Synthesis and Characterization Studies of MIL-101

Directory of Open Access Journals (Sweden)

Emine Kaya EKİNCİ

2017-12-01

Full Text Available MIL-101 is a kind of Metal Organic Frameworks (MOFs, which have attracted much attention in the past decade due to its promising application in chemical industries. MIL-101 is also known as “Porous Chromium Terephthalate”. It has very high surface area and pore volume. MIL-101 exhibits exceptional stability against moisture and other chemicals and is composed of coordinately unsaturated Cr- sites with high concentration available for catalysis and adsorption. MIL-101 was synthesized by hydrothermal method and characterized by XRD, nitrogen adsorption and desorption analyses and SEM. XRD patterns show the presence of MIL-101’s crystal structure with high surface area (~2400 m2/g. Nitrogen adsorption-desorption analyzes showed that the material exhibited mesoporous material behavior.

Coordination polymer nanobamboos of {Fe(x)In(1-x)}-MIL-88B: induced formation of a virtual In-MIL-88B.

Science.gov (United States)

Park, Shin Ae; Lee, Hee Jung; Cho, Yea Jin; Choi, Sora; Oh, Moonhyun

2014-05-05

A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {Fex In1-x }-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {Fex In1-x }-MIL-88B (x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06 In0.94 }-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06 In0.94 }-MIL-88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06 In0.94 }-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In(3+) within the framework. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Highly efficient capture of iodine by Cu/MIL-101

Science.gov (United States)

Qi, Bingbing; Liu, Ying; Zheng, Tao; Gao, Qianhong; Yan, Xuewu; Jiao, Yan; Yang, Yi

2018-02-01

In order to improve the uptake capacity of MIL-101 for iodine, Cu nanoparticles doped MIL-101 were successfully synthesized through a facile method. The obtained Cu/MIL-101 was characterized by SEM, XRD, EDS, TEM, IR, TGA and BET to examine the chemical and thermal stabilities. The capture experiments for the adsorbents showed that the capture capacity of Cu/MIL-101 for volatile iodine is 342 wt%, which is higher than that of pure MIL-101. An I2 uptake of 342 wt% is the highest value reported among metal-organic frameworks. Furthermore, Cu/MIL-101 has a cycle ratio of 95% after three cycles and exhibits a better cyclicity than pure MIL-101. Meanwhile, Cu/MIL-101 shows an excellent reversible adsorption of iodine in solution.

MIL-53(Fe), MIL-101, and SBA-15 porous materials: potential platforms for drug delivery.

Science.gov (United States)

Gordon, Jeff; Kazemian, Hossein; Rohani, Sohrab

2015-02-01

Conventional drug administration suffers from several drawbacks, including a lack of specificity for diseased tissue, the necessity of large and frequent doses, and adverse side effects. Great effort is currently being devoted to developing nanoparticle-based therapeutics capable of prolonging drug administration and providing better control. Here we demonstrate the use of flexible microporous MIL-53(Fe) and mesoporous MIL-101 and SBA-15 as matrices for the adsorption and in vitro drug delivery of acetaminophen, progesterone, and stavudine. A drug loading of 20 wt.% was achieved for each of the nanomaterials using an incipient wetness impregnation procedure. BET, DSC, and XRPD analyses indicated that the entire loaded amount of each of the model drugs had successfully been incorporated within the mesoporous channels of both MIL-101 and SBA-15. DSC analysis evidenced that a portion of each of the model drugs had deposited onto the outer surface of MIL-53(Fe) particles; however, the portion of each drug that had incorporated within the microporous channels was slowly delivered in a diffusion-controlled process, which occurred over a period of up to six days for acetaminophen. These results demonstrate the unique ability of MIL-53(Fe) to adapt its porosity and optimize drug-matrix interactions. Owing to its larger pore diameters and weaker host-guest interactions, MIL-101 release times were shorter, yet still prolonged, as evidenced by the complete release of stavudine after five days. Complete release of each of the drugs from SBA-15 occurred very quickly as a result of rapid drug dissolution and diffusion out of the mesopores. Copyright © 2014 Elsevier B.V. All rights reserved.

33 CFR 110.120 - San Luis Obispo Bay, Calif.

Science.gov (United States)

2010-07-01

... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false San Luis Obispo Bay, Calif. 110... ANCHORAGES ANCHORAGE REGULATIONS Special Anchorage Areas § 110.120 San Luis Obispo Bay, Calif. (a) Area A-1. Area A-1 is the water area bounded by the San Luis Obispo County wharf, the shoreline, a line drawn...

Iron metal-organic frameworks MIL-88B and NH2-MIL-88B for the loading and delivery of the gasotransmitter carbon monoxide.

Science.gov (United States)

Ma, Mingyan; Noei, Heshmat; Mienert, Bernd; Niesel, Johanna; Bill, Eckhard; Muhler, Martin; Fischer, Roland A; Wang, Yuemin; Schatzschneider, Ulrich; Metzler-Nolte, Nils

2013-05-17

Crystals of MIL-88B-Fe and NH2-MIL-88B-Fe were prepared by a new rapid microwave-assisted solvothermal method. High-purity, spindle-shaped crystals of MIL-88B-Fe with a length of about 2 μm and a diameter of 1 μm and needle-shaped crystals of NH2-MIL-88B-Fe with a length of about 1.5 μm and a diameter of 300 nm were produced with uniform size and excellent crystallinity. The possibility to reduce the as-prepared frameworks and the chemical capture of carbon monoxide in these materials was studied by in situ ultrahigh vacuum Fourier-transform infrared (UHV-FTIR) spectroscopy and Mössbauer spectroscopy. CO binding occurs to unsaturated coordination sites (CUS). The release of CO from the as-prepared materials was studied by a myoglobin assay in physiological buffer. The release of CO from crystals of MIL-88B-Fe with t(1/2) = 38 min and from crystals of NH2-MIL-88B-Fe with t(1/2) = 76 min were found to be controlled by the degradation of the MIL materials under physiological conditions. These MIL-88B-Fe and NH2-MIL-88B-Fe materials show good biocompatibility and have the potential to be used in pharmacological and therapeutic applications as carriers and delivery vehicles for the gasotransmitter carbon monoxide. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Petits mils

International Development Research Centre (IDRC) Digital Library (Canada)

cinq fois moins d'eau que le riz ? Note d'analyse ... dont une teneur élevée en micronutriments et en fibres alimentaires et un indice glycémique faible. ... Malgré les qualités nutritionnelles supérieures et la résilience au climat des petits mils, ...

Feldspathic Meteorites MIL 090034 and 090070: Late Additions to the Lunar Crust

Science.gov (United States)

Nyquist, L. E.; Shirai, N.; Yamaguchi, A.; Shih, C.-Y.; Park, J.; Ebihara, M.

2016-01-01

Our studies of the Miller Range lunar meteorites MIL 090034, 090036, and 090070 show them to be a diverse suite of rocks from the lunar highlands hereafter referred to as MIL 34, MIL 36, and MIL 70, resp. MIL34 and MIL70, the focus of this work, are crystalline melt breccias. Plagioclase compositions in both peak sharply around An96-97. Mg numbers of olivine vary from 58-65 with a few higher values. MIL36 is a regolith breccia. MIL 34 and MIL 70 have some of the highest Al2O3 abundances of lunar highland meteorites, indicating that they have among the largest modal abundances of plagioclase for lunar meteorites. They have lower Sc and Cr abundances than nearly all lunar highland meteorites except Dho 081, Dho 489 and Dho 733. MIL34 and MIL70 also have similar cosmic ray exposure (CRE) ages of approximately 1-2 Ma indicating they are launch paired. (MIL36 has a larger CRE age approximately greater than 70 Ma). Park et al. found a variation in Ar-Ar ages among subsamples of MIL 34 and MIL70, but preferred ages of 3500+/-110 Ma for the "Dark" phase of MIL 34 anorthite and 3520+/-30 Ma for the "Light" phase of MIL70. Bouvier et al. reported a Pb-Pb age of 3894+/-39 Ma for a feldspathic clast of MIL 34 and a similar age for a melt lithology. Here we reexamine the Rb-Sr and Sm-Nd isotopic data, which show complexities qualitatively consistent with those of the Ar-Ar and Pb-Pb data. The Sm-Nd data in particular suggest that the feldspathic compositions of MIL 34 and MIL 70 formed during initial lunar geochemical differentiation, and REE modeling suggests a relatively late-stage formation.

40 CFR 81.176 - San Luis Intrastate Air Quality Control Region.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 17 2010-07-01 2010-07-01 false San Luis Intrastate Air Quality Control Region. 81.176 Section 81.176 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Quality Control Regions § 81.176 San Luis Intrastate Air Quality Control Region. The San Luis Intrastate...

Un peu de désordre n'est pas du tout désagréable Clara Gaspar se passionne pour son métier au CERN, sans jamais oublier son Portugal

CERN Multimedia

Imhof, Michel

2002-01-01

Clara Gaspar is passionately fond of her job at CERN and enjoys the enrichment of life being in an international community. She misses some things and will never forget Portugal but counts Geneva as her home (2 pagees)

Metal organic framework MIL-101(Cr) for dehydration reactions

Indian Academy of Sciences (India)

Porous chromium terephthalate MIL-101 (Cr-MIL-101) has been prepared by direct method under hydrothermal conditions and characterized using X-ray diffraction, N2 sorption, TGA and FT-IR. The nitrogen adsorption-desorption isotherm shows that the Cr-MIL-101 possesses BET specific surface area of 2563 m2/g.

Homens de letras e homens de leis ao serviço da monarquia portuguesa (séculos XII-XIII

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Armando Norte

2014-06-01

Full Text Available Ao longo da primeira dinastia, os letrados ao serviço da Coroa portuguesa desempenharam um papel decisivo e cada vez mais importante na afirmação do poder real. Homens de leis e homens de letras serviram à casa real como oficiais, representaram os reis portugueses em atos políticos e diplomáticos e exerceram um grande leque de funções na esfera da administração central - políticas, jurídicas, médicas, económicas, administrativas. A presença desses elementos ao lado dos monarcas fez-se sentir desde a fundação do reino, logo desde o reinado de D. Afonso Henriques, coincidindo o corolário deste processo de recrutamento com a chegada de D. Afonso III ao trono, numa política continuada, de forma firme, por D. Dinis. O conjunto de eruditos recenseados junto dos reis portugueses da época fundacional constitui, nessa medida, um interessante estudo de caso para compreender, em parte, em que consistia um círculo áulico, à luz dos valores do século XII e XIII.

Fatores associados ao baixo conhecimento sobre HIV/AIDS entre homens que fazem sexo com homens no Brasil

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Raquel Regina de Freitas Magalhães Gomes

2017-10-01

Full Text Available Este estudo transversal analisou os fatores de vulnerabilidade social, individual e programática associados ao baixo conhecimento em HIV/AIDS entre homens que fazem sexo com homens (HSH. A técnica amostral Respondent Driven Sampling (RDS foi utilizada em dez cidades brasileiras. Os escores de conhecimento em HIV/AIDS foram estimados pela Teoria de Resposta ao Item e categorizados em três níveis: alto, médio e baixo conhecimento. O modelo de regressão logística ordinal foi utilizado para a análise. Dentre os 3.746 HSH, encontrou-se 36,6%, 37,4% e 26% com alto, médio e baixo conhecimento, respectivamente. No modelo final, apresentaram associação com o baixo conhecimento: escolaridade ≤ 8 anos, cor da pele não branca, critério de classe econômica C e D-E, idade < 25 anos, ter somente um parceiro sexual e nunca ter feito o teste anti-HIV. É fundamental melhorar o nível de conhecimento sobre HIV/AIDS entre os jovens HSH, com condições socioeconômicas desfavoráveis. Intervenções focadas nos fatores de vulnerabilidade programática podem contribuir para a redução dos fatores individual e social.

Voice and Valency in San Luis Potosi Huasteco

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Munoz Ledo Yanez, Veronica

2014-01-01

This thesis presents an analysis of the system of transitivity, voice and valency alternations in Huasteco of San Luis Potosi (Mayan) within a functional-typological framework. The study is based on spoken discourse and elicited data collected in the municipalities of Aquismon and Tancanhuitz de Santos in the state of San Luis Potosi, Mexico. The…

Homens vítimas na intimidade: análise metodológica dos estudos de prevalência

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Andreia Machado

2014-12-01

Full Text Available A violência contra os homens na intimidade é um tema controverso e negligenciado. No entanto, são já vários os estudos que avançam que os homens podem ser vítimas na intimidade. Este artigo contempla uma análise metodológica dos estudos de prevalência acerca da violência contra os homens em relações heterossexuais. A violência contra o sexo masculino perpetrada pelo sexo feminino varia de 0.6% a 100%, dependendo do tipo de violência que abrange, do período temporal de referência, bem como do método e da amostra. Os estudos revelam que os homens são, em sua grande maioria, vítimas de violência moderada, sobretudo psicológica. Porém, as insuficiências metodológicas e o conhecimento diminuto em domínios específicos da vitimação íntima contra os homens restringem as conclusões que podem ser extraídas. Importa que as investigações futuras adotem uma abordagem mais inclusiva de ambos os sexos.

33 CFR 80.1130 - San Luis Obispo Bay, CA.

Science.gov (United States)

2010-07-01

... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false San Luis Obispo Bay, CA. 80.1130 Section 80.1130 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Coast § 80.1130 San Luis Obispo Bay, CA. A line drawn from...

Synergy of mIL-21 and mIL-15 in enhancing DNA vaccine efficacy against acute and chronic Toxoplasma gondii infection in mice.

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Li, Zhong-Yuan; Chen, Jia; Petersen, Eskild; Zhou, Dong-Hui; Huang, Si-Yang; Song, Hui-Qun; Zhu, Xing-Quan

2014-05-23

The synergistic protective efficacy of murine interleukin 21 (mIL-21) and mIL-15 administrated with DNA vaccine against acute and chronic Toxoplasma gondii infection in mice was investigated using T. gondii MIC8 (TgMIC8) as a model. We cloned mIL-21 and mIL-15 from splenic tissues of Kunming mice, and constructed eukaryotic plasmid pVAX/mIL-15, pVAX/mIL-21, and pVAX/mIL-21/mIL-15, respectively. After immunizing with pVAX/TgMIC8 in the presence or absence of these cytokines, immune responses were analyzed using lymphoproliferative assay, cytokine and serum antibody measurements, flow cytometric surface markers on lymphocytes and protection against acute and chronic T. gondii infection. Mice receiving pVAX/TgMIC8 alone developed a strong humoral responses and Th1 type cellular immune responses, and showed an increase of CD4+ and CD8+ T cells compared with all the controls. Adding pVAX/mIL-21 to pVAX/TgMIC8 compared to pVAX/TgMIC8 resulted in only a slight increase in humoral and cellular immune responses, and this immune response was lower than that induced by the pVAX/mIL-15 combined with pVAX/TgMIC8. Co-administration of pVAX/mIL-21/mIL-15 combined with pVAX/TgMIC8 elicited the strongest humoral and cellular immune responses among all the groups, leading to significantly increased survival time against acute infection and the significant reduction of tissue cysts, compared to all the controls. Synergy of mIL-21 and mIL-15 can facilitate specific humoral as well as cellular immune responses elicited by DNA vaccine against acute and chronic T. gondii infection in mice. Copyright © 2014 Elsevier Ltd. All rights reserved.

The flexibility of modified-linker MIL-53 materials.

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Munn, Alexis S; Pillai, Renjith S; Biswas, Shyam; Stock, Norbert; Maurin, Guillaume; Walton, Richard I

2016-03-14

The flexibility of eight aluminium hydroxo terephthalates [Al(OH)(BDC-X)]·n(guest) (BDC = 1,4-benzene-dicarboxylate; X = -H, -CH3, -Cl, -Br, -NH2, -NO2, -(OH)2, -CO2H) crystallising in the MIL-53-type structure was investigated upon thermal dehydration of as-made samples, superhydration and methanol adsorption/desorption using in situ powder X-ray diffraction (PXRD). Profile fitting was used to determine lattice parameters as a function of time and/or temperature to describe their structural evolution. It has thus been shown that while methanol vapour adsorption induces an opening of all the modified frameworks, except the -NH2 material, superhydration only leads to open structures for Al-MIL-53-NO2, -Br and -(OH)2. All the MIL-53 solids, except Al-MIL-53-(OH)2 are present in the open structures upon thermal dehydration. In addition to the exploration of the breathing behavior of this MIL-53 series, the issue of disorder in the distribution of the functional groups between the organic linkers was explored. As a typical illustration, density functional theory calculations were carried out on different structures of Al-MIL-53-Cl, in which the distribution of -Cl within two adjacent BDC linkers is varied. The results show that the most energetically stable configuration leads to the best agreement with the experimental PXRD pattern. This observation supports that the distribution of the selected linker substituent in the functionalised solid is governed by energetics and that there is a preference for an ordering of this arrangement.

Compact, Low-Overhead, MIL-STD-1553B Controller

Science.gov (United States)

Katz, Richard; Barto, Rod

2009-01-01

A compact and flexible controller has been developed to provide MIL-STD- 1553B Remote Terminal (RT) communications and supporting and related functions with minimal demand on the resources of the system in which the controller is to be installed. (MIL-STD-1553B is a military standard that encompasses a method of communication and electrical-interface requirements for digital electronic subsystems connected to a data bus. MIL-STD-1553B is commonly used in defense and space applications.) Many other MIL-STD-1553B RT controllers are complicated, and to enable them to function, it is necessary to provide software and to use such ancillary separate hardware devices as microprocessors and dual-port memories. The present controller functions without need for software and any ancillary hardware. In addition, it contains a flexible system interface and extensive support hardware while including on-chip error-checking and diagnostic support circuitry. This controller is implemented within part of a modern field-programmable gate array.

76 FR 6517 - San Luis & Rio Grande Railroad-Petition for a Declaratory Order

Science.gov (United States)

2011-02-04

... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. FD 35380] San Luis & Rio... petition filed by San Luis & Rio Grande Railroad (SLRG), the Board instituted a declaratory order... proposed operation of a truck-to-rail transload facility in Antonito, Colorado. See San Luis & Rio Grande R...

MEMS and mil/aero: technology push and market pull

Science.gov (United States)

Clifford, Thomas H.

2001-04-01

MEMS offers attractive solutions to high-density fluidics, inertial, optical, switching and other demanding military/aerospace (mil/aero) challenges. However, full acceptance must confront the realities of production-scale producibility, verifiability, testability, survivability, as well as long-term reliability. Data on these `..ilities' are crucial, and are central in funding and deployment decisions. Similarly, mil/aero users must highlight specific missions, environmental exposures, and procurement issues, as well as the quirks of its designers. These issues are particularly challenging in MEMS, because of the laws of physics and business economics, as well as the risks of deploying leading-edge technology into no-fail applications. This paper highlights mil/aero requirements, and suggests reliability/qualification protocols, to guide development effort and to reassure mil/aero users that MEMS labs are mindful of the necessary realities.

Fuzzy logic and information fusion to commemorate the 70th birthday of Professor Gaspar Mayor

CERN Document Server

Sastre, Joan

2016-01-01

This book offers a timely report on key theories and applications of soft-computing. Written in honour of Professor Gaspar Mayor on his 70th birthday, it primarily focuses on areas related to his research, including fuzzy binary operators, aggregation functions, multi-distances, and fuzzy consensus/decision models. It also discusses a number of interesting applications such as the implementation of fuzzy mathematical morphology based on Mayor-Torrens t-norms. Importantly, the different chapters, authored by leading experts, present novel results and offer new perspectives on different aspects of Mayor’s research. The book also includes an overview of evolutionary fuzzy systems, a topic that is not one of Mayor’s main areas of interest, and a final chapter written by the Spanish pioneer in fuzzy logic, Professor E. Trillas. Computer and decision scientists, knowledge engineers and mathematicians alike will find here an authoritative overview of key soft-computing concepts and techniques.

Reseña de Gaspar Aguilar, «La comedia segunda de Los agravios perdonados», ed. C. George Peale, Santa Barbara, University of California, Publications of «eHumanista», 2016, 128 pp., edición digital

Directory of Open Access Journals (Sweden)

Ariel Núñez Sepúlveda

2017-11-01

Full Text Available Reseña de Gaspar Aguilar, La comedia segunda de Los agravios perdonados, ed. C. George Peale, Santa Barbara, University of California, Publications of eHumanista, 2016, 128 pp., edición digital

Hydrothermal crystal growth and Vernier structures of the metal benzenedicarboxylates MIL-47 and MIL-53 containing guest molecules of benzenecarboxylic acid

International Nuclear Information System (INIS)

Wang, Xiqu; Jacobson, Allan J.

2016-01-01

The nanoporous frameworks VO(bdc), MIL-47, and M(OH)(bdc), MIL-53; bdc=1,4-benzenedicarboxylate, can absorb various guest species in their channels. As synthesized, the channels are filled with H 2 bdc molecules that have been reported to be disordered, except for [In(OH)bdc](H 2 bdc) 3/4 , 1, which has a inorganic-organic hybrid Vernier structure with the H 2 bdc molecules forming an ordered sublattice. Based on X-ray data from large single crystals grown by hydrothermal techniques, similar Vernier structures have been found for MIL-47, [VO(bdc)](H 2 bdc) 5/7 , 2, MIL-53Al, [Al(OH)(bdc)](H 2 bdc) 11/16 , 3, and MIL-53Ga, [Ga(OH)(bdc)](H 2 bdc) 12/17 , 4. The Vernier structures of 2–4 at room temperature were determined based on superstructure unit cells that index both host and guest sublattices: 2, space group P2 1 , a=23.903(2), b=17.191(2), c=25.722(2) Å, β=105.914(8)°; 3, P2 1 /n, a=105.224(4), b=12.2441(5), c=17.0143(6) Å, β=89.99(1)°; 4, P2 1 , a=114.562(5), b=12.1503(5), c=17.4275(7) Å, β=89.99(1)°. The number of guest H 2 bdc molecules per framework metal ion is determined by the ratio of the repeat distances of the two sublattices which depends on the size of the metal ion in the octahedral chain. The octahedral chains are parallel to [201] in 2, and to [100] in 3 and 4. Remarkably, all atoms in 3 and 4 show significant sinusoidal modulations transverse to the chain axis. - Graphical abstract: The sinusoidal modulation along the channel axis direction involving all atoms in the structure of [Al(OH)(bdc)](H 2 bdc) 11/16 . - Highlights: • Crystal growth of MIL-47, MIL-53Al, and MIL-53Ga. • The Vernier structures have corner-sharing MO6 octrahedral chains and chains of H2BDC molecules. • The stoichiometry is determined by the ratio of the host framework to the guest H2BDC column lengths. • A correlation is established between the stoichiometry and the radius of the metal ion. • All atoms in the Al and Ga compounds show sinusoidal

Sexo oral e HIV entre homens que fazem sexo com homens Oral sex and HIV among men who have sex with men

Directory of Open Access Journals (Sweden)

Sergio Luis Funari

2003-12-01

Full Text Available A transmissão sexual do Vírus da Imunodeficiência Humana (HIV representa um problema de saúde pública em todo o mundo, e homens que fazem sexo com homens encontram-se sob risco diferenciado para essa infecção. Ainda que existam evidências suficientes para se afirmar que o HIV pode ser transmitido via sexo oral, a percepção desse risco é ambígua, e relaciona-se de forma paradoxal com mudanças de atitude. Novos modelos de percepção de risco devem ser desenvolvidos em diversas áreas de conhecimento para se alcançar compreensão aprofundada desse fenômeno.Sexual transmission of the human immunodeficiency virus (HIV continues to pose a public health problem worldwide. Men who have sex with men are still at differential risk of infection. Although there is evidence to claim that HIV can be transmitted by oral sex, the perception of this risk is ambiguous and relates paradoxically to behavior change. New models of risk perception must be developed in various areas of knowledge to obtain a fuller understanding of this phenomenon.

Enfrentamentos experienciados por homens que vivem com HIV/Aids no ambiente de trabalho

Directory of Open Access Journals (Sweden)

Julyana Gomes de Freitas

2012-06-01

Full Text Available Objetivou-se apreender situações de enfrentamento experienciadas por homens que vivem com HIV/aids no ambiente de trabalho. Estudo qualitativo realizado em ambulatório especializado em Fortaleza-Ceará, de março a junho de 2010, com onze homens infectados pelo vírus. Utilizou-se entrevista semiestruturada, audiogravada, sendo os depoimentos categorizados mediante análise de conteúdo, cujas categorias foram: Afastamento do trabalho em virtude da infecção; Subterfúgios para omissão da doença; Desrespeito ao sigilo no ambiente de trabalho; Sofrimento associado ao medo da rejeição e do preconceito; Formas de enfrentamento após o diagnóstico da doença e a importância do trabalho para a realização pessoal. Concluiu-se que os homens infectados pelo HIV enfrentam situações contraproducentes no ambiente de trabalho, evidenciadas principalmente pelo temor da descoberta da infecção e pelo preconceito. Associadas ao enfrentamento, as ausências para o acompanhamento em saúde interferiram no desempenho do trabalho que implicariam no risco de perda do emprego.

Cidade dos Homens: perspectiva narrativa e relações de amizade

Directory of Open Access Journals (Sweden)

Inara de Amorim Rosas

2010-10-01

Full Text Available Este trabalho tem como objetivo empreender uma análise do discurso ficcional do seriado Cidade dos homens, com atenção para a questão da perspectiva narrativa (focalização, da categoria personagem e das relações entre texto e contexto. O estudo da focalização no seriado nos possibilita conhecer a qualidade do olhar dos dois garotos protagonistas frente às tentações do narcotráfico, em meio as relações comunitárias das quais participam, em relação ao mundo exterior , à comunidade e ante as relações de amizade que os liga desde a infância,o que veremos observando as relações entre o curta-metragem Palace II e alguns episódios de Cidade dos homens.

Hydrothermal crystal growth and Vernier structures of the metal benzenedicarboxylates MIL-47 and MIL-53 containing guest molecules of benzenecarboxylic acid

Energy Technology Data Exchange (ETDEWEB)

Wang, Xiqu; Jacobson, Allan J., E-mail: ajjacob@uh.edu

2016-04-15

The nanoporous frameworks VO(bdc), MIL-47, and M(OH)(bdc), MIL-53; bdc=1,4-benzenedicarboxylate, can absorb various guest species in their channels. As synthesized, the channels are filled with H{sub 2}bdc molecules that have been reported to be disordered, except for [In(OH)bdc](H{sub 2}bdc){sub 3/4}, 1, which has a inorganic-organic hybrid Vernier structure with the H{sub 2}bdc molecules forming an ordered sublattice. Based on X-ray data from large single crystals grown by hydrothermal techniques, similar Vernier structures have been found for MIL-47, [VO(bdc)](H{sub 2}bdc){sub 5/7}, 2, MIL-53Al, [Al(OH)(bdc)](H{sub 2}bdc){sub 11/16}, 3, and MIL-53Ga, [Ga(OH)(bdc)](H{sub 2}bdc){sub 12/17}, 4. The Vernier structures of 2–4 at room temperature were determined based on superstructure unit cells that index both host and guest sublattices: 2, space group P2{sub 1}, a=23.903(2), b=17.191(2), c=25.722(2) Å, β=105.914(8)°; 3, P2{sub 1}/n, a=105.224(4), b=12.2441(5), c=17.0143(6) Å, β=89.99(1)°; 4, P2{sub 1}, a=114.562(5), b=12.1503(5), c=17.4275(7) Å, β=89.99(1)°. The number of guest H{sub 2}bdc molecules per framework metal ion is determined by the ratio of the repeat distances of the two sublattices which depends on the size of the metal ion in the octahedral chain. The octahedral chains are parallel to [201] in 2, and to [100] in 3 and 4. Remarkably, all atoms in 3 and 4 show significant sinusoidal modulations transverse to the chain axis. - Graphical abstract: The sinusoidal modulation along the channel axis direction involving all atoms in the structure of [Al(OH)(bdc)](H{sub 2}bdc){sub 11/16}. - Highlights: • Crystal growth of MIL-47, MIL-53Al, and MIL-53Ga. • The Vernier structures have corner-sharing MO6 octrahedral chains and chains of H2BDC molecules. • The stoichiometry is determined by the ratio of the host framework to the guest H2BDC column lengths. • A correlation is established between the stoichiometry and the radius of the metal ion

Mulheres e homens: diferentes também na percepção das notas musicais?

Directory of Open Access Journals (Sweden)

Jandilson Avelino da Silva

Full Text Available O objetivo deste estudo foi avaliar a percepção das notas musicais RÉ, FÁ, e LÁ em adultos jovens. Participaram do estudo 20 homens e 20 mulheres de 18 a 29 anos, saudáveis, não músicos e não usuários de fármacos ou outras substâncias tóxicas. Realizou-se um teste de discriminação de notas musicais com escolha forçada entre duas alternativas, por meio do qual os participantes escolheram um estímulo previamente apresentado. Comparou-se a frequência de acertos na discriminação das notas musicais em relação ao sexo dos participantes. Encontraram-se diferenças estatisticamente significantes na nota musical Fá, sendo que os homens apresentaram maior quantidade de acertos que as mulheres. Esses resultados encontrados sugerem diferença na percepção das notas musicais para mulheres e homens.

Navy.mil - Photo Galleries

Science.gov (United States)

Personnel Command (NPC) Navy SAPR Navy EEO Inclusion And Diversity Navy Standard Integrated Personnel System (OPSEC) Navy Trademarks Military One Source USA.gov U.S. Office of Special Counsel Social Media Directory Links Navy Reserve Navy.mil Underway Navy Personnel Command (NPC) Navy SAPR Navy EEO Inclusion And

Adjetivo superlativo na fala de homens gays: uma discussão sociolinguística

OpenAIRE

Felix, Rafael de Almeida Arruda [UNESP

2016-01-01

Partindo da observação de que o uso do superlativo no português do Brasil, principalmente em formas com o sufixo -érrimo e -ésimo, poderia estar associado à fala de homens gays, esta pesquisa de mestrado propõe analisar a fala de homens gays através de entrevistas sociolinguísticas, a fim de verificar se o uso de superlativo poderia configurar uma característica real e/ou indiciária de um falar gay. Com vistas a alcançar esse objetivo, analisamos dados coletados de amostras de fala de 24 info...

75 FR 8735 - Endangered and Threatened Wildlife and Plants; Permit, San Luis Obispo County, CA

Science.gov (United States)

2010-02-25

...] Endangered and Threatened Wildlife and Plants; Permit, San Luis Obispo County, CA AGENCY: Fish and Wildlife... Luis Obispo County, California. We invite comments from the public on the application, which includes a... Luis Obispo County, California, that will meet Americans with Disabilities Act (ADA) accessibility...

Bivalent metal-based MIL-53 analogues: Synthesis, properties and application

International Nuclear Information System (INIS)

Liu, Yongxin; Liu, Dan; Wang, Cheng

2015-01-01

Trivalent metal-based MIL-53 (Al 3+ , Cr 3+ , Fe 3+ , In 3+ ) compounds are interesting metal–organic frameworks (MOFs) with breathing effect and are promising gas sorption materials. Replacing bridging μ 2 -OH group by neutral ligands such as pyridine N-oxide and its derivatives (PNOs), the trivalent metal-based MIL-53 analogous structures could be extended to bivalent metal systems. The introduction of PNOs and bivalent metal elements endows the frameworks with new structural features and physical and chemical properties. This minireview summarizes the recent development of bivalent metal-based MIL-53 analogues (Mn 2+ , Co 2+ , Ni 2+ ), typically, focusing on the synthetic strategies and potential applications based on our own works and literatures. We present the synthetic strategy to achieve structures evolution from single-ligand-walled to double-ligand-walled channel. Properties and application of these new materials in a wide range of potential areas are discussed including thermal stability, gas adsorption, magnetism and liquid-phase separation. Promising directions of this research field are also highlighted. - Graphical abstract: The recent development of bivalent metal-based MIL-53 analogues (Mn 2+ , Co 2+ , Ni 2+ ) on their synthetic strategies, properties and potential applications was reviewed. - Highlights: • Structure features of bivalent metal-based MIL-53 analogues are illustrated. • Important properties and application are presented. • Host–guest interactions are main impetus for liquid-phase separation. • Promising directions of bivalent metal-based MIL-53 analogues are highlighted

Study on adsorption refrigeration performance of MIL-101-isobutane working pair

International Nuclear Information System (INIS)

Ma, Liejun; Yang, Huan; Wu, Qi; Yin, Yu; Liu, Zongjian; Cui, Qun; Wang, Haiyan

2015-01-01

Rising concerns about pro-environment and energy conservation bring about the escalating interests in adsorption cooling systems using renewable energy. Adsorption chillers with common refrigerants (water, ethanol, methanol, etc.) face the problem that advanced technologies and intricate design considerations are required to maintain high vacuum. This paper aims at the parameters optimization of adsorption system being operated with the novel working pair, MIL-101-isobutane, under typical conditions of ice making and air-condition. Adsorption isotherms and dynamic of isobutane on MIL-101 are discussed simultaneously. When the hot water inlet temperature, cooling water temperature and desorption time are 95 °C, 30 °C and 30 min, respectively, the cooling capacity is 45.7 kJ/kg, which is 1.7 times as much as that of activated carbon–isobutane pair. Structural stability of MIL-101 subjected to 500 times adsorption/desorption cycles has been successfully verified by XRD (X-ray diffraction). - Highlights: • Adsorption isotherms and kinetic of isobutane on MIL-101 were studied. • A single bed adsorption chiller with MIL-101-isobutane pair was built. • System performed better than that using activated carbon–isobutane pair. • Stability of MIL-101 subjected to 500 ad/desorption cycles has been verified.

75 FR 59285 - Endangered and Threatened Wildlife and Plants; Permit, San Luis Obispo County, CA

Science.gov (United States)

2010-09-27

...] Endangered and Threatened Wildlife and Plants; Permit, San Luis Obispo County, CA AGENCY: U.S. Fish and... project in the community of Los Osos, San Luis Obispo County, California. We invite comments from the... community of Los Osos, San Luis Obispo County, California. The parcel is legally described as Assessor...

Mortalidade de motociclistas em acidentes de transporte no Distrito Federal, 1996 a 2007

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Marli de Mesquita Silva Montenegro

2011-06-01

Full Text Available OBJETIVO: Descrever características sociodemográficas e analisar a tendência temporal da mortalidade de motociclistas traumatizados em acidentes de transporte. MÉTODOS: Estudo de séries temporais com dados de 580 óbitos de motociclistas do Distrito Federal, de 1996 a 2007, obtidos do Sistema de Informações sobre Mortalidade. Foram calculadas as taxas de mortalidade específicas segundo idade e sexo, as taxas padronizadas (método direto e a razão de óbitos por frota (motocicletas. A média móvel centralizada da taxa padronizada de mortalidade de homens foi calculada para o período de três anos e um modelo de regressão linear foi construído para estudar a evolução temporal da mortalidade. Para calcular o incremento anual da taxa de mortalidade padronizada utilizou-se o método joinpoint (ponto de inflexão. RESULTADOS: A maior parte dos motociclistas mortos era do sexo masculino, (94,3%, pardo (71,0% e tinha entre 20 e 39 anos (73,8%. A taxa padronizada de mortalidade de motociclistas (homens residentes foi de 1,9 para 7,2 óbitos/100 mil homens entre 1996 e 2007. Entre 1998 e 2007, a razão de óbitos por frota passou de 2,0 óbitos/10 mil motocicletas para 10,0 óbitos/10 mil motocicletas entre os homens. Estimou-se incremento anual de 0,48 óbito/100 mil homens (IC95% 0,31;0,65; p < 0,001. O incremento percentual anual da taxa padronizada de mortalidade para o sexo masculino foi de 36,2% no período 1998-2007 (IC 95% 21,2%;53,2%; p < 0,05. CONCLUSÕES: A taxa de mortalidade de motociclistas decorrente de acidentes de transporte aumentou expressivamente. Esse aumento é explicado apenas em parte pelo aumento da frota de motocicletas. Características individuais dos condutores, bem como as condições locais do tráfego, necessitam ser investigadas para o planejamento de políticas preventivas.

Hydrogen storage behaviors of Ni-doped graphene Oxide/MIL-101 hybrid composites.

Science.gov (United States)

Lee, Seul-Yi; Park, Soo-Jin

2013-01-01

In this work, Ni-doped graphene oxide/MIL-101 hybrid composites (Ni--GO/MIL) were prepared to investigate their hydrogen storage behaviors. Ni--GO/MIL was synthesized by adding Ni--GO in situ during the synthesis of MIL-101 using a hydrothermal process, which was conducted by conventional convection heating with Cr(III) ion as a metal center and telephthalic acid as organic ligands. The crystalline structures and morphologies were measured by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The specific surface area and micropore volume were investigated by N2/77 K adsorption isotherms using the Brunauer-Emmett-Teller (BET) method and Dubinin-Radushkevic (D-R) equation, respectively. The hydrogen storage capacity was investigated by BEL-HP at 77 K and 1 bar. The obtained results show that Ni--GO/MIL presents new directions for achieving novel hybrid materials with higher hydrogen storage capacity.

Ontwikkeling en demonstratie van een geintegreerd bestrijdingssysteem voor de rode luis Myzus nicotianae

NARCIS (Netherlands)

Dijken, van M.J.

1998-01-01

De geïntegreerde plaagbestrijding van de paprikateelt onder glas, wordt sinds 1993 verstoord door de opkomst van de rode luis, Myzus nicotianae. Deze luis is namelijk resistent tegen het selectieve chemische correctiemiddel pirimicarb en een effectieve biologische bestrijding was onvoldoende

Adsorptive removal of dibenzothiophene from model fuels over one-pot synthesized PTA@MIL-101(Cr) hybrid material

Energy Technology Data Exchange (ETDEWEB)

Jia, Shao-Yi; Zhang, Yan-Fei [School of Chemical Engineering and Technology, Tianjin University, Tianjin (China); Liu, Yong [School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin (China); Qin, Feng-Xiang; Ren, Hai-Tao [School of Chemical Engineering and Technology, Tianjin University, Tianjin (China); Wu, Song-Hai, E-mail: songhaiwu@gmail.com [School of Chemical Engineering and Technology, Tianjin University, Tianjin (China)

2013-11-15

Highlights: • One-pot synthesized PTA@MIL-101(Cr) shows high capacity of benzothiophene. • PTA/MIL-101(Cr) obtained via post-modification performs poor in the adsorption. • PTA and MIL-101(Cr) exhibit synergetic effect on adsorption of benzothiophene. • In the presence of aromatics, PTA@MIL-101(Cr) and MIL-101(Cr) remain their capacity. • PTA-dispersed MOFs adsorb dibenzothiophene through acid–base interaction. -- Abstract: Hybrid nanomaterials comprising phosphotungstic acid (PTA) and MIL-101(Cr) were prepared through one-pot synthesis and post-modification methods and then were used as adsorbents of dibenzothiophene (DBT) from simulated diesel fuels. Samples obtained by different ways (encapsulation and impregnation) were characterized by nitrogen adsorption, transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrum (FT-IR) and series of adsorption experiments. The equilibrium adsorption capacities of PTA@MIL-101(Cr) illustrated that the direct introduction of PTA into MIL-101(Cr) during synthesis resulted in a 10.7% increase compared with MIL-101(Cr). However, porous hybrid adsorbent PTA/MIL-101(Cr) prepared via post-modification method exhibited lower adsorption capacity than virgin MIL-101(Cr). The theoretical maximum adsorption capacity (Q{sub 0}) of PTA@MIL-101(Cr) is 136.5 mg S/g adsorbent, 4.2 times of MIL-101(Cr). Even in competitive adsorption between aromatic compounds, which possess strong affinity with MOFs, and DBT, PTA@MIL-101(Cr) and MIL-101(Cr) remained their effectiveness in removal of DBT in the system. Based on these results, it can be presumed that MIL-101(Cr), modified properly, can be used as a promising adsorbent for eliminating aromatics and S-compounds in commercial fuels simultaneously.

Luis Carlos López

Directory of Open Access Journals (Sweden)

Rafael Maya

1979-04-01

Full Text Available Entre los poetasa del Centenario tuvo Luis Carlos López mucha popularidad en el extranjero, desde la publicación de su primer libro. Creo que su obra llamó la atención de filósofos como Unamuno y, si no estoy equivocado, Darío se refirió a ella en términos elogiosos. En Colombia ha sido encomiada hiperbólicamente por algunos, a tiemp que otros no le conceden mayor mérito.

Anti-UV Radiation Textiles Designed by Embracing with Nano-MIL (Ti, In)-Metal Organic Framework.

Science.gov (United States)

Emam, Hossam E; Abdelhameed, Reda M

2017-08-23

Protective textiles against harmful solar radiation are quite important materials for outdoor workers to secure their skin from several diseases. Current report focuses on production of anti-ultraviolet radiation (UVR) textiles by incorporation of nano-metal-organic frameworks (n-MOFs). Two different MIL-MOFs, namely, MIL-68(In)-NH 2 and MIL-125(Ti)-NH 2 , were immediately formed inside natural textiles (cotton and silk) matrix in nano size using quite simple and one-pot process. The formation of n-MIL-MOFs inside textiles were confirmed by using electron microscope and X-ray diffraction. Different size and morphology were seen depending on textile type reflecting the textiles' chemical composition role in the nature of prepared MIL-MOFs. For MIL-68(In)-NH 2 , particles with size distribution of 70.6-44.5 nm in cotton and 81.3-52.2 nm in silk were detected, while crystalline disc of MIL-125(Ti)-NH 2 was clearly seen inside textiles. The natural textiles exhibited full UVR blocking after modification, and the UV protection factor (UPF) was linearly proportional with MIL-MOFs and metal contents. Whatever metal type, direct incorporation of MIL-MOF contents greater than or equal to 10.4 g/kg was sufficient to attain excellent UV blocking property. Although 38.5-41.0% of MIL-MOFs was lost during five washings, the washed samples showed very good blocking rate (UPF = 26.7-36.2) supporting good laundering durability.

Late Bombardment of the Lunar Highlands Recorded in MIL 090034, MIL 090036 and MIL 090070 Lunar Meteorites

Science.gov (United States)

Park, J.; Nyquist, L. E.; Shih, C.-Y.; Herzog, G. F.; Yamaguchi, A.; Shirai, N.; Ebihara, M.; Lindsay, F. N.; Delaney, J.; Turrin, B.;

Fracture toughness of Ceramic-Fiber-Reinforced Metallic-Intermetallic-Laminate (CFR-MIL) composites

International Nuclear Information System (INIS)

Vecchio, Kenneth S.; Jiang, Fengchun

2016-01-01

Novel Ceramic-Fiber-Reinforced-Metal-Intermetallic-Laminate (CFR-MIL) composites, Ti–Al 3 Ti–Al 2 O 3 –Al, were synthesized by reactive foil sintering in air. Microstructure controlled material architectures were achieved with continuous Al 2 O 3 fibers oriented in 0° and 90° layers to form fully dense composites in which the volume fractions of all four component phases can be tailored. Bend fracture specimens were cut from the laminate plates in divider orientation, and bend tests were performed to study the fracture behavior of CFR-MIL composites under three-point and four-point bending loading conditions. The microstructures and fractured surfaces of the CFR-MIL composites were examined using optical microscopy and scanning electron microscopy to establish a correlation between the fracture toughness, fracture surface morphology and microstructures of CFR-MIL composites. The fracture and toughening mechanisms of the CFR-MIL composites are also addressed. The present experimental results indicate that the fracture toughness of CFR-MIL composites determined by three- and four-point bend loading configurations are quite similar, and increased significantly compared to MIL composites without ceramic fiber reinforcement. The interface cracking behavior is related to the volume fraction of the brittle Al 3 Ti phase and residual ductile Al, but the fracture toughness values appear to be insensitive to the ratio of these two phases. The toughness appears to be dominated by the ductility/strength of the Ti layers and the strength and crack bridging effect of the ceramic fibers.

Hombres: Doctor Luis Ángel Arango

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Boletín Cultural y Bibliográfico Banco de la República

1958-02-01

Full Text Available En el documento se realiza la nota de conmemoración  del fallecimiento del Doctor Luis Ángel Arango  Esta nota tiene como fin realizar un homenaje a tan reputado ciudadano colombiano y mienbro de la comunidad de funcionarios del Banco de la República.

Curation and Allocation of the New Antarctic Nakhlite, MIL03346

Science.gov (United States)

McBride, K. M.; Righter, K.; Satterwhite, C. E.; Schwarz, C.; Robinson, P.

2005-01-01

In January 2004, the ANSMET reconnaissance field team (Fig. 1) working in the Miller Range of the Transantarctic Mountains discovered a 715 g achondrite that was instantly recognized as unique. Named MIL03346, initial processing (NASA Johnson Space Center or JSC) and classification (Smithsonian Institution or SI) revealed this achondrite to be a nakhlite (Fig. 2). MIL03346 is the seventh nakhlite recognized in world collections [2], the third nakhlite returned from Antartica, and the first nakhlite in the US Antarctic collection (Table 1). The following is a summary of the steps taken in the processing and allocating of MIL 03346 and some comparisons to some other lunar and martian meteorites processed and allocated at JSC.

Magnetotelluric data collected to characterize aquifers in the San Luis Basin, New Mexico

Science.gov (United States)

Ailes, Chad E.; Rodriguez, Brian D.

2015-01-01

The U.S. Geological Survey is conducting a series of multidisciplinary studies of the San Luis Basin as part of the Geologic Framework of Rio Grande Basins project. Detailed geologic mapping, high-resolution airborne magnetic surveys, gravity surveys, magnetotelluric surveys, and hydrologic and lithologic data are being used to better understand the aquifers in the San Luis Basin. This report describes one north-south and two east-west regional magnetotelluric sounding profiles, acquired in June of 2010 and July and August of 2011, across the San Luis Basin in northern New Mexico. No interpretation of the data is included.

Application of Metal-Organic Framework Nano-MIL-100(Fe) for Sustainable Release of Doxycycline and Tetracycline.

Science.gov (United States)

Taherzade, Seyed Dariush; Soleimannejad, Janet; Tarlani, Aliakbar

2017-08-06

Nanostructures of MIL-100 were synthesized and used as a drug delivery platform for two members of the Tetracycline family. Doxycycline monohydrate (DOX) and Tetracycline hydrochloride (TC) were loaded separately on nano-MIL-100 (nanoparticles of drug@carrier were abbreviated as DOX@MIL-100 and TC@MIL-100). Characterizations were carried out using FT-IR, XRD, BET, DLS, and SEM. The FT-IR spectra revealed that the drugs were loaded into the framework of the carrier. The XRD patterns of DOX@MIL-100 and TC@MIL-100 indicated that no free DOX or TC were present. It could be concluded that the drugs are well dispersed into the pores of nano-MIL-100. The microporosity of the carrier was confirmed by BJH data. BET analysis showed a reduction in the free surface for both DOX@MIL-100 and TC@MIL-100. The release of TC and DOX was investigated, and it was revealed that MIL-100 mediated the drug solubility in water, which in turn resulted in a decrease in the release rate of TC (accelerating in DOX case) without lowering the total amount of released drug. After 48 h, 96 percent of the TC was sustain released, which is an unprecedented amount in comparison with other methods.

MIL-68 (In) nano-rods for the removal of Congo red dye from aqueous solution.

Science.gov (United States)

Jin, Li-Na; Qian, Xin-Ye; Wang, Jian-Guo; Aslan, Hüsnü; Dong, Mingdong

2015-09-01

MIL-68 (In) nano-rods were prepared by a facile solvothermal synthesis using NaOAc as modulator agent at 100°C for 30 min. The BET test showed that the specific surface area and pore volume of MIL-68 (In) nanorods were 1252 m(2) g(-1) and 0.80 cm(3) g(-1), respectively. The as-prepared MIL-68 (In) nanorods showed excellent adsorption capacity and rapid adsorption rate for removal of Congo red (CR) dye from water. The maximum adsorption capacity of MIL-68 (In) nanorods toward CR reached 1204 mg g(-1), much higher than MIL-68 (In) microrods and most of the previously reported adsorbents. The adsorption process of CR by MIL-68 (In) nano-rods was investigated and found to be obeying the Langmuir adsorption model in addition to pseudo-second-order rate equation. Moreover, the MIL-68 (In) nanorods showed an acceptable reusability after regeneration with ethanol. All information gives an indication that the as-prepared MIL-68 (In) nanorods show their potential as the adsorbent for highly efficient removal of CR in wastewater. Copyright © 2015 Elsevier Inc. All rights reserved.

Fatores associados com a qualidade de vida de homens idosos

Directory of Open Access Journals (Sweden)

Darlene Mara dos Santos Tavares

2013-06-01

Full Text Available Inquérito domiciliário, transversal e analítico que objetivou descrever as características sociodemográficas, de saúde e a qualidade de vida de homens idosos e verificar os fatores socioeconômicos e de saúde associados à qualidade de vida. Participaram 804 homens idosos. Os dados foram coletados pelos instrumentos: Older Americans Resources and Services(OARS, World Health Organization Quality of Life - Bref (WHOQOL-BREF e Health Organization Quality of Life Assessment for Older Adults(WHOQOL-OLD. Foram realizados análise descritiva, teste t-Student, correlação de Pearson e regressão linear múltipla (p <0,05. Predominaram idosos com 60├ 70 anos, casados, 4├ 8 anos de estudo e renda de um salário mínimo. Os menores escores de qualidade de vida foram no domínio físico e na faceta autonomia e estiveram associados a ausência de companheira e de escolaridade, baixa renda, maior número de morbidades e incapacidade funcional. A incapacidade funcional foi o que mais influenciou a qualidade de vida, excetuando-se o domínio físico e a faceta intimidade.

Ln3+ (Ln=Ce, Tb, Dy) and Hf doping of LuI3 powders – A material and spectroscopic study

International Nuclear Information System (INIS)

Wiatrowska, Aneta; Keur, Wilco; Ronda, Cees

2016-01-01

The moisture sensitivity of LuI 3 :Ce,Hf and luminescent properties of undoped LuI 3 and LuI 3 :M (M=Ce 3+ , Tb 3+ , Dy 3+ ) powders were investigated. The possibility of improving the air and moisture stability of LuI 3 :Ce by Hf doping was tested. It was proven that the Hf contribution to the LuI 3 :Ce stability is very limited and is insignificant to render LuI 3 :Ce scintillator powders suitable for applications. Photoluminescence results of LuI 3 without dopants added on purpose showed luminescence due to a plurality of rare-earth elements' impurities. Two types of self-trapped luminescence were found. Energy transfer between host lattice, self-trapped excitons and rare-earth ions was investigated.

Multifunctional polyoxometalates encapsulated in MIL-100(Fe): highly efficient photocatalysts for selective transformation under visible light.

Science.gov (United States)

Liang, Ruowen; Chen, Rui; Jing, Fenfen; Qin, Na; Wu, Ling

2015-11-07

H3PMo12O40 molecules have been successfully encapsulated in the cavities of MIL-100(Fe) via a facile hydrothermal method (denoted as HPMo@MIL-100(Fe)). A series of characterization has corroborated the insertion of H3PMo12O40 within the cavities of MIL-100(Fe). The resulting HPMo@MIL-100(Fe) nanocomposites have exhibited much higher photoactivity than the original-MIL-100(Fe) toward the photocatalytic selective oxidation of benzylic alcohols and the reduction of Cr(vi) under visible light irradiation (λ≥ 420 nm). The higher photoactivity of HPMo@MIL-100(Fe) can be attributed to the integrative effect of enhanced light absorption intensity and more efficient separation of photogenerated electron-hole pairs. The host porous structure of MIL-100(Fe) can achieve a uniform composition with H3PMo12O40, which is significantly important for producing highly reactive dispersed H3PMo12O40 molecules and enhancing the photocatalytic activity of HPMo@MIL-100(Fe) nanocomposites. And the immobilized H3PMo12O40 molecules are more convenient for recycling. Importantly, almost no Fe and Mo ions leach from the MIL-100(Fe) during the reaction, which verifies the photostability of the HPMo@MIL-100(Fe). In addition, possible photocatalytic redox reaction mechanisms have been investigated.

Synthesis of MIL-100(Fe at Low Temperature and Atmospheric Pressure

Directory of Open Access Journals (Sweden)

Jing Shi

2013-01-01

Full Text Available MIL-100(Fe, a mesoporous metal-organic framework (MOF, has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe is synthesized by a facile low-temperature (90% still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.

76 FR 41811 - Kellaway Proposed Low-Effect Habitat Conservation Plan for the Morro Shoulderband Snail, San Luis...

Science.gov (United States)

2011-07-15

...] Kellaway Proposed Low-Effect Habitat Conservation Plan for the Morro Shoulderband Snail, San Luis Obispo... species in the community of Los Osos, San Luis Obispo County, California. The applicants would implement a... Los Osos, San Luis Obispo County, California. The applicants are requesting a permit for take of Morro...

In memory of Luis Bernardo López

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Escuela de Estudios en Psicoanálisis y Cultura

2017-01-01

Full Text Available In this issue of the magazine From the Garden of Freud we want to remember what the presence of Luis Bernardo López meant in the spirit of this publication. The design and the initial model were the work of Santiago Mutis, as well as the idea of inviting a plastic artist for each number and the care of the graphic part for that exercise. However, Luis Bernardo also participated in his conception, and in his birth, in 2001, since it was his first director and editor, work that continued the following year to later take back the address of the number 7 and to advance the graphic edition of the Numbers 8 to 13. In this work I knew how to give the best shape to the project of a serial publication with which we dreamed since the year 2000.

75 FR 17430 - Hopper Mountain, Bitter Creek, and Blue Ridge National Wildlife Refuges, Kern, San Luis Obispo...

Science.gov (United States)

2010-04-06

...] Hopper Mountain, Bitter Creek, and Blue Ridge National Wildlife Refuges, Kern, San Luis Obispo, Tulare... Wildlife Refuges (NWRs) located in Kern, San Luis Obispo, Tulare, and Ventura counties of California. We... developing a CCP for Hopper Mountain, Bitter Creek, and Blue Ridge NWRs in Kern, San Luis Obispo, Tulare, and...

Geologic Map of the San Luis Quadrangle, Costilla County, Colorado

Science.gov (United States)

Machette, Michael N.; Thompson, Ren A.; Drenth, Benjamin J.

2008-01-01

The map area includes San Luis and the primarily rural surrounding area. San Luis, the county seat of Costilla County, is the oldest surviving settlement in Colorado (1851). West of the town are San Pedro and San Luis mesas (basalt-covered tablelands), which are horsts with the San Luis fault zone to the east and the southern Sangre de Cristo fault zone to the west. The map also includes the Sanchez graben (part of the larger Culebra graben), a deep structural basin that lies between the San Luis fault zone (on the west) and the central Sangre de Cristo fault zone (on the east). The oldest rocks exposed in the map area are the Pliocene to upper Oligocene basin-fill sediments of the Santa Fe Group, and Pliocene Servilleta Basalt, a regional series of 3.7?4.8 Ma old flood basalts. Landslide deposits and colluvium that rest on sediments of the Santa Fe Group cover the steep margins of the mesas. Rare exposures of the sediment are comprised of siltstones, sandstones, and minor fluvial conglomerates. Most of the low ground surrounding the mesas and in the graben is covered by surficial deposits of Quaternary age. The alluvial deposits are subdivided into three Pleistocene-age units and three Holocene-age units. The oldest Pleistocene gravel (unit Qao) forms extensive coalesced alluvial fan and piedmont surfaces, the largest of which is known as the Costilla Plain. This surface extends west from San Pedro Mesa to the Rio Grande. The primary geologic hazards in the map area are from earthquakes, landslides, and localized flooding. There are three major fault zones in the area (as discussed above), and they all show evidence for late Pleistocene to possible Holocene movement. The landslides may have seismogenic origins; that is, they may be stimulated by strong ground shaking during large earthquakes. Machette and Thompson based this geologic map entirely on new mapping, whereas Drenth supplied geophysical data and interpretations.

Adsorptive removal of dibenzothiophene from model fuels over one-pot synthesized PTA@MIL-101(Cr) hybrid material.

Science.gov (United States)

Jia, Shao-Yi; Zhang, Yan-Fei; Liu, Yong; Qin, Feng-Xiang; Ren, Hai-Tao; Wu, Song-Hai

2013-11-15

Hybrid nanomaterials comprising phosphotungstic acid (PTA) and MIL-101(Cr) were prepared through one-pot synthesis and post-modification methods and then were used as adsorbents of dibenzothiophene (DBT) from simulated diesel fuels. Samples obtained by different ways (encapsulation and impregnation) were characterized by nitrogen adsorption, transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectrum (FT-IR) and series of adsorption experiments. The equilibrium adsorption capacities of PTA@MIL-101(Cr) illustrated that the direct introduction of PTA into MIL-101(Cr) during synthesis resulted in a 10.7% increase compared with MIL-101(Cr). However, porous hybrid adsorbent PTA/MIL-101(Cr) prepared via post-modification method exhibited lower adsorption capacity than virgin MIL-101(Cr). The theoretical maximum adsorption capacity (Q0) of PTA@MIL-101(Cr) is 136.5mg S/g adsorbent, 4.2 times of MIL-101(Cr). Even in competitive adsorption between aromatic compounds, which possess strong affinity with MOFs, and DBT, PTA@MIL-101(Cr) and MIL-101(Cr) remained their effectiveness in removal of DBT in the system. Based on these results, it can be presumed that MIL-101(Cr), modified properly, can be used as a promising adsorbent for eliminating aromatics and S-compounds in commercial fuels simultaneously. Copyright © 2013 Elsevier B.V. All rights reserved.

Molecular simulations of a CO2/CO mixture in MIL-127

Science.gov (United States)

Chokbunpiam, Tatiya; Fritzsche, Siegfried; Parasuk, Vudhichai; Caro, Jürgen; Assabumrungrat, Suttichai

2018-03-01

Adsorption and diffusion of an equimolar feed mixture of CO2 and CO in MIL-127 at three different temperatures and pressures up to 12 bar were investigated by molecular simulations. The adsorption was simulated using Gibbs-Ensemble Monte Carlo (GEMC). The structure of the adsorbed phase and the diffusion in the MIL were investigated using Molecular Dynamics (MD) simulations. The adsorption selectivity of MIL-127 for CO2 over CO at 233 K was about 15. When combining adsorption and diffusion selectivities, a membrane selectivity of about 12 is predicted. For higher temperatures, both adsorption and diffusion selectivity are found to be smaller.

Optical spectroscopy and luminescence quenching of LuI3:Ce3+

International Nuclear Information System (INIS)

Birowosuto, M.D.; Dorenbos, P.; Haas, J.T.M. de; Eijk, C.W.E. van; Kraemer, K.W.; Guedel, H.U.

2006-01-01

Optical spectroscopy of LuI 3 doped with Ce 3+ using ultraviolet and visible light excitation is reported. LuI 3 host excitation and emission and 4f-5d excitation and emission of Ce 3+ are observed. An empirical model based on crystal field splitting was used to estimate the energy of the highest 4f-5d excitation band. The crystal field splitting and centroid shift were compared to those of LuCl 3 :Ce 3+ and LuBr 3 :Ce 3+ . Temperature dependence of X-ray excited luminescence spectra shows thermal quenching, whereas that of the decay curve of Ce 3+ emission excited at the lowest 5d band of Ce 3+ does not indicate the presence of quenching of Ce 3+ emission for temperature below 625K. The quenching in LuI 3 :Ce 3+ therefore occurs before the 5d Ce 3+ emission takes place

MIL-53(Fe) MOF-mediated catalytic chemiluminescence for sensitive detection of glucose.

Science.gov (United States)

Yi, Xueling; Dong, Wenfei; Zhang, Xiaodan; Xie, Jianxin; Huang, Yuming

2016-12-01

Various analytical applications of metal-organic frameworks (MOFs) have been rapidly developed in the past few years. However, the employment of MOFs as catalysts in chemiluminescence (CL) analysis is rare. Here, for the first time, we found that MIL-53(Fe) MOFs could significantly enhance the CL of luminol in the presence of H 2 O 2 in an alkaline medium. The CL intensity in the luminol-H 2 O 2 -MIL-53(Fe) system was about 20 times higher than that in the luminol-H 2 O 2 system. Moreover, the XRD pattern of MIL-53(Fe) after CL reaction was almost the same as that of the original MIL-53(Fe), confirming the catalytic role of MIL-53(Fe) in the luminol-H 2 O 2 -MIL-53(Fe) system. The possible mechanism behind the enhancing phenomenon was discussed based on the results from the CL spectra, FL probe experiments, and active oxygen species measurements. By coupling with the glucose oxidase-based catalytic oxidation reaction, a sensitive and selective CL method was developed for the detection of glucose. There is a linear relationship between the logarithm of CL intensity and the logarithm of glucose concentration in the range from 0.1 to 10 μM, and a detection limit of 0.05 μM (S/N = 3) is obtained. The proposed method has been applied to the determination of glucose in human serum samples with satisfactory results. Graphical abstract MIL-53(Fe) MOFs are found to greatly enhance the chemiluminescence emission of the luminol-H 2 O 2 system, and this finding resulted in a new chemiluminescence method for biosensing of glucose when coupled with the glucose oxidase.

Organic Linker Defines the Excited-State Decay of Photocatalytic MIL-125(Ti)-Type Materials.

Science.gov (United States)

Santaclara, Jara G; Nasalevich, Maxim A; Castellanos, Sonia; Evers, Wiel H; Spoor, Frank C M; Rock, Kamila; Siebbeles, Laurens D A; Kapteijn, Freek; Grozema, Ferdinand; Houtepen, Arjan; Gascon, Jorge; Hunger, Johannes; van der Veen, Monique A

2016-02-19

Recently, MIL-125(Ti) and NH2 -MIL-125(Ti), two titanium-based metal-organic frameworks, have attracted significant research attention in the field of photocatalysis for solar fuel generation. This work reveals that the differences between these structures are not only based on their light absorption range but also on the decay profile and topography of their excited states. In contrast to MIL-125(Ti), NH2 -MIL-125(Ti) shows markedly longer lifetimes of the charge-separated state, which improves photoconversion by the suppression of competing decay mechanisms. We used spectroelectrochemistry and ultrafast spectroscopy to demonstrate that upon photoexcitation in NH2 -MIL-125(Ti) the electron is located in the Ti-oxo clusters and the hole resides on the aminoterephthalate unit, specifically on the amino group. The results highlight the role of the amino group in NH2 -MIL-125(Ti), the electron donation of which extends the lifetime of the photoexcited state substantially. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CO2/CH4 Separation by a Mixed Matrix Membrane of Polymethylpentyne/MIL-53 Particles

Directory of Open Access Journals (Sweden)

Reza Abedini

2014-10-01

Full Text Available The effect of Materials Institute Lavoisier-53 (MIL-53 particles on gas transport properties of polymethylpentyne (PMP was investigated. MIL-53 was added to the polymer matrix with different loadings of 10, 20 and 30 wt%. The properties of MIL-53 and prepared membranes were analyzed through FTIR, SEM and TGA methods. The adsorption of CO2 and CH4 was conducted and analyzed accurately through Langmuir equation to investigate the gas transport properties of membranes. The results from TGA showed that degradation temperature (Td increases significantly with increasing MIL-53 loading. SEM images demonstrated that MIL-53 particles dispersed well in polymer matrix with no considerable agglomeration and no non-selective void formation at polymer/filler interface. In addition, CO2 and CH4 permeability measurement along with calculation of CO2/CH4 selectivity were performed. The results showed that the permeability of gases (especially for CO2 increased significantly by increasing the MIL-53 loading. Additionally, CO2/CH4 selectivity showed an increasing trend with increasing the MIL-53 weight percent. Unlike CH4, the CO2 solubility coefficient increased with increasing the MIL-53 loading because of high free volume of membrane and selective adsorption of CO2 with MIL-53. Despite CO2 solubility enhancement its diffusivity coefficient remained more or less unchanged. The enhancement in CH4 permeability has been mainly attributed to its slight incremental diffusivity due to the membrane's increasingly higher free volume. Finally, a comparison between membranes performance and CO2/CH4 Robeson upper bound showed that, the performance of membranes improved due to the presence of MIL-53 which was very close to the Robeson bound.

The cinephilic citation in the essay films by José Luis Guerin and Isaki Lacuesta

OpenAIRE

Vidal, Belén

2014-01-01

This paper investigates the contemporary turn to cinephilia as an object of theoretical analysis and historiographical investigation through the essay films by José Luis Guerin and Isaki Lacuesta. In particular, I focus on Innisfree (José Luis Guerin 1990), Tren de sombras (Train of Shadows, José Luis Guerin 1997), Las variaciones Marker (The Marker Variations, Isaki Lacuesta 2008) and La noche que no acaba (All the Night Long, Isaki Lacuesta 2010). This work recovers and restages “cinephilic...

Glucose recovery from aqueous solutions by adsorption in metal-organic framework MIL-101: a molecular simulation study.

Science.gov (United States)

Gupta, Krishna M; Zhang, Kang; Jiang, Jianwen

2015-08-05

A molecular simulation study is reported on glucose recovery from aqueous solutions by adsorption in metal-organic framework MIL-101. The F atom of MIL-101 is identified to be the most favorable adsorption site. Among three MIL-101-X (X = H, NH2 or CH3), the parent MIL-101 exhibits the highest adsorption capacity and recovery efficacy. Upon functionalization by -NH2 or -CH3 group, the steric hindrance in MIL-101 increases; consequently, the interactions between glucose and framework become less attractive, thus reducing the capacity and mobility of glucose. The presence of ionic liquid, 1-ethyl-3-methyl-imidazolium acetate, as an impurity reduces the strength of hydrogen-bonding between glucose and MIL-101, and leads to lower capacity and mobility. Upon adding anti-solvent (ethanol or acetone), a similar adverse effect is observed. The simulation study provides useful structural and dynamic properties of glucose in MIL-101, and it suggests that MIL-101 might be a potential candidate for glucose recovery.

Vivências em espaços educativos: constituição de identidades homossexuais em homens adultos

OpenAIRE

Cechin, Andréa Forgiarini

2006-01-01

Esta pesquisa problematiza a relação entre a constituição das identidades homossexuais de homens adultos e suas vivências em espaços educativos formais, não formais e informais. Como ponto de partida para desenvolver o estudo, foram formuladas questões que focalizam percepções e sentimentos desses homens adultos em relação a si próprios e aos outros, tendo em vista suas vivências nesses espaços educativos e, especialmente, suas experiências de discriminação e resistência. Apoia-se teoricament...

Small Explorer Data System MIL-STD-1773 fiber optic bus

Science.gov (United States)

Flanegan, Mark; Label, Ken

1992-01-01

The MIL-STD-1773 Fiber Optic Data Bus as implemented in the GSFC Small Explorer Data System (SEDS) for the Small Explorer Program is described. It provides an overview of the SEDS MIL-STD-1773 bus components system design considerations, reliability figures, acceptance and qualification testing requirements, radiation requirements and tests, error handling considerations, and component heritage. The first mission using the bus will be launched in June of 1992.

1 mil gold bond wire study.

Energy Technology Data Exchange (ETDEWEB)

Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

2013-05-01

In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

Preparation of magnetic MIL-101 (Cr) for efficient removal of ciprofloxacin.

