. The stress induced martensitic α' plates divided β grains into smaller domains and enabled subgrains to form even in very fine grains. The reverse α' to β transformation occurred when the thickness of the α' laths reached < ∼10 nm, leading to pure β nano-grains. Further deformation to an equivalent strain of 242 resulted in grain growth and the formation of well defined grain boundaries. (paper)
Plasma effects on the metastable H0(2s) atom
International Nuclear Information System (INIS)
Benage, J.F. Jr.
1986-01-01
Atomic radiative processes that occur in plasmas have long been of interest of plasma physicists. The process investigated here is atomic dipole transitions, specifically transitions from the metastable 2s to the 2p in hydrogen, which are induced by processes that occur in the plasma. An experiment was done to measure the rate of transitions from 2s to 2p in hydrogen. This experiment was divided into two sections. The first was to measure the transition rate in a near equilibrium plasma. The second section measured the transition rate when RF oscillations were imposed on the plasma. Results of the first part show that microscopic fluctuating electric fields produced by the motions of the charged particles induce transitions from 2s to 2p in hydrogen. The magnitude of this effect is compared to predicted transition rates due to collisions with electrons and ions and to rates predicted for an equilibrium plasma. In the second part, the plasma was shown to act as a filter, preventing transitions from being caused by the RF unless the RF was in the range where plasma waves could be launched. The interpretation given for this effect is that, when the oscillations are inducing transitions, it is because plasma waves are being launched in the plasma and it is these waves that are inducing the transitions
Mobile Watermarking against Geometrical Distortions
Directory of Open Access Journals (Sweden)
Jing Zhang
2015-08-01
Full Text Available Mobile watermarking robust to geometrical distortions is still a great challenge. In mobile watermarking, efficient computation is necessary because mobile devices have very limited resources due to power consumption. In this paper, we propose a low-complexity geometrically resilient watermarking approach based on the optimal tradeoff circular harmonic function (OTCHF correlation filter and the minimum average correlation energy Mellin radial harmonic (MACE-MRH correlation filter. By the rotation, translation and scale tolerance properties of the two kinds of filter, the proposed watermark detector can be robust to geometrical attacks. The embedded watermark is weighted by a perceptual mask which matches very well with the properties of the human visual system. Before correlation, a whitening process is utilized to improve watermark detection reliability. Experimental results demonstrate that the proposed watermarking approach is computationally efficient and robust to geometrical distortions.
Axonal Actin Transport Driven By Metastable Actin Filaments
Chakrabarty, Nilaj; Ganguly, Archan; Roy, Subhojit; Jung, Peter
Actin is one of the key constituents of the neuronal cytoskeleton and is responsible for driving important cellular processes like axon elongation. Axonal actin is synthesized in the cell body and transported at rates of 0.25 - 3 mm/day, as shown by in-vivo pulse-chase radiolabelling studies. However, the underlying transport mechanisms are unknown. Recent experiments in cultured neurons have revealed a dynamic network of metastable actin filaments (actin trails). Actin trails seem to originate from focal actin hotspots which colocalize with stationary endosomes. Interestingly, the number of actin trails extending anterogradely is higher than the ones extending retrogradely. We hypothesize that the bulk axonal transport of actin originates from this directional asymmetry of the number of actin trails. To test this, we constructed a computational model of actin trail growth and simulated the pulse-chase experiment. In our model, local, metastable trails, which grow with their barbed ends anchored to the hotspots, drive the bulk anterograde transport. Our results indicate that the observed bias of the nucleation probabilities and the elongation rate of actin trails are sufficient to drive the bulk transport of actin at rates that agree with in-vivo pulse chase experiments.
Fluxes, hierarchies, and metastable vacua in supersymmetric field theories
International Nuclear Information System (INIS)
Bruemmer, F.
2008-01-01
This thesis concerns topics both in low-energy effective field theories from type IIB superstring flux compactifications and in four-dimensional, rigidly supersymmetric gauge theories. We introduce flux compactifications with so-called ''warped throat'' regions, which lead to large hierarchies of scales in the effective four-dimensional theory. The correspondence between a particular such throat and a five-dimensional Randall-Sundrum-like model is established. We shown how certain string-theoretic features of the compactification, such as moduli stabilization by fluxes or the presence of an unstabilized Kaehler modulus, are incorporated in the five-dimensional picture. The KKLT construction for metastable de Sitter vacua is reviewed, as well as some possible modifications involving spontaneous F-term supersymmetry breaking. For KKLT-like models with their hidden sector localized inside a throat, the mediation of supersymmetry breaking to the visible sector is investigated. We review the mechanism of mixed modulus-anomaly mediation, and show that there can be additional equally important gravity-mediated contributions. We finally turn to the ISS model of metastable dynamical supersymmetry breaking in four dimensions, and present a renormalizable extension which generates a large hierarchy naturally. We also recapitulate how the ISS model may be obtained from a type IIB superstring model. (orig.)
Negative pion trapping by metastable state in liquid helium
International Nuclear Information System (INIS)
Nakamura, S.N.; Iwasaki, M.; Outa, H.
1991-11-01
We found long-lived metastable states of stopped π - 's in liquid helium by measuring time spectra of two different delayed products: 1) protons emitted after π - absorption by 4 He nuclei and 2) 70-MeV electrons originating from free π - → e - (ν e )-bar decay. The lifetime and fraction of delayed π - absorption obtained by emitted protons are 7.26±0.12 nsec and 1.66±0.05%, respectively. The free-decay fraction was calculated to be 0.64±0.03% from this result, which is consistent with the observed free-decay fraction of π e2 decay. These results imply that 2.30±0.07% of stopped π - are trapped in metastable states which have an overall lifetime of 10.1±0.2 nsec. The same experiment and analysis were performed for stopped π - in liquid neon. No evidence for trapping was found in liquid neon. (author)
Fluxes, hierarchies, and metastable vacua in supersymmetric field theories
Energy Technology Data Exchange (ETDEWEB)
Bruemmer, F.
2008-02-06
This thesis concerns topics both in low-energy effective field theories from type IIB superstring flux compactifications and in four-dimensional, rigidly supersymmetric gauge theories. We introduce flux compactifications with so-called ''warped throat'' regions, which lead to large hierarchies of scales in the effective four-dimensional theory. The correspondence between a particular such throat and a five-dimensional Randall-Sundrum-like model is established. We shown how certain string-theoretic features of the compactification, such as moduli stabilization by fluxes or the presence of an unstabilized Kaehler modulus, are incorporated in the five-dimensional picture. The KKLT construction for metastable de Sitter vacua is reviewed, as well as some possible modifications involving spontaneous F-term supersymmetry breaking. For KKLT-like models with their hidden sector localized inside a throat, the mediation of supersymmetry breaking to the visible sector is investigated. We review the mechanism of mixed modulus-anomaly mediation, and show that there can be additional equally important gravity-mediated contributions. We finally turn to the ISS model of metastable dynamical supersymmetry breaking in four dimensions, and present a renormalizable extension which generates a large hierarchy naturally. We also recapitulate how the ISS model may be obtained from a type IIB superstring model. (orig.)
Metastability and avalanche dynamics in strongly correlated gases with long-range interactions
Hruby, Lorenz; Dogra, Nishant; Landini, Manuele; Donner, Tobias; Esslinger, Tilman
2018-03-01
We experimentally study the stability of a bosonic Mott insulator against the formation of a density wave induced by long-range interactions and characterize the intrinsic dynamics between these two states. The Mott insulator is created in a quantum degenerate gas of 87-Rubidium atoms, trapped in a 3D optical lattice. The gas is located inside and globally coupled to an optical cavity. This causes interactions of global range, mediated by photons dispersively scattered between a transverse lattice and the cavity. The scattering comes with an atomic density modulation, which is measured by the photon flux leaking from the cavity. We initialize the system in a Mott-insulating state and then rapidly increase the global coupling strength. We observe that the system falls into either of two distinct final states. One is characterized by a low photon flux, signaling a Mott insulator, and the other is characterized by a high photon flux, which we associate with a density wave. Ramping the global coupling slowly, we observe a hysteresis loop between the two states—a further signature of metastability. A comparison with a theoretical model confirms that the metastability originates in the competition between short- and global-range interactions. From the increasing photon flux monitored during the switching process, we find that several thousand atoms tunnel to a neighboring site on the timescale of the single-particle dynamics. We argue that a density modulation, initially forming in the compressible surface of the trapped gas, triggers an avalanche tunneling process in the Mott-insulating region.
Antenna with Dielectric Having Geometric Patterns
Dudley, Kenneth L. (Inventor); Elliott, Holly A. (Inventor); Cravey, Robin L. (Inventor); Connell, John W. (Inventor); Ghose, Sayata (Inventor); Watson, Kent A. (Inventor); Smith, Jr., Joseph G. (Inventor)
2013-01-01
An antenna includes a ground plane, a dielectric disposed on the ground plane, and an electrically-conductive radiator disposed on the dielectric. The dielectric includes at least one layer of a first dielectric material and a second dielectric material that collectively define a dielectric geometric pattern, which may comprise a fractal geometry. The radiator defines a radiator geometric pattern, and the dielectric geometric pattern is geometrically identical, or substantially geometrically identical, to the radiator geometric pattern.
Geometric aspects of biological sequence comparison.
Stojmirović, Aleksandar; Yu, Yi-Kuo
2009-04-01
We introduce a geometric framework suitable for studying the relationships among biological sequences. In contrast to previous works, our formulation allows asymmetric distances (quasi-metrics), originating from uneven weighting of strings, which may induce non-trivial partial orders on sets of biosequences. The distances considered are more general than traditional generalized string edit distances. In particular, our framework enables non-trivial conversion between sequence similarities, both local and global, and distances. Our constructions apply to a wide class of scoring schemes and require much less restrictive gap penalties than the ones regularly used. Numerous examples are provided to illustrate the concepts introduced and their potential applications.
Experiments on state selection and Penning ionisation with fast metastable rare gas atoms
International Nuclear Information System (INIS)
Kroon, J.P.C.
1985-01-01
This thesis describes experiments with metastable He/Ne atoms. The experiments are performed in a crossed beam machine. Two different sources are used for the production of metastable atoms: a source for the production of metastable atoms in the thermal energy range and a hollow cathode arc for the production of metastable atoms in the superthermal energy range (1-7 eV). The progress made in the use of the hollow cathode arc is described as well as the experimental set-up. The rare gas energy-level diagram is characterized by two metastable levels. By optical pumping it is possible to select a single metastable level, both for He and Ne. For the case of He this is done by a recently built He quenchlamp which selectively quenches the metastable 2 1 S level population. In the thermal energy range the quenching is complete; in the superthermal energy range the 2 1 S level population is only partly quenched. For the optical pumping of Ne* atoms a cw dye laser is used. New experiments have been started on the measurement, in a crossed beam machine, of the fluorescence caused by inelastic collisions where metastable atoms are involved. The He* + Ne system is used as a pilot study for these experiments. The He-Ne laser is based on this collision system. (Auth.)
Geometric Mixing, Peristalsis, and the Geometric Phase of the Stomach.
Arrieta, Jorge; Cartwright, Julyan H E; Gouillart, Emmanuelle; Piro, Nicolas; Piro, Oreste; Tuval, Idan
2015-01-01
Mixing fluid in a container at low Reynolds number--in an inertialess environment--is not a trivial task. Reciprocating motions merely lead to cycles of mixing and unmixing, so continuous rotation, as used in many technological applications, would appear to be necessary. However, there is another solution: movement of the walls in a cyclical fashion to introduce a geometric phase. We show using journal-bearing flow as a model that such geometric mixing is a general tool for using deformable boundaries that return to the same position to mix fluid at low Reynolds number. We then simulate a biological example: we show that mixing in the stomach functions because of the "belly phase," peristaltic movement of the walls in a cyclical fashion introduces a geometric phase that avoids unmixing.
Geometric Mixing, Peristalsis, and the Geometric Phase of the Stomach.
Directory of Open Access Journals (Sweden)
Jorge Arrieta
Full Text Available Mixing fluid in a container at low Reynolds number--in an inertialess environment--is not a trivial task. Reciprocating motions merely lead to cycles of mixing and unmixing, so continuous rotation, as used in many technological applications, would appear to be necessary. However, there is another solution: movement of the walls in a cyclical fashion to introduce a geometric phase. We show using journal-bearing flow as a model that such geometric mixing is a general tool for using deformable boundaries that return to the same position to mix fluid at low Reynolds number. We then simulate a biological example: we show that mixing in the stomach functions because of the "belly phase," peristaltic movement of the walls in a cyclical fashion introduces a geometric phase that avoids unmixing.
Wu, Z.; Zheng, Y.; Wang, K. W.
2018-02-01
We present an approach to achieve adaptable band structures and nonreciprocal wave propagation by exploring and exploiting the concept of metastable modular metastructures. Through studying the dynamics of wave propagation in a chain composed of finite metastable modules, we provide experimental and analytical results on nonreciprocal wave propagation and unveil the underlying mechanisms that facilitate such unidirectional energy transmission. In addition, we demonstrate that via transitioning among the numerous metastable states, the proposed metastructure is endowed with a large number of bandgap reconfiguration possibilities. As a result, we illustrate that unprecedented adaptable nonreciprocal wave propagation can be realized using the metastable modular metastructure. Overall, this research elucidates the rich dynamics attainable through the combinations of periodicity, nonlinearity, spatial asymmetry, and metastability and creates a class of adaptive structural and material systems capable of realizing tunable bandgaps and nonreciprocal wave transmissions.
Excitation into 3p55p levels from the metastable levels of Ar
International Nuclear Information System (INIS)
Jung, R. O.; Boffard, John B.; Anderson, L. W.; Lin, Chun C.
2007-01-01
Measurements of cross sections for electron-impact excitation out of the J=0 and J=2 3p 5 4s metastable levels of argon into nine of the ten levels of the 3p 5 5p manifold are presented in the energy range from threshold to 10 eV. A mixed target of atoms in both metastable levels was created by a hollow cathode discharge. Laser quenching was used to depopulate either one of the metastable levels, allowing separate measurements of the cross sections from each of the two metastable levels. Unlike the metastable excitation cross sections into 3p 5 4p levels, the cross sections into the 3p 5 5p levels are not found to be proportional to optical oscillator strengths
Geometric Mixing, Peristalsis, and the Geometric Phase of the Stomach
Arrieta, Jorge; Cartwright, Julyan H. E.; Gouillart, Emmanuelle; Piro, Nicolas; Piro, Oreste; Tuval, Idan
2012-01-01
© 2015 Arrieta et al. Mixing fluid in a container at low Reynolds number - in an inertialess environment - is not a trivial task. Reciprocating motions merely lead to cycles of mixing and unmixing, so continuous rotation, as used in many technological applications, would appear to be necessary. However, there is another solution: movement of the walls in a cyclical fashion to introduce a geometric phase.We show using journal-bearing flow as a model that such geometric mixing is a general tool...
Creation and annealing of metastable defect states in CH3NH3PbI3 at low temperatures
Lang, F.; Shargaieva, O.; Brus, V. V.; Rappich, J.; Nickel, N. H.
2018-02-01
Methylammonium lead iodide (CH3NH3PbI3), an organic-inorganic perovskite widely used for optoelectronic applications, is known to dissociate under illumination with light at photon energies around 2.7 eV and higher. Here, we show that photo-induced dissociation is not limited to ambient temperatures but can be observed even at 5 K. The photo-induced dissociation of N-H bonds results in the formation of metastable states. Photoluminescence (PL) measurements reveal the formation of defect states that are located 100 meV within the bandgap. This is accompanied by a quenching of the band-to-band PL by one order of magnitude. Defect generation is reversible and annealing at 30 K recovers the band-to-band PL, while the light-induced defect states disappear concurrently.
Metastability and thermophysical properties of metallic bulk glass forming alloys
International Nuclear Information System (INIS)
Wunderlich, R.K.; Fecht, H.J.
1998-01-01
The absence of crystallization over a wide time/temperature window can be used to produce bulk metallic glass by relatively slow cooling of the melt. For a number of alloys, including several multicomponent Zr-based alloys, the relevant thermodynamic and thermomechanical properties of the metastable glassy and undercooled liquid states have been measured below and above the glass transition temperature. These measurements include specific heat, viscosity, volume, and elastic properties as a function of temperature. As a result, it becomes obvious that the maximum undercooling for these alloys is given by an isentropic condition before an enthalpic or isochoric instability is reached. Alternatively, these glasses can also be produced by mechanical alloying, thus replacing the thermal disorder by static disorder and resulting in the same thermodynamic glass state. During heating through the undercooled liquid, a nanoscale phase separation occurs for most glasses as a precursor of crystallization
Fundamentals of metastability exchange optical pumping in helium
International Nuclear Information System (INIS)
Batz, M; Nacher, P-J; Tastevin, G
2011-01-01
Advances in metastability exchange optical pumping (MEOP) at high laser powers, but also at high gas pressures and high magnetic field strengths, has provided strong motivation for revisiting the understanding of the limitations of this powerful technique. A comprehensive model has been developed for improved description of the combined effects of OP, ME, and relaxation, and of detailed MEOP features observed over the broad range of operating conditions. A brief description is provided, with illustrative comparisons of computed and experimental results. This improved tool is used to explain the excellent photon efficiency of OP obtained at all field strengths. It is combined with an angular momentum budget approach to quantitatively investigate the newly discovered strong OP-enhanced polarisation losses that currently limits MEOP performance.
Fundamentals of metastability exchange optical pumping in helium
Batz, M.; Nacher, P.-J.; Tastevin, G.
2011-06-01
Advances in metastability exchange optical pumping (MEOP) at high laser powers, but also at high gas pressures and high magnetic field strengths, has provided strong motivation for revisiting the understanding of the limitations of this powerful technique. A comprehensive model has been developed for improved description of the combined effects of OP, ME, and relaxation, and of detailed MEOP features observed over the broad range of operating conditions. A brief description is provided, with illustrative comparisons of computed and experimental results. This improved tool is used to explain the excellent photon efficiency of OP obtained at all field strengths. It is combined with an angular momentum budget approach to quantitatively investigate the newly discovered strong OP-enhanced polarisation losses that currently limits MEOP performance.
Metastable decay of photoionized niobium clusters: Evaporation vs fission fragmentation
International Nuclear Information System (INIS)
Cole, S.K.; Liu, K.; Riley, S.J.
1986-01-01
The metastable decay of photoionized niobium clusters (Nb/sub n/ + ) has been observed in a newly constructed cluster beam machine. The decay manifests itself in the time-of-flight (TOF) mass spectrum as an asymmetric broadening of daughter ion peaks. Pulsed ion extraction has been used to measure the decay rate constants and to establish the mechanism of the fragmentation, evaporation and/or fission of the photoionized clusters. It is found that within the experimental time window evaporation dominates for the smaller clusters (n 6 sec -1 . The average kinetic energy release is also determined and is found to be on the order of 5 MeV. 8 refs., 3 figs., 1 tab
Two-photon polarization Fourier spectroscopy of metastable atomic hydrogen
International Nuclear Information System (INIS)
Duncan, A.J.; Beyer, H.-J.; Kleinpoppen, H.; Sheikh, Z.A,; B-Z Univ., Multan
1997-01-01
A novel Fourier-transform spectroscopic method using two-photon polarization to determine the spectral distribution of the two photons emitted in the spontaneous decay of metastable atomic hydrogen is described. The method uses birefringent retardation plates and takes advantage of the subtle interplay between the spectral properties and the entangled polarization properties of the radiation emitted in the decay. Assuming the validity of the theoretical spectral distribution, it is shown that the experimental results agree well with theory. On the other hand, success in solving the inverse problem of determining the spectral distribution from the experimental results is limited by the small number of experimental points. However, making reasonable assumptions it is deduced that the observed spectrum is characterized by a broadband signal of width (0.43 ± 0.06) x 10 16 rad s -1 and centre angular frequency (0.77 ± 0.03) x 10 16 rad s -1 in good agreement with the predictions of 0.489 x 10 16 rad s -1 and 0.775 x 10 16 rad s -1 , respectively, obtained from the theoretical spectral distribution modified to take account of the absorption of the two-photon radiation in air. The values of 1.5 fs for the coherence time and 440 nm for the coherence length for single photons of the two-photon pair which are obtained from the measured bandwidth imply that, in the ideal case, these values are determined by the essentially zero lifetime of the virtual intermediate state of the decay process rather than the long lifetime of the metastable state which, it is suggested, determines the coherence time and coherence length appropriate to certain types of fourth-order interference experiments. (Author)
Fast neutron spectroscopy with tensioned metastable fluid detectors
Energy Technology Data Exchange (ETDEWEB)
Grimes, T.F.; Taleyarkhan, R.P., E-mail: rusi@purdue.edu
2016-09-11
This paper describes research into development of a rapid-turnaround, neutron-spectroscopy capable (gamma-beta blind), high intrinsic efficiency sensor system utilizing the tensioned metastable fluid detector (TMFD) architecture. The inability of prevailing theoretical models (developed successfully for the classical bubble chamber) to adequately predict detection thresholds for tensioned metastable fluid conditions is described. Techniques are presented to overcome these inherent shortcomings, leading thereafter, to allow successful neutron spectroscopy using TMFDs – via the newly developed Single Atom Spectroscopy (SAS) approach. SAS also allows for a unique means for rapidly determining neutron energy thresholds with TMFDs. This is accomplished by simplifying the problem of determining Cavitation Detection Events (CDEs) arising from neutron interactions with one in which several recoiling atom species contribute to CDEs, to one in which only one dominant recoil atom need be considered. The chosen fluid is Heptane (C{sub 7}H{sub 16}) for which only recoiling C atoms contribute to CDEs. Using the SAS approach, the threshold curve for Heptane was derived using isotope neutron source data, and then validated against experiments with mono-energetic (2.45/14 MeV) neutrons from D-D and D-T accelerators. Thereafter the threshold curves were used to produce the response matrix for various geometries. The response matrices were in turn combined with experimental data to recover the continuous spectra of fission (Cf-252) and (α,n) Pu–Be isotopic neutron sources via an unfolding algorithm. A generalized algorithm is also presented for performing neutron spectroscopy using any other TMFD fluid that meets the SAS approach assumptions.
Fast neutron spectroscopy with tensioned metastable fluid detectors
Grimes, T. F.; Taleyarkhan, R. P.
2016-09-01
This paper describes research into development of a rapid-turnaround, neutron-spectroscopy capable (gamma-beta blind), high intrinsic efficiency sensor system utilizing the tensioned metastable fluid detector (TMFD) architecture. The inability of prevailing theoretical models (developed successfully for the classical bubble chamber) to adequately predict detection thresholds for tensioned metastable fluid conditions is described. Techniques are presented to overcome these inherent shortcomings, leading thereafter, to allow successful neutron spectroscopy using TMFDs - via the newly developed Single Atom Spectroscopy (SAS) approach. SAS also allows for a unique means for rapidly determining neutron energy thresholds with TMFDs. This is accomplished by simplifying the problem of determining Cavitation Detection Events (CDEs) arising from neutron interactions with one in which several recoiling atom species contribute to CDEs, to one in which only one dominant recoil atom need be considered. The chosen fluid is Heptane (C7H16) for which only recoiling C atoms contribute to CDEs. Using the SAS approach, the threshold curve for Heptane was derived using isotope neutron source data, and then validated against experiments with mono-energetic (2.45/14 MeV) neutrons from D-D and D-T accelerators. Thereafter the threshold curves were used to produce the response matrix for various geometries. The response matrices were in turn combined with experimental data to recover the continuous spectra of fission (Cf-252) and (α,n) Pu-Be isotopic neutron sources via an unfolding algorithm. A generalized algorithm is also presented for performing neutron spectroscopy using any other TMFD fluid that meets the SAS approach assumptions.
Geometric procedures for civil engineers
Tonias, Elias C
2016-01-01
This book provides a multitude of geometric constructions usually encountered in civil engineering and surveying practice. A detailed geometric solution is provided to each construction as well as a step-by-step set of programming instructions for incorporation into a computing system. The volume is comprised of 12 chapters and appendices that may be grouped in three major parts: the first is intended for those who love geometry for its own sake and its evolution through the ages, in general, and, more specifically, with the introduction of the computer. The second section addresses geometric features used in the book and provides support procedures used by the constructions presented. The remaining chapters and the appendices contain the various constructions. The volume is ideal for engineering practitioners in civil and construction engineering and allied areas.
Geometric group theory an introduction
Löh, Clara
2017-01-01
Inspired by classical geometry, geometric group theory has in turn provided a variety of applications to geometry, topology, group theory, number theory and graph theory. This carefully written textbook provides a rigorous introduction to this rapidly evolving field whose methods have proven to be powerful tools in neighbouring fields such as geometric topology. Geometric group theory is the study of finitely generated groups via the geometry of their associated Cayley graphs. It turns out that the essence of the geometry of such groups is captured in the key notion of quasi-isometry, a large-scale version of isometry whose invariants include growth types, curvature conditions, boundary constructions, and amenability. This book covers the foundations of quasi-geometry of groups at an advanced undergraduate level. The subject is illustrated by many elementary examples, outlooks on applications, as well as an extensive collection of exercises.
Geometric identities in stereological particle analysis
DEFF Research Database (Denmark)
Kötzer, S.; Jensen, Eva Bjørn Vedel; Baddeley, A.
We review recent findings about geometric identities in integral geometry and geometric tomography, and their statistical application to stereological particle analysis. Open questions are discussed.......We review recent findings about geometric identities in integral geometry and geometric tomography, and their statistical application to stereological particle analysis. Open questions are discussed....
Geometric Langlands From Six Dimensions
Witten, Edward
2010-01-01
Geometric Langlands duality is usually formulated as a statement about Riemann surfaces, but it can be naturally understood as a consequence of electric-magnetic duality of four-dimensional gauge theory. This duality in turn is naturally understood as a consequence of the existence of a certain exotic supersymmetric conformal field theory in six dimensions. The same six-dimensional theory also gives a useful framework for understanding some recent mathematical results involving a counterpart of geometric Langlands duality for complex surfaces. (This article is based on a lecture at the Raoul Bott celebration, Montreal, June 2008.)
Catching homologies by geometric entropy
Felice, Domenico; Franzosi, Roberto; Mancini, Stefano; Pettini, Marco
2018-02-01
A geometric entropy is defined in terms of the Riemannian volume of the parameter space of a statistical manifold associated with a given network. As such it can be a good candidate for measuring networks complexity. Here we investigate its ability to single out topological features of networks proceeding in a bottom-up manner: first we consider small size networks by analytical methods and then large size networks by numerical techniques. Two different classes of networks, the random graphs and the scale-free networks, are investigated computing their Betti numbers and then showing the capability of geometric entropy of detecting homologies.
Geometric scaling as traveling waves
International Nuclear Information System (INIS)
Munier, S.; Peschanski, R.
2003-01-01
We show the relevance of the nonlinear Fisher and Kolmogorov-Petrovsky-Piscounov (KPP) equation to the problem of high energy evolution of the QCD amplitudes. We explain how the traveling wave solutions of this equation are related to geometric scaling, a phenomenon observed in deep-inelastic scattering experiments. Geometric scaling is for the first time shown to result from an exact solution of nonlinear QCD evolution equations. Using general results on the KPP equation, we compute the velocity of the wave front, which gives the full high energy dependence of the saturation scale
In Defence of Geometrical Algebra
Blasjo, V.N.E.
The geometrical algebra hypothesis was once the received interpretation of Greek mathematics. In recent decades, however, it has become anathema to many. I give a critical review of all arguments against it and offer a consistent rebuttal case against the modern consensus. Consequently, I find that
Geometric quantization and general relativity
International Nuclear Information System (INIS)
Souriau, J.-M.
1977-01-01
The purpose of geometric quantization is to give a rigorous mathematical content to the 'correspondence principle' between classical and quantum mechanics. The main tools are borrowed on one hand from differential geometry and topology (differential manifolds, differential forms, fiber bundles, homology and cohomology, homotopy), on the other hand from analysis (functions of positive type, infinite dimensional group representations, pseudo-differential operators). Some satisfactory results have been obtained in the study of dynamical systems, but some fundamental questions are still waiting for an answer. The 'geometric quantization of fields', where some further well known difficulties arise, is still in a preliminary stage. In particular, the geometric quantization on the gravitational field is still a mere project. The situation is even more uncertain due to the fact that there is no experimental evidence of any quantum gravitational effect which could give us a hint towards what we are supposed to look for. The first level of both Quantum Theory, and General Relativity describes passive matter: influence by the field without being a source of it (first quantization and equivalence principle respectively). In both cases this is only an approximation (matter is always a source). But this approximation turns out to be the least uncertain part of the description, because on one hand the first quantization avoids the problems of renormalization and on the other hand the equivalence principle does not imply any choice of field equations (it is known that one can modify Einstein equations at short distances without changing their geometrical properties). (Auth.)
Geometric scaling in exclusive processes
International Nuclear Information System (INIS)
Munier, S.; Wallon, S.
2003-01-01
We show that according to the present understanding of the energy evolution of the observables measured in deep-inelastic scattering, the photon-proton scattering amplitude has to exhibit geometric scaling at each impact parameter. We suggest a way to test this experimentally at HERA. A qualitative analysis based on published data is presented and discussed. (orig.)
Height and Tilt Geometric Texture
DEFF Research Database (Denmark)
Andersen, Vedrana; Desbrun, Mathieu; Bærentzen, Jakob Andreas
2009-01-01
compromise between functionality and simplicity: it can efficiently handle and process geometric texture too complex to be represented as a height field, without having recourse to full blown mesh editing algorithms. The height-and-tilt representation proposed here is fully intrinsic to the mesh, making...
Cartan's geometrical structure of supergravity
International Nuclear Information System (INIS)
Baaklini, N.S.
