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Sample records for geochemically variable soil

  1. Geochemical variability of soils and biogeochemical variability of plants in the Piceance Basin, Colorado

    Science.gov (United States)

    Tuttle, M.L.; Severson, R.C.; Dean, W.E.; Klusman, R.W.

    1986-01-01

    Geochemical baselines for native soils and biogeochemical baselines for plants in the Piceance basin provide data that can be used to assess geochemical and biogeochemical effects of oil-shale development, monitor changes in the geochemical and biogeochemical environment during development, and assess the degree of success of rehabilitation of native materials after development. Baseline values for 52 properties in native soils, 15 properties in big sagebrush, and 13 properties in western wheatgrass were established. Our Study revealed statistically significant regional variations of the following properties across the basin: in soil&-aluminum, cobalt, copper, iron, manganese, sodium, nickel, phosphorus, lead, scandium, titanium, vanadium, zinc, organic and total carbon, pH, clay, dolomite, sodium feldspar, and DTPA-extractable calcium, cadmium, iron, potassium, manganese, nickel, phosphorus, yttrium, and zinc; in big sagebrush-barium, calcium, copper, magnesium, molybdenum, sodium, strontium, zinc, and ash; and in western wheatgrass-boron, barium, calcium, magnesium, manganese, molybdenum, strontium, zinc, and ash. These variations show up as north-south trends across the basin, or they reflect differences in elevation, hydrology, and soil parent material. Baseline values for properties that do not have statistically significant regional variations can be represented by geometric means and deviations calculated from all values within the basin. Chemical and mineralogical analyses of soil and chemical analyses of western wheatgrass samples from Colorado State University's experimental revegetation plot at Anvil Points provide data useful in assessing potential effects on soil and plant properties when largescale revegetation operations begin. The concentrations of certain properties are related to the presence of topsoil over spent shale in the lysimeters. In soils, calcium, fluorine, lithium, magnesium, sodium, phosphorus, strontium, carbonate and total carbon

  2. Geochemical variability of natural soils and reclaimed minespoil soils in the San Juan Basin, New Mexico

    Science.gov (United States)

    Gough, L.P.; Severson, R.C.

    1981-01-01

    An inventory of total-and extractable-element concentrations in soils was made for three areas of the San Juan Basin in New Mexico: (1) the broad area likely to be affected by energy-related development. (2) an area of soils considered to have potential for use as topsoil in mined-land reclamation. and (3) an area of the San Juan coal mine that has been regraded. topsoiled, and revegetated. Maps made of concentrations of 16 elements in area 1 soils show no gradational pattern across the region. Further. these maps do not correspond to those showing geology or soil types. Sodic or saline problems, and a possible but unproven deficiency of zinc available to plants. may make some of the soils in this area undesirable for use as topsoil in mined-land reclamation. Taxonomic great groups of soil in this area cannot be distinguished because each great group tends to have a large within-group variability if compared to the between-group variability. In area 2 the major soils sampled were of the Sheppard. Shiprock. and Doak association. These soils are quite uniform in chemical composition and are not greatly saline or sodic. As in area 1 soils. zinc deficiency may cause a problem in revegetating most of these soils. It is difficult to distinguish soil taxonomic families by using their respective chemical compositions. because of small between-family variability. Topsoil from a reclaimed area of the San Juan mine (area 3) most closely resembles the chemical composition of natural C horizons of soil from area 1. Spoil material that has not been topsoiled is likely to cause sodic-and saline-related problems in revegetation and may cause boron toxicity in plants. Topsoiling has apparently ameliorated these potential problems for plant growth on mine spoil. Total and extractable concentrations for elements and other parameters for each area of the San Juan Basin provide background information for the evaluation of the chemical quality of soils in each area.

  3. Relative spatial soil geochemical variability along two transects across the United States and Canada

    Science.gov (United States)

    Garrett, Robert G.

    2009-01-01

    To support the development of protocols for the proposed North American Soil Geochemical Landscapes project, whose objective is to establish baselines for the geochemistry of North American soils, two continental-scale transects across the United States and Canada were sampled in 2004. The sampling employed a spatially stratified random sampling design in order to estimate the variability between 40-km linear sampling units, within them, at sample sites, and due to sample preparation and analytical chemical procedures. The 40-km scale was chosen to be consistent with the density proposed for the continental-scale project. The two transects, north–south (N–S) from northern Manitoba to the USA–Mexico border near El Paso, Texas, and east–west (E–W) from the Virginia shore north of Washington, DC, to north of San Francisco, California, closely following the 38th parallel, have been studied individually. The purpose of this study was to determine if statistically significant systematic spatial variation occurred along the transects. Data for 38 major, minor and trace elements in A- and C-horizon soils where less than 5% of the data were below the detection limit were investigated by Analysis of Variance (ANOVA). A total of 15 elements (K, Na, As, Ba, Be, Ce, La, Mn, Nb, P, Rb, Sb, Th, Tl and W) demonstrated statistically significant (p<0.05) variability at the between-40-km scale for both horizons along both transects. Only Cu failed to demonstrate significant variability at the between-40-km scale for both soil horizons along both transects.

  4. Geochemical baseline studies of soil in Finland

    Science.gov (United States)

    Pihlaja, Jouni

    2017-04-01

    The soil element concentrations regionally vary a lot in Finland. Mostly this is caused by the different bedrock types, which are reflected in the soil qualities. Geological Survey of Finland (GTK) is carrying out geochemical baseline studies in Finland. In the previous phase, the research is focusing on urban areas and mine environments. The information can, for example, be used to determine the need for soil remediation, to assess environmental impacts or to measure the natural state of soil in industrial areas or mine districts. The field work is done by taking soil samples, typically at depth between 0-10 cm. Sampling sites are chosen to represent the most vulnerable areas when thinking of human impacts by possible toxic soil element contents: playgrounds, day-care centers, schools, parks and residential areas. In the mine districts the samples are taken from the areas locating outside the airborne dust effected areas. Element contents of the soil samples are then analyzed with ICP-AES and ICP-MS, Hg with CV-AAS. The results of the geochemical baseline studies are published in the Finnish national geochemical baseline database (TAPIR). The geochemical baseline map service is free for all users via internet browser. Through this map service it is possible to calculate regional soil baseline values using geochemical data stored in the map service database. Baseline data for 17 elements in total is provided in the map service and it can be viewed on the GTK's web pages (http://gtkdata.gtk.fi/Tapir/indexEN.html).

  5. Geochemical variability of heavy metals in soil after land use conversions in Northeast China and its environmental applications.

    Science.gov (United States)

    Jiao, Wei; Ouyang, Wei; Hao, Fanghua; Liu, Bing; Wang, Fangli

    2014-04-01

    The long-term agricultural reclamation since the 1950s has resulted in significant land use change from natural landscape to cultivated land in the Sanjiang Plain of Northeast China, which has had important consequences for many soil physical, chemical and biological processes. To understand the impact of land use conversions on heavy metal geochemistry, soil samples were collected from natural wetland, natural forestland, paddy land and dry farmland in a case study area and analyzed for total concentrations and chemical fractions of six heavy metals. Results showed that the natural wetland reclamation for the paddy land has caused obvious losses of Cd, Cu and Zn from the soils. In addition, a significant decrease in the Zn concentration was found after the land conversion from natural forestland to dry farmland. Because all the analyzed heavy metals predominated in the stable residual fraction regardless of the land use type, the response of metal mobility to the land use conversions was generally weak. Consequently, soil erosion was identified as the major factor that enhances heavy metal losses in the cultivated lands, especially in the paddy land. The close link between heavy metal loss and the reduction of clay and organic matter contents after land reclamation suggested that the diffuse heavy metal pollution occurred mainly in small erosion events. Considering the continuous paddy land expansion, special attention should be paid to the bioaccumulation of Pb in the paddy rice. Overall, these findings can help to improve the sustainability and safety of intensive agricultural activities in Northeast China as well as other similar areas.

  6. Geochemical patterns in soils of the karst region, Croatia

    Science.gov (United States)

    Prohic, E.; Hausberger, G.; Davis, J.C.

    1997-01-01

    Soil samples were collected at 420 locations in a 5-km grid pattern in the Istria and Gorski Kotar areas of Croatia, and on the Croatian islands of Cres, Rab and Krk, in order to relate geochemical variation in the soils to underlying differences in geology, bedrock lithology, soil type, environment and natural versus anthropogenic influences. Specific objectives included assessment of possible agricultural and industrial sources of contamination, especially from airborne effluent emitted by a local power plant. The study also tested the adequacy of a fixed-depth soil sampling procedure developed for meager karstic soils. Although 40 geochemical variables were analyzed, only 15 elements and 5 radionuclides are common to all the sample locations. These elements can be divided into three groups: (1) those of mostly anthropogenic origin -Pb, V, Cu and Cr; (2) those of mixed origin - radionuclides and Zn; and (3) those of mostly geogene origin -Ba, Sr, Ti, Al, Na, Ca, Mg, Fe, Mn, Ni and Co. Variation in Pb shows a strong correlation with the pattern of road traffic in Istria. The distributions of Ca, Na and Mg in the flysch basins of southern Istria and Slovenia are clearly distinguishable from the distributions of these elements in the surrounding carbonate terrains, a consequence of differences in bedrock permeability, type of drainage and pH. The spatial pattern of Cs from the Chernobyl nuclear power plant accident reflects almost exclusively the precipitation in Istria during the days immediately after the explosion. ?? 1997 Elsevier Science B.V.

  7. Relating soil geochemical properties to arsenic bioaccessibility

    Data.gov (United States)

    U.S. Environmental Protection Agency — soil element total concentration, soil pH and arsenic bioaccessibility values. This dataset is not publicly accessible because: EPA cannot release personally...

  8. Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

    2011-01-01

    The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons

  9. Geochemical Cycling of Iodine Species in Soils

    International Nuclear Information System (INIS)

    Hu, Q.; Moran, J.E.; Blackwood, V.

    2007-01-01

    Iodine is an important element in studies of environmental protection and human health, global-scale hydrologic processes and nuclear nonproliferation. Biogeochemical cycling of iodine in soils is complex, because iodine occurs in multiple oxidation states and as inorganic and organic species that may be hydrophilic, atmophilic, and biophilic. In this study, we applied new analytical techniques to study the content and speciation of stable iodine in representative surface soils, and sorption and transport behavior of iodine species (iodide, iodate, and 4-iodoaniline) in sediments collected at numerous nuclear facilities in the United States, where anthropogenic 129 I from prior nuclear fuel processing activities poses an environmental risk. The surface soil samples were chosen for their geographic locations (e.g., near the ocean or nuclear facilities) and for their differing physico-chemical characteristics (organic matter, texture, etc). Extracted solutions were analyzed by IC and ICP-MS methods to determine iodine concentrations and to examine iodine speciation (iodide, iodate, and organic iodine). In natural soils, iodine is mostly (nearly 90% of total iodine) present as organic species, while inorganic iodine becomes important (up to 50%) only in sediments with low organic matter. Results from laboratory column studies, aimed at examining transport of different iodine species, showed much greater retardation of 4-iodoaniline than iodide or iodate. Careful attention must be given to potential interconversion among species when interpreting the biogeochemical behavior of iodine in the environment. In addition to speciation, input concentration and residence time effects will influence the biogeochemical cycling of anthropogenic 129I deposited on surface soils

  10. Soil variability in mountain areas

    OpenAIRE

    Zanini, E.; Freppaz, M.; Stanchi, S.; Bonifacio, E.; Egli, M.

    2015-01-01

    The high spatial variability of soils is a relevant issue at local and global scales, and determines the complexity of soil ecosystem functions and services. This variability derives from strong dependencies of soil ecosystems on parent materials, climate, relief and biosphere, including human impact. Although present in all environments, the interactions of soils with these forming factors are particularly striking in mountain areas.

  11. A Geochemical Reaction Model for Titration of Contaminated Soil and Groundwater at the Oak Ridge Reservation

    Science.gov (United States)

    Zhang, F.; Parker, J. C.; Gu, B.; Luo, W.; Brooks, S. C.; Spalding, B. P.; Jardine, P. M.; Watson, D. B.

    2007-12-01

    This study investigates geochemical reactions during titration of contaminated soil and groundwater at the Oak Ridge Reservation in eastern Tennessee. The soils and groundwater exhibits low pH and high concentrations of aluminum, calcium, magnesium, manganese, various trace metals such as nickel and cobalt, and radionuclides such as uranium and technetium. The mobility of many of the contaminant species diminishes with increasing pH. However, base additions to increase pH are strongly buffered by various precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior and associated geochemical effects is thus critical to evaluate remediation performance of pH manipulation strategies. This study was undertaken to develop a practical but generally applicable geochemical model to predict aqueous and solid-phase speciation during soil and groundwater titration. To model titration in the presence of aquifer solids, an approach proposed by Spalding and Spalding (2001) was utilized, which treats aquifer solids as a polyprotic acid. Previous studies have shown that Fe and Al-oxyhydroxides strongly sorb dissolved Ni, U and Tc species. In this study, since the total Fe concentration is much smaller than that of Al, only ion exchange reactions associated with Al hydroxides are considered. An equilibrium reaction model that includes aqueous complexation, precipitation, ion exchange, and soil buffering reactions was developed and implemented in the code HydroGeoChem 5.0 (HGC5). Comparison of model results with experimental titration curves for contaminated groundwater alone and for soil- water systems indicated close agreement. This study is expected to facilitate field-scale modeling of geochemical processes under conditions with highly variable pH to develop practical methods to control contaminant mobility at geochemically complex sites.

  12. Soil geochemical parameters influencing the spatial distribution of anthrax in Northwest Minnesota, USA

    International Nuclear Information System (INIS)

    Nath, Samuel; Dere, Ashlee

    2016-01-01

    Bacillus anthracis is the pathogenic bacterium that causes anthrax, which dwells in soils as highly resilient endospores. B. anthracis spore viability in soil is dependent upon environmental conditions, but the soil properties necessary for spore survival are unclear. In this study we used a range of soil geochemical and physical parameters to predict the spatial distribution of B. anthracis in northwest Minnesota, where 64 cases of anthrax in livestock were reported from 2000 to 2013. Two modeling approaches at different spatial scales were used to identify the soil conditions most correlated to known anthrax cases using both statewide and locally collected soil data. Ecological niche models were constructed using the Maximum Entropy (Maxent) approach and included 11 soil parameters as environmental inputs and recorded anthrax cases as known presences. One ecological niche model used soil data and anthrax presences for the entire state while a second model used locally sampled soil data (n = 125) and a subset of anthrax presences, providing a test of spatial scale. In addition, simple logistic regression models using the localized soil data served as an independent measure of variable importance. Maxent model results indicate that at a statewide level, soil calcium and magnesium concentrations, soil pH, and sand content are the most important properties for predicting soil suitability for B. anthracis while at the local level, clay and sand content along with phosphorous and strontium concentrations are most important. These results also show that the spatial scale of analysis is important when considering soil parameters most important for B. anthracis spores. For example, at a broad scale, B. anthracis spores may require Ca-rich soils and an alkaline pH, but may also concentrate in microenvironments with high Sr concentrations. The study is also one of the first ecological niche models that demonstrates the major importance of soil texture for defining

  13. Geochemical behavior of radionuclides and heavy metals in soils from Corumbatai River basin (SP), Brazil

    International Nuclear Information System (INIS)

    Conceicao, Fabiano Tomazini da

    2004-01-01

    The purpose of this research was to study the geochemical behavior of radionuclides and heavy metals in soils of agricultural use at Corumbatai River basin (SP). The natural concentration and variability in sedimentary rocks at Corumbatai river basin follow the trend Ca > Mg > K > Na, with the concentration of heavy metals and radionuclides. The distribution of exposure rate in soils shows the occurrence of higher values towards south of the Corumbatai river basin, region where are applied phosphate fertilizers, amendments and 'vinhaca' in sugar cane crops. Heavy metals and radionuclides incorporated in phosphate fertilizers and amendments are annually added during the fertilization process in the sugar cane crops, but if they are utilized in accordance with the recommended rate, they do not rise the concentration levels in soils up to hazards levels. Thus, they are lower transferred from soils to sugar cane at Corumbatai river basin, not offering hazard to the ecosystem and animal or human health. (author)

  14. Top Soils Geochemical and Radioactivity Survey of Naples (Italy) Metropolitan.

    Science.gov (United States)

    Somma, R.; De Vivo, B.; Cicchella, D.

    2001-05-01

    The metropolitan area of Naples due to intense human activities is an emblematic area affected by various environmental pollution of soils and waters in addition to hydrogeological volcanic, seismic and bradyseismic hazards. The geology of the area is prevailing represented by volcanics erupted, from the Upper Pleistocene to Recent by Mt. Somma-Vesuvius on the east and the Campi Flegrei fields on the west. The morphology of the metropolitan area of Naples city can be subdivided in flat areas, constituted by reworked pyroclastic terrains, and by hills originated by the overlapping of different welded pyroclastic flows (i.e.: Campanian Ignimbrite and Neapoletan Yellow Tuff) intercalated with pyroclastic deposits of different origins (i.e.: Campi Flegrei, Mt. Somma-Vesuvius, Ischia) and ages. In order to compile a multi-element baseline geochemical and radioactivity mapping of the metropolitan area of the Napoli we have sampled for this study, in situ top soil and imported filling material (mainly soil, volcanic ash, pumice and scoriae). The sampling and radioactivity survey has been carried out on about 200 sampling sites covering an area of about 150 Km2, with a grid of 0.5 x 0.5 km in the urbanised downtown and 1 km x 1 km in the sub urban areas. In each site has been determined a radioactivity by a Scintrex GRS-500 at different emission spectra as total radioactivity (> 0.08 MeV and > 0.40 MeV), 238U (at 1.76 MeV mostly from 214Bi), 232Th (at 2.6 MeV mostly from 208Tl) and 40K (at 1.46 MeV mostly for 40K). The range of values of in situ soils are as follow for the in situ soils (Total radioactivity: 1327- 360 and 114- 47; 238U: 2.6- 1.3; 40K: 8.1- 3.1; 232U: 0.5- 0.1). Analyses of major, metallic elements and pH of each soil sample are in progress, while Pb isotopes compositions, for a selected number of samples, will be determined to discriminate the natural (geogenic) from the anthropogenic components in the soils by versus the anthropogenetic origin. The data

  15. A regional soil and sediment geochemical study in northern California

    International Nuclear Information System (INIS)

    Goldhaber, Martin B.; Morrison, Jean M.; Holloway, JoAnn M.; Wanty, Richard B.; Helsel, Dennis R.; Smith, David B.

    2009-01-01

    Regional-scale variations in soil geochemistry were investigated in a 20,000-km 2 study area in northern California that includes the western slope of the Sierra Nevada, the southern Sacramento Valley and the northern Coast Ranges. Over 1300 archival soil samples collected from the late 1970s to 1980 in El Dorado, Placer, Sutter, Sacramento, Yolo and Solano counties were analyzed for 42 elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry following a near-total dissolution. These data were supplemented by analysis of more than 500 stream-sediment samples from higher elevations in the Sierra Nevada from the same study site. The relatively high-density data (1 sample per 15 km 2 for much of the study area) allows the delineation of regional geochemical patterns and the identification of processes that produced these patterns. The geochemical results segregate broadly into distinct element groupings whose distribution reflects the interplay of geologic, hydrologic, geomorphic and anthropogenic factors. One such group includes elements associated with mafic and ultramafic rocks including Cr, Ni, V, Co, Cu and Mg. Using Cr as an example, elevated concentrations occur in soils overlying ultramafic rocks in the foothills of the Sierra Nevada (median Cr = 160 mg/kg) as well as in the northern Coast Ranges. Low concentrations of these elements occur in soils located further upslope in the Sierra Nevada overlying Tertiary volcanic, metasedimentary and plutonic rocks (granodiorite and diorite). Eastern Sacramento Valley soil samples, defined as those located east of the Sacramento River, are lower in Cr (median Cr = 84 mg/kg), and are systematically lower in this suite compared to soils from the west side of the Sacramento Valley (median Cr = 130 mg/kg). A second group of elements showing a coherent pattern, including Ca, K, Sr and REE, is derived from relatively silicic rocks types. This group occurs at elevated

  16. A regional soil and sediment geochemical study in northern California

    Science.gov (United States)

    Goldhaber, M.B.; Morrison, J.M.; Holloway, J.M.; Wanty, R.B.; Helsel, D.R.; Smith, D.B.

    2009-01-01

    Regional-scale variations in soil geochemistry were investigated in a 20,000-km2 study area in northern California that includes the western slope of the Sierra Nevada, the southern Sacramento Valley and the northern Coast Ranges. Over 1300 archival soil samples collected from the late 1970s to 1980 in El Dorado, Placer, Sutter, Sacramento, Yolo and Solano counties were analyzed for 42 elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry following a near-total dissolution. These data were supplemented by analysis of more than 500 stream-sediment samples from higher elevations in the Sierra Nevada from the same study site. The relatively high-density data (1 sample per 15 km2 for much of the study area) allows the delineation of regional geochemical patterns and the identification of processes that produced these patterns. The geochemical results segregate broadly into distinct element groupings whose distribution reflects the interplay of geologic, hydrologic, geomorphic and anthropogenic factors. One such group includes elements associated with mafic and ultramafic rocks including Cr, Ni, V, Co, Cu and Mg. Using Cr as an example, elevated concentrations occur in soils overlying ultramafic rocks in the foothills of the Sierra Nevada (median Cr = 160 mg/kg) as well as in the northern Coast Ranges. Low concentrations of these elements occur in soils located further upslope in the Sierra Nevada overlying Tertiary volcanic, metasedimentary and plutonic rocks (granodiorite and diorite). Eastern Sacramento Valley soil samples, defined as those located east of the Sacramento River, are lower in Cr (median Cr = 84 mg/kg), and are systematically lower in this suite compared to soils from the west side of the Sacramento Valley (median Cr = 130 mg/kg). A second group of elements showing a coherent pattern, including Ca, K, Sr and REE, is derived from relatively silicic rocks types. This group occurs at elevated

  17. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    International Nuclear Information System (INIS)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J.; Rogers, V.; Scott, M.T.; Shirley, P.A.

    1990-01-01

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs

  18. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J. (Savannah River Lab., Aiken, SC (USA)); Rogers, V. (Soil Conservation Service, Aiken, SC (USA). Savannah River Site Savannah River Lab., Aiken, SC (USA)); Scott, M.T.; Shirley, P.A. (Sirrine Environmental Consultants, Greenville, SC (USA))

    1990-08-31

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs.

  19. Geochemical Modeling Of F Area Seepage Basin Composition And Variability

    International Nuclear Information System (INIS)

    Millings, M.; Denham, M.; Looney, B.

    2012-01-01

    From the 1950s through 1989, the F Area Seepage Basins at the Savannah River Site (SRS) received low level radioactive wastes resulting from processing nuclear materials. Discharges of process wastes to the F Area Seepage Basins followed by subsequent mixing processes within the basins and eventual infiltration into the subsurface resulted in contamination of the underlying vadose zone and downgradient groundwater. For simulating contaminant behavior and subsurface transport, a quantitative understanding of the interrelated discharge-mixing-infiltration system along with the resulting chemistry of fluids entering the subsurface is needed. An example of this need emerged as the F Area Seepage Basins was selected as a key case study demonstration site for the Advanced Simulation Capability for Environmental Management (ASCEM) Program. This modeling evaluation explored the importance of the wide variability in bulk wastewater chemistry as it propagated through the basins. The results are intended to generally improve and refine the conceptualization of infiltration of chemical wastes from seepage basins receiving variable waste streams and to specifically support the ASCEM case study model for the F Area Seepage Basins. Specific goals of this work included: (1) develop a technically-based 'charge-balanced' nominal source term chemistry for water infiltrating into the subsurface during basin operations, (2) estimate the nature of short term and long term variability in infiltrating water to support scenario development for uncertainty quantification (i.e., UQ analysis), (3) identify key geochemical factors that control overall basin water chemistry and the projected variability/stability, and (4) link wastewater chemistry to the subsurface based on monitoring well data. Results from this study provide data and understanding that can be used in further modeling efforts of the F Area groundwater plume. As identified in this study, key geochemical factors affecting basin

  20. Anthropogenic Increase Of Soil Erosion In The Gangetic Plain Revealed By Geochemical Budget Of Erosion

    Science.gov (United States)

    Galy, V.; France-Lanord, C.; Galy, A.; Gaillardet, J.

    2007-12-01

    Tectonic and climatic factors are the key natural variables controlling the erosion through complex interactions. Nonetheless, over the last few hundred years, human activity also exerts a dominant control in response to extensive land use. The geochemical budget of erosion allows the balance between the different erosion processes to be quantified. The chemical composition of river sediment results from the chemical composition of the source rock modified by (1) weathering reactions occurring during erosion and (2) physical segregation during transport. If erosion is at steady state, the difference between the chemical composition of source rocks and that of river sediments must therefore be counterbalanced by the dissolved flux. However, climatic variations or anthropic impact can induce changes in the erosion distribution in a given basin resulting in non steady state erosion. Using a mass balance approach, the comparison of detailed geochemical data on river sediments with the current flux of dissolved elements allows the steady state hypothesis to be tested. In this study, we present a geochemical budget of weathering for the Ganga basin, one of the most densely populated basin in the world, based on detailed sampling of Himalayan rivers and of the Ganga in the delta. Sampling includes depth profile in the river, to assess the variability generated by transport processes. Himalayan river sediments are described by the dilution of an aluminous component (micas + clays + feldspars) by quartz. Ganga sediments on the other hand correspond to the mixing of bedload, similar to coarse Himalayan sediments, with an aluminous component highly depleted in alkaline elements. Compared with the dissolved flux, the depletion of alkaline elements in Ganga sediments shows that the alkaline weathering budget is imbalanced. This imbalance results from an overabundance of fine soil material in the Ganga sediment relative to other less weathered material directly derived from

  1. Distribution of cadmium among geochemical fractions in floodplain soils of progressing development

    International Nuclear Information System (INIS)

    Lair, G.J.; Graf, M.; Zehetner, F.; Gerzabek, M.H.

    2008-01-01

    Initial soil development in river floodplains influences soil properties and processes. In this study, suites of young floodplain soils sampled at three European rivers (Danube/Austria, Ebro/Spain and Elbe/Germany) were used to link soil development to the soils' retention capacity for cadmium. Geochemichal fractionation of original and metal-spiked soils was conducted. Cadmium remained in weakly bound fractions in both original and spiked soils, representing an entirely different behaviour than observed for copper in an earlier study. The tendency of incorporation into more stable forms over time was only slightly expressed. Correlation analysis revealed the involvement of different sorption surfaces in soil, with no single soil constituent determining cadmium retention behaviour. Nevertheless, in the calcareous soils of the Danube floodplain, we found increased cadmium retention and decreased portions of desorbable cadmium with progressing soil development. - Distribution of cadmium among geochemical fractions in floodplain soils reveals high mobility but increased retention capacity with increasing soil age and development

  2. Soil variability in engineering applications

    Science.gov (United States)

    Vessia, Giovanna

    2014-05-01

    Natural geomaterials, as soils and rocks, show spatial variability and heterogeneity of physical and mechanical properties. They can be measured by in field and laboratory testing. The heterogeneity concerns different values of litho-technical parameters pertaining similar lithological units placed close to each other. On the contrary, the variability is inherent to the formation and evolution processes experienced by each geological units (homogeneous geomaterials on average) and captured as a spatial structure of fluctuation of physical property values about their mean trend, e.g. the unit weight, the hydraulic permeability, the friction angle, the cohesion, among others. The preceding spatial variations shall be managed by engineering models to accomplish reliable designing of structures and infrastructures. Materon (1962) introduced the Geostatistics as the most comprehensive tool to manage spatial correlation of parameter measures used in a wide range of earth science applications. In the field of the engineering geology, Vanmarcke (1977) developed the first pioneering attempts to describe and manage the inherent variability in geomaterials although Terzaghi (1943) already highlighted that spatial fluctuations of physical and mechanical parameters used in geotechnical designing cannot be neglected. A few years later, Mandelbrot (1983) and Turcotte (1986) interpreted the internal arrangement of geomaterial according to Fractal Theory. In the same years, Vanmarcke (1983) proposed the Random Field Theory providing mathematical tools to deal with inherent variability of each geological units or stratigraphic succession that can be resembled as one material. In this approach, measurement fluctuations of physical parameters are interpreted through the spatial variability structure consisting in the correlation function and the scale of fluctuation. Fenton and Griffiths (1992) combined random field simulation with the finite element method to produce the Random

  3. Landscape and bio- geochemical strategy for monitoring transformation and reclamation of the soil mining sites

    Science.gov (United States)

    Korobova, Elena

    2010-05-01

    Sites of active or abandoned mining represent areas of considerable technogenic impact and need scientifically ground organization of their monitoring and reclamation. The strategy of monitoring and reclamation depends on the scale and character of the physical, chemical and biological consequences of the disturbances. The geochemical studies for monitoring and rehabilitation of the career-dump complexes should methodically account of formation of the particular new landforms and the changes in circulation of the remobilized elements of the soil cover. However, the general strategy should account of both the initial and transformed landscape geochemical structure of the area with due regard to the natural and new content of chemical elements in the environmental components. For example the tailings and waste rocks present new geochemical fields with specifically different concentration of chemical elements that cause formation of new geochemical barriers and landscapes. The way of colonization of the newly formed landscapes depends upon the new geochemical features of the technogenic environment and the adaptive ability of local and intrusive flora. The newly formed biogeochemical anomalies need organization of permanent monitoring not only within the anomaly itself but also of its impact zones. Spatial landscape geochemical monitoring combined with bio-geochemical criteria of threshold concentrations seems to be a helpful tool for decision making on reclamation and operation of the soil mining sites to provide a long-term ecologically sustainable development of the impact zone as a whole.

  4. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    International Nuclear Information System (INIS)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-01-01

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r 2 < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  5. Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

    2010-01-01

    This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

  6. A comparison study on detection of key geochemical variables and factors through three different types of factor analysis

    Science.gov (United States)

    Hoseinzade, Zohre; Mokhtari, Ahmad Reza

    2017-10-01

    Large numbers of variables have been measured to explain different phenomena. Factor analysis has widely been used in order to reduce the dimension of datasets. Additionally, the technique has been employed to highlight underlying factors hidden in a complex system. As geochemical studies benefit from multivariate assays, application of this method is widespread in geochemistry. However, the conventional protocols in implementing factor analysis have some drawbacks in spite of their advantages. In the present study, a geochemical dataset including 804 soil samples collected from a mining area in central Iran in order to search for MVT type Pb-Zn deposits was considered to outline geochemical analysis through various fractal methods. Routine factor analysis, sequential factor analysis, and staged factor analysis were applied to the dataset after opening the data with (additive logratio) alr-transformation to extract mineralization factor in the dataset. A comparison between these methods indicated that sequential factor analysis has more clearly revealed MVT paragenesis elements in surface samples with nearly 50% variation in F1. In addition, staged factor analysis has given acceptable results while it is easy to practice. It could detect mineralization related elements while larger factor loadings are given to these elements resulting in better pronunciation of mineralization.

  7. GEMAS: Geochemical distribution of iodine in European agricultural soil

    Science.gov (United States)

    Birke, Manfred; Reimann, Clemens; Ladenberger, Anna; Négrel, Philippe; Rauch, Uwe; Demetriades, Alecos; Korte, Frank; Dinelli, Enrico

    2017-04-01

    Iodine concentrations are reported for the climate, soil formation processes, and geology (parent material, in some cases mineralisation). The distribution of anomalous I concentrations is likely a reflection of I input from atmospheric and marine sources, as well as the accumulation of I as a result of sorption on organic material. Across Europe, high I areas correlate well with soil with elevated TOC values. This is particularly evident for the western coastal areas of Ireland, UK, Norway, Galicia and France, where the organic matter content in the soil is generally high. The continuous supply of I from sea spray represents a potential source for high and elevated I concentrations. In the coastal zones of SE Spain, SE Ukraine and SW Croatia the I concentration in Ap samples is usually high. Along the eastern Adriatic coast as well as in South-East Ukraine and in the Crimea the elevated and anomalous I concentrations correspond well with the distribution of terra rossa soils developed on karst and organic-rich soils (black soil). In SE Spain the I enriched soils are most likely related to the occurrence of evaporites. The comparison of I background values (medians) based on the parent materials demonstrates a higher I content in soils over limestone and shale. Iodine-low soil areas (Iberian Peninsula) and glacial and aeolian deposits (NW Ukraine).

  8. Seasonal variability of microbial biomass phosphorus in urban soils.

    Science.gov (United States)

    Halecki, W; Gąsiorek, M

    2015-01-01

    Urban soils have been formed through human activities. Seasonal evaluation with time-control procedure are essential for plant, and activity of microorganisms. Therefore, these processes are crucial in the urban area due to geochemical changes in the past years. The purpose of this study was to investigate the changes of content of microbial biomass phosphorus (P) in the top layer of soils throughout the season. In this research, the concentration of microbial biomass P ranged from 0.01 to 6.29 mg·kg(-1). We used single-factor repeated-measure analysis of variance to test the effect of season on microbial biomass P content of selected urban soils. We found no statistically significant differences between the concentration of microbial biomass P in the investigated urban and sub-urban soils during the growing season. This analysis explicitly recognised that environmental urban conditions are steady. Specifically, we have studied how vegetation seasonality and ability of microbial biomass P are useful for detecting quality deviations, which affect the equilibrium of urban soil. In conclusion, seasonal variability of the stringency of assurance across the different compounds of soil reveals, as expected, the stable condition of the urban soils. Seasonal responses in microbial biomass P under urban soil use should establish a framework as a reference to the activity of the microorganisms. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Magnetic and Geochemical Properties of Andic Soils from the Massif Central, France

    Science.gov (United States)

    Grison, H.; Petrovsky, E.; Dlouha, S.; Kapicka, A.

    2014-12-01

    Ferrimagnetic iron oxides are the key magnetic minerals responsible for enhancement of the magnetic susceptibility in soils. Soils with andic properties contain high amount of Fe-oxides, but only few attempts were made to characterize these soils using magnetic methods. Magnetic susceptibility is in particular suitable for its sensitivity and fast measurement; the presence of Fe-oxides can be easily identified directly in the field. The aim of our study is to describe main magnetic and geochemical properties of soils rich in Fe oxides derived from strongly magnetic volcanic basement. The studied sites are located at the basalt parent rock formed during Pleistocene, Pliocene and Miocene. Investigated soils are exposed to the mountainous climate with the perudic soil moisture regime and cryic temperature soil regime. Seven basalt soil profiles with typical andic properties were analyzed down to parent rock by a set of magnetic and geochemical methods. The magnetic susceptibility was measured in situ and in laboratory using the Bartington MS2D and AGICO MFK1. Its temperature dependence was measured in order to assess phase transformations of magnetic minerals using the KLY4. Magnetic data were completed by the hysteresis, IRM and DCD measurements using ADE EV9 VSM. Geochemical data include soil reaction (pH), organic carbon, cations exchange capacity, and extractable iron and aluminium in the soil extracted by a dithionite-citrate, acid-ammonium oxalate and a pyrophosphate solution. Scanning electron microscopy was done for top/sub-soil and rock samples. Geochemical soil properties reflecting iron oxide stability correlate well with mass-specific magnetic susceptibility. Well pronounced relationship was observed between magnetic grain size, precipitation and soil pH, second group is reflecting concentration of feri-magnetic particles and age of parent rock, and the third group reflects degree of weathering and the thermomagnetic indices expressing changes in magneto

  10. Phosphorus sorption in relation to soil grain size and geochemical ...

    African Journals Online (AJOL)

    By using stepwise regression, the combination of Al, Fe, clay and Ca predicted more than 94% of the variation in the P sorption capacity of soils samples from Simiyu and Kagera basins. These four soil properties, which are strongly related to P sorption, could therefore be used as quick tests for predicting the P sorption ...

  11. phosphorus sorption in relation to soil grain size and geochemical

    African Journals Online (AJOL)

    Mgina

    use and landscape in the Simiyu and Kagera River basins were determined using the Langmuir ... determination of key soil properties that .... deviation) of selected soil properties in the Simiyu (S) and Kagera (K) basins. Particle size. % dry weight. Sample. %. Sand. % Silt. % Clay. pH. Al2O3. Fe2O3. CaO. Na2O. K2O. S1.

  12. Geochemical soil sampling for deeply-buried mineralized breccia pipes, northwestern Arizona

    Science.gov (United States)

    Wenrich, K.J.; Aumente-Modreski, R. M.

    1994-01-01

    Thousands of solution-collapse breccia pipes crop out in the canyons and on the plateaus of northwestern Arizona; some host high-grade uranium deposits. The mineralized pipes are enriched in Ag, As, Ba, Co, Cu, Mo, Ni, Pb, Sb, Se, V and Zn. These breccia pipes formed as sedimentary strata collapsed into solution caverns within the underlying Mississippian Redwall Limestone. A typical pipe is approximately 100 m (300 ft) in diameter and extends upward from the Redwall Limestone as much as 1000 m (3000 ft). Unmineralized gypsum and limestone collapses rooted in the Lower Permian Kaibab Limestone or Toroweap Formation also occur throughout this area. Hence, development of geochemical tools that can distinguish these unmineralized collapse structures, as well as unmineralized breccia pipes, from mineralized breccia pipes could significantly reduce drilling costs for these orebodies commonly buried 300-360 m (1000-1200 ft) below the plateau surface. Design and interpretation of soil sampling surveys over breccia pipes are plagued with several complications. (1) The plateau-capping Kaibab Limestone and Moenkopi Formation are made up of diverse lithologies. Thus, because different breccia pipes are capped by different lithologies, each pipe needs to be treated as a separate geochemical survey with its own background samples. (2) Ascertaining true background is difficult because of uncertainties in locations of poorly-exposed collapse cones and ring fracture zones that surround the pipes. Soil geochemical surveys were completed on 50 collapse structures, three of which are known mineralized breccia pipes. Each collapse structure was treated as an independent geochemical survey. Geochemical data from each collapse feature were plotted on single-element geochemical maps and processed by multivariate factor analysis. To contrast the results between geochemical surveys (collapse structures), a means of quantifying the anomalousness of elements at each site was developed. This

  13. Factors of the accumulation of heavy metals and metalloids at geochemical barriers in urban soils

    Science.gov (United States)

    Kosheleva, N. E.; Kasimov, N. S.; Vlasov, D. V.

    2015-05-01

    The bulk contents and concentrations of mobile (extracted by an ammonium acetate buffer with EDTA) Cd, Pb, Sb, As, Bi, Zn, and Cu were determined in the surface horizons of urban soils in the Eastern administrative okrug of Moscow. The regression analysis showed that the accumulation of these metals and metalloids in the soils is controlled by the physicochemical soil properties and by number of anthropogenic factors and landscape conditions (geochemical position, type of loose deposits, character of land use, dust load, vehicle emissions, building pattern, percent of green areas, and the extent of sealed soils). The precipitation of studied elements on the geochemical barriers had the following regularities: Cd, Cu, and Zn accumulated on the alkaline barriers; Bi, Sb, As, Cu, Pb, and Zn, on chemisorption barriers; Sb, As, and Pb, on organomineral barriers; and Cd and Cu, on the sorption-sedimentation barriers. Technogenic transformation of the physicochemical properties of urban soils resulted in the increase of the mean bulk contents of heavy metals and metalloids by 33-99%; the portion of elements fixed on the geochemical barriers increased by 26-50%.

  14. Predictor variable resolution governs modeled soil types

    Science.gov (United States)

    Soil mapping identifies different soil types by compressing a unique suite of spatial patterns and processes across multiple spatial scales. It can be quite difficult to quantify spatial patterns of soil properties with remotely sensed predictor variables. More specifically, matching the right scale...

  15. [Environmental geochemical baseline of heavy metals in soils of the Ili river basin and pollution evaluation].

    Science.gov (United States)

    Zhao, Xin-Ru; Nasier, Telajin; Cheng, Yong-Yi; Zhan, Jiang-Yu; Yang, Jian-Hong

    2014-06-01

    Environmental geochemical baseline models of Cu, Zn, Pb, As, Hg were established by standardized method in the ehernozem, chestnut soil, sierozem and saline soil from the Ili river valley region. The theoretical baseline values were calculated. Baseline factor pollution index evaluation method, environmental background value evaluation method and heavy metal cleanliness evaluation method were used to compare soil pollution degrees. The baseline factor pollution index evaluation showed that As pollution was the most prominent among the four typical types of soils within the river basin, with 7.14%, 9.76%, 7.50% of sampling points in chernozem, chestnut soil and sierozem reached the heavy pollution, respectively. 7.32% of sampling points of chestnut soil reached the permitted heavy metal Pb pollution index in the chestnut soil. The variation extent of As and Pb was the largest, indicating large human disturbance. Environmental background value evaluation showed that As was the main pollution element, followed by Cu, Zn and Pb. Heavy metal cleanliness evaluation showed that Cu, Zn and Pb were better than cleanliness level 2 and Hg was the of cleanliness level 1 in all four types of soils. As showed moderate pollution in sierozem, and it was of cleanliness level 2 or better in chernozem, chestnut soil and saline-alkali soil. Comparing the three evaluation systems, the baseline factor pollution index evaluation more comprehensively reflected the geochemical migration characteristics of elements and the soil formation processes, and the pollution assessment could be specific to the sampling points. The environmental background value evaluation neglected the natural migration of heavy metals and the deposition process in the soil since it was established on the regional background values. The main purpose of the heavy metal cleanliness evaluation was to evaluate the safety degree of soil environment.

  16. Leaching of chromium from chromium contaminated soil: Speciation study and geochemical modeling

    Directory of Open Access Journals (Sweden)

    Anđelković Darko H.

    2012-01-01

    Full Text Available Distribution of chromium between soil and leachate was monitored. A natural process of percolating rainwater through the soil was simulated in the laboratory conditions and studied with column leaching extraction. Migration of chromium in the soil is conditioned by the level of chromium soil contamination, the soil organic matter content, and rainwater acidity. Chromium (III and chromium(VI were determined by spectrophotometric method with diphenilcarbazide in acidic media. Comparing the results of chromium speciation in leachate obtained by experimental model systems and geochemical modelling calculations using Visual MINTEQ model, a correlation was observed regarding the influence of the tested parameters. Leachate solutions showed that the concentration of Cr depended on the organic matter content. The influence of pH and soil organic matter content is in compliance after its definition through experimental and theoretical way. The computer model - Stockholm Humic Model used to evaluate the leaching results corresponded rather well with the measured values.

  17. Geochemical Modeling of Trivalent Chromium Migration in Saline-Sodic Soil during Lasagna Process: Impact on Soil Physicochemical Properties

    Science.gov (United States)

    Bukhari, Alaadin; Al-Malack, Muhammad H.; Mu'azu, Nuhu D.; Essa, Mohammed H.

    2014-01-01

    Trivalent Cr is one of the heavy metals that are difficult to be removed from soil using electrokinetic study because of its geochemical properties. High buffering capacity soil is expected to reduce the mobility of the trivalent Cr and subsequently reduce the remedial efficiency thereby complicating the remediation process. In this study, geochemical modeling and migration of trivalent Cr in saline-sodic soil (high buffering capacity and alkaline) during integrated electrokinetics-adsorption remediation, called the Lasagna process, were investigated. The remedial efficiency of trivalent Cr in addition to the impacts of the Lasagna process on the physicochemical properties of the soil was studied. Box-Behnken design was used to study the interaction effects of voltage gradient, initial contaminant concentration, and polarity reversal rate on the soil pH, electroosmotic volume, soil electrical conductivity, current, and remedial efficiency of trivalent Cr in saline-sodic soil that was artificially spiked with Cr, Cu, Cd, Pb, Hg, phenol, and kerosene. Overall desirability of 0.715 was attained at the following optimal conditions: voltage gradient 0.36 V/cm; polarity reversal rate 17.63 hr; soil pH 10.0. Under these conditions, the expected trivalent Cr remedial efficiency is 64.75 %. PMID:25152905

  18. A national-scale geochemical and mineralogical survey of soils of the conterminous United States

    International Nuclear Information System (INIS)

    Smith, David B.; Cannon, William F.; Woodruff, Laurel G.

    2011-01-01

    Highlights: → Sampling for national-scale soil geochemical and mineralogical survey completed for conterminous USA. → Natural variation for most elements is approximately three orders of magnitude. → Composition of soil parent material is the major controlling factor. → Climate (average annual precipitation) is also an important controlling factor for some elements. → Sample archive (4800 sites) available for future investigations. - Abstract: In 2007, the US Geological Survey initiated a low-density (1 site per 1600 km 2 , c. 4800 sites) geochemical and mineralogical survey of soils of the conterminous USA. The ideal sampling protocol at each site includes a sample from 0-5 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The 3 , HClO 4 and HF. Separate methods are used for As, Hg, Se and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling was completed in 2010 with chemical and mineralogical analysis currently underway. Preliminary results for a swath from the central USA to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

  19. Computer analysis to the geochemical interpretation of soil and stream sediment data in an area of Southern Uruguay

    International Nuclear Information System (INIS)

    Spangenberg, J.

    2010-01-01

    In southern Uruguay there are several known occurrences of base metal sulphide mineralization within an area of Precambrian volcanic sedimentary rocks. Regional geochemical stream sediment reconnaissance surveys revealed new polymetallic anomalies in the same stratigraphic zone. Geochemical interpretation of multi-element data from a soil and stream sediment survey carried out in one of these anomalous areas is presented.

  20. Geochemical and microbiological study in soils of southern Uruguay

    International Nuclear Information System (INIS)

    Pianzzola, M.; De Souza, S.; Soubes, M.; Goso Aguilar, C.

    2009-01-01

    The sulphate reducing bacteria (S RB) constitute a diverse group of anaerobic prokaryotes that carry out the dissimilarity sulphate reduction of sulphur compounds like sulphate, sulphite, tio sulphate, and sulphide to hydrogen sulphide. Although B SR are anaerobic, some genre tolerate oxygen and some others, at low concentrations, can res pirate Fe+ 3 or oxygen, using hydrogen as electron donor. Several industries, including oil and natural gas processing and transporting plants, have been affected by their metabolic activity and the fundamental cause is the production of H S, corrosive and toxic. It damages the pumping equipment, tanks, and 2 pipes. On the other hand, the generated sulphide affects human health and causes security and environmental problems producing severe economic losses. Given the ecological and economic importance of the S RB this study attempts of its presence in soils of different characteristics from southern Uruguay. Although in the last years its knowledge at molecular level has been increased, there is still lack of information so as to be able to control all the effects produced by its metabolic activity. The objective of our work is to determine the degree of diversity of these bacteria in our soils and to know the bio corrosion potential of them. As a first step we have collected soil samples with different characteristics, having determined its p H, humidity, content of chloride and sulphates as well as the presence of S RB. Although the main obstacle to understand its ecology and diversity is the incapacity to cultivate many of the microorganisms that come from environmental samples, this difficulty can directly be avoided by means of the use of molecular techniques that allow the study of the microorganisms present or their genes. In this work we correlate the detection of sulphate reducing bacteria by classic and molecular methods in the different soils studied

  1. Soil physics and the water management of spatially variable soils

    International Nuclear Information System (INIS)

    Youngs, E.G.

    1983-01-01

    The physics of macroscopic soil-water behaviour in inert porous materials has been developed by considering water flow to take place in a continuum. This requires the flow region to consist of an assembly of representative elementary volumes, repeated throughout space and small compared with the scale of observations. Soil-water behaviour in swelling soils may also be considered as a continuum phenomenon so long as the soil is saturated and swells and shrinks in the normal range. Macroscale heterogeneity superimposed on the inherent microscale heterogeneity can take many forms and may pose difficulties in the definition and measurement of soil physical properties and also in the development and use of predictive theories of soil-water behaviour. Thus, measurement techniques appropriate for uniform soils are often inappropriate, and criteria for soil-water management, obtained from theoretical considerations of behaviour in equivalent uniform soils, are not applicable without modification when there is soil heterogeneity. The spatial variability of soil-water properties is shown in results from field experiments concerned with water flow measurements; these illustrate both stochastic and deterministic heterogeneity in soil-water properties. Problems of water management of spatially variable soils when there is stochastic heterogeneity appear to present an insuperable problem in the application of theory. However, for soils showing deterministic heterogeneity, soil-water theory has been used in the solution of soil-water management problems. Thus, scaling using similar media theory has been applied to the infiltration of water into soils that vary over a catchment area. Also, the drain spacing to control the water-table height in soils in which the hydraulic conductivity varies with depth has been calculated using groundwater seepage theory. (author)

  2. Pilot study of the application of Tellus airborne radiometric and soil geochemical data for radon mapping

    Energy Technology Data Exchange (ETDEWEB)

    Appleton, J.D. [British Geological Survey, Kingsley Dunham Centre, Keyworth, Nottingham NG12 5GG (United Kingdom)], E-mail: jda@bgs.ac.uk; Miles, J.C.H.; Green, B.M.R. [Health Protection Agency (HPA) - Radiation Protection Division, Chilton, Didcot, Oxon OX11 0RQ (United Kingdom); Larmour, R. [Environment and Heritage Service, Department of the Environment, Belfast BT7 2JA (United Kingdom)

    2008-10-15

    The scope for using Tellus Project airborne gamma-ray spectrometer and soil geochemical data to predict the probability of houses in Northern Ireland having high indoor radon concentrations is evaluated, in a pilot study in the southeast of the province, by comparing these data statistically with in-house radon measurements. There is generally good agreement between radon maps modelled from the airborne radiometric and soil geochemical data using multivariate linear regression analysis and conventional radon maps which depend solely on geological and indoor radon data. The radon maps based on the Tellus Project data identify some additional areas where the radon risk appears to be relatively high compared with the conventional radon maps. One of the ways of validating radon maps modelled on the Tellus Project data will be to carry out additional indoor measurements in these areas.

  3. History and progress of the North American Soil Geochemical Landscapes Project, 2001-2010

    Science.gov (United States)

    Smith, David B.; Cannon, William F.; Woodruff, Laurel G.; Rivera, Francisco Moreira; Rencz, Andrew N.; Garrett, Robert G.

    2012-01-01

    In 2007, the U.S. Geological Survey, the Geological Survey of Canada, and the Mexican Geological Survey initiated a low-density (1 site per 1600 km2, 13323 sites) geochemical and mineralogical survey of North American soils (North American Soil Geochemical Landscapes Project). Sampling and analytical protocols were developed at a series of workshops in 20032004 and pilot studies were conducted from 20042007. The ideal sampling protocol at each site includes a sample from 05 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The 3, HClO4, and HF. Separate methods are used for As, Hg, Se, and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling in the conterminous U.S. was completed in 2010 (c. 4800 sites) with chemical and mineralogical analysis currently underway. In Mexico, approximately 66% of the sampling (871 sites) had been done by the end of 2010 with completion expected in 2012. After completing sampling in the Maritime provinces and portions of other provinces (472 sites, 7.6% of the total), Canada withdrew from the project in 2010. Preliminary results for a swath from the central U.S. to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

  4. Computer analysis to the geochemical of soil and stream sediments data in an area of Southern Uruguay

    International Nuclear Information System (INIS)

    Spangenberg, J.

    2012-01-01

    This work is about geochemical interpretation of multi-element data from a soil and stream sediment survey carried out in Southern of Uruguay .This zone has several occurrences of metal sulphide mineralization

  5. Role of soil geochemical and microbiological components on selenium behaviour in oxic and anoxic conditions

    International Nuclear Information System (INIS)

    Darcheville, O.

    2008-09-01

    Selenium (Se) is naturally present in the environment. Se is essential for living organisms at trace concentrations, but it becomes rapidly toxic with their increases. The 79 Se radioactive isotopes of Se, is found in nuclear wastes that may be buried in deep geological formations. In soil, Se exists in many forms and its mobility is affected by the redox potential and microbial activity. Very few studies have focused on Se behaviour at trace concentration. We have tried to distinguish the major abiotic geochemical and microbiological processes involved in the fate of trace selenite (Se(IV)) in a soil. The study was based on batch incubation in oxic or anoxic conditions of slurry suspension artificially contaminated with Se (IV) to 0.4 mg Se.kg -1 dry soil. The incubation involved sterilized and non-sterile soil samples with or without organic amendment to stimulate microbial activities. For each incubation, we followed the distribution of Se between solid, liquid and gaseous phases as well as the geochemical evolution of the solution, the composition of the atmosphere gas bottles and the soil microflora. The results showed that Se was relatively few mobile in the soil studied. Geochemical processes played a major role in controlling the Se mobility. Over time, some abiotic transformations in the solid phase contributed to increase the Se immobilisation. The microbiological processes contributed to this increase in the solid phase. Moreover, in oxic as in anoxic conditions, some microbial processes were responsible, to a lesser extent, for a dispersion of Se in the atmosphere by the production of volatile compounds. (author)

  6. Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany

    International Nuclear Information System (INIS)

    Norra, Stefan; Lanka-Panditha, Mahesh; Kramar, Utz; Stueben, Doris

    2006-01-01

    This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0-5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by

  7. [Geochemical characteristics of radon and mercury in soil gas in Lhasa, Tibet, China].

    Science.gov (United States)

    Zhou, Xiao-Cheng; Du, Jian-Guo; Wang, Chuan-Yuan; Cao, Zhong-Quan; Yi, Li; Liu, Lei

    2007-03-01

    The geochemical characteristics of radon and mercury in soil gas in Lhasa and vicinity are investigated based on the measurements of Rn and Hg concentrations, and environmental quality for Rn and Hg in soil gas was evaluated by means of the index of geoaccumulation. The data of Rn and Hg of 1 579 sampling site indicate that the values of environmental-geochemical background of Rn and Hg are 7 634.9 Bq/m3, 41.5 ng/m3 with standard deviations of 2.7 Bq/m3, 2.2 ng/m3, respectively. The environmental quality for Rn in soil gas is better in the west and east parts of studied area, but becomes moderate pollution (level III) in the north part of the central area. Rn is derived from radioactive elements in granitic sediments in the intermountain basin and granite base, which are the major sources of pollution. The environmental quality for Hg in soil gas becomes gradually polluted from the suburban to the center of urban, and the highest pollution reaches level IV. The background of Hg in soil gas is mainly controlled by compositions of sediments, but the Hg pollution caused by human waste and religionary use of mercury.

  8. Seasonal variability of soil aggregate stability

    Czech Academy of Sciences Publication Activity Database

    Rohošková, M.; Kodešová, R.; Jirků, V.; Žigová, Anna; Kozák, J.

    2009-01-01

    Roč. 11, - (2009), , , EGU2009-6341-3-EGU2009-6341-3 ISSN 1029-7006. [European Geosciences Union General Assembly. 19.04.2009-24.04.2009, Vienna] R&D Projects: GA ČR GA526/08/0434 Institutional research plan: CEZ:AV0Z30130516 Keywords : seasonal variability * soil aggregate stability * soil types Subject RIV: DF - Soil Science

  9. Using geochemical indicators to distinguish high biogeochemical activity in floodplain soils and sediments

    Energy Technology Data Exchange (ETDEWEB)

    Kenwell, Amy [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Navarre-Sitchler, Alexis, E-mail: asitchle@mines.edu [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Prugue, Rodrigo [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Spear, John R. [Department of Civil and Environmental Engineering, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Hering, Amanda S. [Department of Applied Mathematics and Statistics, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Maxwell, Reed M. [Hydrologic Sciences and Engineering Program, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401 (United States); Carroll, Rosemary W.H. [Desert Research Institute, Division of Hydrologic Sciences, 2215 Raggio Parkway, Reno, NV 89512 (United States); Williams, Kenneth H. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

    2016-09-01

    A better understanding of how microbial communities interact with their surroundings in physically and chemically heterogeneous subsurface environments will lead to improved quantification of biogeochemical reactions and associated nutrient cycling. This study develops a methodology to predict potential elevated rates of biogeochemical activity (microbial “hotspots”) in subsurface environments by correlating microbial DNA and aspects of the community structure with the spatial distribution of geochemical indicators in subsurface sediments. Multiple linear regression models of simulated precipitation leachate, HCl and hydroxylamine extractable iron and manganese, total organic carbon (TOC), and microbial community structure were used to identify sample characteristics indicative of biogeochemical hotspots within fluvially-derived aquifer sediments and overlying soils. The method has been applied to (a) alluvial materials collected at a former uranium mill site near Rifle, Colorado and (b) relatively undisturbed floodplain deposits (soils and sediments) collected along the East River near Crested Butte, Colorado. At Rifle, 16 alluvial samples were taken from 8 sediment cores, and at the East River, 46 soil/sediment samples were collected across and perpendicular to 3 active meanders and an oxbow meander. Regression models using TOC and TOC combined with extractable iron and manganese results were determined to be the best fitting statistical models of microbial DNA (via 16S rRNA gene analysis). Fitting these models to observations in both contaminated and natural floodplain deposits, and their associated alluvial aquifers, demonstrates the broad applicability of the geochemical indicator based approach. - Highlights: • Biogeochemical characterization of alluvial floodplain soils and sediments was performed to investigate parameters that may indicate microbial hot spot formation. • A correlation between geochemical parameters (total organic carbon and

  10. Using geochemical indicators to distinguish high biogeochemical activity in floodplain soils and sediments

    International Nuclear Information System (INIS)

    Kenwell, Amy; Navarre-Sitchler, Alexis; Prugue, Rodrigo; Spear, John R.; Hering, Amanda S.; Maxwell, Reed M.; Carroll, Rosemary W.H.; Williams, Kenneth H.

    2016-01-01

    A better understanding of how microbial communities interact with their surroundings in physically and chemically heterogeneous subsurface environments will lead to improved quantification of biogeochemical reactions and associated nutrient cycling. This study develops a methodology to predict potential elevated rates of biogeochemical activity (microbial “hotspots”) in subsurface environments by correlating microbial DNA and aspects of the community structure with the spatial distribution of geochemical indicators in subsurface sediments. Multiple linear regression models of simulated precipitation leachate, HCl and hydroxylamine extractable iron and manganese, total organic carbon (TOC), and microbial community structure were used to identify sample characteristics indicative of biogeochemical hotspots within fluvially-derived aquifer sediments and overlying soils. The method has been applied to (a) alluvial materials collected at a former uranium mill site near Rifle, Colorado and (b) relatively undisturbed floodplain deposits (soils and sediments) collected along the East River near Crested Butte, Colorado. At Rifle, 16 alluvial samples were taken from 8 sediment cores, and at the East River, 46 soil/sediment samples were collected across and perpendicular to 3 active meanders and an oxbow meander. Regression models using TOC and TOC combined with extractable iron and manganese results were determined to be the best fitting statistical models of microbial DNA (via 16S rRNA gene analysis). Fitting these models to observations in both contaminated and natural floodplain deposits, and their associated alluvial aquifers, demonstrates the broad applicability of the geochemical indicator based approach. - Highlights: • Biogeochemical characterization of alluvial floodplain soils and sediments was performed to investigate parameters that may indicate microbial hot spot formation. • A correlation between geochemical parameters (total organic carbon and

  11. Soil gas radon response to environmental and soil physics variables

    International Nuclear Information System (INIS)

    Thomas, D.M.; Chen, C.; Holford, D.

    1991-01-01

    During the last three years a field study of soil gas radon activities conducted at Poamoho, Oahu, has shown that the primary environmental variables that control radon transport in shallow tropical soils are synoptic and diurnal barometric pressure changes and soil moisture levels. Barometric pressure changes drive advective transport and mixing of soil gas with atmospheric air; soil moisture appears to control soil porosity and permeability to enhance or inhibit advective and diffusive radon transport. An advective barrier test/control experiment has shown that advective exchange of soil gas and air may account for a substantial proportion of the radon loss from shallow soils but does not significantly affect radon activities at depths greater than 2.3 m. An irrigation test/control experiment also suggests that, at soil moisture levels approaching field capacity, saturation of soil macroporosity can halt all advective transport of radon and limit diffusive mobility to that occurring in the liquid phase. The results of the authors field study have been used to further refine and extend a numerical model, RN3D, that has been developed by Pacific Northwest Laboratories to simulate subsurface transport of radon. The field data have allowed them to accurately simulate the steady state soil gas radon profile at their field site and to track transient radon activities under the influence of barometric pressure changes and in response to changes in soil permeability that result from variations in soil moisture levels. Further work is continuing on the model to enable it to properly account for the relative effects of advective transport of soil gas through cracks and diffusive mobility in the bulk soils

  12. Geochemical disturbance of soil cover in the nonferrous mining centers of the Selenga River basin.

    Science.gov (United States)

    Timofeev, Ivan V; Kosheleva, Natalia E

    2017-08-01

    The anthropogenic geochemical transformation of soil cover in large nonferrous mining centers of the Selenga River basin was assessed. The results of the geochemical survey of 2010-2012 revealed the spatial distribution patterns and abundances of 18 hazardous heavy metals and metalloids in the soils of Erdenet (Mongolia) and Zakamensk (Buryat republic, Russian Federation). In both cities, mining activities disturbed soil cover which accumulates Mo, Cu, As, Sb, W in Erdenet and Bi, W, Cd, Be, Pb, Mo, Sb in Zakamensk. Maximum accumulation of elements in Erdenet is restricted to the industrial zone. In Zakamensk, it has spread on ½ of the territory with the degree of multielemental pollution exceeding the extremely dangerous level by 16 times. The effect of mining centers on the state of the river system is local and does not spread to the Selenga River. Downstream from Erdenet, an artificial pool intercepts heavy metal and metalloid flows of the Erdenetii-Gol River. By contrast, downstream from the tailing dumps of the Dzhida tungsten-molybdenum plant the concentrations of ore elements W and Mo and their accessories Bi and Cd in the Modonkul River exceed background values by 146, 20, 57, and 21 times, respectively, decreasing by an order of magnitude 30 km downstream.

  13. Trace elements assessment in agricultural and desert soils of Aswan area, south Egypt: Geochemical characteristics and environmental impacts

    Science.gov (United States)

    Darwish, Mohamed Abdallah Gad; Pöllmann, Hebert

    2015-12-01

    Determination of chemical elements, Al, Cd, Co, Cr, Cu, Fe, Li, Mn, Mo, Ni, P, Pb, Sc, Sr, Ti, Y, and Zn have been performed in agricultural and desert soils and alfalfa (Medicago sativa) at Aswan area. Consequently, the pollution indices, univariate and multivariate statistical methods have been applied, in order to assess the geochemical characteristics of these elements and their impact on soil environmental quality and plant, and to reach for their potential input sources. The investigation revealed that the mean and range values of all element concentrations in agricultural soil are higher than those in desert soil. Furthermore, the agricultural soil displayed various degrees of enrichment and pollution of Cd, Zn, Mo, Co, P, Ti, Pb. The geochemical pattern of integrated pollution indices gave a clear image of extreme and strong pollution in the agricultural soil stations, their poor quality with high risk to human health and considered as a tocsin for an alert. In contrast, the desert soil is the good environmental quality and safe for plant, animal and human health. Alfalfa is tolerant plant and considered as a biomarker for P and Mo in polluted agricultural soil. Four geochemical associations of analyzing elements in agricultural soil and three ones in desert soil have been generated, and their enhancements were essentially caused by various anthropogenic activities and geogenic sources. The investigation also revealed that the broad extended desert soil is fruitful and promising as cultivable lands for agricultural processes in the futures.

  14. Process recognition in multi-element soil and stream-sediment geochemical data

    Science.gov (United States)

    Grunsky, E.C.; Drew, L.J.; Sutphin, D.M.

    2009-01-01

    Stream-sediment and soil geochemical data from the Upper and Lower Coastal Plains of South Carolina (USA) were studied to determine relationships between soils and stream sediments. From multi-element associations, characteristic compositions were determined for both media. Primary associations of elements reflect mineralogy, including heavy minerals, carbonates and clays, and the effects of groundwater. The effects of groundwater on element concentrations are more evident in soils than stream sediments. A "winnowing index" was created using ratios of Th to Al that revealed differing erosional and depositional environments. Both soils and stream sediments from the Upper and Lower Coastal Plains show derivation from similar materials and subsequent similar multi-element relationships, but have some distinct differences. In the Lower Coastal Plain, soils have high values of elements concentrated in heavy minerals (Ce, Y, Th) that grade into high values of elements concentrated into finer-grain-size, lower-density materials, primarily comprised of carbonates and feldspar minerals (Mg, Ca, Na, K, Al). These gradational trends in mineralogy and geochemistry are inferred to reflect reworking of materials during marine transgressions and regressions. Upper Coastal Plain stream-sediment geochemistry shows a higher winnowing index relative to soil geochemistry. A comparison of the 4 media (Upper Coastal Plain soils and stream sediments and Lower Coastal Plain soils and stream sediments) shows that Upper Coastal Plain stream sediments have a higher winnowing index and a higher concentration of elements contained within heavy minerals, whereas Lower Coastal Plain stream sediments show a strong correlation between elements typically contained within clays. It is not possible to calculate a functional relationship between stream sediment-soil compositions for all elements due to the complex history of weathering, deposition, reworking and re-deposition. However, depending on

  15. Boreal coniferous forest density leads to significant variations in soil physical and geochemical properties

    Science.gov (United States)

    Bastianelli, Carole; Ali, Adam A.; Beguin, Julien; Bergeron, Yves; Grondin, Pierre; Hély, Christelle; Paré, David

    2017-07-01

    At the northernmost extent of the managed forest in Quebec, Canada, the boreal forest is currently undergoing an ecological transition between two forest ecosystems. Open lichen woodlands (LW) are spreading southward at the expense of more productive closed-canopy black spruce-moss forests (MF). The objective of this study was to investigate whether soil properties could distinguish MF from LW in the transition zone where both ecosystem types coexist. This study brings out clear evidence that differences in vegetation cover can lead to significant variations in soil physical and geochemical properties.Here, we showed that soil carbon, exchangeable cations, and iron and aluminium crystallinity vary between boreal closed-canopy forests and open lichen woodlands, likely attributed to variations in soil microclimatic conditions. All the soils studied were typical podzolic soil profiles evolved from glacial till deposits that shared a similar texture of the C layer. However, soil humus and the B layer varied in thickness and chemistry between the two forest ecosystems at the pedon scale. Multivariate analyses of variance were used to evaluate how soil properties could help distinguish the two types at the site scale. MF humus (FH horizons horizons composing the O layer) showed significantly higher concentrations of organic carbon and nitrogen and of the main exchangeable base cations (Ca, Mg) than LW soils. The B horizon of LW sites held higher concentrations of total Al and Fe oxides and particularly greater concentrations of inorganic amorphous Fe oxides than MF mineral soils, while showing a thinner B layer. Overall, our results show that MF store three times more organic carbon in their soils (B+FH horizons, roots apart) than LW. We suggest that variations in soil properties between MF and LW are linked to a cascade of events involving the impacts of natural disturbances such as wildfires on forest regeneration that determines the vegetation structure (stand density

  16. Bio-geochemical behavior of 90Sr, 137Cs and 60Co in tropical soil

    International Nuclear Information System (INIS)

    Wasserman, M.A.; Gonzales Viana, A.; Bartoly, F.; Carvalho Conti, C. de; Janvrot Vivone, R.; Perez, V.; Wasserman, J.C.

    2004-01-01

    One manner to assess the bio-geochemical behavior of radionuclides in soils is the integration of experimental methods results obtained in the laboratory with results obtained in field experiments. In this work was used an alternative sequential chemical extraction protocol to evaluate mobility of radionuclides as a function of some physico-chemical conditions operationally defined: Slightly acidic phase: CH 3 COOH + CH 3 COONa 1:1, pH 4.7, shacked at room temperature; Easily reducible phase: NH 2 OH.HCl (0.1 M), pH 2, shacked at room temperature;Oxidizable phase: H 2 O 2 (30%) + HNO 3 , pH 2, CH 3 COONH 4 (1 M);shacked at room temperature; Alkaline phase: NaOH (0.1 M), pH 12, shacked at room temperature; Resistant phase: Aqua regia heated to 50 deg C / 30 min. The results obtained experimentally indicate the vulnerability of some Brazilian soils due to the higher radionuclide transfer to plant. Although it seems clear that it is difficult to identify which soil property will determine a given TF, the results of geochemical partition for 137 Cs, 90 Sr and 60 Co obtained in slightly acidic phase were very consistent with the TF data for reference plants or with some of the soil properties recognized in the specialized literature as related with mechanisms of sorption of Cs (e.g. exchangeable K, organic matter and iron oxides content), Co (e.g. manganese oxide) and Sr (pH and exchangeable Ca). The 137 Cs distribution in soil showed that Fe oxides are the main sink for this element in all type of soil and 16 years after contamination the 137 Cs the TF remains almost the same in Goiania soil. The 60 Co distribution in soil showed that Mn oxides are the main sink for this element in all type of soils and in the Nitisol, 5 years after contamination, the 60 Co was not detected as bioavailable (in the slightly acidic phase) neither detected in plant or were detectable with values very close to the detection limit. In the Nitisol, it is possible that reduction in 137 Cs

  17. Mineralogical and geochemical study of contaminated soils on abandoned Sb deposits Dubrava and Poproc

    International Nuclear Information System (INIS)

    Klimko, T.; Jurkovic, L.

    2010-01-01

    In this paper we present initial results of mineralogical and geochemical study of secondary mineral phases, often with a high content of Sb and As, resulting from oxidation of sulphide minerals in the soil environment on two, now abandoned Sb deposits. Dubrava deposit is situated on the northern slopes of the Dumbier Low Tatras and Poproc deposit is located in the eastern part of Spis-Gemer Rudohorie. Both studied sites were in the past (second half of 20 th century) significant producers of antimony ore and Dubrava deposit belonged to medium-sized Sb deposits in the world.

