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  1. Recent progress in the determination of gases in metals by emission spectrography (1963); Progres recents dans la determination des gaz dans les metaux par spectrographie d'emission (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Rossi, G; Melamed, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    The Fassel method for analysis of bases in metals was used. By employing a smaller, completely cooled chamber greater sensitivity and lover blank values were obtained. A straight calibration curve, independent of the sample nature was established for oxygen using graphite pellets containing known amounts of ZnO and SnO{sub 2}. The calibration curve for hydrogen was obtained from previously analysed Zircaloy samples. In bath cases a lower limit of sensitivity of 15 {mu}g was attained. (authors) [French] On a utilise la methode Fassel pour l'analyse des metalloides dans les metaux. En employant une chambre de volume reduit avec refroidissement des parois, ou a pu abaisser la limite de sensibilite et reduire le blanc a une valeur negligeable. Une courbe de dosage pour l'oxygene, lineaire jusqu'a environ 15 {mu}g et independante de la nature de l'echantillon, a ete obtenue a partir des melanges oxyde de zinc + graphite et oxyde d'etain + graphite. Une courbe de dosage pour l'hydrogene lineaire jusqu'a 15 {mu}g a ete obtenue en partant d'echantillons de Zircaloy a teneur connue en hydrogene. (auteurs)

  2. Contribution to the chromatography of atmospheric gases (1963); Contribution a la chromatographie des gaz de l'air (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Ghalamsiah, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-06-15

    In the first part, the author studies the gas-phase chromatographic separation of the atmospheric rare gases, of hydrogen, and of some gaseous compounds of carbon (CO, CO{sub 2}, CH{sub 4}) using inactive gases to obtain the most favourable operational conditions far this separation. In the second part, the optimum conditions for detecting non-active gases using an ionisation chamber and a {sup 239}Pu radioactive source emitting 5.15 MeV {alpha} particles are determined. (author) [French] Dans une premiere partie, l'auteur etudie la separation par chromatographie en phase gazeuse des gaz rares de l'air, de l'hydrogene, et de quelques composes gazeux du carbone (CO, CO{sub 2}, CH{sub 4}) en utilisant des gaz inactifs an vue d'obtenir les conditions experimenales les plus favorables en vue de cette separation. Dans une deuxieme partie, les conditions optimales de detection de gaz non actifs a l'aide d'une chambre d'ionisation, en utilisant comme source radioactive du {sup 239}Pu qui emet des particules {alpha} de 5,15 MeV, sont determinees. (auteur)

  3. Dépollution des gaz d'échappement des moteurs diesel au moyen de pots catalytiques Depolluting Exhaust Gases from Diesel Engines by Catalytic Mufflers

    Directory of Open Access Journals (Sweden)

    Goldenberg E.

    2006-11-01

    Full Text Available On présente dans cet article les résultats d'une première série de recherches sur la dépollution des gaz d'échappement des moteurs diesel au moyen de pots catalytiques. L'efficacité des catalyseurs à base de platine pour l'oxydation du monoxyde de carbone et des hydrocarbures imbrûlés a pu être établie par des essais sur banc moteur et sur véhicule. L'emploi de certaines phases actives à base de métaux non nobles permet d'autre part d'abaisser la température de début d'oxydation des particules de suie de 380 à 250 °C environ, avec, entre 250 et 350 °C, élimination de 15 à 20 % des produits piégés. L'essai de divers media filtrants a mis en évidence l'importance des phénomènes d'adsorption des revêtements en alumine et a orienté la recherche vers de nouveaux supports pour filtres catalytiques. This article describes the results of a first series of research on the depollution of exhaust gases from diesel engines by catalytic mufflers. The effectiveness of platinum-base catalysts for the oxidation of carbon monoxide and unburned hydrocarbons was determined by test on an engine test bed and on vehicles on the road. The use of some active non-noble metal phases reduced on the other hand the starting oxidation temperature of soot particulates from 380°C to about 250°C, eliminating 15 to 20% of the trapped products between 250 and 350° C. Tests of different filtering media revealed the importance of adsorption phenomena on alumina coatings and directed research toward new supports for catalytic filters.

  4. Determination experimentale des principales caracteristiques ...

    African Journals Online (AJOL)

    Through the present research work, usual scientific parameters and characteristics of Borassus palm wood from Benin, are determined. Specifically, infradensity, shrinkage coefficient and behaviour, breaking stress in the direction of the fibbers at pulling, compression and bending, are known as well as Young modulus at ...

  5. Device for determining heat capacity of gases and gas mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Nachev, N

    1980-01-01

    This article describes the use of a capillary-flow colorimeter to determine the heat capacity of gases and gaseous mixtures. The research and tests confirm the possibility and advisability of making these measurements. The calorimeters are graduated to allow for the influence of the pressure and temperature of the investigated gas and exchange with the environment.

  6. Determining air distribution during outbursts of gases and rocks

    Energy Technology Data Exchange (ETDEWEB)

    Struminski, A; Sikora, M; Urbanski, J [Politechnika Wroclawska (Poland). Instytut Gornictwa

    1989-01-01

    Discusses use of the KPW-1 iterative and autocorrelation method developed by A. Struminski for forecasting effects of rock bursts on ventilation systems of underground coal mines with increased content of methane or carbon dioxide in coal seams and adjacent rock strata. The method is used for prediction of air flow changes caused by a rock burst accompanied by violent outburst of gases. Directions of air flow, flow rate and concentration of gases emitted from surrounding strata to mine workings are predicted. On the basis of this prediction concentration of gases from a coal outburst is determined for any point in a ventilation network. The prediction method is used for assessing hazards for coal mines during and after a rock burst. Use of the method is explained on the example of the Thorez and Walbrzych coal mines. Computer programs developed for ODRA and IBM/XT computers are discussed. 6 refs.

  7. Energy of solution of rare gases in metals; Energie de dissolution des gaz rares dans les metaux

    Energy Technology Data Exchange (ETDEWEB)

    Blin, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In order to calculate the energy of solution of rare gases in metals, a method which has given good results in the case of solid solutions in metals has been applied. Nevertheless, it was necessary for this, to know the compressibility of gases under conditions which are not feasible in a laboratory. H. Jensen has studied this compressibility in a precise way for the rare gases Ar, Kr, Xe. It has thus been possible to calculate the energy of solution of these gases in different metals. These calculations have been carried out most thoroughly for the case of uranium. (author) [French] Nous avons applique au calcul de l'energie de dissolution des gaz rares dans les metaux, une methode qui a donne de bons resultats dans le cas des solutions solides metalliques. Il fallait pour cela connaitre la compressibilite des gaz rares dans des conditions impossibles a realiser en laboratoire. Cette compressibilite a ete etudiee par H. Jensen de facon precise pour les gaz rares A, Kr, Xe. Nous avons pu, de ce fait, calculer les energies de dissolution de ces gaz dans les differents metaux. Les calculs ont ete faits plus completement dans le cas de l'uranium. (auteur)

  8. Energy of solution of rare gases in metals; Energie de dissolution des gaz rares dans les metaux

    Energy Technology Data Exchange (ETDEWEB)

    Blin, J. [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    In order to calculate the energy of solution of rare gases in metals, a method which has given good results in the case of solid solutions in metals has been applied. Nevertheless, it was necessary for this, to know the compressibility of gases under conditions which are not feasible in a laboratory. H. Jensen has studied this compressibility in a precise way for the rare gases Ar, Kr, Xe. It has thus been possible to calculate the energy of solution of these gases in different metals. These calculations have been carried out most thoroughly for the case of uranium. (author) [French] Nous avons applique au calcul de l'energie de dissolution des gaz rares dans les metaux, une methode qui a donne de bons resultats dans le cas des solutions solides metalliques. Il fallait pour cela connaitre la compressibilite des gaz rares dans des conditions impossibles a realiser en laboratoire. Cette compressibilite a ete etudiee par H. Jensen de facon precise pour les gaz rares A, Kr, Xe. Nous avons pu, de ce fait, calculer les energies de dissolution de ces gaz dans les differents metaux. Les calculs ont ete faits plus completement dans le cas de l'uranium. (auteur)

  9. The method of determination of mercury adsorption from flue gases

    Directory of Open Access Journals (Sweden)

    Budzyń Stanisław

    2017-01-01

    Full Text Available For several recent years Faculty of Energy and Fuels of the AGH University of Science and Technology in Krakow conduct intensive studies on the occurrence of mercury contained in thermal and coking coals, as well as on the possible reduction of fossil-fuel mercury emissions. This research focuses, among others, on application of sorbents for removal of mercury from flue gases. In this paper we present the methodology for testing mercury adsorption using various types of sorbents, in laboratory conditions. Our model assumes burning a coal sample, with a specific mercury content, in a strictly determined time period and temperature conditions, oxygen or air flow rates, and the flow of flue gases through sorbent in a specific temperature. It was developed for particular projects concerning the possibilities of applying different sorbents to remove mercury from flue gases. Test stand itself is composed of a vertical pipe furnace inside which a quartz tube was mounted for sample burning purposes. At the furnace outlet, there is a heated glass vessel with a sorbent sample through which flue gases are passing. Furnace allows burning at a defined temperature. The exhaust gas flow path is heated to prevent condensation of the mercury vapor prior to contact with a sorbent. The sorbent container is positioned in the heating element, with controlled and stabilized temperature, which allows for testing mercury sorption in various temperatures. Determination of mercury content is determined before (coal and sorbent, as well as after the process (sorbent and ash. The mercury balance is calculated based on the Hg content determination results. This testing method allows to study sorbent efficiency, depending on sorption temperature, sorbent grain size, and flue-gas rates.

  10. Development of electrochemical sensor for the determination of toxic gases

    International Nuclear Information System (INIS)

    Ahmed, R.

    1997-01-01

    Monitoring release of flue and toxic gases and vapours of volatile organic toxic substances into the atmosphere is one of the most important problems in environmental pollution control studies particularly in industrial installations in order to avoid poisoning and other health hazards. In industrial areas continuous monitoring of toxic gases and vapours is required for the safety of workers and for this purpose different types of sensors and available such as thermal sensors mass sensors, biosensors, optical sensors and electrochemical sensors. Among all of these sensors electrochemical sensors are most cost-effective, accurate and very good for continuous monitoring. They can be categorized into potentiometric, conductometric, amperometric and voltammetric sensors. Applications of different types of electrochemical sensors are briefly reviewed. Development of polymer membrane and conducting polymers are most important for fabrication of electrochemical sensors, which can analyse up to twenty two gases and vapours simultaneously. Some of the commercially used electrochemical sensors are described. For the determination of hydrogen sulfide an electrochemical sensor was developed. Teflon based conduction polymer membrane was treated with some electrolytes and then silver metal was deposited on one side of the membrane. Metal part side was exposed to gases and the other side was deposited on one side of the membrane metal part side was exposed to gasses and the other side was connected with two electrodes including reference and counter electrodes, whereas metal part acted as working electrode. This system can also me used for the analysis of their gases like SO/sub 2/ etc; because they react at different potentials with the metal to generate the signals. (author)

  11. Behaviour of rare gases in solids at high temperature; Comportement des gaz rares dans les solides a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Blin, J [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In this article a number of simple results regarding the solubility and displacement of rare gases in solids have been assembled. These results were obtained from elementary considerations on highly compressed gases and on dislocations. They provide a better understanding of the now fairly numerous experiments dealing with the swelling of irradiated fuels, this swelling being due to the presence of a high proportion of gases in the fission products. Finally, the chances of success of the various methods which may be devised to diminish the swelling are examined. (author) [French] Nous avons rassemble dans ce texte un certain nombre de resultats simples relatifs a la solubilite et au deplacement des gaz rares dans les solides. Ces resultats ont ete obtenus par des considerations elementaires sur les gaz tres comprimes et sur les dislocations. Ils permettent de mieux comprendre les experiences, maintenant assez nombreuses, qui ont trait au gonflement des combustibles irradies; gonflement qui est du a la presence d'une forte proportion de gaz dans les produits de fission. On examine finalement les chances de succes des differents moyens que l'on peut imaginer pour attenuer le gonflement. (auteur)

  12. Study of gases contained in an Antarctica glacier; Etude des gaz contenus dans un glacier antarctique

    Energy Technology Data Exchange (ETDEWEB)

    Raynaud, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-15

    This report presents a study of gases contained in ice samples taken from a drilling 97.8 meters deep in the coastal zone of Adelie Land (Antarctica). Simultaneously, a study has been made of the composition of the atmospheric air and of the gases extracted in situ from the firn. Carbon dioxyde was analysed by means of gas-phase chromatography and argon, oxygen and nitrogen by means of mass spectrometry. The results obtained show that for the most part the oxygen concentration decreases with an increase in the depth of the drilling. The values range from a maximum of 20,83 per cent of the volume at the surface to a minimum of 19,46 per cent of the volume at a depth of 87 meters. The results also show that the distribution of carbon dioxide concentration does not vary with the depth. These concentrations are either in the same range as or lower than the concentration of CO{sub 2} found in atmospheric air. The different results are discussed. (author) [French] Le present travail rend compte d'analyses de gaz contenus dans des echantillons de glace provenant d'un forage de 97,8 m de profondeur, realise dans la zone cotiere de la Terre Adelie (Antarctique). Parallelement, la composition d'air atmospherique et de gaz extraits in situ du neve a ete etudiee. La chromatographie en phase gazeuse a ete utilisee pour analyser le CO{sub 2} et la spectrometrie de masse pour analyser l'argon, l'oxygene et l'azote. Les resultats obtenus indiquent essentiellement le long du forage: - une decroissance de la teneur en oxygene avec la profondeur, les valeurs extremes etant de 20.83 pour cent en volume a la surface et de 19,46 pour cent en volume a - 87 metres, - une repartition des teneurs en CO{sub 2} sans correlation nette avec la profondeur, ces teneurs etant de l'ordre ou inferieures a la teneur atmospherique. Les differents resultats sont discutes. (auteur)

  13. Recent Experimental Advances to Determine (noble) Gases in Waters

    Science.gov (United States)

    Kipfer, R.; Brennwald, M. S.; Huxol, S.; Mächler, L.; Maden, C.; Vogel, N.; Tomonaga, Y.

    2013-12-01

    In aquatic systems noble gases, radon, and bio-geochemically conservative transient trace gases (SF6, CFCs) are frequently applied to determine water residence times and to reconstruct past environmental and climatic conditions. Recent experimental breakthroughs now enable ● to apply the well-established concepts of terrestrial noble gas geochemistry in waters to the minute water amounts stored in sediment pore space and in fluid inclusions (A), ● to determine gas exchange processes on the bio-geochemical relevant time scales of minutes - hours (B), and ● to separate diffusive and advective gas transport in soil air (C). A. Noble-gas analysis in water samples (transport in the pore space and identifying the origin of bio- and geogenic fluids in (un) consolidated sediments [1]. Advanced techniques that combine crushing and sieving speleothem samples in ultra-high-vacuum to a specific grain size allow to separate air and water-bearing fluid inclusions and thus enables noble-gas-based reconstruction of environmental conditions from water masses as small as 1mg [2]. B. The coupling of noble gas analysis with approaches of gas chromatography permits combined analysis of noble gases and other gases species (e.g., SF6, CFCs, O2, N2) from a single water sample. The new method substantially improves ground water dating by SF6 and CFCs as excess air is quantified from the same sample and hence can adequately be corrected for [3]. Portable membrane-inlet mass spectrometers enable the quasi-continuous and real-time analysis of noble gases and other dissolved gases directly in the field, allowing, for instance, quantification of O2 turnover rates on small time scales [4]. C. New technical developments perfect 222Rn analysis in water by the synchronous the determination of the short-lived 220Rn. The combined 220,222Rn analysis sheds light on the emanation behaviour of radon by identifying soil water content to be the crucial control of 220Rn occurrence in the environment

  14. Apparatus for studying the diffusion of rare gases in stainless steel; Appareil pour etude de la diffusion des gaz rares dans l'acier inoxydable

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J A; Alfille, L [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    This apparatus enables measurements to be carried out on the diffusion of gaseous fission products and of gases in general across thin metallic walls at high temperatures. This work was initially intended to solve the problems involved in systems for detecting the rupture of a fuel element can (D.R.G.) by the diffusion of fission products through the cans at high temperatures. The extension of the work to other fields is envisaged. (author) [French] Cet appareil permet d'effectuer des mesures sur la diffusion des produits de fission gazeux, et des gaz en general, au travers de parois metalliques minces a haute temperature. Au depart, ce procede devait contribuer a resoudre les problemes poses aux systemes detecteurs de rupture de gaine (D.R.G.), par la diffusion des produits de fission au travers des gaines de cartouches a haute temperature. Son extension a d'autres etudes est envisagee. (auteur)

  15. Plasmas pour valorisation totale ou partielle des gaz contenant de l'H2S Plasmas for Total Or Partial Upgrading of H2s Containing Gases

    Directory of Open Access Journals (Sweden)

    Czernichowski A.

    2006-12-01

    Full Text Available Des procédés par plasmas alternatifs au procédé Claus sont proposés pour produire de l'hydrogène et récupérer du soufre à partir des gaz contenant une forte teneur en H2S. Quand la teneur en H2S est moins importante, des techniques plasma peuvent également être utiles pour assister certains étages du procédé classique Claus ou réaliser ce procédé pour des gaz non conventionnels. Les tests allant jusqu'à l'échelle industrielle sont menés dans divers réacteurs à plasmas et les résultats encourageants rapportés de la littérature et de la recherche propre laissent envisager des prochaines applications. Plasma assisted processes are proposed to act as an alternative to the Claus process in order to recover hydrogen and sulphur from high H2S gases. For less concentrated gases plasma techniques may also be inserted into classical Claus plant or may allow treatment of non conventional gases. Up to industrial scale tests are performed using different plasma reactors. The literature-based results as well as our own ones make the future applications quite optimistic.

  16. Mass spectrometric determination of gases in individual coated HTR fuel particles. I

    International Nuclear Information System (INIS)

    Strigl, A.; Bildstein, H.

    1977-01-01

    A method is described which allows the simultaneous determination of fission and reaction gases in individual coated particles at temperatures up to 2 000 0 C. The particles are heated under high-vacuum in a micro resistance-furnace up to the desired temperature. After preselected times the particles are crushed by action of a pneumatic cylinder. The gases liberated are fed into a quadrupole analyzer where they are analyzed in a dynamic mode. A peak selector allows the simultaneous measurement of up to four gases. The method is used routinely for the determination of fission gases (Kr and Xe) and of carbon monoxide which is formed as a reaction gas from oxide fuel. Precision and accuracy are in the order of a few percent. Detection limits for routine measurements are about 10 -7 cm 3 (STP) for Kr and Xe and 2x10 -5 cm 3 (STP) for CO but can be lowered by special techniques. (Auth.)

  17. Determination of Hg concentration in gases by PIXE

    Science.gov (United States)

    Dutkiewicz, E.; van Kuijen, W. J. P.; Munnik, F.; Mutsaers, P. H. A.; Rokita, E.; de Voigt, M. J. A.

    1992-05-01

    A method for determination of the concentration of mercury in the gaseous phase is described. In the first step of the method a stable sulphur-mercury complex is formed. For this purpose sulphur is deposited on a filter and the investigated gas flows through the filter. Millipore filters and the deposition of sulphur from Na2S2O3 * 5H2O solution were found to be most suitable. The amount of Hg absorbed on the filter was determined by PIXE or by NAA in the second step of the method. An optimization of proton energy was performed in the PIXE analysis to obtain the maximal signal-to-background ratio. The detection limit of the method, expressed as the minimal amount of Hg which has to flow through the filter equals to 30 and 2 ng for PIXE and NAA techniques, respectively. Applications of the method are also described.

  18. Determination of dissolved gases in basalt groundwater in the Pasco Basin, Washington

    International Nuclear Information System (INIS)

    Halko, D.J.

    1986-09-01

    The determination of dissolved gases in groundwater is required for complete hydrochemical characterization of the Columbia River Basalt Group beneath the Hanford Site. A gas chromatographic method has been developed for the determination of argon, oxygen, nitrogen, carbon monoxide, carbon dioxide, and methane in groundwater. In addition to a gas chromatograph equipped with thermal conductivity and flame ionization detectors, equipment utilized consists of a purge device that strips these gases from solution for subsequent separation using Molecular Sieve 5A and porous polymer columns. This technique is capable of accommodating pressurized fluid samples collected from the deep aquifers with in situ samplers. The analysis is discussed in detail

  19. Detection of radioactive gases in the CO{sub 2} cooling the reactors G 2 - G 3; Detection des gaz radioactifs dans le CO{sub 2} de refroidissement des piles G2 - G3

    Energy Technology Data Exchange (ETDEWEB)

    Pouthier, J; Rossi, J [Commissariat a l' Energie Atomique, Chusclan (France). Centre de Production de Plutonium de Marcoule

    1968-07-01

    The carbon dioxide cooling the reactors G2 - G3 contains activation gases and fission gases. It is of interest to know their concentration, for example to be able to deduce rapidly the norms which would have to be applied in the case of an incident in the circuit. Gas-phase chromatography is applied daily for carrying out analyses. The chromatogram has separate peaks due to tritium, argon 41, krypton 85 and the 133 and 135 isotopes of xenon. By integrating each peak it is possible to calculate the specific activity of each product. The construction of an apparatus for carrying out continuous measurements is under consideration. (authors) [French] Le gaz carbonique, refroidissant les reacteurs G2 - G3, contient des gaz d'activation et des gaz de fission. Il est interessant de connaitre leur teneur par exemple pour etre en mesure de deduire rapidement les normes qu'il y aurait lieu d'appliquer en cas d'incidents sur le circuit. La methode de chromatographie en phase gazeuse est employee quotidiennement pour faire des analyses. Le chromatogramme se presente sous forme de pics distincts dus au tritium, a l'argon 41, au krypton 85 et aux isotopes 133 et 135 du xenon. L'integration de chaque pic permet de calculer l'activite specifique de chaque compose. Il est envisage de construire un appareil pour des mesures en continu. (auteurs)

  20. Spectral study of the luminescence produced by the excitation of noble gases by alpha-rays; Etude spectrale de la luminescence due a l'excitation des gaz rares par les rayons alpha

    Energy Technology Data Exchange (ETDEWEB)

    Koch, L [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Luminescence spectra of the noble gases He, A, Kr and Xe are studied under excitation by {alpha} rays. It is shown that the energy is transferred from excited levels of these gases to Hg and N{sub 2} impurities for impurity concentrations respectively less than 10{sup 6} and 10{sup 4}. These results confirm previous measurements concerning the period of luminescence and its variations versus nitrogen concentration in noble gases. (author) [French] On etudie les spectres de luminescence des gaz rares, He, A, Kr et Xe excites par une source intense de rayons {alpha}. Le transfert d'energie des etats excites des gaz rares sur les impuretes mercure et azote pour des concentrations respectives de ces impuretes inferieures a 1 ppm et 100 ppm est demontre. Ces resultats confirment les mesures anterieures concernant la duree de luminescence et ses variations avec la concentration d'azote dans les gaz rares. (auteur)

  1. Determination of radon concentration in spring gases with a portable semiconductor detector

    International Nuclear Information System (INIS)

    Endo, K.; Yanaga, M.; Yoshikawa, H.; Horiuchi, K.; Nakahara, H.; Murakami, Y.

    1985-01-01

    A portable integrating radon meter, alpha METER-400, was tested. The instrument detects α-rays of energy greater than 2.59 MeV. With this detector, the concentration of 222 Rn in spring gases at volcanic regions was determined. The results were compared with those observed by the liquid scintillation counting method. (author)

  2. Experimental determination of deflagration velocity and blue cone height for natural gases from Guajira and Cusiana

    International Nuclear Information System (INIS)

    Fernandez Martinez, Alejandro; Piza Molina, Carlos Andres; Vanegas Jaramillo, Gilmar Adoni

    2001-01-01

    In this project the conical flame method was implemented to measure deflagration rate and a direct photography method to measure the height of blue cone for to natural gases with Guajira and Cusiana composition. Besides of these the existent relation between both variables was determined. The information obtained in this work is fundamental, as long as it provides an experimental method that applied to real conditions, allows the characterization of the natural gases of Guajira and Cusiana, witch will be of utility to define criterions of de sing and interchange ability in the commercial and industrial combustion systems

  3. Reduction de la sensation des malaises thermiques: determination ...

    African Journals Online (AJOL)

    La présente étude a pour objet de contribuer à la réduction de la sensation des malaises thermiques à travers la recherche des orientations préférentielles des bâtiments dans les différentes zones du Togo à partir des conditions aérodynamiques et climatiques locales. Les données climatiques à savoir la température, ...

  4. Measuring head for determining the pressure of fission gases released inside bars of nuclear fuel

    International Nuclear Information System (INIS)

    Granata, S.

    1984-01-01

    A measuring head suitable for determining the pressure of fission gases released inside non-instrumented bars of nuclear fuel (which have reached high irradiation levels), and for connection to said bars by a method which allows no escape of said active gases and does not cause appreciable disturbance either to the fuel or to the released fission gases, is disclosed. The head consists of a tubular casing adapted to be welded at one end to the bar, and having a metal bellows at its other end. A pointed metal bar is used to penetrate the bar by a blow to a pin, whereupon pressure variations within the casing are measured by a pressure measuring device having an iron core, the movement of the core, due to such pressure variations, being recorded by a differential transformer. (author)

  5. Agriculture and greenhouse gases emissions reduction; Agriculture et reduction des emissions de gaz a effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    Leguet, B.

    2005-09-15

    In France, the agriculture is the third sector of greenhouse gases emitter. Meanwhile since 1990 this sector poorly reduces its greenhouse gases. It is necessary to find mechanisms which allow the valorization of emissions reduction. In this framework the author presents the specificities of the greenhouse gases emissions of the agricultural sector, the possible incentives of emissions reduction, the reduction projects in France and abroad. (A.L.B.)

  6. Determination of chlorinated hydrocarbons in single and multi component test gases

    Energy Technology Data Exchange (ETDEWEB)

    Giese, U.; Stenner, H. (Paderborn Univ. (Gesamthochschule) (Germany, F.R.). Angewandte Chemie); Ludwig, E.; Kettrup, A. (Paderborn Univ. (Gesamthochschule) (Germany, F.R.). Angewandte Chemie Gesellschaft fuer Strahlen- und Umweltforschung mbH Muenchen, Neuherberg (Germany, F.R.). Inst. fuer Oekologische Chemie)

    1990-11-01

    For comparing the efficiency of active and diffusive sampling methods two diffusive samplers with different properties were used to determine chlorinated hydrocarbons (CH{sub 2}Cl{sub 2}, CHCl{sub 3}, CCl{sub 4}) in single and multi component test gas mixtures. One of the chosen diffusive samplers can also be used for active sampling. In general, good correlations of all tested methods could be observed in the direct comparison of active and diffusive sampling and in the determination of the efficiencies. During the application of active and diffusive sampling methods in multi component test gases of the analytes possible interferences could not be ascertained. (orig.).

  7. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  8. Methodology to determine the efficiency of a beta emitter gases monitor

    International Nuclear Information System (INIS)

    Carvalho, Marcos Rodrigues de

    1995-01-01

    This work presents a methodology developed to determinate the efficiency of air monitors used to measure the concentration of beta emitters noble gases in nuclear power stations. Efficiency values, obtained by means of theoretical computation are compared with experimental values. The experimental part of the work was performed using three different point beta source, to simulate small amounts of gas uniformly distributed in small volume. The comparison shows that theoretical an experimental values agree within 4,2 % for 90 Sr + 90 Y, 204 Tl and 45 Ca beta sources. (author)

  9. DETERMINATION OF CO2 MASSES IN THE EXHAUST GASES OF THE MARINE DIESEL ENGINES

    Directory of Open Access Journals (Sweden)

    Doru COSOFRET

    2016-05-01

    Full Text Available Currently, reducing CO2 emissions that contribute to the greenhouse effect is currently under attention of the relevant international bodies. In the field of maritime transport, in 2011 International Maritime Organization (IMO has taken steps to reduce emissions of CO2 from the exhaust gases of marine diesel engines on ships, by imposing their energy efficiency standards. In this regard, we conducted a laboratory study on a 4-stroke diesel engine naturally aspirated by using to power it diesel and different blends of biodiesel with diesel fuel. The purpose of the study was to determine the formulas for calculating the mass flow rates of CO2 from exhaust gases’ concentrations experimentally determined. Determining the mass flow of CO2 is necessary to calculate the energy efficiency coefficient of the ship to assess the energy efficiency of the board of the limits imposed by the IMO.

  10. The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

    Science.gov (United States)

    Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Mathew; Clark, Jordan F.

    2018-01-01

    Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

  11. The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

    Science.gov (United States)

    Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Matthew; Clark, Jordan F.

    2018-02-01

    Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

  12. Comparison of different methods of assessing the tar content of gases from wood gasification; Vergleich verschiedener Methoden zur Bestimmung des Teergehalts in Gasen aus der Holzvergasung

    Energy Technology Data Exchange (ETDEWEB)

    Moersch, O; Spliethoff, H; Hein, K R.G. [Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen

    1998-09-01

    The authors present a method developed at the Institute of Chemical Engineering and Steam Boiler Technology (IVD) of Stuttgart University for quasi-continuous online measurement of tar concentrations in gases from biomass gasification. The method is compared with other methods in terms of time requirements, accuracy, and cost: Gravimetry, wet chemical analysis, solid phase amino-adsorption (SPA), and online process gas chromatography. The measurements were carried out on the fluidized-bed combustion system of the IVD. Wood was gasified at 800 degrees centigrade with a fuel/air ratio of 0.25. The measured tar concentrations differed widely, i.e. between 0.8 and 6.8 g per cubic metre. (orig.) [Deutsch] In dieser Arbeit wird ein am Institut fuer Verfahrenstechnik und Dampfkesselwesen (IVD) entwickeltes Verfahren zur quasikontinuierlichen Online-Messung des Teergehalts im Gas aus der Biomassevergasung vorgestellt und mit anderen Methoden aus der Literatur im Hinblick auf Zeitaufwand, Genauigkeit und Kosten verglichen. Untersucht wurden dabei eine gravimetrische Methode, die nasschemische Bestimmung, das Solid-Phase-Amino Adsorptionsverfahren (SPA), sowie die Online Analyse mittels Prozess-Gaschromatograph. Die Messungen wurden an der Wirbelschichtvergasungsanlage des IVD durchgefuehrt. Vergast wurde Holz bei 800 C und einer Luftzahl von 0.25. Der mit den verschiedenen Verfahren ermittelte Teergehalt unterscheidet sich zum Teil erheblich. Es ergaben sich Werte zwischen 0.8 und 6.8 g/m{sup 3}. (orig.)

  13. Contribution a l'etude des determinants socioculturels et ...

    African Journals Online (AJOL)

    ... a consisté à l'élaboration des outils de collecte et son administration par les techniques variées ... Les résultats obtenus montrent que les facteurs explicatifs de la ... Thus, within the framework of this research, the comparative analysis of the ...

  14. La socialisation comme determinant des inegalites de reussite en ...

    African Journals Online (AJOL)

    Cet article cherche à expliquer les différences de réussite en éducation ... au Sénégal structure en conséquence une meilleure réussite des garçons au ... enquêtées sont du fait, d'une part, de leur capital en matière de socialisation et ...

  15. Methodology to determine the efficiency of a beta emitter gases monitor; Metodologia para determinacao da eficiencia de um monitor de gases emissores de particulas beta

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Marcos Rodrigues de

    1995-07-01

    This work presents a methodology developed to determinate the efficiency of air monitors used to measure the concentration of beta emitters noble gases in nuclear power stations. Efficiency values, obtained by means of theoretical computation are compared with experimental values. The experimental part of the work was performed using three different point beta source, to simulate small amounts of gas uniformly distributed in small volume. The comparison shows that theoretical an experimental values agree within 4,2 % for {sup 90}Sr + {sup 90}Y, {sup 204}Tl and {sup 45}Ca beta sources. (author)

  16. New results concerning the behaviour of fission gases in in-pile UO{sub 2} at high temperatures; Resultats nouveaux sur le comportement des gaz de fission a haute temperature dans l'UO{sub 2} en pile

    Energy Technology Data Exchange (ETDEWEB)

    Soulhier, R; Schurenkamper, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The authors consider in the first part the various phenomena giving rise to the production of fission gases towards the exterior of nuclear fuels. The following aspects are dealt with: diffusion, for which is considered the influence of the predecessors of the radioactive gases, the fission recoil, atom expulsion along the fission paths and the evaporation. In the second part the authors present the results obtained on UO{sub 2} samples subjected to irradiation at temperatures of between 150 and 2000 deg C: - At low temperatures the variation of the amount produced as a function of the half-life of the isotopes studied shows that recoil is hot the only cause of gas production. - Above 1800 deg C, a weight loss by evaporation has been observed and the influence of this phenomenon on gas liberation has been studied; thus the fraction of {sup 135}Xe liberated at 2000 deg C by processes other than evaporation is of the order of 10 per cent. - The influence of the various mechanism on the overall effect as a function of temperature is discussed. (authors) [French] Dans une premiere partie, les auteurs etudient les differents phenomenes pouvant donner lieu au degagement des gaz de fission hors d'un combustible. Sont traites successivement: la diffusion, pour laquelle on discute l'influence des predecesseurs des gaz radioactifs, le recul de fission, l'expulsion des atomes le long des trajets de fission et l'evaporation. Dans une deuxieme partie ils exposent les resultats obtenus sur des echantillons d'UO{sub 2} portes sous irradiation a des temperatures comprises entre 150 deg C et 2000 deg C: - A basse temperature la variation de la quantite degagee suivant la periode des isotopes etudies montre que le recul n'est pas la seule cause du degagement des gaz. - Au-dessus de 1800 deg C on a note une perte de poids par evaporation et on a evalue l'influence de ce phenomene sur la liberation des gaz: ainsi la fraction du {sup 135}Xe liberee a 2000 deg C par d'autres processus

  17. Mobility of Rb{sup +} and Cs{sup +} ions in gases at high pressures; Mobilite des ions Rb{sup +} et Cs{sup +} dans les gaz a haute pression

    Energy Technology Data Exchange (ETDEWEB)

    Bacconnet, E. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    A theoretical study and mobility measurements have been made of Rb{sup +} and Cs{sup +} ions moving in gases at high pressures (10{sup -2} to 25 kg/cm{sup 2}). The theoretical study has been effected using the results of P. Langevin who considers the ions and molecules as elastic spheres and takes into account the electrical polarization forces. The practical work has been carried out using the Rb{sup +} and Cs{sup +} ions emitted by a thermal source; for the measurement of their velocity the method using an ionic beam cut by four grids was employed. Since the source does not work in atmospheres containing oxygen (even in the combined state) the tests only involved pure gases: nitrogen, argon, helium at pressures of from 10{sup -2} to 12 kg/cm{sup 2}. The overall results show that the Rb{sup +} and Cs{sup +} ionic mobilities are very similar and that for fairly-short times spent by the ions in the gas, the measurement results are in agreement with theory. An increase in these times favours a degradation of the ions, which always leads to a decrease in the mobility. This effect is most marked in helium. The gases argon and nitrogen behave identically towards Rb{sup +} and Cs{sup +} ions. (author) [French] Une etude theorique et des mesures de mobilite ont ete effectuees pour des ions Rb{sup +} et Cs{sup +} se deplacant dans des gaz a haute pression (10{sup -2} a 25 kg/cm{sup 2}). L'etude theorique a ete effectuee en utilisant les resultats de P. Langevin qui assimile les ions et les molecules a des spheres elastiques et tient compte des forces de polarisation electrique. L'etude pratique a ete realisee en utilisant des ions Rb{sup +} et Cs{sup +} emis par une source thermique et pour la mesure de leur vitesse, la methode de coupure du faisceau ionique au moyen de quatre grilles a ete adoptee. La source ne fonctionnant pas dans des atmospheres contenant de l'oxygene (meme a l'etat combine) les essais ont seulement porte sur des gaz purs: azote

  18. Mobility of Rb{sup +} and Cs{sup +} ions in gases at high pressures; Mobilite des ions Rb{sup +} et Cs{sup +} dans les gaz a haute pression

    Energy Technology Data Exchange (ETDEWEB)

    Bacconnet, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1965-07-01

    A theoretical study and mobility measurements have been made of Rb{sup +} and Cs{sup +} ions moving in gases at high pressures (10{sup -2} to 25 kg/cm{sup 2}). The theoretical study has been effected using the results of P. Langevin who considers the ions and molecules as elastic spheres and takes into account the electrical polarization forces. The practical work has been carried out using the Rb{sup +} and Cs{sup +} ions emitted by a thermal source; for the measurement of their velocity the method using an ionic beam cut by four grids was employed. Since the source does not work in atmospheres containing oxygen (even in the combined state) the tests only involved pure gases: nitrogen, argon, helium at pressures of from 10{sup -2} to 12 kg/cm{sup 2}. The overall results show that the Rb{sup +} and Cs{sup +} ionic mobilities are very similar and that for fairly-short times spent by the ions in the gas, the measurement results are in agreement with theory. An increase in these times favours a degradation of the ions, which always leads to a decrease in the mobility. This effect is most marked in helium. The gases argon and nitrogen behave identically towards Rb{sup +} and Cs{sup +} ions. (author) [French] Une etude theorique et des mesures de mobilite ont ete effectuees pour des ions Rb{sup +} et Cs{sup +} se deplacant dans des gaz a haute pression (10{sup -2} a 25 kg/cm{sup 2}). L'etude theorique a ete effectuee en utilisant les resultats de P. Langevin qui assimile les ions et les molecules a des spheres elastiques et tient compte des forces de polarisation electrique. L'etude pratique a ete realisee en utilisant des ions Rb{sup +} et Cs{sup +} emis par une source thermique et pour la mesure de leur vitesse, la methode de coupure du faisceau ionique au moyen de quatre grilles a ete adoptee. La source ne fonctionnant pas dans des atmospheres contenant de l'oxygene (meme a l'etat combine) les essais ont seulement porte sur des gaz purs: azote, argon, helium et pour

  19. Radioactive contamination of foodstuffs: determination of permissible levels; Contamination radioactive des denrees alimentaires: determination des niveaux admissibles

    Energy Technology Data Exchange (ETDEWEB)

    Ledermann, S [Commissariat a l' Energie Atomique, Fontenay- aux-Roses (France). Centre d' Etudes Nucleaires

    1965-07-01

    In a latent air-soil contamination situation, the population would receive 80 per cent of its contamination through foodstuffs. The supervision of this food poses many problems: sampling, radionuclide dosages, etc. It is also necessary to estimate the maximum permissible concentration of radionuclides in foodstuffs, once the maximum exposure limit for the human body has been fixed. The passage of this level to the maximum concentrations is not simple since a) each radionuclide has its own particular effect on the body; b) their concentrations vary from one foodstuff to another, and c) the average amounts of foodstuffs vary from one population to another. Two methods are given here for estimating the maximum permissible concentrations in foodstuffs, together with the first diets likely to become critical when several of them are to be considered simultaneously. The results depend on the way in which the present situation can change to become critical. This evolutionary path can only be estimated approximately. Two methods are therefore given for studying the sensitivity of the results. As an example, a numerical application of these methods using data actually available is given. The data used is naturally incomplete and this will always be true. This application test indicates however two fields in which an improvement is absolutely necessary. 1 - The obtention of multiple observations (simultaneous dosage of at least 2 radionuclides in the same foodstuff, and simultaneous dosage of at least two foodstuffs for the same radionuclide); this assumes a combined effort by the various organisms; 2 - The reaching of an agreement on the dosage methods used by the various organisms since the results actually available are not comparable. (authors) [French] Dans une situation de contamination air-sol latente, la contamination des populations se ferait a 80 pour cent par l'alimentation. Surveiller cette alimentation pose des problemes complexes: echantillonnage, dosage des

  20. Sr{sup 90} determination in calcareous water; Determination du {sup 90}Sr dans des eaux chargees en calcium

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, P; Pardo, G; Wormser, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    The Straub method (ref. 2) for determination of radioactive strontium in water containing calcium is valid within very wide limits, and particularly in the case of residual water from the chemical purification treatment of the radioactive liquid effluent at the C.E.N. Saclay. (author) [French] La methode de Straub (ref. 2) de determination du strontium radioactif dans une eau chargee en calcium est valable dans des limites tres larges et en particulier dans le cas d'eaux residuaires provenant du traitement d'epuration chimique des effluents liquides radioactifs du C.E.N. de Saclay. (auteur)

  1. The determination of accurate dipole polarizabilities alpha and gamma for the noble gases

    Science.gov (United States)

    Rice, Julia E.; Taylor, Peter R.; Lee, Timothy J.; Almloef, Jan

    1989-01-01

    The static dipole polarizabilities alpha and gamma for the noble gases helium through xenon were determined using large flexible one-particle basis sets in conjunction with high-level treatments of electron correlation. The electron correlation methods include single and double excitation coupled-cluster theory (CCSD), an extension of CCSD that includes a perturbational estimate of connected triple excitations, CCSD(T), and second order perturbation theory (MP2). The computed alpha and gamma values are estimated to be accurate to within a few percent. Agreement with experimental data for the static hyperpolarizability gamma is good for neon and xenon, but for argon and krypton the differences are larger than the combined theoretical and experimental uncertainties. Based on our calculations, we suggest that the experimental value of gamma for argon is too low; adjusting this value would bring the experimental value of gamma for krypton into better agreement with our computed result. The MP2 values for the polarizabilities of neon, argon, krypton and zenon are in reasonabe agreement with the CCSD and CCSD(T) values, suggesting that this less expensive method may be useful in studies of polarizabilities for larger systems.

  2. Burnup determination of power reactor fuel elements by gamma spectrometry; Determination par spectrometrie {gamma} du taux d'irradiation des elements combustibles des reacteurs de puissance

    Energy Technology Data Exchange (ETDEWEB)

    Robin, M; Jastrzeb, M; Boisliveau, S; Boyer, R; Vidal, R [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    This report describes a method for determining by {gamma} spectrometry the burn up and the specific power of fuel elements irradiated in power reactors. The energy spectrum of {gamma} rays emitted by fission products is measured by means of a simple equipment using a sodium iodide detector and a multichannel analyzer. In order to extract from the spectrum a quantity proportional to the burn up, it is necessary to: - isolate an activity specific of one emitter,- give the same importance to fissions in uranium and plutonium - take into account the radioactive decay during and after irradiation. One hundred fuel elements were studied and burn up values obtained by {gamma} spectrometry are compared to results given by chemical analyses. Preliminary measurements show that the accuracy of the results is greatly increased by the use of a germanium detector, due to its good resolution. (authors) [French] Ce rapport expose une methode de determination par spectrometrie {gamma} du taux d'irradiation et de la puissance specifique des elements combustibles irradies dans les reacteurs de puissance. Une installation simple utilisant un detecteur d'iodure de sodium et un selecteur multicanaux mesure le spectre en energie du rayonnement {gamma} emis par les produits de fission. Afin d'extraire du spectre une quantite proportionnelle au taux de combustion, il faut: - isoler une activite specifique a un emetteur, - donner la meme importance aux fissions survenues dans l'uranium et le plutonium, - prendre en compte la decroissance radioactive pendant et apres l'irradiation. Les mesures ont porte sur une centaine d'elements combustibles et les taux de combustion obtenus par spectrometrie {gamma} sont compares aux resultats des analyses chimiques. Des mesures preliminaires montrent que l'utilisation d'un detecteur de germanium augmente considerablement la precision des resultats, en raison de son excellente resolution. (auteurs)

  3. Irritant gases

    NARCIS (Netherlands)

    Meulenbelt, J

    Acute inhalation injury can result from the use of household cleaning agents (e.g. chlorine, ammonia), industrial or combustion gases (e.g. sulfur dioxide, nitrogen oxides) or bioterrorism. The severity of the injury is to a great extent determined by the circumstances of exposure. If exposure was

  4. Test plan for determining breathing rates in single shell tanks using tracer gases. Revision 1

    International Nuclear Information System (INIS)

    Andersen, J.A.

    1997-01-01

    This test plan specifies the requirements and conditions for the injection of tracer gas (Helium (He)) into single shell tanks to determine breathing rates using periodic sampling. The eight tanks which have been selected at the time this Test Plan was developed are A-101, AX-102, AX-103, BY-105, C-107, U-103 (U-103 is counted twice, once during the winter months and once during the summer), and U-105. Other tanks to be sampled will be assigned by Pacific Northwest National Laboratory (PNNL) at a later date in the study process as resources allow, the document shall be revised as required. The sampling of headspace for each of these tanks shall be performed using available risers or the Standard Hydrogen Monitoring System (SHMS) cabinet as available. The tank farm vapor cognizant engineer shall assign the injection and sample testing point for each tank and document the point in the field work package. SUMMA TMI canisters, equipped in-line with dual particulate air filters and two silica gel sorbent traps will be used to collect the gas samples. The purpose of dual particulate air filters is to ensure no radioactive particulates are transferred to the SUMMA TMI canisters. The silica gel sorbent traps will effectively eliminate any tritiated water vapor that may be present in the sample gas stream. PNNL shall supply the tracer gases injection system and shall perform the analysis on the headspace samples. TWRS Characterization project shall inject the tracer gas and perform the sampling. Refer to Engineering Task Plan HNF-SD-TWR-ETP-002 for a detailed description of the responsibilities for this task

  5. A study of the fluorescence of the rare gases excited by nuclear particles. Use of the principle for the detection of nuclear radiation by scintillation; Etude de la fluorescence des gaz rares excites par des particules nucleaires. Utilisation pour la detection des rayonnements nucleaires par scintillation

    Energy Technology Data Exchange (ETDEWEB)

    Koch, L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1959-12-15

    In the first part is studied the properties of atoms excited by the passage of {alpha} particles through the various rare gases at atmospheric pressure. A spectral analysis of the emitted light showed that certain impurities play an important part in producing the fluorescence, and it has led to the conclusion that the light emission contains at least two components - one very short - lived due to the direct deexcitation of the rare gas, the other relatively slower due to the energy transfers to the impurity. The measurement of the life-time of the excited states has confirmed this foregoing hypothesis, the rapid part of the impulse is extremely short: less than 2,25.10{sup -9} s in the case of xenon; the slower part has a life-time depending directly on the nitrogen concentration, nitrogen being the impurity giving the largest effect in all cases. The study of rare gases under the influence of an electric field has made it possible to show that the amount of light produced by an {alpha} particle can be multiplied (by 60, for example, in a field of 600 V:cm) so that the luminescent efficiency is greater than in the case of INaTI. In the second part the characteristics of the rare gases acting as scintillators is examined, the most important property being the absence of fluorescence saturation when the intensity of the excitation incident on the gas is very large. This, together with the very short time of scintillation has made it possible to study a certain number of nuclear physical applications (heavy particle energy-measurements, kinetic studies on nuclear reactors, neutron spectroscopy). (author) [French] On etudie dans la premiere partie les proprietes des atomes excites par le passage de particules {alpha} dans les differents gaz rares a la pression atmospherique. L'etude spectrale de la lumiere emise a montre que certaines impuretes jouent un role considerable dans la fluorescence et on a ete amene a penser que l'emission de lumiere comporte au moins deux

  6. Economic Aspects of Air and Gas Cleaning for Nuclear Energy Processes; Aspects Economiques de l'Epuration de l'Air et des Gaz au Cours des Operations Nucleaires; 042d 041a 041e 041d 041e 0414 0; Aspectos Economicos de la Depuracion del Aire y de los Gases en los Procesos de Obtencion de Energia Nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Silverman, Leslie [Harvard School of Public Health, Boston, MA (United States)

    1960-07-01

    ont des effluents toxiques ou nuisibles, qui doivent egalement faire l'objet d'un controle relativement peu onereux. L'auteur du memoire procede a un examen detaille des facteurs qui interviennent dans le prix d'achat et les frais d'exploitation du materiel d'epuration des gaz; il decrit en outre les divers systemes utilises aux Etats-Unis. On s'est naturellement efforce de resoudre le probleme des effluents gazeux et plusieurs systemes ont ete mis au point a cet effet mais on a en outre mesure, en donnees comparables, leur degre d'efficacite. On est ainsi en mesure de proceder, du point de vue economique, a un examen critique des differentes caracteristiques de fonctionnement en ce qui concerne la consommation d'energie, les depenses relatives a l'adsorption, le cout de l'encombrement, les problemes de corrosion et d'autres aspects du fonctionnement des appareils. En execution d'un contrat conclu avec le Laboratoire d'epuration de l'air de l'Universite d'Harvard, la Commission de l'energie atomique des Etats- Unis a entrepris la realisation d'un programme d'evaluation en collaboration avec les diverses entreprises ou personnes privees auxquelles la Commission a octroye des contrats. Cette etude a deja permis de determiner quels sont les facteurs a prendre en consideration pour dresser un schema des couts et analyser ceux-ci; certaines conclusions preliminaires seront ulterieurement formulees. Le memoire donne en outre un apercu des autres etudes economiques qui ont ete effectuees, aux Etats-Unis, sur certains procedes ou applications particuliers. (author) [Spanish] En este trabajo, el autor enuncia las normas basicas a las que ha de ajustarse el control de los efluentes gaseosos y en forma de particulas en las siguientes esferas: produccion de materiales para reactores, separacion de isotopos, elaboracion de elementos combustibles, recuperacion de combustibles y funcionamiento de reactores. Existen asimismo casos (produccion de berilio y zirconio, por ejemplo) en

  7. Freeze dried samples of volcanic gases - a new method for the determination of trace elements by NAA

    International Nuclear Information System (INIS)

    Bichler, M.; Sortino, F.

    1997-01-01

    A new routine technique for the determination of trace elements in volcanic gases by NAA is presented. For time and money saving reasons this method is applicable to samples, collected by the conventional method. This technique uses evacuated glass bottles, partly filled with NaOH solution to absorb acidic gas components and CO 2 , which is the main constituent of the incondensable gas fraction at ambient conditions. The application of NAA to samples collected by this method shows two main sources of difficulties: drying of NaOH without loosing volatile elements of interest (in particular Hg and Se) and the high activities of 24 Na after neutron irradiation. The first can be avoided by liquid irradiation, thereby limiting the irradiation time, the second excludes the determination of short and medium lived nuclides because of the high γ-background due to 24 Na. A new freeze drying technique enables the application of long irradiation times and therefore the use of long-lived activation products for analysis. The samples of volcanic gases were collected at the fumarole fields of La Fossa volcano on the island Vulcano. Southern Italy. This technique allows very sensitive determinations of trace elements in volcanic gases and adds highly valuable information to the understanding and modeling of volcanic gas sources. (orig.)

  8. Application of general methods for the study of porous materials to the determination of the characteristics of barriers; Application des methodes generales d'etudes des corps poreux a la determination des caracteristiques des barrieres

    Energy Technology Data Exchange (ETDEWEB)

    Plurien, P; Charpin, J; Mommejac, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Barriers foreseen for the separation of uranium isotopes by gaseous diffusion must posses pores of about 100 Angstrom radius and as high an output as possible. They should thus be of small but uniform thickness. In view of these conditions it is necessary to adapt the normal methods available for studying porous materials in order to check the characteristics of the prototypes examined. It has been found that only by cross-comparison of data from various methods can progress in the development of different prototypes be followed. The following account consists of two parts: 1) A review of the main experimental methods we have used: a) various absorption methods, b) electron microscopy, c) X-ray studies, d) mercury porosimetry, e) liquid permeability, f) gas permeability, g) measurement of separation efficiency. 2) Comparison of the results obtained using these various methods and their application with a view to acquiring as complete a knowledge as possible of the structure of the barrier. (author) [French] Les barrieres susceptibles d'etre utilisees pour la separation des isotopes de l'uranium, par diffusion gazeuse, doivent presenter des pores de rayon de l'ordre de 100 Angstrom et un debit aussi grand que possible. Elles doivent donc avoir une epaisseur faible et constante. Ces conditions necessitent une adaptation des methodes usuelles d'etude des corps poreux pour controler les caracteristiques des prototypes etudies. Il est apparu que seul le recoupement entre diverses methodes permet de suivre les progres dans la realisation de differents prototypes. L'expose qui va suivre comprend deux parties: 1) Une revue des principales methodes experimentales que nous utilisons: a) differentes methodes d'absorption, b) microscopie electronique, c) rayons X, d) porosimetrie a mercure, e) permeabilite aux liquides, f) permeabilite aux gaz, g) mesure de l'efficacite de separation. 2) Comparaison des differents resultats obtenus par ces diverses methodes et leur application

  9. Analysis of odorous gases with simultaneous GC-MS and sensory determination

    Energy Technology Data Exchange (ETDEWEB)

    Orko, I.; Lehtomaeki, J.; Sandell, E.; Arnold, M. [VTT Chemical Technology, Espoo (Finland). Environmental Technology

    1995-12-31

    Industrial odorous off-gases can consist of hundreds of different compounds giving cause to odour annoyance in the vicinity of the odour-emitting plant. For the identification of the odorous components in the gas, traditional analytical methods are not always sufficient since the odour threshold values cannot often be found in literature. This report describes the development of a GC-MS sniffing port method for identifying odorous compounds in off-gases. In the method the sample is injected into a gas chromatograph and divided into two flows. The compounds in these sample flows are separated in two identical columns and detected simultaneously in a mass spectrometer and by sensory means. The olfactory detections are marked in the iongram and the odorous compounds are identified. Tenax TA adsorbent is generally used for collecting the odorous sample for analysis. The compounds are released from the adsorbent for analysis by thermal desorption. The report also describes a case study where the GC-MS sniffing port method was applied to a gaseous emission from a food factory. Over ten odorous compounds could be identified. (author)

  10. Improvement of heat transfer to gases by mean of electric fields (1962); Etude de l'amelioration des echanges de chaleur dans les gaz au moyen de champs electriques (1962)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1962-07-01

    The effects of electric fields on heat transfer to the following gases: air, argon, nitrogen, carbon dioxyde, helium, hydrogen, were studied in an annular channel, the inner part of which is the heating element. Experiments were made both in free convection and forced convection, the latter case with and without an external source of ionisation. Two causes of improvement of heat transfer were found: electro-convection and ionic convection; the influence of various parameters (electric fields, current of ionisation, temperatures, pressures, flow rate, etc...) is also investigated. Increasing of exchanged power was measured: in free convection this increasing reached 400 per cent and, in forced convection, it was found to be mainly dependent on stream velocity, decreasing from 300 per cent at Re = 6000 to few per cent for Re {>=} 30000 for a given gas pressure. Experiments in pile have shown that the use of an external source of ionisation allowed to obtain the same order of improvement as above but with a voltage much lower. This fact would make easier the use of this process of heat transfer in a channel of a reactor. (authors) [French] On a etudie l'action du champ electrique sur les echanges de chaleur dans les gaz suivants: air, argon, azote, anhydride carbonique, helium, hydrogene, avec un element chauffant cylindrique dans un canal concentrique. Des experiences ont ete effectuees en convection libre et en convection forcee en l'absence et en presence d'une source exterieure d'ionisation. On a distingue deux sortes de mecanismes d'accroissement des echanges, l'un d'electroconvection proprement dite et l'autre de convection ionique, et on precise l'influence des divers parametres (champ electrique, courant d'ionisation, temperature, pression, debit, etc...). On a pu chiffrer les ordres de grandeur des accroissements d'echanges observes qui, en convection libre, atteignent 300 a 400 pour cent et, en convection forcee, dependent beaucoup de la vitesse d

  11. Determination of Henry’s law constant of light hydrocarbon gases at low temperatures

    International Nuclear Information System (INIS)

    Mohebbi, V.; Naderifar, A.; Behbahani, R.M.; Moshfeghian, M.

    2012-01-01

    Highlights: ► Henry’s constants of light hydrocarbon gases are reported at low temperatures. ► Solubility of iso-butane in water at low temperatures (275 K to 293 K) was measured. ► An expression of Krichevsky–Kasarnovsky equation is reported. - Abstract: The solubility of i-butane in water at the low temperatures was measured (274 K to 293 K). Additionally, Henry’s law constants of light hydrocarbons (methane, ethane, propane, i-butane, and n-butane) in water at the low temperatures are reported. A modified equation based on Krichevsky–Kasarnovsky equation is proposed to consider the effect of pressure and temperature on the equation parameters. Results show that Henry’s law constant of the selected components depends on temperature. It is deduced that pressure has a considerable effect on Henry’s law constant for methane, ethane, and propane, whereas this dependency for butanes is negligible.

  12. Note: A dual temperature closed loop batch reactor for determining the partitioning of trace gases within CO2-water systems.

    Science.gov (United States)

    Warr, Oliver; Rochelle, Christopher A; Masters, Andrew J; Ballentine, Christopher J

    2016-01-01

    An experimental approach is presented which can be used to determine partitioning of trace gases within CO2-water systems. The key advantages of this system are (1) The system can be isolated with no external exchange, making it ideal for experiments with conservative tracers. (2) Both phases can be sampled concurrently to give an accurate composition at each phase at any given time. (3) Use of a lower temperature flow loop outside of the reactor removes contamination and facilitates sampling. (4) Rapid equilibration at given pressure/temperature conditions is significantly aided by stirring and circulating the water phase using a magnetic stirrer and high-pressure liquid chromatography pump, respectively.

  13. Study of the formation and of the distribution of dissolved gases and hydrogen peroxide in water from a swimming-pool reactor (triton) (1961); Etude de la formation et de la repartition des gaz dissous et de l'eau oxygenee dans l'eau d'un reacteur piscine (triton) (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Chenouard, J; Rozenberg, J; Dolle, L; Dirian, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    In order to determine experimentally the amount of radiolysis in the swimming-pool reactor Triton, direct measurements have been made of the quantity of radiolysis gas and hydrogen peroxide in the water, at the entry and exit of the core. The concentration distribution of these gases in the reactor was also determined. An explanation is given as to why no gases evolution is seen in the swimming-pool reactors of the C.E.A. The overall amount of radiolysis is zero, and a simple interpretation of this result is possible. The real amount of radiolysis occurring in the reactor core can be calculated. This is in satisfactory agreement with certain measurement mad elsewhere. (authors) [French] Pour determiner experimentalement le taux de radiolyse dans la pile piscine Triton, des mesures directes de la quantite de gaz de radiolyse et d'eau oxygenee dans l'eau a l'entree et a la sortie du coeur ont ete faites. La repartition de la concentration de ces gaz dans la piscine a egalement ete determinee. On explique pourquoi aucun degagement gazeux n'est observe dans les piles piscines du CE.A. Le taux de radiolyse global est nul, et une interpretation simple de ce resultat est possible. Un taux de radiolyse reel dans le coeur du reacteur peut etre calcule. Celui-ci est en accord satisfaisant avec certaines determinations faites ailleurs. (auteurs)

  14. Solubility of gases in 1-alkyl-3methylimidazolium alkyl sulfate ionic liquids: Experimental determination and modeling

    International Nuclear Information System (INIS)

    Bermejo, María Dolores; Fieback, Tobias M.; Martín, Ángel

    2013-01-01

    Highlights: ► The solubility of CO 2 , CH 4 and C 2 H 6 in [emim][EtSO 4 ] is measured with a magnetic suspension balance. ► New data and literature results have been modeled with a Group Contribution equation of state. ► A specific group definition is required to model data of ionic liquids with a [MeSO 4 ] anion. ► Deviations between model and experiments are lower than 10% in most cases. ► Deviations of 34% are observed in the case of the solubility of ethane in the ionic liquid. -- Abstract: The solubility of different gases (carbon dioxide, methane, ethane, carbon monoxide and hydrogen) in ionic liquids with an alkyl sulfate anion has been modeled with the Group Contribution equation of state developed by Skjold-Jørgensen. New gas solubility measurements have been carried out with a high pressure magnetic suspension balance in order to cover pressure and temperature ranges not considered in previous studies and to obtain more experimental information for the correlation of parameters of the equation of state. New solubility measurements include the solubility of carbon dioxide in 1-ethyl 3-methyl imidazolium ethyl sulfate [emim][EtSO 4 ] at temperatures of 298 K and 348 K and pressures ranging from 0.3 MPa to 6.5 MPa, the solubility of methane in [emim][EtSO 4 ] at a temperature of 293 K and pressures ranging from 0.2 MPa to 10.2 MPa, and the solubility of ethane in [emim][EtSO 4 ] at temperatures of 323 K and 350 K and pressures ranging from 0.2 MPa to 4 MPa. Results show that the Group Contribution equation of state can be used to describe the solubility of gases in alkyl sulfate ionic liquids as well as infinite dilution coefficients of alkanes in the ionic liquids, with average deviations between experiments and calculations ranging from 1% to 10% in the case of mixtures with CO 2 , CO, CH 4 and H 2 with the alkyl sulfate ionic liquids to up to 34% in the case of the solubility of ethane in [emim][EtSO 4

  15. Contribution of the renewable energies to the decrease of the greenhouse gases emission for 2010; Contribution des EnR a la reduction des emissions de gaz a effet de serre a l'horizon 2010

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2003-03-01

    To illustrate the renewable energies contribution to the decrease of the greenhouse gases emission in 2010 (19 Mt of CO{sub 2} per year, of greenhouse gases emission avoided), this document presents the different renewable energies sources and the international context of their implementation. Today data and estimations for 2010 are provided. (A.L.B.)

  16. Cumulative exposure to dust and gases as determinants of lung function decline in tunnel construction workers.

    Science.gov (United States)

    Bakke, B; Ulvestad, B; Stewart, P; Eduard, W

    2004-03-01

    To study the relation between lung function decrease and cumulative exposure to dust and gases in tunnel construction workers. A total of 651 male construction workers (drill and blast workers, tunnel concrete workers, shotcreting operators, and tunnel boring machine workers) were followed up by spirometric measurements in 1989-2002 for an average of six years. Outdoor concrete workers, foremen, and engineers served as a low exposed referent population. The between worker component of variability was considerably reduced within the job groups compared to the whole population, suggesting that the workers within job groups had similar exposure levels. The annual decrease in FEV1 in low-exposed non-smoking workers was 21 ml and 24 ml in low-exposed ever smokers. The annual decrease in FEV1 in tunnel construction workers was 20-31 ml higher than the low exposed workers depending on job group for both non-smokers and ever smokers. After adjustment for age and observation time, cumulative exposure to nitrogen dioxide showed the strongest association with a decrease in FEV1 in both non-smokers, and ever smokers. Cumulative exposure to nitrogen dioxide appeared to be a major risk factor for lung function decreases in these tunnel construction workers, although other agents may have contributed to the observed effect. Contact with blasting fumes should be avoided, diesel exhaust emissions should be reduced, and respiratory devices should be used to protect workers against dust and nitrogen dioxide exposure.

  17. Contribution to the study of the desorption of fission gases formed in irradiated uranium oxide; Contribution a l'etude de la desorption des gaz de fission formes dans l'oxyde d'uranium irradie

    Energy Technology Data Exchange (ETDEWEB)

    Berry, J -L; Darras, R; Roger, B [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France)

    1966-09-01

    The release of {sup 133}Xe from irradiated UO{sub 2} has been studied in the temperature range 1300 to 1900 deg C, using various monocrystalline or sintered samples. Up to 1600 deg C, this release is proportional to the square root of the time and thus occurs essentially by diffusion. The apparent diffusion constant D' decreases and the activation energy of the corresponding process increases as the integrated neutron flux received by the fuel increases. As the density of the sintered samples decreases however, the activation energy of the release also decreases, so that the difference between D' values for sintered samples of different densities decreases as the temperature rises. Finally, above 1600 deg C, the fission gas release phenomenon is governed by UO{sub 2} evaporation, and all the different types of oxide studied have similar behaviors, characterized by poor retention of these gases. (authors) [French] La desorption du xenon 133 forme dans le bioxyde d'uranium irradie a ete etudiee dans l'intervalle de 1300 a 1900 C, a l'aide de differents echantillons monocristallins ou frittes. Jusqu'a 1600 C, elle s'effectue proportionnellement a la racine carree du temps, donc essentiellement par diffusion. La pseudo-constante de desorption D' decroit et l'energie d'activation du processus correspondant croit lorsque le flux de neutrons integre recu par le combustible augmente. Cependant, lorsque la densite des frittes diminue, l'energie d'activation de desorption diminue egalement, de sorte que l'ecart entre les valeurs de D' relatives a des frittes de densites differentes se restreint lorsque, la temperature s'eleve. Finalement, au-dessus de 1600 C, l'evaporation de l'UO{sub 2} regit le phenomene de liberation des gaz de fission, et toutes les qualites d'oxyde etudiees presentent alors des comportements voisins a cet egard, caracterises par une mediocre retention de ces gaz. (auteurs)

  18. Greenhouse Gases

    Science.gov (United States)

    ... Production of Hydrogen Use of Hydrogen Greenhouse Gases Basics | | Did you know? Without naturally occurring greenhouse gases, the earth would be too cold to support life as we know it. Without the greenhouse effect, ...

  19. Determination of the separation factor of uranium isotopes by gaseous diffusion; Determination des facteurs de separation des isotopes de l'uranium par diffusion gazeuse

    Energy Technology Data Exchange (ETDEWEB)

    Bilous, O; Counas, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    A 12-stage pilot separation cascade with a low output has been constructed to measure the separation factor of uranium isotopes by gaseous diffusion. The report describes some of the separation results obtained, and also provides information on the time necessary for equilibrium to be established and on the influence of various perturbations on the pressure profile in the cascade. (author) [French] Une cascade pilote de 12 etages de separation a faible debit a ete construite pour mesurer le facteur de separation des isotopes de l'uranium par diffusion gazeuse. Le rapport decrit certains des resultats de separation obtenus et fournit egalement des donnees sur les temps de mise en equilibre et l'influence de diverses perturbations sur le profil des pressions dans la cascade. (auteur)

  20. DATING: A computer code for determining allowable temperatures for dry storage of spent fuel in inert and nitrogen gases

    International Nuclear Information System (INIS)

    Simonen, E.P.; Gilbert, E.R.

    1988-12-01

    The DATING (Determining Allowable Temperatures in Inert and Nitrogen Gases) code can be used to calculate allowable initial temperatures for dry storage of light-water-reactor spent fuel. The calculations are based on the life fraction rule using both measured data and mechanistic equations as reported by Chin et al. (1986). The code is written in FORTRAN and utilizes an efficient numerical integration method for rapid calculations on IBM-compatible personal computers. This report documents the technical basis for the DATING calculations, describes the computational method and code statements, and includes a user's guide with examples. The software for the DATING code is available through the National Energy Software Center operated by Argonne National Laboratory, Argonne, Illinois 60439. 5 refs., 8 figs., 5 tabs

  1. Ground-Based Remote Sensing and Imaging of Volcanic Gases and Quantitative Determination of Multi-Species Emission Fluxes

    Directory of Open Access Journals (Sweden)

    Ulrich Platt

    2018-01-01

    Full Text Available The physical and chemical structure and the spatial evolution of volcanic plumes are of great interest since they influence the Earth’s atmospheric composition and the climate. Equally important is the monitoring of the abundance and emission patterns of volcanic gases, which gives insight into processes in the Earth’s interior that are difficult to access otherwise. Here, we review spectroscopic approaches (from ultra-violet to thermal infra-red to determine multi-species emissions and to quantify gas fluxes. Particular attention is given to the emerging field of plume imaging and quantitative image interpretation. Here UV SO2 cameras paved the way but several other promising techniques are under study and development. We also give a brief summary of a series of initial applications of fast imaging techniques for volcanological research.

  2. Hydrogen isotopic spectral determination in inert gases with the use of light source with contracted discharge

    International Nuclear Information System (INIS)

    Nemets, V.M.; Solov'ev, A.A.