1977-06-01
The geometrical partnership of the vierbein and the spin-3/2 field in the structure of the supergravity Lagrangian is emphasized. Both fields are introduced as component of the same matrix differential form. The only local symmetry of the theory is SL(2,C)
Geometric integrator for simulations in the canonical ensemble
International Nuclear Information System (INIS)
Tapias, Diego; Sanders, David P.; Bravetti, Alessandro
2016-01-01
We introduce a geometric integrator for molecular dynamics simulations of physical systems in the canonical ensemble that preserves the invariant distribution in equations arising from the density dynamics algorithm, with any possible type of thermostat. Our integrator thus constitutes a unified framework that allows the study and comparison of different thermostats and of their influence on the equilibrium and non-equilibrium (thermo-)dynamic properties of a system. To show the validity and the generality of the integrator, we implement it with a second-order, time-reversible method and apply it to the simulation of a Lennard-Jones system with three different thermostats, obtaining good conservation of the geometrical properties and recovering the expected thermodynamic results. Moreover, to show the advantage of our geometric integrator over a non-geometric one, we compare the results with those obtained by using the non-geometric Gear integrator, which is frequently used to perform simulations in the canonical ensemble. The non-geometric integrator induces a drift in the invariant quantity, while our integrator has no such drift, thus ensuring that the system is effectively sampling the correct ensemble.
Orth, Dominic; Davids, Keith; Seifert, Ludovic
2018-02-01
Previous investigations have shown that inducing meta-stability in behavior can be achieved by overlapping affordances through constraint manipulation, allowing cooperative and competitive tendencies to functionally coexist. The purpose of this paper was to test a number of conditions applying these design principles on performance during skills practice and transfer. Of additional interest, was whether the existing skill level interacted with the environmental properties of the experimental tasks (varying indoor climbing routes). Two skill groups practised on three routes per session over four separate sessions. At the end of the final session, climbers undertook a transfer test. Routes, matched for difficulty, were manipulated in terms of hand-hold design. Route-1 and Route-2 were designed with holds with a single graspable edge, aligned entirely parallel or perpendicular to the ground plane respectively. Route-3 had at each hold, two graspable edges (one parallel and one perpendicular to the ground plane). Behavioral exploration at the hip and hands were largest under the metastable condition (Route-3). Skill level also interacted with route properties during practice and influenced transfer. Data suggest meta-stability induces exploratory behaviors. Less skilled individuals explore both hand and hip levels, whereas, more experienced climbers explore at the hip level. Copyright © 2017 Elsevier B.V. All rights reserved.
Maker-Breaker games on random geometric graphs
Beveridge, Andrew; Dudek, Andrzej; Frieze, Alan; Muller, Tobias; Stojakovic, Milos
2014-01-01
In a Maker-Breaker game on a graph G, Breaker and Maker alternately claim edges of G. Maker wins if, after all edges have been claimed, the graph induced by his edges has some desired property. We consider four Maker-Breaker games played on random geometric graphs. For each of our four games we show
Carcinoma hepatocelular metastático em Jaguatirica (Leopardus pardalis
Directory of Open Access Journals (Sweden)
Dayane F.H. Miranda
2015-11-01
Full Text Available RESUMO: O carcinoma hepatocelular (CHC é uma neoplasia rara nos animais domésticos e em espécies selvagens foi relatado somente em antílopes, veado, cães da pradaria e furões, mas não existem relatos em Leopardus pardalis (jaguatirica. Este trabalho descreve um caso de carcinoma hepatocelular metastático em uma fêmea felina de aproximadamente 18 anos de idade, da espécie Leopardus pardalis, proveniente do Parque Zoobotânico de Teresina-PI, com histórico de anorexia, apatia e evolução ao óbito que foi encaminhada ao Setor de Patologia Animal da Universidade Federal do Piauí para exame anatomopatológico. À necropsia foram observadas duas nodulações de aproximadamente 8,0cm de diâmetro no fígado, de coloração variando da brancacenta ao vermelhado claro, amarelada a vermelho escuro, subdivididas em lóbulos por tecido conjuntivo. No pâncreas foram observadas múltiplas nodulações de aproximadamente 1,0 cm de diâmetro, com superfície lisa, consistência firme, coloração vermelho-amarelada. A superfície de corte dos rins também apresentava várias nodulações milimétricas de distribuição multifocal, na região córtico-medular, consistência firme, coloração branco-acinzentada ou amarelada, sugerindo metástase. Os fragmentos das lesões de fígado foram coletados e no exame microscópico observaram-se proliferação de hepatócitos em cordões bem diferenciados, formando trabéculas com espessura de três ou mais células. Os hepatócitos apresentavam-se volumosos, pleomórficos, com citoplasma eosinofílico. Na coloração com PAS constataram-se, regularmente, acúmulo de glicogênio nos hepatócitos neoplásicos. A confirmação foi feita pela técnica de imunoistoquímica, utilizando-se anticorpo monoclonal (Hepatocyte Specific Antigen. Os achados anatomohistopatológicos, e o auxilio da imunoistoquímica permitiram concluir pelo diagnóstico de hepatocarcinoma trabecular metastático em Leopardus pardalis
PAMELA, DAMA, INTEGRAL and signatures of metastable excited WIMPs
Energy Technology Data Exchange (ETDEWEB)
Finkbeiner, Douglas P. [Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 (United States); Slatyer, Tracy R. [Physics Department, Harvard University, Cambridge, MA 02138 (United States); Weiner, Neal [Center for Cosmology and Particle Physics, Department of Physics, New York University, New York, NY 10003 (United States); Yavin, Itay, E-mail: dfinkbeiner@cfa.harvard.edu, E-mail: tslatyer@fas.harvard.edu, E-mail: neal.weiner@nyu.edu, E-mail: iyavin@princeton.edu [Department of Physics, Princeton University, Princeton, NJ 08544 (United States)
2009-09-01
Models of dark matter with ∼ GeV scale force mediators provide attractive explanations of many high energy anomalies, including PAMELA, ATIC, and the WMAP haze. At the same time, by exploiting the ∼ MeV scale excited states that are automatically present in such theories, these models naturally explain the DAMA/LIBRA and INTEGRAL signals through the inelastic dark matter (iDM) and exciting dark matter (XDM) scenarios, respectively. Interestingly, with only weak kinetic mixing to hypercharge to mediate decays, the lifetime of excited states with δ < 2m{sub electron} is longer than the age of the universe. The fractional relic abundance of these excited states depends on the temperature of kinetic decoupling, but can be appreciable. There could easily be other mechanisms for rapid decay, but the consequences of such long-lived states are intriguing. We find that CDMS constrains the fractional relic population of ∼ 100 keV states to be ∼< 10{sup −2}, for a 1 TeV WIMP with σ{sub n} = 10{sup −40} cm{sup 2}. Upcoming searches at CDMS, as well as xenon, silicon, and argon targets, can push this limit significantly lower. We also consider the possibility that the DAMA excitation occurs from a metastable state into the XDM state, which decays via e{sup +}e{sup −} emission, which allows lighter states to explain the INTEGRAL signal due to the small kinetic energies required. Such models yield dramatic signals from down-scattering, with spectra peaking at high energies, sometimes as high as ∼ 1 MeV, well outside the usual search windows. Such signals would be visible at future Ar and Si experiments, and may be visible at Ge and Xe experiments, although γ-rays associated with nuclear excitations would complicate the signal for these heavier targets. We also consider other XDM models involving ∼ 500 keV metastable states, and find they can allow lighter WIMPs to explain INTEGRAL as well.
Metastable State Diamond Growth and its Applications to Electronic Devices.
Jeng, David Guang-Kai
Diamond which consists of a dense array of carbon atoms joined by strong covalent bonds and formed into a tetrahedral crystal structure has remarkable mechanical, thermal, optical and electrical properties suitable for many industrial applications. With a proper type of doping, diamond is also an ideal semiconductor for high performance electronic devices. Unfortunately, natural diamond is rare and limited by its size and cost, it is not surprising that people continuously look for a synthetic replacement. It was believed for long time that graphite, another form of carbon, may be converted into diamond under high pressure and temperature. However, the exact condition of conversion was not clear. In 1939, O. I. Leipunsky developed an equilibrium phase diagram between graphite and diamond based on thermodynamic considerations. In the phase diagram, there is a low temperature (below 1000^ circC) and low pressure (below 1 atm) region in which diamond is metastable and graphite is stable, therefore establishes the conditions for the coexistence of the two species. Leipunsky's pioneer work opened the door for diamond synthesis. In 1955, the General Electric company (GE) was able to produce artificial diamond at 55k atm pressure and a temperature of 2000^ circC. Contrary to GE, B. Derjaguin and B. V. Spitzyn in Soviet Union, developed a method of growing diamonds at 1000^circC and at a much lower pressure in 1956. Since then, researchers, particularly in Soviet Union, are continuously looking for methods to grow diamond and diamond film at lower temperatures and pressures with slow but steady progress. It was only in the early 80's that the importance of growing diamond films had attracted the attentions of researchers in the Western world and in Japan. Recent progress in plasma physics and chemical vapor deposition techniques in integrated electronics technology have pushed the diamond growth in its metastable states into a new era. In this research, a microwave plasma
Geometric rectification for nanoscale vibrational energy harvesting
Bustos-Marún, Raúl A.
2018-02-01
In this work, we present a mechanism that, based on quantum-mechanical principles, allows one to recover kinetic energy at the nanoscale. Our premise is that very small mechanical excitations, such as those arising from sound waves propagating through a nanoscale system or similar phenomena, can be quite generally converted into useful electrical work by applying the same principles behind conventional adiabatic quantum pumping. The proposal is potentially useful for nanoscale vibrational energy harvesting where it can have several advantages. The most important one is that it avoids the use of classical rectification mechanisms as it is based on what we call geometric rectification. We show that this geometric rectification results from applying appropriate but quite general initial conditions to damped harmonic systems coupled to electronic reservoirs. We analyze an analytically solvable example consisting of a wire suspended over permanent charges where we find the condition for maximizing the pumped charge. We also studied the effects of coupling the system to a capacitor including the effect of current-induced forces and analyzing the steady-state voltage of operation. Finally, we show how quantum effects can be used to boost the performance of the proposed device.
Fast metastable hydrogen atoms from H2 molecules: twin atoms
Directory of Open Access Journals (Sweden)
Trimèche A.
2015-01-01
Full Text Available It is a difficult task to obtain “twin atoms”, i.e. pairs of massive particles such that one can perform experiments in the same fashion that is routinely done with “twin photons”. One possible route to obtain such pairs is by dissociating homonuclear diatomic molecules. We address this possibility by investigating the production of metastable H(2s atoms coming from the dissociation of cold H2 molecules produced in a Campargue nozzle beam crossing an electron beam from a high intensity pulsed electron gun. Dissociation by electron impact was chosen to avoid limitations of target molecular excited states due to selection rules. Detectors placed several centimeters away from the collision center, and aligned with respect to possible common molecular dissociation channel, analyze the neutral fragments as a function of their time-of-flight (TOF through Lyman-α detection. Evidence for the first time observed coincidence of pairs of H(2s atoms obtained this way is presented.
Finding metastabilities in reversible Markov chains based on incomplete sampling
Directory of Open Access Journals (Sweden)
Fackeldey Konstantin
2017-01-01
Full Text Available In order to fully characterize the state-transition behaviour of finite Markov chains one needs to provide the corresponding transition matrix P. In many applications such as molecular simulation and drug design, the entries of the transition matrix P are estimated by generating realizations of the Markov chain and determining the one-step conditional probability Pij for a transition from one state i to state j. This sampling can be computational very demanding. Therefore, it is a good idea to reduce the sampling effort. The main purpose of this paper is to design a sampling strategy, which provides a partial sampling of only a subset of the rows of such a matrix P. Our proposed approach fits very well to stochastic processes stemming from simulation of molecular systems or random walks on graphs and it is different from the matrix completion approaches which try to approximate the transition matrix by using a low-rank-assumption. It will be shown how Markov chains can be analyzed on the basis of a partial sampling. More precisely. First, we will estimate the stationary distribution from a partially given matrix P. Second, we will estimate the infinitesimal generator Q of P on the basis of this stationary distribution. Third, from the generator we will compute the leading invariant subspace, which should be identical to the leading invariant subspace of P. Forth, we will apply Robust Perron Cluster Analysis (PCCA+ in order to identify metastabilities using this subspace.
Effect of shot peening on metastable austenitic stainless steels
International Nuclear Information System (INIS)
Fargas, G.; Roa, J.J.; Mateo, A.
2015-01-01
In this work, shot peening was performed in a metastable austenitic stainless steel EN 1.4318 (AISI 301LN) in order to evaluate its effect on austenite to martensite phase transformation and also the influence on the fatigue limit. Two different steel conditions were considered: annealed, i.e., with a fully austenitic microstructure, and cold rolled, consisting of a mixture of austenite and martensite. X-ray diffraction, electron back-scattered diffraction and focus ion beam, as well as nanoindentation techniques, were used to elucidate deformation mechanisms activated during shot peening and correlate with fatigue response. Results pointed out that extensive plastic deformation and phase transformation developed in annealed specimens as a consequence of shot peening. However, the increase of roughness and the generation of microcracks led to a limited fatigue limit improvement. In contrast, shot peened cold rolled specimens exhibited enhanced fatigue limit. In the latter case, the main factor that determined the influence on the fatigue response was the distance from the injector, followed successively by the exit speed of the shots and the coverage factor
Cosmic strings in a braneworld theory with metastable gravitons
International Nuclear Information System (INIS)
Lue, Arthur
2002-01-01
If the graviton possesses an arbitrarily small (but nonvanishing) mass, perturbation theory implies that cosmic strings have a nonzero Newtonian potential. Nevertheless in Einstein gravity, where the graviton is strictly massless, the Newtonian potential of a cosmic string vanishes. This discrepancy is an example of the van Dam-Veltman-Zakharov (VDVZ) discontinuity. We present a solution for the metric around a cosmic string in a braneworld theory with a graviton metastable on the brane. This theory possesses those features that yield a VDVZ discontinuity in massive gravity, but nevertheless is generally covariant and classically self-consistent. Although the cosmic string in this theory supports a nontrivial Newtonian potential far from the source, one can recover the Einstein solution in a region near the cosmic string. That latter region grows as the graviton's effective linewidth vanishes (analogous to a vanishing graviton mass), suggesting the lack of a VDVZ discontinuity in this theory. Moreover, the presence of scale dependent structure in the metric may have consequences for the search for cosmic strings through gravitational lensing techniques
Metastability in plyometric training on unstable surfaces: a pilot study
2014-01-01
Background In the past, plyometric training (PT) has been predominantly performed on stable surfaces. The purpose of this pilot study was to examine effects of a 7-week lower body PT on stable vs. unstable surfaces. This type of exercise condition may be denoted as metastable equilibrium. Methods Thirty-three physically active male sport science students (age: 24.1 ± 3.8 years) were randomly assigned to a PT group (n = 13) exercising on stable (STAB) and a PT group (n = 20) on unstable surfaces (INST). Both groups trained countermovement jumps, drop jumps, and practiced a hurdle jump course. In addition, high bar squats were performed. Physical fitness tests on stable surfaces (hexagonal obstacle test, countermovement jump, hurdle drop jump, left-right hop, dynamic and static balance tests, and leg extension strength) were used to examine the training effects. Results Significant main effects of time (ANOVA) were found for the countermovement jump, hurdle drop jump, hexagonal test, dynamic balance, and leg extension strength. A significant interaction of time and training mode was detected for the countermovement jump in favor of the INST group. No significant improvements were evident for either group in the left-right hop and in the static balance test. Conclusions These results show that lower body PT on unstable surfaces is a safe and efficient way to improve physical performance on stable surfaces. PMID:25089202
FPGA Implementation of Metastability-Based True Random Number Generator
Hata, Hisashi; Ichikawa, Shuichi
True random number generators (TRNGs) are important as a basis for computer security. Though there are some TRNGs composed of analog circuit, the use of digital circuits is desired for the application of TRNGs to logic LSIs. Some of the digital TRNGs utilize jitter in free-running ring oscillators as a source of entropy, which consume large power. Another type of TRNG exploits the metastability of a latch to generate entropy. Although this kind of TRNG has been mostly implemented with full-custom LSI technology, this study presents an implementation based on common FPGA technology. Our TRNG is comprised of logic gates only, and can be integrated in any kind of logic LSI. The RS latch in our TRNG is implemented as a hard-macro to guarantee the quality of randomness by minimizing the signal skew and load imbalance of internal nodes. To improve the quality and throughput, the output of 64-256 latches are XOR'ed. The derived design was verified on a Xilinx Virtex-4 FPGA (XC4VFX20), and passed NIST statistical test suite without post-processing. Our TRNG with 256 latches occupies 580 slices, while achieving 12.5Mbps throughput.
Maternal nutrition at conception modulates DNA methylation of human metastable epialleles
In experimental animals, maternal diet during the periconceptional period influences the establishment of DNA methylation at metastable epialleles in the offspring, with permanent phenotypic consequences. Pronounced naturally occurring seasonal differences in the diet of rural Gambian women allowed ...
Johnson; Thywissen; Dekker; Berggren; Chu; Younkin; Prentiss
1998-06-05
The spatially dependent de-excitation of a beam of metastable argon atoms, traveling through an optical standing wave, produced a periodic array of localized metastable atoms with position and momentum spreads approaching the limit stated by the Heisenberg uncertainty principle. Silicon and silicon dioxide substrates placed in the path of the atom beam were patterned by the metastable atoms. The de-excitation of metastable atoms upon collision with the surface promoted the deposition of a carbonaceous film from a vapor-phase hydrocarbon precursor. The resulting patterns were imaged both directly and after chemical etching. Thus, quantum-mechanical steady-state atom distributions can be used for sub-0.1-micrometer lithography.
Behavior of 23S metastable state He atoms in low-temperature recombining plasmas
Kajita, Shin; Tsujihara, Tadashi; Aramaki, Mitsutoshi; van der Meiden, Hennie; Oshima, Hiroshi; Ohno, Noriyasu; Tanaka, Hirohiko; Yasuhara, Ryo; Akiyama, Tsuyoshi; Fujii, Keisuke; Shikama, Taiichi
2017-07-01
We measured the electron density and temperature using laser Thomson scattering and metastable state (23S) of He atoms by laser absorption spectroscopy in the detached recombining plasmas in the divertor simulator NAGDIS-II. Using the measured electron density and temperature combined with the particle trajectory trace simulation, we discussed the behavior of the metastable state He atoms based on comparisons with the experimental results. It is shown that the metastable state atoms are mainly produced in the peripheral region of the plasma column, where the temperature is lower than the central part, and diffused in the vacuum vessel. It was shown that the 0D model is not valid and the transport of the metastable states is to be taken into account for the population distribution of He atoms in the detached plasmas.
Geometrical methods in learning theory
International Nuclear Information System (INIS)
Burdet, G.; Combe, Ph.; Nencka, H.
2001-01-01
The methods of information theory provide natural approaches to learning algorithms in the case of stochastic formal neural networks. Most of the classical techniques are based on some extremization principle. A geometrical interpretation of the associated algorithms provides a powerful tool for understanding the learning process and its stability and offers a framework for discussing possible new learning rules. An illustration is given using sequential and parallel learning in the Boltzmann machine
Geometric Results for Compressible Magnetohydrodynamics
Arter, Wayne
2013-01-01
Recently, compressible magnetohydrodynamics (MHD) has been elegantly formulated in terms of Lie derivatives. This paper exploits the geometrical properties of the Lie bracket to give new insights into the properties of compressible MHD behaviour, both with and without feedback of the magnetic field on the flow. These results are expected to be useful for the solution of MHD equations in both tokamak fusion experiments and space plasmas.
Geometric monodromy - Semisimplicity and maximality
Cadoret, Anna; Hui, Chun Yin; Tamagawa, Akio
2017-01-01
Let X be a connected scheme, smooth and separated over an alge- braically closed field k of characteristic p ≥ 0, let f: Y → X be a smooth proper morphism and x a geometric point on X. We prove that the tensor invariants of bounded length ≤ d of π1(X; x) acting on the étale cohomology groups H*(Yx;
Riemannian geometry and geometric analysis
Jost, Jürgen
2017-01-01
This established reference work continues to provide its readers with a gateway to some of the most interesting developments in contemporary geometry. It offers insight into a wide range of topics, including fundamental concepts of Riemannian geometry, such as geodesics, connections and curvature; the basic models and tools of geometric analysis, such as harmonic functions, forms, mappings, eigenvalues, the Dirac operator and the heat flow method; as well as the most important variational principles of theoretical physics, such as Yang-Mills, Ginzburg-Landau or the nonlinear sigma model of quantum field theory. The present volume connects all these topics in a systematic geometric framework. At the same time, it equips the reader with the working tools of the field and enables her or him to delve into geometric research. The 7th edition has been systematically reorganized and updated. Almost no page has been left unchanged. It also includes new material, for instance on symplectic geometry, as well as the B...
Polar metals by geometric design
Kim, T. H.; Puggioni, D.; Yuan, Y.; Xie, L.; Zhou, H.; Campbell, N.; Ryan, P. J.; Choi, Y.; Kim, J.-W.; Patzner, J. R.; Ryu, S.; Podkaminer, J. P.; Irwin, J.; Ma, Y.; Fennie, C. J.; Rzchowski, M. S.; Pan, X. Q.; Gopalan, V.; Rondinelli, J. M.; Eom, C. B.
2016-05-01
Gauss’s law dictates that the net electric field inside a conductor in electrostatic equilibrium is zero by effective charge screening; free carriers within a metal eliminate internal dipoles that may arise owing to asymmetric charge distributions. Quantum physics supports this view, demonstrating that delocalized electrons make a static macroscopic polarization, an ill-defined quantity in metals—it is exceedingly unusual to find a polar metal that exhibits long-range ordered dipoles owing to cooperative atomic displacements aligned from dipolar interactions as in insulating phases. Here we describe the quantum mechanical design and experimental realization of room-temperature polar metals in thin-film ANiO3 perovskite nickelates using a strategy based on atomic-scale control of inversion-preserving (centric) displacements. We predict with ab initio calculations that cooperative polar A cation displacements are geometrically stabilized with a non-equilibrium amplitude and tilt pattern of the corner-connected NiO6 octahedra—the structural signatures of perovskites—owing to geometric constraints imposed by the underlying substrate. Heteroepitaxial thin-films grown on LaAlO3 (111) substrates fulfil the design principles. We achieve both a conducting polar monoclinic oxide that is inaccessible in compositionally identical films grown on (001) substrates, and observe a hidden, previously unreported, non-equilibrium structure in thin-film geometries. We expect that the geometric stabilization approach will provide novel avenues for realizing new multifunctional materials with unusual coexisting properties.
International Nuclear Information System (INIS)
Jia Zhenglin; Mei Dongcheng
2011-01-01
We numerically investigate the influences of the time delay τ simultaneously existing in both the deterministic and fluctuating forces, the time delay τ r existing only in the fluctuating force and the cross-correlation strength λ on the enhancement of the mean first-passage time (MFPT) as a function of the additive D and the multiplicative α noise intensities in a metastable system. The results indicate that both the multiplicative and additive noises can induce the noise-enhanced stability (NES) effect. An increase of λ can enhance or weaken the NES effect induced by the additive noise, depending on the value of τ. However, it weakens the NES effect induced by the multiplicative noise with a suppression of the effect of λ caused by increasing τ. The τ-induced critical behavior on both NES effects can be observed, i.e. an increase of τ can enhance or restrain the NES effects induced by the two kinds of noises. With an increase of λ and τ, MFPT versus D shows a transition from one peak to two peaks and finally one peak, implying the multiple NES effect caused by λ and τ. An increase of τ r can enhance the NES effect induced by the additive noise and weaken the NES effect induced by the multiplicative noise.
An Information Geometric Analysis of Entangled Continuous Variable Quantum Systems
Energy Technology Data Exchange (ETDEWEB)
Kim, D-H [Institute for the Early Universe, Ewha Womans University, Seoul 120-750 (Korea, Republic of); Ali, S A [Department of Physics, State University of New York at Albany, 1400 Washington Avenue, Albany, NY 12222 (United States); Cafaro, C; Mancini, S [School of Science and Technology, Physics Division, University of Camerino, I-62032 Camerino (Italy)
2011-07-08
In this work, using information geometric (IG) techniques, we investigate the effects of micro-correlations on the evolution of maximal probability paths on statistical manifolds induced by systems whose microscopic degrees of freedom are Gaussian distributed. Analytical estimates of the information geometric entropy (IGE) as well as the IG analogue of the Lyapunov exponents are presented. It is shown that the entanglement duration is related to the scattering potential and incident particle energies. Finally, the degree of entanglement generated by an s-wave scattering event between minimum uncertainty wave-packets is computed in terms of the purity of the system.
Primary populations of metastable antiprotonic $^{4}He$ and $^{3}He$ atoms
Hori, Masaki; Hayano, R S; Ishikawa, T; Sakuguchi, J; Tasaki, T; Widmann, E; Yamaguchi, H; Torii, H A; Juhász, B; Horváth, D; Yamazaki, T
2002-01-01
Initial population distributions of metastable antiprotonic **4He and **3He atoms over principal and angular momentum quantum numbers were investigated using laser spectroscopy. The total fractions of antiprotons captured into the metastable states of the atoms were deduced. Cascade calculations were performed using the measure populations to reproduce the delayed annihilation time spectrum. Results showed agreement between the simulated and measured spectra. (Edited abstract) 30 Refs.
Material Characterization of Fatigue Specimens made from Meta-stable Austenitic Stainless Steel
Energy Technology Data Exchange (ETDEWEB)
Niffenegger, M.; Grosse, M.; Kalkhof, D.; Leber, H. [Paul Scherrer Institut Villigen (Switzerland); Vincent, A.; Pasco, L.; Morin, M. [Insa de Lyon (France)
2003-07-01
The main objective of the EU-project CRETE (Contract No.: FIS5-1999-00280) was to assess the capability and the reliability of innovative NDT-inspection techniques for the detection of material degradation, induced by thermal fatigue and neutron irradiation, of metastable austenitic and ferritic low-alloy steel. Several project partners tested aged or irradiated samples, using various techniques (acoustic, magnetic and thermoelectric). However, these indirect methods require a careful interpretation of the measured signal in terms of micro-structural evolutions due to ageing of the material. Therefore the material had to be characterized in its undamaged, as well as in its damaged state. The present report summarises only the material characterization of the fatigue specimens. It is issued simultaneously as an PSI Bericht and the CRETE work package 3 (WP3) report. Each partner according to their own specifications purchased three materials under investigation, namely AISI 347, AISI 321 and AISI 304L. After sending the material to PSI, all fatigue specimens were manufactured by the same Swiss company. Each partner was responsible for his fatigue tests which are documented in the report WP1, written by FANP. In order to characterize the material in its unfatigued as well as in its fatigued state and to consider microstructural changes related to fatigue damage the methods listed below were employed either by PSI or by INSA de Lyon: (1) Inductive Coupled Plasma Emission Photometry (ICP-OES) was applied to determine the chemical composition, (2) Scanning electron microscopy (SEM) for observing cracks, slip bands between grain and twin boundaries, - Ferromaster for measuring the magnetic permeability, (3) Physical Properties Measuring System (PPMS) for measuring magnetization characteristics, (4) Neutron- and advanced X-ray diffraction methods for the quantitative determination of martensite, - Transmission electron microscopy (TEM) for the observation of crystalline
Directory of Open Access Journals (Sweden)
Charles West
2005-12-01
Full Text Available Metastable austenitic stainless steels are known to undergo a partial transformation of austenite to martensite as a consequence of plastic deformation. In the case of cyclic loading, a certain level of plastic strain must be exceeded, and phase formation takes place after an incubation period, during which the necessary amount of plastic deformation is accumulated. The susceptibility of the austenitic phase to deformation-induced martensite formation is strongly affected by the temperature of loading and the stability of austenite, which itself depends on the chemical composition. A key element in this regard is carbon which stabilizes the austenitic phase. It is shown in this study that the carbon concentration can be analysed systematically and reproducible by means of annealing treatments, if the parameters of these treatments are carefully defined on the basis of advanced theoretical thermodynamic and kinetic considerations. First results on the effect of carbon concentration and temperature of fatigue testing on the austenite/martensite transformation are presented, in order to illustrate the significance of these parameters on the martensite formation rate.
Metastable states and quasicycles in a stochastic Wilson-Cowan model of neuronal population dynamics
Bressloff, Paul C.
2010-11-03
We analyze a stochastic model of neuronal population dynamics with intrinsic noise. In the thermodynamic limit N→∞, where N determines the size of each population, the dynamics is described by deterministic Wilson-Cowan equations. On the other hand, for finite N the dynamics is described by a master equation that determines the probability of spiking activity within each population. We first consider a single excitatory population that exhibits bistability in the deterministic limit. The steady-state probability distribution of the stochastic network has maxima at points corresponding to the stable fixed points of the deterministic network; the relative weighting of the two maxima depends on the system size. For large but finite N, we calculate the exponentially small rate of noise-induced transitions between the resulting metastable states using a Wentzel-Kramers- Brillouin (WKB) approximation and matched asymptotic expansions. We then consider a two-population excitatory or inhibitory network that supports limit cycle oscillations. Using a diffusion approximation, we reduce the dynamics to a neural Langevin equation, and show how the intrinsic noise amplifies subthreshold oscillations (quasicycles). © 2010 The American Physical Society.
Energy barriers between metastable states in first-order quantum phase transitions
Wald, Sascha; Timpanaro, André M.; Cormick, Cecilia; Landi, Gabriel T.