  18. Geochemical pattern of soils in Bobovdol valley, Bulgaria. Assessment of Cd and Co contents

    Directory of Open Access Journals (Sweden)

    Ivona Nikova

    2016-07-01

    Full Text Available The chemical composition of soils spread in the Bobov dol valley was studied in order to reveal the natural and anthropogenic patterns of Cd and Co spatial distribution. A sampling procedure based on the irregular grid of points and validated analytical methods were used in the field and laboratory studies. It is found that Cd content varies from 0.21 to 0.90 mg kg-1 in studied soils and the average value of 0.55 mg kg-1 coincides with concentration demarcating soil pollution (0.5 mg kg-1. Co content ranges from 2.22 to 15.76 mg kg-1 and in 70 % of sampled points exceeds the natural background content of 7.8 mg kg-1 found in local rocks. Still, Cd enrichment of studied soils is more significant than Co’s with coefficient of Clarke concentration of 3.67. Hence, the secondary deposition of studied elements as a result of the Bobov dol Thermal power plant air emissions is verified by results obtained. The spatial distribution of Cd and Co is featured with an altitudinal gradient in deposition and a trend of quantitative depletion in the South of Plant. Soil organic matter and pH have no influence on the content and spatial distribution of studied elements. Elements iron affinity governs their geochemical linkage in soils although cobalt occurs allied with aluminum and titanium.

  19. Geochemical effects on the behavior of LLW radionuclides in soil/groundwater environments

    Energy Technology Data Exchange (ETDEWEB)

    Krupka, K.M.; Sterne, R.J. [Pacific Northwest Lab., Richland, WA (United States)

    1995-12-31

    Assessing the migration potential of radionuclides leached from low-level radioactive waste (LLW) and decommissioning sites necessitates information on the effects of sorption and precipitation on the concentrations of dissolved radionuclides. Such an assessment requires that the geochemical processes of aqueous speciation, complexation, oxidation/reduction, and ion exchange be taken into account. The Pacific Northwest National Laboratory (PNNL) is providing technical support to the U.S. Nuclear Regulatory Commission (NRC) for defining the solubility and sorption behavior of radionuclides in soil/ground-water environments associated with engineered cementitious LLW disposal systems and decommissioning sites. Geochemical modeling is being used to predict solubility limits for radionuclides under geochemical conditions associated with these environments. The solubility limits are being used as maximum concentration limits in performance assessment calculations describing the release of contaminants from waste sources. Available data were compiled regarding the sorption potential of radionuclides onto {open_quotes}fresh{close_quotes} cement/concrete where the expected pH of the cement pore waters will equal to or exceed 10. Based on information gleaned from the literature, a list of preferred minimum distribution coefficients (Kd`s) was developed for these radionuclides. The K{sub d} values are specific to the chemical environments associated with the evolution of the compositions of cement/concrete pore waters.

  20. Monitoring of Ecological and Geochemical State of the Soil Cover in the City of Voronezh

    Directory of Open Access Journals (Sweden)

    Sereda Lyudmila Olegovna

    2015-09-01

    Full Text Available Soil cover in the city of Voronezh accumulates a lot of pollutants and indicates the centers of technological pollution. The high rates of housing construction, functioning and development of urban infrastructure cause infringement to the soil cover. The paper contains main results of an ecological and geochemical research of the soil cover in Voronezh, its characteristics, properties of the horizons of the different types of soils. During spring and summer of 2014 75 samples of soil were collected in special points of monitoring (according to GOST 17.4.3.01-83 and GOST 17.4.4.02-84. During the research the following methods were applied – volt-ampermetric method was used for detecting the concentration of heavy metals, the method of cholophorm-hexan extraction – for petrochemicals, the method of I.V. Tyurin – for humus concentration, potentiometric method and biotesting methods (analysis of seedlings of the following indicating plants – Lepidium sativum, Avena sativa, as well as defining the phytotoxic effect – for actual acidity detection. The obtained results are used for creating an overview soil map of Voronezh. Urbanozems are dominating in the soil cover of Voronezh. There era large areas of them in the majority of the city districts. A smaller part of a total urban area is presented by soils, which are slightly touched by human economic activity. Urban soils of industrial and transport city zones have disadvantageous properties – low rate of humus and alkali reaction of soil environment, high rate of pollution by petrochemicals and heavy metals. The least rate of pollution of a soil cover by heavy metals is detected in residential areas, situated far from industrial objects and highways. We have detected dependence between accumulation of polluting substances in soil cover and functional and planning peculiarities of the city. For example, accumulation of zinc takes place in soils with alkali reaction of soil and low

  1. Boreal coniferous forest density leads to significant variations in soil physical and geochemical properties

    Directory of Open Access Journals (Sweden)

    C. Bastianelli

    2017-07-01

    Full Text Available At the northernmost extent of the managed forest in Quebec, Canada, the boreal forest is currently undergoing an ecological transition between two forest ecosystems. Open lichen woodlands (LW are spreading southward at the expense of more productive closed-canopy black spruce–moss forests (MF. The objective of this study was to investigate whether soil properties could distinguish MF from LW in the transition zone where both ecosystem types coexist. This study brings out clear evidence that differences in vegetation cover can lead to significant variations in soil physical and geochemical properties.Here, we showed that soil carbon, exchangeable cations, and iron and aluminium crystallinity vary between boreal closed-canopy forests and open lichen woodlands, likely attributed to variations in soil microclimatic conditions. All the soils studied were typical podzolic soil profiles evolved from glacial till deposits that shared a similar texture of the C layer. However, soil humus and the B layer varied in thickness and chemistry between the two forest ecosystems at the pedon scale. Multivariate analyses of variance were used to evaluate how soil properties could help distinguish the two types at the site scale. MF humus (FH horizons horizons composing the O layer showed significantly higher concentrations of organic carbon and nitrogen and of the main exchangeable base cations (Ca, Mg than LW soils. The B horizon of LW sites held higher concentrations of total Al and Fe oxides and particularly greater concentrations of inorganic amorphous Fe oxides than MF mineral soils, while showing a thinner B layer. Overall, our results show that MF store three times more organic carbon in their soils (B+FH horizons, roots apart than LW. We suggest that variations in soil properties between MF and LW are linked to a cascade of events involving the impacts of natural disturbances such as wildfires on forest regeneration that determines the vegetation

  2. Evolution of hillslope soils: The geomorphic theater and the geochemical play

    International Nuclear Information System (INIS)

    Yoo, Kyungsoo; Weinman, Beth; Mudd, Simon Marius; Hurst, Martin; Attal, Mikael; Maher, Kate

    2011-01-01

    Highlights: → We ask 'how and how fast do hillslope soils form as the landscape's morphology changes over time?'. → Over wide range of denudation rates, soil thicknesses do not vary significantly. → Colluvial soils with lower denudation rates (above the knick point) are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. → In the two steep hillslopes below the knickpoint, no systematic topgraphic trends were found for soil geochemistry. → Soils show increasing Zr enrichment in the downslope direction only in the hillslope above the knickpoint. - Abstract: How and how fast do hillslope soils form as the landscape's morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of ∼700 m to the plateau at an elevation of ∼1500 m. Hillslopes are significantly steeper below the knickpoint. The area's total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil erosion rates. From

  3. Evolution of hillslope soils: The geomorphic theater and the geochemical play

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Kyungsoo, E-mail: kyoo@umn.edu [Dept. of Soil, Water, and Climate, University of Minnesota, 439 Borlaug Hall, 1991 Upper Buford Circle, St. Paul, MN, 55108-6028 (United States); Weinman, Beth [Dept. of Soil, Water, and Climate, University of Minnesota, 439 Borlaug Hall, 1991 Upper Buford Circle, St. Paul, MN, 55108-6028 (United States); Mudd, Simon Marius; Hurst, Martin; Attal, Mikael [School of GeoSciences, University of Edinburgh, Drummond Street, Edinburgh EH8 9XP, Scotland (United Kingdom); Maher, Kate [Dept. of Geological and Environmental Sciences, Braun Hall 118, 450 Serra Mall, Bldg. 320, Stanford, CA 94305-2115 (United States)

    2011-06-15

    Highlights: > We ask 'how and how fast do hillslope soils form as the landscape's morphology changes over time?'. > Over wide range of denudation rates, soil thicknesses do not vary significantly. > Colluvial soils with lower denudation rates (above the knick point) are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. > In the two steep hillslopes below the knickpoint, no systematic topgraphic trends were found for soil geochemistry. > Soils show increasing Zr enrichment in the downslope direction only in the hillslope above the knickpoint. - Abstract: How and how fast do hillslope soils form as the landscape's morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of {approx}700 m to the plateau at an elevation of {approx}1500 m. Hillslopes are significantly steeper below the knickpoint. The area's total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil

  4. Identifying the role of historical anthropogenic activities on urban soils: geochemical impact and city scale mapping

    Science.gov (United States)

    Le Guern, Cecile; Baudouin, Vivien; Conil, Pierre

    2017-04-01

    Recently, European cities have faced several changes including deindustrialization and population increase. To limit urban sprawl, urban densification is preferred. It conducts to (re)develop available areas such as brownfields. Although these areas can be attractive for housing due to their location (in proximity to the city centre or to a riverside), their soils and subsoils are often contaminated. They are therefore potentially harmful for human health and the environment, and potentially costly to remediate. Currently, in case of contamination suspicion, depth geochemical characterization of urban soil and subsoil are carried out at site scale. Nevertheless, large redevelopment project occur at quarter to city scale. It appears therefore useful to acquire the preliminary knowledge on the structure and quality of soil and subsoils, as well as on the potential sources of contamination at quarter to city scale. In the frame of the Ile de Nantes (France) redevelopment project, we considered more particularly anthropogenic deposits and former industrial activities as main sources of contamination linked to human activities. To face the low traceability of the use of anthropogenic deposits and the lack of synthesis of former industrial activities, we carried out a historical study, synthetizing the information spread in numerous archive documents to spatialize the extent of the deposits and of the former activities. In addition we developed a typology of made grounds according to their contamination potential to build a 3D geological model with a geochemical coherence. In this frame, we valorized existing borehole descriptions coming mainly from pollution diagnosis and geotechnical studies. We also developed a methodology to define urban baseline compatibility levels using the existing analytical data at depth from pollution diagnosis. These data were previously gathered in a local geodatabase towards with borehole descriptions (more than 2000 borehole descriptions

  5. Geochemical markers of soil anthropogenic contaminants in polar scientific stations nearby (Antarctica, King George Island).

    Science.gov (United States)

    Prus, Wojciech; Fabiańska, Monika J; Łabno, Radosław

    2015-06-15

    The organic contamination of Antarctic soils and terrestrial sediments from nearby of five polar scientific stations on King George Island (Antarctica) was investigated. Gas chromatography-mass spectrometry (GC-MS) was applied to find composition of dichloromethane extracts of soil and terrestrial sediments. The presence of geochemical markers, such as n-alkanes, steranes, pentacyclic triterpenoids, and alkyl PAHs, their distribution types, and values of their ratios indicates the predominating source of organic fossil fuels and products of their refining rather than from the natural Antarctic environment. Fossil fuel-originated compounds well survived in conditions of Antarctic climate over long times thus enabling to characterize geochemical features of source fossil fuel identified as petroleum expelled from kerogen II of algal/bacterial origins deposited in sub-oxic conditions and being in the middle of catagenesis. Both microbial activity and water leaching play an important role in degradation of terrestrial oil spills in the Antarctica climate, and petroleum alteration occurs lowly over long periods of time. Synthetic anthropogenic compounds found in terrestrial Antarctica sediments included diisopropylnaphthalenes, products of their sulfonates degradation in paper combustion, and organophosporus compounds used as retardants and plasticizers. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. Determination of geochemical and anthropogenic uranium sources in soil and tailing

    International Nuclear Information System (INIS)

    Stojanovic, M.; Potpara, D.; Tesmanovic, L.

    2002-01-01

    The origin of uranium in soil (geochemical or anthropogenic) influences the degree of its accessibility to plants. Uranium originating from the geochemical sources is much less, if not quite inaccessible to plants. On the other hand uranium accumulated in soil as a result of anthropogenic activity (use of phosphate fertilisers, dissemination of flying ash from the thermal power plants, dissemination of mining wastes, disposal of nuclear waste and use of ammunition produced from depleted uranium) is most often present in forms much more accessible to plants. The aim of this work was to determine the efficiency of different methods of uranium extraction from soil (used to determine the 'mobile' and accessible contents) which could give the answer on the level of its accessibility to plants, and to determine uranium distribution in various chemical fractions by the method of fractional extraction.The applied method of fractional extraction is based on the idea that all metals form bonds of different strength with the solid phase of soil and such bonds can be completely broken under the effect of reagents such as: 0.1M CaCl 2 (pH - 7.0) for extraction of water-soluble and alternately adsorbed forms of metals; 1M CH 3 COONa (pH - 5.0) for the extraction of specifically adsorbed forms of metals bonded to carbonates; 0.04M hydroxylamine hydrochloride in 25% CH 3 COOH (pH - 3.0) for extraction of metals bonded to Fe and Mn oxide; 0.02M HNO 3 in 30% H 2 O 2 for metals bonded to organic matter. Structurally bonded forms of metals in silicates are determined from the difference of the total uranium content and sum of the metal quantity from the first four fractions. Determination of uranium content in samples was performed by the fluorimetric method. (author)

  7. Geochemical composition of permafrost-affected soils around the town Tiksi, Northern Yakutia, Russia

    Science.gov (United States)

    Antcibor, Iuliia; Eschenbach, Annette; Pfeiffer, Eva-Maria

    2014-05-01

    Northeastern Siberia represents an area remote from evident anthropogenic trace metal sources. However, a risk of airborne pollution by trace metals from anthropogenic sources connected to the settlements exists. The largest of these are the settlements Tiksi (71° 42' 55.6" N, 128° 48' 46.3" E) and Kyusyur (70° 45' 41.7" N, 127° 23' 04.7" E). The area of Tiksi is located between the Lena River and the Kharaulach River mouths. It covers parts of Primorsky Ridge and Kharaulach Mountains which are a part of the Verkhoyansk Range. The objective of this study was to investigate features of the spatial element distribution in representative landscape-geochemical units of the Tiksi area and to identify whether local pollution from the settlement takes place. The physical and chemical properties of soils were accessed at three sites located radially in the immediate vicinity to the town Tiksi and one control site remote 10 km south from the settlement. The elements measured were As, Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn in soils. Differences in the element content were found for various relief forms (depressions, slopes, and elevations). The coefficient of soil buffer capacity (Bf) for the surface soil horizons in depressions was the highest (Bf > 40 %) for the majority of elements indicating their intensive accumulation there. In the surface soil horizons of elevated landscape forms the coefficient, by contrast showed low to very low soil buffer capacity to accumulate metals (0 % acid-base barriers. No significant difference in metal distribution among studied sites was revealed, except for the western site which was characterized by the highest median Ni concentration. The data suggest that ecological impacts at the studied sites were low except for one site north to Tiksi where signs of local pollution probably as a result of local emissions of fuel and mining operations were detected. Keywords: Trace metals; Russian Arctic; Northeastern Siberia; Permafrost

  8. Geochemical and isotopic study of soils and waters from an Italian contaminated site: Agro Aversano (Campania)

    Science.gov (United States)

    Bove, M.A.; Ayuso, R.A.; de Vivo, B.; Lima, A.; Albanese, S.

    2011-01-01

    Lead isotope applications have been widely used in recent years in environmental studies conducted on different kinds of sampled media. In the present paper, Pb isotope ratios have been used to determine the sources of metal pollution in soils and waters in the Agro Aversano area. During three different sampling phases, a total of 113 surface soils (5-20. cm), 20 samples from 2 soil profiles (0-1. m), 11 stream waters and 4 groundwaters were collected. Major element concentrations in sampled media have been analyzed by the ICP-MS technique. Surface soils (20 samples), all soil profiles and all waters have been also analyzed for Pb isotope compositions by thermal ionization (TIMS). The geochemical data were assessed using statistic methods and cartographically elaborated in order to have a clear picture of the level of disturbance of the area. Pb isotopic data were studied to discriminate between anthropogenic and geologic sources. Our results show that As (5.6-25.6. mg/kg), Cu (9-677. mg/kg), Pb (22-193. mg/kg), Tl (0.53-3.62. mg/kg), V (26-142. mg/kg) and Zn (34-215. mg//kg) contents in analyzed soils, exceed the intervention limits fixed by the Italian Environmental Law for residential areas in some of the sampled sites, while intervention limit for industrial areas is exceeded only for Cu concentrations. Lead isotopic data, show that there is a high similarity between the ratios measured in the leached soil samples and those deriving from anthropic activities. This similarity with anthropogenic Pb is also evident in the ratios measured in both groundwater and stream water samples. ?? 2010 Elsevier B.V.

  9. Sensitivity analysis of tracer transport in variably saturated soils at USDA-ARS OPE3 field site

    Science.gov (United States)

    The objective of this study was to assess the effects of uncertainties in hydrologic and geochemical parameters on the results of simulations of the tracer transport in variably saturated soils at the USDA-ARS OPE3 field site. A tracer experiment with a pulse of KCL solution applied to an irrigatio...

  10. Geochemical dispersion of Si, Al, Fe, Mn, Na, K, Cu and Zn elements in soils and their use for characterization areas geochemically homogeneous

    International Nuclear Information System (INIS)

    Silva, W.R.L. da.

    1982-01-01

    Variations in the chemical composition of soils are used to characterize sub-areas geochemically - homogenous. The application of this methodology in a tropical humid region of accentuated topography constitute the principal objective of the present research. Samples of red latosols (Horizon B) developed over granite, sandstone and basalt occurring in the Central Granite Region of the Serra dos Carajas, Para State, Brazil were analized for the elements Si, Al, Fe, Mn, Na, K, Cu e Zn, by atomic absorption spectrophotometry. Based on the criterion of similarity in the chemical composition (Cluster Analysis, Factor Analysis) the soils were separeted in to different groups. The geographical distribution of the different groups permit the establishment of a close relationship between the different parent lithologies and their corresponding soils. (author)

  11. Combination of geo- pedo- and technogenic magnetic and geochemical signals in soil profiles - Diversification and its interpretation: A new approach.

    Science.gov (United States)

    Szuszkiewicz, Marcin; Łukasik, Adam; Magiera, Tadeusz; Mendakiewicz, Maria

    2016-07-01

    Magnetic and geochemical parameters of soils are determined with respect to geology, pedogenesis and anthropopression. Depending on local conditions these factors affect magnetic and geochemical signals simultaneously or in various configurations. We examined four type of soils (Entic Podzol, Eutric Cambisol, Humic Cambisol and Dystric Cambisol) developed on various bedrock (the Tumlin Sandstone, basaltoid, amphibolite and serpentinite, respectively). Our primary aim was to characterize the origin and diversification of the magnetic and geochemical signal in soils in order to distinguish the most reliable methods for correct interpretation of measured parameters. Presented data include selected parameters, both magnetic (mass magnetic susceptibility - χ, frequency-dependent magnetic susceptibility - χfd and thermomagnetic susceptibility measurement - TSM), and geochemical (selected heavy metal contents: Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn). Additionally, the enrichment factor (EF) and index of geoaccumulation (Igeo) were calculated. Our results suggest the following: (1) the χ/Fe ratio may be a reliable indicator for determining changes of magnetic signal origin in soil profiles; (2) magnetic and geochemical signals are simultaneously higher (the increment of χ and lead and zinc was noted) in topsoil horizons because of the deposition of technogenic magnetic particles (TMPs); (3) EF and Igeo evaluated for lead and zinc unambiguously showed anthropogenic influence in terms of increasing heavy metal contents in topsoil regardless of bedrock or soil type; (4) magnetic susceptibility measurements supported by TSM curves for soil samples of different genetic horizons are a helpful tool for interpreting the origin and nature of the mineral phases responsible for the changes of magnetic susceptibility values. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Geochemical analysis of leachates from cement/low-level radioactive waste/soil systems

    International Nuclear Information System (INIS)

    Criscenti, L.J.; Serne, R.J.

    1988-09-01

    Laboratory experiments were conducted as part of the Special Waste Form Lysimeters/endash/Arid Program. These experiments were conducted to investigate the performance of solidified low-level nuclear waste in a typical arid, near-surface disposal site, and to evaluate the ability of laboratory tests to predict leaching in actual field conditions. Batch leaching, soil adsorption column, and soil/waste form column experiments were conducted using Portland III cement waste forms containing boiling-water reactor evaporator concentrate and ion-exchange resin waste. In order to understand the reaction chemistry of the cement waste form/soil/ground-water system, the compositions of the leachates from the laboratory experiments were studied with the aid of the MINTEQ ion speciation/solubility and mass transfer computer code. The purpose of this report is to describe the changes in leachate composition that occur during the course of the experiments, to discuss the geochemical modeling results, and to explore the factors controlling the major element chemistry of these leachates. 18 refs., 84 figs., 14 tabs

  13. Soil geochemical factors regulate Cd accumulation by metal hyperaccumulating Noccaea caerulescens (J. Presl & C. Presl) F.K. Mey in field-contaminated soils.

    Science.gov (United States)

    Rosenfeld, Carla E; Chaney, Rufus L; Martínez, Carmen E

    2018-03-01

    Cadmium contamination in soil is a substantial global problem, and of significant concern due to high food-chain transfer. Cadmium hyperaccumulators are of particular interest because of their ability to tolerate and take up significant amounts of heavy metal pollution from soils. One particular plant, Noccaea caerulescens (formerly, Thlaspi caerulescens), has been extensively studied in terms of its capacity to accumulate heavy metals (specifically Zn and Cd), though these studies have primarily utilized hydroponic and metal-spiked model soil systems. We studied Cd and nutrient uptake by two N. caerulescens ecotypes, Prayon (Zn-only hyperaccumulator) and Ganges (Zn- and Cd-hyperaccumulator) in four long-term field-contaminated soils. Our data suggest that individual soil properties such as total soil Cd, Zn:Cd molar ratio, or soil pH do not accurately predict Cd uptake by hyperaccumulating plants. Additionally, total Cd uptake by the hyperaccumulating Ganges ecotype was substantially less than its physiological capacity, which is likely due to Cd-containing solid phases (primarily iron oxides) and pH that play an important role in regulating and limiting Cd solubility. Increased P accumulation in the Ganges leaves, and greater plant Fe accumulation from Cd-containing soils suggests that rhizosphere alterations via proton, and potentially organic acid, secretion may also play a role in nutrient and Cd acquisition by the plant roots. The current study highlights the role that soil geochemical factors play in influencing Cd uptake by hyperaccumulating plants. While these plants may have high physiological potential to accumulate metals from contaminated soils, individual soil geochemical factors and the plant-soil interactions in that soil will dictate the actual amount of phytoextractable metal. This underlines the need for site-specific understanding of metal-containing solid phases and geochemical properties of soils before undertaking phytoextraction efforts

  14. Late Holocene climate variability in the southwestern Mediterranean region: an integrated marine and terrestrial geochemical approach

    Directory of Open Access Journals (Sweden)

    C. Martín-Puertas

    2010-12-01

    Full Text Available A combination of marine (Alboran Sea cores, ODP 976 and TTR 300 G and terrestrial (Zoñar Lake, Andalucia, Spain geochemical proxies provides a high-resolution reconstruction of climate variability and human influence in the southwestern Mediterranean region for the last 4000 years at inter-centennial resolution. Proxies respond to changes in precipitation rather than temperature alone. Our combined terrestrial and marine archive documents a succession of dry and wet periods coherent with the North Atlantic climate signal. A dry period occurred prior to 2.7 cal ka BP – synchronously to the global aridity crisis of the third-millennium BC – and during the Medieval Climate Anomaly (1.4–0.7 cal ka BP. Wetter conditions prevailed from 2.7 to 1.4 cal ka BP. Hydrological signatures during the Little Ice Age are highly variable but consistent with more humidity than the Medieval Climate Anomaly. Additionally, Pb anomalies in sediments at the end of the Bronze Age suggest anthropogenic pollution earlier than the Roman Empire development in the Iberian Peninsula. The Late Holocene climate evolution of the in the study area confirms the see-saw pattern between the eastern and western Mediterranean regions and the higher influence of the North Atlantic dynamics in the western Mediterranean.

  15. The water-soluble fraction of potentially toxic elements in contaminated soils: relationships between ecotoxicity, solubility and geochemical reactivity.

    Science.gov (United States)

    Rocha, L; Rodrigues, S M; Lopes, I; Soares, A M V M; Duarte, A C; Pereira, E

    2011-09-01

    To better understand the impacts posed by soil contamination to aquatic ecosystems it is crucial to characterise the links between ecotoxicity, chemical availability and geochemical reactivity of potentially toxic elements (PTE's) in soils. We evaluated the adverse effects of water extracts obtained from soils contaminated by chemical industry and mining, using a test battery including organisms from different trophic levels (bacteria, algae and daphnids). These tests provided a quick assessment of the ecotoxicity of soils with respect to possible adverse effects on aquatic organisms although the ecotoxicological responses could be related to the solubility of PTE's only to a limited extent. The analysis of results of bioassays together with the chemical characterisation of water extracts provided additional relevant insight into the role of conductivity, pH, Al, Fe, and Mn of soil extracts on toxicity to organisms. Furthermore, an important conclusion of this study was that the toxicity of extracts to the aquatic organisms could also be related to the soil properties (pH, Org C and Fe(ox)) and to the reactivity of PTE's in soils which in fact control the soluble fraction of the contaminants. The combined assessment of ecotoxicity in water fractions, solubility and geochemical reactivity of PTE's in soils provided a more comprehensive understanding of the bioavailability of inorganic contaminants than ecotoxicological or chemical studies alone and can therefore be most useful for environmental risks assessment of contaminated soils. Copyright © 2011 Elsevier Ltd. All rights reserved.

  16. Testing single extraction methods and in vitro tests to assess the geochemical reactivity and human bioaccessibility of silver in urban soils amended with silver nanoparticles

    NARCIS (Netherlands)

    Cruz, N.; Rodrigues, S.M.; Tavares, D.; Monteiro, R.J.R.; Carvalho, L.; Trindade, T.; Duarte, A.C.; Pereira, E.; Romkens, Paul

    2015-01-01

    To assess if the geochemical reactivity and human bioaccessibility of silver nanoparticles (AgNPs) in soils can be determined by routine soil tests commonly applied to other metals in soil, colloidal Ag was introduced to five pots containing urban soils (equivalent to 6.8mgAgkg-1

  17. Geochemical cartography as a tool for assessing the degree of soil contamination with heavy metals in Poland

    Science.gov (United States)

    Szymon Borkowski, Andrzej; Kwiatkowska-Malina, Jolanta

    2016-04-01

    Spatial disposition of chemical elements including heavy metals in the soil environment is a very important information during preparation of the thematic maps for the environmental protection and/or spatial planning. This knowledge is also essential for the earth's surface and soil's monitoring, designation of areas requiring improvement including remediation. The main source of anthropogenic pollution of soil with heavy metals are industry related to the mining coal and liquid fuels, mining and metallurgy, chemical industry, energy production, waste management, agriculture and transport. The geochemical maps as a kind of specific thematic maps made on the basis of datasets obtained from the Polish Geological Institute's resources allow to get to know the spatial distribution of different chemical elements including heavy metals in soil. The results of the research carried out by the Polish Geological Institute showed strong contamination in some regions in Poland mainly with arsenic, cadmium, lead and nickel. For this reason it was the point to prepare geochemical maps showing contamination of soil with heavy metals, and determine main sources of contamination and zones where heavy metals concentration was higher than acceptable contents. It was also presented a summary map of soil contamination with heavy metals. Additionally, location of highly contaminated zones was compiled with predominant in those areas types of arable soils and then results were thoroughly analyzed. This information can provide a base for further detailed studies on the soil contamination with heavy metals.

  18. Effect of mineralogical, geochemical and biological properties on soils reflectance to assess temporal and spatial dynamics of BSCs in Sahelian ecosystems

    Science.gov (United States)

    Bourguignon, A.; Cerdan, O.; Desprats, J. F.; Marin, B.; Malam Issa, O.; Valentin, C.; Rajot, J. L.

    2012-04-01

    pressure on land use Soil surface disturbances due to the intensification of human activities. Spectral field and laboratory data were acquired in 2009, 2010 and 2011 with the FieldSpec Pro®. The spectra of soils with respect to different parameters are studied in details and their separability from BSCs, vegetation and vegetation residue as well are be analysed. First, the effect of the mineralogy and the geochemical variables on the soil reflectance properties is studied and then the feasibility to resolve some of these effects with satellite imagery (e. g., ASTER) will be tested in order to define the potential capability for identifying the locations of sensitive areas affected by soil degradation and appearance of BSCs.

  19. Geochemical Investigations In Soils And Waters Of Ischia Island (southern Italy)

    Science.gov (United States)

    Avino, R.; Capaldi, G.; Di Matteo, V.; Pece, R.

    The island of Ischia is localized in the Gulf of Naples and is a volcanic field belonging to the volcanic district of the Phlegraean Fields. It covers an area of about 42 Km2 and is characterized by a complex system of faults and fractures of tectonic and volcano- tectonic origin. The highest peak of the island is Mt Epomeo (787 m), situated in the central part of Ischia. The last eruption on this island took place in 1302 (Arso) and from that time the volcanic activity has reduced only to hydrothermal manifestations (fumaroles and thermal springs) localized especially along the faults that border Mt Epomeo. So the area around the Epomeo is an area of great interest for geochemical investigations, and in fact in this place high concentration of mercury, carbon dioxide and radon have been measured. In this work are presented the data of a study on the concentration of CO2 and mercury and of the activity of radon in the soils and in the waters of the island of Ischia. For these investigations 184 samples of soils have been collected and analyzed in laboratory to calculate the concentration of mercury using the Jerome 511 Mercury Vapor Analyzer. In the same sampling sites measurements of CO2 and of the activity of radon-222 in the soils have also been made using the Track- etch@ method. As regards the waters, a sampling of 50 wells localized all around the coast of the island has been carried out. In these waters measures of mercury and of the activity of some radioactive elements have been done. The measures of radioactivity has been carried out by gamma spectrometry with a HPE Ge detector. All the investigations (in soils and in waters) allow to have preliminary information about the concentrations of these investigated elements and will be a starting-point for a more detailed sampling in those place where anomalies have been found. This set of data can also help to better understand the degassing process of these elements through the principal structures of the

  20. Geochemical legacies and the future health of cities: A tale of two neurotoxins in urban soils

    Directory of Open Access Journals (Sweden)

    Gabriel M. Filippelli

    2015-07-01

    Full Text Available Abstract The past and future of cities are inextricably linked, a linkage that can be seen clearly in the long-term impacts of urban geochemical legacies. As loci of population as well as the means of employment and industry to support these populations, cities have a long history of co-locating contaminating practices and people, sometimes with negative implications for human health. Working at the intersection between environmental processes, communities, and human health is critical to grapple with environmental legacies and to support healthy, sustainable, and growing urban populations. An emerging area of environmental health research is to understand the impacts of chronic exposures and exposure mixtures—these impacts are poorly studied, yet may pose a significant threat to population health. Acute exposure to lead (Pb, a powerful neurotoxin to which children are particularly susceptible, has largely been eliminated in the U.S. and other countries through policy-based restrictions on leaded gasoline and lead-based paints. But the legacy of these sources remains in the form of surface soil Pb contamination, a common problem in cities and one that has only recently emerged as a widespread chronic exposure mechanism in cities. Some urban soils are also contaminated with another neurotoxin, mercury (Hg. The greatest human exposure to Hg is through fish consumption, so eating fish caught in urban areas presents risks for toxic Hg exposure. The potential double impact of chronic exposure to these two neurotoxins is pronounced in cities. Overall, there is a paradigmatic shift from reaction to and remediation of acute exposures towards a more nuanced understanding of the dynamic cycling of persistent environmental contaminants with resultant widespread and chronic exposure of inner-city dwellers, leading to chronic toxic illness and disability at substantial human and social cost.

  1. Topographic variability influences the carbon sequestration potential of arable soils

    DEFF Research Database (Denmark)

    Chirinda, Ngoni; Elsgaard, Lars; Thomsen, Ingrid Kaag

    2012-01-01

    There is presently limited knowledge on the influence of field spatial variability on the carbon (C) sink-source relationships in arable landscapes. This is accompanied by the fact that our understanding of soil profile C dynamics is also limited. This study aimed at investigating how spatial...... results indicated that variability across arable landscapes makes footslope soils both a larger sink of buried soil C and a bigger potential CO2 source than upslope soils....

  2. Geochemical speciation and dynamic of copper in tropical semi-arid soils exposed to metal-bearing mine wastes

    Energy Technology Data Exchange (ETDEWEB)

    Perlatti, Fabio [Department of Environmental Technology, National Department of Mineral Production – DNPM, Rua Dr. José Lourenço, 90560115-280 Fortaleza, CE (Brazil); Graduate Course of Ecology and Natural Resources, Department of Biology, Federal University of Ceará – UFC, Building 906, 60455-760, Fortaleza, CE (Brazil); Otero, Xosé Luis; Macias, Felipe [Department of Edaphology and Agricultural Chemistry, Faculty of Biology, University of Santiago de Compostela – USC, Rúa Lope Gómez de Marzoa, s/n. Campus sur, 15782 Santiago de Compostela (Spain); Ferreira, Tiago Osório, E-mail: toferreira@usp.br [Department of Soil Science, University of São Paulo (ESALQ/USP), Av. Pádua Dias, 11, 13418-900, Piracicaba, SP (Brazil); Graduate Course of Ecology and Natural Resources, Department of Biology, Federal University of Ceará – UFC, Building 906, 60455-760, Fortaleza, CE (Brazil)

    2014-12-01

    The potentially hazardous effects of rock wastes disposed at open pit in three different areas (Pr: Ore processing; Wr: Waste rock and Bd: Border) of an abandoned copper mine were evaluated in this study, with emphasis on acid drainage generation, metal contamination and copper geochemical dynamics in soils. Samples of waste rock were analyzed by Energy dispersive X-ray fluorescence (XRF), scanning electron microscopy with microanalysis (SEM-EDS) and X-ray diffraction (XRD). Soil samples were analyzed to determine the total metal contents (XRF), mineralogy (XRD), pH (H2O and H2O2), organic and inorganic carbon, % of total N, S and P, particle size, and a sequential extraction procedure was used to identify the different copper fractions. As a result of the prevalence of carbonates over sulphides in the wastes, the soil pH remained close to neutral, with absence of acid mine drainage. The geochemical interaction between these mineral phases seems to be the main mechanism to release Cu{sup 2+} ions. Total Cu in soils from the Pr area reached 11,180 mg.kg{sup −1}, while in Wr and Bd areas the values reached, on average, 4683 and 1086 mg.kg{sup −1}, respectively, indicating a very high level of soil contamination. In the Pr and Wr, the Cu was mainly associated with carbonates and amorphous iron oxides. In the Bd areas, the presence of vegetation has influenced the geochemical behavior of copper by increasing the dissolution of carbonates, affecting the buffer capacity of soils against sulphide oxidation, reducing the pH levels and enhancing the proportion of exchangeable and organic bound Cu. The present findings show that the use of plants or organic amendments in mine sites with high concentration of Cu carbonate-containing wastes should be viewed with caution, as the practice may enhance the mobilization of copper to the environment due to an increase in the rate of carbonates dissolution. - Highlights: • The hazardous effects of mine waste rocks at

  3. Geochemical behaviour of rare earths in Vitis vinifera grafted onto different rootstocks and growing on several soils

    International Nuclear Information System (INIS)

    Censi, P.; Saiano, F.; Pisciotta, A.; Tuzzolino, N.

    2014-01-01

    The geochemical behaviour of lanthanides and yttrium (Rare Earth Elements, REEs) has been investigated mainly in geological systems where these elements represent the best proxies of processes involving the occurrence of an interface between different media. This behaviour is assessed according to features recorded in sequences of REE concentrations along the REE series normalised with respect to a reference material. In this study, the geochemical behaviour of REE was investigated in different parts of Vitis vinifera specimens grown off-soil, on soils of different nature and grafted onto several rootstocks in order to evaluate effects induced by these changes. The results indicated that roots are the plant organs where REEs are preferentially concentrated, in particular elements from Sm to Ho (middle REE, MREE) whereas Eu enrichments occur in aerial parts. The geochemical behaviour of REE suggests that MREE enrichments in roots are due to preferential MREE interactions with biological membranes or to surface complexation with newly formed phosphates. Eu-positive anomalies suggest that Eu 3+ can form stable organic complexes in place of Ca 2+ in several biological processes in xylem fluids. The possibility that Eu mobility in these fluids can be enhanced by its reductive speciation as Eu 2+ cannot be ruled out. The assessment of the geochemical behaviour of REE according to the theory of the Tetrad Effect carried out confirms that REEs coming from soil are scavenged onto root tissues or mineral surfaces whereas their behaviour in aerial parts of V. vinifera is driven by dissolved complexation. - Highlights: • REE behaviour is driven by scavenging onto authigenic solids or membranes in roots. • REE behaviour is driven by dissolved complexation in aerial plant parts. • Positive Eu anomalies are a consequence of the REE translocation by xylem fluids. • Significant REE tetrad effects are observed in Vitis vinifera plants

  4. Descriptive statistics and spatial distributions of geochemical variables associated with manganese oxide-rich phases in the northern Pacific

    Science.gov (United States)

    Botbol, Joseph Moses; Evenden, Gerald Ian

    1989-01-01

    Tables, graphs, and maps are used to portray the frequency characteristics and spatial distribution of manganese oxide-rich phase geochemical data, to characterize the northern Pacific in terms of publicly available nodule geochemical data, and to develop data portrayal methods that will facilitate data analysis. Source data are a subset of the Scripps Institute of Oceanography's Sediment Data Bank. The study area is bounded by 0° N., 40° N., 120° E., and 100° W. and is arbitrarily subdivided into 14-20°x20° geographic subregions. Frequency distributions of trace metals characterized in the original raw data are graphed as ogives, and salient parameters are tabulated. All variables are transformed to enrichment values relative to median concentration within their host subregions. Scatter plots of all pairs of original variables and their enrichment transforms are provided as an aid to the interpretation of correlations between variables. Gridded spatial distributions of all variables are portrayed as gray-scale maps. The use of tables and graphs to portray frequency statistics and gray-scale maps to portray spatial distributions is an effective way to prepare for and facilitate multivariate data analysis.

  5. Soil erodibility variability in laboratory and field rainfall simulations

    Science.gov (United States)

    Szabó, Boglárka; Szabó, Judit; Jakab, Gergely; Centeri, Csaba; Szalai, Zoltán

    2017-04-01

    Rainfall simulation experiments are the most common way to observe and to model the soil erosion processes in in situ and ex situ circumstances. During modelling soil erosion, one of the most important factors are the annual soil loss and the soil erodibility which represent the effect of soil properties on soil loss and the soil resistance against water erosion. The amount of runoff and soil loss can differ in case of the same soil type, while it's characteristics determine the soil erodibility factor. This leads to uncertainties regarding soil erodibility. Soil loss and soil erodibility were examined with the investigation of the same soil under laboratory and field conditions with rainfall simulators. The comparative measurement was carried out in a laboratory on 0,5 m2, and in the field (Shower Power-02) on 6 m2 plot size where the applied slope angles were 5% and 12% with 30 and 90 mm/h rainfall intensity. The main idea was to examine and compare the soil erodibility and its variability coming from the same soil, but different rainfall simulator type. The applied model was the USLE, nomograph and other equations which concern single rainfall events. The given results show differences between the field and laboratory experiments and between the different calculations. Concerning for the whole rainfall events runoff and soil loss, were significantly higher at the laboratory experiments, which affected the soil erodibility values too. The given differences can originate from the plot size. The main research questions are that: How should we handle the soil erodibility factors and its significant variability? What is the best solution for soil erodibility determination?

  6. Geochemical controls on the composition of soil pore waters beneath a mixed waste disposal site in the unsaturated zone

    International Nuclear Information System (INIS)

    Rawson, S.A.; Hubbell, J.M.

    1989-01-01

    Soil pore waters are collected routinely to monitor a thick unsaturated zone that separates a mixed waste disposal site containing transuranic and low-level radioactive wastes from the Snake River Plain aquifer. The chemistry of the soil pore waters has been studied to evaluate the possible control on the water composition by mineral equilibria and determine the extent, if any, of migration of radionuclides from the disposal site. Geochemical codes were used to perform speciation calculations for the waters. The results of speciation calculations suggest that the installation of the lysimeters affects the observed silica contents of the soil pore waters. The results also establish those chemical parameters that are controlled by secondary mineral precipitation. 15 refs., 6 figs., 1 tab

  7. Effect of Particle Size and Soil Compaction on Gas Transport Parameters in Variably Saturated, Sandy Soils

    DEFF Research Database (Denmark)

    Hamamoto, Shoichiro; Møldrup, Per; Kawamoto, Ken

    2009-01-01

    The soil gas diffusion coefficient (Dp) and air permeability (ka) and their dependency on soil air content ( ) control gas diffusion and advection in soils. This study investigated the effects of average particle size (D50) and dry bulk density ( b) on Dp and ka for six sandy soils under variably...

  8. The spatial relationship between human activities and C, N, P, S in soil based on landscape geochemical interpretation.

    Science.gov (United States)

    Yu, Huan; He, Zheng-Wei; Kong, Bo; Weng, Zhong-Yin; Shi, Ze-Ming

    2016-04-01

    The development and formation of chemical elements in soil are affected not only by parent material, climate, biology, and topology factors, but also by human activities. As the main elements supporting life on earth system, the C, N, P, S cycles in soil have been altered by human activity through land-use change, agricultural intensification, and use of fossil fuels. The present study attempts to analyze whether and how a connection can be made between macroscopical control and microcosmic analysis, to estimate the impacts of human activities on C, N, P, S elements in soil, and to determine a way to describe the spatial relationship between C, N, P, S in soil and human activities, by means of landscape geochemical theories and methods. In addition, the disturbances of human activities on C, N, P, S are explored through the analysis of the spatial relationship between human disturbed landscapes and element anomalies, thereby determining the diversified rules of the effects. The study results show that the rules of different landscapes influencing C, N, P, S elements are diversified, and that the C element is closely related to city landscapes; furthermore, the elements N, P, and S are shown to be closely related to river landscapes; the relationships between mine landscapes and the elements C, N, P, S are apparent; the relationships between the elements C, N, P, S and road landscapes are quite close, which shows that road landscapes have significant effects on these elements. Therefore, the conclusion is drawn that the response mechanism analysis of human disturbance and soil chemical element aggregation is feasible, based on the landscape geochemical theories and methods. The spatial information techniques, such as remote sensing and geographic information systems, are effective for research on soil element migration.

  9. Contemporaneous deposition of phyllosilicates and sulfates: Using Australian acidic saline lake deposits to describe geochemical variability on Mars

    Science.gov (United States)

    Baldridge, A.M.; Hook, S.J.; Crowley, J.K.; Marion, G.M.; Kargel, J.S.; Michalski, J.L.; Thomson, B.J.; de Souza, Filho C.R.; Bridges, N.T.; Brown, A.J.

    2009-01-01

    Studies of the origin of the Martian sulfate and phyllosilicate deposits have led to the hypothesis that there was a marked, global-scale change in the Mars environment from circum-neutral pH aqueous alteration in the Noachian to an acidic evaporitic system in the late Noachian to Hesperian. However, terrestrial studies suggest that two different geochemical systems need not be invoked to explain such geochemical variation.Western Australian acidic playa lakes have large pH differences separated vertically and laterally by only a few tens of meters, demonstrating how highly variable chemistries can coexist over short distances in natural environments. We suggest diverse and variable Martian aqueous environments where the coetaneous formation of phyllosilicates and sulfates at the Australian sites are analogs for regions where phyllosilicates and sulfates coexist on Mars. In these systems, Fe and alkali earth phyllosilicates represent deep facies associated with upwelling neutral to alkaline groundwater, whereas aluminous phyllosilicates and sulfates represent near-surface evaporitic facies formed from more acidic brines. Copyright 2009 by the American Geophysical Union.

  10. Geochemical distribution of polycyclic aromatic hydrocarbons in soils and sediments of El-Tabbin, Egypt.

    Science.gov (United States)

    Havelcová, Martina; Melegy, Ahmed; Rapant, Stanislav

    2014-01-01

    Polycyclic aromatic hydrocarbons (PAHs) were extracted from 30 samples (24 soils and 6 stream sediments) collected in El-Tabbin area in the southern part of Greater Cairo, Egypt. Isopleth maps of PAHs clarified the regional variability and identified the most affected regions in the area suffering from high pollution. The total PAH concentrations were 53.4-5558.0 ng g(-1) in the sample extracts. The highest values were found in a soil sample near a coke factory, with the highest concentration of single PAHs, which were 1064.8 ng g(-1) of fluoranthene and 1286.4 ng g(-1) of phenanthrene. The calculated ratios and indexes allowed to elucidate origin of the organic compounds and to identify emission sources. The overall molecular patterns are signatures of pyrolysis of fossil fuels and biomass. Petrogenic contamination was recognised in the sediment samples due to petroleum products deliveries from ships. Also perylene was prominent especially in samples of the River Nile sediments as a diagenetic product of fungi. Other detailed information on petrogenic sources was provided by analysis of alkanes and calculation of alkane ratios. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. Geochemical behavior of radionuclides and heavy metals in soils from Corumbatai River basin (SP), Brazil; Comportamento geoquimico de radionuclideos e metais pesados em solos da bacia do Rio Corumbatai (SP)

    Energy Technology Data Exchange (ETDEWEB)

    Conceicao, Fabiano Tomazini da

    2004-07-01

    The purpose of this research was to study the geochemical behavior of radionuclides and heavy metals in soils of agricultural use at Corumbatai River basin (SP). The natural concentration and variability in sedimentary rocks at Corumbatai river basin follow the trend Ca > Mg > K > Na, with the concentration of heavy metals and radionuclides. The distribution of exposure rate in soils shows the occurrence of higher values towards south of the Corumbatai river basin, region where are applied phosphate fertilizers, amendments and 'vinhaca' in sugar cane crops. Heavy metals and radionuclides incorporated in phosphate fertilizers and amendments are annually added during the fertilization process in the sugar cane crops, but if they are utilized in accordance with the recommended rate, they do not rise the concentration levels in soils up to hazards levels. Thus, they are lower transferred from soils to sugar cane at Corumbatai river basin, not offering hazard to the ecosystem and animal or human health. (author)

  12. Geochemical behavior of radionuclides and heavy metals in soils from Corumbatai River basin (SP), Brazil; Comportamento geoquimico de radionuclideos e metais pesados em solos da bacia do Rio Corumbatai (SP)

    Energy Technology Data Exchange (ETDEWEB)

    Conceicao, Fabiano Tomazini da

    2004-07-01

    The purpose of this research was to study the geochemical behavior of radionuclides and heavy metals in soils of agricultural use at Corumbatai River basin (SP). The natural concentration and variability in sedimentary rocks at Corumbatai river basin follow the trend Ca > Mg > K > Na, with the concentration of heavy metals and radionuclides. The distribution of exposure rate in soils shows the occurrence of higher values towards south of the Corumbatai river basin, region where are applied phosphate fertilizers, amendments and 'vinhaca' in sugar cane crops. Heavy metals and radionuclides incorporated in phosphate fertilizers and amendments are annually added during the fertilization process in the sugar cane crops, but if they are utilized in accordance with the recommended rate, they do not rise the concentration levels in soils up to hazards levels. Thus, they are lower transferred from soils to sugar cane at Corumbatai river basin, not offering hazard to the ecosystem and animal or human health. (author)

  13. Geochemical assessment of light gaseous hydrocarbons in near-surface soils of Kutch-Saurashtra: Implication for hydrocarbon prospects

    Science.gov (United States)

    Rao, P. Lakshmi Srinivasa; Madhavi, T.; Srinu, D.; Kalpana, M. S.; Patil, D. J.; Dayal, A. M.

    2013-02-01

    Light hydrocarbons in soil have been used as direct indicators in geochemical hydrocarbon exploration, which remains an unconventional path in the petroleum industry. The occurrence of adsorbed soil gases, methane and heavier homologues were recorded in the near-surface soil samples collected from Kutch-Saurashtra, India. Soil gas alkanes were interpreted to be derived from deep-seated hydrocarbon sources and have migrated to the surface through structural discontinuities. The source of hydrocarbons is assessed to be thermogenic and could have been primarily derived from humic organic matter with partial contribution from sapropelic matter. Gas chromatographic analyses of hydrocarbons desorbed from soil samples through acid extraction technique showed the presence of methane through n-butane and the observed concentrations (in ppb) vary from: methane (C1) from 4-291, ethane (C2) from 0-84, propane (C3) from 0-37, i-butane (iC4) from 0-5 and n-butane (nC4) from 0-4. Carbon isotopes measured for methane and ethane by GC-C-IRMS, range between -42.9‰ to -13.3‰ (Pee Dee Belemnite - PDB) and -21.2‰ to -12.4‰ (PDB), respectively. The increased occurrence of hydrocarbons in the areas near Anjar of Kutch and the area south to Rajkot of Saurashtra signifies the area potential for oil and gas.

  14. Defining and modeling the soil geochemical background of heavy metals from the Hengshi River watershed (southern China): Integrating EDA, stochastic simulation and magnetic parameters

    International Nuclear Information System (INIS)

    Zhou Xu; Xia Beicheng

    2010-01-01

    It is crucial to separate the soil geochemical background concentrations from anthropogenic anomalies and to provide a realistic environmental geochemical map honoring the fluctuations in original data. This study was carried out in the Hengshi River watershed, north of Guangdong, China and the method proposed combined exploratory data analysis (EDA), sequential indicator co-simulation (SIcS) and the ratio of isothermal remnant magnetization (S 100 = -IRM -100mT /SIRM). The results showed that this is robust procedure for defining and mapping soil geochemical background concentrations in mineralized regions. The rock magnetic parameter helps to improve the mapping process by distinguishing anthropogenic influences. In this study, the geochemical backgrounds for four potentially toxic heavy metals (copper 200 mg/kg; zinc 230 mg/kg; lead 190 mg/kg and cadmium 1.85 mg/kg) Cu, Zn and Cd exceeded the soil Grade II limits (for pH < 6.5) from the Chinese Environmental Quality Standard for Soils (GB 15618-1995) (EQSS) which are 100, 200, 250 and 0.3 mg/kg for Cu, Zn, Pb and Cd, respectively. In particular, the geochemical background level for Cd exceeds standard six times. Results suggest that local public health is at high-risk along the riparian region of the Hengshi River, although the watershed ecosystem has not been severely disturbed.

  15. Spatial variability of physical properties of tropical soil

    International Nuclear Information System (INIS)

    Reichardt, K.; Libardi, P.L.; Queiroz, S.V.; Grohmann, F.

    1976-04-01

    A basic study with objectives of improving the use of soil and water resources under a particular condition and of developing means for controlling the dynamics of soil-water movement are presented. Special emphasis is given to the variability in space of geometric soil properties such as bulk density, particle density and texture in order to make it possible to define representative means which ideed will be usable to describe the movement of water and of salt in the entire field

  16. Chemical composition and Zn bioavailability of the soil solution extracted from Zn amended variable charge soils.

    Science.gov (United States)

    Zampella, Mariavittoria; Adamo, Paola

    2010-01-01

    A study on variable charge soils (volcanic Italian and podzolic Scottish soils) was performed to investigate the influence of soil properties on the chemical composition of soil solution. Zinc speciation, bioavailability and toxicity in the soil solution were examined. The soils were spiked with increasing amounts of Zn (0, 100, 200, 400 and 1000 mg/kg) and the soil solutions were extracted using rhizon soil moisture samplers. The pH, total organic carbon (TOC), base cations, anions, total Zn and free Zn2+ in soil solution were analysed. A rapid bioassay with the luminescent bacterium Escherichia coli HB101 pUCD607 was performed to assess Zn toxicity. The influence of soil type and Zn treatments on the chemical composition of soil solution and on Zn toxicity was considered and discussed. Different trends of total and free Zn concentrations, base cations desorption and luminescence of E. coli HB101 pUCD607 were observed. The soil solution extracted from the volcanic soils had very low total and free Zn concentrations and showed specific Zn2+/Ca2+ exchange. The soil solution from the podzolic soil had much higher total and free Zn concentrations and showed no evidence of specific Zn2+/Ca2+ exchange. In comparison with the subalkaline volcanic soils, the acidic podzol showed enhanced levels of toxic free Zn2+ and consequently stronger effects on E. coli viability.

  17. Geochemical Investigation of Selected Elements in an Agricultural Soil: Case Study in Sumani Watershed West Sumatera in Indonesia

    Directory of Open Access Journals (Sweden)

    Aflizar

    2016-01-01

    Full Text Available This paper presents the geochemical study of agricultural soil and river sediments along Sumani watershed, West Sumatra in Indonesia. We examined the distribution and abundances of 16 elements (Pb, Zn, Cu, Ni, Cr,V, Sr, Rb, Ce, Th, Zr, Si, Ti, Fe Ca, and P in vegetable soil, sawah soil =and river sediment sample, to evaluate the factors controlling their abundances, possible sources, and environmental implications. Average concentrations of Pb, Zn, Cu, Ni, Cr,V, Sr, Rb, Ce, Th, Zr at vegetable (1 soil were 38, 88.3, 38.7, 3, 8, 101, 96, 98, 87, 31 and 218 mg kg-1 , 26, 39.05, 8.8, 13.5, 31, 231.5, 37, 19, 78, 16 and 303.5 mg kg-1 at sawah soil (3, 4 and 30, 61.6, 35.7, 9, 22, 294, 65, 12, 78, 14 and 232 mg kg-1 at river sediment (2, respectively. The concentration of Pb, Rb, Th and Zr at upland vegetables, V and Zr at sawah soil and river sediment were mostly two time Sumatra BCSCST or BCC in several samples. Enrichment factor values showed low to moderate enrichment of Pb, Zn, Cu, Rb, Ce and Zr, whereas Th showed significant contamination at vegetables soil, suggesting contributions from anthropogenic sources. Anthropogenic contributions of most metals mainly originate from natural processes. However, Pb, Ce, Th and Zr ranges of 527–108, 41-89, 66-117 and 35-100%, respectively, at Vegetable and sawah soil and river sediment confirm their anthropogenic contribution. Factor analysis and correlation matrices suggested that elevated metal concentrations at agricultural soil in Sumani watershed might be controlled by pH, CEC, Fe-oxy-hydroxides. Deposition of metals at vegetable and sawah soil and river sediment might be controlled by non-ferrous metal (i.e., aluminosilicates, sediment grain size, or source rock composition (andesite, alluvial fan, undifferentiated volcanic material, granite and gneiss.

  18. Identification of hydrologic and geochemical pathways using high frequency sampling, REE aqueous sampling and soil characterization at Koiliaris Critical Zone Observatory, Crete

    Energy Technology Data Exchange (ETDEWEB)

    Moraetis, Daniel, E-mail: moraetis@mred.tuc.gr [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece); Stamati, Fotini; Kotronakis, Manolis; Fragia, Tasoula; Paranychnianakis, Nikolaos; Nikolaidis, Nikolaos P. [Department of Environmental Engineering, Technical University of Crete, 73100 Chania (Greece)

    2011-06-15

    Highlights: > Identification of hydrological and geochemical pathways within a complex watershed. > Water increased N-NO{sub 3} concentration and E.C. values during flash flood events. > Soil degradation and impact on water infiltration within the Koiliaris watershed. > Analysis of Rare Earth Elements in water bodies for identification of karstic water. - Abstract: Koiliaris River watershed is a Critical Zone Observatory that represents severely degraded soils due to intensive agricultural activities and biophysical factors. It has typical Mediterranean soils under the imminent threat of desertification which is expected to intensify due to projected climate change. High frequency hydro-chemical monitoring with targeted sampling for Rare Earth Elements (REE) analysis of different water bodies and geochemical characterization of soils were used for the identification of hydrologic and geochemical pathways. The high frequency monitoring of water chemical data highlighted the chemical alterations of water in Koiliaris River during flash flood events. Soil physical and chemical characterization surveys were used to identify erodibility patterns within the watershed and the influence of soils on surface and ground water chemistry. The methodology presented can be used to identify the impacts of degraded soils to surface and ground water quality as well as in the design of methods to minimize the impacts of land use practices.

  19. Characterization of soil water content variability and soil texture using GPR groundwave techniques

    Energy Technology Data Exchange (ETDEWEB)

    Grote, K.; Anger, C.; Kelly, B.; Hubbard, S.; Rubin, Y.

    2010-08-15

    Accurate characterization of near-surface soil water content is vital for guiding agricultural management decisions and for reducing the potential negative environmental impacts of agriculture. Characterizing the near-surface soil water content can be difficult, as this parameter is often both spatially and temporally variable, and obtaining sufficient measurements to describe the heterogeneity can be prohibitively expensive. Understanding the spatial correlation of near-surface soil water content can help optimize data acquisition and improve understanding of the processes controlling soil water content at the field scale. In this study, ground penetrating radar (GPR) methods were used to characterize the spatial correlation of water content in a three acre field as a function of sampling depth, season, vegetation, and soil texture. GPR data were acquired with 450 MHz and 900 MHz antennas, and measurements of the GPR groundwave were used to estimate soil water content at four different times. Additional water content estimates were obtained using time domain reflectometry measurements, and soil texture measurements were also acquired. Variograms were calculated for each set of measurements, and comparison of these variograms showed that the horizontal spatial correlation was greater for deeper water content measurements than for shallower measurements. Precipitation and irrigation were both shown to increase the spatial variability of water content, while shallowly-rooted vegetation decreased the variability. Comparison of the variograms of water content and soil texture showed that soil texture generally had greater small-scale spatial correlation than water content, and that the variability of water content in deeper soil layers was more closely correlated to soil texture than were shallower water content measurements. Lastly, cross-variograms of soil texture and water content were calculated, and co-kriging of water content estimates and soil texture

  20. THE SOIL-GEOCHEMICAL SUBSTANTIATION PRINCIPLES OF AN ESTIMATION OF HALOMORPHIC SOIL WITH THE PURPOSES OF FOREST MELIORATION

    Directory of Open Access Journals (Sweden)

    Gheorghe Jigau

    2006-10-01

    Full Text Available In Prut - Dniester interfluves the halomorphic soil meets practically in all soilgeographical areas and is characterized by a significant genetic variety. To them concern as interzones types sodium soil, saline soil and halomorphic soil of the large and small river valleys, and alkalized and solonchak genuses of zones chernozem’s soil. They are distributed both in flood land of the rivers, and outside of flood land. In outside flood lands they form large missives. On an outside flood lands territories they form island sites with the small area dated to an exit on a surface of salt Neogene clays or to territories testing constant or periodic humidifying more often.

  1. Pedogenesis, geochemical forms of heavy metals, and artifact weathering in an urban soil chronosequence, Detroit, Michigan

    Energy Technology Data Exchange (ETDEWEB)

    Howard, Jeffrey L., E-mail: jhoward@wayne.edu [Department of Geology, Wayne State University, Detroit, MI 48202 (United States); Olszewska, Dorota [Department of Geology, Wayne State University, Detroit, MI 48202 (United States)

    2011-03-15

    An urban soil chronosequence in downtown Detroit, MI was studied to determine the effects of time on pedogenesis and heavy metal sequestration. The soils developed in fill derived from mixed sandy and clayey diamicton parent materials on a level late Pleistocene lakebed plain under grass vegetation in a humid-temperate (mesic) climate. The chronosequence is comprised of soils in vacant lots (12 and 44 years old) and parks (96 and 120 years old), all located within 100 m of a roadway. An A-horizon 16 cm thick with 2% organic matter has developed after only 12 years of pedogenesis. The 12 year-old soil shows accelerated weathering of iron (e.g. nails) and cement artifacts attributed to corrosion by excess soluble salts of uncertain origin. Carbonate and Fe-oxide are immobilizing agents for heavy metals, hence it is recommended that drywall, plaster, cement and iron artifacts be left in soils at brownfield sites for their ameliorating effects. - Research highlights: > An A horizon has developed in these urban soils after only 12 years of pedogenesis. > Iron and cement artifacts have undergone accelerated weathering due to deicing salts. > One soil is contaminated by lead derived from weathered paint. > Artifact weathering can have ameliorating effects on urban soils contaminated by heavy metals. - Weathering of artifacts can have ameliorating effects on heavy metal-polluted soils at brownfield sites.

  2. Pedogenesis, geochemical forms of heavy metals, and artifact weathering in an urban soil chronosequence, Detroit, Michigan

    International Nuclear Information System (INIS)

    Howard, Jeffrey L.; Olszewska, Dorota

    2011-01-01

    An urban soil chronosequence in downtown Detroit, MI was studied to determine the effects of time on pedogenesis and heavy metal sequestration. The soils developed in fill derived from mixed sandy and clayey diamicton parent materials on a level late Pleistocene lakebed plain under grass vegetation in a humid-temperate (mesic) climate. The chronosequence is comprised of soils in vacant lots (12 and 44 years old) and parks (96 and 120 years old), all located within 100 m of a roadway. An A-horizon 16 cm thick with 2% organic matter has developed after only 12 years of pedogenesis. The 12 year-old soil shows accelerated weathering of iron (e.g. nails) and cement artifacts attributed to corrosion by excess soluble salts of uncertain origin. Carbonate and Fe-oxide are immobilizing agents for heavy metals, hence it is recommended that drywall, plaster, cement and iron artifacts be left in soils at brownfield sites for their ameliorating effects. - Research highlights: → An A horizon has developed in these urban soils after only 12 years of pedogenesis. → Iron and cement artifacts have undergone accelerated weathering due to deicing salts. → One soil is contaminated by lead derived from weathered paint. → Artifact weathering can have ameliorating effects on urban soils contaminated by heavy metals. - Weathering of artifacts can have ameliorating effects on heavy metal-polluted soils at brownfield sites.

  3. Geochemical characterization of arsenic-rich coal-combustion ashes buried under agricultural soils and the release of arsenic

    International Nuclear Information System (INIS)

    Veselská, Veronika; Majzlan, Juraj; Hiller, Edgar; Peťková, Katarína; Jurkovič, Ľubomír; Ďurža, Ondrej; Voleková-Lalinská, Bronislava

    2013-01-01

    Highlights: ► Sources, mineralogy and mobility of As in coal-combustion ashes were investigated. ► After a dam failure in 1965, the spilled ashes were buried under agricultural soils. ► Primary carriers of As within coal-combustion ashes are aluminosilicate glasses. ► The most probable secondary carriers of labile As are oxyhydroxides of Si, Al, and Fe. ► Arsenic stored in ashes is a long-term contamination source for the environment. - Abstract: A combination of geochemical and mineralogical methods was used to determine the concentrations, mobility, and sources of As in coal-combustion ashes and soils in the vicinity of a thermal power plant at Nováky, central Slovakia. Fresh lagooned ash, ashes buried under agricultural soils for 45 a, and the overlying soils, contain high concentrations of As ranging from 61 to 1535 mg/kg. There is no differences in the water extractable percentages of As between the fresh lagooned ash and buried ashes, which range from 3.80% to 6.70% of the total As. This small amount of As may perhaps reside on the surfaces of the ash particles, as postulated in the earlier literature, but no evidence was found to support this claim. Electron microprobe analyses show that the dominant primary As carriers are the aluminosilicate glasses enriched in Ca and Fe. The acid NH 4 + -oxalate extraction hints that the oxyhydroxides of Si, Al, and Fe are the most probable secondary carriers of labile As. The X-ray absorption spectroscopy (XAS) analyses show that As in the lagooned and buried ashes occurs mostly as As(V). The long-term burial of the coal-combustion ash under agricultural soil did not cause any major change of its chemical composition or As lability compared to the fresh lagooned ash

  4. Role of environmental variables on radon concentration in soil

    International Nuclear Information System (INIS)

    Climent, H.; Bakalowicz, M.; Monnin, M.

    1998-01-01

    In the frame of an European project, radon concentrations in soil and measurements of environmental variables such as the nature of the soil or climatic variables were monitored. The data have been analysed by time-series analysis methods, i.e. Correlation and Spectrum Analysis, to point out relations between radon concentrations and some environmental variables. This approach is a compromise between direct observation and modelling. The observation of the rough time series is unable to point out the relation between radon concentrations and an environmental variable because of the overlapping of the influences of several variables, and the time delay induced by the medium. The Cross Spectrum function between the time series of radon and of an environmental variable describes the nature of the relation and gives the response time in the case of a cause to effect relation. It requires the only hypothesis that the environmental variable is the input function and radon concentration the output function. This analysis is an important preliminary study for modelling. By that way the importance of soil nature has been pointed out. The internal variables of the medium (permeability, porosity) appear to restrain the influence of the environmental variables such as humidity, temperature or atmospheric pressure. (author)

  5. Variability of Measured Runoff and Soil Loss from Field Plots

    Directory of Open Access Journals (Sweden)

    F. Asadzadeh

    2016-02-01

    Full Text Available Introduction: Field plots are widely used in studies related to the measurements of soil loss and modeling of erosion processes. Research efforts are needed to investigate factors affecting the data quality of plots. Spatial scale or size of plots is one of these factors which directly affects measuring runoff and soil loss by means of field plots. The effect of plot size on measured runoff or soil loss from natural plots is known as plot scale effect. On the other hand, variability of runoff and sediment yield from replicated filed plots is a main source of uncertainty in measurement of erosion from plots which should be considered in plot data interpretation processes. Therefore, there is a demand for knowledge of soil erosion processes occurring in plots of different sizes and of factors that determine natural variability, as a basis for obtaining soil loss data of good quality. This study was carried out to investigate the combined effects of these two factors by measurement of runoff and soil loss from replicated plots with different sizes. Materials and Methods: In order to evaluate the variability of runoff and soil loss data seven plots, differing in width and length, were constructed in a uniform slope of 9% at three replicates at Koohin Research Station in Qazvin province. The plots were ploughed up to down slope in September 2011. Each plot was isolated using soil beds with a height of 30 cm, to direct generated surface runoff to the lower part of the plots. Runoff collecting systems composed of gutters, pipes and tankswere installed at the end of each plot. During the two-year study period of 2011-2012, plots were maintained in bare conditions and runoff and soil loss were measured for each single event. Precipitation amounts and characteristics were directly measured by an automatic recording tipping-bucket rain gauge located about 200 m from the experimental plots. The entire runoff volume including eroded sediment was measured on

  6. The spatial variability in studies of soil physical condition

    International Nuclear Information System (INIS)

    Madero M, Edgar; Herrera G Oscar A; Castano C, Alirio

    2000-01-01

    The testing procedure was carried out in 1996-2 at the experimental station of the Universidad Nacional de Colombia in Palmira using vertical tillage (by chiseling) in coherent vertisol (typic Haplustert isohiperthermic fine loamy 1%). eight physical properties in depth of 15-25 cm were studied. the sampling methodology for soil physical properties and corn yield accounted the regionalized variable, and the analysis of results was carried out accounting a map of each variable. the results proved that geostatystics is versatile and give accuracy results. it showed in most of the area that vertical tillage was more favorable than conventional tillage to improve coherence (more soil penetrability without degradation) in seedbed zone. it was not found influence over corn yield. soil organic matter; clay and silt had influence over the soil response to mechanical strengths

  7. Infiltration Variability in Agricultural Soil Aggregates Caused by Air Slaking

    Science.gov (United States)

    Korenkova, L.; Urik, M.

    2018-04-01

    This article reports on variation in infiltration rates of soil aggregates as a result of phenomenon known as air slaking. Air slaking is caused by the compression and subsequent escape of air captured inside soil aggregates during water saturation. Although it has been generally assumed that it occurs mostly when dry aggregates are rapidly wetted, the measurements used for this paper have proved that it takes place even if the wetting is gradual, not just immediate. It is a phenomenon that contributes to an infiltration variability of soils. In measuring the course of water flow through the soil, several small aggregates of five agricultural soils were exposed to distilled water at zero tension in order to characterize their hydraulic properties. Infiltration curves obtained for these aggregates demonstrate the effect of entrapped air on the increase and decrease of infiltration rates. The measurements were performed under various moisture conditions of the A-horizon aggregates using a simple device.

  8. Identifying environmental and geochemical variables governing metal concentrations in a stream draining headwaters in NW Spain

    International Nuclear Information System (INIS)

    Soto-Varela, F.; Rodríguez-Blanco, M.L.; Taboada-Castro, M.M.; Taboada-Castro, M.T.

    2014-01-01

    Highlights: • All metals occur in association with suspended sediment. • DOC and SS appeared to influence the partitioning of metals. • The SS was a good predictor of particulate metal levels. • The most important variable to explain storm-event K D for Al and Fe is DOC. • Enrichment factor values suggest a natural origin for the particulate metals. - Abstract: Headwater stream, draining from a rural catchment in NW Spain, was sampled during baseflow and storm-event conditions to investigate the temporal variability in dissolved and particulate Al, Fe, Mn, Cu and Zn concentrations and the role of discharge (Q), pH, dissolved organic carbon (DOC) and suspended sediment (SS) in the transport of dissolved and particulate metals. Under baseflow and storm-event conditions, concentrations of the five metals were highly variable. The results of this study reveal that all metal concentrations are correlated with SS. DOC and SS appeared to influence both the metal concentrations and the partitioning of metals between dissolved and particulate. The SS was a good predictor of particulate metal levels. Distribution coefficients (K D ) were similar between metals (4.72–6.55) and did not change significantly as a function of discharge regime. Stepwise multiple linear regression analysis reveals that the most important variable to explain storm-event K D for Al and Fe is DOC. The positive relationships found between metals, in each fraction, indicate that these elements mainly come from the same source. Metal concentrations in the stream were relatively low

  9. Interaction of natural complexing agents with soil bound heavy metals -geochemical and environmental technical aspects

    International Nuclear Information System (INIS)

    Fischer, K.

