WorldWideScience

Sample records for fuelling direct hydrazine

  1. Direct-fuelled fuel cells

    Science.gov (United States)

    Waidhas, M.; Drenckhahn, W.; Preidel, W.; Landes, H.

    Fuel supply is one important problem to be solved for commercial application of fuel cell technology. Conventional fuel-cell types require hydrogen as the fuel, which has to be free from impurities when operated at temperatures below 100 °C. The storage and distribution of this explosive and extremely fugitive gas is one of the open questions in the context of a customer-oriented broad commercial market. The direct-fuelled fuel cells (DMFCs) overcome the hydrogen specific restrictions. They are capable of directly using natural gas or fuels which are liquid under ambient conditions. In this paper the different options from direct-fuelled systems are described and their general aspects discussed. The state-of-the-art at Siemens in this field, and also the remaining technical questions are outlined as a basis for assessing future applications.

  2. The catalysis of hydrazines

    Science.gov (United States)

    Tanatar, S.

    1987-01-01

    Hydrazine sulfate in a hot aqueous solution can be catalyzed in the direction of 3 N2H4 = 4 NH3 + N2. Free hydrazine in a hot aqueous solution dissociates in the presence of platinum in the following direction: 2 N2H4 = 2 NH3 + N2 + H2. In the presence of sodium hydroxide, the catalytic dissociation of hydrazine takes a third direction: 3 N2H4 = 2 NH3 + 2 N3 + 3 H2.

  3. Performance evaluation of common rail direct injection (CRDI engine fuelled with Uppage Oil Methyl Ester (UOME

    Directory of Open Access Journals (Sweden)

    D.N. Basavarajappa

    2015-02-01

    Full Text Available For economic and social development of any country energy is one of the most essential requirements. Continuously increasing price of crude petroleum fuels in the present days coupled with alarming emissions and stringent emission regulations has led to growing attention towards use of alternative fuels like vegetable oils, alcoholic and gaseous fuels for diesel engine applications. Use of such fuels can ease the burden on the economy by curtailing the fuel imports. Diesel engines are highly efficient and the main problems associated with them is their high smoke and NOx emissions. Hence there is an urgent need to promote the use of alternative fuels in place of high speed diesel (HSD as substitute. India has a large agriculture base that can be used as a feed stock to obtain newer fuel which is renewable and sustainable. Accordingly Uppage oil methyl ester (UOME biodiesel was selected as an alternative fuel. Use of biodiesels in diesel engines fitted with mechanical fuel injection systems has limitation on the injector opening pressure (300 bar. CRDI system can overcome this drawback by injecting fuel at very high pressures (1500-2500 bar and is most suitable for biodiesel fuels which are high viscous. This paper presents the performance and emission characteristics of a CRDI diesel engine fuelled with UOME biodiesel at different injection timings and injection pressures. From the experimental evidence it was revealed that UOME biodiesel yielded overall better performance with reduced emissions at retarded injection timing of -10° BTDC in CRDI mode of engine operation.

  4. Performance evaluation of common rail direct injection (CRDI engine fuelled with Uppage Oil Methyl Ester (UOME

    Directory of Open Access Journals (Sweden)

    D.N. Basavarajappa

    2015-02-01

    Full Text Available For economic and social development of any country energy is one of the most essential requirements. Continuously increasing price of crude petroleum fuels in the present days coupled with alarming emissions and stringent emission regulations has led to growing attention towards use of alternative fuels like vegetable oils, alcoholic and gaseous fuels for diesel engine applications. Use of such fuels can ease the burden on the economy by curtailing the fuel imports. Diesel engines are highly efficient and the main problems associated with them is their high smoke and NOx emissions.  Hence there is an urgent need to promote the use of alternative fuels in place of high speed diesel (HSD as substitute. India has a large agriculture base that can be used as a feed stock to obtain newer fuel which is renewable and sustainable. Accordingly Uppage oil methyl ester (UOME biodiesel was selected as an alternative fuel. Use of biodiesels in diesel engines fitted with mechanical fuel injection systems has limitation on the injector opening pressure (300 bar. CRDI system can overcome this drawback by injecting fuel at very high pressures (1500-2500 bar and is most suitable for biodiesel fuels which are high viscous. This paper presents the performance and emission characteristics of a CRDI diesel engine fuelled with UOME biodiesel at different injection timings and injection pressures. From the experimental evidence it was revealed that UOME biodiesel yielded overall better performance with reduced emissions at retarded injection timing of -10° BTDC in CRDI mode of engine operation.

  5. Hydrogen Fuelling Stations

    DEFF Research Database (Denmark)

    Rothuizen, Erasmus Damgaard

    This thesis concerns hydrogen fuelling stations from an overall system perspective. The study investigates thermodynamics and energy consumption of hydrogen fuelling stations for fuelling vehicles for personal transportation. For the study a library concerning the components in a hydrogen fuelling...... station has been developed in Dymola. The models include the fuelling protocol (J2601) for hydrogen vehicles made by Society of Automotive Engineers (SAE) and the thermodynamic property library CoolProp is used for retrieving state point. The components in the hydrogen fuelling library are building up....... A system consisting of one high pressure storage tank is used to investigate the thermodynamics of fuelling a hydrogen vehicle. The results show that the decisive parameter for how the fuelling proceeds is the pressure loss in the vehicle. The single tank fuelling system is compared to a cascade fuelling...

  6. Investigation of the direct and indirect electrochemical oxidation of hydrazine in nitric acid medium on platinum; Etude de l`oxydation electrochimique directe et indirecte de l`hydrazine en milieu acide nitrique sur platine

    Energy Technology Data Exchange (ETDEWEB)

    Cames, B

    1997-12-31

    allow consideration of the process of direct electrochemical oxidation of hydrazine to nitrogen, and of Pu(III) to Pu(IV), with electrochemical yields of 100 %. (author) 59 refs.

  7. Does migratory distance affect fuelling in a medium-distance passerine migrant?: results from direct and step-wise simulated magnetic displacements

    Directory of Open Access Journals (Sweden)

    Mihaela Ilieva

    2016-03-01

    Full Text Available In birds, fat accumulation before and during migration has been shown to be endogenously controlled and tuned by, among other factors, the Earth's magnetic field. However, our knowledge about the influence of the geomagnetic field on the fuelling in migrating birds is still limited to just a few nocturnally migrating passerine species. In order to study if variations of the magnetic field can also influence the fuelling of both day- and night-migrating passerines, we caught first-year dunnocks (Prunella modularis and subjected them to three magnetic field conditions simulated by a system of magnetic coils: (1 local geomagnetic field of southern Sweden, (2 magnetic field corresponding to the centre of the expected wintering area, and (3 magnetic field met at the northern limit of the species' breeding distribution. We did not find a difference in mass increase between the birds kept in a local magnetic field and a field resembling their wintering area, irrespectively of the mode of magnetic displacement, i.e. direct or step-wise. However, the dunnocks magnetically displaced north showed a lower rate of fuelling in comparison to the control group, probably due to elevated activity. Compared with previous studies, our results suggest that the fuelling response to magnetic displacements during the migration period is specific to the eco-physiological situation. Future studies need to address if there is an effect of magnetic field manipulation on the level of migratory activity in dunnocks and how widespread the influence of local geomagnetic field parameters is on fuelling decisions in different bird species, which have different migratory strategies, distances and migration history.

  8. Effects of hydrazine addition on gas evolution and performance of the direct borohydride fuel cell

    Science.gov (United States)

    Qin, H. Y.; Liu, Z. X.; Yin, W. X.; Zhu, J. K.; Li, Z. P.

    A fuel cell configuration using alkaline NaBH 4-N 2H 4 solutions as the fuel is suggested. Gas evolution behaviors and cell performances of alkaline NaBH 4-N 2H 4 solutions on different catalysts have been studied. It is found that gas evolution behaviors are influenced by the applied anodic catalysts and the concentration of NaBH 4 and N 2H 4. NaBH 4 is mainly electro-oxidized on Pd but N 2H 4 is mainly electro-oxidized on Ni and surface-treated Zr-Ni alloy when using NaBH 4-N 2H 4 solutions as the fuel and a composite of Pd, Ni and surface-treated Zr-Ni alloy as the anodic catalyst. The cyclic voltammetry results show that electrochemical oxidation potential of NaBH 4 is higher than that of N 2H 4. Adding hydrazine into alkaline sodium borohydride solutions can suppress gas evolution and improve the cell performance of the DBFC. The performances of fuel cells using NaBH 4-N 2H 4 solutions are comparable to that of fuel cell using N 2H 4 solution.

  9. Performance improvement of direct internal reforming solid oxide fuel cell fuelled by H2S-contaminated biogas with paper-structured catalyst technology

    Science.gov (United States)

    Shiratori, Y.; Sakamoto, M.

    2016-11-01

    Direct internal reforming (DIR) operation of a solid oxide fuel cell (SOFC) is a very attractive concept for downsizing and cost reduction of SOFC systems. This study aimed to develop stable operation of a DIR-SOFC fuelled by biogas. The current-voltage (I-V) curves of 2 × 2 cm2 planar SOFCs (anode- and electrolyte-supported cells, ASC and ESC, respectively.) were measured at 800 °C in the direct feed of a simulated biogas mixture (CH4/CO2 = 1), and the flexible structured catalyst material (paper-structured catalyst (PSC)) was applied on the anode material for performance enhancement. By applying a hydrotalcite (HT)-dispersed PSC (HT-PSC), the sulfur tolerance of the SOFC in the DIR operation was remarkably improved. By the effect of the HT-PSC, for both ASC and ESC, a stable cell voltage higher than 800 mV was obtained over 200 h at 0.2 A cm-2 in the direct feed of simulated biogas under 5 ppm H2S poisoning.

  10. CHARACTERISTICS OF PERFORMANCE AND EMISSIONS IN A DIRECT-INJECTION DIESEL ENGINE FUELLED WITH KEROSENE/DIESEL BLENDS

    National Research Council Canada - National Science Library

    K R Patil; S S Thipse

    2014-01-01

      An experimental investigation has been carried out to evaluate the effect of kerosene as an additive to diesel fuel on the combustion, performance and emission characteristics of a direct-injection...

  11. In-situ visualization of N2 evolution in operating direct hydrazine hydrate fuel cell by soft X-ray radiography

    Science.gov (United States)

    Sakamoto, Tomokazu; Deevanhxay, Phengxay; Asazawa, Koichiro; Tsushima, Shohji; Hirai, Shuichiro; Tanaka, Hirohisa

    2014-04-01

    Soft X-ray radiography technique was firstly applied to operating direct hydrazine hydrate fuel cell (DHFCs) in order to visualize N2 gas behaviors with high spatial and temporal resolution. Two different cells for in-situ visualization of N2 gas in the DHFCs in in-plane and through-plane direction were designed and fabricated. The utilization of soft X-ray made the visualization of generated N2 behavior in the DHFC possible with the spatial resolution of 1.5 μm and the temporal resolution of 2.0 s frame-1. In the in-plane visualization, the inhomogeneous N2 gas distribution, suggesting non-uniform reaction distribution in the anode of DHFC, was observed. In the through-plane visualization, N2 gas accumulation under the rib of anode and discharge to the channel was clearly observed, which are related with cell performance instability.

  12. Hydrazine inactivates bacillus spores

    Science.gov (United States)

    Schubert, Wayne; Plett, G. A.; Yavrouian, A. H.; Barengoltz, J.

    2005-01-01

    Planetary Protection places requirements on the maximum number of viable bacterial spores that may be delivered by a spacecraft to another solar system body. Therefore, for such space missions, the spores that may be found in hydrazine are of concern. A proposed change in processing procedures that eliminated a 0.2 um filtration step propmpted this study to ensure microbial contamination issue existed, especially since no information was found in the literature to substantiate bacterial spore inactivation by hydrazine.

  13. COMPLEXES CONTAINING HYDRAZINE AND BENZYL ...

    African Journals Online (AJOL)

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    In previous reports, anhydrous hydrazine and substituted hydrazine were ... DRX 250 spectrometer while that of 3 was recorded on a Bruker 300 MHz instrument at ... The hydrazine complex was prepared from the polymer [{RuCl2(COD)}x] by the ... solution and the acetone was removed under reduced pressure and a white ...

  14. Considerations on the DEMO pellet fuelling system

    Energy Technology Data Exchange (ETDEWEB)

    Lang, P.T., E-mail: peter.lang@ipp.mpg.de [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany); Day, Ch. [Karlsruhe Institute of Technology, 76021 Karlsruhe (Germany); Fable, E. [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany); Igitkhanov, Y. [Karlsruhe Institute of Technology, 76021 Karlsruhe (Germany); Köchl, F. [Association EURATOM-Ö AW/ATI, Atominstitut, TU Wien, 1020 Vienna (Austria); Mooney, R. [Culham Centre for Fusion Energy, Culham Science Centre, Oxfordshire OX14 3DB (United Kingdom); Pegourie, B. [CEA, IRFM, 13108 Saint-Paul-lez-Durance (France); Ploeckl, B. [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany); Wenninger, R. [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany); EFDA, Garching (Germany); Zohm, H. [Max-Planck-Institut für Plasmaphysik, Boltzmannstr. 2, 85748 Garching (Germany)

    2015-10-15

    Graphical abstract: - Highlights: • Considerations are made for a core particle fuelling system covering all DEMO requirements. • Particle deposition beyond the pedestal top is needed to achieve efficient fuelling. • Conventional pellet technology enabling launching from the torus inboard side can be used. • Efforts have been taken for integrating a suitable pellet guiding system into the EU DEMO model. • In addition, further techniques bearing potential for advanced fuelling performance are considered. - Abstract: The Demonstration Fusion Power Reactor DEMO is the step foreseen to bridge the gap between ITER and the first commercial fusion power plant. One key element in the European work plan for DEMO is the elaboration of a conceptual design for a suitable core particle fuelling system. First considerations for such a system are presented in this contribution. Following the well-considered ITER solution, most analysis performed in this study assumes conventional pellet technology will be used for the fuelling system. However, taking advantage of the less compressed time frame for the DEMO project, several other techniques thought to bear potential for advanced fuelling performance are considered as well. In a first, basic analysis all actuation parameters at hand and their implications on the fuelling performance were considered. Tentative transport modeling of a reference scenario strongly indicates only particles deposited inside the plasma pedestal allow for efficient fuelling. Shallow edge fuelling results in an unbearable burden on the fuel cycle. Sufficiently deep particle deposition seems technically achievable, provided pellets are launched from the torus inboard at sufficient speed. All components required for a DEMO pellet system capable for high speed inboard pellet launch are already available or can be developed in due time with reasonable efforts. Furthermore, steps to integrate this solution into the EU DEMO model are taken.

  15. Great Market Potential of Hydrazine Hydrate

    Institute of Scientific and Technical Information of China (English)

    Shi Yuying

    2007-01-01

    @@ Stable consumption growth worldwide Hydrazine hydrate is an organic chemical raw material with extensive applications. The world's capacity to produce hydrazine hydrate has reached more than 200 thousand t/atoday (based on 100% hydrazine content).

  16. Combustion characteristics of a 4-stroke CI engine operated on Honge oil, Neem and Rice Bran oils when directly injected and dual fuelled with producer gas induction

    Energy Technology Data Exchange (ETDEWEB)

    Banapurmath, N.R.; Tewari, P.G. [Department of Mechanical Engineering, B.V.B. College of Engineering and Technology, Hubli 580031, Karnataka (India); Yaliwal, V.S. [Department of Mechanical Engineering, SDM College of Engineering and Technology, Dharwad Karnataka (India); Kambalimath, Satish [Wipro Technologies (India); Basavarajappa, Y.H. [K.L.E. Society' s Polytechnic, Hubli (India)

    2009-07-15

    Energy is an essential requirement for economic and social development of any country. Sky rocketing of petroleum fuel costs in present day has led to growing interest in alternative fuels like vegetable oils, alcoholic fuels, CNG, LPG, Producer gas, biogas in order to provide a suitable substitute to diesel for a compression ignition (CI) engine. The vegetable oils present a very promising alternative fuel to diesel oil since they are renewable, biodegradable and clean burning fuel having similar properties as that of diesel. They offer almost same power output with slightly lower thermal efficiency due to their lower energy content compared to diesel. Utilization of producer gas in CI engine on dual fuel mode provides an effective approach towards conservation of diesel fuel. Gasification involves conversion of solid biomass into combustible gases which completes combustion in a CI engines. Hence the producer gas can act as promising alternative fuel and it has high octane number (100-105) and calorific value (5-6 MJ/Nm{sup 3}). Because of its simpler structure with low carbon content results in substantial reduction of exhaust emission. Downdraft moving bed gasifier coupled with compression ignition engine are a good choice for moderate quantities of available mass up to 500 kW of electrical power. Hence bio-derived gas and vegetable liquids appear more attractive in view of their friendly environmental nature. Experiments have been conducted on a single cylinder, four-stroke, direct injection, water-cooled CI engine operated in single fuel mode using Honge, Neem and Rice Bran oils. In dual fuel mode combinations of Producer gas and three oils were used at different injection timings and injection pressures. Dual fuel mode of operation resulted in poor performance at all the loads when compared with single fuel mode at all injection timings tested. However, the brake thermal efficiency is improved marginally when the injection timing was advanced. Decreased

  17. Distributed power generation using biogas fuelled microturbines

    Energy Technology Data Exchange (ETDEWEB)

    Pointon, K.; Langan, M.

    2002-07-01

    This research sought to analyse the market for small scale biogas fuelled distributed power generation, to demonstrate the concept of a biogas fuelled microturbine using the Capstone microturbine in conjunction with an anaerobic digester, and undertake a technico-economic evaluation of the biogas fuelled microturbine concept. Details are given of the experimental trials using continuous and batch digesters, and feedstocks ranging from cow and pig slurries to vegetable wastes and municipal solid waste. The yields of methane are discussed along with the successful operation of the microturbine with biogas fuels, and anaerobic digestion projects.

  18. Toxicity assessment of hydrazine fuels

    Energy Technology Data Exchange (ETDEWEB)

    Keller, W.C.

    1988-11-01

    The major health aspects of exposure to hydrazine propellants are reviewed. Toxic effects of hydrazine fuels on humans and animals as well as in vitro studies are discussed with emphasis on recent findings and USAF studies. Propellant hydrazines have been found to be genotoxic in in vitro studies and oncogenic in animal studies. Embryotoxicity has been demonstrated at very high exposures but not at occupationally encountered levels for hydrazine and unsymmetrical dimethylhydrazine. Epidemiologic evidence to support these findings is lacking; however, the results of animal and in vitro studies have resulted in lowering both the time-weighted average-threshold limit values and short-term exposure limits for these propellants.

  19. Sensitized Liquid Hydrazine Detonation Studies

    Science.gov (United States)

    Rathgeber, K. A.; Keddy, C. P.; Bunker, R. L.

    1999-01-01

    Vapor-phase hydrazine (N2H4) is known to be very sensitive to detonation while liquid hydrazine is very insensitive to detonation, theoretically requiring extremely high pressures to induce initiation. A review of literature on solid and liquid explosives shows that when pure explosive substances are infiltrated with gas cavities, voids, and/or different phase contaminants, the energy or shock pressure necessary to induce detonation can decrease by an order of magnitude. Tests were conducted with liquid hydrazine in a modified card-gap configuration. Sensitization was attempted by bubbling helium gas through and/or suspending ceramic microspheres in the liquid. The hydrazine was subjected to the shock pressure from a 2 lb (0.9 kg) Composition C-4 explosive charge. The hydrazine was contained in a 4 in. (10.2 cm) diameter stainless steel cylinder with a 122 in(sup 3) (2 L) volume and sealed with a polyethylene cap. Blast pressures from the events were recorded by 63 high speed pressure transducers located on three radial legs extending from 4 to 115 ft (1.2 to 35.1 in) from ground zero. Comparison of the neat hydrazine and water baseline tests with the "sensitized" hydrazine tests indicates the liquid hydrazine did not detonate under these conditions.

  20. Environmental Fate of Hydrazines

    Science.gov (United States)

    1989-12-01

    v/v. The absorbent cartridges removed trace gas contaminants , including remaining water and CO2 . Gas outlet-valves after each unit provided for air...largest kbkg was observed in Run A, presumably due to the interaction of hydrazine vapor with contamination on the chamber walls accumulated during its...64 UDMH Dry Air 2.8 19 13 1.1 a Ambirnt temperature, 50-75 ppm v/v initial concentrationb 24 m of added FEP c 14,700 ppm v/v water vapor Of these

  1. Hydrazine vapor inactivates Bacillus spores

    Science.gov (United States)

    Schubert, Wayne W.; Engler, Diane L.; Beaudet, Robert A.

    2016-05-01

    NASA policy restricts the total number of bacterial spores that can remain on a spacecraft traveling to any planetary body which might harbor life or have evidence of past life. Hydrazine, N2H4, is commonly used as a propellant on spacecraft. Hydrazine as a liquid is known to inactivate bacterial spores. We have now verified that hydrazine vapor also inactivates bacterial spores. After Bacillus atrophaeus ATCC 9372 spores deposited on stainless steel coupons were exposed to saturated hydrazine vapor in closed containers, the spores were recovered from the coupons, serially diluted, pour plated and the surviving bacterial colonies were counted. The exposure times required to reduce the spore population by a factor of ten, known as the D-value, were 4.70 ± 0.50 h at 25 °C and 2.85 ± 0.13 h at 35 °C. These inactivation rates are short enough to ensure that the bioburden of the surfaces and volumes would be negligible after prolonged exposure to hydrazine vapor. Thus, all the propellant tubing and internal tank surfaces exposed to hydrazine vapor do not contribute to the total spore count.

  2. Electrochemical Disposal of Hydrazines in Water

    Science.gov (United States)

    Kim, Jinseong; Gonzalez-Mar, Anuncia; Salinas, Carlos; Rutherford, Larris; Jeng, King-Tsai; Andrews, Craig; Yalamanchili, Ratlaya

    2007-01-01

    An electrochemical method of disposal of hydrazines dissolved in water has been devised. The method is applicable to hydrazine (N2H4), to monomethyl hydrazine [also denoted by MMH or by its chemical formula, (CH3)HNNH2], and to unsymmetrical dimethyl hydrazine [also denoted UDMH or by its chemical formula, (CH3)2NNH2]. The method involves a room-temperature process that converts the hydrazine to the harmless products N2, H2O, and, in some cases, CO2

  3. Performance Test of Engine Fuelled With Diesel and Ethanol Blends.

    Directory of Open Access Journals (Sweden)

    B.K.L.Murthy

    2015-04-01

    Full Text Available Environmental concerns and limited amount of petroleum fuels have caused interests in the development of alternative fuels for internal combustion (ICengines. As an alternative, biodegradable and renewable fuel, ethanol is receiving increasing attention. An experimental investigation on the application of the blends of ethanol with diesel to a diesel engine was carried out. First the solubility of ethanol and diesel was conducted with and without the additive of normal butanol (n-butanol. The purpose of this project is to find the optimum percentage of ethanol that gives simultaneously better performance and lower emissions. The experiments were conducted on a water-cooled single-cylinder Direct Injection (DI diesel engine using 0% (neat diesel fuel, 10% (E10-D, 15%(E15–D, 20% (E20–D, and 25%(E25–D ethanol–diesel blended fuels. Experimental tests were carried out to study the performance of the engine fuelled with the blends compared with those fuelled by diesel. The test results show that it is feasible and applicable for the blends with n-butanol to replace pure diesel as the fuel for diesel engine.

  4. Occupational safety considerations with hydrazine

    Science.gov (United States)

    Clewell, Harvey J., III; Mcdougal, James N.; George, Marilyn E.; Andersen, Melvin E.

    1992-01-01

    Hydrazine is a reducing agent that is most commonly used as a propellant and as an oxygen scavenger in boilers. Hydrazine is extremely irritating and has been demonstrated to produce both acute and chronic toxicity. As a result, the established permissible inhalation exposure limits are very low, and respiration protection is required whenever vapors are present. Liquid hydrazine penetrates the skin and produces a chemical burn; therefore, some protective measures must also be taken to protect the skin from liquid contact. Often, however, a cumbersome, whole-body protective suit is worn to protect against skin contact with vapor as well. To what extent it is actually necessary to protect skin from vapor penetration had not previously been demonstrated. In an attempt to answer this question, we conducted a study with rats to compare the dermal penetration of hydrazine vapor with inhalation. Pharmacokinetic modeling was used to compare body burdens resulting from these different routes of exposure. The analysis concluded that the vapor concentration during a skin-only exposure would have to be at least 200 times higher than that during inhalation to achieve the same body burden. This type of estimation illustrates the use of predictive toxicology in occupational exposures.

  5. LNG fuelling for mine trucks

    Energy Technology Data Exchange (ETDEWEB)

    Melanson, B.E.; Hodgins, K.B. [Westport Innovations Inc., Vancouver, BC (Canada)

    2006-07-01

    Diesel-powered mine haul trucks consume large amounts of fuel. The diesel engines provide the trucks with the flexibility to readily move material while optimizing speed and efficiency. However, the high cost for diesel fuel has prompted the need for lower-cost solutions. Since many mining regions have access to low-cost liquefied natural gas (LNG) feedstock through indigenous natural gas resources and coal mine methane, the use of LNG for mine haul trucks offers a solution to lower operating costs. In addition to reducing the reliance on petroleum resources, the use of LNG would also contribute to a reduction in noise, air pollutants, and greenhouse gas emissions. This presentation demonstrated that significant fuel cost savings can be realized in regions where LNG has cost advantage to diesel fuel. High pressure direct injection (HPDI) of natural gas in a compression ignition engine offers the high performance and efficiency characteristics of diesel engines while reducing particulate matter, nitrogen oxides, sulphur oxides and greenhouse gases. HPDI has been demonstrated in on-road Class 8 trucks since 2001 and mine haul trucks are now considered a prime target for implementing change to lower-carbon gaseous fuels. The supply of LNG fuel will be a necessary aspect of the introduction of HPDI to mining. LNG can be transported to mine sites or it can be produced on or near mining operations that have access to methane sources or pipelines. It was concluded that HPDI powered mine trucks offer a safe, economic and environmentally progressive solution for mine operators. 2 figs.

  6. Active Hydrazine Vapor Sampler (AHVS)

    Science.gov (United States)

    Young, Rebecca C.; Mcbrearty, Charles F.; Curran, Daniel J.

    1993-01-01

    The Active Hydrazine Vapor Sampler (AHVS) was developed to detect vapors of hydrazine (HZ) and monomethylhydrazine (MMH) in air at parts-per-billion (ppb) concentration levels. The sampler consists of a commercial personal pump that draws ambient air through paper tape treated with vanillin (4-hydroxy-3-methoxybenzaldehyde). The paper tape is sandwiched in a thin cardboard housing inserted in one of the two specially designed holders to facilitate sampling. Contaminated air reacts with vanillin to develop a yellow color. The density of the color is proportional to the concentration of HZ or MMH. The AHVS can detect 10 ppb in less than 5 minutes. The sampler is easy to use, low cost, and intrinsically safe and contains no toxic material. It is most beneficial for use in locations with no laboratory capabilities for instrumentation calibration. This paper reviews the development, laboratory test, and field test of the device.

  7. The Oxidation of Hydrazine by Nitric Acid

    Energy Technology Data Exchange (ETDEWEB)

    Karraker, D.G.

    2001-07-02

    Hydrazine nitrate-nitric acid solutions are used in the ion exchange process for separating Pu-238 and Np-237 and have been found to dissolve plutonium metal in a manner advantageous to SRP metal recovery operations. Laboratory tests on the stability of hydrazine in nitric acid solutions were performed to obtain accurate data, and the results of these tests are reported here. These tests provide sufficient information to specify temperature control for hydrazine-nitric acid solutions in plant processes.

  8. Inflow of atomic gas fuelling star formation

    DEFF Research Database (Denmark)

    Michałowski, M. J.; Gentile, G.; Hjorth, Jeppe;

    2016-01-01

    Gamma-ray burst host galaxies are deficient in molecular gas, and show anomalous metal-poor regions close to GRB positions. Using recent Australia Telescope Compact Array (ATCA) Hi observations we show that they have substantial atomic gas reservoirs. This suggests that star formation in these ga......Gamma-ray burst host galaxies are deficient in molecular gas, and show anomalous metal-poor regions close to GRB positions. Using recent Australia Telescope Compact Array (ATCA) Hi observations we show that they have substantial atomic gas reservoirs. This suggests that star formation...... in these galaxies may be fuelled by recent inflow of metal-poor atomic gas. While this process is debated, it can happen in low-metallicity gas near the onset of star formation because gas cooling (necessary for star formation) is faster than the Hi-to-H2 conversion....

  9. New Challenge to the Existing Fuelling Technique for ITER

    Institute of Scientific and Technical Information of China (English)

    DENGBaiquan; PENGLilin

    2003-01-01

    A new challenge to the existing pellet fuelling technique for the International Thermonuclear Experimental Reactor (ITER) has been discussed by computing ablation rate using Kuteev lentil model with considering the kinetic effects. Numerical integral results show the existing pellet injection technique will be difficult to meet the deep fuelling requirement for the reactor relevant plasma of ITER. As high as a pressure of 254 MPa should be applied to the pellet accelerator of 2-meters long single stage pneumatic gun,

  10. Development of a Wood Powder Fuelled 35 kW Stirling CHP Unit

    DEFF Research Database (Denmark)

    Pålsson, M.; Carlsen, Henrik

    2003-01-01

    For biomass fuelled CHP in sizes below 100 kW, Stirling engines are the only feasible alternative today. Using wood powder as fuel, the Stirling engine can be heated directly by the flame like when using a gaseous or liquid fuel burner. However, the combustion chamber will have to be much larger...... recirculation (CGR) a smaller air preheater can be used, while system efficiency will increase compared with using excess air for flame cooling. In a three-year project, a wood powder fuelled Stirling engine CHP unit will be developed and run in field test. The project will use the double-acting four......, using wood powder as fuel will be developed at Lund University, Sweden, in cooperation with the Technical University of Denmark and with the wood powder boiler manufacturer VTS AB. The unit is to be run in CHP operation by Vattenfall - the largest electric power company in Sweden - in a one-year field...

  11. Mars to orbit with pumped hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Whitehead, J C

    1999-04-27

    A propulsion point design is presented for lifting geological samples from Mars. Vehicle complexity is kept low by choosing a monopropellant single stage. Little new development is needed, as miniature pump fed hydrazine has been demonstrated. Loading the propellant just prior to operation avoids structural, thermal, and safety constraints otherwise imposed by earlier mission phases. Hardware mass and engineering effort are thereby diminished. The Mars liftoff mass is 7/8 hydrazine, <5% propulsion hardware, and >3% each for the payload and guidance.

  12. Occupational safety considerations with hydrazine fuels

    Science.gov (United States)

    Clewell, H. J.; Haddad, T. S.; George, M. E.; Mcdougal, J. N.; Andersen, M. E.

    1992-01-01

    A simple pharmacokinetic model and a specially designed dermal vapor exposure chamber which provides respiratory protection were used to determine the rate of penetration of hydrazine and 1,1-dimethylhydrazine (UDMH) vapor through the skin of rats. Parameters for the pharmacokinetic model were determined from intravenous and inhalation exposure data. The model was then used to estimate the skin permeation coefficient for hydrazine or UDMH vapor from the dermal-vapor exposure data. This analysis indicates that UDMH vapor has a relatively high permeability through skin (0.7 cm/hr), a value somewhat higher than was obtained for hydrazine by the same procedure (0.09 cm/hr). Based on these skin permeability results, a skin-only vapor exposure limit giving protection equivalent to the inhalation Threshold Limit Value (TLV) could be calculated. The current TLV's for UDMH and hydrazine are 0.5 and 0.1 ppm, respectively. The corresponding skin-only TLV equivalents, for personnel wearing respiratory protection, are 32 ppm for UDMH and 48 ppm for hydrazine. Should the proposed lowering to the TLV's for these compounds to 0.01 ppm be adopted, the equivalent skin-only TLV's would become 0.64 ppm for UDMH and 4.8 for hydrazine.

  13. Destruction of Hydrazine and Corrosion Monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Won, H. J.; Park, S. Y.; Kim, S. B.; Jung, J. Y.; Choi, W. K.; Moon, J. K. [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    KAERI The agent uses Cu ion and hydrazine in an inorganic acid solution. This agent is used for the dissolution of Fe and Ni ions in a spinel type nickel chromium ferrite. After decontamination, the generation of the secondary waste can be reduced by the destruction of hydrazine. Wellman et al. reported that hydrazine is decomposed to water and nitrogen by hydrogen peroxide in the presence of Cu{sup 2+} ion. N{sub 2}H{sub 4}+2H{sub 2}0{sub 2} (Cu{sup 2+} →) N{sub 2} +4H{sub 2}0 As the decrease of the hydrazine concentration, the solution pH also becomes to decrease. The decrease of solution pH can affect the integrity of structural metal. The objective of the study is to investigate the decomposition characteristics of hydrazine by hydrogen peroxide. The corrosion compatibility of metal after the decomposition of hydrazine is also investigated. The application of a decontamination solution to the primary coolant system before decommissioning is necessary to minimize the personnel dose rates. In foreign countries, system decontaminations have been performed several times by applying the dilute organic chemical decontamination process. To prepare against the decommissioning of the nuclear power plant, it is necessary to develop the unique domestic chemical decontamination process.

  14. An autonomous chemically fuelled small-molecule motor

    Science.gov (United States)

    Wilson, Miriam R.; Solà, Jordi; Carlone, Armando; Goldup, Stephen M.; Lebrasseur, Nathalie; Leigh, David A.

    2016-06-01

    Molecular machines are among the most complex of all functional molecules and lie at the heart of nearly every biological process. A number of synthetic small-molecule machines have been developed, including molecular muscles, synthesizers, pumps, walkers, transporters and light-driven and electrically driven rotary motors. However, although biological molecular motors are powered by chemical gradients or the hydrolysis of adenosine triphosphate (ATP), so far there are no synthetic small-molecule motors that can operate autonomously using chemical energy (that is, the components move with net directionality as long as a chemical fuel is present). Here we describe a system in which a small molecular ring (macrocycle) is continuously transported directionally around a cyclic molecular track when powered by irreversible reactions of a chemical fuel, 9-fluorenylmethoxycarbonyl chloride. Key to the design is that the rate of reaction of this fuel with reactive sites on the cyclic track is faster when the macrocycle is far from the reactive site than when it is near to it. We find that a bulky pyridine-based catalyst promotes carbonate-forming reactions that ratchet the displacement of the macrocycle away from the reactive sites on the track. Under reaction conditions where both attachment and cleavage of the 9-fluorenylmethoxycarbonyl groups occur through different processes, and the cleavage reaction occurs at a rate independent of macrocycle location, net directional rotation of the molecular motor continues for as long as unreacted fuel remains. We anticipate that autonomous chemically fuelled molecular motors will find application as engines in molecular nanotechnology.

  15. Ionic Liquids to Replace Hydrazine

    Science.gov (United States)

    Koelfgen, Syri; Sims, Joe; Forton, Melissa; Allan, Barry; Rogers, Robin; Shamshina, Julia

    2011-01-01

    A method for developing safe, easy-to-handle propellants has been developed based upon ionic liquids (ILs) or their eutectic mixtures. An IL is a binary combination of a typically organic cation and anion, which generally produces an ionic salt with a melting point below 100 deg C. Many ILs have melting points near, or even below, room temperature (room temperature ionic liquids, RTILs). More importantly, a number of ILs have a positive enthalpy of formation. This means the thermal energy released during decomposition reactions makes energetic ILs ideal for use as propellants. In this specific work, to date, a baseline set of energetic ILs has been identified, synthesized, and characterized. Many of the ILs in this set have excellent performance potential in their own right. In all, ten ILs were characterized for their enthalpy of formation, density, melting point, glass transition point (if applicable), and decomposition temperature. Enthalpy of formation was measured using a microcalorimeter designed specifically to test milligram amounts of energetic materials. Of the ten ILs characterized, five offer higher Isp performance than hydrazine, ranging between 10 and 113 seconds higher than the state-of-the-art propellant. To achieve this level of performance, the energetic cations 4- amino-l,2,4-triazolium and 3-amino-1,2,4-triazolium were paired with various anions in the nitrate, dicyanamide, chloride, and 3-nitro-l,2,4-triazole families. Protonation, alkylation, and butylation synthesis routes were used for creation of the different salts.

  16. Microstability analysis of pellet fuelled discharges in MAST

    CERN Document Server

    Garzotti, L; Roach, C M; Valovic, M; Dickinson, D; Naylor, G; Romanelli, M; Scannell, R; Szepesi, G

    2014-01-01

    Reactor grade plasmas are likely to be fuelled by pellet injection. This technique transiently perturbs the profiles, driving the density profile hollow and flattening the edge temperature profile. After the pellet perturbation, the density and temperature profiles relax towards their quasi-steady-state shape. Microinstabilities influence plasma confinement and will play a role in determining the evolution of the profiles in pellet fuelled plasmas. In this paper we present the microstability analysis of pellet fuelled H-mode MAST plasmas. Taking advantage of the unique capabilities of the MAST Thomson scattering system and the possibility of synchronizing the eight lasers with the pellet injection, we were able to measure the evolution of the post-pellet electron density and temperature profiles with high temporal and spatial resolution. These profiles, together with ion temperature profiles measured using a charge exchange diagnostic, were used to produce equilibria suitable for microstability analysis of th...

  17. New practical synthesis of indazoles via condensation of o-fluorobenzaldehydes and their O-methyloximes with hydrazine.

    Science.gov (United States)

    Lukin, Kirill; Hsu, Margaret C; Fernando, Dilinie; Leanna, M Robert

    2006-10-13

    The reaction of o-fluorobenzaldehydes and their O-methyloximes with hydrazine has been developed as a new practical synthesis of indazoles. Utilization of the methyloxime derivatives of benzaldehydes (in the form of the major E-isomers) in this condensation effectively eliminated a competitive Wolf-Kishner reduction to fluorotoluenes, which was observed in the direct preparations of indazoles from aldehydes. Reaction of Z-isomers of methyloximes with hydrazine resulted in the formation of 3-aminoindazoles via a benzonitrile intermediate.

  18. Symmetry Parameters of CSS Sources: Evidence of Fuelling?

    CERN Document Server

    Saikia, D J; Mantovani, F; Salter, C J; Spencer, R E; Thomasson, P; Wiita, P J

    2003-01-01

    The compact steep spectrum (CSS) and gigahertz peaked spectrum (GPS) sources are widely believed to be young radiosources, with ages <10^6 yr. If the activity in the nucleus is fuelled by the supply of gas, one might find evidence of this gas by studying the structural and polarisation characteristics of CSS sources and their evolution through this gas. In this paper we discuss some of the possible `smoking-gun' evidence of this gas which may have triggered and fuelled the radio source.

  19. Treatment for hydrazine-containing waste water solution

    Science.gov (United States)

    Yade, N.

    1986-01-01

    The treatment for waste solutions containing hydrazine is presented. The invention attempts oxidation and decomposition of hydrazine in waste water in a simple and effective processing. The method adds activated charcoal to waste solutions containing hydrazine while maintaining a pH value higher than 8, and adding iron salts if necessary. Then, the solution is aerated.

  20. Hydrazine in the Ugi Tetrazole Reaction

    NARCIS (Netherlands)

    Patil, Pravin; Zhang, Ji; Kurpiewska, Katarzyna; Kalinowska-Tłuścik, Justyna; Dömling, Alexander

    2016-01-01

    We describe the hitherto unknown use of N-Boc-protected hydrazine in the Ugi tetrazole reaction to access a library of highly substituted 5-(hydrazinomethyl)-1-methyl-1H-tetrazoles. The reaction is very versatile and good to high yielding. A one-pot, two-step procedure is given.

  1. Ascorbic Acid Assisted Synthesis of Cobalt Oxide Nanostructures, Their Electrochemical Sensing Application for the Sensitive Determination of Hydrazine

    Science.gov (United States)

    Tahira, Aneela; Nafady, Ayman; Baloach, Quarratulain; Sirajuddin; Sherazi, Syed Tufail Hussain; Shaikh, Tayyaba; Arain, Munazza; Willander, Magnus; Ibupoto, Zafar Hussain

    2016-07-01

    This study describes, the synthesis of cobalt oxide nanostructures using ascorbic acid as a growth directing agent by the hydrothermal method. Ascorbic acid is used for the first time for the synthesis of cobalt oxide nanostructures and a unique morphology is prepared in the present study. The cobalt oxide nanostructures were characterized by scanning electron microcopy, x-ray diffraction, and x-ray photoelectron spectroscopy techniques. These analytical techniques demonstrated well defined morphology, good crystalline quality, and high purity of as prepared cobalt oxide nanostructures. The glassy carbon electrode was modified with cobalt oxide nanostructures for the development of a sensitive and selective electrochemical hydrazine sensor. The developed hydrazine sensor exhibits a linear range of 2-24 μM. The sensitivity and limit of detection of presented hydrazine sensors are 12,734 μA/mM/cm2 and 0.1 μM respectively. The developed hydrazine sensor is highly selective, stable, and reproducible. The proposed sensor is successfully applied for the detection of hydrazine from different water samples. The present study provides the development of an alternative tool for the reliable monitoring of hydrazine from environmental and biological samples.

  2. China's First Orimulsion-fuelled Power Project Kicks off

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ China's first Orimulsion-fuelled power project was recently kicked off in Zhanjiang, a coastal city in Southeastern China's Guangdong Province. This project, which draws an investment of about 4.1 billion yuan, is a joint venture among CNPC Fuel Oil Co Ltd with a 51 percent stake, Guangdong Electric Power Development Co Ltd with a 39 percent stake and Zhanjiang Harbor Group Co Ltd with a 10 percent.

  3. Avalanche Phenomenon of Runaway Electrons During Additional Fuelling

    Institute of Scientific and Technical Information of China (English)

    杨进蔚; 曹建勇; 曾庆希; 张炜; 唐年益; 董贾福; 邓中朝; 肖正贵; 姚良骅

    2002-01-01

    During pellet injection and supersonic molecular beam injection, we have observed the increase of electron density and the enhancement of hard x-ray radiation, but the runaway electrons normally decrease without additional fuelling when the density of plasma increases. This phenomenon may come from the synergetic effects of Dreicer and avalanche runaway electrons. The experimental results are consistent with the calculation based on the theory of avalanche runaway in the HL-1M tokamak.

  4. Utilization of waste glycerin to fuelling of spark ignition engines

    Science.gov (United States)

    Stelmasiak, Z.; Pietras, D.

    2016-09-01

    The paper discusses a possibilities of usage a simple alcohols to fuelling of spark ignition engines. Methanol and blends of methanol with glycerin, being a waste product from production of bio-components to fuels based on rapeseed oil, have been used in course of the investigations. The main objective of the research was to determine possibilities of utilization of glycerin to blending of engine fuels. The investigations have been performed using the Fiat 1100 MPI engine. Parameters obtained with the engine powered by pure methanol and by methanol- glycerin mixtures with 10÷30%vol content of glycerin were compared to parameters of the engine fuelled conventionally with the E95 gasoline. The investigations have shown increase of overall efficiency of the engine run on pure methanol with 2.5÷5.0%, and run on the mixture having 10% addition of glycerin with 2.0÷7.8%. Simultaneously, fuelling of the engine with the investigated alcohols results in reduced concentration of toxic components in exhaust gases like: CO, THC and NOx, as well as the greenhouse gas CO2.

  5. METEV: Measurement Technologies for Emissions from Ethanol Fuelled Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Sandtroem-Dahl, Charlotte

    2009-11-15

    The interest of using alcohols, and especially ethanol, as vehicle fuel is high in Sweden. The advantages are many, such as; being renewable, the ethanol can be produced locally and it is easily mixed with gasoline. Alcohol fuels are considered to be a substantial part of the alternative fuel market, especially in Brazil, USA and Sweden. With this growing interest it is of most importance to investigate the emission performance of vehicles fuelled with alcohols. The focus in this study is on measurement and calculation of hydrocarbon emissions. The emission regulations in different countries have different ways to treat alcohol fuelled vehicles. When alcohols are used as blending components in gasoline, uncombusted alcohols from the fuel are emitted in the exhaust in various amounts. If a Flame Ionization Detector (FID) is used to measure hydrocarbons, the uncombusted alcohol will be included in the measurement. The alcohol is, per definition, however not a hydrocarbon (hydrocarbons contains only hydrogen and carbon). In the US regulations, the alcohol content is measured separately, and the FID measurement is adjusted for the alcohol part. This is not performed in the European regulations. The aim of this project is to highlight the need for a discussion regarding the methodology for measuring hydrocarbon and alcohol emissions from flexible fuelled vehicles operating on alcohol fuel blends.

  6. Crystal structure of hydrazine iron(III) phosphate, the first transition metal phosphate containing hydrazine.

    Science.gov (United States)

    David, Renald

    2015-12-01

    The title compound, poly[(μ2-hydrazine)(μ4-phosphato)iron(III)], [Fe(PO4)(N2H4)] n , was prepared under hydro-thermal conditions. Its asymmetric unit contains one Fe(III) atom located on an inversion centre, one P atom located on a twofold rotation axis, and two O, one N and two H atoms located on general positions. The Fe(III) atom is bound to four O atoms of symmetry-related PO4 tetra-hedra and to two N atoms of two symmetry-related hydrazine ligands, resulting in a slightly distorted FeO4N2 octa-hedron. The crystal structure consists of a three-dimensional hydrazine/iron phoshate framework whereby each PO4 tetra-hedron bridges four Fe(III) atoms and each hydrazine ligand bridges two Fe(III) atoms. The H atoms of the hydrazine ligands are also involved in moderate N-H⋯O hydrogen bonding with phosphate O atoms. The crystal structure is isotypic with the sulfates [Co(SO4)(N2H4)] and [Mn(SO4)(N2H4)].

  7. Crystal structure of hydrazine iron(III phosphate, the first transition metal phosphate containing hydrazine

    Directory of Open Access Journals (Sweden)

    Renald David

    2015-12-01

    Full Text Available The title compound, poly[(μ2-hydrazine(μ4-phosphatoiron(III], [Fe(PO4(N2H4]n, was prepared under hydrothermal conditions. Its asymmetric unit contains one FeIII atom located on an inversion centre, one P atom located on a twofold rotation axis, and two O, one N and two H atoms located on general positions. The FeIII atom is bound to four O atoms of symmetry-related PO4 tetrahedra and to two N atoms of two symmetry-related hydrazine ligands, resulting in a slightly distorted FeO4N2 octahedron. The crystal structure consists of a three-dimensional hydrazine/iron phoshate framework whereby each PO4 tetrahedron bridges four FeIII atoms and each hydrazine ligand bridges two FeIII atoms. The H atoms of the hydrazine ligands are also involved in moderate N—H...O hydrogen bonding with phosphate O atoms. The crystal structure is isotypic with the sulfates [Co(SO4(N2H4] and [Mn(SO4(N2H4].

  8. Chronic Inhalation Toxicity of Hydrazine: Oncogenic Effects

    Science.gov (United States)

    1981-06-01

    showed signs of anorexia and general fatigue. Changing diets and forced feedings resulted in the survival of the remaining two dogs. A 6-month chronic...Esophagus Bladder Stomach Seminal vesicles Duodenum Prostate Jejunum Testes Ileum Ovaries Cecum Uterus Colon Nasal cavity Rectum Brain Mesenteric lymph... malnutrition during chronic exposure. Based upon these studies, the current OSHA Threshold Limit Value of 1.0 ppm for hydrazine is unsatisfactory while the

  9. A centre-triggered magnesium fuelled cathodic arc thruster uses sublimation to deliver a record high specific impulse

    Science.gov (United States)

    Neumann, Patrick R. C.; Bilek, Marcela; McKenzie, David R.

    2016-08-01

    The cathodic arc is a high current, low voltage discharge that operates in vacuum and provides a stream of highly ionised plasma from a solid conducting cathode. The high ion velocities, together with the high ionisation fraction and the quasineutrality of the exhaust stream, make the cathodic arc an attractive plasma source for spacecraft propulsion applications. The specific impulse of the cathodic arc thruster is substantially increased when the emission of neutral species is reduced. Here, we demonstrate a reduction of neutral emission by exploiting sublimation in cathode spots and enhanced ionisation of the plasma in short, high-current pulses. This, combined with the enhanced directionality due to the efficient erosion profiles created by centre-triggering, substantially increases the specific impulse. We present experimentally measured specific impulses and jet power efficiencies for titanium and magnesium fuels. Our Mg fuelled source provides the highest reported specific impulse for a gridless ion thruster and is competitive with all flight rated ion thrusters. We present a model based on cathode sublimation and melting at the cathodic arc spot explaining the outstanding performance of the Mg fuelled source. A further significant advantage of an Mg-fuelled thruster is the abundance of Mg in asteroidal material and in space junk, providing an opportunity for utilising these resources in space.

  10. Analysis of carbon dioxide emission of gas fuelled cogeneration plant

    Science.gov (United States)

    Nordin, Adzuieen; Amin, M.; Majid, A.

    2013-12-01

    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO2 to the environment. This study analyzes the amount of CO2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants.

  11. Exergoeconomic optimization of coaxial tube evaporators for cooling of high pressure gaseous hydrogen during vehicle fuelling

    DEFF Research Database (Denmark)

    Jensen, Jonas Kjær; Rothuizen, Erasmus Damgaard; Markussen, Wiebke Brix

    2014-01-01

    Gaseous hydrogen as an automotive fuel is reaching the point of commercial introduction. Development of hydrogen fuelling stations considering an acceptable fuelling time by cooling the hydrogen to -40 C has started. This paper presents a design study of coaxial tube ammonia evaporators for three...

  12. The Feasibility of Pellet Re-Fuelling of a Fusion Reactor

    DEFF Research Database (Denmark)

    Chang, Tinghong; Jørgensen, L. W.; Nielsen, P.

    1980-01-01

    The feasibility of re-fuelling a fusion reactor by injecting pellets of frozen hydrogen isotopes is reviewed. First a general look is taken of the dominant energy fluxes received by the pellet, the re-fuelling rate required and the relation between pellet size, injection speed and frequency...

  13. Tiny pollutant emissions of a dimethyl ether fuelled engine

    Institute of Scientific and Technical Information of China (English)

    LANG Jing; ZHANG Yu-sheng; ZHOU Xiao-song; WU Hong-wei

    2008-01-01

    Emissions of dimethyl ether (DME) fuelled engines were investigated by orthogonal experiments on a ZS195 diesel engine. The study mainly focused on the tiny pollutant emissions of formaldehyde (CH2O), methyl formate (CH3OCHO) and formic acid (HCOOH). The presence of CH2O, CH3OCHO and HCOOH are proved in the exhaust by gas chromatograph and Fourier transform infrared spectroscopy. The analysis of variance results indicate that the fuel delivery advance angle is the most important factor for CH2O emission. The fuel delivery advance angle and the interaction of injection pressure and nozzle diameter are considerable factors for unburned hydrocarbon (UHC) emission. The mechanism forming tiny pollutants, primarily through CH2O formation, is suggested to be similar to the mechanism forming UHC by DME partial oxidation existing in crevices and boundary zones, and is verified via DME combustion simulation of a multizone chemical kinetic model.

  14. Developing A New Sampling and Analysis Method for Hydrazine and Monomethyl Hydrazine

    Science.gov (United States)

    Allen, John R.

    2002-01-01

    Solid phase microextraction (SPME) will be used to develop a method for detecting monomethyl hydrazine (MMH) and hydrazine (Hz). A derivatizing agent, pentafluorobenzoyl chloride (PFBCl), is known to react readily with MMH and Hz. The SPME fiber can either be coated with PFBCl and introduced into a gaseous stream containing MMH, or PFBCl and MMH can react first in a syringe barrel and after a short equilibration period a SPME is used to sample the resulting solution. These methods were optimized and compared. Because Hz and MMH can degrade the SPME, letting the reaction occur first gave better results. Only MMH could be detected using either of these methods. Future research will concentrate on constructing calibration curves and determining the detection limit.

  15. Developing A New Sampling and Analysis Method for Hydrazine and Monomethyl Hydrazine

    Science.gov (United States)

    Allen, John R.

    2002-01-01

    Solid phase microextraction (SPME) will be used to develop a method for detecting monomethyl hydrazine (MMH) and hydrazine (Hz). A derivatizing agent, pentafluorobenzoyl chloride (PFBCl), is known to react readily with MMH and Hz. The SPME fiber can either be coated with PFBCl and introduced into a gaseous stream containing MMH, or PFBCl and MMH can react first in a syringe barrel and after a short equilibration period a SPME is used to sample the resulting solution. These methods were optimized and compared. Because Hz and MMH can degrade the SPME, letting the reaction occur first gave better results. Only MMH could be detected using either of these methods. Future research will concentrate on constructing calibration curves and determining the detection limit.

  16. Bacterial Toxicity and Metabolism of Three Hydrazine Fuels.

    Science.gov (United States)

    1980-09-01

    zine fuels have toxic effects on developing frog embryos and/or larvae. Hydrazine sulphate proved teratogenic at 40 milligrams per liter. MMH was...and for photographic developing . Hydrazine is also used as a surface active agent in plasticizer manufacturing (Reference 1). As of 1978, most...hour LC50 ranges for the common guppy of 0.6 to 4.6, 2.6 to 6.7, and 10.1 to 26.5 for hydrazine, MMH and UDMH, respectively. The range variation for

  17. Synthesis and Free Radical Scavenging Activity of New Hydroxybenzylidene Hydrazines

    National Research Council Canada - National Science Library

    Frantisek Sersen; Fridrich Gregan; Peter Kotora; Jarmila Kmetova; Juraj Filo; Dusan Loos; Juraj Gregan

    2017-01-01

    Hydroxybenzylidene hydrazines exhibit a wide spectrum of biological activities. Here, we report synthesis and free radical scavenging activity of nine new N-(hydroxybenzylidene)-N′-[2,6-dinitro-4-(trifluoromethyl)]phenylhydrazines...

  18. Enthalpy of Formation of N2H4 (Hydrazine) Revisited

    Energy Technology Data Exchange (ETDEWEB)

    Feller, David; Bross, David H.; Ruscic, Branko

    2017-08-17

    In order to address the accuracy of the long-standing experimental enthalpy of formation of gas-phase hydrazine, fully confirmed in earlier versions of Active Thermochemical Tables (ATcT), the provenance of that value is re-examined in light of new high-end calculations of the Feller-Peterson-Dixon (FPD) variety. An overly optimistic determination of the vaporization enthalpy of hydrazine, which created an unrealistically strong connection between the gas phase thermochemistry and the calorimetric results defining the thermochemistry of liquid hydrazine was identified as the probable culprit. The new enthalpy of formation of gas-phase hydrazine, based on balancing all available knowledge, was determined to be 111.57 ± 0.47 kJ/mol at 0 K (97.41 kJ/mol at 298.15 K). Close agreement was found between the ATcT (even excluding the latest theoretical result) and FPD enthalpies.

  19. Mobility Spectrometer Studies on Hydrazine and Ammonia Detection

    Science.gov (United States)

    Niu, William; Eiceman, Gary; Szumlas, Andrew; Lewis, John

    2011-01-01

    An airborne vapor analyzer for detecting sub- to low- parts-per-million (ppm) hydrazine in the presence of higher concentration levels of ammonia has been under development for the Orion program. The detector is based on ambient pressure ionization and ion mobility characterization. The detector encompasses: 1) a membrane inlet to exclude particulate and aerosols from the analyzer inlet; 2) a method to separate hydrazine from ammonia which would otherwise lead to loss of calibration and quantitative accuracy for the hydrazine determination; and 3) response and quantitative determinations for both hydrazine and ammonia. Laboratory studies were made to explore some of these features including mobility measurements mindful of power, size, and weight issues. The study recommended the use of a mobility spectrometer of traditional design with a reagent gas and equipped with an inlet transfer line of bonded phase fused silica tube. The inlet transfer line provided gas phase separation of neutrals of ammonia from hydrazine at 50 C simplifying significantly the ionization chemistry that underlies response in a mobility spectrometer. Performance of the analyzer was acceptable between ranges of 30 to 80 C for both the pre-fractionation column and the drift tube. An inlet comprised of a combined membrane with valve-less injector allowed high speed quantitative determination of ammonia and hydrazine without cross reactivity from common metabolites such as alcohols, esters, and aldehydes. Preliminary test results and some of the design features are discussed.

  20. Technical and Feasibility Analysis of Gasoline and Natural Gas Fuelled Vehicles

    OpenAIRE

    Charalambos Chasos; George Karagiorgis; Chris Christodoulou

    2014-01-01

    There is recent interest for the utilisation of natural gas for empowering the internal combustion engines (ICE) of vehicles. The production of novel natural gas ICE for vehicles, as well as the conversion of existing gasoline fuelled ICE of vehicles to natural gas fuelled ICE are new technologies which require to be analysed and assessed. The objective of the present study is to examine the adaptation of natural gas as vehicle fuel and carry out a technical analysis and an economical feasibi...

  1. Analysis of fuelling requirements in ITER H-modes with SOLPS-EPED1 derived scalings

    Science.gov (United States)

    Polevoi, A. R.; Loarte, A.; Kukushkin, A. S.; Pacher, H. D.; Pacher, G. W.; Köchl, F.

    2017-02-01

    Fuelling requirements for ITER are analysed in relation to pellet fuelling and ELM pacing, and a divertor power load control consistent with the ITER pumping and fuel throughput capabilities. The plasma parameters at the separatrix and the particle sources are derived from scalings based on SOLPS simulations. Effective transport coefficients in the H-mode pedestal are derived from EPED1 + SOLPS scalings for the pedestal height and width. 1.5D transport is simulated in the ASTRA framework. The operating window for ITER DT plasmas with the required fusion performance and level of ELM, and divertor power load control compatible with ITER fuelling and pumping capabilities, is determined. It is shown that the flexibility of the ITER fuelling systems, comprising pellet and gas injection systems, enables operation with Q  =  10, which was found to be marginal in previous studies following a similar approach but with different assumptions. The present assessment shows that a reduction of by a factor ~2 (from 9 to 5  ×  1019 m-3) in 15 MA H-mode plasmas leads to a reduction in the required pellet fuelling rate by a factor of four. Results of the analysis of the fuelling requirements for a range of ITER scenarios are found to be similar to those obtained with the JINTRAC code that included 2D modelling of the edge plasma.

  2. Hydrazine Borane and Hydrazinidoboranes as Chemical Hydrogen Storage Materials

    Directory of Open Access Journals (Sweden)

    Romain Moury

    2015-04-01

    Full Text Available Hydrazine borane N2H4BH3 and alkali derivatives (i.e., lithium, sodium and potassium hydrazinidoboranes MN2H3BH3 with M = Li, Na and K have been considered as potential chemical hydrogen storage materials. They belong to the family of boron- and nitrogen-based materials and the present article aims at providing a timely review while focusing on fundamentals so that their effective potential in the field could be appreciated. It stands out that, on the one hand, hydrazine borane, in aqueous solution, would be suitable for full dehydrogenation in hydrolytic conditions; the most attractive feature is the possibility to dehydrogenate, in addition to the BH3 group, the N2H4 moiety in the presence of an active and selective metal-based catalyst but for which further improvements are still necessary. However, the thermolytic dehydrogenation of hydrazine borane should be avoided because of the evolution of significant amounts of hydrazine and the formation of a shock-sensitive solid residue upon heating at >300 °C. On the other hand, the alkali hydrazinidoboranes, obtained by reaction of hydrazine borane with alkali hydrides, would be more suitable to thermolytic dehydrogenation, with improved properties in comparison to the parent borane. All of these aspects are surveyed herein and put into perspective.

  3. Emissions from Road Vehicles Fuelled by Fischer Tropsch Based Diesel and Gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, U.; Lundorf, P.; Ivarsson, A.; Schramm, J. [Technical University of Denmark (Denmark); Rehnlund, B. [Atrax Energi AB (Sweden); Blinge, M. [The Swedish Transport Institute (Sweden)

    2006-11-15

    The described results were carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was supposed to be very similar, in many ways, to FT fuel. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline vehicle.

  4. Emissions from Road Vehicles Fuelled by Fischer Tropsch Based Diesel and Gasoline

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, U.; Lundorf, P.; Ivarsson, A.; Schramm, J. [Technical University of Denmark (Denmark); Rehnlund, B. [Atrax Energi AB (Sweden); Blinge, M. [The Swedish Transport Institute (Sweden)

    2006-11-15

    The described results were carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was supposed to be very similar, in many ways, to FT fuel. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline vehicle.

  5. Thermal instabilities in cooling galactic coronae: fuelling star formation in galactic discs

    CERN Document Server

    Hobbs, Alexander; Power, Chris; Cole, David

    2012-01-01

    We investigate the means by which cold gas can accrete onto Milky Way mass galaxies from a hot corona of gas, using a new smoothed particle hydrodynamics code, 'SPHS'. We find that the 'cold clumps' seen in many classic SPH simulations in the literature are not present in our SPHS simulations. Instead, cold gas condenses from the halo along filaments that form at the intersection of supernovae-driven bubbles from previous phases of star formation. This positive feedback feeds cold gas to the galactic disc directly, fuelling further star formation. The resulting galaxies in the SPH and SPHS simulations differ greatly in their morphology, gas phase diagrams, and stellar content. We show that the classic SPH cold clumps owe to a numerical thermal instability caused by an inability for cold gas to mix in the hot halo. The improved treatment of mixing in SPHS suppresses this instability leading to a dramatically different physical outcome. In our highest resolution SPHS simulation, we find that the cold filaments ...

  6. ANALYSIS OF OPERATING PARAMETERS AND INDICATORS OF A COMPRESSION IGNITION ENGINE FUELLED WITH LPG

    Directory of Open Access Journals (Sweden)

    Krzysztof GARBALA

    2016-12-01

    Full Text Available This article presents the possibilities for using alternative fuels to power vehicles equipped with compression ignition (CI engines (diesel. Systems for using such fuels have been discussed. Detailed analysis and research covered the LPG STAG autogas system, which is used to power dual-fuel engine units (LPG+diesel. A description of the operation of the autogas system and installation in a vehicle has been presented. The basic algorithms of the controller, which is an actuating element of the whole system, have been discussed. Protection systems of a serial production engine unit to guarantee its factorycontrolled durability standards have been presented. A long-distance test drive and examinations of the engine over 150,000 km in a Toyota Hilux have been performed. Operating parameters and performance indicators of the engine with STAG LPG+diesel fuelling have been verified. Directions and perspectives for the further development of such a system in diesel-powered cars have been also indicated.

  7. A supersonic gas injection system for fuelling and probing fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Collis, Scott [Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Howard, John [Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Blackwell, Boyd [Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Carlsson, Peter [Department of Physics and Engineering Physics, Chalmers University of Technology, SE-412 96 Goeteburg (Sweden); Abelsson, Mattias [Department of Physics and Engineering Physics, Chalmers University of Technology, SE-412 96 Goeteburg (Sweden); Powell, Ben [Research School of Physical Sciences and Engineering, Australian National University, Canberra, ACT 0200 (Australia)

    2006-11-01

    The large gas reservoir surrounding the H-1NF plasma leads to difficulties in achieving the density control required to maximize the plasma temperature. We have designed and tested an alternative fuelling system which uses a double conical nozzle to generate a directed flow of particles into the plasma without adding to the gas inventory in the rest of the vacuum vessel. By using a closed plenum at a programmable pressure and a piezo-electric valve, the particle flux can be dynamically changed in a controlled and quantitative manner. Measurements of the gas jet using constant temperature hot wire anemometry show that, for plenum pressures between 500 and 1000 Torr, the particle injection rate (helium) ranges between 2 x 10{sup 20} and 4 x 10{sup 20} s{sup -1} with half-cone angles between 5 deg. and 20 deg. The system has been installed on the H-1NF device and first plasma results indicate localized gas injection consistent with test tank anemometry measurements.