Science.gov (United States)

Bayazit, Şahika Sena; Danalıoğlu, Selen Tuğba; Abdel Salam, Mohamed; Kerkez Kuyumcu, Özge

2017-11-01

Metal organic frameworks are widely used as adsorbent materials in recent years. In this study, the most prepared metal organic framework MIL-101 was prepared by hydrothermal method and featured magnetic property using co-precipitation method Fe 3 O 4 . Then, the prepared composite (MIL-101/Fe 3 O 4 ) was first characterized using XRD, FTIR, SEM-EDS, and surface area analysis, then was used for the adsorptive removal of the most used antibiotic, ciprofloxacin (CIP). The effect of different adsorption variables which may affect the removal of CIP by MIL-101/Fe 3 O 4 was investigated, as well as their adsorbent quantity, initial CIP concentration, pH, temperature, and contact time. The non-linear Langmuir and Freundlich isotherm were applied to experimental data. It was observed that rising solution temperature decreases adsorption efficiency, as the maximum adsorption uptake value was 63.28 mg g -1 at 298 K and 22.93 mg g -1 at 313 K, indicating the exothermic nature of the adsorption. The adsorption was studied kinetically and found to follow the pseudo-second-order kinetic model. The desorption of CIP from the MIL-101/Fe 3 O 4 was investigated using three different eluents, and the results showed that phosphate-buffered solution was the most effective desorption eluent. Graphical abstract Schematic diagram of the preparation steps of MIL-101/Fe3O4.

78 FR 73557 - Guadalupe-Nipomo Dunes National Wildlife Refuge, San Luis Obispo County, CA: Intent To Prepare a...

Science.gov (United States)

2013-12-06

...-FF08R00000] Guadalupe-Nipomo Dunes National Wildlife Refuge, San Luis Obispo County, CA: Intent To Prepare a...) for the Guadalupe-Nipomo Dunes National Wildlife Refuge located in San Luis Obispo County of... (Refuge) in San Luis Obispo County, California. This notice complies with our CCP policy to (1) advise...

Glucose recovery from aqueous solutions by adsorption in metal–organic framework MIL-101: a molecular simulation study

Science.gov (United States)

Gupta, Krishna M.; Zhang, Kang; Jiang, Jianwen

2015-01-01

A molecular simulation study is reported on glucose recovery from aqueous solutions by adsorption in metal-organic framework MIL-101. The F atom of MIL-101 is identified to be the most favorable adsorption site. Among three MIL-101-X (X = H, NH2 or CH3), the parent MIL-101 exhibits the highest adsorption capacity and recovery efficacy. Upon functionalization by -NH2 or -CH3 group, the steric hindrance in MIL-101 increases; consequently, the interactions between glucose and framework become less attractive, thus reducing the capacity and mobility of glucose. The presence of ionic liquid, 1-ethyl-3-methyl-imidazolium acetate, as an impurity reduces the strength of hydrogen-bonding between glucose and MIL-101, and leads to lower capacity and mobility. Upon adding anti-solvent (ethanol or acetone), a similar adverse effect is observed. The simulation study provides useful structural and dynamic properties of glucose in MIL-101, and it suggests that MIL-101 might be a potential candidate for glucose recovery. PMID:26242874

Comparative Study of MIL-96(Al) as Continuous Metal-Organic Frameworks Layer and Mixed-Matrix Membrane.

Science.gov (United States)

Knebel, Alexander; Friebe, Sebastian; Bigall, Nadja Carola; Benzaqui, Marvin; Serre, Christian; Caro, Jürgen

2016-03-23

MIL-96(Al) layers were prepared as supported metal-organic frameworks membrane via reactive seeding using the α-alumina support as the Al source for the formation of the MIL-96(Al) seeds. Depending on the solvent mixture employed during seed formation, two different crystal morphologies, with different orientation of the transport-active channels, have been formed. This crystal orientation and habit is predefined by the seed crystals and is kept in the subsequent growth of the seeds to continuous layers. In the gas separation of an equimolar H2/CO2 mixture, the hydrogen permeability of the two supported MIL-96(Al) layers was found to be highly dependent on the crystal morphology and the accompanied channel orientation in the layer. In addition to the neat supported MIL-96(Al) membrane layers, mixed-matrix membranes (MMMs, 10 wt % filler loading) as a composite of MIL-96(Al) particles as filler in a continuous Matrimid polymer phase have been prepared. Five particle sizes of MIL-96(Al) between 3.2 μm and 55 nm were synthesized. In the preparation of the MIL-96(Al)/Matrimid MMM (10 wt % filler loading), the following preparation problems have been identified: The bigger micrometer-sized MIL-96(Al) crystals show a trend toward sedimentation during casting of the MMM, whereas for nanoparticles aggregation and recrystallization to micrometer-sized MIL-96(Al) crystals has been observed. Because of these preparation problems for MMM, the neat supported MIL-96(Al) layers show a relatively high H2/CO2 selectivity (≈9) and a hydrogen permeance approximately 2 magnitudes higher than that of the best MMM.

Effect of synthesis solvent on the breathing behavior of MIL-53(Al).

Science.gov (United States)

Mounfield, William P; Walton, Krista S

2015-06-01

This work reports the effect of using dimethylformamide (DMF) as the solvent for synthesizing MIL-53(Al). This well-known breathing MOF is typically prepared using hydrothermal methods. The two materials synthesized in DMF at 120°C and 220°C show significant deviations from the breathing behavior exhibited by the material synthesized hydrothermally. Powder X-ray diffraction confirmed that MIL-53(Al) synthesized in DMF at 120°C remains in the large-pore form under all conditions, while the other material synthesized at 220°C undergoes a more gradual breathing transition than is observed for MIL-53(Al) prepared by traditional methods. Solid-state NMR was employed to elucidate additional structural information and gain insight into the role synthesis solvent plays on breathing behavior. The CO2 and water adsorption of these large-pore stabilized materials were studied, and the differences in adsorption behavior compared to MIL-53(Al) prepared by traditional methods was discussed. Copyright © 2015 Elsevier Inc. All rights reserved.

Nanometric MIL-125-NH₂ Metal-Organic Framework as a Potential Nerve Agent Antidote Carrier.

Science.gov (United States)

Vilela, Sérgio M F; Salcedo-Abraira, Pablo; Colinet, Isabelle; Salles, Fabrice; de Koning, Martijn C; Joosen, Marloes J A; Serre, Christian; Horcajada, Patricia

2017-10-12

The three-dimensional (3D) microporous titanium aminoterephthalate MIL-125-NH₂ (MIL: Material of Institut Lavoisier) was successfully isolated as monodispersed nanoparticles, which are compatible with intravenous administration, by using a simple, safe and low-cost synthetic approach (100 °C/32 h under atmospheric pressure) so that for the first time it could be considered for encapsulation and the release of drugs. The nerve agent antidote 2-[(hydroxyimino)methyl]-1-methyl-pyridinium chloride (2-PAM or pralidoxime) was effectively encapsulated into the pores of MIL-125-NH₂ as a result of the interactions between 2-PAM and the pore walls being mediated by π-stacking and hydrogen bonds, as deduced from infrared spectroscopy and Monte Carlo simulation studies. Finally, colloidal solutions of MIL-125-NH₂ nanoparticles exhibited remarkable stability in different organic media, aqueous solutions at different pH and under relevant physiological conditions over time (24 h). 2-PAM was rapidly released from the pores of MIL-125-NH₂ in vitro.

Understanding and solving disorder in the substitution pattern of amino functionalized MIL-47(V).

Science.gov (United States)

Heinen, Jurn; Dubbeldam, David

2016-03-14

Electronic energies and elastic constants of four amino functionalized MIL-47(V) supercells were computed using plane wave density functional theory to determine the influence of the substituent positions on the organic linker. An inverse relationship between the ab initio energies and the elastic constants was found, indicating that the high electronic stability correlates with high mechanical stability. Torsion in all supercells was induced upon substitution, which caused strain in the NH2-MIL-47(V) supercell. The combined effect of the substituent bulkiness and the induced torsion reduced the pore volume of the NH2-MIL-47(V) structures by >7% and the surface area by >14% with respect to MIL-47(V). This reduction was confirmed by lower saturation capacities of methane, CO2 and benzene. When unfavourable substituent positions are chosen, large torsions caused a further reduction of the saturation capacity. Differences in surface area, pore volume and saturation capacity illustrate the importance of choosing the correct NH2-MIL-47(V) supercell.

Novel composite material polyoxovanadate@MIL-101(Cr): a highly efficient electrocatalyst for ascorbic acid oxidation.

Science.gov (United States)

Fernandes, Diana M; Barbosa, André D S; Pires, João; Balula, Salete S; Cunha-Silva, Luís; Freire, Cristina

2013-12-26

A novel hybrid composite material, PMo10V2@MIL-101 was prepared by the encapsulation of the tetra-butylammonium (TBA) salt of the vanadium-substituted phosphomolybdate [PMo10V2O40](5-) (PMo10V2) into the porous metal-organic framework (MOF) MIL-101(Cr). The materials characterization by powder X-ray diffraction, Fourier transform infrared spectra and scanning electron microscopy confirmed the preparation of the composite material without disruption of the MOF porous structure. Pyrolytic graphite electrodes modified with the original components (MIL-101(Cr), PMo10V2), and the composite material PMo10V2@MIL-101 were prepared and their electrochemical responses were studied by cyclic voltammetry. Surface confined redox processes were observed for all the immobilized materials. MIL-101(Cr) showed one-electron reduction process due to chromium centers (Cr(III) → Cr(II)), while PMo10V2 presented five reduction processes: the peak at more positive potentials is attributed to two superimposed 1-electron vanadium reduction processes (V(V) → V(IV)) and the other four peaks to Mo-centred two-electron reduction processes (Mo(VI) → Mo(V)). The electrochemical behavior of the composite material PMo10V2@MIL-101 showed both MIL-101(Cr) and PMo10V2 redox features, although with the splitting of the two vanadium processes and the shift of the Mo- and Cr- centered processes to more negative potentials. Finally, PMo10V2@MIL-101 modified electrode showed outstanding enhanced vanadium-based electrocatalytic properties towards ascorbic acid oxidation, in comparison with the free PMo10V2, as a result of its immobilization into the porous structure of the MOF. Furthermore, PMo10V2@MIL-101 modified electrode showed successful simultaneous detection of ascorbic acid and dopamine.

Host-guest interaction of styrene and ethylbenzene in MIL-53 studied by solid-state NMR.

Science.gov (United States)

Li, Shenhui; Li, Jing; Tang, Jing; Deng, Feng

Solid-state NMR was utilized to explore the host-guest interaction between adsorbate and adsorbent at atomic level to understand the separation mechanism of styrene (St) and ethylbenzene (EB) in MIL-53(Al). 13 C- 27 Al double-resonance NMR experiments revealed that the host-guest interaction between St and MIL-53 was much stronger than that of EB adsorption. In addition, 13 C DIPSHIFT experiments suggested that the adsorbed St was less mobile than EB confined inside the MIL-53 pore. Furthermore, the host-guest interaction model between St, EB and MIL-53 was established on the basis of the spatial proximities information extracted from 2D 1 H- 1 H homo-nuclear correlation NMR experiments. According to the experimental observation from solid-state NMR, it was found that the presence of π-π interaction between St and MIL-53 resulted in the stronger host-guest interaction and less mobility of St. This work provides direct experimental evidence for understanding the separation mechanism of St and EB using MIL-53 as an adsorbent. Copyright © 2017 Elsevier Inc. All rights reserved.

Augmentation du rendement des producteurs de petits mils par leur ...

International Development Research Centre (IDRC) Digital Library (Canada)

29 avr. 2016 ... Image. Cultivateurs du petit mils en Inde. Une plus grande diversité de variétés de petit mil contribue à réduire la vulnérabilité à l'égard des mauvaises conditions météorologiques. En dépit du fait qu'ils ont une teneur élevée en micronutriments et en fibres alimentaires, présentent un indice glycémique ...

Novel thymine-functionalized MIL-101 prepared by post-synthesis and enhanced removal of Hg{sup 2+} from water

Energy Technology Data Exchange (ETDEWEB)

Luo, Xubiao, E-mail: luoxubiao@126.com [Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang 330063 (China); College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063 (China); Shen, Tingting; Ding, Lin; Zhong, Weiping; Luo, Jianfeng [Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang 330063 (China); College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063 (China); Luo, Shenglian, E-mail: sllou@hnu.edu.cn [Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang 330063 (China); College of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063 (China)

2016-04-05

Highlights: • A novel thymine-functionalized MIL-101 (MIL-101-Thymine) was first synthesized by post-synthesis method. • The resulting MIL-101-Thymine exhibited high Hg{sup 2+} adsorption. • MIL-101-Thymine exhibited excellent selectivity towards Hg{sup 2+} over other metal ions. • MIL-101-Thymine was used to remove trace Hg{sup 2+} with satisfactory recoveries in real water samples. - Abstract: A novel thymine-functionalized MIL-101 (MIL-101-Thymine) material was synthesized using a post-synthesis method to remove mercury at a high efficiency. MIL-101-Thymine was successfully prepared in this work and was confirmed by several characterization methods, such as {sup 13}C nuclear magnetic resonance, X-ray diffraction, and infrared spectroscopy. The Hg{sup 2+} adsorption agreed well with the Langmuir model, and the maximum adsorption capacity was 51.27 mg/g. The adsorption rate fit with the pseudo-second-order kinetic model. Furthermore, MIL-101-Thymine exhibited excellent selectivity towards Hg{sup 2+} over other cations, and the maximum value of the selective coefficient reached 947.34; this result is very likely due to the highly selective interactions of T-Hg{sup 2+}–T in MIL-101-Thymine. The result of X-ray photoelectron spectroscopy also showed that Hg{sup 2+} was coordinated with the N of thymine in MIL-101-Thymine. Moreover, the results of the thermogravimetric analysis and adsorption experiments showed that the Hg atom was two-coordinated with the thymine group. MIL-101-Thymine was used to remove trace Hg{sup 2+} in real water samples, and satisfactory recoveries were obtained.

Tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos

OpenAIRE

Habermann, Mateus; Gouveia, Nelson

2011-01-01

OBJETIVO: Analisar a associação entre indicadores de exposição à poluição por tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos. MÉTODOS: Foram analisadas informações sobre vias e volume de tráfego no ano de 2007 fornecidas pela companhia de engenharia de tráfego local. Mortalidade por doenças do aparelho circulatório no ano de 2005 entre homens > 40 anos foram obtidas do registro de mortalidade do Programa de Aprimoramento de Informações de Mortalidade do ...

Art as Critical Public Pedagogy: A Qualitative Study of Luis Camnitzer and His Conceptual Art

Science.gov (United States)

Zorrilla, Ana; Tisdell, Elizabeth J.

2016-01-01

This qualitative study explored the connection between art and adult education for critical consciousness from the perspective and work of conceptual artist, Luis Camnitzer. The theoretical framework is grounded in the critical public pedagogy literature. Data collection methods included interviews with conceptual artist Luis Camnitzer and with…

Aspectos clínicos e terapêuticos de prolactinomas em homens

Directory of Open Access Journals (Sweden)

Braucks Gisele Rieffel

2003-01-01

Full Text Available Em homens, macroprolactinomas predominam em relação aos microprolactinomas e têm maior invasividade que nas mulheres. O tratamento clínico é a primeira opção tanto em macro como em microadenomas, independente do sexo. Comparamos apresentação clínica, níveis de prolactina, invasividade neurorradiológica e resposta da prolactinemia em 42 homens com prolactinomas, 23 com terapia clínica (grupo 1 e 19 que também utilizaram tratamento cirúrgico e/ou radioterápico (grupo 2. Os dados obtidos foram submetidos a análise estatística utilizando-se os testes de qui-quadrado ou exato de Fisher para comparações de proporções. Para comparar médias foi aplicado o teste t de Student ou, na ausência de distribuição normal ou com número pequeno de eventos, o não paramétrico de Mann-Whitney. O nível de significância adotado foi de 5% (p<0,05. Os grupos foram similares para idade (p=0,23, período entre primeiro sintoma e diagnóstico (p=0,82, níveis de prolactina pré tratamento (p=0,41 e proporção de macroadenomas invasivos (p=0,096. Ocorreu percentual significativamente maior de cefaléia (p=0,009, deficit visual (p=0,025, tempo de terapia (p=0,007 e período de acompanhamento (p=0,0005 no grupo 2. Variações dos níveis de prolactina antes e após terapia não apresentaram diferença significativa nos grupos (p=0,49, nem o percentual de normalização da prolactina após tratamento (p=0,20. Concluímos, enfatizando a importância do diagnóstico precoce do prolactinoma em homens, tendo em vista a morbidade demonstrada, e reforçamos a necessidade do uso do agonista dopaminérgico como opção terapêutica inicial independente do tamanho do adenoma.

O efeito Salieri: O sindicalismo perante as desigualdades entre mulheres e homens no emprego

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Virgínia Ferreira

2012-10-01

Full Text Available Os actuais padrões de segregação sexual do mercado de trabalho são ainda, em parte, a expressão viva de práticas excludentes e segregadoras dos sindicatos desde o começo da revolução industrial. Estes padrões começaram a desenhar-se a partir da aceitação do pagamento de menores salários às mulheres. Só num segundo momento os sindicatos passaram a reivindicar a igualdade salarial entre mulheres e homens como forma de defesa do emprego masculino. Numa primeira parte do texto, dá-se conta de algumas destas práticas de fechamento dos sindicatos em Portugal. Numa segunda parte, referem-se as principais linhas de mudança das orientações do movimento sindical perante as desigualdades entre os sexos no mercado de trabalho e apontam-se algumas iniciativas no âmbito da promoção da igualdade entre mulheres e homens.

Keisri madrusest impeeriumi esivedurijuhiks / Lui Pikkov ; kommenteerinud Hans Treimann

Index Scriptorium Estoniae

Pikkov, Lui, 1935-2008

2009-01-01

Lui Pikkov oma onust Otto Piksarist (Pikkov), kes sündis Raplamaal Saunakülas, oli madruseks Nikolai II jahtlaeval Poljarnaja Zvezda, töötas vedurijuhina Eestis, oli Eesti NSV Ülemnõukogu saadik

Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

KAUST Repository

Yin, Dongdong

2017-01-05

Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).

Sem Direito de Amar?: A Vontade de Ter Filhos Entre Homens (e Mulheres Vivendo Com o HIV

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Vera Paiva

2002-01-01

Full Text Available Desafios permanecem na prevenção e cuidado da aids. Nesse artigo apresentamos resultados de pesquisa com 250 homens portadores do HIV que fazem sexo com mulheres, sobre o cuidado à sua saúde reprodutiva em centros de referência de aids e comparamos com estudos entre mulheres portadoras. 43% dos homens e até 20 % das mulheres entrevistadas querem ter filhos, principalmente os que não têm filhos. 85% dos homens mantém atividade sexual e é baixo o nível de informação sobre reprodução na condição de portadores. Apesar das conquistas que permitem a paternidade sem infecção da parceira e da criança, os resultados indicam pouco acolhimento, mesmo nos centros de excelência pesquisados. Sugerimos como temas centrais no treinamento de profissionais e na organização de programas: a obrigatoriedade ética e constitucional de promoção dos direitos reprodutivos, desafiar o estigma anti-família associado às pessoas vivendo com HIV e às noções essencialistas que naturalizam as definições sobre a família e os gêneros.

“... Essa coisa começou a pegar!” – vivências cotidianas de homens obesos

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Carminda Maria Goersch Fontenele Lamboglia

2016-03-01

Full Text Available Objetivo: Conhecer as vivências cotidianas de homens com obesidade mórbida. Métodos: Pesquisa com abordagem qualitativa. Foram entrevistados nove homens com diagnóstico de obesidade mórbida que estavam em seguimento no pré-operatório para cirurgia bariátrica, com idade de 27 a 50 anos, casados, com renda familiar de dois a três salários mínimos, caso de obesidade na família e hipertensão como comorbidade. A investigação ocorreu no período de maio a setembro de 2012 em um hospital de referência no tratamento à obesidade e realização de cirurgia bariátrica em Fortaleza, Ceará, Brasil. Realizaram-se entrevistas semiestruturadas com análise, através da Análise de Conteúdo, do tipo análise temática. Eis as categorias de análise definidas: tornar-se obeso, vivências cotidianas do homem obeso e cirurgia bariátrica – um caminho possível para um cotidiano com saúde. Resultados: Os principais achados relacionaram-se a uma rotina diária fixa, com reduzido espaço para atividade física e de lazer. A obesidade, para 90% dos entrevistados, existe desde a infância e trouxe dificuldade na realização das ocupações no dia a dia. Esses homens optaram pela cirurgia por não perderem peso com dieta, exercício e medicamento, em razão da permanência de problemas de saúde, bem como dificuldades nas relações afetivas e no trabalho. Conclusão: Identificou-se a demanda de uma reorganização das vivências cotidianas dos homens para que haja uma efetiva ação da cirurgia bariátrica, a fim de que os usuários sejam protagonistas dessa modificação, inserindo atividades saudáveis e contínuas no seu cotidiano.

Protonated MIL-125-NH2: Remarkable Adsorbent for the Removal of Quinoline and Indole from Liquid Fuel.

Science.gov (United States)

Ahmed, Imteaz; Khan, Nazmul Abedin; Yoon, Ji Woong; Chang, Jong-San; Jhung, Sung Hwa

2017-06-21

The removal of nitrogen-containing compounds (NCCs) from fossil fuels prior to combustion is currently of particular importance, and so we investigated an adsorptive method using metal-organic frameworks (MOFs) for the removal of indole (IND) and quinoline (QUI), which are two of the main NCCs present in fossil fuels. We herein employed an amino (-NH 2 )-functionalized MIL-125 (MIL-125-NH 2 ) MOF, which was further modified by protonation (P-MIL-125-NH 2 ). These modified MOFs exhibited extraordinary performance in the adsorption of both IND (as representative neutral NCC) and QUI (as representative basic NCC). These MOFs were one of the most efficient adsorbents for the removal of NCCs. For example, P-MIL-125-NH 2 showed the highest adsorption capacity for QUI among ever reported adsorbent. The improved adsorption of IND was explained by H-bonding and cation-π interactions for MIL-125-NH 2 and P-MIL-125-NH 2 , respectively, while the mechanisms for QUI were H-bonding and acid-base interactions, respectively. This is a rare phenomenon for a single material (especially not with very high porosity) to exhibit such remarkable performances in the adsorption of both basic QUI and neutral IND. The adsorption results obtained using regenerated MIL-125-NH 2 and P-MIL-125-NH 2 also showed that these materials can be used several times without any severe degradation.

Geothermal resource assessment of western San Luis Valley, Colorado

Energy Technology Data Exchange (ETDEWEB)

Zacharakis, Ted G.; Pearl, Richard Howard; Ringrose, Charles D.

1983-01-01

The Colorado Geological Survey initiated and carried out a fully integrated assessment program of the geothermal resource potential of the western San Luis Valley during 1979 and 1980. The San Luis Valley is a large intermontane basin located in southcentral Colorado. While thermal springs and wells are found throughout the Valley, the only thermal waters found along the western part of the Valley are found at Shaw Warm Springs which is a relatively unused spring located approximately 6 miles (9.66 km) north of Del Norte, Colorado. The waters at Shaws Warm Spring have a temperature of 86 F (30 C), a discharge of 40 gallons per minute and contain approximately 408 mg/l of total dissolved solids. The assessment program carried out din the western San Luis Valley consisted of: soil mercury geochemical surveys; geothermal gradient drilling; and dipole-dipole electrical resistivity traverses, Schlumberger soundings, Audio-magnetotelluric surveys, telluric surveys, and time-domain electro-magnetic soundings and seismic surveys. Shaw Warm Springs appears to be the only source of thermal waters along the western side of the Valley. From the various investigations conducted the springs appear to be fault controlled and is very limited in extent. Based on best evidence presently available estimates are presented on the size and extent of Shaw Warm Springs thermal system. It is estimated that this could have an areal extent of 0.63 sq. miles (1.62 sq. km) and contain 0.0148 Q's of heat energy.

75 FR 76726 - San Luis Solar, LLC; Supplemental Notice That Initial Market-Based Rate Filing Includes Request...

Science.gov (United States)

2010-12-09

... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. ER11-2196-000] San Luis Solar, LLC; Supplemental Notice That Initial Market- Based Rate Filing Includes Request for Blanket... proceeding of San Luis [[Page 76727

The metal-organic framework MIL-53(Al) constructed from multiple metal sources: alumina, aluminum hydroxide, and boehmite.

Science.gov (United States)

Li, Zehua; Wu, Yi-nan; Li, Jie; Zhang, Yiming; Zou, Xin; Li, Fengting

2015-04-27

Three aluminum compounds, namely alumina, aluminum hydroxide, and boehmite, are probed as the metal sources for the hydrothermal synthesis of a typical metal-organic framework MIL-53(Al). The process exhibits enhanced synthetic efficiency without the generation of strongly acidic byproducts. The time-course monitoring of conversion from different aluminum sources into MIL-53(Al) is achieved by multiple characterization that reveals a similar but differentiated crystallinity, porosity, and morphology relative to typical MIL-53(Al) prepared from water-soluble aluminum salts. Moreover, the prepared MIL-53(Al) constructed with the three insoluble aluminum sources exhibit an improved thermal stability of up to nearly 600 °C and enhanced yields. Alumina and boehmite are more preferable than aluminum hydroxide in terms of product porosity, yield, and reaction time. The adsorption performances of a typical environmental endocrine disruptor, dimethyl phthalate, on the prepared MIL-53(Al) samples are also investigated. The improved structural stability of MIL-53(Al) prepared from these alternative aluminum sources enables double-enhanced adsorption performance (up to 206 mg g(-1)) relative to the conventionally obtained MIL-53(Al). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Nas Trilhas (desconhecidas da saúde: a política pública de saúde para os homens no Brasil.

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Marlene Neves Strey

2012-11-01

Full Text Available Neste estudo abordamos as diferentes formas de masculinidades e sua relação com a saúde, contempladas na Política de Atenção Integral à saúde do Homem (PNAISH implementada no Brasil no ano de 2009. Através de uma análise documental dessa política, pretendemos compreender os discursos masculinos que nela estão, bem como analisar a relação entre o discurso da política e as diferentes formas de produção de saúde. Devido a não estarem acostumados a se expor a um profissional de saúde, os homens sentem-se envergonhados, e além disso, atribuem sua baixa procura aos serviços de saúde, à falta de cuidados e escuta adequadas com um olhar de gênero que possa dar conta de suas demandas. Essa nova política de saúde para os homens criada no Brasil pretende atuar de maneira a atingir uma mudança cultural, que possibilite aos homens maior cuidado com sua saúde. Além disso, olhar para os modos de produção de masculinidades nos dias atuais e seus discursos sobre saúde é estar atento aos comportamentos que, devido à herança pautada nas diferenças entre os sexos, contribui para obstaculizar o acesso dos homens aos serviços de saúde.

En el día del bibliotecario: Homenaje al Doctor Luis Ángel Arango

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Ernesto Delgado

1962-04-01

Full Text Available Palabras pronunciadas por el presidente de la Asociación Colombiana de Bibliotecarios, señor Ernesto Delgado, en el Salón de Actos de la Biblioteca Luis Ángel Arango, el sábado 28 de abril, Día del Bibliotecario, con motivo del homenaje que dicha corporación rindió a la memoria del doctor Luis Ángel Arango.

El confesor regio Fray Luis Aliaga y la controversia Inmaculista

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Callado Estela, Emilio

2016-06-01

Full Text Available The present article analyses the participation of the aragonese dominican monk Luis Aliaga (Zaragoza, 1565-† Zaragoza, 1626, last confessor of Philip III and Inquiring general of the Hispanic Monarchy from 1619, in one of the most white hot theological controversies along the 17th century: the Immaculate Conception of the Virgin MaryEl presente artículo analiza la participación del dominico aragonés fray Luis Aliaga (Zaragoza, 1565-† Zaragoza, 1626 , último confesor de Felipe III e Inquisidor general de la Monarquía Hispánica desde 1619, en una de las controversias teológicas más candentes a lo largo del siglo XVII: la Inmaculada Concepción de la Virgen María.

Vida y obra de Luis Jiménez Moreno (1929-2007

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Antonio Jiménez García

2008-10-01

Full Text Available Luis Jiménez Moreno passed away on 27 of October, 2007, 77 years old. For the last 30 years he was professor at Universidad Complutense de Madrid. He became Full Professor. He had studied in Salamanca, Roma, Valencia and München. He got a Ph. Degree whith a tesis about Nietzsche`s Antropological Thought by leading of José Luis López Aranguren. He was High School Teacher in Andujar, Ávila and Badalona; after he was professor at Universities of Barcelona and Madrid. This article develops information about his life and his works: books, articles, essays, conferences, papers to Congress, Symposios, Scientic meetings…

Origen, protagonistas y alianzas. El Banco de San Luis Potosí, 1897-1916

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Moisés Gámez Rodriguez

2017-04-01

Full Text Available En este trabajo se expone el origen de la banca en San Luis Potosí, cuyo estudio se centra a partir de la legislación bancaria de 1897, que representa históricamente la institucionalización y modernización de la empresa bancaria mexicana. Como punto de partida se plantea que los perfiles financieros y empresariales de los involucrados en el nacimiento del Banco de San Luis Potosí, y representados en los miembros de su Consejo de Administración, son importantes para entender la configuración del sistema, y también que las redes extendidas en torno a dicha empresa muestran prácticas financieras de la economía de México en el último cuarto del siglo XIX. _________________________ This article explains the origin of banking in San Luis Potosi from the legislation in 1897, which historically represents the institutionalization and modernization of Mexican banking companies. As a starting point, it argues that financial and business profiles of those involved in the birth of Bank of San Luis Potosi and represented in the Board of Directors are important to understand the system configuration. Furthermore, the networks extended around the banking company show financial practices of Mexican economy in the last quarter of the 19th century.

Amphibians and reptiles of the state of San Luis Potosí, Mexico, with comparisons with adjoining states.

Science.gov (United States)

Lemos-Espinal, Julio A; Smith, Geoffrey R; Woolrich-Piña, Guillermo A

2018-01-01

A summary of the species of amphibians and reptiles of the state has been compiled, including their geographic distributions, habitats, and conservation statuses. The herpetofauna of San Luis Potosí consists of 41 species of amphibians and 141 species of reptiles. San Luis Potosí shares the highest number of species with Hidalgo and Tamaulipas, and the least number of species with Nuevo León. In San Luis Potosí, there are several taxa of particular conservation concern including salamanders, emydid and trionychid turtles, anguid and xenosaurid lizards, and natricid and colubrid snakes.

Nanometric MIL-125-NH2 Metal–Organic Framework as a Potential Nerve Agent Antidote Carrier

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Sérgio M. F. Vilela

2017-10-01

Full Text Available The three-dimensional (3D microporous titanium aminoterephthalate MIL-125-NH2 (MIL: Material of Institut Lavoisier was successfully isolated as monodispersed nanoparticles, which are compatible with intravenous administration, by using a simple, safe and low-cost synthetic approach (100 °C/32 h under atmospheric pressure so that for the first time it could be considered for encapsulation and the release of drugs. The nerve agent antidote 2-[(hydroxyiminomethyl]-1-methyl-pyridinium chloride (2-PAM or pralidoxime was effectively encapsulated into the pores of MIL-125-NH2 as a result of the interactions between 2-PAM and the pore walls being mediated by π-stacking and hydrogen bonds, as deduced from infrared spectroscopy and Monte Carlo simulation studies. Finally, colloidal solutions of MIL-125-NH2 nanoparticles exhibited remarkable stability in different organic media, aqueous solutions at different pH and under relevant physiological conditions over time (24 h. 2-PAM was rapidly released from the pores of MIL-125-NH2 in vitro.

Port San Luis, California Tsunami Forecast Grids for MOST Model

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The Port San Luis, California Forecast Model Grids provides bathymetric data strictly for tsunami inundation modeling with the Method of Splitting Tsunami (MOST)...

Novel thymine-functionalized MIL-101 prepared by post-synthesis and enhanced removal of Hg(2+) from water.

Science.gov (United States)

Luo, Xubiao; Shen, Tingting; Ding, Lin; Zhong, Weiping; Luo, Jianfeng; Luo, Shenglian

2016-04-05

A novel thymine-functionalized MIL-101 (MIL-101-Thymine) material was synthesized using a post-synthesis method to remove mercury at a high efficiency. MIL-101-Thymine was successfully prepared in this work and was confirmed by several characterization methods, such as (13)C nuclear magnetic resonance, X-ray diffraction, and infrared spectroscopy. The Hg(2+) adsorption agreed well with the Langmuir model, and the maximum adsorption capacity was 51.27mg/g. The adsorption rate fit with the pseudo-second-order kinetic model. Furthermore, MIL-101-Thymine exhibited excellent selectivity towards Hg(2+) over other cations, and the maximum value of the selective coefficient reached 947.34; this result is very likely due to the highly selective interactions of T-Hg(2+)-T in MIL-101-Thymine. The result of X-ray photoelectron spectroscopy also showed that Hg(2+) was coordinated with the N of thymine in MIL-101-Thymine. Moreover, the results of the thermogravimetric analysis and adsorption experiments showed that the Hg atom was two-coordinated with the thymine group. MIL-101-Thymine was used to remove trace Hg(2+) in real water samples, and satisfactory recoveries were obtained. Copyright © 2015 Elsevier B.V. All rights reserved.

78 FR 16569 - Iowa Pacific Holdings, LLC, Permian Basin Railways, and San Luis & Rio Grande Railroad-Corporate...

Science.gov (United States)

2013-03-15

... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. FD 35721] Iowa Pacific Holdings, LLC, Permian Basin Railways, and San Luis & Rio Grande Railroad--Corporate Family Transaction... subsidiaries Permian Basin Railways (PBR) and San Luis & Rio Grande Railroad (SLRG), and Massachusetts Coastal...

Os discursos de homens jovens sobre o acesso aos serviços de saúde

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Michael Ferreira Machado

2012-06-01

Full Text Available Apresentam-se algumas reflexões acerca dos sentidos produzidos por homens jovens de uma comunidade de pescadores no Nordeste do Brasil sobre uso dos serviços de atenção básica de sua região. Parte-se de informações obtidas por meio de observação participante, dos dados da Secretaria Municipal de Saúde e dos grupos de discussão realizados com os homens jovens. Identificou-se o crescente consumo de álcool e outras drogas psicoativas entre os jovens, e uma preferência, entre os membros da comunidade, em usar o conhecimento leigo de cuidados com a saúde, e não a rede oficial de assistência, recorrendo a esta só em caso de piora no quadro e/ou dor. Aponta-se a necessidade de se ampliar a reflexão sobre a masculinidade, tendo em vista o comprometimento com a saúde do homem.

Hydrogen selective NH{sub 2}-MIL-53(Al) MOF membranes with high permeability

Energy Technology Data Exchange (ETDEWEB)

Zhang, Feng; Zou, Xiaoqin; Gao, Xue; Fan, Songjie; Sun, Fuxing; Ren, Hao; Zhu, Guangshan [State Key Laboratory of Inorganic, Synthesis and Preparative Chemistry, Jilin University, Changchun (China)

2012-09-11

Hydrogen-based energy is a promising renewable and clean resource. Thus, hydrogen selective microporous membranes with high performance and high stability are demanded. Novel NH{sub 2}-MIL-53(Al) membranes are evaluated for hydrogen separation for this goal. Continuous NH{sub 2}-MIL-53(Al) membranes have been prepared successfully on macroporous glass frit discs assisted with colloidal seeds. The gas sorption ability of NH{sub 2}-MIL-53(Al) materials is studied by gas adsorption measurement. The isosteric heats of adsorption in a sequence of CO{sub 2}> N{sub 2}> CH{sub 4}{approx} H{sub 2} indicates different interactions between NH{sub 2}-MIL-53(Al) framework and these gases. As-prepared membranes are measured by single and binary gas permeation at different temperatures. The results of singe gas permeation show a decreasing permeance in an order of H{sub 2}> CH{sub 4}> N{sub 2}> CO{sub 2}, suggesting that the diffusion and adsorption properties make significant contributions in the gas permeation through the membrane. In binary gas permeation, the NH{sub 2}-MIL-53(Al) membrane shows high selectivity for H{sub 2} with separation factors of 20.7, 23.9 and 30.9 at room temperature (288 K) for H{sub 2} over CH{sub 4}, N{sub 2} and CO{sub 2}, respectively. In comparison to single gas permeation, a slightly higher separation factor is obtained due to the competitive adsorption effect between the gases in the porous MOF membrane. Additionally, the NH{sub 2}-MIL-53(Al) membrane exhibits very high permeance for H{sub 2} in the mixtures separation (above 1.5 x 10{sup -6} mol m{sup -2} s{sup -1} Pa{sup -1}) due to its large cavity, resulting in a very high separation power. The details of the temperature effect on the permeances of H{sub 2} over other gases are investigated from 288 to 353 K. The supported NH{sub 2}-MIL-53(Al) membranes with high hydrogen separation power possess high stability, resistance to cracking, temperature cycling and show high reproducibility

Magmatism and mineralization ages from northeast area of La Sierra de San Luis, Argentina

International Nuclear Information System (INIS)

Ulacco, Jose H

2001-01-01

Three igneous rock groups, characterized as pre, sin and post-kinematics, have intruded the crystalline basement of Sierra de San Luis, Argentina. The ore deposits are associated with Devonian to Carboniferous epizonal granite stocks and batholiths in an area underlain by metamorphic rocks. This granitoids are characterized as post-kinematics magmatism. Model lead ages on the ore deposits (338,8 - 292,1 Ma) are strongly supported by K-Ar ages of the intrusives. The bulk of the north Sierra de San Luis ore deposits are genetically related to late Carboniferous granite plutons. The ore bodies are tungsten veins with greisen envelopes, lead veins, epithermal fluorite veins and REE and Th deposit. A generalized scheme of ore bodies related to granites is proposed. The ore deposits and their lithotectonic setting are characteristic of Gondwana metallogenetic Epoch in the Sierra de San Luis (au)

Glycine post-synthetic modification of MIL-53(Fe) metal-organic framework with enhanced and stable peroxidase-like activity for sensitive glucose biosensing.

Science.gov (United States)

Dong, Wenfei; Yang, Liaoyuan; Huang, Yuming

2017-05-15

A facile and rapid post-synthetic strategy was proposed to prepare a glycine functionalized MIL-53(Fe), namely glycine-MIL-53(Fe), by a simple mixing of water dispersible MIL-53(Fe) and glycine. The FT-IR, SEM, XRD and zeta potential were used to characterize the glycine-MIL-53(Fe). The result showed that glycine post-synthetic modification of MIL-53(Fe) did not change in the morphology and crystal structure of MIL-53(Fe). Interestingly, compared with MIL-53(Fe), the glycine-MIL-53(Fe) exhibits an enhanced peroxidase-like activity, which could catalyze the oxidation of TMB by H 2 O 2 to produce an intensive color reaction. Kinetic analysis indicated that the K m of glycine-MIL-53(Fe) for TMB was one-tenth of that of MIL-53(Fe). The glycine-MIL-53(Fe) as peroxidase mimetic displays better stability under alkaline or acidic conditions than MIL-53(Fe). The good performance of glycine-MIL-53(Fe) over MIL-53(Fe) may be attributed to the increase of affinity between TMB and the glycine-MIL-53(Fe). With these characteristics, a simple and sensitive method was developed for the detection of H 2 O 2 and glucose. The linear detection range for H 2 O 2 is 0.10-10μM with a detection limit of 49nM, and glucose could be linearly detected in the range from 0.25 to 10μM with a detection limit of 0.13μM. The proposed method was successfully used for glucose detection in human serum samples. Copyright © 2017 Elsevier B.V. All rights reserved.

MilQuant: a free, generic software tool for isobaric tagging-based quantitation.

Science.gov (United States)

Zou, Xiao; Zhao, Minzhi; Shen, Hongyan; Zhao, Xuyang; Tong, Yuanpeng; Wang, Qingsong; Wei, Shicheng; Ji, Jianguo

2012-09-18

Isobaric tagging techniques such as iTRAQ and TMT are widely used in quantitative proteomics and especially useful for samples that demand in vitro labeling. Due to diversity in choices of MS acquisition approaches, identification algorithms, and relative abundance deduction strategies, researchers are faced with a plethora of possibilities when it comes to data analysis. However, the lack of generic and flexible software tool often makes it cumbersome for researchers to perform the analysis entirely as desired. In this paper, we present MilQuant, mzXML-based isobaric labeling quantitator, a pipeline of freely available programs that supports native acquisition files produced by all mass spectrometer types and collection approaches currently used in isobaric tagging based MS data collection. Moreover, aside from effective normalization and abundance ratio deduction algorithms, MilQuant exports various intermediate results along each step of the pipeline, making it easy for researchers to customize the analysis. The functionality of MilQuant was demonstrated by four distinct datasets from different laboratories. The compatibility and extendibility of MilQuant makes it a generic and flexible tool that can serve as a full solution to data analysis of isobaric tagging-based quantitation. Copyright © 2012 Elsevier B.V. All rights reserved.

Por mil devaluados pesos

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Annie Rodríguez Collázos

2013-03-01

Full Text Available El estudio de lo popular y lo urbano hasta ahora se ha centrado en el comportamiento y en algunas relaciones de los habitantes con su entorno. “Por mil devaluados pesos. Publicidad popular y urbana”, pretende explorar las formas de publicidad, dispersas en diferentes espacios populares y urbanos en Bogotá, identificando esquemas y formas características de sus propios códigos comunicativos; se centran en un objeto de estudio consistente en las estrategias publicitarias y los códigos comunicativos en los mensajes publicitarios populares en las subculturas de San Victorino, 7 de Agosto y Sanandresito de San José.

Catalytic Performance of Microwave Functionalized NH2-MIL-53 for Cyclic Carbonate Synthesis from CO2 and Epoxides.

Science.gov (United States)

Seok, Han-Geul; Kim, Dong-Woo; Yang, Jeung-Gyu; Kim, Moon-Il; Park, Dae-Won

2016-05-01

The efficacy of microwave irradiation in the quaternization of amino-functionalized MIL-53 metal-organic framework (MOF) as well as the catalytic activity of the resultant MOF in the cycloaddition of carbon dioxide with epoxides under solvent-free conditions has been studied. A series of NH2-MIL-53 were synthesized and quaternized by reacting alkyl halide of various alkyl chains and anions under microwave irradiation. The post-functionalized F-MIL-53-AXs were characterized through solid-state XRD, FT-IR, XPS, and TGA. F-MIL-53-Mel prepared by microwave method showed higher AGC yield than that by the conventional heating method. F-MIL-53-AXs with iodide anion exhibited the best catalytic activity irrespective of the alkyl chain length, in agreement with the generally accepting order of nucleophilicity, ClMIL-53-AX catalysts were found to exhibit high thermal stability and were reusable over than three times, without any significant lowering of activity.

Amphibians and reptiles of the state of San Luis Potosí, Mexico, with comparisons with adjoining states

Science.gov (United States)

Lemos-Espinal, Julio A.; Smith, Geoffrey R.; Woolrich-Piña, Guillermo A.

2018-01-01

Abstract A summary of the species of amphibians and reptiles of the state has been compiled, including their geographic distributions, habitats, and conservation statuses. The herpetofauna of San Luis Potosí consists of 41 species of amphibians and 141 species of reptiles. San Luis Potosí shares the highest number of species with Hidalgo and Tamaulipas, and the least number of species with Nuevo León. In San Luis Potosí, there are several taxa of particular conservation concern including salamanders, emydid and trionychid turtles, anguid and xenosaurid lizards, and natricid and colubrid snakes. PMID:29731682

Effect of Diamine in Amine-Functionalized MIL-101 for Knoevenagel Condensation

International Nuclear Information System (INIS)

Kasinathan, Palraj; Seo, You Kyong; Shim, Kyu Eun; Hwang, Young Kyu; Lee, U Hwang; Hwang, Dong Won; Hong, Do Young; Halligudi, Shiva B.; Chang, Jong San

2011-01-01

Have demonstrated that amines with different basicities successfully functionalized into the pores of MIL-101 and amine functionalized chromium terephthalate used as a base catalyst. The catalytic activity of amine functionalized MIL-101 in Knoevenagel condensation of ethylcyanoacetate and benzaldehyde depends on their basi-cities. The reactivity of these catalytic materials could be also affected by their pore size and/or surface area, which governs the facile diffusion of the molecules through the channels of the MIL-101. The present strategy ensures the development of new functionalities and lead to MOF applications of practically useful heterogeneous base catalysts for chemical transformations. Crystalline Metal-Organic Frameworks (MOFs) are currently an important kind of advanced functional materials due to their novel coordination structures, diverse topologies, and potential applications. As one of topical MOFs, porous chromium terephthalate with giant pores labeled MIL-101(Cr) possesses several unique features such as hierarchical pore structure including a mesoporous zeotype architecture, mesoporous cages and microporous windows, outstanding sorption properties, numerous unsaturated metal cation sites, and high hydrothermal and chemical stability. These properties have led to a number of application potential in catalysis, gas storage, drug delivery and adsorptive separation. One important challenge has to realize is funtionalization via incorporation of binding site or reactive centers for catalysis. The functionalization methods of metal organic frameworks (MOFs) in a wide range of applications are two possible approaches including pre- and post-modification with functional groups

Modulated synthesis of chromium-based metal-organic framework (MIL-101) with enhanced hydrogen uptake

CSIR Research Space (South Africa)

Ren, Jianwei

2014-08-01

Full Text Available Modulated synthesis of MIL-101(Cr) in high yield and with good reproducibility using formic acid as a modulator is reported. Higher molar ratio of formic acid/CrCl(sub3) was found to form better shape-defined MIL-101(Cr) crystals with higher surface...

Exposiciones 1958, presentadas en la Biblioteca Luis Ángel Arango

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Boletín Cultural y Bibliográfico Banco de la República

1958-12-01

Full Text Available Se describe el desarrollo de la actividades culturales del año 1958 correspondientes a las exposiciones de arte presentadas en la Biblioteca Luis Ángel Arango del Banco de la República.

Stable ABTS Immobilized in the MIL-100(Fe) Metal-Organic Framework as an Efficient Mediator for Laccase-Catalyzed Decolorization.

Science.gov (United States)

Liu, Youxun; Geng, Yuanyuan; Yan, Mingyang; Huang, Juan

2017-06-02

The successful encapsulation of 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS), a well-known laccase mediator, within a mesoporous metal-organic framework sample (i.e., MIL-100(Fe)) was achieved using a one-pot hydrothermal synthetic method. The as-prepared ABTS@MIL-100(Fe) was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, nitrogen sorption, and cyclic voltammetry (CV). Our ABTS@MIL-100(Fe)-based electrode exhibited an excellent electrochemical response, indicating that MIL-100(Fe) provides an appropriate microenvironment for the immobilization and electroactivity of ABTS molecules. ABTS@MIL-100(Fe) was then evaluated as an immobilized laccase mediator for dye removal using indigo carmine (IC) as a model dye. Through the application of laccase in combination with a free (ABTS) or immobilized (ABTS@MIL-100(Fe)) mediator, decolorization yields of 95% and 94%, respectively, were obtained for IC after 50 min. In addition, following seven reuse cycles of ABTS@MIL-100(Fe) for dye treatment, a decolorization yield of 74% was obtained. Dye decolorization occurred through the breakdown of the chromophoric group by the Laccase/ABTS@MIL-100(Fe) system, and a catalytic mechanism was proposed. We therefore expect that the stability, reusability, and validity of ABTS@MIL-100(Fe) as a laccase mediator potentially render it a promising tool for dye removal, in addition to reducing the high running costs and potential toxicity associated with synthetic mediators.

76 FR 31678 - San Luis & Rio Grande Railroad-Continuance in Control Exemption-Saratoga and North Creek Railway...

Science.gov (United States)

2011-06-01

... DEPARTMENT OF TRANSPORTATION Surface Transportation Board [Docket No. FD 35499] San Luis & Rio Grande Railroad--Continuance in Control Exemption--Saratoga and North Creek Railway, LLC San Luis & Rio Grande Railroad (SLRG), a Class III rail carrier, has filed a verified notice of exemption to continue in...

The Oxygen Isotopic Composition of MIL 090001: A CR2 Chondrite with Abundant Refractory Inclusions

Science.gov (United States)

Keller, Lindsay P.; McKeegan, K. D.; Sharp, Z. D.

2012-01-01

MIL 090001 is a large (>6 kg) carbonaceous chondrite that was classified as a member of the CV reduced subgroup (CVred) that was recovered during the 2009-2010 ANSMET field season [1]. Based on the abundance of refractory inclusions and the extent of aqueous alteration, Keller [2] suggested a CV2 classification. Here we report additional mineralogical and petrographic data for MIL 090001, its whole-rock oxygen isotopic composition and ion microprobe analyses of individual phases. The whole rock oxygen isotopic analyses show that MIL 090001 should be classified as a CR chondrite.

Geomorphic evolution of the San Luis Basin and Rio Grande in southern Colorado and northern New Mexico

Science.gov (United States)

Ruleman, Chester A.; Machette, Michael; Thompson, Ren A.; Miggins, Dan M; Goehring, Brent M; Paces, James B.

2016-01-01

The San Luis Basin encompasses the largest structural and hydrologic basin of the Rio Grande rift. On this field trip, we will examine the timing of transition of the San Luis Basin from hydrologically closed, aggrading subbasins to a continuous fluvial system that eroded the basin, formed the Rio Grande gorge, and ultimately, integrated the Rio Grande from Colorado to the Gulf of Mexico. Waning Pleistocene neotectonic activity and onset of major glacial episodes, in particular Marine Isotope Stages 11–2 (~420–14 ka), induced basin fill, spillover, and erosion of the southern San Luis Basin. The combined use of new geologic mapping, fluvial geomorphology, reinterpreted surficial geology of the Taos Plateau, pedogenic relative dating studies, 3He surface exposure dating of basalts, and U-series dating of pedogenic carbonate supports a sequence of events wherein pluvial Lake Alamosa in the northern San Luis Basin overflowed, and began to drain to the south across the closed Sunshine Valley–Costilla Plain region ≤400 ka. By ~200 ka, erosion had cut through topographic highs at Ute Mountain and the Red River fault zone, and began deep-canyon incision across the southern San Luis Basin. Previous studies indicate that prior to 200 ka, the present Rio Grande terminated into a large bolson complex in the vicinity of El Paso, Texas, and systematic, headward erosional processes had subtly integrated discontinuously connected basins along the eastern flank of the Rio Grande rift and southern Rocky Mountains. We propose that the integration of the entire San Luis Basin into the Rio Grande drainage system (~400–200 ka) was the critical event in the formation of the modern Rio Grande, integrating hinterland basins of the Rio Grande rift from El Paso, Texas, north to the San Luis Basin with the Gulf of Mexico. This event dramatically affected basins southeast of El Paso, Texas, across the Chisos Mountains and southeastern Basin and Range province, including the Rio

Enhancing the water stability of Al-MIL-101-NH2 via postsynthetic modification.

Science.gov (United States)

Wittmann, Thomas; Siegel, Renée; Reimer, Nele; Milius, Wolfgang; Stock, Norbert; Senker, Jürgen

2015-01-02

The resistance of metal-organic frameworks towards water is a very critical issue concerning their practical use. Recently, it was shown for microporous MOFs that the water stability could be increased by introducing hydrophobic pendant groups. Here, we demonstrate a remarkable stabilisation of the mesoporous MOF Al-MIL-101-NH2 by postsynthetic modification with phenyl isocyanate. In this process 86 % of the amino groups were converted into phenylurea units. As a consequence, the long-term stability of Al-MIL-101-URPh in liquid water could be extended beyond a week. In water saturated atmospheres Al-MIL-101-URPh decomposed at least 12-times slower than the unfunctionalised analogue. To study the underlying processes both materials were characterised by Ar, N2 and H2 O sorption measurements, powder X-ray diffraction, thermogravimetric and chemical analysis as well as solid-state NMR and IR spectroscopy. Postsynthetic modification decreased the BET equivalent surface area from 3363 to 1555 m(2)  g(-1) for Al-MIL-101-URPh and reduced the mean diameters of the mesopores by 0.6 nm without degrading the structure significantly and reducing thermal stability. In spite of similar water uptake capacities, the relative humidity-dependent uptake of Al-MIL-101-URPh is slowed and occurs at higher relative humidity values. In combination with (1) H-(27) Al D-HMQC NMR spectroscopy experiments this favours a shielding mechanism of the Al clusters by the pendant phenyl groups and rules out pore blocking. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Utilidade da citologia anal no rastreamento dos homens heterossexuais portadores do HPV genital Anal cytology for screening heterosexual men harboring genital HPV infection

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Raphael Marianelli

2010-09-01

Full Text Available Os papilomavírus humanos (HPV de alto risco estão fortemente relacionados à etiologia do carcinoma espinocelular (CEC anogenital e suas lesões precursoras. O HPV-16 é o tipo mais freqüente, estando presente em até 87% dos CEC do canal anal HPV-positivo. Apesar de ser relativamente raro, vem sendo cada vez mais diagnosticado, nas últimas décadas, sobretudo em indivíduos do sexo masculino. A incidência é ainda mais elevada nos grupos considerados de risco, particularmente, os homens e as mulheres HIV-positivo e os homens que fazem sexo com homens (HSH. Grande parte das pesquisas direcionadas à infecção anal pelo HPV e sua relação com neoplasia intraepitelial-anal (NIA e com o carcinoma esteve focada nos grupos de risco. Pouco interesse vem sendo destinado à investigação dos homens heterossexuais. Estudos epidemiológicos da prevalência da infecção pelo HPV em homens, mostraram que os heterossexuais masculinos apresentavam infecção anal pelo HPV em até 12%. As Sociedades médicas e os especialistas recomendam o rastreamento dos portadores de imunodepressão e dos HSH com citologia do raspado do canal anal. Entretanto, até o momento, não há recomendação de rastreamento para homens que fazem sexo com mulheres.The oncogenic human papillomaviruses (HPV are straightly associated with anogenital cancer and dysplasia. The HPV-16 is the most common type, isolated in 87% of the HPV-positive anal squamous cell carcinoma (SCC. Despite being a rare tumor, the incidence of SCC has increased in the last decades, especially in males. Incidence is particularly high amongst men who have sex with men (MSM and among HIV infected men and women. For decades anogenital HPV researches have largely focused risk groups. Poor interest was intended to men who have sex with women (MSW. Prevalence studies of HPV infection in MSW have demonstrated that anal infection was identified in as far as 12%. Medical societies and specialists recommend anal

NATO Pallet with Javelin Missiles, MIL-STD-1660 Tests

National Research Council Canada - National Science Library

2004-01-01

The U.S. Army Defense Ammunition Center (DAC), Validation Engineering Division (SJMAC-DEV) conducted tests in accordance with MIL-STD-1660, "Design Criteria for Ammunition Unit Loads" on the NATO pallet with Javelin missiles...

Atomic Layer Deposition of Pt Nanoparticles within the Cages of MIL-101: A Mild and Recyclable Hydrogenation Catalyst

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Karen Leus

2016-03-01

Full Text Available We present the in situ synthesis of Pt nanoparticles within MIL-101-Cr (MIL = Materials Institute Lavoisier by means of atomic layer deposition (ALD. The obtained Pt@MIL-101 materials were characterized by means of N2 adsorption and X-ray powder diffraction (XRPD measurements, showing that the structure of the metal organic framework was well preserved during the ALD deposition. X-ray fluorescence (XRF and transmission electron microscopy (TEM analysis confirmed the deposition of highly dispersed Pt nanoparticles with sizes determined by the MIL-101-Cr pore sizes and with an increased Pt loading for an increasing number of ALD cycles. The Pt@MIL-101 material was examined as catalyst in the hydrogenation of different linear and cyclic olefins at room temperature, showing full conversion for each substrate. Moreover, even under solvent free conditions, full conversion of the substrate was observed. A high concentration test has been performed showing that the Pt@MIL-101 is stable for a long reaction time without loss of activity, crystallinity and with very low Pt leaching.

JORGE LUIS BORGES – SERGIO PITOL: INFLUENCES, SYMMETRIES AND LITERARY TRANSFERENCES JORGE LUIS BORGES – SERGIO PITOL: INFLUENCIAS, SIMETRÍAS Y TRANSFERENCIAS LITERARIAS

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Alejandro Hermosilla Sánchez

2011-02-01

Full Text Available In the entire Pitol‘s work, there is a continuous masquerade and an ungovernable fusion of the forces that link his life and his literature that has dislocated absolutely the "certainties" that we can get to own. Above all, for having been capable to improve the autobiographic genre helped by his way to understand, as Jorge Luis Borges and Marcel Schowb did, the reality as unverified and fiction as one more of many possibilities of what is "real". In this article, we will try to go deeper into the "discredit of the autobiographic and critical genre made by Sergio Pitol in La trilogía de la memoria thanks to the influence of Jorge Luis Borge´s literature.En toda la obra de Pitol hay un enmascaramiento continuo y una fusión ingobernable de las fuerzas que vinculan su vida y su literatura que ha terminado por dislocar absolutamente las "certezas" que podemos a llegar a poseer sobre ambas. Ante todo, por haber sido capaz de dar una nueva vuelta de tuerca más al género autobiográfico gracias a su manera de entender, tal y como hicieron Jorge Luis Borges y el francés Marcel Schwob, la realidad como inverificable y la ficción como una más de las muchas posibilidades de lo "real". En este artìculo, intentaremos profundizar en la desacreditación del género autobiográfico y crítico hecho por Pitol en La trilogía de la memoria o Domar a la divina garza gracias a la influencia de la literatura de Borges.

Olhares sobre os corpos e a construção de "homens" e "mulheres" na escola

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Moisés Sipriano Resende

2012-05-01

Full Text Available http://dx.doi.org/10.5007/2175-8042.2011v23n37p69 Este estudo visa levantar algumas problematizações referentes á construção de homens e mulheres no âmbito escolar e o modo como o corpo se torna local de inserção e produção dos discursos, marcas e linguagens. Foram aplicados questionários a estudantes, professores e gestores de escolas públicas de Goiânia buscando articular as compreensões destes sobre os comportamentos de homens e mulheres. Os dados evidenciaram que os educadores propõem pouca reflexão acerca da construção histórica, social e política dos corpos o que leva a reprodução das atuais diferenças de gênero por meio da educação dos corpos e das formas de viver a sexualidade.

Nanometric MIL-125-NH2 metal–organic framework as a potential nerve agent antidote carrier

NARCIS (Netherlands)

Vilela, S.M.F.; Salcedo-Abraira, P; Colinet, I.; Salles, F.; Koning, M.C. de; Joosen, M.J.A.; Serre, C.; Horcajada, P.

2017-01-01

The three-dimensional (3D) microporous titanium aminoterephthalate MIL-125-NH_2 (MIL: Material of Institut Lavoisier) was successfully isolated as monodispersed nanoparticles, which are compatible with intravenous administration, by using a simple, safe and low-cost synthetic approach (100 °C/32 h

Electro-Synthetic Optimization of Host Material Based on MIL-100(Fe

Directory of Open Access Journals (Sweden)

Witri Wahyu Lestari

2016-05-01

Full Text Available Electro-synthesis of Metal-Organic Frameworks types of MIL-100(Fe (MIL = Material Institute of Lavoisier in ethanol: water (1: 1 with electrolyte TBATFB 0.1 M has been optimized by varying voltage (12, 13, 14 and 15 Volt and temperature (room temperature, 40, 60 and 80 °C. The product showed light brown powder which upon activation becomes dark brown. Optimum condition achieved during use voltage of 15 Volts and at a temperature of 40 °C with 33% yield. The obtained material was characterized by XRD and compared to CCDC 640536 simulated patterns to confirm the phase purity of the product. As comparison hydrothermal and reflux method have been carried out. Characterization by FTIR has also undertaken to ensure the coordination between the metal cation (Fe3+ and the BTC ligand (BTC = 1,3,5-Benzene Tri Carboxylate. Meanwhile pore analysis using SAA confirmed that MIL-100(Fe obtained by electrolysis method has a BET surface area reached till 569.191 m²/g with a total pore volume of 0.4540 cc/g and an average pore diameter reached 16 Å. Based on SEM analysis, morphology material show particle size between 0.4-8.6 μm and has a thermal stability up to 350 °C according thermo-gravimetric analysis. Due to the presence of Lewis acid sites on Fe-trimeric unit, porosity features on MIL-100(Fe and a fairly high thermal stability, this material is potentially used as the host material for the catalyst in the conversion reactions model for green diesel production.

The San Luis Project: An Attempt to Decentralize Physics in Mexico

Science.gov (United States)

Will, T. A.; Valladares, A. A.

1976-01-01

Described is a project being conducted by the Physics Institute of the University of San Luis Potori, Mexico, in order to avoid concentrating physics education and research activities in Mexico City. (SL)

Mil rosas roubadas, Work of Silviano Santiago a Bakhitinian Analysis

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Renata Coelho Marchezan

2017-10-01

Full Text Available This article analyzes Mil rosas roubadas, written by Silviano Santiago in 2014, dealing with the notions of (autobiography, (autobiographical novel, metafiction and autofiction. Although the creation of this last word may indicate the existence of a new genre – it is even adopted by the writer himself to name his work –, the article shows the pertinence of placing Mil rosas roubadas in the route of the transformations and stylisations of the (autobiographical novel, such as examined by M. Bakhtin. The novel is, for Bakhtin, a genre without rigid forms, an unfinished genre, as it always follows the inflections of social life. In this way the ressemantization of the self, proposed by Silviano Santiago, is analyzed.

76 FR 33362 - Request for Interest in Lease Arrangement on Federal Lands, San Luis Project, Los Banos, California

Science.gov (United States)

2011-06-08

... facilitating environmentally appropriate renewable-energy projects involving solar, wind and waves, geothermal... Federal Lands, San Luis Project, Los Banos, California AGENCY: Bureau of Reclamation, Interior. ACTION... energy project(s) in a lease arrangement on existing Reclamation lands in the vicinity of the San Luis...

MIL-Ti metal-organic frameworks (MOFs) nanomaterials as superior adsorbents: Synthesis and ultrasound-aided dye adsorption from multicomponent wastewater systems.

Science.gov (United States)

Oveisi, Mina; Asli, Mokhtar Alina; Mahmoodi, Niyaz Mohammad

2018-04-05

Herein, 1,4-benzenedicarboxylate (BDC) and 2-amino-1,4-benzenedicarboxylate (NH 2 -BDC) as organic linkers and tetraisopropyl orthotitanate as a metal source were used to synthesize several metal-organic frameworks (MOFs) nanomaterials. Five Materials Institut Lavoisiers (MILs) as MOFs include MIL-125(Ti), NH 2 -MIL-125(Ti) and three MILs with different organic linkers molar ratios (BDC/NH 2 -BDC: 75/25, 50/50 and 25/75 denoted as MIL-X1, MIL-X2 and MIL-X3, respectively). The synthesized nanomaterials were used for ultrasound-aided adsorption of cationic dyes (Basic Red 46 (BR46), Basic Blue 41 (BB41) and Methylene Blue (MB)) from single and multicomponent (binary) systems. The BET, XRD, FTIR, SEM, TEM, TGA and zeta potential were used for characterizing the MILs. Dye removal followed pseudo-second order kinetics with constant rate of 0.20833, 0.00481 and 0.00051 mg/g min for BR46, BB41 and MB, respectively. In addition dye adsorption obeyed the Langmuir isotherm model and the experimental dye adsorption capacity for BR46, BB41 and MB was 1296, 1257 and 862 mg/g, respectively. The synthesized MIL showed high reusability and stability over three cycles. The adsorption thermodynamics data presented that dye removal was a spontaneous, endothermic and physical reaction. The free Gibbs energy for dye removal by the NH 2 -MIL-125(Ti) at 308K was -19.424, -15.721 and -17.413 kJ/mol for BR46, BB41 and MB, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

77 FR 21797 - Hopper Mountain, Bitter Creek, and Blue Ridge National Wildlife Refuges, Ventura, Kern, San Luis...

Science.gov (United States)

2012-04-11

... DEPARTMENT OF THE INTERIOR Fish and Wildlife Service [FWS-R8-R-2011-N253: FXRS12650800000S3-112-FF08R00000] Hopper Mountain, Bitter Creek, and Blue Ridge National Wildlife Refuges, Ventura, Kern, San Luis... acres, primarily in Kern County and extending into San Luis Obispo and Ventura Counties. Blue Ridge NWR...

Commercial production of ethanol in the San Luis Valley, Colorado. Final report

Energy Technology Data Exchange (ETDEWEB)

Hewlett, E.M.; Erickson, M.V.; Ferguson, C.D.; Boswell, B.S.; Walter, K.M.; Hart, M.L.; Sherwood, P.B.

1983-07-01

The commercial feasibility of producing between 76 and 189 million liters (20 to 50 million gallons) of ethanol annually in the San Luis Valley, Colorado using geothermal energy as the primary heat source was assessed. The San Luis Valley is located in south-central Colorado. The valley is a high basin situated approximately 2316 meters (7600 feet) above sea level which contains numerous warm water wells and springs. A known geothermal resource area (IGRA) is located in the east-central area of the valley. The main industry in the valley is agriculture, while the main industry in the surrounding mountains is lumber. Both of these industries can provide feedstocks for the production of ethanol.

Homens, gênero e violência contra a mulher Men, gender and violence against women

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Daniel Costa Lima

2008-06-01

Full Text Available Considerando o compromisso do Estado brasileiro de coibir e prevenir a violência contra a mulher, firmado em várias conferências internacionais e tendo em vista a promulgação da Lei 11.340/06 - a Lei Maria da Penha -, este artigo tem como objetivo realizar uma reflexão sobre a incorporação dos homens e da perspectiva de gênero nos esforços de prevenção e atenção à violência contra as mulheres. Apesar do crescente interesse da literatura científica e da intervenção em saúde com o envolvimento dos homens, em especial, no campo dos direitos sexuais e reprodutivos, comparativamente, reflexões e intervenções com homens autores de violência contra a mulher têm recebido bem menos atenção de órgãos governamentais, não-governamentais e pela academia. O artigo apresenta alguns conceitos e dados sobre a violência contra as mulheres e descreve um panorama sobre a conexão entre gênero, saúde e masculinidades; analisa trabalhos que abordam os temas homens e violência contra as mulheres e apresenta algumas ações voltadas à prevenção dessa forma de violência junto à população masculina; e por fim tece algumas considerações finais sobre o tema.Considering the commitment made by the Brazilian Government to restrain and prevent violence against women, signed in various international conferences, and in view of the promulgation of the Law 11.340/06 - Lei Maria da Penha -, this article intends to develop a reflection on the incorporation of men and of the gender perspective in efforts to prevent and attend to violence against women. Despite the increasing interest of scientific literature and health intervention in the involvement of men, especially in the field of sexual and reproductive rights, comparatively, reflections and interventions directed at men who have committed violence against women have received far less attention from governmental and non-governmental institutions, and from the academy. The article

Petits mils, énorme potentiel : diversifiés, nutritifs et adaptés aux ...