    1994-01-01

    The sanitation of heavy metal polluted soils requires the application of an adequate technology, which should be consistent in its ecological aims and methodology. Therefore a research programme has been developed at the 'Institute of Ecological Chemistry' of the 'GSF-Research Center', Neuherberg, which has its starting point in the study of influences of natural organic complexing agents on the chemical activity and dynamic of heavy metals in soils. The groundlaying idea is to elevate the concentration of complexing agents in the soil solution by additional application and possible stimulation of their microbial production to such an extent, that heavy metals will be enhanced solubilized, mobilized and removed together with the seepage water. Batch experiments in order to extract heavy metals from typical soil components (bentonite, peat) by amino acids demonstrate, that removal rates up to 95% can be obtained. (orig.) [de

  10. Geochemical distribution of polycyclic aromatic hydrocarbons in soils and sediments of El-Tabbin, Egypt

    Czech Academy of Sciences Publication Activity Database

    Havelcová, Martina; Melegy, A.; Rapant, S.

    2014-01-01

    Roč. 95, JAN (2014), s. 63-74 ISSN 0045-6535 Institutional support: RVO:67985891 Keywords : polycyclic aromatic hydrocarbons * soils * sediment * contamination Subject RIV: DD - Geochemistry Impact factor: 3.340, year: 2014

  11. Geochemical legacies and the future health of cities: A tale of two neurotoxins in urban soils

    Science.gov (United States)

    Fillipelli, Gabriel M.; Risch, Martin R.; Laidlaw, Mark A. S.; Nichols, Deborah E.; Crewe, Julie

    2015-01-01

    The past and future of cities are inextricably linked, a linkage that can be seen clearly in the long-term impacts of urban geochemical legacies. As loci of population as well as the means of employment and industry to support these populations, cities have a long history of co-locating contaminating practices and people, sometimes with negative implications for human health. Working at the intersection between environmental processes, communities, and human health is critical to grapple with environmental legacies and to support healthy, sustainable, and growing urban populations. An emerging area of environmental health research is to understand the impacts of chronic exposures and exposure mixtures—these impacts are poorly studied, yet may pose a significant threat to population health.

  12. Sensitivity of soil respiration to variability in soil moisture and temperature in a humid tropical forest

    Science.gov (United States)

    Tana Wood; M. Detto; W.L. Silver

    2013-01-01

    Precipitation and temperature are important drivers of soil respiration. The role of moisture and temperature are generally explored at seasonal or inter-annual timescales; however, significant variability also occurs on hourly to daily time-scales. We used small (1.54 m2), throughfall exclusion shelters to evaluate the role soil moisture and temperature as temporal...

  13. Year-round estimation of soil moisture content using temporally variable soil hydraulic parameters

    Czech Academy of Sciences Publication Activity Database

    Šípek, Václav; Tesař, Miroslav

    2017-01-01

    Roč. 31, č. 6 (2017), s. 1438-1452 ISSN 0885-6087 R&D Projects: GA ČR GA16-05665S Institutional support: RVO:67985874 Keywords : hydrological modelling * pore-size distribution * saturated hydraulic conductivity * seasonal variability * soil hydraulic parameters * soil moisture Subject RIV: DA - Hydrology ; Limnology OBOR OECD: Hydrology Impact factor: 3.014, year: 2016

  14. The Source, Spatial Distribution and Risk Assessment of Heavy Metals in Soil from the Pearl River Delta Based on the National Multi-Purpose Regional Geochemical Survey.

    Science.gov (United States)

    Zhang, Lingyan; Guo, Shuhai; Wu, Bo

    2015-01-01

    The data on the heavy metal content at different soil depths derived from a multi-purpose regional geochemical survey in the Pearl River Delta (PRD) were analyzed using ArcGIS 10.0. By comparing their spatial distributions and areas, the sources of heavy metals (Cd, Hg, As and Pb) were quantitatively identified and explored. Netted measuring points at 25 ×25 km were set over the entire PRD according to the geochemical maps. Based on the calculation data obtained from different soil depths, the concentrations of As and Cd in a large area of the PRD exceeded the National Second-class Standard. The spatial disparity of the geometric centers in the surface soil and deep soil showed that As in the surface soil mainly came from parent materials, while Cd had high consistency in different soil profiles because of deposition in the soil forming process. The migration of Cd also resulted in a considerable ecological risk to the Beijiang and Xijiang River watershed. The potential ecological risk index followed the order Cd ≥ Hg > Pb > As. According to the sources, the distribution trends and the characteristics of heavy metals in the soil from the perspective of the whole area, the Cd pollution should be repaired, especially in the upper reaches of the Xijiang and Beijiang watershed to prevent risk explosion while the pollution of Hg and Pb should be controlled in areas with intense human activity, and supervision during production should be strengthened to maintain the ecological balance of As.

  15. Geochemical study of urban soils in public areas of an industrialized town (Ajka, western Hungary)

    Science.gov (United States)

    Zacháry, D.; Jordán, Gy.; Szabó, Cs.

    2012-04-01

    Soil is one of the most essential parts of urban ecosystem contributing to the biogeochemical cycles along the rock-soil-plant-animal and human pathway. Soil plays a fundamental role in plant nutrient uptake and groundwater filtration, too. Urban soils differ from non-urban soils in many aspects, including their origin, and they may also concentrate contaminants in large quantities due to intensive human activities. The pollution sources are industry, traffic, fertilizer, tailing and waste. In addition to the increasing rate of urban areas, urban soils are under growing interest and their pollution have received significant attention in the past few decades. This work focuses on the toxic element (As, Hg, Pb, Cu, Zn, Cd, Ni) content of soils and their spatial distribution in order to find a link between contamination sources and the receiving urban soils at sensitive receptor locations such as children's playgrounds and parks. Ajka town is located in western Hungary. It has an old-established industrial history with multiple contamination sources of heavy alumina industry and coal-based power plants supplied by the nearby bauxite and coal mines. At 44 locations 46 soil samples have been collected at a depth of 0-10 cm along a 1x1 km grid. The whole grid covers an area of 48 km2. In each grid cell a sampling site was selected at public areas. Sample preparation included drying at 40 C°, thorough homogenization and sieving to 2 mm fine earth before chemical analysis. Grain size distribution and soil pH were also determined. Samples were analyzed with ICP-OES and SEM methods. The As, Hg, Pb, Cu, Zn, Cd and Ni concentrations range from 2.07 ppm to 9.48 ppm, 0.02 ppm to 2.84 ppm, 5.08 ppm to 35.74 ppm, 2.55 ppm to 47.78 ppm, 17.00 ppm to 91.00 ppm, 0.07 ppm to 0.61 ppm and 5.57 ppm to 32.09 ppm, respectively. The results revealed the contaminated areas associated with past industrial sites. This study also identified locations with considerable contamination at

  16. Geochemical indicators and characterization of soil water repellence in three dominant ecosystems of Western Australia

    Science.gov (United States)

    Muñoz-Rojas, Miriam; Jiménez-Morillo, Nicasio T.; Jordan, Antonio; Zavala, Lorena M.; Stevens, Jason; González-Pérez, Jose Antonio

    2016-04-01

    Introduction Soil water repellency (SWR) has critical implications for restoration of vegetation in degraded areas as it is responsible of poor plant establishment and a high incidence of erosion processes. Different organic substances are capable of inducing SWR but polar molecules such as certain fatty acids, and waxes i.e. esters and salts of fatty acids, appear to be the main constituents of hydrophobic coatings on soil mineral particles (Doerr et al., 2005). Plant species most commonly associated with SWR are evergreen trees with a considerable amount of resins, waxes or aromatic oils such as eucalypts and pines. Most of these substances are abundant in ecosystems and are released to soil by plants as root exudates or decaying organic debris, and by soil fauna, fungi and other microorganisms, but a thorough knowledge of substances capable of inducing hydrophobicity in soils is still not complete (Jordan et al., 2013). Although SWR has been reported in most continents of the world for different soil types, climate conditions and land uses, there are still many research gaps in this area, particularly in semi-arid areas largely affected by this phenomenon. Materials and methods This research was conducted in three dominant ecosystems of Western Australia (WA), e.g. semi-arid grassland in the Pilbara region (North WA), Banksia woodland, and a coastal dune (both located in South WA). These environments have different climate characteristics and soil types but similar vegetation communities. Soil samples were collected under the canopy of a broad range of plant species that compose the dominant vegetation communities of these ecosystems, and SWR was measured under lab conditions in oven-dry samples (48 h, 105 °C). Soil microbial activity was measured with the 1-day CO2 test, a cost-effective and rapid method to determine soil microbial respiration rate based on the measurement of the CO2 burst produced after moistening dry soil (Muñoz-Rojas et al., 2016). Soil p

  17. Spatial variability of soil erosion and soil quality on hillslopes in the Chinese loess plateau

    International Nuclear Information System (INIS)

    Li, Y.; Lindstrom, M.J.; Zhang, J.; Yang, J.

    2000-01-01

    Soil erosion rates and soil quality indicators were measured along two hillslope transects in the Loess Plateau near Yan'an, China. The objectives were to: (a) quantify spatial patterns and controlling processes of soil redistribution due to water and tillage erosion, and (b) correlate soil quality parameters with soil redistribution along the hillslope transects for different land use management systems. Water erosion data were derived from 137 Cs measurements and tillage erosion from the simulation of a Mass Balance Model along the hillslope transects. Soil quality measurements, i.e. soil organic matter, bulk density and available nutrients were made at the same sampling locations as the 137 Cs measurements. Results were compared at the individual site locations and along the hillslope transect through statistical and applied time series analysis. The results showed that soil loss due to water erosion and soil deposition from tillage are the dominant soil redistribution processes in range of 23-40 m, and soil deposition by water erosion and soil loss by tillage are dominant processes occurring in range of more than 80 m within the cultivated landscape. However, land use change associated with vegetation cover can significantly change both the magnitudes and scale of these spatial patterns within the hillslope landscapes. There is a strong interaction between the spatial patterns of soil erosion processes and soil quality. It was concluded that soil loss by water erosion and deposition by tillage are the main cause for the occurrence of significant scale dependency of spatial variability of soil quality along hillslope transects. (author)

  18. Influence of management history and landscape variables on soil organic carbon and soil redistribution

    Science.gov (United States)

    Venteris, E.R.; McCarty, G.W.; Ritchie, J.C.; Gish, T.

    2004-01-01

    Controlled studies to investigate the interaction between crop growth, soil properties, hydrology, and management practices are common in agronomy. These sites (much as with real world farmland) often have complex management histories and topographic variability that must be considered. In 1993 an interdisiplinary study was started for a 20-ha site in Beltsville, MD. Soil cores (271) were collected in 1999 in a 30-m grid (with 5-m nesting) and analyzed as part of the site characterization. Soil organic carbon (SOC) and 137Cesium (137Cs) were measured. Analysis of aerial photography from 1992 and of farm management records revealed that part of the site had been maintained as a swine pasture and the other portion as cropped land. Soil properties, particularly soil redistribution and SOC, show large differences in mean values between the two areas. Mass C is 0.8 kg m -2 greater in the pasture area than in the cropped portion. The pasture area is primarily a deposition site, whereas the crop area is dominated by erosion. Management influence is suggested, but topographic variability confounds interpretation. Soil organic carbon is spatially structured, with a regionalized variable of 120 m. 137Cs activity lacks spatial structure, suggesting disturbance of the profile by animal activity and past structures such as swine shelters and roads. Neither SOC nor 137Cs were strongly correlated to terrain parameters, crop yields, or a seasonal soil moisture index predicted from crop yields. SOC and 137Cs were weakly correlated (r2 ???0.2, F-test P-value 0.001), suggesting that soil transport controls, in part, SOC distribution. The study illustrates the importance of past site history when interpreting the landscape distribution of soil properties, especially those strongly influenced by human activity. Confounding variables, complex soil hydrology, and incomplete documentation of land use history make definitive interpretations of the processes behind the spatial distributions

  19. On the role of "internal variability" on soil erosion assessment

    Science.gov (United States)

    Kim, Jongho; Ivanov, Valeriy; Fatichi, Simone

    2017-04-01

    Empirical data demonstrate that soil loss is highly non-unique with respect to meteorological or even runoff forcing and its frequency distributions exhibit heavy tails. However, all current erosion assessments do not describe the large associated uncertainties of temporal erosion variability and make unjustified assumptions by relying on central tendencies. Thus, the predictive skill of prognostic models and reliability of national-scale assessments have been repeatedly questioned. In this study, we attempt to reveal that the high variability in soil losses can be attributed to two sources: (1) 'external variability' referring to the uncertainties originating at macro-scale, such as climate, topography, and land use, which has been extensively studied; (2) 'geomorphic internal variability' referring to the micro-scale variations of pedologic properties (e.g., surface erodibility in soils with multi-sized particles), hydrologic properties (e.g., soil structure and degree of saturation), and hydraulic properties (e.g., surface roughness and surface topography). Using data and a physical hydraulic, hydrologic, and erosion and sediment transport model, we show that the geomorphic internal variability summarized by spatio-temporal variability in surface erodibility properties is a considerable source of uncertainty in erosion estimates and represents an overlooked but vital element of geomorphic response. The conclusion is that predictive frameworks of soil erosion should embed stochastic components together with deterministic assessments, if they do not want to largely underestimate uncertainty. Acknowledgement: This study was supported by the Basic Science Research Program of the National Research Foundation of Korea funded by the Ministry of Education (2016R1D1A1B03931886).

  20. Environmental-geochemical characteristics of Cu in the soil and water in copper-rich deposit area of southeastern Hubei Province, along the middle Yangtze River, Central China

    International Nuclear Information System (INIS)

    Zhang Ling; Wang Lu; Yin Kedong; Lv Ying; Zhang Derong

    2009-01-01

    In this study, the natural Cu background concentration and Cu natural and anthropogenic contamination in soil, water and crop were investigated systematically in Huangshi area. The results show that regional geology is the dominant factor controlling the natural Cu background concentration in soil and water, and that pH is important to control the vertical distribution of Cu in soil under the same geographical and climatic conditions. The mineralization of rock bodies causes the natural Cu increase in soil and water, whereas, a large number of mining-smelting plants and chemical works are the main sources of Cu anthropogenic contamination. Cu in naturally and anthropogenically polluted soil displays differences in total and available contents, vertical distribution patterns and physico-chemical properties, the same happens in water. - Consider the rock-soil-water-crop as a system to study the geochemical activities and environmental pollution of copper.

  1. Effects of short-term variability of meteorological variables on soil temperature in permafrost regions

    Science.gov (United States)

    Beer, Christian; Porada, Philipp; Ekici, Altug; Brakebusch, Matthias

    2018-03-01

    Effects of the short-term temporal variability of meteorological variables on soil temperature in northern high-latitude regions have been investigated. For this, a process-oriented land surface model has been driven using an artificially manipulated climate dataset. Short-term climate variability mainly impacts snow depth, and the thermal diffusivity of lichens and bryophytes. These impacts of climate variability on insulating surface layers together substantially alter the heat exchange between atmosphere and soil. As a result, soil temperature is 0.1 to 0.8 °C higher when climate variability is reduced. Earth system models project warming of the Arctic region but also increasing variability of meteorological variables and more often extreme meteorological events. Therefore, our results show that projected future increases in permafrost temperature and active-layer thickness in response to climate change will be lower (i) when taking into account future changes in short-term variability of meteorological variables and (ii) when representing dynamic snow and lichen and bryophyte functions in land surface models.

  2. Spatial variability of atrazine dissipation in an allophanic soil.

    Science.gov (United States)

    Müller, Karin; Smith, Roger E; James, Trevor K; Holland, Patrick T; Rahman, Anis

    2003-08-01

    The small-scale variability (0.5 m) of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) concentrations and soil water contents in a volcanic silt loam soil (Haplic Andosol, FAO system) was studied in an area of 0.1 ha. Descriptive and spatial statistics were used to analyse the data. On average we recovered 102% of the applied atrazine 2 h after the herbicide application (CV = 35%). An increase in the CV of the concentrations with depth could be ascribed to a combination of extrinsic and intrinsic factors. Both variables, atrazine concentrations and soil water content, showed a high horizontal variability. The semivariograms of the atrazine concentrations exhibited the pure nugget effect, no pattern could be determined along the 15.5-m long transects on any of the seven sampling days over a 55-day period. Soil water content had a weak spatial autocorrelation with a range of 6-10 m. The dissipation of atrazine analysed using a high vertical sampling resolution of 0.02 m to 0.2 m showed that 70% of the applied atrazine persisted in the upper 0.02-m layer of the soil for 12 days. After 55 days and 410 mm of rainfall the centre of the pesticide mass was still at a soil depth of 0.021 m. The special characteristics of the soil (high organic carbon content, allophanic clay) had a strong influence on atrazine sorption and mobility. The mass recovery after 55 days was low. The laboratory degradation rate for atrazine, determined in a complementary incubation study and corrected for the actual field temperature using the Arrhenius equation, only accounted for about 35% of the losses that occurred in the field. Results suggest field degradation rates to be more changeable in time and much faster than under controlled conditions. Preferential flow is discussed as a component of the field transport process.

  3. Comparing the Ability of Conventional and Digital Soil Maps to Explain Soil Variability using Diversity Indices

    Directory of Open Access Journals (Sweden)

    zohreh mosleh

    2017-06-01

    Full Text Available Introduction: Effective and sustainable soil management requires knowledge about the spatial patterns of soil variation and soil surveys are important and useful sources of data that can be used. Prior knowledge about the spatial distribution of the soils is the first essential step for this aim but this requires the collection of large amounts of soil information. However, the conventional soil surveys are usually not useful for providing quantitative information about the spatial distribution of soil properties that are used in many environmental studies. Recently, by the rapid development of the computers and technology together with the availability of new types of remote sensing data and digital elevation models (DEMs, digital and quantitative approaches have been developed. These new techniques relies on finding the relationships between soil properties or classes and the auxiliary information that explain the soil forming factors or processes and finally predict soil patterns on the landscape. Different types of the machine learning approaches have been applied for digital soil mapping of soil classes, such as the logistic and multinomial logistic regressions, neural networks and classification trees. In reality, soils are physical outcomes of the interactions happening among the geology, climate, hydrology and geomorphic processes. Diversity is a way of measuring soil variation. Ibanez (9 first introduced ecological diversity indices as measures of diversity. Application of the diversity indices in soil science have considerably increased in recent years. Taxonomic diversity has been evaluated in the most previous researches whereas comparing the ability of different soil mapping approaches based on these indices was rarely considered. Therefore, the main objective of this study was to compare the ability of the conventional and digital soil maps to explain the soil variability using diversity indices in the Shahrekord plain of

  4. Geochemistry of soils along a transect from Central Mexico to the Pacific Coast: a pilot study for continental-scale geochemical mapping

    Science.gov (United States)

    Chiprés, J.A.; de la Calleja,; Tellez, J.I.; Jiménez, F.; Cruz, Carlos; Guerrero, E.G.; Castro, J.; Monroy, M.G.; Salinas, J.C.

    2009-01-01

    The Mexican Geological Survey (SGM), the National Institute of Statistics, Geography and Informatics (INEGI) and the Autonomous University of San Luis Potosi (UASLP) have established a multidisciplinary team with the objective of creating a national program of geochemical mapping of soils in Mexico. This is being done as part of the North American Soil Geochemical Landscapes Project in partnership with the US Geological Survey and the Geological Survey of Canada. As the first step, a pilot study was conducted over a transect that extends from the Mexico–US border near Ciudad Juarez in the north to the Pacific Ocean in the south. This pilot transect was conducted in two phases, and this paper presents results from the first phase, which sampled soils at about a 40-km spacing along a 730-km transect beginning in Central Mexico and ending at the Pacific Coast. Samples were collected from the A and C horizons at each site and 60 elements were analyzed. This pilot study demonstrates that geochemical mapping based on a 40-km spacing is adequate to identify broad-scale geochemical patterns. Geologic influence (i.e., soil parent material) was the most important factor influencing the distribution of elements along the transect, followed by the influence of regional mineralization. The study also showed that influence by human activities over the transect is minimal except possibly in large mining districts. A comparison of element abundance in the A horizon with the environmental soil guidelines in Mexico showed that the natural concentrations of the studied soils were lower than the established threshold for soil restoration with the exception of V and As. The former had a median value (75 mg/kg) approximately equal to the value established in Mexico for soil restoration in agricultural and residential lands (78 mg/kg), and the latter had three values higher than the 22 mg/kg threshold for soil restoration in agricultural and residential lands. These cases demonstrate

  5. The Impact of Soil Sampling Errors on Variable Rate Fertilization

    Energy Technology Data Exchange (ETDEWEB)

    R. L. Hoskinson; R C. Rope; L G. Blackwood; R D. Lee; R K. Fink

    2004-07-01

    Variable rate fertilization of an agricultural field is done taking into account spatial variability in the soil’s characteristics. Most often, spatial variability in the soil’s fertility is the primary characteristic used to determine the differences in fertilizers applied from one point to the next. For several years the Idaho National Engineering and Environmental Laboratory (INEEL) has been developing a Decision Support System for Agriculture (DSS4Ag) to determine the economically optimum recipe of various fertilizers to apply at each site in a field, based on existing soil fertility at the site, predicted yield of the crop that would result (and a predicted harvest-time market price), and the current costs and compositions of the fertilizers to be applied. Typically, soil is sampled at selected points within a field, the soil samples are analyzed in a lab, and the lab-measured soil fertility of the point samples is used for spatial interpolation, in some statistical manner, to determine the soil fertility at all other points in the field. Then a decision tool determines the fertilizers to apply at each point. Our research was conducted to measure the impact on the variable rate fertilization recipe caused by variability in the measurement of the soil’s fertility at the sampling points. The variability could be laboratory analytical errors or errors from variation in the sample collection method. The results show that for many of the fertility parameters, laboratory measurement error variance exceeds the estimated variability of the fertility measure across grid locations. These errors resulted in DSS4Ag fertilizer recipe recommended application rates that differed by up to 138 pounds of urea per acre, with half the field differing by more than 57 pounds of urea per acre. For potash the difference in application rate was up to 895 pounds per acre and over half the field differed by more than 242 pounds of potash per acre. Urea and potash differences

  6. Spatial variability of nitrogen-15 and its relation to the variability of other soil properties

    International Nuclear Information System (INIS)

    Selles, F.; Karamanos, R.E.; Kachanoski, R.G.

    1986-01-01

    The spatial variability of natural 15 N abundance of a cultivated Chernozemic soil and its native prairie counterpart were smaller than that of total N, organic C, and the C/N ratio. Further, the number of samples required to estimate the true mean of total N with a given precision at various probability levels were twofold those required to estimate the true mean of total N with a given precision at various probability levels were twofold those required to determine the mean 15 N abundance of total soil N in the surface horizons may reflect the isotopic composition of the nitrogenous substances entering the soil system or changes in the isotopic composition of soil N due to humification processes, probably induced by variations in topographic and microrelief features of the soil

  7. The geochemical atlas of Alaska, 2016

    Science.gov (United States)

    Lee, Gregory K.; Yager, Douglas B.; Mauk, Jeffrey L.; Granitto, Matthew; Denning, Paul; Wang, Bronwen; Werdon, Melanie B.

    2016-06-21

    A rich legacy of geochemical data produced since the early 1960s covers the great expanse of Alaska; careful treatment of such data may provide significant and revealing geochemical maps that may be used for landscape geochemistry, mineral resource exploration, and geoenvironmental investigations over large areas. To maximize the spatial density and extent of data coverage for statewide mapping of element distributions, we compiled and integrated analyses of more than 175,000 sediment and soil samples from three major, separate sources: the U.S. Geological Survey, the National Uranium Resource Evaluation program, and the Alaska Division of Geological & Geophysical Surveys geochemical databases. Various types of heterogeneity and deficiencies in these data presented major challenges to our development of coherently integrated datasets for modeling and mapping of element distributions. Researchers from many different organizations and disparate scientific studies collected samples that were analyzed using highly variable methods throughout a time period of more than 50 years, during which many changes in analytical techniques were developed and applied. Despite these challenges, the U.S. Geological Survey has produced a new systematically integrated compilation of sediment and soil geochemical data with an average sample site density of approximately 1 locality per 10 square kilometers (km2) for the entire State of Alaska, although density varies considerably among different areas. From that compilation, we have modeled and mapped the distributions of 68 elements, thus creating an updated geochemical atlas for the State.

  8. Soil fauna and its relation with environmental variables in soil management systems

    Directory of Open Access Journals (Sweden)

    Dilmar Baretta

    Full Text Available The present study aims to generate knowledge about the soil fauna, its relation to other explanatory environmental variables, and, besides it, to select edaphic indicators that more contribute to separate the land use systems (LUS. Five different LUS were chosen: conventional tillage with crop rotation (CTCR; no-tillage with crop rotation (NTCR; conventional tillage with crop succession (CTCS; no-tillage with crop succession (NTCS and minimum tillage with crop succession (MTCS. The samples were made in the counties Chapecó, Xanxerê and Ouro Verde located in the state of Santa Catarina, Brazil, and were considered the true replicates of the LUS. In each site, nine points were sampled in a sampling grid of 3 x 3. At the same points, soil was sampled for the physical, chemical and biological attributes (environmental variables. Pitfall traps were used to evaluate the soil fauna. Data were analyzed using principal component analysis (PCA and canonical discriminant analysis (CDA. The soil fauna presented potential to be used as indictors of soil quality, since some groups proved to be sensible to changes of the environmental variables and to soil management and tillage. The soil management using crop rotation (NTCR and CTCR presented higher diversity, compared to the systems using crop succession (NTCS, MTCS and NTCS, evidencing the importance of the soil tillage, independent of the season (summer or winter. The variable that better contributed to explain these changes were the chemical variables (potassium, pH, calcium, organic matter, available phosphorus, potential acidity, and biological variables (Shannon diversity index, Collembola, Pielou equitability index and microbial biomass carbon, respectively.

  9. Pilot studies for the North American Soil Geochemical Landscapes Project - Site selection, sampling protocols, analytical methods, and quality control protocols

    Science.gov (United States)

    Smith, D.B.; Woodruff, L.G.; O'Leary, R. M.; Cannon, W.F.; Garrett, R.G.; Kilburn, J.E.; Goldhaber, M.B.

    2009-01-01

    In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada sampled and chemically analyzed soils along two transects across Canada and the USA in preparation for a planned soil geochemical survey of North America. This effort was a pilot study to test and refine sampling protocols, analytical methods, quality control protocols, and field logistics for the continental survey. A total of 220 sample sites were selected at approximately 40-km intervals along the two transects. The ideal sampling protocol at each site called for a sample from a depth of 0-5 cm and a composite of each of the O, A, and C horizons. The Ca, Fe, K, Mg, Na, S, Ti, Ag, As, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO3, HClO4, and HF. Separate methods were used for Hg, Se, total C, and carbonate-C on this same size fraction. Only Ag, In, and Te had a large percentage of concentrations below the detection limit. Quality control (QC) of the analyses was monitored at three levels: the laboratory performing the analysis, the USGS QC officer, and the principal investigator for the study. This level of review resulted in an average of one QC sample for every 20 field samples, which proved to be minimally adequate for such a large-scale survey. Additional QC samples should be added to monitor within-batch quality to the extent that no more than 10 samples are analyzed between a QC sample. Only Cr (77%), Y (82%), and Sb (80%) fell outside the acceptable limits of accuracy (% recovery between 85 and 115%) because of likely residence in mineral phases resistant to the acid digestion. A separate sample of 0-5-cm material was collected at each site for determination of organic compounds. A subset of 73 of these samples was analyzed for a suite of

  10. Soil moisture variability across different scales in an Indian watershed for satellite soil moisture product validation

    KAUST Repository

    Singh, Gurjeet

    2016-05-05

    Strategic ground-based sampling of soil moisture across multiple scales is necessary to validate remotely sensed quantities such as NASA’s Soil Moisture Active Passive (SMAP) product. In the present study, in-situ soil moisture data were collected at two nested scale extents (0.5 km and 3 km) to understand the trend of soil moisture variability across these scales. This ground-based soil moisture sampling was conducted in the 500 km2 Rana watershed situated in eastern India. The study area is characterized as sub-humid, sub-tropical climate with average annual rainfall of about 1456 mm. Three 3x3 km square grids were sampled intensively once a day at 49 locations each, at a spacing of 0.5 km. These intensive sampling locations were selected on the basis of different topography, soil properties and vegetation characteristics. In addition, measurements were also made at 9 locations around each intensive sampling grid at 3 km spacing to cover a 9x9 km square grid. Intensive fine scale soil moisture sampling as well as coarser scale samplings were made using both impedance probes and gravimetric analyses in the study watershed. The ground-based soil moisture samplings were conducted during the day, concurrent with the SMAP descending overpass. Analysis of soil moisture spatial variability in terms of areal mean soil moisture and the statistics of higher-order moments, i.e., the standard deviation, and the coefficient of variation are presented. Results showed that the standard deviation and coefficient of variation of measured soil moisture decreased with extent scale by increasing mean soil moisture. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  11. Variability of atmospheric depositions of artificial radioelements and their transfer into soils

    International Nuclear Information System (INIS)

    Pourcelot, Laurent

    2008-01-01

    In this Habilitation thesis, I present the results and prospects of the main research topics that contribute to bettering our knowledge of the behaviour of artificial radioelements in the geosphere and biosphere. In the first chapter I present a summary of the research carried out for my thesis on the Oklo reactors. In the subsequent chapters I present my research work at the IRSN. The second chapter concerns the atmospheric depositions of radioactive contaminants. I have studied the principal environmental parameters involved in the empirical modelling of the transfer of artificial radioelements from the atmosphere to the soil. Here I essentially use measurements of artificial radioelements ( 137 Cs, plutonium, americium) in soils that reveal the variability of accidental depositions further to the Chernobyl disaster (paragraph 2.1) and chronic radioactive depositions coming from the atmospheric testing of nuclear weapons (paragraph 2.2). In the third chapter I address the problem of transfers of artificial radioelements into the soil. The interest of this lies in the fact that these transfers represent serious risks for man. Taken over the long term (in the months and years that follow the depositing of radioactive elements on the ground and plants), the transfers of radioactive pollutants into the soil are responsible for the contamination of both plants (transfer via the roots) and underground water and surface water (transfer after vertical migration). My research work into the transfers of radioactive pollutants in soils is centred on vertical migrations and root transfers, as both these processes can be studied through environmental samplings and measurements. More precisely, I have studied the migrations of radioactive pollutants and their geochemical analogues in different types of soils (paragraph 3.1) and the variability of the activities of radiostrontium and radiocesium in the compartments of permanent grassland zones (soil, grass, milk and cheese

  12. Geochemical and radiological characterization of soils from former radium processing sites.

    Science.gov (United States)

    Landa, E R

    1984-02-01

    Soil samples were collected from former radium processing sites in Denver, CO, and East Orange, NJ. Particle-size separations and radiochemical analyses of selected samples showed that while the greatest contents of both 226Ra and U were generally found in the finest (less than 45 micron) fraction, the pattern was not always of progressive increase in radionuclide content with decreasing particle size. Leaching tests on these samples showed a large portion of the 226Ra and U to be soluble in dilute hydrochloric acid. Radon-emanation coefficients measured for bulk samples of contaminated soil were about 20%. Recovery of residual uranium and vanadium, as an adjunct to any remedial action program, appears unlikely due to economic considerations.

  13. Spatial variability of chemical properties of soil under pasture

    Directory of Open Access Journals (Sweden)

    Samuel Ferreira da Silva

    2016-04-01

    Full Text Available The objective of this study was to analyze the spatial variability of soil chemical attributes under pasture, as well as lime and fertilizer recommendations based on the interpretation of soil chemical analysis from two sampling methods: conventional and systematic depths of 0 to 10 and 10 to 20 cm. The study was conducted at IFES-campus Alegre-ES. Data analysis was performed using descriptive statistics and geostatistics. Results indicate that the spatial method enabled the identification of deficit areas and excessive liming and fertilization, which could not be defined by the conventional method.

  14. Horizontal and vertical variability of soil moisture in savanna ecosystems

    Science.gov (United States)

    Caylor, K.; D'Odorico, P.; Rodriguez-Iturbe, I.

    2004-12-01

    Soil moisture is a key hydrological variable that mediates the interactions between climate, soil, and vegetation dynamics in water-limited ecosystems. Because of the importance of water limitation in savannas, a number of theoretical models of tree-grass coexistence have been developed which differ in their underlying assumptions about the ways in which trees and grasses access and use soil moisture. However, clarification of the mechanisms that allow savanna vegetation to persist as a mixture of grasses and trees remains a vexing problem in both hydrological and vegetation science. A particular challenge is the fact that the spatial pattern of vegetation is both a cause and effect of variation in water availability in semiarid ecosystems. At landscape to regional scales, climatic and geologic constraints on soil moisture availability are primary determinants of vegetation structural pattern. However, at local to landscape scales the patchy vegetation structural mosaic serves to redistribute the availability of soil moisture in ways that have important consequences for structural dynamics and community composition. In this regard, the emerging field of ecohydrology is well suited to investigate questions concerning couplings between the patchy structural mosaic of savanna vegetation and the kinds self-organizing dynamics known to exist in other light and nutrient-limited vegetation systems. Here we address the role of patchy vegetation structure through the use of a lumped model of soil moisture dynamics that accounts for the effect of tree canopy on the lateral and vertical distribution of soil moisture. The model includes mechanisms for the drying of the ground surface due to soil evaporation in the sites with no tree cover, and for the lateral water uptake due to root invading areas with no canopy cover located in the proximity of trees. The model, when applied to a series of sites along a rainfall gradient in southern Africa, is able to explain the cover

  15. Geochemical evidence for airborne dust additions to soils in Channel Islands National Park, California

    Science.gov (United States)

    Muhs, D.R.; Budahn, J.R.; Johnson, D.L.; Reheis, M.; Beann, J.; Skipp, G.; Fisher, E.; Jones, J.A.

    2008-01-01

    There is an increasing awareness that dust plays important roles in climate change, biogeochemical cycles, nutrient supply to ecosystems, and soil formation. In Channel Islands National Park, California, soils are clay-rich Vertisols or Alfisols and Mollisols with vertic properties. The soils are overlain by silt-rich mantles that contrast sharply with the underlying clay-rich horizons. Silt mantles contain minerals that are rare or absent in the volcanic rocks that dominate these islands. Immobile trace elements (Sc-Th-La and Ta-Nd-Cr) and rare-earth elements show that the basalt and andesite on the islands have a composition intermediate between upper-continental crust and oceanic crust. In contrast, the silt fractions and, to a lesser extent, clay fractions of the silt mantle have compositions closer to average upper-continental crust and very similar to Mojave Desert dust. Island shelves, exposed during the last glacial period, could have provided a source of eolian sediment for the silt mantles, but this is not supported by mineralogical data. We hypothesize that a more likely source for the silt-rich mantles is airborne dust from mainland California and Baja California, either from the Mojave Desert or from the continental shelf during glacial low stands of sea. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. The eolian silt mantles constitute an important medium of plant growth and provide evidence that abundant eolian silt and clay may be delivered to the eastern Pacific Ocean from inland desert sources. ?? 2007 Geological Society of America.

  16. Geochemical background of zinc, cadmium and mercury in anthropically influenced soils in a semi-arid zone (SE, Spain)

    Science.gov (United States)

    García-Lorenzo, M. L.; Pérez-Sirvent, C.; Martínez-Sánchez, M. J.; Molina, J.; Tudela, M. L.; Hernández-Córdoba, M.

    2009-04-01

    This work seeks to establish the geochemical background for three potentially toxic trace elements (Zn, Cd and Hg) in a pilot zone included in the DesertNet project in the province of Murcia. The studied area, known as Campo de Cartagena, Murcia (SE Spain) is an area of intensive agriculture and has been much affected over the years by anthropic activity. The zone can be considered an experimental pilot zone for establishing background levels in agricultural soils. Sixty four samples were collected and corresponded to areas subjected to high and similar agricultural activity or soils with natural vegetation, which correspond to abandoned agricultural areas. The Zn content was determined by flame atomic absorption spectrometry. The Cd content was determined by electrothermal atomization atomic absorption spectrometry and mercury content was determined by atomic fluorescence spectrometry. Geostatistical analysis consisting of kriging and mapping was performed using the geostatistical analyst extension of ArcGIS 8.3. Zinc values ranged from 10 mg kg-1 to 151 mg kg-1, with an average value of 45 mg kg-1. Cadmium values ranged between 0.1 mg kg-1 and 0.9mg kg-1, with a mean value of 0.3 mg kg-1 and mercury values ranged from 0.1 mg kg-1 to 2.3 mg kg-1, with a mean value of 0.5 mg kg-1. At a national level, the Spanish Royal Decree 9/2005 proposes toxicological and statistical approaches to establish background values. According to the statistical approach, background values consist of the median value for the selected element. The background values for Zn, Cd and Hg in the studied area were 40 mg kg-1 for Zn, 0.3 mg kg-1 for Cd and 0.4 mg kg-1 for Hg.

  17. Kinetics and Mechanism of Metal Retention/Release in Geochemical Processes in Soil - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Robert W.

    2000-12-29

    Effective, remediation of soils contaminated with heavy metals requires a better understanding of the mechanisms by which the metals are retained/released in soils over a long period of time. Studies on reaction of Cr(VI) with iron-rich clays indicated that structural iron (II) in these surfaces is capable of reducing chromate to chromium (III). We found that iron (II) either found naturally or produced by treatment of clay with sodium dithionite, effectively reduced Cr (VI) to Cr (III). Thus, in situ remediation of chromium combines reduction of Cr (VI) to Cr (III) and immobilization of chromium on mineral surfaces. During this study, lead sorption on a kaolin surface was found to be a rapid and a pH dependant process in which lead sorption significantly increased with the amount of phosphate on the clay surface. This study verifies that methylmercury cation remains intact when it binds to humic acids, forming a monodentate complex with some sub-population of humic thiol ligands .

  18. Mapping The Temporal and Spatial Variability of Soil Moisture Content Using Proximal Soil Sensing

    Science.gov (United States)

    Virgawati, S.; Mawardi, M.; Sutiarso, L.; Shibusawa, S.; Segah, H.; Kodaira, M.

    2018-05-01

    In studies related to soil optical properties, it has been proven that visual and NIR soil spectral response can predict soil moisture content (SMC) using proper data analysis techniques. SMC is one of the most important soil properties influencing most physical, chemical, and biological soil processes. The problem is how to provide reliable, fast and inexpensive information of SMC in the subsurface from numerous soil samples and repeated measurement. The use of spectroscopy technology has emerged as a rapid and low-cost tool for extensive investigation of soil properties. The objective of this research was to develop calibration models based on laboratory Vis-NIR spectroscopy to estimate the SMC at four different growth stages of the soybean crop in Yogyakarta Province. An ASD Field-spectrophotoradiometer was used to measure the reflectance of soil samples. The partial least square regression (PLSR) was performed to establish the relationship between the SMC with Vis-NIR soil reflectance spectra. The selected calibration model was used to predict the new samples of SMC. The temporal and spatial variability of SMC was performed in digital maps. The results revealed that the calibration model was excellent for SMC prediction. Vis-NIR spectroscopy was a reliable tool for the prediction of SMC.

  19. Geochemical signature and phytoremediation of urban soil: a case in Barcelona city

    Science.gov (United States)

    Rodríguez-Bocanegra, Javier; Roca, Núria; Febrero, Anna; Bort, Jordi

    2016-04-01

    The cleanup of contaminated places with heavy metals is necessary, but environmental remediation strategies are often expensive and energy consuming. Thus, it is important to develop low-cost and environmentally friendly strategies. Phytoremediation-based technologies could provide a long-lasting solution. The study area is located in Sants, a neighbourhood in Barcelona city (Catalonia, Spain). This place was an industrial area in the last century, which was occupied by a metal smelting industry. Nowadays, the neighbours want to cultivate vegetables in this location, but the history of this area suggests that the soil is polluted by elevated concentrations of heavy metals. The aim of this work was to determine heavy metal concentration in: a) soil, to know the degree of the soil pollution; b) roots and leaves of two plant species, Brassica juncea as an accumulator plant and Solanum lycopersicum as a crop plant, to know the capacity of each species to accumulate metals, and c) drainage water, to evaluate the heavy metal mobility. The main pollutants are Cu, Pb and Zn with topsoil total concentrations about 1355, 2230 and 6239 mg•kg-1, respectively. The established background upper limits in this area in mg•kg-1 were: Cu 145, Pb 91 and Zn 326. The same soil elements for available fractions, extracted with DTPA, were slightly elevated (9.6, 5.8 and 6.7 % of total concentration). The environmental pollution implies great extractability, suggesting the plants in these soils have facility with potentially toxic elements absorption. Instead, the concentrations in subsoil are lower than in topsoil. The concentrations of Cu, Pb and Zn in the plants' leaves are greater in B. juncea 170 ± 52.7, 137 ± 46.3 and 2365 ± 860.4 mg•kg-1, than in S. lycopersicum 102.5 ± 7.1, 22.5 ± 1.3 and 1002 ± 85.2 mg•kg-1 respectively. Furthermore, they are also greater in roots than in leaves. All of them are lower than the threshold to be considered like a hyperaccumulator species

  20. Wet-dry seasonal and vertical geochemical variations in soil water and their driving forces under different land covers in southwest China karst

    Science.gov (United States)

    Wang, Peng; Hu, Bill X.; Wu, Chuanhao; Xu, Kai

    2017-04-01

    Karst aquifers supply drinking water for 25% of the world's population, and they are, however, vulnerable to climate change. Bimonthly hydrochemical data in karst soil water samples from July 2010 to July 2011 were obtained to reveal the seasonal and vertical geochemical variations in soil water under five vegetation types in Qingmuguan, a small karst catchment in southwest China. Soil water chemistry was dominated by Ca2+, HCO3-, and SO42- because of the dissolution of limestone, dolomite, and gypsum minerals in the strata. The predominant hydrochemical types in soil water were Ca2+-HCO3-, Ca2+-SO42-, and mixed Ca2+-HCO3-SO42-. Ca2+ and HCO3- concentrations ranked in the following order: shrub land > dry land > afforestation farmland > bamboo land > grassland. In warm and wet seasons, the main ion concentrations in soil water from grasslands were low. Na+, K+, Ca2+, Mg2+, HCO3-, SO42-, and Cl- concentrations in soil water from other lands were high. An opposite trend was observed in cold and dry seasons. Marked seasonal variations were observed in Ca2+, HCO3-, and NO3- in soil water from dry land. The main ion concentrations in soil water from bamboo lands decreased as soil depth increased. By contrast, the chemistry of soil water from other lands increased as soil depth increased. Their ions were accumulated in depth. A consistent high and low variation between the main ions in soil water and the contents of carbonate and CO2 was found in the soil. Hydrochemical changes in soil water were regulated by the effects of dilution and soil CO2.

  1. Controls of Soil Spatial Variability in a Dry Tropical Forest.

    Directory of Open Access Journals (Sweden)

    Sandeep Pulla

    Full Text Available We examined the roles of lithology, topography, vegetation and fire in generating local-scale (<1 km2 soil spatial variability in a seasonally dry tropical forest (SDTF in southern India. For this, we mapped soil (available nutrients, Al, total C, pH, moisture and texture in the top 10 cm, rock outcrops, topography, all native woody plants ≥1 cm diameter at breast height (DBH, and spatial variation in fire frequency (times burnt during the 17 years preceding soil sampling in a permanent 50-ha plot. Unlike classic catenas, lower elevation soils had lesser moisture, plant-available Ca, Cu, Mn, Mg, Zn, B, clay and total C. The distribution of plant-available Ca, Cu, Mn and Mg appeared to largely be determined by the whole-rock chemical composition differences between amphibolites and hornblende-biotite gneisses. Amphibolites were associated with summit positions, while gneisses dominated lower elevations, an observation that concurs with other studies in the region which suggest that hillslope-scale topography has been shaped by differential weathering of lithologies. Neither NO3(--N nor NH4(+-N was explained by the basal area of trees belonging to Fabaceae, a family associated with N-fixing species, and no long-term effects of fire on soil parameters were detected. Local-scale lithological variation is an important first-order control over soil variability at the hillslope scale in this SDTF, by both direct influence on nutrient stocks and indirect influence via control of local relief.

  2. Temporal Changes in the Spatial Variability of Soil Nutrients

    Energy Technology Data Exchange (ETDEWEB)

    Hoskinson, Reed Louis; Hess, John Richard; Alessi, Randolph Samuel

    1999-07-01

    This paper reports the temporal changes in the spatial variability of soil nutrient concentrations across a field during the growing season, over a four-year period. This study is part of the Site-Specific Technologies for Agriculture (SST4Ag) precision farming research project at the INEEL. Uniform fertilization did not produce a uniform increase in fertility. During the growing season, several of the nutrients and micronutrients showed increases in concentration although no additional fertilization had occurred. Potato plant uptake did not explain all of these changes. Some soil micronutrient concentrations increased above levels considered detrimental to potatoes, but the plants did not show the effects in reduced yield. All the nutrients measured changed between the last sampling in the fall and the first sampling the next spring prior to fertilization. The soil microbial community may play a major role in the temporal changes in the spatial variability of soil nutrient concentrations. These temporal changes suggest potential impact when determining fertilizer recommendations, and when evaluating the results of spatially varying fertilizer application.

  3. Spatial Variability of Soil Morphorlogical and Physico-Chemical ...

    African Journals Online (AJOL)

    Spatial Variability of Soil Morphorlogical and Physico-Chemical Properties in Ladoke Akintola University of Technology Cashew Plantation, Ogbomoso. ... Colour (AP, B1 B2 and B3), structure (B2 and B3), stoniness (B1, B2 and B3), concretion (AP B1, B2 and B3) and boundary forms (B1, B2 and B3) have extremely ...

  4. Modelling carbon and nitrogen turnover in variably saturated soils

    Science.gov (United States)

    Batlle-Aguilar, J.; Brovelli, A.; Porporato, A.; Barry, D. A.

    2009-04-01

    Natural ecosystems provide services such as ameliorating the impacts of deleterious human activities on both surface and groundwater. For example, several studies have shown that a healthy riparian ecosystem can reduce the nutrient loading of agricultural wastewater, thus protecting the receiving surface water body. As a result, in order to develop better protection strategies and/or restore natural conditions, there is a growing interest in understanding ecosystem functioning, including feedbacks and nonlinearities. Biogeochemical transformations in soils are heavily influenced by microbial decomposition of soil organic matter. Carbon and nutrient cycles are in turn strongly sensitive to environmental conditions, and primarily to soil moisture and temperature. These two physical variables affect the reaction rates of almost all soil biogeochemical transformations, including microbial and fungal activity, nutrient uptake and release from plants, etc. Soil water saturation and temperature are not constants, but vary both in space and time, thus further complicating the picture. In order to interpret field experiments and elucidate the different mechanisms taking place, numerical tools are beneficial. In this work we developed a 3D numerical reactive-transport model as an aid in the investigation the complex physical, chemical and biological interactions occurring in soils. The new code couples the USGS models (MODFLOW 2000-VSF, MT3DMS and PHREEQC) using an operator-splitting algorithm, and is a further development an existing reactive/density-dependent flow model PHWAT. The model was tested using simplified test cases. Following verification, a process-based biogeochemical reaction network describing the turnover of carbon and nitrogen in soils was implemented. Using this tool, we investigated the coupled effect of moisture content and temperature fluctuations on nitrogen and organic matter cycling in the riparian zone, in order to help understand the relative

  5. Use of Soil Moisture Variability in Artificial Neural Network Retrieval of Soil Moisture

    Directory of Open Access Journals (Sweden)

    Bert Veenendaal

    2009-12-01

    Full Text Available Passive microwave remote sensing is one of the most promising techniques for soil moisture retrieval. However, the inversion of soil moisture from brightness temperature observations is not straightforward, as it is influenced by numerous factors such as surface roughness, vegetation cover, and soil texture. Moreover, the relationship between brightness temperature, soil moisture and the factors mentioned above is highly non-linear and ill-posed. Consequently, Artificial Neural Networks (ANNs have been used to retrieve soil moisture from microwave data, but with limited success when dealing with data different to that from the training period. In this study, an ANN is tested for its ability to predict soil moisture at 1 km resolution on different dates following training at the same site for a specific date. A novel approach that utilizes information on the variability of soil moisture, in terms of its mean and standard deviation for a (sub region of spatial dimension up to 40 km, is used to improve the current retrieval accuracy of the ANN method. A comparison between the ANN with and without the use of the variability information showed that this enhancement enables the ANN to achieve an average Root Mean Square Error (RMSE of around 5.1% v/v when using the variability information, as compared to around 7.5% v/v without it. The accuracy of the soil moisture retrieval was further improved by the division of the target site into smaller regions down to 4 km in size, with the spatial variability of soil moisture calculated from within the smaller region used in the ANN. With the combination of an ANN architecture of a single hidden layer of 20 neurons and the dual-polarized brightness temperatures as input, the proposed use of variability and sub-region methodology achieves an average retrieval accuracy of 3.7% v/v. Although this accuracy is not the lowest as comparing to the research in this field, the main contribution is the ability of ANN in

  6. Determining baselines and variability of elements in plants and soils near the Kenai National Wildlife Refuge, Alaska

    Science.gov (United States)

    Crock, J.G.; Severson, R.C.; Gough, L.P.

    1992-01-01

    Recent investigations on the Kenai Peninsula had two major objectives: (1) to establish elemental baseline concentrations ranges for native vegetation and soils; and, (2) to determine the sampling density required for preparing stable regional geochemical maps for various elements in native plants and soils. These objectives were accomplished using an unbalanced, nested analysis-of-variance (ANOVA) barbell sampling design. Hylocomium splendens (Hedw.) BSG (feather moss, whole plant), Picea glauca (Moench) Voss (white spruce, twigs and needles), and soil horizons (02 and C) were collected and analyzed for major and trace total element concentrations. Using geometric means and geometric deviations, expected baseline ranges for elements were calculated. Results of the ANOVA show that intensive soil or plant sampling is needed to reliably map the geochemistry of the area, due to large local variability. For example, producing reliable element maps of feather moss using a 50 km cell (at 95% probability) would require sampling densities of from 4 samples per cell for Al, Co, Fe, La, Li, and V, to more than 15 samples per cell for Cu, Pb, Se, and Zn.Recent investigations on the Kenai Peninsula had two major objectives: (1) to establish elemental baseline concentrations ranges for native vegetation and soils; and, (2) to determine the sampling density required for preparing stable regional geochemical maps for various elements in native plants and soils. These objectives were accomplished using an unbalanced, nested analysis-of-variance (ANOVA) barbell sampling design. Hylocomium splendens (Hedw.) BSG (feather moss, whole plant), Picea glauca (Moench) Voss (white spruce, twigs and needles), and soil horizons (02 and C) were collected and analyzed for major and trace total element concentrations. Using geometric means and geometric deviations, expected baseline ranges for elements were calculated. Results of the ANOVA show that intensive soil or plant sampling is needed to

  7. EXPERIMENTAL DETERMINATION OF VARIABILITY IN PERMEABILITY OF SANDY SILT SOIL MIXED WITH FLY ASH IN PROPORTIONATE

    OpenAIRE

    Rasna Sharma*, Dr. M.K. Trivedi

    2016-01-01

    This paper presents the experimental determination of variability in permeability of sandy silt soil by blending with fly ash. The grain size, porosity, structure of the soil, specific gravity of the soil, viscosity and temperature are important factors in varying the permeability of the soil. Permeability is the flow conduction property of the soil. The void ratio with in the soil plays a vital role in varying the permeability. By blending with finer grains like fly ash in the soil with sand...

  8. Comparaison of last centuries variability in the eastern and central Pacific reconstructed from massive coral geochemical tracers

    Science.gov (United States)

    Moreau, Melanie; Corrège, Thierry; Cole, Julie; Le Cornec, Florence; Edwards, Lawrence; Cheng, Hai; Charlier, Karine

    2014-05-01

    The tropical Pacific is under the influence of different climate modes (from the seasonal to the decadal scale) and, through teleconnections, affects the global climate. At the seasonal scale the latitudinal migration of the Intertropical Convergence Zone (ITCZ) drive the hydrological dynamic of the tropical zone. The tropical Pacific is also a place of strong and variable zonal gradients due to the El Niño Southern Oscillation phenomenon (ENSO) at the interannual scale. A good amount of data is available in the western and the central part of the Pacific to reconstruct climatic parameters such as sea surface temperature (SST) and sea surface salinity (SSS) while there is a striking lack of data in the eastern part. To better estimate the zonal gradients in the tropical Pacific and the different climatic processes in the last two centuries, we present geochemical results (Sr/Ca and δ18O) obtained from aragonitic coral skeletons (Porites genus) from Clipperton atoll (10° N, 109° W) and the Marquesas Islands (10° S, 140° W). Clipperton being the only atoll located in the northern part of the ITCZ latitudinal migration area, information about eastern Pacific hydrological cycle and advection can be obtained. On the other hand, the precise chronology of the Clipperton coral and the comparaison with the records from the Marquesas Islands allows us to calculate SST gradients between the eastern and central Pacific. We will discuss about the recent theory of an El Niño-like condition triggered by a slowdown of the equatorial Walker circulation under global warming. We will also discuss about the evolution (frequency and intensity) of the two differents 'flavours' of El Niño (e.g. the canonical eastern El Niño and the central El Niño Modoki) through the 20thcentury. Indeed the canonical El Niño is characterised by a maximum SST anomaly in the eastern Pacific while the El Niño Modoki is characterised by a maximum SST anomaly persisting in the central Pacific. A

  9. Accumulation, sources and health risks of trace metals in elevated geochemical background soils used for greenhouse vegetable production in southwestern China.

    Science.gov (United States)

    Zhang, Haidong; Huang, Biao; Dong, Linlin; Hu, Wenyou; Akhtar, Mohammad Saleem; Qu, Mingkai

    2017-03-01

    Greenhouse vegetable cultivation with substantive manure and fertilizer input on soils with an elevated geochemical background can accumulate trace metals in soils and plants leading to human health risks. Studies on trace metal accumulation over a land use shift duration in an elevated geochemical background scenario are lacking. Accumulation characteristics of seven trace metals in greenhouse soil and edible plants were evaluated along with an assessment of the health risk to the consumers. A total of 118 greenhouse surface soils (0-20cm) and 30 vegetables were collected from Kunming City, Yunnan Province, southwestern China, and analyzed for total Cd, Pb, Cu, Zn, As, Hg, and Cr content by ICP-MS and AFS. The trace metals were ordered Cu>Cd>Hg>Zn>Pb>As>Cr in greenhouse soils accumulation level, and the geo-accumulation index suggested the soil more severely polluted with Cd, Cu, Hg and Zn. The greenhouse and open-field soils had significant difference in Cd, Cr and Zn. The duration of shift from paddy to greenhouse land-use significantly influenced trace metal accumulation with a dramatic change during five to ten year greenhouse land-use, and continuous increase of Cd and Hg. A spatial pattern from north to south for Cd and Hg and a zonal pattern for Cu and Zn were found. An anthropogenic source primarily caused trace metal accumulation, where the principal component analysis/multiple linear regression indicated a contribution 61.2%. While the assessment showed no potential risk for children and adults, the hazard health risks index was greater than one for adolescents. The extended duration of land use as greenhouses caused the trace metal accumulation, rotation in land use should be promoted to reduce the health risks. Copyright © 2016. Published by Elsevier Inc.

  10. Geochemical association of Pu and Am in selected host-phases of contaminated soils from the UK and their susceptibility to chemical and microbiological leaching

    International Nuclear Information System (INIS)

    Kimber, Richard L.; Corkhill, Claire L.; Amos, Sean; Livens, Francis R.; Lloyd, Jonathan R.

    2015-01-01

    Understanding the biogeochemical behaviour and potential mobility of actinides in soils and groundwater is vital for developing remediation and management strategies for radionuclide-contaminated land. Pu is known to have a high Kd in soils and sediments, however remobilization of low concentrations of Pu remains a concern. Here, some of the physicochemical properties of Pu and the co-contaminant, Am, are investigated in contaminated soils from Aldermaston, Berkshire, UK, and the Esk Estuary, Cumbria, UK, to determine their potential mobility. Sequential extraction techniques were used to examine the host-phases of the actinides in these soils and their susceptibility to microbiological leaching was investigated using acidophilic sulphur-oxidising bacteria. Sequential extractions found the majority of 239,240 Pu associated with the highly refractory residual phase in both the Aldermaston (63.8–85.5 %) and Esk Estuary (91.9–94.5%) soils. The 241 Am was distributed across multiple phases including the reducible oxide (26.1–40.0%), organic (45.6–63.6%) and residual fractions (1.9–11.1%). Plutonium proved largely resistant to leaching from microbially-produced sulphuric acid, with a maximum 0.18% leached into solution, although up to 12.5% of the 241 Am was leached under the same conditions. If Pu was present as distinct oxide particles in the soil, then 241 Am, a decay product of Pu, would be expected to be physically retained in the particle. The differences in geochemical association and bioleachability of the two actinides suggest that this is not the case and hence, that significant Pu is not present as distinct particles. These data suggest the majority of Pu in the contaminated soils studied is highly recalcitrant to geochemical changes and is likely to remain immobile over significant time periods, even when challenged with aggressive “bioleaching” bacteria. - Highlights: • Pu in the contaminated soils is associated with the recalcitrant

  11. Spatial Variability and Geostatistical Prediction of Some Soil Hydraulic Coefficients of a Calcareous Soil

    Directory of Open Access Journals (Sweden)

    Ali Akbar Moosavi

    2017-02-01

    Full Text Available Introduction: Saturated hydraulic conductivity and the other hydraulic properties of soils are essential vital soil attributes that play role in the modeling of hydrological phenomena, designing irrigation-drainage systems, transportation of salts and chemical and biological pollutants within the soil. Measurement of these hydraulic properties needs some special instruments, expert technician, and are time consuming and expensive and due to their high temporal and spatial variability, a large number of measurements are needed. Nowadays, prediction of these attributes using the readily available soil data using pedotransfer functions or using the limited measurement with applying the geostatistical approaches has been receiving high attention. The study aimed to determine the spatial variability and prediction of saturated (Ks and near saturated (Kfs hydraulic conductivity, the power of Gardner equation (α, sorptivity (S, hydraulic diffusivity (D and matric flux potential (Фm of a calcareous soil. Material and Methods: The study was carried out on the soil series of Daneshkadeh located in the Bajgah Agricultural Experimental Station of Agricultural College, Shiraz University, Shiraz, Iran (1852 m above the mean sea level. This soil series with about 745 ha is a deep yellowish brow calcareous soil with textural classes of loam to clay. In the studied soil series 50 sampling locations with the sampling distances of 16, 8 , and 4 m were selected on the relatively regular sampling design. The saturated hydraulic conductivity (Ks, near saturated hydraulic conductivity (Kfs, the power of Gardner equation (α, sorptivity (S, hydraulic diffusivity (D and matric flux potential (Фm of the aforementioned sampling locations was determined using the Single Ring and Droplet methods. After, initial statistical processing, including a normality test of data, trend and stationary analysis of data, the semivariograms of each studied hydraulic attributes were

  12. Of the necessity of knowledge of the natural pedo-geochemical background content in the evaluation of the contamination of soils by trace elements.

    Science.gov (United States)

    Baize, D; Sterckeman, T

    2001-01-08

    In order to evaluate the contamination of the Dornach (Switzerland) site within the framework of the CEEM-Soil project, each participating team was allowed to take a maximum of 15 samples. The French team's sampling was organized in such a way as to answer the following questions: (i) what is the natural concentration of the soils at this site (local pedo-geochemical background content)?; (ii) what are the levels of Cd, Cu, Pb and Zn contamination of the soil?; (iii) what is the depth reached by the surface contamination that is derived from atmospheric fallout?; (iv) how is the contamination spread along the longest axis of the area under study? The relationships between total Fe and the trace metals have allowed local variations in the natural pedo-geochemical background content to be detected and thus permitted the anthropogenic contamination to be estimated. There would appear to be a low level of Pb contamination over all the site investigated (an increase of the order of 5-10 mg kg(-1) on the background level), limited to the surface humus-bearing layers. There is also a significant contamination by Cu over all of the site (an increase of the order of 30-40 mg kg(-1)). This contamination has remained in the surface horizons (0-20 cm). Very high Zn and Cd concentrations have been found in the four surface (0-4 cm) and deep horizons (15-70 cm) taken under the forest and very much lower values in the samples taken from cultivated soils. The most likely explanation is an unequal inheritance between the upper part of the site (wooded with thinner very clayey soils) and the lower cultivated part of the site (with thicker less clayey soils developed in a loamy material). For various reasons, it seems unlikely that a contamination of the wooded part should be so much higher than the cultivated part due to the interception of atmospheric dust by the trees. The local pedo-geochemical background Cd and Zn content of the upper wooded part proved to be clearly higher than

  13. ENSO and interdecadal climate variability over the last century documented by geochemical records of two coral cores from the South West Pacific

    Directory of Open Access Journals (Sweden)

    T. Ourbak

    2006-01-01

    Full Text Available The south west Pacific is affected by climatic phenomena such as ENSO (El Niño Southern Oscillation or the PDO (Pacific Decadal Oscillation. Near-monthly resolution calibrations of Sr/Ca, U/Ca and δ18Oc were made on corals taken from New Caledonia and Wallis Island. These geochemical variations could be linked to SST (sea surface temperature and SSS (sea surface salinity variations over the last two decades, itselves dependent on ENSO occurrences. On the other hand, near-half-yearly resolution over the last century smoothes seasonal and interannual climate signals, but emphasizes low frequency climate variability.

  14. Exploring innovative techniques for identifying geochemical elements as fingerprints of sediment sources in an agricultural catchment of Argentina affected by soil erosion.

    Science.gov (United States)

    Torres Astorga, Romina; de Los Santos Villalobos, Sergio; Velasco, Hugo; Domínguez-Quintero, Olgioly; Pereira Cardoso, Renan; Meigikos Dos Anjos, Roberto; Diawara, Yacouba; Dercon, Gerd; Mabit, Lionel

    2018-05-15

    Identification of hot spots of land degradation is strongly related with the selection of soil tracers for sediment pathways. This research proposes the complementary and integrated application of two analytical techniques to select the most suitable fingerprint tracers for identifying the main sources of sediments in an agricultural catchment located in Central Argentina with erosive loess soils. Diffuse reflectance Fourier transformed in the mid-infrared range (DRIFT-MIR) spectroscopy and energy-dispersive X-ray fluorescence (EDXRF) were used for a suitable fingerprint selection. For using DRIFT-MIR spectroscopy as fingerprinting technique, calibration through quantitative parameters is needed to link and correlate DRIFT-MIR spectra with soil tracers. EDXRF was used in this context for determining the concentrations of geochemical elements in soil samples. The selected tracers were confirmed using two artificial mixtures composed of known proportions of soil collected in different sites with distinctive soil uses. These fingerprint elements were used as parameters to build a predictive model with the whole set of DRIFT-MIR spectra. Fingerprint elements such as phosphorus, iron, calcium, barium, and titanium were identified for obtaining a suitable reconstruction of the source proportions in the artificial mixtures. Mid-infrared spectra produced successful prediction models (R 2  = 0.91) for Fe content and moderate useful prediction (R 2  = 0.72) for Ti content. For Ca, P, and Ba, the R 2 were 0.44, 0.58, and 0.59 respectively.

  15. Associations between soil variables and vegetation structure and composition of Caribbean dry forests

    Science.gov (United States)

    Elvia M. Melendez-Ackerman; Julissa Rojas-Sandoval; Danny S. Fernandez; Grizelle Gonzalez; Hana Lopez; Jose Sustache; Mariely Morales; Miguel Garcia-Bermudez; Susan Aragon

    2016-01-01

    Soil–vegetation associations have been understudied in tropical dry forests when compared to the amount of extant research on this issue in tropical wet forests. Recent studies assert that vegetation in tropical dry forests is highly heterogeneous and that soil variability may be a contributing factor. In this study, we evaluated the relationship between soil variables...

  16. effective hydraulic conductivity for a soil of variable pore size

    African Journals Online (AJOL)

    eobe

    Keywords: hydraulic conductivity, soil, infiltration, permeability, water. 1. INTRODUCTION. INTRODUCTION. INTRODUCTION. Accurate determination of hydraulic conductivity is very crucial for infiltration and runoff estimation. Factors which affect water infiltration in the soil include hydraulic conductivity, wetting front and soil.

  17. Evaluation of processes controlling the geochemical constituents in deep groundwater in Bangladesh: Spatial variability on arsenic and boron enrichment

    International Nuclear Information System (INIS)

    Halim, M.A.; Majumder, R.K.; Nessa, S.A.; Hiroshiro, Y.; Sasaki, K.; Saha, B.B.; Saepuloh, A.; Jinno, K.

    2010-01-01

    Forty-six deep groundwater samples from highly arsenic affected areas in Bangladesh were analyzed in order to evaluate the processes controlling geochemical constituents in the deep aquifer system. Spatial trends of solutes, geochemical modeling and principal component analysis indicate that carbonate dissolution, silicate weathering and ion exchange control the major-ion chemistry. The groundwater is dominantly of Na-Cl type brackish water. Approximately 17% of the examined groundwaters exhibit As concentrations higher than the maximum acceptable limit of 10 μg/L for drinking water. Strong correlation (R 2 = 0.67) of Fe with dissolved organic carbon (DOC) and positive saturation index of siderite suggests that the reductive dissolution of Fe-oxyhydroxide in presence of organic matter is considered to be the dominant process to release high content of Fe (median 0.31 mg/L) in the deep aquifer. In contrast, As is not correlated with Fe and DOC. Boron concentration in the 26% samples exceeds the standard limit of 500 μg/L, for water intended for human consumption. Negative relationships of B/Cl ratio with Cl and boron with Na/Ca ratio demonstrate the boron in deep groundwater is accompanied by brackish water and cation exchange within the clayey sediments.

  18. VARIABILITY OF ARABLE AND FOREST SOILS PROPERTIES ON ERODED SLOPES

    Directory of Open Access Journals (Sweden)

    Paweł Wiśniewski

    2014-10-01

    Full Text Available The basic method of reducing soil and land erosion is a change of land use, for example, from arable to forest. Particularly effective as a protective role – according to the Polish law – soil-protecting forests. The thesis presents differences in the deformation of the basic soil properties on moraine slopes, depending on land use. There has been presented the function and the efficiency of the soil-protecting forests in erosion control. The soil cross section transects and soil analysis displayed that soil-protecting forests are making an essential soil cover protection from degradation, inter alia, limiting the decrease of humus content, reduction of upper soil horizons and soil pedons layer. On the afforested slopes it was stated some clear changes of grain size and chemical properties of soils in relation to adjacent slopes agriculturally used.

  19. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive geochemical Transport in Variably Saturated Geologic Media

    International Nuclear Information System (INIS)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2004-01-01

    Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of mineral alteration in hydrothermal systems, waste disposal sites, acid mine drainage remediation, contaminant transport, and groundwater quality. A comprehensive non-isothermal multi-component reactive fluid flow and geochemical transport simulator, TOUGHREACT, has been developed. A wide range of subsurface thermo-physical-chemical processes is considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. The program can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions are considered, such as aqueous complexation, gas dissolution/exsolution, and cation exchange. Mineral dissolution/precipitation can proceed either subject to local equilibrium or kinetic conditions. Changes in porosity and permeability due to mineral dissolution and precipitation can be considered. Linear adsorption and decay can be included. For the purpose of future extensions, surface complexation by double layer model is coded in the program. Xu and Pruess (1998) developed a first version of a non-isothermal reactive geochemical transport model, TOUGHREACT, by introducing reactive geochemistry into the framework of the existing multi-phase fluid and heat flow code TOUGH2 (Pruess, 1991). Xu, Pruess, and their colleagues have applied the program to a variety of problems such as: (1) supergene copper enrichment (Xu et al, 2001), (2) caprock mineral alteration in a hydrothermal system (Xu and Pruess, 2001a), and (3) mineral trapping for CO 2 disposal in deep saline aquifers (Xu et al, 2003b and 2004a). For modeling the coupled thermal, hydrological, and chemical processes during heater

  20. Decreasing DOC trends in soil solution along the hillslopes at two IM sites in southern Sweden--geochemical modeling of organic matter solubility during acidification recovery.

    Science.gov (United States)

    Löfgren, Stefan; Gustafsson, Jon Petter; Bringmark, Lage

    2010-12-01

    Numerous studies report increased concentrations of dissolved organic carbon (DOC) during the last two decades in boreal lakes and streams in Europe and North America. Recently, a hypothesis was presented on how various spatial and temporal factors affect the DOC dynamics. It was concluded that declining sulphur deposition and thereby increased DOC solubility, is the most important driver for the long-term DOC concentration trends in surface waters. If this recovery hypothesis is correct, the DOC levels should increase both in the soil solution as well as in the surrounding surface waters as soil pH rises and the ionic strength declines due to the reduced input of SO(4)(2-) ions. In this project a geochemical model was set up to calculate the net humic charge and DOC solubility trends in soils during the period 1996-2007 at two integrated monitoring sites in southern Sweden, showing clear signs of acidification recovery. The Stockholm Humic Model was used to investigate whether the observed DOC solubility is related to the humic charge and to examine how pH and ionic strength influence it. Soil water data from recharge and discharge areas, covering both podzols and riparian soils, were used. The model exercise showed that the increased net charge following the pH increase was in many cases counteracted by a decreased ionic strength, which acted to decrease the net charge and hence the DOC solubility. Thus, the recovery from acidification does not necessarily have to generate increasing DOC trends in soil solution. Depending on changes in pH, ionic strength and soil Al pools, the trends might be positive, negative or indifferent. Due to the high hydraulic connectivity with the streams, the explanations to the DOC trends in surface waters should be searched for in discharge areas and peat lands. Copyright © 2010 Elsevier B.V. All rights reserved.

  1. Integrated assessment of space, time, and management-related variability of soil hydraulic properties

    Energy Technology Data Exchange (ETDEWEB)

    Es, H.M. van; Ogden, C.B.; Hill, R.L.; Schindelbeck, R.R.; Tsegaye, T.