  8. Research on the Reaction Between Technetium and Hydrazine in Nitric Acid Medium

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The reaction between technetium and hydrazine in nitric acid medium was studied by the titration ofthe concentration of hydrazine and pursuing the concentration of heptavalent technetium along with time.It is approved that the reaction between technetium and hydrazine includes an inducing period, a fast

  9. Effect of Fuelling Depth on the Fusion Performance and Particle Confinement of a Fusion Reactor

    Science.gov (United States)

    Wang, Shijia; Wang, Shaojie

    2016-12-01

    The fusion performance and particle confinement of an international thermonuclear experimental reactor (ITER)-like fusion device have been modeled by numerically solving the energy transport equation and the particle transport equation. The effect of fuelling depth has been investigated. The plasma is primarily heated by the fusion produced alpha particles and the loss process of particles and energy in the scrape-off layer has been taken into account. To study the effect of fuelling depth on fusion performance, the ITERH-98P(y,2) scaling law has been used to evaluate the transport coefficients. It is shown that the particle confinement and fusion performance are significantly dependent on the fuelling depth. Deviation of 10% of the minor radius on fuelling depth can make the particle confinement change by ∼ 61% and the fusion performance change by ∼ 108%. The enhancement of fusion performance is due to the better particle confinement induced by deeper particle fuelling. supported by National Natural Science Foundation of China (Nos. 11175178 and 11375196) and the National Magnetic Confinement Fusion Science Program of China (No. 2014GB113000)

  10. MICROWAVE-ASSISTED CYCLOCONDENSATION OF HYDRAZINE DERIVATIVES WITH ALKYL DIHALIDES OR DITOSYLATES IN AQUEOUS MEDIA: SYNTHESES OF PYRAZOLE, PYRAZOLIDINE AND PHTHALAZINE DERIVATIVES

    Science.gov (United States)

    Direct synthesis of 4,5-dihydro-pyrazole, pyrazolidine, and 1,2-dihydro-phthalazine derivatives via double alkylation of hydrazines by alkyl dihalides or ditosylates were accomplished in aqueous media under microwave irradiation conditions; the environmentally friendlier chemical...

  11. Pellet fuelling of plasmas with ELM mitigation by resonant magnetic perturbations in MAST

    CERN Document Server

    Valovic, M; Garzotti, L; Gurl, C; Kirk, A; Naylor, G; Patel, A; Scannell, R; Thornton, A J

    2013-01-01

    Shallow fuelling pellets are injected from the high field side into plasmas in which ELMs have been mitigated using external magnetic perturbation coils. The data are compared with ideal assumptions in the ITER fuelling model, namely that mitigated ELMs are not affected by fuelling pellets. Firstly it is shown that during the pellet evaporation an ELM is triggered, during which the amount particle loss could be larger (factor ~1.5) than the particle loss during an ELM which was not induced by pellet. Secondly, a favourable example is shown in which post-pellet particle losses due to mitigated ELMs are similar to the non-pellet case, however unfavourable counter-examples also exist.

  12. Moderation of target loads using fuelling and impurity seeding on JET

    Energy Technology Data Exchange (ETDEWEB)

    Maddison, G., E-mail: geoff.maddison@ccfe.ac.uk [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); Giroud, C. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); McCormick, K. [Max-Planck IPP, EURATOM Association, D-85748 Garching (Germany); Alonso, A. [Asociacion EURATOM-CIEMAT, Laboratorio Nacional de Fusion (Spain); Alper, B.; Andrew, Y.; Arnoux, G. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); Belo, P. [IPFN, EURATOM-IST Associacao, 1096 Lisbon (Portugal); Beurskens, M.; Boboc, A.; Brett, A. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); Brezinsek, S. [IEF-Plasmaphysik, Forschungszentrum Juelich, Association EURATOM-FZJ, Juelich (Germany); Brix, M. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom); Coffey, I. [Queen' s University Belfast, University Road, Belfast BT7 1NN, Northern Ireland (United Kingdom); Luna, E. de la [Asociacion EURATOM-CIEMAT, Laboratorio Nacional de Fusion (Spain); Devaux, S. [Max-Planck IPP, EURATOM Association, D-85748 Garching (Germany); Vries, P. de [FOM IPP Rijnhuizen, Association EURATOM-FOM, 3430 BE NIEUWEGEIN (Netherlands); Devynck, P. [Association EURATOM-CEA, IRFM, F-13108 St Paul lez Durance (France); Eich, T. [Max-Planck IPP, EURATOM Association, D-85748 Garching (Germany); Felton, R. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon OX14 3DB (United Kingdom)

    2011-08-01

    Operation with an all metal, ITER-like wall on JET is scheduled from 2011. Adaptation particularly of baseline ELMy H-mode (q{sub 95} {approx} 3.5) to the new exhaust constraints involved has been explored by systematic scans of deuterium fuelling and seeding with extrinsic impurities neon or nitrogen. Peak heat load between ELMs on the outboard target can be strongly reduced by fuelling (recycling), and approach detachment with either seed species, for only {approx}10% loss of normalised energy confinement. Simultaneously, normalised plasma density and total radiation averaged between ELMs are not simply increased, but at stronger fuelling can actually fall with increasing seeding, indicating some redistribution of efflux power temporally and spatially. At highest nitrogen seeding, ELMs can also be mitigated, even while the electron pedestal and confinement are largely preserved. Charge-exchange recombination spectroscopy indicates a substitution of intrinsic carbon with extrinsic species.

  13. Synthesis of the row of new functional derivatives of 7-arylalkyl-8-hydrazine theophyllines

    Directory of Open Access Journals (Sweden)

    Dmytro Korobko

    2016-03-01

    Full Text Available Hydrazine functional derivatives are widely used in medical practice as remedies applied for pharmacotherapy of depression, infection diseases, hypertension, diabetes, etc. It is worth mentioning that among obtained 7-R-8-hydrazine derivatives of 1,3-dimethylxantine promising substances have been identified. Due to the fact that literature sources display only results of occasional studies of the reactions between 7-R-8-hydrazine theophyllines and mono- or dicarbonyle substances, the use of other keto reagents for xanthine bicycle at 8th position functionalization will allow to explore synthetic potential of the last one, and with high probability may lead to obtaining original biologically active substances.Aim. To study types of reaction between 8-hydrazinyl-1,3-dimethyl-7-aryl alkyl-1H-purine-2,6(3H,7H-diones and a number of carbonyl containing reagents.Methods. A nucleophilic addition reaction followed by dehydration or ethanol splitting was used, as well as the complex of the modern analysis methods to confirm the structure and individuality of the synthesized substances.Results. Different directions of 8-hydrazinyl-1,3,-dimethyl-7(fenetyl-, 3-phenylpropyl-, 3-phenylalyl-1H-purine-2,6(3H,7H-diones chemical transformations in reactions with the appropriate carbonyl containing compounds have been studied experimentally. The structure of synthesized substances was confirmed by chromatography/mass and 1H NMR spectroscopy.Conclusion. The group of 7-arylalkyl-8-(3,5-R,R1-pyrazole-1-yltheophyllines, consisting of two functionally substituted bioactive heterocycles, has been synthesized by reaction between initial substances and selected mono- and dicarbonyl compounds

  14. Ultraviolet surface plasmon-mediated low temperature hydrazine decomposition

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Siying; Sheldon, Matthew T.; Atwater, Harry A. [Thomas J. Watson Laboratories of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States); Liu, Wei-Guang; Jaramillo-Botero, Andres; Goddard, William Andrew [Materials and Process Simulation Center, California Institute of Technology, Pasadena, California 91125 (United States)

    2015-01-12

    Conventional methods require elevated temperatures in order to dissociate high-energy nitrogen bonds in precursor molecules such as ammonia or hydrazine used for nitride film growth. We report enhanced photodissociation of surface-absorbed hydrazine (N{sub 2}H{sub 4}) molecules at low temperature by using ultraviolet surface plasmons to concentrate the exciting radiation. Plasmonic nanostructured aluminum substrates were designed to provide resonant near field concentration at λ = 248 nm (5 eV), corresponding to the maximum optical cross section for hydrogen abstraction from N{sub 2}H{sub 4}. We employed nanoimprint lithography to fabricate 1 mm × 1 mm arrays of the resonant plasmonic structures, and ultraviolet reflectance spectroscopy confirmed resonant extinction at 248 nm. Hydrazine was cryogenically adsorbed to the plasmonic substrate in a low-pressure ambient, and 5 eV surface plasmons were resonantly excited using a pulsed KrF laser. Mass spectrometry was used to characterize the photodissociation products and indicated a 6.2× overall enhancement in photodissociation yield for hydrazine adsorbed on plasmonic substrates compared with control substrates. The ultraviolet surface plasmon enhanced photodissociation demonstrated here may provide a valuable method to generate reactive precursors for deposition of nitride thin film materials at low temperatures.

  15. Development and test of a new catalytic converter for natural gas fuelled engine

    Indian Academy of Sciences (India)

    M A Kalam; H H Masjuki; M Redzuan; T M I Mahlia; M A Fuad; M Mohibah; K H Halim; A Ishak; M Khair; A Shahrir; A Yusoff

    2009-06-01

    This paper presents characteristics of a new catalytic converter (catco) to be used for natural gas fuelled engine. The catco were developed based on catalyst materials consisting of metal oxides such as titanium dioxide (TiO2) and cobalt oxide (CoO) with wire mesh substrate. Both of the catalyst materials (such as TiO2 and CoO) are inexpensive in comparison with conventional catalysts (noble metals) such as palladium or platinum. In addition, the noble metals such as platinum group metals are now identified as human health risk due to their rapid emissions in the environment from various resources like conventional catalytic converter, jewelers and other medical usages. It can be mentioned that the TiO2/CoO based catalytic converter and a new natural gas engine such as compressed natural gas (CNG) direct injection (DI) engine were developed under a research collaboration program. The original engine manufacture catalytic conveter (OEM catco) was tested for comparison purposes. The OEM catco was based on noble metal catalyst with honeycomb ceramic substrate. It is experimentally found that the conversion efficiencies of TiO2/CoO based catalytic converter are 93%, 89% and 82% for NOx, CO and HC emissions respectively. It is calculated that the TiO2/CoO based catalytic converter reduces 24%, 41% and 40% higher NOx, CO and HC emissions in comparison to OEM catco respectively. The objective of this paper is to develop a low-cost three way catalytic converter to be used with the newly developed CNG-DI engine. Detailed review on catalytic converter, low-cost catalytic converter development characteristics and CNGDI engine test results have been presented with discussions.

  16. Migrating Broad-billed Sandpipers achieve high fuelling rates by taking a multi-course meal

    NARCIS (Netherlands)

    Verkuil, Y.I.; Dekinga, A; Koolhaas, A; van der Winden, J; van der Have, T M; Chernichko, I I

    2006-01-01

    In spring, large numbers of migrating Broad-billed Sandpipers make a stop-over in the Sivash, a shallow lagoon system in the Crimea, Ukraine, between the Black Sea and the Sea of Azov. Observed fuelling rates are high and, in just a few weeks, the birds can build up sufficient departure mass to reac

  17. FARE device operational characteristics of remote controlled fuelling machine at Wolsong NPP

    Energy Technology Data Exchange (ETDEWEB)

    Namgung, I. [Korea Power Engineering Co., Taejon (Korea, Republic of); Kim, Y. B.; Lee, S. K. [Korea Electric Power Research Institute, Taejon (Korea, Republic of)

    2002-10-01

    There are 4 CANDU6 type reactors operating at Wolsong site. For fuelling operation of certain fuel channels (with flow less than 21.5 kg/s) a FARE (flow Assist Ram Extension) device is used. During the refuelling operation, two remote controlled F/Ms (Fuelling Machines) are attached to a designated fuel channel and carry out refuelling job. The upstream F/M inserts new fuel bundles into the fuel channel while the downstream F/M discharges spent fuel bundles. In order to assist fuelling operation of channels that has lower coolant flow rate, the FARE device is used instead of F/M C-ram to push the fuel bundle string. The FARE device is essentially a flow restricting element that produces enough drag force to push the fuel bundle string toward downstream F/M. Channels that require the use of FARE device for refuelling are located along the outside perimeter of reactor. This paper presents the FARE device design feature, steady state hydraulic and operational characteristics and behavior of the device when coupled with fuel bundle string during fuelling operation. The study showed that the steady state performance of Fare device meets the design objective that was confirmed by downstream F/M C-ram force to be positive.

  18. Avian pectoral muscle size rapidly tracks body mass changes during flight, fasting and fuelling

    NARCIS (Netherlands)

    Lindstrom, A; Kvist, A; Piersma, T; Dekinga, A; Dietz, MW; Lindström, Åke

    2000-01-01

    We used ultrasonic imaging to monitor short-term changes in the pectoral muscle size of captive red knots Calidris canutus. Pectoral muscle thickness changed rapidly and consistently in parallel with body mass changes caused by flight, fasting;and fuelling. Four knots hew repeatedly for 10h periods

  19. A comparison of exhaust emissions from vehicles fuelled with petrol, LPG and CNG

    Science.gov (United States)

    Bielaczyc, P.; Szczotka, A.; Woodburn, J.

    2016-09-01

    This paper presents an analysis of THC, NMHC, CO, NOx and CO2 emissions during testing of two bi-fuel vehicles, fuelled with petrol and gaseous fuels, on a chassis dynamometer in the context of the Euro 6 emissions requirements. The analyses were performed on one Euro 5 bi-fuel vehicle (petrol/LPG) and one Euro 5 bi-fuel vehicle (petrol/CNG), both with SI engines equipped with MPI feeding systems operating in closed-loop control, typical three-way-catalysts and heated oxygen sensors. The vehicles had been adapted by their manufacturers for fuelling with LPG or CNG by using additional special equipment mounted onto the existing petrol fuelling system. The vehicles tested featured multipoint gas injection systems. The aim of this paper was an analysis of the impact of the gaseous fuels on the exhaust emission in comparison to the emission of the vehicles fuelled with petrol. The tests subject to the analyses presented here were performed in the Engine Research Department of BOSMAL Automotive Research and Development Institute Ltd in Bielsko-Biala, Poland, within a research programme investigating the influence of alternative fuels on exhaust emissions from light duty vehicle vehicles with spark-ignition and compression-ignition engines.

  20. Galaxy Zoo: the effect of bar-driven fuelling on the presence of an active galactic nucleus in disc galaxies

    Science.gov (United States)

    Galloway, Melanie A.; Willett, Kyle W.; Fortson, Lucy F.; Cardamone, Carolin N.; Schawinski, Kevin; Cheung, Edmond; Lintott, Chris J.; Masters, Karen L.; Melvin, Thomas; Simmons, Brooke D.

    2015-04-01

    We study the influence of the presence of a strong bar in disc galaxies which host an active galactic nucleus (AGN). Using data from the Sloan Digital Sky Survey and morphological classifications from the Galaxy Zoo 2 project, we create a volume-limited sample of 19 756 disc galaxies at 0.01 < z < 0.05 which have been visually examined for the presence of a bar. Within this sample, AGN host galaxies have a higher overall percentage of bars (51.8 per cent) than inactive galaxies exhibiting central star formation (37.1 per cent). This difference is primarily due to known effects: that the presence of both AGN and galactic bars is strongly correlated with both the stellar mass and integrated colour of the host galaxy. We control for this effect by examining the difference in AGN fraction between barred and unbarred galaxies in fixed bins of mass and colour. Once this effect is accounted for, there remains a small but statistically significant increase that represents 16 per cent of the average barred AGN fraction. Using the L_{[O III]}/MBH ratio as a measure of AGN strength, we show that barred AGNs do not exhibit stronger accretion than unbarred AGNs at a fixed mass and colour. The data are consistent with a model in which bar-driven fuelling does contribute to the probability of an actively growing black hole, but in which other dynamical mechanisms must contribute to the direct AGN fuelling via smaller, non-axisymmetric perturbations.

  1. Enzyme-free electrochemical immunosensor based on methylene blue and the electro-oxidation of hydrazine on Pt nanoparticles.

    Science.gov (United States)

    Dutta, Gorachand; Nagarajan, Sureshbabu; Lapidus, Lisa J; Lillehoj, Peter B

    2017-06-15

    Enzyme-free electrochemical sensors enable rapid, high sensitivity measurements without the limitations associated with enzyme reporters. However, the performance of non-enzymatic electrochemical sensors tends to suffer from slow electrode kinetics and poor signal stability. We report a new enzyme-free electrochemical immunosensor based on a unique competitive detection scheme using methylene blue (MB), hydrazine and platinum nanoparticles (Pt NPs). This scheme is coupled with a robust immunosandwich format employing a MB-labelled detection antibody as a non-enzymatic reporter. In the presence of the target antigen, surface-immobilized MB consumes interfacial hydrazine thereby diminishing the electro-oxidation of hydrazine on Pt NPs. Thus, the concentration of the antigen is directly proportional to the reduction in the electrochemical signal. For proof-of-concept, this sensor was used to detect Plasmodium falciparum histidine-rich protein 2 (PfHRP2), an important malaria biomarker, in unadulterated human saliva samples. Chronocoulometric measurements showed that this platform exhibits pM-range sensitivity, high specificity and good reproducibility, making it well suited for many biosensing applications including noninvasive diagnostic testing.

  2. Developing a New Sampling And Analysis Method For Hydrazine And Monomethyl Hydrazine: Using a Derivatizing Agent With Solid Phase Microextraction

    Science.gov (United States)

    Allen, John

    2001-01-01

    Solid phase microextraction (SPME) will be used to develop a method for detecting monomethyl hydrazine (MMH) and hydrazine (Hz). A derivatizing agent, pentafluorobenzoyl chloride (PFBCI), is known to react readily with MMH and Hz. The SPME fiber can either be coated with PFBCl and introduced into a gaseous stream containing MMH, or PFBCl and MMH can react first in a syringe barrel and after a short equilibration period a SPME is used to sample the resulting solution. These methods were optimized and compared. Because Hz and MMH can degrade the SPME, letting the reaction occur first gave better results. Only MMH could be detected using either of these methods. Future research will concentrate on constructing calibration curves and determining the detection limit.

  3. Developing a New Sampling And Analysis Method For Hydrazine And Monomethyl Hydrazine: Using a Derivatizing Agent With Solid Phase Microextraction

    Science.gov (United States)

    Allen, John

    2001-01-01

    Solid phase microextraction (SPME) will be used to develop a method for detecting monomethyl hydrazine (MMH) and hydrazine (Hz). A derivatizing agent, pentafluorobenzoyl chloride (PFBCI), is known to react readily with MMH and Hz. The SPME fiber can either be coated with PFBCl and introduced into a gaseous stream containing MMH, or PFBCl and MMH can react first in a syringe barrel and after a short equilibration period a SPME is used to sample the resulting solution. These methods were optimized and compared. Because Hz and MMH can degrade the SPME, letting the reaction occur first gave better results. Only MMH could be detected using either of these methods. Future research will concentrate on constructing calibration curves and determining the detection limit.

  4. Monomethylhydrazine versus hydrazine fuels - Test results using a 100 pound thrust bipropellant rocket engine

    Science.gov (United States)

    Smith, J. A.; Stechman, R. C.

    1981-01-01

    A test program was performed to evaluate hydrazine (N2H4) as a fuel for a 445 Newton (100 lbf) thrust bipropellant rocket engine. Results of testing with an identical thruster utilizing monomethylhydrazine (MMH) are included for comparison. Engine performance with hydrazine fuel was essentially identical to that experienced with monomethylhydrazine although higher combustor wall temperatures (approximately 400 F) were obtained with hydrazine. Results are presented which indicate that hydrazine as a fuel is compatible with Marquardt bipropellant rocket engines which use monomethylhydrazine as a baseline fuel.

  5. Evaluation of hydrazine reduction by cellulose acetate filters using infrared tunable diode laser spectroscopy.

    Science.gov (United States)

    Harward, Charles N; Parrish, Milton E; Plunkett, Susan E; Banyasz, Joseph L; Shafer, Kenneth H

    2002-11-15

    Cellulose acetate (CA) filters have been investigated to determine their hydrazine (N2H4) breakthrough characteristics using a system based on tunable diode laser absorption spectroscopy (TDIAS). The breakthrough mass loading sorption curves for hydrazine were dependent on both the flow rate and the concentration. In experiments using a 4.5 ppmv hydrazine standard, the amounts of hydrazine retained by the CA filter were 4.25 microg at a flow rate of 2.82 L/min and 65 microg at a flow rate of 0.28 L/min. These loadings are much greater than the 31.5 ng/cigarette of hydrazine reported in smoke for unfiltered cigarettes. Further, CA filters exposed to four and eight puffs of smoke actually made the filter more efficient in retaining hydrazine compared to CA filters that had not been exposed to smoke. Therefore, if hydrazine is present in smoke at the levels reported in unfiltered cigarettes, all of the hydrazine would be trapped by the CA filter, and would be unable to break through during smoking. A unique feature of this analytical method is that the instrument does not require calibration after molecular parameters have been determined, in this case from previously acquired quantitative hydrazine FT-IR reference spectra.

  6. Fabrication of liquid crystal based sensor for detection of hydrazine vapours

    Science.gov (United States)

    Nandi, Rajib; Singh, Sachin Kumar; Singh, Hemant Kumar; Singh, Bachcha; Singh, Ranjan K.

    2014-10-01

    A novel liquid crystal (LC) based sensor to detect trace level amount of hydrazine vapour has been developed. The LC 4‧-pentyl-4-biphenylcarbonitrile (5CB) doped with 0.5 wt% 4-decyloxy benzaldehyde (DBA) shows dark to bright optical texture upon exposure of hydrazine vapours as revealed by polarizing optical microscopy under crossed polarizers. The hydrazine interacts with the doped DBA and form diimine compound which disrupt the orientation of aligned 5CB. The interaction between DBA and hydrazine has been also studied by Raman spectroscopy.

  7. Combustion Characteristics of Gasoline Direct Injection Engine Fuelled with Gasoline Blend Fuel of High n-Butanol Ratio%直喷汽油机燃用高比例正丁醇-汽油混合燃料的燃烧特性

    Institute of Scientific and Technical Information of China (English)

    陈征; 杨峰; 薛硕; 刘敬平

    2015-01-01

    在一台增压直喷汽油机上,进行了不同调和比例正丁醇-汽油混合燃料的燃烧特性研究,特别针对高比例正丁醇-汽油混合燃料(丁醇体积分数为 40%,)进行燃烧特性研究.结果表明,在相同负荷下,与汽油和低比例正丁醇-汽油混合燃料(丁醇体积分数为 15%,)相比,高比例混合燃料的滞燃期和燃烧持续期缩短,缸内最大爆发压力和瞬时放热率峰值升高,同时主放热时刻提前,燃烧反应速度加快;此外,高比例正丁醇-汽油混合燃料的燃烧稳定性增强,但抗爆震能力减弱;尽管其燃油消耗率有所升高,但有效热效率得到改善.%Combustion characteristics of n-butanol-gasoline blend fuels with different blending ratio,especially gasoline blend fuel of high n-butanol ratio(40%, n-butanol volume fraction),were investigated on a turbocharged gasoline direct injection(GDI)engine.The results showed that under the same load,for gasoline blend fuel of high n-butanol ratio,its ignition was delayed and combustion duration shortened compared with pure gaosoline and gasoline blend fuel of low n-butanol ratio (15%, n-butanol volume fraction).The peaks of combustion pressure and heat re-lease rate were raised,the main heat release timing advanced and the burning rate increased.In addition,its com-bustion stability was improved,but the anti-knock ability was degraded.Although its brake specific fuel consumption was increased,the brake thermal efficiency was improved.

  8. Ion temperature anisotropy in high power helium neutral beam fuelling experiments in JET

    Energy Technology Data Exchange (ETDEWEB)

    Maas, A.C.; Core, W.G.F.; Gerstel, U.C.; Von Hellermann, M.G.; Koenig, R.W.T.; Marcus, F.B. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking

    1994-07-01

    During helium beam fuelling experiments in JET, distinctive anisotropic features have been observed in the velocity distribution function describing both fast and thermal alpha particle populations. During the initial fuelling phase the central helium ion temperature observed perpendicular to the magnetic field is higher than the central electron temperature, while the central helium ion temperature observed parallel to the magnetic field is lower than or equal to the central electron temperature. In order to verify temperature measurements of both perpendicular and parallel lines of sight, other independent methods of deducing the ion temperature are investigated: deuterium ion temperature, deuterium density, comparison with neutron rates and profiles (influence of a possible metastable population of helium). 6 refs., 7 figs.

  9. The control of convection by fuelling and pumping in the JET pumped divertor

    Energy Technology Data Exchange (ETDEWEB)

    Harbour, P.J.; Andrew, P.; Campbell, D.; Clement, S.; Davies, S.; Ehrenberg, J.; Erents, S.K.; Gondhalekar, A.; Gadeberg, M.; Gottardi, N.; Von Hellermann, M.; Horton, L.; Loarte, A.; Lowry, C.; Maggi, C.; McCormick, K.; O`Brien, D.; Reichle, R.; Saibene, G.; Simonini, R.; Spence, J.; Stamp, M.; Stork, D.; Taroni, A.; Vlases, G. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking

    1994-07-01

    Convection from the scrape-off layer (SOL) to the divertor will control core impurities, if it retains them in a cold, dense, divertor plasma. This implies a high impurity concentration in the divertor, low at its entrance. Particle flux into the divertor entrance can be varied systematically in JET, using the new fuelling and pumping systems. The convection ratio has been estimated for various conditions of operation. Particle convection into the divertor should increase thermal convection, decreasing thermal conduction, and temperature and density gradients along the magnetic field, hence increasing the frictional force and decreasing the thermal force on impurities. Changes in convection in the SOL, caused by gaseous fuelling, have been studied, both experimentally in the JET Mk I divertor and with EDGE2/NIMBUS. 1 ref., 4 figs., 1 tab.

  10. Impact of fuelling and impurity on pedestal dynamics and instabilities in the HL-2A tokamak

    Science.gov (United States)

    Zhong, W. L.; Zou, X. L.; Gao, J. M.; Shi, Z. B.; Feng, B. B.; Cui, Z. Y.; Xu, M.; Shen, Y.; Dong, J. Q.; Ding, X. T.; Duan, X. R.; Liu, Yong; HL-2A Team

    2017-01-01

    In recent experiments of the HL-2A tokamak, the effect on the pedestal dynamics by the plasma fuelling with supersonic molecular beam injection (SMBI) has been intensively investigated. Experimental results in several tokamaks suggested that SMBI is a promising technique for ELM mitigation. In addition to the fuelling, the impact of impurities on the pedestal dynamics and instabilities has been investigated in HL-2A. Experimental results have shown that during the H-mode phase, a broadband electromagnetic (EM) turbulence was driven by peaked impurity density profile at the edge plasma region, and governed by double critical gradients of the impurity density. The absolute value of the threshold in positive gradient region is much lower than that in the negative region. This strong asymmetry in the critical gradients has been predicted by theoretical simulation. The results reveal that pedestal dynamics and heat loads can be actively controlled by exciting or changing pedestal instabilities.

  11. Application of exhaust gas fuel reforming in diesel and homogeneous charge compression ignition (HCCI) engines fuelled with biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Tsolakis, A. [School of Engineering, Mechanical and Manufacturing Engineering, University of Birmingham, Birmingham B15 2TT (United Kingdom); Megaritis, A. [Department of Mechanical Engineering, School of Engineering and Design, Brunel University, West London, Uxbridge UB8 3PH (United Kingdom); Yap, D. [Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075 (Singapore)

    2008-03-15

    This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed gas to a diesel engine fuelled by a mixture of 50% ultra low sulphur diesel (ULSD) and 50% rapeseed methyl ester (RME) as well as to a homogeneous charge compression ignition (HCCI) engine fuelled by bioethanol. In the case of the biodiesel fuelled engine, a reduction of NO{sub x} emissions was achieved without considerable smoke increase. In the case of the bioethanol fuelled HCCI engine, the engine tolerance to exhaust gas recirculation (EGR) was extended and hence the typically high pressure rise rates of HCCI engines, associated with intense combustion noise, were reduced. (author)

  12. Sustainability Indicators for Open-Cycle Thorium-Fuelled Nuclear Energy

    OpenAIRE

    2012-01-01

    The potential for countries which currently have a nominal nuclear energy infrastructure to adopt thorium-uranium-fuelled nuclear energy systems, using a once-through “open” nuclear fuel cycle, has been presented by the International Atomic Energy Agency. This paper highlights Generation III and III+ nuclear energy technologies that could potentially adopt an open thorium-uranium fuel cycle and qualitatively highlights the main differences between the open thorium-uranium and open uranium fue...

  13. Disaggregate demand for conventional and alternative fuelled vehicles in the Census Metropolitan Area of Hamilton, Canada

    Science.gov (United States)

    Potoglou, Dimitrios

    The focus of this thesis is twofold. First, it offers insight on how households' car-ownership behaviour is affected by urban form and availability of local-transit at the place of residence, after controlling for socio-economic and demographic characteristics. Second, it addresses the importance of vehicle attributes, household and individual characteristics as well as economic incentives and urban form to potential demand for alternative fuelled vehicles. Data for the empirical analyses of the aforementioned research activities were obtained through an innovative Internet survey, which is also documented in this thesis, conducted in the Census Metropolitan Area of Hamilton. The survey included a retrospective questionnaire of households' number and type of vehicles and a stated choices experiment for assessing the potential demand for alternative fuelled vehicles. Established approaches and emerging trends in automobile demand modelling identified early on in this thesis suggest a disaggregate approach and specifically, the estimation of discrete choice models both for explaining car ownership and vehicle-type choice behaviour. It is shown that mixed and diverse land uses as well as short distances between home and work are likely to decrease the probability of households to own a large number of cars. Regarding the demand for alternative fuelled vehicles, while vehicle attributes are particularly important, incentives such as free parking and access to high occupancy vehicle lanes will not influence the choice of hybrids or alternative fuelled vehicles. An improved understating of households' behaviour regarding the number of cars as well as the factors and trade-offs for choosing cleaner vehicles can be used to inform policy designed to reduce car ownership levels and encourage adoption of cleaner vehicle technologies in urban areas. Finally, the Internet survey sets the ground for further research on implementation and evaluation of this data collection method.

  14. A modelling evaluation of an ammonia-fuelled microchannel reformer for hydrogen generation

    OpenAIRE

    Chiuta, Steven; Everson, Raymond C.; Neomagus, Hein W.J.P.; Le Grange, Louis A.; Bessarabov, Dmitri G.

    2014-01-01

    Hydrogen production from an ammonia-fuelled microchannel reactor is simulated in a three-dimensional (3D) model implemented via Comsol Multiphysics™. The work described in this paper endeavours to obtain a mathematical framework that provides an understanding of reaction-coupled transport phenomena within the microchannel reactor. The transport processes and reactor performance are elucidated in terms of velocity, temperature, and species concentration distributions, as well as local reaction...

  15. Tracing the origin of the AGN fuelling reservoir in MCG-6-30-15

    Science.gov (United States)

    Raimundo, S. I.; Davies, R. I.; Canning, R. E. A.; Celotti, A.; Fabian, A. C.; Gandhi, P.

    2017-02-01

    The active galaxy MCG-6-30-15 has a 400 pc diameter stellar kinematically distinct core, counter-rotating with respect to the main body of the galaxy. Our previous high spatial resolution (0.1 arcsec) H-band observations of this galaxy mapped the stellar kinematics and [Fe II] 1.64 μm gas dynamics though mainly restricted to the spatial region of the counter-rotating core. In this work, we probe the stellar kinematics on a larger field of view and determine the ionized and molecular gas dynamics to study the formation of the counter-rotating core and the implications for active galactic nucleus (AGN) fuelling. We present integral field spectroscopy observations with SINFONI in the H and K bands in the central 1.2 kpc and with VIMOS HR-blue in the central 4 kpc of the galaxy. Ionized gas outflows of vout ˜ 100 km s-1 are traced by the [Ca VIII] 2.32 μm coronal line and extend out to at least a radius of r ˜ 140 pc. The molecular gas, traced by the H2 2.12 μm emission, is also counter-rotating with respect to the main body of the galaxy, indicating that the formation of the distinct core was associated with inflow of external gas into the centre of MCG-6-30-15. The molecular gas traces the available gas reservoir for AGN fuelling and is detected as close as r ˜ 50-100 pc. External gas accretion is able to significantly replenish the fuelling reservoir suggesting that the event which formed the counter-rotating core was also the main mechanism providing gas for AGN fuelling.

  16. Effects of gas types and models on optimized gas fuelling station reservoir's pressure

    OpenAIRE

    M. Farzaneh-Gord; M. Deymi-Dashtebayaz; Rahbari,H. R.

    2013-01-01

    There are similar algorithms and infrastructure for storing gas fuels at CNG (Compressed Natural Gas) and CHG (Compressed Hydrogen Gas) fuelling stations. In these stations, the fuels are usually stored in the cascade storage system to utilize the stations more efficiently. The cascade storage system generally divides into three reservoirs, commonly termed low, medium and high-pressure reservoirs. The pressures within these reservoirs have huge effects on performance of the stations. In the c...

  17. Technical and Feasibility Analysis of Gasoline and Natural Gas Fuelled Vehicles

    Directory of Open Access Journals (Sweden)

    Charalambos Chasos

    2014-03-01

    Full Text Available There is recent interest for the utilisation of natural gas for empowering the internal combustion engines (ICE of vehicles. The production of novel natural gas ICE for vehicles, as well as the conversion of existing gasoline fuelled ICE of vehicles to natural gas fuelled ICE are new technologies which require to be analysed and assessed. The objective of the present study is to examine the adaptation of natural gas as vehicle fuel and carry out a technical analysis and an economical feasibility analysis of the two types of ICE vehicles, namely gasoline and natural gas fuelled vehicles. The technical model uses the physical properties of the two fuels and the performance factors of internal combustion engines including brake thermal efficiency. The resulting exhaust gas emissions are also estimated by the technical model using combustion calculations which provide the expected levels of exhaust gas emissions. Based on the analysis with the technical model, comparisons of the two types of engines are performed. Furthermore, the estimated performance characteristics of the two types of engines, along with local statistical data on annual fuel imports and annual fuel consumption for transportation and data on the vehicles fleet for the case study of Cyprus are used as input in the economical model. For the base year 2013, data of natural gas price is also used in the economical model. The economical model estimates the capital cost, the carbon dioxide emissions avoidance of fines, the net present value and the internal rate of return of the investment of large scale adaptation of natural gas fuelled vehicles for the case study. From the results and comparisons, conclusions are drawn and recommendations are provided for the adaptation of natural gas vehicles which can provide improved performance with reduced pollutant emissions.

  18. Performance evaluation of common rail direct injection (CRDI) engine fuelled with Uppage Oil Methyl Ester (UOME)

    OpenAIRE

    D.N. Basavarajappa; Banapurmath, N. R.; S.V. Khandal

    2015-01-01

    For economic and social development of any country energy is one of the most essential requirements. Continuously increasing price of crude petroleum fuels in the present days coupled with alarming emissions and stringent emission regulations has led to growing attention towards use of alternative fuels like vegetable oils, alcoholic and gaseous fuels for diesel engine applications. Use of such fuels can ease the burden on the economy by curtailing the fuel imports. Diesel engines are highly ...

  19. Chemosensitive nanocomposite for conductometric detection of hydrazine and NADH

    Energy Technology Data Exchange (ETDEWEB)

    Lange, Ulrich [Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, 93047 Regensburg (Germany); Mirsky, Vladimir M., E-mail: vmirsky@hs-lausitz.d [Department of Nanobiotechnology, Lausitz University of Applied Sciences, 01968 Senftenberg (Germany)

    2011-04-01

    A new chemosensitive material based on palladium nanoparticles and PEDOT-PSS is described. The composite was characterized by transmission electron microscopy, cyclic voltammetry and in situ resistance measurements. The material was applied for conductometric detection of hydrazine and NADH. Upon exposure to these analytes PEDOT is reduced leading to an increase in its conductance. This process is catalyzed by palladium. A model for description of the potential dependence of polymer conductivity was suggested, tested and applied for the development of new calibration procedure of chemiresistors based on electroactive polymers.

  20. Performance of a capillary propellant management device with hydrazine

    Science.gov (United States)

    Tegart, J. R.

    1979-01-01

    The propellant management device that was successfully used in the Viking Orbiter spacecraft was selected for the main propulsion system of the Teleoperator Retrieval System (TRS). Due to differences in the missions and different propellants, the operation of this sheet metal vane device required reverification for the TRS application. An analytical investigation was performed considering the adverse acceleration environment and the high contract angle of the hydrazine propellant. Drop tower tests demonstrated that the device would provide propellant acquisition while the TRS was docked with Skylab, but its operation would have to be supplemented through propellant settling when free-flying.

  1. 60-WATT HYDRAZINE-AIR FUEL CELL SYSTEM.

    Science.gov (United States)

    fuel cell system as presented in our Design Plan. Prior to preparation of the Design Plan, a systems analysis of the basic electrochemical system was made. From the results of this analysis, the operating parameters of the support equipment were defined and an initial selection of components made. System components defined were: the cell stack, electrolyte tank, hydrazine feed system, cooling and chemical air blowers, voltage regulator, and thermal control system. A package design was then made for these components and the final detail design completed.

  2. A rhodol-based fluorescent chemosensor for hydrazine and its application in live cell bioimaging

    Science.gov (United States)

    Tiensomjitr, Khomsan; Noorat, Rattha; Wechakorn, Kanokorn; Prabpai, Samran; Suksen, Kanoknetr; Kanjanasirirat, Phongthon; Pewkliang, Yongyut; Borwornpinyo, Suparerk; Kongsaeree, Palangpon

    2017-10-01

    A rhodol cinnamate fluorescent chemosensor (RC) has been developed for selective detection of hydrazine (N2H4). In aqueous medium, the rhodol-based probe exhibited high selectivity for hydrazine among other molecules. The addition of hydrazine triggered a fluorescence emission with 48-fold enhancement based on hydrazinolysis and a subsequent ring-opening process. The chemical probe also displayed a selective colorimetric response toward N2H4 from colorless solution to pink, readily observed by the naked eye. The detection limit of RC for hydrazine was calculated to be 300 nM (9.6 ppb). RC is membrane permeable and was successfully demonstrated to detect hydrazine in live HepG2 cells by confocal fluorescence microscopy.

  3. Dihydropyrimidine based hydrazine dihydrochloride derivatives as potent urease inhibitors.

    Science.gov (United States)

    Khan, Ajmal; Hashim, Jamshed; Arshad, Nuzhat; Khan, Ijaz; Siddiqui, Naureen; Wadood, Abdul; Ali, Muzaffar; Arshad, Fiza; Khan, Khalid Mohammed; Choudhary, M Iqbal

    2016-02-01

    Four series of heterocyclic compounds 4-dihydropyrimidine-2-thiones 7-12 (series A), N,S-dimethyl-dihydropyrimidines 13-18 (series B), hydrazine derivatives of dihydropyrimidine 19-24 (series C), and tetrazolo dihydropyrimidine derivatives 25-30 (series D), were synthesized and evaluated for in vitro urease inhibitory activity. The series B-D were first time examined for urease inhibition. Series A and C were found to be significantly active with IC50 values between 34.7-42.9 and 15.0-26.0 μM, respectively. The structure-activity relationship showed that the free S atom and hydrazine moiety are the key pharmacophores against urease enzyme. The kinetic studies of the active series A (7-12) and C (19-24) were carried out to determine their modes of inhibition and dissociation constants Ki. Compounds of series A (7-12) and series C (19-24) showed a mixed-type of inhibition with Ki values ranging between 15.76-25.66 and 14.63-29.42 μM, respectively. The molecular docking results showed that all the active compounds of both series have significant binding interactions with the active sites specially Ni-ion of the urease enzyme. Cytotoxicity of all series A-D was also evaluated against mammalian mouse fibroblast 3T3 cell lines, and no toxicity was observed in cellular model.

  4. Complexes with Mercaptosuccinic Acid and Hydrazine as Ligands

    Directory of Open Access Journals (Sweden)

    S. Devipriya

    2013-01-01

    Full Text Available Reaction of hydrazine and mercaptosuccinic acid with metal ions forms\tcomplexes with general formula [Ln(N2H42CH2(COOCH(SH(COO1.5]·(H2O, where Ln = La(III, Pr(III, Nd(III, Sm(III, and Gd(III at pH 5. The complexes have been characterized by elemental analysis, IR and UV-visible spectroscopic, thermal and X-ray diffraction studies. The IR data reveal that the acid moiety in the complexes is present as dianion due to the deprotonation of COOH groups by lanthanides in these complexes, leaving –SH group unionized and hydrazine as bidental neutral ligand showing absorptions in the range of 945–948 cm−1. The thermoanalytical data evince that the complexes are stable up to 103°C and undergo complete decomposition in the range of 550–594°C resulting in metal oxides. SEM images of La2O3 and Gd2O3 residues show their nano sized clusters suggesting that the complexes may be used as precursors for nano La2O3 and Gd2O3, respectively. X-ray powder diffraction patterns show isomorphism among the complexes. The kinetic parameters of the decomposition of the complexes have been computed by Coats-Redfern equation.

  5. Facile growth of Ag@Pt bimetallic nanorods on electrochemically reduced graphene oxide for an enhanced electrooxidation of hydrazine

    Indian Academy of Sciences (India)

    Jeena S E; Selvaraju T

    2016-03-01

    An efficient transducer was constructed by the direct growth of bimetallic Ag@Pt nanorods (NRDs) on L−tryptophan functionalized electrochemically reduced graphene oxide (L−ERGO) modified electrode using galvanic displacement method for the electrooxidation of hydrazine.Initially, one dimensionalbimetallic Ag@Cu core−shell NRDs were grown on L−ERGO modified electrode by simple seed mediated growth method. Then, the Cu shells at bimetallic NRDs were exchanged by Pt through galvanic displacement method. Accordingly, the synergetic effect produced by the combination of Ag and Pt as NRDs at L−ERGO surface enabled an enhancement in the electrocatalytic efficiency for hydrazine oxidation. L−ERGO supported bimetallic Ag@Pt NRDs were characterised by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and cyclic voltammetric techniques. Finally, the modified electrode was successfully used for the electrooxidation of hydrazine in PB (pH 7.4)with a detection limit of 6*10−7M(SdivN=3). Importantly, the presence of Pt on Ag surface plays a vital role in the electrooxidation of [N2H4] at−0.2 V with an onset potential at−0.5 V where its overpotential has decreased. On the other hand, L−ERGO nanosheets tend to facilitate an effective immobilization of low density Ag seeds (Agseeds) on its surface. Chronoamperometric studies were used to study the linear correlation of [N2H4] between 1 mM and 10 mM. The modified electrode shows a high sensitivity and selectivity for a trace amount of N2H4 in the presence of different interfering cations and anions

  6. Efficiency evaluation of gas fuelled and electric driven buses in the public transport sector

    Energy Technology Data Exchange (ETDEWEB)

    Aigner, Tobias Alexander

    2013-07-01

    The following report evaluates the efficiency of gas fuelled and electric driven buses in the public transport sector on a theoretical basis. The results indicate that the combination of CHP power plants and electric driven buses reach an overall efficiency of about 51% throughout the production chain (Well-to-Wheel), including heat distribution losses. The overall Well-to-Wheel efficiency for conventional gas turbines without heat recovery decreases to around 28%. For gas fuelled buses the Well-to-Wheel efficiency is about 30%. The Co2-emissions are evaluated based on the example of a #Left Double Quotation Mark#Volvo B10L CNG#Right Double Quotation Mark# gas bus and the electric driven #Left Double Quotation Mark#Eurabus 600#Right Double Quotation Mark#. The low energy consumption of the electric driven bus results in Co2-emissions of only 181.4 g Co2/km (Grid-to-Wheel). Depending on the utilised power plant technology the overall Co2-emissions (Well-to-Wheel) amount to 307.5 g Co2/km for a CHP power plant and 553.5 g Co2/km for a conventional gas turbine. On the other hand, gas fuelled buses emit about 1.25 kg Co2/km (Tank-to-Wheel), which is eightfold the emissions of an electrical bus. The Well-to-Tank emissions further increase to about 1.32 kg Co2/km. The emission calculation is based on real gas consumption data from a Norwegian public transport utility. The results indicate that the combination of CHP plants and electrical buses provide a much higher efficiency while reducing Co2-emissions. (author)

  7. Occupational exposure to asbestos during renovation of oil-shale fuelled power plants in Estonia.

    Science.gov (United States)

    Kangur, Maie

    2007-01-01

    Many thousands of tonnes of asbestos were used in buildings in the past, especially for thermal insulation of pipes and boilers in power plants. Occupational exposure to asbestos dust now mainly occurs during demolition, renovation and routine maintenance activities. The objective of this study was to evaluate occupational exposure to airborne asbestos during renovation of solid oil-shale fuelled power plants carried out in 2001-2003. Air monitoring inside and outside of the renovation area was performed. The concentration of airborne fibres in the working environment increased during renovation but the valid limit value (0.1 fibres/cm(3)) was not exceeded.

  8. Determination of operating parameters of industrial engine fuelled with post processing gases with high hydrogen content

    Science.gov (United States)

    Brzeżański, M.; Mareczek, M.; Marek, W.; Papuga, T.

    2016-09-01

    The results of investigations of SI engine fuelled with hydrogen and mixed n-butanol with isobutanol have been presented in article. The idea of flexible feeding system and the aim and methodology of carried out measurement have been also described. Obtained results have been compared to the results of tests carried out during flexible feeding of the same engine. The proposed control system enables not only application of different liquid and gaseous fuels but also application of the fuels which chemical composition vary within the relatively short time intervals.

  9. Performance analysis of different organic Rankine cycle configurations on board liquefied natural gas-fuelled vessels

    DEFF Research Database (Denmark)

    Baldasso, Enrico; Andreasen, Jesper Graa; Meroni, Andrea

    2017-01-01

    Gas-fuelled shipping is expected to increase significantly in the coming years. Similarly, much effort is devoted to the study of waste heat recovery systems to be implemented on board ships. In this context, the organic Rankine cycle (ORC) technology is considered one of the most promising...... solutions. The ORC favorably compares to the steam Rankine cycle because of its simple layout and high efficiency, achievable by selecting a working fluid with desirable properties. This paper aims at assessing the fuel savings attainable by implementing ORC units on board vessels powered by liquefied...

  10. Antisymmetric Amino-Wagging Band of Hydrazine up to K' = 13 Levels

    Science.gov (United States)

    Gulaczyk; Kr; Valentin

    1997-12-01

    A newly recorded high-resolution infrared spectrum of hydrazine has been studied in the 729-1198 cm-1 region (the nu12 antisymmetric wagging band) with a resolution of 0.002 cm-1. About 1350 transitions with K' from 7 to 13 have been newly assigned and about 2350 transitions with lower values of K' reanalyzed with the improved precision. The effective parameters have been calculated separately for each value of K' using the Hougen-Ohashi hamiltonian for hydrazine. The extended assignment completes the analysis of the nu12 band of hydrazine. Copyright 1997 Academic Press. Copyright 1997Academic Press

  11. An Ecosystem-Based Job-Creation Engine Fuelled by Technology Entrepreneurs

    Directory of Open Access Journals (Sweden)

    Sonia D. Bot

    2013-02-01

    Full Text Available Job creation is at the centre of the rationale provided by governments and publicly funded organizations for investing in services purported to support entrepreneurs to launch and grow technology startups. However, little is known about how to design and build the engines that convert these publicly funded services into jobs in a region. In this article, we argue that the architecture of a job-creation engine fuelled by technology entrepreneurs is important and that it should be made visible to the stakeholders of a regional venture system. The manner in which the components of a job-creation engine are organized and integrated determines the effectiveness and efficiency of the conversion of public funds into jobs. Making visible the architecture of a job-creation engine enables individuals and organizations to: i better understand the link between the investment made to service technology entrepreneurs and systematic job creation; ii utilize the regional venture system more effectively; and iii set the performance benchmark for capability improvement and rapid adjustment to environmental changes. The experience gained from operating Lead To Win since 2009 is used to describe the architecture of a job-creation engine fuelled by technology entrepreneurs that operate in Canada’s Capital Region. Lead To Win is an ecosystem designed to help a technology venture generate sufficient revenue to create six or more knowledge jobs in the region within three years of inception.

  12. Optimization of biomass fuelled systems for distributed power generation using Particle Swarm Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, P. Reche; Reyes, N. Ruiz [Department of Telecommunication Engineering, University of Jaen, 23700 EPS Linares, Jaen (Spain); Gonzalez, M. Gomez [Junta of Andalusia, 23470 Maestro Francisco Yuste 2, Cazorla, Jaen (Spain); Jurado, F. [Department of Electrical Engineering, University of Jaen, 23700 EPS Linares, Jaen (Spain)

    2008-08-15

    With sufficient territory and abundant biomass resources Spain appears to have suitable conditions to develop biomass utilization technologies. As an important decentralized power technology, biomass gasification and power generation has a potential market in making use of biomass wastes. This paper addresses biomass fuelled generation of electricity in the specific aspect of finding the best location and the supply area of the electric generation plant for three alternative technologies (gas motor, gas turbine and fuel cell-microturbine hybrid power cycle), taking into account the variables involved in the problem, such as the local distribution of biomass resources, transportation costs, distance to existing electric lines, etc. For each technology, not only optimal location and supply area of the biomass plant, but also net present value and generated electric power are determined by an own binary variant of Particle Swarm Optimization (PSO). According to the values derived from the optimization algorithm, the most profitable technology can be chosen. Computer simulations show the good performance of the proposed binary PSO algorithm to optimize biomass fuelled systems for distributed power generation. (author)

  13. Avian pectoral muscle size rapidly tracks body mass changes during flight, fasting and fuelling.

    Science.gov (United States)

    Lindström, A; Kvist, A; Piersma, T; Dekinga, A; Dietz, M W

    2000-03-01

    We used ultrasonic imaging to monitor short-term changes in the pectoral muscle size of captive red knots Calidris canutus. Pectoral muscle thickness changed rapidly and consistently in parallel with body mass changes caused by flight, fasting and fuelling. Four knots flew repeatedly for 10 h periods in a wind tunnel. Over this period, pectoral muscle thickness decreased in parallel with the decrease in body mass. The change in pectoral muscle thickness during flight was indistinguishable from that during periods of natural and experimental fasting and fuelling. The body-mass-related variation in pectoral muscle thickness between and within individuals was not related to the amount of flight, indicating that changes in avian muscle do not require power-training as in mammals. Our study suggests that it is possible for birds to consume and replace their flight muscles on a time scale short enough to allow these muscles to be used as part of the energy supply for migratory flight. The adaptive significance of the changes in pectoral muscle mass cannot be explained by reproductive needs since our knots were in the early winter phase of their annual cycle. Instead, pectoral muscle mass changes may reflect (i) the breakdown of protein during heavy exercise and its subsequent restoration, (ii) the regulation of flight capacity to maintain optimal flight performance when body mass varies, or (iii) the need for a particular protein:fat ratio in winter survival stores.

  14. Density and impurity profile behaviours in HL-2A tokamak with different gas fuelling methods

    Institute of Scientific and Technical Information of China (English)

    Cui Zheng-Ying; Zhou Yan; Li Wei; Feng Bei-Bin; Sun Ping; Dong Chun-Feng; Liu Yi; Hong Wen-Yu; Yang Qing-Wei; Ding Xuan-Tong; Duan Xu-Ru

    2009-01-01

    The electron density profile peaking and the impurity accumulation in the HL-2A tokamak plasma are observed when three kinds of fuelling methods are separately used at different fuelling particle locations.The density profile becomes more peaked when the line-averaged electron density approaches the Greenwald density limit nG and,consequently,impurity accumulation is often observed.A linear increase regime in the density range ne<0.6nG and a saturation regime in ne>0.6nG are obtained.There is no significant difference in achieved density peaking factor fne between the supersonic molecular beam injection (SMBI) and gas puffing into the plasma main chamber.However,the achieved fne is relatively low,in particular,in the case of density below 0.7nG,when the working gas is puffed into the divertor chamber.A discharge with a density as high as 1.2nG,i.e.ne=1.2nG,can be achieved by SMBI just after siliconization as a wall conditioning.The metallic impurities,such as iron and chromium,also increase remarkably when the impurity accumulation happens.The mechanism behind the density peaking and impurity accumulation is studied by investigating both the density peaking factor versus the effective collisionality and the radiation peaking versus density peaking.

  15. Remediation of Cr(VI)-Contaminated Soil Using the Acidified Hydrazine Hydrate.

    Science.gov (United States)

    Ma, Yameng; Li, Fangfang; Jiang, Yuling; Yang, Weihua; Lv, Lv; Xue, Haotian; Wang, Yangyang

    2016-09-01

    Acidified hydrazine hydrate was used to remediate Cr(VI)-contaminated soil. The content of water-soluble Cr(VI) in contaminated soil was 4977.53 mg/kg. The optimal initial pH of hydrazine hydrate solution, soil to solution ratio and molar ratio of Cr(VI) to hydrazine hydrate for remediation of Cr(VI)-contaminated soil were 5.0, 3:1 and 1:3, respectively. Over 99.50 % of water-soluble Cr(VI) in the contaminated soil was reduced at the optimal condition within 30 min. The remediated soil can keep stable within 4 months. Meanwhile the total phosphorus increased from 0.47 to 4.29 g/kg, indicating that using of acidified hydrazine hydrate is an effective method to remediate Cr(VI)-contaminated soil.

  16. Au(I)-Catalyzted Synthesis of 5-Bromodifluoromethyl Pyrazoles from Fluorinated Alkynyl Ketones and Hydrazine

    Institute of Scientific and Technical Information of China (English)

    李珊; 李正珂; 彭东杰; 李亚军; 祝江涛; 解海波; 袁雅芬; 陈资衔; 吴永明

    2011-01-01

    Fluorinated alkynyl ketones react with hydrazine to give fluorinated pyrazols in good to excellent yields with Au(I) as catalyst. All the reactions were carried out at room temperature with excellent regioselectivity.

  17. Fixation and loss of hydrazine-induced premutational damage in Haemophilus influenzae

    Energy Technology Data Exchange (ETDEWEB)

    Kimball, R.F.; Hirsch, B.F.

    1976-01-01

    Premutational damage induced in Haemophilus influenzae by hydrazine appears to be fixed as final mutation only at replication as judged by the transformation assay. Fixation at replication is independent of the rec 1 gene, unlike the case with nitrosocarbaryl. Prior to replication premutational damage induced by hydrazine disappears by an unknown process that is not dependent on the presence of a pyrimidine dimer excision system nor on the rec 1 gene. Hydrazine does not produce detectable single-strand breaks or alkali-labile sites in the treated DNA nor gaps in DNA newly synthesized after treatment. In these respects it also differs from nitroso compounds. It is concluded that hydrazine acts to produce an altered base, possibly N(4)-aminocytosine, that produces mutations by mispairing at replication rather than by error-prone repair.

  18. U.S. experience with hydrazine and flow-accelerated corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Merilo, M.; Munson, D.; Horowitz, J.S. [EPRI US (United States); Bouchacourt, M. [EDF France (France)

    2002-07-01

    Flow-accelerated corrosion (FAC) has been studied intensely for the last 30 years. In most regards, the parametric behavior of FAC has been well understood since the eighties. However, recent experience showing the impact of hydrazine has challenged this understanding. Until the early 1990's, hydrazine levels at most U.S. PWRs had been low, typically around 20 ppb. Since the mid 1990's the U.S. trend has been to increase hydrazine concentration (> 100 ppb) to provide further protection the steam generators tubes from stress corrosion cracking. In the last five years, high concentrations of hydrazine have been shown in the laboratory to affect the rate of FAC. These experiments have demonstrated this effect although there remains considerable scatter in the data supporting this conclusion. It is believed that the impact of hydrazine is due to the change in the oxidizing-reducing potential of the solution, but there is no generally accepted theory to completely describe its behavior. Recently, plant experience has begun to support the laboratory data that high hydrazine does increase the rate of FAC. It should be noted that there are several factors affecting the rate of FAC. Since most plants have changed their water chemistry in recent years, it has been difficult to ''back-out'' the influence of hydrazine. But now, plant experience has clearly shown the impact of high hydrazine especially in the high temperature portions of the feedwater piping. This has been seen at two PWRs, discussed below, and perhaps at several others. This accelerated thinning of the feedwater piping is especially significant since feedwater piping is particularly expensive to inspect and to replace. In addition to the experience with piping, there has also been degradation reported in steam generators, particularly at Gravelines in France, possibly linked to high hydrazine. In order to deal with this issue, the EPRI computer program CHECWORKS was modified in

  19. Propellant Grade Hydrazine in Mono/Bi-propellant Thrusters: Preparation and Performance Evaluation

    Directory of Open Access Journals (Sweden)

    S. Krishnamachary

    2015-03-01

    Full Text Available Propellant grade hydrazine was prepared with 64 per cent yield and 95.5 per cent purity. Purity of the propellant grade hydrazine was determined using wet chemical, gas chromatographic (GC and eudiometric methods. It was observed that the compositions containing blends of hydrazine-methyl alcohol-ammonium nitrate and hydrazine-methyl alcohol-ammonium perchlorate were not found to be frozen even after cooling to -65 °C for 30 minutes. Mono and bi-propellant thrusters were designed and developed to demonstrate the performance of prepared propellant grade hydrazine as a promising rocket fuel. Five static tests with 22 N thruster and one static test with 1 N thruster were performed successfully in mono-propellant mode. The hurdles of chamber pressure oscillations were overcome by compact packing of the catalyst. The desired decomposition and chamber pressure were achieved. One static test was performed successfully with 60 N bi-propellant thruster. The desired chamber pressure and thrust were achieved. The combustion was smooth and C* achieved was higher than that of UH-25, N2O4 combination. The performance of prepared propellant grade hydrazine shows it as a promising rocket fuels.Defence Science Journal, Vol. 65, No. 1, January 2015, pp.31-38, DOI:http://dx.doi.org/10.14429/dsj.65.7986

  20. Hydrazine selective dual signaling chemodosimetric probe in physiological conditions and its application in live cells

    Energy Technology Data Exchange (ETDEWEB)

    Nandi, Sandip; Sahana, Animesh; Mandal, Sandip [Department of Chemistry, The University of Burdwan, Burdwan, 713104 West Bengal (India); Sengupta, Archya; Chatterjee, Ansuman [Department of Zoology, Visva Bharati University, Santiniketan, West Bengal (India); Safin, Damir A., E-mail: damir.a.safin@gmail.com [Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST), Université catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve (Belgium); Babashkina, Maria G.; Tumanov, Nikolay A.; Filinchuk, Yaroslav [Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST), Université catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve (Belgium); Das, Debasis, E-mail: ddas100in@yahoo.com [Department of Chemistry, The University of Burdwan, Burdwan, 713104 West Bengal (India)

    2015-09-17

    A rhodamine–cyanobenzene conjugate, (E)-4-((2-(3′,6′-bis(diethylamino)-3-oxospiro[isoindoline-1,9′-xanthene] -2-yl)ethylimino)methyl)benzonitrile (1), which structure has been elucidated by single crystal X-ray diffraction, was synthesized for selective fluorescent “turn-on” and colorimetric recognition of hydrazine at physiological pH 7.4. It was established that 1 detects hydrazine up to 58 nM. The probe is useful for the detection of intracellular hydrazine in the human breast cancer cells MCF-7 using a fluorescence microscope. Spirolactam ring opening of 1, followed by its hydrolysis, was established as a probable mechanism for the selective sensing of hydrazine. - Highlights: • A selective rhodamine–cyanobenzene conjugate is synthesized. • The conjugate is a selective dual signaling chemodosimetric probe towards hydrazine. • Spirolactam ring opening of the probe, followed by its hydrolysis, is the sensing mechanism. • The probe detects hydrazine in the human breast cancer cells MCF-7 imaging.

  1. Preparation of hydrazine functionalized polymer brushes hybrid magnetic nanoparticles for highly specific enrichment of glycopeptides.

    Science.gov (United States)

    Huang, Guang; Sun, Zhen; Qin, Hongqiang; Zhao, Liang; Xiong, Zhichao; Peng, Xiaojun; Ou, Junjie; Zou, Hanfa

    2014-05-07

    Hydrazide chemistry is a powerful technique in glycopeptides enrichment. However, the low density of the monolayer hydrazine groups on the conventional hydrazine-functionalized magnetic nanoparticles limits the efficiency of glycopeptides enrichment. Herein, a novel magnetic nanoparticle grafted with poly(glycidyl methacrylate) (GMA) brushes was fabricated via reversible addition-fragmentation chain transfer (RAFT) polymerization, and a large amount of hydrazine groups were further introduced to the GMA brushes by ring-opening the epoxy groups with hydrazine hydrate. The resulting magnetic nanoparticles (denoted as Fe3O4@SiO2@GMA-NHNH2) demonstrated the high specificity of capturing glycopeptides from a tryptic digest of the sample comprising a standard non-glycosylated protein bovine serum albumin (BSA) and four standard glycoproteins with a weight ratio of 50 : 1, and the detection limit was as low as 130 fmol. In the analysis of a real complex biological sample, the tryptic digest of hepatocellular carcinoma, 179 glycosites were identified by the Fe3O4@SiO2@GMA-NHNH2 nanoparticles, surpassing that of 68 glycosites by Fe3O4@SiO2-single-NHNH2 (with monolayer hydrazine groups on the surface). It can be expected that the magnetic nanoparticles modified with hydrazine functionalized polymer brushes via RAFT technique will improve the specificity and the binding capacity of glycopeptides from complex samples, and show great potential in the analysis of protein glycosylation in biological samples.

  2. Emissions from Diesel and Gasoline Vehicles Fuelled by Fischer-Tropsch Fuels and Similar Fuels

    DEFF Research Database (Denmark)

    Larsen, Ulrik; Lundorff, Peter; Ivarsson, Anders

    2007-01-01

    vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were...... and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline. FT based diesel generally showed good emission performance, whereas the FT based gasoline not necessary lead to lower emissions. On the other hand, the Aspen fuel did show many advantages for the emissions from the gasoline......The described investigation was carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from...

  3. Auxiliary power unit based on a solid oxide fuel cell and fuelled with diesel

    Science.gov (United States)

    Lawrence, Jeremy; Boltze, Matthias

    An auxiliary power unit (APU) is presented that is fuelled with diesel, thermally self-sustaining, and based on a solid oxide fuel cell (SOFC). The APU is rated at 1 kW electrical, and can generate electrical power after a 3 h warm-up phase. System features include a "dry" catalytic partial oxidation (CPOX) diesel reformer, a 30 cell SOFC stack with an open cathode, and a porous-media afterburner. The APU does not require a supply of external water. The SOFC stack is an outcome of a development partnership with H.C. Starck GmbH and Fraunhofer IKTS, and is discussed in detail in an accompanying paper.