2018-02-01
A system of neutral atoms trapped in an optical lattice and dispersively coupled to the field of an optical cavity can realize a variation of the Bose-Hubbard model with infinite-range interactions. This model exhibits a first-order quantum phase transition between a Mott insulator and a charge density wave, with spontaneous symmetry breaking between even and odd sites, as was recently observed experimentally [Landig et al., Nature (London) 532, 476 (2016), 10.1038/nature17409]. In the present paper, we approach the analysis of this transition using a variational model which allows us to establish the notion of an energy barrier separating the two phases. Using a discrete WKB method, we then show that the local tunneling of atoms between adjacent sites lowers this energy barrier and hence facilitates the transition. Within our simplified description, we are thus able to augment the phase diagram of the model with information concerning the height of the barrier separating the metastable minima from the global minimum in each phase, which is an essential aspect for the understanding of the reconfiguration dynamics induced by a quench across a quantum critical point.
Energetics and metastability of the adenine dication observed in proton-adenine collisions
Moretto-Capelle, Patrick; Le Padellec, Arnaud; Brière, Guillaume; Massou, Sophie; Franceries, Frédéric
2007-12-01
We present here a study that deals with the correlated fragmentation of a doubly charged adenine molecular target induced by a 100keV proton beam. We have elucidated part of the dissociation dynamics for several channels and have obtained the corresponding kinetic energy released values. We have extracted activation energies by combining our experimental data with computations using the ab initio GAMESS code. We have observed metastability patterns against fragmentation, for which we have extracted the temporal mechanism (one or two steps). Subsequently, we have obtained lifetimes in the 100-200ns range. In the simplest case of two-body fragmentation with the emission of mass 28, the determination of transition states and reaction paths has showed that emission of the H-C-N-H fragment is preferred to that of C -N-H2. From the calculated activation barriers and lifetimes, we have deduced an equivalent temperature of the dication that we have compared with the existing models.
Noncyclic geometric changes of quantum states
International Nuclear Information System (INIS)
Kult, David; Sjoeqvist, Erik; Aaberg, Johan
2006-01-01
Non-Abelian quantum holonomies, i.e., unitary state changes solely induced by geometric properties of a quantum system, have been much under focus in the physics community as generalizations of the Abelian Berry phase. Apart from being a general phenomenon displayed in various subfields of quantum physics, the use of holonomies has lately been suggested as a robust technique to obtain quantum gates; the building blocks of quantum computers. Non-Abelian holonomies are usually associated with cyclic changes of quantum systems, but here we consider a generalization to noncyclic evolutions. We argue that this open-path holonomy can be used to construct quantum gates. We also show that a structure of partially defined holonomies emerges from the open-path holonomy. This structure has no counterpart in the Abelian setting. We illustrate the general ideas using an example that may be accessible to tests in various physical systems
Geometric regularizations and dual conifold transitions
International Nuclear Information System (INIS)
Landsteiner, Karl; Lazaroiu, Calin I.
2003-01-01
We consider a geometric regularization for the class of conifold transitions relating D-brane systems on noncompact Calabi-Yau spaces to certain flux backgrounds. This regularization respects the SL(2,Z) invariance of the flux superpotential, and allows for computation of the relevant periods through the method of Picard-Fuchs equations. The regularized geometry is a noncompact Calabi-Yau which can be viewed as a monodromic fibration, with the nontrivial monodromy being induced by the regulator. It reduces to the original, non-monodromic background when the regulator is removed. Using this regularization, we discuss the simple case of the local conifold, and show how the relevant field-theoretic information can be extracted in this approach. (author)
Characteristic signatures of quantum criticality driven by geometrical frustration.
Tokiwa, Yoshifumi; Stingl, Christian; Kim, Moo-Sung; Takabatake, Toshiro; Gegenwart, Philipp
2015-04-01
Geometrical frustration describes situations where interactions are incompatible with the lattice geometry and stabilizes exotic phases such as spin liquids. Whether geometrical frustration of magnetic interactions in metals can induce unconventional quantum critical points is an active area of research. We focus on the hexagonal heavy fermion metal CeRhSn, where the Kondo ions are located on distorted kagome planes stacked along the c axis. Low-temperature specific heat, thermal expansion, and magnetic Grüneisen parameter measurements prove a zero-field quantum critical point. The linear thermal expansion, which measures the initial uniaxial pressure derivative of the entropy, displays a striking anisotropy. Critical and noncritical behaviors along and perpendicular to the kagome planes, respectively, prove that quantum criticality is driven be geometrical frustration. We also discovered a spin flop-type metamagnetic crossover. This excludes an itinerant scenario and suggests that quantum criticality is related to local moments in a spin liquid-like state.
Magnetic Evidence for Metastable Ferrihydrite Particles in a Vertisol
Gehring, A. U.; Schill, E.; Weidler, P. G.; Luster, J.
2004-12-01
Poorly crystalline iron oxides in soils are of ecological importance since their chemical properties (e.g. solubility, surface area and reactivity) affect the bioavailability of iron and promote processes such as adsorption and transport of metals, pesticides, and organic nutrients. In natural environments these highly reactive phases are difficult to detect because they form generally a minor component with a nano-sized nature. Ferrihydrite is the best known phase among these materials with ambiguous identity. For the magnetic and soil-chemical investigation a Vertisol in southern Mali was chosen. Southern Mali has a subtropical climate with a wet and a dry season, an annual rainfall of 1300mm, and an average temperature of 27° C. The Vertisol mainly consists of montmorillonite and quartz, and no iron oxides were detected by X-ray diffractometry. It has a relatively high amount of oxalate extractable Fe and reveals a strong increase of IRM acquisition at 77K compared to room temperature. In order to characterize the low temperature magnetic phase, AC susceptibility frequency experiments on bulk samples were conducted between 2 and 300K with 10 and 1000Hz. The in-phase susceptibility exhibited an increase at 120K followed by two peaks at 65 and 35K and a steep increase at 25K. In the temperature range of the peaks a clear frequency dependency was observed. The out-of-phase component revealed a similar behavior with a more pronounced frequency dependency below 65K. The beginning of magnetic ordering in the out-of-phase component at about 120K and the two peaks are assigned to two ferrihydrites with different magnetic properties. After oven-drying the bulk samples at 60° C, the two peaks had vanished. This behavior suggests that ferrihydrites are metastable and convert into a thermodynamically more stable phase.
Population dynamics of metastable growth-rate phenotypes.
Directory of Open Access Journals (Sweden)
Lindsay S Moore
Full Text Available Neo-Darwinian evolution has presented a paradigm for population dynamics built on random mutations and selection with a clear separation of time-scales between single-cell mutation rates and the rate of reproduction. Laboratory experiments on evolving populations until now have concentrated on the fixation of beneficial mutations. Following the Darwinian paradigm, these experiments probed populations at low temporal resolution dictated by the rate of rare mutations, ignoring the intermediate evolving phenotypes. Selection however, works on phenotypes rather than genotypes. Research in recent years has uncovered the complexity of genotype-to-phenotype transformation and a wealth of intracellular processes including epigenetic inheritance, which operate on a wide range of time-scales. Here, by studying the adaptation dynamics of genetically rewired yeast cells, we show a novel type of population dynamics in which the intracellular processes intervene in shaping the population structure. Under constant environmental conditions, we measure a wide distribution of growth rates that coexist in the population for very long durations (>100 generations. Remarkably, the fastest growing cells do not take over the population on the time-scale dictated by the width of the growth-rate distributions and simple selection. Additionally, we measure significant fluctuations in the population distribution of various phenotypes: the fraction of exponentially-growing cells, the distributions of single-cell growth-rates and protein content. The observed fluctuations relax on time-scales of many generations and thus do not reflect noisy processes. Rather, our data show that the phenotypic state of the cells, including the growth-rate, for large populations in a constant environment is metastable and varies on time-scales that reflect the importance of long-term intracellular processes in shaping the population structure. This lack of time-scale separation between the
Metastable structures and size effects in small group dynamics
Directory of Open Access Journals (Sweden)
Rosapia eLauro Grotto
2014-07-01
Full Text Available In his seminal works on group dynamics Bion defined a specific therapeutic setting allowing psychoanalytic observations on group phenomena. In describing the setting he proposed that the group was where his voice arrived. This physical limit was later made operative by assuming that the natural dimension of a therapeutic group is around 12 people. Bion introduced a theory of the group aspects of the mind in which proto-mental individual states spontaneously evolve into shared psychological states that are characterized by a series of features: 1 they emerge as a consequence of the natural tendency of (both conscious and unconscious emotions to combine into structured group patterns; 2 they have a certain degree of stability in time; 3 they tend to alternate so that the dissolution of one is rapidly followed by the emergence of another; 4 they can be described in qualitative terms according to the nature of the emotional mix that dominates the state, in structural terms by a kind of typical 'leadership’ pattern, and in 'cognitive’ terms by a set of implicit expectations that are helpful in explaining the group behavior (i.e. the group behaves 'as if’ it was assuming that…. Here we adopt a formal approach derived from Socio-physics in order to explore some of the structural and dynamic properties of this small group dynamics. We will described data from an analytic DS model simulating small group interactions of agents endowed with a very simplified emotional and cognitive dynamic in order to assess the following main points: 1 are metastable collective states allowed to emerge in the model and if so, under which conditions in the parameter space? 3 can these states be differentiated in structural terms? 3 to what extent are the emergent dynamic features of the systems dependent of the system size? We will finally discuss possible future applications of the quantitative descriptions of the interaction structure in the small group clinical
Metastable structures and size effects in small group dynamics.
Lauro Grotto, Rosapia; Guazzini, Andrea; Bagnoli, Franco
2014-01-01
In his seminal works on group dynamics Bion defined a specific therapeutic setting allowing psychoanalytic observations on group phenomena. In describing the setting he proposed that the group was where his voice arrived. This physical limit was later made operative by assuming that the natural dimension of a therapeutic group is around 12 people. Bion introduced a theory of the group aspects of the mind in which proto-mental individual states spontaneously evolve into shared psychological states that are characterized by a series of features: (1) they emerge as a consequence of the natural tendency of (both conscious and unconscious) emotions to combine into structured group patterns; (2) they have a certain degree of stability in time; (3) they tend to alternate so that the dissolution of one is rapidly followed by the emergence of another; (4) they can be described in qualitative terms according to the nature of the emotional mix that dominates the state, in structural terms by a kind of typical "leadership" pattern, and in "cognitive" terms by a set of implicit expectations that are helpful in explaining the group behavior (i.e., the group behaves "as if" it was assuming that). Here we adopt a formal approach derived from Socio-physics in order to explore some of the structural and dynamic properties of this small group dynamics. We will described data from an analytic DS model simulating small group interactions of agents endowed with a very simplified emotional and cognitive dynamic in order to assess the following main points: (1) are metastable collective states allowed to emerge in the model and if so, under which conditions in the parameter space? (2) can these states be differentiated in structural terms? (3) to what extent are the emergent dynamic features of the systems dependent of the system size? We will finally discuss possible future applications of the quantitative descriptions of the interaction structure in the small group clinical setting.
Metastable states and energy flow pathway in square graphene resonators
Wang, Yisen; Zhu, Zhigang; Zhang, Yong; Huang, Liang
2018-01-01
Nonlinear interaction between flexural modes is critical to heat conductivity and mechanical vibration of two-dimensional materials such as graphene. Much effort has been devoted to understand the underlying mechanism. In this paper, we examine solely the out-of-plane flexural modes and identify their energy flow pathway during thermalization process. The key is the development of a universal scheme that numerically characterizes the strength of nonlinear interactions between normal modes. In particular, for our square graphene system, the modes are grouped into four classes by their distinct symmetries. The couplings are significantly larger within a class than between classes. As a result, the equations for the normal modes in the same class as the initially excited one can be approximated by driven harmonic oscillators, therefore, they get energy almost instantaneously. Because of the hierarchical organization of the mode coupling, the energy distribution among the modes will arrive at a stable profile, where most of the energy is localized on a few modes, leading to the formation of "natural package" and metastable states. The dynamics for modes in other symmetry classes follows a Mathieu type of equation, thus, interclass energy flow, when the initial excitation energy is small, starts typically when there is a mode that lies in the unstable region in the parameter space of Mathieu equation. Due to strong coupling of the modes inside the class, the whole class will get energy and be lifted up by the unstable mode. This characterizes the energy flow pathway of the system. These results bring fundamental understandings to the Fermi-Pasta-Ulam problem in two-dimensional systems with complex potentials, and reveal clearly the physical picture of dynamical interactions between the flexural modes, which will be crucial to the understanding of their abnormal contribution to heat conduction and nonlinear mechanical vibrations.
Metastability and reliability of CdTe solar cells
Guo, Da; Brinkman, Daniel; Shaik, Abdul R.; Ringhofer, Christian; Vasileska, Dragica
2018-04-01
Thin-film modules of all technologies often suffer from performance degradation over time. Some of the performance changes are reversible and some are not, which makes deployment, testing, and energy-yield prediction more challenging. Manufacturers devote significant empirical efforts to study these phenomena and to improve semiconductor device stability. Still, understanding the underlying reasons of these instabilities remains clouded due to the lack of ability to characterize materials at atomistic levels and the lack of interpretation from the most fundamental material science. The most commonly alleged causes of metastability in CdTe devices, such as ‘migration of Cu’, have been investigated rigorously over the past fifteen years. Still, the discussion often ended prematurely with stating observed correlations between stress conditions and changes in atomic profiles of impurities or CV doping concentration. Multiple hypotheses suggesting degradation of CdTe solar cell devices due to interaction and evolution of point defects and complexes were proposed, and none of them received strong theoretical or experimental confirmation. It should be noted that atomic impurity profiles in CdTe provide very little intelligence on active doping concentrations. The same elements could form different energy states, which could be either donors or acceptors, depending on their position in crystalline lattice. Defects interact with other extrinsic and intrinsic defects; for example, changing the state of an impurity from an interstitial donor to a substitutional acceptor often is accompanied by generation of a compensating intrinsic interstitial donor defect. Moreover, all defects, intrinsic and extrinsic, interact with the electrical potential and free carriers so that charged defects may drift in the electric field and the local electrical potential affects the formation energy of the point defects. Such complexity of interactions in CdTe makes understanding of temporal
Geometric phase from dielectric matrix
International Nuclear Information System (INIS)
Banerjee, D.
2005-10-01
The dielectric property of the anisotropic optical medium is found by considering the polarized photon as two component spinor of spherical harmonics. The Geometric Phase of a polarized photon has been evaluated in two ways: the phase two-form of the dielectric matrix through a twist and the Pancharatnam phase (GP) by changing the angular momentum of the incident polarized photon over a closed triangular path on the extended Poincare sphere. The helicity in connection with the spin angular momentum of the chiral photon plays the key role in developing these phase holonomies. (author)
Field guide to geometrical optics
Greivenkamp, John E
2004-01-01
This Field Guide derives from the treatment of geometrical optics that has evolved from both the undergraduate and graduate programs at the Optical Sciences Center at the University of Arizona. The development is both rigorous and complete, and it features a consistent notation and sign convention. This volume covers Gaussian imagery, paraxial optics, first-order optical system design, system examples, illumination, chromatic effects, and an introduction to aberrations. The appendices provide supplemental material on radiometry and photometry, the human eye, and several other topics.
Geometric Computations On Indecisive Points
DEFF Research Database (Denmark)
Jørgensen, Allan Grønlund; Phillips, Jeff; Loffler, Maarten
2011-01-01
We study computing with indecisive point sets. Such points have spatial uncertainty where the true location is one of a finite number of possible locations. This data arises from probing distributions a few times or when the location is one of a few locations from a known database. In particular......, we study computing distributions of geometric functions such as the radius of the smallest enclosing ball and the diameter. Surprisingly, we can compute the distribution of the radius of the smallest enclosing ball exactly in polynomial time, but computing the same distribution for the diameter is #P...
Geometric Rationalization for Freeform Architecture
Jiang, Caigui
2016-06-20
The emergence of freeform architecture provides interesting geometric challenges with regards to the design and manufacturing of large-scale structures. To design these architectural structures, we have to consider two types of constraints. First, aesthetic constraints are important because the buildings have to be visually impressive. Sec- ond, functional constraints are important for the performance of a building and its e cient construction. This thesis contributes to the area of architectural geometry. Specifically, we are interested in the geometric rationalization of freeform architec- ture with the goal of combining aesthetic and functional constraints and construction requirements. Aesthetic requirements typically come from designers and architects. To obtain visually pleasing structures, they favor smoothness of the building shape, but also smoothness of the visible patterns on the surface. Functional requirements typically come from the engineers involved in the construction process. For exam- ple, covering freeform structures using planar panels is much cheaper than using non-planar ones. Further, constructed buildings have to be stable and should not collapse. In this thesis, we explore the geometric rationalization of freeform archi- tecture using four specific example problems inspired by real life applications. We achieve our results by developing optimization algorithms and a theoretical study of the underlying geometrical structure of the problems. The four example problems are the following: (1) The design of shading and lighting systems which are torsion-free structures with planar beams based on quad meshes. They satisfy the functionality requirements of preventing light from going inside a building as shad- ing systems or reflecting light into a building as lighting systems. (2) The Design of freeform honeycomb structures that are constructed based on hex-dominant meshes with a planar beam mounted along each edge. The beams intersect without
A history of geometrical methods
Coolidge, Julian Lowell
2013-01-01
Full and authoritative, this history of the techniques for dealing with geometric questions begins with synthetic geometry and its origins in Babylonian and Egyptian mathematics; reviews the contributions of China, Japan, India, and Greece; and discusses the non-Euclidean geometries. Subsequent sections cover algebraic geometry, starting with the precursors and advancing to the great awakening with Descartes; and differential geometry, from the early work of Huygens and Newton to projective and absolute differential geometry. The author's emphasis on proofs and notations, his comparisons betwe
Energy Technology Data Exchange (ETDEWEB)
Filipek, S.M., E-mail: sfilipek@unipress.waw.pl [Institute of High Pressure Physics PAS, ul. Sokolowska 29, 01-142 Warsaw (Poland); Paul-Boncour, V. [ICMPE-CMTR, CNRS-UPEC, 2-8 rue Henri Dunant, 94320 Thiais (France); Liu, R.S. [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Jacob, I. [Unit Nuclear Eng., Ben Gurion University of the Negev, Beer-Sheva (Israel); Tsutaoka, T. [Dept. of Sci. Educ., Grad. School of Educ., Hiroshima University, Hiroshima (Japan); Budziak, A. [Institute of Nuclear Physics PAS, 31-342 Kraków (Poland); Morawski, A. [Institute of High Pressure Physics PAS, ul. Sokolowska 29, 01-142 Warsaw (Poland); Sugiura, H. [Yokohama City University, 22-2 Seto, Kanazawa-ku, Yokohama 236-0027 (Japan); Zachariasz, P. [Institute of Electron Technology Cracow Division, ul. Zablocie 39, 30-701 Krakow (Poland); Dybko, K. [Institute of Physics, PAS, 02-668 Warsaw (Poland); Diduszko, R. [Tele and Radio Research Institute, ul. Ratuszowa 11, Warsaw (Poland)
2016-12-01
Brief summary of our former work on high hydrogen pressure syntheses of novel hydrides and studies of their properties is supplemented with new results. Syntheses and properties of a number of hydrides (unstable, metastable or stable in ambient conditions) derived under high hydrogen pressure from intermetallic compounds, like MeT{sub 2}, MeNi{sub 5}, Me{sub 7}T{sub 3}, Y{sub 6}Mn{sub 23} and YMn{sub 12} (where Me = zirconium, yttrium or rare earth; T = transition metal) are presented. Stabilization of ZrFe{sub 2}H{sub 4} due to surface phenomena was revealed. Unusual role of manganese in hydride forming processes is pointed out. Hydrogen induced phase transitions, suppression of magnetism, antiferromagnetic-ferromagnetic and metal-insulator or semimetal-metal transitions are described. Equations of state (EOS) of hydrides submitted to hydrostatic pressures up to 30 GPa are presented and discussed.
Image understanding using geometric context
Zhang, Xiaochun; Liu, Chuancai
2017-07-01
A Gibbs Sampler based topic model for image annotation, which takes into account the interaction between visual geometric context and related topic, is presented. Most of the existing topic models for scene annotation use segmentation-based algorithm. However, topic models using segmentation algorithm alone sometimes can produce erroneous results when used to annotate real-life scene pictures. Therefore, our algorithm makes use of peaks of image surface instead of segmentation regions. Existing approaches use SIFT algorithm and treat the peaks as round blob features. In this paper, the peaks are treated as anisotropic blob features, which models low level visual elements more precisely. In order to better utilize visual features, our model not only takes into consideration visual codeword, but also considers influence of visual properties to topic formation, such as orientation, width, length and color. The basic idea is based on the assumption that different topics will produce distinct visual appearance, and different visual appearance is helpful to distinguish topics. During the learning stage, each topic will be associated with a set of distributions of visual properties, which depicts appearance of the topic. This paper considers more geometric properties, which will reduce topic uncertainty and learn the images better. Tested with Corel5K, SAIAPR-TC12 and Espgame100k Datasets, our method performs moderately better than some state of the arts methods.
Formation of Kinetically Trapped Nanoscopic Unilamellar Vesicles from Metastable Nanodiscs
Energy Technology Data Exchange (ETDEWEB)
Nieh, Mu-Ping [Univ. of Connecticut, Storrs, CT (United States). Inst. of Materials Science, Dept. of Chemical, Materials & Biomolecular Engineering; Dolinar, Paul [Univ. of Ottawa, ON (Canada); Kucerka, Norbert [National Research Council, Chalk River, ON (Canada). Chalk River Lab., Canadian Neutron Beam Centre; Comenius Univ., Bratislava (Slovakia). Dept. of Physical Chemistry of Drugs; Kline, Steven R. [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Debeer-Schmitt, Lisa M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division; Littrell, Kenneth C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division; Katsaras, John [National Research Council, Chalk River, ON (Canada). Chalk River Lab., Canadian Neutron Beam Centre; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division; Brock Univ., St. Catharines, ON (Canada). Dept. of Physics; Univ. of Guelph, ON (Canada). Guelph-Waterloo Physics Inst.
2011-09-27
Zwitterionic long-chain lipids (e.g., dimyristoyl phosphatidylcholine, DMPC) spontaneously form onion-like, thermodynamically stable structures in aqueous solutions (commonly known as multilamellar vesicles, or MLVs). It has also been reported that the addition of zwitterionic short-chain (i.e., dihexanoyl phosphatidylcholine, DHPC) and charged long-chain (i.e., dimyristoyl phosphatidylglycerol, DMPG) lipids to zwitterionic long-chain lipid solutions results in the formation of unilamellar vesicles (ULVs). Here, we report a kinetic study on lipid mixtures composed of DMPC, DHPC, and DMPG. Two membrane charge densities (i.e., [DMPG]/[DMPC] = 0.01 and 0.001) and two solution salinities (i.e., [NaCl] = 0 and 0.2 M) are investigated. Upon dilution of the high-concentration samples at 50 °C, thermodynamically stable MLVs are formed, in the case of both weakly charged and high salinity solution mixtures, implying that the electrostatic interactions between bilayers are insufficient to cause MLVs to unbind. Importantly, in the case of these samples small angle neutron scattering (SANS) data show that, initially, nanodiscs (also known as bicelles) or bilayered ribbons form at low temperatures (i.e., 10 °C), but transform into uniform size, nanoscopic ULVs after incubation at 10 °C for 20 h, indicating that the nanodisc is a metastable structure. The instability of nanodiscs may be attributed to low membrane rigidity due to a reduced charge density and high salinity. Moreover, the uniform-sized ULVs persist even after being heated to 50 °C, where thermodynamically stable MLVs are observed. This result clearly demonstrates that these ULVs are kinetically trapped, and that the mechanical properties (e.g., bending rigidity) of 10 C nanodiscs favor the formation of nanoscopic ULVs over that of MLVs. From a practical point of view, this method of forming uniform-sized ULVs may lend itself to their mass production, thus making them economically feasible for medical
Calculation of the relative metastabilities of proteins using the CHNOSZ software package
Directory of Open Access Journals (Sweden)
Dick Jeffrey M
2008-10-01
Full Text Available Abstract Background Proteins of various compositions are required by organisms inhabiting different environments. The energetic demands for protein formation are a function of the compositions of proteins as well as geochemical variables including temperature, pressure, oxygen fugacity and pH. The purpose of this study was to explore the dependence of metastable equilibrium states of protein systems on changes in the geochemical variables. Results A software package called CHNOSZ implementing the revised Helgeson-Kirkham-Flowers (HKF equations of state and group additivity for ionized unfolded aqueous proteins was developed. The program can be used to calculate standard molal Gibbs energies and other thermodynamic properties of reactions and to make chemical speciation and predominance diagrams that represent the metastable equilibrium distributions of proteins. The approach takes account of the chemical affinities of reactions in open systems characterized by the chemical potentials of basis species. The thermodynamic database included with the package permits application of the software to mineral and other inorganic systems as well as systems of proteins or other biomolecules. Conclusion Metastable equilibrium activity diagrams were generated for model cell-surface proteins from archaea and bacteria adapted to growth in environments that differ in temperature and chemical conditions. The predicted metastable equilibrium distributions of the proteins can be compared with the optimal growth temperatures of the organisms and with geochemical variables. The results suggest that a thermodynamic assessment of protein metastability may be useful for integrating bio- and geochemical observations.
Geometrical charged-particle optics
Rose, Harald
2012-01-01
This second edition is an extended version of the first edition of Geometrical Charged-Particle Optics. The updated reference monograph is intended as a guide for researchers and graduate students who are seeking a comprehensive treatment of the design of instruments and beam-guiding systems of charged particles and their propagation in electromagnetic fields. Wave aspects are included in this edition for explaining electron holography, the Aharanov-Bohm effect and the resolution of electron microscopes limited by diffraction. Several methods for calculating the electromagnetic field are presented and procedures are outlined for calculating the properties of systems with arbitrarily curved axis. Detailed methods are presented for designing and optimizing special components such as aberration correctors, spectrometers, energy filters monochromators, ion traps, electron mirrors and cathode lenses. In particular, the optics of rotationally symmetric lenses, quadrupoles, and systems composed of these elements are...
Geometric Operators on Boolean Functions
DEFF Research Database (Denmark)
Frisvad, Jeppe Revall; Falster, Peter
In truth-functional propositional logic, any propositional formula represents a Boolean function (according to some valuation of the formula). We describe operators based on Decartes' concept of constructing coordinate systems, for translation of a propositional formula to the image of a Boolean...... function. With this image of a Boolean function corresponding to a propositional formula, we prove that the orthogonal projection operator leads to a theorem describing all rules of inference in propositional reasoning. In other words, we can capture all kinds of inference in propositional logic by means...... of a few geometric operators working on the images of Boolean functions. The operators we describe, arise from the niche area of array-based logic and have previously been tightly bound to an array-based representation of Boolean functions. We redefine the operators in an abstract form to make them...
Geometrical charged-particle optics
Rose, Harald H
2009-01-01
This reference monograph covers all theoretical aspects of modern geometrical charged-particle optics. It is intended as a guide for researchers, who are involved in the design of electron optical instruments and beam-guiding systems for charged particles, and as a tutorial for graduate students seeking a comprehensive treatment. Procedures for calculating the properties of systems with arbitrarily curved axes are outlined in detail and methods are discussed for designing and optimizing special components such as aberration correctors, spectrometers, energy filters, monochromators, ion traps, electron mirrors and cathode lenses. Also addressed is the design of novel electron optical components enabling sub-Angstroem spatial resolution and sub-0.1eV energy resolution. Relativistic motion and spin precession of the electron is treated in a concise way by employing a covariant five-dimensional procedure.
Geometric Methods in Physics XXXV
Odzijewicz, Anatol; Previato, Emma
2018-01-01
This book features a selection of articles based on the XXXV Białowieża Workshop on Geometric Methods in Physics, 2016. The series of Białowieża workshops, attended by a community of experts at the crossroads of mathematics and physics, is a major annual event in the field. The works in this book, based on presentations given at the workshop, are previously unpublished, at the cutting edge of current research, typically grounded in geometry and analysis, and with applications to classical and quantum physics. In 2016 the special session "Integrability and Geometry" in particular attracted pioneers and leading specialists in the field. Traditionally, the Białowieża Workshop is followed by a School on Geometry and Physics, for advanced graduate students and early-career researchers, and the book also includes extended abstracts of the lecture series.
Geometric algebra in plasma electrodynamics
Resendes, D. P.; Resendes
2013-10-01
Geometric algebra (GA) is a recent broad mathematical framework incorporating synthetic and coordinate geometry, complex variables, quarternions, vector analysis, matrix algebra, spinors, tensors, and differential forms. It has been claimed to be a unified language for physics. GA is presented in the context of the Maxwell-Plasma system. In this formalism the divergence and curl differential operators are united in a single vector derivative, which is invertible, in the form of a first-order Green function. The four Maxwell equations can be combined into a single equation (for homogeneous and constant media) or into two equations involving the invertible vector derivative for more complex media. GA is applied to simple examples to illustrate the compactness of the notation and coordinate-free computations.
Self-organizing human cardiac microchambers mediated by geometric confinement
Ma, Zhen; Wang, Jason; Loskill, Peter; Huebsch, Nathaniel; Koo, Sangmo; Svedlund, Felicia L.; Marks, Natalie C.; Hua, Ethan W.; Grigoropoulos, Costas P.; Conklin, Bruce R.; Healy, Kevin E.
2015-07-01
Tissue morphogenesis and organ formation are the consequences of biochemical and biophysical cues that lead to cellular spatial patterning in development. To model such events in vitro, we use PEG-patterned substrates to geometrically confine human pluripotent stem cell colonies and spatially present mechanical stress. Modulation of the WNT/β-catenin pathway promotes spatial patterning via geometric confinement of the cell condensation process during epithelial-mesenchymal transition, forcing cells at the perimeter to express an OCT4+ annulus, which is coincident with a region of higher cell density and E-cadherin expression. The biochemical and biophysical cues synergistically induce self-organizing lineage specification and creation of a beating human cardiac microchamber confined by the pattern geometry. These highly defined human cardiac microchambers can be used to study aspects of embryonic spatial patterning, early cardiac development and drug-induced developmental toxicity.
