Shock Structure Analysis and Aerodynamics in a Weakly Ionized Gas Flow

Science.gov (United States)

Saeks, R.; Popovic, S.; Chow, A. S.

2006-01-01

The structure of a shock wave propagating through a weakly ionized gas is analyzed using an electrofluid dynamics model composed of classical conservation laws and Gauss Law. A viscosity model is included to correctly model the spatial scale of the shock structure, and quasi-neutrality is not assumed. A detailed analysis of the structure of a shock wave propagating in a weakly ionized gas is presented, together with a discussion of the physics underlying the key features of the shock structure. A model for the flow behind a shock wave propagating through a weakly ionized gas is developed and used to analyze the effect of the ionization on the aerodynamics and performance of a two-dimensional hypersonic lifting body.

Imaging spectrophotometry of ionized gas in NGC 1068. I - Kinematics of the narrow-line region

Science.gov (United States)

Cecil, Gerald; Bland, Jonathan; Tully, R. Brent

1990-01-01

The kinematics of collisionally excited forbidden N II 6548, 6583 across the inner 1 arcmin diameter of the nearby Seyfert galaxy NGC 1068 is mapped using an imaging Fabry-Perot interferometer and low-noise CCD. The stack of monochromatic images, which spatially resolved the high-velocity gas, was analyzed for kinematic and photometric content. Profiles agree well with previous long-slit work, and their complete spatial coverage makes it possible to constrain the gas volume distribution. It is found that the narrow-line region is distributed in a thick center-darkened, line-emitting cylinder that envelopes the collimated radio jet. Three distinct kinematic subsystems, of which the cylinder is composed, are discussed in detail. Detailed behavior of the emission-line profiles, at the few points in the NE quadrant with simple kinematics, argues that the ionized gas develops a significant component of motion perpendicular to the jet axis.

INTEGRAL-FIELD STELLAR AND IONIZED GAS KINEMATICS OF PECULIAR VIRGO CLUSTER SPIRAL GALAXIES

International Nuclear Information System (INIS)

Cortés, Juan R.; Hardy, Eduardo; Kenney, Jeffrey D. P.

2015-01-01

We present the stellar and ionized gas kinematics of 13 bright peculiar Virgo cluster galaxies observed with the DensePak Integral Field Unit at the WIYN 3.5 m telescope in order to look for kinematic evidence that these galaxies have experienced gravitational interactions or gas stripping. Two-dimensional maps of the stellar velocity V, stellar velocity dispersion σ, and the ionized gas velocity (Hβ and/or [O III]) are presented for the galaxies in the sample. The stellar rotation curves and velocity dispersion profiles are determined for 13 galaxies, and the ionized gas rotation curves are determined for 6 galaxies. Misalignments between the optical and kinematical major axes are found in several galaxies. While in some cases this is due to a bar, in other cases it seems to be associated with gravitational interaction or ongoing ram pressure stripping. Non-circular gas motions are found in nine galaxies, with various causes including bars, nuclear outflows, or gravitational disturbances. Several galaxies have signatures of kinematically distinct stellar components, which are likely signatures of accretion or mergers. For all of our galaxies, we compute the angular momentum parameter λ R . An evaluation of the galaxies in the λ R ellipticity plane shows that all but two of the galaxies have significant support from random stellar motions, and have likely experienced gravitational interactions. This includes some galaxies with very small bulges and truncated/compact Hα morphologies, indicating that such galaxies cannot be fully explained by simple ram pressure stripping, but must have had significant gravitational encounters. Most of the sample galaxies show evidence for ICM-ISM stripping as well as gravitational interactions, indicating that the evolution of a significant fraction of cluster galaxies is likely strongly impacted by both effects

A novel method for producing multiple ionization of noble gas

International Nuclear Information System (INIS)

Wang Li; Li Haiyang; Dai Dongxu; Bai Jiling; Lu Richang

1997-01-01

We introduce a novel method for producing multiple ionization of He, Ne, Ar, Kr and Xe. A nanosecond pulsed electron beam with large number density, which could be energy-controlled, was produced by incidence a focused 308 nm laser beam onto a stainless steel grid. On Time-of-Flight Mass Spectrometer, using this electron beam, we obtained multiple ionization of noble gas He, Ne, Ar and Xe. Time of fight mass spectra of these ions were given out. These ions were supposed to be produced by step by step ionization of the gas atoms by electron beam impact. This method may be used as a ideal soft ionizing point ion source in Time of Flight Mass Spectrometer

State and trends of ionization gas analysis. 3

International Nuclear Information System (INIS)

Leonhardt, J.W.; Grosse, H.J.; Popp, P.

1980-01-01

Theory, properties, and main fields of application of noble gas detectors are discussed. The theory and design of the indirect electron mobility detector is presented. Conclusions are drawn with regard to possibilities of further development of detectors for the ionization gas analysis

Gauging Metallicity of Diffuse Gas under an Uncertain Ionizing Radiation Field

Science.gov (United States)

Chen, Hsiao-Wen; Johnson, Sean D.; Zahedy, Fakhri S.; Rauch, Michael; Mulchaey, John S.

2017-06-01

Gas metallicity is a key quantity used to determine the physical conditions of gaseous clouds in a wide range of astronomical environments, including interstellar and intergalactic space. In particular, considerable effort in circumgalactic medium (CGM) studies focuses on metallicity measurements because gas metallicity serves as a critical discriminator for whether the observed heavy ions in the CGM originate in chemically enriched outflows or in more chemically pristine gas accreted from the intergalactic medium. However, because the gas is ionized, a necessary first step in determining CGM metallicity is to constrain the ionization state of the gas which, in addition to gas density, depends on the ultraviolet background radiation field (UVB). While it is generally acknowledged that both the intensity and spectral slope of the UVB are uncertain, the impact of an uncertain spectral slope has not been properly addressed in the literature. This Letter shows that adopting a different spectral slope can result in an order of magnitude difference in the inferred CGM metallicity. Specifically, a harder UVB spectrum leads to a higher estimated gas metallicity for a given set of observed ionic column densities. Therefore, such systematic uncertainties must be folded into the error budget for metallicity estimates of ionized gas. An initial study shows that empirical diagnostics are available for discriminating between hard and soft ionizing spectra. Applying these diagnostics helps reduce the systematic uncertainties in CGM metallicity estimates.

Gauging Metallicity of Diffuse Gas under an Uncertain Ionizing Radiation Field

Energy Technology Data Exchange (ETDEWEB)

Chen, Hsiao-Wen; Zahedy, Fakhri S. [Department of Astronomy and Astrophysics, The University of Chicago, 5640 S Ellis Avenue, Chicago, IL 60637 (United States); Johnson, Sean D. [Department of Astrophysics, Princeton University, Princeton, NJ (United States); Rauch, Michael; Mulchaey, John S., E-mail: hchen@oddjob.uchicago.edu [The Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

2017-06-20

Gas metallicity is a key quantity used to determine the physical conditions of gaseous clouds in a wide range of astronomical environments, including interstellar and intergalactic space. In particular, considerable effort in circumgalactic medium (CGM) studies focuses on metallicity measurements because gas metallicity serves as a critical discriminator for whether the observed heavy ions in the CGM originate in chemically enriched outflows or in more chemically pristine gas accreted from the intergalactic medium. However, because the gas is ionized, a necessary first step in determining CGM metallicity is to constrain the ionization state of the gas which, in addition to gas density, depends on the ultraviolet background radiation field (UVB). While it is generally acknowledged that both the intensity and spectral slope of the UVB are uncertain, the impact of an uncertain spectral slope has not been properly addressed in the literature. This Letter shows that adopting a different spectral slope can result in an order of magnitude difference in the inferred CGM metallicity. Specifically, a harder UVB spectrum leads to a higher estimated gas metallicity for a given set of observed ionic column densities. Therefore, such systematic uncertainties must be folded into the error budget for metallicity estimates of ionized gas. An initial study shows that empirical diagnostics are available for discriminating between hard and soft ionizing spectra. Applying these diagnostics helps reduce the systematic uncertainties in CGM metallicity estimates.

Ionized gas at the edge of the central molecular zone

Science.gov (United States)

Langer, W. D.; Goldsmith, P. F.; Pineda, J. L.; Velusamy, T.; Requena-Torres, M. A.; Wiesemeyer, H.

2015-04-01

Context. The edge of the central molecular zone (CMZ) is the location where massive dense molecular clouds with large internal velocity dispersions transition to the surrounding more quiescent and lower CO emissivity region of the Galaxy. Little is known about the ionized gas surrounding the molecular clouds and in the transition region. Aims: We determine the properties of the ionized gas at the edge of the CMZ near Sgr E using observations of N+ and C+. Methods: We observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C ii] 158 μm and [N ii] 205 μm fine structure lines at six positions with the GREAT instrument on SOFIA and in [C ii] using Herschel HIFI on-the-fly strip maps. We use the [N ii] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C ii] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. Results: We detect two [C ii] and [N ii] velocity components, one along the line of sight to a CO molecular cloud at - 207 km s-1 associated with Sgr E and the other at -174 km s-1 outside the edge of another CO cloud. From the [N ii] emission we find that the average electron density is in the range of ~5 to 21 cm-3 for these features. This electron density is much higher than that of the disk's warm ionized medium, but is consistent with densities determined for bright diffuse H ii nebula. The column density of the CO-dark H2 layer in the -207 km s-1 cloud is ~1-2 × 1021 cm-2 in agreement with theoretical models. The CMZ extends further out in Galactic radius by ~7 to 14 pc in ionized gas than it does in molecular gas traced by CO. Conclusions: The edge of the CMZ likely contains dense hot ionized gas surrounding the neutral molecular material. The high fractional abundance of N+ and high electron density require an intense EUV field with a photon flux of order 106 to 107 photons cm-2 s-1, and/or efficient proton charge exchange with

Resonance ionization in a gas cell: a feasibility study for a laser ion source

International Nuclear Information System (INIS)

Qamhieh, Z.N.; Vandeweert, E.; Silverans, R.E.; Duppen, P. van; Huyse, M.; Vermeeren, L.

1992-01-01

A laser ion source based on resonance photo-ionization in a gas cell is proposed. The gas cell, filled with helium, consists of a target chamber in which the recoil products are stopped and neutralized, and an ionization chamber where the atoms of interest are selectively ionized by the laser light. The extraction of the ions from the ionization chamber through the exit hole-skimmer setup is similar to the ion-guide system. The conditions to obtain an optimal system are given. The results of a two-step one-laser resonance photo-ionization of nickel and the first results of laser ionization in a helium buffer gas cell are presented. (orig.)

The critical ionization velocity mechnism for the case of gas mixture

International Nuclear Information System (INIS)

Raadu, M.A.

1982-08-01

The theory of the critical ionization velocity mechnisms is discussed. In the case of gas mixture the critical velocity is expected to depend on the ionization cross sections. An analytic approximation is introduced which can be used to set limits on a generalized expression for the critical velocity of gas mixtures. (Author)

Ionization and scintillation response of high-pressure xenon gas to alpha particles

International Nuclear Information System (INIS)

Álvarez, V; Cárcel, S; Cervera, A; Díaz, J; Ferrario, P; Gil, A; Gómez-Cadenas, J J; Borges, F I G; Conde, C A N; Fernandes, L M P; Freitas, E D C; Cebrián, S; Dafni, T; Gómez, H; Egorov, M; Gehman, V M; Goldschmidt, A; Esteve, R; Evtoukhovitch, P; Ferreira, A L

2013-01-01

High-pressure xenon gas is an attractive detection medium for a variety of applications in fundamental and applied physics. In this paper we study the ionization and scintillation detection properties of xenon gas at 10 bar pressure. For this purpose, we use a source of alpha particles in the NEXT-DEMO time projection chamber, the large scale prototype of the NEXT-100 neutrinoless double beta decay experiment, in three different drift electric field configurations. We measure the ionization electron drift velocity and longitudinal diffusion, and compare our results to expectations based on available electron scattering cross sections on pure xenon. In addition, two types of measurements addressing the connection between the ionization and scintillation yields are performed. On the one hand we observe, for the first time in xenon gas, large event-by-event correlated fluctuations between the ionization and scintillation signals, similar to that already observed in liquid xenon. On the other hand, we study the field dependence of the average scintillation and ionization yields. Both types of measurements may shed light on the mechanism of electron-ion recombination in xenon gas for highly-ionizing particles. Finally, by comparing the response of alpha particles and electrons in NEXT-DEMO, we find no evidence for quenching of the primary scintillation light produced by alpha particles in the xenon gas.

Spatial profiling of ion and neutral excitation in noble gas electron cyclotron resonance plasmas

International Nuclear Information System (INIS)

Rhoades, R.L.; Gorbatkin, S.M.

1994-01-01

Optical emission from neutrals and ions of several noble gases has been profiled in an electron cyclotron resonance plasma system. In argon plasmas with a net microwave power of 750 W, the neutral (696.5-nm) and ion (488-nm) emission profiles are slightly center peaked at 0.32 mTorr and gradually shift to a hollow appearance at 2.5 mTorr. Neon profiles show a similar trend from 2.5 to 10.0 mTorr. For the noble gases, transition pressure scales with the ionization potential of the gas, which is consistent with neutral depletion. Studies of noble gas mixtures, however, indicate that neutral depletion is not always dominant in the formation of hollow profiles. For Kr/Ar, Ar/Ne, and Ne/He plasmas, the majority gas tends to set the overall shape of the profile at any given pressure. For the conditions of the current system, plasma density appears to be more dominant than electron temperature in the formation of hollow profiles. The general method described is also a straightforward, inexpensive technique for measuring the spatial distribution of power deposited in plasmas, particularly where absolute scale can be calibrated by some other means

The Formation and Physical Origin of Highly Ionized Cooling Gas

Energy Technology Data Exchange (ETDEWEB)

Bordoloi, Rongmon [MIT-Kavli Center for Astrophysics and Space Research, 77 Massachusetts Avenue, Cambridge, MA, 02139 (United States); Wagner, Alexander Y. [University of Tsukuba, Center for Computational Sciences, Tennodai 1-1-1, Tsukuba, Ibaraki (Japan); Heckman, Timothy M.; Norman, Colin A., E-mail: bordoloi@mit.edu, E-mail: bordoloi@mit.edu [Department of Physics and Astronomy, John Hopkins University, 21218, Baltimore, MD (United States)

2017-10-20

We present a simple model that explains the origin of warm, diffuse gas seen primarily as highly ionized absorption-line systems in the spectra of background sources. We predict the observed column densities of several highly ionized transitions such as O vi, O vii, Ne viii, N v, and Mg x, and we present a unified comparison of the model predictions with absorption lines seen in the Milky Way disk, Milky Way halo, starburst galaxies, the circumgalactic medium, and the intergalactic medium at low and high redshifts. We show that diffuse gas seen in such diverse environments can be simultaneously explained by a simple model of radiatively cooling gas. We show that most such absorption-line systems are consistent with being collisionally ionized, and we estimate the maximum-likelihood temperature of the gas in each observation. This model satisfactorily explains why O vi is regularly observed around star-forming low- z L* galaxies, and why N v is rarely seen around the same galaxies. We further present some consequences of this model in quantifying the dynamics of the cooling gas around galaxies and predict the shock velocities associated with such flows. A unique strength of this model is that while it has only one free (but physically well-constrained) parameter, it nevertheless successfully reproduces the available data on O vi absorbers in the interstellar, circumgalactic, intragroup, and intergalactic media, as well as the available data on other absorption lines from highly ionized species.

Influence of ionization on ultrafast gas-based nonlinear fiber optics.

Science.gov (United States)

Chang, W; Nazarkin, A; Travers, J C; Nold, J; Hölzer, P; Joly, N Y; Russell, P St J

2011-10-10

We numerically investigate the effect of ionization on ultrashort high-energy pulses propagating in gas-filled kagomé-lattice hollow-core photonic crystal fibers by solving an established uni-directional field equation. We consider the dynamics of two distinct regimes: ionization induced blue-shift and resonant dispersive wave emission in the deep-UV. We illustrate how the system evolves between these regimes and the changing influence of ionization. Finally, we consider the effect of higher ionization stages.

Penning ionization cross sections of excited rare gas atoms

International Nuclear Information System (INIS)

Ukai, Masatoshi; Hatano, Yoshihiko.

1988-01-01

Electronic energy transfer processes involving excited rare gas atoms play one of the most important roles in ionized gas phenomena. Penning ionization is one of the well known electronic energy transfer processes and has been studied extensively both experimentally and theoretically. The present paper reports the deexcitation (Penning ionization) cross sections of metastable state helium He(2 3 S) and radiative He(2 1 P) atoms in collision with atoms and molecules, which have recently been obtained by the authors' group by using a pulse radiolysis method. Investigation is made of the selected deexcitation cross sections of He(2 3 S) by atoms and molecules in the thermal collisional energy region. Results indicate that the cross sections are strongly dependent on the target molecule. The deexcitation probability of He(2 3 S) per collision increases with the excess electronic energy of He(2 3 S) above the ionization potential of the target atom or molecule. Another investigation, made on the deexcitation of He(2 1 P), suggests that the deexcitation cross section for He(2 1 P) by Ar is determined mainly by the Penning ionization cross section due to a dipole-dipole interaction. Penning ionization due to the dipole-dipole interaction is also important for deexcitation of He(2 1 P) by the target molecules examined. (N.K.)

Two-step laser ionization schemes for in-gas laser ionization and spectroscopy of radioactive isotopesa

OpenAIRE

Kudryavtsev, Yuri; Ferrer, Rafael; Huyse, Mark; Van den Bergh, Paul; Van Duppen, Piet; Vermeeren, L.

2014-01-01

The in-gas laser ionization and spectroscopy technique has been developed at the Leuven isotope separator on-line facility for the production and in-source laser spectroscopy studies of short-lived radioactive isotopes. In this article, results from a study to identify efficient optical schemes for the two-step resonance laser ionization of 18 elements are presented. © 2013 AIP Publishing LLC.

On the relation between plasma and neutral gas profiles in a cold gas-blanket system

International Nuclear Information System (INIS)

Bures, M.

1981-01-01

A solution for the neutral density profile using the measured plasma density and temperature gradients is presented. The fluid model is used. It is found that the penetration length for neutrals is underestimated in the situation where the integrated profiles are used. The ionization rate need not be inferred in the present calculation, because the ionization of neutrals diffusing into the plasma is implicitly included in measured profiles. This calculation is advantageous in the low temperature range where the ionization rate is a strongly varying function of temperature. Finally the presented solution indicates that the temperature gradient plays the essential role in the determination of the neutral density profile. (Auth.)

PHYSICS OF A PARTIALLY IONIZED GAS RELEVANT TO GALAXY FORMATION SIMULATIONS—THE IONIZATION POTENTIAL ENERGY RESERVOIR

International Nuclear Information System (INIS)

Vandenbroucke, B.; De Rijcke, S.; Schroyen, J.; Jachowicz, N.

2013-01-01

Simulation codes for galaxy formation and evolution take on board as many physical processes as possible beyond the standard gravitational and hydrodynamical physics. Most of this extra physics takes place below the resolution level of the simulations and is added in a ''sub-grid'' fashion. However, these sub-grid processes affect the macroscopic hydrodynamical properties of the gas and thus couple to the ''on-grid'' physics that is explicitly integrated during the simulation. In this paper, we focus on the link between partial ionization and the hydrodynamical equations. We show that the energy stored in ions and free electrons constitutes a potential energy term which breaks the linear dependence of the internal energy on temperature. Correctly taking into account ionization hence requires modifying both the equation of state and the energy-temperature relation. We implemented these changes in the cosmological simulation code GADGET2. As an example of the effects of these changes, we study the propagation of Sedov-Taylor shock waves through an ionizing medium. This serves as a proxy for the absorption of supernova feedback energy by the interstellar medium. Depending on the density and temperature of the surrounding gas, we find that up to 50% of the feedback energy is spent ionizing the gas rather than heating it. Thus, it can be expected that properly taking into account ionization effects in galaxy evolution simulations will drastically reduce the effects of thermal feedback. To the best of our knowledge, this potential energy term is not used in current simulations of galaxy formation and evolution.

Several versions of forward gas ionization calorimeter

International Nuclear Information System (INIS)

Babintsev, V.V.; Kholodenko, A.G.; Rodnov, Yu.V.

1994-01-01

The properties of several versions of a gas ionization calorimeter are analyzed by means of the simulation with the GEANT code. The jet energy and coordinate resolutions are evaluated. Some versions of the forward calorimeter meet the ATLAS requirements. 13 refs., 15 figs., 7 tabs

The first experience with LHC beam gas ionization monitor

CERN Document Server

Sapinski, M; Dehning, B; Guerrero, A; Patecki, M; Versteegen, R

2012-01-01

The Beam Gas Ionization Monitors (BGI) are used to measure beam emittance on LHC. This paper describes the detectors and their operation and discusses the issues met during the commissioning. It also discusses the various calibration procedures used to correct for non-uniformity of Multi-Channel plates and to correct the beam size for effects affecting the electron trajectory after ionization.

Lyman-continuum leakage as dominant source of diffuse ionized gas in the Antennae galaxy

Science.gov (United States)

Weilbacher, Peter M.; Monreal-Ibero, Ana; Verhamme, Anne; Sandin, Christer; Steinmetz, Matthias; Kollatschny, Wolfram; Krajnović, Davor; Kamann, Sebastian; Roth, Martin M.; Erroz-Ferrer, Santiago; Marino, Raffaella Anna; Maseda, Michael V.; Wendt, Martin; Bacon, Roland; Dreizler, Stefan; Richard, Johan; Wisotzki, Lutz

2018-04-01

The Antennae galaxy (NGC 4038/39) is the closest major interacting galaxy system and is therefore often studied as a merger prototype. We present the first comprehensive integral field spectroscopic dataset of this system, observed with the MUSE instrument at the ESO VLT. We cover the two regions in this system which exhibit recent star formation: the central galaxy interaction and a region near the tip of the southern tidal tail. In these fields, we detect HII regions and diffuse ionized gas to unprecedented depth. About 15% of the ionized gas was undetected by previous observing campaigns. This newly detected faint ionized gas is visible everywhere around the central merger, and shows filamentary structure. We estimate diffuse gas fractions of about 60% in the central field and 10% in the southern region. We are able to show that the southern region contains a significantly different population of HII regions, showing fainter luminosities. By comparing HII region luminosities with the HST catalog of young star clusters in the central field, we estimate that there is enough Lyman-continuum leakage in the merger to explain the amount of diffuse ionized gas that we detect. We compare the Lyman-continuum escape fraction of each HII region against emission line ratios that are sensitive to the ionization parameter. While we find no systematic trend between these properties, the most extreme line ratios seem to be strong indicators of density bounded ionization. Extrapolating the Lyman-continuum escape fractions to the southern region, we conclude that simply from the comparison of the young stellar populations to the ionized gas there is no need to invoke other ionization mechanisms than Lyman-continuum leaking HII regions for the diffuse ionized gas in the Antennae. FITS images and Table of HII regions are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/611/A95 and at http://muse-vlt.eu/science/antennae/

Coupling of gas chromatography and electrospray ionization high resolution mass spectrometry for the analysis of anabolic steroids as trimethylsilyl derivatives in human urine.

Science.gov (United States)

Cha, Eunju; Jeong, Eun Sook; Cha, Sangwon; Lee, Jaeick

2017-04-29

In this study, gas chromatography (GC) was interfaced with high resolution mass spectrometry (HRMS) with electrospray ionization source (ESI) and the relevant parameters were investigated to enhance the ionization efficiency. In GC-ESI, the distances (x-, y- and z) and angle between the ESI needle, GC capillary column and MS orifice were set to 7 (x-distance), 4 (y-distance), and 1 mm (z-distance). The ESI spray solvent, acid modifier and nebulizer gas flow were methanol, 0.1% formic acid and 5 arbitrary units, respectively. Based on these results, analytical conditions for GC-ESI/HRMS were established. In particular, the results of spray solvent flow indicated a concentration-dependent mechanism (peak dilution effect), and other parameters also greatly influenced the ionization performance. The developed GC-ESI/HRMS was then applied to the analysis of anabolic steroids as trimethylsilyl (TMS) derivatives in human urine to demonstrate its application. The ionization profiles of TMS-derivatized steroids were investigated and compared with those of underivatized steroids obtained from gas chromatography-electrospray ionization/mass spectrometry (GC-ESI/MS) and liquid chromatography-electrospray ionization/mass spectrometry (LC-ESI/MS). The steroids exhibited ionization profiles based on their structural characteristics, regardless of the analyte phase or derivatization. Groups I and II with conjugated or unconjugated keto functional groups at C3 generated the [M+H] + and [M+H-TMS] + ions, respectively. On the other hand, Groups III and IV gave rise to the characteristic fragment ions [M+H-TMS-H 2 O] + and [M+H-2TMS-H 2 O] + , corresponding to loss of a neutral TMS·H 2 O moiety from the protonated molecular ion by in-source dissociation. To the best of our knowledge, this is the first study to successfully ionize and analyze steroids as TMS derivatives using ESI coupled with GC. The present system has enabled the ionization of TMS derivatives under ESI conditions

PHYSICS OF A PARTIALLY IONIZED GAS RELEVANT TO GALAXY FORMATION SIMULATIONS-THE IONIZATION POTENTIAL ENERGY RESERVOIR

Energy Technology Data Exchange (ETDEWEB)

Vandenbroucke, B.; De Rijcke, S.; Schroyen, J. [Department of Physics and Astronomy, Ghent University, Krijgslaan 281, S9, B-9000 Gent (Belgium); Jachowicz, N. [Department of Physics and Astronomy, Ghent University, Proeftuinstraat 86, B-9000 Gent (Belgium)

2013-07-01

Simulation codes for galaxy formation and evolution take on board as many physical processes as possible beyond the standard gravitational and hydrodynamical physics. Most of this extra physics takes place below the resolution level of the simulations and is added in a ''sub-grid'' fashion. However, these sub-grid processes affect the macroscopic hydrodynamical properties of the gas and thus couple to the ''on-grid'' physics that is explicitly integrated during the simulation. In this paper, we focus on the link between partial ionization and the hydrodynamical equations. We show that the energy stored in ions and free electrons constitutes a potential energy term which breaks the linear dependence of the internal energy on temperature. Correctly taking into account ionization hence requires modifying both the equation of state and the energy-temperature relation. We implemented these changes in the cosmological simulation code GADGET2. As an example of the effects of these changes, we study the propagation of Sedov-Taylor shock waves through an ionizing medium. This serves as a proxy for the absorption of supernova feedback energy by the interstellar medium. Depending on the density and temperature of the surrounding gas, we find that up to 50% of the feedback energy is spent ionizing the gas rather than heating it. Thus, it can be expected that properly taking into account ionization effects in galaxy evolution simulations will drastically reduce the effects of thermal feedback. To the best of our knowledge, this potential energy term is not used in current simulations of galaxy formation and evolution.

Determination of equilibrium composition of thermally ionized monoatomic gas under different physical conditions

Science.gov (United States)

Romanova, M. S.; Rydalevskaya, M. A.

2017-05-01

Perfect gas mixtures that result from thermal ionization of spatially and chemically homogeneous monoatomic gases are considered. Equilibrium concentrations of the components of such mixtures are determined using integration over the momentum space and summation with respect to energy levels of the distribution functions that maximize the entropy of system under condition for constancy of the total number of nuclei and electrons. It is demonstrated that such a method allows significant simplification of the calculation of the equilibrium composition for ionized mixtures at different temperatures and makes it possible to study the degree of ionization of gas versus gas density and number in the periodic table of elements.

Study on time response character for high pressure gas ionization chamber of krypton and xenon

International Nuclear Information System (INIS)

Tan Chunming; Wu Haifeng; Qing Shangyu; Wang Liqiang

2006-01-01

The time response character for Kr and Xe high pressure gas ionization chamber is analyzed and deduced. Compared with the measure data of pulse rising time for three gas-filled ionization chambers, the calculated and experimental results are equal to each other. The rising time less than 10 ms for this kind of ionization chamber can be achieved, so this ionization chamber is able to meet the requirement for imaging detection. (authors)

Development of a sodium ionization detector for sodium-to-gas leaks

International Nuclear Information System (INIS)

Swaminathan, K.; Elumalai, G.

1984-01-01

A sensitive sodium-to-gas leak detector has been indigenously developed for use in liquid metal cooled fast breeder reactor. The detector relies on the relative ease with which sodium vapour or its aerosols including its oxides and hydroxides can be thermally ionized compared with other possible constituents such as nitrogen, oxygen, water vapour etc. in a carrier gas and is therefore called sodium ionization detector (SID). The ionization current is a measure of sodium concentration in the carrier gas sampled through the detector. Different sensor designs using platinum and rhodium as filament materials in varying sizes were constructed and their responses to different sodium aerosol concentrations in the carrier gas were investigated. Nitrogen was used as the carrier gas. Both the background current and speed of response were found to depend on the diameter of the filament. There was also a particular collector voltage which yielded maximum sensitivity of the detector. The sensor was therefore optimised considering influence of above factors and a detector has been built which demonstrates a sensitivity better than 0.3 nanogram of sodium per cubic centimetre of carrier gas for a signal to background ratio of 1:1. Its usefulness in detecting sodium fires in experimental area was also demonstrated. Currently efforts are under way to improve the life time of the filament used in the above detector. (author)

The Gaia-ESO Survey: dynamics of ionized and neutral gas in the Lagoon nebula (M 8)

Science.gov (United States)

Damiani, F.; Bonito, R.; Prisinzano, L.; Zwitter, T.; Bayo, A.; Kalari, V.; Jiménez-Esteban, F. M.; Costado, M. T.; Jofré, P.; Randich, S.; Flaccomio, E.; Lanzafame, A. C.; Lardo, C.; Morbidelli, L.; Zaggia, S.

2017-08-01

Aims: We present a spectroscopic study of the dynamics of the ionized and neutral gas throughout the Lagoon nebula (M 8), using VLT-FLAMES data from the Gaia-ESO Survey. The new data permit exploration of the physical connections between the nebular gas and the stellar population of the associated star cluster NGC 6530. Methods: We characterized through spectral fitting emission lines of Hα, [N II] and [S II] doublets, [O III], and absorption lines of sodium D doublet, using data from the FLAMES-Giraffe and UVES spectrographs, on more than 1000 sightlines toward the entire face of the Lagoon nebula. Gas temperatures are derived from line-width comparisons, densities from the [S II] doublet ratio, and ionization parameter from Hα/[N II] ratio. Although doubly-peaked emission profiles are rarely found, line asymmetries often imply multiple velocity components along the same line of sight. This is especially true for the sodium absorption, and for the [O III] lines. Results: Spatial maps for density and ionization are derived, and compared to other known properties of the nebula and of its massive stars 9 Sgr, Herschel 36 and HD 165052 which are confirmed to provide most of the ionizing flux. The detailed velocity fields across the nebula show several expanding shells, related to the cluster NGC 6530, the O stars 9 Sgr and Herschel 36, and the massive protostar M 8East-IR. The origins of kinematical expansion and ionization of the NGC 6530 shell appear to be different. We are able to put constrains on the line-of-sight (relative or absolute) distances between some of these objects and the molecular cloud. The data show that the large obscuring band running through the middle of the nebula is being compressed by both sides, which might explain its enhanced density. We also find an unexplained large-scale velocity gradient across the entire nebula. At larger distances, the transition from ionized to neutral gas is studied using the sodium lines. Based on observations

Signal generation in gas detectors

International Nuclear Information System (INIS)

Stillman, A.

1993-01-01

This tutorial describes the generation of electrical signals in gas detectors. Ionization of the gas by the passage of charged particles generates these signals. Starting with the Bethe-Bloch equation, the treatment is a general introduction to the production of ion-pairs in gas devices. I continue with the characterization of the ionization as an electrical signal, and calculate the signal current in a simple example. Another example demonstrates the effect of space charge on the design of a detector. The AGS Booster ionization profile monitor is a model for this calculation

Heat transfer to a particle exposed to a rarefield ionized-gas flow

International Nuclear Information System (INIS)

Chen, X.; He, P.

1986-01-01

Analytical results are presented concerning the heat transfer to a spherical particle exposed to a high temperature, ionized- gas flow for the extreme case of free-molecule flow regime. It has been shown that the presence of relative velocity between the particle and the ionized gas reduces the floating potential on the particle, enhances the heat flux and causes appreciably non-uniform distribution of the local heat flux. Pronounced difference is found between metallic and non-metallic particles in the floating potential and the local heat flux distributions, in particular for the case with high gas-flow temperature. Relative contribution of atoms to the total heat flux is dominant for the case of low gas-flow temperature, while the heat flux is mainly caused by ions and electrons for the case of high gas-flow temperature

Characteristics of Noble Gas-filled Ionization Chambers for a Low Dose Rate Monitoring

International Nuclear Information System (INIS)

Kim, Han Soo; Park, Se Hwan; Ha, Jan Ho; Lee, Jae Hyung; Lee, Nam Ho; Kim, Jung Bok; Kim, Yong Kyun; Kim, Do Hyun; Cho, Seung Yeon

2007-01-01

An ionization chamber is still widely used in fields such as an environmental radiation monitoring, a Radiation Monitoring System (RMS) in nuclear facilities, and an industrial application due to its operational stability for a long period and its designs for its applications. Ionization chambers for RMS and an environmental radiation monitoring are requested to detect a low dose rate at as low as 10-2 mR/h and several 3R/h, respectively. Filling gas and its pressure are two of the important factors for an ionization chamber development to use it in these fields, because these can increase the sensitivity of an ionization chamber. We developed cylindrical and spherical ionization chambers for a low dose rate monitoring. Response of a cylindrical ionization chamber, which has a 1 L active volume, was compared when it was filled with Air, Ar, and Xe gas respectively. Response of a spherical ionization chamber was also compared in the case of 9 atm and 25 atm filling-pressures. An inter-comparison with a commercially available high pressure Ar ionization chamber and a fabricated ionization chamber was also performed. A High Pressure Xenon (HPXe) ionization chamber, which was configured with a shielding mesh to eliminate an induced charge of positive ions, was fabricated both for the measurement of an environmental dose rate and for the measurement of an energy spectrum

Ionization profile of beta radiation from radioactive cloud

International Nuclear Information System (INIS)

Vujovic, M.; Vojvodic, V.

1978-01-01

A method for calculation of the ionization profile induced by beta radiation from a radioactive cloud is given. The procedure can be applied for high altitudes of the could (H 75 km) as well as for lower ones, when the thickness of the cloud must be taken into account. The final result is given in the analytical form. (author)

Measurements made in the SPS with a rest gas profile monitor by collecting electrons

International Nuclear Information System (INIS)

Fischer, C.; Koopman, J.

2000-01-01

Measurements have regularly been performed during the 1999 run, using the Rest Gas Monitor installed in the SPS. The exploited signal resulted from electrons produced by ionization of the rest gas during the circulating beam passage. A magnetic field parallel to the electric extraction field was applied to channel the electrons. Proton beam horizontal transverse distributions were recorded during entire SPS acceleration cycles, between 14 GeV/c and 450 GeV/c and for different beam structures and bunch intensities. The influence of several parameters on the measured beam profiles was investigated. Results are presented and analyzed in order to determine the performance that can be expected

Ionization chamber for measurements of high-level tritium gas

International Nuclear Information System (INIS)

Carstens, D.H.W.; David, W.R.

1980-01-01

The construction and calibration of a simple ionization-chamber apparatus for measurement of high level tritium gas is described. The apparatus uses an easily constructed but rugged chamber containing the unknown gas and an inexpensive digital multimeter for measuring the ion current. The equipment after calibration is suitable for measuring 0.01 to 100% tritium gas in hydrogen-helium mixes with an accuracy of a few percent. At both the high and low limits of measurements deviations from the predicted theoretical current are observed. These are briefly discussed

Collisional energy dependence of molecular ionization by metastable rare gas atoms

International Nuclear Information System (INIS)

Martin, R.M.; Parr, T.P.

1979-01-01

The collisional energy dependence of several molecular total ionization cross sections by metastable rare gas atoms was studied over the thermal energy region using the crossed molecular beam time-of-flight method. Results are reported for the collision systems He, Ne, and Ar ionizing the geometric isomers cis- and trans-dichloroethylene and ortho- and para-dichlorobenzene. The He ionization cross sections oscillate about an energy dependence of E/sup -1/2/ over the energy range 0.004--1.0 eV, and the Ar*+para-dichlorobenzene cross section oscillates about an energy dependence of E/sup -2/5/ over the energy range 0.011--0.64 eV. The remaining systems are characterized by ''bent'' E/sup -m/ dependences with m values of 0.56--0.70 at low energies changing to 0.07--0.29 at higher energies. Comparison with the slopes of the He* systems and the Ar*+para-dichlorobenzene system shows that the ''bent'' and ''oscillating'' energy dependences are similar except for the form of the cross section functions at the lowest energies. No systematic differences are found between the cross section energy dependences for ionization of different geometric isomers or for ionization by the different metastable rare gas atoms

Switch-shock wave structure in a magnetized partly-ionized gas

International Nuclear Information System (INIS)

Cramer, N.F.

1975-01-01

The effect of the interaction of plasma and neutral gas on the structure of switch-type shock waves propagating in a partly-ionized gas is studied. These shocks, in which the magnetic field is perpendicular to the shock front either upstream or downstream, exhibit a spiralling behaviour of the magnetic field in the shock transition region, if the Hall term is important in the Ohm's law. Observations of this behaviour for shocks propagating into a plasma with a residual neutral content of about 15% has implied an anomalously high resistivity of the plasma. We show that this can be partly explained by considering the collisions of ions with the neutral atoms in a magnetic field. We show that the extra dissipation due to the increase in resistivity goes primarily to the ions and neutrals. Thus even in the absence of viscous dissipation within each species, the heavy particles can be appreciably heated in a shock propagating into a partly-ionized gas in a magnetic field. (author)

Ultraviolet/Optical Emission of the Ionized Gas in AGN: Diagnostics of the Ionizing Source and Gas Properties

Energy Technology Data Exchange (ETDEWEB)

Feltre, Anna [Univ Lyon, Univ Lyon1, Ens de Lyon, Centre National de la Recherche Scientifique, Centre de Recherche Astrophysique de Lyon UMR5574, Saint-Genis-Laval (France); Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Charlot, Stephane [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Mignoli, Marco [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Bongiorno, Angela [INAF-Osservatorio Astronomico di Roma, Monteporzio Catone (Italy); Calura, Francesco [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Chevallard, Jacopo [Scientific Support Office, Directorate of Science and Robotic Exploration, European Space Research and Technology Centre (ESTEC), European Space Agency (ESA), Noordwijk (Netherlands); Curtis-Lake, Emma [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France); Gilli, Roberto [INAF-Osservatorio Astronomico di Bologna, Bologna (Italy); Plat, Adele, E-mail: anna.feltre@univ-lyon1.fr [Sorbonne Universités, UPMC-Centre National de la Recherche Scientifique, UMR7095, Institut d' Astrophysique de Paris, Paris (France)

2017-11-02

Spectroscopic studies of active galactic nuclei (AGN) are powerful means of probing the physical properties of the ionized gas within them. In particular, near future observational facilities, such as the James Webb Space Telescope (JWST), will allow detailed statistical studies of rest-frame ultraviolet and optical spectral features of the very distant AGN with unprecedented accuracy. In this proceedings, we discuss the various ways of exploiting new dedicated photoionization models of the narrow-line emitting regions (NLR) of AGN for the interpretation of forthcoming revolutionary datasets.

First ECR-Ionized Noble Gas Radioisotopes at ISOLDE

CERN Document Server

Wenander, F; Gaubert, G; Jardin, P; Lettry, Jacques

2004-01-01

The production of light noble gas radioisotopes with high ionization potentials has been hampered by modest ionization efficiencies for standard plasma ion-sources. However, the decay losses are minimal as the lingering time of light noble gases within plasma ion-sources is negligible when compared to its diffusion out of the target material. Previous singly charged ECRIS have shown a higher efficiency but also a lingering time of the order of 1 s and a total weight that prevents remote handling by the ISOLDE robot. The compact MINIMONO efficiently addressed the lingering time and weight issues. In addition, the MINIMONO maintained the high off-line ionization efficiency for light noble gases. This paper describes a standard ISOLDE target unit equipped with a MINIMONO ion-source and the first tests. The ion-source has been tested off-line and equipped with a CaO target for on-line tests. Valuable information was gained about high current (100-500 muA) transport through the ISOLDE mass separators designed for ...

X-ray detector for automatic exposure control using ionization chamber filled with xenon gas

CERN Document Server

Nakagawa, A; Yoshida, T

2003-01-01

This report refers to our newly developed X-ray detector for reliable automatic X-ray exposure control, which is to be widely used for X-ray diagnoses in various clinical fields. This new detector utilizes an ionization chamber filled with xenon gas, in contrast to conventional X-ray detectors which use ionization chambers filled with air. Use of xenon gas ensures higher sensitivity and thinner design of the detector. The xenon gas is completely sealed in the chamber, so that the influence of the changes in ambient environments is minimized. (author)

Air ionization as a control technology for off-gas emissions of volatile organic compounds.

Science.gov (United States)

Kim, Ki-Hyun; Szulejko, Jan E; Kumar, Pawan; Kwon, Eilhann E; Adelodun, Adedeji A; Reddy, Police Anil Kumar

2017-06-01

High energy electron-impact ionizers have found applications mainly in industry to reduce off-gas emissions from waste gas streams at low cost and high efficiency because of their ability to oxidize many airborne organic pollutants (e.g., volatile organic compounds (VOCs)) to CO 2 and H 2 O. Applications of air ionizers in indoor air quality management are limited due to poor removal efficiency and production of noxious side products, e.g., ozone (O 3 ). In this paper, we provide a critical evaluation of the pollutant removal performance of air ionizing system through comprehensive review of the literature. In particular, we focus on removal of VOCs and odorants. We also discuss the generation of unwanted air ionization byproducts such as O 3 , NOx, and VOC oxidation intermediates that limit the use of air-ionizers in indoor air quality management. Copyright © 2017. Published by Elsevier Ltd.

Ionization processes in combined high-voltage nanosecond - laser discharges in inert gas

Science.gov (United States)

Starikovskiy, Andrey; Shneider, Mikhail; PU Team

2016-09-01

Remote control of plasmas induced by laser radiation in the atmosphere is one of the challenging issues of free space communication, long-distance energy transmission, remote sensing of the atmosphere, and standoff detection of trace gases and bio-threat species. Sequences of laser pulses, as demonstrated by an extensive earlier work, offer an advantageous tool providing access to the control of air-plasma dynamics and optical interactions. The avalanche ionization induced in a pre-ionized region by infrared laser pulses where investigated. Pre-ionization was created by an ionization wave, initiated by high-voltage nanosecond pulse. Then, behind the front of ionization wave extra avalanche ionization was initiated by the focused infrared laser pulse. The experiment was carried out in argon. It is shown that the gas pre-ionization inhibits the laser spark generation under low pressure conditions.

Ionized and Molecular Gas Kinematics in a z = 1.4 Star-forming Galaxy

Science.gov (United States)

Übler, H.; Genzel, R.; Tacconi, L. J.; Förster Schreiber, N. M.; Neri, R.; Contursi, A.; Belli, S.; Nelson, E. J.; Lang, P.; Shimizu, T. T.; Davies, R.; Herrera-Camus, R.; Lutz, D.; Plewa, P. M.; Price, S. H.; Schuster, K.; Sternberg, A.; Tadaki, K.; Wisnioski, E.; Wuyts, S.

2018-02-01

We present deep observations of a z = 1.4 massive, star-forming galaxy (SFG) in molecular and ionized gas at comparable spatial resolution (CO 3–2, NOrthern Extended Millimeter Array (NOEMA); Hα, Large Binocular Telescope (LBT)). The kinematic tracers agree well, indicating that both gas phases are subject to the same gravitational potential and physical processes affecting the gas dynamics. We combine the one-dimensional velocity and velocity dispersion profiles in CO and Hα to forward-model the galaxy in a Bayesian framework, combining a thick exponential disk, a bulge, and a dark matter halo. We determine the dynamical support due to baryons and dark matter, and find a dark matter fraction within one effective radius of {f}DM}(≤slant {R}e)={0.18}-0.04+0.06. Our result strengthens the evidence for strong baryon-dominance on galactic scales of massive z ∼ 1–3 SFGs recently found based on ionized gas kinematics alone. Based on observations carried out with the IRAM Interferometer NOEMA. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain). Based on observations carried out with the LBT. The LBT is an international collaboration among institutions in the United States, Italy, and Germany. LBT Corporation partners are: LBT Beteiligungsgesellschaft, Germany, representing the Max-Planck Society, The Leibniz Institute for Astrophysics Potsdam, and Heidelberg University; The University of Arizona on behalf of the Arizona Board of Regents; Istituto Nazionale di Astrofisica, Italy; The Ohio State University, and The Research Corporation, on behalf of The University of Notre Dame, University of Minnesota and University of Virginia.

Natural gas annual 1992: Supplement: Company profiles

Energy Technology Data Exchange (ETDEWEB)

1994-01-01

The data for the Natural Gas Annual 1991 Supplement : Company Profiles are taken from Form EIA-176, (open quotes) Annual Report of Natural and Supplemental Gas Supply and Disposition (close quotes). Other sources include industry literature and corporate annual reports to shareholders. The companies appearing in this report are major interstate natural gas pipeline companies, large distribution companies, or combination companies with both pipeline and distribution operations. The report contains profiles of 45 corporate families. The profiles describe briefly each company, where it operates, and any important issues that the company faces. The purpose of this report is to show the movement of natural gas through the various States served by the 45 large companies profiled.

Ultraviolet/Optical Emission of the Ionized Gas in AGN: Diagnostics of the Ionizing Source and Gas Properties

Directory of Open Access Journals (Sweden)

Anna Feltre

2017-11-01

Full Text Available Spectroscopic studies of active galactic nuclei (AGN are powerful means of probing the physical properties of the ionized gas within them. In particular, near future observational facilities, such as the James Webb Space Telescope (JWST, will allow detailed statistical studies of rest-frame ultraviolet and optical spectral features of the very distant AGN with unprecedented accuracy. In this proceedings, we discuss the various ways of exploiting new dedicated photoionization models of the narrow-line emitting regions (NLR of AGN for the interpretation of forthcoming revolutionary datasets.

Natural gas annual 1993 supplement: Company profiles

Energy Technology Data Exchange (ETDEWEB)

1995-02-01

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. This report, the Natural Gas Annual 1993 Supplement: Company Profiles, presents a detailed profile of 45 selected companies in the natural gas industry. The purpose of this report is to show the movement of natural gas through the various States served by the companies profiled. The companies in this report are interstate pipeline companies or local distribution companies (LDC`s). Interstate pipeline companies acquire gas supplies from company owned production, purchases from producers, and receipts for transportation for account of others. Pipeline systems, service area maps, company supply and disposition data are presented.

Application of gas chromatography/flame ionization detector-based metabolite fingerprinting for authentication of Asian palm civet coffee (Kopi Luwak).

Science.gov (United States)

Jumhawan, Udi; Putri, Sastia Prama; Yusianto; Bamba, Takeshi; Fukusaki, Eiichiro

2015-11-01

Development of authenticity screening for Asian palm civet coffee, the world-renowned priciest coffee, was previously reported using metabolite profiling through gas chromatography/mass spectrometry (GC/MS). However, a major drawback of this approach is the high cost of the instrument and maintenance. Therefore, an alternative method is needed for quality and authenticity evaluation of civet coffee. A rapid, reliable and cost-effective analysis employing a universal detector, GC coupled with flame ionization detector (FID), and metabolite fingerprinting has been established for discrimination analysis of 37 commercial and non-commercial coffee beans extracts. gas chromatography/flame ionization detector (GC/FID) provided higher sensitivity over a similar range of detected compounds than GC/MS. In combination with multivariate analysis, GC/FID could successfully reproduce quality prediction from GC/MS for differentiation of commercial civet coffee, regular coffee and coffee blend with 50 wt % civet coffee content without prior metabolite details. Our study demonstrated that GC/FID-based metabolite fingerprinting can be effectively actualized as an alternative method for coffee authenticity screening in industries. Copyright © 2015. Published by Elsevier B.V.

Ionization profile of beta radiation from radioactive cloud; Jonizacioni profil beta zracenja radioaktivnog oblaka

Energy Technology Data Exchange (ETDEWEB)

Vujovic, M [Boris Kidric Institute of nuclear sciences, Vinca, Belgrade (Yugoslavia); Vojvodic, V [VTI Belgrade (Yugoslavia)

1978-07-01

A method for calculation of the ionization profile induced by beta radiation from a radioactive cloud is given. The procedure can be applied for high altitudes of the could (H 75 km) as well as for lower ones, when the thickness of the cloud must be taken into account. The final result is given in the analytical form. (author)

Ionization rates and profiles of electron concentration in Martian atmosphere

International Nuclear Information System (INIS)

Komitov, B.; Spasov, S.; Gogoshev, M.

1981-01-01

The ionization and vertical profiles of electron concentration in the Martian atmosphere are calculated as functions of the solar zenith angles varying from O deg to 90 deg. A neutral atmospheric model based on direct mass-spectometric measurements from the Viking-1 landing modul is employed in the calculation. The Earth data of the ionization solar flux at the same level of the solar activity and for the month of the Viking-1 measurements reduced for the Mars orbit are used. The numerical result for the photoionization rates and quasi-equilibrium electron-concentration profiles in the upper Martian atmosphere at different solar zenith angles from 0 deg to 100 deg are presented. It is shown that the maxima of both quantities decrease and move towards the upper atmosphere regions. The calculated electron density at the zenith solar angle of 40 deg are compared to Viking-1 experimental data and a good agreement is achieved

Gas chromatography/chemical ionization triple quadrupole mass spectrometry analysis of anabolic steroids: ionization and collision-induced dissociation behavior.

Science.gov (United States)

Polet, Michael; Van Gansbeke, Wim; Van Eenoo, Peter; Deventer, Koen

2016-02-28

The detection of new anabolic steroid metabolites and new designer steroids is a challenging task in doping analysis. Switching from electron ionization gas chromatography triple quadrupole mass spectrometry (GC/EI-MS/MS) to chemical ionization (CI) has proven to be an efficient way to increase the sensitivity of GC/MS/MS analyses and facilitate the detection of anabolic steroids. CI also extends the possibilities of GC/MS/MS analyses as the molecular ion is retained in its protonated form due to the softer ionization. In EI it can be difficult to find previously unknown but expected metabolites due to the low abundance or absence of the molecular ion and the extensive (and to a large extent unpredictable) fragmentation. The main aim of this work was to study the CI and collision-induced dissociation (CID) behavior of a large number of anabolic androgenic steroids (AAS) as their trimethylsilyl derivatives in order to determine correlations between structures and CID fragmentation. Clarification of these correlations is needed for the elucidation of structures of unknown steroids and new metabolites. The ionization and CID behavior of 65 AAS have been studied using GC/CI-MS/MS with ammonia as the reagent gas. Glucuronidated AAS reference standards were first hydrolyzed to obtain their free forms. Afterwards, all the standards were derivatized to their trimethylsilyl forms. Full scan and product ion scan analyses were used to examine the ionization and CID behavior. Full scan and product ion scan analyses revealed clear correlations between AAS structure and the obtained mass spectra. These correlations were confirmed by analysis of multiple hydroxylated, methylated, chlorinated and deuterated analogs. AAS have been divided into three groups according to their ionization behavior and into seven groups according to their CID behavior. Correlations between fragmentation and structure were revealed and fragmentation pathways were postulated. Copyright © 2016 John Wiley

Angular intensity of a gas-phase field ionization source

International Nuclear Information System (INIS)

Orloff, J.; Swanson, L.W.

1979-01-01

Angular intensities of 1 μA sr -1 have been measured for a gas-phase field ionization source in an optical column under practical operating conditions. The source, which was differentially pumped and cooled to 77 K, utilized a -oriented iridium emitter and precooled hydrogen gas at 10 -2 Torr. The ion beam was collimated with an electrostatic lens and detected below an aperture subtending 0.164 msr. A transmitted current of approx.10 -10 A was measured at voltages corresponding to a field of approx. =2.2 V/A at the emitter

Beam profile measurements on RHIC

International Nuclear Information System (INIS)

Connolly, R.; Michnoff, R.; Moore, T.; Shea, T.; Tepikian, S.

2000-01-01

The Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Lab was commissioned during the summer of 1999. Transverse beam profiles on RHIC are measured with ionization profile monitors (IPMs). An IPM measures beam profiles by collecting the electrons liberated by residual gas ionization by the beam. The detector is placed in the gap of a dipole magnet to force the electrons to travel in straight lines from the beamline center to the collector. One IPM was tested and it measured the profiles of a single gold bunch containing 10 8 ions on consecutive turns. We show an example of one of these profiles giving transverse emittance. Also several profiles are combined into a mountain-range plot which shows betatron oscillations at injection

Alpha-ionization gas analyzer for air traces in hydrogen or deuterium at atmospheric pressure

International Nuclear Information System (INIS)

Mitrofanov, A.V.

1975-01-01

The constructional features and the principle of operation of and α-ionization gas analyzer are described. The analyzer is based on a radioactive monometric transducer MP-2 with a plutonium source, which makes it possible to measure the volume admixture of air in H 2 or D 2 in the range from 0 to 30% with an accuracy to about 0.3%. The operating principle of the instrument involves the dependence of the saturation current in the ionization chamber on the molecular weight of the gas analysed. As the output unit of the gas analyzer, either a microamperometer or a recording potentiometer is used. The sensitivity of the gas analyzer is about the same as that of instruments based on the phenomenon of heat conduction. The gas analyzer is explosion proof and reliable in operation, which enables it to compete with thermal gas analyzers [ru

Investigation of the profile of phenolic compounds in the leaves and stems of Pandiaka heudelotii using gas chromatography coupled with flame ionization detector.

Science.gov (United States)

Ifeanacho, Mercy O; Ikewuchi, Catherine C; Ikewuchi, Jude C

2017-05-01

The profile of phenolic compounds in the leaves and stems of Pandiaka heudelotii was investigated using gas chromatography coupled with flame ionization detector. The leaves and stems had high flavonoids and benzoic acid derivatives content, and moderate levels of lignans and hydroxycinnamates. Twenty-eight known flavonoids were detected, which consisted mainly of kaempferol (41.93% in leaves and 47.97% in stems), (+)-catechin (17.12% in leaves and 16.11% in stems), quercetin (13.83% in leaves and 9.39% in stems), luteolin (7.34% in leaves and 7.71% in stems), and artemetin (6.53% in leaves and 4.83% in stems). Of the six known hydroxycinnamates detected, chlorogenic acid (80.79% in leaves and 87.56% in stems) and caffeic acid (18.98% in leaves and 12.30% in stems) were the most abundant, while arctigenin (77.81% in leaves and 83.40% in stems) and retusin (13.82% in leaves and 10.59% in stems) were the most abundant of the nine known lignans detected. Twelve known benzoic acid derivatives were detected, consisting mainly of ellagic acid (65.44% in leaves and 72.89% in stems), p-hydroxybenzoic acid (25.10% in leaves and 18.95% in stems), and vanillic acid (8.80% in leaves and 7.30% in stems). The rich phytochemical profile of the leaves and stems is an indication of their ability to serve as sources of nutraceuticals.

III. Penning ionization, associative ionization and chemi-ionization processes

International Nuclear Information System (INIS)

Cermak, V.

1975-01-01

Physical mechanisms of three important ionization processes in a cold plasma and the methods of their experimental study are discussed. An apparatus for the investigation of the Penning ionization using ionization processes of long lived metastable rare gas atoms is described. Methods of determining interaction energies and ionization rates from the measured energy spectra of the originating electrons are described and illustrated by several examples. Typical associative ionization processes are listed and the ionization rates are compared with those of the Penning ionization. Interactions with short-lived excited particles and the transfer of excitation without ionization are discussed. (J.U.)

Resonance ionization spectroscopy: Counting noble gas atoms

International Nuclear Information System (INIS)

Hurst, G.S.; Payne, M.G.; Chen, C.H.; Willis, R.D.; Lehmann, B.E.; Kramer, S.D.

1981-01-01

The purpose of this paper is to describe new work on the counting of noble gas atoms, using lasers for the selective ionization and detectors for counting individual particles (electrons or positive ions). When positive ions are counted, various kinds of mass analyzers (magnetic, quadrupole, or time-of-flight) can be incorporated to provide A selectivity. We show that a variety of interesting and important applications can be made with atom-counting techniques which are both atomic number (Z) and mass number (A) selective. (orig./FKS)

Thermoregulated Nitric Cryosystem for Cooling Gas-Filled Detectors of Ionizing Radiation

Directory of Open Access Journals (Sweden)

Zharkov I.P.

2015-09-01

Full Text Available Cryosystem for cooling and filling of gas-filled detectors of ionizing radiation with compressed inert gas on the basis of wide-nitrogen cryostat, which provides detetector temperature control in a range of 173 — 293 K and its stabilization with accuracy of ± 1°. The work was carried out within the Ukraine — NATO Program of Collaboration, Grant SfP #984655.

Aerosol ionization gas analyzer for continious detection of toxic compounds in industrial gaseous effluents

International Nuclear Information System (INIS)

Groze, Kh.; Dering, Kh.; Gleizberg, F.