    1981-01-01

    Isotopic-spectral technique for hydrogen determination in helium, neon and argon is developed. It employs a contracted high-frequency discharge as a light source to decrease the distorting effect. of a dummy signal and the ''memory'' effect of the discharge tube. The discharge is realized in a quartz tube approximately 7 mm dia. and gas pressure in it approximately 6x10 4 Pa. The analysis technique comprises sampling of gas, dosed introduction of deuterium into the sample, selection of a mixture portion into the discharge tube, spectroscopic determination of hydrogen isotope ratio and calculation of the sought for hydrogen concentration. The lower boundary of the determined concentrations of hydrogen constitutes 7x10 - 5 , 2x10 - 4 and 4x10 - 4 volumetric per cent in helium, neon, and argon, respectively

  3. Some results on the fluorescence of gases excited by high-energy charged particles; Quelques resultats concernant la fluorescence de gaz excites par des particules chargees de grande energie

    Energy Technology Data Exchange (ETDEWEB)

    Koch, L; Lesureur, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    The essential characteristics of rare gases for use as scintillators are as follows: a very brief period of luminescence, generally less than 10{sup -8} s; a linear response as a function of the energy lost by the nuclear particle in the gas, even in the case of strongly ionising particles (fission fragments). In the gaseous or condensed state therefore, they are of great interest in nuclear physics. (author) [French] Les caracteristiques essentielles des gaz rares en tant que scintillateurs sont: une duree de luminescence tres breve, inferieure a 10{sup -8} s en general; une reponse lineaire en fonction de l'energie perdue par la particule nucleaire dans le gaz, meme dans le cas de particules fortement ionisantes (fragments de fission). A l'etat gazeux ou condense, ils presentent donc un grand interet en physique nucleaire. (auteur)

  4. Study of the equation of state and determination of molecular parameters of some fluorinated gases

    International Nuclear Information System (INIS)

    Morizot, Pierre

    1972-01-01

    Volumetric and dielectric techniques are used to determine non-ideality and molar polarization of UF 6 , MoF 6 , WF 6 and ClF 3 . Comparisons are made between these dielectric non-ideality parameters and those obtained by MAGNUSON and volumetry method. It is demonstrated that dielectric non-ideality parameters are unsettled by an adsorption phenomena on the electrodes. The volumetric second virial coefficients are interpreted with known transport coefficients to determine molecular parameters of the three hexafluorides. Using viscosity data, the existence of a dimerization in the vapor of ClF 3 was demonstrated. Its effect on the observed second virial coefficient was evaluated. (author) [fr

  5. The Determination of Hydrogen Sulfide in Stack Gases, Iodometric Titration After Sulfite Removal.

    Science.gov (United States)

    Robles, E. G.

    The determination of hydrogen sulfide in effluents from coal-fired furnaces and incinerators is complicated by the presence of sulfur oxides (which form acids). Organic compounds also may interfere with or prevent the formation of the cadmium sulfide precipitate or give false positive results because of reaction with iodine. The report presents a…

  6. Detection of high energy gamma radiations with liquid rare gases as scintillators; Detection des rayonnements Gamma de grande energie avec les gaz rares liquides comme scintillateurs

    Energy Technology Data Exchange (ETDEWEB)

    Ho, Phan Xuan

    1965-11-25

    This research thesis reports the study of a sensor based on a liquid scintillator for the detection of high energy (10 to 30 MeV) gamma radiations. The scintillator is a liquefied argon or xenon rare gas. The author first studies the process of energy transfer from the particle to the sensing medium. He addresses the different involved elements and phenomena: electromagnetic radiations (Compton Effect, photoelectric effect, pair production, and total gamma absorption), charged particles (braking radiation, collisions) and application to gamma spectrometry. He describes and discusses the scintillation mechanisms (scintillation of organic and inorganic materials), the general characteristics of scintillators (impurities, converters), and then reports the practical realisation of the sensor. Results are presented and discussed [French] Dans ce travail, nous nous proposons d'etudier une technique. Il s'agit d'un detecteur a scintillateur liquide pour la detection des rayonnements gamma energiques (10 a 30 MeV). Le scintillateur utilise est un gaz rare liquefie argon ou xenon. Nous examinerons d'abord les processus de transfert de l'energie de la particule au milieu detecteur puis les mecanismes de scintillation en general pour pouvoir exploiter au mieux les phenomenes favorables. Nous presenterons ensuite la realisation pratique du detecteur. Ses qualites (et defauts) trouveront leur place dans la fin de ce memoire. Bien qu'a l'heure actuelle, par la methode de Kyropoulos, on puisse faire pousser des gros cristaux d'iodure de sodium, l'utilisation des 'gaz rares' liquefies comme scintillateurs est, grace a la brievete de la scintillation, tres utile lorsqu'on recherche un fort taux de comptage (jusqu'a 10 impulsions par seconde) ou lorsqu'on veut resoudre certains problemes de coincidence. Les cristaux NaI(Tl) de grandes dimensions sont d'un montage facile mais leur manipulation requiert beaucoup de precautions du fait qu'ils supportent tres mal les chocs thermiques

  7. Determination of stresses in a sheath connected to a rod; Determination des contraintes dans une gaine liee a un barreau

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J L; Gauthron, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    Uranium rods introduced into a pile must be protected by impermeable metal canning. Depending on the type of canning adopted, it can be assumed that in certain cases there is a longitudinally rigid connection between this tubular sheath and the rod, either along the whole length (a threaded rod for example) or only at the ends. Even unintentional points of contact, of mechanical or physico-chemical origin, can sometimes be produced accidentally. During pile operation and the resulting variable thermal cycles, the rod and the canning will tend to expand each according to its own expansion law. Given the respective surfaces of rod and canning involved in a cross-section, and the mechanical properties of the two materials considered, it can be legitimately supposed that the canned rod will follow the expansion law of uranium. It follows that the canning, always compelled to follow the expansions of the rod, will be subject to stresses and this study is aimed at their determination. (author) [French] Les barreaux d'uranium introduits dans une pile doivent etre proteges par une gaine metallique etanche. Suivant le mode de gainage adopte, on peut admettre qu'il existe dans certains cas une liaison rigide dans le sens longitudinal entre cette gaine tubulaire et le barreau, sur la totalite de leur longueur (barreau filete par exemple) ou simplement a leurs extremites. Meme s'ils n'ont pas ete provoques, des points d'accrochage, d' origine mecanique ou physico-chimique, peuvent accidentellement nous ramener parfois a ce cas. Lors du fonctionnement de la pile et des cycles thermiques variables qui en resultent, le barreau et la gaine vont tendre a se dilater chacun suivant sa loi de dilatation propre. Etant donne les sections respectives de barreau et de gaine mises en jeu dans une section droite, et les caracteristiques mecaniques des deux materiaux consideres, on peut legitimement admettre que le barreau gaine va suivre la loi de dilatation de l'uranium. Il s'ensuit que la

  8. Determination of splenic blood flow by inhalation of radioactive rare gases

    Energy Technology Data Exchange (ETDEWEB)

    Huchzermeyer, H; Schmitz-Feuerhake, I; Reblin, T [Medizinische Hochschule Hannover (Germany, F.R.). Abt. fuer Nuklearmedizin und Spezielle Biophysik; Medizinische Hochschule Hannover (Germany, F.R.). Abt. fuer Gastroenterologie)

    1977-10-01

    We have evaluated the /sup 133/Xenon inhalation method for the determination of splenic blood flow. In twenty-two healthy persons the blood flow was on average 109 +- 4 ml/100 g x min, which is equivalent to a total blood flow of about 170 ml/min. In patients with chronic fatty liver hepatitis specific blood flow was reduced (81 +- 10 ml/100 g x min) as it was in patients with cirrhotic liver without splenomegaly (75 +- 2 ml/100 g x min.). With increasing weight of the spleen, the total blood flow rises, although specific blood flow is low. Our results obtained by the /sup 133/Xenon inhalation method are similar to results obtained by others using intraarterial injection of tracer gas. The advantages of the inhalation method as a non-traumatic method are: 1) the stress for the patient is very small; 2) blood flow measurements can be repeated within short periods of time. We consider for the present the /sup 133/Xenon inhalation method to be the method of choice for the determination of the splenic blood flow.

  9. Electronegative gases

    International Nuclear Information System (INIS)

    Christophorou, L.G.

    1981-01-01

    Recent knowledge on electronegative gases essential for the effective control of the number densities of free electrons in electrically stressed gases is highlighted. This knowledge aided the discovery of new gas dielectrics and the tailoring of gas dielectric mixtures. The role of electron attachment in the choice of unitary gas dielectrics or electronegative components in dielectric gas mixtures, and the role of electron scattering at low energies in the choice of buffer gases for such mixtures is outlined

  10. A Gas Chromatographic Method for the Determination of Bicarbonate and Dissolved Gases

    Directory of Open Access Journals (Sweden)

    John H. Loughrin

    2017-11-01

    Full Text Available A gas chromatographic method for the rapid determination of aqueous carbon dioxide and its speciation into solvated carbon dioxide and bicarbonate is presented. One-half mL samples are injected through a rubber septum into 20-mL vials that are filled with 9.5 mL of 0.1 N HCl. A one mL portion of the headspace is withdrawn and injected onto a gas chromatograph equipped with a thermal conductivity detector. Using the dimensionless Henry's constant for carbon dioxide and an adaptation of the Henderson-Hasselbalch equation, carbon dioxide in the samples can be categorized among solvated, bicarbonate, and carbonate forms. Natural water samples as well as wastewater from a municipal sewage treatment plant and a swine rearing operation were analyzed by this method and the results compared favorably to those obtained by titration. Samples stored for up to 5 weeks showed no significant changes in carbon dioxide concentrations. In addition, using flame ionization and electron capture detectors, methane and nitrous oxide concentrations in the samples were also measured.

  11. Influence of atmospheric 14CO2 on determination of the ratio of biogenic carbon to fossil one in exhaust gases using accelerator mass spectrometry. Experimental evaluation for industrial flue gases

    International Nuclear Information System (INIS)

    Yunoki, Shunji; Saito, Masaaki; Nagakawa, Yoshiyasu

    2012-01-01

    The influence of atmospheric 14 CO 2 was evaluated on the determination of biogenic carbon ratios in industrial flue gases using accelerated mass spectrometry(AMS). Bioethanol, n-hexane, and their mixtures were combusted with a four-stroke engine, and 14 CO 2 in exhaust gases was analyzed by AMS. The experimental biogenic carbon ratio determined by ASTM D6866 method was 1.2 times higher than the theoretical value of mixed fuel containing 3.18% biogenic carbons. In general, the influence of atmospheric 14 CO 2 taken in combustion gases is neglected. It seems that the error cannot be neglected under international trading of emission allowances, where a large amount of carbons in the fuel were evaluated. The experimental value became to be the theoretical value by subtracting the amount of atmospheric 14 C from that of the samples. As the contents of biofuel increased, the experimental biogenic carbon ratios reached the theoretical values and the influence of atmospheric 14 CO 2 decreased. We recommend that the influence of atmospheric 14 CO 2 should be corrected when fuel samples contain low amounts of 14 C. (author)

  12. Elements for a policy of greenhouse effect gases reduction; Elements pour une politique de reduction des emissions de gaz a effet de serre

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-01-15

    In the framework of the ''Grenelle de l'environnement'' on the fight against the greenhouse effect gases, the authors aim to offer propositions and recommendations for the future energy policy. They explain the possible confusions. They discuss the economic efficiency of propositions of CO{sub 2} emissions reduction, the actions propositions in the different sectors and the axis of research and development. (A.L.B.)

  13. determinants de l'adoption et impact des varietes ameliorees sur la ...

    African Journals Online (AJOL)

    ACSS

    C'est ainsi que la recherche a créé des nouvelles variétés ... La recherche en économie de la production agricole a montré que les taux d'adoption et les facteurs influençant la décision des agriculteurs d'adopter une technologie agricole varient fortement entre ..... des agriculteurs sur l'innovation sont fortement liées aux ...

  14. Applications of Qualitative Microanalysis to the Determination of Secondary Species Associated with Uranium; Application de la microanalyse qualitative a la determination des especes secondaires d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Agrinier, H

    1959-02-01

    Microanalytical techniques are described which allow rapid determinations of secondary species associated with uranium. They consist in exposing the constituent elements of the ores by means of characteristic microchemical reactions. Because of their rapidity and the small amount of apparatus needed, these techniques can be used either in the field or in the laboratory. (author) [French] Les techniques de microanalyse decrites dans cet ouvrage permettent la determination rapide des especes secondaires d'uranium. Elles consistent a mettre en evidence les elements constitutifs des mineraux par des reactions microchimiques caracteristiques. En raison de leur rapidite et du peu de materiel qu'elles necessitent, ces techniques peuvent etre utilisees aussi bien sur le terrain qu'au laboratoire. (auteur)

  15. Greenhouse Gases

    Science.gov (United States)

    ... also produced by human activities. Some, such as industrial gases, are exclusively human made. What are the types ... Carbon dioxide (CO2) Methane (CH4) Nitrous oxide (N2O) Industrial gases: Hydrofluorocarbons (HFCs) Perfluorocarbons (PFCs) Sulfur hexafluoride (SF6 Nitrogen ...

  16. Measurement of the activity of beta emitting gases using an ionisation chamber; Mesure de l'activite des gaz emetteurs beta au moyen d'une chambre d'ionisation

    Energy Technology Data Exchange (ETDEWEB)

    Lebouleux, P [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France)

    1962-07-01

    An ionization chamber was developed for measuring directly the activity of a {beta}-emitting gas whatever the gas may be. The following two parameters are defined and determined: p, the average specific ionization produced by a {beta} disintegration, and i, the average {beta} path in the chamber. It was shown, during the determination of i, that the {beta} particles are reflected on the walls of the ionization chamber when the latter are made of a high atomic number material. It was possible to eliminate this effect by constructing an electrode chamber made of graphite. With this chamber a direct measurement can be made of the activity of a gaseous {beta} emitter with a precision of about {+-}10%. Some applications are given of the graphite electrode chamber (calibration of the chambers built industrially and determination of the activation cross section of a gaseous emitter). It was possible to determine the activation cross section of {sup 134}Xe; a value of 0.18 {+-} 0.03 barn was found. (author) [French] Le but de l'etude est de realiser une chambre d'ionisation permettant d'effectuer une mesure directe de l'activite d'un gaz emetteur {beta} quel que soit l'emetteur considere. On definit et l'on determine les deux parametres suivants: p: ionisation specifique moyenne produite par une desintegration {beta}. La determination est effectuee par une methode graphique, i: moyenne des parcours des {beta} dans la chambre. La determination est effectuee experimentalement par introduction dans la chambre d'un gaz radioactif dont on peut calculer l'activite. On a mis en evidence, au cours de la determination de i, la reflexion des particules {beta} sur les parois des chambres d'ionisation lorsque celles-ci sont constituees d'un materiau de numero atomique eleve. La construction d'une chambre a electrodes de graphite nous a permis d'eliminer ce phenomene. Avec cette chambre, on effectue une mesure directe de l'activite d'un emetteur {beta} gazeux avec une precision de l

  17. Determination of elements in citrus leaves; Dosage des elements dans les feuilles de citrus

    Energy Technology Data Exchange (ETDEWEB)

    Masozera, C.; Compernolle, G. van; Brandstetr, J.; Krivanek, M. [Centre nucléaire TRICO, Kinshasa (Congo, The Democratic Republic of the); Université Lovanium, Kinshasa (Congo, The Democratic Republic of the)

    1970-01-15

    In many agricultural stations and farms most of the problems encountered generally reduce to questions of diminished yield. This may be due to a number of factors, including soil exhaustion and the application of fertilizers of unsuitable formula. The chemical impoverishment of the soil is due to the leaching-out phenomenon, i- e. the washing out of bases, and to the ''exportation'' of fertilizer elements in the form of crops in years when nothing has been returned to the soil. These losses have a particularly adverse effect if the parent rock does not contain sufficient mineral reserves to compensate for them by a slow alteration process. Such impoverishment is revealed by soil and foliar analyses. The authors have attempted to determine the content in citrus plants of the following elements: Mn, P, Cu, Cl and K (the latter on three samples only). After collection, the samples are treated by Bransolten's method (Rapport de Recherche TRICO № 15/1968), dried for at least 12 hours at 105°C, followed by pulverization of the leaves, after which the determination is carried out. The determination of Mn and Cl is very simple, as is that of Cu. The latter is determined by activation with slow neutrons in order to avoid Zn formation. The phosphorus content is determined by measuring the beta-radiation emitted by the radioactive elements. In this case particular precautions must be taken to ensure that the same layer is used for the samples and the standards, since beta-radiation is absorbed by these layers. For the K and Na determinations thermal neutrons are used for activation and a Ge(Li) detector for measurement of the gamma-spectra. Because of the high resolution of the detector, the two elements can be determined without separation. (author) [French] La plupart des problèmes que l’on rencontre dans plusieurs stations ou exploitations agricoles se résument généralement à une diminution de rendement. Cette dernière peut être provoquée par plusieurs

  18. Submarine Alkalic Lavas Around the Hawaiian Hotspot; Plume and Non-Plume Signatures Determined by Noble Gases

    Science.gov (United States)

    Hanyu, T.; Clague, D. A.; Kaneoka, I.; Dunai, T. J.; Davies, G. R.

    2004-12-01

    Noble gas isotopic ratios were determined for submarine alkalic volcanic rocks distributed around the Hawaiian islands to constrain the origin of such alkalic volcanism. Samples were collected by dredging or using submersibles from the Kauai Channel between Oahu and Kauai, north of Molokai, northwest of Niihau, Southwest Oahu, South Arch and North Arch volcanic fields. Sites located downstream from the center of the hotspot have 3He/4He ratios close to MORB at about 8 Ra, demonstrating that the magmas erupted at these sites had minimum contribution of volatiles from a mantle plume. In contrast, the South Arch, located upstream of the hotspot on the Hawaiian Arch, has 3He/4He ratios between 17 and 21 Ra, indicating a strong plume influence. Differences in noble gas isotopic characteristics between alkalic volcanism downstream and upstream of the hotspot imply that upstream volcanism contains incipient melts from an upwelling mantle plume, having primitive 3He/4He. In combination with lithophile element isotopic data, we conclude that the most likely source of the upstream magmatism is depleted asthenospheric mantle that has been metasomatised by incipient melt from a mantle plume. After major melt extraction from the mantle plume during production of magmas for the shield stage, the plume material is highly depleted in noble gases and moderately depleted in lithophile elements. Partial melting of the depleted mantle impregnated by melts derived from this volatile depleted plume source may explain the isotopic characteristics of the downstream alkalic magmatism.

  19. Fission gas pressure build-up and fast-breeder economy; Accumulation de la pression des gaz de fission et economie des reacteurs surgenerateurs a neutrons rapides; Nakoplenie davleniya gazov produktov deleniya i ehkonomika reaktorov-razmnozhitelej na bystrykh nejtronakh; Aumento de la presion de los gases de fision y economia de los reactores reproductores rapidos

    Energy Technology Data Exchange (ETDEWEB)

    Engelmann, P [Kernforschungszentrum, Karlsruhe (Germany)

    1962-03-15

    Fuel-cycle costs and doubling time of fast-breeder reactors are strongly affected by the fuel-burn-up obtainable. Use of oxide or carbide fuel offers the possibility of reaching a burn-up of 100 000 MWd/t. In fuel-clad elements, a limiting factor is the fission-gas-pressure build-up. At the high burn-up considered, an appreciable fraction of the fission gases gets into the pores and thus contributes to the pressure on the can. Starting from the known fission-product yields and decay chains, gas production and pressure build-up have been calculated. Three physical models have been employed in calculating the pressure acting upon the can : the gas is contained either in interconnected pores, in separate pores, or in a central hole. The pressure-dependence upon free volume (fuel density) and temperature will be discussed. Cans made of high-strength materials as Ineonel-X and molybdenum could stand the fission-gas pressure at operating temperatures. Unfortunately, these materials have higher absorption cross-sections than stainless steel. Results of a multi-group calculation are given, showing the effect of using these can materials and of decreasing the fuel density on critical mass and breeding ratio in small and medium-size breeders. (author) [French] Le cout du cycle de combustible et la periode de doublement des reacteurs surgenerateurs a neutrons rapides dependent etroitement du taux de combustion. En utilisant pour combustible un oxyde ou un carbure, on peut atteindre un taux de combustion de 100 000 MW j/t. Avec des combustibles gaines, l'accumulation de la pression des gaz de fission est un facteur limitatif. Pour le fort taux de combustion envisage, une fraction non negligeable des gaz de fission penetre dans les interstices et contribue ainsi a la pression sur la gaine. A partir des rendements en produits de fission et des chaines de desintegration connus, l'auteur a calcule la production de gaz et l'accumulation de pression. Pour calculer la pression

  20. Indirect Determination of Half-Lives of Short-Lived Fission Gases Using a Gas Flow Method; Determination Indirecte des Courtes PeRiodes de Produits de Fission Gazeux, par une Methode a Courant Gazeux; 041a 041e 0421 0412 0415 041d 041d 041e 0415 041e 041f 0420 0415 0414 0415 041b 0415 041d 0418 0415 041f 0415 0420 0418 041e 0414 041e 0412 041f 041e 041b 0423 0420 0410 0421 041f 0410 0414 0410 041a 041e 0420 041e 0422 041a 041e 0416 0418 0412 0423 0429 0418 0425 0413 0410 0417 041e - 041e 0411 0420 0410 0417 041d 042b 0425 041f 0420 041e 0414 0423 041a 0422 041e 0412 0414 0415 041b 0415 041d 0418 042f 0421 0418 0421 041f 041e 041b 042c 0417 041e 0412 0410 041d 0418 0415 041c 041c 0415 0422 041e 0414 041e 0412 0413 0410 0417 041e 0412 041e 0413 041e 041f 041e 0422 041e 041a 0410 ; Determinacion Indirecta del T 1/2 de los Cases de Fision de Periodo Corto por un Metodo de Circulacion

    Energy Technology Data Exchange (ETDEWEB)

    Patzelt, P.; Herrmann, G. [Institut fuer Anorganische Chemie und Kernchemie der Universitaet Mainz, Mainz, Federal Republic of Germany (Germany)

    1965-07-15

    Since the investigation of charge distribution in nuclear fission requires the determination of primary yields of individual fission products, which in most cases are either short-lived themselves or grow from shortlived precursors, very rapid and effective separations of neighbouring members of a fission chain have to be carried out. Making use of the extremely high emanating power of certain uranium compounds, separations are performed most easily for the fission gases In more than a dozen fission-product chains. Yield calculations as well as the effective emanating power of thick target layers, however, may be influenced considerably by the half-life data of the gases. Therefore the half-lives of the krypton and xenon isotopes Kr{sup 89}-Kr{sup 93} and Xe{sup 137}- X{sup 143} have been determined with great precision by using a rate-of-flow method in connection with an improved charged-electrode technique. Measurements were made via the active deposit of long-lived decay products on the electrodes. Flow- rare, irradiation time, cooling period and counting arrangements were chosen in such a way that measurements of individual daughter products became strongly favoured. In some cases, for reasons of selectivity, radiochemical separations proved to be indispensable. Results obtained are: Kr{sup 89}, 3.11 {+-} 0.06 min: Kr{sup 90}, 32.1 {+-} 0.8 s; Kr{sup 91}, 8.36 {+-} 0.15 s; Kr{sup 92}, 1,92 {+-} 0.07 s; Kr{sup 93}, 1.17 {+-} 0.04 s; Xe{sup 137}, 3.87 {+-} 0.15 min; Xe{sup 138}, 14.5 {+-} 0.5 min; Xe{sup 139}, 40.4 {+-} 1.3 s: Xe{sup 140}, 13.33 {+-} 0.27s; Xe{sup 141}, 1.70 {+-} 0.05s; Xe{sup 142}, 1.15 {+-} 0.04s- and Xe{sup 143}, 0.96 {+-} 0.02s. The half-lives were obtained by extrapolating the appropriate {beta}-decay curves or decay curves of y-peaks. The data listed are average values of a number of runs, resulting from a W{sub i} {approx} 1/o{sup 2} weighting procedure. All calculations were made at the computer centre of Mainz University. (author

  1. New determination of the vapour pressures of the isotopes of neon; Nouvelles determinations des tensions de vapeur des isotopes du neon

    Energy Technology Data Exchange (ETDEWEB)

    Roth, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1960-03-15

    We have undertaken an experimental reinvestigation of the vapor pressures of the neon isotopes over the temperature range 16.30-30.1 deg. K. Measurements were made by differential manometry in a Giauque-Johnston type cryostat modified for temperature stability. The New sample contained 99.9 % Ne{sup 20} and the Ne{sup 22} sample contained 72,2 % Ne{sup 22}. Extrapolation to pure Ne{sup 20} and Ne{sup 22} can be made with sufficient accuracy by the use of Raoult's law. Our results are in substantial agreement with those of Keesom and Haantjes. At 20 deg. K, where the scatter in our data is an order of magnitude smaller than in the data of Keesom and Haantjes, we find In P{sub Ne{sup 2}{sup 0}}/P{sub Ne{sup 2}{sup 2}} is 6 % larger than the smoothed line given by them. For solid neon, our data can be represented to a high accuracy by a Debye harmonic lattice with {theta}{sub D} (Ne{sup 20}) = 74.6 deg. K. The result may be compared with the value obtained by Henshaw from the Debye-Waller temperature factor, {theta}{sub D} = 73 deg. K, and with the recent calculation of the zero point energy of Ne by Bernardes, from which he obtains {theta}{sub D} 8E{sub {theta}}/9R = 73 deg.. K. (author) [French] On a construit un appareillage dont le principe est derive de celui des instruments decrits par GIAUQUE et EGAN ou par H.L. JOHNSTON qui a permis d'etendre le domaine des mesures de tension de vapeur des isotopes du Neon entre 16,30 et 32 deg. K environ. Le rapport des pressions extremes atteintes est ainsi multiplie par plus de 40 pour le neon ordinaire qui servait de reference et de thermometre. L'appareil, adapte en particulier au travail sous pressions elevees, permet, de plus, de travailler sur de relativement petites quantites totales de gaz - environ 500 cm{sup 3} suffisent dans l'intervalle de pression evoque. La stabilite de temperature obtenue peut etre tres bonne surtout lorsque l'on travaille dans la phase liquide; dans ce cas, les variations totales de

  2. New determination of the vapour pressures of the isotopes of neon; Nouvelles determinations des tensions de vapeur des isotopes du neon

    Energy Technology Data Exchange (ETDEWEB)

    Roth, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1960-03-15

    We have undertaken an experimental reinvestigation of the vapor pressures of the neon isotopes over the temperature range 16.30-30.1 deg. K. Measurements were made by differential manometry in a Giauque-Johnston type cryostat modified for temperature stability. The New sample contained 99.9 % Ne{sup 20} and the Ne{sup 22} sample contained 72,2 % Ne{sup 22}. Extrapolation to pure Ne{sup 20} and Ne{sup 22} can be made with sufficient accuracy by the use of Raoult's law. Our results are in substantial agreement with those of Keesom and Haantjes. At 20 deg. K, where the scatter in our data is an order of magnitude smaller than in the data of Keesom and Haantjes, we find In P{sub Ne{sup 2}{sup 0}}/P{sub Ne{sup 2}{sup 2}} is 6 % larger than the smoothed line given by them. For solid neon, our data can be represented to a high accuracy by a Debye harmonic lattice with {theta}{sub D} (Ne{sup 20}) = 74.6 deg. K. The result may be compared with the value obtained by Henshaw from the Debye-Waller temperature factor, {theta}{sub D} = 73 deg. K, and with the recent calculation of the zero point energy of Ne by Bernardes, from which he obtains {theta}{sub D} 8E{sub {theta}}/9R = 73 deg.. K. (author) [French] On a construit un appareillage dont le principe est derive de celui des instruments decrits par GIAUQUE et EGAN ou par H.L. JOHNSTON qui a permis d'etendre le domaine des mesures de tension de vapeur des isotopes du Neon entre 16,30 et 32 deg. K environ. Le rapport des pressions extremes atteintes est ainsi multiplie par plus de 40 pour le neon ordinaire qui servait de reference et de thermometre. L'appareil, adapte en particulier au travail sous pressions elevees, permet, de plus, de travailler sur de relativement petites quantites totales de gaz - environ 500 cm{sup 3} suffisent dans l'intervalle de pression evoque. La stabilite de temperature obtenue peut etre tres bonne surtout lorsque l'on travaille dans la phase liquide; dans ce cas, les

  3. Late production of hydrocarbon gases in sedimentary basins: kinetic and isotopic study; Genese tardive des gaz hydrocarbures dans les bassins sedimentaires: etude cinetique et isotopique

    Energy Technology Data Exchange (ETDEWEB)

    Lorant, F.

    1999-06-23

    the mechanisms of cracking and the isotopic processes. Following this concept, a general class-compound model for the production and the degradation of oil and gas, including the calculation of the isotopic compositions, was set up. The kinetic scheme, based on that proposed by Behar et at. (1992), comprises 10 first-order reactions whose pre exponential factors (A) are not all the same. The various kinetic and isotopic parameters were determined on the basis of pyrolysis experiments performed on an immature Type II kerogen. The first simulations at low temperature show that this model can reproduce isotopic trends that are consistent with natural observations. However the current uncertainty on the isotopic parameters does not yet allow a confident utilization of the model to predict the {delta}{sup 13}C of hydrocarbon gases is the geological conditions. (author)

  4. Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques

    Energy Technology Data Exchange (ETDEWEB)

    Messager, C

    2007-07-15

    build up a new system to measure continuously CO{sub 2} (or CO), CH{sub 4}, N{sub 2}O and SF{sub 6} mixing ratios. It is based on a commercial gas chromatograph (Agilent 6890N) which have been modified to reach better precision. Reproducibility computed with a target gas on a 24 hours time step gives: 0.06 ppm for CO{sub 2}, 1.4 ppb for CO, 0.7 ppb for CH{sub 4}, 0.2 ppb for N{sub 2}O and 0.05 ppt for SF{sub 6}. The instrument's run is fully automated, an air sample analysis takes about 5 minutes. In July 2006, I install instrumentation on a telecommunication tall tower (200 m) situated near Orleans forest in Trainou, to monitor continuously greenhouse gases (CO{sub 2}, CH{sub 4}, N{sub 2}O, SF{sub 6}), atmospheric tracers (CO, Radon-222) and meteorological parameters. Intake lines were installed at 3 levels (50, 100 and 180 m) and allow us to sample air masses along the vertical. Continuous measurement started in January 2007. I used Mace Head (Ireland) and Gif-sur-Yvette continuous measurements to estimate major greenhouse gases emission fluxes at regional scale. To make the link between atmospheric measurements and surface fluxes, we need to quantify dilution due to atmospheric transport. I used Radon-222 as tracer (radon tracer method) and planetary boundary layer heights estimates from ECMWF model (boundary layer budget method) to parameterize atmospheric transport. In both cases I compared results to available emission inventories. (author)

  5. Greenhouse gases regional fluxes estimated from atmospheric measurements; Estimation des flux de gaz a effet de serre a l'echelle regionale a partir de mesures atmospheriques

    Energy Technology Data Exchange (ETDEWEB)

    Messager, C

    2007-07-15

    build up a new system to measure continuously CO{sub 2} (or CO), CH{sub 4}, N{sub 2}O and SF{sub 6} mixing ratios. It is based on a commercial gas chromatograph (Agilent 6890N) which have been modified to reach better precision. Reproducibility computed with a target gas on a 24 hours time step gives: 0.06 ppm for CO{sub 2}, 1.4 ppb for CO, 0.7 ppb for CH{sub 4}, 0.2 ppb for N{sub 2}O and 0.05 ppt for SF{sub 6}. The instrument's run is fully automated, an air sample analysis takes about 5 minutes. In July 2006, I install instrumentation on a telecommunication tall tower (200 m) situated near Orleans forest in Trainou, to monitor continuously greenhouse gases (CO{sub 2}, CH{sub 4}, N{sub 2}O, SF{sub 6}), atmospheric tracers (CO, Radon-222) and meteorological parameters. Intake lines were installed at 3 levels (50, 100 and 180 m) and allow us to sample air masses along the vertical. Continuous measurement started in January 2007. I used Mace Head (Ireland) and Gif-sur-Yvette continuous measurements to estimate major greenhouse gases emission fluxes at regional scale. To make the link between atmospheric measurements and surface fluxes, we need to quantify dilution due to atmospheric transport. I used Radon-222 as tracer (radon tracer method) and planetary boundary layer heights estimates from ECMWF model (boundary layer budget method) to parameterize atmospheric transport. In both cases I compared results to available emission inventories. (author)

  6. Direct determination of enthalpies of solid phase reactions by immersion method; Determination directe des enthalpies de reaction en phase solide par une methode de plongee

    Energy Technology Data Exchange (ETDEWEB)

    Roux, A; Richard, M; Eyraud, L; Stevanovic, M; Elston, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    It is not generally possible to measure the enthalpy change corresponding to solid phase reactions using the dynamic differential thermal analysis method because these reactions are usually too slow at the temperature of operation of present equipment. A ballistic differential thermal analysis apparatus has been developed which is based on an immersion-compensation method; it overcomes the difficulties previously encountered. This apparatus has been used after calibration for determining the enthalpies of formation of calcium and cadmium titanates. and also the Wigner energies of BeO, MgO and Al{sub 2}O{sub 3} samples irradiated at variable dose at a temperature of under 100 deg. C. (authors) [French] Il n'est generalement pas possible de mesurer la variation d'enthalpie correspondant aux reactions en phase solide par la methode d'analyse thermique differentielle dynamique. En effet, ces reactions sont le plus souvent trop lentes aux temperatures d'utilisation des dispositifs actuels. Un appareil d'analyse thermique differentielle balistique, base sur une methode de plongee avec compensation, a ete mis au point et permet de surmonter les difficultes precedentes. Apres etalonnages, cet appareil a ete utilise pour la determination des enthalpies de formation du titanate de calcium et du titanate de cadmium ainsi que pour celle des energies Wigner emmagasinees dans des echantillons de BeO, MgO et Al{sub 2}O{sub 3} irradies a une temperature inferieure a 100 deg. C et a differentes doses. (auteurs)

  7. Inventory of greenhouse effect gases in France under the united nation framework convention on climatic change; Inventaire des emissions de gaz a effet de serre en France au titre de la convention cadre des nations unies sur le changement climatique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-01

    The present report supplies emission data, for France and for the period 1990 - 2000 concerning all the substances involved in the increase in the greenhouse effect and covered under the United Nations' Framework Convention on Climate Change (UNFCCC). The substances are the six direct greenhouse gases covered by the Kyoto protocol: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), the two species of halogenous substances - hydro-fluorocarbons (HFCs) and per-fluorocarbons (PFCs), and sulphur hexafluoride (SF{sub 6}). Emissions of sulphur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), non methane volatile organic compounds (NMVOCs), and carbon monoxide (CO), gases which indirectly make a significant contribution to the greenhouse effect, are reported under the Convention. For the period 1990 - 1999 as a whole, estimates provided in the previous inventories have been reviewed and corrected to take into account updated statistics, improved knowledge, possible changes in methodology and specifications contained in the guidelines (FCCC/CP/1999/7) defined by the UNFCCC on reporting for inventories of emissions, in particular the use of the Common Reporting Format (CRF). (author)

  8. Determining the source and genetic fingerprint of natural gases using noble gas geochemistry: a northern Appalachian Basin case study

    Science.gov (United States)

    Hunt, Andrew G.; Darrah, Thomas H.; Poreda, Robert J.

    2012-01-01

    Silurian and Devonian natural gas reservoirs present within New York state represent an example of unconventional gas accumulations within the northern Appalachian Basin. These unconventional energy resources, previously thought to be noneconomically viable, have come into play following advances in drilling (i.e., horizontal drilling) and extraction (i.e., hydraulic fracturing) capabilities. Therefore, efforts to understand these and other domestic and global natural gas reserves have recently increased. The suspicion of fugitive mass migration issues within current Appalachian production fields has catalyzed the need to develop a greater understanding of the genetic grouping (source) and migrational history of natural gases in this area. We introduce new noble gas data in the context of published hydrocarbon carbon (C1,C2+) (13C) data to explore the genesis of thermogenic gases in the Appalachian Basin. This study includes natural gases from two distinct genetic groups: group 1, Upper Devonian (Marcellus shale and Canadaway Group) gases generated in situ, characterized by early mature (13C[C1  C2][13C113C2]: –9), isotopically light methane, with low (4He) (average, 1  103 cc/cc) elevated 4He/40Ar and 21Ne/40Ar (where the asterisk denotes excess radiogenic or nucleogenic production beyond the atmospheric ratio), and a variable, atmospherically (air-saturated–water) derived noble gas component; and group 2, a migratory natural gas that emanated from Lower Ordovician source rocks (i.e., most likely, Middle Ordovician Trenton or Black River group) that is currently hosted primarily in Lower Silurian sands (i.e., Medina or Clinton group) characterized by isotopically heavy, mature methane (13C[C1 – C2] [13C113C2]: 3), with high (4He) (average, 1.85  103 cc/cc) 4He/40Ar and 21Ne/40Ar near crustal production levels and elevated crustal noble gas content (enriched 4He,21Ne, 40Ar). Because the release of each crustal noble gas (i.e., He, Ne, Ar

  9. The Self-Correlation Function of Real Gases; Fonction d'Autocorrelation des Gaz Reels; 0424 0423 041d 041a 0426 0418 042f 0421 0410 041c 041e 041a 041e 0420 0420 0415 041b 042f 0426 0418 0418 0420 0415 0410 041b 042c 041d 042b 0425 0413 0410 0417 041e 0412 ; La Funcion de Autocorrelacion de los Gases Reales

    Energy Technology Data Exchange (ETDEWEB)

    Sigmar, D. J. [Institute for Theoretical Physics, Technical University of Vienna Vienna (Austria)

    1965-06-15

    In the formal theory of inelastic scattering of neutrons, the self-correlation function has been worked out in terms of statistical averages of the derivatives of die N-body interaction-potential of the scatterer. In the present paper, these averages are evaluated for real gases by means of a cluster-expansion related to that of Mayer-Ursell. This leads to certain non-linear types of clusters, which are investigated with respect to the topology of the graphs, their multiplicity (by combinatorial analysis) and their quadrature. As one expects, in view of the many-body problem, some of the clusters are not separable and have to be machine-integrated. In this way, the self-correlation function {gamma}{sub s}(K, t) is calculated for short times, including also the first non-Gaussian term. The cluster-expansion breaks off after the first interaction term, so that the results are valid for low density only. This still gives rise to very many different types of clusters, containing up to seven points, for each coefficient. The assumed potential is a general two-particle, hard-core type. As Singwi et al. have shown, the long time behaviour of {gamma}s is determined by the time integral of the velocity auto-correlation: {integral}{sup {infinity}}{sub 0} {sub T}dt. To construct the integrand for all times, we can make use of our cluster-expansion for small t and adopt Langevin's diffusion theory for large t. Numerical computations are under way. (author) [French] Dans la theorie formelle de la diffusion inelastique des neutrons, on a etabli la fonction d'autocorrelation en se fondant sur les moyennes statistiques des derivees du potentiel d'interaction a N corps du diffuseur. L'auteur a evalue ces moyennes pour des gaz reels a l'aide d'un developpement par amas en rapport avec celui de Mayer-Ursell. U obtient ainsi des types d'amas non lineaires qu'il etudie du point de vue de la topo- logie des diagrammes, de leur multiplicite (par analyse

  10. Determination of the form of very short luminous pulses. Application to scintillation phenomena (1962); Determination de la forme des impulsions lumineuses tres breves. Application aux phenomenes de scintillation (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Koechlin, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-12-15

    During studies on photomultipliers and scintillators we have developed a new method of measurement making it possible to determine with precision the form of luminous pulses whose duration may be less that of an anodic photomultiplier pulse. This method, which can be applied to non-recurrent pulses, makes possible the study of scintillations caused by particles of photons in the case where it is possible to operate on a large number of pulses having the same form. We have thus determined the form of the scintillations of various fluorescent liquids excited by {alpha} particles and {gamma} photons. The results obtained are in agreement with the energy transfer theory for organic liquids elaborated by H. Kallmann and M. FURST. The results are used to determine exactly the parameters occurring in the theory. (author) [French] A l'occasion d'etudes sur les photomultiplicateurs et les scintillateurs nous avons mis au point une nouvelle methode de mesure permettant de determiner avec precision la forme des impulsions lumineuses dont la duree peut etre inferieure a celle d'une impulsion anodique de photomultiplicateur. Cette methode, qui peut s'appliquer a des impulsions non recurrentes, permet d'etudier les scintillations provoquees par des particules ou des photons, a la seule condition que l'on puisse operer sur un grand nombre d'impulsions ayant la meme forme. Nous avons determine ainsi la forme des scintillations des divers liquides fluorescents excites par des particules {alpha} et des photons {gamma} Les resultats obtenus sont en accord avec la theorie des transferts d'energie dans les scintillateurs organiques, elaboree par H. KALLMANN et M. FURST. Ils conduisent a une determination precise des parameters intervenant dans cette theorie. (auteur)

  11. Electronic measurement equipment for determining the cloud cover of the sky. Elektronisches Messgeraet zur Bestimmung des Bedeckungsgrades des Himmels

    Energy Technology Data Exchange (ETDEWEB)

    Siebrasse, R

    1990-01-18

    The invention is used for the automatic determination of the degree of cloud cover of the sky. Compared to the state of the art, the invention has the advantage that it manages without mechanical controls, like those of 'sky scanners' for example, and that the measuring head has a very simple, cheap and robust construction. In order to do without any mechanics, a group of 24 photo-transistors of type BPX 43 was mounted on a hemispherical support, which screens the individual elements from one another, so that a certain section of the sky is allocated to each transistor. The optical axes of the individual axes are distributed completely evenly, so that there is an even and beam-shaped alignment to the sky above the measurement head. The individual measurements of the 24 transistors together give a certain optical impression, a 'picture' or a brightness distribution of the sky hemisphere, which can be read by a suitable program via a normal commercial adaptor into a personal computer, where this distribution is compared with given distributions which have degrees of cover of 0-8 or 0-10 as heading. The given 'picture' which comes closest to the current distribution is ejected as the result, and the heading of this picture gives the current degree of cloud cover.

  12. Possibility of using radioactivity control measurements for determining contamination paths in nutritional vectors; Etude des possibilites d'utilisation des resultats de la surveillance de la radioactivite pour la recherche des trajectoires d'evolution de la contamination des vecteurs alimentaires

    Energy Technology Data Exchange (ETDEWEB)

    Garnier, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    The object of the report is to study the possibility of using results of radioactivity controls for determining the paths followed by contamination in nutritional vectors; these are necessary for calculating protection norms. Radioactive contamination of a nutritional vector is expressed in terms of parameters which suggest that a certain number of criteria may be used for choosing the results which are to be exploited. An actual example of a 'vertical' study based on results of measurements made purely for control purposes shows the difficulties which may be encountered. A list of the results obtained by the control networks set up in the Community Countries, either for the atmosphere, for milk, or for other foodstuffs, shows that these networks are not at the present organised in such a way as to make such a study possible. It appears desirable that a large part of the work carried out by the control Services be oriented in such a way as to yield the complementary information required for experimental studies of radioactive contamination transfers. (author) [French] L'objet du rapport est l'examen des possibilites d'utilisation des resultats de la surveillance de la radioactivite pour la recherche des trajectoires d'evolution de la contamination des vecteurs alimentaires, necessaires au calcul des niveaux de protection. La contamination radioactive d'un vecteur alimentaire s'exprime en fonction de parametres, qui suggerent de retenir un certain nombre de criteres pour la selection des resultats a exploiter. Un exemple concret d'etude 'verticale' basee sur des resultats de mesures faites uniquement dans un but de controle met en evidence les difficultes rencontrees. L'inventaire des resultats obtenus par les reseaux de controle des differents Pays de la Communaute, soit pour l'atmosphere, soit pour le lait, soit pour d'autres aliments, montre que ces reseaux ne sont pas actuellement organises de facon a permettre de telles etudes, Il parait souhaitable qu

  13. Industrial gases

    International Nuclear Information System (INIS)

    Hunter, D.; Jackson, D.; Coeyman, M.

    1993-01-01

    Industrial gas companies have fought hard to boost sales and hold margins in the tough economic climate, and investments are well down from their 1989-'91 peak. But 'our industry is still very strong long term' says Alain Joly, CEO of industry leader L'Air Liquide (AL). By 1994, if a European and Japanese recovery follows through on one in the U.S., 'we could see major [investment] commitments starting again,' he says. 'Noncryogenic production technology is lowering the cost of gas-making possible new applications, oxygen is getting plenty of attention in the environmental area, and hydrogen also fits into the environmental thrust,' says Bob Lovett, executive v.p./gases and equipment with Air Products ampersand Chemicals (AP). Through the 1990's, 'Industrial gases could grow even faster than in the past decade,' he says. Virtually a new generation of new gases applications should become reality by the mid-1990s, says John Campbell, of industry consultants J.R. Campbell ampersand Associates (Lexington, MA). Big new oxygen volumes will be required for powder coal injection in blast furnaces-boosting a steel mill's requirement as much as 40% and coal gasification/combined cycle (CGCC). Increased oil refinery hydroprocessing needs promise hydrogen requirements

  14. Absolute measurement of {beta} activities and application to the determination of neutronic densities; Mesure absolue d'activites {beta} et application a la determination des densites neutronique

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R [Commissariat a l' Energie Atomique, Lab. du Fort de Chatillon, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1951-01-15

    M. Berthelot, to my entrance to the ''Commissariat a l 'Energie Atomique'', proposed me to study the absolute measurement of neutron densities. Very quickly the problem of the absolute activity of {beta} sources became the central object of this work. In a first part, we will develop the methods of absolute determination for {beta} activities. The use of a 4{pi} counter permits to get the absolute activity of all beta radioactive source, susceptible to be put as thin leaf and of period superior than some minutes. The method is independent of the spectra of the measured radioelement. we will describe in the second part some applications which use neutron densities measurement, neutron sources intensities and ratio of cross sections of capture of thermal neutrons. (M.B.) [French] M. Berthelot, a mon entree au ''Commissariat a l 'Energie Atomique'', m'a propose d'etudier la mesure absolue des densites neutroniques. Tres rapidement le probleme de l'activite absolue des sources beta est devenu l'objet central de ce travail. Dans une premiere partie, on abordera les methodes de determination absolue des activites beta. L'utilisation d'un compteur 4{pi} permet d 'obtenir l'activite absolue de toute source radioactive beta, susceptible d'etre mise sous forme de feuille mince et de periode superieure a quelques minutes. La methode est independante du spectre du radioelement mesure. On decrira dans la seconde partie quelques applications a des mesures de densites neutroniques, d'intensites de sources de neutrons et de rapport de sections efficaces de capture de neutrons thermiques. (M.B.)

  15. Absolute measurement of {beta} activities and application to the determination of neutronic densities; Mesure absolue d'activites {beta} et application a la determination des densites neutronique

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R. [Commissariat a l' Energie Atomique, Lab. du Fort de Chatillon, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1951-01-15

    M. Berthelot, to my entrance to the ''Commissariat a l 'Energie Atomique'', proposed me to study the absolute measurement of neutron densities. Very quickly the problem of the absolute activity of {beta} sources became the central object of this work. In a first part, we will develop the methods of absolute determination for {beta} activities. The use of a 4{pi} counter permits to get the absolute activity of all beta radioactive source, susceptible to be put as thin leaf and of period superior than some minutes. The method is independent of the spectra of the measured radioelement. we will describe in the second part some applications which use neutron densities measurement, neutron sources intensities and ratio of cross sections of capture of thermal neutrons. (M.B.) [French] M. Berthelot, a mon entree au ''Commissariat a l 'Energie Atomique'', m'a propose d'etudier la mesure absolue des densites neutroniques. Tres rapidement le probleme de l'activite absolue des sources beta est devenu l'objet central de ce travail. Dans une premiere partie, on abordera les methodes de determination absolue des activites beta. L'utilisation d'un compteur 4{pi} permet d 'obtenir l'activite absolue de toute source radioactive beta, susceptible d'etre mise sous forme de feuille mince et de periode superieure a quelques minutes. La methode est independante du spectre du radioelement mesure. On decrira dans la seconde partie quelques applications a des mesures de densites neutroniques, d'intensites de sources de neutrons et de rapport de sections efficaces de capture de neutrons thermiques. (M.B.)

  16. Contribution to the study of the ionization and heating of gases by laser radiation; Contribution a l'etude de l'ionisation et du chauffage des gaz par le rayonnement d'un laser declenche

    Energy Technology Data Exchange (ETDEWEB)

    Veyrie, P [Commissariat a l' Energie Atomique, Limeil-Brevannes (France). Centre d' Etudes

    1968-01-01

    The ionization and heating of gases by the concentrated radiation of a neodymium laser is studied. The power is 300 MW, the gas studied is primarily deuterium between 300 mm and 2280 mm. The first part concerns a certain number of experimental results on the absorption of the radiation and on changes produced in the plasma as a function of time. From these results are deduced a certain number of consequences, amongst which may be mentioned the definition of a pre-ionization threshold. These experimental results are interpreted in the second part. A calculation is made of the length of the period during which the electrons multiply up to when the absorption becomes measurable. The last phase corresponds to the hydrodynamics evolution, the calculations are compared with the experiments. The agreement between theory and experiment is satisfactory for the different phases. (author) [French] On etudie l'ionisation et le chauffage des gaz par le rayonnement concentre d'un laser au neodyme. La puissance est de 300 MW, le gaz etudie est principalement le deuterium entre 300 mm et 2280 mm. La premiere partie concerne un certain nombre de resultats experimentaux. Il s'agit de l'absorption du rayonnement et de l'evolution chronologique du plasma. De ces resultats on deduit un certain nombre de consequences parmi lesquelles il faut citer la definition d'un seuil de preionisation. Ces resultats experimentaux sont interpretes dans la deuxieme partie. On calcule la duree de la phase pendant laquelle se multiplient les electrons jusqu'a ce que l'absorption soit mesurable. La derniere phase correspond a l'evolution hydrodynamique. Les calculs sont confrontes avec l'experience. L'accord entre theorie et experience est satisfaisant pour les differentes phases. (auteur)

  17. Contribution to the study of the ionization and heating of gases by laser radiation; Contribution a l'etude de l'ionisation et du chauffage des gaz par le rayonnement d'un laser declenche

    Energy Technology Data Exchange (ETDEWEB)

    Veyrie, P. [Commissariat a l' Energie Atomique, Limeil-Brevannes (France). Centre d' Etudes

    1968-01-01

    The ionization and heating of gases by the concentrated radiation of a neodymium laser is studied. The power is 300 MW, the gas studied is primarily deuterium between 300 mm and 2280 mm. The first part concerns a certain number of experimental results on the absorption of the radiation and on changes produced in the plasma as a function of time. From these results are deduced a certain number of consequences, amongst which may be mentioned the definition of a pre-ionization threshold. These experimental results are interpreted in the second part. A calculation is made of the length of the period during which the electrons multiply up to when the absorption becomes measurable. The last phase corresponds to the hydrodynamics evolution, the calculations are compared with the experiments. The agreement between theory and experiment is satisfactory for the different phases. (author) [French] On etudie l'ionisation et le chauffage des gaz par le rayonnement concentre d'un laser au neodyme. La puissance est de 300 MW, le gaz etudie est principalement le deuterium entre 300 mm et 2280 mm. La premiere partie concerne un certain nombre de resultats experimentaux. Il s'agit de l'absorption du rayonnement et de l'evolution chronologique du plasma. De ces resultats on deduit un certain nombre de consequences parmi lesquelles il faut citer la definition d'un seuil de preionisation. Ces resultats experimentaux sont interpretes dans la deuxieme partie. On calcule la duree de la phase pendant laquelle se multiplient les electrons jusqu'a ce que l'absorption soit mesurable. La derniere phase correspond a l'evolution hydrodynamique. Les calculs sont confrontes avec l'experience. L'accord entre theorie et experience est satisfaisant pour les differentes phases. (auteur)

  18. Determination of the concentration of {alpha} emitting radioactive aerosols; Mesure de la concentration des aerosols radioactifs emetteurs {alpha}

    Energy Technology Data Exchange (ETDEWEB)

    Labeyrie, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1953-06-15

    In the first part of this work the techniques used for the quantitative measurement of the concentrations of aerosols carrying short lived (radon or thoron daughters) or long lived (uranium) {alpha} radioactive emitters are described. In the second part the author investigates the problem of the determination of radon concentration in air by means of activity determinations on airborne dusts. Special reference is made to the measurement of the radon active deposit on two types of dusts (iron oxide (yellow) and uranium oxide) in small chambers (6 liters). In the third part are given data resulting from determinations of radon and thoron concentrations in atmospheric air in the south of Paris area using this method. (author) [French] Dans la premiere partie de ce travail on expose les techniques utilisees pour la mesure quantitative des concentrations d'aerosols contenant des emetteurs radioactifs {alpha}, tant pour ceux a vie courte (derives du radon ou du thoron) que pour ceux a vie longue (uranium). Dans la seconde partie on traite le probleme de la determination de la concentration de l'air en radon par la mesure de l'activite des poussieres ayant sejourne dans cet air. En particulier, on indique pour de petits volumes (6 litres) la proportion de depot actif du radon qui est fixee sur deux types de poussieres (limonite et oxyde d'uranium) en fonction de la concentration de celles-ci. Dans la troisieme partie on donne quelques exemples de mesure par cette methode de la concentration en radon et en thoron de l'atmosphere de la region parisienne. (auteur)

  19. Study of free acidity determinations in aqueous solution; Etude des dosages d'acidite libre en solution aqueuse

    Energy Technology Data Exchange (ETDEWEB)

    Kergreis, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-04-01

    The object of this work is the study of the principal methods which can be applied to the measurement of 'free' acidity. In the first part, we define the various types of acidity which can exist in aqueous solution; then, after having studied some hydrolysis reactions, we compare the value of the neutralisation pH of the hydrated cation and that of the precipitation of the hydroxide. In the second part we have started to study the determination of the acidity of an aqueous solution. After having rapidly considered the 'total' acidity determination, we deal with the problem of the 'free' acidity titration. We have considered in particular certain methods: extrapolation of the equivalent point, colorimetric titrations with or without a complexing agent, and finally the use of ion-exchange resins with mixed aqueous and solvent solutions. (author) [French] Le but de ce travail est l'etude des principales methodes de determination de l'acidite 'libre'. Dans une premiere partie nous avons defini les differentes sortes d'acidites pouvant exister en solution aqueuse, puis apres avoir etudie quelques reactions d'hydrolyse, nous avons compare la valeur de pH de neutralisation du cation hydrate et celle de precipitation de l'hydroxyde. Dans la seconde partie nous avons aborde l'etuce des dosages de l'acidite d'une solution aqueuse. Apres avoir envisage assez rapidement la determination de l'acidite 'totale', nous traitons du probleme du titrage de l'acidite 'libre'. Nous avons porte notre attention sur certaines methodes: extrapolation du point equivalent, titrimetrie colorimetrique avec ou sans complexant, et enfin utilisation des resines echangeuses d'ions en milieu aqueux et solvant mixte.

  20. Noble Gases

    Science.gov (United States)

    Podosek, F. A.

    2003-12-01

    The noble gases are the group of elements - helium, neon, argon, krypton, xenon - in the rightmost column of the periodic table of the elements, those which have "filled" outermost shells of electrons (two for helium, eight for the others). This configuration of electrons results in a neutral atom that has relatively low electron affinity and relatively high ionization energy. In consequence, in most natural circumstances these elements do not form chemical compounds, whence they are called "noble." Similarly, much more so than other elements in most circumstances, they partition strongly into a gas phase (as monatomic gas), so that they are called the "noble gases" (also, "inert gases"). (It should be noted, of course, that there is a sixth noble gas, radon, but all isotopes of radon are radioactive, with maximum half-life a few days, so that radon occurs in nature only because of recent production in the U-Th decay chains. The factors that govern the distribution of radon isotopes are thus quite different from those for the five gases cited. There are interesting stories about radon, but they are very different from those about the first five noble gases, and are thus outside the scope of this chapter.)In the nuclear fires in which the elements are forged, the creation and destruction of a given nuclear species depends on its nuclear properties, not on whether it will have a filled outermost shell when things cool off and nuclei begin to gather electrons. The numerology of nuclear physics is different from that of chemistry, so that in the cosmos at large there is nothing systematically special about the abundances of the noble gases as compared to other elements. We live in a very nonrepresentative part of the cosmos, however. As is discussed elsewhere in this volume, the outstanding generalization about the geo-/cosmochemistry of the terrestrial planets is that at some point thermodynamic conditions dictated phase separation of solids from gases, and that the

  1. Visualisation of Gasoline and Exhaust Gases Distribution in a 4-Valve Si Engine; Effects of Stratification on Combustion and Pollutants Visualisation de la répartition du carburant et des gaz brûlés dans un moteur à 4 soupapes à allumage commandé ; effet de la stratification sur la combustion et les polluants

    Directory of Open Access Journals (Sweden)

    Deschamps B.

    2006-12-01

    Full Text Available sAn indirect method to map the burned gases in SI engine has been developed. It is based on visualisation by Laser Induced Fluorescence of the unburned mixture seeded with biacetyl. Both internally and externally recirculated burned gases are monitored. This diagnostic is complementary to the LIF technique applied to measure the gasoline distribution. These LIF gasoline and burned gases measurements are applied in a 4-valve optical access SI engine for a large range of operating conditions. These include variations of both fuel injection and burned gas recirculation modes causing different types of stratification leading to very distinct heat release and exhaust emissions characteristics. Tumble level and spark location are also modified. The observation of the actual stratification in the engine forms a sound basis explanation of the engine performance. Parameters allowing an optimisation of NOx and HC levels can be inferred, and in particular the effectiveness of recirculation and fuel injection strategies. The conclusions are confirmed by measurements in a single engine cylinder conventional head with the same geometry. Une méthode indirecte pour cartographier les gaz brûlés dans un moteur à allumage commandé a été développée. Elle est fondée sur une visualisation à partir de la fluorescence induite par laser (LIF du mélange air-carburant non brûlé et ensemencé avec du biacétyl. Les gaz brûlés provenant à la fois des recirculations internes et externes sont observés. Ce type de diagnostic est complémentaire des techniques de LIF utilisées pour observer la distribution du carburant. Ces mesures de concentration sont réalisées dans un moteur à 4 soupapes avec accès optiques, pour une gamme étendue de conditions opératoires. Celles-ci comprennent des variations des modes d'injection du carburant et des modes de recirculation des gaz brûlés, provoquant ainsi différents types de stratifications qui correspondent

  2. Rare gases adsorption and separation on silver doped adsorbent

    International Nuclear Information System (INIS)

    Deliere, Ludovic

    2015-01-01

    The Comprehensive Nuclear-Test-Ban Treaty (CTBT) implements means for detecting nuclear tests in an International Monitoring System (IMS). The Commissariat a l'Energie Atomique et aux Energies Alternatives (CEA) has developed in the mid-90's, the SPALAX system (Systeme de Prelevement d'Air en Ligne avec l'Analyse des radioXenons). Xenon analysis, including radioactive isotopes from the fission reaction during the explosion, requires the development of highly efficient process for xenon concentration. In this work, the adsorption and diffusion phenomena of noble gases are studied in silver exchanged ZSM-5 zeolite. The 'experience/Monte Carlo simulation' coupling is used to determine the essential thermodynamic data on the adsorption of noble gases and to characterize the adsorption sites. The presence of a strong adsorption site, identified as silver nanoparticles and intervening at low concentration of noble gases (including xenon and radon) in some silver exchanged zeolites, achieves adsorption and selectivity performance to date unrivaled. These results allow considering their use in many critical applications in the field of capture and separation of rare gases: rare gas industrial production, reprocessing of spent fuel from gas, radon in air pollution control. (author) [fr

  3. Fuel gases

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    This paper gives a brief presentation of the context, perspectives of production, specificities, and the conditions required for the development of NGV (Natural Gas for Vehicle) and LPG-f (Liquefied Petroleum Gas fuel) alternative fuels. After an historical presentation of 80 years of LPG evolution in vehicle fuels, a first part describes the economical and environmental advantages of gaseous alternative fuels (cleaner combustion, longer engines life, reduced noise pollution, greater natural gas reserves, lower political-economical petroleum dependence..). The second part gives a comparative cost and environmental evaluation between the available alternative fuels: bio-fuels, electric power and fuel gases, taking into account the processes and constraints involved in the production of these fuels. (J.S.)

  4. Greenhouse effect gases and climatic change: quantification and tools to fight against the emissions; Gaz a effet de serre et changement climatique: quantification et instruments de lutte contre des emissions

    Energy Technology Data Exchange (ETDEWEB)

    Bizec, R.F

    2006-07-01

    The greenhouse effect gases are considered responsible of the climatic change. Their consequences are numerous: increase of the sea level, displacement of the climatic areas, modification of the forests ecosystems, rarefaction of water, progressively decrease of glaciers... This fast modification of the climate would lead to the increase of natural hazards as hurricanes, storms, hails and so on. It is then a necessity to reduce as fast as possible the greenhouse effect gases. The author describes in a first part the methods of the greenhouse effect gases quantification and in the second part the tools to fight these gases, regulations, standards, economic tools, national tools and the projects. (A.L.B.)

  5. Methods for determining fast neutron spectra using threshold detectors; Les methodes de determination des spectres de neutrons rapides a l'aide de detecteurs a seuil

    Energy Technology Data Exchange (ETDEWEB)

    Delattre, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    We propose to examine all the methods by which fast neutron spectra can be determined using the response of threshold detectors (activation or fission chamber detectors). Most of these methods have been proposed and often even used by various authors of which a list will be found in the bibliography. The aim of the present report is thus not to present original work but rather to gather into a single article and to present in a rational form a whole series of methods which have already been described in articles scattered throughout the specialised literature. Up to the present, each author has in general studied one or two methods and no comparative study of all the possible methods seems to have been made. The most comprehensive study on this topic is that of P.M. UTHE from whose article much has been borrowed. We have tried here to develop a useful tool which should facilitate the systematic experimental study leading to the recognition of the respective merits of the methods proposed. (author) [French] On se propose d'examiner l'ensemble des methodes permettant de determiner les spectres de neutrons rapides a partir des reponses de detecteurs a seuil (detecteurs par activation ou chambre a fission). La plupart de ces methodes ont deja ete proposees, et souvent meme utilisees, par differents auteurs dont on trouvera la liste en bibliographie. Le but du present rapport n'est donc pas de faire oeuvre originale mais plutot de rassembler dans un meme document et de presenter de maniere homogene toute une serie de methodes qui ont deja fait l'objet d'articles disperses dans la litterature specialisee. Jusqu'a present, chaque auteur s'est en general limite a l'etude experimentale d'une ou deux methodes et aucune etude comparative de l'ensemble des methodes possibles ne semble avoir ete faite. Le rapport le plus complet a ce sujet est celui de P.M. UTHE auquel de larges emprunts ont ete faits. On s'est efforce ici d'elaborer un outil de travail commode qui devrait

  6. A novel method for the determination of adsorption partition coefficients of minor gases in a shale sample by headspace gas chromatography.

    Science.gov (United States)

    Zhang, Chun-Yun; Hu, Hui-Chao; Chai, Xin-Sheng; Pan, Lei; Xiao, Xian-Ming

    2013-10-04

    A novel method has been developed for the determination of adsorption partition coefficient (Kd) of minor gases in shale. The method uses samples of two different sizes (masses) of the same material, from which the partition coefficient of the gas can be determined from two independent headspace gas chromatographic (HS-GC) measurements. The equilibrium for the model gas (ethane) was achieved in 5h at 120°C. The method also involves establishing an equation based on the Kd at higher equilibrium temperature, from which the Kd at lower temperature can be calculated. Although the HS-GC method requires some time and effort, it is simpler and quicker than the isothermal adsorption method that is in widespread use today. As a result, the method is simple and practical and can be a valuable tool for shale gas-related research and applications. Copyright © 2013 Elsevier B.V. All rights reserved.

  7. Strategies for method development for an inductively coupled plasma mass spectrometer with bandpass reaction cell. Approaches with different reaction gases for the determination of selenium

    International Nuclear Information System (INIS)

    Hattendorf, Bodo; Guenther, Detlef

    2003-01-01

    An inductively coupled plasma mass spectrometer with dynamic reaction cell (DRC) was used to investigate different approaches for chemical resolution of Ar 2 + ions and to improve the determination of Se. Hydrogen, methane, oxygen and nitrous oxide were used as reaction gases. The method development for each approach consists of the acquisition of spectra for blank and spiked samples at different operating parameters, including reaction gas flow and transmission settings, of the DRC. Isotope ratio studies and the analytes signal to background ratio (SBR), were used as criteria to determine the operating conditions of the DRC where spectral interferences from the ion source or from polyatomic ions formed inside the DRC are minimized. Methane was found to provide the highest reaction efficiency for determination of Se. Nitrous oxide and oxygen also very efficiently suppress the Ar 2 + interference but reaction or scattering losses of Se + and SeO + are significant. Hydrogen is the least efficient gas for Ar 2 + reduction but little scattering or reactive loss lead to a good SBR. The determination of Se as SeO + was investigated with oxygen and nitrous oxide as reaction gases. The efficiency when using the oxygenation reaction was found to be similar to the efficiency for the charge transfer reactions but the slow oxygenation of the potentially interfering Mo + renders this approach less useful for analytical purposes. Using a natural water sample it could be shown that very good agreement is obtained using methane or hydrogen for analysis of 80 Se + at the μg/l level. Limits of detection are lowest (2 ng/l) when methane is used to suppress the Ar 2 + ion and when 80 Se + is used for analysis

  8. Determination of diets for the populations of eleven regions of the European community to be used for obtaining radioactive contamination levels. First results concerning the food consumption of individuals classified in nine age-groups; Determination des regimes alimentaires des populations de onze regions de la Communaute Europenne et vue de l'etude des niveaux de contamination radioactive. Premiere serie de resultats concernant la consommation alimentaire des individus groupes en neuf classes d'ages

    Energy Technology Data Exchange (ETDEWEB)

    Ledermann, S; Lacourly, G; Garnier, A; Cresta, M; Lombardo, E [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    The present document continues the report CEA-R--2979 - EUR--2768-f. The processing of the data given by the family food enquiry carried out in eleven regions of the European Community, has permitted to determine the food consumption of individuals classified in nine age-groups, in order to study the radioactive contamination levels in the food-chain. The used statistical method is described, and the obtained results are presented in form of double-entry tables giving for each region and for each age-group the mean weekly food-consumption and the contribution of each diet in nutrition principles, in minerals, vitamins, trace elements and calories. (authors) [French] Ce rapport fait suite au rapport CEA-R--2979 - EUR--2768-f. Le traitement de l'information apportee par les enquetes alimentaires familiales realisees dans onze regions de la Communaute Europeenne a permis de determiner les consommations alimentaires des individus groupes en neuf classes d'age, en vue de l'etude des niveaux de contamination radioactive dans les chaines alimentaires. La methode statistique employee est decrite et les resultats obtenus sont presentes sous forme de tableaux a double entree donnant pour chacune des regions etudiees et pour chacune des neuf classes d'age, les consommations moyennes hebdomadaires, ainsi que les apports en principes nutritifs, mineraux, vitamines et oligo-elements, et calories de chaque regime. (auteurs)

  9. Technical papers 2: regional evaluation of the greenhouse gases emissions bound to the energy; Cahiers techniques 2: bilan regional des emissions de gaz a effet de serre liees a l'energie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    The regional evaluation of the greenhouse gases emissions is realized in the framework of the climatic change fight. This technical paper aims to give regions information on the greenhouse gases emissions bound the the energy consumption. It provides a sectoral analysis in function of the energy sources and pollution sources. (A.L.B.)