Geometric solitons of Hamiltonian flows on manifolds
Energy Technology Data Exchange (ETDEWEB)
Song, Chong, E-mail: songchong@xmu.edu.cn [School of Mathematical Sciences, Xiamen University, Xiamen 361005 (China); Sun, Xiaowei, E-mail: sunxw@cufe.edu.cn [School of Applied Mathematics, Central University of Finance and Economics, Beijing 100081 (China); Wang, Youde, E-mail: wyd@math.ac.cn [Academy of Mathematics and Systems Science, Chinese Academy of Sciences, Beijing 100190 (China)
2013-12-15
It is well-known that the LIE (Locally Induction Equation) admit soliton-type solutions and same soliton solutions arise from different and apparently irrelevant physical models. By comparing the solitons of LIE and Killing magnetic geodesics, we observe that these solitons are essentially decided by two families of isometries of the domain and the target space, respectively. With this insight, we propose the new concept of geometric solitons of Hamiltonian flows on manifolds, such as geometric Schrödinger flows and KdV flows for maps. Moreover, we give several examples of geometric solitons of the Schrödinger flow and geometric KdV flow, including magnetic curves as geometric Schrödinger solitons and explicit geometric KdV solitons on surfaces of revolution.
Metastable decay of argon clusters after photoionisation at high excess energies
International Nuclear Information System (INIS)
Steger, H.; Vries, J. de; Kamke, W.; Hertel, I.V.
1991-01-01
Recently Maerk and collaborators reported the metastable emission of large fractions from argon and neon cluster ions after electron impact ionisation at high excess energies. The decay was interpreted as the result of an intra-cluster excitation of a metastable state by one of the electrons involved in the ionisation process. Here we report the first direct observation of such a correlated two electron process during photoionisation of argon clusters using synchrotron radiation and the TPEPICO technique. We observe at least two distinct maxima of the metastable TPEPICO spectrum at around 27 eV and 28.5 eV, the former being consistent with the previously reported energetic threshold for electron impact ionisation. (orig.)
International Nuclear Information System (INIS)
Angelo, E.; Angelo, G.; Andrade, D.A.
2012-01-01
Highlights: ► A mathematical model to determine the metastable flow degree in expansions. ► This model is based on the evaporation wave theory and a pressure jump discontinuity condition. ► The proposed model is not appropriate in cases where is present a low intensity evaporation wave. - Abstract: The determination of the metastability condition in fluid flows through singularities (expansion devices) when flashing occurs is the key to determine the mass flow rate going through devices when there is a great pressure difference between upstream and downstream. An application of the evaporation waves considered together with a maximizing condition for the pressure jump through the wave to determine the metastable state is presented. The model results are compared to several outflows reported in the literature indicating values within engineering standards for those flows in which fluids are highly superheated (highly expanded flashing liquid jets).
High-scale validity of a two-Higgs-doublet scenario: metastability included
Energy Technology Data Exchange (ETDEWEB)
Chakrabarty, Nabarun; Mukhopadhyaya, Biswarup [Harish-Chandra Research Institute, Regional Centre for Accelerator-based Particle Physics, Allahabad (India)
2017-03-15
We identify regions in a Type-II two-Higgs-doublet model which correspond to a metastable electroweak vacuum with lifetime larger than the age of the universe. We analyse scenarios which retain perturbative unitarity up to grand unification and Planck scales. Each point in the parameter space is restricted using data from the Large Hadron Collider (LHC) as well as flavour and precision electroweak constraints. We find that substantial regions of the parameter space are thus identified as corresponding to metastability, which complement the allowed regions for absolute stability, for top quark mass at the high as well as low end of its currently allowed range. Thus, a two-Higgs-doublet scenario with the electroweak vacuum, either stable or metastable, can sail through all the way up to the Planck scale without facing any contradiction. (orig.)
Control of switching between metastable superconducting states in δ-MoN nanowires.
Buh, Jože; Kabanov, Viktor; Baranov, Vladimir; Mrzel, Aleš; Kovič, Andrej; Mihailovic, Dragan
2015-12-21
The superconducting state in one-dimensional nanosystems is very delicate. While fluctuations of the phase of the superconducting wave function lead to the spontaneous decay of persistent supercurrents in thin superconducting wires and nanocircuits, discrete phase-slip fluctuations can also lead to more exotic phenomena, such as the appearance of metastable superconducting states in current-bearing wires. Here we show that switching between different metastable superconducting states in δ-MoN nanowires can be very effectively manipulated by introducing small amplitude electrical noise. Furthermore, we show that deterministic switching between metastable superconducting states with different numbers of phase-slip centres can be achieved in both directions with small electrical current pulse perturbations of appropriate polarity. The observed current-controlled bi-stability is in remarkable agreement with theoretically predicted trajectories of the system switching between different limit cycle solutions of a model one-dimensional superconductor.
Andrikopoulos, K. S.; Kalampounias, A. G.; Falagara, O.; Yannopoulos, S. N.
2013-09-01
We report a detailed investigation of vibrational modes, structure, and dynamics of elemental sulfur in the glassy and the supercooled state, using Raman scattering and ab initio calculations. Polarized Raman spectra are recorded - for sulfur quenched from 473 K - over a broad temperature range from 93 K to 273 K where the supercooled liquid crystallized. The temperature induced shifts of the majority of the vibrational modes are determined and compared with the corresponding ones of crystalline sulfur. Analysis of the reduced isotropic spectra showed that the structure of the quenched product is composed of eight member rings (S8) and polymeric chains (Sμ) with a relative fraction comparable to that of the parent liquid at 473 K. Low temperature spectra, where spectral line broadening due to thermal effects is limited, revealed that two different polymeric species are present in the glass with distinct vibrational frequencies. Their interpretation was assisted by ab initio calculations used to simulate the vibrational frequencies of polymeric chains S8k (k = 1, …, 7). Theoretical results exhibit an increasing breathing mode frequency for sulfur chains up to k = 2, although it remains constant beyond the above value. The polymeric content is metastable; heating the glass above its glass transition temperature, Tg, destabilizes the chains and drives them back to the more thermodynamically stable rings. This bond interchange mechanism provides the structural origin of a secondary relaxation process in supercooled sulfur reported long ago, which has been also considered as a complication in the correct fragility estimation of this material. Finally, the Boson peak of the glass was found to exhibit strong temperature dependence even at temperatures below Tg.
Geometric Analogue of Holographic Reduced Representation
Aerts, Diederik; Czachor, Marek; De Moor, Bart
2007-01-01
Holographic reduced representations (HRR) are based on superpositions of convolution-bound $n$-tuples, but the $n$-tuples cannot be regarded as vectors since the formalism is basis dependent. This is why HRR cannot be associated with geometric structures. Replacing convolutions by geometric products one arrives at reduced representations analogous to HRR but interpretable in terms of geometry. Variable bindings occurring in both HRR and its geometric analogue mathematically correspond to two ...
Guide to Geometric Algebra in Practice
Dorst, Leo
2011-01-01
This highly practical "Guide to Geometric Algebra in Practice" reviews algebraic techniques for geometrical problems in computer science and engineering, and the relationships between them. The topics covered range from powerful new theoretical developments, to successful applications, and the development of new software and hardware tools. This title: provides hands-on review exercises throughout the book, together with helpful chapter summaries; presents a concise introductory tutorial to conformal geometric algebra (CGA) in the appendices; examines the application of CGA for the d
Ghosh, Mrinal; Banerjee, Shaibal; Shafeeuulla Khan, Md Abdul; Sikder, Nirmala; Sikder, Arun Kanti
2016-09-14
Multiphase growth during crystallization severely affects deliverable output of explosive materials. Appearance and incomplete transformation of metastable phases are a major source of polymorphic impurities. This article presents a methodical and molecular level understanding of the metastable phase transformation mechanism during crystallization of cyclic nitramine explosives, viz. RDX, HMX and CL-20. Instantaneous reverse precipitation yielded metastable γ-HMX and β-CL-20 which undergo solution mediated transformation to the respective thermodynamic forms, β-HMX and ε-CL-20, following 'Ostwald's rule of stages'. However, no metastable phase, anticipated as β-RDX, was evidenced during precipitation of RDX, which rather directly yielded the thermodynamically stable α-phase. The γ→β-HMX and β→ε-CL-20 transformations took 20 and 60 minutes respectively, whereas formation of α-RDX was instantaneous. Density functional calculations were employed to identify the possible transition state conformations and to obtain activation barriers for transformations at wB97XD/6-311++G(d,p)(IEFPCM)//B3LYP/6-311G(d,p) level of theory. The computed activation barriers and lattice energies responsible for transformation of RDX, HMX and CL-20 metastable phases to thermodynamic ones conspicuously supported the experimentally observed order of phase stability. This precise result facilitated an understanding of the occurrence of a relatively more sensitive and less dense β-CL-20 phase in TNT based melt-cast explosive compositions, a persistent and critical problem unanswered in the literature. The crystalline material recovered from such compositions revealed a mixture of β- and ε-CL-20. However, similar compositions of RDX and HMX never showed any metastable phase. The relatively long stability with the highest activation barrier is believed to restrict complete β→ε-CL-20 transformation during processing. Therefore a method is suggested to overcome this issue.
Geometrical and Graphical Solutions of Quadratic Equations.
Hornsby, E. John, Jr.
1990-01-01
Presented are several geometrical and graphical methods of solving quadratic equations. Discussed are Greek origins, Carlyle's method, von Staudt's method, fixed graph methods and imaginary solutions. (CW)
Geometric Aspects of Iterated Matrix Multiplication
DEFF Research Database (Denmark)
Gesmundo, Fulvio
2016-01-01
This paper studies geometric properties of the Iterated Matrix Multiplication polynomial and the hypersurface that it defines. We focus on geometric aspects that may be relevant for complexity theory such as the symmetry group of the polynomial, the dual variety and the Jacobian loci of the hyper......This paper studies geometric properties of the Iterated Matrix Multiplication polynomial and the hypersurface that it defines. We focus on geometric aspects that may be relevant for complexity theory such as the symmetry group of the polynomial, the dual variety and the Jacobian loci...
Accelerated Recombination in Cold Dense Plasmas with Metastable Ions due to Resonant Deexcitation
International Nuclear Information System (INIS)
Ralchenko, Yu.V.; Maron, M.
2001-01-01
In a recombining plasma the metastable states are known to accumulate population thereby slowing down the recombination process. We show that a proper account of the doubly-excited autoionizing states, populated through collisional 3-body recombination of metastable ions, results in a significant acceleration of recombination. 3-body recombination followed by collisional (de)excitations and autoionization effectively produces deexcitation via the following chain of elementary events: A fully time-dependent collisional-radiative (CR) modeling for stripped ions of carbon recombining in a cold dense plasma demonstrates an order of magnitude faster recombination of He-like ions. The CR model used in calculations is discussed in details
Energy Technology Data Exchange (ETDEWEB)
Gorban, Oksana, E-mail: matscidep@aim.com [Donetsk Institute for Physics and Engineering named after A.A. Galkin of the NAS of Ukraine, Nauki av. 46, Kyiv 03680 (Ukraine); Synyakina, Susanna; Volkova, Galina; Gorban, Sergey; Konstantiova, Tetyana [Donetsk Institute for Physics and Engineering named after A.A. Galkin of the NAS of Ukraine, Nauki av. 46, Kyiv 03680 (Ukraine); Lyubchik, Svetlana, E-mail: s_lyubchik@yahoo.com [REQUIMTE, Universida de Nova de Lisboa, 2829-516 Caparica (Portugal)
2015-12-15
The effect of the surface modification of the nanoparticles of amorphous and crystalline partially stabilized zirconia by fluoride ions on stability of the metastable tetragonal phase was investigated. Based on the DSC, titrimetry and FTIR spectroscopy data it was proven that surface modification of the xerogel resulted from an exchange of the fluoride ions with the basic OH groups. The effect of the powder pre-calcination temperature before modification on the formation of metastable tetragonal phase in partially stabilized zirconia was investigated. It was shown that the main factor of tetragonal zirconia stabilization is the state of nanoparticles surface at pre-crystallization temperatures.
Beam experiments with state selected Ne (3P0, 3P2) metastable atoms
International Nuclear Information System (INIS)
Verheijen, M.J.
1984-01-01
Metastable rare gas atoms play an important role in all types of plasmas and gas discharges, e.g. in fluorescent lamps and in laser discharges (helium-neon laser or excimer lasers). In this thesis, the metastable states of NeI are studied. First, the theory of excited neon atoms and diatomic molecules is introduced, as well as Penning ionisation. Next, some experimental facilities are described (e.g. the dye laser system). With these instruments, natural lifetime measurements of the 2p fine structure states of NeI are carried out. Results are reported. Finally, total Penning ionisation cross sections are calculated using the optical potential model. (Auth.)
Averaging out magnetic forces with fast rf sweeps in an optical trap for metastable chromium atoms
Beaufils, Q.; Chicireanu, R.; Pouderous, A.; de Souza Melo, W.; Laburthe-Tolra, B.; Maréchal, E.; Vernac, L.; Keller, J. C.; Gorceix, O.
2008-05-01
We introduce a time-averaged trap in which the internal state of the atoms is rapidly modulated to modify the magnetic trapping potential. In our experiment, fast radio-frequency linear sweeps flip the spins of atoms at a fast rate, which averages out the magnetic forces. We use this procedure to optimize the accumulation of metastable chromium atoms in an optical dipole trap from a magneto-optical trap. The potential experienced by the metastable atoms is identical to the bare optical dipole potential, so that this procedure allows for trapping all magnetic sublevels, hence increasing by up to 80% the final number of accumulated atoms.
Electron-impact excitation out of the metastable levels of Krypton
International Nuclear Information System (INIS)
Jung, R.O.; Stone, Tom E.; Boffard, John B.; Anderson, L.W.; Lin, Chun C.
2005-01-01
We have measured the electron-impact excitation cross sections out of the two metastable levels of Kr into the ten levels of the 4p 5 5p configuration. For a common 4p 5 5p final level, the peak excitation cross sections out of the two individual 4p 5 5s metastable levels are found to differ by 1 to 2 orders of magnitude. This is explained by the special features of the electronic structure of the two configurations involved. The peak cross sections are 10 to 1600 times larger than the corresponding peak cross sections out of the ground state
Discrete geometric structures for architecture
Pottmann, Helmut
2010-06-13
The emergence of freeform structures in contemporary architecture raises numerous challenging research problems, most of which are related to the actual fabrication and are a rich source of research topics in geometry and geometric computing. The talk will provide an overview of recent progress in this field, with a particular focus on discrete geometric structures. Most of these result from practical requirements on segmenting a freeform shape into planar panels and on the physical realization of supporting beams and nodes. A study of quadrilateral meshes with planar faces reveals beautiful relations to discrete differential geometry. In particular, we discuss meshes which discretize the network of principal curvature lines. Conical meshes are among these meshes; they possess conical offset meshes at a constant face/face distance, which in turn leads to a supporting beam layout with so-called torsion free nodes. This work can be generalized to a variety of multilayer structures and laid the ground for an adapted curvature theory for these meshes. There are also efforts on segmenting surfaces into planar hexagonal panels. Though these are less constrained than planar quadrilateral panels, this problem is still waiting for an elegant solution. Inspired by freeform designs in architecture which involve circles and spheres, we present a new kind of triangle mesh whose faces\\' in-circles form a packing, i.e., the in-circles of two triangles with a common edge have the same contact point on that edge. These "circle packing (CP) meshes" exhibit an aesthetic balance of shape and size of their faces. They are closely tied to sphere packings on surfaces and to various remarkable structures and patterns which are of interest in art, architecture, and design. CP meshes constitute a new link between architectural freeform design and computational conformal geometry. Recently, certain timber structures motivated us to study discrete patterns of geodesics on surfaces. This
Information geometric methods for complexity
Felice, Domenico; Cafaro, Carlo; Mancini, Stefano
2018-03-01
Research on the use of information geometry (IG) in modern physics has witnessed significant advances recently. In this review article, we report on the utilization of IG methods to define measures of complexity in both classical and, whenever available, quantum physical settings. A paradigmatic example of a dramatic change in complexity is given by phase transitions (PTs). Hence, we review both global and local aspects of PTs described in terms of the scalar curvature of the parameter manifold and the components of the metric tensor, respectively. We also report on the behavior of geodesic paths on the parameter manifold used to gain insight into the dynamics of PTs. Going further, we survey measures of complexity arising in the geometric framework. In particular, we quantify complexity of networks in terms of the Riemannian volume of the parameter space of a statistical manifold associated with a given network. We are also concerned with complexity measures that account for the interactions of a given number of parts of a system that cannot be described in terms of a smaller number of parts of the system. Finally, we investigate complexity measures of entropic motion on curved statistical manifolds that arise from a probabilistic description of physical systems in the presence of limited information. The Kullback-Leibler divergence, the distance to an exponential family and volumes of curved parameter manifolds, are examples of essential IG notions exploited in our discussion of complexity. We conclude by discussing strengths, limits, and possible future applications of IG methods to the physics of complexity.
Generalized Geometric Quantum Speed Limits
Pires, Diego Paiva; Cianciaruso, Marco; Céleri, Lucas C.; Adesso, Gerardo; Soares-Pinto, Diogo O.
2016-04-01
The attempt to gain a theoretical understanding of the concept of time in quantum mechanics has triggered significant progress towards the search for faster and more efficient quantum technologies. One of such advances consists in the interpretation of the time-energy uncertainty relations as lower bounds for the minimal evolution time between two distinguishable states of a quantum system, also known as quantum speed limits. We investigate how the nonuniqueness of a bona fide measure of distinguishability defined on the quantum-state space affects the quantum speed limits and can be exploited in order to derive improved bounds. Specifically, we establish an infinite family of quantum speed limits valid for unitary and nonunitary evolutions, based on an elegant information geometric formalism. Our work unifies and generalizes existing results on quantum speed limits and provides instances of novel bounds that are tighter than any established one based on the conventional quantum Fisher information. We illustrate our findings with relevant examples, demonstrating the importance of choosing different information metrics for open system dynamics, as well as clarifying the roles of classical populations versus quantum coherences, in the determination and saturation of the speed limits. Our results can find applications in the optimization and control of quantum technologies such as quantum computation and metrology, and might provide new insights in fundamental investigations of quantum thermodynamics.
Generalized Geometric Quantum Speed Limits
Directory of Open Access Journals (Sweden)
Diego Paiva Pires
2016-06-01
Full Text Available The attempt to gain a theoretical understanding of the concept of time in quantum mechanics has triggered significant progress towards the search for faster and more efficient quantum technologies. One of such advances consists in the interpretation of the time-energy uncertainty relations as lower bounds for the minimal evolution time between two distinguishable states of a quantum system, also known as quantum speed limits. We investigate how the nonuniqueness of a bona fide measure of distinguishability defined on the quantum-state space affects the quantum speed limits and can be exploited in order to derive improved bounds. Specifically, we establish an infinite family of quantum speed limits valid for unitary and nonunitary evolutions, based on an elegant information geometric formalism. Our work unifies and generalizes existing results on quantum speed limits and provides instances of novel bounds that are tighter than any established one based on the conventional quantum Fisher information. We illustrate our findings with relevant examples, demonstrating the importance of choosing different information metrics for open system dynamics, as well as clarifying the roles of classical populations versus quantum coherences, in the determination and saturation of the speed limits. Our results can find applications in the optimization and control of quantum technologies such as quantum computation and metrology, and might provide new insights in fundamental investigations of quantum thermodynamics.
Geometric Phase Generated Optical Illusion.
Yue, Fuyong; Zang, Xiaofei; Wen, Dandan; Li, Zile; Zhang, Chunmei; Liu, Huigang; Gerardot, Brian D; Wang, Wei; Zheng, Guoxing; Chen, Xianzhong
2017-09-12
An optical illusion, such as "Rubin's vase", is caused by the information gathered by the eye, which is processed in the brain to give a perception that does not tally with a physical measurement of the stimulus source. Metasurfaces are metamaterials of reduced dimensionality which have opened up new avenues for flat optics. The recent advancement in spin-controlled metasurface holograms has attracted considerate attention, providing a new method to realize optical illusions. We propose and experimentally demonstrate a metasurface device to generate an optical illusion. The metasurface device is designed to display two asymmetrically distributed off-axis images of "Rubin faces" with high fidelity, high efficiency and broadband operation that are interchangeable by controlling the helicity of the incident light. Upon the illumination of a linearly polarized light beam, the optical illusion of a 'vase' is perceived. Our result provides an intuitive demonstration of the figure-ground distinction that our brains make during the visual perception. The alliance between geometric metasurface and the optical illusion opens a pathway for new applications related to encryption, optical patterning, and information processing.
Geometric aspects of ordering phenomena
Cugliandolo, Leticia F.
2017-01-01
A macroscopic system prepared in a disordered phase and quenched across a second-order phase transition into an ordered phase undergoes a coarsening process whereby it orders locally in one of the equilibrium states. The study of the evolution of the morphology of the ordered structures in two dimensions has recently unveiled two interesting and generic features. On the one hand, the dynamics first approach a critical percolating state via the growth of a new lengthscale and satisfying scaling properties with respect to it. The time needed to reach the critical percolating state diverges with the system size, though more weakly than the equilibration time. On the other hand, once the critical percolating structures established, the geometrical and statistical properties at larger scales than the one established by the usual dynamic growing length remain the ones of critical percolation. These observations are common to different microscopic dynamics (single spin flip, local and non-local spin exchange, voter) in pure or weakly disordered systems. We discuss these results and we refer to the relevant publications for details. xml:lang="fr"
Simulating geometrically complex blast scenarios
Directory of Open Access Journals (Sweden)
Ian G. Cullis
2016-04-01
Full Text Available The effects of blast waves generated by energetic and non-energetic sources are of continuing interest to the ballistics research community. Modern conflicts are increasingly characterised by asymmetric urban warfare, with improvised explosive devices (IEDs often playing a dominant role on the one hand and an armed forces requirement for minimal collateral effects from their weapons on the other. These problems are characterised by disparate length- and time-scales and may also be governed by complex physics. There is thus an increasing need to be able to rapidly assess and accurately predict the effects of energetic blast in topologically complex scenarios. To this end, this paper presents a new QinetiQ-developed advanced computational package called EAGLE-Blast, which is capable of accurately resolving the generation, propagation and interaction of blast waves around geometrically complex shapes such as vehicles and buildings. After a brief description of the numerical methodology, various blast scenario simulations are described and the results compared with experimental data to demonstrate the validation of the scheme and its ability to describe these complex scenarios accurately and efficiently. The paper concludes with a brief discussion on the use of the code in supporting the development of algorithms for fast running engineering models.
Geometrical aspects of quantum spaces
International Nuclear Information System (INIS)
Ho, P.M.
1996-01-01
Various geometrical aspects of quantum spaces are presented showing the possibility of building physics on quantum spaces. In the first chapter the authors give the motivations for studying noncommutative geometry and also review the definition of a Hopf algebra and some general features of the differential geometry on quantum groups and quantum planes. In Chapter 2 and Chapter 3 the noncommutative version of differential calculus, integration and complex structure are established for the quantum sphere S 1 2 and the quantum complex projective space CP q (N), on which there are quantum group symmetries that are represented nonlinearly, and are respected by all the aforementioned structures. The braiding of S q 2 and CP q (N) is also described. In Chapter 4 the quantum projective geometry over the quantum projective space CP q (N) is developed. Collinearity conditions, coplanarity conditions, intersections and anharmonic ratios is described. In Chapter 5 an algebraic formulation of Reimannian geometry on quantum spaces is presented where Riemannian metric, distance, Laplacian, connection, and curvature have their quantum counterparts. This attempt is also extended to complex manifolds. Examples include the quantum sphere, the complex quantum projective space and the two-sheeted space. The quantum group of general coordinate transformations on some quantum spaces is also given
Geometric reasoning about assembly tools
Energy Technology Data Exchange (ETDEWEB)
Wilson, R.H.
1997-01-01
Planning for assembly requires reasoning about various tools used by humans, robots, or other automation to manipulate, attach, and test parts and subassemblies. This paper presents a general framework to represent and reason about geometric accessibility issues for a wide variety of such assembly tools. Central to the framework is a use volume encoding a minimum space that must be free in an assembly state to apply a given tool, and placement constraints on where that volume must be placed relative to the parts on which the tool acts. Determining whether a tool can be applied in a given assembly state is then reduced to an instance of the FINDPLACE problem. In addition, the author presents more efficient methods to integrate the framework into assembly planning. For tools that are applied either before or after their target parts are mated, one method pre-processes a single tool application for all possible states of assembly of a product in polynomial time, reducing all later state-tool queries to evaluations of a simple expression. For tools applied after their target parts are mated, a complementary method guarantees polynomial-time assembly planning. The author presents a wide variety of tools that can be described adequately using the approach, and surveys tool catalogs to determine coverage of standard tools. Finally, the author describes an implementation of the approach in an assembly planning system and experiments with a library of over one hundred manual and robotic tools and several complex assemblies.
Persistence of metastable vortex lattice domains in MgB2 in the presence of vortex motion.
Rastovski, C; Schlesinger, K J; Gannon, W J; Dewhurst, C D; DeBeer-Schmitt, L; Zhigadlo, N D; Karpinski, J; Eskildsen, M R
2013-09-06
Recently, extensive vortex lattice metastability was reported in MgB2 in connection with a second-order rotational phase transition. However, the mechanism responsible for these well-ordered metastable vortex lattice phases is not well understood. Using small-angle neutron scattering, we studied the vortex lattice in MgB2 as it was driven from a metastable to the ground state through a series of small changes in the applied magnetic field. Our results show that metastable vortex lattice domains persist in the presence of substantial vortex motion and directly demonstrate that the metastability is not due to vortex pinning. Instead, we propose that it is due to the jamming of counterrotated vortex lattice domains which prevents a rotation to the ground state orientation.
Directory of Open Access Journals (Sweden)
Zixuan Yang
2017-11-01
Full Text Available Hydrostatic pressure effects on pitting initiation and propagation in X70 steel are investigated by evaluating metastable pitting probability using electrochemical methods and immersion corrosion tests in containing chlorine ion solution. Potentiodynamic tests indicated that hydrostatic pressure can decrease the breakdown potential and lead to a reduced transpassivity region. Metastable test results revealed that hydrostatic pressure can increase metastable pitting formation frequency and promote stabilization of metastable pitting growth. Electrochemical impedance spectroscopy (EIS results indicate that Hydrostatic pressure decreases the charge transfer resistance and increases the dissolution rate within the cavities. Corrosion test results also indicated that pitting initiation and propagation are accelerated by hydrostatic pressure. Result validity was verified by evaluating metastable pitting to predict pitting corrosion resistance.
Geometric integrators for stochastic rigid body dynamics
Tretyakov, Mikhail
2016-01-05
Geometric integrators play an important role in simulating dynamical systems on long time intervals with high accuracy. We will illustrate geometric integration ideas within the stochastic context, mostly on examples of stochastic thermostats for rigid body dynamics. The talk will be mainly based on joint recent work with Rusland Davidchak and Tom Ouldridge.
Geometric phases in discrete dynamical systems
Energy Technology Data Exchange (ETDEWEB)
Cartwright, Julyan H.E., E-mail: julyan.cartwright@csic.es [Instituto Andaluz de Ciencias de la Tierra, CSIC–Universidad de Granada, E-18100 Armilla, Granada (Spain); Instituto Carlos I de Física Teórica y Computacional, Universidad de Granada, E-18071 Granada (Spain); Piro, Nicolas, E-mail: nicolas.piro@epfl.ch [École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland); Piro, Oreste, E-mail: piro@imedea.uib-csic.es [Departamento de Física, Universitat de les Illes Balears, E-07122 Palma de Mallorca (Spain); Tuval, Idan, E-mail: ituval@imedea.uib-csic.es [Mediterranean Institute for Advanced Studies, CSIC–Universitat de les Illes Balears, E-07190 Mallorca (Spain)
2016-10-14
In order to study the behaviour of discrete dynamical systems under adiabatic cyclic variations of their parameters, we consider discrete versions of adiabatically-rotated rotators. Parallelling the studies in continuous systems, we generalize the concept of geometric phase to discrete dynamics and investigate its presence in these rotators. For the rotated sine circle map, we demonstrate an analytical relationship between the geometric phase and the rotation number of the system. For the discrete version of the rotated rotator considered by Berry, the rotated standard map, we further explore this connection as well as the role of the geometric phase at the onset of chaos. Further into the chaotic regime, we show that the geometric phase is also related to the diffusive behaviour of the dynamical variables and the Lyapunov exponent. - Highlights: • We extend the concept of geometric phase to maps. • For the rotated sine circle map, we demonstrate an analytical relationship between the geometric phase and the rotation number. • For the rotated standard map, we explore the role of the geometric phase at the onset of chaos. • We show that the geometric phase is related to the diffusive behaviour of the dynamical variables and the Lyapunov exponent.
A geometric characterization of arithmetic varieties
Indian Academy of Sciences (India)
R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22
The main result is the characterization of arithmetically defined divisors in the plane as geometrically rigid divisors in the plane. Keywords. Equisingular; geometrically rigid. 1. Introduction. This paper is an attempt to generalize a result of Belyi (see [1]). Theorem (Belyi). Let C be a smooth projective curve over an algebraic ...