1979-01-01

In is noted that the problem of the environment protection as well as protection of the personnel at their working places against influence of harmful substances in air, demands continious measuring of an increasing number of harmful substances with provision of high sensitivity and accuracy of measurements. The demands are listed to the gas analyzers developed for these purposes: flexibility towards solution of different problems of measurement; great number of the substances to be measured; acceptable threshold of determination of different substances concentration in air and small measurement error; simplicity of maintanance and technical service and high reliability in exploitation; economy of fabrication and application. The data are given for the aerosol ionization gas analyzer which, in many cases, met the requirements listed. In the gas analyzer described, the analysed substance is converted for measuring its concentration into an aerosol by means of the aerosol generator, especially designed for this substance or group of substances. The produced aerosol is introduced into an ionization chamber with build-in radiation source and caused decrease of the ionization current in it. According to the decrease of the ionization current, concentration of the harmful substance in air is determined. Characteristics and possibilities of the gas analyzer exploitation are given and discussed on the base of the results of determination of some harmful substances concentrations in air in the laboratory conditions and in the real conditions of industrial production and in the health protection system [ru

Gas chromatography interfaced with atmospheric pressure ionization-quadrupole time-of-flight-mass spectrometry by low-temperature plasma ionization

DEFF Research Database (Denmark)

Norgaard, Asger W.; Kofoed-Sorensen, Vivi; Svensmark, Bo

2013-01-01

A low temperature plasma (LTP) ionization interface between a gas chromatograph (GC) and an atmospheric pressure inlet mass spectrometer, was constructed. This enabled time-of-flight mass spectrometric detection of GC-eluting compounds. The performance of the setup was evaluated by injection...

Pressure of a partially ionized hydrogen gas : numerical results from exact low temperature expansions

OpenAIRE

Alastuey , Angel; Ballenegger , Vincent

2010-01-01

8 pages; International audience; We consider a partially ionized hydrogen gas at low densities, where it reduces almost to an ideal mixture made with hydrogen atoms in their ground-state, ionized protons and ionized electrons. By performing systematic low-temperature expansions within the physical picture, in which the system is described as a quantum electron-proton plasma interacting via the Coulomb potential, exact formulae for the first five leading corrections to the ideal Saha equation ...

Cross section determination for the higher ionization of rare gas ions by electron collisions

International Nuclear Information System (INIS)

Becker, R.; Frodl, R.; Klein, H.; Schmidt, W.; Clausnitzer, G.; Klinger, H.; Mueller, A.; Salzborn, E.; Fuchs, G.; Viehboeck, F.

1975-01-01

The higher ionization of rare gas ions is reported on, which were excited by an electron beam using a crossed-beam technique. A detector for the identification of metastable excited rare gas ions was developed. (WL) [de

Studies of Flow in Ionized Gas: Historical Perspective, Contemporary Experiments, and Applications

International Nuclear Information System (INIS)

Popovic, S.; Vuskovic, L.

2007-01-01

Since the first observations that a very small ionized fraction (order of 1 ppm) could strongly affect the gas flow, numerous experiments with partially or fully wall-free discharges have demonstrated the dispersion of shock waves, the enhancement of lateral forces in the flow, the prospects of levitation, and other aerodynamic effects with vast potential of application. A review of physical effects and observations are given along with current status of their interpretation. Special attention will be given to the physical problems of energy efficiency in generating wall-free discharges and the phenomenology of filamentary discharges. Comments and case examples are given on the current status of availability of necessary data for modelling and simulation of the aerodynamic phenomena in weakly ionized gas

Ionizing gas breakdown waves in strong electric fields.

Science.gov (United States)

Klingbeil, R.; Tidman, D. A.; Fernsler, R. F.

1972-01-01

A previous analysis by Albright and Tidman (1972) of the structure of an ionizing potential wave driven through a dense gas by a strong electric field is extended to include atomic structure details of the background atoms and radiative effects, especially, photoionization. It is found that photoionization plays an important role in avalanche propagation. Velocities, electron densities, and temperatures are presented as a function of electric field for both negative and positive breakdown waves in nitrogen.

The Application of Resonance-Enhanced Multiphoton Ionization Technique in Gas Chromatography Mass Spectrometry

Directory of Open Access Journals (Sweden)

Adan Li

2014-01-01

Full Text Available Gas chromatography resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (GC/REMPI-TOFMS using a nanosecond laser has been applied to analyze the 16 polycyclic aromatic hydrocarbons (PAHs. The excited-state lifetime, absorption characters, and energy of electronic states of the 16 PAHs were investigated to optimize the ionization yield. A river water sample pretreated by means of solid phase extraction was analyzed to evaluate the performance of the analytical instrument. The results suggested that REMPI is superior to electron impact ionization method for soft ionization and suppresses the background signal due to aliphatic hydrocarbons. Thus, GC/REMPI-TOFMS is a more reliable method for the determination of PAHs present in the environment.

THE ESCAPE FRACTION OF IONIZING RADIATION FROM GALAXIES

International Nuclear Information System (INIS)

Benson, Andrew; Venkatesan, Aparna; Shull, J. Michael

2013-01-01

The escape of ionizing radiation from galaxies plays a critical role in the evolution of gas in galaxies, and the heating and ionization history of the intergalactic medium. We present semi-analytic calculations of the escape fraction of ionizing radiation for both hydrogen and helium from galaxies ranging from primordial systems to disk-type galaxies that are not heavily dust-obscured. We consider variations in the galaxy density profile, source type, location, and spectrum, and gas overdensity/distribution factors. For sufficiently hard first-light sources, the helium ionization fronts closely track or advance beyond that of hydrogen. Key new results in this work include calculations of the escape fractions for He I and He II ionizing radiation, and the impact of partial ionization from X-rays from early active galactic nuclei or stellar clusters on the escape fractions from galaxy halos. When factoring in frequency-dependent effects, we find that X-rays play an important role in boosting the escape fractions for both hydrogen and helium, but especially for He II. We briefly discuss the implications of these results for recent observations of the He II reionization epoch at low redshifts, as well as the UV data and emission-line signatures from early galaxies anticipated from future satellite missions.

THE ESCAPE FRACTION OF IONIZING RADIATION FROM GALAXIES

Energy Technology Data Exchange (ETDEWEB)

Benson, Andrew [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Venkatesan, Aparna [Department of Physics and Astronomy, University of San Francisco, San Francisco, CA 94117 (United States); Shull, J. Michael, E-mail: abenson@obs.carnegiescience.edu, E-mail: avenkatesan@usfca.edu, E-mail: michael.shull@colorado.edu [CASA, Department of Astrophysical and Planetary Sciences, University of Colorado, Boulder, CO 80309 (United States)

2013-06-10

The escape of ionizing radiation from galaxies plays a critical role in the evolution of gas in galaxies, and the heating and ionization history of the intergalactic medium. We present semi-analytic calculations of the escape fraction of ionizing radiation for both hydrogen and helium from galaxies ranging from primordial systems to disk-type galaxies that are not heavily dust-obscured. We consider variations in the galaxy density profile, source type, location, and spectrum, and gas overdensity/distribution factors. For sufficiently hard first-light sources, the helium ionization fronts closely track or advance beyond that of hydrogen. Key new results in this work include calculations of the escape fractions for He I and He II ionizing radiation, and the impact of partial ionization from X-rays from early active galactic nuclei or stellar clusters on the escape fractions from galaxy halos. When factoring in frequency-dependent effects, we find that X-rays play an important role in boosting the escape fractions for both hydrogen and helium, but especially for He II. We briefly discuss the implications of these results for recent observations of the He II reionization epoch at low redshifts, as well as the UV data and emission-line signatures from early galaxies anticipated from future satellite missions.

LARGE-SCALE SHOCK-IONIZED AND PHOTOIONIZED GAS IN M83: THE IMPACT OF STAR FORMATION

International Nuclear Information System (INIS)

Hong, Sungryong; Calzetti, Daniela; Dopita, Michael A.; Blair, William P.; Whitmore, Bradley C.; Bond, Howard E.; Balick, Bruce; Carollo, Marcella; Disney, Michael J.; Frogel, Jay A.; Hall, Donald; Holtzman, Jon A.; Kimble, Randy A.; McCarthy, Patrick J.; O'Connell, Robert W.; Paresce, Francesco; Saha, Abhijit; Silk, Joseph I.; Trauger, John T.; Walker, Alistair R.

2011-01-01

We investigate the ionization structure of the nebular gas in M83 using the line diagnostic diagram, [O III](5007 A)/Hβ versus [S II](6716 A+6731 A)/Hα, with the newly available narrowband images from the Wide Field Camera 3 (WFC3) of the Hubble Space Telescope (HST). We produce the diagnostic diagram on a pixel-by-pixel (0.''2 x 0.''2) basis and compare it with several photo- and shock-ionization models. We select four regions from the center to the outer spiral arm and compare them in the diagnostic diagram. For the photoionized gas, we observe a gradual increase of the log ([O III]/Hβ) ratios from the center to the spiral arm, consistent with the metallicity gradient, as the H II regions go from super-solar abundance to roughly solar abundance from the center out. Using the diagnostic diagram, we separate the photoionized from the shock-ionized component of the gas. We find that the shock-ionized Hα emission ranges from ∼2% to about 15%-33% of the total, depending on the separation criteria used. An interesting feature in the diagnostic diagram is a horizontal distribution around log ([O III]/Hβ) ∼ 0. This feature is well fit by a shock-ionization model with 2.0 Z sun metallicity and shock velocities in the range of 250-350 km s -1 . A low-velocity shock component, -1 , is also detected and is spatially located at the boundary between the outer ring and the spiral arm. The low-velocity shock component can be due to (1) supernova remnants located nearby, (2) dynamical interaction between the outer ring and the spiral arm, and (3) abnormal line ratios from extreme local dust extinction. The current data do not enable us to distinguish among those three possible interpretations. Our main conclusion is that, even at the HST resolution, the shocked gas represents a small fraction of the total ionized gas emission at less than 33% of the total. However, it accounts for virtually all of the mechanical energy produced by the central starburst in M83.

Global gas company profiles

International Nuclear Information System (INIS)

1997-01-01

This report provides a detailed assessment of 60 of the top gas companies form around the world, analysing them according to their internal dynamics and in relation to their competitors. It devotes each chapter to an individual company, providing invaluable insight into the organisation's operational background, financial performance and strategic goals. Using the most up-to-date information available, Global Gas Company Profiles allows you to make detailed analysis of each company's performance and future direction. (author)

Lipids and Fatty Acids in Algae: Extraction, Fractionation into Lipid Classes, and Analysis by Gas Chromatography Coupled with Flame Ionization Detector (GC-FID).

Science.gov (United States)

Guihéneuf, Freddy; Schmid, Matthias; Stengel, Dagmar B

2015-01-01

Despite the number of biochemical studies exploring algal lipids and fatty acid biosynthesis pathways and profiles, analytical methods used by phycologists for this purpose are often diverse and incompletely described. Potential confusion and potential variability of the results between studies can therefore occur due to change of protocols for lipid extraction and fractionation, as well as fatty acid methyl esters (FAME) preparation before gas chromatography (GC) analyses. Here, we describe a step-by-step procedure for the profiling of neutral and polar lipids using techniques such as solid-liquid extraction (SLE), thin-layer chromatography (TLC), and gas chromatography coupled with flame ionization detector (GC-FID). As an example, in this protocol chapter, analyses of neutral and polar lipids from the marine microalga Pavlova lutheri (an EPA/DHA-rich haptophyte) will be outlined to describe the distribution of fatty acid residues within its major lipid classes. This method has been proven to be a reliable technique to assess changes in lipid and fatty acid profiles in several other microalgal species and seaweeds.

Determination of electron impact ionization and excitation coefficients in He-Xe gas mixtures. He-Xe kongo gas ni okeru denshi shototsu denri keisu oyobi reiki keisu no sokutei to kaiseki

Energy Technology Data Exchange (ETDEWEB)

Takahashi, K.; Tachibana, K. (Kyoto Inst. of Technology, Kyoto (Japan))

1991-03-20

The rare gas discharge gives a stable discharge and light emission characteristics at low temperature in comparison with the discharge of the vapor of such a metal as Hg. The present barrier for the commercialization of the color PDP lies in the lower level of its emission intensity and efficiency in comparison with that of CRT. In this report, an electron impact ionization coefficient in a gas mixture and an electron impact excitation coefficient for a XeIs {sub 4} level were analyzed using a Boltzmann equation by means of a steady state Townsend method using a drift tube. By comparing both, the elementary process in the gas mixture is investiagted to discuss the respective contributions for the effective ionization coefficient and the excitation coefficient. As a result, it was found that the ionization process in the He-Xe gas mixture could be described by the processes of direct ionization of Xe and He, and an indirect ionization (Penning effect) by an active helium. 37 refs., 12 figs.

Synthesis of refractory organic matter in the ionized gas phase of the solar nebula.

Science.gov (United States)

Kuga, Maïa; Marty, Bernard; Marrocchi, Yves; Tissandier, Laurent

2015-06-09

In the nascent solar system, primitive organic matter was a major contributor of volatile elements to planetary bodies, and could have played a key role in the development of the biosphere. However, the origin of primitive organics is poorly understood. Most scenarios advocate cold synthesis in the interstellar medium or in the outer solar system. Here, we report the synthesis of solid organics under ionizing conditions in a plasma setup from gas mixtures (H2(O)-CO-N2-noble gases) reminiscent of the protosolar nebula composition. Ionization of the gas phase was achieved at temperatures up to 1,000 K. Synthesized solid compounds share chemical and structural features with chondritic organics, and noble gases trapped during the experiments reproduce the elemental and isotopic fractionations observed in primitive organics. These results strongly suggest that both the formation of chondritic refractory organics and the trapping of noble gases took place simultaneously in the ionized areas of the protoplanetary disk, via photon- and/or electron-driven reactions and processing. Thus, synthesis of primitive organics might not have required a cold environment and could have occurred anywhere the disk is ionized, including in its warm regions. This scenario also supports N2 photodissociation as the cause of the large nitrogen isotopic range in the solar system.

Collisions of fast multicharged ions in gas targets: charge transfer and ionization

International Nuclear Information System (INIS)

Schlachter, A.S.

1981-05-01

Measurements of cross sections for charge transfer and ionization of H 2 and rare-gas targets have been made with fast, highly stripped projectiles in charge states as high as 59+. We have found an empirical scaling rule for electron-capture cross section in H 2 valid at energies above 275 keV/amu. Similar scaling might exist for other target gases. Cross sections are generally in good agreement with theory. We have found a scaling rule for electron loss from H in collisions with a fast highly stripped projectile, based on Olson's classical-trajectory Monte-Carlo calculations, and confirmed by measurements in an H 2 target. We have found a similar scaling rule for net ionization of rare-gas targets, based on Olson's CTMC calculations and the independent-electron model. Measurements are essentially consistent with the scaled cross sections. Calculations and measurements of recoil-ion charge-state spectra show large cross sections for the production of highly charged slow recoil ions

A new in-gas-laser ionization and spectroscopy laboratory for off-line studies at KU Leuven

International Nuclear Information System (INIS)

Kudryavtsev, Yu.; Creemers, P.; Ferrer, R.; Granados, C.; Gaffney, L.P.; Huyse, M.; Mogilevskiy, E.; Raeder, S.; Sels, S.; Van den Bergh, P.; Van Duppen, P.; Zadvornaya, A.

2016-01-01

The in-gas laser ionization and spectroscopy (IGLIS) technique is used to produce and to investigate short-lived radioactive isotopes at on-line ion beam facilities. In this technique, the nuclear reaction products recoiling out of a thin target are thermalized and neutralized in a high-pressure noble gas, resonantly ionized by the laser beams in a two-step process, and then extracted from the ion source to be finally accelerated and mass separated. Resonant ionization of radioactive species in the supersonic gas jet ensures very high spectral resolution because of essential reduction of broadening mechanisms. To obtain the maximum efficiency and the best spectral resolution, properties of the supersonic jet and the laser beams must be optimized. To perform these studies a new off-line IGLIS laboratory, including a new high-repetition-rate laser system and a dedicated off-line mass separator, has been commissioned. In this article, the specifications of the different components necessary to achieve optimum conditions in laser-spectroscopy studies of radioactive beams using IGLIS are discussed and the results of simulations are presented.

Mobilities of positive ions in gas ionization chambers

International Nuclear Information System (INIS)

Kusumegi, Asao

1990-01-01

Observed ion mobilities of organic molecules in Ar are compared with a complete polarization model to examine the performance of the model, and its applicability is discussed. In spite of its simplicity, the polarization model (small sphere limit) is found to agree satisfactorily with observed mobilities in the case of alkali ions in Ar. However, the model fails to account for the mobility of Ar + in Ar due to a resonant charge transfer interaction between the ion and the parent gas. On the other hand, the values of k, a parameter which depends on the kinetic and the potential energy of the relevant ion, derived from observed ion mobilities of organic molecules in Ar and in the parent gas are found to be close to each other. Except for few cases, it appears that the complete polarization model gives a reasonable approximation for the positive ion mobilities of organic molecules in Ar, though the importance of the ion mass identification is significant in considering the applicability of the model to the positive ion mobility of those organic molecules in Ar used in a gas ionization chamber. (N.K.)

Aerodynamic Effects in Weakly Ionized Gas: Phenomenology and Applications

International Nuclear Information System (INIS)

Popovic, S.; Vuskovic, L.

2006-01-01

Aerodynamic effects in ionized gases, often neglected phenomena, have been subject of a renewed interest in recent years. After a brief historical account, we discuss a selected number of effects and unresolved problems that appear to be relevant in both aeronautic and propulsion applications in subsonic, supersonic, and hypersonic flow. Interaction between acoustic shock waves and weakly ionized gas is manifested either as plasma-induced shock wave dispersion and acceleration or as shock-wave induced double electric layer in the plasma, followed by the localized increase of the average electron energy and density, as well as enhancement of optical emission. We describe the phenomenology of these effects and discuss several experiments that still do not have an adequate interpretation. Critical for application of aerodynamic effects is the energy deposition into the flow. We classify and discuss some proposed wall-free generation schemes with respect to the efficiency of energy deposition and overall generation of the aerodynamic body force

Use of electron ionization and atmospheric pressure chemical ionization in gas chromatography coupled to time-of-flight mass spetrometry for screening and identification of organic pollutants in waters

NARCIS (Netherlands)

Portoles, T.; Mol, J.G.J.; Sancho, J.V.; Hernandez, F.

2014-01-01

A new approach has been developed for multiclass screening of organic contaminants in water based on the use of gas chromatography coupled to hybrid quadrupole high-resolution time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC–(APCI)QTOF MS). The soft ionization

SDSS-IV MaNGA: the impact of diffuse ionized gas on emission-line ratios, interpretation of diagnostic diagrams and gas metallicity measurements

Science.gov (United States)

Zhang, Kai; Yan, Renbin; Bundy, Kevin; Bershady, Matthew; Haffner, L. Matthew; Walterbos, René; Maiolino, Roberto; Tremonti, Christy; Thomas, Daniel; Drory, Niv; Jones, Amy; Belfiore, Francesco; Sánchez, Sebastian F.; Diamond-Stanic, Aleksandar M.; Bizyaev, Dmitry; Nitschelm, Christian; Andrews, Brett; Brinkmann, Jon; Brownstein, Joel R.; Cheung, Edmond; Li, Cheng; Law, David R.; Roman Lopes, Alexandre; Oravetz, Daniel; Pan, Kaike; Storchi Bergmann, Thaisa; Simmons, Audrey

2017-04-01

Diffuse ionized gas (DIG) is prevalent in star-forming galaxies. Using a sample of 365 nearly face-on star-forming galaxies observed by Mapping Nearby Galaxies at APO, we demonstrate how DIG in star-forming galaxies impacts the measurements of emission-line ratios, hence the interpretation of diagnostic diagrams and gas-phase metallicity measurements. At fixed metallicity, DIG-dominated low ΣHα regions display enhanced [S II]/Hα, [N II]/Hα, [O II]/Hβ and [O I]/Hα. The gradients in these line ratios are determined by metallicity gradients and ΣHα. In line ratio diagnostic diagrams, contamination by DIG moves H II regions towards composite or low-ionization nuclear emission-line region (LI(N)ER)-like regions. A harder ionizing spectrum is needed to explain DIG line ratios. Leaky H II region models can only shift line ratios slightly relative to H II region models, and thus fail to explain the composite/LI(N)ER line ratios displayed by DIG. Our result favours ionization by evolved stars as a major ionization source for DIG with LI(N)ER-like emission. DIG can significantly bias the measurement of gas metallicity and metallicity gradients derived using strong-line methods. Metallicities derived using N2O2 are optimal because they exhibit the smallest bias and error. Using O3N2, R23, N2 = [N II]/Hα and N2S2Hα to derive metallicities introduces bias in the derived metallicity gradients as large as the gradient itself. The strong-line method of Blanc et al. (IZI hereafter) cannot be applied to DIG to get an accurate metallicity because it currently contains only H II region models that fail to describe the DIG.

A new algorithm predicts pressure and temperature profiles of gas/gas-condensate transmission pipelines

Energy Technology Data Exchange (ETDEWEB)

Mokhatab, Saied [OIEC - Oil Industries' Engineering and Construction Group, Tehran (Iran, Islamic Republic of); Vatani, Ali [University of Tehran (Iran, Islamic Republic of)

2003-07-01

The main objective of the present study has been the development of a relatively simple analytical algorithm for predicting flow temperature and pressure profiles along the two-phase, gas/gas-condensate transmission pipelines. Results demonstrate the ability of the method to predict reasonably accurate pressure gradient and temperature gradient profiles under operating conditions. (author)

IONIZED GAS KINEMATICS AT HIGH RESOLUTION. V. [Ne ii], MULTIPLE CLUSTERS, HIGH EFFICIENCY STAR FORMATION, AND BLUE FLOWS IN HE 2–10

International Nuclear Information System (INIS)

Beck, Sara; Turner, Jean; Lacy, John; Greathouse, Thomas

2015-01-01

We measured the 12.8 μm [Ne ii] line in the dwarf starburst galaxy He 2–10 with the high-resolution spectrometer TEXES on the NASA IRTF. The data cube has a diffraction-limited spatial resolution of ∼1″ and a total velocity resolution, including thermal broadening, of ∼5 km s −1 . This makes it possible to compare the kinematics of individual star-forming clumps and molecular clouds in the three dimensions of space and velocity, and allows us to determine star formation efficiencies. The kinematics of the ionized gas confirm that the starburst contains multiple dense clusters. From the M/R of the clusters and the ≃30%–40% star formation efficiencies, the clusters are likely to be bound and long lived, like globulars. Non-gravitational features in the line profiles show how the ionized gas flows through the ambient molecular material, as well as a narrow velocity feature, which we identify with the interface of the H ii region and a cold dense clump. These data offer an unprecedented view of the interaction of embedded H ii regions with their environment

Ionization Waves in a Fast, Hollow-Cathode-Assisted Capillary Discharge

International Nuclear Information System (INIS)

Rutkevich, I.; Mond, M.; Kaufman, Y.; Choi, P.; Favre, M.

1999-01-01

The initial, low-current stage of the evolution of a soft x-ray emitting, hollow-cathode-assisted capillary discharge initiated by a steep high-voltage pulse is investigated. The capillary is surrounded by a shield having the cathode potential. The mean electric field E of the order of 10 kV/cm and the low gas pressure (P<1Torr) provide conditions for extensive electron runaway. This is taken into account in the formulation of the theoretical approach by retaining the inertial terms in the momentum equation for the electrons. In addition, the ionization rate is calculated by considering the cross section for ionization by high-energy electrons. The two-dimensional system of the basic equations is reduced to a system of one-dimensional equations for the axial distributions of the physical quantities by introducing appropriate radial profiles of the electric potential, and the electron gas parameters and satisfying the electrodynamic boundary conditions at the capillary wall and at the shield. The resulting system of equations admits solutions in the form of stationary ionization waves transferring the anode potential to the cathode end. Numerical calculations of such solutions for argon show that the wave velocity V increases with the gas pressure P and with the density of initial electron beam ejected from the cathode hole ahead of the ionization front, while the dependence of V on the applied voltage is weak. At the instant when the virtual anode reaches the cathode hole, the plasma in the capillary is not yet fully ionized. The traverse time of the ionization wave along the capillary calculated for various gas pressures is in reasonable agreement with experimentally registered time delay for a high-current stage resulting in voltage collapse and soft x-ray emission

The identification and rejection of energy-degraded events in gas ionization counters

International Nuclear Information System (INIS)

Ophel, T.R.; Fifield, L.K.; Catford, W.N.; Orr, N.A.; Woods, C.L.; Harding, A.; Clarkson, G.P.

1988-05-01

A common feature of the measurement of charged particles with gas detectors is the presence of a small fraction of events (∼0.1-0.2%) for which significantly less than total ionization is recorded. These events cause an energy tailing that can seriously impair the identification functions of gas detectors used either to instrument the focal plane of magnetic spectrometers or for accelerator mass spectrometry. The anomalous, energy-degraded events are shown to arise both from reactions between the incident ions and the detector gas and, more importantly from the scattering of ions by the gas. It is demonstrated that an appropriate detector configuration provides the means to reject most of the anomalous events, allowing the measurement of very low cross-section reactions without significant background interference from such events

Development of gas ionization chambers with coplanar electrodes for alpha-ray spectrometry

International Nuclear Information System (INIS)

Iwasaki, Kenta; Tanaka, Naomichi; Murakami, Kohei; Hasebe, Nobuyuki; Kusano, Hiroki; Shibamura, Eido; Miyajima, Mitsuhiro

2016-01-01

A large-area alpha-ray spectrometer is required to measure the low level alpha emitters in environmental samples, which may be distributed in the vicinity of nuclear power plants. A gas ionization chamber with a coplanar electrode has attractive features such as with mechanical ruggedness, easy handling, easy fabrication of large electrode, and relatively well-known performance. We have investigated the performance of a gas ionization chamber with a coplanar electrode for alpha-ray spectrometry, particularly in the energy resolution. The present experiment shows that the energy resolution in the full width at half maximum (FWHM) is 129 keV (= 2.7%) for alpha-rays from Np with an energy of 4.78 MeV, 120 keV (= 2.2%) for those with 5.49 MeV from Am, and 109 keV (= 1.9%) for those with 5.81 MeV from Cm. It is found that the energy resolution obtained at the present experiment is dominated in the electronic noise caused by the large capacitance existed between the collecting anode (CA) and non-collecting anode (NCA) in the coplanar electrode. (author)

Collisions of highly stripped ions at MeV energies in gas targets: charge transfer and ionization

International Nuclear Information System (INIS)

Schlachter, A.S.

1980-01-01

Cross sections have been measured for charge transfer and ionization in H 2 and rare-gas targets by fast, highly ionized carbon, iron, niobium, and lead ions in charge states +3 to +59, with energies in the range 0.1 to 4.8 MeV/amu. Experimental results are compared with classical-trajectory calculations; agreement is generally good. For a given target, the cross sections for net ionization reduce to a common curve when plotted as cross section divided by charge state versus energy per nucleon divided by charge state

Influence of gas mixture and primary ionization on the performance of limit streamer mode tubes

International Nuclear Information System (INIS)

An Jigang; Anderson, K.J.; Merritt, F.S.; Oreglia, M.; Pilcher, J.E.; Possoz, A.; Schappert, W.; Chicago Univ., IL

1988-01-01

We report a study of the dependence of limited streamer mode operation on gas composition. Results are given for the plateau onset voltage, plateau length, charge versus voltage, charge spectra and pulse width for various fractions of (Ar, CO 2 , pentane) and (Ar, isobutane). In addition, a series of argon-free strong quenching gas mixtures has been studied which have very attractive characteristics. Chamber lifetime tests for these are also reported. As part of a study of the nature of the limited streamer mode mechanism, the response to X-rays and minimum ionizing particles are compared and differences noted. The character of the primary ionization is found to have a clear effect on the chamber response even in the streamer region. (orig.)

Theory on a partially ionized gas centrifuge

International Nuclear Information System (INIS)

Berg, M.S. van den.

1982-01-01

This thesis contains a study of some flow processes occurring in the Gaswhirl experiments. In this apparatus a partially ionized gas is forced into rotation by an azimuthal electromagnetic force. After a short introduction in which a motivation is given of our research project, a comprehensive treatment is presented of the principle of rotating plasmas. Further, a historical review is given of rotating plasma systems. A derivation of the fundamental equations is given which describe the flow system mathematically and these are applied to rotating plasmas. The occurrence of secondary flows with radial and axial components is considered. This qualitative picture of secondary whirls is confirmed by measurements reported in the next chapter. The last chapter offers a possible explanation of the occurrence of the transition process in the Gaswhirl apparatus. (Auth.)

Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

Science.gov (United States)

Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

2002-08-25

Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

Highly informative multiclass profiling of lipids by ultra-high performance liquid chromatography - Low resolution (quadrupole) mass spectrometry by using electrospray ionization and atmospheric pressure chemical ionization interfaces.

Science.gov (United States)

Beccaria, Marco; Inferrera, Veronica; Rigano, Francesca; Gorynski, Krzysztof; Purcaro, Giorgia; Pawliszyn, Janusz; Dugo, Paola; Mondello, Luigi

2017-08-04

A simple, fast, and versatile method, using an ultra-high performance liquid chromatography system coupled with a low resolution (single quadrupole) mass spectrometer was optimized to perform multiclass lipid profiling of human plasma. Particular attention was made to develop a method suitable for both electrospray ionization and atmospheric pressure chemical ionization interfaces (sequentially in positive- and negative-ion mode), without any modification of the chromatographic conditions (mobile phase, flow-rate, gradient, etc.). Emphasis was given to the extrapolation of the structural information based on the fragmentation pattern obtained using atmospheric pressure chemical ionization interface, under each different ionization condition, highlighting the complementary information obtained using the electrospray ionization interface, of support for related molecule ions identification. Furthermore, mass spectra of phosphatidylserine and phosphatidylinositol obtained using the atmospheric pressure chemical ionization interface are reported and discussed for the first time. Copyright © 2017 Elsevier B.V. All rights reserved.

Ionization instabilities of an electromagnetic wave propagating in a tenuous gas

International Nuclear Information System (INIS)

Bian Zhigang; Antonsen, Thomas M. Jr.

2001-01-01

A theory is developed to study the scattering instability that occurs when a laser pulse propagates through and ionizes a gas. The instability is due to the intensity dependence of the ionization rate, which leads to a transversely structured free electron density. The instability is convective in the frame of the laser pulse, but can have a relatively short growth length scaling as L g ∼k 0 /k p 2 , where k 0 is the laser wave number, k p 2 =ω p 2 /c 2 and ω p is the plasma frequency. The most unstable perturbations correspond to a scattering angle for which the transverse wave number is around the plasma wave number, k p . The scattered light is frequency upshifted. The comparison between simple analytic theory and numerical simulation shows good agreement

The Electron Temperature of a Partially Ionized Gas in an Electric Field

Energy Technology Data Exchange (ETDEWEB)

Robben, F

1968-03-15

The electron temperature of a partially ionized gas in an electric field can be determined by the collision rate for momentum transfer and the collision rate for energy transfer. Mean values of these rates are defined such that a simple expression for the electron temperature is obtained, and which depends, among other things, on the ratio of these mean rates. This ratio is calculated in the Lorentz approximation for power law cross sections, and also as a function of the degree of ionization for a helium plasma. It is pointed out that the complete results of refined transport theory can be used in calculating electron mobility and electron temperature in a multicomponent plasma without undue difficulty.

The Electron Temperature of a Partially Ionized Gas in an Electric Field

International Nuclear Information System (INIS)

Robben, F.

1968-03-01

The electron temperature of a partially ionized gas in an electric field can be determined by the collision rate for momentum transfer and the collision rate for energy transfer. Mean values of these rates are defined such that a simple expression for the electron temperature is obtained, and which depends, among other things, on the ratio of these mean rates. This ratio is calculated in the Lorentz approximation for power law cross sections, and also as a function of the degree of ionization for a helium plasma. It is pointed out that the complete results of refined transport theory can be used in calculating electron mobility and electron temperature in a multicomponent plasma without undue difficulty

Simulation study of the ionizing front in the critical ionization velocity phenomenon

International Nuclear Information System (INIS)

Machida, S.; Goertz, C.K.; Lu, G.

1988-01-01

Simulations of the Critical Ionization Velocity (CIV) for a neutral gas cloud moving across the static magnetic field are made. We treat a low-β plasma and use a 2-1/2 D electrostatic code linked with our Plasma and Neutral Interaction Code (PANIC). Our study is focused on the understanding of the interface between the neutral gas cloud and the surrounding plasma where the strong interaction takes place. We assume the existence of some hot electrons in the ambient plasma to provide a seed ionization for CIV. When the ionization starts a sheath-like structure is formed at the surface of the neutral gas (Ionizing Front). In that region the crossfield component of the electric field causes the electron to E x B drift with a velocity of the order of the neutral gas velocity times the square root of the ion to electron mass ratio. Thus the kinetic energy of the drifting electrons can be large enough for electron impact ionization. In addition a diamagnetic drift of the electron occurs due to the number density and temperature inhomogeneity in the ionization front. These drift currents excite the lower-hybrid waves with the wave k-vectors almost perpendicular to the neutral flow and magnetic field again resulting in electron heating and additional ionization. The overall structure is studied by developing a simple analytic model as well as making simulation runs. (author)

A Photo-Ionization Method for Black Hole Mass Estimation in Quasars

Directory of Open Access Journals (Sweden)

Marziani Paola

2011-09-01

Full Text Available Determining the masses of the central compact object believed to power all active galactic nuclei is relevant to our understanding of their evolution and of their inner workings. Keys to present-day mass estimates are: (1 the assumption of line broadening due to virial motion of the emitting gas, (2 an estimate of the distance of broad-line emitting gas from the central compact object, and (3 a measure of the AGN luminosity. We discuss the merits and the limitations of an alternative method based on estimates of physical conditions in the broad line emitting region derived from an appropriate multi-component analysis of emission line profiles. This ‘photo-ionization method’, applied to UV intermediate-ionization lines appears to be promising for at least a sizable population of high-z quasars.

The SAURON project : XVI. On the sources of ionization for the gas in elliptical and lenticular galaxies

NARCIS (Netherlands)

Sarzi, Marc; Shields, Joseph C.; Schawinski, Kevin; Jeong, Hyunjin; Shapiro, Kristen; Bacon, Roland; Bureau, Martin; Cappellari, Michele; Davies, Roger L.; de Zeeuw, P. Tim; Emsellem, Eric; Falcon-Barroso, Jesus; Krajnovic, Davor; Kuntschner, Harald; McDermid, Richard M.; Peletier, Reynier F.; van den Bosch, Remco C. E.; van de Ven, Glen; Yi, Sukyoung K.

Following our study on the incidence, morphology and kinematics of the ionized gas in early-type galaxies, we now address the question of what is powering the observed nebular emission. To constrain the likely sources of gas excitation, we resort to a variety of ancillary data we draw from

The SAURON project - XVI. On the sources of ionization for the gas in elliptical and lenticular galaxies

NARCIS (Netherlands)

Sarzi, Marc; Shields, Joseph C.; Schawinski, Kevin; Jeong, Hyunjin; Shapiro, Kristen; Bacon, Roland; Bureau, Martin; Cappellari, Michele; Davies, Roger L.; de Zeeuw, P. Tim; Emsellem, Eric; Falcón-Barroso, Jesús; Krajnović, Davor; Kuntschner, Harald; McDermid, Richard M.; Peletier, Reynier F.; van den Bosch, Remco C. E.; van de Ven, Glen; Yi, Sukyoung K.

Following our study on the incidence, morphology and kinematics of the ionized gas in early-type galaxies, we now address the question of what is powering the observed nebular emission. To constrain the likely sources of gas excitation, we resort to a variety of ancillary data we draw from

Ionization front accelerator

International Nuclear Information System (INIS)

Olson, C.L.

1975-01-01

In a recently proposed linear collective accelerator, ions are accelerated in a steep, moving potential well created at the head of an intense relativistic electron beam. The steepness of the potential well and its motion are controlled by the external ionization of a suitable background gas. Calculations concerning optimum choices for the background gas and the ionization method are presented; a two-step photoionization process employing Cs vapor is proposed. In this process, a super-radiant light source is used to excite the gas, and a UV laser is used to photoionize the excited state. The appropriate line widths and coupled ionization growth rate equations are discussed. Parameter estimates are given for a feasibility experiment, for a 1 GeV proton accelerator, and for a heavy ion accelerator (50 MeV/nucleon uranium). (auth)

Image simulation of high-speed imaging by high-pressure gas ionization detector

International Nuclear Information System (INIS)

Miao Jichen; Liu Ximing; Wu Zhifang

2005-01-01

The signal of the neighbor pixels is cumulated in Freight Train Inspection System because data fetch time is shorter than ion excursion time. This paper analyzes the pertinency of neighbor pixels and designs computer simulation method to generate some emulate images such as indicator image. The result indicates the high-pressure gas ionization detector can be used in high-speed digital radiography field. (authors)

An Ionization Profile Monitor for the Tevatron

CERN Document Server

Jansson, Andreas; Bowie, Kwame; Bross, Alan; Dysert, Robert; Fitzpatrick, Thomas; Kwarciany, Richard; Lundberg, Carl; Nguyen, Hogan; Rivetta, Claudio H; Slimmer, David; Valerio, Linda; Zagel, James

2005-01-01

Primarily to study emittance blowup during injection and ramping, an ionization profile monitor has been developed for the Tevatron. It is based on a prototype installed in the Main Injector, although with extensive modifications. In particular, the electromagnetic shielding has been improved, the signal path has been cleaned up, and provisions have been made for an internal electron source. Due to the good Tevatron vacuum, a local pressure bump is introduced to increase the primary signal, which is then amplified by a microchannel plate and detected on anode strips. For the DAQ, a custom ASIC developed for the CMS experiment is used. It is a combined charge integrator and digitizer, with a sensitivity of a few fC, and a time-resolution that allows single bunch measurement. Digitization is done in the tunnel to reduce noise. Preparations for detector installation were made during the long 2004 shutdown, with the installation of magnets, vacuum chambers, vacuum pumps and cabling. The actual detector will be in...

Relationships between structure, ionization profile and sensitivity of exogenous anabolic steroids under electrospray ionization and analysis in human urine using liquid chromatography-tandem mass spectrometry.

Science.gov (United States)

Cha, Eunju; Kim, Sohee; Kim, Hee Won; Lee, Kang Mi; Kim, Ho Jun; Kwon, Oh-Seung; Lee, Jaeick

2016-04-01

The relationships between the ionization profile, sensitivity, and structures of 64 exogenous anabolic steroids (groups I-IV) was investigated under electrospray ionization (ESI) conditions. The target analytes were ionized as [M + H](+) or [M + H-nH2 O](+) in the positive mode, and these ions were used as precursor ions for selected reaction monitoring analysis. The collision energy and Q3 ions were optimized based on the sensitivity and selectivity. The limits of detection (LODs) were 0.05-20 ng/mL for the 64 steroids. The LODs for 38 compounds, 14 compounds and 12 compounds were in the range of 0.05-1, 2-5 and 10-20 ng/mL, respectively. Steroids including the conjugated keto-functional group at C3 showed good proton affinity and stability, and generated the [M + H](+) ion as the most abundant precursor ion. In addition, the LODs of steroids using the [M + H](+) ion as the precursor ion were mostly distributed at low concentrations. In contrast, steroids containing conjugated/unconjugated hydroxyl functional groups at C3 generated [M + H - H2 O](+) or [M + H - 2H2 O](+) ions, and these steroids showed relatively high LODs owing to poor stability and multiple ion formation. An LC-MS/MS method based on the present ionization profile was developed and validated for the determination of 78 steroids (groups I-V) in human urine. Copyright © 2015 John Wiley & Sons, Ltd.

Simulation of the Interaction of X-rays with a Gas in an Ionization Chamber by the Monte Carlo Method

International Nuclear Information System (INIS)

Grau Carles, A.; Garcia Gomez-Tejedor, G.

2001-01-01

The final objective of any ionization chamber is the measurement of the energy amount or radiation dose absorbed by the gas into the chamber. The final value depends on the composition of the gas, its density and temperature, the ionization chamber geometry, and type and intensity of the radiation. We describe a Monte Carlo simulation method, which allows one to compute the dose absorbed by the gas for a X-ray beam. Verification of model has been carried out by simulating the attenuation of standard X-ray radiation through the half value layers established in the ISO 4037 report, while assuming a Weibull type energy distribution for the incident photons. (Author) 6 refs

First successful ionization of Lr (Z = 103) by a surface-ionization technique

Energy Technology Data Exchange (ETDEWEB)

Sato, Tetsuya K., E-mail: sato.tetsuya@jaea.go.jp; Sato, Nozomi; Asai, Masato; Tsukada, Kazuaki; Toyoshima, Atsushi; Ooe, Kazuhiro; Miyashita, Sunao; Schädel, Matthias [Advanced Science Research Center, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata-shirane, Tokai-mura, Ibaraki 319-1195 (Japan); Kaneya, Yusuke; Nagame, Yuichiro [Advanced Science Research Center, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata-shirane, Tokai-mura, Ibaraki 319-1195 (Japan); Graduate School of Science and Engineering, Ibaraki University, 2-1-1, Bunkyo, Mito, Ibaraki 310-8512 (Japan); Osa, Akihiko [Department of Research Reactor and Tandem Accelerator, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata shirane, Tokai-mura, Ibaraki 319-1195 (Japan); Ichikawa, Shin-ichi [Advanced Science Research Center, Japan Atomic Energy Agency (JAEA), 2-4 Shirakata-shirane, Tokai-mura, Ibaraki 319-1195 (Japan); Nishina Center for Accelerator-Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Stora, Thierry [ISOLDE, CERN, CH-1211 Geneva 23 (Switzerland); Kratz, Jens Volker [Institut für Kernchemie, Universität Mainz, D-55099 Mainz (Germany)

2013-02-15

We have developed a surface ionization ion-source as part of the JAEA-ISOL (Isotope Separator On-Line) setup, which is coupled to a He/CdI{sub 2} gas-jet transport system to determine the first ionization potential of the heaviest actinide lawrencium (Lr, Z = 103). The new ion-source is an improved version of the previous source that provided good ionization efficiencies for lanthanides. An additional filament was newly installed to give better control over its operation. We report, here, on the development of the new gas-jet coupled surface ion-source and on the first successful ionization and mass separation of 27-s {sup 256}Lr produced in the {sup 249}Cf + {sup 11}B reaction.

Instantaneous characterization of vegetable oils via TAG and FFA profiles by easy ambient sonic-spray ionization mass spectrometry.

Science.gov (United States)

Simas, Rosineide C; Catharino, Rodrigo R; Cunha, Ildenize B S; Cabral, Elaine C; Barrera-Arellano, Daniel; Eberlin, Marcos N; Alberici, Rosana M

2010-04-01

A fast and reliable method is presented for the analysis of vegetable oils. Easy ambient sonic-spray ionization mass spectrometry (EASI-MS) is shown to efficiently desorb and ionize the main oil constituents from an inert surface under ambient conditions and to provide comprehensive triacylglyceride (TAG) and free fatty acid (FFA) profiles detected mainly as either [TAG + Na](+) or [FFA-H](-) ions. EASI(+/-)-MS analysis is simple, easily implemented, requires just a tiny droplet of the oil and is performed without any pre-separation or chemical manipulation. It also causes no fragmentation of TAG ions hence diacylglyceride (DAG) and monoacylglyceride (MAG) profiles and contents can also be measured. The EASI(+/-)-MS profiles of TAG and FFA permit authentication and quality control and can be used, for instance, to access levels of adulteration, acidity, oxidation or hydrolysis of vegetable oils in general.

Performance of a high repetition pulse rate laser system for in-gas-jet laser ionization studies with the Leuven laser ion source LISOL

International Nuclear Information System (INIS)

Ferrer, R.; Sonnenschein, V.T.; Bastin, B.; Franchoo, S.; Huyse, M.; Kudryavtsev, Yu.; Kron, T.; Lecesne, N.; Moore, I.D.; Osmond, B.; Pauwels, D.; Radulov, D.; Raeder, S.; Rens, L.

2012-01-01

The laser ionization efficiency of the Leuven gas cell-based laser ion source was investigated under on- and off-line conditions using two distinctly different laser setups: a low-repetition rate dye laser system and a high-repetition rate Ti:sapphire laser system. A systematic study of the ion signal dependence on repetition rate and laser pulse energy was performed in off-line tests using stable cobalt and copper isotopes. These studies also included in-gas-jet laser spectroscopy measurements on the hyperfine structure of 63 Cu. A final run under on-line conditions in which the radioactive isotope 59 Cu (T 1/2 = 81.5 s) was produced, showed a comparable yield of the two laser systems for in-gas-cell ionization. However, a significantly improved time overlap by using the high-repetition rate laser system for in-gas-jet ionization was demonstrated by an increase of the overall duty cycle, and at the same time, pointed to the need for a better shaped atomic jet to reach higher ionization efficiencies.

Flatness of two-dimensional beam profile measured with an ionization chamber array

International Nuclear Information System (INIS)

Stefanovski, Z.

2006-01-01

Open beam profiles are basic dosimetric characteristics for the formation of the dose calculation algorithms parameters and for determination of beam quality. One characteristic of the beam profiles as a measure for the beam quality is the field flatness defined as ratio of the difference of maximum and minimum dose in central 80% of the field to the sum of these doses in the part of the field. The measurements, instead with an ordinary ionization chamber, were performed with a chamber array in two depths (1.6 cm and 10 cm) in water phantom. Nominal photon beam energy was 6 MV and field size was 25 cm x 25 cm on the water surface. Field flatness was in the range of 1-2 % which is in accordance with the data acquired during the acceptance testing and commissioning of the accelerators. with the array chamber the beam profiles can be performed quickly and preciously. These features recommend a chamber array as an excellent tool for periodic quality control of beam profiles. (Author)

The ionization mechanisms in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

Science.gov (United States)

Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

2014-11-01

A novel, gas-tight API interface for gas chromatography-mass spectrometry was used to study the ionization mechanism in direct and dopant-assisted atmospheric pressure photoionization (APPI) and atmospheric pressure laser ionization (APLI). Eight analytes (ethylbenzene, bromobenzene, naphthalene, anthracene, benzaldehyde, pyridine, quinolone, and acridine) with varying ionization energies (IEs) and proton affinities (PAs), and four common APPI dopants (toluene, acetone, anisole, and chlorobenzene) were chosen. All the studied compounds were ionized by direct APPI, forming mainly molecular ions. Addition of dopants suppressed the signal of the analytes with IEs above the IE of the dopant. For compounds with suitable IEs or Pas, the dopants increased the ionization efficiency as the analytes could be ionized through dopant-mediated gas-phase reactions, such as charge exchange, proton transfer, and other rather unexpected reactions, such as formation of [M + 77](+) in the presence of chlorobenzene. Experiments with deuterated toluene as the dopant verified that in case of proton transfer, the proton originated from the dopant instead of proton-bound solvent clusters, as in conventional open or non-tight APPI sources. In direct APLI using a 266 nm laser, a narrower range of compounds was ionized than in direct APPI, because of exceedingly high IEs or unfavorable two-photon absorption cross-sections. Introduction of dopants in the APLI system changed the ionization mechanism to similar dopant-mediated gas-phase reactions with the dopant as in APPI, which produced mainly ions of the same form as in APPI, and ionized a wider range of analytes than direct APLI.

The sensitivity and dynamic response of field ionization gas sensor based on ZnO nanorods

International Nuclear Information System (INIS)

Min Jiahua; Liang Xiaoyan; Wang Bin; Wang Linjun; Zhao Yue; Shi Weimin; Xia Yiben

2011-01-01

Field ionization gas sensors based on ZnO nanorods (50–300 nm in diameter, and 3–8 μm in length) with and without a buffer layer were fabricated, and the influence of the orientation of nano-ZnO on the ionization response of devices was discussed, including the sensitivity and dynamic response of the ZnO nanorods with preferential orientation. The results indicated that ZnO nanorods as sensor anode could dramatically decrease the breakdown voltage. The XRD and SEM images illustrated that nano-ZnO with a ZnO buffer layer displayed high c-axis orientation, which helps to significantly reduce the breakdown voltage. Device A based on ZnO nanorods with a ZnO buffer layer could distinguish toluene and acetone. The dynamic responses of device A to the NO x compounds presented the sensitivity of 0.045 ± 0.007 ppm/pA and the response speed within 17–40 s, and indicated a linear relationship between NO x concentration and current response at low NO x concentrations. In addition, the dynamic responses to benzene, isopropyl alcohol, ethanol, and methanol reveals that the device has higher sensitivity to gas with larger static polarizability and lower ionization energy.

Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

International Nuclear Information System (INIS)

Saheed, Mohamed Shuaib Mohamed; Mohamed, Norani Muti; Burhanudin, Zainal Arif

2012-01-01

Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 μm. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 μm can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

Energy Technology Data Exchange (ETDEWEB)

Saheed, Mohamed Shuaib Mohamed; Mohamed, Norani Muti; Burhanudin, Zainal Arif [Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Fundamental and Applied Science, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia)

2012-09-26

Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 {mu}m. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 {mu}m can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

Quantitative study of the ionization-induced refraction of picosecond laser pulses in gas-jet targets

International Nuclear Information System (INIS)

Mackinnon, A.J.; Borghesi, M.; Iwase, A.; Jones, M.W.; Pert, G.J.; Rae, S.; Burnett, K.; Willi, O.

1996-01-01

A quantitative study of refractive whole beam defocusing and small scale breakup induced by optical ionization of subpicosecond and picosecond, 0.25 and 1 μm, laser pulses in gas-jet targets at densities above 1x10 19 cm -3 has been carried out. A significant reduction of the incident laser intensity was observed due to refraction from ionization-induced density gradients. The level of refraction measured with optical probing correlated well with the fraction of energy transmitted through the plasma. The numerical and analytical models were found to agree well with experimental observations. copyright 1996 The American Physical Society

Electron kinetics modeling in a weakly ionized gas

International Nuclear Information System (INIS)

Boeuf, Jean-Pierre

1985-01-01

This work presents some features of electron kinetics in a weakly ionized gas. After a summary of the basis and recent developments of the kinetic theory, and a review of the most efficient numerical techniques for solving the Boltzmann equation, several aspects of electron motion in gases are analysed. Relaxation phenomena toward equilibrium under a uniform electric field, and the question of the existence of the hydrodynamic regime are first studied. The coupling between electron kinetics and chemical kinetics due to second kind collisions in Nitrogen is then analysed; a quantitative description of the evolution of the energy balance, accounting for electron-molecule as well as molecule-molecule energy transfer is also given. Finally, electron kinetics in space charge distorted, highly non uniform electric fields (glow discharges, streamers propagation) is investigated with microscopic numerical methods based on Boltzmann and Poisson equations. (author) [fr

Gas chromatography with simultaneous detection: Ultraviolet spectroscopy, flame ionization, and mass spectrometry.

Science.gov (United States)

Gras, Ronda; Luong, Jim; Haddad, Paul R; Shellie, Robert A

2018-05-08

An effective analytical strategy was developed and implemented to exploit the synergy derived from three different detector classes for gas chromatography, namely ultraviolet spectroscopy, flame ionization, and mass spectrometry for volatile compound analysis. This strategy was achieved by successfully hyphenating a user-selectable multi-wavelength diode array detector featuring a positive temperature coefficient thermistor as an isothermal heater to a gas chromatograph. By exploiting the non-destructive nature of the diode array detector, the effluent from the detector was split to two parallel detectors; namely a quadrupole mass spectrometer and a flame ionization detector. This multi-hyphenated configuration with the use of three detectors is a powerful approach not only for selective detection enhancement but also for improvement in structural elucidation of volatile compounds where fewer fragments can be obtained or for isomeric compound analysis. With the diode array detector capable of generating high resolution gas phase spectra, the information collected provides useful confirmatory information without a total dependence on the chromatographic separation process which is based on retention time. This information-rich approach to chromatography is achieved without incurring extra analytical time, resulting in improvements in compound identification accuracy, analytical productivity, and cost. Chromatographic performance obtained from model compounds was found to be acceptable with a relative standard deviation of the retention times of less than 0.01% RSD, and a repeatability at two levels of concentration of 100 and 1000 ppm (v/v) of less than 5% (n = 10). With this configuration, correlation of data between the three detectors was simplified by having near identical retention times for the analytes studied. Copyright © 2018 Elsevier B.V. All rights reserved.

Instantaneous Characterization Of Vegetable Oils Via Tag And Ffa Profiles By Easy Ambient Sonic-spray Ionization Mass Spectrometry.

OpenAIRE

Simas, Rosineide C; Catharino, Rodrigo R; Cunha, Ildenize B S; Cabral, Elaine C; Barrera-Arellano, Daniel; Eberlin, Marcos N; Alberici, Rosana M

2015-01-01

A fast and reliable method is presented for the analysis of vegetable oils. Easy ambient sonic-spray ionization mass spectrometry (EASI-MS) is shown to efficiently desorb and ionize the main oil constituents from an inert surface under ambient conditions and to provide comprehensive triacylglyceride (TAG) and free fatty acid (FFA) profiles detected mainly as either [TAG + Na](+) or [FFA-H](-) ions. EASI(+/-)-MS analysis is simple, easily implemented, requires just a tiny droplet of the oil an...

Miniature ionization chamber

International Nuclear Information System (INIS)

Alexeev, V.I.; Emelyanov, I.Y.; Ivanov, V.M.; Konstantinov, L.V.; Lysikov, B.V.; Postnikov, V.V.; Rybakov, J.V.

1976-01-01

A miniature ionization chamber having a gas-filled housing which accommodates a guard electrode made in the form of a hollow perforated cylinder is described. The cylinder is electrically associated with the intermediate coaxial conductor of a triaxial cable used as the lead-in of the ionization chamber. The gas-filled housing of the ionization chamber also accommodates a collecting electrode shaped as a rod electrically connected to the center conductor of the cable and to tubular members. The rod is disposed internally of the guard electrode and is electrically connected, by means of jumpers passing through the holes in the guard electrode, to the tubular members. The tubular members embrace the guard electrode and are spaced a certain distance apart along its entire length. Arranged intermediate of these tubular members are spacers secured to the guard electrode and fixing the collecting electrode throughout its length with respect to the housing of the ionization chamber

Transport processes in ionized gases

International Nuclear Information System (INIS)

Kremer, G.M.

1997-01-01

Based on kinetic theory of gases and on the combined of Chapman-Enskog and Grad, the laws of Ohm, Fourier and Navier-Stokes are derived for a non-relativistic fully ionized gas. Moreover, the combined method is applied to the BGK model of the relativistic Boltzmann equation and the Ohm's law is derived for a relativistic fully ionized gas. (author)

Ionization cell for sensing and measuring gaseous impurities

International Nuclear Information System (INIS)

Castelman, B.W.

1978-01-01

An improved gas ionization cell is described with compensation for variations in flow rate of the gas and variations in radioactive source intensity. A gas sample is directed past a source of ionizing radiation and through a recombination region to an ion collection screen, where output current is monitored to give an indication of trace gases or vapors present in the gas under surveillance. Compensation for changes in gas flow rate and source intensity is provided by taking a portion of the gas subjected to the ionizing radiation and directing that portion of the gas through a channel by-passing the recombination region of the cell and past a pair of conductive probes. The first probe of the pair is biased at a predetermined voltage, while electric current is monitored at the second probe spaced downstream from the first probe. The current generated at the second probe, which is for all practical purposes a function of only the rate of gas flow and the source intensity, provides the compensation signal for the ionization cell. 4 claims, 8 figures

Electron impact ionization of the gas-phase sorbitol

Science.gov (United States)

Chernyshova, Irina; Markush, Pavlo; Zavilopulo, Anatoly; Shpenik, Otto

2015-03-01

Ionization and dissociative ionization of the sorbitol molecule by electron impact have been studied using two different experimental methods. In the mass range of m/ z = 10-190, the mass spectra of sorbitol were recorded at the ionizing electron energies of 70 and 30 eV. The ion yield curves for the fragment ions have been analyzed and the appearance energies of these ions have been determined. The relative total ionization cross section of the sorbitol molecule was measured using monoenergetic electron beam. Possible fragmentation pathways for the sorbitol molecule were proposed.

Classical electron ionization mass spectra in gas chromatography/mass spectrometry with supersonic molecular beams.

Science.gov (United States)

Gordin, Alexander; Fialkov, Alexander B; Amirav, Aviv

2008-09-01

A major benefit of gas chromatography/mass spectrometry (GC/MS) with a supersonic molecular beam (SMB) interface and its fly-through ion source is the ability to obtain electron ionization of vibrationally cold molecules (cold EI), which show enhanced molecular ions. However, GC/MS with an SMB also has the flexibility to perform 'classical EI' mode of operation which provides mass spectra to mimic those in commercial 70 eV electron ionization MS libraries. Classical EI in SMB is obtained through simple reduction of the helium make-up gas flow rate, which reduces the SMB cooling efficiency; hence the vibrational temperatures of the molecules are similar to those in traditional EI ion sources. In classical EI-SMB mode, the relative abundance of the molecular ion can be tuned and, as a result, excellent identification probabilities and very good matching factors to the NIST MS library are obtained. Classical EI-SMB with the fly-through dual cage ion source has analyte sensitivity similar to that of the standard EI ion source of a basic GC/MS system. The fly-through EI ion source in combination with the SMB interface can serve for cold EI, classical EI-SMB, and cluster chemical ionization (CCI) modes of operation, all easily exchangeable through a simple and quick change (not involving hardware). Furthermore, the fly-through ion source eliminates sample scattering from the walls of the ion source, and thus it offers full sample inertness, tailing-free operation, and no ion-molecule reaction interferences. It is also robust and enables increased column flow rate capability without affecting the sensitivity.

Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

CERN Document Server

Rondo, L.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

2016-01-01

Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosolnucleation. Based on quantum chemical calculations it has been suggested that the quantitative detectionof gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased inthe presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was setup at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection ofH2SO4in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time inthe CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF(Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutralsulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presenceof dimethylamine (<5 to 70 pptv) the sulfuric acid monomer measured by the CIMS...

[Determination of acetanilide herbicide residues in tea by gas chromatography-mass spectrometry with two different ionization techniques].

Science.gov (United States)

Shen, Weijian; Xu, Jinzhong; Yang, Wenquan; Shen, Chongyu; Zhao, Zengyun; Ding, Tao; Wu, Bin

2007-09-01

An analytical method of solid phase extraction-gas chromatography-mass spectrometry with two different ionization techniques was established for simultaneous determination of 12 acetanilide herbicide residues in tea-leaves. Herbicides were extracted from tea-leaf samples with ethyl acetate. The extract was cleaned-up on an active carbon SPE column connected to a Florisil SPE column. Analytical screening was determined by the technique of gas chromatography (GC)-mass spectrometry (MS) in the selected ion monitoring (SIM) mode with either electron impact ionization (EI) or negative chemical ionization (NCI). It is reliable and stable that the recoveries of all herbicides were in the range from 50% to 110% at three spiked levels, 10 microg/kg, 20 microg/kg and 40 microg/kg, and the relative standard deviations (RSDs) were no more than 10.9%. The two different ionization techniques are complementary as more ion fragmentation information can be obtained from the EI mode while more molecular ion information from the NCI mode. By comparison of the two techniques, the selectivity of NCI-SIM was much better than that of EI-SIM method. The sensitivities of the both techniques were high, the limit of quantitative (LOQ) for each herbicide was no more than 2.0 microg/kg, and the limit of detection (LOD) with NCI-SIM technique was much lower than that of EI-SIM when analyzing herbicides with several halogen atoms in the molecule.

Quantitative Profiling of Major Neutral Lipid Classes in Human Meibum by Direct Infusion Electrospray Ionization Mass Spectrometry

Science.gov (United States)

Chen, Jianzhong; Green, Kari B.; Nichols, Kelly K.

2013-01-01

Purpose. The purpose of this investigation was to better understand lipid composition in human meibum. Methods. Intact lipids in meibum samples were detected by direct infusion electrospray ionization mass spectrometry (ESI-MS) analysis in positive detection mode using sodium iodide (NaI) as an additive. The peak intensities of all major types of lipid species, that is, wax esters (WEs), cholesteryl esters (CEs), and diesters (DEs) were corrected for peak overlapping and isotopic distribution; an additional ionization efficiency correction was performed for WEs and CEs, which was simplified by the observation that the corresponding ionization efficiency was primarily dependent on the specific lipid class and saturation degree of the lipids while independent of the carbon chain length. A set of WE and CE standards was spiked in meibum samples for ionization efficiency determination and absolute quantitation. Results. The absolute amount (μmol/mg) for each of 51 WEs and 31 CEs in meibum samples was determined. The summed masses for 51 WEs and 31 CEs accounted for 48 ± 4% and 40 ± 2%, respectively, of the total meibum lipids. The mass percentages of saturated and unsaturated species were determined to be 75 ± 2% and 25 ± 1% for CEs and 14 ± 1% and 86 ± 1% for WEs. The profiles for two types of DEs were also obtained, which include 42 α,ω Type II DEs, and 21 ω Type I-St DEs. Conclusions. Major neutral lipid classes in meibum samples were quantitatively profiled by ESI-MS analysis with NaI additive. PMID:23847307

Average energy expended per ion pair, exciton enhanced ionization (Jesse effect), electron drift velocity, average electron energy and scintillation in rare gas liquids

International Nuclear Information System (INIS)

Doke, T.; Hitachi, A.; Hoshi, Y.; Masuda, K.; Hamada, T.

1977-01-01

Precise measurements of W-values, the average energy expended per electron-hole pair in liquid Ar and Xe, were made by the electron-pulse method, and that in liquid Kr by the steady conduction current method. The results showed that the W-values were clearly smaller than those in gaseous Ar, Xe and Kr as predicted by Doke. The results can be explained by the conduction bands which exist in these rare gas liquids as well as in the solid state. The enhanced ionization yield was observed for Xe-doped liquid Ar, and it was attributed to the ionizing excitation transfer process from Ar excitons to doped Xe. This is very similar to the Jesse effect in the gas phase. The saturated value of the enhanced ionization was in good agreement with the theoretical value, and it provides strong evidence for the existence of the exciton states in liquid Ar. Fano factors in liquid Ar, Kr, Xe and Xe-doped liquid Ar have been estimated from the Fano Formula, and they were smaller than those in the gas phase. The drift velocity of electrons in liquid Ar, liquid Ar-gas mixtures and liquid Xe have been measured with gridded ionization chambers. The average electron energy in liquid Ar has been measured. The electron-induced scintillations of liquid Xe and Ar have been studied. (Kato, T.)

Quantitative analysis of abused drugs in physiological fluids by gas chromatography/chemical ionization mass spectrometry

International Nuclear Information System (INIS)

Foltz, R.L.

1978-01-01

Methods have been developed for quantitative analysis of commonly abused drugs in physiological fluids using gas chromatography/chemical ionization mass spectrometry. The methods are being evaluated in volunteer analytical and toxicological laboratories, and analytical manuals describing the methods are being prepared. The specific drug and metabolites included in this program are: Δ 9 -tetrahydrocannabinol, methadone, phencyclidine, methaqualone, morphine, amphetamine, methamphetamine, mescaline, 2,5-dimethoxy-4-methyl amphetamine, cocaine, benzoylecgonine, diazepam, and N-desmethyldiazepam. The current analytical methods utilize relatively conventional instrumentation and procedures, and are capable of measuring drug concentrations as low as 1 ng/ml. Various newer techniques such as sample clean-up by high performance liquid chromatography, separation by glass capillary chromatography, and ionization by negative ion chemical ionization are being investigated with respect to their potential for achieving higher sensitivity and specificity, as well as their ability to facilitate simultaneous analysis of more than one drug and metabolite. (Auth.)

Development of a He/CdI$_2$ gas-jet system coupled to a surface-ionization type ion-source in JAEA-ISOL: towards determination of the first ionization potential of Lr (Z = 103)

CERN Document Server

Sato, T K; Sato, N; Tsukada, K; Toyoshima, A; Ooe, K; Miyashita, S; Kaneya, Y; Osa, A; Schädel, M; Nagame, Y; Ichikawa, S; Stora, T; Kratz, J V

2015-01-01

We report on development of a gas-jet transport system coupled to a surface ionization ion-source in the JAEA-ISOL (Isotope Separator On-Line) system. As a new aerosol material for the gas-jet system, CdI2, which has a low boiling point of 713 °C, is exploited to prevent deposition of the aerosol material on the surface of the ion-source. An additional filament is newly installed in the previous ion-source to provide uniform heating of an ionizer. The present system is applied to the measurement of absolute efficiencies of various short-lived lanthanide isotopes produced in nuclear reactions.

A New Approach to Gas Discharge Theory with Sheath Boundaries

Science.gov (United States)

Chen, Francis F.; Curreli, Davide

Classical theories of gas discharges have concentrated on the microscopic properties of collisions and diffusion coefficients, but few have considered the macroscopic observables such as the density and temperature profiles. Since practical devices cannot be approximated by infinite cylinders, we consider finite cylinders with endplates. There, the short-circuit effect permits electrons to be Maxwellian even in the presence of a DC magnetic field. For uniform electron temperature Te and pressure p, the radial density profile is found to have a "universal" shape independent of p. A code EQM is developed to solve for radial profiles when all quantities vary with r and includes ionization balance and neutral depletion. The profile Te(r) depends on the type of discharge and is found for helicon discharges by iterating with the code HELIC. Resulting n(r) profiles are flat or peaked on axis, as found in experiment, even when ionization is localized to the edge.

In gas laser ionization and spectroscopy experiments at the Superconducting Separator Spectrometer (S3): Conceptual studies and preliminary design

International Nuclear Information System (INIS)

Ferrer, R.; Bastin, B.; Boilley, D.; Creemers, P.; Delahaye, P.; Liénard, E.; Fléchard, X.; Franchoo, S.; Ghys, L.; Huyse, M.; Kudryavtsev, Yu.; Lecesne, N.; Lu, H.; Lutton, F.; Mogilevskiy, E.; Pauwels, D.; Piot, J.; Radulov, D.; Rens, L.; Savajols, H.

2013-01-01

Highlights: • A setup to perform In-Gas Laser Ionization and Spectroscopy experiments at the Super Separator Spectrometer is presented. • The reported studies address important aspects necessary to applied the IGLIS technique to short-lived isotopes. • An R and D phase required to reach an enhanced spectral resolution will be carried out at KU Leuven. • High-sensitivity and enhanced-resolution laser spectroscopy studies will be possible with the IGLIS setup at S 3 . -- Abstract: The results of preparatory experiments and the preliminary designs of a new in-gas laser ionization and spectroscopy setup, to be coupled to the Super Separator Spectrometer S 3 of SPIRAL2-GANIL, are reported. Special attention is given to the development and tests to carry out a full implementation of the in-gas jet laser spectroscopy technique. Application of this novel technique to radioactive species will allow high-sensitivity and enhanced-resolution laser spectroscopy studies of ground- and excited-state properties of exotic nuclei

Breakdown voltage reduction by field emission in multi-walled carbon nanotubes based ionization gas sensor

Energy Technology Data Exchange (ETDEWEB)

Saheed, M. Shuaib M.; Muti Mohamed, Norani; Arif Burhanudin, Zainal, E-mail: zainabh@petronas.com.my [Centre of Innovative Nanostructures and Nanodevices, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

2014-03-24

Ionization gas sensors using vertically aligned multi-wall carbon nanotubes (MWCNT) are demonstrated. The sharp tips of the nanotubes generate large non-uniform electric fields at relatively low applied voltage. The enhancement of the electric field results in field emission of electrons that dominates the breakdown mechanism in gas sensor with gap spacing below 14 μm. More than 90% reduction in breakdown voltage is observed for sensors with MWCNT and 7 μm gap spacing. Transition of breakdown mechanism, dominated by avalanche electrons to field emission electrons, as decreasing gap spacing is also observed and discussed.

IONIZATION IN ATMOSPHERES OF BROWN DWARFS AND EXTRASOLAR PLANETS. V. ALFVÉN IONIZATION

International Nuclear Information System (INIS)

Stark, C. R.; Helling, Ch.; Rimmer, P. B.; Diver, D. A.

2013-01-01

Observations of continuous radio and sporadic X-ray emission from low-mass objects suggest they harbor localized plasmas in their atmospheric environments. For low-mass objects, the degree of thermal ionization is insufficient to qualify the ionized component as a plasma, posing the question: what ionization processes can efficiently produce the required plasma that is the source of the radiation? We propose Alfvén ionization as a mechanism for producing localized pockets of ionized gas in the atmosphere, having sufficient degrees of ionization (≥10 –7 ) that they constitute plasmas. We outline the criteria required for Alfvén ionization and demonstrate its applicability in the atmospheres of low-mass objects such as giant gas planets, brown dwarfs, and M dwarfs with both solar and sub-solar metallicities. We find that Alfvén ionization is most efficient at mid to low atmospheric pressures where a seed plasma is easier to magnetize and the pressure gradients needed to drive the required neutral flows are the smallest. For the model atmospheres considered, our results show that degrees of ionization of 10 –6 -1 can be obtained as a result of Alfvén ionization. Observable consequences include continuum bremsstrahlung emission, superimposed with spectral lines from the plasma ion species (e.g., He, Mg, H 2 , or CO lines). Forbidden lines are also expected from the metastable population. The presence of an atmospheric plasma opens the door to a multitude of plasma and chemical processes not yet considered in current atmospheric models. The occurrence of Alfvén ionization may also be applicable to other astrophysical environments such as protoplanetary disks

Extremely-high vacuum pressure measurement by laser ionization

International Nuclear Information System (INIS)

Kokubun, Kiyohide

1991-01-01

Laser ionization method has the very high sensitivity for detecting atoms and molecules. Hurst et al. successfully detected a single Cs atom by means of resonance ionization spectroscopy developed by them. Noting this high sensitivity, the authors have attempted to apply the laser ionization method to measure gas pressure, particularly in the range down to extremely high vacuum. At present, hot cathode ionization gauges are used for measuring gas pressure down to ultrahigh vacuum, however, those have a number of disadvantages. The pressure measurement using lasers does not have such disadvantages. The pressure measurement utilizing the laser ionization method is based on the principle that when laser beam is focused through a lens, the amount of atom or molecule ions generated in the focused space region is proportional to gas pressure. In this paper, the experimental results are presented on the nonresonant multiphoton ionization characteristics of various kinds of gases, the ion detection system with high sensitivity and an extremely high vacuum system prepared for the laser ionization experiment. (K.I.)

Carbon-14 labelling of biomolecules induced by 14CO ionized gas

International Nuclear Information System (INIS)

Lier, J.E. van; Sanche, L.

1979-01-01

Ionized 14 CO gas provides a rapid method for producing 14 C-labelled biomolecules. The apparatus consists of a high vacuum system in which a small amount of 14 CO is ionized by electron impact. The resulting species drift towards a target where they interact with the molecule of interest to produce 14 C-labelled compounds. Since the reaction time is only 2 minutes, the method is particularly promising for producing tracer biomolecules with short-lived 11 C at high specific activities. The applicability of the method to various classes of compounds of biological importance, including steroids, alkaloids, prostaglandins, nucleosides, amino acids and proteins has been studied. All compounds treated gave rise to 14 C addition and degradation products. Furthermore, for some compounds, chromatographic analysis in multiple systems followed by derivatization and crystallization to constant specific activity, indicated that carbon exchange may occur to produce the labelled, but otherwise unaltered substrate in yields of the order of 10-100 mCi/mol. More conclusive proof of radiochemical identity must await production of larger quantities of material and rigorous purification including at least two different chromatographic techniques. (author)

Identification of Guest-Host Inclusion Complexes in the Gas Phase by Electrospray Ionization-Mass Spectrometry

Science.gov (United States)

Mendes, De´bora C.; Ramamurthy, Vaidhyanathan; Da Silva, Jose´ P.

2015-01-01

In this laboratory experiment, students follow a step-by-step procedure to prepare and study guest-host complexes in the gas phase using electrospray ionization-mass spectrometry (ESI-MS). Model systems are the complexes of hosts cucurbit[7]uril (CB7) and cucurbit[8]uril (CB8) with the guest 4-styrylpyridine (SP). Aqueous solutions of CB7 or CB8…

Injector design for liner-on-target gas-puff experiments

Science.gov (United States)

Valenzuela, J. C.; Krasheninnikov, I.; Conti, F.; Wessel, F.; Fadeev, V.; Narkis, J.; Ross, M. P.; Rahman, H. U.; Ruskov, E.; Beg, F. N.

2017-11-01

We present the design of a gas-puff injector for liner-on-target experiments. The injector is composed of an annular high atomic number (e.g., Ar and Kr) gas and an on-axis plasma gun that delivers an ionized deuterium target. The annular supersonic nozzle injector has been studied using Computational Fluid Dynamics (CFD) simulations to produce a highly collimated (M > 5), ˜1 cm radius gas profile that satisfies the theoretical requirement for best performance on ˜1-MA current generators. The CFD simulations allowed us to study output density profiles as a function of the nozzle shape, gas pressure, and gas composition. We have performed line-integrated density measurements using a continuous wave (CW) He-Ne laser to characterize the liner gas density. The measurements agree well with the CFD values. We have used a simple snowplow model to study the plasma sheath acceleration in a coaxial plasma gun to help us properly design the target injector.

Comparison of Gas Chromatography-Mass Spectrometry and Gas Chromatography-Tandem Mass Spectrometry with Electron Ionization and Negative-Ion Chemical Ionization for Analyses of Pesticides at Trace Levels in Atmospheric Samples

Directory of Open Access Journals (Sweden)

Renata Raina

2008-01-01

Full Text Available A comparison of detection limits of gas chromatography-mass spectrometry (GC-MS in selected ion monitoring (SIM with gas chromatography-tandem mass spectrometry (GC-MS/MS in selected reaction monitoring (SRM mode with both electron ionization (EI and negative-ion chemical ionization (NCI are presented for over 50 pesticides ranging from organochlorines (OCs, organophosphorus pesticides (OPs and pre-emergent herbicides used in the Canadian prairies (triallate, trifluralin, ethalfluralin. The developed GC-EI/SIM, GC-NCI/SIM, and GC-NCI/SRM are suitable for the determination of pesticides in air sample extracts at concentrations <100 pg µL -1 (< 100 pg m -3 in air. No one method could be used to analyze the range of pre-emergent herbicides, OPs, and OCs investigated. In general GC-NCI/SIM provided the lowest method detection limits (MDLs commonly 2.5-10 pg µL -1 along with best confirmation (<25% RSD of ion ratio, while GC-NCI/SRM is recommended for use where added selectivity or confirmation is required (such as parathion-ethyl, tokuthion, carbofenothion. GC-EI/SRM at concentration < 100 pg µL -1 was not suitable for most pesticides. GC-EI/SIM was more prone to interference issues than NCI methods, but gave good sensitivity (MDLs 1-10 pg µL -1 for pesticides with poor NCI response (OPs: sulfotep, phorate, aspon, ethion, and OCs: alachlor, aldrin, perthane, and DDE, DDD, DDT.

Fabrication of gas sensor based on field ionization from SWCNTs with tripolar microelectrode

Science.gov (United States)

Cai, Shengbing; Zhang, Yong; Duan, Zhemin

2012-12-01

We report the nanofabrication of a sulfur dioxide (SO2) sensor with a tripolar on-chip microelectrode utilizing a film of single-walled carbon nanotubes (SWCNTs) as the field ionization cathode, where the ion flow current and the partial discharge current generated by the field ionization process of gaseous molecules can be gauged to gas species and concentration. The variation of the sensitivity is less than 4% for all of the tested devices, and the sensor has selectivity against gases such as He, NO2, CO, H2, SO2 and O2. Further, the sensor response presents well-defined and reproducible linear behavior with regard to concentration in the range investigated and a detection limitation of tripolar on-chip microelectrode with SWCNTs as a cathode exhibits an impressive performance with respect to stability and anti-oxidation behavior, which are significantly better than had been possible before in the traditional bipolar sensor under explicit circumstances at room temperature.

H ii REGION G46.5-0.2: THE INTERPLAY BETWEEN IONIZING RADIATION, MOLECULAR GAS, AND STAR FORMATION

International Nuclear Information System (INIS)

Paron, S.; Ortega, M. E.; Dubner, G.; Petriella, A.; Giacani, E.; Yuan, Jing-Hua; Li, Jin Zeng; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju; Wu, Yuefang

2015-01-01

H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey ( 13 CO J = 1–0) and from the James Clerk Maxwell Telescope data archive ( 12 CO, 13 CO, C 18 O J = 3–2, HCO + , and HCN J = 4–3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10′ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution

H II Region G46.5-0.2: The Interplay between Ionizing Radiation, Molecular Gas, and Star Formation

Science.gov (United States)

Paron, S.; Ortega, M. E.; Dubner, G.; Yuan, Jing-Hua; Petriella, A.; Giacani, E.; Zeng Li, Jin; Wu, Yuefang; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju

2015-06-01

H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey (13CO J = 1-0) and from the James Clerk Maxwell Telescope data archive (12CO, 13CO, C18O J = 3-2, HCO+, and HCN J = 4-3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10‧ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution.

Preliminary study of silica aerogel as a gas-equivalent material in ionization chambers

Science.gov (United States)

Caresana, M.; Zorloni, G.

2017-12-01

Since about two decades, a renewed interest on aerogels has risen. These peculiar materials show fairly unique properties. Thus, they are under investigation for both scientific and commercial purposes and new optimized production processes are studied. In this work, the possibility of using aerogel in the field of radiation detection is explored. The idea is to substitute the gas filling in a ionization chamber with the aerogel. The material possesses a density about 100 times greater than ambient pressure air. Where as the open-pore structure should allow the charge carriers to move freely. Small hydrophobic silica aerogel samples were studied. A custom ionization chamber, capable of working both with aerogel or in the classic gas set up, was built. The response of the chamber in current mode was investigated using an X-ray tube. The results obtained showed, under proper conditions, an enhancement of about 60 times of the current signal in the aerogel configuration with respect to the classic gas one. Moreover, some unusual behaviours were observed, i.e. time inertia of the signal and super-/sub-linear current response with respect to the dose rate. While testing high electric fields, aerogel configuration seemed to enhance the Townsend's effects. In order to represent the observed trends, a trapping-detrapping model is proposed, which is capable to predict semi-empirically the steady state currents measured. The time evolution of the signal is semi-quantitatively represented by the same model. The coefficients estimated by the fits are in agreement with similar trapping problems in the literature. In particular, a direct comparison between the benchmark of the FET silica gates and aerogel case endorses the idea that the same type of phenomenon occurs in the studied case.

Advantages of Atmospheric Pressure Chemical Ionization in Gas Chromatography Tandem Mass Spectrometry: Pyrethroid Insecticides as a Case Study

NARCIS (Netherlands)

Portolés, T.; Mol, J.G.J.; Sancho, J.V.; Hernández, F.

2012-01-01

Gas chromatography coupled to mass spectrometry (GC/MS) has been extensively applied for determination of volatile, nonpolar, compounds in many applied fields like food safety, environment, or toxicology. The wide majority of methods reported use electron ionization (EI), which may result in

'Saddle-point' ionization

International Nuclear Information System (INIS)

Gay, T.J.; Hale, E.B.; Irby, V.D.; Olson, R.E.; Missouri Univ., Rolla; Berry, H.G.

1988-01-01

We have studied the ionization of rare gases by protons at intermediate energies, i.e., energies at which the velocities of the proton and the target-gas valence electrons are comparable. A significant channel for electron production in the forward direction is shown to be 'saddle-point' ionization, in which electrons are stranded on or near the saddle-point of electric potential between the receding projectile and the ionized target. Such electrons yield characteristic energy spectra, and contribute significantly to forward-electron-production cross sections. Classical trajectory Monte Carlo calculations are found to provide qualitative agreement with our measurements and the earlier measurements of Rudd and coworkers, and reproduce, in detail, the features of the general ionization spectra. (orig.)

Theory for the asymmetry in the auroral ionization density profile for the generation of auroral infrasonic waves

International Nuclear Information System (INIS)

Goodwin, P.A.

1979-01-01

Traveling pressure waves with periods from 10 to 100 seconds are generated in the lower ionosphere by auroral electrojet current filaments as they move supersonically in an equatorward direction. The infrasonic waves produced by the auroral motions propagate to the ground as highly directional bow waves that can be detected by infrasonic microphones on the surface. There is an asymmetry in the reception of auroral infrasonic waves (AIW) with respect to whether the auroral arcs are moving equatorward to poleward. In the literature it is suggested that the asymmetry may be due to anisotropic propagation conditions along the acoustic ray path from the E-region, where AIW are produced, to the surface. Some intrinsic property of the AIW generation mechanism itself has also been suggested as a possible explanation. In this thesis anisotropic propagation is eliminated as the cause of the AIW reception asymmetry. Theoretical calculations, beginning with a model of an auroral precipitation region, are presented to show that there can be a significant difference in the transverse ionization density profiles between an auroral arc that is moving equatorward and an arc that is moving poleward, for a given equatorward-directed E-region ambient electric field. The calculation has been accomplished by solving the equations of motion and continuity for the cross-sectional ionization density profile associated with the transverse motion of a filamentary auroral electrojet. Thus, it is shown that there is an asymmetry in the ionization profiles associated with moving arcs, and in their coupling, that is related to the relative direction of motion of the arc with respect to the ambient electric field, and that it is this asymmetry that is probably the cause of the observed AIW reception asymmetry

Acceleration of Vaporization, Atomization, and Ionization Efficiencies in Inductively Coupled Plasma by Merging Laser-Ablated Particles with Hydrochloric Acid Gas.

Science.gov (United States)

Nakazawa, Takashi; Izumo, Saori; Furuta, Naoki

2016-01-01

To accelerate the vaporization, atomization, and ionization efficiencies in laser ablation inductively coupled plasma mass spectrometry, we merged HCl gas with laser-ablated particles before introduction into the plasma, to convert their surface constituents from oxides to lower-melting chlorides. When particles were merged with HCl gas generated from a HCl solution at 200°C, the measured concentrations of elements in the particles were 135% higher on average than the concentrations in particles merged with ultrapure water vapor. Particle corrosion and surface roughness were observed by scanning electron microscopy, and oxide conversion to chlorides was confirmed by X-ray photoelectron spectroscopy. Under the optimum conditions, the recoveries of measured elements improved by 23% on average, and the recoveries of elements with high-melting oxides (Sr, Zr, and Th) improved by as much as 36%. These results indicate that vaporization, atomization, and ionization in the ICP improved when HCl gas was merged with the ablated particles.

Physics of partially ionized plasmas

CERN Document Server

Krishan, Vinod

2016-01-01

Plasma is one of the four fundamental states of matter; the other three being solid, liquid and gas. Several components, such as molecular clouds, diffuse interstellar gas, the solar atmosphere, the Earth's ionosphere and laboratory plasmas, including fusion plasmas, constitute the partially ionized plasmas. This book discusses different aspects of partially ionized plasmas including multi-fluid description, equilibrium and types of waves. The discussion goes on to cover the reionization phase of the universe, along with a brief description of high discharge plasmas, tokomak plasmas and laser plasmas. Various elastic and inelastic collisions amongst the three particle species are also presented. In addition, the author demonstrates the novelty of partially ionized plasmas using many examples; for instance, in partially ionized plasma the magnetic induction is subjected to the ambipolar diffusion and the Hall effect, as well as the usual resistive dissipation. Also included is an observation of kinematic dynam...

Hyphenation of two simultaneously employed soft photo ionization mass spectrometers with thermal analysis of biomass and biochar

International Nuclear Information System (INIS)

Fendt, Alois; Geissler, Robert; Streibel, Thorsten

2013-01-01

Highlights: ► First simultaneous hyphenation of two time-of-flight mass spectrometers with different soft photo ionization techniques (SPI and REMPI) to Thermal Analysis using a newly developed prototype for EGA is presented. ► Resonance enhanced multi-photon ionization (REMPI) enables sensitive and selective analysis of aromatic species. ► Single photon ionization (SPI) using VUV light supplied by an innovative electron-beam pumped excimer light source (EBEL) comprehensively ionizes (nearly) all organic molecules. ► The resulting mass spectra show distinct patterns for the evolved gases of the miscellaneous biomasses and chars thereof. ► The potential for detailed kinetic studies is apparent on account of the complex pyrolysis gas compositions. - Abstract: Evolved gas analysis (EGA) is a powerful and complementary tool for Thermal Analysis. In this context, two time-of-flight mass spectrometers with different soft photo-ionization techniques are simultaneously hyphenated to a thermo balance and applied in form of a newly developed prototype for EGA of pyrolysis gases from biomass and biochar. Resonance enhanced multi-photon ionization (REMPI) is applied for selective analysis of aromatic species. Furthermore, single photon ionization (SPI) using VUV light supplied by an electron-beam pumped excimer light source (EBEL) was used to comprehensively ionize (nearly) all organic molecules. The soft ionization capability of photo-ionization techniques allows direct and on-line analysis of the evolved pyrolysis gases. Characteristic mass spectra with specific patterns could be obtained for the miscellaneous biomass feeds used. Temperature profiles of the biochars reveal a desorption step, followed by pyrolysis as observed for the biomasses. Furthermore, the potential for kinetic studies is apparent for this instrumental setup.

Depth profiling of inks in authentic and counterfeit banknotes by electrospray laser desorption ionization/mass spectrometry.

Science.gov (United States)

Kao, Yi-Ying; Cheng, Sy-Chyi; Cheng, Chu-Nian; Shiea, Jentaie

2016-01-01

Electrospray laser desorption ionization is an ambient ionization technique that generates neutrals via laser desorption and ionizes those neutrals in an electrospray plume and was utilized to characterize inks in different layers of copy paper and banknotes of various currencies. Depth profiling of inks was performed on overlapping color bands on copy paper by repeatedly scanning the line with a pulsed laser beam operated at a fixed energy. The molecules in the ink on a banknote were desorbed by irradiating the banknote surface with a laser beam operated at different energies, with results indicating that different ions were detected at different depths. The analysis of authentic $US100, $100 RMB and $1000 NTD banknotes indicated that ions detected in 'color-shifting' and 'typography' regions were significantly different. Additionally, the abundances of some ions dramatically changed with the depth of the aforementioned regions. This approach was used to distinguish authentic $1000 NTD banknotes from counterfeits. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

Employing Beam-Gas Interaction Vertices for Transverse Profile Measurements

CERN Document Server

Rihl, Mariana; Baglin, Vincent; Barschel, Colin; Bay, Aurelio; Blanc, Frederic; Bravin, Enrico; Bregliozzi, Giuseppe; Chritin, Nicolas; Dehning, Bernd; Ferro-Luzzi, Massimiliano; Gaspar, Clara; Gianì, Sebastiana; Giovannozzi, Massimo; Greim, Roman; Haefeli, Guido; Hopchev, Plamen; Jacobsson, Richard; Jensen, Lars; Jones, Owain Rhodri; Jurado, Nicolas; Kain, Verena; Karpinski, Waclaw; Kirn, Thomas; Kuhn, Maria; Luthi, Berengere; Magagnin, Paolo; Matev, Rosen; Nakada, Tatsuya; Neufeld, Niko; Panman, Jaap; Rakotomiaramanana, Barinjaka; Salustino Guimaraes, Valdir; Salvant, Benoit; Schael, Stefan; Schneider, Olivier; Schwering, Georg; Tobin, Mark; Veness, Raymond; Veyrat, Quentin; Vlachos, Sotiris; Wlochal, Michael; Xu, Zhirui; von Dratzig, Arndt

2016-01-01

Interactions of high-energy beam particles with residual gas offer a unique opportunity to measure the beam profile in a non-intrusive fashion. Such a method was successfully pioneered* at the LHCb experiment using a silicon microstrip vertex detector. During the recent Large Hadron Collider shutdown at CERN, a demonstrator Beam-Gas Vertexing system based on eight scintillating-fibre modules was designed**, constructed and installed on Ring 2 to be operated as a pure beam diagnostics device. The detector signals are read out and collected with LHCb-type front-end electronics and a DAQ system consisting of a CPU farm. Tracks and vertices will be reconstructed to obtain a beam profile in real time. Here, first commissioning results are reported. The advantages and potential for future applications of this technique are discussed.

Profiles of Gene Expression Induced by Ionizing Radiation in Different Human Cell Types. Doctoral thesis prepared at SCK-CEN and defended in 2005

International Nuclear Information System (INIS)

Mori, M.

2006-01-01

Ionizing radiation disrupts chemical bonds in biomolecules, such as proteins and DNA, which result in important cellular damage. Exposure to relatively high doses of ionizing radiation such as those delivered to the tumor in a radiotherapy protocol is generally lethal for the cell. However, non-lethal dose of ionizing radiation can be delivered during radiotherapy to the healthy tissue surrounding the tumor. Although the effects of ionizing radiation at the cellular level are quite well established (cell cycle arrest, senescence, apoptosis, mitotic catastrophe), questions remain concerning the molecular pathways regulating these cellular responses, including those differentiating the responses between tumor and normal cells. In normal cells, the p53 protein plays a central role. However, the efficacy of radiation treatments on tumor cells is often reduced because of the frequent inactivation of the p53 protein in those cells. Our study used the microarray technology to investigate the molecular pathways induced by irradiation in transformed and nontransformed human cells. Profiles of gene expression obtained with cDNA microarrays were regarded as steps to characterize the general response to ionizing radiation and, possibly also, differentiating the response between transformed and nontransformed cells. Possible implications of such research include the development of radiosensitizing (to maximize the effect of radiotherapeutic irradiation) and of radioprotecting strategies. Transcriptional profiles were investigated in transformed (Jurkat, HL60) and non-transformed (freshly isolated lymphocyte subpopulations) cells of hematopoietic origin. Also, because HeLa carcinoma-derived cells expressing human papilloma virus (HPV) 18 derived E2 protein represent a reliable model to study the p53 pathway, which is normally activated in response to radiation, molecular profiles were obtained to characterize this pathway in these cells

Simulation of temperature-pressure profiles and wax deposition in gas-lift wells

Directory of Open Access Journals (Sweden)

Sevic Snezana

2017-01-01

Full Text Available Gas-lift is an artificial lift method in which gas is injected down the tubing- -casing annulus and enters the production tubing through the gas-lift valves to reduce the hydrostatic pressure of the formation fluid column. The gas changes pressure, temperature and fluid composition profiles throughout the production tubing string. Temperature and pressure drop along with the fluid composition changes throughout the tubing string can lead to wax, asphaltenes and inorganic salts deposition, increased emulsion stability and hydrate formation. This paper presents a new model that can sucesfully simulate temperature and pressure profiles and fluid composition changes in oil well that operates by means of gas-lift. This new model includes a pipe-in-pipe segment (production tubing inside production casing, countercurrent flow of gas-lift gas and producing fluid, heat exchange between gas-lift gas and the surrounding ambient – ground; and gas-lift gas with the fluid in the tubing. The model enables a better understanding of the multiphase fluid flow up the production tubing. Model was used to get insight into severity and locations of wax deposition. The obtained information on wax deposition can be used to plan the frequency and depth of wax removing operations. Model was developed using Aspen HYSYS software.

Ionization particle detector

International Nuclear Information System (INIS)

Ried, L.

1982-01-01

A new device is claimed for detecting particles in a gas. The invention comprises a low cost, easy to assemble, and highly accurate particle detector using a single ionization chamber to contain a reference region and a sensing region. The chamber is designed with the radioactive source near one electrode and the second electrode located at a distance less than the distance of maximum ionization from the radioactive source

The dependence of C IV broad absorption line properties on accompanying Si IV and Al III absorption: relating quasar-wind ionization levels, kinematics, and column densities

Energy Technology Data Exchange (ETDEWEB)

Filiz Ak, N.; Brandt, W. N.; Schneider, D. P.; Trump, J. R. [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Hall, P. B. [Department of Physics and Astronomy, York University, 4700 Keele Street, Toronto, Ontario M3J 1P3 (Canada); Anderson, S. F. [Astronomy Department, University of Washington, Seattle, WA 98195 (United States); Hamann, F. [Department of Astronomy, University of Florida, Gainesville, FL 32611-2055 (United States); Myers, Adam D. [Department of Physics and Astronomy, University of Wyoming, Laramie, WY 82071 (United States); Pâris, I. [Departamento de Astronomía, Universidad de Chile, Casilla 36-D, Santiago (Chile); Petitjean, P. [Institut d' Astrophysique de Paris, Universite Paris 6, F-75014 Paris (France); Ross, Nicholas P. [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Shen, Yue [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); York, Don, E-mail: nfilizak@astro.psu.edu [Department of Astronomy and Astrophysics, The University of Chicago, Chicago, IL 60637 (United States)

2014-08-20

We consider how the profile and multi-year variability properties of a large sample of C IV Broad Absorption Line (BAL) troughs change when BALs from Si IV and/or Al III are present at corresponding velocities, indicating that the line of sight intercepts at least some lower ionization gas. We derive a number of observational results for C IV BALs separated according to the presence or absence of accompanying lower ionization transitions, including measurements of composite profile shapes, equivalent width (EW), characteristic velocities, composite variation profiles, and EW variability. We also measure the correlations between EW and fractional-EW variability for C IV, Si IV, and Al III. Our measurements reveal the basic correlated changes between ionization level, kinematics, and column density expected in accretion-disk wind models; e.g., lines of sight including lower ionization material generally show deeper and broader C IV troughs that have smaller minimum velocities and that are less variable. Many C IV BALs with no accompanying Si IV or Al III BALs may have only mild or no saturation.

Ionized Gas Kinematics around an Ultra-luminous X-Ray Source in NGC 5252: Additional Evidence for an Off-nuclear AGN

Energy Technology Data Exchange (ETDEWEB)

Kim, Minjin [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of); Ho, Luis C. [Kavli Institute for Astronomy and Astrophysics, Peking University, Beijing 100871 (China); Im, Myungshin [Center for the Exploration of the Origin of the Universe (CEOU), Astronomy Program, Department of Physics and Astronomy, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul, 151-742 (Korea, Republic of)

2017-08-01

The Seyfert 2 galaxy NGC 5252 contains a recently identified ultra-luminous X-ray (ULX) source that has been suggested to be a possible candidate off-nuclear low-mass active galactic nucleus. We present follow-up optical integral-field unit observations obtained using Gemini Multi-Object Spectrographs on the Gemini-North telescope. In addition to confirming that the ionized gas in the vicinity of the ULX is kinematically associated with NGC 5252, the new observations reveal ordered motions consistent with rotation around the ULX. The close coincidence of the excitation source of the line-emitting gas with the position of the ULX further suggests that ULX itself is directly responsible for the ionization of the gas. The spatially resolved measurements of [N ii] λ 6584/H α surrounding the ULX indicate a low gas-phase metallicity, consistent with those of other known low-mass active galaxies but not that of its more massive host galaxy. These findings strengthen the proposition that the ULX is not a background source but rather that it is the nucleus of a small, low-mass galaxy accreted by NGC 5252.

Improvements in ionization chambers

International Nuclear Information System (INIS)

Whetten, N.R.; Zubal, C.

1980-01-01

A method of reducing mechanical vibrations transmitted to the parallel plate electrodes of ionization chamber x-ray detectors, commonly used in computerized x-ray axial tomography systems, is described. The metal plate cathodes and anodes are mounted in the ionizable gas on dielectric sheet insulators consisting of a composite of silicone resin and glass fibres. (UK)

Investigation of mechanisms for He-I emission radial profile broadening in a weakly ionized cylindrical helium plasma with recombining edge

Energy Technology Data Exchange (ETDEWEB)

Hollmann, E. M.; Brandt, C.; Hudson, B.; Nishijima, D.; Pigarov, A. Yu. [University of California–San Diego, 9500 Gilman Dr., La Jolla, California 92093-0417 (United States); Kumar, D. [Johns Hopkins University, 3400 N Charles St., Baltimore, Maryland 21218 (United States)

2013-09-15

Spatially resolved spectroscopic measurements of He-I line emission are used to study the causes of emission profile broadening radially across the cylinder of a weakly ionized helium plasma. The plasma consists of an ionizing core (r < 2 cm) surrounded by a recombining edge (r > 2 cm) plasma. The brightness profiles of low-n EUV He-I resonance lines are shown to be strongly radially broadened due to opacity. The brightness profiles of high-n visible lines are also found to be strongly radially broadened, but dominantly due to edge recombination. Visible low-n lines are less strongly radially broadened, apparently by a combination of both recombination and EUV opacity. The low-n visible He-I line ratio method with central opacity correction is found to calculate central electron density and temperature well, with poor agreement at the edge, as expected for recombining plasma. In the recombining edge, high-n Boltzmann analysis is found to accurately measure the cold (T{sub e} < 0.2 eV) edge temperature. Near the core, however, high-n Boltzmann analysis can be complicated by electron-impact excitation, giving incorrect (T{sub e}≈ 0.1 eV) apparent temperatures. Probe measurements were not able to capture the cold edge temperature accurately, probably due to large potential fluctuations, even when using fast triple probe measurements. Fast spectroscopic measurements show that this discrepancy is not explained by recombining plasma alternating with ionizing plasma in the edge region.

The theory of ionizing shock waves in a magnetic field

International Nuclear Information System (INIS)

Liberman, M.A.; Velikovich, A.L.

1981-01-01

The general theory of ionizing shock waves in a magnetic field is constructed. The theory takes into account precursor ionization of a neutral gas ahead of the shock wave front, caused by photo-ionization, as well as by the impact ionization with electrons accelerated by a transverse electric field induced by the shock front in the incident flow of a neutral gas. The concept of shock wave ionization stability, being basic in the theory of ionizing shock waves in a magnetic field, is introduced. The ionizing shock wave structures are shown to transform from the GD regime at a low shock velocity to the MHD regime at an enhanced intensity of the shock wave. The abruptness of such a transition is determined by precursor photo-ionization. (author)

Thermal boundary conditions for electrons in a weakly ionized gas near a catalytic wall

International Nuclear Information System (INIS)

Chekmarev, I.

1981-01-01

A technique of matched asymptotic expansions is used to examine the derivation of hydrodynamic transport equations for the external region of a weakly ionized multitemperature gas near an absorbing and conducting wall. An approximate moment solution is constructed for the Knudsen boundary layer. The conditions for the matching of the external and internal expansions lead to a new form of the hydrodynamic boundary conditions, from which the singular behavior of the energy equation for electrons near the wall has been eliminated

Ionized Outflows in 3-D Insights from Herbig-Haro Objects and Applications to Nearby AGN

Science.gov (United States)

Cecil, Gerald

1999-01-01

HST shows that the gas distributions of these objects are complex and clump at the limit of resolution. HST spectra have lumpy emission-line profiles, indicating unresolved sub-structure. The advantages of 3D over slits on gas so distributed are: robust flux estimates of various dynamical systems projected along lines of sight, sensitivity to fainter spectral lines that are physical diagnostics (reddening-gas density, T, excitation mechanisms, abundances), and improved prospects for recovery of unobserved dimensions of phase-space. These advantages al- low more confident modeling for more profound inquiry into underlying dynamics. The main complication is the effort required to link multi- frequency datasets that optimally track the energy flow through various phases of the ISM. This tedium has limited the number of objects that have been thoroughly analyzed to the a priori most spectacular systems. For HHO'S, proper-motions constrain the ambient B-field, shock velocity, gas abundances, mass-loss rates, source duty-cycle, and tie-ins with molecular flows. If the shock speed, hence ionization fraction, is indeed small then the ionized gas is a significant part of the flow energetics. For AGN'S, nuclear beaming is a source of ionization ambiguity. Establishing the energetics of the outflow is critical to determining how the accretion disk loses its energy. CXO will provide new constraints (especially spectral) on AGN outflows, and STIS UV-spectroscopy is also constraining cloud properties (although limited by extinction). HHO's show some of the things that we will find around AGN'S. I illustrate these points with results from ground-based and HST programs being pursued with collaborators.

Dwarf galaxy dark matter density profiles inferred from stellar and gas kinematics

International Nuclear Information System (INIS)

Adams, Joshua J.; Simon, Joshua D.; Fabricius, Maximilian H.; Bender, Ralf; Thomas, Jens; Van den Bosch, Remco C. E.; Van de Ven, Glenn; Barentine, John C.; Gebhardt, Karl; Hill, Gary J.; Murphy, Jeremy D.; Swaters, R. A.

2014-01-01

We present new constraints on the density profiles of dark matter (DM) halos in seven nearby dwarf galaxies from measurements of their integrated stellar light and gas kinematics. The gas kinematics of low-mass galaxies frequently suggest that they contain constant density DM cores, while N-body simulations instead predict a cuspy profile. We present a data set of high-resolution integral-field spectroscopy on seven galaxies and measure the stellar and gas kinematics simultaneously. Using Jeans modeling on our full sample, we examine whether gas kinematics in general produce shallower density profiles than are derived from the stars. Although two of the seven galaxies show some localized differences in their rotation curves between the two tracers, estimates of the central logarithmic slope of the DM density profile, γ, are generally robust. The mean and standard deviation of the logarithmic slope for the population are γ = 0.67 ± 0.10 when measured in the stars and γ = 0.58 ± 0.24 when measured in the gas. We also find that the halos are not under-concentrated at the radii of half their maximum velocities. Finally, we search for correlations of the DM density profile with stellar velocity anisotropy and other baryonic properties. Two popular mechanisms to explain cored DM halos are an exotic DM component or feedback models that strongly couple the energy of supernovae into repeatedly driving out gas and dynamically heating the DM halos. While such models do not yet have falsifiable predictions that we can measure, we investigate correlations that may eventually be used to test models. We do not find a secondary parameter that strongly correlates with the central DM density slope, but we do find some weak correlations. The central DM density slope weakly correlates with the abundance of α elements in the stellar population, anti-correlates with H I fraction, and anti-correlates with vertical orbital anisotropy. We expect, if anything, the opposite of these

Gas-filled capillaries for plasma-based accelerators

International Nuclear Information System (INIS)

Filippi, F; Anania, M P; Brentegani, E; Biagioni, A; Chiadroni, E; Ferrario, M; Pompili, R; Romeo, S; Cianchi, A; Zigler, A

2017-01-01

Plasma Wakefield Accelerators are based on the excitation of large amplitude plasma waves excited by either a laser or a particle driver beam. The amplitude of the waves, as well as their spatial dimensions and the consequent accelerating gradient depend strongly on the background electron density along the path of the accelerated particles. The process needs stable and reliable plasma sources, whose density profile must be controlled and properly engineered to ensure the appropriate accelerating mechanism. Plasma confinement inside gas filled capillaries have been studied in the past since this technique allows to control the evolution of the plasma, ensuring a stable and repeatable plasma density distribution during the interaction with the drivers. Moreover, in a gas filled capillary plasma can be pre-ionized by a current discharge to avoid ionization losses. Different capillary geometries have been studied to allow the proper temporal and spatial evolution of the plasma along the acceleration length. Results of this analysis obtained by varying the length and the number of gas inlets will be presented. (paper)

Gas-filled capillaries for plasma-based accelerators

Science.gov (United States)

Filippi, F.; Anania, M. P.; Brentegani, E.; Biagioni, A.; Cianchi, A.; Chiadroni, E.; Ferrario, M.; Pompili, R.; Romeo, S.; Zigler, A.

2017-07-01

Plasma Wakefield Accelerators are based on the excitation of large amplitude plasma waves excited by either a laser or a particle driver beam. The amplitude of the waves, as well as their spatial dimensions and the consequent accelerating gradient depend strongly on the background electron density along the path of the accelerated particles. The process needs stable and reliable plasma sources, whose density profile must be controlled and properly engineered to ensure the appropriate accelerating mechanism. Plasma confinement inside gas filled capillaries have been studied in the past since this technique allows to control the evolution of the plasma, ensuring a stable and repeatable plasma density distribution during the interaction with the drivers. Moreover, in a gas filled capillary plasma can be pre-ionized by a current discharge to avoid ionization losses. Different capillary geometries have been studied to allow the proper temporal and spatial evolution of the plasma along the acceleration length. Results of this analysis obtained by varying the length and the number of gas inlets will be presented.

Measurement of the density profile of pure and seeded molecular beams by femtosecond ion imaging

NARCIS (Netherlands)

Meng, C.; Janssen, M.H.M.

2015-01-01

Here, we report on femtosecond ion imaging experiments to measure the density profile of a pulsed supersonic molecular beam. Ion images are measured for both a molecular beam and bulk gas under identical experimental conditions via femtosecond multiphoton ionization of Xe atoms. We report the

PRESENT-DAY GALACTIC EVOLUTION: LOW-METALLICITY, WARM, IONIZED GAS INFLOW ASSOCIATED WITH HIGH-VELOCITY CLOUD COMPLEX A

Energy Technology Data Exchange (ETDEWEB)

Barger, K. A.; Haffner, L. M.; Wakker, B. P.; Hill, Alex S. [Department of Astronomy, University of Wisconsin-Madison, Madison, WI 53706 (United States); Madsen, G. J. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Duncan, A. K., E-mail: kbarger@astro.wisc.edu, E-mail: haffner@astro.wisc.edu, E-mail: Alex.Hill@csiro.au, E-mail: wakker@astro.wisc.edu, E-mail: greg.madsen@sydney.edu.au [Rose-Hulman Institute of Technology, Terre Haute, IN 47803 (United States)

2012-12-20

The high-velocity cloud Complex A is a probe of the physical conditions in the Galactic halo. The kinematics, morphology, distance, and metallicity of Complex A indicate that it represents new material that is accreting onto the Galaxy. We present Wisconsin H{alpha} Mapper kinematically resolved observations of Complex A over the velocity range of -250 to -50 km s{sup -1} in the local standard of rest reference frame. These observations include the first full H{alpha} intensity map of Complex A across (l, b) = (124 Degree-Sign , 18 Degree-Sign ) to (171 Degree-Sign , 53 Degree-Sign ) and deep targeted observations in H{alpha}, [S II] {lambda}6716, [N II] {lambda}6584, and [O I] {lambda}6300 toward regions with high H I column densities, background quasars, and stars. The H{alpha} data imply that the masses of neutral and ionized material in the cloud are similar, both being greater than 10{sup 6} M{sub Sun }. We find that the Bland-Hawthorn and Maloney model for the intensity of the ionizing radiation near the Milky Way is consistent with the known distance of the high-latitude part of Complex A and an assumed cloud geometry that puts the lower-latitude parts of the cloud at a distance of 7-8 kpc. This compatibility implies a 5% ionizing photon escape fraction from the Galactic disk. We also provide the nitrogen and sulfur upper abundance solutions for a series of temperatures, metallicities, and cloud configurations for purely photoionized gas; these solutions are consistent with the sub-solar abundances found by previous studies, especially for temperatures above 10{sup 4} K or for gas with a high fraction of singly ionized nitrogen and sulfur.

Fabrication of gas sensor based on field ionization from SWCNTs with tripolar microelectrode

International Nuclear Information System (INIS)

Cai, Shengbing; Zhang, Yong; Duan, Zhemin

2012-01-01

We report the nanofabrication of a sulfur dioxide (SO 2 ) sensor with a tripolar on-chip microelectrode utilizing a film of single-walled carbon nanotubes (SWCNTs) as the field ionization cathode, where the ion flow current and the partial discharge current generated by the field ionization process of gaseous molecules can be gauged to gas species and concentration. The variation of the sensitivity is less than 4% for all of the tested devices, and the sensor has selectivity against gases such as He, NO 2 , CO, H 2 , SO 2 and O 2 . Further, the sensor response presents well-defined and reproducible linear behavior with regard to concentration in the range investigated and a detection limitation of <∼0.5 ppm for SO 2 . More importantly, a tripolar on-chip microelectrode with SWCNTs as a cathode exhibits an impressive performance with respect to stability and anti-oxidation behavior, which are significantly better than had been possible before in the traditional bipolar sensor under explicit circumstances at room temperature. (paper)

Simulation of the Interaction of X-rays with a Gas in an Ionization Chamber by the Monte Carlo Method; Simulacion Monte Carlo de la Interaccion de Rays X con el Gas de una Camara de Ionizacion

Energy Technology Data Exchange (ETDEWEB)

Grau Carles, A.; Garcia Gomez-Tejedor, G.

2001-07-01

The final objective of any ionization chamber is the measurement of the energy amount or radiation dose absorbed by the gas into the chamber. The final value depends on the composition of the gas, its density and temperature, the ionization chamber geometry, and type and intensity of the radiation. We describe a Monte Carlo simulation method, which allows one to compute the dose absorbed by the gas for a X-ray beam. Verification of model has been carried out by simulating the attenuation of standard X-ray radiation through the half value layers established in the ISO 4037 report, while assuming a Weibull type energy distribution for the incident photons. (Author) 6 refs.

Measurement of the first Townsend ionization coefficient in a methane-based tissue-equivalent gas

Energy Technology Data Exchange (ETDEWEB)

Petri, A.R. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Gonçalves, J.A.C. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Departamento de Física, Pontifícia Universidade Católica de São Paulo, 01303-050 São Paulo (Brazil); Mangiarotti, A. [Instituto de Física - Universidade de São Paulo, Cidade Universitária, 05508-080 São Paulo (Brazil); Botelho, S. [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil); Bueno, C.C., E-mail: ccbueno@ipen.br [Instituto de Pesquisas Energéticas e Nucleares, Cidade Universitária, 05508-000 São Paulo (Brazil)

2017-03-21

Tissue-equivalent gases (TEGs), often made of a hydrocarbon, nitrogen, and carbon dioxide, have been employed in microdosimetry for decades. However, data on the first Townsend ionization coefficient (α) in such mixtures are scarce, regardless of the chosen hydrocarbon. In this context, measurements of α in a methane-based tissue-equivalent gas (CH{sub 4} – 64.4%, CO{sub 2} – 32.4%, and N{sub 2} – 3.2%) were performed in a uniform field configuration for density-normalized electric fields (E/N) up to 290 Td. The setup adopted in our previous works was improved for operating at low pressures. The modifications introduced in the apparatus and the experimental technique were validated by comparing our results of the first Townsend ionization coefficient in nitrogen, carbon dioxide, and methane with those from the literature and Magboltz simulations. The behavior of α in the methane-based TEG was consistent with that observed for pure methane. All the experimental results are included in tabular form in the .

Development Of A Permanent Magnet Residual Gas Profile Monitor With Fast Readout

CERN Document Server

Barabin, S; Giacomini, T; Liakin, D; Orlov, A; Skachkov, V S

2004-01-01

The beam profile measurements at modern ion synchrotrons and storage rings require high timing performances on a turn-by-turn basis. On the other hand, high spatial resolutions are very desirable for cooled beams. We are developing a residual gas monitor to cover the wide range of beam intensities and dimensions. It supplies the needed high-resolution and high-speed tools for beam profiling. The new residual gas monitor will operate on scattered residual gas electrons whose trajectories are localized within 0.1 mm filaments by using appropriate magnetic field. The required magnetic field of 100 mT will be excited by either a permanent or an electromagnet. The high resolution mode of 0.1 mm is provided by a CCD camera with upstream MCP-phosphor screen assembly. In the fast turn-by-turn mode the beam profile will be read out with a resolution of 1 mm by a 100-channel photodiode-amplifier-digitizer, which will be explained in detail.

Effective ionization coefficients, electron drift velocities, and limiting breakdown fields for gas mixtures of possible interest to particle detectors

International Nuclear Information System (INIS)

Datskos, P.G.

1991-01-01

We have measured the gas-density, N, normalized effective ionization coefficient, bar a/N, and the electron drift velocity, w, as a function of the density-reduced electric field, E/N, and obtained the limiting, (E/N) lim , value of E/N for the unitary gases Ar, CO 2 , and CF 4 , the binary gas mixtures CO 2 :Ar (20: 80), CO 2 :CH 4 (20:80), and CF 4 :Ar (20:80), and the ternary gas mixtures CO 2 :CF 4 :Ar (10:10:80) and H 2 O: CF 4 :Ar (2:18:80). Addition of the strongly electron thermalizing gas CO 2 or H 2 O to the binary mixture CF 4 :Ar (1)''cools'' the mixture (i.e., lowers the electron energies), (2) has only a small effect on the magnitude of w(E/N) in the E/N range employed in the particle detectors, and (3) increases bar a/N for E/N ≥ 50 x 10 -17 V cm 2 . The increase in bar a/N, even though the electron energies are lower in the ternary mixture, is due to the Penning ionization of CO 2 (or H 2 O) in collisions with excited Ar* atoms. The ternary mixtures -- being fast, cool, and efficient -- have potential for advanced gas-filled particle detectors such as those for the SCC muon chambers. 17 refs., 8 figs., 1 tab

H ii REGION G46.5-0.2: THE INTERPLAY BETWEEN IONIZING RADIATION, MOLECULAR GAS, AND STAR FORMATION

Energy Technology Data Exchange (ETDEWEB)

Paron, S.; Ortega, M. E.; Dubner, G.; Petriella, A.; Giacani, E. [Instituto de Astronomía y Física del Espacio (IAFE, CONICET-UBA), CC 67, Suc. 28, 1428 Buenos Aires (Argentina); Yuan, Jing-Hua; Li, Jin Zeng; Liu, Hongli; Huang, Ya Fang; Zhang, Si-Ju [National Astronomical Observatories, Chinese Academy of Sciences, 20 A Datun Road, Chaoyang District, Beijing 100012 (China); Wu, Yuefang, E-mail: sparon@iafe.uba.ar [Department of Astronomy, Peking University, 100871 Beijing (China)

2015-06-15

H ii regions are particularly interesting because they can generate dense layers of gas and dust, elongated columns or pillars of gas pointing toward the ionizing sources, and cometary globules of dense gas where triggered star formation can occur. Understanding the interplay between the ionizing radiation and the dense surrounding gas is very important to explain the origin of these peculiar structures, and hence to characterize triggered star formation. G46.5-0.2 (G46), a poorly studied galactic H ii region located at about 4 kpc, is an excellent target for performing this kind of study. Using public molecular data extracted from the Galactic Ring Survey ({sup 13}CO J = 1–0) and from the James Clerk Maxwell Telescope data archive ({sup 12}CO, {sup 13}CO, C{sup 18}O J = 3–2, HCO{sup +}, and HCN J = 4–3), and infrared data from the GLIMPSE and MIPSGAL surveys, we perform a complete study of G46, its molecular environment, and the young stellar objects (YSOs) placed around it. We found that G46, probably excited by an O7V star, is located close to the edge of the GRSMC G046.34-00.21 molecular cloud. It presents a horse-shoe morphology opening in the direction of the cloud. We observed a filamentary structure in the molecular gas likely related to G46 and not considerable molecular emission toward its open border. We found that about 10′ to the southwest of G46 there are some pillar-like features, shining at 8 μm and pointing toward the H ii region open border. We propose that the pillar-like features were carved and sculpted by the ionizing flux from G46. We found several YSOs likely embedded in the molecular cloud grouped in two main concentrations: one, closer to the G46 open border consisting of Class II type sources, and another mostly composed of Class I type YSOs located just ahead of the pillar-like features, strongly suggesting an age gradient in the YSO distribution.

Spatial profiles of electron and metastable atom densities in positive polarity fast ionization waves sustained in helium

International Nuclear Information System (INIS)

Weatherford, Brandon R.; Barnat, E. V.; Xiong, Zhongmin; Kushner, Mark J.