  10. The pulsed neutron method applied to the determination of the nuclear constants of graphite (1961); La methode des neutrons pulses appliquee a la determination des constantes nucleaires du graphite (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Lalande, J [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1961-07-01

    A method for determining the nuclear constants {sigma}{sub a} and {lambda}{sub t} of a moderator is described. The disappearance of a burst of neutrons introduced into a finite medium is studied as a function of time. This decrease in the thermal neutron density is the product of two exponentials; one representing the absorption, the other the leakage. By varying one or other of these factors, the constants of the factor left unvaried can be determined, and from this the nuclear constant values are deduced. (author) [French] On decrit une methode permettant de determiner les constantes nucleaires {sigma}{sub a} et {lambda}{sub t} d'un moderateur. On etudie la decroissance dans le temps d'une bouffee de neutrons introduite dans un milieu fini. Cette decroissance de la densite en neutrons thermiques est le produit de deux exponentielles; l'une represente l'absorption, l'autre les fuites. Par variation de l'un ou l'autre de ces facteurs, on determine les constantes du facteur laisse invariant dont on deduit les valeurs des constantes nucleaires. (auteur)

  11. Determination of the food consumption in eleven regions of the european community with a view to studying the radioactive contamination level: Methods used. Results of family enquiries; Determination des regimes alimentaires des populations de onze regions de la communaute europeenne en vue de l'etude des niveaux de contamination radioactive: Methodologie. Resultats des enquetes familiales

    Energy Technology Data Exchange (ETDEWEB)

    Cresta, M; Lacourly, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    In the present report are given the results obtained from food surveys carried out during the period 1963-1965 and involving 9000 families living in eleven regions spread out over the six European Community countries. A partial analysis of the results obtained covers a reduced sample of 3725 families; it makes it possible to fix the composition of the mean individual, monthly and annual food consumptions for each of the eleven regions. Details of the organisation of the survey, of the data processing methods and of the method of presenting the results are given in the first part of the report. the second part presents, in numerical table form, the consumption of various foodstuffs and the feeding principles for each region covered by the survey. Tables summarizing the data make it possible to compare the mean individual consumptions in the various regions studied. (author) [French] Dans le present rapport sont rassembles les premiers resultats des enquetes alimentaires effectuees pendant la periode 1963-1965, aupres de 9000 familles, dans onze regions reparties dans les six pays de la Communaute Europeenne. L'exploitation partielle des donnees obtenues porte sur un echantillon reduit a 3725 familles et permet d'etablir la composition du regime alimentaire moyen individuel, mensuel et annuel de chacune des onze regions. L'organisation des enquetes, la methode de traitement des donnees et l'expression des resultats sont exposees dans la premiere partie du rapport. La seconde reunit, sous forme de tableaux numeriques, les consommations des differents aliments et principes alimentaires par region d'enquetes. Des tableaux recapitulatifs permettent, en outre, une comparaison des consommations moyennes, individuelles des differentes regions etudiees. (auteur)

  12. Determination of the food consumption in eleven regions of the european community with a view to studying the radioactive contamination level: Methods used. Results of family enquiries; Determination des regimes alimentaires des populations de onze regions de la communaute europeenne en vue de l'etude des niveaux de contamination radioactive: Methodologie. Resultats des enquetes familiales

    Energy Technology Data Exchange (ETDEWEB)

    Cresta, M.; Lacourly, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-07-01

    In the present report are given the results obtained from food surveys carried out during the period 1963-1965 and involving 9000 families living in eleven regions spread out over the six European Community countries. A partial analysis of the results obtained covers a reduced sample of 3725 families; it makes it possible to fix the composition of the mean individual, monthly and annual food consumptions for each of the eleven regions. Details of the organisation of the survey, of the data processing methods and of the method of presenting the results are given in the first part of the report. the second part presents, in numerical table form, the consumption of various foodstuffs and the feeding principles for each region covered by the survey. Tables summarizing the data make it possible to compare the mean individual consumptions in the various regions studied. (author) [French] Dans le present rapport sont rassembles les premiers resultats des enquetes alimentaires effectuees pendant la periode 1963-1965, aupres de 9000 familles, dans onze regions reparties dans les six pays de la Communaute Europeenne. L'exploitation partielle des donnees obtenues porte sur un echantillon reduit a 3725 familles et permet d'etablir la composition du regime alimentaire moyen individuel, mensuel et annuel de chacune des onze regions. L'organisation des enquetes, la methode de traitement des donnees et l'expression des resultats sont exposees dans la premiere partie du rapport. La seconde reunit, sous forme de tableaux numeriques, les consommations des differents aliments et principes alimentaires par region d'enquetes. Des tableaux recapitulatifs permettent, en outre, une comparaison des consommations moyennes, individuelles des differentes regions etudiees. (auteur)

  13. Determination of permeability to gases of concrete used as repository for radioactive wastes; Determinacao da permeabilidade a gas em concreto usado em repositorios para rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Miyake, Eloisa Tamie

    1994-12-31

    Concrete is widely used in final radioactive waste repository construction and must have well defined characteristics. The permeability is a property that allows to evaluate the durability of concrete which guarantee the protection of the surroundings. Durable concretes have low permeability which reduces liquids intrusion into the repository and decreases the probability of leaching of soluble radioactive compounds and gases escapes to the human habitat. This work includes: the construction of a camera to measure the permeability coefficient of hydraulic products, by using gaseous nitrogen as a permeation fluid; determination of characteristics of material used in concrete compositions; and tests in concretes with different compositions in which ordinary Portland cement and blast-furnace cement were used. (author). 61 refs., 33 figs., 16 tabs.

  14. The gas-filled counting tube of the PTB - a device for the activity determination of radioactive gases

    International Nuclear Information System (INIS)

    Guenther, E.W.

    1993-08-01

    A measuring device for the activity determination of gaseous radioactive materials (H-3, Kr-85, C-14 O 2 ) has been set up as a PTB primary standard. Samples measured in it or their initial substances are the basis for activity standards. The gaseous samples are introduced directly into the vacuum device. The amount of gas filled can be determined by measuring pressure, volume and temperature. After the gas has been mixed with a counting gas (methane, argon/methane or propane), the count-rates are measured and the activity of the gas calculated. The activity of solid or liquid radioactive substances can also be determined with the device described, if they can be converted into a suitable gas. For this purpose there are additional devices (e.g. for producing hydrogen from water or C-14 O 2 from carbonate). The first models of these devices have been developed and are described. (orig.) [de

  15. Clay stones of the deep Namur as potental sources of nitrogen of Northwest-German natural gases - first indications from the pyrolisis tests; Tonsteine des tiefen Namur als potentielle Stickstoffquellen nordwestdeutscher Erdgase - erste Indizien aus Pyrolyseuntersuchungen

    Energy Technology Data Exchange (ETDEWEB)

    Krooss, B.M. [Forschungszentrum Juelich (Germany). Inst. fuer Erdoel und organische Geochemie; Karg, H. [RWTH Aachen (Germany)

    1998-12-31

    The content of molecular nitrogen in the natural gas deposits of the Northwest-German basin can show values of up to 100 volume percent (nitrogen province) and therefore carry a high exploration risk. Analysis of the generation of the gas from carboniferous clay stone by means of open pyrolysis shows that the nitrogen generation potential is relatively high when compared to coal (according to TOC standards). This analysis enabled the determination of generation graphs for nitrogen, partly also for methane, from Namur clay stones of a maturity between 2.81 and 3.86 volume percent. (orig.). [Deutsch] Die Gehalte an molekularem Stickstoff (N{sub 2}) in Erdgaslagerstaetten des Nordwestdeutschen Beckens koennen Werte von nahezu 100 Vol.-% (Stickstoffprovinz) erreichen und stellen somit ein hohes Explorationsrisiko dar. Die Untersuchung der Gasgenese aus karbonischen Tonsteinen mit der Methode der offenen Pyrolyse zeigt ein im Vergleich zu Kohlen hohes Stickstoff-Genesepotential (TOC-normiert). Mit Hilfe der verwendeten Analysenmethode konnten Genesekurven fuer Stickstoff, sowie teilweise fuer Methan, aus Namur Tonsteinen in einem Reifebereich von 2.81 bis 3.86% VR{sub r} bestimmt werden. (orig.)

  16. The anisotropic potential of molecular hydrogen determined from the scattering of oriented H2 on inert gases

    International Nuclear Information System (INIS)

    Zandee, A.P.L.M.

    1977-01-01

    This thesis deals with an experiment aimed at determining the angle dependence of an intermolecular potential between H 2 molecule and a rare gas atom. The small relative difference in total collision cross section for beams of differently oriented H 2 molecules colliding with inert gas atoms in a scattering box is measured (anisotropy A). Through variation of the orientation and by studying its influence on the total collision cross sections, the angle dependence of the intermolecular potential can be arrived at

  17. Measuring probe and method for determining the oxygen content in gases, vapors, and liquids, especially in liquid metals

    International Nuclear Information System (INIS)

    Sundermann, H.; Andrae, U.

    1978-01-01

    The invention is concerned with the improvement of the measuring probe described in the main patent no. 1798002 with which the oxygen content in liquid metals, e.g. Na, is to be determined. In order to avoid the glass stopper shutting off the reference space having to be ground out it is proposed to connect the solid electrolyte firmly and hermetically with a metallic mounting support (e.g. Fe-Co-Ni alloy), having got the same thermal coefficient of expansion as the solid electrolyte (e.g. zirconium dioxide stabilized with ythium oxide or thorium dioxide). Further details of the design are very explicitly described. (HP) [de

  18. Determination of the 20 MeV linear accelerator, new injector for the synchrotron Saturne. Choice of the electrical and dynamical particle parameters; Determination de l'accelerateur lineaire de 20 MeV, nouvel injecteur du synchrotron Saturne. Choix des parametres electriques, dynamique des particules

    Energy Technology Data Exchange (ETDEWEB)

    Prome, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-12-15

    This report takes place in the general determination of the 20 MeV linear accelerator which will be the new Saturne injector; it deals with particle dynamics. Starting from beam requirements at the output of the linac, cells lengths with variable synchronous phase angle, buncher and de-buncher parameters, beam emittances at the output in several phase spaces are successively determined. (author) [French] Dans le contexte general de la determination de l'accelerateur lineaire de 20 MeV, nouvel injecteur du synchrotron Saturne, ce rapport traite de la partie relative au mecanisme de l'acceleration des particules; a partir des caracteristiques souhaitees pour le faisceau a la sortie de cet accelerateur, on determine successivement les longueurs des cellules, compte tenu du choix d'un angle de phase synchrone variable, les caracteristiques du groupeur et du degroupeur et les emittances du faisceau en sortie dans les differents plans de phase. (auteur)

  19. Radiochemical Determination of Plutonium for Radiological Purposes; Determination Radiochimique du Plutonium a des Fins Radiologiques; Radiokhimicheskoe opredelenie plutoniya dlya tselej radiologii; Determinacion Radioquimica del Plutonio con Fines Radiologicos

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, J. M.; Beasley, T. M. [Chemical Laboratory, Hanford Laboratories, General Electric Company, Richland, WA (United States)

    1964-10-15

    In this paper the procedures that have been and are currently being used for the determination of micro- microgram quantities of plutonium in biological and environmental samples are reviewed. Special emphasis is placed on excretion analysis. Expected urinary excretion rates have been calculated, using assumed levels of plutonium deposition, so that the analytical sensitivities of various procedures can be compared. Complete dissolution of excreta, soil, bone, tissue and vegetation are described with emphasis on avoiding the formation of refractory compounds of plutonium which are soluble with difficulty. Analytical methods for plutonium analysis of these materials are reviewed and include co-precipitation, liquid-liquid extraction, ion exchange chromatography and the use of plutonium isotopes for yield determinations by means of alpha energy analysis. Using counting statistics, comparisons are made of the sensitivities available in low-level alpha counting, using ionization chambers,- proportional counters, diode counters, and nuclear track emulsions. Isotopic analysis of plutonium by alpha spectrometry, nuclear emulsion techniques, and liquid scintillation counting are included. The use of non-isotopic carriers as a source of extraneous activity and the environmental levels of plutonium recently encountered around the world are discussed in connection with ''blank'' samples. Two possibilities are considered for future methods of plutonium analysis where increased sensitivity is required. These are activation analysis and fission fragment counting. (author) [French] Les auteurs examinent l'ensemble des methodes que l'on a employees et que Ton emploie actuellement pour evaluer les quantites de plutonium de l'ordre du picogramme presentes dans des echantillons biologiques et mesologiques. Ils insistent particulierement sur l'analyse des excreta. Ils ont calcule des taux d'elimination urinaire probables a partir de concentrations de plutonium theoriques, de maniere a

  20. Detection of carbon dioxide in the gases evolved during the hot extraction determination of hydrogen in uranium ingots

    International Nuclear Information System (INIS)

    Jursik, M.L.; Pope, J.D.

    1977-08-01

    The hot extraction method was used at the National Lead Company of Ohio to determine hydrogen in uranium metal at the 2 ppM level. The volume of gas evolved from the heated sample was assumed to be hydrogen. When a liquid nitrogen trap was placed into the system the hydrogen values were reduced 5 to 10%. The gas retained by the nitrogen trap was identified by mass spectrometry as predominantly carbon dioxide. Low hydrogen values were observed only when the nitrogen trap was used in the analysis of high-carbon (300 to 600 ppM) uranium from NLO production ingots. However, hydrogen values for low-carbon (30 to 50 ppM) uranium were unaffected by the nitrogen trap. The formation of carbon dioxide appears to be associated with the carbon content of the uranium metal. Comparisons of hydrogen values obtained with the hot extraction method and with an inert fusion--thermal conductivity method are also presented. 3 tables, 4 figures

  1. Theory of high frequency discharge in gases under low pressures. Experimental investigation of high-frequency type ion sources; Theorie de la decharge haute frequence dans les gaz aux faibles pressions. Etude experimentale des sources d'ions du type haute frequence

    Energy Technology Data Exchange (ETDEWEB)

    Salmon, Jean

    1955-03-02

    The first part of this research thesis addresses the theory of high frequency discharge in gases under low pressures, and first proposes a calculation of the distribution function for electrons present within the gas. The author then studies the evolution of electron density within a discharge tube by assigning the governing role in electron multiplication to the secondary emission of tube walls. The second part proposes a detailed description of a source operating at 96.5 Mc/s, a discussion of measurements performed on this source, and the search for a theoretical explanation of some of its properties. The author then briefly analyses various existing types of high frequency sources, and finally discusses their use in corpuscular microscopy and in particle accelerators [French] La presente these comprend deux parties. La premiere est consacree a la theorie de la decharge haute frequence dans les gaz aux faibles pressions et comporte tout d'abord le calcul de la fonction de distribution des electrons presents au sein du gaz. Nous etudions ensuite l'evolution de la densite electronique a l'interieur d'un tube a decharge en attribuant, a l'emission secondaire des parois de ce dernier, le role essentiel dans la multiplicalion des electrons. Nous obtenons ainsi les conditions d'amorcage. Tout au long de cette etude, on doit distinguer soigneusement le cas ou le libre parcours moyen des electrons dans le gaz est inferieur aux dimensions de l'enceinte et le cas ou il leur est superieur. La deuxieme partie comprend la description detaillee d'une source fonctionnant sur 96.5 Mc/s, l'expose des mesures effectuees sur celle-ci et la recherche d'une explication theorique de certaines de ses proprietes. Nous faisons ensuite une breve analyse des divers types de sources d'ions haute frequence existant a l'heure actuelle et nous terminons en traitant de leur utilisation en microscopie corpusculaire et dans les accelerateurs de particules.

  2. Le problème des hydrates dans le contexte de la production et du transport polyphasiques des pétroles bruts et des gaz naturels. Première partie : physico-chimie de la formation et de la dissociation des hydrates Hydrates Problem Within the Framework of Multiphase Production and Transport of Crude Oils and Natural Gases. Part One: Physical-Chemistry of Hydrates Formation and Dissociation

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available L'exploitation en mer des gisements de combustibles fossiles fluides a amplifié le besoin d'accroître nos connaissances sur les hydrates qui sont susceptibles de boucher les installations de production, de traitement et de transport. Dans cette publication, la structure moléculaire des hydrates I, II et H est rappelée, ensuite l'analyse physico-chimique de leur formation est succinctement décrite tant sur les plans thermodynamique que cinétique. Enfin, les remèdes possibles aux problèmes rencontrés par les compagnies opératrices sont indiqués, essentiellement les inhibiteurs thermodynamiques classiques tels que les alcools ou les sels qui diminuent la température de formation des hydrates, et les additifs dispersants qui évitent la croissance et/ou l'agglomération des cristaux. Pour terminer, une boucle pilote de circulation originale est présentée, ses caractéristiques qui permettent la validation des additifs dispersants dans des conditions hydrodynamiques et physico-chimiques représentatives étant soulignées. Offshore exploitation of fossil fluid fuels has emphasized the need of improving our knowledge on hydrates which can plug production, treatment and transport facilities. In this paper, the molecular structure of I, II and H hydrates is recalled, then the physical-chemistry of their formation is briefly reviewed from both the thermodynamic and the kinetic points of view. Finally, the possible remedies to the problems met by operating companies are described, mainly classical thermodynamic inhibitors such as alcohols or salts which decrease the hydrates formation temperature, and dispersant additives which avoid crystals growth and/or agglomeration. At last an original circulation loop at pilot scale is presented, its characteristics which allow the testing of dispersant additives under representative hydrodynamic and physico-chemical conditions being outlined.

  3. Count rate balance method of measuring sediment transport of sand beds by radioactive tracers; Methode du bilan des taux de comptage d'indicateurs radioactifs pour la determination du debit de charriage des lits sableux

    Energy Technology Data Exchange (ETDEWEB)

    Sauzay, G [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires

    1967-11-01

    Radioactive tracers are applied to the direct measurement of the sediment transport rate of sand beds. The theoretical measurement formula is derived: the variation of the count rate balance is inverse of that of the transport thickness. Simultaneously the representativeness of the tracer is critically studied. The minimum quantity of tracer which has to be injected in order to obtain a correct statistical definition of count rate given by a low number of grains 'seen' by the detector is then studied. A field experiment was made and has let to study the technological conditions for applying this method: only the treatment of results is new, the experiment itself is carried out with conventional techniques applied with great care. (author) [French] Les indicateurs radioactifs sont appliques a la mesure directe du debit de charriage des lits sableux. On etablit la formule theorique de mesure: le bilan des taux de comptage varie en sens inverse de l'epaisseur de charriage. Parallelement on fait une etude critique de la representativite de l'indicateur, puis on determine la quantite minimale de traceur qu'il faut immerger pour que les taux de comptage fournis pour un faible nombre de grains 'vus' par le detecteur aient une definition statistique correcte. Une experience de terrain a permis d'etudier les conditions technologiques de cette methode: seul le depouillement des resultats est nouveau. L'experimentation in-situ se fait suivant les procedes classiques avec un tres grand soin. (auteur)

  4. Determination of the free enthalpies of formation of borosilicate glasses; Determination des enthalpies libres de formation des verres borosilicates. Application a l'etude de l'alteration des verres de confinement de dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Linard, Y

    2000-07-01

    This work contributes to the study of the thermochemical properties of nuclear waste glasses. Results are used to discuss mechanisms and parameters integrated in alteration models of conditioning materials. Glass is a disordered material defined thermodynamically as a non-equilibrium state. Taking into account one order parameter to characterise its configurational state, the metastable equilibrium for the glass was considered and the main thermochemical properties were determined. Calorimetric techniques were used to measure heat capacities and formation enthalpies of borosilicate glasses (from 3 to 8 constitutive oxides). Formation Entropies were measured too, using the entropy theory of relaxation processes proposed by Adam and Gibbs (1965). The configurational entropy contribution were determined from viscosity measurements. This set of data has allowed the calculation of Gibb's free energies of dissolution of glasses in pure water. By comparison with leaching experiments, it has been demonstrated that the decreasing of the dissolution rate at high reaction progress cannot be associated to the approach of an equilibrium between the sound glass and the aqueous solution. The composition changes of the reaction area at the glass surface need to be considered too. To achieve a complete description of the thermodynamic stability, the equilibrium between hydrated de-alkalinized glass and/or the gel layer with the aqueous solution should also be evaluated. (author)

  5. Quantification of the greenhouse effect gases at the territorial scale. Final report; Quantification des emissions de gaz a effet de serre a l'echelle territoriale. Rapport final

    Energy Technology Data Exchange (ETDEWEB)

    Magnin, G.; Lacassagne, S

    2003-07-01

    An efficient action against the greenhouse effect needs the implication of the local collectivities. To implement appropriate energy policies, deciders need information and tools to quantify the greenhouse gases and evaluate the obtained results of their greenhouse gases reduction policies. This study is a feasibility study of the tools realization, adapted to the french context. It was done in three steps: analysis of the existing tools, application to the french context and elaboration of the requirements of appropriate tools. This report presents the study methodology, the information analysis and the conclusions. (A.L.B.)

  6. Mass measurement project by determination of Q{sub {beta}} for neutron-rich nuclei; Projet de mesure des masses par determination des Q{sub {beta}} pour des noyaux tres riches en neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Pautrat, M; Lagrange, J M; Petizon, L [Paris-11 Univ., 91 - Orsay (France). Inst. de Physique Nucleaire; Vanhorenbeeck, J; Duhamel, P [Brussels Univ. (Belgium). Inst. d` Astronomie et d` Astrophysique; Binon, F [Universite Libre de Bruxelles (Belgium)

    1994-12-31

    The aim of the project described hereafter is to collect new data on the exotic neutron rich nuclei of the Fe to Zn region, and in particular to determine their masses, for both nuclear physics and astrophysics purposes. These isotopes will be produced through projectile fragmentation at the GANIL facility and selected by the LISE3 spectrometer. Their half-lives will be measured as well as the energy of their main {gamma} rays; {gamma} - {gamma} coincidences will then allow to build a preliminary level scheme. The analysis of {beta} spectra and {beta} - {gamma} coincidences will finally provide the maximum {beta} decay energies of the studied nuclei leading to their masses. The difficulties arising from the low production rates, the {beta} detection, the data handling are discussed together with the solutions proposed to overcome them. (authors). 17 refs.

  7. An attempt at determining Des of glacial sediments using different luminescence methods

    International Nuclear Information System (INIS)

    Ou Xianjiao; Lai Zhongping; Zeng Lanhua

    2013-01-01

    Background: Absolute dating is the key technical issue of Quaternary glacial research. Optically stimulated luminescence (OSL) has been increasingly applied to Quaternary glacial dating in recent years. However, problems such as insufficient bleaching, low luminescence sensitivity, high thermal transfer effect, etc, still remain. Purpose: In order to investigate the applicability of equivalent dose (D e ) determination of glacial sediments by different OSL methods, six samples were collected from the Yingpu Valley of eastern Qinghai-Tibetan Plateau (two samples from modern glacial sediments, three from moraines and glacial terrace attributed to Neoglacial and one from a moraine attributed to the last glaciation). Methods: The D e s were determined by SAR combined SGC technique, using three methods: quartz large aliquot (6 mm) BSL, small aliquot (2/3 mm) BSL and polymineral IRSL. Results: D e s determined by SGC are consistent with D e s determined by SAR protocol. Comparison of three methods shows that IRSL D e >large aliquot BSL D e >small aliquot BSL D e . D e s of polymineral IRSL are obviously higher than quartz BSL. Conclusions: It is obviously that feldspar is more difficult to reset than quartz, thus is not suitable for dating glacial sediments in this region. Quartz large aliquot method is suitable for well bleached glacial samples. Due to the low luminescence sensitivity of quartz, small aliquot method showed poor luminescence characteristics. Moreover, this method cannot distinguish the poor bleached grains in this measurement. However, it is possible that quartz small aliquot, even single grain method could be used to date older or brighter glacial samples. More works are required to solve the problems we have encountered in dating low sensitivity glacial sediments. (authors)

  8. Hydration of swelling clays: multi-scale sequence of hydration and determination of macroscopic energies from microscopic properties; Hydratation des argiles gonflantes: sequence d'hydratation multi-echelle determination des energies macroscopiques a partir des proprietes microscopiques

    Energy Technology Data Exchange (ETDEWEB)

    Salles, F

    2006-10-15

    Smectites have interesting properties which make them potential candidates for engineered barriers in deep geological nuclear waste repository: low permeability, swelling and cations retention. The subject of this thesis consists in the determination of the relationship between hydration properties, swelling properties and cations mobility in relation with confinement properties of clayey materials. The aim is to understand and to predict the behaviour of water in smectites, following two research orientations: the mechanistic aspects and the energetic aspects of the hydration of smectites. We worked on the Na-Ca montmorillonite contained in the MX80 bentonite, with the exchanged homo ionic structure (saturated with alkaline cations and calcium cations). The approach crosses the various scales (microscopic, mesoscopic and macroscopic) and implied the study of the various components of the system (layer-cation-water), by using original experimental methods (thermo-poro-metry and electric conductivity for various relative humidities (RH) and electrostatic calculations. Initially, the dry state is defined by SCTA (scanning calorimetry thermal analysis). Then a classical characterization of the smectite porosity for the dry state is carried out using mercury intrusion and nitrogen adsorption. We evidenced the existence of a meso-porosity which radius varies from 2 to 10 nm depending on the compensating cation. The thermo-poro-metry and conductivity experiments performed at various hydration states made it possible to follow the increase in the pore sizes and the cations mobility as a function of the hydration state. We highlight in particular the existence of an osmotic mesoscopic swelling for low RH (approximately 50-60%RH for Li and Na). By combining the results of thermo-poro-metry, X-ray diffraction and electric conductivity, we are able to propose a complete hydration sequence for each cation, showing the crucial role of the compensating cation in the hydration of

  9. Greenhouse effect gases inventory in France during the years 1990-1999; Inventaire des emissions de gaz a effet de serre en France au cours de la periode 1990-1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-12-01

    The present report supplies emission data, for France and for the period 1990-1999, concerning all the substances involved in the increase in the greenhouse effect and covered under the United Nations' Framework Convention on Climate Change (UNFCCC). The substances are the six direct greenhouse gases covered by the Kyoto protocol: carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), the two species of halogenous substances - hydro-fluorocarbons (HFCs) and per-fluorocarbons (PFCs), and sulphur hexafluoride (SF{sub 6}). Emissions of sulphur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), non methane volatile organic compounds (NMVOCs), and carbon monoxide (CO), gases which indirectly make a significant contribution to the greenhouse effect, are reported under the Convention. The emissions of the six gases that directly contribute to the greenhouse effect are expressed in terms of Global Warming Potential (GWP) which decreased by 2.1 % in 1999 compared to 1990. The emissions of the four gases that indirectly contribute to the greenhouse effect are moving towards decrease: this is by 17% for NO{sub x}, 23% as regards NMVOCs, 33% for CO and by 44% regarding SO{sub 2}. Out of the six greenhouse gases covered by the Kyoto Protocol, CO{sub 2} accounts for the largest share in total GWP emissions (70 %), followed by N{sub 2}O (16 %), CH{sub 4} (12 %), HFCs (0.99 %), SF{sub 6} (0.5 %), and PFCs (0.39 %). (author)

  10. Determinants of the energy storage capacity of electric vehicles; Determinanten des Energiespeicherpotentials von Elektrofahrzeugen

    Energy Technology Data Exchange (ETDEWEB)

    Schlegel, S.; Westermann, D. [Technische Univ. Ilmenau (Germany). FG EEV; Agsten, M. [Fraunhofer IOSB, Ilmenau (Germany). Institutsteil Angewandte Systemtechnik (AST)

    2012-07-01

    Future power systems have to meet the challenge of uncontrollable, decentralized generation through increasing renewable. Utilize energy storage to harmonize the load with fluctuating generation is an option. On the other hand in today's markets large scale energy storage systems are hard to find. The reason is assumed in the high costs. Electric vehicle utilization with smart charging could be an alternative solution, due to the secondary use of the electric vehicles battery when not used for driving. This paper will describe the electric vehicle storage capability which determinants influence the storage potential Therefore a model based approach will be provided, which is based on the experiences of a field test (''MINI-E-Berlin powered by Vattenfall''). (orig.)

  11. Determination of radioactive risks connected with the working of a nuclear plant; Evaluation des risques radioactifs lies au fonctionnement d'une installation nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Lavie, J M; Doury, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Numerous problems which are posed by the evaluation of the radioactive risks linked to the working of a nuclear plant are new problems which have not yet been satisfactorily solved. In these conditions this study must be considered only as a preliminary approach whose essential aims are the following: - development and synthesis of the existing data; - rapid determination of conservative and usable orders of greatness for the security factors, both for normal working and in the case of an accident. The most probable typical accidents are reviewed together with the nature of the resulting risks and the principal factors on which these risks depend. Among these factors, one of the most important is atmospheric diffusion which is studied in some detail using the analytic model due to Sutton. A logical graphical presentation increasing the flexibility in the use of the results and presents the responsible authorities with a flexible, practical and rapid means of evaluating the risks involved starting from a sufficiently general system of initial and simultaneously valid conditions (types of accident, atmospheric conditions). (author) [French] De nombreux problemes souleves par l'evaluation des risques radioactifs lies au fonctionnement d'une installation nucleaire sont des problemes nouveaux qui n'ont pas encore recu de solution satisfaisante. Dans ces conditions cette etude ne doit etre consideree que comme une premiere approche dont les objectifs essentiels sont les suivants: - mise au point et synthese de donnees existantes; - determination rapide d'ordres de grandeur conservatifs et utilisables de valeurs de securite, tant en fonctionnement normal qu'en cas d'accident. Les accidents types les plus probables sont passes en revue ainsi que la nature des risques qui en decoulent et les principaux facteurs dont dependent ces risques. Parmi ces facteurs, l'un des plus importants est la diffusion atmospherique qui fait l'objet d'une etude particuliere a l'aide du modele

  12. Modeling of radiant heat transfers in non-grey gases using the discrete ordinate method in association with a narrow bands statistical model; Modelisation des transferts radiatifs dans des gaz non gris par la methode des ordonnees discretes associee a un modele statistique a bandes etroites

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, A.B. de; Delmas, A; Sacadura, J F [Institut National des Sciences Appliquees (INSA), 69 - Villeurbanne (France)

    1997-12-31

    A formulation based on the use of the discrete ordinate method applied to the integral form of the radiant heat transfer equation is proposed for non-grey gases. The correlations between transmittances are neglected and no explicit wall reflexion is considered. The configuration analyzed consists in a flat layer of non-isothermal steam-nitrogen mixture. Cavity walls are grey with diffuse reflexion and emission. A narrow band statistical model is used to represent the radiative properties of the gas. The distribution of the radiative source term inside the cavity is calculated along two temperature profiles in a uniform steam concentration. Results obtained using this simplified approach are in good agreement with those found in the literature for the same temperature and concentration distributions. This preliminary study seems to indicate that the algorithm based on the integration of radiant heat transfer along the luminance path is less sensitive to de-correlation effects than formulations based on the differential form the the radiant heat transfer. Thus, a more systematic study of the influence of the neglecting of correlations on the integral approach is analyzed in this work. (J.S.) 16 refs.

  13. Modeling of radiant heat transfers in non-grey gases using the discrete ordinate method in association with a narrow bands statistical model; Modelisation des transferts radiatifs dans des gaz non gris par la methode des ordonnees discretes associee a un modele statistique a bandes etroites

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, A.B. de; Delmas, A.; Sacadura, J.F. [Institut National des Sciences Appliquees (INSA), 69 - Villeurbanne (France)

    1996-12-31

    A formulation based on the use of the discrete ordinate method applied to the integral form of the radiant heat transfer equation is proposed for non-grey gases. The correlations between transmittances are neglected and no explicit wall reflexion is considered. The configuration analyzed consists in a flat layer of non-isothermal steam-nitrogen mixture. Cavity walls are grey with diffuse reflexion and emission. A narrow band statistical model is used to represent the radiative properties of the gas. The distribution of the radiative source term inside the cavity is calculated along two temperature profiles in a uniform steam concentration. Results obtained using this simplified approach are in good agreement with those found in the literature for the same temperature and concentration distributions. This preliminary study seems to indicate that the algorithm based on the integration of radiant heat transfer along the luminance path is less sensitive to de-correlation effects than formulations based on the differential form the the radiant heat transfer. Thus, a more systematic study of the influence of the neglecting of correlations on the integral approach is analyzed in this work. (J.S.) 16 refs.

  14. Fission product determination in irradiated fuel processing waste (electrophoresis); Dosage des produits de fission dans les effluents de traitement des combustibles irradies (electrophorese)

    Energy Technology Data Exchange (ETDEWEB)

    Auchapt, J M; Tret, J [Commissariat a l' Energie Atomique, Centre de Marcoule, 30 - Bagnols-sur-Ceze (France). Centre de Production de Plutonium de Marcoule. Services d' Extraction du Plutonium

    1966-07-01

    This dosage method concerns fission products present in the waste produced from the processing of cooled irradiated fuels. - Sr, Cs, Ce, Y, Ru by quantitative analysis; - Zr, Nb by qualitative analysis. It includes electrophoresis on paper strips one meter long which is then analysed between two window-less Geiger counters. For an activity of 10{sup -2} {mu}Ci of any cation in a 10 {mu}l spot, the standard error {sigma} if 3 to 4 per cent. complete analysis lasts about 5 hours. (authors) [French] Cette methode de dosage concerne les produits de fission presents dans les effluents de traitement des combustibles irradies refroidis: - Sr, Cs, Ce, Y, Ru en analyse quantitative; - Zr, Nb en analyse qualitative. Elle comporte une electrophorese sur bande de papier de un metre de longueur suivie d'un depouillement entre deux compteurs Geiger sans fenetre. Pour une activite de 10{sup -2} {mu}Ci d'un cation quelconque dans une tache de 10 {mu}l l'erreur standard {sigma} est de 3 a 4 pour cent. L'analyse complete demande environ 5 heures. (auteurs)

  15. For a better control of the greenhouse gases emissions of the international maritime and aerial baggage holds: evaluation and possible actions; Pour une maitrise des emissions de gaz a effet de serre des soutes internationales aeriennes et maritimes: constat et actions possibles

    Energy Technology Data Exchange (ETDEWEB)

    Sassi, O. [Ecole Nationale des Ponts et Chaussees, 77 - Marne la Vallee (France)

    2003-07-01

    The greenhouse gases emissions resulting from the aerial and marine baggage holds, are not taken into account in the national objectives of greenhouse gases reduction, defined by the Kyoto protocol. Thus they have to be controlled separately by each country concerned by the Kyoto protocol and urgent actions to reduce the greenhouse gases emissions are necessary. This study brings in first parts information on the context (legislation, traffic), the emission inventories and the options of allocation. It proposes then control methods and analyzes the possible measures. (A.L.B.)

  16. Principle and construction of a cell for the dosing of low quantities of oxygen in gases; Principe et construction d'une cellule de dosage des faibles quantites d'oxygene dans les gaz

    Energy Technology Data Exchange (ETDEWEB)

    Schaub, Bernard; Nolin, Jean- Paul [Commissariat a l' energie atomique et aux energies alternatives - CEA, Departement de Metallurgie, Service de Recherches de Metallurgie Physique et Chimique (France)

    1964-02-15

    This note presents a cell which is mainly a pile and is aimed at analysing a gas absorbed on the cathode surface and passed through a membrane by means of hydroxyl ions. The objective of this analysis is to dose low quantities of oxygen contained in gases. The pile construction is briefly described, as well as its regeneration, its calibration, its performance (sensitivity, flow rate influence, resistance influence, temperature influence), and its electric circuits.

  17. Study of total ionization by {alpha} particles, in pure gases and gaseous mixtures containing metastable atoms, as a function of temperature; Etude de l'ionisation totale par les paricules {alpha}, dans les gaz purs et les melanges gazeux contenant des atomes metastables, en fonction de la temperature

    Energy Technology Data Exchange (ETDEWEB)

    Bristeau, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    Experiments have been carried out on the total ionization by alpha particles, in pure gases and gaseous mixtures containing metastable atoms, as a function of temperature. Using a different experimental method, the results for the mean ionization energy at 300 K given by Jesse in 1953 have been confirmed to within 1 per cent. It is established that in pure gases the mean energy W required to form a pair of ions remains constant as the temperature varies from 77 to 300 K. It is shown that there is a temperature effect for W in binary gas mixtures of the type A-B containing meta-stable atoms A{sup *} and an 'impurity' B. A systematic study is made of the change {delta}W in W as a function of the temperature and of the B 'impurity' concentration in the mixtures Ne - Ar, Ne - Kr, Ne - H{sub 2}, Ne - N{sub 2}, Ne - CH{sub 4} and He - Ar. Experiments have been carried out on a ternary gas mixture of the type A - B - C, where C is a second ionizable 'impurity' added to the binary mixture A - B; they show the existence of excited atoms B{sup *} formed from the 'impurity' B. Finally, it is shown that the amount of metastable atoms formed in a pure gas must be very close to the number N{sub 0} of ion pairs, and that there must exist a correlation between the number N{sub 0} of ion pairs and the number {approx_equal} N{sub 0} of metastable atoms created in the pure rare gases. (author) [French] On realise des experiences sur l'ionisation totale par les particules alpha, dans les gaz purs et les melanges gazeux contenant des atomes metastables, en fonction de la temperature. Avec une methode experimentale differente, on retrouve a mieux que 1 pour cent pres les valeurs de l'energie moyenne d'ionisation que JESSE a obtenues en 1953 et a 300 K. On etablit que dans les gaz purs, l'energie moyenne W pour creer une paire d'ions demeure constante, quand la temperature varie entre 77 et 300 K. On met en evidence un effet de temperature sur W, dans les melanges gazeux binaires du type

  18. The Cyrano program. 1 - description and operation of an irradiation device 'Cyrano'. 2 - results of the experiments Cyrano 1 and 2 (study of the EL 4 first-bach pencil); measurement of the thermal conductivity integral for UO{sub 2} sintered up to 2300 deg C; evolution of fission gases at constant power; Programme Cyrano. 1 - description et exploitation d'un dispositif d'irradiation ''cyrano''. 2 - resultats des experiences cyrano 1 et 2 (etude du crayon EL4 1. jeu). Mesure de l'integrale de conductibilite thermique d'UO{sub 2} fritte jusqu'a 2300 deg C. Evolution des gaz de fission a puissance constante

    Energy Technology Data Exchange (ETDEWEB)

    Stora, J P; Chenebault, P [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    Two rods of the type 'EL 4 first score' have been irradiated in 'Cyrano' capsules which are suited for continuous measurement of the nuclear power evolved and equipped with thermocouples. The variations of the integral of conductivity of sintered 96 per cent theoretical dense UO{sub 2} has been established until 2300 deg. C; these variations are coherent with those previously measured out-of-pile. The released fission gases have been recovered at different times during the irradiation: the kinetics of release of stable gases is such that, in the experimental conditions (T{sub surface} = 610 deg. C, {integral}{sub T{sub s}}{sup T{sub c}} kdT = 34.7 W cm{sup -1}) the fraction of released gases is still widely increasing after 12 days of irradiation. Numerous observations have been made on concentrations of rare gases locally present in the irradiated fuel. (authors) [French] L'irradiation de deux crayons combustibles type EL 4, 1er jeu, a ete menee a bien dans des capsules 'Cyrano' equipees de dispositifs de mesure continue de la puissance nucleaire et de plusieurs reperes de temperatures; la variation de l'integrale de conductibilite thermique de l'oxyde d'uranium fritte (96 pour cent d. th.) a ete tracee jusqu'a 2300 deg. C; la courbe representative de ces variations est coherente avec celle obtenue precedemment hors pile. Les gaz de fission apparus hors du combustible ont ete extraits du crayon a plusieurs reprises pendant l'experience: la cinetique d'accumulation des gaz stables est telle que dans les conditions etudiees (T{sub surface} = 610 deg. C, {integral}{sub T{sub s}}{sup T{sub c}} kdT = 34.7 W cm{sup -1}) la fraction des gaz degages est encore largement croissante apres 12 jours d'irradiation. De nombreuses observations ont ete recueillies sur la nature et la concentration des gaz rares presents en differents points du combustible irradie. (auteurs)

  19. Methods for determining thermal stresses values. Some examples relating to nuclear reactors; Methodes de determination des contraintes thermiques. Quelques exemples d'application aux reacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J; Gautier, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Peres, A [Israel Institute of Technology, Dept. of Nuclear Science Technion (Israel)

    1958-07-01

    As modern techniques develop more elaborate machines, and make their way towards higher and higher temperatures and pressures, the thermal stresses become a matter of major importance in the design of mechanical structures. In the first part of this paper, the authors examine the problem from a theoretical standpoint, and try to evaluate the aptitude and limitation of mathematical techniques to attain the quantitative values of thermal stresses. This paper deals mainly with the experimental methods to measure thermal stresses. The authors show some examples relating to nuclear reactors. (author)Fren. [French] Au fur et a mesure que la technique moderne developpe des machines plus poussees et s'oriente vers des temperatures et des pressions toujours plus elevees, les contraintes thermiques deviennent un facteur d'importance capitale dans le calcul des structures mecaniques. Les auteurs examinent d'abord l'aspect theorique du probleme, ainsi que l'aptitude et les limites du calcul pour exprimer quantitativement la valeur des contraintes thermiques. Les auteurs exposent principalement, ensuite, les methodes experimentales qui permettent de mesurer ces contraintes, et illustrent cet expose de quelques exemples relatifs aux installations nucleaires. (auteur)

  20. The determination methods of the velocity constant for electrochemical reactions; Les methodes de determination de la constante de vitesse des reactions electrochimiques

    Energy Technology Data Exchange (ETDEWEB)

    Molina, R

    1963-07-01

    In a brief introduction are recalled the fundamental mechanisms of the electrochemical reaction and the definition of the intrinsic velocity constant of a such reaction. By the nature of the different parameters which enter in this definition are due some experimental problems which are examined. Then are given the principles of the measurement methods of the velocity constant. These methods are developed with the mathematical expression of the different rates of the mass transfer to an electrode. In each case are given the experimental limits of use of the methods and the size order of the velocity constant that can be reached. A list of fundamental works to be consulted conclude this work. (O.M.) [French] Dans une breve introduction sont rappeles les mecanismes fondamentaux de la reaction electrochimique et la definition de la constante de vitesse intrinseque d'une telle reaction. De la nature des differents parametres qui entrent dans celle definition, decoulent un certain nombre de problemes experimentaux qui sont passes en revue. On donne ensuite les principes des methodes de mesure de la constante de vitesse. L'exposition de ces methodes est developpee a l'aide de l'expression mathematique des differents regimes de transfert de masse a une electrode. On s'attache dans chaque cas, a donner les limitations experimentales d'utilisation des methodes et l'ordre de grandeur de la constante de vitesse qu'elles permettent d'atteindre. Une liste des ouvrages fondamentaux a consulter conclut ce travail. (auteur)

  1. 40 CFR 89.312 - Analytical gases.

    Science.gov (United States)

    2010-07-01

    ... determined to calibration gas tolerances by chromatographic analysis of total hydrocarbons plus impurities or.... (2) Mixtures of gases having the following chemical compositions shall be available: (i) C3H8 and... check gases shall contain propane with 350 ppmC ±75 ppmC hydrocarbon. The three oxygen interference...

  2. Greenhouse Gases Concentrations in the Atmosphere Along ...

    African Journals Online (AJOL)

    This study investigated effect of vehicular emission on greenhouse gases concentrations along selected roads of different traffic densities in Abeokuta, Ogun State, Nigeria. Nine roads comprised highway, commercial and residential were selected. Greenhouse Gases (GHGs) were determined from both sides of the roads by ...

  3. [Gases in vitreoretinal surgery].

    Science.gov (United States)

    Janco, L; Vida, R; Bartos, M; Villémová, K; Izák, M

    2012-02-01

    To evaluate the importance and benefits of using gases in vitreoretinal surgery. The gases represent a wide group of substances used in eye surgery for more than 100 years. The role of intraocular gases in vitreoretinal surgery is irreplaceable. Their use is still considered to be the "gold standard". An important step in eye surgery was the introduction of expanding gases--sulfur hexafluoride and perfluorocarbons into routine clinical practice. The most common indications for the use of intraocular gases are: retinal detachment, idiopathic macular hole, complications of vitreoretinal surgery and others. The introduction of intraocular gases into routine clinical practice, along with other modern surgical techniques resulted in significant improvement of postoperative outcomes in a wide range of eye diseases. Understanding the principles of intraocular gases use brings the benefits to the patient and physician as well. Due to their physical and chemical properties they pose far the best and most appropriate variant of intraocular tamponade. Gases also bring some disadvantages, such as difficulties in detailed fundus examination, visual acuity testing, ultrasonographic examination, difficulties in application of intravitreal drugs or reduced possibility of retina laser treatment. The gases significantly change optical system properties of the eye. The use of gases in vitreoretinal surgery has significantly increased success rate of retinal detachment surgery, complicated posterior segment cases, trauma, surgery of the macula and other diseases.

  4. Extraction with supercritical gases

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, G M; Wilke, G; Stahl, E

    1980-01-01

    The contents of this book derives from a symposium on the 5th and 6th of June 1978 in the ''Haus der Technik'' in Essen. Contributions were made to separation with supercritical gases, fluid extraction of hops, spices and tobacco, physicochemical principles of extraction, phase equilibria and critical curves of binary ammonia-hydrocarbon mixtures, a quick method for the microanalytical evaluation of the dissolving power of supercritical gases, chromatography with supercritical fluids, the separation of nonvolatile substances by means of compressed gases in countercurrent processes, large-scale industrial plant for extraction with supercritical gases, development and design of plant for high-pressure extraction of natural products.

  5. Handbook of purified gases

    CERN Document Server

    Schoen, Helmut

    2015-01-01

    Technical gases are used in almost every field of industry, science and medicine and also as a means of control by government authorities and institutions and are regarded as indispensable means of assistance. In this complete handbook of purified gases the physical foundations of purified gases and mixtures as well as their manufacturing, purification, analysis, storage, handling and transport are presented in a comprehensive way. This important reference work is accompanied with a large number of Data Sheets dedicated to the most important purified gases.  

  6. Gases in molten salts

    CERN Document Server

    Tomkins, RPT

    1991-01-01

    This volume contains tabulated collections and critical evaluations of original data for the solubility of gases in molten salts, gathered from chemical literature through to the end of 1989. Within the volume, material is arranged according to the individual gas. The gases include hydrogen halides, inert gases, oxygen, nitrogen, hydrogen, carbon dioxide, water vapor and halogens. The molten salts consist of single salts, binary mixtures and multicomponent systems. Included also, is a special section on the solubility of gases in molten silicate systems, focussing on slags and fluxes.

  7. Prevention of air pollution: guidebook of the French techniques of dedusting and purification of gases and smokes in the industry; Prevention de la pollution de l'air: guide des techniques francaises de depoussierage et d'epuration des gaz et fumees dans l'industrie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    This new edition favours the multi-pollutants approach and integrates the improvements made in the European standardization of emission measurements. It contributes to the diffusion of the French techniques in the domain of gases dedusting and purification. (J.S.)

  8. Diffusion coefficients gases, dissolved in fluid of NPPs circulation contours

    International Nuclear Information System (INIS)

    Piontkovskij, A.I.

    2000-01-01

    In article is brought analysis of diverse gases diffusion coefficients computation methods, dissolved in liquid. On the basis of this analysis and treatment of being equalizations for concrete gases and certain parameters offers universal diffusion coefficients determination dependence for diverse gases in wide range of parameters, circulation contours typical for work NPP

  9. Contribution to the activation analysis of the rare gases. Contribution to the analysis of carbon monoxide and water vapour in gases (1963); Contribution a l'analyse par activation des gaz rares. Contribution a l'analyse de l'oxyde de carbone et de la vapeur d'eau dans les gaz (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Diebolt, J [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-07-15

    In the present work, we have applied radioactive analysis to the general technique of rare gas separation. This separation is carried out on active charcoal, at constant pressure. The desorption of the gas is caused by an increase in the initial temperature of adsorption. These separations are quantitative and can be confirmed by chemical analysis. The volumes of desorbed gas are measured by radioactive counting. We have also used radioactivation to study the reduction of palladous chloride by carbon monoxide. Since this reduction is quantitative, we can have a knowledge of the mass of palladium reduced by measuring its activity. We have used the property which have organic chlorides of being hydrolysed by water vapour and of liberating hydrochloric acid to study quantitatively the amount of water vapour which a gas contains. The hydrochloric acid formed is measured by activation of the chlorine in the acid. (author) [French] Dans les travaux que nous presentons, nous avons applique l'analyse par radioactivation, a la technique generale de separation des gaz rares. Cette separation est faite sur charbon active, a pression constante. La desorption des gaz est provoquee par une augmentation de la temperature initiale d'adsorption. Ces separations sont quantitatives, et peuvent etre exploitees par l'analyse chimique. Les volumes de gaz dedorbes sont mesures par comptage de la radioactivite. Nous avons egalement utilise la radioactivation pour l'etude de la reduction du chlorure palladeux par l'oxyde de carbone. Cette reduction etant quantitative, nous pouvons connaitre la masse de palladium reduit par la mesure de son activite. Nous avons exploite la propriete que possede un chlorure organique d'etre hydrolise par la vapeur d'eau et de liberer de l'acide chlorhydrique pour etudier quantitativement la vapeur d'eau contenue dans un gaz. L'acide chlorhydrique forme est mesure par l'activation du chlore de l'acide. (auteur)

  10. Rheological online determination of the organic dry substance concentration of sewage sludge; Rheologische online Bestimmung des oTS-Gehalts von Klaerschlamm

    Energy Technology Data Exchange (ETDEWEB)

    Schmitz, P.; Boehm, A.; Fessler, J.; Liebelt, U. [BASF AG, Ludwigshafen am Rhein (Germany); Traegner, U. [Fachhochschule fuer Technik, Mannheim (Germany)

    1999-07-01

    In order to adjust the filter cake to a certain calorific value and to enhance the dehydratability of sludge, ash, carbon and flocculation agents are added to the latter prior to filtration. Dosage of the additives depends on the sludge's content of organic solids, determined in the form of the so-called organic dry substance concentration. In bench-scale and technical-scale experiments on the rheological properties of sewage sludge, a correlation between organic dry substance concentration and rheological properties, especially the liquid limit of sewage sludge, was established. This knowledge was used to develop a measuring technique for online determination of organic dry substance concentration by means of rheology. (orig.) [German] Zur Einstellung eines bestimmten Heizwertes des Filterkuchens und zur Verbesserung der Entwaesserbarkeit werden dem Schlamm vor der Filtration Asche, Kohle und Flockungsmittel zugegeben. Die Dosierung der Zuschlagsstoffe erfolgt in Abhaengigkeit vom Gehalt des Schlamms an organischem Feststoff, bestimmt in Form der sog. oTS-Konzentration. In Labor- und Betriebsversuchen zum rheologischen Verhalten von Klaerschlamm konnte eine Korrelation zwischen der oTS-Konzentration und den Fliesseigenschaften, insbesondere der Fliessgrenze von Klaerschlamm ermittelt werden. Diese Erkenntnis wurde in ein Messverfahren zur online-Bestimmung der oTS-Konzentration mittels Rheologie umgesetzt. (orig.)

  11. Le problème des hydrates dans le contexte de la production et du transport polyphasiques des pétroles bruts et des gaz naturels. Deuxième partie : les solutions possibles aux difficultés d'exploitation générées par les hydrates Hydrates Problem Within the Framework of Multiphase Production and Transport of Crude Oils and Natural Gases. Part Two: Possible Solutions to Exploitation Difficulties Generated by Hydrates

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available L'exploitation en mer des gisements de combustibles fossiles fluides a amplifié le besoin d'accroître nos connaissances sur les hydrates qui sont susceptibles de boucher les installations de production, de traitement et de transport. La première partie rappelait la structure moléculaire des hydrates I, Il et H et décrivait ensuite succinctement l'analyse physico-chimique de leur formation, tant sur les plans thermodynamique que cinétique. Dans cette deuxième partie, les remèdes possibles aux problèmes rencontrés par les compagnies opératrices sont indiqués, essentiellement les inhibiteurs thermodynamiques classiques tels que les alcools ou les sels qui diminuent la température de formation des hydrates, et les additifs dispersants qui évitent la croissance et/ou l'agglomération des cristaux. Pour terminer, une boucle pilote de circulation originale est présentée, ses caractéristiques qui permettent la validation des additifs dispersants dans des conditions hydrodynamiques et physico-chimiques représentatives étant soulignées. Offshore exploitation of fossil fluid fuels has emphasized the need of improving our knowledge on hydrates which can plug production, treatment and transport facilities. The first part recalled the molecular structure of I, II and H hydrates, then the physical-chemistry of their formation was briefly reviewed from both the thermodynamic and the kinetic points of view. In this second part, the possible remedies to the problems met by operating companies are described, mainly classical thermodynamic inhibitors such as alcohols or salts which decrease the hydrates formation temperature, and dispersant additives which avoid crystals growth and/or agglomeration. At last an original circulation loop at pilot scale is presented, its characteristics which allow the testing of dispersant additives under representative hydrodynamic and physico-chemical conditions being outlined.

  12. Principle of the determination of neutron multiplication coefficients by the Monte Carlo method. Application. Description of a code for ibm 360-75; Principe de la determination des coefficients de multiplication neutronique par methode de Monte-Carlo. Application. Description d'un code pour IBM 360-75

    Energy Technology Data Exchange (ETDEWEB)

    Moreau, J; Parisot, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The determination of neutron multiplication coefficients by the Monte Carlo method can be carried out in different ways; the are first examined particularly complex geometries; it makes use of multi-group isotropic cross sections. The performances of this code are illustrated by some examples. (author) [French] La determination des coefficients de multiplication neutronique par methode de Monte Carlo peut se faire par differentes voies, elles sont successivement examinees et comparees. On en deduit un code rapide pour des geometries particulierement complexes, il utilise des sections efficaces multigroupes isotropes. Les performances de ce code sont demontrees par quelques exemples. (auteur)

  13. Kinetic theory of gases

    CERN Document Server

    Kauzmann, Walter

    2012-01-01

    Monograph and text supplement for first-year students of physical chemistry focuses chiefly on the molecular basis of important thermodynamic properties of gases, including pressure, temperature, and thermal energy. 1966 edition.

  14. AC BREAKDOWN IN GASES

    Science.gov (United States)

    electron- emission (multipactor) region, and (3) the low-frequency region. The breakdown mechanism in each of these regions is explained. An extensive bibliography on AC breakdown in gases is included.

  15. The use of polarized deuterons beams and the determination of the optical model parameters; Utilisation de faisceaux de deutons polarises et determination des parametres du modele optique

    Energy Technology Data Exchange (ETDEWEB)

    Raynal, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-06-15

    entraine des relations entre les parametres adoptes. Les limitations de ces parametres sont etudiees specialement dans le cas d'un faisceau de particules de spin 1 ayant un plan de symetrie. Les reactions nucleaires a deux corps sont decrites dans le formalisme de l'helicite. A l'aide des coefficients de polarisation adoptes, on etudie la polarisation dans l'etat final avec etat initial polarise. Un potentiel optique pour deutons pout comprendre une partie scalaire, un couplage L.S et des potentiels tensoriels formes avec la distance du deuton au noyau, son moment angulaire ou son impulsion relative. Des calculs ont ete faits avec les deux premieres sortes de potentiels tensoriels. Plusieurs auteurs ont calcule un potentiel pour deutons a partir du modele optique nucleon oyau. Ces calculs sont repris en considerant l'onde S et l'onde D du deuton. Les differentes parties du potentiel ont ete calculees avec plusieurs fonctions d'onde intrinseque. L'utilisation de potentiels non uniquement scalaires permet d'obtenir de bons accords pour la section efficace avec des rayons nucleaires plus eleves que ceux necessaires avec un potentiel purement central. Les mesures experimentales de polarisation faites a Saclay pour la diffusion elastique de deutons sur le calcium sont en desaccord avec l'existence d'un potentiel tensoriel important ; elles peuvent etre reproduites en utilisant un couplage L.S. independant du potentiel central, mais avec des rayons tres faibles. (auteur)

  16. Chemical and isotopic fractionations of natural gases during their migration. Importance of methane solubilization and diffusion during geological times; Fractionnements chimiques et isotopiques des gaz naturels lors de leur migration. Importance de la solubilisation et de la diffusion du methane au cours des temps geologiques

    Energy Technology Data Exchange (ETDEWEB)

    Pernaton, E

    1998-09-09

    Two experimental devices have been elaborated in the purpose of simulating in laboratory the solubilization of methane in water and the migration by solubilization/diffusion of some gas species (methane, ethane, propane and nitrogen) through porous media saturated with water. Significant shifts in isotopic ratios of diffused methane (carbon and hydrogen) have been observed. Those fractionations for carbon isotopes, which in most cases are characterised by a {sup 12}C-enriched diffused methane, have fundamental consequences about the interpretation of the origin of methane in sedimentary basins and, in a more general way, about the genetic characterisation of hydrocarbon gases in reservoirs. Indeed, this gives an ambiguous origin for any gas having {sup 12}C-enriched methane, two different interpretations are possible: mixing between thermogenic and bacterial hydrocarbon gases and a diffusive trend during migration. Using a diagram C2/C1 versus {delta}{sup 13}C1, we have shown that in some geological cases, these two processes, mixing and diffusion, exist and that it is possible to discern them.The chemical and isotopic compositions of natural gases do not only reflect genetic processes but are also an indication of their migration. Moreover, the experiments have shown that the gas transport by solubilization/diffusion is a potential operator of gas leakage from natural accumulations. In consequence, a numerical model of gas migration through cap rocks of reservoirs has been elaborated and will be integrated into sedimentary basin models. (author)

  17. Reale Gase, tiefe Temperaturen

    Science.gov (United States)

    Heintze, Joachim

    Wir werden uns in diesem Kapitel zunächst mit der van der Waals'schen Zustandsgleichung befassen. In dieser Gleichung wird versucht, die Abweichungen, die reale Gase vom Verhalten idealer Gase zeigen, durch physikalisch motivierte Korrekturterme zu berücksichtigen. Es zeigt sich, dass die van derWaals-Gleichung geeignet ist, nicht nur die Gasphase, sondern auch die Phänomene bei der Verflüssigung von Gasen und den kritischen Punkt zu beschreiben.

  18. Gases in uranium exploration

    International Nuclear Information System (INIS)

    Wright, R.J.; Pacer, J.C.

    1981-01-01

    Interest continues to grow in the use of helium and radon detection as a uranium exploration tool because, in many instances, these radiogenic gases are the only indicators of deeply buried mineralization. The origin of these gases, their migration in the ground, the type of samples and measurement techniques are discussed. Case histories of comparative tests conducted on known uranium deposits at three geologically diverse sites in the United States of America are also presented. (author)

  19. Determination of the exchange capacity of soils using radio-strontium; Determination de la capacite d'echange des sols au moyen du radio-strontium

    Energy Technology Data Exchange (ETDEWEB)

    Grauby, A; Saas, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    In order to improve the technique and in particular to reduce the time required for measuring the exchange capacity of soils, the authors have developed a rapid measurement method based on the use of radio-active tracers. The element chosen for showing the occurrence of exchangeable bases is radio-strontium; it can displace the ions Ca{sup ++}, Mg{sup ++}, Na{sup ++}, K{sup +} from the soil. The use of a de-sorbent, barium chloride, makes it possible to recover the strontium fixed. A comparison of the results obtained using the two methods appears to be very satisfactory. The conventional method requires from 1 1/2 to 2 days - the radio-strontium method requires only 3 hours with the possibility also of carrying out large series of measurements. (authors) [French] Pour ameliorer la technique et surtout reduire le temps de manipulation que necessite la mesure de la capacite d'echange des sols, les auteurs ont mis au point une methode de mesure rapide qui fait appel aux traceurs radioactifs. C'est le radio-strontium qui a ete choisi pour la mise en evidence des bases echangeables. Il permet de deplacer les ions Ca{sup ++}, Mg{sup ++}, Na{sup ++}, K{sup +} du sol. Un desorbant, le chlorure de baryum, permet de recuperer la quantite du strontium fixe. La comparaison des resultats obtenus par les deux methodes semble tres satisfaisante. La methode classique necessite 1 jour et demi a 2 jours - la methode radiostrontium exige seulement 3 heures avec la possibilite de grandes series. (auteurs)

  20. Determination of endogenous and exogenous corticosteroids in bovine urine and effect of fighting stress during the "Batailles des Reines" on their biosynthesis.

    Science.gov (United States)

    Leporati, Marta; Nobile, Maria; Capra, Pierluigi; Alladio, Eugenio; Vincenti, Marco

    2017-10-01

    Natural corticosteroids include two families of substances: mineralocorticoids and glucocorticoids. Several drugs of similar structure and biological activity have been synthesized and are currently used in the clinical practice. Beside legal pharmacological treatments, these drugs have been consistently misused in animal breeding. One of the most abused corticosteroids is prednisolone. For many years, prednisolone has been considered of exclusive synthetic origin, but nowadays a debate about its possible endogenous production is under way. Several studies have been addressed to ascertain the potential relationship between stressful conditions, such as transportation and slaughtering, and endogenous production of prednisolone. In order to verify further the effect of stressful conditions, our laboratory analysed urine samples collected from the cows participating to the "Batailles des Reines" (a traditional contest based on ritual and spontaneous fights of pregnant cows), to verify if an endogenous prednisolone production may occur in these animals. We developed and validated a LC-MS/MS method for the simultaneous determination of cortisol, cortisone, prednisolone and five of its metabolites. The method was applied to the analysis of urine samples collected from "Batailles des Reines" competitions in 2012 and 2013. All these samples had been previously analysed within an anti-doping control program and tested compliant to all screenings. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Heavy element concentration determination by the x-ray fluorescence analysis using radioisotope {gamma}-ray sources; Dosage d'elements lourds par fluorescence X utilisant des radio-sources de rayons gamma

    Energy Technology Data Exchange (ETDEWEB)

    Enomoto, S [Commissariat a l' Energie Atomique, Dir. des Materiaux et des Combustibles Nucleaires, Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    A theoretical and experimental study has been made on the fluorescence analysis of high atomic number element, using {gamma}-ray sources for excitation and characteristic K X-rays for the measurement. The choice of the proper {gamma}-ray energy according to the conditions of the determination is considered. The author has studied the usefulness of using the backscattered {gamma}-rays as a correction mean for matrix and grain-size effects. Sources of {sup 153}Gd, {sup 57}Co, {sup 137}Cs have been used for excitation using collimated geometries. Concentration measurements of tungsten in steel, tungsten and lead in aqueous solution, PbS in SiO{sub 2}-PbS powder mixtures have been done, as well as thickness evaluation of gold layers on copper. A precision of about 0.2 per cent (abs.) is obtained for lead determination in light matrixes. A probe design is proposed for the continuous determination of lead in aqueous solutions. (author) [French] On etudie de maniere theorique et experimentale l'analyse d'elements a nombre atomique eleve par fluorescence en utilisant des sources de rayons {gamma} pour l'excitation, et des rayons-X K caracteristiques pour la mesure. On considere le choix de l'energie appropriee des rayons {gamma} suivant les conditions experimentales. L'utilite d'employer les rayons {gamma} retrodiffuses pour corriger les effets de la matrice et de la dimension des grains est etudiee. Des sources de {sup 153}Gd, de {sup 57}Co et de {sup 137}Cs a geometrie collimatee ont ete utilisees pour l'excitation. Des mesures de la concentration du tungstene dans l'acier, du tungstene et du plomb en solutions aqueuses, et du PbS dans des melanges de poudre SiO{sub 2}-PbS ont ete entreprises ainsi que l'evaluation de l'epaisseur des couches d'or sur le cuivre. On obtient une precision d'environ 0,2 pour cent (en absolu) pour la determination du plomb dans des matrices legeres. On propose un modele de sonde pour la determination en continu du plomb en solution aqueuse

  2. Avalanches in insulating gases

    International Nuclear Information System (INIS)

    Verhaart, H.F.A.

    1982-01-01

    Avalanches of charged particles in gases are often studied with the ''electrical method'', the measurement of the waveform of the current in the external circuit. In this thesis a substantial improvement of the time resolution of the measuring setup, to be used for the electrical method, is reported. The avalanche is started by an N 2 -laser with a pulse duration of only 0.6 ns. With this laser it is possible to release a high number of primary electrons (some 10 8 ) which makes it possible to obtain sizeable signals, even at low E/p values. With the setup it is possible to analyze current waveforms with a time resolution down to 1.4 ns, determined by both the laser and the measuring system. Furthermore it is possible to distinguish between the current caused by the electrons and the current caused by the ions in the avalanche and to monitor these currents simultaneously. Avalanche currents are measured in N 2 , CO 2 , O 2 , H 2 O, air of varying humidity, SF 6 and SF 6 /N 2 mixtures. Depending on the nature of the gas and the experimental conditions, processes as diffusion, ionization, attachment, detachment, conversion and secondary emission are observed. Values of parameters with which these processes can be described, are derived from an analysis of the current waveforms. For this analysis already published theories and new theories described in this thesis are used. The drift velocity of both the electrons and the ions could be easily determined from measured avalanche currents. Special attention is paid to avalanches in air becasue of the practical importance of air insulation. (Auth.)

  3. Tin dioxide: synthesis, characterization and study of the interactions with different polluting gases - application to DeNOx catalysis; Dioxyde d'etain: synthese, caracterisation et etude des interactions avec differents gaz polluants - application a la catalyse DeNOx

    Energy Technology Data Exchange (ETDEWEB)

    Sergent, N

    2003-01-01

    Two high specific surface area tin dioxides after calcination at 600 degrees C under O{sub 2} have been synthesized: SnO{sub 2}-HNO{sub 3} (24 m{sup 2} g{sup -1}) and SnO{sub 2}-N{sub 2}H{sub 4} (101 m{sup 2} g{sup -1}). The surface of the 600 degrees C - calcined SnO{sub 2}-N{sub 2}H{sub 4} sample was found to be more hydroxylated than the 600 degrees C - calcined SnO{sub 2}-HNO{sub 3} one. The thermal treatment under O{sub 2} involves the formation of mono-ionized oxygen vacancies, leading to non-stoichiometric tin dioxides. A specific treatment like outgassing at temperatures above 300-400 degrees C, was found to be necessary to extract surface oxygen atoms. The CO adsorption at liquid N{sub 2} temperature on the SnO{sub 2}-N{sub 2}H{sub 4} sample has shown the existence of two cationic Sn{sup 4+} sites, having different Lewis acidities. Concerning the surface OH groups, it has been observed: i) hydroxyl which are inaccessible to CO, ii) weakly acidic surface hydroxyl and iii) surface hydroxyl having a weak Broensted acidity. Then, a study of the interactions between the 600 degrees C - calcined SnO{sub 2}-N{sub 2}H{sub 4} sample and various pollutant gases has been carried out by transmission FTIR spectroscopy. Carbon dioxide interacts with SnO{sub 2} surface, leading to CO{sub 2} species adsorbed on cationic sites together with carbonates and bicarbonates ad-species. Carbon monoxide involves the partial reduction of SnO{sub 2} surface by reaction of CO with surface oxygens to form carbonate species and CO{sub 2}. Interactions of SnO{sub 2} surface with NO{sub 2} have shown the formation of NO{sup +}, nitrite and nitrate ad-species. The NO adsorption on SnO{sub 2}-N{sub 2}H{sub 4} have shown the formation of electron donor species (nitrite and nitrate species) together with electron acceptor species (nitrosyl species). Finally, in the Selective Catalytic Reduction (SCR) of NO{sub x} by propene in oxygen excess, SnO{sub 2} was found to be active at high

  4. Unified fit of solar and atmospheric neutrinos: towards the MNSP matrix; Ajustements globaux des resultats des experiences de neutrinos solaires et atmospheriques: vers la determination de la matrice de melange des neutrinos (dite MNSP)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-01-01

    Present solar and atmospheric neutrino give a strong indication that neutrinos oscillate between the three active species. This is the first step towards the determination of their mass. But we have also to determine the 3 x 3 neutrino mixing matrix (3 angles and one or several phases linked to CP violation), called MNSP (Maki-Nakagawa-Suzuki-Pontecorvo) and similar to the quark mixing matrix, called CKM (Cabibbo-Kobayashi-Maskawa). The purpose of the colloquium (one day) is to give an overview of the present situation and what progresses are expected in the forthcoming years. 3 guidelines: pedagogical approach, critical review of the experimental situation and of the different analyses, lookout to the future. (author)

  5. Grain scale stresses and strains determination by X-ray diffraction; Contribution a l'analyse par diffractometrie X des deformations et des contraintes a l'echelle des grains

    Energy Technology Data Exchange (ETDEWEB)

    Huang, W

    2007-03-15

    A new methodology for strain and stress analysis by X ray diffraction (XRD) in single crystal was developed. It can be applied to determine the second order stress (in grain scale) in single and multi-crystal material with non-cubic lattice. This method is based on the method Ortner I. It has introduced the metric tensor G which is deduced from the lattice space measured by XRD. In the developed method, when the crystal reference is non-orthonormal, an orthonormal reference associated with the crystal basis is defined, so all calculation could be done with usual calculation laws. The use of the least square method allows the acquisition of many more measurements than the six absolute necessary. Then a better metric tensor G is calculated and the statistical error is obtained. This developed method was applied in a bi crystal copper. The experimental results have shown that this method is also effective. The second order residuals stresses for coarse Zn grains in a galvanized coating were determined after annealing. The four coarse grains with different orientations were also characterized and demonstrated the elastic and plastic deformation mechanism in a grain or between the grains during in situ tensile loading. So this method is well able to determine the strains and stresses in grain scale in a mono crystal or multi crystal with any crystalline structure. (author)

  6. Fuel material neutron crystallography texture and structure determinations (1960); Etudes sur l'evolution des structures cristallines de l'uranium par neutrocristallographie (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Laniesse, J; Englander, M; Meriel, P [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The method here described has the advantage over the classic X-ray diffraction method of giving fuller and quicker information about the texture of a built polycrystalline aggregate of U metal, and of following more easily the evolution of its crystalline structure during the allotropic transformation. It uses a thermal neutron beam coming out of the Saclay CEN reactor EL3, monochromatized at {lambda} = 1,143 {+-} 0,030 Angstrom, and directed after collimation, perpendicularly to the fiber axis of an optimized dimensioned cylindrical specimen. The scattered neutron beam is collected into a BF3 counter which is able to describe in a horizontal plane containing the neutron beam axis, a circle 130 cm in radius centered on the specimen. In testing at room temperature a specimen which is entirely free from residual or parasite texture, the reference spectral lines of pure U alpha phase are determined by means of a recording meter and a counting device. The same method gives the spectral distribution of the U beta phase by using, instead of pure uranium, a metastable solid solution containing a minimum concentration of some metallic impurities (Cr or Si). These spectra are then compared with the calculated ones and the X-ray diffraction ones. After choosing a certain number of given diffraction lines, it was possible to check qualitatively and semi-quantitatively the evolution of eventual predominant orientations versus mechanical and/or thermal treatments. By following the intensity of a 'mixed' spectrum line suitably placed within the lines of the {alpha} and {beta} spectra, it was possible to determine the kinetic of the {beta} {yields} {alpha} transformation at temperature where frequency and counting rates are adequate. By way of examples, the paper illustrates results obtained with a 600 deg. C extruded pure U rod (reduction in area = 6 ,4) , and with a four times beta-water quenched {alpha} extruded specimen. It also shows the equation giving the time for the

  7. Simplified method for the determination of strontium-90 in large amounts of bone-ash; Methode simplifiee de dosage du strontium 90 sur des quantites importantes de cendres d'os

    Energy Technology Data Exchange (ETDEWEB)

    Patti, F; Jeanmaire, L [Commissariat a l' Energie Atomique, Fontenay-aux-roses (France). Centre d' Etudes Nucleaires

    1966-06-01

    The principle of the determination is based on a 3-step process: 1) concentrating the strontium by attacking the ash with nitric acid; 2) elimination of residual phosphoric ions by a double precipitation of strontium oxalate; and 3) extraction of yttrium 90, counted in the oxalate form. The advantages of the method: -) using simple techniques it makes it possible to process 50 g of ash; -) the initial concentration of strontium considerably reduces the volume of the solutions as well as the size of precipitates handled. Fuming nitric acid is used in a specially designed burette. (authors) [French] Le principe du dosage repos sur un procede en 3 etapes: 1) Concentration du strontium par une attaque nitrique des cendres; 2) Elimination des ions phosphoriques restants par une double precipitation de l'oxalate de strontium. 3) Extraction de l'yttrium 90, compte sous forme d'oxalate. Interet de la methode: dans des conditions techniques simples, elle permet le traitement de 50 g de cendres d'os; la concentration initiale du strontium reduit notablement le volume des solutions ainsi que l'importance des precipites manipules. L'acide nitrique fumant est utilise par l'intermediaire d'une burette specialement concue a cet effet.