Early Sex Differences in Weighting Geometric Cues
Lourenco, Stella F.; Addy, Dede; Huttenlocher, Janellen; Fabian, Lydia
2011-01-01
When geometric and non-geometric information are both available for specifying location, men have been shown to rely more heavily on geometry compared to women. To shed insight on the nature and developmental origins of this sex difference, we examined how 18- to 24-month-olds represented the geometry of a surrounding (rectangular) space when…
Geometric Growing Patterns: What's the Rule?
Hourigan, Mairéad; Leavy, Aisling
2015-01-01
While within a geometric repeating pattern, there is an identifiable core which is made up of objects that repeat in a predictable manner, a geometric growing pattern (also called visual or pictorial growing patterns in other curricula) "is a pattern that is made from a sequence of figures [or objects] that change from one term to the next in…
Geometric Control of Patterned Linear Systems
Hamilton, Sarah C
2012-01-01
This monograph is aiming at researchers of systems control, especially those interested in multiagent systems, distributed and decentralized control, and structured systems. The book assumes no prior background in geometric control theory; however, a first year graduate course in linear control systems is desirable. Since not all control researchers today are exposed to geometric control theory, the book also adopts a tutorial style by way of examples that illustrate the geometric and abstract algebra concepts used in linear geometric control. In addition, the matrix calculations required for the studied control synthesis problems of linear multivariable control are illustrated via a set of running design examples. As such, some of the design examples are of higher dimension than one may typically see in a text; this is so that all the geometric features of the design problem are illuminated.
Geometric distortion correction for sinusoidally scanned images
International Nuclear Information System (INIS)
Xu, Lijun; Tian, Xiangrui; Li, Xiaolu; Shang, Guangyi; Yao, Junen
2011-01-01
A method for correcting the geometric distortion of sinusoidally scanned images was proposed. The generation mechanism of the geometric distortion in sinusoidally scanned images was analyzed. Based on the relationship between the coordinates of uniformly scanned points and those of sinusoidally scanned points, a transformation formula was obtained for correcting the geometric distortion when the sampling rate was a constant. By comparing the forward method with the inverse method, a hybrid method for correcting the geometric distortion of sinusoidally scanned images was proposed. This method takes advantage of both the forward and inverse methods and was proven to be better than either of them in terms of peak signal-to-noise ratio (PSNR). The time consumed by the hybrid method was between the other two. When a higher PSNR is desired, the hybrid method is recommended if time permits. In addition, it is a universal approach to the correction of geometric distortion of the images scanned in the sinusoidal mode
Decay of Metastable State with Account of Agglomeration and Relaxation Processes
Directory of Open Access Journals (Sweden)
Victor Kurasov
2016-01-01
Full Text Available Theoretical description of the metastable phase decay kinetics in the presence of specific connections between the embryos of small sizes has been given. The theory of the decay kinetics in the presence of relaxation processes is constructed in analytical manner. The m-mers nucleation is investigated and the global kinetics of decay is also constructed in this case analytically.
Thermal decay rate of a metastable state with two degrees of ...
Indian Academy of Sciences (India)
I I Gontchar
2017-06-01
Jun 1, 2017 ... Abstract. Accuracy of the Kramers approximate formula for the thermal decay rate of the metastable state is studied for the two-dimensional potential pocket. This is done by comparing with the quasistationary rate resulting from the dynamical modelling. It is shown that the Kramers rate is in agreement with ...
Quantum mechanical look at the radioactive-like decay of metastable dark energy
Energy Technology Data Exchange (ETDEWEB)
Szydlowski, Marek [Jagiellonian University, Astronomical Observatory, Krakow (Poland); Jagiellonian University, Mark Kac Complex Systems Research Centre, Krakow (Poland); Stachowski, Aleksander [Jagiellonian University, Astronomical Observatory, Krakow (Poland); Urbanowski, Krzysztof [University of Zielona Gora, Institute of Physics, Zielona Gora (Poland)
2017-12-15
We derive the Shafieloo, Hazra, Sahni and Starobinsky (SHSS) phenomenological formula for the radioactive-like decay of metastable dark energy directly from the principles of quantum mechanics. To this aim we use the Fock-Krylov theory of quantum unstable states. We obtain deeper insight on the decay process as having three basic phases: the phase of radioactive decay, the next phase of damping oscillations, and finally the phase of power-law decay. We consider the cosmological model with matter and dark energy in the form of decaying metastable dark energy and study its dynamics in the framework of non-conservative cosmology with an interacting term determined by the running cosmological parameter. We study the cosmological implications of metastable dark energy and estimate the characteristic time of ending of the radioactive-like decay epoch to be 2.2 x 10{sup 4} of the present age of the Universe. We also confront the model with astronomical data which show that the model is in good agreement with the observations. Our general conclusion is that we are living in the epoch of the radioactive-like decay of metastable dark energy which is a relict of the quantum age of the Universe. (orig.)
Probing metastable Sm2+ and optically stimulated tunnelling emission in YPO4: Ce, Sm
DEFF Research Database (Denmark)
Prasad, Amit Kumar; Kook, Myung Ho; Jain, Mayank
2017-01-01
optical stimulation. The work presented here adds further details to the energy levels of the metastable Sm2+ defect and the electron transfer processes by undertaking measurements of a) Sm2+ excitation spectrum through the internal 5D0 → 7F2 emission at 7 K, b) relaxation lifetime of Sm2+ (5D0 state...
Metastable states in antiprotonic helium atoms an island stability in a sea of continuum
Korobov, V I
2002-01-01
In this contribution we consider a phenomenon of metastable states in antiprotonic helium atoms, precise spectroscopy of these states and a present-day study of the electromagnetic properties of antiprotons. Calculation of nonrelativistic energies, relativistic and QED corrections as well as the fine and hyperfine structure and the magnetic moment of an antiproton are the main parts of this study. Refs. 22 (nevyjel)
Correction for Metastability in the Quantification of PID in Thin-film Module Testing
DEFF Research Database (Denmark)
Hacke, Peter; Spataru, Sergiu; Johnston, Steve
2017-01-01
A fundamental change in the analysis for the accelerated stress testing of thin-film modules is proposed, whereby power changes due to metastability and other effects that may occur due to the thermal history are removed from the power measurement that we obtain as a function of the applied stres...
Triple differential cross-sections for the ionization of metastable 2P ...
Indian Academy of Sciences (India)
2016-10-06
Oct 6, 2016 ... Abstract. In this paper, triple differential cross-sections for the ionization of metastable 2P-state hydrogen atoms by 250 eV electron energy with exchange effects for various kinematic conditions are calculated. Multiple scattering theory proposed by Das and Seal in Phys. Rev. A 47, 2978 (1993) is utilized ...
Molecular geometric phase from the exact electron-nuclear factorization
Requist, Ryan; Tandetzky, Falk; Gross, E. K. U.
2016-04-01
The Born-Oppenheimer electronic wave function ΦRBO(r ) picks up a topological phase factor ±1 , a special case of Berry phase, when it is transported around a conical intersection of two adiabatic potential energy surfaces in R space. We show that this topological quantity reverts to a geometric quantity ei γ if the geometric phase γ =∮Im .d Rμ is evaluated with the conditional electronic wave function ΦR(r ) from the exact electron-nuclear factorization ΦR(r ) χ (R ) instead of the adiabatic function ΦRBO(r ) . A model of a pseudorotating triatomic molecule, also applicable to dynamical Jahn-Teller ions in bulk crystals, provides examples of nontrivial induced vector potentials and molecular geometric phase from the exact factorization. The induced vector potential gives a contribution to the circulating nuclear current that cannot be removed by a gauge transformation. The exact potential energy surface is calculated and found to contain a term depending on the Fubini-Study metric for the conditional electronic wave function.
Theoretical investigation of existence of meta-stability in iron and cobalt clusters
Berry, Habte Dulla; Zhang, Qinfang; Wang, Baolin
2018-03-01
Nowadays considerable attention has been given for researches on magnetic properties of transition metal clusters (specifically FeN and CoN). This is because these clusters offer big hopes for the possibility of presenting significant magnetic anisotropy energy which is critical for technological applications. This study intends to find out the causes for the existence of the two states (ground and meta-stable) in Iron and Cobalt clusters. The study also explains the role of valence electrons for the existence of magnetism in the two states by using the concept of ionization potential, electron dipole polarizabilities, chemical hardness and softness of the clusters. Assuming that, when all itinerant electrons are at s-level and also at the d-level (ns = n andns → 0.) the ground state and meta-stable state energies with distinct energy minima are (Egs = l / 2 n +εc n - 2μB hn andEms =εd n - gμB hn) respectively. The findings also showed that polarizability of small cluster of the specified elements are increased compared with the bulk value, which means that there is an effective increase in the cluster radius due to the spilling out of the electronic charge. Furthermore, it is obvious that 4s electrons are more delocalized than the 3d electrons so that they spill out more than the 3d electrons. This leads to the conclusion that 4s electrons are primarily responsible for the enhanced polarizabilities and for shell structure effects. This indicates that polarizability at the meta-stable state is less than that of the ground state i.e. the meta-stable state loses its s electron. Therefore the two minima represent a ground state of configuration 3 d↑5 3 d↓ 2 + δ 4s 2 - δ with energy Egs and meta-stable state of configuration 3 d↑5 3 d↓ 3 + δ 4s 1 - δ with energy Ems for Co clusters and a ground state configuration 3 d↑5 3 d↓ 1 + δ 4s 2 - δ with energy Egs an meta-stable state of configuration 3 d↑5 3 d↓ 2 + δ 4s 1 - δ with energy Ems for
Modelling and experimental investigation of geometrically graded NiTi shape memory alloys
International Nuclear Information System (INIS)
Shariat, Bashir S; Liu, Yinong; Rio, Gerard
2013-01-01
To improve actuation controllability of a NiTi shape memory alloy component in applications, it is desirable to create a wide stress window for the stress-induced martensitic transformation in the alloy. One approach is to create functionally graded NiTi with a geometric gradient in the actuation direction. This geometric gradient leads to transformation load and displacement gradients in the structure. This paper reports a study of the pseudoelastic behaviour of geometrically graded NiTi by means of mechanical model analysis and experimentation using three types of sample geometry. Closed-form solutions are obtained for nominal stress–strain variation of such components under cyclic tensile loading and the predictions are validated with experimental data. The geometrically graded NiTi samples exhibit a distinctive positive stress gradient for the stress-induced martensitic transformation and the slope of the stress gradient can be adjusted by sample geometry design. (paper)
Laser-Induced-Emission Spectroscopy In Hg/Ar Discharge
Maleki, Lutfollah; Blasenheim, Barry J.; Janik, Gary R.
1992-01-01
Laser-induced-emission (LIE) spectroscopy used to probe low-pressure mercury/argon discharge to determine influence of mercury atoms in metastable 6(Sup3)P(Sub2) state on emission of light from discharge. LIE used to study all excitation processes affected by metastable population, including possible effects on excitation of atoms, ions, and buffer gas. Technique applied to emissions of other plasmas. Provides data used to make more-accurate models of such emissions, exploited by lighting and laser industries and by laboratories studying discharges. Also useful in making quantitative measurements of relative rates and cross sections of direct and two-step collisional processes involving metastable level.
Estimation of geometrically undistorted B0 inhomogeneity maps
International Nuclear Information System (INIS)
Matakos, A; Balter, J; Cao, Y
2014-01-01
Geometric accuracy of MRI is one of the main concerns for its use as a sole image modality in precision radiation therapy (RT) planning. In a state-of-the-art scanner, system level geometric distortions are within acceptable levels for precision RT. However, subject-induced B 0 inhomogeneity may vary substantially, especially in air-tissue interfaces. Recent studies have shown distortion levels of more than 2 mm near the sinus and ear canal are possible due to subject-induced field inhomogeneity. These distortions can be corrected with the use of accurate B 0 inhomogeneity field maps. Most existing methods estimate these field maps from dual gradient-echo (GRE) images acquired at two different echo-times under the assumption that the GRE images are practically undistorted. However distortion that may exist in the GRE images can result in estimated field maps that are distorted in both geometry and intensity, leading to inaccurate correction of clinical images. This work proposes a method for estimating undistorted field maps from GRE acquisitions using an iterative joint estimation technique. The proposed method yields geometrically corrected GRE images and undistorted field maps that can also be used for the correction of images acquired by other sequences. The proposed method is validated through simulation, phantom experiments and applied to patient data. Our simulation results show that our method reduces the root-mean-squared error of the estimated field map from the ground truth by ten-fold compared to the distorted field map. Both the geometric distortion and the intensity corruption (artifact) in the images caused by the B 0 field inhomogeneity are corrected almost completely. Our phantom experiment showed improvement in the geometric correction of approximately 1 mm at an air-water interface using the undistorted field map compared to using a distorted field map. The proposed method for undistorted field map estimation can lead to improved geometric
Estimation of geometrically undistorted B0 inhomogeneity maps
Matakos, A.; Balter, J.; Cao, Y.
2014-09-01
Geometric accuracy of MRI is one of the main concerns for its use as a sole image modality in precision radiation therapy (RT) planning. In a state-of-the-art scanner, system level geometric distortions are within acceptable levels for precision RT. However, subject-induced B0 inhomogeneity may vary substantially, especially in air-tissue interfaces. Recent studies have shown distortion levels of more than 2 mm near the sinus and ear canal are possible due to subject-induced field inhomogeneity. These distortions can be corrected with the use of accurate B0 inhomogeneity field maps. Most existing methods estimate these field maps from dual gradient-echo (GRE) images acquired at two different echo-times under the assumption that the GRE images are practically undistorted. However distortion that may exist in the GRE images can result in estimated field maps that are distorted in both geometry and intensity, leading to inaccurate correction of clinical images. This work proposes a method for estimating undistorted field maps from GRE acquisitions using an iterative joint estimation technique. The proposed method yields geometrically corrected GRE images and undistorted field maps that can also be used for the correction of images acquired by other sequences. The proposed method is validated through simulation, phantom experiments and applied to patient data. Our simulation results show that our method reduces the root-mean-squared error of the estimated field map from the ground truth by ten-fold compared to the distorted field map. Both the geometric distortion and the intensity corruption (artifact) in the images caused by the B0 field inhomogeneity are corrected almost completely. Our phantom experiment showed improvement in the geometric correction of approximately 1 mm at an air-water interface using the undistorted field map compared to using a distorted field map. The proposed method for undistorted field map estimation can lead to improved geometric
Fatigue crack growth in metastable austenitic stainless steels
International Nuclear Information System (INIS)
Mei, Z.; Chang, G.; Morris, J.W. Jr.
1988-06-01
The research reported here is an investigation of the influence of the mechanically induced martensitic transformation on the fatigue crack growth rate in 304-type steels. The alloys 304L and 304LN were used to test the influence of composition, the testing temperatures 298 K and 77 K were used to study the influence of test temperature, and various load ratios (R) were used to determine the influence of the load ratio. It was found that decreasing the mechanical stability of the austenite by changing composition or lowering temperature decreases the fatigue crack growth rate. The R-ratio effect is more subtle. The fatigue crack growth rate increases with increasing R-ratio, even though this change increases the martensite transformation. Transformation-induced crack closure can explain the results in the threshold regime, but cannot explain the R-ratio effect at higher cyclic stress intensities. 26 refs., 6 figs
A Geometrical View of Higgs Effective Theory
CERN. Geneva
2016-01-01
A geometric formulation of Higgs Effective Field Theory (HEFT) is presented. Experimental observables are given in terms of geometric invariants of the scalar sigma model sector such as the curvature of the scalar field manifold M. We show how the curvature can be measured experimentally via Higgs cross-sections, W_L scattering, and the S parameter. The one-loop action of HEFT is given in terms of geometric invariants of M. The distinction between the Standard Model (SM) and HEFT is whether M is flat or curved, with the curvature a signal of the scale of new physics.
Geometrical formulation of the conformal Ward identity
International Nuclear Information System (INIS)
Kachkachi, M.
2002-08-01
In this paper we use deep ideas in complex geometry that proved to be very powerful in unveiling the Polyakov measure on the moduli space of Riemann surfaces and lead to obtain the partition function of perturbative string theory for 2, 3, 4 loops. Indeed, a geometrical interpretation of the conformal Ward identity in two dimensional conformal field theory is proposed: the conformal anomaly is interpreted as a deformation of the complex structure of the basic Riemann surface. This point of view is in line with the modern trend of geometric quantizations that are based on deformations of classical structures. Then, we solve the conformal Ward identity by using this geometrical formalism. (author)
Geometrical analysis of the interacting boson model
International Nuclear Information System (INIS)
Dieperink, A.E.L.
1983-01-01
The Interacting Boson Model is considered, in relation with geometrical models and the application of mean field techniques to algebraic models, in three lectures. In the first, several methods are reviewed to establish a connection between the algebraic formulation of collective nuclear properties in terms of the group SU(6) and the geometric approach. In the second lecture the geometric interpretation of new degrees of freedom that arise in the neutron-proton IBA is discussed, and in the third one some further applications of algebraic techniques to the calculation of static and dynamic collective properties are presented. (U.K.)
Lectures on geometrical properties of nuclei
International Nuclear Information System (INIS)
Myers, W.D.
1975-11-01
Material concerning the geometrical properties of nuclei is drawn from a number of different sources. The leptodermous nature of nuclear density distributions and potential wells is used to draw together the various geometrical properties of these systems and to provide a unified means for their description. Extensive use is made of expansions of radial properties in terms of the surface diffuseness. A strong case is made for the use of convolution as a geometrical ansatz for generating diffuse surface distributions because of the number of simplifications that arise which are of practical importance. 7 figures
Stock price prediction using geometric Brownian motion
Farida Agustini, W.; Restu Affianti, Ika; Putri, Endah RM
2018-03-01
Geometric Brownian motion is a mathematical model for predicting the future price of stock. The phase that done before stock price prediction is determine stock expected price formulation and determine the confidence level of 95%. On stock price prediction using geometric Brownian Motion model, the algorithm starts from calculating the value of return, followed by estimating value of volatility and drift, obtain the stock price forecast, calculating the forecast MAPE, calculating the stock expected price and calculating the confidence level of 95%. Based on the research, the output analysis shows that geometric Brownian motion model is the prediction technique with high rate of accuracy. It is proven with forecast MAPE value ≤ 20%.
Permeability prediction of non-crimp fabrics based on a geometric model
Loendersloot, Richard; ten Thije, R.H.W.; Akkerman, Remko; Lomov, S.V.; Galiotis, C.
2004-01-01
A model to predict the permeability of Non-Crimp Fabrics is proposed. The model is based on the geometrical features of the fabric. The stitches penetrating the uni-directional plies of the NCF induce distortions in the plane of the fabric. The dimensions of these Stitch Yarn induced fibre
Transition curves for highway geometric design
Kobryń, Andrzej
2017-01-01
This book provides concise descriptions of the various solutions of transition curves, which can be used in geometric design of roads and highways. It presents mathematical methods and curvature functions for defining transition curves. .
5th Dagstuhl Seminar on Geometric Modelling
Brunnett, Guido; Farin, Gerald; Goldman, Ron
2004-01-01
In 19 articles presented by leading experts in the field of geometric modelling the state-of-the-art on representing, modeling, and analyzing curves, surfaces as well as other 3-dimensional geometry is given. The range of applications include CAD/CAM-systems, computer graphics, scientific visualization, virtual reality, simulation and medical imaging. The content of this book is based on selected lectures given at a workshop held at IBFI Schloss Dagstuhl, Germany. Topics treated are: – curve and surface modelling – non-manifold modelling in CAD – multiresolution analysis of complex geometric models – surface reconstruction – variational design – computational geometry of curves and surfaces – 3D meshing – geometric modelling for scientific visualization – geometric models for biomedical applications
Geometric symmetries in superfluid vortex dynamics
Kozik, Evgeny; Svistunov, Boris
2010-10-01
Dynamics of quantized vortex lines in a superfluid feature symmetries associated with the geometric character of the complex-valued field, w(z)=x(z)+iy(z) , describing the instant shape of the line. Along with a natural set of Noether’s constants of motion, which—apart from their rather specific expressions in terms of w(z) —are nothing but components of the total linear and angular momenta of the fluid, the geometric symmetry brings about crucial consequences for kinetics of distortion waves on the vortex lines, the Kelvin waves. It is the geometric symmetry that renders Kelvin-wave cascade local in the wave-number space. Similar considerations apply to other systems with purely geometric degrees of freedom.
Geometric U-folds in four dimensions
Lazaroiu, C. I.; Shahbazi, C. S.
2018-01-01
We describe a general construction of geometric U-folds compatible with a non-trivial extension of the global formulation of four-dimensional extended supergravity on a differentiable spin manifold. The topology of geometric U-folds depends on certain flat fiber bundles which encode how supergravity fields are globally glued together. We show that smooth non-trivial U-folds of this type can exist only in theories where both the scalar and space-time manifolds have non-trivial fundamental group and in addition the scalar map of the solution is homotopically non-trivial. Consistency with string theory requires smooth geometric U-folds to be glued using subgroups of the effective discrete U-duality group, implying that the fundamental group of the scalar manifold of such solutions must be a subgroup of the latter. We construct simple examples of geometric U-folds in a generalization of the axion-dilaton model of \
Mechanisms of geometrical seismic attenuation
Directory of Open Access Journals (Sweden)
Igor B. Morozov
2011-07-01
Full Text Available In several recent reports, we have explained the frequency dependence of the apparent seismic quality-factor (Q observed in many studies according to the effects of geometrical attenuation, which was defined as the zero-frequency limit of the temporal attenuation coefficient. In particular, geometrical attenuation was found to be positive for most waves traveling within the lithosphere. Here, we present three theoretical models that illustrate the origin of this geometrical attenuation, and we investigate the causes of its preferential positive values. In addition, we discuss the physical basis and limitations of both the conventional and new attenuation models. For waves in media with slowly varying properties, geometrical attenuation is caused by variations in the wavefront curvature, which can be both positive (for defocusing and negative (for focusing. In media with velocity/density contrasts, incoherent reflectivity leads to geometrical-attenuation coefficients which are proportional to the mean squared reflectivity and are always positive. For «coherent» reflectivity, the geometrical attenuation is approximately zero, and the attenuation process can be described according to the concept of «scattering Q». However, the true meaning of this parameter is in describing the mean reflectivity within the medium, and not that of the traditional resonator quality factor known in mechanics. The general conclusion from these models is that non-zero and often positive levels of geometrical attenuation are common in realistic, heterogeneous media, both observationally and theoretically. When transformed into the conventional Q-factor form, this positive geometrical attenuation leads to Q values that quickly increase with frequency. These predictions show that the positive frequency-dependent Q observed in many datasets might represent artifacts of the transformations of the attenuation coefficients into Q.
The geometric semantics of algebraic quantum mechanics.
Cruz Morales, John Alexander; Zilber, Boris
2015-08-06
In this paper, we will present an ongoing project that aims to use model theory as a suitable mathematical setting for studying the formalism of quantum mechanics. We argue that this approach provides a geometric semantics for such a formalism by means of establishing a (non-commutative) duality between certain algebraic and geometric objects. © 2015 The Author(s) Published by the Royal Society. All rights reserved.
A geometric rationale for invariance, covariance and constitutive relations
Romano, Giovanni; Barretta, Raffaele; Diaco, Marina
2018-01-01
There are, in each branch of science, statements which, expressed in ambiguous or even incorrect but seemingly friendly manner, were repeated for a long time and eventually became diffusely accepted. Objectivity of physical fields and of their time rates and frame indifference of constitutive relations are among such notions. A geometric reflection on the description of frame changes as spacetime automorphisms, on induced push-pull transformations and on proper physico-mathematical definitions of material, spatial and spacetime tensor fields and of their time-derivatives along the motion, is here carried out with the aim of pointing out essential notions and of unveiling false claims. Theoretical and computational aspects of nonlinear continuum mechanics, and especially those pertaining to constitutive relations, involving material fields and their time rates, gain decisive conceptual and operative improvement from a proper geometric treatment. Outcomes of the geometric analysis are frame covariance of spacetime velocity, material stretching and material spin. A univocal and frame-covariant tool for evaluation of time rates of material fields is provided by the Lie derivative along the motion. The postulate of frame covariance of material fields is assessed to be a natural physical requirement which cannot interfere with the formulation of constitutive laws, with claims of the contrary stemming from an improper imposition of equality in place of equivalence.
Metastable states in parametrically excited multimode Hamiltonian systems
Kirr, E
2003-01-01
Consider a linear autonomous Hamiltonian system with time periodic bound state solutions. In this paper we study their dynamics under time almost periodic perturbations which are small, localized and Hamiltonian. The analysis proceeds through a reduction of the original infinite dimensional dynamical system to the dynamics of two coupled subsystems: a dominant m-dimensional system of ordinary differential equations (normal form), governing the projections onto the bound states and an infinite dimensional dispersive wave equation. The present work generalizes previous work of the authors, where the case of a single bound state is considered. Here, the interaction picture is considerably more complicated and requires deeper analysis, due to a multiplicity of bound states and the very general nature of the perturbation's time dependence. Parametric forcing induces coupling of bound states to continuum radiation modes, bound states directly to bound states, as well as coupling among bound states, which is mediate...
Effect of the subgap conductance on the metastable states in a Josephson tunnel junction
International Nuclear Information System (INIS)
Cristiano, R.; Pagano, S.; Silvestrini, P.; Gray, K.E.; Liengme, O.
1987-09-01
An investigation of the decay rate of metastable states in Josephson tunnel junctions in presence of thermal noise is presented. We have observed that, in the extremely underdamped regime, there is an exponential temperature dependence of the best fit value for the shunt conductance. Such a dependence shows a close relation with the temperature dependence of the subgap conductance, suggesting that the effective conductance for the escape from the metastable states obeys to a quasi-particle thermal activation mechanism. The introduction of this effective conductance into the lifetime expression for the zero-voltage states leads to significant changes in the width of the switching current distributions. A comparisons of the experimental data with the proposed model is reported. 7 refs., 2 figs
Improving of wear resistance of alloys with metastable austenite structure in abrasion wearing
International Nuclear Information System (INIS)
Popov, V.S.; Brykov, N.N.; Pugachev, G.A.
1979-01-01
The effect of grain composition of abrasive masses upon the wear resistance of alloys having a metastable austenitic structure is studied. The investigations have been carried out on Kh12F1 steel, using diffraction and hardness measurements and the metallographic analysis. Experimental data indicate that the specific wear of the stable alloys increases substantially with the size of abrasive particles. As regards the metastable alloys, the increase in the size of the abrasive grains has little effect upon the specific wear, as the increasing abradability of the grains is compensated for by the strengthening of the rubbing surfaces, this resulting from the ability of the metal surface layer to underao structure transformations in the course of wear
Bixbyite-type V2O3--a metastable polymorph of vanadium sesquioxide.
Weber, D; Stork, A; Nakhal, S; Wessel, C; Reimann, C; Hermes, W; Müller, A; Ressler, T; Pöttgen, R; Bredow, T; Dronskowski, R; Lerch, M
2011-07-18
A metastable polymorph of vanadium sesquioxide was prepared by the reaction of vanadium trifluoride with a water-saturated gaseous mixture of 10 vol % hydrogen in argon. The new polymorph crystallizes in the bixbyite-type structure. At temperatures around 823 K a transformation to the well-known corundum-type phase is observed. Quantum-chemical calculations show that the bixbyite-type structure is about 9 kJ/mol less stable than the known corundum-based one. This result, in combination with the absence of imaginary modes in the phonon density of states, supports the classification of the bixbyite-type phase as a metastable V(2)O(3) polymorph. At ~50 K a paramagnetic to canted antiferromagnetic transition is detected.
Visualization and manipulation of meta-stable polarization variants in multiferroic materials
Directory of Open Access Journals (Sweden)
Moonkyu Park
2013-04-01
Full Text Available Here we demonstrate the role of meta-stable polarization variants in out-of-plane polarization switching behavior in epitaxially grown BiFeO3 thin films using angle-resolved piezoresponse force microscopy (AR-PFM. The out-of-plane polarization switching mainly occurred at the boundary between meta-stable and stable polarization domains, and was accompanied by a significant change in in-plane domain configuration from complicated structure with 12 polarization variants to simple stripe structure with 4 polarization variants. These results imply that the biased tip rearranges the delicately balanced domain configuration, which is determined by the competition between electrostatic and strain energies, into simple interweaving one that is more thermodynamically stable.
Model reduction for slow-fast stochastic systems with metastable behaviour.
Bruna, Maria; Chapman, S Jonathan; Smith, Matthew J
2014-05-07
The quasi-steady-state approximation (or stochastic averaging principle) is a useful tool in the study of multiscale stochastic systems, giving a practical method by which to reduce the number of degrees of freedom in a model. The method is extended here to slow-fast systems in which the fast variables exhibit metastable behaviour. The key parameter that determines the form of the reduced model is the ratio of the timescale for the switching of the fast variables between metastable states to the timescale for the evolution of the slow variables. The method is illustrated with two examples: one from biochemistry (a fast-species-mediated chemical switch coupled to a slower varying species), and one from ecology (a predator-prey system). Numerical simulations of each model reduction are compared with those of the full system.
Liu, Jinxuan
2012-12-04
A novel class of metal organic frameworks (MOFs) has been synthesized from Cu-acetate and dicarboxylic acids using liquid phase epitaxy. The SURMOF-2 isoreticular series exhibits P4 symmetry, for the longest linker a channel-size of 3 3 nm2 is obtained, one of the largest values reported for any MOF so far. High quality, ab-initio electronic structure calculations confirm the stability of a regular packing of (Cu++) 2-carboxylate paddle-wheel planes with P4 symmetry and reveal, that the SURMOF-2 structures are in fact metastable, with a fairly large activation barrier for the transition to the bulk MOF-2 structures exhibiting a lower, twofold (P2 or C2) symmetry. The theoretical calculations also allow identifying the mechanism for the low-temperature epitaxial growth process and to explain, why a synthesis of this highly interesting, new class of high-symmetry, metastable MOFs is not possible using the conventional solvothermal process.