2014-01-01

Fast ionization waves (FIWs), often generated with high voltage pulses over nanosecond timescales, are able to produce large volumes of ions and excited states at moderate pressures. The mechanisms of FIW propagation were experimentally and computationally investigated to provide insights into the manner in which these large volumes are excited. The two-dimensional structure of electron and metastable densities produced by short-pulse FIWs sustained in helium were measured using laser-induced fluorescence and laser collision-induced fluorescence diagnostics for times of 100–120 ns after the pulse, as the pressure was varied from 1 to 20 Torr. A trend of center-peaked to volume-filling to wall-peaked electron density profiles was observed as the pressure was increased. Instantaneous FIW velocities, obtained from plasma-induced emission, ranged from 0.1 to 3 × 10 9  cm s −1 , depending on distance from the high voltage electrode and pressure. Predictions from two-dimensional modeling of the propagation of a single FIW correlated well with the experimental trends in electron density profiles and wave velocity. Results from the model show that the maximum ionization rate occurs in the wavefront, and the discharge continues to propagate forward after the removal of high voltage from the powered electrode due to the potential energy stored in the space charge. As the pressure is varied, the radial distribution of the ionization rate is shaped by changes in the electron mean free path, and subsequent localized electric field enhancement at the walls or on the centerline of the discharge.

Hyphenation of two simultaneously employed soft photo ionization mass spectrometers with thermal analysis of biomass and biochar

Energy Technology Data Exchange (ETDEWEB)

Fendt, Alois [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group for Analysis of Complex Molecular Systems, Institute of Ecological Chemistry, Helmholtz Zentrum Muenchen - German Research Center for Environmental Health (GmbH), IngolstaedterLandstr. 1, 85764 Neuherberg (Germany); Analytical Chemistry, Institute of Physics, University of Augsburg, 86159 Augsburg (Germany); Geissler, Robert [Joint Mass Spectrometry Centre, Cooperation Group for Analysis of Complex Molecular Systems, Institute of Ecological Chemistry, Helmholtz Zentrum Muenchen - German Research Center for Environmental Health (GmbH), IngolstaedterLandstr. 1, 85764 Neuherberg (Germany); Analytical Chemistry, Institute of Physics, University of Augsburg, 86159 Augsburg (Germany); Streibel, Thorsten, E-mail: thorsten.streibel@uni-rostock.de [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group for Analysis of Complex Molecular Systems, Institute of Ecological Chemistry, Helmholtz Zentrum Muenchen - German Research Center for Environmental Health (GmbH), IngolstaedterLandstr. 1, 85764 Neuherberg (Germany); and others

2013-01-10

Highlights: Black-Right-Pointing-Pointer First simultaneous hyphenation of two time-of-flight mass spectrometers with different soft photo ionization techniques (SPI and REMPI) to Thermal Analysis using a newly developed prototype for EGA is presented. Black-Right-Pointing-Pointer Resonance enhanced multi-photon ionization (REMPI) enables sensitive and selective analysis of aromatic species. Black-Right-Pointing-Pointer Single photon ionization (SPI) using VUV light supplied by an innovative electron-beam pumped excimer light source (EBEL) comprehensively ionizes (nearly) all organic molecules. Black-Right-Pointing-Pointer The resulting mass spectra show distinct patterns for the evolved gases of the miscellaneous biomasses and chars thereof. Black-Right-Pointing-Pointer The potential for detailed kinetic studies is apparent on account of the complex pyrolysis gas compositions. - Abstract: Evolved gas analysis (EGA) is a powerful and complementary tool for Thermal Analysis. In this context, two time-of-flight mass spectrometers with different soft photo-ionization techniques are simultaneously hyphenated to a thermo balance and applied in form of a newly developed prototype for EGA of pyrolysis gases from biomass and biochar. Resonance enhanced multi-photon ionization (REMPI) is applied for selective analysis of aromatic species. Furthermore, single photon ionization (SPI) using VUV light supplied by an electron-beam pumped excimer light source (EBEL) was used to comprehensively ionize (nearly) all organic molecules. The soft ionization capability of photo-ionization techniques allows direct and on-line analysis of the evolved pyrolysis gases. Characteristic mass spectra with specific patterns could be obtained for the miscellaneous biomass feeds used. Temperature profiles of the biochars reveal a desorption step, followed by pyrolysis as observed for the biomasses. Furthermore, the potential for kinetic studies is apparent for this instrumental setup.

COMPLETE IONIZATION OF THE NEUTRAL GAS: WHY THERE ARE SO FEW DETECTIONS OF 21 cm HYDROGEN IN HIGH-REDSHIFT RADIO GALAXIES AND QUASARS

Energy Technology Data Exchange (ETDEWEB)

Curran, S. J. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Whiting, M. T., E-mail: sjc@physics.usyd.edu.au [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia)

2012-11-10

From the first published z {approx}> 3 survey of 21 cm absorption within the hosts of radio galaxies and quasars, Curran et al. found an apparent dearth of cool neutral gas at high redshift. From a detailed analysis of the photometry, each object is found to have a {lambda} = 1216 A continuum luminosity in excess of L {sub 1216} {approx} 10{sup 23} W Hz{sup -1}, a critical value above which 21 cm has never been detected at any redshift. At these wavelengths, and below, hydrogen is excited above the ground state so that it cannot absorb in 21 cm. In order to apply the equation of photoionization equilibrium, we demonstrate that this critical value also applies to the ionizing ({lambda} {<=} 912 A) radiation. We use this to show, for a variety of gas density distributions, that upon placing a quasar within a galaxy of gas, there is always an ultraviolet luminosity above which all of the large-scale atomic gas is ionized. While in this state, the hydrogen cannot be detected or engage in star formation. Applying the mean ionizing photon rate of all of the sources searched, we find, using canonical values for the gas density and recombination rate coefficient, that the observed critical luminosity gives a scale length (3 kpc) similar that of the neutral hydrogen (H I) in the Milky Way, a large spiral galaxy. Thus, this simple yet physically motivated model can explain the critical luminosity (L {sub 912} {approx} L {sub 1216} {approx} 10{sup 23} W Hz{sup -1}), above which neutral gas is not detected. This indicates that the non-detection of 21 cm absorption is not due to the sensitivity limits of current radio telescopes, but rather that the lines of sight to the quasars, and probably the bulk of the host galaxies, are devoid of neutral gas.

Radiation effects on polymer materials. Ionizing radiation induces degradation or improvement? (2) Gas evolution by irradiation

International Nuclear Information System (INIS)

Sasuga, Tsuneo

2005-01-01

The present article reviews gas evolution from organic polymers induced by ionizing radiations, focusing on gamma-ray irradiation of PE (polyethylene) and PP (polypropylene)-model compounds at temperatures from -77 to 55degC. In the polyolefins, the main gas evolved by irradiation is hydrogen with G-value of 3-4 at room temperatures and G(H 2 ) is 1.8 at 77K. For PE, G(H 2 ) is higher for the low-density PE than for higher-density PE. For the halogenated polymers as PVC, etc., evolved gas is hydrogen halogenated: G(HCl)=6.8 for PVC. For the case where the irradiation is accompanied with the oxidation of polymers, the de-oxygenation and formation of carboxylic radicals are remarkably high and known to emit a bad smell which depends on the thickness of oxidized layers. In conclusion, the gas evolution can be estimated by considering the molecular structure of polymer materials. (S.Ohno)

Characteristics of A-150 plastic equivalent gas in A-150 plastic ionization chambers for p(66)Be(49) neutrons

International Nuclear Information System (INIS)

Awschalom, M.; Rosenberg, I.; Ten Haken, R.K.; Pearson, D.W.; DeLuca, P.M. Jr.; Attix, F.H.

1982-01-01

The average energy necessary to produce an electron-ion pair (anti W) of a gas mixture having an atomic composition very close to that of A-150 plastic has been studied through use in different size ionization chambers made of that plastic in a p(66)Be(49) neutron therapy beam. A tentative value for anti W(A-150-gas) of 27.3 +/ -0.5 J C -1 was derived. The anti W value of the A-150 equivalent gas mixture is compared to those of methane-based tissue-equivalent gas and of air for the p(66)Be(49) neutron beam as well as to corresponding values found in similar experiments using 14.8 MeV monoenergetic neutrons

The analog of Blanc's law for drift velocities of electrons in gas mixtures in weakly ionized plasma

International Nuclear Information System (INIS)

Chiflikian, R.V.

1995-01-01

The analog of Blanc's law for drift velocities of electrons in multicomponent gas mixtures in weakly ionized spatially homogeneous low-temperature plasma is derived. The obtained approximate-analytical expressions are valid for average electron energy in the 1--5 eV range typical for plasma conditions of low-pressure direct current (DC) discharges. The accuracy of these formulas is ±5%. The analytical criterion of the negative differential conductivity (NDC) of electrons in binary mixtures of gases is obtained. NDC of electrons is predicted in He:Kr and He:Xe rare gas mixtures. copyright 1995 American Institute of Physics

Displacement of an electric arc by a stationary transverse magnetic field to different pressures of the ionized gas

International Nuclear Information System (INIS)

Ramos, J.

1987-01-01

The displacement of a wall-stabilized electric arc by a stationary transverse magnetic field is measured to different pressures of the ionized gas. The increase of the pressure makes the heat transfer function and the mass flow velocity in the arc column to raise, and it makes the arc displacement to decrease. (author)

Non-polar lipids characterization of Quinoa (Chenopodium quinoa) seed by comprehensive two-dimensional gas chromatography with flame ionization/mass spectrometry detection and non-aqueous reversed-phase liquid chromatography with atmospheric pressure chemical ionization mass spectrometry detection.

Science.gov (United States)

Fanali, Chiara; Beccaria, Marco; Salivo, Simona; Tranchida, Peter; Tripodo, Giusy; Farnetti, Sara; Dugo, Laura; Dugo, Paola; Mondello, Luigi

2015-07-08

A chemical characterization of major lipid components, namely, triacylglycerols, fatty acids and the unsaponifiable fraction, in a Quinoa seed lipids sample is reported. To tackle such a task, non-aqueous reversed-phase high-performance liquid chromatography with mass spectrometry detection was employed. The latter was interfaced with atmospheric pressure chemical ionization for the analysis of triacylglycerols. The main triacylglycerols (>10%) were represented by OLP, OOL and OLL (P = palmitoyl, O = oleoyl, L = linoleoyl); the latter was present in the oil sample at the highest percentage (18.1%). Furthermore, fatty acid methyl esters were evaluated by gas chromatography with flame ionization detection. 89% of the total fatty acids was represented by unsaturated fatty acid methyl esters with the greatest percentage represented by linoleic and oleic acids accounting for approximately 48 and 28%, respectively. An extensive characterization of the unsaponifiable fraction of Quinoa seed lipids was performed for the first time, by using comprehensive two-dimensional gas chromatography with dual mass spectrometry/flame ionization detection. Overall, 66 compounds of the unsaponifiable fraction were tentatively identified, many constituents of which (particularly sterols) were confirmed by using gas chromatography with high-resolution time-of-flight mass spectrometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Does the schock wave in a highly ionized non-isothermal plasma really exist ?

OpenAIRE

Rukhadze, A. A.; Sadykova, S.; Samkharadze, T.

2015-01-01

Here, we study the structure of a highly ionizing shock wave in a gas of high atmospheric pressure. We take into account the gas ionization when the gas temperature reaches few orders above ionization potential. It is shown that after gasdynamic temperature-raising shock and formation of a highly-ionized nonisothermal collisionless plasma Te≫Ti , only the solitary ion-sound wave (soliton) can propagate in this plasma. In such a wave, the charge separation occurs: electrons and ions form the d...

Application of pyrolysis–mass spectrometry and pyrolysis–gas chromatography–mass spectrometry with electron-ionization or resonance-enhanced-multi-photon ionization for characterization of crude oils

Energy Technology Data Exchange (ETDEWEB)

Otto, Stefan [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Streibel, Thorsten, E-mail: thorsten.streibel@uni-rostock.de [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany); Erdmann, Sabrina [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Sklorz, Martin [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany); Schulz-Bull, Detlef [Marine Chemistry, Leibniz Institute for Baltic Sea Research, Warnemünde, Seestrasse 15, 18119 Rostock (Germany); Zimmermann, Ralf [Joint Mass Spectrometry Centre, Chair of Analytical Chemistry, Institute of Chemistry, University of Rostock, 18059 Rostock (Germany); Joint Mass Spectrometry Centre, Cooperation Group Comprehensive Molecular Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München-German Research Center of Environmental Health (GmbH), Ingolstädter Landstrasse 1, 85764 Neuherberg (Germany)

2015-01-15

Highlights: • Gas chromatography setup with two MS detectors applying different ionization methods. • In parallel structural information and sensitive detection of aromatic species. • Characterization of setup and application for crude oil samples. • Detection of polycyclic aromatic hydrocarbons next to sulfur containing aromatics. - Abstract: A novel analytical system for gas-chromatographic investigation of complex samples has been developed, that combines the advantages of several analytical principles to enhance the analytical information. Decomposition of high molecular weight structures is achieved by pyrolysis and a high separation capacity due to the chromatographic step provides both an universal as well as a selective and sensitive substance detection. The latter is achieved by simultaneously applying electron ionization quadrupole mass spectrometry (EI-QMS) for structural elucidation and [1 + 1]-resonance-enhanced-multi-photon ionization (REMPI) combined with time-of-flight mass spectrometry (ToFMS). The system has been evaluated and tested with polycyclic aromatic hydrocarbon (PAH) standards. It was applied to crude oil samples for the first time. In such highly complex samples several thousands of compounds are present and the identification especially of low concentrated chemical species such as PAH or their polycyclic aromatic sulfur containing heterocyclic (PASH) derivatives is often difficult. Detection of unalkylated and alkylated PAH together with PASH is considerably enhanced by REMPI–ToFMS, at times revealing aromatic structures which are not observable by EI-QMS due to their low abundance. On the other hand, the databased structure proposals of the EI-QMS analysis are needed to confirm structural information and isomers distinction. The technique allows a complex structure analysis as well as selective assessment of aromatic substances in one measurement. Information about the content of sulfur containing compounds plays a

Application of pyrolysis–mass spectrometry and pyrolysis–gas chromatography–mass spectrometry with electron-ionization or resonance-enhanced-multi-photon ionization for characterization of crude oils

International Nuclear Information System (INIS)

Otto, Stefan; Streibel, Thorsten; Erdmann, Sabrina; Sklorz, Martin; Schulz-Bull, Detlef; Zimmermann, Ralf

2015-01-01

Highlights: • Gas chromatography setup with two MS detectors applying different ionization methods. • In parallel structural information and sensitive detection of aromatic species. • Characterization of setup and application for crude oil samples. • Detection of polycyclic aromatic hydrocarbons next to sulfur containing aromatics. - Abstract: A novel analytical system for gas-chromatographic investigation of complex samples has been developed, that combines the advantages of several analytical principles to enhance the analytical information. Decomposition of high molecular weight structures is achieved by pyrolysis and a high separation capacity due to the chromatographic step provides both an universal as well as a selective and sensitive substance detection. The latter is achieved by simultaneously applying electron ionization quadrupole mass spectrometry (EI-QMS) for structural elucidation and [1 + 1]-resonance-enhanced-multi-photon ionization (REMPI) combined with time-of-flight mass spectrometry (ToFMS). The system has been evaluated and tested with polycyclic aromatic hydrocarbon (PAH) standards. It was applied to crude oil samples for the first time. In such highly complex samples several thousands of compounds are present and the identification especially of low concentrated chemical species such as PAH or their polycyclic aromatic sulfur containing heterocyclic (PASH) derivatives is often difficult. Detection of unalkylated and alkylated PAH together with PASH is considerably enhanced by REMPI–ToFMS, at times revealing aromatic structures which are not observable by EI-QMS due to their low abundance. On the other hand, the databased structure proposals of the EI-QMS analysis are needed to confirm structural information and isomers distinction. The technique allows a complex structure analysis as well as selective assessment of aromatic substances in one measurement. Information about the content of sulfur containing compounds plays a

Low-frequency observations of Galactic supernova remnants and the distribution of low-density ionized gas in the interstellar medium

International Nuclear Information System (INIS)

Kassim, N.E.

1989-01-01

New long-wavelength observations of Galactic SNRs at 30.9 and 57.5 MHz are used to derive detailed low-frequency radio spectra for 32 SNRs. Of these, about two-thirds show turnovers at low frequencies, implying the presence of a widespread, but inhomogeneous, ionized absorbing medium along the lines of sight. These observations are combined with other low-frequency data to derive free-free optical depths toward 457 SNRs and to constrain the physical properties of the ionized gas responsible for the absorption. These optical depths are consistent with the expected absorbing properties of extended H II region envelopes. 43 refs

Plasma production via field ionization

Directory of Open Access Journals (Sweden)

C. L. O’Connell

2006-10-01

Full Text Available Plasma production via field ionization occurs when an incoming particle beam is sufficiently dense that the electric field associated with the beam ionizes a neutral vapor or gas. Experiments conducted at the Stanford Linear Accelerator Center explore the threshold conditions necessary to induce field ionization by an electron beam in a neutral lithium vapor. By independently varying the transverse beam size, number of electrons per bunch, or bunch length, the radial component of the electric field is controlled to be above or below the threshold for field ionization. Additional experiments ionized neutral xenon and neutral nitric oxide by varying the incoming beam’s bunch length. A self-ionized plasma is an essential step for the viability of plasma-based accelerators for future high-energy experiments.

Effect of the systemic versus inhalatory administration of synthetic glucocorticoids on the urinary steroid profile as studied by gas chromatography-mass spectrometry

International Nuclear Information System (INIS)

Mazzarino, Monica; Rossi, Francesca; Giacomelli, Laura; Botre, Francesco

2006-01-01

This paper presents a gas chromatography-mass spectrometry (GC-MS) study carried out on human urine to verify whether the administration of glucocorticoids can affect the urinary steroid profile, and especially the levels of endogenous glucocorticoids, androgens and their main metabolites. Betamethasone and beclomethasone, administered either systemically (per os or i.m.) or locally (by inhalation) have been studied. The determination of the urinary levels of endogenous glucocorticoids and androgens was carried out by GC-MS in electron impact ionization mode. Data were evaluated taking into account the baseline individual variability, and compared with values obtained on a control group. Detectable differences were recorded in the steroids metabolites excretion profiles between men and women. The circadian variability of the steroid profile was the same for both sexes, showing a maximum during the morning hours. After systemic treatment with synthetic glucocorticoids, the relative urinary concentrations of corticosteroids, androgens and of their metabolites were significantly altered, recording a transient decrease of the concentration of cortisol and tetrahydrocortisol and a parallel, although less pronounced, increase of the concentration of testosterone, epitestosterone and related androgenic steroids; while no effects were recorded if the administration was by inhalation

Effect of the systemic versus inhalatory administration of synthetic glucocorticoids on the urinary steroid profile as studied by gas chromatography-mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

Mazzarino, Monica [Laboratorio Antidoping, Federazione Medico Sportiva Italiana, Largo Giulio Onesti 1, 00197 Rome (Italy); Rossi, Francesca [Laboratorio Antidoping, Federazione Medico Sportiva Italiana, Largo Giulio Onesti 1, 00197 Rome (Italy); Giacomelli, Laura [Dipartimento di Scienze Chirurgiche, Universita La Sapienza, Viale Regina Elena 324, 00161 Rome (Italy); Botre, Francesco [Laboratorio Antidoping, Federazione Medico Sportiva Italiana, Largo Giulio Onesti 1, 00197 Rome (Italy) and Dipartimento CGMIA, Universita La Sapienza, Via del Castro Laurenziano 9, 00161 Rome (Italy)]. E-mail: francesco.botre@uniroma1.it

2006-02-10

This paper presents a gas chromatography-mass spectrometry (GC-MS) study carried out on human urine to verify whether the administration of glucocorticoids can affect the urinary steroid profile, and especially the levels of endogenous glucocorticoids, androgens and their main metabolites. Betamethasone and beclomethasone, administered either systemically (per os or i.m.) or locally (by inhalation) have been studied. The determination of the urinary levels of endogenous glucocorticoids and androgens was carried out by GC-MS in electron impact ionization mode. Data were evaluated taking into account the baseline individual variability, and compared with values obtained on a control group. Detectable differences were recorded in the steroids metabolites excretion profiles between men and women. The circadian variability of the steroid profile was the same for both sexes, showing a maximum during the morning hours. After systemic treatment with synthetic glucocorticoids, the relative urinary concentrations of corticosteroids, androgens and of their metabolites were significantly altered, recording a transient decrease of the concentration of cortisol and tetrahydrocortisol and a parallel, although less pronounced, increase of the concentration of testosterone, epitestosterone and related androgenic steroids; while no effects were recorded if the administration was by inhalation.

GEMINI NEAR INFRARED FIELD SPECTROGRAPH OBSERVATIONS OF THE SEYFERT 2 GALAXY MRK 573: IN SITU ACCELERATION OF IONIZED AND MOLECULAR GAS OFF FUELING FLOWS

Energy Technology Data Exchange (ETDEWEB)

Fischer, Travis C.; Straughn, A. N. [Astrophysics Science Division, Goddard Space Flight Center, Code 665, Greenbelt, MD 20771 (United States); Machuca, C.; Crenshaw, D. M.; Baron, F.; Revalski, M.; Pope, C. L. [Department of Physics and Astronomy, Georgia State University, Astronomy Offices, 25 Park Place, Suite 605, Atlanta, GA 30303 (United States); Diniz, M. R.; Riffel, R. A. [Departamento de Física, Centro de Ciências Naturais e Exatas, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS (Brazil); Kraemer, S. B. [Institute for Astrophysics and Computational Sciences, Department of Physics, The Catholic University of America, Washington, DC 20064 (United States); Schmitt, H. R. [Naval Research Laboratory, Washington, DC 20375 (United States); Storchi-Bergmann, T., E-mail: travis.c.fischer@nasa.gov [Departamento de Astronomia, Universidade Federal do Rio Grande do Sul, IF, CP 15051, 91501-970 Porto Alegre, RS (Brazil)

2017-01-01

We present near-infrared and optical emission-line and stellar kinematics of the Seyfert 2 galaxy Mrk 573 using the Near-Infrared Field Spectrograph (NIFS) at Gemini North and Dual Imaging Spectrograph at Apache Point Observatory, respectively. By obtaining full kinematic maps of the infrared ionized and molecular gas and stellar kinematics in a ∼700 × 2100 pc{sup 2} circumnuclear region of Mrk 573, we find that kinematics within the Narrow-Line Region are largely due to a combination of both rotation and in situ acceleration of material originating in the host disk. Combining these observations with large-scale, optical long-slit spectroscopy that traces ionized gas emission out to several kpcs, we find that rotation kinematics dominate the majority of the gas. We find that outflowing gas extends to distances less than 1 kpc, suggesting that outflows in Seyfert galaxies may not be powerful enough to evacuate their entire bulges.

Gemini Near Infrared Field Spectrograph Observations of the Seyfert 2 Galaxy MRK 573: In Situ Acceleration of Ionized and Molecular Gas Off Fueling Flows

Science.gov (United States)

Fischer, Travis C.; Machuca, C.; Diniz, M. R.; Crenshaw, D. M.; Kraemer, S. B.; Riffel, R. A.; Schmitt, H. R.; Baron, F.; Storchi-Bergmann, T.; Straughn, A. N.;

Gas dynamics considerations in a non-invasive profile monitor for charged particle beams

CERN Document Server

Tzoganis, Vasilis; Welsch, Carsten P

2014-01-01

A non-invasive, gas jet-based, beam profile monitor has been developed in the QUASAR Group at the Cockcroft Institute, UK. This allows on-line measurement of the 2-dimensional transverse profile of particle beams with negligible disturbance to either primary beam or accelerator vacuum. The monitor is suitable for use with beams across a wide range of energies and intensities. In this setup a nozzle-skimmer system shapes a thin supersonic gas jet into a curtain. However, the small dimensions of the gas inlet nozzle and subsequent skimmers were shown to be the cause of many operational problems. In this paper, the dynamics of gas jet formation transport and shaping is discussed before an image-processing based alignment technique is introduced. Furthermore, experimental results obtained with a 5 keV electron beam are discussed and the effects of gas stagnation pressure on the acquired beam are presented.

SDSS IV MaNGA: Deep observations of extra-planar, diffuse ionized gas around late-type galaxies from stacked IFU spectra

Science.gov (United States)

Jones, A.; Kauffmann, G.; D'Souza, R.; Bizyaev, D.; Law, D.; Haffner, L.; Bahé, Y.; Andrews, B.; Bershady, M.; Brownstein, J.; Bundy, K.; Cherinka, B.; Diamond-Stanic, A.; Drory, N.; Riffel, R. A.; Sánchez, S. F.; Thomas, D.; Wake, D.; Yan, R.; Zhang, K.

2017-03-01

We have conducted a study of extra-planar diffuse ionized gas using the first year data from the MaNGA IFU survey. We have stacked spectra from 49 edge-on, late-type galaxies as a function of distance from the midplane of the galaxy. With this technique we can detect the bright emission lines Hα, Hβ, [O II]λλ3726, 3729, [O III]λ5007, [N II]λλ6549, 6584, and [S II]λλ6717, 6731 out to about 4 kpc above the midplane. With 16 galaxies we can extend this analysis out to about 9 kpc, I.e. a distance of 2Re, vertically from the midplane. In the halo, the surface brightnesses of the [O II] and Hα emission lines are comparable, unlike in the disk where Hα dominates. When we split the sample by specific star-formation rate, concentration index, and stellar mass, each subsample's emission line surface brightness profiles and ratios differ, indicating that extra-planar gas properties can vary. The emission line surface brightnesses of the gas around high specific star-formation rate galaxies are higher at all distances, and the line ratios are closer to ratios characteristic of H II regions compared with low specific star-formation rate galaxies. The less concentrated and lower stellar mass samples exhibit line ratios that are more like H II regions at larger distances than their more concentrated and higher stellar mass counterparts. The largest difference between different subsamples occurs when the galaxies are split by stellar mass. We additionally infer that gas far from the midplane in more massive galaxies has the highest temperatures and steepest radial temperature gradients based on their [N II]/Hα and [O II]/Hα ratios between the disk and the halo. SDSS IV.

Measurement of indoor background ionizing radiation in some ...

African Journals Online (AJOL)

Certain types of building materials are known to be radioactive. Exposure to indoor ionizing radiation like exposure to any other type of ionizing radiation results in critical health challenges. Measurement of the background ionizing radiation profile within the Chemistry Research Laboratory and Physics Laboratory III all of ...

The Students’ misconceptions profile on chapter gas kinetic theory

Science.gov (United States)

Jauhariyah, M. N. R.; Suprapto, N.; Suliyanah; Admoko, S.; Setyarsih, W.; Harizah, Z.; Zulfa, I.

2018-03-01

Students have conception and misconceptions in the learning process. Misconceptions are caused by the teacher, students, and learning source. In the previous study, the researcher developed a misconception diagnosis instrument using three-tier on chapter gas kinetic theory. There are 14 items including 5 sub-chapters on gas kinetic theory. The profile of students’ misconceptions shows that students have misconceptions in each sub-chapter. The cause of misconceptions came from preconceptions, associative thinking, reasoning, intuition, and false negative. The highest cause of misconception in this chapter is student’s humanistic thinking.

Reliability of semiconductor and gas-filled diodes for over-voltage protection exposed to ionizing radiation

Directory of Open Access Journals (Sweden)

Stanković Koviljka

2009-01-01

Full Text Available The wide-spread use of semiconductor and gas-filled diodes for non-linear over-voltage protection results in a variety of possible working conditions. It is therefore essential to have a thorough insight into their reliability in exploitation environments which imply exposure to ionizing radiation. The aim of this paper is to investigate the influence of irradiation on over-voltage diode characteristics by exposing the diodes to californium-252 combined neutron/gamma radiation field. The irradiation of semiconductor over-voltage diodes causes severe degradation of their protection characteristics. On the other hand, gas-filled over-voltage diodes exhibit a temporal improvement of performance. The results are presented with the accompanying theoretical interpretations of the observed changes in over-voltage diode behaviour, based on the interaction of radiation with materials constituting the diodes.

Neutron accelerator tube having improved ionization section

International Nuclear Information System (INIS)

Givens, W.W.

1982-01-01

A neutron accelerator tube is described having a target section, an ionization section, and a replenisher section for supplying accelerator gas to the ionization section. The ionization section is located between the target and the replenisher section and includes an ionization chamber adapted to receive accelerator gas from the replenisher section. The ionization section further includes spaced cathodes having opposed active surfaces exposed to the interior of the ionization chamber. An anode is located intermediate the cathodes whereby in response to an applied positive voltage, electrons created by field emission are transmitted between the opposed active surfaces of the cathodes and produce the emission of secondary electrons. The active surface of at least one of the cathodes is formulated of a material having a secondary electron emission factor of at least one cathode member located in the tube adjacent to th replenisher section may have a protuberant portion extending axially into the ionization chamber. The other cathode spaced from the first cathode member in the direction of the target has an aperture therein along the axis of the protuberant portion. An annular magnet extends around the exterior of the ionization chamber and envelops the anode member. Means are provided to establish a high permeability magnetic flux path extending outwardly from the opposed poles from the magnet to the active surfaces of the cathode members

Advances in marine ice profiling for oil and gas applications

International Nuclear Information System (INIS)

Fissel, D.; Marko, J.; Melling, H.

2008-01-01

Developments in acoustic profiling technologies have allowed ever more accurate and information-rich extraction of data on the draft, undersurface topography and immediately adjacent water column environment of polar and other marine and freshwater ice covers. The purpose of these advances was to replace and improve upon other, often inconvenient, costly and/or otherwise unsatisfactory methodologies such as the use of upward looking sonar (ULS) sounders on submarines as well as deployments of airborne- sensors such as laser profilometers and electromagnetic induction instrumentation. ULS is a primary source of data for measurements of ice thickness. Self-contained units now have the data capacity and accuracy/resolution sufficient for unattended operation. Recent technological advances have now led to the next generation of ice profiling sonar (IPS), incorporating much expanded on-board data storage capacity and powerful onboard real-time firmware. This paper outlined the nature of the issues addressed in past oil and gas related ice profiling studies. The paper focused on identifying the key items of interest and the remaining uncertainties in the derived products. All of the data gathered in this regard was obtained with first generation profiling instrumentation of the type initially introduced by Melling and coworkers in 1995. The additional features of a recently introduced next generation IPS instrument were briefly described. The observed and potential benefits offered in oil and gas related applications were also presented. It was concluded that the next generation ice profilers sets the stage for research and development into the measurement of new ice parameters, the combination of information from ice profilers and all-weather radar satellite systems, and the possibility of remote access to the ice profiler data from multi-year moorings located well within the main Arctic Ocean ice pack. 11 refs., 10 figs

Electronegative Plasma Equilibria with Spatially-Varying Ionization

Science.gov (United States)

Lieberman, M. A.; Kawamura, E.; Lichtenberg, A. J.

2012-10-01

Electronegative inductive discharges in higher pressure ranges typically exhibit localized ionization near the coil structure, with decay of the ionization into the central discharge. We use a two-dimensional fluid code [1] with chlorine feedstock to determine the spatial profiles of the plasma parameters in a cylindrical transformer-coupled plasma device excited by a planar coil. To compare with one-dimensional (1D) analytic modeling, the results are area-averaged. The ionization is found to decay roughly exponentially along the axial direction, allowing the ansatz of an exponentially decaying ionization to be used in a 1D computational model. The model captures the main features of the axial variations of the area-averaged fluid simulation, indicating that the main diffusion mechanisms act along the axial direction. A simple analytic global discharge model is developed, accounting for the asymmetric density and ionization profiles. The global model gives the scalings with power and pressure of volume-averaged densities, electron temperature, and ionization decay rate, also in reasonable agreement with the scalings obtained by averaging the simulation results. [4pt] [1] E. Kawamura, D.B. Graves, and M.A. Lieberman, Plasma Sources Sci. Technol. 20, 035009 (2012)

Determination of polycyclic aromatic hydrocarbons in palm oil mill effluent by soxhlet extraction and gas chromatography-flame ionization detector

International Nuclear Information System (INIS)

Nor Fairolzukry Ahmad Rasdy; Mohd Marsin Sanagi; Wan Aini Wan Ibrahim; Ahmedy Abu Naim

2008-01-01

A method has been developed for the determination of polycyclic aromatic hydrocarbons (PAHs) from palm oil mill effluent based on gas chromatography-flame ionization detection. Extraction of spiked PAHs (napthalene, fluorene phenanthrene, fluoranthene and pyrene) in palm oil waste was carried out by Soxhlet extraction using hexane-dichloromethane (60:40 v/v) as the solvent. Excellent separations were achieved using temperature programmed GC on Ultra-1 fused-silica capillary column (30 m x 250 μm ID), carrier gas helium at a flow rate of 1 mL/ min. (author)

Pressure of a partially ionized hydrogen gas: numerical results from exact low temperature expansions

Energy Technology Data Exchange (ETDEWEB)

Alastuey, A. [Laboratoire de Physique, ENS Lyon, CNRS, Lyon (France); Ballenegger, V. [Institut UTINAM, Universite de Franche-Comte, CNRS, Besancon (France)

2010-01-15

We consider a partially ionized hydrogen gas at low densities, where it reduces almost to an ideal mixture made with hydrogen atoms in their ground-state, ionized protons and ionized electrons. By performing systematic low-temperature expansions within the physical picture, in which the system is described as a quantum electron-proton plasma interacting via the Coulomb potential, exact formulae for the first.ve leading corrections to the ideal Saha equation of state have been derived[A. Alastuey, V. Ballenegger et al., J. Stat. Phys. 130, 1119 (2008)]. Those corrections account for all effects of interactions and thermal excitations up to order exp(E{sub H} /kT) included, where E{sub H} {approx_equal} -13.6 eV is the ground state energy of the hydrogen atom. Among the.ve leading corrections, three are easy to evaluate, while the remaining ones involve suitably truncated internal partition functions of H{sub 2} molecules and H{sup -} and H{sub 2}{sup +} ions, for which no analytical formulae are available in closed form. We estimate those partitions functions at.nite temperature via a simple phenomenology based on known values of rotational and vibrational energies. This allows us to compute numerically the leading deviations to the Saha pressure along several isotherms and isochores. Our values are compared with those of the OPAL tables (for pure hydrogen) calculated within the ACTEX method (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Approximate thermodynamic state relations in partially ionized gas mixtures

International Nuclear Information System (INIS)

Ramshaw, John D.

2004-01-01

Thermodynamic state relations for mixtures of partially ionized nonideal gases are often approximated by artificially partitioning the mixture into compartments or subvolumes occupied by the pure partially ionized constituent gases, and requiring these subvolumes to be in temperature and pressure equilibrium. This intuitively reasonable procedure is easily shown to reproduce the correct thermal and caloric state equations for a mixture of neutral (nonionized) ideal gases. The purpose of this paper is to point out that (a) this procedure leads to incorrect state equations for a mixture of partially ionized ideal gases, whereas (b) the alternative procedure of requiring that the subvolumes all have the same temperature and free electron density reproduces the correct thermal and caloric state equations for such a mixture. These results readily generalize to the case of partially degenerate and/or relativistic electrons, to a common approximation used to represent pressure ionization effects, and to two-temperature plasmas. This suggests that equating the subvolume electron number densities or chemical potentials instead of pressures is likely to provide a more accurate approximation in nonideal plasma mixtures

Turbulent Dynamics of Partially-Ionized Fluids in 2D

Science.gov (United States)

Benavides, S.; Flierl, G.

2017-12-01

Ionization occurs in the upper atmospheres of Hot Jupiters, as well asthe interiors of Gas Giants, leading to Magnetohydrodynamic (MHD) effectswhich can significantly alter the flow. The interactions of these MHDregions with the non-ionized atmosphere will occur in transitionregions where only a fraction of the fluid is ionized. We areexploring the dynamics of Partially-Ionized MHD (PIMHD) using a twofluid model - one neutral and one ionized and subject to MHD -coupled by a collision, or Joule heating, term proportional to thedifference in velocities. By varying both the ionization fraction aswell as the collision frequency (coupling), we examine the parameterspace of 2D PIMHD turbulence in hopes of better understanding itscharacteristics in certain, possibly realistic, regimes. We payparticular attention to the Joule heating term and its role indissipation and energy exchange between the two species. Thisknowledge will serve as the basis to further studies in which we lookat, in a more realistic setting, the PIMHD dynamics in Gas Giant orHot Jupiter atmospheres.

A Mathematical Model for the Exhaust Gas Temperature Profile of a Diesel Engine

Science.gov (United States)

Brito, C. H. G.; Maia, C. B.; Sodré, J. R.

2015-09-01

This work presents a heat transfer model for the exhaust gas of a diesel power generator to determine the gas temperature profile in the exhaust pipe. The numerical methodology to solve the mathematical model was developed using a finite difference method approach for energy equation resolution and determination of temperature profiles considering turbulent fluid flow and variable fluid properties. The simulation was carried out for engine operation under loads from 0 kW to 40 kW. The model was compared with results obtained using the multidimensional Ansys CFX software, which was applied to solve the governor equations of turbulent fluid flow. The results for the temperature profiles in the exhaust pipe show a good proximity between the mathematical model developed and the multidimensional software.

Reproducibility of serum protein profiling by systematic assessment using solid-phase extraction and matrix-assisted laser desorption/ionization mass spectrometry

DEFF Research Database (Denmark)

Callesen, Anne K; Christensen, René Depont; Madsen, Jonna S

2008-01-01

for serum protein profiling we investigated a range of sample preparation techniques and developed a statistical method based on repeated analyses for evaluation of protein-profiling performance of MALDI MS. Two different solid-phase extraction (SPE) methods were investigated, namely custom......Protein profiling of human serum by matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) is potentially a new diagnostic tool for early detection of human diseases, including cancer. Sample preparation is a key issue in MALDI MS and the analysis of complex samples such as serum......-made microcolumns and commercially available magnetic beads. Using these two methods, nineteen different sample preparation methods for serum profiling by MALDI MS were systematically tested with regard to matrix selection, stationary phase, selectivity, and reproducibility. Microcolumns were tested with regard...

Towards radiation detected resonance ionization spectroscopy on transfermium elements in a buffer gas cell

Energy Technology Data Exchange (ETDEWEB)

Lautenschlaeger, Felix; Walther, Thomas [Institut fuer Angewandte Physik, TU Darmstadt, 64289 Darmstadt (Germany); Laatiaoui, Mustapha; Block, Michael [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Helmholtz-Institut Mainz, 55128 Mainz (Germany); Lauth, Werner; Backe, Hartmut [Institut fuer Kernphysik, JGU Mainz, 55128 Mainz (Germany); Hessberger, Fritz-Peter [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany)

2013-07-01

The study of the atomic structure of transfermium elements like nobelium (No) and lawrencium (Lr) via Radiation Detected Resonance Ionization Spectroscopy (RADRIS) is one of the most fascinating disciplines of modern atomic physics. It allows the determination of relativistic effects at the heaviest elements and provides a critical test of theoretical predictions. For these transfermium elements no experimental data on atomic level schemes are available at present. First experiments on {sup 254}No were performed in 2007, in which a buffer gas cell with an overall efficiency of 1%. In this experiment the evaporation temperature of nobelium was determined for the first time. To increase the efficiency of the buffer gas cell, off-line measurements have been performed with nat. ytterbium, the chemical homologue of nobelium. Also on-line experiments during a parasitic beam-time in 2012 provided an insight into the critical parameters of our setup. The results of the off-line and on-line measurements are briefly summarized in this talk.

Three-Dimensional View of Ionized Gas Conditions in Galaxies

Science.gov (United States)

Juneau, Stephanie; NOAO Data Lab

2018-06-01

We present a 3D version of common emission line diagnostic diagrams used to identify the source of ionization in galaxies, and highlight interesting features in this new 3D space, which are associated with global galaxy properties. Namely, we combine the BPT and Mass-Excitation (MEx) diagrams, and apply it to a set of >300,000 galaxies from the SDSS survey. Among other features, we show that the usual “branch” of star-forming galaxies becomes a curved surface in the new 3D space. Understanding the underlying reasons can shed light on the nearby galaxy population but also aid our interpretation of high-redshift surveys, which indicate a strong evolution of emission line ratios. Despite efforts to explain the origin of this strong evolution, a consensus has not yet been reached. Yet, the implications are crucial to our understanding of galaxy growth across cosmic time, and in particular to assess how star forming regions differed at earlier times (gas properties? stellar properties? a combination?). We perform this analysis within the framework of the NOAO Data Lab (datalab.noao.edu) jointly with public visualization tools. The final workflow will be released publicly.

A multi purpose 4 π counter spherical ionization chamber type

International Nuclear Information System (INIS)

Calin, Marian Romeo; Calin, Adrian Cantemir

2004-01-01

A pressurized ionization chamber detector able to measure radioactive sources in internal 2π or 4π geometry was built in order to characterize alpha and beta radioactive sources, i.e. to calibrate these sources by relative method and to test the behavior of gas mixtures in pressurized-gas radiation detectors. The detector we made is of spherical shape and works by collecting in a uniform electric field the ionization charges resulting from the interaction of ionizing radiation with gas in the sensitive volume of the chamber. An ionizing current proportional to the activity of the radioactive source to be measured is obtained. In this paper a gas counter with a spherical symmetry is described. This detector can work in a very satisfactory manner, either as a flow counter or as a ionization chamber reaching in the latter case a good α pulse height resolution, even with large emitting sources. Calculations are made in order to find the dependence of the pulse shape on the direction of emission of an α-particle by a point source in the chamber (finite track). A good agreement is found between these calculations and the experimental tests performed, which show that this dependence can be employed in high efficiency measurements of angular α-γ correlations. (authors)

Development of a Portable Single Photon Ionization-Photoelectron Ionization Time-of-Flight Mass Spectrometer

Directory of Open Access Journals (Sweden)

Yunguang Huang

2015-01-01

Full Text Available A vacuum ultraviolet lamp based single photon ionization- (SPI- photoelectron ionization (PEI portable reflecting time-of-flight mass spectrometer (TOFMS was designed for online monitoring gas samples. It has a dual mode ionization source: SPI for analyte with ionization energy (IE below 10.6 eV and PEI for IE higher than 10.6 eV. Two kinds of sampling inlets, a capillary inlet and a membrane inlet, are utilized for high concentration and trace volatile organic compounds, respectively. A mass resolution of 1100 at m/z 64 has been obtained with a total size of 40 × 31 × 29 cm, the weight is 27 kg, and the power consumption is only 70 W. A mixture of benzene, toluene, and xylene (BTX, SO2, and discharging products of SF6 were used to test its performance, and the result showed that the limit of quantitation for BTX is as low as 5 ppbv (S/N = 10 : 1 with linear dynamic ranges greater than four orders of magnitude. The portable TOFMS was also evaluated by analyzing volatile organic compounds from wine and decomposition products of SF6 inside of a gas-insulated switchgear.

Neutron accelerator tube having improved ionization section

International Nuclear Information System (INIS)

Givens, W.W.

1981-01-01

A neutron accelerator tube having a target section, an ionization section, and a replenisher section for supplying accelerator gas to the ionization section. The ionization section is located between the target and the replenisher section and includes an ionization chamber adapted to receive accelerator gas from the replenisher section. The ionization section further includes spaced cathodes having opposed active surfaces exposed to the interior of the ionization chamber. An anode is located intermediate the cathodes whereby in response to an applied positive voltage, electrons created by field emmission are transmitted between the opposed active surfaces of the cathodes and produce the emission of secondary electrons. The active surface of at least one of the cathodes is formulated of a material having a secondary electron emission factor of at least 2. One cathode member located in the tube adjacent to the replenisher section may have a protuberant portion extending axially into the ioization chamber. The other cathode spaced from the first cathode member in the direction of the target has an aperture therein along the axis of the protuberant portion. An annular magnet extends around the exterior of the ionization chamber and envelops the anode member. Means are provided to establish a high permeability magnetic flux path extending outwardly from the opposed poles from the magnet to the active surfaces of the cathode members

Laws governing the energy conversion of ionization curves

International Nuclear Information System (INIS)

Gorgoskii, V.I.

1986-01-01

The author attempts to determine if ionization curves are structured or smooth, the cause of the smoothing of the curves, the possibility of the curves having maxima and why, how many maxima are on the ionization curve, and which of these maxima is the fundamental maxima. The study shows that ionization curves without and additional maximum, i.e., with one fundamental maximum, can be obtained for potassium, rubidium, and cesium. This requires reduction of the density of the electrons in the stream and the density of the atoms of the target gas. It is also shown that in order to obtain ionization curves with additional maxima in the cases of neon, argon, and krypton, the measurements must be carried out at high densities of the electrons in the stream and of the atoms of the target gas

Resonantly enhanced collisional ionization measurements of radionuclides

International Nuclear Information System (INIS)

Whitaker, T.J.; Bushaw, B.A.; Gerke, G.K.

1986-01-01

The authors developed a new laser technique to analyze for radionuclides at extremely low levels. The technique, called resonantly enhanced collisional ionization (RECI), uses two nitrogen-laser pumped dye lasers to excite the target isotope to a high-energy Rydberg state. Atoms in these Rydberg states (within a few hundred wavenumbers in energy from the ionization threshold) efficiently ionize upon colliding with an inert gas and the ions can be detected by conventional means. The principal advantage of resonantly-enhanced collisional ionization is the extreme sensitivity coupled with its relative simplicity and low cost. Actinides typically have an ionization potential of about 6eV (uranium I.P. = 6.2 eV, plutonium I.P. = 5.7 eV). Two-step laser excitation to a state just below threshold requires wavelengths in the blue region of the visible spectrum. They showed that when both steps in the excitation process are resonant steps, relatively low-power lasers can populate the Rydberg state with almost unit efficiency. This is because the resonant excitations have much larger cross-sections than do photoionization processes. They also demonstrated that a few torr of a buffer gas will cause most of the excited-state atoms to be ionized

Modulation of ionization in the plasma column of an optical discharge

International Nuclear Information System (INIS)

Nastoyashchii, A.F.

1981-01-01

Stability of the ionization in the plasma column of an optical discharge is discussed. It is shown that a plasma filament formed by a long laser spike under optical discharge conditions may break up into a chain of bright luminous layers oriented in the direction of propagation of a laser beam and characterized by a higher gas ionization (''optical striations''). A nonlinear formulation of the problem is used to find the depth of modulation of the gas ionization

Laser desorption/ionization mass spectrometry for direct profiling and imaging of small molecules from raw biological materials

Energy Technology Data Exchange (ETDEWEB)

Cha, Sangwon [Iowa State Univ., Ames, IA (United States)

2008-01-01

Matrix-assisted laser desorption/ionization(MALDI) mass spectrometry(MS) has been widely used for analysis of biological molecules, especially macromolecules such as proteins. However, MALDI MS has a problem in small molecule (less than 1 kDa) analysis because of the signal saturation by organic matrixes in the low mass region. In imaging MS (IMS), inhomogeneous surface formation due to the co-crystallization process by organic MALDI matrixes limits the spatial resolution of the mass spectral image. Therefore, to make laser desorption/ionization (LDI) MS more suitable for mass spectral profiling and imaging of small molecules directly from raw biological tissues, LDI MS protocols with various alternative assisting materials were developed and applied to many biological systems of interest. Colloidal graphite was used as a matrix for IMS of small molecules for the first time and methodologies for analyses of small metabolites in rat brain tissues, fruits, and plant tissues were developed. With rat brain tissues, the signal enhancement for cerebroside species by colloidal graphite was observed and images of cerebrosides were successfully generated by IMS. In addition, separation of isobaric lipid ions was performed by imaging tandem MS. Directly from Arabidopsis flowers, flavonoids were successfully profiled and heterogeneous distribution of flavonoids in petals was observed for the first time by graphite-assisted LDI(GALDI) IMS.

Analysis of acylcarnitines as their N-demethylated ester derivatives by gas chromatography-chemical ionization mass spectrometry.

Science.gov (United States)

Huang, Z H; Gage, D A; Bieber, L L; Sweeley, C C

1991-11-15

A novel approach to the analysis of acylcarnitines has been developed. It involves a direct esterification using propyl chloroformate in aqueous propanol followed by ion-pair extraction with potassium iodide into chloroform and subsequent on-column N-demethylation of the resulting acylcarnitine propyl ester iodides. The products, acyl N-demethylcarnitine propyl esters, are volatile and are easily analyzed by gas chromatography-chemical ionization mass spectrometry. For medium-chain-length (C4-C12) acylcarnitine standards, detection limits are demonstrated to be well below 1 ng starting material using selected ion monitoring. Well-separated gas chromatographic peaks and structure-specific mass spectra are obtained with samples of synthetic and biological origin. Seven acylcarnitines have been characterized in the urine of a patient suffering from medium-chain acyl-CoA dehydrogenase deficiency.

Ionization chamber

International Nuclear Information System (INIS)

1977-01-01

An improved ionization chamber type X-ray detector comprises a heavy gas at high pressure disposed between an anode and a cathode. An open grid structure is placed next to the anode and is maintained at a voltage intermediate between the cathode and anode potentials. The electric field which is produced by positive ions drifting towards the cathode is thus shielded from the anode. Current measuring circuits connected to the anode are, therefore, responsive only to electron current flow within the chamber and the recovery time of the chamber is shortened. The grid structure also serves to shield the anode from electrical currents which might otherwise be induced by mechanical vibrations in the ionization chamber structure

HIGH-TEMPERATURE IONIZATION IN PROTOPLANETARY DISKS

Energy Technology Data Exchange (ETDEWEB)

Desch, Steven J. [School of Earth and Space Exploration, Arizona State University, P.O. Box 871404, Tempe, AZ 85287-1404 (United States); Turner, Neal J. [Jet Propulsion Laboratory, Mail Stop 169-506, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States)

2015-10-01

We calculate the abundances of electrons and ions in the hot (≳500 K), dusty parts of protoplanetary disks, treating for the first time the effects of thermionic and ion emission from the dust grains. High-temperature ionization modeling has involved simply assuming that alkali elements such as potassium occur as gas-phase atoms and are collisionally ionized following the Saha equation. We show that the Saha equation often does not hold, because free charges are produced by thermionic and ion emission and destroyed when they stick to grain surfaces. This means the ionization state depends not on the first ionization potential of the alkali atoms, but rather on the grains’ work functions. The charged species’ abundances typically rise abruptly above about 800 K, with little qualitative dependence on the work function, gas density, or dust-to-gas mass ratio. Applying our results, we find that protoplanetary disks’ dead zone, where high diffusivities stifle magnetorotational turbulence, has its inner edge located where the temperature exceeds a threshold value ≈1000 K. The threshold is set by ambipolar diffusion except at the highest densities, where it is set by Ohmic resistivity. We find that the disk gas can be diffusively loaded onto the stellar magnetosphere at temperatures below a similar threshold. We investigate whether the “short-circuit” instability of current sheets can operate in disks and find that it cannot, or works only in a narrow range of conditions; it appears not to be the chondrule formation mechanism. We also suggest that thermionic emission is important for determining the rate of Ohmic heating in hot Jupiters.

HIGH-TEMPERATURE IONIZATION IN PROTOPLANETARY DISKS

International Nuclear Information System (INIS)

Desch, Steven J.; Turner, Neal J.

2015-01-01

We calculate the abundances of electrons and ions in the hot (≳500 K), dusty parts of protoplanetary disks, treating for the first time the effects of thermionic and ion emission from the dust grains. High-temperature ionization modeling has involved simply assuming that alkali elements such as potassium occur as gas-phase atoms and are collisionally ionized following the Saha equation. We show that the Saha equation often does not hold, because free charges are produced by thermionic and ion emission and destroyed when they stick to grain surfaces. This means the ionization state depends not on the first ionization potential of the alkali atoms, but rather on the grains’ work functions. The charged species’ abundances typically rise abruptly above about 800 K, with little qualitative dependence on the work function, gas density, or dust-to-gas mass ratio. Applying our results, we find that protoplanetary disks’ dead zone, where high diffusivities stifle magnetorotational turbulence, has its inner edge located where the temperature exceeds a threshold value ≈1000 K. The threshold is set by ambipolar diffusion except at the highest densities, where it is set by Ohmic resistivity. We find that the disk gas can be diffusively loaded onto the stellar magnetosphere at temperatures below a similar threshold. We investigate whether the “short-circuit” instability of current sheets can operate in disks and find that it cannot, or works only in a narrow range of conditions; it appears not to be the chondrule formation mechanism. We also suggest that thermionic emission is important for determining the rate of Ohmic heating in hot Jupiters

Alkaloid profiling of the Chinese herbal medicine Fuzi by combination of matrix-assisted laser desorption ionization mass spectrometry with liquid chromatography-mass spectrometry

NARCIS (Netherlands)

Wang, J.; Heijden, R. van der; Spijksma, G.; Reijmers, T.; Wang, M.; Xu, G.; Hankemeier, T.; Greef, J. van der

2009-01-01

A matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) method was developed for the high throughput and robust qualitative profiling of alkaloids in Fuzi-the processed lateral roots of the Chinese herbal medicine Aconitum carmichaeli Debx (A. carmichaeli). After optimization,

Gas phase ion chemistry

CERN Document Server

Bowers, Michael T

1979-01-01

Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

Ionizing radiation effects in Acai oil analysed by gas chromatography coupled to mass spectrometry technique

International Nuclear Information System (INIS)

Valli, Felipe; Fernandes, Carlos Eduardo; Moura, Sergio; Machado, Ana Carolina; Furasawa, Helio Akira; Pires, Maria Aparecida Faustino; Bustillos, Oscar Vega

2007-01-01

The Acai fruit is a well know Brazilian seed plant used in large scale as a source of feed stock, specially in the Brazilian North-east region. The Acai oil is use in many purposes from fuel sources to medicine. The scope of this paper is to analyzed the chemical structures modification of the acai oil after the ionizing radiation. The radiation were set in the range of 10 to 25 kGy in the extracted Acai oil. The analyses were made by gas chromatography coupled to mass spectrometry techniques. A GC/MS Shimatzu QP-5000 equipped with 30 meters DB-5 capillary column with internal diameter of 0.25 mm and 0.25 μm film thickness was used. Helium was used as carried gas and gave a column head pressure of 12 p.s.i. (1 p.s.i. = 6894.76 Pa) and an average flux of 1 ml/min. The temperature program for the GC column consisted of a 4-minutes hold at 75 deg C, a 15 deg C /min ramp to 200 deg C, 8 minutes isothermal. 20 deg C/min ramp to 250 deg C, 2 minutes isothermal. The extraction of the fatty acids was based on liquid-liquid method using chloroform as solvent. The chromatograms resulted shows the presences of the oleic acid and others fatty acids identify by the mass spectra library (NIST-92). The ionization radiation deplete the fatty acids presents in the Acai oil. Details on the chemical qualitative analytical is present as well in this work. (author)

Shock velocity in weakly ionized nitrogen, air, and argon

International Nuclear Information System (INIS)

Siefert, Nicholas S.

2007-01-01

The goal of this research was to determine the principal mechanism(s) for the shock velocity increase in weakly ionized gases. This paper reports experimental data on the propagation of spark-generated shock waves (1< Mach<3) into weakly ionized nitrogen, air, and argon glow discharges (1 < p<20 Torr). In order to distinguish between effects due solely to the presence of electrons and effects due to heating of the background gas via elastic collisions with electrons, the weakly ionized discharge was pulsed on/off. Laser deflection methods determined the shock velocity, and the electron number density was collected using a microwave hairpin resonator. In the afterglow of nitrogen, air, and argon discharges, the shock velocity first decreased, not at the characteristic time for electrons to diffuse to the walls, but rather at the characteristic time for the centerline gas temperature to equilibrate with the wall temperature. These data support the conclusion that the principal mechanism for the increase in shock velocity in weakly ionized gases is thermal heating of the neutral gas species via elastic collisions with electrons

Effect of surface potential and intrinsic magnetic field on resistance of a body in a supersonic flow of rarefied partially ionized gas

International Nuclear Information System (INIS)

Shuvalov, V.A.

1986-01-01

The character of flow over a body, structure of the perturbed zone, and flow resistance in a supersonic flow of rarefied partially ionized gas are determined by the intrinsic magnetic field and surface potential of the body. There have been practically no experimental studies of the effect of intrinsic magnetic field on flow of a rarefied plasma. Studies of the effect of surface potential have been limited to the case R/λd 10 2 (where R is the characteristic dimension of the body and λd is the Debye radius). At the same time R/λd > 10 2 , the regime of flow over a large body, is of the greatest practical interest. The present study will consider the effect of potential and intrinsic magnetic field on resistance of a large (R/λd > 10 2 ) axisymmetric body (disk, sphere) in a supersonic flow of rarefield partially ionized gas

Chemical profile of Taxodium distichum winter cones

Directory of Open Access Journals (Sweden)

Đapić Nina M.

2017-01-01

Full Text Available This work is concerned with the chemical profile of Taxodium distichum winter cones. The extract obtained after maceration in absolute ethanol was subjected to qualitative analysis by gas chromatography/mass spectrometry and quantification was done by gas chromatography/ flame ionization detector. The chromatogram revealed the presence of 53 compounds, of which 33 compounds were identified. The extract contained oxygenated monoterpenes (12.42%, sesquiterpenes (5.18%, oxygenated sesquiterpenes (17.41%, diterpenes (1.15%, and oxygenated diterpenes (30.87%, while the amount of retinoic acid was 0.32%. Monoacylglycerols were detected in the amount of 4.32%. The most abundant compounds were: caryophyllene oxide (14.27%, 6,7-dehydro-ferruginol (12.49%, bornyl acetate (10.96%, 6- deoxy-taxodione (9.50% and trans-caryophyllene (4.20%.