  8. Curiosities of arithmetic gases

    International Nuclear Information System (INIS)

    Bakas, I.; Bowick, M.J.

    1991-01-01

    Statistical mechanical systems with an exponential density of states are considered. The arithmetic analog of parafermions of arbitrary order is constructed and a formula for boson-parafermion equivalence is obtained using properties of the Riemann zeta function. Interactions (nontrivial mixing) among arithmetic gases using the concept of twisted convolutions are also introduced. Examples of exactly solvable models are discussed in detail

  9. Strongly interacting Fermi gases

    Directory of Open Access Journals (Sweden)

    Bakr W.

    2013-08-01

    Full Text Available Strongly interacting gases of ultracold fermions have become an amazingly rich test-bed for many-body theories of fermionic matter. Here we present our recent experiments on these systems. Firstly, we discuss high-precision measurements on the thermodynamics of a strongly interacting Fermi gas across the superfluid transition. The onset of superfluidity is directly observed in the compressibility, the chemical potential, the entropy, and the heat capacity. Our measurements provide benchmarks for current many-body theories on strongly interacting fermions. Secondly, we have studied the evolution of fermion pairing from three to two dimensions in these gases, relating to the physics of layered superconductors. In the presence of p-wave interactions, Fermi gases are predicted to display toplogical superfluidity carrying Majorana edge states. Two possible avenues in this direction are discussed, our creation and direct observation of spin-orbit coupling in Fermi gases and the creation of fermionic molecules of 23Na 40K that will feature strong dipolar interactions in their absolute ground state.

  10. Radiation effects in gases

    International Nuclear Information System (INIS)

    Leonhardt, J.W.

    1985-01-01

    Problems in the studies of radiation effects in gases are discussed. By means of ionization- excitation- and electron-capture yields various applications are characterized: ionization detectors, X-ray detectors, radionuclide battery, and radiation-induced chemical gas-phase reactions. Some new results of basic research in respect to the SO 2 oxidation are discussed. (author)

  11. The greenhouse effect gases

    International Nuclear Information System (INIS)

    2006-06-01

    This road-map proposes by the Group Total aims to inform the public on the greenhouse effect gases. It presents the greenhouses effect as a key component of the climate system, the impacts of the human activity, the foreseeable consequences of global warming, the Kyoto protocol and Total commitment in the domain. (A.L.B.)

  12. Experimental determination of unsteady flow forces on turbine blades by hydraulic analogy; Determination experimentale, par analogie hydraulique, des efforts instationnaires sur les aubages d`une turbine

    Energy Technology Data Exchange (ETDEWEB)

    Verdonk, G. [GEC Alsthom Rateau, 93 - La Courneuve (France); Naudin, M. [Framatome Thermodyn, 71 - Le Creusot (France); Pluviose, M. [CNAM, 75 - Paris (France); Sankale, H. [CETIM, 44 - Nantes (France)

    1998-06-01

    The blades of turbomachinery undergo unsteady flow forces, created principally by the presence of a series of stator or diffuser blades prior to a series of rotor blades. The stage geometry is the main factor which defines the magnitude of these forces. The influence of both geometric and thermodynamic parameters is currently being analysed using a model representing the turbine blades and by applying the hydraulic analogy technique. The study is being conducted at CETIM in Nantes amongst a working group including manufacturers, research organisms, and technical center. Work is in progress and initial results have proved sufficiently encouraging for presentation at the forthcoming Symposium on multidisciplinary turbomachinery issues organised by the Societe Francaise des Mecaniciens. The study should eventually facilitate the optimisation of rotor blade dimensioning for total and partial injection turbine applications and furthermore to reduce the risk of blade failure. Following quantitative study, results obtained for a given geometry of total injection turbine are presented in this paper. (authors) 16 refs.

  13. Optimization of conditions to produce nitrous gases by electrochemical reduction of nitric acid; Optimisation des conditions operatoires de production de vapeurs nitreuses par reduction electrochimique d`acide nitrique

    Energy Technology Data Exchange (ETDEWEB)

    Lemaire, M. [CEA Centre d`Etudes Nucleaires de Saclay, 91 -Gif-sur-Yvette (France)]|[CEA Centre d`Etudes de la Vallee du Rhone, 30 -Marcoule (France). Direction du Cycle du Combustible

    1996-11-22

    Gaseous nitrogen oxides (NO and NO{sub 2}) involved as oxidizing agents in nuclear fuel reprocessing can be an produced by electrochemical reduction of nitric acid. This could be an interesting alternative to the usual process because no wastes are generated. Voltammetric studies on a platinum electrode show that two reduction potential regions are observed in concentrated nitric acid solutions, between 0.05 V{sub S}HE and 0.3 V{sub S}HE and O.5 V{sub S}HE and 1 V{sub S}HE. The highest potential region reduction mechanism was studies by: classical micro-electrolysis methods; macro-electrolysis methods; infra-red spectroscopy couplet to electrochemistry. It was determined that the origin of nitric acid reduction is the electrochemical reduction of nitrous acid in nitric oxide which chemically reduces nitric acid. This reaction produces nitrous acid back which indicate an auto-catalytic behaviour of nitric acid reduction mechanism. Nitrogen dioxide evolution during nitric acid reduction can also be explained by an other chemical reaction. In the potential value of platinum electrode is above 0.8 V{sub S}HE, products of the indirect nitric acid reduction are nitrous acid, nitrogen oxide and nitrogen dioxide. Below this value nitric oxide can be reduced in nitrous oxide. Thus the potential value is the most important parameter for the nitrogen oxides production selectivity. However, owing to the auto-catalytic character of the reduction mechanism, potential value can be controlled during intentiostatic industrial electrolysis. (author). 91 refs.

  14. Process of radioactive waste gases

    International Nuclear Information System (INIS)

    Queiser, H.; Schwarz, H.; Schroter, H.J.

    1975-01-01

    A method is described in which the radiation level of waste gases from nuclear power plants containing both activation and fission gases is controlled at or below limits permitted by applicable standards by passing such gases, prior to release to the atmosphere, through an adsorptive delay path including a body of activated carbon having the relation to the throughput and character of such gases. (U.S.)

  15. Fuel gases in Algeria

    International Nuclear Information System (INIS)

    Arachiche, B.; Elandaloussi, H.

    1996-01-01

    For a country like Algeria, fuel gases represent an important economical challenge. To answer the increasing energy demand in the transportation sector, the use of fuel gases allows to preserve the petroleum reserves and to create specific industrial structures devoted to LPG-f (liquefied petroleum gas-fuel) and NGV (natural gas for vehicles). This paper presents the energy policy of Algeria, its reserves, production, and exportations of hydrocarbons and the internal rational use of energy sources according to its economic and environmental policy and to its internal needs. The energy consumption of Algeria in the transportation sector represents 2/3 of the petroleum products consumed in the internal market and follows a rapid increase necessary to the socio-economic development of the country. The Algerian experience in fuel gases is analysed according to the results of two successive experimentation periods for the development of NGV before and after 1994, and the resulting transportation and distribution network is described. The development of LPG-f has followed also an experimental phase for the preparation of regulation texts and a first statement of the vehicles conversion to LPG-f is drawn with its perspectives of development according to future market and prices evolutions. (J.S.)

  16. Validation of a method to determine methylmercury in fish tissues using gas chromatography; Validacion de un metodo para determinar metilmercurio en tejido de pescado por cromatografia de gases

    Energy Technology Data Exchange (ETDEWEB)

    Vega Bolannos, Luisa O; Arias Verdes, Jose A; Beltran Llerandi, Gilberto; Castro Diaz, Odalys; Moreno Tellez, Olga L [Instituto de Nutricion e Higiene de los Alimentos, La Habana (Cuba)

    2000-07-01

    We validated a method to determine methylmercury in fish tissues using gas chromatography with an electron capture detector as described by the Association of Official Analytical Chemist (AOAC) International. The linear curve range was 0.02 to 1 g/ml and linear correlation coefficient was 0.9979. A 1 mg/kg methylmercury-contaminated fish sample was analyzed 20 times to determine repeatability of the method. The quantification limit was 0.16 mg/kg and detection limit was 0.06 ppm. Fish samples contaminated with 0.2 to 10 mg/kg methylmercury showed recovery indexes from 94.66 to 108.8%.

  17. Fluorine poisoning from waste gases and dust emitted by a superphosphate plant: determination of F content from deposits in plants, drinking water, forage, and bones

    Energy Technology Data Exchange (ETDEWEB)

    Stas, M E

    1941-01-01

    An extensive review is given of the literature on detrimental effects caused by fluorine in plants, animals, and humans, as well as the literature on methods of determining trace amounts of fluorine in water, air, and various other locales. A report is given of an original study of fluorine determination in plants, rainwater, drinking water, plant life consumed by cattle, and the bones of cattle. Results obtained in the immediate vicinity (distances of 100 to 300 m from the fertilizer factory) were compared with control results from other locales. The water, grass, and hay consumed by the cattle contained high amounts of fluorine, and that the bones of cattle that died with the symptoms of fluorine poisoning contained a higher fluorine level than other cattle.

  18. Measuring arrangement for simultaneous and continuous determination of the total and radioactive amounts of reactive matters in flowing inert gases. Pt. 1

    International Nuclear Information System (INIS)

    Figge, K.; Martinen, H.; Schulz, W.

    1976-01-01

    In order to investigate the metabolism behaviour of radiocarbon-labelled substances, a special apparatus has been designed which enables a fully automatic as well as continuous and simultaneous determination of the total and the 14 C-labelled carbon dioxide (CO 2 ) in the respiratory air of small animals. The CO 2 which is exhaled by the experimental animals is absorbed quantitatively in a novel absorber-scintillator cocktail. The quantity of combined total CO 2 is then determined by measuring the specific conductivity whereas the amount of radioactive CO 2 is assessed via scintillation measurement. The measuring accuracy achieved is around 10 N cm 3 or about 5 nCi, whereas the CO 2 recovery is above 98%. In addition to the recording in a linear recorder, the data are transferred to punching tapes and can be evaluated in an EDP unit. (orig.) [de

  19. A new method to measure radon and thoron in flowing gases and its use to determine the thoron- content of atmospheric air

    Energy Technology Data Exchange (ETDEWEB)

    Jacobi, W.

    1963-11-15

    The measurement of Rn (Rn222) and Tn (Rn220) in air is of interest mainly for three purposes: distribution studies of the atmosphere; control of the inhalation hazard of workers in the uranium and thorium mining and milling industry; and, determination of the Ra226 or Th232-body burden. The paper describes methods used for measurement.

  20. Method for monitoring stack gases for uranium activity

    International Nuclear Information System (INIS)

    Beverly, C.R.; Ernstberger, H.G.

    1988-01-01

    A method for sampling stack gases emanating from the purge cascade of a gaseous diffusion cascade system utilized to enrich uranium for determining the presence and extent of uranium in the stack gases in the form of gaseous uranium hexafluoride, is described comprising the steps of removing a side stream of gases from the stack gases, contacting the side stream of the stack gases with a stream of air sufficiently saturated with moisture for reacting with and converting any gaseous uranium hexafluroide contracted thereby in the side stream of stack gases to particulate uranyl fluoride. Thereafter contacting the side stream of stack gases containing the particulate uranyl fluoride with moving filter means for continuously intercepting and conveying the intercepted particulate uranyl fluoride away from the side stream of stack gases, and continually scanning the moving filter means with radiation monitoring means for sensing the presence and extent of particulate uranyl fluoride on the moving filter means which is indicative of the extent of particulate uranyl fluoride in the side stream of stack gases which in turn is indicative of the presence and extent of uranium hexafluoride in the stack gases

  1. A Study of the Diffusion and Precipitation of Rare Gases in Metals; Étude de la diffusion et de la précipitation des gaz rares dans les métaux; ИЗУЧЕНИЕ РАСПРОСТРАНЕНИЯ И ОСАЖДЕНИЯ ИНЕРТНЫХ ГАЗОВ В МЕТАЛЛАХ; Estudio de la difusion y de la precipitacion de los gases nobles en los metales

    Energy Technology Data Exchange (ETDEWEB)

    Brebec, M. Gilbert; Levy, Viviane; Leteurtre, Jean; Adda, Yves [Centre d' Études Nucléaires de Saclay, Gif-sur-Yvette (S. et O.) (France)

    1963-08-15

    In an attempt to explain the mechanism of swelling of irradiated uranium, we studied the behaviour ol various rare gases(helium, argon, krypton, xenon) in several metals (silver, zirconium, uranium). Rare-gas/metal alloys of different concentrations were produced by electric discharge. It was shown that the introduction mechanism is probably based on the penetration of rare gas ions into the metallic lattice combined with redeposition. Using these alloys we studied: (a) Changes in the crystal lattice, including variations in crystal parameter due to introduction of rare gases into the lattice, and formation of defects through bombardment by the rare gas ions. (b) Diffusion of the Xe and Kr fission gases in various metals (silver, uranium). (c) Precipitation of rare gases (helium, argon, xenon, krypton) in the form of bubbles in various metals (silver, uranium, zirconium). These studies were carried out partly by optical microscopy and partly by transmission electron microscopy. (author) [French] En vue d'essayer de préciser les mécanismes du gonflement de l'uranium irradié nous avons étudié le comportement de différents gaz rares (hélium, argon, krypton, xénon) dans différents métaux (argent, zirconium, uranium). Des alliages gaz rare-métal de différentes concentrations ont été réalisés par décharge électrique. On a montré que le mécanisme d'introduction est probablement basé sur une pénétration des ions gaz rare dans le réseau métallique combinée à une redéposition. Sur de tels alliages nous avons étudié: a) Les modifications du réseau cristallin. - Variations de paramètre cristallin dû à l'introduction des gaz rares dans le réseau. - Création de défauts dus au bombardement par les ions gaz rares. b) La diffusion des gaz de fission Xe et Kr dans différents métaux (argent, uranium). c) La précipitation des gaz rares (hélium, argon, xénon, krypton) sous forme de bulles dans différents métaux (argent, uranium, zirconium

  2. Acid dew point measurement in flue gases

    Energy Technology Data Exchange (ETDEWEB)

    Struschka, M.; Baumbach, G.

    1986-06-01

    The operation of modern boiler plants requires the continuous measurement of the acid dew point in flue gases. An existing measuring instrument was modified in such a way that it can determine acid dew points reliably, reproduceably and continuously. The authors present the mechanisms of the dew point formation, the dew point measuring principle, the modification and the operational results.

  3. Measuring Viscosities of Gases at Atmospheric Pressure

    Science.gov (United States)

    Singh, Jag J.; Mall, Gerald H.; Hoshang, Chegini

    1987-01-01

    Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

  4. Determination of the flux per electron-volt at the resonance energy of gold by means op thick gold detectors (1962); Determination des flux par electron-volt a l'energie de resonance de l'or a l'aide de detecteurs d'or epais. (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Brisbois, J; Fogagnolo, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1962-07-01

    We calculated the coefficients which allow determining a neutron flux at 5 eV by means of 2/10 mm thick gold detectors on Geiger-Muller counter assemblies. These coefficients were obtained comparing the thick detectors with the thin ones. (authors) [French] Nous avons calcule les coefficients permettant de determiner le flux de neutrons a 5 eV a partir de comptages de detecteurs d'or de 2/10 mm d'epaisseur sur des groupes a compteur de Geiger-Muller. Ces coefficients ont ete obtenus en comparant les detecteurs epais avec des detecteurs minces. (auteurs)

  5. On Classical Ideal Gases

    Directory of Open Access Journals (Sweden)

    Laurent Chusseau

    2013-02-01

    Full Text Available We show that the thermodynamics of ideal gases may be derived solely from the Democritean concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion, aside from the law of energy conservation. Only a single corpuscle in contact with a heat bath submitted to a z and t-invariant force is considered. Most of the end results are known but the method appears to be novel. The mathematics being elementary, the present paper should facilitate the understanding of the ideal gas law and of classical thermodynamics even though not-usually-taught concepts are being introduced.

  6. Auto-ignition modelling: analysis of the dilution effects by the unburnt gases and of the interactions with turbulence for diesel homogeneous charge compression ignition (HCCI) engines; Modelisation de l'auto-inflammation: analyse des effets de la dilution par les gaz brules et des interactions avec la turbulence dediee aux moteurs Diesel a charge homogene

    Energy Technology Data Exchange (ETDEWEB)

    Subramanian, G.

    2005-09-15

    Homogeneous Charge Compression Ignition (HCCI) is an alternative engine combustion process that offers the potential for substantial reductions in both NO{sub x} and particulate matter still providing high Diesel-like efficiencies. Combustion in HCCI mode takes place essentially by auto-ignition. It is mainly controlled by the chemical kinetics. It is therefore necessary to introduce detailed chemistry effects in combustion CFD codes in order to properly model the HCCI combustion process. The objective of this work is to develop an auto-ignition model including detailed chemical kinetics and its interactions with turbulence. Also, a comprehensive study has been performed to analyze the chemical influence of CO and H{sub 2} residual species on auto-ignition, which can be present in the exhaust gases. A new auto-ignition model, TKI-PDF (Tabulated Kinetics for Ignition - with turbulent mixing interactions through a pdf approach) dedicated to RANS 3D engine combustion CFD calculations is proposed. The TKI-PDF model is formulated in order to accommodate the detailed chemical kinetics of auto-ignition coupled with turbulence/chemistry interactions. The complete model development and its validation against experimental results are presented in two parts. The first part of this work describes the detailed chemistry input to the model. The second part is dedicated to the turbulent mixing description. A method based on a progress variable reaction rate tabulation is used. A look-up table for the progress variable reaction rates has been built through constant volume complex chemistry simulations. Instantaneous local reaction rates inside the CFD computational cell are then calculated by linear interpolation inside the look-up table depending on the local thermodynamic conditions. In order to introduce the turbulent mixing effects on auto-ignition, a presumed pdf approach is used. The model has been validated in different levels. First, the detailed kinetic approach was

  7. Determination of the cross-sections of some nuclear reactions occurring as a result of cosmic radiation (1963); Determination des sections efficaces de quelques reactions nucleaires intervenant dans les effets ou rayonnement cosmique (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Tamers, M A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-06-15

    The high energy reactions studied during this research are reactions liable to occur as a result of cosmic radiation. On the one hand the reaction {sup 16}O(p, 3p){sup 14}C was studied and its cross-section measured between 65 MeV and 2.7 GeV; a value of 2.3 mb {+-} 0.5 was found. These values have mode it possible to forecast measurable quantities of carbon-14 in meteorites and also to measure them. On the other hand the reactions {sup 12}C({sup 16}O...), {sup 12}C({sup 14}N...) and {sup 12}C({sup 12}C...) have been studied and an attempt has been made to explain the mechanism of these reactions. (author) [French] Les reactions a hautes energies qui ont ete etudiees au court de ce travail sont des reactions susceptibles de se produire sous l'effet du rayonnement cosmique. Il s'agit d'une part de la reaction {sup 16}O(p, 3p){sup 14}C dont on a mesure la section efficoce egale a 2,3 mb {+-} 0,5 entre 65 MeV et 2,7 GeV. Ces valeurs ont permis de prevoir des quantites mesurables de carbone 14 dans les meteorites et par suite de les determiner. D'autre part les reaction {sup 12}C({sup 16}O...), {sup 12}C({sup 14}N...) et {sup 12}C({sup 12}C...) ont ete etudiees et on a tente d'expliquer le mecanisme de ces reactions. (auteur)

  8. Vers une meilleure comprehension des savoirs disciplinaires et curriculaires des enseignants ou Ie paradigme retrouve

    Directory of Open Access Journals (Sweden)

    Stephane Martineau

    1999-01-01

    Full Text Available eet article se veut essentieUement un travail de synthese sous la forme d 'une breve revue de litterature au sujet des savoirs disciplinaires et curriculaires en enseignement. Plus specifiquement, il vise a determiner queUes sont les principales conclusions qui se degagent de la lecture des recherches empiriques sur les savoirs disciplinaires et curriculaires des enseignants des ordres d'enseignement primaire et secondaire. Il propose donc une classification des differentes dimensions constitutives du rapport entre les savoirs disciplinaires et curriculaires et la pratique enseignante. Les resultats mis au jour permettent d 'une part, d'identifier les facteurs qui entrainent des differences dans les connaissances disciplinaires et curriculaires des enseignants et d'autre part, de mieux saisir comment ces connaissances de l'enseignant peuvent influencer en retour sa pratique.

  9. Method by chromatography of gases for the determination of made up of alcoholic fermentation in pineapple fruits (Ananas comosus [L.] Merr)

    International Nuclear Information System (INIS)

    Murillo Williams, A.

    2001-01-01

    The pineapple (Ananas comosus) it is used in the entire world for the fresh consumption or for processed products (canned, frozen, dehydrated). it is cultivated in a wide range of countries and in extreme latitudes.The factors of quality include: maturity, stability, size uniformity, absence of microbial deterioration, absence of burns for the sun, absence of blows, damage for insects and breaking, crowns, color, longitude and integrity. The factors that determine the longevity of a product can be physiologic or pathological. The physiologic conditions refer to the processes of degradation of the fabrics after the crop, while the pathological ones involve the attack of mushrooms and bacteria. In the case of the pineapple, a physiologic problem exists, called black heart, internal brewing (IB), brown endogenic stain ( m ancha cafe endogena , MCE) or chilling injury (CI) that can happen in any part of the world where it is cultivated. This problem has associated to the exhibition from the pineapple to low temperatures, so it is a challenge to manage a fruit like the pineapple that it cannot tolerate low temperatures without problems. In studies made about the physiologic changes that happen during the storage in controlled atmospheres in fruits, it has been observed that the ethanol and the acetaldehyde are volatile compounds associated with metabolic post-crop changes and that they have implication in the quality of the product. (author) [es

  10. Removing radioactive noble gases from nuclear process off-gases

    International Nuclear Information System (INIS)

    Lofredo, A.

    1977-01-01

    A system is claimed for separating, concentrating and storing radioactive krypton and xenon in the off-gases from a boiling water reactor, wherein adsorption and cryogenic distillation are both efficiently used for rapid and positive separation and removal of the radioactive noble gases, and for limiting such gases in circulation in the system to low inventory at all times, and wherein the system is self-regulating to eliminate operator options or attention

  11. Liquid scintillators and liquefied rare gases for particle detectors. Background-determination in Double Chooz and scintillation properties of liquid argon

    International Nuclear Information System (INIS)

    Hofmann, Martin Alexander

    2012-01-01

    Evidence for physics beyond the well-established standard model of particle physics is found in the sector of neutrino physics, in particular in neutrino oscillations, and in experimental hints requiring the presence of Dark Matter. Neutrino oscillations demand the neutrinos to be massive and at least four additional parameters, three mixing angles and one phase, are introduced. A non-vanishing value for the third mixing angle, θ 13 , has only recently been found, amongst others by the reactor antineutrino disappearance experiment Double Chooz. This experiment detects anti ν e 's by means of the Inverse Beta Decay (IBD), which has a clear signature that can very effectively be discriminated from most of the background. However, some background still survives the selection cuts applied to the data, partly induced by radioactivity. In order to determine the amount of radioimpurities in the detector, germanium spectroscopy measurements and neutron activation analyses have been carried out for various parts of the Double Chooz far detector. A dedicated Monte-Carlo simulation was performed to obtain the singles event rate induced by the identified radioimpurities in the fiducial volume of Double Chooz. In the present thesis, parts from the outer detector systems, as well as components of the inner detector liquids were measured. In sum, a singles rate of less than 0.35 Hz above the antineutrino detection threshold of 0.7 MeV has been found. This is by far below the design goal of Double Chooz of ∝ 20 Hz. The analysis of bismuth-polonium (BiPo) coincidences in the first Double Chooz data allows to directly determine the number of decays from the U- and the Th-decay chain in the active detector parts. Assuming radioactive equilibrium, concentrations of (1.71±0.08).10 -14 (g)/(g) for uranium and (8.16±0.49).10 -14 (g)/(g) for thorium have been found, which are also well below the design goal of Double Chooz (2.10 -13 (g)/(g)). Both gamma spectroscopy measurements and

  12. Liquid scintillators and liquefied rare gases for particle detectors. Background-determination in Double Chooz and scintillation properties of liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Hofmann, Martin Alexander

    2012-11-27

    Evidence for physics beyond the well-established standard model of particle physics is found in the sector of neutrino physics, in particular in neutrino oscillations, and in experimental hints requiring the presence of Dark Matter. Neutrino oscillations demand the neutrinos to be massive and at least four additional parameters, three mixing angles and one phase, are introduced. A non-vanishing value for the third mixing angle, {theta}{sub 13}, has only recently been found, amongst others by the reactor antineutrino disappearance experiment Double Chooz. This experiment detects anti {nu}{sub e}'s by means of the Inverse Beta Decay (IBD), which has a clear signature that can very effectively be discriminated from most of the background. However, some background still survives the selection cuts applied to the data, partly induced by radioactivity. In order to determine the amount of radioimpurities in the detector, germanium spectroscopy measurements and neutron activation analyses have been carried out for various parts of the Double Chooz far detector. A dedicated Monte-Carlo simulation was performed to obtain the singles event rate induced by the identified radioimpurities in the fiducial volume of Double Chooz. In the present thesis, parts from the outer detector systems, as well as components of the inner detector liquids were measured. In sum, a singles rate of less than 0.35 Hz above the antineutrino detection threshold of 0.7 MeV has been found. This is by far below the design goal of Double Chooz of {proportional_to} 20 Hz. The analysis of bismuth-polonium (BiPo) coincidences in the first Double Chooz data allows to directly determine the number of decays from the U- and the Th-decay chain in the active detector parts. Assuming radioactive equilibrium, concentrations of (1.71{+-}0.08).10{sup -14}(g)/(g) for uranium and (8.16{+-}0.49).10{sup -14}(g)/(g) for thorium have been found, which are also well below the design goal of Double Chooz (2.10{sup -13

  13. An introduction to the Boltzmann equation and transport processes in gases

    CERN Document Server

    Kremer, Gilberto M; Colton, David

    2010-01-01

    This book covers classical kinetic theory of gases, presenting basic principles in a self-contained framework and from a more rigorous approach based on the Boltzmann equation. Uses methods in kinetic theory for determining the transport coefficients of gases.

  14. Experimental determination and evaluation of the friction behavior of geosynthetics; Experimentelle Ermittlung und Bewertung des Reibungsverhaltens von Geokunststoffen

    Energy Technology Data Exchange (ETDEWEB)

    Heinemann, Maik

    2016-08-17

    In many fields of geotechnical engineering geosynthetics have established itself as an alternative to common used earth materials. Particularly in landfill sealing systems many different types of geosynthetics are used together. In embankments geosynthetics form inclined planes. The safety against sliding must be proved for all contact surfaces. For this purpose, the knowledge of the friction behavior of the geosynthetics is required. Normally, the friction behavior is modeled analytically with the Coulomb failure criterion. The Coulomb friction parameters usually must be determined experimentally. In spite of the good state of the art and numerous studies into geosynthetics, in detail, there are still issues relating to the determination of friction behavior of geosynthetics, to the application of the Coulomb failure criterion and to the assessment of the friction parameters with a view to the time- and temperature-dependent behavior of synthetics. The main objective of this work is to contribute to a reliable determination of the friction behavior and to a correct assessment of the evaluated test results as the basis for a reliable and economical dimensioning of structures with geosynthetics. For this, the measurement technique of a standard large direct shear box was upgraded by the author, so that the effective normal stress can be measured below the test surface. Also tests with very small normal stresses can be carried out with this modification. Furthermore, a force-controlled test device was designed for studies of the influences arising from long-term combined compressive and shear loads and temperature. Based on experimental investigations inadequacies in the current experimental procedure are identified. In addition, the impact of factors are quantified, which are often ignored or considered to be marginal in practice. With further experimental investigations it is demonstrated that the linear Coulomb failure criterion is valid for limited normal stress

  15. ANALYSE DES PERCEPTIONS LOCALES ET DES FACTEURS ...

    African Journals Online (AJOL)

    AISA

    1Faculté des Sciences Agronomiques (FSA), Université d'Abomey-Calavi (UAC), 01 BP 526 Cotonou Bénin. Email : cgbemavo@yahoo.fr. 2Institut National des Recherches Agricoles du Bénin, Centre de Recherches Agricoles d'Agonkanmey (CRA-A),. Laboratoire des Sciences du Sol, Eau et Environnement (LSSEE).

  16. Solubility of gases in water at high temperature

    International Nuclear Information System (INIS)

    Crovetto, Rosa; Fernandez Prini, R.J.; Japas, M.L.

    1981-01-01

    In the primary circuits of the PWR, it is usual to find apolar gases such as the noble gases like, nitrogen, hydrogen (deuterium) and oxygen. These gases enter into the circuit partly due to failures in the fuel elements, accidental entries of air into the system and corrosion processes and radiolisis in the coolant media. For the operation of several auxiliary systems in the primary circuit, it is important to know the solubility of these gases in the flux of the circuit and the evaluation of physicochemical processes that take place. A cell has been built that allows to carry out determinations of solubility in the range of 350 deg C and 100 Mega Pascal. Three alternative experimental techniques have been developed to determine the solubility of the gases which are compared to each other. Measures of solubility of argon in H2O and D2O have been made in a wide range of temperatures. (V.B.) [es

  17. Selective noble gases monitoring

    International Nuclear Information System (INIS)

    Janecka, S.; Jancik, O.; Kapisovsky, V.; Kubik, I.; Sevecka, S.

    1995-01-01

    The monitoring of leak releases from ventilation stack of NPP requires a system by several orders more sensitive then currently used radiometer Kalina, designed to cover the range up to a design-based accident. To reach this goal a noble gases monitor with a germanium detector (MPVG) has been developed. It enables nuclide selective monitoring of current value of volume activity of particular nuclides in ventilation stack and daily releases of noble gases (balancing). MPVG can be viewed as a system build of three levels of subsystem: measuring level; control level; presentation level. Measuring level consists of gamma-spectroscopy system and operational parameters monitoring unit (flow rate, temperature, humidity). Control level provides communication between presentation and measuring level, acquisition of operational parameters and power supply. The presentation level of MPVG enables: 1) the measured data storage in predetermined time intervals; 2) the presentation of measured and evaluated values of radiation characteristics. The monitored radionuclides - default set: argon-41, krypton-85m, krypton-87, krypton-88, krypton-89, xenon-131m, xenon-133, xenon-133m, xenon-135, xenon-135m, xenon-137 and xenon-138. The values of volume activities observed at maximum releases have been approximately ten times higher. In that case in balancing some other nuclides exceed corresponding detection limits: 88 Kr(67; 22) Bq/m 3 ; 85m Kr(17; 7) Bq/m 3 ; 135m Xe(7.1; 0.5) Bq/m 3 ; 138 Xe(5.9; 0.9) Bq/m 3 . (J.K.)

  18. Selective noble gases monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Janecka, S; Jancik, O; Kapisovsky, V; Kubik, I; Sevecka, S [Nuclear Power Plants Research Institute, a.s., Trnava (Slovakia)

    1996-12-31

    The monitoring of leak releases from ventilation stack of NPP requires a system by several orders more sensitive then currently used radiometer Kalina, designed to cover the range up to a design-based accident. To reach this goal a noble gases monitor with a germanium detector (MPVG) has been developed. It enables nuclide selective monitoring of current value of volume activity of particular nuclides in ventilation stack and daily releases of noble gases (balancing). MPVG can be viewed as a system build of three levels of subsystem: measuring level; control level; presentation level. Measuring level consists of gamma-spectroscopy system and operational parameters monitoring unit (flow rate, temperature, humidity). Control level provides communication between presentation and measuring level, acquisition of operational parameters and power supply. The presentation level of MPVG enables: 1) the measured data storage in predetermined time intervals; 2) the presentation of measured and evaluated values of radiation characteristics. The monitored radionuclides - default set: argon-41, krypton-85m, krypton-87, krypton-88, krypton-89, xenon-131m, xenon-133, xenon-133m, xenon-135, xenon-135m, xenon-137 and xenon-138. The values of volume activities observed at maximum releases have been approximately ten times higher. In that case in balancing some other nuclides exceed corresponding detection limits: {sup 88}Kr(67; 22) Bq/m{sup 3}; {sup 85m}Kr(17; 7) Bq/m{sup 3}; {sup 135m}Xe(7.1; 0.5) Bq/m{sup 3}; {sup 138}Xe(5.9; 0.9) Bq/m{sup 3}. (J.K.).

  19. Researches on the adaptation of green frogs to environment with various salinity level, and its endocrine determinism; Recherches sur l'adaptation de grenouilles vertes a des milieux de salinite diverse et, sur son determinisme endocrinien

    Energy Technology Data Exchange (ETDEWEB)

    Jard, Serge

    1958-06-09

    This research thesis reports a study in which the author examined whether modifications of sodium flows noticed during the adaptation to environments displaying a different salinity would result from a hormonal determinism. The author first reports in vitro studies which aimed at determining whether the neuro-hypophysis hormone was itself able to explain noticed observations. Knowing that for mammals, a sodium-rich regime results in a resting mineralotropic function of the adrenal cortex, the author studied, by in vivo administering of aldosterone, whether the sodium flow variations through the animal skin due to a prolonged stay in a high salinity bath would result from a similar mechanism. [French] Chez Rana esculenta, la conservation prolongee dans une solution de NaCl isotonique au plasma d'une part, dans de l'eau desionisee d'autre part modifie les flux de sodium a travers la peau mesures dans une solution diluee de NaCl (25 μg Na/ml). La conservation dans une solution de NaCl 7 0/00 entraine: une diminution du transport actif de sodium a travers la peau, in vivo et in vitro et d'autre part une augmentation de la diffusion passive de cet ion a travers la peau (flux de sortie augmente). La conservation dans un milieu appauvri en Na entraine les modifications inverses (augmentation du flux d'entree de sodium a travers la peau, flux net nul). Par ailleurs une forte salinite du milieu exterieur entraine une surcharge sodique plasmatique et tissulaire, la conservation dans un milieu pauvre en sodium une depletion sodique plasmatique et tissulaire. In vitro, l'ocytocine ne peut pas, a elle seule, rendre compte des modifications du transport actif de sodium a travers la peau des animaux conserves au prealable dans des milieux de salinite differente. Par contre, in vivo, des injections repetees d'aldosterone provoquent une augmentation du flux d'entree de sodium a travers la peau des animaux conserves dans la solution de NaCl a 7 0/00 comparable a celle observee chez

  20. New experimental determination of the neutron resonance parameters of {sup 99}Tc; Nouvelle determination experimentale des parametres de resonances neutroniques de {sup 99}Tc

    Energy Technology Data Exchange (ETDEWEB)

    Brienne-Raepsaet, C. [CEA Bruyeres-le-Chatel, 91 (France). Dept. de Physique Theorique et Appliquee]|[Aix-Marseille-1 Univ., 13 - Marseille (France)

    1999-04-01

    In order to improve nuclear data for nuclear waste transmutation cross-sections of Tc{sup 99} in the resonance energy region have been performed using the time-of-flight method at the pulsed white neutron source GELINA of the Institute for Reference Materials and Measurements, Geel, Belgium. The energy range studied spreads from 3 eV to 100 KeV. 2 kinds of measurements have been performed: capture and transmission measurements. In the energy range between 0 and 2 KeV, more than 220 resonances have been analyzed. About 130 resonances which had stayed previously undiscovered, have been detected and analyzed. Because of instability problems concerning the process of measuring itself, the systematic error is not yet determined. The accuracy which takes into account statistical and systematic errors is expected to be between 4 and 5%.

  1. Determination of detection limits for a VPD ICPMS method of analysis; Determination des limites de detection d'une methode d'analyse VPD ICPMS

    Energy Technology Data Exchange (ETDEWEB)

    Badard, M.; Veillerot, M

    2007-07-01

    This training course report presents the different methods of detection and quantifying of metallic impurities in semiconductors. One of the most precise technique is the collection of metal impurities by vapor phase decomposition (VPD) followed by their analysis by ICPMS (inductively coupled plasma mass spectrometry). The study shows the importance of detection limits in the domain of chemical analysis and the way to determine them for the ICPMS analysis. The results found on detection limits are excellent. Even if the detection limits reached with ICPMS performed after manual or automatic VPD are much higher than detection limits of ICPMS alone, this method remains one of the most sensible for ultra-traces analysis. (J.S.)

  2. Photoacoustic absorption spectra of atmospheric gases near 7603 cm-1

    International Nuclear Information System (INIS)

    Lawton, S.A.; Bragg, S.L.

    1984-01-01

    Absorption spectra of carbon monoxide, water vapor, memane, and ammonia are presented as part of an effort to determine absolute absorption cross sections for some atmospheric gases at the iodine laser wavelength

  3. Modelisation des effets physico-techniques pour la conception des ...

    African Journals Online (AJOL)

    automatisation dans les installations industrielles a besoin d'une régulation automatique des commandes des processus technologiques pour lesquelles certaines contraintes sont à relever compte tenu des exigences des innovations scientifiques de ...

  4. Safety characteristics. Vol. 1. Combustible liquids and gases; Sicherheitstechnische Kenngroessen. Bd. 1. Brennbare Fluessigkeiten und Gase

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, E.; Moeller, W. [Laboratorium ' Sicherheitstechnische Kenngroessen' , Braunschweig (Germany)

    2003-07-01

    This reference manual is based on the 2002 version of the CHEMSAFE database, which is produced since 1989 by the PTB (Physikalisch-Technische Bundesanstalt), the BAM (Bundesanstalt fuer Materialforschung und -pruefung) and the DECHEMA (Gesellschaft fuer Chemische Technik und Biotechnologie e.V.). About 1,900 combustible gases and vapours are listed, along with explosion protection characteristics like flame point, ignition temperature, explosion limits, minimum ignition energy, normal gap width, maximum explosion pressure, and maximum pressure increase over time. Important thermophysical data are presented as well, e.g. boiling temperature, vapour pressure as a function of temperature, melting temperature, and density. Definitions of the characteristics are presented. There are several indexis to facilitate acces (CAS number, sum formula, synonyms). [German] Anwender in Industrie, Handel, Handwerk und Behoerden benoetigen verlaessliche Daten, von Fachleuten bewertete Kenngroessen des Brand- und Explosionsschutzes, um Brand- und Explosionsgefahren beim Verarbeiten, Abfuellen, Lagern, Befoerdern und Entsorgen brennbarer Stoffe beurteilen und angemessene Schutzmassnahmen ergreifen zu koennen. Die 1989 gemeinsam mit der Bundesanstalt fuer Materialfoschung und -pruefung (BAM) und der Gesellschaft fuer Chemische Technik und Biotechnologie e.v (DECHEMA) erstellte Datenbank CHEMSAFE diente als Grundlage dieses Nachschlagewerkes. Die hier bei Drucklegung wiedergegebenen Kenngroessen entsprechen dem Update 2002 der Datenbank CHEMSAFE. Etwa 1.900 brennbare Gase und Daempfe, Kenngroessen des Explosionsschutzes wie Flammpunkt, Zuendtemperatur, Explosionsgrenzen, Mindestzuendenergie, Normspaltweite, maximaler Explosionsdruck und maximaler zeitlicher Druckanstieg sind ebenso aufgelistet wie auch einige wichtige thermophysikalische Groessen wie Siedetemperatur, Dampfdruck als Funktion der Temperatur, Schmelztemperatur und Dichte. Die Angaben werden eingeleitet durch Definitionen

  5. Determination of the physical values of a plasma puff by analysis of the diamagnetic signals. 1. part: expansion model for the puff. 2. part: comparison of experimental results with the expansion model for the plasma puff; Determination des grandeurs physiques d'une bouffee de plasma par l'analyse de signaux diamagnetiques. 1. partie: modele d'expansion de bouffee. 2. partie: confrontation des resultats experimentaux et du modele d'expansion de la bouffee de plasma

    Energy Technology Data Exchange (ETDEWEB)

    Jacquinot, J; Leloup, Ch; Waelbroeck, F; Poffe, J P [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    The flow of a dense plasma puff, along the axis of a uniform magnetic field is examined, assuming the following hypotheses: the axial distribution of the line density can be described at any time by a gaussian function whose characteristic parameter is independent of the distance from the axis of the system; the {beta} ratio is less than 0,6. An approximate solution of the magnetohydrodynamics equations is obtained. The evolution of the characteristic properties of the plasma (local velocity, temperature and density) can be calculated from a set of equations involving 5 plasma parameters. A method leading to the determination of these parameters is described. It uses 5 informations picked up from the diamagnetic signals induced by the plasma into a set of 4 compensated magnetic loops. (authors) [French] L'ecoulement d'une bouffee dense de plasma le long des lignes de force d'un champ magnetique uniforme est etudie en faisant les hypotheses suivantes : la distribution axiale de la densite lineique est, a chaque instant, une gaussienne dont le parametre caracteristique ne depend pas de la distance a l'axe de revolution du systeme; {beta}(2 {mu}{sub 0} p/B{sup 2}{sub e}) est inferieur a 0,6. Dans ces conditions, une solution approchee des equations magneto-hydrodynamiques a pu etre trouvee. L'evolution des quantites physiques du plasma (vitesse, temperature, densite locale) est alors explicitement donnee par des equations dependant de 5 parametres. On decrit une methode permettant la determination de ces parametres. Elle necessite 5 informations prises sur les signaux diamagnetiques induits par le plasma dans un jeu de quatre boucles magnetiques compensees. (auteurs)

  6. On the determination of the heat of fusion of one of the constituents of a binary mixture from the heat of fusion of the other, by measurement of the slopes of two liquidus curves at the eutectic point; Sur la determination de la chaleur de fusion d'un des constituants d'un melange binaire a partir de la chaleur de fusion de l'autre, par mesure des pentes des deux liquidus au point d'eutexie

    Energy Technology Data Exchange (ETDEWEB)

    Dode, Maurice; Hagege, Raoul [Commissariat a l' energie atomique et aux energies alternatives - CEA (France)

    1959-07-01

    A method for calculating latent heats of fusion from binary diagrams of liquid-solid equilibrium was proposed several years ago by J. Bousquet and one of us. The method is base on the hypothesis of the regularity of the solution in a small region around the eutectic and involves an integration along the liquidus curves slightly extrapolated below the eutectic point. Reprint of a paper published in Comptes rendus des seances de l'Academie des Sciences, t. 248, p. 2339-2341, sitting of April 20, 1959 [French] Une methode de calcul des chaleurs latentes de fusion a partir des diagrammes binaires d'equilibre liquide-solide a ete proposee il y a quelques annees par J. Bousquet et l'un de nous. La methode repose sur l'hypothese de la regularite de la solution dans un petit domaine autour de l'eutectique et comporte une integration le long des liquidus, legerement extrapoles en dessous de l'eutectique. Reproduction d'un article publie dans les Comptes rendus des seances de l'Academie des Sciences, t. 248, p. 2339-2341, seance du 20 avril 1959.

  7. Evaluation of the greenhouse effect gases (CO{sub 2}, CH{sub 4}, N{sub 2}O) in grass land and in the grass breeding. Greenhouse effect gases prairies. report of the first part of the project December 2002; Bilan des emissions de gaz a effet de serre (CO{sub 2}, CH{sub 4}, N{sub 2}O) en prairie paturee et dans des exploitations d'elevage herbager. GES-Prairies. Rapport de la premiere tranche du projet Decembre 2002

    Energy Technology Data Exchange (ETDEWEB)

    Soussana, J.F

    2002-12-15

    In the framework of the Kyoto protocol on the greenhouse effect gases reduction, many ecosystems as the prairies can play a main role for the carbon sequestration in soils. The conservation of french prairies and their management adaptation could allow the possibility of carbon sequestration in the soils but also could generate emissions of CO{sub 2} and CH{sub 4} (by the breeding animals on grass) and N{sub 2}O (by the soils). This project aims to establish a detailed evaluation of the contribution of the french prairies to the the greenhouse effect gases flux and evaluate the possibilities of reduction of the emissions by adaptation of breeding systems. (A.L.B.)

  8. Analytical methods for toxic gases from thermal degradation of polymers

    Science.gov (United States)

    Hsu, M.-T. S.

    1977-01-01

    Toxic gases evolved from the thermal oxidative degradation of synthetic or natural polymers in small laboratory chambers or in large scale fire tests are measured by several different analytical methods. Gas detector tubes are used for fast on-site detection of suspect toxic gases. The infrared spectroscopic method is an excellent qualitative and quantitative analysis for some toxic gases. Permanent gases such as carbon monoxide, carbon dioxide, methane and ethylene, can be quantitatively determined by gas chromatography. Highly toxic and corrosive gases such as nitrogen oxides, hydrogen cyanide, hydrogen fluoride, hydrogen chloride and sulfur dioxide should be passed into a scrubbing solution for subsequent analysis by either specific ion electrodes or spectrophotometric methods. Low-concentration toxic organic vapors can be concentrated in a cold trap and then analyzed by gas chromatography and mass spectrometry. The limitations of different methods are discussed.

  9. Statutes of limitations: the special problem of DES suits

    International Nuclear Information System (INIS)

    Feigin, C.A.

    1981-01-01

    In 1971, medical studies determined that DES causes a rare type of vaginal cancer in a small number of daughters of mothers who took DES during pregnancy. Subsequently, medical studies determined that exposure to DES can cause other vaginal abnormalities in the daughters, some of which may be precancerous. As a result of these discoveries, many lawsuits have been filed by these daughters against DES manufacturers. Many DES suits may be barred by statutes of limitations, both because the number of years between the daughters' exposure to DES in utero and the discovery that DES can cause injuries exceeds the statutory period, and because the cancer or other injuries caused by DES may not develop for many additional years. This Note discusses two methods that DES plaintiffs may be able to use to overcome the potential statutes of limitations bar: the discovery rule, and state provisions which toll the statute of limitations for minors. The Note contends that courts should apply an expanded discovery rule to DES suits to avoid the unfair result of barring a claim before the plaintiff could have known that she had a cause of action. In addition, the Note argues that the injury which causes the statute of limitations to begin to run in DES suits should not be rigidly defined. Finally, the Note urges that courts allow eligible DES plaintiffs to take advantage of applicable state provisions that toll the statute of limitations for minors

  10. Canonical partition functions: ideal quantum gases, interacting classical gases, and interacting quantum gases

    Science.gov (United States)

    Zhou, Chi-Chun; Dai, Wu-Sheng

    2018-02-01

    In statistical mechanics, for a system with a fixed number of particles, e.g. a finite-size system, strictly speaking, the thermodynamic quantity needs to be calculated in the canonical ensemble. Nevertheless, the calculation of the canonical partition function is difficult. In this paper, based on the mathematical theory of the symmetric function, we suggest a method for the calculation of the canonical partition function of ideal quantum gases, including ideal Bose, Fermi, and Gentile gases. Moreover, we express the canonical partition functions of interacting classical and quantum gases given by the classical and quantum cluster expansion methods in terms of the Bell polynomial in mathematics. The virial coefficients of ideal Bose, Fermi, and Gentile gases are calculated from the exact canonical partition function. The virial coefficients of interacting classical and quantum gases are calculated from the canonical partition function by using the expansion of the Bell polynomial, rather than calculated from the grand canonical potential.

  11. Impact de la preparation des anodes crues et des conditions de cuisson sur la fissuration dans des anodes denses

    Science.gov (United States)

    Amrani, Salah

    La fabrication de l'aluminium est realisee dans une cellule d'electrolyse, et cette operation utilise des anodes en carbone. L'evaluation de la qualite de ces anodes reste indispensable avant leur utilisation. La presence des fissures dans les anodes provoque une perturbation du procede l'electrolyse et une diminution de sa performance. Ce projet a ete entrepris pour determiner l'impact des differents parametres de procedes de fabrication des anodes sur la fissuration des anodes denses. Ces parametres incluent ceux de la fabrication des anodes crues, des proprietes des matieres premieres et de la cuisson. Une recherche bibliographique a ete effectuee sur tous les aspects de la fissuration des anodes en carbone pour compiler les travaux anterieurs. Une methodologie detaillee a ete mise au point pour faciliter le deroulement des travaux et atteindre les objectifs vises. La majorite de ce document est reservee pour la discussion des resultats obtenus au laboratoire de l'UQAC et au niveau industriel. Concernant les etudes realisees a l'UQAC, une partie des travaux experimentaux est reservee a la recherche des differents mecanismes de fissuration dans les anodes denses utilisees dans l'industrie d'aluminium. L'approche etait d'abord basee sur la caracterisation qualitative du mecanisme de la fissuration en surface et en profondeur. Puis, une caracterisation quantitative a ete realisee pour la determination de la distribution de la largeur de la fissure sur toute sa longueur, ainsi que le pourcentage de sa surface par rapport a la surface totale de l'echantillon. Cette etude a ete realisee par le biais de la technique d'analyse d'image utilisee pour caracteriser la fissuration d'un echantillon d'anode cuite. L'analyse surfacique et en profondeur de cet echantillon a permis de voir clairement la formation des fissures sur une grande partie de la surface analysee. L'autre partie des travaux est basee sur la caracterisation des defauts dans des echantillons d'anodes crues

  12. Development of a test system for the determination of biodegradability in surface waters; Entwicklung eines Testsystems fuer die Pruefung des biologischen Abbaus in Oberflaechengewaessern

    Energy Technology Data Exchange (ETDEWEB)

    Kalsch, W; Knacker, T; Robertz, M; Schallnass, H J

    1997-04-01

    The study presented here describes the development of a laboratory test system for the determination of aerobic biodegradability of substances at low concentrations in surface water. It was aimed to prepare a draft guideline for a biodegradation simulation test according to OECD format. The experimental approach was based on a literature study conducted within the frame of this project. Further useful information on the possible test design was derived from the German BBA guideline 5-1. Natural water and sediments were collected. Radiolabelled Lindane or 4-Nitrophenol was added. The test vessels (reactors) were aerated and incubated under controlled conditions for up to 92 days. The results showed biological stability of the sediment/water systems even without addition of nutrients and adherence to non-reducing conditions. Mineralisation of 4-Nitrophenol was influenced by the sediment type, the method of aeration and temperature. Factors affecting the mineralisation of Lindane were the method of application and again, the sediment type and temperature. Considerable amounts of the radioactivity were bound to the sediment and were to a large extent unextractable. The potential of a reactor to mineralise a test substance could not be correlated with the biological parameters measured. (orig.) [Deutsch] Die vorliegende Studie beschreibt die Entwicklung eines Labortestverfahrens zur Pruefung des aeroben Abbaus niedrig konzentrierter Stoffe in Oberflaechengewaessern. Dabei war es ein Ziel, das Verfahren so weit abzusichern, dass ein Entwurf fuer eine Pruefrichtlinie als Simulationstest im Format der OECD-Richtlinien abgefasst werden konnte. Grundlage fuer die Konzeption war eine zuvoerderst durchgefuehrte Literaturstudie. Hinweise auf ein moegliches Testdesign ergaben sich auch aus der BBA-Richtlinie 5-1. Wasser und Sediment wurden der Natur entnommen und nach Zugabe der radioaktiven Pruefsubstanz Lindan oder 4-Nitrophenol in einem beluefteten Gefaess unter

  13. variabilite des productions et des revenus des exploitations

    African Journals Online (AJOL)

    3Centre de coopération internationale en recherche agronomique pour le développement (CIRAD), UMR Innovation,. Montpellier, France. Doubangolo COULIBALY, Email kone_b@yahoo.fr. RESUME. La durabilité des systèmes de production à base de coton dans un contexte de variabilité des prix aux producteurs et de ...

  14. Economic Hazardous Gases Management for SOX Removal from Flue Gases

    International Nuclear Information System (INIS)

    Isaack, S.L.; Mohi, M.A.; Mohamed, S.T.

    1995-01-01

    Hazardous gases emerging from industries accumulate as pollutants in air and falls as acid rains resulting also in water and soil pollution. To minimize environmental pollution, the present process is suggested in order to desulfurize flue gases resulting from burning fuel oil in a 100/MWh steam power plant. The process makes use of the cheap Ca C O 3 powder as the alkaline material to sequistre the sulphur oxide gases. The resulting sulphur compounds, namely calcium sulphate and gypsum have a great market demand as reducing and sulphiting agents in paper industry and as an important building material. About 44000 ton of gypsum could be produced yearly when treating flue gases resulting from a 100 MWh unit burning fuel oil. Feasibility study shows that a great return on investment could be achieved when applying the process. 1 fig

  15. Noble gases solubility in water

    International Nuclear Information System (INIS)

    Crovetto, Rosa; Fernandez Prini, Roberto.

    1980-07-01

    The available experimental data of solubility of noble gases in water for temperatures smaller than 330 0 C have been critically surveyed. Due to the unique structure of the solvent, the solubility of noble gases in water decreases with temperature passing through a temperature of minimum solubility which is different for each gas, and then increases at higher temperatures. As aresult of the analysis of the experimental data and of the features of the solute-solvent interaction, a generalized equation is proposed which enables thecalculation of Henry's coefficient at different temperatures for all noble gases. (author) [es

  16. Quotation systems for greenhouse gases

    International Nuclear Information System (INIS)

    Trong, Maj Dang

    2000-01-01

    The article surveys recommendations from a Norwegian committee for implementing at a national level, the Kyoto protocol aims for reducing the total emissions of greenhouse gases from the industrial countries through quotation systems

  17. Cryogenic method for measuring nuclides and fission gases

    Science.gov (United States)

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  18. Greenhouse gases and global warming

    International Nuclear Information System (INIS)

    1995-01-01

    From previous articles we have learned about the complexities of our environment, its atmosphere and its climate system. we have also learned that climate change and, therefore global warm and cool periods are naturally occurring phenomena. Moreover, all scientific evidence suggests that global warming, are likely to occur again naturally in the future. However, we have not yet considered the role of the rates of climate change in affecting the biosphere. It appears that how quickly the climate changes may be more important than the change itself. In light of this concern, let us now consider the possibility that, is due to human activity. We may over the next century experience global warming at rates and magnitudes unparalleled in recent geologic history. The following questions are answered; What can we learn from past climates? What do we know about global climates over the past 100 years? What causes temperature change? What are the greenhouse gases? How much have concentration of greenhouse gases increased in recent years? Why are increases in concentrations of greenhouse of concern? What is the e nhanced greenhouse effect ? How can human activity impact the global climate? What are some reasons for increased concentrations of greenhouse gases? What are fossil fuel and how do they transform into greenhouse gases? Who are the biggest emitters of greenhouse gases? Why are canada per capita emissions of greenhouse gases relatively high? (Author)

  19. Application of new fast-electronic techniques to the determination of the exact moment of particle detection; Application des techniques nouvelles de l'electronique rapide a la determination de l'instant precis de detection d'une particule

    Energy Technology Data Exchange (ETDEWEB)

    Hesse, M [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1965-06-01

    Fluctuations in the time response of photomultipliers employed in scintillation counting are studied and experimentally checked. Statistical measurements of the output pulses show that the relative variance of the time fluctuations is minimum for the portion located around the bending point of the leading edge. A shaping circuit using this property is described. Experimental results are given, showing an improvement of the resolving time. (author) [French] Les fluctuations de la reponse temporelle des photomultiplicateurs, utilises dans les detecteurs a scintillations, sont etudiees et mesurees experimentalement. L'etude statistique des signaux de sortie montre que les fluctuations en temps presentent une variance relative minimale pour la region situee autour du point d'inflexion du front de montee. Un circuit de mise en forme utilisant cette propriete est decrit. Des resultats experimentaux sont donnes; ils montrent une amelioration sensible du pouvoir de resolution. (auteur)

  20. Civili, langue des Baloango

    DEFF Research Database (Denmark)

    Mavoungou, Paul Achille; Ndinga-Koumba-Binza, Hugues Steve

    , Congo, Angola, etc.) issus de la décolonisation. Il présente de façon succincte quelques phénomènes historiques, phonologiques, morphosyntaxiques, homonymiques et analogiques de la langue. Des faits sémantiques des emprunts linguistiques y sont également décrits dans le cadre des changements...

  1. Des racines et des ailes

    Directory of Open Access Journals (Sweden)

    Stéphanie Vincent-Geslin

    2012-05-01

    Full Text Available Les mobilités pendulaires semblent être en augmentation en Europe depuis une dizaine d’années. Cette croissance du temps passé à se déplacer amène à remettre en question la conjecture de Zahavi et apparaît relativement inexplicable en regard du paradigme classique de l’acteur rationnel traditionnellement utilisé dans le champ des transports. Si, dans la littérature, les temps de déplacements sont principalement expliqués par le contexte résidentiel, la forme urbaine et le travail, ce cadre explicatif ne dit rien des processus de décision eux-mêmes qui amènent aux pendularités intensives.À partir d’une enquête qualitative menée auprès de pendulaires français, suisses et belges, cette contribution propose d’analyser les arbitrages et les éléments déterminants des processus de la grande pendularité. Les mobilités quotidiennes pendulaires apparaissent comme le résultat de compromis entre activité professionnelle, attachement résidentiel et choix de vie et prennent ainsi la forme de stratégies de conciliation entre vie privée et vie professionnelle. Ces mobilités spatiales permettent alors paradoxalement la préservation des ancrages résidentiels, sociaux et familiaux.Roots and wings. Long-distance commuting patterns, or how to conciliate professional and personal lifeLong-distance commuting patterns appear to be increasing in Europe over the last ten years. These raising mobility patterns lead to reappraise the Zahavi conjecture and appear largely inexplicable by the classical rational actor paradigm traditionally used in transportation research. In literature, commuting is mainly explained by residential contexts, urban forms and job. Nevertheless this theoretical frame says little about the decision-making processes themselves. Based on a qualitative survey conducted in three European countries - France, Belgium and Switzerland – among a population of high commuters, this paper proposes an analysis of

  2. Working group results on the division by four of the greenhouse gases emissions in France, at 2050, called factor four; Les travaux du groupe de travail sur la division par quatre des emissions de gaz a effet de serre de la France, a l'horizon 2050, dit facteur 4

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This working group aims to evaluate and propose different ways to divide by four the greenhouse gases emissions at 2050 in France. This objective was decided by the Government and fixed in the Climate Plan and in the Program law of 13 July 2005. In this framework, this meeting presents studies of the working group, concerning the following topics: buildings and greenhouse gases, a scenario for the UE25 realized by Greenpeace, the agriculture and the forests facing the climate, the biomass the nature the agriculture and the silviculture facing the climate. (A.L.B.)

  3. Control panel for radiation around reactors (1963); Tableaux de controle des radiations aupres des piles (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Candes, P; Barthoux, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    This report outlines the general philosophy of radiation control in French reactors and their annexes. The supervision is carried out continuously from a central control panel on which appear all the measurements made and the alarm signals. The equipment is described; one item makes it possible to measure simultaneously the radioactive dusts and gases. The specifications of the alarm system, which is considered to be the most important are given. Finally a new measuring technique is proposed which makes it possible to reduce considerably the cost of radiation control while at the same time providing the results in a form in which they can be easily treated, in particular in the case of the calculation of total doses. (authors) [French] Ce rapport definit la philosophie generale du controle des radiations dans les piles francaises et dans leurs annexes. La surveillance se fait d'une maniere continue a partir d'un tableau de controle centralise ou sont reportees toutes les mesures et les signalisations d'alarme. On decrit les appareils utilises, dont un permet la mesure simultanee des poussieres et gaz radioactifs, et on definit les specifications de la fonction alarme qui est consideree comme la plus importante. Enfin on propose une nouvelle technique de mesure qui permettrait de reduire considerablement le cout du controle des radiations tout en fournissant des resultats plus facilement exploitables, en particulier pour le calcul des doses integrees. (auteurs)

  4. Radioactive gases monitor system: tritium, radon, noble gases

    International Nuclear Information System (INIS)

    Egey, J.Z.; Matatagui, E.

    2015-01-01

    A system for monitoring the radioactive gases tritium, radon and noble gases is described. We present the description of the sensor and the associated electronics that have been developed to monitor the presence of radioactive gases in air or other gaseous effluents. The system has a high sensitivity and a wide range of operation. The sensor is an ionization chamber, featuring the internal circulation of the gas to monitor and the associated electronics has a resolution better than 10 E-15A (fA). It allows the detection of the individual pulses that are produced during the alpha decay of radon and its daughter elements. The measurement system is made up of a commercial data acquisition system connected to a computer. The acquired data is presented on a graphical display and it is stored for later processing and analysis. We have a system that is of simple construction and versatile. Here we present the experimental results. (authors) [es

  5. Determination of the mean free path of the thermal neutrons transport by the measure of a complex diffusion length; Determination du libre parcours moyen de transport des neutrons thermiques par la mesure d'une longueur de diffusion complexe

    Energy Technology Data Exchange (ETDEWEB)

    Raievski, V; Horowitz, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    The further method is the outcome of a technique used in the study of neutrons in scattering and slowing-down environment. In this technique, we replace the constant sources used in the classic experiences by modulated sources with a variable frequency. The object of this article is to describe the extension of the method for the mean free path for transport of thermal neutrons and also to indicate the possible applications for other sizes, as the slowing length, or the absolute value of the cross-section of the boron. (M.B.) [French] La methode qui va etre decrite est l'aboutissement d'une technique utilisee dans l'etude des milieux ou diffusent et se ralentissent des neutrons. Dans cette technique, on remplace les sources constantes utilisees dans les experiences classiques par des sources modulees, a frequence variable. L'objet de cet article est de decrire l'extension de la methode a la mesure du libre parcours moyen de transport des neutrons thermiques et egalement d'indiquer les applications possibles a la mesure d'autres grandeurs, telles que la longueur de ralentissement, ou la valeur absolue de la section de capture du bore. (M.B.)

  6. Determination of Thermodynamical Data of Calcium Hydroxichloride Détermination des données thermodynamiques de l'hydroxychlorure de calcium

    Directory of Open Access Journals (Sweden)

    Allal K. M.

    2006-12-01

    Full Text Available The reaction of hydrochloric acid with dry alkaline sorbents such as hydrated lime in the incineration units leads to the formation of not only calcium chloride but calcium hydroxichloride as well. A thermodynamic study of the chemical reactions involved in the dechlorination process is required in order to show if such a product is theoretically possible to be formed. However, the data of CaCIOH necessary to carry out such a study are not available in the literature. Hence, a method of predicting these data is developed in the present work. Predicted values of Gibbs energy and entropy of formation of CaCIOH at different temperatures are compared to values calculated by Mostafa's model and satisfactory results were obtained. La réaction de l'acide chlorhydrique avec des adsorbants alcalins tels que la chaux au niveau de stations d'incinération entraîne la formation de chlorure ainsi que de l'hydroxychlorure de calcium. Une étude thermodynamique des différentes réactions mises en jeu dans le procédé de déchloruration serait nécessaire, afin de montrer qu'un tel produit serait théoriquement susceptible d'être formé. Cependant, les données thermodynamiques de CaCIOH permettant de mener à bien une telle étude ne sont pas disponibles dans la littérature. Par conséquent, une méthode permettant de prédire ces données a été développée dans ce présent travail. Des valeurs d'énergie de Gibbs et d'entropie de formation de CaCIOH prédites par cette méthode à différentes températures ont été comparées à celles déterminées à l'aide du modèle de Mostafa, et des résultats satisfaisants ont été obtenus.

  7. Analyses and quantitative determination of the strontium radioisotopes 89 and 90 in milk powder; Recherche et dosage des isotopes radioactifs 89 et 90 du strontium dans le lait en poudre

    Energy Technology Data Exchange (ETDEWEB)

    Jeanmaire, L; Michon, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    The authors describe a procedure for the determination of the strontium radioisotopes 89 and 90. The concentration of strontium is made possible by the insolubility of its nitrate salt in strong nitric acid which allows the removal of greatest part of calcium. The purification is performed on a cation exchange column. The amount of radioisotope 90 is determined by means of its daughter product yttrium 90 necessary calibrations and computations are treated in special paragraphs. With regard to the reproducibility of the measurements, the fluctuations are less than 20 per cent. This seems satisfaction for such a technique which have great sensibility while being long and necessitative great carefulness. (author) [French] Les auteurs decrivent une technique de dosage des isotopes 89 et 90 du strontium. La concentration du strontium est assuree grace a l'insolubilite de son nitrate dans l'acide nitrique concentre, ce qui permet d'eliminer la plus grande partie du Ca. La purification se fait sur une colonne echangeuse de cations. L'isotope 90 est dose grace a son descendant l'yttrium 90. Les etalonnages et calculs necessaires font l'objet de paragraphes detailles. En ce qui concerne la reproductibilite des mesures, les fluctuations sont inferieures a 20 pour cent, ce qui semble satisfaisant devant la grande sensibilite de la methode qui reste cependant longue et delicate. (auteur)

  8. Gases and carbon in metals

    International Nuclear Information System (INIS)

    Jehn, H.; Fromm, E.; Hoerz, G.