    1999-12-01

    Computer-based models that simulate soil hydrologic processes and their impacts on crop growth and contaminant transport depend on accurate characterization of soil hydraulic properties. Soil hydraulic properties have numerous sources of variability related to spatial, temporal, and management-related processes. Soil type is considered to be the dominant source of variability, and parameterization is typically based on soil survey databases. This study evaluated the relative significance of other sources of variability: spatial and temporal at multiple scales, and management-related factors. Identical field experiments were conducted for 3 yr. at two sites in New York on clay loam and silt loam soils, and at two sites in Maryland on silt loam and sandy loam soils, all involving replicated plots with plow-till and no-till treatments. Infiltrability was determined from 2054 measurements using parameters, and Campbell's a and b parameters were determined based on water-retention data from 875 soil cores. Variance component analysis showed that differences among the sites were the most important source of variability for a (coefficient of variation, CV = 44%) and b (CV = 23%). Tillage practices were the most important source of variability for infiltrability (CV = 10%). For all properties, temporal variability was more significant than field-scale spatial variability. Temporal and tillage effects were more significant for the medium- and fine-textured soils, and correlated to initial soil water conditions. The parameterization of soil hydraulic properties solely based on soil type may not be appropriate for agricultural lands since soil-management factors are more significant. Sampling procedures should give adequate recognition to soil-management and temporal processes at significant sources of variability to avoid biased results.

  2. Moisture variability resulting from water repellency in Dutch soils

    NARCIS (Netherlands)

    Dekker, L.W.

    1998-01-01

    The present study suggests that many soils in the Netherlands, in natural as well as in agricultural areas, may be water repellent to some degree, challenging the common perception that soil water repellency is only an interesting aberration. When dry, water repellent soils resist or retard

  3. Spatial Variability of Soil Morphorlogical and Physico- Chemical ...

    African Journals Online (AJOL)

    user

    The available moisture of soil was very low thus water holding capacity (WHC) and wilting point (WP) of the soil was ... with spatial distribution of soil properties and its effect on ... Pore size and root .... nutrient and have better stability. Thus.

  4. Assessment of soil variability of South moravian region based on the satellite imagery

    Czech Academy of Sciences Publication Activity Database

    Novák, J.; Lukas, V.; Rodriguez Moreno, Fernando; Křen, J.

    2018-01-01

    Roč. 66, č. 1 (2018), s. 119-129 ISSN 1211-8516 Institutional support: RVO:86652079 Keywords : Coefficient of variation * lpis * ndvi * pca * RapidEye * Remote sensing * sentinel 2 * Soil variability Subject RIV: DF - Soil Science OBOR OECD: Soil science

  5. Nitrate and dissolved organic carbon mobilization in response to soil freezing variability

    Science.gov (United States)

    Colin B. Fuss; Charles T. Driscoll; Peter M. Groffman; John L. Campbell; Lynn M. Christenson; Timothy J. Fahey; Melany C. Fisk; Myron J. Mitchell; Pamela H. Templer; Jorge Durán; Jennifer L. Morse

    2016-01-01

    Reduced snowpack and associated increases in soil freezing severity resulting from winter climate change have the potential to disrupt carbon (C) and nitrogen (N) cycling in soils. We used a natural winter climate gradient based on elevation and aspect in a northern hardwood forest to examine the effects of variability in soil freezing depth, duration, and frequency on...

  6. Temporal variability of structure and hydraulic properties of topsoil of three soil types

    Czech Academy of Sciences Publication Activity Database

    Jirků, V.; Kodešová, R.; Nikodem, A.; Mühlhanselová, M.; Žigová, Anna

    204/205, August (2013), s. 43-58 ISSN 0016-7061 R&D Projects: GA ČR GA526/08/0434 Institutional support: RVO:67985831 Keywords : aggragate stability * soil -water retention curve * hydraulic conductivity * soil micromorphology * seasonal and annual variability Subject RIV: DF - Soil Science Impact factor: 2.509, year: 2013

  7. Temporal variability of selected chemical and physical propertires of topsoil of three soil types

    Czech Academy of Sciences Publication Activity Database

    Jirků, V.; Kodešová, R.; Nikodem, A.; Mühlhanselová, M.; Žigová, Anna

    2013-01-01

    Roč. 15, - (2013) ISSN 1607-7962. [EGU General Assembly /10./. 07.04.2013-12.04.2013, Vienna] R&D Projects: GA ČR GA526/08/0434 Institutional support: RVO:67985831 Keywords : soil properties * soil types * temporal variability Subject RIV: DF - Soil Science http://meetingorganizer.copernicus.org/EGU2013/EGU2013-7650-1.pdf

  8. Generalized Density-Corrected Model for Gas Diffusivity in Variably Saturated Soils

    DEFF Research Database (Denmark)

    Chamindu, Deepagoda; Møldrup, Per; Schjønning, Per

    2011-01-01

    models. The GDC model was further extended to describe two-region (bimodal) soils and could describe and predict Dp/Do well for both different soil aggregate size fractions and variably compacted volcanic ash soils. A possible use of the new GDC model is engineering applications such as the design...... of highly compacted landfill site caps....

  9. The study of operating variables in soil washing with EDTA

    International Nuclear Information System (INIS)

    Zou Zeli; Qiu Rongliang; Zhang Weihua; Dong Hanying; Zhao Zhihao; Zhang Tao; Wei Xiange; Cai Xinde

    2009-01-01

    This study discusses the operating variables for removal of metals from soils using EDTA, including the type of EDTA, reaction time, solution pH, dose, temperature, agitation, ultrasound and number of extractions. For As, Cd, Cu, Pb and Zn, the removal efficiency order was: H 4 -EDTA > Na 2 EDTA > (NH 4 ) 2 EDTA. At low EDTA concentrations the removal increased progressively with increasing dose while above 0.4 mmol/g only small increases in extraction efficiency were observed. EDTA induced a two-step process including a rapid desorption within the first hour, and a gradual release in the following hours. The extraction efficiency of metals decreased with increasing pH in the range of 2-10. Consecutive extractions using low concentrations were more effective than a single extraction with concentrated EDTA if the same dose of EDTA was used. - Consecutive extractions using low concentrations are more effective than a single extraction with concentrated EDTA if the same dose of EDTA is used

  10. Microbial and geochemical assessment of bauxitic un-mined and post-mined chronosequence soils from Mocho Mountains, Jamaica.

    Science.gov (United States)

    Lewis, Dawn E; Chauhan, Ashvini; White, John R; Overholt, Will; Green, Stefan J; Jasrotia, Puja; Wafula, Denis; Jagoe, Charles

    2012-10-01

    Microorganisms are very sensitive to environmental change and can be used to gauge anthropogenic impacts and even predict restoration success of degraded environments. Here, we report assessment of bauxite mining activities on soil biogeochemistry and microbial community structure using un-mined and three post-mined sites in Jamaica. The post-mined soils represent a chronosequence, undergoing restoration since 1987, 1997, and 2007. Soils were collected during dry and wet seasons and analyzed for pH, organic matter (OM), total carbon (TC), nitrogen (TN), and phosphorus. The microbial community structure was assessed through quantitative PCR and massively parallel bacterial ribosomal RNA (rRNA) gene sequencing. Edaphic factors and microbial community composition were analyzed using multivariate statistical approaches and revealed a significant, negative impact of mining on soil that persisted even after greater than 20 years of restoration. Seasonal fluctuations contributed to variation in measured soil properties and community composition, but they were minor in comparison to long-term effects of mining. In both seasons, post-mined soils were higher in pH but OM, TC, and TN decreased. Bacterial rRNA gene analyses demonstrated a general decrease in diversity in post-mined soils and up to a 3-log decrease in rRNA gene abundance. Community composition analyses demonstrated that bacteria from the Proteobacteria (α, β, γ, δ), Acidobacteria, and Firmicutes were abundant in all soils. The abundance of Firmicutes was elevated in newer post-mined soils relative to the un-mined soil, and this contrasted a decrease, relative to un-mined soils, in proteobacterial and acidobacterial rRNA gene abundances. Our study indicates long-lasting impacts of mining activities to soil biogeochemical and microbial properties with impending loss in soil productivity.

  11. The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

    Science.gov (United States)

    Reeves, J. B.; Smith, D.B.

    2009-01-01

    In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east-west across the USA, and north-south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0-5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (Ctotal, Ccarbonate and Corganic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000-400 cm-1) and near-infrared (10,000-4000 cm-1) at 4 cm-1 resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional

  12. Variability in urban soils influences the health and growth of native tree seedlings

    Science.gov (United States)

    Clara C. Pregitzer; Nancy F. Sonti; Richard A. Hallett

    2016-01-01

    Reforesting degraded urban landscapes is important due to the many benefits urban forests provide. Urban soils are highly variable, yet little is known about how this variability in urban soils influences tree seedling performance and survival. We conducted a greenhouse study to assess health, growth, and survival of four native tree species growing in native glacial...

  13. The Spatial Variability of Soil Dehydrogenase Activity: A Survey in Urban Soils

    OpenAIRE

    Kizilkaya, Ridvan; Aşkin, Tayfun

    2007-01-01

    Information on soil microorganisms and their activity used to determine microbiological characteristics are very important for soil quality and productivity. Studies of enzyme activities provide information on the biochemical processes occurring in soil. There is growing evidence that soil biological parameters may be potential and sensitive indicators of soil ecological conditions and soil management. Soil microbiological parameters may be evaluated statistically due to application of geosta...

  14. Modeling temporal and large-scale spatial variability of soil respiration from soil water availability, temperature and vegetation productivity indices

    Science.gov (United States)

    Reichstein, Markus; Rey, Ana; Freibauer, Annette; Tenhunen, John; Valentini, Riccardo; Banza, Joao; Casals, Pere; Cheng, Yufu; Grünzweig, Jose M.; Irvine, James; Joffre, Richard; Law, Beverly E.; Loustau, Denis; Miglietta, Franco; Oechel, Walter; Ourcival, Jean-Marc; Pereira, Joao S.; Peressotti, Alessandro; Ponti, Francesca; Qi, Ye; Rambal, Serge; Rayment, Mark; Romanya, Joan; Rossi, Federica; Tedeschi, Vanessa; Tirone, Giampiero; Xu, Ming; Yakir, Dan

    2003-12-01

    Field-chamber measurements of soil respiration from 17 different forest and shrubland sites in Europe and North America were summarized and analyzed with the goal to develop a model describing seasonal, interannual and spatial variability of soil respiration as affected by water availability, temperature, and site properties. The analysis was performed at a daily and at a monthly time step. With the daily time step, the relative soil water content in the upper soil layer expressed as a fraction of field capacity was a good predictor of soil respiration at all sites. Among the site variables tested, those related to site productivity (e.g., leaf area index) correlated significantly with soil respiration, while carbon pool variables like standing biomass or the litter and soil carbon stocks did not show a clear relationship with soil respiration. Furthermore, it was evidenced that the effect of precipitation on soil respiration stretched beyond its direct effect via soil moisture. A general statistical nonlinear regression model was developed to describe soil respiration as dependent on soil temperature, soil water content, and site-specific maximum leaf area index. The model explained nearly two thirds of the temporal and intersite variability of soil respiration with a mean absolute error of 0.82 μmol m-2 s-1. The parameterized model exhibits the following principal properties: (1) At a relative amount of upper-layer soil water of 16% of field capacity, half-maximal soil respiration rates are reached. (2) The apparent temperature sensitivity of soil respiration measured as Q10 varies between 1 and 5 depending on soil temperature and water content. (3) Soil respiration under reference moisture and temperature conditions is linearly related to maximum site leaf area index. At a monthly timescale, we employed the approach by [2002] that used monthly precipitation and air temperature to globally predict soil respiration (T&P model). While this model was able to

  15. Modelling temporal and large-scale spatial variability of soil respiration from soil water availability, temperature and vegetation productivity indices

    Science.gov (United States)

    Reichstein, M.; Rey, A.; Freibauer, A.; Tenhunen, J.; Valentini, R.; Soil Respiration Synthesis Team

    2003-04-01

    Field-chamber measurements of soil respiration from 17 different forest and shrubland sites in Europe and North America were summarized and analyzed with the goal to develop a model describing seasonal, inter-annual and spatial variability of soil respiration as affected by water availability, temperature and site properties. The analysis was performed at a daily and at a monthly time step. With the daily time step, the relative soil water content in the upper soil layer expressed as a fraction of field capacity was a good predictor of soil respiration at all sites. Among the site variables tested, those related to site productivity (e.g. leaf area index) correlated significantly with soil respiration, while carbon pool variables like standing biomass or the litter and soil carbon stocks did not show a clear relationship with soil respiration. Furthermore, it was evidenced that the effect of precipitation on soil respiration stretched beyond its direct effect via soil moisture. A general statistical non-linear regression model was developed to describe soil respiration as dependent on soil temperature, soil water content and site-specific maximum leaf area index. The model explained nearly two thirds of the temporal and inter-site variability of soil respiration with a mean absolute error of 0.82 µmol m-2 s-1. The parameterised model exhibits the following principal properties: 1) At a relative amount of upper-layer soil water of 16% of field capacity half-maximal soil respiration rates are reached. 2) The apparent temperature sensitivity of soil respiration measured as Q10 varies between 1 and 5 depending on soil temperature and water content. 3) Soil respiration under reference moisture and temperature conditions is linearly related to maximum site leaf area index. At a monthly time-scale we employed the approach by Raich et al. (2002, Global Change Biol. 8, 800-812) that used monthly precipitation and air temperature to globally predict soil respiration (T

  16. Geochemical and mineralogical investigation of domestic archaeological soil features at the Tiel-Passewaaij site, The Netherlands

    NARCIS (Netherlands)

    Oonk, S.; Slomp, C.P.; Huisman, D.J.; Vriend, S.P.

    2008-01-01

    Archaeological soil features can be defined as areas of staining in ancient cultural soil horizons and are frequently used in surveys to locate sites and activity areas. Visual observation of these features, however, provides only limited information on their origin and the processes leading to

  17. Geochemical and mineralogical investigation of domestic archaeological soil features at the Tiel-Passewaaij sit, The Netherlands

    NARCIS (Netherlands)

    Oonk, S.; Slomp, C.P.; Huisman, D.J.; Vriend, S.P.

    2009-01-01

    Archaeological soil features can be defined as areas of staining in ancient cultural soil horizons and are frequently used in surveys to locate sites and activity areas. Visual observation of these features, however, provides only limited information on their origin and the processes leading to

  18. Geochemical and mineralogical investigation of domestic archaeological soil features at the Tiel-Passewaaij site, The Netherlands

    NARCIS (Netherlands)

    Oonk, S.; Slomp, C.P.; Huisman, D.J.; Vriend, S.P.

    2009-01-01

    Archaeological soil features can be defined as areas of staining in ancient cultural soil horizons and are frequently used in surveys to locate sites and activity areas. Visual observation of these features, however, provides only limited information on their origin and the processes leading to

  19. Multiscale analysis of the spatial variability of heavy metals and organic matter in soils and groundwater across Spain

    Science.gov (United States)

    Luque-Espinar, J. A.; Pardo-Igúzquiza, E.; Grima-Olmedo, J.; Grima-Olmedo, C.

    2018-06-01

    During the last years there has been an increasing interest in assessing health risks caused by exposure to contaminants found in soil, air, and water, like heavy metals or emerging contaminants. This work presents a study on the spatial patterns and interaction effects among relevant heavy metals (Sb, As and Pb) that may occur together in different minerals. Total organic carbon (TOC) have been analyzed too because it is an essential component in the regulatory mechanisms that control the amount of metal in soils. Even more, exposure to these elements is associated with a number of diseases and environmental problems. These metals can have both natural and anthropogenic origins. A key component of any exposure study is a reliable model of the spatial distribution the elements studied. A geostatistical analysis have been performed in order to show that selected metals are auto-correlated and cross-correlated and type and magnitude of such cross-correlation varies depending on the spatial scale under consideration. After identifying general trends, we analyzed the residues left after subtracting the trend from the raw variables. Three scales of variability were identified (compounds or factors) with scales of 5, 35 and 135 km. The first factor (F1) basically identifies anomalies of natural origin but, in some places, of anthropogenics origin as well. The other two are related to geology (F2 and F3) although F3 represents more clearly geochemical background related to large lithological groups. Likewise, mapping of two major structures indicates that significant faults have influence on the distribution of the studied elements. Finally, influence of soil and lithology on groundwater by means of contingency analysis was assessed.

  20. Temporal variability in Cu speciation, phytotoxicity, and soil microbial activity of Cu-polluted soils as affected by elevated temperature.

    Science.gov (United States)

    Fu, Qing-Long; Weng, Nanyan; Fujii, Manabu; Zhou, Dong-Mei

    2018-03-01

    Global warming has obtained increasing attentions due to its multiple impacts on agro-ecosystem. However, limited efforts had been devoted to reveal the temporal variability of metal speciation and phytotoxicity of heavy metal-polluted soils affected by elevated temperature under the global warming scenario. In this study, effects of elevated temperature (15 °C, 25 °C, and 35 °C) on the physicochemical properties, microbial metabolic activities, and phytotoxicity of three Cu-polluted soils were investigated by a laboratory incubation study. Soil physicochemical properties were observed to be significantly altered by elevated temperature with the degree of temperature effect varying in soil types and incubation time. The Biolog and enzymatic tests demonstrated that soil microbial activities were mainly controlled and decreased with increasing incubation temperature. Moreover, plant assays confirmed that the phytotoxicity and Cu uptake by wheat roots were highly dependent on soil types but less affected by incubation temperature. Overall, the findings in this study have highlighted the importance of soil types to better understand the temperature-dependent alternation of soil properties, Cu speciation and bioavailability, as well as phytotoxicity of Cu-polluted soils under global warming scenario. The present study also suggests the necessary of investigating effects of soil types on the transport and accumulation of toxic elements in soil-crop systems under global warming scenario. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Geochemical evidence for African dust inputs to soils of western Atlantic islands: Barbados, the Bahamas, and Florida

    Science.gov (United States)

    Muhs, D.R.; Budahn, J.R.; Prospero, J.M.; Carey, S.N.

    2007-01-01

    We studied soils on high-purity limestones of Quaternary age on the western Atlantic Ocean islands of Barbados, the Florida Keys, and the Bahamas. Potential soil parent materials in this region, external to the carbonate substrate, include volcanic ash from the island of St. Vincent (near Barbados), volcanic ash from the islands of Dominica and St. Lucia (somewhat farther from Barbados), the fine-grained component of distal loess from the lower Mississippi River Valley, and wind-transported dust from Africa. These four parent materials can be differentiated using trace elements (Sc, Cr, Th, and Zr) and rare earth elements that have minimal mobility in the soil-forming environment. Barbados soils have compositions that indicate a complex derivation. Volcanic ash from the island of St. Vincent appears to have been the most important influence, but African dust is a significant contributor, and even Mississippi River valley loess may be a very minor contributor to Barbados soils. Soils on the Florida Keys and islands in the Bahamas appear to have developed mostly from African dust, but Mississippi River valley loess may be a significant contributor. Our results indicate that inputs of African dust are more important to the genesis of soils on islands in the western Atlantic Ocean than previously supposed. We hypothesize that African dust may also be a major contributor to soils on other islands of the Caribbean and to soils in northern South America, central America, Mexico, and the southeastern United States. Dust inputs to subtropical and tropical soils in this region increase both nutrient-holding capacity and nutrient status and thus may be critical in sustaining vegetation. Copyright 2007 by the American Geophysical Union.

  2. Variability of soil moisture and its relationship with surface albedo ...

    Indian Academy of Sciences (India)

    Time (s). A. Amplitude of the soil thermal wave at any depth (. ◦. C). A0. Amplitude of thermal ... system, soil moisture has a long memory (Pielke et al 1999; Wu et al .... measurements of the short wave radiation compo- nents as follows: α = Su.

  3. Variability of soil moisture and its relationship with surface albedo

    Indian Academy of Sciences (India)

    Continuous observation data collected over the year 2008 at Astronomical Observatory, Thiruvananthapuram in south Kerala (76° 59′E longitude and 8° 30′N latitude) are used to study the diurnal, monthly and seasonal soil moisture variations. The effect of rainfall on diurnal and seasonal soil moisture is discussed.

  4. A Simple Model of the Variability of Soil Depths

    Directory of Open Access Journals (Sweden)

    Fang Yu

    2017-06-01

    Full Text Available Soil depth tends to vary from a few centimeters to several meters, depending on many natural and environmental factors. We hypothesize that the cumulative effect of these factors on soil depth, which is chiefly dependent on the process of biogeochemical weathering, is particularly affected by soil porewater (i.e., solute transport and infiltration from the land surface. Taking into account evidence for a non-Gaussian distribution of rock weathering rates, we propose a simple mathematical model to describe the relationship between soil depth and infiltration flux. The model was tested using several areas in mostly semi-arid climate zones. The application of this model demonstrates the use of fundamental principles of physics to quantify the coupled effects of the five principal soil-forming factors of Dokuchaev.

  5. The variability of standard artificial soils: Behaviour, extractability and bioavailability of organic pollutants

    International Nuclear Information System (INIS)

    Hofman, Jakub; Hovorková, Ivana; Semple, Kirk T.

    2014-01-01

    Highlights: • Artificial soils from different laboratories revealed different fates, behaviour and bioavailability of lindane and phenanthrene. • Lindane behaviour was related to organic carbon. • Phenanthrene behaviour was significantly affected by degrading microorganisms from peat. • Sterilization of artificial soils might reduce unwanted variability. -- Abstract: Artificial soil is an important standard medium and reference material for soil ecotoxicity bioassays. Recent studies have documented the significant variability of their basic properties among different laboratories. Our study investigated (i) the variability of ten artificial soils from different laboratories by means of the fate, extractability and bioavailability of phenanthrene and lindane, and (ii) the relationships of these results to soil properties and ageing. Soils were spiked with 14 C-phenanthrene and 14 C-lindane, and the total residues, fractions extractable by hydroxypropyl-β-cyclodextrin, and the fractions of phenanthrene mineralizable by bacteria were determined after 1, 14, 28 and 56 days. Significant temporal changes in total residues and extractable and mineralizable fractions were observed for phenanthrene, resulting in large differences between soils after 56 days. Phenanthrene mineralization by indigenous peat microorganisms was suggested as the main driver of that, outweighing the effects of organic matter. Lindane total residues and extractability displayed much smaller changes over time and smaller differences between soils related to organic matter. Roughly estimated, the variability between the artificial soils was comparable to natural soils. The implications of such variability for the results of toxicity tests and risk assessment decisions should be identified. We also suggested that the sterilization of artificial soils might reduce unwanted variability

  6. The variability of standard artificial soils: Behaviour, extractability and bioavailability of organic pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Hofman, Jakub, E-mail: hofman@recetox.muni.cz [Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Science, Masaryk University, Kamenice 753/5, Brno CZ-62500 (Czech Republic); Hovorková, Ivana [Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Science, Masaryk University, Kamenice 753/5, Brno CZ-62500 (Czech Republic); Semple, Kirk T. [Lancaster Environment Centre, Lancaster University, Lancaster LA1 4YQ (United Kingdom)

    2014-01-15

    Highlights: • Artificial soils from different laboratories revealed different fates, behaviour and bioavailability of lindane and phenanthrene. • Lindane behaviour was related to organic carbon. • Phenanthrene behaviour was significantly affected by degrading microorganisms from peat. • Sterilization of artificial soils might reduce unwanted variability. -- Abstract: Artificial soil is an important standard medium and reference material for soil ecotoxicity bioassays. Recent studies have documented the significant variability of their basic properties among different laboratories. Our study investigated (i) the variability of ten artificial soils from different laboratories by means of the fate, extractability and bioavailability of phenanthrene and lindane, and (ii) the relationships of these results to soil properties and ageing. Soils were spiked with {sup 14}C-phenanthrene and {sup 14}C-lindane, and the total residues, fractions extractable by hydroxypropyl-β-cyclodextrin, and the fractions of phenanthrene mineralizable by bacteria were determined after 1, 14, 28 and 56 days. Significant temporal changes in total residues and extractable and mineralizable fractions were observed for phenanthrene, resulting in large differences between soils after 56 days. Phenanthrene mineralization by indigenous peat microorganisms was suggested as the main driver of that, outweighing the effects of organic matter. Lindane total residues and extractability displayed much smaller changes over time and smaller differences between soils related to organic matter. Roughly estimated, the variability between the artificial soils was comparable to natural soils. The implications of such variability for the results of toxicity tests and risk assessment decisions should be identified. We also suggested that the sterilization of artificial soils might reduce unwanted variability.

  7. Vegetation-induced soil water repellency as a strategy in arid ecosystems. A geochemical approach in Banksia woodlands (SW Australia)

    Science.gov (United States)

    Muñoz-Rojas, Miriam; Jiménez-Morillo, Nicasio T.; González-Pérez, Jose Antonio; Zavala, Lorena M.; Stevens, Jason; Jordan, Antonio

    2016-04-01

    Introduction Banksia woodlands (BW) are iconic ecosystems of Western Australia (WA) composed by an overstorey dominated by Proteaceae, e.g. Banksia menziesii and Banksia attenuata, in combination with other species, such as Eucalyptus spp., Verticordia spp. or Melaleuca spp. Although located in very poor dune soils, BW provide numerous ecosystem services and sustain a high biodiversity. In this area, annual rainfall is relatively high (about 800 mm) but permeability of the sandy substrate leads to a functionally arid ecosystem. Currently, BW are threatened by sand mining activities and urban expansion; therefore conservation and restoration of these woodlands are critical. Despite numerous efforts, the success of restoration plans is usually poor mostly due to the high sensitivity to drought stress and poor seedling survival rates (5-30%) (Benigno et al., 2014). A characteristic feature of BW is their root architecture, formed by a proteoid (cluster) system that spreads to form thick mats below the soil surface, favouring the uptake of nutrients (especially, P), and preventing soil erosion. Root exudates are related to numerous plant functions, as they facilitate penetration of roots in soil and enhance the extraction of scarce mineral nutrients and its further assimilation. Exudates may also interact directly with soil or indirectly through microbial mediated events being also related to soil water repellency (SWR; Lozano et al, 2014). Knowledge about the specific compounds able to induce SWR is limited (Doerr et al., 2000), but it is generally accepted that is caused by organic molecules coating the surface of soil mineral particles and aggregates (Jordán et al., 2013). Proteaceae release short-chained organic acids to enhance phosphate acquisition, which have been also reported to be related with SWR (Jiménez-Morillo et al., 2014). It is hypothesized that disruption of water dynamics in mature BW soils is underlying the failure of restoration plans. This

  8. [Effects of variable temperature on organic carbon mineralization in typical limestone soils].

    Science.gov (United States)

    Wang, Lian-Ge; Gao, Yan-Hong; Ding, Chang-Huan; Ci, En; Xie, De-Ti

    2014-11-01

    Soil sampling in the field and incubation experiment in the laboratory were conducted to investigate the responses of soil organic carbon (SOC) mineralization to variable temperature regimes in the topsoil of limestone soils from forest land and dry land. Two incubated limestone soils were sampled from the 0-10 cm layers of typical forest land and dry land respectively, which were distributed in Tianlong Mountain area of Puding county, Guizhou province. The soils were incubated for 56 d under two different temperature regimes including variable temperature (range: 15-25 degrees C, interval: 12 h) and constant temperature (20 degrees C), and the cumulative temperature was the same in the two temperature treatments. In the entire incubation period (56 d), the SOC cumulative mineralization (63.32 mg x kg(-1)) in the limestone soil from dry land (SH) under the variable temperature was lower than that (63.96 mg x kg(-1)) at constant 20 degrees C, and there was no significant difference in the SOC cumulative mineralization between the variable and constant temperature treatments (P variable temperature was significantly lower than that (209.52 mg x kg(-1)) at constant 20 degrees C. The results indicated that the responses of SOC mineralization to the variable temperature were obviously different between SL and SH soils. The SOC content and composition were significantly different between SL and SH soils affected by vegetation and land use type, which suggested that SOC content and composition were important factors causing the different responses of SOC mineralization to variable temperature between SL and SH soils. In addition, the dissolved organic carbon (DOC) content of two limestone soils were highly (P variable temperature mainly influenced SOC mineralization by changing microbial community activity rather than by changing microbial quantity.

  9. Geochemical and Radiological Characteristics of Harvested Rainwater and Surficial Soil in El-Alamein-Alam El-Rum area, Western Mediterranean Coastal Zone, Egypt

    International Nuclear Information System (INIS)

    El-Sayed, S.A.; Ramadan, A.A.; Salama, M.H.; Diab, M.

    2015-01-01

    This study deals with investigating the geochemical and radiological properties of surficial soil and harvested rainwater in Al-Alamein-Alam El-Rum area located in the western Mediterranean coastal zone of Egypt. Forty five water and soil samples were investigated. The surficial soil has heterogeneous physical, chemical and radiological properties and the texture was dominated by sand clayey loam and sandy loam. The salinities were varied from non-saline (EC=1.25 dS/m) to strongly saline (EC=38 dS/m) and the pH ranged from slightly alkaline (7.6) to strongly alkaline (8.95). The major part of soil samples has chemical composition dominated by Na + and Cl - ions and occasionally Mg2 + and SO 4 2 - ions indicating the existence of different chemical facies. The radioactivity level indicated the dominance of 40 K followed by 226 Ra and 232 Th radionuclides and the average radioactivities in the surficial soil samples were 16.59, 11.75, 290.80 and 1.79 Bq/kg for 226 Ra, 232 Th, 40 K and 137 Cs, respectively. The heterogeneity in major ion and radioactivity concentrations were attributed to the variation in chemical and radionuclide compositions of the exposed rocks in the area where the soils are originated. The harvested rainwater is fresh (EC ranged from 0.24 to 0.83 dS/m) and has alkalinity nature varied between slightly alkaline (pH=7.27) and alkaline (pH=8.69). Its chemical composition was prevailed by Na + and HCO 3 - ions and sometimes Ca 2+ and/or Mg 2+ and SO 4 2 - ions reflecting the presence of various hydrochemical facies. It shows the same trend of radionuclide dominance of soils ( 40 K > 226 Ra > 232 Th). The radioactivity concentrations in harvested water samples were 19, 1.01 and 14.0 Bq/l for 226 Ra, 232 Th and 40 K, respectively, while the water samples have 137 Cs concentrations under the detection limit and the water rocks interaction is the main reason causing the variation in major ions and radionuclide concentrations. The obtained chemical and

  10. Response of three soil water sensors to variable solution electrical conductivity in different soils

    Science.gov (United States)

    Commercial dielectric soil water sensors may improve management of irrigated agriculture by providing continuous field soil water information. Use of these sensors is partly limited by sensor sensitivity to variations in soil salinity and texture, which force expensive, time consuming, soil specific...

  11. An examination of the spatial variability of CO2 in the profile of managed forest soils

    International Nuclear Information System (INIS)

    Black, M.; Kellman, L.; Beltrami, H.

    2005-01-01

    Soil carbon dioxide (CO 2 ) profiles are typically used in soil-gas exchange studies. Although surface flux measuring methods may be more efficient for deriving surface soil CO 2 exchange budgets, they do not provide enough information about the generation of gas through depth. This poses a challenge in quantifying the CO 2 generated from different zones and soil carbon pools through time. The combination of subsurface concentration profiles and estimates of soil diffusivity reveal where CO 2 is being generated in the soil. This combined approach offers greater awareness into processes controlling CO 2 production in soils through depth, and clarifies how soil CO 2 exchange processes in these ecosystems can be changed by management regimes and climate change. Although information about spatial variability in subsurface concentrations within forested soils is limited, it is assumed to be high because of the high spatial variability in soil CO 2 flux estimates and the large variation in vegetation distribution and topography within sites. In this study, the soil CO 2 profile was monitored during the fall of 2004 at depths of 0, 5, 20 and 35 cm at 10 microsites of a clear-cut and an 80 year old intact mixed forest in Atlantic Canada. Microsites were about 10 meters apart and represented a range of microtopographical conditions that typically encompass extremes in soil CO 2 profile patterns. Preliminary results reveal predictable patterns in concentration profiles through depth, and increasing CO 2 concentration with depth, consistent with a large soil source of CO 2 . The significant variability in the soil carbon profile between microsites in the clear-cut and intact forest sites will be investigated to determine if distinct microsite patterns can be identified. The feasibility of using this method for providing process-based versus soil C exchange budgeting information at forested sites will also be examined

  12. Effect of land-use practice on soil moisture variability for soils covered with dense forest vegetation of Puerto Rico

    Science.gov (United States)

    Tsegaye, T.; Coleman, T.; Senwo, Z.; Shaffer, D.; Zou, X.

    1998-01-01

    Little is known about the landuse management effect on soil moisture and soil pH distribution on a landscape covered with dense tropical forest vegetation. This study was conducted at three locations where the history of the landuse management is different. Soil moisture was measured using a 6-cm three-rod Time Domain Reflectometery (TDR) probe. Disturbed soil samples were taken from the top 5-cm at the up, mid, and foothill landscape position from the same spots where soil moisture was measured. The results showed that soil moisture varies with landscape position and depth at all three locations. Soil pH and moisture variability were found to be affected by the change in landuse management and landscape position. Soil moisture distribution usually expected to be relatively higher in the foothill (P3) area of these forests than the uphill (P1) position. However, our results indicated that in the Luquillo and Guanica site the surface soil moisture was significantly higher for P1 than P3 position. These suggest that the surface and subsurface drainage in these two sites may have been poor due to the nature of soil formation and type.

  13. Modeling Short-Range Soil Variability and its Potential Use in Variable-Rate Treatment of Experimental Plots

    Directory of Open Access Journals (Sweden)

    A Moameni

    2011-02-01

    Full Text Available Abstract In Iran, the experimental plots under fertilizer trials are managed in such a way that the whole plot area uniformly receives agricultural inputs. This could lead to biased research results and hence to suppressing of the efforts made by the researchers. This research was conducted in a selected site belonging to the Gonbad Agricultural Research Station, located in the semiarid region, northeastern Iran. The aim was to characterize the short-range spatial variability of the inherent and management-depended soil properties and to determine if this variation is large and can be managed at practical scales. The soils were sampled using a grid 55 m apart. In total, 100 composite soil samples were collected from topsoil (0-30 cm and were analyzed for calcium carbonate equivalent, organic carbon, clay, available phosphorus, available potassium, iron, copper, zinc and manganese. Descriptive statistics were applied to check data trends. Geostatistical analysis was applied to variography, model fitting and contour mapping. Sampling at 55 m made it possible to split the area of the selected experimental plot into relatively uniform areas that allow application of agricultural inputs with variable rates. Keywords: Short-range soil variability, Within-field soil variability, Interpolation, Precision agriculture, Geostatistics

  14. Kinetics and mechanisms of metal retention/release in geochemical processes in soil. 1997 annual progress report

    International Nuclear Information System (INIS)

    Taylor, R.W.

    1997-01-01

    'Remediation of soils polluted with heavy metals is a major challenge facing the nation. This is especially so at many DOE facilities and other superfund sites. In many cases, speciation of the metals is inaccurate and difficult and the mechanisms by which the metals are retained/released in soils over long times are poorly understood. Consequently, the long-term fate of metals in soils cannot be precisely predicted and often, the remediation recommendations and techniques that are employed to clean up soils may be ineffective or unnecessary. Accordingly, the authors are proposing work to generate basic knowledge on the kinetics and mechanism(s) of heavy metal retention/release by soil mineral colloids as affected by inorganic anion. The nature of the interaction of Cd(II), Co(II), Cr(VI), Cu(II), Ni(II) and Pb(II) with pure soil minerals and extracted soil clays will be investigated. The colloids will be characterized in terms of surface area, surface charge and surface site density. They will be used to study the effect(s) of pH, phosphate rate, and temperature on metals retention/release. The experiments will involve using various kinetic and isothermic sorption equations as models to describe the data thus acquired. The spectroscopic methods will involve using extended x-ray absorption fine structure spectroscopy (EXAFS) and Fourier Transform Infrared Spectroscopy (FTIR). The data generated from the proposed study will assist in designing better remediation strategies to effectively clean up toxic heavy metal contaminated soils at DOE facilities and other superfund sites.'

  15. Mapping spatial variability of soil salinity in a coastal paddy field based on electromagnetic sensors.

    Science.gov (United States)

    Guo, Yan; Huang, Jingyi; Shi, Zhou; Li, Hongyi

    2015-01-01

    In coastal China, there is an urgent need to increase land area for agricultural production and urban development, where there is a rapid growing population. One solution is land reclamation from coastal tidelands, but soil salinization is problematic. As such, it is very important to characterize and map the within-field variability of soil salinity in space and time. Conventional methods are often time-consuming, expensive, labor-intensive, and unpractical. Fortunately, proximal sensing has become an important technology in characterizing within-field spatial variability. In this study, we employed the EM38 to study spatial variability of soil salinity in a coastal paddy field. Significant correlation relationship between ECa and EC1:5 (i.e. r >0.9) allowed us to use EM38 data to characterize the spatial variability of soil salinity. Geostatistical methods were used to determine the horizontal spatio-temporal variability of soil salinity over three consecutive years. The study found that the distribution of salinity was heterogeneous and the leaching of salts was more significant in the edges of the study field. By inverting the EM38 data using a Quasi-3D inversion algorithm, the vertical spatio-temporal variability of soil salinity was determined and the leaching of salts over time was easily identified. The methodology of this study can be used as guidance for researchers interested in understanding soil salinity development as well as land managers aiming for effective soil salinity monitoring and management practices. In order to better characterize the variations in soil salinity to a deeper soil profile, the deeper mode of EM38 (i.e., EM38v) as well as other EMI instruments (e.g. DUALEM-421) can be incorporated to conduct Quasi-3D inversions for deeper soil profiles.

  16. Mapping spatial variability of soil salinity in a coastal paddy field based on electromagnetic sensors.

    Directory of Open Access Journals (Sweden)

    Yan Guo

    Full Text Available In coastal China, there is an urgent need to increase land area for agricultural production and urban development, where there is a rapid growing population. One solution is land reclamation from coastal tidelands, but soil salinization is problematic. As such, it is very important to characterize and map the within-field variability of soil salinity in space and time. Conventional methods are often time-consuming, expensive, labor-intensive, and unpractical. Fortunately, proximal sensing has become an important technology in characterizing within-field spatial variability. In this study, we employed the EM38 to study spatial variability of soil salinity in a coastal paddy field. Significant correlation relationship between ECa and EC1:5 (i.e. r >0.9 allowed us to use EM38 data to characterize the spatial variability of soil salinity. Geostatistical methods were used to determine the horizontal spatio-temporal variability of soil salinity over three consecutive years. The study found that the distribution of salinity was heterogeneous and the leaching of salts was more significant in the edges of the study field. By inverting the EM38 data using a Quasi-3D inversion algorithm, the vertical spatio-temporal variability of soil salinity was determined and the leaching of salts over time was easily identified. The methodology of this study can be used as guidance for researchers interested in understanding soil salinity development as well as land managers aiming for effective soil salinity monitoring and management practices. In order to better characterize the variations in soil salinity to a deeper soil profile, the deeper mode of EM38 (i.e., EM38v as well as other EMI instruments (e.g. DUALEM-421 can be incorporated to conduct Quasi-3D inversions for deeper soil profiles.

  17. Mapping Spatial Variability of Soil Salinity in a Coastal Paddy Field Based on Electromagnetic Sensors

    Science.gov (United States)

    Guo, Yan; Huang, Jingyi; Shi, Zhou; Li, Hongyi

    2015-01-01

    In coastal China, there is an urgent need to increase land area for agricultural production and urban development, where there is a rapid growing population. One solution is land reclamation from coastal tidelands, but soil salinization is problematic. As such, it is very important to characterize and map the within-field variability of soil salinity in space and time. Conventional methods are often time-consuming, expensive, labor-intensive, and unpractical. Fortunately, proximal sensing has become an important technology in characterizing within-field spatial variability. In this study, we employed the EM38 to study spatial variability of soil salinity in a coastal paddy field. Significant correlation relationship between ECa and EC1:5 (i.e. r >0.9) allowed us to use EM38 data to characterize the spatial variability of soil salinity. Geostatistical methods were used to determine the horizontal spatio-temporal variability of soil salinity over three consecutive years. The study found that the distribution of salinity was heterogeneous and the leaching of salts was more significant in the edges of the study field. By inverting the EM38 data using a Quasi-3D inversion algorithm, the vertical spatio-temporal variability of soil salinity was determined and the leaching of salts over time was easily identified. The methodology of this study can be used as guidance for researchers interested in understanding soil salinity development as well as land managers aiming for effective soil salinity monitoring and management practices. In order to better characterize the variations in soil salinity to a deeper soil profile, the deeper mode of EM38 (i.e., EM38v) as well as other EMI instruments (e.g. DUALEM-421) can be incorporated to conduct Quasi-3D inversions for deeper soil profiles. PMID:26020969

  18. Variability of soil-to-crop transfer factor

    International Nuclear Information System (INIS)

    Uchida, Shigeo; Kamada, Hiroshi; Yokosuka, Setsuko; Ohmomo, Yoichiro

    1987-01-01

    Many European countries have nuclear facilities in inland areas, where extremely low level radioactive waste liquid is discharged to rivers. In those nations, therefore, many studies have been made oncerning the transfer of radioisotopes into plants. In Japan, greater attention has been attracted to such radioisotope transfer into plants and then into human bodies. Thus the present report reviews various studies on this issue. The key parameter for this process is the transfer factor (also called concentration factor, coefficient or ratio). The factor largely depends on various other factors including the characteristics of different nuclides, properties of soil (pH, oxidation-reduction potential, grain size distribution, contents of clay minerals, contents of organic matters, water content, etc.), characteristics of crops and cultivation conditions. It has been reported that I is absorbed by plants more rapidly than IO 3 . Of the various soil parameters, the pH of soil has the greatest effect on the transfer factor. Soil is mostly alkaline in Europe and America while acid soil account for a great part in Japan, suggesting that the transfer factor would be greater in Japan. The total potassium content in soil has the second largest effect on the factor. Radioactive iodine has shown to be transferred into soy beans and spinach 30 times more rapidly than into fruit vegetables. The oxidation-reduction potential also has a significant influence on the transfer factor. (Nogami, K.)

  19. Physical and geochemical drivers of CDOM variability near a natural seep site in the Gulf of Mexico

    Science.gov (United States)

    Edwards, C. R.; Powers, L.; Medeiros, P. M.

    2016-02-01

    Colored dissolved organic matter (CDOM) on the continental shelf and slope can serve as a marker for fresh water influence, indicate the presence of hydrocarbons, and provide important clues about nutrient content and organic matter cycling. Autonomous underwater vehicles such as gliders allow for subsurface measurement of CDOM fluorescence for weeks to months; these time series may be especially valuable in the northern Gulf of Mexico, where CDOM inputs of both terrestrial and oil and gas sources can be significant. Data from a recent glider deployment near a natural seep site (GC600) on the continental slope over 180km from shore suggest simultaneous influence of Mississippi plume water and hydrocarbon inputs in the upper 200m, with variability in fluorescence at a range of vertical and temporal scales. We will explore patterns in spatial and temporal variability of glider-measured hydrography, dissolved oxygen, and bio-optical data (CDOM, chlorophyll-a, backscatter fluorescence), and use their combination to infer a terrigenous and/or fossil fuel source(s). Taking advantage of a combination of satellite sea surface temperature, ocean color, wind, and data from moored and mobile platforms, we will examine physical controls on transport and vertical mixing of CDOM and the potential role of nonlinear mesoscale eddies, which can trap water in their interior and may transport river- or hydrocarbon-derived CDOM over long distances. The combined data set will be used to consider and potentially constrain the effect of photodegradation and other biogeochemical causes for CDOM fluorescence variability in the upper 200m.

  20. Landscape controls and vertical variability of soil organic carbon storage in permafrost-affected soils of the Lena River Delta

    DEFF Research Database (Denmark)

    Siewert, Matthias Benjamin; Hugelius, Gustaf; Heim, Birgit

    2016-01-01

    To project the future development of the soil organic carbon (SOC) storage in permafrost environments, the spatial and vertical distribution of key soil properties and their landscape controls needs to be understood. This article reports findings from the Arctic Lena River Delta where we sampled 50...... in the permafrost. The major geomorphological units of a subregion of the Lena River Delta were mapped with a land form classification using a data-fusion approach of optical satellite imagery and digital elevation data to upscale SOC storage. Landscape mean SOC storage is estimated to 19.2 ± 2.0 kg C m− 2. Our...... results show that the geomorphological setting explains more soil variability than soil taxonomy classes or vegetation cover. The soils from the oldest, Pleistocene aged, unit of the delta store the highest amount of SOC per m2 followed by the Holocene river terrace. The Pleistocene terrace affected...

  1. Reconstructing Tropical Southwest Pacific Climate Variability and Mean State Changes at Vanuatu during the Medieval Climate Anomaly using Geochemical Proxies from Corals

    Science.gov (United States)

    Lawman, A. E.; Quinn, T. M.; Partin, J. W.; Taylor, F. W.; Thirumalai, K.; WU, C. C.; Shen, C. C.

    2017-12-01

    The Medieval Climate Anomaly (MCA: 950-1250 CE) is identified as a period during the last 2 millennia with Northern Hemisphere surface temperatures similar to the present. However, our understanding of tropical climate variability during the MCA is poorly constrained due to a lack of sub-annually resolved proxy records. We investigate seasonal and interannual variability during the MCA using geochemical records developed from two well preserved Porites lutea fossilized corals from the tropical southwest Pacific (Tasmaloum, Vanuatu; 15.6°S, 166.9°E). Absolute U/Th dates of 1127.1 ± 2.7 CE and 1105.1 ± 3.0 CE indicate that the selected fossil corals lived during the MCA. We use paired coral Sr/Ca and δ18O measurements to reconstruct sea surface temperature (SST) and the δ18O of seawater (a proxy for salinity). To provide context for the fossil coral records and test whether the mean state and climate variability at Vanuatu during the MCA is similar to the modern climate, our analysis also incorporates two modern coral records from Sabine Bank (15.9°S, 166.0°E) and Malo Channel (15.7°S, 167.2°E), Vanuatu for comparison. We quantify the uncertainty in our modern and fossil coral SST estimates via replication with multiple, overlapping coral records. Both the modern and fossil corals reproduce their respective mean SST value over their common period of overlap, which is 25 years in both cases. Based on over 100 years of monthly Sr/Ca data from each time period, we find that SSTs at Vanuatu during the MCA are 1.3 ± 0.7°C cooler relative to the modern. We also find that the median amplitude of the annual cycle is 0.8 ± 0.3°C larger during the MCA relative to the modern. Multiple data analysis techniques, including the standard deviation and the difference between the 95th and 5th percentiles of the annual SST cycle estimates, also show that the MCA has greater annual SST variability relative to the modern. Stable isotope data acquisition is ongoing, and when

  2. Amplification and dampening of soil respiration by changes in temperature variability

    Science.gov (United States)

    C.A. Sierra; M.E. Harmon; E.A. Thomann; S.S. Perakis; H.W. Loescher

    2011-01-01

    Accelerated release of carbon from soils is one of the most important feedbacks related to anthropogenically induced climate change. Studies addressing the mechanisms for soil carbon release through organic matter decomposition have focused on the effect of changes in the average temperature, with little attention to changes in temperature variability. Anthropogenic...

  3. Variability in soil CO2 production and surface CO2 efflux across riparian-hillslope transitions

    Science.gov (United States)

    Vincent Jerald. Pacific

    2007-01-01

    The spatial and temporal controls on soil CO2 production and surface CO2 efflux have been identified as an outstanding gap in our understanding of carbon cycling. I investigated both the spatial and temporal variability of soil CO2 concentrations and surface CO2 efflux across eight topographically distinct riparian-hillslope transitions in the ~300 ha subalpine upper-...

  4. Trace elements and nutrients adsorption onto nano-maghemite in a contaminated-soil solution: A geochemical/statistical approach.

    Science.gov (United States)

    Martínez-Fernández, Domingo; Bingöl, Deniz; Komárek, Michael

    2014-07-15

    Two experiments were carried out to study the competition for adsorption between trace elements (TEs) and nutrients following the application of nano-maghemite (NM) (iron nano-oxide; Fe2O3) to a soil solution (the 0.01molL(-1) CaCl2 extract of a TEs-contaminated soil). In the first, the nutrients K, N, and P were added to create a set of combinations: potential availability of TEs during their interaction with NM and nutrients were studied. In the second, response surface methodology was used to develop predictive models by central composite design (CCD) for competition between TEs and the nutrients K and N for adsorption onto NM. The addition of NM to the soil solution reduced specifically the concentrations of available As and Cd, but the TE-adsorption capacity of NM decreased as the P concentration increased. The CCD provided more concise and valuable information, appropriate to estimate the behavior of NM sequestering TEs: according to the suggested models, K(+) and NH4(+) were important factors for Ca, Fe, Mg, Mn, Na, and Zn adsorption (Radj(2)=95%, except for Zn with Radj(2)=87%). The obtained information and models can be used to predict the effectiveness of NM for the stabilization of TEs, crucial during the phytoremediation of contaminated soils. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Geochemical characterization of fluoride in water, table salt, active sediment, rock and soil samples, and its possible relationship with the prevalence of enamel fluorosis in children in four municipalities of the department of Huila (Colombia).

    Science.gov (United States)

    Martignon, Stefania; Opazo-Gutiérrez, Mario Omar; Velásquez-Riaño, Möritz; Orjuela-Osorio, Iván Rodrigo; Avila, Viviana; Martinez-Mier, Esperanza Angeles; González-Carrera, María Clara; Ruiz-Carrizosa, Jaime Alberto; Silva-Hermida, Blanca Cecilia

    2017-06-01

    Fluoride is an element that affects teeth and bone formation in animals and humans. Though the use of systemic fluoride is an evidence-based caries preventive measure, excessive ingestion can impair tooth development, mainly the mineralization of tooth enamel, leading to a condition known as enamel fluorosis. In this study, we investigated the geochemical characterization of fluoride in water, table salt, active sediment, rock and soil samples in four endemic enamel fluorosis sentinel municipalities of the department of Huila, Colombia (Pitalito, Altamira, El Agrado and Rivera), and its possible relationship with the prevalence of enamel fluorosis in children. The concentration of fluoride in drinking water, table salt, active sediment, rock, and soil was evaluated by means of an ion selective electrode and the geochemical analyses were performed using X-ray fluorescence. Geochemical analysis revealed fluoride concentrations under 15 mg/kg in active sediment, rock and soil samples, not indicative of a significant delivery to the watersheds studied. The concentration of fluoride in table salt was found to be under the inferior limit (less than 180 μg/g) established by the Colombian regulations. Likewise, exposure doses for fluoride water intake did not exceed the recommended total dose for all ages from 6 months. Although the evidence does not point out at rocks, soils, fluoride-bearing minerals, fluoridated salt and water, the hypothesis of these elements as responsible of the current prevalence of enamel fluorosis cannot be discarded since, aqueducts might have undergone significant changes overtime.

  6. Analysis of the spatial variability of crop yield and soil properties in small agricultural plots

    Directory of Open Access Journals (Sweden)

    Vieira Sidney Rosa

    2003-01-01

    Full Text Available The objective of this study was to assess spatial variability of soil properties and crop yield under no tillage as a function of time, in two soil/climate conditions in São Paulo State, Brazil. The two sites measured approximately one hectare each and were cultivated with crop sequences which included corn, soybean, cotton, oats, black oats, wheat, rye, rice and green manure. Soil fertility, soil physical properties and crop yield were measured in a 10-m grid. The soils were a Dusky Red Latossol (Oxisol and a Red Yellow Latossol (Ultisol. Soil sampling was performed in each field every two years after harvesting of the summer crop. Crop yield was measured at the end of each crop cycle, in 2 x 2.5 m sub plots. Data were analysed using semivariogram analysis and kriging interpolation for contour map generation. Yield maps were constructed in order to visually compare the variability of yields, the variability of the yield components and related soil properties. The results show that the factors affecting the variability of crop yield varies from one crop to another. The changes in yield from one year to another suggest that the causes of variability may change with time. The changes with time for the cross semivariogram between phosphorus in leaves and soybean yield is another evidence of this result.

  7. Soil variability and effectiveness of soil and water conservation in the Sahel.

    NARCIS (Netherlands)

    Hien, F.G.; Rietkerk, M.; Stroosnijder, L.

    1997-01-01

    Sahelian sylvopastoral lands often degrade into bare and crusted areas where regeneration of soil and vegetation is impossible in the short term unless soil and water conservation measures are implemented. Five combinations of tillage with and without mulch on three crust type/soil type combinations

  8. Soil moisture variability across different scales in an Indian watershed for satellite soil moisture product validation

    KAUST Repository

    Singh, Gurjeet; Panda, Rabindra K.; Mohanty, Binayak P.; Jana, Raghavendra Belur

    2016-01-01

    Strategic ground-based sampling of soil moisture across multiple scales is necessary to validate remotely sensed quantities such as NASA’s Soil Moisture Active Passive (SMAP) product. In the present study, in-situ soil moisture data were collected

  9. 222Rn and CO2 soil-gas geochemical characterization of thermally altered clays at Orciatico (Tuscany, Central Italy)

    International Nuclear Information System (INIS)

    Voltattorni, N.; Lombardi, S.; Rizzo, S.

    2010-01-01

    Research highlights: → Soil-gas technique is applied to study gas permeability of Orciatico clay units. → Clay permeability depends on thermal and mechanical alteration degree. → Soil-gas distributions are due to shallow fracturing of clays. → Rn and CO 2 soil-gas anomalies highlight secondary permeability in clay sequence. → Soil-gas results are supported by detailed geoelectrical surveys. - Abstract: The physical properties of clay allow argillaceous formations to be considered geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The clays of the Orciatico area (Tuscany, Central Italy), which were thermally altered via the intrusion of an alkali-trachyte laccolith, represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil-gas surveys to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different degrees of thermal alteration. The results of this study show that gas permeability is increased in the clay sequences subjected to greater heat input from the emplacement of the Orciatico intrusion, despite the lack of apparent mineral and geotechnical variations. These results, which take into consideration long time periods in a natural, large-scale geological system, may have important implications for the long-term safety of underground storage of nuclear waste in clay formations.

  10. Geochemical Background and Baseline Values Determination and Spatial Distribution of Heavy Metal Pollution in Soils of the Andes Mountain Range (Cajamarca-Huancavelica, Peru)

    Science.gov (United States)

    Santos-Francés, Fernando; Alonso Rojo, Pilar; García Sánchez, Antonio

    2017-01-01

    Concentrations of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) and one metalloid (As) as well as various parameters (pH, organic carbon, granulometric analysis and cation exchange capacity) were analyzed in 77 soil samples collected in the mining areas of La Zanja and Colquirrumi (Department of Cajamarca) and Julcani (Department of Huancavelica). Our study proposed geochemical baseline values for heavy metals in a natural region (La Zanja) from samples collected during the period of the environmental impact study (2006), that is, from an earlier period which occurred at the beginning of the exploitation of the current gold mine. The baseline values obtained were as follows: 8.26 mg·kg−1 for Cr; 56.97 mg·kg−1 for Ni; 22, 20 mg·kg−1 for the Cu; 47.42 mg·kg−1 for Zn; 27.50 mg·kg−1 for As; 4.36 mg·kg−1 for Cd; 4.89 mg·kg−1 for Hg, and 44.87 mg·kg−1 for Pb. Through the use of different indices of heavy metal contamination (geo-accumulation index (Igeo), improved Nemerow index (IIN) and potential ecological risk index (RI)), the degree of pollution caused by mining activities in two areas, Colquirrumi and Julcani, which have a high density of mining sites in operation, was determined. The values obtained from these indices indicated that the Colquirrumi region was the most contaminated, followed by Julcani. The area of La Zanja, despite being free of mining operations, presented slight diffuse pollution. Several positive correlations were obtained, with a high level of significance, between pH, organic carbon content, cation exchange capacity, and the Cr, Pb and Ni concentrations of the soils. The spatial distribution of the heavy metals was realized by means of the interpolation method of ordinary kriging. The results obtained and the experience gained in this work were necessary to facilitate the identification of soil contamination processes in high altitude areas of the Andes Western Cordillera (Peru) as a basis for taking appropriate

  11. Geochemical Background and Baseline Values Determination and Spatial Distribution of Heavy Metal Pollution in Soils of the Andes Mountain Range (Cajamarca-Huancavelica, Peru).

    Science.gov (United States)

    Santos-Francés, Fernando; Martinez-Graña, Antonio; Alonso Rojo, Pilar; García Sánchez, Antonio

    2017-07-31

    Concentrations of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) and one metalloid (As) as well as various parameters (pH, organic carbon, granulometric analysis and cation exchange capacity) were analyzed in 77 soil samples collected in the mining areas of La Zanja and Colquirrumi (Department of Cajamarca) and Julcani (Department of Huancavelica). Our study proposed geochemical baseline values for heavy metals in a natural region (La Zanja) from samples collected during the period of the environmental impact study (2006), that is, from an earlier period which occurred at the beginning of the exploitation of the current gold mine. The baseline values obtained were as follows: 8.26 mg kg-1 for Cr; 56.97 mg kg-1 for Ni; 22, 20 mg kg-1 for the Cu; 47.42 mg kg-1 for Zn; 27.50 mg kg-1 for As; 4.36 mg kg-1 for Cd; 4.89 mg kg-1 for Hg, and 44.87 mg kg-1 for Pb. Through the use of different indices of heavy metal contamination (geo-accumulation index (Igeo), improved Nemerow index (IIN) and potential ecological risk index (RI)), the degree of pollution caused by mining activities in two areas, Colquirrumi and Julcani, which have a high density of mining sites in operation, was determined. The values obtained from these indices indicated that the Colquirrumi region was the most contaminated, followed by Julcani. The area of La Zanja, despite being free of mining operations, presented slight diffuse pollution. Several positive correlations were obtained, with a high level of significance, between pH, organic carbon content, cation exchange capacity, and the Cr, Pb and Ni concentrations of the soils. The spatial distribution of the heavy metals was realized by means of the interpolation method of ordinary kriging. The results obtained and the experience gained in this work were necessary to facilitate the identification of soil contamination processes in high altitude areas of the Andes Western Cordillera (Peru) as a basis for taking appropriate measures when restoring

  12. Variability in chemistry of surface and soil waters of an ...

    African Journals Online (AJOL)

    Water chemistry is important for the maintenance of wetland structure and function. Interpreting ecological patterns in a wetland system therefore requires an in-depth understanding of the water chemistry of that system. We investigated the spatial distribution of chemical solutes both in soil pore water and surface water, ...

  13. Genetic Variability in Soybean (Glycine max L.) for Low Soil ...

    African Journals Online (AJOL)

    Abush Tesfaye

    component analysis also revealed that the first five principal components (PCs) accounted for more ... nutritional value with 40% protein and 20% oil (Fekadu et al., 2009) that makes it an important raw ...... protein and oil content under both conditions using molecular marker technologies. ... for global modeling. Soil Use and ...

  14. TAPIR--Finnish national geochemical baseline database.

    Science.gov (United States)

    Jarva, Jaana; Tarvainen, Timo; Reinikainen, Jussi; Eklund, Mikael

    2010-09-15

    In Finland, a Government Decree on the Assessment of Soil Contamination and Remediation Needs has generated a need for reliable and readily accessible data on geochemical baseline concentrations in Finnish soils. According to the Decree, baseline concentrations, referring both to the natural geological background concentrations and the diffuse anthropogenic input of substances, shall be taken into account in the soil contamination assessment process. This baseline information is provided in a national geochemical baseline database, TAPIR, that is publicly available via the Internet. Geochemical provinces with elevated baseline concentrations were delineated to provide regional geochemical baseline values. The nationwide geochemical datasets were used to divide Finland into geochemical provinces. Several metals (Co, Cr, Cu, Ni, V, and Zn) showed anomalous concentrations in seven regions that were defined as metal provinces. Arsenic did not follow a similar distribution to any other elements, and four arsenic provinces were separately determined. Nationwide geochemical datasets were not available for some other important elements such as Cd and Pb. Although these elements are included in the TAPIR system, their distribution does not necessarily follow the ones pre-defined for metal and arsenic provinces. Regional geochemical baseline values, presented as upper limit of geochemical variation within the region, can be used as trigger values to assess potential soil contamination. Baseline values have also been used to determine upper and lower guideline values that must be taken into account as a tool in basic risk assessment. If regional geochemical baseline values are available, the national guideline values prescribed in the Decree based on ecological risks can be modified accordingly. The national geochemical baseline database provides scientifically sound, easily accessible and generally accepted information on the baseline values, and it can be used in various

  15. Application of nanoparticle of rock phosphate and biofertilizer in increasing some soil chemical characteristics of variable charge soil

    Science.gov (United States)

    Devnita, Rina; Joy, Benny; Arifin, Mahfud; Hudaya, Ridha; Oktaviani, Nurul

    2018-02-01

    Soils in Indonesia are dominated by variable charge soils where the technology like fertilization did not give the same result as the soils with permanent charge. The objectives of this research is to increase some chemical characteristic of variable charge soils by using the high negative charge ameliorations like rock phosphate in nanoparticle combined with biofertilizer. The research used a complete randomized experimental design in factorial with two factors. The first factor was nanoparticle of rock phosphate consists of four doses on soil weight percentage (0%, 2.5%, 5.0% and 7.5%). The second factor was biofertilizer consisted of two doses (without biofertilizer and 1 g.kg-1 soil biofertilizer). The combination treatments replicated three times. Variable charge soil used was Andisol. Andisol and the treatments were incubated for 4 months. Soil samples were taken after one and four months during incubation period to be analyzed for P-retention, available P and potential P. The result showed that all combinations of rock phosphate and biofertilizer decreased the P-retention to 75-77% after one month. Independently, application of 7.5% of rock phosphate decreased P-retention to 87.22% after four months, increased available P (245.37 and 19.12 mg.kg-1) and potential P (1354.78 and 3000.99 mg/100) after one and four months. Independently, biofertilizer increased the P-retention to 91.66% after four months, decreased available P to 121.55 mg.kg-1 after one month but increased to 12.55 mg.kg-1 after four months, decreased potential P to 635.30 after one month but increased to 1810.40 mg.100 g-1 after four months.

  16. A study of soil moisture variability for landmine detection by the neutron technique

    OpenAIRE

    Avdić Senada

    2007-01-01

    This paper is focused on the space and temporal variability of soil moisture experimental data acquired at a few locations near landmine fields in the Tuzla Canton, as well as on the quantification of the statistical nature of soil moisture data on a small spatial scale. Measurements of soil water content at the surface were performed by an electro-magnetic sensor over 1 25, and 100 m2 grids, at intervals of 0.2, 0.5, and 1 m, respectively. The sampling of soil moisture at different spatial r...

  17. Spatial variability of soil potassium in sugarcane areas subjected to the application of vinasse

    Directory of Open Access Journals (Sweden)

    LAÉRCIO A. DE CARVALHO

    2014-12-01

    Full Text Available When deposited on land the vinasse can promote improvement in fertility, however, often fertilizer application occurs in areas considered homogeneous, without taking into account the variability of the soil. The objective of this study was to evaluate the effect of vinasse application on potassium content in two classes of soils cultivated with sugarcane, and characterize the spatial variability of soil using geostatistical techniques. In the 2010 and 2011 crop year, soil samples were collected from an experimental grid at 0-0.2 and 0.2-0.4 m depth in three soils cultivated with sugarcane, totaling 90 samplings in each grid, for the determination of pH, calcium (Ca, magnesium (Mg, potassium (K, phosphorus (P, aluminum (Al and potential acidity (H + Al. The data have been submitted to analysis of descriptive statistics and the K attribute was subjected to geostatistical analysis. The coefficient of variation indicated medium and high variability of K for the three soils. The results showed that the spatial dependence of K increased in depth to FRce and decreased to PHlv, indicating that the attribute could have followed the pattern of distribution of clay in depth. The investigation of the spatial variability of K on the surface and subsurface soils provided the definition of management zones with different levels of fertility, which can be organized into sub-areas for a more efficient management of the resources and the environment.

  18. Field Scale Studies on the Spatial Variability of Soil Quality Indicators in Washington State, USA

    Directory of Open Access Journals (Sweden)

    Jeffrey L. Smith

    2011-01-01

    Full Text Available Arable lands are needed for sustainable agricultural systems to support an ever-growing human population. Soil quality needs to be defined to assure that new land brought into crop production is sustainable. To evaluate soil quality, a number of soil attributes will need to be measured, evaluated, and integrated into a soil-quality index using the multivariable indicator kriging (MVIK procedure. This study was conducted to determine the spatial variability and correlation of indicator parameters on a field scale with respect to soil quality and suitability for use with MVIK. The variability of the biological parameters decreased in the order of respiration > enzyme assays and qCO2 > microbial biomass C. The distribution frequency of all parameters except respiration were normal although the spatial distribution across the landscape was highly variable. The biological parameters showed little correlation with each other when all data points were considered; however, when grouped in smaller sections, the correlations were more consistent with observed patterns across the field. To accurately assess soil quality, and arable land use, consideration of spatial and temporal variability, soil conditions, and other controlling factors must be taken into account.

  19. Spatial variability of soil CO2 emission in different topographic positions

    Directory of Open Access Journals (Sweden)

    Liziane de Figueiredo Brito

    2010-01-01

    Full Text Available The spatial variability of soil CO2 emission is controlled by several properties related to the production and transport of CO2 inside the soil. Considering that soil properties are also influenced by topography, the objective of this work was to investigate the spatial variability of soil CO2 emission in three different topographic positions in an area cultivated with sugarcane, just after mechanical harvest. One location was selected on a concave-shaped form and two others on linear-shaped form (in back-slope and foot-slope. Three grids were installed, one in each location, containing 69 points and measuring 90 x 90 m each. The spatial variability of soil CO2 emission was characterized by means of semivariance. Spatial variability models derived from soil CO2 emission were exponential in the concave location while spherical models fitted better in the linear shaped areas. The degree of spatial dependence was moderate in all cases and the range of spatial dependence for the CO2 emission in the concave area was 44.5 m, higher than the mean value obtained for the linear shaped areas (20.65 m. The spatial distribution maps of soil CO2 emission indicate a higher discontinuity of emission in the linear form when compared to the concave form.

  20. Adsorption properties of subtropical and tropical variable charge soils: Implications from climate change and biochar amendment

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Ren-Kou; Qafoku, Nikolla; Van Ranst, Eric; Li, Jiu-yu; Jiang, Jun

    2016-01-25

    This review paper attempts to summarize the progress made in research efforts conducted over the last years to study the surface chemical properties of the tropical and subtropical soils, usually called variable charge soils, and the way they response to different management practices. The paper is composed of an introductory section that provides a brief discussion on the surface chemical properties of these soils, and five other review sections. The focus of these sections is on the evolution of surface chemical properties during the development of the variable charge properties (second section), interactions between oppositely charged particles and the resulting effects on the soil properties and especially on soil acidity (third section), the surface effects of low molecular weight organic acids sorbed to mineral surfaces and the chemical behavior of aluminum (fourth section), and the crop straw derived biochar induced changes of the surface chemical properties of these soils (fifth section). A discussion on the effect of climate change variables on the properties of the variable charge soils is included at the end of this review paper (sixth section).

  1. Environmental and management influences on temporal variability of near saturated soil hydraulic properties.

    Science.gov (United States)

    Bodner, G; Scholl, P; Loiskandl, W; Kaul, H-P

    2013-08-01

    Structural porosity is a decisive property for soil productivity and soil environmental functions. Hydraulic properties in the structural range vary over time in response to management and environmental influences. Although this is widely recognized, there are few field studies that determine dominant driving forces underlying hydraulic property dynamics. During a three year field experiment we measured temporal variability of soil hydraulic properties by tension infiltrometry. Soil properties were characterized by hydraulic conductivity, effective macroporosity and Kosugi's lognormal pore size distribution model. Management related influences comprised three soil cover treatment (mustard and rye vs. fallow) and an initial mechanical soil disturbance with a rotary harrow. Environmental driving forces were derived from meteorological and soil moisture data. Soil hydraulic parameters varied over time by around one order of magnitude. The coefficient of variation of soil hydraulic conductivity K(h) decreased from 69.5% at saturation to 42.1% in the more unsaturated range (- 10 cm pressure head). A slight increase in the Kosugi parameter showing pore heterogeneity was observed under the rye cover crop, reflecting an enhanced structural porosity. The other hydraulic parameters were not significantly influenced by the soil cover treatments. Seedbed preparation with a rotary harrow resulted in a fourfold increase in macroporosity and hydraulic conductivity next to saturation, and homogenized the pore radius distribution. Re-consolidation after mechanical loosening lasted over 18 months until the soil returned to its initial state. The post-tillage trend of soil settlement could be approximated by an exponential decay function. Among environmental factors, wetting-drying cycles were identified as dominant driving force explaining short term hydraulic property changes within the season (r 2  = 0.43 to 0.59). Our results suggested that beside considering average

  2. Land agroecological quality assessment in conditions of high spatial soil cover variability at the Pereslavskoye Opolye.

    Science.gov (United States)

    Morev, Dmitriy; Vasenev, Ivan

    2015-04-01

    The essential spatial variability is mutual feature for most natural and man-changed soils at the Central region of European territory of Russia. The original spatial heterogeneity of forest soils has been further complicated by a specific land-use history and human impacts. For demand-driven land-use planning and decision making the quantitative analysis and agroecological interpretation of representative soil cover spatial variability is an important and challenging task that receives increasing attention from private companies, governmental and environmental bodies. Pereslavskoye Opolye is traditionally actively used in agriculture due to dominated high-quality cultivated soddy-podzoluvisols which are relatively reached in organic matter (especially for conditions of the North part at the European territory of Russia). However, the soil cover patterns are often very complicated even within the field that significantly influences on crop yield variability and have to be considered in farming system development and land agroecological quality evaluation. The detailed investigations of soil regimes and mapping of the winter rye yield have been carried in conditions of two representative fields with slopes sharply contrasted both in aspects and degrees. Rye biological productivity and weed infestation have been measured in elementary plots of 0.25 m2 with the following analysis the quality of the yield. In the same plot soil temperature and moisture have been measured by portable devices. Soil sampling was provided from three upper layers by drilling. The results of ray yield detailed mapping shown high differences both in average values and within-field variability on different slopes. In case of low-gradient slope (field 1) there is variability of ray yield from 39.4 to 44.8 dt/ha. In case of expressed slope (field 2) the same species of winter rye grown with the same technology has essentially lower yield and within-field variability from 20 to 29.6 dt/ha. The

  3. Variability of the soil-to-plant radiocaesium transfer factor for Japanese soils predicted with soil and plant properties.