High-frequency magneto-impedance in metastable metallic materials: An overview
International Nuclear Information System (INIS)
Vinai, F.; Coisson, M.; Tiberto, P.
2006-01-01
The giant magneto-impedance effect (GMI) is a common feature of a wide class of metastable ferromagnetic alloys. This effect can be enhanced by submitting the as-prepared materials to suitable thermal treatments. Recently, a remarkably high magneto-impedance response has been observed in the GHz region for several systems. The increase in miniaturization of telecommunication devices dramatically increases the working frequencies; as a consequence, the interest in studying magneto-impedance effect leads to microwave region. In this paper, analogies and differences among the magneto-transport effect observed in ferromagnetic metastable alloys will be highlighted and discussed from the experimental point of view in a wide range of frequencies
Rare quantum metastable states in the strongly dispersive Jaynes-Cummings oscillator
Mavrogordatos, Th; Barratt, F; Asari, U; Szafulski, P; Ginossar, Eran; Szymanska, M
2018-01-01
We present evidence of metastable rare quantum- uctuation switching for the driven dissipative Jaynes-Cummings (JC) oscillator coupled to a zero-temperature bath in the strongly dispersive regime. We show that single-atom complex amplitude bistability is accompanied by the appearance of a low-amplitude long-lived transient state, hereinafter called `dark state', having a distribution with quasi-Poissonian statistics both for the coupled qubit and cavity mode. We find that the ...
In Situ Observations of Phase Transitions in Metastable Nickel (Carbide)/Carbon Nanocomposites
2016-01-01
Nanocomposite thin films comprised of metastable metal carbides in a carbon matrix have a wide variety of applications ranging from hard coatings to magnetics and energy storage and conversion. While their deposition using nonequilibrium techniques is established, the understanding of the dynamic evolution of such metastable nanocomposites under thermal equilibrium conditions at elevated temperatures during processing and during device operation remains limited. Here, we investigate sputter-deposited nanocomposites of metastable nickel carbide (Ni3C) nanocrystals in an amorphous carbon (a-C) matrix during thermal postdeposition processing via complementary in situ X-ray diffractometry, in situ Raman spectroscopy, and in situ X-ray photoelectron spectroscopy. At low annealing temperatures (300 °C) we observe isothermal Ni3C decomposition into face-centered-cubic Ni and amorphous carbon, however, without changes to the initial finely structured nanocomposite morphology. Only for higher temperatures (400–800 °C) Ni-catalyzed isothermal graphitization of the amorphous carbon matrix sets in, which we link to bulk-diffusion-mediated phase separation of the nanocomposite into coarser Ni and graphite grains. Upon natural cooling, only minimal precipitation of additional carbon from the Ni is observed, showing that even for highly carbon saturated systems precipitation upon cooling can be kinetically quenched. Our findings demonstrate that phase transformations of the filler and morphology modifications of the nanocomposite can be decoupled, which is advantageous from a manufacturing perspective. Our in situ study also identifies the high carbon content of the Ni filler crystallites at all stages of processing as the key hallmark feature of such metal–carbon nanocomposites that governs their entire thermal evolution. In a wider context, we also discuss our findings with regard to the much debated potential role of metastable Ni3C as a catalyst phase in graphene and
Rosen, G.
1973-01-01
A survey is presented of free radicals and electronically excited metastable species as high energy propellants for rocket engines. Nascent or atomic forms of diatomic gases are considered free radicals as well as the highly reactive diatomic triatomic molecules that posess unpaired electrons. Manufacturing and storage problems are described, and a review of current experimental work related to the manufacture of atomic hydrogen propellants is presented.
International Nuclear Information System (INIS)
Buzza, S.A.; Wei, S.; Purnell, J.; Castleman, A.W. Jr.
1995-01-01
The formation and metastable dissociation mechanism of unprotonated ammonia cluster ions, (NH 3 ) + n , produced by multiphoton ionization (MPI) at 624 nm and a nominal pulse width of 350 fs, are investigated through a reflectron time-of-flight (TOF) mass spectrometric technique. Detection of the unprotonated ions after femtosecond and nanosecond multiphoton ionization under various intensity conditions is explained. The role of the energy of the ionizing photons, and the observation of these ions after femtosecond MPI is examined. The formation of the unprotonated series is found to be a function of intensity in the case of ionization on the nanosecond time scale, but not so for the femtosecond time domain. The results can be explained in terms of ionization mechanisms and ionizing pulse durations. The findings of the present study suggest that the unprotonated ions are trapped behind the barrier to intracluster proton transfer and/or concomitant NH 2 loss. The studies of metastable decomposition also reveal that the unprotonated ammonia cluster ions dissociate in the field-free region of the TOF by losing an NH 2 radical rather than via the evaporative loss of NH 3 as occurs for protonated clusters. Additionally, isotopic investigations of the unimolecular decay reveal a strong dependence on the conditions of cluster formation. The cluster formation condition dependence of the unimolecular decay is further investigated by altering formation temperatures and observing the consequences reflected by changes in the spontaneous metastable decay rate constant. This is a unique example of a cluster system whose metastable dissociation does not obey an evaporative ensemble model
A metastable equilibrium model for the relative abundances of microbial phyla in a hot spring.
Directory of Open Access Journals (Sweden)
Jeffrey M Dick
Full Text Available Many studies link the compositions of microbial communities to their environments, but the energetics of organism-specific biomass synthesis as a function of geochemical variables have rarely been assessed. We describe a thermodynamic model that integrates geochemical and metagenomic data for biofilms sampled at five sites along a thermal and chemical gradient in the outflow channel of the hot spring known as "Bison Pool" in Yellowstone National Park. The relative abundances of major phyla in individual communities sampled along the outflow channel are modeled by computing metastable equilibrium among model proteins with amino acid compositions derived from metagenomic sequences. Geochemical conditions are represented by temperature and activities of basis species, including pH and oxidation-reduction potential quantified as the activity of dissolved hydrogen. By adjusting the activity of hydrogen, the model can be tuned to closely approximate the relative abundances of the phyla observed in the community profiles generated from BLAST assignments. The findings reveal an inverse relationship between the energy demand to form the proteins at equal thermodynamic activities and the abundance of phyla in the community. The distance from metastable equilibrium of the communities, assessed using an equation derived from energetic considerations that is also consistent with the information-theoretic entropy change, decreases along the outflow channel. Specific divergences from metastable equilibrium, such as an underprediction of the relative abundances of phototrophic organisms at lower temperatures, can be explained by considering additional sources of energy and/or differences in growth efficiency. Although the metabolisms used by many members of these communities are driven by chemical disequilibria, the results support the possibility that higher-level patterns of chemotrophic microbial ecosystems are shaped by metastable equilibrium states that
Production of Ar and Xe metastables in rare gas mixtures in a dielectric barrier discharge
Mikheyev, Pavel A.; Han, Jiande; Clark, Amanda; Sanderson, Carl; Heaven, Michael C.
2017-12-01
Optically pumped all-rare-gas lasers (OPRGL) utilize metastable atoms of the heavier rare gases as lasing species. The required number density of metastables for efficient laser operation is 1012–1013 cm‑3 in He buffer gas at pressures in the 400–1000 Torr range. Such metastable densities are easily produced in a nanosecond pulsed discharge, even at pressures larger than atmospheric, but problems appear when one is trying to achieve continuous production. The reason for low production efficiency in many types of continuous discharge at atmospheric pressure is the low value of the E/N parameter (<5–6 Td). In the present work, we have examined the possibility of using a dielectric barrier discharge (DBD) to provide near continuous, high densities of Ar and Xe metastables. Experiments were performed using a 20 kHz DBD in binary Ar and Xe mixtures with He, and in ternary Ar:Xe:He mixtures at pressures up to 1 atmosphere. Concentrations were measured by means of tunable diode laser absorption spectroscopy. Time-averaged [Ar(1s5)] and [Xe(1s5)] number densities on the order of 1012 cm‑3 were readily achieved. The temporal behavior of [Xe(1s5)] throughout the DBD cycle was observed. The results demonstrate the feasibility of using DBDs for OPRGL development. Spectral scans over the absorption lines were also used to examine the pressure broadening coefficients for the 912.3 nm Ar line in He and the Xe 904.5 nm line in Ne and He.
Huang, Ting-Chia; Smet, Vanessa; Kawamoto, Satomi; Pulugurtha, Markondeya R.; Tummala, Rao R.
2018-01-01
Emerging high-performance systems are driving the need for advanced packaging solutions such as 3-D integrated circuits (ICs) and 2.5-D system integration with increasing performance and reliability requirements for off-chip interconnections. Solid-liquid interdiffusion (SLID) bonding resulting in all-intermetallic joints has been proposed to extend the applicability of solders, but faces fundamental and manufacturing challenges hindering its wide adoption. This paper introduces a Cu-Sn SLID interconnection technology, aiming at stabilization of the microstructure in the Cu6Sn5 metastable phase rather than the usual stable Cu3Sn phase. This enables formation of a void-free interface yielding higher mechanical strength than standard SLID bonding, as well as significantly reducing the transition time. The metastable SLID technology retains the benefits of standard SLID with superior I/O pitch scalability, thermal stability and current handling capability, while advancing assembly manufacturability. In the proposed concept, the interfacial reaction is controlled by introducing Ni(P) diffusion barrier layers, designed to effectively isolate the metastable Cu6Sn5 phase preventing any further transformation. Theoretical diffusion and kinetic models were applied to design the Ni-Cu-Sn interconnection stack to achieve the targeted joint composition. A daisy chain test vehicle was used to demonstrate this technology as a first proof of concept. Full transition to Cu6Sn5 was successfully achieved within a minute at 260°C as confirmed by scanning electron microscope (SEM) and x-ray energy dispersive spectroscopy (XEDS) analysis. The joint composition was stable through 10× reflow, with outstanding bond strength averaging 90 MPa. The metastable SLID interconnections also showed excellent electromigration performance, surviving 500 h of current stressing at 105 A/cm2 at 150°C.
Chiaverotti, Dominic J.
2016-01-01
Approved for public release; distribution is unlimited Centrifugal tensioned metastable fluid detectors (CTMFDs) promise a compact, easy to use, highly sensitive, robust, discriminatory, mobile sensor platform that could detect the presence of special nuclear materials in real time. CTMFDs could help in the detection of fast neutrons or alpha particles that are telltale signs of nuclear material, while remaining blind to gamma radiation that could otherwise interfere with the desired measu...
Melting in Two-Dimensional Lennard-Jones Systems: Observation of a Metastable Hexatic Phase
International Nuclear Information System (INIS)
Chen, K.; Kaplan, T.; Mostoller, M.
1995-01-01
Large scale molecular dynamics simulations of two-dimensional melting have been carried out using a recently revised Parrinello-Rahman scheme on massively parallel supercomputers. A metastable state is observed between the solid and liquid phases in Lennard-Jones systems of 36 864 and 102 400 atoms. This intermediate state shows the characteristics of the hexatic phase predicted by the theory of Kosterlitz, Thouless, Halperin, Nelson, and Young
Properties of the triplet metastable states of the alkaline-earth-metal atoms
International Nuclear Information System (INIS)
Mitroy, J.; Bromley, M.W.J.
2004-01-01
The static and dynamic properties of the alkaline-earth-metal atoms in their metastable state are computed in a configuration interaction approach with a semiempirical model potential for the core. Among the properties determined are the scalar and tensor polarizabilities, the quadrupole moment, some of the oscillator strengths, and the dispersion coefficients of the van der Waals interaction. A simple method for including the effect of the core on the dispersion parameters is described
A Metastable Equilibrium Model for the Relative Abundances of Microbial Phyla in a Hot Spring
Dick, Jeffrey M.; Shock, Everett L.
2013-01-01
Many studies link the compositions of microbial communities to their environments, but the energetics of organism-specific biomass synthesis as a function of geochemical variables have rarely been assessed. We describe a thermodynamic model that integrates geochemical and metagenomic data for biofilms sampled at five sites along a thermal and chemical gradient in the outflow channel of the hot spring known as “Bison Pool” in Yellowstone National Park. The relative abundances of major phyla in individual communities sampled along the outflow channel are modeled by computing metastable equilibrium among model proteins with amino acid compositions derived from metagenomic sequences. Geochemical conditions are represented by temperature and activities of basis species, including pH and oxidation-reduction potential quantified as the activity of dissolved hydrogen. By adjusting the activity of hydrogen, the model can be tuned to closely approximate the relative abundances of the phyla observed in the community profiles generated from BLAST assignments. The findings reveal an inverse relationship between the energy demand to form the proteins at equal thermodynamic activities and the abundance of phyla in the community. The distance from metastable equilibrium of the communities, assessed using an equation derived from energetic considerations that is also consistent with the information-theoretic entropy change, decreases along the outflow channel. Specific divergences from metastable equilibrium, such as an underprediction of the relative abundances of phototrophic organisms at lower temperatures, can be explained by considering additional sources of energy and/or differences in growth efficiency. Although the metabolisms used by many members of these communities are driven by chemical disequilibria, the results support the possibility that higher-level patterns of chemotrophic microbial ecosystems are shaped by metastable equilibrium states that depend on both the
Czech Academy of Sciences Publication Activity Database
Kadashchuk, A.; Nešpůrek, Stanislav; Ostapenko, N.; Skryshevskii, Yu.; Zaika, V.
2001-01-01
Roč. 35, special issue (2001), s. 413-428 ISSN 1058-725X R&D Projects: GA AV ČR IAA1050901; GA MŠk OC 518.10; GA AV ČR KSK4050111 Institutional research plan: CEZ:AV0Z4050913 Keywords : metastability * degradation * poly[methyl(phenyl)silylene] Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 0.457, year: 2001
Kuribayashi, Kazuhiko; Kumar, M. S. Vijaya
2012-01-01
Undercooling a melt often facilitates a metastable phase to nucleate preferentially. Although the classical nucleation theory shows that the most critical factor for forming a metastable phase is the interface free energy, the crystallographic stability is also indispensable for the phase to be frozen at ambient temperature. In compound materials such as oxides, authors have suggested that the decisive factors for forming a critical nucleus are not only the free energy difference but also the difference of the entropy of fusion between stable and metastable phases. In the present study, using REFeO3 (RE: rare-earth element) as a model material, we investigate the formation of a metastable phase from undercooled melts with respect to the competitive nucleation and crystallographical stabilities of both phases.
Rabesiaka, Mihasina; Porte, Catherine; Bonnin-Paris, Johanne; Havet, Jean-Louis
2011-10-01
An essential tool in the study of crystallization is the saturation curve and metastable zone width, since the shape of the solubility curve defines the crystallization mode and the supersaturation conditions, which are the driving force of crystallization. The purpose of this work was to determine saturation and supersaturation curves of lysine monohydrochloride by an automatic method based on the turbidity of the crystallization medium. As lysine solution is colored, the interest of turbidimetry is demonstrated. An automated installation and the procedure to determine several points on the saturation curve and metastable zone width were set up in the laboratory. On-line follow-up of the solution turbidity and temperature enabled the dissolution and nucleation temperatures of the crystals to be determined by measuring attenuation of the light beam by suspended particles. The thermal regulation system was programmed so that the heating rate took into account the system inertia, i.e. duration related to the dissolution rate of the compound. Using this automatic method, the saturation curve and the metastable zone width of lysine monohydrochloride were plotted.
A comparison of binding energy and metastable zone width for adipic acid with various additives
Myerson, Allan S.; Jang, Shyh M.
1995-12-01
The binding energy of nine alkanoic acids to the major crystal faces of adipic acid were calculated employing molecular modelling techniques. The results indicate that the alkanoic acids bind strongly to the surface when compared to solvents and to adipic acid itself indicating that the alkanoic acids could be potential growth and nucleation inhibitors. The binding energies were found to increase with increasing carbon number to C 14 to decrease from C 14 to C 16 and then to increase again. The effect of the alkanoic acids on the metastable zone width of adipic acid in ethanol solution were measured employing a differential scanning calorimeter. The results showed that each of the nine alkanoic acids increased the metastable zone width. The metastable zone widths were found to increase with increasing carbon number to C 14 to decrease from C 14 to C 16 and to then increase again thus correlating well with the results obtained from binding energies. These results indicate that binding energy calculations appear to provide a valid method to screen impurities as potential nucleation inhibitors.
Phase transformation of metastable cubic γ-phase in U-Mo alloys
International Nuclear Information System (INIS)
Sinha, V.P.; Hegde, P.V.; Prasad, G.J.; Dey, G.K.; Kamath, H.S.
2010-01-01
Over the past decade considerable efforts have been put by many fuel designers to develop low enriched uranium (LEU 235 ) base U-Mo alloy as a potential fuel for core conversion of existing research and test reactors which are running on high enriched uranium (HEU > 85%U 235 ) fuel and also for the upcoming new reactors. U-Mo alloy with minimum 8 wt% molybdenum shows excellent metastability with cubic γ-phase in cast condition. However, it is important to characterize the decomposition behaviour of metastable cubic γ-uranium in its equilibrium products for in reactor fuel performance point of view. The present paper describes the phase transformation behaviour of cubic γ-uranium phase in U-Mo alloys with three different molybdenum compositions (i.e. 8 wt%, 9 wt% and 10 wt%). U-Mo alloys were prepared in an induction melting furnace and characterized by X-ray diffraction (XRD) method for phase determination. Microstructures were developed for samples in as cast condition. The alloys were hot rolled in cubic γ-phase to break the cast structure and then they were aged at 500 o C for 68 h and 240 h, so that metastable cubic γ-uranium will undergo eutectoid decomposition to form equilibrium phases of orthorhombic α-uranium and body centered tetragonal U 2 Mo intermetallic compound. U-Mo alloy samples with different ageing history were then characterized by XRD for phase and development of microstructure.
Lifetimes of metastable levels of singly ionized titanium: theory and experiment
International Nuclear Information System (INIS)
Palmeri, P; Quinet, P; Biemont, E; Gurell, J; Lundin, P; Royen, P; Mannervik, S; Norlin, L-O; Blagoev, K
2008-01-01
This paper presents new theoretical lifetimes of metastable levels in singly ionized titanium, Ti II. Along with the lifetimes, transition probabilities for several decay channels from these metastable levels are presented. The calculations are supported by experimental lifetime determinations of the 3d 3 b 2 D 5/2 and 3d 2 ( 3 P)4s b 2 P 3/2 levels along with revised values of the previously published lifetimes of the 3d 2 ( 3 P)4s b 4 P 5/2 and 3d 2 ( 3 P)4s b 2 P 1/2 levels originating partly from a reanalysis utilizing a recently developed method applied on the previously recorded data and partly from new measurements. The presented theoretical investigation of lifetimes of metastable levels in Ti II shows that the HFR calculations are in general compatible with measurements performed using the ion storage ring CRYRING of Stockholm University. The transition probabilities of forbidden lines derived from the new lifetime values will be useful for the diagnostics of low density laboratory or astrophysical plasmas, particularly those encountered in the strontium filament found in the ejecta of η Carinae
Barrow, Matthew S; Williams, P Rhodri; Chan, Hoi-Houng; Dore, John C; Bellissent-Funel, Marie-Claire
2012-10-14
High-speed photographic studies and neutron diffraction measurements have been made of water under tension in a Berthelot tube. Liquid water was cooled below the normal ice-nucleation temperature and was in a doubly-metastable state prior to a collapse of the liquid state. This transition was accompanied by an exothermic heat release corresponding with the rapid production of a solid phase nucleated by cavitation. Photographic techniques have been used to observe the phase transition over short time scales in which a solidification front is observed to propagate through the sample. Significantly, other images at a shorter time interval reveal the prior formation of cavitation bubbles at the beginning of the process. The ice-nucleation process is explained in terms of a mechanism involving hydrodynamically-induced changes in tension in supercooled water in the near vicinity of an expanding cavitation bubble. Previous explanations have attributed the nucleation of the solid phase to the production of high positive pressures. Corresponding results are presented which show the initial neutron diffraction pattern after ice-nucleation. The observed pattern does not exhibit the usual crystalline pattern of hexagonal ice [I(h)] that is formed under ambient conditions, but indicates the presence of other ice forms. The composite features can be attributed to a mixture of amorphous ice, ice-I(h)/I(c) and the high-pressure form, ice-III, and the diffraction pattern continues to evolve over a time period of about an hour.
Efremenko, V. G.; Shimizu, K.; Cheiliakh, A. P.; Pastukhova, T. V.; Chabak, Yu. G.; Kusumoto, K.
2016-06-01
Full factorial design was used to evaluate the two-body abrasive resistance of 3wt%C-4wt%Mn-1.5wt%Ni spheroidal carbide cast irons with varying vanadium (5.0wt%-10.0wt%) and chromium (up to 9.0wt%) contents. The alloys were quenched at 920°C. The regression equation of wear rate as a function of V and Cr contents was proposed. This regression equation shows that the wear rate decreases with increasing V content because of the growth of spheroidal VC carbide amount. Cr influences the overall response in a complex manner both by reducing the wear rate owing to eutectic carbides (M7C3) and by increasing the wear rate though stabilizing austenite to deformation-induced martensite transformation. This transformation is recognized as an important factor in increasing the abrasive response of the alloys. By analyzing the regression equation, the optimal content ranges are found to be 7.5wt%-10.0wt% for V and 2.5wt%-4.5wt% for Cr, which corresponds to the alloys containing 9vol%-15vol% spheroidal VC carbides, 8vol%-16vol% M7C3, and a metastable austenite/martensite matrix. The wear resistance is 1.9-2.3 times that of the traditional 12wt% V-13wt% Mn spheroidal carbide cast iron.
International Nuclear Information System (INIS)
Han, J.G.
1985-01-01
Fatigue response of ion implanted Ti-24V alloy was studied under strain and stress controlled fatigue conditions. The structural changes by ion implantation were investigated using Auger electron spectroscopy (AES), x-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). Nitrogen and boron implantation resulted in surface regions having a fine titanium nitride and dense titanium boride, respectively. A metastable substitutional solid solution was produced through vanadium implantation. These modifications in surface structure altered the surface deformation modes and crack initiation response and the related fatigue life under strain controlled fatigue conditions. Nitrogen and vanadium implantation resulted in a beneficial effect in strain controlled fatigue. The improvement contributed to enhancement of crack nucleation resistance through strain homogenization for nitrogen implanted surfaces and an increase of slip reversibility for vanadium implanted specimens. The inhomogeneous coarse slip resulting from boron implantation induced early crack initiation under strain controlled conditions and thereby reduced the fatigue life. Under stress controlled fatigue conditions, fatigue life and endurance limit were enhanced following ion implantation with nitrogen, boron, and vanadium
Viaris De Lesegno, B; Perales, F; Mainos, C; Reinhardt, J; Baudon, J; Grancharova, D; Durt, T; Robert, J; Boustimi, M; Bocvarski, V; Dos Santos, F P; Durt, T; Haberland, H
2003-01-01
A new Stern Gerlach interferometer operating with a nozzle beam of metastable argon atoms Ar* (3p sup 5 4s, sup 3 P sub 2) is described. The selection of incoming (polarisation) and outgoing (analysis) Zeeman sublevels is achieved by use of laser induced transitions at two wavelengths, 811.5 nm (closed J 2 -> J = 3 transition) and 801.5 nm (open J = 2 -> J = 2 transition). Linear superpositions of Zeeman sublevels, just beyond the polarizer and just before the analyser, are prepared by means of two zones where Majorana transitions take place. In between, a controlled magnetic field configuration (the phase object) is produced within a triple mu-metal shielding. Standard interference patterns are obtained by scanning the field and detecting the atoms by secondary electron emission from a Faraday cup. When a static radial magnetic gradient is used, the beam profile is modulated by interference. The transverse pattern. which can be translated at will by adding a homogeneous field, is observed for the first time ...
Maréchal, David; Sinclair, Chad W.; Dufour, Philippe; Jacques, Pascal J.; Mithieux, Jean-Denis
2012-12-01
In order to construct physically based models of the mechanical response of metastable austenitic steels, one must know the load partitioning between the austenite and the strain-induced martensitic phases. While diffraction-based techniques have become common for such measurements, they often require access to large facilities. In this work, we have explored a simple magnetic technique capable of providing a measure of the stresses in an embedded ferromagnetic phase. This technique makes use of the coupling between the elastic strain and the magnetic response of the α^'-martensite in an austenitic stainless steel undergoing straining. The magnetic technique proposed here is compared to neutron diffraction measurements made on the same material and is shown to give nearly identical results. The resulting predictions of the load partitioning to the α^'-martensite phase suggest that α^' deforms in a complex fashion, reflecting the fact that the microstructure is progressively transformed from austenite to martensite with straining. In particular, it is shown that the apparent hardening of the α^'-martensite suggests elastic deformation as an important source of high macroscopic work-hardening rate in this material.
International Nuclear Information System (INIS)
Weatherford, Brandon R.; Barnat, E. V.; Xiong, Zhongmin; Kushner, Mark J.
2014-01-01
Fast ionization waves (FIWs), often generated with high voltage pulses over nanosecond timescales, are able to produce large volumes of ions and excited states at moderate pressures. The mechanisms of FIW propagation were experimentally and computationally investigated to provide insights into the manner in which these large volumes are excited. The two-dimensional structure of electron and metastable densities produced by short-pulse FIWs sustained in helium were measured using laser-induced fluorescence and laser collision-induced fluorescence diagnostics for times of 100–120 ns after the pulse, as the pressure was varied from 1 to 20 Torr. A trend of center-peaked to volume-filling to wall-peaked electron density profiles was observed as the pressure was increased. Instantaneous FIW velocities, obtained from plasma-induced emission, ranged from 0.1 to 3 × 10 9 cm s −1 , depending on distance from the high voltage electrode and pressure. Predictions from two-dimensional modeling of the propagation of a single FIW correlated well with the experimental trends in electron density profiles and wave velocity. Results from the model show that the maximum ionization rate occurs in the wavefront, and the discharge continues to propagate forward after the removal of high voltage from the powered electrode due to the potential energy stored in the space charge. As the pressure is varied, the radial distribution of the ionization rate is shaped by changes in the electron mean free path, and subsequent localized electric field enhancement at the walls or on the centerline of the discharge.
Introduction to Dynamical Systems and Geometric Mechanics
Maruskin, Jared M.
2012-01-01
Introduction to Dynamical Systems and Geometric Mechanics provides a comprehensive tour of two fields that are intimately entwined: dynamical systems is the study of the behavior of physical systems that may be described by a set of nonlinear first-order ordinary differential equations in Euclidean space, whereas geometric mechanics explores similar systems that instead evolve on differentiable manifolds. In the study of geometric mechanics, however, additional geometric structures are often present, since such systems arise from the laws of nature that govern the motions of particles, bodies, and even galaxies. In the first part of the text, we discuss linearization and stability of trajectories and fixed points, invariant manifold theory, periodic orbits, PoincarÃ© maps, Floquet theory, the PoincarÃ©-Bendixson theorem, bifurcations, and chaos. The second part of the text begins with a self-contained chapter on differential geometry that introduces notions of manifolds, mappings, vector fields, the Jacobi-Lie bracket, and differential forms. The final chapters cover Lagrangian and Hamiltonian mechanics from a modern geometric perspective, mechanics on Lie groups, and nonholonomic mechanics via both moving frames and fiber bundle decompositions. The text can be reasonably digested in a single-semester introductory graduate-level course. Each chapter concludes with an application that can serve as a springboard project for further investigation or in-class discussion.
Nodal free geometric phases: Concept and application to geometric quantum computation
International Nuclear Information System (INIS)
Ericsson, Marie; Kult, David; Sjoeqvist, Erik; Aberg, Johan
2008-01-01
Nodal free geometric phases are the eigenvalues of the final member of a parallel transporting family of unitary operators. These phases are gauge invariant, always well defined, and can be measured interferometrically. Nodal free geometric phases can be used to construct various types of quantum phase gates
Estimating motors from a variety of geometric data in 3D conformal geometric algebra
Valkenburg, R.; Dorst, L.; Dorst, L.; Lasenby, J.
2011-01-01
The motion rotors, or motors, are used to model Euclidean motion in 3D conformal geometric algebra. In this chapter we present a technique for estimating the motor which best transforms one set of noisy geometric objects onto another. The technique reduces to an eigenrotator problem and has some
Geometric function theory in higher dimension
2017-01-01
The book collects the most relevant outcomes from the INdAM Workshop “Geometric Function Theory in Higher Dimension” held in Cortona on September 5-9, 2016. The Workshop was mainly devoted to discussions of basic open problems in the area, and this volume follows the same line. In particular, it offers a selection of original contributions on Loewner theory in one and higher dimensions, semigroups theory, iteration theory and related topics. Written by experts in geometric function theory in one and several complex variables, it focuses on new research frontiers in this area and on challenging open problems. The book is intended for graduate students and researchers working in complex analysis, several complex variables and geometric function theory.
Geometrical factors in the perception of sacredness
DEFF Research Database (Denmark)
Costa, Marco; Bonetti, Leonardo
2016-01-01
in geometrical figures differing in shape, verticality, size, and symmetry. Verticality, symmetry, and convexity were found to be important factors in the perception of sacredness. In the second test, participants had to mark the point inside geometrical surfaces that was perceived as most sacred, dominant......Geometrical and environmental factors in the perception of sacredness, dominance, and attractiveness were assessed by 137 participants in five tests. In the first test, a two-alternative forced-choice paradigm was used to test the perception of sacredness, dominance, and attractiveness......, and attractive. The top and the center areas were associated with sacredness, dominance, and attractiveness. In the third test, peaks and elevated regions in landscapes were evaluated as more sacred, dominant, and attractive than valley regions. In the fourth test, three figures sharing the same area...
MM Algorithms for Geometric and Signomial Programming.