  4. Epidermal cells help coordinate leukocyte migration during inflammation through fatty acid-fuelled matrix metalloproteinase production.

    Science.gov (United States)

    Hall, Christopher J; Boyle, Rachel H; Sun, Xueying; Wicker, Sophie M; Misa, June P; Krissansen, Geoffrey W; Print, Cristin G; Crosier, Kathryn E; Crosier, Philip S

    2014-05-23

    In addition to satisfying the metabolic demands of cells, mitochondrial metabolism helps regulate immune cell function. To date, such cell-intrinsic metabolic-immunologic cross-talk has only been described operating in cells of the immune system. Here we show that epidermal cells utilize fatty acid β-oxidation to fuel their contribution to the immune response during cutaneous inflammation. By live imaging metabolic and immunological processes within intact zebrafish embryos during cutaneous inflammation, we uncover a mechanism where elevated β-oxidation-fuelled mitochondria-derived reactive oxygen species within epidermal cells helps guide matrix metalloproteinase-driven leukocyte recruitment. This mechanism requires the activity of a zebrafish homologue of the mammalian mitochondrial enzyme, Immunoresponsive gene 1. This study describes the first example of metabolic reprogramming operating within a non-immune cell type to help control its contribution to the immune response. Targeting of this metabolic-immunologic interface within keratinocytes may prove useful in treating inflammatory dermatoses.

  5. Performance and Emissions of Internal Combustion Engine Fuelled With CNG - A Review

    Directory of Open Access Journals (Sweden)

    P. M. Darade

    2012-10-01

    Full Text Available The development of alternative fuels such as natural gases has become very essential because of the continuously decrease in the petroleum reserves and also their contribution for pollutants. In this paper, a survey of research papers on the utilization of Compressed Natural Gas in the Internal Combustion engines along with its effects on the performance and emissions is done. It is revealed that the performance characteristics except thermal efficiency and exhaust temperature, various other performance parameters like brake mean effective pressure, power, torque and brake specific fuel consumption are decreased for CNG fuelled engine while the emission characteristics of unburnt hydrocarbon, Carbon monoxide and Carbon-di-oxide except nitrogen oxides are better for CNG compared to petrol and diesel engines. The improvement in performance is observed with the addition of hydrogen.

  6. Performance of Membrane-Assisted Solid Oxide Fuel Cell System Fuelled by Bioethanol

    Directory of Open Access Journals (Sweden)

    Amornchai Arpornwichanop

    2011-04-01

    Full Text Available The membrane separation units for bioethanol purification including pervaporation and vapor permeation are integrated with the bioethanol-fuelled solid oxide fuel cell (SOFC system. The preliminary calculations indicate that Hydrophilic type is a suitable membrane for vapor permeation to be installed after a hydrophobic pervaporation. Based on energy self-sufficient condition and data of available pervaporation membranes, the simulation results show that the use of vapor permeation unit after the pervaporation can significantly improve the overall electrical efficiency from 10.96% for the system with pervaporation alone to 26.56%. Regarding the effect of ethanol recovery, the ethanol recovery at 75% can offer the optimal overall efficiency from the proposed purification system compared to the ethanol recovery at 31.16% for the case with the single pervaporation.

  7. Energy and Exergy Analysis of a Diesel Engine Fuelled with Diesel and Simarouba Biodiesel Blends

    Science.gov (United States)

    Panigrahi, Nabnit; Mohanty, Mahendra Kumar; Mishra, Sruti Ranjan; Mohanty, Ramesh Chandra

    2016-08-01

    This article intends to determine the available work and various losses of a diesel engine fuelled with diesel and SB20 (20 % Simarouba biodiesel by volume blended with 80 % diesel by volume). The energy and exergy analysis were carried out by using first law and second law of thermodynamics respectively. The experiments were carried out on a 3.5 kW compression ignition engine. The analysis was conducted on per mole of fuel basis. The energy analysis indicates that about 37.23 and 37.79 % of input energy is converted into the capacity to do work for diesel and SB20 respectively. The exergetic efficiency was 34.8 and 35 % for diesel and Simarouba respectively. Comparative study indicates that the energetic and exergetic performance of SB20 resembles with that of diesel fuel.

  8. Plasma fuelling with cryogenic pellets in the stellarator TJ-II

    Energy Technology Data Exchange (ETDEWEB)

    McCarthy, K. J. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Panadero, N. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Velasco, J. L. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Combs, S. K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Caughman, J. B. O. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Fontdecaba, J. M. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Foust, C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); García, R. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Hernández Sánchez, J. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Navarro, M. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Pastor, I. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain); Soleto, A. [Research Centre for Energy, Environment and Technology (CIEMAT), Madrid (Spain)

    2017-04-04

    Cryogenic pellet injection is a widely used technique for delivering fuel to the core of magnetically confined plasmas. Indeed, such systems are currently functioning on many tokamak, reversed field pinch and stellarator devices. A pipe-gun-type pellet injector is now operated on the TJ-II, a low-magnetic shear stellarator of the heliac type. Cryogenic hydrogen pellets, containing between 3×1018 and 4×1019 atoms, are injected at velocities between 800 and 1200 m s-1 from its low-field side into plasmas created and/or maintained in this device by electron cyclotron resonance and/or neutral beam injection heating. In this paper, the first systematic study of pellet ablation, particle deposition and fuelling efficiency is presented for TJ-II. From this, light-emission profiles from ablating pellets are found to be in reasonable agreement with simulated pellet ablation profiles (created using a neutral gas shielding-based code) for both heating scenarios. In addition, radial offsets between recorded light-emission profiles and particle deposition profiles provide evidence for rapid outward drifting of ablated material that leads to pellet particle loss from the plasma. Finally, fuelling efficiencies are documented for a range of target plasma densities (~4×1018– ~2×1019 m-3). These range from ~20%– ~85% and are determined to be sensitive to pellet penetration depth. Additional observations, such as enhanced core ablation, are discussed and planned future work is outlined.

  9. An Internet based stated choices household survey for alternative fuelled vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Potoglou, D.; Kanaroglou, P.S. [McMaster Univ., Hamilton, ON (Canada). Centre for Spatial Analysis

    2006-01-15

    Vehicles fuelled by alternative energy sources have the potential to reduce greenhouse gas emissions and other negative externalities associated with the transportation sector. However, the demand for alternative fuelled vehicles (AFV) and the effectiveness of incentives, marketing promotions, new vehicle designs, and fuel subsystems should be evaluated before devising policy measures that promote the use of new vehicle technologies. This paper discussed the design and application of a stated choices experiment for the demand for AFVs that is administered uniquely through the Internet. The use of the Internet is a new method of survey data collection which provides many advantages over tradition methods of computer-aided telephone interviews (CATI) and mail interviews. The main advantages of Internet surveys are the savings in cost and time. The authors designed a Choice Internet Based Experiment for Research on Cars (CIBER-CARS). It is a self-administered online questionnaire that was used in the Census Metropolitan Area of Hamilton, Ontario. This paper described the survey design in detail and reviewed the implementation and data collection procedures. Measures for evaluating the efficiency of the Internet survey were also highlighted and the characteristics of the collected information were summarized with emphasis on the profiles of respondents and households. The characteristics of this survey were also compared with those of a similar study conducted in the State of California. Out of the 902 respondents in Hamilton, 602 stated that they would buy a vehicle in the next 5 years and 496 provided valid observations for each of the 8 stated choice exercises that included 3 fuel-type options (gasoline, hybrid, and alternative fuel) and 8 vehicle type/size-classes. The objective was to determine the impact of vehicle attributes and household characteristics to the actual choice of certain vehicles. It was expected that people with access to information via the

  10. Plasma fuelling with cryogenic pellets in the stellarator TJ-II

    Science.gov (United States)

    McCarthy, K. J.; Panadero, N.; Velasco, J. L.; Combs, S. K.; Caughman, J. B. O.; Fontdecaba, J. M.; Foust, C.; García, R.; Hernández Sánchez, J.; Navarro, M.; Pastor, I.; Soleto, A.; the TJ-II Team

    2017-05-01

    Cryogenic pellet injection is a widely used technique for delivering fuel to the core of magnetically confined plasmas. Indeed, such systems are currently functioning on many tokamak, reversed field pinch and stellarator devices. A pipe-gun-type pellet injector is now operated on the TJ-II, a low-magnetic shear stellarator of the heliac type. Cryogenic hydrogen pellets, containing between 3  ×  1018 and 4  ×  1019 atoms, are injected at velocities between 800 and 1200 m s-1 from its low-field side into plasmas created and/or maintained in this device by electron cyclotron resonance and/or neutral beam injection heating. In this paper, the first systematic study of pellet ablation, particle deposition and fuelling efficiency is presented for TJ-II. From this, light-emission profiles from ablating pellets are found to be in reasonable agreement with simulated pellet ablation profiles (created using a neutral gas shielding-based code) for both heating scenarios. In addition, radial offsets between recorded light-emission profiles and particle deposition profiles provide evidence for rapid outward drifting of ablated material that leads to pellet particle loss from the plasma. Finally, fuelling efficiencies are documented for a range of target plasma densities (~4  ×  1018-  ~2  ×  1019 m-3). These range from ~20%-  ~85% and are determined to be sensitive to pellet penetration depth. Additional observations, such as enhanced core ablation, are discussed and planned future work is outlined.

  11. Exhaust gas catalysts for heavy-duty vehicles fuelled by alcohol or biogas

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, L.J.; Wahlberg, A.M.; Jaeraas, S.G. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Chemical Engineering and Technology

    1997-06-01

    The long-term objective for the project is to develop tailor-made exhaust gas catalysts for heavy-duty ethanol fuelled diesel vehicles operating in urban traffic. Due to special problems, related to emissions of unregulated compounds emanating from ethanol fuelled buses in Swedish fleet tests, a catalyst research programme has been initiated. The engineering target was to achieve a light-off temperature (T{sub 50}) for ethanol conversion below 110 deg C and a selectivity for total oxidation over 90 %. In this report results from laboratory-reactor tests are described. The results indicate that by combining two different precious metals both activity and selectivity can be positively affected compared to the properties of the corresponding mono metallic catalysts. The best results show a light-off temperature for ethanol conversion below 100 deg C. The base metal oxides were more selective for total oxidation than the corresponding precious metal catalysts. The results also indicate a considerable interaction between support and active material which affects the product distribution in catalytic oxidation of ethanol. At temperatures below 250 deg C the by-product formation can be quite high and the major by-product is acetaldehyde. The metal support interaction also has a certain influence on the oxidation of NO to NO{sub 2}. The results show that the NO{sub 2} formation can be suppressed without considerably affecting the activity of the catalyst. This report also includes a preliminary life cycle analysis (LCA) and life cycle cost (LCC) estimate for exhaust gas catalysts intended for heavy-duty ethanol vehicles in urban traffic. 22 refs, numerous figs and tabs

  12. Evaporative emissions of 1,3-butadiene from petrol-fuelled motor vehicles

    Science.gov (United States)

    Ye, Y.; Galbally, I. E.; Weeks, I. A.; Duffy, B. L.; Nelson, P. F.

    This study reports the identification and quantification of 1,3-butadiene in petrol and in the evaporative emissions from Australian light-duty passenger vehicles. The mass fraction of 1,3-butadiene in each of the different grades of any brand of Australian petrol was found to be relatively constant for a given marketing area. However, the mass fractions vary significantly between the different brands (or refineries) from 0.004±0.001% to 0.047±0.008%. The measurements of the evaporative emissions of 1,3-butadiene from in-service motor vehicles were performed using standard Australian Design Rule 37/00 (ADR 37/00) Sealed Housing Evaporative Determination (SHED) tests. For post-1985 catalyst equipped vehicles fuelled with unleaded petrol, average evaporative emissions of 1,3-butadiene were 9.4 (0.7-22) and 5.0 (0.1-23) mg per test for diurnal and hot soak SHED tests, respectively. The corresponding average evaporative emissions for the older, pre-1986 non-catalyst equipped vehicles fuelled with leaded petrol were 26.5 (11.7-45.4) and 9.2 (4.3-13.1) mg per test, respectively, about double the observed emissions from newer vehicles. For the complete vehicle set (all ages), the average mass fraction of 1,3-butadiene in the total hydrocarbon (sum of C 1-C 10 hydrocarbons) emission was 0.21±0.14% from the diurnal phase and was 0.11±0.06% from the hot-soak phase. Evaporative emissions were estimated to contribute about 4% (ranging from 1-15%) of the total (exhaust and evaporative) emissions of 1,3-butadiene from Australian motor vehicles.

  13. Hydrazine borane-induced destabilization of ammonia borane, and vice versa

    Energy Technology Data Exchange (ETDEWEB)

    Petit, Jean-Fabien; Moussa, Georges [IEM (Institut Europeen des Membranes), UMR 5635 (CNRS-ENSCM-UM2), Universite Montpellier 2, Place E. Bataillon, F-34095 Montpellier (France); Demirci, Umit B., E-mail: umit.demirci@um2.fr [IEM (Institut Europeen des Membranes), UMR 5635 (CNRS-ENSCM-UM2), Universite Montpellier 2, Place E. Bataillon, F-34095 Montpellier (France); Toche, François; Chiriac, Rodica [Université Lyon 1, CNRS, UMR 5615, Laboratoire des Multimatériaux et Interfaces, 43 boulevard du 11 Novembre 1918, F-69622 Villeurbanne (France); Miele, Philippe [IEM (Institut Europeen des Membranes), UMR 5635 (CNRS-ENSCM-UM2), Universite Montpellier 2, Place E. Bataillon, F-34095 Montpellier (France)

    2014-08-15

    Graphical abstract: - Highlights: • Hydrazine borane and ammoniaborane (mole ratio 1:1) destabilize each other. • This is characterized by a melting point at ∼30 °C and decomposition into hydrazine. • Also, some hydrogen H{sub 2} is “explosively” liberated at around 90 °C. • The mixture can be however stabilized into a potential hydrogen storage material. • This hydrogen storage material dehydrogenates up to 300 °C to form boron nitride. - Abstract: In the field of solid-state chemical hydrogen storage, ammonia borane NH{sub 3}BH{sub 3} has been widely studied while hydrazine borane N{sub 2}H{sub 4}BH{sub 3} can be considered as a “novel” material. In the present work, we investigated the behaviour of these boranes when mixed together in a mole ratio of 1:1. Hydrazine borane and ammonia borane destabilize each other. Though stable at 20–25 °C, the mixture melts at ∼30 °C and then undergoes significant decomposition, with desorption of hydrogen H{sub 2} and hydrazine N{sub 2}H{sub 4} from 67 °C. This is explained by the fact that the presence of hydrazine borane disrupts the H{sup δ+}⋯H{sup δ−} network of ammonia borane, and vice versa; the mixture is then much less stable than the pristine boranes. The mixture can nevertheless be stabilized (by heat- or vacuum-treatment and thus extraction of evolving hydrogen and hydrazine), making the as-obtained solid a potential chemical hydrogen storage material. Over the range 25–300 °C, it is able to release ca. 11.4 wt% of almost pure H{sub 2}. Furthermore forms boron nitride as the solid residue, at temperatures as low as 300 °C.

  14. Multidisciplinary Design Optimization and Analysis of Hydrazine Monopropellant Propulsion System

    Directory of Open Access Journals (Sweden)

    Amirhossein Adami

    2015-01-01

    Full Text Available Monopropellant propulsion systems are widely used especially for low cost attitude control or orbit correction (orbit maintenance. To optimize the total propulsion system, subsystems should be optimized. Chemical decomposition, aerothermodynamics, and structure disciplines demand different optimum condition such as tank pressure, catalyst bed length and diameter, catalyst bed pressure, and nozzle geometry. Subsystem conflicts can be solved by multidisciplinary design optimization (MDO technique with simultaneous optimization of all subsystems with respect to any criteria and limitations. In this paper, monopropellant propulsion system design algorithm is presented and the results of the proposed algorithm are validated. Then, multidisciplinary design optimization of hydrazine propulsion system is proposed. The goal of optimization can be selected as minimizing the total mass (including propellant, minimizing the propellant mass (maximizing the Isp, or minimizing the dry mass. Minimum total mass, minimum propellant mass, and minimum dry mass are derived using MDO technique. It is shown that minimum total mass, minimum dry mass, and minimum propellant mass take place in different conditions. The optimum parameters include bed-loading, inlet pressure, mass flow, nozzle geometry, catalyst bed length and diameter, propellant tank mass, specific impulse (Isp, and feeding mass which are derived using genetic algorithm (GA.

  15. Potentiation of cardiovascular responses to hydralazine by diverse hydrazine derivatives.

    Science.gov (United States)

    Vidrio, H

    1994-10-01

    After the observation that in anesthetized rats the antitubercular agent isoniazid potentiates the hypotensive effect of the vasodilator hydralazine (H) and transforms the accompanying reflex tachycardia to bradycardia, a number of hydrazine (HYD) derivatives were tested for this interaction in pentobarbital-anesthetized rats. All HYDs studied elicited this response in varying degrees, isoniazid, thiosemicarbazide and thiocarbohydrazide being the most active. Experiments were then carried out to explore the possibility of an influence of the HYDs on reflex reactions to H due to interaction with pyridoxal, inhibition of glutamic acid decarboxylase and decreased levels of brain gamma-aminobutyric acid. Although the H-HYDs interaction was prevented by vagotomy, it was unaffected by exogenous pyridoxal, did not occur with the alpha adrenergic antagonist prazosin and was not mimicked by non-HYD pyridoxal reactors. In other experiments, pharmacokinetic interactions and monoamine oxidase inhibition were ruled out as alternative explanations for this phenomenon. It was concluded that the H-HYDs interaction is not related to a possible influence of these drugs on central gamma-aminobutyric acid cardiovascular regulation and that other presently unknown mechanisms are involved.

  16. Adjustable hydrazine modulation of single-wall carbon nanotube network field effect transistors from p-type to n-type

    Science.gov (United States)

    Dai, Ruixuan; Xie, Dan; Xu, Jianlong; Sun, Yilin; Sun, MengXing; Zhang, Cheng; Li, Xian

    2016-11-01

    Single-wall carbon nanotube (SWCNT) network field effect transistors (FETs), which show decent p-type electronic properties, have been fabricated. The use of hydrazine as an aqueous solution and a strong n-type dopant for the SWCNTs is demonstrated in this paper. The electrical properties are obviously tuned by hydrazine treatment at different concentrations on the surface of the SWCNT network FETs. The transport behavior of SWCNTs can be modulated from p-type to n-type, demonstrating the controllable and adjustable doping effect of hydrazine. With a higher concentration of hydrazine, more electrons can be transferred from the hydrazine molecules to the SWCNT network films, thus resulting in a change of threshold voltage, carrier mobility and on-current. By cleaning the device, the hydrazine doping effects vanish, which indicates that the doping effects of hydrazine are reversible. Through x-ray photoelectron spectroscopy (XPS) characterization, the doping effects of hydrazine have also been studied.

  17. Flow injection chemiluminescence determination of hydrazine by oxidation with chlorinated isocyanurates.

    Science.gov (United States)

    Safavi, Afsaneh; Karimi, Mohammad Ali

    2002-10-16

    A rapid and sensitive flow injection chemiluminescence (CL) method is described for the determination of hydrazine based on the CL generated during its reaction with either sodium dichloroisocyanurate (SDCC) or trichloroisocyanuric acid (TCCA) in alkaline medium. The emission intensity is greatly enhanced if dichlorofluorescein (DCF) as sensitizer is present in the reaction medium. The presence of citrate prevents the precipitation of some cations in the reaction medium and also causes an enhancement in emission intensity. The effect of analytical and flow injection variables on these CL systems and determination of hydrazine are discussed. The optimum parameters for the determination of hydrazine were studied and were found to be the following: SDCC and TCCA both 1x10(-3) M; NaOH, 2x10(-1) M; DCF, 5x10(-6) M; citrate, 1x10(-3) M and flow rate, 3.8 ml min(-1). The optimized method yielded 3sigma detection limits of 2x10(-7) and 3x10(-7) M for hydrazine with SDCC and TCCA oxidants, respectively. The method is simple, fast, sensitive, and precise and was applied to the determination of hydrazine in water samples.

  18. Preparation of fine nickel powders via reduction of nickel hydrazine complex precursors

    Institute of Scientific and Technical Information of China (English)

    HUANG Guo-yong; XU Sheng-ming; XU Gang; LI Lin-yan; ZHANG Li-feng

    2009-01-01

    Fine nickel(Ni) powders with controllable particle sizes were synthesized via the reduction of nickel hydrazine complex precursors of pure [Ni(N2H4)2]Cl2 and a mixture of [Ni(N2H4)2]Cl2 and [Ni(N2H4)3]Cl2 in aqueous solution. The mechanism of the formation of metallic Ni powders experiences the reduction of nickel hydroxide by hydrazine released from the ligand exchange reaction between nickel hydrazine complex and NaOH. In comparison with the method of preparing Ni powders from nickel salts, the method of making Ni powders via the reduction of nickel hydrazine complex precursors shows the advantages of using half dosage of hydrazine for complete reduction of nickel ions in solution, and the obtained Ni particles show less agglomeration and better dispersibility. Moreover, the average particle size of nickel powders can be controlled from 180 to 260 nm by adjusting the reaction molar ratio and concentration.

  19. Theoretical performance of liquid ammonia, hydrazine and mixture of liquid ammonia and hydrazine as fuels with liquid oxygen biflouride as oxidant for rocket engines : I-mixture of liquid ammonia and hydrazine

    Science.gov (United States)

    Huff, Vearl N; Gordon, Sanford

    1952-01-01

    Theoretical performance for mixture of 36.3 percent liquid ammonia and 63.7 percent hydrazine with liquid oxygen bifluoride as rocket propellant was calculated on assumption of equilibrium composition during expansion for a wide range of fuel-oxidant and expansios ratios. Parameters included were specific impulse, combustion-chamber temperature, nozzle exit temperature, composition mean molecular weight, characteristic velocity, coefficient of thrust and ratio of nozzle-exit area to throat area. For chamber pressure of 300 pounds per square inch absolute and expansion to 1 atmosphere, maximum specific impulse was 295.8 pound-seconds per pound. Five percent by weight of water in the hydrazine lowered specific impulse from about one to three units over a wide range of weight-percent fuel.

  20. Formulation & Storage Studies on Hydrazine-Based Gelled Propellants.

    Directory of Open Access Journals (Sweden)

    Mohan Verma

    1996-12-01

    Full Text Available The current trend in the area of high energy storable liquid rocket propellant research is to develop gelled/metallized systems and to explore the feasibility of their application in rocket motors. The idea stems from the fact that the conversion of a conventional liquid propellant to a gelled state and its subsequent metallization has the potential to significantly enhance the performance and density specific impulse. However, it is mandatory that the gelation of the liquid propellant be brought about with a minimum concentration of gellant and the gel formed should show a shear-thinning behaviour and good storage life. Keeping this in view, an experimental program to prepare thixotropic gels of hydrazine and its methyl substitutedderivatives like monomethyl hydrazineand unsymmetrical dimethyl hydrazinewas conducted under ambient conditions. The gellants investigated included particulate, chemical and synthetic materials. The gelation of the liquid fuels ..ould be brought about with gellant concentration as low as I wt per cent in some cases. Metallized gels using up to 40 wt per cent of AlIMg metal powders could be formulated. These heterogeneous systems showed a reduction in critical gellant concentration with degree of metallization. Further, less gelation time is observed if the gellant concentration is kept fixed and metal content is increased. The storage studies on gelled systems conducted over a period of three months showed good stability. The metallized systems, however, showed the settling of metal powders in meagre concentration which does not pose a major problem as these gels could be re-homogenized with stirring.

  1. Arrays of TiO2 Nanowires as Photoelectrochemical Sensors for Hydrazine Detection

    Directory of Open Access Journals (Sweden)

    Michael Ongaro

    2015-05-01

    Full Text Available Electrodes based on arrays of TiO2 nanowires were prepared by template sol-gel synthesis with the goal of developing a hydrazine photoelectrochemical sensor. Experimental conditions were chosen so that the gelation reaction occurred inside the nanopores of track-etched polycarbonate membranes, with consequent filling with TiO2 nanowires. Different procedures for the removal of the template were examined, in order to obtain arrays of self-standing TiO2 nanowires. The nanowire arrays were bound to fluorine doped tin oxide substrates to produce handy photoelectrodes. The photocurrent recorded with the photoelectrodes in the presence of hydrazine showed significant dependence on the pollutant concentration. The development of a photoelectrochemical sensor for hydrazine detection in water samples, based on this principle, is presented.

  2. Efficient hydrogen evolution in transition metal dichalcogenides via a simple one-step hydrazine reaction

    Science.gov (United States)

    Cummins, Dustin R.; Martinez, Ulises; Sherehiy, Andriy; Kappera, Rajesh; Martinez-Garcia, Alejandro; Schulze, Roland K.; Jasinski, Jacek; Zhang, Jing; Gupta, Ram K.; Lou, Jun; Chhowalla, Manish; Sumanasekera, Gamini; Mohite, Aditya D.; Sunkara, Mahendra K.; Gupta, Gautam

    2016-01-01

    Hydrogen evolution reaction is catalysed efficiently with precious metals, such as platinum; however, transition metal dichalcogenides have recently emerged as a promising class of materials for electrocatalysis, but these materials still have low activity and durability when compared with precious metals. Here we report a simple one-step scalable approach, where MoOx/MoS2 core-shell nanowires and molybdenum disulfide sheets are exposed to dilute aqueous hydrazine at room temperature, which results in marked improvement in electrocatalytic performance. The nanowires exhibit ∼100 mV improvement in overpotential following exposure to dilute hydrazine, while also showing a 10-fold increase in current density and a significant change in Tafel slope. In situ electrical, gate-dependent measurements and spectroscopic investigations reveal that hydrazine acts as an electron dopant in molybdenum disulfide, increasing its conductivity, while also reducing the MoOx core in the core-shell nanowires, which leads to improved electrocatalytic performance. PMID:27282871

  3. Surface-catalyzed air oxidation reactions of hydrazines: Tubular reactor studies

    Science.gov (United States)

    Kilduff, Jan E.; Davis, Dennis D.; Koontz, Steven L.

    1988-01-01

    The surface-catalyzed air oxidation reactions of hydrazine, monomethylhydrazine, unsymmetrical dimethylhydrazine, symmetrical dimethylhydrazine, trimethylhydrazine and tetramethylhydrazine were investigated in a metal-powder packed turbular flow reactor at 55 plus or minus 3 C. Hydrazine was completely reacted on all surfaces studied. The major products of monomethylhydrazine (MMH) oxidation were methanol, methane and methyldiazene. The di-, tri- and tetra-methyl hydrazines were essentially unreactive under these conditions. The relative catalytic reactivities toward MMH are: Fe greater than Al2O3 greater than Ti greater than Zn greater than 316 SS greater than Cr greater than Ni greater than Al greater than 304L SS. A kinetic scheme and mechanism involving adsorption, oxidative dehydrogenation and reductive elimination reactions on a metal oxide surface are proposed.

  4. Electroless plating of Ni-B film as a binder-free highly efficient electrocatalyst for hydrazine oxidation

    Science.gov (United States)

    Wen, Xiao-Ping; Dai, Hong-Bin; Wu, Lin-Song; Wang, Ping

    2017-07-01

    Hydrazine is a promising energy carrier for fuel cells owing to its combined advantages of high theoretical cell voltage, high-power density, and no greenhouse gas emission. By using an electroless plating process, we have prepared a robust Ni-B film grown on Ni foam that is highly effective for hydrazine electrooxidation in alkaline media. The effects of reaction temperature, concentrations of hydrous hydrazine and sodium hydroxide in the fuel solution on performance of hydrazine electrooxidation reaction are investigated. The mechanistic reason for the property advantage of as-prepared Ni-B/Ni foam catalyst over the relevant catalysts is discussed based on careful kinetics studies and characterization. The facile synthesis of Ni-based catalyst with high activity and good stability is of clear significance for the development of hydrous hydrazine as a viable energy carrier.

  5. Concentric-Electrode Organic Electrochemical Transistors: Case Study for Selective Hydrazine Sensing

    Directory of Open Access Journals (Sweden)

    Sébastien Pecqueur

    2017-03-01

    Full Text Available We report on hydrazine-sensing organic electrochemical transistors (OECTs with a design consisting of concentric annular electrodes. The design engineering of these OECTs was motivated by the great potential of using OECT sensing arrays in fields such as bioelectronics. In this work, poly(3,4-ethylenedioxythiophene:poly(styrenesulfonate (PEDOT:PSS-based OECTs have been studied as aqueous sensors that are specifically sensitive to the lethal hydrazine molecule. These amperometric sensors have many relevant features for the development of hydrazine sensors, such as a sensitivity down to 10−5 M of hydrazine in water, an order of magnitude higher selectivity for hydrazine than for nine other water-soluble common analytes, the capability to entirely recover its base signal after water flushing, and a very low operation voltage. The specificity for hydrazine to be sensed by our OECTs is caused by its catalytic oxidation at the gate electrode, and enables an increase in the output current modulation of the devices. This has permitted the device-geometry study of the whole series of 80 micrometric OECT devices with sub-20-nm PEDOT:PSS layers, channel lengths down to 1 µm, and a specific device geometry of coplanar and concentric electrodes. The numerous geometries unravel new aspects of the OECT mechanisms governing the electrochemical sensing behaviours of the device—more particularly the effect of the contacts which are inherent at the micro-scale. By lowering the device cross-talk, micrometric gate-integrated radial OECTs shall contribute to the diminishing of the readout invasiveness and therefore further promote the development of OECT biosensors.

  6. Concentric-Electrode Organic Electrochemical Transistors: Case Study for Selective Hydrazine Sensing

    Science.gov (United States)

    Pecqueur, Sébastien; Lenfant, Stéphane; Guérin, David; Alibart, Fabien; Vuillaume, Dominique

    2017-01-01

    We report on hydrazine-sensing organic electrochemical transistors (OECTs) with a design consisting of concentric annular electrodes. The design engineering of these OECTs was motivated by the great potential of using OECT sensing arrays in fields such as bioelectronics. In this work, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)-based OECTs have been studied as aqueous sensors that are specifically sensitive to the lethal hydrazine molecule. These amperometric sensors have many relevant features for the development of hydrazine sensors, such as a sensitivity down to 10−5 M of hydrazine in water, an order of magnitude higher selectivity for hydrazine than for nine other water-soluble common analytes, the capability to entirely recover its base signal after water flushing, and a very low operation voltage. The specificity for hydrazine to be sensed by our OECTs is caused by its catalytic oxidation at the gate electrode, and enables an increase in the output current modulation of the devices. This has permitted the device-geometry study of the whole series of 80 micrometric OECT devices with sub-20-nm PEDOT:PSS layers, channel lengths down to 1 µm, and a specific device geometry of coplanar and concentric electrodes. The numerous geometries unravel new aspects of the OECT mechanisms governing the electrochemical sensing behaviours of the device—more particularly the effect of the contacts which are inherent at the micro-scale. By lowering the device cross-talk, micrometric gate-integrated radial OECTs shall contribute to the diminishing of the readout invasiveness and therefore further promote the development of OECT biosensors. PMID:28287475

  7. Impact of hydrogen onboard storage technologies on the performance of hydrogen fuelled vehicles: A techno-economic well-to-wheel assessment

    NARCIS (Netherlands)

    de Wit, M.P.|info:eu-repo/dai/nl/310873754; Faaij, A.P.C.|info:eu-repo/dai/nl/10685903X

    2007-01-01

    Hydrogen onboard storage technologies form an important factor in the overall performance of hydrogen fuelled transportation, both energetically and economically. Particularly, advanced storage options such as metal hydrides and carbon nanotubes are often hinted favourable to conventional, liquid

  8. Impact of hydrogen onboard storage technologies on the performance of hydrogen fuelled vehicles: A techno-economic well-to-wheel assessment

    NARCIS (Netherlands)

    de Wit, M.P.; Faaij, A.P.C.

    2007-01-01

    Hydrogen onboard storage technologies form an important factor in the overall performance of hydrogen fuelled transportation, both energetically and economically. Particularly, advanced storage options such as metal hydrides and carbon nanotubes are often hinted favourable to conventional, liquid an

  9. Synthesis, characterization and antioxidant study of N,N’-bis(2-chlorobenzamidothiocarbonyl)hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Firdausiah, Syadza; Hasbullah, Siti Aishah; Yamin, Bohari M. [School of Chemical Science and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2015-09-25

    N,N’-bis(2-chlorobenzamidothiocarbonyl)hydrazine was synthesized from 2-chlorobenzoylisothiocyanate and hydrazine in acetone. The compound was characterized by infrared, {sup 1}H and {sup 13}C NMR, and UV-Vis spectroscopies. X-ray crystallography study showed the molecule adopt trans configuration at both N-N and C-N bonds. The compound showed high antioxidant activity, EC{sub 50} of 374.89 µM, compared to ascorbic acid (EC{sub 50} of 561.36 µM)

  10. Selective fluorescent detection of aspartic acid and glutamic acid employing dansyl hydrazine dextran conjugate.

    Science.gov (United States)

    Nasomphan, Weerachai; Tangboriboonrat, Pramuan; Tanapongpipat, Sutipa; Smanmoo, Srung

    2014-01-01

    Highly water soluble polymer (DD) was prepared and evaluated for its fluorescence response towards various amino acids. The polymer consists of dansyl hydrazine unit conjugated into dextran template. The conjugation enhances higher water solubility of dansyl hydrazine moiety. Of screened amino acids, DD exhibited selective fluorescence quenching in the presence of aspartic acid (Asp) and glutamic acid (Glu). A plot of fluorescence intensity change of DD against the concentration of corresponding amino acids gave a good linear relationship in the range of 1 × 10(-4) M to 25 × 10(-3) M. This establishes DD as a potential polymeric sensor for selective sensing of Asp and Glu.

  11. Kinetic Study of Np(Ⅵ) Reduction With Tert-butyl Hydrazine

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Tert-butyl hydrazine(TBH) is a new salt free reductant, it can effectively reduce Np(Ⅵ) to Np(Ⅴ) but reduce Pu(Ⅳ)very slowly. Further more, it has the highest ratio of rate constant for Np(Ⅵ) reduction to the rate constant for Pu(Ⅳ) reduction in hydrazine derivatives, so it’s a promising reductant to separate Np, Pu effectively,Reduction kinetic study of the reaction in nitric acid is performed by spectrophotometry. The effect of some factors such as concentration of TBH, HNO3, Np(Ⅵ) and temperature on the redox

  12. The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene).

    Science.gov (United States)

    Mashtalir, O; Lukatskaya, M R; Kolesnikov, A I; Raymundo-Piñero, E; Naguib, M; Barsoum, M W; Gogotsi, Y

    2016-04-28

    Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g(-1) in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.

  13. Transformation of Hydrazine Fuels in Soil%肼类燃料在土壤中迁移转化

    Institute of Scientific and Technical Information of China (English)

    任向红

    2001-01-01

    Adsorption, degradation, transformation of hydrazines, methyl hydrazines and unsymmetrical dimethyl hydrazines in soil and their toxicity to microorganisms in soil are evaluated in the present investigation. It may be concluded that principal reactions between the hydrazine fuels and clay are physical absorption and chemical degradation. It has also been found that ion- exchange can only occur at low pH level, the unsolvable hydroxides may be formed on surface of the soil, suggesting that those could combine lots of hydrazine fuels by hydrogen- bond and ionization at the high pH level. The order of toxicity of the hydrazine fuels to microorganisms is hydrazines>methyl hydrazines> unsymmetrical dimethyl hydrazines. It has been indicated that some microorganisms in the soil can degrade the hydrazine fuels.%论述了对肼、甲基肼和偏二甲肼在土壤环境中的吸附、降解、迁移转化模型及对土壤中的微生物的毒性。肼类燃料在土壤环境中与粘土的作用最强,主要存在着物理吸附与化学降解两个方面。pH值较低时,在粘土中主要是可逆离子交换;pH值较高时,在土壤表面形成不溶的氢氧化物,通过氢键和离子作用结合大量肼类燃料。肼类燃料对土壤中的微生物的毒性大小是肼>甲基肼>偏二甲肼,土壤中的某些微生物也可促进肼类燃料的降解。

  14. THE HYDROGEN-FUELLED INTERNAL COMBUSTION ENGINES FOR MARINE APPLICATIONS WITH A CASE STUDY

    Directory of Open Access Journals (Sweden)

    Ibrahim S. Seddiek

    2015-03-01

    Full Text Available Modern marine power plants have been designed to improve the overall ship’s efficiency. This pushed the designers of marine machinery to search for unconventional fuels for these plants. During the previous years, diesel oil has been extensively used on-board ships. Due to the high price of light diesel oil and the environmental problems resulting from the use of heavy fuel oil, it has become necessary to search for an alternative to traditional fuels. As a result, natural gas fuel has been used on-board some types of ships, especially short-voyage cruise ships. Unfortunately, there are still some technical and logistic problems related to the use of natural gas as a fuel, especially as it is considered a non-renewable energy source. The use of hydrogen fuel on-board ships, particularly in modern power plants may contribute to overcoming the above problems. The present paper considers the possibility of the use of hydrogen fuel for marine applications and discusses different stages of hydrogen gas cycle beginning with hydrogen generation process from clean energy until using it as fuel for internal combustion engines on-board one RO/RO ship, named Taba, operating in the Mediterranean Sea. Compared to the diesel engine, the hydrogen fuelled engine is found to be lower in thermal efficiency and fuel consumption, however, some adjustments are needed.

  15. Bioethanol/gasoline blends for fuelling conventional and hybrid scooter. Regulated and unregulated exhaust emissions

    Science.gov (United States)

    Costagliola, Maria Antonietta; Prati, Maria Vittoria; Murena, Fabio

    2016-05-01

    The aim of this experimental activity was to evaluate the influence of ethanol fuel on the pollutant emissions measured at the exhaust of a conventional and a hybrid scooter. Both scooters are 4-stroke, 125 cm3 of engine capacity and Euro 3 compliant. They were tested on chassis dynamometer for measuring gaseous emissions of CO, HC, NOx, CO2 and some toxic micro organic pollutants, such as benzene, 1,3-butadiene, formaldehyde and acetaldehyde. The fuel consumption was estimated throughout a carbon balance on the exhaust species. Moreover, total particles number with diameter between 20 nm up to 1 μm was measured. Worldwide and European test cycles were carried out with both scooters fuelled with gasoline and ethanol/gasoline blends (10/90, 20/80 and 30/70% vol). According to the experimental results relative to both scooter technologies, the addiction of ethanol in gasoline reduces CO and particles number emissions. The combustion of conventional scooter becomes unstable when a percentage of 30%v of bioethanol is fed; as consequence a strong increasing of hydrocarbon is monitored, including carcinogenic species. The negative effects of ethanol fuel are related to the increasing of fuel consumption due to the less carbon content for volume unit and to the increasing of formaldehyde and acetaldehyde due to the higher oxygen availability. Almost 70% of Ozone Formation Potential is covered by alkenes and aromatics.

  16. Effects of gas types and models on optimized gas fuelling station reservoir's pressure

    Directory of Open Access Journals (Sweden)

    M. Farzaneh-Gord

    2013-06-01

    Full Text Available There are similar algorithms and infrastructure for storing gas fuels at CNG (Compressed Natural Gas and CHG (Compressed Hydrogen Gas fuelling stations. In these stations, the fuels are usually stored in the cascade storage system to utilize the stations more efficiently. The cascade storage system generally divides into three reservoirs, commonly termed low, medium and high-pressure reservoirs. The pressures within these reservoirs have huge effects on performance of the stations. In the current study, based on the laws of thermodynamics, conservation of mass and real/ideal gas assumptions, a theoretical analysis has been constructed to study the effects of gas types and models on performance of the stations. It is intended to determine the optimized reservoir pressures for these stations. The results reveal that the optimized pressure differs between the gas types. For ideal and real gas models in both stations (CNG and CHG, the optimized non-dimensional low pressure-reservoir pressure is found to be 0.22. The optimized non-dimensional medium-pressure reservoir pressure is the same for the stations, and equal to 0.58.

  17. Tracing the origin of the AGN fuelling reservoir in MCG--6-30-15

    CERN Document Server

    Raimundo, S I; Canning, R E A; Celotti, A; Fabian, A C; Gandhi, P

    2016-01-01

    The active galaxy MCG--6-30-15 has a 400 pc diameter stellar kinematically distinct core, counter-rotating with respect to the main body of the galaxy. Our previous high spatial resolution (0".1) H-band observations of this galaxy mapped the stellar kinematics and [Fe II] 1.64 {\\mu}m gas dynamics though mainly restricted to the spatial region of the counter-rotating core. In this work we probe the stellar kinematics on a larger field-of-view and determine the ionised and molecular gas dynamics to study the formation of the counter-rotating core and the implications for AGN fuelling. We present integral field spectroscopy observations with SINFONI in the H and K-bands in the central 1.2 kpc and with VIMOS HR-blue in the central 4 kpc of the galaxy. Ionised gas outflows of v ~ 100 km/s are traced by the [Ca VIII] 2.32 {\\mu}m coronal line and extend out to at least a radius of r ~ 140 pc. The molecular gas, traced by the H2 2.12 {\\mu}m emission is also counter rotating with respect to the main body of the galaxy...

  18. PERFORMANCE AND EMISSION CHARACTERISTICS OF CI ENGINE FUELLED WITH NON EDIBLE VEGETABLE OIL AND DIESEL BLENDS

    Directory of Open Access Journals (Sweden)

    T. ELANGO

    2011-04-01

    Full Text Available This study investigates performance and emission characteristics of a diesel engine which is fuelled with different blends of jatropha oil and diesel (10–50%. A single cylinder four stroke diesel engine was used for the experiments at various loads and speed of 1500 rpm. An AVL 5 gas analyzer and a smoke meter were used for the measurements of exhaust gas emissions. Engine performance (specific fuel consumption SFC, brake thermal efficiency, and exhaust gas temperature and emissions (HC, CO, CO2, NOx and Smoke Opacity were measured to evaluate and compute the behaviour of the diesel engine running on biodiesel. The results showed that the brake thermal efficiency of diesel is higher at all loads. Among the blends maximum brake thermal efficiency and minimum specific fuel consumption were found for blends upto 20% Jatropha oil. The specific fuel consumption of the blend having 20% Jatropha oil and 80% diesel (B20 was found to be comparable with the conventional diesel. The optimum blend is found to be B20 as the CO2 emissions were lesser than diesel while decrease in brake thermal efficiency is marginal.

  19. PM, carbon, and PAH emissions from a diesel generator fuelled with soy-biodiesel blends.

    Science.gov (United States)

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lin, Yuan-Chung; Lee, Wen-Jhy; Lin, Chih-Chung; Lin, Wen-Yinn

    2010-07-15

    Biodiesels have received increasing attention as alternative fuels for diesel engines and generators. This study investigates the emissions of particulate matter (PM), total carbon (TC), e.g., organic/elemental carbons, and polycyclic aromatic hydrocarbons (PAHs) from a diesel generator fuelled with soy-biodiesel blends. Among the tested diesel blends (B0, B10 (10 vol% soy-biodiesel), B20, and B50), B20 exhibited the lowest PM emission concentration despite the loads (except the 5 kW case), whereas B10 displayed lower PM emission factors when operating at 0 and 10 kW than the other fuel blends. The emission concentrations or factors of EC, OC, and TC were the lowest when B10 or B20 was used regardless of the loading. Under all tested loads, the average concentrations of total-PAHs emitted from the generator using the B10 and B20 were lower (by 38% and 28%, respectively) than those using pure petroleum diesel fuel (B0), while the emission factors of total-PAHs decreased with an increasing ratio of biodiesel to premium diesel. With an increasing loading, although the brake specific fuel consumption decreased, the energy efficiency increased despite the bio/petroleum diesel ratio. Therefore, soy-biodiesel is promising for use as an alternative fuel for diesel generators to increase energy efficiency and reduce the PM, carbon, and PAH emissions.

  20. Particulate Matter Emission from Dual Fuel Diesel Engine Fuelled with Natural Gas

    Directory of Open Access Journals (Sweden)

    Stelmasiak Zdzisław

    2017-06-01

    Full Text Available The paper presents the results of examination of particulate matter emission from the Diesel engine FPT 1.3 MJT simultaneously fuelled with diesel oil and natural gas CNG. The basic premise for engine adaptation was the addition of a small amount of CNG to reduce exhaust gas opacity and particulate matter emission. At this assumption, diesel oil remained the basic fuel, with contribution amounting to 0,70-0,85 of total energy delivered to the engine. The dual fuel engine was examined using an original controller installed in the Diesel engine FPT 1.3 MJT which controlled the diesel fuel dose. The dose of the injected natural gas was controlled by changing the opening time of gas injectors at constant pressure in the gas collector. The examined issues included the exhaust gas opacity, and the total number and fractional distribution of the emitted particles. The measurements were performed at twenty selected measuring points corresponding to the New European Driving Cycle (NEDC test. The performed tests have demonstrated a positive effect of gas addition on exhaust gas opacity and particulate matter emission. Depending on test conditions, the exhaust gas opacity was reduced by 10÷92%, and the total number of particles by 30÷40%. The performed tests have revealed that a small addition of gas can reduce the load of the DPF filter, extend its lifetime, and increase engine reliability. Longer time intervals between successive DPF filter regenerations improve ecological properties of the engine.

  1. Emission of a compression ignition engine fuelled by diesel and imitated syngas

    Science.gov (United States)

    Mahgoub, Bahaaddein Kamal M.; Sulaiman, S. A.; Karim, Zainal Ambri B. A.

    2012-06-01

    Biomass can be converted into a useful source of energy through gasification. The gasification product, known as synthesis gas or syngas, composition of syngas may fluctuate due to many factors such as operational errors of the gasifier as well as the type of feedstock used or may be due to the feeding rate fluctuation. Therefore it would be difficult to assess the effect of syngas composition and diesel replacement ratio to the emission when combusted in dual fuel syngas - diesel compression ignition engine. In order to overcome this problem controllable composition and conditions of imitated syngas was used in this study by selective three compositions of syngas close to the real conditions. The objective of this study is to determine the exhaust emissions of a compression ignition engine fuelled with diesel and imitated syngas at different compositions and diesel replacement ratios to determine the most appropriate composition of syngas and diesel replacement ratio which will give less emission. The test results on syngas emission are compared with the results of diesel. CO2 and NOX emission level was reduced on syngas dual fuel mode, but there were increases in CO and THC emissions throughout all syngas compositions examined due to poor combustion efficiency of dual fuel operation.

  2. Developing a Knock Predictive Criterion in Spark Ignition Engines Fuelled with Gaseous Fuels

    Institute of Scientific and Technical Information of China (English)

    G.A.Karim

    1993-01-01

    Consideration of the chemical reaction activity of the end gas in a spark ignition and operating conditions are combined to predict the onset of knock and associated performance in an engine fuelled with methane.A two-zone predictive combustion model was developed based on an estimate of the effective duration of the combustion period and the mass burning rate for any set of operating conditions.The unburned end gas preignition chemical reaction activity is described by a detailed chemical reaction kinetic scheme for methane and air,The variation with time of the value of a formulated dimensionless knock parameter(k)is calcuated.It is shown that whenever knocking is encounteren.the value of “k” builds up to a sufficiently high value that exceeds a critical value.Under normal operating conditions,the value of “k” remains throughout the whole combustion period at comparatively very low levels.It is shown that the model and the use of this knock criterion“k” produce results that are in good agreement with experiment.

  3. Particle emission from heavy-duty engine fuelled with blended diesel and biodiesel.

    Science.gov (United States)

    Martins, Leila Droprinchinski; da Silva Júnior, Carlos Roberto; Solci, Maria Cristina; Pinto, Jurandir Pereira; Souza, Davi Zacarias; Vasconcellos, Pérola; Guarieiro, Aline Lefol Nani; Guarieiro, Lílian Lefol Nani; Sousa, Eliane Teixeira; de Andrade, Jailson B

    2012-05-01

    In this study, particulate matter (PM) were characterized from a place impacted by heavy-duty vehicles (Bus Station) fuelled with diesel/biodiesel fuel blend (B3) in the city of Londrina, Brazil. Sixteen priority polycyclic aromatic hydrocarbons (PAH) concentrations were analyzed in the samples by their association with atmospheric PM, mass size distributions and major ions (fluorite, chloride, bromide, nitrate, phosphate, sulfate, nitrite, oxalate; fumarate, formate, succinate and acetate; lithium, sodium, potassium, magnesium, calcium and ammonium). Results indicate that major ions represented 21.2% particulate matter mass. Nitrate, sulfate, and ammonium, respectively, presented the highest concentration levels, indicating that biodiesel may also be a significant source for these ions, especially nitrate. Dibenzo[a,h]anthracene and indeno[1,2,3,-cd]pyrene were the main PAH found, and a higher fraction of PAH particles was found in diameters lower than 0.25 μm in Londrina bus station. The fine and ultrafine particles were dominant among the PM evaluated, suggesting that biodiesel decreases the total PAH emission. However, it does also increase the fraction of fine and ultrafine particles when compared to diesel.

  4. Ozone depletion in the plume of a solid-fuelled rocket

    Directory of Open Access Journals (Sweden)

    B. C. Krüger

    Full Text Available The local effects of the emission of a solid-fuelled rocket on the stratospheric ozone concentration have been investigated by photochemical model calculations. A one-dimensional horizontal model has been applied which calculates the trace gas composition at a single atmospheric altitude spatially resolved around the exhaust plume. Different cases were tested for the emissions of the Space Shuttle concerning the composition of the exhaust and the effects of heterogeneous reactions on atmospheric background aerosol.

    The strongest depletion of ozone is achieved when a high amount of the emitted chlorine is Cl2. If it is purely HCl, the effect is smallest, though in this case the heterogeneous reactions show their largest influence. From the results it may be estimated whether ozone depletion caused by rocket launches can be detected by satellite instruments. It appears that the chance of coincidental detection of such an event is rather small.

  5. The Stability of Lubricant Oil Acidity of Biogas Fuelled Engine due to Biogas Desulfurization

    Science.gov (United States)

    Gde Tirta Nindhia, Tjokorda; Wayan Surata, I.; Wardana, Ari

    2017-05-01

    This research is established for the purpose of the understanding the stability of the acidity of lubricant oil in biogas fuelled engine due to the absence of hydrogen sulfide (H2S). As was recognized that other than Methane (CH4), there are also other gas impurities in the biogas such as carbon dioxide (CO2), hydrogen sulfide (H2S), moisture (H2O) and ammonia (NH3). Due to H2S contents in the biogas fuel, the engine was found failure. This is caused by corrosion in the combustion chamber due to increase of lubricant acidity. To overcome this problem in practical, the lubricant is increased the pH to basic level with the hope will be decrease to normal value after several time use. Other method is by installing pH measurement sensor in the engine lubricant so that when lubricant is known turn to be acid, then lubricant replacement should be done. In this research, the effect of biogas desulfurization down to zero level to the acidity of lubricant oil in the four stroke engine was carried out with the hope that neutral lubrication oil to be available during running the engine. The result indicates that by eliminating H2S due desulfurization process, effect on stability and neutrality of pH lubricant. By this method the engine safety can be obtained without often replacement the lubricant oil.

  6. Evaluation of the use of bioethanol fuelled buses based on ambient air pollution screening and on-road measurements.

    Science.gov (United States)

    López-Aparicio, S; Hak, C

    2013-05-01

    Mitigation measures to reduce greenhouse gas emissions may have adverse effects on urban air quality and human exposure to harmful pollutants. The use of bioethanol fuelled vehicles is increasing worldwide and may create new undesired pollution effects. Different measurement campaigns were performed in a pilot study to contribute to the understanding of the consequences associated with the use of bioethanol blended fuel (E95) on a series of pollutants. Ambient screening measurements of NO2, O3, acetic acid, formaldehyde and acetaldehyde were performed at different urban locations, exposed and not exposed to the circulation of bioethanol buses. In addition, volatile organic compounds were measured at the exhaust pipe of a bioethanol fuelled bus, both under idling conditions (carbonyls; DNPH cartridge) and under on-road driving conditions applying online monitoring (PTR-TOF). Higher ambient acetaldehyde values were measured at locations exposed to bioethanol fuelled buses than at locations not exposed, and very high acetaldehyde and acetic acid values were measured from the exhaust pipe during driving conditions (acetaldehyde>150 ppm; acetic acid ≈ 20-30 ppm) and modelled at close distance to the bioethanol bus. Human exposure to high concentration of acetaldehyde is expected, and it may involve a significantly increased chance in developing cancer. The high concentration of acetic acid will involve odour annoyance and significant material degradation or corrosion.

  7. Galaxy pairs in the Sloan Digital Sky Survey - XII: The fuelling mechanism of low excitation radio-loud AGN

    CERN Document Server

    Ellison, Sara L; Hickox, Ryan C

    2015-01-01

    We investigate whether the fuelling of low excitation radio galaxies (LERGs) is linked to major galaxy interactions. Our study utilizes a sample of 10,800 spectroscopic galaxy pairs and 97 post-mergers selected from the Sloan Digital Sky Survey with matches to multi-wavelength datasets. The LERG fraction amongst interacting galaxies is a factor of 3.5 higher than that of a control sample matched in local galaxy density, redshift and stellar mass. However, the LERG excess in pairs does not depend on projected separation and remains elevated out to at least 500 kpc, suggesting that major mergers are not their main fuelling channel. In order to identify the primary fuelling mechanism of LERGs, we compile samples of control galaxies that are matched in various host galaxy and environmental properties. The LERG excess is reduced, but not completely removed, when halo mass or D4000 are included in the matching parameters. However, when BOTH M_halo and D4000 are matched, there is no LERG excess and the 1.4 GHz lumin...

  8. A Pyridine-Based Ligand with Two Hydrazine Functions for Lanthanide Chelation: Remarkable Kinetic Inertness for a Linear, Bishydrated Complex.

    Science.gov (United States)

    Bonnet, Célia S; Laine, Sophie; Buron, Frédéric; Tircsó, Gyula; Pallier, Agnès; Helm, Lothar; Suzenet, Franck; Tóth, Éva

    2015-06-15

    To study the influence of hydrazine functions in the ligand skeleton, we designed the heptadentate HYD ligand (2,2',2″,2‴-(2,2'-(pyridine-2,6-diyl)bis(2-methylhydrazine-2,1,1-triyl)) tetraacetic acid) and compared the thermodynamic, kinetic, and relaxation properties of its Ln(3+) complexes to those of the parent pyridine (Py) analogues without hydrazine (Py = 2,6-pyridinebis(methanamine)-N,N,N',N'-tetraacetic acid). The protonation constants of HYD were determined by pH-potentiometric measurements, and assigned by a combination of UV-visible and NMR spectroscopies. The protonation sequence is rather unusual and illustrates that small structural changes can strongly influence ligand basicity. The first protonation step occurs on the pyridine nitrogen in the basic region, followed by two hydrazine nitrogens and the carboxylate groups at acidic pH. Contrary to Py, HYD self-aggregates through a pH-dependent process (from pH ca. 4). Thermodynamic stability constants have been obtained by pH-potentiometry and UV-visible spectrophotometry for various Ln(3+) and physiological cations (Zn(2+), Ca(2+), Cu(2+)). LnHYD stability constants show the same trend as those of LnDTPA complexes along the Ln(3+) series, with log K = 18.33 for Gd(3+), comparable to the Py analogue. CuHYD has a particularly high stability (log K > 19) preventing its determination from pH-potentiometric measurements. The stability constant of CuPy was also revisited and found to be underestimated in previous studies, highlighting that UV-visible spectrophotometry is often indispensable to obtain reliable stability constants for Cu(2+) chelates. The dissociation of GdL, assessed by studying the Cu(2+)-exchange reaction, occurs mainly via an acid-catalyzed process, with limited contribution from direct Cu(2+) attack. The kinetic inertness of GdHYD is remarkable for a linear bishydrated chelate; the 25-fold increase in the dissociation half-life with respect to the monohydrated commercial contrast agent

  9. A Hydrazine-Free Wolff-Kishner Reaction Suitable for an Undergraduate Laboratory

    Science.gov (United States)

    Cranwell, Philippa B.; Russell, Andrew T.

    2016-01-01

    A Wolff-Kishner reaction that does not require hydrazine has been developed. The reaction sequence has two steps: formation of a carbomethoxyhydrazone from methyl hydrazinocarboxylate and acetophenone, then decomposition of this intermediate by treatment with potassium hydroxide in triethylene glycol. Purification is by filtration through a plug…

  10. Hydrazine Blending and Storage Facility Wastewater Treatment and Decommissioning Assessment. Version 3.1

    Science.gov (United States)

    1988-06-01

    concrete pads and dikes; a drum storage I 6764a 1-5 05 -- iti kwij 1-6a pad; a storage shed; a tool shed; an office shed, and associated Ipiping . Two... Oceanic and Atnospheric Administration). 1983. Local climatological data, Denver, CO. Neumann, E.J., and B. Jody. 1986. Neutralization of hydrazine

  11. X-ray absorption spectroscopy study on the thermal and hydrazine reduction of graphene oxide

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Xianqing, E-mail: lxq@gxu.edu.cn [The Colleague of Physics Science and Technology, Guangxi University, Nanning 530004 (China); Wang, Yu [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204 (China); Zheng, Huiyuan [The Colleague of Physics Science and Technology, Guangxi University, Nanning 530004 (China); Wu, Ziyu, E-mail: wuzy@ustc.edu.cn [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China)

    2014-10-15

    Highlights: • XAS study of GO and reduced GO was performed. • Detailed evolution of the electronic structures and chemical bonding of GO was revealed. • A new efficient route for the reduction of GO is proposed. - Abstract: X-ray absorption spectroscopy (XAS) was applied to systemically investigate the deoxygenation of graphene oxide (GO) via annealing and hydrazine treatment. Detailed evolution of the electronic structures and chemical bonding of GO was presented. The enhanced intensity of π{sup *} resonance and the appearance of splitting σ{sup *} resonance in C K-edge XAS spectra suggest high extents of recoveries of π-conjugation upon reduction using thermal annealing or hydrazine. Experimental results revealed that the carboxyl as well as epoxide and hydroxyl groups on the surface of GO were thermally reduced first, followed by the more difficult removal of carbonyl and cyclic ether groups at higher temperatures. The hydrazine reduction could remove epoxide, hydroxyl and carboxyl groups effectively, whereas the carbonyl groups were partially reduced with the incorporation of nitrogen species simultaneously. The residual oxygen functional groups on hydrazine-reduced GO could be further removed after modest thermal annealing. It was proposed that a combination of both types of reductions would give the best deoxygenation efficiency for the production of graphene.

  12. Kinetic Study of the Reaction between Tert-butyl Hydrazine and Nitrous Acid

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The kinetic study of the reaction between tert-butyl hydrazine(TBH)and nitrous acid in nitric acid system is performed by spectrophotometry. The effect of some factors such as the concentration of TBH, the concentration of nitric acid, ionic strength, temperature and the

  13. The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)

    Science.gov (United States)

    Mashtalir, O.; Lukatskaya, M. R.; Kolesnikov, A. I.; Raymundo-Piñero, E.; Naguib, M.; Barsoum, M. W.; Gogotsi, Y.

    2016-04-01

    Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g-1 in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g-1 in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm. Electronic supplementary information (ESI) available: Characterization methods, additional XRD patterns (Fig. S1) and INS spectra (Fig. S2-S4). See DOI: 10.1039/c6nr01462c

  14. Redox conditions effect on flow accelerated corrosion: Influence of hydrazine and oxygen

    Energy Technology Data Exchange (ETDEWEB)

    Bouvier, O. de [EDF, R and D Div., Moret sur Loing (France); Bouchacourt, M. [EDF, Engineering and Service Div., Villeurbanne (France); Fruzzetti, K. [EPRI, Science and Technology Div., Palo Alto, CA (United States)

    2002-07-01

    Flow accelerated corrosion (FAC) of carbon steels has been studied world-wide for more than twenty years and is now fairly well understood. The influence of several parameters like water chemistry (i.e. pH and oxygen content), temperature, hydrodynamic or mass transfer conditions (i.e. flow velocity, geometry, steam quality..) and steel composition on the corrosion kinetics has been demonstrated both theoretically and experimentally. However, the effect of a reducing environment and variable redox conditions have not yet been fully explored. It's well known that a reducing environment is effective in increasing the resistance of steam generator tubing to intergranular attack / stress corrosion cracking (IGA/SCC) and pitting. In that way, secondary water chemistry specifications have been modified from low hydrazine to high hydrazine chemistry in the steam-water circuit. Nevertheless, increasing hydrazine levels up to 200 {mu}g/kg could have a detrimental effect by potentially enhancing the FAC process. Moreover, in order to have a complete understanding of the possible impact of the water chemistry environment it is also important to consider the impact of redox conditions during shutdowns (cold and/or hot shutdowns) and start up periods when aerated water injections are made to maintain a constant water level in the Steam Generators from the auxiliary feedwater circuit. Therefore, a common EDF and EPRI R and D effort has been recently carried out to study the effects of hydrazine and oxygen on FAC. The results are presented as follows. (authors)

  15. Hydrazine reduction of transition metal oxides - In situ characterization using X-ray photoelectron spectroscopy

    Science.gov (United States)

    Littrell, D. M.; Tatarchuk, B. J.

    1986-01-01

    The transition metal oxides (TMOs) V2O5, FeO3, Co3O4, NiO, CuO, and ZnO were exposed to hydrazine at various pressures. The metallic surfaces were surveyed by in situ X-ray photoelectron spectroscopy to determine the irrelative rate of reduction by hydrazine. The most easily reducible oxide, CuO, could be reduced to the metallic state at room temperature and 10 to the -6th torr. The reaction is first order with respect to CuO, with an activation energy of about 35 kJ/mol. Two types of adsorption were seen to occur at 295 K: (1) a reversible component in which the measured N:Cu ratio increased to 0.60 at hydrazine pressures up to 0.5 torr, and (2) an irreversible component, with a N:Cu ratio of 0.28, which could not be removed by extended vacuum pumping. The results of this study are useful for the identification of TMO's that can be used as solid neatallizers of hydrazine spills, and for the preparation of metal surfaces for electroplating and evaporative thin-film coating.

  16. Highly selective amperometric sensor for the trace level detection of hydrazine at bismuth nanoparticles decorated graphene nanosheets modified electrode.

    Science.gov (United States)

    Devasenathipathy, Rajkumar; Mani, Veerappan; Chen, Shen-Ming

    2014-06-01

    A highly selective amperometric sensor was developed for the trace level determination of hydrazine at bismuth nanoparticles (Bi) decorated graphene nanosheets (GR) composite film modified glassy carbon electrode (GCE). GR-Bi nanocomposite has been successfully prepared via simple and facile chemical reduction approach and its structure was characterized by various techniques. Surface morphological and X-ray diffraction studies revealed the formation and high loading of Bi nanoparticles on graphene sheets. GR-Bi nanocomposite modified GCE exhibited greatly enhanced electrocatalytic performance towards electro-oxidation of hydrazine in terms of decrease in overpotential and increase in oxidation peak current (Ip). The kinetic parameters such as electron transfer coefficient (α) and diffusion coefficient (Do) of the hydrazine oxidation were determined to be 0.70 and 2.65×10(-5) cm(2) s(-1), respectively. An amperometric sensor has been fabricated which detects trace level concentration of hydrazine. The sensor exhibited a wide linear range from 20 nM to 0.28 mM and a very low detection limit (LOD) of 5 nM. Remarkably, this is the lowest LOD achieved for the determination of hydrazine in neutral pH among other reported electrochemical hydrazine sensors. In addition, the sensor selectively detects hydrazine even in the presence of 1000 fold excess quantity of common interferrants. The practical feasibility of the sensor has been assessed in water and urine samples with good recoveries. Furthermore, the sensor exhibited appreciable stability, repeatability and reproducibility results.