    1978-01-01

    This issue is part of a series of data on 'gases and carbon in metals'. The present survey includes results from papers dealing with gases and carbon in actinides and recommends critically selected data for each element. Firstly data od binary systems are presented, starting with hydrogen and followed by carbon, nitrogen, oxygen, and rare gases. Within one metal-metalloid system the data are listed under topics such as solubility limit, dissociation pressure of compunds, vapour pressure of volatile oxides, thermodynamic data, diffusion, transport parameters (effective valence, heat of transport), permeation of gases through metals, gas adsorption and gas desorption kinetics, compound formation, precipitation kinetics, and property changes. Following the data on binary systems, the data of ternary systems are presented, beginning with systems which contain one metal and two gases or one gas and carbon and continuing with systems with two metals and one gas or carbon. Within a ternary system the topics are arranged in the same way as in binary systems. (HB) [de

  9. Application of the FTIR system K300 for the emission and immission measurement of atmospheric trace gases and harmful substances in the air: examples of cases and results. Anwendung des FTIR-Systems K300 zur Emissions- und Immissionsmessung atmosphaerischer Spurengase und Luftschadstoffe: Fallbeispiele und Ergebnisse

    Energy Technology Data Exchange (ETDEWEB)

    Eisenmann, T [Kayser-Threde GmbH, Muenchen (Germany); Mosebach, H [Kayser-Threde GmbH, Muenchen (Germany); Bittner, H [Kayser-Threde GmbH, Muenchen (Germany)

    1993-01-01

    The K300 double oscillation interferometer used for the investigations is a Fourier transform infrared (FTIR) spectrometer which, due to its special optical design, is very suitable for high resolution remote sensing emission and immission (long-path monitoring) measurements of harmful substances in the air and atmospheric trace gases, when used in the field. The spectrum of applications extends from the direct measurement of hot chimney waste gases and of engine exhaust gases via the monitoring of industrial plants or waste dumps (diffuse emission) to the immission measurement of sites with heavy traffic. For direct emission measurements, the infrared characteristic radiation of hot waste gases is used; for the measurement of cold diffuse emission or immission, one measures against an artificial infrared source of radiation, which can be erected at a distance of several hundred metres from the equipment (bistatic configuration, socalled long-path monitoring). The results of different applications, which were obtained in the context of various campaigns of measurements, are shown after a short introduction of the system. (orig./BBR)

  10. Presentation of conclusions of the 9. meeting of the working group on the division by four of the greenhouse gases emissions in France for 2050, called factor 4; Releve de conclusions de la 9. reunion du groupe de travail sur la division par quatre des emissions de gaz a effet de serre de la France a l'horizon 2050, dit Facteur 4

    Energy Technology Data Exchange (ETDEWEB)

    Lamblin, V

    2006-05-15

    This document provides opinions and recommendations of the working group on the factor 4. It deals with the individual behaviors and their positive evolution, the part of the public policies, the actions of the CITEPA, the scientific context about the greenhouse gases decrease objectives, the works of the factor 4 and the long dated reduction aboard. (A.L.B.)

  11. Pulse radiolysis of gases

    International Nuclear Information System (INIS)

    Nielsen, O.J.

    1984-04-01

    The pulse radiolysis equipment and technique are described and its relevance to atmospheric chemistry is discussed. Pulse radiolysis of a number of different chemical systems have been used to check the validity of the proposed mechanisms: 1) The hydrogen atom yield in the pulse radiolysis of H 2 was measured by four independent calibration techniques, using reactions of H with O 2 , C1NO, and HI. The H atom yield was compared with O 2 yields in pure O 2 and in O 2 /SF 6 mixtures which lead to a value G(H) = 17.6. The rate constants at room temperature of several reactions were determined. 2) OH radical reactions with tetraalkyllead at room temperature and with ethane, methane, and a series of C1- and F-substituted methanes at 300-400 K were studied. Arrhenius parameters, A and Esub(a), were determined for several reactions. The lifetime of Pb(CH 3 ) 4 and Pb(C 2 H 5 ) 4 in ambient air is estimated. CF 2 C1 2 was found to be a very efficient third body, M, in the reaction OH + OH + M arrow H 2 O 2 + M. 3) In the H 2 S systems the HS extinction coefficient at 3242 AA was determined to 9.5 x 10 2 cm -1 mol -1 . Four rate constants at room temperature were determined. (author)

  12. Thermodynamics of ultracold Fermi gases

    International Nuclear Information System (INIS)

    Nascimbene, Sylvain

    2010-01-01

    Complex Hamiltonians from condensed matter, such as the Fermi-Hubbard model, can be experimentally studied using ultracold gases. This thesis describes a new method for determining the equation of state of an ultracold gas, making the comparison with many-body theories straightforward. It is based on the measurement of the local pressure inside a trapped gas from the analysis of its in situ image. We first apply this method to the study of a Fermi gas with resonant interactions, a weakly-interacting 7 Li gas acting as a thermometer. Surprisingly, none of the existing many-body theories of the unitary gas accounts for the equation of state deduced from our study over its full range. The virial expansion extracted from the high-temperature data agrees with the resolution of the three-body problem. At low temperature, we observe, contrary to some previous studies, that the normal phase behaves as a Fermi liquid. Finally we obtain the critical temperature for superfluidity from a clear signature on the equation of state. We also measure the pressure of the ground state as a function of spin imbalance and interaction strength - measure directly relevant to describe the crust of neutron stars. Our data validate Monte-Carlo simulations and quantify the Lee-Huang-Yang corrections to mean-field interactions in low-density fermionic or bosonic superfluids. We show that, in most cases, the partially polarized normal phase can be described as a Fermi liquid of polarons. The polaron effective mass extracted from the equation of state is in agreement with a study of collective modes. (author)

  13. Desulphurization of exhaust gases in chemical processes

    Energy Technology Data Exchange (ETDEWEB)

    Asperger, K.; Wischnewski, W.

    1981-01-01

    The sulfur content of exhaust gases can be reduced by: desulphurization of fuels; modification of processes; or treatment of resultant gases. In this paper a few selected examples from the chemical industry in the German Democratic Republic are presented. Using modified processes and treating the resultant gases, the sulphuric content of exhaust gases is effectively reduced. Methods to reduce the sulfur content of exhaust gases are described in the field of production of: sulphuric acid; viscose; fertilizers; and paraffin.

  14. The application of isotope techniques to the analysis of gases

    International Nuclear Information System (INIS)

    Leonhardt, J.W.; Grosse, H.J.; Popp, P.; Thuemmel, H.W.

    1978-01-01

    The development of devices for the detection of nuclear radiation has also led to systems permitting concentrations of gaseous components in gases or mixtures of gases to be determined with the aid of ionizing radiation. Such systems, which use either the ionization of gases in connection with recombination processes or the multiplication of charged particles, or the excitation of gases by means of α,β,γ or X-rays, are described. The most frequently used ionization detectors (electron capture detectors, aerosol ionization analysers, cross-section detectors, noble gas detectors and electron mobility detectors) are characterized with reference to their properties and main fields of application. It is shown that as a result of the development of sensitive energy-resolving detectors the possibilities for the utilization of excitation processes for gas analysis are increasing. The prospects for ionization detectors and systems based on the excitation of characteristic X-rays are discussed. (author)

  15. Determination of the contributions of the waste management sector to increasing resource productivity and of the share recycling takes in the value-added chain displaying the paths of recovery of relevant waste; Ermittlung des Beitrages der Abfallwirtschaft zur Steigerung der Ressourcenproduktivitaet sowie des Anteils des Recyclings an der Wertschoepfung unter Darstellung der Verwertungs- und Beseitigungspfade des ressourcenrelevanten Abfallaufkommens

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, Joerg; Heidrich, Kerstin; Baumann, Janett; Kuegler, Thomas; Reichenbach, Jan [INTECUS GmbH Abfallwirtschaft und umweltintegratives Management, Dresden (Germany)

    2012-05-15

    The degree of substitution of primary raw materials by secondary raw materials cannot explicitly be seen in the resource productivity indicator of the national sustainability strategy. To incorporate the effects of substitution of primary raw materials, secondary raw materials should be considered in addition as a separate category. In the present study a reproducible and continuously adaptable presentation of material flows of recyclable wastes has been developed and the contributions of the waste management sector to resource productivity have been described on that basis. The material flows of metal, plastics, construction and demolition waste as well as for the biodegradable waste were mapped at a low level of detail using German waste statistics. With the help of in-depth studies the material flows of iron and steel, copper, gold, polyethylene (HD- /LDPE), polyethylene terephthalate (PET) and polyvinyl chloride (PVC) could be displayed in more detail. The amounts of waste and secondary raw materials determined in this way led to a quantification of the feedstock, energy and economic savings from recycling by means of a comparison with the primary commodities substituted. Without considering preceding steps of processing and production abroad the raw material and energetic substitution was set into relation with the consumption of primary materials by the German economy to establish the socalled DERec parameter (Direct Effect of Recovery). The total DERec, determined for all material flows considered in the study amounts to 49.525 million tons, which, in the absence of recycling and energy recovery, would additionally be necessary to generate the substituted raw materials and energy. This would mean a significant increase in material inputs to the economy. Only this amount already corresponds to 3.7% of DMI (Direct Material Input), which in 2007 made up a total of 1.35 billion tons of domestic and imported abiotic resources. This underlines the importance of

  16. Process for separating radioactive gases

    International Nuclear Information System (INIS)

    Kimura, Shigeru; Awada, Yoshihisa.

    1976-01-01

    Object: To efficiently and safely separate and recover raw gases such as krypton which requires radioactive attenuation by a long term storage. Structure: A mixture of krypton and xenon is separated by liquefaction from raw gases at a first distillation column, using latent heat of liquid nitrogen. The krypton and xenon mixture separated by liquefaction at the first distillation column is separated into krypton and xenon, by controlling operation pressure of a second distillation column at about 3 - 5 atm., using sensible heat of low temperature nitrogen gas discharged from a top of the first distillation column and a condenser. (Aizawa, K.)

  17. The ideal gases of tachyons

    International Nuclear Information System (INIS)

    Mrowczynski, St.

    1984-01-01

    The formalism of statistical mechanics of particles slower than light has been considered from the point of view of the application of this formalism for the description of tachyons. Properties of ideal gases of tachyons have been discussed in detail. After finding general formulae for quantum, Bose and Fermi gases the classical limit has been considered. It has been shown that Bose-Einstein condensation occurs. The tachyon gas of bosons violates the third principle of thermodynamics. Degenerated Fermi gas has been considered and in this case the entropy vanishes at zero temperature. Difficulties of formulating covariant statistical mechanics have been discussed

  18. A microscope for Fermi gases

    International Nuclear Information System (INIS)

    Omran, Ahmed

    2016-01-01

    This thesis reports on a novel quantum gas microscope to investigate many-body systems of fermionic atoms in optical lattices. Single-site resolved imaging of ultracold lattice gases has enabled powerful studies of bosonic quantum many-body systems. The extension of this capability to Fermi gases offers new prospects to studying complex phenomena of strongly correlated systems, for which numerical simulations are often out of reach. Using standard techniques of laser cooling, optical trapping, and evaporative cooling, ultracold Fermi gases of 6 Li are prepared and loaded into a large-scale 2D optical lattice of flexible geometry. The atomic distribution is frozen using a second, short-scaled lattice, where we perform Raman sideband cooling to induce fluorescence on each atom while maintaining its position. Together with high-resolution imaging, the fluorescence signals allow for reconstructing the initial atom distribution with single-site sensitivity and high fidelity. Magnetically driven evaporative cooling in the plane allows for producing degenerate Fermi gases with almost unity filling in the initial lattice, allowing for the first microscopic studies of ultracold gases with clear signatures of Fermi statistics. By preparing an ensemble of spin-polarised Fermi gases, we detect a flattening of the density profile towards the centre of the cloud, which is a characteristic of a band-insulating state. In one set of experiments, we demonstrate that losses of atom pairs on a single lattice site due to light-assisted collisions are circumvented. The oversampling of the second lattice allows for deterministic separation of the atom pairs into different sites. Compressing a high-density sample in a trap before loading into the lattice leads to many double occupancies of atoms populating different bands, which we can image with no evidence for pairwise losses. We therefore gain direct access to the true number statistics on each lattice site. Using this feature, we can

  19. Determination of neutron resonance parameters of Neptunium 237 between 0 and 500 eV. The covariance matrices of statistical and of systematic origin, relating the resonance parameters, are also given; Determination des parametres des resonances neutroniques du neptunium 237, en dessous de 500eV, et obtention des matrices de covariances statistiques et systematiques entre les parametres de ces resonances

    Energy Technology Data Exchange (ETDEWEB)

    Lepretre, A.; Herault, N. [CEA Saclay, Dept. d' Astrophysique de Physique des Particules, de Physique Nucleaire et de l' Instrumentation Associee, 91- Gif sur Yvette (France); Brusegan, A.; Noguere, G.; Siegler, P. [Institut des Materiaux et des Metrologies - IRMM, Joint Research Centre, Gell (Belgium)

    2002-12-01

    This report is a follow up of the report CEA DAPNIA/SPHN-99-04T of Vincent Gressier. In the frame of a collaboration between the 'Commissariat a l'Energie Atomique (CEA)' and the Institute for Reference Materials and Measurement (IRMM, Geel, Belgique), the resonance parameters of neptunium 237 have been determined in the energy interval between 0 and 500 eV. These parameters have been obtained by using the Refit code in analysing simultaneously three transmission experiments. The covariance matrix of statistical origin is provided. A new method, based on various sensitivity studies is proposed for determining also the covariance matrix of systematic origin, relating the resonance parameters. From an experimental viewpoint, the study indicated that, with a large probability, the background spectrum has structure. A two dimensional profiler for the neutron density has been proved feasible. Such a profiler could, among others, demonstrate the existence of the structured background. (authors)

  20. Analysis of determination modalities concerning the exposure and emission limits values of chemical and radioactive substances; Analyse des modalites de fixation des valeurs limites d'exposition et d'emission pour les substances chimiques et radioactives

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, C.; Schneider, T

    2002-08-01

    This document presents the generic approach adopted by various organizations for the determination of the public exposure limits values to chemical and radioactive substances and for the determination of limits values of chemical products emissions by some installations. (A.L.B.)

  1. Experimental Determination of the Neutron Characteristics of UO{sub 2}-PuO{sub 2}-H{sub 2}O Lattices; Determination Experimentale Des Caracteristiques Neutroniques De Reseaux UO{sub 2}-PuO{sub 2}-H{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Debrue, J.; Fabry, A.; Leenders, L.; Motte, F.; Van Den Broeck, H. [Centre d' Etude de l' Energie Nucleaire, Mol (Belgium)

    1967-09-15

    plutonium: fission density measurements by direct counting of the fission products formed in the mixed fuel as a result of irradiation, and measurements of spectral indices by means of fission detectors and detectors having resonances close to those of the isotopes of plutonium. The optimum conditions for applying these techniques are described and the effect on the fuel cycle of uncertainties in the values for the spectral indices (ratios of cross-sections) is discussed. A brief reference is finally made to a programme of sub-critical experiments conducted hitherto with two batches of UO{sub 2} fuel enriched to 5% and 7% {sup 235}U, and having the purpose of studying possible methods of exciting a sub-critical lattice by means of an external neutron source in pulsed and modulated operation. The aim of this programme is to ascertain to what extent these methods, which employ a quantity of fuel considerably less than the critical mass, can help in determining the characteristics of a lattice. The advantages of such methods are particularly obvious in the case of plutonium fuels. (author) [French] Au cours de l'etude dans l'installation critique VENUS du coeur a moderation variable du reacteur BR3/VULCAIN, un assemblage combustible constitue de 37 crayons UO{sub 2}-PuO{sub 2} (94% UO{sub 2} naturel, PuO{sub 2}) a ete substitue a un des assemblages combustibles UO{sub 2} enrichi a 7% {sup 235}U constituant le coeur de ce reacteur. Des experiences ont ete effectuees dans le but de permettre l'ajustement des modeles du calcul des performances de cet assemblage special: on a notamment mesure la distribution de la densite de fission ainsi que l'evolution du rapport des sections efficaces effectives de fission dans {sup 239}Pu et {sup 235}U. Une experience critique directement orientee sur les problemes de recyclage du plutonium dans les reacteurs thermiques a eau legere pressurisee est en cours d'execution dans la meme installation critique. A cette fin, on dispose de deux

  2. Method for detecting trace impurities in gases

    Science.gov (United States)

    Freund, S.M.; Maier, W.B. II; Holland, R.F.; Beattie, W.H.

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (approx. 2 ppM) present in commercial Xe and ppM levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  3. Positron scattering from noble gases future prospects

    Energy Technology Data Exchange (ETDEWEB)

    Jones, A C L; Caradonna, P; Makochekanwa, C; Slaughter, D S; Sullivan, J P; Buckman, S J [Centre for Antimatter-Matter Studies, Research School of Physics and Engineering, Australian National University, Canberra, ACT (Australia); Mitroy, J, E-mail: acj107@rsphysse.anu.edu.a [Faculty of Education Health and Science, Charles Darwin University, NT (Australia)

    2009-11-01

    Recent results for positron scattering from noble gases over an energy range from 0.5 to 60eV are presented. Measurements include the grand total ({sigma}{sub GT}), Ps formation ({sigma}{sub Ps}) and Grand total - Ps formation (({sigma}{sub GT}-P{sub s}) cross sections. Some preliminary DCS results will also be presented. Work on a formulation of modified effective range theory (MERT) is being undertaken to determine the value of the scattering length which may be useful for identifying a bound state. Plans for experiments on metal atoms will be outlined.

  4. On the velocity distributions of granular gases

    International Nuclear Information System (INIS)

    Polito, A.M.M.; Rocha Filho, T.M.; Figueiredo, A.

    2009-01-01

    We present a new approach to determine velocity distributions in granular gases to improve the Sonine polynomial expansion of the velocity distribution function, at higher inelasticities, for the homogeneous cooling regime of inelastic hard spheres. The perturbative consistency is recovered using a new set of dynamical variables based on the characteristic function and we illustrate our approach by computing the first four Sonine coefficients for moderate and high inelasticities. The analytical coefficients are compared with molecular dynamics simulations results and with a previous approach by Huthmann et al.

  5. Transport processes in ionized gases

    International Nuclear Information System (INIS)

    Kremer, G.M.

    1997-01-01

    Based on kinetic theory of gases and on the combined of Chapman-Enskog and Grad, the laws of Ohm, Fourier and Navier-Stokes are derived for a non-relativistic fully ionized gas. Moreover, the combined method is applied to the BGK model of the relativistic Boltzmann equation and the Ohm's law is derived for a relativistic fully ionized gas. (author)

  6. Stratospheric aerosols and precursor gases

    Science.gov (United States)

    1982-01-01

    Measurements were made of the aerosol size, height and geographical distribution, their composition and optical properties, and their temporal variation with season and following large volcanic eruptions. Sulfur-bearing gases were measured in situ in the stratosphere, and studied of the chemical and physical processes which control gas-to-particle conversion were carried out in the laboratory.

  7. Permeability of cork to gases.

    Science.gov (United States)

    Faria, David P; Fonseca, Ana L; Pereira, Helen; Teodoro, Orlando M N D

    2011-04-27

    The permeability of gases through uncompressed cork was investigated. More than 100 samples were assessed from different plank qualities to provide a picture of the permeability distribution. A novel technique based on a mass spectrometer leak detector was used to directly measure the helium flow through the central area of small disks 10 mm in diameter and 2 mm thick. The permeability for nitrogen, oxygen, and other gases was measured by the pressure rise technique. Boiled and nonboiled cork samples from different sections were evaluated. An asymmetric frequency distribution ranging 3 orders of magnitude (roughly from 1 to 1000 μmol/(cm·atm·day)) for selected samples without macroscopic defects was found, having a peak below 100 μmol/(cm·atm·day). Correlation was found between density and permeability: higher density samples tend to show lower permeability. However, boiled cork showed a mean lower permeability despite having a lower density. The transport mechanism of gases through cork was also examined. Calculations suggest that gases permeate uncompressed cork mainly through small channels between cells under a molecular flow regime. The diameter of such channels was estimated to be in the range of 100 nm, in agreement with the plasmodesmata size in the cork cell walls.

  8. Determination by neutron activation of the uranium-235 concentration in uranium oxides; Determination par activation neutronique de la concentration d'uranium-235 dans des oxydes d'urane

    Energy Technology Data Exchange (ETDEWEB)

    May, S; Leveque, P [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    Classical methods of measuring isotopic abundance have the disadvantage of being long and of requiring chemical separation. A non-destructive method of measuring the uranium-235 content is described. It is based on an overall measurement of the short lived fission product activity formed during a 15 s neutron irradiation. The precision is of the order {+-} 1.5 per cent for 20 per cent enriched samples. The error due to the contribution from fast fission is discussed in detail. (author) [French] Les methodes classiques de mesure de l'abondance isotopique presentent le gros inconvenient d'etre longues et de necessiter des separations chimiques. Nous exposons une methode non destructive de mesure de la concentration d'uranium-235. Elle est basee sur la mesure globale de l'activite des produits de fission de courte periode formes par une irradiation neutronique de 15 s de l'echantillon. La precision est de l'ordre de {+-} 1,5 pour cent pour des echantillons enrichis jusqu'a 20 pour cent. L'erreur a la contribution de la fission rapide est discutee en detail. (auteur)

  9. Des Connaissances Aux Politiques

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les synergies ont été mises en commun au fur et à mesure des progrès de la recherche. .... Recherche normative (sur le rôle et la performance des institutions .... Système national d'information sur la gestion environnementale connecté à 19 ...... Un fort contrôle centralisé sur l'élaboration des politiques nationales peut ...

  10. Évaluation des pratiques agricoles des légumes feuilles : le cas des ...

    African Journals Online (AJOL)

    SARAH

    30 sept. 2017 ... ... de Biochimie et Immunologie Appliquée, Centre de Recherche en Sciences Biologiques, Alimentaires et .... l'intoxication des agriculteurs et des consommateurs, ... source d'alimentation en eau et au pouvoir d'achat des.

  11. Luminescence yield in irradiating gases by X-rays and alpha particles

    International Nuclear Information System (INIS)

    Combecher, D.

    1973-01-01

    In this paper, the measurable light emission in the irradiation of gases as modle substances has been quantitatively determined. The gases Ar, H 2 , N 2 , air, and C 3 H 8 were irradiated with X-rays and α-particles at a pressure of 730 torr. The emitted light was measured in the spectral range between the short-wave absorption edge of the gases and 6000 A (spectral resolution: 20 A). The spectral light yield was determined from the efficiency of the apparatus and from the total energy absorbed in the gases. (HK) [de

  12. The Determination of Components of Radioactive Decay Mixtures by Computer Analysis of Count-Rate Data; Determination des Composants de Melanges Radioactifs en Decroissance par Analyse a l'Ordinateur des Resultats du Comptage; Opredelenie komponentov smesej radioaktivnogo raspada posredstvom analiza dannykh skorostej scheta s pomoshch'yu schetno-reshayushchego ustrojstva; Determinacion de los Componentes de Mezclas Radiactivas por Analisis de los Datos de Recuento Mediante Calculadoras

    Energy Technology Data Exchange (ETDEWEB)

    Airman, W. D.F.; Tyler, S. A.; Dipertand, M. H.; Sedlet, J. [Argonne National Laboratory, Argonne, IL (United States)

    1965-10-15

    measurements are made permit correlations between the data obtained and the total decay and growth rates. The development of the programme and the results obtained from theoretical and experimental data used to test it are discussed. (author) [French] Les composants d'un melange de n radioisotopes peuvent etre determines d'apres les variations de l'activite avec le temps, a condition que l'activite d'au moins n-1 elements se modifie de maniere appreciable au cours de la periode consideree, soit par la decroissance directe, soit par la croissance des produits de desintegration. Pour chaque melange, il est possible de predire un ensemble d'elements d'apres des facteurs tels que l'origine et l'evolution anterieure du melange et les techniques de separation chimique et de comptage utilisees. Si ces facteurs sont appliques de maniere convenable, l'ensemble suppose contiendra tous les elements que comporte effectivement le melange. On peut alors, soit formuler les equations de croissance ou de decroissance et les resoudre simultanement pour obtenir chaque element, soit determiner le melange sous forme graphique par extrapolation des parties lineaires de la courbe totale decroissance-croissance. Toutefois, lorsque le nombre d'elements est eleve ou que des schemas complexes de decroissance entrent en ligne de compte, il est impossible, soit d'appliquer l'une ou l'autre de ces techniques, soit d'evaluer les erreurs inherentes aux previsions. L'application de la methode des moindres carres permet d'identifier plus exactement les elements en decroissance que la methode consistant a n'utiliser que des equations simultanees. Les auteurs ont donc mis au point un programme d'ordinateur Fortran, fonde sur la methode des moindres carres (designe par le vocable CORD) et destine a resoudre le probleme general, a savoir: etant donne le taux de comptage pour un echantillon, les precurseurs et les schemas de decroissance possibles, toutes les constantes de decroissance et les caracteristiques de

  13. History of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gases Experiment (AGAGE

    Directory of Open Access Journals (Sweden)

    R. G. Prinn

    2018-06-01

    Full Text Available We present the organization, instrumentation, datasets, data interpretation, modeling, and accomplishments of the multinational global atmospheric measurement program AGAGE (Advanced Global Atmospheric Gases Experiment. AGAGE is distinguished by its capability to measure globally, at high frequency, and at multiple sites all the important species in the Montreal Protocol and all the important non-carbon-dioxide (non-CO2 gases assessed by the Intergovernmental Panel on Climate Change (CO2 is also measured at several sites. The scientific objectives of AGAGE are important in furthering our understanding of global chemical and climatic phenomena. They are the following: (1 to accurately measure the temporal and spatial distributions of anthropogenic gases that contribute the majority of reactive halogen to the stratosphere and/or are strong infrared absorbers (chlorocarbons, chlorofluorocarbons – CFCs, bromocarbons, hydrochlorofluorocarbons – HCFCs, hydrofluorocarbons – HFCs and polyfluorinated compounds (perfluorocarbons – PFCs, nitrogen trifluoride – NF3, sulfuryl fluoride – SO2F2, and sulfur hexafluoride – SF6 and use these measurements to determine the global rates of their emission and/or destruction (i.e., lifetimes; (2 to accurately measure the global distributions and temporal behaviors and determine the sources and sinks of non-CO2 biogenic–anthropogenic gases important to climate change and/or ozone depletion (methane – CH4, nitrous oxide – N2O, carbon monoxide – CO, molecular hydrogen – H2, methyl chloride – CH3Cl, and methyl bromide – CH3Br; (3 to identify new long-lived greenhouse and ozone-depleting gases (e.g., SO2F2, NF3, heavy PFCs (C4F10, C5F12, C6F14, C7F16, and C8F18 and hydrofluoroolefins (HFOs; e.g., CH2  =  CFCF3 have been identified in AGAGE, initiate the real-time monitoring of these new gases, and reconstruct their past histories from AGAGE, air archive, and firn air measurements; (4

  14. Radiation hazards in the neighbourhood of uranium reactors; Dangers des rayonnements aupres des piles a uranium

    Energy Technology Data Exchange (ETDEWEB)

    Joffre, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1956-07-01

    Radiation hazards near uranium reactors may be divided in two groups. Hazards when the reactor is normally operating: {gamma} radiation from hot uranium or air contamination by fission gases, {gamma} radiation or contamination by the coolant (air, nitrogen, heavy-water), {gamma} radiation from radioisotopes. Hazards in the case of an accident: presence of hot uranium in the atmosphere, soil contamination. (author) [French] Les dangers d'irradiation aupres des piles a uranium sont a classer essentiellement en deux groupes. Les dangers existant aupres d'une pile exploitee normalement: irradiation {gamma} par l'uranium irradie ou contamination de l'air par des gaz de fission, irradiation {gamma} ou contamination par les fluides de refroidissement (air, azote, eau lourde), irradiation {gamma} par les radioelements fabriques. Les dangers en cas d'accident survenant a un reacteur en fonctionnement, ayant pour consequence : la presence dans l'air d'uranium irradie, la contamination du sol. (auteur)

  15. Soliton Gases and Generalized Hydrodynamics

    Science.gov (United States)

    Doyon, Benjamin; Yoshimura, Takato; Caux, Jean-Sébastien

    2018-01-01

    We show that the equations of generalized hydrodynamics (GHD), a hydrodynamic theory for integrable quantum systems at the Euler scale, emerge in full generality in a family of classical gases, which generalize the gas of hard rods. In this family, the particles, upon colliding, jump forward or backward by a distance that depends on their velocities, reminiscent of classical soliton scattering. This provides a "molecular dynamics" for GHD: a numerical solver which is efficient, flexible, and which applies to the presence of external force fields. GHD also describes the hydrodynamics of classical soliton gases. We identify the GHD of any quantum model with that of the gas of its solitonlike wave packets, thus providing a remarkable quantum-classical equivalence. The theory is directly applicable, for instance, to integrable quantum chains and to the Lieb-Liniger model realized in cold-atom experiments.

  16. Noble Gases in Lakes and Ground Waters

    OpenAIRE

    Kipfer, Rolf; Aeschbach-Hertig, Werner; Peeters, Frank; Stute, Marvin

    2002-01-01

    In contrast to most other fields of noble gas geochemistry that mostly regard atmospheric noble gases as 'contamination,' air-derived noble gases make up the far largest and hence most important contribution to the noble gas abundance in meteoric waters, such as lakes and ground waters. Atmospheric noble gases enter the meteoric water cycle by gas partitioning during air / water exchange with the atmosphere. In lakes and oceans noble gases are exchanged with the free atmosphere at the surface...

  17. Comparaison de diverses méthodes de dosage des argiles d'un sable de gisement. Dosage des argiles Comparison of Different Methods of Determining Clays in a Reservoir Sand. Quantitative Analysis of Clays

    Directory of Open Access Journals (Sweden)

    Yvon J.

    2006-11-01

    Full Text Available Les argiles d'un sable de gisement, concentrées dans la fraction de diamètre Phi Oil, gas and geothermal reservoirs all contain clayey fractions no matter how small they may be. This has been blamed whenever operating or producing problems arise. It may be revealed by phenomena of mechanical resistance, permeability or interfacial properties (ion exchange, adsorption, etc. . Tests to understand such phenomena then go via the quantitative mineralogical analysis of the clays present. This analysis must also be looked at in terms of methods. It is subjected to constraints of cost, instrumentation, competence or deadlines. This article proposes:(a A so-called conventional route (Dejou et al, 1977 based on chemical and weighted analyses. (b An overall assessment method of the clay phase by difference (determination of two nonclay species. (c A method based on the statistical processing of microanalytic data obtained by an electronic microprobe. The material examined was a quartzose arenite made up mainly of quartz, jarosite, orthoclase, plagioclases, calcite, dolomite, muscovite, kaolinite, illite, montmorillonite, interstratified illite-montmorillionite, iron oxyhydroxides and accessory minerals such as rutile, zircon, garnet, tourmaline and hydroxylapatite. The arenite was subjected to an ultrasonic treatment (Letelier, 1986 to recover pellicular or weakly cemented clays. After this treatment, all the free clays were found in the < 40 m fraction which were used for the measurements. The so-called conventionalmethod is based on the associating of multiple techniques that are normally used for analyzing clays. They include X-ray diffraction, TDA, TGA, selective dissolution, CEC, adsorption of various reagents and gravimetric separations. They have been reviewed by Dejou et al (1977. The results they give depend on the grain size, chrystallochemistry, presence of amorphous elements and especially the typical chemical compositions assigned to the

  18. Centrifugal separation of mixture gases

    International Nuclear Information System (INIS)

    Zhou, M.S.; Chen, W.N.; Yin, Y.T.

    2008-01-01

    An attempt for single centrifugal separation of mixtures with different molecular formula was presented in this paper. The mixtures of SF 6 and CCl 3 F, and SF 6 and CCl 4 were chosen as the processing gases, which were prepared in three mass ratios, 0.5, 0.8 and 0.2, respectively. The separating characteristics such as the overall separation factors and the variation of cuts were studied. (author)

  19. Landfill gases and some effects on vegetation

    Science.gov (United States)

    Franklin B. Flower; Ida A. Leone; Edward F. Gilman; John J. Arthur

    1977-01-01

    Gases moving from refuse landfills through soil were studied in New Jersey. The gases, products of anaerobic decomposition of organic matter in the refuse, caused injury and death of peach trees, ornamentals, and commercial farm crops, and create possible hazards to life and property because of the entrance of combustible gases into residences. Remedial measures are...

  20. Gestion des risques

    CERN Document Server

    Louisot, Jean-Paul

    2009-01-01

    Depuis le début du lie siècle, la gestion des risques connaît une véritable révolution culturelle. Jusqu'alors fonction technique, centrée autour de l'achat de couverture d'assurances, elle est devenue une discipline managériale et transversale : une valise d'instruments que chaque manager doit connaître et appliquer quels que soient son domaine de compétence et ses missions au sein de l'organisation. En effet, la gestion des risques est une culture qui doit être assimilée par chacun des acteurs. C'est précisément l'ambition des 101 questions rassemblées dans cet ouvrage : apporter à chaque manager d'entreprise, de collectivité, d'établissement de santé..., des réponses claires au " pourquoi " et au " comment " : Comment identifier les risques ? Comment analyser les risques ? Quels sont les objectifs de la gestion des risques ? Une carte des risques pour quoi faire ? Pourquoi faut-il financer les risques ? Les entreprises ont-elles des responsabilités pénales ? En quoi consiste la gestion...

  1. La gouvernance des risques naturels et la problematique des ...

    African Journals Online (AJOL)

    Depuis quelques années, la gouvernance des risques naturels dus aux inondations remet en cause les processus de mise en oeuvre des politiques urbaines et la qualité de la structure des aménagements dans les grandes villes du Golfe de Guinée. La perception de la gouvernance et l'application des politiques de ...

  2. Effect of adding Te to layered GaSe crystals to increase the van der Waals bonding force

    Science.gov (United States)

    Tanabe, Tadao; Zhao, Shu; Sato, Yohei; Oyama, Yutaka

    2017-10-01

    The interplanar binding strength of layered GaSe1-xTex crystals was directly measured using a tensile testing machine. The GaSe1-xTex crystals were grown by a low temperature liquid phase solution method under a controlled Se vapor pressure. The stoichiometry-controlled GaSe1-xTex crystal has the ɛ-polytype structure of GaSe, where the Te atoms are substituted for some of the Se atoms in the GaSe crystal. The effect of adding Te on the bonding strength between the GaSe layers was determined from direct measurements of the van der Waals bonding energy. The bonding energy was increased from 0.023 × 106 N/m2 for GaSe to 0.16 × 106 N/m2 for GaSe1-xTex (x = 0.106).

  3. Determination of LongR3-IGF-I, R3-IGF-I, Des1-3 IGF-I and their metabolites in human plasma samples by means of LC-MS.

    Science.gov (United States)

    Thomas, Andreas; Walpurgis, Katja; Delahaut, Philippe; Fichant, Eric; Schänzer, Wilhelm; Thevis, Mario

    2017-08-01

    According to the regulations of the World Anti-Doping Agency (WADA), growth promoting peptides such as the insulin-like growth factor-I (IGF-I) and its synthetic analogues belong to the class of prohibited compounds. While several assays to quantify endogenous IGF-I have been established, the potential misuse of synthetic analogues such as LongR 3 -IGF-I, R 3 -IGF-I and Des1-3-IGF-I remains a challenge and superior pharmacokinetic properties have been described for these analogues. Within the present study, it was demonstrated that the target peptides can be successfully detected in plasma samples by means of magnetic beads-based immunoaffinity purification and subsequent nanoscale liquid chromatographic separation with high resolution mass spectrometric detection. Noteworthy, the usage of a specific antibody for LongR 3 -IGF-I enables the determination in low ng/mL levels despite the presence of an enormous excess of endogenous human IGF-I. In addition, different metabolism studies (in-vitro and in-vivo) were performed using sophisticated strategies such as incubation with skin tissue microsomes, degradation in biological fluids (for all analogues), and administration to rats (for LongR 3 -IGF-I). Herewith, several C-and N-terminally truncated metabolites were identified and their relevancy was additionally confirmed by in-vivo experiments with rodents. Especially for LongR 3 -IGF-I, a metabolite ((Des1-11)-LongR 3 -IGF-I) was identified that prolonged the detectability in-vivo by a factor of approximately 2. The method was validated for qualitative interpretation considering the parameters specificity, identification capability, recovery (26-60%), limit of detection (0.5ng/mL), imprecision (IGF-I was used as internal standard to control all sample preparation steps. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Subcooled boiling effect on dissolved gases behaviour

    International Nuclear Information System (INIS)

    Zmitko, M.; Sinkule, J.; Linek, V.

    1999-01-01

    A model describing dissolved gasses (hydrogen, nitrogen) and ammonia behaviour in subcooled boiling conditions of WWERs was developed. Main objective of the study was to analyse conditions and mechanisms leading to formation of a zone with different concentration of dissolved gases, eg. a zone depleted in dissolved hydrogen in relation to the bulk of coolant. Both, an equilibrium and dynamic approaches were used to describe a depletion of the liquid surrounding a steam bubble in the gas components. The obtained results show that locally different water chemistry conditions can be met in the subcooled boiling conditions, especially, in the developed subcooled boiling regime. For example, a 70% hydrogen depletion in relation to the bulk of coolant takes about 1 ms and concerns a liquid layer of 1 μn surrounding the steam bubble. The locally different concentration of dissolved gases can influence physic-chemical and radiolytic processes in the reactor system, eg. Zr cladding corrosion, radioactivity transport and determination of the critical hydrogen concentration. (author)

  5. Radiolytic and thermal generation of gases from Hanford grout samples

    Energy Technology Data Exchange (ETDEWEB)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Mulac, W.A.

    1993-10-01

    Gamma irradiation of WHC-supplied samples of grouted Tank 102-AP simulated nonradioactive waste has been carried out at three dose rates, 0.25, 0.63, and 130 krad/hr. The low dose rate corresponds to that in the actual grout vaults; with the high dose rate, doses equivalent to more than 40 years in the grout vault were achieved. An average G(H{sub 2}) = 0.047 molecules/100 eV was found, independent of dose rate. The rate of H2 production decreases above 80 Mrad. For other gases, G(N{sub 2}) = 0.12, G(O{sub 2}) = 0.026, G(N{sub 2}O) = 0.011 and G(CO) = 0.0042 at 130 krad/hr were determined. At lower dose rates, N{sub 2} and O{sub 2} could not be measured because of interference by trapped air. The value of G(H{sub 2}) is higher than expected, suggesting segregation of water from nitrate and nitrite salts in the grout. The total pressure generated by the radiolysis at 130 krad/h has been independently measured, and total amounts of gases generated were calculated from this measurement. Good agreement between this measurement and the sum of all the gases that were independently determined was obtained. Therefore, the individual gas measurements account for most of the major components that are generated by the radiolysis. At 90 {degree}C, H{sub 2}, N{sub 2}, and N{sub 2}O were generated at a rate that could be described by exponential formation of each of the gases. Gases measured at the lower temperatures were probably residual trapped gases. An as yet unknown product interfered with oxygen determinations at temperatures above ambient. The thermal results do not affect the radiolytic findings.

  6. Use of geothermal heat by means of energetic geostructures. Methodology to identify potential zones of application; Exploitation de la chaleur terrestre par des geostructures energetiques. Methodologie de determination des zones potentielles

    Energy Technology Data Exchange (ETDEWEB)

    Joliquin, P.

    2002-07-01

    This study focuses on the realisation of earth heat exchangers by means of so-called geostructures. These geostructures are works of concrete being in close contact with the ground and which are used for foundation or as retaining structures. The three main types of geostructures are piles, the walls and the foundation slabs. These structures can be equipped with a network of tubes where a liquid circulates to permit a heat exchange with the ground. In this case, they can be called energetic geostructures. To date, the use of this technology is rather limited in Switzerland. Therefore, the aim of this study is to increase its development, and a methodology to identify potential zones of application will be given for the purpose of energy planning. The correct land planning and the geotechnical properties of the ground are the two basic criteria to select the type of geostructure and its foundation conditions. Additional criteria like the thermal properties of the ground and the presence of groundwater will determine whether geostructures can be equipped with heat exchangers. Finally, the protection of the groundwater and thermal ground disturbances are possible criteria which could limit the application of energetic geostructures. To validate this methodology, six sites were selected in the canton of Geneva. Two of them ('La Chapelle - Les Sciers' and 'Frontenex - Gradelle'), were investigated by applying the above mentioned criteria. The conclusion is that the two sites represent potential zones for using energetic geostructures. Nevertheless, within the site 'La Chapelle - Les Sciers', the presence of an important groundwater resource was identified. To protect it, it is not permitted to pierce the impermeable layer above the aquifer, and therefore foundation depths must carefully be chosen by controlling the lengths of piles. (author)

  7. Significance of the agreement and results of the Bonn and Marrakesh Conventions with respect to long-term reduction of greenhouse gases. An analysis of supply-side and demand-side aspects; Bedeutung des Bonner Beschlusses und der Ergebnisse aus Marrakesch fuer die langfristige Senkung der Treibhausgasemissionen. Eine Analyse der Angebots- und Nachfrageseite

    Energy Technology Data Exchange (ETDEWEB)

    Wartmann, S.C.; Cremer, C.; Betz, R. [Fraunhofer Institut Systemtechnik und Innovationsforschung, Karlsruhe (Germany)

    2001-07-01

    The article examines in great detail the Bonn resolution and the results of the Marrakesh Convention of the Parties to the UNFCCC with respect to the achievable contributions to a global reduction of greenhouse emissions. The analysis looks at the most important action plans and the relevant mechanisms agreed upon and derives global demand-side and national supply-side estimates and develops relevant projections of lasting greenhouse gas reductions, also indicating further required measures. (orig./CB) [German] Es wird untersucht, inwiefern die Regelungen des Bonner Beschlusses und der Konferenz in Marrakesch tatsaechlich auf das urspruengliche Ziel der Klimarahmenkonvention, langfristige Treibhausgasminderungen, abzielen. Zunaechst werden die wichtigsten Ergebnisse dieser Konferenzen erlaeutert. Anschliessend kann die internationale Nachfrage bzw. das entsprechende Angebot an Emissionsminderungen in Bezug auf Treibhausgasminderungen abgeschaetzt werden. Es ergibt sich ein Ueberblick, ob und in welchem Masse eigene Anstrengungen der verpflichteten Staaten noch notwendig sind. (orig./CB)

  8. Quelques aspects de la géochimie organique dans la prospection des hydrocarbures Several Aspects of Organic Geochemistry in Prospection for Hydrocarbons

    Directory of Open Access Journals (Sweden)

    Kubler B.

    2006-10-01

    know whether origins are similar or different. In some cases, correlations not only between shows and accumulations, but also between source rocks and accumulations, have become certain. Study along logical lines of the development of living, dead, fossilized and then diagenized organic matter compounds, has made it possible to define the organic origin of petroleum and also to associate its composition with the dominant types of organic matter in sedimentary basins, and hence to determine sedimentation conditions and the most favourable environment for the accumulation and preservation of petroligenic organic matter. However, the greatest contribution of organic geochemistry to exploration has certainly been its ability to determine, in the initial stage, a range of temperature, and then of temperature and duration: the heat-time factor generating maximum production and then conservation of liquid hydrocarbons: the potential ail window. More recently, geochemistry of hydrocarbon gases was able to demonstrate that thisoil windowwas surrounded by the generation of light gases. This recent development has refocused attention on prospecting objectives which had been abandoned or deemed without interest. However, organic geochemistry by its very nature and like most laboratory-based sciences, yieldsspotresults; these will not be fully significant unless the geological specimens are properly situated in the geological configuration to which they belong.

  9. Photonique des Morphos

    CERN Document Server

    Berthier, Serge

    2010-01-01

    La photonique est déjà présente dans notre vie quotidienne, et on attend maintenant que la manipulation des photons permette aussi le traitement logique des informations. Cependant, l’élément de base qui permet cette manipulation de la lumière, le cristal photonique, est d’une réalisation complexe et mal contrôlée. Dans la course à la maîtrise de la lumière, les structures photoniques naturelles ont beaucoup à nous apprendre. C’est ce que nous montre Serge Berthier qui étudie dans ce livre la structure des écailles des Morphos. Tenant compte de l’essor récent des approches biomimétiques, il présente de manière détaillée plus de dix-huit techniques expérimentales utilisées pour ses analyses, ainsi que les diverses approches théoriques développées pour la modélisation de structures multi-échelles complexes. Première étude quasi-exhaustive des structures fines d’un genre et des propriétés optiques ainsi que colorimétriques générées, ce livre fournit aux entomologiste...

  10. Droit des organisations internationales

    CERN Document Server

    Sorel, Jean-Marc; Ndior, Valère

    2013-01-01

    Cet ouvrage collectif offre aux enseignants et chercheurs en droit international, aux praticiens et aux étudiants, une analyse actualisée du droit des organisations internationales. Il dresse en cinq parties un tableau, illustré par des exemples variés, des problématiques que soulève le phénomène polymorphe d institutionnalisation de la société internationale. La première partie est consacrée au phénomène des « organisations internationales », sous l angle à la fois de l institutionnalisation progressive des relations internationales et de la difficulté à cerner une catégorie unifiée. La deuxième partie rend compte de la création, de la disparition et des mutations des organisations internationales, ici envisagées comme systèmes institutionnels et ordres juridiques dérivés. La troisième partie analyse l autonomie que l acquisition de la personnalité juridique et de privilèges et immunités, un organe administratif intégré, un personnel ou un budget propres confèrent aux organi...

  11. Noble Gases in the Hamlet Meteorite (LL4)

    Science.gov (United States)

    Amari, S.; Sabe, Y.; Shiraishi, T.; Matsuda, J.

    2014-09-01

    We analyzed noble gases in a bulk sample and an HF-HCl residue of Hamlet (LL4). The Xe composition of the residue shows that no diamond is contained in the residue. The 20Ne/22Ne ratio of Hamlet Ne-Q has been determined to be 11.0 ± 0.5.

  12. Greenhouse Gases and Animal Agriculture

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, J. (ed.) [Department of Animal Science, Obihiro University of Agriculture and Veterinary Medicine, Obihiro, Hokkaido (Japan); Young, B.A. (ed.) [The University of Queensland, Gatton, Queensland 4343 (Australia)

    2002-07-01

    Reports from interdisciplinary areas including microbiology, biochemistry, animal nutrition, agricultural engineering and economics are integrated in this proceedings. The major theme of this book is environmental preservation by controlling release of undesirable greenhouse gases to realize the sustainable development of animal agriculture. Technology exists for the effective collection of methane generated from anaerobic fermentation of animal effluent and its use as a biomass energy source. Fossil fuel consumption can be reduced and there can be increased use of locally available energy sources. In addition, promoting environmentally-conscious agriculture which does not rely on the chemical fertilizer can be realized by effective use of animal manure and compost products.

  13. Mechanics of liquids and gases

    CERN Document Server

    Loitsyanskii, L G; Jones, W P

    1966-01-01

    Mechanics of Liquids and Gases, Second Edition is a 10-chapter text that covers significant revisions concerning the dynamics of an ideal gas, a viscous liquid and a viscous gas.After an expanded introduction to the fundamental properties and methods of the mechanics of fluids, this edition goes on dealing with the kinetics and general questions of dynamics. The next chapters describe the one-dimensional pipe flow of a gas with friction, the elementary theory of the shock tube; Riemann's theory of the wave propagation of finite intensity, and the theory of plane subsonic and supersonic flows.

  14. A Geochemical Approach for Monitoring a CO2 Pilot Site: Rousse, France. A Major gases, CO2-Carbon Isotopes and Noble Gases Combined Approach Une méthode géochimique pour la surveillance d’un site pilote de stockage de CO2 : Rousse, France. Approche combinant les gaz majeurs, l’isotopie du carbone du CO2 et les gaz rares

    Directory of Open Access Journals (Sweden)

    Garcia B.

    2012-02-01

    Full Text Available This paper presents the geochemical characterization of various gas end-members involved in a depleted gas field CO2 storage pilot (Rousse, France. In this pilot, CO2 is produced by oxycombustion from natural gas transformed into fuel gas at the Lacq plant, and transported in a pipeline 30 km away to the depleted gas reservoir of Rousse. Gases produced at Rousse before CO2 injection, the Lacq fuel gas and the CO2 resulting from the oxy-fuel combustion were sampled, together with gases from a –45 m monitoring well and from soils in the vicinity of the Rousse structure. For all samples, the bulk gas composition, the carbon isotopic compositions and the abundance and isotopic signatures of the noble gases were determined. The bulk gas compositions of the Rousse natural gas are comparable to the Lacq fuel gas with methane as the main compound with residual C2-C5 and CO2. Soil gases are typical mixtures of air with biogenic CO2 (up to 9-10%, while the monitoring well gases display typical air compositions with no excess CO2 The Rousse gas and the Lacq fuel gas have δ13CCH4 values of –41.0‰ and –43.0‰ respectively. The injected CO2 out of the oxycombustion chamber has a δ13CCO2 of –40.0‰, whereas δ13CCO2 value for soils samples is comprised between –15 and –25‰. The Rousse natural gas and the Lacq fuel gas are both characterized by a high He enrichment, and depletion in Ne, Ar and Kr compared to the air values. The oxyfuel combustion process provides a CO2 with the He enrichment of the Lacq fuel gas, and a Ne, Ar and Kr composition reflecting that of the oxygen produced at the Air Separation Unit (ASU. Indeed, Ne is depleted relatively to the air, while Kr is enriched up to tenfold, which results from the cryogenic separation of the air noble gases within the ASU. Soil samples noble gas compositions are equivalent to that of the air. In the light of these results, the compositions of the various end-members involved in this CO2

  15. Determination of consumption biogenic solid fuels in the commercial sector, trade, services (tertiary sector). Final report; Ermittlung des Verbrauchs biogener Festbrennstoffe im Sektor Gewerbe, Handel, Dienstleistungen (GHD-Sektor). Endbericht

    Energy Technology Data Exchange (ETDEWEB)

    Viehmann, Cornelia; Westerkamp, Tanja; Schwenker, Andre; Schenker, Marian; Thraen, Daniela; Lenz, Volker [DBFZ Deutsches BiomasseForschungsZentrum gemeinnuetzige GmbH, Leipzig (Germany); Ebert, Marcel [Leipziger Institut fuer Energie GmbH (Ireland), Leipzig (DE)

    2012-07-01

    . While in the energy balance of fossil fuels for the tertiary sector is determined by residual definition, this is not possible with biogenic solid fuels, since the sum of the total energy-recycled wood (and straw) is not known. Reasons for this are that only a fraction of the fuel are sold through the official fuel trade, while at the same time a considerable variety of usable biogenic solid fuels and their sources of supply are available. For this reason, in this project, the bottom-up approach, that is the consideration of the individual selected sectors of the tertiary sector, is used for the extrapolation. The tertiary sector comprises a wide variety of different industries, but not all are suitable for using solid fuels. Therefore, first, the identification of relevant sectors for this project is necessary. In addition to the group of relevant and irrelevant industries, potentially relevant industries are reported, which despite of currently low use of solid fuels can gain important in the future. The input data of classified relevant sectors are collected in a literature review and through interviews. These are processed accordingly and entered into the part of the project to be developed extrapolation method. For a holistic view of the tertiary sector, the extrapolation method is able to include data of potentially relevant or not relevant industries. In conclusion, in this study, the extrapolation results are presented and discussed. [German] Die Politik hat sich sowohl auf nationaler als auch auf europaeischer Ebene ambitionierte Ziele zum Ausbau erneuerbarer Energien und zur Minderung der Treibhausgasemissionen gesetzt. Im Nationalen Aktionsplan fuer Erneuerbare Energien der Bundesrepublik Deutschland sind diese Ziele bis zum Jahr 2020 definiert. Der Anteil erneuerbarer Energien bei der Bereitstellung von Waerme und Kaelte soll demnach von 6,6 % auf 15,5 % des Bruttoendenergieverbrauches steigen. Entsprechend der zunehmenden Bedeutung der solarthermischen

  16. Santé des adolescents et des jeunes au Burkina Faso : état des ...

    African Journals Online (AJOL)

    Il s'est agi d'une étude évaluative ayant utilisé une revue documentaire associée à une interview des acteurs clés et un atelier de validation et d'identification des interventions pertinentes pour un plan stratégique national. La situation de la santé des adolescents et des jeunes est caractérisée par des grossesses précoces ...

  17. Inerting Aircraft Fuel Systems Using Exhaust Gases

    Science.gov (United States)

    Hehemann, David G.

    2002-01-01

    Our purpose in this proposal was to determine the feasibility of using carbon dioxide, possibly obtained from aircraft exhaust gases as a substance to inert the fuel contained in fuel tanks aboard aircraft. To do this, we decided to look at the effects carbon dioxide has upon commercial Jet-A aircraft fuel. In particular, we looked at the solubility of CO2 in Jet-A fuel, the pumpability of CO2-saturated Jet-A fuel, the flashpoint of Jet-A fuel under various mixtures of air and CO2, the static outgassing of CO2-Saturated Jet-A fuel and the dynamic outgassing of Jet-A fuel during pumping of Jet-A fuel.

  18. Dental Encounter System (DES)

    Data.gov (United States)

    Department of Veterans Affairs — Dental Encounter System (DES) is an automated health care application designed to capture critical data about the operations of VA Dental Services. Information on...

  19. Diethylstilbestrol (DES) and Cancer

    Science.gov (United States)

    ... DES-exposed grandchildren have? Researchers are also studying possible health effects among women and men who are the children ... for unexposed men. In addition, researchers are studying possible health effects on the grandchildren of mothers who were exposed ...

  20. Table des illustrations

    OpenAIRE

    2016-01-01

    Tableaux Dates d’inauguration des grands hôtels japonais entre 1860 et 1945… 19 Histoire, tourisme et hôtellerie en Corée depuis les années 1870… 59-60 Dates d’inauguration des grands hôtels chinois depuis 1863… 84 Les hôtels de luxe et leurs capacités d’hébergement en Corée en 2000… 103 Les flux de personnes suscités par les hôtels « super luxe » de Séoul en 2000… 105 L’activité des grands hôtels à Séoul en 1999 (en wons)… 106 Propriété et gestion des grands hôtels à Séoul en 1999…. 110 La c...

  1. Direction des Publications

    African Journals Online (AJOL)

    Synthese

    potential and surface properties of their mixtures were investigated, in an ... suppose that the electrostatic repulsive interactions between the two anion ... concentration, et de la conformation des ..... proteins and polysaccharides in solutions,.

  2. determination des parametres influents de la dynamique des forets

    African Journals Online (AJOL)

    Administrateur

    Chev. Leguminoseae-Mim. LOL. Loloti. Lannea welwitschii (Hiern) Engl. Anacardiaceae. LON. Lohonfé. Celtis adolphi-frederici Engl. Ulmaceae. LOT. Lotofa. Sterculia rhinopetala K.Schum. Sterculiaceae. MEL. Mélégba. Berlinia confusa Hoyle.

  3. La revolution des savants

    CERN Document Server

    Chavanne, A

    1989-01-01

    Premiere cassette : - 1666 : impact de la creation de l'Academie des Sciences par Colbert, trente ans apres le proces de Galile, et au moment des disparitions de Pascal, Descartes et Fermat. Elle dirigee par le hollandais Huyggens jusqu'a sa fuite de France au moment de la revocation de l'Edit de Nantes. - 1750 : l'Encyclopedie (ou "Dictionnaire raisonne des Sciences, des Arts et des Metiers") de Diderot et d'Alembert, soutenus par Malherbes, Buffon, Condorcet et Rousseau. - 1789 : Revolution francaise. - 8 aout 1793 : l'Assemblee, par une declaration de Marat, dissout l'Academie des Sciences. Celle-ci continue cependant ses travaux pour les poids et mesures jusqu'en 1795. - la Terreur : la condamnation a mort, pas au nom d'une "Revolution qui n'a pas besoin de savants" mais pour d'autres raisons, de trois grands hommes de science : Lavoisier, Bailly et Condorcet. - 1793-1794 : Au printemps 93, le Comite de Salut Publique s'inquiete du demi-million de soldats etrangers de toutes les pays frontaliers qui essai...

  4. Throat gases against the CO2

    International Nuclear Information System (INIS)

    Michaut, C.

    2006-01-01

    The steel production needs carbon consumption and generates carbon dioxide, the main greenhouse gases. It represents about 6 % of the greenhouse gases emissions in the world. That is why the steel industry began last year a research program, Ideogaz, to reduce its CO 2 releases. The first results on the throat gases recovery seems very promising: it uses 25 % less of carbon. The author presents the program and the main technical aspects of the method. (A.L.B.)

  5. Optical Lattice Gases of Interacting Fermions

    Science.gov (United States)

    2015-12-02

    interacting Fermi gases has topological properties similar to the conventional chiral p- wave state. These include a non-zero Chern number and the...interacting cold gases with broad impacts on the interfaces with condensed matter and particle physics . Applications and experiments of some of the physics ...AFRL-AFOSR-VA-TR-2016-0016 Optical Lattice Gases of Interacting Fermions Wensheng Vincent Liu UNIVERSITY OF PITTSBURGH Final Report 12/02/2015

  6. Noble gases in nuclear medicine

    International Nuclear Information System (INIS)

    Calderon, M.; Burdine, J.A.

    1973-01-01

    Radioactive noble gases have made a significant contribution to diagnostic nuclear medicine. In the area of regional assessment of pulmonary function, 133 Xe has had its greatest clinical impact. Following a breath of 133 Xe gas, pulmonary ventilation can be measured using a scintillation camera or other appropriate radiation detector. If 133 Xe dissolved in saline is injected intravenously, both pulmonary capillary perfusion and ventilation can be measured since 90 percent of the highly insoluble xenon escapes into the alveoli during the first passage through the lungs. Radionuclide pulmonary function tests provide the first qualitative means of assessing lung ventilation and blood flow on a regional basis, and have recently been extended to include quantification of various parameters of lung function by means of a small computer interfaced to the scintillation camera. 133 Xe is also used in the measurement of organ blood flow following injection into a vessel leading into an organ such as the brain, heart kidneys, or muscles

  7. Emission and Sink of Greenhouse Gases in Soils of Moscow

    Science.gov (United States)

    Mozharova, N. V.; Kulachkova, S. A.; Lebed'-Sharlevich, Ya. I.

    2018-03-01

    The first inventory and zoning of the emission and sink of methane and carbon dioxide in the urban structure of greenhouse gases from soils and surface technogenic formations (STFs) (Technosols) on technogenic, recrementogenic, and natural sediments have been performed with consideration for the global warming potential under conditions of different formation rate of these gases, underflooding, and sealing. From gas geochemical criteria and anthropogenic pedogenesis features, the main sources of greenhouse gases, their intensity, and mass emission were revealed. The mass fractions of emissions from the sectors of waste and land use in the inventories of greenhouse gas emissions have been determined. New sources of gas emission have been revealed in the first sector, the emissions from which add tens of percent to the literature and state reports. In the second sector, emissions exceed the available data in 70 times. Estimation criteria based on the degree of manifestation and chemical composition of soil-geochemical anomalies and barrier capacities have been proposed. The sink of greenhouse gases from the atmosphere and the internal (latent) sink of methane in soils and STFs have been determined. Ecological functions of soils and STFs have been shown, and the share of latent methane sink has been calculated. The bacterial oxidation of methane in soils and STFs exceeds its emission to the atmosphere in almost hundred times.

  8. Energy efficiency and greenhouse gases

    International Nuclear Information System (INIS)

    Hamburg, A.; Martins, A.; Pesur, A.; Roos, I.

    1996-01-01

    Estonia's energy balance for 1990 - 1994 is characterized by the dramatic changes in the economy after regaining independence in 1991. In 1990 - 1993, primary energy supply decreased about 1.9 times. The reasons were a sharp decrease in exports of electric energy and industrial products, a steep increase in fuel prices and the transition from the planned to a market-oriented economy. Over the same period, the total amount of emitted greenhouse gases decreased about 45%. In 1993, the decrease in energy production and consumption stopped, and in 1994, a moderate increase occurred (about 6%), which is a proof stabilizing economy. Oil shale power engineering will remain the prevailing energy resource for the next 20 - 25 years. After stabilization, the use of oil shale will rise in Estonia's economy. Oil shale combustion in power plants will be the greatest source of greenhouse gases emissions in near future. The main problem is to decrease the share of CO 2 emissions from the decomposition of carbonate part of oil shale. This can be done by separating limestone particles from oil shale before its burning by use of circulating fluidized bed combustion technology. Higher efficiency of oil shale power plants facilitates the reduction of CO 2 emissions per generated MWh electricity considerably. The prognoses for the future development of power engineering depend essentially on the environmental requirements. Under the highly restricted development scenario, which includes strict limitations to emissions (CO 2 , SO 2 , thermal waste) and a severe penalty system, the competitiveness of nuclear power will increase. The conceptual steps taken by the Estonian energy management should be in compliance with those of neighboring countries, including the development programs of the other Baltic states

  9. The determination by irradiation with a pulsed neutron generator and delayed neutron counting of the amount of fissile material present in a sample; Determination de la quantite de matiere fissile presente dans un echantillon par irradiation au moyen d'une source pulsee de neutrons et comptage des neutrons retardes

    Energy Technology Data Exchange (ETDEWEB)

    Beliard, L; Janot, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    A preliminary study was conducted to determine the amount of fissile material present in a sample. The method used consisted in irradiating the sample by means of a pulsed neutron generator and delayed neutron counting. Results show the validity of this method provided some experimental precautions are taken. Checking on the residual proportion of fissile material in leached hulls seems possible. (authors) [French] Ce rapport rend compte d'une etude preliminaire effectuee en vue de determiner la quantite de matiere fissile presente dans un echantillon. La methode utilisee consiste a irradier l'echantillon considere au moyen d'une source puisee de neutrons et a compter les neutrons retardes produits. Les resultats obtenus permettent de conclure a la validite de la methode moyennant certaines precautions. Un controle de la teneur residuelle en matiere fissile des gaines apres traitement semble possible. (auteurs)

  10. Contribution des radios communautaires a l'education des ...

    African Journals Online (AJOL)

    Contribution des radios communautaires a l'education des populations rurales pour un developpement durable au Benin: etude de cas. ... Journal de la Recherche Scientifique de l'Université de Lomé. Journal Home · ABOUT THIS JOURNAL ...

  11. La convergence des rôles respectifs des relationnistes et des journalistes influence-t-elle la perception qu'ils ont les uns des autres?

    DEFF Research Database (Denmark)

    Valentini, Chiara

    2017-01-01

    la convergence des rôles respectifs des praticiens des relations publiques et des journalistes a un effet favorable sur la perception qu’ils ont les uns des autres. L’effet est plus marqué chez les praticiens des relations publiques, car leur vision de la profession en journalisme correspond à celle...

  12. Gas Well Testing Analysis Using Finite-Difference Models and Optimization Techniques Analyse d'essais de puits de gaz par des modèles utilisant la méthode des différences finies et par des techniques d'optimisation

    Directory of Open Access Journals (Sweden)

    Darderes E. A.

    2006-11-01

    Full Text Available In reservoir engineering studies of gas fields, three important parameters are needed: the permeability-thickness product, the skin factor, and the inertial-turbulent factor. Several methods have been proposed to determine these parameters from gas well tests. The most powerful one is the pseudo-steady state analysis, where a linear dependence on a semilogarithmic plot is found between the real gas pseudo-pressure and time. Another one is the type-curve matching. Both have drawbacks because they can be rigorously applied only to specific cases. An automated type-curve match, which provides a general method to analyze well test data, is presented in this paper. It is based on the adjustment of a numerical model to gas well test data, by means of optimization techniques. The numerical model is the solution of the second order strongly non-linear partial differential equation which rules the radial flow of real gases towards a well. The differential equation is solved by finite-differences, taking into account the variation of gas properties with pressure. In order to simulate any gas well test, appropriate initial and boundary conditions are imposed. The least squares method is used to minimize residual differences between actual pressures measured during test and computed pressures. Two optimization techniques are applied to obtain the best estimate of parameters that minimize the sum of the square of the residuals: the univariate method of Fibonacci [1] and the multivariate method of Marquardt [1, 2]. This procedure is applied to a single-rate and a two-rate drawdown test. Numerical results showed excellent agreement with well test data. Les études de gisements de gaz rendent indispensables la connaissance de trois paramètres importants : la capacité de flux (produit de la perméabilité par l'épaisseur de la couche productrice, l'effet de peau et le facteur d'inertie et de turbulence. On connaît plusieurs méthodes pour déterminer ces

  13. Promouvoir l'entrepreneuriat inclusif des jeunes et des femmes ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Le projet vise à analyser la contribution réelle et potentielle de l'entrepreneuriat inclusif au bien-être des jeunes et des femmes en Côte d'Ivoire, au Burkina Faso et au Kenya. Après un état des lieux de la pratique de l'entrepreneuriat inclusif dans chacun des pays ciblés, l'équipe de recherche étudiera son incidence sur ...

  14. Technical note concerning the use of cellulose ester filtering membranes in the determination of plutonium in urine; Note technique sur l'utilisation des membranes filtrantes d'esters de cellulose dans le dosage du plutonium dans les urines

    Energy Technology Data Exchange (ETDEWEB)

    Harduin, J C; Montels, P [Commissariat a l' Energie Atomique, la Hague (France)

    1968-07-01

    During the last stage of the determination of plutonium in biological media, cellulose ester filtering membranes are used for collecting, with the help of a special device, the very fine precipitate resulting from the co-precipitation of plutonium and lanthanum fluorides. The membranes are then dried, and stuck on to flat watch-glasses for a {alpha} counting. A method is then given for purifying the lanthanum so as to keep the background noise during counting as low as possible. (author) [French] Dans la phase terminale du dosage du plutonium dans les milieux biologiques, on utilise les membranes filtrantes d'esters de cellulose pour recueillir, a l'aide d'un dispositif particulier, le precipite tres tenu resultant de la co-precipitation plutonium-lanthane sous forme de fluorure - Les membranes sont ensuite sechees puis collees sur verre de montre plat avant d'etre passees au compteur alpha. Un mode de purification du lanthane est ensuite donne afin de ne pas augmenter le bruit de fond des appareils de comptage. (auteur)

  15. On the determination of track parameters with the forward drift chambers of the ZEUS detector. Zur Bestimmung von Spurparametern mit den Vorwaertsdriftkammern des ZEUS-Detektors

    Energy Technology Data Exchange (ETDEWEB)

    Guenzel, T F

    1989-01-01

    The ep-collider HERA at DESY in Hamburg will probe unexplored kinematical regions of the deep-inelastic electron-proton-scattering. The ZEUS-Collaboration develops a detector to study the physical interactions of the incoming particles. Among the requirements of the ZEUS-detector a good momentum resolution of the particle tracks in the inner detector resp. forward tracking detector (FTD) is necessary. The behaviour of the tracks in the forward tracking detector is determined by the lorentzboost ({beta}=0.93) in forward direction and by the inhomogeneous magnetic field in the FTD, which is mainly parallel to the beampipe-axis. In this thesis all studies regard only the FTD (not including VXD or CTD) for the momentum determination. Two scenarios are considered to determine the limits of momentum measurability in the FTD. The results show that the determination of the momentum in the FTD is only possible with the (exact) knowledge of the vertex position, where the tracks come from. The functional dependence of the track parameters at the vertex on the track parameters at the first FTD-module was intensively studied. Disconnected ambiguities are not found. A track model for tracks in the FTD is developed without regarding multiple scattering. The momentum determination of a track is mainly based on the track part between the first FTD-module and the vertex. A momentum resolution of {sigma}p/P=0.008 P-0.0025 P can be achieved depending on the polar angle (relative to the beampipe-axis) of the track at the vertex. Finally the influence of the multiple scattering between the first FTD-module and the vertex on the momentum resolution is estimated. The increase of the dead material for small polar angles restricts the area of acceptable momentum resolution to polar angles of {lambda}>180 mrad. (orig.).