    Science.gov (United States)

    Uematsu, Shinichiro; Vandenhove, Hildegarde; Sweeck, Lieve; Van Hees, May; Wannijn, Jean; Smolders, Erik

    2016-03-01

    Food chain contamination with radiocaesium (RCs) in the aftermath of the Fukushima accident calls for an analysis of the specific factors that control the RCs transfer. Here, soil-to-plant transfer factors (TF) of RCs for grass were predicted from the potassium concentration in soil solution (mK) and the Radiocaesium Interception Potential (RIP) of the soil using existing mechanistic models. The mK and RIP were (a) either measured for 37 topsoils collected from the Fukushima accident affected area or (b) predicted from the soil clay content and the soil exchangeable potassium content using the models that had been calibrated for European soils. An average ammonium concentration was used throughout in the prediction. The measured RIP ranged 14-fold and measured mK varied 37-fold among the soils. The measured RIP was lower than the RIP predicted from the soil clay content likely due to the lower content of weathered micas in the clay fraction of Japanese soils. Also the measured mK was lower than that predicted. As a result, the predicted TFs relying on the measured RIP and mK were, on average, about 22-fold larger than the TFs predicted using the European calibrated models. The geometric mean of the measured TFs for grass in the affected area (N = 82) was in the middle of both. The TFs were poorly related to soil classification classes, likely because soil fertility (mK) was obscuring the effects of the soil classification related to the soil mineralogy (RIP). This study suggests that, on average, Japanese soils are more vulnerable than European soils at equal soil clay and exchangeable K content. The affected regions will be targeted for refined model validation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Geochemical behaviour of palladium in soils and Pd/PdO model substances in the presence of the organic complexing agents L-methionine and citric acid.

    Science.gov (United States)

    Zereini, Fathi; Wiseman, Clare L S; Vang, My; Albers, Peter; Schneider, Wolfgang; Schindl, Roland; Leopold, Kerstin

    2016-01-01

    Risk assessments of platinum group metal (PGE) emissions, notably those of platinum (Pt), palladium (Pd) and rhodium (Rh), have been mostly based on data regarding the metallic forms used in vehicular exhaust converters, known to be virtually biologically inert and immobile. To adequately assess the potential impacts of PGE, however, data on the chemical behaviour of these metals under ambient conditions post-emission is needed. Complexing agents with a high affinity for metals in the environment are hypothesized to contribute to an increased bioaccessibility of PGE. The purpose of this study is to examine the modulating effects of the organic complexing agents, L-methionine and citric acid, on the geochemical behavior of Pd in soils and model substances (Pd black and PdO). Batch experimental tests were conducted with soils and model substances to examine the impacts of the concentration of complexing agents, pH and length of extraction period on Pd solubility and its chemical transformation. Particle surface chemistry was examined using X-ray photoelectron spectroscopy (XPS) on samples treated with solutions under various conditions, including low and high O2 levels. Pd was observed to be more soluble in the presence of organic complexing agents, compared to Pt and Rh. Pd in soils was more readily solubilized with organic complexing agents compared to the model substances. After 7 days of extraction, L-methionine (0.1 M) treated soil and Pd black samples, for instance, had mean soluble Pd fractions of 12.4 ± 5.9% and 0.554 ± 0.024%, respectively. Surface chemistry analyses (XPS) confirmed the oxidation of metallic Pd surfaces when treated with organic complexing agents. The type of organic complexing agent used for experimental purposes was observed to be the most important factor influencing solubility, followed by solution pH and time of extraction. The results demonstrate that metallic Pd can be transformed into more bioaccessible species in the presence of

  5. Spatial Variability of Dielectric Properties in Field Soils

    National Research Council Canada - National Science Library

    Hendrickx, J

    2001-01-01

    ... since it directly influences the three other properties The variability of these properties may be such that either potential land mine signatures are overshadowed or false alarms result In this paper...

  6. A study of soil moisture variability for landmine detection by the neutron technique

    Directory of Open Access Journals (Sweden)

    Avdić Senada

    2007-01-01

    Full Text Available This paper is focused on the space and temporal variability of soil moisture experimental data acquired at a few locations near landmine fields in the Tuzla Canton, as well as on the quantification of the statistical nature of soil moisture data on a small spatial scale. Measurements of soil water content at the surface were performed by an electro-magnetic sensor over 1 25, and 100 m2 grids, at intervals of 0.2, 0.5, and 1 m, respectively. The sampling of soil moisture at different spatial resolutions and over different grid sizes has been investigated in order to achieve the quantification of the statistical nature of soil moisture distribution. The statistical characterization of spatial variability was performed through variogram and correlogram analysis of measurement results. The temporal variability of the said samples was examined over a two-season period. For both sampling periods, the spatial correlation length is about 1 to 2 m, respectively, or less. Thus, sampling should be done on a larger spatial scale, in order to capture the variability of the investigated areas. Since the characteristics of many landmine sensors depend on soil moisture, the results of this study could form a useful data base for multisensor landmine detection systems with a promising performance.

  7. Effects of Recent Regional Soil Moisture Variability on Global Net Ecosystem CO2 Exchange

    Science.gov (United States)

    Jones, L. A.; Madani, N.; Kimball, J. S.; Reichle, R. H.; Colliander, A.

    2017-12-01

    Soil moisture exerts a major regional control on the inter-annual variability of the global land sink for atmospheric CO2. In semi-arid regions, annual biomass production is closely coupled to variability in soil moisture availability, while in cold-season-affected regions, summer drought offsets the effects of advancing spring phenology. Availability of satellite solar-induced fluorescence (SIF) observations and improvements in atmospheric inversions has led to unprecedented ability to monitor atmospheric sink strength. However, discrepancies still exist between such top-down estimates as atmospheric inversion and bottom-up process and satellite driven models, indicating that relative strength, mechanisms, and interaction of driving factors remain poorly understood. We use soil moisture fields informed by Soil Moisture Active Passive Mission (SMAP) observations to compare recent (2015-2017) and historic (2000-2014) variability in net ecosystem land-atmosphere CO2 exchange (NEE). The operational SMAP Level 4 Carbon (L4C) product relates ground-based flux tower measurements to other bottom-up and global top-down estimates to underlying soil moisture and other driving conditions using data-assimilation-based SMAP Level 4 Soil Moisture (L4SM). Droughts in coastal Brazil, South Africa, Eastern Africa, and an anomalous wet period in Eastern Australia were observed by L4C. A seasonal seesaw pattern of below-normal sink strength at high latitudes relative to slightly above-normal sink strength for mid-latitudes was also observed. Whereas SMAP-based soil moisture is relatively informative for short-term temporal variability, soil moisture biases that vary in space and with season constrain the ability of the L4C estimates to accurately resolve NEE. Such biases might be caused by irrigation and plant-accessible ground-water. Nevertheless, SMAP L4C daily NEE estimates connect top-down estimates to variability of effective driving factors for accurate estimates of regional

  8. Aspect-related Vegetation Differences Amplify Soil Moisture Variability in Semiarid Landscapes

    Science.gov (United States)

    Yetemen, O.; Srivastava, A.; Kumari, N.; Saco, P. M.

    2017-12-01

    Soil moisture variability (SMV) in semiarid landscapes is affected by vegetation, soil texture, climate, aspect, and topography. The heterogeneity in vegetation cover that results from the effects of microclimate, terrain attributes (slope gradient, aspect, drainage area etc.), soil properties, and spatial variability in precipitation have been reported to act as the dominant factors modulating SMV in semiarid ecosystems. However, the role of hillslope aspect in SMV, though reported in many field studies, has not received the same degree of attention probably due to the lack of extensive large datasets. Numerical simulations can then be used to elucidate the contribution of aspect-driven vegetation patterns to this variability. In this work, we perform a sensitivity analysis to study on variables driving SMV using the CHILD landscape evolution model equipped with a spatially-distributed solar-radiation component that couples vegetation dynamics and surface hydrology. To explore how aspect-driven vegetation heterogeneity contributes to the SMV, CHILD was run using a range of parameters selected to reflect different scenarios (from uniform to heterogeneous vegetation cover). Throughout the simulations, the spatial distribution of soil moisture and vegetation cover are computed to estimate the corresponding coefficients of variation. Under the uniform spatial precipitation forcing and uniform soil properties, the factors affecting the spatial distribution of solar insolation are found to play a key role in the SMV through the emergence of aspect-driven vegetation patterns. Hence, factors such as catchment gradient, aspect, and latitude, define water stress and vegetation growth, and in turn affect the available soil moisture content. Interestingly, changes in soil properties (porosity, root depth, and pore-size distribution) over the domain are not as effective as the other factors. These findings show that the factors associated to aspect-related vegetation

  9. Kinetics and mechanisms of metal retention/release in geochemical processes in soil. 1998 annual progress report

    International Nuclear Information System (INIS)

    Taylor, R.W.

    1998-01-01

    'The long-term fate of toxic metals in soils cannot be precisely predicted, and often remediation recommendations and techniques may be ineffective or unnecessary. This work will generate basic knowledge on the kinetics and mechanism(s) of heavy metal retention/release by soil mineral colloids. The information should assist in improving remediation strategies for toxic heavy metal contaminated soils. The objectives are: (1) To determine the effects of residence time on the mechanisms of Cr(VI), Cu(II), Co(II), Cd(II), Pb(II), and Ni(II) sorption/release on Fe and Al oxide and clay mineral surfaces using kinetic studies coupled to extended x-ray absorption fine structure (EXAFS) spectroscopy and fourier transform infrared (FTIR) spectroscopy. (2) To study the effect of temperature, pH, and phosphate on metal sorption by oxides, and derive thermodynamic parameters to describe the sorption process. As of June, 16, 1997 several clay minerals were tested for their efficiency of removing Cr from aqueous systems. The materials tested--smectite, vermiculites, illites, and kaolinite--represent the natural clay minerals that are abundant in soils and sediments. The clays were used in either their original or reduced (reduced with sodium dithionite) forms. The experimental result indicate that the reduced clays acted as an efficient remover of Cr(VI) from an aqueous system. The XANES spectra of Cr-treated clays provided evidence that the clays reduced Cr(VI) to Cr(III) and immobilized Cr in the clays at the same time. Sodium dithionite applied directly into aqueous systems reduced Cr(VI) to Cr(III), but could not immobilize Cr even in the presence of the clays. The Cr(VI) removal capacity varied with the clay mineral type and the structural Fe content. For the clays used in this study, the removal capacity follows the orders of smectites > vermiculites and illites > kaolinite. Within the same type of clay minerals, reduction of Cr(VI) is highly related to the ferrous iron

  10. Effects of short term bioturbation by common voles on biogeochemical soil variables.

    Directory of Open Access Journals (Sweden)

    Burkhard Wilske

    Full Text Available Bioturbation contributes to soil formation and ecosystem functioning. With respect to the active transport of matter by voles, bioturbation may be considered as a very dynamic process among those shaping soil formation and biogeochemistry. The present study aimed at characterizing and quantifying the effects of bioturbation by voles on soil water relations and carbon and nitrogen stocks. Bioturbation effects were examined based on a field set up in a luvic arenosol comprising of eight 50 × 50 m enclosures with greatly different numbers of common vole (Microtus arvalis L., ca. 35-150 individuals ha-1 mth-1. Eleven key soil variables were analyzed: bulk density, infiltration rate, saturated hydraulic conductivity, water holding capacity, contents of soil organic carbon (SOC and total nitrogen (N, CO2 emission potential, C/N ratio, the stable isotopic signatures of 13C and 15N, and pH. The highest vole densities were hypothesized to cause significant changes in some variables within 21 months. Results showed that land history had still a major influence, as eight key variables displayed an additional or sole influence of topography. However, the δ15N at depths of 10-20 and 20-30 cm decreased and increased with increasing vole numbers, respectively. Also the CO2 emission potential from soil collected at a depth of 15-30 cm decreased and the C/N ratio at 5-10 cm depth narrowed with increasing vole numbers. These variables indicated the first influence of voles on the respective mineralization processes in some soil layers. Tendencies of vole activity homogenizing SOC and N contents across layers were not significant. The results of the other seven key variables did not confirm significant effects of voles. Thus overall, we found mainly a first response of variables that are indicative for changes in biogeochemical dynamics but not yet of those representing changes in pools.

  11. McMaster Mesonet soil moisture dataset: description and spatio-temporal variability analysis

    Directory of Open Access Journals (Sweden)

    K. C. Kornelsen

    2013-04-01

    Full Text Available This paper introduces and describes the hourly, high-resolution soil moisture dataset continuously recorded by the McMaster Mesonet located in the Hamilton-Halton Watershed in Southern Ontario, Canada. The McMaster Mesonet consists of a network of time domain reflectometer (TDR probes collecting hourly soil moisture data at six depths between 10 cm and 100 cm at nine locations per site, spread across four sites in the 1250 km2 watershed. The sites for the soil moisture arrays are designed to further improve understanding of soil moisture dynamics in a seasonal climate and to capture soil moisture transitions in areas that have different topography, soil and land cover. The McMaster Mesonet soil moisture constitutes a unique database in Canada because of its high spatio-temporal resolution. In order to provide some insight into the dominant processes at the McMaster Mesonet sites, a spatio-temporal and temporal stability analysis were conducted to identify spatio-temporal patterns in the data and to suggest some physical interpretation of soil moisture variability. It was found that the seasonal climate of the Great Lakes Basin causes a transition in soil moisture patterns at seasonal timescales. During winter and early spring months, and at the meadow sites, soil moisture distribution is governed by topographic redistribution, whereas following efflorescence in the spring and summer, soil moisture spatial distribution at the forested site was also controlled by vegetation canopy. Analysis of short-term temporal stability revealed that the relative difference between sites was maintained unless there was significant rainfall (> 20 mm or wet conditions a priori. Following a disturbance in the spatial soil moisture distribution due to wetting, the relative soil moisture pattern re-emerged in 18 to 24 h. Access to the McMaster Mesonet data can be provided by visiting www.hydrology.mcmaster.ca/mesonet.

  12. An integrated geochemical, geophysical and mineralogical study of river sediments in alpine area and soil samples near steel plant, in Austria

    Science.gov (United States)

    Irfan, M. I.; Meisel, T.

    2012-04-01

    Concentration of nickel and chromium in any part of the ecosystem is important for environmental concerns in particular human health due to the reason that some species of them can cause health problem e.g. dermatitis and cancer. Sediment samples collected form a river Vordernberger Bach (Leoben, Austria) in an alpine region and soil samples collected in an area adjacent to steel production unit in same narrow valley were investigated. In previous studies a correlation between magnetic susceptibility values and concentration of nickel and chromium showed that a magnetic susceptibility meter can be used to point out the contaminated areas as in-situ device. The purpose of the whole study is to understand the real (point or diffuse, anthropogenic or geogenic) sources of contamination of soils, water and river sediments through heavy metal deposition. Unseparated, magnetic and non-magnetic fractions of soil samples were investigated for geochemical and mineralogical aspects with XRF, ICP-MS, EMPA, Multi-Functional Kappabridge (MFK1) and laser ablation coupled with ICP-MS. Mineralogical study of sediment samples for several sampling points with higher Ni and Cr content was performed. Sediment samples were sieved below 1.4 mm and then a concentrate of heavy minerals was prepared in the field through panning. Concentrated heavy minerals were then subjected for heavy liquid separation in the laboratory. Separated magnetic and non-magnetic fractions below 0.71/0.1 mm and density greater than 2.9 g/cm3 were selected for mineralogical investigation. The abundance of typical anthropogenic particles, e.g., spherical, tinder, roasted ores, iron and steel mill slag was observed under the microscope. Magnetite (mostly anthropogenic), maghemite, chromspinel, chromite (type I & II), (Ca,Al)-ferrite, wustite, apatite (anthropogenic), olivine mixed crystals, calcium silicate and spinel (anthropogenic) are found in magnetic fraction. Non-magnetic fractions contain hematite, siderite

  13. Key indicator tools for shallow slope failure assessment using soil chemical property signatures and soil colour variables.

    Science.gov (United States)

    Othman, Rashidi; Hasni, Shah Irani; Baharuddin, Zainul Mukrim; Hashim, Khairusy Syakirin Has-Yun; Mahamod, Lukman Hakim

    2017-10-01

    Slope failure has become a major concern in Malaysia due to the rapid development and urbanisation in the country. It poses severe threats to any highway construction industry, residential areas, natural resources and tourism activities. The extent of damages that resulted from this catastrophe can be lessened if a long-term early warning system to predict landslide prone areas is implemented. Thus, this study aims to characterise the relationship between Oxisols properties and soil colour variables to be manipulated as key indicators to forecast shallow slope failure. The concentration of each soil property in slope soil was evaluated from two different localities that consist of 120 soil samples from stable and unstable slopes located along the North-South Highway (PLUS) and East-West Highway (LPT). Analysis of variance established highly significant difference (P shallow slope failure were high value of L*(62), low values of c* (20) and h* (66), low concentration of iron (53 mg kg -1 ) and aluminium oxide (37 mg kg -1 ), low soil TOC (0.5%), low CEC (3.6 cmol/kg), slightly acidic soil pH (4.9), high amount of sand fraction (68%) and low amount of clay fraction (20%).

  14. Changes in canopy structure and ant assemblages affect soil ecosystem variables as a foundation species declines

    DEFF Research Database (Denmark)

    Kendrick, Joseph A.; Ribbons, Relena Rose; Classen, Aimee Taylor

    2015-01-01

    in ant species composition would interact to alter soil ecosystem variables. In the Harvard Forest Hemlock Removal Experiment (HF-HeRE), established in 2003, T. canadensis in large plots were killed in place or logged and removed to mimic adelgid infestation or salvage harvesting, respectively. In 2006...... (richness and abundance) of ants increases rapidly as T. canadensis is lost from the stands. Because ants live and forage at the litter-soil interface, we hypothesized that environmental changes caused by hemlock loss (e.g., increased light and warmth at the forest floor, increased soil pH) and shifts......, we built ant exclosure subplots within all of the canopy manipulation plots to examine direct and interactive effects of canopy change and ant assemblage composition on soil and litter variables. Throughout HF-HeRE, T. canadensis was colonized by the adelgid in 2009, and the infested trees are now...

  15. Patterns and variability in geochemical signatures and microbial activity within and between diverse cold seep habitats along the lower continental slope, Northern Gulf of Mexico

    Science.gov (United States)

    Bowles, Marshall; Hunter, Kimberley S.; Samarkin, Vladimir; Joye, Samantha

    2016-07-01

    We collected 69 sediment cores from distinct ecological and geological settings along the deep slope in the Northern Gulf of Mexico to evaluate whether specific geochemical- or habitat-related factors correlated with rates of microbial processes and geochemical signatures. By collecting replicate cores from distinct habitats across multiple sites, we illustrate and quantify the heterogeneity of cold seep geochemistry and microbial activity. These data also document the factors driving unique aspects of the geochemistry of deep slope gas, oil and brine seeps. Surprisingly little variation was observed between replicate (n=2-5) cores within sites for most analytes (except methane), implying that the common practice of collecting one core for geochemical analysis can capture the signature of a habitat in most cases. Depth-integrated concentrations of methane, dissolved inorganic carbon (DIC), and calcium were the predominant geochemical factors that correlated with a site's ecological or geological settings. Pore fluid methane concentration was related to the phosphate and DIC concentration, as well as to rates of sulfate reduction. While distinctions between seep habitats were identified from geochemical signatures, habitat specific geochemistry varied little across sites. The relative concentration of dissolved inorganic nitrogen versus phosphorus suggests that phosphorus availability limits biomass production at cold seeps. Correlations between calcium, chloride, and phosphate concentrations were indicative of brine-associated phosphate transport, suggesting that in addition to the co-migration of methane, dissolved organic carbon, and ammonium with brine, phosphate delivery is also associated with brine advection.

  16. Inter-Annual Variability of Soil Moisture Stress Function in the Wheat Field

    Science.gov (United States)

    Akuraju, V. R.; Ryu, D.; George, B.; Ryu, Y.; Dassanayake, K. B.

    2014-12-01

    Root-zone soil moisture content is a key variable that controls the exchange of water and energy fluxes between land and atmosphere. In the soil-vegetation-atmosphere transfer (SVAT) schemes, the influence of root-zone soil moisture on evapotranspiration (ET) is parameterized by the soil moisture stress function (SSF). Dependence of actual ET: potential ET (fPET) or evaporative fraction to the root-zone soil moisture via SSF can also be used inversely to estimate root-zone soil moisture when fPET is estimated by remotely sensed land surface states. In this work we present fPET versus available soil water (ASW) in the root zone observed in the experimental farm sites in Victoria, Australia in 2012-2013. In the wheat field site, fPET vs ASW exhibited distinct features for different soil depth, net radiation, and crop growth stages. Interestingly, SSF in the wheat field presented contrasting shapes for two cropping years of 2012 and 2013. We argue that different temporal patterns of rainfall (and resulting soil moisture) during the growing seasons in 2012 and 2013 are responsible for the distinctive SSFs. SSF of the wheat field was simulated by the Agricultural Production Systems sIMulator (APSIM). The APSIM was able to reproduce the observed fPET vs. ASW. We discuss implications of our findings for existing modeling and (inverse) remote sensing approaches relying on SSF and alternative growth-stage-dependent SSFs.

  17. Incorporating soil variability in continental soil water modelling: a trade-off between data availability and model complexity

    Science.gov (United States)

    Peeters, L.; Crosbie, R. S.; Doble, R.; van Dijk, A. I. J. M.

    2012-04-01

    Developing a continental land surface model implies finding a balance between the complexity in representing the system processes and the availability of reliable data to drive, parameterise and calibrate the model. While a high level of process understanding at plot or catchment scales may warrant a complex model, such data is not available at the continental scale. This data sparsity is especially an issue for the Australian Water Resources Assessment system, AWRA-L, a land-surface model designed to estimate the components of the water balance for the Australian continent. This study focuses on the conceptualization and parametrization of the soil drainage process in AWRA-L. Traditionally soil drainage is simulated with Richards' equation, which is highly non-linear. As general analytic solutions are not available, this equation is usually solved numerically. In AWRA-L however, we introduce a simpler function based on simulation experiments that solve Richards' equation. In the simplified function soil drainage rate, the ratio of drainage (D) over storage (S), decreases exponentially with relative water content. This function is controlled by three parameters, the soil water storage at field capacity (SFC), the drainage fraction at field capacity (KFC) and a drainage function exponent (β). [ ] D- -S- S = KF C exp - β (1 - SFC ) To obtain spatially variable estimates of these three parameters, the Atlas of Australian Soils is used, which lists soil hydraulic properties for each soil profile type. For each soil profile type in the Atlas, 10 days of draining an initially fully saturated, freely draining soil is simulated using HYDRUS-1D. With field capacity defined as the volume of water in the soil after 1 day, the remaining parameters can be obtained by fitting the AWRA-L soil drainage function to the HYDRUS-1D results. This model conceptualisation fully exploits the data available in the Atlas of Australian Soils, without the need to solve the non

  18. Spatial variability of soil carbon stock in the Urucu river basin, Central Amazon-Brazil.

    Science.gov (United States)

    Ceddia, Marcos Bacis; Villela, André Luis Oliveira; Pinheiro, Érika Flávia Machado; Wendroth, Ole

    2015-09-01

    The Amazon Forest plays a major role in C sequestration and release. However, few regional estimates of soil organic carbon (SOC) stock in this ecoregion exist. One of the barriers to improve SOC estimates is the lack of recent soil data at high spatial resolution, which hampers the application of new methods for mapping SOC stock. The aims of this work were: (i) to quantify SOC stock under undisturbed vegetation for the 0-30 and the 0-100 cm under Amazon Forest; (ii) to correlate the SOC stock with soil mapping units and relief attributes and (iii) to evaluate three geostatistical techniques to generate maps of SOC stock (ordinary, isotopic and heterotopic cokriging). The study site is located in the Central region of Amazon State, Brazil. The soil survey covered the study site that has an area of 80 km(2) and resulted in a 1:10,000 soil map. It consisted of 315 field observations (96 complete soil profiles and 219 boreholes). SOC stock was calculated by summing C stocks by horizon, determined as a product of BD, SOC and the horizon thickness. For each one of the 315 soil observations, relief attributes were derived from a topographic map to understand SOC dynamics. The SOC stocks across 30 and 100 cm soil depth were 3.28 and 7.32 kg C m(-2), respectively, which is, 34 and 16%, lower than other studies. The SOC stock is higher in soils developed in relief forms exhibiting well-drained soils, which are covered by Upland Dense Tropical Rainforest. Only SOC stock in the upper 100 cm exhibited spatial dependence allowing the generation of spatial variability maps based on spatial (co)-regionalization. The CTI was inversely correlated with SOC stock and was the only auxiliary variable feasible to be used in cokriging interpolation. The heterotopic cokriging presented the best performance for mapping SOC stock. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. A soil-landscape framework for understanding spatial and temporal variability in biogeochemical processes in catchments

    Science.gov (United States)

    McGuire, K. J.; Bailey, S. W.; Ross, D. S.

    2017-12-01

    Heterogeneity in biophysical properties within catchments challenges how we quantify and characterize biogeochemical processes and interpret catchment outputs. Interactions between the spatiotemporal variability of hydrological states and fluxes and soil development can spatially structure catchments, leading to a framework for understanding patterns in biogeochemical processes. In an upland, glaciated landscape at the Hubbard Brook Experimental Forest (HBEF) in New Hampshire, USA, we are embracing the structure and organization of soils to understand the spatial relations between runoff production zones, distinct soil-biogeochemical environments, and solute retention and release. This presentation will use observations from the HBEF to demonstrate that a soil-landscape framework is essential in understanding the spatial and temporal variability of biogeochemical processes in this catchment. Specific examples will include how laterally developed soils reveal the location of active runoff production zones and lead to gradients in primary mineral dissolution and the distribution of weathering products along hillslopes. Soil development patterns also highlight potential carbon and nitrogen cycling hotspots, differentiate acidic conditions, and affect the regulation of surface water quality. Overall, this work demonstrates the importance of understanding the landscape-level structural organization of soils in characterizing the variation and extent of biogeochemical processes that occur in catchments.

  20. Geochemical distribution of harmful elements in top soils of an Italian National Interest Area (S.I.N.): the Domizio-Flegreo Littoral and Agro Aversano case study

    Science.gov (United States)

    Bove, M.; Grezzi, G.; Albanese, S.; de Vivo, B.; Lima, A.

    2009-04-01

    The Domizio-Flegreo Littoral and Agro Aversano area has been classified by the Italian Ministry of Environment (Italian Ministero dell'Ambiente e della Tutela del Territorio e del Mare) as a S.I.N. (Sito di Interesse Nazionale, L. 426/98 - Decreto 10 Gennaio 2000 - G.U. 29/5/01). In this category have been included all those contaminated lands that, both for their extension and their historical and present land use, are considered to be particularly harmful for human health. In Italy have been selected a total of 54 S.I.N.; among all of these, the Domizio-Flegreo Littoral and Agro Aversano S.I.N. is one of the widest (1564 Km2). The study area is located in north-western Campania region, from the Avella Mountain to the coastline, and from the Campi Flegrei area to the northern boundaries between Campania and Latium Regions. It includes a total of 77 towns from both Naples and Caserta provinces. The Domizio-Flegreo Littoral and Agro Aversano S.I.N. is characterized by a strongly urbanization in its internal portions, and by intensive agricultural activities in its northern and coastal portions. During past years this wide area has been the set of an unknown number of illegal activities controlled by the organized crime, including toxic waste disposal of unknown sources from different Regions of Italy, unauthorized building, intensive uncontrolled agricultural practices and so on. Part of these environmental crimes have been and are under investigations by Italian Authorities. For a geochemical characterization of this contaminated land, between May 2006 and January 2008, a total of 292 (179 in the Litorale Domizio-Flegreo and 113 in the Agro Aversano) top soils (5-15 cm depth) have been collected, with a sampling density of about 1 sample/5 Km2. The GIS™ and a new Multifractal Inverse Distance Weighted (MIDW) (Cheng 1999 a; b) method available in the software GeoDAS™ (Cheng, 2003; Lima et al., 2003) interpolated maps have been obtained. The latter are overlaid

  1. Environmental and management impacts on temporal variability of soil hydraulic properties

    Science.gov (United States)

    Bodner, G.; Scholl, P.; Loiskandl, W.; Kaul, H.-P.

    2012-04-01

    Soil hydraulic properties underlie temporal changes caused by different natural and management factors. Rainfall intensity, wet-dry cycles, freeze-thaw cycles, tillage and plant effects are potential drivers of the temporal variability. For agricultural purposes it is important to determine the possibility of targeted influence via management. In no-till systems e.g. root induced soil loosening (biopores) is essential to counteract natural soil densification by settling. The present work studies two years of temporal evolution of soil hydraulic properties in a no-till crop rotation (durum wheat-field pea) with two cover crops (mustard and rye) having different root systems (taproot vs. fibrous roots) as well as a bare soil control. Soil hydraulic properties such as near-saturated hydraulic conductivity, flow weighted pore radius, pore number and macroporosity are derived from measurements using a tension infiltrometer. The temporal dynamics are then analysed in terms of potential driving forces. Our results revealed significant temporal changes of hydraulic conductivity. When approaching saturation, spatial variability tended to dominate over the temporal evolution. Changes in near-saturated hydraulic conductivity were mainly a result of changing pore number, while the flow weighted mean pore radius showed less temporal dynamic in the no-till system. Macroporosity in the measured range of 0 to -10 cm pressure head ranged from 1.99e-4 to 8.96e-6 m3m-3. The different plant coverage revealed only minor influences on the observed system dynamics. Mustard increased slightly the flow weighted mean pore radius, being 0.090 mm in mustard compared to 0.085 mm in bare soil and 0.084 mm in rye. Still pore radius changes were of minor importance for the overall temporal dynamics. Rainfall was detected as major driving force of the temporal evolution of structural soil hydraulic properties at the site. Soil hydraulic conductivity in the slightly unsaturated range (-7 cm to -10

  2. Sensitivity of the biosphere-atmosphere transfer scheme (BATS) to the inclusion of variable soil characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, M.F.; Henderson-Sellers, A.; Dickinson, R.E.; Kennedy, P.J.

    1987-03-01

    The soils data of Wilson and Henderson-Sellers have been incorporated into the land-surface parameterization scheme of the NCAR Community Climate Model after Dickinson. A stand-alone version of this land-surface scheme, termed the Biosphere-Atmosphere Transfer Scheme (BATS), has been tested in a series of sensitivity experiments designed to assess the sensitivity of the scheme to the inclusion of variable soil characteristics. The cases investigated were for conditions designed to represent a low-latitude, evergreen forest; a low-latitude sand desert; a high-latitude coniferous forest; high-latitude tundra; and prairie grasslands, each for a specified time of year. The tundra included spring snowmelt and the grassland incorporated snow accumulation. The sensitivity experiments included varying the soil texture from a coarse texture typical of sand through a medium texture typical of loam to a fine texture typical of clay. The sensitivity of the formation to the specified total and upper soil column depth and the response to altering the parameterization of the soil albedo dependence upon soil wetness and snow-cover were also examined. The biosphere-atmosphere transfer scheme showed the greatest sensitivity to the soil texture variation, particularly to the associated variation in the hydraulic conductivity and diffusivity parameters. There was only a very small response to the change in the soil albedo dependence on wetness and, although the sensitivity to the snow-covered soil albedo via the response to roughness length/snowmasking depth was significant, the results were predictable. Soil moisture responses can also be initiated by changes in vegetation characteristics such as the stomatal resistance through changed canopy interaction which modify the radiation and water budgets of the soil surface.

  3. Petrographic, mineralogical and geochemical characterization of the Serrinha coal waste pile (Douro Coalfield, Portugal) and the potential environmental impacts on soil, sediments and surface waters

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, J. [Centro de Geologia, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Ferreira da Silva, E. [GeoBioTec, Geobiosciences, Geotechnologies and Geoengineering Research Center, Universidade de Aveiro, Campus de Santiago, 3810-193 Aveiro (Portugal); Li, Z.; Ward, C. [School of Biological, Earth and Environmental Sciences, University of New South Wales. Sydney, NSW 2052 (Australia); Flores, D. [Departamento de Geociencias, Ambiente e Ordenamento do Territorio, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

    2010-09-01

    Serrinha is the largest coal waste pile resulting from mining activities in the Douro Coalfield, Portugal. The exploitation of anthracite in tens of small mines caused some environmental impacts, as is the case of the coal waste piles that exist in old mines and adjacent areas. The Serrinha waste pile is essentially made up of 2 million tonnes of shales and carbonaceous shales, deposited in a topographical depression over about 30 years. Despite the environmental restoration accomplished in the Serrinha waste pile, some environmental problems seem to persist. In this study a petrographic, mineralogical and geochemical characterization was done in order to recognize and understand these problems. The materials studied were coal waste, sediments and waters from the drainage system and decanting basins, soils from the surrounding areas, leachates from waste material and neoformed minerals formed at the bottom of the waste pile. The main lithologies (carbonaceous shale and lithic arenite) and coal from the Douro Coalfield were also analyzed. Petrographic analysis shows some evidence of weathering (on organic and inorganic matter) related to the time of exposure to the weathering agents and the easy access of air within the waste pile (due to both the poor compaction and the heterogeneity of the material). Mineralogically, the composition of coal waste material has contributions from both the coal and the associated lithologies. R-type cluster analysis of the waste pile material allows two distinct clusters to be identified. In the first cluster a sulfide fraction is represented by the association of As, Cd, Cu, Pb, Ni and Zn, while Fe clustered with Al, Co, and Ti indicates that some of the Fe and the other elements are likely associated with silicate minerals such as clays. The second cluster, represented by Cr, V, Zr, Rb, REE, Mn, Li and Ba, probably represent a silicate fraction, perhaps detrital accessory minerals. The waste pile material, leachates, soils

  4. Holocene climate variability in arid Central Asia as revealed from high-resolution sedimentological and geochemical analyses of laminated sediments from Lake Chatyr Kol (Central Tian Shan, Kyrgyzstan)

    Science.gov (United States)

    Lauterbach, S.; Plessen, B.; Dulski, P.; Mingram, J.; Prasad, S.

    2013-12-01

    A pronounced trend from a predominantly wet climate during the early Holocene towards significantly drier conditions since the mid-Holocene, mainly attributed to the weakening of the Asian summer monsoon (ASM), is documented in numerous palaeoclimate records from the monsoon-influenced parts of Asia, e.g. the Tibetan Plateau and north- and southeastern China. In contrast, climate in the adjacent regions of mid-latitude arid Central Asia, located north and northwest of the Tibetan Plateau, is supposed to have been characterized by pronounced dry conditions during the early Holocene, wet conditions during the mid-Holocene and a rather moderate drying during the late Holocene, which is mainly attributed to the complex interplay between the mid-latitude Westerlies and the ASM. However, although mid-latitude Central Asia thus might represent a key region for the understanding of teleconnections between the ASM system and the Westerlies, knowledge about past climate development in this region is still ambiguous due to the limited number of high-resolution palaeoclimate records. Hence, new well-dated and highly resolved palaeoclimate records from this region are expected to provide important information about spatio-temporal changes in the regional interplay between Westerlies and ASM and thus aid the understanding of global climate teleconnections. As a part of the project CADY (Central Asian Climate Dynamics), aiming at reconstructing past climatic and hydrological variability in Central Asia, a sediment core of about 6.25 m length has been recovered from alpine Lake Chatyr Kol (40°36' N, 75°14' E, 3530 m a. s. l., surface area ~170 km2, maximum depth ~20 m), located in the Central Tian Shan of Kyrgyzstan. Sediment microfacies analysis on large-scale petrographic thin sections reveals continuously sub-mm scale laminated sediments throughout the record except for the uppermost ca. 60 cm. Microsedimentological characterization of these laminae, which are most probably

  5. Selecting minimum dataset soil variables using PLSR as a regressive multivariate method

    Science.gov (United States)

    Stellacci, Anna Maria; Armenise, Elena; Castellini, Mirko; Rossi, Roberta; Vitti, Carolina; Leogrande, Rita; De Benedetto, Daniela; Ferrara, Rossana M.; Vivaldi, Gaetano A.

    2017-04-01

    Long-term field experiments and science-based tools that characterize soil status (namely the soil quality indices, SQIs) assume a strategic role in assessing the effect of agronomic techniques and thus in improving soil management especially in marginal environments. Selecting key soil variables able to best represent soil status is a critical step for the calculation of SQIs. Current studies show the effectiveness of statistical methods for variable selection to extract relevant information deriving from multivariate datasets. Principal component analysis (PCA) has been mainly used, however supervised multivariate methods and regressive techniques are progressively being evaluated (Armenise et al., 2013; de Paul Obade et al., 2016; Pulido Moncada et al., 2014). The present study explores the effectiveness of partial least square regression (PLSR) in selecting critical soil variables, using a dataset comparing conventional tillage and sod-seeding on durum wheat. The results were compared to those obtained using PCA and stepwise discriminant analysis (SDA). The soil data derived from a long-term field experiment in Southern Italy. On samples collected in April 2015, the following set of variables was quantified: (i) chemical: total organic carbon and nitrogen (TOC and TN), alkali-extractable C (TEC and humic substances - HA-FA), water extractable N and organic C (WEN and WEOC), Olsen extractable P, exchangeable cations, pH and EC; (ii) physical: texture, dry bulk density (BD), macroporosity (Pmac), air capacity (AC), and relative field capacity (RFC); (iii) biological: carbon of the microbial biomass quantified with the fumigation-extraction method. PCA and SDA were previously applied to the multivariate dataset (Stellacci et al., 2016). PLSR was carried out on mean centered and variance scaled data of predictors (soil variables) and response (wheat yield) variables using the PLS procedure of SAS/STAT. In addition, variable importance for projection (VIP

  6. Geochemical and physical properties, distribution coefficients of soils and sediments at the Olkiluoto Island and in the reference area in 2010-2011

    International Nuclear Information System (INIS)

    Lahdenperae, A.-M.

    2014-04-01

    The report summarises the chemical, physical and mineralogical data and the calculated 'in situ' distribution coefficients (K d ) values of the indigenous elements from the different types of soil and sediment samples at the Olkiluoto Island and in the Reference area that were taken in 2010-2011. The data has been collected in order to extend the understanding of the site evolution and for radionuclide transport analyses and modelling. 'In situ' distribution coefficients, K d values are used to indicate the relevant mobility of elements and radionuclides. This report is part of the entirety of soil and sediment data from different soil types, soil layers and environmental conditions collected earlier for the biosphere site description and development. Soil and sediment samples were taken at various depths of humus, peat, gyttja, sandy/fine sandy till and cropland soils. The analyses procedure varied to some extent between the samples. In all samples were analysed pH, LOI, C, N, and the total concentrations of the elements using HNO 3 -HF extraction. The 'in situ' K d values were calculated using the formula by Sheppard et al.. For selected samples the easily leachable fraction was analysed by NH 4 Ac (pH 4.5). Bulk density and mineralogy was determined for a few samples. Grain size distribution was measured only from till samples. The results are discussed and the physical-chemical data and distribution coefficients of the results are presented. The cation exchange capacity and base saturation are calculated for the sandy/fine sandy till samples from Olkiluoto. The K d values of the important indigenous elements Ag, Cl, Cs, I, Mo, Ni, Se and Sr are of main interest in biosphere development due to the longest half-lives of the associated radionuclides, thus having long interaction times. The K d data are inherently extremely variable due to nature of practical quantity in question, aggregating a number of processes into a single value, but the data also vary

  7. Geochemical and physical properties, distribution coefficients of soils and sediments at the Olkiluoto Island and in the reference area in 2010-2011

    Energy Technology Data Exchange (ETDEWEB)

    Lahdenperae, A.-M. [Saanio and Riekkola Oy, Helsinki (Finland)

    2014-04-15

    The report summarises the chemical, physical and mineralogical data and the calculated 'in situ' distribution coefficients (K{sub d}) values of the indigenous elements from the different types of soil and sediment samples at the Olkiluoto Island and in the Reference area that were taken in 2010-2011. The data has been collected in order to extend the understanding of the site evolution and for radionuclide transport analyses and modelling. 'In situ' distribution coefficients, K{sub d} values are used to indicate the relevant mobility of elements and radionuclides. This report is part of the entirety of soil and sediment data from different soil types, soil layers and environmental conditions collected earlier for the biosphere site description and development. Soil and sediment samples were taken at various depths of humus, peat, gyttja, sandy/fine sandy till and cropland soils. The analyses procedure varied to some extent between the samples. In all samples were analysed pH, LOI, C, N, and the total concentrations of the elements using HNO{sub 3}-HF extraction. The 'in situ' K{sub d} values were calculated using the formula by Sheppard et al.. For selected samples the easily leachable fraction was analysed by NH{sub 4}Ac (pH 4.5). Bulk density and mineralogy was determined for a few samples. Grain size distribution was measured only from till samples. The results are discussed and the physical-chemical data and distribution coefficients of the results are presented. The cation exchange capacity and base saturation are calculated for the sandy/fine sandy till samples from Olkiluoto. The K{sub d} values of the important indigenous elements Ag, Cl, Cs, I, Mo, Ni, Se and Sr are of main interest in biosphere development due to the longest half-lives of the associated radionuclides, thus having long interaction times. The K{sub d} data are inherently extremely variable due to nature of practical quantity in question, aggregating a number of

  8. Sorption–bioavailability nexus of arsenic and cadmium in variable-charge soils

    International Nuclear Information System (INIS)

    Bolan, Nanthi; Mahimairaja, Santiago; Kunhikrishnan, Anitha; Naidu, Ravi

    2013-01-01

    Highlights: ► Demonstrates the nexus between sorption and bioavailability of As and Cd in variable-charge soils. ► Liming variable-charge soils increase negative charge, thereby decreasing Cd bioavailability. ► Ageing of As and Cd increases their immobilization, thereby decreasing bioavailability. ► Phosphate enhances desorption and phytoavailability of As from sheep dip soil. ► Metal(loid)s transfer to food chain can be managed by controlling sorption reactions. -- Abstract: In this work, the nexus between sorption and bioavailability of arsenic (As) and cadmium (Cd) as affected by soil type, soil pH, ageing, and mobilizing agents were examined. The adsorption of As and Cd was examined using a number of allophanic and non-allophanic soils which vary in their charge components. The effect of pH and ageing on the bioavailability of As and Cd was examined using spiked soils in a plant growth experiment. The effect of phosphate (P)-induced mobility of As on its bioavailability was examined using a naturally contaminated sheep dip soil. The results indicated that the adsorption of both As and Cd varied amongst the soils, and the difference in Cd adsorption is attributed to the difference in surface charge. An increase in soil pH increased net negative charge by an average of 45.7 mmol/kg/pH thereby increasing cation (Cd) adsorption; whereas, the effect of pH on anion (As) adsorption was inconsistent. The bioavailability of As and Cd decreased by 3.31- and 2.30-fold, respectively, with ageing which may be attributed to increased immobilization. Phosphate addition increased the mobility and bioavailability of As by 4.34- and 3.35-fold, respectively, in the sheep dip soil. However, the net effect of P on As phytoavailability depends on the extent of P-induced As mobilization in soils and P-induced competition for As uptake by roots. The results demonstrate the nexus between sorption and bioavailability of As and Cd in soils, indicating that the effects of

  9. Sorption–bioavailability nexus of arsenic and cadmium in variable-charge soils

    Energy Technology Data Exchange (ETDEWEB)

    Bolan, Nanthi, E-mail: Nanthi.Bolan@unisa.edu.au [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes, SA (Australia); CRC for Contamination Assessment and Remediation in the Environment, University of South Australia, Mawson Lakes, SA (Australia); Mahimairaja, Santiago [Department of Environmental Science, Tamil Nadu Agricultural University, Coimbatore, Tamil Nadu (India); Kunhikrishnan, Anitha [Chemical Safety Division, Department of Agro-Food Safety, National Academy of Agricultural Science, Suwon-si, Gyeonggi-do 441-707 (Korea, Republic of); Naidu, Ravi [Centre for Environmental Risk Assessment and Remediation, University of South Australia, Mawson Lakes, SA (Australia); CRC for Contamination Assessment and Remediation in the Environment, University of South Australia, Mawson Lakes, SA (Australia)

    2013-10-15

    Highlights: ► Demonstrates the nexus between sorption and bioavailability of As and Cd in variable-charge soils. ► Liming variable-charge soils increase negative charge, thereby decreasing Cd bioavailability. ► Ageing of As and Cd increases their immobilization, thereby decreasing bioavailability. ► Phosphate enhances desorption and phytoavailability of As from sheep dip soil. ► Metal(loid)s transfer to food chain can be managed by controlling sorption reactions. -- Abstract: In this work, the nexus between sorption and bioavailability of arsenic (As) and cadmium (Cd) as affected by soil type, soil pH, ageing, and mobilizing agents were examined. The adsorption of As and Cd was examined using a number of allophanic and non-allophanic soils which vary in their charge components. The effect of pH and ageing on the bioavailability of As and Cd was examined using spiked soils in a plant growth experiment. The effect of phosphate (P)-induced mobility of As on its bioavailability was examined using a naturally contaminated sheep dip soil. The results indicated that the adsorption of both As and Cd varied amongst the soils, and the difference in Cd adsorption is attributed to the difference in surface charge. An increase in soil pH increased net negative charge by an average of 45.7 mmol/kg/pH thereby increasing cation (Cd) adsorption; whereas, the effect of pH on anion (As) adsorption was inconsistent. The bioavailability of As and Cd decreased by 3.31- and 2.30-fold, respectively, with ageing which may be attributed to increased immobilization. Phosphate addition increased the mobility and bioavailability of As by 4.34- and 3.35-fold, respectively, in the sheep dip soil. However, the net effect of P on As phytoavailability depends on the extent of P-induced As mobilization in soils and P-induced competition for As uptake by roots. The results demonstrate the nexus between sorption and bioavailability of As and Cd in soils, indicating that the effects of

  10. Environmental and management influences on temporal variability of near saturated soil hydraulic properties☆

    Science.gov (United States)

    Bodner, G.; Scholl, P.; Loiskandl, W.; Kaul, H.-P.

    2013-01-01

    Structural porosity is a decisive property for soil productivity and soil environmental functions. Hydraulic properties in the structural range vary over time in response to management and environmental influences. Although this is widely recognized, there are few field studies that determine dominant driving forces underlying hydraulic property dynamics. During a three year field experiment we measured temporal variability of soil hydraulic properties by tension infiltrometry. Soil properties were characterized by hydraulic conductivity, effective macroporosity and Kosugi's lognormal pore size distribution model. Management related influences comprised three soil cover treatment (mustard and rye vs. fallow) and an initial mechanical soil disturbance with a rotary harrow. Environmental driving forces were derived from meteorological and soil moisture data. Soil hydraulic parameters varied over time by around one order of magnitude. The coefficient of variation of soil hydraulic conductivity K(h) decreased from 69.5% at saturation to 42.1% in the more unsaturated range (− 10 cm pressure head). A slight increase in the Kosugi parameter showing pore heterogeneity was observed under the rye cover crop, reflecting an enhanced structural porosity. The other hydraulic parameters were not significantly influenced by the soil cover treatments. Seedbed preparation with a rotary harrow resulted in a fourfold increase in macroporosity and hydraulic conductivity next to saturation, and homogenized the pore radius distribution. Re-consolidation after mechanical loosening lasted over 18 months until the soil returned to its initial state. The post-tillage trend of soil settlement could be approximated by an exponential decay function. Among environmental factors, wetting-drying cycles were identified as dominant driving force explaining short term hydraulic property changes within the season (r2 = 0.43 to 0.59). Our results suggested that beside considering average

  11. A stochastic analysis of the influence of soil and climatic variability on the estimate of pesticide ground water polution potential

    Science.gov (United States)

    Jury, William A.; Gruber, Joachim

    1989-12-01

    Soil and climatic variability contribute in an unknown manner to the leaching of pesticides below the surface soil zone where degradation occurs at maximum levels. In this paper we couple the climatic variability model of Eagleson (1978) to the soil variability transport model of Jury (1982) to produce a probability density distribution of residual mass fraction (RMF) remaining after leaching below the surface degradation zone. Estimates of the RMF distribution are shown to be much more sensitive to soil variability than climatic variability, except when the residence time of the chemical is shorter than one year. When soil variability dominates climatic variability, the applied water distribution may be replaced by a constant average water application rate without serious error. Simulations of leaching are run with 10 pesticides in two climates and in two representative soil types with a range of soil variability. Variability in soil or climate act to produce a nonnegligible probability of survival of a small value of residual mass even for relatively immobile compounds which are predicted to degrade completely by a simple model which neglects variability. However, the simpler model may still be useful for screening pesticides for groundwater pollution potential if somewhat larger residual masses of a given compound are tolerated. Monte Carlo simulations of the RMF distribution agreed well with model predictions over a wide range of pesticide properties.

  12. Spatial variability of caesium-137 activities in soils in the Jura mountains

    International Nuclear Information System (INIS)

    Pimou-Heumou, G.; Lucot, E.; Crini, N.; Briot, M.; Badot, P.M.

    2011-01-01

    275 soil samples were taken in the catchment area of the upper part of the Doubs river located in the Jura mountains according to a sampling strategy designed to evaluate the extent of the spatial variability of 137 Cs activities and to identify its main sources. 137 Cs activities ranged between about 1000 and 12000 Bq.m -2 with an average of approximately 3600 Bq.m -2 . The spatial variability of the contamination is high: 137 Cs activity shows statistically significant links with altitude, soil organic matter and land cover, whereas the other studied parameters, i.e. soil type and topographic position, do not constitute significant sources of variation. These results are discussed in terms of evaluation of the radioactive contamination on a regional scale. They show that to be satisfactory, a sampling strategy must necessarily take into account the various types of land cover. (authors)

  13. Variability of soil potential for biodegradation of petroleum hydrocarbons in a heterogeneous subsurface

    DEFF Research Database (Denmark)

    Kristensen, Andreas Houlberg; Poulsen, Tjalfe; Mortensen, Lars

    2010-01-01

    for biodegradation was highly variable, which from autoregressive state-space modeling was partly explained by changes in soil air-filled porosity and gravimetric water content. The results suggest considering biological heterogeneity when evaluating the fate of contaminants in the subsurface.......Quantifying the spatial variability of factors affecting natural attenuation of hydrocarbons in the unsaturated zone is important to (i) performing a reliable risk assessment and (ii) evaluating the possibility for bioremediation of petroleum-polluted sites. Most studies to date have focused...... on the shallow unsaturated zone. Based on a data set comprising analysis of about 100 soil samples taken in a 16-m-deep unsaturated zone polluted with volatile petroleum compounds, we statistically and geostatistically analyzed values of essential soil properties. The subsurface of the site was highly layered...

  14. Screening variability and change of soil moisture under wide-ranging climate conditions: Snow dynamics effects.

    Science.gov (United States)

    Verrot, Lucile; Destouni, Georgia

    2015-01-01

    Soil moisture influences and is influenced by water, climate, and ecosystem conditions, affecting associated ecosystem services in the landscape. This paper couples snow storage-melting dynamics with an analytical modeling approach to screening basin-scale, long-term soil moisture variability and change in a changing climate. This coupling enables assessment of both spatial differences and temporal changes across a wide range of hydro-climatic conditions. Model application is exemplified for two major Swedish hydrological basins, Norrström and Piteälven. These are located along a steep temperature gradient and have experienced different hydro-climatic changes over the time period of study, 1950-2009. Spatially, average intra-annual variability of soil moisture differs considerably between the basins due to their temperature-related differences in snow dynamics. With regard to temporal change, the long-term average state and intra-annual variability of soil moisture have not changed much, while inter-annual variability has changed considerably in response to hydro-climatic changes experienced so far in each basin.

  15. Areal variability of the mineral soil cover in a reclaimed soda waste dumping site

    Directory of Open Access Journals (Sweden)

    Klatka Sławomir

    2017-03-01

    Full Text Available Areal variability of the mineral soil cover in a reclaimed soda waste dumping site. This paper provides an analysis of the areal variability of the thickness and selected physical and chemical properties of the mineral cover formed in the process of settling ponds reclamation at the former Krakow Soda Plant “Solvay”. The topsoil is intended to provide a substrate for plants, therefore, its quality is the main determinant of the development for herbaceous and woody vegetation. Areal variability of the topsoil parameters was determined by kriging. In the context of the envisaged direction of management of the settling ponds, the analysis showed that electrical conductivity, thickness of the soil cover and the sand fraction content have potentially the highest impact on the diversification of vegetation. Understanding the spatial variability of the soil cover parameters, that are essential for vegetation, may contribute to increasing the efficiency of biological reclamation and also to cost reduction. Precise selection of the areas unsuitable for plant growth makes it possible to improve soil parameters on limited areas similarly as in the precision agriculture.

  16. Representing major soil variability at regional scale by constrained Latin Hypercube Sampling of remote sensing data

    NARCIS (Netherlands)

    Mulder, V.L.; Bruin, de S.; Schaepman, M.E.

    2013-01-01

    This paper presents a sparse, remote sensing-based sampling approach making use of conditioned Latin Hypercube Sampling (cLHS) to assess variability in soil properties at regional scale. The method optimizes the sampling scheme for a defined spatial population based on selected covariates, which are

  17. Soil temperature variability in complex terrain measured using fiber-optic distributed temperature sensing

    Science.gov (United States)

    Soil temperature (Ts) exerts critical controls on hydrologic and biogeochemical processes but magnitude and nature of Ts variability in a landscape setting are rarely documented. Fiber optic distributed temperature sensing systems (FO-DTS) potentially measure Ts at high density over a large extent. ...

  18. Landsat thematic mapper (TM) soil variability analysis over Webster County, Iowa

    Science.gov (United States)

    Thompson, D. R.; Henderson, K. E.; Pitts, D. E.

    1984-01-01

    Thematic mapper simulator (TMS) data acquired June 7, June 23, and July 31, 1982, and Landsat thematic mapper (TM) data acquired August 2, September 3, and October 21, 1982, over Webster County, Iowa, were examined for within-field soil effects on corn and soybean spectral signatures. It was found that patterns displayed on various computer-generated map products were in close agreement with the detailed soil survey of the area. The difference in spectral values appears to be due to a combination of subtle soil properties and crop growth patterns resulting from the different soil properties. Bands 4 (0.76-.90 micron), 5 (1.55-1.75 micron), and 7 (2.08-2.35 micron) were found to be responding to the within-field soil variability even with increasing ground cover. While these results are preliminary, they do indicate that the soil influence on the vegetation is being detected by TM and should provide improved information relating to crop and soil properties.

  19. Spatial Variability of Physical Soil Quality Index of an Agricultural Field

    Directory of Open Access Journals (Sweden)

    Sheikh M. Fazle Rabbi

    2014-01-01

    Full Text Available A field investigation was carried out to evaluate the spatial variability of physical indicators of soil quality of an agricultural field and to construct a physical soil quality index (SQIP map. Surface soil samples were collected using 10  m×10 m grid from an Inceptisol on Ganges Tidal Floodplain of Bangladesh. Five physical soil quality indicators, soil texture, bulk density, porosity, saturated hydraulic conductivity (KS, and aggregate stability (measured as mean weight diameter, MWD were determined. The spatial structures of sand, clay, and KS were moderate but the structure was strong for silt, bulk density, porosity, and MWD. Each of the physical soil quality indicators was transformed into 0 and 1 using threshold criteria which are required for crop production. The transformed indicators were the combined into SQIP. The kriged SQIP map showed that the agricultural field studied could be divided into two parts having “good physical quality” and “poor physical soil quality.”

  20. Controls on the spatial variability of key soil properties: comparing field data with a mechanistic soilscape evolution model

    Science.gov (United States)

    Vanwalleghem, T.; Román, A.; Giraldez, J. V.

    2016-12-01

    There is a need for better understanding the processes influencing soil formation and the resulting distribution of soil properties. Soil properties can exhibit strong spatial variation, even at the small catchment scale. Especially soil carbon pools in semi-arid, mountainous areas are highly uncertain because bulk density and stoniness are very heterogeneous and rarely measured explicitly. In this study, we explore the spatial variability in key soil properties (soil carbon stocks, stoniness, bulk density and soil depth) as a function of processes shaping the critical zone (weathering, erosion, soil water fluxes and vegetation patterns). We also compare the potential of a geostatistical versus a mechanistic soil formation model (MILESD) for predicting these key soil properties. Soil core samples were collected from 67 locations at 6 depths. Total soil organic carbon stocks were 4.38 kg m-2. Solar radiation proved to be the key variable controlling soil carbon distribution. Stone content was mostly controlled by slope, indicating the importance of erosion. Spatial distribution of bulk density was found to be highly random. Finally, total carbon stocks were predicted using a random forest model whose main covariates were solar radiation and NDVI. The model predicts carbon stocks that are double as high on north versus south-facing slopes. However, validation showed that these covariates only explained 25% of the variation in the dataset. Apparently, present-day landscape and vegetation properties are not sufficient to fully explain variability in the soil carbon stocks in this complex terrain under natural vegetation. This is attributed to a high spatial variability in bulk density and stoniness, key variables controlling carbon stocks. Similar results were obtained with the mechanistic soil formation model MILESD, suggesting that more complex models might be needed to further explore this high spatial variability.

  1. Spatio-temporal soil moisture variability in Southwest Germany observed with a new monitoring network within the COPS domain

    Energy Technology Data Exchange (ETDEWEB)

    Krauss, Liane; Kottmeier, Christoph [Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany). Inst. for Meteorology and Climate Research; Hauck, Christian [Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany). Inst. for Meteorology and Climate Research; Fribourg Univ. (Switzerland). Dept. of Geosciences

    2010-12-15

    Within the 'Convective and Orographically-induced Precipitation Study' (COPS) 2007 in Southwest Germany and Northeast France a soil moisture monitoring network was installed. The aim of the network is to identify the interaction between the temporal and spatial variability of the soil moisture field and its influence on the energy balance and the moisture availability in the planetary boundary layer. The network is comprised of a large number of newly developed low-cost soil moisture sensors based on the frequency-domain reflectometry method (FDR). In total 47 soil moisture stations within the COPS domain were each equipped with two to four sensors simultaneously measuring vertical profiles of soil moisture and soil temperature down to 50 cm depth. This contribution describes the soil moisture network, its installation procedure and the calibration of the sensor output signal. Furthermore we discuss the soil texture distribution within the study area and present first analyses of the spatio-temporal soil moisture variability during a 13 month period from June 2007 till June 2008 based on regional differences and site specific properties (altitude and soil texture). Results show that the altitude plays a key role for the overall soil moisture pattern relative to the area mean due to the direct linkage to precipitation patterns. Soil texture controls the vertical soil moisture gradient relative to the near surface soil moisture, as their properties control water storage and drainage characteristics. Both factors significantly influence regional soil moisture patterns in Southwest Germany. (orig.)

  2. Effect of source integration on the geochemical fluxes from springs

    International Nuclear Information System (INIS)

    Frisbee, Marty D.; Phillips, Fred M.; White, Art F.; Campbell, Andrew R.; Liu, Fengjing

    2013-01-01

    Geochemical fluxes from watersheds are typically defined using mass-balance methods that essentially lump all weathering processes operative in a watershed into a single flux of solute mass measured in streamflow at the watershed outlet. However, it is important that we understand how weathering processes in different hydrological zones of a watershed (i.e., surface, unsaturated, and saturated zones) contribute to the total geochemical flux from the watershed. This capability will improve understanding of how geochemical fluxes from these different zones may change in response to climate change. Here, the geochemical flux from weathering processes occurring solely in the saturated zone is investigated. This task, however, remains exceedingly difficult due to the sparsity of subsurface sampling points, especially in large, remote, and/or undeveloped watersheds. In such cases, springflow is often assumed to be a proxy for groundwater (defined as water residing in fully saturated geologic formations). However, springflow generation may integrate different sources of water including, but not limited to, groundwater. The authors’ hypothesis is that long-term estimates of geochemical fluxes from groundwater using springflow proxies will be too large due to the integrative nature of springflow generation. Two conceptual models of springflow generation are tested using endmember mixing analyses (EMMA) on observations of spring chemistries and stable isotopic compositions in a large alpine watershed in the San Juan Mountains of southwestern Colorado. In the “total springflow” conceptual model, springflow is assumed to be 100% groundwater. In the “fractional springflow” conceptual model, springflow is assumed to be an integration of different sources of water (e.g., groundwater, unsaturated flow, preferential flow in the soil, etc.) and groundwater is only a fractional component. The results indicate that groundwater contributions in springflow range from 2% to 100

  3. Recalcitrant soil organic matter : how useful is radiocarbon for estimating its amount and variability?

    International Nuclear Information System (INIS)

    Tate, K.; Parshotam, A.; Scott, Neal

    1997-01-01

    The role of the terrestrial biosphere in the global carbon (C) cycle is poorly understood because of the complex biology underlying C storage, the spatial variability of vegetation and soils, and the effects of land use. Little is known about the nature, amount and variability of recalcitrant C in soils, despite the importance of determining whether soils behave as sources or sinks of CO 2 . 14 C dating indicates that most soils contain this very stable C fraction, with turnover times of millennia. The amount of this fraction, named the Inert Organic Matter (IOM) in one model, is estimated indirectly using the 'bomb' 14 C content of soil. In nine New Zealand grassland and forest ecosystems, amounts of IOM-C ranged between 0.03 to 2.9 kg C m -2 (1-18% of soil C to 0.25m depth). A decomposable C fraction, considered to be more susceptible to the effects of climate and land use, was estimated by subtracting the IOM-C fraction from the total soil organic C. Turnover times ranged between 8 and 36 years, and were inversely related to mean annual temperature (R 2 0.91, P 13 C NMR and pyrolysis-mass spectrometry as alkyl C. Paradoxically, for some ecosystems, the variation in IOM-C appears to be best explained by differences in soil hydrological conditions rather than by the accumulation of a discrete C fraction. Thus characterisation of environmental factors that constrain decomposition could be most useful for explaining the differences observed in IOM across different ecosystems, climates and soils. Despite the insights the modelling approach using 'bomb' 14 C provides into mechanisms for organic matter stabilisation, on theoretical grounds the validity of using 14 C measurements to estimate a recalcitrant C fraction that by definition contains no 14 C is questionable. We conclude that more rigorous models are needed with pools that can be experimentally verified, to improve understanding of the spatial variability of soil C storage. (author)

  4. Evaluation of spatial variability of metal bioavailability in soils using geostatistics

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Hauschild, Michael Zwicky; Rosenbaum, Ralph K.

    2012-01-01

    Soil properties show signifficant spatial variability at local, regional and continental scales. This is a challenge for life cycle impact assessment (LCIA) of metals, because fate, bioavailability and effect factors are controlled by environmental chemistry and can vary orders of magnitude...... is performed using ArcGIS Geostatistical Analyst. Results show that BFs of copper span a range of 6 orders of magnitude, and have signifficant spatial variability at local and continental scales. The model nugget variance is signifficantly higher than zero, suggesting the presence of spatial variability...

  5. Assessing geotechnical centrifuge modelling in addressing variably saturated flow in soil and fractured rock.

    Science.gov (United States)

    Jones, Brendon R; Brouwers, Luke B; Van Tonder, Warren D; Dippenaar, Matthys A

    2017-05-01

    The vadose zone typically comprises soil underlain by fractured rock. Often, surface water and groundwater parameters are readily available, but variably saturated flow through soil and rock are oversimplified or estimated as input for hydrological models. In this paper, a series of geotechnical centrifuge experiments are conducted to contribute to the knowledge gaps in: (i) variably saturated flow and dispersion in soil and (ii) variably saturated flow in discrete vertical and horizontal fractures. Findings from the research show that the hydraulic gradient, and not the hydraulic conductivity, is scaled for seepage flow in the geotechnical centrifuge. Furthermore, geotechnical centrifuge modelling has been proven as a viable experimental tool for the modelling of hydrodynamic dispersion as well as the replication of similar flow mechanisms for unsaturated fracture flow, as previously observed in literature. Despite the imminent challenges of modelling variable saturation in the vadose zone, the geotechnical centrifuge offers a powerful experimental tool to physically model and observe variably saturated flow. This can be used to give valuable insight into mechanisms associated with solid-fluid interaction problems under these conditions. Findings from future research can be used to validate current numerical modelling techniques and address the subsequent influence on aquifer recharge and vulnerability, contaminant transport, waste disposal, dam construction, slope stability and seepage into subsurface excavations.

  6. Soil structure interaction model and variability of parameters in seismic analysis of nuclear island connected building

    International Nuclear Information System (INIS)

    Subramanian, K.V.; Palekar, S.M.; Bavare, M.S.; Mapari, H.A.; Patel, S.C.; Pillai, C.S.

    2005-01-01

    This paper provides salient features of the Soil Structure Interaction analysis of Nuclear Island Connected Building (NICB). The dynamic analysis of NICB is performed on a full 3D model accounting for the probable variation in the stiffness of the founding medium. A range analyses was performed to establish the effect of variability of subgrade parameters on the results of seismic analyses of NICB. This paper presents details of various analyses with respect to the subgrade model, uncertainties in subgrade properties, results of seismic analyses and a study of effect of the variability of parameters on the results of these analyses. The results of this study indicate that the variability of soil parameters beyond a certain value of shear wave velocity does not influence the response and in fact the response marginally diminishes. (authors)

  7. Spatial variability of detrended soil plow layer penetrometer resistance transect in a sugarcane field

    Science.gov (United States)

    Pérez, Luis D.; Cumbrera, Ramiro; Mato, Juan; Millán, Humberto; Tarquis, Ana M.

    2015-04-01

    Spatial variability of soil properties is relevant for identifying those zones with physical degradation. In this sense, one has to face the problem of identifying the origin and distribution of spatial variability patterns (Brouder et al., 2001; Millán et al., 2012). The objective of the present work was to quantify the spatial structure of soil penetrometer resistance (PR) collected from a transect data consisted of 221 points equidistant. In each sampling, readings were obtained from 0 cm till 70 cm of depth, with an interval of 5 cm (Pérez, 2012). The study was conducted on a Vertisol (Typic Hapludert) dedicated to sugarcane (Saccharum officinarum L.) production during the last sixty years (Pérez et al., 2010). Recently, scaling approach has been applied on the determination of the scaling data properties (Tarquis et al., 2008; Millán et al., 2012; Pérez, 2012). We focus in the Hurst analysis to characterize the data variability for each depth. Previously a detrended analysis was conducted in order to better study de intrinsic variability of the series. The Hurst exponent (H) for each depth was estimated showing a characteristic pattern and differentiating PR evolution in depth. References Brouder, S., Hofmann, B., Reetz, H.F., 2001. Evaluating spatial variability of soil parameters for input management. Better Crops 85, 8-11. Millán, H; AM Tarquís, Luís D. Pérez, Juan Mato, Mario González-Posada, 2012. Spatial variability patterns of some Vertisol properties at a field scale using standardized data. Soil and Tillage Research, 120, 76-84. Pérez, Luís D. 2012. Influencia de la maquinaria agrícola sobre la variabilidad espacial de la compactación del suelo. Aplicación de la metodología geoestadística-fractal. PhD thesis, UPM (In Spanish). Pérez, Luís D., Humberto Millán, Mario González-Posada 2010. Spatial complexity of soil plow layer penetrometer resistance as influenced by sugarcane harvesting: A prefractal approach. Soil and Tillage

  8. Spatiotemporal predictions of soil properties and states in variably saturated landscapes

    Science.gov (United States)

    Franz, Trenton E.; Loecke, Terrance D.; Burgin, Amy J.; Zhou, Yuzhen; Le, Tri; Moscicki, David

    2017-07-01

    Understanding greenhouse gas (GHG) fluxes from landscapes with variably saturated soil conditions is challenging given the highly dynamic nature of GHG fluxes in both space and time, dubbed hot spots, and hot moments. On one hand, our ability to directly monitor these processes is limited by sparse in situ and surface chamber observational networks. On the other hand, remote sensing approaches provide spatial data sets but are limited by infrequent imaging over time. We use a robust statistical framework to merge sparse sensor network observations with reconnaissance style hydrogeophysical mapping at a well-characterized site in Ohio. We find that combining time-lapse electromagnetic induction surveys with empirical orthogonal functions provides additional environmental covariates related to soil properties and states at high spatial resolutions ( 5 m). A cross-validation experiment using eight different spatial interpolation methods versus 120 in situ soil cores indicated an 30% reduction in root-mean-square error for soil properties (clay weight percent and total soil carbon weight percent) using hydrogeophysical derived environmental covariates with regression kriging. In addition, the hydrogeophysical derived environmental covariates were found to be good predictors of soil states (soil temperature, soil water content, and soil oxygen). The presented framework allows for temporal gap filling of individual sensor data sets as well as provides flexible geometric interpolation to complex areas/volumes. We anticipate that the framework, with its flexible temporal and spatial monitoring options, will be useful in designing future monitoring networks as well as support the next generation of hyper-resolution hydrologic and biogeochemical models.