  17. New Modified-Multiwall Carbon Nanotubes Paste Electrode for Electrocatalytic Oxidation and Determination of Hydrazine Using Square Wave Voltammetry

    Institute of Scientific and Technical Information of China (English)

    Ali A. ENSAF; Mahsa LOTFI; Hassan KARIMI-MALEH

    2012-01-01

    The application of p-aminophenol as a suitable mediator, as a sensitive and selective voltammetric sensor for the determination of hydrazine using square wave voltammetric method were described. The modified multiwall carbon nanotubes paste electrode exhibited a good electrocatalytic activity for the oxidation of hydrazine at pH = 7.0. The catalytic oxidation peak currents showed a linear dependence of the peaks current to the hydrazine concentrations in the range of 0.5–175 μmol/L with a correlation coefficient of 0.9975. The detection limit (S/N = 3) was estimated to be 0.3 μmol/L of hydrazine. The relative standard deviations for 0.7 and 5.0 μmol/L hydrazine were 1.7 and 1.1%, respectively. The modified electrode showed good sensitivity and selectivity. The diffusion coefficient (D = 9.5 × 10–4 cm2/s) and the kinetic parameters such as the electron transfer coefficient (α = 0.7) of hydrazine at the surface of the modified electrode were determined using electrochemical approaches. The electrode was successfully applied for the determination of hydrazine in real samples with satisfactory results.

  18. Cyclic voltammetry deposition of copper nanostructure on MWCNTs modified pencil graphite electrode: An ultra-sensitive hydrazine sensor.

    Science.gov (United States)

    Heydari, Hamid; Gholivand, Mohammad B; Abdolmaleki, Abbas

    2016-09-01

    In this study, Copper (Cu) nanostructures (CuNS) were electrochemically deposited on a film of multiwall carbon nanotubes (MWCNTs) modified pencil graphite electrode (MWCNTs/PGE) by cyclic voltammetry method to fabricate a CuNS-MWCNTs composite sensor (CuNS-MWCNT/PGE) for hydrazine detection. Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX) were used for the characterization of CuNS on the MWCNTs matrix. The composite of CuNS-MWCNTs was characterized with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The preliminary studies showed that the proposed sensor have a synergistic electrocatalytic activity for the oxidation of hydrazine in phosphate buffer. The catalytic currents of square wave voltammetry had a linear correlation with the hydrazine concentration in the range of 0.1 to 800μM with a low detection limit of 70nM. Moreover, the amperometric oxidation current exhibited a linear correlation with hydrazine concentration in the concentration range of 50-800μM with the detection limit of 4.3μM. The proposed electrode was used for the determination of hydrazine in real samples and the results were promising. Empirical results also indicated that the sensor had good reproducibility, long-term stability, and the response of the sensor to hydrazine was free from interferences. Moreover, the proposed sensor benefits from simple preparation, low cost, outstanding sensitivity, selectivity, and reproducibility for hydrazine determination. Copyright © 2016. Published by Elsevier B.V.

  19. Cyclic voltammetry deposition of copper nanostructure on MWCNTs modified pencil graphite electrode: An ultra-sensitive hydrazine sensor

    Energy Technology Data Exchange (ETDEWEB)

    Heydari, Hamid [Faculty of Sciences, Razi University, Kermanshah (Iran, Islamic Republic of); Gholivand, Mohammad B., E-mail: mbgholivand@razi.ac.ir [Faculty of Sciences, Razi University, Kermanshah (Iran, Islamic Republic of); Abdolmaleki, Abbas [Department of Chemistry, Malek Ashtar University of Technology, Tehran (Iran, Islamic Republic of)

    2016-09-01

    In this study, Copper (Cu) nanostructures (CuNS) were electrochemically deposited on a film of multiwall carbon nanotubes (MWCNTs) modified pencil graphite electrode (MWCNTs/PGE) by cyclic voltammetry method to fabricate a CuNS–MWCNTs composite sensor (CuNS–MWCNT/PGE) for hydrazine detection. Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDX) were used for the characterization of CuNS on the MWCNTs matrix. The composite of CuNS-MWCNTs was characterized with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The preliminary studies showed that the proposed sensor have a synergistic electrocatalytic activity for the oxidation of hydrazine in phosphate buffer. The catalytic currents of square wave voltammetry had a linear correlation with the hydrazine concentration in the range of 0.1 to 800 μM with a low detection limit of 70 nM. Moreover, the amperometric oxidation current exhibited a linear correlation with hydrazine concentration in the concentration range of 50–800 μM with the detection limit of 4.3 μM. The proposed electrode was used for the determination of hydrazine in real samples and the results were promising. Empirical results also indicated that the sensor had good reproducibility, long-term stability, and the response of the sensor to hydrazine was free from interferences. Moreover, the proposed sensor benefits from simple preparation, low cost, outstanding sensitivity, selectivity, and reproducibility for hydrazine determination. - Highlights: • The Copper nanostructures (CuNS) were prepared by cyclic voltammetry deposition. • The CuNS-MWCNT/PGE sensor shows high activity toward hydrazine (N{sub 2}H{sub 4}). • The proposed sensor exhibits a wide linear range (0.1 to 800 μM), low detection limit (70 nM), high sensitivity and stability for hydrazine.

  20. Effect of hydrazine on general corrosion of carbon and low-alloyed steels in pressurized water reactor secondary side water

    Energy Technology Data Exchange (ETDEWEB)

    Järvimäki, Sari [Fortum Ltd, Loviisa Power Plant, Loviisa (Finland); Saario, Timo; Sipilä, Konsta [VTT Technical Research Centre of Finland Ltd., Nuclear Safety, P.O. Box 1000, FIN-02044 VTT (Finland); Bojinov, Martin, E-mail: martin@uctm.edu [Department of Physical Chemistry, University of Chemical Technology and Metallurgy, Kl. Ohridski Blvd, 8, 1756 Sofia (Bulgaria)

    2015-12-15

    Highlights: • The effect of hydrazine on the corrosion of steel in secondary side water investigated by in situ and ex situ techniques. • Oxide grown on steel in 100 ppb hydrazine shows weaker protective properties – higher corrosion rates. • Possible explanation of the accelerating effect of higher concentrations of hydrazine on flow assisted corrosion offered. - Abstract: The effect of hydrazine on corrosion rate of low-alloyed steel (LAS) and carbon steel (CS) was studied by in situ and ex situ techniques under pressurized water reactor secondary side water chemistry conditions at T = 228 °C and pH{sub RT} = 9.2 (adjusted by NH{sub 3}). It is found that hydrazine injection to a maximum level of 5.06 μmol l{sup −1} onto surfaces previously oxidized in ammonia does not affect the corrosion rate of LAS or CS. This is confirmed also by plant measurements at Loviisa NPP. On the other hand, hydrazine at the level of 3.1 μmol l{sup −1} decreases markedly the amount and the size of deposited oxide crystals on LAS and CS surface. In addition, the oxide grown in the presence of 3.1 μmol l{sup −1} hydrazine is somewhat less protective and sustains a higher corrosion rate compared to an oxide film grown without hydrazine. These observations could explain the accelerating effect of higher concentrations of hydrazine found in corrosion studies of LAS and CS.

  1. COMBUSTION AND PERFORMANCE CHARACTERISTICS OF A SMALL SPARK IGNITION ENGINE FUELLED WITH HCNG

    Directory of Open Access Journals (Sweden)

    A. SONTHALIA

    2015-04-01

    Full Text Available Due to environmental concerns and fossil fuel depletion, large scale researches were carried out involving the use of natural gas in internal combustion engines. Natural gas is a clean burning fuel that is available from large domestic natural reserve. When it is used as a fuel in SI engines, it reduces emissions to meet EURO-III norms with carburettors and EURO-IV norms with manifold injection. Countries like India with fewer natural fossil fuel reserves depend heavily on oil imported from Middle East Asian countries and on the other hand combustion of fossil fuel has negative impact on air quality in urban areas. Use of CNG as a fuel in internal combustion engines can reduce the intensiveness of these pervasive problems. The performance of CNG can further be improved by addition of small percentages of hydrogen to it to overcome the drawbacks like lower energy density of the fuel, drop in engine power and engine out exhaust emissions. When hydrogen is added to CNG it is called as Hythane or Hydrogen enriched Compressed Natural Gas (HCNG. This can be considered as a first step towards promotion of hydrogen in automobiles. In this study, the effects of mixing hydrogen with CNG on a small air cooled four stroke SI engine’s performance, emissions and heat release rate was analyzed. A comparison of performance and emission by running engine separately on gasoline, hydrogen, CNG and HCNG was done. The results show a significant decrease in HC, CO and NOx emissions and marginal increase in specific energy consumption when fuelled with HCNG.

  2. Understanding CO2 capture mechanisms in aqueous hydrazine via combined NMR and first-principles studies.

    Science.gov (United States)

    Lee, Byeongno; Stowe, Haley M; Lee, Kyu Hyung; Hur, Nam Hwi; Hwang, Son-Jong; Paek, Eunsu; Hwang, Gyeong S

    2017-09-13

    Aqueous amines are currently the most promising solution for large-scale CO2 capture from industrial sources. However, molecular design and optimization of amine-based solvents have proceeded slowly due to a lack of understanding of the underlying reaction mechanisms. Unique and unexpected reaction mechanisms involved in CO2 absorption into aqueous hydrazine are identified using (1)H, (13)C, and (15)N NMR spectroscopy combined with first-principles quantum-mechanical simulations. We find production of both hydrazine mono-carbamate (NH2-NH-COO(-)) and hydrazine di-carbamate ((-)OOC-NH-NH-COO(-)), with the latter becoming more populated with increasing CO2 loading. Exchange NMR spectroscopy also demonstrates that the reaction products are in dynamic equilibrium under ambient conditions due to CO2 exchange between mono-carbamate and di-carbamate as well as fast proton transfer between un-protonated free hydrazine and mono-carbamate. The exchange rate rises steeply at high CO2 loadings, enhancing CO2 release, which appears to be a unique property of hydrazine in aqueous solution. The underlying mechanisms of these processes are further evaluated using quantum mechanical calculations. We also analyze and discuss reversible precipitation of carbamate and conversion of bicarbonate to carbamates. The comprehensive mechanistic study provides useful guidance for optimal design of amine-based solvents and processes to reduce the cost of carbon capture. Moreover, this work demonstrates the value of a combined experimental and computational approach for exploring the complex reaction dynamics of CO2 in aqueous amines.

  3. Morpho-functional Blood Changes Under the Influence of Hydrazine and Correction with “Salsokollin” Drug

    Directory of Open Access Journals (Sweden)

    Marat R. Khanturin

    2012-09-01

    Full Text Available Hydrazine derivatives are used in different areas: airspace industry, healthcare, laboratory-diagnostic activity, that’s why the environment is subjected to contamination by hydrazines. For Kazakhstan, which houses the "Baikonur" Cosmodrome, the problem of environmental pollution by rocket fuel and its components is a burning issue nowadays. This article deals with the impacts by industrial hydrazines on biochemical data of the blood and its correction with the “Salsokollin” Drug. The samples of bilirubin, the whole protein, urea, creatinine, cholesterol, glucose, aminotransferase a-amylases, α-amylase were taken. The thymol test was carried out.

  4. Coal-fuelled systems for peaking power with 100% CO2 capture through integration of solid oxide fuel cells with compressed air energy storage

    Science.gov (United States)

    Nease, Jake; Adams, Thomas A.

    2014-04-01

    In this study, a coal-fuelled integrated solid oxide fuel cell (SOFC) and compressed air energy storage (CAES) system in a load-following power production scenario is discussed. Sixteen SOFC-based plants with optional carbon capture and sequestration (CCS) and syngas shifting steps are simulated and compared to a state-of-the-art supercritical pulverised coal (SCPC) plant. Simulations are performed using a combination of MATLAB and Aspen Plus v7.3. It was found that adding CAES to a SOFC-based plant can provide load-following capabilities with relatively small effects on efficiencies (1-2% HHV depending on the system configuration) and levelized costs of electricity (∼0.35 ¢ kW-1 h-1). The load-following capabilities, as measured by least-squares metrics, show that this system may utilize coal and achieve excellent load-tracking that is not adversely affected by the inclusion of CCS. Adding CCS to the SOFC/CAES system reduces measurable direct CO2 emission to zero. A seasonal partial plant shutdown schedule is found to reduce fuel consumption by 9.5% while allowing for cleaning and maintenance windows for the SOFC stacks without significantly affecting the performance of the system (∼1% HHV reduction in efficiency). The SOFC-based systems with CCS are found to become economically attractive relative to SCPC above carbon taxes of 22 ton-1.

  5. Simultaneous determination of hydrazine and phenyl hydrazine using 4′-(4-carboxyphenyl)-2,2′:6′,2″ terpyridine diacetonitrile triphenylphosphine ruthenium(II) tetrafluoroborate complex functionalized multiwalled carbon nanotubes modified electrode

    Energy Technology Data Exchange (ETDEWEB)

    Tiwari, Ida, E-mail: idatiwari_2001@rediffmail.com [Department of Chemistry (Center of Advanced Study), Faculty of Science, Banaras Hindu University, Varanasi (India); Gupta, Mandakini; Sinha, Preeti [Department of Chemistry (Center of Advanced Study), Faculty of Science, Banaras Hindu University, Varanasi (India); Banks, Craig E. [Faculty of Science and Engineering, School of Science and the Environment, Division of Chemistry and Environmental Science, Manchester Metropolitan University, Chester Street, Manchester M1 5GD (United Kingdom)

    2014-12-15

    Highlights: • A nanocomposite of ruthenium(II) terpyridine, triphenylphosphine based complex and multiwalled carbon nanotubes have been used first time for simultaneous detection of hydrazine and phenyl hydrazine. • The detection limit reported is lower as compared to other reported works. • The paper also focuses towards effect of ligand variation attached to ruthenium(II) terpyridine based complexes complex for the hydrazine and phenyl hydrazine detection. • Nanocomposite does not involve any biological entity hence high stability. - Abstract: A nanocomposite based on the incorporation of the complex 4′-(4-carboxyphenyl)-2,2′:6′,2″ terpyridine triphenylphosphine diacetonitrile ruthenium(II) tetrafluoroborate with multiwalled carbon nanotubes and ionomer supported upon a glassy carbon electrode substrate is reported and characterized with scanning electron microscopy, transmission electron microscopy and infrared spectroscopy. The electrochemical behavior and stability of the composite electrode was investigated via cyclic voltammetry. The modified electrode exhibits an electro-catalytic activity towards the oxidation of both hydrazine and phenyl hydrazine in 0.1 M phosphate buffer solution (PBS, pH 7.4). The oxidation of hydrazine and phenyl hydrazine occurs at 0.81 V and 0.32 V with limit of detection found to be 3.7 × 10{sup −7} M and 1.15 × 10{sup −7} M and having a linear range from 5 × 10{sup −6} M to 6.5 × 10{sup −3} M, and 5 × 10{sup −6} M to 0.2 × 10{sup −3} M, respectively.

  6. Energy-optimisation of biogas-fuelled CHP units; Energetische Optimierung von Biogas-BHKW's

    Energy Technology Data Exchange (ETDEWEB)

    Soltic, P.; Edenhauser, D.; Winkler, A.

    2008-07-15

    This illustrated final report for the Swiss Federal office of Energy (SFOE) reports on the energy-related optimisation of combined heat and power (CHP) units that are fuelled with non-processed biogas. Ways of increasing the efficiency of these units as far as the production of electricity is concerned are examined and commented on. Also, ways of using the heat generated by the CHP units to produce electricity using other, exergetic means are also described. Systems such as Stirling engines and existing and new thermo-electrical elements are discussed. The economic viability of the systems is also discussed.

  7. Kinetic Study of the Electro-Catalytic Oxidation of Hydrazine on Cobalt Hydroxide Modified Glassy Carbon Electrode

    Institute of Scientific and Technical Information of China (English)

    HASANZADEH,Mohammad; KARIM-NEZHAD,Ghasem; SHADJOU,Nasrin; KHALILZADEH,Balal; SAGHATFOROUSH,Lotali; ERSHAD,Sohrab; KAZEMAN,Isa

    2009-01-01

    Electrocatalytic oxidation of hydrazine was investigated on a cobalt hydroxide modified glassy carbon (CHM-GC) electrode in alkaline solution.The process of oxidation involved and its kinetics were established by using cyclic voltammetry,chronoamperometry techniques as well as steady state polarization measurements.In cyclic voltammetry (CV) studies,in the presence of hydrazine the peak current increase of the oxidation of cobalt hydroxide is followed by a decrease in the corresponding cathodic current.This indicates that hydrazine is oxidized on the redox mediator that is immobilized on the electrode surface via an electrocatalytic mechanism.A mechanism based on the electrochemical generation of Co(IV) active sites and their subsequent consumption by the hydrazine in question was also investigated.

  8. Origin and switch of different colors: Thermo-isomerism and crystal structure of (1E,2E)-bis[1-(4-nitrophenyl)ethylidene] hydrazine

    Indian Academy of Sciences (India)

    Said Tighadouini; Smaail Radi; Loic Toupet; Muhammad Sirajuddin; Taibi Ben Hadda; Mehmet Akkurt; Ismail Warad; Yahia N Mabkhot; Saqib Ali

    2015-12-01

    A new symmetric branched 4-nitrophenyl hydrazine compound has been prepared in one-step procedure by direct condensation of aromatic ketone with hydrazine in MeOH. The synthesized compound, red isomer, was characterized by IR, 1H and 13C NMR spectroscopy, Elemental analyses, Mass spectrometry and X-ray crystallography. Refluxing in MeOH solution led to thermo-isomerism offering a white isomer product that was characterized by X-ray crystallography. The red isomer crystallizes in the orthorhombic system having space group Pbcn, with a = 12.7612(4), b = 11.5197(3), c = 20.1586(7) Å, V = 2963.42(16)Å3, Z = 8 while the white isomer crystallizes in the triclinic system having space group P−1, with a = 7.8007(4), 8.5966(7), 12.224 (1) Å, = 71.133(7), = 81.281(5), = 74.895(5)°, V = 746.86(9)Å3, Z = 2. Molecules of both compounds are twisted at N2–N3 bond with the C7-N2-N3-C9 torsion angle of 155.23(12) and −113.36(18)°, respectively. The crystal structures of both compounds are stabilized by weak intramolecular C—H. . .N contacts and intermolecular C—H. . .O hydrogen bonding interactions. In addition, – stacking interactions are observed between the same aromatic rings of molecules.

  9. EFFECT OF IGNITION TIMING ON THE PERFORMANCE OF LPG FUELLED SI ENGINE

    Directory of Open Access Journals (Sweden)

    R.M.Dabhadkar

    2013-05-01

    Full Text Available Fast depletion of fossil fuels and their detrimental effect on the environment is demanding an urgent need of alternative fuels for meeting sustainable energy demand with minimum environmental impact.A lot of research is being carried out throughout the world to evaluate the performance, exhaust emission and combustion characteristics of the existing engines using several alternative fuels such as hydrogen, compressed natural gas, alcohols, liquefied petroleum gas (LPG, biogas, producer gas, bio-diesels developed from vegetable oils, and others (Roy et. al, 2010. LPG and CNG are the alternative fuels to be widely adopted for use in the world. Gaseous fuel mix uniformly with air which burns precisely during combustion than liquid fuels. It has minimum carbon deposition & negligible physical delay. Internal combustion engines running on liquid petroleum gas (LPG are well-proven technologies and work much likegasoline-powered spark-ignition engines. They are normally used as spark-ignition engines for bi-fuelled (gasoline/CH4 cars, but have also been used, for example, in compression-ignition engines for heavy-duty vehicles. Both LPG and NG are not used alone, but always in bi-fuel vehicles, in combination with gasoline. In bi-fuel vehicles two fuels are stored in separate tanks and the engine runs on one fuel at a time. Bi-fuel vehicles have the capability to switch back and forth from gasoline to the other fuel, manually or automatically. As a fuel for spark-ignition engines LPG have some advantages over gasoline, such as a better anti-knock characteristic and reduced CO and unburned HC emissions (Hsieh et al., 2002. Environmental point of view is that there is an increasing interest among the suppliers to investigate LPG as a transportation fuel.It was found that the liquid petroleum gas, roughly a mixture of propane and butane, which gives a benefit in terms of toxic hydrocarbons emissions and ozone formation due to its composition and CO2

  10. Self-regulating heater application to Shuttle/Centaur hydrazine fuel line thermal control

    Science.gov (United States)

    Unkrich, David B.

    1987-01-01

    The Shuttle/Centaur high energy upper stage vehicle thermal environments were more severe than previous Centaur vehicle thermal environments, creating need for a new hydrazine fuel line thermal control technique. Constant power heaters did not satisfy power dissipation requirements, because the power required to maintain fuel line thermal control during cold conditions exceeded the maximum power allowable during hot conditions. Therefore, a Raychem Thermolimit self-regulating heater was selected for this application, and was attached to the hydrazine fuel line with Kapton and aluminum foil tapes. Fuel line/heater thermal modeling and subsequent thermal vacuum chamber testing simulated heater thermal performance during all worst-case Shuttle/Centaur thermal environmental conditions. Fuel line temperatures were maintained between the 4C to 71C limits during all analytical and test cases. Finally, the thermal model predictions were correlated with the test data, thereby ensuring that the model would provide satisfactory predictions for future missions and/or vehicles.

  11. 2-(Hetero(aryl)methylene)hydrazine-1-carbothioamides as potent urease inhibitors.

    Science.gov (United States)

    Saeed, Aamer; Imran, Aqeel; Channar, Pervaiz A; Shahid, Mohammad; Mahmood, Wajahat; Iqbal, Jamshed

    2015-02-01

    A small series of 2-(hetero(aryl)methylene) hydrazine-1-carbothioamides including two aryl derivatives was synthesized and tested for their inhibitory activity against urease. Compound (E)-2-(Furan-2-ylmethylene) hydrazine-1-carbothioamide (3f), having a furan ring, was the most potent inhibitor of urease with an IC50 value of 0.58 μM. Molecular modeling was carried out through docking the designed compounds into the urease binding site to predict whether these derivatives have analogous binding mode to the urease inhibitors. The study revealed that all of the tested compounds bind with both metal atoms at the active site of the enzyme. The aromatic ring of the compounds forms ionic interactions with the residues, Ala(440), Asp(494), Ala(636), and Met(637).

  12. Towards Safer Rocket Fuels: Hypergolic Imidazolylidene-Borane Compounds as Replacements for Hydrazine Derivatives.

    Science.gov (United States)

    Huang, Shi; Qi, Xiujuan; Liu, Tianlin; Wang, Kangcai; Zhang, Wenquan; Li, Jianlin; Zhang, Qinghua

    2016-07-11

    Currently, toxic and volatile hydrazine derivatives are still the main fuel choices for liquid bipropellants, especially in some traditional rocket propulsion systems. Therefore, the search for safer hypergolic fuels as replacements for hydrazine derivatives has been one of the most challenging tasks. In this study, six imidazolylidene-borane compounds with zwitterionic structure have been synthesized and characterized, and their hypergolic reactivity has been studied. As expected, these compounds exhibited fast spontaneous combustion upon contact with white fuming nitric acid (WFNA). Among them, compound 5 showed excellent integrated properties including wide liquid operating range (-70-160 °C), superior loading density (0.99 g cm(-3) ), ultrafast ignition delay times with WFNA (15 ms), and high specific impulse (303.5 s), suggesting promising application potential as safer hypergolic fuels in liquid bipropellant formulations.

  13. Formation of raspberry like cobalt particles with hydrazine reduction in a polyol route

    Science.gov (United States)

    Khe, Cheng Seong; Aziz, Azizan; Lockman, Zainovia; Rajalingam, Sokkalingam; Merican, Zulkifli; Vasant, Pandian

    2016-11-01

    This work describes the effect of hydrazine hydrate on the formation of the raspberry-like morphology of the cobalt nanomaterials in a polyol route. In the synthesis, the molar ratio of N2H4 to Co2+was varied from 2.5 to 10. At the beginning with low molar ratio, spherical microspheres were formed. When the molar ratio was increased to 5 and above, final morphology of the cobalt nanomaterials became raspberry-like. This might be attributed to the absorption of the hydrazine complex of cobalt nanoparticles at certain facets during their growth stage and later self-assembled into the raspberry shaped microparticles. The plausible formation mechanism were proposed.

  14. Microwave-assisted synthesis of carbon-supported carbides catalysts for hydrous hydrazine decomposition

    Science.gov (United States)

    Mnatsakanyan, Raman; Zhurnachyan, Alina R.; Matyshak, Valery A.; Manukyan, Khachatur V.; Mukasyan, Alexander S.

    2016-09-01

    Microwave-assisted synthesis of carbon-supported Mo2C and WC nanomaterials was studied. Two different routes were utilized to prepare MoO3 (WO3) - C precursors that were then subjected to microwave irradiation in an inert atmosphere. The effect of synthesis conditions, such as irradiation time and gas environment, was investigated. The structure and formation mechanism of the carbide phases were explored. As-synthesized nanomaterials exhibited catalytic activity for hydrous hydrazine (N2H4·H2O) decomposition at 30-70 °C. It was shown that the catalyst activity significantly increases if microwave irradiation is applied during the decomposition process. Such conditions permit complete conversion of hydrazine to ammonia and nitrogen within minutes. This effect can be attributed to the unique nanostructure of the catalysts that includes microwave absorbing carbon and active carbide constituents.

  15. The Effects of Hydrazines and Related Compounds on Calcium Calmodulin Regulated Synaptic Processes

    Science.gov (United States)

    1983-07-01

    4F -631 0 1984 E IS. KEY WORDS (Continue on reverse side if necessary and identify by block nunmber) Calmodulin, protein kinase, adenylate cyclase...hydrazines, organophosphates, C) calcium, synaptic processes, protein phosphorylation. 20. BSTRACT (Continue an reverse side it necessary mid Identify...Date Entered) %. % V -*> ~ * - Unclassified SECURITY CLASIFICATION OF THIS PAGE(Vhun Dots tn er@Q 20. A BWT&CT continued, nmembrane fractions and

  16. Dimethyl hydrazine-1,2-dicarboxylate–triphenylphosphine oxide (1/1

    Directory of Open Access Journals (Sweden)

    Bogdan Doboszewski

    2011-07-01

    Full Text Available In the crystal structure of the title compound, C4H8N2O4·C18H15OP, two triphenylphosphine oxide molecules and two dimethyl hydrazine-1,2-dicarboxylate molecules are connected via N—H...O hydrogen bonds of moderate strength and are related via a twofold rotational axis. Weak Car—H... O contacts strengthen the crystal structure.

  17. Preparation of Peptide p-Nitroanilides using an Aryl Hydrazine Solid Support

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Y; Welsh, K; Mitchell, A R; Camarero, J A

    2004-08-05

    Peptide p-nitroanilides are useful compounds for studying protease activity, however the poor nucleophilicity of p-nitroaniline makes their preparation difficult. We describe a new efficient approach for the Fmoc-based synthesis of peptide p-nitroanilides using an aryl hydrazine resin. Mild oxidation of the peptide hydrazide resin yields a highly reactive acyl diazene, which efficiently reacts with weak nucleophiles. We have prepared several peptide p-nitroanilides, including substrates for the Lethal Factor protease from B. anthracis.

  18. Nanostructured SnO2 encapsulated guar-gum hybrid nanocomposites for electrocatalytic determination of hydrazine.

    Science.gov (United States)

    Malik, Priya; Srivastava, Manish; Verma, Ranjana; Kumar, Manish; Kumar, D; Singh, Jay

    2016-01-01

    The present article deals with synthesis of sol-gel derived tin dioxide (SnO2) nanoparticles encapsulated in to guar gum (GG) biopolymer as the organic-inorganic hybrid materials for the determination of hydrazine. The organic-inorganic hybrid combines the perfunctory strength offered by the inorganic SnO2 nanoparticles with flexible binding sites provided by the organic biopolymer (GG) solution by the ultrasonication. The phase identification, crystalline size, surface morphology and optical properties of prepared SnO2 and SnO2-GG nanocomposites has been investigated through FT-IR, XRD, SEM, AFM, TEM, UV-Vis, and PL techniques. The colloidal solution of SnO2 and GG is electrophoretically deposited (EPD) onto the indium tin-oxide (ITO) glass substrate and studied for the electrooxidation of hydrazine. Under the optimized experimental conditions, the linearity between the current response and the hydrazine concentration has been obtained in the range of 2-22 mM, with a low detection limit of 2.76 mM and a high sensitivity of 5.72 μA cm(-2). Based on the linear increase in amperometric current, a sensitive hydrazine electrochemical sensor is constructed. The proposed SnO2-GG/ITO electrode shows a good response time (35s), reproducibility, and long-term stability. The obtained results suggest that SnO2-GG nanocomposites electrode provides a favorable sensing platform for the electrochemical studies. In addition, the cyclic voltammetry (CV) studies are used to evaluate the kinetic parameters.

  19. Design, Synthesis and Biological Activities of Novel Benzoyl Hydrazines Containing Pyrazole

    Institute of Scientific and Technical Information of China (English)

    闫涛; 于淑晶; 刘鹏飞; 刘卓; 王宝雷; 熊丽霞; 李正名

    2012-01-01

    In search of environmentally benign compounds with high biological activity, low toxicity and low resistance, 8 novel benzoyl hydrazines containing pyrazole were designed and synthesized. All compounds were characterized by I H NMR spectra and HRMS. The preliminary results of biological activity assessment indicated that most of title compounds exhibited certain insecticidal activities against M),thimna separata Walker at 200 mg L-1 but excellent fungicidal activities against six fungus at 50 mg L-1, which were better than the control.

  20. Dose response of hydrazine - Deproteinated tooth enamel under blue light stimulation

    Energy Technology Data Exchange (ETDEWEB)

    Yuece, Ulkue Rabia, E-mail: ulkuyuce@hotmail.co [Ankara University, Faculty of Engineering, Department of Engineering Physics, 06100, Tandogan - Ankara (Turkey); Meric, Niyazi, E-mail: meric@ankara.edu.t [Ankara University, Faculty of Engineering, Department of Engineering Physics, 06100, Tandogan - Ankara (Turkey); Atakol, Orhan, E-mail: atakol@science.ankara.edu.t [Ankara University, Science Faculty, Department of Chemistry, 06100, Tandogan - Ankara (Turkey); Yasar, Fusun, E-mail: ab121310@adalet.gov.t [Council of Forensic Medicine, Ankara Branch, Ankara (Turkey)

    2010-08-15

    The beta dose response and Optically Stimulated Luminescence (OSL) signal stability characteristics of human tooth enamel deproteinated by hydrazine reagent under blue photon stimulation are reported. Removal of the protein organic component of tooth enamel resulted in a higher OSL sensitivity and slower fading of OSL signals. The effect of chemical sample preparation on the enamel sample sensitivity is discussed and further steps to make this deproteinization treatment suitable for in vitro dose reconstruction studies are suggested.

  1. Highly Sensitive Hydrazine Chemical Sensor Based on CNT-PdPt Nanocomposites

    Directory of Open Access Journals (Sweden)

    Sung Phil Kim

    2015-01-01

    Full Text Available Bimetallic PdPt nanoparticles were prepared using the chemical reduction method. The PdPt nanoparticles were successfully deposited on thiolated carbon nanotubes (CNTs to form a CNT-PdPt nanocomposite as an electron mediator for the fabrication of a hydrazine sensor. The PdPt nanoparticles had an average particle size of 2.3 nm and were well dispersed on the surfaces of the CNTs in the prepared CNT-PdPt nanocomposite, as demonstrated using transmission electron microscopy (TEM, energy dispersive X-ray spectroscopy (EDX, and X-ray diffraction (XRD. Based on X-ray photoelectron spectroscopy (XPS results, the estimated proportions of Pd and Pt in the CNT-PdPt nanocomposite were approximately 3.0% and 3.2%, respectively. A fabricated chemical sensor based on CNT-PdPt was found to exhibit better amperometric activity with respect to the hydrazine oxidation reaction than CNT-Pd, CNT-Pt, and commercial Pd/C and Pt/C catalysts. This sensor exhibited a linear range of 0.55–1,200 μM and a detection limit of 0.28 μM (S/N = 3 with a fast response time (within 5 s. Furthermore, the sensor could be used repeatedly for the consecutive detection of hydrazine with good reusability and storage stability. These properties demonstrate that the CNT-PdPt nanocomposite is a promising electron mediator for the fabrication of amperometric hydrazine sensors.

  2. Reactivity of 4-tert-Butyldimethylsiloxy-1,2,3,6-tetrahydropyridines with Hydrazines

    Directory of Open Access Journals (Sweden)

    Manuel Medarde

    2006-11-01

    Full Text Available The reactivity of 6-(nitrophenyl or trimethoxyphenyl-4-tert-butyldimethyl- siloxy-1,2,3,6-tetrahydropyridine derivatives with hydrazines under acid conditions is described. The structure of the products isolated − hydrazones, pyrazolines or pyridazinones − depended on the conditions used. In addition, a systematic study of the reaction outcomes was carried out by introducing variations on the substituents of the tetrahydropyridine ring.

  3. Study on the Reaction Between Methyl Hydrazine and Formaldehyde in Nitric Acid Medium

    Institute of Scientific and Technical Information of China (English)

    LI; Chuan-bo; CAO; Zhi; BIAN; Xiao-yan; XIAN; Liang; YAN; Tai-hong; ZHENG; Wei-fang

    2012-01-01

    <正>To make sure whether the reaction between formaldehyde and methyl hydrazine (MMH) could happen in dilute nitric acid solution, the condensation reaction between the two ones was investigated at 16 ℃. The reaction was slow and it took over 5 hours to reach the balance and the solution turned yellow at last. The maximum absorption peaks of the product existed at 340 nm and 400-450 nm, respectively.

  4. (E)-1-Benzyl-idene-2,2-diphenyl-hydrazine.

    Science.gov (United States)

    Mendoza, Angel; Meléndrez-Luevano, Ruth; Cabrera-Vivas, Blanca M; Lozano-Márquez, Claudia D; Carranza, Vladimir

    2012-02-01

    The asymmetric unit of the title compound, C(19)H(16)N(2), contains two independent mol-ecules, both of which show an E configuration with respect to the C=N bond. The dihedral angles between the phenyl rings bonded to the hydrazine group are 81.00 (10) and 88.34 (8)° in the two mol-ecules. Inter-molecular C-H⋯π inter-actions are observed in the crystal structure.

  5. The Decomposition of Hydrazine in the Gas Phase and over an Iridium Catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Michael W. [Ames Laboratory; Gordon, Mark S. [Ames Laboratory

    2013-09-30

    Hydrazine is an important rocket fuel, used as both a monopropellant and a bipropellant. This paper presents theoretical results to complement the extensive experimental studies of the gas phase and Ir catalyzed decompositions involved in the monopropellant applications of hydrazine. Gas phase electronic structure theory calculations that include electron correlation predict that numerous molecular and free radical reactions occur within the same energy range as the basic free radical pathways: NN bond breaking around 65 kcal/mol and NH bond breaking around 81 kcal/mol. The data suggest that a revision to existing kinetics modeling is desirable, based on the energetics and the new elementary steps reported herein. A supported Ir-6 octahedron model for the Shell 405 Iridium catalyst used in thrusters was developed. Self-Consistent Field and electron correlation calculations (with core potentials and associated basis sets) find a rich chemistry for hydrazine on this catalyst model. The model catalyst provides dramatically lower NN and NH bond cleavage energies and an even smaller barrier to breaking the NH bond by NH2 abstractions. Thus, the low temperature decomposition over the catalyst is interpreted in terms of consecutive NH2 abstractions to produce ammonia and nitrogen. The higher temperature channel, which has hydrogen and nitrogen products, may be due to a mixture of two mechanisms. These two mechanisms are successive NH cleavages with surface H + H recombinations, and the same type of assisted H-2 eliminations found to occur in the gas phase part of this study.

  6. Alkalization of steam and condensate with 2-amino-1-butanol and hydrazine; Alkalisering av aanga och kondensat med butanolamin och hydrazin

    Energy Technology Data Exchange (ETDEWEB)

    Falk, I. [Studsvik Material AB, Nykoeping (Sweden)

    1996-04-01

    To maintain a low corrosion level in steam- and condensate systems at power and industrial plants, an alkalization of the steam is needed. A low corrosion level lowers the risk of operation disturbances and reduces the cost of the condensate clean up. A better knowledge in the behavior of the alkalis will improve the possibilities to avoid the corrosion attacks. In this work experimental measurements have been carried out during steam boiler conditions as temperature, continuous steam generation and condensation. It has been found that the volatility of 2-amino-1-butanol is very low during stationary dynamic conditions at 250 deg C and 120 deg C. To achieve a high ph-value in the final condensate a very high concentration of 2-amino-1-butanol is thus needed especially when the steam contains acidic compounds. The alkalization effect is obtained from ammonia which is created by thermal decomposition of hydrazine in the boiler water. It is necessary to carry out experimental investigations showing the thermal stability of organic compounds in boiler water before it is possible to recommend them as better volatile alkalis than ammonia and hydrazine. 6 refs, 13 figs

  7. AGN fuelling: Bridging Large and Small Scales - Overlapping Inflows as Catalysts of Accretion

    Science.gov (United States)

    Manuel Carmona Loaiza, Juan Manuel

    2015-05-01

    One of the biggest challenges in understanding the fuelling of supermassive black holes in active galactic nuclei (AGN) is not on accounting for the source of fuel, as a galaxy can comfortably supply the required mass budget, but on its actual delivery. While a clear picture has been developed for the large scale (~ kpc) down to the intermediate one (~ 100 pc), and for the smallest scales (~ 0.1 pc) where an accretion disc likely forms, a bridge that has proven difficult to build is that between ~ 100 pc and ~ 0.1 pc. It is feared that gas at these scales might still retain enough angular momentum and settle into a larger scale disc with very low or no inflow to form or replenish the inner accretion disc (on ~ 0.01 pc scales). In this Thesis, I present numerical simulations in which a rotating gaseous shell flows towards a SMBH because of its lack of rotational support. As inflow proceeds, gas from the shell impacts an already present nuclear (~ 10pc) disc. The cancellation of angular momentum and redistribution of gas, due to the misalignment between the angular momentum of the shell and that of the disc, is studied in this scenario. The underlying hypothesis is that even if transport of angular momentum at these scales may be inefficient, the interaction of an inflow with a nuclear disc would still provide a mechanism to bring mass inwards because of the cancellation of angular momentum. I quantify the amount of gas such a cancellation would bring to the central parsec under different circumstances: Co- and counter-rotation between the disc and the shell and the presence or absence of an initial turbulent kick; I also discuss the impact of self gravity in our simulations. The scenario we study is highly idealized and designed to capture the specific outcomes produced by the mechanism proposed. I find that angular momentum cancellation and redistribution via hydrodynamical shocks leads to sub-pc inflows enhanced by more than 2-3 orders of magnitude. In all of our

  8. On exhaust emissions from petrol-fuelled passenger cars at low ambient temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Laurikko, J. [VTT Energy, Espoo (Finland). Energy Use

    1998-11-01

    The study at hand deals with regulated and unregulated exhaust emissions from petrol-fuelled cars at low ambient temperatures with present-day or near-future exhaust after treatment systems. The subject has been investigated at VTT over a decade and this report compiles data from various sub-studies carried out between the years 1993 - 1997. Each one of them viewed different aspects of the phenomenon, like determining the low-temperature response of today`s new cars employing three-way catalytic converters or assessing the long-term durability and the influence of vehicle mileage upon the low-temperature emissions performance. Within these studies, together more than 120 cars of model years from 1990 to 1997 have been tested. Most of them were normal, in-service vehicles with total mileages differing between only a few thousand kilometres for new cars up to 80,000 km or even more for the in-use vehicles. Both the US FTP75 and the European test cycle have been employed, and the ambient temperatures ranged from the baseline (+22 deg C) down to +- O deg C, -7 deg C and in some cases even to -20 deg C. The studies attested that new cars having today`s advanced emissions control systems produced fairly low levels of emissions when tested in conditions designated in the regulations that are the basis of the current new-vehicle certification. However, this performance was not necessarily attained at ambient temperatures that were below the normative range. Fairly widespread response was recorded, and cars having almost equal emissions output at baseline could produce largely deviating outcomes in low-temperature conditions. On average, CO and HC emissions increased by a factor of five to 10, depending on the ambient temperature and vehicle type. However, emissions of NO{sub x} were largely unaffected. Apart from these regulated emissions, many unregulated species were also determined, either by using traditional sampling and chromatography methods or on-line, employing

  9. The influence of tertiary butyl hydrazine as a co-reactant on the atomic layer deposition of silver

    Science.gov (United States)

    Golrokhi, Zahra; Marshall, Paul A.; Romani, Simon; Rushworth, Simon; Chalker, Paul R.; Potter, Richard J.

    2017-03-01

    Ultra-thin conformal silver films are the focus of development for applications such as anti-microbial surfaces, optical components and electronic devices. In this study, metallic silver films have been deposited using direct liquid injection thermal atomic layer deposition (ALD) using (hfac)Ag(1,5-COD) ((hexafluoroacetylacetonato)silver(I)(1,5-cyclooctadiene)) as the metal source and tertiary butyl hydrazine (TBH) as a co-reactant. The process provides a 23 °C wide 'self-limiting' ALD temperature window between 105 and 128 °C, which is significantly wider than is achievable using alcohol as a co-reactant. A mass deposition rate of ∼20 ng/cm2/cycle (∼0.18 Å/cycle) is observed under self-limiting growth conditions. The resulting films are crystalline metallic silver with a near planar film-like morphology which are electrically conductive. By extending the temperature range of the ALD window by the use of TBH as a co-reactant, it is envisaged that the process will be exploitable in a range of new low temperature applications.

  10. Intramolecular Electron Transfer in Bis(tetraalkyl Hydrazine) and Bis(hydrazyl) Radical Cations.

    Science.gov (United States)

    Chang, Hao

    A series of multicyclic bis(hydrazine) and bis(diazenium) compounds connected by relatively rigid hydrocarbon frameworks were prepared for the study of intramolecular electron transfer. The thermodynamics of electron removal of these compounds was investigated by cyclic voltammetry. The difference between the first and second oxidation potentials for the 4 sigma-bonded species was found to be larger for the bis(hydrazyl) radical systems than for the bis(hydrazines) by ca. 0.2 V (4.6 kcal/mol). This indicates a greater degree of interaction between the two nitrogen moieties for the hydrazyl systems, which is consistent with a greater degree of electronic coupling (H _{rm AB}) in these systems. The ESR spectra of the 4 sigma -bonded bis(hydrazine) radical cations indicate localized radical cations, which corresponds to slow intramolecular electron transfer on the ESR timescale. Conversely, the ESR spectra of the corresponding bis(hydrazyl) radical cation systems show nitrogen hyperfine splittings of a(4N) of ca. 4.5 G. This indicates that intramolecular electron transfer between the two nitrogen moieties is fast on the ESR timescale; the rate of exchange, k_ {rm ex} was estimated to be well above 1.9 times 10^8 s^{-1}. The contrast in exchange rates is consistent with the large geometry change upon oxidation which is characteristic of hydrazines. The hydrazyls undergo a smaller geometry change upon oxidation, and thus are expected to exhibit smaller inner-sphere reorganization energies. The optical spectra of these radical species was investigated in hopes of observing absorption bands corresponding to intramolecular electron transfer, as predicted by Hush theory. A broad absorption band was observed in the near IR region for the saturated bis(hydrazyl) radical cation system at 1060 nm (9420 cm^{-1} ) in acetonitrile at room temperature, and was accompanied by a narrower band at 1430 nm (6993 cm^ {-1}). The width of this band was estimated to be 545 nm (6496 cm^{-1

  11. Comparative study of cogasification and co-combustion of communal sewage sludge in brown coal fuelled plants; Vergleich der Mitvergasung und Mitverbrennung kommunaler Klaerschlaemme in braunkohlegefeuerten Anlagen

    Energy Technology Data Exchange (ETDEWEB)

    Schiffer, H.P.; Bierbaum, K.; Adlhoch, W.; Thomas, G. [Rheinbraun AG, Koeln (Germany)

    1996-12-31

    Co-combustion and cogasification of sewage sludge in brown coal fuelled plants are compared, and an economic assessment is made. (ABI) [Deutsch] Die Mitverbrennung und Mitvergasung von Klaerschlamm in braunkohlegefeuerten Anlagen werden verglichen und auf ihre Wirtschaftlichkeit hin untersucht. (ABI)

  12. Comparing in Cylinder Pressure Modelling of a DI Diesel Engine Fuelled on Alternative Fuel Using Two Tabulated Chemistry Approaches.

    Science.gov (United States)

    Ngayihi Abbe, Claude Valery; Nzengwa, Robert; Danwe, Raidandi

    2014-01-01

    The present work presents the comparative simulation of a diesel engine fuelled on diesel fuel and biodiesel fuel. Two models, based on tabulated chemistry, were implemented for the simulation purpose and results were compared with experimental data obtained from a single cylinder diesel engine. The first model is a single zone model based on the Krieger and Bormann combustion model while the second model is a two-zone model based on Olikara and Bormann combustion model. It was shown that both models can predict well the engine's in-cylinder pressure as well as its overall performances. The second model showed a better accuracy than the first, while the first model was easier to implement and faster to compute. It was found that the first method was better suited for real time engine control and monitoring while the second one was better suited for engine design and emission prediction.

  13. A cycle simulation model for predicting the performance of a diesel engine fuelled by diesel and biodiesel blends

    Energy Technology Data Exchange (ETDEWEB)

    Gogoi, T.K. [Mechanical Engineering Department, Tezpur University, Napaam, Tezpur, Assam 784028 (India); Baruah, D.C. [Energy Department, Tezpur University, Napaam, Tezpur, Assam 784028 (India)

    2010-03-15

    Among the alternative fuels, biodiesel and its blends are considered suitable and the most promising fuel for diesel engine. The properties of biodiesel are found similar to that of diesel. Many researchers have experimentally evaluated the performance characteristics of conventional diesel engines fuelled by biodiesel and its blends. However, experiments require enormous effort, money and time. Hence, a cycle simulation model incorporating a thermodynamic based single zone combustion model is developed to predict the performance of diesel engine. The effect of engine speed and compression ratio on brake power and brake thermal efficiency is analysed through the model. The fuel considered for the analysis are diesel, 20%, 40%, 60% blending of diesel and biodiesel derived from Karanja oil (Pongamia Glabra). The model predicts similar performance with diesel, 20% and 40% blending. However, with 60% blending, it reveals better performance in terms of brake power and brake thermal efficiency. (author)

  14. Carcinogenicity and chronic toxicity of hydrazine monohydrate in rats and mice by two-year drinking water treatment.

    Science.gov (United States)

    Matsumoto, Michiharu; Kano, Hirokazu; Suzuki, Masaaki; Katagiri, Taku; Umeda, Yumi; Fukushima, Shoji

    2016-04-01

    The carcinogenicity and chronic toxicity of hydrazine monohydrate was examined by administrating hydrazine monohydrate in drinking water to groups of 50 F344/DuCrj rats and 50 Crj:BDF1 mice of both sexes for two years. The drinking water concentration of hydrazine monohydrate was 0, 20, 40 or 80 ppm (wt/wt) for male and female rats and male mice; and 0, 40, 80 or 160 ppm for female mice. Survival rates of each group of males and females rats and mice were similar to the respective controls, except female rats administered 80 ppm. Two-year administration of hydrazine monohydrate produced an increase in the incidences of hepatocellular adenomas and carcinomas in rats of both sexes along with hepatic foci. In mice, the incidences of hepatocellular adenomas and carcinomas were increased in females, and significantly increased incidences of hepatocellular adenomas in females administered 160 ppm were observed. Thus, hydrazine monohydrate is carcinogenic in two species, rats and mice. Additionally, non-neoplastic renal lesions in rats and mice and non-neoplastic nasal lesions in mice were observed.

  15. An Improved Calibration Method for Hydrazine Monitors for the United States Air Force

    Energy Technology Data Exchange (ETDEWEB)

    Korsah, K

    2003-07-07

    This report documents the results of Phase 1 of the ''Air Force Hydrazine Detector Characterization and Calibration Project''. A method for calibrating model MDA 7100 hydrazine detectors in the United States Air Force (AF) inventory has been developed. The calibration system consists of a Kintek 491 reference gas generation system, a humidifier/mixer system which combines the dry reference hydrazine gas with humidified diluent or carrier gas to generate the required humidified reference for calibrations, and a gas sampling interface. The Kintek reference gas generation system itself is periodically calibrated using an ORNL-constructed coulometric titration system to verify the hydrazine concentration of the sample atmosphere in the interface module. The Kintek reference gas is then used to calibrate the hydrazine monitors. Thus, coulometric titration is only used to periodically assess the performance of the Kintek reference gas generation system, and is not required for hydrazine monitor calibrations. One advantage of using coulometric titration for verifying the concentration of the reference gas is that it is a primary standard (if used for simple solutions), thereby guaranteeing, in principle, that measurements will be traceable to SI units (i.e., to the mole). The effect of humidity of the reference gas was characterized by using the results of concentrations determined by coulometric titration to develop a humidity correction graph for the Kintek 491 reference gas generation system. Using this calibration method, calibration uncertainty has been reduced by 50% compared to the current method used to calibrate hydrazine monitors in the Air Force inventory and calibration time has also been reduced by more than 20%. Significant findings from studies documented in this report are the following: (1) The Kintek 491 reference gas generation system (generator, humidifier and interface module) can be used to calibrate hydrazine detectors. (2) The

  16. Exposure assessment of particulates originating from diesel and CNG fuelled engines

    Energy Technology Data Exchange (ETDEWEB)

    Oravisjaervi, K.; Pietikaeinen, M.; Keiski, R. L. (Univ. of Oulu, Dept. of Process and Environmental Engineering (Finland)). email: kati.oravisjarvi@oulu.fi; Voutilainen, A. (Univ. of Kuopio, Dept. of Physics (Finland)); Haataja, M. (Oulu Univ. of Applied Sciences (Finland); Univ. of Oulu, Dept. of Mechanical Engineering (Finland)); Ruuskanen, J. (Univ. of Kuopio, Dept. of Environmental Sciences (Finland)); Rautio, A. (Univ. of Oulu, Thule Inst. (Finland))

    2009-07-01

    Particulates emitted from combustion engines have been a great concern in past years due to their adverse health effects, such as pulmonary and cardiovascular diseases, morbidity and mortality. The source of particulates can be stationary and transient, such as gas and oil fuelled engines, turbines and boilers. Particulate matter (PM) dispersed into ambient air can be classified in many ways: the mechanism of the formation, the size and the composition. Fine particles (PM2.5) are particles with an aerodynamic diameter less than 2.5 mum and particles, greater than 2.5 mum in diameter are generally referred to as coarse particles (PM10). PM2.5 is also called the respirable fraction, because they can penetrate to the unciliated regions of the lung. Fine particles consist of so called ultrafine particles (an aerodynamic diameter less than 0.1 mum). The sizes of particulates emitted from combustion processes range between 10 nm and 100 mum, and are usually a mixture of unburned and partially burned hydrocarbons. Diesel exhaust particles have a mass median diameter of 0.05-1.0 mum. They are a complex mixture of elemental carbon, a variety of hydrocarbons, sulphur compounds, and other species. They consist of a numerous spherical primary particles, which are agglomerated into aggregates. Particles from natural gas engine emissions range from 0.01-0.7 mum. Increase in PM10 pollution has been found to be associated with a range of adverse health effects, such as increased use of medication for asthma, attacks of asthma in patients with pre-existing asthma, attacks of chronic obstructive pulmonary disease (COPD), deaths from respiratory causes, admission to hospital for cardiovascular causes, deaths from heart attacks and deaths from strokes. While it is unknown, which particulate matter component is the most hazardous for humans, a number of factors suggest that ultrafine particles may be more toxic than larger particles. Ultrafine particles have a large surface area per

  17. The effect of EGR rates on NOX and smoke emissions of an IDI diesel engine fuelled with Jatropha biodiesel blends

    Directory of Open Access Journals (Sweden)

    M. Gomaa, A.J. Alimin, K.A. Kamarudin

    2011-05-01

    Full Text Available The depletion of fossil fuels and the worst impact on environmental pollution caused of their burning have led to the search for renewable clean energies. Nowadays, there are many sources of renewable energy. Biodiesel is just one source, but a very important one. Biodiesel has been known as an attractive alternative fuel although biodiesel produced from edible oil is very expensive than conventional diesel. Therefore, the uses of biodiesel produced from non-edible oils are much better option. Currently Jatropha biodiesel (JBD is receiving attention as an alternative fuel for diesel engine. However, previous studies have reported that combustion of JBD emitted higher nitrogen oxides (NOX, while hydrocarbon (HC and smoke emissions were lower than conventional diesel fuel. Exhaust gas recirculation (EGR is one of the techniques being used to reduce NOX emission from diesel engines; because it decreases both flame temperature and oxygen concentration in the combustion chamber. Some studies succeeded to reduce NOX emission from biodiesel fuelled engines using EGR; but they observed increase in smoke emission with increasing engine load and EGR rate. The aim of the present work is to investigate the effect of EGR on an indirect injection (IDI diesel engine fuelled with JBD blends in order to reduce NOX and smoke emissions. A 4-cylinder, water-cooled, turbocharged, IDI diesel engine was used for investigation. Smoke, NOX, carbon monoxide (CO and carbon dioxide (CO2 emissions were recorded and various engine performance parameters were also evaluated. The results showed that, at 5% EGR with JB5, both NOX and smoke opacity were reduced by 27% and 17% respectively. Furthermore, JB20 along with 10% EGR was also able to reduce both NOX and smoke emission by 36% and 31%, respectively compared to diesel fuel without EGR.

  18. Spectral, thermal and X-ray studies on some new bis-hydrazine metal glyoxylates and bis-hydrazine mixed metal glyoxylates

    Energy Technology Data Exchange (ETDEWEB)

    Vikram, L. [Department of Chemistry, Government Arts College, Ooty, The Nilgiris, Udhagamandalam 643002 (India); Sivasankar, B.N. [Department of Chemistry, Government Arts College, Ooty, The Nilgiris, Udhagamandalam 643002 (India)]. E-mail: sivabickol@yahoo.com

    2007-01-01

    Bis-hydrazine complexes of metal glyoxylates and mixed metal glyoxylates of 3d-metal ions of the formula M(OOCCHO){sub 2}(N{sub 2}H{sub 4}){sub 2}, where M = Mg, Mn, Co, Ni, Cu, Zn or Cd and M{sub 1/3}Co{sub 2/3}(OOCCHO){sub 2}(N{sub 2}H{sub 4}){sub 2}, where M = Mg, Mn, Ni, Zn or Cd, respectively, have been prepared and studied. The compositions of the complexes have been determined by chemical analyses. The magnetic moments and electronic spectra suggest a high-spin octahedral geometry for the metal complexes. Infrared spectral data indicate the bidentate bridging by hydrazine molecules and monodentate coordination by glyoxylate ions in both the metal and mixed metal compounds. Thermogravimetry and differential thermal analyses in air have been used to study the thermal behaviour of the complexes. The simultaneous TG-DTA traces of all the complexes show multi-step deg.radation and the final products are found to be the respective metal oxides in the case of metal complexes and metal cobaltites in the case of mixed metal complexes. The final residues were identified by their X-ray powder diffraction patterns. X-ray powder diffraction patterns of the complexes including mixed metal complexes are almost superimposable with in each of the series indicating isomorphism. The metal cobaltites MCo{sub 2}O{sub 4}, where M = Mg, Mn, Ni, Zn or Cd were also prepared by decomposing the respective mixed metal complex in a pre-heated silica crucible at about 300 deg. C, and their identities were confirmed by chemical analyses, infrared spectra and X-ray powder diffraction.

  19. Ammonia and hydrazine. Transition-metal-catalyzed hydroamination and metal-free catalyzed functionalization

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, Guy [Univ. of California, San Diego, CA (United States)

    2012-06-29

    The efficient and selective preparation of organic molecules is critical for mankind. For the future, it is of paramount importance to find catalysts able to transform abundant and cheap feedstocks into useful compounds. Acyclic and heterocyclic nitrogen-containing derivatives are common components of naturally occurring compounds, agrochemicals, cosmetics, and pharmaceuticals; they are also useful intermediates in a number of industrial processes. One of the most widely used synthetic strategies, allowing the formation of an N-C bond, is the addition of an N-H bond across a carbon-carbon multiple bond, the so-called hydroamination reaction. This chemical transformation fulfills the principle of “green chemistry” since it ideally occurs with 100% atom economy. Various catalysts have been found to promote this reaction, although many limitations remain; one of the most prominent is the lack of methods that permit the use of NH3 and NH2NH2 as the amine partners. In fact, ammonia and hydrazine have rarely succumbed to homogeneous catalytic transformations. Considering the low cost and abundance of ammonia (136 million metric tons produced in 2011) and hydrazine, catalysts able to improve the reactivity and selectivity of the NH3- and NH2NH2-hydroamination reaction, and more broadly speaking the functionalization of these chemicals, are highly desirable. In the last funded period, we discovered the first homogeneous catalysts able to promote the hydroamination of alkynes and allenes with ammonia and the parent hydrazine. The key feature of our catalytic systems is that the formation of catalytically inactive Werner complexes is reversible, in marked contrast to most of the known ammonia and hydrazine transition metal complexes. This is due to the peculiar electronic properties of our neutral ancillary ligands, especially their strong donating capabilities. However, our catalysts currently require

  20. Electrocatalytic oxidation of hydrazine with alizarin red S as a homogenous mediator on the glassy carbon electrode

    Institute of Scientific and Technical Information of China (English)

    Mohammad; Mazloum-Ardakani; Roya; Mazidi; Mohammad; Hossein; Mashhadizadeh; Parvanah; Rahimi; Mohammad; Ali; Karimi

    2010-01-01

    Electro-catalytic oxidation and detection of hydrazine on a glassy carbon electrode,at pH 6.0,was studied by using alizarin red S as a homogeneous mediator.The overall number of electrons involved in the catalytic oxidation of hydrazine and that involved in the rate-determining step were four and one,respectively.The interfering effect of some cations,anions and organic compounds were examined.Peak current for this process varied linearly with the square root of the scan rate.The kinetic parameters,such as the electron transfer coefficient(α) and catalytic rate constant(k) ,were determined using cyclic voltammetry,linear sweep voltammetry and chronoamperometry.The electro-catalytic response was optimized with regards to the pH,scan rate,hydrazine concentration and other variables.

  1. The synthesis and molecular recognization of the polyamine transporter of hydrazine-modified diamine conjugates

    Institute of Scientific and Technical Information of China (English)

    Jun Jun Zhou; Hao Huang; Song Qiang Xie; Yu Xia Wang; Jin Zhao; Chao Jie Wang

    2008-01-01

    A series of four novel hydrazine-modified diamine conjugates (7a-b, 8a-b) were synthesized and evaluated for cytotoxicityagainst Melanoma B 16, α-difluoromethylornithine (DFMO)-treated B 16, spermidine (SPD)-treated B 16, Mouse leukemia L 1210and Hela cell lines. Both the DFMO-B 16 and SPD-B 16 experiments indicated that conjugates 7a-b and 8a-b could recognize thepolyamine transporter (PAT) and enter the cells in part or in whole via PAT, although they were not as efficient as the reference, 9-anthracenemethyl homospermidine (1).

  2. Hydrazine Blending and Storage Facility, Interim Response Action, Final Implementation Document for Decommissioning, Phase 1

    Science.gov (United States)

    1991-03-18

    PRIMARY OBJECTIVES OF THE IRA 2. SITE INVENTORY - TANKS, PIPING, BUILDINGS, ASBEST , DEBRIS, DRUMS 3. PLAN OF ACTION - TRANSFER OF UNTREATED WASTEWATER...Response Action (IRA) H at thte Hydrazine Blending and Storage Facility (HBSF) located at Rocky Mountain Arsenal (RMA) in Commerce City , Colorado. It was...LOCATION MAP Commerce CIty , Colorado 1A U) Cl)) zr LU .i I 0< 9< z (’ICM ..w co ai >. r 0) IC., Z C’) ________________0 W jl cor cliB destruction of

  3. Hydrogenation of liquid natural rubber via diimide reduction in hydrazine hydrate/hydrogen peroxide system

    Energy Technology Data Exchange (ETDEWEB)

    Yusof, Muhammad Jefri Mohd; Jamaluddin, Naharullah; Abdullah, Ibrahim; Yusoff, Siti Fairus M. [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2015-09-25

    Liquid natural rubber (LNR) with molecular weight of lower than 10{sup 5} and shorter polymeric chain than natural rubber was prepared. LNR was then hydrogenated via diimide reduction by oxidation of hydrazine hydrate with hydrogen peroxide. The unsaturated units of the rubber were converted into saturated hydrocarbon to strengthen the backbone of the polymer so it was able to resist thermal degradation. The results indicated that hydrogenation degree of the product (HLNR) could be extended to 91.2% conversion under appropriate conditions. The hydrogenated LNR (HLNR) was characterized using Fourier-Transform Infrared (FTIR) and Nuclear Magnetic Resonance (NMR) spectroscopy. The physical characteristics of HLNR were analyzed with Termogravimetric Analysis (TGA)

  4. Alternatives to hydrazine in steam and hot water systems. Pt. 1

    Energy Technology Data Exchange (ETDEWEB)

    Hoehenberger, L.

    1989-04-01

    Ever since hydrazine was classified among the carcinogenics, users were confronted with a number of alternatives. The most common of these, i.e. ascorbate, carbohydrazide, diethyl hydroxylamine (DEHA), hydrochinine, hyposulfite, methyl ethylketoxime (MEKO), sulfite and tannines, are compared in a table with a view to their oxygen binding efficiency and other important characteristics. So far, there is no substitute with a simple reaction mechanism and optimum corrosion protection efficiency. Established physical methods are favoured for oxygen removal. Corrosion protection by passivation and inhibition are gone into. (orig.).

  5. Structure and Quantum Chemistry Study on Hexaacetyl D-Mannose Hydrazine

    Institute of Scientific and Technical Information of China (English)

    CAO Rui; LIU Xiao-Hong; CHENG Chang-Mei; WANG Ru-Ji; ZHAO Yu-Fen; WANG Lai-Xi

    2007-01-01

    Hexaacetyl D-mannose hydrazine is one type of important intermediates in saccharide chemistry. In this paper, its single crystal was obtained and furthermore, X-ray diffraction and quantum chemistry calculation were performed. It belongs to orthorhombic system, space group P212121, with a=16.267(3), b=19.263(3), c=7.1948(12)(A), Mr=446.41, Dc=1.315 g/cm3, V=2254.5(6)(A)3 and Z=4. Meanwhile, the experimental results also provide information for designing a kind of molecular switch based on the mannose nitrogenous derivatives.