Ionization Processes in the Atmosphere of Titan (Research Note). III. Ionization by High-Z Nuclei Cosmic Rays

Science.gov (United States)

Gronoff, G.; Mertens, C.; Lilensten, J.; Desorgher, L.; Fluckiger, E.; Velinov, P.

2011-01-01

Context. The Cassini-Huygens mission has revealed the importance of particle precipitation in the atmosphere of Titan thanks to in-situ measurements. These ionizing particles (electrons, protons, and cosmic rays) have a strong impact on the chemistry, hence must be modeled. Aims. We revisit our computation of ionization in the atmosphere of Titan by cosmic rays. The high-energy high-mass ions are taken into account to improve the precision of the calculation of the ion production profile. Methods. The Badhwahr and O Neill model for cosmic ray spectrum was adapted for the Titan model. We used the TransTitan model coupled with the Planetocosmics model to compute the ion production by cosmic rays. We compared the results with the NAIRAS/HZETRN ionization model used for the first time for a body that differs from the Earth. Results. The cosmic ray ionization is computed for five groups of cosmic rays, depending on their charge and mass: protons, alpha, Z = 8 (oxygen), Z = 14 (silicon), and Z = 26 (iron) nucleus. Protons and alpha particles ionize mainly at 65 km altitude, while the higher mass nucleons ionize at higher altitudes. Nevertheless, the ionization at higher altitude is insufficient to obscure the impact of Saturn s magnetosphere protons at a 500 km altitude. The ionization rate at the peak (altitude: 65 km, for all the different conditions) lies between 30 and 40/cu cm/s. Conclusions. These new computations show for the first time the importance of high Z cosmic rays on the ionization of the Titan atmosphere. The updated full ionization profile shape does not differ significantly from that found in our previous calculations (Paper I: Gronoff et al. 2009, 506, 955) but undergoes a strong increase in intensity below an altitude of 400 km, especially between 200 and 400 km altitude where alpha and heavier particles (in the cosmic ray spectrum) are responsible for 40% of the ionization. The comparison of several models of ionization and cosmic ray spectra (in

Single and multiple ionization of noble gas atoms by H0 impact

International Nuclear Information System (INIS)

Sarkadi, L.; Gulyas, L.; Herczku, P.; Kovacs, S.T.S.; Koever, A.

2012-01-01

Complete text of publication follows. The understanding of the mechanisms of collisions between energetic charged particles and neutral atoms is of fundamental significance, and it has large importance in many research fields (plasma physics, astrophysics, materials science, etc.), as well as in number of practical applications. In the present work we measured total direct ionization and electron loss cross sections for the collisions of H 0 atoms with noble gas atoms (He, Ne, Ar, Kr) in the energy range 75-300 keV. The experiment was carried out at the 1.5 MV Van de Graaff accelerator of Atomki by coincident detection of the recoil target ions and the charge-state analyzed scattered projectiles. With this study we wished to obtain information about the role played by the electron of the H 0 projectile in the process of the single and multiple vacancy production induced by the collision. For this purpose we repeated the measurements also with proton projectile under the same experimental conditions. For calibration of the measuring system and normalization of our data we used the cross section values of Ref. [1]. The experimental results were analysed with using the classical trajectory Monte Carlo (CTMC) method. CTMC describes well the experimental data for both projectiles for the single vacancy creation, however we observed increasing deviation between the theory and experiment with increasing number of the created vacancies, as well as with decreasing atomic number of the target atoms. Fig. 1 shows our results obtained for the single, double and triple ionization (q = 1, 2, 3) of Kr at H 0 impact for the two cases when the outgoing projectile is H 0 (a) and H + (b), i.e., for pure ionization of the target, and ionization of the target with simultaneous electron loss of the projectile. The curves in the figure were obtained by two versions of the three-body CTMC theory: a conventional model (dashed curves); and a model taking partially account of the many

Kinetic theory of weakly ionized dilute gas of hydrogen-like atoms of the first principles of quantum statistics and dispersion laws of eigenwaves

Science.gov (United States)

Slyusarenko, Yurii V.; Sliusarenko, Oleksii Yu.

2017-11-01

We develop a microscopic approach to the construction of the kinetic theory of dilute weakly ionized gas of hydrogen-like atoms. The approach is based on the statements of the second quantization method in the presence of bound states of particles. The basis of the derivation of kinetic equations is the method of reduced description of relaxation processes. Within the framework of the proposed approach, a system of common kinetic equations for the Wigner distribution functions of free oppositely charged fermions of two kinds (electrons and cores) and their bound states—hydrogen-like atoms— is obtained. Kinetic equations are used to study the spectra of elementary excitations in the system when all its components are non-degenerate. It is shown that in such a system, in addition to the typical plasma waves, there are longitudinal waves of matter polarization and the transverse ones with a behavior characteristic of plasmon polaritons. The expressions for the dependence of the frequencies and Landau damping coefficients on the wave vector for all branches of the oscillations discovered are obtained. Numerical evaluation of the elementary perturbation parameters in the system on an example of a weakly ionized dilute gas of the 23Na atoms using the D2-line characteristics of the natrium atom is given. We note the possibility of using the results of the developed theory to describe the properties of a Bose condensate of photons in the diluted weakly ionized gas of hydrogen-like atoms.

A combined segmented anode gas ionization chamber and time-of-flight detector for heavy ion elastic recoil detection analysis

Science.gov (United States)

Ström, Petter; Petersson, Per; Rubel, Marek; Possnert, Göran

2016-10-01

A dedicated detector system for heavy ion elastic recoil detection analysis at the Tandem Laboratory of Uppsala University is presented. Benefits of combining a time-of-flight measurement with a segmented anode gas ionization chamber are demonstrated. The capability of ion species identification is improved with the present system, compared to that obtained when using a single solid state silicon detector for the full ion energy signal. The system enables separation of light elements, up to Neon, based on atomic number while signals from heavy elements such as molybdenum and tungsten are separated based on mass, to a sample depth on the order of 1 μm. The performance of the system is discussed and a selection of material analysis applications is given. Plasma-facing materials from fusion experiments, in particular metal mirrors, are used as a main example for the discussion. Marker experiments using nitrogen-15 or oxygen-18 are specific cases for which the described improved species separation and sensitivity are required. Resilience to radiation damage and significantly improved energy resolution for heavy elements at low energies are additional benefits of the gas ionization chamber over a solid state detector based system.

Supercritical carbon dioxide extraction of electrolyte from spent lithium ion batteries and its characterization by gas chromatography with chemical ionization

Science.gov (United States)

Mönnighoff, Xaver; Friesen, Alex; Konersmann, Benedikt; Horsthemke, Fabian; Grützke, Martin; Winter, Martin; Nowak, Sascha

2017-06-01

The aging products of the electrolyte from a commercially available state-of-the-art 18650-type cell were investigated. During long term cycling a huge difference in their performance and lifetime at different temperatures was observed. By interpretation of a strong capacity fading of cells cycled at 20 °C compared to cells cycled at 45 °C a temperature depending aging mechanism was determined. To investigate the influence of the electrolyte on this fading, the electrolyte was extracted by supercritical fluid extraction (SFE) and then analyzed by gas chromatography (GC) with electron impact (EI) ionization and mass selective detection. To obtain more information with regard to the identification of unknown decomposition products further analysis with positive chemical ionization (PCI) and negative chemical ionization (NCI) was performed. 17 different volatile organic aging products were detected and identified. So far, seven of them were not yet known in literature and several formation pathways were postulated taking previously published literature into account.

The critical ionization velocity

International Nuclear Information System (INIS)

Raadu, M.A.

1980-06-01

The critical ionization velocity effect was first proposed in the context of space plasmas. This effect occurs for a neutral gas moving through a magnetized plasma and leads to rapid ionization and braking of the relative motion when a marginal velocity, 'the critical velocity', is exceeded. Laboratory experiments have clearly established the significance of the critical velocity and have provided evidence for an underlying mechanism which relies on the combined action of electron impact ionization and a collective plasma interaction heating electrons. There is experimental support for such a mechanism based on the heating of electrons by the modified two-stream instability as part of a feedback process. Several applications to space plasmas have been proposed and the possibility of space experiments has been discussed. (author)

Radial Surface Density Profiles of Gas and Dust in the Debris Disk around 49 Ceti

Energy Technology Data Exchange (ETDEWEB)

Hughes, A. Meredith; Lieman-Sifry, Jesse; Flaherty, Kevin M.; Daley, Cail M. [Department of Astronomy, Van Vleck Observatory, Wesleyan University, 96 Foss Hill Drive, Middletown, CT 06459 (United States); Roberge, Aki [Exoplanets and Stellar Astrophysics Laboratory, NASA Goddard Space Flight Center, Code 667, Greenbelt, MD 20771 (United States); Kóspál, Ágnes; Moór, Attila; Ábrahám, Peter [Konkoly Observatory, Research Centre for Astronomy and Earth Sciences, Hungarian Academy of Sciences, P.O. Box 67, 1525 Budapest (Hungary); Kamp, Inga [Kapteyn Astronomical Institute, University of Groningen, Postbus 800, 9700 AV Groningen (Netherlands); Wilner, David J.; Andrews, Sean M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-51, Cambridge, MA 02138 (United States); Kastner, Joel H., E-mail: amhughes@astro.wesleyan.edu [Rochester Institute of Technology, 54 Lomb Memorial Drive, Rochester, NY 14623 (United States)

2017-04-20

We present ∼0.″4 resolution images of CO(3–2) and associated continuum emission from the gas-bearing debris disk around the nearby A star 49 Ceti, observed with the Atacama Large Millimeter/Submillimeter Array (ALMA). We analyze the ALMA visibilities in tandem with the broadband spectral energy distribution to measure the radial surface density profiles of dust and gas emission from the system. The dust surface density decreases with radius between ∼100 and 310 au, with a marginally significant enhancement of surface density at a radius of ∼110 au. The SED requires an inner disk of small grains in addition to the outer disk of larger grains resolved by ALMA. The gas disk exhibits a surface density profile that increases with radius, contrary to most previous spatially resolved observations of circumstellar gas disks. While ∼80% of the CO flux is well described by an axisymmetric power-law disk in Keplerian rotation about the central star, residuals at ∼20% of the peak flux exhibit a departure from axisymmetry suggestive of spiral arms or a warp in the gas disk. The radial extent of the gas disk (∼220 au) is smaller than that of the dust disk (∼300 au), consistent with recent observations of other gas-bearing debris disks. While there are so far only three broad debris disks with well characterized radial dust profiles at millimeter wavelengths, 49 Ceti’s disk shows a markedly different structure from two radially resolved gas-poor debris disks, implying that the physical processes generating and sculpting the gas and dust are fundamentally different.

Ionization detection system for aerosols

International Nuclear Information System (INIS)

Jacobs, M.E.

1977-01-01

This invention relates to an improved smoke-detection system of the ionization-chamber type. In the preferred embodiment, the system utilizes a conventional detector head comprising a measuring ionization chamber, a reference ionization chamber, and a normally non-conductive gas triode for discharging when a threshold concentration of airborne particulates is present in the measuring chamber. The improved system utilizes a measuring ionization chamber which is modified to minimize false alarms and reductions in sensitivity resulting from changes in ambient temperature. In the preferred form of the modification, an annular radiation shield is mounted about the usual radiation source provided to effect ionization in the measuring chamber. The shield is supported by a bimetallic strip which flexes in response to changes in ambient temperature, moving the shield relative to the source so as to vary the radiative area of the source in a manner offsetting temperature-induced variations in the sensitivity of the chamber. 8 claims, 7 figures

RESIDUAL GAS MOTIONS IN THE INTRACLUSTER MEDIUM AND BIAS IN HYDROSTATIC MEASUREMENTS OF MASS PROFILES OF CLUSTERS

International Nuclear Information System (INIS)

Lau, Erwin T.; Kravtsov, Andrey V.; Nagai, Daisuke

2009-01-01

We present analysis of bulk and random gas motions in the intracluster medium using high-resolution Eulerian cosmological simulations of 16 simulated clusters, including both very relaxed and unrelaxed systems and spanning a virial mass range of 5 x 10 13 - 2 x 10 15 h -1 M-odot. We investigate effects of the residual subsonic gas motions on the hydrostatic estimates of mass profiles and concentrations of galaxy clusters. In agreement with previous studies, we find that the gas motions contribute up to ∼5%-15% of the total pressure support in relaxed clusters with contribution increasing with the cluster-centric radius. The fractional pressure support is higher in unrelaxed systems. This contribution would not be accounted for in hydrostatic estimates of the total mass profile and would lead to systematic underestimate of mass. We demonstrate that total mass can be recovered accurately if pressure due to gas motions measured in simulations is explicitly taken into account in the equation of hydrostatic equilibrium. Given that the underestimate of mass is increasing at larger radii, where gas is less relaxed and contribution of gas motions to pressure is larger, the total density profile derived from hydrostatic analysis is more concentrated than the true profile. This may at least partially explain some high values of concentrations of clusters estimated from hydrostatic analysis of X-ray data.

Hydrocarbon analysis using desorption atmospheric pressure chemical ionization

KAUST Repository

Jjunju, Fred Paul Mark; Badu-Tawiah, Abraham K.; Li, Anyin; Soparawalla, Santosh; Roqan, Iman S.; Cooks, Robert Graham

2013-01-01

Characterization of the various petroleum constituents (hydronaphthalenes, thiophenes, alkyl substituted benzenes, pyridines, fluorenes, and polycyclic aromatic hydrocarbons) was achieved under ambient conditions without sample preparation by desorption atmospheric pressure chemical ionization (DAPCI). Conditions were chosen for the DAPCI experiments to control whether ionization was by proton or electron transfer. The protonated molecule [M+H]+ and the hydride abstracted [MH]+ form were observed when using an inert gas, typically nitrogen, to direct a lightly ionized plasma generated by corona discharge onto the sample surface in air. The abundant water cluster ions generated in this experiment react with condensed-phase functionalized hydrocarbon model compounds and their mixtures at or near the sample surface. On the other hand, when naphthalene was doped into the DAPCI gas stream, its radical cation served as a charge exchange reagent, yielding molecular radical cations (M+) of the hydrocarbons. This mode of sample ionization provided mass spectra with better signal/noise ratios and without unwanted side-products. It also extended the applicability of DAPCI to petroleum constituents which could not be analyzed through proton transfer (e.g., higher molecular PAHs such as chrysene). The thermochemistry governing the individual ionization processes is discussed and a desorption/ionization mechanism is inferred. © 2012 Elsevier B.V.

Hydrocarbon analysis using desorption atmospheric pressure chemical ionization

KAUST Repository

Jjunju, Fred Paul Mark

2013-07-01

Characterization of the various petroleum constituents (hydronaphthalenes, thiophenes, alkyl substituted benzenes, pyridines, fluorenes, and polycyclic aromatic hydrocarbons) was achieved under ambient conditions without sample preparation by desorption atmospheric pressure chemical ionization (DAPCI). Conditions were chosen for the DAPCI experiments to control whether ionization was by proton or electron transfer. The protonated molecule [M+H]+ and the hydride abstracted [MH]+ form were observed when using an inert gas, typically nitrogen, to direct a lightly ionized plasma generated by corona discharge onto the sample surface in air. The abundant water cluster ions generated in this experiment react with condensed-phase functionalized hydrocarbon model compounds and their mixtures at or near the sample surface. On the other hand, when naphthalene was doped into the DAPCI gas stream, its radical cation served as a charge exchange reagent, yielding molecular radical cations (M+) of the hydrocarbons. This mode of sample ionization provided mass spectra with better signal/noise ratios and without unwanted side-products. It also extended the applicability of DAPCI to petroleum constituents which could not be analyzed through proton transfer (e.g., higher molecular PAHs such as chrysene). The thermochemistry governing the individual ionization processes is discussed and a desorption/ionization mechanism is inferred. © 2012 Elsevier B.V.

On possible structures of transverse ionizing shock waves

International Nuclear Information System (INIS)

Liberman, M.A.; Velikovich, A.L.

1978-01-01

The possible structures of ionizing shock waves propagating in gases across the magnetic field are investigated taking account of both ionization kinetics and the non-isothermality of the plasma which is formed within the shock front. It is shown that a definite factor in shaping the structure of the transverse ionizing shock wave is photo-ionization of the neutral gas across the front. The paper includes a study of the evolution of the transverse ionizing shock front with regard to photo-ionization, disclosing that a stable stationary shock structure emerges only in boundary conditions which are close to magnetohydrodynamic ones, i.e. upsilon 1 H 1 = upsilon 2 H 2 . In the case of strong transverse ionizing shock waves, when the flux of ionizing radiation across the front is great, the shock structure is obviously magnetohydrodynamic. (author)

The Ionization Fraction in the Obscuring ``Torus'' of an Active Galactic Nucleus

Science.gov (United States)

Wilson, A. S.; Roy, A. L.; Ulvestad, J. S.; Colbert, E. J. M.; Weaver, K. A.; Braatz, J. A.; Henkel, C.; Matsuoka, M.; Xue, S.; Iyomoto, N.; Okada, K.

1998-10-01

The LINER galaxy NGC 2639 contains a water vapor megamaser, suggesting the presence of a nuclear accretion disk or torus viewed close to edge-on. This galaxy is thus a good candidate for revealing absorption by the torus of any compact nuclear continuum emission. In this paper, we report VLBA radio maps at three frequencies and an ASCA X-ray spectrum obtained to search for free-free and photoelectric absorptions, respectively. The radio observations reveal a compact (~1.3 × 10-5, which is comparable to the theoretical upper limit derived by Neufeld, Maloney, and Conger for X-ray heated molecular gas. The two values may be reconciled if the molecular gas is very dense: nH2>~109 cm-3. The measured ionization fraction is also consistent with the idea that both absorptions occur in a hot (~6000 K), weakly ionized (ionization fraction a few times 10-2) atomic region that may coexist with the warm molecular gas. If this is the case, the absorbing gas is ~1 pc from the nucleus. We rule out the possibility that both absorptions occur in a fully ionized gas near 104 K. If our line of sight passes through more than one phase, the atomic gas probably dominates the free-free absorption, while the molecular gas may dominate the photoelectric absorption.

Optimization of laser-plasma injector via beam loading effects using ionization-induced injection

Science.gov (United States)

Lee, P.; Maynard, G.; Audet, T. L.; Cros, B.; Lehe, R.; Vay, J.-L.

2018-05-01

Simulations of ionization-induced injection in a laser driven plasma wakefield show that high-quality electron injectors in the 50-200 MeV range can be achieved in a gas cell with a tailored density profile. Using the PIC code Warp with parameters close to existing experimental conditions, we show that the concentration of N2 in a hydrogen plasma with a tailored density profile is an efficient parameter to tune electron beam properties through the control of the interplay between beam loading effects and varying accelerating field in the density profile. For a given laser plasma configuration, with moderate normalized laser amplitude, a0=1.6 and maximum electron plasma density, ne 0=4 ×1018 cm-3 , the optimum concentration results in a robust configuration to generate electrons at 150 MeV with a rms energy spread of 4% and a spectral charge density of 1.8 pC /MeV .

The Effects of Added Hydrogen on Noble Gas Discharges Used as Ambient Desorption/Ionization Sources for Mass Spectrometry

Science.gov (United States)

Ellis, Wade C.; Lewis, Charlotte R.; Openshaw, Anna P.; Farnsworth, Paul B.

2016-09-01

We demonstrate the effectiveness of using hydrogen-doped argon as the support gas for the dielectric barrier discharge (DBD) ambient desorption/ionization (ADI) source in mass spectrometry. Also, we explore the chemistry responsible for the signal enhancement observed when using both hydrogen-doped argon and hydrogen-doped helium. The hydrogen-doped argon was tested for five analytes representing different classes of molecules. Addition of hydrogen to the argon plasma gas enhanced signals for gas-phase analytes and for analytes coated onto glass slides in positive and negative ion mode. The enhancements ranged from factors of 4 to 5 for gas-phase analytes and factors of 2 to 40 for coated slides. There was no significant increase in the background. The limit of detection for caffeine was lowered by a factor of 79 using H2/Ar and 2 using H2/He. Results are shown that help explain the fundamental differences between the pure-gas discharges and those that are hydrogen-doped for both argon and helium. Experiments with different discharge geometries and grounding schemes indicate that observed signal enhancements are strongly dependent on discharge configuration.

Modeling of radial gas fraction profiles for bubble flow in vertical pipes

Energy Technology Data Exchange (ETDEWEB)

Lucas, D.; Krepper, E.; Prasser, H.-M. [Forschungszentrum Rossendorf e.V., Institute of Safety Research, Dresden (Germany)

2001-07-01

The paper presents a method for the prediction of radial gas fraction profiles from a given bubble size distribution. The method is based on the assumption of the equilibrium of the forces acting on a bubble perpendicularly to the flow direction. Assuming a large number of bubble size classes radial distributions are calculated separately for all bubble classes. The sum of these distributions is the radial profile of the gas fraction. The results of the model are compared with experimental data for a number of gas and liquid volume flow rates. The experiments were performed at a vertical test loop (inner diameter 50 mm) in FZ-Rossendorf using a wire mesh sensor. The sensor enables the determination of void distributions in the cross section of the loop. A special evaluation procedure supplies bubble size distributions as well as local distributions of bubbles within a predefined interval of bubble sizes. There is a good agreement between experimental and calculated data. In particular the change from wall peaking to core peaking is well predicted. (authors)

Modeling of radial gas fraction profiles for bubble flow in vertical pipes

International Nuclear Information System (INIS)

Lucas, D.; Krepper, E.; Prasser, H.-M.

2001-01-01

The paper presents a method for the prediction of radial gas fraction profiles from a given bubble size distribution. The method is based on the assumption of the equilibrium of the forces acting on a bubble perpendicularly to the flow direction. Assuming a large number of bubble size classes radial distributions are calculated separately for all bubble classes. The sum of these distributions is the radial profile of the gas fraction. The results of the model are compared with experimental data for a number of gas and liquid volume flow rates. The experiments were performed at a vertical test loop (inner diameter 50 mm) in FZ-Rossendorf using a wire mesh sensor. The sensor enables the determination of void distributions in the cross section of the loop. A special evaluation procedure supplies bubble size distributions as well as local distributions of bubbles within a predefined interval of bubble sizes. There is a good agreement between experimental and calculated data. In particular the change from wall peaking to core peaking is well predicted. (authors)

Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

International Nuclear Information System (INIS)

Hong, Sung-Ha; Jenkins, A Toby A; Szili, Endre J; Short, Robert D

2014-01-01

This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine. (fast track communication)

Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

Science.gov (United States)

Hong, Sung-Ha; Szili, Endre J.; Jenkins, A. Toby A.; Short, Robert D.

2014-09-01

This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine.

Partially ionized gas flow and heat transfer in the separation, reattachment, and redevelopment regions downstream of an abrupt circular channel expansion.

Science.gov (United States)

Back, L. H.; Massier, P. F.; Roschke, E. J.

1972-01-01

Heat transfer and pressure measurements obtained in the separation, reattachment, and redevelopment regions along a tube and nozzle located downstream of an abrupt channel expansion are presented for a very high enthalpy flow of argon. The ionization energy fraction extended up to 0.6 at the tube inlet just downstream of the arc heater. Reattachment resulted from the growth of an instability in the vortex sheet-like shear layer between the central jet that discharged into the tube and the reverse flow along the wall at the lower Reynolds numbers, as indicated by water flow visualization studies which were found to dynamically model the high-temperature gas flow. A reasonably good prediction of the heat transfer in the reattachment region where the highest heat transfer occurred and in the redevelopment region downstream can be made by using existing laminar boundary layer theory for a partially ionized gas. In the experiments as much as 90 per cent of the inlet energy was lost by heat transfer to the tube and the nozzle wall.

Kinetic theory of neutrals in a bounded plasma slab with inhomogeneous temperature and density profile

International Nuclear Information System (INIS)

Tendler, M.B.; Agren, O.

1982-01-01

The transport of neutral hydrogen atoms in a hydrogen plasma slab is considered. The influence of the inhomogeneous ion temperature profile on the neutral density and distribution is discussed as well as the influence of the neutral edge energy, charge exchange, and ionization rates. The analytical solutions for the neutral density and distribution function are obtained and compared with the numerical results. The effects due to the inhomogeneous temperature profile are discussed. The recommen-dations from the viewpoint of the effects mentioned previously for the purposes of the cold-gas mantle system have been given

A rapid novel derivatization of amphetamine and methamphetamine using 2,2,2-trichloroethyl chloroformate for gas chromatography electron ionization and chemical ionization mass spectrometric analysis.

Science.gov (United States)

Dasgupta, A; Spies, J

1998-05-01

Amphetamine and methamphetamine are commonly abused central nervous system stimulants. We describe a rapid new derivatization of amphetamine and methamphetamine using 2,2,2-trichloroethyl chloroformate for gas chromatography-mass spectrometric analysis. Amphetamine and methamphetamine, along with N-propyl amphetamine (internal standard), were extracted from urine using 1-chlorobutane. The derivatization with 2,2,2-trichloroethyl chloroformate can be achieved at room temperature in 10 minutes. The electron ionization mass spectrum of amphetamine 2,2,2-trichloroethyl carbamate showed two weak molecular ions at m/z 309 and 311, but showed diagnostic strong peaks at m/z 218, 220, and 222. In contrast, chemical ionization of the mass spectrum of amphetamine 2,2,2-trichloroethyl carbamate showed strong (M + 1) ions at m/z 310 and 312 and other strong diagnostic peaks at m/z 274 and 276. The major advantages of this derivative are the presence of a diagnostic cluster of peaks due to the isotopic effect of three chlorine atoms (isotopes 35 and 37) in the derivatized molecule and the relative ease of its preparation. We also observed strong molecular ions for derivatized methamphetamine in the chemical ionization mass spectrum, but the molecular ions were very weak in the electron ionization mass spectrum. We used the scan mode of mass spectrometry in all analyses. When using a urine standard containing 1,000 ng/mL of amphetamine (a 7.4-micromol/L concentration) and methamphetamine (a 6.7-micromol/L concentration), the within-run precisions were 4.8% for amphetamine and 3.6% for methamphetamine. The corresponding between-run precisions were 5.3% for amphetamine and 6.7% for methamphetamine. The assay was linear for amphetamine and methamphetamine concentrations of 250 to 5,000 ng/mL (amphetamine, 1.9-37.0 micromol/L; methamphetamine, 1.7-33.6 micromol/L). The detection limit was 100 ng/mL (amphetamine, 0.74 micromol/L; methamphetamine, 0.67 micromol/L) using the scan mode

Heavy ion source support gas mixing experiments

International Nuclear Information System (INIS)

Hudson, E.D.; Mallory, M.L.

1977-01-01

Experiments on mixing an easily ionized support gas with the primary ion source gas have produced large beam enhancements for high charge state light ions (masses less than or equal to 20). In the Oak Ridge Isochronous Cyclotron (ORIC), the beam increase has been a factor of 5 or greater, depending on ion species and charge state. Approximately 0.1 cc/min of the easily ionized support gas (argon, krypton, or xenon) is supplied to the ion source through a separate gas line and the primary gas flow is reduced by approximately 30 percent. The proposed mechanism for increased intensity is as follows: The heavier support gas ionizes readily to a higher charge state, providing increased cathode heating. The increased heating permits a reduction in primary gas flow (lower pressure) and the subsequent beam increase

Oxidation of Carbon Nanotubes in an Ionizing Environment.

Science.gov (United States)

Koh, Ai Leen; Gidcumb, Emily; Zhou, Otto; Sinclair, Robert

2016-02-10

In this work, we present systematic studies on how an illuminating electron beam which ionizes molecular gas species can influence the mechanism of carbon nanotube oxidation in an environmental transmission electron microscope (ETEM). We found that preferential attack of the nanotube tips is much more prevalent than for oxidation in a molecular gas environment. We establish the cumulative electron doses required to damage carbon nanotubes from 80 keV electron beam irradiation in gas versus in high vacuum. Our results provide guidelines for the electron doses required to study carbon nanotubes within or without a gas environment, to determine or ameliorate the influence of the imaging electron beam. This work has important implications for in situ studies as well as for the oxidation of carbon nanotubes in an ionizing environment such as that occurring during field emission.

A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge.

Science.gov (United States)

Kirk, Ansgar T; Last, Torben; Zimmermann, Stefan

2017-02-03

In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75×60×25mm 3 and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone. Copyright © 2017 Elsevier B.V. All rights reserved.

Ionization waves caused by the effects of a magnetic field

International Nuclear Information System (INIS)

Miura, Kosuke; Imazu, Shingo

1980-01-01

The self-excited ionization waves was observed in the Ne positive column. The experiments were made for Ne gas from 0.07 to 1.0 Torr, with the magnetic field from 0 to 3.33 kG. The discharge current were 10 to 300 mA. The longitudinal magnetic field was made by an air-core solenoid coil. The axial electric field was measured by two wall probes. The frequency, wave length and amplitude of waves were measured with a photo multiplier. It was found that the longitudinal magnetic field caused new self-excited ionization waves. The frequency of these waves decreased monotonously with increasing field. The behaviors of the wave length and amplitude were complicate, and the cause of these phenomena is related to the ionization waves due to the spatial resonance of electron gas, namely s-waves, p-waves and fluid γ-waves. The threshold of the magnetic field to cause the ionization waves increased with increasing gas pressure, and with decreasing discharge current in the range 0.07 to 0.44 Torr. The frequency of the self-excited ionization waves occurred at zero field was almost constant in the field-frequency relation. A simple dispersion equation was derived, and the Novak constant can be introduced. (J.P.N.)

CF3+ fragmentation by electron impact ionization of perfluoro-propyl-vinyl-ethers, C5F10O, in gas phase

Science.gov (United States)

Kondo, Yusuke; Ishikawa, Kenji; Hayashi, Toshio; Miyawaki, Yudai; Takeda, Keigo; Kondo, Hiroki; Sekine, Makoto; Hori, Masaru

2015-04-01

The gas phase fragmentations of perfluoro-propyl-vinyl ether (PPVE, C5F10O) are studied experimentally. Dominant fragmentations of PPVE are found to be the result of a dissociative ionization reaction, i.e., CF3+ via direct bond cleavage, and C2F3O- and C3F7O- via electron attachment. Regardless of the appearance energy of around 14.5 eV for the dissociative ionization of CF3+, the observed ion efficiency for the CF3+ ion was extremely large the order of 10-20 cm-2, compared with only 10-21 cm-2 for the other channels. PPVE characteristically generated CF3+ as the largest abundant ion are advantageous for use of feedstock gases in plasma etching processes.

Gas-phase pesticide measurement using iodide ionization time-of-flight mass spectrometry

Directory of Open Access Journals (Sweden)

T. Murschell

2017-06-01

Full Text Available Volatilization and subsequent processing in the atmosphere are an important environmental pathway for the transport and chemical fate of pesticides. However, these processes remain a particularly poorly understood component of pesticide lifecycles due to analytical challenges in measuring pesticides in the atmosphere. Most pesticide measurements require long (hours to days sampling times coupled with offline analysis, inhibiting observation of meteorologically driven events or investigation of rapid oxidation chemistry. Here, we present chemical ionization time-of-flight mass spectrometry with iodide reagent ions as a fast and sensitive measurement of four current-use pesticides. These semi-volatile pesticides were calibrated with injections of solutions onto a filter and subsequently volatilized to generate gas-phase analytes. Trifluralin and atrazine are detected as iodide–molecule adducts, while permethrin and metolachlor are detected as adducts between iodide and fragments of the parent analyte molecule. Limits of detection (1 s are 0.37, 0.67, 0.56, and 1.1 µg m−3 for gas-phase trifluralin, metolachlor, atrazine, and permethrin, respectively. The sensitivities of trifluralin and metolachlor depend on relative humidity, changing as much as 70 and 59, respectively, as relative humidity of the sample air varies from 0 to 80 %. This measurement approach is thus appropriate for laboratory experiments and potentially near-source field measurements.

Monte Carlo simulation of ionization in a magnetron plasma

International Nuclear Information System (INIS)

Miranda, J.E.; Goeckner, M.J.; Goree, J.; Sheridan, T.E.

1990-01-01

A Monte Carlo simulation of electrons emitted from the cathode of a planar magnetron is tested against experiments that were reported by Wendt, Lieberman, and Meuth [J. Vac. Sci. Technol. A 6, 1827 (1988)] and by Gu and Lieberman [J. Vac. Sci. Technol. A 6, 2960 (1988)]. Comparing their measurements of the radial profile of current and the axial profile of optical emission to the ionization profiles predicted by the model, we find good agreement for a typical magnetic field strength of 456 G. We also find that at 456 G the product of the average number of ionizations left-angle N i right-angle and the secondary electron emission coefficient γ is ∼1. This indicates that secondary emission contributes significantly to the ionization that sustains the discharge. At 171 G, however, left-angle N i right-angle γ much-lt 1, revealing that cathode emission is inadequate to sustain a discharge at a low magnetic field

Radionuclide measurements using resonantly enhanced collisional ionization

International Nuclear Information System (INIS)

Whitaker, T.J.; Bushaw, B.A.; Gerke, G.K.

1987-01-01

This report describes development of a laser-enhanced collisional ionization method for direct radionuclide measurements that are independent of radioactive decay. The technique uses two nitrogen-laser-pumped dye lasers to selectively excite the target isotope to an electronic state near the ionization threshold. The excited actinide atoms then undergo collisions with a buffer gas and are efficiently ionized. The resulting ions can be detected by conventional methods. The attributes of this approach include highly sensitive isotope analysis with relatively inexpensive lasers and a simple vacuum system. 9 refs., 3 figs

Low-profile high-voltage compact gas switch

International Nuclear Information System (INIS)

Goerz, D.A.; Wilson, M.J.; Speer, R.D.

1997-01-01

This paper discusses the development and testing of a low-profile, high-voltage, spark-gap switch designed to be closely coupled with other components into an integrated high-energy pulsed-power source. The switch is designed to operate at 100 kV using SF6 gas pressurized to less than 0.7 MPa. The volume of the switch cavity region is less than 1.5 cm3, and the field stress along the gas-dielectric interface is as high as 130 kV/cm. The dielectric switch body has a low profile that is only I -cm tall at its greatest extent and nominally 2-mm thick over most of its area. This design achieves a very low inductance of less than 5 nH, but results in field stresses exceeding 500 kV/cm in the dielectric material. Field modeling was done to determine the appropriate shape for the highly stressed insulator and electrodes, and special manufacturing techniques were employed to mitigate the usual mechanisms that induce breakdown and failure in solid dielectrics. Static breakdown tests verified that the switch operates satisfactorily at 100 kV levels. The unit has been characterized with different shaped electrodes having nominal gap spacings of 2.0, 2.5, and 3.0 mm. The relationship between self-break voltage and operating pressure agrees well with published data on gas properties, accounting for the field enhancements of the electrode shapes being used. Capacitor discharge tests in a low inductance test fixture exhibited peak currents up to 25 kA with characteristic frequencies of the ringdown circuit ranging from 10 to 20 MHz. The ringdown waveforms and scaling of measured parameters agree well with circuit modeling of the switch and test fixture. Repetitive operation has been demonstrated at moderate rep-rates up to 15 Hz, limited by the power supply being used. Preliminary tests to evaluate lifetime of the compact switch assembly have been encouraging. In one case, after more than 7,000 high-current ringdown tests with approximately 30 C of total charge transferred, the

Gridded ionization chamber

International Nuclear Information System (INIS)

Houston, J.M.

1977-01-01

An improved ionization chamber type x-ray detector comprises a heavy gas at high pressure disposed between an anode and a cathode. An open grid structure is disposed adjacent the anode and is maintained at a voltsge intermediate between the cathode and anode potentials. The electric field which is produced by positive ions drifting toward the cathode is thus shielded from the anode. Current measuring circuits connected to the anode are, therefore, responsive only to electron current flow within the chamber and the recovery time of the chamber is shortened. The grid structure also serves to shield the anode from electrical currents which might otherwise be induced by mechanical vibrations in the ionization chamber structure

Distribution and Kinematics of Ionized Gas in the central 500pc of Seyfert Galaxies

Science.gov (United States)

Hyland, Ella; Hicks, Erin K. S.; Kade, Kiana

2018-06-01

We have characterized the spatial distribution and kinematics of the ionized hydrogen gas in a sample of 40 Seyfert galaxies as part of the KONA (Keck OSIRIS Nearby AGN) survey. An analysis of the narrow Brackett Gamma emission (2.16 microns) in the central 500 pc of these local AGN will be presented. Measurements include the azimuthal averages of the flux distribution, velocity dispersion, and emission line equivalent width. In addition, the excitation of the Brackett Gamma emission is considered using the ratio of its flux with that of molecular hydrogen (2.12 microns) as a diagnostic. A comparison of the circumnuclear narrow Brackett Gamma emission characteristics in the Seyfert type 1 and type 2 subsamples will also be presented.

The Effect of Pericellular Oxygen Levels on Proteomic Profile and Lipogenesis in 3T3-L1 Differentiated Preadipocytes Cultured on Gas-Permeable Cultureware.

Directory of Open Access Journals (Sweden)

Martin Weiszenstein

Full Text Available Pericellular oxygen concentration represents an important factor in the regulation of cell functions, including cell differentiation, growth and mitochondrial energy metabolism. Hypoxia in adipose tissue has been associated with altered adipokine secretion profile and suggested as a possible factor in the development of type 2 diabetes. In vitro experiments provide an indispensable tool in metabolic research, however, physical laws of gas diffusion make prolonged exposure of adherent cells to desired pericellular O2 concentrations questionable. The aim of this study was to investigate the direct effect of various O2 levels (1%, 4% and 20% O2 on the proteomic profile and triglyceride accumulation in 3T3-L1 differentiated preadipocytes using gas-permeable cultureware. Following differentiation of cells under desired pericellular O2 concentrations, cell lysates were subjected to two-dimensional gel electrophoresis and protein visualization using Coomassie blue staining. Spots showing differential expression under hypoxia were analyzed using matrix-assisted laser desorption/ionization mass spectrometry. All identified proteins were subjected to pathway analysis. We observed that protein expression of 26 spots was reproducibly affected by 4% and 1% O2 (17 upregulated and 9 downregulated. Pathway analysis showed that mitochondrial energy metabolism and triglyceride synthesis were significantly upregulated by hypoxia. In conclusion, this study demonstrated the direct effects of pericellular O2 levels on adipocyte energy metabolism and triglyceride synthesis, probably mediated through the reversed tricarboxylic acid cycle flux.

Possible ionization ''ignition'' in laser-driven clusters

International Nuclear Information System (INIS)

Rose-Petruck, C.; Schafer, K.J.; Barty, C.P.J.

1995-01-01

The authors use Classical Trajectory Monte Carlo (CTMC) simulations to study the ionization of small rare gas clusters in short pulse, high intensity laser fields. They calculate, for a cluster of 25 neon atoms, the ionization stage reached and the average kinetic energy of the ionized electrons as functions of time and peak laser intensity. The CTMC calculations mimic the results of the much simpler barrier suppression model in the limit of isolated atoms. At solid density the results give much more ionization in the cluster than that predicted by the barrier suppression model. They find that when the laser intensity reaches a threshold value such that on average one electron is ionized from each atom, the cluster atoms rapidly move to higher ionization stages, approaching Ne +8 in a few femtoseconds. This ignition process creates an ultrafast pulse of energetic electrons in the cluster at quite modest laser intensities

On possible structures of normal ionizing shock waves in electromagnetic shock tubes

International Nuclear Information System (INIS)

Liberman, M.A.; Synakh, V.S.; Zakajdakhov, V.V.; Velikovich, A.L.

1982-01-01

The problem of possible structures of normal ionizing shock waves is studied. On the basis of the general theory of ionizing shock waves in magnetic fields, a similarity solution of the piston problem for an impenetrable piston and a magnetic piston is described and a numerical solution of the non-stationary piston problem is obtained. It is shown that precursor photo-ionization of the neutral gas by the radiation of the shock-heated gas is the dominant factor in shaping normal ionizing shock structures. In particular, it is shown that the strong overheating of atoms and ions in shock fronts is due to the tensor form of Ohm's law in the precursor region. (author)

Dust trap formation in a non-self-sustained discharge with external gas ionization

International Nuclear Information System (INIS)

Filippov, A. V.; Babichev, V. N.; Pal’, A. F.; Starostin, A. N.; Cherkovets, V. E.; Rerikh, V. K.; Taran, M. D.

2015-01-01

Results from numerical studies of a non-self-sustained gas discharge containing micrometer dust grains are presented. The non-self-sustained discharge (NSSD) was controlled by a stationary fast electron beam. The numerical model of an NSSD is based on the diffusion drift approximation for electrons and ions and self-consistently takes into account the influence of the dust component on the electron and ion densities. The dust component is described by the balance equation for the number of dust grains and the equation of motion for dust grains with allowance for the Stokes force, gravity force, and electric force in the cathode sheath. The interaction between dust grains is described in the self-consistent field approximation. The height of dust grain levitation over the cathode is determined and compared with experimental results. It is established that, at a given gas ionization rate and given applied voltage, there is a critical dust grain size above which the levitation condition in the cathode sheath cannot be satisfied. Simulations performed for the dust component consisting of dust grains of two different sizes shows that such grains levitate at different heights, i.e., size separation of dust drains levitating in the cathode sheath of an NSSD takes place

Dust trap formation in a non-self-sustained discharge with external gas ionization

Energy Technology Data Exchange (ETDEWEB)

Filippov, A. V., E-mail: fav@triniti.ru; Babichev, V. N.; Pal’, A. F.; Starostin, A. N.; Cherkovets, V. E.; Rerikh, V. K.; Taran, M. D. [Troitsk Institute for Innovation and Fusion Research (Russian Federation)

2015-11-15

Results from numerical studies of a non-self-sustained gas discharge containing micrometer dust grains are presented. The non-self-sustained discharge (NSSD) was controlled by a stationary fast electron beam. The numerical model of an NSSD is based on the diffusion drift approximation for electrons and ions and self-consistently takes into account the influence of the dust component on the electron and ion densities. The dust component is described by the balance equation for the number of dust grains and the equation of motion for dust grains with allowance for the Stokes force, gravity force, and electric force in the cathode sheath. The interaction between dust grains is described in the self-consistent field approximation. The height of dust grain levitation over the cathode is determined and compared with experimental results. It is established that, at a given gas ionization rate and given applied voltage, there is a critical dust grain size above which the levitation condition in the cathode sheath cannot be satisfied. Simulations performed for the dust component consisting of dust grains of two different sizes shows that such grains levitate at different heights, i.e., size separation of dust drains levitating in the cathode sheath of an NSSD takes place.

Sensitivity of hot-cathode ionization vacuum gages in several gases

Science.gov (United States)

Holanda, R.

1972-01-01

Four hot-cathode ionization vacuum gages were calibrated in 12 gases. The relative sensitivities of these gages were compared to several gas properties. Ionization cross section was the physical property which correlated best with gage sensitivity. The effects of gage accelerating voltage and ionization-cross-section energy level were analyzed. Recommendations for predicting gage sensitivity according to gage type were made.

Gas composition of sludge residue profiles in a sludge treatment reed bed between loadings

DEFF Research Database (Denmark)

Larsen, Julie Dam; Nielsen, Steen M; Scheutz, Charlotte

2017-01-01

Treatment of sludge in sludge treatment reed bed systems includes dewatering and mineralization. The mineralization process, which is driven by microorganisms, produces different gas species as by-products. The pore space composition of the gas species provides useful information on the biological...... processes occurring in the sludge residue. In this study, we measured the change in composition of gas species in the pore space at different depth levels in vertical sludge residue profiles during a resting period of 32 days. The gas composition of the pore space in the sludge residue changed during...

MicroRNA expression profiles in human cancer cells after ionizing radiation

International Nuclear Information System (INIS)

Niemoeller, Olivier M; Niyazi, Maximilian; Corradini, Stefanie; Zehentmayr, Franz; Li, Minglun; Lauber, Kirsten; Belka, Claus

2011-01-01

MicroRNAs are regulators of central cellular processes and are implicated in the pathogenesis and prognosis of human cancers. MicroRNAs also modulate responses to anti-cancer therapy. In the context of radiation oncology microRNAs were found to modulate cell death and proliferation after irradiation. However, changes in microRNA expression profiles in response to irradiation have not been comprehensively analyzed so far. The present study's intend is to present a broad screen of changes in microRNA expression following irradiation of different malignant cell lines. 1100 microRNAs (Sanger miRBase release version 14.0) were analyzed in six malignant cell lines following irradiation with clinically relevant doses of 2.0 Gy. MicroRNA levels 6 hours after irradiation were compared to microRNA levels in non-irradiated cells using the 'Geniom Biochip MPEA homo sapiens'. Hierarchical clustering analysis revealed a pattern, which significantly (p = 0.014) discerned irradiated from non-irradiated cells. The expression levels of a number of microRNAs known to be involved in the regulation of cellular processes like apoptosis, proliferation, invasion, local immune response and radioresistance (e. g. miR-1285, miR-24-1, miR-151-5p, let-7i) displayed 2 - 3-fold changes after irradiation. Moreover, several microRNAs previously not known to be radiation-responsive were discovered. Ionizing radiation induced significant changes in microRNA expression profiles in 3 glioma and 3 squamous cell carcinoma cell lines. The functional relevance of these changes is not addressed but should by analyzed by future work especially focusing on clinically relevant endpoints like radiation induced cell death, proliferation, migration and metastasis

Simulations of Hall reconnection in partially ionized plasmas

Science.gov (United States)

Innocenti, Maria Elena; Jiang, Wei; Lapenta, Giovanni

2017-04-01

Magnetic reconnection occurs in the Hall, partially ionized regime in environments as diverse as molecular clouds, protostellar disks and regions of the solar chromosphere. While much is known about Hall reconnection in fully ionized plasmas, Hall reconnection in partially ionized plasmas is, in comparison, still relatively unexplored. This notwithstanding the fact that partial ionization is expected to affect fundamental processes in reconnection such as the transition from the slow, fluid to the fast, kinetic regime, the value of the reconnection rate and the dimensions of the diffusion regions [Malyshkin and Zweibel 2011 , Zweibel et al. 2011]. We present here the first, to our knowledge, fully kinetic simulations of Hall reconnection in partially ionized plasmas. The interaction of electrons and ions with the neutral background is realistically modelled via a Monte Carlo plug-in coded into the semi-implicit, fully kinetic code iPic3D [Markidis 2010]. We simulate a plasma with parameters compatible with the MRX experiments illustrated in Zweibel et al. 2011 and Lawrence et al. 2013, to be able to compare our simulation results with actual experiments. The gas and ion temperature is T=3 eV, the ion to electron temperature ratio is Tr=0.44, ion and electron thermal velocities are calculated accordingly resorting to a reduced mass ratio and a reduced value of the speed of light to reduce the computational costs of the simulations. The initial density of the plasma is set at n= 1.1 1014 cm-3 and is then left free to change during the simulation as a result of gas-plasma interaction. A set of simulations with initial ionisation percentage IP= 0.01, 0.1, 0.2, 0.6 is presented and compared with a reference simulation where no background gas is present (full ionization). In this first set of simulations, we assume to be able to externally control the initial relative densities of gas and plasma. Within this parameter range, the ion but not the electron population is

A Comparison of Thermal Models for Temperature Profiles in Gas-Lift Wells

Directory of Open Access Journals (Sweden)

Langfeng Mu

2018-02-01

Full Text Available Gas lift is a simple, reliable artificial lift method which is frequently used in offshore oil field developments. In order to enhance the efficiency of production by gas lift, it is vital to exactly predict the distribution of temperature-field for fluid within the wellbore. A new mechanistic model is developed for computing flowing fluid temperature profiles in both conduits simultaneously for a continuous-flow gas-lift operation. This model assumes steady heat transfer in the formation, as well as steady heat transfer in the conduits. A micro-units discrete from the wellbore, whose heat transfer process is analyzed and whose heat transfer equation is set up according to the law of conservation of energy. A simplified algebraic solution to our model is conducted to analyze the temperature profile. Sensitivity analysis was conducted with the new model. The results indicate that mass flow rate of oil and the tubing overall heat transfer coefficient are the main factors that influence the temperature distribution inside the tubing and that the mass flow rate of oil is the main factor affecting temperature distribution in the annulus. Finally, the new model was tested in three various wells and compared with other models. The results showed that the new model is more accurate and provides significant references for temperature prediction in gas lift well.

ANALYSIS AND IDENTIFICATION SPIKING CHEMICAL COMPOUNDS RELATED TO CHEMICAL WEAPON CONVENTION IN UNKNOWN WATER SAMPLES USING GAS CHROMATOGRAPHY AND GAS CHROMATOGRAPHY ELECTRON IONIZATION MASS SPECTROMETRY

Directory of Open Access Journals (Sweden)

Harry Budiman

2010-06-01

Full Text Available The identification and analysis of chemical warfare agents and their degradation products is one of important component for the implementation of the convention. Nowadays, the analytical method for determination chemical warfare agent and their degradation products has been developing and improving. In order to get the sufficient analytical data as recommended by OPCW especially in Proficiency Testing, the spiking chemical compounds related to Chemical Weapon Convention in unknown water sample were determined using two different techniques such as gas chromatography and gas chromatography electron-impact ionization mass spectrometry. Neutral organic extraction, pH 11 organic extraction, cation exchanged-methylation, triethylamine/methanol-silylation were performed to extract the chemical warfare agents from the sample, before analyzing with gas chromatography. The identification of chemical warfare agents was carried out by comparing the mass spectrum of chemicals with mass spectrum reference from the OPCW Central Analytical Database (OCAD library while the retention indices calculation obtained from gas chromatography analysis was used to get the confirmation and supported data of  the chemical warfare agents. Diisopropyl methylphosphonate, 2,2-diphenyl-2-hydroacetic acid and 3-quinuclidinol were found in unknown water sample. Those chemicals were classified in schedule 2 as precursor or reactant of chemical weapons compound in schedule list of Chemical Weapon Convention.   Keywords: gas chromatography, mass spectrometry, retention indices, OCAD library, chemical warfare agents

LPWA using supersonic gas jet with tailored density profile

Science.gov (United States)

Kononenko, O.; Bohlen, S.; Dale, J.; D'Arcy, R.; Dinter, M.; Erbe, J. H.; Indorf, G.; di Lucchio, L.; Goldberg, L.; Gruse, J. N.; Karstensen, S.; Libov, V.; Ludwig, K.; Martinez de La Ossa, A.; Marutzky, F.; Niroula, A.; Osterhoff, J.; Quast, M.; Schaper, L.; Schwinkendorf, J.-P.; Streeter, M.; Tauscher, G.; Weichert, S.; Palmer, C.; Horbatiuk, Taras

2016-10-01

Laser driven plasma wakefield accelerators have been explored as a potential compact, reproducible source of relativistic electron bunches, utilising an electric field of many GV/m. Control over injection of electrons into the wakefield is of crucial importance in producing stable, mono-energetic electron bunches. Density tailoring of the target, to control the acceleration process, can also be used to improve the quality of the bunch. By using gas jets to provide tailored targets it is possible to provide good access for plasma diagnostics while also producing sharp density gradients for density down-ramp injection. OpenFOAM hydrodynamic simulations were used to investigate the possibility of producing tailored density targets in a supersonic gas jet. Particle-in-cell simulations of the resulting density profiles modelled the effect of the tailored density on the properties of the accelerated electron bunch. Here, we present the simulation results together with preliminary experimental measurements of electron and x-ray properties from LPWA experiments using gas jet targets and a 25 TW, 25 fs Ti:Sa laser system at DESY.

Fundamentals of Biomolecule Analysis by Electrospray Ionization Mass Spectrometry

Science.gov (United States)

Weinecke, Andrea; Ryzhov, Victor

2005-01-01

Electrospray ionization (ESI) is a soft ionization technique that allows transfer of fragile biomolecules directly from solution into the gas phase. An instrumental analysis laboratory experiment is designed that would introduce the students to the ESI technique, major parameters of the ion trap mass spectrometers and some caveats in…

Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): review.

Science.gov (United States)

Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J

2015-09-03

Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a "soft" ion source for preserving highly diagnostic molecular ion is desirable, as compared to the "hard" ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. Copyright © 2015. Published by Elsevier B.V.

Detection of lung cancer using plasma protein profiling by matrix-assisted laser desorption/ionization mass spectrometry.

Science.gov (United States)

Shevchenko, Valeriy E; Arnotskaya, Natalia E; Zaridze, David G

2010-01-01

There are no satisfactory plasma biomarkers which are available for the early detection and monitoring of lung cancer, one of the most frequent cancers worldwide. The aim of this study is to explore the application of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-ToF MS) to plasma proteomic patterns to distinguish lung cancer patients from healthy individuals. The EDTA plasma samples have been pre-fractionated using magnetic bead kits functionalized with weak cation exchange coatings. We compiled MS protein profiles for 90 patients with squamous cell carcinomas (SCC) and compared them with profiles from 187 healthy controls. The MALDI-ToF spectra were analyzed statistically using ClinProTools bioinformatics software. Depending on the sample used, up to 441 peaks/spectrum could be detected in a mass range of 1000-20,000 Da; 33 of these proteins had statistically differential expression levels between SCC and control plasma (P 90%) in external validation test. These results suggest that plasma MALDI-ToF MS protein profiling can distinguish patients with SCC and also from healthy individuals with relatively high sensitivity and specificity and that MALDI- ToF MS is a potential tool for the screening of lung cancer.

MEASURING PROTOPLANETARY DISK GAS SURFACE DENSITY PROFILES WITH ALMA

Energy Technology Data Exchange (ETDEWEB)

Williams, Jonathan P.; McPartland, Conor, E-mail: jpw@ifa.hawaii.edu [Institute for Astronomy, University of Hawaii at Manoa, Honolulu, HI 96822 (United States)

2016-10-10

The gas and dust are spatially segregated in protoplanetary disks due to the vertical settling and radial drift of large grains. A fuller accounting of the mass content and distribution in disks therefore requires spectral line observations. We extend the modeling approach presented in Williams and Best to show that gas surface density profiles can be measured from high fidelity {sup 13}CO integrated intensity images. We demonstrate the methodology by fitting ALMA observations of the HD 163296 disk to determine a gas mass, M {sub gas} = 0.048 M {sub ⊙}, and accretion disk characteristic size R {sub c} = 213 au and gradient γ = 0.39. The same parameters match the C{sup 18}O 2–1 image and indicate an abundance ratio [{sup 12}CO]/[C{sup 18}O] of 700 independent of radius. To test how well this methodology can be applied to future line surveys of smaller, lower mass T Tauri disks, we create a large {sup 13}CO 2–1 image library and fit simulated data. For disks with gas masses 3–10 M {sub Jup} at 150 pc, ALMA observations with a resolution of 0.″2–0.″3 and integration times of ∼20 minutes allow reliable estimates of R {sub c} to within about 10 au and γ to within about 0.2. Economic gas imaging surveys are therefore feasible and offer the opportunity to open up a new dimension for studying disk structure and its evolution toward planet formation.

Observed damage during Argon gas cluster depth profiles of compound semiconductors

Energy Technology Data Exchange (ETDEWEB)

Barlow, Anders J., E-mail: anders.barlow@ncl.ac.uk; Portoles, Jose F.; Cumpson, Peter J. [National EPSRC XPS Users' Service (NEXUS), School of Mechanical and Systems Engineering, Newcastle University, Newcastle upon Tyne NE1 7RU (United Kingdom)

2014-08-07

Argon Gas Cluster Ion Beam (GCIB) sources have become very popular in XPS and SIMS in recent years, due to the minimal chemical damage they introduce in the depth-profiling of polymer and other organic materials. These GCIB sources are therefore particularly useful for depth-profiling polymer and organic materials, but also (though more slowly) the surfaces of inorganic materials such as semiconductors, due to the lower roughness expected in cluster ion sputtering compared to that introduced by monatomic ions. We have examined experimentally a set of five compound semiconductors, cadmium telluride (CdTe), gallium arsenide (GaAs), gallium phosphide (GaP), indium arsenide (InAs), and zinc selenide (ZnSe) and a high-κ dielectric material, hafnium oxide (HfO), in their response to argon cluster profiling. An experimentally determined HfO etch rate of 0.025 nm/min (3.95 × 10{sup −2} amu/atom in ion) for 6 keV Ar gas clusters is used in the depth scale conversion for the profiles of the semiconductor materials. The assumption has been that, since the damage introduced into polymer materials is low, even though sputter yields are high, then there is little likelihood of damaging inorganic materials at all with cluster ions. This seems true in most cases; however, in this work, we report for the first time that this damage can in fact be very significant in the case of InAs, causing the formation of metallic indium that is readily visible even to the naked eye.

Ionization of EPA contaminants in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

Science.gov (United States)

Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

2015-06-01

Seventy-seven EPA priority environmental pollutants were analyzed using gas chromatography-mass spectrometry (GC-MS) equipped with an optimized atmospheric pressure photoionization (APPI) and an atmospheric pressure laser ionization (APLI) interface with and without dopants. The analyzed compounds included e.g., polycyclic aromatic hydrocarbons (PAHs), nitro compounds, halogenated compounds, aromatic compounds with phenolic, acidic, alcohol, and amino groups, phthalate and adipatic esters, and aliphatic ethers. Toluene, anisole, chlorobenzene, and acetone were tested as dopants. The widest range of analytes was ionized using direct APPI (66/77 compounds). The introduction of dopants decreased the amount of compounds ionized in APPI (e.g., 54/77 with toluene), but in many cases the ionization efficiency increased. While in direct APPI the formation of molecular ions via photoionization was the main ionization reaction, dopant-assisted (DA) APPI promoted ionization reactions, such as charge exchange and proton transfer. Direct APLI ionized a much smaller amount of compounds than APPI (41/77 compounds), showing selectivity towards compounds with low ionization energies (IEs) and long-lived resonantly excited intermediate states. DA-APLI, however, was able to ionize a higher amount of compounds (e.g. 51/77 with toluene), as the ionization took place entirely through dopant-assisted ion/molecule reactions similar to those in DA-APPI. Best ionization efficiency in APPI and APLI (both direct and DA) was obtained for PAHs and aromatics with O- and N-functionalities, whereas nitro compounds and aliphatic ethers were the most difficult to ionize. Halogenated aromatics and esters were (mainly) ionized in APPI, but not in APLI.