  16. La fabrique des sciences des institutions aux pratiques

    CERN Document Server

    Benninghoff, Martin; Crettaz von Roten, Fabienne; Merz, Martina

    2006-01-01

    Aujourd'hui, les façons de produire, d'organiser, d'évaluer et d'utiliser les savoirs sont en profond débat. De plus en plus, l'Etat, la société civile et l'économie tentent d'influencer les activités des universités et des laboratoires de recherche. Ces développements mettent à l'épreuve tout à la fois les fondements des systèmes d'enseignement supérieur et de recherche, l'autonomie des institutions scientifiques, la définition des frontières des savoirs et l'acceptation des sciences. Dans des contextes suisses et européens, cet ouvrage s'intéresse aux manières dont les sciences et les technologies sont fabriquées, en analysant leurs institutions et les pratiques. A partir d'une approche relationnelle, les sciences et les technologies sont conçues comme des phénomènes profondément sociaux, culturels et politiques. Une telle démarche déstabilise les visions parfois idéalisées et stéréotypées de la construction des savoirs. Des études de cas détaillées décrivent des phénomè...

  17. Effets des extraits vegetaux sur la dynamique de populations des ...

    African Journals Online (AJOL)

    La présente étude se propose de trouver une alternative de l'utilisation des pesticides chimiques en testant l'effet insecticide des extraits aqueux des feuilles de Hyptis suaveolens, graines de Ricinus communis et de Azadirachta indica contre les ravageurs du niébé en conditions de champ en utilisant le cyperméthrine ...

  18. Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians

    Science.gov (United States)

    Kotarba, M.J.; Curtis, John B.; Lewan, M.D.

    2009-01-01

    kerogen less enriched in 13C. The typically assumed linear trend for ??13C of methane, ethane and propane versus their reciprocal carbon number for a single sourced natural gas is not observed in the experimental gases. Instead, the so-called "dogleg" trend, exemplified by relatively 13C depleted methane and enriched propane as compared to ethane, is observed for all the kerogen types and at both experimental conditions. Three of the natural gases from the same thrust unit had similar "dogleg" trends indicative of Menilite source rocks with Type III kerogen. These natural gases also contained varying amounts of a microbial gas component that was approximated using the ????13C for methane and propane determined from the experiments. These approximations gave microbial methane components that ranged from 13-84%. The high input of microbial gas was reflected in the higher gas:oil ratios for Outer Carpathian production (115-1568 Nm3/t) compared with those determined from the experiments (65-302 Nm3/t). Two natural gas samples in the far western part of the study area had more linear trends that suggest a different organic facies of the Menilite Shales or a completely different source. This situation emphasizes the importance of conducting hydrous pyrolysis on samples representing the complete stratigraphic and lateral extent of potential source rocks in determining specific genetic gas correlations. ?? 2009 Elsevier Ltd.

  19. Determination on Mice and other Organisms of the RBE of High-Energy Protons and Electrons; Efficacite Biologique Relative sur la Souris et d'Autres Organismes des Protons et des Electrons De Haute Energie; Opredelenie obeh pri obluchenii myshej i drugikh organizmov protonami i ehlektronami vysokikh ehnergij; Determinacion de la Eficacia Biologica Relativa de los Protones y de los Electrones de Elevada Emergia en el Raton y en Otros Organismos

    Energy Technology Data Exchange (ETDEWEB)

    Bonet-Maury, P.; Baarli, J.; Kahn, T.; Dardenne, G.; Frilley, M.; Deysine, A. [Institut du Radium, Paris (France)

    1964-03-15

    The general effects of 157- and 592-MeV protons and 150- and 950-MeV electrons were observed on mice exposed to lethal doses of whole-body irradiation. The irradiated animals displayed the same general symptoms as those produced by X - or gamma-rays. The biological tests did not bring to light any particular phenomenon which can be considered as characteristic of these high-energy particles. As determined in four tests (LD{sub 50}, average expectation of life and diminution of thymus and testicles), the RBE is close to 1. This corresponds to the mean LET of the particles and, in the case of the protons, does not appear to be increased by the higher local LET of the spallation fragments. (author) [French] Les effets generaux des protons de 157 et 592 MeV et des electrons de 150 et 950 MeV oiit ete observes sur des souris irradiees in toto, a des doses letales. Les animaux irradies presentent les memes symptomes generaux que ceux produits par les rayonnements de reference X ou {gamma}. Aucun phenomene caracteristique de ces particules de haute energie n'a pu etre mis en evidence avec les tests biologiques choisis. Lfefficacite biologique relative determinee sur 4 tests (DL{sub 50}, survie moyenne, reduction du thymus et des testicules) est peu differente de 1; cette EBR correspond au TEL moyen des particules et, pour les protons, ne parait pas augmentee par le TEL local plus eleve des etoiles de spallation. (author) [Spanish] Se han observado los efectos generales de los protones de 157 y 592 MeV y de los electrones de 150 y 950 MeV sobre ratones expuestos in toto, a dosis letales de radiaciones. Los animales irradiados presentan los mismos sintomas generales que los producidos por los rayos X o los rayos gamma adoptados como radiaciones de referencia. Los ensayos biologicos llevados a cabo no han puesto de manifiesto ningun fenomeno caracteristico de la accion de estas particulas de elevada energia. La eficacia biologica relativa determinada en cuatro ensayo (DL

  20. Development of a method to determine the nuclide inventory in bituminized waste packages; Entwicklung eines Verfahrens zur Bestimmung des Nuklidinventars in bituminierten Abfallgebinden

    Energy Technology Data Exchange (ETDEWEB)

    Mesalic, E.; Kortman, F.; Lierse von Gostomski, C. [Technische Univ. Muenchen, Garching (Germany). Zentrale Technisch-Wissenschaftliche Betriebseinheit Radiochemie Muenchen (RCM)

    2014-01-15

    Until the 1980s, bitumen was used as a conditioning agent for weak to medium radioactive liquid waste. Its use can be ascribed mainly to the properties that indicated that the matrix was optimal. However, fires broke out repeatedly during the conditioning process, so that the method is meanwhile no longer permitted in Germany. There are an estimated 100 waste packages held by the public authorities in Germany that require a supplementary declaration. In contrast to the common matrices, such as for example resins or sludges, there is still no standardized technology for taking samples and subsequently determining the radio-nuclide for bitumen. Aspects, such as the thermoplastic behaviour, make determining the nuclide inventory more difficult in bituminized waste packages. The development of a standardized technology to take samples with a subsequent determination of the radio-nuclide analysis is the objective of a project funded by the BMBF. Known, new methods, specially developed for the project, are examined on inactive bitumen samples and then transferred to active samples. At first non-destructive methods are used. The resulting information forms an important basis to work out and apply destructive strategy for sampling and analysis. Since the project is on-going, this report can only address the development of the sampling process. By developing a sampling system, it will be possible to take samples from an arbitrary selected location of the package across the entire matrix level and thus gain representative analysis material. The process is currently being optimized. (orig.)

  1. Specific heats of degenerate ideal gases

    OpenAIRE

    Caruso, Francisco; Oguri, Vitor; Silveira, Felipe

    2017-01-01

    From arguments based on Heisenberg's uncertainty principle and Pauli's exclusion principle, the molar specific heats of degenerate ideal gases at low temperatures are estimated, giving rise to values consistent with the Nerst-Planck Principle (third law of Thermodynamics). The Bose-Einstein condensation phenomenon based on the behavior of specific heat of massive and non-relativistic boson gases is also presented.

  2. Method for storing radioactive rare gases

    International Nuclear Information System (INIS)

    Watabe, Atsushi; Nagao, Hiroyuki; Takiguchi, Yukio; Kanazawa, Toshio; Soya, Masataka.

    1975-01-01

    Object: To safely and securely store radioactive rare gases for a long period of time. Structure: The waste gases produced in nuclear power plant are cooled by a cooler and then introduced into a low temperature adsorbing device so that the gases are adsorbed by adsorbents, and then discharged into atmosphere through the purifying gas discharge line. When the radioactive rare gases reach a level of saturation in the amount of adsorption, they are heated and extracted by a suction pump and heated by a heater. The gases are then introduced into an oxygen-impurity removing device and the purified rare gases containing no oxygen and impurities are cooled by a cooler and fed into a gas holder. When the amount of radioactive rare gases stored within the gas holder reaches a given level, they are compressed and sealed by a compressure into a storing cylinder and residual gases in the piping are sucked and recovered into the gas holder, after which the cylinder is removed and stored in a fixed room. (Kamimura, M.)

  3. Explorative analysis of microbes, colloids and gases

    Energy Technology Data Exchange (ETDEWEB)

    Hallbeck, Lotta; Pedersen, Karsten (Microbial Analytics Sweden AB, Goeteborg (Sweden))

    2008-08-15

    potential to transport radionuclides in groundwater. The aim of the study of colloids in the Forsmark 2.3 site investigation was to quantify and determine the composition of colloids in groundwater samples from the boreholes. There are both inorganic and organic colloids, and the site investigation measured both types. - Gases (Chapter 3): Dissolved gases in groundwater contribute to the mass of dissolved species. The distribution and composition of dissolved gases in deep groundwater are important to understand in the safety assessment of a deep geological nuclear waste repository: Micro bubbles of gas may potentially transport radionuclides from the repository to the surface. Oxygen, hydrogen sulphide and carbon dioxide are parts of fundamental redox couples that participate in several solid-aqueous phase transformations such as the precipitation of ferric iron oxides, iron sulphide and calcite. Methane and hydrogen, may serve as sources of energy to various microbiological processes

  4. Explorative analysis of microbes, colloids and gases

    International Nuclear Information System (INIS)

    Hallbeck, Lotta; Pedersen, Karsten

    2008-08-01

    radionuclides in groundwater. The aim of the study of colloids in the Forsmark 2.3 site investigation was to quantify and determine the composition of colloids in groundwater samples from the boreholes. There are both inorganic and organic colloids, and the site investigation measured both types. - Gases (Chapter 3): Dissolved gases in groundwater contribute to the mass of dissolved species. The distribution and composition of dissolved gases in deep groundwater are important to understand in the safety assessment of a deep geological nuclear waste repository: Micro bubbles of gas may potentially transport radionuclides from the repository to the surface. Oxygen, hydrogen sulphide and carbon dioxide are parts of fundamental redox couples that participate in several solid-aqueous phase transformations such as the precipitation of ferric iron oxides, iron sulphide and calcite. Methane and hydrogen, may serve as sources of energy to various microbiological processes

  5. Impact Delivery of Reduced Greenhouse Gases on Early Mars

    Science.gov (United States)

    Haberle, R. M.; Zahnle, K. J.; Barlow, N. G.

    2017-12-01

    Reducing greenhouse gases are the latest trend in finding solutions to the early Mars climate dilemma. In thick CO2 atmospheres with modest concentrations of H2 and/or CH4, collision induced absorptions can reduce the outgoing long wave radiation enough to provide a significant greenhouse effect. To raise surface temperatures significantly by this process, surface pressures must be at least 500 mb and H2 and/or CH4 concentrations must be at or above the several percent level. Volcanism, serpentinization, and impacts are possible sources for reduced gases. Here we investigate the delivery of such gases by impact degassing from comets and asteroids. We use a time-marching stochastic impactor model that reproduces the observed crater size frequency distribution of Noachian surfaces. Following each impact, reduced gases are added to the atmosphere from a production function based on gas equilibrium calculations for several classes of meteorites and comets at typical post-impact temperatures. Escape and photochemistry then remove the reduced greenhouse gases continuously in time throughout each simulation. We then conduct an ensemble of simulations with this simple model varying the surface pressure, impact history, reduced gas production and escape functions, and mix of impactor types, to determine if this could be a potentially important part of the early Mars story. Our goal is to determine the duration of impact events that elevate reduced gas concentrations to significant levels and the total time of such events throughout the Noachian. Our initial simulations indicate that large impactors can raise H2 concentrations above the 10% level - a level high enough for a very strong greenhouse effect in a 1 bar CO2 atmosphere - for millions of years, and that the total time spent at or above that level can be in the 10's of millions of years range. These are interesting results that we plan to explore more thoroughly for the meeting.

  6. Method of contacting solids and gases

    Energy Technology Data Exchange (ETDEWEB)

    1942-08-06

    A continuous method is described for contacting solids and gases. The process involves passing a confined stream of gases through an extended path including a treating zone and imposing a pressure on the stream of gases at least sufficient to overcome the resistence of said path to the flow of said gases. A solid in finely divided form is then introduced into said stream of gases, maintaining a vertical column of finely divided solid in fluidized state of a height which will produce a pressure at the column bottom at least equal to the gas pressure at the point of entry of the solids into the stream. The solids then pass from the bottom of the column into the stream.

  7. Charte du Conseil des Gouverneurs

    International Development Research Centre (IDRC) Digital Library (Canada)

    Office 2004 Test Drive User

    7. favoriser des communications ouvertes et franches entre le personnel, la direction ..... de dresser le procès-verbal des réunions du Conseil et de ses comités et de veiller à ce ... et des résultats qu'il obtient, et non de sa gestion quotidienne.

  8. Impact of solute concentration on the electrocatalytic conversion of dissolved gases in buffered solutions

    KAUST Repository

    Shinagawa, Tatsuya; Takanabe, Kazuhiro

    2015-01-01

    . These alterations of the electrolyte properties associated with the solute concentration are universally applicable to other aqueous gas-related electrochemical reactions because the currents are purely determined by mass transfer of the dissolved gases. © 2015

  9. Dosage direct des alcools dans les carburols par chromatographie en phase gazeuse Direct Gas Chromatographie Determination of Alcohols in Gasolines Blended by Oxygenated Compounds

    Directory of Open Access Journals (Sweden)

    Petroff N.

    2006-11-01

    Full Text Available Dans cette étude, on décrit une méthode de chromatographie en phase gazeuse utilisant une colonne remplie ; elle permet de doser, sans préfractionnement, les alcools jusqu'aux butanols dans les carburols (carburants additionnés de composés oxygénés. La phase stationnaire sélectionnée est le glycérol. This report describes a gas chromatographie method using a packed column. It allows the direct determination of alcohols up to butanols in gasolines blended with oxygenated compounds without prefractionation. Glycerol has been selected as stationary phase.

  10. Le statut vitaminique des individus et des populations…

    Directory of Open Access Journals (Sweden)

    Icart Jean-Claude

    2000-05-01

    Full Text Available Comme le souligne un récent rapport du Haut comité de santé publique, le statut vitaminique des individus et des populations demeure une question d’actualité. Si les études ne révèlent plus de signes évocateurs de carence, au plus des problèmes de déficiences pour certains groupes à risque, des interrogations, demeurent malgré le contexte d’abondance, concernant la couverture des besoins, laquelle pourrait s’avérer inférieure aux valeurs considérées comme satisfaisantes.

  11. Les lueurs des sables

    CERN Multimedia

    Les lueurs des sables

    2013-01-01

    Two CERN ladies are getting ready for the “Trophée Roses des Sables” rally adventure: Julie and Laetitia are finalizing the last details before setting off on Monday 7th October 2013. Julie from EN-MEF group and Laetitia from DGS-SEE group, met at the CERN Rugby club. This year, they are participating in the 100 % female rally which will take place in Morocco from 10 to 20 October. They will be carrying along 100 kg of humanitarian donation for children such as some clothes, books and medical material. Do not hesitate to show your support at their farewell party to be held on Monday 7 October, from 4 to 6 pm in front of the St Genis-Pouilly Mairie (city Hall). Follow their exciting adventure on the blog leslueursdessables.trophee-roses-des-sables.org and on their association’s Facebook page Les Lueurs des Sables.

  12. Liste des auteurs

    OpenAIRE

    2016-01-01

    Madeleine Akrich      Ecole des Mines – Centre de Sociologie de l’innovation – Paris Noël Barbe      Association comtoise des Arts et Traditions populaires – Besançon Lucien Bernot      Ecole des hautes études en sciences sociales (EHESS) – Paris Anni Borzeix      Centre national de la recherche scientifique (CNRS) –     Groupement d’intérêt public (GIP) « Mutations industrielles » – Paris François Boudarias      Laboratoire d’Anthropologie et de sociologie de Tours (LAST) Dominique Boullier ...

  13. Combined novel methods for the determination of the humidification conditions of polymer electrolyte fuel cells; Kombination neuer Methoden zur Bestimmung des Wasserhaushaltes von Polymer-Elektrolyt-Brennstoffzellen

    Energy Technology Data Exchange (ETDEWEB)

    Kuhn, Robert Martin

    2011-05-02

    The water management is one of the key factors for the performance of a low temperature PEM fuel cell. With respect to the optimization of the fuel cell operation it is important to detect and differentiate water in the membrane, in the gas diffusion layer (GDL) and excess water in the flow field channel. The water content of each component influences the performance in different ways and adapted operation modes have to be kept. This work entitled 'Combined novel methods for the determination of the humidification conditions of PEM fuel cells' provides techniques and guidelines for fuel cell operation and will conclude in a straightforward control and operation strategy. Based on a combination of electrochemical impedance spectroscopy (EIS), locally resolved current distribution measurements and neutron radiography an informative basis for the determination of the water content of an operating PEM fuel cell is created. Special attention has been paid to the reproducibility and comparability in order to set up a consistent investigation and control strategy. (orig.)

  14. Composition of lunar noble gases traped 2.5 AE and 3.5 AE ago

    International Nuclear Information System (INIS)

    Eugster, O.

    1986-01-01

    The times when the soils 74001 and 73261 were exposed on the lunar surface were determined by the U-235 - Xe-136 dating method. The isotopic composition of the trapped noble gases in these two soils is compared with that of the surface correlated noble gases in the young soils 12001 and in the present day solar wind. The surface correlated trapped gases are a mixture of implanted solar wind particles and retrapped lunar atmospheric gases. The observed changes are interpreted as a result of decreasing outgassing of radiogenic Ar-40 and perhaps He-4 and of fissiogenic Xe from the lunar crust. The old soils probably also contain surface correlated Kr-80 and Kr-82 produced by secondary cosmic ray neutron capture of adsorbed or retrapped bromine. To some extent the isotopic composition of the trapped gases in old lunar soil may also have been altered due to diffusion loss from material of low retentivity

  15. Stress analysis of the O-element pipe during the process of flue gases purification

    Directory of Open Access Journals (Sweden)

    Nekvasil R.

    2008-11-01

    Full Text Available Equipment for flue gases purification from undesired substances is used throughout power and other types of industry. This paper deals with damaging of the O-element pipe designed to remove sulphur from the flue gases, i.e. damaging of the pipe during flue gases purification. This purification is conducted by spraying the water into the O-shaped pipe where the flue gases flow. Thus the sulphur binds itself onto the water and gets removed from the flue gas. Injection of cold water into hot flue gases, however, causes high stress on the inside of the pipe, which can gradually damage the O-element pipe. In this paper initial injection of water into hot pipe all the way to stabilization of temperature fields will be analyzed and the most dangerous places which shall be considered for fatigue will be determined.

  16. Kinetic Theory of Granular Gases

    Energy Technology Data Exchange (ETDEWEB)

    Trizac, Emmanuel [Center of Theoretical Biological Physics, UC San Diego, La Jolla, CA 92093-0374 (United States); Laboratoire de Physique Theorique et Modeles Statistiques, Campus Universitaire, 91405 Orsay (France)

    2005-11-25

    Granular gases are composed of macroscopic bodies kept in motion by an external energy source such as a violent shaking. The behaviour of such systems is quantitatively different from that of ordinary molecular gases: due to the size of the constituents, external fields have a stronger effect on the dynamics and, more importantly, the kinetic energy of the gas is no longer a conserved quantity. The key role of the inelasticity of collisions has been correctly appreciated for about fifteen years, and the ensuing consequences in terms of phase behaviour or transport properties studied in an increasing and now vast body of literature. The purpose of this book is to help the newcomer to the field in acquiring the essential theoretical tools together with some numerical techniques. As emphasized by the authors-who were among the pioneers in the domain- the content could be covered in a one semester course for advanced undergraduates, or it could be incorporated in a more general course dealing with the statistical mechanics of dissipative systems. The book is self-contained, clear, and avoids mathematical complications. In order to elucidate the main physical ideas, heuristic points of views are sometimes preferred to a more rigorous route that would lead to a longer discussion. The 28 chapters are short; they offer exercises and worked examples, solved at the end of the book. Each part is supplemented with a relevant foreword and a useful summary including take-home messages. The editorial work is of good quality, with very few typographical errors. In spite of the title, kinetic theory stricto sensu is not the crux of the matter covered. The authors discuss the consequences of the molecular chaos assumption both at the individual particle level and in terms of collective behaviour. The first part of the book addresses the mechanics of grain collisions. It is emphasized that considering the coefficient of restitution {epsilon} -a central quantity governing the

  17. Kinetic Theory of Granular Gases

    International Nuclear Information System (INIS)

    Trizac, Emmanuel

    2005-01-01

    Granular gases are composed of macroscopic bodies kept in motion by an external energy source such as a violent shaking. The behaviour of such systems is quantitatively different from that of ordinary molecular gases: due to the size of the constituents, external fields have a stronger effect on the dynamics and, more importantly, the kinetic energy of the gas is no longer a conserved quantity. The key role of the inelasticity of collisions has been correctly appreciated for about fifteen years, and the ensuing consequences in terms of phase behaviour or transport properties studied in an increasing and now vast body of literature. The purpose of this book is to help the newcomer to the field in acquiring the essential theoretical tools together with some numerical techniques. As emphasized by the authors-who were among the pioneers in the domain- the content could be covered in a one semester course for advanced undergraduates, or it could be incorporated in a more general course dealing with the statistical mechanics of dissipative systems. The book is self-contained, clear, and avoids mathematical complications. In order to elucidate the main physical ideas, heuristic points of views are sometimes preferred to a more rigorous route that would lead to a longer discussion. The 28 chapters are short; they offer exercises and worked examples, solved at the end of the book. Each part is supplemented with a relevant foreword and a useful summary including take-home messages. The editorial work is of good quality, with very few typographical errors. In spite of the title, kinetic theory stricto sensu is not the crux of the matter covered. The authors discuss the consequences of the molecular chaos assumption both at the individual particle level and in terms of collective behaviour. The first part of the book addresses the mechanics of grain collisions. It is emphasized that considering the coefficient of restitution ε -a central quantity governing the inelasticity of

  18. The storage of greenhouse gases

    International Nuclear Information System (INIS)

    Herzog, H.; Kaarstad, O.; Eliasson, B

    2000-01-01

    Since 1850, that is to say the beginning of the industrial era,the concentration of carbon dioxide in the atmosphere has risen from 280 ppm to 370 ppm, this increase is mainly due to the combustion of fossil fuels. Today fossil fuels represent 85% of all the energy used in the world. Fearing progressive climatic changes, more and more governments become aware of the necessity of reducing the emission of greenhouse gases. A more efficient use of energy and the promoting of renewable energies and of the nuclear energy are the most evident solutions but they appear to be insufficient. A third solution is the storage of carbon dioxide in geological layers. This technique has been put into use since 1996 in Norway. An off-shore natural gas platform injects carbon dioxide in a geological reservoir situated 1000 meters below the ocean bed. The injection of CO 2 could be used in oil fields in order to facilitate the extraction of petroleum. Far more large and efficient reservoirs would be the oceans, they already hold up 40000 10 9 tons of dissolved CO 2 . Even if the double of the carbon dioxide accumulated in the atmosphere since 1850 were injected, the concentration of carbon in sea waters would rise by less than 2%. The safety of CO 2 storage and the impact on the environment of ocean injection sites are being studied. (A.C.)

  19. Greenhouse gases and emissions trading

    International Nuclear Information System (INIS)

    LeBlanc, A.; Dudek, D.J.

    1993-01-01

    Global cooperation is essential in cutting greenhouse-gas emissions, say Alice LeBlanc and Daniel J. Dudek of the Environmental Defense in New York City. The first step, they continue, is agreement among nations on an overall global limit for all greenhouse gases, followed by an allocation of the global limit among nations. The agreements must contain effective reporting and monitoring systems and enforcement provisions, they add. The Framework Convention on Climate Change, signed by most nations of the world in Brazil in 1992, provides the foundation for such an agreement, LeBlanc and Dudek note. open-quotes International emissions trading is a way to lower costs and expand reduction options for the benefit of all,close quotes they contend. Under such an arrangement, an international agency would assign allowances, stated in tons of carbon dioxide. Countries would be free to buy and sell allowances, but no country could exceed, in a given year, the total allowances it holds. By emitting less than its allowed amount, a country would accumulate more allowances, which it could sell. The authors claim such a system would offer benefits to the world economy by saving billions of dollars in pollution-reduction costs while still achieving emission limits established in an international agreement

  20. Etude theorique et experimentale des evaporateurs de dioxyde de carbone operant dans des conditions de givrage

    Science.gov (United States)

    Bendaoud, Adlane Larbi

    frigorifique moyenne superieures de 20 % par rapport a celle du cas de base. 3. la diminution de la temperature de l'air a l'entree du serpentin entraine une diminution du temps de fonctionnement et augmente la frequence de degivrage alors que la diminution de l'humidite relative de l'air a l'entree augmente le temps de fonctionnement et reduis la frequence de degivrage. 4. le debit massique de l'air est un parametre tres important qu'il faut choisir et determiner avec beaucoup de soin afin de ne pas serieusement affecter le temps de fonctionnement du serpentin. Les resultats issus de ce travail de recherche ont fait l'objet de trois publications dans des revues internationales [4-6] et de deux presentations dans des conferences specialisees [7,8]. (Abstract shortened by UMI.)

  1. Studies on the gamma-gamma method. Definition of an apparatus for on-the-spot measurement of uranium ore densities; Etudes sur la methode gamma-gamma. Determination d'un appareillage pour la mesure en place de la densite des minerais d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Czubek, J A [Institut de Recheches Nucleaires, Dept. 6, Cracovie (Poland); Guitton, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-07-01

    The work described follows on to the research published in report CEA-R--2720 in march 1965. It includes: - experimental results obtained with a model composed of a constant density material (graphite); - the drawing-up of calibration curves using the similitude principle; - determination of the characteristics of a gamma-gamma probe, together with a discussion. The influence is studied of a certain number of parameters on the shape of the energy spectra of scattered radiation, and of the calibration curves: nature of the radioactive source, diameter of the probe area, source detector distance, geometrical shape of shielding between the source and the detector. An attempt is made to find a mathematical model for the calibration curve, for given conditions. Numerical applications make it possible to establish the optimum technical characteristics for a probe measuring the density with the smallest statistical error. (authors) [French] Les travaux decrits font suite aux etudes presentees dans le rapport CEA-R--2720 de mars 1965. Ils portent sur: - les resultats experimentaux obtenus sur un modele constitue d'un materiau de densite constante (graphite) ; - l'etablissement de courbes d'etalonnage a l'aide du principe de similitude; - la recherche et la discussion des caracteristiques d'une sonde gamma-gamma. L'influence d'un certain nombre de parametres sur la forme des spectres d'energie du rayonnement diffuse et des courbes d'etalonnage est etudiee: nature de la source radioactive, diametre du sondage, distance source-detecteur, forme geometrique du blindage entre la source et le detecteur. Pour des conditions determinees, le modele mathematique de la courbe d'etalonnage est recherche. Des applications numeriques permettent d'etablir les caracteristiques techniques optimales d'une sonde mesurant la densite avec la plus faible erreur statistique. (auteurs)

  2. Évaluation des pratiques agricoles des légumes feuilles : le cas des ...

    African Journals Online (AJOL)

    Face à ce constat, le défi de la recherche serait la détermination du niveau actuel de contamination des légumes feuilles et des eaux du barrage et celui de l'État serait l'initiation de programmes de sensibilisation des producteurs par rapport à une gestion plus rigoureuse des pesticides. Mots-clés : pratiques paysannes, ...

  3. Tin dioxide: synthesis, characterization and study of the interactions with different polluting gases - application to DeNOx catalysis; Dioxyde d'etain: synthese, caracterisation et etude des interactions avec differents gaz polluants - application a la catalyse DeNOx

    Energy Technology Data Exchange (ETDEWEB)

    Sergent, N.

    2003-01-01

    Two high specific surface area tin dioxides after calcination at 600 degrees C under O{sub 2} have been synthesized: SnO{sub 2}-HNO{sub 3} (24 m{sup 2} g{sup -1}) and SnO{sub 2}-N{sub 2}H{sub 4} (101 m{sup 2} g{sup -1}). The surface of the 600 degrees C - calcined SnO{sub 2}-N{sub 2}H{sub 4} sample was found to be more hydroxylated than the 600 degrees C - calcined SnO{sub 2}-HNO{sub 3} one. The thermal treatment under O{sub 2} involves the formation of mono-ionized oxygen vacancies, leading to non-stoichiometric tin dioxides. A specific treatment like outgassing at temperatures above 300-400 degrees C, was found to be necessary to extract surface oxygen atoms. The CO adsorption at liquid N{sub 2} temperature on the SnO{sub 2}-N{sub 2}H{sub 4} sample has shown the existence of two cationic Sn{sup 4+} sites, having different Lewis acidities. Concerning the surface OH groups, it has been observed: i) hydroxyl which are inaccessible to CO, ii) weakly acidic surface hydroxyl and iii) surface hydroxyl having a weak Broensted acidity. Then, a study of the interactions between the 600 degrees C - calcined SnO{sub 2}-N{sub 2}H{sub 4} sample and various pollutant gases has been carried out by transmission FTIR spectroscopy. Carbon dioxide interacts with SnO{sub 2} surface, leading to CO{sub 2} species adsorbed on cationic sites together with carbonates and bicarbonates ad-species. Carbon monoxide involves the partial reduction of SnO{sub 2} surface by reaction of CO with surface oxygens to form carbonate species and CO{sub 2}. Interactions of SnO{sub 2} surface with NO{sub 2} have shown the formation of NO{sup +}, nitrite and nitrate ad-species. The NO adsorption on SnO{sub 2}-N{sub 2}H{sub 4} have shown the formation of electron donor species (nitrite and nitrate species) together with electron acceptor species (nitrosyl species). Finally, in the Selective Catalytic Reduction (SCR) of NO{sub x} by propene in oxygen excess, SnO{sub 2} was found to be active at high

  4. Development of techniques and models for the determination of redox potentials of saline solutions; Entwicklung von Methoden und Modellen zur Bestimmung des Redoxpotentials salinarer Loesungen

    Energy Technology Data Exchange (ETDEWEB)

    Hagemann, Sven; Bischofer, Barbara; Scharge, Tina; Schoenwiese, Dagmar

    2014-03-15

    The mobility of radionuclides and heavy metals in aqueous systems depends significantly on their oxidation state. Under saline conditions the measurement of pH values and redox potential are distorted/falsified by solution-specific and hardly assessable ion diffusion effects at the reference electrode. The secure prognosis of redox properties is an essential prerequisite for the calculation of the expected heavy metal and radionuclide concentrations in case of a hypothetical solution ingress in an underground disposal facility. The evaluation of the existing data base shows that there are large uncertainties even for the solubility of widespread oxides and oxy-hydroxides like goethite or hematite. The redox properties of natural systems are determined by the solubility of metastable ferrous intermediate products like ferrihydrite, ''green rust'' or jarosite. The work is aimed to establish a consistent data base with information on these phases and ferrous solute species.

  5. Development of techniques and models for the determination of redox potentials of saline solutions; Entwicklung von Methoden und Modellen zur Bestimmung des Redoxpotentials salinarer Loesungen

    Energy Technology Data Exchange (ETDEWEB)

    Hagemann, Sven; Bischofer, Barbara; Scharge, Tina; Schoenwiese, Dagmar

    2014-03-15

    The mobility of radionuclides and heavy metals in aqueous systems depends significantly on their oxidation state. Under saline conditions the measurement of pH values and redox potential are distorted/falsified by solution-specific and hardly assessable ion diffusion effects at the reference electrode. The secure prognosis of redox properties is an essential prerequisite for the calculation of the expected heavy metal and radionuclide concentrations in case of a hypothetical solution ingress in an underground disposal facility. The evaluation of the existing data base shows that there are large uncertainties even for the solubility of widespread oxides and oxy-hydroxides like goethite or hematite. The redox properties of natural systems are determined by the solubility of metastable ferrous intermediate products like ferrihydrite, ''green rust'' or jarosite. The work is aimed to establish a consistent data base with information on these phases and ferrous solute species.

  6. Determination of the Effectiveness of Control Rods in the VVER Reactor Fuel Assemblies; Determination de l'Efficacite des Barres de Reglage dans les Ensembles Combustibles du reacteur VVER; Opredelenie ehffektivnosti reguliruyushchikh sterzhnej v sborkakh reaktora VVEHR; Determinacion de la Eficacia de las Barras de Control en los Conjuntos de Elementos Combustibles del Reactor VVER

    Energy Technology Data Exchange (ETDEWEB)

    Semenov, V. N.; Lunin, G. L.; Komissarov, L. V.; Kamyshan, A. N.; Halizev, V. I.; Andrianov, G. Ja.; Voznesenskij, V. A.; Kuz' micheva, V. A.; Lebedev, V. I. [Ordena Lenina Institut Atomnoj Energii Im. I.V. Kurchatova, Moskva, SSSR (Russian Federation)

    1964-06-15

    The paper describes experiments done in homogeneous mock-ups of the fuel assemblies from the VVER Reactor (at one level of enrichment) to determine the effectiveness of absorbing systems comprising shim fuel assemblies or water cavities and of absorbing rods clad in jackets made of differing materials. The paper also gives data on some experiments that have been done in mock-ups of assemblies with differing levels of enrichment. These experiments make it possible to verify the methods used in calculation and to evaluate the prospects of using them for heterogeneous reactors. (author) [French] Le memoire decrit les experiences qui ont ete faites pour determiner l 'efficacite des absorbants contenus dans les barres de compensation, l'effet cavitaire et l 'efficacite des absorbants gaines de materiaux divers, au moyen d'assemblages homogenes de cartouches de combustible du reacteur VVER (reacteur de puissance ralenti et refroidi a l 'eau ayant le meme taux d'enrichissement. On y trouve en outre des donnees sur certaines experiences executees a l 'aide d'assemblages de cartouches de combustible taux d'enrichissement differents. Ces travaux permettent de verifier la methode de calcul et d'evaluer ses possibilites d'application aux reacteurs non homogenes. (author) [Spanish] Se describen en la memoria experimentos para determinar la eficacia de los materiales absorbentes contenidos en las barras de compensacion, el efecto de cavitacion y la eficacia de los materiales absorbentes revestidos de diversos materiales, realizados con ayuda de los conjuntos homogeneos de elementos combustibles del reactor VVER (reactor de potencia moderado y refrigerado por agua) con un solo grado de enriquecimiento. Ademas, se exponen datos sobre los experimentos efectuados con ayuda de conjuntos de grados de enriquecimientos; variados. Tales experimentos permiten verificar el metodo de calculo teorico, utilizad o y evaluar la posibilidad de aplicarlo a los reactores no homogeneos. (author

  7. Utilization of the noble gases in studies of underground nuclear detonations

    International Nuclear Information System (INIS)

    Smith, C.F.

    1973-01-01

    The Livermore Gas Diagnostics Program employs a number of rare gas isotopes, both stable and radioactive, in its investigations of the phenomenology of underground nuclear detonations. Radioactive gases in a sample are radiochemically purified by elution chromatography, and the separated gases are radioassayed by gamma-ray spectrometry and by internal or thin-window beta proportional counting. Concentrations of the stable gases are determined by mass-spectrometry, following chemical removal of the reactive gases in the sample. The most general application of the noble gases is as device fraction indicators to provide a basis for estimating totals of chimney-gas components. All of the stable rare gases, except argon, have been used as tracers, as have xenon-127 and krypton-85. Argon-37 and krypton-85 have proven to be of particular value in the absence of a good tracer material as reference species for studies of chimney-gas chemistry. The rate of mixing of chimney gases, and the degree to which the sampled gas truly represents the underground gas mixture, can be studied with the aid of the fission-product gases. Radon-222 and helium are released to the cavity from the surrounding rock, and are, therefore, useful in studies of the interaction of the detonation with the surrounding medium

  8. Application des TIC à l'atténuation des effets des catastrophes dans ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'Amérique centrale est souvent aux prises avec des inondations et des ... (SIG) et de traitement des images, afin de cartographier les dangers et de modéliser les ... de l'Institut d'étude du développement international de l'Université McGill.

  9. Emissions of biogenic sulfur gases from northern bogs and fens

    Science.gov (United States)

    Demello, William Zamboni; Hines, Mark E.; Bayley, Suzanne E.

    1992-01-01

    Sulfur gases are important components of the global cycle of S. They contribute to the acidity of precipitation and they influence global radiation balance and climate. The role of terrestrial sources of biogenic S and their effect on atmospheric chemistry remain as major unanswered questions in our understanding of the natural S cycle. The role of northern wetlands as sources and sinks of gaseous S by measuring rates of S gas exchange as a function of season, hydrologic conditions, and gradients in tropic status was investigated. Experiments were conducted in wetlands in New Hampshire, particularly a poor fen, and in Mire 239, a poor fen at the Experimental Lakes Area (ELA) in Ontario. Emissions were determined using Teflon enclosures, gas cryotrapping methods and gas chromatography (GC) with flame photometric detection. Dynamic (sweep flow) and static enclosures were employed which yielded similar results. Dissolved S gases and methane were determined by gas stripping followed by GC.

  10. Physical replicas and the Bose glass in cold atomic gases

    International Nuclear Information System (INIS)

    Morrison, S; Kantian, A; Daley, A J; Zoller, P; Katzgraber, H G; Lewenstein, M; Buechler, H P

    2008-01-01

    We study cold atomic gases in a disorder potential and analyse the correlations between different systems subjected to the same disorder landscape. Such independent copies with the same disorder landscape are known as replicas. While, in general, these are not accessible experimentally in condensed matter systems, they can be realized using standard tools for controlling cold atomic gases in an optical lattice. Of special interest is the overlap function which represents a natural order parameter for disordered systems and is a correlation function between the atoms of two independent replicas with the same disorder. We demonstrate an efficient measurement scheme for the determination of this disorder-induced correlation function. As an application, we focus on the disordered Bose-Hubbard model and determine the overlap function within the perturbation theory and a numerical analysis. We find that the measurement of the overlap function allows for the identification of the Bose-glass phase in certain parameter regimes

  11. Physical replicas and the Bose glass in cold atomic gases

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, S; Kantian, A; Daley, A J; Zoller, P [Institute for Theoretical Physics, University of Innsbruck, Technikerstr. 25, A-6020 Innsbruck (Austria); Katzgraber, H G [Theoretische Physik, ETH Zurich, CH-8093 Zuerich (Switzerland); Lewenstein, M [ICAO-Institut de Ciencies Fotoniques, Parc Mediterrani de la Tecnologia, E-08860 Castelldefels, Barcelona (Spain); Buechler, H P [Institute for Theoretical Physics III, University of Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart (Germany)], E-mail: sarah.morrison@uibk.ac.at

    2008-07-15

    We study cold atomic gases in a disorder potential and analyse the correlations between different systems subjected to the same disorder landscape. Such independent copies with the same disorder landscape are known as replicas. While, in general, these are not accessible experimentally in condensed matter systems, they can be realized using standard tools for controlling cold atomic gases in an optical lattice. Of special interest is the overlap function which represents a natural order parameter for disordered systems and is a correlation function between the atoms of two independent replicas with the same disorder. We demonstrate an efficient measurement scheme for the determination of this disorder-induced correlation function. As an application, we focus on the disordered Bose-Hubbard model and determine the overlap function within the perturbation theory and a numerical analysis. We find that the measurement of the overlap function allows for the identification of the Bose-glass phase in certain parameter regimes.

  12. Determination of low concentrations of pyridine in piperidine by gas chromatography and infrared spectroscopy; Determinacion de bajas concentraciones de piperidina en piridina por cromatografia de gases y espectroscopia infrarroja

    Energy Technology Data Exchange (ETDEWEB)

    Perez Garcia, M. M.; Parellada Bellod, R.

    1979-07-01

    This paper describes the determination of low amounts of piperidine in pyridine in the concentration range of 0-5%. After an exhausting review of the bibliography on the column selection, the chromatographic separation and determination are made on the following column: 27% Pennwalt- 223; 4% KOH on Gas-Chrom R; 80-100 mesh with flame ionization detector. The retention indexes of both compounds and tho Rohrschneider constants of the phase used are calculated. The minimum detection limit achieved for piperidine is 0,25%. (Author) 25 refs.

  13. Method by chromatography of gases for the determination of made up of alcoholic fermentation in pineapple fruits (Ananas comosus [L.] Merr); Metodo por cromatografia de gases para la determinacion de compuestos de fermentacion alcoholica en frutos de pina (Ananas comosus [L.] Merr)

    Energy Technology Data Exchange (ETDEWEB)

    Murillo Williams, A

    2001-07-01

    The pineapple (Ananas comosus) it is used in the entire world for the fresh consumption or for processed products (canned, frozen, dehydrated). it is cultivated in a wide range of countries and in extreme latitudes.The factors of quality include: maturity, stability, size uniformity, absence of microbial deterioration, absence of burns for the sun, absence of blows, damage for insects and breaking, crowns, color, longitude and integrity. The factors that determine the longevity of a product can be physiologic or pathological. The physiologic conditions refer to the processes of degradation of the fabrics after the crop, while the pathological ones involve the attack of mushrooms and bacteria. In the case of the pineapple, a physiologic problem exists, called black heart, internal brewing (IB), brown endogenic stain ({sup m}ancha cafe endogena{sup ,} MCE) or chilling injury (CI) that can happen in any part of the world where it is cultivated. This problem has associated to the exhibition from the pineapple to low temperatures, so it is a challenge to manage a fruit like the pineapple that it cannot tolerate low temperatures without problems. In studies made about the physiologic changes that happen during the storage in controlled atmospheres in fruits, it has been observed that the ethanol and the acetaldehyde are volatile compounds associated with metabolic post-crop changes and that they have implication in the quality of the product. (author) [Spanish] La pina (Ananas comosus) se utiliza en todo el mundo para el consumo fresco o para productos procesados (enlatados, congelados, deshidratados). Se cultiva en un amplio rango de paises y en latitudes extremas. Los factores de calidad incluyen: madurez, firmeza, uniformidad de tamano, ausencia de deterioro microbiano, ausencia de quemaduras por el sol, ausencia de golpes, dano por insectos y quebraduras, corona, color, longitud e integridad. Los factores que determinan la longevidad de un producto pueden ser

  14. Determination of the neutron-induced fission cross section of {sup 242}Pu; Bestimmung des neutroneninduzierten Spaltquerschnitts von {sup 242}Pu

    Energy Technology Data Exchange (ETDEWEB)

    Koegler, Toni Joerg

    2016-04-26

    Neutron induced fission cross sections of actinides like the Pu-isotopes are of relevance for the development of nuclear transmutation technologies. For {sup 242}Pu, current uncertainties are of around 21%. Sensitivity studies show that the total uncertainty has to be reduced to below 5% to allow for reliable neutron physics simulations. This challenging task was performed at the neutron time-of-flight facility of the new German National Center for High Power Radiation Sources at HZDR, Dresden. Within the TRAKULA project, thin, large and homogeneous deposits of {sup 235}U and {sup 242}Pu have been produced successfully. Using two consecutively placed fission chambers allowed the determination of the neutron induced fission cross section of {sup 242}Pu relative to {sup 235}U. The areal density of the Plutonium targets was calculated using the measured spontaneous fission rate. Experimental results of the fast neutron induced fission of {sup 242}Pu acquired at nELBE will be presented and compared to recent experiments and evaluated data. Corrections addressing the neutron scattering are discussed by using results of different neutron transport simulations (Geant 4, MCNP 6 and FLUKA).

  15. Determination of Fallout Radionuclides in Environmental Samples by Gamma-Ray Spectrometry; Mesure Spectrometrique Gamma des Radionucleides de Retombee Presents dans des Echantillons du Millieu; Opredelenie radioizotopov radioaktivnykh osadkov v probakh iz okruzhayushchej sredy pri pomoshchi spektrometrii gamma-luchej; Determinacion, por Espectrometria Gamma, de los Radionuclidos de Precipitaciones en Muestras del Medio Ambiente

    Energy Technology Data Exchange (ETDEWEB)

    Ward, G. M.; Johnson, J. E.; Wilson, D. W. [Department of Animal Science, Colorado State University, Fort Collins, CO (United States)

    1965-10-15

    From May 1962 to date, many environmental samples have been collected from the University farm to study the passage of {sup 137}Cs through an important part of man's food chain. All samples were of low specific activity and determinations were made in a low level gamma-ray spectrometer system consisting of an 8-in diam., 4-in-thick Nal(Tl) crystal that was shielded from background by a 5-in-thick steel walled chamber and connected to a 400-channel pulse-height analyser. Air filter pads and large samples (1 kg) of dried forage, grains and bovine faeces were counted directly in a constant geometry. Precipitation samples were concentrated by passing through Dowex-50 cation exchange columns. Milk, meat, and urine Vere counted in large annular Lucite containers. {sup 137}Cs, {sup 40}K, {sup 131}I and Ba-{sup 14}'0La are the only gamma-ray emitting radionuclides found in milk, meat and urine, since these are the only fission products absorbed in appreciable amounts. In addition, the other samples contained {sup 141,} {sup 144}Ce, {sup 125}Sb, {sup 103,106}Ru, Zr-{sup 95}Nb and {sup 54}Mn. In these samples, which were collected in 1962 and 1963, only Zr-{sup 95}Nb (because of its relative abundance) could be determined reliably by gamma-ray spectrometry during a period of about six months after collection. Photopeaks of {sup 137}Cs, {sup 54}Mn and were completely obscured and lower energy nuclides ({sup 141}, {sup 144}Ce and {sup 103}Ru) had large Compton contributions from higher energy nuclides. Spectrum stripping is not reliable if the photopeaks are not apparent. When interference makes the direct determination of {sup 137}Cs and other nuclides impossible, storage of the samples until decay of Zr-{sup 95}Nb (T{sub Vulgar-Fraction-One-Half} = 65 d) and {sup 103}Ru (T{sub Vulgar-Fraction-One-Half} = 40 d) makes possible identification of the photopeaks of the remaining nuclides. {sup 137}Cs and {sup 54}Mn can be separated chemically by digesting samples in concentrated

  16. Noble gases in ten stone meteorites from Antarctica

    International Nuclear Information System (INIS)

    Weber, H.W.; Schultz, L.

    1980-01-01

    The concentrations and isotopic composition of noble gases have been determined in all ten stone meteorites recovered in Antarctica during 1976-1977 by a U.S.-Japanese expedition. From a comparison of spallogenic and radiogenic gas components it is concluded that the chondrites Mt. Baldr (a) and Mt. Baldr (b) belong to the same fall but that all other stone meteorites are individual finds. (orig.)

  17. The electron energy distribution function of noble gases with flow

    International Nuclear Information System (INIS)

    Karditsas, P.J.

    1989-01-01

    The treatment of the Boltzmann equation by several investigators, for the determination of the electron energy distribution function (EEDF) in noble gases was restricted to static discharges. It is of great interest to magnetoplasmadynamic power generation to develop the Boltzmann equation to account for the effect of the bulk fluid flow on the EEDF. The two term expansion of the Boltzmann equation, as given, results in additional terms introduced to the equations due to the bulk fluid flow, with velocity u

  18. Determination of the thermal radiation effect on an optical strontium lattice clock; Bestimmung des Einflusses thermischer Strahlung auf eine optische Strontium-Gitteruhr

    Energy Technology Data Exchange (ETDEWEB)

    Middelmann, Thomas

    2013-05-31

    Optical clocks have the potential to be 100 times more accurate than current best cesium atomic clocks within a fraction of the averaging time. This corresponds to a fractional uncertainty of the clock frequency on the level of 10{sup -18} and requires highaccuracy knowledge of systematic frequency shifts, such that they can be avoided or corrected for. In strontium optical lattice clocks an ensemble of ultracold strontium atoms is confined in an optical lattice, to allow for spectroscopy of the reference transition 5s{sup 2} {sup 1}S{sub 0}-5s5p {sup 3}P{sub 0} in the Lamb-Dicke regime. The by far largest systematic frequency shift of the strontium clock transition is caused by its high sensitivity to blackbody radiation (BBR). The knowledge of the resulting frequency shift limited the achievable clock uncertainty to about 1 x 10{sup -16}. In this thesis for the first time an experimental approach was followed, to determine the sensitivity of the strontium clock transition to blackbody radiation. At an environmental temperature of 300 K the resulting frequency shift corresponds to 2.277 8(23) Hz. The achieved uncertainty contributes with 5 x 10{sup -18} to the fractional systematic uncertainty of the clock frequency. The determination is based on a precision measurement of the difference of static polarizabilities of the two clock states {Delta}{alpha}{sub dc} = {alpha}(5s5p {sup 3}P{sub 0})-{alpha}(5s{sup 2} {sup 1}S{sub 0}) = 4.078 73(11) x 10{sup -39} Cm{sup 2} /V. For this the de Stark shift of the clock transition has been measured in the accurately known electric field of a precision plate capacitor, which has been developed in this work. The attained static polarizability difference {Delta}{alpha}{sub dc} corresponds to the first term of a power series of the sensitivity to BBR. Higher orders are accumulated as dynamic part of the BBR shift. Which has been modelled using {Delta}{alpha}{sub dc} and experimental data for other atomic properties. To

  19. Greenhouse gases study in Amazonia

    International Nuclear Information System (INIS)

    D'Amelio, Monica Tais Siqueira

    2006-01-01

    The Amazon plays an important role on the global carbon cycle, as changing as carbon storage, since Amazon Basin is the biggest area of tropical forest, around 50% of global. Natural's process, deforestation, and use land are CO 2 sources. The Amazon forest is a significant source of N 2 O by soil process, and CH 4 by anaerobic process like flooded areas, rice cultures, and others sources. This project is part of the LBA project (Large-Scale Biosphere Atmosphere Experiment in Amazonia), and this project is 'Vertical profiles of carbon dioxide and other trace gas species over the Amazon basin using small aircraft'. Since December 2000 vertical profiles of CO 2 , CH 4 , CO, H 2 , N 2 O and SF 6 have been measured above central Amazonia. The local sampling was over Tapajos National Forest, a primary forest in Para State, where had a CO 2 flux tower and an east impact area with sources like animals, rice cultivation, biomass burning, etc, to compare the influence of an impact area and a preserved area in the profiles. The Reserva Biologica de Cuieiras, at Amazon State, is the other studied place, where there already exists a CO 2 flux tower, and an east preserved area at this State, to compare with the Cuieiras. The sampling has been carried out on vertical profile from 1000 ft up to 12000 ft using a semi-automated sampling package developed at GMD/NOAA and a small aircraft. The analysis uses the MAGICC system (Multiple Analysis of Gases Influence Climate Change) which is installed at the Atmospheric Chemistry Laboratory (LQA) in IPEN (Instituto de Pesquisas Energeticas e Nucleares). The results showed that all gases studied, except H 2 gas, has been following the global trend. At the Para State, for the studied years, the Amazonian Forest performed as small CO 2 sink. To compare Wet and Dry Seasons, subtracted the Ascension concentration values in the period to remove the global influence. So that, in the 2004 and 2005 wet seasons and 2004 dry season comparison it was

  20. Dipolar quantum gases of erbium

    International Nuclear Information System (INIS)

    Frisch, A.

    2014-01-01

    Since the preparation of the first Bose-Einstein condensate about two decades ago and the first degenerate Fermi gas following four years later a plethora of fascinating quantum phenomena have been explored. The vast majority of experiments focused on quantum degenerate atomic gases with short-range contact interaction between particles. Atomic species with large magnetic dipole moments, such as chromium, dysprosium, and erbium, offer unique possibilities to investigate phenomena arising from dipolar interaction. This kind of interaction is not only long-range but also anisotropic in character and imprints qualitatively novel features on the system. Prominent examples are the d-wave collapse of a dipolar Bose-Einstein condensate of chromium atoms realized by the group in Stuttgart, the spin magnetization and demagnetization dynamics observed by groups in Stuttgart, Paris, and Stanford, and the deformation of the Fermi surface observed by our group in Innsbruck. This thesis reports on the creation and study of the first Bose-Einstein condensate and degenerate Fermi gas of erbium atoms. Erbium belongs to the lanthanide group of elements and has a large magnetic moment of seven Bohr magneton. In particular, this thesis describes the experimental apparatus and the sequence for producing a dipolar quantum gas. There is an emphasis on the production of the narrow-line magneto-optical trap of erbium since this represents a very efficient and robust laser-cooling scheme that greatly simplifies the experimental procedure. After describing the experimental setup this thesis focuses on several fundamental questions related to the dipolar character of erbium and to its lanthanide nature. A first set of studies centers on the scattering properties of ultracold erbium atoms, including the elastic and the inelastic cross section and the spectrum of Feshbach resonances. Specifically, we observe that identical dipolar fermions do collide and rethermalize even at low temperatures

  1. Rare gases in Samoan xenoliths

    Science.gov (United States)

    Poreda, R. J.; Farley, K. A.

    1992-09-01

    The rare gas isotopic compositions of residual harzburgite xenoliths from Savai'i (SAV locality) and an unnamed seamount south of the Samoan chain (PPT locality) provide important constraints on the rare gas evolution of the mantle and atmosphere. Despite heterogeneous trace element compositions, the rare gas characteristics of the xenoliths from each of the two localities are strikingly similar. SAV and PPT xenoliths have 3He/ 4He ratios of11.1 ± 0.5 R A and21.6 ± 1 R A, respectively; this range is comparable to the 3He/ 4He ratios in Samoan lavas and clearly demonstrates that they have trapped gases from a relatively undegassed reservoir. The neon results are not consistent with mixing between MORB and a plume source with an atmospheric signature. Rather, the neon isotopes reflect either a variably degassed mantle (with a relative order of degassing of Loihi Honda et al. that the 20Ne/ 22Ne ratio in the mantle more closely resembles the solar ratio than the atmospheric one. 40Ar/ 36Ar ratios in the least contaminated samples range from 4,000 to 12,000 with the highest values in the 22 RA PPT xenoliths. There is no evidence for atmospheric 40Ar/ 36Ar ratios in the mantle source of these samples, which indicates that the lower mantle may have 40Ar/ 36Ar ratios in excess of 5,000. Xenon isotopic anomalies in 129Xe and 136Xe are as high as 6%, or about half of the maximum MORB excess and are consistent with the less degassed nature of the Samoan mantle source. These results contradict previous suggestions that the high 3He/ 4He mantle has a near-atmospheric heavy rare gas isotopic composition.

  2. Direct measurement of the interaction energy between solids and gases--3. Comparison of the calorimetric titration method with the amine titration method for the determination of acid strength distribution of the silica-alumina surface

    Energy Technology Data Exchange (ETDEWEB)

    Taniguchi, H.; Masuda, T.; Tsutsumi, K.; Takahashi, H.

    1978-07-01

    Comparison of the calorimetric titration method with the amine titration method for the determination of acid strength distribution of the silica-alumina surface was carried out for a catalyst containing 13% by wt alumina and evacuated at 400/sup 0/C at 0.00001 mm Hg for five hours. The heats of adsorption of ammonia on silica-alumina poisoned with Hammett indicators of 8.2 to 3.3 pK/sub a/ were also measured to obtain the relation between the dissociation constant of the acid (pK/sub a/) and the heat of adsorption. At pK/sub a/ values of -5.6 and +3.3, the differential heats of adsorption were 76.1 and 55.1 kj/mole, respectively. The number of acid sites calculated from the heat vs. adsorbed-amount curve was about twice as large as that determined by amine titration. The discrepancy is discussed.

  3. Equilibrium phase experimental determination of petroleum + gas systems at supercritical condition using ultrasonic technology; Estudo experimental do equilibrio de fases de sistemas de fracoes de petroleo e gases em condicoes supercriticas utilizando tecnicas de ultra-som: aparato experimental

    Energy Technology Data Exchange (ETDEWEB)

    Mehl, Ana; Pessoa, Fernando L.P.; Silva, Silvia M.C. da [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica; Feiteira, Jose F. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Escola de Engenharia

    2008-07-01

    In separation process of multicomponent systems based on phase equilibrium is essential know the phase behavior and the critical points of the system for determination and optimization of the operational conditions. The experimental apparatus presents the challenge of determine the equilibrium phase dates of a system composed by petroleum residua and supercritical solvent. The used method, named acoustic method, allows the composition identification of the phases in equilibrium also in cloudy systems as they are the systems formed by residues of crude oil. For this reason, the acoustic methodology, based on the ultra-sound technology will be used in the study of the phase equilibrium and experimental characterization of the system, in benches scale, operating in severe conditions of temperature and pressure.The acoustic method is one not invasive and not subjective technique, what becomes the work in high pressures safer. (author)

  4. Elaboration de nouvelles approches micromecaniques pour l'optimisation des performances mecaniques des materiaux heterogenes

    Science.gov (United States)

    Aboutajeddine, Ahmed

    Les modeles micromecaniques de transition d'echelles qui permettent de determiner les proprietes effectives des materiaux heterogenes a partir de la microstructure sont consideres dans ce travail. L'objectif est la prise en compte de la presence d'une interphase entre la matrice et le renforcement dans les modeles micromecaniques classiques, de meme que la reconsideration des approximations de base de ces modeles, afin de traiter les materiaux multiphasiques. Un nouveau modele micromecanique est alors propose pour tenir compte de la presence d'une interphase elastique mince lors de la determination des proprietes effectives. Ce modele a ete construit grace a l'apport de l'equation integrale, des operateurs interfaciaux de Hill et de la methode de Mori-Tanaka. Les expressions obtenues pour les modules globaux et les champs dans l'enrobage sont de nature analytique. L'approximation de base de ce modele est amelioree par la suite dans un nouveau modele qui s'interesse aux inclusions enrobees avec un enrobage mince ou epais. La resolution utilisee s'appuie sur une double homogeneisation realisee au niveau de l'inclusion enrobee et du materiau. Cette nouvelle demarche, permettra d'apprehender completement les implications des approximations de la modelisation. Les resultats obtenus sont exploites par la suite dans la solution de l'assemblage de Hashin. Ainsi, plusieurs modeles micromecaniques classiques d'origines differentes se voient unifier et rattacher, dans ce travail, a la representation geometrique de Hashin. En plus de pouvoir apprecier completement la pertinence de l'approximation de chaque modele dans cette vision unique, l'extension correcte de ces modeles aux materiaux multiphasiques est rendue possible. Plusieurs modeles analytiques et explicites sont alors proposee suivant des solutions de differents ordres de l'assemblage de Hashin. L'un des modeles explicite apparait comme une correction directe du modele de Mori-Tanaka, dans les cas ou celui ci echoue a

  5. REPRISE DES COURS - Yoga

    CERN Multimedia

    Club de Yoga

    2015-01-01

    REPRISE DES COURS – Venez nombreux ! Yoga, Sophrologie, Tai Chi La liste des cours pour le semestre allant du 1er septembre 2015 au 31 janvier 2016 est disponible sur notre site web : http://club-yoga.web.cern.ch Lieu Les cours ont lieu dans la salle des clubs, à l’entresol du restaurant No 2, Bât. 504 (dans la salle no 3 pour la Sophrologie). Prix des cours Le prix pour le semestre (environ 18 leçons) est fixé à 220 CHF plus 10 CHF d’adhésion annuelle au Club. Couple : 200 CHF par personne. 2 cours par semaine : 400 CHF. Inscriptions Les inscriptions aux cours seront prises directement auprès du professeur, lors de la 1ère séance. Avant de s’inscrire pour le semestre, il est possible d’essayer une séance gratuitement. Informations : http://club-yoga.web.cern.ch ----------------------------------------- cern.ch/club-yoga/

  6. Praxis des Klebens

    CERN Document Server

    Theuerkauff, Petra

    1989-01-01

    Bei diesem Buch handelt es sich um einen Leitfaden fur Klebepraktiker. Es werden die verschiedenen Einzelschritte beim kleben beschrieben, als auch die vorbereitenden Massnahmen und anschliessenden Prufverfahren auf Festigkeit behandelt. Das Buch sollte an keinem Arbeitsplatz fehlen, wo man sich mit Problemen der Fugetechnik des Klebens beschaftigt.

  7. Dimensions des stabulations 2018

    OpenAIRE

    Früh, Barbara; Maurer, Veronika; Schneider, Claudia; Schürmann, Stefan; Spengler Neff, Anet; Werne, Steffen

    2018-01-01

    Les «Dimensions des stabulations» contiennent toutes les dimensions pour les stabulations et les parcours pour la production animale en agriculture biologique. Cette liste sert d’instrument de planification pour les éleveurs, d’outil de travail pour la vulgarisation et d’ouvrage de référence pour le contrôle bio.

  8. Direction des Publications

    African Journals Online (AJOL)

    Synthese

    économique des services rendus par les écosystèmes marins. La richesse ... croissance plus rapide que la moyenne de l‟économie ...... services and natural capital. Nature. 387, 253-260. .... d‟interactions où l‟humain est partie prenante. In.

  9. La physique des infinis

    CERN Document Server

    Bernardeau, Francis; Laplace, Sandrine; Spiro, Michel

    2013-01-01

    Écrire l'histoire de l'Univers, tel est l'objectif commun des physiciens des particules et des astrophysiciens. Pour y parvenir, deux approches s'épaulent : la voie de l'infiniment petit, que l'on emprunte via de gigantesques accélérateurs de particules, et celle de l'infiniment grand, dont le laboratoire est l'Univers. Un Univers qui est bien loin d'avoir livré tous ses secrets. On connaît à peine 4,8 % de la matière qui le constitue, le reste étant composé de matière noire (25,8 %) et d'énergie noire (69,4 %), toutes deux de nature inconnue. Et si la récente découverte du boson de Higgs valide le Modèle standard de la physique des particules, celui-ci est toujours incomplet et doit être étendu à ou dépassé. Est-on arrivé au bout du jeu de poupées russes de la matière ? Quelles sont les particules manquantes ? Faut-il revoir les lois fondamentales ? Quels instruments faut-il mettre en œuvre pour accéder à cette « nouvelle physique » ? Comment parler de Super Big Science aux citoye...

  10. Contribution to the geochemical knowledge of the uranium-radium and thorium families in the southern Vosges. Applications of some results in the prospecting of uranium deposits; Contribution a la connaissance geochimique des familles uranium-radium et du thorium dans les Vosges meridionales. Application de certains resultats en prospection des gisements d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Jurain, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    This work's aim is to lead to a more accurate knowledge of the geochemistry of the Uranium-Radium and Thorium families in the Southern Vosges and to apply some of the results to the prospecting of uraniferous deposits: It has been showed: a bond between Calcium-Magnesium and Uranium-Thorium in the calco-alkaline granites. The host minerals of Uranium and Thorium are hornblende, biotite, titanite and epidote. a concentration of Uranium, at present time with secular disequilibrium in a thermal zone where the satellite mineralizations form an epithermal paragenesis. a disequilibrium of the Uranium-Radium family in the supergene minerals of the lead (phosphate and vanadate) showing the present circulations of Uranium. a bond between the radon grade of the spring waters and Uranium-Radium of the rocks. Such a relation allow to realize a prospecting method based on the determination of radioactive gases from the cold spring-waters of a common country. (author) [French] L'etude presentee ici a pour but de conduire a une connaissance plus precise de la geochimie des familles Uranium-Radium et Thorium dans les Vosges meridionales et d'appliquer certains resultats a la prospection des gites uraniferes. Il a ete mis en evidence: une liaison Calcium-Magnesium et Uranium-Thorium dans des granites calco-alcalins. Les mineraux hotes de l'Uranium et du Thorium sont: la hornblende, la biotite, le sphene, l'epidote. une concentration actuelle de l'Uranium en desequilibre seculaire dans une zone thermale ou les mineralisations satellites constituent une paragenese epithermale. un desequilibre de la famille Uranium-Radium dans des mineraux supergenes du plomb (phosphates et vanadates) prouvant les circulations actuelles de l'Uranium. une liaison entre la teneur en Radon des eaux de sources et celle en Uranium-Radium des roches. Une telle liaison permet de realiser une methode de prospection fondee sur le dosage du gaz radioactif des eaux de sources froides d'une region quelconque

  11. Contribution to the geochemical knowledge of the uranium-radium and thorium families in the southern Vosges. Applications of some results in the prospecting of uranium deposits; Contribution a la connaissance geochimique des familles uranium-radium et du thorium dans les Vosges meridionales. Application de certains resultats en prospection des gisements d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Jurain, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-07-01

    This work's aim is to lead to a more accurate knowledge of the geochemistry of the Uranium-Radium and Thorium families in the Southern Vosges and to apply some of the results to the prospecting of uraniferous deposits: It has been showed: a bond between Calcium-Magnesium and Uranium-Thorium in the calco-alkaline granites. The host minerals of Uranium and Thorium are hornblende, biotite, titanite and epidote. a concentration of Uranium, at present time with secular disequilibrium in a thermal zone where the satellite mineralizations form an epithermal paragenesis. a disequilibrium of the Uranium-Radium family in the supergene minerals of the lead (phosphate and vanadate) showing the present circulations of Uranium. a bond between the radon grade of the spring waters and Uranium-Radium of the rocks. Such a relation allow to realize a prospecting method based on the determination of radioactive gases from the cold spring-waters of a common country. (author) [French] L'etude presentee ici a pour but de conduire a une connaissance plus precise de la geochimie des familles Uranium-Radium et Thorium dans les Vosges meridionales et d'appliquer certains resultats a la prospection des gites uraniferes. Il a ete mis en evidence: une liaison Calcium-Magnesium et Uranium-Thorium dans des granites calco-alcalins. Les mineraux hotes de l'Uranium et du Thorium sont: la hornblende, la biotite, le sphene, l'epidote. une concentration actuelle de l'Uranium en desequilibre seculaire dans une zone thermale ou les mineralisations satellites constituent une paragenese epithermale. un desequilibre de la famille Uranium-Radium dans des mineraux supergenes du plomb (phosphates et vanadates) prouvant les circulations actuelles de l'Uranium. une liaison entre la teneur en Radon des eaux de sources et celle en Uranium-Radium des roches. Une telle liaison permet de realiser une methode de prospection fondee sur le dosage du gaz radioactif des eaux de sources

  12. Physics of phenomena in the zone close to an underground nuclear explosion; Physique des phenomenes en zone proche des explosions nucleaires souterraines

    Energy Technology Data Exchange (ETDEWEB)

    Maury, J; Levret, C [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1969-07-01

    After a description of the phenomenology of underground explosions, the basic laws governing the propagation in the ground of the energy produced by the explosion are given. The reports considers hydrodynamics, the mechanics of solids, the equations of state for solids and gases in the case of very high and medium pressures, and the dynamical strength of solids. These various elements make it possible to draw up a system of equations which define completely the changes with time of the shock-wave produced in the ground by the explosion. (authors) [French] Apres une description de la phenomenologie des explosions souterraines, on expose les lois fondamentales regissant la propagation dans le sol de l'energie degagee par l'explosion. L'expose comprend des developpements sur l'hydrodynamique, la mecanique des solides, les equations d'etat des solides et des gaz, aux tres fortes et moyennes pressions, et sur la resistance dynamique des solides. Ces differents elements permettent d'ecrire un systeme d'equations qui definissent completement l'evolution dans le temps de l'onde de choc emise dans le sol par l'explosion. (auteurs)

  13. Physics of phenomena in the zone close to an underground nuclear explosion; Physique des phenomenes en zone proche des explosions nucleaires souterraines

    Energy Technology Data Exchange (ETDEWEB)

    Maury, J.; Levret, C. [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1969-07-01

    After a description of the phenomenology of underground explosions, the basic laws governing the propagation in the ground of the energy produced by the explosion are given. The reports considers hydrodynamics, the mechanics of solids, the equations of state for solids and gases in the case of very high and medium pressures, and the dynamical strength of solids. These various elements make it possible to draw up a system of equations which define completely the changes with time of the shock-wave produced in the ground by the explosion. (authors) [French] Apres une description de la phenomenologie des explosions souterraines, on expose les lois fondamentales regissant la propagation dans le sol de l'energie degagee par l'explosion. L'expose comprend des developpements sur l'hydrodynamique, la mecanique des solides, les equations d'etat des solides et des gaz, aux tres fortes et moyennes pressions, et sur la resistance dynamique des solides. Ces differents elements permettent d'ecrire un systeme d'equations qui definissent completement l'evolution dans le temps de l'onde de choc emise dans le sol par l'explosion. (auteurs)

  14. Nouvelle méthode expérimentale pour déterminer le gonflement libre des sols argileux Novel experimental method to determine clay soil free swelling

    Directory of Open Access Journals (Sweden)

    Essaaidi M.