  6. Effect of kaempferol on lipid peroxidation and antioxidant status in 1,2-dimethyl hydrazine induced colorectal carcinoma in rats.

    Science.gov (United States)

    Nirmala, Parthasarathy; Ramanathan, Manickam

    2011-03-01

    Colorectal cancer, a common cause of cancer related deaths in both sexes in western population is often due to persistent oxidative stress leading to DNA damage. Antioxidants scavenge free radicals and inhibit neoplastic process. Kaempferol, a flavonol widely distributed in tea, broccoli, grape fruit, brussels sprouts and apple, is claimed to have chemopreventive action in colon cancer. The aim of our study was to evaluate the effect of kaempferol on tissue lipid peroxidation and antioxidant status in 1,2-dimethyl hydrazine induced colorectal cancer in male Wistar rats and to compare its efficacy with irinotecan. Experimental colon cancer induced by 1,2-dimethyl hydrazine in rats mimic human colon cancer and therefore is an ideal model for chemoprevention studies. The rats were divided into six groups. Group 1 served as control. Group 2 received 1,2-dimethyl hydrazine (20 mg/kg body weight) subcutaneously once a week for four weeks. Group 3 received irinotecan (100 mg/kg body weight) intravenously once a week for four weeks with 1,2-dimethyl hydrazine. Groups 4 to 6 were given a daily oral dose of 50, 100, 200 mg/kg body weight of kaempferol with 1,2-dimethyl hydrazine. The total study period was 16 weeks. Kaempferol supplementation lowered 1,2-dimethyl hydrazine induced erythrocyte lysate and liver thiobarbituric acid reactive substances level and rejuvenated anti oxidant enzymes catalase, super oxide dismutase and glutathione peroxidase. The recovery of enzyme status was maximum at the dose of 200 mg/kg body weight and was comparable to irinotecan. Our study reveals that kaempferol could be safely used as a chemopreventive agent in colorectal cancer.

  7. Sensitive amperometric determination of hydrazine using a carbon paste electrode modified with silver-doped zeolite L nanoparticles

    Indian Academy of Sciences (India)

    NEDA SALEK GILANI; SEYED NASER AZIZI; SHAHRAM GHASEMI

    2017-02-01

    Silver-loaded nanozeolite-L-modified carbon paste electrode (Ag/L–CPE) was used as a novel sensing platform for enhanced electrocatalytic oxidation and determination of hydrazine. Zeolite L nanoparticles were synthesized via hydrothermal approach and then characterized using various techniques such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), scanning electronic microscopy (SEM) and Brunauer–Emmett–Teller (BET). Silver-exchanged nanozeolite L (Ag/L) was prepared and mixed with carbon paste to prepare the modified electrode. Cyclic voltammetry studies revealed the high performance of Ag/L–CPE for electrocatalytic oxidation of hydrazine. Two linear ranges were detected in the amperometric detection of hydrazine. The first range was from10 $\\mu$M to 0.4 mM with sensitivity of 103.13 $\\mu$A mM$^{−1}$ and the second one was from 0.4 to 4mM with sensitivity of 58.131 $\\mu$A mM$^{−1}$. The response time and detection limit ($S/N = 3$) of this sensor were determined to be 2 s and 1.5 $\\mu$M, respectively. The unique porous structure of nanozeolite L offers a promising catalyst support candidate for efficient electrochemical sensing of hydrazine. The sensor exhibited appreciable repeatability, reproducibility and stability, and was able to detect hydrazine in the presence of even 500-fold excess concentrations of interfering species. Also, the sensor was used to determine hydrazine concentration in water samples with satisfactory results.

  8. The development of a non-cryogenic nitrogen/oxygen supply system. [using hydrazine/water electrolysis

    Science.gov (United States)

    Greenough, B. M.; Mahan, R. E.

    1974-01-01

    A hydrazine/water electrolysis process system module design was fabricated and tested to demonstrate component and module performance. This module is capable of providing both the metabolic oxygen for crew needs and the oxygen and nitrogen for spacecraft leak makeup. The component designs evolved through previous R and D efforts, and were fabricated and tested individually and then were assembled into a complete module which was successfully tested for 1000 hours to demonstrate integration of the individual components. A survey was made of hydrazine sensor technology and a cell math model was derived.

  9. Ultrathin willow-like CuO nanoflakes as an efficient catalyst for electro-oxidation of hydrazine

    Science.gov (United States)

    Ma, Yuanyuan; Li, Hao; Wang, Rongfang; Wang, Hui; Lv, Weizhong; Ji, Shan

    2015-09-01

    In this paper, preparation of ultrathin willow-like CuO nanoflakes via a one-step process was reported. X-ray diffraction pattern showed the formation of monoclinic CuO crystal, which was also confirmed by result of high resolution transmission electron microscopy. Scanning electron microscopy showed that ultrathin willow-like CuO nanoflakes were formed. Catalytic testing indicated that the ultrathin willow-like CuO nanoflakes exhibited high electrocatalytic activity and durability toward the electro-oxidation of hydrazine in alkaline medium. The results suggested that the as-prepared CuO nanoflakes were potential electrode materials for hydrazine fuel cell.

  10. Meiotic changes in Vicia faba L. subsequent to treatments of hydrazine hydrate and maleic hydrazide

    Directory of Open Access Journals (Sweden)

    Shaheen Husain

    2013-01-01

    Full Text Available Assessing the impact of mutagens for creating variations in crops like faba bean (Vicia faba L. is an important criterion in the contemporary world where food insecurity and malnutrition is alarming at the doors of various nations. Impact of two chemical mutagens viz. hydrazine hydrate (HZ and maleic hydrazide (MH on the two varieties (NDF-1 and HB-405 of Vicia faba were analysed in terms of meiotic behavior and pollen sterility. Since there are not enough data about the effect of these mutagens on the chromosomal behaviors of Vicia faba, this study presents the role of hydrazine hydrate and maleic hydrazide as well as various types of chromosomal aberrations in crop improvement. The lower concentration of mutagens showed less pollen sterility compared to the higher concentrations. Manipulation of plant structural component to induce desirable alternations provides valuable material for the breeders and could be used favorably for increasing mutation rate and obtaining a desirable spectrum of mutation in faba beans based on preliminary studies of cell division.

  11. Crystal structures of nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper and chloro-(2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) copper

    Energy Technology Data Exchange (ETDEWEB)

    Chumakov, Yu. M. [Academy of Sciences of Moldova, Institute of Applied Physics (Moldova, Republic of); Paholnitcaia, A. Yu. [State University of Moldova (Moldova, Republic of); Petrenko, P. A. [Academy of Sciences of Moldova, Institute of Applied Physics (Moldova, Republic of); Tsapkov, V. I., E-mail: vtsapkov@gmail.com [State University of Moldova (Moldova, Republic of); Poirier, D. [Centre Hospitalier Universitaire de Quebec (Canada); Gulea, A. P. [State University of Moldova (Moldova, Republic of)

    2015-01-15

    Two crystal modifications of nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper (I and II) and two modifications of chloro-(2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) copper (III and IV) have been synthesized and studied by X-ray diffraction. In structures I and II, the copper atoms coordinate a monodeprotonated molecule of the organic ligand, nitrate ions, and a water molecule. In crystals of I, the complexes are monomeric, whereas complexes II are linked via nitrate ions to form polymeric chains. In both structures the coordination polyhedron of the copper atom can be described as a distorted tetragonal bipyramid—(4 + 1 + 1) in I and (4 + 2) in II. These coordination polyherdra have different compositions. In structures III and IV, the metal atoms coordinate a monodeprotonated (2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazole molecule and chloride ions. In III the complex-forming ion has square-planar coordination geometry, whereas structure IV consists of centrosymmetric dimers with two bridging chlorine atoms. It was found that nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper possesses antitumor activity.

  12. Sol-gel process preparation and evaluation of the analytical performances of an hydrazine specific chemical sensor; Preparation par procede sol-gel et evaluation des performances analytiques d`un capteur chimique specifique de l`hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Gojon, C

    1996-12-01

    The realisation of optical fibers active chemical collector to analyze hydrazine in line, in the spent fuel reprocessing process is the subject of this work. The p.dimethyl-amino-benzaldehyde has been chosen as reagent for its chemical and optical properties. 186 refs.

  13. Crystal structures of nitrato-{2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo}aquacopper and chloro-{2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo}copper

    Science.gov (United States)

    Chumakov, Yu. M.; Paholnitcaia, A. Yu.; Petrenko, P. A.; Tsapkov, V. I.; Poirier, D.; Gulea, A. P.

    2015-01-01

    Two crystal modifications of nitrato-{2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo}aquacopper ( I and II) and two modifications of chloro-{2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo}copper ( III and IV) have been synthesized and studied by X-ray diffraction. In structures I and II, the copper atoms coordinate a monodeprotonated molecule of the organic ligand, nitrate ions, and a water molecule. In crystals of I, the complexes are monomeric, whereas complexes II are linked via nitrate ions to form polymeric chains. In both structures the coordination polyhedron of the copper atom can be described as a distorted tetragonal bipyramid—(4 + 1 + 1) in I and (4 + 2) in II. These coordination polyherdra have different compositions. In structures III and IV, the metal atoms coordinate a monodeprotonated {2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazole molecule and chloride ions. In III the complex-forming ion has square-planar coordination geometry, whereas structure IV consists of centrosymmetric dimers with two bridging chlorine atoms. It was found that nitrato-{2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo}aquacopper possesses antitumor activity.

  14. A 50 cc Two-Stroke DI Compression Ignition Engine Fuelled by DME

    DEFF Research Database (Denmark)

    Hansen, Kim Rene; Nielsen, Claus Suldrup; Sorenson, Spencer C

    2008-01-01

    The low auto-ignition temperature, rapid evaporation and high cetane number of dimethyl ether (DME) enables the use of low-pressure direct injection in compression ignition engines, thus potentially bringing the cost of the injection system down. This in turn holds the promise of bringing CI effi...

  15. Adsorption of hydrazine on the perfect and defective copper (111) surface: A dispersion-corrected DFT study

    NARCIS (Netherlands)

    Tafreshi, Saeedeh S.; Roldan, Alberto; Dzade, Nelson Y.; de Leeuw, Nora H.

    2014-01-01

    We have investigated the adsorption of hydrazine (N2H4) on perfect and defect-containing copper (111) surfaces by first-principles calculations. The long-range interactions are included in the geometry optimization through the application of the generalised gradient approximation with dispersion cor

  16. In situ synthesis of ceria nanoparticles in the ordered mesoporous carbon as a novel electrochemical sensor for the determination of hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yue [College of Chemistry, Nankai University, 94 WeiJin Road, Tianjin 300071 (China); Li, Yijun, E-mail: yijunli@nankai.edu.cn [Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071 (China); College of Chemistry, Nankai University, 94 WeiJin Road, Tianjin 300071 (China); He, Xiwen [College of Chemistry, Nankai University, 94 WeiJin Road, Tianjin 300071 (China)

    2014-03-01

    Highlights: • CeO{sub 2}–OMC composites were prepared via a hydrothermal method. • CeO{sub 2}–OMC had electrocatalytic ability to oxidation of hydrazine. • The sensor had high sensitivity, excellent stability and reproducibility. • The sensor was successfully employed to detect hydrazine in real water samples. - Abstract: A novel ceria (CeO{sub 2})–ordered mesoporous carbon (OMC) modified electrode for the sensitive amperometric determination of hydrazine was reported. CeO{sub 2}–OMC composites were synthesized via a hydrothermal method at a relatively low temperature (180 °C) and characterized by scanning electron microscopy (SEM), transmission electron microcopy (TEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The CeO{sub 2}–OMC modified glassy carbon electrode was characterized by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) and indicated good electrocatalytic effect to the oxidation of hydrazine. Under the optimized conditions, the present sensor could be used to measure hydrazine in wide linear range from 40 nM to 192 μM (R{sup 2} = 0.999) with a low detection limit of 12 nM (S/N = 3). Additionally, the sensor has been successfully applied to detect hydrazine in real water samples and the recoveries were between 98.2% and 105.6%. Eventually, the sensor exhibited an excellent stability and reproducibility as a promising method for determination of hydrazine.

  17. SPARC fast reactor design : Design of two passively safe metal-fuelled sodium-cooled pool-type small modular fast reactors with Autonomous Reactivity Control

    OpenAIRE

    Lindström, Tobias

    2015-01-01

    In this master thesis a small modular sodium-cooled metal-fuelled pool-type fast reactor design, called SPARC - Safe and Passive with Autonomous Reactivity control, has been designed. The long term reactivity changes in the SPARC are managed by implementation of the the Autonomous Reactivity Control (ARC) system, which is the novelty of the design. The overall design is mainly based on the Integral Fast Reactor project (IFR), which experimentally demonstrated the passive safety characteristic...

  18. Contrasting H-mode behaviour with deuterium fuelling and nitrogen seeding in the all-carbon and metallic versions of JET

    CERN Document Server

    Maddison, G P; Alper, B; Arnoux, G; Balboa, I; Beurskens, M N A; Boboc, A; Brezinsek, S; Brix, M; Clever, M; Coelho, R; Coenen, J W; Coffey, I; Belo, P C da Silva Aresta; Devaux, S; Devynck, P; Eich, T; Felton, R C; Flanagan, J; Frassinetti, L; Garzotti, L; Groth, M; Jachmich, S; Järvinen, A; Joffrin, E; Kempenaars, M A H; Kruezi, U; Lawson, K D; Lehnen, M; Leyland, M J; Liu, Y; Lomas, P J; Lowry, C G; Marsen, S; Matthews, G F; McCormick, G K; Meigs, A G; Morris, A W; Neu, R; Nunes, I M; Oberkofler, M; Rimini, F G; Saarelma, S; Sieglin, B; Sips, A C C; Sirinelli, A; Stamp, M F; van Rooij, G J; Ward, D J; Wischmeier, M; contributors, JET EFDA

    2014-01-01

    The former all-carbon wall on JET has been replaced with beryllium in the main torus and tungsten in the divertor to mimic the surface materials envisaged for ITER. Comparisons are presented between Type I H-mode characteristics in each design by examining respective scans over deuterium fuelling and impurity seeding, required to ameliorate exhaust loads both in JET at full capability and in ITER.

  19. Fuelling the future: microbial engineering for the production of sustainable biofuels.

    Science.gov (United States)

    Liao, James C; Mi, Luo; Pontrelli, Sammy; Luo, Shanshan

    2016-04-01

    Global climate change linked to the accumulation of greenhouse gases has caused concerns regarding the use of fossil fuels as the major energy source. To mitigate climate change while keeping energy supply sustainable, one solution is to rely on the ability of microorganisms to use renewable resources for biofuel synthesis. In this Review, we discuss how microorganisms can be explored for the production of next-generation biofuels, based on the ability of bacteria and fungi to use lignocellulose; through direct CO2 conversion by microalgae; using lithoautotrophs driven by solar electricity; or through the capacity of microorganisms to use methane generated from landfill. Furthermore, we discuss how to direct these substrates to the biosynthetic pathways of various fuel compounds and how to optimize biofuel production by engineering fuel pathways and central metabolism.

  20. Natural gas fuelled vehicles, energetic and environmental problems; Il gas naturale in autotrazione, aspetti energetici ed ambientali

    Energy Technology Data Exchange (ETDEWEB)

    Ciancia, A.; Pede, G. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dipt.Energia

    1998-03-01

    The present report deals with the analysis and the presentation of the main problems concerning the introduction of the natural gas fuel for vehicles. The offer and demand side of the NGV market are analyzed, together with the presently available NG fuelled vehicles and the status of the technology for engines and on-board storage systems, with particular regard to the energetic and environmental performance of the system. Finally the NGV market development is presented, and the actors on the stage, showing the opportunities together with the possible obstacle to a wider diffusion of this technology. [Italiano] Il rapporto e` dedicato all`esposizione ed all`analisi delle principali tematiche afferenti all`introduzione del metano nel settore dell`autotrazione. Vengono quindi esaminati nell`ordine la situazione del mercato della domanda e dell`offerta di metano, le realizzazioni veicolari oggi disponibili, la tecnologia e le prestazioni dei motori alimentati a metano e quelle dei sistemi di accumulo a bordo, l`impatto ambientale di questi veicoli. Vengono infine trattati i temi dello sviluppo del mercato e degli attori di questo sviluppo, evidenziandone i possibili sbocchi insieme agli ostacoli che ne limitano la diffusione.

  1. Potential of renewable energy in large fossil-fuelled boilers; Potential erneuerbarer Energien in groesseren fossilen Feuerungen

    Energy Technology Data Exchange (ETDEWEB)

    Dettli, R.; Baur, M.; Philippen, D. [Econcept AG, Zuerich (Switzerland); Kernen, M. [Planair SA, La Sagne (Switzerland)

    2007-01-15

    This comprehensive final report for the Swiss Federal Office of Energy (SFOE) presents the findings of a project that examined large heat generation systems used in Switzerland for the supply of heating services to several buildings via small and large district heating systems. Focus is placed on those using fossil fuels and the potential of using combined heat and power plants and renewable forms of energy such as heat-pumps and boilers fired with wood-chippings. The study was also extended to other large-scale, fossil-fuelled heating installations. The report discusses the setting up of a data base, the assessment of the potentials for fuel substitution, the economic viability of wood-fired systems and heat-pumps and the analysis of various factors that can obstruct the use of systems employing renewable forms of energy. Around 20 owners of large installations were interviewed on the subject. Strategic planning, studies, putting to tender, realisation and operation aspects are reviewed.

  2. Combustion and Vibration Analysis of Idi- Diesel Engine Fuelled With Neat Preheated Jatropha Methyl Ester

    Directory of Open Access Journals (Sweden)

    Y.Ashok Kumar Reddy

    2014-03-01

    Full Text Available Experimentation is conducted on an IDI diesel engine and the results of combustion and vibration on IDI -Diesel engine fueled with the preheated Jatropha Methyl Ester (JME are presented. The Present research trend is to replace conventional diesel by renewable alternative fuels in view of fast depletion of petroleum reserves and to reduce the exhaust emissions from the engines without altering the basic design of the engine. Due to moderately higher viscosity effects, the direct use of biodiesel in C.I. engines is limited to 20% and the limitation is based on the NO emission also. In this work, the biodiesel is preheated using on line electronically controlled electrical preheating system before it enters into the injector. Experiments are conducted on a four stroke single cylinder IDI engine to find combustion and vibration characteristics of the engine with the preheated Jatropha Methyl Ester (JME heated to temperatures viz. 60,70,80,90 and 1000C. Normally thin oils due to heating may trigger fast burning leading to either detonation or knocking of the engine. This can be predicted by recording vibration on the cylinder head in different directions. The cylinder vibrations in the form of FFT and time waves have been analyzed to estimate the combustion propensity. Experiments are done using diesel, biodiesel and biodiesel at different preheated temperatures and for different engine loading conditions keeping the speed constant at 1500 rpm. Biodiesel preheated to 600C proved encouraging in all respects.

  3. Liquid phase synthesis: preparation of co microspheres by hydrazine reducing method

    Science.gov (United States)

    Deng, Y.; Lu, Z. Q.; Xie, F.; Liang, H.; Wang, Y. J.; Du, X. H.

    2017-01-01

    The study synthesizes Co microspheres with perfect spherical shape by use hydrazine hydrate as reducing agent to reduce CoCl2 in alkaline conditions at room temperature, the influence of NaOH addition amount on crystal morphology and structure of cobalt particle were studied. The results show that, under the condition of concentration of NaOH, 0.030g ml-1 and having ethylene glycol as solvent, are the best choice to synthesize Co microspheres, and the grain is smaller, suitable for industrial production. At the condition of less amount of NaOH, cobalt particle's surface is smooth spherical, and with the increase of NaOH, particles will deviate from the spherical morphology and the surface become rough. The first section in your paper

  4. A simple hydrazine based molecule for selective detection of Fluoride ion in DMSO

    Indian Academy of Sciences (India)

    ADDITI ROY CHOWDHURY; PRIYABRATA BANERJEE

    2017-04-01

    A newly synthesized hydrazine-functionalized Schiff base chemoreceptor [N¹N³−bis(4-cyanobenzylidene) isophthalahydrazide], NBCBIH has been prepared and successfully utilized for selective detection of Fluoride ion. Herein, NH and C=N-like functional units have been incorporated which providebetter colorimetric response compared to systems where such kind of units are absent. On exposure to F⁻, NBCBIH turns from almost colorless to yellow. The recognition is well-supported by UV-Vis, fluorescence and ¹H-NMR in DMSO. The fluorescence quenching is well-explained by photoinduced electron transfer mechanism (PET). The limit of detection of F− with NBCBIH is 0.7 × 10⁻⁴M.

  5. Theoretical Studies of Structure, Spectroscopy, and Properties of a New Hydrazine Derivative

    Directory of Open Access Journals (Sweden)

    Hajar Sahebalzamani

    2013-01-01

    Full Text Available We will report a combined experimental and theoretical study on molecular structure, vibrational spectra, and energies of (E-1-(2,4-dinitrophenyl-2-[(4-methylphenylmethylidene]hydrazine (1. The molecular geometry and vibrational frequencies and energies in the ground state are calculated by using HF and DFT levels of theory with 6-311G basis sets. The calculated HOMO and LUMO energies also confirm that charge transfer occurs within the molecule. The harmonic vibrational frequencies were calculated, and the scaled values have been compared with experimental FTIR and FT-Raman spectra. The observed and the calculated frequencies are found to be in good agreement. The experimental spectra also coincide satisfactorily with those of theoretically constructed bar-type spectrograms.

  6. Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine

    Directory of Open Access Journals (Sweden)

    Xingxing Wang

    2011-01-01

    Full Text Available Cubic copper hexacyanoferrate (CuHCF nanoparticles prepared via electrolytic deposition are presented with their morphology and crystalline structure characterized with SEM and XRD. The advantage of this methodology is that it allows the fabrication of uniform cubic nanoparticles with permeable structures onto the desired underlying electrode substrate. It was observed that the CuHCF film acts as a permeable membrane for cations such as K+, Na+, Li+, and NH4+ with a selection order of K+> Li+>NH4+> Na+. Furthermore, the analytical utility of these cubic-like CuHCF morphologies supported on a glassy carbon electrode was evaluated towards the electrochemical oxidation of hydrazine which was found to exhibit a linear response over the range 66 M to 17 mM with a detection limit corresponding to 16.5 M.

  7. Superior supercapacitor electrode material from hydrazine hydrate modified porous polyacrylonitrile fiber

    Science.gov (United States)

    Li, Ying; Lu, Chunxiang; Wang, Junzhong; Yan, Hua; Zhang, Shouchun

    2016-03-01

    A hierarchical porous carbon fiber with high nitrogen doping was fabricated for high-performance supercapacitor. For the purpose of high nitrogen retention, the porous polyacrylonitrile fiber was treated by hydrazine hydrate, and then underwent pre-oxidation, carbonization, and activation in sequence. The resulted material exhibited high nitrogen content of 7.82 at.%, large specific surface area of 1963.3m2 g-1, total pore volume of 1.523cm3 g-1, and the pores with size range of 1-4nm were account for 49.1%. Due to these features, the high reversible capacitance of 415F g-1 and the good performance in heavy load discharge were obtained. In addition, the amazing cyclability was observed after 10,000 circles without capacitance fading.

  8. Local charge transport properties of hydrazine reduced monolayer graphene oxide sheets prepared under pressure condition

    DEFF Research Database (Denmark)

    Ryuzaki, Sou; Meyer, Jakob Abild Stengaard; Petersen, Søren Vermehren

    2014-01-01

    Charge transport properties of chemically reduced graphene oxide (RGO) sheets prepared by treatment with hydrazine were examined using conductive atomic force microscopy. The current-voltage (I-V) characteristics of monolayer RGO sheets prepared under atmospheric pressure followed an exponentially...... increase due to 2D variable-range hopping conduction through small graphene domains in an RGO sheet containing defect regions of residual sp3carbon clusters bonded to oxygen groups, whereas RGO sheets prepared in a closed container under moderate pressure showed linear I-V characteristics...... with a conductivity of 267.2-537.5S/m. It was found that the chemical reduction under pressure results in larger graphene domains (sp2networks) in the RGO sheets when compared to that prepared under atmospheric pressure, indicating that the present reduction of GO sheets under the pressure is one of the effective...

  9. Template-free Synthesis of One-dimensional Cobalt Nanostructures by Hydrazine Reduction Route

    Directory of Open Access Journals (Sweden)

    Lan Tianmin

    2011-01-01

    Full Text Available Abstract One-dimensional cobalt nanostructures with large aspect ratio up to 450 have been prepared via a template-free hydrazine reduction route under external magnetic field assistance. The morphology and properties of cobalt nanostructures were characterized by scanning electron microscopy, X-ray diffractometer, and vibrating sample magnetometer. The roles of the reaction conditions such as temperature, concentration, and pH value on morphology and magnetic properties of fabricated Co nanostructures were investigated. This work presents a simple, low-cost, environment-friendly, and large-scale production approach to fabricate one-dimensional magnetic Co materials. The resulting materials may have potential applications in nanodevice, catalytic agent, and magnetic recording.

  10. Chemosensing ability of hydroxynaphthylidene derivatives of hydrazine towards Cu2+: Experimental and computational studies

    Indian Academy of Sciences (India)

    Jayaraman Dessingiou; Jayshree K Khedkar; Chebrolu P Rao

    2014-07-01

    2-Hydroxynaphthylidene derivatives of hydrazine, namely L1, L2 and L3, were synthesized by going through two-step reactions and the products were characterized. The ion recognition properties of these receptors were studied using fluorescence and absorption spectroscopy. The receptors were found to be sensitive and selective towards Cu2+ in methanol solution among the 13 metal ions studied, namely Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, Na+, K+, Ca2+ and Mg2+, by exhibiting switch off fluorescence. The stoichiometry of the complexed species was found to be 2:1. The fluorescence quenching with Cu2+ is in the order of L1 > L2 > L3. These conjugates were also found to act as colorimetric sensors for Cu2+ in solution by exhibiting visual colour change. The 2:1 complex shows a centrosymmetric structure based on DFT computations.

  11. Precursor combustion synthesis of nanocrystalline cobalt substituted nickel zinc ferrites from hydrazinated mixed metal fumarates

    Energy Technology Data Exchange (ETDEWEB)

    Gawas, S.G.; Verenkar, V.M.S., E-mail: vmsv@rediffmail.com

    2015-04-10

    Highlights: • Convenient synthesis of hydrazinated mixed metal fumarates under nitrogen atmosphere. • Six hydrazine molecules in precursor provide high exothermicity for the decomposition. • Autocatalytic decomposition of precursors helps in ferritization at 410 °C. • Single domain-superparamagnetic particles of uniform size in the range of 15–30 nm. - Abstract: In present investigation, a systematic approach towards synthesis of nanocrystalline ferrites, Co{sub x}Ni{sub 0.6−x}Zn{sub 0.4}Fe{sub 2}O{sub 4} (x = 0.1 and 0.4) has been reported by room temperature decomposition of precursors, Co{sub x}Ni{sub 0.6−x}Zn{sub 0.4}Fe{sub 2} (C{sub 4}H{sub 2}O{sub 4}){sub 3}·6N{sub 2}H{sub 4} (x = 0.1 and 0.4). The precursor complexes were characterized by Fourier transform infrared spectroscopy (FTIR), chemical analysis and thermal studies like isothermal mass loss, total mass loss, thermogravimetry (TG), derivative of thermogravimetry (DTG) and differential thermal analysis (DTA). The TG–DTG–DTA patterns of both precursors reveal multistep decomposition with complete ferritization at 410 °C. The thermally decomposed products were characterized by X-ray diffractometry (XRD) for phase purity. The FT-IR spectroscopy studies of the same shows complete removal of all organic moieties from decomposed precursors. The nanophasic nature of synthesized ferrites was confirmed by transmission electron microscopy (TEM) analysis as well as from broadening of XRD peaks. The AC magnetization studies show the existence of single domain and superparamagnetic particles, which supports nanosize particles distribution in the ferrite system under study.

  12. Acoustic measurements for the combustion diagnosis of diesel engines fuelled with biodiesels

    Science.gov (United States)

    Zhen, Dong; Wang, Tie; Gu, Fengshou; Tesfa, Belachew; Ball, Andrew

    2013-05-01

    In this paper, an experimental investigation was carried out on the combustion process of a compression ignition (CI) engine running with biodiesel blends under steady state operating conditions. The effects of biodiesel on the combustion process and engine dynamics were analysed for non-intrusive combustion diagnosis based on a four-cylinder, four-stroke, direct injection and turbocharged diesel engine. The signals of vibration, acoustic and in-cylinder pressure were measured simultaneously to find their inter-connection for diagnostic feature extraction. It was found that the sound energy level increases with the increase of engine load and speed, and the sound characteristics are closely correlated with the variation of in-cylinder pressure and combustion process. The continuous wavelet transform (CWT) was employed to analyse the non-stationary nature of engine noise in a higher frequency range. Before the wavelet analysis, time synchronous average (TSA) was used to enhance the signal-to-noise ratio (SNR) of the acoustic signal by suppressing the components which are asynchronous. Based on the root mean square (RMS) values of CWT coefficients, the effects of biodiesel fractions and operating conditions (speed and load) on combustion process and engine dynamics were investigated. The result leads to the potential of airborne acoustic measurements and analysis for engine condition monitoring and fuel quality evaluation.

  13. Performance and emissions of an engine fuelled with a biodiesel fuel produced from animal fats

    Directory of Open Access Journals (Sweden)

    Taymaz Imdat

    2013-01-01

    Full Text Available Oil reserves which are located around the world are declining day by day, so new alternative energy sources must be invented for engines of internal combustion and compression ignition, so biodiesel that is an alternative fuel source for diesel engines and it is a renewable energy resource. Biodiesel is a fuel made from vegetable oils, animals’ fats and waste oils. In this study, physical and chemical properties of biodiesel were analyzed and matched to the diesel fuel. In the experimental study, biodiesel was made from animal fats and compared to diesel fuel. Its effects on engine performance and emissions are studied. A single-cylinder, four-stroke, direct injected diesel engine with air cooling system are used as test equipment in different cycles. After the experimental study, it is concluded that the reduction of the emissions of CO and HC as biodiesel has the advantage of emission output. Environmentalist property of biodiesel is the most important characteristic of it. But the sight of engine performance diesel fuel has more advantage to biodiesel fuel.

  14. The determination of optimum injection pressure in an engine fuelled with soybean biodiesel/diesel blend

    Directory of Open Access Journals (Sweden)

    Çelik Bahattin M.

    2014-01-01

    Full Text Available In this study, the optimum blend rate and injection pressure in a four-stroke, single cylinder, direct injection diesel engine using soybean methyl ester were investigated experimentally. The tests were conducted at two stages. Firstly, the engine was tested with diesel fuel, B25 (25% biodiesel+75% diesel fuel, B50, B75 and B100 fuels at full load and at a constant speed. According to the test results, it was determined that the most suitable fuel was B25 in terms of performance and emission. Secondly, the engine was tested at different loads with diesel fuel at original injection pressure and with B25 at different injection pressures (160, 180, 200, 220, 240 bar for comparison. It was determined from tests performed with B25 that the most suitable injection pressure in terms of performance and emissions was 220 bar. The specific fuel consumption and power values of the B25 were found to be nearly the same as those of diesel fuel at 220 bar injection pressure. In addition, HC, CO, and smoke emissions were reduced by about 33%, 9% and 20%, respectively. On the other hand, NOx emission increased by about 12%.

  15. Experimental investigations on a CRDI system assisted diesel engine fuelled with aluminium oxide nanoparticles blended biodiesel

    Directory of Open Access Journals (Sweden)

    C. Syed Aalam

    2015-09-01

    Full Text Available Experiments were conducted to determine engine performance, exhaust emissions and combustion characteristics of a single cylinder, common rail direct injection (CRDI system assisted diesel engine using diesel with 25 percentage of zizipus jujube methyl ester blended fuel (ZJME25. Along with this ZJME25 aluminium oxide nanoparticles were added as additive in mass fractions of 25 ppm (AONP 25 and 50 ppm (AONP 50 with the help of a mechanical Homogenizer and an ultrasonicator. It was observed that aluminium oxide nanoparticles blended fuel exhibits a significant reduction in specific fuel consumption and exhaust emissions at all operating loads. At the full load, the magnitude of HC and smoke emission for the ZJME25 before the addition of aluminium oxide nanoparticles was 13.459 g/kW h and 79 HSU, whereas it was 8.599 g/kW h and 49 HSU for the AONP 50 blended ZJME25 fuel respectively. The results also showed a considerable enhancement in brake thermal efficiency and heat release rate due to the influence of aluminium oxide nanoparticles addition in biodiesel–diesel blend.

  16. Engine performance and emission of compression ignition engine fuelled with emulsified biodiesel-water

    Science.gov (United States)

    Maawa, W. N.; Mamat, R.; Najafi, G.; Majeed Ali, O.; Aziz, A.

    2015-12-01

    The depletion of fossil fuel and environmental pollution has become world crucial issues in current era. Biodiesel-water emulsion is one of many possible approaches to reduce emissions. In this study, emulsified biodiesel with 4%, 6% and 8% of water contents were prepared to be used as fuel in a direct injection compression ignition engine. The performance indicator such as brake power, brake specific fuel consumption (BSFC) and brake thermal efficiency (BTE) and emissions such as NOx and particulate matter (PM) were investigated. The engine was set at constant speed of 2500 rpm and load from 20% to 60%. All the results were compared to B5 (blend of 95% petroleum diesel and 5% palm oil biodiesel) biodiesel. At low load, the BSFC decrease by 12.75% at 4% water ratio and decreased by 1.5% at 6% water ratio. However, the BSFC increases by 17.19% with increasing water ratio to 8% compared to B5. Furthermore, there was no significant decrease in brake power and BTE at 60% load. For 20% and 40% load there was some variance regarding to brake power and BTE. Significant reduction in NOx and PM emissions by 73.87% and 20.00% respectively were achieved with increasing water ratio to 8%. Overall, it is observed that the emulsified of biodiesel-water is an appropriate alternative fuel method to reduce emissions.

  17. A binary engine fuelling HD87643' s complex circumstellar environment, using AMBER/VLTI

    CERN Document Server

    Millour, Florentin; Borges-Fernandes, Marcelo; Meilland, Anthony; Mars, Gilbert; Benoist, C; Thiébaut, E; Stee, Philippe; Hofmann, K -H; Baron, Fabien; Young, John R; Bendjoya, Philippe; Carciofi, A C; De Souza, Armando Domiciano; Driebe, Thomas; Jankov, Slobodan; Kervella, Pierre; Petrov, R G; Robbe-Dubois, Sylvie; Vakili, Farrokh; Waters, L B F M; Weigelt, Gerd

    2009-01-01

    Context. The star HD 87643, exhibiting the ?B[e] phenomenon?, has one of the most extreme infrared excesses for this object class. It harbours a large amount of both hot and cold dust, and is surrounded by an extended re?ection nebula. Aims. One of our major goals was to investigate the presence of a companion in HD87643. In addition, the presence of close dusty material was tested through a combination of multi-wavelength high spatial resolution observations. Methods. We observed HD 87643 with high spatial resolution techniques, using the near-IR AMBER/VLTI interferometer with baselines ranging from 60 m to 130 m and the mid-IR MIDI/VLTI interferometer with baselines ranging from 25 m to 65 m. These observations are complemented by NACO/VLT adaptive-optics-corrected images in the K and L-bands, ESO-2.2m optical Wide-Field Imager large-scale images in the B, V and R-bands, Results. We report the direct detection of a companion to HD 87643 by means of image synthesis using the AMBER/VLTI instrument. The presen...

  18. Performance analysis of a biodiesel fuelled diesel engine with the effect of alumina coated piston

    Directory of Open Access Journals (Sweden)

    Senthil Kumar Srinivasan

    2017-01-01

    Full Text Available Biodiesel is one of the best alternative fuels to Diesel engine among other sources due to having potential to reduce emissions. Biodiesel is a renewable, biodegradable and environment friendly fuel in nature. The advantages of biodiesel are lower exhaust gas emissions and its biodegradability and renewability compared with petroleum-based diesel fuel. The energy of the biodiesel can be released more efficiently with the concept of semi adiabatic (thermal barrier coated piston engine. The objective of this study is to investigate the performance and emission characteristics of a single cylinder direct injection Diesel engine using 25% biodiesel blend (rubber seed oil methyl ester as fuel with thermal barrier coated piston. Initially the piston crown was coated with alumina (Al2O3 of thickness of 300 micron (0.3 mm by plasma coating method. The results revealed that the brake thermal efficiency was increased by 4% and brake specific fuel consumption was decreased by 9% for B25 with coated piston compared to un-coated piston with diesel. The smoke, CO, and HC emissions were also decreased for B25 blend with coated piston compared with the uncoated piton engine. The combustion characteristics such as peak pressure, maximum rate of pressure rise, and heat release rate were increased and the ignition delay was decreased for B25 blend for the coated piston compared with diesel fuel.

  19. Emissions Characteristics of Small Diesel Engine Fuelled by Waste Cooking Oil

    Directory of Open Access Journals (Sweden)

    Khalid Amir

    2014-07-01

    Full Text Available Biodiesel is an alternative, decomposable and biological-processed fuel that has similar characteristics with mineral diesel which can be used directly into diesel engines. However, biodiesel has oxygenated, more density and viscosity compared to mineral diesel. Despite years of improvement attempts, the key issue in using waste cooking oil-based fuels is oxidation stability, stoichiometric point, bio-fuel composition, antioxidants on the degradation and much oxygen with comparing to diesel gas oil. Thus, the improvement of emission exhausted from diesel engines fueled by biodiesel derived from waste cooking oil (WCO is urgently required to meet the future stringent emission regulations. The purpose of this research is to investigate the influences of WCO blended fuel and combustion reliability in small engine on the combustion characteristics and exhaust emissions. The engine speed was varied from 1500-2500 rpm and WCO blending ratio from 5-15 vol% (W5-W15. Increased blends of WCO ratio is found to influences to the combustion process, resulting in decreased the HC emissions and also other exhaust emission element. The improvement of combustion process is expected to be strongly influenced by oxygenated fuel in biodiesel content.

  20. Medical Radioisotope Production in a Power-Flattened ADS Fuelled with Uranium and Plutonium Dioxides

    Directory of Open Access Journals (Sweden)

    Gizem Bakır

    2016-01-01

    Full Text Available This study presents the medical radioisotope production performance of a conceptual accelerator driven system (ADS. Lead-bismuth eutectic (LBE is selected as target material. The subcritical fuel core is conceptually divided into ten equidistant subzones. The ceramic (natural U, PuO2 fuel mixture and the materials used for radioisotope production (copper, gold, cobalt, holmium, rhenium, thulium, mercury, palladium, thallium, molybdenum, and yttrium are separately prepared as cylindrical rods cladded with carbon/carbon composite (C/C and these rods are located in the subzones. In order to obtain the flattened power density, percentages of PuO2 in the mixture of UO2 and PuO2 in the subzones are adjusted in radial direction of the fuel zone. Time-dependent calculations are performed at 1000 MW thermal fission power (Pth for one hour using the BURN card. The neutronic results show that the investigated ADS has a high neutronic capability, in terms of medical radioisotope productions, spent fuel transmutation and energy multiplication. Moreover, a good quasiuniform power density is achieved in each material case. The peak-to-average fission power density ratio is in the range of 1.02–1.28.

  1. AQUEOUS N-HETEROCYCLIZATION OF PRIMARY AMINES AND HYDRAZINES WITH DIHALIDES: MICROWAVE-ASSISTED SYNTHESES OF N-AZACYCLOALKANES, ISOINDOLE, PYRAZOLE, PYRAZOLIDINE AND PHTHALAZINE DERIVATIVES

    Science.gov (United States)

    The synthesis of nitrogen-containing heterocycles from alkyl dihalides (ditosylates) and primary amines and hydrazines via a simple and efficient cyclocondensation in alkaline aqueous medium that occurs under microwave irradiation is described. This improved greener synthetic met...

  2. EXPERIMENTAL DETERMINATION OF BRAKE THERMAL EFFICIENCY AND BRAKE SPECIFIC FUEL CONSUMPTION OF DIESEL ENGINE FUELLED WITH BIO-DIESEL

    Directory of Open Access Journals (Sweden)

    M. SHIVA SHANKAR

    2010-10-01

    Full Text Available The rapid depletion in world petroleum reserves and uncertainty in petroleum supply due to political and economical reasons, as well as, the sharp escalations in the petroleum prices have stimulated the search for alternatives to petroleum fuels. The situation is very grave in developing countries like India which imports 70% of the required fuel, spending 30% of her total foreign exchange earnings on oil imports. Petroleum fuels are being consumed by agriculture and transport sector for which diesel engine happens to be the prime mover. Diesel fuelled vehicles discharge significant amount of pollutants like CO, HC, NOx, soot, lead compounds which are harmful to the universe. Though there are wide varieties of alternative fuels available, the research has not yet provided the right renewable fuel to replace diesel. Vegetable oils due to their properties being close to diesel fuel may be a promising alternative for its use in diesel engines. The high viscosity and low volatility are the major drawbacks of the use of vegetable oils in diesel engines. India is the second largest cotton producing country in the world today. The cotton seeds are available in India at cheaper price. Experiments were conducted on 5.2 BHP single cylinder four stroke water-cooled variable compression diesel engine. Methyl ester of cottonseed oil is blended with the commercially available Xtramile diesel. Cottonseed oil methyl ester (CSOME is blended in four different compositions varying from 10% to 40% in steps of 10 vol%. Using these four blends and Xtramile diesel brake thermal efficiency (BTE and brake specific fuel consumption (BSFC are determined at 17.5 compression ratio.

  3. Composition and comparative toxicity of particulate matter emitted from a diesel and biodiesel fuelled CRDI engine

    Science.gov (United States)

    Gangwar, Jitendra N.; Gupta, Tarun; Agarwal, Avinash K.

    2012-01-01

    There is a global concern about adverse health effects of particulate matter (PM) originating from diesel engine exhaust. In the current study, parametric investigations were carried out using a CRDI (Common Rail Direct Injection) diesel engine operated at different loads at two different engine speeds (1800 and 2400 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. A partial flow dilution tunnel was employed to collect and measure the mass of the primary particulates from diesel and biodiesel blend collected on a 47 mm quartz substrate. The collected PM (particulate matter) was subjected to chemical analyses in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICP-OES). For both diesel and biodiesel, BSOF results showed decreasing levels with increasing engine load. B20 showed higher BSOF as compared to those measured with diesel. The concentration of different trace metals analyzed also showed decreasing trends with increasing engine loads. In addition, real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs) were carried out on the primary engine exhaust coming out of the partial flow dilution tunnel. Analysis of OC/EC data suggested that the ratio of OC to EC decreases with corresponding increase in engine load for both fuels. A peak in PAH concentration was observed at 60% engine load at 1800 rpm and 20% engine load at 2400 rpm engine speeds almost identical for both kinds of fuels. Comparison of chemical components of PM emitted from this CRDI engine provides new insight in terms of PM toxicity for B20 vis-a-vis diesel.

  4. Nanostructured SnO{sub 2} encapsulated guar-gum hybrid nanocomposites for electrocatalytic determination of hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Malik, Priya [Department of Applied Chemistry & Polymer Technology, Delhi Technological University, Shahbad Daulatpur, Main Bawana Road, Delhi 110042 (India); Srivastava, Manish [Department of Physics & Astrophysics, University of Delhi, Delhi 110007 (India); Verma, Ranjana [Solar Energy Material Laboratory, Department of Energy, Tezpur University, Tezpur, Assam 784 028 (India); Kumar, Manish [Department of Applied Chemistry & Polymer Technology, Delhi Technological University, Shahbad Daulatpur, Main Bawana Road, Delhi 110042 (India); Kumar, D., E-mail: dkumar@dce.ac.in [Department of Applied Chemistry & Polymer Technology, Delhi Technological University, Shahbad Daulatpur, Main Bawana Road, Delhi 110042 (India); Singh, Jay, E-mail: jay_singh143@yahoo.co.in [Department of Applied Chemistry & Polymer Technology, Delhi Technological University, Shahbad Daulatpur, Main Bawana Road, Delhi 110042 (India)

    2016-01-01

    The present article deals with synthesis of sol–gel derived tin dioxide (SnO{sub 2}) nanoparticles encapsulated in to guar gum (GG) biopolymer as the organic–inorganic hybrid materials for the determination of hydrazine. The organic–inorganic hybrid combines the perfunctory strength offered by the inorganic SnO{sub 2} nanoparticles with flexible binding sites provided by the organic biopolymer (GG) solution by the ultrasonication. The phase identification, crystalline size, surface morphology and optical properties of prepared SnO{sub 2} and SnO{sub 2}-GG nanocomposites has been investigated through FT-IR, XRD, SEM, AFM, TEM, UV–Vis, and PL techniques. The colloidal solution of SnO{sub 2} and GG is electrophoretically deposited (EPD) onto the indium tin-oxide (ITO) glass substrate and studied for the electrooxidation of hydrazine. Under the optimized experimental conditions, the linearity between the current response and the hydrazine concentration has been obtained in the range of 2–22 mM, with a low detection limit of 2.76 mM and a high sensitivity of 5.72 μA cm{sup −2}. Based on the linear increase in amperometric current, a sensitive hydrazine electrochemical sensor is constructed. The proposed SnO{sub 2}-GG/ITO electrode shows a good response time (35 s), reproducibility, and long-term stability. The obtained results suggest that SnO{sub 2}-GG nanocomposites electrode provides a favorable sensing platform for the electrochemical studies. In addition, the cyclic voltammetry (CV) studies are used to evaluate the kinetic parameters. - Graphical abstract: Synthesis of sol–gel derived tin dioxide (SnO{sub 2}) nanoparticles grafted in to gaur gum (GG) organic–inorganic hybrid nanocomposite for determination of hydrazine (HZ). Under optimized experimental conditions, SnO{sub 2}-GG/ITO electrode shows, linearity 2–22 mM, and detection limit 2.769 mM with high sensitivity of 5.72 μA cm{sup −2}. The results clearly suggest that SnO{sub 2}-GG

  5. Restudy of the Ground Vibrational State of Hydrazine Using the Generalized IAM-like Treatment for the Amino-Wagging Tunneling Motion.

    Science.gov (United States)

    Pyka, Jan; Ohashi, Nobukimi

    2001-05-01

    The amino-wagging tunneling process in hydrazine was treated using the generalized IAM-like method developed by Hougen and Coudert, and Hamiltonian matrix elements were derived for each symmetry species in the combined group-theoretical and IAM-like treatment. Ground state microwave absorption transition data of hydrazine were least squares analyzed again in this treatment to determine axis switching angles for the amino-wagging tunneling process. Copyright 2001 Academic Press.

  6. Fuelling Insecurity? Sino-Myanmar Energy Cooperation and Human Security in Myanmar

    Science.gov (United States)

    Botel, Gabriel

    This thesis examines the relationship between energy, development and human security in Sino-Myanmar relations. Rapid economic growth and increased urbanisation have intensified China's industrial and domestic energy consumption, drastically increasing demand and overwhelming national supply capacities. Chinese foreign policy has responded by becoming more active in securing and protecting foreign energy resources and allowing Chinese companies more freedom and opportunities for investment abroad. Consequently, Chinese foreign investment and policies have become increasing sources of scrutiny and debate, typically focusing on their (presumed) intentions and the social, economic, environmental and political impacts they have on the rest of the world. Within this debate, a key issue has been China's engagement with so-called pariah states. China has frequently received substantial international criticism for its unconditional engagement with such countries, often seen as a geopolitical pursuit of strategic national (energy) interests, unconcerned with international opprobrium. In the case of Myanmar, traditional security analyses interpret this as, at best, undermining (Western) international norms and, at worst, posing a direct challenge to international security. However, traditional security analyses rely on state-centric concepts of security, and tend to over-simply Sino-Myanmar relations and the dynamics which inform it. Conversely, implications for human security are overlooked; this is in part because human security remains poorly defined and also because there are questions regarding its utility. However, human security is a critical tool in delineating between state, corporate and 'civilian' interests, and how these cleavages shape the security environment and potential for instability in the region. This thesis takes a closer look at some of the entrenched and changing security dynamics shaping this Sino-Myanmar energy cooperation, drawing on an extensive

  7. Spatially addressable chemoselective C-terminal ligation of an intein fusion protein from a complex mixture to a hydrazine-terminated surface.

    Science.gov (United States)

    Yang, Peng; Marinakos, Stella M; Chilkoti, Ashutosh

    2011-02-15

    Protein immobilization on surfaces is useful in many areas of research, including biological characterization, antibody purification, and clinical diagnostics. A critical limitation in the development of protein microarrays and heterogeneous protein-based assays is the enormous amount of work and associated costs in the purification of proteins prior to their immobilization onto a surface. Methods to address this problem would simplify the development of interfacial diagnostics that use a protein as the recognition element. Herein, we describe an approach for the facile, site-specific immobilization of proteins on a surface without any preprocessing or sample purification steps that ligates an intein fusion protein at its C-terminus by reaction with a hydrazine group presented by a surface. Furthermore, we demonstrate that this methodology can directly immobilize a protein directly from cell lysate onto a protein-resistant surface. This methodology is also compatible with soft lithography and inkjet printing so that one or more proteins can be patterned on a surface without the need for purification.

  8. Unregulated gaseous exhaust emission from modern ethanol fuelled light duty vehicles in cold ambient condition

    Science.gov (United States)

    Clairotte, M.; Adam, T. W.; Zardini, A. A.; Astorga, C.

    2011-12-01

    According to Directive 2003/30/EC and 2009/28/EC of the European Parliament and the Council, Member States should promote the use of biofuel. Consequently, all petrol and diesel used for transport purpose available on the market since the 1st of January 2011 must contain a reference value of 5.75% of renewable energy. Ethanol in gasoline could be a promising alternative to comply with this objective, and is actually available in higher proportion in Sweden and Brazil. In addition to a lower dependence on fossil fuel, it is well established that ethanol contributes to reduce air pollutant emissions during combustion (CO, THC), and presents a beneficial effect on the greenhouse gas emissions. However, these statements rely on numerous chassis dynamometer emission studies performed in warm condition (22°C), and very few emission data are available at cold ambient condition encountered in winter, particularly in the north of Europe. In this present study, the effects of ethanol (E75-E85) versus gasoline (E5) have been investigated at cold ambient temperature (-7°C). Experiments have been carried out in a chassis dynamometer at the Vehicle Emission Laboratory (VELA) of the European Commission's Joint Research Centre (JRC - Ispra, Italy). Emissions of modern passenger cars complying with the latest European standard (Euro4 and Euro5a) were tracked over the New European Driving Cycle (NEDC). Unregulated gaseous compounds like greenhouse gases (carbon dioxide, methane, nitrous oxide), and air quality related compounds (ammonia, formaldehyde, acetaldehyde) were monitored by an online Fourier Transformed Infra-Red spectrometer with 1 Hz acquisition frequency. In addition, a number of ozone precursors (carbonyls and volatile organic hydrocarbons) were collected in order to assess the ozone formation potential (OFP) of the exhaust. Results showed higher unregulated emissions at -7°C, regardless of the ethanol content in the fuel blend. Most of the emissions occurred during

  9. EXPERIMENTAL INVESTIGATIONS ON THE EFFECT OF HYDROGEN INDUCTION ON PERFORMANCE AND EMISSION BEHAVIOUR OF A SINGLE CYLINDER DIESEL ENGINE FUELLED WITH PALM OIL METHYL ESTER AND ITS BLEND WITH DIESEL

    Directory of Open Access Journals (Sweden)

    BOOPATHI D.

    2017-07-01

    Full Text Available Internal combustion engines are an integral part of our daily lives, especially in the agricultural and transportation sector. With depleting fossil fuel and increasing environmental pollution, the researchers are foraying into alternate sources for fuelling the internal combustion engine. Vegetable oils derived from plant seeds is one such solution, but using them in unmodified diesel engine leads to reduced thermal efficiency and increased smoke emissions. Hydrogen if induced in small quantities in the air intake manifold can enhance the engine performance running on biodiesel. In this work, experiments were performed to evaluate the engine performance when hydrogen was inducted in small quantities and blends of esterified palm oil and diesel was injected as pilot fuel in the conventional manner. Tests were performed on a single cylinder, 4 - stroke, water cooled, direct injection diesel engine running at constant speed of 1500 rpm under variable load conditions and varying hydrogen flow. At full load for 75D25POME (a blend of 75% diesel and 25% palm oil methyl ester by volume, the results indicated an increase in brake thermal efficiency from 29.75% with zero hydrogen flow to a maximum of 30.17% at 5lpm hydrogen flow rate. HC emission reduced from 34 to 31.5 ppm, by volume at maximum load. Whereas, CO emission reduced from 0.09 to 0.045 % by volume at maximum load. Due to higher combustion rates with hydrogen induction, NOx emission increased from 756 to 926 ppm, at maximum load.

  10. Light-controlled propulsion, aggregation and separation of water-fuelled TiO2/Pt Janus submicromotors and their ``on-the-fly'' photocatalytic activities

    Science.gov (United States)

    Mou, Fangzhi; Kong, Lei; Chen, Chuanrui; Chen, Zhihong; Xu, Leilei; Guan, Jianguo

    2016-02-01

    In this work, water-fuelled TiO2/Pt Janus submicromotors with light-controlled motions have been developed by utilizing the asymmetrical photocatalytic water redox reaction over TiO2/Pt Janus submicrospheres under UV irradiation. The motion state, speed, aggregation and separation behaviors of the TiO2/Pt Janus submicromotor can be reversibly, wirelessly and remotely controlled at will by regulating the ``on/off'' switch, intensity and pulsed/continuous irradiation mode of UV light. The motion of the water-fuelled TiO2/Pt Janus submicromotor is governed by light-induced self-electrophoresis under the local electrical field generated by the asymmetrical water oxidation and reduction reactions on its surface. The TiO2/Pt Janus submicromotors can interact with each other through the light-switchable electrostatic forces, and hence continuous and pulsed UV irradiation can make the TiO2/Pt Janus submicromotors aggregate and separate at will, respectively. Because of the enhanced mass exchange between the environment and active submicromotors, the separated TiO2/Pt Janus submicromotors powered by the pulsed UV irradiation show a much higher activity for the photocatalytic degradation of the organic dye than the aggregated TiO2/Pt submicromotors. The water-fuelled TiO2/Pt Janus submicromotors developed here have some outstanding advantages as ``swimming'' photocatalysts for organic pollutant remediation in the macro or microenvironment (microchannels and microwells in microchips) because of their small size, long-term stability, wirelessly controllable motion behaviors and long life span.In this work, water-fuelled TiO2/Pt Janus submicromotors with light-controlled motions have been developed by utilizing the asymmetrical photocatalytic water redox reaction over TiO2/Pt Janus submicrospheres under UV irradiation. The motion state, speed, aggregation and separation behaviors of the TiO2/Pt Janus submicromotor can be reversibly, wirelessly and remotely controlled at will by

  11. Use of activated enol ethers in the synthesis of pyrazoles: reactions with hydrazine and a study of pyrazole tautomerism

    Directory of Open Access Journals (Sweden)

    Denisa Tarabová

    2014-04-01

    Full Text Available Activated enol ethers derived from esters or the dinitrile of malonic acid, or from pentane-2,4-dione were treated with hydrazine hydrate. The structures of the obtained products – pyrazoles 5 – were studied with a focus on tautomerism and supramolecular structure. A reverse addition of the reagents led to the isolation of two novel products, namely bis-enehydrazines 6 with an unsymmetrical arrangement of the formally equivalent subunits.

  12. Effects of Methanol, Methylamine, Formate, N, N-Dimethylhydroxylamine and Formaldehyde on Determining the Methyl Hydrazine Concentration Using Paradime Thylaminobenzaldehyde

    Institute of Scientific and Technical Information of China (English)

    LI; Chuan-bo; CAO; Zhi; BIAN; Xiao-yan; XIAN; Liang; YAN; Tai-hong; ZHENG; Wei-fang

    2012-01-01

    <正>To make sure the feasibility of determining the concentrations of methyl hydrazine (MMH) in 1BP and 2BP using paradime thylaminobenzaldehyde. Researches were done to measure the effects of methanol, methylamine, formate, N, N-dimethylhydroxylamine (DMHAN) and formaldehyde on the method. Though paradime thylaminobenzaldehyde took place condensation reaction with methanol and methylamine, the resultant’s absorbance was zero in 470 nm. So methanol and methylamine did not affect the method of determing the MMH by paradime thylaminobenzaldehyde.

  13. Three-dimensionally grown thorn-like Cu nanowire arrays by fully electrochemical nanoengineering for highly enhanced hydrazine oxidation

    Science.gov (United States)

    Huang, Jianfei; Zhao, Shunan; Chen, Wei; Zhou, Ying; Yang, Xiaoling; Zhu, Yihua; Li, Chunzhong

    2016-03-01

    This communication reports fully electrochemical nanoengineering toward three-dimensionally grown thorn-like Cu nanowire arrays (CNWAs) as a highly efficient and durable electrocatalyst for hydrazine oxidation. Characterized by substantial negative shifting of the onset potential and an enlarged catalytic current density, the CNWAs afforded greatly enhanced hydrazine oxidation activity, even transcending that of the Pt/C catalyst at a higher reaction rate. The parameters of the electrochemical engineering and metallization methods were found to be essentially influential on the microstructure, and thus the electrocatalytic activity of the CNWAs. The present work typifies a flexible and expandible route toward integrated electrodes of metallic 1D nanostructures which are of interest in advancing the performance of cutting-edge electrochemical applications.This communication reports fully electrochemical nanoengineering toward three-dimensionally grown thorn-like Cu nanowire arrays (CNWAs) as a highly efficient and durable electrocatalyst for hydrazine oxidation. Characterized by substantial negative shifting of the onset potential and an enlarged catalytic current density, the CNWAs afforded greatly enhanced hydrazine oxidation activity, even transcending that of the Pt/C catalyst at a higher reaction rate. The parameters of the electrochemical engineering and metallization methods were found to be essentially influential on the microstructure, and thus the electrocatalytic activity of the CNWAs. The present work typifies a flexible and expandible route toward integrated electrodes of metallic 1D nanostructures which are of interest in advancing the performance of cutting-edge electrochemical applications. Electronic supplementary information (ESI) available: Experimental details, additional figures and table. See DOI: 10.1039/c5nr06512g

  14. N'-[5-(4-Nitro-phen-yl)furan-2-yl-methyl-idene]-N,N-diphenyl-hydrazine.

    Science.gov (United States)

    Mendoza, Angel; Cabrera-Vivas, Blanca M; Meléndrez-Luevano, Ruth; Pacheco-Álvarez, Teresa; Carranza, Vladimir

    2010-07-17

    The title compound, C(23)H(17)N(3)O(3), has an E configuration with respect to the C=N bond. The dihedral angle between the two phenyl rings bonded to the hydrazine group is 86.45 (13)°. The furan ring makes dihedral angles of 3.4 (2) and 7.06 (13)°, respectively, with the methyl-idenehydrazine C=N-N plane and the benzene ring.

  15. Reduction of Sulphur-containing Aromatic Nitro Compounds with Hydrazine Hydrate over Iron(Ⅲ) Oxide-MgO Catalyst

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Sulphur-containing aromatic amines were prepared efficiently in good to excellent yields by reduction of the corresponding sulphur-containing aromatic nitro compounds with hydrazine hydrate in the presence of iron(Ⅲ) oxide-MgO catalyst. The catalyst exhibited high activity and stability for the reduction of sulphur-containing aromatic nitro compounds. The yields of sulphur-containing aromatic amines were up to 91-99 % at 355 K after reduction for 1-4 h over this catalyst.

  16. Noble metal-free hydrazine fuel cell catalysts: EPOC effect in competing chemical and electrochemical reaction pathways.

    Science.gov (United States)

    Sanabria-Chinchilla, Jean; Asazawa, Koichiro; Sakamoto, Tomokazu; Yamada, Koji; Tanaka, Hirohisa; Strasser, Peter

    2011-04-13

    We report the discovery of a highly active Ni-Co alloy electrocatalyst for the oxidation of hydrazine (N(2)H(4)) and provide evidence for competing electrochemical (faradaic) and chemical (nonfaradaic) reaction pathways. The electrochemical conversion of hydrazine on catalytic surfaces in fuel cells is of great scientific and technological interest, because it offers multiple redox states, complex reaction pathways, and significantly more favorable energy and power densities compared to hydrogen fuel. Structure-reactivity relations of a Ni(60)Co(40) alloy electrocatalyst are presented with a 6-fold increase in catalytic N(2)H(4) oxidation activity over today's benchmark catalysts. We further study the mechanistic pathways of the catalytic N(2)H(4) conversion as function of the applied electrode potential using differentially pumped electrochemical mass spectrometry (DEMS). At positive overpotentials, N(2)H(4) is electrooxidized into nitrogen consuming hydroxide ions, which is the fuel cell-relevant faradaic reaction pathway. In parallel, N(2)H(4) decomposes chemically into molecular nitrogen and hydrogen over a broad range of electrode potentials. The electroless chemical decomposition rate was controlled by the electrode potential, suggesting a rare example of a liquid-phase electrochemical promotion effect of a chemical catalytic reaction ("EPOC"). The coexisting electrocatalytic (faradaic) and heterogeneous catalytic (electroless, nonfaradaic) reaction pathways have important implications for the efficiency of hydrazine fuel cells. © 2011 American Chemical Society

  17. Comparative studies on single-layer reduced graphene oxide films obtained by electrochemical reduction and hydrazine vapor reduction

    Science.gov (United States)

    Wang, Zhijuan; Wu, Shixin; Zhang, Juan; Chen, Peng; Yang, Guocheng; Zhou, Xiaozhu; Zhang, Qichun; Yan, Qingyu; Zhang, Hua

    2012-02-01

    The comparison between two kinds of single-layer reduced graphene oxide (rGO) sheets, obtained by reduction of graphene oxide (GO) with the electrochemical method and hydrazine vapor reduction, referred to as E-rGO and C-rGO, respectively, is systematically studied. Although there is no morphology difference between the E-rGO and C-rGO films adsorbed on solid substrates observed by AFM, the reduction process to obtain the E-rGO and C-rGO films is quite different. In the hydrazine vapor reduction, the nitrogen element is incorporated into the obtained C-rGO film, while no additional element is introduced to the E-rGO film during the electrochemical reduction. Moreover, Raman spectra show that the electrochemical method is more effective than the hydrazine vapor reduction method to reduce the GO films. In addition, E-rGO shows better electrocatalysis towards dopamine than does C-rGO. This study is helpful for researchers to understand these two different reduction methods and choose a suitable one to reduce GO based on their experimental requirements.

  18. Silver nanoparticles sensitized C60(Ag@C60) as efficient electrocatalysts for hydrazine oxidation: Implication for hydrogen generation reaction

    Science.gov (United States)

    Narwade, Shankar S.; Mulik, Balaji B.; Mali, Shivsharan M.; Sathe, Bhaskar R.