International Development Research Centre (IDRC) Digital Library (Canada)

29 avr. 2016 ... La culture des petits mils en complément des cultures existantes ... Redynamiser la production de petits mils pourrait améliorer la nutrition et la santé en Inde, ... que nécessite leur transformation et de la perception négative que l'on en ... Increasing gender equality among small millet farmers in South Asia.

José Luis Hidalgo, poeta de los muertos

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Román GARCÍA-CAMINO MATEOS

2009-11-01

Full Text Available RESUMEN: La figura de José Luis Hidalgo (Torres, 1919-Madrid, 1947, poeta y pintor, ha de tomar un nuevo relieve como representante de una generación de autores montañeses que surgió en torno a los años cuarenta. Destaca en su breve obra, al igual que su corta pero intensa vida, la extrema sensibilidad de su poesía en el uso de imágenes, metáforas que acercan sus versos hacia el terreno de lo plástico y sensorial. Las preocupaciones son de profunda raigambre existencialista, al ser nuestro poeta un joven lector de pensadores como Nietzsche, Schopenhauer o Unamuno; es con este último con el que guarda una ineludible afinidad de ideas. La búsqueda que emprende José Luis Hidalgo hacia la verdad se sitúa dentro de una metafísica trascendente y una vertiente religiosa muy significativa, en un diálogo sincero y directo con Dios. Contrasta la sencillez formal de su poesía con el complejo sistema simbólico de elementos naturales, espacios... en los que se mueve dentro del marco fluctuante entre la tradición y la vanguardia; encontramos resonancias que nos llevan desde el romanticismo becqueriano, pasando por el simbolismo, hasta los movimientos vanguardistas —sobre todo el surrealismo— y el grupo poético del 27. La obra de Los muertos supone un momento culmen del dilatado periodo de posguerra.ABSTRACT: The literary figure of José Luis Hidalgo (Torres, 1919-Madrid, 1947, both a poet and a painter, achieves renown once more as a representative of a generation of writers from Cantabria (in the north of Spain which came to light around the 1940's. His work, as brief as his short but intense life, is remarkable for the great feeling of his poetry in the use of imagery and metaphors, which draw his verse near the domain of the vivid and sensorial. His concerns have deep existentialist roots; as a young man the poet was a devoted reader of great thinkers such as Nietzsche, Schopenhauer or Unamuno; it is the latter with whom he has an

Evaluating the Implementation of the Re-Engineering Systems of Primary Care Treatment in the Military (RESPECT-Mil)

Science.gov (United States)

Wong, Eunice C.; Jaycox, Lisa H.; Ayer, Lynsay; Batka, Caroline; Harris, Racine; Naftel, Scott; Paddock, Susan M.

2015-01-01

Abstract A RAND team conducted an independent implementation evaluation of the Re-Engineering Systems of Primary Care Treatment in the Military (RESPECT-Mil) Program, a system of care designed to screen, assess, and treat posttraumatic stress disorder and depression among active duty service members in the Army's primary care settings. Evaluating the Implementation of the Re-Engineering Systems of Primary Care Treatment in the Military (RESPECT-Mil) presents the results from RAND's assessment of the implementation of RESPECT-Mil in military treatment facilities and makes recommendations to improve the delivery of mental health care in these settings. Analyses were based on existing program data used to monitor fidelity to RESPECT-Mil across the Army's primary care clinics, as well as discussions with key stakeholders. During the time of the evaluation, efforts were under way to implement the Patient Centered Medical Home, and uncertainties remained about the implications for the RESPECT-Mil program. Consideration of this transition was made in designing the evaluation and applying its findings more broadly to the implementation of collaborative care within military primary care settings. PMID:28083389

Luis Alvarez - a personal approach to physics

Energy Technology Data Exchange (ETDEWEB)

Anon.

1988-12-15

One of the major pioneer figures and outstanding personalities of particle physics, Luis Alvarez, died on 1 September. In addition to his numerous particle physics achievements, he became famous for his ventures in archaeology, palaeontology, and astronomy, and for his inventions. As a tribute to this remarkable man, we publish here some extracts from 'Adventures in Nuclear Physics', given as the 1962 University of California Faculty Research Lecture. According to custom, this presentation is a personalized account rather than an impersonal scientific discourse.

Demonstration of coupling correction below the per-mil limit in the LHC

CERN Document Server

Maclean, Ewen Hamish; Fartoukh, Stephane; Persson, Tobias Hakan Bjorn; Skowronski, Piotr Krzysztof; Tomas Garcia, Rogelio; Wierichs, David Alexander; CERN. Geneva. ATS Department

2016-01-01

Linear coupling between betatron motion in the transverse planes is one of the key optics parameters for any accelerator. It can substantially affect the nonlinear dynamics, influencing both lifetime and the damping of instabilities, as well as affecting the ability to measure and control the linear optics. A review of published material revealed no account of coupling having been corrected significantly below the per-mil level in any hadron accelerator. This note reports the achievement of a sub-per-mil coupling correction during an LHC Machine Development study.

Chromium-based metal-organic framework MIL-101 as a highly effective catalyst in plasma for toluene removal

Science.gov (United States)

Wu, Junliang; Xia, Qibin; Xiao, Jing; Li, Zhong

2017-11-01

Catalytic performance of MIL-101—a type of chromium-based metal-organic frameworks (MOFs)—in a plasma catalysis system for toluene removal was experimentally studied. The MIL-101 was synthesized using a hydrothermal method, and its catalytic performance was compared to two other catalysts, Cr2O3/γ-Al2O3 and γ-Al2O3, in a dielectric barrier discharge (DBD) reactor. Results showed that the presence of a catalyst in plasma changed the voltage and current characteristic substantially, and promoted the performance of the plasma reactor. Among the catalysts, the MIL-101 exhibited a significantly high toluene conversion, which was 20% and 35% higher than Cr2O3/γ-Al2O3 and γ-Al2O3, respectively, under the same testing conditions, as well as higher carbon balance and CO2 selectivity. The analysis of by-products on the surfaces of the catalysts before and after reaction demonstrated that MIL-101 had better resistance towards by-products accumulation compared to Cr2O3/γ-Al2O3 and γ-Al2O3. The loading of MnO x on MIL-101 further promoted its catalytic performance. MIL-101 exhibits attractive catalytic properties as a catalyst in a plasma catalysis system for the decomposition of volatile organic compounds.

Chromium-based metal-organic framework MIL-101 as a highly effective catalyst in plasma for toluene removal

International Nuclear Information System (INIS)

Wu, Junliang; Xia, Qibin; Xiao, Jing; Li, Zhong

2017-01-01

Catalytic performance of MIL-101—a type of chromium-based metal-organic frameworks (MOFs)—in a plasma catalysis system for toluene removal was experimentally studied. The MIL-101 was synthesized using a hydrothermal method, and its catalytic performance was compared to two other catalysts, Cr 2 O 3 / γ -Al 2 O 3 and γ -Al 2 O 3 , in a dielectric barrier discharge (DBD) reactor. Results showed that the presence of a catalyst in plasma changed the voltage and current characteristic substantially, and promoted the performance of the plasma reactor. Among the catalysts, the MIL-101 exhibited a significantly high toluene conversion, which was 20% and 35% higher than Cr 2 O 3 / γ -Al 2 O 3 and γ -Al 2 O 3 , respectively, under the same testing conditions, as well as higher carbon balance and CO 2 selectivity. The analysis of by-products on the surfaces of the catalysts before and after reaction demonstrated that MIL-101 had better resistance towards by-products accumulation compared to Cr 2 O 3 / γ -Al 2 O 3 and γ -Al 2 O 3 . The loading of MnO x on MIL-101 further promoted its catalytic performance. MIL-101 exhibits attractive catalytic properties as a catalyst in a plasma catalysis system for the decomposition of volatile organic compounds. (paper)

Pionero de la comunicación (Entrevista a Luis Ramiro Beltrán

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Juan Braun

2015-01-01

Full Text Available Luis Ramiro es, sin lugar a dudas, el comunicador más reconocido de la América Latina. Sus ideas circulan libremente en el Norte y en el Sur. Es un líder. Pero pocos saben de su vida. Los esfuerzos que tuvo que hacer para "llegar". De sus primeros años de periodista bohemio, su lucha en la Universidad del Estado de Michigan para sobrevivir a las exigencias de Berlo, Kumata, Rogers y Miller. Y la importancia fundamental en todo esto de su madre, Mama Becha. Nos conocimos allá lejos, en Michigan. Luis Ramiro se graduaba de Doctor, terminaba su "vía crucis". El mío apenas comenzaba. Las ideas de Luis, su diagnóstico de la comunicación en América Latina, tuvieron un profundo impacto en mí que se hizo sentir años después. ¡Gracias! ¡y también alcancé a probar las empanadas de Mama Becha! El Dr. Beltrán habla sobre su vida y el pasado, presente y futuro de la comunicación en América Latina.

76 FR 45602 - Proposed Safe Harbor Agreement for California Red-Legged Frog, at Swallow Creek Ranch, San Luis...

Science.gov (United States)

2011-07-29

... DEPARTMENT OF THE INTERIOR Fish and Wildlife Service [FWS-R8-ES-2011-N144; 81440-1113-0000-F3] Proposed Safe Harbor Agreement for California Red-Legged Frog, at Swallow Creek Ranch, San Luis Obispo... Ranch in San Luis Obispo County, California. Within the 620 acres of land comprising the Enrolled...

Selective recognition of 6-mercaptopurine based on luminescent metal-organic frameworks Fe-MIL-88NH₂.

Science.gov (United States)

Sun, Zhengjuan; Liu, Yali; Li, Yuanfang

2015-03-15

A novel and rapid spectrofluorometry method for the recognition of 6-mercaptopurine (6-MP) has been developed based on luminescent metal-organic frameworks Fe-MIL-88NH2 as fluorescent probe. The strong fluorescence of Fe-MIL-88NH2 at 430 nm could be quenched by 6-MP directly, and the Fe-MIL-88NH2 shows high selectivity for 6-MP compared to other thiol-containing amino acids such as homocysteine (Hcy), cysteine (Cys), glutathione (GSH), etc. Under optimal conditions, the relative fluorescence intensity was linearly proportional to the concentration of 6-MP in the range of 5-600 μM with the detection limit at 1.17 μM (S/N=3). Furthermore, the present approach has been successfully applied to the determination of 6-MP in human serum samples. The possible fluorescence quenching mechanism has also been investigated, where it is revealed that the quenching was attributed to competition of absorption of the light source energy as well as electron transfer between Fe-MIL-88NH2 and 6-MP. Copyright © 2014 Elsevier B.V. All rights reserved.

Por uma matriz feminista de gênero para os estudos sobre homens e masculinidades

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Benedito Medrado

2008-09-01

Full Text Available http://dx.doi.org/10.1590/S0104-026X2008000300005 Este artigo tem o objetivo de contribuir para os estudos e pesquisas sobre homens e masculinidades, apresentando um marco conceitual de gênero, a partir de uma matriz que dialoga com produções feministas e se organiza em quatro eixos: 1 o sistema sexo/gênero; 2 a dimensão relacional; 3 as marcações de poder; e 4 a ruptura da tradução do modelo binário de gênero nas esferas da política, das instituições e das organizações sociais. Para tanto, dialogamos com produções contemporâneas que adotam “gênero” como categoria analítica e se baseiam em referenciais teóricos distintos, mas têm em comum (e se autodefinem a partir de uma perspectiva feminista crítica. A partir dessa matriz, traz-se uma análise dos estudos sobre os homens e masculinidades no campo da saúde, sexualidade e reprodução, destacando a necessidade de abrir espaço para novas construções teóricas que resgatem o caráter plural, polissêmico e crítico das leituras feministas.

Distribución del ocelote (Leopardus pardalis en San Luis Potosí, México Distribution of the ocelot (Leopardus pardalis in San Luis Potosí, Mexico

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Jesús Manuel Martínez-Calderas

2011-09-01

Full Text Available Para definir la distribución geográfica del ocelote en el estado de San Luis Potosí, México, se obtuvieron nuevos registros de la especie. El estudio se realizó de enero de 2007 a abril de 2009. Se obtuvieron 41 registros de ocelotes por medio de entrevistas y trampeo-fotográfico. Los registros se localizaron en comunidades vegetales de selva baja caducifolia (37%, matorral submontano (22%, bosque de encino (15%, selva mediana (10%, selva alta perennifolia, bosque mesófilo de montaña, bosque de pino-encino y matorral desértico micrófilo (10%. La presencia de ocelotes se ubicó en los municipios de Ciudad del Maíz, El Naranjo, Cerritos, Guadalcázar, San Nicolás Tolentino y Ciudad Valles en de elevaciones de 38 a 2 400 m snm. Los resultados de esta investigación sugieren una distribución del ocelote más hacia el oeste del estado respecto a su distribución original. El presente estudio definió nuevas regiones con presencia de ocelotes que pueden ser consideradas en el desarrollo de estrategias de conservación de la especie en el estado de San Luis Potosí.To determine the geographic distribution of ocelot in the state of San Luis Potosí, Mexico, we obtained new records. The study was conducted from January 2007 to April 2009. We recorded 41 ocelot records by interviews and camera-trapping. Ocelots records were located in tropical deciduous forest (37%, semitropical thornscrub (22%, oak forest (15%, tropical forest (10%, tall tropical deciduous forest, desert scrub, pine-oak forest and clouded forest (10%. Ocelot records were located in the municipalities of Ciudad del Maíz, El Naranjo, Cerritos, Guadalcazar, San Nicolás Tolentino and Ciudad Valles where the elevation ranged from 38 to 2 400 m. The evidence of this research suggests that ocelot range is more extended to the west than its original geographical range. This study defined new regions with presence of ocelots that may be considered to develop conservation strategies

Commercial production of ethanol in the San Luis Valley, Colorado. Final Report

Energy Technology Data Exchange (ETDEWEB)

Hewlett, E.M.; Erickson, M.V.; Ferguson, C.D.; Sherwood, P.B.; Boswell, B.S.; Walter, K.M.; Hart, M.L.

1983-07-01

The purpose of this study is to assess the commercial feasibility of producing between 76 and 189 million liters (20 and 50 million gallons) of ethanol annually in the San Luis Valley, Colorado using geothermal energy as the primary heat source. The San Luis Valley is located in south-central Colorado. The valley is a high basin situated approximately 2316 meters (7600 feet) above sea level which contains numerous warm water wells and springs. A known geothermal resource area (KGRA) is located in the east-central area of the valley. The main industry in the valley is agriculture, while the main industry in the surrounding mountains is lumber. Both of these industries can provide feedstock for the production of ethanol.

Effective Adsorption and Removal of Phosphate from Aqueous Solutions and Eutrophic Water by Fe-based MOFs of MIL-101.

Science.gov (United States)

Xie, Qiying; Li, Yan; Lv, Zhaoling; Zhou, Hang; Yang, Xiangjun; Chen, Jing; Guo, Hong

2017-06-12

Although many efforts have been devoted to the adsorptive removal of phosphate from aqueous solutions and eutrophic water, it is still highly desirable to develop novel adsorbents with high adsorption capacities. In this study, Fe-based metal-organic frameworks (MOFs), MIL-101 and NH 2 -MIL-101, are fabricated through a general facile strategy. Their performance as an adsorbent for phosphate removal is investigated. Experiments are performed to study the effects of various factors on the phosphate adsorption, including adsorbent dosage, contact time and co-existing ions. Both MIL-101(Fe) and NH 2 -MIL-101(Fe) show highly effective removal of phosphates from aqueous solutions, and the concentration of phosphates decrease sharply from the initial 0.60 mg·L -1 to 0.045 and 0.032 mg·L -1 , respectively, within just 30 min of exposure. The adsorption kinetics and adsorption isotherms reveal that NH 2 -MIL-101(Fe) has higher adsorption capacity than MIL-101(Fe) possibly due to the amine group. Furthermore, the Fe-based MOFs also exhibit a high selectivity towards phosphate over other anions such as chloride, bromide, nitrate and sulfate. Particularly, the prepared Fe-based MIL-101 materials are also capable of adsorbing phosphate in an actual eutrophic water sample and display better removal effect.

Chasing Personal Meaning: Pedagogical Lessons through Luis Rodriguez's "Always Running"

Science.gov (United States)

Theisen-Homer, Victoria

2014-01-01

In this autobiographical narrative, the author recounts her experiences teaching the novel "Always Running" by Luis Rodriguez with her English classes at a high school in a gang-heavy area. When she first started teaching, this teacher struggled to engage students. One particularly disruptive student requested to read "Always…

Luis Alvarez - a personal approach to physics

International Nuclear Information System (INIS)

Anon.

1988-01-01

One of the major pioneer figures and outstanding personalities of particle physics, Luis Alvarez, died on 1 September. In addition to his numerous particle physics achievements, he became famous for his ventures in archaeology, palaeontology, and astronomy, and for his inventions. As a tribute to this remarkable man, we publish here some extracts from 'Adventures in Nuclear Physics', given as the 1962 University of California Faculty Research Lecture. According to custom, this presentation is a personalized account rather than an impersonal scientific discourse

El “indio” don Gaspar Jurado y su lucha por la escribanía de cámara de la Real Audiencia de Lima (1811-1812

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Marissa Bazán Díaz

2015-11-01

Full Text Available El artículo estudia la igualdad jurídica otorgada a los indios y mestizos durante las Cortes de Cádiz, a partir del juicio del “indio” Gaspar Jurado, quien reclamó el acceso al cargo de escribano de cámara de la Real Audiencia de Lima. Este alegato suscitó la oposición de los escribanos españoles a partir del argumento relativo a la confusión en los orígenes de su nacimiento, asociándolo con la casta “zambaiga”. Jurado logró que la sentencia fuera a su favor a partir de la utilización del criterio de igualdad, demostrando la rapidez con la que se difundieron las novedosas disposiciones gaditanas y su interpretación en el imaginario jurídico del imperio hispánico.

Ru Nanoparticles Supported on MIL-101 by Double Solvents Method as High-Performance Catalysts for Catalytic Hydrolysis of Ammonia Borane

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Tong Liu

2015-01-01

Full Text Available Highly dispersed crystalline Ru nanoparticles (NPs were successfully immobilized inside the pores of MIL-101 by a double solvents method (DSM. HRTEM clearly demonstrated the uniform distribution of the ultrafine Ru NPs throughout the interior cavities of MIL-101. The synthesized Ru@MIL-101 catalyst was also characterized by X-ray diffraction (XRD, N2 adsorption desorption, and ICP-AES. The catalytic test indicated that the Ru NPs supported MIL-101 material exhibited exceedingly high activity and excellent durability for hydrogen generation from the catalytic hydrolysis of amine boranes.

Structure and properties of Al-MIL-53-ADP, a breathing MOF based on the aliphatic linker molecule adipic acid.

Science.gov (United States)

Reinsch, Helge; Pillai, Renjith S; Siegel, Renée; Senker, Jürgen; Lieb, Alexandra; Maurin, Guillaume; Stock, Norbert

2016-03-14

The new aluminium based metal-organic framework [Al(OH)(O2C-C4H8-CO2)]·H2O denoted as Al-MIL-53-ADP-lp (lp stands for large pore) was synthesised under solvothermal conditions. This solid is an analogue of the archetypical aluminium terephthalate Al-MIL-53 based on the aliphatic single-chain linker molecule adipic acid (H2ADP, hexanedioic acid). In contrast to its aromatic counterparts, Al-MIL-53-ADP exhibits a structural breathing behaviour solely upon dehydration/rehydration. The crystal structure of the anhydrous compound denoted as Al-MIL-53-ADP-np (np stands for narrow pore) was determined by a combination of forcefield-based computations and Rietveld refinement of the powder X-ray diffraction data while the structure of the hydrated form Al-MIL-53-ADP-lp was derived computationally by a combination of force field based methods and Density Functional Theory calculations. Both structures were further supported by (1)H, (13)C and (27)Al high-resolution NMR MAS 1D data coupled again with simulations. Al-MIL-53-ADP was further characterised by means of vibrational spectroscopy, elemental analysis, thermogravimetry and water vapour sorption.

Luis Patiño Camargo Maestro, Investigador, Humanista

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José Felix Patiño Restrepo

1992-09-01

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Palabras del doctor José Félix Patiño Restrepo, Académico de Número, con motivo de la Sesión Solemne de la Academia Nacional de Medicina para conmemorar el centenario del natalicio del Profesor Luis Patiño Camargo.

Santafé de Bogotá, noviembre 21 de 1991

Son varias las semblanzas que distinguidas personalidades de Colombia y del exterior han escrito sobre el Profesor Luis Patiño Camargo, cuya vida ejemplar dejó honda huella en la medicina y la ciencia colombianas: Carlos Lleras Restrepo y Juan Lozano y Lozano en 1978; Augusto Gast Galvis, Fernando Serpa Flórez y Alfonso Jaram illo Salazar en 1979; Eduardo Guzmán Esponda, Remando Groot y José Francisco Socarrás en 1981; Amador Neghme, de Chile en 1987; Ernesto Andradc Valderrama en 1988, y ahora Carlos Sanmartín Barberi.

“Bella vida y bella muerte la de Luis Patiño Camargo, pensaba yo cuando iba caminando detrás del féretro, después de los sencillos oficios en la iglesia de Iza, hacia el cementerio campesino donde él dispuso que se enterrara en medio de las tumbas de sus padres y debajo de los pinos que plantó con su propia mano”. Así inició Carlos Lleras Restrepo un sentido artículo sobre Patiño Camargo publicado en la Nueva Frontera a los pocos días de su muerte, acaecida en Sogamoso el 13 de noviembre de 1978. Porque ese fue su deseo: reposar para siempre en el cementerio que domina su bello pueblo andino, Iza, donde había nacido el 24 de noviembre de 1891.

Dijo Gast Galvis: “El Dr. Patiño, como el cacique de Inza, después de mucho peregrinar por todo el territorio colombiano, encontró un lugar de brisas tibias, cielo siempre azul, abundantes aguas, suelo fértil, en donde se pudiera vivir y morir en paz”.

Científico, maestro, médico, naturalista, filósofo, humanista, todo eso fue Luis Patiño Camargo, y ninguno de estos términos lo caracteriza de por sí, sino más bien el conjunto de ellos

Barrio residencial de Gratosoglio, Milán

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Giannini, Sandro

1967-04-01

Full Text Available The group of 23 buildings in the residential zone of Gratosoglio, which provide space for 1,000 dwellings, has been built by the firm «Fintech Italcamus». This Italian firms applies in Italy the «Raymond Camus» system, which is a positive aid to heavy prefabrication in housing projects. The above group of buildings constitute part of the General Building Scheme so successfully initiated by the Autonomous Building Institute of the Province of Milan, with the purpose of helping to overcome the extensive lack of housing in the Milan region.El grupo de edificios levantado en el Barrio Residencial de Gratosoglio, Milán (23, con un total de 1.000 viviendas, ha sido construido por la firma «Fintech Italcamus», Sociedad italiana que aplica en Italia el sistema «Raymond Camus» y constituye una aportación positiva de la prefabricación pesada a la edificación residencial. Este conjunto forma parte del Plan General de edificación, emprendido con tanto éxito como acierto por el Instituto Autónomo de la Vivienda de la Provincia de Milán, para solucionar los problemas que la gigantesca presión demográfica planteaba en dicha provincia.

Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

KAUST Repository

Yin, Dongdong; Li, Chuang; Ren, Hangxing; Shekhah, Osama; Liu, Jinxuan; Liang, Changhai

2017-01-01

Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101

Suicídio de homens idosos no Brasil Suicide of elderly men in Brazil

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Maria Cecília de Souza Minayo

2012-10-01

Full Text Available Discute-se o suicídio de homens idosos no Brasil. O texto se fundamenta em estudos de gênero e masculinidades e dá ênfase ao sentido de "masculinidade hegemônica" dentro da lógica do patriarcalismo que, no caso dos suicídios, se expressa na perda do trabalho como referência existencial e no sentido de honra como escudo. O estudo contempla casos de 40 homens que faleceram por suicídio no período entre 2006 a 2009 em dez municípios do país e tinham idade acima de 60 anos. Pela técnica de autópsia psicossocial foram coletados e analisados dados da história e modo de vida; avaliação dos antecedentes; impacto na família; letalidade do método; proximidade de fontes de apoio; tentativas anteriores; estado mental que antecedeu o ato; reações da família e da comunidade. Embora sejam vários os fatores que se associam à morte autoinfligida nesse grupo social, é inegável a importância da cultura masculina hegemônica na preeminência do número de suicídios de homens idosos em relação com as mulheres idosas. É fundamental dar atenção especial aos homens nos momentos de passagem da vida laboral para a aposentadoria, nas situações de perdas de familiares referenciais e quando são diagnosticados com enfermidades crônicas degenerativas que provoquem deficiências, perda de autonomia ou impotência sexual.This paper assesses the suicide of elderly men in Brazil. The text is based on studies of gender and masculinity and emphasizes the sense of "hegemonic masculinity" within the logic of patriarchalism that, in the case of suicide, is expressed in the loss of employment as an existential reference and as a loss of honor. The study includes 40 cases of men over 60 who committed suicide between 2007 and 2010 in ten districts of the country. Using the psychosocial autopsy technique, data were collected and analyzed from their history and lifestyle; evaluation of the background to the act; the impact on their families; lethality

MIL-L-87177 and CLT:X-10 Lubricants Improve Electrical Connector Fretting Corrosion Behavior

International Nuclear Information System (INIS)

AUKLAND, NEIL R.; HANLON, JAMES T.

1999-01-01

We have conducted a fretting research project using MIL-L-87177 and CLT: X-10 lubricants on Nano-miniature connectors. When they were fretted without lubricant, individual connectors first exceeded our 0.5 ohm failure criteria from 2,341 to 45,238 fretting cycles. With additional fretting, their contact resistance increased to more than 100,000 ohms. Unmodified MIL-L-87177 lubricant delayed the onset of first failure to between 430,000 and over 20,000,000 fretting cycles. MIL-L-87177 modified by addition of Teflon powder delayed first failure to beyond 5 million fretting cycles. Best results were obtained when Teflon was used and also when both the straight and modified lubricants were poured into and then out of the connector. CLT: X-10 lubricant delayed the onset of first failure to beyond 55 million cycles in one test where a failure was actually observed and to beyond 20 million cycles in another that was terminated without failure. CLT: X-10 recovered an unlubricated connector driven deeply into failure, with six failed pins recovering immediately and four more recovering during an additional 420 thousand fretting cycles. MIL-L-87177 was not able to recover a connector under similar conditions

Geology and petrography of the Socoscora Sierra . Province of San Luis. Republica Argentina

International Nuclear Information System (INIS)

Carugno Duran, A.

1998-01-01

The following paper include an study geological and petrographic of the Sierra de Socoscora. San Luis, Argentina. This mountainas is a block with less elevation that the Sierra de San Luis, and it located in the west center of it. It' s formed by an crystalline basement composed by metamorphic haigh grade rocks, with a penetrative foliation of strike N-S. in this context is possible to define petrographicly the following units, migmatitic that fill a big part of the mountain, amphibolites, marbles, skarns, milonites and pegmatites. This units have amphibolitic facies assemblanges mineral and in some them, we can observe retrograde metamorphism of the greesnschist facies. The metamorphic structure is complex and evidence at least three deformation event

Social Integration and Health Behavioral Change in San Luis, Honduras

Science.gov (United States)

McQuestion, Michael J.; Calle, Ana Quijano; Drasbek, Christopher; Harkins, Thomas; Sagastume, Lourdes J.

2010-01-01

This study explores the effects of social integration on behavioral change in the course of an intensive, community-based public health intervention. The intervention trained volunteers and mobilized local organizations to promote 16 key family health practices in rural San Luis, Honduras, during 2004 to 2006. A mixed methods approach is used.…

Expansão espacial da leishmaniose visceral americana em São Luis, Maranhão, Brasil Space expansion of the American visceral leishmaniasis in São Luis, Maranhão, Brazil

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Wellington da Silva Mendes

2002-06-01

Full Text Available Descreve-se a ocupação espacial no município de São Luis e a expansão da leishmaniose visceral americana(LVA na mesma. Foram analisadas as fichas de registro de atendimento de casos de leishmaniose visceral da Diretoria Regional da Fundação Nacional de Saúde do Maranhão no período de setembro de 1982 a dezembro de 1996, assim como documentos oficiais sobre a ocupação espacial do município. Foi observado que os casos de LVA ao longo da evolução da epidemia em São Luis apresentaram distribuição espacial e concentração semelhantes a apresentada pelo fluxo migratório na cidade no mesmo período.The space occupation and the expansion of American visceral leishmaniasis (AVL were described in the municipality of São Luis, Maranhão, Northeast Brazil. AVL medical notes from the Fundação Nacional de Saúde as well as official documents about the space occupation were analyzed from September 1982 to December 1996. AVL cases were more likely to occur in recently settled suburbs and tended to follow the same spatial pattern observed for land occupations secondary to migratory fluxes.

CuNi NPs supported on MIL-101 as highly active catalysts for the hydrolysis of ammonia borane

Science.gov (United States)

Gao, Doudou; Zhang, Yuhong; Zhou, Liqun; Yang, Kunzhou

2018-01-01

The catalysts containing Cu, Ni bi-metallic nanoparticles were successfully synthesized by in-situ reduction of Cu2+ and Ni2+ salts into the highly porous and hydrothermally stable metal-organic framework MIL-101 via a simple liquid impregnation method. When the total amount of loading metal is 3 × 10-4 mol, Cu2Ni1@MIL-101 catalyst shows higher catalytic activity comparing to CuxNiy@MIL-101 with different molar ratio of Cu and Ni (x, y = 0, 0.5, 1.5, 2, 2.5, 3). Cu2Ni1@MIL-101 catalyst has the highest catalytic activity comparing to mono-metallic Cu and Ni counterparts and pure bi-metallic CuNi nanoparticles in hydrolytic dehydrogeneration of ammonia borane (AB) at room temperature. Additionally, in the hydrolysis reaction, the Cu2Ni1@MIL- 101 catalyst possesses excellent catalytic performances, which exhibit highly catalytic activity with turn over frequency (TOF) value of 20.9 mol H2 min-1 Cu mol-1 and a very low activation energy value of 32.2 kJ mol-1. The excellent catalytic activity has been successfully achieved thanks to the strong bi-metallic synergistic effects, uniform distribution of nanoparticles and the bi-functional effects between CuNi nanoparticles and the host of MIL-101. Moreover, the catalyst also displays satisfied durable stability after five cycles for the hydrolytically releasing H2 from AB. The non-noble metal catalysts have broad prospects for commercial applications in the field of hydrogen-stored materials due to the low prices and excellent catalytic activity.

The studies on gas adsorption properties of MIL-53 series MOFs materials

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Yuqiu Jiao

2017-08-01

Full Text Available Molecular dynamics (MD, grand canonical Monte Carlo (GCMC and ideal adsorbed solution theory (IAST were used to study the structures and gas adsorption properties of MIL-53(M[M=Cr, Fe, Sc, Al] metal organic framework (MOF materials. The results show that the volumes of those MOF materials increase significantly at high temperature. By analyzing the adsorption isotherms, we found that the temperature had a paramount effect on the gas adsorption behaviors of these MOF materials. For MIL-53(Cr, the orders of the quantities of adsorbed gases were CH4>N2>CO2>H2S, CH4>H2S>CO2>N2 and CH4>CO2>H2S>N2 at 100K, 293K and 623K, respectively. We also calculated the adsorption of several combinations of two gases by MIL-53(Cr at 293K, the results indicate that the material had selective adsorption of CH4 over CO2, H2S and N2. Our calculations provide microscopic insights into the gas adsorption performances of these MOFs and may further guide the practice of gas separation.

The studies on gas adsorption properties of MIL-53 series MOFs materials

Science.gov (United States)

Jiao, Yuqiu; Li, Zhenyu; Ma, Yue; Zhou, Guanggang; Wang, Shuangxi; Lu, Guiwu

2017-08-01

Molecular dynamics (MD), grand canonical Monte Carlo (GCMC) and ideal adsorbed solution theory (IAST) were used to study the structures and gas adsorption properties of MIL-53(M)[M=Cr, Fe, Sc, Al] metal organic framework (MOF) materials. The results show that the volumes of those MOF materials increase significantly at high temperature. By analyzing the adsorption isotherms, we found that the temperature had a paramount effect on the gas adsorption behaviors of these MOF materials. For MIL-53(Cr), the orders of the quantities of adsorbed gases were CH4>N2>CO2>H2S, CH4>H2S>CO2>N2 and CH4>CO2>H2S>N2 at 100K, 293K and 623K, respectively. We also calculated the adsorption of several combinations of two gases by MIL-53(Cr) at 293K, the results indicate that the material had selective adsorption of CH4 over CO2, H2S and N2. Our calculations provide microscopic insights into the gas adsorption performances of these MOFs and may further guide the practice of gas separation.

Post-synthetic modification of MIL-101(Cr) with pyridine for high-performance liquid chromatographic separation of tocopherols.

Science.gov (United States)

Yang, Fang; Yang, Cheng-Xiong; Yan, Xiu-Ping

2015-05-01

Effective separation of tocopherols is challenging and significant due to their structural similarity and important biological role. Here we report the post-synthetic modification of metal-organic framework (MOF) MIL-101(Cr) with pyridine for high-performance liquid chromatographic (HPLC) separation of tocopherols. Baseline separation of four tocopherols was achieved on a pyridine-grafted MIL-101(Cr) packed column within 10 min using hexane/isopropanol (96:4, v/v) as the mobile phase at a flow rate of 0.5 mL min(-1). The pyridine-grafted MIL-101(Cr) packed column gave high column efficiency (85,000 plates m(-1) for δ-tocopherol) and good precision (0.2-0.3% for retention time, 1.8-3.4% for peak area, 2.6-2.7% for peak height), and also offered much better performance than unmodified MIL-101(Cr) and commercial amino-bonded silica packed column for HPLC separation of tocopherols. The results not only show the promising application of pyridine-grafted MIL-101(Cr) as a novel stationary phase for HPLC separation of tocopherols, but also reveal a facile post-modification of MOFs to expand the application of MOFs in separation sciences. Copyright © 2015 Elsevier B.V. All rights reserved.

Doctor Ramón Luis Miranda Torres, su relación con las neurociencias

OpenAIRE

Hodelín Tablada,Ricardo

2005-01-01

Objetivo: en el presente trabajo se reseña la relación del doctor Ramón Luis Miranda con las neurociencias, dirigido a destacar su inclinación por estas disciplinas. Desarrollo: conocido en la historiografía médica como el médico de José Martí el apóstol cubano el doctor Ramón Luis Miranda Torres, se destacó en otros aspectos poco divulgados, por lo que opinamos que no se le ha otorgado su verdadera dimensión. Nacido en la ciudad de Matanzas, Cuba, estudió medicina en Francia y desde sus años...

Los avisos para la muerte de Luis Ramirez de Arellano

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Inmaculada Osuna

2009-01-01

Full Text Available Avisos para la muerte (1634, compiled by Luis Ramírez de Arellano, gathers, along with other complementary materials (among these, two prayers written in verse for before confession and before communion, and an act of contrition in prose, thirty poems that are presented as models for prayers addressed to a crucified Christ in the moment of his death. These poems emerge from a group initiative in which notable poets from the Madrid court took part, poets such as Lope de Vega, Pedro Calderón de la Barca, José de Pellicer, José de Valdivielso, Luis Vélez de Guevara, Juan Pérez de Montalbán and Francisco de Rojas Zorrilla. My article examines the social context in which this poetic collection is born, the composition of the book, its successful publishing history throughout two centuries as well as the reiterative representation in the poems of particular meditatio mortis topics (the staging of agony; the expression of repentance, love for Christ and hope for his mercy; and the contemplation of Christ’s body on the cross.

MIL-HDBK-338: Environmental Conversion Table Correction

Science.gov (United States)

Hark, Frank; Novack, Steven

2017-01-01

In reliability analysis, especially for launch vehicles, limited data is frequently a problem. Component data from other environments must be used. MIL-HBK-338 has a matrix showing the conversation between environments. Due to round off the conversions are not commutative, converting from A to B will not equal converting from B to A. Agenda: Introduction to environment conversions; Original table; Original table with edits; How big is the problem?; First attempt at correction; Proposed solution.

Moessbauer, TEM/SAED and XRD investigation on waste dumps of the Valea lui Stan gold mines

Energy Technology Data Exchange (ETDEWEB)

Constantinescu, Serban Grigore, E-mail: sconst@infim.ro [National Institute of Materials Physics, Bucharest-Magurele (Romania); Udubasa, Sorin S.; Udubasa, Gheorghe [University of Bucharest, Fac. of Geology and Geophysics (Romania); Kuncser, Victor; Popescu-Pogrion, Nicoleta; Mercioniu, Ionel; Feder, Marcel [National Institute of Materials Physics, Bucharest-Magurele (Romania)

2012-03-15

The complementary investigation techniques, Moessbauer spectroscopy, transmission electron microscopy with selected area electron diffraction (TEM/SAED), X-ray diffraction (XRD) have been used to investigate the fate of the Valea lui Stan, Romania, gold-ore nanoscale-minerals during the long time of residence in the waste dumps. The preliminary investigations showed such waste dumps to contain significant amount of metals which cannot be identified by conventional methods. An intense research activity started up in order to evaluate the possibilities to recycle Valea lui Stan waste dumps and to recover metals by chemical or phytoextraction procedures. The waste dumps naturally show different mineral constituents with clay minerals as major phases, observed by XRD-technique. Although the waste dumps materials have whitish-yellowish colours, MOeSSBAUER technique evidences the presence of the finely dispersed iron bearing minerals. The authors are focusing to inspect and analyze Fe-compounds in the samples collected from Valea lui Stan's waste dumps in order to identify the magnetic phases by Moessbauer technique.

“Faz tempo que você é velhinho?” – Ou... das memórias do vivido nos encontros e encantamentos com a Rede de Educação Infantil de Gaspar

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Adilson Ângelo Lopes Francisco

2012-07-01

Full Text Available http://dx.doi.org/10.5007/1980-4512.2012n26p91 A motivação para escrever o presente texto vem do desejo de partilhar as experiências dos nossos encontros e dos nossos encantamentos com a Rede de Educação Infantil de Gaspar. O que possibilitou este encontro foi o espaço do estágio curricular do curso de Pedagogia - na Universidade do Estado de Santa Catarina (FAED/UDESC - no âmbito da  Atividade interdisciplinar realizada nos semestres 2011.1 e 2011.2, em parceria com as professoras Geysa S. A. Abreu e Julice Dias, reunindo as disciplinas “Prática de Ensino I”, “Estrutura e Fundamentos da Educação Infantil” e “A Criança, a Natureza e a Sociedade”. onde temos construído e partilhado com o/as estagiárias o nosso desejo de pensarmos e de fazermos Educação Infantil com qualidade e competência.   Abstract The motivation for writing this text comes from the desire to share the experiences of our meetings and our enchantment with the Early Childhood Education of the municipality of Gaspar. What enabled this meeting was the space of the traineeship the Faculty of Education at the University of Santa Catarina (UDESC - as part of interdisciplinary activity performed in the six 2011.1 and 2011.2, in partnership with teachers Geysa S. A. Abreu and Julice Days, bringing together the disciplines "Teaching Practice I", "Structure and Foundations of Early Childhood Education" and "Children, Nature and Society." where we have built and shared with the trainees our desire to think and make early childhood education with quality and competence.

Programming MIL-101Cr for selective and enhanced CO2 adsorption at low pressure by postsynthetic amine functionalization.

Science.gov (United States)

Khutia, Anupam; Janiak, Christoph

2014-01-21

MIL-101Cr fully or partially (p) postsynthetically modified with nitro (-NO2) or amino (-NH2) groups was shown to be a robust, water stable, selective and enhanced carbon dioxide (CO2) adsorption material with the amine-functionality. The highly microporous amine-modified frameworks (up to 1.6 cm(3) g(-1) total pore volume) exhibit excellent thermal stability (>300 °C) with BET surface areas up to 2680 m(2) g(-1). At 1 bar (at 273 K) the gases CO2, CH4 and N2 are adsorbed up to 22.2 wt%, 1.67 wt% and 2.27 wt%, respectively. The two amine-modified MIL-101Cr-NH2 (4) and MIL-101Cr-pNH2 (5) showed the highest gas uptake capacities in the series with high ratios for the CO2 : N2 and CO2 : CH4 selectivities (up to 119 : 1 and 75 : 1, respectively, at 273 K). Comparison with non-modified MIL-101Cr traces the favorable CO2 adsorption properties of MIL-101Cr-NH2 (4) and MIL-101Cr-pNH2 (5) to the presence of the Lewis-basic amine groups. MIL-101Cr-NH2 (4) has a high isosteric heat of adsorption of 43 kJ mol(-1) at zero surface coverage and also >23 kJ mol(-1) over the entire adsorption range, which is well above the heat of liquefaction of bulk CO2. Large CO2 uptake capacities of amine-functionalized 4 and 5, coupled with high adsorption enthalpy, high selectivities and proven long-term water stability, make them suitable candidates for capturing CO2 at low pressure from gas mixtures including the use as a CO2 sorbent from moist air.

Brønsted instead of Lewis acidity in functionalized MIL-101Cr MOFs for efficient heterogeneous (nano-MOF) catalysis in the condensation reaction of aldehydes with alcohols.

Science.gov (United States)

Herbst, Annika; Khutia, Anupam; Janiak, Christoph

2014-07-21

Porous chromium(III) 2-nitro-, 2-amino-, and nonfunctionalized terephthalate (MIL-101Cr) metal organic frameworks are heterogeneous catalysts for diacetal formation from benzaldehyde and methanol (B-M reaction) as well as other aldehydes and alcohols. MIL-101Cr-NO2 obtained by direct reaction between CrO3 and 2-nitro-terephthalate showed the highest activity with 99% conversion in the B-M reaction in 90 min and turnover numbers of 114. The activity decreased in the order MIL-101Cr-NO2 > MIL-101Cr > MIL-101Cr-NH2. Within different samples of nonfunctionalized MIL-101Cr the activity increased with surface area. Methanol gas sorption of the different MIL materials correlates with the BET surface area and pore volume but not with the diacetalization activity. Benzaldehyde adsorption from heptane showed no significant difference for the different MILs. Gas sorption studies of CD3CN to probe for a higher Lewis acidity in MIL-101Cr-NO2 remained inconclusive. A high B-M catalytic activity of wet MIL-101Cr-NO2 excluded significant contributions from coordinatively unsaturated Lewis-acid sites. pH measurements of methanol dispersions of the MIL materials gave the most acidic pH (as low as 1.9) for MIL-101Cr-NO2, which significantly increased over MIL-101Cr (3.0) to MIL-101Cr-NH2 (3.3). The increase in acidity is of short range or a surface effect to the heterogeneous MIL particles as protons dissociating from the polarized aqua ligands (Cr-OH2) have to stay near the insoluble counteranionic framework. The variation in Brønsted acidity of MIL-101Cr-NO2 > MIL-101Cr ≈ MIL-101Cr-NH2 correlates with the withdrawing effect of NO2 and the diacetalization activity. The catalytic B-M activity of soluble, substitution-inert, and acidic Cr(NO3)3·9H2O supports the Brønsted-acid effect of the MIL materials. Filtration and centrifugation experiments with MIL-101Cr-NO2 revealed that about 2/3 of the catalytic activity comes from nano-MOF particles with a diameter below 200 nm. The MIL

O efeito da infidelidade sobre a atratividade facial de homens e mulheres The effect of infidelity on male and female facial attractiveness

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Rosana Suemi Tokumaru

2010-04-01

Full Text Available Os estudos da atratividade e da seleção de parceiros têm recebido atenção especial dentro da perspectiva da Psicologia Evolucionista, mostrando influências tanto de fatores físicos quanto de fatores não-físicos. Neste estudo, utilizou-se de fotografias da face de homens e mulheres, pré-julgados como medianamente atraentes, desconhecidos dos participantes, associadas a uma história neutra ou que envolvia comportamento de infidelidade, para avaliar a influência de informação sobre o comportamento de infidelidade na avaliação da atratividade de indivíduos do sexo oposto. Os resultados mostraram diferenças significativas apenas quando as mulheres avaliavam fotografias de homens, atribuindo menor atratividade a homens associados à história de infidelidade. As diferenças entre homens e mulheres podem refletir mecanismos adaptativos para a avaliação da atratividade do sexo oposto relacionados às diferenças nos custos reprodutivos. Esses resultados são discutidos sob a perspectiva da Psicologia Evolucionista.Studies of attractiveness and mate selection have received special attention within the Evolutionary Psychology perspective, showing influences from both physical and non-physical factors. In the present study, we used photographs showing faces of men and women, pre-judged as median attractive people, unknown to the participants, associated with neutral stories or stories involving infidelity behavior, to investigate the influence of information about infidelity behavior on the evaluation of attractiveness of opposite sex individuals. Results showed significant differences only when women evaluated men's photographs, attributing lower attractiveness to men associated with a story of infidelity. The sex differences found may represent adapted mechanisms to evaluate opposite sex attractiveness related to differences in reproductive costs. These results are discussed mainly under the Evolutionary Psychology perspective.

Post synthetic modification of MIL-101(Cr) for S-shaped isotherms and fast kinetics with water adsorption

International Nuclear Information System (INIS)

Teo, How Wei Benjamin; Chakraborty, Anutosh; Kayal, Sibnath

2017-01-01

Highlights: • Modification of parent MIL-101(Cr) metal organic framework (MOF) employing alkali metal ions (Li + , Na + , K + ). • Surface characteristics of the parent and alkali doped MIL-101(Cr) adsorbents. • Water uptakes are measured for the temperatures ranging from 25 °C to 60 °C under static and dynamic conditions. • Isotherms and kinetics data are fitted with Langmuir analogy models. • The 5% Li-doped MIL-101(Cr) is suitable for adsorption cooling. - Abstract: This article presents the surface characteristics of alkali (Li + , Na + , K + ) doped MIL-101(Cr) metal organic frameworks (MOFs), and the structural properties are evaluated by scanning electron micrography (SEM), X-ray diffraction (XRD), thermo-gravimetric analyser (TGA) and N 2 adsorption analysis. The amount of water uptakes are measured by a gravimetric analyser for the temperatures ranging from 298 K to 333 K and pressures up to the saturated conditions. The experimentally measured isotherms and kinetics data are fitted with the equations developed from the concept of Langmuir analogy. The isosteric heat of adsorption is calculated employing Van’t Hoff equation in the pressure-temperature-uptake co-ordinate systems. The hydrophobic length at low pressure regions is shortened by the addition of alkali dopants. It is observed that the alkali (Na, K and Li) ions on MIL-101(Cr) MOF increase the water uptakes at lower relative pressure region with fast kinetics. We have shown here that the alkali doped MIL-101(Cr) MOFs can be used as potential adsorbents for various low temperature heat transmission applications such as adsorption assisted heat pump, cooling and desalination.

Neuroimaging Features of San Luis Valley Syndrome

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Matthew T. Whitehead

2015-01-01

Full Text Available A 14-month-old Hispanic female with a history of double-outlet right ventricle and developmental delay in the setting of recombinant chromosome 8 syndrome was referred for neurologic imaging. Brain MR revealed multiple abnormalities primarily affecting midline structures, including commissural dysgenesis, vermian and brainstem hypoplasia/dysplasia, an interhypothalamic adhesion, and an epidermoid between the frontal lobes that enlarged over time. Spine MR demonstrated hypoplastic C1 and C2 posterior elements, scoliosis, and a borderline low conus medullaris position. Presented herein is the first illustration of neuroimaging findings from a patient with San Luis Valley syndrome.

Au3+/Au0 Supported on Chromium(III Terephthalate Metal Organic Framework (MIL-101 as an Efficient Heterogeneous Catalystfor Three-Component Coupling Synthesis of Propargylamines

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Lili Liu

2017-01-01

Full Text Available Post-synthesis modification is a useful method for the functionalization of metal–organic frameworks (MOFs. A novel catalyst Au@MIL-101-ED-SA (ED = ethylenediamine, SA = salicylaldehyde, containing coexisting Au3+ ions and Au0 nanoparticles, was prepared successfully by post-synthesis modification with ethylenediamine, salicylaldehyde and gold. Gold nanoparticles supported on MIL-101 (Au@MIL-101 were prepared successfully by the impregnation method. Au@MIL-101-ED-SA and Au@MIL-101 were characterized by N2 adsorption–desorption, X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy, and inductively coupled plasma-optical emission spectrometry. Au@MIL-101-ED-SA and Au@MIL-101 were applied as environmentally friendly catalysts in the three-component coupling reaction of aldehydes, amines, and alkynes for the preparation of diverse propargylamines. Au@MIL-101-ED-SA contained a fraction of cationic gold (Au3+/Au0 = 0.9 and showed higher catalytic activity than Au@MIL-101, which was prepared by the impregnation method. Furthermore, the reactions were performed under heterogeneous conditions and the novel catalyst was successfully recycled for four consecutive runs.

Luis Alcoriza o la mexicanización del exiliado cinematográfico republicano = Luis Alcoriza or the Mexican Nationalization of the Republican Cinematography Exile

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Jorge Chaumel Fernández

2016-03-01

Full Text Available Luis Alcoriza,  exiliado republicano español en México, desarrolló su carrera como  actor, guionista y director en su patria de adopción dándola algunas de sus mejores películas. En su condición de exiliado dispuso de mayor objetividad para mostrar los cambios de la sociedad mexicana y de sus principales problemas políticos. Figura imprescindible de la evolución del Cine Mexicano  de  la segunda mitad del siglo XX, se configura como uno de los principales ejemplos del  fenómeno de mexicanización de los cineastas exiliados.Luis Alcoriza, Spanish republican exile in Mexico, developed his career as an actor, writer and director in his adopted country giving her some of his best films. In his exile he had before as objective to show the changes in Mexican society and its major political problems. Essential figure in the evolution of Mexican cinema in the second half of the twentieth century stands as one of the prime examples of the phenomenon of mexicanización of exiled filmmakers.

MIL-100-Fe derived N-doped Fe/Fe3C@C electrocatalysts for efficient oxygen reduction reaction

Science.gov (United States)

Guo, Dakai; Han, Sancan; Wang, Jiacheng; Zhu, Yufang

2018-03-01

N-doped porous Fe/Fe3C@C electrocatalysts were prepared by the pyrolysis of the hexamethylenetetramine (HMT)-incorporated MIL-100-Fe at different temperatures (700-1000 °C) under N2 atmosphere. Rotary evaporation of MIL-100-Fe and HMT solution could make more N-enriched HMT molecules enter into the pores of MIL-100-Fe, thus improving nitrogen contents of the final pyrolyzed samples. All pyrolyzed samples show porous textures with middle specific surface areas. The X-ray photoelectron spectroscopy (XPS) results demonstrate the successful introduction of N atoms into carbon framework. Sample Fe-N2-800 prepared by annealing the precursors with the HMT/MIL-100-Fe weight ratio of 2 at 800 °C exhibits the best electrocatalytic activity towards the oxygen reduction reaction (ORR) in terms of onset potential and current density because of high graphitic N and pyridinic N content. The enwrapped Fe/Fe3C nanoparticles and Fe-Nx active sites in these samples could also boost the ORR activity synergistically. Moreover, sample Fe-N2-800 demonstrates a dominant four electron reduction process, as well as excellent long-term operation stability and methanol crossover resistance. Thus, the N-doped Fe/Fe3C@C composites derived from the HMT-incorporated MIL-100-Fe are promising electrocatalysts to replace Pt/C for ORR in practical applications.

Future Drinking Water Supply, Spatial Analysis and Vulnerability of the City of San Luis Potosi, Mexico

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Carlos Contreras Servín

2008-01-01

Full Text Available This paper discusses and presents the physical, social and economic circumstances that affect the overall picture and the current issues that involve the drinking water supply for the metropolitan area of San Luis Potosi. The relationship between water availability and increasing population, as well as the evolution of the groundwater extraction, are among the topics addressed here. Additionally, this research shows a diagnosis of the current situation of the drinking water supply in San Luis Potosi and the surrounding areas, as well as the likely scenario in the near future.

Airborne electromagnetic and magnetic survey data of the Paradox and San Luis Valleys, Colorado

Science.gov (United States)

Ball, Lyndsay B.; Bloss, Benjamin R.; Bedrosian, Paul A.; Grauch, V.J.S.; Smith, Bruce D.

2015-01-01

In October 2011, the U.S. Geological Survey (USGS) contracted airborne magnetic and electromagnetic surveys of the Paradox and San Luis Valleys in southern Colorado, United States. These airborne geophysical surveys provide high-resolution and spatially comprehensive datasets characterizing the resistivity structure of the shallow subsurface of each survey region, accompanied by magnetic-field information over matching areas. These data were collected to provide insight into the distribution of groundwater brine in the Paradox Valley, the extent of clay aquitards in the San Luis Valley, and to improve our understanding of the geologic framework for both regions. This report describes these contracted surveys and releases digital data supplied under contract to the USGS.

Luis Buñuel: trascendiendo el tópico

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Dr. Manuel Carlos Fernández Sánchez

2001-01-01

Full Text Available En 1900 nace el cineasta Luis Buñuel en Calanda, Aragón. En el año 2000 se celebró en distintos ámbitos cinematográficos y televisivos de todo el mundo el centenario de su nacimiento. Festivales de cine, cadenas de televisión por satélite u onda hertziana, periódicos y revistas se hacen eco de la enorme trascendencia del lenguaje cinematográfico buñueliano. Este estudio sobre la última de sus películas rodada en Andalucía, concretamente en Sevilla, pretende aportar un nuevo análisis sobre esta obra que trascendió el tópico andaluz.ABSTRACIn 1900 the film director Luis Buñuel is born in Calanda, Aragón. In 2000, it took place the centennial of his birth in different film and television environments in all over the world. The transcendency of film languaje used by Buñuel has been anlysed in cinema festivals, television, newspapers and magazines. This study, focus on his last movies filmed in Andalusia, concretely in Seville, it seeks to contribute with a new analysis on this work that transcended the Andalusian topic.

Theoretical investigations on the high light yield of the LuI3:Ce scintillator

International Nuclear Information System (INIS)

Vasil'ev, A.N.; Iskandarova, I.M.; Scherbinin, A.V.; Markov, I.A.; Bagatur'yants, A.A.; Potapkin, B.V.; Srivastava, A.M.; Vartuli, J.S.; Duclos, S.J.

2009-01-01

The extremely high scintillation efficiency of lutetium iodide doped by cerium is explained as a result of at least three factors controlling the energy transfer from the host matrix to activator. We propose and theoretically validate the possibility of a new channel of energy transfer to excitons and directly to cerium, namely the Auger process when Lu 4f hole relaxes to the valence band hole with simultaneous creation of additional exciton or excitation of cerium. This process should be efficient in LuI 3 , and inefficient in LuCl 3 . To justify this channel, we perform calculations of density of states using a periodic plane-wave density functional approach. The second factor is the increase of the efficiency of valence hole capture by cerium in the row LuCl 3 -LuBr 3 -LuI 3 . The third one is the increase of the efficiency of energy transfer from self-trapped excitons to cerium ions in the same row. The latter two factors are verified by cluster ab initio calculations. We estimate either the relaxation of these excitations and barriers for the diffusion of self-trapped holes (STH) and self-trapped exciton (STE). The performed estimations theoretically justify the high LuI 3 :Ce 3+ scintillator yield.

Metal organic framework MIL-101(Cr) for dehydration reactions

Indian Academy of Sciences (India)

under vapour phase conditions in the temperature range of 513–533 K and time on stream (TOS) at 513 K. Cr-MIL-101 ... gies and potential applications in gas storage, sep- aration ... these materials have not been explored much. Recently .... The products were collected in ice cold trap and ... There is no change in the crys-.

Ni-Pt nanoparticles growing on metal organic frameworks (MIL-96) with enhanced catalytic activity for hydrogen generation from hydrazine at room temperature.

Science.gov (United States)

Wen, Lan; Du, Xiaoqiong; Su, Jun; Luo, Wei; Cai, Ping; Cheng, Gongzhen

2015-04-07

Well-dispersed bimetallic Ni-Pt nanoparticles (NPs) with different compositions have been successfully grown on the MIL-96 by a simple liquid impregnation method using NaBH4 as the reducing agent. Powder X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy, N2 adsorption-desorption, and inductively coupled plasma-atomic emission spectroscopy measurements were employed to characterize the NiPt/MIL-96. Catalytic activity of NiPt/MIL-96 catalysts was tested in the hydrogen generation from the aqueous alkaline solution of hydrazine at room temperature. These catalysts are composition dependent on their catalytic activity, while Ni64Pt36/MIL-96 exhibits the highest catalytic activity among all the catalysts tested, with a turnover frequency value of 114.3 h(-1) and 100% hydrogen selectivity. This excellent catalytic performance might be due to the synergistic effect of the MIL-96 support and NiPt NPs, while NiPt NPs supported on other conventional supports, such as SiO2, carbon black, γ-Al2O3, poly(N-vinyl-2-pyrrolidone) (PVP), and the physical mixture of NiPt and MIL-96, all of them exhibit inferior catalytic activity compared to that of NiPt/MIL-96.

Exposiciones: Capuleto en la sala "Luis Ángel Arango"

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Arístides Meneghetti

1958-07-01

Full Text Available La exposición del joven pintor español Francisco Capuleto, realizada en la Biblioteca "Luis Ángel Arango" el pasado mes de mayo, refresca un viejo problema en la conciencia de todo americano. Existen dos Españas diferentes, la una folclórica, de aire flamenco, majas y alegres panderetas, creada para la exportación y el turismo, a que son tan afectas las personas.

Research of mercury removal from sintering flue gas of iron and steel by the open metal site of Mil-101(Cr).

Science.gov (United States)

Zhao, Songjian; Mei, Jian; Xu, Haomiao; Liu, Wei; Qu, Zan; Cui, Yong; Yan, Naiqiang

2018-06-05

Metal-organic frameworks (MOFs) adsorbent Mil-101(Cr) was introduced for the removal of elemental mercury from sintering flue gas. Physical and chemical characterization of the adsorbents showed that MIL-101(Cr) had the largest BET surface area, high thermal stability and oxidation capacity. Hg 0 removal performance analysis indicated that the Hg 0 removal efficiency of MIL-101(Cr) increased with the increasing temperature and oxygen content. Besides, MIL-101(Cr) had the highest Hg 0 removal performance compared with Cu-BTC, UiO-66 and activated carbon, which can reach about 88% at 250 °C. The XPS and Hg-TPD methods were used to analyze the Hg 0 removal mechanism; the results show that Hg 0 was first adsorbed on the surface of Mil-101(Cr), and then oxidized by the open metal site Cr 3+ . The generated Hg 2+ was then combined surface adsorbed oxygen of adsorbent to form HgO, and the open metal site Cr 2+ was oxidized to Cr 3+ by surface active oxygen again. Furthermore, MIL-101(Cr) had good chemical and thermal stability. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of electrical test conditions in MIL-M-38510 slash sheets

Science.gov (United States)

Sandgren, K.

1980-08-01

Adequacy of MIL-M-38510 slash sheet requirements for electrical test conditions in an automated test environment were evaluated. Military temperature range commercial devices of 13 types from 6 manufacturers were purchased. Software for testing these devices and for varying the test conditions was written for the Tektronix S-3260 test system. The devices were tested to evaluate the effects of pin-condition settling time, measurement sequence of the same and different D-C parameters, temperature sequence, differently defined temperature ambients, variable measurement conditions, sequence of time measurements, pin-application sequence, and undesignated pin condition ambiguity. An alternative to current tri-state enable and disable time measurements is proposed; S-3260 'open' and 'ground' conditions are characterized; and suggestions for changes in MIL-M-38510 slash sheet specifications and MIL-STD-883 test methods are proposed, both to correct errors and ambiguities and to facilitate the gathering of repeatable data on automated test equipment. Data obtained showed no sensitivity to measurement or temperature sequence nor to temperature ambient, provided that test times were not excessive. V sub ICP tests and some low current measurements required allowance for a pin condition settling time because of the test system speed. Some pin condition application sequences yielded incorrect measurements. Undefined terminal conditions of output pins were found to affect I sub OS and propagation delay time measurements. Truth table test results varied with test frequency and V sub IL for low-power Schottky devices.

Eric Bach : ilustrador de Luis de Góngora

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María Dolores Antigüedad del Castillo Olivares

1991-01-01

Full Text Available El pintor holandés Eric Bach [Eríurt (Alemania 1911] ha mostrado durante el año 1991 sus obras como ilustrador en sendas exposiciones celebradas en Córdoba y Madrid. El artista que reside indistintamente en Munich y Barcelona, expuso las ilustraciones que ha realizado para la edición en alemán de Los veinticuatro sonetos amorosos, heroicos y fúnebres de don Luis de Góngora, edición hecha por encargo del Sr. Rüdiger Kampmann de Munich.

Tereza Trautman and Os homens que eu tive: a history on cinema and censorship

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Ana Maria Veiga

2013-12-01

Full Text Available Beyond politics, the moral censorship was widely practiced in Brazil toward films that contested the military patterns of conduct. In the context of erotic cinema, promoted by Embrafilme, a young director saw her dreams sink in 1973 with a censorship act. This article analyses the interdiction of the film Os homens que eu tive [the men that I’ve had], by Tereza Trautman, as a representative element of arbitrariness with its basis on moral and good habits, strongly emphasized from the military coup d’état.

Fabrication of metal-organic framework MIL-88B films on stainless steel fibers for solid-phase microextraction of polychlorinated biphenyls.

Science.gov (United States)

Wu, Ye-Yu; Yang, Cheng-Xiong; Yan, Xiu-Ping

2014-03-21

Metal-organic frameworks (MOFs) have received considerable attention as novel sorbents for sample preparation due to their fascinating structures and functionalities such as large surface area, good thermal stability, and uniform structured nanoscale cavities. Here, we report the application of a thermal and solvent stable MOF MIL-88B with nanosized bipyramidal cages and large surface area for solid-phase microextraction (SPME) of polychlorinated biphenyls (PCBs). Novel MIL-88B coated fiber was fabricated via an in situ hydrothermal growth of MIL-88B film on etched stainless steel fiber. The MIL-88B coated fiber gave large enhancement factors (757-2243), low detection limits (0.45-1.32ngL(-1)), and good linearity (5-200ngL(-1)) for PCBs. The relative standard deviation (RSD) for six replicate extractions of PCBs at 100ngL(-1) on MIL-88B coated fiber ranged from 4.2% to 8.7%. The recoveries for spiked PCBs (10ngL(-1)) in water and soil samples were in the range of 79.7-103.2%. Besides, the MIL-88B coated fiber was stable enough for 150 extraction cycles without significant loss of extraction efficiency. The developed method was successfully applied to the determination of PCBs in water samples and soil samples. Copyright © 2014 Elsevier B.V. All rights reserved.

Mortalidade por acidentes de trânsito e homicídios em Curitiba, Paraná, 1996-2011

Directory of Open Access Journals (Sweden)

Mayckel da Silva Barreto

Full Text Available Resumo OBJETIVO: descrever a tendência da mortalidade por homicídios e acidentes de trânsito de residentes em Curitiba, Paraná, Brasil, no período 1996-2011. MÉTODOS: estudo ecológico de séries temporais com dados do Sistema de Informações sobre Mortalidade; a análise de tendência foi realizada por modelos de regressão polinomial, segundo sexo. RESULTADOS: o coeficiente de mortalidade por acidentes de trânsito no sexo masculino declinou de 61,7 em 1996 para 28,4 em 2011 (-46%, e no feminino, de 16,5 para 7,3 óbitos por 100 mil habitantes (-44,2%; o coeficiente de mortalidade por homicídios entre os homens elevou-se de 32,5 para 69,3 (+113,2% e, entre as mulheres, de 4,4 para 5,3 óbitos por 100 mil habitantes (+20,4%. CONCLUSÃO: a mortalidade por homicídios aumentou; estratégias de prevenção das violências devem ser direcionadas às especificidades das causas externas e à maior exposição dos homens a esses agravos.

Deposition of CdS nanoparticles on MIL-53(Fe) metal-organic framework with enhanced photocatalytic degradation of RhB under visible light irradiation

Energy Technology Data Exchange (ETDEWEB)

Hu, Longxing, E-mail: hulxhhhb@shu.edu.cn [School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444 (China); Deng, Guihua [School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444 (China); Lu, Wencong [College of Sciences, Shanghai University, Shanghai 200444 (China); Pang, Siwei; Hu, Xing [School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444 (China)

2017-07-15

Graphical abstract: The CdS/MIL-53(Fe) photocatalyst has been synthesized by a facile two-step solvothermal method and applied for photocatalytic degradation of organic pollutant RhB under visible light irradiation. - Highlights: • A novel CdS/MIL-53(Fe) photocatalyst was successfully synthesized via a facile two-step solvothermal method. • CdS/MIL-53(Fe) exhibited an enhanced visible-light photocatalytic degradation of RhB in water. • The mechanisms for the formation of CdS/MIL-53(Fe) and photocatalytic degradation of RhB were proposed. - Abstract: A novel composite, CdS/MIL-53(Fe), was successfully fabricated via a facile solvothermal method and characterized with XRD, SEM, TEM, XPS, FT-IR and UV–vis DRS. The results showed that the fabrication was able to result in a good dispersion of CdS nanoparticles onto MIL-53(Fe). The photocatalytic activities of the as-synthesized composite were investigated through the degradation of Rhodamine B (RhB) in water under visible light irradiation. It was found that the composite prepared at the mass ratio of CdS to MIL-53(Fe) of 1.5:1 displayed the highest photocatalytic activity. An approximately 92.5% of photocatalytic degradation of RhB was achieved at 0.5 g/L of 1.5-CdS/MIL dosage, 10 mg/L of initial RhB concentration and 23 °C of reaction temperature under visible light irradiation. The RhB photocatalytic degradation followed well the first-order kinetics equation and the increased catalyst dosage and optimal initial RhB concentration were responsible for the enhanced photocatalytic degradation. Quenching tests revealed that the predominant free radicals in the CdS/MIL-(53)-RhB{sub aq}-visible light system was O{sub 2}{sup −}·; nevertheless, h{sup +} and ·OH also contributed to a certain degree. The enhanced photocatalytic performance was ascribed to the formation of heterojunction structure between CdS and MIL-53(Fe) which significantly suppressed the recombination of photogenerated electron-hole pairs

Deposition of CdS nanoparticles on MIL-53(Fe) metal-organic framework with enhanced photocatalytic degradation of RhB under visible light irradiation

International Nuclear Information System (INIS)

Hu, Longxing; Deng, Guihua; Lu, Wencong; Pang, Siwei; Hu, Xing

2017-01-01

Graphical abstract: The CdS/MIL-53(Fe) photocatalyst has been synthesized by a facile two-step solvothermal method and applied for photocatalytic degradation of organic pollutant RhB under visible light irradiation. - Highlights: • A novel CdS/MIL-53(Fe) photocatalyst was successfully synthesized via a facile two-step solvothermal method. • CdS/MIL-53(Fe) exhibited an enhanced visible-light photocatalytic degradation of RhB in water. • The mechanisms for the formation of CdS/MIL-53(Fe) and photocatalytic degradation of RhB were proposed. - Abstract: A novel composite, CdS/MIL-53(Fe), was successfully fabricated via a facile solvothermal method and characterized with XRD, SEM, TEM, XPS, FT-IR and UV–vis DRS. The results showed that the fabrication was able to result in a good dispersion of CdS nanoparticles onto MIL-53(Fe). The photocatalytic activities of the as-synthesized composite were investigated through the degradation of Rhodamine B (RhB) in water under visible light irradiation. It was found that the composite prepared at the mass ratio of CdS to MIL-53(Fe) of 1.5:1 displayed the highest photocatalytic activity. An approximately 92.5% of photocatalytic degradation of RhB was achieved at 0.5 g/L of 1.5-CdS/MIL dosage, 10 mg/L of initial RhB concentration and 23 °C of reaction temperature under visible light irradiation. The RhB photocatalytic degradation followed well the first-order kinetics equation and the increased catalyst dosage and optimal initial RhB concentration were responsible for the enhanced photocatalytic degradation. Quenching tests revealed that the predominant free radicals in the CdS/MIL-(53)-RhB aq -visible light system was O 2 − ·; nevertheless, h + and ·OH also contributed to a certain degree. The enhanced photocatalytic performance was ascribed to the formation of heterojunction structure between CdS and MIL-53(Fe) which significantly suppressed the recombination of photogenerated electron-hole pairs. Moreover, the

Late Miocene-Pleistocene evolution of a Rio Grande rift subbasin, Sunshine Valley-Costilla Plain, San Luis Basin, New Mexico and Colorado

Science.gov (United States)

Ruleman, C.A.; Thompson, R.A.; Shroba, R.R.; Anderson, M.; Drenth, B.J.; Rotzien, J.; Lyon, J.