Meter or profile. Exact and undisputed consumption data indispensable to the free gas market

International Nuclear Information System (INIS)

Ter Horst, G.J.P.; Fransen, T.

2000-01-01

Before larger gas consumers can start choosing different suppliers, these suppliers and the system operator should first know exactly how much gas their clients are using at each hour of the day. Expensive measuring units on site are one way to accomplish this, but consumption profiles agreed on by all parties involved might be a cheaper alternative

Emission profiles of K-He exciplexes in cold helium gas

International Nuclear Information System (INIS)

Allard, N F

2012-01-01

Emission spectra of exciplexes composed of a light alkali atom in the first excited state and 4 He atoms have been observed in cryogenic gas in the spectral range from the atomic D lines to 6300 cm −1 . A unified semi-classical theory of line broadening has been used to determine the total profile from the center to the far wings of emission profiles of potassium perturbed by helium at low temperatures and high He density. The agreement of the theoretical peak positions of K*He n exciplexes compared to the experimental determinations is fairly good. Such comparisons provide a critical test of the calculated molecular potentials and the relevance of the theoretical approach which has been used.

Characterization of some Jordanian oil shales by pyrolysis gas chromatography

International Nuclear Information System (INIS)

Jaradat, Q. M.

1995-01-01

Gas chromatography with flame ionization detector (GC-FID) was used to study pyrolysis of some Jordanian oil shale samples. Three sampls of different altitudes from El-Lajjun were studied. Pyrograms of solid sampls were studied at different temperature profiles. Solid-liquid extraction with water, methanol, or hexane allowed extraction of organics of different polarity. Hexane showed the highest extraction efficiency. Reproducibility of the pyrograms of the solid sample was evalualted. Relative standard deviation was 7.56%. (author). 7 refs., 8 figs

NON-EQUILIBRIUM HELIUM IONIZATION IN AN MHD SIMULATION OF THE SOLAR ATMOSPHERE

International Nuclear Information System (INIS)

Golding, Thomas Peter; Carlsson, Mats; Leenaarts, Jorrit

2016-01-01

The ionization state of the gas in the dynamic solar chromosphere can depart strongly from the instantaneous statistical equilibrium commonly assumed in numerical modeling. We improve on earlier simulations of the solar atmosphere that only included non-equilibrium hydrogen ionization by performing a 2D radiation-magnetohydrodynamics simulation featuring non-equilibrium ionization of both hydrogen and helium. The simulation includes the effect of hydrogen Lyα and the EUV radiation from the corona on the ionization and heating of the atmosphere. Details on code implementation are given. We obtain helium ion fractions that are far from their equilibrium values. Comparison with models with local thermodynamic equilibrium (LTE) ionization shows that non-equilibrium helium ionization leads to higher temperatures in wavefronts and lower temperatures in the gas between shocks. Assuming LTE ionization results in a thermostat-like behavior with matter accumulating around the temperatures where the LTE ionization fractions change rapidly. Comparison of DEM curves computed from our models shows that non-equilibrium ionization leads to more radiating material in the temperature range 11–18 kK, compared to models with LTE helium ionization. We conclude that non-equilibrium helium ionization is important for the dynamics and thermal structure of the upper chromosphere and transition region. It might also help resolve the problem that intensities of chromospheric lines computed from current models are smaller than those observed

Quasar Black Hole Mass Estimates from High-Ionization Lines: Breaking a Taboo?

Directory of Open Access Journals (Sweden)

Paola Marziani

2017-09-01

Full Text Available Can high ionization lines such as CIV λ 1549 provide useful virial broadening estimators for computing the mass of the supermassive black holes that power the quasar phenomenon? The question has been dismissed by several workers as a rhetorical one because blue-shifted, non-virial emission associated with gas outflows is often prominent in CIV λ 1549 line profiles. In this contribution, we first summarize the evidence suggesting that the FWHM of low-ionization lines like H β and MgII λ 2800 provide reliable virial broadening estimators over a broad range of luminosity. We confirm that the line widths of CIV λ 1549 is not immediately offering a virial broadening estimator equivalent to the width of low-ionization lines. However, capitalizing on the results of Coatman et al. (2016 and Sulentic et al. (2017, we suggest a correction to FWHM CIV λ 1549 for Eddington ratio and luminosity effects that, however, remains cumbersome to apply in practice. Intermediate ionization lines (IP ∼ 20–30 eV; AlIII λ 1860 and SiIII] λ 1892 may provide a better virial broadening estimator for high redshift quasars, but larger samples are needed to assess their reliability. Ultimately, they may be associated with the broad-line region radius estimated from the photoionization method introduced by Negrete et al. (2013 to obtain black hole mass estimates independent from scaling laws.

MICROWAVE INTERACTIONS WITH INHOMOGENEOUS PARTIALLY IONIZED PLASMA

Energy Technology Data Exchange (ETDEWEB)

Kritz, A. H.

1962-11-15

Microwave interactions with inhomogeneous plasmas are often studied by employing a simplified electromagnetic approach, i.e., by representing the effects of the plasma by an effective dielectric coefficient. The problems and approximations associated with this procedure are discussed. The equation describing the microwave field in an inhomogeneous partially ionized plasma is derived, and the method that is applied to obtain the reflected, transmitted, and absorbed intensities in inhomogeneous plasmas is presented. The interactions of microwaves with plasmas having Gaussian electron density profiles are considered. The variation of collision frequency with position is usually neglected. In general, the assumption of constant collision frequency is not justified; e.g., for a highly ionized plasma, the electron density profile determines, in part, the profile of the electron-ion collision frequency. The effect of the variation of the collision frequency profile on the interaction of microwaves with inhomogeneous plasmas is studied in order to obtain an estimate of the degree of error that may result when constant collision frequency is assumed instead of a more realistic collision frequency profile. It is shown that the degree of error is of particular importance when microwave analysis is used as a plasma diagnostic. (auth)

Ionizing device comprising a microchannel electron multiplier with secondary electron emission

International Nuclear Information System (INIS)

Chalmeton, Vincent.

1974-01-01

The present invention relates to a ionizing device comprising a microchannel electron multiplier involving secondary electron emission as a means of ionization. A system of electrodes is used to accelerate said electrons, ionize the gas and extract the ions from thus created plasma. Said ionizer is suitable for bombarding the target in neutron sources (target of the type of nickel molybdenum coated with tritiated titanium or with a tritium deuterium mixture) [fr

CIFOG: Cosmological Ionization Fields frOm Galaxies

Science.gov (United States)

Hutter, Anne

2018-03-01

CIFOG is a versatile MPI-parallelised semi-numerical tool to perform simulations of the Epoch of Reionization. From a set of evolving cosmological gas density and ionizing emissivity fields, it computes the time and spatially dependent ionization of neutral hydrogen (HI), neutral (HeI) and singly ionized helium (HeII) in the intergalactic medium (IGM). The code accounts for HII, HeII, HeIII recombinations, and provides different descriptions for the photoionization rate that are used to calculate the residual HI fraction in ionized regions. This tool has been designed to be coupled to semi-analytic galaxy formation models or hydrodynamical simulations. The modular fashion of the code allows the user to easily introduce new descriptions for recombinations and the photoionization rate.

Analysis of benzene, toluene, ethylbenzene and xylenes in soils by headspace and gas chromatography/flame ionization detector

Directory of Open Access Journals (Sweden)

Jurandir Pereira Pinto

2006-02-01

Full Text Available The constituents of gasoline: benzene, toluene, ethylbenzene and xylenes (BTEX are frequently found in soils due to leaks in fuel storage tanks and they present chronic toxicity. In this work it was developed and validated a methodology of BTEX analysis in soil by gas chromatography/ flame ionization detector and static headspace. The recovery of BTEX in soil samples was evaluated using soils with different textures (sandy and loamy. The analysis method showed good resolution, in a low time of analysis (less than 30 minutes. Limits of quantification of 0.05 mg Kg¯¹ soil for benzene, toluene, ethylbenzene and xylenes are below the guiding values that range from 0.15 to 95 mg Kg¯¹ soil, established to determine soil quality. It was verified that the methodology enables the use of this method for BTEX analysis of soil samples for passive environmental identification of gas stations.

Ionizing and non-ionizing radiations

International Nuclear Information System (INIS)

1994-01-01

The monograph is a small manual to get a knowledge of ionizing and non-ionizing radiations. The main chapters are: - Electromagnetic radiations - Ionizing and non-ionizing radiations - Non-ionizing electromagnetic radiations - Ionizing electromagnetic radiation - Other ionizing radiations - Ionizing radiation effects - The Nuclear Safety Conseil

Modeling of gas flow and deposition profile in HWCVD processes

Energy Technology Data Exchange (ETDEWEB)

Pflug, Andreas; Höfer, Markus; Harig, Tino; Armgardt, Markus; Britze, Chris; Siemers, Michael; Melzig, Thomas; Schäfer, Lothar

2015-11-30

Hot wire chemical vapor deposition (HWCVD) is a powerful technology for deposition of high quality films on large area, where drawbacks of plasma based technology such as defect generation by ion bombardment and high equipment costs are omitted. While processes for diamond coatings using H{sub 2} and CH{sub 4} as precursor have been investigated in detail since 1990 and have been transferred to industry, research also focuses on silicon based coatings with H{sub 2}, SiH{sub 4} and NH{sub 3} as process gases. HWCVD of silicon based coatings is a promising alternative for state-of-the-art radiofrequency-plasma enhanced chemical vapor deposition reactors. The film formation in HWCVD results from an interaction of several concurrent chemical reactions such as gas phase chemistry, film deposition, abstraction of surplus hydrogen bonds and etching by atomic hydrogen. Since there is no easy relation between process parameters and resulting deposition profiles, substantial experimental effort is required to optimize the process for a given film specification and the desired film uniformity. In order to obtain a deeper understanding of the underlying mechanisms and to enable an efficient way of process optimization, simulation methods come into play. While diamond deposition occurs at pressures in the range of several kPa HWCVD deposition of Si based coatings operates at pressures in the 0.1–30 Pa range. In this pressure regime, particle based simulation methods focused on solving the Boltzmann equation are computationally feasible. In comparison to computational fluid dynamics this yields improved accuracy even near small gaps or orifices, where characteristic geometric dimensions approach the order of the mean free path of gas molecules. At Fraunhofer IST, a parallel implementation of the Direct Simulation Monte Carlo (DSMC) method extended by a reactive wall chemistry model is developed. To demonstrate the feasibility of three-dimensional simulation of HWCVD processes

Ionization impact on molecular clouds and star formation: Numerical simulations and observations

International Nuclear Information System (INIS)

Tremblin, Pascal

2012-01-01

At all the scales of Astrophysics, the impact of the ionization from massive stars is a crucial issue. At the galactic scale, the ionization can regulate star formation by supporting molecular clouds against gravitational collapse and at the stellar scale, indications point toward a possible birth place of the Solar System close to massive stars. At the molecular cloud scale, it is clear that the hot ionized gas compresses the surrounding cold gas, leading to the formation of pillars, globules, and shells of dense gas in which some young stellar objects are observed. What are the formation mechanisms of these structures? Are the formation of these young stellar objects triggered or would have they formed anyway? Do massive stars have an impact on the distribution of the surrounding gas? Do they have an impact on the mass distribution of stars (the initial mass function, IMF)? This thesis aims at shedding some light on these questions, by focusing especially on the formation of the structures between the cold and the ionized gas. We present the state of the art of the theoretical and observational works on ionized regions (H II regions) and we introduce the numerical tools that have been developed to model the ionization in the hydrodynamic simulations with turbulence performed with the HERACLES code. Thanks to the simulations, we present a new model for the formation of pillars based on the curvature and collapse of the dense shell on itself and a new model for the formations of cometary globules based on the turbulence of the cold gas. Several diagnostics have been developed to test these new models in the observations. If pillars are formed by the collapse of the dense shell on itself, the velocity spectrum of a nascent pillar presents a large spectra with a red-shifted and a blue-shifted components that are caused by the foreground and background parts of the shell that collapse along the line of sight. If cometary globules emerge because of the turbulence of

Gas Flows in Dual Active Galactic Nuclei

Science.gov (United States)

Mueller Sanchez, Francisco; Comerford, Julia M.; Davies, Richard; Treister, Ezequiel; Privon, George C.; Nevin, Becky

2018-06-01

Dual Active Galactic Nuclei (AGN) are the Rosetta stone to understand the role of galaxy mergers in triggering nuclear activity and regulating black hole (BH) and galaxy growth. But very little is known about the physical processes required to effectively trigger AGN activity and regulate the growth of the two BHs. The work I will present here characterizes for the first time the properties of the stars, gas (molecular, ionized, and highly-ionized) and dust in all the confirmed dual AGN at z prototypical merger system NGC 6240: vigorous star formation, two AGNs, outflowing winds of ionized gas, rippling dust and gas lanes, and tidal tails. In this galaxy, we observe for the first time a dual outflow of different species of gas: an AGN-driven outflow of highly-ionized gas to the northeast and a starburst-driven outflow of ionized hydrogen to the northwest. This shows that stellar feedback and supermassive black hole feedback can work in tandem to regulate the stellar growth of a galaxy after a merger event. These results open a new door to studies of dual AGN and AGN pairs in general, and enable dual AGN to be used, for the first time, for studies of galaxy evolution.

Ionization chamber for monitoring radioactive gas

International Nuclear Information System (INIS)

Kotrappa, P.; Dempsey, J.

1992-01-01

This present invention provides simple, effective and accurate cumulative measurement of radioactive gas over a time period. Measurements of radioactive gas are important for many purposes. Tritium concentrations in potentially exposed workers are measured, for example, with periodic urine specimens. Carbon-14 serves as a useful research tool for monitoring the progress of many chemical and biological reactions and interactions. For example, many microorganisms break down carbon-14 containing compounds in sugar to produce carbon-14 dioxide gas which can be collected and measured to determine various characteristics of the microorganisms. Both tritium and carbon-14 dioxide produce low energy radiation which cannot be easily measured by conventional radioactivity detectors. (author). 4 figs

Ionization chamber for monitoring radioactive gas

Energy Technology Data Exchange (ETDEWEB)

Kotrappa, P; Dempsey, J

1992-09-22

This present invention provides simple, effective and accurate cumulative measurement of radioactive gas over a time period. Measurements of radioactive gas are important for many purposes. Tritium concentrations in potentially exposed workers are measured, for example, with periodic urine specimens. Carbon-14 serves as a useful research tool for monitoring the progress of many chemical and biological reactions and interactions. For example, many microorganisms break down carbon-14 containing compounds in sugar to produce carbon-14 dioxide gas which can be collected and measured to determine various characteristics of the microorganisms. Both tritium and carbon-14 dioxide produce low energy radiation which cannot be easily measured by conventional radioactivity detectors. (author). 4 figs.

Ionization chamber circuit arrangement for counterbalancing long-term aging processes

International Nuclear Information System (INIS)

Fischer, H.; Goeldner, R.; Grosse, H.J.; Reinhardt, K.

1985-01-01

The described circuit arrangement changes the amplification of the output signal during the lifetime of the ionization chamber in such a way that the sensitivity of the detector becomes independent of the decreasing activity of the radiation source. It is suitable for ionization flue gas detectors

Determination of low specific activity iodine-129 off-gas concentrations by GC separation and negative ionization mass spectrometry

International Nuclear Information System (INIS)

Fernandez, S.J.; Rankin, R.A.; McManus, G.J.; Nielsen, R.A.; Delmore, J.E.; Hohorst, F.A.; Murphy, L.P.

1983-09-01

This document is the final report of the laboratory development of a method for determining the specific activity of the 129 I emitted from a nuclear fuel reprocessing plant. The technique includes cryogenic sample collection, chemical form separation, quantitation by gas chromatography, and specific activity measurement of each chemical species by negative ionization mass spectrometry. The major conclusions were that both organic and elemental iodine can be quantitatively collected without fractionation and that specific activity measurements as low as one atom of 129 I per 10 5 atoms of 127 I are possible

Metal enrichment of the neutral gas of blue compact dwarf galaxies: the compelling case of Pox 36

Science.gov (United States)

Lebouteiller, V.; Kunth, D.; Thuan, T. X.; Désert, J. M.

2009-02-01

Context: Evidence has grown over the past few years that the neutral phase of blue compact dwarf (BCD) galaxies may be metal-deficient as compared to the ionized gas of their H ii regions. These results have strong implications for our understanding of the chemical evolution of galaxies, and it is essential to strengthen the method, as well as to find possible explanations. Aims: We present the analysis of the interstellar spectrum of Pox 36 with the Far Ultraviolet Spectroscopic Explorer (FUSE). Pox 36 was selected because of the relatively low foreground gas content that makes it possible to detect absorption-lines weak enough that unseen components should not be saturated. Methods: Interstellar lines of H i, N i, O i, Si ii, P ii, Ar i, and Fe ii are detected. Column densities are derived directly from the observed line profiles except for H i, whose lines are contaminated by stellar absorption, thus needing the stellar continuum to be removed. We used the TLUSTY models to remove the stellar continuum and isolate the interstellar component. The best fit indicates that the dominant stellar population is B0. The observed far-UV flux agrees with an equivalent number of ~300 B0 stars. The fit of the interstellar H i line gives a column density of 1020.3±0.4 cm-2. Chemical abundances were then computed from the column densities using the dominant ionization stage in the neutral gas. Our abundances are compared to those measured from emission-line spectra in the optical, probing the ionized gas of the H ii regions. Results: Our results suggest that the neutral gas of Pox 36 is metal-deficient by a factor ~7 as compared to the ionized gas, and they agree with a metallicity of ≈1/35 Z_⊙. Elemental depletion is not problematic because of the low dust content along the selected lines of sight. In contrast, the ionized gas shows a clear depletion pattern, with iron being strongly depleted. Conclusions: The abundance discontinuity between the neutral and ionized phases

Tomographic scanning apparatus with ionization detector means

International Nuclear Information System (INIS)

1981-01-01

This patent specification describes a tomographic scanning apparatus using a fan beam and digital output signal. Particular reference is made to the gas-pressurized ionization detector chamber, consisting of an array of side-by-side elongate ionization detection cells, the principal axis of each of the said cells being oriented along a radius extending towards the radiation source, and connection means for applying potentials across the cells for taking their output signals. (U.K.)

THE PHOTOMETRIC AND KINEMATIC STRUCTURE OF FACE-ON DISK GALAXIES. II. INTEGRATED LINE PROFILE CHARACTERIZATION AND THE ORIGIN OF LINE PROFILE ASYMMETRY

International Nuclear Information System (INIS)

Andersen, David R.; Bershady, Matthew A.

2009-01-01

We perform a moments analysis of H I and H II global line profiles for 33 nearly face-on disk galaxies for the threefold purpose of rationalizing and interpreting line profile indices in the literature, presenting robust moment definitions with analytic error functions calibrated against Monte Carlo simulation, and probing the physical origin of line profile asymmetries. The first four profile moments serve as viable surrogates for the recession velocity, line width, asymmetry, and profile shape, respectively. The first three moments are superior, by a factor of ∼2 in precision, to related quantities defined in the literature. First and third profile moments are related; skew can be used to calculate more accurate recession velocities from global profiles. Second and fourth profile moments are linked, corresponding to the known trend that narrow (but well resolved) line widths tend to be more Gaussian. Hα kurtosis also appears correlated with the spatially resolved line width of the ionized gas. No systematics appear between various measures of line width and true rotation speed other than the wide range of normalizations, which we calibrate. This conclusion and calibration, however, is highly sample dependent. The ratio of H II to H I widths is consistent with unity, even at low projected line width. There may be a trend toward a decrease in the ratio of H II to H I widths consistent with previous studies, but we also observe greater scatter. While there is good agreement between H I and H II first, second, and fourth moments, we find no positive correlation between skew measured from H I and H II profiles. Detailed analysis of the spatially resolved Hα distribution demonstrates that H II global profile asymmetries are dominated by differences in the gas distribution, not kinematic asymmetries.

Determination of clebopride in plasma by capillary gas chromatography-negative-ion chemical ionization mass spectrometry.

Science.gov (United States)

Robinson, P R; Jones, M D; Maddock, J

1988-11-18

A procedure for the analysis of clebopride in plasma using capillary gas chromatography-negative-ion chemical ionization mass spectrometry has been developed. Employing an ethoxy analogue as internal standard, the two compounds were extracted from basified plasma using dichloromethane. Subsequent reaction with heptafluorobutyryl imidazole produced volatile monoheptafluorobutyryl derivatives whose ammonia negative-ion mass spectra proved ideal for selected-ion monitoring. The recovery of clebopride from plasma at 0.536 nmol/l was found to be 85.5 +/- 0.9% (n = 3) whilst measurement down to 0.268 nmol/l was possible with a coefficient of variation of 7.9%. Plasma levels of the compound are reported in two volunteers following ingestion of 1 mg of clebopride as the malate salt.

DWARF GALAXIES WITH IONIZING RADIATION FEEDBACK. I. ESCAPE OF IONIZING PHOTONS

International Nuclear Information System (INIS)

Kim, Ji-hoon; Krumholz, Mark R.; Goldbaum, Nathan J.; Wise, John H.; Turk, Matthew J.; Abel, Tom

2013-01-01

We describe a new method for simulating ionizing radiation and supernova feedback in the analogs of low-redshift galactic disks. In this method, which we call star-forming molecular cloud (SFMC) particles, we use a ray-tracing technique to solve the radiative transfer equation for ultraviolet photons emitted by thousands of distinct particles on the fly. Joined with high numerical resolution of 3.8 pc, the realistic description of stellar feedback helps to self-regulate star formation. This new feedback scheme also enables us to study the escape of ionizing photons from star-forming clumps and from a galaxy, and to examine the evolving environment of star-forming gas clumps. By simulating a galactic disk in a halo of 2.3 × 10 11 M ☉ , we find that the average escape fraction from all radiating sources on the spiral arms (excluding the central 2.5 kpc) fluctuates between 0.08% and 5.9% during a ∼20 Myr period with a mean value of 1.1%. The flux of escaped photons from these sources is not strongly beamed, but manifests a large opening angle of more than 60° from the galactic pole. Further, we investigate the escape fraction per SFMC particle, f esc (i), and how it evolves as the particle ages. We discover that the average escape fraction f esc is dominated by a small number of SFMC particles with high f esc (i). On average, the escape fraction from an SFMC particle rises from 0.27% at its birth to 2.1% at the end of a particle lifetime, 6 Myr. This is because SFMC particles drift away from the dense gas clumps in which they were born, and because the gas around the star-forming clumps is dispersed by ionizing radiation and supernova feedback. The framework established in this study brings deeper insight into the physics of photon escape fraction from an individual star-forming clump and from a galactic disk

The VLT/MUSE view of the central galaxy in Abell 2052. Ionized gas swept by the expanding radio source

Science.gov (United States)

Balmaverde, Barbara; Capetti, Alessandro; Marconi, Alessandro; Venturi, Giacomo

2018-04-01

We report observations of the radio galaxy 3C 317 (at z = 0.0345) located at the center of the Abell cluster A2052, obtained with the VLT/MUSE integral field spectrograph. The Chandra images of this cluster show cavities in the X-ray emitting gas, which were produced by the expansion of the radio lobes inflated by the active galactic nucleus (AGN). Our exquisite MUSE data show with unprecedented detail the complex network of line emitting filaments enshrouding the northern X-ray cavity. We do not detect any emission lines from the southern cavity, with a luminosity asymmetry between the two regions higher than 75. The emission lines produced by the warm phase of the interstellar medium (WIM) enable us to obtain unique information on the properties of the emitting gas. We find dense gas (up to 270 cm-3) that makes up part of a global quasi spherical outflow that is driven by the radio source, and obtain a direct estimate of the expansion velocity of the cavities (265 km s-1). The emission lines diagnostic rules out ionization from the AGN or from star-forming regions, suggesting instead ionization from slow shocks or from cosmic rays. The striking asymmetric line emission observed between the two cavities contrasts with the less pronounced differences between the north and south sides in the hot gas; this represents a significant new ingredient for our understanding of the process of the exchange of energy between the relativistic plasma and the external medium. We conclude that the expanding radio lobes displace the hot tenuous phase of the interstellar medium (ISM), but also impact the colder and denser ISM phases. These results show the effects of the AGN on its host and the importance of radio mode feedback. The reduced datacube is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/612/A19

Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

International Nuclear Information System (INIS)

Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J.

2015-01-01

Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): Review

Energy Technology Data Exchange (ETDEWEB)

Li, Du-Xin; Gan, Lin; Bronja, Amela [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany); Schmitz, Oliver J., E-mail: oliver.schmitz@uni-due.de [University of Duisburg-Essen, Applied Analytical Chemistry, Universitaetsstr. 5-7, 45141 Essen (Germany)

2015-09-03

Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a “soft” ion source for preserving highly diagnostic molecular ion is desirable, as compared to the “hard” ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS. - Highlights: • Atmospheric pressure ion sources (APCI, ESI, APPI, APLC etc) enable the coupling of LC-based high-end MS to GC. • APIs show advantages in selectivity and sensitivity compared with EI in GC-MS. • Accurate mass database in GC-APCI/MS is emerging as an alternative to GC-EI/MS database.

Study of gas-puff Z-pinches on COBRA

Energy Technology Data Exchange (ETDEWEB)

Qi, N.; Rosenberg, E. W.; Gourdain, P. A.; Grouchy, P. W. L. de; Kusse, B. R.; Hammer, D. A.; Bell, K. S.; Shelkovenko, T. A.; Potter, W. M.; Atoyan, L.; Cahill, A. D.; Evans, M.; Greenly, J. B.; Hoyt, C. L.; Pikuz, S. A.; Schrafel, P. C. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); Kroupp, E.; Fisher, A.; Maron, Y. [Weizmann Institute of Science, Rehovot 76100 (Israel)

2014-11-15

Gas-puff Z-pinch experiments were conducted on the 1 MA, 200 ns pulse duration Cornell Beam Research Accelerator (COBRA) pulsed power generator in order to achieve an understanding of the dynamics and instability development in the imploding and stagnating plasma. The triple-nozzle gas-puff valve, pre-ionizer, and load hardware are described. Specific diagnostics for the gas-puff experiments, including a Planar Laser Induced Fluorescence system for measuring the radial neutral density profiles along with a Laser Shearing Interferometer and Laser Wavefront Analyzer for electron density measurements, are also described. The results of a series of experiments using two annular argon (Ar) and/or neon (Ne) gas shells (puff-on-puff) with or without an on- (or near-) axis wire are presented. For all of these experiments, plenum pressures were adjusted to hold the radial mass density profile as similar as possible. Initial implosion stability studies were performed using various combinations of the heavier (Ar) and lighter (Ne) gasses. Implosions with Ne in the outer shell and Ar in the inner were more stable than the opposite arrangement. Current waveforms can be adjusted on COBRA and it was found that the particular shape of the 200 ns current pulse affected on the duration and diameter of the stagnated pinched column and the x-ray yield.

Cluster chemical ionization for improved confidence level in sample identification by gas chromatography/mass spectrometry.

Science.gov (United States)

Fialkov, Alexander B; Amirav, Aviv

2003-01-01

Upon the supersonic expansion of helium mixed with vapor from an organic solvent (e.g. methanol), various clusters of the solvent with the sample molecules can be formed. As a result of 70 eV electron ionization of these clusters, cluster chemical ionization (cluster CI) mass spectra are obtained. These spectra are characterized by the combination of EI mass spectra of vibrationally cold molecules in the supersonic molecular beam (cold EI) with CI-like appearance of abundant protonated molecules, together with satellite peaks corresponding to protonated or non-protonated clusters of sample compounds with 1-3 solvent molecules. Like CI, cluster CI preferably occurs for polar compounds with high proton affinity. However, in contrast to conventional CI, for non-polar compounds or those with reduced proton affinity the cluster CI mass spectrum converges to that of cold EI. The appearance of a protonated molecule and its solvent cluster peaks, plus the lack of protonation and cluster satellites for prominent EI fragments, enable the unambiguous identification of the molecular ion. In turn, the insertion of the proper molecular ion into the NIST library search of the cold EI mass spectra eliminates those candidates with incorrect molecular mass and thus significantly increases the confidence level in sample identification. Furthermore, molecular mass identification is of prime importance for the analysis of unknown compounds that are absent in the library. Examples are given with emphasis on the cluster CI analysis of carbamate pesticides, high explosives and unknown samples, to demonstrate the usefulness of Supersonic GC/MS (GC/MS with supersonic molecular beam) in the analysis of these thermally labile compounds. Cluster CI is shown to be a practical ionization method, due to its ease-of-use and fast instrumental conversion between EI and cluster CI, which involves the opening of only one valve located at the make-up gas path. The ease-of-use of cluster CI is analogous

Penning ionization processes studied by electron spectroscopy

International Nuclear Information System (INIS)

Yencha, A.J.

1978-01-01

The technique of measuring the kinetic energy of electrons ejected from atomic or molecular species as a result of collisional energy transfer between a metastable excited rare gas atom and an atom or molecule is known as Penning ionization spectroscopy. Like the analogous photoionization process of photoelectron spectroscopy, a considerable amount of information has been gained about the ionization potentials of numerous molecular systems. It is, in fact, through the combined analyses of photoelectron and Penning electron spectra that affords a probe of the particle-particle interactions that occur in the Penning process. In this paper a short survey of the phenomenon of Penning ionization, as studied by electron spectroscopy, will be presented as it pertains to the ionization processes of simple molecules by metastable excited atoms. (author)

Understanding deposition rate loss in high power impulse magnetron sputtering: I. Ionization-driven electric fields

International Nuclear Information System (INIS)

Brenning, N; Huo, C; Raadu, M A; Lundin, D; Helmersson, U; Vitelaru, C; Stancu, G D; Minea, T

2012-01-01

The lower deposition rate for high power impulse magnetron sputtering (HiPIMS) compared with direct current magnetron sputtering for the same average power is often reported as a drawback. The often invoked reason is back-attraction of ionized sputtered material to the target due to a substantial negative potential profile, sometimes called an extended presheath, from the location of ionization toward the cathode. Recent studies in HiPIMS devices, using floating-emitting and swept-Langmuir probes, show that such extended potential profiles do exist, and that the electric fields E z directed toward the target can be strong enough to seriously reduce ion transport to the substrate. However, they also show that the potential drops involved can vary by up to an order of magnitude from case to case. There is a clear need to understand the underlying mechanisms and identify the key discharge variables that can be used for minimizing the back-attraction. We here present a combined theoretical and experimental analysis of the problem of electric fields E z in the ionization region part of HiPIMS discharges, and their effect on the transport of ionized sputtered material. In particular, we have investigated the possibility of a ‘sweet spot’ in parameter space in which the back-attraction of ionized sputtered material is low. It is concluded that a sweet spot might possibly exist for some carefully optimized discharges, but probably in a rather narrow window of parameters. As a measure of how far a discharge is from such a window, a Townsend product Π Townsend is proposed. A parametric analysis of Π Townsend shows that the search for a sweet spot is complicated by the fact that contradictory demands appear for several of the externally controllable parameters such as high/low working gas pressure, short/long pulse length, high/low pulse power and high/low magnetic field strength. (paper)

Re-ionization of a partially ionized plasma by an Alfven wave of moderate amplitude

International Nuclear Information System (INIS)

Brennan, M.H.; Sawley, M.L.

1980-01-01

The use of forced magnetic-acoustic oscillations to investigate the effect of a torsional hydromagnetic (Alfven) wave pulse of moderate amplitude on the properties of a partially ionized afterglow helium plasma is reported. Observations of the magnetic flux associated with the oscillations, measured at a number of frequencies are used to determine radial density profiles and to provide estimates of plasma temperature. The torsional wave is shown to cause significant re-ionization of the plasma with no corresponding increase in the plasma temperature. The presence of a number of energetic particles is evidenced by the production of a significant number of doubly charged helium ions. (author)

Evaluation of a digital optical ionizing radiation particle track detector

International Nuclear Information System (INIS)

Hunter, S.R.

1987-06-01

An ionizing radiation particle track detector is outlined which can, in principle, determine the three-dimensional spatial distribution of all the secondary electrons produced by the passage of ionizing radiation through a low-pressure (0.1 to 10 kPa) gas. The electrons in the particle track are excited by the presence of a high-frequency AC electric field, and two digital cameras image the optical radiation produced in electronic excitation collisions of the surroundings gas by the electrons. The specific requirements of the detector for neutron dosimetry and microdosimetry are outlined (i.e., operating conditions of the digital cameras, high voltage fields, gas mixtures, etc.) along with an estimate of the resolution and sensitivity achievable with this technique. The proposed detector is shown to compare favorable with other methods for obtaining the details of the track structure, particularly in the quality of the information obtainable about the particle track and the comparative simplicity and adaptability of the detector for measuring the secondary electron track structure for many forms of ionizing radiation over a wide range of energies

A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

Energy Technology Data Exchange (ETDEWEB)

Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

2008-12-05

In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

H α and H β Raman scattering line profiles of the symbiotic star AG Pegasi

Science.gov (United States)

Lee, Seong-Jae; Hyung, Siek

2018-04-01

The H α and H β line profiles of the symbiotic star AG Pegasi, observed in 1998 September (phase ϕ = 10.24), display top narrow double Gaussian components and bottom broad components (FWHM = 200-400 km s-1). The photoionization model indicates that the ionized zone, responsible for the hydrogen Balmer and Lyman lines, is radiation-bounded, with a hydrogen gas number density of nH ˜ 109.85 cm-3 and a gas temperature of Te = 12 000-15 000 K. We have carried out Monte Carlo simulations to fit the Raman scattering broad wings, assuming that the hydrogen Ly β and Ly γ lines emitted within the radiation-bounded H II zone around a white dwarf have the same double Gaussian line profile shape as the hydrogen Balmer lines. The simulation shows that the scattering H I zones are attached to (or located just outside) the inner H II shells. The best fit to the observed broad H I line profiles indicates that the column density of the scattering neutral zone is NH ≃ 3-5 × 1019 cm-2. We have examined whether the geometrical structure responsible for the observed H α and H β line profiles is a bipolar conical shell structure, consisting of the radiation-bounded ionized zone and the outer material bounded neutral zone. The expanding bipolar structure might be two opposite regions of the common envelope or the outer shell of the Roche lobe around the hot white dwarf, formed through the mass inflows from the giant star and pushed out by the fast winds from the hot white dwarf.

Laser interferometry of radiation driven gas jets

Science.gov (United States)

Swanson, Kyle James; Ivanov, Vladimir; Mancini, Roberto; Mayes, Daniel C.

2017-06-01

In a series of experiments performed at the 1MA Zebra pulsed power accelerator of the Nevada Terawatt Facility nitrogen gas jets were driven with the broadband x-ray flux produced during the collapse of a wire-array z-pinch implosion. The wire arrays were comprised of 4 and 8, 10μm-thick gold wires and 17μm-thick nickel wires, 2cm and 3cm tall, and 0.3cm in diameter. They radiated 12kJ to 16kJ of x-ray energy, most of it in soft x-ray photons of less than 1keV of energy, in a time interval of 30ns. This x-ray flux was used to drive a nitrogen gas jet located at 0.8cm from the axis of the z-pinch radiation source and produced with a supersonic nozzle. The x-ray flux ionizes the nitrogen gas thus turning it into a photoionized plasma. We used laser interferometry to probe the ionization of the plasma. To this end, a Mach-Zehnder interferometer at the wavelength of 266 nm was set up to extract the atom number density profile of the gas jet just before the Zebra shot, and air-wedge interferometers at 266 and 532 nm were used to determine the electron number density of the plasma right during the Zebra shot. The ratio of electron to atom number densities gives the distribution of average ionization state of the plasma. A python code was developed to perform the image data processing, extract phase shift spatial maps, and obtain the atom and electron number densities via Abel inversion. Preliminary results from the experiment are promising and do show that a plasma has been created in the gas jet driven by the x-ray flux, thus demonstrating the feasibility of a new experimental platform to study photoionized plasmas in the laboratory. These plasmas are found in astrophysical scenarios including x-ray binaries, active galactic nuclei, and the accretion disks surrounding black holes1. This work was sponsored in part by DOE Office of Science Grant DE-SC0014451.1R. C. Mancini et al, Phys. Plasmas 16, 041001 (2009)

Numerical Study on Blast Wave Propagation Driven by Unsteady Ionization Plasma

International Nuclear Information System (INIS)

Ogino, Yousuke; Sawada, Keisuke; Ohnishi, Naofumi

2008-01-01

Understanding the dynamics of laser-produced plasma is essential for increasing the available thrust and energy conversion efficiency from a pulsed laser to a blast wave in a gas-driven laser-propulsion system. The performance of a gas-driven laser-propulsion system depends heavily on the laser-driven blast wave dynamics as well as on the ionizing and/or recombining plasma state that sustains the blast wave. In this study, we therefore develop a numerical simulation code for a laser-driven blast wave coupled with time-dependent rate equations to explore the formation of unsteady ionizing plasma produced by laser irradiation. We will also examine the various properties of blast waves and unsteady ionizing plasma for different laser input energies

Delivering Transmembrane Peptide Complexes to the Gas Phase Using Nanodiscs and Electrospray Ionization

Science.gov (United States)

Li, Jun; Richards, Michele R.; Kitova, Elena N.; Klassen, John S.

2017-10-01

The gas-phase conformations of dimers of the channel-forming membrane peptide gramicidin A (GA), produced from isobutanol or aqueous solutions of GA-containing nanodiscs (NDs), are investigated using electrospray ionization-ion mobility separation-mass spectrometry (ESI-IMS-MS) and molecular dynamics (MD) simulations. The IMS arrival times measured for (2GA + 2Na)2+ ions from isobutanol reveal three different conformations, with collision cross-sections (Ω) of 683 Å2 (conformation 1, C1), 708 Å2 (C2), and 737 Å2 (C3). The addition of NH4CH3CO2 produced (2GA + 2Na)2+ and (2GA + H + Na)2+ ions, with Ω similar to those of C1, C2, and C3, as well as (2GA + 2H)2+, (2GA + 2NH4)2+, and (2GA + H + NH4)2+ ions, which adopt a single conformation with a Ω similar to that of C2. These results suggest that the nature of the charging agents, imparted by the ESI process, can influence dimer conformation in the gas phase. Notably, the POPC NDs produced exclusively (2GA + 2NH4)2+ dimer ions; the DMPC NDs produced both (2GA + 2H)2+ and (2GA + 2NH4)2+ dimer ions. While the Ω of (2GA + 2H)2+ is similar to that of C2, the (2GA + 2NH4)2+ ions from NDs adopt a more compact structure, with a Ω of 656 Å2. It is proposed that this compact structure corresponds to the ion conducting single stranded head-to-head helical GA dimer. These findings highlight the potential of NDs, combined with ESI, for transferring transmembrane peptide complexes directly from lipid bilayers to the gas phase. [Figure not available: see fulltext.

A method for measuring the electron drift velocity in working gas using a Frisch-grid ionization chamber

Energy Technology Data Exchange (ETDEWEB)

Bai, Huaiyong; Wang, Zhimin; Zhang, Luyu; Chen, Jinxiang; Zhang, Guohui, E-mail: guohuizhang@pku.edu.cn

2016-12-21

A method for measuring the electron drift velocity in working gas is proposed. Based on the cathode and the anode signal waveforms of the Frisch-grid ionization chamber, the electron drift velocity is extracted. With this method, the electron drift velocities in Ar + 10% CH{sub 4}, Ar + 3.5% CO{sub 2} and Kr + 2.7% CO{sub 2} gases have been measured and the results are compared with the existing measurements and the simulating results. Using this method, the electron drift velocity can be monitored throughout the experiment of charged particle without bothering the measurement of other parameters, such as the energy and orientation.

F--Ray: A new algorithm for efficient transport of ionizing radiation

Science.gov (United States)

Mao, Yi; Zhang, J.; Wandelt, B. D.; Shapiro, P. R.; Iliev, I. T.

2014-04-01

We present a new algorithm for the 3D transport of ionizing radiation, called F2-Ray (Fast Fourier Ray-tracing method). The transfer of ionizing radiation with long mean free path in diffuse intergalactic gas poses a special challenge to standard numerical methods which transport the radiation in position space. Standard methods usually trace each individual ray until it is fully absorbed by the intervening gas. If the mean free path is long, the computational cost and memory load are likely to be prohibitive. We have developed an algorithm that overcomes these limitations and is, therefore, significantly more efficient. The method calculates the transfer of radiation collectively, using the Fast Fourier Transform to convert radiation between position and Fourier spaces, so the computational cost will not increase with the number of ionizing sources. The method also automatically combines parallel rays with the same frequency at the same grid cell, thereby minimizing the memory requirement. The method is explicitly photon-conserving, i.e. the depletion of ionizing photons is guaranteed to equal the photoionizations they caused, and explicitly obeys the periodic boundary condition, i.e. the escape of ionizing photons from one side of a simulation volume is guaranteed to be compensated by emitting the same amount of photons into the volume through the opposite side. Together, these features make it possible to numerically simulate the transfer of ionizing photons more efficiently than previous methods. Since ionizing radiation such as the X-ray is responsible for heating the intergalactic gas when first stars and quasars form at high redshifts, our method can be applied to simulate thermal distribution, in addition to cosmic reionization, in three-dimensional inhomogeneous cosmological density field.

Determination of Pesticides by Gas Chromatography Combined with Mass Spectrometry Using Femtosecond Lasers Emitting at 267, 400, and 800 nm as the Ionization Source.

Science.gov (United States)

Yang, Xixiang; Imasaka, Tomoko; Imasaka, Totaro

2018-04-03

A standard sample mixture containing 51 pesticides was separated by gas chromatography (GC), and the constituents were identified by mass spectrometry (MS) using femtosecond lasers emitting at 267, 400, and 800 nm as the ionization source. A two-dimensional display of the GC/MS was successfully used for the determination of these compounds. A molecular ion was observed for 38 of the compounds at 267 nm and for 30 of the compounds at 800 nm, in contrast to 27 among 50 compounds when electron ionization was used. These results suggest that the ultraviolet laser is superior to the near-infrared laser for molecular weight determinations and for a more reliable analysis of these compounds. In order to study the conditions for optimal ionization, the experimental data were examined using the spectral properties (i.e., the excitation and ionization energies and absorption spectra for the neutral and ionized species) obtained by quantum chemical calculations. A few molecules remained unexplained by the currently reported rules, requiring additional rules for developing a full understanding of the femtosecond ionization process. The pesticides in the homogenized matrix obtained from kabosu ( citrus sphaerocarpa) were measured using lasers emitting at 267 and 800 nm. The pesticides were clearly separated and measured on the two-dimensional display, especially for the data measured at 267 nm, suggesting that this technique would have potential for use in the practical trace analysis of the pesticides in the environment.

Dynamic wedge, electron energy and beam profile Q.A. using an ionization chamber linear array

International Nuclear Information System (INIS)

Kenny, M.B.; Todd, S.P.

1996-01-01

Since the introduction of multi-modal linacs the quality assurance workload of a Physical Sciences department has increased dramatically. The advent of dynamic wedges has further complicated matters because of the need to invent accurate methods to perform Q.A. in a reasonable time. We have been using an ionization chamber linear array, the Thebes 7000 TM by Victoreen, Inc., for some years to measure X-ray and electron beam profiles. Two years ago we developed software to perform Q.A. on our dynamic wedges using the array and more recently included a routine to check electron beam energies using the method described by Rosenow, U.F. et al., Med. Phys. 18(1) 19-25. The integrated beam and profile management system has enabled us to maintain a comprehensive quality assurance programme on all our linaccs. Both our efficiency and accuracy have increased to the point where we are able to keep up with the greater number of tests required without an increase in staff or hours spent in quality assurance. In changing the processor from the Z80 of the Thebes console to the 486 of the PC we have also noticed a marked increase in the calibration stability of the array. (author)

Determination of low specific activity iodine-129 off-gas concentrations by GC separation and negative ionization mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

Fernandez, S.J.; Rankin, R.A.; McManus, G.J.; Nielsen, R.A.; Delmore, J.E.; Hohorst, F.A.; Murphy, L.P.

1983-09-01

This document is the final report of the laboratory development of a method for determining the specific activity of the /sup 129/I emitted from a nuclear fuel reprocessing plant. The technique includes cryogenic sample collection, chemical form separation, quantitation by gas chromatography, and specific activity measurement of each chemical species by negative ionization mass spectrometry. The major conclusions were that both organic and elemental iodine can be quantitatively collected without fractionation and that specific activity measurements as low as one atom of /sup 129/I per 10/sup 5/ atoms of /sup 127/I are possible.

COLLISIONLESS SHOCKS IN A PARTIALLY IONIZED MEDIUM. II. BALMER EMISSION

Energy Technology Data Exchange (ETDEWEB)

Morlino, G.; Bandiera, R.; Blasi, P.; Amato, E. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy)

2012-12-01

Strong shocks propagating into a partially ionized medium are often associated with optical Balmer lines. This emission is due to impact excitation of neutral hydrogen by hot protons and electrons in the shocked gas. The structure of such Balmer-dominated shocks has been computed in a previous paper, where the distribution function of neutral particles was derived from the appropriate Boltzmann equation including coupling with ions and electrons through charge exchange and ionization. This calculation showed how the presence of neutrals can significantly modify the shock structure through the formation of a neutral-induced precursor ahead of the shock. Here we follow up on our previous work and investigate the properties of the resulting Balmer emission, with the aim of using the observed radiation as a diagnostic tool for shock parameters. Our main focus is on supernova remnant shocks, and we find that, for typical parameters, the H{alpha} emission typically has a three-component spectral profile, where (1) a narrow component originates from upstream cold hydrogen atoms, (2) a broad component comes from hydrogen atoms that have undergone charge exchange with shocked protons downstream of the shock, and (3) an intermediate component is due to hydrogen atoms that have undergone charge exchange with warm protons in the neutral-induced precursor. The relative importance of these three components depends on the shock velocity, on the original degree of ionization, and on the electron-ion temperature equilibration level. The intermediate component, which is the main signature of the presence of a neutral-induced precursor, becomes negligible for shock velocities {approx}< 1500 km s{sup -1}. The width of the intermediate line reflects the temperature in the precursor, while the width of the narrow one is left unaltered by the precursor. In addition, we show that the profiles of both the intermediate and broad components generally depart from a thermal distribution, as a

Profiling of plasma metabolites in canine oral melanoma using gas chromatography-mass spectrometry.

Science.gov (United States)

Kawabe, Mifumi; Baba, Yuta; Tamai, Reo; Yamamoto, Ryohei; Komori, Masayuki; Mori, Takashi; Takenaka, Shigeo

2015-08-01

Malignant melanoma is one of the most common and aggressive tumors in the oral cavity of dog. The tumor has a poor prognosis, and methods for diagnosis and prediction of prognosis after treatment are required. Here, we examined metabolite profiling using gas chromatography-mass spectrometry (GC-MS) for development of a discriminant model for evaluation of prognosis. Metabolite profiles were evaluated in healthy and melanoma plasma samples using orthogonal projection to latent structure using discriminant analysis (OPLS-DA). Cases that were predicted to be healthy using the OPLS discriminant model had no advanced lesions after radiation therapy. These results indicate that metabolite profiling may be useful in diagnosis and prediction of prognosis of canine malignant melanoma.

Evaluation of a novel helium ionization detector within the context of (low-)flow modulation comprehensive two-dimensional gas chromatography.

Science.gov (United States)

Franchina, Flavio A; Maimone, Mariarosa; Sciarrone, Danilo; Purcaro, Giorgia; Tranchida, Peter Q; Mondello, Luigi

2015-07-10

The present research is focused on the use and evaluation of a novel helium ionization detector, defined as barrier discharge ionization detector (BID), within the context of (low-)flow modulation comprehensive two-dimensional gas chromatography (FM GC×GC). The performance of the BID device was compared to that of a flame ionization detector (FID), under similar FM GC×GC conditions. Following development and optimization of the FM GC×GC method, the BID was subjected to fine tuning in relation to acquisition frequency and discharge flow. Moreover, the BID performance was measured and compared to that of the FID, in terms of extra-column band broadening, sensitivity and dynamic range. The comparative study was carried out by using standard compounds belonging to different chemical classes, along with a sample of diesel fuel. Advantages and disadvantages of the BID system, also within the context of FM GC×GC, are critically discussed. In general, the BID system was characterized by a more limited dynamic range and increased sensitivity, compared to the FID. Additionally, BID and FID contribution to band broadening was found to be similar under the operational conditions applied. Particular attention was devoted to the behaviour of the FM GC×GC-BID system toward saturated and aromatic hydrocarbons, for a possible future use in the field of mineral-oil food contamination research. Copyright © 2015 Elsevier B.V. All rights reserved.

Making MUSIC: A multiple sampling ionization chamber

International Nuclear Information System (INIS)

Shumard, B.; Henderson, D.J.; Rehm, K.E.; Tang, X.D.

2007-01-01

A multiple sampling ionization chamber (MUSIC) was developed for use in conjunction with the Atlas scattering chamber (ATSCAT). This chamber was developed to study the (α, p) reaction in stable and radioactive beams. The gas filled ionization chamber is used as a target and detector for both particles in the outgoing channel (p + beam particles for elastic scattering or p + residual nucleus for (α, p) reactions). The MUSIC detector is followed by a Si array to provide a trigger for anode events. The anode events are gated by a gating grid so that only (α, p) reactions where the proton reaches the Si detector result in an anode event. The MUSIC detector is a segmented ionization chamber. The active length of the chamber is 11.95 in. and is divided into 16 equal anode segments (3.5 in. x 0.70 in. with 0.3 in. spacing between pads). The dead area of the chamber was reduced by the addition of a Delrin snout that extends 0.875 in. into the chamber from the front face, to which a mylar window is affixed. 0.5 in. above the anode is a Frisch grid that is held at ground potential. 0.5 in. above the Frisch grid is a gating grid. The gating grid functions as a drift electron barrier, effectively halting the gathering of signals. Setting two sets of alternating wires at differing potentials creates a lateral electric field which traps the drift electrons, stopping the collection of anode signals. The chamber also has a reinforced mylar exit window separating the Si array from the target gas. This allows protons from the (α, p) reaction to be detected. The detection of these protons opens the gating grid to allow the drift electrons released from the ionizing gas during the (α, p) reaction to reach the anode segment below the reaction

Making MUSIC: A multiple sampling ionization chamber

Science.gov (United States)

Shumard, B.; Henderson, D. J.; Rehm, K. E.; Tang, X. D.

2007-08-01

A multiple sampling ionization chamber (MUSIC) was developed for use in conjunction with the Atlas scattering chamber (ATSCAT). This chamber was developed to study the (α, p) reaction in stable and radioactive beams. The gas filled ionization chamber is used as a target and detector for both particles in the outgoing channel (p + beam particles for elastic scattering or p + residual nucleus for (α, p) reactions). The MUSIC detector is followed by a Si array to provide a trigger for anode events. The anode events are gated by a gating grid so that only (α, p) reactions where the proton reaches the Si detector result in an anode event. The MUSIC detector is a segmented ionization chamber. The active length of the chamber is 11.95 in. and is divided into 16 equal anode segments (3.5 in. × 0.70 in. with 0.3 in. spacing between pads). The dead area of the chamber was reduced by the addition of a Delrin snout that extends 0.875 in. into the chamber from the front face, to which a mylar window is affixed. 0.5 in. above the anode is a Frisch grid that is held at ground potential. 0.5 in. above the Frisch grid is a gating grid. The gating grid functions as a drift electron barrier, effectively halting the gathering of signals. Setting two sets of alternating wires at differing potentials creates a lateral electric field which traps the drift electrons, stopping the collection of anode signals. The chamber also has a reinforced mylar exit window separating the Si array from the target gas. This allows protons from the (α, p) reaction to be detected. The detection of these protons opens the gating grid to allow the drift electrons released from the ionizing gas during the (α, p) reaction to reach the anode segment below the reaction.

Making MUSIC: A multiple sampling ionization chamber

Energy Technology Data Exchange (ETDEWEB)

Shumard, B. [Argonne National Laboratory, Building 203 H-113, Argonne, IL 60439 (United States)]. E-mail: shumard@phy.anl.gov; Henderson, D.J. [Argonne National Laboratory, Building 203 H-113, Argonne, IL 60439 (United States); Rehm, K.E. [Argonne National Laboratory, Building 203 H-113, Argonne, IL 60439 (United States); Tang, X.D. [Argonne National Laboratory, Building 203 H-113, Argonne, IL 60439 (United States)

2007-08-15

A multiple sampling ionization chamber (MUSIC) was developed for use in conjunction with the Atlas scattering chamber (ATSCAT). This chamber was developed to study the ({alpha}, p) reaction in stable and radioactive beams. The gas filled ionization chamber is used as a target and detector for both particles in the outgoing channel (p + beam particles for elastic scattering or p + residual nucleus for ({alpha}, p) reactions). The MUSIC detector is followed by a Si array to provide a trigger for anode events. The anode events are gated by a gating grid so that only ({alpha}, p) reactions where the proton reaches the Si detector result in an anode event. The MUSIC detector is a segmented ionization chamber. The active length of the chamber is 11.95 in. and is divided into 16 equal anode segments (3.5 in. x 0.70 in. with 0.3 in. spacing between pads). The dead area of the chamber was reduced by the addition of a Delrin snout that extends 0.875 in. into the chamber from the front face, to which a mylar window is affixed. 0.5 in. above the anode is a Frisch grid that is held at ground potential. 0.5 in. above the Frisch grid is a gating grid. The gating grid functions as a drift electron barrier, effectively halting the gathering of signals. Setting two sets of alternating wires at differing potentials creates a lateral electric field which traps the drift electrons, stopping the collection of anode signals. The chamber also has a reinforced mylar exit window separating the Si array from the target gas. This allows protons from the ({alpha}, p) reaction to be detected. The detection of these protons opens the gating grid to allow the drift electrons released from the ionizing gas during the ({alpha}, p) reaction to reach the anode segment below the reaction.

Ionizing potential waves and high-voltage breakdown streamers.

Science.gov (United States)

Albright, N. W.; Tidman, D. A.

1972-01-01

The structure of ionizing potential waves driven by a strong electric field in a dense gas is discussed. Negative breakdown waves are found to propagate with a velocity proportional to the electric field normal to the wavefront. This causes a curved ionizing potential wavefront to focus down into a filamentary structure, and may provide the reason why breakdown in dense gases propagates in the form of a narrow leader streamer instead of a broad wavefront.

Study of the molecular and ionized gas in a possible precursor of an ultra-compact H II region

Science.gov (United States)

Ortega, M. E.; Paron, S.; Giacani, E.; Celis Peña, M.; Rubio, M.; Petriella, A.

2017-10-01

Aims: We aim to study the molecular and the ionized gas in a possible precursor of an ultra-compact H II region to contribute to the understanding of how high-mass stars build-up their masses once they have reached the zero-age main sequence. Methods: We carried out molecular observations toward the position of the Red MSX source G052.9221-00.4892, using the Atacama Submillimeter Telescope Experiment (ASTE; Chile) in the 12CO J = 3-2, 13CO J = 3-2, C18O J = 3-2, and HCO+J = 4-3 lines with an angular resolution of about 22''. We also present radio continuum observations at 6 GHz carried out with the Jansky Very Large Array (JVLA; USA) interferometer with a synthesized beam of 4.8 arcsec × 4.1 arcsec. The molecular data were used to study the distribution and kinematics of the molecular gas, while the radio continuum data were used to characterize the ionized gas in the region. Combining these observations with public infrared data allowed us to inquire about the nature of the source. Results: The analysis of the molecular observations reveals the presence of a kinetic temperature and H2 column density gradients across the molecular clump in which the Red MSX source G052.9221-00.4892 is embedded, with the hotter and less dense gas in the inner region. The 12CO J = 3-2 emission shows evidence of misaligned massive molecular outflows, with the blue lobe in positional coincidence with a jet-like feature seen at 8 μm. The radio continuum emission shows a slightly elongated compact radio source, with a flux density of about 0.9 mJy, in positional coincidence with the Red MSX source. The polar-like morphology of this compact radio source perfectly matches the hourglass-like morphology exhibited by the source in the Ks band. Moreover, the axes of symmetry of the radio source and the near-infrared nebula are perfectly aligned. Thus, based on the presence of molecular outflows, the slightly elongated morphology of the compact radio source matching the hourglass

[S IV] IN THE NGC 5253 SUPERNEBULA: IONIZED GAS KINEMATICS AT HIGH RESOLUTION

Energy Technology Data Exchange (ETDEWEB)

Beck, Sara C. [Department of Physics and Astronomy, Tel Aviv University, Ramat Aviv (Israel); Lacy, John H. [Department of Astronomy, University of Texas at Austin, Austin, TX 78712 (United States); Turner, Jean L. [Department of Physics and Astronomy, UCLA, Los Angeles, CA 90095-1547 (United States); Kruger, Andrew; Richter, Matt [Department of Physics, University of California at Davis, Davis, CA 95616 (United States); Crosthwaite, Lucian P., E-mail: sara@wise.tau.ac.il [Northrop Grumman Aerospace Systems, San Diego, CA 92127 (United States)

2012-08-10

The nearby dwarf starburst galaxy NGC 5253 hosts a deeply embedded radio-infrared supernebula excited by thousands of O stars. We have observed this source in the 10.5 {mu}m line of S{sup +3} at 3.8 km s{sup -1} spectral and 1.''4 spatial resolution, using the high-resolution spectrometer TEXES on the IRTF. The line profile cannot be fit well by a single Gaussian. The best simple fit describes the gas with two Gaussians, one near the galactic velocity with FWHM 33.6 km s{sup -1} and another of similar strength and FWHM 94 km s{sup -1} centered {approx}20 km s{sup -1} to the blue. This suggests a model for the supernebula in which gas flows toward us out of the molecular cloud, as in a 'blister' or 'champagne flow' or in the H II regions modelled by Zhu.