    2017-02-01

    Herein, we report the synthesis of silver nanoparticles (Ag NPs; 10 ± 0.5 nm) sensitized Fullerene (C60; 15 ±2 nm) nanocatalysts (Ag@C60) for the first time showing efficient electroatalytic activity for the oxidation of hydrazine demonstrating activity comparable to that of Pt in acidic, neutral and basic media. The performance is comparable with the best available electrocatalytic system and plays a vital role in the overall hydrogen generation reactions from hydrazine as a one of the fuel cell reaction. The materials are synthesized by a simple and scalable synthetic route involving acid functionalization of C60 followed by chemical reduction of Ag+ ions in ethylene glycol at high temperature. The distributation of Silver nanoparticles (Ag NPs) (morphological information) on C60, bonding, its crystal structure, along with activity towards hydrazine oxidation (electrocatalytic) is studied using TEM, XRD, UV-vis, XPS, FTIR and electrochemical (cyclic voltammetry) studies, respectively. The observed efficient electrocatalytic activity of the as-synthesized electrode is attributed to the co-operative response and associated structural defects due to their oxidative functionalization along with thier cooperative functioning at nanodimensions.

  19. Derivatization Ion Chromatography for the Determination of Monoethanolamine in Presence of Hydrazine in PHWR Steam-Water Circuits

    Directory of Open Access Journals (Sweden)

    Ayushi D.

    2011-01-01

    Full Text Available A simple, rapid and accurate method for the determination of monoethanolamine (MEA in PHWR steam-water circuits has been developed. MEA is added in the feed water to provide protection against corrosion while hydrazine is added to scavenge dissolved oxygen. The quantitative determination of MEA in presence of hydrazine was accomplished using derivatization ion chromatography with conductometric detection in nonsuppressed mode. A Metrosep cation 1-2 analytical column and a Metrosep cartridge were used for cation separation. A mixture of 4 mM tartaric acid, 20% acetone and 0.05 mM HNO3 was used as eluent. Acetone in the mobile phase leads to the formation of different derivatives with MEA and hydrazine. The interferences due Na+ and NH4 + were eliminated by adopting a simple pretreatment procedure employing OnGuard-H cartridge. The limit of detection limit of MEA was 0.1 μg mL−1 and the relative standard deviation was 2% for the overall method. The recovery of MEA added was in the range 95%–102%. The method was applied to the determination of MEA in steam generator water samples.

  20. Optimal design and operation of a syngas-fuelled SOFC micro CHP system for residential applications in different climate zones in China

    OpenAIRE

    Yang, Wenyuan; Zhao, Yingru; Liso, Vincenzo; Brandon, Nigel

    2014-01-01

    Fuel cell based micro-CHP systems are expected to be one of the most promising technologies for implementation in the residential sector. Since the design and operation of such CHP systems are greatly dependent upon the seasonal atmospheric conditions, it is important to evaluate their performance under difference climate conditions to ensure that it is well matched with the local heat-to-power ratio. The aim of this study is to investigate the optimal design and operation of a syngas-fuelled...

  1. Energetic and environmental balance of a natural gas fuelled low-capacity cogeneration system; Energetische und umwelttechnische Bilanz eines erdgasbetriebenen Klein-BHKW

    Energy Technology Data Exchange (ETDEWEB)

    Hentschel, D. [Hochschule fuer Technik, Wirtschaft und Kultur (F.H.), Leipzig (Germany). Lehrgebiet Produktionsplanung und -steuerung; Werner, C. [Technische Univ. Bergakademie, Freiberg (Germany). Inst. fuer Waermetechnik und Thermodynamik

    2002-03-01

    FH Leipzig University has been operating a natural gas fuelled cogeneration system since 1998. The performance of the system was tested in field experiments. The contribution presents the energy- and environment-related results. [German] Seit 1998 betreibt die Hochschule fuer Technik, Wirtschaft und Kultur Leipzig (FH) am Fachbereich Maschinen- und Energietechnik zu Lehr- und Forschungszwecken ein erdgasbetriebenes Blockheizkraftwerk (BHKW). Unter Beachtung wesentlicher energetischer und umwelttechnischer Aspekte ist das Betriebsverhalten des Gas-Otto-Motoren-BHKW anhand von Feldversuchen ermittelt worden. Im Folgenden erfolgt eine Verknuepfung der energetischen und umwelttechnischen Anlageneigenschaften. (orig.)

  2. Fuelling the Nigerian economy

    Energy Technology Data Exchange (ETDEWEB)

    Oseni, T.

    1987-05-01

    A special report on the achievements of the Nigerian National Petroleum Corp. credits the merger of the Nigerian National Oil Corp. and the Ministry of Petroleum Resources as a step which revolutionized the industry has had a positive impact on the economy. A national corporation with close links to OPEC, it was charged with all aspects, from exploring to marketing, of petroleum development. The author describes activities, including joint ventures, which have led to new production and refining facilities and the diversification of the industry into petrochemicals. The impact on end-use applications will be to produce consumer items and improve the balance of trade. Government regulation includes inspections and oversight of performance of all operations, including environmental standards.

  3. Thermal chemistry of hydrazine on clean and oxygen- and water-predosed Cu(110) single-crystal surfaces

    Science.gov (United States)

    Yao, Yunxi; Zaera, Francisco

    2016-08-01

    The chemistry of hydrazine on Cu(110) single-crystal surfaces was probed under ultrahigh vacuum (UHV) conditions by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). Survey TPD experiments identified molecular nitrogen and ammonia as the main desorbing products from thermal activation of the adsorbate, but small amounts of diazene and NH2· radicals were also detected. At saturation coverage, N2 production leads NH3 desorption by approximately 10 K (with TPD peaks at 350 K versus 360 K, respectively), indicating a preference for dehydrogenation over N-N bond scission steps, and additional nitrogen was seen at even lower temperatures (320 K) in experiments starting with even higher doses of hydrazine. On the other hand, the formation of NH3 and NH2·, which desorb in a wide range of temperatures between approximately 300 K and 700 K, dominates in experiments with low N2H4 doses, presumably because a stronger interaction of the N-N bond with the metal in the flat adsorption geometry expected at such low coverages. Dosing at room temperature seems to also facilitate the dissociative adsorption, albeit via dehydrogenation steps that lead to the subsequent production of more significant amounts of diazene and of molecular hydrogen (in addition to N2, NH3, and NH2·). Preadsorption of oxygen on the Cu(110) surface helps stabilize the hydrazine, increasing its desorption temperature and helping with the low-temperature (320 K) production of N2. Coadsorption of hydrazine with water leads to facile proton exchange, as indicated by the production of NH2D in TPD experiments with N2H4 + D2O. This isotope scrambling must occur at cryogenic temperatures because all water desorbs from the surface below 200 K and no other changes in surface chemistry are observed after that. The implications of all this chemistry to practical applications that may use hydrazine in surface reactions with copper, including its use as a reducing agent in atomic layer

  4. Determination of hydrazine in drinking water: Development and multivariate optimization of a rapid and simple solid phase microextraction-gas chromatography-triple quadrupole mass spectrometry protocol.

    Science.gov (United States)

    Gionfriddo, Emanuela; Naccarato, Attilio; Sindona, Giovanni; Tagarelli, Antonio

    2014-07-04

    In this work, the capabilities of solid phase microextraction were exploited in a fully optimized SPME-GC-QqQ-MS analytical approach for hydrazine assay. A rapid and easy method was obtained by a simple derivatization reaction with propyl chloroformate and pyridine carried out directly in water samples, followed by automated SPME analysis in the same vial without further sample handling. The affinity of the different derivatized compounds obtained towards five commercially available SPME coatings was evaluated, in order to achieve the best extraction efficiency. GC analyses were carried out using a GC-QqQ-MS instrument in selected reaction monitoring (SRM) acquisition mode which has allowed the achievement of high specificity by selecting appropriate precursor-product ion couples improving the capability in analyte identification. The multivariate approach of experimental design was crucial in order to optimize derivatization reaction, SPME process and tandem mass spectrometry parameters. Accuracy of the proposed protocol, tested at 60, 200 and 800 ng L(-1), provided satisfactory values (114.2%, 83.6% and 98.6%, respectively), whereas precision (RSD%) at the same concentration levels were of 10.9%, 7.9% and 7.7% respectively. Limit of detection and quantification of 4.4 and 8.3 ng L(-1) were obtained. The reliable application of the proposed protocol to real drinking water samples confirmed its capability to be used as analytical tool for routine analyses.

  5. Effects of hydrazine derivatives on vascular smooth muscle contractility, blood pressure and cGMP production in rats: comparison with hydralazine.

    Science.gov (United States)

    Vidrio, Horacio; Fernández, Gabriela; Medina, Martha; Alvarez, Ezequiel; Orallo, Francisco

    2003-01-01

    Hydralazine is a hydrazine derivative used clinically as a vasodilator and antihypertensive agent. Despite numerous studies with the drug, its mechanism of action has remained unknown; guanylate cyclase activation and release of endothelial relaxing factors are thought to be involved in its vasodilator effect. Other hydrazine derivatives are known to stimulate guanylate cyclase and could therefore share the vasodilator activity of hydralazine, although such possibility has not been assessed systematically. In the present study, hydralazine, hydrazine, phenylhydrazine, and isoniazid were evaluated for vascular smooth muscle relaxation in rat aortic rings with and without endothelium, as well as after incubation with the guanylate cyclase inhibitor methylene blue. They were also tested for enhancement of cyclic guanosine monophosphate (cGMP) production by cultured rat aortic smooth muscle cells and for hypotension in the anesthetized rat. All hydrazines relaxed aortic rings, an action unaffected by endothelium removal and, in all cases except hydralazine, antagonized by methylene blue. Only phenylhydrazine increased cGMP production and only hydralazine markedly lowered blood pressure. It was concluded that hydralazine vascular relaxation is independent of endothelium and is not related to guanylate cyclase activation. The other hydrazines studied also elicit endothelium-independent relaxation, but the effect is related to guanylate cyclase. The marked hypotensive effect of hydralazine contrasts with its modest relaxant activity and is not shared by the other hydrazines. The fact that hydrazine and isoniazid produce methylene blue-sensitive relaxation, yet do not enhance cGMP production suggests the need for activating factors present in aortic rings but not in isolated cells.

  6. Prototype development and test results of a continuous ambient air monitoring system for hydrazine at the 10 ppb level

    Science.gov (United States)

    Meneghelli, Barry; Parrish, Clyde; Barile, Ron; Lueck, Dale E.

    1995-01-01

    A Hydrazine Vapor Area Monitor (HVAM) system is currently being field tested as a detector for the presence of hydrazine in ambient air. The MDA/Polymetron Hydrazine Analyzer has been incorporated within the HVAM system as the core detector. This analyzer is a three-electrode liquid analyzer typically used in boiler feed water applications. The HVAM system incorporates a dual-phase sample collection/transport method which simultaneously pulls ambient air samples containing hydrazine and a very dilute sulfuric acid solution (0.0001 M) down a length of 1/4 inch outside diameter (OD) tubing from a remote site to the analyzer. The hydrazine-laden dilute acid stream is separated from the air and the pH is adjusted by addition of a dilute caustic solution to a pH greater than 10.2 prior to analysis. Both the dilute acid and caustic used by the HVAM are continuously generated during system operation on an "as needed" basis by mixing a metered amount of concentrated acid/base with dilution water. All of the waste water generated by the analyzer is purified for reuse by Barnstead ion-exchange cartridges so that the entire system minimizes the generation of waste materials. The pumping of all liquid streams and mixing of the caustic solution and dilution water with the incoming sample are done by a single pump motor fitted with the appropriate mix of peristaltic pump heads. The signal to noise (S/N) ratio of the analyzer has been enhanced by adding a stirrer in the MDA liquid cell to provide mixing normally generated by the high liquid flow rate designed by the manufacturer. An onboard microprocessor continuously monitors liquid levels, sample vacuum, and liquid leak sensors, as well as handles communications and other system functions (such as shut down should system malfunctions or errors occur). The overall system response of the HVAM can be automatically checked at regular intervals by measuring the analyzer response to a metered amount of calibration standard injected

  7. Conformational effects on hydrazine and OH coadsorption on Ni(111): A first-principles investigation

    Science.gov (United States)

    Agusta, Mohammad Kemal; Purwoko, Prasetiyo Hadi; Saputro, Adhitya Gandaryus; Fathurrahman, Fadjar; Dipojono, Hermawan K.; Diño, Wilson Agerico

    2017-10-01

    Using first-principles Density Functional Theory calculations, we investigated coadsorption of hydrazine (N2H4) and OH on Ni(111) surface. Two types of N2H4 conformations: anti and cis-conformer, with coadsorbed OH on several high symmetry sites on Ni(111) surface were studied. We found that coadsorption with cis-conformer N2H4 significantly modifies OH site preferences while such modification is less profound for coadsorption with anti-conformer N2H4. On the other way around, the cis-confomer N2H4 coadsorption becomes more stable due to the pressence of OH. We identified the electrostatic attractive dipole interaction between the coadsorbed species as the underlying mechanism for the stabilization. This electrostatic interaction is particularly strong for cis-conformer N2H4 due to its large dipole moment. We also found Nsbnd H bond elongation for cis-conformer N2H4 coadsorption with OH due to the interaction between accumulated charge in OH with the H atom of N2H4. Therefore, it can be inferred that coadsorption with OH promotes the dehydrogenation reaction of N2H4 via stabilization of cis-confomer N2H4.

  8. Hydrogen generation from decomposition of hydrous hydrazine over Ni-Ir/CeO2 catalyst

    Directory of Open Access Journals (Sweden)

    Hongbin Dai

    2017-02-01

    Full Text Available The synthesis of highly active and selective catalysts is the central issue in the development of hydrous hydrazine (N2H4·H2O as a viable hydrogen carrier. Herein, we report the synthesis of bimetallic Ni-Ir nanocatalyts supported on CeO2 using a one-pot coprecipitation method. A combination of XRD, HRTEM and XPS analyses indicate that the Ni-Ir/CeO2 catalyst is composed of tiny Ni-Ir alloy nanoparticles with an average size of around 4 nm and crystalline CeO2 matrix. The Ni-Ir/CeO2 catalyst exhibits high catalytic activity and excellent selectivity towards hydrogen generation from N2H4·H2O at mild temperatures. Furthermore, in contrast to previously reported Ni-Pt catalysts, the Ni-Ir/CeO2 catalyst shows an alleviated requirement on alkali promoter to achieve its optimal catalytic performance.

  9. Investigation of a catalytic gas generator for the Space Shuttle APU. [hydrazine Auxiliary Propulsion Unit

    Science.gov (United States)

    Emmons, D. L.; Huxtable, D. D.; Blevins, D. R.

    1974-01-01

    An investigation was conducted to establish the capability of a monopropellant hydrazine catalytic gas generator to meet the requirements specified for the Space Shuttle APU. Detailed analytical and experimental studies were conducted on potential problem areas including long-term nitriding effects on materials, design variables affecting catalyst life, vehicle vibration effects, and catalyst oxidation/contamination. A full-scale gas generator, designed to operate at a chamber pressure of 750 psia and a flow rate of 0.36 lbm/sec, was fabricated and subjected to three separate life test series. The objective of the first test series was to demonstrate the capability of the gas generator to successfully complete 20 simulated Space Shuttle missions in steady-state operation. The gas generator was then refurbished and subjected to a second series of tests to demonstrate the pulse-mode capability of the gas generator during 20 simulated missions. The third series of tests was conducted with a refurbished reactor to further demonstrate pulse-mode capability with a modified catalyst bed.

  10. Influence of ultrasonic waves in the reduction of nitrate to nitrite by hydrazine-Cu(II).

    Science.gov (United States)

    Silva, Luciana A; Korn, Mauro; de Andrade, Jailson B

    2007-02-01

    Colorimetric methods are still important for determining nitrate and nitrite. A critical step in the use of these methods to determine nitrate in low concentrations is the reaction time required to totally reduce nitrate to nitrite, i.e., 24h in the dark. This work involved a study of the influence of ultrasonic irradiation on the nitrate reduction reaction by hydrazine. Our findings indicated that ultrasonic irradiation, associated with copper(II) ion as a catalyst, increased the redox reaction rate, decreasing the reaction time to about 10min when the power of the ultrasonic irradiation was set in 14.0357W. The strong influence of the ultrasonic irradiation in the reduction reaction rates can be sustained by an excellent linear correlation (R(2)=0.9993) between the kinetic constants and ultrasonic powers. Nitrate conversion also increased from 68% to 98% at the latter conditions. It thus become clear that high intensity ultrasound is very beneficial for this reduction reaction to proceed in good yield and in short reaction time in comparison to its silent reaction.

  11. Stoichiometry and kinetics of the anaerobic ammonium oxidation (Anammox) with trace hydrazine addition.

    Science.gov (United States)

    Yao, Zongbao; Lu, Peili; Zhang, Daijun; Wan, Xinyu; Li, Yulian; Peng, Shuchan

    2015-12-01

    Purpose of this study is to investigate the stoichiometry and kinetics of anaerobic ammonium oxidation (Anammox) with trace hydrazine addition. The stoichiometry was established based on the electron balance of Anammox process with trace N2H4 addition. The stoichiometric coefficients were determined by the proton consumption and the changes in substrates and products. It was found that trace N2H4 addition can increase the yield of Anammox bacteria (AnAOB) and reduce NO3(-) yield, which enhances the Anammox. Subsequently, kinetic model of Anammox with trace N2H4 addition was developed, and the parameters of the anaerobic degradation model of N2H4 were obtained for the first time. The maximum specific substrate utilization rate, half-saturation constant and inhibition constant of N2H4 were 25.09mgN/g VSS/d, 10.42mgN/L and 1393.88mgN/L, respectively. These kinetic parameters might provide important information for the engineering applications of Anammox with trace N2H4 addition.

  12. Feasibility of a Dual-Fuel Engine Fuelled with Waste Vegetable Oil and Municipal Organic Fraction for Power Generation in Urban Areas

    Directory of Open Access Journals (Sweden)

    L. De Simio

    2012-01-01

    Full Text Available Biomass, in form of residues and waste, can be used to produce energy with low environmental impact. It is important to use the feedstock close to the places where waste are available, and with the shortest conversion pathway, to maximize the process efficiency. In particular waste vegetable oil and the organic fraction of municipal solid waste represent a good source for fuel production in urban areas. Dual fuel engines could be taken into consideration for an efficient management of these wastes. In fact, the dual fuel technology can achieve overall efficiencies typical of diesel engines with a cleaner exhaust emission. In this paper the feasibility of a cogeneration system fuelled with waste vegetable oil and biogas is discussed and the evaluation of performance and emissions is reported on the base of experimental activities on dual fuel heavy duty engine in comparison with diesel and spark ignition engines. The ratio of biogas potential from MSW and biodiesel potential from waste vegetable oil was estimated and it results suitable for dual fuel fuelling. An electric power installation of 70 kW every 10,000 people could be achieved.

  13. Analysis of unprotected transients with control and safety rod drive mechanism expansion feedback in a medium sized oxide fuelled fast breeder reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sathiyasheela, T., E-mail: sheela@igcar.gov.in; Natesan, K.; Srinivasan, G.S.; Devan, K.; Puthiyavinayagam, P.

    2015-09-15

    Highlights: • Possibilities of enhancing safety under ULOF and UTOP accidents. • CSRDM expansion feedbacks under unprotected transients. • CSRDM expansion feedback enhances the safety of fast reactors. • CSRDM expansion feedbacks ensuring enough time for initiating safety actions. - Abstract: Possibilities of enhancing core safety under unprotected loss of flow (ULOF) and unprotected transient over power (UTOP) accidents with control and safety rod drive mechanism (CSRDM) expansion feedbacks are explored in a medium sized oxide fuelled fast breeder reactor. This feedback is expected to take the reactor to a safe shutdown under ULOF and to an another steady state under UTOP where there is no significant fuel melting. Under ULOF, with CSRDM feedback net reactivity was maintained negative throughout the transient (up to 2000 s) and the power dropped to a level of heat removal capacity of decay heat removal system based on natural circulation. Similarly, under UTOP with the above feedback reactor power goes to a lower peak value. The fuel temperature is just touching the melting temperature and the melt fraction does not cross 5%. With CSRDM expansion feedbacks both ULOF and UTOP transients prolong beyond 2000 s. It ensures, availability of time for initiating any safety actions against the transients, and thus it helps to preclude core disruptive accidents (CDA) in a medium sized oxide fuelled reactors.Classification: L. safety and risk analysis.

  14. Thermodynamic Performance Analysis of a Biogas-Fuelled Micro-Gas Turbine with a Bottoming Organic Rankine Cycle for Sewage Sludge and Food Waste Treatment Plants

    Directory of Open Access Journals (Sweden)

    Sunhee Kim

    2017-02-01

    Full Text Available In the Republic of Korea, efficient biogas-fuelled power systems are needed to use the excess biogas that is currently burned due to a lack of suitable power technology. We examined the performance of a biogas-fuelled micro-gas turbine (MGT system and a bottoming organic Rankine cycle (ORC. The MGT provides robust operation with low-grade biogas, and the exhaust can be used for heating the biodigester. Similarly, the bottoming ORC generates additional power output with the exhaust gas. We selected a 1000-kW MGT for four co-digestion plants with 28,000-m3 capacity. A 150-kW ORC system was selected for the MGT exhaust gas. We analysed the effects of the system size, methane concentration, and ORC operating conditions. Based on the system performance, we analysed the annual performance of the MGT with a combined heat and power (CHP system, bottoming ORC, or both a bottoming ORC and CHP system. The annual net power outputs for each system were 7.4, 8.5, and 9.0 MWh per year, respectively.

  15. Theoretical studies on vibrational spectra, thermodynamic properties, detonation properties and pyrolysis mechanism for 1,2-bis(2,4,6-trinitrophenyl) hydrazine.

    Science.gov (United States)

    Xiao-Hong, Li; Rui-Zhou, Zhang; Xian-Zhou, Zhang

    2012-07-01

    The thermal stability and pyrolysis mechanism of 1,2-bis(2,4,6-trinitrophenyl) hydrazine were investigated based on fully optimized molecular geometric structures. The results demonstrate the existence of intramolecular hydrogen bond interactions 1,2-bis(2,4,6-trinitrophenyl) hydrazine. The assigned infrared spectrum was also obtained; the results reveal four main characteristic regions in the calculated IR spectra of the title compound. Detonation velocities (D) and pressures (P) were also evaluated by using Kamlet-Jacobs equations based on the calculated density and heat of formation. Thermal stability and the pyrolysis mechanism of 1,2-bis(2,4,6-trinitrophenyl) hydrazine were investigated by calculating the bond dissociation energies at the B3LYP/6-31 G* level.

  16. Structures of N- (2,3,4,6-Tetra- O-acetyl-β- D-glycosyl) thiocar-bamic Benzoyl Hydrazine

    Institute of Scientific and Technical Information of China (English)

    ZHANG,Shu-Sheng(张书圣); LIN,Jie-Hua(林洁华); JIAN,Fang-Fang(建方方); JIAO,Kui(焦奎)

    2002-01-01

    The crystal structure of N-( 2, 3 , 4 , 6-tetra-O-acetyl- β- D-glycosyl)-thiocarbamic benzoyl hydrazine ( C22 H27 N3O9S) was determined by X-ray diffraction method. The hexopyranosyl ring adopts a chair conformation. All the ring substituents are in the equatorial positions. The acetoxyl-methyl group is in synclinal conformation. The S atom is in synperiplanar conformation while the benzoyl hydrazine moiety is anti-periplanar. The thiocarbamic moiety is almost coplanar with the benzoyl hydrazine group. There are two intramolecular hydrogen bonds and one intermolecular hydrogen bond for each molecule in the crystal structure. The molecules form a network structure through intermolecular hydrogen bonds.

  17. Hydrazine-Free Solution-Deposited CuIn(S,Se)2 Solar Cells by Spray Deposition of Metal Chalcogenides

    Energy Technology Data Exchange (ETDEWEB)

    Arnou, Panagiota; van Hest, Maikel F. A. M.; Cooper, Carl S.; Malkov, Andrei V.; Walls, John M.; Bowers, Jake W.

    2016-05-18

    Solution processing of semiconductors, such as CuInSe2 and its alloys (CIGS), can significantly reduce the manufacturing costs of thin film solar cells. Despite the recent success of solution deposition approaches for CIGS, toxic reagents such as hydrazine are usually involved, which introduce health and safety concerns. Here, we present a simple and safer methodology for the preparation of high-quality CuIn(S, Se)2 absorbers from metal sulfide solutions in a diamine/dithiol mixture. The solutions are sprayed in air, using a chromatography atomizer, followed by a postdeposition selenization step. Two different selenization methods are explored resulting in power conversion efficiencies of up to 8%.

  18. Change in plant cycle chemistry from hydrazine/phosphate to amine/polyamine treatment in an industrial power station

    Energy Technology Data Exchange (ETDEWEB)

    Vogt, T.; Besl, G. [TUeV SUeD Industrie Service GmbH, Muenchen (Germany); Stecklina, M. [MD Papier GmbH, Dachau (Germany)

    2007-08-15

    In an industrial power station with several natural circulation boilers (permissible operation pressure 13.6 MPa), raw water treatment via demineralization, condensate polishing and thermal feedwater degasification, the cycle chemistry was changed from hydrazine/phosphate to amine/polyamine treatment. The modification was supervised by TUeV SUeD with several water chemical analyses of the water/steam circuit. No problematic water conditions were found during the investigations. Fewer condensate impurities and a reduced amount of boiler blowdown can be stated as positive results of the transition to the polyamine treatment. (orig.)

  19. Tests for the mutagenic action of a number of chemicals on Haemophilus influenzae with special emphasis on hydrazine

    Energy Technology Data Exchange (ETDEWEB)

    Kimball, R.F.; Hirsch, B.F.

    1975-01-01

    A number of chemicals have been tested for their ability to produce novobiocin-resistant mutants in Haemophilus influenzae. Of these, hydrazine (HZ) proved unique because it induced a fairly high incidence of mutation without killing significant numbers of cells at concentrations ranging over nearly four orders of magnitude. Moreover, its dose--effect curve increased very slowly initially and reached a relatively low maximum. It is suggested that HZ may be acting as both a mutagen and an antimutagen in this system. (auth)

  20. Effects of ethanolamine, pH change, and increased hydrazine levels on deposit-covered alloy 600 and brass corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Barkatt, A.; Labuda, E.; Wilder, D.M. [Catholic Univ. of America, Washington, DC (United States). Dept. of Chemistry; Smialowska, S.; Rebak, R.B. [Ohio State Univ., Columbus, OH (United States). Fontana Corrosion Center; Cherepakhov, G. [Consolidated Edison Co. of New York, Inc., New York, NY (United States); Burns, R.J. [Consolidated Edison Co. of New York, Inc., Buchanan, NY (United States)

    1997-09-01

    Chemical dissolution tests and electrochemical tests were carried out on alloy 600 (UNS N06600) specimens covered with synthetic deposit simulating the tube deposits in the steam generators at Indian Point 2 Station in Buchanan, New York. The tests showed that the introduction of ethanolamine (ETA) and a moderate increase in pH gave rise to lower corrosion rates, but enhancement of hydrazine levels caused them to rise. In the case of brass, both types of tests showed that raising the pH caused the corrosion rates to increase, but the introduction of ETA led to a mild decrease in these rates.

  1. The interaction of hydrazine with an Rh(1 1 1) surface as a model for adsorption to rhodium nanoparticles: A dispersion-corrected DFT study

    Energy Technology Data Exchange (ETDEWEB)

    He, Yan Bin [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Pharmaceutical Department, Changzhi Medical College, Changzhi 046000 (China); Jia, Jian Feng, E-mail: jiajf@dns.sxnu.edu.cn [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China); Wu, Hai Shun, E-mail: wuhs@mail.sxnu.edu.cn [School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004 (China)

    2015-02-01

    Highlights: • We propose a model suitable for simulating the adsorption of hydrazine on rhodium nanoparticles. • We found that inclusion of dispersion correction results in significant enhancement for the adsorption to the Rh(1 1 1) surface. • Nanoparticles surface with lower-coordinated sites are more reactive than those with almost saturated surface sites. - Abstract: In recent years, metal nanoparticles were found to be excellent catalysts for hydrogen generation from hydrazine for chemical hydrogen storage. In order to gain a better understanding of these catalytic systems, we have simulated the adsorption of hydrazine on rhodium nanoparticles surfaces by density functional theory (DFT) calculations with dispersion correction, DFT-D3 in the method of Grimme. The rhodium nanoparticles were modeled by the Rh(1 1 1) surface, in addition, the adsorptions at corners and edges sites of nanoparticles were considered by using rhodium adatoms on the surfaces. The calculations showed that hydrazine binds most strongly to the edge of nanoparticle with adsorption energy of −2.48 eV, where the hydrazine bridges adatoms of edge with the molecule twisted to avoid a cis structure; similar adsorption energy was found at the corner of nanoparticle, where the hydrazine bridges corner atom and surface atom with gauche configuration. However, we found that inclusion of the dispersion correction results in significant enhancement of molecule–substrate binding, thereby increasing the adsorption energy, especially the adsorption to the Rh(1 1 1) surface. The results demonstrate that the surface structure is a key factor to determine the thermodynamics of adsorption, with low coordinated atoms which providing sites of strong adsorption from the surface.

  2. Optimal Design and Operation of A Syngas-fuelled SOFC Micro-CHP System for Residential Applications in Different Climate Zones in China

    DEFF Research Database (Denmark)

    Yang, Wenyuan; Liso, Vincenzo; Zhao, Yingru

    2013-01-01

    demand. Numerical simulations are conducted in Matlab environment. System design trade-offs are discussed to determine the optimal match between the energy demand of the household for different climates across China and the energy supply of the micro-CHP during the whole year. Moreover, criteria......Energy consumption in residential sector can be considerably reduced by enhancing the efficiency of energy supply. Fuel cell-based residential micro-CHP systems are expected to be one of the most promising technologies because of their high efficiency and low environmental impact. Since the design...... heat-to-power load ratio. Therefore, the aim of this study is to investigate the optimal design and operation of a syngas-fuelled SOFC micro-CHP system for small households located in five different climate zones in China. The ability of the micro-CHP to cover the heat and electricity demand of a 70m2...

  3. Energetic and Exergetic Analysis of a Heat Exchanger Integrated in a Solid Biomass-Fuelled Micro-CHP System with an Ericsson Engine

    Directory of Open Access Journals (Sweden)

    Marie Creyx

    2016-04-01

    Full Text Available A specific heat exchanger has been developed to transfer heat from flue gas to the working fluid (hot air of the Ericsson engine of a solid biomass-fuelled micro combined heat and power (CHP. In this paper, the theoretical and experimental energetic analyses of this heat exchanger are compared. The experimental performances are described considering energetic and exergetic parameters, in particular the effectiveness on both hot and cold sides. A new exergetic parameter called the exergetic effectiveness is introduced, which allows a comparison between the real and the ideal heat exchanger considering the Second Law of Thermodynamics. A global analysis of exergetic fluxes in the whole micro-CHP system is presented, showing the repartition of the exergy destruction among the components.

  4. 天然气燃料动力船燃料加注模式研究%Research on Bunkering Mode of Natural Gas-fuelled Ship

    Institute of Scientific and Technical Information of China (English)

    石国政; 张晖; 范洪军

    2013-01-01

    针对天然气燃料加注方案,分析国内外船舶天然气燃料加注的现状、主要加注模式及其特点。结合我国内河水域的特点,提出适合我国天然气燃料动力船加注模式的建议。%The bunkering modes for natural gas fuel were taken as the research object .The bunkering situation on the do-mestic and international ships was analyzed , as well as the current principal bunkering modes and their features .Some sugges-tions on the bunkering modes applying to Chinese natural gas fuelled ships were put forward in light of the special features of Chi -nese inland waterways .

  5. EXPERIMENTAL INVESTIGATIONS OF REAL TIME SECONDARY CO-INJECTION OF WATER – DIETHYL ETHER SOLUTION IN DI-DIESEL ENGINE FUELLED WITH PALM KERNEL METHYL ESTER

    Directory of Open Access Journals (Sweden)

    Y. V. V. SATYANARAYANAMURTHY

    2012-12-01

    Full Text Available In this investigation tests were conducted on single cylinder diesel engine fuelled with neat diesel and biodiesel palm kernel methyl ester as a base line fuel with secondary injection of Water-DEE solution through the inlet manifold. A real time control systems consists of electronic unit pump that delivers 5% to 25% vol. Water-DEE solution through injector tip mounted nearer to the inlet manifold under a pressure of 3 kgf/cm2. NOx emissions reduced to a level of 500 ppm with simultaneous reduction of soot especially for PKME. However for 15% vol. of Water-DEE injection the HC emissions are closely tallying with that of neat diesel. A global overview of the results has shown that the 15% Water-DEE solution is the optimal blend based on performance and emission characteristics.

  6. Fundamental Study of Direct Injection Diesel Engine Fuelled with Hydrogen(1st Report: Analysis on Process of Mixture Formation in Unsteady Hydrogen Jet)

    OpenAIRE

    藤本, 元; 千田, 二郎; 大田, 篤志; フジモト, ハジメ; センダ, ジロウ; オオタ, アツシ; Fujimoto, Hajime; Senda, Jiro; Ohta, Atsushi

    2004-01-01

    In this study, the mixture formation processes of high pressure hydrogen jets were investigated using a constant-volume vessel. The mixture formations of steady gas jets injected into atmospheric pressure ambient are well known. However, there are few works about the mixture formations of high pressure hydrogen jets injected into high pressure ambient. Also, in gas releases having a pressure ratio of exit pressure to ambient pressure greater than 1.89, underexpanded jet will be formed. So the...

  7. Effects of fuel processing methods on industrial scale biogas-fuelled solid oxide fuel cell system for operating in wastewater treatment plants

    Science.gov (United States)

    Farhad, Siamak; Yoo, Yeong; Hamdullahpur, Feridun

    The performance of three solid oxide fuel cell (SOFC) systems, fuelled by biogas produced through anaerobic digestion (AD) process, for heat and electricity generation in wastewater treatment plants (WWTPs) is studied. Each system has a different fuel processing method to prevent carbon deposition over the anode catalyst under biogas fuelling. Anode gas recirculation (AGR), steam reforming (SR), and partial oxidation (POX) are the methods employed in systems I-III, respectively. A planar SOFC stack used in these systems is based on the anode-supported cells with Ni-YSZ anode, YSZ electrolyte and YSZ-LSM cathode, operated at 800 °C. A computer code has been developed for the simulation of the planar SOFC in cell, stack and system levels and applied for the performance prediction of the SOFC systems. The key operational parameters affecting the performance of the SOFC systems are identified. The effect of these parameters on the electrical and CHP efficiencies, the generated electricity and heat, the total exergy destruction, and the number of cells in SOFC stack of the systems are studied. The results show that among the SOFC systems investigated in this study, the AGR and SR fuel processor-based systems with electrical efficiency of 45.1% and 43%, respectively, are suitable to be applied in WWTPs. If the entire biogas produced in a WWTP is used in the AGR or SR fuel processor-based SOFC system, the electricity and heat required to operate the WWTP can be completely self-supplied and the extra electricity generated can be sold to the electrical grid.

  8. First status seminar `Druckflamm`. Development of a coal-fuelled combined cycle process with liquid ash separation. Conference report; Erstes Statusseminar `Druckflamm`. Entwicklung eines kohlegefeuerten Gas- und Dampfturbinenprozesses mit Fluessigascheabscheidung. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    Hannes, K. [ed.

    1999-09-01

    Six industrial enterprises in the Ruhr, plus several universities and national rsearch centers are working on the `Druckflamm` process of pressurized coal dust combustion, which is described in this status report and is scheduled to be implementable within the next 20 years. To this end, an experimental facility (DKSF) was constructed at Dorsten. The plant works by a coal-fuelled combined cycle process in which the flue gas can be led directly onto a gas turbine after purification. This means that the flue gas must be free of particulate materials and noxious vapours, i.e. a particle size of less than 3 mg/m{sup 3}, a particle diameter of less than 3 {mu}m and an alkali concentration of less than 1 ppm. The Dorsten plant is fuelled with coal; it has a thermal capacity of 1 MW and can be operated at pressures up to 20 bar. The contribution presents an outline drawing of the plant and a survey of the results and information obtained so far. Material problems and methods of measurement are reported separately. The fuel coals were of different composition, with slag flow points between 1200 and 1400 degrees centigrade. [Deutsch] Im Ruhrgebiet wird an einem neuen Verfahren zur Verstromung von Steinkohle gearbeitet. Es soll in etwa 20 Jahren mit einem neuen Kraftwerkstyp einsetzbar sein. Kennzeichen dieses Verfahrens sind ein hoher Wirkungsgrad von mehr als 50% und eine geringe CO{sub 2}-Emission. Entwickelt wird das ``Druckkohlenstaubfeuerung`` genannte Projekt von sechs Industrieunternehmen. Zusaetzlich arbeiten an diesem Thema weitere Unternehmen sowie Universitaeten und Grossforschungseinrichtungen unter dem Arbeitstitel ``Druckflamm``. Bisherige Ergebnisse der grundlegenden Entwicklungsarbeiten sind in diesem Statusbericht zusammengefasst. Ziel des Verbundprojektes Druckkohlenstaubfeuerung (DKSF) in Dorsten ist, einen GUD-Prozess auf Kohlebasis zu entwickeln, der dadurch charakterisiert ist, dass das Rauchgas nach Reinigung unmittelbar auf eine Gasturbine geleitet

  9. Detection of Copper(II) Ions Using Glycine on Hydrazine-Adsorbed Gold Nanoparticles via Raman Spectroscopy

    Science.gov (United States)

    Ly, Nguyễn Hoàng; Seo, Chulhun; Joo, Sang-Woo

    2016-01-01

    A facile, selective, and sensitive detection method for the Cu2+ ions in environmental and biological solutions has been newly developed by observing the unique CN stretching peaks at ~2108 cm−1 upon the dissociative adsorption of glycine (GLY) in hydrazine buffer on gold nanoparticles (AuNPs). The relative abundance of Cu species on AuNPs was identified from X-ray photoelectron spectroscopy analysis. UV-Vis spectra also indicated that the Au particles aggregated to result in the color change owing to the destabilization induced by the GLY-Cu2+ complex. The CN stretching band at ~2108 cm−1 could be observed to indicate the formation of the CN species from GLY on the hydrazine-covered AuNP surfaces. The other ions of Fe3+, Fe2+, Hg2+, Mg2+, Mn2+, Ni2+, Zn2+, Cr3+, Co2+, Cd2+, Pb2+, Ca2+, NH4+, Na+, and K+ at high concentrations of 50 µM did not produce such spectral changes. The detection limit based on the CN band for the determination of the Cu2+ ion could be estimated to be as low as 500 nM in distilled water and 1 µM in river water, respectively. We attempted to apply our method to estimate intracellular ion detection in cancer cells for more practical purposes. PMID:27792178

  10. New PCR primers targeting hydrazine synthase and cytochrome c biogenesis proteins in anammox bacteria.

    Science.gov (United States)

    Zhou, Zhichao; Chen, Jing; Meng, Han; Dvornyk, Volodymyr; Gu, Ji-Dong

    2017-02-01

    PCR primers targeting genes encoding the two proteins of anammox bacteria, hydrazine synthase and cytochrome c biogenesis protein, were designed and tested in this study. Three different ecotypes of samples, namely ocean sediments, coastal wetland sediments, and wastewater treatment plant (WWTP) samples, were used to assess the primer efficiency and the community structures of anammox bacteria retrieved by 16S ribosomal RNA (rRNA) and the functional genes. Abundances of hzsB gene of anammox bacteria in South China Sea (SCS) samples were significantly correlated with 16S rRNA gene by qPCR method. And hzsB and hzsC gene primer pair hzsB364f-hzsB640r and hzsC745f-hzsC862r in combination with anammox bacterial 16S rRNA gene primers were recommended for quantifying anammox bacteria. Congruent with 16S rRNA gene-based community study, functional gene hzsB could also delineate the coastal-ocean distributing pattern, and seawater depth was positively associated with the diversity and abundance of anammox bacteria from shallow- to deep-sea. Both hzsC and ccsA genes could differentiate marine samples between deep and shallow groups of the Scalindua sp. clades. As for WWTP samples, non-Scalindua anammox bacteria reflected by hzsB, hzsC, ccsA, and ccsB gene-based libraries showed a similar distribution pattern with that by 16S rRNA gene. NH4(+) and NH4(+)/Σ(NO3(-) + NO2(-)) positively correlated with anammox bacteria gene diversity, but organic matter contents correlated negatively with anammox bacteria gene diversity in SCS. Salinity was positively associated with diversity indices of hzsC and ccsB gene-harboring anammox bacteria communities and could potentially differentiate the distribution patterns between shallow- and deep-sea sediment samples. SCS surface sediments harbored considerably diverse community of Scalindua. A new Mai Po clade representing coastal estuary wetland anammox bacteria group based on 16S rRNA gene phylogeny is proposed. Existence of anammox

  11. A QSAR/QSTR Study on the Environmental Health Impact by the Rocket Fuel 1,1-Dimethyl Hydrazine and its Transformation Products

    Directory of Open Access Journals (Sweden)

    Lars Carlsen

    2008-01-01

    Full Text Available QSAR/QSTR modelling constitutes an attractive approach to preliminary assessment of the impact on environmental health by a primary pollutant and the suite of transformation products that may be persistent in and toxic to the environment. The present paper studies the impact on environmental health by residuals of the rocket fuel 1,1-dimethyl hydrazine (heptyl and its transformation products. The transformation products, comprising a variety of nitrogen containing compounds are suggested all to possess a significant migration potential. In all cases the compounds were found being rapidly biodegradable. However, unexpected low microbial activity may cause significant changes. None of the studied compounds appear to be bioaccumulating. Apart from substances with an intact hydrazine structure or hydrazone structure the transformation products in general display rather low environmental toxicities. Thus, it is concluded that apparently further attention should be given to tri- and tetramethyl hydrazine and 1-formyl 2,2-dimethyl hydrazine as well as to the hydrazones of formaldehyde and acetaldehyde as these five compounds may contribute to the overall environmental toxicity of residual rocket fuel and its transformation products.

  12. A QSAR/QSTR Study on the Environmental Health Impact by the Rocket Fuel 1,1-Dimethyl Hydrazine and its Transformation Products.

    Science.gov (United States)

    Carlsen, Lars; Kenessov, Bulat N; Batyrbekova, Svetlana Ye

    2008-07-18

    QSAR/QSTR modelling constitutes an attractive approach to preliminary assessment of the impact on environmental health by a primary pollutant and the suite of transformation products that may be persistent in and toxic to the environment. The present paper studies the impact on environmental health by residuals of the rocket fuel 1,1-dimethyl hydrazine (heptyl) and its transformation products. The transformation products, comprising a variety of nitrogen containing compounds are suggested all to possess a significant migration potential. In all cases the compounds were found being rapidly biodegradable. However, unexpected low microbial activity may cause significant changes. None of the studied compounds appear to be bioaccumulating.Apart from substances with an intact hydrazine structure or hydrazone structure the transformation products in general display rather low environmental toxicities. Thus, it is concluded that apparently further attention should be given to tri- and tetramethyl hydrazine and 1-formyl 2,2-dimethyl hydrazine as well as to the hydrazones of formaldehyde and acetaldehyde as these five compounds may contribute to the overall environmental toxicity of residual rocket fuel and its transformation products.

  13. Infrared spectra of hydrazine and products of its reactions with HF, F/sub 2/, and O/sub 3/ in solid argon

    Energy Technology Data Exchange (ETDEWEB)

    Lascola, R.; Withnall, R.; Andrews, L.

    1988-02-24

    Hydrazine, N/sub 2/H/sub 4/, and its reactions with HF, F/sub 2/, and O/sub 3/ have been studied in an argon matrix. Vibrational assignments have been made for hydrazine, including clarification of the /nu//sub 6/, /nu//sub 10/, and 2/nu//sub 7/ bands. Complexation of N/sub 2/H/sub 4/ with HF produced a strong band at 2928 cm/sup /minus/1/ (/nu//sub s/(HF)) and sharp bands at 940 and 922 cm/sup /minus/1/ (/nu//sub 1/(HF)), as well as several perturbed N/sub 2/H/sub 4/ submolecule absorptions; the frequencies of these bands suggest a chelated structure similar to that for the NH/sub 2/OH-HF complex. Hydrazine and fluorine reacted during deposition to give the NH/sub 2/NHF-HF complex (/nu//sub s/ = 3113 cm/sup /minus/1/, /nu//sub 1/ = 726, 680 cm/sup /minus/1/). Reaction of hydrazine and ozone produced hydroxyhydrazine, NH/sub 2/NHOH, and minor products during deposition; photolysis increased the yield of hydroxyhydrazine. Evidence for an intramolecular hydrogen bond was found for NH/sub 2/NHOH. This matrix study presents the first spectroscopic evidence for both NH/sub 2/NHF and NH/sub 2/NHOH. 32 references, 3 figures, 4 tables.

  14. Preparation of Sulphur-containing Aromatic Amines by Reduction of the Corresponding Aromatic Nitro Compounds with Hydrazine Hydrate over Iron Oxide Hydroxide Catalyst

    Institute of Scientific and Technical Information of China (English)

    Qi Xun SHI; Rong Wen LU; Zhu Xia ZHANG; De Feng ZHAO

    2006-01-01

    Sulphur-containing aromatic nitro compounds were rapidly reduced to the corresponding amines in high yields by employing hydrazine hydrate as a hydrogen donor in the presence of iron oxide hydroxide catalyst. It was worth noting that the catalyst exhibited extremely high activity. The reduction could be completed within 20-50 min and the yields were up to 97-99 %.

  15. Photoconversion of 4-nitrophenol in the presence of hydrazine with AgNPs-TiO{sub 2} nanoparticles prepared by the sol–gel method

    Energy Technology Data Exchange (ETDEWEB)

    Hernández-Gordillo, Agileo, E-mail: agileo12@hotmail.com [División de Materiales Avanzados, Instituto Potosino de Investigación Científica y Tecnológica, Camino a la Presa San José 2055 Col. Lomas 4a. sección, C.P. 78216 San Luis Potosí, SLP, México (Mexico); CIIEMAD, Instituto Politécnico Nacional, Calle 30 de Junio de 1520 s/n, Barrio la Laguna Ticomán, C.P. 07340, Del. Gustavo A. Madero, DF, México (Mexico); Arroyo, Missael [División de Materiales Avanzados, Instituto Potosino de Investigación Científica y Tecnológica, Camino a la Presa San José 2055 Col. Lomas 4a. sección, C.P. 78216 San Luis Potosí, SLP, México (Mexico); Zanella, R. [Centro de Ciencias Aplicadas y Desarrollo Tecnológico, Universidad Nacional Autónoma de México, Circuito Exterior S/N, Ciudad Universitaria, A.P. 70-186, Delegación Coyoacán, C.P. 04510 México, DF, México (Mexico); and others

    2014-03-01

    Graphical abstract: - Highlights: • AgNPs are well dispersed on TiO{sub 2} semiconductor surface. • TiO{sub 2} with 1.5 wt% of Ag{sup 0} is the most photoactive for the 4-nitrophenol conversion. • High conversion of 4-nitrofenol to 4-aminophenol was achieved with hydrazine. • Enhanced photoactivity of Ag-TiO{sub 2} is associated with the ability to oxidize hydrazine. - Abstract: The photocatalytic properties of functionalized TiO{sub 2} with silver nanoparticles (AgNPs) for the conversion of 4-nitrophenol to 4-aminophenol in the presence of hydrazine were investigated. The TiO{sub 2} semiconductor synthesized by the sol–gel method was functionalized with AgNPs at different loadings, and their structural and optical properties were characterized by several techniques. The functionalized TiO{sub 2} with 1.5 wt% AgNPs presented the highest photocatalytic activity for the conversion of 4-nitrophenol with appropriate hydrazine concentrations (0.5 M). The photoefficiency enhancement under UV light irradiation was attributed to the electron transfer from the TiO{sub 2} semiconductor surface to the adsorbed acceptor reactant (4-nitrophenol) through the deposited AgNPs.

  16. Palladium nanoparticles decorated on reduced graphene oxide rotating disk electrodes toward ultrasensitive hydrazine detection: effects of particle size and hydrodynamic diffusion.

    Science.gov (United States)

    Krittayavathananon, Atiweena; Srimuk, Pattarachai; Luanwuthi, Santamon; Sawangphruk, Montree

    2014-12-16

    Although metal nanoparticle/graphene composites have been widely used as the electrode in electrochemical sensors, two effects, consisting of the particle size of the nanoparticles and the hydrodynamic diffusion of analytes to the electrodes, are not yet fully understood. In this work, palladium nanoparticles/reduced graphene oxide (PdNPs/rGO) composites were synthesized using an in situ polyol method. Palladium(II) ions and graphene oxide were reduced together with a reducing agent, ethylene glycol. By varying the concentration of palladium(II) nitrate, PdNPs with different sizes were decorated on the surface of rGO sheets. The as-fabricated PdNPs/rGO rotating disk electrodes (RDEs) were investigated toward hydrazine detection. Overall, a 3.7 ± 1.4 nm diameter PdNPs/rGO RDE exhibits high performance with a rather low limit of detection of about 7 nM at a rotation speed of 6000 rpm and provides a wide linear range of 0.1-1000 μM with R(2) = 0.995 at 2000 rpm. This electrode is highly selective to hydrazine without interference from uric acid, glucose, ammonia, caffeine, methylamine, ethylenediamine, hydroxylamine, n-butylamine, adenosine, cytosine, guanine, thymine, and l-arginine. The PdNPs/rGO RDEs with larger sizes show lower detection performance. Interestingly, the detection performance of the electrodes is sensitive to the hydrodynamic diffusion of hydrazine. The as-fabricated electrode can detect trace hydrazine in wastewater with high stability, demonstrating its practical use as an electrochemical sensor. These findings may lead to an awareness of the effect of the hydrodynamic diffusion of analyte that has been previously ignored, and the 3.7 ± 1.4 nm PdNPs/rGO RDE may be useful toward trace hydrazine detection, especially in wastewater from related chemical industries.

  17. A highly selective long-wavelength fluorescent probe for hydrazine and its application in living cell imaging

    Science.gov (United States)

    Hao, Yuanqiang; Zhang, Yintang; Ruan, Kehong; Meng, Fanteng; Li, Ting; Guan, Jinsheng; Du, Lulu; Qu, Peng; Xu, Maotian

    2017-09-01

    A highly selective long-wavelength turn-on fluorescent probe has been developed for the detection of N2H4. The probe was prepared by conjugation the tricyanofuran-based D-π-A system with a recognizing moiety of acetyl group. In the presence of N2H4, the probe can be effectively hydrazinolysized and produce a turn-on fluorescent emission at 610 nm as well as a large red-shift in the absorption spectrum corresponding to a color change from yellow to blue. The sensing mechanism was confirmed by HPLC, MS, UV-vis, emission spectroscopic and theoretical calculation studies. The probe displayed high selectivity and sensitivity for N2H4 with a LOD (limit of detection) of 0.16 μM. Moreover, the probe was successfully utilized for the detection of hydrazine in living cells.

  18. Palladium-free electroless deposition of pure copper film on glass substrate using hydrazine as reducing agent

    Science.gov (United States)

    Nobari, N.; Behboudnia, M.; Maleki, Ramin

    2016-11-01

    Thin copper films were fabricated on glass substrates by palladium-free electroless deposition, using hydrazine. The effects of modifying the deposition parameters like temperature, initial concentration and pH of electroless bath on the deposition rate and morphology of resulting films were studied and optimized. The film deposition is performed in two simple steps which shortens the pretreatment time and avoids applying expensive components and is environmentally benign. FESEM images show a uniform dispersion of Cu nanoparticles on the glass substrates in the first step. These nanoparticles act as an activator in the growth of homogeneous Cu thin film in the second step. The activation energy for the growth of Cu films was found to be 62 kJ/mol. EDX and XRD analysis demonstrates that the composition of the deposits was pure Cu with FCC crystal structure. The Cu films of 260 nm thickness showed a resistivity of about 2 × 10-6 Ω cm.

  19. [A promising method of hygienic evaluation of air pollution inside the modules of the international space station by hydrazine derivatives].

    Science.gov (United States)

    Mikos, K N; Mukhamedieva, L N; Pakhomova, A A; Ul'ianov, A V; Serdiuk, T M; Buriak, A K

    2009-01-01

    The increasing frequency of ISS egress operations resulted in ISS air pollution by an uncharacteristic group of toxic compounds, i. e. propellant residues and products of propellant incomplete burning. High reactivity and toxicity of these compounds necessitated the development of a method of sanitary-chemical evaluation of ISS air safety given penetration of the new pollutants. The method is fulfilled in two stages. First is air sampling and then--sample analysis in ground laboratory by chromatography-mass spectrometry. Air sampling, as well as sample handling and analysis procedures were refined with the use of artificial gas mixtures. The proposed method shows promise as an instrument for the hygienic evaluation of ISS air pollution by hydrazine derivatives.

  20. Incorporation of alpha-Ketoglutaric Acid as a Fixed Bed Scrubber Media for the Neutralization of Hydrazine Family Hypergolic Fuels

    Science.gov (United States)

    DeVor, R. W.; Santiago-Maldonado, E.; Parkerson, J. K.

    2010-01-01

    A candidate scrubber media, alpha-ketoglutaric acid (aKGA) adsorbed onto a silica-based substrate was examined as a potential alternative to the hydrazine-family hypergolic fuel neutralization techniques currently utilized at NASA/Kennedy Space Center (KSC). Helvenson et. al. has indicated that aKGA will react with hydrazines to produce non-hazardous, possibly biodegradable products. Furthermore, the authors have previously tested and demonstrated the use of aKGA aqueous solutions as a replacement neutralizing agent for citric acid, which is currently used as a scrubbing agent in liquid scrubbers at KSC. Specific properties examined include reaction efficiency, the loading capacity of aKGA onto various silica substrates, and the comparison of aKGA media performance to that of the citric acid vapor scrubber systems at KSC and a commercial vapor scrubber media. Preliminary investigations showed hydrophobic aerogel particles to be an ideal substrate for the deposition of the aKGA. Current studies have shown that the laboratory produced aKGA-Aerogel absorbent media are more efficient and cost effective than a commercially available fixed bed scrubber media, although much less cost effective than liquid-based citric acid scrubbers (although possibly safer and less labor intensive). A comparison of all three alternative scrubber technologies (liquid aKGA, solid-phase aKGA, and commercially available sorbent materials) is given considering both hypergolic neutralization capabilities and relative costs (as compared to the current citric acid scrubbing technology in use at NASA/KSC).

  1. Hydrazine 5,5'-bitetrazole-1,1'-diolate: a promising high density energetic salt with good properties.

    Science.gov (United States)

    Zhang, Zhi-Bin; Xu, Cai-Xia; Yin, Xin; Zhang, Jian-Guo

    2016-12-21

    The development of new environmentally friendly energetic compounds with reasonable detonation performance and safety is a long-term target in energetic materials research. A new energetic eco-friendly salt of hydrazine 5,5'-bitetrazole-1,1'-diolate (HA·BTO) is developed based on the reaction of 1H,1'H-5,5'-bitetrazole-1,1'-diolate (BTO) with hydrazine hydrochloride (HA·HCl), and fully characterized. The monocrystal of the title salt is obtained and the structure is determined by powder X-ray diffraction and single crystal X-ray diffraction. Results show that the salt belongs to the triclinic space group P1[combining macron] with a relatively high density of 1.912 g cm(-3) under 298 K. The properties of the salt are discussed in detail. The thermal decomposition behaviors of the salt are tested, indicating that the salt has good thermal stability with a decomposition temperature above 200 °C. The enthalpy of formation for the salt is dependent on the combustion heat date measured by oxygen bomb calorimetry with a result of 425.6 kJ mol(-1), which is the same level as TKX-50, and four times higher than that of RDX. The detonation pressure (P) and detonation velocity (D) of the salt are calculated as 8931 m s(-1) and 36.1 GPa, which are higher than those of RDX. In addition, the impact and friction sensitivities are tested through a relevant standard method with a result of 28 J and 120 N, which are better than those of TKX-50. We can draw the conclusion that the salt could provide a promising future in use as a kind of insensitive explosive alternative. The discovery also contributes significantly to the expansion and application of the chemistry of 1H,1'H-5,5'-bitetrazole-1,1'-diolate, as well as N-heterocyclic compounds.

  2. Experimental investigation into the oxidation reactivity and nanostructure of particulate matter from diesel engine fuelled with diesel/polyoxymethylene dimethyl ethers blends

    Science.gov (United States)

    Yang, Hao; Li, Xinghu; Wang, Yan; Mu, Mingfei; Li, Xuehao; Kou, Guiyue

    2016-11-01

    This paper focuses on oxidation reactivity and nanostructural characteristics of particulate matter (PM) emitted from diesel engine fuelled with different volume proportions of diesel/polyoxymethylene dimethyl ethers (PODEn) blends (P0, P10 and P20). PM was collected using a metal filter from the exhaust manifold. The collected PM samples were characterized using thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The TGA results indicated that the PM produced by P20 had the highest moisture and volatility contents and the fastest oxidation rate of solid carbon followed by P10 and P0 derived PM. SEM analysis showed that PM generated from P20 was looser with a lower mean value than PM emitted from P10 and P0. Quantitative analysis of high-resolution TEM images presented that fringe length was reduced along with increased separation distance and tortuosity with an increase in PODEn concentration. These trends improved the oxidation reactivity. According to Raman spectroscopy data, the intensity, full width at half-maximum and intensity ratio of the bands also changed demonstrating that PM nanostructure disorder was correlated with a faster oxidation rate. The results show the use of PODEn affects the oxidation reactivity and nanostructure of PM that is easier to oxidize.

  3. INVESTIGATION OF COMBUSTION, PERFORMANCE AND EMISSION CHARACTERISTICS OF SPARK IGNITION ENGINE FUELLED WITH BUTHANOL – GASOLINE MIXTURE AND A HYDROGEN ENRICHED AIR

    Directory of Open Access Journals (Sweden)

    Alfredas Rimkus

    2016-09-01

    Full Text Available In this study, spark ignition engine fuelled with buthanol-gasoline mixture and a hydrogen-enriched air was investigated. Engine performance, emissions and combustion characteristics were investigated with different buthanol (10% and 20% by volume gasoline mixtures and additionally supplied oxygen and hydrogen (HHO gas mixture (3.6 l/min in the sucked air. Hydrogen, which is in the HHO gas, improves gasoline and gasoline-buthanol mixture combustion, increases indicated pressure during combustion phase and decreases effective specific fuel consumption. Buthanol addition decreases the rate of heat release, the combustion temperature and pressure are lower which have an influence on lower nitrous oxide (NOx emission in exhaust gases. Buthanol lowers hydrocarbon (HC formation, but it increases carbon monoxide (CO concentration and fuel consumption. Combustion process analysis was carried out using AVL BOOST software. Experimental research and combustion process numerical simulation showed that using balanced buthanol and hydrogen addition, optimal efficient and ecological parameters could be achieved when engine is working with optimal spark timing, as it would work on gasoline fuel.

  4. Evaluation of the subsidy scheme for heat pumps, pellet-fuelled fireplaces and control systems; Evaluering av tilskuddsordningen til varmepumper, pelletskaminer og styringssystemer

    Energy Technology Data Exchange (ETDEWEB)

    Bjoernstad, Even; Grande, Jorunn; Sand, Roar; Wendelborg, Christian

    2005-07-01

    Enova's subsidy scheme for energy economising in households was carried out in 2003. Subsidies were given to investments in heat pumps, pellet-fuelled fireplaces and electric energy management systems. The primary objective for this evaluation is to build knowledge about the effect of such subsidy schemes, and determine if they contribute to the reduction of electricity consumption in households. Questions that are addressed include Enova's administration of the subsidy scheme, the effects on households, the effects on the energy market, prices and technology. It is concluded that the scheme had a varied effect for the three technologies entitled to subsidies, and heat pump applications got 92,5 percent of the total sum. The households that received subsidies are in general positive, and the households that did not are in general not so satisfied with the service. It is concluded Enova has administered the subsidy scheme well, especially considering the time-frame and the changed economical conditions given (ml)

  5. Optimal design and operation of a syngas-fuelled SOFC micro CHP system for residential applications in different climate zones in China

    DEFF Research Database (Denmark)

    Yang, Wenyuan; Zhao, Yingru; Liso, Vincenzo

    2014-01-01

    to determine the optimal match between the energy demand of the household for different climates across China and the energy supply of the micro-CHP during the whole year. Moreover, criteria for sizing the system components of the micro-CHP are specifically addressed. The developed methodology can be applied...... under difference climate conditions to ensure that it is well matched with the local heat-to-power ratio. The aim of this study is to investigate the optimal design and operation of a syngas-fuelled SOFC micro-CHP system for small households located in five different climate zones in China. The ability...... of the micro-CHP to cover the heat and electricity demand of a 70 m2 single-family apartment with an average number of occupants of 3 is evaluated. A detailed model of the micro-CHP unit coupled with a hot water storage tank and an auxiliary boiler is developed. System design trade-offs are discussed...

  6. Effects of hydrazine on the solvothermal synthesis of Cu{sub 2}ZnSnSe{sub 4} and Cu{sub 2}CdSnSe{sub 4} nanocrystals for particle-based deposition of films

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, Ming-Hung [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan 701 (China); Fu, Yaw-Shyan, E-mail: ysfu@mail.nutn.edu.tw [Department of Greenergy, National University of Tainan, Tainan, Taiwan 700 (China); Shih, Cheng-Hung; Kuo, Chun-Cheng [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan 701 (China); Guo, Tzung-Fang [Department of Photonics, Advanced Optoelectronic Technology Center, National Cheng Kung University, Tainan, Taiwan 701 (China); Lin, Wen-Tai, E-mail: wtlin@mail.ncku.edu.tw [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan 701 (China)

    2013-10-01

    The effects of hydrazine on the synthesis of Cu{sub 2}ZnSnSe{sub 4} (CZTSe) and Cu{sub 2}CdSnSe{sub 4} (CCTSe) nanocrystals in an autoclave as a function of temperature and time were explored. On heating at 190 °C for 24-72 h, pure CZTSe and CCTSe nanocrystals could readily grow in the hydrazine-added solution, while in the hydrazine-free solution the intermediate phases such as ZnSe, Cu{sub 2}Se, and Cu{sub 2}SnSe{sub 3}, and Cu{sub 2}SnSe{sub 3} and CdSe associated with the CZTSe and CCTSe nanocrystals grew, respectively. This result reveals that hydrazine can speed up the synthesis of pure CZTSe and CCTSe nanocrystals via a solvothermal process. The mechanisms for the hydrazine-enhanced growth of CZTSe and CCTSe nanocrystals were discussed. The pure CZTSe and CCTSe nanocrystals were subsequently fabricated to the smooth films by spin coating without further annealing in selenium atmosphere. This processing may be beneficial to the fabrication of the absorber layer for solar cells and thermoelectric devices. - Highlights: • Hydrazine enhances the growth of pure Cu{sub 2}ZnSnSe{sub 4} and Cu{sub 2}CdSnSe{sub 4} nanocrystals. • The nanocrystals can be fabricated to films by spin coating without annealing. • This solvothermal processing is promising for the fabrication of thin film devices.