2013-01-01

The Sunshine Valley-Costilla Plain, a structural subbasin of the greater San Luis Basin of the northern Rio Grande rift, is bounded to the north and south by the San Luis Hills and the Red River fault zone, respectively. Surficial mapping, neotectonic investigations, geochronology, and geophysics demonstrate that the structural, volcanic, and geomorphic evolution of the basin involves the intermingling of climatic cycles and spatially and temporally varying tectonic activity of the Rio Grande rift system. Tectonic activity has transferred between range-bounding and intrabasin faults creating relict landforms of higher tectonic-activity rates along the mountain-piedmont junction. Pliocene–Pleistocene average long-term slip rates along the southern Sangre de Cristo fault zone range between 0.1 and 0.2 mm/year with late Pleistocene slip rates approximately half (0.06 mm/year) of the longer Quaternary slip rate. During the late Pleistocene, climatic influences have been dominant over tectonic influences on mountain-front geomorphic processes. Geomorphic evidence suggests that this once-closed subbasin was integrated into the Rio Grande prior to the integration of the once-closed northern San Luis Basin, north of the San Luis Hills, Colorado; however, deep canyon incision, north of the Red River and south of the San Luis Hills, initiated relatively coeval to the integration of the northern San Luis Basin.Long-term projections of slip rates applied to a 1.6 km basin depth defined from geophysical modeling suggests that rifting initiated within this subbasin between 20 and 10 Ma. Geologic mapping and geophysical interpretations reveal a complex network of northwest-, northeast-, and north-south–trending faults. Northwest- and northeast-trending faults show dual polarity and are crosscut by north-south– trending faults. This structural model possibly provides an analog for how some intracontinental rift structures evolve through time.

Highly efficient Fenton and enzyme-mimetic activities of NH2-MIL-88B(Fe) metal organic framework for methylene blue degradation.

Science.gov (United States)

He, Jianchuan; Zhang, Yao; Zhang, Xiaodan; Huang, Yuming

2018-03-26

Here, we show that NH 2 -MIL-88B(Fe) can be used as a peroxidase-like catalyst for Fenton-like degradation of methylene blue (MB) in water. The iron-based NH 2 -MIL-88B(Fe) metal organic framework (MOF) was synthesized by a facile and rapid microwave heating method. It was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, powder X-ray diffraction, and the Brunauer-Emmett-Teller method. The NH 2 -MIL-88B(Fe) MOF possesses intrinsic oxidase-like and peroxidase-like activities. The reaction parameters that affect MB degradation were investigated, including the solution pH, NH 2 -MIL-88B(Fe) MOF and H 2 O 2 concentrations, and temperature. The results show that the NH 2 -MIL-88B(Fe) MOF exhibits a wide working pH range (pH 3.0-11.0), temperature tolerance, and good recyclability for MB removal. Under the optimal conditions, complete removal of MB was achieved within 45 min. In addition, removal of MB was above 80% after five cycles, showing the good recyclability of NH 2 -MIL-88B(Fe). The NH 2 -MIL-88B(Fe) MOF has the features of easy preparation, high efficiency, and good recyclability for MB removal in a wide pH range. Electron spin resonance and fluorescence probe results suggest the involvement of hydroxyl radicals in MB degradation. These findings provide new insight into the application of high-efficient MOF-based Fenton-like catalysts for water purification.

Metal-organic frameworks as potential shock absorbers: the case of the highly flexible MIL-53(Al).

Science.gov (United States)

Yot, Pascal G; Boudene, Zoubeyr; Macia, Jasmine; Granier, Dominique; Vanduyfhuys, Louis; Verstraelen, Toon; Van Speybroeck, Veronique; Devic, Thomas; Serre, Christian; Férey, Gérard; Stock, Norbert; Maurin, Guillaume

2014-08-28

The mechanical energy absorption ability of the highly flexible MIL-53(Al) MOF material was explored using a combination of experiments and molecular simulations. A pressure-induced transition between the large pore and the closed pore forms of this solid was revealed to be irreversible and associated with a relatively large energy absorption capacity. Both features make MIL-53(Al) the first potential MOF candidate for further use as a shock absorber.

Endurance Pump Tests With Fresh and Purified MIL-PRF-83282 Hydraulic Fluid

National Research Council Canada - National Science Library

Sharma, Shashi

1999-01-01

.... Two endurance pump tests were conducted with F-16 aircraft hydraulic pumps, using both fresh and purified MIL-PRF-83282 hydraulic fluid, to determine if fluid purification had any adverse effect on pump life...

Photoelectrochemical detection of the herbicide clethodim by using the modified metal-organic framework amino-MIL-125(Ti)/TiO2

International Nuclear Information System (INIS)

Jin, Dangqin; Yu, Liangyun; Xu, Qin; Hu, Xiaoya

2015-01-01

We describe a sensitive photoelectrochemical (PEC) sensor for the determination of the herbicide clethodim. The PEC sensor was constructed by using amino-MIL-125/TiO 2 (MIL stands for Materials from Institute Lavoisier), an amino-functionalized metal-organic framework (MOF) modified with TiO2. The amino-MIL-125/TiO 2 was synthesized by a simple one-step solvothermal method and placed on a glassy carbon electrode where it displays photoelectrocatalytic activity. Scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy and X-ray diffractometry (XRD) were used to characterize the amino-MIL-125/TiO2. In the sensing process, amino-MIL-125/TiO 2 is illuminated by visible light to produce electrons. These excited electrons are delivered to the glassy carbon electrode, leaving positively charged holes (h+) on the surface of the amino-MIL-125/TiO 2 . The holes react with H 2 O to generate hydroxy radicals (•OH). Clethodim rapidly attacks the hydroxy radicals and improves the efficiency of charge separation, this leading to an enhanced photocurrent. Under the optimal experimental conditions, this photoelectrochemical method enables clethodim to be quantified in the concentration range from 0.2 to 25 μmol L −1 , with a detection limit (3 S/N) of 10 nmol L −1 . The assay was applied to the determination of clethodim in soil samples, and results were in acceptable agreement with data obtained by liquid chromatography/mass spectrometry. (author)

Fluorescent metal-organic framework MIL-53(Al) for highly selective and sensitive detection of Fe3+ in aqueous solution.

Science.gov (United States)

Yang, Cheng-Xiong; Ren, Hu-Bo; Yan, Xiu-Ping

2013-08-06

Fluorescent metal-organic frameworks (MOFs) have received great attention in sensing application. Here, we report the exploration of fluorescent MIL-53(Al) for highly selective and sensitive detection of Fe(3+) in aqueous solution. The cation exchange between Fe(3+) and the framework metal ion Al(3+) in MIL-53(Al) led to the quenching of the fluorescence of MIL-53(Al) due to the transformation of strong-fluorescent MIL-53(Al) to weak-fluorescent MIL-53(Fe), allowing highly selective and sensitive detection of Fe(3+) in aqueous solution with a linear range of 3-200 μM and a detection limit of 0.9 μM. No interferences from 0.8 M Na(+); 0.35 M K(+); 11 mM Cu(2+); 10 mM Ni(2+); 6 mM Ca(2+), Pb(2+), and Al(3+); 5.5 mM Mn(2+); 5 mM Co(2+) and Cr(3+); 4 mM Hg(2+), Cd(2+), Zn(2+), and Mg(2+); 3 mM Fe(2+); 0.8 M Cl(-); 60 mM NO2(-) and NO3(-); 10 mM HPO4(2-), H2PO4(-), SO3(2-), SO4(2-), and HCOO(-); 8 mM CO3(2-), HCO3(-), and C2O4(2-); and 5 mM CH3COO(-) were found for the detection of 150 μM Fe(3+). The possible mechanism for the quenching effect of Fe(3+) on the fluorescence of MIL-53(Al) was elucidated by inductively coupled plasma-mass spectrometry, X-ray diffraction spectrometry, and Fourier transform infrared spectrometry. The specific cation exchange behavior between Fe(3+) and the framework Al(3+) along with the excellent stability of MIL-53(Al) allows highly selective and sensitive detection of Fe(3+) in aqueous solution. The developed method was applied to the determination of Fe(3+) in human urine samples with the quantitative spike recoveries from 98.2% to 106.2%.

Luis José de Tejada y Guzmán : espejo de peregrinos penitentes

Directory of Open Access Journals (Sweden)

Darío Achury Valenzuela

1979-03-01

Full Text Available Graciela Maturo, docta escritora argentina, ha escrito un estudio documentado y erudito bajo el rubro de Luis de Tejada y su peregrino místico, editado por el Instituto de Literatura Argentina "Ricardo Rojas", de la Universidad de Buenos Aires.

Geochemistry of Lunar Highland Meteorites Mil, 090034, 090036 AND 090070

Science.gov (United States)

Shirai, N.aoki; Ebihara, M.; Sekimoto, S.; Yamaguchi, A.; Nyquist, L.; Shih, C.-Y.; Park, J.; Nagao, K.

2012-01-01

Apollo and Luna samples were collected from a restricted area on the near side of the Moon, while the source craters of the lunar meteorites are randomly distributed. For example, Takeda et al. [1] and Yamaguchi et al. [2] found a variety of lithic clasts in Dho 489 and Y 86032 which were not represented by Apollo samples, and some of these clasts have lower rare earth elements (REE) and FeO abundances than Apollo anorthosites, respectively. Takeda et al. [1] and Yamaguchi et al. [2] concluded that Dho 489 and Y 86032 originated from the lunar farside. Therefore, lunar meteorites provide an opportunity to study lunar surface rocks from areas not sampled by Apollo and Luna missions. Three lunar anorthitic breccias (MIL 090034, 090036 and 090070) were found on the Miller Range Ice Field in Antarctica during the 2009-2010 ANSMET season [3]. In this study, we determined elemental abudnances for MIL 090034, 090036 and 090070 by using INAA and aimed to characterize these meteorites in chemical compositions in comparison with those for other lunar meteorites and Apollo samples.

Escrituras, hurtos y reelaboraciones de Luis Hurtado de Toledo (1523-1590): edición de su obra literaria y estudio de su obra impresa

OpenAIRE

Gamba Corradine, Jimena

2014-01-01

[ES] La tesis doctoral «Escrituras, hurtos y reelaboraciones de Luis Hurtado de Toledo (1523-1590): edición de su obra literaria y estudio de su obra impresa» consiste en la edición de una parte del corpus literario adjudicado a Luis Hurtado de Toledo. Se editan aquí, con notas al texto, los romances en pliego resguardados en RM 259 + [260] (Romance de las notables cosas que tiene la imperial ciudad de Toledo), RM 261 + [261] y 263 (Romance nuevamente hecho por Luis Hurtado, en el qual se co...

Performance of metal-organic framework MIL-101 after surfactant modification in the extraction of endocrine disrupting chemicals from environmental water samples.

Science.gov (United States)

Huang, Zhenzhen; Lee, Hian Kee

2015-10-01

The research presented in this paper explored the modification and application of a metal-organic framework, MIL-101, with nonionic surfactant-Triton X-114 in dispersive solid-phase extraction for the preconcentration of four endocrine disrupting chemicals (estrone, 17α-ethynylestradiol, estriol and diethylstilbestrol) from environmental water samples. Triton X-114 molecules could be adsorbed by the hydrophobic surface of the MIL-101 crystals, and thus improved the dispersibility of MIL-101 in aqueous solution by serving as a hydrophilic coating. Cloud point phase separation from Triton X-114 accelerated the separation of extracts from the aqueous matrix. The proposed method combines the favorable attributes of strong adsorption capacity resulting from the porous structure of MIL-101 and self-assembly of Triton X-114 molecules. Post-extraction derivatization using N-methyl-N-(trimethylsilyl)trifluoroacetamide was employed to facilitate the quantitative determination of the extracts by gas chromatography-mass spectrometry. The main factors affecting the preparation of modified MIL-101, and extraction of the analytes, such as the amount of surfactant, the ultrasonic and vortex durations, solution pH and desorption conditions, were investigated in detail. Under the optimized conditions, the present method yielded low limits of detection (0.006-0.023 ng/mL), good linearity from 0.09 to 45 ng/mL (coefficients of determination higher than 0.9980) and acceptable precision (relative standard deviations of 2.2-13%). The surface modified MIL-101 was demonstrated to be effective for the extraction of the selected estrogens from aqueous samples, giving rise to markedly improved extraction performance compared to the unmodified MIL-101. Copyright © 2015 Elsevier B.V. All rights reserved.

“Y SAN LUIS OBEDIENTE RESPONDÍA” LOS TERRATENIENTES DE LA CIUDAD DE SAN LUIS Y EL PLAN SANMARTINIANO (1814 - 1829

Directory of Open Access Journals (Sweden)

Melody Celeste Vera

2015-12-01

Full Text Available La base fundamental de la identidad de los habitantes de la provincia de San Luis (Argentina y de su historiografía, es el axioma que el pueblo puntano se inmoló por el proyecto sanmartiniano. El Gobernador Intendente Vicente Dupuy (1814-1820 fue el principal colaborador de José de San Martin en la provincia, y el coordinador de las donaciones de bienes y vidas para la causa. Contaba con el apoyo del “cabildo sanmartiniano”, un grupo de vecinos que secundaban sus ideales, apoyaban sus iniciativas y colaboraban materialmente. Pero luego de la caída del gobierno central en 1820 no se ofrece una interpretación sobre el cambio de proyecto político que representó el nuevo Gobernador, José Santos Ortiz (1820-1829. Si se consideran conjuntamente las oposiciones de un grupo de vecinos levantadas durante el gobierno de Dupuy y el accionar de Santos Ortiz durante su mandato, cabe preguntarse: ¿los cabildantes terratenientes apoyaron la gesta sanmartiniana por convicción, o se vieron forzados a hacerlo por la imposición de un grupo en el poder? ¿Representó Santos Ortiz el proyecto de lo que el grupo terrateniente buscaba y no pudo obtener mientras se llevaba delante el plan sanmartiniano? En este trabajo se busca comparar los objetivos primarios de ambos gobernadores durante sus mandatos, con el fin de vislumbrar cuál de los planes de gobierno representaba los ideales y necesidades de los grandes terratenientes de la ciudad de San Luis.

Provencance of the late Proterozoic to early Cambrian metaclastic sediments ot the Sierra de San Luis (Eastern Sierras Pampeanas) and Cordillera Oriental, Argentina

DEFF Research Database (Denmark)

Drobe, M.; López de Luchi, M.; Steenken, A.

2009-01-01

Provenance studies have been performed utilising major and trace elements, Nd systematics, whole rock Pb-Pb isotopes and zircon U/Pb SHRIMP data on metasedimentary rocks of the Sierra de San Luis (Nogolí Metamorphic Complex, Pringles Metamorphic Complex, Conlara Metamorphic Complex and San Luis...... is depicted for all the complexes using major and trace elements. The Pringles Metamorphic Complex shows indications for crustal recycling, pointing to a bimodal provenance. Major volcanic input has to be rejected due to Th/Sc, Y/Ni and Cr/V ratios for all units. The eNd(540 Ma) data is lower for the San Luis...... Formation and higher for the Conlara Metamorphic Complex, as compared to the other units, in which a good consistency is given. This is similar to the TDM ages, where the metapsammitic samples of the San Luis Formation are slightly older. The spread of data is largest for the Pringles Metamorphic Complex...

Luis Ramiro Beltrán: Semblanza de un comunicador vanguardista

Directory of Open Access Journals (Sweden)

Alfonso Gumucio Dagron

2009-03-01

Full Text Available Luis Ramiro Beltrán es un "WAKIKI" investigador de seriedad académica reconocida, pensador que ha dado un aporte significativo a los estudios sobre la comunicación para el desarrollo en América Latina son frases de Alfonso Gumucio al hacer una semblanza de Beltrán en la que destaca su generosidad, apertura tolerancia y colaboración, amigo fiel, constante e incondicional y su creatividad.

Acesso à consulta a portadores de doenças sexualmente transmissíveis: experiências de homens em uma unidade de saúde de Fortaleza, Ceará, Brasil

Directory of Open Access Journals (Sweden)

Araújo Maria Alix Leite

2005-01-01

Full Text Available O acesso aos serviços de saúde é uma das características importantes e um desafio ao Sistema Único de Saúde. Este estudo tem por objetivo compreender as dificuldades dos homens com DST no acesso à consulta. Trata-se de uma pesquisa qualitativa com homens atendidos em uma unidade de referência de DST, na cidade de Fortaleza, Ceará, Brasil, em novembro de 2003. A mesma foi aprovada pelo Comitê de Ética e utilizou a técnica de análise de conteúdo na análise e interpretação dos resultados. As entrevistas centraram-se na categoria acesso. Os achados evidenciaram que os homens com DST enfrentam dificuldade no acesso à consulta, mesmo utilizando diferentes mecanismos para consegui-la. Os serviços são oferecidos em horários incompatíveis com a demanda. Este fato é agravado pela falta de planejamento do número de consultas e de profissionais disponíveis para o atendimento dos casos de DST. Concluímos que precisa haver um investimento maior em nível do SUS na melhoria do acesso à consulta para homens com DST e faz-se necessário que, do ponto de vista institucional, a oferta de serviços leve em consideração a demanda da população.

Gestion intégrée du mildiou du mil en station au centre régional de ...

African Journals Online (AJOL)

user

Le mil (Pennicetum glaucum) L.R.Br constitue 75% de la production céréalière du Niger. Cependant, son rendement est très faible dû à plusieurs types de contraintes. La maladie du mildiou du mil causé par un champignon Sclerospora graminicola (Sacc) Schroët, occupe une place importante. L'objectif de cette étude.

E agora o homem vem?! Estratégias de atenção à saúde dos homens

Directory of Open Access Journals (Sweden)

Martha Cristina Nunes Moreira

2016-01-01

Full Text Available Resumo: Analisamos, com base em uma pesquisa qualitativa sob a perspectiva hermenêutica-dialética, as estratégias de atenção à saúde dos homens segundo a ótica de profissionais de saúde. Contamos com um acervo de 18 entrevistas semiestruturadas sobre sexualidade masculina, cuidados de saúde masculinos, pré-natal e paternidade. A partir da compreensão do conjunto dos depoimentos, foram identificados três eixos, independentemente da temática abordada (sexualidade masculina, envolvimento de homens no pré-natal e paternidade e da região. Os eixos são estruturantes e estruturados por ideias que permeiam os diferentes depoimentos. Os temas sexualidade masculina em associação com paternidade e cuidado à saúde ainda evocam a dimensão privada, referida aos limites da geografia da casa. Essas ideias povoam o repertório cultural sobre o homem; a novidade está em desvincular sexualidade de relações sexuais, assim como saúde sexual de transmissão e contágio, na interpretação de nosso acervo.

Media and Information Literacy (MIL) in journalistic learning: strategies for accurately engaging with information and reporting news

Science.gov (United States)

Inayatillah, F.

2018-01-01

In the era of digital technology, there is abundant information from various sources. This ease of access needs to be accompanied by the ability to engage with the information wisely. Thus, information and media literacy is required. From the results of preliminary observations, it was found that the students of Universitas Negeri Surabaya, whose major is Indonesian Literature, and they take journalistic course lack of the skill of media and information literacy (MIL). Therefore, they need to be equipped with MIL. The method used is descriptive qualitative, which includes data collection, data analysis, and presentation of data analysis. Observation and documentation techniques were used to obtain data of MIL’s impact on journalistic learning for students. This study aims at describing the important role of MIL for students of journalistic and its impact on journalistic learning for students of Indonesian literature batch 2014. The results of this research indicate that journalistic is a science that is essential for students because it affects how a person perceives news report. Through the reinforcement of the course, students can avoid a hoax. MIL-based journalistic learning makes students will be more skillful at absorbing, processing, and presenting information accurately. The subject influences students in engaging with information so that they can report news credibly.

Solid-State NMR Spectroscopy Proves the Presence of Penta-coordinated Sc Sites in MIL-100(Sc).

Science.gov (United States)

Giovine, Raynald; Volkringer, Christophe; Ashbrook, Sharon E; Trébosc, Julien; McKay, David; Loiseau, Thierry; Amoureux, Jean-Paul; Lafon, Olivier; Pourpoint, Frédérique

2017-07-18

Advanced solid-state NMR methods and first-principles calculations demonstrate for the first time the formation of penta-coordinated scandium sites. These coordinatively unsaturated sites were shown during the thermal activation of scandium-based metal-organic frameworks (MOFs). A 45 Sc NMR experiment allows their specific observation in activated Sc 3 BTB 2 (H 3 BTB=1,3,5-tris(4-carboxyphenyl)benzene) and MIL-100(Sc) MOFs. The assignment of the ScO 5 groups is supported by the DFT calculations of NMR parameters. The presence of ScO 5 Lewis acid sites in MIL-100(Sc) explains furthermore its catalytic activity. The first NMR experiment to probe 13 C- 45 Sc distances is also introduced. This advanced solid-state NMR pulse sequence allows the demonstration of the shrinkage of the MIL-100(Sc) network when the activation temperature is raised. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

De la BLAA: Exposición en la Biblioteca Luis Angel Arango

Directory of Open Access Journals (Sweden)

Juan Camilo Sierra

2001-01-01

Full Text Available Hasta febrero de 2003 la Biblioteca Luis Ángel Arango exhibirá una de las muestras más representativas del arte religioso internacional: 500 años de arte ruso. Iconos de la Galería Tretyakof de Moscú. Publicamos algunos apartes del plegable que acompaña la muestra.

Transient electromagnetic mapping of clay units in the San Luis Valley, Colorado

Science.gov (United States)

Fitterman, David V.; Grauch, V.J.S.

2010-01-01

Transient electromagnetic soundings were used to obtain information needed to refine hydrologic models of the San Luis Valley, Colorado. The soundings were able to map an aquitard called the blue clay that separates an unconfined surface aquifer from a deeper confined aquifer. The blue clay forms a conductor with an average resistivity of 6.9 ohm‐m. Above the conductor are found a mixture of gray clay and sand. The gray clay has an average resistivity of 21 ohm‐m, while the sand has a resistivity of greater than 100 ohm‐m. The large difference in resistivity of these units makes mapping them with a surface geophysical method relatively easy. The blue clay was deposited at the bottom of Lake Alamosa which filled most of the San Luis Valley during the Pleistocene. The geometry of the blue clay is influenced by a graben on the eastern side of the valley. The depth to the blue clay is greater over the graben. Along the eastern edge of valley the blue clay appears to be truncated by faults.

“Candidatus Rickettsia andeanae” en Amblyomma tigrinum, San Luis, Argentina

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Gabriel CICUTTIN

2016-11-01

Full Text Available El objetivo del estudio fue detectar especies del género Rickettsia en garrapatas de la especie Amblyomma tigrinum colectadas sobre carnívoros domésticos y en sangre de caninos domésticos de la provincia de San Luis (Argentina. Entre 2013 y 2015 se colectaron 56 garrapatas adultas de la especie A. tigrinum sobre caninos y felinos domésticos, y se obtuvieron 65 muestras sanguíneas de caninos. Tres garrapatas resultaron positivas mediante la amplificación de un fragmento del espacio intergénico 23S-5S ARNr del género Rickettsia, lográndose secuenciar uno de los productos positivos. La muestra positiva secuenciada también resultó positiva por PCRs de los fragmentos de los genes gltA y ompA. Las secuencias obtenidas resultaron tener una identidad del 100 % de identidad con “Candidatus Rickettsia andeanae”. Todas las muestras sanguíneas resultaron negativas. “Ca. R. andeanae” no ha sido asociada con enfermedad en humanos o animales, sin embargo, es necesario realizar nuevas investigaciones para lograr un mayor conocimiento del riesgo potencial de transmisión de rickettsiosis en la región. SUMMARY. “Candidatus Rickettsia andeanae” in Amblyomma tigrinum ticks from San Luis (Argentina. The aim of this study was to detect species of Rickettsia in Amblyomma tigrinum ticks collected from domestic carnivores and blood of domestic dogs of San Luis (Argentina. Between 2013 and 2015, 56 adults of A. tigrinum from dogs and cats and 65 blood from dogs were collected. Three ticks were positive by amplification of a 23S-5S rRNA fragment, and the sequence of one of the positive products was obtained. The positive sample sequenced was positive by PCRs of fragments of genes gltA and ompA. The sequences obtained were 100% identical with "Candidatus Rickettsia andeanae". All blood samples were negative. “Ca. R. andeanae” has not been associated with disease in humans or animals; however, further research is necessary to achieve greater

Mineralogy and Petrography of MIL 090001, a Highly Altered CV Chondrite from the Reduced Sub-Group

Science.gov (United States)

Keller, Lindsay P.

2011-01-01

MIL 090001 is a large (greater than 6 kg) CV chondrite from the reduced subgroup (CV(sub red)) that was recovered during the 2009-2010 ANSMET field season [1]. The CV(sub red) subgroup meteorites retain primitive characteristics and have escaped the Na and Fe meta-somatism that affected the oxidized (CV(sub ox)) subgroups. MIL 090001 is, however, reported to be altered [1], and thus a major objective of this study is to characterize its mineralogy and petrography and the extent of the alteration.

Theoretical study of carbon dioxide adsorption and diffusion in MIL-127(Fe) metal organic framework

Science.gov (United States)

Pongsajanukul, Pavee; Parasuk, Vudhichai; Fritzsche, Siegfried; Assabumrungrat, Suttichai; Wongsakulphasatch, Suwimol; Bovornratanaraks, Thiti; Chokbunpiam, Tatiya

2017-07-01

The UFF force field is found to reproduce the adsorption isotherm of carbon dioxide in MIL-127(Fe) well. It has therefore been used to investigate the structure and self-diffusion of carbon dioxide molecules in the MIL which is a candidate for membrane or adsorption application. The structure of the adsorbed phase shows different regions of high concentration. The highest particle concentration was found in the central regions of the channels. The self-diffusion coefficient slightly increases with the loading for low concentration of guest molecules while for higher concentrations it decreases because of mutual hindrance of guest molecules.

Fé antropológica como ponte entre fé e ideología em Juan Luis Segundo

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Alvori Ahlert

2007-01-01

Full Text Available Este texto busca a compreensão da ideología em sua relação com a fé na teologia latinoamericana a partir da concepção de fé antropológica na obra de Juan Luis Segundo. Acreditamos que a questão da ideología, e sua relação com a fé, continua sendo urna questão atual no pensamento cristão, face aos velhos e novos problemas humanos que o novo sáculo vem apresentando. Concentramos nossa análise nos escritos de Juan Luis Segundo, um dos principáis representantes dessa teologia, por ser este teólogo que, ao nosso ver, mais trabalhou, de forma explícita, a questão da ideología e sua relação com a fé no contexto latinoamericanoThis text searchs the understanding of the ideology in its relation with the faith in the Latin American theology from the conception of antropology faith in the workmanship of Juan Luis Segundo. We believe that the question of the ideology, and its relation with the faith, continue being a current question in the Christian thought, face to the old and new human problems that the new century comes presenting. We concentrate our analysis on the writings of Juan Luis Segundo, one of the main representatives of this theology, for being this theologian who, to ours to see, more worked, of explicit form, the question of the ideology and its relation with the faith in the Latin American context

El pachuco entre Octavio Paz y el trayecto para su reinvención en "Zoot Suit" de Luis Valdez

OpenAIRE

Ochoa, Edna

2010-01-01

This article focuses on the figure of the pachuco in the play Zoot Suit by Luis Valdez in order to explore the most important aspects about this character. To achieve this purpose I will examine its representation in various literary texts and I will trace its history to show how the projection of the character changes from the Chicano movement in the 6os. This character is seen in a positive and memorable way, especially in the play Zoot Suit by Luis Valdez, who regards him as...

Multiphysics Modeling and Simulations of Mil A46100 Armor-Grade Martensitic Steel Gas Metal Arc Welding Process

Science.gov (United States)

2013-05-23

further. Application of the Scheil additive rule to MIL A46100 yielded the CCT diagram displayed in Fig. 8. The diagram displayed in Fig. 8 is obtained...computational procedure used to construct the TTTand CCT diagrams could be used to predict the incubation time for austenite decomposition under an...of austenite into allotriomorphic ferrite is Fig. 8 MIL A46100 CCT diagram corresponding to the TTT dia- gram displayed in Figure 7(a): CCT curves and

Fabrication Parameters of Asymmetric Mixed Matrix Matrimid-MIL-53/PMHS Membrane for CO2/CH4 Separation

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Fatereh Dorosti

2017-03-01

Full Text Available Asymmetrically mixed matrix Matrimid-MIL-53 membranes with silicone cover layer were fabricated. For better understanding of membrane fabrication process, three main parameters of fabrication, Matrimid concentration, silicone concentration and weight percentage of metal organic framework (MIL-53 particles, were optimized by an experimental design method. Cross-section SEM images were used to study the membrane structure and polymer-particles interface. Moreover, thermal resistance of the membranes and the existence of various bonds in them were investigated by FTIR and TGA analyses. The results showed that membranes had porous structure with finger-like morphology. At low and moderate percentages of particles, there were no non-selective voids observed at polymer-particles interface. The thermal resistance of membranes increased with the increase of MIL-53 weight percentage and the destruction temperature of polymer increased from 410°C to 450°C. The permeability tests results showed that the Matrimid (20% wt-MIL-53(15% wt/PMHS (10%wt membrane exhibited the highest level of CO2/CH4 selectivity (23.6. However, in the membrane with 30 wt% particles loading, selectivity decreased due to particles agglomeration and void formation. The experimental design results showed that the concentration of silicone in covering solution had significant effect. CO2 and CH4 permeability decreased and ideal selectivity of CO2/CH4 increased with silicone concentration enhancement. Although the Matrimid concentration had a little effect on CO2/CH4 ideal selectivity, its enhancement increased the selectivity of the gases. The optimization results showed the membrane with 17.8% of Matrimd polymer, 13.2% of silicone polymer and 15.5 wt% of MIL-53 particle displayed the highest selectivity and CO2 permeability.

Prevalence and spatial distribution of bovine brucellosis in San Luis and La Pampa, Argentina.

Science.gov (United States)

Aznar, M N; Linares, F J; Cosentino, B; Sago, A; La Sala, L; León, E; Duffy, S; Perez, A

2015-08-15

Bovine brucellosis (BB) is a zoonotic disease caused by Brucella abortus. BB is endemic in Argentina, where vaccination with Brucella abortus strain 19 is compulsory for 3-to-8 month-old heifers. The objectives of this study were to quantify the prevalence of BB and to identify factors associated with its occurrence, along with the spatial distribution of the disease, in the provinces of La Pampa and San Luis. A two-stage random sampling design was used to sample 8,965 cows (3,513 in La Pampa and 5,452 in San Luis) from 451 farms (187 in La Pampa and 264 in San Luis). Cow and herd prevalence were 1.8 % (95 % CI: 1.3-2.2; n = 157) and 19.7 % (95 % CI: 17.0-22.4; n = 89), respectively. Both cow-level and herd-level prevalence in La Pampa (2.4 and 26.0 %, respectively) were significantly higher than in San Luis (1.4 and 15.5 %, respectively). There were not differences between the proportions of reactive cattle compared to that obtained in a survey conducted in 2005. However, herd prevalence in La Pampa was significantly (P < 0.05) higher compared to that study. Disease was found to be spatially clustered in west La Pampa. The lower the bovine density and the calf/cow ratio, the higher odds of belonging to the cluster. The increase of farm prevalence in the last five years suggests that the disease is spreading and that control measures should be applied in the region. The cluster of infected farms was located in the west region of La Pampa. There, farms have lower animal densities and smaller cow/calf indices compared to the rest of the province. Although western La Pampa has more infected herds, within-farm prevalence was not higher, which suggests that the control program has been relatively successful in controlling the disease at the farm level, and/or that low animal density inherently results in low disease prevalence. Our results provide baseline information on the epidemiology of BB and its potential pattern of transmission in Argentina, which will ultimately

Deposition of CdS nanoparticles on MIL-53(Fe) metal-organic framework with enhanced photocatalytic degradation of RhB under visible light irradiation

Science.gov (United States)

Hu, Longxing; Deng, Guihua; Lu, Wencong; Pang, Siwei; Hu, Xing

2017-07-01

A novel composite, CdS/MIL-53(Fe), was successfully fabricated via a facile solvothermal method and characterized with XRD, SEM, TEM, XPS, FT-IR and UV-vis DRS. The results showed that the fabrication was able to result in a good dispersion of CdS nanoparticles onto MIL-53(Fe). The photocatalytic activities of the as-synthesized composite were investigated through the degradation of Rhodamine B (RhB) in water under visible light irradiation. It was found that the composite prepared at the mass ratio of CdS to MIL-53(Fe) of 1.5:1 displayed the highest photocatalytic activity. An approximately 92.5% of photocatalytic degradation of RhB was achieved at 0.5 g/L of 1.5-CdS/MIL dosage, 10 mg/L of initial RhB concentration and 23 °C of reaction temperature under visible light irradiation. The RhB photocatalytic degradation followed well the first-order kinetics equation and the increased catalyst dosage and optimal initial RhB concentration were responsible for the enhanced photocatalytic degradation. Quenching tests revealed that the predominant free radicals in the CdS/MIL-(53)-RhBaq-visible light system was O2-rad ; nevertheless, h+ and rad OH also contributed to a certain degree. The enhanced photocatalytic performance was ascribed to the formation of heterojunction structure between CdS and MIL-53(Fe) which significantly suppressed the recombination of photogenerated electron-hole pairs. Moreover, the reusability of 1.5-CdS/MIL composite was also studied.

Mapas de Significados Espaciais e Vivência Geracional de Homens e Mulheres Nikkeys de Maringá e Londrina, Paraná. DOI: 10.5212/Rlagg.v.6.i1.0005

OpenAIRE

Kataoka, Caio Shigueharu; Universidade Estadual de Ponta Grossa; Ornat, Marcio Jose; Universidade Estadual de Ponta Grossa

2014-01-01

Este artigo problematiza a relação entre os mapas de significados espaciais e a vivência geracional de homens e mulheres nikkeys no Norte do Paraná. Nosso recorte espacial refere-se às cidades de Maringá e Londrina, tendo visto o fato de apresentarem tanto considerável população relativa de japoneses, quanto expressiva manifestação cultural, organizada segundo Associações Culturais e Esportivas. O campo realizado evidencia os diferentes mapas de significados espaciais constituídos por homens ...

Synthesis of highly efficient α-Fe{sub 2}O{sub 3} catalysts for CO oxidation derived from MIL-100(Fe)

Energy Technology Data Exchange (ETDEWEB)

Cui, Lifeng; Zhao, Di; Yang, Yang [Environment and Low-Carbon Research Center, School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093 (China); Wang, Yuxin [Institute of Applied Biotechnology, Taizhou Vocation & Technical College, Taizhou, Zhejiang 318000 (China); Zhang, Xiaodong, E-mail: fatzhxd@126.com [Environment and Low-Carbon Research Center, School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093 (China)

2017-03-15

Mesoporous hollow α-Fe{sub 2}O{sub 3} bricks were synthesized via a hydrothermal method to create a precursor MIL-100(Fe) and a subsequent calcination process was applied to prepare the Fe{sub 2}O{sub 3} phase. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) results showed the morphology of hollow α-Fe{sub 2}O{sub 3} bricks which inherited from the MIL-100(Fe) template. The catalytic activities of hollow α-Fe{sub 2}O{sub 3} bricks for CO oxidation are studied in this work. Due to better low temperature reduction behavior, mesoporous hollow α-Fe{sub 2}O{sub 3} bricks obtained at calcination temperature of 430 °C displayed high catalytic activity and excellent stability with a complete CO conversion temperature (T{sub 100}) of 255 °C. - Graphical abstract: Synthesis of highly efficient α-Fe{sub 2}O{sub 3} catalysts for CO oxidation derived from MIL-100(Fe). - Highlights: • α-Fe{sub 2}O{sub 3} is prepared by the thermolysis of a MIL-100(Fe) template. • The morphology of hollow α-Fe{sub 2}O{sub 3} bricks is inherited from MIL-100(Fe) template. • α-Fe{sub 2}O{sub 3} obtained at calcined temperature of 430 °C displays high activity • Enhanced activity is attributed to crystal plane and reduction behavior.

High performance liquid chromatography of substituted aromatics with the metal-organic framework MIL-100(Fe): Mechanism analysis and model-based prediction.

Science.gov (United States)

Qin, Weiwei; Silvestre, Martin Eduardo; Li, Yongli; Franzreb, Matthias

2016-02-05

Metal-organic framework (MOF) MIL-100(Fe) with well-defined thickness was homogenously coated onto the outer surface of magnetic microparticles via a liquid-phase epitaxy method. The as-synthesized MIL-100(Fe) was used as stationary phase for high-performance liquid chromatography (HPLC) and separations of two groups of mixed aromatic hydrocarbons (toluene, styrene and p-xylene; acetanilide, 2-nirtoaniline and 1-naphthylamine) using methanol/water as mobile phase were performed to evaluate its performance. Increasing water content of the mobile phase composition can greatly improve the separations on the expense of a longer elution time. Stepwise elution significantly shortens the elution time of acetanilide, 2-nirtoaniline and 1-naphthylamine mixtures, while still achieving a baseline separation. Combining the experimental results and in-depth modeling using a recently developed chromatographic software (ChromX), adsorption equilibrium parameters, including the affinities and maximum capacities, for each analyte toward the MIL-100(Fe) are obtained. In addition, the pore diffusivity of aromatic hydrocarbons within MIL-100(Fe) was determined to be 5×10(-12)m(2)s(-1). While the affinities of MIL-100(Fe) toward the analyte molecules differs much, the maximum capacities of the analytes are in a narrow range with q*MOFmax,toluene=3.55molL(-1), q*MOFmax,styrene or p-xylene=3.53molL(-1), and q*MOFmax,anilines=3.12molL(-1) corresponding to approximately 842 toluene and 838 styrene or p-xylene, and 740 aniline molecules per MIL-100(Fe) unit cell, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

Sm-Nd, Rb-Sr and K-Ar age constraints of the El Molle and Barroso plutons, western Sierra de San Luis, Argentina

International Nuclear Information System (INIS)

Sato, A.M.; Gonzalez, P.D; Petronilho, L.A; Llambias, E.J.; Varela, R; Basei, M.A.S

2001-01-01

Within the Early Paleozoic Famatinian orogeny of Southern Sierras Pampeanas (Sierra de San Luis and Sierra de Cordoba), the post-orogenic granitoids are characterized by circular intrusions. The published Rb-Sr and K-Ar ages from plutons in the Sierra de San Luis range between 408 and 320 Ma (see synthesis in Llambias et al., 1998). The El Molle and Barroso plutons (Sims et al., 1997; Gonzalez and Sato, 2000) are the two main exposures of a post-orogenic intrusive complex located in the western area of the Sierra de San Luis basement. They also exhibit an overall circular map view of almost 8 km in diameter, and are emplaced in a metamorphic complex developed through pre-Famatinian (Proterozoic? to Early Paleozoic) to Famatinian (Early Paleozoic) orogenies (Gonzalez and Llambias, 1998; von Gosen and Prozzi, 1998). We are carrying out isotopic datings of the El Molle and Barroso plutons in order to contribute to the understanding of the magmatic and metamorphic evolution of the final stages of the Famatinian orogenic cycle in the Sierra de San Luis. The first results of the Sm-Nd, Rb-Sr and K-Ar dates are here presented (au)

Upper Holocene in a profile:tectonic depression of Conlara-Sierra de San Luis, San Luis, Argentina

International Nuclear Information System (INIS)

Strasser, E.; Chiesa, J.

2004-01-01

The characteristics of three column profiles belonging to eolic sediments, assignated to Upper Holocene of the Depression of Conlara and oriental edge of San Luis range, comprising loessic materials and sandy loessoides, associated to aluvio-eolic and pedogenetic levels are texturally described. Lineal graphics of expression are used to visualize the textual variations according to the deph, those graphics are built according to the curve of frequency accumulated of the distribution of the size, using the parameters of rank in phi (Q) intervals and the half diameter expressed in microns. The interpretation of the succession in ecuatorial direction allows the inferences of the decrease of the size of grain from the planicie (on the east) towards the mountain region (on the west). The values of parameters of rank and statistiral parameters are presented, of all the succession although it is proposed that the Upper Holocene corresponds to the two upper meters [es

Edificio de viviendas. Ca´Granda, Milán

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Gandolfi, Vittorio

1959-04-01

Full Text Available Con el nombre de "Ca'Granda" se ha querido designar el distrito, capaz de 6.000 habitantes, que el Ayuntamiento de Milán está construyendo, y en parte ha construido ya, en la zona detrás de las calles Fulvio Testi y Ospedale Maggiore; es decir, en el sector norte de la ciudad correspondiente a la dirección de mayor impulso del desarrollo urbanístico de lo habitado.

EATING HABITS: A study with adolescents aged 10 to 15, from Gaspar Bartholomay Elementary School in Santa Cruz do Sul

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Bruna Fernada Soder

2012-11-01

Full Text Available Eating habits in adolescence, may suffer several changes as they can vary from one day to another. The objective of this study is to determine the eating habits of adolescents aged 10 to 15 years old. The study comprised 81 students aged between 10 and 15 years, 48 male and 33 female students, from Gaspar Bartholomay Elementary School. The research was carried out through a descriptive exploratory study, addressing the eating habits and weight control, and focusing on the frequency of food consumption per week. The tool for the study was a questionnaire on health and well-being - children and adolescents - eating habits and weight control. According to the results obtained in this study, the consumption of fried foods, pizza, lasagna and treats,were consumed less frequently, being considered among adolescents as a good eating habit, since foods such as these will cause obesity if consumed more frequently and in large quantities. In relation to the consumption of salads and vegetables males (40.5% have the habit of eating more that kind of food, when compared to the females(38.2%. For both genders, adults become more or less prone to obesitywith a more regular consumption of this type of food. Thus, we can see that the teenagers in their diet, prioritize foods they like to eat, and seldom choose foods which are healthier, without worrying about becoming obese adolescents or even in the future, obese adults with poor eating habits.

Ampliación de la distribución de Physalaemus biligonigerus (Cope, 1860 (Anura: Leiuperidae en la provincia de San Luis, Argentina

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Moreno, Liliana

2008-03-01

Full Text Available República Argentina, San Luis, Departamento Gral. Pedernera, Villa Mercedes (33º42'18,71" S 66º26'27,98" W. Fecha de colección: 29/XII/ 2006. Col: R. Gutierrez y L. Moreno. Los ejemplares están depositados en la Colección Herpetológica de la Universidad Nacional de San Luis (CH-UNSL 0389 – CH-UNSL 0390.

San Luis Valley - Taos Plateau Landscape-Level Cultural Heritage Values and Risk Assessment

Energy Technology Data Exchange (ETDEWEB)

Wescott, Konstance L. [Argonne National Lab. (ANL), Argonne, IL (United States); Abplanalp, Jennifer M. [Argonne National Lab. (ANL), Argonne, IL (United States); Brown, Jeff [Bureau of Land Management, Monte Vista, CO (United States); Cantwell, Brian [Argonne National Lab. (ANL), Argonne, IL (United States); Dicks, Merrill [Bureau of Land Management, Taos, NM (United States); Fredericks, Brian [Bureau of Land Management, Monte Vista, CO (United States); Krall, Angie [US Forest Service, Creede, CO (United States); Rollins, Katherine E. [Argonne National Lab. (ANL), Argonne, IL (United States); Sullivan, Robert [Argonne National Lab. (ANL), Argonne, IL (United States); Valdez, Arnie [Univ. of New Mexico, Albuquerque, NM (United States); Verhaaren, Bruce [Argonne National Lab. (ANL), Argonne, IL (United States); Vieira, Joseph [Bureau of Land Management, Monte Vista, CO (United States); Walston, Lee [Argonne National Lab. (ANL), Argonne, IL (United States); Zvolanek, Emily A. [Argonne National Lab. (ANL), Argonne, IL (United States)

2016-10-01

The San Luis Valley – Taos Plateau Landscape-Level Cultural Heritage Values and Risk Assessment (hereafter referred to as cultural assessment) is a BLM pilot project designed to see whether the Rapid Ecoregional Assessment (REA) framework (already established and implemented throughout many ecoregions in the West) can be applied to the cultural environment.

Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications

CSIR Research Space (South Africa)

Musyoka, Nicholas M

2016-06-01

Full Text Available Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised...

Antes do mito: Soldados-cidadãos da Guarda Nacional do Rio Grande do Sul (1850-1873

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Miqueias H. Mugge

Full Text Available Resumo O artigo investiga a composição das fileiras de soldados e oficiais da Guarda Nacional na província do Rio Grande do Sul, durante os anos de centralização política da administração da milícia (1850-1873. Dessa forma, busca solapar a imagem já clássica do sul do Brasil, onde, supostamente, os homens em armas seriam sobretudo peões sob as ordens de estancieiros, facilmente mobilizáveis para as lides guerreiras - configuração, aliás, que pretensamente seria a marca indelével da estrutura social da região. A partir das listas de qualificação da Guarda Nacional, o trabalho revela uma fotografia muito mais complexa da sociedade brasileira na parte meridional do país, dando especial enfoque aos homens livres, libertos e pobres que faziam parte da milícia. Sendo a Guarda a espinha dorsal do híbrido sistema militar do Império, conclui-se que foi através dessas redes e cadeias de interdependência que os assuntos de guerra eram gerenciados ali, conformando a própria natureza do Estado Imperial.

Noble metals can have different effects on photocatalysis over metal-organic frameworks (MOFs): a case study on M/NH₂-MIL-125(Ti) (M=Pt and Au).

Science.gov (United States)

Sun, Dengrong; Liu, Wenjun; Fu, Yanghe; Fang, Zhenxing; Sun, Fangxiang; Fu, Xianzhi; Zhang, Yongfan; Li, Zhaohui

2014-04-14

M-doped NH2-MIL-125(Ti) (M=Pt and Au) were prepared by using the wetness impregnation method followed by a treatment with H2 flow. The resultant samples were characterized by powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption fine structure (XAFS) analyses, N2-sorption BET surface area, and UV/Vis diffuse reflectance spectroscopy (DRS). The photocatalytic reaction carried out in saturated CO2 with triethanolamine (TEOA) as sacrificial agent under visible-light irradiations showed that the noble metal-doping on NH2-MIL-125(Ti) promoted the photocatalytic hydrogen evolution. Unlike that over pure NH2-MIL-125(Ti), in which only formate was produced, both hydrogen and formate were formed over Pt- and Au-loaded NH2-MIL-125(Ti). However, Pt and Au have different effects on the photocatalytic performance for formate production. Compared with pure NH2-MIL-125(Ti), Pt/NH2-MIL-125(Ti) showed an enhanced activity for photocatalytic formate formation, whereas Au has a negative effect on this reaction. To elucidate the origin of the different photocatalytic performance, electron spin resonance (ESR) analyses and density functional theory (DFT) calculations were carried out over M/NH2-MIL-125(Ti).The photocatalytic mechanisms over M/NH2-MIL-125(Ti) (M=Pt and Au) were proposed. For the first time, the hydrogen spillover from the noble metal Pt to the framework of NH2-MIL-125(Ti) and its promoting effect on the photocatalytic CO2 reduction is revealed. The elucidation of the mechanism on the photocatalysis over M/NH2-MIL-125(Ti) can provide some guidance in the development of new photocatalysts based on MOF materials. This study also demonstrates the potential of using noble metal-doped MOFs in photocatalytic reactions involving hydrogen as a reactant, like hydrogenation reactions. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Amine-functionalized MIL-53(Al)-coated stainless steel fiber for efficient solid-phase microextraction of synthetic musks and organochlorine pesticides in water samples.

Science.gov (United States)

Xie, Lijun; Liu, Shuqin; Han, Zhubing; Jiang, Ruifen; Zhu, Fang; Xu, Weiqin; Su, Chengyong; Ouyang, Gangfeng

2017-09-01

The fiber coating is the key part of the solid-phase microextraction (SPME) technique, and it determines the sensitivity, selectivity, and repeatability of the analytical method. In this work, amine (NH 2 )-functionalized material of Institute Lavoisier (MIL)-53(Al) nanoparticles were successfully synthesized, characterized, and applied as the SPME fiber coating for efficient sample pretreatment owing to their unique structures and excellent adsorption properties. Under optimized conditions, the NH 2 -MIL-53(Al)-coated fiber showed good precision, low limits of detection (LODs) [0.025-0.83 ng L -1 for synthetic musks (SMs) and 0.051-0.97 ng L -1 for organochlorine pesticides (OCPs)], and good linearity. Experimental results showed that the NH 2 -MIL-53(Al) SPME coating was solvent resistant and thermostable. In addition, the extraction efficiencies of the NH 2 -MIL-53(Al) coating for SMs and OCPs were higher than those of commercially available SPME fiber coatings such as polydimethylsiloxane, polydimethylsiloxane-divinylbenzene, and polyacrylate. The reasons may be that the analytes are adsorbed on NH 2 -MIL-53(Al) primarily through π-π interactions, electron donor-electron acceptor interactions, and hydrogen bonds between the analytes and organic linkers of the material. Direct immersion (DI) SPME-gas chromatography-mass spectrometry methods based on NH 2 -MIL-53(Al) were successfully applied for the analysis of tap and river water samples. The recoveries were 80.3-115% for SMs and 77.4-117% for OCPs. These results indicate that the NH 2 -MIL-53(Al) coating may be a promising alternative to SPME coatings for the enrichment of SMs and OCPs.

Sustainable Catalysis: Rational Pd Loading on MIL-101Cr-NH2 for More Efficient and Recyclable Suzuki–Miyaura Reactions

Science.gov (United States)

Pascanu, Vlad; Yao, Qingxia; Bermejo Gómez, Antonio; Gustafsson, Mikaela; Yun, Yifeng; Wan, Wei; Samain, Louise; Zou, Xiaodong; Martín-Matute, Belén

2013-01-01

Palladium nanoparticles have been immobilized into an amino-functionalized metal–organic framework (MOF), MIL-101Cr-NH2, to form Pd@MIL-101Cr-NH2. Four materials with different loadings of palladium have been prepared (denoted as 4-, 8-, 12-, and 16 wt %Pd@MIL-101Cr-NH2). The effects of catalyst loading and the size and distribution of the Pd nanoparticles on the catalytic performance have been studied. The catalysts were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectroscopy, powder X-ray diffraction (PXRD), N2-sorption isotherms, elemental analysis, and thermogravimetric analysis (TGA). To better characterize the palladium nanoparticles and their distribution in MIL-101Cr-NH2, electron tomography was employed to reconstruct the 3D volume of 8 wt %Pd@MIL-101Cr-NH2 particles. The pair distribution functions (PDFs) of the samples were extracted from total scattering experiments using high-energy X-rays (60 keV). The catalytic activity of the four MOF materials with different loadings of palladium nanoparticles was studied in the Suzuki–Miyaura cross-coupling reaction. The best catalytic performance was obtained with the MOF that contained 8 wt % palladium nanoparticles. The metallic palladium nanoparticles were homogeneously distributed, with an average size of 2.6 nm. Excellent yields were obtained for a wide scope of substrates under remarkably mild conditions (water, aerobic conditions, room temperature, catalyst loading as low as 0.15 mol %). The material can be recycled at least 10 times without alteration of its catalytic properties. PMID:24265270

La prisión de Fray Luis

Directory of Open Access Journals (Sweden)

Victor Sánchez Montenegro

1960-11-01

Full Text Available Es una creencia general difundida por muchas historias de la literatura española y universal de que la principal causa de la prisión de Fray Luis de León en Valladolid por la Inquisición de esa ciudad, fue el haber traducido el Cantar de los Cantares, atribuidoa Salomón , es decir el Sir hassirim que los LXX tradujeron al griego Aisma Aismaton, y el Cantica Canticorum de la Vulgata. Sin embargo, como  pasaré a demostrar, no fue esa precisamente la causa de la tremenda injusticia sino otras presentarlas por sus enemigos , quienes en sus ataques hasta llegaron a probar que no descendía de Cristianos viejos sino que tenía sangre de judíos.

Puelles romero, Luis: Honoré Daumier: la risa republicana

Directory of Open Access Journals (Sweden)

Óscar Ortega Ruiz

2015-01-01

Full Text Available Recientemente, Abada Editores ha puesto a disposición de sus lectores el nuevo ensayo de Luis Puelles Romero, titular de Estética y Teoría de las Artes de la Universidad de Málaga. Honoré Daumier: la risa republicana se interna en la vida y la obra de este marsellés nacido en 1808 y muerto en París en 1879, cuyo trabajo se desarrolló durante cincuenta años decisivos de la historia de Francia, desde el final del periodo legitimista hasta los inicios de la III República.

Seroprevalencia de sífilis en mujeres embarazadas en San Luis Potosí Seroprevalence of syphilis in pregnant women in San Luis Potosí

OpenAIRE

Daniel E Noyola; Octavio Malacara-Alfaro; Victoria Lima-Rogel; Abraham Torres-Montes

2006-01-01

OBJETIVO: Determinar la seroprevalencia de sífilis en mujeres embarazadas. MATERIAL Y MÉTODOS: Encuesta seroepidemiológica en 1 857 mujeres que acudieron para la atención del parto a un hospital general de la ciudad de San Luis Potosí. RESULTADOS: Se diagnosticó sífilis en cinco (0.27%) mujeres al momento del parto. Los factores maternos asociados con una probabilidad superior de presentar sífilis incluyeron mayor edad materna, mayor número de embarazos previos y vivir en unión libre con su p...

The tectonic significance of K/Ar illite fine-fraction ages from the San Luis Formation (Eastern Sierras Pampeanas, Argentina)

Science.gov (United States)

Wemmer, Klaus; Steenken, André; Müller, Stefan; de Luchi, Mónica G. López; Siegesmund, Siegfried

2011-04-01

The Sierra de San Luis forms the southern tip of the Eastern Sierras Pampeanas in central Argentina. Two narrow belts of low-grade phyllites and quartz arenites, i.e. the San Luis Formation, have accommodated part of the strain-related differential exhumation of the medium- to high-grade metamorphic domains that constitute to the basement complex of the sierra. Eleven phyllite samples were subjected to the K/Ar fine-fraction dating technique. Results are interpreted in relation to the Kübler index of the illites, which indicate epimetamorphic conditions for the majority of the samples. Obtained ages between 330 and 290 Ma cover a period of compressional tectonics in the late Mississippian (Visean/Serpukhovian boundary) followed by the subsidence during the formation of the Paganzo Basin in the provinces of La Rioja and San Luis. These tectonic movements are coincident with the Toco orogeny in northern Chile and southern Bolivia. This suggests that the older K/Ar ages document the compressional stage and that younger ages record the cooling of the basement during the subsequent extensional uplift of the basement.

Metal organic framework MIL-101 for radioiodine capture and storage

Science.gov (United States)

Assaad, Thaer; Assfour, Bassem

2017-09-01

we report on the use of metal organic frameworks(MOFs) for radioiodine recovery and storage. One MOF (namely MIL-101) was prepared and investigated in detail to demonstrate the iodine removal efficiency and capacity of MOFs. The typical sorption kinetics and uptake isotherms were measured using radioactive iodine (123 I) for the first time. Our measurements indicate that MOFs can capture and store radioiodine in very high efficiency and fast kinetics.

Concentrations of persistent organic pollutants (POPs) and heavy metals in soil from San Luis Potosí, México.

Science.gov (United States)

Perez-Vazquez, Francisco Javier; Flores-Ramirez, Rogelio; Ochoa-Martinez, Angeles Catalina; Orta-Garcia, Sandra Teresa; Hernandez-Castro, Berenice; Carrizalez-Yañez, Leticia; Pérez-Maldonado, Iván N

2015-01-01

The aim of this study was to assess the levels of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), p,p'-dichlorodiphenyltrichloroethane (DDT), p,p'-dichlorodiphenyldichloroethylene (DDE), and four heavy metals (arsenic, cadmium, lead, and mercury) in soil from the city of San Luis Potosí in Mexico. In order to confirm the presence of the previously mentioned compounds, outdoor surface soil samples were collected and analyzed by gas chromatography/mass spectrometer for PBDEs, PCBs, DDT, and DDE. Meanwhile, heavy metals were quantified using the atomic absorption spectrophotometry technique. The total PBDEs levels ranged from 5.0 to 134 μg/kg dry weight (dw), with a total mean PBDEs level of 22.0 ± 32.5 μg/kg dw (geometric mean ± standard deviation). For PCBs, the total mean level in the studied soil was 21.6 ± 24.7 μg/kg dw (range, Luis Potosí, Mexico, and considering that soil is an important pathway of exposure for people, a biomonitoring program for the surveillance of the general population in the city of San Luis Potosi is necessary.

Enhanced catalytic activity over MIL-100(Fe) loaded ceria catalysts for the selective catalytic reduction of NO{sub x} with NH{sub 3} at low temperature

Energy Technology Data Exchange (ETDEWEB)

Wang, Peng [School of Environmental Science and Technology, Dalian University of Technology, Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), Dalian 116024 (China); Sun, Hong [School of Environmental & Chemical Engineering, Dalian Jiaotong University, Dalian 116028 (China); Quan, Xie, E-mail: quanxie@dlut.edu.cn [School of Environmental Science and Technology, Dalian University of Technology, Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), Dalian 116024 (China); Chen, Shuo [School of Environmental Science and Technology, Dalian University of Technology, Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China), Dalian 116024 (China)

2016-01-15

Highlights: • Nano-ceria was successfully encapsulated into MIL-100(Fe) for the SCR of NO{sub x}. • The incorporated ceria in MIL-100(Fe) showed high content of chemisorbed oxygen. • The added ceria into MIL-100(Fe) improved the formation of adsorbed NO{sub 2} species. • The addition of ceria into MIL-100(Fe) enhanced SCR activity at low temperature. - Abstract: The development of catalysts for selective catalytic reduction (SCR) reactions that are highly active at low temperatures and show good resistance to SO{sub 2} and H{sub 2}O is still a challenge. In this study, we have designed and developed a high-performance SCR catalyst based on nano-sized ceria encapsulated inside the pores of MIL-100(Fe) that combines excellent catalytic power with a metal organic framework architecture synthesized by the impregnation method (IM). Transmission electron microscopy (TEM) revealed the encapsulation of ceria in the cavities of MIL-100(Fe). The prepared IM-CeO{sub 2}/MIL-100(Fe) catalyst shows improved catalytic activity both at low temperatures and throughout a wide temperature window. The temperature window for 90% NO{sub x} conversion ranges from 196 to 300 °C. X-ray photoelectron spectroscopy (XPS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) analysis indicated that the nano-sized ceria encapsulated inside MIL-100(Fe) promotes the production of chemisorbed oxygen on the catalyst surface, which greatly enhances the formation of the NO{sub 2} species responsible for fast SCR reactions.

Homens, vítimas e autores de violência: a corrosão do espaço público e a perda da condição humana

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Rejane Aparecida Alves

2012-12-01

Full Text Available Trata-se de estudo qualitativo, realizado no Município de Ribeirão das Neves-MG, com o objetivo de compreender o envolvimento dos homens com a violência. A metodologia consistiu de grupos focais organizados segundo sexo, faixa etária e região administrativa do Município, sendo, ao todo, trinta grupos, com 231 participantes, recrutados aleatoriamente. Para analisar, foi utilizado o método hermenêutico-dialético e, à luz da teoria política de Hannah Arendt, a violência foi interpretada como dominação que perpassa as relações humanas. Homens e mulheres foram identificados como possíveis autores e vítimas de violência, o envolvimento de cada um sendo definido a partir de relações desiguais que estabelecem. Os números da violência, assim como as explicações centradas em teorias biológicas, podem levar à conclusão prematura de que os homens sejam mais violentos do que as mulheres. A fundamentação teórica e a contextualização mais profundas permitem clarear outras faces desse importante problema.

Ni foam-immobilized MIL-101(Cr) nanocrystals toward system integration for hydrogen storage

CSIR Research Space (South Africa)

Ren, Jianwei

2015-10-01

Full Text Available Metal–organic framework (MOF) materials are only obtained as loose powders with low packing density and thermal conductivity. To enable the developed MOF powdered materials to be utilized in a hydrogen storage system, in this study, MIL-101...

B-1 Aircraft Main Hydraulic Pump Tests With MIL-H-87257 Hydraulic Fluid

National Research Council Canada - National Science Library

Sharma, Shashi

1998-01-01

In an effort to convert the B-1 aircraft from MIL-H-5606 to M1-H-87257, the Air Force sponsored a study conducted by Rockwell International from April 1991 through June 1992, under contract F34601-89-C-0401...

Ship-in-a-bottle CMPO in MIL-101(Cr) for selective uranium recovery from aqueous streams through adsorption

Energy Technology Data Exchange (ETDEWEB)

De Decker, Jeroen [Department of Inorganic and Physical Chemistry, Center for Ordered Materials, Organometallics, and Catalysis (COMOC), Ghent University, Krijgslaan 281-S3, 9000 Ghent (Belgium); Folens, Karel [Laboratory of Analytical Chemistry and Applied Ecochemistry, Ghent University, Coupure Links 653, 9000 Ghent (Belgium); De Clercq, Jeriffa [Department of Materials, Textiles, and Chemical Engineering, Industrial Catalysis and Adsorption Technology (INCAT), Ghent University, Valentin, Vaerwyckweg 1, 9000 Ghent (Belgium); Meledina, Maria; Van Tendeloo, Gustaaf [EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp (Belgium); Du Laing, Gijs [Laboratory of Analytical Chemistry and Applied Ecochemistry, Ghent University, Coupure Links 653, 9000 Ghent (Belgium); Van Der Voort, Pascal, E-mail: pascal.vandervoort@ugent.be [Department of Inorganic and Physical Chemistry, Center for Ordered Materials, Organometallics, and Catalysis (COMOC), Ghent University, Krijgslaan 281-S3, 9000 Ghent (Belgium)

2017-08-05

Highlights: • Highly stable metal-organic framework, MIL-101(Cr), for uses in aqueous, acidic adsorption. • Uranium recovery from low concentration acidic solutions. • One-step ship-around-the-bottle synthetic approach to incorporate CMPO in MIL-101(Cr). • Highly selective U(VI) adsorbent in competition with a high variety of metals, incl. rare earths and transition metals. • Regenerable and reusable adsorbent via 0.1 M nitric acid stripping. - Abstract: Mesoporous MIL-101(Cr) is used as host for a ship-in-a-bottle type adsorbent for selective U(VI) recovery from aqueous environments. The acid-resistant cage-type MOF is built in-situ around N,N-Diisobutyl-2-(octylphenylphosphoryl)acetamide (CMPO), a sterically demanding ligand with high U(VI) affinity. This one-step procedure yields an adsorbent which is an ideal compromise between homogeneous and heterogeneous systems, where the ligand can act freely within the pores of MIL-101, without leaching, while the adsorbent is easy separable and reusable. The adsorbent was characterized by XRD, FTIR spectroscopy, nitrogen adsorption, XRF, ADF-STEM and EDX, to confirm and quantify the successful encapsulation of the CMPO in MIL-101, and the preservation of the host. Adsorption experiments with a central focus on U(VI) recovery were performed. Very high selectivity for U(VI) was observed, while competitive metal adsorption (rare earths, transition metals...) was almost negligible. The adsorption capacity was calculated at 5.32 mg U/g (pH 3) and 27.99 mg U/g (pH 4), by fitting equilibrium data to the Langmuir model. Adsorption kinetics correlated to the pseudo-second-order model, where more than 95% of maximum uptake is achieved within 375 min. The adsorbed U(VI) is easily recovered by desorption in 0.1 M HNO{sub 3}. Three adsorption/desorption cycles were performed.

Ship-in-a-bottle CMPO in MIL-101(Cr) for selective uranium recovery from aqueous streams through adsorption

International Nuclear Information System (INIS)

De Decker, Jeroen; Folens, Karel; De Clercq, Jeriffa; Meledina, Maria; Van Tendeloo, Gustaaf; Du Laing, Gijs; Van Der Voort, Pascal

2017-01-01

Highlights: • Highly stable metal-organic framework, MIL-101(Cr), for uses in aqueous, acidic adsorption. • Uranium recovery from low concentration acidic solutions. • One-step ship-around-the-bottle synthetic approach to incorporate CMPO in MIL-101(Cr). • Highly selective U(VI) adsorbent in competition with a high variety of metals, incl. rare earths and transition metals. • Regenerable and reusable adsorbent via 0.1 M nitric acid stripping. - Abstract: Mesoporous MIL-101(Cr) is used as host for a ship-in-a-bottle type adsorbent for selective U(VI) recovery from aqueous environments. The acid-resistant cage-type MOF is built in-situ around N,N-Diisobutyl-2-(octylphenylphosphoryl)acetamide (CMPO), a sterically demanding ligand with high U(VI) affinity. This one-step procedure yields an adsorbent which is an ideal compromise between homogeneous and heterogeneous systems, where the ligand can act freely within the pores of MIL-101, without leaching, while the adsorbent is easy separable and reusable. The adsorbent was characterized by XRD, FTIR spectroscopy, nitrogen adsorption, XRF, ADF-STEM and EDX, to confirm and quantify the successful encapsulation of the CMPO in MIL-101, and the preservation of the host. Adsorption experiments with a central focus on U(VI) recovery were performed. Very high selectivity for U(VI) was observed, while competitive metal adsorption (rare earths, transition metals...) was almost negligible. The adsorption capacity was calculated at 5.32 mg U/g (pH 3) and 27.99 mg U/g (pH 4), by fitting equilibrium data to the Langmuir model. Adsorption kinetics correlated to the pseudo-second-order model, where more than 95% of maximum uptake is achieved within 375 min. The adsorbed U(VI) is easily recovered by desorption in 0.1 M HNO 3 . Three adsorption/desorption cycles were performed.