Lange, Kenneth; Zhou, Hua
2014-02-01
This paper derives new algorithms for signomial programming, a generalization of geometric programming. The algorithms are based on a generic principle for optimization called the MM algorithm. In this setting, one can apply the geometric-arithmetic mean inequality and a supporting hyperplane inequality to create a surrogate function with parameters separated. Thus, unconstrained signomial programming reduces to a sequence of one-dimensional minimization problems. Simple examples demonstrate that the MM algorithm derived can converge to a boundary point or to one point of a continuum of minimum points. Conditions under which the minimum point is unique or occurs in the interior of parameter space are proved for geometric programming. Convergence to an interior point occurs at a linear rate. Finally, the MM framework easily accommodates equality and inequality constraints of signomial type. For the most important special case, constrained quadratic programming, the MM algorithm involves very simple updates.
Geometric inequalities for axially symmetric black holes
International Nuclear Information System (INIS)
Dain, Sergio
2012-01-01
A geometric inequality in general relativity relates quantities that have both a physical interpretation and a geometrical definition. It is well known that the parameters that characterize the Kerr-Newman black hole satisfy several important geometric inequalities. Remarkably enough, some of these inequalities also hold for dynamical black holes. This kind of inequalities play an important role in the characterization of the gravitational collapse; they are closely related with the cosmic censorship conjecture. Axially symmetric black holes are the natural candidates to study these inequalities because the quasi-local angular momentum is well defined for them. We review recent results in this subject and we also describe the main ideas behind the proofs. Finally, a list of relevant open problems is presented. (topical review)
EARLY HISTORY OF GEOMETRIC PROBABILITY AND STEREOLOGY
Directory of Open Access Journals (Sweden)
Magdalena Hykšová
2012-03-01
Full Text Available The paper provides an account of the history of geometric probability and stereology from the time of Newton to the early 20th century. It depicts the development of two parallel ways: on one hand, the theory of geometric probability was formed with minor attention paid to other applications than those concerning spatial chance games. On the other hand, practical rules of the estimation of area or volume fraction and other characteristics, easily deducible from geometric probability theory, were proposed without the knowledge of this branch. A special attention is paid to the paper of J.-É. Barbier published in 1860, which contained the fundamental stereological formulas, but remained almost unnoticed both by mathematicians and practicians.
Understanding geometric algebra for electromagnetic theory
Arthur, John W
2011-01-01
"This book aims to disseminate geometric algebra as a straightforward mathematical tool set for working with and understanding classical electromagnetic theory. It's target readership is anyone who has some knowledge of electromagnetic theory, predominantly ordinary scientists and engineers who use it in the course of their work, or postgraduate students and senior undergraduates who are seeking to broaden their knowledge and increase their understanding of the subject. It is assumed that the reader is not a mathematical specialist and is neither familiar with geometric algebra or its application to electromagnetic theory. The modern approach, geometric algebra, is the mathematical tool set we should all have started out with and once the reader has a grasp of the subject, he or she cannot fail to realize that traditional vector analysis is really awkward and even misleading by comparison"--Provided by publisher.
Geometric optimization and sums of algebraic functions
Vigneron, Antoine E.
2014-01-01
We present a new optimization technique that yields the first FPTAS for several geometric problems. These problems reduce to optimizing a sum of nonnegative, constant description complexity algebraic functions. We first give an FPTAS for optimizing such a sum of algebraic functions, and then we apply it to several geometric optimization problems. We obtain the first FPTAS for two fundamental geometric shape-matching problems in fixed dimension: maximizing the volume of overlap of two polyhedra under rigid motions and minimizing their symmetric difference. We obtain the first FPTAS for other problems in fixed dimension, such as computing an optimal ray in a weighted subdivision, finding the largest axially symmetric subset of a polyhedron, and computing minimum-area hulls.
Exponentiated Lomax Geometric Distribution: Properties and Applications
Directory of Open Access Journals (Sweden)
Amal Soliman Hassan
2017-09-01
Full Text Available In this paper, a new four-parameter lifetime distribution, called the exponentiated Lomax geometric (ELG is introduced. The new lifetime distribution contains the Lomax geometric and exponentiated Pareto geometric as new sub-models. Explicit algebraic formulas of probability density function, survival and hazard functions are derived. Various structural properties of the new model are derived including; quantile function, Re'nyi entropy, moments, probability weighted moments, order statistic, Lorenz and Bonferroni curves. The estimation of the model parameters is performed by maximum likelihood method and inference for a large sample is discussed. The flexibility and potentiality of the new model in comparison with some other distributions are shown via an application to a real data set. We hope that the new model will be an adequate model for applications in various studies.
Czech Academy of Sciences Publication Activity Database
Hausild, P.; Davydov, Vadim; Drahokoupil, Jan; Landa, Michal; Pilvin, P.
2010-01-01
Roč. 31, č. 4 (2010), s. 1821-1827 ISSN 0261-3069 R&D Projects: GA ČR GA106/07/0805 Institutional research plan: CEZ:AV0Z10480505; CEZ:AV0Z10100520; CEZ:AV0Z20760514 Keywords : Microstructure * Non-destructive testing (NDT) * Electron backscatter diffraction Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.694, year: 2010
Primary School Teacher Candidates' Geometric Habits of Mind
Köse, Nilu¨fer Y.; Tanisli, Dilek
2014-01-01
Geometric habits of mind are productive ways of thinking that support learning and using geometric concepts. Identifying primary school teacher candidates' geometric habits of mind is important as they affect the development of their future students' geometric thinking. Therefore, this study attempts to determine primary school teachers' geometric…
Alternate Derivation of Geometric Extended Kalman Filter by MEKF Approach
Chang, Lubin
2017-01-01
This note is devoted to deriving the measurement update of the geometric extended Kalman filter using the multiplicative extended Kalman filtering approach, resulting in the attitude estimator referred as geometric multiplicative extended Kalman filter. The equivalence of the derived geometric multiplicative extended Kalman filter and geometric extended Kalman filter is also demonstrated in this note.
Geometric Weil representation in characteristic two
Genestier, Alain; Lysenko, Sergey
2009-01-01
International audience; Let k be an algebraically closed field of characteristic two. Let R be the ring of Witt vectors of length two over k. We construct a group stack \\hat G over k, the metaplectic extension of the Greenberg realization of Sp_{2n}(R). We also construct a geometric analog of the Weil representation of \\hat G, this is a triangulated category on which \\hat G acts by functors. This triangulated category and the action are geometric in a suitable sense.
Robust topology optimization accounting for geometric imperfections
DEFF Research Database (Denmark)
Schevenels, M.; Jansen, M.; Lombaert, Geert
2013-01-01
performance. As a consequence, the actual structure may be far from optimal. In this paper, a robust approach to topology optimization is presented, taking into account two types of geometric imperfections: variations of (1) the crosssections and (2) the locations of structural elements. The first type......Topology optimization is a powerful method to optimize the performance of macro, micro, or nano structures. However, the geometry of the actual structure may differ from the optimized design due to manufacturing errors. Such geometric imperfections can have a significant impact on the structural...
The geometric phase in quantum physics
International Nuclear Information System (INIS)
Bohm, A.
1993-03-01
After an explanatory introduction, a quantum system in a classical time-dependent environment is discussed; an example is a magnetic moment in a classical magnetic field. At first, the general abelian case is discussed in the adiabatic approximation. Then the geometric phase for nonadiabatic change of the environment (Anandan--Aharonov phase) is introduced, and after that general cyclic (nonadiabatic) evolution is discussed. The mathematics of fiber bundles is introduced, and some of its results are used to describe the relation between the adiabatic Berry phase and the geometric phase for general cyclic evolution of a pure state. The discussion is restricted to the abelian, U(1) phase
Workshop on Topology and Geometric Group Theory
Fowler, James; Lafont, Jean-Francois; Leary, Ian
2016-01-01
This book presents articles at the interface of two active areas of research: classical topology and the relatively new field of geometric group theory. It includes two long survey articles, one on proofs of the Farrell–Jones conjectures, and the other on ends of spaces and groups. In 2010–2011, Ohio State University (OSU) hosted a special year in topology and geometric group theory. Over the course of the year, there were seminars, workshops, short weekend conferences, and a major conference out of which this book resulted. Four other research articles complement these surveys, making this book ideal for graduate students and established mathematicians interested in entering this area of research.
Geometric calibration of ERS satellite SAR images
DEFF Research Database (Denmark)
Mohr, Johan Jacob; Madsen, Søren Nørvang
2001-01-01
Geometric calibration of the European Remote Sensing (ERS) Satellite synthetic aperture radar (SAR) slant range images is important in relation to mapping areas without ground reference points and also in relation to automated processing. The relevant SAR system parameters are discussed and calib......Geometric calibration of the European Remote Sensing (ERS) Satellite synthetic aperture radar (SAR) slant range images is important in relation to mapping areas without ground reference points and also in relation to automated processing. The relevant SAR system parameters are discussed...
Geometric nonlinear functional analysis volume 1
Benyamini, Yoav
1999-01-01
The book presents a systematic and unified study of geometric nonlinear functional analysis. This area has its classical roots in the beginning of the twentieth century and is now a very active research area, having close connections to geometric measure theory, probability, classical analysis, combinatorics, and Banach space theory. The main theme of the book is the study of uniformly continuous and Lipschitz functions between Banach spaces (e.g., differentiability, stability, approximation, existence of extensions, fixed points, etc.). This study leads naturally also to the classification of
Sudan-decoding generalized geometric Goppa codes
DEFF Research Database (Denmark)
Heydtmann, Agnes Eileen
2003-01-01
Generalized geometric Goppa codes are vector spaces of n-tuples with entries from different extension fields of a ground field. They are derived from evaluating functions similar to conventional geometric Goppa codes, but allowing evaluation in places of arbitrary degree. A decoding scheme...... for these codes based on Sudan's improved algorithm is presented and its error-correcting capacity is analyzed. For the implementation of the algorithm it is necessary that the so-called increasing zero bases of certain spaces of functions are available. A method to obtain such bases is developed....
International Nuclear Information System (INIS)
Li, Shou-Zhe; Zhang, Xin; Chen, Chuan-Jie; Zhang, Jialiang; Wang, Yong-Xing; Xia, Guang-Qing
2014-01-01
The atmospheric-pressure microwave N 2 -H 2 plasma torch is generated and diagnosed by optical emission spectroscopy. It is found that a large amount of N atoms and NH radicals are generated in the plasma torch and the emission intensity of N 2 + first negative band is the strongest over the spectra. The mixture of hydrogen in nitrogen plasma torch causes the morphology of the plasma discharge to change with appearance that the afterglow shrinks greatly and the emission intensity of N 2 + first negative band decreases with more hydrogen mixed into nitrogen plasma. In atmospheric-pressure microwave-induced plasma torch, the hydrogen imposes a great influence on the characteristics of nitrogen plasma through the quenching effect of the hydrogen on the metastable state of N 2
Robust topology optimization accounting for geometric imperfections
DEFF Research Database (Denmark)
Schevenels, M.; Jansen, M.; Lombaert, Geert
2013-01-01
performance. As a consequence, the actual structure may be far from optimal. In this paper, a robust approach to topology optimization is presented, taking into account two types of geometric imperfections: variations of (1) the crosssections and (2) the locations of structural elements. The first type...
A graph spectrum based geometric biclustering algorithm.
Wang, Doris Z; Yan, Hong
2013-01-21
Biclustering is capable of performing simultaneous clustering on two dimensions of a data matrix and has many applications in pattern classification. For example, in microarray experiments, a subset of genes is co-expressed in a subset of conditions, and biclustering algorithms can be used to detect the coherent patterns in the data for further analysis of function. In this paper, we present a graph spectrum based geometric biclustering (GSGBC) algorithm. In the geometrical view, biclusters can be seen as different linear geometrical patterns in high dimensional spaces. Based on this, the modified Hough transform is used to find the Hough vector (HV) corresponding to sub-bicluster patterns in 2D spaces. A graph can be built regarding each HV as a node. The graph spectrum is utilized to identify the eigengroups in which the sub-biclusters are grouped naturally to produce larger biclusters. Through a comparative study, we find that the GSGBC achieves as good a result as GBC and outperforms other kinds of biclustering algorithms. Also, compared with the original geometrical biclustering algorithm, it reduces the computing time complexity significantly. We also show that biologically meaningful biclusters can be identified by our method from real microarray gene expression data. Copyright © 2012 Elsevier Ltd. All rights reserved.
An information theoretic approach to geometric clustering
Strouse, Dj; Schwab, David
Clustering is a basic task in data analysis for both understanding and pre-processing data. Classic clustering methods, such as k-means or EM fitting of a gaussian mixture model, are based on geometry. These geometric clustering methods group data points together based on their Euclidean distance from one another; roughly speaking, points within a cluster have smaller distances to one another than to points in other clusters. More recently, however, distributional clustering methods, such as the information bottleneck (IB) and deterministic information bottleneck (DIB), have been introduced that group data points based upon their conditional distributions over a target variable. Here, points within a cluster provide similar information about the target variable. Are distributional and geometric clustering related, and if so, how? Can we blend these two approaches? Here we first describe a method to incorporate geometric information into the (D)IB clustering algorithm, where the target variable our clustering should be informative about is the spatial location of the contained data points. This enables us to derive a novel set of geometric clustering algorithms, which we then compare to the classic methods mentioned above. Finally, we compare both approaches on data.
Geometric Abstract Art and Public Health Data
Centers for Disease Control (CDC) Podcasts
2016-10-18
Dr. Salaam Semaan, a CDC behavioral scientist, discusses the similarities between geometric abstract art and public health data analysis. Created: 10/18/2016 by National Center for Emerging and Zoonotic Infectious Diseases (NCEZID). Date Released: 10/18/2016.
Left ventricular hypertrophy, geometric patterns and clinical ...
African Journals Online (AJOL)
Background: Left ventricular hypertrophy can be due to various reasons including hypertension. It constitutes an increased cardiovascular risk. Various left ventricular geometric patterns occur in hypertension and may affect the cardiovascular risk profile of hypertensive subjects. Methods: One hundred and eighty eight ...
Geometrical tile design for complex neighborhoods.
Czeizler, Eugen; Kari, Lila
2009-01-01
Recent research has showed that tile systems are one of the most suitable theoretical frameworks for the spatial study and modeling of self-assembly processes, such as the formation of DNA and protein oligomeric structures. A Wang tile is a unit square, with glues on its edges, attaching to other tiles and forming larger and larger structures. Although quite intuitive, the idea of glues placed on the edges of a tile is not always natural for simulating the interactions occurring in some real systems. For example, when considering protein self-assembly, the shape of a protein is the main determinant of its functions and its interactions with other proteins. Our goal is to use geometric tiles, i.e., square tiles with geometrical protrusions on their edges, for simulating tiled paths (zippers) with complex neighborhoods, by ribbons of geometric tiles with simple, local neighborhoods. This paper is a step toward solving the general case of an arbitrary neighborhood, by proposing geometric tile designs that solve the case of a "tall" von Neumann neighborhood, the case of the f-shaped neighborhood, and the case of a 3 x 5 "filled" rectangular neighborhood. The techniques can be combined and generalized to solve the problem in the case of any neighborhood, centered at the tile of reference, and included in a 3 x (2k + 1) rectangle.
Rejuvenating Allen's Arc with the Geometric Mean.
Phillips, William A.
1994-01-01
Contends that, despite ongoing criticism, Allen's arc elasticity formula remains entrenched in the microeconomics principles curriculum. Reviews the evolution and continuing scrutiny of the formula. Argues that the use of the geometric mean offers pedagogical advantages over the traditional arithmetic mean approach. (CFR)
Online course Geometrical Optics for undergraduate students
Bakholdin, Alexey; Voznesenskaya, Anna; Romanova, Galina; Ivanova, Tatiana; Tolstoba, Nadezhda; Ezhova, Kseniia; Garshin, Aleksei; Trifonov, Oleg; Sazonenko, Dmitry; Ekimenkova, Alisa
2017-08-01
The paper is devoted to the description of the on-line course "Geometrical Optics" placed on the national open-education platform. The course is purposed mainly for undergraduate students in optics and related fields. We discuss key features of the on-line form of this course, the issues of its realization and learning outcomes' evaluation.
Two particle entanglement and its geometric duals
International Nuclear Information System (INIS)
Wasay, Muhammad Abdul; Bashir, Asma
2017-01-01
We show that for a system of two entangled particles, there is a dual description to the particle equations in terms of classical theory of conformally stretched spacetime. We also connect these entangled particle equations with Finsler geometry. We show that this duality translates strongly coupled quantum equations in the pilot-wave limit to weakly coupled geometric equations. (orig.)
Non-equilibrium current via geometric scatterers
Czech Academy of Sciences Publication Activity Database
Exner, Pavel; Neidhardt, H.; Tater, Miloš; Zagrebnov, V. A.
2014-01-01
Roč. 47, č. 39 (2014), s. 395301 ISSN 1751-8113 R&D Projects: GA ČR(CZ) GA14-06818S Institutional support: RVO:61389005 Keywords : non-equilibrioum steady states * geometric scatterer * Landauer-Buttiker formula Subject RIV: BE - Theoretical Physics Impact factor: 1.583, year: 2014
Robust Geometric Control of a Distillation Column
DEFF Research Database (Denmark)
Kymmel, Mogens; Andersen, Henrik Weisberg
1987-01-01
A frequency domain method, which makes it possible to adjust multivariable controllers with respect to both nominal performance and robustness, is presented. The basic idea in the approach is that the designer assigns objectives such as steady-state tracking, maximum resonance peaks, bandwidth, m...... is used to examine and improve geometric control of a binary distillation column....
Geometrical efficiency in computerized tomography: generalized model
International Nuclear Information System (INIS)
Costa, P.R.; Robilotta, C.C.
1992-01-01
A simplified model for producing sensitivity and exposure profiles in computerized tomographic system was recently developed allowing the forecast of profiles behaviour in the rotation center of the system. The generalization of this model for some point of the image plane was described, and the geometrical efficiency could be evaluated. (C.G.C.)
Two particle entanglement and its geometric duals
Energy Technology Data Exchange (ETDEWEB)
Wasay, Muhammad Abdul [University of Agriculture, Department of Physics, Faisalabad (Pakistan); Quaid-i-Azam University Campus, National Centre for Physics, Islamabad (Pakistan); Bashir, Asma [University of Agriculture, Department of Physics, Faisalabad (Pakistan)
2017-12-15
We show that for a system of two entangled particles, there is a dual description to the particle equations in terms of classical theory of conformally stretched spacetime. We also connect these entangled particle equations with Finsler geometry. We show that this duality translates strongly coupled quantum equations in the pilot-wave limit to weakly coupled geometric equations. (orig.)
Impossible Geometric Constructions: A Calculus Writing Project
Awtrey, Chad
2013-01-01
This article discusses a writing project that offers students the opportunity to solve one of the most famous geometric problems of Greek antiquity; namely, the impossibility of trisecting the angle [pi]/3. Along the way, students study the history of Greek geometry problems as well as the life and achievements of Carl Friedrich Gauss. Included is…
Wooden Geometric Puzzles: Design and Hardness Proofs
Alt, H.; Bodlaender, H.L.; Kreveld, M.J. van; Rote, G.; Tel, G.
2008-01-01
We discuss some new geometric puzzles and the complexity of their extension to arbitrary sizes. For gate puzzles and two-layer puzzles we prove NP-completeness of solving them. Not only the solution of puzzles leads to interesting questions, but also puzzle design gives rise to interesting
Reinforcing Geometric Properties with Shapedoku Puzzles
Wanko, Jeffrey J.; Nickell, Jennifer V.
2013-01-01
Shapedoku is a new type of puzzle that combines logic and spatial reasoning with understanding of basic geometric concepts such as slope, parallelism, perpendicularity, and properties of shapes. Shapedoku can be solved by individuals and, as demonstrated here, can form the basis of a review for geometry students as they create their own. In this…
Wooden Geometric Puzzles: Design and Hardness Proofs
Alt, H.; Bodlaender, H.L.; Kreveld, M.J. van; Rote, G.; Tel, G.
2007-01-01
We discuss some new geometric puzzles and the complexity of their extension to arbitrary sizes. For gate puzzles and two-layer puzzles we prove NP-completeness of solving them. Not only the solution of puzzles leads to interesting questions, but also puzzle design gives rise to interesting
GEOMETRIC MEASUREMENTS OF THE ACETABULUM IN ADULT ...
African Journals Online (AJOL)
hi-tech
2003-10-10
Oct 10, 2003 ... Objectives: To determine the acetabular depth as well as acetabular and centre edge angles; to assess the influence of sex, if any, in these geometric measurements; and to determine the prevalence of hip dysplasia in adult Malawians. Design: A retrospective study. Setting: Queen Elizabeth Central ...
Geometrical interpretation and architecture selection of MLP.
Xiang, Cheng; Ding, Shenqiang Q; Lee, Tong Heng
2005-01-01
A geometrical interpretation of the multilayer perceptron (MLP) is suggested in this paper. Some general guidelines for selecting the architecture of the MLP, i.e., the number of the hidden neurons and the hidden layers, are proposed based upon this interpretation and the controversial issue of whether four-layered MLP is superior to the three-layered MLP is also carefully examined.
On Arithmetic-Geometric-Mean Polynomials
Griffiths, Martin; MacHale, Des
2017-01-01
We study here an aspect of an infinite set "P" of multivariate polynomials, the elements of which are associated with the arithmetic-geometric-mean inequality. In particular, we show in this article that there exist infinite subsets of probability "P" for which every element may be expressed as a finite sum of squares of real…
Geometrical scaling in high energy hadron collisions
International Nuclear Information System (INIS)
Kundrat, V.; Lokajicek, M.V.
1984-06-01
The concept of geometrical scaling for high energy elastic hadron scattering is analyzed and its basic equations are solved in a consistent way. It is shown that they are applicable to a rather small interval of momentum transfers, e.g. maximally for |t| 2 for pp scattering at the ISR energies. (author)
Geometric structures on loop and path spaces
Indian Academy of Sciences (India)
∗Departamento de Geometrıa y Topologıa, Facultad de Matemáticas,. Universidad Complutense de Madrid, 28040 Madrid, Spain. †Instituto de Ciencias ..... To finish, let us check that the familiar finite dimensional picture translates to this case. PROPOSITION 4.2. Let (M,g) be a Riemannian manifold which has a locally ...
Geometric phase topology in weak measurement
Samlan, C. T.; Viswanathan, Nirmal K.
2017-12-01
The geometric phase visualization proposed by Bhandari (R Bhandari 1997 Phys. Rep. 281 1–64) in the ellipticity-ellipse orientation basis of the polarization ellipse of light is implemented to understand the geometric aspects of weak measurement. The weak interaction of a pre-selected state, acheived via spin-Hall effect of light (SHEL), results in a spread in the polarization ellipticity (η) or ellipse orientation (χ) depending on the resulting spatial or angular shift, respectively. The post-selection leads to the projection of the η spread in the complementary χ basis results in the appearance of a geometric phase with helical phase topology in the η ‑ χ parameter space. By representing the weak measurement on the Poincaré sphere and using Jones calculus, the complex weak value and the geometric phase topology are obtained. This deeper understanding of the weak measurement process enabled us to explore the techniques’ capabilities maximally, as demonstrated via SHEL in two examples—external reflection at glass-air interface and transmission through a tilted half-wave plate.
Pucilowski, Sebastian; Tordesillas, Antoinette; Froyland, Gary
2017-06-01
In transitive metastable chaotic dynamical systems, there are no invariant neighbourhoods in the phase space. The best that one can do is look for metastable or almost-invariant (AI) regions as a means to decompose the system into its basic self-organising building blocks. Here we study the metastable dynamics of a dense granular material embodying strain localization in 3D from the perspective of its conformational landscape: the state space of all observed conformations as defined by the local topology of individual grains relative to their first ring of contacting neighbors. We determine the metastable AI sets that divide this conformational landscape, such that grain rearrangements from one conformation to another conformation in the same AI set occurs with high probability: by contrast, grain rearrangements involving conformational transitions between AI sets are unlikely. The great majority of conformational transitions are identity transitions: grains rearrange and exchange contacts to preserve those topological properties with the greatest influence on cluster stability, namely, the number of contacts and 3-cycles. Force chains show a clear preference for that AI set with the most number of accessible and highly connected conformations. Here force chains continually explore the conformational landscape, wandering from one rarely inhabited conformation to another. As force chains become overloaded and buckle, the energy released enables member grains to overcome the high dynamical barriers that separate metastable regions and subsequently escape one region to enter another in the conformational landscape. Thus, compared to grains locked in stable force chains, those in buckling force chains, confined to the shear band, show a greater propensity for not only non-identity transitions within each metastable region but also inter-transitions between metastable regions.
Can EPR non-locality be geometrical?
International Nuclear Information System (INIS)
Ne'eman, Y.
1995-01-01
The presence in Quantum Mechanics of non-local correlations is one of the two fundamentally non-intuitive features of that theory. The non-local correlations themselves fall into two classes: EPR and Geometrical. The non-local characteristics of the geometrical type are well-understood and are not suspected of possibly generating acausal features, such as faster-than-light propagation of information. This has especially become true since the emergence of a geometrical treatment for the relevant gauge theories, i.e. Fiber Bundle geometry, in which the quantum non-localities are seen to correspond to pure homotopy considerations. This aspect is reviewed in section 2. Contrary-wise, from its very conception, the EPR situation was felt to be paradoxical. It has been suggested that the non-local features of EPR might also derive from geometrical considerations, like all other non-local characteristics of QM. In[7], one of the authors was able to point out several plausibility arguments for this thesis, emphasizing in particular similarities between the non-local correlations provided by any gauge field theory and those required by the preservation of the quantum numbers of the original EPR state-vector, throughout its spatially-extended mode. The derivation was, however, somewhat incomplete, especially because of the apparent difference between, on the one hand, the closed spatial loops arising in the analysis of the geometrical non-localities, from Aharonov-Bohm and Berry phases to magnetic monopoles and instantons, and on the other hand, in the EPR case, the open line drawn by the positions of the two moving decay products of the disintegrating particle. In what follows, the authors endeavor to remove this obstacle and show that as in all other QM non-localities, EPR is somehow related to closed loops, almost involving homotopy considerations. They develop this view in section 3
Energy Technology Data Exchange (ETDEWEB)
Grucker, J
2007-12-15
In this thesis, we present a new type of atomic source: an ultra-narrow beam of metastable atoms produced by resonant metastability exchange inside a supersonic beam of rare gas atoms. We used the coherence properties of this beam to observe the diffraction of metastable helium, argon and neon atoms by a nano-transmission grating and by micro-reflection-gratings. Then, we evidenced transitions between Zeeman sublevels of neon metastable {sup 3}P{sub 2} state due to the quadrupolar part of Van der Waals potential. After we showed experimental proofs of the observation of this phenomenon, we calculated the transition probabilities in the Landau - Zener model. We discussed the interest of Van der Waals - Zeeman transitions for atom interferometry. Last, we described the Zeeman cooling of the supersonic metastable argon beam ({sup 3}P{sub 2}). We have succeeded in slowing down atoms to speeds below 100 m/s. We gave experimental details and showed the first time-of-flight measurements of slowed atoms.
Glassy and Metastable Crystalline BaTi2O5 by Containerless Processing
Yoda, Shinichi; Kentei Yu, Yu; Kumar, Vijaya; Kameko, Masashi
Many efforts have been devoted to forming bulk glass from the melt of ferroelectric crystalline materials without adding any network-forming oxides such as SiO2 due to the potential for producing transparent glass ceramics with high dielectric constant and enhanced piezoelectric, pyroelectric and electro-optic use. The containerless processing is an attractive synthesis tech-nique as it can prevent melt contamination, minimize heterogeneous nucleation, and allow melt to achieve deep undercooling for forming metastable and glassy materials. We have fabricated a new ferroelectric materiel BaTi2 O5 [1] as bulk glass from melt by us-ing containerless processing and studied the phase relationship between microstructure and ferroelectric properties of BaTi2 O5 [2]. The structures of glassy and metastable crystalline BaTi2 O5 fabricated by the containerless pro-cessing were comprehensively investigated by combined X-ray and neutron diffractions, XANES analyses and computer simulations [3]. The 3-dimensional atomic structure of glassy BaTi2 O5 (g-BaTi2 O5 ), simulated by Reverse Monte Carlo (RMC) modelling on diffraction data, shows that extremely distorted TiO5 polyhedra interconnected with both corner-and edge-shared oxy-gen, formed a higher packing density structure than that of conventional silicate glass linked with only corner-sharing of SiO4 polyhedra. In addition, XANES measurement reveales that five-coordinated TiO5 polyhedra were formable in the crystallized metastable a-and b-BaTi2 O5 phases. The structure of metastable b-BaTi2 O5 was solved by ab initio calculation, and refined by Rietveld refinement as group Pnma with unit lattices a = 10.23784 ˚, b = 3.92715 ˚, c A A = 10.92757 A ˚. Our results show that the glass-forming ability enhanced by containerless pro-cessing, not by `strong glass former', fabricated new bulk oxide glasses with peculiar structures and properties. The intermediate-range structure of g-BaTi2 O5 and the crystalline structure of
Recombination and detachment in oxygen discharges: the role of metastable oxygen molecules
International Nuclear Information System (INIS)
Gudmundsson, J T
2004-01-01
A global (volume averaged) model of oxygen discharges is used to study the transition from a recombination dominated discharge to a detachment dominated discharge. The model includes the metastable oxygen molecules O 2 (a 1 Δ g ) and O 2 (b 1 Σ g + ) and the three Herzberg states O 2 (A 3 Σ u + , A' 3 Δ u , c 1 Σ u - ). Dissociative attachment of the oxygen molecule in the ground state O 2 ( 3 Σ g - ) and the metastable oxygen molecule O 2 (a 1 Δ g ) are the dominating channels for creation of the negative oxygen ion O - . At high pressures, dissociative attachment of the Herzberg states contributes significantly to the creation of the negative oxygen ion, O - . The detachment by a collision of the metastable oxygen molecule O 2 (b 1 Σ g + ) with the oxygen ion, O - , is a significant loss process for the O - at pressures above 10 mTorr. Its contribution to the loss is more significant at a lower applied power, but at the higher pressures it is always significant. Detachment by collision with O( 3 P) is also an important loss mechanism for O - . We find that ion-ion recombination is the dominating loss process for negative ions in oxygen discharges at low pressures and calculate the critical pressure where the contributions of recombination reactions and detachment reactions are equal. This critical pressure depends on the applied power, increases with applied power and is in the range 5-14 mTorr in the pressure and power range investigated
Balibar, S
2003-01-01
How far can one supercool a liquid before it crystallizes? How much can one stretch it before cavitation occurs? In order to answer such questions, we have studied liquid helium, a model system. In this review, we show the limitations of the elementary 'standard nucleation theory'. We then show that the existence of 'spinodal' limits needs to be considered in the framework of 'density functional' methods. We also briefly consider the possibility of nucleation by quantum tunnelling. The main emphasis is on cavitation and crystallization in liquid helium, but we also mention several connections with more classical systems, in particular water.