  7. Surface modification of g-C3N4 by hydrazine: Simple way for noble-metal free hydrogen evolution catalysts

    KAUST Repository

    Chen, Yin

    2015-11-02

    The graphitic carbon nitride (g-C3N4) usually is thought to be an inert material and it’s difficult to have the surface terminated NH2 groups functionalized. By modifying the g-C3N4 surface with hydrazine, the diazanyl group was successfully introduced onto the g-C3N4 surface, which allows the introduction with many other function groups. Here we illustrated that by reaction of surface hydrazine group modified g-C3N4 with CS2 under basic condition, a water electrolysis active group C(=S)SNi can be implanted on the g-C3N4 surface, and leads to a noble metal free hydrogen evolution catalyst. This catalyst has 40% hydrogen evolution efficiency compare to the 3 wt% Pt photo precipitated g-C3N4, with only less than 0.2 wt% nickel.

  8. Design, testing, fabrication and launch support of a liquid chemical barium release payload (utilizing the liquid fluorine-barium salt/hydrazine system)

    Science.gov (United States)

    Stokes, C. S.; Smith, E. W.; Murphy, W. J.

    1972-01-01

    A payload was designed which included a cryogenic oxidizer tank, a fuel tank, and burner section. Release of 30 lb of chemicals was planned to occur in 2 seconds at the optimum oxidizer to fuel ratio. The chemicals consisted of 17 lb of liquid fluorine oxidizer and 13 lb of hydrazine-barium salt fuel mixture. The fuel mixture was 17% barium chloride, 16% barium nitrate, and 67% hydrazine, and contained 2.6 lb of available barium. Two significant problem areas were resolved during the program: explosive valve development and burner operation. The release payload was flight tested, from Wallops Island, Virginia. The release took place at an altitude of approximately 260 km. The release produced a luminous cloud which expanded very rapidly, disappearing to the human eye in about 20 seconds. Barium ion concentration slowly increased over a wide area of sky until measurements were discontinued at sunrise (about 30 minutes).

  9. Synthesis, characterization and evaluation of 1,2-bis(2,4,6-trinitrophenyl) hydrazine: a key precursor for the synthesis of high performance energetic materials.

    Science.gov (United States)

    Badgujar, D M; Talawar, M B; Harlapur, Sujata F; Asthana, S N; Mahulikar, P P

    2009-12-15

    1,2-Bis(2,4,6-trinitrophenyl) hydrazine (3) is one of the precursors in the synthesis of an important energetic material viz., hexanitrazobenzene. The simple and convenient lab scale synthesis of title compound (3) was carried out by the condensation of picryl chloride (2) with hydrazine hydrate at 30-50 degrees C in methanol based on the lines of scanty literature reports. Picryl chloride was synthesized by the reaction of picric acid (1) with phosphorous oxychloride based on the lines of reported method. The synthesized compound (3) was characterized by IR and 1H NMR spectral data. Some of the energetic properties of the synthesized compound have also been studied. The theoretically computed energetic properties of the title compound (3) indicated the superior performance in comparison to tetranitrodibenzo tetraazapentalene (TACOT) and hexanitrostilbene (HNS) in terms of velocity of detonation.

  10. Combustion and emission characteristics of diesel engine fuelled with rice bran oil methyl ester and its diesel blends

    Directory of Open Access Journals (Sweden)

    Gattamaneni Rao Narayana Lakshmi

    2008-01-01

    Full Text Available There has been a worldwide interest in searching for alternatives to petroleum-derived fuels due to their depletion as well as due to the concern for the environment. Vegetable oils have capability to solve this problem because they are renewable and lead to reduction in environmental pollution. The direct use of vegetable oils as a diesel engine fuel is possible but not preferable because of their extremely higher viscosity, strong tendency to polymerize and bad cold start properties. On the other hand, Biodiesels, which are derived from vegetable oils, have been recently recognized as a potential alternative to diesel oil. This study deals with the analysis of rice bran oil methyl ester (RBME as a diesel fuel. RBME is derived through the transesterification process, in which the rice bran oil reacts with methanol in the presence of KOH. The properties of RBME thus obtained are comparable with ASTM biodiesel standards. Tests are conducted on a 4.4 kW, single-cylinder, naturally aspirated, direct-injection air-cooled stationary diesel engine to evaluate the feasibility of RBME and its diesel blends as alternate fuels. The ignition delay and peak heat release for RBME and its diesel blends are found to be lower than that of diesel and the ignition delay decreases with increase in RBME in the blend. Maximum heat release is found to occur earlier for RBME and its diesel blends than diesel. As the amount of RBME in the blend increases the HC, CO, and soot concentrations in the exhaust decreased when compared to mineral diesel. The NOx emissions of the RBME and its diesel blends are noted to be slightly higher than that of diesel.

  11. Comprehensive DFT and MP2 Level Investigations of Reaction of 2,3-Dihydro-1,5-benzodiazepine-2-thiones with Hydrazine

    Science.gov (United States)

    Okovytyy, Sergiy I.; Sviatenko, Liudmyla K.; Gaponov, Alexandr O.; Tarabara, Igor N.; Kasyan, Lilija I.; Leszczynski, Jerzy

    2009-09-01

    Density functional theory approach was used for the 4-phenyl-2,3-dihydro-1,5-benzodiazepine-2-thione compound to determine the mechanism of hydrazinolysis of 4-substituted 2,3-dihydro-1,5-benzodiazepine-2-thiones. Single-point calculations at the MP2/6-311+G(d,p)//B3LYP/6-311+G(d,p) level were performed for the more accurate energy prediction. The solvent effect was taken into account by carrying out single-point calculations using the PCM methodology. The obtained results show that in the investigating mechanism the first step consists of the hydrazine molecule addition to the thiocarbonyl bond of the 4-phenyl-2,3-dihydro-1,5-benzodiazepine-2-thione following removal of H2S. Further addition of another hydrazine molecule to the azomethyne bond and cyclization with pyrazole ring formation occur, and then the diazepine ring-opening and the removal of hydrazine molecule proceed. Finally, imine-enamine tautomerization leads to 5-N-(2-aminophenyl-1-amino)-3-phenylpyrazole as a main product that is in agreement with the experimental observation. The cyclization step is a rate-determining step of this reaction.

  12. Peak exposures to main components of ash and gaseous diesel exhausts in closed and open ash loading stations at biomass-fuelled power plants.

    Science.gov (United States)

    Laitinen, Juha; Koponen, Hanna; Sippula, Olli; Korpijärvi, Kirsi; Jumpponen, Mika; Laitinen, Sirpa; Aatamila, Marjaleena; Tissari, Jarkko; Karhunen, Tommi; Ojanen, Kari; Jokiniemi, Jorma; Korpinen, Leena

    2017-10-01

    Fly and bottom ashes are collected at power plants to reduce the environmental effects of energy production. However, handling the ashes causes health problems for operators, maintenance workers and truck drivers at the power plants. Hence, we evaluated ash loaders' peak inhalation exposures to the chemical components of ash and diesel exhausts in open and closed ash loading stations at biomass-fuelled combined heat and power plants. We also carried out chemical and morphological analyses of the ashes to evaluate their health hazard potential in order to find practical technical measures to reduce workers' exposure. On the basis of X-ray diffraction analyses, the main respirable crystalline ash compounds were SiO2, CaSO4, CaO, Ca2Al2SiO7, NaCl and Ca3Al2O6 in the fly ashes and SiO2, KAlSi3O8, NaAlSi3O8 and Ca2Al2SiO7 in the bottom ashes. The short-term exposure levels of respirable crystalline silica, inhalable inorganic dust, Cr, Mn, Ni and nitric oxide exceeded their Finnish eight hours occupational exposure limit values in the closed ash loading station. According to our observations, more attention should be paid to the ash-moistening process, the use of tank trucks instead of open cassette flatbed trucks, and the sealing of the loading line from the silo to the truck which would prevent spreading the ash into the air. The idling time of diesel trucks should also be limited, and ash loading stations should be equipped with exhaust gas ventilators. If working conditions make it impossible to keep to the OEL values, workers must use respirators and protect their eyes and skin. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Comparison of Carbonyls and BTEX Emissions from a Light Duty Vehicle Fuelled with Gasoline and Ethanol-Gasoline Blend, and Operated without 3-Way Catalytic Converter

    Directory of Open Access Journals (Sweden)

    Asad Naeem Shah

    2011-10-01

    Full Text Available This paper presents the comparison of unregulated emissions such as carbonyls and BTEX (Benzene, Toluene, Ethyl Benzene, and Xylenes species emanated from a light duty SI (Spark Ignition vehicle E-0 (fuelled on gasoline and E-10 (ethanol-gasoline blend. Meanwhile, the ozone forming potential of these pollutants based on their ozone SR (Specific Reactivity has also been addressed in this study. The experiments were performed on transient as well as steady-state modes in accordance with the standard protocols recommended for light duty vehicle emissions. Carbonyls and BTEX were analyzed by HPLC (High Performance Liquid Chromatography with UV detector and GC/MS (Gas Chromatography/Mass Spectroscopy, respectively. Formaldehyde and acetaldehyde were the predominant components of the carbonyls for E-0 and E-10, respectively. During transient mode, formaldehyde, acrolein + acetone, and tolualdehyde pollutants were decreased but, acetaldehyde emissions increased with E-10 as compared to E-0. The BTEX emissions were also decreased with E-10, relative to E-0. During the steady-state modes, formaldehyde, acrolein + acetone and propionaldehyde were lower, aromatic aldehydes were absent, but acetaldehyde pollutants were higher with E-10 compared to E-0. The BTEX emissions were decreased at medium and higher speed modes however, increased at lower speed mode with E-10 as compared to E-0. Total BTEX emissions were maximal at lower speed mode but, least at medium speed mode for both the fuels. SR of the pollutants was higher over transient cycle of operation, compared with steady-state mode. Relative to E-0, E-10 displayed lower SR during both transient as well as steady-state mode.

  14. SCR in biomass and waste fuelled plants. Benchmarking of Swedish and European plants; SCR i biobraensle- och avfallseldade anlaeggningar. Erfarenheter fraan svenska och europeiska anlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Goldschmidt, Barbara; Olsson, Henrik; Lindstroem, Erica

    2010-11-15

    In this report the state-of-art of SCR technology in biomass and waste fired plants is investigated. The aim of the investigation is to answer the question why new Swedish biomass combustion and co-combustion plants often prefer SNCR technology, whilst European waste combustion plants often choose SCR technology. In the report positives and negatives of various types of SCR installations are discussed, high-dust versus tail-end, 'normal' SCR versus low-temperature SCR, etc. Experiences, e g catalyst lifetime, deactivation and maintenance requirement, are discussed. The investigation is based partly on literature, but mainly on interviews with plant owners and with suppliers of SCR installations. The interviewed suppliers are mentioned in the reference list and the interviewed plant owners are mentioned in appendix A and B. The experiences from the Swedish and European plants are quite similar. Tail-end SCR is often operated without serious problems in both biomass and waste fuelled plants. The catalyst lifetimes are as long or even longer than for coal fired plants with high-dust SCR. In waste incineration plants high-dust SCR causes big problems and these plants are almost always equipped with tail-end SCR. In co-combustion boilers, where coal and biomass is co-combusted, high-dust SCR is more common, especially if the boilers were originally coal fired. In plants with both SNCR and high-dust SCR, i.e. slip-SCR, the SCR installation is considered to be much less of a problem. Although the activity loss of the catalyst is as quick as in conventional high-dust SCR, the catalyst can be changed less often. This is due to the fact that installed slip-SCR catalysts often are as large as conventional SCR catalysts, although less NO{sub x} reduction is required after the initial SNCR step. Thus, the catalyst lifetime is prolonged.

  15. Sambar, an Indian Dish Prevents the Development of Dimethyl Hydrazine-Induced Colon Cancer: A Preclinical Study.

    Science.gov (United States)

    Prasad, Vutturu Ganga; Reddy, Neetinkumar; Francis, Albi; Nayak, Pawan G; Kishore, Anoop; Nandakumar, Krishnadas; Rao, Mallikarjuna C; Shenoy, Rekha

    2016-07-01

    Colon cancer (CC) is the third commonly diagnosed cancer and the second leading cause of mortality in the US when compared to India where prevalence is less. Possible reason could be the vegetarian diet comprising spices used in curry powders. Researchers believe that 70% of the cases are associated with diet. Spices have inherited a rich tradition for their flavor and medicinal properties. Researchers have been oriented towards spices present in food items for their antitumorigenic properties. We investigated the effects of sambar as a preventive measure for 1,2-dimethyl hydrazine (DMH)-induced CC in Wistar albino rats. The animals were divided into three groups (n = 6) namely control, DMH, and sambar. At the end of the experimental period, the animals were killed using anesthesia and the colons and livers were examined. All the treatment groups exhibited a significant change in the number of aberrant crypt foci (ACF). Sambar group showed a significant change in the colonic GSH when compared to both normal and DMH groups. A significant reduction in the liver GSH was noted in the sambar group. Only sambar group showed a significant change in the liver catalase levels when compared to DMH. There was a significant reduction in the colonic nitrite in the sambar-treated group; 2.94 ± 0.29 when compared to DMH control at 8.09 ± 1.32. On the contrary, a significant rise in the liver nitrite levels was observed in the sambar-treated rats. Sambar may prevent the risk of CC when consumed in dietary proportions. Consumption of sambar significantly reduced aberrant crypt foci in DMH-induced colon cancer modelSambar treatment prevented DMH-induced oxidative changes in the colonic tissue, indicating its antioxidant roleSambar comprises a variety of spices that exhibited both pro- and antioxidant properties in different tissues, leading to its overall beneficial effect in this model. Abbreviations used: ACF: aberrant crypt foci, CC: colon cancer, DMH: 1,2-dimethyl hydrazine

  16. Consumers' risk elimination in fuel supply chain. The Attica's Marinas yacht fuelling case study

    Energy Technology Data Exchange (ETDEWEB)

    Liapis, Nikolaos [ELINOIL-HELLENIC PETROLEUM COMPANY, S.A., Kifisia (Greece); Zannikos, Fanourios [National Technical Univ. of Athens (Greece). Lab. of Fuels Technology and Lubricants

    2013-06-01

    Oil products distribution system is a complicated supply chain and includes a lot of uncertainties. A limited but quite interesting part of this system is yachting supply in marinas. Yachts usually are equipped with high efficiency and big horsepower modem engines; sea travelling is risky itself so fuel quality contributes significant in safety; many of the yachts are chartered for hired cruises and so operators have the right to purchase tax-free marine diesel, which creates conditions for smuggling and adulteration. All above create a great need for quality control in these fuels, as Greek oil companies do not apply at the moment Total Quality Management (TQM) for securing both quality specifications and quantity paid by the end user. In this research project the Laboratory of Fuel Technology and Lubricants of NTUA collected samples and analysed fuels delivered by tank trucks to yachts in six marinas in the district of Attica. These fuels were marketed by ELINOIL SA, a medium size oil distribution company, operating in Greece. ELINOIL has a market share of 6% of the Greek fuel market but is a market leader in yachting supply in Attica, having more than 50% of the specific market. Problems concerning fuel quality were analysed, direct or indirect causes were tracked, recorded and analysed, always in comparison with data from other Quality Control procedures applied from the company. A specially developed database was updated with facts and figures from incidents and quality issues covering this activity of the company during this period. The project, as it was targeted, detected the quality problems of the specific supply chain and ended to suggestions concerning the building of Quality Assurance System in yachting fuel supply. (orig.)

  17. Fuelling a BioMess. Why Burning Trees for Energy Will Harm People,the Climate and Forests

    Energy Technology Data Exchange (ETDEWEB)

    Mainville, N.

    2011-10-15

    impacts on forest health and biodiversity are expected if the 'green gold rush' continues along its current trajectory. This report shows that forest biomass cannot and should not replace fossil fuels on a large-scale. Electricity production from forest biomass is inefficient, while transforming trees into biofuels for transportation will mean impacting vast areas of forests. There is an urgent need for provincial policy makers to reassess the perceived environmental benefits of forest-based bioenergy and its role within Canada's energy portfolio. In a series of recommendations, Greenpeace aims to set the forest bioenergy sector back on track by highlighting the importance of focusing on industrial leftovers rather than relying directly on forests. This report can help policymakers realign forest bioenergy development in Canada and elsewhere before plunging the forest industry into a new environmental controversy.

  18. Exploring Sustainable Rocket Fuels: [Imidazolyl-Amine-BH2](+)-Cation-Based Ionic Liquids as Replacements for Toxic Hydrazine Derivatives.

    Science.gov (United States)

    Huang, Shi; Qi, Xiujuan; Zhang, Wenquan; Liu, Tianlin; Zhang, Qinghua

    2015-12-01

    The application of hypergolic ionic liquids as propellant fuels is a newly emerging area in the fields of chemistry and propulsion science. Herein, a new class of [imidazolyl-amine-BH2](+)-cation-based ionic liquids, which included fuel-rich anions, such as dicyanamide (N(CN)2(-)) and cyanoborohydride (BH3CN(-)) anions, were synthesized and characterized. As expected, all of the ionic liquids exhibited spontaneous combustion upon contact with the oxidizer 100 % HNO3. The densities of these ionic liquids varied from 0.99-1.12 g cm(-3), and the heats of formation, predicted based on Gaussian 09 calculations, were between -707.7 and 241.8 kJ mol(-1). Among them, the salt of compound 5, that is, (1-allyl-1H-imidazole-3-yl)-(trimethylamine)-dihydroboronium dicyanamide, exhibited the lowest viscosity (168 MPa s), good thermal properties (Tg 130 °C), and the shortest ignition-delay time (18 ms) with 100 % HNO3. These ionic fuels, as "green" replacements for toxic hydrazine-derivatives, may have potential applications as bipropellant formulations.

  19. Key study on the potential of hydrazine bisborane for solid- and liquid-state chemical hydrogen storage.

    Science.gov (United States)

    Pylypko, Sergii; Petit, Eddy; Yot, Pascal G; Salles, Fabrice; Cretin, Marc; Miele, Philippe; Demirci, Umit B

    2015-05-04

    Hydrazine bisborane N2H4(BH3)2 (HBB; 16.8 wt %) recently re-emerged as a potential hydrogen storage material. However, such potential is controversial: HBB was seen as a hazardous compound up to 2010, but now it would be suitable for hydrogen storage. In this context, we focused on fundamentals of HBB because they are missing in the literature and should help to shed light on its effective potential while taking into consideration any risk. Experimental/computational methods were used to get a complete characterization data sheet, including, e.g., XRD, NMR, FTIR, Raman, TGA, and DSC. From the reported results and discussion, it is concluded that HBB has potential in the field of chemical hydrogen storage given that both thermolytic and hydrolytic dehydrogenations were analyzed. In solid-state chemical hydrogen storage, it cannot be used in the pristine state (risk of explosion during dehydrogenation) but can be used for the synthesis of derivatives with improved dehydrogenation properties. In liquid-state chemical hydrogen storage, it can be studied for room-temperature dehydrogenation, but this requires the development of an active and selective metal-based catalyst. HBB is a thus a candidate for chemical hydrogen storage.

  20. Ruthenium nanoparticles confined in SBA-15 as highly efficient catalyst for hydrolytic dehydrogenation of ammonia borane and hydrazine borane

    Science.gov (United States)

    Yao, Qilu; Lu, Zhang-Hui; Yang, Kangkang; Chen, Xiangshu; Zhu, Meihua

    2015-10-01

    Ultrafine ruthenium nanoparticles (NPs) within the mesopores of the SBA-15 have been successfully prepared by using a “double solvents” method, in which n-hexane is used as a hydrophobic solvent and RuCl3 aqueous solution is used as a hydrophilic solvent. After the impregnation and reduction processes, the samples were characterized by XRD, TEM, EDX, XPS, N2 adsorption-desorption, and ICP techniques. The TEM images show that small sized Ru NPs with an average size of 3.0 ± 0.8 nm are uniformly dispersed in the mesopores of SBA-15. The as-synthesized Ru@SBA-15 nanocomposites (NCs) display exceptional catalytic activity for hydrogen generation by the hydrolysis of ammonia borane (NH3BH3, AB) and hydrazine borane (N2H4BH3, HB) at room temperature with the turnover frequency (TOF) value of 316 and 706 mol H2 (mol Ru min)-1, respectively, relatively high values reported so far for the same reaction. The activation energies (Ea) for the hydrolysis of AB and HB catalyzed by Ru@SBA-15 NCs are measured to be 34.8 ± 2 and 41.3 ± 2 kJ mol-1, respectively. Moreover, Ru@SBA-15 NCs also show satisfied durable stability for the hydrolytic dehydrogenation of AB and HB, respectively.

  1. The influence of engine operating parameters on aldehyde emissions from an ethanol-fuelled vehicle; Influencia de parametros de operacao do motor nas emissoes de aldeidos por um veiculo a etanol

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Rinaldo Antunes [FIAT Automoveis S.A., Betim, MG (Brazil). Engenharia de Motores]. E-mail: expmotor@fiat.com.br; Sodre, Jose Ricardo [Pontificia Univ. Catolica de Minas Gerais, Belo Horizonte, MG (Brazil). Dept. de Engenharia Mecanica]. E-mail: ricardo@pucminas.br

    2000-07-01

    This work presents results and analysis of experiments on aldehyde emissions and on the regulated pollutants (CO, HC and NO{sub X}) emissions, with varying engine operational parameters in an ethanol-fuelled vehicle during a standard urban test cycle. The test cycle was carried out with the vehicle in a chassis dynamometer, and simulates an average urban trip of approximately 5,8 km, under steady state conditions. The varied parameters were fuel/air equivalence ratio, dash pot function, cut off function and gear change speed. The results found showed lower aldehyde emissions for gear change at lower speeds and for richer mixtures. (author)

  2. Overpressure wave generated by the pneumatic explosion of a solid propellant-fuelled propeller; Onde de surpression generee par l`explosion pneumatique d`un propulseur a propergol solide

    Energy Technology Data Exchange (ETDEWEB)

    Rolland, C.; Roussille, A. [DGA, Direction des Missiles et de l`Espace, Centre d`Achevement et d`Essais des Propulseurs et Engins, 33 - Saint Medard en Jalles (France)

    1996-12-31

    The CAEPE, the French Centre of Propellers and Engines Completion and Testing is in charge of the static tests of solid propellant fuelled propellers. In order to evaluate the risks linked with the explosion of such propellers, an analytical method is proposed which allows to determine the energy, impulses and overpressure due to an explosion occurring at any time of the firing process. This method is based on the exploitation of the shock tube equations. Concerning the overpressure wave propagation, several laws are compared to full scale tests performed at the CAEPE. (J.S.) 14 refs.

  3. Fuelling fortress America : a report on the Athabasca Tar Sands and U.S. demands for Canada's energy

    Energy Technology Data Exchange (ETDEWEB)

    McCullum, H.

    2006-07-01

    The economic, ecological, and social costs at stake in developing the Athabasca tar sands were examined in order to stimulate public discussion, debate, and action towards a new made-in-Canada energy policy and strategy. The report is organized according to five lines of inquiry. It first looks at the United States empire and its demands for energy security. This includes the growing dependence of the United States on foreign oil; how Canada exports its oil and natural gas to the U.S.; the growth and threat of China's energy needs; and how this relates to the global depletion of fossil fuels and Canada's future energy security. The report also looks at the role that Canada plays as a United States energy satellite. Topics that are covered include the nature and scope of the Athabasca tar sands as a major source of oil; the existing projects and rapidly growing developments; the kind of extraction processes used; the energy intensity of the process and the role played by natural gas; the proposed Mackenzie Valley pipeline to bring gas from the High Arctic; and, the emerging continental energy corridor. In addition, the report examines the environmental costs of this new energy corridor and looks at the fuelling of the United States military-industrial complex. Last, the report discusses the social impacts of the tar sands and pipeline including how the fast pace of development combines with a lack of vision or industrial strategy in Alberta; the issue of royalties and financing social needs; the moves to use non-unionized and cheap foreign labour in the tar sands projects; and the impacts on First Nations. The report concludes with a set of recommendations on what needs to be done to stimulate new policies and strategies on three fronts including further development of the Athabasca tar sands and the construction of the accompanying Mackenzie Valley and Alaska natural gas pipelines; a made-in-Canada national energy policy and strategy; and, short- and long

  4. (E-1-Diphenylmethylidene-2-[(1H-indol-3-ylmethylidene]hydrazine

    Directory of Open Access Journals (Sweden)

    R. Archana

    2010-07-01

    Full Text Available In the title compound, C22H17N3, the 1H-indole unit is essentially planar, with a dihedral angle of 0.95 (10° between the pyrrole ring and the fused benzene ring. The dihedral angle between the two phenyl rings is 65.09 (10°. In the crystal, an intermolecular N—H...N hydrogen bond forms an infinite chain in the b-axis direction.

  5. Test and Evaluation of an Energetics Science Incorporated Model 7660 Electrochemical Hydrazines Analyzer.

    Science.gov (United States)

    1980-06-01

    experienced with servicing the CO and NOx Ecolyzer instruments that we use in our field monitoring programs. No electronic prob- lems were experienced...hydrocarbons; aldehydes ; ketones; organic sulfides; and common air pollutants such as sulfur dioxide, nitrogen oxides, and carbon monoxide. Of the compounds... Cigarette smoke directed toward the analyzer sample inlet, for example, caused an off-scale spike on the 0-20-ppm range; return to instrument zero took

  6. Fuelling the future with LNG

    NARCIS (Netherlands)

    Anonymous

    2013-01-01

    It is important to be able to quantify risks in order to determine LNG behaviour and to ensure its containment. This facilitates comprehensive safety management. Quantitative risk assessments are necessary to enable the selection of preventive and protective measures that suit the situation. Every s

  7. Fuelling innovation in building design.

    Science.gov (United States)

    Baillie, Jonathan

    2012-08-01

    Established in 2005 on a 78-acre site near Watford by a research-based consultancy, testing, and training organisation with a reputation for independence and impartiality, the BRE's Watford Innovation Park is today home to a broad range of research, consultancy, and testing activities, for the built environment. HEJ editor, Jonathan Baillie, met with BRE director of Strategic Research, Peter Ball, to learn about the organisation's history and current-day activities, and tour of some of the key facilities where staff undertake cutting-edge research, consultancy, and testing, to improve the performance, efficiency, and sustainability, of a wide range of buildings.

  8. Fuelling the future with LNG

    NARCIS (Netherlands)

    Anonymous

    2013-01-01

    It is important to be able to quantify risks in order to determine LNG behaviour and to ensure its containment. This facilitates comprehensive safety management. Quantitative risk assessments are necessary to enable the selection of preventive and protective measures that suit the situation. Every

  9. Electrochemical flow injection analysis of hydrazine in an excess of an active pharmaceutical ingredient: achieving pharmaceutical detection limits electrochemically.

    Science.gov (United States)

    Channon, Robert B; Joseph, Maxim B; Bitziou, Eleni; Bristow, Anthony W T; Ray, Andrew D; Macpherson, Julie V

    2015-10-06

    The quantification of genotoxic impurities (GIs) such as hydrazine (HZ) is of critical importance in the pharmaceutical industry in order to uphold drug safety. HZ is a particularly intractable GI and its detection represents a significant technical challenge. Here, we present, for the first time, the use of electrochemical analysis to achieve the required detection limits by the pharmaceutical industry for the detection of HZ in the presence of a large excess of a common active pharmaceutical ingredient (API), acetaminophen (ACM) which itself is redox active, typical of many APIs. A flow injection analysis approach with electrochemical detection (FIA-EC) is utilized, in conjunction with a coplanar boron doped diamond (BDD) microband electrode, insulated in an insulating diamond platform for durability and integrated into a two piece flow cell. In order to separate the electrochemical signature for HZ such that it is not obscured by that of the ACM (present in excess), the BDD electrode is functionalized with Pt nanoparticles (NPs) to significantly shift the half wave potential for HZ oxidation to less positive potentials. Microstereolithography was used to fabricate flow cells with defined hydrodynamics which minimize dispersion of the analyte and optimize detection sensitivity. Importantly, the Pt NPs were shown to be stable under flow, and a limit of detection of 64.5 nM or 0.274 ppm for HZ with respect to the ACM, present in excess, was achieved. This represents the first electrochemical approach which surpasses the required detection limits set by the pharmaceutical industry for HZ detection in the presence of an API and paves the wave for online analysis and application to other GI and API systems.

  10. N-(acyl)-N'-(ferrocenylidene)hydrazines and their nickel(II) complexes: Syntheses, structures and physical properties

    Indian Academy of Sciences (India)

    G NARENDRA BABU; SAMUDRANIL PAL

    2017-08-01

    The Schiff bases N-(acyl)-N’-(ferrocenylidene)hydrazines (HFcah (1) and HFcbh (2), where acyl = acetyl in 1 and benzoyl in 2 and H represents the dissociable amide proton) were synthesized in high yields (74 and 81%) by condensation reactions of equimolar amounts of ferrocene-carboxaldehyde and the corresponding acylhydrazines in presence of acetic acid in refluxing methanol.Reactions of Ni(OAc) ₂·4H ₂O, the Schiff bases (1 and 2) and NaOAc ·3H ₂O in 1:2:4 mole ratio in refluxing methanol afforded the diamagnetic iron(II)-nickel(II)- iron(II) species [Ni(Fcah) ₂] (3) and [Ni(Fcbh) ₂] (4) in 60 and 68% yields, respectively. Both Schiff bases and the two trinuclear complexes were characterized by elemental (CHN) analysis, mass spectrometric, various spectroscopic (IR, UV-Vis and 1H NMR) and cyclic voltammetric measurements. Molecular structures of 2, 3and 4 were determined by single crystal X-ray diffraction studies. The cyclopentadienide rings in the ferrocene moieties are essentially in eclipsed conformation in all three structures. Deprotonated Schiff base ligands in each complex (Fcah− in 3 and Fcbh− in 4) act as five-membered chelate ring forming azomethine-N and amidate-O donors and assemble a square-planar trans-N ₂O ₂ coordination environment around the nickel centre. The redox active 1–4 exhibit an iron centred redox couple in the potential range 0.23–0.50 V (vs. Ag/AgCl).

  11. Torsion-wagging tunneling and vibrational states in hydrazine determined from its ab initio potential energy surface

    Science.gov (United States)

    Łodyga, Wiesław; Makarewicz, Jan

    2012-05-01

    Geometries, anharmonic vibrations, and torsion-wagging (TW) multiplets of hydrazine and its deuterated species are studied using high-level ab initio methods employing the second-order Møller-Plesset perturbation theory (MP2) as well as the coupled cluster singles and doubles model including connected triple corrections, CCSD(T), in conjunction with extended basis sets containing diffuse and core functions. To describe the splitting patterns caused by tunneling in TW states, the 3D potential energy surface (PES) for the large-amplitude TW modes is constructed. Stationary points in the 3D PES, including equivalent local minima and saddle points are characterized. Using this 3D PES, a flexible Hamiltonian is built numerically and then employed to solve the vibrational problem for TW coupled motion. The calculated ground state rav structure is expected to be more reliable than the experimental one that has been determined using a simplified structural model. The calculated fundamental frequencies allowed resolution of the assignment problems discussed earlier in the literature. The determined energy barriers, including the contributions from the small-amplitude vibrations, to the tunneling of the symmetric and antisymmetric wagging mode of 1997 cm-1 and 3454 cm-1, respectively, are in reasonable agreement with the empirical estimates of 2072 cm-1 and 3312 cm-1, respectively [W. Łodyga et al. J. Mol. Spectrosc. 183, 374 (1997), 10.1006/jmsp.1997.7271]. However, the empirical torsion barrier of 934 cm-1 appears to be overestimated. The ab initio calculations yield two torsion barriers: cis and trans of 744 cm-1 and 2706 cm-1, respectively. The multiplets of the excited torsion states are predicted from the refined 3D PES.

  12. Multifunctional Co0.85Se/graphene hybrid nanosheets: controlled synthesis and enhanced performances for the oxygen reduction reaction and decomposition of hydrazine hydrate

    Science.gov (United States)

    Zhang, Lin-Fei; Zhang, Chun-Yang

    2014-01-01

    Ultrathin nanosheets possess novel electronic structures and physical properties as compared with their corresponding bulk samples. However, the controlled synthesis of ultrathin monolayer nanosheets still remains a great challenge due to the lack of an intrinsic driving force for anisotropic growth of two-dimensional (2D) structures. Here we demonstrate, for the first time to our knowledge, the in situ synthesis of large-scale ultrathin single-crystalline Co0.85Se nanosheets on graphene oxide (GO) sheets, with a thickness of 3 nm. Owing to the synergetic chemical coupling effects between GO and Co0.85Se, the Co0.85Se/graphene hybrid nanosheets exhibit the highest catalytic performance among the available cobalt chalcogenide-based catalysts for the oxygen reduction reaction (ORR). Moreover, Co0.85Se/graphene hybrid nanosheets can catalyze the decomposition of hydrazine hydrate rapidly, with 97% of hydrazine hydrate being degraded in 12 min and the degradation rate remaining constant over 10 consecutive cycles, thus having great potential as long-term catalysts in wastewater treatment.Ultrathin nanosheets possess novel electronic structures and physical properties as compared with their corresponding bulk samples. However, the controlled synthesis of ultrathin monolayer nanosheets still remains a great challenge due to the lack of an intrinsic driving force for anisotropic growth of two-dimensional (2D) structures. Here we demonstrate, for the first time to our knowledge, the in situ synthesis of large-scale ultrathin single-crystalline Co0.85Se nanosheets on graphene oxide (GO) sheets, with a thickness of 3 nm. Owing to the synergetic chemical coupling effects between GO and Co0.85Se, the Co0.85Se/graphene hybrid nanosheets exhibit the highest catalytic performance among the available cobalt chalcogenide-based catalysts for the oxygen reduction reaction (ORR). Moreover, Co0.85Se/graphene hybrid nanosheets can catalyze the decomposition of hydrazine hydrate rapidly

  13. Effects of ETA, pH change, and increased hydrazine levels on deposit-covered Alloy 600 and brass corrosion at Indian Point 2

    Energy Technology Data Exchange (ETDEWEB)

    Barkatt, A.; Labuda, E.; Wilder, D.M. [Catholic Univ. of America, Washington, DC (United States); Smialowska, S.; Rebak, R.B. [Ohio State Univ., Columbus, OH (United States). Fontana Corrosion Center; Cherepakhov, G. [Consolidated Edison Co. of New York, Inc., NY (United States); Burns, R.J. [Consolidated Edison Co. of New York, Inc., Buchanan, NY (United States)

    1997-12-01

    Chemical dissolution tests and electrochemical tests were carried out on Alloy 600 specimens covered with synthetic deposit simulating the tube deposits in the steam generators at Indian Point 2. The tests showed that the introduction of ETA and a moderate increase in pH gave rise to lower corrosion rates, but enhancement of hydrazine levels caused them to rise. In the case of brass, both types of tests showed that raising the pH caused the corrosion rates to increase, but the introduction of ETA led to mild decrease in these rates.

  14. ANTIMICROBIAL ACTIVITY EVALUATION OF SOME (Z)-2- (2-OXO-1-((ARYLAMINO)METHYL)INDOLIN-3-YLIDENE)-N- (4-(2-OXO-2H-CHROMEN-3-YL)THIAZOL-2-YL)HYDRAZINE- 1-CARBOXAMIDES

    OpenAIRE

    Mohd. Imran*

    2016-01-01

    Fourteen(Z)-2-(2-oxo-1-((arylamino)methyl)indolin-3-ylidene)-N-(4-(2-oxo-2H-chromen-3-yl)thiazol-2 yl)hydrazine-1-carboxamides 4a-4n were prepared by treating (Z)-N-(4-(2-oxo-2H-chromen-3-yl)thiazol-2-yl)-2-(2- oxoindolin-3-ylidene)hydrazine-1-carboxamide 3 with the aryl amines and formaldehyde. The chemical structures of these compounds were elucidated by their physical constants, spectral data and elemental analysis. These compounds were investigated for their antimicrobial activity against...

  15. Preparation of FeO(OH Modified with Polyethylene Glycol and Its Catalytic Activity on the Reduction of Nitrobenzene with Hydrazine Hydrate

    Directory of Open Access Journals (Sweden)

    Ke Ying Cai

    2016-10-01

    Full Text Available Iron oxyhydroxide was prepared by dropping ammonia water to Fe(NO33.9H2O dispersed in polyethylene glycol (PEG 1000. The catalyst was characterized by X-ray powder diffraction, Fourier transform infrared spectroscopy and laser particle size analyzer. The results showed the catalyst modified with polyethylene glycol was amorphous. The addition of PEG during the preparation make the particle size of the catalyst was smaller and more uniform. The catalytic performance was tested in the reduction of nitroarenes to corresponding amines with hydrazine hydrate, and the catalyst showed excellent activity and stability. Copyright © 2016 BCREC GROUP. All rights reserved Received: 2nd February 2016; Revised: 26th April 2016; Accepted: 7th June 2016 How to Cite: Cai, K.Y., Liu, Y.S., Song, M., Zhou, Y.M., Liu, Q., Wang, X.H. (2016. Preparation of FeO(OH Modified with Polyethylene Glycol and Its Catalytic Activity on the Reduction of Nitrobenzene with Hydrazine Hydrate. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (3: 363-368 (doi:10.9767/bcrec.11.3.576.363-368 Permalink/DOI: http://doi.org/10.9767/bcrec.11.3.576.363-368

  16. 二异丁腈肼母液残留丙酮氰醇的测定%Determination of Acetone Cyanohydrin in 1,2-Bis(2-cyano-2-propyl)-hydrazine Crystallization Mother Liquor

    Institute of Scientific and Technical Information of China (English)

    曹子英

    2013-01-01

      以丙酮氰醇和水合肼为原料缩合生成二异丁腈肼,结晶母液一般作为废水处理。通过对二异丁腈肼结晶母液特殊处理,用配位滴定法测定了丙酮氰醇的残留量,并对母液中水合肼的含量作出推算,为优化偶氮二异丁腈工艺,进行清洁工艺设计提供相关基础数据。%In the production of 1,2-bis(2-cyano-2-propyl)-hydrazine from acetone cyanohydrin and hydrazine hydrate by condensation reaction, crystallization mother liquor is generally treated as wastewater. In this paper, after special treatment of 1,2-bis(2-cyano-2-propyl)-hydrazine crystallization mother liquor, residual amount of acetone cyanohydrin was determined by complexometric titration method, and calculation of hydrazine hydrate content in the mother liquor was carried out, which provide relevant data for the optimization of azobisisobutyronitrile process and the design of cleaner process.

  17. NO{sub x}-abatement in bio-fuelled combustion units through catalytic reburning; Minskning av NO{sub x}-emissioner fraan biobraensleeldade anlaeggningar genom katalytisk reburning

    Energy Technology Data Exchange (ETDEWEB)

    Silversand, F.A. [Katator AB, Lund (Sweden)

    2000-03-01

    A study concerning the possibility of using catalytic reburning in the abatement of nitrogen oxides from bio-fuelled combustion units has been accomplished. In catalytic reburning, the fuel is combusted at a low excess-air-ratio to minimize the necessary amount of reburning gas added downstream the combustion chamber. The reburning fuel (a reducing agent, e.g. natural gas or LPG) will react catalytically with oxygen and nitrogen oxides in the reburning catalyst to produce carbon oxides, water and nitrogen. Secondary air is injected downstream the reburning catalyst to facilitate an effective combustion of remaining CO and hydrocarbons in the oxidation catalyst, usually in a tail-end position. Experiments were carried out in a small-scale combustion unit (10-20 kW{sub fuel} for pellets of bio-fuel). The results indicate possible conversion degrees of 90% with respect to nitrogen oxides, without increased emissions of CO and hydrocarbons. The economic evaluation indicates a great sensitivity to the price of the reburning fuel. Problems with uneven flow conditions and concentration gradients are expected to reduce the performance of catalytic reburning. Damages caused by corrosion at low oxygen concentrations are likely to occur in positions with high metal temperatures, e.g. in the super-heater-portion of the flue-gas-channel. Hydrocarbon-SCR is an alternative method to obtain a reasonable reduction of the emissions of nitrogen oxides. Small amounts of certain hydrocarbons (e.g. LPG) are added to the flue-gas-stream at a normal excess-air-ratio to obtain a conversion degree of 50 - 70% over a transition-metal-exchanged zeolite catalyst. Continued experiments should focus on installations in large bio-fuelled appliances, where a detailed technical and economical evaluation is possible. Especially catalyst deactivation needs to be evaluated further.

  18. A preliminary evaluation of post-combustion CO{sub 2} capture performance in a pilot plant test using mono-ethanolamine at a lignite-fuelled power station in Australia

    Energy Technology Data Exchange (ETDEWEB)

    Y. Artanto; M.I. Attalla; A. Cottrell; J. Jansen; J.M. McGregor; E.E.B. Meuleman; S. Morgan; M. Osborn; P. Pearson; L. Wardhaugh; P.H.M. Feron [CSIRO, Clayton, Vic. (Australia). Division of Energy Technology

    2009-07-01

    CSIRO has developed three PCC pilot plants to be connected to the flue gas of coal-fuelled power stations in Australia. Currently, two pilot plants are in operation. This paper presents results achieved with CSIRO's mobile plant which is fed with real flue gas from a lignite-fuelled power station at Loy Yang, Victoria, Australia. The findings of preliminary pilot plant trials are evaluated through comparison with results derived from WinSim Design II process simulation. The pilot plant operates with a 30% mono-ethanolamine (MEA) solution to capture CO{sub 2} under nominal conditions defined as a flue gas rate of 150 m{sup 3}/h and a solvent rate of 0.34 m{sup 3}/h. These conditions are set as the base-line for further experiments with different conditions. Different flue gas and solvent flow rates (three selected cases) were examined in the pilot plant in order to study the effects on CO{sub 2} recovery, heat reboiler duty, lean solvent loading and temperature profiles in the absorber columns. Gas and liquid sample analyses were used to determine the amount of CO{sub 2} recovered. The CO{sub 2} balance was also calculated in this study. The CO{sub 2} recovered (15-20 kg/h), based on liquid analysis, are below values from simulation modeling. The CO{sub 2} recovery is approximately 95% in simulation, while experiments indicate CO{sub 2} recovery of 60-83%. Preliminary results on comparing temperature profiles in the absorber columns show similar trends. 7 refs., 6 figs., 3 tabs.

  19. Electrochemical sensor for detection of hydrazine based on Au@Pd core–shell nanoparticles supported on amino-functionalized TiO{sub 2} nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xianlan [School of Science, Honghe University, Mengzi, Yunnan 661100 (China); College of Chemistry and Chemical Engineering, Qishan Campus, Fuzhou University, Fuzhou, Fujian 350108 (China); Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian 350002 (China); Liu, Wei [School of Science, Honghe University, Mengzi, Yunnan 661100 (China); Tang, Lele [College of Chemistry and Chemical Engineering, Qishan Campus, Fuzhou University, Fuzhou, Fujian 350108 (China); Wang, Jian [School of Science, Honghe University, Mengzi, Yunnan 661100 (China); Pan, Haibo, E-mail: hbpan@fzu.edu.cn [College of Chemistry and Chemical Engineering, Qishan Campus, Fuzhou University, Fuzhou, Fujian 350108 (China); Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian 350002 (China); Du, Min [Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Yishan Campus, Fuzhou University, Fuzhou, Fujian 350002 (China)

    2014-01-01

    In this paper, we reported a simple strategy for synthesizing well-defined TiO{sub 2}NTs–Au@Pd hybrid nanostructures with prior TiO{sub 2} nanotube functionalization (F-TiO{sub 2}NTs). TiO{sub 2}NTs with larger surface area (BET surface area is 184.9 m{sup 2} g{sup −1}) were synthesized by hydrothermal method, and the NTs are anatase phase with a range of 2–3 μm in length and 30–50 nm in diameter after calcined at 400 °C for 3 h. 3-Aminopropyl-trimethoxysilane (APTMS) as a coupling agent was reacted with the surface hydroxyl groups as anchoring sites for flower-shaped bimetallic Au@Pd nanostructures, self-assembling amine functionality on the surface of TiO{sub 2}NTs. Note that two faces at the interface between F-TiO{sub 2}NTs with (004) plane and Au@Pd nanostructures with (111) one of cubic Au and Pd nanoparticles are compatible, benefiting to the charge transfer between two components due to their crystalline coordination. The results showed that as-prepared F-TiO{sub 2}NTs–Au@Pd hybrid nanostructures modified glassy carbon electrode (GCE) exhibits high electrocatalytic activity toward hydrazine (N{sub 2}H{sub 4}) at low potential and a linear response from 0.06 to 700 μM with the detection limit for N{sub 2}H{sub 4} was found to be 1.2 × 10{sup −8} M (S/N = 3). Based on scan rate effect during the hydrazine oxidation, it indicates that the number of electrons transferred in the rate-limiting step is 1, and a transfer coefficient (α) is estimated as 0.73. The self-assembled F-TiO{sub 2}NTs–Au@Pd hybrid nanostructures as enhanced materials present excellent electrocatalytic activity, fast response, highly sensitive and have a promising application potential in nonenzymatic sensing. - Highlights: • Flower Au@Pd nanoparticles -TiO{sub 2} nanotubes (NTs) hybrid nanostructures were prepared by a self-assembled technique. • (004) plane of TiO{sub 2}NTs and (111) one of Au@Pd nanoparticles at the interface are compatible. • The electrochemical

  20. Hydrazine Sulfate (PDQ)

    Science.gov (United States)

    ... Grants Management Legal Requirements NCI Grant Policies Grant Management Contacts Other Funding Find NCI funding for small business innovation, technology transfer, and contracts Training Cancer Training at NCI ( ...

  1. Evaluation of Electrochemical Characteristics on Graphene Coated Austenitic and Martensitic Stainless Steels for Metallic Bipolar Plates in PEMFC Fabricated with Hydrazine Reduction Methods

    Energy Technology Data Exchange (ETDEWEB)

    Cha, Seong-Yun; Lee, Jae-Bong [School of Advanced Materials Engineering, Kookmin University, Seoul (Korea, Republic of)

    2016-04-15

    Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.

  2. Homogeneous and nanomolar detection of hydrazine by indigocarmine as a mediator at the surface of TiO2 nanoparticles modified carbon paste electrode

    Institute of Scientific and Technical Information of China (English)

    Mohammad Mazloum-Ardakani; Hossein Rajabi; Hadi Beitollahi

    2012-01-01

    The homogeneous electrocatalytic oxidation of hydrazine (HZ) has been studied by indigocarmine (IND) as a mediator at the surface of TiO2 nanoparticles modified carbon paste electrode (TNMCPE).Cyclic voltammetry was used to study the electrochemical behavior of IND at different scan rates.The voltammetric response of the modified electrode was linear against the concentration of HZ in the ranges of 3.0 × 10-8-7.0 × 10 -6 mol/L with differential pulse voltammetry method.The detection limit (3σ) was determined as 27.3 nmoL/L.To evaluate the applicability of the proposed method to real samples,the modified CPE was applied to the determination of HZ in water samples.

  3. N-methyl-2-(2-nitrobenzylidene) hydrazine carbothioamide-A new corrosion inhibitor for mild steel in 1 mol·L-1 hydrochloric acid

    Institute of Scientific and Technical Information of China (English)

    K Krishnaveni; K Sampath; J Ravichandran; C Jayabalakrishnan

    2015-01-01

    The corrosion inhibition of mild steel in 1 mol·L−1 hydrochloric acid by N-methyl-2-(2-nitrobenzylidene) hydrazine carbothioamide (MNBHC) was studied using weight loss and electrochemical studies. Results obtained indicate that the inhibitor is effective in hydrochloric acid medium and the efficiency decreases with increase in temperature. Added halide additives improve the efficiency of the inhibitor. The AC impedance studies reveal that the process of inhibition is through charge transfer. Polarization studies indicate the mixed nature of the in-hibitor. From the thermodynamic, spectral and surface analyses the nature of adsorption has been found out. The adsorption of the inhibitor on mild steel follows the Langmuir isotherm.

  4. The electroanalytical detection of hydrazine: a comparison of the use of palladium nanoparticles supported on boron-doped diamond and palladium plated BDD microdisc array.

    Science.gov (United States)

    Batchelor-McAuley, Christopher; Banks, Craig E; Simm, Andrew O; Jones, Timothy G J; Compton, Richard G

    2006-01-01

    We show that both a random distribution of palladium nanoparticles supported on a BDD electrode or a palladium plated BDD microelectrode array can each provide a sensing platform for the electrocatalytic detection of hydrazine. The palladium nanoparticle modified electrode displays a sensitivity and limit of detection of 60 mA mol(-1) L and 2.6 microM respectively while the array has a sensitivity of 8 mA mol(-1) L with a detection limit of 1.8 microM. The beneficial cost implications of using palladium nano- or micro-particles in sensors compared to a palladium macroelectrode are evident. Interestingly the array of the nanoparticles shows similar sensitivity and limit of detection to the microelectrode array which probably indicates that the random distribution of the former leads to 'clumps' of nanoparticles that effectively act as microelectrodes.

  5. A general method for preparing lanthanide oxide nanoparticles via thermal decomposition of lanthanide(III) complexes with 1-hydroxy-2-naphthoic acid and hydrazine ligands

    Science.gov (United States)

    Parimalagandhi, Karuppannan; Premkumar, Thathan; Vairam, Sundararajan

    2016-09-01

    Six new lanthanide(III) complexes (i.e., [Ln(L)2(NA)1.5]·3H2O, where Ln=La(III), Pr(III), Nd(III), Sm(III), Gd(III), and Ce(III) and L and NA indicate N2H4 and C10H6(1-O)(2-COO), respectively) with 1-hydroxy-2-naphthoic acid [C10H6(1-O)(2-COOH)] and hydrazine (N2H4) as co-ligands were characterized by elemental, FTIR, UV-visible, and XRD techniques. In the FT-IR spectra, the N-N stretching frequency in the range of 981-949 cm-1 demonstrates evidence of the presence of coordinated N2H4, indicating the bidentate bridging nature of hydrazine in the complexes. These complexes show symmetric and asymmetric COO- stretching from 1444 to 1441 cm-1 and 1582 to 1557 cm-1, respectively, indicating bidentate coordination. TG-DTA studies revealed that the compounds underwent endothermic dehydration from 98 to 110 °C. This was followed by the exothermic decomposition of oxalate intermediates to yield the respective metal oxides as the end products. From SEM images, the average size of the metal oxide particles prepared by thermal decomposition of the complexes was determined to be 39-42 nm. The powder X-ray and SEM coupled with energy dispersive X-ray (EDX) studies revealed the presence of the respective nano-sized metal oxides. The kinetic parameters of the decomposition of the complexes were calculated using the Coats-Redfern equation.

  6. Preparation, characterization, non-isothermal reaction kinetics, thermodynamic properties, and safety performances of high nitrogen compound: Hydrazine 3-nitro-1,2,4-triazol-5-one complex

    Energy Technology Data Exchange (ETDEWEB)

    Yi Jianhua [Xi' an Modern Chemistry Research Institute, Xi' an 710065 (China); Zhao Fengqi [Xi' an Modern Chemistry Research Institute, Xi' an 710065 (China)], E-mail: yiren@nwu.edu.cn; Gao Hongxu; Xu Siyu; Wang Minchang; Hu Rongzu [Xi' an Modern Chemistry Research Institute, Xi' an 710065 (China)

    2008-05-01

    A new high nitrogen compound hydrazine 3-nitro-1,2,4-triazol-5-one complex (HNTO) was prepared by the reaction of 3-nitro-1,2,4-triazol-5-one with hydrazine hydrate, and its structure was characterized by means of organic elemental analyzer, FT-IR, XRD, {sup 13}C NMR and {sup 15}N NMR. The non-isothermal reaction kinetics of the main exothermic decomposition reaction of HNTO was investigated by means of DSC. The thermodynamic properties of HNTO were calculated. The results showed that the formation of HNTO is achieved by proton transfer of N(4) atom, and it makes a higher nitrogen content and lower acidity. The reaction mechanism of HNTO is classified as nucleation and growth, and the mechanism function is Avramo-Erofeev equation with n = 2/5. The kinetic parameters of the reaction are E{sub a} = 195.29 kJ mol{sup -1}, lg(A (s{sup -1})) = 19.37, respectively. The kinetic equation can be expressed as: (d{alpha})/(dt) =10{sup 18.97}(1-{alpha})[-ln(1-{alpha})]{sup 3/5}e{sup -2.35x10{sup 4}/T} The safety performances of HNTO were carried out. The critical temperature of thermal explosion are 464.26 and 474.37 K, the adiabatic time-to-explosion is 262 s, the impact sensitivity H{sub 50} = 45.7 cm, the friction sensitivity P = 20% and the electrostatic spark sensitivity E{sub 50} > 5.4 J (no ignition). It shows that HNTO has an insensitive nature as RDX and NTO, etc.

  7. Study of Supported Nickel Catalysts Prepared by Aqueous Hydrazine Method. Hydrogenating Properties and Hydrogen Storage: Support Effect. Silver Additive Effect; Catalyseurs de nickel supportes prepares par la methode de l'hydrazine aqueuse. Proprietes hydrogenantes et stockage d'hydrogene. Effet du support. Effet de l'ajout d'argent

    Energy Technology Data Exchange (ETDEWEB)

    Wojcieszak, R

    2006-06-15

    We have studied Ni or NiAg nano-particles obtained by the reduction of nickel salts (acetate or nitrate) by hydrazine and deposited by simple or EDTA-double impregnation on various supports ({gamma}-Al{sub 2}O{sub 3}, amorphous or crystallized SiO{sub 2}, Nb{sub 2}O{sub 5}, CeO{sub 2} and carbon). Prepared catalysts were characterized by different methods (XRD, XPS, low temperature adsorption and desorption of N{sub 2}, FTIR and FTIR-Pyridine, TEM, STEM, EDS, H{sub 2}-TPR, H{sub 2}-adsorption, H{sub 2}-TPD, isopropanol decomposition) and tested in the gas phase hydrogenation of benzene or as carbon materials in the hydrogen storage at room temperature and high pressure. The catalysts prepared exhibited better dispersion and activity than classical catalysts. TOF's of NiAg/SiO{sub 2} or Ni/carbon catalysts were similar to Pt catalysts in benzene hydrogenation. Differences in support acidity or preparation method and presence of Ag as metal additive play a crucial role in the chemical reduction of Ni by hydrazine and in the final properties of the materials. Ni/carbon catalysts could store significant amounts of hydrogen at room temperature and high pressure (0.53%/30 bars), probably through the hydrogen spillover effect. (author)

  8. Direct Democracy

    DEFF Research Database (Denmark)

    Doerr, Nicole

    2013-01-01

    Direct democracy describes a theory of democracy and a form of collective decision-making in which sovereignty is directly exercised by the people. Democracy is direct if it is characterized by citizens making all decisions together with a maximum of equal participation. Direct democracy can...

  9. EVALUATION OF THE PERFORMANCE AND EMISSION CHARACTERISTICS OF A 4-STROKE SINGLE CYLINDER DIRECT INJECTION DIESEL ENGINE FUELLED WITH SESAME METHYL ESTER AND DIESEL FUEL BLENDS--AN EXPERIMENTAL INVESTIGATION

    Energy Technology Data Exchange (ETDEWEB)

    Rajashekhar S. Hosmath [K.L.E' s College of Engineering and Technology, Belgaum (India); P. Mohanan [National Institute of Technology Karnataka, Surathkal (India)

    2008-09-30

    India produces only about 33% of her annual crude oil requirement of 105 MT, relying on imports to the tune of Rs. 1,06,875 crores for meeting the remaining requirement in 2005. There is a need to search and find ways of using fuels that are preferably renewable, clean burning fuels. Today, India and China are the world's largest producers of sesame, followed by Burma, Sudan, Mexico, Nigeria, Venezuela, Turkey, Uganda and Ethiopia. 25% of the world production is from India. Sesame seeds contain about 50% oil compositions as compared to 20% oil in soybeans. In view of this Sesame oil could be regarded as an alternative fuel for CI engine applications

  10. Synthesis of Au nanoparticles decorated graphene oxide nanosheets: Noncovalent functionalization by TWEEN 20 in situ reduction of aqueous chloroaurate ions for hydrazine detection and catalytic reduction of 4-nitrophenol

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Wenbo [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin (China); Ning, Rui [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Qin, Xiaoyun; Zhang, Yingwei; Chang, Guohui; Liu, Sen; Luo, Yonglan [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin (China); Sun, Xuping, E-mail: sunxp@ciac.jl.cn [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin (China)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer TWEEN 20 is used as a stabilizing agent for GO as well as a reducing and immobilizing agent for Au nanoparticles. Black-Right-Pointing-Pointer The hydrazine sensor based on the nanocomposites has a fast amperometric response. Black-Right-Pointing-Pointer The detection limit of the hydrazine sensor is estimated to be 78 nM. Black-Right-Pointing-Pointer The nanocomposites also exhibit good catalytic activity toward 4-nitrophenol reduction. - Abstract: In this paper, we develop a cost-effective and simple route for the synthesis of Au nanoparticles (AuNPs) decorated graphene oxide (GO) nanosheets using polyoxyethylene sorbitol anhydride monolaurate (TWEEN 20) as a stabilizing agent for GO as well as a reducing and immobilizing agent for AuNPs. The AuNPs assemble on the surface of TWEEN-functionalized GO by the in situ reduction of HAuCl{sub 4} aqueous solution. The morphologies of these composites were characterized by atomic force microscopy (AFM) and transmission electron microscopy (TEM). It is found that the resultant AuNPs decorated GO nanosheets (AuNPs/TWEEN/GO) exhibit remarkable catalytic performance for hydrazine oxidation. This hydrazine sensor has a fast amperometric response time of less than 3 s. The linear range is estimated to be from 5 {mu}M to 3 mM (r = 0.999), and the detection limit is estimated to be 78 nM at a signal-to-noise ratio of 3. The AuNPs/TWEEN/GO composites also exhibit good catalytic activity toward 4-nitrophenol (4-NP) reduction and the GO supports also enhance the catalytic activity via a synergistic effect.

  11. A QSAR/QSTR study on the human health impact of the rocket fuel 1,1-dimethyl hydrazine and its transformation products Multicriteria hazard ranking based on partial order methodologies.

    Science.gov (United States)

    Carlsen, Lars; Kenessov, Bulat N; Batyrbekova, Svetlana Ye

    2009-05-01

    The possible impact of the rocket fuel 1,1-dimethyl hydrazine (heptyl) (1) and its transformation products on human health has been studied using (Quantitative) Structure Activity/Toxicity ((Q)SAR/(Q)STR) modelling, including both ADME models and models for acute toxicity, organ specific adverse haematological effects, the cardiovascular and gastrointestinal systems, the kidneys, the liver and the lungs, as well as a model predicting the biological activity of the compounds. It was predicted that all compounds studied are readily bioavailable through oral intake and that significant amounts of the compounds will be freely available in the systemic circulation. In general, the compounds are not predicted to be acutely toxic apart from hydrogen cyanide, whereas several compounds are predicted to cause adverse organ specific human health effects. Further, several compounds are predicted to exhibit high probabilities for potential carcinogenicity, mutagenicity, teratogenicity and/or embryotoxicity. The compounds were ranked based on their predicted human health impact using partial order ranking methodologies that highlight which compounds on a cumulative basis should receive the major attention, i.e., N-nitroso dimethyl amine, 1,1,4,4-tetramethyl tetrazene, trimethyl, trimethyl hydrazine, acetaldehyde dimethyl hydrazone, 1, 1-formyl 2,2-dimethyl hydrazine and formaldehyde dimethyl hydrazone, respectively.

  12. Synthsis of salicylidene condensation hydrazine dithiocarbamate benzyl ester%水杨醛缩肼基二硫代甲酸苄酯类Schiff碱配体的合成

    Institute of Scientific and Technical Information of China (English)

    苏新立; 贾真; 刘秋平; 强根荣

    2011-01-01

    由水合肼、CS2与取代的溴化苄在低温条件下反应,合成肼基二硫代甲酸苄酯类化合物,再在无水乙醇体系中及高温回流条件下与取代的水杨醛进行反应,合成了一系列标题化合物,其结构经质谱、紫外光谱、红外光谱、元素分析及1H核磁共振等进行表征.%Hydrazine dithiocarbamate benzyl ester was synthesized by reaction of the hydrazine hydrate, CS2 and substituted benzyl bromide at low temperature.Then a series of substituted salicylidene condensation hydrazine dithiocarbamate benzyl esters were synthesized at high temperature reflowing with absolute ethanol as solvent.The structures of samples were confirmed by MS, UV, IR and elemental analysis.

  13. Directed homology

    DEFF Research Database (Denmark)

    Fahrenberg, Uli

    2004-01-01

    We introduce a new notion of directed homology for semicubical sets. We show that it respects directed homotopy and is functorial, and that it appears to enjoy some good algebraic properties. Our work has applications to higher-dimensional automata.......We introduce a new notion of directed homology for semicubical sets. We show that it respects directed homotopy and is functorial, and that it appears to enjoy some good algebraic properties. Our work has applications to higher-dimensional automata....

  14. Effect of coriander seed powder (CSP) on 1, 2-dimethyl hydrazine-induced changes in antioxidant enzyme system and lipid peroxide formation in rats.

    Science.gov (United States)

    Anilakumar, K R; Khanum, Farhath; Bawa, A S

    2010-03-01

    The effect of coriander seed powder (CSP), a culinary spice, on dimethyl hydrazine (DMH)-induced oxidative stress and toxicity in rats was investigated. Six groups of 6 male rats each were maintained for 12 weeks as (a) Control; (b) DMH (60 mg/kg body weight) injected; (c) 5% CSP incorporated diet; (d) 5% CSP incorporated diet + DMH; (e) 10% CSP incorporated diet; and (f) 10% CSP incorporated diet + DMH. The rats were sacrificed after 12 weeks. The results revealed that DMH administration lead to an increase in hepatic lipid peroxidation associated with reduction in levels of glutathione (GSH), activity of superoxide dismutase (SOD), and catalase and glucose-6-phosphate dehydrogenase. The coadministration of CSP and DMH diminished the hepatic malondialdehyde (MDA) significantly as compared to DMH-alone administered rats. The intake of coriander seeds at 10% level also enhanced the hepatic GSH-redox system by elevating GSH-Px, GSSGR, and GST activities. The DMH-induced decline in SOD and catalase activities was brought to normal by 10% CSP. The coadministration of CSP and the DMH produced a significant reduction in MDA and enhancement in catalase activity as compared to control. Coriander powder at 5% and 10% levels produced a significant rise in colonic catalase and GSH-Px. The coriander seeds produced significant beneficial effects by reducing the DMH-induced oxidative stress and enhancing the tissue levels of antioxidant/detoxification agent in tissues.

  15. Experimental and theoretical study of crystal and molecular structure of 1,2-di(9H-fluoren-9-ylidene)hydrazine

    Science.gov (United States)

    Lasri, Jamal; Eltayeb, Naser Eltaher; Ismail, Ali I.