Embarazo en la adolescencia: su comportamiento en San Luis Pregnancy in adolescence: its behavior in San Luis municipality

Directory of Open Access Journals (Sweden)

Dania Rangel Díaz

2012-08-01

Full Text Available Introducción: El embarazo en las edades tempranas, sin la adecuada preparación biológica y psicológica, trae al contraste una serie de dificultades y problemas. Objetivo: Evaluar el comportamiento del embarazo en la adolescencia en el municipio de "San Luis" durante el período 2005-2010. Material y método: Se realizó una investigación aplicada partiendo de los conocimientos teóricos y prácticos. A partir de la metodología cuantitativa se presenta un diseño longitudinal, retrospectivo, analítico y descriptivo. Se utilizó como universo (2165 todas las mujeres embarazadas desde enero de 2005 a diciembre del año 2010; la muestra la constituyeron todas las embarazadas adolescentes (405 pertenecientes al municipio San Luis. Las técnicas y procedimientos de obtención de la información fue a través de la revisión documental. Se hizo una minuciosa revisión de las historias clínicas y de la información que se guarda en archivo del departamento de genética municipal y se recolectaron datos como: la edad materna, causa del embarazo, ocupación, las enfermedades presentadas durante el embarazo, el peso al nacer y el abandono escolar. Se utilizó el método empírico empleando la media porcentual como medida de tendencia central para variables cualitativas. Resultados: Predominan las adolescentes entre 16 y 18 años de edad, todas estudiantes; la principal causa del embarazo fue el desconocimiento. Se realizó una captación precoz al mayor porciento de ellas; como la enfermedad asociada predominó la hipertensión arterial. Conclusiones: Se logró un peso adecuado al final de la gestación y en su mayoría las estudiantes no continuaron los estudios.Introduction: pregnancy in early ages, without sufficient biological and psychological preparation, brings about a series of difficulties and problems. Objective: to assess the behavior of pregnancy in adolescence in “San Luis” municipality during a five-year period (2005

Fossil content and structural relationships of the San Luis zone and the Caborca zone of NW Sonora, Mexico, suppression of the precambrian Z of Caborca

International Nuclear Information System (INIS)

Radelli, Luigi; Solis Weiss, Vivianne; Dorame Navarro, Miguel; De La Cruz Ortega, Lissette del Carmen; Urrutia, Jose

2008-01-01

In the Caborca region of western Sonora a Precambrian Z does not cover a unique Precambrian socle as previously believed. Two tectonic zones occur there instead: the San Luis Zone and the Caborca Zone. The first is comprised of the Precambrian San Luis socle of gneiss and granite, crossed by 1.1 Ga old anorthosites, the San Luis sedimentary cover, and, above it, a Lower Jurassic volcano-sedimentary sequence. The Caborca Zone consists of the Precambrian Bamori socle of parametamorphic rocks crossed by 1.1 Ga old Aibo granite, and of the Gamuza sedimentary cover. 1.1 Ga ago the two zones were far away from each other. They have been brought together by the Nevadian orogeny. Both zones are allochthonous, and the Caborca Zone is a nappe upon the San Luis Zone. The lowermost units of the Gamuza cover furnished psammocorals and a possible Pterophyllum jageri (?). Accordingly, its geological age is either Palaeozoic or Triassic.The San Luis cover furnished Nematophites [Prototaxites (?) and Nematothallus] from its lower part; Calcispongiae, Cardaicarpus' seeds, and Artisia from its upper part Thus, it is a Devono-Carboniferous unit. The study area belongs in the Baja-Borderland block, which underwent, an Eocene northwards drifting of about 900 - 1000 km, and a 30 celsius degrade to 40 celsius degrade clockwise rotation relative to the main part of Sonora.

Revisiting the Aluminum Trimesate-based MOF (MIL-96): from Structure Determination to the Processing of Mixed Matrix Membranes for CO2 Capture.

KAUST Repository

Benzaqui, Marvin; S. Pillai, Renjith; Sabetghadam, Anahid; Benoit, Virginie; Normand, Pé rine; Marrot, Jerome; Menguy, Nicolas; Montero, David; Shepard, William; Tissot, Antoine; Martineau-Corcos, Charlotte; Sicard, Clé mence; Mihaylov, Mihail; Carn, Florent; Beurroeis, Isabelle; Llewellyn, Philip L.; De Weireld, Guy; Hadjiivanov, Konstantin; Gascon, Jorge; Kapteijn, Freek; Maurin, Guillaume; Steunou, Nathalie; Serre, Christian

2017-01-01

A microporous Al trimesate-based metal-organic framework (MOF), denoted MIL-96-(Al), was selected as a porous hybrid filler for the processing of mixed matrix membranes (MMMs) for CO2/N-2 postcombustion separation. First, the structural model of MIL-96-(Al) initially reported was revisited using a combination of synchrotron-based single-crystal X-ray diffraction, solid-state nuclear magnetic resonance spectroscopy, and density functional theory (DFT) calculations. In a second step, pure MIL-96-(Al) crystals differing by their size and aspect ratio, including anisotropic hexagonal platelets and nanoparticles of about 70 nm in diameter, were prepared. Then, a combination of in situ IR spectroscopy, single-gas, and CO2/N-2 coadsorption experiments, calorimetry, and molecular simulations revealed that MIL-96-(Al) nanoparticles show a relatively high CO2 affinity over N-2 owing to strong interactions between CO2 molecules and several adsorption sites such as Al3+ Lewis centers, coordinated water, and hydroxyl groups. Finally, the high compatibility between MIL-96-(Al) nanoparticles and the 6FDA-DAM polymer allowed the processing of homogeneous and defect-free MMMs with a high MOF loading (up to 25 wt %) that outperform pure polymer membranes for CO2/N-2 separation.

Revisiting the Aluminum Trimesate-based MOF (MIL-96): from Structure Determination to the Processing of Mixed Matrix Membranes for CO2 Capture.

KAUST Repository

Benzaqui, Marvin

2017-11-08

A microporous Al trimesate-based metal-organic framework (MOF), denoted MIL-96-(Al), was selected as a porous hybrid filler for the processing of mixed matrix membranes (MMMs) for CO2/N-2 postcombustion separation. First, the structural model of MIL-96-(Al) initially reported was revisited using a combination of synchrotron-based single-crystal X-ray diffraction, solid-state nuclear magnetic resonance spectroscopy, and density functional theory (DFT) calculations. In a second step, pure MIL-96-(Al) crystals differing by their size and aspect ratio, including anisotropic hexagonal platelets and nanoparticles of about 70 nm in diameter, were prepared. Then, a combination of in situ IR spectroscopy, single-gas, and CO2/N-2 coadsorption experiments, calorimetry, and molecular simulations revealed that MIL-96-(Al) nanoparticles show a relatively high CO2 affinity over N-2 owing to strong interactions between CO2 molecules and several adsorption sites such as Al3+ Lewis centers, coordinated water, and hydroxyl groups. Finally, the high compatibility between MIL-96-(Al) nanoparticles and the 6FDA-DAM polymer allowed the processing of homogeneous and defect-free MMMs with a high MOF loading (up to 25 wt %) that outperform pure polymer membranes for CO2/N-2 separation.

Ratiometric Fluorescence Sensing and Real-Time Detection of Water in Organic Solvents with One-Pot Synthesis of Ru@MIL-101(Al)-NH2.

Science.gov (United States)

Yin, Hua-Qing; Yang, Ji-Chun; Yin, Xue-Bo

2017-12-19

Ratiometric fluorescence detection attracts much attention because of its decreased environmental influence and easy-to-differentiate color and intensity change. Herein, a guest-encapsulation metal-organic framework (MOF), Ru@MIL-NH 2 , is prepared with 2-aminoterephthalic acid, AlCl 3 , and Ru(bpy) 3 2+ by a simple one-pot method for ratiometric fluorescence sensing of water in organic solvents. The rational selection of the excitation wavelength provides dual emission at 465 and 615 nm from Ru@MIL-NH 2 under a single excitation of 300 nm. High sensitivity, low detection limit (0.02% v/v), wide response range (0-100%), and fast response (less than 1 min) are obtained for ratiometric fluorescence sensing of water under single excitation with Ru@MIL-NH 2 as the probe. Moreover, the result of water content is independent of the concentration of Ru@MIL-NH 2 as the merit of ratiometric fluorescence detection. The response mechanism reveals that the protonation of the nitrogen atom of the MIL-NH 2 , the π-conjugation system, and the stable fluorescence of Ru(bpy) 3 2+ achieve the ratiometric fluorescence. The analysis of real spirit samples confirms the proposed method. A test strip is prepared with Ru@MIL-NH 2 for convenient use. We believe that such turn-on ratiometric host-guest MOFs and the rational selection of excitation wavelength will offer guidance for ratiometric fluorescence detection with wide applications.

Dye-sensitized MIL-101 metal organic frameworks loaded with Ni/NiOx nanoparticles for efficient visible-light-driven hydrogen generation

Directory of Open Access Journals (Sweden)

Xin-Ling Liu

2015-10-01

Full Text Available The Ni/NiOx particles were in situ photodeposited on MIL-101 metal organic frameworks as catalysts for boosting H2 generation from Erythrosin B dye sensitization under visible-light irradiation. The highest H2 production rate of 125 μmol h−1 was achieved from the system containing 5 wt. % Ni-loaded MIL-101 (20 mg and 30 mg Erythrosin B dye. Moreover, the Ni/NiOx catalysts show excellent stability for long-term photocatalytic reaction. The enhancement on H2 generation is attributed to the efficient charge transfer from photoexcited dye to the Ni catalyst via MIL-101. Our results demonstrate that the economical Ni/NiOx particles are durable and active catalysts for photocatalytic H2 generation.

Emma Zunz by Jorge Luis Borges: the Concept of Justice

OpenAIRE

Rosa Vila

2014-01-01

Emma Zunz, by Jorge Luis Borges, is the story of a girl who decides to kill her boss in order to avenge her father’s death, believing that her father’s version of an event that occurred years before was true. Thus, she devises a secret plan, which includes losing her virginity to a complete stranger, shortly before committing the crime, so she could argue that her boss had raped her and that she killed him in self-defense. Firstly, the text shows the contrast between formal justic...

Entrevista con Luis Ramiro Beltrán Salmón

Directory of Open Access Journals (Sweden)

Fanny Patricia Franco Chávez

2011-01-01

Full Text Available Luis Ramiro Beltrán es un personaje obligado a la hora de hablar de la relación entre la comunicación y el desarrollo. En la siguiente entrevista, conocemos la génesis de este campo a través de un personaje que nos comparte su perfil como pionero y sus experiencias iniciales en Latinoamérica para acercarnos a las primeras definiciones de este campo y a lo que debe ser esencial en la formación del perfil de un comunicador para el desarrollo social.

MIL-STD-2411-1 Change 3. Notice Impacts to NAVAIR

Science.gov (United States)

2010-07-30

Macedonia ZX Macais Nguema Biyogo MA Madagascar VD Madeira Islands (PO) MI Malawi MY Malaysia MV Maldives ML Mali MT Malta IM Isle of Man (UK) MIL...and Niger) PON Pointe Noire 1948 (Congo) POS Porto Santo 1936 (Porto Santo, Madeira Islands) HIT Prov. S. Chilean (S. Chile, 53 S.) PRPM Prov. S...Asia (Southeast Asia, Singapore) POS SE Base (Porte Santo) (Porto Santo & Madeira Islands) GRA SW Base (Faial, Graciosa, Pico, Sao Jorge, and

Magnetic solid phase extraction of typical polycyclic aromatic hydrocarbons from environmental water samples with metal organic framework MIL-101 (Cr) modified zero valent iron nano-particles.

Science.gov (United States)

Zhou, Qingxiang; Lei, Man; Wu, Yalin; Yuan, Yongyong

2017-03-03

Metal-organic framework material has been paid more attention because of its good physical and chemical properties. Nanoscale zero valent iron is also in the center of concern recently. Combination of their merits will give impressive results. Present study firstly synthesized a new magnetic nanomaterial nano-scale zero valent iron-functionalized metal-organic framworks MIL-101 (Fe@MIL-101) by co-precipitation method. The morphology and structure of the as-prepared Fe@MIL-101 were characterized by transmission electron microscopy and X-ray diffraction, etc. The experimental results showed that Fe@MIL-101 earned good adsorption ability to polycyclic aromatic hydrocarbons. The limits of detection of developed magnetic solid phase extraction were all below 0.064μgL -1 and precision can be expressed as relative standard deviation (RSD, %) and which was better than 4.4% (n=6). The real water analysis indicated that the spiked recoveries were satisfied, and Fe@MIL-101 earned excellent reusability. All these demonstrated that Fe@MIL-101 exhibited excellent adsorption capability to polycyclic aromatic hydrocarbons and would be a good adsorbent for development of new monitoring methods for environmental pollutants. Copyright © 2017 Elsevier B.V. All rights reserved.

Missionary Pragmalinguistics: Father Diego Luis de Sanvitores’ grammar within the tradition of Philippine grammars

NARCIS (Netherlands)

Winkler, A.P.

2016-01-01

The grammar written in Latin, in 1668, by the Jesuit missionary Father Diego Luis de Sanvitores (1627-1672) is the oldest description we have of Chamorro, a language spoken on the Mariana islands. The grammar received a number of bad reviews and as a consequence has become neglected and almost

Luis Llach : el arquitecto de Quibdó

Directory of Open Access Journals (Sweden)

Luis Fernando González Escobar

1993-09-01

Full Text Available En el año 1907, en varias ediciones del periódico Ecos del Chocó, de la ciudad de Quibdó, apareció un anuncio en donde un tal Luis Llach Ll., ostentando el título de ingeniero civil, ofertaba sus servicios para la "Construcción de toda clase de edificios, Levantamientos de planos. elaboración de presupuestos, etc. y toda lo concerniente al ramo de ingeniería, contando para el efecto con instrumentos modernos y personal idóneo" ¿La dirección? El lado sur del Convento. ¿Quién era este "ingeniero" y cuáles eran las razones que lo condujeron a establecerse en una localidad que por esos años no era más que un villorrio con algo menos de 12.000 habitantes?

Reduced blood nrf-2 mRNA in local overweight boys at risk of metabolic complications: a study in San Luis City, San Luis, Argentina.

Science.gov (United States)

Santillán, Lucas D; Moyano, Marta; Frau, Martín; Flores, Orlando; Siewert, Susana; Zirulnick, Fanny; Ramirez, Dario C; Giménez, Maria S

2013-10-01

Childhood overweight (OW) is a matter of public health concern because of its long-term impact on adulthood health. NF-E2-related factor 2 (Nrf-2) regulates the antioxidant/lipogenic response to a sustained positive energy balance that prevails during weight gain. Here we aimed at studying a possible link between OW and Nrf-2-dependent antioxidant/lipogenic response in a local population of boys at risk of metabolic complications. We measured clinical and biochemical parameters related to lipid metabolism, oxidative stress, and metabolic syndrome in a population of OW boys [body mass index (BMI) percentile ≥85(th) and Luis City, San Luis, Argentina. Compared to NW, OW boys had lower insulin sensitivity, an altered plasma lipid profile, and increased markers of oxidative stress and inflammatory fatty acids. OW boys also had a higher atherogenic index and peripheral insulin resistance than NW boys. We also found that glutathione peroxidase activity and the reduced glutathione to oxidized glutathione ratio were lower in OW boys than NW boys, suggesting that OW boys may have an altered antioxidant response to oxidative stress. Finally, Nrf-2 expression negatively correlated with metabolic syndrome parameters in OW boys. Our data suggest that OW boys have a reduced antioxidant and lipogenic response to a positive energy balance, resulting in oxidative stress, insulin resistance, and risk of developing metabolic complications. Our data also provide a rationale for nutritional interventions aimed at restoring Nrf-2 expression to reduce the risk of metabolic complications in OW boys.

Behemoth, Lilith e Anjos: três monstros judaicos em Jorge Luis Borges

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Marcos Fábio de Faria

2009-10-01

Full Text Available Análise dos verbetes de monstros judaicos recriados por Jorge Luis Borges em Manual de zoologia fantástica e O livro dos seres imaginários, a saber: Behemoth, Lilith e os anjos Haniel, Kazfiel, Azriel e Aniel. As múltiplas representações e versões desses verbetes, bem como seu diálogo com a Torah e sua inscrição na literatura.

Juizados Especiais e Ativismo Judicial à Luz de Luis Alberto Warat

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Zenildo Bodnar

2012-07-01

Full Text Available This article addresses, in a punctual way, some reflections on the judicial activism in the Special Courts camp. It seeks to evaluate the existence of a place for the conciliator in the stir that permeates the procedural and substantial models of legal proceedings. For this, as theoretical references, the postulates of Luis Alberto Warat are used, in order to overcome such dyad in favor of an effective judicial protection, without following the ways of the Free Movement of Law and Instrumentality of Process. For the development of this research, it has been used the inductive method, operated by the operational concepts and techniques of literature.Resumo: O presente artigo aborda de forma pontual algumas reflexões sobre o ativismo judicial na seara dos Juizados Especiais. Procura-se avaliar a existência de um lugar para o conciliador na celeuma que permeia os modelos procedimentalistas e substancialistas de processo jurisdicional. Para tanto, como referencial teórico utiliza-se os postulados de Luis Alberto Warat no intuito de superar a referida díade em favor de uma tutela judicial efetiva, sem que se trilhe os caminhos do Movimento do Direito Livre e da Instrumentalidade do Processo. Utilizou-se, para o desenvolvimento desta pesquisa, o método indutivo, operacionalizado pelas técnicas de conceitos operacionais e da pesquisa bibliográfica.

As políticas de combate à violência contra a mulher no Brasil e a "responsabilização" dos "homens autores de violência"

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Aparecida Fonseca Moraes

Full Text Available O artigo analisa os significados que os homens acusados de violência atribuem às agressões perpetradas contra as mulheres, no contexto da Lei Maria da Penha e de suas políticas públicas no Brasil. Chama a atenção também para as possíveis contribuições da abordagem interacionista e para a importância do foco nas ideias e nos valores nas análises das políticas públicas, principalmente aquelas que alcançam as identidades. A pesquisa realizada em Grupos de Reflexão para homens autores de violência em um Juizado de Violência Doméstica e Familiar contra a Mulher na cidade do Rio de Janeiro mostrou como alguns valores e ideias difundidos, como aqueles associados à "responsabilização" do agressor, são confrontados pelos homens. Muitas vezes eles recorrem às circunstâncias da situação nas quais ocorreram os conflitos interpessoais do casal de modo a denotar as agressões como uma resposta, ou até mesmo punição, ao comportamento inadequado das mulheres, que teriam desafiado a divisão tradicional dos papéis de gênero, reconhecida por eles como universalmente aceita.

Luis Huerta: eugenesia, medicina y pedagogía en España Luis Huerta: Eugenics, Medicine and Pedagogy in Spain

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Luis Miguel LÁZARO LORENTE

2013-07-01

Full Text Available En contraste con lo observable en la historiografía de otros países europeos y anglosajones, el estudio de la introducción y difusión de los principios y prácticas de la Eugenesia, como tema de investigación, no ha contado en España con muchos cultivadores. Menos todavía han sido objeto de estudio las relaciones del pensamiento eugénico con el ámbito pedagógico para indagar la recepción que tiene entre el Magisterio, y conocer el conjunto de reacciones que provoca, así como la participación de los maestros en la potencial difusión de sus planteamientos. Se aborda aquí una aproximación a ese tema centrando el análisis en las relaciones que en la España del primer tercio del siglo XX se establecen entre Medicina, Pedagogía y Eugenesia. Para ello tomamos como referente e hilo conductor la figura y el pensamiento del maestro asturiano Luis Huerta Naves, decidido impulsor y propagandista incansable de la Eugenesia en nuestro país.By comparison with the historiography of other European and Anglo-Saxon countries, the study of the origins and spread of Eugenics in Spain has not received much attention. Even less research has been done on the degree of acceptance of eugenic thought in the pedagogical domain or on the role teachers may have in the diffusion of eugenics. This paper attempts to explore the subject while focusing the analysis on the relations that were established among Medicine, Pedagogy and Eugenics in Spain during the first third of the 20th century. We will take as a point of reference and guiding line of thought the figure of the Asturian teacher Luis Huerta Naves, who was the driving force and tireless advocate of the eugenics movement in our country.

Mesquite: A multi-purpose species in two locations of San Luis Potosi, Mexico

Science.gov (United States)

Jose Villanueva-Diaz; Augustin Hernandez-Reyna; J. Armando Ramirez-Garcia

2000-01-01

The mesquite woodland distributed in approximately 200,000 ha in Llanos de Angostura, and Pozo del Carmen, San Luis Potosi, represents a main source of firewood, construction material, honey, and forage for the rural people that inhabit part of the lowlands of the hydrological region RH26 and RH37. Firewood collection in this region averages 142 m3 /week. Most of this...

Mil doscientos títulos de antropología colombiana: primera parte

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Manuel Lucena Salmoral

1969-08-01

Full Text Available La aparición de estos mil doscientos títulos sobre antropología Colombiana representa un esfuerzo juvenil de universitarios javerianos, pertenecientes a distintas ciencias sociales, quienes fueron confluyendo a mis clases de Antropología Cultural guiados por la misma problemática: la búsqueda del hombre.

Fabrication of core-shell Fe{sub 3}O{sub 4}@MIL-100(Fe) magnetic microspheres for the removal of Cr(VI) in aqueous solution

Energy Technology Data Exchange (ETDEWEB)

Yang, Qingxiang, E-mail: qxyangzz@163.com; Zhao, Qianqian; Ren, ShuangShuang; Lu, Qiongqiong; Guo, Xinmeng; Chen, Zhijun, E-mail: chenzj@zzuli.edu.cn

2016-12-15

Facile regeneration of an adsorbent is very important for commercial feasibility. One typical highly porous metal-organic framework (MOF) materials based on MIL-100(Fe) and magnetic iron oxide particles (denoted as MMCs) with diameter about of 350 nm were successfully synthesized. The growth of MIL-100(Fe) shell on the surface of Fe{sub 3}O{sub 4} was utilized precursor as crystal seed via in-situ step hydrothermal reaction. It is a simple way to obtain well organized core-shell MOF composites, compared to the step-by-step method. MMCs were firstly used to uptake of Cr(VI) anions in aqueous solution. Adsorption experiments were carried out in batch sorption mode investigating with the factors of contact time (0–1000 min), pH (from 2 to 12), dose of adsorbent (4–25 mg), and initial Cr(VI) concentration (range from 10 to 100 ppm). - Graphical abstract: One typical highly porous metal-organic framework (MOF) materials based on MIL-100(Fe) and magnetic iron oxide particles (denoted as MMCs) were successfully synthesized. Utilizing Fe{sub 3}O{sub 4} precursor as crystal seed to grow MIL-100(Fe) shell by in-situ step hydrothermal reaction. It is a simple way to obtain core-shell MOF composites. MMCs could effectively uptake of Cr(VI) anions in aqueous solution. - Highlights: • Fe{sub 3}O{sub 4}@MIL-100(Fe) composites with core-shell structure were successfully prepared through a simple method. • The influence factors on Cr(VI) adsorption by Fe{sub 3}O{sub 4}@MIL-100(Fe) were investigated. • Cr(VI) can efficiently adsorbed by Fe{sub 3}O{sub 4}@MIL-100(Fe) composites from aqueous solution.

A sensitive and selective sensor for biothiols based on the turn-on fluorescence of the Fe-MIL-88 metal-organic frameworks-hydrogen peroxide system.

Science.gov (United States)

Sun, Zheng Juan; Jiang, Jun Ze; Li, Yuan Fang

2015-12-21

Herein, we present a novel strategy based on a "turn-on" fluorescence system made up of metal-organic frameworks Fe-MIL-88 and H2O2 for detecting biothiols in human serum. The nonfluorescent Fe-MIL-88 gives weak fluorescence in the presence of H2O2. Interestingly, it was found that biothiols such as glutathione (GSH), cysteine (Cys) or homocysteine (Hcy) could induce fluorescence turn-on of the Fe-MIL-88/H2O2 system. Under optimal conditions, the relative fluorescence intensity exhibited a good linear relationship in the range from 50 nM-10 μM for GSH (r = 0.994), 50 nM-10 μM for Cys (r = 0.990), and 50 nM-10 μM (r = 0.992) for Hcy; the detection limits of GSH, Cys and Hcy were 30 nM, 40 nM, and 40 nM respectively. Mechanism investigation reveals that biothiols could associate with Fe-MIL-88 via hydrogen bonding and electrostatic interaction followed by redox reaction between biothiols and Fe(3+) present in the Fe-MIL-88, Fe(3+) was thus reduced to Fe(2+), and then Fe(2+) could efficiently catalyze the decomposition of H2O2 to yield ˙OH radicals through the Fenton reaction. Besides, biothiols were able to reduce H2O2 to produce ˙OH radicals directly. Thus the Fe-MIL-88 as well as biothiols could cooperatively contribute to the activation of H2O2 to generate higher amounts of ˙OH radicals, which in turn oxidize the free ligand terephthalic acid (BDC) outside or within the Fe-MIL-88 structure to strongly fluorescent hydroxylated terephthalic acid (OHBDC), thereby turning on the fluorescence.

MIL-125-NH2@TiO2 Core-Shell Particles Produced by a Post-Solvothermal Route for High-Performance Photocatalytic H2 Production.

Science.gov (United States)

Zhang, Bingxing; Zhang, Jianling; Tan, Xiuniang; Shao, Dan; Shi, Jinbiao; Zheng, Lirong; Zhang, Jing; Yang, Guanying; Han, Buxing

2018-05-02

Metal-organic frameworks (MOFs) have proven to be an interesting class of sacrificial precursors of functional inorganic materials for catalysis, energy storage, and conversion applications. However, the controlled synthesis of MOF-derived materials with desirable compositions, structures, and properties still remains a big challenge. Herein, we propose a post-solvothermal route for the outer-to-inner loss of organic linkers from MOF, which is simple, rapid, and controllable and can be operated at temperature much lower than that of the commonly adopted pyrolysis method. By such a strategy, the MIL-125-NH 2 particles coated by TiO 2 nanosheets were produced, and the thickness of TiO 2 shell can be easily tuned. The MIL-125-NH 2 @TiO 2 core-shell particles combine the advantages of highly active TiO 2 nanosheets, MIL-125-NH 2 photosensitizer, plenty of linker defects and oxygen vacancies, and mesoporous structure, which allows them to be utilized as photocatalysts for the visible-light-driven hydrogen production reaction. It is remarkable that the hydrogen evolution rate by MIL-125-NH 2 @TiO 2 can be enhanced 70 times compared with the pristine MIL-125-NH 2 . Such a route can be easily applied to the synthesis of different kinds of MOF-derived functional materials.

MIL-STD-1553B Marconi LSI chip set in a remote terminal application

Science.gov (United States)

Dimarino, A.

1982-11-01

Marconi Avionics is utilizing the MIL-STD-1553B LSI Chip Set in the SCADC Air Data Computer application to perform all of the required remote terminal MIL-STD-1553B protocol functions. Basic components of the RTU are the dual redundant chip set, CT3231 Transceivers, 256 x 16 RAM and a Z8002 microprocessor. Basic transfers are to/from the RAM command of the bus controller or Z8002 processor. During transfers from the processor to the RAM, the chip set busy bit is set for a period not exceeding 250 microseconds. When the transfer is complete, the busy bit is released and transfers to the data bus occur on command. The LSI Chip Set word count lines are used to locate each data word in the local memory and 4 mode codes are used in the application: reset remote terminal, transmit status word, transmitter shut-down, and override transmitter shutdown.

ÎNCEPUTURILE FILOSOFICE ALE LUI LUCIAN BLAGA

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Svetlana COANDĂ

2016-12-01

Full Text Available În articol sunt evidenţiate etapele evoluţiei spirituale a lui Lucian Blaga, este demonstrată importanţa primei perioade de activitate a gânditorului român, perioada anilor 1914-1919, care constituie începutul activităţii filosofice a lui L.Blaga, acesta fiind deosebit de semnificativ pentru înţelegerea genezei ideilor sale, a influenţelor pe care le-a suportat, a continuităţii tematicii şi reflecţiilor filosofice, care au culminat cu elaborarea unui profund sistem filosofic. Sunt analizate în detaliu ideile filosofice centrale, temele de meditaţie din lucrările scrise şi publicate de L.Blaga între anii 1914 şi 1919: analiza şi aprecierea ideilor filosofului francez Henri Bergson, coraportul dintre filosofie şi ştiinţă, aportul specific al filosofiei la formarea concepţiei despre lume a personalităţii, rolul deosebit de important al metodelor de cercetare în asigurarea obţinerii adevărului în procesul de cunoaştere, unitatea formelor culturii etc.THE PHILOSOFICAL BEGINNINGS OF LUCIAN BLAGAThis article highlights the spiritual evolution steps of Lucian Blaga and demonstrates the importance of the first period of activity of the Romanian thinker - the period between 1914 and 1919. This time frame constitutes the beginning of his philosophical activity and it is especially significant to understand the genesis of his ideas, of his influences, the continuity of the philosophical themes and reflections that culminated with the elaboration of a profound philosophical system. Analysis is done over the central philosophical ideas, the meditation themes from the works written and published by Lucian Blaga between 1914 and 1919: the analysis and appreciation of the ideas of the French philosopher Henri Bergson, the correlation between philosophy and science, the specific input of philosophy in the formation of the world conception on personality, the extremely important role of the research methods in ensuring the

Synthesis and sonocatalytic performance of a ternary magnetic MIL-101(Cr)/RGO/ZnFe2O4 nanocomposite for degradation of dye pollutants.

Science.gov (United States)

Nirumand, Ladan; Farhadi, Saeed; Zabardasti, Abedin; Khataee, Alireza

2018-04-01

In this study, new ternary magnetic MIL-101(Cr)/RGO/ZnFe 2 O 4 catalyst (with 30% wt of ZnFe 2 O 4 ) was synthesized via a hydrothermal route for sonodegradation of organic dyes. The structural, optical and magnetic properties of the nanocomposite were detected by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy (UV-visible), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, vibrating sample magnetometer (VSM), atomic force microscopy (AFM), Raman spectroscopy and BET surface area analysis. To evaluate the sonocatalytic activity of the as-prepared MIL-101(Cr)/RGO/ZnFe 2 O 4 nanocomposite, the H 2 O 2 -assisted degradation of organic dyes such as congo red (CR), methylene blue (MB), Rhodamine B (RhB) and methyl orange (MO) in aqueous solution was studied under ultrasound irradiation. The obtained results indicated that the ternary MIL-101(Cr)/RGO/ZnFe 2 O 4 nanocomposite had better performance for sonodegradation of these dyes than MIL-101(Cr)/RGO, pure MIL-101(Cr) or ZnFe 2 O 4 . The enhanced sonocatalytic performance of the as-prepared ternary nanocomposite could be attributed to the fast generation and separation of charge carriers (electrons and holes) in ZnFe 2 O 4 and MIL-101(Cr) and their transfer to the surface of graphene sheets. Moreover, the relatively high specific surface area of the MIL-101(Cr)/rGO and magnetic property of ZnFe 2 O 4 improve the degradation efficiency of the dyes. The recovery of the ternary magnetic sonocatalyst from treated water could be easily achieved using an external magnetic field. The main influence factors on the sonocatalytic activity such as catalyst dosage and dye initial concentration were also investigated. The trapping experiments indicated that OH radicals are the prominent active species in dye degradation. In addition, the reusability test, was also carried out to ensure the stability of the employed sonocatalyst

Effects of ductile phase volume fraction on the mechanical properties of Ti-Al3Ti metal-intermetallic laminate (MIL) composites

International Nuclear Information System (INIS)

Price, Richard D.; Jiang Fengchun; Kulin, Robb M.; Vecchio, Kenneth S.

2011-01-01

Research highlights: → Residual Al improves the mechanical properties of Ti-Al 3 Ti MIL composites. → Residual Al can eliminate intermetallic centerline delaminations in MILs. → Low levels of residual Al increase fracture toughness in MIL composites. → MIL stiffness, strength, and fracture toughness can be optimized at low Al levels. - Abstract: Metal-intermetallic laminate (MIL) composites consisting of alternating layers of Ti, Al, and the intermetallic Al 3 Ti have been fabricated by reactive foil sintering in open air. Six initially identical stacks of alternating Ti-3Al-2.5 V and 1100-Al foils were processed for different lengths of time, yielding specimens with different metal and intermetallic volume fractions. Their mechanical properties have been investigated with an emphasis on the effect of residual Al at the intermetallic centerline on composite strength and fracture toughness, as well as fracture and failure modes. Samples were cut from each composite plate (in layer orientations parallel and perpendicular to the intended load direction) for mechanical testing in compression and four-point bending under quasi-static and high-rate loading conditions. Examination of the damaged specimens and their fracture surfaces by optical and scanning electron microscopy was performed to establish a correlation between the failure mechanisms present, composite strength, and microstructure. Results indicated that regardless of loading direction, cracks always initiated in the intermetallic region, rarely at the centerline, and crack propagation and failure were heavily influenced by the thickness of the residual aluminum layers. There is an ideal residual aluminum volume fraction that represents the amount of ductile reinforcement that maximizes the combined properties of strength, toughness and stiffness.

Emphatic or Reflexive? On the Endophoric Character of French "lui-meme" and Similar Complex Pronouns.

Science.gov (United States)

Zribi-Hertz, Anne

1995-01-01

This study examined the referential properties of a class of complex pronouns labelled M-Pronouns, exemplified by Old English "himself," French "lui-meme," and English "his own." It is shown that M-Pronouns exhibit some properties commonly taken as characterizing reflexive anaphors, and that they also occur as…

Uranium occurrences in the pegmatite 'Las Cuevas', province of San Luis, Argentine Republic

International Nuclear Information System (INIS)

Daziano, C.O.; Karlsson, A.C.; Ayala, R.

1993-01-01

Mineral associations found in an uranium deposit of Sierras Pampeanas, San Luis, are considered in these papers. Damourite stands out among the uranium minerals related to uraninite and coffinite. Pyrite, marcasite and other sulphides are found together with apatite and gummite. Autunite is the uranium secondary mineral more abundant. A mineralization with epigenetic contribution by circulating solutions is suggested to the studied area. (Author)

The nuclear industry is about to begin a new dynamic. Interview with Luis Echavarri

Energy Technology Data Exchange (ETDEWEB)

Mitev, Lubomir [NucNet, Brussels (Belgium)

2014-05-15

The nuclear industry has changed significantly in the 17 years since Luis Echavarri became director-general of the Organisation for Economic Development and Cooperation's (OECD) Paris-based Nuclear Energy Agency (NEA). As he approaches retirement, Mr Echavarri speaks to NucNet about the priorities for the industry as it enters the post-Fukushima era. (orig.)

Tendência da mortalidade por suicídio na população brasileira e idosa, 1980-2006

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Maria Cecília de Souza Minayo

2012-04-01

Full Text Available OBJETIVO: Descrever a mortalidade por suicídio no Brasil, com destaque para a população idosa. MÉTODOS: Análise temporal e estudo de tendência por regressão polinomial de suicídios na população acima de dez anos no Brasil e no Estado do Rio de Janeiro de 1980 a 2006. Os dados foram extraídos do Sistema de Informações sobre Mortalidade e as taxas, calculadas segundo sexo e faixa etária, considerando-se a população residente fornecida pelo Datasus por 100 mil habitantes. Para os anos de 1980 a 1995, utilizou-se a nona revisão da Classificação Internacional de Doenças e Problemas Relacionados à Saúde, e para 1996 a 2006, a décima revisão. RESULTADOS: Crescimento significativo foi observado nas taxas de suicídio na população brasileira e no Rio de Janeiro (5,7 e 3,1 para cada 100 mil habitantes, respectivamente em 2006. Esse incremento ocorreu pelo aumento dos suicídios na população masculina em todas as idades. A curva crescente aconteceu principalmente entre homens maiores de 60 anos. O incremento não foi estatisticamente significativo entre homens e houve decréscimo entre mulheres no Rio de Janeiro. Os principais meios de suicídio utilizados pelos homens foram enforcamento, sufocação, estrangulamento e armas de fogo. Para as mulheres, o enforcamento também ocupou a primeira posição, seguido pela ingestão de substâncias, atiramento ao fogo e precipitação de altura. A elevada taxa de indefinição dos meios ressaltou problemas na qualidade dos dados. CONCLUSÕES: Suicídios são eventos significantes na população masculina, sobretudo entre homens idosos, ao longo do tempo. No Rio de Janeiro, as taxas entre homens idosos também são maiores, mas não estatisticamente significantes. Segundo a Organização Mundial da Saúde e o Ministério da Saúde, o suicídio é passível de prevenção e existem cuidados preconizados para cada grupo etário.

Relação entre nível de atividade física e disfunção erétil em homens com idade entre 40 e 75 anos

OpenAIRE

Agostini, Lucas Côrtes Machado

2010-01-01

INTRODUÇÃO: A disfunção erétil possui alta prevalência em homens com 40 a 70 anos e tem se tornado um marcador de maior risco cardiovascular. Homens que adotam mudanças no estilo de vida, incluindo atividades físicas e perda de peso melhoram sua função erétil. OBJETIVO: Avaliar a presença da associação entre o nível de atividade física, o nível de condicionamento físico e características (obesidade, dislipidemia e aumento do volume abdominal) e hábitos (tabagismo) de maior risco cardiovascula...

Separation properties of the MIL-125(Ti) Metal-Organic Framework in high-performance liquid chromatography revealing cis/trans selectivity.

Science.gov (United States)

Van der Perre, Stijn; Liekens, Anuschka; Bueken, Bart; De Vos, Dirk E; Baron, Gino V; Denayer, Joeri F M

2016-10-21

Monodisperse MIL-125(Ti) Metal-Organic Framework crystals were synthesized and studied as stationary phase in high performance liquid chromatography (HPLC). Different pure compounds and model mixtures (including stereoisomer mixtures) were injected from which chromatographic parameters, including selectivities and resolution factors, were determined to evaluate the adsorption properties and separation performance of MIL-125(Ti) in liquid phase. The MIL-125(Ti) framework displayed a trans selectivity for cis/trans difunctionalized cyclohexane molecules with high selectivity and resolution for 1,3-dimethylcyclohexane and 4-ethylcyclohexanol. The slurry-packed column was further characterized via van Deemter analysis. Fitting of the van Deemter equation through the experimental points allowed to define the contributions of the different processes to plate height with a significant proportion of the A-term, reflecting the importance of a good crystal packing. Although high in comparison to commercial HPLC stationary phases, a very good plate height of around 50μm was found. Copyright © 2016 Elsevier B.V. All rights reserved.

Mineralogical characterization of historical portuguese wall tiles of Sao Luis, Maranhao, Brazil; Caracterizacao mineralogica de azulejos portugueses do Centro Historico de Sao Luis do Maranhao

Energy Technology Data Exchange (ETDEWEB)

Rivas Mercury, J.M.; Vasconcelos, N.S.L.S.; Cabral, A.A., E-mail: rivascefetma@gmail.co [Instituto Federal de Educacao, Ciencia e Tecnologia do Maranhao (IFMA), Sao Luis, MA (Brazil). Programa de Mestrado em Engenharia de Materiais; Pereira, D.J. Costa [Centro de Criatividade Odylo Costa Filho (SECMA), Sao Luis, MA (Brazil). Centro Historico; Angelica, R.S. [Universidade Federal do Para (CG/UFPA), Belem, PA (Brazil). Inst. de Geociencias

2010-07-01

Portuguese wall tiles from centuries, XVII, XVIII and XIX, found in Sao Luis Maranhao has been studied by X-ray diffraction, in order to interpret the possible raw material and burning temperature. The mineral phases, Quartz, Wollastonite, Calcite and Gehlenite were identified in all samples. Based on the results it is possible to affirm that the main raw materials used to manufacture this materials was probably mixtures of kaolinite clay and calcite. Based on the mineralogical information it was also possible to state that burning temperature of this wall tiles was lower than 1000 deg C. (author)

Luis Huerta: Eugenics, Medicine and Pedagogy in Spain

Directory of Open Access Journals (Sweden)

Luis Miguel LÁZARO LORENTE

2013-11-01

Full Text Available By comparison with the historiography of other European and Anglo-Saxon countries, the study of the origins and spread of Eugenics in Spain has not received much attention. Even less research has been done on the degree of acceptance of eugenic thought in the pedagogical domain or on the role teachers may have in the diffusion of eugenics. This paper attempts to explore the subject while focusing the analysis on the relations that were established among Medicine, Pedagogy and Eugenics in Spain during the first third of the 20th century. We will take as a point of reference and guiding line of thought the figure of the Asturian teacher Luis Huerta Naves, who was the driving force and tireless advocate of the eugenics movement in our country.

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

Science.gov (United States)

Méndez-García, C.; Renteria-Villalobos, M.; García-Tenorio, R.; Montero-Cabrera, M. E.

2014-07-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232Th-series, 238U-series, 40K and 137Cs activity concentrations (AC, Bq kg-1) were determined by gamma spectrometry with a high purity Ge detector. 238U and 234U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210Pb activities. Results were verified by 137Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento - Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234U/overflow="scroll">238U and 238U/overflow="scroll">226Ra in sediments have values between 0.9-1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232Th/overflow="scroll">238U, 228Ra/overflow="scroll">226Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

International Nuclear Information System (INIS)

Méndez-García, C.; Montero-Cabrera, M. E.; Renteria-Villalobos, M.; García-Tenorio, R.

2014-01-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232 Th-series, 238 U-series, 40 K and 137 Cs activity concentrations (AC, Bq kg −1 ) were determined by gamma spectrometry with a high purity Ge detector. 238 U and 234 U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210 Pb activities. Results were verified by 137 Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238 U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234 U/ 238 U and 238 U/ 226 Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232 Th/ 238 U, 228 Ra/ 226 Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs

Evaluating the sustainability of a regional system using Fisher information in the San Luis Basin, Colorado

Science.gov (United States)

This paper describes the theory, data, and methodology necessary for using Fisher information to assess the sustainability of the San Luis Basin (SLB) regional system over time. Fisher information was originally developed as a measure of the information content in data and is an ...

Green Net Regional Product for the San Luis Basin, Colorado: An Economic Measure of Regional Sustainability

Science.gov (United States)

This paper presents the data sources and methodology used to estimate Green Net Regional Product (GNRP), a green accounting approach, for the San Luis Basin (SLB). GNRP is equal to aggregate consumption minus the depreciation of man-made and natural capital. We measure the move...

Introducción [Jorge Luis Borges : Translación e Historia

OpenAIRE

de Toro, Alfonso

2015-01-01

El presente volumen es el resultado de una selección de las ponencias presentadas en el coloquio internacional "Jorge Luis Borges: Translación e Historia" realizado con el auspicio de la Deutsche Forschungsgemeinschaft en el Centro de Investigación Iberoamericana del 4 al 9 de diciembre de 2007 y pone en el centro de su reflexión a Borges como fenómeno de "translación", entendiendo por el concepto de "translación" un complejo proceso cultural, medial, social y pragmasemiótico que abarca tanto...

Master Mentors: Linda Golian-Lui University of Hawaii-Hilo--George Oberle George Mason University, VA

Science.gov (United States)

Library Journal, 2005

2005-01-01

Many movers and shakers inspire admiration and even awe, but those who inspire love are the mentors who have changed lives. That is why many grateful librarians nominated Linda Golian-Lui and George Oberle. Both of them were accidental librarians, work-study students whose supervisors encouraged them to become paraprofessionals, and then…

Blue oak plant communities of southern San Luis Obispo and northern Santa Barbara Counties, California

Science.gov (United States)

Mark I. Borchert; Nancy D. Cunha; Patricia C. Krosse; Marcee L. Lawrence

1993-01-01

An ecological classification system has been developed for the Pacific Southwest Region of the Forest Service. As part of that classification effort, blue oak (Quercus douglasii) woodlands and forests of southern San Luis Obispo and northern Santa Barbara Counties in Los Padres National Forest were classified into I3 plant communities using...

Luis G. Urbina: crônicas porfirianas

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Miguel Angel Castro

2015-11-01

Full Text Available As descrições amenas de uma cidade instável, às vezes divertida e atrativa, outras, entediante e miserável, assim como a crítica de costumes de seus habitantes, abrem um espaço original à tolerância e nele se fundamenta a natureza democrática da crônica jornalística do último quarto do século XIX e se determina o prolongamento de alguns dos seus traços literários no início do século XX. Com o intuito de conservar o valor literário de origem se constrói uma poética do gênero. Neste artigo, apresentamos algumas observações feitas a esse respeito nas crônicas que Luis G. Urbina publicou em El Mundo ilustrado entre 1899 e 1906.      This work is licensed under a Creative Commons Attribution 3.0 License.

SEDS MIL-STD-1773 fiber optic data bus: Proton irradiation test results and spaceflight SEU data

Energy Technology Data Exchange (ETDEWEB)

LaBel, K.A.; Stassinopoulos, E.G.; Miller, J.T. (NASA/GSFC, Greenbelt, MD (United States)); Marshall, P. (NRL/SFA, Washington, DC (United States)); Dale, C. (NRL, Washington, DC (United States)); Crabtree, C.M. (Hughes/ST Systems Corp., Seabrook, MD (United States)); Gates, M.M. (Jackson and Tull, Seabrook, MD (United States))

1993-12-01

The Small Explorer Data System (SEDS) was launched in July of 1992 as part of the Solar Anomalous Magnetospheric Particle Explorer (SAMPEX) mission. The SEDS utilizes NASA's first MIL-STD-1773 Fiber Optic Multiplexed Data Bus (or 1773 bus) to communicate with other spacecraft subsystems in the space environment. The 1773 bus is the fiber optic version of the MIL-STD-1553 Data Bus, a electronic wire bus used in many avionics applications. The authors present proton test and space flight single event effect data for NASA's first fiber optic data bus. Bit error rate predictions based on a new proton direct ionization model agree well with flight data for proton belt and solar flare effects.

Fatores associados à procura por serviços de saúde: diferenças entre mulheres e homens

OpenAIRE

Cleice Daiana Levorato

2012-01-01

Os valores da cultura masculina envolvem comportamentos de risco à saúde, sendo que a forma como os homens constroem e vivenciam a sua masculinidade torna-se uma das matrizes masculinas dos modos de adoecer e morrer. Objetivos: Considerando-se a relevância para o planejamento de políticas de saúde, este estudo abarcou, enquanto objetivo geral: Descrever e analisar os fatores associados à procura dos serviços de saúde por pessoas do sexo masculino e sexo feminino. Os objetivos específicos visa...

El estilo "rasgueado" de la guitarra barroca y su influencia en la guitarra flamenca: fuentes escritas y musicales, siglo XVII

Directory of Open Access Journals (Sweden)

Norberto Torres Cortés

2012-01-01

Full Text Available En nuestra tesis doctoral (Torres, 2009, hemos podido observar, utilizando fuentes musicológicas, iconográficas y escritas, el paso de la guitarra popular rasgueada a la guitarra flamenca en España, y particularmente en Andalucía, desde el siglo XVI al XIX. El trabajo que proponemos a continuación se centrará en las fuentes del siglo XVII, con la popularidad de la guitarra española o rasgueada durante el Barroco, los barberos como primeros tocaores de este estilo, la guitarra rasgueada en el teatro del Siglo de Oro, el análisis de fuentes musicales italianas y francesas que dan cuenta de la popularidad del rasgueado en Europa, el estudio del repertorio rasgueado de Luis de Briceño y Gaspar Sanz, siempre desde el contraste entre fuentes musicales y escritas, para señalar los elementos que perdurarán y cristalizarán en el toque flamenco decimonónico.

Enhanced catalytic activity over MIL-100(Fe) loaded ceria catalysts for the selective catalytic reduction of NOx with NH₃ at low temperature.

Science.gov (United States)

Wang, Peng; Sun, Hong; Quan, Xie; Chen, Shuo

2016-01-15

The development of catalysts for selective catalytic reduction (SCR) reactions that are highly active at low temperatures and show good resistance to SO2 and H2O is still a challenge. In this study, we have designed and developed a high-performance SCR catalyst based on nano-sized ceria encapsulated inside the pores of MIL-100(Fe) that combines excellent catalytic power with a metal organic framework architecture synthesized by the impregnation method (IM). Transmission electron microscopy (TEM) revealed the encapsulation of ceria in the cavities of MIL-100(Fe). The prepared IM-CeO2/MIL-100(Fe) catalyst shows improved catalytic activity both at low temperatures and throughout a wide temperature window. The temperature window for 90% NOx conversion ranges from 196 to 300°C. X-ray photoelectron spectroscopy (XPS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) analysis indicated that the nano-sized ceria encapsulated inside MIL-100(Fe) promotes the production of chemisorbed oxygen on the catalyst surface, which greatly enhances the formation of the NO2 species responsible for fast SCR reactions. Copyright © 2015 Elsevier B.V. All rights reserved.

A Preliminary Report on the Strength and Metallography of a Bimetallic Friction Stir Weld Joint Between AA6061 and MIL-DTL-46100E High Hardness Steel Armor

Science.gov (United States)

2012-11-26

bimetallic friction stir weld joint between AA6061 and MIL-DTL-46100E High Hardness steel armor. ABSTRACT One half inch thick plates of 6061-T6 aluminum...alloy and High Hardness steel armor (MIL- STD-46100) were successfully joined by the friction stir welding (FSW) process using a tungsten-rhenium...4. TITLE AND SUBTITLE A preliminary report on the strength and metallography of a bimetallic friction stir weld joint between AA6061 and MIL-DTL

Sexualidade e prevenção de DST/AIDS: representações sociais de homens rurais de um município da zona da mata pernambucana, Brasil

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Maria de Fátima Paz Alves

Full Text Available Neste trabalho analisamos as concepções de homens rurais residentes na zona da mata pernambucana sobre suas práticas sexuais e a prevenção de DST/AIDS. Ele baseia-se numa metodologia de natureza qualitativa, tendo sido entrevistados 22 homens. Os resultados indicam que a primeira relação sexual destes apresenta um caráter de aprendizado, sendo marcada, por vezes, pela violência. Que eles fazem distinção entre mulheres "de casa e da rua", reconhecem o desejo feminino e valorizam a reciprocidade nas relações sexuais, diferenciando o sexo que se faz com distintas categorias de mulheres. Sete homens relatam experiências homoeróticas na adolescência, atribuídas à imaturidade, que não afetam a identidade heterossexual. O uso do preservativo, percebido negativamente, é inconstante e irregular, concorrendo com o conhecimento da parceira. As DSTs são pouco temidas ao passo que a AIDS é associada à morte, não vendo-se os entrevistados sob risco de contraí-la. Ambigüidades presentes no discurso, aliadas a uma atuação pouco eficaz dos serviços de saúde e campanhas de prevenção, evidenciam um elevado nível de exposição ao risco de contrair DST/AIDS por parte dos entrevistados e suas/seus parceiras/os.

Self and transport diffusivity of CO2 in the metal-organic framework MIL-47(V) explored by quasi-elastic neutron scattering experiments and molecular dynamics simulations.

Science.gov (United States)

Salles, Fabrice; Jobic, Hervé; Devic, Thomas; Llewellyn, Philip L; Serre, Christian; Férey, Gérard; Maurin, Guillaume

2010-01-26

Quasi-elastic neutron scattering measurements are combined with molecular dynamics simulations to determine the self-diffusivity, corrected diffusivity, and transport diffusivity of CO(2) in the metal-organic framework MIL-47(V) (MIL = Materials Institut Lavoisier) over a wide range of loading. The force field used for describing the host/guest interactions is first validated on the thermodynamics of the MIL-47(V)/CO(2) system, prior to being transferred to the investigations of the dynamics. A decreasing profile is then deduced for D(s) and D(o) whereas D(t) presents a non monotonous evolution with a slight decrease at low loading followed by a sharp increase at higher loading. Such decrease of D(t) which has never been evidenced in any microporous systems comes from the atypical evolution of the thermodynamic correction factor that reaches values below 1 at low loading. This implies that, due to intermolecular interactions, the CO(2) molecules in MIL-47(V) do not behave like an ideal gas. Further, molecular simulations enabled us to elucidate unambiguously a 3D diffusion mechanism within the pores of MIL-47(V).

Making Borges. The Early Reception of Jorge Luis Borges's Work in France and the United States

NARCIS (Netherlands)

Wijnterp, L.

2016-01-01

This thesis analyzes the role of individual mediators in the early reception of the works of the Argentine writer Jorge Luis Borges (1899-1986). It focuses on a number of key mediators such as publishers, editors, translators, and critics in the translation and publication process and in criticism

Intermodal Storage and Transport Frame (ISTF) MIL-STD-1660 Design Criteria for Ammunition Unit Loads Tests

National Research Council Canada - National Science Library

Barickman, Philip

2004-01-01

.... The ISTF was evaluated by the testing procedures set forth in MIL-STD-1660. Stacking, vibration, edgewise rotational drop, incline impact, sling compatibility, forklifting, and disassembly testing were conducted on the ISTF units...

Eu(III)-functionalized MIL-124 as fluorescent probe for highly selectively sensing ions and organic small molecules especially for Fe(III) and Fe(II).

Science.gov (United States)

Xu, Xiao-Yu; Yan, Bing

2015-01-14

A layerlike MOF (MIL-124, orGa2(OH)4(C9O6H4)) has been prepared and chosen as a parent compound to encapsulate Eu(3+) cations by one uncoordinated carbonyl group in its pores. The Eu(3+)-incorporated sample (Eu(3+)@MIL-124) is fully characterized, which shows excellent luminescence and good fluorescence stability in water or other organic solvents. Subsequently, we choose Eu(3+)@MIL-124 as sensitive probe for sensing metal ions, anions, and organic small molecules because of its robust framework. Studying of the luminescence properties reveals that the complex Eu(3+)@MIL-124 was developed as a highly selective and sensitive probe for detection of Fe(3+) (detection limit, 0.28 μM) and Fe(2+) ions through fluorescence quenching of Eu(3+) and MOF over other metal ions. In connection to this, a probable sensing mechanism was also discussed in this paper. In addition, when Eu(3+)@MIL-124 was immersed in the different anions solutions and organic solvents, it also shows highly selective for Cr2O7(2-)(detection limit, 0.15 μM)and acetone. Remarkably, it is the first Eu-doped MOF to exhibit an excellent ability for the detection of Fe(3+) and Fe(2+) in an aqueous environment without any structural disintegration of the framework.

Dye-sensitized MIL-101 metal organic frameworks loaded with Ni/NiO{sub x} nanoparticles for efficient visible-light-driven hydrogen generation

Energy Technology Data Exchange (ETDEWEB)

Liu, Xin-Ling; Wang, Rong; Yuan, Yu-Peng, E-mail: yupengyuan@ahu.edu.cn, E-mail: cxue@ntu.edu.sg [School of Chemistry and Chemical Engineering, and Innovation Lab for Clean Energy and Green Catalysis, Anhui University, Hefei 230036 (China); Zhang, Ming-Yi [Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025 (China); Xue, Can, E-mail: yupengyuan@ahu.edu.cn, E-mail: cxue@ntu.edu.sg [Solar Fuels Lab, School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

2015-10-01

The Ni/NiO{sub x} particles were in situ photodeposited on MIL-101 metal organic frameworks as catalysts for boosting H{sub 2} generation from Erythrosin B dye sensitization under visible-light irradiation. The highest H{sub 2} production rate of 125 μmol h{sup −1} was achieved from the system containing 5 wt. % Ni-loaded MIL-101 (20 mg) and 30 mg Erythrosin B dye. Moreover, the Ni/NiO{sub x} catalysts show excellent stability for long-term photocatalytic reaction. The enhancement on H{sub 2} generation is attributed to the efficient charge transfer from photoexcited dye to the Ni catalyst via MIL-101. Our results demonstrate that the economical Ni/NiO{sub x} particles are durable and active catalysts for photocatalytic H{sub 2} generation.

Fe-MIL-101 exhibits selective cytotoxicity and inhibition of angiogenesis in ovarian cancer cells via downregulation of MMP.

Science.gov (United States)

Wang, Jiaqiang; Chen, Daomei; Li, Bin; He, Jiao; Duan, Deliang; Shao, Dandan; Nie, Minfang

2016-05-18

Though metal-organic frameworks (MOFs) have inspired potential applications in biomedicine, cytotoxicity studies of MOFs have been relatively rare. Here we demonstrate for the first time that an easily available MOF, Fe-MIL-101, possesses intrinsic activity against human SKOV3 ovarian cancer cells and suppress the proliferation of SKOV3 cells (IC50 = 23.6 μg mL(-1)) and normal mouse embryonic fibroblasts (BABL-3T3, IC50 = 78.3 μg mL(-1)) cells. It was more effective against SKOV3 cells than typical anticancer drugs such as artesunate (ART, IC50 = 96.9 μg mL(-1)) and oxaliplatin (OXA, IC50 = 64.4 μg mL(-1)), but had less effect on normal BABL-3T3 cells compared with ART (IC50 = 36.6 μg mL(-1)) and OXA (IC50 = 13.8 μg mL(-1)). Fe-MIL-101 induced apoptosis of human umbilical vein endothelial cells (HUVECs) via G0/G1 cell cycle arrest and decreased the mitochondrial membrane potential in HUVECs and induced apoptosis. Furthermore, Fe-MIL-101 exhibited stronger antiangiogenic effects in HUVEC cells than antiangiogenic inhibitor (SU5416) via downregulation the expression of MMP-2/9. Our results reveal a new role of Fe-MIL-101 as a novel, non-toxic anti-angiogenic agent that restricted ovarian tumour growth. These findings could open a new avenue of using MOFs as potential therapeutics in angiogenesis-dependent diseases, including ovarian cancer.

Black bear abundance, habitat use, and food habits in the Sierra San Luis, Sonora, Mexico

Science.gov (United States)

Rodrigo Sierra Corona; Ivan A. Sayago Vazquez; M. del Carmen Silva Hurtado; Carlos A. Lopez Gonzalez

2005-01-01

We studied black bears to determine habitat use, food habits, and abundance between April 2002 and November 2003 in the Sierra San Luis, Sonora. We utilized transects to determine spoor presence, camera traps for abundance, and scat analysis. During 2002, bears fed principally on plant material, and for 2003 on animal matter, namely livestock. Habitat use differed...

Una aproximación al poema “Arte Poética” de Jorge Luis Borges

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Lorena Chaves Salgado

2013-01-01

Full Text Available Este artículo presenta una lectura del poema 'Arte poética' de Jorge Luis Borges desarrollando aspectos teóricos relacionados con el análisis poético. El poema describe la labor del poeta y que significa escribir poesía, entendido para Borges como un acto y proceso creativo.

Una aproximación al poema “Arte Poética” de Jorge Luis Borges

Directory of Open Access Journals (Sweden)

Lorena Chaves Salgado

2013-01-01

Full Text Available Este artículo presenta una lectura del poema 'Arte poética' de Jorge Luis Borges desarrollando aspectos teóricos relacionados con el análisis poético. El poema describe la labor del poeta y qué significa escribir poesía, entendido para Borges como un acto y proceso creativo.

Synthesis and structure determination of new open-framework chromium carboxylate MIL-105 or CrIII(OH).{O2C-C6(CH3)4-CO2}.nH2O

International Nuclear Information System (INIS)

Serre, Christian; Millange, Franck; Devic, Thomas; Audebrand, Nathalie; Van Beek, Wouter

2006-01-01

Two new three-dimensional chromium(III) dicarboxylate, MIL-105 or Cr III (OH).{O 2 C-C 6 (CH 3 ) 4 -CO 2 }.nH 2 O, have been obtained under hydrothermal conditions, and their structures solved using X-ray powder diffraction data. Both solids are structural analogs of the known Cr benzenedicarboxylate compound (MIL-53). Both contain trans corner-sharing CrO 4 (OH) 2 octahedral chains connected by tetramethylterephthalate di-anions. Each chain is linked by the ligands to four other chains to form a three-dimensional framework with an array of 1D pores channels. The pores of the high temperature form of the solid, MIL-105ht, are empty. However, MIL-105ht re-hydrates at room temperature to finally give MIL-105lt with pores channels filled with free water molecules (lt: low temperature form; ht: high temperature form). The thermal behaviour of the two solids has been investigated using TGA. Crystal data for MIL-105ht: monoclinic space group C2/c with a = 19.653(1) A, b = 9.984(1) A, c = 6.970(1) A, β = 110.67(1) o and Z = 4. Crystal data for MIL-105lt: orthorhombic space group Pnam with a = 17.892(1) A, b = 11.165(1) A, c = 6.916(1) A and Z = 4

Purification of Contaminated MIL-PRF-83282 Hydraulic Fluid Using the Pall Purifier and Multiple Process Configurations (Preprint)

National Research Council Canada - National Science Library

Snyder, Jr., Carl E; Gschwender, Lois J; Gunderson, Stephen L; Fultz, George W

2006-01-01

.... This report describes a project that evaluated the effectiveness of various hydraulic fluid purification process configurations on the removal of water and particulate contaminants from MIL-PRF-83282...

Urea-modified metal-organic framework of type MIL-101(Cr) for the preconcentration of phosphorylated peptides

International Nuclear Information System (INIS)

Yang, Xiaoqing; Xia, Yan

2016-01-01

Mass spectrometry (MS) is the most powerful tool in phosphoproteomics research. However, phosphopeptides usually are present in low concentrations and their preconcentration therefore is highly desired. We describe a two-step method for the synthesis of a metal organic framework of the type MIL-101(Cr) that is modified with urea (then designated as MIL-101(Cr)-UR 2 ). It possesses large surface area, good solvent stability and high affinity for some phosphates. Due to the presence of modified urea functions, this material allows for selective and effective enrichment of phosphorylated peptides. It was successfully applied to the enrichment of phosphopeptides from non-fat-milk. The method was applied to the detection of phosphopeptides in a tryptic digest of β-casein where is showed a detection sensitivity as low as 10 −10 M. (author)

MIL-100 derived nitrogen-embodied carbon shells embedded with iron nanoparticles

Science.gov (United States)

Mao, Chengyu; Kong, Aiguo; Wang, Yuan; Bu, Xianhui; Feng, Pingyun

2015-06-01

The use of metal-organic frameworks (MOFs) as templates and precursors to synthesize new carbon materials with controllable morphology and pre-selected heteroatom doping holds promise for applications as efficient non-precious metal catalysts. Here, we report a facile pyrolysis pathway to convert MIL-100 into nitrogen-doped carbon shells encapsulating Fe nanoparticles in a comparative study involving multiple selected nitrogen sources. The hierarchical porous architecture, embedded Fe nanoparticles, and nitrogen decoration endow this composite with a superior oxygen reduction activity. Furthermore, the excellent durability and high methanol tolerance even outperform the commercial Pt-C catalyst.The use of metal-organic frameworks (MOFs) as templates and precursors to synthesize new carbon materials with controllable morphology and pre-selected heteroatom doping holds promise for applications as efficient non-precious metal catalysts. Here, we report a facile pyrolysis pathway to convert MIL-100 into nitrogen-doped carbon shells encapsulating Fe nanoparticles in a comparative study involving multiple selected nitrogen sources. The hierarchical porous architecture, embedded Fe nanoparticles, and nitrogen decoration endow this composite with a superior oxygen reduction activity. Furthermore, the excellent durability and high methanol tolerance even outperform the commercial Pt-C catalyst. Electronic supplementary information (ESI) available: Material synthesis and elemental analysis, electrochemistry measurements, and additional figures. See DOI: 10.1039/c5nr02346g

Males unveiling the different forms of conjugal violence Hombres develando las formas de la violencia conyugal Homens desvelando as formas da violência conjugal

Directory of Open Access Journals (Sweden)

Nadirlene Pereira Gomes

2008-01-01

ón social de la identidad de género.OBJETIVOS: Identificar as formas de desvelamento da violência a partir do discurso de um grupo de homens que praticam atos violentos contra suas companheiras. MÉTODOS: Estudo de abordagem qualitativa. Foram entrevistados sete homens que violentavam suas companheiras, residentes na periferia de Salvador-BA. As falas dos sujeitos foram analisadas por meio da análise de conteúdo. RESULTADOS: O estudo mostrou que os homens entrevistados vivenciam a violência conjugal, a qual se desvela sob as formas psicológica, sexual, moral e física. CONCLUSÃO: O relacionamento conjugal é marcado por uma relação assimétrica entre homens e mulheres, de modo que, ao sentir que seu poder está sendo ameaçado, o homem utiliza alguns meios para controlar suas companheiras, lançando mão, inclusive, da violência física. Faz-se necessária a implementação de políticas públicas que garantam intervenções junto a homens e mulheres que conduzam uns e outros à compreensão da construção social da identidade de gênero.

Thin Film Nanocomposite Membrane Filled with Metal-Organic Frameworks UiO-66 and MIL-125 Nanoparticles for Water Desalination

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Mohammed Kadhom

2017-06-01

Full Text Available Knowing that the world is facing a shortage of fresh water, desalination, in its different forms including reverse osmosis, represents a practical approach to produce potable water from a saline source. In this report, two kinds of Metal-Organic Frameworks (MOFs nanoparticles (NPs, UiO-66 (~100 nm and MIL-125 (~100 nm, were embedded separately into thin-film composite membranes in different weight ratios, 0%, 0.05%, 0.1%, 0.15%, 0.2%, and 0.3%. The membranes were synthesized by the interfacial polymerization (IP of m-phenylenediamine (MPD in aqueous solution and trimesoyl chloride (TMC in an organic phase. The as-prepared membranes were characterized by scanning electron microscopy (SEM, transmission electron microscopy (TEM, contact angle measurement, attenuated total reflection Fourier transform infrared (ATR FT-IR spectroscopy, and salt rejection and water flux assessments. Results showed that both UiO-66 and MIL-125 could improve the membranes’ performance and the impacts depended on the NPs loading. At the optimum NPs loadings, 0.15% for UiO-66 and 0.3% for MIL-125, the water flux increased from 62.5 L/m2 h to 74.9 and 85.0 L/m2 h, respectively. NaCl rejection was not significantly affected (UiO-66 or slightly improved (MIL-125 by embedding these NPs, always at >98.5% as tested at 2000 ppm salt concentration and 300 psi transmembrane pressure. The results from this study demonstrate that it is promising to apply MOFs NPs to enhance the TFC membrane performance for desalination.