Measurement of the density profile of pure and seeded molecular beams by femtosecond ion imaging

Energy Technology Data Exchange (ETDEWEB)

Meng, Congsen [LaserLaB Amsterdam, VU University Amsterdam, de Boelelaan 1083, 1081 HV Amsterdam (Netherlands); Department of Physics, National University of Defense Technology, Changsha 410073 (China); Janssen, Maurice H. M. [LaserLaB Amsterdam, VU University Amsterdam, de Boelelaan 1083, 1081 HV Amsterdam (Netherlands)

2015-02-15

Here, we report on femtosecond ion imaging experiments to measure the density profile of a pulsed supersonic molecular beam. Ion images are measured for both a molecular beam and bulk gas under identical experimental conditions via femtosecond multiphoton ionization of Xe atoms. We report the density profile of the molecular beam, and the measured absolute density is compared with theoretical calculations of the centre line beam density. Subsequently, we discuss reasons accounting for the differences between measurements and calculations and propose that strong skimmer interference is the most probable cause for the differences. Furthermore, we report on experiments measuring the centre line density of seeded supersonic beams. The femtosecond ion images show that seeding the heavy Xe atom at low relative seed fractions (1%-10%) in a light carrier gas like Ne results in strong relative enhancements of up to two orders of magnitude.

Analytical Estimates of the Dispersion Curve in Planar Ionization Fronts

International Nuclear Information System (INIS)

Arrayas, Manuel; Trueba, Jose L.; Betelu, Santiago; Fontelos, Marco A.

2009-01-01

Fingers from ionization fronts for a hydrodynamic plasma model result from a balance between impact ionization and electron diffusion in a non-attaching gas. An analytical estimation of the size of the fingers and its dependence on both the electric field and electron diffusion coefficient can be done when the diffusion is low and the electric field is strong.

Localization of ionization-induced trapping in a laser wakefield accelerator using a density down-ramp

CERN Document Server

Hansson, M.; Ekerfelt, H.; Aurand, B.; Gallardo Ganzalez, I.; Desforges, F. G.; Davoine, X.; Maitrallain, A.; Reymond, S.; Monot, P.; Persson, A.; Dobosz Dufrénoy S.; Wahlström C-G.; Cros, B.; Lundh, O.

2016-01-01

We report on a study on controlled trapping of electrons, by field ionization of nitrogen ions, in laser wakefield accelerators in variable length gas cells. In addition to ionization-induced trapping in the density plateau inside the cells, which results in wide, but stable, electron energy spectra, a regime of ionization-induced trapping localized in the density down-ramp at the exit of the gas cells, is found. The resulting electron energy spectra are peaked, with 10% shot-to-shot fluctuations in peak energy. Ionization-induced trapping of electrons in the density down-ramp is a way to trap and accelerate a large number of electrons, thus improving the efficiency of the laser-driven wakefield acceleration.

On the stabilization of gas discharge by an hf-electric field

International Nuclear Information System (INIS)

Rakhimova, T.V.; Rakhimov, A.T.

1975-01-01

It is shown that when the bulk gas discharge is placed in an hf-electric field of sufficiently high frequency in the process of gas discharge burning there appears a long phase during which the gas ionization is inessential and the discharge burns in a recombining plasma. Such a stage may affect the stability of a gas discharge. It is shown also that at comparable values of intensities of the d.c. and hf electric fields there is a small parameter for the weakly-ionized plasma in which the relative portion of energy introduced into the discharge during the stage of gas ionization may be sufficiently small. (Auth.)

Analysis of ionization wave dynamics in low-temperature plasma jets from fluid modeling supported by experimental investigations

Science.gov (United States)

Yousfi, M.; Eichwald, O.; Merbahi, N.; Jomaa, N.

2012-08-01

This work is devoted to fluid modeling based on experimental investigations of a classical setup of a low-temperature plasma jet. The latter is generated at atmospheric pressure using a quartz tube of small diameter crossed by helium gas flow and surrounded by an electrode system powered by a mono-polar high-voltage pulse. The streamer-like behavior of the fast plasma bullets or ionization waves launched in ambient air for every high-voltage pulse, already emphasized in the literature from experimental or analytical considerations or recent preliminary fluid models, is confirmed by a numerical one-moment fluid model for the simulation of the ionization wave dynamics. The dominant interactions between electron and the main ions present in He-air mixtures with their associated basic data are taken into account. The gradual dilution of helium in air outside the tube along the axis is also considered using a gas hydrodynamics model based on the Navier-Stokes equation assuming a laminar flow. Due to the low magnitude of the reduced electric field E/N (not exceeding 15 Td), it is first shown that consideration of the stepwise ionization of helium metastables is required to reach the critical size of the electron avalanches in order to initiate the formation of ionization waves. It is also shown that a gas pre-ionization ahead of the wave front of about 109 cm-3 (coming from Penning ionization without considering the gas photo-ionization) is required for the propagation. Furthermore, the second ionization wave experimentally observed during the falling time of the voltage pulse, between the powered electrode and the tube exit, is correlated with the electric field increase inside the ionized channel in the whole region between the electrode and the tube exit. The propagation velocity and the distance traveled by the front of the ionization wave outside the tube in the downstream side are consistent with the present experimental measurements. In comparison with the

Impact parameter dependence of inner-shell ionization probabilities

International Nuclear Information System (INIS)

Cocke, C.L.

1974-01-01

The probability for ionization of an inner shell of a target atom by a heavy charged projectile is a sensitive function of the impact parameter characterizing the collision. This probability can be measured experimentally by detecting the x-ray resulting from radiative filling of the inner shell in coincidence with the projectile scattered at a determined angle, and by using the scattering angle to deduce the impact parameter. It is conjectured that the functional dependence of the ionization probability may be a more sensitive probe of the ionization mechanism than is a total cross section measurement. Experimental results for the K-shell ionization of both solid and gas targets by oxygen, carbon and fluorine projectiles in the MeV/amu energy range will be presented, and their use in illuminating the inelastic collision process discussed

The photoionization of the diffuse galactic gas

Science.gov (United States)

Mathis, J. S.

1986-01-01

In a study of the diffuse ionized gas (DIG) component of the interstellar medium, it is attempted to see if the general properties of dilute gas ionized by O stars are similar to observations and to what extent the observations of the DIG can be used to determine the nature of the ionizing radiation field at great distances above the plane of the Galaxy. It has been suggested by Reynolds (1985) that either shocks or photoionization might be responsible for the DIG. The photoionization model seems required by the observations.

Ionization of Local Interstellar Gas Based on STIS and FUSE spectra of Nearby Stars

Science.gov (United States)

Redfield, Seth; Linsky, J. L.

2009-01-01

The ultraviolet contains many resonance line transitions that are sensitive to a range of ionization stages of ions present in the local interstellar medium (LISM). We couple observations of high resolution ultraviolet spectrographs, STIS and GHRS on the Hubble Space Telescope (HST) and the Far-Ultraviolet Spectroscopic Explorer (FUSE) in order to make a comprehensive survey of the ionization structure of the local interstellar medium. In particular, we focus on the sight line toward G191-B2B, a nearby (69 pc) white dwarf. We present interstellar detections of highly ionized elements (e.g., SiIII, CIII, CIV, etc) and compare them directly to neutral or singly ionized LISM detections (e.g., SiII, CII, etc). The extensive observations of G191-B2B provides an opportunity for a broad study of ionization stages of several elements, while a survey of several sight lines provides a comprehensive look at the ionization structure of the LISM. We acknowledge support for this project through NASA FUSE Grant NNX06AD33G.

THE IONIZED GAS IN NEARBY GALAXIES AS TRACED BY THE [NII] 122 AND 205 μm TRANSITIONS

Energy Technology Data Exchange (ETDEWEB)

Herrera-Camus, R.; Bolatto, A.; Wolfire, M. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Smith, J. D. [Department of Physics and Astronomy, University of Toledo, 2801 West Bancroft Street, Toledo, OH 43606 (United States); Draine, B. [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Pellegrini, E. [Zentrum für Astronomie der Universität Heidelberg, Institut für Theoretische Astrophysik, Albert-Ueberle-Str. 2, D-69120 Heidelberg (Germany); Croxall, K. [Department of Astronomy, The Ohio State University, 4051 McPherson Laboratory, 140 West 18th Avenue, Columbus, OH 43210 (United States); Looze, I. de; Kennicutt, R. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA (United Kingdom); Calzetti, D. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Crocker, A. [Department of Physics, Reed College, Portland, OR 97202 (United States); Armus, L. [Spitzer Science Center, California Institute of Technology, MC 314-6, Pasadena, CA 91125 (United States); Van der Werf, P.; Brandl, B. [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands); Sandstrom, K. [Center for Astrophysics and Space Sciences, Department of Physics, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (United States); Galametz, M. [European Southern Observatory, Karl Schwarzschild Strasse 2, D-85748 Garching (Germany); Groves, B. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Rigopoulou, D. [Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Walter, F. [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); and others

2016-08-01

The [N ii] 122 and 205 μ m transitions are powerful tracers of the ionized gas in the interstellar medium. By combining data from 21 galaxies selected from the Herschel KINGFISH and Beyond the Peak surveys, we have compiled 141 spatially resolved regions with a typical size of ∼1 kpc, with observations of both [N ii] far-infrared lines. We measure [N ii] 122/205 line ratios in the ∼0.6–6 range, which corresponds to electron gas densities of n {sub e} ∼ 1–300 cm{sup −3}, with a median value of n {sub e} = 30 cm{sup −3}. Variations in the electron density within individual galaxies can be as high as a factor of ∼50, frequently with strong radial gradients. We find that n {sub e} increases as a function of infrared color, dust-weighted mean starlight intensity, and star-formation rate (SFR) surface density (Σ{sub SFR}). As the intensity of the [N ii] transitions is related to the ionizing photon flux, we investigate their reliability as tracers of the SFR. We derive relations between the [N ii] emission and SFR in the low-density limit and in the case of a log-normal distribution of densities. The scatter in the correlation between [N ii] surface brightness and Σ{sub SFR} can be understood as a property of the n {sub e} distribution. For regions with n {sub e} close to or higher than the [N ii] line critical densities, the low-density limit [N ii]-based SFR calibration systematically underestimates the SFR because the [N ii] emission is collisionally quenched. Finally, we investigate the relation between [N ii] emission, SFR, and n {sub e} by comparing our observations to predictions from the MAPPINGS-III code.

THE IONIZED GAS IN NEARBY GALAXIES AS TRACED BY THE [NII] 122 AND 205 μm TRANSITIONS

International Nuclear Information System (INIS)

Herrera-Camus, R.; Bolatto, A.; Wolfire, M.; Smith, J. D.; Draine, B.; Pellegrini, E.; Croxall, K.; Looze, I. de; Kennicutt, R.; Calzetti, D.; Crocker, A.; Armus, L.; Van der Werf, P.; Brandl, B.; Sandstrom, K.; Galametz, M.; Groves, B.; Rigopoulou, D.; Walter, F.

2016-01-01

The [N ii] 122 and 205 μ m transitions are powerful tracers of the ionized gas in the interstellar medium. By combining data from 21 galaxies selected from the Herschel KINGFISH and Beyond the Peak surveys, we have compiled 141 spatially resolved regions with a typical size of ∼1 kpc, with observations of both [N ii] far-infrared lines. We measure [N ii] 122/205 line ratios in the ∼0.6–6 range, which corresponds to electron gas densities of n e ∼ 1–300 cm −3 , with a median value of n e = 30 cm −3 . Variations in the electron density within individual galaxies can be as high as a factor of ∼50, frequently with strong radial gradients. We find that n e increases as a function of infrared color, dust-weighted mean starlight intensity, and star-formation rate (SFR) surface density (Σ SFR ). As the intensity of the [N ii] transitions is related to the ionizing photon flux, we investigate their reliability as tracers of the SFR. We derive relations between the [N ii] emission and SFR in the low-density limit and in the case of a log-normal distribution of densities. The scatter in the correlation between [N ii] surface brightness and Σ SFR can be understood as a property of the n e distribution. For regions with n e close to or higher than the [N ii] line critical densities, the low-density limit [N ii]-based SFR calibration systematically underestimates the SFR because the [N ii] emission is collisionally quenched. Finally, we investigate the relation between [N ii] emission, SFR, and n e by comparing our observations to predictions from the MAPPINGS-III code.

High molecular weight non-polar hydrocarbons as pure model substances and in motor oil samples can be ionized without fragmentation by atmospheric pressure chemical ionization mass spectrometry.

Science.gov (United States)

Hourani, Nadim; Kuhnert, Nikolai

2012-10-15

High molecular weight non-polar hydrocarbons are still difficult to detect by mass spectrometry. Although several studies have targeted this problem, lack of good self-ionization has limited the ability of mass spectrometry to examine these hydrocarbons. Failure to control ion generation in the atmospheric pressure chemical ionization (APCI) source hampers the detection of intact stable gas-phase ions of non-polar hydrocarbon in mass spectrometry. Seventeen non-volatile non-polar hydrocarbons, reported to be difficult to ionize, were examined by an optimized APCI methodology using nitrogen as the reagent gas. All these analytes were successfully ionized as abundant and intact stable [M-H](+) ions without the use of any derivatization or adduct chemistry and without significant fragmentation. Application of the method to real-life hydrocarbon mixtures like light shredder waste and car motor oil was demonstrated. Despite numerous reports to the contrary, it is possible to ionize high molecular weight non-polar hydrocarbons by APCI, omitting the use of additives. This finding represents a significant step towards extending the applicability of mass spectrometry to non-polar hydrocarbon analyses in crude oil, petrochemical products, waste or food. Copyright © 2012 John Wiley & Sons, Ltd.

Measurement Of Ultrafast Ionisation From Intense Laser Interactions With Gas-Jets

International Nuclear Information System (INIS)

Gizzi, Leonida A.; Galimberti, Marco; Giulietti, Antonio; Giulietti, Danilo; Koester, Petra; Labate, Luca; Tomassini, Paolo; Martin, Philippe; Ceccotti, Tiberio; De Oliveira, Pascal; Monot, Pascal

2006-01-01

Interaction of an intense, ultrashort laser pulse with a gas-jet target is investigated through femtosecond optical interferometry to study the dynamics of ionization of the gas. Experimental results are presented in which the propagation of the pulse in the gas and the consequent plasma formation is followed step by step with high temporal and spatial resolution. We demonstrate that, combining the phase shift with the measurable depletion of fringe visibility associated with the transient change of refractive index in the ionizing region and taking into account probe travel time can provide direct information on gas ionization dynamics

Ionizing radiations, detection, dosimetry, spectrometry

International Nuclear Information System (INIS)

Blanc, D.

1997-10-01

A few works in French language are devoted to the detection of radiations. The purpose of this book is to fill a gap.The five first chapters are devoted to the properties of ionizing radiations (x rays, gamma rays, leptons, hadrons, nuclei) and to their interactions with matter. The way of classification of detectors is delicate and is studied in the chapter six. In the chapter seven are studied the statistics laws for counting and the spectrometry of particles is treated. The chapters eight to thirteen study the problems of ionization: charges transport in a gas, ionization chambers (theory of Boag), counters and proportional chambers, counters with 'streamers', chambers with derive, spark detectors, ionization chambers in liquid medium, Geiger-Mueller counters. The use of a luminous signal is the object of the chapters 14 to 16: conversion of a luminous signal in an electric signal, scintillators, use of the Cerenkov radiation. Then, we find the neutron detection with the chapter seventeen and the dosimetry of particles in the chapter eighteen. This book does not pretend to answer to specialists questions but can be useful to physicians, engineers or physics teachers. (N.C.)

Central peaking of magnetized gas discharges

International Nuclear Information System (INIS)

Chen, Francis F.; Curreli, Davide

2013-01-01

Partially ionized gas discharges used in industry are often driven by radiofrequency (rf) power applied at the periphery of a cylinder. It is found that the plasma density n is usually flat or peaked on axis even if the skin depth of the rf field is thin compared with the chamber radius a. Previous attempts at explaining this did not account for the finite length of the discharge and the boundary conditions at the endplates. A simple 1D model is used to focus on the basic mechanism: the short-circuit effect. It is found that a strong electric field (E-field) scaled to electron temperature T e , drives the ions inward. The resulting density profile is peaked on axis and has a shape independent of pressure or discharge radius. This “universal” profile is not affected by a dc magnetic field (B-field) as long as the ion Larmor radius is larger than a

Ionized Gas Outflows from the MAGNUM Survey: NGC 1365 and NGC 4945

Energy Technology Data Exchange (ETDEWEB)

Venturi, Giacomo; Marconi, Alessandro [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Sesto Fiorentino (Italy); Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Mingozzi, Matilde [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Dipartimento di Fisica e Astronomia, Università di Bologna, Bologna (Italy); Carniani, Stefano [Cavendish Laboratory, Department of Physics, University of Cambridge, Cambridge (United Kingdom); Kavli Institute for Cosmology, University of Cambridge, Cambridge (United Kingdom); Cresci, Giovanni [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Risaliti, Guido [Dipartimento di Fisica e Astronomia, Università degli Studi di Firenze, Sesto Fiorentino (Italy); Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy); Mannucci, Filippo, E-mail: gventuri@arcetri.astro.it [Osservatorio Astrofisico di Arcetri (INAF), Firenze (Italy)

2017-11-24

AGN feedback, acting through strong outflows accelerated in the nuclear region of AGN hosts, is invoked as a key ingredient for galaxy evolution by many models to explain the observed BH-galaxy scaling relations. Recently, some direct observational evidence of radiative mode feedback in action has been finally found in quasars at z >1.5. However, it is not possible to study outflows in quasars at those redshifts on small scales (≲100 pc), as spatial information is limited by angular resolution. This is instead feasible in nearby active galaxies, which are ideal laboratories to explore outflow structure and properties, as well as the effects of AGN on their host galaxies. In this proceeding we present preliminary results from the MAGNUM survey, which comprises nearby Seyfert galaxies observed with the integral field spectrograph VLT/MUSE. We focus on two sources, NGC 1365 and NGC 4945, that exhibit double conical outflows extending on distances >1 kpc. We disentangle the dominant contributions to ionization of the various gas components observed in the central ~5.3 kpc of NGC 1365. An attempt to infer outflow 3D structure in NGC 4945 is made via simple kinematic modeling, suggesting a hollow cone geometry.

Ionization and scintillation of nuclear recoils in gaseous xenon

Energy Technology Data Exchange (ETDEWEB)

Renner, J., E-mail: jrenner@lbl.gov [Lawrence Berkeley National Laboratory (LBNL), 1 Cyclotron Road, Berkeley, CA 94720 (United States); Department of Physics, University of California, Berkeley, CA 94720 (United States); Gehman, V.M.; Goldschmidt, A.; Matis, H.S.; Miller, T.; Nakajima, Y.; Nygren, D.; Oliveira, C.A.B.; Shuman, D. [Lawrence Berkeley National Laboratory (LBNL), 1 Cyclotron Road, Berkeley, CA 94720 (United States); Álvarez, V. [Instituto de Física Corpuscular (IFIC), CSIC & Universitat de València, Calle Catedrático José Beltrán, 2, 46980 Paterna, Valencia (Spain); Borges, F.I.G. [Departamento de Fisica, Universidade de Coimbra, Rua Larga, 3004-516 Coimbra (Portugal); Cárcel, S. [Instituto de Física Corpuscular (IFIC), CSIC & Universitat de València, Calle Catedrático José Beltrán, 2, 46980 Paterna, Valencia (Spain); Castel, J.; Cebrián, S. [Laboratorio de Física Nuclear y Astropartículas, Universidad de Zaragoza, Calle Pedro Cerbuna 12, 50009 Zaragoza (Spain); Cervera, A. [Instituto de Física Corpuscular (IFIC), CSIC & Universitat de València, Calle Catedrático José Beltrán, 2, 46980 Paterna, Valencia (Spain); Conde, C.A.N. [Departamento de Fisica, Universidade de Coimbra, Rua Larga, 3004-516 Coimbra (Portugal); and others

2015-09-01

Ionization and scintillation produced by nuclear recoils in gaseous xenon at approximately 14 bar have been simultaneously observed in an electroluminescent time projection chamber. Neutrons from radioisotope α-Be neutron sources were used to induce xenon nuclear recoils, and the observed recoil spectra were compared to a detailed Monte Carlo employing estimated ionization and scintillation yields for nuclear recoils. The ability to discriminate between electronic and nuclear recoils using the ratio of ionization to primary scintillation is demonstrated. These results encourage further investigation on the use of xenon in the gas phase as a detector medium in dark matter direct detection experiments.

Theory of the ionization yield in gases under electron irradiation

International Nuclear Information System (INIS)

Inokuti, M.

1974-01-01

The total number N/sub i/(T) of ionizations that an incident electron of kinetic energy T causes in a pure gas obeys an integral equation known as the Fowler equation. Its solution is shown to closely approximate N/sub i/(T) = (T -- U)/W/sub a/ for T exceeding several multiples of the first ionization energy I, where U and W/sub a/ are constants having the energy dimension. Simple formulas express U and W/sub a/ in terms of various cross sections for electron inelastic collisions with a gas molecule. In particular, U - I represents the average kinetic energy of a subionization electron. (35 refs) (U.S.)

A statistical mechanical model for equilibrium ionization

International Nuclear Information System (INIS)

Macris, N.; Martin, P.A.; Pule, J.

1990-01-01

A quantum electron interacts with a classical gas of hard spheres and is in thermal equilibrium with it. The interaction is attractive and the electron can form a bound state with the classical particles. It is rigorously shown that in a well defined low density and low temperature limit, the ionization probability for the electron tends to the value predicted by the Saha formula for thermal ionization. In this regime, the electron is found to be in a statistical mixture of a bound and a free state. (orig.)

Reactions of metal ions and their clusters in the gas phase using laser ionization: ion cyclotron resonance spectroscopy

International Nuclear Information System (INIS)

Freiser, B.S.

1981-04-01

Two subjects are discussed in this report: advances in proposed studies on metal ion chemistry and expansion of laboratory facilities. The development of a combined pulsed laser source-ion cyclotron resonance spectrometer has proven to be a convenient and powerful method for generating metal ions and for studying their subsequent chemistry in the gas phase. The main emphasis of this research has been on the application of metal ions as a selective chemical ionization reagents and progress in this area are discussed. The goal is to identify trends in reactivity i.e. mechanisms useful in interpreting the chemical ionization spectra of unknown compounds and to test for the functional group selectivity of the various metal ions. The feasibility of these goals have been demonstrated in extensive studies on Cu + with esters and ketones, on Fe + with ethers, ketones, and hydrocarbons, and on Ti + with hydrocarbons. In addition, preliminary results on sulfur containing compounds and on a variety of other metallic ions have been obtained. Laboratory facilities were expanded from one ion cyclotron resonance (ICR) spectrometer to two, plus a third instrument the Fourier Transform Ion Cyclotron Resonance (FTICR) spectrometer

Matrix Assisted and/or Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of WO3 Clusters Formation in Gas Phase. Nanodiamonds, Fullerene, and Graphene Oxide Matrices

Science.gov (United States)

Ausekar, Mayuri Vilas; Mawale, Ravi Madhukar; Pazdera, Pavel; Havel, Josef

2018-03-01

The formation of W x O y +●/-● clusters in the gas phase was studied by laser desorption ionization (LDI) and matrix assisted laser desorption ionization (MALDI) of solid WO3. LDI produced (WO3) n + ●/- ● ( n = 1-7) clusters. In MALDI, when using nano-diamonds (NDs), graphene oxide (GO), or fullerene (C60) matrices, higher mass clusters were generated. In addition to (WO3) n -● clusters, oxygen-rich or -deficient species were found in both LDI and MALDI (with the total number of clusters exceeding one hundred ≈ 137). This is the first time that such matrices have been used for the generation of(WO3) n + ●/-● clusters in the gas phase, while new high mass clusters (WO3) n -● ( n = 12-19) were also detected. [Figure not available: see fulltext.

Two-phase xenon detector with gas amplification and electroluminescent signal detection

International Nuclear Information System (INIS)

Akimov, D.Yu.; Burenkov, A.A.; Grishkin, Yu.L.; Kovalenko, A.G.; Lebedenko, V.N.; Stekhanov, V.N.

2008-01-01

An optical technique for detecting ionization electrons produced during ionization of the liquid phase has been experimentally tested in two-phase (liquid-gas) xenon. The effects of gas and electroluminescent amplifications at the wire anode are simultaneously used for detection. This method allows construction of a supersensitive detector of small ionization signals-down to those corresponding to the detection of single electrons [ru

THE GAS CONSUMPTION HISTORY TO REDSHIFT 4

International Nuclear Information System (INIS)

Bauermeister, Amber; Blitz, Leo; Ma, Chung-Pei

2010-01-01

Using the observations of the star formation rate (SFR) and H I densities to z ∼ 4, with measurements of the molecular gas depletion rate (MGDR) and local density of H 2 at z = 0, we derive the history of the gas consumption by star formation to z ∼ 4. We find that closed-box models in which H 2 is not replenished by H I require improbably large increases in ρ(H 2 ) and a decrease in the MGDR with lookback time that is inconsistent with observations. Allowing the H 2 used in star formation to be replenished by H I does not alleviate the problem because observations show that there is very little evolution of ρ H I (z) from z = 0 to z = 4. We show that to be consistent with observational constraints, star formation on cosmic timescales must be fueled by intergalactic ionized gas, which may come from either accretion of gas through cold (but ionized) flows, or from ionized gas associated with accretion of dark matter halos. We constrain the rate at which the extragalactic ionized gas must be converted into H I and ultimately into H 2 . The ionized gas inflow rate roughly traces the SFR density: about 1-2 x 10 8 M sun Gyr -1 Mpc -3 from z ≅ 1-4, decreasing by about an order of magnitude from z = 1 to z = 0 with details depending largely on MGDR(t). All models considered require the volume-averaged density of ρ H 2 to increase by a factor of 1.5-10 to z ∼ 1.5 over the currently measured value. Because the molecular gas must reside in galaxies, it implies that galaxies at high-z must, on average, be more molecule rich than they are at the present epoch, which is consistent with observations. These quantitative results, derived solely from observations, agree well with cosmological simulations.

Comparison of Atmospheric Pressure Chemical Ionization and Field Ionization Mass Spectrometry for the Analysis of Large Saturated Hydrocarbons.

Science.gov (United States)

Jin, Chunfen; Viidanoja, Jyrki; Li, Mingzhe; Zhang, Yuyang; Ikonen, Elias; Root, Andrew; Romanczyk, Mark; Manheim, Jeremy; Dziekonski, Eric; Kenttämaa, Hilkka I

2016-11-01

Direct infusion atmospheric pressure chemical ionization mass spectrometry (APCI-MS) was compared to field ionization mass spectrometry (FI-MS) for the determination of hydrocarbon class distributions in lubricant base oils. When positive ion mode APCI with oxygen as the ion source gas was employed to ionize saturated hydrocarbon model compounds (M) in hexane, only stable [M - H] + ions were produced. Ion-molecule reaction studies performed in a linear quadrupole ion trap suggested that fragment ions of ionized hexane can ionize saturated hydrocarbons via hydride abstraction with minimal fragmentation. Hence, APCI-MS shows potential as an alternative of FI-MS in lubricant base oil analysis. Indeed, the APCI-MS method gave similar average molecular weights and hydrocarbon class distributions as FI-MS for three lubricant base oils. However, the reproducibility of APCI-MS method was found to be substantially better than for FI-MS. The paraffinic content determined using the APCI-MS and FI-MS methods for the base oils was similar. The average number of carbons in paraffinic chains followed the same increasing trend from low viscosity to high viscosity base oils for the two methods.

Collective acceleration investigations with the ionization front accelerator

International Nuclear Information System (INIS)

Olson, C.L.; Poukey, J.W.; VanDevender, J.P.; Owyoung, A.; Pearlman, J.S.

1977-01-01

Part I of a three part program to demonstrate feasibility of the Ionization Front Accelerator (IFA) has been completed and is successful. Experiments describing intense relativistic electron beam (IREB) propagation in Cs are reported. The threshold pressure for electron beam ionization of Cs is found to agree with earlier theoretical predictions. These results experimentally establish Cs as a feasible working gas for the IFA. Numerical simulation results are also reported which demonstrate controlled potential well motion and collective ion acceleration with the IFA

A Laboratory Experiment To Measure Henry's Law Constants of Volatile Organic Compounds with a Bubble Column and a Gas Chromatography Flame Ionization Detector (GC-FID)

Science.gov (United States)

Lee, Shan-Hu; Mukherjee, Souptik; Brewer, Brittany; Ryan, Raphael; Yu, Huan; Gangoda, Mahinda

2013-01-01

An undergraduate laboratory experiment is described to measure Henry's law constants of organic compounds using a bubble column and gas chromatography flame ionization detector (GC-FID). This experiment is designed for upper-division undergraduate laboratory courses and can be implemented in conjunction with physical chemistry, analytical…

Potential of atmospheric pressure chemical ionization source in gas chromatography tandem mass spectrometry for the screening of urinary exogenous androgenic anabolic steroids.

Science.gov (United States)

Raro, M; Portolés, T; Pitarch, E; Sancho, J V; Hernández, F; Garrostas, L; Marcos, J; Ventura, R; Segura, J; Pozo, O J

2016-02-04

The atmospheric pressure chemical ionization (APCI) source for gas chromatography-mass spectrometry analysis has been evaluated for the screening of 16 exogenous androgenic anabolic steroids (AAS) in urine. The sample treatment is based on the strategy currently applied in doping control laboratories i.e. enzymatic hydrolysis, liquid-liquid extraction (LLE) and derivatization to form the trimethylsilyl ether-trimethylsilyl enol ether (TMS) derivatives. These TMS derivatives are then analyzed by gas chromatography tandem mass spectrometry using a triple quadrupole instrument (GC-QqQ MS/MS) under selected reaction monitoring (SRM) mode. The APCI promotes soft ionization with very little fragmentation resulting, in most cases, in abundant [M + H](+) or [M + H-2TMSOH](+) ions, which can be chosen as precursor ions for the SRM transitions, improving in this way the selectivity and sensitivity of the method. Specificity of the transitions is also of great relevance, as the presence of endogenous compounds can affect the measurements when using the most abundant ions. The method has been qualitatively validated by spiking six different urine samples at two concentration levels each. Precision was generally satisfactory with RSD values below 25 and 15% at the low and high concentration level, respectively. Most the limits of detection (LOD) were below 0.5 ng mL(-1). Validation results were compared with the commonly used method based on the electron ionization (EI) source. EI analysis was found to be slightly more repeatable whereas lower LODs were found for APCI. In addition, the applicability of the developed method has been tested in samples collected after the administration of 4-chloromethandienone. The highest sensitivity of the APCI method for this compound, allowed to increase the period in which its administration can be detected. Copyright © 2015 Elsevier B.V. All rights reserved.

Compaction wave profiles: Simulations of gas gun experiments

International Nuclear Information System (INIS)

Menikoff, Ralph

2001-01-01

Mesoscale simulations of a compaction wave in a granular bed of HMX have been performed. The grains are fully resolved in order that the compaction, i.e., the porosity behind the wave front, is determined by the elastic-plastic response of the grains rather than by an empirical law for the porosity as a function of pressure. Numerical wave profiles of the pressure and velocity are compared with data from a gas gun experiment. The experiment used an initial porosity of 36%, and the wave had a pressure comparable to the yield strength of the grains. The profiles are measured at the front and back of the granular bed. The transit time for the compaction wave to propagate between the gauges determines the wave speed. The wave speed depends on the porosity behind the wave and is affected by the strength model. The yield strength needed to match the experimental wave speed is discussed. Analysis of the lead wave through the granular bed, based on impedance matches using the Hugoniot loci, indicates that the compaction wave triggers a small amount of burn, less than 1% mass fraction, on the microsecond time scale of the experiment. copyright 2001 American Institute of Physics

Improving N-Glycan Coverage using HPLC-MS with Electrospray Ionization at Subambient Pressure

Energy Technology Data Exchange (ETDEWEB)

Marginean, Ioan; Kronewitter, Scott R.; Moore, Ronald J.; Slysz, Gordon W.; Monroe, Matthew E.; Anderson, Gordon A.; Tang, Keqi; Smith, Richard D.

2012-10-01

Human serum glycan profiling with mass spectrometry (MS) has been employed to study several disease conditions and is demonstrating promise for e.g. clinical biomarker discovery. However, the poor glycan ionization efficiency and the large dynamic range of glycan concentrations in human sera hinder comprehensive profiling. In particular, large glycans are problematic because they are present at low concentrations and prone to fragmentation. Here we show that the sub-ambient pressure ionization with nanoelectrospray (SPIN)-MS can expand the serum glycome profile when compared with the conventional atmospheric pressure electrospray ionization (ESI)-MS with a heated capillary inlet. Notably, the ions generated by the SPIN interface were observed at higher charge states for 50% of the annotated glycans. Out of a total of 130 detected glycans, 34 were only detected with the SPIN-MS, resulting in improved coverage of glycan families as well as of glycans with larger numbers of labile monosaccharides.

Negative chemical ionization mass spectrometry

International Nuclear Information System (INIS)

Smit, A.L.C.

1979-01-01

This thesis describes some aspects of Negative Chemical Ionization (NCI) mass spectrometry. The reasons for the growing interest in NCI are: (i) to extend the basic knowledge of negative ions and their reactions in the gas phase; (ii) to investigate whether or not this knowledge of negative ions can be used successfully to elucidate the structure of molecules by mass spectrometry. (Auth.)

Diffusion and drift regimes of plasma ionization wave propagation in a microwave field

International Nuclear Information System (INIS)

Khodataev, K.V.; Gorelik, B.R.

1997-01-01

Investigation into diffusion and drift modes of a plasma ionization wave propagation in the microwave field are conducted within the framework of a one-dimensional model with regard to gas ionization by electron shock in an electrical field, adhesion, mobility and diffusion of electrons

Dependence of charge collection distributions and dose on the gas type filling the ionization chamber for a p(66)Be(49) clinical neutron beam

International Nuclear Information System (INIS)

Awschalom, M.; Haken, R.K.T.

1985-01-01

Measurements of central axis depth charge distributions (CADCD) in a p(66)Be(49) clinical neutron beam using A-150 TE plastic ionization chambers (IC) have shown that these distributions are dependent on the gas type filling the ICs. IC volumes from 0.1 to 8 cm 3 and nine different gases were investigated. Off axis ratios and build-up measurements do not seem to be as sensitive to gas type. The gas dosimetry constants given in the AAPM Protocol for Neutron Beam Dosimetry for air and methane based TE gases were tested for consistency in water and in TE solution filled phantoms at depths of 10 cm, when used in conjunction with an IC having 5 mm thick walls of A-150. 29 refs., 7 figs., 1 tab

Noble-gas ionization in the ion source with Penning effect

International Nuclear Information System (INIS)

Monchka, D.; Lyatushinskij, A.; Vasyak, A.

1982-01-01

By additional use of that the ion source efficiency can be increased the Penning ionization. The results of estimates of certain coefficients for the processes taking place in the plasma ion sources are presented

Identification of volatiles by headspace gas chromatography with simultaneous flame ionization and mass spectrometric detection.

Science.gov (United States)

Tiscione, Nicholas B; Yeatman, Dustin Tate; Shan, Xiaoqin; Kahl, Joseph H

2013-10-01

Volatiles are frequently abused as inhalants. The methods used for identification are generally nonspecific if analyzed concurrently with ethanol or require an additional analytical procedure that employs mass spectrometry. A previously published technique utilizing a capillary flow technology splitter to simultaneously quantitate and confirm ethyl alcohol by flame ionization and mass spectrometric detection after headspace sampling and gas chromatographic separation was evaluated for the detection of inhalants. Methanol, isopropanol, acetone, acetaldehyde, toluene, methyl ethyl ketone, isoamyl alcohol, isobutyl alcohol, n-butyl alcohol, 1,1-difluoroethane, 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane (Norflurane, HFC-134a), chloroethane, trichlorofluoromethane (Freon®-11), dichlorodifluoromethane (Freon®-12), dichlorofluoromethane (Freon®-21), chlorodifluoromethane (Freon®-22) and 1,2-dichlorotetrafluoroethane (Freon®-114) were validated for qualitative identification by this method. The validation for qualitative identification included evaluation of matrix effects, sensitivity, carryover, specificity, repeatability and ruggedness/robustness.

Use of a hand-portable gas chromatograph-toroidal ion trap mass spectrometer for self-chemical ionization identification of degradation products related to O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX)

Energy Technology Data Exchange (ETDEWEB)

Smith, Philip A., E-mail: Smith.Philip.A@dol.gov [Uniformed Services University of the Health Sciences, Department of Preventive Medicine and Biometrics, 4301 Jones Bridge Road, Bethesda, MD, 20814 (United States); Lepage, Carmela R. Jackson [Defence R and D Canada - Suffield, Box 400, Station Main, Medicine Hat, Alberta, T1A 8K6 (Canada); Savage, Paul B. [Brigham Young University, Department of Chemistry and Biochemistry, Provo, UT, 84602 (United States); Bowerbank, Christopher R.; Lee, Edgar D. [Torion Technologies Inc., 796 East Utah Valley Drive, Suite 200, American Fork, UT, 84003 (United States); Lukacs, Michael J. [Defence R and D Canada - Suffield, Box 400, Station Main, Medicine Hat, Alberta, T1A 8K6 (Canada)

2011-04-01

The chemical warfare agent O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX) and many related degradation products produce poorly diagnostic electron ionization (EI) mass spectra by transmission quadrupole mass spectrometry. Thus, chemical ionization (CI) is often used for these analytes. In this work, pseudomolecular ([M+H]{sup +}) ion formation from self-chemical ionization (self-CI) was examined for four VX degradation products containing the diisopropylamine functional group. A person-portable toroidal ion trap mass spectrometer with a gas chromatographic inlet was used with EI, and both fixed-duration and feedback-controlled ionization time. With feedback-controlled ionization, ion cooling (reaction) times and ion formation target values were varied. Evidence for protonation of analytes was observed under all conditions, except for the largest analyte, bis(diisopropylaminoethyl)disulfide which yielded [M+H]{sup +} ions only with increased fixed ionization or ion cooling times. Analysis of triethylamine-d{sub 15} provided evidence that [M+H]{sup +} production was likely due to self-CI. Analysis of a degraded VX sample where lengthened ion storage and feedback-controlled ionization time were used resulted in detection of [M+H]{sup +} ions for VX and several relevant degradation products. Dimer ions were also observed for two phosphonate compounds detected in this sample.

Use of a hand-portable gas chromatograph-toroidal ion trap mass spectrometer for self-chemical ionization identification of degradation products related to O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX)

International Nuclear Information System (INIS)

Smith, Philip A.; Lepage, Carmela R. Jackson; Savage, Paul B.; Bowerbank, Christopher R.; Lee, Edgar D.; Lukacs, Michael J.

2011-01-01

The chemical warfare agent O-ethyl S-(2-diisopropylaminoethyl) methyl phosphonothiolate (VX) and many related degradation products produce poorly diagnostic electron ionization (EI) mass spectra by transmission quadrupole mass spectrometry. Thus, chemical ionization (CI) is often used for these analytes. In this work, pseudomolecular ([M+H] + ) ion formation from self-chemical ionization (self-CI) was examined for four VX degradation products containing the diisopropylamine functional group. A person-portable toroidal ion trap mass spectrometer with a gas chromatographic inlet was used with EI, and both fixed-duration and feedback-controlled ionization time. With feedback-controlled ionization, ion cooling (reaction) times and ion formation target values were varied. Evidence for protonation of analytes was observed under all conditions, except for the largest analyte, bis(diisopropylaminoethyl)disulfide which yielded [M+H] + ions only with increased fixed ionization or ion cooling times. Analysis of triethylamine-d 15 provided evidence that [M+H] + production was likely due to self-CI. Analysis of a degraded VX sample where lengthened ion storage and feedback-controlled ionization time were used resulted in detection of [M+H] + ions for VX and several relevant degradation products. Dimer ions were also observed for two phosphonate compounds detected in this sample.

Lyman series profiles: From laser-plasmas to white dwarf stars

Energy Technology Data Exchange (ETDEWEB)

Kielkopf, J.F. [University of Louisville, Louisville, Kentucky 40292 (United States); Allard, N.F. [Observatoire de Paris-Meudon, France and Institut d Astrophysique, Paris (France)

1999-04-01

The low energy interactions of neutral and ionized hydrogen atoms are fundamental processes which also have important applications to the diagnostics of laboratory and astrophysical plasmas. Satellites in the far wings of Lyman {alpha} and Lyman {beta} have been identified as ultraviolet absorption features in the spectra of white dwarf and {lambda} Bootis stars, and they are seen in the emission spectra of plasmas produced when a pulsed laser excites a target H{sub 2} gas. The observed Lyman series profiles agree with unified line shape theory which includes variation of the dipole transition moment during the radiative collision. {copyright} {ital 1999 American Institute of Physics.}

Online Simultaneous Hydrogen/Deuterium Exchange of Multitarget Gas-Phase Molecules by Electrospray Ionization Mass Spectrometry Coupled with Gas Chromatography.

Science.gov (United States)

Jeong, Eun Sook; Cha, Eunju; Cha, Sangwon; Kim, Sunghwan; Oh, Han Bin; Kwon, Oh-Seung; Lee, Jaeick

2017-11-21

In this study, a hydrogen/deuterium (H/D) exchange method using gas chromatography-electrospray ionization/mass spectrometry (GC-ESI/MS) was first investigated as a novel tool for online H/D exchange of multitarget analytes. The GC and ESI source were combined with a homemade heated column transfer line. GC-ESI/MS-based H/D exchange occurs in an atmospheric pressure ion source as a result of reacting the gas-phase analyte eluted from GC with charged droplets of deuterium oxide infused as the ESI spray solvent. The consumption of the deuterated solvent at a flow rate of 2 μL min -1 was more economical than that in online H/D exchange methods reported to date. In-ESI-source H/D exchange by GC-ESI/MS was applied to 11 stimulants with secondary amino or hydroxyl groups. After H/D exchange, the spectra of the stimulants showed unexchanged, partially exchanged, and fully exchanged ions showing various degrees of exchange. The relative abundances corrected for naturally occurring isotopes of the fully exchanged ions of stimulants, except for etamivan, were in the range 24.3-85.5%. Methylephedrine and cyclazodone showed low H/D exchange efficiency under acidic, neutral, and basic spray solvent conditions and nonexchange for etamivan with an acidic phenolic OH group. The in-ESI-source H/D exchange efficiency by GC-ESI/MS was sufficient to determine the number of hydrogen by elucidation of fragmentation from the spectrum. Therefore, this online H/D exchange technique using GC-ESI/MS has potential as an alternative method for simultaneous H/D exchange of multitarget analytes.

Multiphoton ionization of H2+ in xuv laser pulses

International Nuclear Information System (INIS)

Guan Xiaoxu; Secor, Ethan B.; Bartschat, Klaus; Schneider, Barry I.

2011-01-01

We consider the ionization of the hydrogen molecular ion after one-, two-, and three-photon absorption over a large range of photon energies between 9 and 40 eV in the fixed-nuclei approximation. The temporal development of the system is obtained in a fully ab initio time-dependent grid-based approach in prolate spheroidal coordinates. The alignment dependence of the one-photon ionization amplitude is highlighted in the framework of time-dependent perturbation theory. For one-photon ionization as a function of the nuclear separation, the calculations reveal a significant minimum in the ionization probability. The suppressed ionization is attributed to a Cooper-type minimum, which is similar, but not identical, to the cancellation effect observed in photoionization cross sections of some noble-gas atoms. The effect of the nonspherical two-center Coulomb potential is analyzed. For two- and three-photon ionization, the angle-integrated cross sections clearly map out intermediate-state resonances, and the predictions of the current computations agree very well with those from time-independent calculations. The dominant emission modes for two-photon ionization are found to be very similar in both resonance and off-resonance regions.

Dwarf galaxies with ionizing radiation feedback. II. Spatially resolved star formation relation

International Nuclear Information System (INIS)

Kim, Ji-hoon; Krumholz, Mark R.; Goldbaum, Nathan J.; Wise, John H.; Turk, Matthew J.; Abel, Tom

2013-01-01

We investigate the spatially resolved star formation relation using a galactic disk formed in a comprehensive high-resolution (3.8 pc) simulation. Our new implementation of stellar feedback includes ionizing radiation as well as supernova explosions, and we handle ionizing radiation by solving the radiative transfer equation rather than by a subgrid model. Photoheating by stellar radiation stabilizes gas against Jeans fragmentation, reducing the star formation rate (SFR). Because we have self-consistently calculated the location of ionized gas, we are able to make simulated, spatially resolved observations of star formation tracers, such as Hα emission. We can also observe how stellar feedback manifests itself in the correlation between ionized and molecular gas. Applying our techniques to the disk in a galactic halo of 2.3 × 10 11 M ☉ , we find that the correlation between SFR density (estimated from mock Hα emission) and H 2 density shows large scatter, especially at high resolutions of ≲75 pc that are comparable to the size of giant molecular clouds (GMCs). This is because an aperture of GMC size captures only particular stages of GMC evolution and because Hα traces hot gas around star-forming regions and is displaced from the H 2 peaks themselves. By examining the evolving environment around star clusters, we speculate that the breakdown of the traditional star formation laws of the Kennicutt-Schmidt type at small scales is further aided by a combination of stars drifting from their birthplaces and molecular clouds being dispersed via stellar feedback.

Dwarf galaxies with ionizing radiation feedback. II. Spatially resolved star formation relation

Energy Technology Data Exchange (ETDEWEB)

Kim, Ji-hoon; Krumholz, Mark R.; Wise, John H.; Turk, Matthew J.; Goldbaum, Nathan J.; Abel, Tom

2013-11-15

AWe investigate the spatially resolved star formation relation using a galactic disk formed in a comprehensive high-resolution (3.8 pc) simulation. Our new implementation of stellar feedback includes ionizing radiation as well as supernova explosions, and we handle ionizing radiation by solving the radiative transfer equation rather than by a subgrid model. Photoheating by stellar radiation stabilizes gas against Jeans fragmentation, reducing the star formation rate (SFR). Because we have self-consistently calculated the location of ionized gas, we are able to make simulated, spatially resolved observations of star formation tracers, such as Hα emission. We can also observe how stellar feedback manifests itself in the correlation between ionized and molecular gas. Applying our techniques to the disk in a galactic halo of 2.3 × 10¹¹ M _⊙, we find that the correlation between SFR density (estimated from mock Hα emission) and H₂ density shows large scatter, especially at high resolutions of ≲ 75 pc that are comparable to the size of giant molecular clouds (GMCs). This is because an aperture of GMC size captures only particular stages of GMC evolution and because Hα traces hot gas around star-forming regions and is displaced from the H₂ peaks themselves. By examining the evolving environment around star clusters, we speculate that the breakdown of the traditional star formation laws of the Kennicutt-Schmidt type at small scales is further aided by a combination of stars drifting from their birthplaces and molecular clouds being dispersed via stellar feedback.

Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

International Nuclear Information System (INIS)

Pallix, J.B.; Becker, C.H.; Missert, N.; Char, K.; Hammond, R.H.

1988-01-01

Surface analysis by laser ionization (SALI) has been used to examine a high-T/sub c/ superconducting thin film of nominal composition YBa 2 Cu 3 O 7 deposited on SrTiO 3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 A thick film having critical current densities of 1 to 2 x 10 6 A/cm 2 . SALI depth profiles show this film to be more uniform than thicker films (∼1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y 2 O 2 + , Y 2 O 3 + , Y 3 O 4 + , Ba 2 O + , Ba 2 O 2 + , BaCu + , BaCuO + , YBaO 2 + , YSrO 2 + , etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and CO/sub x/ are evident particularly in the sample's near surface region (the top ∼100 A)

Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

Science.gov (United States)

Pallix, J. B.; Becker, C. H.; Missert, N.; Char, K.; Hammond, R. H.

1988-02-01

Surface analysis by laser ionization (SALI) has been used to examine a high-Tc superconducting thin film of nominal composition YBa2Cu3O7 deposited on SrTiO3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 Å thick film having critical current densities of 1 to 2×106 A/cm2. SALI depth profiles show this film to be more uniform than thicker films (˜1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y2O2+, Y2O3+, Y3O4+, Ba2O+, Ba2O2+, BaCu+, BaCuO+, YBaO2+, YSrO2+, etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and COx are evident particularly in the sample's near surface region (the top ˜100 Å).

Mass spectra and ionization temperatures in an argon-nitrogen inductively coupled plasma

International Nuclear Information System (INIS)

Houk, R.S.; Montaser, A.; Fassel, V.A.

1983-01-01

Positive ions were extracted from the axial channel of an inductively coupled plasma (ICP) in which the outer gas flow was Ar, N 2 , or a mixture of Ar and N 2 . Addition of N 2 to the outer gas decreases the electron number density (n/sub e/) in the axial channel. Ar +2 , O 2 + , and ArH + react with N-containing species in the plasma and/or during the ion extraction process. Ar + remains abundant even if there is no Ar in the outer gas, which indicates the probable occurrence of charge transfer reactions between N 2 + and Ar. The present work corroborates two general concepts upon which several theories of theorigin of suprathermal ionization in ICPs are based: (a) species are physically transported from the induction region to the axial channel; and (b) these species may react with a ionize neutral species in the axial channel. Ionization temperatures (T/sub ion/) measured from the ratio Cd + /I + were 5750 to 6700 K for a N 2 outer flow ICP a forward power of 1.2 kW. This T/sub ion/ range is significantly below that obtained for an Ar outer gas ICP under otherwise similar operating parameters

Multi-Sampling Ionization Chamber (MUSIC) for measurements of fusion reactions with radioactive beams

International Nuclear Information System (INIS)

Carnelli, P.F.F.; Almaraz-Calderon, S.; Rehm, K.E.; Albers, M.; Alcorta, M.; Bertone, P.F.; Digiovine, B.; Esbensen, H.; Fernández Niello, J.; Henderson, D.; Jiang, C.L.; Lai, J.; Marley, S.T.; Nusair, O.; Palchan-Hazan, T.; Pardo, R.C.; Paul, M.; Ugalde, C.

2015-01-01

A detection technique for high-efficiency measurements of fusion reactions with low-intensity radioactive beams was developed. The technique is based on a Multi-Sampling Ionization Chamber (MUSIC) operating as an active target and detection system, where the ionization gas acts as both target and counting gas. In this way, we can sample an excitation function in an energy range determined by the gas pressure, without changing the beam energy. The detector provides internal normalization to the incident beam and drastically reduces the measuring time. In a first experiment we tested the performance of the technique by measuring the 10,13,15 C+ 12 C fusion reactions at energies around the Coulomb barrier

Multi-Sampling Ionization Chamber (MUSIC) for measurements of fusion reactions with radioactive beams

Energy Technology Data Exchange (ETDEWEB)

Carnelli, P.F.F. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Laboratorio TANDAR, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA, San Martín, Buenos Aires (Argentina); Consejo Nacional de Investigaciones Científicas y Técnicas, Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Almaraz-Calderon, S. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Rehm, K.E., E-mail: rehm@anl.gov [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Albers, M.; Alcorta, M.; Bertone, P.F.; Digiovine, B.; Esbensen, H. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Fernández Niello, J. [Laboratorio TANDAR, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA, San Martín, Buenos Aires (Argentina); Universidad Nacional de San Martín, Campus Miguelete, B1650BWA San Martín, Buenos Aires (Argentina); Henderson, D.; Jiang, C.L. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Lai, J. [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Marley, S.T.; Nusair, O.; Palchan-Hazan, T.; Pardo, R.C. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Paul, M. [Racah Institute of Physics, Hebrew University, Jerusalem (Israel); Ugalde, C. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States)

2015-11-01

A detection technique for high-efficiency measurements of fusion reactions with low-intensity radioactive beams was developed. The technique is based on a Multi-Sampling Ionization Chamber (MUSIC) operating as an active target and detection system, where the ionization gas acts as both target and counting gas. In this way, we can sample an excitation function in an energy range determined by the gas pressure, without changing the beam energy. The detector provides internal normalization to the incident beam and drastically reduces the measuring time. In a first experiment we tested the performance of the technique by measuring the {sup 10,13,15}C+{sup 12}C fusion reactions at energies around the Coulomb barrier.

Improving quantitative gas chromatography-electron ionization mass spectrometry results using a modified ion source: demonstration for a pharmaceutical application.

Science.gov (United States)

D'Autry, Ward; Wolfs, Kris; Hoogmartens, Jos; Adams, Erwin; Van Schepdael, Ann

2011-07-01

Gas chromatography-mass spectrometry is a well established analytical technique. However, mass spectrometers with electron ionization sources may suffer from signal drifts, hereby negatively influencing quantitative performance. To demonstrate this phenomenon for a real application, a static headspace-gas chromatography method in combination with electron ionization-quadrupole mass spectrometry was optimized for the determination of residual dichloromethane in coronary stent coatings. Validating the method, the quantitative performance of an original stainless steel ion source was compared to that of a modified ion source. Ion source modification included the application of a gold coating on the repeller and exit plate. Several validation aspects such as limit of detection, limit of quantification, linearity and precision were evaluated using both ion sources. It was found that, as expected, the stainless steel ion source suffered from signal drift. As a consequence, non-linearity and high RSD values for repeated analyses were obtained. An additional experiment was performed to check whether an internal standard compound would lead to better results. It was found that the signal drift patterns of the analyte and internal standard were different, consequently leading to high RSD values for the response factor. With the modified ion source however, a more stable signal was observed resulting in acceptable linearity and precision. Moreover, it was also found that sensitivity improved compared to the stainless steel ion source. Finally, the optimized method with the modified ion source was applied to determine residual dichloromethane in the coating of coronary stents. The solvent was detected but found to be below the limit of quantification. Copyright © 2011 Elsevier B.V. All rights reserved.

Unified first principles description from warm dense matter to ideal ionized gas plasma: electron-ion collisions induced friction.

Science.gov (United States)

Dai, Jiayu; Hou, Yong; Yuan, Jianmin

2010-06-18

Electron-ion interactions are central to numerous phenomena in the warm dense matter (WDM) regime and at higher temperature. The electron-ion collisions induced friction at high temperature is introduced in the procedure of ab initio molecular dynamics using the Langevin equation based on density functional theory. In this framework, as a test for Fe and H up to 1000 eV, the equation of state and the transition of electronic structures of the materials with very wide density and temperature can be described, which covers a full range of WDM up to high energy density physics. A unified first principles description from condensed matter to ideal ionized gas plasma is constructed.

Degradation of chlorpyrifos by ionizing radiation

International Nuclear Information System (INIS)

Mori, M.N.; Oikawa, H.; Sampa, M.H.O.; Duarte, C.L.

2006-01-01

Chlorpyrifos is an organophosphate pesticide commercialized since 1965 and it is now one of the top five commercial insecticides. It is registered for use in over 900 different pesticide formulations in the world. Chlorpyrifos poisoning usually affects many organs of the body, such as the central and peripheral nervous system, eyes, respiratory system, and the digestive tract. Depending on the pesticide formulation and type of application, chlorpyrifos residues may be detectable in water, soil, and on the surfaces from months to years. This paper presents preliminary studies of the removal of chlorpyrifos by exposition to ionizing radiation, to be applied in pesticide container decontamination. Samples containing various concentrations of chlorpyrifos in acetonitrile were irradiated with absorbed doses varying from 5 to 50 kGy, using a 60 Co gamma-source with 5,000 Ci activity (Gamma cell type). The chemical analysis of the chlorpyrifos and the by-products resulted from the radiolytic degradation were made using a gas chromatography associated to mass spectrometry (GC-MS) and gas chromatography with flame ionization detector (GCFID). (author)

Initial ionization stage of FRC formation

International Nuclear Information System (INIS)

Commisso, R.J.; Armstrong, W.T.; Cochrane, J.C.; Ekdahl, C.A.; Lipson, J.; Linford, R.K.; Sherwood, E.G.; Siemon, R.E.; Tuszewski, M.

1980-01-01

A Field-Reversed Configuration (FRC) is a prolate compact torus that is confined by poloidal fields only. Theta-pinch formation of an FRC employs an initial bias field, B 1 , whose direction is opposite to that of the main theta-pinch field. Some fraction of the flux associated with this bias field eventually constitutes the closed-field-line flux of the FRC. Experimental and theoretical evidence suggest that the longest-lived FRC's are obtained when the closed flux is maximized. Because the initial ionization is done in the presence of the bias field, the actual bias flux available at the time of application of the main theta-pinch field depends strongly on the initial ionization, or preionization, technique used. In this paper we report on experiments characterizing the previously used theta-pinch preionization technique that employed a net field (bias plus preionization) null, or zero-crossing, of the axial component of the magnetic field to break down the gas. We also discuss results of experiments designed to develop preionization techniques in which the gas breakdown is not accomplished by a zero-crossing

Comments on GUT monopole energy loss and ionization

International Nuclear Information System (INIS)

Hagstrom, R.