  9. Spatial variability of soil carbon stock in the Urucu river basin, Central Amazon-Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Ceddia, Marcos Bacis, E-mail: marcosceddia@gmail.com [Department of Soil, Institute of Agronomy, Universidade Federal Rural do Rio de Janeiro (UFRRJ), Seropédica, RJ 23890-000 (Brazil); Villela, André Luis Oliveira [Colégio Técnico da UFRRJ, RJ, Seropédica 23890-000 (Brazil); Pinheiro, Érika Flávia Machado [Department of Soil, Institute of Agronomy, Universidade Federal Rural do Rio de Janeiro (UFRRJ), Seropédica, RJ 23890-000 (Brazil); Wendroth, Ole [Department of Plant & Soil Sciences, University of Kentucky, College of Agriculture, Lexington, KY (United States)

    2015-09-01

    The Amazon Forest plays a major role in C sequestration and release. However, few regional estimates of soil organic carbon (SOC) stock in this ecoregion exist. One of the barriers to improve SOC estimates is the lack of recent soil data at high spatial resolution, which hampers the application of new methods for mapping SOC stock. The aims of this work were: (i) to quantify SOC stock under undisturbed vegetation for the 0–30 and the 0–100 cm under Amazon Forest; (ii) to correlate the SOC stock with soil mapping units and relief attributes and (iii) to evaluate three geostatistical techniques to generate maps of SOC stock (ordinary, isotopic and heterotopic cokriging). The study site is located in the Central region of Amazon State, Brazil. The soil survey covered the study site that has an area of 80 km{sup 2} and resulted in a 1:10,000 soil map. It consisted of 315 field observations (96 complete soil profiles and 219 boreholes). SOC stock was calculated by summing C stocks by horizon, determined as a product of BD, SOC and the horizon thickness. For each one of the 315 soil observations, relief attributes were derived from a topographic map to understand SOC dynamics. The SOC stocks across 30 and 100 cm soil depth were 3.28 and 7.32 kg C m{sup −2}, respectively, which is, 34 and 16%, lower than other studies. The SOC stock is higher in soils developed in relief forms exhibiting well-drained soils, which are covered by Upland Dense Tropical Rainforest. Only SOC stock in the upper 100 cm exhibited spatial dependence allowing the generation of spatial variability maps based on spatial (co)-regionalization. The CTI was inversely correlated with SOC stock and was the only auxiliary variable feasible to be used in cokriging interpolation. The heterotopic cokriging presented the best performance for mapping SOC stock. - Highlights: • The SOC stocks across 30 and 100 cm depth were 3.28 and 7.32 kg C m{sup −2}, respectively. • SOC stocks were 34 and 16

  10. Spatial variability of soil carbon stock in the Urucu river basin, Central Amazon-Brazil

    International Nuclear Information System (INIS)

    Ceddia, Marcos Bacis; Villela, André Luis Oliveira; Pinheiro, Érika Flávia Machado; Wendroth, Ole

    2015-01-01

    The Amazon Forest plays a major role in C sequestration and release. However, few regional estimates of soil organic carbon (SOC) stock in this ecoregion exist. One of the barriers to improve SOC estimates is the lack of recent soil data at high spatial resolution, which hampers the application of new methods for mapping SOC stock. The aims of this work were: (i) to quantify SOC stock under undisturbed vegetation for the 0–30 and the 0–100 cm under Amazon Forest; (ii) to correlate the SOC stock with soil mapping units and relief attributes and (iii) to evaluate three geostatistical techniques to generate maps of SOC stock (ordinary, isotopic and heterotopic cokriging). The study site is located in the Central region of Amazon State, Brazil. The soil survey covered the study site that has an area of 80 km 2 and resulted in a 1:10,000 soil map. It consisted of 315 field observations (96 complete soil profiles and 219 boreholes). SOC stock was calculated by summing C stocks by horizon, determined as a product of BD, SOC and the horizon thickness. For each one of the 315 soil observations, relief attributes were derived from a topographic map to understand SOC dynamics. The SOC stocks across 30 and 100 cm soil depth were 3.28 and 7.32 kg C m −2 , respectively, which is, 34 and 16%, lower than other studies. The SOC stock is higher in soils developed in relief forms exhibiting well-drained soils, which are covered by Upland Dense Tropical Rainforest. Only SOC stock in the upper 100 cm exhibited spatial dependence allowing the generation of spatial variability maps based on spatial (co)-regionalization. The CTI was inversely correlated with SOC stock and was the only auxiliary variable feasible to be used in cokriging interpolation. The heterotopic cokriging presented the best performance for mapping SOC stock. - Highlights: • The SOC stocks across 30 and 100 cm depth were 3.28 and 7.32 kg C m −2 , respectively. • SOC stocks were 34 and 16%, respectively

  11. Soil process-oriented modelling of within-field variability based on high-resolution 3D soil type distribution maps.

    Science.gov (United States)

    Bönecke, Eric; Lück, Erika; Gründling, Ralf; Rühlmann, Jörg; Franko, Uwe

    2016-04-01

    Today, the knowledge of within-field variability is essential for numerous purposes, including practical issues, such as precision and sustainable soil management. Therefore, process-oriented soil models have been applied for a considerable time to answer question of spatial soil nutrient and water dynamics, although, they can only be as consistent as their variation and resolution of soil input data. Traditional approaches, describe distribution of soil types, soil texture or other soil properties for greater soil units through generalised point information, e.g. from classical soil survey maps. Those simplifications are known to be afflicted with large uncertainties. Varying soil, crop or yield conditions are detected even within such homogenised soil units. However, recent advances of non-invasive soil survey and on-the-go monitoring techniques, made it possible to obtain vertical and horizontal dense information (3D) about various soil properties, particularly soil texture distribution which serves as an essential soil key variable affecting various other soil properties. Thus, in this study we based our simulations on detailed 3D soil type distribution (STD) maps (4x4 m) to adjacently built-up sufficient informative soil profiles including various soil physical and chemical properties. Our estimates of spatial STD are based on high-resolution lateral and vertical changes of electrical resistivity (ER), detected by a relatively new multi-sensor on-the-go ER monitoring device. We performed an algorithm including fuzzy-c-mean (FCM) logic and traditional soil classification to estimate STD from those inverted and layer-wise available ER data. STD is then used as key input parameter for our carbon, nitrogen and water transport model. We identified Pedological horizon depths and inferred hydrological soil variables (field capacity, permanent wilting point) from pedotransferfunctions (PTF) for each horizon. Furthermore, the spatial distribution of soil organic carbon

  12. Amplification and dampening of soil respiration by changes in temperature variability

    Directory of Open Access Journals (Sweden)

    C. A. Sierra

    2011-04-01

    Full Text Available Accelerated release of carbon from soils is one of the most important feedbacks related to anthropogenically induced climate change. Studies addressing the mechanisms for soil carbon release through organic matter decomposition have focused on the effect of changes in the average temperature, with little attention to changes in temperature variability. Anthropogenic activities are likely to modify both the average state and the variability of the climatic system; therefore, the effects of future warming on decomposition should not only focus on trends in the average temperature, but also variability expressed as a change of the probability distribution of temperature. Using analytical and numerical analyses we tested common relationships between temperature and respiration and found that the variability of temperature plays an important role determining respiration rates of soil organic matter. Changes in temperature variability, without changes in the average temperature, can affect the amount of carbon released through respiration over the long-term. Furthermore, simultaneous changes in the average and variance of temperature can either amplify or dampen the release of carbon through soil respiration as climate regimes change. These effects depend on the degree of convexity of the relationship between temperature and respiration and the magnitude of the change in temperature variance. A potential consequence of this effect of variability would be higher respiration in regions where both the mean and variance of temperature are expected to increase, such as in some low latitude regions; and lower amounts of respiration where the average temperature is expected to increase and the variance to decrease, such as in northern high latitudes.

  13. Amplification and dampening of soil respiration by changes in temperature variability

    Science.gov (United States)

    Sierra, C.A.; Harmon, M.E.; Thomann, E.; Perakis, S.S.; Loescher, H.W.

    2011-01-01

    Accelerated release of carbon from soils is one of the most important feed backs related to anthropogenically induced climate change. Studies addressing the mechanisms for soil carbon release through organic matter decomposition have focused on the effect of changes in the average temperature, with little attention to changes in temperature vari-ability. Anthropogenic activities are likely to modify both the average state and the variability of the climatic system; therefore, the effects of future warming on decomposition should not only focus on trends in the average temperature, but also variability expressed as a change of the probability distribution of temperature.Using analytical and numerical analyses we tested common relationships between temperature and respiration and found that the variability of temperature plays an important role determining respiration rates of soil organic matter. Changes in temperature variability, without changes in the average temperature, can affect the amount of carbon released through respiration over the long term. Furthermore, simultaneous changes in the average and variance of temperature can either amplify or dampen there release of carbon through soil respiration as climate regimes change. The effects depend on the degree of convexity of the relationship between temperature and respiration and the magnitude of the change in temperature variance. A potential consequence of this effect of variability would be higher respiration in regions where both the mean and variance of temperature are expected to increase, such as in some low latitude regions; and lower amounts of respiration where the average temperature is expected to increase and the variance to decrease, such as in northern high latitudes.

  14. Raw material variability as archaeological tools: Preliminary results from a geochemical study of the basalt vessel workshop at Iron Age Tel Hazor, Israel

    Directory of Open Access Journals (Sweden)

    Tatjana Gluhak

    2016-10-01

    Full Text Available The discovery of a basalt vessel workshop at Tel Hazor, one of the most important Iron Age sites in the Near East, marks a turning point in our understanding of stone artifact production and distribution during the1st millennium BCE. It offers a rare opportunity to characterize ancient raw material sources, production sites, and study production, trade and distribution systems. The basalt vessel workshop, the only one of its kind in the Levant, produced large quantities of bowl preforms and production waste. To better understand the production and distribution systems behind this specialized production center, in 2011 we initiated a focused geochemical project that concentrated on the products of this unique workshop.  We measured the major and trace element composition of 44 unfinished basalt vessels from the workshop and other contexts at Hazor, and can demonstrate that the majority of these objects were derived from one specific, geochemically well-constrained, basaltic rock source. Only a few bowls clearly deviate from this geochemical composition and were produced using raw material from other sources. Thus, we believe that one major quarry existed that supplied the Hazor workshop with the majority of the basaltic raw material. The products from this specific extraction site provide us with a “Hazor reference group” that can be used to test whether or not finished vessels from Hazor and contemporary sites were produced in the Hazor workshop.

  15. Latin Hypercube Sampling (LHS) at variable resolutions for enhanced watershed scale Soil Sampling and Digital Soil Mapping.

    Science.gov (United States)

    Hamalainen, Sampsa; Geng, Xiaoyuan; He, Juanxia

    2017-04-01

    Latin Hypercube Sampling (LHS) at variable resolutions for enhanced watershed scale Soil Sampling and Digital Soil Mapping. Sampsa Hamalainen, Xiaoyuan Geng, and Juanxia, He. AAFC - Agriculture and Agr-Food Canada, Ottawa, Canada. The Latin Hypercube Sampling (LHS) approach to assist with Digital Soil Mapping has been developed for some time now, however the purpose of this work was to complement LHS with use of multiple spatial resolutions of covariate datasets and variability in the range of sampling points produced. This allowed for specific sets of LHS points to be produced to fulfil the needs of various partners from multiple projects working in the Ontario and Prince Edward Island provinces of Canada. Secondary soil and environmental attributes are critical inputs that are required in the development of sampling points by LHS. These include a required Digital Elevation Model (DEM) and subsequent covariate datasets produced as a result of a Digital Terrain Analysis performed on the DEM. These additional covariates often include but are not limited to Topographic Wetness Index (TWI), Length-Slope (LS) Factor, and Slope which are continuous data. The range of specific points created in LHS included 50 - 200 depending on the size of the watershed and more importantly the number of soil types found within. The spatial resolution of covariates included within the work ranged from 5 - 30 m. The iterations within the LHS sampling were run at an optimal level so the LHS model provided a good spatial representation of the environmental attributes within the watershed. Also, additional covariates were included in the Latin Hypercube Sampling approach which is categorical in nature such as external Surficial Geology data. Some initial results of the work include using a 1000 iteration variable within the LHS model. 1000 iterations was consistently a reasonable value used to produce sampling points that provided a good spatial representation of the environmental

  16. Variability of soil fertility properties in areas planted to sugarcane in the State of Goias, Brazil

    Directory of Open Access Journals (Sweden)

    José Avelino Cardoso

    2014-04-01

    Full Text Available Soil sampling should provide an accurate representation of a given area so that recommendations for amendments of soil acidity, fertilization and soil conservation may be drafted to increase yield and improve the use of inputs. The aim of this study was to evaluate the variability of soil fertility properties of Oxisols in areas planted to sugarcane in the State of Goias, Brazil. Two areas of approximately 8,100 m² each were selected, representing two fields of the Goiasa sugarcane mill in Goiatuba. The sugarcane crop had a row spacing of 1.5 m and subsamples were taken from 49 points in the row and 49 between the row with a Dutch auger at depths of 0.0-0.2 and 0.2-0.4 m, for a total of 196 subsamples for each area. The samples were individually subjected to chemical analyses of soil fertility (pH in CaCl2, potential acidity, organic matter, P, K, Ca and Mg and particle size analysis. The number of subsamples required to compose a sample within the acceptable ranges of error of 5, 10, 20 and 40 % of each property were computed from the coefficients of variation and the Student t-value for 95 % confidence. The soil properties under analysis exhibited different variabilities: high (P and K, medium (potential acidity, Ca and Mg and low (pH, organic matter and clay content. Most of the properties analyzed showed an error of less than 20 % for a group of 20 subsamples, except for P and K, which were capable of showing an error greater than 40 % around the mean. The extreme variability in phosphorus, particularly at the depth of 0.2-0.4 m, attributed to banded application of high rates of P fertilizers at planting, places limitations on assessment of its availability due to the high number of subsamples required for a composite sample.

  17. Soil Carbon Variability and Change Detection in the Forest Inventory Analysis Database of the United States

    Science.gov (United States)

    Wu, A. M.; Nater, E. A.; Dalzell, B. J.; Perry, C. H.

    2014-12-01

    The USDA Forest Service's Forest Inventory Analysis (FIA) program is a national effort assessing current forest resources to ensure sustainable management practices, to assist planning activities, and to report critical status and trends. For example, estimates of carbon stocks and stock change in FIA are reported as the official United States submission to the United Nations Framework Convention on Climate Change. While the main effort in FIA has been focused on aboveground biomass, soil is a critical component of this system. FIA sampled forest soils in the early 2000s and has remeasurement now underway. However, soil sampling is repeated on a 10-year interval (or longer), and it is uncertain what magnitude of changes in soil organic carbon (SOC) may be detectable with the current sampling protocol. We aim to identify the sensitivity and variability of SOC in the FIA database, and to determine the amount of SOC change that can be detected with the current sampling scheme. For this analysis, we attempt to answer the following questions: 1) What is the sensitivity (power) of SOC data in the current FIA database? 2) How does the minimum detectable change in forest SOC respond to changes in sampling intervals and/or sample point density? Soil samples in the FIA database represent 0-10 cm and 10-20 cm depth increments with a 10-year sampling interval. We are investigating the variability of SOC and its change over time for composite soil data in each FIA region (Pacific Northwest, Interior West, Northern, and Southern). To guide future sampling efforts, we are employing statistical power analysis to examine the minimum detectable change in SOC storage. We are also investigating the sensitivity of SOC storage changes under various scenarios of sample size and/or sample frequency. This research will inform the design of future FIA soil sampling schemes and improve the information available to international policy makers, university and industry partners, and the public.

  18. CO and H2 uptake and emissions by soil: variability of fluxes and their isotopic signatures

    Science.gov (United States)

    Popa, Maria Elena; Chen, Qianjie; Ferrero Lopez, Noelia; Röckmann, Thomas

    2017-04-01

    In order to study the uptake and release of H2 and CO by soil, we performed long term, high frequency measurements with an automatic soil chamber at two sites in the Netherlands (Cabauw - grassland, and Speuld - forest). The measurements were performed over different seasons and cover in total a cumulated interval of about one year. These measurements allow determining separately, for each species, the two distinct fluxes i.e. uptake and release, and investigating their temporal variability and dependencies on environmental variables. Additional experiments were performed for determining the isotopic signatures of the H2 and CO uptake and release by soil. Flask samples were filled from the soil chamber, and then analyzed in the laboratory for the stable isotopic composition of H2 (δD) and CO (δ13C and δ18O). We find that both uptake and release are present at all times, regardless of the direction of the net flux. The emissions are significant for both species and at Cabauw, there are times and places where emissions outweigh the soil uptake. For each species, the two fluxes have different behavior and dependence on external variables, which indicates that they have different origins. The isotope results also support that, for both H2 and CO, uptake and emission occur simultaneously. We were able to determine separately the isotopic effects of the two fluxes. For both H2 and CO, soil uptake is associated with a small positive fractionation (the lighter molecule is taken up faster). The soil uptake fractionation (α = kheavy/klight) was 0.945 ± 0.004 for H2; for CO, the fractionation was 0.992 for 13C and 0.985 for 18O. The isotopic composition of the H2 emitted from the grassland was -530 ± 40 ‰, less depleted that what is expected from the isotopic equilibrium of H2 with water. For CO, the isotopic composition of the soil emission is depleted in 13C compared to atmospheric CO, and lower than the average isotopic composition of plant or soil organic matter.

  19. Agriculture at the Edge: Landscape Variability of Soil C Stocks and Fluxes in the Tropical Andes

    Science.gov (United States)

    Riveros-Iregui, D. A.; Peña, C.

    2015-12-01

    Paramos, or tropical alpine grasslands occurring right above the forest tree-line (2,800 - 4,700 m), are among the most transformed landscapes in the humid tropics. In the Tropical Andes, Paramos form an archipelago-like pattern from Northern Colombia to Central Peru that effectively captures atmospheric moisture originated in the Amazon-Orinoco basins, while marking the highest altitude capable of sustaining vegetation growth (i.e., 'the edge'). This study investigates the role of land management on mediating soil carbon stocks and fluxes in Paramo ecosystems of the Eastern Cordillera of Colombia. Observations were collected at a Paramo site strongly modified by land use change, including active potato plantations, pasture, tillage, and land abandonment. Results show that undisturbed Paramos soils have high total organic carbon (TOC), high soil water content (SWC), and low soil CO2 efflux (RS) rates. However, Paramo soils that experience human intervention show lower TOC, higher and more variable RS rates, and lower SWC. This study demonstrates that changes in land use in Paramos affect differentially the accumulation and exchange of soil carbon with the atmosphere and offers implications for management and protection strategies of what has been deemed the fastest evolving biodiversity ecosystem in the world.

  20. Variable pore connectivity model linking gas diffusivity and air-phase tortuosity to soil matric potential

    DEFF Research Database (Denmark)

    Chamindu, Deepagoda; Møldrup, Per; Schjønning, Per

    2012-01-01

    information on soil functional pore structure, e.g., pore network tortuosity and connectivity, can also be revealed from Dp/Do–ψ relations. Based on Dp/Do measurements in a wide range of soil types across geographically remote vadose zone profiles, this study analyzed pore connectivity for the development...... of a variable pore connectivity factor, X, as a function of soil matric potential, expressed as pF (=log |−ψ|), for pF values ranging from 1.0 to 3.5. The new model takes the form of X = X* (F/F*)A with F = 1 + pF−1, where X* is the pore network tortuosity at reference F (F*) and A is a model parameter......- and intraaggregate pore regions of aggregated soils. We further suggest that the new model with parameter values of X* = 1.7 and A = 0 may be used for upper limit Dp/Do predictions in risk assessments of, e.g., fluxes of toxic volatile organics from soil to indoor air at polluted soil sites....

  1. Spatial and temporal variability of soil moisture in a restored reach of an Alpine river

    Science.gov (United States)

    Luster, Jörg

    2010-05-01

    In order to assess the effects of river restoration on water quality, the biogeochemical functions of restored river reaches have to be quantified, and soil moisture is a key environmental variable controlling this functionality. Restored sections of rivers often are characterized by a dynamic mosaic of riparian zones with varying exposure to flooding. In this presentation, the spatial and temporal variability of soil moisture in riparian soils of a restored reach of the Alpine river Thur in northeastern Switzerland is shown. The study was part of the interdisciplinary project cluster RECORD, which was initiated to advance the mechanistic understanding of coupled hydrological and ecological processes in river corridors. The studied river reach comprised the following three functional processing zones (FPZ) representing a lateral successional gradient with decreasing hydrological connectivity (i.e. decreasing flooding frequency and duration). (i) The grass zone developed naturally on a gravel bar after restoration of the channelized river section (mainly colonized by canary reed grass Phalaris arundinacae). The soil is loamy sand to sandy loam composed of up to 80 cm thick fresh sediments trapped and stabilized by the grass roots. (ii) The bush zone is composed of young willow trees (Salix viminalis) planted during restoration to stabilize older overbank deposits with a loamy fine earth. (iii) The mixed forest is a mature riparian hardwood forest with ash and maple as dominant trees developed on older overbank sediments with a silty loamy fine earth. The study period was between spring 2009 and winter 2009/2010 including three flood events in June, July and December 2009. The first and third flood inundated the grass zone and lower part of the bush zone while the second flood was bigger and swept through all the FPZs. Water contents in several soil depths were measured continuously in 30 minute intervals using Decagon EC-5 and EC-TM sensors. There were six spatial

  2. Variability of soil CO2 efflux in a semi-arid grassland in Arizona

    Science.gov (United States)

    Krishnan, P.; Meyers, T. P.; Heuer, M.

    2017-12-01

    Soil surface CO2 efflux or soil respiration (RS) is one of the most important components of the global carbon cycle. So it is critical to evaluate the response of soil respiration to environmental conditions to predict how future climate and land cover changes influence the ecosystem carbon balance. Continuous half-hourly measurements of RS were made between the end of March to December 2015 in a semi-arid temperate grassland located on the Audubon Research Ranch in south western Arizona (31.5907N, 110.5104W, elevation 1496 m), USA. This first time measurements of Rs over this site using an automated soil chamber were used to investigate the seasonal and diurnal variation of Rs and its relationship to environmental variables. The mean annual air temperature and precipitation at this site were 16 deg C and 370 mm with more than 60% of the annual precipitation was received during the North American monsoon period (July-September). Following the onset of the monsoon, drastic changes in vegetation growth occured turning the ecosystem to a carbon sink by August. Temporal variability in Rs was closely related to the changes in near surface soil temperature at 2 cm (Ts) and soil water content at 5 cm (θ). Half -hourly Rs varied from nearly 0.1 μmol m-2 s-1 in the winter months to a maximum of 5 μmol m-2 s-1 in the peak growing season in August. During the dry pre-monsoon period (May -June), Rs was relatively low ( 0.0.08 m3 m-3, RS was positively correlated to soil temperature at the 2 cm depth following an exponential relationship. Below this value of θ, RS was largely decoupled from TS dropping to less than half of their maximum values during wet soil conditions. Analysis of daily mean nighttime Rs for the year showed that for periods with θ below the threshold, the sensitivity of RS to temperature were substantially reduced resulting in a Q10 significantly < 2, thereby confirming that RS was less affected by soil temperature under low soil water conditions at this

  3. Geochemical approach to evaluate deforest of mangroves

    OpenAIRE

    Ishiga, Hiroaki; Diallo, Ibrahima M'bemba; Bah Mamadou Lamine Malick,; Ngulimi. Faustine Miguta,; Magai. Paschal Justin,; Shati Samwel Stanley,

    2016-01-01

    Processes of mangrove deforest related human activities were examined. To evaluate changes of soil feature, multielements geochemical compositions of mangrove muds and soils of deforest were analyzed. To describe present situation of the mangrove, Conakry in Guinea, Dar es Salaam in Tanzania, Sundarbans of Bangladesh and Nago in Okinawa of Japan were selected. Soil samples of the forests were evaluated enrichment of biologically concentrated heavy metals such as Zn, Cu and Fe, and TS (total s...

  4. Geochemical and Pb isotopic characterization of soil, groundwater, human hair, and corn samples from the Domizio Flegreo and Agro Aversano area (Campania region, Italy)

    Science.gov (United States)

    Rezza, Carmela; Albanese, Stefano; Ayuso, Robert A.; Lima, Annamaria; Sorvari, Jaana; De Vivo, Benedetto

    2018-01-01

    A geochemical survey was carried out to investigate metal contamination in the Domizio Littoral and Agro Aversano area (Southern Italy) by means of soil, groundwater, human hair and corn samples. Pb isotope ratios were also determined to identify the sources of metals. Specifically, the investigation focused on topsoils (n = 1064), groundwater (n = 26), 25 human hair (n = 24) and corn samples (n = 13). Topsoils have been sampled and analysed in a previous study for 53 elements (including potentially harmful ones), and determined by ICP-MS after dissolving with aqua regia. Groundwater was analysed for 72 elements by ICP-MS and by ICP-ES. Samples of human hair were prepared and analysed for 16 elements by ICP-MS. Dried corn collected at several farms were also analysed for 53 elements by ICP-MS. The isotopic ratios of 206Pb/207Pb and 208Pb/207Pb in selected topsoil (n = 24), groundwater (n = 9), human hair (n = 9) and corn (n = 4) samples were analysed from both eluates and residues to investigate possible anthropogenic contamination and geogenic contributions. All data were processed and mapped by ArcGis software to produce interpolated maps and contamination factor maps of potentially harmful elements, in accordance with Italian Environmental Law (Legislative Decree 152/06). Results show that soil sampling sites are characterized by As, Cd, Co, Cr, Cu, Hg, Pb, Se, and Zn contents exceeding the action limits established for residential land use (RAL) and, in some cases, also the action limits for industrial land use (IAL) as established by Legislative Decree 152/06. A map of contamination factors and a map showing the degrees of contamination indicate that the areas in the municipalities of Acerra, Casoria and Giugliano have been affected by considerable anthropogenic-related pollution. To interpret the isotopic data and roughly estimate proportion of Pb from an anthropogenic source we broadly defined possible natural and anthropogenic Pb end

  5. Using Environmental Variables for Studying of the Quality of Sampling in Soil Mapping

    Directory of Open Access Journals (Sweden)

    A. Jafari

    2016-02-01

    profiles, which were then described, sampled, analyzed and classified according to the USDA soil classification system (16. The basic rationale is to set up a hypercube, the axes of which are the quantiles of rasters of environmental covariates, e.g., digital elevation model. Sampling evaluation was made using the HELS algorithm. This algorithm was written based on the study of Carre et al., 2007 (3 and run in R. Results and Discussion: The covariate dataset is represented by elevation, slope and wetness index (Table 2. All data layers were interpolated to a common grid of 30 m resolution. The size of the raster layer is 421 by 711 grid cells. Each of the three covariates is divided into four quantiles (Table 2. The hypercube character space has 43, i.e. 64 strata (Figure 5. The average number of grid cells within each stratum is therefore 4677 grid cells. The map of the covariate index (Figure 6 shows some patterns representative of the covariate variability. The values of the covariate index range between 0.0045 and 5.95. This means that some strata are very dense compared to others. This index allows us to explain if high or low relative weight of the sampling units (see below is due to soil sampling or covariate density. The strata with the highest density are in the areas with high geomorphology diversity. It means that geomorphology processes can cause the diversity and variability and it is in line with the geomorphology map (Figure 2. Of the 64 strata, 30.4% represent under-sampling, 60.2% represent adequate sampling and 9.4% represent over-sampling. Regarding the covariate index, most of the under-sampling appears in the high covariate index, where soil covariates are then highly variable. Actually, it is difficult to collect field samples in these highly variable areas (Figure 7. Also, most of the over-sampling was observed in areas with alow covariate index (Figure 7. We calculated the weights of all the sampling units and showed the results in Figure 8. One 64

  6. Trace metal pyritization variability in response to mangrove soil aerobic and anaerobic oxidation processes.

    Science.gov (United States)

    Machado, W; Borrelli, N L; Ferreira, T O; Marques, A G B; Osterrieth, M; Guizan, C

    2014-02-15

    The degree of iron pyritization (DOP) and degree of trace metal pyritization (DTMP) were evaluated in mangrove soil profiles from an estuarine area located in Rio de Janeiro (SE Brazil). The soil pH was negatively correlated with redox potential (Eh) and positively correlated with DOP and DTMP of some elements (Mn, Cu and Pb), suggesting that pyrite oxidation generated acidity and can affect the importance of pyrite as a trace metal-binding phase, mainly in response to spatial variability in tidal flooding. Besides these aerobic oxidation effects, results from a sequential extraction analyses of reactive phases evidenced that Mn oxidized phase consumption in reaction with pyrite can be also important to determine the pyritization of trace elements. Cumulative effects of these aerobic and anaerobic oxidation processes were evidenced as factors affecting the capacity of mangrove soils to act as a sink for trace metals through pyritization processes. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. Fine scale spatial variability of microbial pesticide degradation in soil: scales, controlling factors, and implications

    DEFF Research Database (Denmark)

    Dechesne, Arnaud; Badawi, N.; Aamand, Jens

    2014-01-01

    across pesticide classes: they include some soil characteristics (pH) and some agricultural management practices (pesticide application, tillage), while other potential controlling factors have more conflicting effects depending on the site or the pesticide. Evidence demonstrating the importance......Pesticide biodegradation is a soil microbial function of critical importance for modern agriculture and its environmental impact. While it was once assumed that this activity was homogeneously distributed at the field scale, mounting evidence indicates that this is rarely the case. Here, we...... critically examine the literature on spatial variability of pesticide biodegradation in agricultural soil. We discuss the motivations, methods, and main findings of the primary literature. We found significant diversity in the approaches used to describe and quantify spatial heterogeneity, which complicates...

  8. Analysis of the variability of some properties of a semi-deciduous forest soil

    International Nuclear Information System (INIS)

    Okae-Anti, D.; Ogoe, J.I.

    2003-05-01

    The formation of soils in any region is influenced by many factors such as the parent materials and the secondary materials derived from them, the vegetation and the history of land use. These factors vary from place to place and they contribute to the spatial variation in properties of the soil. Quantification of the magnitude, location and causes of spatial variability is an essential but insufficient ingredient of soil surveys. We took soil samples from the 0-20 cm depth covering soils in the Asuansi-Akroso-Nta-Ofin compound association (Lixisol, Cambisol and Fluvisol association) at the study site, following the nested balanced hierarchical sampling technique. This covered distances between 100 and 0.80 m. Standard laboratory analyses were performed to quantify the selected properties, namely, pH, organic carbon, total nitrogen, total phosphorus, exchangeable potassium and content of sand, silt and clay. Classical statistics and geostatistical procedures were performed on the data and models fitted to the variability patterns. Physical and the more stable properties such as sand, silt and clay were fitted with spherical variogram models. These models indicate a high level of spatial dependence and therefore such properties may be said to be fairly stable in the field. On the contrary, chemical properties such as exchangeable potassium, were fitted with exponential variogram models, indicating that these properties were less stable and showed dependence over longer distances. The scale of variation of the properties ranged between 35 m - 62 m. The degree of uncertainty associated with time and space can be reduced by improved documentation of field variability using the tools of geostatistics. (author)

  9. Comparing measured and modelled soil carbon: which site-specific variables are linked to high stability?

    Science.gov (United States)

    Robertson, Andy; Schipanski, Meagan; Ma, Liwang; Ahuja, Lajpat; McNamara, Niall; Smith, Pete; Davies, Christian

    2016-04-01

    Changes in soil carbon (C) stocks have been studied in depth over the last two decades, as net greenhouse gas (GHG) sinks are highlighted to be a partial solution to the causes of climate change. However, the stability of this soil C is often overlooked when measuring these changes. Ultimately a net sequestration in soils is far less beneficial if labile C is replacing more stable forms. To date there is no accepted framework for measuring soil C stability, and as a result there is considerable uncertainty associated with the simulated impacts of land management and land use change when using process-based systems models. However, a recent effort to equate measurable soil C fractions to model pools has generated data that help to assess the impacts of land management, and can ultimately help to reduce the uncertainty of model predictions. Our research compiles this existing fractionation data along with site metadata to create a simplistic statistical model able to quantify the relative importance of different site-specific conditions. Data was mined from 23 published studies and combined with original data to generate a dataset of 100+ land use change sites across Europe. For sites to be included they required soil C fractions isolated using the Zimmermann et al. (2007) method and specific site metadata (mean annual precipitation, MAP; mean annual temperature, MAT; soil pH; land use; altitude). Of the sites, 75% were used to develop a generalized linear mixed model (GLMM) to create coefficients where site parameters can be used to predict influence on the measured soil fraction C stocks. The remaining 25% of sites were used to evaluate uncertainty and validate this empirical model. Further, four of the aforementioned sites were used to simulate soil C dynamics using the RothC, DayCent and RZWQM2 models. A sensitivity analysis (4096 model runs for each variable applying Latin hypercube random sampling techniques) was then used to observe whether these models place

  10. Addressing Geographic Variability in the Comparative Toxicity Potential of Copper and Nickel in Soils

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Rosenbaum, Ralph K.; Huijbregts, Mark A. J.

    2013-01-01

    Comparative toxicity potentials (CTP), in life cycle impact assessment also known as characterization factors (CF), of copper (Cu) and nickel (Ni) were calculated for a global set of 760 soils. An accessibility factor (ACF) that takes into account the role of the reactive, solid-phase metal pool...... findings stress the importance of dealing with geographic variability in the calculation of CTPs for terrestrial ecotoxicity of metals....

  11. The effect of short-range spatial variability on soil sampling uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Perk, Marcel van der [Department of Physical Geography, Utrecht University, P.O. Box 80115, 3508 TC Utrecht (Netherlands)], E-mail: m.vanderperk@geo.uu.nl; De Zorzi, Paolo; Barbizzi, Sabrina; Belli, Maria [Agenzia per la Protezione dell' Ambiente e per i Servizi Tecnici (APAT), Servizio Laboratori, Misure ed Attivita di Campo, Via di Castel Romano, 100-00128 Roma (Italy); Fajgelj, Ales; Sansone, Umberto [International Atomic Energy Agency (IAEA), Agency' s Laboratories Seibersdorf, A-1400 Vienna (Austria); Jeran, Zvonka; Jacimovic, Radojko [Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)

    2008-11-15

    This paper aims to quantify the soil sampling uncertainty arising from the short-range spatial variability of elemental concentrations in the topsoils of agricultural, semi-natural, and contaminated environments. For the agricultural site, the relative standard sampling uncertainty ranges between 1% and 5.5%. For the semi-natural area, the sampling uncertainties are 2-4 times larger than in the agricultural area. The contaminated site exhibited significant short-range spatial variability in elemental composition, which resulted in sampling uncertainties of 20-30%.

  12. The effect of short-range spatial variability on soil sampling uncertainty.

    Science.gov (United States)

    Van der Perk, Marcel; de Zorzi, Paolo; Barbizzi, Sabrina; Belli, Maria; Fajgelj, Ales; Sansone, Umberto; Jeran, Zvonka; Jaćimović, Radojko

    2008-11-01

    This paper aims to quantify the soil sampling uncertainty arising from the short-range spatial variability of elemental concentrations in the topsoils of agricultural, semi-natural, and contaminated environments. For the agricultural site, the relative standard sampling uncertainty ranges between 1% and 5.5%. For the semi-natural area, the sampling uncertainties are 2-4 times larger than in the agricultural area. The contaminated site exhibited significant short-range spatial variability in elemental composition, which resulted in sampling uncertainties of 20-30%.

  13. Local Versus Remote Contributions of Soil Moisture to Near-Surface Temperature Variability

    Science.gov (United States)

    Koster, R.; Schubert, S.; Wang, H.; Chang, Y.

    2018-01-01

    Soil moisture variations have a straightforward impact on overlying air temperatures, wetter soils can induce higher evaporative cooling of the soil and thus, locally, cooler temperatures overall. Not known, however, is the degree to which soil moisture variations can affect remote air temperatures through their impact on the atmospheric circulation. In this talk we describe a two-pronged analysis that addresses this question. In the first segment, an extensive ensemble of NASA/GSFC GEOS-5 atmospheric model simulations is analyzed statistically to isolate and quantify the contributions of various soil moisture states, both local and remote, to the variability of air temperature at a given local site. In the second segment, the relevance of the derived statistical relationships is evaluated by applying them to observations-based data. Results from the second segment suggest that the GEOS-5-based relationships do, at least to first order, hold in nature and thus may provide some skill to forecasts of air temperature at subseasonal time scales, at least in certain regions.

  14. Dimensioning the Irrigation Variables for Table Grape Vineyards in Litho-soils

    Directory of Open Access Journals (Sweden)

    Pasquale Campi

    2010-10-01

    Full Text Available The pedo-climatic and farm characteristics of Bari’s hinterland have allowed for the diffusion of prestigious table viticulture. The typical “tendone” vineyard structure is set up after managing the surface of the soil. The karstic nature of the region and the thermo-rainfall trend during the vegetative season impede the vineyard from producing adequately without irrigation. Given the importance of water contributions to table grapes, it is necessary to correctly measure the water variables for economic and environmental reasons. Farmers often irrigate according to “fixed” turns and volumes, against the rules of “good irrigation practice” which consider monitoring the water status of the soil or plant as a prerequisite of irrigation scheduling. During this experiment, two methods of irrigation management were compared: “fixed-turn” and “on demand”. For “on demand” irrigation, the irrigation volume is calculated on the basis of the soil water status (estimated according to the “water balance” method described in the “Paper n. 56 FAO” and the irrigation is scheduled on the basis of the experimental relationship between “pre-dawn” leaf water potential and the water available in the soil. For this comparison, data from a 2-year “on farm” experimentation, in an area typical of table grape cultivation in Southern Italy, have been used. The results obtained show that, in respect to the “fixed-turn” management, the “on demand” management allows for a 20% reduction in water volumes, without compromising production. The water balance method proved to be a promising criterion for irrigation scheduling in these shallow soils, rich in stones (litho-soils. This only held true when the depth of the soil layer explored by the root system was defined by the “equivalent depth” and not by the actual soil’s depth.

  15. Modeling impacts of human footprint and soil variability on the potential distribution of invasive plant species in different biomes

    Science.gov (United States)

    Wan, Ji-Zhong; Wang, Chun-Jing; Yu, Fei-Hai

    2017-11-01

    Human footprint and soil variability may be important in shaping the spread of invasive plant species (IPS). However, until now, there is little knowledge on how human footprint and soil variability affect the potential distribution of IPS in different biomes. We used Maxent modeling to project the potential distribution of 29 IPS with wide distributions and long introduction histories in China based on various combinations of climatic correlates, soil characteristics and human footprint. Then, we evaluated the relative importance of each type of environmental variables (climate, soil and human footprint) as well as the difference in range and similarity of the potential distribution of IPS between different biomes. Human footprint and soil variables contributed to the prediction of the potential distribution of IPS, and different types of biomes had varying responses and degrees of impacts from the tested variables. Human footprint and soil variability had the highest tendency to increase the potential distribution of IPS in Montane Grasslands and Shrublands. We propose to integrate the assessment in impacts of human footprint and soil variability on the potential distribution of IPS in different biomes into the prevention and control of plant invasion.

  16. Variability in uptake of Cs isotopes by fenugreek plant from three soils

    Energy Technology Data Exchange (ETDEWEB)

    Pulhani, V; Dafauti, S; Dahiya, S; Hedge, A G [Environmental Studies Section, Health Physics Div., Bhabha Atomic Research Centre, Mumbai (India)

    2008-07-01

    Soil to plant transfer via root uptake is one of the major compartments in the radionuclide transfer pathways to man and can be used to assess the internal radiation dose via ingestion. The variability in the Transfer Factor (TF) of Cs isotopes was investigated in three different soils from nuclear power plant sites at Rajasthan and Narora with alkaline sandy loam alluvial and Madras with acidic coastal sandy loam alluvial soil. The soils were characterized for soil properties like texture, pH, EC, organic carbon, CaCO{sub 3} (%), CEC, silt, clay sand etc. and spiked with a mixture of 800 Bq {sup 137}Cs, 300 Bq {sup 134}Cs and 10mg of {sup 133}Cs (stable). Fenugreek (Trigonella foenum-graecum L.) from Leguminosae family an annual plant commonly used as a vegetable was grown in these soils to study the uptake of Cs. The uptake of heavy toxic elements like Pb, Cd, Ni, Cr etc. and nutrients Fe, Co, Cu, Zn, Mn, Ca, Mg, Na and K was also studied. The uptake of heavy toxic elements like Pb, Cd, Ni, Cr etc. and nutrients Fe, Co, Cu, Zn, Mn, Ca, Mg, Na and K was also studied. {sup 137}Cs and{sup 134}Cs was estimated using HPGe detector (15% Relative Efficiency, 54cc-coaxial, 2keV resolution at 1332keV of {sup 60}Co). Stable Cs, K and Na were determined by the Atomic Emission Spectrophotometry and Pb, Cd, Cr etc. by Atomic Absorption Spectrophotometry. Among the three soils the transfer factor for all the elements and Cs was highest for MAPS due to higher organic matter content and acidic pH followed by NAPS and RAPS. The {sup 137}Cs and {sup 134}Cs isotopes have been taken up to the same extent from soil and transfer factors are similar to each other. But the stable Cs uptake appears to be slightly high, probably because of excess of {sup 133}Cs (mg level) added as compared to the radioactive isotopes. In spite of this high difference in the soil concentrations of Cs isotopes, uptake of {sup 133}Cs is not very high indicating to a physiological limiting process for uptake

  17. ASSESSMENT SPATIAL VARIABILITY OF SOIL ERODIBILITY BY USING OF GEOSTATISTIC AND GIS (Case study MEHR watershed of SABZEVAR

    Directory of Open Access Journals (Sweden)

    Ayoubi, S.A

    2005-05-01

    Full Text Available Soil erodibility is one of the key factors on some sediment and soil erosion models such as USLE, MUSLE, RUSLE, AUSLE (USLE modified in LS factor and MMF and represents like K factor and is function of particle distribution, organic mater, soil structure and ermeability. Traditional methods do not take spatial variability and estimate precision of variables in to consideration and amount of them are constant across the whole of soil series .This study was performed to assess spatial variability of soil erodibility and its relevant variables at MEHR watershed from Khorasan province, in northern Iran. Interested network was designed by 110 samples like nested- systematic with distance about 50, 100, 250 and 500 meter across the study area by preparing point map at GIS. Sampling points were identified in field by an Global Positioning system. Soil sampling was done at depth of 0-5cm of ground surface and permeability was studied at depth of 5-30 cm. Some soil properties such as particle distribution and organic mater were measured at laboratory. Particle size distribution was determined by Hydrometer method and Organic matter was measured by wet oxidation approach. Then spatial analysis was done. Variography analysis on soil attributes according to soil erodibility, showed that Gaussian, exponential and spherical models were the most models to predict spatial variability of soil parameters. The range of spatial dependencies was changed from 320 to 3200 m. Soil attribute maps prepared by kriging technique using models parameters. Then soil attributes were composed by Wischmeier (1978 formula in Illwis media to calculate K factor. Amount of soil erodibility changed from 0.13 to 0.91 that it's maximum and minimum was identified in east and southwest of studiedarea. Soil spatial variability pattern, is similar to silt pattern due to high effect of silt on soil rodibility, Also that is partially confirmed with geology map, indicated which soil

  18. Alaskan soil carbon stocks: spatial variability and dependence on environmental factors

    Directory of Open Access Journals (Sweden)

    U. Mishra

    2012-09-01

    Full Text Available The direction and magnitude of soil organic carbon (SOC changes in response to climate change depend on the spatial and vertical distributions of SOC. We estimated spatially resolved SOC stocks from surface to C horizon, distinguishing active-layer and permafrost-layer stocks, based on geospatial analysis of 472 soil profiles and spatially referenced environmental variables for Alaska. Total Alaska state-wide SOC stock was estimated to be 77 Pg, with 61% in the active-layer, 27% in permafrost, and 12% in non-permafrost soils. Prediction accuracy was highest for the active-layer as demonstrated by highest ratio of performance to deviation (1.5. Large spatial variability was predicted, with whole-profile, active-layer, and permafrost-layer stocks ranging from 1–296 kg C m−2, 2–166 kg m−2, and 0–232 kg m−2, respectively. Temperature and soil wetness were found to be primary controllers of whole-profile, active-layer, and permafrost-layer SOC stocks. Secondary controllers, in order of importance, were found to be land cover type, topographic attributes, and bedrock geology. The observed importance of soil wetness rather than precipitation on SOC stocks implies that the poor representation of high-latitude soil wetness in Earth system models may lead to large uncertainty in predicted SOC stocks under future climate change scenarios. Under strict caveats described in the text and assuming temperature changes from the A1B Intergovernmental Panel on Climate Change emissions scenario, our geospatial model indicates that the equilibrium average 2100 Alaska active-layer depth could deepen by 11 cm, resulting in a thawing of 13 Pg C currently in permafrost. The equilibrium SOC loss associated with this warming would be highest under continuous permafrost (31%, followed by discontinuous (28%, isolated (24.3%, and sporadic (23.6% permafrost areas. Our high-resolution mapping of soil carbon stock reveals the

  19. Fine scale spatial variability of microbial pesticide degradation in soil: scales, controlling factors, and implications

    Directory of Open Access Journals (Sweden)

    Arnaud eDechesne

    2014-12-01

    Full Text Available Pesticide biodegradation is a soil microbial function of critical importance for modern agriculture and its environmental impact. While it was once assumed that this activity was homogeneously distributed at the field scale, mounting evidence indicates that this is rarely the case. Here, we critically examine the literature on spatial variability of pesticide biodegradation in agricultural soil. We discuss the motivations, methods, and main findings of the primary literature. We found significant diversity in the approaches used to describe and quantify spatial heterogeneity, which complicates inter-studies comparisons. However, it is clear that the presence and activity of pesticide degraders is often highly spatially variable with coefficients of variation often exceeding 50% and frequently displays nonrandom spatial patterns. A few controlling factors have tentatively been identified across pesticide classes: they include some soil characteristics (pH and some agricultural management practices (pesticide application, tillage, while other potential controlling factors have more conflicting effects depending on the site or the pesticide. Evidence demonstrating the importance of spatial heterogeneity on the fate of pesticides in soil has been difficult to obtain but modelling and experimental systems that do not include soil’s full complexity reveal that this heterogeneity must be considered to improve prediction of pesticide biodegradation rates or of leaching risks. Overall, studying the spatial heterogeneity of pesticide biodegradation is a relatively new field at the interface of agronomy, microbial ecology, and geosciences and a wealth of novel data is being collected from these different disciplinary perspectives. We make suggestions on possible avenues to take full advantage of these investigations for a better understanding and prediction of the fate of pesticides in soil.

  20. Evaluating Genetic Variability of Sorghum Mutant Lines Tolerant to Acid Soil

    International Nuclear Information System (INIS)

    Puspitasari, W.; Human, S.; Wirnas, D.; Trikoesoemaningtyas

    2012-01-01

    High rainfall in some parts in Indonesia causes soil become acidic. The main constraint of acid soil is phosphor (P) deficiency and aluminum (Al) toxicity which decrease plant productivity. To overcome this problem, it is important to develop a crop variety tolerant to such conditions. Sorghum is probably one of the potential crops to meet that objective. Sorghum has been reported to have wide adaptability to various agro-ecology and can be used as food and animal feed. Unfortunately, sorghum is not Indonesian origin so its genetic variability is still low. From previous breeding works with induced mutation, some promising mutant lines have been developed. These mutant lines were included in the experiment carried out in Tenjo with soil condition was classified as acid soil with pH 4.8 and exchangeable-Al content 2.43 me/100 g. The objectives of this experiment were to study the magnitude of genetic variability of agronomy and grain quality characters in sorghum in order to facilitate the breeding improvement of the species. Plant materials used in this study were ten genotypes, including 6 mutant lines and 4 control varieties. The randomized block design with three replications was used in the experiment. The genetic variabilities of agronomic and grain quality characters existed among genotypes, such as plant height, number of leaves, stalk diameter, biomass weight, panicle length, grain yield per plant, 100 seed weight and tannin content in the grain. The broad sense heritabilities of agronomic characters were estimated ranging from medium to high. Grain yield showed significantly positive correlation with agronomic characters observed, but it was negatively correlated with protein content (author)

  1. The contribution of hydroxylamine content to spatial variability of N2O formation in soil of a Norway spruce forest

    Science.gov (United States)

    Liu, Shurong; Herbst, Michael; Bol, Roland; Gottselig, Nina; Pütz, Thomas; Weymann, Daniel; Wiekenkamp, Inge; Vereecken, Harry; Brüggemann, Nicolas

    2016-04-01

    Hydroxylamine (NH2OH), a reactive intermediate of several microbial nitrogen turnover processes, is a potential precursor of nitrous oxide (N2O) formation in the soil. However, the contribution of soil NH2OH to soil N2O emission rates in natural ecosystems is unclear. Here, we determined the spatial variability of NH2OH content and potential N2O emission rates of organic (Oh) and mineral (Ah) soil layers of a Norway spruce forest, using a recently developed analytical method for the determination of soil NH2OH content, combined with a geostatistical Kriging approach. Potential soil N2O emission rates were determined by laboratory incubations under oxic conditions, followed by gas chromatographic analysis and complemented by ancillary measurements of soil characteristics. Stepwise multiple regressions demonstrated that the potential N2O emission rates, NH2OH and nitrate (NO3-) content were spatially highly correlated, with hotspots for all three parameters observed in the headwater of a small creek flowing through the sampling area. In contrast, soil ammonium (NH4+) was only weakly correlated with potential N2O emission rates, and was excluded from the multiple regression models. While soil NH2OH content explained the potential soil N2O emission rates best for both layers, also NO3- and Mn content turned out to be significant parameters explaining N2O formation in both soil layers. The Kriging approach was improved markedly by the addition of the co-variable information of soil NH2OH and NO3- content. The results indicate that determination of soil NH2OH content could provide crucial information for the prediction of the spatial variability of soil N2O emissions.

  2. Assessing soil hydrological variability at the cm- to dm-scale using air permeameter measurements

    Science.gov (United States)

    Beerten, K.; Vandersmissen, N.; Rogiers, B.; Mallants, D.

    2012-04-01

    Soils and surficial sediments are crucial elements in the hydrological cycle since they are the medium through which infiltrating precipitation percolates to the aquifer. At the same time, soil horizons and shallow stratigraphy may act as hydraulic barriers that can promote runoff or interflow and hamper deep infiltration. For most catchments little is known about the small-scale horizontal and vertical variability of soil hydrological properties. Such information is however required to calculate detailed soil water flow paths and estimate small scale spatial variability in recharge and run-off. We present the results from field air permeameter measurements to assess the small-scale variability of saturated hydraulic conductivity in heterogeneous 2-D soil profiles. To this end, several outcrops in the unsaturated zone (sandy soils with podzolisation) of an interfluve in the Kleine Nete river catchment (Campine area, Northern Belgium) were investigated using a hand-held permeameter. Measurements were done each 10 cm on ~ 2 x 1 m or ~ 2 x 0.5 m grids. The initial results of the measurements (air permeability Kair; millidarcy) are recalculated to saturated hydraulic conductivity (Ks; m/s) using specific transfer functions (Loll et al., 1999; Iversen et al., 2003). Validation of the results is done with independent lab-based constant head Ks measurements. The results show that field based Ks values generally range between 10-3 m/s and 10-7 m/s within one profile, but extremely high values (up to 10-1 m/s) have been measured as well. The lowest values are found in the organic- and silt-rich Bh horizon of podzol soils observed within the profiles (~ 10-6-10-7m/s), while the highest values are observed in overlying dune sands less than 40 cm deep (up to 10-3 m/s with outliers to 10-1 m/s). Comparison of field and laboratory based Ks data reveals there is fair agreement between both methods, apart from several outliers. Scatter plots indicate that almost all points

  3. The impact of soil moisture extremes and their spatiotemporal variability on Zambian maize yields

    Science.gov (United States)

    Zhao, Y.; Estes, L. D.; Vergopolan, N.

    2017-12-01

    Food security in sub-Saharan Africa is highly sensitive to climate variability. While it is well understood that extreme heat has substantial negative impacts on crop yield, the impacts of precipitation extremes, particularly over large spatial extents, are harder to quantify. There are three primary reasons for this difficulty, which are (1) lack of high quality, high resolution precipitation data, (2) rainfall data provide incomplete information on plant water availability, the variable that most directly affects crop performance, and (3) the type of rainfall extreme that most affects crop yields varies throughout the crop development stage. With respect to the first reason, the spatial and temporal variation of precipitation is much greater than that of temperature, yet the spatial resolution of rainfall data is typically even coarser than it is for temperature, particularly within Africa. Even if there were high-resolution rainfall data, the amount of water available to crops also depends on other physical factors that affect evapotranspiration, which are strongly influenced by heterogeneity in the land surface related to topography, soil properties, and land cover. In this context, soil moisture provides a better measure of crop water availability than rainfall. Furthermore, soil moisture has significantly different influences on crop yield depending on the crop's growth stage. The goal of this study is to understand how the spatiotemporal scales of soil moisture extremes interact with crops, more specifically, the timing and the spatial scales of extreme events like droughts and flooding. In this study, we simulate daily-1km soil moisture using HydroBlocks - a physically based land surface model - and compare it with precipitation and remote sensing derived maize yields between 2000 and 2016 in Zambia. We use a novel combination of the SCYM (scalable satellite-based yield mapper) method with DSSAT crop model, which is a mechanistic model responsive to water

  4. Mercury in urban soils: A comparison of local spatial variability in six European cities

    International Nuclear Information System (INIS)

    Rodrigues, S.; Pereira, M.E.; Duarte, A.C.; Ajmone-Marsan, F.; Davidson, C.M.; Grcman, H.; Hossack, I.; Hursthouse, A.S.; Ljung, K.; Martini, C.; Otabbong, E.; Reinoso, R.; Ruiz-Cortes, E.; Urquhart, G.J.; Vrscaj, B.

    2006-01-01

    The objective of this study was to quantify and assess for the first time the variability of total mercury in urban soils at a European level, using a systematic sampling strategy and a common methodology. We report results from a comparison between soil samples from Aveiro (Portugal), Glasgow (Scotland), Ljubljana (Slovenia), Sevilla (Spain), Torino (Italy) and Uppsala (Sweden). At least 25 sampling points (in about 4-5 ha) from a park in each city were sampled at two depths (0-10 and 10-20 cm). Total mercury was determined by pyrolysis atomic absorption spectrometry with gold amalgamation. The quality of results was monitored using certified reference materials (BCR 142R and BCR 141R). Measured total mercury contents varied from 0.015 to 6.3 mg kg -1 . The lowest median values were found in Aveiro, for both surface (0-10 cm) and sub-surface (10-20 cm) samples (0.055 and 0.054 mg kg -1 , respectively). The highest median mercury contents in soil samples were found in samples from Glasgow (1.2 and 1.3 mg kg -1 , for surface and sub-surface samples, respectively). High variability of mercury concentrations was observed, both within each park and between cities. This variability reflecting contributions from natural background, previous anthropogenic activities and differences in the ages of cities and land use, local environmental conditions as well as the influence of their location within the urban area. Short-range variability of mercury concentrations was found to be up to an order of magnitude over the distance of only a few 10 m

  5. Geochemical and biotic factors influencing the diversity and distribution of soil microfauna across ice-free coastal habitats in Victoria Land, Antarctica

    Czech Academy of Sciences Publication Activity Database

    Smykla, J.; Porazinska, D. L.; Iakovenko, Nataliia; Devetter, Miloslav; Drewnik, M.; Siang Hii, Y.; Emslie, S.D.

    2018-01-01

    Roč. 116, č. 1 (2018), s. 265-276 ISSN 0038-0717 Institutional support: RVO:67985904 ; RVO:60077344 Keywords : habitat suitability * soil biodiversity * Nematodes Subject RIV: DF - Soil Science OBOR OECD: Soil science Impact factor: 4.857, year: 2016

  6. Behaviour of nature and technogenic radioisotopes in buried geochemical barriers

    International Nuclear Information System (INIS)

    Kuznetsov, V.A.; Onoshko, M.P.; Generalova, V.A.

    1998-01-01

    Behaviour of potassium 40, radium 226, thorium 232, strontium 90 and cesium 137 on geochemical barriers connected with buried soils and cut-off meander sediments of the Holocene age of the Sozh river valley are examined. Some sides of the barrier geochemical structure caused by syngeneic and epigenetic processes have been taken into consideration

  7. Landscape structure control on soil CO2 efflux variability in complex terrain: Scaling from point observations to watershed scale fluxes

    Science.gov (United States)

    Diego A. Riveros-Iregui; Brian L. McGlynn

    2009-01-01

    We investigated the spatial and temporal variability of soil CO2 efflux across 62 sites of a 393-ha complex watershed of the northern Rocky Mountains. Growing season (83 day) cumulative soil CO2 efflux varied from ~300 to ~2000 g CO2 m-2, depending upon landscape position, with a median of 879.8 g CO2 m-2. Our findings revealed that highest soil CO2 efflux rates were...

  8. Spatial variability of soil magnetic susceptibility in an agricultural field located in Eastern Ukraine

    Science.gov (United States)

    Menshov, Oleksandr; Pereira, Paulo; Kruglov, Oleksandr

    2015-04-01

    Magnetic susceptibility (MS) have been used to characterize soil properties. It gives an indirect information about heavy metals content and degree of human impacts on soil contamination derived from atmospheric pollution (Girault et al., 2011). This method is inexpensive in relation to chemical analysis and very useful to track soil pollution, since several toxic components deposited on soil surface are rich in particulates produced by oxidation processes (Boyko et al., 2004; Morton-Bernea et al., 2009). Thus, identify the spatial distribution of MS is of major importance, since can give an indirect information of high metals content (Dankoub et al., 2012). This allows also to distinguish the pedogenic and technogenic origin magnetic signal. For example Ukraine chernozems contain fine-grained oxidized magnetite and maghemite of pedogenic origin formed by weathering of the parent material (Jeleńska et al., 2004). However, to a correct understanding of variables distribution, the identification of the most accurate interpolation method is fundamental for a better interpretation of map information (Pereira et al., 2013). The objective of this work is to study the spatial variability of soil MS in an agricultural fields located in the Tcherkascy Tishki area (50.11°N, 36.43 °E, 162 m a.s.l), Ukraine. Soil MS was measured in 77 sampling points in a north facing slope. To estimate the best interpolation method, several interpolation methods were tested, as inverse distance to a weight (IDW) with the power of 1,2,3,4 and 5, Local Polynomial (LP) with the power of 1 and 2, Global Polynomial (GP), radial basis functions - spline with tension (SPT), completely regularized spline (CRS), multiquatratic (MTQ), inverse multiquatratic (IMTQ), and thin plate spline (TPS) - and some geostatistical methods as, ordinary kriging (OK), Simple Kriging (SK) and Universal Kriging (UK), used in previous works (Pereira et al., 2014). On average, the soil MS of the studied plot had 686

  9. Soil Temperature Variability in Complex Terrain measured using Distributed a Fiber-Optic Distributed Temperature Sensing

    Science.gov (United States)

    Seyfried, M. S.; Link, T. E.

    2013-12-01

    Soil temperature (Ts) exerts critical environmental controls on hydrologic and biogeochemical processes. Rates of carbon cycling, mineral weathering, infiltration and snow melt are all influenced by Ts. Although broadly reflective of the climate, Ts is sensitive to local variations in cover (vegetative, litter, snow), topography (slope, aspect, position), and soil properties (texture, water content), resulting in a spatially and temporally complex distribution of Ts across the landscape. Understanding and quantifying the processes controlled by Ts requires an understanding of that distribution. Relatively few spatially distributed field Ts data exist, partly because traditional Ts data are point measurements. A relatively new technology, fiber optic distributed temperature system (FO-DTS), has the potential to provide such data but has not been rigorously evaluated in the context of remote, long term field research. We installed FO-DTS in a small experimental watershed in the Reynolds Creek Experimental Watershed (RCEW) in the Owyhee Mountains of SW Idaho. The watershed is characterized by complex terrain and a seasonal snow cover. Our objectives are to: (i) evaluate the applicability of fiber optic DTS to remote field environments and (ii) to describe the spatial and temporal variability of soil temperature in complex terrain influenced by a variable snow cover. We installed fiber optic cable at a depth of 10 cm in contrasting snow accumulation and topographic environments and monitored temperature along 750 m with DTS. We found that the DTS can provide accurate Ts data (+/- .4°C) that resolves Ts changes of about 0.03°C at a spatial scale of 1 m with occasional calibration under conditions with an ambient temperature range of 50°C. We note that there are site-specific limitations related cable installation and destruction by local fauna. The FO-DTS provide unique insight into the spatial and temporal variability of Ts in a landscape. We found strong seasonal

  10. Soil salinity and acidity : spatial variabil[it]y and effects on rice production in West Africa's mangrove zone

    NARCIS (Netherlands)

    Sylla, M.

    1994-01-01

    In the mangrove environment of West Africa, high spatial and temporal variability of soil constraints (salinity and acidity) to rice production is a problem for the transfer and adoption of new agronomic techniques, for land use planning, and for soil and water management. Recently, several

  11. Influence of Surface Roughness Spatial Variability and Temporal Dynamics on the Retrieval of Soil Moisture from SAR Observations

    Directory of Open Access Journals (Sweden)

    Jesús Álvarez-Mozos

    2009-01-01

    Full Text Available Radar-based surface soil moisture retrieval has been subject of intense research during the last decades. However, several difficulties hamper the operational estimation of soil moisture based on currently available spaceborne sensors. The main difficulty experienced so far results from the strong influence of other surface characteristics, mainly roughness, on the backscattering coefficient, which hinders the soil moisture inversion. This is especially true for single configuration observations where the solution to the surface backscattering problem is ill-posed. Over agricultural areas cultivated with winter cereal crops, roughness can be assumed to remain constant along the growing cycle allowing the use of simplified approaches that facilitate the estimation of the moisture content of soils. However, the field scale spatial variability and temporal variations of roughness can introduce errors in the estimation of soil moisture that are difficult to evaluate. The objective of this study is to assess the impact of roughness spatial variability and roughness temporal variations on the retrieval of soil moisture from radar observations. A series of laser profilometer measurements were performed over several fields in an experimental watershed from September 2004 to March 2005. The influence of the observed roughness variability and its temporal variations on the retrieval of soil moisture is studied using simulations performed with the Integral Equation Model, considering different sensor configurations. Results show that both field scale roughness spatial variability and its temporal variations are aspects that need to be taken into account, since they can introduce large errors on the retrieved soil moisture values.

  12. Interannual variability of plant phenology in tussock tundra: modelling interactions of plant productivity, plant phenology, snowmelt and soil thaw

    NARCIS (Netherlands)

    Wijk, van M.T.; Williams, M.; Laundre, J.A.; Shaver, G.R.

    2003-01-01

    We present a linked model of plant productivity, plant phenology, snowmelt and soil thaw in order to estimate interannual variability of arctic plant phenology and its effects on plant productivity. The model is tested using 8 years of soil temperature data, and three years of bud break data of

  13. Assessing the Biophysical Impact and Financial Viability of Soil Management Technologies Under Variable Climate in Cabo Verde Drylands

    NARCIS (Netherlands)

    Baptista, Isaurinda; Irvine, Brian; Fleskens, Luuk; Geissen, Violette; Ritsema, Coen

    2016-01-01

    Field trials have demonstrated the potential of soil conservation technologies but have also shown significant spatial-temporal yield variability. This study considers the Pan-European Soil Erosion Risk Assessment - Desertification Mitigation Cost-Effectiveness modelling approach to capture a

  14. The effect of Cs-137 short-range spatial variability on soil after the Chernobyl disaster

    Science.gov (United States)

    Martynenko, Vladimir; Vakulovsky, Sergey; Linnik, Vitaly

    2014-05-01

    After the Chernobyl accident of 1986, large areas of Russia were contaminated by 137Cs. Post-depositional redistribution of 137Cs fallout across the land surface resulting from mechanical, physical, chemical, and biological processes operating in the soil system and the grain size selectivity associated with soil erosion and sediment transport processes. Therefore of uppermost importance are data on evaluating 137Cs variability at short distances, obtained at the early period after the accident. Measurements of 137Cs deposit at the territory of Russia exposed to radioactive contamination were mainly conducted with the help of air-gamma survey, and were verified by soil sampling on test plots with size 10x10 m with control soil sampling using "envelope" method of fivefold soil sampling (1 sampling at the centre and 4 along the edges of the plot under study). Presented here are evaluation data of 137Cs contamination, obtained in the Bryansk, Yaroslav and Rostov regions in 1991. Test plots were selected at the distance of 50-100 m away from a road on matted areas with undisturbed soil structure. Test routes of sampling were made perpendicularly to directions crossing basic traces of radioactive contamination. Sampling measurements were carried out at Canberra and Ortec gamma spectrometers. Each of the 5 samples of the "envelope" was measured separately, soil mixing was not applied. 137Cs value for the Bryansk Region varied from 2,6 kBq/m2 to 2294 kBq/m2, at the territories of the Yaroslav and Rostov regions 137Cs value varied from 0,44 kBq/m2 to 5,1 kBq/m2 and 0,56 kBq/m2 to 22,2 kBq/m2, respectively. Statistical analysis of 137Cs deposit at different plots is a solid argumentation in favour of nonuniform distribution in various landscapes and at a different distance from the Chernobyl NPP. Such nonuniformity of 137Cs soil contamination in the limits of 10 m of the plot is most likely to be related to initial aerosol contamination nonuniformity at the moment of

  15. A coupled approach for the three-dimensional simulation of pipe leakage in variably saturated soil

    Science.gov (United States)

    Peche, Aaron; Graf, Thomas; Fuchs, Lothar; Neuweiler, Insa

    2017-12-01

    In urban water pipe networks, pipe leakage may lead to subsurface contamination or to reduced waste water treatment efficiency. The quantification of pipe leakage is challenging due to inaccessibility and unknown hydraulic properties of the soil. A novel physically-based model for three-dimensional numerical simulation of pipe leakage in variably saturated soil is presented. We describe the newly implemented coupling between the pipe flow simulator HYSTEM-EXTRAN and the groundwater flow simulator OpenGeoSys and its validation. We further describe a novel upscaling of leakage using transfer functions derived from numerical simulations. This upscaling enables the simulation of numerous pipe defects with the benefit of reduced computation times. Finally, we investigate the response of leakage to different time-dependent pipe flow events and conclude that larger pipe flow volume and duration lead to larger leakage while the peak position in time has a small effect on leakage.

  16. Soil fertility dynamics in a semiarid basin: impact of scale level in weighing the effect of the landscape variables

    International Nuclear Information System (INIS)

    Ruiz-Navarro, A.; Barbera, G. G.; Albaladejo, J.

    2009-01-01

    Arid and semi-arid Mediterranean soils are particularly sensitive to degradation processes, and soil fertility could play important role in restoration/conservation practices. Our objective was to study the relationships between soil and landscape at different scales in order to understand the main drivers of soil fertility on a semiarid catchment. A stratified sampling plan was carried out to take soil and landscape representative variability. Multivariate statistic techniques were used to elucidate the relationship between both. The results showed that soil fertility are positively related with density of vegetation and topographical conditions favourable to soil moisture at small scale, while negatively with topographical factors that contributed erosion dynamic on ero debility lithologies at medium and large scale. (Author) 8 refs.

  17. Simulating maize yield and bomass with spatial variability of soil field capacity

    Science.gov (United States)

    Ma, Liwang; Ahuja, Lajpat; Trout, Thomas; Nolan, Bernard T.; Malone, Robert W.

    2015-01-01

    Spatial variability in field soil properties is a challenge for system modelers who use single representative values, such as means, for model inputs, rather than their distributions. In this study, the root zone water quality model (RZWQM2) was first calibrated for 4 yr of maize (Zea mays L.) data at six irrigation levels in northern Colorado and then used to study spatial variability of soil field capacity (FC) estimated in 96 plots on maize yield and biomass. The best results were obtained when the crop parameters were fitted along with FCs, with a root mean squared error (RMSE) of 354 kg ha–1 for yield and 1202 kg ha–1 for biomass. When running the model using each of the 96 sets of field-estimated FC values, instead of calibrating FCs, the average simulated yield and biomass from the 96 runs were close to measured values with a RMSE of 376 kg ha–1 for yield and 1504 kg ha–1 for biomass. When an average of the 96 FC values for each soil layer was used, simulated yield and biomass were also acceptable with a RMSE of 438 kg ha–1 for yield and 1627 kg ha–1 for biomass. Therefore, when there are large numbers of FC measurements, an average value might be sufficient for model inputs. However, when the ranges of FC measurements were known for each soil layer, a sampled distribution of FCs using the Latin hypercube sampling (LHS) might be used for model inputs.

  18. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1

    International Nuclear Information System (INIS)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2008-01-01

    Coupled modeling of subsurface multiphase fluid and heat flow, solute transport, and chemical reactions can be applied to many geologic systems and environmental problems, including geothermal systems, diagenetic and weathering processes, subsurface waste disposal, acid mine drainage remediation, contaminant transport, and groundwater quality. TOUGHREACT has been developed as a comprehensive non-isothermal multi-component reactive fluid flow and geochemical transport simulator to investigate these and other problems. A number of subsurface thermo-physical-chemical processes are considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. TOUGHREACT can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The code can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions are considered, such as aqueous complexation, gas dissolution/exsolution, and cation exchange. Mineral dissolution/precipitation can take place subject to either local equilibrium or kinetic controls, with coupling to changes in porosity and permeability and capillary pressure in unsaturated systems. Chemical components can also be treated by linear adsorption and radioactive decay. The first version of the non-isothermal reactive geochemical transport code TOUGHREACT was developed (Xu and Pruess, 1998) by introducing reactive geochemistry into the framework of the existing multi-phase fluid and heat flow code TOUGH2 (Pruess, 1991). TOUGHREACT was further enhanced with the addition of (1) treatment of mineral-water-gas reactive-transport under boiling conditions, (2) an improved HKF activity model for aqueous species, (3) gas species diffusion coefficients calculated as a function of pressure, temperature, and molecular properties, (4) mineral reactive surface area formulations for fractured

  19. TOUGHREACT User's Guide: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media, V1.2.1

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

    2008-09-29

    Coupled modeling of subsurface multiphase fluid and heat flow, solute transport, and chemical reactions can be applied to many geologic systems and environmental problems, including geothermal systems, diagenetic and weathering processes, subsurface waste disposal, acid mine drainage remediation, contaminant transport, and groundwater quality. TOUGHREACT has been developed as a comprehensive non-isothermal multi-component reactive fluid flow and geochemical transport simulator to investigate these and other problems. A number of subsurface thermo-physical-chemical processes are considered under various thermohydrological and geochemical conditions of pressure, temperature, water saturation, and ionic strength. TOUGHREACT can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The code can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions are considered, such as aqueous complexation, gas dissolution/exsolution, and cation exchange. Mineral dissolution/precipitation can take place subject to either local equilibrium or kinetic controls, with coupling to changes in porosity and permeability and capillary pressure in unsaturated systems. Chemical components can also be treated by linear adsorption and radioactive decay. The first version of the non-isothermal reactive geochemical transport code TOUGHREACT was developed (Xu and Pruess, 1998) by introducing reactive geochemistry into the framework of the existing multi-phase fluid and heat flow code TOUGH2 (Pruess, 1991). TOUGHREACT was further enhanced with the addition of (1) treatment of mineral-water-gas reactive-transport under boiling conditions, (2) an improved HKF activity model for aqueous species, (3) gas species diffusion coefficients calculated as a function of pressure, temperature, and molecular properties, (4) mineral reactive surface area formulations for fractured

  20. Geochemical Constraints for Mercury's PCA-Derived Geochemical Terranes

    Science.gov (United States)

    Stockstill-Cahill, K. R.; Peplowski, P. N.