Investigation into the production of metastable Nb3Ge powder via the rotating electrode process
International Nuclear Information System (INIS)
McCormick, J.P.
1977-12-01
The production of metastable Nb 3 Ge powder via the rotating electrode process (REP) employing ''splat cooling'' was investigated. An electrode capable of withstanding the thermal shock of the electric arc used in REP was produced through powder metallurgy techniques. The effect of various parameters involved in the rotating electrode process was studied in correlation with process control and crystal structure, microstructure and compositional analyses of the powder produced. Superconducting transition temperature measurements were made on the powder both as-produced and after annealing experiments
Metastable Magnesium fluorescence spectroscopy using a frequency-stabilized 517 nm laser
DEFF Research Database (Denmark)
He, Ming; Jensen, Brian B; Therkildsen, Kasper T
2009-01-01
We present a laser operating at 517 nm for our Magnesium laser-cooling and atomic clock project. A two-stage Yb-doped fiber amplifier (YDFA) system generates more than 1.5 W of 1034 nm light when seeded with a 15 mW diode laser. Using a periodically poled lithium niobate (PPLN) waveguide, we...... obtained more than 40 mW of 517 nm output power by single pass frequency doubling. In addition, fluorescence spectroscopy of metastable magnesium atoms could be used to stabilize the 517 nm laser to an absolute frequency within 1 MHz....
Improvement of metastable crystal of acetaminophen via control of crystal growth rate
Nii, Kosuke; Maruyama, Mihoko; Okada, Shino; Adachi, Hiroaki; Takano, Kazufumi; Murakami, Satoshi; Yoshikawa, Hiroshi Y.; Matsumura, Hiroyoshi; Inoue, Tsuyoshi; Imanishi, Masayuki; Tsukamoto, Katsuo; Yoshimura, Masashi; Mori, Yusuke
2018-03-01
We showed a relationship among the growth rate, defect generation process, and stability of the metastable phase form II crystal of acetaminophen. Appropriate control of the form II crystal growth rate via slow cooling and nanosize crystal seeding not only suppressed the defect formation but improved the crystallinity of form II. The boundary condition between the interfacial control and transport control was determined based on the relationship between the crystal growth rate and supersaturation. The nanosize crystal seeds met the conditions of interfacial control; thus, the serious defects were suppressed. Finally, better temporal stability of the form II crystal was achieved.
Self-diffusion coefficients of the metastable Lennard-Jones vapor
Energy Technology Data Exchange (ETDEWEB)
Nie Chu; Zhou Youhua [School of Physics and Information Engineering, Jianghan University, Wuhan 430056 (China); Marlow, W H; Hassan, Y A [Department of Nuclear Engineering, Texas A and M University, College Station, TX 77843 (United States)], E-mail: yhzhou@jhun.edu.cn
2008-10-15
Self-diffusion coefficients of a metastable Lennard-Jones vapor were obtained using the memory function formalism and the frequency moments of the velocity autocorrelation function at reduced temperatures from 0.75 to 1.0. The radial density distribution functions used to evaluate the second, fourth and sixth frequency moments of the velocity autocorrelation function were obtained from the restricted canonical ensemble Monte Carlo simulation (Corti and Debenedetti 1994 Chem. Eng. Sci. 49 2717). The self-diffusion coefficients at reduced temperature 0.75 do not vary monotonically as the density increases, and for the other three temperatures the self-diffusion coefficients vary normally.
Quenching of metastable antiprotonic helium atoms in collisions with deuterium molecules
Juhász, B; Hayano, R S; Hori, Masaki; Horváth, D; Ishikawa, T; Sakaguchi, J; Torii, H A; Widmann, E; Yamaguchi, H; Yamazaki, T
2002-01-01
Quenching of metastable antiprotonic helium atoms in collisions with deuterium molecules has been studied using laser spectroscopy at CERN's new Antiproton Decelerator facility. The quenching cross- sections of the states (n, l)=(39, 36), (39, 37), and (39, 38) were determined from the decay rates of the states which were observed using the "deuterium-assisted inverse resonance" (DAIR) method. The results. revealed a similar (n, l)-dependence of the quenching cross- sections as in the case of hydrogen but the values were smaller by a factor of ~1.5. (27 refs).
Structure and properties of the metastable bacteriocin Lcn972 from Lactococcus lactis
Turner, David L.; Lamosa, Pedro; Rodríguez, Ana; Martínez, Beatriz
2013-01-01
Lactococcus lactis subsp. lactis IPLA 972 produces a polypeptide bacteriocin of 7.5 kDa which has a bactericidal effect on sensitive lactococci, inhibiting septum formation in dividing cells. The active form is a monomer that is metastable under normal conditions but is stabilised by glycerol. The NMR structure of Lcn972 shows a β-sandwich comprising two three-stranded antiparallel β-sheets. Detaching the final strand could allow the sandwich to open, and the irreversible unfolding leads to a loss of antibacterial activity. Covalent linkage of the final strand should increase the stability of Lcn972 and facilitate the study of its interaction with lipid II.
Energy Technology Data Exchange (ETDEWEB)
Rossi, Alessandra; Savioli, Alessandra; Bini, Marcella; Capsoni, Doretta; Massarotti, Vincenzo; Bettini, Ruggero; Gazzaniga, Andrea; Sangalli, Maria Edvige; Giordano, Ferdinando
2003-11-28
Two metastable polymorphs of paracetamol (forms II and III) were prepared by appropriate thermal methods from binary mixtures containing 10% (w/w) of hydroxypropylmethylcellulose. By controlling the reheating step, it was possible to address the recrystallization of the drug either into form II or III. Moreover, it was observed that form III transforms either into form II or I depending on the preparation method. The physical characterization of the polymorphs was performed by means of micro-Fourier transform infrared spectroscopy (MFTIR) and powder X-ray diffractometry (PXRD), both temperature controlled.
Stable and metastable equilibrium states of the Zr-O system
International Nuclear Information System (INIS)
Versaci, R.A.; Abriata, J.P.; Garces, J.; Comision Nacional de Energia Atomica, San Carlos de Bariloche
1987-01-01
The precise knowledge of the phase diagrams is of fundamental importance for the comprehension of processes like soldering and thermal treatment. The Zr-O diagram has been widely studied, mainly in the zone corresponding to ZrO 2 . A critical analysis of the existing information about this diagram is presented. Furthermore, a lot of information about the phase equilibrium, metastable phase, crystal structure, thermodynamic properties and a possible diagram for pressures higher than one atmosphere is presented. (M.E.L.) [es
{332}〈113〉 Deformation Twinning in Metastable β-type Titanium Alloys
Directory of Open Access Journals (Sweden)
CHEN Bin
2017-01-01
Full Text Available {332} deformation twinning is a unique deformation mode which can have some special features and a strong influence on the mechanical properties for metastable β-type titanium alloys.{332} deformation twinning has already got more and more attention.The research situation and observed characteristics for the {332} deformation twinning are summarized in this paper.Some typical models for the {332} twinning are reviewed,and their assumptions and remaining problems are presented so as to provide useful information for understanding and revealing the deformation mechanism of {332} deformation twinning.
Multicharged Ion-induced simple molecule fragmentation dynamics
International Nuclear Information System (INIS)
Tarisien, M.
2003-10-01
The aim of this work is to study the dynamics of swift multicharged ion-induced fragmentation of diatomic (CO) and triatomic (CO 2 ) molecules. Performed at the GANIL facility, this study used the Recoil Ion Momentum Spectroscopy technique (RIMS), which consists of a time-of-flight mass spectrometer, coupled with a multi-hit capability position sensitive detector (delay line anode). The high-resolution measurement of the kinetic energy distribution released (KER) during the CO fragmentation points out the limitation of the Coulomb Explosion Model, revealing, for example, the di-cation CO 2 + electronic state contribution in the case of C + /O + fragmentation pathway. Furthermore, the multi-ionization cross section dependence with the orientation of the internuclear axis of CO is compared with a geometrical model calculation. Finally, different behaviours are observed for the dissociation dynamics of a triatomic molecule (CO 2 ). While triple ionization leads mainly to a synchronous concerted fragmentation dynamics, a weak fraction of dissociating molecule follows a sequential dynamics involving CO 2 + metastable states. In the case of double ionization, (CO 2 ) 2+ di-cation dissociation dynamics is asynchronously concerted and has been interpreted using a simple model involving an asymmetrical vibration of the molecule. (author)
International Nuclear Information System (INIS)
Grucker, J.
2007-12-01
In this thesis, we present a new type of atomic source: an ultra-narrow beam of metastable atoms produced by resonant metastability exchange inside a supersonic beam of rare gas atoms. We used the coherence properties of this beam to observe the diffraction of metastable helium, argon and neon atoms by a nano-transmission grating and by micro-reflection-gratings. Then, we evidenced transitions between Zeeman sublevels of neon metastable 3 P 2 state due to the quadrupolar part of Van der Waals potential. After we showed experimental proofs of the observation of this phenomenon, we calculated the transition probabilities in the Landau - Zener model. We discussed the interest of Van der Waals - Zeeman transitions for atom interferometry. Last, we described the Zeeman cooling of the supersonic metastable argon beam ( 3 P 2 ). We have succeeded in slowing down atoms to speeds below 100 m/s. We gave experimental details and showed the first time-of-flight measurements of slowed atoms
Subjective surfaces: a geometric model for boundary completion
Energy Technology Data Exchange (ETDEWEB)
Sarti, Alessandro; Malladi, Ravi; Sethian, J.A.
2000-06-01
We present a geometric model and a computational method for segmentation of images with missing boundaries. In many situations, the human visual system fills in missing gaps in edges and boundaries, building and completing information that is not present. Boundary completion presents a considerable challenge in computer vision, since most algorithms attempt to exploit existing data. A large body of work concerns completion models, which postulate how to construct missing data; these models are often trained and specific to particular images. In this paper, we take the following, alternative perspective: we consider a reference point within an image as given, and then develop an algorithm which tries to build missing information on the basis of the given point of view and the available information as boundary data to the algorithm. Starting from this point of view, a surface is constructed. It is then evolved with the mean curvature flow in the metric induced by the image until a piecewise constant solution is reached. We test the computational model on modal completion, amodal completion, texture, photo and medical images. We extend the geometric model and the algorithm to 3D in order to extract shapes from low signal/noise ratio medical volumes. Results in 3D echocardiography and 3D fetal echography are presented.
The geometric Hopf invariant and surgery theory
Crabb, Michael
2017-01-01
Written by leading experts in the field, this monograph provides homotopy theoretic foundations for surgery theory on higher-dimensional manifolds. Presenting classical ideas in a modern framework, the authors carefully highlight how their results relate to (and generalize) existing results in the literature. The central result of the book expresses algebraic surgery theory in terms of the geometric Hopf invariant, a construction in stable homotopy theory which captures the double points of immersions. Many illustrative examples and applications of the abstract results are included in the book, making it of wide interest to topologists. Serving as a valuable reference, this work is aimed at graduate students and researchers interested in understanding how the algebraic and geometric topology fit together in the surgery theory of manifolds. It is the only book providing such a wide-ranging historical approach to the Hopf invariant, double points and surgery theory, with many results old and new. .
Geometrical dynamics of Born-Infeld objects
International Nuclear Information System (INIS)
Cordero, Ruben; Molgado, Alberto; Rojas, Efrain
2007-01-01
We present a geometrically inspired study of the dynamics of Dp-branes. We focus on the usual non-polynomial Dirac-Born-Infeld action for the worldvolume swept out by the brane in its evolution in general background spacetimes. We emphasize the form of the resulting equations of motion which are quite simple and resemble Newton's second law, complemented with a conservation law for a worldvolume bicurrent. We take a closer look at the classical Hamiltonian analysis which is supported by the ADM framework of general relativity. The constraints and their algebra are identified as well as the geometrical role they play in phase space. In order to illustrate our results, we review the dynamics of a D1-brane immersed in a AdS 3 x S 3 background spacetime. We exhibit the mechanical properties of Born-Infeld objects paving the way to a consistent quantum formulation
Geometric description of images as topographic maps
Caselles, Vicent
2010-01-01
This volume discusses the basic geometric contents of an image and presents a tree data structure to handle those contents efficiently. The nodes of the tree are derived from connected components of level sets of the intensity, while the edges represent inclusion information. Grain filters, morphological operators simplifying these geometric contents, are analyzed and several applications to image comparison and registration, and to edge and corner detection, are presented. The mathematically inclined reader may be most interested in Chapters 2 to 6, which generalize the topological Morse description to continuous or semicontinuous functions, while mathematical morphologists may more closely consider grain filters in Chapter 3. Computer scientists will find algorithmic considerations in Chapters 6 and 7, the full justification of which may be found in Chapters 2 and 4 respectively. Lastly, all readers can learn more about the motivation for this work in the image processing applications presented in Chapter 8...
Geometric modeling for computer aided design
Schwing, James L.
1993-01-01
Over the past several years, it has been the primary goal of this grant to design and implement software to be used in the conceptual design of aerospace vehicles. The work carried out under this grant was performed jointly with members of the Vehicle Analysis Branch (VAB) of NASA LaRC, Computer Sciences Corp., and Vigyan Corp. This has resulted in the development of several packages and design studies. Primary among these are the interactive geometric modeling tool, the Solid Modeling Aerospace Research Tool (smart), and the integration and execution tools provided by the Environment for Application Software Integration and Execution (EASIE). In addition, it is the purpose of the personnel of this grant to provide consultation in the areas of structural design, algorithm development, and software development and implementation, particularly in the areas of computer aided design, geometric surface representation, and parallel algorithms.
Universal geometrical scaling of the elliptic flow
Directory of Open Access Journals (Sweden)
Andrés C.
2015-01-01
Full Text Available The presence of scaling variables in experimental observables provide very valuable indications of the dynamics underlying a given physical process. In the last years, the search for geometric scaling, that is the presence of a scaling variable which encodes all geometrical information of the collision as well as other external quantities as the total energy, has been very active. This is motivated, in part, for being one of the genuine predictions of the Color Glass Condensate formalism for saturation of partonic densities. Here we extend these previous findings to the case of experimental data on elliptic flow. We find an excellent scaling for all centralities and energies, from RHIC to LHC, with a simple generalization of the scaling previously found for other observables and systems. Interestingly, the case of the photons, difficult to reconcile in most formalisms, nicely fit the scaling curve. We discuss on the possible interpretations of this finding in terms of initial or final state effects.
Geometric modeling in probability and statistics
Calin, Ovidiu
2014-01-01
This book covers topics of Informational Geometry, a field which deals with the differential geometric study of the manifold probability density functions. This is a field that is increasingly attracting the interest of researchers from many different areas of science, including mathematics, statistics, geometry, computer science, signal processing, physics and neuroscience. It is the authors’ hope that the present book will be a valuable reference for researchers and graduate students in one of the aforementioned fields. This textbook is a unified presentation of differential geometry and probability theory, and constitutes a text for a course directed at graduate or advanced undergraduate students interested in applications of differential geometry in probability and statistics. The book contains over 100 proposed exercises meant to help students deepen their understanding, and it is accompanied by software that is able to provide numerical computations of several information geometric objects. The reader...
Geometrical approach to gaussian beam propagation.
Laures, P
1967-04-01
The curvature of the wavefront and the spot size of a propagating Gaussian beam may be determined from simple geometrical transformations of the lateral foci. The analysis starts from the construction of the lateral foci in the case of a spherical Fabry-Perot. Then the cases of Gaussian beam propagation through media with different refractive indices, lenses, and simple optical systems are treated. Constructions show how propagation in the image space is readily determined in each case. This analysis is the generalization of the technique outlined by Deschamps and Mast. The geometrical constructions developed for simple cases are applied to the design of some special cases of interest in laser optics: cavities by a lens, laser zoom telescope, and ring cavity.
A practical guide to experimental geometrical optics
Garbovskiy, Yuriy A
2017-01-01
A concise, yet deep introduction to experimental, geometrical optics, this book begins with fundamental concepts and then develops the practical skills and research techniques routinely used in modern laboratories. Suitable for students, researchers and optical engineers, this accessible text teaches readers how to build their own optical laboratory and to design and perform optical experiments. It uses a hands-on approach which fills a gap between theory-based textbooks and laboratory manuals, allowing the reader to develop their practical skills in this interdisciplinary field, and also explores the ways in which this knowledge can be applied to the design and production of commercial optical devices. Including supplementary online resources to help readers track and evaluate their experimental results, this text is the ideal companion for anyone with a practical interest in experimental geometrical optics.
Manfredini, Maria; Morbidelli, Daniele; Polidoro, Sergio; Uguzzoni, Francesco
2015-01-01
The analysis of PDEs is a prominent discipline in mathematics research, both in terms of its theoretical aspects and its relevance in applications. In recent years, the geometric properties of linear and nonlinear second order PDEs of elliptic and parabolic type have been extensively studied by many outstanding researchers. This book collects contributions from a selected group of leading experts who took part in the INdAM meeting "Geometric methods in PDEs", on the occasion of the 70th birthday of Ermanno Lanconelli. They describe a number of new achievements and/or the state of the art in their discipline of research, providing readers an overview of recent progress and future research trends in PDEs. In particular, the volume collects significant results for sub-elliptic equations, potential theory and diffusion equations, with an emphasis on comparing different methodologies and on their implications for theory and applications. .
Geometrical dynamics of Born-Infeld objects
Energy Technology Data Exchange (ETDEWEB)
Cordero, Ruben [Departamento de Fisica, Escuela Superior de Fisica y Matematicas del I.P.N., Unidad Adolfo Lopez Mateos, Edificio 9, 07738 Mexico, D.F. (Mexico); Molgado, Alberto [Facultad de Ciencias, Universidad de Colima, Bernal DIaz del Castillo 340, Col. Villas San Sebastian, Colima (Mexico); Rojas, Efrain [Facultad de Fisica e Inteligencia Artificial, Universidad Veracruzana, 91000 Xalapa, Veracruz (Mexico)
2007-03-21
We present a geometrically inspired study of the dynamics of Dp-branes. We focus on the usual non-polynomial Dirac-Born-Infeld action for the worldvolume swept out by the brane in its evolution in general background spacetimes. We emphasize the form of the resulting equations of motion which are quite simple and resemble Newton's second law, complemented with a conservation law for a worldvolume bicurrent. We take a closer look at the classical Hamiltonian analysis which is supported by the ADM framework of general relativity. The constraints and their algebra are identified as well as the geometrical role they play in phase space. In order to illustrate our results, we review the dynamics of a D1-brane immersed in a AdS{sub 3} x S{sup 3} background spacetime. We exhibit the mechanical properties of Born-Infeld objects paving the way to a consistent quantum formulation.
Coated sphere scattering by geometric optics approximation.
Mengran, Zhai; Qieni, Lü; Hongxia, Zhang; Yinxin, Zhang
2014-10-01
A new geometric optics model has been developed for the calculation of light scattering by a coated sphere, and the analytic expression for scattering is presented according to whether rays hit the core or not. The ray of various geometric optics approximation (GOA) terms is parameterized by the number of reflections in the coating/core interface, the coating/medium interface, and the number of chords in the core, with the degeneracy path and repeated path terms considered for the rays striking the core, which simplifies the calculation. For the ray missing the core, the various GOA terms are dealt with by a homogeneous sphere. The scattering intensity of coated particles are calculated and then compared with those of Debye series and Aden-Kerker theory. The consistency of the results proves the validity of the method proposed in this work.
Investigations on geometrical features in induced ordering of ...
Indian Academy of Sciences (India)
Binding energies of the interaction of collagen like triple helical peptides with a series of polyphenols, viz. gallic acid, catechin, epigallocatechingallate and pentagalloylglucose have been computed using molecular modelling approaches. A correlation of calculated binding energies with the interfacial molecular volumes ...
Investigations on geometrical features in induced ordering of ...
Indian Academy of Sciences (India)
Unknown
Overwhelming influence of water structure and hydration on the molecular aggregation and properties of ... 1α2 chains) of the native type I collagen except residue 204 of the α1 chain, where Ala of native collagen is ..... the understanding of the interaction of collagen-like peptide and polyphenolic substances through the ...
Compression induced intercellular shaping for some geometric cellular lattices
Directory of Open Access Journals (Sweden)
Adonai Gimenez Calbo
2001-03-01
Full Text Available The wall perimeter fraction, which contact neighboring cells, was named compression ratio (alpha. A zero compression ratio indicates maximum intercellular (air volume (vG, v/v and neglectable contact among cells, while alpha=1 indicates complete adherence between neighboring cells and no vG in the lattice. The maximum intercellular air volume (beta, v/v, when alpha=0, was 0.593 for triangular, 0.2146 for square and 0,0931 for hexagonal lattices. The equation alpha=1- (vG/beta½ was derived to relate alpha, beta and vG in the studied lattices. The relation (P S=p/alpha between cell turgor (P S and the tissue aggregating pressure (p, defined as the compression to keep in place a layer of cells, was demonstrated using the compression ratio concept. Intercellular deformations of Ipomea batatas L. roots obtained with pressure chamber were used to test alpha, vG, p and P S as a function of compression. Volumetric and transversal elastic extensibilities and the lamella media tearing forces were obtained and alpha constancy was considered as a criteria of cellular shape stability.A fração do perímetro da parede celular em contato com células vizinha foi denominada razão de compressão (alfa. Razão de compressão zero indica volume intercelular (vG, v/v máximo e contato neglível entre as células, enquanto alfa=1 ocorre quando há completa aderência com as células vizinhas (vG=0. O volume (gasoso intercelular máximo (beta, v/v, quando alfa=0, foi 0,593, 0,2146 e 0,0931 para látices triangulares, quadradas e hexagonais. A equação derivada para relacionar alfa, beta and vG nas látices estudadas foi alfa=1- (vG/beta½. A razão de compressão foi em seguida empregada para estabelecer a relação P S=p/alfa entre a pressão de turgescência (P S e a pressão de agregação (p, definida com a compressão para manter uma camada de células no seu lugar. As deformações intercelulares de batata-doce obtidas com procedimentos de câmara-de-pressão foram empregados para obter informações sobre as variações de alfa, vG, p e P S em função da compressão empregando módulos de elasticidade transversal e volumétrico. A constância de alfa foi sugerida como critério de estabilidade de látices celulares.
Lieb-Thirring inequalities for geometrically induced bound states
Czech Academy of Sciences Publication Activity Database
Exner, Pavel; Linde, H.; Weidi, T.
2004-01-01
Roč. 70, č. 1 (2004), s. 83-95 ISSN 0377-9017 R&D Projects: GA AV ČR KSK1010104 Keywords : quantum wave -guides * Schrödinger-operators * dirichlet Subject RIV: BE - Theoretical Physics Impact factor: 0.926, year: 2004
GEOMETRICAL CHARACTERIZATION OF MICRO END MILLING TOOLS
DEFF Research Database (Denmark)
Borsetto, Francesca; Bariani, Paolo
/lubricants, milling strategies and controls. Moreover the accuracy of tool geometry directly affects the performance of the milling process influencing the dimensional tolerances of the machined part, the surface topography, the chip formation, the cutting forces and the tool-life. The dimensions of certain...... report is to develop procedures for the geometrical characterization of micro end milling tools in order to define a method suitable for the quality assurance in the micro cutting field....
Constellation design with geometric and probabilistic shaping
Zhang, Shaoliang; Yaman, Fatih
2018-02-01
A systematic study, including theory, simulation and experiments, is carried out to review the generalized pairwise optimization algorithm for designing optimized constellation. In order to verify its effectiveness, the algorithm is applied in three testing cases: 2-dimensional 8 quadrature amplitude modulation (QAM), 4-dimensional set-partitioning QAM, and probabilistic-shaped (PS) 32QAM. The results suggest that geometric shaping can work together with PS to further bridge the gap toward the Shannon limit.
A CT simulator phantom for geometrical test
International Nuclear Information System (INIS)
Min, Chul Kee; Yi, Byong Yong; Ahn, Seung Do; Choi, Eun Kyung; Chang, Hye Sook
2000-01-01
To design and test the CT simulator phantom for geometrical test. The PMMA phantom was designed as a cylinder which is 20 cm in diameter and 24 cm in length, along with a 25x25x31 cm 3 rectangular parallelepiped. Radio-opaque wires of which diameter is 0.8 mm are attached on the other surface of the phantom as a spiral. The rectangular phantom was made of four 24x24xO.5 cm 3 square plates and each plate had a 24x24 cm 2 . 12x12 cm 2 , 6x6 cm 2 square line. The squares were placed to face the cylinder at angles 0 .deg., 15 .deg., 30 .deg., respectively. The rectangular phantom made it possible to measure the field size, couch angle, the collimator angle, the isocenter shift and the SSD, the measurements of the gantry angle from the cylindrical part. A virtual simulation Software, AcQSim TM , offered various conditions to perform virtual simulations and these results were used to perform the geometrical quality assurance of CT simulator. A 0.3-0.5 mm difference was found on the 24 cm field size which was created with the DRR measurements obtained by scanning of the rectangular phantom. The isocenter shift, the collimator rotation, the couch rotation, and the gantry rotation test showed 0.5-1 mm, 0.5-1 .deg. 0.5-1 .deg. , and 0.5-1 .deg. differences, respectively. We could not find any significant differences between the results from the two scanning methods. The geometrical test phantom developed in the study showed less than 1 mm (or 1 .deg. ) differences. The phantom could be used as a routine geometrical QC/OA tools, since the differences are within clinically acceptable ranges
Geometric Algebra Model of Distributed Representations
Patyk, Agnieszka
2010-01-01
Formalism based on GA is an alternative to distributed representation models developed so far --- Smolensky's tensor product, Holographic Reduced Representations (HRR) and Binary Spatter Code (BSC). Convolutions are replaced by geometric products, interpretable in terms of geometry which seems to be the most natural language for visualization of higher concepts. This paper recalls the main ideas behind the GA model and investigates recognition test results using both inner product and a clipp...
Geometrical Methods for Power Network Analysis
Bellucci, Stefano; Gupta, Neeraj
2013-01-01
This book is a short introduction to power system planning and operation using advanced geometrical methods. The approach is based on well-known insights and techniques developed in theoretical physics in the context of Riemannian manifolds. The proof of principle and robustness of this approach is examined in the context of the IEEE 5 bus system. This work addresses applied mathematicians, theoretical physicists and power engineers interested in novel mathematical approaches to power network theory.
Multiphase flow in geometrically simple fracture intersections
Basagaoglu, H.; Meakin, P.; Green, C.T.; Mathew, M.; ,
2006-01-01
A two-dimensional lattice Boltzmann (LB) model with fluid-fluid and solid-fluid interaction potentials was used to study gravity-driven flow in geometrically simple fracture intersections. Simulated scenarios included fluid dripping from a fracture aperture, two-phase flow through intersecting fractures and thin-film flow on smooth and undulating solid surfaces. Qualitative comparisons with recently published experimental findings indicate that for these scenarios the LB model captured the underlying physics reasonably well.
An Information Geometric Framework for Dimensionality Reduction
Carter, Kevin M.; Raich, Raviv; Hero III, Alfred O.
2008-01-01
This report concerns the problem of dimensionality reduction through information geometric methods on statistical manifolds. While there has been considerable work recently presented regarding dimensionality reduction for the purposes of learning tasks such as classification, clustering, and visualization, these methods have focused primarily on Riemannian manifolds in Euclidean space. While sufficient for many applications, there are many high-dimensional signals which have no straightforwar...
Salt Bridges: Geometrically Specific, Designable Interactions
Donald, Jason E.; Kulp, Daniel W.; DeGrado, William F.
2011-01-01
Salt bridges occur frequently in proteins, providing conformational specificity and contributing to molecular recognition and catalysis. We present a comprehensive analysis of these interactions in protein structures by surveying a large database of protein structures. Salt bridges between Asp or Glu and His, Arg, or Lys display extremely well-defined geometric preferences. Several previously observed preferences are confirmed and others that were previously unrecognized are discovered. Salt ...
Protection from Unresponsive Flows with Geometric CHOKe
Eshete, Addisu Tadesse; Jiang, Yuming
2012-01-01
This paper proposes a simple and stateless active queue management (AQM) scheme, called geometric CHOKe (gCHOKe), to protect responsive flows from unresponsive ones. The proposed gCHOKe has its root on and is a generalization of the original CHOKe. It provides an extended power of flow protection, achieved by introducing an extra flow matching trial upon each successful matching of packets. Compared to the plain CHOKe, analysis and simulation show that gCHOKe can achieve over 20% improvement ...