More than Meets the Eye: Adult Education for Critical Consciousness in Luis Camnitzer's Art

Science.gov (United States)

Zorrilla, Ana Carlina

2012-01-01

The purpose of this study was to explore the connection between art and adult education for critical consciousness through the conceptual art of Luis Camnitzer. The theoretical framework grounding this research was critical public pedagogy, influenced by both critical theory and Stuart Hall's systems of representation (1997). This framework…

A Mixed Matrix Membrane of Poly (4-methyl-1-pentyne Filled with MIL 53 Particles and Its Application in Carbon Dioxide and Nitrogen Separation

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Reza Abedini

2016-05-01

Full Text Available The performance of poly (4-metyl-1-pentyne as mixed matrix membrane (MMM mixed with MIL 53 particles was studied to separate mixtures of carbon dioxide and nitrogen. MIL 53 particles was added to the polymer matrix with 10, 20 and 30 weight percentages. The adsorption of CO2 and N2 gases by MIL 53 was evaluated and the adsorption data was analyzed by Langmuir equation. Structure and thermal/mechanical properties of prepared membranes were characterized by means of FTIR, SEM, TGA and elongation test. Moreover, the gas permeation properties of membranes were studied by measuring the permeation of pure CO2 and N2. Furthermore, for accurate understanding of the gas permeation properties of the membranes, diffusion and solution coefficient of gases in neat membrane and MMMs were calculated using modified time-lag method. The results from TGA analysis showed that the degradation temperature of MMMs was enhanced and increased to 348ºC for membrane containing 30 wt% of MIL 53. The SEM images also illustrated a relatively uniform dispersion of particles with proper polymer/filler interfaces in the polymer matrix. The gas permeation results revealed that the permeability of both gases (especially CO2 increased with increasing MIL 53 loading, in which the permeability of CO2 increased from 98.74 Barrer in neat membrane to 217.65 Barrer in MMM containing 30 wt% filler. Moreover, calculation of CO2/N2 selectivity depicted that the selectivity enhanced from 16.66 to 22.70. Finally, the performance of MMMs was compared with Robeson’s upper bound in CO2/N2 separation and results showed that the MMM having 30 wt% of MIL 53 took over the Robeson bound.

Adsorption of 1,2-dichlorobenzene and 1,2,4-trichlorobenzene in nano- and microsized crystals of MIL-101(Cr): static and dynamic gravimetric studies.

Science.gov (United States)

Bullot, Laetitia; Vieira-Sellaï, Ludivine; Chaplais, Gérald; Simon-Masseron, Angélique; Daou, Toufic Jean; Patarin, Joël; Fiani, Emmanuel

2017-12-01

This work aims to highlight the promising adsorption capacity and kinetic of (poly)chlorobenzene pollutants in the hybrid MIL-101(Cr) type material for technological uses in industrial waste exhaust decontamination. The influence of the MIL-101(Cr) crystal size (nano- and microcrystals) on the adsorption behavior was studied in static and dynamic modes. For this purpose, crystals of MIL-101(Cr) in nano- and micrometric sizes were synthesized and fully characterized. Their sorption properties regarding 1,2-dichlorobenzene were examined using gravimetric method in dynamic (p/p° = 0.5) and static (p/p° = 1) modes at room temperature. 1,2,4-trichlorobenzene adsorption was only performed under static mode because of its too low vapor pressure. 1,2-dichlorobenzene and 1,2,4-trichlorobenzene were used to mimic 2,3-dichlorodibenzo-p-dioxin and 1,2,3,4-tetrachlorodibenzo-p-dioxin, respectively, and more largely dioxin compounds. Adsorptions of these probes were successfully carried out in nano- and microcrystals of MIL-101(Cr). Indeed, in static mode (p/p° = 1) and at room temperature, nanocrystals adsorb 2266 molecules of 1,2-dichlorobenzene and 2093 molecules of 1,2,4-trichlorobenzene per unit cell, whereas microcrystals adsorb 1871 molecules of 1,2-dichlorobenzene and 1631 molecules of 1,2,4-trichlorobenzene per unit cell. In dynamic mode, the 1,2-dichlorobenzene adsorbed amounts are substantially similar to those obtained in static mode. However, the adsorption kinetics are different because of a different scheme of diffusivity of the adsorbate between the two modes. To the best of our knowledge, these adsorption capacities of MIL-101(Cr) as adsorbent for polychlorobenzenes trapping have never been referenced. MIL-101(Cr) appears as a promising material for technological uses in industrial waste exhaust decontamination.

A política dos homens de cor no tempo da Independência

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Ubiratan Castro de Araújo

2004-04-01

Full Text Available O AUTOR analisa o movimento político pelo qual homens negros e pobres manifestaram o seu descontentamento contra a monarquia portuguesa e contra a sociedade escravista na Bahia, em 1798. O regionalismo baiano inspirou a exaltação deste movimento, batizado então de Inconfidência Baiana, mais radical nos propósitos de independência do Brasil e mais republicano do que a Inconfidência Mineira porque portador dos anseios das classes subordinadas do Brasil colonial.THE AUTHOR analyzes the political movement through which poor, black men manifested their discontent with the Portuguese monarchy and the proslavery society of Bahia in 1798. The regionalism of Bahia contributed to the exalted status of this movement, known then as Inconfidência Baiana [Insurrection of Bahia], which was more radical in advocating the independence of Brazil and more republican than the Inconfidência Mineira [Insurrection of Minas] because it embodied the yearnings of colonial Brazil's subordinate classes.

Rating the quality of the landscape of Sierra de las Quijadas National Park, Province of San Luis, Argentina

International Nuclear Information System (INIS)

Maero, I.; Rivarola, D.; Tognelli, G.

2007-01-01

The National Park Sierra de las Quijadas is located to 120 km to the northwest of the Province of San Luis, Argentina. The study area is of 24,000 hectares, that correspond to 32 % of the total surface, this surface covers the totality with the Potrero de la Aguada and the next zones, the same one was selected because it conforms at the present time the zone of greater frequency of visitors within the Park. The objective of this work is centered in the obtaining of the Total Quality of the Landscape, having compared the demand of beauty to the rest of the other natural resources, to be able to make proposals to improve the Plan of Handling that takes ahead the Administration of National Parks. The used Methodology is the described one by Cendrero et. al. (1987), it is an indirect valuation that is carried out through the components of the landscape and allows to determine the Intrinsic Visual Quality and the Fragility of each one of the Environmental Units in which the park is divided. This analysis allowed to determine 2 Total Qualities of Landscape, that have been mapped using aerial photography equipment and materials and SIG, with field control. This investigation is developed within the Project of Investigation Geology of the Neogeno and Cuaternario of the Mountain range of San Luis, Faculty of Sciences Physical, Mathematics and Natural - National University of San Luis, Argentina. (author)

Las dos Celamas de Luis Mateo Díez: recuerdo y olvido

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Oscar Bazán Rodríguez

2015-02-01

Full Text Available El artículo reflexiona sobre el tratamiento del espacio en la trilogía de Luis Mateo Díez, El reino de Celama. Con un diverso aporte teórico y crítico explica la relación intrínseca que ocurre entre el espacio y sus habitantes en la obra, y postula que implícitamente hay una separación entre dos Celamas que, a pesar de ocupar un mismo espacio, son distintas en el tiempo, y se corresponden con los valores del recuerdo (luz y del olvido (oscuridad.

Yacimientos de Celestina en la Plataforma Valles-San Luis Potosí

OpenAIRE

Rocha Rocha, Macario

2008-01-01

En la zona de estudio, la Plataforma Valles-San Luis Potosí (PVSLP), existen depósitos de celestina; las características geotectónicas de la zona, hacen pensar que estos depósitos se asocian con evaporitas del Jurásico Superior-Cretácico Inferior. La mineralización de celestina arma en la Formación El Abra y en menor grado la Formación Indidura, en forma de vetas, mantos, zonas de brecha y cuerpos irregulares. La mineralogía consiste básicamente de celestina y algunos minerales...

The Onset and Duration of Action of 0.2% Lidocaine in a One-per-Mil Tumescent Solution for Hand Surgery.

Science.gov (United States)

Prasetyono, Theddeus O H; Lestari, Puri A

2016-05-01

One-per-mil tumescent solution, which contains 0.2% lidocaine with 1:1,000,000 epinephrine, has been reported to be clinically effective for hand surgery under local anesthesia. However, it was lacking in its basic pharmacokinetics profile in regard to the onset of action (OOA) and duration of action (DOA). A randomized, double-blind study was conducted on 12 volunteers who met the inclusion criteria from October to November 2014. All volunteers had their right and left ring finger pulps injected with either one-per-mil solution or 2% lidocaine. Semmes-Weinstein and two-point discrimination tests were used to test sensation. Visual analogue scale was recorded at the time when the finger lost its sensation and when it regained normal sensation to measure the OOA and DOA. The data were then analyzed with a paired t-test and a Wilcoxon signed-rank test. The OOA and DOA of 2% plain lidocaine were 1 minute and 99.67 minutes, respectively. Meanwhile, 0.2% lidocaine in a one-per-mil tumescent solution showed an OOA of 5 minutes and a DOA of 186.83 minutes. The OOA of 0.2% lidocaine in a one-per-mil tumescent solution is statistically shorter than 2% plain lidocaine (P=0.04); while its DOA is statistically longer than 2% plain lidocaine (Pmil tumescent solution is statistically and clinically superior to 2% plain lidocaine in achieving longer duration of local anesthesia.

Una imatge val per mil paraules

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Jaume Cabré

1999-11-01

Full Text Available Una vegada hi havia un videoclub ple de pel·lícules i a l'entrada hi havia un rètol lluminós molt bonic que deia el lema d'aquesta casa, que és una imatge val per mil paraules. I vet aquí un dia que la clientela ja se n'havia anat, però encara no havien tancat els llums, van entrar al videoclub dues rates, l'Amàlia i l'Amèlia. I van dir: "Què fem avui?" Aleshores l'Amèlia se'n va anar de seguida cap al racó de la sèrie B i va agafar una pel·lícula poc coneguda, mentre que l'Amàlia va agafar Mort a Venècia. Llavors la va començar a rosegar i l'Amèlia li va dir: "Què, què te'n sembla?", i l'Amàlia li va contestar: "Mmm... Em va agradar més la novel·la."

MIL-HDBK-338-Environmental Conversion Table Correction

Science.gov (United States)

Hark, Frank; Novack, Steve

2017-01-01

In reliability analysis for space launch vehicles, limited data is frequently a challenge due to the pure number of launches. A common solution is to use surrogate historical data of similar components from other industries (military data). The operating environment of the common data may be different from that of the necessary target analysis. The military electronic design handbook (MIL-HDBK-338) has a table for converting Mean Time Between Failure (MTBF) data from one environment to another. However, the table has some discrepancies and rounding of complementary conversions; namely going from environment A to B does not given the same result as going from B to A. This presentation will show the discrepancies in the original conversation table, the greater than expected magnitude, the problem with the updated published table and a suggested corrected table to reference when doing MTBF data environment conversion.

Facile synthesis of highly efficient amorphous Mn-MIL-100 catalysts: The formation mechanism and the structure changes during the application for CO oxidation.

Science.gov (United States)

Zhang, Xiaodong; Li, Hongxin; Lv, Xutian; Xu, Jingcheng; Wang, Yuxin; He, Chi; Liu, Ning; Yang, Yiqiong; Wang, Yin

2018-04-13

A comprehensive study was carried out on amorphous metal-organic frameworks Mn-MIL-100 as efficient catalysts towards CO oxidation. This study focuses on explaining the crystalline-amorphous-crystalline transformations during thermolysis process of Mn-MIL-100 and studying the structure changes during the reaction process for CO oxidation. A possible formation mechanism of amorphous Mn-MIL-100 was proposed. Amorphous Mn-MIL-100 obtained by calcination at 250°C (a-Mn-250) showed a smaller specific surface area (4 m2/g), but displayed a high catalytic activity. Furthermore, the structure of amorphous Mn-MIL-100 was labile during the reaction process. When used a-Mn-250 were treated with reaction atmosphere at high temperature (named used a-Mn-250-S), the amorphous catalysts transformed to Mn2O3. Meanwhile, BET surface area (164 m2/g) and the catalytic performance both sharply increased. In addition, used a-Mn-250-S catalyst transformed from Mn2O3 to Mn3O4, resulting in the slightly decrease of catalytic activity under the presence of 1 vol% water vapor in the stream. A schematic of the structure changes during the reaction process was proposed. The achievement of our synthesis relies on the increase of BET surface area using CO as retreatment atmosphere, and the enhanced catalytic activity was attributed to the unique structure, a high quantity of surface active oxygen species, oxygen vacancies and good low temperature reduction behavior. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage

CSIR Research Space (South Africa)

Ren, Jianwei

2014-09-01

Full Text Available of the individual metal-organic framework (MOF) components and the coreeshell hybrid crystals were also characterized. The hydrogen storage capacity exhibited by the resulting core eshell nanocrystals was 26% and 60% higher than those of pure phase MIL-101 and Ui...

An amino-functionalized magnetic framework composite of type Fe3O4-NH2@MIL-101(Cr) for extraction of pyrethroids coupled with GC-ECD.

Science.gov (United States)

He, Xi; Yang, Wei; Li, Sijia; Liu, Yu; Hu, Baichun; Wang, Ting; Hou, Xiaohong

2018-01-24

An amino-functionalized magnetic framework composite of type Fe 3 O 4 -NH 2 @MIL-101(Cr) was synthesized using a solvothermal method. The material was characterized by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption, and magnetometry. The composite combines the advantages of amino-modified Fe 3 O 4 and MIL-101(Cr). The presence of amino groups facilitates the fairly specific adsorption of pyrethroids. The composite was employed as a sorbent for magnetic solid phase extraction of five pyrethroids from environmental water samples. Following desorption with acidified acetone, the pyrethroids were quantified by gas chromatography with electron capture detection. The detection limits for bifenthrin, fenpropathrin, λ-cyhalothrin, permethrin, and deltamethrin range from 5 to 9 pg·mL -1 . The method is rapid, accurate, and highly sensitive. The molecular interactions and free binding energies between MIL-101(Cr) and the five pyrethroids were calculated by means of molecular docking. Graphical abstract A novel functionalized magnetic framework composite of type Fe 3 O 4 -NH 2 @MIL-101(Cr) was synthesized. It was applied as a sorbent for magnetic solid phase extraction of pyrethroids prior to their quantitation by gas chromatography with electron capture detection. The molecular interactions of analytes and MIL-101(Cr) were studied.

Diagnostic des systèmes de culture à base de mil [ Pennisetum ...

African Journals Online (AJOL)

Objectif : Le présent travail a pour objectif, de faire un état des lieux des systèmes de production à base de mil en Côte d'Ivoire septentrionale afin de proposer de nouvelles pistes d'amélioration. Méthodologie et résultats : L'approche méthodologique s'est reposée sur une enquête auprès des paysans sur le terrain dans ...

Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

Energy Technology Data Exchange (ETDEWEB)

Méndez-García, C.; Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx [Centro de Investigación en Materiales Avanzados, CIMAV, Miguel de Cervantes 120, 31109, Chihuahua, Chihuahua (Mexico); Renteria-Villalobos, M. [Facultad de Zootecnia y Ecología Universidad Autónoma de Chihuahua, Periferico Francisco R. Almada Km 1, 31410, Chihuahua (Mexico); García-Tenorio, R. [Applied Nuclear Physics Group, University of Seville, ETS Arquitectura, Avda. Reina Mercedes s/n, 41012 Seville (Spain)

2008-01-01

Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. ²³²Th-series, ²³⁸U-series, ⁴⁰K and ¹³⁷Cs activity concentrations (AC, Bq kg⁻¹) were determined by gamma spectrometry with a high purity Ge detector. ²³⁸U and ²³⁴U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to ²¹⁰Pb activities. Results were verified by ¹³⁷Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High ²³⁸U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) ²³⁴U/²³⁸U and ²³⁸U/²²⁶Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. ²³²Th/²³⁸U, ²²⁸Ra/²²⁶Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

Os homens do Erário Régio =The men of the Exchequer

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Manuel Benavente Rodrigues

2011-12-01

Full Text Available Este estudio tiene como objetivo descubir el pasado social y profesional de los funcionarios llegados al Erário Régio en 1762. Con ello, se pretende evaluar las continuidades y rupturas a raíz de las reformas de Pombal en lo que respecta al control gastos e ingresos del Reino. Así, se hace un breve recorrido por la institución anterior –Contos do Reino e Casa– y después se describe el Erário y la Carta de Lei que le dió forma para, finalmente, detenernos en la élite pombalina de la que forman parte estos hombres del Erário. Quiénes eran, qué poder tenían, de qué prestigio social disfrutaban, son preguntas a las que se intentará dar alguna respuesta. Y tratar de mostrar lo que los contables portugueses, incluso antes del Aula do Comércio y del Erário Régio, conocían de la contabilidad y de la partida doble.The goal of this paper is to provide a glimpse into the professional and social lives of some of the Exchequer’s employees that were appointed in 1762.We will then extrapolate the rifts caused by the Pombaline reforms in the context of the elite controlling the Exchequer.Who were these men, what power did they truly hold, what was their real prestige are all questions that we will try to adress.Esta comunicação visa descortinar o passado social e profissional dos funcionários do Erário Régio que tomaram posse em 1762.Com isso pretende-se aquilatar das continuidades e rupturas que aconteceram com as reformas pombalinas no que respeita ao controlo das Despesas e Receitas do Reino. Assim, faz-se uma ligeira viagem pela instituição antecedente –Contos do Reino e Casa–, depois caracteriza-se o Erário mais a Carta de Lei que lhe deu forma, para finalmente nos determos na elite pombalina de que fazem parte estes homens do Erário.Quem eram estes homens, que poder detinham, de que prestígio social desfrutavam, são tudo questões a que procuraremos dar algumas respostas.

Jorge Luis Borges y Wilhem Ostwald. Notas para una alianza entre la ciencia y las humanidades

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Lothar Beyer

2011-05-01

Full Text Available Jorge Luis Borges (1899-1986 de nacionalidad argentina, fue escritor, poeta y filósofo de fama mundial. Wilhelm Ostwald (1853-1932, de nacionalidad alemana, fue uno de los fundadores de la físicoquímica.También fue filósofo, pintor y premio Nobel de Química (1909. Los dos hombres enriquecieron el diálogo entre ciencia y humanidades gracias a sus obras y sus discursos, a pesar de que nunca se conocieron personalmente.Un simposio en la ciudad de Leipzig, en cuya universidad Wilhelm Ostwald se desempeñó durante 20 años como catedrático principal de físicoquímica, realizado en octubre de 2001, tenía el título: «Jorge Luis Borges. Ciencia y filosofía». A ese simposio el autor de este artículo contribuyó con una conferencia: «Ciencias y humanidades en diálogoconstructivo» dictada en presencia de la viuda María Kodama de Borges.

Mangue, homens e caranguejos em Josué de Castro: significados e ressonâncias

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Melo Filho Djalma Agripino de

2003-01-01

Full Text Available Analisa-se na obra de Josué de Castro a eclosão da metáfora 'homem-caranguejo', criada para designar uma nova espécie de homem que habitava os mangues do Recife. Procede-se a uma releitura do texto de onde provém a metáfora com o propósito de revelar a existência subjacente de outras figuras, como a sinédoque e a metonímia. O olhar recaiu fundamentalmente sobre três obras: Documentário do Nordeste, onde o autor descreve o 'ciclo do caranguejo'; Fatores de localização da cidade do Recife e Homens e caranguejos, romance autobiográfico. Busca-se ainda compreender duas recentes atualizações da metáfora original, a partir da hipérbole homem-gabiru e da personificação caranguejo-com-cérebro.

Chelating agent-free, vapor-assisted crystallization method to synthesize hierarchical microporous/mesoporous MIL-125 (Ti).

Science.gov (United States)

McNamara, Nicholas D; Hicks, Jason C

2015-03-11

Titanium-based microporous heterogeneous catalysts are widely studied but are often limited by the accessibility of reactants to active sites. Metal-organic frameworks (MOFs), such as MIL-125 (Ti), exhibit enhanced surface areas due to their high intrinsic microporosity, but the pore diameters of most microporous MOFs are often too small to allow for the diffusion of larger reactants (>7 Å) relevant to petroleum and biomass upgrading. In this work, hierarchical microporous MIL-125 exhibiting significantly enhanced interparticle mesoporosity was synthesized using a chelating-free, vapor-assisted crystallization method. The resulting hierarchical MOF was examined as an active catalyst for the oxidation of dibenzothiophene (DBT) with tert-butyl hydroperoxide and outperformed the solely microporous analogue. This was attributed to greater access of the substrate to surface active sites, as the pores in the microporous analogues were of inadequate size to accommodate DBT. Moreover, thiophene adsorption studies suggested the mesoporous MOF contained larger amounts of unsaturated metal sites that could enhance the observed catalytic activity.

Inquérito soro-epidemiológico na Ilha de São Luis durante epidemia de dengue no Maranhão Seroepidemiologic survey in São Luis Island, State of Maranhão, Brazil, during a dengue fever epidemics

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Pedro Fernando da C. Vasconcelos

1999-04-01

Full Text Available Nos anos de 1995 e 1996, ocorreu em São Luis uma epidemia de dengue (DEN, causada pelo sorotipo DEN1. Objetivando avaliar o impacto da mesma na população da grande São Luis (municípios de Paço do Lumiar - PL, São José de Ribamar - SJR e São Luis SL, realizamos um inquérito soro - epidemiológico aleatório, onde aplicamos um questionário. Os soros foram testados por inibição da hemaglutinação (IH, e os resultados, negativo e positivo (resposta primária - RP e resposta secundária - RS, foram analisados utilizando os "software's" Lotus 123, Epi-info 6.0, Excel 5.0 e STATA. Coletaram-se 1217 amostras, (101 de PL, 100 de SJR e 1016 de SL. A positividade foi: 55,4% em PL, 28% em SJR e 41,4% em SL. Destes, 505 (41,2% amostras foram positivas sendo 96 RP (7,9% e 405 RS (33,3%. Da amostra obtida, 508 soros (227 positivos foram do sexo masculino e 709 (278 positivos do feminino, não havendo diferença estatística significativa. Houve significância (p The Island of São Luis in the State of Maranhão, constituted by the municipalities of São Luis - SL (835,428 inhabitants, São José de Ribamar - SJR (60,633 inhabitants and Paço do Lumiar - PL (80,274 inhabitants, has been suffering dengue (DEN fever epidemics since 1995, caused by DEN-1. In 1996, from August through October, an aleatory sero-epidemiologic survey was carried out in order to estimate the incidence of DEN infection and to analyze other clinical and epidemiological parameters. A questionnaire was applied and serum samples were simultaneously obtained. Serum samples were tested by hemagglutination inhibition (HI. Results were analyzed using Lotus123, Epi-info 6.0, Excel 5.0 and STATA softwares. A total of 1,217 serum samples were obtained (101 of PL, 100 of SJR and 1017 of SL. The rate of DEN was 55.4% in PL, 28% in SJR and 41.4% in SL, suggesting the occurrence of 401,933 infections. No difference was seen between males and females, but infection occurred more in the

76 FR 39091 - San Luis Obispo Flood Control and Water Conservation District; Notice of Effectiveness of Surrender

Science.gov (United States)

2011-07-05

... Flood Control and Water Conservation District; Notice of Effectiveness of Surrender On October 27, 1981... \\1\\ to the San Luis Obispo Flood Control and Water Conservation District (District) for the Lopez... and Water Conservation District, 17 FERC ] 62,113 (1981). On October 24, 2005, the District filed an...

Functionalized MIL-101 with imidazolium-based ionic liquids for the cycloaddition of CO2 and epoxides under mild condition

Science.gov (United States)

Liu, Dan; Li, Gang; Liu, Haiou

2018-01-01

A kind of multi-functional sites metal-organic framework (MOF) composite (MIL-101-IMBr) was successfully prepared by post-synthesis modification of MIL-101 with imidazolium-based ionic liquids. The ionic liquids not only functionalize as basic sites but also provide halide anions, which serve as a nucleophile in cycloaddition reaction. The prepared functional MOF materials were characterized by X-ray diffraction, fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive spectroscopy, N2 adsorption-desorption and CO2 temperature programmed desorption. The results of fourier transform infrared spectroscopy and energy dispersive spectroscopy show that the MIL-101-IMBr composite was successfully synthesized. The N2 adsorption-desorption results clearly demonstrated that the modified composites still preserve high BET surface area and total pore volume. The composite exhibits high catalytic activity for the cycloaddition of CO2 with epoxides under mild and co-catalyst free conditions. The conversion of propylene oxide was 95.8% and the selectivity of cyclic carbonate was 97.6% under 0.8 MPa at 80 °C for 4 h. Moreover, the catalyst can be used for at least five times.

Transient Electromagnetic Soundings Near Great Sand Dunes National Park and Preserve, San Luis Valley, Colorado (2006 Field Season)

Science.gov (United States)

Fitterman, David V.; de Sozua Filho, Oderson A.

2009-01-01

Time-domain electromagnetic (TEM) soundings were made near Great Sand Dunes National Park and Preserve in the San Luis Valley of southern Colorado to obtain subsurface information of use to hydrologic modeling. Seventeen soundings were made to the east and north of the sand dunes. Using a small loop TEM system, maximum exploration depths of about 75 to 150 m were obtained. In general, layered earth interpretations of the data found that resistivity decreases with depth. Comparison of soundings with geologic logs from nearby wells found that zones logged as having increased clay content usually corresponded with a significant resistivity decrease in the TEM determined model. This result supports the use of TEM soundings to map the location of the top of the clay unit deposited at the bottom of the ancient Lake Alamosa that filled the San Luis Valley from Pliocene to middle Pleistocene time.

Effets de la microdose sur la production du niébé, du mil et du ...

African Journals Online (AJOL)

Effets de la microdose sur la production du niébé, du mil et du sorgho en fonction la toposéquence. Fatimata Saba, Sibiri Jean Baptiste Taonda, Idriss Serme, Alimata A. Bandaogo, Augustin P. Sourwema, Adama Kabre ...

Consumo alimentar da população adulta segundo perfil sócio-econômico e demográfico: Projeto Bambuí

Directory of Open Access Journals (Sweden)

Bonomo Élido

2003-01-01

Full Text Available Foi realizado inquérito nutricional em amostra probabilística de 546 indivíduos (idade > 18 anos, residentes na cidade de Bambuí (15 mil habitantes, Minas Gerais, Brasil, utilizando-se o Questionário Semiquantitativo de Freqüência Alimentar (QSFA. A mediana de ingestão calórica entre mulheres e homens foi de 2.807 e 3.775kcal, respectivamente. Homens ingeriram quatro vezes mais álcool que mulheres e estas, mais carboidratos, fibras e ácidos graxos polinsaturados (AGP. A distribuição de proteínas (15%, carboidratos (57% e lipídios (28% foi adequada. As proporções médias de inadequação da participação de lipídios, ácidos graxos saturados (AGS, AGP e colesterol na energia total foram, respectivamente, 36%, 50% e 90%, sendo mais pronunciadas entre os homens. A ingestão de lipídios, AGS e AGP, entre mulheres, e de lipídios e AGS entre homens, aumentou de acordo com a renda. A ingestão de AGP e fibras e a relação AGP/AGS estavam abaixo do recomendado nos dois gêneros. A dieta apresentou proporções de inadequação diferenciais, sugerindo possíveis agregados de risco à saúde da população para doenças cardiovasculares.

Remarkable adsorptive removal of nitrogen-containing compounds from a model fuel by a graphene oxide/MIL-101 composite through a combined effect of improved porosity and hydrogen bonding

Energy Technology Data Exchange (ETDEWEB)

Ahmed, Imteaz; Jhung, Sung Hwa, E-mail: sung@knu.ac.kr

2016-08-15

Highlights: • Metal-organic frameworks (MIL-101) were composed with graphene oxide (GnO). • GnO/MIL-101 showed the highest adsorption capacity for indole and quinoline. • Adsorption mechanism was clearly shown based on adsorption results and FTIR. • GnO/MIL-101 might be applied commercially considering capacity and reusability. - Abstract: A composite was prepared by combining a highly porous metal-organic framework (MOF), MIL-101 (Cr-benzenedicarboxylate), and graphene oxide (GnO). The porosity of the composite increased appreciably by the addition of GnO up to a specific amount in the MOF, though further increases in the quantity of GnO was detrimental to porosity. The improved porosity of the GnO/MIL-101 composite was utilized for adsorptive denitrogenation (ADN) of a model fuel where indole (IND) and quinoline (QUI) were used as nitrogen-containing compounds (NCCs). It was found that both IND and QUI showed improved adsorption on the composite compared with pristine MIL-101 or GnO due to the improved porosity of the composite. Interestingly, the improvement in adsorption of IND was much higher than the quantity estimated for the porosity. Importantly, GnO/MIL-101 showed the highest adsorption capacities for NCCs. Irrespective of the studied solvents and co-presence of IND and QUI, the composite adsorbent performed ADN most effectively. This remarkable improvement is explained by the additional mechanism of hydrogen bonding between the surface functional groups of GnO and the hydrogen attached to the nitrogen atom of IND. This hydrogen bonding mechanism is also supported by the results of the adsorption of pyrrole and methylpyrrole. On the other hand, QUI does not show hydrogen-bonding capability, and therefore, its enhanced adsorption originates from only the increased porosity of the adsorbents.

Remarkable adsorptive removal of nitrogen-containing compounds from a model fuel by a graphene oxide/MIL-101 composite through a combined effect of improved porosity and hydrogen bonding

International Nuclear Information System (INIS)

Ahmed, Imteaz; Jhung, Sung Hwa

2016-01-01

Highlights: • Metal-organic frameworks (MIL-101) were composed with graphene oxide (GnO). • GnO/MIL-101 showed the highest adsorption capacity for indole and quinoline. • Adsorption mechanism was clearly shown based on adsorption results and FTIR. • GnO/MIL-101 might be applied commercially considering capacity and reusability. - Abstract: A composite was prepared by combining a highly porous metal-organic framework (MOF), MIL-101 (Cr-benzenedicarboxylate), and graphene oxide (GnO). The porosity of the composite increased appreciably by the addition of GnO up to a specific amount in the MOF, though further increases in the quantity of GnO was detrimental to porosity. The improved porosity of the GnO/MIL-101 composite was utilized for adsorptive denitrogenation (ADN) of a model fuel where indole (IND) and quinoline (QUI) were used as nitrogen-containing compounds (NCCs). It was found that both IND and QUI showed improved adsorption on the composite compared with pristine MIL-101 or GnO due to the improved porosity of the composite. Interestingly, the improvement in adsorption of IND was much higher than the quantity estimated for the porosity. Importantly, GnO/MIL-101 showed the highest adsorption capacities for NCCs. Irrespective of the studied solvents and co-presence of IND and QUI, the composite adsorbent performed ADN most effectively. This remarkable improvement is explained by the additional mechanism of hydrogen bonding between the surface functional groups of GnO and the hydrogen attached to the nitrogen atom of IND. This hydrogen bonding mechanism is also supported by the results of the adsorption of pyrrole and methylpyrrole. On the other hand, QUI does not show hydrogen-bonding capability, and therefore, its enhanced adsorption originates from only the increased porosity of the adsorbents.

Chitosan capped nanoscale Fe-MIL-88B-NH2 metal-organic framework as drug carrier material for the pH responsive delivery of doxorubicin

Science.gov (United States)

Sivakumar, P.; Priyatharshni, S.; Nagashanmugam, K. B.; Thanigaivelan, A.; Kumar, K.

2017-08-01

In recent years nanoscale metal-organic frameworks (NMOFs) are contributing as an effective material for use in drug delivery and imaging applications due to their porous surfaces and easy surface modifications. In this work, Fe-MIL-88B-NH2 NMOFs were successfully synthesized on facile hydrothermal route and 2-aminoterephthalic acid (NH2-BDC) was employed as a bridging ligand to activate amine functional groups on the surface. Amine functional groups not only serve as a structure stabilizing agent but also enhance the loading efficiency of the doxorubicin (DOX) anticancer drug. A pH responsive DOX release was realized by introducing a positively charged chitosan (Chi) capping layer. Upon Chi-coating, cleavage was observed in the Fe-MIL-88B-NH2 structure at acidic pH, while gel-like insoluble structure was formed at basic pH. By utilizing this phenomenon, a pH responsive DOX release system was developed by using Chi capped Fe-MIL-88B-NH2 NMOFs under the designed pH (4.0-8.0). The results suggest the Chi capped Fe-MIL-88B-NH2 can be a promising candidate for future pH responsive drug delivery systems.

Green synthesis and evaluation of an iron-based metal-organic framework MIL-88B for efficient decontamination of arsenate from water.

Science.gov (United States)

Hou, Shuliang; Wu, Yi-Nan; Feng, Lingyu; Chen, Wei; Wang, Ying; Morlay, Catherine; Li, Fengting

2018-02-13

Iron-containing metal-organic frameworks (MOFs) have gradually emerged as environmentally benign alternatives for reducing the levels of environmental contamination because of their advantages, such as readily obtained raw materials with low cost, nontoxic metal source with good biocompatibility, and distinguished physicochemical features e.g., high porosity, framework flexibility, and semiconductor properties. In this study, we reported an innovative strategy for synthesizing an iron-based MOF, MIL-88B, at room temperature. The novelty of this strategy was the use of ethanol as solvent and the pretreatment of dry milling with neither the bulk use of a toxic organic solvent nor the addition of extremely dangerous hydrofluoric acid or strong alkali. The synthesized MIL-88B(Fe) was evaluated as a sorbent for removing arsenate in water and it exhibited high adsorption capacity (156.7 mg g -1 ) at a low dosage. The removal capacity of trace arsenate on MIL-88B(Fe) was 32.3 mg g -1 at a low equilibrium concentration (6.4 μg L -1 ), which satisfied the arsenic threshold for drinking water. The results of Fourier transform infrared and X-ray photoelectron spectroscopy indicated that the As(v) molecules bonded with the oxygen molecules, which were coordinated with FeO clusters in the framework. This work presented the potential use of the up-scaled MIL-88B as an excellent sorbent for purifying arsenate-contaminated water.

Metal organic framework g-C3N4/MIL-53(Fe) heterojunctions with enhanced photocatalytic activity for Cr(VI) reduction under visible light

Science.gov (United States)

Huang, Wenyuan; Liu, Ning; Zhang, Xiaodong; Wu, Minghong; Tang, Liang

2017-12-01

In this study, hybrid nanocomposites based on Fe-based MOF and graphitic carbon nitride (g-C3N4) were developed by a facile solvothermal method. The as-prepared materials were characterized by XRD, FESEM, TEM, XPS and PL analysis. It was showed that the introduction of a certain amount of g-C3N4 on the surface of MIL-53(Fe) would improve the separation and migration rate of photo-induced charges, consequently resulting in the boost of photocatalytic efficiency. Compared with g-C3N4 and MIL-53(Fe), the CMFe composites displayed more excellent visible light-resposive photocatalytic activity for the reduction of Cr(VI). The optimal doping content of g-C3N4 in g-C3N4/MIL-53(Fe) composite was determined to be 3.0 wt%, and it showed about 2.1 and 2.0 times as high photocatalytic efficiency for the reduction of Cr(VI) as that of pure g-C3N4 and MIL-53(Fe), respectively. Meanwhile, the composite exhibited good reusability and stability in the process of cyclic experiments. A possible photocatalytic reaction mechanism was also investigated in detail by the related electrochemical analysis.

Mulheres e homens em sindicato docente: um estudo de caso Men and women in an educator's union: a case study

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Márcia Ondina Vieira Ferreira

2004-08-01

Full Text Available O estudo examina a relação entre participação feminina e masculina no Centro dos Professores do Estado do Rio Grande do Sul - CPERS/Sindicato -, comparando filiação e presença nas diretorias da entidade segundo o sexo, para verificar se nessa entidade a situação das mulheres é diferente da sua situação em outras diretorias de sindicatos de classe, com base composta majoritariamente por homens. Discorre sobre a reduzida participação sociopolítica das mulheres, apresentando, também, números sobre docência e gênero no Brasil. Os resultados indicam inversão da proporcionalidade homens/mulheres na base da categoria em relação às direções da entidade, de tal maneira que, mesmo estando as mulheres bem representadas nesse sindicato, são os homens que ocupam os lugares com maior poder de mando e prestígio, como nas diretorias. Por fim, considerando que a atividade sindical é dominada por um viés masculino, questiona-se se o sindicato estaria tendo condições de acompanhar possíveis modificações na identidade docente, a partir da imagem que tem da categoria.This study examines the relationship between male and female participation in the Centro dos Professores do Estado do Rio Grande do Sul - CPERS/Sindicato (Center of Educators in the State of Rio Grande do Sul - CPERS/Union, comparing membership and presence in the board of directors according to sex, to find out whether women's situation in this union is different from those of other class union boards of directors, composed mostly of men. It discusses the small social and political participation of women and shows some figures on educators and gender in Brazil. The findings indicate a men vs. women proportionality inversion in the category base compared to the board of directors, in such a way that, although women are well represented in this union, men are the ones who occupy positions of greater power and prestige, such as the board. Finally, considering the fact

Propuesta de una planificación estratégica e indicadores de desempeño para la empresa Talleres Mil Usos

OpenAIRE

Gómez Zhiminaicela, Johanna Elizabeth; Redrován Reyes, Mayra Elizabeth

2014-01-01

En el presente trabajo se realizó una propuesta de Planificación Estratégica y medidores de desempeño para la empresa Talleres Mil Usos, se analizó los diferentes parámetros de la Planificación Estratégica y su importancia dentro de las organizaciones, también se planteó objetivos, estrategias e indicadores desempeño para verificar su desempeño laboral. In this work was carried out a Strategic Planning proposal and performance mediators for the company Talleres Mil Usos, looking at differe...

Homicídios de homens de quinze a 29 anos e fatores relacionados no estado do Paraná, de 2002 a 2004 Homicides between men aged 15 to 29 years and related factors in the State of Paraná, Brazil, 2002/2004

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Selma Maffei de Andrade

2011-01-01

Full Text Available Os homicídios constituem-se a primeira causa de morte não natural no Brasil e seu estudo pode subsidiar medidas para seu controle. O objetivo deste estudo foi verificar a mortalidade por homicídios e intervenções legais de homens jovens no estado do Paraná, e identificar características municipais correlacionadas. Foi realizado estudo ecológico, com os municípios do Paraná como unidades de análise. Foram calculados os coeficientes de mortalidade por homicídios e intervenções legais de homens de quinze a 29 anos, de 2002 a 2004 e obtidos dados socioeconômicos e demográficos municipais. O coeficiente de mortalidade do estado foi de 94,8 por cem mil. O tamanho da população, a proporção de jovens de quinze a 24 anos, a proporção de matrículas no ensino superior e o índice de Gini foram os indicadores mais correlacionados à mortalidade por homicídios (pHomicides are the main cause of non-natural death in Brazil and studies about them may contribute to their control. The objective of this study was to verify mortality rates due to homicides and legal interventions among young men in the State of Paraná, Brazil, and to identify correlated municipal characteristics. An ecological study was conducted, having the municipalities of the State as units of analysis. Mortality rates of homicides and legal interventions among men from 15 to 29 years of age were calculated for the years 2002-2004 and demographic and social municipal indicators were obtained. Mortality rate in the State was 94.8 per one hundred thousand. The size of the population, the proportion of young people aged 15 to 24 years, the proportion of enrollments in universities and the Gini index were the main indicators correlated to homicide mortality (p<0.0001. Mortality rates were highest in municipalities of metropolitan regions, in those located at the border with Paraguay and in those located in the way between them and the Southeast Region of Brazil. Mortality

El satisfecho: fama y fortuna de una comedia desconocida de Luis Belmonte (El satisfecho: fame and fortune of an unknown comedy by Luis Belmonte

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Elisa Domínguez de Paz

2014-01-01

Full Text Available Resumen: Este artículo ofrece un estudio del manuscrito autógrafo de la comedia, El satisfecho, firmado por el dramaturgo Luis Belmonte en Sevilla, el 24 de Julio de 1634. El documento proporciona buena información acerca de su recorrido por el tiempo, desde que obtiene la licencia de representación en Lisboa, en 1639, hasta que aparece en Toro, en 1653, como propiedad de Santiago Manteca. El manuscrito resulta muy interesante por la gran cantidad de probationes pennae, de contenido variado y ajeno al asunto teatral, que contiene. Estos ejercicios de escritura, salidos todos ellos de la pluma de Santiago Manteca, revelan que el escribano es un hombre preocupado por el mundo documental y formulístico. Su poco interés por conservar limpio el documento indica, por un lado, que , tal vez, la comedia ya no tenía éxito y, por otro lado, la más que probable desconexión de Manteca del mundo teatral.Abstract: This article studies an autographic manuscript of the comedy, El satisfecho, signed by the playwright Luis Belmonte in Seville, on July 24 1634. The document provides sound information about its journey through time, from the moment when it obtained its representation permit in Lisbon, in 1639, until it appeared in Toro, property of Santiago Manteca. The interest of the manuscript is very high due to the great number of probationes pennae that it contains, of very varied content and unrelated to the world of theatre. These writing exercises, coming out of Santiago Manteca’s pen, reveal that the secretary was a man concerned about the documental and formulaic world. His lack of interest in keeping the document clean may indicate, on the one hand, that the comedy was not successful any more, and, on the other, Manteca’s likely disconnection from the theatrical world.

Mineralogical characterization of historical portuguese wall tiles of Sao Luis, Maranhao, Brazil

International Nuclear Information System (INIS)

Rivas Mercury, J.M.; Vasconcelos, N.S.L.S.; Cabral, A.A.; Pereira, D.J. Costa; Angelica, R.S.

2010-01-01

Portuguese wall tiles from centuries, XVII, XVIII and XIX, found in Sao Luis Maranhao has been studied by X-ray diffraction, in order to interpret the possible raw material and burning temperature. The mineral phases, Quartz, Wollastonite, Calcite and Gehlenite were identified in all samples. Based on the results it is possible to affirm that the main raw materials used to manufacture this materials was probably mixtures of kaolinite clay and calcite. Based on the mineralogical information it was also possible to state that burning temperature of this wall tiles was lower than 1000 deg C. (author)

'Homens trans': novos matizes na aquarela das masculinidades? 'Trans men': new colours in the masculinities picture?

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Guilherme Almeida

2012-08-01

Full Text Available O artigo discute de forma exploratória a emergência de uma nova categoria identitária no Brasil, a de 'homem trans'. Essa se constrói diferenciando-se da identidade lésbica e, também, de expressões de gênero de outros grupos que tiveram seus corpos assignados como femininos ao nascimento, mas que contestam essa assignação sem, contudo, se afirmarem 'homens' de forma constante. Afirma-se que a emergência dos 'homens trans' tem sido potencializada pelo estabelecimento do processo transexualizador no SUS. Discutem-se o uso do termo "homem trans" e algumas características comuns a tais sujeitos. Problematizam-se a complexidade de seus processos de autorreconhecimento e construção de masculinidades, sua rápida capacidade de indiferenciação a partir de modificações corporais e, alguns dos efeitos políticos e subjetivos, da visibilidade e da indiferenciação.The article discusses in an exploratory form the emergence of a new identity category in Brazil, namely "transmen". This identity is constructed as a differentiation from the lesbian identity and also from gender expressions of other groups that had their bodies assigned as female upon birth, but that later refuted this assignment without, however, affirming themselves as "men" on a permanent way. The article claims that the emergence of "transmen" has been made possible by the establishment of the transexualization process in the Public Health Care System. Furthermore, the article discusses the use of the term "transman" and some common characteristics related to those persons. The author critiques their complex processes of self-knowledge and construction of masculinities, as well as their quick capacity for non-differentiation from the stand-point of bodily modifications. Finally, the author discusses the political and subjective consequences of their visibility and non-differentiation.

Padrões de refluxo nas veias safenas em homens com insuficiência venosa crônica

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Carlos Alberto Engelhorn

Full Text Available Resumo Contexto A insuficiência venosa crônica (IVCr é frequente e predomina nas mulheres, mas ainda há poucas informações sobre o refluxo nas veias safenas na população masculina. Objetivos Identificar os diferentes padrões de refluxo nas veias safenas magnas (VSMs e parvas (VSPs em homens, correlacionando esses dados com a apresentação clínica conforme a classificação Clínica, Etiológica, Anatômica e Fisiopatológica (CEAP. Métodos Foram avaliados 369 membros inferiores de 207 homens pela ultrassonografia vascular (UV com diagnóstico clínico de IVCr primária. As variáveis analisadas foram a classificação CEAP, o padrão de refluxo nas VSMs e VSPs e a correlação entre os dois. Resultados Nos 369 membros avaliados, 72,9% das VSMs apresentaram refluxo com predominância do padrão segmentar (33,8%. Nas VSPs, 16% dos membros inferiores analisados apresentaram refluxo, sendo o mais frequente o padrão distal (33,9%. Dos membros classificados como C4, C5 e C6, 100% apresentaram refluxo na VSM com predominância do refluxo proximal (25,64%, e 38,46% apresentaram refluxo na VSP com equivalência entre os padrões distal e proximal (33,3%. Refluxo na junção safeno-femoral (JSF foi detectado em 7,1% dos membros nas classes C0 e C1, 35,6% nas classes C2 e C3, e 64,1% nas classes C4 a C6. Conclusões O padrão de refluxo segmentar é predominante na VSM, e o padrão de refluxo distal é predominante na VSP. A ocorrência de refluxo na JSF é maior em pacientes com IVCr mais avançada.

A propósito de José Luis Brea: del archivo a la RAM

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Fernando Broncano

2014-06-01

Full Text Available The philosopher José Luis Brea proposes a notion of memory spread around a network of connections, which reveals a conception of culture based on a RAM structure and contrary to the culture of archive. The underwent changes in the classification of disciplines caused by individual’s attitudes deriving from the new media hyperconnectivity environment will be reviewed here and the relevance in the present humanities of concepts such as exile, frontier and question without answer.

Petits mils, énorme potentiel : diversifiés, nutritifs et adaptés aux ...

International Development Research Centre (IDRC) Digital Library (Canada)

29 avr. 2016 ... Dans les pays en développement, le manque de diversité dans l'alimentation est l'une des principales causes de la malnutrition et de la prévalence de maladies non transmissibles comme le diabète. La culture des petits mils en complément des cultures existantes pourrait faire partie de la solution.

Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)-Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS).

Science.gov (United States)

Jeazet, Harold B Tanh; Koschine, Tönjes; Staudt, Claudia; Raetzke, Klaus; Janiak, Christoph

2013-10-25

Hydrothermally stable particles of the metal-organic framework MIL-101(Cr) were incorporated into a polysulfone (PSF) matrix to produce mixed-matrix or composite membranes with excellent dispersion of MIL-101 particles and good adhesion within the polymer matrix. Pure gas (O2, N2, CO2 and CH4) permeation tests showed a significant increase of gas permeabilities of the mixed-matrix membranes without any loss in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that the increased gas permeability is due to the free volume in the PSF polymer and the added large free volume inside the MIL-101 particles. The trend of the gas transport properties of the composite membranes could be reproduced by a Maxwell model.

Desemprego e inatividade nas metrópoles brasileiras: as diferenças entre homens e mulheres

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Pedro Rodrigues de Oliveira

2011-01-01

Full Text Available Analisar a evolução recente da estrutura do desemprego e da inatividade nas metrópoles brasileiras é o objetivo deste trabalho. Além de um panorama geral, foram realizadas análises separadas por gênero. A resposta da inatividade para a variável "número de crianças no domicílio" é a que mais se destaca: há uma relação negativa para os homens, e positiva para as mulheres. Além disso, os padrões observados entre mulheres pobres e não pobres são muito diferenciados – a inatividade para as mulheres de renda baixa é significativamente maior –, refletindo diferenças de escolaridade e, provavelmente, dificuldades de acesso à creche.

Preparation of MIL-53(Fe)-Reduced Graphene Oxide Nanocomposites by a Simple Self-Assembly Strategy for Increasing Interfacial Contact: Efficient Visible-Light Photocatalysts.

Science.gov (United States)

Liang, Ruowen; Shen, Lijuan; Jing, Fenfen; Qin, Na; Wu, Ling

2015-05-13

In this work, MIL-53(Fe)-reduced graphene oxide (M53-RGO) nanocomposites have been successfully fabricated by a facile and efficient electrostatic self-assembly strategy for improving the interfacial contact between RGO and the MIL-53(Fe). Compared with D-M53-RGO (direct synthesis of MIL-53(Fe)-reduced graphene oxide nanocomposites via one-pot solvothermal approach), M53-RGO nanocomposites exhibit improved photocatalytic activity compared with the D-M53-RGO under identical experimental conditions. After 80 min of visible light illumination (λ ≥ 420 nm), the reduction ratio of Cr(VI) is rapidly increased to 100%, which is also higher than that of reference sample (N-doped TiO2). More significantly, the M53-RGO nanocomposites are proven to perform as bifunctional photocatalysts with considerable activity in the mixed systems (Cr(VI)/dyes) under visible light, which made it a potential candidate for industrial wastewater treatment. Combining with photoelectrochemical analyses, it could be revealed that the introduction of RGO would minimize the recombination of photogenerated electron-hole pairs. Additionally, the effective interfacial contact between MIL-53(Fe) and RGO surface would further accelerate the transfer of photogenerated electrons, leading to the enhancement of photocatalytic activity of M53-RGO toward photocatalytic reactions. Finally, a possible photocatalytic reaction mechanism is also investigated in detail.

Synthesis, characterization and sorption properties of functionalized Cr-MIL-101-X (X=–F, –Cl, –Br, –CH3, –C6H4, –F2, –(CH3)2) materials

International Nuclear Information System (INIS)

Buragohain, Amlan; Couck, Sarah; Van Der Voort, Pascal; Denayer, Joeri F.M.; Biswas, Shyam

2016-01-01

Four existing and three new functionalized chromium terephthalates having MIL-101 topology and denoted as Cr-MIL-101-X (existing ones with X=–F, 1-F; –Cl, 2-Cl; –Br, 3-Br; –CH 3 , 4-CH 3 ; new ones with X=–C 6 H 4 , 5-C 6 H 4 ; –F 2 , 6-F 2 , –(CH 3 ) 2 , 7-(CH 3 ) 2 ) were synthesized under hydrothermal conditions. All the materials except 5-C 6 H 4 could be prepared by a general synthetic route, in which the mixtures of CrO 3 , H 2 BDC-X (BDC=1,4-benzenedicarboxylate) linkers, conc. HCl and water with a molar ratio of 1:1:3.9:222.2 were reacted at 180 °C for 144 h. Compared to the 144 h of synthesis time, three of the compounds, namely 1-Cl, 2-Br and 5-C 6 H 4 , could be prepared in much shorter reaction times (12–18 h at 180–210 °C). The materials possess high thermal stability up to 270–300 °C in an air atmosphere. The activated compounds exhibit significant porosity (S BET range: 1273–2135 m 2 g −1 ). At 0 °C and 1 bar, the CO 2 adsorption capacities of the compounds fall in the 1.7–2.9 mmol g −1 range. Compounds 1-F and 6-F 2 showed enhanced CO 2 uptake values compared to parent Cr-MIL-101. The benzene adsorption capacities of the compounds lie in the range of 66.2–139.5 molecules per unit cell at 50 °C and p/p 0 =0.35. The increased benzene uptake value of 1-F compared to un-functionalized Cr-MIL-101 and 4-CH 3 suggests that the fluorination has induced more hydrophobicity in Cr-MIL-101 as compared to the methylation. - Graphical abstract: Benzene adsorption by seven functionalized Cr-MIL-101-X metal-organic framework (MOF) materials Display Omitted - Highlights: • Seven functionalized Cr-MIL-101-X materials were synthesized solvothermally. • All Cr-MIL-101-X materials exhibited high thermal stability up to 270–300 °C in air. • All Cr-MIL-101-X compounds displayed considerable porosity towards N 2 , CO 2 and benzene. • Mono- and di-fluorinated Cr-MIL-101 materials showed enhanced CO 2 adsorption capacities. �

Characterization of adsorbed water in MIL-53(Al) by FTIR spectroscopy and ab-initio calculations.

Science.gov (United States)

Salazar, J M; Weber, G; Simon, J M; Bezverkhyy, I; Bellat, J P

2015-03-28

Here, we report ab-initio calculations developed with a twofold purpose: understand how adsorbed water molecules alter the infrared spectrum of the metal-organic framework MIL-53(Al) and to investigate which are the associated physico-chemical processes. The analyzed structures are the two anhydrous narrow (np⊘) and large (lp⊘) pore forms and the hydrated narrow pore form (np-H2O) of the MIL-53(Al). For these structures, we determined their corresponding infrared spectra (FTIR) and we identified the vibrational modes associated to the dominant spectral lines. We show that wagging and scissoring modes of CO2 give flexibility to the structure for facilitating the lp⊘- np⊘ transition. In our studies, this transition is identified by eight vibrational modes including the δCH(18a) vibrational mode currently used to identify the mentioned transition. We report an exhaustive band identification of the infrared spectra associated to the analyzed structures. Moreover, the FTIR for the np-H2O structure allowed us to identify four types of water molecules linked to the host structure by one to three hydrogen bonds.

Emma Zunz by Jorge Luis Borges: the Concept of Justice

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Rosa Vila

2014-12-01

Full Text Available Emma Zunz, by Jorge Luis Borges, is the story of a girl who decides to kill her boss in order to avenge her father’s death, believing that her father’s version of an event that occurred years before was true. Thus, she devises a secret plan, which includes losing her virginity to a complete stranger, shortly before committing the crime, so she could argue that her boss had raped her and that she killed him in self-defense. Firstly, the text shows the contrast between formal justice and taking justice into own hands. Secondly, the question of self-inflicted punishment, which in the story takes place before the perpetration of the crime. Finally, the issue whether truth is the version that can be inferred from the evidence presented in a trial, or the one which is kept to themselves by those involved in a crime. Emma Zunz, de Jorge Luis Borges, es la historia de una chica que decide matar a su jefe para vengar la muerte de su padre, creyendo que la versión de su padre de un hecho que ocurrió años atrás era cierta. De este modo, diseña un plan secreto, que incluye la pérdida de su virginidad con un desconocido, poco antes de cometer el crimen, para poder argumentar que su jefe la había violado y que ella lo mató en defensa propia. En primer lugar, el texto muestra el contraste entre la justicia formal y la justicia por cuenta propia. En segundo lugar, la cuestión de la pena infligida a uno mismo, lo que en la historia se produce antes de la comisión del delito. Por último, la cuestión de si la verdad es la versión que se puede inferir de las pruebas presentadas en un juicio, o la que se guardan para sí mismas las personas involucradas en un crimen. DOWNLOAD THIS PAPER FROM SSRN: http://ssrn.com/abstract=2519490

Augmentation de la production de petits mils en Asie du Sud | CRDI ...

International Development Research Centre (IDRC) Digital Library (Canada)

La production de petits mils, en dépit des vertus nutritionnelles de cette céréale, de sa capacité de croître dans des conditions difficiles et de sa facilité de stockage, a toujours été négligée par les politiques agricoles déployées en Asie du Sud. Ces dernières, en effet, ont privilégié les cultures de rente et les céréales comme ...

Effect of Amine-Functionalized MIL-53 Metal Organic Frameworks on the Performance of Poly(4-methyl-1-pentyne Membrane in CO2/CH4 Separation Gas Mixture

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Reza Abedini

2015-06-01

Full Text Available The effect of NH2-MIL 53 metal organic framework (MOF on gas transport properties of poly(4-methyl-1-pentyne (PMP was investigated. Various characterization methods such as FTIR, DSC, SEM and gas adsorption test as well as a series of CO2/CH4 gas separation tests (i.e., pure and mixed gas test were conducted in order to determine the effect of ligand functionalization (–NH2 on the properties of the prepared mixed matrix membranes and their gas transport characteristics. The results of DSC showed that glass transition temperature (Tg increased by increasing NH2-MIL 53 loading. The SEM images also demonstrated that the NH2-MIL 53 particles were dispersed well in the PMP matrix with no noticeable agglomeration. The gas adsorption test of NH2-MIL 53 particles revealed there was a selective adsorption behavior with respect to CO2. It was also found that, incorporation of NH2-MIL 53 into the PMP resulted in an increase in gas permeability (especially towards CO2 and a higher CO2/CH4 selectivity. Adding 30 wt% NH2-MIL 53 into the polymer matrix increased CO2 permeability and CO2/CH4 selectivity of the mixed gas from 83.35 to 210.21 barrer and 7.61 to 19.88, respectively. Rising the temperature from 30 to 60°C led to the permeability increment of both CO2 and CH4 in the mixed gas test, while the CO2/CH4 selectivity decreased. Moreover, the results showed that amino groups required no regeneration and their performance did not decline during 120 h of permeation test. A comparison between the permeation data and those calculated from permeation models revealed that the Bruggeman model could fit the CO2 permeability data better than the Maxwell and Lewis models.

Risky sexual practices among men who have sex with men in Northeast Brazil: results from four sequential surveys Práticas sexuais de risco de homens que fazem sexo com homens no Nordeste do Brasil: resultados de quatro inquéritos seqüenciais

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Rogério Costa Gondim

2009-06-01

Full Text Available This paper focuses on recent trends in risky sexual practices for HIV/AIDS among men who have sex with men (MSM in Fortaleza, Ceará State, Brazil. Four cross-sectional surveys were conducted (1995, 1998, 2002, and 2005 among MSM 14 years or older who reported oral or anal sex in the previous 12 months. Sexual practices were considered risky whenever the respondent reported unprotected receptive or insertive anal intercourse in the six months preceding the interview. Different selection techniques were used to recruit the study population: snowball (1995, 1998, 2002 - 32%; time-space sampling (2002 - 68%; and respondent-driven sampling (2005. Analyses were based on the comparison between proportions. High rates of risky sexual practices were reported in 1995 (49.9%, decreasing in 1998 (32.6%, increasing again in 2002 (51.3%, and showing the lowest level in 2005 (31.4%. Participants with more schooling increased their risky practices from 1998 to 2002, decreasing in 2005. Among individuals with medium or low schooling, risky behavior declined from 2002 to 2005. The article highlights the need for behavioral surveillance to properly address STD/HIV prevention.Estudaram-se as tendências recentes das práticas sexuais de risco para DST/AIDS entre homens que fazem sexo com homens (HSH em Fortaleza, Ceará, Brasil. Realizaram-se quatro estudos seccionais (1995, 1998, 2002 e 2005 em HSH, com 14 anos ou mais, que tenham referido prática sexual oral ou anal com homens nos últimos 12 meses. Definiu-se prática sexual de risco uma relação anal insertiva ou receptiva sem uso de preservativo nos seis meses que antecederam a entrevista. Utilizaram-se técnicas de recrutamento do tipo snow ball (1995, 1998, 2002 - 32%; time space sampling (2002 - 68% e respondent driven sampling (2005. Análises basearam-se nas comparações entre proporções. Elevados percentuais de práticas sexuais de risco foram referidos em 1995 (49,9%, decrescendo em 1998 (32

Las políticas forestales en el estado de San Luis Potosí en el porfiriato

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Julio César Errejón Gómez

2017-04-01

Full Text Available Las acciones y omisiones del presente en materia de política forestal pueden clarificarse si se revisan los antecedentes históricos. Por ello, el objetivo de esta investigación fue analizar la influencia del contexto internacional sobre las políticas forestales implementadas durante el régimen de Porfirio Díaz. Se amplía el panorama sobre las de uso y conservación de los bosques, así como sus repercusiones en San Luis Potosí. Para contextualizar los procesos mencionados, se realizó una consulta exhaustiva de documentos históricos y bibliográficos, y se encontró que el entorno internacional incentivó la creación de leyes e instituciones federales y locales para regular la explotación, el manejo y la conservación de los bosques. A pesar de ello, en esta entidad hubo una reducción importante en sus superficies boscosas; además, el gobierno federal y estatal no evidenció un interés por preservarlas. _______________ Current actions and omissions in forest policy can be clarified if the historical background is reviewed. Therefore, the objective of this research is to analyze the influence of the international context on forest policies implemented during the regime of Porfirio Diaz (1876-1911. In particular, it aims to broaden the outlook on government policies created for the management, use and conservation of forests and their impacts on San Luis Potosi. A thorough consultation of historical and bibliographical documents was made to understand the historical processes. It was found that the international environment encouraged the creation of laws, regulations and federal and local institutions for the purpose of regulating the exploitation, management and conservation of forests. However, the state of San Luis Potosi experienced a significant reduction in their forest areas; in addition, the federal and state governments showed no interest in applying conservation of forests in Potosi territory.

Diagnóstico etiológico de la ceguera de Jorge Luis Borges basado en su obra literaria

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Mario Enrique de la Piedra Walter

2017-07-01

Conclusiones: Pese a que la miopía degenerativa es la etiología más probable de la ceguera de Jorge Luis Borges, no es posible descartar por completo otras oftalmopatías sin una exploración física adecuada. Se cumple el objetivo solo en el marco presuntivo.

Fe3O4 and metal-organic framework MIL-101(Fe) composites catalyze luminol chemiluminescence for sensitively sensing hydrogen peroxide and glucose.

Science.gov (United States)

Qian Tang, Xue; Dan Zhang, Yi; Wei Jiang, Zhong; Mei Wang, Dong; Zhi Huang, Cheng; Fang Li, Yuan

2018-03-01

In this work, Fe 3 O 4 and metal-organic framework MIL-101(Fe) composites (Fe 3 O 4 /MIL-101(Fe)) was demonstrated to possess excellent catalytic property to directly catalyze luminol chemiluminescence without extra oxidants. We utilized Fe 3 O 4 /MIL-101(Fe) to develop a ultra-sensitive quantitative analytical method for H 2 O 2 and glucose. The possible mechanism of the chemiluminescence reaction had been investigated. Under optimal conditions, the relative chemiluminescence intensity was linearly proportional to the logarithm of H 2 O 2 concentration in the range of 5-150nM with a limit of detection of 3.7nM (signal-to-noise ratio = 3), and glucose could be linearly detected in the range from 5 to 100nM and the detection limit was 4.9nM (signal-to-noise ratio = 3). Furthermore, the present approach was successfully applied to quantitative determination of H 2 O 2 in medical disinfectant and glucose in human serum samples. Copyright © 2017 Elsevier B.V. All rights reserved.

Fabrication, interfacial characterization and mechanical properties of continuous Al{sub 2}O{sub 3} ceramic fiber reinforced Ti/Al{sub 3}Ti metal-intermetallic laminated (CCFR-MIL) composite

Energy Technology Data Exchange (ETDEWEB)

Han, Yuqiang; Lin, Chunfa; Han, Xiaoxiao; Chang, Yunpeng; Guo, Chunhuan, E-mail: guochunhuan@hrbeu.edu.cn; Jiang, Fengchun, E-mail: fengchunjiang@hrbeu.edu.cn

2017-03-14

Continuous Al{sub 2}O{sub 3} ceramic fiber reinforced Ti/Al{sub 3}Ti metal-intermetallic laminated (CCFR-MIL) composite was fabricated using a vacuum hot pressing (VHP) sintering method and followed by hot isostatic pressing (HIP). The microstructure characteristics of the interfaces between Ti and Al{sub 3}Ti, as well as Al{sub 2}O{sub 3} fiber and Al{sub 3}Ti intermetallic were analyzed by scanning electron microscopy (SEM). Elemental distribution in the interfacial reaction zones were quantitatively examined by energy-dispersive spectroscopy (EDS). The phases in the composite were identified by X-ray diffractometer (XRD). The mechanical properties of the CCFR-MIL composite were measured using compression and tensile tests under quasi-static strain rate. The experimental results indicated that the residual Al was found in Al{sub 3}Ti intermetallic layer of CCFR-MIL composite. The interfacial reactions occurred during HIP and the reaction products were determined to be Al{sub 2}Ti, TiSi{sub 2}, TiO{sub 2} and Al{sub 2}SiO{sub 5} phases. Compared to Ti/Al{sub 3}Ti MIL composite without fiber reinforcement, both the strength and failure strain of CCFR-MIL composite under both compressive and tensile stress states increased due to the contribution of the continuous ceramic Al{sub 2}O{sub 3} fiber.

OS VINHOS DE MÚRCIA: CONTRIBUTO DE JOSÉ LUIS ANDRÉS SARASA

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Victor Dordio

2011-01-01

Full Text Available José Luis Andrés Sarasa y su equipo de investigadores de la Universidad de Murcia hizo un excelente análisis estructural de la producción de vino en la Región de Murcia en el marco del proyecto «Filières Innovantes» (2002-2005. Los temas del espacio y tiempo, la tipología de los productores, bajo la óptica del savoir-faire, han sido minuciosamente estudiados y presentados. Nuestra contribución a este estudio consistió en un capítulo sobre el turismo del vino, que no se trató anteriormente debido a la falta de tiempo.

Introduction to the Special Collection of Papers on the San Luis Basin Sustainability Metrics Project: A Methodology for Evaluating Regional Sustainability

Science.gov (United States)

This paper introduces a collection of four articles describing the San Luis Basin Sustainability Metrics Project. The Project developed a methodology for evaluating regional sustainability. This introduction provides the necessary background information for the project, descripti...

Prevalência de violência física por parceiro íntimo em homens e mulheres de Florianópolis, Santa Catarina, Brasil: estudo de base populacional

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Sheila Rubia Lindner

2015-04-01

Full Text Available Investigou-se a associação entre sexo e violência física entre parceiros íntimos. Encontrou-se prevalência de sofrer qualquer violência física (17%, violência física moderada (16,6% e violência física grave (7,3%. Não houve diferença significativa para violência física moderada em homens e mulheres, porém, quanto mais grave o ato maior a ocorrência deste nas mulheres. Por meio de regressão logística testou-se a associação da violência com o sexo, ajustando-se às variáveis exploratórias. Mulheres de maior idade, viúvas/separadas, pobres, menos escolarizadas e pretas registram maior probabilidade de sofrer violência. Nos homens, a prevalência de violência física grave apresentou alteração significativa apenas para estado civil. Uso abusivo de álcool por mulheres representou maior chance de sofrer violência física.

Facile Synthesis of Potassium Poly(heptazine imide) (PHIK)/Ti-Based Metal-Organic Framework (MIL-125-NH2) Composites for Photocatalytic Applications.

Science.gov (United States)

Rodríguez, Nicolás A; Savateev, Aleksandr; Grela, María A; Dontsova, Dariya

2017-07-12

Photocatalytically active composites comprising potassium poly(heptazine imide) (PHIK) and a Ti-based metal-organic framework (MOF, MIL-125-NH 2 ) are prepared in situ by simply dispersing both materials in water. The driving forces of composite formation are the electrostatic interactions between the solids and the diffusion of potassium ions from PHIK to MIL-125-NH 2 . This mechanism implies that other composites of poly(heptazine imide) salts and different MOFs bearing positive surface charge can potentially be obtained in a similar fashion. The suggested strategy thus opens a new avenue for the facile synthesis of such materials. The composites are shown to have a superior photocatalytic activity in Rhodamine B degradation under blue light irradiation. The reaction rate is doubled compared to that of pure MOF compound and is 7 times higher than the activity of the pristine PHIK. The results of the electron paramagnetic resonance (EPR) investigations and the analysis of the electronic structures of the solids suggest the electron transfer from MIL-125-NH 2 to PHIK in the composite. The possible pathways for the dye degradation and the rationalization of the increased activity of the composites are elaborated.

Ship-in-a-bottle CMPO in MIL-101(Cr) for selective uranium recovery from aqueous streams through adsorption.