    2012-09-01

    Full Text Available Le dispositif est un interferometre de Michelson modifie. En effet sur le miroir mobile est colle un echantillon d’fargile cylindrique, seche, de longueur L, de rayon R et faconnee de maniere a retenir les gouttes d’feau a sa surface pour controler la teneur en eau. Lorsqu’fon injecte un volume d’feau distillee (quelques gouttes a la surface de l’fechantillon, celui-ci se gonfle et le miroir se deplace. On observe le defilement des franges et on procede au comptage de leur nombre durant le temps t que dure le gonflement (environ 40 mn. On peut ainsi mesurer le deplacement libre du miroir et determiner: la valeur du gonflement exprime en % ou g/cm3, le gonflement sous contrainte σ (pour comparer avec l’foedometre et sa vitesse au cours du temps t. The propose device is based on Michelson interferometer. In fact, we put the a sample of cylindrical shape dry clay of length L and radius R on the mobile mirror, This sample can retain a drop of water on its surface in order to monitor water content. When injecting a volume of distilled water (a few drops to the surface of the sample, it swells and moves the mirror. Consequently, we see scrolling fringes and we proceed to count their number during the time t during this swelling (about 40 min. We can measure the free displacement of the mirror and to establish the value of swelling expressed in% or g/cm3, the swelling under stress σ (to compare with the oedometer and speed during a time t.

  15. Determination of the uncertainties of air pollutant emissions of land bound traffic in Germany, computed with the models TREMOD and TREMOD MM; Ermittlung der Unsicherheiten der mit den Modellen TREMOD und TREMOD-MM berechneten Luftschadstoffemissionen des landgebundenen Verkehrs in Deutschland

    Energy Technology Data Exchange (ETDEWEB)

    Knoerr, Wofram [ifeu - Institut fuer Energie- und Umweltforschung Heidelberg gGmbH, Heidelberg (Germany); Heldstab, Juerg; Kasser, Florian; Keller, Mario [INFRAS, Zuerich (Switzerland)

    2010-05-15

    Germany is obligated to the implementation of emission inventories for climatic gases and air pollutants. This requires the proof and documentation of the data quality and uncertainties. In the project under consideration the uncertainties of the ZSE data records (ZSE = central system emissions) of the source groups road traffic, rail traffic, inland navigation traffic and residual traffic of the emission inventory are to be determined for all fuel methods, greenhouse gases and air pollutants. The basis of the ZSE data records are the programs TREMOD and TREMOD MM as well as the sales figures of fuels. Provisional results of the actual mineral oil statistics, updated road performances and stocks of vehicles as well as the actual emission factor data base of traffic are used as a fundament for the determination of uncertainties.

  16. Injectabilite des coulis de ciment dans des milieux fissures

    Science.gov (United States)

    Mnif, Thameur

    Le travail presente ici est un bilan du travaux de recherche effectues sur l'injectabilite des coulis de ciment dans lu milieux fissures. Un certain nombre de coulis a base de ciment Portland et microfin ont ete selectionnes afin de caracteriser leur capacite a penetrer des milieux fissures. Une partie des essais a ete menee en laboratoire. L'etude rheologique des differents melanges a permis de tester l'influence de l'ajout de superplastifiant et/ou de fumee de silice sur la distribution granulometrique des coulis et par consequent sur leur capacite a injecter des colonnes de sable simulant un milieu fissure donne. La classe granulometrique d'un coulis, sa stabilite et sa fluidite sont apparus comme les trois facteurs principaux pour la reussite d'une injection. Un facteur de finesse a ete defini au cours de cette etude: base sur la classe granulometrique du ciment et sa stabilite, il peut entrer dans la formulation theorique du debit d'injection avant application sur chantier. La deuxieme et derniere partie de l'etude presente les resultats de deux projets de recherche sur l'injection realises sur chantier. L'injection de dalles de beton fissurees a permis le suivi de l'evolution des pressions avec la distance au point d'injection. L'injection de murs de maconnerie a caractere historique a montre l'importance de la definition de criteres de performance des coulis a utiliser pour traiter un milieu donne et pour un objectif donne. Plusieurs melanges peuvent ainsi etre predefinis et mis a disposition sur le chantier. La complementarite des ciments traditionnels et des ciments microfins devient alors un atout important. Le choix d'utilisation de ces melanges est fonction du terrain rencontre. En conclusion, cette recherche etablit une methodologie pour la selection des coulis a base de ciment et des pressions d'injection en fonction de l'ouverture des fissures ou joints de construction.

  17. Screening phytochimique et identification spectroscopique des ...

    African Journals Online (AJOL)

    Origin

    plante, effectuée pour la première fois, a révélé la présence des alcaloïdes, des flavonoïdes, des tanins catéchiques, des terpènes, des coumarines et des composés cyanogénétiques. Quant aux saponines et les quinones libres, ils sont présents chez les fleurs et absents chez les feuilles. La caractérisation des molécules.

  18. Determination of correction coefficients for quantitative analysis by mass spectrometry. Application to uranium impurities analysis; Recherche des coefficients de correction permettant l'analyse quantitative par spectrometrie de masse. Application a l'analyse d'impuretes dans l'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Billon, J P [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1970-07-01

    Some of basic principles in spark source mass spectrometry are recalled. It is shown how this method can lead to quantitative analysis when attention is paid to some theoretical aspects. A time constant relation being assumed between the analysed solid sample and the ionic beam it gives we determined experimental relative sensitivity factors for impurities in uranium matrix. Results being in fairly good agreement with: an unelaborate theory on ionization yield in spark-source use of theoretically obtained relative sensitivity factors in uranium matrix has been developed. (author) [French] Apres avoir rappele quelques principes fondamentaux regissant la spectrometrie de masse a etincelles, nous avons montre que moyennant un certain nombre de precautions, il etait possible d'utiliser cette methode en analyse quantitative. Ayant admis qu'il existait une relation constante dans le temps entre l'echantillon solide analyse et le faisceau ionique qui en est issu, nous avons d'abord entrepris de determiner des coefficients de correction experimentaux pour des matrices d'uranium. Les premiers resultats pratiques semblant en accord avec une theorie simple relative au rendement d'ionisation dans la source a etincelles, nous avons etudie la possibilite d'appliquer directement les coefficients theoriques ainsi definis, l'application etant toujours faite sur des matrices d'uranium. (auteur)

  19. Anaesthetic gases: environmental impact and alternatives

    African Journals Online (AJOL)

    Little consideration has been given to the environmental impact of anaesthetic gas .... our practice to select gases with a lower environmental impact is also ... is used as raw material for new anaesthetics. ... none in the pipeline.1. Conclusion.

  20. Voluntary reporting of greenhouse gases, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  1. Granular Gases: Probing the Boundaries of Hydrodynamics

    International Nuclear Information System (INIS)

    Goldhirsch, I.

    1999-01-01

    The dissipative nature of the particle interactions in granular systems renders granular gases mesoscopic and bearing some similarities to regular gases in the ''continuum transition regime'' where shear rates and/or thermal gradients are very large). The following properties of granular gases support the above claim: (i). Mean free times are of the same order as macroscopic time scales (inverse shear rates); (ii). Mean free paths can be macroscopic and comparable to the system's dimensions; (iii). Typical flows are supersonic; (iv). Shear rates are typically ''large''; (v). Stress fields are scale (resolution) dependent; (vi). Burnett and super-Burnett corrections to both the constitutive relations and the boundary conditions are of importance; (vii). Single particle distribution functions can be far from Gaussian. It is concluded that while hydrodynamic descriptions of granular gases are relevant, they are probing the boundaries of applicability of hydrodynamics and perhaps slightly beyond

  2. Greenhouse gases - observed tendencies contra scenarios

    International Nuclear Information System (INIS)

    Groenaas, Sigbjoern

    2006-01-01

    The article presents a study of the increase in greenhouse gases and concludes that it will be necessary to substantially reduce the CO2 concentrations in the atmosphere in order to avoid serious climatic changes

  3. Climate Change, Greenhouse Gases and Aerosols

    Indian Academy of Sciences (India)

    user

    their radiative properties are similar to the glass used in a green- house. Greenhouse gases in the Earth's atmosphere absorb 90% of the radiation emitted .... and wind speed and direction in each box is calculated using the physical laws gov-.

  4. Roadside management strategies to reduce greenhouse gases.

    Science.gov (United States)

    2010-06-01

    Californias Global Warming Solutions Act of 2006 (AB 32), Sustainable Communities and Climate Protection Act : (SB 375), and Executive Order S-14-08 direct Caltrans to develop actions to reduce greenhouse gases (GHGs). Air : pollution reduction is...

  5. Nozzle flow calculation for real gases

    International Nuclear Information System (INIS)

    Bier, K.; Ehrler, F.; Hartz, U.; Kissau, G.

    1977-01-01

    The flow of CHF 2 Cl vapor (refrigerant R 22) through a Laval nozzle of annular geometry has been investigated in the region near the saturation line with stagnation pressures up to 85 per cent of the critical pressure. Static pressure profiles measured along the nozzle axis were found in good agreement with profiles calculated for one-dimensional isentropic flow of the real gas the thermal properties of which were derived from an equation of state proposed previously by Rombusch. Minor deviations between measured and calculated static pressure curves occur in the supersonic part of the mozzle, especially when supersaturated states of the vapour are passed. These deviations can be attributed to uncertainties in the calculation of the enthalpy and to a small influence of the static pressure probe. An additional investigation was concerned with an approximate calculation of the nozzle flow of real gases. In this approximation the well known relations of ideal gas dynamics are applied, the ratio of specific heats for the ideal gas being replaced, however, by a suitably adapted isentropic exponent, which can be determined e.g. from measured values of the Laval pressure or of the mass flow. For pressure ratios p/po between 1 and approximately 0.1, corresponding to Mach numbers up to approximately 2.2, all the interesting properties of the investigated flow of CHF 2 Cl vapour are approximated within a few per cent. (orig.) [de

  6. Efficacité des néonicotinoïdes et des pyréthrinoïdes utilisés contre le ...

    African Journals Online (AJOL)

    Efficacité des néonicotinoïdes et des pyréthrinoïdes utilisés contre le foreur des tiges du cacaoyer ( Eulophonotus myrmeleon Felder : Lepidoptera, Cossidae). Implications dans la stratégie de protection de la cacaoculture en Côte d'Ivoire.

  7. Primordial Noble Gases from Earth's Core

    Science.gov (United States)

    Wang, K.; Lu, X.; Brodholt, J. P.

    2016-12-01

    Recent partitioning experiment suggests helium is more compatible in iron melt than in molten silicates at high pressures (> 10 GPa) (1), thus provide the possibility of the core as being the primordial noble gases warehouse that is responsible for the high primordial/radiogenic noble gas isotopic ratios observed in plume-related basalts. However, the possible transportation mechanism of the noble gases from the core to the overlying mantle is still ambiguous, understanding how this process would affect the noble gas isotopic characteristics of the mantle is critical to validate this core reservoir model. As diffusion is a dominant mass transport process that plays an important role in chemical exchange at the core-mantle boundary (CMB), we have determined the diffusion coefficients of helium, neon and argon in major lower mantle minerals, i.e. periclase (MgO), bridgemanite (MgSiO3-Pv) and post-perovskite (MgSiO3-PPv), by first-principles calculation based on density functional theory (DFT). As expected, the diffusion rate of helium is the fastest at the CMB, which is in the range of 3 × 10-10 to 1 × 10-8 m2/s. The neon diffusion is slightly slower, from 5 × 10-10 to 5 × 10-9 m2/s. Argon diffuses slowest at the rate from 1 × 10-10 to 2 × 10-10 m2/s. We have further simulated the evolution of noble gas isotopic ratios in the mantle near the CMB. Considering its close relationship with the mantle plumes and very likely to be the direct source of "hot-spot" basalts, we took a close investigation on the large low-shear-velocity provinces (LLSVPs). Under reasonable assumptions based on our diffusion parameters, the modelling results indicate that LLSVP is capable of generating all the noble gas isotope signals, e.g., 3He/4He = 55 Ra, 3He/22Ne = 3.1, 3He/36Ar = 0.82, 40Ar/36Ar = 9500, that are in good agreement with the observed values in "hot-spot" basalts (2). Therefore, this core-reservior hypothesis is a self-consistent model that can fits in multiple noble gas

  8. Theoretical Assessment of Compressibility Factor of Gases by Using Second Virial Coefficient

    Science.gov (United States)

    Mamedov, Bahtiyar A.; Somuncu, Elif; Askerov, Iskender M.

    2018-01-01

    We present a new analytical approximation for determining the compressibility factor of real gases at various temperature values. This algorithm is suitable for the accurate evaluation of the compressibility factor using the second virial coefficient with a Lennard-Jones (12-6) potential. Numerical examples are presented for the gases H2, N2, He, CO2, CH4 and air, and the results are compared with other studies in the literature. Our results showed good agreement with the data in the literature. The consistency of the results demonstrates the effectiveness of our analytical approximation for real gases.

  9. Gases for an SSC muon detector

    International Nuclear Information System (INIS)

    Christophorou, L.G.; Datskos, P.G.; Carter, J.G.; Tennessee Univ., Knoxville, TN

    1990-01-01

    Recent measurements of electron drift velocities as a function of the density-reduced electric field E/N are reported for a number of unitary gases and the mixtures CO 2 /CH 4 and NH 3 /CF 4 /Ar. Calculated values of the mean electron energy as a function of E/N are also reported for unitary gases and mixtures of CO 2 /CH 4 . 7 refs., 5 figs

  10. Flux Jacobian Matrices For Equilibrium Real Gases

    Science.gov (United States)

    Vinokur, Marcel

    1990-01-01

    Improved formulation includes generalized Roe average and extension to three dimensions. Flux Jacobian matrices derived for use in numerical solutions of conservation-law differential equations of inviscid flows of ideal gases extended to real gases. Real-gas formulation of these matrices retains simplifying assumptions of thermodynamic and chemical equilibrium, but adds effects of vibrational excitation, dissociation, and ionization of gas molecules via general equation of state.

  11. Pseudogap phenomena in ultracold atomic Fermi gases

    OpenAIRE

    Chen, Qijin; Wang, Jibiao

    2014-01-01

    The pairing and superfluid phenomena in a two-component ultracold atomic Fermi gas is an analogue of Cooper pairing and superconductivity in an electron system, in particular, the high $T_c$ superconductors. Owing to the various tunable parameters that have been made accessible experimentally in recent years, atomic Fermi gases can be explored as a prototype or quantum simulator of superconductors. It is hoped that, utilizing such an analogy, the study of atomic Fermi gases may shed light to ...

  12. La gestion des résultats des entreprises innovantes

    OpenAIRE

    Dumas, Guillaume

    2014-01-01

    Cette thèse s’intéresse à la gestion des résultats dans le cadre des entreprises innovantes. Elle est constituée de trois articles. Dans le premier, il s’agit d’examiner si les résultats des entreprises innovantes sont gérés et si le stade de développement des innovations influence cette gestion des résultats. Il apparaît que les résultats des entreprises innovantes sont gérés à la hausse. Cette gestion ne semble intervenir qu’au cours de l’activité d’innovation (c’est-à-dire lorsque les entr...

  13. Analysis of electron interactions in dielectric gases

    International Nuclear Information System (INIS)

    Olivet, Aurelio; Duque, Daniel; Vega, Lourdes F.

    2007-01-01

    We present and discuss results concerning electron interactions processes of dielectric gases and their relationship with the macroscopic behavior of these gases, in particular, with their dielectric strength. Such analysis is based on calculating energies of reactions for molecular ionization, dissociative ionization, parent negative ion formation, and dissociative electron attachment processes. We hypothesize that the estimation of the required energy for a reduced number of processes that take place in electrically stressed gases could be related to the gas' capability to manage the electron flow during an electrical discharge. All calculations were done with semiempirical quantum chemistry methods, including an initial optimization of molecular geometry and heat of formation of the dielectric gases and all of species that appear during electron interaction reactions. The performance of semiempirical methods Austin model 1 and Parametric model 3 (PM3) was compared for several compounds, PM3 being superior in most cases. Calculations performed for a sample of nine dielectric gases show that electron attachment and detachment processes occur in different energy bands that do not overlap for any value of the dielectric strength. We have also analyzed the relationship between dielectric strength and two physical properties: electron affinity and ionization energy. Calculations performed for 43 dielectric gases show no clear correlation between them, although certain guidelines for the qualitative estimation of dielectric strength can still be assessed

  14. Gases and carbon in metals. Pt. 14

    International Nuclear Information System (INIS)

    Jehn, H.; Speck, H.; Hehn, W.; Fromm, E.; Hoerz, G.

    1981-01-01

    This issue is part of a series of data on 'Gases and Carbon in Metals' which supplements the data compilation in the book 'Gase und Kohlenstoff in Metallen' (Gases and Carbon in Metals), edited by E. Fromm and E. Gebhardt, Springer-Verlag, Berlin 1976. The present survey includes results from papers published after the copy deadline and recommends critically selected data. Furthermore, it comprises a bibliography of relevant literature. For each element, firstly data on binary systems are presented, starting with hydrogen and followed by carbon, nitrogen, oxygen, and rare gases. Within one metal-metalloid system the data are listed under topics such as solubility, solubility limit, dissociation pressure of compounds, vapour pressure of volatile oxides, thermodynamic data, diffusion, transport parameters (effective valence, heat of transport), permeation of gases through metals, gas absorption and gas desorption kinetics, compound formation kinetics, precipitation kinetics, and property changes. Following the data on binary systems, the data of ternary systems are presented, beginning with systems which contain one metal and two gases or one gas and carbon and continuing with systems with two metals and one gas or carbon. (orig./GE)

  15. Routine Isotopic Analysis of {sup 235}U by Emission Spectrometry. 1. Interferometry using electrode-less discharge lamps 2. determination of the {sup 235}U/{sup 238}U ratio using a spectrograph and electrode-less lamps; Contribution a l'analyse isotopique de routine de l'uranium 235 par spectrometrie d'emission. 1. interferometrie avec des lampes a decharge sans electrode. 2. determination du rapport {sup 235}U/{sup 238}U a l'aide d'un spectrographe et avec des lampes sans electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Capitini, R; Ceccaldi, M; Leicknam, J P; Rabec, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1970-07-01

    acceptable accuracy by using a photographic plate spectrograph which has not undergone any modification; the isotopic lines used are located at 4.244 A. By carrying out a certain number of corrections necessitated by the very rich nature of the uranium spectrum, it is shown that it is possible to carry out isotopic analyses with a relative accuracy of about 2.5 to 3.0 per cent in the neighbourhood of the natural abundance; this accuracy can reach and exceed 1 per cent for samples enriched in the 235 isotope. These results, for routine determinations, are close to those which can be obtained with grating or interferometric equipment, which follows the isotopic lines simultaneously. (author) [French] I. Nous avons utilise l'appareil interferometrique ''HYPEAC'' pour le dosage de routine de l'uranium 235. Pour faciliter l'examen des echantillons non metalliques et reduire la duree des analyses, on est conduit a substituer des lampes a decharge sans electrode aux sources de lumiere a cathode creuse habituellement utilisees. La preparation hors de l'appareil de telles lampes contenant du tetrachlorure d'uranium est decrite; elle est aisee et rapide: une heure et demie environ pour chacune, plusieurs sources pouvant etre fabriquees simultanement, ce qui reduit encore la duree totale de chaque analyse. Chaque determination ne necessite que quelques milligrammes d'echantillon. Pour pallier l'effet de dereglages optiques spontanes qui empechent d'appliquer la methode de determination habituelle des abondances isotopiques, on est conduit a comparer les spectres des echantillons a ceux d'etalons, tous ces spectres etant enregistres successivement et alternativement. Une serie d'exemples de determinations portant sur plus de 150 mesures est presentee et discutee. Avec des echantillons dont les abondances sont voisines de celle de l'uranium naturel et jusqu'a 5 pour cent environ en isotope 235, la reproductibilite des mesures est voisine de 2 pour cent, la precision relative etant de

  16. Stable isotope measurement techniques for atmospheric greenhouse gases

    International Nuclear Information System (INIS)

    2002-01-01

    The technical requirements to perform useful measurements of atmospheric greenhouse gas concentrations and of their isotope ratios are of direct relevance for all laboratories engaged in this field. A meaningful interpretation of isotopes in global models on sources and sinks of CO 2 and other greenhouse gases depends on strict laboratory protocols and data quality control measures ensuring comparable data in time and space. Only with this precondition met, the isotope techniques can serve as a potentially powerful method for reducing uncertainties in the global CO 2 budgets and for tracing pathways and interaction of terrestrial, oceanic, and atmospheric pools of carbon. This publication provides four contributions describing methods for the determination of the isotopic composition of trace gases in atmospheric air and in ice cores. These contributions have been indexed separately

  17. Magmatic gases in fluid inclusions from hydrothermal ore deposits

    Energy Technology Data Exchange (ETDEWEB)

    Graney, J.; Kesler, S. (University of Michigan, MI (United States))

    1992-08-31

    In this study, magmatic gases in fluid inclusions from hydrothermal ore deposits have been analyzed. The gas composition of fluid inclusions from a wide range of extinct hydrothermal systems as represented by different ore deposit types was determined using a quadrupole mass spectrometer. Most samples used for analysis consisted of transparent quartz, although barite, jasperoid, opal, sphalerite, pyrite, chalcopyrite, and bornite were also analyzed. H2O was the dominant volatile component in fluid inclusions, and composed 95-99 mole percent of the inclusion fluid. CO2 comprised most of the remaining volatile component and the other gases were generally present in amounts smaller than 0.1 mole percent. Analysis from porphyry and acid-sulfate deposits, in which magmatic gas contributions are considered to be largest, plotted closest to the fumarolic gas compositions. These inclusion fluid volatile component comparisons have shown that there are systematic differences in inclusion fluids from different hydrothermal systems. 9 refs., 3 figs.

  18. Membrane methods for separation of radioactive noble gases

    International Nuclear Information System (INIS)

    Bekman, I.N.; Bozhenko, E.I.; Ievlev, A.L.; Kazankin, Yu.N.; Nikonov, V.N.; Teplyakov, V.V.; Shvyryaev, A.A.

    1984-01-01

    Using the different ial permeability method at different temperatures (20-120 deg C) transport characteristics of inert gases, N 2 , O 2 , CH 4 , CQ 2 and H 2 as the main components of waste gases in homogeneous films of arylate-siloxane block-copolymer (silar) of different composition, as well as of its components - polydimethylsiloxane (PDMS) and polyarylate, have been measured. Dependences of diffusion and permeability coefficients on inert gas atom dimensions, and solubility coefficient - on strength constant of the Lennard-Jones potential, are analyzed. It is shown that selectivity of silar gas permbility is determined by the properties of siloxane component, and the values of permeability coefficients decrease with the increase of polyarylate block part due to dominating decrease in diffusion coefficients as compared with solubility coefficients

  19. Measurement of biocarbon in flue gases using 14C

    Energy Technology Data Exchange (ETDEWEB)

    Haemaelaeinen, K.M.; Jungner, H.; Antson, O.; Rasanen, J.; Tormonen, K.; Roine, J. [University of Helsinki, Helsinki (Finland). Radiocarbon Dating Laboratory

    2007-07-01

    A preliminary investigation of the biocarbon fraction in carbon dioxide emissions of power plants using both fossil- and biobased fuels is presented. Calculation of the biocarbon fraction is based on radiocarbon content measured in power plant flue gases. Samples were collected directly from the chimneys into plastic sampling bags. The C-14 content in CO{sub 2} was measured by accelerator mass spectrometry (AMS). Flue gases from power plants that use natural gas, coal, wood chips, bark, plywood residue, sludge from the pulp factory, peat, and recovered fuel were measured. Among the selected plants, there was one that used only fossil fuel and one that used only biofuel; the other investigated plants burned mixtures of fuels. The results show that C-14 measurement provides the possibility to determine the ratio of bio and fossil fuel burned in power plants.

  20. Des dispositions responsables à prendre pour la protection des ...

    African Journals Online (AJOL)

    En considérant l'effet néfaste des maladies, des parasites, du changement climatique et d'autres facteurs environnementaux (les OGM par exemple) sur la survie des abeilles, la baisse de leurs populations dans certaines parties du monde ne saurait être attribuée aux seules pesticides. En plus, l'impact de ces derniers sur ...

  1. Aspects des Onychomycoses chez des patients camerounais de ...

    African Journals Online (AJOL)

    ... biologiques et évolutifs des onychomycoses chez des patients camerounais. Méthode : Il s'agit d'une étude rétrospective et descriptive menée de mars 2011 à mars 2014 dans l'unité de dermatologie de l'hôpital général de Douala (HGD), incluant des patients chez lesquels le diagnostic d'onychomycose avait été posé.

  2. Results of the working group on the division by four of greenhouse gases emissions in France, at the horizon of 2050, called ''factor 4''. DGEMP- Observatory of the energy; Les travaux du groupe de travail sur la division par quatre des emissions de gaz a effet de serre de la france, a l'horizon 2050, dit ''facteur 4''. DGEMP-Observatoire de l'Energie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This group, created by the french Government in march 2005, aims to evaluate the different possibilities to reach the objective of division by four the greenhouse gases emissions. This document presents some recalls on the climatic change and the situation today, the positions of the France and the foreign and the conclusions and the recommendations of the group. (A.L.B.)

  3. Results of the working group on the division by four of greenhouse gases emissions in France, at the horizon of 2050, called ''factor 4''. DGEMP- Observatory of the energy; Les travaux du groupe de travail sur la division par quatre des emissions de gaz a effet de serre de la france, a l'horizon 2050, dit ''facteur 4''. DGEMP-Observatoire de l'Energie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This group, created by the french Government in march 2005, aims to evaluate the different possibilities to reach the objective of division by four the greenhouse gases emissions. This document presents some recalls on the climatic change and the situation today, the positions of the France and the foreign and the conclusions and the recommendations of the group. (A.L.B.)

  4. Noble gases and the early history of the Earth: Inappropriate paradigms and assumptions inhibit research and communication

    Science.gov (United States)

    Huss, G. R.; Alexander, E. C., Jr.

    1985-01-01

    The development of models as tracers of nobel gases through the Earth's evolution is discussed. A new set of paradigms embodying present knowledge was developed. Several important areas for future research are: (1) measurement of the elemental and isotopic compositions of the five noble gases in a large number of terrestrial materials, thus better defining the composition and distribution of terrestrial noble gases; (2) determinations of relative diffusive behavior, chemical behavior, and the distribution between solid and melt of noble gases under mantle conditions are urgently needed; (3) disequilibrium behavior in the nebula needs investigation, and the behavior of plasmas and possible cryotrapping on cold nebular solids are considered.

  5. Usages des TIC et socialisation professionnelle des enseignants-chercheurs

    OpenAIRE

    Lavielle-Gutnik, Nathalie; Massou, Luc

    2013-01-01

    En prenant appui sur une nouvelle analyse des données recueillies dans l’enquête Tec-Meus (2008-2011, MSH Lorraine) sur la place accordée par des enseignants-chercheurs en sciences humaines et sociales aux technologies de l’information et de la communication (TIC) dans leur activité d’enseignement, nous souhaitons nous focaliser dans cet article sur la compréhension des processus de socialisation professionnelle en jeu dans leur usage déclaré des TIC. Par socialisation professionnelle, nous e...

  6. A modification of the method for determining current efficiency of aluminium electrolytic cells; Modification de la methode permettant de determiner le rendement des cuves dans la production d'aluminium par electrolyse; Izmenenie metoda opredeleniya ehffektivnosti toka v alyuminievykh ehlektroliticheskikh bakakh; Modificacion del metodo para determinar el rendimiento de las celdas utilizadas en la produccion de aluminio por electrolisis

    Energy Technology Data Exchange (ETDEWEB)

    Pradzynski, A [Institute of Basic Technical Problems, Polish Academy of Sciences. Warsaw (Poland); Orman, Z [Institute of Nonferrous Metals, Gliwice (Poland)

    1962-01-15

    The method for determining the current efficiency of aluminium electrolytic cells described first by REMPEL et al. was improved by BOZOKY et al. by using the radioisotope Au{sup 198}. In that work, master alloys of aluminium with Au{sup 198} were made, and samples of this were measured by means of a G-M tube with a lead absorber inserted between the tube and the sample. In this work the specific activity of the master alloy was reduced by diluting with a known quantity of pure aluminium. In that way samples of diluted master alloy and samples taken from the electrolytic cell were of the same order of specific activity and could be measured without any absorber. Radioactivation analysis was employed in order to facilitate the application of the above method in aluminium plants and to avoid all restrictions and dangers connected with the handling of unsealed radioactive sources outside special radioisotope laboratories. Inactive gold was introduced into the master alloy and into the smelting bath in the electrolytic cell. The concentration of gold in samples of both the master alloy and the smelt was then measured after irradiating the samples in a nuclear reactor. (author) [French] La methode permettant de determiner le rendement des cuves a aluminium, exposee tout d'abord par Rempel et al., a ete perfectionnee par Bozoky et al. qui ont utilise a cet effet le radioisotope or-198. Des alliages types d'aluminium et d'or-198 ont ete prepares et des echantillons mesures au moyen d'un tube Geiger-Muller, un absorbeur en plomb etant insere entre le tube et l'echantillon. Les auteurs du memoire ont mesure l'activite specifique de l'alliage type apres dilution dans une quantite connue d'aluminium pur. Les echantillons d'alliage type ainsi dilue et les echantillons preleves dans la cuve electrolytique ayant alors une activite specifique du meme ordre, il a ete possible de la mesurer sans aucun absorbeur. Les auteurs ont procede a des essais d'analyse par radioactivation afin

  7. Concept of Heat Recovery from Exhaust Gases

    Science.gov (United States)

    Bukowska, Maria; Nowak, Krzysztof; Proszak-Miąsik, Danuta; Rabczak, Sławomir

    2017-10-01

    The theme of the article is to determine the possibility of waste heat recovery and use it to prepare hot water. The scope includes a description of the existing sample of coal-fired boiler plant, the analysis of working condition and heat recovery proposals. For this purpose, a series of calculations necessary to identify the energy effect of exhaust temperature decreasing and transferring recovery heat to hot water processing. Heat recover solutions from the exhaust gases channel between boiler and chimney section were proposed. Estimation for the cost-effectiveness of such a solution was made. All calculations and analysis were performed for typical Polish conditions, for coal-fired boiler plant. Typicality of this solution is manifested by the volatility of the load during the year, due to distribution of heat for heating and hot water, determining the load variation during the day. Analysed system of three boilers in case of load variation allows to operational flexibility and adaptation of the boilers load to the current heat demand. This adaptation requires changes in the operating conditions of boilers and in particular assurance of properly conditions for the combustion of fuel. These conditions have an impact on the existing thermal loss and the overall efficiency of the boiler plant. On the boiler plant efficiency affects particularly exhaust gas temperature and the excess air factor. Increasing the efficiency of boilers plant is possible to reach by following actions: limiting the excess air factor in coal combustion process in boilers and using an additional heat exchanger in the exhaust gas channel outside of boilers (economizer) intended to preheat the hot water.

  8. Relation of Hydrogen and Methane to Carbon Monoxide in Exhaust Gases from Internal-Combustion Engines

    Science.gov (United States)

    Gerrish, Harold C; Tessmann, Arthur M

    1935-01-01

    The relation of hydrogen and methane to carbon monoxide in the exhaust gases from internal-combustion engines operating on standard-grade aviation gasoline, fighting-grade aviation gasoline, hydrogenated safety fuel, laboratory diesel fuel, and auto diesel fuel was determined by analysis of the exhaust gases. Two liquid-cooled single-cylinder spark-ignition, one 9-cylinder radial air-cooled spark-ignition, and two liquid-cooled single-cylinder compression-ignition engines were used.

  9. Influence of the gray gases number in the weighted sum of gray gases model on the radiative heat exchange calculation inside pulverized coal-fired furnaces

    Directory of Open Access Journals (Sweden)

    Crnomarković Nenad Đ.

    2016-01-01

    Full Text Available The influence of the number of gray gases in the weighted sum in the gray gases model on the calculation of the radiative heat transfer is discussed in the paper. A computer code which solved the set of equations of the mathematical model describing the reactive two-phase turbulent flow with radiative heat exchange and with thermal equilibrium between phases inside the pulverized coal-fired furnace was used. Gas-phase radiative properties were determined by the simple gray gas model and two combinations of the weighted sum of the gray gases models: one gray gas plus a clear gas and two gray gases plus a clear gas. Investigation was carried out for two values of the total extinction coefficient of the dispersed phase, for the clean furnace walls and furnace walls covered by an ash layer deposit, and for three levels of the approximation accuracy of the weighting coefficients. The influence of the number of gray gases was analyzed through the relative differences of the wall fluxes, wall temperatures, medium temperatures, and heat transfer rate through all furnace walls. The investigation showed that there were conditions of the numerical investigations for which the relative differences of the variables describing the radiative heat exchange decrease with the increase in the number of gray gases. The results of this investigation show that if the weighted sum of the gray gases model is used, the complexity of the computer code and calculation time can be reduced by optimizing the number of gray gases. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018: Increase in energy and ecology efficiency of processes in pulverized coal-fired furnace and optimization of utility steam boiler air preheater by using in-house developed software tools

  10. Direction des Publications

    African Journals Online (AJOL)

    Synthese

    Unité de Recherche des Matériaux et des Energies Renouvelables (U.R.M.E.R). Université Abou –Baker Belkaid B.p : 119 Tlemcen 13000 Algerie. 2. Unité de Développement de la Technologie Du Silicium. UDTS, BP 399, Alger, Algérie. Accepté le : 08/06/2011. صخلم. داوﻣﻟا نﻣ ﻲﺗﻟا ﺔﺻﺎﺧو ،ﺔﻋﺎﻧﺻ يأ رﯾوطﺗ ﻲﻓ ﺎﯾﺳﯾﺋر ﻼﻣﺎﻋ ةرﯾﺧﻷا تاوﻧﺳﻟا ...

  11. Mykotische Infektionen des Penis

    Directory of Open Access Journals (Sweden)

    Mayser P

    1999-01-01

    Full Text Available Die häufigste mykotische Infektion des Penis stellt die Balanitis/Balonoposthitis durch Candida albicans dar. Sie weist eine steigende Inzidenz auf und scheint vornehmlich durch Genitalverkehr übertragen zu werden. Penile Infektionen durch Dermatophyten sind sehr selten, obwohl die Tinea inguinalis zu den häufigeren Erkrankungen zählt. Eine Mitbeteiligung des Penis im Rahmen von Systemmykosen kennzeichnet zumeist ein schwer verlaufende Erkrankung. Ursächlich kann beim immunoinkompetenten Patienten nahezu jeder Erreger in Frage kommen. Biopsie sowie Gewebekultur aus den meist ulzerativen Veränderungen können die Diagnose sichern. Die meisten superfiziellen Infektionen sprechen zufriedenstellend auf eine topische antimykotische Behandlung an, insbesondere wenn Provokationsfaktoren und die Möglichkeit der sexuellen Transmission berücksichtigt werden. Ausgedehnte Infektionen durch Dermatophyten, Hefen und natürlich systemische Infektionen erfordern eine systemische antimykotische Therapie.

  12. Chimie des processus biologiques

    OpenAIRE

    Fontecave, Marc

    2014-01-01

    Cours : Chimie biologique radicalaire : de l’origine de l’ADN au métabolisme d’aujourd’hui Il est généralement admis que les radicaux libres, espèces chimiques très réactives, sont des poisons pour les systèmes vivants qui ont élaboré des mécanismes efficaces pour s’en protéger et s’en débarrasser lorsqu’ils viennent à se former, par accident. Par exemple ce qu’on appelle communément le stress oxydant est une situation caractérisée par une accumulation de radicaux issus de l’oxygène moléculai...

  13. The Origins of dEs

    Science.gov (United States)

    Skillman, Evan D.

    With the new discoveries that some dEs are rotationally supported and that dIs may show a large variety in star formation histories, the perceived relationships between these two families of galaxies are changing. There are at least three viable channels for the origin of dwarf elliptical galaxies with strong observational evidence that support their reality. I will discuss the observational evidence for each of these channels and the likely physical processes which determine each channel.

  14. La cogestion des Ressources naturelles

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'eau, le sol, les nutriments, la lumière du soleil — ce sont des choses de la vie. .... habitent encore ces régions, soit de 9 % à 14 % de la population mondiale. ...... La guerre civile a fait vivre au Cambodge des années de chaos, d'anarchie et ...... et les allégeances politiques sont des facteurs qu'il est impossible d'ignorer.

  15. Des Ogle's old stump

    International Nuclear Information System (INIS)

    Jones, M.; Sutton, D.; Wallace, R.

    1998-01-01

    On 17 October 1997 Sylvia Bryan of RD4 Kaitaia wrote to 'Dear Somebody-Everybody' at the Anthropology Department, University of Auckland, urging further examination of an adzed stump found by Des Ogle during planting out of the Te Aupouri forest. The authors have since sought out relevant information and present it here for the interests of our readers. (author). 7 refs., 1 fig

  16. Determination of anisotropic velocity model by reflection tomography of compression and shear modes; Determination de modele de vitesse anisotrope par tomographie de reflexion des modes de compression et de cisaillement

    Energy Technology Data Exchange (ETDEWEB)

    Stopin, A.

    2001-12-01

    As the jump from 2D to 3D, seismic exploration lives a new revolution with the use of converted PS waves. Indeed PS converted waves are proving their potential as a tool for imaging through gas; lithology discrimination; structural confirmation; and more. Nevertheless, processing converted shear data and in particular determining accurate P and S velocity models for depth imaging of these data is still a challenging problem, especially when the subsurface is anisotropic. To solve this velocity model determination problem we propose to use reflection travel time tomography. In a first step, we derive a new approximation of the exact phase velocity equation of the SV wave in anisotropic (TI) media. This new approximation is valid for non-weak anisotropy and is mathematically simpler to handle than the exact equation. Then, starting from an isotropic reflection tomography tool developed at Lt-'P, we extend the isotropic bending ray tracing method to the anisotropic case and we implement the quantities necessary for the determination of the anisotropy parameters from the travel time data. Using synthetic data we then study the influence of the different anisotropy parameters on the travel times. From this analysis we propose a methodology to determine a complete anisotropic subsurface model (P and S layer velocities, interface geometries, anisotropy parameters). Finally, on a real data set from the Gulf of Mexico we demonstrate that this new anisotropic reflection tomography tool allows us to obtain a reliable subsurface model yielding kinematically correct and mutually coherent PP and PS images in depth; such a result could not be obtained with an isotropic velocity model. Similar results are obtained on a North Sea data set. (author)

  17. Determination of anisotropic velocity model by reflection tomography of compression and shear modes; Determination de modele de vitesse anisotrope par tomographie de reflexion des modes de compression et de cisaillement

    Energy Technology Data Exchange (ETDEWEB)

    Stopin, A

    2001-12-01

    As the jump from 2D to 3D, seismic exploration lives a new revolution with the use of converted PS waves. Indeed PS converted waves are proving their potential as a tool for imaging through gas; lithology discrimination; structural confirmation; and more. Nevertheless, processing converted shear data and in particular determining accurate P and S velocity models for depth imaging of these data is still a challenging problem, especially when the subsurface is anisotropic. To solve this velocity model determination problem we propose to use reflection travel time tomography. In a first step, we derive a new approximation of the exact phase velocity equation of the SV wave in anisotropic (TI) media. This new approximation is valid for non-weak anisotropy and is mathematically simpler to handle than the exact equation. Then, starting from an isotropic reflection tomography tool developed at Lt-'P, we extend the isotropic bending ray tracing method to the anisotropic case and we implement the quantities necessary for the determination of the anisotropy parameters from the travel time data. Using synthetic data we then study the influence of the different anisotropy parameters on the travel times. From this analysis we propose a methodology to determine a complete anisotropic subsurface model (P and S layer velocities, interface geometries, anisotropy parameters). Finally, on a real data set from the Gulf of Mexico we demonstrate that this new anisotropic reflection tomography tool allows us to obtain a reliable subsurface model yielding kinematically correct and mutually coherent PP and PS images in depth; such a result could not be obtained with an isotropic velocity model. Similar results are obtained on a North Sea data set. (author)

  18. Development of speciation analysis for selenium in nutritional supplements by the determination of the seleno-methionine; Developpement de l'analyse de speciation du selenium dans des complements alimentaires par la determination de la selenomethionine

    Energy Technology Data Exchange (ETDEWEB)

    Sannac, S.; Labarraque, G.; Fisicaro, P. [Laboratoire National de Metrologie et d' Essai (LNE), 75 - Paris (France); Sannac, S.; Pannier, F.; Potin-Gautier, M. [Pau Univ. et des Pays de l' Adour, CNRS/UMR 5254, Lab. de Chimie Analytique, Bio-Inorganique et Environnement (IPREM), 64 (France)

    2009-07-01

    The development of a reference method in analytical chemistry is presented. Liquid chromatography with inductively coupled plasma mass spectrometry is employed to perform in speciation analysis. Applications are developed for the determination of seleno-methionine in nutritional supplements. The use of isotope dilution, a primary method, is required to enable measurement traceability. Method validation is ensured by the study of a certified reference material. (authors)

  19. Standard model parameters determination and validity tests in Z{sup 0} hadronic disintegrations; Determination des parametres du modele standard et tests de sa validite dans les desintegrations hadroniques du Z{sup 0}

    Energy Technology Data Exchange (ETDEWEB)

    Todorov, T

    1993-05-01

    This thesis describes the determination of the electroweak parameters from the measurements of the total hadronic cross-section by the DELPHI experiment at LEP-I. The analysed data was taken in the years 1991 and 1992; a previous analysis of the data taken in 1990 is included in the final fits. The first part of the thesis describes the interest of the measurement of the Z{sup 0} resonance parameters in the framework of the Standard Model as well as their implications for alternative models. The Standard Model predictions are described in some detail, and their precision is estimated. Then follows a brief description of the LEP collider, of the measurement of the collision energy, and of the experimental setup. A chapter is devoted to the description of the luminosity measurement, essential for the determination of total cross-sections. The measurement of the hadronic cross-section (event selection, study of backgrounds, study of sources of systematic uncertainties) is described in detail in the next chapter. Then follows a description of the method of the extraction of the resonance parameters, and a discussion of the uncertainties in their determination. The values obtained are interpreted in the framework of the Standard Model, as well as in the framework of some more general theories. Finally, the event generator for hadron production in two-photon collisions is described in the appendix. (author). 69 refs., 51 figs., 9 tabs., 1 ann.

  20. Grundlagen des Tissue Engineering

    Science.gov (United States)

    Mayer, Jörg; Blum, Janaki; Wintermantel, Erich

    Die Organtransplantation stellt eine verbreitete Therapie dar, um bei krankheitsoder unfallbedingter Schädigung eines Organs die Gesamtheit seiner Funktionen wieder herzustellen, indem es durch ein Spenderorgan ersetzt wird. Organtransplantationen werden für die Leber, die Niere, die Lunge, das Herz oder bei schweren grossflächigen Verbrennungen der Haut vorgenommen. Der grosse apparative, personelle und logistische Aufwand und die Risiken der Transplantationschirurgie (Abstossungsreaktionen) sowie die mangelnde Verfügbarkeit von immunologisch kompatiblen Spenderorganen führen jedoch dazu, dass der Bedarf an Organtransplantaten nur zu einem sehr geringen Teil gedeckt werden kann. Sind Spenderorgane nicht verfügbar, können in einzelnen Fällen lebenswichtige Teilfunktionen, wie beispielsweise die Filtrationsfunktion der Niere durch die Blutreinigung mittels Dialyse ersetzt oder, bei mangelnder Funktion der Bauchspeicheldrüse (Diabetes), durch die Verabreichung von Insulin ein normaler Zustand des Gesamtorganismus auch über Jahre hinweg erhalten werden. Bei der notwendigen lebenslangen Anwendung apparativer oder medikamentöser Therapie können für den Patienten jedoch häufig schwerwiegende, möglicherweise lebensverkürzende Nebenwirkungen entstehen. Daher werden in der Forschung Alternativen gesucht, um die Funktionen des ausgefallenen Organs durch die Implantation von Zellen oder in vitro gezüchteten Geweben möglichst umfassend wieder herzustellen. Dies erfordert biologisch aktive Implantate, welche die für den Stoffwechsel des Organs wichtigen Zellen enthalten und einen organtypischen Stoffwechsel entfalten.

  1. Dictionnaire des risques psychosociaux

    CERN Document Server

    Zawieja, Philippe

    2014-01-01

    Stress, suicide, harcèlement, épuisement professionnel, workaholism... Au-delà de la souffrance qu'elles désignent, ces notions souvent récentes constituent une approche inédite, et demandent à mieux être comprises, dans leur ensemble et isolément. C'est tout l'enjeu de ce dictionnaire, pionnier en son genre. Le lecteur y trouvera représentés, avec les 314 entrées (rédigées par 251 contributeurs) qui le composent, tous les champs disciplinaires s'intéressant à la souffrance au travail : psychologie du travail et des organisations, psychologie sociale et psychosociologie, psychanalyse, psychopathologie et psychiatrie, ergonomie, sociologie du travail et des organisations, médecine du travail, droit du travail et de la sécurité sociale, sciences de gestion, philosophie... Y sont détaillés les principaux concepts, notions, approches, méthodes, théories, outils, études, etc., ayant cours dans l'étude des risques psychosociaux, mais aussi certaines professions emblématiques (infirmières,...

  2. Le vernis des apparences

    Directory of Open Access Journals (Sweden)

    Grazia Nicosia

    2010-04-01

    Full Text Available Le but de cet article est de comprendre l’incidence sémiotique du nettoyage d’un tableau ainsi que la résultante cognitive induite sur l’observateur. Cette étude confronte l’analyse des phénomènes visuels engendrés par le jaunissement du vernis et son retrait, à des entretiens réalisés à dessein. Le retrait d’un vernis jauni change considérablement l’image. L’heure, le climat, la saison et l’activité même des personnages s’en trouvent ainsi modifié. La patine peut être perçue, soit comme un obstacle à l’exploration, soit pour ceux qui l’apprécient, comme le medium d’une relation plus intime entre l’œuvre et l’observateur.The purpose of this article is to understand the semiotic impact of the cleaning of a painting and the cognitive effects induced on the observer. This study analyses conjointly the visual phenomenon generated by yellowing varnish and its removal and controlled interviews of observers.The removal of yellowing varnish modifies considerably the perception of the picture. Daytime, climate, season and characters activities are modified. The patina may be perceived either as an obstacle to the painting exploration, or, for those who appreciate it, as a medium for a closer relationship between the painting and the observer.

  3. Ventilation of radioactive enclosures; Ventilation des enceintes radioactives

    Energy Technology Data Exchange (ETDEWEB)

    Caminade, F; Laurent, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-07-01

    Mechanical, physical and chemical manipulations on radioactive products must be carried out in properly ventilated enclosed places. The air extracted can only be discharged into the atmosphere after a correct filtration. The power of the ventilation systems is a function of the dimensions and purpose of the enclosure? The choice of types of filter is determined by the physical state and chemical nature of the radioactive materials to be manipulated. This study deals with the individual equipment of small installations: glove boxes, manipulation boxes with outside control and, if necessary, production chambers (maximum useful volume: 5 m{sup 3}). The performances of three types of 'ventilators', and the modifications provided by the addition of filters, are measured and compared. (author) [French] Les manipulations oceaniques, physiques et chimiques sur des produits radioactifs doivent s'effectuer dans des enceintes convenablement ventilees. L'air extrait ne peut etre rejete dans l'atmosphere qu'apres une filtration correcte. La puissance des installations de ventilation est fonction des dimensions de l'enceinte et de son utilisation. Le choix des types de filtres est determine par l'etat physique et la nature ehimique des corps radioactifs manipules. Notre etude porte sur l'equipement individuel d'installations de petites dimensions: boites a gants, boites a pinces et, a la rigueur, enceintes de production (volume maximum utilisable 5 m{sup 3}). Nous mesurons et comparons les performances de trois types de 'ventilateurs' et les modifications apportees par l'adjonction de filtres. (auteur)

  4. The activity of {gamma}-emitters as measured by ionisation chambers the determination of the specific emission coefficient {gamma} for some radio-elements (1961); Mesure de l'activite des emetteurs {gamma} par chambre d'ionisation. Determination du coefficient specifique d'emission {gamma} de quelques radioelements (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Engelmann, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-06-15

    chambre d'ionisation gamma, permettant soit de mesurer l'activite de sources radioactives, soit de determiner le coefficient specifique d'emission {gamma} (ou coefficient K) d'un radioelement determine. Les chambres d'ionisation etudiees appartiennent a deux categories: chambre-cavites en graphite, et chambres a puits {gamma}. Pour les mesures effectuees avec une chambre-cavite, on a calcule les differents facteurs do correction dont il faut tenir compte, en particulier les corrections de geometrie et d'hygrometrie. Les corrections d'absorption et d'autoabsorption ont amene a introduire la notion 'd'energie efficace {gamma}' d'un radioelement. Dans le cas des chambres a puits, on a montre qu'une forme appropriee des 'electrodes permettait d'ameliorer leurs performances. Une des chambres decrites permet la mesure des emetteurs {beta} par le rayonnement de freinage associe. Pour la determination du coefficient K de quelques radioelements, il s'est avere commode d'utiliser une chambre a puits a parois de graphite, les mesures etant effectuees par comparaison avec un etalon de radium. La validite de la methode a ete verifiee avec quelques radioelements pour lesquels la valeur du coefficent K etait deja bien connue ({sup 24}Na, {sup 60}Co, {sup 131}I, {sup 198}Au). Pour d'autres radioelements, les valeurs suivantes ont ete obtenues (exprimees en r cm{sup 3} mc{sup 1} h{sup 1}): {sup 51}Cr: 0,18; {sup 56}Mn: 8,8; {sup 65}Zn: 3,05; {sup 124}Sb: 9,9; {sup 134}Cs: 9,3; {sup 137}Cs: 3,35; {sup 141}Ce: 0,46; {sup 170}Tm: 0,023; {sup 192}Ir: 24,9; {sup 203}Hg: 1,18; Ces valeurs ont ete corrigees de la contribution qu'apportent a la dose les rayonnements de fluorescence eventuellement emis par la source, sauf dans le cas du {sup 170}Tm. Dans la derniere partie de ce travail, on a compare les performances des differents dispositifs electrometriques utilises. (auteur)

  5. The activity of {gamma}-emitters as measured by ionisation chambers the determination of the specific emission coefficient {gamma} for some radio-elements (1961); Mesure de l'activite des emetteurs {gamma} par chambre d'ionisation. Determination du coefficient specifique d'emission {gamma} de quelques radioelements (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Engelmann, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-06-15

    'ionisation gamma, permettant soit de mesurer l'activite de sources radioactives, soit de determiner le coefficient specifique d'emission {gamma} (ou coefficient K) d'un radioelement determine. Les chambres d'ionisation etudiees appartiennent a deux categories: chambre-cavites en graphite, et chambres a puits {gamma}. Pour les mesures effectuees avec une chambre-cavite, on a calcule les differents facteurs do correction dont il faut tenir compte, en particulier les corrections de geometrie et d'hygrometrie. Les corrections d'absorption et d'autoabsorption ont amene a introduire la notion 'd'energie efficace {gamma}' d'un radioelement. Dans le cas des chambres a puits, on a montre qu'une forme appropriee des 'electrodes permettait d'ameliorer leurs performances. Une des chambres decrites permet la mesure des emetteurs {beta} par le rayonnement de freinage associe. Pour la determination du coefficient K de quelques radioelements, il s'est avere commode d'utiliser une chambre a puits a parois de graphite, les mesures etant effectuees par comparaison avec un etalon de radium. La validite de la methode a ete verifiee avec quelques radioelements pour lesquels la valeur du coefficent K etait deja bien connue ({sup 24}Na, {sup 60}Co, {sup 131}I, {sup 198}Au). Pour d'autres radioelements, les valeurs suivantes ont ete obtenues (exprimees en r cm{sup 3} mc{sup 1} h{sup 1}): {sup 51}Cr: 0,18; {sup 56}Mn: 8,8; {sup 65}Zn: 3,05; {sup 124}Sb: 9,9; {sup 134}Cs: 9,3; {sup 137}Cs: 3,35; {sup 141}Ce: 0,46; {sup 170}Tm: 0,023; {sup 192}Ir: 24,9; {sup 203}Hg: 1,18; Ces valeurs ont ete corrigees de la contribution qu'apportent a la dose les rayonnements de fluorescence eventuellement emis par la source, sauf dans le cas du {sup 170}Tm. Dans la derniere partie de ce travail, on a compare les performances des differents dispositifs electrometriques utilises. (auteur)

  6. Harmonische Reduktion des linken Ventrikels

    OpenAIRE

    Atila, M. (Mehmet)

    2005-01-01

    In der vorliegenden Arbeit wurde die harmonische Reduktion des linken Ventrikels am Modell des ausgewachsenen Hausschweins, unter Verwendung von Saugkappen variabler Größe untersucht. In 10 Schweinen mit Herzen normaler Größe und Funktion wurde eine Saugkappe, in Größe und Form an das abzufaltende Wandsegment angepasst, auf die epikardiale Oberfläche des schlagenden Herzens gesetzt. Wir führten Messungen der linksventrik. und der pulmonalart. Drücke, des ventrikulären Durchmessers und der Her...

  7. Méthode rapide de caractérisation des roches mètres, de leur potentiel pétrolier et de leur degré d'évolution Rapid Method for Source Rocks Characrerysation and for Determination of Petroleum Potential and Degree of Evolution

    Directory of Open Access Journals (Sweden)

    Espitalié J.

    2006-11-01

    Full Text Available Les études fondamentales réalisées sur les kérogènes à l'aide de diverses méthodes physico-chimiques d'analyse ont permis de mettre au point une méthode et un appareillage adaptés à l'exploration pétrolière. On expose dans cet article la mise au point de cette méthode et on montre, à l'aide des paramètres qu'elle permet d'obtenir, ses applications dans le domaine de l'exploration pétrolière - reconnaissance des différents types de roche mère et de leur potentiel pétrolier; - caractérisation de leur degré d'évolution (zone à huile - zone à gaz. On montre aussi que cette méthode convient particulièrement bien à l'estimation du rendement en huile des roches bitumineuses et à l'étude de la qualité et du rang des charbons. Fundamental research on kerogens by different physico-chemical analysis methods have led to the development of a method and equipment suited for petroleum exploration. This article describes the development of this method and, by means of the parameters it determines, shows how it con be applied in the field of petroleum exploration - exploring different types of source rock and their petroleum potential ; - characterizing their degree of evolution (ail zone/gas zone. This method is also shown ta be particularly suited for estimating the oil yield of cil shales and investigating the quality and classification of cool.

  8. Determining

    Directory of Open Access Journals (Sweden)

    Bahram Andarzian

    2015-06-01

    Full Text Available Wheat production in the south of Khuzestan, Iran is constrained by heat stress for late sowing dates. For optimization of yield, sowing at the appropriate time to fit the cultivar maturity length and growing season is critical. Crop models could be used to determine optimum sowing window for a locality. The objectives of this study were to evaluate the Cropping System Model (CSM-CERES-Wheat for its ability to simulate growth, development, grain yield of wheat in the tropical regions of Iran, and to study the impact of different sowing dates on wheat performance. The genetic coefficients of cultivar Chamran were calibrated for the CSM-CERES-Wheat model and crop model performance was evaluated with experimental data. Wheat cultivar Chamran was sown on different dates, ranging from 5 November to 9 January during 5 years of field experiments that were conducted in the Khuzestan province, Iran, under full and deficit irrigation conditions. The model was run for 8 sowing dates starting on 25 October and repeated every 10 days until 5 January using long-term historical weather data from the Ahvaz, Behbehan, Dezful and Izeh locations. The seasonal analysis program of DSSAT was used to determine the optimum sowing window for different locations as well. Evaluation with the experimental data showed that performance of the model was reasonable as indicated by fairly accurate simulation of crop phenology, biomass accumulation and grain yield against measured data. The normalized RMSE were 3%, 2%, 11.8%, and 3.4% for anthesis date, maturity date, grain yield and biomass, respectively. Optimum sowing window was different among locations. It was opened and closed on 5 November and 5 December for Ahvaz; 5 November and 15 December for Behbehan and Dezful;and 1 November and 15 December for Izeh, respectively. CERES-Wheat model could be used as a tool to evaluate the effect of sowing date on wheat performance in Khuzestan conditions. Further model evaluations

  9. Developpement d'une methode calorimetrique de mesure des pertes ac pour des rubans supraconducteurs a haute temperature critique

    Science.gov (United States)

    Dolez, Patricia

    supraconductrice qui restent fixes a l'interface coeur-enveloppe, et le revetement en alliage d'argent. L'interet d'une methode calorimetrique par rapport a la technique electrique, plus rapide, plus sensible et maintenant fiable, reside dans la possibilite de realiser des mesures de pertes ac dans des environnements complexes, reproduisant la situation presente par exemple dans un cable de transport d'energie ou dans un transformateur. En particulier, la superposition d'un courant dc en plus du courant ac habituel nous a permis d'observer experimentalement, pour la premiere fois a notre connaissance, un comportement particulier des pertes ac en fonction de la valeur du courant dc decrit theoriquement par LeBlanc. Nous avons pu en deduire la presence d'un courant d'ecrantage Meissner de 16 A, ce qui nous permet de determiner les conditions dans lesquelles une reduction du niveau de pertes ac pourrait etre obtenue par application d'un courant dc, phenomene denomme "vallee de Clem".

  10. Détermination automatique de l'indice d'octane et de la composition des reformats par chromatographie en phase gazeuse Automatic Determination of Reformate Octane Number and Composition by Gas Chromatography

    Directory of Open Access Journals (Sweden)

    Petroff N.

    2006-11-01

    Full Text Available Utilisant des analyses par chromatographie en phase gazeuse, diverses méthodes ont été testées pour calculer l'indice d'octane de reformats. L'une d'elles s'est imposée par la simplicité de l'appareillage, ses possibilités d'automatisation et son adéquation à des échantillons provenant de charges différentes. Cette étude décrit les conditions opératoires de la méthode chromatographique optimisées pour les réformes, en vue d'obtenir des valeurs calculées de l'indice d'octane (IO dit Recherche différant de moins de un point des valeurs mesurées sur un moteur CFR selon la norme ASTM/D2699 (NF MO7026. L'analyse chromatographique est faite sur une colonne capillaire fonctionnant en température programmée. Le traitement des données est réalisé par un logiciel qui assure àla fois l'identification des constituants et le calcul de l'indice d'octane, à partir des données chromatographiques standard (temps de rétention et surface des pics. Les résultats obtenus portent sur une soixantaine de reformats divers. La fiabilité de la méthode d'identification, la répétabilité et la reproductibilité des valeurs de IO calculés sont démontrées. Ces résultats permettent d'envisager l'exploitation de la méthode en sortie d'unité. Various methods were tested by gas chromatography analysis for calculating the octane number of reformates. One of them was superior because of the simplicity of its equipment, its possibilities of automation and its suitability for samples coming from different feeds. This article describes the operating conditions of the optimized chromatographic method for reformates with a view to obtaining calculated values of the so-called Researchoctane number (RON different by at least one point from the values measured with a CFR engine according to the ASTM/D2699 standard. Chromatographic analysis is performed in a capillary column operating with programmedtemperature. Data processing is done with a software

  11. Determining the climate impact of the German government's Integrated Energy and Climate Programme (IEKP) and proposing a plan to continuously monitor its climate impact. Summary; Ermittlung der Klimaschutzwirkung des Integrierten Energie- und Klimaschutzprogramms der Bundesregierung IEKP und Vorschlag fuer ein Konzept zur kontinuierlichen Ueberpruefung der Klimaschutzwirkung des IEKP. Zusammenfassung

    Energy Technology Data Exchange (ETDEWEB)

    Doll, Claus; Eichhammer, Wolfgang; Fleiter, Tobias [Fraunhofer-Institut fuer System- und Innovationsforschung, Karlsruhe (DE)] (and others)

    2012-02-15

    of the IEKP measures which enables a periodic comparison with the projections at fixed points in time. 3. To determine how the instruments specified in IEKP, which have been implemented partly at national, and partly at EU level, will affect the emissions of greenhouse gases up to the year 2020 (quantitative evaluation). With this end in view, the first version of the monitoring plan should be implemented as an Excel tool which will enable the effects to be updated annually, possibly by simplifications compared with a detailed modelling approach.

  12. Shale gases, a windfall for France?

    International Nuclear Information System (INIS)

    Tonnac, Alain de; Perves, Jean-Pierre

    2013-11-01

    After having recalled the definition and origin of shale gases, the different non conventional gases and their exploitation techniques (hydraulic fracturing and horizontal drilling) this report examines whether these gases are an opportunity for France. Some characteristics and data of the fossil and gas markets are presented and commented: world primary energy consumption, proved reserves of non conventional gases and their locations, European regions which may possess reserves of shale gases and coal-bed methane, origins of gas imports in France. The second part addresses shale gas deposits and their exploitation: discussion of the influence of the various rock parameters, evolution of production. The third part discusses the exploitation techniques and specific drilling tools. The issue of exploitation safety and security is addressed as well as the associated controversies: about the pollution of underground waters, about the fact that deep drillings result in pollution, about the risks associated with hydraulic fracturing and injections of chemical products, about the hold on ground and site degradation, about water consumption, about pollution due to gas pipeline leakage, about seismic risk, about noise drawbacks, about risks for health, about exploration and production authorization and license, and about air pollution and climate. The last part addresses the French situation and its future: status of the energy bill, recommendations made by a previous government, cancellation of authorizations, etc. Other information are provided in appendix about non conventional hydrocarbons, about shale gas exploitation in the USA, and about the Lacq gas

  13. CFD simulations in the nuclear containment using the DES turbulence models

    International Nuclear Information System (INIS)

    Ding, Peng; Chen, Meilan; Li, Wanai; Liu, Yulan; Wang, Biao

    2015-01-01

    Highlights: • The k-ε based DES model is used in the nuclear containment simulation. • The comparison of results between different turbulent models is obtained. • The superiority of DES models is analyzed. • The computational efficiency with the DES turbulence models is explained. - Abstract: Different species of gases would be released into the containment and cause unpredicted disasters during the nuclear severe accidents. It is important to accurately predict the transportation and stratification phenomena of these gas mixtures. CFD simulations of these thermal hydraulic issues in nuclear containment are investigated in this paper. The main work is to study the influence of turbulence model on the calculation of gas transportation and heat transfer. The k-ε based DES and other frequently used turbulence models are used in the steam and helium release simulation in THAI series experiment. This paper will show the superiority of the DES turbulence model in terms of computational efficiency and accuracy with the experimental results, and analyze the necessities of DES model to simulate the large-scale containment flows with both laminar and turbulence regions

  14. CFD simulations in the nuclear containment using the DES turbulence models

    Energy Technology Data Exchange (ETDEWEB)

    Ding, Peng [School of Engineering, Sun Yat-Sen University, Guangzhou (China); Chen, Meilan [China Nuclear Power Technology Research Institute, Shenzhen (China); Li, Wanai, E-mail: liwai@mail.sysu.edu.cn [Sino-French Institute of Nuclear Engineering & Technology, Sun Yat-Sen University, Guangzhou (China); Liu, Yulan [School of Engineering, Sun Yat-Sen University, Guangzhou (China); Wang, Biao [Sino-French Institute of Nuclear Engineering & Technology, Sun Yat-Sen University, Guangzhou (China)

    2015-06-15

    Highlights: • The k-ε based DES model is used in the nuclear containment simulation. • The comparison of results between different turbulent models is obtained. • The superiority of DES models is analyzed. • The computational efficiency with the DES turbulence models is explained. - Abstract: Different species of gases would be released into the containment and cause unpredicted disasters during the nuclear severe accidents. It is important to accurately predict the transportation and stratification phenomena of these gas mixtures. CFD simulations of these thermal hydraulic issues in nuclear containment are investigated in this paper. The main work is to study the influence of turbulence model on the calculation of gas transportation and heat transfer. The k-ε based DES and other frequently used turbulence models are used in the steam and helium release simulation in THAI series experiment. This paper will show the superiority of the DES turbulence model in terms of computational efficiency and accuracy with the experimental results, and analyze the necessities of DES model to simulate the large-scale containment flows with both laminar and turbulence regions.

  15. Chemical production from industrial by-product gases: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  16. Possibilities for using a temperature-controlled pyrolysis method in order to determine the bonding form of mecury in soils and sediments; Moeglichkeiten der Anwendung eines temperaturgesteuerten Pyrolyseverfahrens zur Bestimmung der Bindungsform des Quecksilbers in Boeden und Sedimenten

    Energy Technology Data Exchange (ETDEWEB)

    Biester, H.

    1994-12-31

    The bonding behaviour of mercury in solids was investigated by means of a temperature-controlled pyrolysis method. Starting from the special property of elemental mercury to evaporate already at room temperature, a method was developed which permits to characterize different mercury bonding forms on the basis of Hg evaporation behaviour from solids at continuously increased temperature. The method starts from the assumption that it is possible to thermally reduce compounded mercury and release it in elemental form. The focus of the work was on the study of Hg bonding behaviour in soils and sediments. The soil samples used were from the areas of two mercury deposits, different kyanizing sites, some former mirror factories, and a chlor-alkali electrolysis workshop. The investigated sediments are a collection of mercury-polluted samples from the rivers Elbe, Rhine, Murg, the Rio Sao Joao de Meriti (Brazil) and some brooks and rivers of the Saar-Nahe depression. (orig./EF) [Deutsch] In der vorliegenden Arbeit wurde das Bindungsverhalten von Quecksilber in Feststoffen mittels eines temperaturgesteuerten Pyrolyseverfahrens untersucht. Ausgehend von der besonderen Eigenschaften des elementaren Quecksilbers, bereits bei Zimmertemperatur zu verdampfen, wurde ein Verfahren entwickelt, das eine Charakterisierung verschiedener Quecksilberbindungsformen aufgrund des Abdampfverhaltens des Hg aus dem Feststoff unter kontinuierlicher Temperaturerhoehung zulaesst. Dem Verfahren liegt dabei die Annahme zugrunde, dass sich das Quecksilber in seinen Verbindungen thermisch reduzieren und in elementarer Form freisetzen laesst. Durch den kontinuierlichen Aufheizprozess erfolgt die Freisetzung des Quecksilbers in Abhaengigkeit von der Bindungsstaerke in unterschiedlichen Temperaturbereichen. Die Darstellung der Ergebnisse erfolgte in Form von Abdampfkurven, die die Extinktion in Abhaengigkeit von der Temperatur darstellen. Der Schwerpunkt dieser Arbeit lag auf der Untersuchung des

  17. La recherche en action : des solutions locales, des effets durables ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    15 déc. 2010 ... Le Centre de recherches pour le développement international (CRDI) appuie la production et l'application de connaissances qui améliorent de façon notable la situation des habitants des pays en développement.

  18. Analyse des caractéristiques structurelles et des performances ...

    African Journals Online (AJOL)

    SARAH

    28 févr. 2014 ... performances technico-économiques de la riziculture irriguée en Côte d' .... en nous basant sur les prix des intrants et des produits en vigueur au cours ..... la recherche et de la vulgarisation et le transfert de technologies ; (2) ...

  19. Evaluation des pratiques de gestion des adventices en riziculture

    African Journals Online (AJOL)

    Les résultats ont montré que les méthodes de gestion de l'enherbement ont .... Le contrôle des adventices en riziculture irriguée a principalement .... mesurer la hauteur des plantes et la longueur ..... Performance agronomique du Sys- tème de ...

  20. Diversification des moyens de subsistance des petits producteurs de ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'économie du Malawi repose essentiellement sur la culture du tabac, qui représente plus de 70 % des revenus d'exportation. Pour 60 % des 100 000 membres de la National Smallholder Farmers' Association of Malawi (NASFAM), le tabac est la seule et unique source de revenus. Les cultivateurs de tabac, au Malawi ...

  1. Culture du bambou : diversification des moyens de subsistance des ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Culture du bambou : diversification des moyens de subsistance des petits producteurs de tabac du sud de la province de Nyanza, au Kenya - phase II. Au cours de la première phase du projet (projet no 103765), les chercheurs ont effectué une analyse de marché pour le bambou et les produits du bambou, comparé les ...