    2018-05-01

    PCA-derived geochemical terranes provide a robust, analytical means of defining these terranes using strictly geochemical inputs. Using the end members derived in this way, we are able to assess the geochemical implications for Mercury.

  1. Regional geochemical maps of uranium in Northern Scotland. Environmental and economic considerations

    International Nuclear Information System (INIS)

    Plant, J.

    1978-01-01

    The Institute of Geological Studies geochemical mapping programme is outlined. The natural levels of uranium in rocks, soils and waters are discussed. Some practical details of geochemical mapping are given. Applications of geochemical maps of uranium in Scotland are considered: economic applications and medical geography and agriculture. A list of 38 references is appended. (U.K.)

  2. Spatial variability of isoproturon mineralizing activity within an agricultural field: geostatistical analysis of simple physicochemical and microbiological soil parameters.

    Science.gov (United States)

    El Sebai, T; Lagacherie, B; Soulas, G; Martin-Laurent, F

    2007-02-01

    We assessed the spatial variability of isoproturon mineralization in relation to that of physicochemical and biological parameters in fifty soil samples regularly collected along a sampling grid delimited across a 0.36 ha field plot (40 x 90 m). Only faint relationships were observed between isoproturon mineralization and the soil pH, microbial C biomass, and organic nitrogen. Considerable spatial variability was observed for six of the nine parameters tested (isoproturon mineralization rates, organic nitrogen, genetic structure of the microbial communities, soil pH, microbial biomass and equivalent humidity). The map of isoproturon mineralization rates distribution was similar to that of soil pH, microbial biomass, and organic nitrogen but different from those of structure of the microbial communities and equivalent humidity. Geostatistics revealed that the spatial heterogeneity in the rate of degradation of isoproturon corresponded to that of soil pH and microbial biomass.

  3. Decadal to millennial time scale climate variability in the Central Mediterranean during the Holocene: a reconstruction based on geochemical proxies from high resolution sedimentary records

    NARCIS (Netherlands)

    Goudeau, M.S.

    2014-01-01

    To assess potential anthropogenic contributions to future climate change it is necessary to understand natural climate variability. This can be achieved by studying climate variability during the Holocene, when similar basic climate boundary conditions persisted as today. During this period climate

  4. SPATIAL MODELLING FOR DESCRIBING SPATIAL VARIABILITY OF SOIL PHYSICAL PROPERTIES IN EASTERN CROATIA

    Directory of Open Access Journals (Sweden)

    Igor Bogunović

    2016-06-01

    Full Text Available The objectives of this study were to characterize the field-scale spatial variability and test several interpolation methods to identify the best spatial predictor of penetration resistance (PR, bulk density (BD and gravimetric water content (GWC in the silty loam soil in Eastern Croatia. The measurements were made on a 25 x 25-m grid which created 40 individual grid cells. Soil properties were measured at the center of the grid cell deep 0-10 cm and 10-20 cm. Results demonstrated that PR and GWC displayed strong spatial dependence at 0-10 cm BD, while there was moderate and weak spatial dependence of PR, BD and GWC at depth of 10-20 cm. Semi-variogram analysis suggests that future sampling intervals for investigated parameters can be increased to 35 m in order to reduce research costs. Additionally, interpolation models recorded similar root mean square values with high predictive accuracy. Results suggest that investigated properties do not have uniform interpolation method implying the need for spatial modelling in the evaluation of these soil properties in Eastern Croatia.

  5. Geochemical evidence for African dust and volcanic ash inputs to terra rossa soils on carbonate reef terraces, northern Jamaica, West Indies

    Science.gov (United States)

    Muhs, D.R.; Budahn, J.R.

    2009-01-01

    The origin of red or reddish-brown, clay-rich, "terra rossa" soils on limestone has been debated for decades. A traditional qualitative explanation for their formation has been the accumulation of insoluble residues as the limestone is progressively dissolved over time. However, this mode of formation often requires unrealistic or impossible amounts of carbonate dissolution. Therefore, where this mechanism is not viable and where local fluvial or colluvial inputs can be ruled out, an external source or sources must be involved in soil formation. On the north coast of the Caribbean island of Jamaica, we studied a sequence of terra rossa soils developed on emergent limestones thought to be of Quaternary age. The soils become progressively thicker, redder, more Fe- and Al-rich and Si-poor with elevation. Furthermore, although kaolinite is found in all the soils, the highest and oldest soils also contain boehmite. Major and trace element geochemistry shows that the host limestones and local igneous rocks are not likely source materials for the soils. Other trace elements, including the rare earth elements (REE), show that tephra from Central American volcanoes is not a likely source either. However, trace element geochemistry shows that airborne dust from Africa plus tephra from the Lesser Antilles island arc are possible source materials for the clay-rich soils. A third, as yet unidentified, source may also contribute to the soils. We hypothesize that older, more chemically mature Jamaican bauxites may have had a similar origin. The results add to the growing body of evidence of the importance of multiple parent materials, including far-traveled dust, to soil genesis.

  6. Geochemical exploration for uranium

    International Nuclear Information System (INIS)

    1988-01-01

    This Technical Report is designed mainly to introduce the methods and techniques of uranium geochemical exploration to exploration geologists who may not have had experience with geochemical exploration methods in their uranium programmes. The methods presented have been widely used in the uranium exploration industry for more than two decades. The intention has not been to produce an exhaustive, detailed manual, although detailed instructions are given for a field and laboratory data recording scheme and a satisfactory analytical method for the geochemical determination of uranium. Rather, the intention has been to introduce the concepts and methods of uranium exploration geochemistry in sufficient detail to guide the user in their effective use. Readers are advised to consult general references on geochemical exploration to increase their understanding of geochemical techniques for uranium

  7. Using Environmental Variables for Studying of the Quality of Sampling in Soil Mapping

    OpenAIRE

    A. Jafari; Norair Toomanian; R. Taghizadeh Mehrjerdi

    2016-01-01

    Introduction: Methods of soil survey are generally empirical and based on the mental development of the surveyor, correlating soil with underlying geology, landforms, vegetation and air-photo interpretation. Since there are no statistical criteria for traditional soil sampling; this may lead to bias in the areas being sampled. In digital soil mapping, soil samples may be used to elaborate quantitative relationships or models between soil attributes and soil covariates. Because the relationshi...

  8. Variability of Effective Micro-organisms (EM) in bokashi and soil and effects on soil-borne plant pathogens

    NARCIS (Netherlands)

    Shin, Keumchul; Diepen, van G.; Blok, W.; Bruggen, van A.H.C.

    2017-01-01

    The microbial inoculant ‘Effective Microorganisms’ (EM) has been used to promote soil fertility and plant growth in agriculture. We tested effects of commercial EM products on suppression of soil-borne diseases, microbial activity and bacterial composition in organically managed sandy soils. EM was

  9. Spatial Variability of Tree Transpiration Along a Soil Drainage Gradient of Boreal Black Spruce Forest

    Science.gov (United States)

    Angstmann, J. L.; Ewers, B. E.; Kwon, H.; Bond-Lamberty, B.; Amiro, B.; Gower, S. T.

    2008-12-01

    Boreal forests are an integral component in obtaining a predictive understanding of global climate change because they comprise 33% of the world's forests and store large amounts of carbon. Much of this carbon storage is a result of peat formation in cold, poorly-drained soils. Transpiration plays a crucial role in the interaction between carbon and water cycles due to stomatal control of these fluxes. The primary focus of this study is to quantify the spatial variability and drivers of tree transpiration in boreal forest stands across a well- to poorly-drained soil drainage gradient. Species composition of this region of boreal forest changes during succession in well-drained soils from being primarily dominated by Picea mariana with co-dominant Pinus banksiana and Populus tremuloides in younger stands to being dominated solely by Picea marianain older stands. Poorly-drained soils are dominated by Picea mariana and change little with succession. Previous work in well-drained stands showed that 1) tree transpiration changed substantially with stand age due to sapwood-to-leaf area ratio dynamics and 2) minimum leaf water potential (Ψ) was kept constant to prevent excessive cavitation. We hypothesized that 1) minimum Ψ would be constant, 2) transpiration would be proportional to the sapwood-to-leaf area ratio across a soil drainage gradient, and 3) spatial relationships between trees would vary depending on stomatal responses to vapor pressure deficit (D). We tested these hypotheses by measuring Ψ of 33 trees and sap flux from 204 trees utilizing cyclic sampling constructed to study spatial relationships. Measurements were conducted at a 42-year-old stand representing maximum tree diversity during succession. There were no significant differences between growing season averaged Ψ in well- (-0.35 and -1.37 for pre-dawn and mid-day respectively) and poorly- drained soil conditions (-0.38 and -1.41 for pre-dawn and mid-day respectively) for Picea mariana. Water use

  10. Spatial variability of soil carbon, pH, available phosphorous and potassium in organic farm located in Mediterranean Croatia

    Science.gov (United States)

    Bogunović, Igor; Pereira, Paulo; Šeput, Miranda

    2016-04-01

    Soil organic carbon (SOC), pH, available phosphorus (P), and potassium (K) are some of the most important factors to soil fertility. These soil parameters are highly variable in space and time, with implications to crop production. The aim of this work is study the spatial variability of SOC, pH, P and K in an organic farm located in river Rasa valley (Croatia). A regular grid (100 x 100 m) was designed and 182 samples were collected on Silty Clay Loam soil. P, K and SOC showed moderate heterogeneity with coefficient of variation (CV) of 21.6%, 32.8% and 51.9%, respectively. Soil pH record low spatial variability with CV of 1.5%. Soil pH, P and SOC did not follow normal distribution. Only after a Box-Cox transformation, data respected the normality requirements. Directional exponential models were the best fitted and used to describe spatial autocorrelation. Soil pH, P and SOC showed strong spatial dependence with nugget to sill ratio with 13.78%, 0.00% and 20.29%, respectively. Only K recorded moderate spatial dependence. Semivariogram ranges indicate that future sampling interval could be 150 - 200 m in order to reduce sampling costs. Fourteen different interpolation models for mapping soil properties were tested. The method with lowest Root Mean Square Error was the most appropriated to map the variable. The results showed that radial basis function models (Spline with Tension and Completely Regularized Spline) for P and K were the best predictors, while Thin Plate Spline and inverse distance weighting models were the least accurate. The best interpolator for pH and SOC was the local polynomial with the power of 1, while the least accurate were Thin Plate Spline. According to soil nutrient maps investigated area record very rich supply with K while P supply was insufficient on largest part of area. Soil pH maps showed mostly neutral reaction while individual parts of alkaline soil indicate the possibility of penetration of seawater and salt accumulation in the

  11. Spatial and temporal variability of grass cover in two olive grove catchments on contrasting soil types

    Science.gov (United States)

    Aguilera, Laura; Taguas, Encarnación V.; Gimeno, Enrique; Gómez, José A.

    2013-04-01

    Mediterranean climate conditions -characterized by the concentration of the precipitation in the seasons of autumn and spring, the low temperatures in winter and extremely warm and dry summers- determine that ground cover by adventitious (or cover crop) vegetation shows significant seasonal and annual variability. In addition, its spatial variability associates also, partially, to water availability among the landscape. This is especially relevant in olive orchards, an agricultural system under high erosion risk in the region where the establishment of herbaceous cover has proved to improve soil protection reducing erosion risk, as well as the improvement of soil properties (Gómez et al., 2009). All these benefits are based on small scale studies where full ground cover by the cover crop is relatively easy to obtain. However, few information is available about the actual ground cover achieved at farm scale, although preliminary observations suggests that this might be extremely variable (Gómez and Giráldez, 2009). This study presents the preliminary results evaluating the spatial and temporal evolution of ground cover by adventitious vegetation (the preferred option by farmers to achieve a cover crop) in two commercial olive farms during 2 hydrological years (2011-2012). The study was conducted in two farms located in the province of Cordoba, Southern Spain. Both were olive orchards grown under deficit irrigation systems and present a gauge station where rainfall, runoff and sediment loads have been measured from the year 2005. The soil management in "La Conchuela" farm was based in the use of herbicide in the line of olive trees to keep the bare soil all year round, and the application of selective herbicide in the lane between the olive trees to promote the grown of graminaceae grasses . In addition, the grass is mechanically killed in June. In the another farm, "Arroyo Blanco", the grass spontaneous cover is allowed until mid-spring in which is also

  12. The effects of spatial variability of the aggressiveness of soil on system reliability of corroding underground pipelines

    International Nuclear Information System (INIS)

    Sahraoui, Yacine; Chateauneuf, Alaa

    2016-01-01

    In this paper, a probabilistic methodology is presented for assessing the time-variant reliability of corroded underground pipelines subjected to space-variant soil aggressiveness. The Karhunen-Loève expansion is used to model the spatial variability of soil as a correlated stochastic field. The pipeline is considered as a series system for which the component and system failure probabilities are computed by Monte Carlo simulations. The probabilistic model provides a realistic time and space modelling of stochastic variations, leading to appropriate estimation of the lifetime distribution. The numerical analyses allow us to investigate the impact of various parameters on the reliability of underground pipelines, such as the soil aggressiveness, the pipe design variables, the soil correlation length and the pipeline length. The results show that neglecting the effect of spatial variability leads to pessimistic estimation of the residual lifetime and can lead to condemn prematurely the structure. - Highlights: • The role of soil heterogeneity in pipeline reliability assessment has been shown. • The impact of pipe length and soil correlation length has been examined. • The effect of the uncertainties related to design variables has been observed. • Pipe thickness design for homogeneous reliability has been proposed.

  13. Variability in soil-water retention properties and implications for physics-based simulation of landslide early warning criteria

    Science.gov (United States)

    Thomas, Matthew A.; Mirus, Benjamin B.; Collins, Brian D.; Lu, Ning; Godt, Jonathan W.

    2018-01-01

    Rainfall-induced shallow landsliding is a persistent hazard to human life and property. Despite the observed connection between infiltration through the unsaturated zone and shallow landslide initiation, there is considerable uncertainty in how estimates of unsaturated soil-water retention properties affect slope stability assessment. This source of uncertainty is critical to evaluating the utility of physics-based hydrologic modeling as a tool for landslide early warning. We employ a numerical model of variably saturated groundwater flow parameterized with an ensemble of texture-, laboratory-, and field-based estimates of soil-water retention properties for an extensively monitored landslide-prone site in the San Francisco Bay Area, CA, USA. Simulations of soil-water content, pore-water pressure, and the resultant factor of safety show considerable variability across and within these different parameter estimation techniques. In particular, we demonstrate that with the same permeability structure imposed across all simulations, the variability in soil-water retention properties strongly influences predictions of positive pore-water pressure coincident with widespread shallow landsliding. We also find that the ensemble of soil-water retention properties imposes an order-of-magnitude and nearly two-fold variability in seasonal and event-scale landslide susceptibility, respectively. Despite the reduced factor of safety uncertainty during wet conditions, parameters that control the dry end of the soil-water retention function markedly impact the ability of a hydrologic model to capture soil-water content dynamics observed in the field. These results suggest that variability in soil-water retention properties should be considered for objective physics-based simulation of landslide early warning criteria.

  14. Variability of standard artificial soils: Physico-chemical properties and phenanthrene desorption measured by means of supercritical fluid extraction

    International Nuclear Information System (INIS)

    Bielská, Lucie; Hovorková, Ivana; Komprdová, Klára; Hofman, Jakub

    2012-01-01

    The study is focused on artificial soil which is supposed to be a standardized “soil like” medium. We compared physico-chemical properties and extractability of Phenanthrene from 25 artificial soils prepared according to OECD standardized procedures at different laboratories. A substantial range of soil properties was found, also for parameters which should be standardized because they have an important influence on the bioavailability of pollutants (e.g. total organic carbon ranged from 1.4 to 6.1%). The extractability of Phe was measured by supercritical fluid extraction (SFE) at harsh and mild conditions. Highly variable Phe extractability from different soils (3–89%) was observed. The extractability was strongly related (R 2 = 0.87) to total organic carbon content, 0.1–2 mm particle size, and humic/fulvic acid ratio in the following multiple regression model: SFE (%) = 1.35 * sand (%) − 0.77 * TOC (%)2 + 0.27 * HA/FA. - Highlights: ► We compared properties and extractability of Phe from 25 different artificial soils. ► Substantial range of soil properties was found, also for important parameters. ► Phe extractability was measured by supercritical fluid extraction (SFE) at 2 modes. ► Phe extractability was highly variable from different soils (3–89%). ► Extractability was strongly related to TOC, 0.1–2 mm particles, and HA/FA. - Significant variability in physico-chemical properties exists between artificial soils prepared at different laboratories and affects behavior of contaminants in these soils.

  15. Spatial Variability of Soil-Water Storage in the Southern Sierra Critical Zone Observatory: Measurement and Prediction

    Science.gov (United States)

    Oroza, C.; Bales, R. C.; Zheng, Z.; Glaser, S. D.

    2017-12-01

    Predicting the spatial distribution of soil moisture in mountain environments is confounded by multiple factors, including complex topography, spatial variably of soil texture, sub-surface flow paths, and snow-soil interactions. While remote-sensing tools such as passive-microwave monitoring can measure spatial variability of soil moisture, they only capture near-surface soil layers. Large-scale sensor networks are increasingly providing soil-moisture measurements at high temporal resolution across a broader range of depths than are accessible from remote sensing. It may be possible to combine these in-situ measurements with high-resolution LIDAR topography and canopy cover to estimate the spatial distribution of soil moisture at high spatial resolution at multiple depths. We study the feasibility of this approach using six years (2009-2014) of daily volumetric water content measurements at 10-, 30-, and 60-cm depths from the Southern Sierra Critical Zone Observatory. A non-parametric, multivariate regression algorithm, Random Forest, was used to predict the spatial distribution of depth-integrated soil-water storage, based on the in-situ measurements and a combination of node attributes (topographic wetness, northness, elevation, soil texture, and location with respect to canopy cover). We observe predictable patterns of predictor accuracy and independent variable ranking during the six-year study period. Predictor accuracy is highest during the snow-cover and early recession periods but declines during the dry period. Soil texture has consistently high feature importance. Other landscape attributes exhibit seasonal trends: northness peaks during the wet-up period, and elevation and topographic-wetness index peak during the recession and dry period, respectively.

  16. Application of EDTA decontamination on soils affected by mining activities and impact of treatment on the geochemical partition of metal contaminants.

    Science.gov (United States)

    Xia, Wenbin; Gao, Hui; Wang, Xianhai; Zhou, Chunhua; Liu, Yunguo; Fan, Ting; Wang, Xin

    2009-05-30

    Two soil samples were collected at mining areas located in southern Hunan Province, China. EDTA extraction of Pb, Zn, Cu and Cd from these two tailing soils was studied using column leaching experiments. The redistributions of heavy metals (HMs) were determined using the modified BCR (Community Bureau of Reference) sequential extraction procedure, before and after EDTA extraction. The results indicated that EDTA was an effective extractant because of its strong chelating ability for various HMs. The proportions of Pb, Zn, Cu and Cd in the four fractions varied largely after EDTA extraction. The extraction efficiency of EDTA of the acid-extractable fraction (AEX) was significant in shallow soil column, while in deeper soil column, decrease of the extraction efficiency of reduced (RED), oxidizable (OX) and residual fractions (RES) was obtained, which was mainly due to the decrease of EDTA concentration.

  17. Regional Variability of Cd, Hg, Pb and C Concentrations in Different Horizons of Swedish Forest Soils

    International Nuclear Information System (INIS)

    Alriksson, A.

    2001-01-01

    Contents of cadmium (Cd), mercury (Hg), lead (Pb) and carbon(C) in the O, B and C horizons of podzolized forest soils in Sweden were surveyed. Concentrations and storage of Cd, Hg and Pb in the O and B horizons were high in southern Sweden and gradually decreased towards the north, though with considerable local variability. This pattern reflects the influence of anthropogenic emissions of these metals, as well as the effects of soil-forming processes. Parent till material, as represented by the C horizon concentration of the respective metal, accounted for little of the variation in metal concentration in the O horizon. For Cd and Pb, the correlations were not significant or slightly negative (R 2 = 0.12 and 0.09 respectively) depending on region, while for Hg the correlation was not significant or slightly positive (R 2 = 0.03 and 0.08). Furthermore, parent till material accounted for more of the variation in metal concentrations in the B horizons in the northern part of Sweden than in the middle and southernmost parts, where the concentration of total carbon had more influence. The correlation between the metal concentrations in the B and C horizon was strongest for Pb (R 2 = 0.63 and 0.36 in the two northernmost regions), lower for Cd (R 2 = 0.19 and 0.16) and not significant for Hg. For all soil horizons, total C concentration accounted for much of the variation in Hg concentration in particular (O-horizon R 2 = 0.15-0.69, B horizon R 2 = 0.36-0.50, C horizon R 2 = 0.23-0.50 and ns in one region). Ratios of metal concentrations between the B and C horizons were highest for Hg(maximum value of 30), indicating a relatively larger addition or retention of Hg compared to Cd and Pb (maximum value of 10)in the B horizon. This study indicate that factors other than parent material account for the large scale variation in O horizon concentrations of metals but patterns correspond well with those of atmospheric deposition of heavy metals and acidifying substances

  18. Variability of soil properties within large termite mounds in South Katanga, DRC - origins and applications.

    Science.gov (United States)

    Erens, Hans; Bazirake Mujinya, Basile; Boeckx, Pascal; Baert, Geert; Mees, Florias; Van Ranst, Eric

    2014-05-01

    The miombo woodlands of South Katanga (D.R. Congo) are characterized by a high spatial density of large conic termite mounds built by Macrotermes falciger (3 to 5 ha-1). With an average height of 5.05 m and diameter of 14.88 m, these are some of the largest biogenic structures in the world. The mound material is known to differ considerably from the surrounding Ferralsols. Specifically, mound material exhibits a finer texture, higher CEC and exchangeable basic cation content, lower organic matter content, and an accumulation of phosphorous, nitrate and secondary carbonates. However, as demonstrated by the present study, these soil properties are far from uniform within the volume of the mound. The termites' nesting and foraging activity, combined with pedogenic processes over extended periods of time, generates a wide range of physical, chemical, and biological conditions in different parts of the mound. Analysis of samples taken along a cross-section of a large active mound allowed generating contour plots, thus visualizing the variability of soil properties within the mound. The central columns of three other mounds were sampled to confirm apparent trends. The contour plots show that the mounds comprise four functional zones: (i) the active nest, found at the top; (ii) an accumulation zone , in more central parts of the mound; (iii) a dense inactive zone, surrounding the accumulation zone and consisting of accumulated erosion products from former active nests; and (iv) the outer mantle, characterized by intense varied biological activity and by a well-developed soil structure. Intermittent leaching plays a key role in explaining these patterns. Using radiocarbon dating, we found that some of these mounds are at least 2000 years old. Their current size and shape is likely the result of successive stages of erosion and rebuilding, in the course of alternating periods of mound abandonment and recolonization. Over time, termite foraging combined with limited leaching

  19. Geochemical processes during managed aquifer recharge with desalinated seawater

    Science.gov (United States)

    Ganot, Y.; Holtzman, R.; Weisbrod, N.; Russak, A.; Katz, Y.; Kurtzman, D.

    2017-12-01

    In this work we study the geochemical processes along the variably-saturated zone during managed aquifer recharge (MAR) with reverse-osmosis desalinated seawater (DSW) to an infiltration pond at the Menashe site, located above the Israeli coastal aquifer. The DSW is post-treated by calcite dissolution (remineralization) in order to meet the Israeli desalinated water quality criteria. Suction cups and monitoring wells inside the pond were used to monitor water quality during two MAR events on 2015 and 2016. Results show that cation exchange is dominant, driven by the high Ca2+ concentration in the post-treated DSW. Stable isotope analysis shows that the composition of the shallow groundwater is similar to the recharged DSW, but with enrichment of Mg2+, Na+, Ca2+ and HCO3-. A calibrated variably-saturated reactive transport model was used to predict the geochemical evolution during 50 years of MAR with two water quality scenarios: post-treated DSW and soft DSW (without post-treatment). The latter scenario was aimed to test soil-aquifer-treatment as an alternative post-treatment technique. In terms of water quality, the results of the two scenarios were found within the range of the desalinated water criteria. Mg2+ enrichment was stable ( 2.5 mg L-1), higher than the zero concentration found in the Israeli DSW. Calcite content reduction was low (<1%) along the variably-saturated profile, after 50 years of MAR. This suggests that using soil-aquifer-treatment as a remineralization technique for DSW is potentially a sustainable practice, which is limited only by the current hydraulic capacity of the Menashe MAR site.

  20. Use of geophysical survey as a predictor of the edaphic properties variability in soils used for livestock production

    Directory of Open Access Journals (Sweden)

    Nahuel R. Peralta

    2015-12-01

    Full Text Available The spatial variability in soils used for livestock production (i.e. Natraquoll and Natraqualf at farm and paddock scale is usually very high. Understanding this spatial variation within a field is the first step for site-specific crop management. For this reason, we evaluated whether apparent electrical conductivity (ECa, a widely used proximal soil sensing technology, is a potential estimator of the edaphic variability in these types of soils. ECa and elevation data were collected in a paddock of 16 ha. Elevation was negatively associated with ECa. Geo-referenced soil samples were collected and analyzed for soil organic matter (OM content, pH, the saturation extract electrical conductivity (ECext, available phosphorous (P, and anaerobically incubated Nitrogen (Nan. Relationships between soil properties and ECa were analyzed using regression analysis, principal components analysis (PCA, and stepwise regression. Principal components (PC and the PC-stepwise were used to determine which soil properties have an important influence on ECa. In this experiment elevation was negatively associated with ECa. The data showed that pH, OM, and ECext exhibited a high correlation with ECa (R2=0.76; 0.70 and 0.65, respectively. Whereas P and Nan showed a lower correlation (R2=0.54 and 0.11 respectively. The model resulting from the PC-stepwise regression analysis explained slightly more than 69% of the total variation of the measured ECa, only retaining PC1. Therefore, ECext, pH and OM were considered key latent variables because they substantially influence the relationship between the PC1 and the ECa (loading factors>0.4. Results showed that ECa is associated with the spatial distribution of some important soil properties. Thus, ECa can be used as a support tool to implement site-specific management in soils for livestock use.

  1. Use of geophysical survey as a predictor of the edaphic properties variability in soils used for livestock production

    Energy Technology Data Exchange (ETDEWEB)

    Peralta, N.R.; Cicore, P.L.; Marino, M.A.; Marques da Silva, J. R.; Costa, J.L.

    2015-07-01

    The spatial variability in soils used for livestock production (i.e. Natraquoll and Natraqualf) at farm and paddock scale is usually very high. Understanding this spatial variation within a field is the first step for site-specific crop management. For this reason, we evaluated whether apparent electrical conductivity (ECa), a widely used proximal soil sensing technology, is a potential estimator of the edaphic variability in these types of soils. ECa and elevation data were collected in a paddock of 16 ha. Elevation was negatively associated with ECa. Geo-referenced soil samples were collected and analyzed for soil organic matter (OM) content, pH, the saturation extract electrical conductivity (ECext), available phosphorous (P), and anaerobically incubated Nitrogen (Nan). Relationships between soil properties and ECa were analyzed using regression analysis, principal components analysis (PCA), and stepwise regression. Principal components (PC) and the PC-stepwise were used to determine which soil properties have an important influence on ECa. In this experiment elevation was negatively associated with ECa. The data showed that pH, OM, and ECext exhibited a high correlation with ECa (R2=0.76; 0.70 and 0.65, respectively). Whereas P and Nan showed a lower correlation (R2=0.54 and 0.11 respectively). The model resulting from the PC-stepwise regression analysis explained slightly more than 69% of the total variation of the measured ECa, only retaining PC1. Therefore, ECext, pH and OM were considered key latent variables because they substantially influence the relationship between the PC1 and the ECa (loading factors>0.4). Results showed that ECa is associated with the spatial distribution of some important soil properties. Thus, ECa can be used as a support tool to implement site-specific management in soils for livestock use. (Author)

  2. Extracting Archaeological Feautres from GPR Surveys Conducted with Variable Soil Moisture Conditions

    Science.gov (United States)

    Morris, I. M.; Glisic, B.; Gonciar, A.

    2017-12-01

    As a common tool for subsurface archaeological prospection, ground penetrating radar (GPR) is a useful method for increasing the efficiency of archaeological excavations. Archaeological sites are often temporally and financially constrained, therefore having limited ability to reschedule surveys compromised by weather. Furthermore, electromagnetic GPR surveys are especially sensitive to variations in water content, soil type, and site-specific interference. In this work, GPR scans of a partially excavated Roman villa consisting of different construction materials and phases (limestone, andesite, brick) in central Romania are compared. Surveys were conducted with a 500 MHz GPR antenna in both dry (pre-rain event) and wet (post-rain event) conditions. Especially in time or depth slices, wet surveys present additional archaeological features that are not present or clear in the standard dry conditions, while simultaneously masking the clutter present in those scans. When dry, the limestone has a similar dielectric constant to the soil and does not provide enough contrast in electromagnetic properties for strong reflections despite the significant difference in their physical properties. Following precipitation, however, the electromagnetic properties of these two materials is dominated by their respective water content and the contrast is enhanced. For this reason, the wet surveys are particularly necessary for revealing reflections from the limestone features often invisible in dry surveys. GPR surveys conducted in variable environmental conditions provide unique archaeological information, with potential near-surface geophysical applications in nondestructive material characterization and identification.

  3. Spatial variability of soil CO2 emission in a sugarcane area characterized by secondary information

    Directory of Open Access Journals (Sweden)

    Daniel De Bortoli Teixeira

    2013-06-01

    Full Text Available Soil CO2 emission (FCO2 is governed by the inherent properties of the soil, such as bulk density (BD. Mapping of FCO2 allows the evaluation and identification of areas with different accumulation potential of carbon. However, FCO2 mapping over larger areas is not feasible due to the period required for evaluation. This study aimed to assess the quality of FCO2 spatial estimates using values of BD as secondary information. FCO2 and BD were evaluated on a regular sampling grid of 60 m × 60 m comprising 141 points, which was established on a sugarcane area. Four scenarios were defined according to the proportion of the number of sampling points of FCO2 to those of BD. For these scenarios, 67 (F67, 87 (F87, 107 (F107 and 127 (F127 FCO2 sampling points were used in addition to 127 BD sampling points used as supplementary information. The use of additional information from the BD provided an increase in the accuracy of the estimates only in the F107, F67 and F87 scenarios, respectively. The F87 scenario, with the approximate ratio between the FCO2 and BD of 1.00:1.50, presented the best relative improvement in the quality of estimates, thereby indicating that the BD should be sampled at a density 1.5 time greater than that applied for the FCO2. This procedure avoided problems related to the high temporal variability associated with FCO2, which enabled the mapping of this variable to be elaborated in large areas.

  4. Spatio-temporal variability of soil respiration in a spruce-dominated headwater catchment in western Germany

    Science.gov (United States)

    Bossa, A. Y.; Diekkrüger, B.

    2014-08-01

    CO2 production and transport from forest floors is an important component of the carbon cycle and is closely related to the global atmosphere CO2 concentration. If we are to understand the feedback between soil processes and atmospheric CO2, we need to know more about the spatio-temporal variability of this soil respiration under different environmental conditions. In this study, long-term measurements were conducted in a spruce-dominated forest ecosystem in western Germany. Multivariate analysis-based similarities between different measurement sites led to the detection of site clusters along two CO2 emission axes: (1) mainly controlled by soil temperature and moisture condition, and (2) mainly controlled by root biomass and the forest floor litter. The combined effects of soil temperature and soil moisture were used as a time-dependent rating factor affecting the optimal CO2 production and transport at cluster level. High/moderate/weak time-dependent rating factors were associated with the different clusters. The process-based, most distant clusters were identified using specified pattern characteristics: the reaction rates in the soil layers, the activation energy for bio-chemical reactions, the soil moisture dependency parameter, the root biomass factor, the litter layer factor and the organic matter factor. A HYDRUS-1D model system was inversely used to compute soil hydraulic parameters from soil moisture measurements. Heat transport parameters were calibrated based on observed soil temperatures. The results were used to adjust CO2 productions by soil microorganisms and plant roots under optimal conditions for each cluster. Although the uncertainty associated with the HYDRUS-1D simulations is higher, the results were consistent with both the multivariate clustering and the time-dependent rating of site production. Finally, four clusters with significantly different environmental conditions (i.e. permanent high soil moisture condition, accumulated litter amount

  5. Reconnaissance Geochemical Study

    African Journals Online (AJOL)

    distribution patterns. The geochemical distribution maps of the elements reveal that Cu, Pb, Zn, Co, Sc, Ni, Cr, .... After filtration, the leached solutions were diluted with ultra ...... some other rare earth elements in the study area. The occurrence ...

  6. Measurements of the fallout flux of beryllium-7 and its variability in the soil

    Directory of Open Access Journals (Sweden)

    Avacir Casanova Andrello

    2010-02-01

    Full Text Available The aim of this study was to examine the beryllium-7 behavior in the soil. Natural variability of beryllium-7 concentration was calculated to be about 23% (relative standard deviation, and the depth distribution could be approximated by an exponential decay in bare soil, with an average penetration depth in the soil about 1 cm. The nuclide was not found below 2 cm depth, which confirmed its utilization to infer the erosion processes as a tracer of soil surface. The maximum beryllium-7 concentration in the analyzed period was about 40 Bq.kg-1.Berílio-7 é um radionuclídeo cosmogênico, com meia-vida de 53 dias, produzido pelo processo de espalação de átomos de oxigênio e nitrogênio dentro da troposfera e estratosfera. Após sua produção, este é transportado até a superfície terrestre pela deposição úmida e seca. A precipitação seca contribui somente com 3-8% do inventário total. Medidas de berílio-7 no solo podem serem usadas para indicar movimento de solo da camada superficial e este estudo objetiva examinar o comportamento de berílio-7 no solo. Variabilidade natural do inventário de berílio-7 é em torno de 23% (desvio padrão relativo. A distribuição em profundidade de berílio-7 pode ser aproximada por uma função exponencial no solo nu, com uma profundidade média de distribuição no solo em torno de 1 cm. O berílio-7 não foi encontrado abaixo da profundidade de 2 cm para o tipo de solo estudado, o que confirma sua utilização para avaliar processo de erosão superficial como um traçador de solo superficial. A concentração máxima de berílio-7 no período analisado é em torno de 40 Bq.kg-1.

  7. Pro-glacial soil variability and geomorphic activity - the case of three Swiss valleys

    NARCIS (Netherlands)

    Temme, A.J.A.M.; Lange, de K.

    2014-01-01

    Soils in pro-glacial areas are often approached from a chronosequence viewpoint. In the chronosequence approach, the objective is to derive rates of soil formation from differences in properties between soils of different age. For this reason, in chronosequence studies, soils are sampled in

  8. The response of archaeal species to seasonal variables in a subtropical aerated soil: insight into the low abundant methanogens.

    Science.gov (United States)

    Xie, Wei; Jiao, Na; Ma, Cenling; Fang, Sa; Phelps, Tommy J; Zhu, Ruixin; Zhang, Chuanlun

    2017-08-01

    Archaea are cosmopolitan in aerated soils around the world. While the dominance of Thaumarchaeota has been reported in most soils, the methanogens are recently found to be ubiquitous but with low abundances in the aerated soil globally. However, the seasonal changes of Archaea community in the aerated soils are still in the mist. In this study, we investigated the change of Archaea in the context of environmental variables over a period of 12 months in a subtropical soil on the Chongming Island, China. The results showed that Nitrososphaera spp. were the dominant archaeal population while the methanogens were in low proportions but highly diverse (including five genera: Methanobacterium, Methanocella, Methanosaeta, Methanosarcina, and Methanomassiliicoccus) in the aerated soil samples determined by high throughput sequencing. A total of 126 LSA correlations were found in the dataset including all the 72 archaeal OTUs and 8 environmental factors. A significance index defined as the pagerank score of each OTU divided by its relative abundance was used to evaluate the significance of each OTU. The results showed that five out of 17 methanogen OTUs were significantly positively correlated with temperature, suggesting those methanogens might increase with temperature rather than being dormant in the aerated soils. Given the metabolic response of methanogens to temperature under aerated soil conditions, their contribution to the global methane cycle warrants evaluation.

  9. Geospatial variability of soil CO2-C exchange in the main terrestrial ecosystems of Keller Peninsula, Maritime Antarctica.

    Science.gov (United States)

    Thomazini, A; Francelino, M R; Pereira, A B; Schünemann, A L; Mendonça, E S; Almeida, P H A; Schaefer, C E G R

    2016-08-15

    Soils and vegetation play an important role in the carbon exchange in Maritime Antarctica but little is known on the spatial variability of carbon processes in Antarctic terrestrial environments. The objective of the current study was to investigate (i) the soil development and (ii) spatial variability of ecosystem respiration (ER), net ecosystem CO2 exchange (NEE), gross primary production (GPP), soil temperature (ST) and soil moisture (SM) under four distinct vegetation types and a bare soil in Keller Peninsula, King George Island, Maritime Antarctica, as follows: site 1: moss-turf community; site 2: moss-carpet community; site 3: phanerogamic antarctic community; site 4: moss-carpet community (predominantly colonized by Sanionia uncinata); site 5: bare soil. Soils were sampled at different layers. A regular 40-point (5×8 m) grid, with a minimum separation distance of 1m, was installed at each site to quantify the spatial variability of carbon exchange, soil moisture and temperature. Vegetation characteristics showed closer relation with soil development across the studied sites. ER reached 2.26μmolCO2m(-2)s(-1) in site 3, where ST was higher (7.53°C). A greater sink effect was revealed in site 4 (net uptake of 1.54μmolCO2m(-2)s(-1)) associated with higher SM (0.32m(3)m(-3)). Spherical models were fitted to describe all experimental semivariograms. Results indicate that ST and SM are directly related to the spatial variability of CO2 exchange. Heterogeneous vegetation patches showed smaller range values. Overall, poorly drained terrestrial ecosystems act as CO2 sink. Conversely, where ER is more pronounced, they are associated with intense soil carbon mineralization. The formations of new ice-free areas, depending on the local soil drainage condition, have an important effect on CO2 exchange. With increasing ice/snow melting, and resulting widespread waterlogging, increasing CO2 sink in terrestrial ecosystems is expected for Maritime Antarctica. Copyright

  10. Spatial variability and response of soil organic carbon stocks to land abandonment and erosion in mountainous drylands (Invited)

    Science.gov (United States)

    De Baets, S. L.; Meersmans, J.; Vanacker, V.; Quine, T. A.; van oost, K.

    2013-12-01

    This research focuses on understanding the impact of human activities on C dynamics in a mountainous and semi-arid environment. Despite the low C status of drylands, soil organic carbon (SOC) is the largest C pool in these systems and hence possess a large restoration capacity. Still, regional estimates of SOC stocks and insights in their determining factors are lacking. This study therefore aims 1) to interpret the variability of soil organic carbon in relation to key soil, topographical and land use variables and 2) to quantify the effects of land regeneration following abandonment on SOC stocks. Soil profiles were taken in the Sierra de los Filabres (SE Spain) in different land units along geomorphic and degradation gradients. SOC contents were modelled using recovery period, soil and topographical variables. Sample depth, topographical position, altitude, recovery period and stone content are identified as the main factors for predicting SOC concentrations. SOC stocks in 1 m depth of soil vary between 3.16 and 76.44 t ha-1. Recovery period (years since abandonment), topographical position and altitude were used to predict and map SOC stocks in the top 0.2 m. The results show that C accumulates fast during the first 10-50 years following abandonment, whereafter the stocks evolve towards a steady state level. The erosion zones in the study area demonstrate a higher potential to increase their SOC stocks when abandoned. Deposition zones have higher SOC stocks, although their C accumulation rate is lower compared to erosion dominated landscapes in the first 10-50 years following abandonment. Therefore, full understanding of the C sequestration potential of land use change in areas of complex topography requires knowledge of spatial variability in soil properties and in particular SOC.

  11. Annual and seasonal variability of metals and metalloids in urban and industrial soils in Alcalá de Henares (Spain)

    International Nuclear Information System (INIS)

    Peña-Fernández, A.; Lobo-Bedmar, M.C.; González-Muñoz, M.J.

    2015-01-01

    Contamination of urban and industrial soils with trace metals has been recognized as a major concern at local, regional and global levels due to their implication on human health. In this study, concentrations of aluminum (Al), arsenic (As), beryllium (Be), cadmium (Cd), chromium (Cr), manganese (Mn), nickel (Ni), lead (Pb), tin (Sn), thallium (Tl), vanadium (V) and zinc (Zn) were determined in soil samples collected in Alcalá de Henares (Madrid, Spain) in order to evaluate the annual and seasonal variation in their levels. The results show that the soils of the industrial area have higher metals concentrations than the urban area. Principal component analysis (PCA) revealed that the two principal sources of trace metal contamination, especially Cd, Cu, Pb, and Zn in the urban soils of Alcalá can be attributed to traffic emissions, while As, Ni and Be primarily originated from industrial discharges. The seasonal variation analysis has revealed that the emission sources in the industrial area remain constant with time. However, in urban areas, both emissions and emission pathways significantly increase over time due to ongoing development. Currently, there is no hypothesis that explains the small seasonal fluctuations of trace metals in soils, since there are many factors affecting this. Owing to the fact that urban environments are becoming the human habitat, it would therefore be advisable to monitor metals and metalloids in urban soils because of the potential risks to human health. - Highlights: • Anthropogenic activities may affect the seasonal metal variation in Alcalá's soils. • Weather characteristics may also influence the seasonal metal variation in soils. • Alcalá's continual urban growth may have increased the levels of metals in its soils. • Metal variability in Alcalá's industrial soils might be dependent on their sources. • High soil metal content might make it difficult to identify temporal variation

  12. Annual and seasonal variability of metals and metalloids in urban and industrial soils in Alcalá de Henares (Spain)

    Energy Technology Data Exchange (ETDEWEB)

    Peña-Fernández, A. [Departamento de Ciencias Biomédicas, Unidad de Toxicología, Universidad de Alcalá, Crta. Madrid-Barcelona Km, 33.6, 28871 Alcalá de Henares, Madrid (Spain); Lobo-Bedmar, M.C. [Instituto Madrileño de Investigación y Desarrollo Rural Agrario y Alimentario (IMIDRA), Finca el Encín, Crta. Madrid-Barcelona Km, 38.2, 28800 Alcalá de Henares, Madrid (Spain); González-Muñoz, M.J., E-mail: mariajose.gonzalez@uah.es [Departamento de Ciencias Biomédicas, Unidad de Toxicología, Universidad de Alcalá, Crta. Madrid-Barcelona Km, 33.6, 28871 Alcalá de Henares, Madrid (Spain)

    2015-01-15

    Contamination of urban and industrial soils with trace metals has been recognized as a major concern at local, regional and global levels due to their implication on human health. In this study, concentrations of aluminum (Al), arsenic (As), beryllium (Be), cadmium (Cd), chromium (Cr), manganese (Mn), nickel (Ni), lead (Pb), tin (Sn), thallium (Tl), vanadium (V) and zinc (Zn) were determined in soil samples collected in Alcalá de Henares (Madrid, Spain) in order to evaluate the annual and seasonal variation in their levels. The results show that the soils of the industrial area have higher metals concentrations than the urban area. Principal component analysis (PCA) revealed that the two principal sources of trace metal contamination, especially Cd, Cu, Pb, and Zn in the urban soils of Alcalá can be attributed to traffic emissions, while As, Ni and Be primarily originated from industrial discharges. The seasonal variation analysis has revealed that the emission sources in the industrial area remain constant with time. However, in urban areas, both emissions and emission pathways significantly increase over time due to ongoing development. Currently, there is no hypothesis that explains the small seasonal fluctuations of trace metals in soils, since there are many factors affecting this. Owing to the fact that urban environments are becoming the human habitat, it would therefore be advisable to monitor metals and metalloids in urban soils because of the potential risks to human health. - Highlights: • Anthropogenic activities may affect the seasonal metal variation in Alcalá's soils. • Weather characteristics may also influence the seasonal metal variation in soils. • Alcalá's continual urban growth may have increased the levels of metals in its soils. • Metal variability in Alcalá's industrial soils might be dependent on their sources. • High soil metal content might make it difficult to identify temporal variation.

  13. Coupling geochemical, mineralogical and microbiological approaches to assess the health of contaminated soil around the Almalyk mining and smelter complex, Uzbekistan

    International Nuclear Information System (INIS)

    Shukurov, Nosir; Kodirov, Obidjon; Peitzsch, Mirko; Kersten, Michael; Pen-Mouratov, Stanislav; Steinberger, Yosef

    2014-01-01

    This study describes the impact of airborne pollution resulting from mining and smelting activities on the soils of the Almalyk mining and industrial area (NE Uzbekistan). Samples were collected along a transect downwind of the industrial area. Enriched contents of some metals were found in the upper soil layers near the metallurgical complex (Zn ≤ 3010 mg kg −1 , Pb ≤ 630 mg kg −1 , Cd ≤ 30 mg kg −1 ) which suggests that these metals were derived from local stack emissions. The morphology and internal microstructure of metal-bearing spherical particles found in the heavy mineral fraction suggest that these particles were probably a result of inefficient flue gas cleaning technique of the smelter. The highest metal concentrations were found also in soil solutions and exchangeable solid fractions from the first three locations, and decreased with increasing distance from the pollution source along transect. Thermodynamic equilibrium calculations suggest that the mobile metal pool in the contaminated soil is mainly controlled by dissolution of metal carbonates formed as weathering product of the metalliferous particles. The health of the microbiological soil ecosystem was assessed by measurements of basal respiration, nematode abundance, biomass-related C and N content, and microbial metabolic quotient qCO 2 . Significant correlations were found between the dissolved metal content and the microbiological health parameters, a negative one for C mic /C org ratio, and a positive one for qCO 2 . A negative correlation was found between the amount of nematodes and the metal contents suggesting that the contaminated soil has significant impact on the functioning of the microbiological community. A better understanding of the spatial variations in the whole ecosystem functioning due to airborne impact could be very useful for establishing suitable land use and best management practices for the polluted areas. - Highlights: • Soil samples were collected along a

  14. Coupling geochemical, mineralogical and microbiological approaches to assess the health of contaminated soil around the Almalyk mining and smelter complex, Uzbekistan

    Energy Technology Data Exchange (ETDEWEB)

    Shukurov, Nosir; Kodirov, Obidjon; Peitzsch, Mirko [Geosciences Institute, Johannes Gutenberg University, Mainz 55099 (Germany); Kersten, Michael, E-mail: kersten@uni-mainz.de [Geosciences Institute, Johannes Gutenberg University, Mainz 55099 (Germany); Pen-Mouratov, Stanislav; Steinberger, Yosef [The Mina and Everard Goodman Faculty of Life Sciences, Bar-Ilan University, Ramat Gan 52900 (Israel)

    2014-04-01

    This study describes the impact of airborne pollution resulting from mining and smelting activities on the soils of the Almalyk mining and industrial area (NE Uzbekistan). Samples were collected along a transect downwind of the industrial area. Enriched contents of some metals were found in the upper soil layers near the metallurgical complex (Zn ≤ 3010 mg kg{sup −1}, Pb ≤ 630 mg kg{sup −1}, Cd ≤ 30 mg kg{sup −1}) which suggests that these metals were derived from local stack emissions. The morphology and internal microstructure of metal-bearing spherical particles found in the heavy mineral fraction suggest that these particles were probably a result of inefficient flue gas cleaning technique of the smelter. The highest metal concentrations were found also in soil solutions and exchangeable solid fractions from the first three locations, and decreased with increasing distance from the pollution source along transect. Thermodynamic equilibrium calculations suggest that the mobile metal pool in the contaminated soil is mainly controlled by dissolution of metal carbonates formed as weathering product of the metalliferous particles. The health of the microbiological soil ecosystem was assessed by measurements of basal respiration, nematode abundance, biomass-related C and N content, and microbial metabolic quotient qCO{sub 2}. Significant correlations were found between the dissolved metal content and the microbiological health parameters, a negative one for C{sub mic}/C{sub org} ratio, and a positive one for qCO{sub 2}. A negative correlation was found between the amount of nematodes and the metal contents suggesting that the contaminated soil has significant impact on the functioning of the microbiological community. A better understanding of the spatial variations in the whole ecosystem functioning due to airborne impact could be very useful for establishing suitable land use and best management practices for the polluted areas. - Highlights: • Soil

  15. {sup 222}Rn and CO{sub 2} soil-gas geochemical characterization of thermally altered clays at Orciatico (Tuscany, Central Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Voltattorni, N., E-mail: nunzia.voltattorni@ingv.it [Istituto Nazionale di Geofisica e Vulcanologia, Via di Vigna Murata 605, 00143 Rome (Italy); Lombardi, S. [Earth Science Department, University ' La Sapienza' , Piazzale A. Moro 5, 00185 Rome (Italy); Rizzo, S. [Via Tito, 1/A, 00061 Anguillara Sabazia, Rome (Italy)

    2010-08-15

    Research highlights: {yields} Soil-gas technique is applied to study gas permeability of Orciatico clay units. {yields} Clay permeability depends on thermal and mechanical alteration degree. {yields} Soil-gas distributions are due to shallow fracturing of clays. {yields} Rn and CO{sub 2} soil-gas anomalies highlight secondary permeability in clay sequence. {yields} Soil-gas results are supported by detailed geoelectrical surveys. - Abstract: The physical properties of clay allow argillaceous formations to be considered geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The clays of the Orciatico area (Tuscany, Central Italy), which were thermally altered via the intrusion of an alkali-trachyte laccolith, represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil-gas surveys to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different degrees of thermal alteration. The results of this study show that gas permeability is increased in the clay sequences subjected to greater heat input from the emplacement of the Orciatico intrusion, despite the lack of apparent mineral and geotechnical variations. These results, which take into consideration long time periods in a natural, large-scale geological system, may have important implications for the long-term safety of underground storage of nuclear waste in clay formations.

  16. Influence of plant productivity over variability of soil respiration: a multi-scale approach

    Science.gov (United States)

    Curiel Yuste, J.

    2009-04-01

    general controlled by the seasonality of substrate supply by plants (via photosynthates translocation and/or litter) to soil. Although soil temperature and soil moisture exert a strong influence over the variation in SR, our results indicates that substrate supply by plant activity could exert a more important than previously expected role in the variability of soil respiration. 1. CREAF (Centre de Recerca Ecológica i Aplicacions Forestals), Unitat d'Ecofisiologia i Canvi Global CREAF-CEAB-CSIC, BELLATERRA (Barcelona), Spain (j.curiel@creaf.uab.es) 2. University of Antwerp (UA), Antwerp, Belgium (ivan.janssens@ua.ac.be) 3. Institute of Ecology, University of Innsbruck, Innsbruck, Austria (michael.bahn@uibk.ac.at) 4. UMR Ecologie et Ecophysiologie Forestières, Centre INRA de Nancy, France (longdoz@nancy.inra.fr) 5. ESPM, University of Calicornia at Berkeley, Berkeley, CA, US (baldocchi@nature.berkeley.edu) 6. The Woods Hole Research Center, Falmouth, USA (edavidson@whrc.org) 7. Max-Planck-Institute for Biogeochemistry, Jena, Germany (markus.reichstein@bgc-jena.mpg.de) 8. Institute of Systems Biology and Ecology, Academy of Sciences of the Czech Republic, Czech Republic (manuel@brno.cas.cz) 9. Università degli studi della Tuscia, Viterbo, Italy (arriga@unitus.it) 10. Laurence Berkeley lab, Berkeley, CA, USA (mstorn@lbl.gov) 11. Gembloux Agricultural University, Gembloux, Belgium (aubinet.m@fsagx.ac.be) 12. Fundacion CEAM(Centro de Estudios Ambientales del Mediterráneo), Valencia, Spain (arnaud@ceam.es) 13. Institute of Hydrology and Meteorology, Technische Universität Dresden, Pienner, Germany (gruenwald@forst.tu-dresden.de) 14. Department of Environmental Sciences, Second University of Naples, Caserta, Italy (ilaria.inglima@unina2.it) 15. CNRS-CEFE Montpellier, France (Laurent.MISSON@cefe.cnrs.fr) 16. Agenzia Provinciale per l'Ambiente, Bolzano, Italy (leonar@inwind.it) 17. University of Helsinki Department of Forest Ecology, Helsinki, Finland (jukka

  17. Geochemical Variability and the Potential for Beneficial Use of Waste Water Coproduced with Oil from Permian Basin of the Southwest USA

    Science.gov (United States)

    Khan, N. A.; Holguin, F. O.; Xu, P.; Engle, M.; Dungan, B.; Hunter, B.; Carroll, K. C.

    2014-12-01

    The U.S. generates 21 billion barrels/year of coproduced water from oil and gas exploration, which is generally considered waste water. Growth in unconventional oil and gas production has spurred interest in beneficial uses of produced water, especially in arid regions such as the Permian Basin of Texas and New Mexico, the largest U.S. tight oil producer. Produced waters have variable chemistries, but generally contain high levels of organics and salts. In order to evaluate the environmental impact, treatment, and reuse potential, there is a need to characterize the compositional variability of produced water. In the present study, produced water samples were collected from 12 wells across the Permian Basin. Compositional analyses including coupled gas chromatography-time of flight-mass spectrometry and inductively coupled plasma-optical emission spectroscopy were conducted. The samples show elevated benzene, ethylbenzene, toluene, xylene, alkyl benzenes, propyl-benzene, and naphthalene compared to other heteroaromatics; they also contain complex hydrocarbon compounds containing oxygen, nitrogen, and sulfur. Van Krevelen diagrams show an increase in the concentration of heteroaromatic hydrocarbons with increasing well depth. The salinity, dominated by sodium-chloride, also increases with depth, ranging from 37-150 g/L TDS. Depth of wells (or producing formation) is a primary control on predicting water quality for treatment and beneficial use. Our results suggest that partial treatment by removing suspended solids and organic contaminants would support some beneficial uses such as onsite reuse, bioenergy production, and other industrial uses. Due to the high salinity, conventional desalination processes are not applicable or very costly, making beneficial uses requiring low salinity not feasible.

  18. Theoretical and experimental study of the bio-geochemical behaviour of americium 241 in simplified rhizosphere conditions. Application to a calcareous agricultural soil

    International Nuclear Information System (INIS)

    Perrier, T.

    2004-06-01

    Americium 241, is one of the most radio-toxic contaminant produced during the nuclear fuel cycle. It can be found in all environmental compartments, in particular the soils. The main goals of this study are to identify, quantify and model the effect of the main factors controlling the mobility of 241 Am in the rhizosphere and the agricultural soils. The physico-chemical parameters of the soil and of the soil solution, the potential role of microorganisms on the sorption-desorption processes, and the speciation of americium in solution have been more particularly studied. 241 Am remobilization has been studied at the laboratory using leaching experiments performed in controlled conditions on reworked calcareous soils artificially contaminated with 241 Am. The soil samples have been washed out in different hydrodynamic conditions by solutions with various compositions. The eluted solution has been analyzed (pH, conductivity, ionic composition, Fe tot , organic acids, 241 Am) and its bacterial biomass content too. The overall results indicate that 241 Am remobilization is contrasted and strongly linked with the condition under study (pH, ionic strength, glucose and/or citrate concentration). Therefore, a solution in equilibrium with the soil or containing small exudate concentrations (10 -4 M) re-mobilizes only a very small part of the americium fixed on the solid phase. The desorption of 241 Am corresponds to a solid/liquid coefficient of partition (K d ) of about 10 5 L.kg -1 . A significant addition of glucose induces an important dissolution of soil carbonates by the indirect action of microorganisms, but does not significantly favor the 241 Am remobilization. On the other hand, the presence of strong citrate concentrations (≥ 10 -2 M) allows 300 to 10000 time greater re-mobilizations by the complexing of 241 Am released after the dissolution of the carrying phases. Finally, the colloidal transport of 241 Am has been systematically observed in a limited but

  19. Geochemical assessment of light gaseous hydrocarbons in near ...

    Indian Academy of Sciences (India)

    Light hydrocarbons in soil have been used as direct indicators in geochemical hydrocarbon exploration, which remains an unconventional path in the petroleum industry. The occurrence of adsorbed soil ... Kalpana1 D J Patil1 A M Dayal1. National Geophysical Research Institute, Uppal Road, Hyderabad 500606, India.

  20. Geochemical exploration for uranium

    International Nuclear Information System (INIS)

    Rose, A.W.

    1977-01-01

    The processes and types of dispersion that produce anomalies in stream water, stream sediment, and ground water, and the factors that must be considered in planning and interpreting geochemical surveys are reviewed. Examples of surveys near known deposits show the types of results to be expected. Background values depend mainly on the content of U in rocks of the drainage area. In igneous rocks, U tends to increase with potassium from ultramafic rocks (0.01 ppM) to granitic rocks (1 to 5 ppM). Some alkalic rocks have unusually high contents of U (15 to 100 ppM). Uranium-rich provinces marked by igneous rocks unusually rich in U are recognized in several areas and appear to have a deep crustal or mantle origin. In western U.S., many tertiary tuffaceous rocks have a high U content. Sandstones, limestones, and many shales approximate the crustal abundance at 0.5 to 4 ppM, but black shales, phosphates, and some organic materials are notably enriched in U. Uranium is very soluble in most oxidizing waters at the earth's surface, but is precipitated by reducing agents (organic matter, H 2 S) and adsorbed by organic material and some Fe oxides. In most surface and ground waters, U correlates approximately with the total dissolved solids, conductivity, and bicarbonate concentration of the water, and with the U content of rocks it comes into contact with. Most surveys of stream water near known districts show distinct anomalies extending a few km to tens of km downstream. A complication with water is the large variability with time, up to x 50, as a result of changes in the ratio of ground water to direct runoff, and changes in rate of oxidation and leaching. Collection and analysis of water samples also pose some difficulties

  1. Contenido pseudototal de Cobre, Cinc, Hierro y Manganeso como estimador del fondo geoquímico en suelos de la Llanura Chaco-Pampeana de Córdoba, Argentina Pseudototal Copper, Zinc, Iron and Manganese content in soils for assessing the geochemical background of the Chaco-Pampean Plain of Cordoba, Argentina

    Directory of Open Access Journals (Sweden)

    Eduardo V Buffa

    2009-12-01

    cristalinidad. El carbono orgánico en superficie como segunda variable en la mayoría de los modelos para los cuatro elementos confirma la importancia de la materia orgánica como fuente de estos microelementos.Data on the total nutrient content of soils is essential for assessing potential fertility and is fundamental to environmental and edaphogenetic studies. The aim of this paper was to measure Cu, Zn, Fe y Mn in soils of the Chaco Pampean Plain in Argentina using the simultaneous acid nitric (HNO3 4 M extraction procedure (called pseudototal to infer geochemical background and geochemical baseline data by analysing surface and subsurface samples. The results can be related with other edaphic features such as organic carbon, acidity, salinity and carbonates. Average values of 11.3 to 19.2 mg Cu kg-¹, 29.4 to 61.5 mg Zn kg-¹, 285 to 626 mg Mn kg-¹ g-¹ and 9 to 19.9 g Fe kg-¹ were found at a soil depth of 0-60 cm, falling within the range reported in worldwide literature. The lowest values were found in sandy soils. The values at a soil depth of 0-20 cm were 17 mg Cu kg-1, 55 mg Zn kg-¹, 562 mg Mn kg-¹ and 16 g Fe kg-¹ in loessic and loam loessic soils and 12 Cu kg-¹, 36 mg Zn kg-¹, 347 mg Mn kg-¹ and 11 g Fe kg-¹in loam sandy soils. The textural difference between loessic and sandy soils reflects different background values for the four elements studied, the lowest values corresponding to sandy soils. Multiple regression analysis included Fe and Mn as the main variables to explain the amounts found for each of the four elements at each depth which is related to the high affinity between transition metals and their tendency to co-precipitate as low cristallinity oxides.The second variable in most of the models for the studied elements was organic carbon, confirming the importance of organic matter as a primary source of these micronutrients.

  2. Effect of Crop-Straw Derived Biochars on Pb(II) Adsorption in Two Variable Charge Soils

    Institute of Scientific and Technical Information of China (English)

    JIANG Tian-yu; XU Ren-kou; GU Tian-xia; JIANG Jun

    2014-01-01

    Two variable charge soils were incubated with biochars derived from straws of peanut, soybean, canola, and rice to investigate the effect of the biochars on their chemical properties and Pb(II) adsorption using batch experiments. The results showed soil cation exchange capacity (CEC) and pH signiifcantly increased after 30 d of incubation with the biochars added. The incorporation of the biochars markedly increased the adsorption of Pb(II), and both the electrostatic and non-electrostatic adsorption mechanisms contributed to Pb(II) adsorption by the variable charge soils. Adsorption isotherms illustrated legume-straw derived biochars more greatly increased Pb(II) adsorption on soils through the non-electrostatic mechanism via the formation of surface complexes between Pb(II) and acid functional groups of the biochars than did non-legume straw biochars. The adsorption capacity of Pb(II) increased, while the desorption amount slightly decreased with the increasing suspension pH for the studied soils, especially in a high suspension pH, indicating that precipitation also plays an important role in immobilizing Pb(II) to the soils.

  3. Spatial variability of isoproturon mineralizing activity within an agricultural field: Geostatistical analysis of simple physicochemical and microbiological soil parameters

    Energy Technology Data Exchange (ETDEWEB)

    El Sebai, T. [UMR Microbiologie et Geochimie des Sols, INRA/CMSE, 17 Rue Sully, BP 86510, 21065 Dijon Cedex (France); Lagacherie, B. [UMR Microbiologie et Geochimie des Sols, INRA/CMSE, 17 Rue Sully, BP 86510, 21065 Dijon Cedex (France); Soulas, G. [UMR Microbiologie et Geochimie des Sols, INRA/CMSE, 17 Rue Sully, BP 86510, 21065 Dijon Cedex (France); Martin-Laurent, F. [UMR Microbiologie et Geochimie des Sols, INRA/CMSE, 17 Rue Sully, BP 86510, 21065 Dijon Cedex (France)]. E-mail: fmartin@dijon.inra.fr

    2007-02-15

    We assessed the spatial variability of isoproturon mineralization in relation to that of physicochemical and biological parameters in fifty soil samples regularly collected along a sampling grid delimited across a 0.36 ha field plot (40 x 90 m). Only faint relationships were observed between isoproturon mineralization and the soil pH, microbial C biomass, and organic nitrogen. Considerable spatial variability was observed for six of the nine parameters tested (isoproturon mineralization rates, organic nitrogen, genetic structure of the microbial communities, soil pH, microbial biomass and equivalent humidity). The map of isoproturon mineralization rates distribution was similar to that of soil pH, microbial biomass, and organic nitrogen but different from those of structure of the microbial communities and equivalent humidity. Geostatistics revealed that the spatial heterogeneity in the rate of degradation of isoproturon corresponded to that of soil pH and microbial biomass. - In field spatial variation of isoproturon mineralization mainly results from the spatial heterogeneity of soil pH and microbial C biomass.

  4. Spatial variability of isoproturon mineralizing activity within an agricultural field: Geostatistical analysis of simple physicochemical and microbiological soil parameters

    International Nuclear Information System (INIS)

    El Sebai, T.; Lagacherie, B.; Soulas, G.; Martin-Laurent, F.

    2007-01-01

    We assessed the spatial variability of isoproturon mineralization in relation to that of physicochemical and biological parameters in fifty soil samples regularly collected along a sampling grid delimited across a 0.36 ha field plot (40 x 90 m). Only faint relationships were observed between isoproturon mineralization and the soil pH, microbial C biomass, and organic nitrogen. Considerable spatial variability was observed for six of the nine parameters tested (isoproturon mineralization rates, organic nitrogen, genetic structure of the microbial communities, soil pH, microbial biomass and equivalent humidity). The map of isoproturon mineralization rates distribution was similar to that of soil pH, microbial biomass, and organic nitrogen but different from those of structure of the microbial communities and equivalent humidity. Geostatistics revealed that the spatial heterogeneity in the rate of degradation of isoproturon corresponded to that of soil pH and microbial biomass. - In field spatial variation of isoproturon mineralization mainly results from the spatial heterogeneity of soil pH and microbial C biomass

  5. [Effects of land use and environmental factors on the variability of soil quality indicators in hilly Loess Plateau region of China].

    Science.gov (United States)

    Xu, Ming-Xiang; Liu, Guo-Bin; Zhao, Yun-Ge

    2011-02-01

    Classical statistics methods were adopted to analyze the soil quality variability, its affecting factors, and affecting degree at a regional scale (700 km2) in the central part of hilly Loess Plateau region of China. There existed great differences in the variability of test soil quality indicators. Soil pH, structural coefficient, silt content, specific gravity, bulk density, total porosity, capillary porosity, and catalase activity were the indicators with weak variability; soil nutrients (N, P, and K) contents, CaCO3 content, cation exchange capacity (CEC), clay content, micro-aggregate mean mass diameter, aggregate mean mass diameter, water-stable aggregates, respiration rate, microbial quotient, invertase and phosphatase activities, respiratory quotient, and microbial carbon and nitrogen showed medium variation; while soil labile organic carbon and phosphorus contents, erosion-resistance, permeability coefficient, and urease activity were the indicators with strong variability. The variability of soil CaCO3, total P and K, CEC, texture, and specific gravity, etc. was correlated with topography and other environmental factors, while the variability of dynamic soil quality indicators, including soil organic matter content, nitrogen content, water-stable aggregates, permeability, microbial biomass carbon and nitrogen, enzyme activities, and respiration rate, was mainly correlated with land use type. Overall, land use pattern explained 97% of the variability of soil quality indicators in the region. It was suggested that in the evaluation of soil quality in hilly Loess Plateau region, land use type and environmental factors should be fully considered.

  6. Field Soil Water Retention of the Prototype Hanford Barrier and Its Variability with Space and Time

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z. F.

    2015-08-14

    Engineered surface barriers are used to isolate underlying contaminants from water, plants, animals, and humans. To understand the flow processes within a barrier and the barrier’s ability to store and release water, the field hydraulic properties of the barrier need to be known. In situ measurement of soil hydraulic properties and their variation over time is challenging because most measurement methods are destructive. A multiyear test of the Prototype Hanford Barrier (PHB) has yielded in situ soil water content and pressure data for a nine-year period. The upper 2 m layer of the PHB is a silt loam. Within this layer, water content and water pressure were monitored at multiple depths at 12 water balance stations using a neutron probe and heat dissipation units. Valid monitoring data from 1995 to 2003 for 4 depths at 12 monitoring stations were used to determine the field water retention of the silt loam layer. The data covered a wide range of wetness, from near saturation to the permanent wilt point, and each retention curve contained 51 to 96 data points. The data were described well with the commonly used van Genuchten water retention model. It was found that the spatial variation of the saturated and residual water content and the pore size distribution parameter were relatively small, while that of the van Genuchten alpha was relatively large. The effects of spatial variability of the retention properties appeared to be larger than the combined effects of added 15% w/w pea gravel and plant roots on the properties. Neither of the primary hydrological processes nor time had a detectible effect on the water retention of the silt loam barrier.