Science.gov (United States)

De Decker, Jeroen; Folens, Karel; De Clercq, Jeriffa; Meledina, Maria; Van Tendeloo, Gustaaf; Du Laing, Gijs; Van Der Voort, Pascal

2017-08-05

Mesoporous MIL-101(Cr) is used as host for a ship-in-a-bottle type adsorbent for selective U(VI) recovery from aqueous environments. The acid-resistant cage-type MOF is built in-situ around N,N-Diisobutyl-2-(octylphenylphosphoryl)acetamide (CMPO), a sterically demanding ligand with high U(VI) affinity. This one-step procedure yields an adsorbent which is an ideal compromise between homogeneous and heterogeneous systems, where the ligand can act freely within the pores of MIL-101, without leaching, while the adsorbent is easy separable and reusable. The adsorbent was characterized by XRD, FTIR spectroscopy, nitrogen adsorption, XRF, ADF-STEM and EDX, to confirm and quantify the successful encapsulation of the CMPO in MIL-101, and the preservation of the host. Adsorption experiments with a central focus on U(VI) recovery were performed. Very high selectivity for U(VI) was observed, while competitive metal adsorption (rare earths, transition metals...) was almost negligible. The adsorption capacity was calculated at 5.32mg U/g (pH 3) and 27.99mg U/g (pH 4), by fitting equilibrium data to the Langmuir model. Adsorption kinetics correlated to the pseudo-second-order model, where more than 95% of maximum uptake is achieved within 375min. The adsorbed U(VI) is easily recovered by desorption in 0.1M HNO 3 . Three adsorption/desorption cycles were performed. Copyright © 2017 Elsevier B.V. All rights reserved.

Hydrogeologic Assessment of the East Bear Creek Unit, San LuisNational Wildlife Refuge

Energy Technology Data Exchange (ETDEWEB)

Quinn, Nigel W.T.

2007-07-15

San Luis National Wildlife Refuge Complex to meetReclamation s obligations for Level 4 water supply under the CentralValley Project Improvement Act. Hydrogeological assessment of the EastBear Creek Unit of the San Luis National Wildlife Refuge was conductedusing a combination of field investigations and a survey of availableliterature from past US Geological Survey Reports and reports by localgeological consultants. Conservative safe yield estimates made using theavailable data show that the East Bear Creek Unit may have sufficientgroundwater resources in the shallow groundwater aquifer to meet aboutbetween 25 percent and 52 percent of its current Level II and between 17percent and 35 percent of its level IV water supply needs. The rate ofsurface and lateral recharge to the Unit and the design of the well fieldand the layout and capacity of pumped wells will decide both thepercentage of annual needs that the shallow aquifer can supply andwhether this yield is sustainable without affecting long-term aquiferquality. In order to further investigate the merits of pumping the nearsurface aquifer, which appears to have reasonable water quality for usewithin the East Bear Creek Unit -- monitoring of the potential sources ofaquifer recharge and the installation of a pilot shallow well would bewarranted. Simple monitoring stations could be installed both upstreamand downstream of both the San Joaquin River and Bear Creek and beinstrumented to measureriver stage, flow and electrical conductivity.Ideally this would be done in conjunction with a shallow pilot well,pumped to supply a portion of the Unit's needs for the wetland inundationperiod.

HKUST-1 Membranes Anchored on Porous Substrate by Hetero MIL-110 Nanorod Array Seeds.

Science.gov (United States)

Mao, Yiyin; Cao, Wei; Li, Junwei; Sun, Luwei; Peng, Xinsheng

2013-09-02

Great anchors and seeds: Hetero-seeding growth processes and anchored nanorod arrays were successfully utilized in the synthesis of HKUST-1 membranes. These arrays were firmly anchored on porous substrates by using a MIL-110 nanorod array as both the anchor and seed. The resulting HKUST-1 membranes demonstrated good separation factors for binary gases exceeding the Knudson selectivity. Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim.

El basamento de la sierra de San Luis: Nuevas evidencias magnéticas y sus implicancias tectónicas The basement of Sierra de San Luis: New magnetic evidence and tectonic implication

OpenAIRE

CJ Chernicoff; VA Ramos

2003-01-01

Los mapas aeromagnéticos disponibles de las sierras de San Luis y Comechingones en el sector sudoriental de las Sierras Pampeanas de Argentina, permiten examinar las características geológicas y estructurales de las unidades metamórficas e intrusivas del basamento de la región. A través de la aplicación del filtro de continuación ascendente a los datos del campo magnético total reducido al polo, se ha podido observar la configuración profunda de las distintas unidades. Entre ellas se destaca ...

Effets de la microdose sur la production du niébé, du mil et du ...

African Journals Online (AJOL)

respectivement pour le sorgho, le mil et le niébé comparativement au témoin. La microdose a été .... Les prix utilisés sont celui du marché local au moment des semis pour les engrais soit 17500 FCFA pour NPK et ..... Projet « Transfert de la.

76 FR 414 - Tier 1 Environmental Impact Statement for the Los Angeles to San Luis Obispo (LOSSAN North) Rail...

Science.gov (United States)

2011-01-04

... expected growth in population and resulting increases in intercity travel demand between Los Angeles and San Luis Obispo. As a result of this growth in travel demand, their travel delays from the growing... environmental analysis to help make corridor level decisions regarding the level of intercity passenger rail...

Real-Time Water Quality Monitoring and Habitat Assessment in the San Luis National Wildlife Refuge

OpenAIRE

Quinn, Nigel W.T.; Hanlon, Jeremy S.; Burns, Josephine R.; Stromayer, Karl A.K.; Jordan, Brandon M.; Ennis, Mike J.; Woolington, Dennis W.

2005-01-01

The project report describes a two year experiment to control wetland drainage to the San Joaquin River of California from the San Luis National Wildlife Refuge using a decision support system for real-time water quality management. This system required the installation and operation of one inlet and three drainage flow and water quality monitoring stations which allowed a simnple mass balance model to be developed of the seasonally managed wetlands in the study area. Remote sensing meth...

Trivalent Chromium Process (TCP) as a Sealer for MIL-A-8625F Type II, IIB, and IC Anodic Coatings

National Research Council Canada - National Science Library

Matzdorf, Craig; Beck, Erin; Hilgeman, Amy; Prado, Ruben

2008-01-01

This report documents evaluations of trivalent chromium compositions (TCP) as sealers for MIL-A-8625F Type II, IIB, and IC anodic coatings conducted from March 2001 through December 2007 by Materials Engineering...

Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)–Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS)

Science.gov (United States)

Jeazet, Harold B. Tanh; Koschine, Tönjes; Staudt, Claudia; Raetzke, Klaus; Janiak, Christoph

2013-01-01

Hydrothermally stable particles of the metal-organic framework MIL-101(Cr) were incorporated into a polysulfone (PSF) matrix to produce mixed-matrix or composite membranes with excellent dispersion of MIL-101 particles and good adhesion within the polymer matrix. Pure gas (O2, N2, CO2 and CH4) permeation tests showed a significant increase of gas permeabilities of the mixed-matrix membranes without any loss in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that the increased gas permeability is due to the free volume in the PSF polymer and the added large free volume inside the MIL-101 particles. The trend of the gas transport properties of the composite membranes could be reproduced by a Maxwell model. PMID:24957061

Disseminating Evidence-Based Physical Education Practices in Rural Schools: The San Luis Valley Physical Education Academy.

Science.gov (United States)

Belansky, Elaine S; Cutforth, Nick; Kern, Ben; Scarbro, Sharon

2016-09-01

To address childhood obesity, strategies are needed to maximize physical activity during the school day. The San Luis Valley Physical Education Academy was a public health intervention designed to increase the quality of physical education and quantity of moderate to vigorous physical activity (MVPA) during physical education class. Elementary school physical education teachers from 17 schools participated in the intervention. They received SPARK curriculum and equipment, workshops, and site coordinator support for 2 years. A pre/post/post within physical education teacher design was used to measure intervention effectiveness. System for Observing Fitness Instruction Time (SOFIT) and a physical education teacher survey were collected 3 times. MVPA increased from 51.1% to 67.3% over the 2-year intervention resulting in approximately 14.6 additional hours of physical activity over a school year and 4662 kcal or 1.33 lbs. of weight gain prevention. More time was spent on skill drills and less time on classroom management and free play. The San Luis Valley Physical Education Academy succeeded in increasing rural, low-income students' physical activity. The multicomponent intervention contributed to the program's success. However, cost-effective approaches are needed to disseminate and implement evidencebased practices aimed at increasing students' physical activity during the school day.

Thermally driven refrigeration by methanol adsorption on coatings of HKUST-1 and MIL-101(Cr)

International Nuclear Information System (INIS)

Kummer, Harry; Baumgartner, Max; Hügenell, Philipp; Fröhlich, Dominik; Henninger, Stefan K.; Gläser, Roger

2017-01-01

Highlights: • A novel approach of shaping MOFs as coatings on Al-substrates used as HX materials. • The efficiency of HKUST-1 and MIL-101(Cr) for refrigeration via Methanol sorption. • The thermal stability of the MOF coatings under application relevant conditions. • Focus on early implementation by use of commercially and pre-industrially MOFs. • Modelling of sorption uptakes under application conditions for apparatus design. - Abstract: A new and versatile binder-based metal organic framework-(MOF-) coating enables efficient use in fast-cycle adsorption chillers for cooling and refrigeration applications. Two different adsorbents were presented, HKUST-1 and Mil-101(Cr), with promising methanol adsorption characteristics and high loading capacities up to 1.22 g g"−"1. Polysiloxane-based coatings containing 65 and 80 wt% of the MOF adsorbents were produced and the adsorption characteristics were studied before and after extensive thermal treatment over 1000 cycles between 20 °C and 130 °C under methanol atmosphere by thermogravimetric analysis and X-ray diffractometry. Using the Dubinin-Astakhov approach, possible methanol loading lifts in a refrigeration process under different application conditions were quantified.

H5PV2Mo10O40 encapsulated in MIL-101(Cr): facile synthesis and characterization of rationally designed composite materials for efficient decontamination of sulfur mustard.

Science.gov (United States)

Li, Yanqin; Gao, Qi; Zhang, Lijuan; Zhou, Yunshan; Zhong, Yuxu; Ying, Ying; Zhang, Mingcai; Huang, Chunqian; Wang, Yong'an

2018-04-24

Currently extensive effort is compulsively expended to decontaminate efficiently banned chemical war agents. In this work, H5PV2Mo10O40 molecules have been encapsulated in mesoporous MIL-101(Cr), which features two types of mesoporous cages (internal diameters of 29 Å and 34 Å) and microporous windows (diameters of 12 Å and 16 Å), leading to the formation of a new composite H5PV2Mo10O40@MIL-101(Cr) through a simple impregnation method. The composite was characterized thoroughly by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, TG/DTA, and textural analysis thereby confirming the encapsulation of the H5PV2Mo10O40 into MIL-101(Cr). The decontamination efficiency of sulfur mustard (4 μL HD in 40 μL of petroleum ether) by 20 mg of the composite is found to be 97.39% in 120 min under ambient conditions. GC-MS analysis on the decontaminated products using 2-chloroethyl ethyl sulfide (CEES), which has been widely used as a simulant of sulfur mustard, showed that MIL-101(Cr) just decontaminates CEES by adsorption, while CEES can be decontaminated under ambient conditions by a synergetic combination of adsorption of MIL-101(Cr) and subsequent chemical oxidation degradation to nontoxic 2-chloroethyl ethyl sulfoxide (CEESO) due to the presence of highly dispersed H5PV2Mo10O40 within the composites.

Mortalidade por cirrose, câncer hepático e transtornos devidos ao uso de álcool: Carga Global de Doenças no Brasil, 1990 e 2015

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Ana Paula Souto Melo

Full Text Available RESUMO: Introdução: O uso de álcool é um dos principais fatores de risco preveníveis para mortalidade ou incapacidade prematuras. Objetivo: Descrever as estimativas de mortalidade e anos de vida perdidos por morte prematura (YLL por cirrose, câncer hepático e transtornos devidos ao uso de álcool no Brasil e suas unidades da federação (UFs, em 1990 e 2015. Métodos: Estudo descritivo com dados do estudo de Carga Global de Doenças (2015 e do Sistema de Informações sobre Mortalidade (SIM. Modelos estatísticos foram empregados para obter estimativas corrigidas de mortalidade pelas causas selecionadas. As taxas de mortalidade foram padronizadas por idade (TMPI. Resultados: Em 1990, foram estimados 16.226 óbitos para as 3 condições (17,0/100 mil habitantes, enquanto em 2015 foram 28.337 (15,7/100 mil habitantes. Houve redução da mortalidade (por 100 mil habitantes por cirrose (de 11,4 para 9,5 e estabilidade por câncer hepático (1,5 e 1,9 e transtornos devidos ao uso de álcool (4,1 e 4,3. As TMPI foram 5,1 vezes maiores entre os homens, e as 5 UFs com maiores TMPI e YLL foram da Região Nordeste: Sergipe, Ceará, Pernambuco, Paraíba e Alagoas. As taxas de mortalidade e de YLL pelas três condições estudadas ascenderam no ranking das causas de óbito, em ambos os sexos, exceto a cirrose no feminino. Conclusão: As três condições estudadas são responsáveis por importante carga de mortalidade prematura no Brasil, principalmente entre homens e residentes na região nordeste. Esses resultados reforçam a necessidade de políticas públicas para o enfrentamento ao consumo nocivo do álcool no Brasil.

Resposta da cinética de consumo de oxigênio e da eficiência mecânica delta de homens e mulheres em diferentes intensidades de esforço

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Lucenildo S Cerqueira

2011-08-01

Full Text Available INTRODUÇÃO:A eficiência mecânica delta (EMΔ e a cinética do consumo de oxigênio (K2 são influenciadas por parâmetros metabólicos musculares e pelo transporte de 2. O objetivo do presente estudo foi determinar a diferença na K2 e na EMΔ em três intensidades de esforço nos dois gêneros. MÉTODOS: 56 sujeitos (26 mulheres foram submetidos ao protocolo de esforço escalonado, contínuo e máximo (GxT no cicloergômetro mecânico para determinação da potência aeróbia máxima (2máx, carga máxima (Wmax, limiar anaeróbio (AT e ponto de compensação respiratória (PCR. O AT foi determinado através dos métodos V-slope e E E / 2; o PCR através da relação 2 versus E ; ambos por dois avaliadores. A EMΔ e a K 2 foram consideradas como a inclinação entre 2 versus Watts e 2 versus tempo (s, respectivamente, do começo do teste até o AT (S1, do AT ao PCR (S2 e do PCR ao 2máx (S3, determinada por análise de regressão linear. RESULTADOS: Para a EMΔ, diferenças significativas foram observadas entre S1 versus S2 (p = 0,001, S1 versus S3 (p = 0,001 e S2 versus S3 (p = 0,006. Não foi observada diferença (p = 0,060 ou interação significativa (p = 0,062 entre homens versus mulheres. Para a K 2 diferenças significativas foram observadas entre S1 versus S3 (p = 0,001 e S2 versus S3 (p = 0,001 em ambos gêneros. Diferenças (p = 0,001 e interação significativa (p = 0,006 foram observadas entre homens versus mulheres, no último parâmetro. CONCLUSÕES: A EMΔ decresce com o incremento da intensidade de trabalho, porém, não há diferenças quando se compara homens e mulheres. Por outro lado, as mulheres apresentam K 2 mais rápida do que os homens.

TECNOLOGÍA LÍTICA Y USO DIFERENCIAL DEL ESPACIO EN ESTANCIA LA SUIZA, SAN LUIS, ARGENTINA / Lithic technology and differential use of space in Estancia La Suiza, San Luis, Argentina

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Gisela Sario

2013-07-01

Full Text Available El trabajo pretende contribuir, desde la perspectiva de la organización de la tecnología, al conocimiento de las ocupaciones cazadoras-recolectoras que habitaron las inmediaciones de la Sierra de la Estanzuela, en la provincia de San Luis, Argentina. Se explican cómo fueron las secuencias de producción de herramientas en los sitios de la localidad arqueológica Estancia La Suiza, a partir del análisis de los materiales líticos recuperados en excavación y prospecciones sistemáticas. Las metodologías propuestas para abordar este estudio corresponden al análisis nodular y más específicamente a una combinación del análisis tipológico y no tipológico. Los resultados permiten interpretar que en esta localidad hubo un uso diferencial del espacio, particularmente en dos sitios que son Estancia La Suiza 2 y Estancia La Suiza 3. Abstract This paper aims at gaining insight, from the angle of technological organization, into the hunter-gatherer communities that dwelled in the surrounding areas of Sierras de la Estanzuela, in the province of San Luis, Argentina. The sequence of tool development in the archaeological site of Estancia La Suiza is described from analysis of lithic materials from excavation and systematic surveys. The methods adopted for conducting this study form part of Minimal Nodule analysis (MANA and more specifically a combination of typological and non-typological analysis. Results indicate that this site evidences a differential use of space, more specifically found in Estancia La Suiza 2 and Estancia La Suiza 3. 

Elucidating the breathing of the metal-organic framework MIL-53(Sc) with ab initio molecular dynamics simulations and in situ X-ray powder diffraction experiments.

Science.gov (United States)

Chen, Linjiang; Mowat, John P S; Fairen-Jimenez, David; Morrison, Carole A; Thompson, Stephen P; Wright, Paul A; Düren, Tina

2013-10-23

Ab initio molecular dynamics (AIMD) simulations have been used to predict structural transitions of the breathing metal-organic framework (MOF) MIL-53(Sc) in response to changes in temperature over the range 100-623 K and adsorption of CO2 at 0-0.9 bar at 196 K. The method has for the first time been shown to predict successfully both temperature-dependent structural changes and the structural response to variable sorbate uptake of a flexible MOF. AIMD employing dispersion-corrected density functional theory accurately simulated the experimentally observed closure of MIL-53(Sc) upon solvent removal and the transition of the empty MOF from the closed-pore phase to the very-narrow-pore phase (symmetry change from P2(1)/c to C2/c) with increasing temperature, indicating that it can directly take into account entropic as well as enthalpic effects. We also used AIMD simulations to mimic the CO2 adsorption of MIL-53(Sc) in silico by allowing the MIL-53(Sc) framework to evolve freely in response to CO2 loadings corresponding to the two steps in the experimental adsorption isotherm. The resulting structures enabled the structure determination of the two CO2-containing intermediate and large-pore phases observed by experimental synchrotron X-ray diffraction studies with increasing CO2 pressure; this would not have been possible for the intermediate structure via conventional methods because of diffraction peak broadening. Furthermore, the strong and anisotropic peak broadening observed for the intermediate structure could be explained in terms of fluctuations of the framework predicted by the AIMD simulations. Fundamental insights from the molecular-level interactions further revealed the origin of the breathing of MIL-53(Sc) upon temperature variation and CO2 adsorption. These simulations illustrate the power of the AIMD method for the prediction and understanding of the behavior of flexible microporous solids.

Fe II/Fe III mixed-valence state induced by Li-insertion into the metal-organic-framework Mil53(Fe): A DFT+U study

Science.gov (United States)

Combelles, C.; Ben Yahia, M.; Pedesseau, L.; Doublet, M.-L.

The iron-based metal-organic-framework MIL53(Fe) has recently been tested as a cathode materials for Li-Ion batteries, leading to promising cycling life and rate capability. Despite a poor capacity of 70 mAh g -1 associated with the exchange of almost 0.5Li/Fe, this result is the first evidence of a reversible lithium insertion never observed in a MOF system. In the present study, the MIL53(Fe) redox mechanism is investigated through first-principles DFT+U calculations. The results show that MIL53(Fe) is a weak antiferromagnetic charge transfer insulator at T = 0 K, with iron ions in the high-spin S = 5/2 state. Its reactivity vs elemental lithium is then investigated as a function of lithium composition and distribution over the most probable Li-sites of the MOF structure. The redox mechanism is fully interpreted as a two-step insertion/conversion mechanism, associated with the stabilization of the Fe 3+/Fe 2+ mixed-valence state prior to the complete decomposition of the inorganic-organic interactions within the porous MOF architecture.

Factors and Problems Related to Female Genital Mutilation as Seen ...

African Journals Online (AJOL)

Objective: To determine the aetiological factors and problems related to female genital mutilation as seen in children at St. Gaspar Hospital. Data source: Secondary data were obtained from St. Gaspar Hospital, records, registers and patients files or case notes from children ward were retrieved and reviewed, later a special ...

PA171 Containers on a Wood Pallet with Metal Top Adapter, Air Pressure Tests During MIL-STD-1660 Tests

National Research Council Canada - National Science Library

2004-01-01

... (PM-MAS) to conduct Air Pressure Tests during MIL-STD-1660, "Design Criteria for Ammunition Unit Loads" testing on the PA171 containers on a wood pallet with metal top adapter as manufactured by Alliant Tech...

Tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos Tráfico vehicular y mortalidad por enfermedades del aparato circulatorio en hombres Motor vehicle traffic and cardiovascular mortality in male adults

OpenAIRE

Mateus Habermann; Nelson Gouveia

2012-01-01

OBJETIVO: Analisar a associação entre indicadores de exposição à poluição por tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos. MÉTODOS: Foram analisadas informações sobre vias e volume de tráfego no ano de 2007 fornecidas pela companhia de engenharia de tráfego local. Mortalidade por doenças do aparelho circulatório no ano de 2005 entre homens > 40 anos foram obtidas do registro de mortalidade do Programa de Aprimoramento de Informações de Mortalidade do ...

CoFe2O4@MIL-100(Fe) hybrid magnetic nanoparticles exhibit fast and selective adsorption of arsenic with high adsorption capacity

Science.gov (United States)

Yang, Ji-Chun; Yin, Xue-Bo

2017-01-01

In this study, we report the synthesis and application of mesoporous CoFe2O4@MIL-100(Fe) hybrid magnetic nanoparticles (MNPs) for the simultaneous removal of inorganic arsenic (iAs). The hybrid adsorbent had a core-shell and mesoporous structure with an average diameter of 260 nm. The nanoscale size and mesoporous character impart a fast adsorption rate and high adsorption capacity for iAs. In total, 0.1 mg L−1 As(V) and As(III) could be adsorbed within 2 min, and the maximum adsorption capacities were 114.8 mg g−1 for As(V) and 143.6 mg g−1 for As(III), higher than most previously reported adsorbents. The anti-interference capacity for iAs adsorption was improved by the electrostatic repulsion and size exclusion effects of the MIL-100(Fe) shell, which also decreased the zero-charge point of the hybrid absorbent for a broad pH adsorption range. The adsorption mechanisms of iAs on the MNPs are proposed. An Fe-O-As structure was formed on CoFe2O4@MIL-100(Fe) through hydroxyl substitution with the deprotonated iAs species. Monolayer adsorption of As(V) was observed, while hydrogen bonding led to the multi-layer adsorption of neutral As(III) for its high adsorption capacity. The high efficiency and the excellent pH- and interference-tolerance capacities of CoFe2O4@MIL-100(Fe) allowed effective iAs removal from natural water samples, as validated with batch magnetic separation mode and a portable filtration strategy. PMID:28102334

PARADOXURILE CONCEPŢIEI POLITICE ÎN OPERA LUI JEAN-JACQUES ROUSSEAU

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Alexandru MAZILU

2015-12-01

Full Text Available Ideile lui Rousseau au avut un impact major asupra societăţii la sfârşitul sec. al XVIII-lea şi pe parcursul întregii perioade a sec. al XIX-lea. Aceste idei au imprimat un suflu modern cugetului său, fiind considerat şi un ideologist politic, o voce puternică a Revoluţiei Franceze şi un pioner al curentului romantic. În legătură cu domeniul nostru de studiu, paradoxurile concepţiei politice ale lui Rousseau se referă la contradicţia dintre aspiraţiile modernităţii şi criticile violente ale progresului social. El pune accentul pe contradicţia dintre încrede-rea deplină în ,,contractul social”, ca pattern cultural şi lipsa de încredere în ,,educaţia socială”. Unicul mod de a depăşi aceste contradicţii este abordarea noului model al filosofiei educaţiei bazat pe reforme radicale pentru a facilita autodezvoltarea individului.   THE PARADOXES OF POLITICAL CONCEPTION IN THE WORK OF JEAN-JACQUES ROUSSEAUHis ideas have a big impact on the society at the end of the 18th century and the whole 19th century period. These ideas transform his spirit into a modern one, as well as a political ideologist, main voice of the French Revolution and pioneer of the Romantic Movement. Related to our article subject, Rousseau's political conceptual paradoxes refer to the contradiction between moderni-ty aspiration and the violent critic of the social progress. He emphasizes the contradiction between full trust of the "social contract", as a cultural pattern and the distrust of the "social education." The only way to leave the contradictions behind is his new education philosophy pattern based on a radical reform in order for the individual to develop himself.

Validation of MIL-F-9490D. General Specification for Flight Control System for Piloted Military Aircraft. Volume III. C-5A Heavy Logistics Transport Validation

Science.gov (United States)

1977-04-01

subjected to extreme environmental climatic tests, including the IdL,-T-5289 test requirement. 5.1.9.2 Invulnerability to Lightning Strikes and Static...specified in Paragraph 3.2.3.2.1. The hydi aulic computing elements were designed to the requirements of MIL-C- 5503 and �-H-8775. I 297 L...and climate in any area of the world using MI,- STD-210, FAA-T3O-(49C, and MIL-F-9490, as applicable. Environmental areas included solar radiation

Towards protective MOFs: post-synthetic modification of MIL-101 with oxime groups and their interactions with toxic chemicals

NARCIS (Netherlands)

Grol, M. van; Gorzkowska-Sobasb, A.A.; Koning, M.C. de

2017-01-01

In an attempt to broaden the scope of protective MOFs towards toxic compounds, we decided to introduce a reactive (nucleophilic) functionality in MIL101 by post-synthesis modification 1,2. This functionality would complement already existing adsorptive properties with an ability to capture or

MIL SPEC 28 Square Foot Fire Burnback and Extinguishment Testing of FireAde, FlameOut II and Hawk ALLFIRE

National Research Council Canada - National Science Library

Barrett, Kimberly D; Kalberer, Jennifer L

2008-01-01

... for hydrocarbon fuel fires. This report documents the evaluation performed on the fire extinguishing agents FireAde 2000 AFFF LP, FlameOut II and Hawk ALLFORE in accordance with the parameters set forth in Military Specification ( MIL SPEC...

Human papillomavirus type 16 variants in cervical intraepithelial neoplasia and invasive carcinoma in San Luis Potosí City, Mexico

Science.gov (United States)

López-Revilla, Rubén; Pineda, Marco A; Ortiz-Valdez, Julio; Sánchez-Garza, Mireya; Riego, Lina

2009-01-01

Background In San Luis Potosí City cervical infection by human papillomavirus type 16 (HPV16) associated to dysplastic lesions is more prevalent in younger women. In this work HPV16 subtypes and variants associated to low-grade intraepithelial lesions (LSIL), high-grade intraepithelial lesions (HSIL) and invasive cervical cancer (ICC) of 38 women residing in San Luis Potosí City were identified by comparing their E6 open reading frame sequences. Results Three European (E) variants (E-P, n = 27; E-T350G, n = 7; E-C188G, n = 2) and one AA-a variant (n = 2) were identified among the 38 HPV16 sequences analyzed. E-P variant sequences contained 23 single nucleotide changes, two of which (A334G, A404T) had not been described before and allowed the phylogenetic separation from the other variants. E-P A334G sequences were the most prevalent (22 cases, 57.9%), followed by the E-P Ref prototype (8 cases, 21.1%) and E-P A404T (1 case, 2.6%) sequences. The HSIL + ICC fraction was 0.21 for the E-P A334G variants and 0.00 for the E-P Ref variants. Conclusion We conclude that in the women included in this study the HPV16 E subtype is 19 times more frequent than the AA subtype; that the circulating E variants are E-P (71.1%) > E-T350G (18.4%) > E-C188G (5.3%); that 71.0% of the E-P sequences carry the A334G single nucleotide change and appear to correspond to a HPV16 variant characteristic of San Luis Potosi City more oncogenic than the E-P Ref prototype. PMID:19216802

Software support for Motorola 68000 microprocessor at CERN. M68MIL cross macro assembler

International Nuclear Information System (INIS)

Eicken, H. von.

1983-01-01

This document is a user's guide for programming the Motorola 68000 microprocessor in assembly language. It describes the programming model, addressing modes and instruction set of the M 68000 as well as the use of the M68mil cross macro assembler. Version 3.6 of the assembler has been installed at CERN on CDC, DEC VAX, IBM, Norsk Data and Siemens computers. The source code of the assembler is available from CERN on request. (orig.)

Observations on nests of Crocodylus moreletii in San Luis Potosí, Mexico Observaciones sobre nidos de Crocodylus moreletii en San Luis Potosí, México

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Armando H. Escobedo-Galván

2011-03-01

Full Text Available Nesting ecology of Morelet's crocodile (Crocodylus moreletii has been documented since 1940. However, only 2 nests constructed on floating vegetation have been recorded. Here, we presented additional information from a mainland population of C. moreletii in the Ciénega de Cabezas wetland, San Luis Potosí, describing 2 nests constructed on floating mats of cattails. The nests were constructed using Typha sp., close to the main channel. One nest was lost due to flooding, and contained 32 eggs. Seven eggs had a mean 72.6 ± 2.63 mm length (range = 70.0 -75.0 mm, 45.0 ± 2.30 mm width (range = 41.0-48.0 mm, and 140.7 ± 2.98 mm diameter (range = 136.0-145.0 mm. We suggest that the use of floating vegetation for nesting by C. moreletii is related to the availability of aquatic vegetation, combined with the lack of adequate nesting sites on land.La ecología de anidación del cocodrilo de pantano (Crocodylus moreletii ha sido documentada desde 1940. Sin embargo, sólo existen 2 registros de nidos construidos sobre vegetación acuática. Presentamos información adicional de 2 nidos (N1 y N2 construidos en este tipo de hábitat en una población ubicada en la Ciénega de Cabezas en el estado de San Luis Potosí. Los nidos fueron construidos sobre Typha sp., cerca del cauce principal de la ciénega. El N2 se perdió por inundación, en su interior encontramos 32 huevos, los promedios (± SD del largo, ancho y diámetro de 7 huevos fueron 72.6 ± 2.63 mm (rango = 70.0 -75.0 mm, 45.0 ± 2.30 mm (rango = 41.0-48.0 mm, 140.7 ± 2.98 mm (rango = 136.0-145.0 mm, respectivamente. Sugerimos que este tipo de sitios para anidar por parte de C. moreletii está relacionado con la disponibilidad de vegetación acuática, combinado con la ausencia de sitios adecuados en tierra firme.

Multiple Nebular Gas Reservoirs Recorded by Oxygen Isotope Variation in a Spinel-Rich CAI in CO3 MIL 090019

Science.gov (United States)

Simon, J. I.; Simon, S. B.; Nguyen, A. N.; Ross, D. K.; Messenger, S.

2017-07-01

We conducted NanoSIMS ion imaging studies of a primitive spinel-rich CAI from the MIL 090019 CO3 chondrite. It records radial O-isotopic heterogeneity among multiple occurrences of the same mineral, reflecting distinct nebular O-isotopic reservoirs.

A novel metal-organic framework composite MIL-101(Cr)@GO as an efficient sorbent in dispersive micro-solid phase extraction coupling with UHPLC-MS/MS for the determination of sulfonamides in milk samples.

Science.gov (United States)

Jia, Xiuna; Zhao, Pan; Ye, Xiu; Zhang, Lianjun; Wang, Ting; Chen, Qinyu; Hou, Xiaohong

2017-07-01

As a novel material, metal-organic framework/graphite oxide (MIL-101(Cr)@GO) has great potential for the pretreatment of trace analytes. In the present study, MIL-101(Cr)@GO was synthesized using a solvothermal synthesis method at the nanoscale and was applied as sorbent in the dispersive micro-solid phase extraction (DMSPE) for the enrichment of the trace sulfonamides (SAs) from milk samples for the first time. Several experimental parameters including kinds of sorbents, the effect of pH, the amount of MIL-101(Cr)@GO, ionic strength, adsorption time, desorption solvent and desorption time were investigated. Under the optimal conditions, the linear ranges were from 0.1 to 10μg/L, 0.2-20μg/L or 0.5-50μg/L for the analytes with regression coefficients (r) from 0.9942 to 0.9999. The limits of detection were between 0.012 and 0.145μg/L. The recoveries ranged from 79.83% to 103.8% with relative standard deviations (RSDs)MIL-101(Cr)@GO exhibited remarkable advantages compared to MIL-101(Cr), MIL-100(Fe), activated carbon and other sorbent materials used in pretreatment methods. A simple, rapid, sensitive, inexpensive and less solvent consuming method of DMSPE-ultra-high performance liquid chromatography-tandem mass spectrometry (DMSPE-UHPLC-MS/MS) was successfully applied to the pre-concentration and determination of twelve SAs in milk samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Ciberprens@. El medio de los ‘diez mil nombres’

Directory of Open Access Journals (Sweden)

Dr. José Álvarez Marcos

2000-01-01

Full Text Available Los chinos han traducido el significado de World Wide Web como "la red de diez mil dimensiones en el cielo y la tierra". La telaraña cibernética no sólo se ha convertido en un gigantesco hipermercado de la información, donde confluyen medios tradicionales e innovadoras propuestas comunicativas, sino que aparece como el fenómeno de mayor impacto social de los últimos años. En un mundo donde la evolución tecnológica acorta cada vez más los ciclos de la innovación, como bien señala Díaz Nosty, Internet tiene visos de consolidarse como el embrión de la primera gran solución sostenible desde que apareció la televisión, al menos en una interpretación hecha desde el campo de análisis de los medios

Indicador nacional de alfabetismo funcional-2001: explorando as diferenças entre mulheres e homens The National Index of Functional Literacy - 2001: examining the differences between men and women

Directory of Open Access Journals (Sweden)

Amélia Cristina Abreu Artes

2007-12-01

Full Text Available Este trabalho se insere em um conjunto de estudos na área educacional que investigam as diferenças nos resultados que homens e mulheres apresentam em pesquisas educacionais. O Indicador Nacional de Alfabetismo Funcional é composto por um teste com 20 questões de dificuldade variada, que mensura como as pessoas utilizam-se da escrita e da leitura em seus espaços cotidianos, tendo sido desenvolvido pelo Instituto Paulo Montenegro (IBOPE e Ação Educativa e aplicado a uma amostra estratificada da população brasileira, composta de 2.000 pessoas (15 a 64 anos. Os resultados indicam que as mulheres apresentam um resultado melhor em todas as questões do teste na comparação com os homens. Utilizando o conceito de gênero e afastando-se da dicotomia homem-mulher, trabalhou-se com três grupos ocupacionais: homens que trabalham; mulheres que trabalham fora e donas-de-casa. A análise inferencial realizada indica que as diferenças entre as proporções médias de acertos nos três grupos ocupacionais são significativas, uma vez controladas as cinco variáveis preditoras (escolaridade, idade, cor, Critério Brasil e gosto por leitura. Isso sugere que as diferenças encontradas entre os grupos independem dessas variáveis preditoras. Na análise questão a questão, observa-se que, para nove destas, as mulheres que trabalham apresentam um desempenho médio superior aos homens que trabalham ou donas-de-casa. O que mais surpreende é que em três questões as donas-de-casa apresentam um desempenho significativamente superior aos homens que trabalham.This work is part of a group of studies in the educational field that investigate the differences in the results obtained by men and women in educational researches. The National Index of Functional Literacy is composed from a test of 20 questions of varying difficulty that measure how people make use of reading and writing in their daily activities. It was developed by the Paulo Montenegro Institute

Missionary Pragmalinguistics: Father Diego Luis de Sanvitores’ grammar (1668) within the tradition of Philippine grammars

OpenAIRE

Winkler, A.P.

2016-01-01

The grammar written in Latin, in 1668, by the Jesuit missionary Father Diego Luis de Sanvitores (1627-1672) is the oldest description we have of Chamorro, a language spoken on the Mariana islands. The grammar received a number of bad reviews and as a consequence has become neglected and almost forgotten. The main point of criticism has been that Sanvitores used the Latin grammatical framework to explain a language that in many ways does not fit this framework. In this thesis it is argued inst...

On editing the fifth stanza of El aire se serena by fray Luis

Directory of Open Access Journals (Sweden)

Aquilino Suárez Pallasá

2011-12-01

Full Text Available Although many scholars and editors of the ode «El aire se serena» by fray Luis de León have denied or questioned the authenticity of its fifth stanza, there now seems to be a general assent to its acceptance. The reason for such a change of heart has not to do with textual criticism proper, but with literature. The sources of the ode are said to justify it. In this paper a strictly critico-textual demonstration of the authenticity of stanza 5 is proposed, placing emphasis on the cause of the diffraction displayed in the erroneous lectiones of a segment of the stanza.

Distribution and abundance of Least Bell’s Vireos (Vireo bellii pusillus) and Southwestern Willow Flycatchers (Empidonax traillii extimus) on the Middle San Luis Rey River, San Diego County, southern California—2017 data summary

Science.gov (United States)

Allen, Lisa D.; Howell, Scarlett L.; Kus, Barbara E.

2018-04-20

We surveyed for Least Bell’s Vireos (LBVI) (Vireo bellii pusillus) and Southwestern Willow Flycatchers (SWFL) (Empidonax traillii extimus) along the San Luis Rey River, between College Boulevard in Oceanside and Interstate 15 in Fallbrook, California (middle San Luis Rey River), in 2017. Surveys were conducted from April 13 to July 11 (LBVI) and from May 16 to July 28 (SWFL). We found 146 LBVI territories, at least 107 of which were occupied by pairs. Five additional transient LBVIs were detected. LBVIs used five different habitat types in the survey area: mixed willow, willow-cottonwood, willow-sycamore, riparian scrub, and upland scrub. Forty-four percent of the LBVIs occurred in habitat characterized as mixed willow and 89 percent of the LBVI territories occurred in areas with greater than 50 percent native plant cover. Of 16 banded LBVIs detected in the survey area, 8 had been given full color-band combinations prior to 2017. Four other LBVIs with single (natal) federal bands were recaptured and banded in 2017. Three LBVIs with single dark blue federal bands indicating that they were banded as nestlings on the lower San Luis Rey River and one LBVI with a single gold federal band indicating that it was banded as a nestling on Marine Corps Base Camp Pendleton (MCBCP) could not be recaptured for identification. One banded LBVI emigrated from the middle San Luis Rey River to the lower San Luis Rey River in 2017.One resident SWFL territory and one transient Willow Flycatcher of unknown subspecies (WIFL) were observed in the survey area in 2017. The resident SWFL territory, which was comprised of mixed willow habitat (5–50 percent native plant cover), was occupied by a single male from May 22 to June 21, 2017. No evidence of pairing or nesting activity was observed. The SWFL male was banded with a full color-combination indicating that he was originally banded as a nestling on the middle San Luis Rey River in 2014 and successfully bred in the survey area in 2016

El modelo ideal de interactividad es la conversación. Entrevista a José Luis Orihuela

Directory of Open Access Journals (Sweden)

Juan Salvador Victoria Mas

2012-04-01

Full Text Available José Luis Orihuela, "profesor universitario, conferenciante y bloguer" - tal y como él mismo se define-, habla sobre la interactividad como una potencia o una capacidad de los dispositivos (ordenadores y redes que actualiza o ejecuta el usuario en la medida en que inicia acciones que generan una respuesta por parte del sistema o de otros usuarios. Tras unas preguntas para adentrarnos en dicho concepto, Orihuela relaciona interactividad con diálogo y otros conceptos.

Experimentally determined coordinates for three MILS hydrophones near Ascension Island

International Nuclear Information System (INIS)

Harben, P.E.; Hollfelder, J.R.; Rodgers, A.J.

1999-01-01

We conducted an airgun survey in the waters of Ascension Island in May 1999 to determine new locations and depths for three Missile Impact Location System (MILS) hydrophones (ASC23, ASC24, and ASC26) currently in use by the Prototype International Data Center (PIDC) and the National Data Center (NDC). The nominal and new locations are summarized. Although not rigorous, errors in the new locations and depths are conservatively estimated to be less than 100 m. The hydrophones are either on or near the ocean bottom in all three cases. The new depths are consistent with the following: Direct-phase airgun arrivals; Bathymetry determined along the track of the ship used for this airgun survey; Reflected phases from the airgun data; Depths given in the original hydrophone installation report. (author)

Atomic Fisher information versus atomic number

International Nuclear Information System (INIS)

Nagy, A.; Sen, K.D.

2006-01-01

It is shown that the Thomas-Fermi Fisher information is negative. A slightly more sophisticated model proposed by Gaspar provides a qualitatively correct expression for the Fisher information: Gaspar's Fisher information is proportional to the two-third power of the atomic number. Accurate numerical calculations show an almost linear dependence on the atomic number

A New Destination for "The Flying Bus"?: The Implications of Orlando-Rican Migration for Luis Rafael Sanchez's "La guagua aerea"

Science.gov (United States)

Barreneche, Gabriel Ignacio; Lombardi, Jane; Ramos-Flores, Hector

2012-01-01

Puerto Rican author Luis Rafael Sanchez's "La guagua aerea" explores the duality, hybridity, and fluidity of US-Puerto Rican identity through the frequent travel of migrants between New York City (the traditional destination city for Puerto Rican migrants) and the island. In recent years, however, the "flying bus" has adopted a…

Investigation of ball bond integrity for 0.8 mil (20 microns) diameter gold bonding wire on low k die in wire bonding technology

Science.gov (United States)

Kudtarkar, Santosh Anil

Microelectronics technology has been undergoing continuous scaling to accommodate customer driven demand for smaller, faster and cheaper products. This demand has been satisfied by using novel materials, design techniques and processes. This results in challenges for the chip connection technology and also the package technology. The focus of this research endeavor was restricted to wire bond interconnect technology using gold bonding wires. Wire bond technology is often regarded as a simple first level interconnection technique. In reality, however, this is a complex process that requires a thorough understanding of the interactions between the design, material and process variables, and their impact on the reliability of the bond formed during this process. This research endeavor primarily focused on low diameter, 0.8 mil thick (20 mum) diameter gold bonding wire. Within the scope of this research, the integrity of the ball bond formed by 1.0 mil (25 mum) and 0.8 mil (20 mum) diameter wires was compared. This was followed by the evaluation of bonds formed on bond pads having doped SiO2 (low k) as underlying structures. In addition, the effect of varying the percentage of the wire dopant, palladium and bonding process parameters (bonding force, bond time, ultrasonic energy) for 0.8 mil (20 mum) bonding wire was also evaluated. Finally, a degradation empirical model was developed to understand the decrease in the wire strength. This research effort helped to develop a fundamental understanding of the various factors affecting the reliability of a ball bond from a design (low diameter bonding wire), material (low k and bonding wire dopants), and process (wire bonding process parameters) perspective for a first level interconnection technique, namely wire bonding. The significance of this research endeavor was the systematic investigation of the ball bonds formed using 0.8 mil (20 microm) gold bonding wire within the wire bonding arena. This research addressed low k

DEVELOPMENT OF A WELDING PROCEDURE FOR MIL A 46100 ARMOR STEEL JOINTS USING GAS METAL ARC WELDING

Directory of Open Access Journals (Sweden)

DAVID MAZUERA ROBLEDO

2011-01-01

Full Text Available Se desarrolló un procedimiento de soldadura (WPS para unir láminas de acero para blindaje bajo especificación MIL A46100 usando el proceso GMAW, el cual fue calificado mediante ensayos mecánicos y no destructivos (NDT de acuerdo con los requerimientos de códigos militares. Los resultados obtenidos fueron comparados con procedimientos de soldadura para este material realizados con el proceso SMAW. Los resultados obtenidos mostraron que el WPS diseñado es una opción viable para la soldadura de blindajes de acero MIL A 46100. Además, con el WPS diseñado se obtuvo una reducción en el ancho de la zona afectada térmicamente (ZAT que debería conducir a un mejor desempeño en servicio de los blindajes de acuerdo con los resultados de estudios previos. Finalmente, se encontró un incremento en la energía absorbida en los ensayos de impacto Charpy V comparada con la de soldaduras realizadas con el proceso SMAW.

Impacto da vacinação contra influenza na mortalidade por doenças respiratórias em idosos

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Priscila Maria Stolses Bergamo Francisco

2005-01-01

Full Text Available OBJETIVO: As doenças respiratórias, particularmente as infecciosas, vêm se tornando cada vez mais representativas na morbi-mortalidade da população idosa. O objetivo do estudo foi analisar a tendência de mortalidade por doenças respiratórias e observar o impacto da vacinação contra influenza nos coeficientes de mortalidade. MÉTODOS: O estudo foi realizado no período de 1980 a 2000 em idosos residentes no Estado de São Paulo, utilizando-se dados de mortalidade do Sistema de Informações de Mortalidade do Ministério da Saúde. Trata-se de estudo ecológico de séries temporais. Foram analisadas as tendências das taxas padronizadas de mortalidade por doenças respiratórias infecciosas, segundo faixas etárias (60 a 64, 65 a 69, 70 a 74, 75 a 79 e 80 ou mais anos e sexo, por meio de modelos de regressão polinomial. Foram calculados intervalos de confiança para a resposta média esperada nos anos subseqüentes à intervenção. RESULTADOS: Os coeficientes aumentaram para ambos os sexos na população idosa. Após a intervenção nota-se tendência ao declínio dos indicadores de mortalidade. Para a população idosa masculina, o coeficiente médio no período de 1980 a 1998 foi de 5,08 óbitos por mil homens com aumento linear não constante de 0,13 ao ano; em 2000, o coeficiente observado foi de 4,72 óbitos por mil homens. Já para as mulheres de 60 anos e mais, o coeficiente anual médio foi de 3,18 óbitos por mil mulheres com incremento não constante de 0,08 ao ano; no ano de 2000 o coeficiente observado foi 2,99 óbitos por mil mulheres, além da redução significativa dos mesmos em todas as faixas etárias. CONCLUSÕES: Os dados indicam a importância das doenças respiratórias entre os idosos e sugerem que a proteção específica contra influenza tem se refletido positivamente na prevenção da mortalidade por essas doenças.

Pyrolytic in situ magnetization of metal-organic framework MIL-100 for magnetic solid-phase extraction.

Science.gov (United States)

Huo, Shu-Hui; An, Hai-Yan; Yu, Jing; Mao, Xue-Feng; Zhang, Zhe; Bai, Lei; Huang, Yan-Feng; Zhou, Peng-Xin

2017-09-29

In this study, we report a facile, environmental friendly fabrication of a type of magnetic metal-organic framework (MOF) MIL-100 that can be used for magnetic solid-phase extraction (MSPE). The magnetic MOF composites were fabricated using in situ calcination method. The as-synthesized materials exhibited both high porosity and magnetic characteristics. They used for the MSPE of polycyclic aromatic hydrocarbons (PAHs) from water samples. Such MOF-based magnetic solid-phase extraction in combination with gas chromatography equipped with a flame ionization detector (GC-FID), exhibited wide linearity (0.02-250μgL -1 ), low detection limits (4.6-8.9ngL -1 ), and high enrichment factors (452-907) for PAHs. The relative standard deviations (RSDs) for intra- and inter-day extractions of PAHs were ranging from 1.7% to 9.8% and 3.8% to 9.2%, respectively. The recoveries for spiked PAHs (1μgL -1 ) in water samples were in the range of 88.5% to 106.6%. The results showed that the special anion-π orbital (electron donor-acceptor) interaction and π-π stacking between magnetic MIL-100 and PAHs play an important role in the adsorption of PAHs. Copyright © 2017. Published by Elsevier B.V.

Luis Fayad. Dalla narrativa urbana agli innesti socioculturali. Presentazione

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Martha L. Canfield

2013-03-01

Full Text Available The article looks at Luis Fayad’s novel La caída de los puntos cardinales (2000 in order to foreground the influence of Arabic on the Colom- bian author whose grandparents were Lebanese. Born in Bogotá in 1945, Fayad published the novel after being identified as one of the first Colombian novelists dealing with urban literature. It represents a change of direction in his career, as Fayad narrates the entire life of six main characters, four men and two women, who decide to leave Lebanon and migrate to South America, ending up in Colombia. The analysis will focus on the importance of the circulation of the book in Italy by virtue of issues of intercultural exchange embedded in the novel. La caída de los puntos cardinales mixes Arabic tradition and Colombian customs; in the novel, Fayad achieves a cross-cultural story that may provide a successful model of integration. The Spanish-Italian translation and a critical approach to the language used by the novelist and employed by the translator will complete the essay.

Salen- Zr(IV) complex grafted into amine-tagged MIL-101(Cr) as a robust multifunctional catalyst for biodiesel production and organic transformation reactions

Science.gov (United States)

Hassan, Hassan M. A.; Betiha, Mohamed A.; Mohamed, Shaimaa K.; El-Sharkawy, E. A.; Ahmed, Emad A.

2017-08-01

The synthesis of metal-organic frameworks (MOFs), porous coordination polymers with functional groups has received immense interest due to the functional groups can offer desirable properties and allow post-synthetic modification. Herein, for the first time, Zr(IV)-Sal Schiff base complex incorporated into amino-functionalized MIL-101(Cr) framework by salicylaldehyde condensing to amino group, and coordinating Zr(IV) ion have been successfully synthesized. The worthiness of the synthesized material as a catalyst has been examined for the esterification of oleic acid (free fatty acid) with methanol producing biodiesel (methyl oleate), Knoveonagel condensation reaction of aldehydes and Friedel-Crafts acylation of anisole. Our findings demonstrated that Salen-Zr(IV) grafted to framework of NH2-MIL-101(Cr) as a solid acid catalyst exhibited distinct catalytic performance for the production of biodiesel by esterification of oleic acid with methanol, Knoveonagel condensation and Friedel-Crafts acylation. These could be attributed to high surface area which allow high distribution of Zr(IV) species lead to a sufficient contact with the reactants species. Furthermore, the catalyst showed excellent recycling efficiency due to the strong interaction between the Zr(IV) ions and chelating groups in the NH2-MIL-101(Cr)-Sal.

Survey of the University "Luis Vargas Torres" through Econometric Techniques. Comprehensive Income

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Ramón Rodríguez-Betancourt

2015-12-01

Full Text Available Government Programme 2013-2017 defines in higher education, the principles of the curriculum proposals of much public interest careers. In this regard the authorities of the Technical University "Luis Vargas Torres" of Esmeraldas, have taken the decision to evaluate its management and action against the development of the province and the country. Therefore, the objective of this research is the application of a survey of students of different specialties, Faculty of Engineering and Technology to explore their views on the educational process, research, outreach, culture and sport, stratified random sampling with results showing that key processes are completed by 66% on average is applied, indicating that the authority still has to set goals to overcome the short comings that have an emphasis on research.

Superinfection between Influenza and RSV Alternating Patterns in San Luis Potosí State, México

Science.gov (United States)

Velasco-Hernández, Jorge Xicoténcatl; Núñez-López, Mayra; Comas-García, Andreu; Cherpitel, Daniel Ernesto Noyola; Ocampo, Marcos Capistrán

2015-01-01

The objective of this paper is to explain through the ecological hypothesis superinfection and competitive interaction between two viral populations and niche (host) availability, the alternating patterns of Respiratory Syncytial Virus (RSV) and influenza observed in a regional hospital in San Luis Potosí State, México using a mathematical model as a methodological tool. The data analyzed consists of community-based and hospital-based Acute Respiratory Infections (ARI) consultations provided by health-care institutions reported to the State Health Service Epidemiology Department from 2003 through 2009. PMID:25803450

Infección congénita por citomegalovirus en recién nacidos del estado de San Luis Potosí, México Congenital cytomegalovirus infection in newborn infants from the state of San Luis Potosí, Mexico

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Daniel E Noyola

2011-12-01

Full Text Available OBJETIVO: Determinar la prevalencia de infección congénita por citomegalovirus en recién nacidos participantes en el programa de tamiz neonatal de los Servicios de Salud de San Luis Potosí. MATERIAL Y MÉTODOS: Se evaluó la presencia de citomegalovirus en muestras de sangre almacenadas en papel filtro. RESULTADOS. Se detectó la presencia de citomegalovirus en 10 (0.68% de 1 457 muestras estudiadas. No se encontraron diferencias en las características de los recién nacidos con infección congénita en comparación con aquéllos sin infección. CONCLUSIONES: Es necesario concientizar a los profesionales de la salud sobre la prevalencia e impacto de la infección congénita por citomegalovirus.OBJECTIVE: To determine the prevalence of congenital cytomegalovirus infection in newborn infants included in the neonatal screening program coordinated by the State Health Services in San Luis Potosí. MATERIAL AND METHODS: We evaluated the presence of cytomegalovirus in blood samples stored in filter paper. RESULTS: Cytomegalovirus was detected in 10 (0.68% of the 1 457 samples included in the study. There were no differences in the characteristics of infants with congenital infection compared to those without infection. CONCLUSIONS: It is necessary to increase awareness of health professionals regarding the prevalence and impact of congenital cytomegalovirus infection.

Mise en place d'une collection de ressources génétiques du mil ...

African Journals Online (AJOL)

Le mil est une céréale importante pour l'alimentation humaine. La Côte d'Ivoire représente un des centres de production et de consommation. Afin de collecter, conserver et étudier les variabilités existantes, une seconde mission a été effectuée dans les zones de culture de cette céréale en 1989 et 1990, faisant suite à la ...

"Non qua servus est, sed qua homo." Der rechtliche Status von Sklaven bei Luis de Molina

OpenAIRE

Simmermacher, Danaë

2014-01-01

Luis de Molina (1535-1600) grants slaves a legal status through which they can take up a position with respect to their masters between equivalent legal entity and legal object. Here, what is decisive is the figure of the subjective right, which both for Molina and modern proponents of this legal concept describes the 'right per se'. According to Molina's definition of ius, the denial of a subjective right or the hindrance of exercising an individual right represents an injustice. The rights ...

Brote de encefalitis de San Luis en el Área Metropolitana Buenos Aires Outbreack of St. Luis encephalitis in the Metropolitan Buenos Aires Area

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Alfredo Seijo

2011-06-01

Full Text Available Se describen los hallazgos epidemiológicos y clínicos de 13 enfermos con diagnóstico de infección por virus de la encefalitis de San Luis, con transmisión entre enero y marzo de 2010, en el Area Metropolitana Buenos Aires (AMBA. Los 13 enfermos, promedio de edad 38 años, tuvieron un comienzo agudo caracterizado por hipertermia y cefalea. Entre los días dos y diez de iniciados los síntomas, 7/13 enfermos tuvieron signos y síntomas de compromiso neurológico caracterizado por meningitis sin signos encefálicos en 1/7. En 6/7 los hallazgos más frecuentes fueron: rigidez de nuca, desorientación temporoespacial, fotofobia, confusión y alteración del lenguaje. Dos resonancias magnéticas y un electroencefalograma presentaron signos de afectación de lóbulos temporales. El líquido cefalorraquídeo se caracterizó por pleocitosis con predominio de células mononucleadas, glucorraquia normal y discreto aumento de proteínas. No hubo casos fatales. En 6/13 pacientes la sospecha clínica inicial fue dengue. Por la agrupación espacial y temporal de los casos puede considerarse un brote epidémico, el primero conocido en el AMBA, ya que no se había notificado previamente la circulación epidémica del virus.We describe the epidemiological and clinical findings of 13 patients with diagnosis of infection by St. Louis encephalitis virus, transmitted between January and March 2010 in Buenos Aires Metropolitan Area (AMBA. Thirteen patients, average age 38 years, had an acute onset with hyperthermia and headache. Between days two and ten of the onset of symptoms, 7/13 patients had signs and symptoms of neurological involvement. This was characterized by meningitis without encephalic sings in 1/7 and in 6/7 the most frequent findings were: stiff neck, disorientation, photophobia, confusion and language impairment. Two MR and one EEG revealed signs of involvement of temporal lobes. The cerebrospinal fluid showed pleocytosis with predominance of

Aging method for electronic components and systems based on MIL-HDBK 217

International Nuclear Information System (INIS)

Declercq, M.; Simoens, F.

1984-01-01

Accelerated aging tests as requested to comply IEEE Std 323-1974, rise the question of the availability of an adequate aging model. After getting through the usual models, the authors describe an aging methodology based on MIL-HDBK 217. The method, taking into account several stress factors, is shown to yield on acceptable acceleration of time, while reducing the relative importance of temperature. Practical implementation of acceleration testing is discussed, and a summary of the gained experience is made and discussed in the scope of the philosophy of IEEE Std 650. Only natural thermal aging and functional aging, excluding irradiation or thermal shocks, are considered [fr

Abastecimento futuro da água potável abate, análise espacial e da vulnerabilidade da cidade de san luis potosi, méxico

OpenAIRE

Contreras Servín, Carlos; Galindo Mendoza, María Guadalupe

2009-01-01

O presente artigo discute e apresenta as condições físicas, sociais e económicas que afectam a imagem global e os problemas actuais respeito ao abastecimento de água potável da região metropolitana de San Luis Potosi. Entre os temas a abordar está a relação entre disponibilidade hídrica e aumento da população, bem como a evolução de extração de águas subterrâneas. Além disso, a pesquisa mostra um diagnóstico da situação actual de abastecimento de água potável em San Luis Potosi e áreas circun...

Ampliación de la distribución de Teius oculatus y T. suquiensis (Sauria: Teiidae en la provincia de San Luis (República Argentina

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Guerreiro, Analía C.

1998-01-01

Full Text Available Teius oculatus (D'Orbigny & Bibron, 1837. Dpto. La Capital. Localidades: Daniel Donovan (33°21'S; 66°15'W UNSUCH 0098; Ciudad de San Luis (33°18'S; 66°22'W UNSL-CH 0132, 0137. Teius suquiensis Avila & Martori, 1991. Dpto. La Capital. Localidades: Daniel Dono- van, UNSL-CH 0095, 0097, 0230; Ciudad de San Luis, UNSL-CH 0118, 0120, 0141, 0172, 0214, 0221; Ruta Prov. 3 (33°15'S; 66°18'W, UNSL-CH 0231, 0232. Dpto. Cnel. Pringles: La Florida (33°08'S; 66°02'W UNSL-CH 0223. Colectores: Juan Cruz Baldoni, Ana María Brigada, Matías García, Analía C. Guerreiro y Flavio Martínez.

Inventario de recursos turísticos como base para la planificación territorial en la zona altiplano de san Luis Potosi, México

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Paloma Blanco López

2015-01-01

Full Text Available Este artículo aborda el análisis del potencial turístico como condición para la planificación turística. Se explica el turismo como factor de desarrollo y a la planificación como instrumento de su gestión. Se utilizan los municipios con mayor potencial turístico en la Zona Altiplano de San Luis Potosí para exponer y ejemplificar los resultados del diagnóstico de la región. Después se evalúan los instrumentos vigentes de planificación turística vigentes en San Luis Potosí y se ofrece una propuesta de aprovechamiento turístico con ayuda de un análisis FODA para los municipios seleccionados.

Innovations in Stream Restoration and Flood Control Design Meeting Flood Capacity and Environmental Goals on San Luis Obispo Creek

Science.gov (United States)

Wayne Peterson

1989-01-01

Can a natural flowing creek be increased in drainage capacity to protect an adjacent community from flooding while still maintaining a natural habitat? San Luis Obispo constructed one such project on over a mile of Creek as a part of a housing development. The City found that some of the mitigation measures included in the project worked while others did not. In the...

Fabrication of γ-Fe2O3 Nanoparticles by Solid-State Thermolysis of a Metal-Organic Framework, MIL-100(Fe, for Heavy Metal Ions Removal

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Shengtao Hei

2014-01-01

Full Text Available Porous γ-Fe2O3 nanoparticles were prepared via a solid-state conversion process of a mesoporous iron(III carboxylate crystal, MIL-100(Fe. First, the MIL-100(Fe crystal that served as the template of the metal oxide was synthesized by a low-temperature (<100°C synthesis route. Subsequently, the porous γ-Fe2O3 nanoparticles were fabricated by facile thermolysis of the MIL-100(Fe powders via a two-step calcination treatment. The obtained γ-Fe2O3 was characterized by X-ray diffraction (XRD, N2 adsorption, X-ray photoelectron spectroscopy (XPS, and scanning electron microscopy (SEM techniques, and then used as an adsorbent for heavy metal ions removal in water treatment. This study illustrates that the metal-organic frameworks may be suitable precursors for the fabrication of metal oxides nanomaterials with large specific surface area, and the prepared porous γ-Fe2O3 exhibits a superior adsorption performance for As(V and As(III ions removal in water treatment.

Álcool e violência em homens e mulheres Alcohol: gender and implications in the violence

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Rosa Maria Martins de Almeida

2009-01-01

Full Text Available O uso nocivo do álcool configura-se como um problema de saúde pública, associado ao aumento da violência, envolvendo ambos os sexos. Esse artigo tem por objetivo discutir sobre o impacto do uso do álcool em homens e mulheres do ponto de vista neurobiológico, enfatizando a ação psicoativa da substância e sua implicação no comportamento violento. Foi conduzida uma análise baseada em artigos selecionados nas fontes eletrônicas do Scielo, LILACS, MEDLINE, PubMed e Web of Science no período de 1996 a 2008. Do total de 420 artigos selecionados, 90 foram considerados relevantes para a análise. Verificou-se que o uso nocivo do álcool causa mudanças neuroquímicas e alterações nas funções cognitivas, podendo gerar comportamentos violentos em homens e mulheres, entretanto, evidenciou-se importantes diferenças entre os sexos quanto à ação psicoativa do álcool, assim como, no tipo de violência expressa. Estudos sobre a temática proposta ainda são escassos, sugerindo a necessidade de pesquisas futuras que possam contribuir para um melhor entendimento e para ações preventivas eficazes.The abuse of alcohol can engender serious public health problems in certain people, particularly due to its link to violence involving both men and women. This article has the aim to discuss the impact of alcohol in men and women regarding neurobiological mechanisms, emphasizing its psychoactive effects as well as its implication for violent behavior. An analysis was conduct based on reviews and articles in electronic databases, selected from 1996 to 2008 at Scielo, Lilacs, MEDLINE, Pub Med and Web of Science. From a total of 420 selected articles 90 were considered relevant for this analysis. It was evident that the abuse of alcohol causes changes in neurochemistry and in cognitive functions, and some of those changes lead to violent behavior in men and women. However, there are important differences between both genders and the type of aggressive

Tectonic Implications of Changes in the Paleogene Paleodrainage Network in the West-Central Part of the San Luis Basin, Northern Rio Grande Rift, New Mexico and Colorado, USA

Science.gov (United States)

Thompson, R. A.; Turner, K. J.; Cosca, M. A.; Drenth, B.

2016-12-01

The San Luis Basin is the largest of extensional basins in the northern Rio Grande rift (>11,400 km2). The modern basin configuration is the result of Neogene deformation that has been the focus of numerous studies. In contrast, Paleogene extensional deformation is relatively little studied owing to a fragmentary or poorly exposed stratigraphic record in most areas. However, volcanic and volcaniclastic deposits exposed along the western margin of the basin provide the spatial and temporal framework for interpretation of paleodrainage patterns that changed in direct response to Oligocene basin subsidence and the migration of centers of Tertiary volcanism. The early Oligocene (34 to 30 Ma) drainage pattern that originated in the volcanic highlands of the San Juan Mountains flowed south into the northern Tusas Mountains. A structural and topographic high composed of Proterozoic rocks in the Tusas Mountains directed flow to the southeast at least as late as 29 Ma, as ash-flow tuffs sourced in the southeast San Juan Mountains are restricted to the north side of the paleohigh. Construction of volcanic highlands in the San Luis Hills between 30 and 28.5 Ma provided an abundant source of volcanic debris that combined with volcanic detritus sourced in the southeast San Juan Mountains and was deposited (Los Pinos Formation) throughout the northern Tusas Mountains progressively onlapping the paleotopographic high. By 29 Ma, subsidence of the Las Mesitas graben, a structural sub-basin, between the San Luis Hills and the southeast San Juan and northern Tusas Mountains is reflected by thick deposits of Los Pinos Formation beneath 26.5 Ma basalts. Regional tectonism responsible for the formation of the graben may have also lowered the topographic and structural high in the Tusas Mountains, which allowed development of a southwest-flowing paleodrainage that likely flowed onto the Colorado Plateau. Tholeiitic basalt flows erupted in the San Luis Hills at 25.8 Ma, that presently cap

Genetic diversity of the Mycobacterium tuberculosis complex in San Luis Potosí, México.

Science.gov (United States)

López-Rocha, Estela; Juárez-Álvarez, Julio; Riego-Ruiz, Lina; Enciso-Moreno, Leonor; Ortega-Aguilar, Francisco; Hernández-Nieto, Julián; Enciso-Moreno, José A; López-Revilla, Rubén

2013-05-01

Although epidemiologic and socioeconomic criteria and biomedical risk factors indicate high-priority for tuberculosis (TB) control in Mexico, molecular epidemiology studies of the disease in the country are scarce. Complete sociodemographic and clinical data were obtained from 248 of the 432 pulmonary TB (PTB) cases confirmed from 2006 to 2010 on the population under epidemiological surveillance in the state of San Luis Potosí, México. From most PTB cases with complete data Mycobacterium tuberculosis complex (MTC) isolates were recovered and their spoligotypes, lineages and families, geographic distribution and drug resistance determined. Pulmonary tuberculosis incidence ranged from 2.4 to 33.4 (cases per 100,000 inhabitants) in the six state sanitary jurisdictions that were grouped in regions of low (jurisdictions I-II-III), intermediate (jurisdictions IV-V) and high incidence (jurisdiction VI) with 6.2, 17.3 and 33.4 rates, respectively. Most patients were poor, 50-years-median-age males and housewives. Among the 237 MTC spoligotyped isolates, 232 corresponded to M. tuberculosis (104 spoligotypes in 24 clusters) and five to M. bovis. The predominant Euro-American lineage was distributed all over the state, the East-Asian lineage (Beijing family) in the capital city, the Indo-Oceanic (Manila family) in eastern localities, and M. bovis in rural localities. In San Luis Potosí TB affects mainly poor male adults and is caused by M. tuberculosis and to a minor extent by M. bovis. There is great genotypic diversity among M. tuberculosis strains, the Euro-American lineage being much more prevalent than the Indo-Oceanic and East-Asian lineages. The frequency of resistant strains is relatively low and not associated to any particular lineage.

ENHANCEMENT OF ACIDITY AND CATALYTIC ACTIVITY OF ALUMINA BASED METAL ORGANIC FRAMEWORK (MIL-53 Al)

OpenAIRE

Yilmaz, Esra; Sert, Emine; Atalay, Ferhan Sami

2017-01-01

Metal organic frameworks are highly porous materials which are formed bycombination of metal precursor and salts as inorganic part and ligand asorganic part. They have many advantages such as low density, high surface area,tunable pore size and high porosity. Due to peculiar features, such asunsaturated metal active sites, high surface area and easily functionalization,its usage as catalyst are promising.  The MIL-53(Al) structure contains chains of transcorner-sharing [AlO4(OH)2] oc...

Contradictions porteñas: modernity, modernism and modernization in Jorge Luis Borges during the 1920’s

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Pedro Demenech

2013-06-01

Full Text Available The aim of the article is discuss the concepts of modernity, modernism and modernization from the propositions raised by Marshal Berman and Néstor García Canclini. The fierce transformation of Buenos Aires during the 1920’s will be the focus of the analysis. To this end, we use the work of argentine poet Jorge Luis Borges to comprehend the development of these processes in the urban space of Buenos Aires.