  2. Roles et taches des accompagnateurs des patients hospitalises ...

    African Journals Online (AJOL)

    Roles et taches des accompagnateurs des patients hospitalises dans le service de pneumo-phtysiologie au Centre Hospitalier Universitaire Yalgado Ouedraogo de ... Logistical support represented by material support, drug supply, cleaning of premises, and littering occupied respectively 100%, 91%, 42% and 73%.

  3. Measurements of waste tank passive ventilation rates using tracer gases

    International Nuclear Information System (INIS)

    Huckaby, J.L.; Olsen, K.B.; Sklarew, D.S.; Evans, J.C.; Remund, K.M.

    1997-09-01

    This report presents the results of ventilation rate studies of eight passively ventilated high-level radioactive waste tanks using tracer gases. Head space ventilation rates were determined for Tanks A-101, AX-102, AX-103, BY-105, C-107, S-102, U-103, and U-105 using sulfur hexafluoride (SF 6 ) and/or helium (He) as tracer gases. Passive ventilation rates are needed for the resolution of several key safety issues. These safety issues are associated with the rates of flammable gas production and ventilation, the rates at which organic salt-nitrate salt mixtures dry out, and the estimation of organic solvent waste surface areas. This tracer gas study involves injecting a tracer gas into the tank headspace and measuring its concentration at different times to establish the rate at which the tracer is removed by ventilation. Tracer gas injection and sample collection were performed by SGN Eurisys Service Corporation and/or Lockheed Martin Hanford Corporation, Characterization Project Operations. Headspace samples were analyzed for He and SF 6 by Pacific Northwest National Laboratory (PNNL). The tracer gas method was first demonstrated on Tank S-102. Tests were conducted on Tank S-102 to verify that the tracer gas was uniformly distributed throughout the tank headspace before baseline samples were collected, and that mixing was sufficiently vigorous to maintain an approximately uniform distribution of tracer gas in the headspace during the course of the study. Headspace samples, collected from a location about 4 in away from the injection point and 15, 30, and 60 minutes after the injection of He and SF 6 , indicated that both tracer gases were rapidly mixed. The samples were found to have the same concentration of tracer gases after 1 hour as after 24 hours, suggesting that mixing of the tracer gas was essentially complete within 1 hour

  4. Bose-Einstein condensation of atomic gases

    International Nuclear Information System (INIS)

    Anglin, J. R.; Ketterle, W.

    2003-01-01

    The early experiments on Bose-Einstein condensation in dilute atomic gases accomplished three longstanding goals. First, cooling of neutral atoms into their motional state, thus subjecting them to ultimate control, limited only by Heisenberg uncertainty relation. Second, creation of a coherent sample of atoms, in which all occupy the same quantum states, and the realization of atom lasers - devices that output coherent matter waves. And third, creation of gaseous quantum fluid, with properties that are different from the quantum liquids helium-3 and helium-4. The field of Bose-Einstein condensation of atomic gases has continued to progress rapidly, driven by the combination of new experimental techniques and theoretical advances. The family of quantum degenerate gases has grown, and now includes metastable and fermionic atoms. condensates have become an ultralow-temperature laboratory for atom optics, collisional physics and many-body physics, encompassing phonons, superfluidity, quantized vortices, Josephson junctions and quantum phase transitions. (author)

  5. Density Fluctuations in Uniform Quantum Gases

    International Nuclear Information System (INIS)

    Bosse, J.; Pathak, K. N.; Singh, G. S.

    2011-01-01

    Analytical expressions are given for the static structure factor S(k) and the pair correlation function g(r) for uniform ideal Bose-Einstein and Fermi-Dirac gases for all temperatures. In the vicinity of Bose Einstein condensation (BEC) temperature, g(r) becomes long ranged and remains so in the condensed phase. In the dilute gas limit, g(r) of bosons and fermions do not coincide with Maxwell-Boltzmann gas but exhibit bunching and anti-bunching effect respectively. The width of these functions depends on the temperature and is scaled as √(inverse atomic mass). Our numerical results provide the precise quantitative values of suppression/increase (antibunching and bunching) of the density fluctuations at small distances in ideal quantum gases in qualitative agreement with the experimental observation for almost non-trapped dilute gases.

  6. Method of processing radioactive rare gase

    International Nuclear Information System (INIS)

    Tagusagawa, Atsushi; Tuda, Kazuaki.

    1988-01-01

    Purpose: To obtain a safety processing method without using mechanical pumps or pressure-proof containers and, accordingly, with no risk for the leakage of radioactive rare gas. Method: A container filled with zeolige is inserted with a cover being opened into an autoclave. Meanwhile, krypton-containing gases are supplied to an adsorption tower filled with adsorbents, cooled, adsorbed and then heated to desorb adsorbed krypton. The krypton-containing gases are introduced due to the pressure difference to the autoclave thereby causing krypton to adsorb at ambient temperature to zeolite. Then, the inside of the autoclave is heated to desorb krypton and adsorbed moistures from zeolite and the pressure is elevated. After sending the gases under pressure to the adsorption tower, the zeolite-filled container is taken out from the autoclave, tightly closed and then transferred to a predetermined site. (Takahashi, M.)

  7. GREENHOUSE GASES AND MEANS OF PREVENTION

    Directory of Open Access Journals (Sweden)

    Dušica Stojanović

    2013-09-01

    Full Text Available The greenhouse effect can be defined as the consequence of increased heating of the Earth's surface, as well as the lower atmosphere by carbon dioxide, water vapor, and other trace amounts gases. It is well-known that human industrial activities have released large amounts of greenhouse gases in the atmosphere, about 900 billion tons of carbon dioxide, and it is estimated that up to 450 billion are still in the atmosphere. In comparison to greenhouse gases water vapor is one of the greatest contributors to the greenhouse effect on Earth. Many projects, as does the PURGE project, have tendences to build on the already conducted research and to quantify the positive and negative impacts on health and wellbeing of the population with greenhouse gas reduction strategies that are curently being implemented and should be increasingly applied in various sectors and urban areas, having offices in Europe, China and India.

  8. Dark lump excitations in superfluid Fermi gases

    Science.gov (United States)

    Xu, Yan-Xia; Duan, Wen-Shan

    2012-11-01

    We study the linear and nonlinear properties of two-dimensional matter-wave pulses in disk-shaped superfluid Fermi gases. A Kadomtsev—Petviashvili I (KPI) solitary wave has been realized for superfluid Fermi gases in the limited cases of Bardeen—Cooper—Schrieffer (BCS) regime, Bose—Einstein condensate (BEC) regime, and unitarity regime. One-lump solution as well as one-line soliton solutions for the KPI equation are obtained, and two-line soliton solutions with the same amplitude are also studied in the limited cases. The dependence of the lump propagating velocity and the sound speed of two-dimensional superfluid Fermi gases on the interaction parameter are investigated for the limited cases of BEC and unitarity.

  9. Dark lump excitations in superfluid Fermi gases

    International Nuclear Information System (INIS)

    Xu Yan-Xia; Duan Wen-Shan

    2012-01-01

    We study the linear and nonlinear properties of two-dimensional matter-wave pulses in disk-shaped superfluid Fermi gases. A Kadomtsev—Petviashvili I (KPI) solitary wave has been realized for superfluid Fermi gases in the limited cases of Bardeen—Cooper—Schrieffer (BCS) regime, Bose—Einstein condensate (BEC) regime, and unitarity regime. One-lump solution as well as one-line soliton solutions for the KPI equation are obtained, and two-line soliton solutions with the same amplitude are also studied in the limited cases. The dependence of the lump propagating velocity and the sound speed of two-dimensional superfluid Fermi gases on the interaction parameter are investigated for the limited cases of BEC and unitarity

  10. A green deep eutectic solvent dispersive liquid-liquid micro-extraction (DES-DLLME) for the UHPLC-PDA determination of oxyprenylated phenylpropanoids in olive, soy, peanuts, corn, and sunflower oil.

    Science.gov (United States)

    Ferrone, Vincenzo; Genovese, Salvatore; Carlucci, Maura; Tiecco, Matteo; Germani, Raimondo; Preziuso, Francesca; Epifano, Francesco; Carlucci, Giuseppe; Taddeo, Vito Alessandro

    2018-04-15

    A green dispersive liquid-liquid microextraction (DLLME) using deep eutectic solvent (DES) as the extracting solvent has been developed and applied for the simultaneous quantification of ferulic acid, umbelliferone, boropinic acid, 7-isopentenyloxycoumarin, 4'-geranyloxyferulic acid (GOFA), and auraptene in some vegetable oils using ultra high performance liquid chromatography (UHPLC) with photodiode array detection (PDA). All parameters in the extraction step, including selection and loading of both extracting and dispersing solvents, amount of both extractant and disperser solvent were investigated and optimized. PhAA/TMG DES achieved higher recovery and enrichment factor compared to other DESs. The validated method showed good linearity with correlation coefficients, r 2 >0.9990 for all the analytes. Furthermore, this is the first time that eco-friendly solvents are used for the extraction of oxyprenylated phenylpropanoids and the corresponding extract analyzed with ultra high performance liquid chromatography with photodiode array detection. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Perspectives d'amélioration du rendement à très faible charge des moteurs d'automobile Prospects for Lmprovinq the Very-Low-Load Efficiency of Automotive Engines

    Directory of Open Access Journals (Sweden)

    Douaud A.

    2006-11-01

    Full Text Available Le mauvais rendement énergétique des véhicules utilisés à très faible charge (circulation urbaine, vitesses limitées provient entre autres des combustions non optimales. Celles-ci sont de plusieurs types : combustion lente et/ou tardive, ratés de propagation. L'acquisition de cycles de pression au moyen du système DIGITAP développé à l'In-titut Français du Pétrole (IFP est décrite et le calcul instantané du travail cycle-à-cycle permet de définir un critère de stabilité de fonctionnement du moteur. L'analyse thermodynamique des cycles montre que la composition du mélange air + carburant + gaz résiduels, trop proche des limites de propagabilité de flamme, est à l'origine des phénomènes observés. Des voies d'action portant sur les gaz résiduels, la turbulence et les paramètres du système d'allumage sont dégagées et permettent des améliorations importantes du rendement. The poor energy efficiency of vehicles used at very low engine load (urban traffic, limited speeds comes from non-optimum combustion, among other causes. Such combustion may be of several types, i. e. slow and/or late combustion, propagation misfiring. The recording of pressure cycles by the DIGITAP system developed at Institut Français du Pétrole (IFP is described, and the instantaneous computing of the cycle-to-cycle work enables a stability criterion for engine operating to be described. The thermodynamic analysis of the cycles shows that the composition of the air + fuel + residuel gas mixture which is too close to flame propagation limits is at the origin of the phenomena observed. Methods of action concerning residual gases, turbulence and the parameters of the ignition system are determined and make for great improvements in efficiency and stability for such types of running.

  12. New experimental determination of the neutronic resonance parameters of {sup 237}Np below 500 eV; Nouvelle determination experimentale des parametres de resonances neutroniques de {sup 237}Np en dessous de 500 eV

    Energy Technology Data Exchange (ETDEWEB)

    Gressier, V

    1999-10-01

    For studies of future nuclear reactors dedicated to nuclear waste transmutation, an improvement of the accuracy of the neutron radiative capture cross section of {sup 237}Np appears necessary. In the framework of a collaboration between the Commissariat a l'Energie atomique (CEA) and Institute for Reference Materials and Measurement (IRMM, Geel, Bergium), a new determination of the resonance parameters of {sup 237}Np has been performed. Two types of experiments are carried out at GELINA, the IRMM pulsed neutron source, using the time of flight method: a transmission experiment which is related to the neutron total cross section and a capture experiment which gives the neutron radiative capture cross section. The resonance parameters presented in this work are extracted from the transmission data between 0 and 500 eV with the least square code REFIT, using the Reich-Moore formalism. In parallel, the Doppler effect is investigated. The commonly used free gas model appears inadequate below 20 eV for neptunium dioxide at room temperature. By the use of the program DOPUSH, which calculates the Doppler broadening with a harmonic crystal model according to Lamb's theory, we are able to produce abetter fit of the experimental data for the resonances of {sup 237}Np in NpO{sub 2} at low energy or temperatures. In addition to the resonance parameters, a study of their mean value and distribution is included in this work. (authors)

  13. Gases and vacua handbook of vacuum physics

    CERN Document Server

    Beck, A H

    2013-01-01

    Handbook of Vacuum Physics, Volume 1: Gases and Vacua presents three major topics, which are the fourth to sixth parts of this volume. These topics are the remarks on units of physical quantities; kinetic theory of gases and gaseous flow; and theory of vacuum diffusion pumps. The first topic aims to present concisely the significance of units of physical quantities, catering the need and interest of those who take measurements and make calculations in different fields of vacuum sciences. The technique and applications of this particular topic are also provided. The second main topic focuses sp

  14. Origins of geothermal gases at Yellowstone

    Science.gov (United States)

    Lowenstern, Jacob B.; Bergfeld, Deborah; Evans, William C.; Hunt, Andrew G.

    2015-01-01

    Gas emissions at the Yellowstone Plateau Volcanic Field (YPVF) reflect open-system mixing of gas species originating from diverse rock types, magmas, and crustal fluids, all combined in varying proportions at different thermal areas. Gases are not necessarily in chemical equilibrium with the waters through which they vent, especially in acid sulfate terrain where bubbles stream through stagnant acid water. Gases in adjacent thermal areas often can be differentiated by isotopic and gas ratios, and cannot be tied to one another solely by shallow processes such as boiling-induced fractionation of a parent liquid. Instead, they inherit unique gas ratios (e.g., CH4/He) from the dominant rock reservoirs where they originate, some of which underlie the Quaternary volcanic rocks. Steam/gas ratios (essentially H2O/CO2) of Yellowstone fumaroles correlate with Ar/He and N2/CO2, strongly suggesting that H2O/CO2 is controlled by addition of steam boiled from water rich in atmospheric gases. Moreover, H2O/CO2 varies systematically with geographic location, such that boiling is more enhanced in some areas than others. The δ13C and 3He/CO2 of gases reflect a dominant mantle origin for CO2 in Yellowstone gas. The mantle signature is most evident at Mud Volcano, which hosts gases with the lowest H2O/CO2, lowest CH4 concentrations and highest He isotope ratios (~16Ra), consistent with either a young subsurface intrusion or less input of crustal and meteoric gas than any other location at Yellowstone. Across the YPVF, He isotope ratios (3He/4He) inversely vary with He concentrations, and reflect varied amounts of long- stored, radiogenic He added to the magmatic endmember within the crust. Similarly, addition of CH4 from organic-rich sediments is common in the eastern thermal areas at Yellowstone. Overall, Yellowstone gases reflect addition of deep, high-temperature magmatic gas (CO2-rich), lower-temperatures crustal gases (4He- and CH4-bearing), and those gases (N2, Ne, Ar) added

  15. Itinerant Ferromagnetism in Ultracold Fermi Gases

    DEFF Research Database (Denmark)

    Heiselberg, Henning

    2012-01-01

    Itinerant ferromagnetism in cold Fermi gases with repulsive interactions is studied applying the Jastrow-Slater approximation generalized to finite polarization and temperature. For two components at zero temperature a second order transition is found at akF ≃ 0.90 compatible with QMC. Thermodyna......Itinerant ferromagnetism in cold Fermi gases with repulsive interactions is studied applying the Jastrow-Slater approximation generalized to finite polarization and temperature. For two components at zero temperature a second order transition is found at akF ≃ 0.90 compatible with QMC...

  16. Flammability characteristics of combustible gases and vapors

    Energy Technology Data Exchange (ETDEWEB)

    Zabetakis, M. G. [Bureau of Mines, Pittsburgh, PA (United States)

    1964-05-01

    This is a summary of the available limit of flammability, autoignition and burning-rate data for more than 200 combustible gases and vapors in air and other oxidants, as well as of empirical rules and graphs that can be used to predict similar data for thousands of other combustibles under a variety of environmental conditions. Spec$c data are presented on the paraffinic, unsaturated, aromatic, and alicyclic hydrocarbons, alcohols, ethers, aldehydes, ketones, and sulfur compounds, and an assortment of fuels, fuel blends, hydraulic fluids, engine oils, and miscellaneous combustible gases and vapors.

  17. Investigations into electrical discharges in gases

    CERN Document Server

    Klyarfel'D, B N

    2013-01-01

    Investigations into Electrical Discharges in Gases is a compilation of scientific articles that covers the advances in the investigation of the fundamental processes occurring in electrical discharges in gases and vapors. The book details the different aspects of the whole life cycle of an arc, which include the initiation of a discharge, its transition into an arc, the lateral spread of the arc column, and the recovery of electric strength after extinction of an arc. The text also discusses the methods for the dynamic measurement of vapor density in the vicinity of electrical discharges, alon

  18. Nanoclusters and Microparticles in Gases and Vapors

    CERN Document Server

    Smirnov, Boris M

    2012-01-01

    Research of processes involving Nanoclusters and Microparticleshas been developing fastin many fields of rescent research, in particular in materials science. To stay at the cutting edge of this development, a sound understanding of the processes is needed. In this work, several processes involving small particles are described, such as transport processes in gases, charging of small particles in gases, chemical processes, atom attachment and quenching of excited atomic particles on surfaces, nucleation, coagulation, coalescence and growth processes for particles and aggregates. This work pres

  19. Indoor air pollution caused by geothermal gases

    International Nuclear Information System (INIS)

    Durand, Michael

    2006-01-01

    This paper discusses the little-known but potentially serious indoor air quality problems that may occur where buildings are constructed on geothermal ground. The main problems are related to seepage of carbon dioxide, hydrogen sulphide, radon and other gases from soil cavities directly into indoor air through perforations in the structure. These gases present a health hazard, and hydrogen sulphide, which is particularly corrosive, may cause problems electrical and electronic systems. Counter-measures are not always effective, so developments in such areas should only be undertaken with a clear understanding of site-specific issues and their possible solutions. (author)

  20. Ultracold Dipolar Gases in Optical Lattices

    OpenAIRE

    Trefzger, C.; Menotti, C.; Capogrosso-Sansone, B.; Lewenstein, M.

    2011-01-01

    This tutorial is a theoretical work, in which we study the physics of ultra-cold dipolar bosonic gases in optical lattices. Such gases consist of bosonic atoms or molecules that interact via dipolar forces, and that are cooled below the quantum degeneracy temperature, typically in the nK range. When such a degenerate quantum gas is loaded into an optical lattice produced by standing waves of laser light, new kinds of physical phenomena occur. These systems realize then extended Hubbard-type m...

  1. X-ray magnetic dichroism: from quantitative determination of magnetic moments to imaging of magnetization dynamics; Dichroisme magnetique des rayons X: de la determination quantitative des moments magnetiques a l'imagerie de la dynamique de l'aimantation

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, J

    2006-03-15

    In this document, I use some results of my research activities of the last ten years to show the power of x-ray magnetic dichroism for determining magnetic properties of thin layers, multilayers and nano-structures. The use of sum rules for x-ray dichroism allows a quantitative determination of the spin and orbital contributions to the magnetic moment, for each element of a heterogeneous material separately. Used in a qualitative way, x-ray dichroism allows monitoring the magnetization of the different layers in a multilayer material as a function of applied field. In combination with the temporal structure of synchrotron radiation, it is possible to study fast magnetization reversal with element selectivity, which is important for devices like spin valves and magnetic tunnel junctions. Adding the spatial resolution of a photoelectron emission microscope (PEEM), it becomes possible to study all the details of the fast magnetization reversal in complex magnetic systems. (author)

  2. Utilisation sans risque des eaux usées, des excréta et des eaux ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les responsables de ce projet piloteront l'application et l'adaptation des principes directeurs relatifs à l'utilisation sans risque des eaux usées, des excreta et des eaux grises en agriculture et en aquaculture (Guidelines for the Safe Use of Wastewater, Excreta and Greywater in Agriculture and Aquaculture), que ...

  3. Direction des Publications

    African Journals Online (AJOL)

    Synthese

    mélange pulvérulent de coke et de calcaire. La réduction est assurée par le gaz CO à 1250°C [2]. Le procédé Kawazaki iron powder utilise la calamine comme matière première et aussi CO comme gaz réducteur pour élaborer des poudres de fer. [3]. Un autre procédé plus connu qui fabrique les poudres de fer à partir de la.

  4. Glossaire des sigles

    OpenAIRE

    2015-01-01

    ABM Anti-ballistic missile = Missile antimissile balistique AGM Air-to-ground missile = Missile air-sol AIEA Agence Internationale de l’Energie Atomique ALCM Air-launched cruise missile = Missile de croisière air-sol ANSEA Association des Nations du Sud-Est asiatique ANT* Arme nucléaire tactique ASAT Anti-satellite = Arme antisatellite ASW Anti-submarine warfare = Guerre anti-sous-marine AWACS Airborne warning and control system = Système aérien de contrôle et d’alerte BMD Ballistic missile d...

  5. Measurement and Prediction of Volumetric and Transport Properties of Reservoir Fluids At High Pressure Mesure et prédiction des propriétés volumétriques et des propriétés de transport des fluides de gisement à haute pression

    Directory of Open Access Journals (Sweden)

    De Sant'ana H. B.

    2006-12-01

    Full Text Available Discoveries of oil and gas fields under severe conditions of temperature (above 150°C or pressure (in excess of 50 MPa have been made in various regions of the world. In the North Sea, production is scheduled from deep reservoirs at 190°C and 110 MPa. This brings with it important challenges for predicting the properties of reservoir fluids, both from an experimental and a theoretical standpoint. In order to perform fluid studies for these reservoir conditions, IFP has developed a specific mercury-free high pressure apparatus with sapphire windows, a phase sampling device and viscosity determination by the capillary tube method. Its application is illustrated here using examples of real fluids and model mixtures. This equipment was first used to measure volumetric properties for gases. It has been shown that very high compressibility factors can be found with HP-HT gas condensates. This has a strong influence on recovery factors during primary depletion. In order to predict more accurately the volumetric properties of mixtures under these conditions, we propose to use a conventional equation of state, such as Peng-Robinson, with two improvements :- a modified temperature-dependent volume translation method, calibrated for high pressure density data; the method is simple, more accurate than other volume translation methods and fully consistent with lumping procedures;- a quadratic mixing rule on the covolume. Specific phase behavior can also be found. At low temperatures, wax crystallization can occur from a fluid which is a gas condensate at reservoir temperature. This feature is due to the simultaneous presence of abundant methane and heavy paraffins. A study of model fluids in a sapphire cell has allowed us to identify the possible types of phase diagrams. Although generally not considered to be an important parameter, gas viscosity may have some importance in the production of HP-HT accumulations, because of high flow rates. Viscosity

  6. Wall shear stress hot film sensor for use in gases

    International Nuclear Information System (INIS)

    Osorio, O D; Silin, N

    2011-01-01

    The purpose of this work is to present the construction and characterization of a wall shear stress hot film sensor for use in gases made with MEMS technology. For this purpose, several associated devices were used, including a constant temperature feedback bridge and a shear stress calibration device that allows the sensor performance evaluation. The sensor design adopted here is simple, economical and is manufactured on a flexible substrate allowing its application to curved surfaces. Stationary and transient wall shear stress tests were carried on by means of the calibration device, determining its performance for different conditions.

  7. Investigating tunable KRb gases and Bose-Einstein condensates

    DEFF Research Database (Denmark)

    Jørgensen, Nils Byg

    2015-01-01

    We present the production of dual-species Bose-Einstein condensates of 39K and 87Rb with tunable interactions. A dark spontaneous force optical trap was used for 87Rb to reduce the losses in 39K originating from light-assisted collisions in the magneto optical trapping phase. Using sympathetic...... for dual-species condensates with tunable interactions. Employing the dual-species condensates, the miscible to immiscible phase transition was investigated. By applying an empirical model, the transition was used to determine the background scattering length. Two species quantum gases with tunable...

  8. Corrosion by cooling gases in nuclear reactors; la corrosion par les gaz caloporteurs dans les reacteurs nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Darras, R. [Commissariat a l' energie atomique et aux energies alternatives - CEA, Centre de Saclay, Section d' etude de la corrosion par gaz et metaux liquides (France)

    1960-07-01

    This article begins with a review of the various materials which can be used and the cooling gases in which they may be heated, emphasis being placed on the importance of reaching temperatures as high as possible. This is followed by a few general remarks on the dry oxidation of metals and alloys, particularly with regard to diffusion phenomena and their various possible mechanisms, and also the methods of investigation employed. Finally, the behaviour of the chief nuclear materials heated in the various gases is studied successively. Materials used for fuel (metallic uranium, uranium oxide, carbides and silicides), canning materials (magnesium, aluminium, zirconium, beryllium, stainless and refractory steels), structural materials (ordinary or slightly alloyed steels), and finally moderators (graphite, beryllium oxide) are deal with in this way. This account is backed up both by the results obtained at the CEA and by work published outside or abroad up to the present day. In conclusion, every effort has been made to direct future research on the basis of the foregoing. Reprint of a paper published in Industries Atomiques - no. 9/10, 1959, p. 3-23 [French] Dans cet article, on passe tout d'abord en revue les divers materiaux utilisables et les gaz de refroidissement dans lesquels ils peuvent etre chauffes, en insistant sur l'interet d'atteindre des temperatures aussi elevees que possible. On rappelle ensuite quelques generalites sur l'oxydation seche des metaux et alliages, notamment en ce qui concerne les phenomenes de diffusion et leurs divers mecanismes possibles ainsi que les methodes d'etude. Enfin, le comportement des principaux materiaux nucleaires chauffes dans les divers gaz est etudie successivement. On traita ainsi des materiaux combustibles (uranium metallique, oxyde, carbures et siliciures d'uranium), des materiaux de gainage (magnesium, aluminium, zirconium, beryllium, aciers inoxydables et refractaires), des materiaux de structure (aciers ordinaires

  9. Influence of water vapour and permanent gases on the atmospheric optical depths and transmittance

    Science.gov (United States)

    Badescu, V.

    1991-05-01

    The influence of the atmospheric state on the extinction of direct solar radiation has been studied by using a four layer atmospheric model. Simple analytical formulae are established for the spectral optical depths of permanent gases and water vapour. These formulae use the ground level values of air pressure, temperature and relative huniidity. An additional parameter, related to the vertical distribution of the hunmidity content, is used for a better estimation of the water vapour optical depth. Good agreement between theory and measurements is found. The paper shows the dependence of the atmospheric spectral transmittance on the above mentioned parameters. L'influence de l'état atmosphérique sur l'extinction de la radiation solaire directe a été étudiée à l'aide d'un modèle atmosphérique développé antérieurement par l'auteur. Des formules simples ont été établies pour l'épaisseur optique spectrale des gaz et de la vapeur d'eau. Ces formules utilisent les valeurs de la pression atmosphérique, de la température et de l'humidité relative, mesurées au niveau du sol. Un paramètre supplémentaire, lié à la distribution verticale du contenu d'humidité, est utilisé pour calculer l'épaisseur optique due à la vapeur d'eau. La théorie est en bon accord avec les résultats des mesures. Le travail montre la dépendance de la transmittance atmosphérique spectrale en fonction des paramètres spécifiés ci-dessus.

  10. Fate of Gases generated from Nuclear Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasulu, M.; Francis, A. J. [Pohang Univ. of Science and Technology, Pohang (Korea, Republic of); Francis, A. J. [Brookhaven National Laboratory, New York (United States)

    2013-05-15

    The backfill materials such as cement, bentonite or crushed rock are used as engineered barriers against groundwater infiltration and radionuclide transport. Gas generation from radioactive wastes is attributed to radiolysis, corrosion of metals, and degradation of organic materials. Corrosion of steel drums and biodegradation of organic materials in L/ILW can generate gas which causes pressure build up and has the potential to compromise the integrity of waste containers and release the radionuclides and other contaminants into the environment. Performance assessment therefore requires a detailed understanding of the source and fate of gas generation and transport within the disposal system. Here we review the sources and fate of various type of gases generated from nuclear wastes and repositories. Studies on modeling of the fate and transport of repository gases primarily deal with hydrogen and CO{sub 2}. Although hydrogen and carbon dioxide are the major gases of concern, microbial transformations of these gases in the subterranean environments could be significant. Metabolism of hydrogen along with the carbon dioxide results in the formation of methane, low molecular weight organic compounds and cell biomass and thus could affect the total inventory in a repository environment. Modeling studies should take into consideration of both the gas generation and consumption processes over the long-term.

  11. Electron-Atom Collisions in Gases

    Science.gov (United States)

    Kraftmakher, Yaakov

    2013-01-01

    Electron-atom collisions in gases are an aspect of atomic physics. Three experiments in this field employing a thyratron are described: (i) the Ramsauer-Townsend effect, (ii) the excitation and ionization potentials of xenon and (iii) the ion-electron recombination after interrupting the electric discharge.

  12. Properties and Bibliography of GaSe

    Science.gov (United States)

    1994-02-01

    Musaev, A. E. Bakhyshev, N. M. Gasanly and L. G. Musaeva . (1975). "Anisotropy of the optical constants of GaS and GaSe near the absorption edge." Sov...Phys. Semiconductors. 9 94-95 Russian ref.: Fiz. Tekh. Poluprovodn. 9 142-145 (January 1975). Akhundov, G. A., L. G. Musaeva and M. D. Khomutova

  13. Mitigation of greenhouse gases from agriculture

    DEFF Research Database (Denmark)

    Schils, R.L.M.; Ellis, J. L.; de Klein, C. A. M.

    2013-01-01

    Models are widely used to simulate the emission of greenhouse gases (GHG). They help to identify knowledge gaps, estimate total emissions for inventories, develop mitigation options and policies, raise awareness and encourage adoption. These models vary in scale, scope and methodological approach...

  14. Noble gases as cardioprotectants - translatability and mechanism

    NARCIS (Netherlands)

    Smit, Kirsten F.; Weber, Nina C.; Hollmann, Markus W.; Preckel, Benedikt

    2015-01-01

    Several noble gases, although classified as inert substances, exert a tissue-protective effect in different experimental models when applied before organ ischaemia as an early or late preconditioning stimulus, after ischaemia as a post-conditioning stimulus or when given in combination before,

  15. Toxicity of pyrolysis gases from polyether sulfone

    Science.gov (United States)

    Hilado, C. J.; Olcomendy, E. M.

    1979-01-01

    A sample of polyether sulfone was evaluated for toxicity of pyrolysis gases, using the toxicity screening test method developed at the University of San Francisco. Animal response times were relatively short at pyrolysis temperatures of 600 to 800 C, with death occurring within 6 min. The principal toxicant appeared to be a compound other than carbon monoxide.

  16. Anaesthetic gases: environmental impact and alternatives ...

    African Journals Online (AJOL)

    Anaesthetic gases: environmental impact and alternatives. ... PROMOTING ACCESS TO AFRICAN RESEARCH ... to be small when compared to gaseous emissions from industrial and agricultural sources, the actual percentage contribution to climate change is small. ... EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT

  17. Cold quantum gases with resonant interactions

    NARCIS (Netherlands)

    Marcelis, B.

    2008-01-01

    We study ultracold gases of alkali-metal atoms in the quantum degenerate regime. The interatomic interactions in these type of systems can be tuned using resonances induced by magnetic or electric fields. The tunability of the interactions, together with the possibility of confining the atoms with

  18. Teacher's Guide for Balloons and Gases.

    Science.gov (United States)

    Griffith, Joe H.; And Others

    This guide was developed to provide children with an opportunity to prepare and collect several common gases and to discover and work with some of their properties. The guide is divided into five major sections: (1) introduction, (2) materials, (3) activities, (4) balloons aloft, and (5) an appendix. The introduction provides information…

  19. Prediction of friction coefficients for gases

    Science.gov (United States)

    Taylor, M. F.

    1969-01-01

    Empirical relations are used for correlating laminar and turbulent friction coefficients for gases, with large variations in the physical properties, flowing through smooth tubes. These relations have been used to correlate friction coefficients for hydrogen, helium, nitrogen, carbon dioxide and air.

  20. Plant for removing radioactive rare gases

    International Nuclear Information System (INIS)

    An, Buzai; Kanazawa, Toshio

    1977-01-01

    The outline of the pilot plant to remove and recover radioactive rare gases generated from nuclear power plants, reprocessing installations for nuclear fuel, nuclear research installations, etc. is described below. Among the studies of various processes such as liquefaction and distillation, absorption into solvents, active carbon adsorption, diaphragm method, etc., the liquefaction and distillation process by rectification at low temperature has been positively developed. It is in the stage of practical application for removing rare gases in waste gases from reprocessing and nuclear power plants. This is the process with high safety and excellent rare gas removing capability. Further research and development have been also made for selective adsorption and desorption method at low temperature which is very efficient as there is no release of long life nuclides such as Krypton-85. Rare gases recovered by the above mentioned removal systems must be stored safely for a long time as their half lives are long and specific radioactivities are high. The study has been made continuously on the storage methods including adsorption in cylinders and remotely automatically sealing storing system. (Kobatake, H.)

  1. Isolement et identification des levures.

    Directory of Open Access Journals (Sweden)

    S. DOMERCQ

    1967-06-01

    Full Text Available La fermentation du moût de raisin est assurée par les levures qui se trouvent sur la pellicule du raisin, sur les rafles, et aussi, par celles qui envahissent le matériel de vendange et de vinification dès que la récolte est commencée. L'apparition deLa fermentation du moût de raisin est assurée par les levures qui se trouvent sur la pellicule du raisin, sur les rafles, et aussi, par celles qui envahissent le matériel de vendange et de vinification dès que la récolte est commencée. L'apparition des signes de la fermentation est spontanée. La fermentation est rapide dans la majorité des cas, si elle devient trop violente et que la température s'élève dangeureusement, il faut la « canaliser », la calmer. Des accidents peuvent se produire; des arrêts de fermentation laissant des sucres non fermentés pouvant être attaqués par d'autres microorganismes, des développements de levures formant des substances nuisibles à la qualité; par la suite, il s'agit d'obtenir la stabilité du vin, en particulier, éviter les refermentations des vins doux. L'étude de ces problèmes nécessite une étude préliminaire, celle des levures responsables de la fermentation alcoolique du jus de raisin, qui ne peut être faite que sur des cultures pures, isolées au préalable à l'aide de prélèvements soigneusement réalisés.s signes de la fermentation est spontanée. La fermentation est rapide dans la majorité des cas, si elle devient trop violente et que la température s'élève dangeureusement, il faut la « canaliser », la calmer. Des accidents peuvent se produire; des arrêts de fermentation laissant des sucres non fermentés pouvant être attaqués par d'autres microorganismes, des développements de levures formant des substances nuisibles à la qualité; par la suite, il s'agit d'obtenir la stabilité du vin, en particulier, éviter les refermentations des vins doux. L'étude de ces problèmes nécessite une étude pr

  2. Energy–pressure relation for low-dimensional gases

    Directory of Open Access Journals (Sweden)

    Francesco Mancarella

    2014-10-01

    Full Text Available A particularly simple relation of proportionality between internal energy and pressure holds for scale-invariant thermodynamic systems (with Hamiltonians homogeneous functions of the coordinates, including classical and quantum – Bose and Fermi – ideal gases. One can quantify the deviation from such a relation by introducing the internal energy shift as the difference between the internal energy of the system and the corresponding value for scale-invariant (including ideal gases. After discussing some general thermodynamic properties associated with the scale-invariance, we provide criteria for which the internal energy shift density of an imperfect (classical or quantum gas is a bounded function of temperature. We then study the internal energy shift and deviations from the energy–pressure proportionality in low-dimensional models of gases interpolating between the ideal Bose and the ideal Fermi gases, focusing on the Lieb–Liniger model in 1d and on the anyonic gas in 2d. In 1d the internal energy shift is determined from the thermodynamic Bethe ansatz integral equations and an explicit relation for it is given at high temperature. Our results show that the internal energy shift is positive, it vanishes in the two limits of zero and infinite coupling (respectively the ideal Bose and the Tonks–Girardeau gas and it has a maximum at a finite, temperature-depending, value of the coupling. Remarkably, at fixed coupling the energy shift density saturates to a finite value for infinite temperature. In 2d we consider systems of Abelian anyons and non-Abelian Chern–Simons particles: as it can be seen also directly from a study of the virial coefficients, in the usually considered hard-core limit the internal energy shift vanishes and the energy is just proportional to the pressure, with the proportionality constant being simply the area of the system. Soft-core boundary conditions at coincident points for the two-body wavefunction introduce

  3. Energy–pressure relation for low-dimensional gases

    International Nuclear Information System (INIS)

    Mancarella, Francesco; Mussardo, Giuseppe; Trombettoni, Andrea

    2014-01-01

    A particularly simple relation of proportionality between internal energy and pressure holds for scale-invariant thermodynamic systems (with Hamiltonians homogeneous functions of the coordinates), including classical and quantum – Bose and Fermi – ideal gases. One can quantify the deviation from such a relation by introducing the internal energy shift as the difference between the internal energy of the system and the corresponding value for scale-invariant (including ideal) gases. After discussing some general thermodynamic properties associated with the scale-invariance, we provide criteria for which the internal energy shift density of an imperfect (classical or quantum) gas is a bounded function of temperature. We then study the internal energy shift and deviations from the energy–pressure proportionality in low-dimensional models of gases interpolating between the ideal Bose and the ideal Fermi gases, focusing on the Lieb–Liniger model in 1d and on the anyonic gas in 2d. In 1d the internal energy shift is determined from the thermodynamic Bethe ansatz integral equations and an explicit relation for it is given at high temperature. Our results show that the internal energy shift is positive, it vanishes in the two limits of zero and infinite coupling (respectively the ideal Bose and the Tonks–Girardeau gas) and it has a maximum at a finite, temperature-depending, value of the coupling. Remarkably, at fixed coupling the energy shift density saturates to a finite value for infinite temperature. In 2d we consider systems of Abelian anyons and non-Abelian Chern–Simons particles: as it can be seen also directly from a study of the virial coefficients, in the usually considered hard-core limit the internal energy shift vanishes and the energy is just proportional to the pressure, with the proportionality constant being simply the area of the system. Soft-core boundary conditions at coincident points for the two-body wavefunction introduce a length scale

  4. Le Débat des semences

    International Development Research Centre (IDRC) Digital Library (Canada)

    Solutions pour les lois nationales régissant le contrôle des ressources génétiques et des ...... des pouvoirs) qui reconnaissent, dans une certaine mesure, les droits de gestion collectifs des ...... documentés, les performances physiques, etc.

  5. Mécanique des sols et des roches

    CERN Document Server

    Vullier, Laurent; Zhao, Jian

    2016-01-01

    La mécanique des sols et la mécanique des roches sont des disciplines généralement traitées séparément dans la littérature. Pour la première fois, un traité réunit ces deux spécialités, en intégrant également les connaissances en lien avec les écoulements souterrains et les transferts thermiques. A la fois théorique et pratique, cet ouvrage propose tout d'abord une description détaillée de la nature et de la composition des sols et des roches, puis s'attache à la modélisation de problèmes aux conditions limites et présente les essais permettant de caractériser les sols et les roches, tant d'un point de vue mécanique qu'hydraulique et thermique. La problématique des sols non saturés et des écoulements multiphasiques est également abordée. Une attention particulière est portée aux lois de comportement mécanique et à la détermination de leurs paramètres par des essais in situ et en laboratoire, et l'ouvrage offre également une présentation détaillée des systèmes de classi...

  6. Chirurgie des grassmanniennes

    CERN Document Server

    Lafforgue, Laurent

    2003-01-01

    Les compactifications diverses de variétés de modules sont un thème important et récurrent des mathématiques modernes, et elles connaissent un grand nombre d'applications. Ce livre traite le cas de cellules de Schubert minces, qui sont de sous-variétés naturelles de grassmanniennes. L'auteur a été amené à traiter ces questions par un cas particulier lié à ses travaux sur le programme de Langlands. Dans cette monographie, il en développe une théorie plus systématique, présentant le fortes similarités avec celle des modules du courbes stables. The various compactifications of moduli spaces are an important recurrent theme of modern mathematics, and they have a large number of applications. This book treats the case of thin Schubert varieties, which are natural subvarieties of Grassmannians. The author was led to these questions by a particular case linked to his work on the Langlands program. In this monograph, he develops the theory in a more systematic way, which exhibits strong similarities...

  7. Comportement des polluants des eaux pluviales urbaines en ...

    African Journals Online (AJOL)

    développement et la croissance des organismes vivant dans l'eau et particulièrement les micro- organismes. Le suivi des températures enregistrées oscille entre 9 et 16°C dans les trois sites d'observation durant la période ... de la lumière du soleil. Le site C est bien aéré et .... Effets de différents modes de gestion des eaux ...

  8. THE LAWS OF MOLECULAR AND VISCOUS FLOW OF GASES THROUGH TUBES. Die Gesetze der Molekularstroemung und der inneran Reibungsstroemung der Gase durch Roehren

    Energy Technology Data Exchange (ETDEWEB)

    Knudsen, M

    1909-07-01

    Experimental data from studies of the flow of H/sub 2/, O/sub 2/, and CO/ sub 2/ through glass capillary tubes were collected and treated to determine the effect of tube dimensions and physical properties of the gases on molecular flow. Laws governing the transition from viscous to molecular flow were also sought. (T.R.H.)

  9. Determination of D{sub 2}O-2% Enriched Uranium Lattice Parameters by Means of a Critical System; Determination des Parametres d'un Reseau Uranium Enrichi a 2%-Eau Lourde au Moyen d'un Ensemble Critique; Opredelenie s pomoshch'yu kriticheskoj sistemy parametrov reshetki s 2%-nym obog ashcheniem Urana i s zamedlitelem D{sub 2}O; Determinacion, Mediante un Conjunto Critico, de los Parametros de un Reticulado de D{sub 2}O y Uranio Enriquecido al 2%

    Energy Technology Data Exchange (ETDEWEB)

    Raisic, N.; Takac, S.; Markovic, H.; Bosevski, T. [Boris Kidric Institute of Nuclear Sciences, Belgrade, Yugoslavia (Serbia)

    1964-02-15

    The paper describes a series of experiments performed to determine the basic parameters of a D{sub 2}O-2% enriched-uranium lattice. The fuel elements were hollow cylinders, canned in aluminium and wetted by heavy water both on the inside and outside. The experiments were performed on the RB critical assembly of the Boris Kidric Institute of Nuclear Sciences in Belgrade. The clean geometry of this system enables a rather simple theoretical interpretation of experimental results, and straightforward comparison with two-group diffusion-theory calculations. Measurements performed for ten different lattice configurations included determination of buckling, water-level reactivity coefficient and disadvantage factors for thermal-and epithermal-neutron flux inside a reactor cell. Techniques for these measurements are described. The experimental data are then used to derive the lattice parameters defined by the four-factor formula and two-group diffusion-theory treatment of the reactor core. The results are compared with the standard calculations of the same parameters for measured lattice configurations. Deviations are found in the value of n and resonance integral for U{sup 238}. In conclusion, an analysis is made of the usefulness and accuracy of information obtained from critical experiments for design and exploitation of a research reactor, composed of D{sub 2}O and enriched uranium. (author) [French] Les auteurs decrivent une serie d'experiences qu'ils ont faites pour determiner les parametres fondamentaux d'un reseau uranium enrichi a 2%-eau lourde. Les elements combustiblesetaient des cylindres creux, gaines d'aluminium et baignant'dans l'eau lourde, a l'interieur comme a l'exterieur. Ils se sont servis de l'assemblage critique RB de l'Institut Boris Kidric des sciences nucleaires a Belgrade. La geometrie de cet assemblage non empoisonne a permis d'interpreter le resultat experimental a l'aide d'une theorie assez simple et de le comparer directement aux calculs

  10. Purification of burned gases of domestic wastes; Moderna purificacion de gases quemados de las basuras domesticas

    Energy Technology Data Exchange (ETDEWEB)

    Gottschalk, J.; Buttman, P.; Johansson, T.

    1997-09-01

    The author presents the technology to reduce the emission from the burned gases purification of domestic wastes combustion. The technology was demonstrated in Hobec, Denmark, and developed in Germany. (Author)

  11. Les reseaux de politique publique comme facteur d'influence du choix des instruments de politique energetique canadienne a des fins environnementales de 1993 a nos jours

    Science.gov (United States)

    Fathy El Dessouky, Naglaa

    l'agenda politique du pays. Notre projet de recherche, par le truchement de l'approche des reseaux de politique publique, s'attarde a decrire et a expliquer le processus de la formulation d'une politique particuliere, soit la politique energetique a des fins de protection de l'environnement, elaboree en 1993. Il s'agit de mettre en evidence les facteurs affectant le choix des instruments de ces politiques publiques dans leur contexte national. Ainsi, la question generale de cette recherche est: Comment les phases evolutives de la formation d'un reseau de politique, en l'occurrence le Conseil canadien de l'energie (CCE), menent a des caracteristiques particulieres a ce reseau; et comment celles-ci determinent-elles les types des instruments de politique publique choisis, particulierement ceux de la recente orientation des politiques energetiques canadiennes a des fins environnementales elaborees en 1993? Afin d'atteindre l'objectif de notre recherche, deux facteurs primordiaux sont utilises, soit la circulation de l'information et l'exercice du controle sur les ressources des acteurs. L'analyse des caracteristiques du reseau en fonction des liens forts et des liens faibles autant que la presence ou l'absence des trous structuraux nous permettent de bien identifier les positions des differents acteurs, etatiques et non etatiques, sur le plan de l'information et du controle, qui a leur tour, nous semble-t-il, constituent des facteurs affectant les types des instruments des politiques publiques choisis: instruments substantifs, qui indiquent le degre de l'intervention du gouvernement, et instruments proceduraux, qui mettent plutot l'accent sur le degre de l'influence du gouvernement sur les acteurs non etatiques. L'etude soutient que l'approche des reseaux se distingue notamment par son potentiel a expliquer l'interrelation relative entre idees, interets et institutions, ce qui a son tour est susceptible de permettre une meilleure comprehension des processus de l

  12. Approche historique des classifications en psychiatrie

    OpenAIRE

    Garrabé , J.

    2011-01-01

    Resume Des le milieu du xixe siecle s?est posee la question des criteres de classification des maladies. Pour les maladies mentales, diverses classifications ont alors ete proposees par des auteurs francais (Morel) et allemands (Kahlbaum, Kraepelin). A partir de la fin du xixe siecle, le Bureau International de Statistique (Paris) a publie a une Classification Internationale des Maladies, a revision decennale (J. Bertillon). Cette tache a ete poursuivie dans l?entre-deux-guerres pa...

  13. Complications du traitement traditionnel des fractures : aspects ...

    African Journals Online (AJOL)

    Tous les patients reçus avec des complications du traitement traditionnel des fractures ont été inclus dans ce travail. Le diagnostic des lésions était clinique et radiologique. Nous avions reçu 51 patients porteurs de complications suite à des traitements de médecine traditionnelle, soit 13,7% du total des patients hospitalisés ...

  14. Determination of some fundamental characteristics of Geiger-Mueller counters. Applications to the study of delayed particles from cosmic-ray shower; Sur la determination de quelques caracteristiques fondamentales de compteurs de geiger-muller applications a l'etude des particules retardees des gerbes atmospheriques du rayonnement cosmique

    Energy Technology Data Exchange (ETDEWEB)

    Picard, E [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1954-06-15

    After some historic recalls, the different phases of discharge of a Geiger-Mueller counter is studied. It measures, by oscillograph method, the time between the flow of a particle through a determined area of the counter and the response of the associated amplifier. This time length is composed by the latency period and the delay itself which depends on the amplifier sensitivity. The selection of particles which generate a discharge in the studied counter is obtained with a two coincidence counters telescope in which the aperture is limited by four counters in anticoincidence with the first two counters. The measures have been done with different distance values and an overvoltage V{sub s} which was applied to the counter. The dead time of a GM counter is also measured with a delayed coincidences method. The counter pulses which supply the coincidence circuit are delivered directly or with a known and variable delay. This method allows also to study the spurious pulses which are due to the positive ions impact on the counter cathode. Results for counters working in different conditions are given. It describes the system to limit the discharge which induces the increase of the life working of a counter, the decrease of its dead time and the reduction of the number of spurious pulses. In a second part, it describes the system to study the time correlation between different particles of the cosmic ray. An experiment concerning the presence of delayed particles in cosmic showers has permitted to specify the superior limit of this phenomena which is directly connected to the presence of heavy nuclear particles in the cosmic shower. (M.P.)

  15. Permeation, diffusion and dissolution of hydrogen isotopes, methane and inert gases through/in a tetrafluoroethylene film

    International Nuclear Information System (INIS)

    Matsuyama, M.; Miyake, H.; Ashida, K.; Watanabe, K.

    1982-01-01

    Tetrafluoroethylene (TFE) is widely used for conventional tritium handling systems such as vacuum seals, tubing and so on. We measured the permeation of the three hydrogen isotopes, methane and the inert gases through a TFE film at room temperature by means of the time-lag method in order to establish the physicochemical properties which determine the solubility and diffusivity of those gases. It was found that the diffusion constant of the inert gases changed exponentially with the heat of vaporization and the solubility was an exponential function of the Lennard-Jones force constant of the gases. On the other hand, hydrogen isotopes and methane deviated from these relations. It is concluded that chemical interactions between the solute and the solvent play an important role for the dissolution and the diffusion of these gases in TFE. (orig.)

  16. Quantitative analysis of occluded gases in uranium dioxide pellets by the mass spectrometry technique

    International Nuclear Information System (INIS)

    Vega Bustillos, J.O.W.; Rodrigues, C.; Iyer, S.S.

    1981-05-01

    A quantitative analysis of different components of occluded gases except water in uranium dioxide pellets is attempted here. A high temperature vacuum extration system is employed for the liberation and the determination of total volume of the occluded gases. A mass spectrometric technique is employed for the qualitative and quantitative analysis of these gases. The UO 2 pellets are placed in a graphite crucible and are subjected to varing temperatures (1000 0 C - 1700 0 C). The liberated gases are dehydrated and transferred to a measuring unit consisting essentially of a Toepler pump and a McLeod gauge. In this system the total volume of the gases liberated at N. T. P. is determined with a sensitivity of 0.002 cm 3 /g of UO 2 . An aliquot of the liberated gas is introduced into a quadrupole mass spectrometer (VGA-100 Varian Corp.) for the determination of the different components of the gas. On the basis of the analysis suggestions are made for the possible sources of these gas components. (Author) [pt

  17. Des cartes dans la classe…

    Directory of Open Access Journals (Sweden)

    R. Gimeno

    1990-09-01

    Full Text Available La majorité des enseignants qui veulent faire des cartes — et les faire réaliser aux élèves — pour répondre aux exigences des instructions officielles, doivent surmonter leur manque de compétences en cartographie et en didactique ainsi que les difficultés propres aux logiciels de cartographie encore peu performants. Ces compétences et la réflexion qui les accompagne sont pourtant accessibles aux enfants de l’école élémentaire…

  18. Diversification des moyens de subsistance des petits producteurs de ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Cette subvention permettra à l'Institut international de recherche sur les cultures des zones tropicales ... In ROSSA's latest bulletin issue: A farewell message from Simon Carter, the Regional Director of the ... Cigarette Taxation in Tanzania.

  19. Dew point of gases with low sulfuric acid content

    Energy Technology Data Exchange (ETDEWEB)

    Fieg, J.

    1981-07-01

    Discusses control of air pollution caused by sulfur compounds in solid fuels during combustion. Excessive amount of oxygen during combustion leads to formation of sulfur trioxide. Sulfur trioxide reacts with water vapor and forms sulfuric acid. Chemical reactions which lead to formation of sulfuric acid are described. Conditions for sulfuric acid condensation are analyzed. Several methods for determining dew point of flue gases with low sulfuric acid content are reviewed: methods based on determination of electric conductivity of condensed sulfuric acid (Francis, Cheney, Kiyoure), method based on determination of sulfuric acid concentration in the gaseous phase and in the liquid phase after cooling (Lee, Lisle and Sensenbaugh, Ross and Goksoyr). (26 refs.) (In Polish)

  20. L'exode des cerveaux et le renforcement des capacités en Afrique ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    1 févr. 2011 ... Ce phénomène ébranle les assises économiques et politiques de bien des pays africains. ... le défi consiste à recruter ces cerveaux. ... des missions africaines, des organisations non gouvernementales et des groupes de la diaspora réunis pour parler de l'exode des cerveaux en Afrique et des stratégies à ...

  1. Evaluation des pratiques de gestion des adventices en riziculture ...

    African Journals Online (AJOL)

    Le riz est l'aliment principal pour la quasi-totalité des populations vivant en Côte d'Ivoire. Cependant, les adventices sont considérées comme la contrainte biologique la plus importante faisant obstacle à la production rizicole. L'objectif de cette étude menée en 2015 était d'évaluer différentes techniques de gestion des ...

  2. Cartographie des zones d'intervention des partenaires techniques et ...

    African Journals Online (AJOL)

    cartographier les zones d'intervention des partenaires techniques et financiers au Bénin. L'approche méthodologique utilisée a consisté à la recherche documentaire, à la collecte de données auprès des partenaires techniques et financiers et à l'analyse de ces données. Les résultats ont permis de constater que cent dix ...

  3. Modernisation des marchés agroalimentaires - inclusion des petits ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les marchés agroalimentaires connaissent de rapides changements dans les pays en développement et les pays en transition. Sous l'influence de la libéralisation du commerce et des nouvelles technologies de transformation des aliments et de commerce de détail, les marchés agroalimentaires évoluent vers une plus ...

  4. Determination of Radiotracer Stability of Tritium-Labelled Compounds in Biological Studies; Determination de la Stabilite des Composes Trities Employes comme Indicateurs en Biologie; 041e 043f 0440 0435 0434 0414 043b ; Determinacion de la Estabilidad de los Compuestos Tritiados en los Estudios Biologicos Mediante Indicadores

    Energy Technology Data Exchange (ETDEWEB)

    Okita, G. T.; Spratt, J. L. [Argonne Cancer Research Hospital and Department of Pharmacology, University of Chicago, Chicago, IL (United States)

    1962-02-15

    composes en tant qu'indicateurs. Meme le fait de purifier les composes marques jusqu'a ce que l'on parvienne a une activite specifique constante n'exclut pas la possibilite d'un echange tritium-hydrogene dans un systeme biologique. Une fois faite la purification radiochimique meticuleuse de la substance marquee, la stabilite de l'indicateur peut etre etablie par diverses methodes. Le memoire en decrit trois. L'une consiste a comparer la periode biologique d'un compose tritie avec celle d'un compose similaire marque au carbone-14. Cette methode s'applique en particulier aux substances endogenes qui subissent une dilution isotopique lorsqu'elles sont administrees a des animaux. Quant a la stabilite des composes exogenes, on peut la verifier a l'aide d'une deuxieme methode: il suffit d'etablir qu'il n'y a pas diminution de l'activite specifique quand la substance marquee est de nouveau isolee des echantillons biologiques. Une troisieme methode, plus rapide que la premiere et applicable aux substances tant endogenes qu'exogenes, consiste a determiner le rapport isotopique {sup 3}H/{sup 14}C dans un melange du meme compose marque par ces deux isotopes. Si ce rapport est identique avant administration de la substance doublement marquee et apres son isolement des organes ou excreta, la stabilite de l'indicateur est demontree. Cette methode est particulierement valable lorsque l'isolement de menues quantites de substances necessite l'emploi d'un entraineur non radioactif. Le memoire donne des renseignements explicatifs sur l'emploi de ces trois methodes de verification de la stabilite de l'indicateur et cite, pour chacune d'elles respectivement, l'exemple du cholesterol, de la morphine et de la digitoxine marques. (author) [Spanish] El empleo extensivo que viene haciendose en los ultimos tiempos de compuestos marcados con tritio en los estudios biologicos obliga a los investigadores a comprobar la estabilidad radiotrazadora de los compuestos de tritio. Incluso la purificacion de

  5. Mercury transformation and speciation in flue gases from anthropogenic emission sources: a critical review

    Science.gov (United States)

    Zhang, Lei; Wang, Shuxiao; Wu, Qingru; Wang, Fengyang; Lin, Che-Jen; Zhang, Leiming; Hui, Mulin; Yang, Mei; Su, Haitao; Hao, Jiming

    2016-02-01

    Mercury transformation mechanisms and speciation profiles are reviewed for mercury formed in and released from flue gases of coal-fired boilers, non-ferrous metal smelters, cement plants, iron and steel plants, waste incinerators, biomass burning and so on. Mercury in coal, ores, and other raw materials is released to flue gases in the form of Hg0 during combustion or smelting in boilers, kilns or furnaces. Decreasing temperature from over 800 °C to below 300 °C in flue gases leaving boilers, kilns or furnaces promotes homogeneous and heterogeneous oxidation of Hg0 to gaseous divalent mercury (Hg2+), with a portion of Hg2+ adsorbed onto fly ash to form particulate-bound mercury (Hgp). Halogen is the primary oxidizer for Hg0 in flue gases, and active components (e.g., TiO2, Fe2O3, etc.) on fly ash promote heterogeneous oxidation and adsorption processes. In addition to mercury removal, mercury transformation also occurs when passing through air pollution control devices (APCDs), affecting the mercury speciation in flue gases. In coal-fired power plants, selective catalytic reduction (SCR) system promotes mercury oxidation by 34-85 %, electrostatic precipitator (ESP) and fabric filter (FF) remove over 99 % of Hgp, and wet flue gas desulfurization system (WFGD) captures 60-95 % of Hg2+. In non-ferrous metal smelters, most Hg0 is converted to Hg2+ and removed in acid plants (APs). For cement clinker production, mercury cycling and operational conditions promote heterogeneous mercury oxidation and adsorption. The mercury speciation profiles in flue gases emitted to the atmosphere are determined by transformation mechanisms and mercury removal efficiencies by various APCDs. For all the sectors reviewed in this study, Hgp accounts for less than 5 % in flue gases. In China, mercury emission has a higher Hg0 fraction (66-82 % of total mercury) in flue gases from coal combustion, in contrast to a greater Hg2+ fraction (29-90 %) from non-ferrous metal smelting, cement and

  6. EVALUATION OF SIGNIFICANT ANTHROPOGENIC SOURCES OF RADIATIVELY IMPORTANT TRACE GASES

    Science.gov (United States)

    The report is an initial evaluation of significant anthropogenic sources of radiatively important trace gases. missions of greenhouse gases from human activities--including fossil fuel combustion, industrial/agricultural activities, and transportation--contribute to the increasin...

  7. 75 FR 57669 - Mandatory Reporting of Greenhouse Gases

    Science.gov (United States)

    2010-09-22

    ... Mandatory Reporting of Greenhouse Gases AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: This action amends the Final Mandatory Reporting of Greenhouse Gases Rule to require reporters... Numbers GHG greenhouse gas GHGRP Greenhouse Gas Reporting Program HCFC hydrochlorofluorocarbon HFC...

  8. Geodesics in thermodynamic state spaces of quantum gases

    International Nuclear Information System (INIS)

    Oshima, H.; Obata, T.; Hara, H.

    2002-01-01

    The geodesics for ideal quantum gases are numerically studied. We show that 30 ideal quantum state is connected to an ideal classical state by geodesics and that the bundle of geodesics for Bose gases have a tendency of convergence

  9. Die Versprachlichung des Sakralen

    DEFF Research Database (Denmark)

    Larsen, Øjvind

    2011-01-01

    transformation of the sacred as a harmonious theory of secularization. However, if we follow Weber in his religious-sociological considerations of modernity, we reach a tragic theory of secularization that poses the real problem that modernity’s connection to the sacred has been dissolved.......Habermas claims in connection with his development of the theory of communicative action that the sacred is transformed in a positive way and can take the form of free deliberation in society, the so-called Versprachlichung des Sakralen. The thesis is that the authority which could be found...... in religion and which is of fundamental significance for the integration of pre-modern societies is taken over by modern societies in forms of deliberation. Habermas develops his thesis in a discussion of Durkheim’s religious-sociological considerations. Habermas presents his thesis about the linguistic...

  10. Code des baux 2018

    CERN Document Server

    Vial-Pedroletti, Béatrice; Kendérian, Fabien; Chavance, Emmanuelle; Coutan-Lapalus, Christelle

    2017-01-01

    Le code des baux 2018 vous offre un contenu extrêmement pratique, fiable et à jour au 1er août 2017. Cette 16e édition intègre notamment : le décret du 27 juillet 2017 relatif à l’évolution de certains loyers dans le cadre d’une nouvelle location ou d’un renouvellement de bail, pris en application de l’article 18 de la loi n° 89-462 du 6 juillet 1989 ; la loi du 27 janvier 2017 relative à l’égalité et à la citoyenneté ; la loi du 9 décembre 2016 relative à la transparence, à la lutte contre la corruption et à la modernisation de la vie économique ; la loi du 18 novembre 2016 de modernisation de la justice du xxie siècle

  11. Radiolytic generation of gases in reactors

    International Nuclear Information System (INIS)

    Ramshesh, V.; Venkateswarlu, K.S.

    1988-01-01

    Water or heavy water is used in different circuits in a reactor. Their most common use is as a moderator and/or as a coolant. Light water is used at other places such as in end shield, calandria vault etc., In the process they are exposed to intense ionizing radiation and undergo radiolytic degradation. The molecular produts of radiolysis are hydrogen, hydrogen peroxide and oxygen. As is commonly known if hydrogen is formed beyond a certain level, in the presence of oxygen it may lead to combustion or even explosion. Thus one should comprehend the basic principles of radiolysis and see whether the concentration of these gases under various conditions can be worked out. This report attempts to analyse in depth the radiolytic generation of gases in reactor systems. (author). 3 tabs

  12. Simulation of diffusion in concentrated lattice gases

    International Nuclear Information System (INIS)

    Kehr, K.W.

    1986-01-01

    Recently the diffusion of particles in lattice gases was studied extensively by theoretical methods and numerical simulations. This paper reviews work on collective and, in particular, on tracer diffusion. The diffusion of tagged particles is characterized by a correlation factor whose behavior as a function of concentration is now well understood. Also the detailed kinetics of the tracer transitions was investigated. A special case is the one-dimensional lattice gas where the tracer diffusion coefficient vanishes. An interesting extension is the case of tagged atoms with a different transition rate. This model allows to study various physical situations, including impurity diffusion, percolation, and diffusion in partially blocked lattices. Finally some recent work on diffusion in lattice gases under the influence of a drift field will be reported. (author)

  13. Functional renormalization and ultracold quantum gases

    International Nuclear Information System (INIS)

    Floerchinger, Stefan

    2010-01-01

    Modern techniques from quantum field theory are applied in this work to the description of ultracold quantum gases. This leads to a unified description of many phenomena including superfluidity for bosons and fermions, classical and quantum phase transitions, different dimensions, thermodynamic properties and few-body phenomena as bound state formation or the Efimov effect. The non-perturbative treatment with renormalization group flow equations can account for all known limiting cases by solving one single equation. It improves previous results quantitatively and brings qualitatively new insights. As an example, new quantum phase transitions are found for fermions with three spin states. Ultracold atomic gases can be seen as an interesting model for features of high energy physics and for condensed matter theory. The research reported in this thesis helps to solve the difficult complexity problem in modern theoretical physics. (orig.)

  14. Properties of quantum self-gravitating gases

    International Nuclear Information System (INIS)

    Rumyantseva, E.N.

    1981-01-01

    Ways of development of the quantum field theory in the general relativity theory are under consideration. A direction, where consideration of quantum fields in strong nonstatic gravitational fields leads to such effects as particle production, is found out. Authors managed to explain properties of quantum self-gravitating gases on the base of an expansion the fugacity in power series for bose- and fermi gases. Expressions for fluctuations in statistical models of the Fridmann universe are presented. The spectrum density of relict neutrinos in Fridmann models is calculated. A characteristic low boundary of the neutrino energy spectrum constitutes 1 MeV. A number of neutrinos with such energies practically is equal to zero. A great number of neutrinos has energies 0 . It is precisely these neurinos, which are responsible for the closed state of the universe according to the built up model

  15. Detecting Friedel oscillations in ultracold Fermi gases

    Science.gov (United States)

    Riechers, Keno; Hueck, Klaus; Luick, Niclas; Lompe, Thomas; Moritz, Henning

    2017-09-01

    Investigating Friedel oscillations in ultracold gases would complement the studies performed on solid state samples with scanning-tunneling microscopes. In atomic quantum gases interactions and external potentials can be tuned freely and the inherently slower dynamics allow to access non-equilibrium dynamics following a potential or interaction quench. Here, we examine how Friedel oscillations can be observed in current ultracold gas experiments under realistic conditions. To this aim we numerically calculate the amplitude of the Friedel oscillations which are induced by a potential barrier in a 1D Fermi gas and compare it to the expected atomic and photonic shot noise in a density measurement. We find that to detect Friedel oscillations the signal from several thousand one-dimensional systems has to be averaged. However, as up to 100 parallel one-dimensional systems can be prepared in a single run with present experiments, averaging over about 100 images is sufficient.

  16. Two-Dimensional Homogeneous Fermi Gases

    Science.gov (United States)

    Hueck, Klaus; Luick, Niclas; Sobirey, Lennart; Siegl, Jonas; Lompe, Thomas; Moritz, Henning

    2018-02-01

    We report on the experimental realization of homogeneous two-dimensional (2D) Fermi gases trapped in a box potential. In contrast to harmonically trapped gases, these homogeneous 2D systems are ideally suited to probe local as well as nonlocal properties of strongly interacting many-body systems. As a first benchmark experiment, we use a local probe to measure the density of a noninteracting 2D Fermi gas as a function of the chemical potential and find excellent agreement with the corresponding equation of state. We then perform matter wave focusing to extract the momentum distribution of the system and directly observe Pauli blocking in a near unity occupation of momentum states. Finally, we measure the momentum distribution of an interacting homogeneous 2D gas in the crossover between attractively interacting fermions and bosonic dimers.

  17. Comparing greenhouse gases for policy purposes

    International Nuclear Information System (INIS)

    Schmalensee, R.

    1993-01-01

    In order to derive optimal policies for greenhouse gas emissions control, the discounted marginal damages of emissions from different gases must be compared. The greenhouse warming potential (GWP) index, which is most often used to compare greenhouse gases, is not based on such a damage comparison. This essay presents assumptions under which ratios of gas-specific discounted marginal damages reduce to ratios of discounted marginal contributions to radiative forcing, where the discount rate is the difference between the discount rate relevant to climate-related damages and the rate of growth of marginal climate-related damages over time. If there are important gas-specific costs or benefits not tied to radiative forcing, however, such as direct effects of carbon dioxide on plant growth, there is in general no shortcut around explicit comparison of discounted net marginal damages. 16 refs

  18. Oxygen partial pressure sensor for gases

    International Nuclear Information System (INIS)

    Barbero, J.A.; Azcona, M.A.; Orce, A.

    1997-01-01

    Precise measurement of very low oxygen partial pressure is important in both laboratories and industries. Particularly in nuclear industry, it is relevant in the different steps of the nuclear fuel fabrication. It is presented an instrument which is handy and of easy construction, suitable for the measurement of oxygen partial pressure of gases, in the range of 10 -6 -1 atm. It is based on a solid electrolyte galvanic cell, using Yttria doped zirconia as a ceramic membrane. Through an indirect measurement and calibration, the instrument can be used to measure the content of free oxygen in liquids. It is a import feature in NPP instrumentation. The equipment was calibrated with mixtures of special nonreactive gases. (author). 5 refs

  19. Oxygen partial pressure sensor for gases

    Energy Technology Data Exchange (ETDEWEB)

    Barbero, J.A.; Azcona, M.A.; Orce, A. [Comision Nacional de Energia Atomica, San Carlos de Bariloche (Argentina). Centro Atomico Bariloche

    1997-10-01

    Precise measurement of very low oxygen partial pressure is important in both laboratories and industries. Particularly in nuclear industry, it is relevant in the different steps of the nuclear fuel fabrication. It is presented an instrument which is handy and of easy construction, suitable for the measurement of oxygen partial pressure of gases, in the range of 10{sup -6}-1 atm. It is based on a solid electrolyte galvanic cell, using Yttria doped zirconia as a ceramic membrane. Through an indirect measurement and calibration, the instrument can be used to measure the content of free oxygen in liquids. It is a import feature in NPP instrumentation. The equipment was calibrated with mixtures of special nonreactive gases. (author). 5 refs.

  20. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    Science.gov (United States)

    Turick, C.E.

    1997-06-10

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.