  7. Iron corrosion in an anoxic soil: Comparison between thermodynamic modelling and ferrous archaeological artefacts characterised along with the local in situ geochemical conditions

    Energy Technology Data Exchange (ETDEWEB)

    Saheb, M.; Neff, D.; Michelin, A.; Dillmann, P. [CEA Saclay, CNRS, LAPA SIS2M, UMR3299, 91 - Gif-sur-Yvette (France); Saheb, M. [ANDRA, F-92298 Chatenay Malabry (France); Descostes, M. [CEA Saclay, DEN DANS DPC SECR, Lab Radionuclides Migrat Measurements and Modelling, 91 - Gif-sur-Yvette (France); Descostes, M. [Univ Evry, CEA, CNRS, UMR 8587, Evry (France); Dillmann, P. [CNRS, Inst Rech Archeomat, UMR 5060, F-75700 Paris (France)

    2010-07-01

    This article is part of an ongoing study on the long-term corrosion behaviour of ferrous archaeological artefacts. The aim of this study is to correlate the corrosion products formed on ancient artefacts in an anoxic medium to the environmental data using thermodynamic modelling. For this purpose, measurement campaigns have been conducted on the archaeological site of Glinet (16. century, High Normandy (Seine-Maritime), France) where the evolution of the pore water chemistry has been recorded for a period of one year. Three evolution steps have been distinguished after the oxidizing perturbation which was induced by the piezometers installation. The first step was related to an oxidizing environment in which pore water was in equilibrium with a Fe(III) precipitated phase: ferri-hydrite (FeOOH center dot 0.4 H{sub 2}O). The second step was considered as an intermediate step and Fe speciation had evolved; equilibrium was achieved between ferri-hydrite and a Fe(II) carbonate phase: siderite (Fe(II)CO{sub 3}). The last step of the evolution was related to a reducing stage where pore water was in equilibrium with magnetite (Fe(II, III){sub 3}O{sub 4}) and with chukanovite (Fe(II){sub 2}(OH){sub 2}CO{sub 3}). As these phases were present in the corrosion layers formed on the archaeological samples, it is possible to conclude that the thermodynamic approach was helpful in developing a better understanding of the effect of geochemical conditions on the composition and mineralogy of the corrosion products formed on archaeological artefacts. This work could be used as a reference for further corrosion studies, especially on long-term corrosion processes applied to nuclear waste disposal. (authors)

  8. A Bézier-Spline-based Model for the Simulation of Hysteresis in Variably Saturated Soil

    Science.gov (United States)

    Cremer, Clemens; Peche, Aaron; Thiele, Luisa-Bianca; Graf, Thomas; Neuweiler, Insa

    2017-04-01

    Most transient variably saturated flow models neglect hysteresis in the p_c-S-relationship (Beven, 2012). Such models tend to inadequately represent matrix potential and saturation distribution. Thereby, when simulating flow and transport processes, fluid and solute fluxes might be overestimated (Russo et al., 1989). In this study, we present a simple, computationally efficient and easily applicable model that enables to adequately describe hysteresis in the p_c-S-relationship for variably saturated flow. This model can be seen as an extension to the existing play-type model (Beliaev and Hassanizadeh, 2001), where scanning curves are simplified as vertical lines between main imbibition and main drainage curve. In our model, we use continuous linear and Bézier-Spline-based functions. We show the successful validation of the model by numerically reproducing a physical experiment by Gillham, Klute and Heermann (1976) describing primary drainage and imbibition in a vertical soil column. With a deviation of 3%, the simple Bézier-Spline-based model performs significantly better that the play-type approach, which deviates by 30% from the experimental results. Finally, we discuss the realization of physical experiments in order to extend the model to secondary scanning curves and in order to determine scanning curve steepness. {Literature} Beven, K.J. (2012). Rainfall-Runoff-Modelling: The Primer. John Wiley and Sons. Russo, D., Jury, W. A., & Butters, G. L. (1989). Numerical analysis of solute transport during transient irrigation: 1. The effect of hysteresis and profile heterogeneity. Water Resources Research, 25(10), 2109-2118. https://doi.org/10.1029/WR025i010p02109. Beliaev, A.Y. & Hassanizadeh, S.M. (2001). A Theoretical Model of Hysteresis and Dynamic Effects in the Capillary Relation for Two-phase Flow in Porous Media. Transport in Porous Media 43: 487. doi:10.1023/A:1010736108256. Gillham, R., Klute, A., & Heermann, D. (1976). Hydraulic properties of a porous

  9. Methods for geochemical analysis

    Science.gov (United States)

    Baedecker, Philip A.

    1987-01-01

    The laboratories for analytical chemistry within the Geologic Division of the U.S. Geological Survey are administered by the Office of Mineral Resources. The laboratory analysts provide analytical support to those programs of the Geologic Division that require chemical information and conduct basic research in analytical and geochemical areas vital to the furtherance of Division program goals. Laboratories for research and geochemical analysis are maintained at the three major centers in Reston, Virginia, Denver, Colorado, and Menlo Park, California. The Division has an expertise in a broad spectrum of analytical techniques, and the analytical research is designed to advance the state of the art of existing techniques and to develop new methods of analysis in response to special problems in geochemical analysis. The geochemical research and analytical results are applied to the solution of fundamental geochemical problems relating to the origin of mineral deposits and fossil fuels, as well as to studies relating to the distribution of elements in varied geologic systems, the mechanisms by which they are transported, and their impact on the environment.

  10. Release of dissolved phosphorus from riparian wetlands: Evidence for complex interactions among hydroclimate variability, topography and soil properties.

    Science.gov (United States)

    Gu, Sen; Gruau, Gérard; Dupas, Rémi; Rumpel, Cornélia; Crème, Alexandra; Fovet, Ophélie; Gascuel-Odoux, Chantal; Jeanneau, Laurent; Humbert, Guillaume; Petitjean, Patrice

    2017-11-15

    In agricultural landscapes, establishment of vegetated buffer zones in riparian wetlands (RWs) is promoted to decrease phosphorus (P) emissions because RWs can trap particulate P from upslope fields. However, long-term accumulation of P risks the release of dissolved P, since the unstable hydrological conditions in these zones may mobilize accumulated particulate P by transforming it into a mobile dissolved P species. This study evaluates how hydroclimate variability, topography and soil properties interact and influence this mobilization, using a three-year dataset of molybdate-reactive dissolved P (MRDP) and total dissolved P (TDP) concentrations in soil water from two RWs located in an agricultural catchment in western France (Kervidy-Naizin), along with stream P concentrations. Two main drivers of seasonal dissolved P release were identified: i) soil rewetting during water-table rise after dry periods and ii) reductive dissolution of soil Fe (hydr)oxides during prolonged water saturation periods. These mechanisms were shown to vary greatly in space (according to topography) and time (according to intra- and interannual hydroclimate variability). The concentration and speciation of the released dissolved P also varied spatially depending on soil chemistry and local topography. Comparison of sites revealed a similar correlation between soil P speciation (percentage of organic P ranging from 35-70%) and the concentration and speciation of the released P (MRDP from topography and soil chemistry must be considered to decrease the risk of remobilizing legacy soil P when establishing riparian buffer zones in agricultural landscapes. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. Soil water sensing: Implications of sensor capabilities for variable rate irrigation management

    Science.gov (United States)

    Irrigation scheduling using soil water sensors aims at maintaining the soil water content in the crop root zone above a lower limit defined by the management allowed depletion (MAD) for that soil and crop, but not so wet that too much water is lost to deep percolation, evaporation and runoff or that...

  12. Soil Moisture Variability and its Effects on Herbage Production in Semi-arid Rangelands of Kenya

    International Nuclear Information System (INIS)

    Too, D.K.; Trlica, M.J.; Swift, D.M.; Musembi, D.K.

    1999-01-01

    Results obtained from recent studies focused on rangelands potential as influenced by human activity and climatic factors in the semi-arid and arid pastoral ecosystems of Northern Kenya indicated great temporal and spatial forage production variability. The objective of the studies was to document primary production in relation to water stress (drought), herbivory and direct human activities. Efforts also focused on finding possibilities of increasing productivity while conserving the finite resources for sustainable use. Laboratory, field and numerical methods were employed over several seasons and years. Forb and grass production was more variable than that of the browse (dwarf shrub) layer. Compared to forbs and dwarf shrubs, the grass layer contributed less to the total production in all seasons, indicating that the region had less potential for grazers compared to browsers. Spatial-temporal variation in rangeland carrying capacity reflected the great spatial heterogeneity in vegetation types and production. Similarly, seasonal differences were very evident, with highest estimates in the long rainy and the lowest during the dry and short rainy seasons, respectively. Factors limiting rangeland production potential were identified to be moisture deficiency, resource-use conflicts, an increasing and partially sedentarised nomadic population, overgrazing, tree felling, and land degradation (desert encroachment). Measures that can improve rangeland production potential and provide a better way of life for the inhabitants of the region include: (a) identification of land degradation (e.g. by means of bio-indicators and Geographical Information Systems, GIS); (b) technical interventions (i.e. soil and water conservation, restoration of degraded areas, fodder production); (c) social-economic interventions (i.e. resolution of resource-use conflicts, alleviation of poverty, infrastructure development improvement of livestock marketing channels etc.) and (d) continued

  13. Interpolation Approaches for Characterizing Spatial Variability of Soil Properties in Tuz Lake Basin of Turkey

    Science.gov (United States)

    Gorji, Taha; Sertel, Elif; Tanik, Aysegul

    2017-12-01

    Soil management is an essential concern in protecting soil properties, in enhancing appropriate soil quality for plant growth and agricultural productivity, and in preventing soil erosion. Soil scientists and decision makers require accurate and well-distributed spatially continuous soil data across a region for risk assessment and for effectively monitoring and managing soils. Recently, spatial interpolation approaches have been utilized in various disciplines including soil sciences for analysing, predicting and mapping distribution and surface modelling of environmental factors such as soil properties. The study area selected in this research is Tuz Lake Basin in Turkey bearing ecological and economic importance. Fertile soil plays a significant role in agricultural activities, which is one of the main industries having great impact on economy of the region. Loss of trees and bushes due to intense agricultural activities in some parts of the basin lead to soil erosion. Besides, soil salinization due to both human-induced activities and natural factors has exacerbated its condition regarding agricultural land development. This study aims to compare capability of Local Polynomial Interpolation (LPI) and Radial Basis Functions (RBF) as two interpolation methods for mapping spatial pattern of soil properties including organic matter, phosphorus, lime and boron. Both LPI and RBF methods demonstrated promising results for predicting lime, organic matter, phosphorous and boron. Soil samples collected in the field were used for interpolation analysis in which approximately 80% of data was used for interpolation modelling whereas the remaining for validation of the predicted results. Relationship between validation points and their corresponding estimated values in the same location is examined by conducting linear regression analysis. Eight prediction maps generated from two different interpolation methods for soil organic matter, phosphorus, lime and boron parameters

  14. Variations in Carabidae assemblages across the farmland habitats in relation to selected environmental variables including soil properties

    Directory of Open Access Journals (Sweden)

    Beáta Baranová

    2018-03-01

    Full Text Available The variations in ground beetles (Coleoptera: Carabidae assemblages across the three types of farmland habitats, arable land, meadows and woody vegetation were studied in relation to vegetation cover structure, intensity of agrotechnical interventions and selected soil properties. Material was pitfall trapped in 2010 and 2011 on twelve sites of the agricultural landscape in the Prešov town and its near vicinity, Eastern Slovakia. A total of 14,763 ground beetle individuals were entrapped. Material collection resulted into 92 Carabidae species, with the following six species dominating: Poecilus cupreus, Pterostichus melanarius, Pseudoophonus rufipes, Brachinus crepitans, Anchomenus dorsalis and Poecilus versicolor. Studied habitats differed significantly in the number of entrapped individuals, activity abundance as well as representation of the carabids according to their habitat preferences and ability to fly. However, no significant distinction was observed in the diversity, evenness neither dominance. The most significant environmental variables affecting Carabidae assemblages species variability were soil moisture and herb layer 0-20 cm. Another best variables selected by the forward selection were intensity of agrotechnical interventions, humus content and shrub vegetation. The other from selected soil properties seem to have just secondary meaning for the adult carabids. Environmental variables have the strongest effect on the habitat specialists, whereas ground beetles without special requirements to the habitat quality seem to be affected by the studied environmental variables just little.

  15. Geochemical Investigations of Groundwater Stability

    International Nuclear Information System (INIS)

    Bath, Adrian

    2006-05-01

    The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

  16. Geochemical Investigations of Groundwater Stability

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2006-05-15

    The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

  17. Using scaling factors for evaluating spatial and temporal variability of soil hydraulic properties within one elevation transect

    Science.gov (United States)

    Nikodem, Antonín; Kodešová, Radka; Jakšík, Ondřej; Fér, Miroslav; Klement, Aleš

    2016-04-01

    This study was carried out in Southern Moravia, in the Czech Republic. The original soil unit in the wider area is a Haplic Chernozem developed on loess. The intensive agricultural exploitation in combination with terrain morphology has resulted in a highly diversified soil spatial pattern. Nowadays the original soil unit is preserved only on top of relatively flat parts, and is gradually transformed by water erosion up to Regosols on the steepest slopes, while colluvial soils are formed in terrain depressions and at toe slopes due to sedimentation of previously eroded material. Soils within this area has been intensively investigated during the last several years (e.g. Jakšík et al., 2015; Vašát et al., 2014, 2015a,b). Soil sampling (disturbed and undisturbed 100-cm3 soil samples) was performed at 5 points of one elevation transect in November 2010 (after wheat sowing) and August 2011 (after wheat harvest). Disturbed soil samples were used to determine basic soil properties (grain size distribution and organic carbon content etc.). Undisturbed soil samples were used to determine the soil water retention curves and the hydraulic conductivity functions using the multiple outflow tests in Tempe cells and a numerical inversion with HYDRUS 1-D. Scaling factors (alpha-h for pressure head, alpha-theta for soil water contents and alpha-k for hydraulic conductivities) were used here to express soil hydraulic properties variability. Evaluated scaling factors reflected position within the elevation transect as well as time of soil sampling. In general large values of alpha-h, lower values of alpha-k and similar values of alpha-theta were obtained in 2010 in comparison to values obtained in 2011, which indicates development of soil structure during the vegetation season. Jakšík, O., Kodešová, R., Kubiš, A., Stehlíková, I., Drábek, O., Kapička, A. (2015): Soil aggregate stability within morphologically diverse areas. Catena, 127, 287-299. Vašát, R., Kode

  18. Small scale variability of soil parameters in different land uses on the southern slopes of Mount Kilimanjaro

    Science.gov (United States)

    Bogner, Christina; Kühnel, Anna; Hepp, Johannes; Huwe, Bernd

    2016-04-01

    indicator of vegetation patterns. First results support our general hypotheses. In the coffee plantation anisotropic variation of soil parameters clearly showed the anthropogenic influence like compaction due to agricultural machinery. However, soil bulk density and penetration resistance in the homegarden were also quite variable at the sites. The larger variability of throughfall in the homegarden is reflected in the patterns of soil moisture. Regarding the larger scale, where we compared different homegardens and coffee plantations along the southern slope of the mountain, soil parameters of the coffee plots were less diverse than those of the homegardens.

  19. Spatial variability of soil pH based on GIS combined with geostatistics in Panzhihua tobacco area

    International Nuclear Information System (INIS)

    Du Wei; Wang Changquan; Li Bing; Li Qiquan; Du Qian; Hu Jianxin; Liu Chaoke

    2012-01-01

    GIS and geostatistics were utilized to study the spatial variability of soil pH in Panzhihua tobacco area. Results showed that pH values in this area ranged from 4.5 to 8.3, especially 5.5 to 6.5, and in few areas were lower than 5.0 or higher than 7.0 which can meet the need of high-quality tobacco production. The best fitting model of variogram was exponential model with the nugget/sill of soil pH in 13.61% indicating strong spatial correlation. The change process was 5.40 km and the coefficient of determination was 0.491. The spatial variability of soil pH was mainly caused by structural factors such as cane, topography and soil type. The soil pH in Panzhihua tobacco area also showed a increasing trend of northwest to southeast trend. The pH of some areas in Caochang, Gonghe and Yumen were lower, and in Dalongtan were slightly higher. (authors)

  20. Quantitative physical and chemical variables used to assess erosion and fertility loss in tropical Dominican and Haitian soils

    Science.gov (United States)

    Pastor, J.; Alexis, S.; Vizcayno, C.; Hernández, A. J.

    2009-04-01

    mines (bauxite and limestone), crops and livestock. The hypothesis that heavy metals liberated by geochemical actions in some of these tropical ecosystems could be related both to productivity and to human and animal health, led us also to assess metal bioavailability in the area's main crops as the primary source of food or fodder. To establish the context of the heavy metal pollution, we characterized the geoedaphic features of the region. The predominant rocks are sedimentary limestones: with limestone colluvial deposits dominant in the tropical conifer forest and rain forest of the Sierra de Bahoruco; crystalline limestones in the tropical latifoliated forest; and Quaternary detritic rocks and reefs (carbonates overlying alterites) in the dry tropical forest. Across the territory, there is a marked predominance of soils that range from surface soils to shallow, poorly developed stony soils of low natural fertility. Most can be classified as entisols. Soils of recent alluvial origin lack pedogenetic horizons and are subjected to diverse humidity and temperature regimens. Slopes are pronounced and relief and altitudes vary. Their profiles include A-R horizons characterised by displaying an ochre epipedon over a fractured rock bed whose depth is shallow and A-C horizons of a sandy to clayey soil and subsoil texture, whose colours range from dark brown to grey and depths from very shallow to deep. Soils occur from the mountains to landscapes including rivers or sandy coasts. The ecosystems examined occur from an altitude of 1300-1200 m to sea level and the cultivated soils have the main food sources for human and animal consumption: bean, corn, sorghum, coffee, Guinea banana, fruit trees and tubers. We present these data for 79 soil samples according to the corresponding landscape units (forests) along with their dominant lithologies (crystalline limestones, carbonated limestones on alterites and coral limestones). Our study describes edaphic processes linked to

  1. Vertical and lateral variability of soils structure – potentials for environmental reconstruction. Case study of the Middle Paeleoithic alluvial plain of the Wallertheim site (Germany).

    OpenAIRE

    Becze-Deák, Judit; Langohr, Judit

    2017-01-01

    This study highlights the potential contributions of soil studies to the environmental reconstructions in terrestrial context. The soils structure of the soil-sedimentary sequence of the Middle Palaeolithic site of Wallertheim has been analysed in details. The observation of the vertical and lateral variability of the soils characteristics as well as their related distribution on large section enabled to detect the impact of various and changing climatic and environmental conditions. As such ...

  2. Characterization of soils in terms of pedological variability under different physiography of Damodar command area (part, West Bengal, India

    Directory of Open Access Journals (Sweden)

    Ranjan Bera

    2015-12-01

    Full Text Available Five representative soil profiles occurring on four different physiography under subtropical environment of Damodar command area, India, were studied for soil pedological variability. Two way approaches were taken to evaluate the extent of profile development. Firstly different extractants were used to determine various forms of Fe and Al and their different ratios. Average contents of Fe and Al, extracted by different extracting reagents were found to be in descending order, as follows: Aldith > Aloxa > Alpyr and Fedith > Feoxa > Fepyr. Analysis of pyrophosphate (pyr, oxalate (oxa, and dithionate (dith extractable Fe and Al fractions indicated that with increasing soil age, the content of crystalline Fe and Al oxides increased at the expense of the poorly crystalline forms. The mean content of amorphous Fe and Al, crystalline Fe and Al, and their ratios estimated the degree of soil development. In the second part, elemental analysis was done, silica to sesquioxide ratio as well as ratio of alkali cations was measured and weathering index of each horizon was determined. The ratios and weathering indices indicated that except Madhpur soil series, all other soils were young and pedological development was still in progress in Damodar command area.

  3. All-union Conference. Principles and methods of regional and geochemical investigations into radionuclide migration

    International Nuclear Information System (INIS)

    Khitrov, L.M.

    1989-01-01

    The collection presents abstracts of papers concerning landscape-geochemical research of radionuclides migration; aspects of 'hot particles' study; radionuclides forms and behaviour in soils, in soil-plant; soil-natural water systems, as well as in water ecosystems. Methods of natural objects artificial radioactivity study are reviewed. Distribution of natural radionuclides in soils. natural waters, etc. is discussed

  4. The estimation of soil parameters using observations on crop biophysical variables and the crop model STICS improve the predictions of agro environmental variables.

    Science.gov (United States)

    Varella, H.-V.

    2009-04-01

    Dynamic crop models are very useful to predict the behavior of crops in their environment and are widely used in a lot of agro-environmental work. These models have many parameters and their spatial application require a good knowledge of these parameters, especially of the soil parameters. These parameters can be estimated from soil analysis at different points but this is very costly and requires a lot of experimental work. Nevertheless, observations on crops provided by new techniques like remote sensing or yield monitoring, is a possibility for estimating soil parameters through the inversion of crop models. In this work, the STICS crop model is studied for the wheat and the sugar beet and it includes more than 200 parameters. After a previous work based on a large experimental database for calibrate parameters related to the characteristics of the crop, a global sensitivity analysis of the observed variables (leaf area index LAI and absorbed nitrogen QN provided by remote sensing data, and yield at harvest provided by yield monitoring) to the soil parameters is made, in order to determine which of them have to be estimated. This study was made in different climatic and agronomic conditions and it reveals that 7 soil parameters (4 related to the water and 3 related to the nitrogen) have a clearly influence on the variance of the observed variables and have to be therefore estimated. For estimating these 7 soil parameters, a Bayesian data assimilation method is chosen (because of available prior information on these parameters) named Importance Sampling by using observations, on wheat and sugar beet crop, of LAI and QN at various dates and yield at harvest acquired on different climatic and agronomic conditions. The quality of parameter estimation is then determined by comparing the result of parameter estimation with only prior information and the result with the posterior information provided by the Bayesian data assimilation method. The result of the

  5. Role of the Soil Thermal Inertia in the short term variability of the surface temperature and consequences for the soil-moisture temperature feedback

    Science.gov (United States)

    Cheruy, Frederique; Dufresne, Jean-Louis; Ait Mesbah, Sonia; Grandpeix, Jean-Yves; Wang, Fuxing

    2017-04-01

    A simple model based on the surface energy budget at equilibrium is developed to compute the sensitivity of the climatological mean daily temperature and diurnal amplitude to the soil thermal inertia. It gives a conceptual framework to quantity the role of the atmospheric and land surface processes in the surface temperature variability and relies on the diurnal amplitude of the net surface radiation, the sensitivity of the turbulent fluxes to the surface temperature and the thermal inertia. The performances of the model are first evaluated with 3D numerical simulations performed with the atmospheric (LMDZ) and land surface (ORCHIDEE) modules of the Institut Pierre Simon Laplace (IPSL) climate model. A nudging approach is adopted, it prevents from using time-consuming long-term simulations required to account for the natural variability of the climate and allow to draw conclusion based on short-term (several years) simulations. In the moist regions the diurnal amplitude and the mean surface temperature are controlled by the latent heat flux. In the dry areas, the relevant role of the stability of the boundary layer and of the soil thermal inertia is demonstrated. In these regions, the sensitivity of the surface temperature to the thermal inertia is high, due to the high contribution of the thermal flux to the energy budget. At high latitudes, when the sensitivity of turbulent fluxes is dominated by the day-time sensitivity of the sensible heat flux to the surface temperature and when this later is comparable to the thermal inertia term of the sensitivity equation, the surface temperature is also partially controlled by the thermal inertia which can rely on the snow properties; In the regions where the latent heat flux exhibits a high day-to-day variability, such as transition regions, the thermal inertia has also significant impact on the surface temperature variability . In these not too wet (energy limited) and not too dry (moisture-limited) soil moisture (SM

  6. Soils

    Science.gov (United States)

    Emily Moghaddas; Ken Hubbert

    2014-01-01

    When managing for resilient forests, each soil’s inherent capacity to resist and recover from changes in soil function should be evaluated relative to the anticipated extent and duration of soil disturbance. Application of several key principles will help ensure healthy, resilient soils: (1) minimize physical disturbance using guidelines tailored to specific soil types...

  7. Geochemical prospecting in Guiana

    International Nuclear Information System (INIS)

    Coulomb, R.

    1957-01-01

    During the last few years geochemical prospecting techniques have become common usage in the field of mineral deposit prospecting. The real scope of these methods lies in their use in the prospecting of large areas. The most promising use of the geochemistry and hydro-geochemistry of uranium is in heavily forested tropical territories, with few outcrops, where radiometry is strongly handicapped. (author) [fr

  8. Assessment of diagenetic alteration of dinosaur eggshells through petrography and geochemical analysis

    Science.gov (United States)

    Enriquez, M. V.; Eagle, R.; Eiler, J. M.; Tripati, A. K.; Ramirez, P. C.; Loyd, S. J.; Chiappe, L.; Montanari, S.; Norell, M.; Tuetken, T.

    2012-12-01

    Carbonate clumped isotope analysis of fossil eggshells has the potential to constrain both the physiology of extinct animals and, potentially, paleoenvironmental conditions, especially when coupled with isotopic measurements of co-occurring soil carbonates. Eggshell samples from both modern vertebrates and Cretaceous Hadrosaurid, Oviraptorid, Titanosaur, Hypselosaurus, Faveoolithus, dinosaur fossils have been collected from Auca Mahuevo, Argentina and Rousett, France, amongst other locations, for geochemical analysis to determine if isotopic signatures could be used to indicate warm- or cold-bloodedness. In some locations soil carbonates were also analyzed to constrain environmental temperatures. In order to test the validity of the geochemical results, an extensive study was undertaken to establish degree of diagenetic alteration. Petrographic and cathodoluminescence characterization of the eggshells were used to assess diagenetic alteration. An empirical 1-5 point scale was used to assign each sample an alteration level, and the observations were then compared with the geochemical results. Specimens displayed a wide range of alteration states. Some of which were well preserved and others highly altered. Another group seemed to be structural intact and only under cathodoluminescence was alteration clearly observed. In the majority of samples, alteration level was found to be predictably related to geochemical results. From specimens with little evidence for diagenesis, carbonate clumped isotope signatures support high (37-40°C) body temperature for Titanosaurid dinosaurs, but potentially lower body temperatures for other taxa. If these data do, in fact, represent original eggshell growth temperatures, these results support variability in body temperature amongst Cretaceous dinosaurs and potentially are consistent with variations between adult body temperature and size — a characteristic of 'gigantothermy'.

  9. Effect of variable soil texture, metal saturation of soil organic matter (SOM) and tree species composition on spatial distribution of SOM in forest soils in Poland.

    Science.gov (United States)

    Gruba, Piotr; Socha, Jarosław; Błońska, Ewa; Lasota, Jarosław

    2015-07-15

    In this study we investigated the effect of fine (ϕclay (FF) content in soils, site moisture, metal (Al and Fe) of soil organic matter (SOM) and forest species composition on the spatial distribution of carbon (C) pools in forest soils at the landscape scale. We established 275 plots in regular 200×200m grid in a forested area of 14.4km(2). Fieldwork included soil sampling of the organic horizon, mineral topsoil and subsoil down to 40cm deep. We analysed the vertical and horizontal distribution of soil organic carbon (SOC) stocks, as well as the quantity of physically separated fractions including the free light (fLF), occluded light (oLF) and mineral associated fractions (MAF) in the mineral topsoil (A, AE) horizons. Distribution of C in soils was predominantly affected by the variation in the FF content. In soils richer in the FF more SOC was accumulated in mineral horizons and less in the organic horizons. Accumulation of SOC in mineral soil was also positively affected by the degree of saturation of SOM with Al and Fe. The increasing share of beech influenced the distribution of C stock in soil profiles by reducing the depth of O horizon and increasing C stored in mineral soil. The content of FF was positively correlated with the content of C in MAF and fLF fractions. The content of oLF and MAF fractions was also positively influenced by a higher degree of metal saturation, particularly Al. Our results confirmed that Al plays an important role in the stabilization of SOM inside aggregates (CoLF) and as in CMAF fractions. We also found a significant, positive effect of beech on the CfLF and fir on the CoLF content. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Soil Organic Carbon Variability in High-Andean Ecosystems: Bringing Together Machine Learning and Proximal Soil Sensing

    Science.gov (United States)

    Gavilan, C.; Grunwald, S.; Quiroz, R.

    2017-12-01

    The Andes represent the largest and highest mountain range in the tropics and is considered an important reserve of biodiversity, water provision and soil organic carbon (SOC) stocks. Nevertheless, limited attention has been given to estimate these stocks due to the lack of recent soil data, the poor accessibility and the wide range of coexistent ecosystems. In addition, conventional methods to determine SOC are usually time consuming and expensive to use in large-scale studies, hindering the possibility to have an accurate SOC assessment in the region. Proximal soil sensing techniques, such as visible near infrared (VNIR) and mid infrared (MIR) spectroscopy, have proven to be useful as an alternative to conventional methods for characterizing SOC but have not been tested in Andean soils. The aim of this study was to evaluate the potential of using VNIR and MIR spectroscopy to predict SOC content in the Central Andean region, using multivariate methods. Three study areas were selected across the Peruvian Central Andes. A total of 400 topsoil samples (0-30 cm) were collected and analyzed for SOC. The VNIR and MIR reflectance of the soil samples was measured in the laboratory. Three modeling approaches: Partial least squares regression (PLSR), random forest (RF) and support vector machine (SVM) were used to predict SOC from VNIR and MIR spectra in the study areas. The data was preprocessed in order to minimize the noise and optimize the accuracy of predictions. The models, for each study area, were assessed using 10-fold cross validation. Independent validation was implemented in the whole dataset (400 observations) by splitting it into calibration (70 %) and validation (30%) sets. Overall, the results indicate potential for both VNIR and MIR spectra to predict SOC content in the Andean soils. SOC content predictions from MIR spectra outperformed those from VNIR spectra. The evaluation of model performance shows that RF and SVM provide more accurate SOC predictions

  11. Reference Evapotranspiration Retrievals from a Mesoscale Model Based Weather Variables for Soil Moisture Deficit Estimation

    Directory of Open Access Journals (Sweden)

    Prashant K. Srivastava

    2017-10-01

    Full Text Available Reference Evapotranspiration (ETo and soil moisture deficit (SMD are vital for understanding the hydrological processes, particularly in the context of sustainable water use efficiency in the globe. Precise estimation of ETo and SMD are required for developing appropriate forecasting systems, in hydrological modeling and also in precision agriculture. In this study, the surface temperature downscaled from Weather Research and Forecasting (WRF model is used to estimate ETo using the boundary conditions that are provided by the European Center for Medium Range Weather Forecast (ECMWF. In order to understand the performance, the Hamon’s method is employed to estimate the ETo using the temperature from meteorological station and WRF derived variables. After estimating the ETo, a range of linear and non-linear models is utilized to retrieve SMD. The performance statistics such as RMSE, %Bias, and Nash Sutcliffe Efficiency (NSE indicates that the exponential model (RMSE = 0.226; %Bias = −0.077; NSE = 0.616 is efficient for SMD estimation by using the Observed ETo in comparison to the other linear and non-linear models (RMSE range = 0.019–0.667; %Bias range = 2.821–6.894; NSE = 0.013–0.419 used in this study. On the other hand, in the scenario where SMD is estimated using WRF downscaled meteorological variables based ETo, the linear model is found promising (RMSE = 0.017; %Bias = 5.280; NSE = 0.448 as compared to the non-linear models (RMSE range = 0.022–0.707; %Bias range = −0.207–−6.088; NSE range = 0.013–0.149. Our findings also suggest that all the models are performing better during the growing season (RMSE range = 0.024–0.025; %Bias range = −4.982–−3.431; r = 0.245–0.281 than the non−growing season (RMSE range = 0.011–0.12; %Bias range = 33.073–32.701; r = 0.161–0.244 for SMD estimation.

  12. Influence of environmental variables on the structure and composition of soil bacterial communities in natural and constructed wetlands.

    Science.gov (United States)

    Arroyo, Paula; Sáenz de Miera, Luis E; Ansola, Gemma

    2015-02-15

    Bacteria are key players in wetland ecosystems, however many essential aspects regarding the ecology of wetland bacterial communities remain unknown. The present study characterizes soil bacterial communities from natural and constructed wetlands through the pyrosequencing of 16S rDNA genes in order to evaluate the influence of wetland variables on bacterial community composition and structure. The results show that the composition of soil bacterial communities was significantly associated with the wetland type (natural or constructed wetland), the type of environment (lagoon, Typha or Salix) and three continuous parameters (SOM, COD and TKN). However, no clear associations were observed with soil pH. Bacterial diversity values were significantly lower in the constructed wetland with the highest inlet nutrient concentrations. The abundances of particular metabolic groups were also related to wetland characteristics. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Seasonal variability of soil CO2 flux and its carbon isotope composition in Krakow urban area, Southern Poland.

    Science.gov (United States)

    Jasek, Alina; Zimnoch, Miroslaw; Gorczyca, Zbigniew; Smula, Ewa; Rozanski, Kazimierz

    2014-06-01

    As urban atmosphere is depleted of (13)CO2, its imprint should be detectable in the local vegetation and therefore in its CO2 respiratory emissions. This work was aimed at characterising strength and isotope signature of CO2 fluxes from soil in urban areas with varying distances from anthropogenic CO2 emissions. The soil CO2 flux and its δ(13)C isotope signature were measured using a chamber method on a monthly basis from July 2009 to May 2012 within the metropolitan area of Krakow, Southern Poland, at two locations representing different levels of anthropogenic influence: a lawn adjacent to a busy street (A) and an urban meadow (B). The small-scale spatial variability of the soil CO2 flux was also investigated at site B. Site B revealed significantly higher summer CO2 fluxes (by approximately 46 %) than site A, but no significant differences were found between their δ(13)CO2 signatures.

  14. Toxicity screening of soils from different mine areas—A contribution to track the sensitivity and variability of Arthrobacter globiformis assay

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Catarina R., E-mail: crmarques@ua.pt [Departamento de Biologia and CESAM (Centro de Estudos do Ambiente e do Mar), Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Caetano, Ana L. [Departamento de Biologia and CESAM (Centro de Estudos do Ambiente e do Mar), Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Haller, Andreas [ECT Oekotoxikologie GmbH, Böttgerstraße 2–14, D-65439 Flörsheim a. M. (Germany); Gonçalves, Fernando [Departamento de Biologia and CESAM (Centro de Estudos do Ambiente e do Mar), Universidade de Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro (Portugal); Pereira, Ruth [Faculdade de Ciências da Universidade do Porto, Rua do Campo Alegre, s/n, 4169-007 Porto (Portugal); Interdisciplinary Centre of Marine and Environmental Research (CIIMAR/CIMAR), Universidade do Porto, Rua dos Bragas 289, P 4050-123 Porto (Portugal); Römbke, Jörg [ECT Oekotoxikologie GmbH, Böttgerstraße 2–14, D-65439 Flörsheim a. M. (Germany)

    2014-06-01

    Highlights: • The assay gave rapid and feasible discrimination of toxic soils to A. globiformis. • Sensitive and low variability response to soils from different regions. • Soil properties may interfere with metal toxicity and fluorescence measurements. • Proposal of a toxicity threshold for the contact assay regarding soils. • A. globiformis assay should be included in the Tier I of risk assessment frameworks. - Abstract: This study used the Arthrobacter globiformis solid-contact test for assessing the quality of soils collected in areas subjected to past and present mine activities in Europe (uranium mine, Portugal) and North Africa (phosphogypsum pile, Tunisia; iron mine, Morocco). As to discriminate the influence of soils natural variability from the effect of contaminants, toxicity thresholds were derived for this test, based on the dataset of each study area. Furthermore, the test sensitivity and variability was also evaluated. As a result, soils that inhibited A. globiformis dehydrogenase activity above 45% or 50% relatively to the control, were considered to be toxic. Despite the soil metal content determined, the properties of soils seemed to influence dehydrogenase activity. Overall, the contact test provided a coherent outcome comparing to other more time-consuming and effort-demanding ecotoxicological assays. Our results strengthened the feasibility and ecological relevance of this assay, which variability was quite reduced hence suggesting its potential integration within the test battery of tier 1 of soil risk assessment schemes.

  15. Toxicity screening of soils from different mine areas—A contribution to track the sensitivity and variability of Arthrobacter globiformis assay

    International Nuclear Information System (INIS)

    Marques, Catarina R.; Caetano, Ana L.; Haller, Andreas; Gonçalves, Fernando; Pereira, Ruth; Römbke, Jörg

    2014-01-01

    Highlights: • The assay gave rapid and feasible discrimination of toxic soils to A. globiformis. • Sensitive and low variability response to soils from different regions. • Soil properties may interfere with metal toxicity and fluorescence measurements. • Proposal of a toxicity threshold for the contact assay regarding soils. • A. globiformis assay should be included in the Tier I of risk assessment frameworks. - Abstract: This study used the Arthrobacter globiformis solid-contact test for assessing the quality of soils collected in areas subjected to past and present mine activities in Europe (uranium mine, Portugal) and North Africa (phosphogypsum pile, Tunisia; iron mine, Morocco). As to discriminate the influence of soils natural variability from the effect of contaminants, toxicity thresholds were derived for this test, based on the dataset of each study area. Furthermore, the test sensitivity and variability was also evaluated. As a result, soils that inhibited A. globiformis dehydrogenase activity above 45% or 50% relatively to the control, were considered to be toxic. Despite the soil metal content determined, the properties of soils seemed to influence dehydrogenase activity. Overall, the contact test provided a coherent outcome comparing to other more time-consuming and effort-demanding ecotoxicological assays. Our results strengthened the feasibility and ecological relevance of this assay, which variability was quite reduced hence suggesting its potential integration within the test battery of tier 1 of soil risk assessment schemes

  16. The water budget of heterogeneous areas : impact of soil and rainfall variability

    NARCIS (Netherlands)

    Kim, C.P.

    1995-01-01

    In this thesis the heterogeneity of the soil water budget components is investigated. Heterogeneity of soil hydraulic properties and rainfall rate are taken into account by using stochastic methods. The importance of lateral groundwater flow in causing heterogeneity of the water budget

  17. Heavy metal accumulation in earthworms exposed to spatially variable soil contamination

    NARCIS (Netherlands)

    Marinussen, M.

    1997-01-01

    Ecotoxicity of contaminated soil is commonly tested in standard laboratory tests. Extrapolation of these data to the field scale is complicated due to considerable differences between conditions in laboratory tests and conditions in situ in contaminated soils. In this

  18. On the remote measurement of evaporation rates from bare wet soil under variable cloud cover

    Science.gov (United States)

    Auer, S.

    1976-01-01

    Evaporation rates from a natural wet soil surface are calculated from an energy balance equation at 0.1-hour intervals. A procedure is developed for calculating the heat flux through the soil surface from a harmonic analysis of the surface temperature curve. The evaporation integrated over an entire 24-hour period is compared with daily evaporation rates obtained from published models.

  19. Effects of annual and interannual environmental variability on soil fungi associated with an old-growth, temperate hardwood forest.

    Science.gov (United States)

    Burke, David J

    2015-06-01

    Seasonal and interannual variability in temperature, precipitation and chemical resources may regulate fungal community structure in forests but the effect of such variability is still poorly understood. In this study, I examined changes in fungal communities over two years and how these changes were correlated to natural variation in soil conditions. Soil cores were collected every month for three years from permanent plots established in an old-growth hardwood forest, and molecular methods were used to detect fungal species. Species richness and diversity were not consistent between years with richness and diversity significantly affected by season in one year but significantly affected by depth in the other year. These differences were associated with variation in late winter snow cover. Fungal communities significantly varied by plot location, season and depth and differences were consistent between years but fungal species within the community were not consistent in their seasonality or in their preference for certain soil depths. Some fungal species, however, were found to be consistently correlated with soil chemistry across sampled years. These results suggest that fungal community changes reflect the behavior of the individual species within the community pool and how those species respond to local resource availability. © FEMS 2015. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  20. Impact of Hydrologic and Micro-topographic Variabilities on Spatial Distribution of Mean Soil-Nitrogen Age

    Science.gov (United States)

    Woo, D.; Kumar, P.

    2015-12-01

    Excess reactive nitrogen in soils of intensively managed agricultural fields causes adverse environmental impact, and continues to remain a global concern. Many novel strategies have been developed to provide better management practices and, yet, the problem remains unresolved. The objective of this study is to develop a 3-dimensional model to characterize the spatially distributed ``age" of soil-nitrogen (nitrate and ammonia-ammonium) across a watershed. We use the general theory of age, which provides an assessment of the elapsed time since nitrogen is introduced into the soil system. Micro-topographic variability incorporates heterogeneity of nutrient transformations and transport associated with topographic depressions that form temporary ponds and produce prolonged periods of anoxic conditions, and roadside agricultural ditches that support rapid surface movement. This modeling effort utilizes 1-m Light Detection and Ranging (LiDAR) data. We find a significant correlation between hydrologic variability and mean nitrate age that enables assessment of preferential flow paths of nitrate leaching. The estimation of the mean nitrogen age can thus serve as a tool to disentangle complex nitrogen dynamics by providing the analysis of the time scales of soil-nitrogen transformation and transport processes without introducing additional parameters.

  1. Responses of plant available water and forest productivity to variably layered coarse textured soils

    Science.gov (United States)

    Huang, Mingbin; Barbour, Lee; Elshorbagy, Amin; Si, Bing; Zettl, Julie

    2010-05-01

    Reforestation is a primary end use for reconstructed soils following oil sands mining in northern Alberta, Canada. Limited soil water conditions strongly restrict plant growth. Previous research has shown that layering of sandy soils can produce enhanced water availability for plant growth; however, the effect of gradation on these enhancements is not well defined. The objective of this study was to evaluate the effect of soil texture (gradation and layering) on plant available water and consequently on forest productivity for reclaimed coarse textured soils. A previously validated system dynamics (SD) model of soil moisture dynamics was coupled with ecophysiological and biogeochemical processes model, Biome-BGC-SD, to simulate forest dynamics for different soil profiles. These profiles included contrasting 50 cm textural layers of finer sand overlying coarser sand in which the sand layers had either a well graded or uniform soil texture. These profiles were compared to uniform profiles of the same sands. Three tree species of jack pine (Pinus banksiana Lamb.), white spruce (Picea glauce Voss.), and trembling aspen (Populus tremuloides Michx.) were simulated using a 50 year climatic data base from northern Alberta. Available water holding capacity (AWHC) was used to identify soil moisture regime, and leaf area index (LAI) and net primary production (NPP) were used as indices of forest productivity. Published physiological parameters were used in the Biome-BGC-SD model. Relative productivity was assessed by comparing model predictions to the measured above-ground biomass dynamics for the three tree species, and was then used to study the responses of forest leaf area index and potential productivity to AWHC on different soil profiles. Simulated results indicated soil layering could significantly increase AWHC in the 1-m profile for coarse textured soils. This enhanced AWHC could result in an increase in forest LAI and NPP. The increased extent varied with soil

  2. Maxwell's Law Based Models for Liquid and Gas Phase Diffusivities in Variably-Saturated Soil

    DEFF Research Database (Denmark)

    Mamamoto, Shoichiro; Møldrup, Per; Kawamoto, Ken

    2012-01-01

    -s,D-l). Different percolation threshold terms adopted from recent studies for gas (D-s,D-g) and solute (D-s,D-l) diffusion were applied. For gas diffusion, epsilon(th) was a function of bulk density (total porosity), while for solute diffusion theta(th) was best described by volumetric content of finer soil...... particles (clay and organic matter), FINESvol. The resulting LIquid and GAs diffusivity and tortuosity (LIGA) models were tested against D-s,D-g and D-s,D-l data for differently-textured soils and performed well against the measured data across soil types. A sensitivity analysis using the new Maxwell's Law...... based LIGA models implied that the liquid phase but not the gaseous-phase tortuosity was controlled by soil type. The analyses also suggested very different pathways and fluid-phase connectivity for gas and solute diffusion in unsaturated soil...

  3. Functional interpretation of representative soil spatial-temporal variability at the Central region of European territory of Russia

    Science.gov (United States)

    Vasenev, I.

    2012-04-01

    The essential spatial and temporal variability is mutual feature for most natural and man-changed soils at the Central region of European territory of Russia. The original spatial heterogeneity of forest and forest-steppe soils has been further complicated by a specific land-use history and different-direction soil successions due to environmental changes and human impacts. For demand-driven land-use planning and decision making the quantitative analysis, modeling and functional-ecological interpretation of representative soil cover patterns spatial variability is an important and challenging task that receives increasing attention from scientific society, private companies, governmental and environmental bodies. On basis of long-term different-scale soil mapping, key plot investigation, land quality and land-use evaluation, soil forming and degradation processes modeling, functional-ecological typology of the zonal set of elementary soil cover patterns (ESCP) has been done in representative natural and man transformed ecosystems of the forest, forest-steppe and steppe zones at the Central region of European territory of Russia (ETR). The validation and ranging of the limiting factors of functional quality and ecological state have been made for dominating and most dynamical components of ESCP regional-typological forms - with application of local GIS, traditional regression kriging and correlation tree models. Development, zonal-regional differentiation and verification of the basic set of criteria and algorithms for logically formalized distinguishing of the most "stable" & "hot" areas in soil cover patterns make it possible for quantitative assessment of dominating in them elementary landscape, soil-forming and degradation processes. The received data essentially expand known ranges of the soil forming processes (SFP) rate «in situ». In case of mature forests mutual for them the windthrow impacts and lateral processes make SFPs more active and complex both in

  4. Variability of Soil Strength Parameters and its Effect on the Slope Stability of the Želazny Most Tailing Dam

    OpenAIRE

    Stella A. Arnaouti; Demos C. Angelides; Theodoros N. Chatzigogos; Witold M. Pytel

    2012-01-01

    The Želazny Most tailing pond is one of the largest facilities worldwide for waste disposal from the copper mines located in South-West Poland. A potential failure of the dam would allow more than 10 million cubic meters of contaminated slurry to flow to the valley, causing immense environmental problems to the surrounding area. Thus, the determination of the strength properties of the dam's soils and their variability is of utmost importance. An extensive site investigat...

  5. Geochemical mapping study of Panjang island

    International Nuclear Information System (INIS)

    Sutisna; Sumardjo

    2010-01-01

    Impact of industrial and regional development are not only related to an improvement of socio-economic, but also to an environmental conservation and sustainable. This impact could be observed on a change of geochemical mapping before and after an operational of the industry. In the relation with a regional development and resources utilization, the geochemical mapping have been done in the aim to know a resources and an elemental distribution at Panjang island. In this research, ko-Instrumental Neutron Activation Analysis (k_0-INAA) have been applied in an elemental quantification on the geochemical mapping. Pencuplikan of geochemical sample have been carried out by using a grid systematic method with a sample density of about 10 sample per square kilometre involved 85 pencuplikan point. The geochemical sample of sediment and soil have been provided as a dry weight of 100 mesh. Internal quality control have done by using a number of Standard Reference Materials obtained from US. Geological Survey. Fifteen elements of Sc, Co, In, Rb, Mo, Ba, Ce, Nd, Eu, La, Yb, Th, U, lr and Hf contained in standard materials have been evaluated. The analysis result show that a relative standard deviation less than 11 %, except for Mo (13 %) and lr (26 %). Fourteen elements of Al, Br, Ca, Co, Eu, Fe, La, U, Na, Ce, Mn, As, Sc and Th have been mapped and presented in this paper. The major elements of Ca, Al and Fe, and minor elements of Mn, U and Sc are distributed at all region. The lanthanide elements of La, Ce and Eu have vary concentration and could be found at the middle to the north of the island. (author)

  6. Geochemical Processes During Managed Aquifer Recharge With Desalinated Seawater

    Science.gov (United States)

    Ganot, Y.; Holtzman, R.; Weisbrod, N.; Russak, A.; Katz, Y.; Kurtzman, D.

    2018-02-01

    We study geochemical processes along the variably-saturated zone during managed aquifer recharge (MAR) with reverse-osmosis desalinated seawater (DSW). The DSW, post-treated at the desalination plant by calcite dissolution (remineralization) to meet the Israeli water quality standards, is recharged into the Israeli Coastal Aquifer through an infiltration pond. Water quality monitoring during two MAR events using suction cups and wells inside the pond indicates that cation exchange is the dominant subsurface reaction, driven by the high Ca2+ concentration in the post-treated DSW. Stable isotope analysis shows that the shallow groundwater composition is similar to the recharged DSW, except for enrichment of Mg2+, Na+, Ca2+, and HCO3-. A calibrated variably-saturated reactive transport model is used to predict the geochemical evolution during 50 years of MAR for two water quality scenarios: (i) post-treated DSW (current practice) and (ii) soft DSW (lacking the remineralization post-treatment process). The latter scenario was aimed to test soil-aquifer-treatment (SAT) as an alternative post-treatment technique. Both scenarios provide an enrichment of ˜2.5 mg L-1 in Mg2+ due to cation exchange, compared to practically zero Mg2+ currently found in the Israeli DSW. Simulations of the alternative SAT scenario provide Ca2+ and HCO3- remineralization due to calcite dissolution at levels that meet the Israeli standard for DSW. The simulated calcite content reduction in the sediments below the infiltration pond after 50 years of MAR was low (<1%). Our findings suggest that remineralization using SAT for DSW is a potentially sustainable practice at MAR sites overlying calcareous sandy aquifers.

  7. Variable response of three Trifolium repens ecotypes to soil flooding by seawater.

    Science.gov (United States)

    White, Anissia C; Colmer, Timothy D; Cawthray, Greg R; Hanley, Mick E

    2014-08-01

    Despite concerns about the impact of rising sea levels and storm surge events on coastal ecosystems, there is remarkably little information on the response of terrestrial coastal plant species to seawater inundation. The aim of this study was to elucidate responses of a glycophyte (white clover, Trifolium repens) to short-duration soil flooding by seawater and recovery following leaching of salts. Using plants cultivated from parent ecotypes collected from a natural soil salinity gradient, the impact of short-duration seawater soil flooding (8 or 24 h) on short-term changes in leaf salt ion and organic solute concentrations was examined, together with longer term impacts on plant growth (stolon elongation) and flowering. There was substantial Cl(-) and Na(+) accumulation in leaves, especially for plants subjected to 24 h soil flooding with seawater, but no consistent variation linked to parent plant provenance. Proline and sucrose concentrations also increased in plants following seawater flooding of the soil. Plant growth and flowering were reduced by longer soil immersion times (seawater flooding followed by drainage and freshwater inputs), but plants originating from more saline soil responded less negatively than those from lower salinity soil. The accumulation of proline and sucrose indicates a potential for solute accumulation as a response to the osmotic imbalance caused by salt ions, while variation in growth and flowering responses between ecotypes points to a natural adaptive capacity for tolerance of short-duration seawater soil flooding in T. repens. Consequently, it is suggested that selection for tolerant ecotypes is possible should the predicted increase in frequency of storm surge flooding events occur. © The Author 2014. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  8. Hot regions of labile and stable soil organic carbon in Germany - Spatial variability and driving factors

    Science.gov (United States)

    Vos, Cora; Jaconi, Angélica; Jacobs, Anna; Don, Axel

    2018-06-01

    Atmospheric carbon dioxide levels can be mitigated by sequestering carbon in the soil. Sequestration can be facilitated by agricultural management, but its influence is not the same on all soil carbon pools, as labile pools with a high turnover may be accumulated much faster but are also more vulnerable to losses. The aims of this study were to (1) assess how soil organic carbon (SOC) is distributed among SOC fractions on a national scale in Germany, (2) identify factors influencing this distribution and (3) identify regions with high vulnerability to SOC losses. The SOC content and proportion of two different SOC fractions were estimated for more than 2500 mineral topsoils (soil texture, bulk soil C / N ratio, total SOC content and pH. For some regions, the drivers were linked to the land-use history of the sites. Arable topsoils in central and southern Germany were found to contain the highest proportions and contents of stable SOC fractions, and therefore have the lowest vulnerability to SOC losses. North-western Germany contains an area of sandy soils with unusually high SOC contents and high proportions of light SOC fractions, which are commonly regarded as representing a labile carbon pool. This is true for the former peat soils in this area, which have already lost and are at high risk of losing high proportions of their SOC stocks. Those black sands can, however, also contain high amounts of stable SOC due to former heathland vegetation and need to be treated and discussed separately from non-black sand agricultural soils. Overall, it was estimated that, in large areas all over Germany, over 30 % of SOC is stored in easily mineralisable forms. Thus, SOC-conserving management of arable soils in these regions is of great importance.

  9. Vegetation-induced spatial variability of soil redox properties in wetlands

    Science.gov (United States)

    Szalai, Zoltán; Jakab, Gergely; Kiss, Klaudia; Ringer, Marianna; Balázs, Réka; Zacháry, Dóra; Horváth Szabó, Kata; Perényi, Katalin

    2016-04-01

    Vegetation induced land patches may result spatial pattern of on soil Eh and pH. These spatial pattern are mainly emerged by differences of aeration and exudation of assimilates. Present paper focuses on vertical extent and temporal dynamics of these patterns in wetlands. Two study sites were selected: 1. a plain wetland on calcareous sandy parent material (Ceglédbercel, Danube-Tisza Interfluve, Hungary); 2. headwater wetland with calcareous loamy parent material (Bátaapáti, Hungary). Two vegetation patches were studied in site 1: sedgy (dominated by Carex riparia) and reedy (dominated by Phragmites australis). Three patches were studied in site2: sedgy1 (dominated by C vulpina), sedgy 2 (C. riparia); nettle-horsetail (Urtica dioica and Equisetum arvense). Boundaries between patches were studied separately. Soil redox, pH and temperature studied by automated remote controlled instruments. Three digital sensors (Ponsell) were installed in each locations: 20cm and 40cm sensors represent the solum and 100 cm sensor monitors the subsoil). Groundwater wells were installed near to triplets for soil water sampling. Soil Eh, pH and temperature values were recorded in each 10 minutes. Soil water sampling for iron and DOC were carried out during saturated periods. Spatial pattern of soil Eh is clearly caused by vegetation. We measured significant differences between Eh values of the studied patches in the solum. We did not find this kinds horizontal differences in the subsoil. Boundaries of the patches usually had more reductive soil environment than the core areas. We have found temporal dynamics of the spatial redox pattern. Differences were not so well expressed during wintertime. These spatial patterns had influence on the DOC and iron content of porewater, as well. Highest temporal dynamics of soil redox properties and porewater iron could be found in the boundaries. These observations refer to importance patchiness of vegetation on soil chemical properties in

  10. State-space approach to evaluate spatial variability of field measured soil water status along a line transect in a volcanic-vesuvian soil

    Directory of Open Access Journals (Sweden)

    A. Comegna

    2010-12-01

    Full Text Available Unsaturated hydraulic properties and their spatial variability today are analyzed in order to use properly mathematical models developed to simulate flow of the water and solute movement at the field-scale soils. Many studies have shown that observations of soil hydraulic properties should not be considered purely random, given that they possess a structure which may be described by means of stochastic processes. The techniques used for analyzing such a structure have essentially been based either on the theory of regionalized variables or to a lesser extent, on the analysis of time series. This work attempts to use the time-series approach mentioned above by means of a study of pressure head h and water content θ which characterize soil water status, in the space-time domain. The data of the analyses were recorded in the open field during a controlled drainage process, evaporation being prevented, along a 50 m transect in a volcanic Vesuvian soil. The isotropic hypothesis is empirical proved and then the autocorrelation ACF and the partial autocorrelation functions PACF were used to identify and estimate the ARMA(1,1 statistical model for the analyzed series and the AR(1 for the extracted signal. Relations with a state-space model are investigated, and a bivariate AR(1 model fitted. The simultaneous relations between θ and h are considered and estimated. The results are of value for sampling strategies and they should incite to a larger use of time and space series analysis.

  11. Soil Physical and Environmental Conditions Controlling Patterned-Ground Variability at a Continuous Permafrost Site, Svalbard

    DEFF Research Database (Denmark)

    Watanabe, Tatsuya; Matsuoka, Norikazu; Christiansen, Hanne Hvidtfeldt

    2017-01-01

    properties and principal component analysis indicate that the distribution of patterned ground depends primarily on soil texture, soil moisture and the winter ground thermal regime associated with snow cover. Mudboils and composite patterns (mudboils surrounded by small polygons) occupy well-drained areas...... composed of clay-rich aeolian sediments. Compared to mudboils, composite patterns show a sharper contrast in soil texture between barren centres and vegetated rims. Hummocks filled with organic materials develop on poorly drained lowlands associated with a shallow water table. Ice-wedge polygons...

  12. Predictive geochemical mapping using environmental correlation

    International Nuclear Information System (INIS)

    Wilford, John; Caritat, Patrice de; Bui, Elisabeth

    2016-01-01

    The distribution of chemical elements at and near the Earth's surface, the so-called critical zone, is complex and reflects the geochemistry and mineralogy of the original substrate modified by environmental factors that include physical, chemical and biological processes over time. Geochemical data typically is illustrated in the form of plan view maps or vertical cross-sections, where the composition of regolith, soil, bedrock or any other material is represented. These are primarily point observations that frequently are interpolated to produce rasters of element distributions. Here we propose the application of environmental or covariate regression modelling to predict and better understand the controls on major and trace element geochemistry within the regolith. Available environmental covariate datasets (raster or vector) representing factors influencing regolith or soil composition are intersected with the geochemical point data in a spatial statistical correlation model to develop a system of multiple linear correlations. The spatial resolution of the environmental covariates, which typically is much finer (e.g. ∼90 m pixel) than that of geochemical surveys (e.g. 1 sample per 10-10,000 km 2 ), carries over to the predictions. Therefore the derived predictive models of element concentrations take the form of continuous geochemical landscape representations that are potentially much more informative than geostatistical interpolations. Environmental correlation is applied to the Sir Samuel 1:250,000 scale map sheet in Western Australia to produce distribution models of individual elements describing the geochemical composition of the regolith and exposed bedrock. As an example we model the distribution of two elements – chromium and sodium. We show that the environmental correlation approach generates high resolution predictive maps that are statistically more accurate and effective than ordinary kriging and inverse distance weighting interpolation

  13. Geochemical modeling: a review

    International Nuclear Information System (INIS)

    Jenne, E.A.

    1981-06-01

    Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted

  14. Geochemical modeling: a review

    Energy Technology Data Exchange (ETDEWEB)

    Jenne, E.A.

    1981-06-01

    Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted.

  15. Spatiotemporal Variability and Covariability of Temperature, Precipitation, Soil Moisture, and Vegetation in North America for Regional Climate Model Applications

    Science.gov (United States)

    Castro, C. L.; Beltran-Przekurat, A. B.; Pielke, R. A.

    2007-05-01

    Previous work has established that the dominant modes of Pacific SSTs influence the summer climate of North America through large-scale forcing, and this effect is most pronounced during the early part of the season. It is hypothesized, then, that land surface influences become more dominant in the latter part of the season as remote teleconnection influences diminish. As a first step toward investigation of this hypothesis in a regional climate model (RCM) framework, the statistically signficant spatiotemporal patterns of variability and covariability in North American precipitation (specified by the standardized precipitation index, or SPI), soil moisture, and vegetation are determined for timescales from a month to six months. To specify these respective data we use: CPC gauge- derived precipitation (1950-2000), Variable Infiltration Capacity (VIC) Model and NOAH Model NLDAS soil moisture and temperature, and the Global Inventory Modeling and Mapping Studies Normalized Difference Vegetation Index (GIMMS-NDVI). The principal statistical tool used is multiple taper frequency singular value decomposition (MTM-SVD), and this is supplemented by wavelet analysis for specific areas of interest. The significant interannual variability in all of these data occur at a timescale of about 7 to 9 years and appears to be the integrated effect of remote SST forcing from the Pacific. Considering the entire year, the spatial pattern for precipitation resembles the typical ENSO winter signature. If the summer season is considered seperately, the out of phase relationship between precipitation anomalies in the central U.S. and core monsoon region is apparent. The largest soil moisture anomalies occur in the central U.S., since precipitation in this region has a consistent relationship to Pacific SSTs for the entire year. This helps to explain the approximately 20 year periodicity in drought conditions there. Unlike soil moisture, the largest anomalies in vegetation occur in the

  16. Capturing the Initiation and Spatial Variability of Runoff on Soils Affected by Wildfire

    Science.gov (United States)

    Martin, D. A.; Wickert, A. D.; Moody, J. A.

    2011-12-01

    Rainfall after wildfire often leads to intense runoff and erosion, since fire removes ground cover that impedes overland flow and water is unable to efficiently infiltrate into the fire-affected soils. In order to understand the relation between rainfall, infiltration, and runoff, we modified a camera to be triggered by a rain gage to take time-lapse photographs of the ground surface every 10 seconds until the rain stops. This camera allows us to observe directly the patterns of ground surface ponding, the initiation of overland flow, and erosion/deposition during single rainfall events. The camera was deployed on a hillslope (average slope = 23 degrees) that was severely burned by the 2010 Fourmile Canyon Fire near Boulder, Colorado. The camera's field of view is approximately 3 m2. We integrate the photographs with rainfall and overland flow measurements to determine thresholds for the initiation of overland flow and erosion. We have recorded the spatial variability of wetted patches of ground and the connection of these patches together to initiate overland flow. To date we have recorded images for rain storms with 30-minute maximum intensities ranging from 5 mm/h (our threshold to trigger continuous photographs) to 32 mm/h. In the near future we will update the camera's control system to 1) include a clock to enable time-lapse photographs at a lower frequency in addition to the event-triggered images, and 2) to add a radio to allow the camera to be triggered remotely. Radio communication will provide a means of starting the camera in response to non-local events, allowing us to capture images or video of flash flood surge fronts and debris flows, and to synchronize the operations of multiple cameras in the field. Schematics and instructions to build this camera station, which can be used to take either photos or video, are open-source licensed and are available online at http://instaar.colorado.edu/~wickert/atvis. It is our hope that this tool can be used by

  17. Modeling Air Permeability in Variably Saturated Soil from Two Natural Clay Gradients

    DEFF Research Database (Denmark)

    Chamindu, Deepagoda T K K; Arthur, Emmanuel; Møldrup, Per

    2013-01-01

    measurements from two Danish arable fields, each located on natural clay gradients, this study presents a pore tortuosity–disconnectivity analysis to characterize the soil–gas phase. The main objective of this study is to investigate the effect of soil–moisture condition, clay content, and other potential......Understanding soil–gas phase properties and processes is important for finding solutions to critical environmental problems such as greenhouse gas emissions and transport of gaseous-phase contaminants in soils. Soil–air permeability, ka (μm2), is the key parameter governing advective gas movement...... in soil and is controlled by soil physical characteristics representing soil texture and structure. Models predicting ka as a function of air-filled porosity (ɛ) often use a reference-point measurement, for example, ka,1000 at ɛ1000 (where the measurement is done at a suction of –1000 cm H2O). Using ka...

  18. Transport properties and pore-network structure in variably-saturated Sphagnum peat soil

    DEFF Research Database (Denmark)

    Hamamoto, Shoichiro; Dissanayaka, Shiromi Himalika; Kawamoto, K.

    2016-01-01

    Gas and water transport in peat soil are of increasing interest because of their potentially large environmental and climatic effects under different types of land use. In this research, the water retention curve (WRC), gas diffusion coefficient (Dg) and air and water permeabilities (ka and kw......) of layers in peat soil from two profiles were measured under different moisture conditions. A two-region Archie's Law (2RAL)-type model was applied successfully to the four properties; the reference point was taken at -9.8kPa of soil-water matric potential where volume shrinkage typically started to occur....... For WRC in the very decomposed peat soil, the 2RAL saturation exponents (n) obtained for both the wetter (nw) and drier regions (nd) were smaller than those for the less decomposed peat. For Dg, the saturation exponent in the wetter region was larger than that in the drier one for all layers, which...

  19. A probabilistic analysis of the dynamic response of monopile foundations: Soil variability and its consequences

    DEFF Research Database (Denmark)

    Damgaard, M.; Andersen, L.V.; Ibsen, L.B.

    2015-01-01

    The reliability of offshore wind turbines is highly influenced by the uncertainties related to the subsoil conditions. Traditionally, the evaluation of the dynamic structural behaviour is based on a computational model with deterministic soil properties. Using this approach, however, provides...... on a Monte Carlo method facilitating the derivation of the probability densities of the modal properties and the fatigue loading. The main conclusion of the presented work is that the dynamic structural behaviour of the wind turbine and its support structure is strongly affected by the stochastic soil......-analytical impedance functions of a monopile embedded in a stochastic linear viscoelastic soil layer, fully coupled aero-hydro-elastic simulations are conducted in the nonlinear multi-body code Hawc2. The probabilistic analysis accounts for the uncertainty of soil properties (e.g. damping and stiffness) and relies...

  20. Spatio-temporal effects of soil and bedrock variability on grapevine water status in hillslope vineyards.

    Science.gov (United States)

    Brillante, Luca; Bois, Benjamin; Mathieu, Olivier; Leveque, Jean

    2014-05-01

    Hillslope vineyards show various and complex water dynamics between soil and plants, and in order to gain further insight into this phenomenon, 8 grapevine plots were monitored during three vintages, from 2010 to 2013, on Corton Hill, Burgundy, France. Plots were distributed along a topolithosequence from 330 to 270 metres a.s.l. Grapevine water status was monitored weekly by surveying water potential, and, at the end of the season, by the use of the δ13C analysis of grape juice. Soil profile of each plot was described and analysed (soil texture, gravel content, organic carbon, total nitrogen, pH, CEC). Soil volumetric humidity was measured weekly, using TDR probes. A pedotransfer function was developed to transform Electrical Resistivity Imaging (ERI) into soil volume wetness and therefore to spatialise and observe variation in the Fraction of Transpirable Soil Water (FTSW). During the three years of monitoring, grapevines experienced great variation in water status, which ranged from low to considerable water deficit (as expressed by pre-dawn leaf water potential and δ13C analysis of grape juice). With ERI imaging, it was possible to observe differences in water absorption pattern by roots, in different soils, and at different depth. In addition, significant differences were observed in grapevine water status in relation to variations in the physical characteristics of the terroir along the hillslope (i.e. the geo-pedological context, the elevation etc.). Grapevine water behaviour and plant-soil water relationships on the hillslope of Corton Hill have been extensively characterised in this study by ultimate technologies, allowing to present this terroir as a very interesting example for future generalisation and modelling of the hillslope vineyard water dynamics.

  1. Assessment of soil hydrology variability of a new weighing lysimeter facility

    Science.gov (United States)

    Brown, S. E.; Wagner-Riddle, C.; Berg, A. A.

    2017-12-01

    Diversifying annual crop rotations is a strategy that mimics natural ecosystems and is postulated to increase agricultural resilience to climate change, soil quality and provision of soil ecosystem services. However, diverse cropping systems could increase soil mineral N levels and lead to greater leaching and/or N2O emissions; which raises the questions: (i) are diverse cropping systems actually beneficial for air and water quality? (ii) what are the trade-offs between soil, water, and air quality upon implementing a diverse cropping rotation? It can be difficult to fully evaluate the interactions between the two N-pollution pathways simultaneously in traditional field studies as drainage is largely unconstrained. Weighing lysimeters solve this issue by providing a closed system to measure N outputs via drainage and soil gas fluxes. A set of 18 weighting lysimeters were installed in Elora, Ontario, Canada in May 2016, to establish a long-term study of N-leaching and greenhouse gas emission from traditional and diverse cropping rotations for two different soil types. Each lysimeter is equipped with an automated chamber for continuous measurement of soil N2O and CO2 fluxes. A full characterization of variations of physical properties that may affect GHG emissions and N-leaching (e.g., soil temperature, moisture, drainage and evapotranspiration rates) amongst the lysimeters is required prior to application and assessment of the management treatments. Novel techniques such as wavelet analysis is required as standard statistical analyses are not applicable to the time series data. A full description of the lysimeters will be presented along with results of the characterization.

  2. SOIL VARIABILITY IN DIFFERENT LANDSCAPE POSITIONS IN THE PORTO ALEGRE BOTANICAL GARDEN, SOUTHERN BRAZIL

    OpenAIRE

    Silva,Luís Fernando da; Nascimento,Paulo César do; Inda,Alberto Vasconcellos; Silva,Edsleine Ribeiro

    2015-01-01

    ABSTRACTKnowledge of soil characteristics in areas where activities related to the environment are developed, such as Porto Alegre Botanical Garden (JB-PoA), is a fundamental condition for the sustainable use of this natural resource. The objective of this study was to characterize, classify and evaluate some issues about soil formation in Porto Alegre Botanical Garden, as well as relate their distribution on the landscape according to environmental characteristics. For the morphological desc...

  3. Effects of seasonal and well construction variables on soil vapor extraction pilot tests

    International Nuclear Information System (INIS)

    Campbell, R.; Hudon, N.; Bass, D.

    1995-01-01

    The selection and design of an effective soil vapor extraction system is dependent upon data generated from pilot testing. Therefore, it is critical to understand factors that may affect the testing prior to selecting or designing a system. In Sebago Lake Village, Maine, two adjacent gasoline stations experienced a release. Gasoline migrated through fine sand into the groundwater and discharged to a small stream. Soil vapor extraction was investigated as a remedial alternative to reduce volatile organic compounds in the unsaturated soil. Three soil vapor extraction pilot tests were performed at one of the sites and one test at the other site. The results of the testing varied. Data collected during a summer test indicated soil vapor extraction was less likely to work. The wells tested were installed using an excavator. An adequate surface seal was not present in any of the tested wells. An additional test was performed in the winter using wells installed by a drill rig. Winter test results indicated that soil vapor extraction could be effective. Another test was performed after a horizontal soil vapor extraction system with a surface seal was installed. The results of this testing indicated that soil vapor extraction was more effective than predicted by the earlier tests. Tests performed on the other property indicated that the horizontal wells were more effective than the vertical wells. Testing results were affected by the well installation method, well construction, proximity to manmade structures, and the season in which testing was performed. Understanding factors that affect the testing is critical in selecting and designing the system

  4. Application of cluster analysis to geochemical compositional data for identifying ore-related geochemical anomalies

    Science.gov (United States)

    Zhou, Shuguang; Zhou, Kefa; Wang, Jinlin; Yang, Genfang; Wang, Shanshan

    2017-12-01

    Cluster analysis is a well-known technique that is used to analyze various types of data. In this study, cluster analysis is applied to geochemical data that describe 1444 stream sediment samples collected in northwestern Xinjiang with a sample spacing of approximately 2 km. Three algorithms (the hierarchical, k-means, and fuzzy c-means algorithms) and six data transformation methods (the z-score standardization, ZST; the logarithmic transformation, LT; the additive log-ratio transformation, ALT; the centered log-ratio transformation, CLT; the isometric log-ratio transformation, ILT; and no transformation, NT) are compared in terms of their effects on the cluster analysis of the geochemical compositional data. The study shows that, on the one hand, the ZST does not affect the results of column- or variable-based (R-type) cluster analysis, whereas the other methods, including the LT, the ALT, and the CLT, have substantial effects on the results. On the other hand, the results of the row- or observation-based (Q-type) cluster analysis obtained from the geochemical data after applying NT and the ZST are relatively poor. However, we derive some improved results from the geochemical data after applying the CLT, the ILT, the LT, and the ALT. Moreover, the k-means and fuzzy c-means clustering algorithms are more reliable than the hierarchical algorithm when they are used to cluster the geochemical data. We apply cluster analysis to the geochemical data to explore for Au deposits within the study area, and we obtain a good correlation between the results retrieved by combining the CLT or the ILT with the k-means or fuzzy c-me