Prevalência de hipertensão arterial sistêmica e fatores associados em homens e mulheres residentes em municípios da Amazônia Legal

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Elcimary Cristina Silva

2016-03-01

Full Text Available RESUMO: Introdução: A hipertensão arterial sistêmica é um importante problema de saúde pública devido à sua alta prevalência, baixas taxas de controle e causa de morbidade e mortalidade cardiovascular. Objetivo: Analisar a prevalência de hipertensão arterial sistêmica e fatores associados em homens e mulheres residentes em municípios da Amazônia Legal. Métodos: No estudo transversal de base populacional conduzido com 1.296 adultos de ambos os sexos foram coletados dados sociodemográficos, estilo de vida, antropométricos e pressão arterial, sendo considerados hipertensos os que apresentaram pressão arterial ≥ 140/90 mmHg e/ou os que referiram uso de drogas anti-hipertensivas. As análises estatísticas foram feitas no módulo survey do programa Stata versão 11.0. Resultados: A prevalência da hipertensão arterial sistêmica foi de 22,3%. Após ajustes, as variáveis que se associaram à hipertensão nos homens foram a idade de 30 a 39 anos (RP ajustada = 2,69; IC95% 1,49 - 4,86, 40 a 49 anos (RP ajustada = 3,28; IC95% 1,82 - 5,93 e 50 a 59 anos (RP ajustada = 4,80; IC95% 2,63 - 8,76, sobrepeso (RP ajustada = 1,97; IC95% 1,39 - 2,78, obesidade (RP ajustada = 3,32; IC95% 2,32 - 4,75 e ser natural da região Norte ou Nordeste (RP ajustada = 0,31; IC95% 0,18 - 0,59. Entre as mulheres, associaram à hipertensão a idade de 40 a 49 anos (RP ajustada = 3,41; IC95% 1,91 - 6,07 e 50 a 59 anos (RP ajustada = 7,29; IC95% 4,07 - 13,07; o consumo de vinho (RP ajustada = 0,31; IC95% 0,10 - 0,97 e obesidade (RP ajustada = 2,39; IC95% 1,65 - 3,45. Conclusão: A hipertensão arterial associou-se independentemente com a idade, estado nutricional e naturalidade nos homens. E nas mulheres com a idade, estado nutricional e tipo de bebida alcoólica.

Saber mirar, saber contar. La narrativa cinematográfica de José Luis Borau

OpenAIRE

Mérida Donoso, José Antonio

2018-01-01

Tesis doctoral inédita leída en la Universidad Autónoma de Madrid, Facultad de Filosofía y Letras, Departamento de Filología Española. Fecha de lectura: 29-9-2017 La presente tesis doctoral se adentra en una de las figuras fundamentales de la historia del cine español, José Luis Borau. Para ello se analiza su cine desde una perspectiva textual, atendiendo al emisor, el receptor, el contexto –de producción y sociopolítico- y el texto fílmico. Bajo este prisma se ofrece una visión del estilo...

Consequências da vasectomia: experiência de homens que se submeteram à cirurgia em Campinas (São Paulo, Brasil Consequences of vasectomy: experience of men who underwent the surgery in Campinas (São Paulo, Brazil

Directory of Open Access Journals (Sweden)

Nádia Maria Marchi

2011-09-01

Full Text Available OBJETIVO: Descrever a experiência de homens vasectomizados há pelo menos um ano em serviços públicos de saúde de Campinas, Estado de São Paulo. Procedimentos metodológicos: estudo descritivo com um componente qualitativo e outro quantitativo. Para a etapa qualitativa, realizaram-se 10 entrevistas semiestruturadas com homens selecionados de acordo com critérios propositais de escolaridade e número de filhos. Em seguida, foi aplicado um formulário estruturado a 202 homens, sorteados a partir da lista completa daqueles que haviam sido vasectomizados entre 1998 e 2004. Realizou-se análise temática do conteúdo das entrevistas semiestruturadas. Os dados quantitativos foram digitados e foi realizada análise descritiva. RESULTADOS: Observou-se que 97% dos homens estavam satisfeitos por terem feito a cirurgia e poucos referiram efeitos indesejados. Entre os poucos homens insatisfeitos, apenas um havia feito a reversão da cirurgia porque vivia com uma nova companheira e queria ter filhos; entre os demais a insatisfação devia-se à dor provocada pelo procedimento cirúrgico. A maioria dos entrevistados atribuiu à vasectomia mudanças para melhor sobre sua saúde, corpo, relacionamento em geral com a família e com a esposa, na vida sexual e na situação econômica. Prevaleceu a ideia de que a vasectomia só trouxera benefícios. A possibilidade de arrependimento foi mencionada pelos entrevistados como algo que não aconteceria com eles. CONCLUSÃO: Os resultados deste estudo permitiram verificar que os homens que optam pela vasectomia tendem a ver o método como fator de mudanças positivas, principalmente sobre a vida sexual e o relacionamento com a companheira e a família em geral.OBJECTIVE: To describe the experience of men who had a vasectomy at least one year before at public healthcare services at Campinas, State of São Paulo. Methodological procedures: descriptive study with a qualitative and a quantitative component. In the

Potential human health risk by 234,238U and 210Po due to consumption of fish from the "Luis L. Leon" reservoir (Northern Mexico)

Science.gov (United States)

Luna-Porres, M. Y.; Rodríguez-Villa, M. A.; Herrera-Peraza, E.; Cabral-Lares, M.; Renteria-Villalobos, M.; Montero-Cabrera, M. E.

2014-07-01

The Conchos River is one of the most important in northern Mexico and the main surface waterway in the arid state of Chihuahua. The Luis L. Leon dam produces the Luis L. Leon Reservoir, which is the last major reservoir before the Conchos River enters the Rio Grande at the Texas-Chihuahua border. Activity concentrations (AC) of 234,238U and 210Po in fillet and liver of three stocked fish species (Lepomis cyanellus, Cyprinus carpio and Ictalurus furcatus), as well as in water from the Luis L. Leon reservoir were determined. 238U and 234U ACs in fillet samples showed values of 0.007-0.014 and 0.01-0.02 Bq kg-1 wet weight (ww), respectively. Liver samples for Lepomis cyanellus, Cyprinus carpio and Ictalurus furcatus species, present 210Po AC of 1.16-3.26 0.70-1.13 and 0.93-1.37 Bqṡkg-1 ww. The elemental Bioaccumulation Factor (BAF) for fish tissues respect to their concentrations in water was determined. Lepomis cyanellus species showed the highest BAF for total uranium in fillet, with value 1.5. The annual effective dose for uranium in adults by fish consumption in this work ranged from 4.46×10-3 to 3.68×10-2 μSvṡyear-1. The difference in concentrations of uranium in fillet among the studied species is likely primarily due to their differences in diet and habitat.

The MIL-88A-Derived Fe3O4-Carbon Hierarchical Nanocomposites for Electrochemical Sensing

Science.gov (United States)

Wang, Li; Zhang, Yayun; Li, Xia; Xie, Yingzhen; He, Juan; Yu, Jie; Song, Yonghai

2015-01-01

Metal or metal oxides/carbon nanocomposites with hierarchical superstructures have become one of the most promising functional materials in sensor, catalysis, energy conversion, etc. In this work, novel hierarchical Fe3O4/carbon superstructures have been fabricated based on metal-organic frameworks (MOFs)-derived method. Three kinds of Fe-MOFs (MIL-88A) with different morphologies were prepared beforehand as templates, and then pyrolyzed to fabricate the corresponding novel hierarchical Fe3O4/carbon superstructures. The systematic studies on the thermal decomposition process of the three kinds of MIL-88A and the effect of template morphology on the products were carried out in detail. Scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy and thermal analysis were employed to investigate the hierarchical Fe3O4/carbon superstructures. Based on these resulted hierarchical Fe3O4/carbon superstructures, a novel and sensitive nonenzymatic N-acetyl cysteine sensor was developed. The porous and hierarchical superstructures and large surface area of the as-formed Fe3O4/carbon superstructures eventually contributed to the good electrocatalytic activity of the prepared sensor towards the oxidation of N-acetyl cysteine. The proposed preparation method of the hierarchical Fe3O4/carbon superstructures is simple, efficient, cheap and easy to mass production. It might open up a new way for hierarchical superstructures preparation. PMID:26387535

Predicting arsenic concentrations in groundwater of San Luis Valley, Colorado: implications for individual-level lifetime exposure assessment.

Science.gov (United States)

James, Katherine A; Meliker, Jaymie R; Buttenfield, Barbara E; Byers, Tim; Zerbe, Gary O; Hokanson, John E; Marshall, Julie A

2014-08-01

Consumption of inorganic arsenic in drinking water at high levels has been associated with chronic diseases. Risk is less clear at lower levels of arsenic, in part due to difficulties in estimating exposure. Herein we characterize spatial and temporal variability of arsenic concentrations and develop models for predicting aquifer arsenic concentrations in the San Luis Valley, Colorado, an area of moderately elevated arsenic in groundwater. This study included historical water samples with total arsenic concentrations from 595 unique well locations. A longitudinal analysis established temporal stability in arsenic levels in individual wells. The mean arsenic levels for a random sample of 535 wells were incorporated into five kriging models to predict groundwater arsenic concentrations at any point in time. A separate validation dataset (n = 60 wells) was used to identify the model with strongest predictability. Findings indicate that arsenic concentrations are temporally stable (r = 0.88; 95 % CI 0.83-0.92 for samples collected from the same well 15-25 years apart) and the spatial model created using ordinary kriging best predicted arsenic concentrations (ρ = 0.72 between predicted and observed validation data). These findings illustrate the value of geostatistical modeling of arsenic and suggest the San Luis Valley is a good region for conducting epidemiologic studies of groundwater metals because of the ability to accurately predict variation in groundwater arsenic concentrations.

Comportamento da pressão arterial em homens pré-hipertensos participantes em um programa regular de natação

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Jairo Eleotério da Silva

2015-06-01

Full Text Available INTRODUÇÃO: A natação tem sido recomendada como tipo de atividade física para a prevenção, tratamento e controle da hipertensão arterial. OBJETIVO: Analisar os efeitos da prática regular de natação sobre a pressão arterial de adultos pré-hipertensos. MÉTODOS: A amostra foi composta por 36 homens pré-hipertensos divididos em dois grupos: Experimental - GE (n=24, 40,60±9,36 anos e Controle - GC (n=12, 40,57±8,05 anos. O GE realizou um programa regular de natação, com três sessões semanais de 45 min, durante 12 semanas, enquanto o GC não alterou seus hábitos alimentares e permaneceu sem praticar atividade física no período. O procedimento estatístico utilizado para verificar as diferenças entre as médias antes e depois de 12 semanas do programa regular de natação foi o teste-t de Student. O estudo admitiu o nível de p < 0.05 para a significância estatística. RESULTADOS: O grupo GE apresentou diferenças estatisticamente significativas nas variáveis analisadas quando comparadas com o GC, tanto na pressão arterial sistólica, PAS (Δ = - 5,89 mmHg, p = 0,00, como na pressão arterial diastólica, PAD (Δ = - 5,15mmHg, p = 0,00. CONCLUSÃO: Os resultados mostram que um programa regular de natação provoca reduções significativas na pressão arterial em repouso em homens pré-hipertensos.

Synthesis, characterization and sorption properties of functionalized Cr-MIL-101-X (X=–F, –Cl, –Br, –CH{sub 3}, –C{sub 6}H{sub 4}, –F{sub 2}, –(CH{sub 3}){sub 2}) materials

Energy Technology Data Exchange (ETDEWEB)

Buragohain, Amlan [Department of Chemistry, Indian Institute of Technology Guwahati, 781039 Assam (India); Couck, Sarah [Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels (Belgium); Van Der Voort, Pascal [Department of Inorganic and Physical Chemistry, Ghent University, COMOC – Center for Ordered Materials, Organometallics and Catalysis, Krijgslaan 281-S3, 9000 Ghent (Belgium); Denayer, Joeri F.M. [Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels (Belgium); Biswas, Shyam, E-mail: sbiswas@iitg.ernet.in [Department of Chemistry, Indian Institute of Technology Guwahati, 781039 Assam (India)

2016-06-15

Four existing and three new functionalized chromium terephthalates having MIL-101 topology and denoted as Cr-MIL-101-X (existing ones with X=–F, 1-F; –Cl, 2-Cl; –Br, 3-Br; –CH{sub 3}, 4-CH{sub 3}; new ones with X=–C{sub 6}H{sub 4}, 5-C{sub 6}H{sub 4}; –F{sub 2}, 6-F{sub 2}, –(CH{sub 3}){sub 2}, 7-(CH{sub 3}){sub 2}) were synthesized under hydrothermal conditions. All the materials except 5-C{sub 6}H{sub 4} could be prepared by a general synthetic route, in which the mixtures of CrO{sub 3}, H{sub 2}BDC-X (BDC=1,4-benzenedicarboxylate) linkers, conc. HCl and water with a molar ratio of 1:1:3.9:222.2 were reacted at 180 °C for 144 h. Compared to the 144 h of synthesis time, three of the compounds, namely 1-Cl, 2-Br and 5-C{sub 6}H{sub 4}, could be prepared in much shorter reaction times (12–18 h at 180–210 °C). The materials possess high thermal stability up to 270–300 °C in an air atmosphere. The activated compounds exhibit significant porosity (S{sub BET} range: 1273–2135 m{sup 2} g{sup −1}). At 0 °C and 1 bar, the CO{sub 2} adsorption capacities of the compounds fall in the 1.7–2.9 mmol g{sup −1} range. Compounds 1-F and 6-F{sub 2} showed enhanced CO{sub 2} uptake values compared to parent Cr-MIL-101. The benzene adsorption capacities of the compounds lie in the range of 66.2–139.5 molecules per unit cell at 50 °C and p/p{sub 0}=0.35. The increased benzene uptake value of 1-F compared to un-functionalized Cr-MIL-101 and 4-CH{sub 3} suggests that the fluorination has induced more hydrophobicity in Cr-MIL-101 as compared to the methylation. - Graphical abstract: Benzene adsorption by seven functionalized Cr-MIL-101-X metal-organic framework (MOF) materials Display Omitted - Highlights: • Seven functionalized Cr-MIL-101-X materials were synthesized solvothermally. • All Cr-MIL-101-X materials exhibited high thermal stability up to 270–300 °C in air. • All Cr-MIL-101-X compounds displayed considerable porosity towards N{sub 2

THE SONG OF SONGS IN THE WORK OF LUIS DE LEON, SAN JUAN DE LA CRUZ Y JUAN GELMAN LANGUAGE, CHILDREN AND SPIRITUAL EXPERIENCE

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Geneviève Fabry

2015-04-01

Full Text Available This paper aims to study the intertextual traces dell Song of Songs in the work of Luis de León, San Juan de la Cruz and Juan Gelman from a particular point of view: the resonance in the vernacular of small biblical book as founder dimension of an experience spiritual, emotional and literary time. Choosing our corpus may surprise but, for one, would like to emphasize the importance of two pivotal moments in the reception of the Song: the Spanish Renaissance, whose approach to the Bible is enriched by new currents philological and exegetical of which Luis de León is a sublime representative; the late twentieth century in which an insistent intertextuality observed with sanjuanista work in one direction often foreign to Christian spirituality, as in the case of the Argentine Juan Gelman.

Application of Cs-137 techniques to problems of sediment redistribution in Sungai Lui representative basin, Selangor, Malaysia (Part 1)

International Nuclear Information System (INIS)

Daud bin Mohamad.

1982-11-01

Since the beginning of the nuclear age, Cesium-137 has become a part of the world's ecosystems. Cs-137 is carried from the atmosphere to the ground by rainfall. On reaching the earth's surface, 137 Cs becomes strongly adsorbed to soil profiles and is concentrated predominantly in the surface layer, particularly in clayey soils. Systematic measurements of Cs-137 levels will therefore permit estimates to be made of the cumulative effects of soil redistribution over the past 25 years. Sediment movement in river catchments and coastal areas is a very old problem in Malaysia. In view of rapid development of urban and agricultural areas in Malaysia it was realised tha soil loss problems are particularly serious. The Sungai Lui catchment was chosen to be the investigational site. Geologically, the area comprises of granite and granitic schist. The area is mostly covered by forest (approx. 83%) and rubber (13%), padi (2%) and others (2%). The climate is considered to be typical of Peninsular Malaysia (equatorial) characterised by uniform temperature, high humidity and high rainfall. The area is mainly drained by the Lui River. Soil samples were collected from the catchment area at 4 sampling points in April 1981. The results of analyses of Cs-137 in soil samples from Sungai Lui catchment area ranged from 1.3 to 6.8 M Bq g -1 of sample and they could still be detected even up to 20 cm depth. A general pattern of Cs-137 distribution was observed in the soil profile at each site. The highest activity being in the top 3 cm layer and then decreasing up to about 6 cm. The activity increases again up to about 9 cm layer. From there onwards, it decreases. Based on these results, the estimated rate of sediment accumulation in the area was found to be about 0.47 cm/year. Since the samples were only collected from the depositional sites, further sampling especially from erosional site should therefore be carried out in order to obtain more complete data

MIL-STD-1553 dynamic bus controller/remote terminal hybrid set

Science.gov (United States)

Friedman, S. N.

This paper describes the performance, physical and electrical requirements of a Dual Redundant BUS Interface Unit (BIU) acting as a BUS Controller Interface Unit (BCIU) or Remote Terminal Unit (RTU) between a Motorola 68000 VME BUS and MIL-STD-1553B Multiplex Data Bus. A discussion of how the BIU Hybrid set is programmed, and operates as a BCIU or RTU, will be included. This paper will review Dynamic Bus Control and other Mode Code capabilities. The BIU Hybrid Set interfaces to a 68000 Microprocessor with a VME Bus using programmed I/O transfers. This special interface will be discussed along with the internal Dual Access Memory (4K x 16) used to support the data exchanges between the CPU and the BIU Hybrid Set. The hybrid set's physical size and power requirements will be covered. This includes the present Double Eurocard the BIU function is presently being offered on.

José Teruel, Los años norteamericanos de Luis Cernuda: una singular propuesta de lectura

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Dana Guisasola

2014-07-01

Full Text Available La presente reseña se aboca al reciente libro de José Teruel, Los años norteamericanos de Luis Cernuda. El crítico revisa un abundante material bibliográfico y da cuenta de  los pormenores de la vida y obra del poeta español entre 1947 -año en el que el poeta llega a Nueva Inglaterra- y 1963, año de su muerte. El libro ha sido galardonado con el Premio de Investigación Literaria Gerardo Diego en 2013.

Feria de Milán. Pabellón de maquinaria pesada

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Covre, Gino

1960-04-01

Full Text Available Después de demoler el edificio destinado a las exposiciones de los adelantos y mejoras de la mecánica pesada, las autoridades Que rigen estas manifestaciones de la mecánica en Milán, Italia, se entregaron a un estudio de conjunto del problema que para ellos constituía la construcción de un pabellón que sustituyera al destruido y que, tanto por sus condiciones intrínsecas como por su aspecto estático y funcional, supliera ampliamente a su antecesor. El solar disponible constituía una amplia parcela aislada, y se pensó, en principio, en un cuerpo arquitectónico de dos plantas, una en semisótano y otra superior que constituiría la sala general de las exposiciones.

New K-Ar ages of volcanic rocks and associated mineralization in Canada Honda district, San Luis, Argentina

International Nuclear Information System (INIS)

Urbina, N.E.; Oggier, F.P

2001-01-01

New K-Ar ages in the Late Tertiary gold-bearing volcanic belt of the Sierras Pampeanas of San Luis, Argentina are presented. At Canada Honda district, an age of 8.49±0.2 Ma yielded by Cerro del Valle andesite indicates that the dome emplacement postdates the Diente Verde eruptive event. An even younger age of 7.3±0.2 Ma was obtained for illite from hydrothermal alteration at La Reynela mineralization which is hosted by Cerro del Valle andesite (au)

A forgotten chapter of Mexican technology and science: Luis Gutiérrez Villegas and poliomyelitis in Mexico.

Science.gov (United States)

Velázquez-Arellano, Antonio

Two different types of vaccines were developed against poliomyelitis: The Salk vaccine using inactivated virus and the Sabin one, that was used later, after investigations assured its safety. The first one was made in Mexico with its own resources since 1957 thanks to the efforts of young researchers and technicians coordinated by Luis Gutiérrez-Villegas, M.D., who was a Clinical Pathologist, University Professor and President of the Mexican National Academy of Mexico. Copyright: © 2017 SecretarÍa de Salud.

Interfacing the septa movement (DC motors) equipment to the PS control system and the MIL1553 bus

CERN Document Server

Dehavay, Claude

1995-01-01

Continuing the rejuvenation of the PS Control system , this application replaces the Single Transceiver Hybrid used to interface the Septa Movement Fquipment by a G64 system connected to the VME crate via the MIL1553 bus. This note explains the G64 hardware interface and details the standard message as defined in the Control Protocole for Power Converter, RF and Stepping Motor equipment.

Interfacing the septa movement (DC motor) equipment to the PS control system and the MIL1553 bus

CERN Document Server

Dehavay, Claude

1993-01-01

Continuing the rejuvenation of the PS Control system , it is planned to replace the Single Transceiver Hybrid used to interface the Septa Movement Equipment by a G64 system connected to the VME crate via the MIL1553 bus. This note explains the G64 hardware interface and details the standard message as defined in the Control Protocole for Power Converter, RF and Stepping Motor equipment.

Los hongos poliporoides de la Huasteca Potosina, San Luis Potosí, México

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Victor I. Alvarez

2016-03-01

Full Text Available Se estudiaron 98 especies de hongos poliporoides basados en 358 especímenes procedentes de 15 localidades de nueve municipios de la Huasteca Potosina en el estado de San Luis Potosí. Las 98 especies se clasifican en tres órdenes de Agaricomycetes, el orden Gloeophyllales con una familia, un género y  una especie, el orden Hymenochaetales con 2 familias, 10 géneros y 33 especies, y el orden Polyporales con seis familias,  32 géneros y 64 especies. De éstas, 73 se citan por primera vez para el estado, incluidas Phellinus calcitratus, P. coffeatoporus y Ceriporia reticulata que son nuevos registros para México.Palabras clave: Gloeophyllales, Hymenochaetales, Polyporales, macrohongos xilófagos.

Percepções sobre o gênero em homens acusados de agressão

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Winck, Gustavo Espíndola

2007-01-01

Full Text Available O presente texto pretende apresentar e discutir percepções acerca das relações e da violência de gênero entre homens acusados de agressão. Para tanto, os dados foram obtidos a partir de entrevistas individuais estruturadas (com questões abertas, além de anotações em diário de campo relativas à participação dos mesmos em grupos de reflexão. O delineamento foi qualitativo e, para o levantamento, foi utilizada a Análise de Discurso. Os resultados encontrados direcionam para questões como a dificuldade do reconhecimento da violência psicológica no ambiente familiar, a manutenção dos estereótipos ideológicos de gênero, a percepção da rede de poio social e a utilização da violência psicológica como recurso de coerção e de manutenção das relações de poder - especialmente na conjugalidade. A importância do debate social acerca dos papéis de gênero e futuras implicações do estudo também são discutidas

Genetic diversity of the Mycobacterium tuberculosis Complex in San Luis Potosí, México

Science.gov (United States)

2013-01-01

Background Although epidemiologic and socioeconomic criteria and biomedical risk factors indicate high-priority for tuberculosis (TB) control in Mexico, molecular epidemiology studies of the disease in the country are scarce. Methods Complete sociodemographic and clinical data were obtained from 248 of the 432 pulmonary TB (PTB) cases confirmed from 2006 to 2010 on the population under epidemiological surveillance in the state of San Luis Potosí, México. From most PTB cases with complete data Mycobacterium tuberculosis complex (MTC) isolates were recovered and their spoligotypes, lineages and families, geographic distribution and drug resistance determined. Results Pulmonary tuberculosis incidence ranged from 2.4 to 33.4 (cases per 100,000 inhabitants) in the six state sanitary jurisdictions that were grouped in regions of low (jurisdictions I-II-III), intermediate (jurisdictions IV-V) and high incidence (jurisdiction VI) with 6.2, 17.3 and 33.4 rates, respectively. Most patients were poor, 50-years-median-age males and housewives. Among the 237 MTC spoligotyped isolates, 232 corresponded to M. tuberculosis (104 spoligotypes in 24 clusters) and five to M. bovis. The predominant Euro-American lineage was distributed all over the state, the East-Asian lineage (Beijing family) in the capital city, the Indo-Oceanic (Manila family) in eastern localities, and M. bovis in rural localities. Conclusions In San Luis Potosí TB affects mainly poor male adults and is caused by M. tuberculosis and to a minor extent by M. bovis. There is great genotypic diversity among M. tuberculosis strains, the Euro-American lineage being much more prevalent than the Indo-Oceanic and East-Asian lineages. The frequency of resistant strains is relatively low and not associated to any particular lineage. PMID:23635381

1959: los intentos de derrocamiento de las dictaduras de Trujillo, Stroessner y Luis Somoza

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María Dolores Ferrero Blanco

2016-03-01

Full Text Available El triunfo de la revolución cubana trajo, entre sus múltiples consecuencias, la reanimación de la oposición a las tres dictaduras fuertes en 1959: la República Dominicana, Nicaragua y Paraguay. En el presente artículo se analizan las características generales de las mismas, los paralelismos y diferencias entre Trujillo, Stroessner y Somoza, al tiempo que se exponen los diversos intentos de los opositores exiliados para acabar con los regímenes tiránicos implantados en sus respectivos países. Las fuentes utilizadas proceden de los archivos nacionales y de relaciones exteriores, especialmente la documentación diplomática, que aporta una visión singular de los embajadores dependiendo de los destinos. Palabras clave: Rafael Leónidas Trujillo, Luis Somoza, Alfredo Stroessner, dictaduras iberoamericanas, revolución cubana, oposición a las dictaduras._______________________________Abstract: Cuban revolution success brought, among its multiple consequences, the liveliness of the political opposition against the three dictatorships in 1959: the Dominican Republic, Nicaragua and Paraguay. In the present article it is analyzed their general characteristics of the same ones, the differences between Trujillo, Stroessner and the Somoza's, as same as it is exposed the several attempts of the exiles op-ponents to end the implanted tyrannies' regimes in their respective countries. The sources used come from the national archives and foreign relations, especially the diplomatic docu-mentation, that contributes with a singular vision of the ambassadors depending on their destinies, an optics that serves us to know the relations established between the three dictators.Keywords: Rafael Leónidas Trujillo, Luis Somoza, Alfredo Stroessner, latinoamerican dictatorships, Cuban Revolution, dictatorships political opposition.    

Presence of exotic birds in San Luis Potosi city, Mexican Plateau

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Ramírez-Albores, J.E.

2015-01-01

Full Text Available We recorded 12 exotic bird species in San Luis Potosi, Mexico and adjacent areas. Obtained data were collected during the period August 2012 to August 2013. From the total of recorded species, eight are confirmations (Anas platyrhynchos domesticus, Cairina moschata, Bubulcus ibis, Columba livia, Sturnus vulgaris, Turdus rufopalliatus, Quiscalus mexicanus and Passer domesticus and four are new records (Aratinga canicularis, Amazona oratrix, A. autumnalis and Cyanocorax yncas. Although not all exotic species represent a risk because of the lack of the necessary resources for the establishment of abundant viable populations, it is important to publicize their status in the region. Therefore, knowing the presence of exotic species in a new distribution area is important for monitoring its establishment and colonization, and defining management, control and eradication programs of these species, along with environmental education programs that would lead to a better understanding of impacts that these species can cause.

Petrological and geochemical characterization of the plutonic rocks of the Sierra de La Aguada, Province of San Luis, Argentina: Genetic implications with the Famatinian magmatic arc

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E. Cristofolini

2017-07-01

Full Text Available This study presents a synthesis on the geology of the crystalline complex that constitute the Sierra de la Aguada, San Luis province, Argentine, from an approach based on field relations, petrologic and structural features and geochemical characteristic. This mountain range exposes a basement dominated by intermediate to mafic calcalkaline igneous rocks and peraluminous felsic granitoids, both emplaced in low to medium grade metamorphic rocks stabilized under low amphibolite facies. All this lithological terrane has been grouped in the El Carrizal-La Aguada Complex. Field relations, petrographic characterization and geochemical comparison of the plutonic rocks from the study area with those belonging to the Ordovician Famatinian suit exposed in the Sierra Grande de San Luis, suggest a genetic and temporal relation linked to the development of the Famatinian magmatic arc.

Clima y compromiso organizacional en una mediana empresa manufacturera de San Luis Potosí, S.L.P.

OpenAIRE

Crespo Bravo, Carolina

2016-01-01

Este trabajo tiene como objetivo principal analizar la relación que existe entre clima y compromiso organizacional y de estos con las características personales. La muestra se integró con 80 trabajadores de una mediana empresa manufacturera ubicada en la ciudad de San Luis Potosí. Se realizó un estudio empírico transversal aplicando cuestionarios para clima organizacional de Araujo et al. (2011), el cual se construyó con características inherentes a las dimensiones: a) estilo de geren...

«In favor of happiness»: the legacy of the Enlightenment in the poetry of Luis García Montero «Partidario de la felicidad»: el horizonte de la Ilustración en la poesía de Luis García Montero

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Araceli IRAVEDRA

2012-06-01

Full Text Available The most celebrated book of Luis García Montero, Habitaciones separadas (1994, includes a dramatic monologue starring the figure of Jovellanos. Far from an anectodal fact, the presence of the asturian intellectual in this point of the lyric biography of García Montero comes to ratify the importance that the enlightened tradition has acquired in the poetic system of the author from Granada, main theoretical mentor of the so called poetry of experience. Following the reading suggested by Luis García Montero, we systematize the enlightened foundations of this aesthetic trend, which would find its modern roots in some capital notions of the eighteen century doctrine. Furthermore, we attempt to show how far those enlightened categories finally conform an axiological canon and reinforce García Montero’s theoretical opinion in favour of the value of the trade as an effective intervention of the poet in the social order. Finally, we suggest an interpretation of the «El insomnio de Jovellanos» in the light of the enlightened reading of the Modernity that the poet postulates in his essayistic discourse, a Modernity aimed to the transformation of the present against the repeated decrees of the end of History.El libro tal vez más celebrado de Luis García Montero, Habitaciones separadas (1994, incorpora un monólogo dramático protagonizado por la figura de Jovellanos. Lejos de tratarse de un dato anecdótico, la compañía del asturiano en este punto de la biografía lírica de García Montero no viene sino a rubricar el predicamento que la tradición ilustrada ha conquistado en el sistema poético del autor granadino, principal mentor teórico de la llamada poesía de la experiencia. A la zaga de la lectura propuesta por Luis García Montero, efectuamos una sistematización de los fundamentos ilustrados de dicha corriente estética, que hallaría sus raíces modernas en algunas nociones capitales de la preceptiva dieciochesca. Además, tratamos

Analysis of a MIL-L-27502 lubricant from a gas-turbine engine test by size-exclusion chromatography

Science.gov (United States)

Jones, W. R., Jr.; Morales, W.

1983-01-01

Size exclusion chromatography was used to determine the chemical degradation of MIL-L-27502 oil samples from a gas turbine engine test run at a bulk oil temperature of 216 C. Results revealed a progressive loss of primary ester and additive depletion and the formation of higher molecular weight products with time. The high molecular weight products absorbed strongly in the ultraviolet indicating the presence of chromophoric groups.

Metal-organic framework MIL-101(Cr) as a sorbent of porous membrane-protected micro-solid-phase extraction for the analysis of six phthalate esters from drinking water: a combination of experimental and computational study.

Science.gov (United States)

Wang, Ting; Wang, Jian; Zhang, Conglu; Yang, Zhao; Dai, Xinpeng; Cheng, Maosheng; Hou, Xiaohong

2015-08-07

An attractive metal-organic framework (MOF) MIL-101(Cr) material was synthesized at the nanoscale and applied as a sorbent in the porous membrane-protected micro-solid-phase extraction (μ-SPE) device for the pre-concentration of phthalate esters (PAEs) in drinking water samples for the first time. Parameters influencing the extraction efficiency, such as the selection of sorbent materials, pH adjustment, the effect of salt, magnetic-stirring extraction time, the desorption solvent and the desorption time, were investigated. Under the optimum conditions, the limits of detection from gas chromatography-mass spectrometric analysis for PAEs varied from 0.004 to 0.02 μg L(-1). The linear ranges were from 0.1 to 50 μg L(-1) or from 0.2 to 50 μg L(-1) for the analytes with the relative standard deviations fluctuating from 0.8 to 10.9% (n = 5). The enrichment factors (EFs) for the target PAEs were varied from 143 to 187. MIL-101(Cr) exhibited remarkable advantages compared to activated carbon and MIL-100(Fe). On the other hand, the computational method was first used to predict the adsorption of MIL-101(Cr) towards PAEs. The molecular interactions and the free binding energies between MIL-101(Cr) and PAEs were observed and calculated in terms of the molecular modeling method. MIL-101(Cr) showed high potential in the analysis of PAEs at trace levels in drinking water. The computational result was consistent with the detected enrichment factors. The computational modeling accurately predicted the extraction efficiency of MOF-based material towards the target analytes. Therefore, the combination of experimental and computational study provided a new strategy on the trace contaminant analysis.

Magnetic solid-phase extraction of triazine herbicides from rice using metal-organic framework MIL-101(Cr) functionalized magnetic particles.

Science.gov (United States)

Liang, Li; Wang, Xinghua; Sun, Ying; Ma, Pinyi; Li, Xinpei; Piao, Huilan; Jiang, Yanxiao; Song, Daqian

2018-03-01

The metal-organic framework (MOF) functionalized magnetic graphene oxide/mesoporous silica composites (Fe 3 O 4 @SiO 2 -GO/MIL-101(Cr)) were synthesized and utilized as magnetic solid-phase extraction (MSPE) adsorbent for the extraction of seven triazine herbicides (terbuthylazine, secbumeton, terbumeton, atraton, atrazine, prometon and trietazine) in rice samples. Several experimental parameters, including type and volume of extraction solvent, amount of MIL-101(Cr), extraction time, volume of desorption solvent and desorption time were investigated and optimized. The limits of detection (LODs) of seven triazine herbicides obtained by using the proposed MSPE method combined with high performance liquid chromatography (HPLC) were in the range of 0.010-0.080µgkg -1 . The recoveries of the triazine herbicides in spiked rice samples ranged from of 83.9-103.5% with the relative standard deviations lower than 8.7%. The intra and inter-day (n = 6) precisions for all triazine herbicides at the spiked level of 100.0µgkg -1 were 1.4-5.9% and 2.6-7.8%, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

Another Look at the Draft Mil-Std-1540E Unit Random Vibration Test Requirements

Science.gov (United States)

Perl, E.; Peterson, A. J..; Davis, D.

2012-07-01

The draft Mil-Std-1540E has been updated to reflect lessons learned since its publication as an SMC Standard in 2008, [1], and an earlier Aerospace Corporation Technical Report released in 2006, [2]. This paper discusses the technical rationale supporting some of the unit random vibration test requirements to provide better insight into their derivation and application to programs. It is intended that these requirements be tailored for each program to reflect the customer risk profile. Several tailoring options are provided and a two phase test strategy is discussed to highlight its applicability to utilizing heritage hardware in new applications.

Jorge Luis Borges at two final judgments

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Gustavo Ponciano Cunha de Oliveira

2017-06-01

Full Text Available Em 1988, Beatriz Sarlo propõe uma passagem entre duas poéticas em Jorge Luis Borges: de Evaristo Carriego (1930 em direção a Historia universal de la infamia (1935. Os dois textos são “insidiosos”, defende a pesquisadora, porque falsificam as biografias de seus personagens. Porém, a coletânea de 1935 opera em âmbito universal. Este movimento, afirma Sarlo, é portador de um acumulo de prerrogativas, associado à dupla inscrição de Borges: o cidadão do mundo e, simultaneamente, o de um país pensado a partir de Buenos Aires. Neste ensaio, sugerimos uma passagem anterior, evidenciada em “Sentirse en muerte” (1928: do criollismo – o poeta dos arrabaldes, dotado da capacidade de transporte sensível e instalado nos limites de sua cidade imaginada, que busca a representação poética digna de seu conceito de argentinidade – em direção à prosa que alcança o caráter argumentativo-reflexivo dos ensaios sobre o tempo e a eternidade característicos de Borges, início de sua legitimação como “percibidor abstracto del mundo”. Este movimento é também portador de um acúmulo de prerrogativas, dupla inscrição de Borges: como poeta, literato e ensaísta programático do criollismo; como meditador dedicado aos assombros contidos em nossos conceitos de vida, tempo e universo, operador de textos da Filosofia e da Teologia.

Un precedente de psicología conductual en la Universidad Nacional de San Luis (Argentina)

OpenAIRE

Calabresi, Corina; Polanco, Fernando

2008-01-01

En 1970 un grupo de estudiantes de la Licenciatura en Psicología y Pedagogía de la Universidad Nacional de San Luis, Argentina, tuvo un activo compromiso con el desarrollo de una psicología científica basada en la teoría conductual. El trabajo analiza la conformación de dicho movimiento estudiantil y la fundación, por parte del mismo, en 1974 del Centro de Estudios de Psicología Objetiva I. P. Pavlov (CEDEPO), el cual progresivamente cuestionó la hegemonía psicoanalítica en el medio académico...

Atuação do pediatra nos primeiros mil dias da criança: a busca pela nutrição e desenvolvimento saudáveis

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Antonio Jose Ledo Alves da Cunha

2015-12-01

Full Text Available Resumo Objetivos: Descrever o conceito dos primeiros mil dias, sua importância para a saúde e ações a serem implantadas, em especial pelos pediatras, para que a criança alcance nutrição e desenvolvimento saudáveis. Fonte dos dados: Revisão não sistemática nas bases SciELO, Lilacs, Medline, Scopus e Web of Science nos últimos dez anos com os termos mil dias, nutrição infantil, desenvolvimento infantil, infância, criança. Busca não sistemática na Internet de organizações que adotam o conceito dos mil dias e emitem recomendações sobre a saúde da criança. Síntese dos dados: Os primeiros mil dias vão da concepção até o fim do segundo ano de vida. É um importante período para intervenções que garantam nutrição e desenvolvimento saudáveis, que trarão benefícios em todo o ciclo de vida. As crianças devem receber alimentação adequada, por meio de nutrição pré-natal adequada, aleitamento materno exclusivo nos primeiros seis meses, adição de alimentos complementares adequados e continuação da amamentação até os dois anos. Face à condição de dependência absoluta de cuidados de um adulto, é fundamental que tenham um ambiente propício e acolhedor necessário para desenvolver laços fortes com seus cuidadores e lançar as bases para um desenvolvimento pleno e saudável. Conclusões: O pediatra, junto com outros profissionais, pode atuar na promoção de ações com ênfase no conceito dos primeiros mil dias que garantam a nutrição e o desenvolvimento saudáveis da criança. Focalizar ações nesse período poderá aumentar as chances de a criança ter uma vida saudável e produtiva no futuro, fortalecer famílias e comunidades e contribuir para quebrar o ciclo intergeracional da pobreza.

Interaction of methanol with the flexible metal-organic framework MIL-53(Fe) observed by inelastic neutron scattering

International Nuclear Information System (INIS)

Munn, Alexis S.; Ramirez-Cuesta, Anibal J.; Millange, Franck; Walton, Richard I.

2013-01-01

Highlights: • A spectroscopic signature of guest-induced swelling of a flexible MOF has been identified. • Librations of the linker contribute to pore opening of the MOF structure. • Complementary in situ powder XRD shows changes in long-range order during guest uptake. - Abstract: In situ powder X-ray diffraction and thermogravimetry show that the iron(III) carboxylate material MIL-53(Fe) expands in two steps upon exposure to methanol vapour to give a ‘half open’ phase and then a fully expanded structure; these correspond to the uptake of one and two molar equivalents of methanol, respectively. This knowledge allows interpretation of inelastic neutron scattering (INS) spectra, measured using TOSCA at ISIS, of the solid loaded with various amounts of water, methanol or d3-methanol (CD 3 OH), aided also by DFT simulation of INS spectra of the analogous MIL-53(Al) structure. The key signature of the expansion and contraction of the structure is the shift of bands in the 400 cm −1 region: these are assigned as due to the librations of the terephthalate rings, involving motions that result in distortion of the aromatic ring and a rocking motion of the aromatic ring about the bonds to the carboxylate groups

CONTRIBUTIONS TO RICKETTSIOSES RESEARCH IN COLOMBIA (1917-1943), LUIS B. PATIÑO CAMARGO

Science.gov (United States)

FACCINI-MARTÍNEZ, Álvaro A.; BOTERO-GARCÍA, Carlos A.; HIDALGO, Marylin

2016-01-01

Colombian physician Luis Benigno Patiño Camargo was one of the pioneers in the study of rickettsioses in South America, demonstrating for the first time in Colombia the presence of Rickettsia rickettsii as the etiological agent of a highly deadly exanthematic febrile syndrome in the 1930s. However, Patiño-Camargo performed other investigations from 1917-1943, which represent the first descriptions and scientific evidence of the presence of R. prowazekii and R. typhi in Colombia. Almost 60 years after the latest research conducted by Dr. Patiño-Camargo, rickettsioses were again a matter of interest and research. In the last decade over 20 research studies have been published, showing new endemic areas for R. rickettsii, as well as the description of new rickettsial species in Colombia. PMID:27074327

Visual Resource Analysis for Solar Energy Zones in the San Luis Valley

Energy Technology Data Exchange (ETDEWEB)

Sullivan, Robert [Argonne National Laboratory (ANL), Argonne, IL (United States). Environmental Science Division; Abplanalp, Jennifer M. [Argonne National Laboratory (ANL), Argonne, IL (United States). Environmental Science Division; Zvolanek, Emily [Argonne National Laboratory (ANL), Argonne, IL (United States). Environmental Science Division; Brown, Jeffery [Bureau of Land Management, Washington, DC (United States). Dept. of the Interior

2016-01-01

This report summarizes the results of a study conducted by Argonne National Laboratory’s (Argonne’s) Environmental Science Division for the U.S. Department of the Interior Bureau of Land Management (BLM). The study analyzed the regional effects of potential visual impacts of solar energy development on three BLM-designated solar energy zones (SEZs) in the San Luis Valley (SLV) in Colorado, and, based on the analysis, made recommendations for or against regional compensatory mitigation to compensate residents and other stakeholders for the potential visual impacts to the SEZs. The analysis was conducted as part of the solar regional mitigation strategy (SRMS) task conducted by BLM Colorado with assistance from Argonne. Two separate analyses were performed. The first analysis, referred to as the VSA Analysis, analyzed the potential visual impacts of solar energy development in the SEZs on nearby visually sensitive areas (VSAs), and, based on the impact analyses, made recommendations for or against regional compensatory mitigation. VSAs are locations for which some type of visual sensitivity has been identified, either because the location is an area of high scenic value or because it is a location from which people view the surrounding landscape and attach some level of importance or sensitivity to what is seen from the location. The VSA analysis included both BLM-administered lands in Colorado and in the Taos FO in New Mexico. The second analysis, referred to as the SEZ Analysis, used BLM visual resource inventory (VRI) and other data on visual resources in the former Saguache and La Jara Field Offices (FOs), now contained within the San Luis Valley FO (SLFO), to determine whether the changes in scenic values that would result from the development of utility-scale solar energy facilities in the SEZs would affect the quality and quantity of valued scenic resources in the SLV region as a whole. If the regional effects were judged to be significant, regional

A Simple Vortex-Assisted Magnetic Dispersive Solid Phase Microextraction System for Preconcentration and Separation of Triazine Herbicides from Environmental Water and Vegetable Samples Using Fe₃O₄@MIL-100(Fe) Sorbent.

Science.gov (United States)

Nasrollahpour, Atefe; Moradi, Seyyed Ershad

2018-04-04

A vortex-assisted magnetic dispersive solid phase microextraction coupled with high-performance liquid chromatography has been developed for the extraction and determination of triazine herbicides by using magnetic metal organic frameworks [Fe₃O₄@MIL-100(Fe)] in environmental water and vegetable samples. The Fe₃O₄@MIL-100(Fe) composite has been characterized by using X-ray diffraction spectroscopy, tunneling electron microscopy, thermogravimetric measurement, and Brunauer-Emmett-Teller analysis. The method is based on the sorption of triazine herbicides on Fe₃O₄@MIL-100(Fe) because of the complex formation between iron oxide nanoparticles and triazine herbicides beside π-π interactions between organic parts of Fe₃O₄@MIL-100(Fe) and triazine herbicides. The experimental parameters for the preconcentration of triazine herbicides, such as the type and volume of the eluent, pH, time of the sorption and desorption, and the amount of the sorbent, were optimized. Under the optimized conditions, the method was linear over the concentration range of 0.0061 to 70 ng/mL for each triazine herbicide, and the correlation coefficients ranged from 0.9988 to 0.9997. The limit of detection of the method at a signal-to-noise ratio of 3 was 2.0 to 5.3 ng/mL. The relative standard deviations for inter- and intraday assays were in the range of 5.8 to 10.2% and 3.8 to 6.3%, respectively.

Using the Auditory Hazard Assessment Algorithm for Humans (AHAAH) With Hearing Protection Software, Release MIL-STD-1474E

Science.gov (United States)

2013-12-01

unfolding.” Invited article in NHCA’s Spectrum. 1997 MIL-STD-1474D. (1997). “Department of defense design criteria. Noise limits,” http...Passenger Safety, Washington, DC. Price, G. R. (1997). “Understanding hazard from intense sounds.” Invited seminar to Audiology Department, University of...Putting theory into practice.” In H. M. Borchgrevink (Ed.), Hearing and hearing prophylaxis, Scandinavian Audiology Supplement 16 (pp. 111-121

The Outreach Process in the Technical University Luis Vargas Torres, Esmeraldas, Ecuador

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Harold Oyarvide-Ramirez

2016-06-01

Full Text Available As part of the transformative process that takes place in the ecuadorian university is research that aims to improve the outreach model at the Technical University Luis Vargas Torres Esmeraldas developed. The need of jobs forces people to venture into small businesses, however, this process is done in an empirical way, without sufficient technical and administrative knowledge that will enable the company to manage efficiently and obtain funding sources. Hence the relevance of the study, which allows guide and train the business sector in order to conduct an efficient management and create new businesses that operate as a means for the transformation of the productive matrix. The research results are: the structure and function of outreach model, the key elements that support the creation of the Center for Business Development and Entrepreneurship Support and the socioeconomic impact achieved from the development of relations among universities, businesses and government.

Luis Álvarez-Gaumé to speak at El Ser Creativo 2011

CERN Multimedia

Jordan Juras

2011-01-01

During the weekend of 19 October, 2011, Madrid will host this year’s El Ser Creativo – a three-day conference celebrating new ideas that can change the world.   Over the course of the conference, 21 speakers will have the chance to share their opinions and ideas for 21 minutes each – the estimated time that the human brain is able to maintain complete focus. Among the Nobel Prize winners, scientists, doctors, and thinkers invited to this year's conference is Luis Álvarez-Gaumé, a theoretical physicist at CERN. Having made significant contributions to the understanding of gravitation, minimal supergravity theory and supersymmetry, Álvarez-Gaumé was an obvious choice to be invited to share his thoughts about the theory and reality of current physics ideas with the conference attendees. A webcast will be available to stream the entire conference live.

The archaeological investigations of 1984 at Trinca “Izvorul lui Luca” site

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Oleg Leviţki

2017-09-01

Full Text Available The article presents the archaeological researches carried out at Trinca “Izvorul lui Luca” settlement in 1984. The paper is part of the series of articles initiated by the authors in order to include the research results of this unusual site. The discovered archaeological remains were treated in a complex way, presented on layers, complexes, categories and types. Thus, the discovered complexes were described, the pieces of inventory systematized according to the categories of materials from which they were made, while the ceramics is presented by categories, types and variants. The most relevant findings have been analysed in more detail, being related to those specific of other synchronous or partially synchronic neighbouring cultures. As a result, the existence of a set of artefacts has been established, having analogies in the Hallstattian Carpathian-Nistrian cultural environment and, respectively, in the Middle Danube area.

A divisão de tarefas domésticas entre homens e mulheres no cotidiano do casamento*

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Bernardo Jablonski

Full Text Available O presente trabalho visa a investigar como se dá a negociação de tarefas dentro do lar face às novas demandas impostas a reboque do movimento de emancipação feminina e do ingresso maciço das mulheres no mercado de trabalho. Procuramos avaliar atitudes e comportamentos acerca de diversos tópicos relativos ao cotidiano da vida em comum entrevistando 20 membros de casais heterossexuais de classe média, com idades entre 30 e 40 anos, com pelo menos 5 anos de união e ao menos um filho. Entre os principais resultados, destacamos que, apesar da existência de uma dupla jornada de trabalho e das dificuldades demonstradas pelos homens em compartilhar de forma igualitária as tarefas domésticas - recaindo sobre a mulher o peso maior (cuidar da casa e das crianças, fazer compras, arrumar, lavar e passar, etc. - não observamos, como seria esperado, um aumento considerável de conflitos na relação marital.

A divisão de tarefas domésticas entre homens e mulheres no cotidiano do casamento

Directory of Open Access Journals (Sweden)

Bernardo Jablonski

Full Text Available O presente trabalho visa a investigar como se dá a negociação de tarefas dentro do lar face às novas demandas impostas a reboque do movimento de emancipação feminina e do ingresso maciço das mulheres no mercado de trabalho. Procuramos avaliar atitudes e comportamentos acerca de diversos tópicos relativos ao cotidiano da vida em comum entrevistando 20 membros de casais heterossexuais de classe média, com idades entre 30 e 40 anos, com pelo menos 5 anos de união e ao menos um filho. Entre os principais resultados, destacamos que, apesar da existência de uma dupla jornada de trabalho e das dificuldades demonstradas pelos homens em compartilhar de forma igualitária as tarefas domésticas - recaindo sobre a mulher o peso maior (cuidar da casa e das crianças, fazer compras, arrumar, lavar e passar, etc. - não observamos, como seria esperado, um aumento considerável de conflitos na relação marital.

PPy@MIL-100 Nanoparticles as a pH- and Near-IR-Irradiation-Responsive Drug Carrier for Simultaneous Photothermal Therapy and Chemotherapy of Cancer Cells.

Science.gov (United States)

Zhu, Yu-Da; Chen, Su-Ping; Zhao, Huan; Yang, You; Chen, Xiao-Qin; Sun, Jing; Fan, Hong-Song; Zhang, Xing-Dong

2016-12-21

A medical nanoplatform with small size, low cost, biocompatibility, good biodegradability, and, in particular, multifunctionality has attracted much attention in the exploration of novel therapeutic methodologies. As an emerging material of self-assembled porous structure, metal-organic frameworks (MOFs) have high expectations because of their special properties compared to traditional porous materials. Therefore, integration of MOFs and functional materials is leading to the creation of new multifunctional composites/hybrids. Photothermal therapy (PTT), using near-IR (NIR) laser-absorbing nanomaterials as PTT agents, has shown encouraging therapeutic effects to photothermally ablate tumors. However, the most of widely used PTT agents are inorganic materials and nonbiodegradable. Herein, uniform polypyrrole (PPy) nanoparticles (NPs) with good biodegradability were synthesized by a microemulsion method. The PPy NPs were further coated with the mesoporous iron-based MOF structure MIL-100 by interaction between PPy NPs and MIL-100 precursors at room temperature. As a multifunctional nanoplatform, an anticancer drug could easily be loaded into the mesopores of the MIL-100 shell. The PPy core, as an organic photothermal agent, is able to photothermally ablate cancer cells and improve the efficacy of chemotherapy under NIR irradiation. The composites showed an outstanding in vivo synergistic anticancer capacity. Our work could encourage further study in the construction of a synergetic system using MOFs and organic PTT agents.

Quentin Skinner, Staten og friheten. Oslo: Res Publica, 2011. José Luis Martí and Philip Pettit, A Political Philosophy in Public Life. Civic Republicanism in Zapatero's Spain. Princeton: Princeton University Press, 2010 (Simon Laumann Jørgensen)

DEFF Research Database (Denmark)

Jørgensen, Simon Laumann

2012-01-01

Anmeldelse af Quentin Skinner, Staten og friheten, Oslo: Res Publica 2011, 199 NOK & José Luis Martí & Philip Pettit, A Political Philosophy in Public Life. Civic Republicanism in Zapatero’s Spain, Princeton: Princeton University Press 2010, $ 24.95......Anmeldelse af Quentin Skinner, Staten og friheten, Oslo: Res Publica 2011, 199 NOK & José Luis Martí & Philip Pettit, A Political Philosophy in Public Life. Civic Republicanism in Zapatero’s Spain, Princeton: Princeton University Press 2010, $ 24.95...

Ciudades invisibles. Tijuana en la obra de Federico Campbell, Luis Humberto Crosthwaite, Francisco Morales y Heriberto Yépez

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Diana Palaversich

2014-06-01

This essay employs the concepts of “the haunted place” (Michel de Certeau and “the sense of place” (Kent Ryden to examine the representation of the US-Mexico border in the works of Federico Campbell, Luis Humberto Crosthwaite, Francisco Morales and Heriberto Yépez. While Campbell, Crosthwaite, and Morales represent Tijuana as a place imbued with personal and collective history, Yépez, in his most recent novel, Al otro lado, offers an apocalyptic vision of this border city, defined by narcoviolence, illegal immigration, and militarization.

«In favor of happiness»: the legacy of the Enlightenment in the poetry of Luis García Montero

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Araceli IRAVEDRA

2012-02-01

Full Text Available The most celebrated book of Luis García Montero, Habitaciones separadas (1994, includes a dramatic monologue starring the figure of Jovellanos. Far from an anectodal fact, the presence of the asturian intellectual in this point of the lyric biography of García Montero comes to ratify the importance that the enlightened tradition has acquired in the poetic system of the author from Granada, main theoretical mentor of the so called poetry of experience. Following the reading suggested by Luis García Montero, we systematize the enlightened foundations of this aesthetic trend, which would find its modern roots in some capital notions of the eighteen century doctrine. Furthermore, we attempt to show how far those enlightened categories finally conform an axiological canon and reinforce García Montero’s theoretical opinion in favour of the value of the trade as an effective intervention of the poet in the social order. Finally, we suggest an interpretation of the «El insomnio de Jovellanos» in the light of the enlightened reading of the Modernity that the poet postulates in his essayistic discourse, a Modernity aimed to the transformation of the present against the repeated decrees of the end of History.

Introduction to the special collection of papers on the San Luis Basin Sustainability Metrics Project: a methodology for evaluating regional sustainability.

Science.gov (United States)

Heberling, Matthew T; Hopton, Matthew E

2012-11-30

This paper introduces a collection of four articles describing the San Luis Basin Sustainability Metrics Project. The Project developed a methodology for evaluating regional sustainability. This introduction provides the necessary background information for the project, description of the region, overview of the methods, and summary of the results. Although there are a multitude of scientifically based sustainability metrics, many are data intensive, difficult to calculate, and fail to capture all aspects of a system. We wanted to see if we could develop an approach that decision-makers could use to understand if their system was moving toward or away from sustainability. The goal was to produce a scientifically defensible, but straightforward and inexpensive methodology to measure and monitor environmental quality within a regional system. We initiated an interdisciplinary pilot project in the San Luis Basin, south-central Colorado, to test the methodology. The objectives were: 1) determine the applicability of using existing datasets to estimate metrics of sustainability at a regional scale; 2) calculate metrics through time from 1980 to 2005; and 3) compare and contrast the results to determine if the system was moving toward or away from sustainability. The sustainability metrics, chosen to represent major components of the system, were: 1) Ecological Footprint to capture the impact and human burden on the system; 2) Green Net Regional Product to represent economic welfare; 3) Emergy to capture the quality-normalized flow of energy through the system; and 4) Fisher information to capture the overall dynamic order and to look for possible regime changes. The methodology, data, and results of each metric are presented in the remaining four papers of the special collection. Based on the results of each metric and our criteria for understanding the sustainability trends, we find that the San Luis Basin is moving away from sustainability. Although we understand

Tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos

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Mateus Habermann

2012-02-01

Full Text Available OBJETIVO: Analisar a associação entre indicadores de exposição à poluição por tráfego veicular e mortalidade por doenças do aparelho circulatório em homens adultos. MÉTODOS: Foram analisadas informações sobre vias e volume de tráfego no ano de 2007 fornecidas pela companhia de engenharia de tráfego local. Mortalidade por doenças do aparelho circulatório no ano de 2005 entre homens > 40 anos foram obtidas do registro de mortalidade do Programa de Aprimoramento de Informações de Mortalidade do Município de São Paulo, SP. Dados socioeconômicos do Censo 2000 e informações sobre a localização dos serviços de saúde também foram coletados. A exposição foi avaliada pela densidade de vias e volume de tráfego para cada distrito administrativo. Foi calculada regressão (α = 5% entre esses indicadores de exposição e as taxas de mortalidade padronizadas, ajustando os modelos para variáveis socioeconômicas, número de serviços de saúde nos distritos e autocorrelação espacial. RESULTADOS: A correlação entre densidade de vias e volume de tráfego foi modesta (r² = 0,28. Os distritos do centro apresentaram os maiores valores de densidade de vias. O modelo de regressão espacial de densidade de vias indicou associação com mortalidade por doenças do aparelho circulatório (p = 0,017. Não se observou associação no modelo de volume de tráfego. Em ambos os modelos - vias e volume de tráfego (veículos leves/pesados - a variável socioeconômica foi estatisticamente significante. CONCLUSÕES: A associação entre mortalidade por doenças do aparelho circulatório e densidade de vias converge com a literatura e encoraja a realização de mais estudos epidemiológicos em nível individual e com métodos mais acurados de avaliação da exposição.

Masculinidad y violencia en el nuevo cine mexicano. Las películas de Luis Estrada

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Claudia Elizabeth Puente

2016-01-01

Full Text Available En este artículo exploraremos la conformación de las masculinidades a través de las representaciones cinematográficas en América latina, específicamente en la obra del mexicano Luis Estrada, parte fundamental del llamado Nuevo cine mexicano en sus obras exhibidas entre 1999 y 2010. Aunque el universo de estudios de masculinidades es cada vez más amplio, las representaciones cinematográficas no han sidomuy exploradas. Este artículo pretende hacer un análisis de las representaciones masculinas y su relación con las representaciones femeninas en el nuevo cine mexicano en un contexto de violencia desde una perspectiva crítica feminista.

Elucidating the Vibrational Fingerprint of the Flexible Metal–Organic Framework MIL-53(Al) Using a Combined Experimental/Computational Approach

Science.gov (United States)

2018-01-01

In this work, mid-infrared (mid-IR), far-IR, and Raman spectra are presented for the distinct (meta)stable phases of the flexible metal–organic framework MIL-53(Al). Static density functional theory (DFT) simulations are performed, allowing for the identification of all IR-active modes, which is unprecedented in the low-frequency region. A unique vibrational fingerprint is revealed, resulting from aluminum-oxide backbone stretching modes, which can be used to clearly distinguish the IR spectra of the closed- and large-pore phases. Furthermore, molecular dynamics simulations based on a DFT description of the potential energy surface enable determination of the theoretical Raman spectrum of the closed- and large-pore phases for the first time. An excellent correspondence between theory and experiment is observed. Both the low-frequency IR and Raman spectra show major differences in vibrational modes between the closed- and large-pore phases, indicating changes in lattice dynamics between the two structures. In addition, several collective modes related to the breathing mechanism in MIL-53(Al) are identified. In particular, we rationalize the importance of the trampoline-like motion of the linker for the phase transition. PMID:29449906

Encefalitis por virus San Luis en la Ciudad de Buenos Aires durante el brote de dengue 2009

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Horacio López

2011-06-01

Full Text Available Se presenta un paciente de 80 años de edad, residente en la Ciudad de Buenos Aires, con diagnóstico serológico para el virus de la encefalitis de San Luis (SLE durante el brote de dengue ocurrido entre enero y mayo de 2009. Presentaba leucemia linfoide crónica en tratamiento con clorambucilo, cáncer de próstata tratado con hormonoterapia y radioterapia, e imágenes óseas compatibles con metástasis. El estudio del líquido cefalorraquídeo demostró pleocitosis con predominio de mononucleares y proteinorraquia elevada. El resultado de los cultivos para bacterias, hongos y micobacterias, así como el PCR en LCR para herpes virus, HSV, CMV y EBV, fue negativo. Se detectaron anticuerpos IgM para virus SLE tanto en LCR como en muestra de suero, con seroconversión IgG por neutralización en cultivos celulares y resultados negativos para los demás Flavivirus con circulación en Argentina. Se revisan evidencias sobre la presencia de virus de San Luis en nuestro país, y se señala la importancia de la confirmación diagnóstica y el estudio de otros Flavivirus en casos sospechosos de dengue con presentación grave o atípica. Este trabajo remarca la necesidad de fortalecer tanto la vigilancia epidemiológica del virus SLE, como el control vectorial para prevenir las diferentes infecciones transmitidas por mosquitos y conocer su efecto en Salud Pública en la Argentina.

Saúde reprodutiva em homens com lúpus eritematoso sistêmico Reproductive health in male systemic lupus erythematosus

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Clovis Artur Almeida da Silva

2009-06-01

Full Text Available OBJETIVO: Avaliar a saúde reprodutiva em homens com lúpus eritematoso sistêmico (LES e compará-la com controles saudáveis. MÉTODOS: Vinte e cinco pacientes com LES do sexo masculino foram avaliados com dados demográficos, exame urológico (incluindo parâmetros pubertários e função sexual/erétil, ultrassonografia testicular com Doppler, perfil hormonal, análise seminal, características clínicas e tratamento. O grupo-controle incluiu 25 homens saudáveis. RESULTADOS: A mediana da idade atual foi similar nos pacientes com LES comparada aos controles (26 versus 27 anos, P = 0,756. As frequências de disfunções sexual/erétil foram significativamente maiores nos pacientes com LES em relação aos controles (20% versus 0%, P = 0,0001 e o número de gestações espontâneas foi menor (20% versus 60%, P = 0,0086. Uma tendência de uso infrequente de contraceptivos foi observada em pacientes com LES comparada aos controles (48% versus 76%, P = 0,079. Além disso, as frequências de parâmetros de disfunção gonadal: atrofia testicular avaliada pela ultrassonografia (36% versus 8%, P = 0,037, níveis elevados de FSH e/ou LH (36% versus 0%, P = 0,002 e alterações dos espermatozoides (48% versus 0%, P = 0,0001 foram estatisticamente maiores nos pacientes com LES versus controles. Os pacientes com LES e disfunção sexual/erétil não realizaram atividade sexual no último mês versus 95% dos pacientes sem disfunção (P = 0,0001. Entretanto, nenhuma diferença foi evidenciada nos pacientes com LES com e sem disfunção sexual/erétil em relação a dados demográficos, atividade da doença, dano cumulativo e tratamento. CONCLUSÃO: Este é o primeiro estudo que identificou disfunção sexual/erétil e gonadal em homens lúpicos. Uma abordagem multidisciplinar é essencial para oferecer medidas preventivas para esses pacientes.OBJECTIVE: To assess reproductive health in male systemic lupus erythematosus (SLE patients and compare them with

A combination of computational-experimental study on metal-organic frameworks MIL-53(Al) as sorbent for simultaneous determination of estrogens and glucocorticoids in water and urine samples by dispersive micro-solid-phase extraction coupled to UPLC-MS/MS.

Science.gov (United States)

Gao, Guihua; Li, Sijia; Li, Shuo; Wang, Yudan; Zhao, Pan; Zhang, Xiangyu; Hou, Xiaohong

2018-04-01

In this work, computational and experimental methods were used to study the adsorption of estrogens and glucocorticoids on metal-organic frameworks (MOFs). Computer-aided molecular simulation was applied to predict the adsorption of eight analytes on four MOFs (MIL-101(Cr), MIL-100(Fe), MIL-53(Al), and UiO-66(Zr)) by examining molecular interactions and calculating free binding energies. Subsequently, the four water-stable MOFs were synthesized and evaluated as adsorbents for the target hormones in aqueous solution. As the MOF exhibiting the highest adsorption capacity in both computations and experiments, MIL-53(Al) was chosen as a sorbent to develop a dispersive micro-solid-phase extraction procedure coupled to ultra-performance liquid chromatography tandem mass spectrometry for simultaneous determination of the target analytes in water and human urine samples. Experimental parameters affecting the extraction recoveries, including pH, ionic strength, MIL-53(Al) amount, extraction time, desorption time, and desorption solvent, were optimized. The optimized method provided a linear range of 0.005025-368.6μg/L with good correlation coefficients (0.9982 ≤ r 2 ≤ 0.9992), and limits of detection (S/N = 3) and quantification (S/N = 10) of 0.0015-1.0μg/L and 0.005-1.8μg/L, respectively. The analyte recoveries were in the range of 80.6-98.4% in water samples and 88.4-93.2% in urine samples. Furthermore, MIL-53(Al) showed good stability over 10 extraction cycles (RSD extraction efficiencies for MOFs and targets, providing new directions for the development and utilization of MOFs. Copyright © 2017 Elsevier B.V. All rights reserved.

Luis Moya y las bóvedas tabicadas en la posguerra española

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Adell, Josep Mª

2005-04-01

Full Text Available In the precarious economic conditions prevailing after the Spanish Civil War, tiled vault construction was resumed to economize on steel and capitalize on the cheap labour available at the time.
Luis Moya excelled in this area, re-exploring this construction technique. Moya benefited in this regard from his thorough knowledge of the early twentieth century works of the Guastavinos in New York acquired during his visits to the U.S.A. with Professor Collins.
His architecture featured tiled vaults with medium-sized spans, normally reinforced with exposed internal Basque tiled arches or ribbing on the extrados.
He described his architectural experimentation in this field in a book titled "Bóvedas tabicadas" (tile vaults, one of the few extensive treatises on the subject, which surpassed the papers published earlier by Fornés-Gurrea and Bergós.

Después de la Guerra Civil, y ante la precaria situación económica del pais, se volvió a retomar en España, la construcción tabicada como medio de encomizar acero en la edificación, y aprovechando la mano de obra barata del momento.
Luis Moya destacó en este aspecto, reinvestigando sobre la construcción tabicada siendo perfectamente conocedor de la obra de los Guastavino en Nueva York, de principios de siglo, por sus visitas realizadas acompañadas del Profesor Collins a EEUU.
La arquitectura de Moya destacó por aplicar soluciones de bóvedas tabicadas de mediana luz que normalmente reforzaba empleando arcos tabicados internos vistos, o bien acostillando las bóvedas por sus trasdós.
Esta labor arquitectónica basada en su propia experimentación constructiva, la publicó en el libro "Bóvedas Tabicadas", siendo uno de los pocos tratados amplios sobre este tema existente, superando con él a lo publicado por Fornés-Gurrea y Bergós con anterioridad.

Tecnología lítica y uso diferencial del espacio en Estancia La Suiza, San Luis, Argentina

OpenAIRE

Sario, Gisela Mariela

2017-01-01

El trabajo pretende contribuir, desde la perspectiva de la organización de la tecnología, al conocimiento de las ocupaciones cazadoras-recolectoras que habitaron las inmediaciones de la Sierra de la Estanzuela, en la provincia de San Luis, Argentina. Se explican cómo fueron las secuencias de producción de herramientas en los sitios de la localidad arqueológica Estancia La Suiza, a partir del análisis de los materiales líticos recuperados en excavación y prospecciones sistemáticas. Las metod...