1982-01-01

A few comments about the likely behavior of the electromagnetic energy loss and ionization rates of super-slowly moving magnetic monopoles are presented. The questions of energy loss rates and ionization rates for super-low monopoles passing through matter are considered, concentrating on aspects of these issues which affect practical detection techniques. It is worthwhile here to emphasize that there is a potentially great distinction between energy loss rates and ionization rates and that the magnitude of this distinction is really the great issue which must be settled in order to understand the significance of experimental results from present and proposed investigations of the slow monopole question. Energy loss here means the total dE/dX of the projectile due to interactions with the electrons of the slowing medium. To the extent that nuclear collisions can be neglected, this so-called electronic energy loss is the relevant quantity in questions about whether monopoles stop within the earth's crust, whether they are slowed by interstellar plasmas, or the signal in a truly calorimetric measurement (measuring temperature rises along the trajectory), etc. Most of our successful detection techniques depend upon the promotion of ground state electrons into states which lie above some energy gap in the material of the detector: electrons must be knocked completely free from the gas atoms in a proportional chamber gas, electrons must be promoted to a higher band in solid scintillator plastics. These processes are generically identified as ionization

Ionized Gas Outflows from the MAGNUM Survey: NGC 1365 and NGC 4945

Directory of Open Access Journals (Sweden)

Giacomo Venturi

2017-11-01

Full Text Available AGN feedback, acting through strong outflows accelerated in the nuclear region of AGN hosts, is invoked as a key ingredient for galaxy evolution by many models to explain the observed BH-galaxy scaling relations. Recently, some direct observational evidence of radiative mode feedback in action has been finally found in quasars at z >1.5. However, it is not possible to study outflows in quasars at those redshifts on small scales (≲100 pc, as spatial information is limited by angular resolution. This is instead feasible in nearby active galaxies, which are ideal laboratories to explore outflow structure and properties, as well as the effects of AGN on their host galaxies. In this proceeding we present preliminary results from the MAGNUM survey, which comprises nearby Seyfert galaxies observed with the integral field spectrograph VLT/MUSE. We focus on two sources, NGC 1365 and NGC 4945, that exhibit double conical outflows extending on distances >1 kpc. We disentangle the dominant contributions to ionization of the various gas components observed in the central ~5.3 kpc of NGC 1365. An attempt to infer outflow 3D structure in NGC 4945 is made via simple kinematic modeling, suggesting a hollow cone geometry.

Ionization waves of arbitrary velocity driven by a flying focus

Science.gov (United States)

Palastro, J. P.; Turnbull, D.; Bahk, S.-W.; Follett, R. K.; Shaw, J. L.; Haberberger, D.; Bromage, J.; Froula, D. H.

2018-03-01

A chirped laser pulse focused by a chromatic lens exhibits a dynamic, or flying, focus in which the trajectory of the peak intensity decouples from the group velocity. In a medium, the flying focus can trigger an ionization front that follows this trajectory. By adjusting the chirp, the ionization front can be made to travel at an arbitrary velocity along the optical axis. We present analytical calculations and simulations describing the propagation of the flying focus pulse, the self-similar form of its intensity profile, and ionization wave formation. The ability to control the speed of the ionization wave and, in conjunction, mitigate plasma refraction has the potential to advance several laser-based applications, including Raman amplification, photon acceleration, high-order-harmonic generation, and THz generation.

Annotation of metabolites from gas chromatography/atmospheric pressure chemical ionization tandem mass spectrometry data using an in silico generated compound database and MetFrag.

Science.gov (United States)

Ruttkies, Christoph; Strehmel, Nadine; Scheel, Dierk; Neumann, Steffen

2015-08-30

Gas chromatography (GC) coupled to atmospheric pressure chemical ionization quadrupole time-of-flight mass spectrometry (APCI-QTOFMS) is an emerging technology in metabolomics. Reference spectra for GC/APCI-MS/MS barely exist; therefore, in silico fragmentation approaches and structure databases are prerequisites for annotation. To expand the limited coverage of derivatised structures in structure databases, in silico derivatisation procedures are required. A cheminformatics workflow has been developed for in silico derivatisation of compounds found in KEGG and PubChem, and validated on the Golm Metabolome Database (GMD). To demonstrate this workflow, these in silico generated databases were applied together with MetFrag to APCI-MS/MS spectra acquired from GC/APCI-MS/MS profiles of Arabidopsis thaliana and Solanum tuberosum. The Metabolite-Likeness of the original candidate structure was included as additional scoring term aiming at candidate structures of natural origin. The validation of our in silico derivatisation workflow on the GMD showed a true positive rate of 94%. MetFrag was applied to two datasets. In silico derivatisation of the KEGG and PubChem database served as a candidate source. For both datasets the Metabolite-Likeness score improved the identification performance. The derivatised data sources have been included into the MetFrag web application for the annotation of GC/APCI-MS/MS spectra. We demonstrated that MetFrag can support the identification of components from GC/APCI-MS/MS profiles, especially in the (common) case where reference spectra are not available. This workflow can be easily adapted to other types of derivatisation and is freely accessible together with the generated structure databases. Copyright © 2015 John Wiley & Sons, Ltd.

Effective ionization coefficient of C5 perfluorinated ketone and its mixtures with air

Science.gov (United States)

Aints, Märt; Jõgi, Indrek; Laan, Matti; Paris, Peeter; Raud, Jüri

2018-04-01

C5 perfluorinated ketone (C5 PFK with UIPAC chemical name 1,1,1,3,4,4,4-heptafluoro-3-(trifluoromethyl)-2-butanone and sold by 3M as Novec™ 5110) has a high dielectric strength and a low global warming potential, which makes it interesting as an insulating gas in medium and high-voltage applications. The study was carried out to determine the effective Townsend ionization coefficient α eff as a function of electric field strength and gas density for C5 PFK and for its mixtures with air. The non-self-sustained Townsend discharge between parallel plate electrodes was initiated by illuminating the cathode by UV radiation. The discharge current, I, was measured as a function of inter-electrode distance, d, at different gas densities, N, and electric field strengths, E. The effective ionization coefficient α eff was determined from the semi-logarithmic plots of I/I 0 against d. For each tested gas mixture, the density normalized effective ionization coefficient α eff/N was found to be a unique function of reduced electric field strength E/N. The measurements were carried out in the absolute pressure range of 0.05-1.3 bar and E/N range of 150-1200 Td. The increasing fraction of C5 PFK in air resulted in the decrease of effective ionization coefficient. The limiting electric field strength (E/N)lim where the effective ionization coefficient α eff became zero was 770 Td (190 kV cm-1 at 1 bar) for pure C5 PFK and decreased to 225 Td (78 kV cm-1 at 1.4 bar) for 7.6% C5 PFK/air mixture. The latter value of (E/N)lim is still more than two times higher than the (E/N)lim value of synthetic air and about two-thirds of the value corresponding to pure SF6. The investigated gas mixtures have the potential to become an alternative to SF6 in numerous high- and medium-voltage applications.

Kinematic Study of Ionized and Molecular Gases in Ultracompact HII Region in Monoceros R2

Science.gov (United States)

Kim, Hwihyun; Lacy, John H.; Jaffe, Daniel Thomas

2017-06-01

Monoceros R2 (Mon R2) is an UltraCompact HII region (UCHII) surrounded by several PhotoDissociation Regions (PDRs). It is an excellent example to investigate the chemistry and physics of early stage of massive star formation due to its proximity (830pc) and brightness. Previous studies suggest that the wind from the star holds the ionized gas up against the dense molecular core and the higher pressure at the head drives the ionized gas along the shell. In order for the model to work, there should be evidence for dense molecular gas along the shell walls, irradiated by the UCHII region and perhaps entrained into the flow along the walls.We obtained the Immersion Grating INfrared Spectrograph (IGRINS) spectra of Mon R2 to study the kinematic patterns in the areas where ionized and molecular gases interact. The position-velocity maps from the high resolution (R~45,000) H- and K-band (1.4-2.5μm) IGRINS spectra demonstrate that the ionized gases (Brackett and Pfund series, He and Fe emission lines; Δv ≈ 40km/s) flow along the walls of the surrounding clouds. This is consistent with the model by Zhu et al. (2008). In the PV maps of the H2 emission lines there is no obvious motion (Δv ≈ 10km/s) of the molecular hydrogen right at the ionization boundary. This implies that the molecular gas is not taking part in the flow as the ionized gas is moving along the cavity walls.This work used the Immersion Grating Infrared Spectrograph (IGRINS) that was developed under a collaboration between the University of Texas at Austin and the Korea Astronomy and Space Science Institute (KASI) with the financial support of the US National Science Foundation (NSF; grant AST-1229522), of the University of Texas at Austin, and of the Korean GMTProject of KASI.

Transverse MHD shock waves in a partly ionized plasma

International Nuclear Information System (INIS)

Mathers, C.D.

1980-01-01

The structure of transverse MHD shock waves in a partly ionized hydrogen plasma is studied using a three-fluid model with collisional transport coefficients. The morphology of the various sublayers in the shock front is analyzed in detail and it is shown that strong shock waves have a characteristic viscous structure. Weak to moderate strength shock waves display a resistive structure in which the enhanced transverse resistivity due to ion-slip plays a significant role, leading to a pronounced peak in the ion temperature profile. Calculated shock structure profiles are also compared with experimental temperature data. Results in the form of tables and figures are presented for shock waves with fast Mach number ranging from 1-10 in hydrogen plasma with initial degree of ionization ranging from 5-100%. (author)

Method and apparatus for analyzing ionizable materials

International Nuclear Information System (INIS)

Ehrlich, B.J.; Hall, R.C.; Thiede, P.W.

1979-01-01

An apparatus and method are described for analyzing a solution of ionizable compounds in a liquid. The solution is irradiated with electromagnetic radiation to ionize the compounds and the electrical conductivity of the solution is measured. The radiation may be X-rays, ultra-violet, infra-red or microwaves. The solution may be split into two streams, only one of which is irradiated, the other being used as a reference by comparing conductivities of the two streams. The liquid must be nonionizable and is preferably a polar solvent. The invention provides an analysis technique useful in liquid chromatography and in gas chromatography after dissolving the eluted gases in a suitable solvent. Electrical conductivity measurements performed on the irradiated eluent provide a quantitative indication of the ionizable materials existing within the eluent stream and a qualitative indication of the purity of the eluent stream. (author)

Development of a gas-phase field ionization ion source

International Nuclear Information System (INIS)

Allan, G.L.; Legge, G.J.F.

1983-01-01

A field ionization ion source has been developed to investigate the suitability of using such a source with the Melbourne Proton Microprobe. Operating parameters have been measured, and the source has been found to be brighter than the radiofrequency ion source presently used in the Melbourne 5U Pelletron Accelerator. Improvements to the source geometry to increase the current output are planned

Assembly and application of an instrument for attosecond-time-resolved ionization chronoscopy

International Nuclear Information System (INIS)

Uphues, T.

2006-11-01

In the framework of this thesis a new setup for attosecond time-resolved measurements has been built and observations of ionization dynamics in rare gas atoms have been made. This new technique is entitled Ionization Chronoscopy and gives further evidence that time-resolved experiments in the attosecond regime will become a powerful tool for investigations in atomic physics. (orig.)

Direct profiling of phytochemicals in tulip tissues and in vivo monitoring of the change of carbohydrate content in tulip bulbs by probe electrospray ionization mass spectrometry.

Science.gov (United States)

Yu, Zhan; Chen, Lee Chuin; Suzuki, Hiroaki; Ariyada, Osamu; Erra-Balsells, Rosa; Nonami, Hiroshi; Hiraoka, Kenzo

2009-12-01

Probe electrospray ionization (PESI) is a recently developed ESI-based ionization technique which generates electrospray from the tip of a solid needle. In this study, we have applied PESI interfaced with a time of flight mass spectrometer (TOF-MS) for direct profiling of phytochemicals in a section of a tulip bulb in different regions, including basal plate, outer and inner rims of scale, flower bud and foliage leaves. Different parts of tulip petals and leaves have also been investigated. Carbohydrates, amino acids and other phytochemicals were detected. A series of in vivo PESI-MS experiments were carried out on the second outermost scales of four living tulip bulbs to monitoring the change of carbohydrate content during the first week of initial growth. The breakdown of carbohydrates was observed which was in accordance with previous reports achieved by other techniques. This study has indicated that PESI-MS can be used for rapid and direct analysis of phytochemicals in living biological systems with advantages of low sample consumption and little sample preparation. Therefore, PESI-MS can be a new choice for direct analysis/profiling of bioactive compounds or monitoring metabolic changes in living biological systems.

Profiling of volatile organic compounds produced by clinical Aspergillus isolates using gas chromatography-mass spectrometry

NARCIS (Netherlands)

Gerritsen, M G; Brinkman, P; Escobar Salazar, Natalia; Bos, L D; de Heer, K; Meijer, M; Janssen, H-G; de Cock, H; Wösten, H A B; Visser, C.E.; van Oers, M H J; Sterk, P J

Volatile organic compounds (VOCs) in exhaled breath may identify the presence of invasive pulmonary aspergillosis. We aimed to detect VOC profiles emitted by in vitro cultured, clinical Aspergillus isolates using gas chromatography-mass spectrometry (GC-MS). Three clinical Aspergillus isolates and a

Profiling of volatile organic compounds produced by clinical Aspergillus isolates using gas chromatography-mass spectrometry

NARCIS (Netherlands)

Gerritsen, M. G.; Brinkman, P.; Escobar, N.; Bos, L. D.; de Heer, K.; Meijer, M.; Janssen, H.-G.; de Cock, H.; Wösten, H. A. B.; Visser, C. E.; van Oers, M. H. J.; Sterk, P. J.

2018-01-01

Volatile organic compounds (VOCs) in exhaled breath may identify the presence of invasive pulmonary aspergillosis. We aimed to detect VOC profiles emitted by in vitro cultured, clinical Aspergillus isolates using gas chromatography-mass spectrometry (GC-MS). Three clinical Aspergillus isolates and a

FIRST INVESTIGATION OF THE COMBINED IMPACT OF IONIZING RADIATION AND MOMENTUM WINDS FROM A MASSIVE STAR ON A SELF-GRAVITATING CORE

International Nuclear Information System (INIS)

Ngoumou, Judith; Hubber, David; Dale, James E.; Burkert, Andreas

2015-01-01

Massive stars shape the surrounding interstellar matter (ISM) by emitting ionizing photons and ejecting material through stellar winds. To study the impact of the momentum from the wind of a massive star on the surrounding neutral or ionized material, we implemented a new HEALPix-based momentum-conserving wind scheme in the smoothed particle hydrodynamics (SPH) code SEREN. A qualitative study of the impact of the feedback from an O7.5-like star on a self-gravitating sphere shows that on its own, the transfer of momentum from a wind onto cold surrounding gas has both a compressing and dispersing effect. It mostly affects gas at low and intermediate densities. When combined with a stellar source's ionizing ultraviolet (UV) radiation, we find the momentum-driven wind to have little direct effect on the gas. We conclude that during a massive star's main sequence, the UV ionizing radiation is the main feedback mechanism shaping and compressing the cold gas. Overall, the wind's effects on the dense gas dynamics and on the triggering of star formation are very modest. The structures formed in the ionization-only simulation and in the combined feedback simulation are remarkably similar. However, in the combined feedback case, different SPH particles end up being compressed. This indicates that the microphysics of gas mixing differ between the two feedback simulations and that the winds can contribute to the localized redistribution and reshuffling of gas

EXTREMELY BROAD RADIO RECOMBINATION MASER LINES TOWARD THE HIGH-VELOCITY IONIZED JET IN CEPHEUS A HW2

International Nuclear Information System (INIS)

Jimenez-Serra, I.; Patel, N.; Martin-Pintado, J.; Baez-Rubio, A.; Thum, C.

2011-01-01

We present the first detection of the H40α, H34α, and H31α radio recombination lines (RRLs) at millimeter wavelengths toward the high-velocity ionized jet in the Cepheus A HW2 star-forming region. From our single-dish and interferometric observations, we find that the measured RRLs show extremely broad asymmetric line profiles with zero-intensity line widths of ∼1100 km s -1 . From the line widths, we estimate a terminal velocity for the ionized gas in the jet of ≥500 km s -1 , consistent with that obtained from the proper motions of the HW2 radio jet. The total integrated line-to-continuum flux ratios of the H40α, H34α, and H31α lines are 43, 229, and 280 km s -1 , clearly deviating from LTE predictions. These ratios are very similar to those observed for the RRL masers toward MWC349A, suggesting that the intensities of the RRLs toward HW2 are affected by maser emission. Our radiative transfer modeling of the RRLs shows that their asymmetric profiles could be explained by maser emission arising from a bi-conical radio jet with a semi-opening angle of 18 deg., electron density distribution varying as r -2.11 , and turbulent and expanding wind velocities of 60 and 500 km s -1 .

Vertical seismic profile data from well Mallik 2L-38 for gas hydrate studies

Energy Technology Data Exchange (ETDEWEB)

Mi, Y [Calgary Univ., AB (Canada). Dept. of Geology and Geophysics; Walia, R [Victoria Univ., BC (Canada) School of Earth and Ocean Sciences; Hyndman, R [Geological Survey of Canada, Sidney, BC (Canada) Pacific Geoscience Centre

1999-07-01

A gas hydrate research well was drilled in the Canadian Arctic to study gas hydrates in a permafrost setting in a collaborative research project between the Japan National Oil Corp., the Geological Survey of Canada and other agencies. The multidisciplinary study included an electromagnetic survey, permafrost and gas hydrate coring, comprehensive downhole geophysical logging and measurement. Laboratory studies concerned studies on recovered cuttings and core including sedimentology, physical properties, geochemistry, and reservoir characteristics of the Mallik gas accumulation. As part of the Mallik 2L-38 field program, a vertical seismic profiling survey was conducted at zero and other offset source positions with three component receiver tools and horizontal and vertical vibration sources. A special effort was made to record shear wave data, which will be used to estimate the effect of gas hydrate on formation velocities and to determine gas hydrate concentration as a function of the Mallik gas accumulation. From the initial VSP analysis, certain conclusions follow: 1) zero offset vertical vibration component Z and horizontal X component data give reliable velocity determination within the gas hydrate formation zone. P wave velocities from offset VSP data show an excellent consistency with that from offset data and with the sonic log. And 2) the VSP data permit reliable identification of gas hydrate bearing zones. Abstract only included.

Kinetic theory of transport processes in weakly ionized gases

International Nuclear Information System (INIS)

Odenhoven, F.J.F. van

1984-01-01

A consistent method for the treatment of a plasma of arbitrary degree of ionization is presented. This method consists of a perturbation expansion in the framework of the multiple time scales formalism. Here the results are presented for a weakly ionized gas where elastic electron-atom collisions dominate. It appears that an isotropic correction to the zeroth order Maxwellian electron distribution function is necessary. Calculated electron transport coefficients are compared with the Frost mixture rule and with other calculations. (orig.)

Dark matter and gas density profiles - a consequence of entropy bifurcation

International Nuclear Information System (INIS)

Leubner, M. P.

2006-01-01

The radial profiles of dark matter and hot plasma density distributions of relaxed galaxies and clusters were hitherto commonly fitted by empirical functions. On the other hand, the fundamental concept of non-extensive statistics accounts for long-range interactions and correlations present in gravitationally coupled ensembles and plasmas. We provide a theoretical link of non-extensive statistics to large scale astrophysical structures and show that the underlying tandem character of the entropy results in a bifurcation of the density distribution. A kinetic dark matter and thermodynamic gas branch turn out as natural consequence within the theory and is controlled by one single parameter, measuring physically the degree of correlations in the system. The theoretically derived density profiles are shown to represent accurately the characteristics of both, DM and hot plasma distributions, as observed or generated in N-body and hydro-simulations. The significant advantage over empirical fitting functions is provided by the physical content of the non-extensive approach wherefore it is proposed to model observed density profiles of astrophysical structures within the fundamental context of entropy generalization, accounting for nonlocality and long-range interactions in gravitationally coupled systems

Spherical ionization chamber of 14 liter for precise measurement of environmental radiation dose rate

International Nuclear Information System (INIS)

Nagaoka, Toshi; Saito, Kimiaki; Moriuchi, Shigeru

1991-05-01

A spherical ionization chamber of 14 liter filled with 1 atm. nitrogen gas was arranged aiming at precise measurement of dose rate due to environmental gamma rays and cosmic rays. Ionization current-dose rate conversion factor for this ionization chamber was derived from careful consideration taking into account the attenuation by chamber wall, ionization current due to alpha particles and so on. Experiments at calibrated gamma ray fields and intercomparison with NaI(Tl) scintillation detector were also performed, which confirmed this ionization chamber using the conversion factor can measure the dose rate with an error of only a few percent. This ionization chamber will be used for measurement of environmental gamma ray and cosmic ray dose rate. (author)

Combined Determination of Poly-β-Hydroxyalkanoic and Cellular Fatty Acids in Starved Marine Bacteria and Sewage Sludge by Gas Chromatography with Flame Ionization or Mass Spectrometry Detection

Science.gov (United States)

Odham, Göran; Tunlid, Anders; Westerdahl, Gunilla; Mårdén, Per

1986-01-01

Extraction of lipids from bacterial cells or sewage sludge samples followed by simple and rapid extraction procedures and room temperature esterification with pentafluorobenzylbromide allowed combined determinations of poly-β-hydroxyalkanoate constituents and fatty acids. Capillary gas chromatography and flame ionization or mass spectrometric detection was used. Flame ionization permitted determination with a coefficient of variation ranging from 10 to 27% at the picomolar level, whereas quantitative chemical ionization mass spectrometry afforded sensitivities for poly-β-hydroxyalkanoate constituuents in the attomolar range. The latter technique suggests the possibility of measuring such components in bacterial assemblies with as few as 102 cells. With the described technique using flame ionization detection, it was possible to study the rapid formation of poly-β-hydroxyalkanoate during feeding of a starved marine bacterium isolate with a complex medium or glucose and correlate the findings to changes in cell volumes. Mass spectrometric detection of short β-hydroxy acids in activated sewage sludge revealed the presence of 3-hydroxybutyric, 3-hydroxyhexanoic, and 3-hydroxyoctanoic acids in the relative proportions of 56, 5 and 39%, respectively. No odd-chain β-hydroxy acids were found. PMID:16347181

On the SIMS Ionization Probability of Organic Molecules.

Science.gov (United States)

Popczun, Nicholas J; Breuer, Lars; Wucher, Andreas; Winograd, Nicholas

2017-06-01

The prospect of improved secondary ion yields for secondary ion mass spectrometry (SIMS) experiments drives innovation of new primary ion sources, instrumentation, and post-ionization techniques. The largest factor affecting secondary ion efficiency is believed to be the poor ionization probability (α + ) of sputtered material, a value rarely measured directly, but estimated to be in some cases as low as 10 -5 . Our lab has developed a method for the direct determination of α + in a SIMS experiment using laser post-ionization (LPI) to detect neutral molecular species in the sputtered plume for an organic compound. Here, we apply this method to coronene (C 24 H 12 ), a polyaromatic hydrocarbon that exhibits strong molecular signal during gas-phase photoionization. A two-dimensional spatial distribution of sputtered neutral molecules is measured and presented. It is shown that the ionization probability of molecular coronene desorbed from a clean film under bombardment with 40 keV C 60 cluster projectiles is of the order of 10 -3 , with some remaining uncertainty arising from laser-induced fragmentation and possible differences in the emission velocity distributions of neutral and ionized molecules. In general, this work establishes a method to estimate the ionization efficiency of molecular species sputtered during a single bombardment event. Graphical Abstract GRAPHICAL ABSTRACT TEXT HERE] -->.

Electron ionization and dissociation of aliphatic amino acids

Science.gov (United States)

Papp, P.; Shchukin, P.; Kočíšek, J.; Matejčík, Š.

2012-09-01

We present experimental and theoretical study of electron ionization and dissociative ionization to the gas phase amino acids valine, leucine, and isoleucine. A crossed electron/molecular beams technique equipped with quadrupole mass analyzer has been applied to measure mass spectra and ion efficiency curves for formation of particular ions. From experimental data the ionization energies of the molecules and the appearance energies of the fragment ions were determined. Ab initio calculations (Density Functional Theory and G3MP2 methods) were performed in order to calculate the fragmentation paths and interpret the experimental data. The experimental ionization energies of parent molecules [P]+ 8.91 ± 0.05, 8.85 ± 0.05, and 8.79 ± 0.05 eV and G3MP2 ionization energies (adiabatic) of 8.89, 8.88, and 8.81 eV were determined for valine, leucine, and isoleucine, respectively, as well as the experimental and theoretical threshold energies for dissociative ionization channels. The comparison of experimental data with calculations resulted in identification of the ions as well as the neutral fragments formed in the dissociative reactions. Around 15 mass/charge ratio fragments were identified from the mass spectra by comparison of experimental appearance energies with calculated reaction enthalpies for particular dissociative reactions.

Determination of free amino compounds in betalainic fruits and vegetables by gas chromatography with flame ionization and mass spectrometric detection.

Science.gov (United States)

Kugler, Florian; Graneis, Stephan; Schreiter, Pat P-Y; Stintzing, Florian C; Carle, Reinhold

2006-06-14

Amino acids and amines are the precursors of betalains. Therefore, the profiles of free amino compounds in juices obtained from cactus pears [Opuntia ficus-indica (L.) Mill. cv. Bianca, cv. Gialla, and cv. Rossa], pitaya fruits [Selenicereus megalanthus (K. Schumann ex Vaupel) Moran, Hylocereus polyrhizus (Weber) Britton & Rose, and Hylocereus undatus (Haworth) Britton & Rose], and in extracts from differently colored Swiss chard [Beta vulgaris L. ssp. cicla (L.) Alef. cv. Bright Lights] petioles and red and yellow beets (B. vulgaris L. ssp. vulgaris var. conditiva Alef. cv. Burpee's Golden) were investigated for the first time. Amino compounds were derivatized with propyl chloroformate. While gas chromatography (GC) with mass spectrometry was used for peak assignment, GC flame ionization detection was applied for quantification of individual compounds. Whereas proline was the major free amino compound of cactus pear and pitaya fruit juices, glutamine dominated in Swiss chard stems and beets, respectively. Interestingly, extremely high concentrations of dopamine were detected in Swiss chard stems and beets. Furthermore, the cleavage of betaxanthins caused by derivatization in alkaline reaction solutions is demonstrated for the first time. Amino acids and amines thus released might increase the actual free amino compound contents of the respective sample. To evaluate the contribution of betaxanthin cleavage to total amino acid and amine concentration, isolated betaxanthins were derivatized according to the "EZ:faast" method prior to quantification of the respective amino compounds released. On a molar basis, betaxanthin contribution to overall amino compound contents was always below 6.4%.

A modified commercial gas chromatograph for the continuous monitoring of the thermal degradation of sunflower oil and off-line solid phase extraction gas-chromatography-mass spectrometry characterization of released volatiles.

Science.gov (United States)

Ontañon, I; Sanz, J; Escudero, A; de Marcos, S; Ferreira, V; Galbán, J

2015-04-03

A homemade flow cell attached to a commercial Gas Chromatograph equipped with a Flame Ionization Detector (FID) has been designed for the continuous monitoring of volatile compounds released during heating edible oils. Analytical parameters such as mass of sample, temperature and flow rates have been optimized and the obtained results have been compared with the corresponding thermographs from standard TG systems. Results show that under optimum conditions, the profiles of volatiles released upon heating are comparable to the profiles of TG curves, suggesting that the FID based system could be an alternative to TGA. Additionally, volatiles have been retained in a Lichrolut EN(®) resin, eluted and analyzed by Gas Chromatography-Mass Spectrometry. In this case, forty five compounds have been identified (acids, alcohols, alkanes, aldehydes, ketones and furans) and compared with the FID signals, working both in air or nitrogen atmosphere. It has been concluded that the oxidative thermal degradation is prevented in the presence of a nitrogen atmosphere. Copyright © 2015 Elsevier B.V. All rights reserved.

Simulated X-ray galaxy clusters at the virial radius: Slopes of the gas density, temperature and surface brightness profiles

Science.gov (United States)

Roncarelli, M.; Ettori, S.; Dolag, K.; Moscardini, L.; Borgani, S.; Murante, G.

2006-12-01

Using a set of hydrodynamical simulations of nine galaxy clusters with masses in the range 1.5 × 1014 matter of tension between simulated and observed properties, and up to the virial radius and beyond, where present observations are unable to provide any constraints. We have modelled the radial profiles between 0.3R200 and 3R200 with power laws with one index, two indexes and a rolling index. The simulated temperature and [0.5-2] keV surface brightness profiles well reproduce the observed behaviours outside the core. The shape of all these profiles in the radial range considered depends mainly on the activity of the gravitational collapse, with no significant difference among models including extraphysics. The profiles steepen in the outskirts, with the slope of the power-law fit that changes from -2.5 to -3.4 in the gas density, from -0.5 to -1.8 in the gas temperature and from -3.5 to -5.0 in the X-ray soft surface brightness. We predict that the gas density, temperature and [0.5-2] keV surface brightness values at R200 are, on average, 0.05, 0.60, 0.008 times the measured values at 0.3R200. At 2R200, these values decrease by an order of magnitude in the gas density and surface brightness, by a factor of 2 in the temperature, putting stringent limits on the detectable properties of the intracluster-medium (ICM) in the virial regions.

SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

Energy Technology Data Exchange (ETDEWEB)

Bizyaev, D.; Pan, K.; Brinkmann, J. [Apache Point Observatory and New Mexico State University, Sunspot, NM 88349 (United States); Walterbos, R. A. M. [Department of Astronomy, New Mexico State University, Las Cruces, NM 88003 (United States); Yoachim, P. [Department of Astronomy, University of Washington, Seattle, WA 98195 (United States); Riffel, R. A. [Departamento de Física, CCNE, Universidade Federal de Santa Maria, Av. Roraima, 1000-97105-900, Santa Maria, RS (Brazil); Fernández-Trincado, J. G. [Institut Utinam, CNRS UMR 6213, Université de Franche-Comté, OSU THETA Franche-Comté-Bourgogne, Observatoire de Besançon, BP 1615, F-25010 Besançon Cedex (France); Diamond-Stanic, A. M. [Department of Astronomy, University of Wisconsin-Madison, Madison, WI 53706 (United States); Jones, A. [Max-Planck Institute for Astrophysics, Karl-Schwarzschild-Str 1, Garching, D-85748 (Germany); Thomas, D. [Institute of Cosmology and Gravitation, University of Portsmouth, Dennis Sciama Building, Portsmouth PO1 3FX (United Kingdom); Cleary, J. [Department of Physics and Astronomy, Johns Hopkins University, Bloomberg Center, 3400 North Charles Street, Baltimore, MD 21218 (United States)

2017-04-20

We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed H α emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

International Nuclear Information System (INIS)

Bizyaev, D.; Pan, K.; Brinkmann, J.; Walterbos, R. A. M.; Yoachim, P.; Riffel, R. A.; Fernández-Trincado, J. G.; Diamond-Stanic, A. M.; Jones, A.; Thomas, D.; Cleary, J.

2017-01-01

We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed H α emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

SDSS IV MaNGA—Rotation Velocity Lags in the Extraplanar Ionized Gas from MaNGA Observations of Edge-on Galaxies

Science.gov (United States)

Bizyaev, D.; Walterbos, R. A. M.; Yoachim, P.; Riffel, R. A.; Fernández-Trincado, J. G.; Pan, K.; Diamond-Stanic, A. M.; Jones, A.; Thomas, D.; Cleary, J.; Brinkmann, J.

2017-04-01

We present a study of the kinematics of the extraplanar ionized gas around several dozen galaxies observed by the Mapping of Nearby Galaxies at the Apache Point Observatory (MaNGA) survey. We considered a sample of 67 edge-on galaxies out of more than 1400 extragalactic targets observed by MaNGA, in which we found 25 galaxies (or 37%) with regular lagging of the rotation curve at large distances from the galactic midplane. We model the observed Hα emission velocity fields in the galaxies, taking projection effects and a simple model for the dust extinction into account. We show that the vertical lag of the rotation curve is necessary in the modeling, and estimate the lag amplitude in the galaxies. We find no correlation between the lag and the star formation rate in the galaxies. At the same time, we report a correlation between the lag and the galactic stellar mass, central stellar velocity dispersion, and axial ratio of the light distribution. These correlations suggest a possible higher ratio of infalling-to-local gas in early-type disk galaxies or a connection between lags and the possible presence of hot gaseous halos, which may be more prevalent in more massive galaxies. These results again demonstrate that observations of extraplanar gas can serve as a potential probe for accretion of gas.

Greenhouse gas and carbon profile of the U.S. forest products industry value chain

Science.gov (United States)

Linda S. Heath; Van Maltby; Reid Miner; Kenneth E. Skog; James E. Smith; Jay Unwin; Brad Upton

2010-01-01

A greenhouse gas and carbon accounting profile was developed for the U.S. forest products industry value chain for 1990 and 2004-2005 by examining net atmospheric fluxes of CO2 and other greenhouse gases (GHGs) using a variety of methods and data sources. Major GHG emission sources include direct and indirect (from purchased electricity...

Novel Laser Ignition Technique Using Dual-Pulse Pre-Ionization

Science.gov (United States)

Dumitrache, Ciprian

Recent advances in the development of compact high power laser sources and fiber optic delivery of giant pulses have generated a renewed interest in laser ignition. The non-intrusive nature of laser ignition gives it a set of unique characteristics over the well-established capacitive discharge devices (or spark plugs) that are currently used as ignition sources in engines. Overall, the use of laser ignition has been shown to have a positive impact on engine operation leading to a reduction in NOx emission, fuel saving and an increased operational envelope of current engines. Conventionally, laser ignition is achieved by tightly focusing a high-power q-switched laser pulse until the optical intensity at the focus is high enough to breakdown the gas molecules. This leads to the formation of a spark that serves as the ignition source in engines. However, there are certain disadvantages associated with this ignition method. This ionization approach is energetically inefficient as the medium is transparent to the laser radiation until the laser intensity is high enough to cause gas breakdown. As a consequence, very high energies are required for ignition (about an order of magnitude higher energy than capacitive plugs at stoichiometric conditions). Additionally, the fluid flow induced during the plasma recombination generates high vorticity leading to high rates of flame stretching. In this work, we are addressing some of the aforementioned disadvantages of laser ignition by developing a novel approach based on a dual-pulse pre-ionization scheme. The new technique works by decoupling the effect of the two ionization mechanisms governing plasma formation: multiphoton ionization (MPI) and electron avalanche ionization (EAI). An UV nanosecond pulse (lambda = 266 nm) is used to generate initial ionization through MPI. This is followed by an overlapped NIR nanosecond pulse (lambda = 1064 nm) that adds energy into the pre-ionized mixture into a controlled manner until the

The requirements for low-temperature plasma ionization support miniaturization of the ion source.

Science.gov (United States)

Kiontke, Andreas; Holzer, Frank; Belder, Detlev; Birkemeyer, Claudia

2018-06-01

Ambient ionization mass spectrometry (AI-MS), the ionization of samples under ambient conditions, enables fast and simple analysis of samples without or with little sample preparation. Due to their simple construction and low resource consumption, plasma-based ionization methods in particular are considered ideal for use in mobile analytical devices. However, systematic investigations that have attempted to identify the optimal configuration of a plasma source to achieve the sensitive detection of target molecules are still rare. We therefore used a low-temperature plasma ionization (LTPI) source based on dielectric barrier discharge with helium employed as the process gas to identify the factors that most strongly influence the signal intensity in the mass spectrometry of species formed by plasma ionization. In this study, we investigated several construction-related parameters of the plasma source and found that a low wall thickness of the dielectric, a small outlet spacing, and a short distance between the plasma source and the MS inlet are needed to achieve optimal signal intensity with a process-gas flow rate of as little as 10 mL/min. In conclusion, this type of ion source is especially well suited for downscaling, which is usually required in mobile devices. Our results provide valuable insights into the LTPI mechanism; they reveal the potential to further improve its implementation and standardization for mobile mass spectrometry as well as our understanding of the requirements and selectivity of this technique. Graphical abstract Optimized parameters of a dielectric barrier discharge plasma for ionization in mass spectrometry. The electrode size, shape, and arrangement, the thickness of the dielectric, and distances between the plasma source, sample, and MS inlet are marked in red. The process gas (helium) flow is shown in black.

Probing Conditions at Ionized/Molecular Gas Interfaces With High Resolution Near-Infrared Spectroscopy

Science.gov (United States)

Kaplan, Kyle Franklin

2017-08-01

Regions of star formation and star death in our Galaxy trace the cycle of gas and dust in the interstellar medium (ISM). Gas in dense molecular clouds collapses to form stars, and stars at the end of their lives return the gas that made up their outer layers back out into the Galaxy. Hot stars generate copious amounts of ultraviolet photons which interact with the surrounding medium and dominate the energetics, ionization state, and chemistry of the gas. The interface where molecular gas is being dissociated into neutral atomic gas by far-UV photons from a nearby hot source is called a photodissociation or photon-dominated region (PDR). PDRs are found primarily in star forming regions where O and B stars serve as the source of UV photons, and in planetary nebulae where the hot core of the dying star acts as the UV source. The main target of this dissertation is molecular hydrogen (H2), the most abundant molecule in the Universe, made from hydrogen formed during the Big Bang. H2 makes up the overwhelming majority of molecules found in the ISM and in PDRs. Far-UV radiation absorbed by H2 will excite an electron in the molecule. The molecule then either dissociates ( 10% of the time; Field et al. 1966) or decays into excited rotational and vibrational ("rovibrational") levels of the electronic ground state. These excited rovibrational levels then decay via a radiative cascade to the ground rovibrational state (v = 0, J = 0), giving rise to a large number of transitions observable in emission from the mid-IR to the optical (Black & van Dishoeck, 1987). These transitions provide an excellent probe of the excitation and conditions within the gas. These transitions are also observed in warm H2, such as in shocks, where collisions excite H2 to higher rovibrational levels. High resolution near-infrared spectroscopy, with its ability to see through dust, and avoid telluric absorption and emission, serves as an effective tool to detect emission from ions, atoms, and molecules

Influence of Ionization Source Conditions on the Gas-Phase Protomer Distribution of Anilinium and Related Cations.

Science.gov (United States)

Attygalle, Athula B; Xia, Hanxue; Pavlov, Julius

2017-08-01

The gas-phase-ion generation technique and specific ion-source settings of a mass spectrometer influence heavily the protonation processes of molecules and the abundance ratio of the generated protomers. Hitherto that has been attributed primarily to the nature of the solvent and the pH. By utilizing electrospray ionization and ion-mobility mass spectrometry (IM-MS), we demonstrate, even in the seemingly trivial case of protonated aniline, that the protomer ratio strongly depends on the source conditions. Under low in-source ion activation, nearly 100% of the N-protomer of aniline is produced, and it can be subsequently converted to the C-protomer by collisional activation effected by increasing the electrical potential difference between the entrance and exit orifices of the first vacuum region. This activation and transformation process takes place even before the ion is mass-selected and subjected to IM separation. Despite the apparent simplicity of the problem, the preferred protonation site of aniline in the gas phase-the amino group or the aromatic ring-has been a topic of controversy. Our results not only provide unambiguous evidence that ring- and nitrogen-protonated aniline can coexist and be interconverted in the gas phase, but also that the ratio of the protomers depends on the internal energy of the original ion. There are many dynamic ion-transformation and fragmentation processes that take place in the different physical compartments of a Synapt G2 HDMS instrument. Such processes can dramatically change the very identity even of small ions, and therefore should be taken into account when interpreting product-ion mass spectra. Graphical Abstract ᅟ.

Reference ionization chamber

International Nuclear Information System (INIS)

Golnik, N.; Zielczynski, M.

1999-01-01

The paper presents the design of ionization chamber devoted for the determination of the absolute value of the absorbed dose in tissue-equivalent material. The special attention was paid to ensure that the volume of the active gas cavity was constant and well known. A specific property of the chamber design is that the voltage insulators are 'invisible' from any point of the active volume. Such configuration ensures a very good time stability of the electrical field and defines the active volume. The active volume of the chamber was determined with accuracy of 0.3%. This resulted in accuracy of 0.8% in determination of the absorbed dose in the layer of material adherent to the gas cavity. The chamber was applied for calibration purposes at radiotherapy facility in Joint Institute for Nuclear Research in Dubna (Russia) and in the calibration laboratory of the Institute of Atomic Energy in Swierk. (author)

measurement of indoor background ionizing radiation in some

African Journals Online (AJOL)

Administrator

Measurement of the background ionizing radiation profile within the. Chemistry Research Laboratory and Physics Laboratory III all of the. University of Jos and their immediate neighbourhood were carried out. These science laboratories also harbour a number of active radiation sources. The radiation levels were measured ...

Controlling branching in streamer discharge by laser background ionization

International Nuclear Information System (INIS)

Takahashi, E; Kato, S; Furutani, H; Sasaki, A; Kishimoto, Y

2011-01-01

Irradiation with a KrF laser controlled the positive streamer branching in atmospheric argon gas. This laser irradiation changed the amount of background ionization before the streamer discharge. Measuring the ionization current allowed us to evaluate the initial electron density formed by the KrF laser. We observed characteristic feather-like branching structure and found that it was only suppressed in the irradiated region. The threshold of ionization density which can influence the branching was evaluated to be 5 x 10 5 cm -3 . The relationship between the size of avalanche head and mean distance between initial electrons explained this suppression behaviour. These experimental results support that the feather-like structure originates from the branching model of Loeb-Meek, a probabilistic merging of individual avalanches.

Gas chromatography/multiphoton ionization/time-of-flight mass spectrometry of polychlorinated biphenyls

International Nuclear Information System (INIS)

Matsui, Taiki; Uchimura, Tomohiro; Imasaka, Totaro

2011-01-01

A sample mixture of polychlorinated biphenyls (PCBs) was measured by gas chromatography/multiphoton ionization/time-of-flight mass spectrometry (GC/MPI/TOF-MS) using four types of laser sources. When a fourth harmonic emission (266 nm) of a picosecond Nd:YAG laser (1064 nm) was utilized, highly chlorinated PCBs larger than hepta-CBs were not observed. A fifth harmonic emission (213 nm) of the picosecond Nd:YAG laser allowed the measurement of PCBs from di-CBs to octa-CBs, and the limit of detection (LOD) was several pg for each component of PCBs. The LOD for the total amount of PCBs, which was calculated using the protocol provided by the Ministry of the Environment, Japan, was 1000 pg. The signal intensity of the congeners with chlorine atoms at the ortho positions (non-coplanar PCBs) was enhanced by using the fifth harmonic emission. When the fourth harmonic emission remaining after fifth harmonic generation was simultaneously used, the LOD for total PCBs was improved to 667 pg. The PCB sample was also measured using a third harmonic emission (267 nm) of a femtosecond Ti:sapphire laser (800 nm), providing an LOD of 677 pg. Thus, the two-color beam (266/213 nm) of a picosecond Nd:YAG laser had a comparable, or even slightly superior, performance to the more expensive femtosecond Ti:sapphire laser.

Initial ionization stage of FRC formation

Energy Technology Data Exchange (ETDEWEB)

Commisso, R.J.; Armstrong, W.T.; Cochrane, J.C.; Ekdahl, C.A.; Lipson, J.; Linford, R.K.; Sherwood, E.G.; Siemon, R.E.; Tuszewski, M.

1980-01-01

A Field-Reversed Configuration (FRC) is a prolate compact torus that is confined by poloidal fields only. Theta-pinch formation of an FRC employs an initial bias field, B/sub 1/, whose direction is opposite to that of the main theta-pinch field. Some fraction of the flux associated with this bias field eventually constitutes the closed-field-line flux of the FRC. Experimental and theoretical evidence suggest that the longest-lived FRC's are obtained when the closed flux is maximized. Because the initial ionization is done in the presence of the bias field, the actual bias flux available at the time of application of the main theta-pinch field depends strongly on the initial ionization, or preionization, technique used. In this paper we report on experiments characterizing the previously used theta-pinch preionization technique that employed a net field (bias plus preionization) null, or zero-crossing, of the axial component of the magnetic field to break down the gas. We also discuss results of experiments designed to develop preionization techniques in which the gas breakdown is not accomplished by a zero-crossing.

SDSS-IV MaNGA: A Serendipitous Observation of a Potential Gas Accretion Event

Science.gov (United States)

Cheung, Edmond; Stark, David V.; Huang, Song; Rubin, Kate H. R.; Lin, Lihwai; Tremonti, Christy; Zhang, Kai; Yan, Renbin; Bizyaev, Dmitry; Boquien, Médéric; Brownstein, Joel R.; Drory, Niv; Gelfand, Joseph D.; Knapen, Johan H.; Maiolino, Roberto; Malanushenko, Olena; Masters, Karen L.; Merrifield, Michael R.; Pace, Zach; Pan, Kaike; Riffel, Rogemar A.; Roman-Lopes, Alexandre; Rujopakarn, Wiphu; Schneider, Donald P.; Stott, John P.; Thomas, Daniel; Weijmans, Anne-Marie

2016-12-01

The nature of warm, ionized gas outside of galaxies may illuminate several key galaxy evolutionary processes. A serendipitous observation by the MaNGA survey has revealed a large, asymmetric Hα complex with no optical counterpart that extends ≈8″ (≈6.3 kpc) beyond the effective radius of a dusty, starbursting galaxy. This Hα extension is approximately three times the effective radius of the host galaxy and displays a tail-like morphology. We analyze its gas-phase metallicities, gaseous kinematics, and emission-line ratios and discuss whether this Hα extension could be diffuse ionized gas, a gas accretion event, or something else. We find that this warm, ionized gas structure is most consistent with gas accretion through recycled wind material, which could be an important process that regulates the low-mass end of the galaxy stellar mass function.

SDSS-IV MaNGA: A SERENDIPITOUS OBSERVATION OF A POTENTIAL GAS ACCRETION EVENT

International Nuclear Information System (INIS)

Cheung, Edmond; Stark, David V.; Huang, Song; Rubin, Kate H. R.; Lin, Lihwai; Tremonti, Christy; Zhang, Kai; Yan, Renbin; Bizyaev, Dmitry; Malanushenko, Olena; Boquien, Médéric; Brownstein, Joel R.; Drory, Niv; Gelfand, Joseph D.; Knapen, Johan H.; Maiolino, Roberto; Masters, Karen L.

2016-01-01

The nature of warm, ionized gas outside of galaxies may illuminate several key galaxy evolutionary processes. A serendipitous observation by the MaNGA survey has revealed a large, asymmetric H α complex with no optical counterpart that extends ≈8″ (≈6.3 kpc) beyond the effective radius of a dusty, starbursting galaxy. This H α extension is approximately three times the effective radius of the host galaxy and displays a tail-like morphology. We analyze its gas-phase metallicities, gaseous kinematics, and emission-line ratios and discuss whether this H α extension could be diffuse ionized gas, a gas accretion event, or something else. We find that this warm, ionized gas structure is most consistent with gas accretion through recycled wind material, which could be an important process that regulates the low-mass end of the galaxy stellar mass function.

SDSS-IV MaNGA: A SERENDIPITOUS OBSERVATION OF A POTENTIAL GAS ACCRETION EVENT

Energy Technology Data Exchange (ETDEWEB)

Cheung, Edmond; Stark, David V.; Huang, Song [Kavli Institute for the Physics and Mathematics of the Universe (WPI), The University of Tokyo Institutes for Advanced Study, The University of Tokyo, Kashiwa, Chiba 277-8583 (Japan); Rubin, Kate H. R. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Lin, Lihwai [Institute of Astronomy and Astrophysics, Academia Sinica, Taipei 106, Taiwan (China); Tremonti, Christy [Department of Astronomy, University of Wisconsin–Madison, 475 North Charter Street, Madison, WI 53706 (United States); Zhang, Kai; Yan, Renbin [Department of Physics and Astronomy, University of Kentucky, 505 Rose Street, Lexington, KY 40506-0055 (United States); Bizyaev, Dmitry; Malanushenko, Olena [Apache Point Observatory and New Mexico State University, P.O. Box 59, Sunspot, NM, 88349-0059 (United States); Boquien, Médéric [Unidad de Astronomía, Universidad de Antofagasta, Avenida Angamos 601, Antofagasta 1270300 (Chile); Brownstein, Joel R. [Department of Physics and Astronomy, University of Utah, 115 S. 1400 E., Salt Lake City, UT 84112 (United States); Drory, Niv [McDonald Observatory, Department of Astronomy, University of Texas at Austin, 1 University Station, Austin, TX 78712-0259 (United States); Gelfand, Joseph D. [NYU Abu Dhabi, P.O. Box 129188, Abu Dhabi (United Arab Emirates); Knapen, Johan H. [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain); Maiolino, Roberto [Cavendish Laboratory, University of Cambridge, 19 J. J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Masters, Karen L., E-mail: ec2250@gmail.com [Institute for Cosmology and Gravitation, University of Portsmouth, Dennis Sciama Building, Burnaby Road, Portsmouth PO1 3FX (United Kingdom); and others

2016-12-01

The nature of warm, ionized gas outside of galaxies may illuminate several key galaxy evolutionary processes. A serendipitous observation by the MaNGA survey has revealed a large, asymmetric H α complex with no optical counterpart that extends ≈8″ (≈6.3 kpc) beyond the effective radius of a dusty, starbursting galaxy. This H α extension is approximately three times the effective radius of the host galaxy and displays a tail-like morphology. We analyze its gas-phase metallicities, gaseous kinematics, and emission-line ratios and discuss whether this H α extension could be diffuse ionized gas, a gas accretion event, or something else. We find that this warm, ionized gas structure is most consistent with gas accretion through recycled wind material, which could be an important process that regulates the low-mass end of the galaxy stellar mass function.

Simple method for identifying doubly ionized uranium (U III) produced in a hollow-cathode discharge

International Nuclear Information System (INIS)

Piyakis, K.N.; Gagne, J.M.

1988-01-01

We have studied by emission spectroscopy the spectral properties of doubly ionized uranium, produced in a vapor generator of hollow-cathode design, as a function of the nature of a pure fill gas (helium, neon, argon, krypton, xenon) and its pressure. The spectral intensity is found to increase with increasing ionization potential of the discharge buffer gas, except in the case of helium. Based on our preliminary results, a simple and practical method for the positive identification of the complex U III spectrum is suggested

Thermodynamic analysis of oil and gas platforms over various production profiles and feed compositions

DEFF Research Database (Denmark)

Nguyen, Tuong-Van; Junior, Silvio de Oliveira

2017-01-01

Oil and gas platforms present similar structural designs but process fluids with different thermo-physical and chemical properties. In addition, the field properties, such as the gas-to-oil and water-to-oil ratios, change significantly over time. It is therefore not possible to suggest a standard...... of energy and exergy. Feed compositions and production profiles, which correspond to data from actual fields, are used for calibrating the simulations. In a second step, the minimum energy and exergy losses of the platform are assessed by performing thermodynamic analyses, assuming an ideal scenario...... in which all processes are run at their design points. This approach proves to be useful for evaluating consistently different options for oil and gas production, and for determining, in a further step, the most promising solutions for minimising the energy use over a field lifetime....

GAS PHASE ION CHEMISTRY OF COUMARINS: AB INITIO ...

African Journals Online (AJOL)

B. S. Chandravanshi

The gas phase ion chemistry of coumarins using electron ionization (EI), positive chemical ionization (PCI) and ... Figure 1. Generic chemical structures of the coumarins in this study. ..... Part of this work was conducted using the resources of ...

Highly sensitive high resolution Raman spectroscopy using resonant ionization methods

International Nuclear Information System (INIS)

Owyoung, A.; Esherick, P.

1984-05-01

In recent years, the introduction of stimulated Raman methods has offered orders of magnitude improvement in spectral resolving power for gas phase Raman studies. Nevertheless, the inherent weakness of the Raman process suggests the need for significantly more sensitive techniques in Raman spectroscopy. In this we describe a new approach to this problem. Our new technique, which we call ionization-detected stimulated Raman spectroscopy (IDSRS), combines high-resolution SRS with highly-sensitive resonant laser ionization to achieve an increase in sensitivity of over three orders of magnitude. The excitation/detection process involves three sequential steps: (1) population of a vibrationally excited state via stimulated Raman pumping; (2) selective ionization of the vibrationally excited molecule with a tunable uv source; and (3) collection of the ionized species at biased electrodes where they are detected as current in an external circuit

On the stability of boundary layers in gas mantle systems

International Nuclear Information System (INIS)

Ohlsson, D.

1978-10-01

In this thesis a systematic investigation of the stability properties of the partially ionized boundary regions of gas mantle systems for a large class of dissipative magneto-hydrodynamic modes is presented. In the partially ionized boundary regions of gas mantle systems several strong stabilizing mechanisms arise due to coupling between various dissipative effects in certain parameter regions. The presence of neutral gas strongly enhances the stabilizing effects in a dual fashion. First in an indirect way by cooling the edge region and second in a direct way by enhancing viscous and heat conduction effects. It has, however, to be pointed out that exceptions from this general picture may be found. The stabilizing influence of neutral gas on a large class of electrostatic as well as electromagnetic modes in the boundary regions of gas blanket systems is contrary to what has been found in low density weakly ionized plasmas. In these latter cases presence of neutral gas has even been found to be responsible for the onset of entirely new classes of instabilities. Thus there is no universal stabilizing or destabilizing effect associated with plasma-neutral gas interaction effects. (author)

Gasdynamics of H II regions. V. The interaction of weak R ionization fronts with dense clouds

Energy Technology Data Exchange (ETDEWEB)

Tenorio-Tagle, G; Bedijn, P J

1981-06-01

The interaction of weak R-type ionization fronts with a density enhancement is calculated numerically as a function of time within the framework of the champagne model of the evolution of H II regions. Calculations are performed under the assumption of plane-parallel geometry for various relative densities of the cloud in which the exciting star is formed and a second cloud with which an ionization front from the first cloud interacts. The supersonic ionization front representing the outer boundary of an H II region experiencing the champagne phase is found to either evolve into a D-type front or remain of type R, depending on the absolute number of photons leaving the H II region that undergoes the champagne phase. Recombinations in the ionized gas eventually slow the ionization front, however photon fluxes allow it to speed up again, resulting in oscillatory propagation of the front. Front-cloud interactions are also shown to lead to the development of a backward-facing shock, a forward-facing shock, and a density maximum in the ionized gas. The results can be used to explain the origin of bright rims in H II regions.

Profiles

International Nuclear Information System (INIS)

2004-01-01

Profiles is a synthetic overview of more than 100 national energy markets in the world, providing insightful facts and key energy statistics. A Profile is structured around 6 main items and completed by key statistics: Ministries, public agencies, energy policy are concerned; main companies in the oil, gas, electricity and coal sectors, status, shareholders; reserve, production, imports and exports, electricity and refining capacities; deregulation of prices, subsidies, taxes; consumption trends by sector, energy market shares; main energy projects, production and consumption prospects. Statistical Profiles are present in about 3 pages the main data and indicators on oil, gas, coal and electricity. (A.L.B.)

Use of a radio-frequency resonance circuit in studies of alkali ionization in flames

International Nuclear Information System (INIS)

Borgers, A.J.

1978-01-01

The construction of a radio-frequency resonance system and its use in the study of alkali metal ionization in flames is described. The author re-determines the values of the alkali ionization rate constants for a CO flame with N 2 as diluent gas of known temperature using the RF resonance method. (Auth.)

Fundamentals of gas counters

International Nuclear Information System (INIS)

Bateman, J.E.

1994-01-01

The operation of gas counters used for detecting radiation is explained in terms of the four fundamental physical processes which govern their operation. These are 1) conversion of neutral radiation into charged particles, 2) ionization of the host gas by a fast charge particle 3) transport of the gas ions to the electrodes and 4) amplification of the electrons in a region of enhanced electric field. Practical implications of these are illustrated. (UK)

Vertical seismic profile data from well Mallik 2L-38 for gas hydrate studies

Energy Technology Data Exchange (ETDEWEB)

Mi, Y [Calgary Univ., AB (Canada); Walia, R [Victoria Univ., BC (Canada); Hyndman, R D; Sakai, A

1999-01-01

A gas hydrate research well was drilled in the Canadian Arctic to determine gas hydrates in a permafrost setting in a collaborative research project between the Japan National Oil Corp., and the Geological Survey of Canada with the participation of other agencies. The multidisciplinary study included an electromagnetic survey, permafrost and gas hydrate coring, and comprehensive downhole geophysical logging and measurement. Laboratory studies on recovered cores and cuttings included sedimentology, physical properties, geochemistry, and reservoir characteristics of the Mallik gas accumulation. As part of the field program, a vertical seismic profiling survey was conducted at zero and offset source positions with 3 component receiver tools and horizontal and vertical vibration sources. A special effort was made to record shear wave data, and results from this work were combined with down hole logs and regional surface seismic data. The data will be used also to determine the effect of gas hydrates on formation velocities and to measure gas hydrate concentrations as a function of depth in the formation penetrated by the well. Certain conclusions followed from the initial VSP analysis. 1) Zero offset vertical vibration Z component and horizontal X component data give reliable velocity estimation within the gas hydrate formation zone, and P wave velocities from offset data indicate excellent consistency with that from zero offset data and with the sonic log. 2) The VSP data permitted reliable identification of gas hydrate bearing zones. 4 refs.