    2016-10-01

    The molecular structure and spectroscopic properties of 1,2-di(9H-fluoren-9-ylidene)hydrazine were studied experimentally by ESI-MS, FTIR, NMR and UV-Vis techniques and computationally by the density functional theory (DFT) method at B3LYP/6-31+G(d,p) level of theory. XRD single crystal showed that the molecule is crystalline as a monoclinic with space group P21/n, the crystal parameters are a, b, c (Å) 11.164(3), 5.9761(16) and 13.457(3), respectively. Also, β (°) and Z were found to be 103.822(12) and 2, respectively. The theoretical vibrational frequencies obtained by DFT calculations are in good agreement with the experimental values. TD-DFT calculations were carried out in both gas phase and in different solvent systems using polarizable continuum model (PCM) to calculate the electronic absorption spectra. GIAO method was used to calculate the NMR spectra in four different solvents CD3CN, CDCl3, DMSO-d6 and MeOD-d4. The correlation between the calculated and experimental chemical shifts was mostly in the range of 0.87-0.97 for 1H, whereas, the correlation for 13C in all solvents was 0.98.

  16. One-pot synthesis of core-shell Cu@SiO2 nanospheres and their catalysis for hydrolytic dehydrogenation of ammonia borane and hydrazine borane

    Science.gov (United States)

    Yao, Qilu; Lu, Zhang-Hui; Zhang, Zhujun; Chen, Xiangshu; Lan, Yaqian

    2014-12-01

    Ultrafine copper nanoparticles (Cu NPs) within porous silica nanospheres (Cu@SiO2) were prepared via a simple one-pot synthetic route in a reverse micelle system and characterized by SEM, TEM, EDX, XRD, N2 adsorption-desorption, CO-TPD, XPS, and ICP methods. The characterized results show that ultrafine Cu NPs with diameter of around 2 nm are effectively embedded in the center of well-proportioned spherical SiO2 NPs of about 25 nm in diameter. Compared to commercial SiO2 supported Cu NPs, SiO2 nanospheres supported Cu NPs, and free Cu NPs, the synthesized core-shell nanospheres Cu@SiO2 exhibit a superior catalytic activity for the hydrolytic dehydrogenation of ammonia borane (AB, NH3BH3) and hydrazine borane (HB, N2H4BH3) under ambient atmosphere at room temperature. The turnover frequencies (TOF) for the hydrolysis of AB and HB in the presence of Cu@SiO2 nanospheres were measured to be 3.24 and 7.58 mol H2 (mol Cu min)-1, respectively, relatively high values for Cu nanocatalysts in the same reaction. In addition, the recycle tests show that the Cu@SiO2 nanospheres are still highly active in the hydrolysis of AB and HB, preserving 90 and 85% of their initial catalytic activity even after ten recycles, respectively.

  17. Seasonal dynamics of anammox bacteria in estuarial sediment of the Mai Po Nature Reserve revealed by analyzing the 16S rRNA and hydrazine oxidoreductase (hzo) genes.

    Science.gov (United States)

    Li, Meng; Cao, Huiluo; Hong, Yi-Guo; Gu, Ji-Dong

    2011-01-01

    The community and population dynamics of anammox bacteria in summer (wet) and winter (dry) seasons in estuarial mudflat sediment of the Mai Po Nature Reserve were investigated by 16S rRNA and hydrazine oxidoreductase (hzo) genes. 16S rRNA phylogenetic diversity showed that sequences related to 'Kuenenia' anammox bacteria were presented in summer but not winter while 'Scalindua' anammox bacteria occurred in both seasons and could be divided into six different clusters. Compared to the 16S rRNA genes, the hzo genes revealed a relatively uniform seasonal diversity, with sequences relating to 'Scalindua', 'Anammoxoglobus', and planctomycete KSU-1 found in both seasons. The seasonal specific bacterial groups and diversity based on the 16S rRNA and hzo genes indicated strong seasonal community structures in estuary sediment of this site. Furthermore, the higher abundance of hzo genes in summer than winter indicates clear seasonal population dynamics. Combining the physicochemical characteristics of estuary sediment in the two seasons and their correlations with anammox bacteria community structure, we proposed the strong seasonal dynamics in estuary sediment of Mai Po to be due to the anthropogenic and terrestrial inputs, especially in summer, which brings in freshwater anammox bacteria, such as 'Kuenenia', interacting with the coastal marine anammox bacteria 'Scalindua'.

  18. QSAR and 3D-QSAR studies of the diacyl-hydrazine derivatives containing furan rings based on the density functional theory

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    QSAR studies of 27 diacyl-hydrazine derivatives containing furan rings were conducted and compared with the DFT method and AM1-MOPAC method.q2 values of 0.61 and 0.40 validated the predictability and reliability of eq.(5) from the DFT method were higher than those of eq.(6) from the AM1-MOPAC method.The DFT-optimized conformations and ESP-fitting charges of the target compounds were also used for 3D-QSAR analysis,including CoMFA and CoMSIA.The leave-one-out cross-validation correlation coefficient and the good correlation between the predicted and experimental activities of excluded test compounds revealed that CoMFA and CoMSIA models were robust.The QSAR results were consistent with the 3D-QSAR results,indicating that the electrostatic and hydrophobic properties of the target compounds were significant to the biological activity.These models are useful tools for predicting the larvicidal activities of new compounds and designing new specific insect growth regulators.

  19. A combined experimental and DFT study of a novel unsymmetrical azine 2-(4-methoxybenzylidene)-1-(1-(4-isobutylphenyl) ethylidene) hydrazine

    Science.gov (United States)

    Vijaya, P.; Sankaran, K. R.

    2015-03-01

    A novel unsymmetrical azine 2-(4-methoxybenzylidene)-1-(1-(4-isobutylphenyl) ethylidene) hydrazine (UA) was prepared and characterized by IR, 1H and 13C NMR spectral studies. A 2D - potential energy scan (PES) of p-isobutylacetophenone (IBAP) was the portal to the conformational analysis of UA by density functional theory (DFT) methods using 6-31G(d,p) basis set by Gaussian 03 program. The theoretical IR frequencies were found to be in good agreement with the experimental values. The IR frequencies of UA were analyzed by means of Potential energy Distribution (PED %) calculation using Vibrational Energy Distribution Analysis (VEDA 4) program. The experimental NMR chemical shift values of UA were compared with the theoretical values obtained by DFT method. Nonlinear optical behavior of the unsymmetrical azine is also examined by the theoretically predicted values of dipole moment (μ), polarizability (α0) and first hyperpolarizability (βtot). Stability of the UA molecule has been analyzed using NBO analysis. The electrochemistry of UA studied experimentally by cyclic voltammetry is complemented by the computational analysis of the anionic form of the molecule UA. The determination of various global and local reactivity descriptors in the context of chemical reactivity is also performed and the electrophilicity at the vital atomic sites in UA is revealed. Bader's Atoms in molecules (AIM) theory of UA indicated the presence of intramolecular hydrogen bonding in the molecule. The molecular electrostatic potential (MEP) and HOMO-LUMO orbital analysis are also performed for the molecule UA.

  20. Synthesis, spectroscopic, anticancer, antibacterial and antifungal studies of Ni(II) and Cu(II) complexes with hydrazine carboxamide, 2-[3-methyl-2-thienyl methylene

    Science.gov (United States)

    Chandra, Sulekh; Vandana; Kumar, Suresh

    2015-01-01

    Schiff's base ligand(L) hydrazine carboxamide, 2-[3-methyl-2-thienyl methylene] and its metal complexes have been synthesized and characterized by elemental analysis, molar conductance, various spectroscopic techniques such as electronic, IR, 1H NMR, mass, EPR. Molar conductance of complexes in DMF solution corresponds to non-electrolyte. Complexes have general composition [M(L)2X2], where M = Ni(II) and Cu(II), X = Cl-, NO3-, CH3COO- and ½SO42-. On the basis of above spectral studies, an octahedral geometry has been assigned for Ni(II) complexes and tetragonal geometry for Cu(II) complexes except [Cu(L)2SO4] which possesses five coordinated trigonal bipyramidal geometry. These metal complexes were also tested for their anticancer, antibacterial and antifungal activities to assess their inhibition potential. Anticancer activity of ligand and its metal complexes were evaluated using SRB fluorometric assay and Adriamycin (ADR) was applied as positive control. Schiff's base ligand and its metal complexes were screened for their antibacterial and antifungal activity against Escherichia coli, Bacillus cereus and Aspergillus niger, Aspergillus flavus, respectively. Kirby-Bauer single disk susceptibility test was used for antibacterial activity and well diffusion method for antifungal activity of the compounds on the used fungi.

  1. Application of pentafluorophenyl hydrazine derivatives to the analysis of nabumetone and testosterone in human plasma by liquid chromatography-atmospheric pressure chemical ionization-tandem mass spectrometry.

    Science.gov (United States)

    Sheen, J F; Her, G R

    2004-12-01

    Two carbonyl compounds, nabumetone and testosterone, were derivatized with pentafluorophenyl hydrazine (PFPH) and analyzed by atmospheric-pressure chemical-ionization mass spectrometry. The PFPH derivatives underwent dissociative electron capture in negative-ion APCI (ECAPCI) and gave intense [M-20](-) ions in the mass spectra. In positive-ion APCI, the PFPH derivatives underwent efficient protonation and gave intense [M + H](+) ions in the mass spectra. In CID, the major product ions of the [M-20](-) ions in ECAPCI corresponded to the partial moiety of PFPH. In contrast, the major product ions of [M + H](+) corresponded to the partial moiety of the analyte. By using selected reaction monitoring (SRM) detection, low pg of nabumetone (1 pg) and testosterone (7 pg) could be detected in both ECAPCI and positive-ion APCI. In comparison with the detection limits (SRM) of the underivatized analytes, use of the PFPH derivatives resulted in 2500-fold and 35-fold sensitivity enhancements for nabumetone and testosterone, respectively. The PFPH derivatives were applied to the analysis of nabumetone and testosterone in human plasma by both ECAPCI and positive-ion APCI and were found to enable detection of 0.1 ng mL(-1) nabumetone in spiked plasma. For testosterone, endogenous testosterone in female plasma was detected in both ECAPCI and positive-ion APCI.

  2. π-Delocalization in the vicinal lone pairs of hydrazines: Electronic effects in derivatives of 1-(2-nitrophenyl)-1-phenylhydrazine

    Science.gov (United States)

    Poisson, Joël; Butler, Ian S.; Bohle, D. Scott

    2016-07-01

    Several highly colored, crystalline derivatives of 1-(2-nitrophenyl)-1-phenylhydrazine have been synthesized and characterized by UV-Vis, 1H- and 13C-NMR, mass and IR spectroscopic methods, as well as by single-crystal X-ray diffraction and combustion elemental analysis. The study indicates that the electronic dependence of one nitrogen atom on the other in these systems becomes more pronounced with a decrease in the difference of their formal hybridization. While 1,1-di-aromatic substitution leads to a formal sp2 hybridization at one nitrogen atom, introduction of a π-bond in the form of a Schiff base or an acetylamide function at the second nitrogen atom leads to different hydrazine conformations and N-N bond lengths. One interpretation of these results is that, in many cases, a greater contribution from σ-bonding from two sp2 hybridized nitrogen atoms leads to stronger and shorter N-N bonds than do the often proposed N-N π-bonding double bonds in the absence of significant intermolecular forces.

  3. Direct Democracy

    DEFF Research Database (Denmark)

    Beramendi, Virginia; Ellis, Andrew; Kaufman, Bruno

    While many books on direct democracy have a regional or national approach, or simply focus on one of the many mechanisms associated with direct democracy, this Handbook delves into a global comparison of direct democracy mechanisms, including referendums, citizens' initiatives, agenda initiatives...... included as a chapter in the Handbook are possible measures for best practices of implementation, designed for those who wish to tailor direct democracy instruments to their specific needs. In order to further complement the best practices, a variety of global case studies detail the practical uses...... of direct democracy mechanisms in specific contexts. These country case studies allow for in depth discussion of particular issues, including signature collection and voter participation, campaign financing, media coverage, national variations in the usage of direct democracy procedures and national lessons...

  4. Direct Democracy

    DEFF Research Database (Denmark)

    Beramendi, Virginia; Ellis, Andrew; Kaufman, Bruno

    While many books on direct democracy have a regional or national approach, or simply focus on one of the many mechanisms associated with direct democracy, this Handbook delves into a global comparison of direct democracy mechanisms, including referendums, citizens' initiatives, agenda initiatives...... valuable information regarding the binding or non-binding nature of referendums, as well as issues that can be brought forth to a referendum....

  5. Performance of diesel engine fuelled with sunflower biodiesel blends; Desempenho de motor diesel com misturas de biodiesel de oleo de girassol

    Energy Technology Data Exchange (ETDEWEB)

    Correa, Ila Maria; Maziero, Jose Valdemar Gonzalez; Bernardi, Jose Augusto; Storino, Moises [Instituto Agronomico de Campinas (CEA/IAC), SP (Brazil). Centro de Engenharia e Automacao; Ungaro, Maria Regina [Instituto Agronomico de Campinas (IAC), SP (Brazil). Centro de Graos e Fibras

    2006-07-01

    The aim of this paper was to evaluate the use of sunflower bio diesel blends in a CI engine, direct injection. The test procedure was done in a dynamometer bench had been determined the performance of engine through power take-off (PTO) with use of diesel and sunflower bio diesel blends (B5, B10, B20 and B100). The lubricating oil was analyzed before and after period of 96 hours. The results were: D (40,7 kw; 271 g/kw.h); B5 (40,3 kw; 271 g/kw.h); B10 (39,8 kw; 277 g/kw.h); B20 (40,0 kw; 277 g/kw.h) e B100 (39,8 kw; 291 g/kw.h). It was conclude that the use of blends B5, B10, B20 and B100 decreased the power of PTO max. 2,2% and increased the fuel consumption max. 7, 3%. The analyze of lubricating oil showed that the viscosity, water content and level of iron were the parameters more affected, although it had been acceptable. (author)

  6. On the effect of Di-Ethyl-Ether (DEE) injection upon the cold starting of a biodiesel fuelled compression ignition engine

    Science.gov (United States)

    Clenci, Adrian; Niculescu, Rodica; Iorga-Simǎn, Victor; Tricǎ, Alina; Danlos, Amélie

    2017-02-01

    The use of biodiesel fuel in compression ignition engines has the potential to reduce CO2, which can lead to a reduction in global warming and environmental hazards. Biodiesel is an attractive fuel, as it is made from renewable resources. A major drawback associated with the use of biodiesel, however, is its poor cold flow properties, which have a direct influence on the cold starting performance of the engine. This paper is a consequence of a study on assessing the cold-starting performance of a compression ignition engine fueled with different blends of fossil diesel fuel and biodiesel. Through experimental investigations, it was found that the engine starting at -20°C was no longer possible in the case of using B50 (50% diesel + 50% biofuel made from sunflower oil). In order to "force" the engine starting in this particular situation, Di-Ethyl-Ether (DEE) was injected into the intake manifold. DEE being a highly flammable substance, the result was a sudden and explosive engine starting, the peak pressure in the monitored cylinder in the first successful engine cycle being almost twice the one which is usually considered as normal. Thus, to explain the observed phenomena, we launched this work relying on the analysis of the in-cylinder instantaneous pressure evolution, which was acquired during cranking, stabilizing and idling phases. Moreover, since the cause of the sudden and explosive engine starting was the DEE, by using a CFD approach, we also obtained results regarding the inter-cylinder distribution of the injected DEE.

  7. Early spawning of Antarctic krill in the Scotia Sea is fuelled by “superfluous” feeding on non-ice associated phytoplankton blooms

    Science.gov (United States)

    Schmidt, Katrin; Atkinson, Angus; Venables, Hugh J.; Pond, David W.

    2012-01-01

    The spawning success of Antarctic krill ( Euphausia superba) is generally assumed to depend on substantial winter sea ice extent, as ice biota can serve as a food source during winter/spring and the seasonal ice melt conditions the upper water column for extensive phytoplankton blooms. However, direct observations during spring are rare. Here we studied krill body condition and maturity stage in relation to feeding (i.e. stomach fullness, diet, absorption of individual fatty acids and defecation rate) across the Scotia Sea in November 2006. The phytoplankton concentrations were low at the marginal ice zone (MIZ) in the southern Scotia Sea (Stn. 1, 2, and 3), high in open waters of the Southern Antarctic Circumpolar Current Front (SACCF) in the central Scotia Sea (Stn. 5), and moderate further north (Stn. 6 and 7). Krill had low lipid reserves (˜6.5% of dry mass, DM), low mass:length ratios (˜1.7 mg DM mm -1), and small digestive glands (˜7% of total DM) near the ice edge. The stomachs contained lithogenic particles, diatom debris, and bacterial fatty acids, but low proportions of diatom-indicating fatty acids, which suggest that these krill were feeding on detritus rather than on fresh ice algae. In the SACCF, krill had higher lipid reserves (˜10% of DM), high mass:length ratios (˜2.2 mg DM mm -1), and large digestive glands (˜16% of total DM). Stomach content and tissue composition indicate feeding on diatoms. In the north, moderate food concentrations co-occurred with low lipid reserves in krill, and moderate mass:length ratios and digestive gland sizes. Only in the phytoplankton bloom in the SACCF had the mating season already started and some females were about to spawn. Based on the way krill processed their food at the different stations, we indicate two mechanisms that can lead to fast regeneration of body reserves and oocyte maturation in E. superba. One is "superfluous" feeding at high food concentrations, which maximises the overall nutrient gain

  8. Synthesis of octahedral, truncated octahedral, and cubic Rh2Ni nanocrystals and their structure-activity relationship for the decomposition of hydrazine in aqueous solution to hydrogen

    Science.gov (United States)

    Li, Chun; Wang, Tao; Chu, Wei; Wu, Ping; Tong, Dong Ge

    2016-03-01

    We developed a co-reduction method to synthesize octahedral, truncated octahedral, and cubic Rh2Ni nanocrystals. The shape/size distribution, structural characteristics, and composition of the Rh2Ni nanocrystals are investigated, and their possible formation mechanism at high temperatures in margaric acid/1-aminoheptadecane solution in the presence of tetraethylgermanium and borane trimethylamine complexes is proposed. A preliminary probing of the structure-activity dependence of the surface ``clean'' Rh2Ni nanocrystals supported on carbon towards hydrazine (N2H4) in aqueous solution dehydrogenation revealed that the higher the percentage of {111} facets, the higher is the activity and H2 selectivity of the nanocrystals. This result was attributed to the {111} facets not only introducing more basic sites, but also weakening the interaction between the produced adspecies (including H2 and NHx) and surface metal atoms in comparison with those of {100} facets. Furthermore, the as-prepared Rh2Ni nanooctahedra exhibited 100% H2 selectivity and high activity at room temperature for H2 generation via N2H4 decomposition. The activation energy of the Rh2Ni nanooctahedra was 41.6 +/- 1.2 kJ mol-1. The Rh2Ni nanooctahedra were stable catalysts for the hydrolytic dehydrogenation of N2H4, providing 27 723 total turnovers in 30 h. Our work provides a new perspective concerning the possibility of constructing hydrogen-producing systems based on N2H4 and surface ``clean'' Rh2Ni nanocrystal catalysts with defined shapes supported on carbon that possess a competitive performance in comparison with NaBH4 and NH3BH3 hydrogen-producing systems for fuel cell applications.We developed a co-reduction method to synthesize octahedral, truncated octahedral, and cubic Rh2Ni nanocrystals. The shape/size distribution, structural characteristics, and composition of the Rh2Ni nanocrystals are investigated, and their possible formation mechanism at high temperatures in margaric acid/1

  9. Directing Creativity

    DEFF Research Database (Denmark)

    Darsø, Lotte; Ibbotson, Piers

    2008-01-01

    In this article we argue that leaders facing complex challenges can learn from the arts, specifically that leaders can learn by examining how theatre directors direct creativity through creative constraints. We suggest that perceiving creativity as a boundary phenomenon is helpful for directing it....... Like leaders, who are caught in paradoxical situations where they have to manage production and logistics simultaneously with making space for creativity and innovation, theatre directors need to find the delicate balance between on one hand renewal of perceptions, acting and interaction...... and on the other hand getting ready for the opening night. We conclude that the art of directing creativity is linked to developing competencies of conscious presence, attention and vigilance, whereas the craft of directing creativity concerns communication, framing and choice....

  10. Future directions.

    Science.gov (United States)

    Raffa, Robert B; Tallarida, Ronald J

    2010-01-01

    The chapters of this book summarize much of what has been done and reported regarding cancer chemotherapy-related cognitive impairment. In this chapter, we point out some future directions for investigation.

  11. Preparation of CuO/NiO composite nanofibers by electrospinning and their application for electro-catalytic oxidation of hydrazine

    Science.gov (United States)

    Hosseini, Sayed Reza; Ghasemi, Shahram; Kamali-Rousta, Mina

    2017-03-01

    In present work, polyvinyl alcohol/copper acetate-nickel acetate composite nanofibers (PVA/Cu(OAc)2-Ni(OAc)2 NFs) with various weight percentages of Cu(OAc)2:Ni(OAc)2 such as 25:75, 50:50 and 75:25 are fabricated by electrospinning method. After this, the CuO/NiO composite NFs are produced after thermal treatment. A calcination temperature at about 600 °C is determined by thermal gravimetric analysis. Field-emission scanning electron microscopy (FE-SEM) for morphology characterization indicates that large quantities of the prepared PVA/Cu(OAc)2-Ni(OAc)2 composite fibers have smooth and bead-free surfaces. Fourier transform infrared spectroscopy, FE-SEM and energy dispersive X-ray spectroscopy are used to characterize the CuO/NiO composites. According to FE-SEM results, with increasing of Cu(OAc)2 content in polymeric solution, the fibers don't remain as continuous structures after calcination and accumulate in the form of nanoparticles. Also, a carbon paste electrode (CPE) bulky modified with CuO/NiO composites is used for investigation of the electro-catalytic oxidation of hydrazine hydrate in NaOH solution. The catalytic activities of the synthesized catalysts are studied through cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy. The obtained results demonstrate that the most appropriate proportion of Cu(OAc)2:Ni(OAc)2 in electrospinning solution to enhance the electro-catalytic ability is 25:75.

  12. Enhanced therapeutic efficacy and amelioration of cisplatin-induced nephrotoxicity by quercetin in 1,2-dimethyl hydrazine-induced colon cancer in rats.

    Science.gov (United States)

    Li, Qing-Chun; Liang, Yun; Hu, Guang-Rui; Tian, Yuan

    2016-01-01

    The aim of quercetin treatment in combination of cisplatin (CP)-induced nephrotoxicity as well on 1,2-dimethyl hydrazine (DMH)-induced colon cancer. In this study, animals are exposed to DMH hydrochloride to induce colon cancer. In these groups, nephrotoxicity was assessed with the help of blood urea nitrogen, urea, and creatinine. The antitumor activity of quercetin and CP assessed with the help of number of aberrant crypts and foci formation. Tumor size in different treatment group determined with the help of vernier caliper. CP is one of the most widely used antineoplastic drugs against colon cancer, but it has a major dose-limiting drawbacks of causing nephrotoxicity. Therefore, there is a need for a novel therapeutic regimen which will reduce the nephrotoxicity and enhance the anticancer activity of CP. The protective effect of quercetin on CP-induced nephrotoxicity is well-known. Moreover, quercetin is proven to have antitumor activity in colon cancer. Keeping all the facts in view, this study was conceived to evaluate the role of quercetin on therapeutic efficacy and nephrotoxicity of CP in DMH-induced colon cancer in male Sprague-Dawley rats. Treatment of quercetin with CP (7.5 mg/kg) prevents the CP-induced nephrotoxicity along with enhance the anticancer activity confirmed by the reduction of aberrant crypt foci number. Treatment of CP and quercetin alone leads to significant increase in the anticancer activity as compared to control colon tumor rats. In DMH-induced colon cancer model, combination of quercetin and CP ameliorates CP-induced nephrotoxicity as well as enhanced antitumor activity.

  13. Anodic Oxidation and Amperometric Sensing of Hydrazine at a Glassy Carbon Electrode Modified with Cobalt (II Phthalocyanine–cobalt (II Tetraphenylporphyrin (CoPc- (CoTPP4 Supramolecular Complex

    Directory of Open Access Journals (Sweden)

    Kenneth I. Ozoemena

    2006-08-01

    Full Text Available This paper describes the electrocatalytic behaviour of a glassy carbon electrode (GCEmodified with cobalt(IIphthalocyanine (CoPc complex peripherally tetrasubstituted withcobalt(IItetraphenylporphyrin (CoTPP complexes via ether linkages (i.e., CoPc-(CoTPP4. Thefeatures of the immobilised pentamer were interrogated with cyclic voltammetry andelectrochemical impedance spectroscopy (EIS using [Fe(CN6]3-/4- as redox probe revealedenhanced electron transfer properties with kapp ≈ 18 x 10-6 cms-1 compared to that of the bareGCE (4.7 x 10-6 cms-1. The viability of this supramolecular complex as a redox mediator for theanodic oxidation and sensitive amperometric determination of hydrazine in alkaline conditions isdescribed. The electrocatalytic oxidation of hydrazine by GCE-CoPc-(CoTPP4 was characterisedwith satisfactory catalytic current response with low non-Faradaic current (ca. 30 times lowerthan the bare GCE and at much lower oxidation potential (ca. 300 mV lower than the bareGCE. A mechanism for the studied electrocatalytic reaction was proposed based on thespectrophotometric evidence that revealed the major involvement of the Co(III/Co(II redox coupleof the central CoPc species rather than the CoTPP component of the pentamer. Rate constant forthe anodic oxidation of hydrazine was estimated from chronoamperometry as ~ 3x103 M-1s-1. Theproposed amperometric sensor displayed excellent charateristics towards the determination ofhydrazine in 0.2 M NaOH ; such as low overpotentials ( 100 mV vs Ag|AgCl, very fastamperometric response time (1 s, linear concentration range of up to 230 μM, with micromolardetection limit, high sensitivity and stability.

  14. Enhancement of the analytical properties and catalytic activity of a nickel hexacyanoferrate modified carbon ceramic electrode prepared by two-step sol-gel technique: application to amperometric detection of hydrazine and hydroxyl amine.

    Science.gov (United States)

    Salimi, Abdollah; Abdi, Kamaleddin

    2004-05-28

    The electroless sol-gel technique was used for the construction of nickel hexacyanoferrat (NiHCF) modified carbon composite electrodes (CCEs).This involves two steps: formation of a carbon ceramic electrode fabricated by nickel powder and then immersing the electrode into a sodium- hexacyanoferate solution for the immobilization of NiHCF films. The cyclic voltammety of the resulting modified CCEs prepared under optimum conditions, shows a well defined surface redox couple due to the [Ni(II)Fe(III/II)(CN)(6)](-2/-1) system. The effect of different alkali metal cations in supporting electrolyte on the behavior of the modified electrode were studied. The charge transfer coefficient (alpha) and charge transfer rate constant (k(s)) for modified films were calculated. Hydrazine and hydroxylamine have been chosen as a model to elucidate the electocatalytic ability and analytical parameters of NiHCF modified CCE prepared by one and two-step sol-gel techniques and these compounds determined amperometically at the surface of modified electrodes. The latter shows a good electocatalytic activity towards the oxidation of hydrazine and hydroxylamine in the pH range 3-8 in comparison with CCEs modified by homogeneous mixture of graphite powder, Ni(NO(3))(2) and Na(2)[Fe(CN)(6)], (one-step sol-gel technique). Furthermore, the catalytic rate constant, linear dynamic range, limit of detection, and sensitivity for hydrazine and hydroxylamine detections were evaluated and compared with CCEs prepared with one-step sol-gel method. The modified CCEs containing NiHCF shows good repeatability, short response time, t 90%<3s, long term stability (3 months) and excellent catalytic activity. Furthermore, the method of preparation is rapid and simple and the modified electrodes are renewed by simple mechanical polishing and immersing in [Na(3)Fe(CN](6)] solution.

  15. Directed Replacement

    CERN Document Server

    Karttunen, L

    1996-01-01

    This paper introduces to the finite-state calculus a family of directed replace operators. In contrast to the simple replace expression, UPPER -> LOWER, defined in Karttunen (ACL-95), the new directed version, UPPER @-> LOWER, yields an unambiguous transducer if the lower language consists of a single string. It transduces the input string from left to right, making only the longest possible replacement at each point. A new type of replacement expression, UPPER @-> PREFIX ... SUFFIX, yields a transducer that inserts text around strings that are instances of UPPER. The symbol ... denotes the matching part of the input which itself remains unchanged. PREFIX and SUFFIX are regular expressions describing the insertions. Expressions of the type UPPER @-> PREFIX ... SUFFIX may be used to compose a deterministic parser for a ``local grammar'' in the sense of Gross (1989). Other useful applications of directed replacement include tokenization and filtering of text streams.

  16. Directing Creativity

    DEFF Research Database (Denmark)

    Darsø, Lotte; Ibbotson, Piers

    2008-01-01

    In this article we argue that leaders facing complex challenges can learn from the arts, specifically that leaders can learn by examining how theatre directors direct creativity through creative constraints. We suggest that perceiving creativity as a boundary phenomenon is helpful for directing it....... Like leaders, who are caught in paradoxical situations where they have to manage production and logistics simultaneously with making space for creativity and innovation, theatre directors need to find the delicate balance between on one hand renewal of perceptions, acting and interaction...

  17. Direct marketing

    Directory of Open Access Journals (Sweden)

    Čičić Muris

    2002-01-01

    Full Text Available Direct Marketing (DM is usually treated as unworthy activity, with actions at the edge of legality and activities minded cheating. Despite obvious problems regarding ethics and privacy threat, DM with its size, importance and role in a concept of integrated marketing communication deserves respect and sufficient analysis and review

  18. Fuelling a National Innovation System in Colombia

    Science.gov (United States)

    Lucio-Arias, Diana

    2006-01-01

    This presentation of the innovation-driven environment in Colombia derives from important national efforts to gather and store pertinent information. Two large surveys have tested the "innovative behaviour" of Colombian manufacturing firms--the more recent of these was in 2005. Another information source is the Scienti platform, an online effort…

  19. Biomass fuelled indirect fired micro turbine

    Energy Technology Data Exchange (ETDEWEB)

    Pritchard, D.

    2005-07-01

    This report summarises the findings of a project to further develop and improve a system based on the Bowman TG50 50kWe turbine and a C3(S) combustor with a high temperature heat exchanger for the production of electricity from biomass. Details are given of the specific aims of the project, the manufacture of a new larger biomass combustor, the development of startup and shutdown procedures, waste heat recuperation, adaption of a PC-based mathematical model, and capital equipment costs. The significant levels of carbon emission savings and the commercial prospects of the biomass generator gas turbine combined heat and power (CHP) system are considered, and recommendations are presented.

  20. Direct ELISA.

    Science.gov (United States)

    Lin, Alice V

    2015-01-01

    First described by Engvall and Perlmann, the enzyme-linked immunosorbent assay (ELISA) is a rapid and sensitive method for detection and quantitation of an antigen using an enzyme-labeled antibody. Besides routine laboratory usage, ELISA has been utilized in medical field and food industry as diagnostic and quality control tools. Traditionally performed in 96-well or 384-well polystyrene plates, the technology has expanded to other platforms with increase in automation. Depending on the antigen epitope and availability of specific antibody, there are variations in ELISA setup. The four basic formats are direct, indirect, sandwich, and competitive ELISAs. Direct ELISA is the simplest format requiring an antigen and an enzyme-conjugated antibody specific to the antigen. This chapter describes the individual steps for detection of a plate-bound antigen using a horseradish peroxidase (HRP)-conjugated antibody and luminol-based enhanced chemiluminescence (ECL) substrate. The methodological approach to optimize the assay by chessboard titration is also provided.

  1. Determination of Hydrazine Hydrate in Water with Paradime Thylaminobenzaldehyde Spectrophotometric Method%对二甲氨基苯甲醛分光光度法测定水中水合肼

    Institute of Scientific and Technical Information of China (English)

    黄岭; 李叙柏

    2016-01-01

    在酸性条件下,水合肼与对二甲氨基苯甲醛作用,形成黄色醌式化合物,可用分光光度法对其进行测定。文中主要介绍对二甲氨基苯甲醛分光光度法测定的回收率、相对标准偏差及检出限的复验,并对上海水源水及其出厂水水合肼进行测定。%Hydrazine hydrate can be detected using spectrophotometer,because yellow quinine compound is produced when it reacts with paradime thylaminobenzaldehyde under acidic conditions. In this paper,the recovery rate,relative standard deviation and lowest detection limit of this method were analyzed,and the hydrazine hydrate in the raw water and processed water of three water plants were determined.

  2. Synthesis and Crystal Structure of N-tert-butyl-N′-(2,4-dichlorobenzoyl)-N-[1-(4-chlorophenyl)-1, 4-dihydro-6-methylpyridazine-4-oxo-3- carbonyl] hydrazine

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The title compound N-tert-butyl-N¢-(2,4-dichlorobenzoyl)-N-[1-(4-chlorophenyl)- 1,4-dihydro-6-methylpyridazine-4-oxo-3-carbonyl]hydrazine [(C23H21N4O3Cl3)2·1.5H2O, Mr = 1042.60] was prepared by the reaction of 1-(4-chlorophenyl)-1,4-dihydro-4-oxo-6- methylpyridazine-3-carboxylic acid with chloroformate ethyl ester, then with N′-tert-butyl-N- (2,4-dichlorobenzoyl) hydrazine in the present of triethylamine. The crystal structure has been determined by X-ray diffraction. The crystal belongs to Monoclinic, space group P21/c, with unit cell constants a =11.4948(9), b=12.7495(10), c=35.854(3) ?, β =92.964(2)°, Z=4, V=5247.6(7) ?3, Dc = 1.320 Mg/m3, F(000) = 2156 , μ (MoKa)= 0.385, R = 0.0661, wR = 0.1875, for 9151 observed reflections( I >2σ(I)). The structure is a dimer linked by intermolecular hydrogen bond which can be observed between N(1)- H…O(6), N(5)- H…O(3). The distances are 2.068 and 2.027? respectively.

  3. Directing Lives

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    YANG Yang is he director of China Television PlayCenter.Before the arrival of the series Holding Hands,she filmed television plays reflecting women and marriage.Examples of her work include Niu Yuqin and Her Trees and theMidnight Trolley.The artistry and sympathy towards women inthese programmes make it obvious that they were directed by awoman.Holding Hands especially cements this connection.

  4. Irida-β-ketoimines Derived from Hydrazines To Afford Metallapyrazoles or N-N Bond Cleavage: A Missing Metallacycle Disclosed by a Theoretical and Experimental Study.

    Science.gov (United States)

    Zumeta, Itziar; Mendicute-Fierro, Claudio; Bustos, Itxaso; Huertos, Miguel A; Rodríguez-Diéguez, Antonio; Seco, José M; San Sebastian, Eider; Garralda, María A

    2016-10-17

    Unprecedented metallapyrazoles [IrH2{Ph2P(o-C6H4)CNNHC(o-C6H4)PPh2}] (3) and [IrHCl{Ph2P(o-C6H4)CNNHC(o-C6H4)PPh2}] (4) were obtained by the reaction of the irida-β-ketoimine [IrHCl{(PPh2(o-C6H4CO))(PPh2(o-C6H4CNNH2))H}] (2) in MeOH heated at reflux in the presence and absence of KOH, respectively. In solution, iridapyrazole 3 undergoes a dynamic process due to prototropic tautomerism with an experimental barrier for the exchange of ΔGcoal(⧧) = 53.7 kJ mol(-1). DFT calculations agreed with an intrapyrazole proton transfer process assisted by two water molecules (ΔG = 63.1 kJ mol(-1)). An X-ray diffraction study on 4 indicated electron delocalization in the iridapyrazole ring. The reaction of the irida-β-diketone [IrHCl{(PPh2(o-C6H4CO))2H}] (1) with H2NNRR' in aprotic solvents gave irida-β-ketoimines [IrHCl{(PPh2(o-C6H4CO))(PPh2(o-C6H4CNNRR'))H}] (R = R' = Me (5); R = H, R' = Ph (8)), which can undergo N-N bond cleavage to afford the acyl-amide complex [IrHCl(PPh2(o-C6H4CO))(PPh2(o-C6H4C(O)N(CH3)2))-κP,κO] (6) or [IrHCl(PPh2(o-C6H4CO))(PPh2(o-C6H4CN)-κP)(NH2NHPh-κNH2)] (9) containing o-(diphenylphosphine)benzonitrile and phenylhydrazine, respectively. From a CH2Cl2/CH3OH solution of 9 kept at -18 °C, single crystals of [IrHCl(PPh2(o-C6H4CO))(PPh2(o-C6H4CN)-κP))(HN═NPh-κNH)] (10) containing o-(diphenylphosphine)benzonitrile and phenyldiazene were formed, as shown by X-ray diffraction. The reaction of 1 with methylhydrazine in methanol gave the hydrazine complex [IrCl(PPh2(o-C6H4CO))2(NH2NH(CH3)-κNH2)] (7). Single-crystal X-ray diffraction analysis was performed on 6 and 7.

  5. Electrocatalytic oxidation of hydrazine on magnetic bar carbon paste electrode modified with benzothiazole and iron oxide nanoparticles:Simultaneous determination of hydrazine and phenol%苯并噻唑和铁氧化物纳米粒子修饰的磁性棒碳糊电极上肼的电催化氧化反应:同时检测肼和苯酚

    Institute of Scientific and Technical Information of China (English)

    Ali Benvidi; Shahriar Jahanbani; Bibi-Fatemeh Mirjalili; Reza Zare

    2016-01-01

    A magnetic bar carbon paste electrode (MBCPE) modified with Fe3O4 magnetic nanoparticles (Fe3O4NPs) and 2‐(3,4‐dihydroxyphenyl) benzothiazole (DPB) for the electrochemical determina‐tion of hydrazine was developed. The DPB was firstly self‐assembled on the Fe3O4NPs, and the re‐sulting Fe3O4NPs/DPB composite was then absorbed on the designed MBCPE. The MBCPE was used to attract the magnetic nanoparticles to the electrode surface. Owing to its high conductivity and large effective surface area, the novel electrode had a very large current response for the electrocat‐alytic oxidation of hydrazine. The modified electrode was characterized by voltammetry, scanning electron microscopy, electrochemical impedance spectroscopy, infrared spectroscopy, and UV‐visible spectroscopy. Voltammetric methods were used to study the electrochemical behaviour of hydrazine on MBCPE/Fe3O4NPs/DPB in phosphate buffer solution (pH = 7.0). The MBCPE/Fe3O4NPs/DPB, acting as an electrochemical sensor, exhibited very high electrocatalytic activity for the oxidation of hydrazine. The presence of DPB was found to reduce the oxidation potential of hydrazine and increase the catalytic current. The dependence of the electrocatalytic current on the hydrazine concentration exhibited two linear ranges, 0.1–0.4 µmol/L and 0.7–12.0 µmol/L, with a detection limit of 18.0 nmol/L. Additionally, the simultaneous determination of hydrazine and phe‐nol was investigated using the MBCPE/Fe3O4NPs/DPB electrode. Voltammetric experiments showed a linear range of 100–470 µmol/L and a detection limit of 24.3 µmol/L for phenol, and the proposed electrode was applied to the determination of hydrazine and phenol in water samples.%开发了一种磁性Fe3O4纳米粒子和2-(3,4-二羟苯基)苯并噻唑(DPB)修饰的磁性棒碳糊电极(MBCPE)用于电化学检测肼.首先将DPB自组装在Fe3O4纳米粒子上,然后将此复合物吸附于设计的MBCPE上. MBCPE电极将磁性纳米粒子

  6. Future direction of direct writing

    Science.gov (United States)

    Kim, Nam-Soo; Han, Kenneth N.

    2010-11-01

    Direct write technology using special inks consisting of finely dispersed metal nanoparticles in liquid is receiving an undivided attention in recent years for its wide range of applicability in modern electronic industry. The application of this technology covers radio frequency identification-tag (RFID-tag), flexible-electronics, organic light emitting diodes (OLED) display, e-paper, antenna, bumpers used in flip-chip, underfilling, frit, miniresistance applications and biological uses, artificial dental applications and many more. In this paper, the authors have reviewed various direct write technologies on the market and discussed their advantages and shortfalls. Emphasis has given on microdispensing deposition write (MDDW), maskless mesoscale materials deposition (M3D), and ink-jet technologies. All of these technologies allow printing various patterns without employing a mask or a resist with an enhanced speed with the aid of computer. MDDW and M3D are capable of drawing patterns in three-dimension and MDDW, in particular, is capable of writing nanoinks with high viscosity. However, it is still far away for direct write to be fully implemented in the commercial arena. One of the hurdles to overcome is in manufacturing conductive inks which are chemically and physically stable, capable of drawing patterns with acceptable conductivity, and also capable of drawing patterns with acceptable adhesiveness with the substrates. The authors have briefly discussed problems involved in manufacturing nanometal inks to be used in various writing devices. There are numerous factors to be considered in manufacturing such inks. They are reducing agents, concentrations, oxidation, compact ability allowing good conductivity, and stability in suspension.

  7. Advance care directives

    Science.gov (United States)

    ... advance directive; Do-not-resuscitate - advance directive; Durable power of attorney - advance care directive; POA - advance care directive; Health care agent - advance care directive; Health care proxy - ...

  8. The Effect of Graphene Oxide on Monocrystalline Silicon Texture in Hydrazine Hydrate%氧化石墨烯在水合肼中对单晶硅织构化的影响

    Institute of Scientific and Technical Information of China (English)

    张会丹; 裴重华

    2016-01-01

    单晶硅太阳能电池的表面反射率是影响其光电转换效率的重要因素之一,表面织构化对降低表面反射率有着重要作用。采用水合肼对单晶硅进行刻蚀,并采用不同氧化程度的氧化石墨烯作为碳催化剂对水合肼腐蚀体系进行催化,采用失重法、XRD、SEM 和 FTIR 测试手段对反应产物进行表征。结果表明:氧化石墨烯的加入对水合肼体系起到了促进催化的效果,质量浓度为1 mg/ mL 的氧化石墨烯促进效果最好,单晶硅表面金字塔形貌最佳;不同还原态的氧化石墨烯促进效果不同,还原时间最短时表面金字塔形貌最佳;随着还原程度的增加,促进作用越来越小,当还原时间为7 h 时,水合肼的各向异性消失,表现出各向同性的特性。%The surface reflectivity of monocrystalline silicon solar battery is one of the important factors of effect on photoelectric conversion efficiency. It is important for texturing monocrystalline to improve photo-electric conversion efficiency. We firstly adopt hydrazine hydrate as etching agent and graphene oxide with different oxidation degree were added into hydrazine hydrate to catalyze the corrosion. Products were char-acterized by XRD,SEM,FTIR and weight loss method. The results indicate that graphene oxide facili-tates the corrosion of monocrystalline silicon. And the optimal concentration is 1 mg / mL at that concentra-tion pyramid structures is fine. Moreover,the reduction time has an effect on the corrosion results. The less the reduction time is,the great effects of facilitating the corrosion is. When the reduction time is 7 h, the anisotropy disappears and turns into isotropy of hydrazine hydrate.

  9. Directly connected series coupled HTPEM fuel cell stacks to a Li-ion battery DC bus for a fuel cell electrical vehicle

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Ashworth, Leanne; Remón, Ian Natanael

    2008-01-01

    The work presented in this paper examines the use of pure hydrogen fuelled high temperature polymer electrolyte membrane (HTPEM) fuel cell stacks in an electrical car, charging a Li-ion battery pack. The car is equipped with two branches of two series coupled 1 kW fuel cell stacks which...... are connected directly parallel to the battery pack during operation. This enables efficient charging of the batteries for increased driving range. With no power electronics used, the fuel cell stacks follow the battery pack voltage, and charge the batteries passively. This saves the electrical and economical...... losses related to these components and their added system complexity. The new car battery pack consists of 23 Li-ion battery cells and the charging and discharging are monitored by a battery management system (BMS) which ensures safe operating conditions for the batteries. The direct connection...

  10. Design of sensor for hydrazine gas based on photo ionization principle%基于光离子化原理的肼类监测传感器的设计

    Institute of Scientific and Technical Information of China (English)

    范秋生; 薛晨阳; 梁庭; 孙瑞霞; 谭秋林; 张文栋

    2009-01-01

    为满足航天工程的需求,根据光离子化原理,设计了一种响应快、精度高(10-6)、便携、可连续测试的肼类监测传感器,可用于现场检测有机蒸气和气体.介绍了微型电离室设计和信号检测电路及安装工艺,并给出了测试结果.%Based on photo ionization principle,a gas sensor for hydrazine is designed to meet aerospace industry. The design of micro ionization chamber, signal detection circuits and installation technology is expatiated. Experiment results show that the gas sensor has the advantages of portable, high accuracy (10~(-6) ) ,fast response and continuous test,and can apply in detecting the organic gases.

  11. Synthesis of TiO₂-loaded Co0.85Se thin films with heterostructure and their enhanced catalytic activity for p-nitrophenol reduction and hydrazine hydrate decomposition.

    Science.gov (United States)

    Zuo, Yong; Song, Ji-Ming; Niu, He-Lin; Mao, Chang-Jie; Zhang, Sheng-Yi; Shen, Yu-Hua

    2016-04-08

    P-nitrophenol (4-NP) and hydrazine hydrate are considered to be highly toxic pollutants in wastewater, and it is of great importance to remove them. Herein, TiO2-loaded Co0.85Se thin films with heterostructure were successfully synthesized by a hydrothermal route. The as-synthesized samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy, transmission electron microscopy and selective-area electron diffraction. The results demonstrate that TiO2 nanoparticles with a size of about 10 nm are easily loaded on the surface of graphene-like Co0.85Se nanofilms, and the NH3 · H2O plays an important role in the generation and crystallization of TiO2 nanoparticles. Brunauer-Emmett-Teller measurement shows that the obtained nanocomposites have a larger specific surface area (199.3 m(2) g(-1)) than that of Co0.85Se nanofilms (55.17 m(2) g(-1)) and TiO2 nanoparticles (19.49 m(2) g(-1)). The catalytic tests indicate Co0.85Se-TiO2 nanofilms have the highest activity for 4-NP reduction and hydrazine hydrate decomposition within 10 min and 8 min, respectively, compared with the corresponding precursor Co0.85Se nanofilms and TiO2 nanoparticles. The enhanced catalytic performance can be attributed to the larger specific surface area and higher rate of interfacial charge transfer in the heterojunction than that of the single components. In addition, recycling tests show that the as-synthesized sample presents stable conversion efficiency for 4-NP reduction.

  12. Synthesis of TiO2-loaded Co0.85Se thin films with heterostructure and their enhanced catalytic activity for p-nitrophenol reduction and hydrazine hydrate decomposition

    Science.gov (United States)

    Zuo, Yong; Song, Ji-Ming; Niu, He-Lin; Mao, Chang-Jie; Zhang, Sheng-Yi; Shen, Yu-Hua

    2016-04-01

    P-nitrophenol (4-NP) and hydrazine hydrate are considered to be highly toxic pollutants in wastewater, and it is of great importance to remove them. Herein, TiO2-loaded Co0.85Se thin films with heterostructure were successfully synthesized by a hydrothermal route. The as-synthesized samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy, transmission electron microscopy and selective-area electron diffraction. The results demonstrate that TiO2 nanoparticles with a size of about 10 nm are easily loaded on the surface of graphene-like Co0.85Se nanofilms, and the NH3 · H2O plays an important role in the generation and crystallization of TiO2 nanoparticles. Brunauer-Emmett-Teller measurement shows that the obtained nanocomposites have a larger specific surface area (199.3 m2 g-1) than that of Co0.85Se nanofilms (55.17 m2 g-1) and TiO2 nanoparticles (19.49 m2 g-1). The catalytic tests indicate Co0.85Se-TiO2 nanofilms have the highest activity for 4-NP reduction and hydrazine hydrate decomposition within 10 min and 8 min, respectively, compared with the corresponding precursor Co0.85Se nanofilms and TiO2 nanoparticles. The enhanced catalytic performance can be attributed to the larger specific surface area and higher rate of interfacial charge transfer in the heterojunction than that of the single components. In addition, recycling tests show that the as-synthesized sample presents stable conversion efficiency for 4-NP reduction.

  13. 水合肼还原2,6-二硝基甲苯的研究%Study on reduction of 2,6-dinitrotoluene with hydrazine hydrate

    Institute of Scientific and Technical Information of China (English)

    蔡可迎

    2012-01-01

    Catalyst FeO(OH) was prepared by dropping iron chloride solution to sodium hydroxide solu-tion, which catalyzed the reduction of 2,6-dinitrotoluene to 2-amino-6-nitrotoluene and 2,6-diaminotolu-ene. The results showed that when the mol ratio of hydrazine hydrate to 2,6-dinitrotoluene is 1.6 : 1 ,and the reaction time is 40 min, the yield of 2-amino-6-nitrotoluene can reach 94%. When the mol ratio of hy-drazine hydrate to 2,6-dinitrotoluene is 3. 1.: 1 ,and the reaction time is 50 min,the yield of 2,6-diamin-otoluene can reach about 100%.%将FeCl3溶液快速滴加至NaOH溶液中,制备了FeO(OH)催化剂,用于催化水合肼还原2,6-二硝基甲苯,得到2-氨基-6-硝基甲苯和2,6-二氨基甲苯.结果表明,水合肼与2,6-二硝基甲苯的摩尔比为1.6:1,反应40 min时,2-氨基-6-硝基甲苯的收率可达94%;水合肼与2,6-二硝基甲苯的摩尔比为3.1:1,反应50 min时,2,6-二氨基甲苯的收率可接近100%.

  14. 丙酮连氮催化水解反应精馏工艺的研究%Process of hydrazine hydrate production by acetone azine hydrolysis via catalytic distillation

    Institute of Scientific and Technical Information of China (English)

    李柏春; 吴晓旺; 许沉娜

    2013-01-01

    The process of hydrazine hydrate produced by acetone azine hydrolysis via catalytic distillation was simulated and experimented.By using NTRL equation and RadFrac module,as well as the data obtained from dynamics and phase equilibrium,the process of producing hydrazine hydrate by acetone azine hydrolysis via catalytic distillation was simulated.The effects of process parameter,such as reflux ratio,mole ratio of acetone azine to water and feeding location on the acetone azine hydrolysis reaction were investigated.The optimized process parameters obtained were as follows:theoretical tray number 5 for rectifying,theoretical tray number 14 for reaction,reflux ratio 2,the mole fraction of acetone azine to water 1:7,feed tray 9th tray.Under such conditions,the hydrolysis rate of acetone azine was over 99%,the mass fraction of hydrazine hydrate at bottom was 34% and the temperature and mass fraction distributions of whole column were got.It provides a reference for industry production.%对丙酮连氮催化水解反应精馏制水合肼的工艺过程进行了模拟与实验.采用NRTL方程与RadFrac模型,使用实验回归得到的动力学方程与汽液平衡参数,对丙酮连氮催化水解精馏制水合肼的工艺进行模拟计算.考察了回流比、丙酮连氮与水的摩尔比、进料位置等工艺条件对丙酮连氮水解反应的影响,并通过实验验证了模型的准确性和可靠性.在模拟和实验的基础上,确定了最优工艺条件:精馏段理论板数为5,反应精馏段理论板数为14,回流比为2,丙酮连氮与水的摩尔比为1:7,原料进料位置为第9块板.在此条件下,丙酮连氮的水解率可达99%以上,塔釜肼质量分数为34%,并且得到了全塔的温度和质量分数分布曲线,为工业生产提供了依据.

  15. A single domain direct carbon fuel cell (DCFC) 2-D modeling

    Energy Technology Data Exchange (ETDEWEB)

    Elleuch, A.; Boussetta, A.; Halouani, K. [Sfax Univ., Sfax (Tunisia). Inst. Preparatoire aux Etudes d' Ingenieurs de Sfax, Micro-Electro-Thermal Systems, Industrial Energy Systems Group; Sahraoui, M. [Tunis Univ., Tunis (Tunisia). LASMAP EPT IPEIT

    2010-07-01

    There has been a renewed interest in cells fuelled with solid carbon because they promise increased conversion efficiencies for coal-based power generation with less production of carbon dioxide (CO{sub 2}). In addition, the CO{sub 2} produced in a direct carbon fuel cell (DCFC) is capture-ready for sequestration. The DCFC is a special type of high temperature fuel cell in which solid carbon directly reacts with oxygen to form CO{sub 2} and electricity. This paper presented a numerical 2-D model that simulates the transport of gaseous species, electrochemical kinetics, energy transport, and ionic current distribution for all regions of the DCFC. The governing differential equations were solved over a single computational domain, which consisted of a cathode gas channel, cathode gas diffusion layer, and cathode catalyst layer for the cathode side of the cell, a simple bloc for the anode side as well as the molten carbonate electrolyte. The coupled set of differential equations was solved using a FORTRAN code, and was readily adaptable in terms of geometry and material property definitions. The results showed temperature, carbon dioxide and oxygen concentration profile in all DCFC compartments. It was concluded that the model contributes to a better understanding of the heat and mass transfer mechanisms occurring within the cell. 10 refs., 3 tabs., 8 figs.

  16. Continuous gas/liquid–liquid/liquid flow synthesis of 4-fluoropyrazole derivatives by selective direct fluorination

    Directory of Open Access Journals (Sweden)

    Jessica R. Breen

    2011-08-01

    Full Text Available 4-Fluoropyrazole systems may be prepared by a single, sequential telescoped two-step continuous gas/liquid–liquid/liquid flow process from diketone, fluorine gas and hydrazine starting materials.

  17. Molecular structure, spectroscopic (FT-IR, FT-Raman, NMR, UV) studies and first-order molecular hyperpolarizabilities of 1,2-bis(3-methoxy-4-hydroxybenzylidene)hydrazine by density functional method

    Science.gov (United States)

    Subramanian, N.; Sundaraganesan, N.; Jayabharathi, J.

    2010-07-01

    Quantum chemical calculations of energies, geometrical structure and vibrational wavenumbers of 1,2-bis(3-methoxy-4-hydroxybenzylidene)hydrazine [vanillin azine (VA)] were carried out by using density functional (DFT/B3LYP) method with 6-31G(d) as basis set. The optimized geometrical parameters obtained by DFT calculations are in good agreement with single crystal XRD data. The vibrational spectral data obtained from solid phase FT-IR and FT-Raman spectra are assigned based on the results of the theoretical calculations. The observed spectra are found to be in good agreement with calculated values. The electric dipole moment ( μ) and the first hyperpolarizability ( β) values of the investigated molecule have been computed using ab initio quantum mechanical calculations. The calculation results also show that the VA molecule might have microscopic nonlinear optical (NLO) behavior with non-zero values. A detailed interpretation of the infrared and Raman spectra of VA was also reported. The energy and oscillator strength calculated by time-dependent density functional theory (TD-DFT) results complements with the experimental findings. The calculated HOMO and LUMO energies show that charge transfer occurs within the molecule. The theoretical NMR chemical shifts complement with experimentally measured ones.

  18. Effects of the novel compound DK223 ([1E,2E-1,2-Bis(6-methoxy-2H-chromen-3-yl)methylene]hydrazine) on migration and proliferation of human keratinocytes and primary dermal fibroblasts.

    Science.gov (United States)

    Ho, Manh Tin; Kang, Hyun Sik; Huh, Jung Sik; Kim, Young Mee; Lim, Yoongho; Cho, Moonjae

    2014-07-23

    Wound healing plays an important role in protecting the human body from external infection. Cell migration and proliferation of keratinocytes and dermal fibroblasts are essential for proper wound healing. Recently, several studies have demonstrated that secondary compounds produced in plants could affect skin cells migration and proliferation. In this study, we identified a novel compound DK223 ([1E,2E-1,2-bis(6-methoxy-2H-chromen-3-yl)methylene]hydrazine) that concomitantly induced human keratinocyte migration and dermal fibroblast proliferation. We evaluated the regulation of epithelial and mesenchymal protein markers, such as E-cadherin and Vimentin, in human keratinocytes, as well as extracellular matrix (ECM) secretion and metalloproteinase families in dermal fibroblasts. DK223 upregulated keratinocyte migration and significantly increased the epithelial marker E-cadherin in a time-dependent manner. We also found that reactive oxygen species (ROS) increased significantly in keratinocytes after 2 h of DK223 exposure, returning to normal levels after 24 h, which indicated that DK223 had an early shock effect on ROS production. DK223 also stimulated fibroblast proliferation, and induced significant secretion of ECM proteins, such as collagen I, III, and fibronectin. In dermal fibroblasts, DK223 treatment induced TGF-β1, which is involved in a signaling pathway that mediates proliferation. In conclusion, DK223 simultaneously induced both keratinocyte migration via ROS production and fibroblast proliferation via TGF-β1 induction.

  19. Deconjugation of N-glucuronide conjugated metabolites with hydrazine hydrate - Biomarkers for exposure to the food-borne carcinogen 2-amino-l-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP)

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lauritz

    2007-01-01

    The metabolism of the carcinogen 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) has been investigated in rabbit liver S9. Two phase I metabolites, N-2-OH-PhIP and 4'-OH-PhIP were identified based on UV and mass spectra and co-elution with reference standards. Fortification of the incubation...... with UDGPA resulted in a complete glucuronidation of PhIP and N-2-OH-PhIP, while 4'-OH-PhIP was only partly glucuronidated. Also, the PhIP metabolite 5-OH-PhIP was completely glucuronidated by rabbit liver S9, while 5-OH-PhIP was a poor substrate for CYP mediated hydroxylation. The glucuronic acid conjugates...... of PhIP and 5-OH-PhIP. The data show that hydrazine hydrate can hydrolyse N-glucuronides of metabolites of PhIP, glucuronides that are unsusceptible to enzymatic hydrolysis. In addition the data indicate that humans metabolise a large fraction of ingested PhIP to genotoxic metabolites. The chemical...

  20. Effects of the Novel Compound DK223 ([1E,2E-1,2-Bis(6-methoxy-2H-chromen-3-ylmethylene]hydrazine on Migration and Proliferation of Human Keratinocytes and Primary Dermal Fibroblasts

    Directory of Open Access Journals (Sweden)

    Manh Tin Ho

    2014-07-01

    Full Text Available Wound healing plays an important role in protecting the human body from external infection. Cell migration and proliferation of keratinocytes and dermal fibroblasts are essential for proper wound healing. Recently, several studies have demonstrated that secondary compounds produced in plants could affect skin cells migration and proliferation. In this study, we identified a novel compound DK223 ([1E,2E-1,2-bis(6-methoxy-2H-chromen-3-ylmethylene]hydrazine that concomitantly induced human keratinocyte migration and dermal fibroblast proliferation. We evaluated the regulation of epithelial and mesenchymal protein markers, such as E-cadherin and Vimentin, in human keratinocytes, as well as extracellular matrix (ECM secretion and metalloproteinase families in dermal fibroblasts. DK223 upregulated keratinocyte migration and significantly increased the epithelial marker E-cadherin in a time-dependent manner. We also found that reactive oxygen species (ROS increased significantly in keratinocytes after 2 h of DK223 exposure, returning to normal levels after 24 h, which indicated that DK223 had an early shock effect on ROS production. DK223 also stimulated fibroblast proliferation, and induced significant secretion of ECM proteins, such as collagen I, III, and fibronectin. In dermal fibroblasts, DK223 treatment induced TGF-β1, which is involved in a signaling pathway that mediates proliferation. In conclusion, DK223 simultaneously induced both keratinocyte migration via ROS production and fibroblast proliferation via TGF-β1 induction.

  1. Crystal structure of 1,2-bis[(1H-imidazol-2-ylmethylidene]hydrazine and its one-dimensional hydrogen-bonding network

    Directory of Open Access Journals (Sweden)

    Chia-Hwa Lee

    2016-04-01

    Full Text Available In the title compound, C8H8N6, two imidazolyl groups are separated by a zigzag –CH=N—N=CH– linkage. An inversion center is located at the mid-point of the N—N single bond and the complete molecule is generated by symmetry. In the crystal, each molecule forms four N—H...N hydrogen bonds with two neighbouring molecules to constitute a one-dimensional ladder-like structure propagating along the a-axis direction.

  2. Reduction of Aromatic Nitro Compounds under Solvent-free Condition Using Almnina-suppored Hydrazine/Fe2 (NO3)3· 9H2O

    Institute of Scientific and Technical Information of China (English)

    WANG Yu-Lu; ZHANG Chang-Rui

    2003-01-01

    @@ The application of microwave techniques for chemical synthesis has attracted considerable interest in recent years because of their enhanced selectivity, reduced reaction time, easier work-up procedure. Aromatic amines are widely used as intermediate for dyes, photographic materials, pharmaceutical and agricultural chemicals and as antioxidants. So, particularly intense interest has been directed toward the synthesis of these compounds. Reduction of aromatic nitro compounds is one of the important routes to prepare them. Generally, the processes have been carried out in solvent. [ 1 ~ 6] The drawback of these methods is long reaction time.

  3. Determination of palladium in palladium oxide by EDTA titration with hydrazine hydrate reduction%水合肼还原-ED TA 滴定法测定氧化钯中钯

    Institute of Scientific and Technical Information of China (English)

    王艳红; 宫嘉辰; 张瑞峰

    2016-01-01

    氧化钯使用常规的酸溶方法难溶。采用水合肼作为还原剂,于80℃时,在氧化钯的悬浮水溶液中,将氧化钯还原为金属钯黑,过滤后,该金属钯黑连同滤纸经过盐酸及硝硫混酸碳化处理后,钯进入溶液,从而解决了难溶氧化钯的溶样难题。然后,于pH 5.8的醋酸‐醋酸钠缓冲介质中,以二甲酚橙为指示剂,锌盐返滴定过量EDTA ,用丁二酮肟析出与钯等量的ED‐TA ,三氯甲烷萃取丁二酮肟‐钯沉淀,锌盐滴定析出的EDTA以测定钯含量,从而建立了水合肼还原‐EDTA滴定法测定难溶氧化钯中钯的方法。按照实验方法测定实际样品中钯,结果的相对标准偏差(RSD ,n=5)在0.12%~0.20%之间。对基准物质氧化钯中钯进行分析,测定值与理论值相符合。%The palladium oxide was hardly dissolved by the common acid method .In proposed study ,the palladium oxide was reduced to the metal palladium black in supernatant solution at 80 ℃ using hydrazine hydrate as reducing agent .After filtration ,the metal palladium black with filter paper was treated by car‐bonization with hydrochloric acid and nitric‐sulfuric acid .The palladium was introduced into solution ,sol‐ving the sample preparation problem of indissolvable palladium oxide .Then ,the excessive EDTA was back‐titrated with zinc salt in HAc‐NaAc buffer solution at pH 5.8 using xylenol orange as indicator .The equal amount of EDTA to palladium was precipitated with dimethylglyoxime .The dimethylglyoxime‐palla‐dium precipitate was extracted with trichloromethane .The precipitated EDTA was titrated with zinc salt to determine the content of palladium .T hus ,the determination method of palladium in indissolvable palla‐dium oxide by EDTA titration with hydrazine hydrate reduction was established .The content of palladium in actual sample was determined according to the experimental method .The relative standard

  4. Influence of glutathione and glutathione S-transferases on DNA interstrand cross-link formation by 1,2-bis(methylsulfonyl)-1-(2-chloroethyl)hydrazine, the active anticancer moiety generated by laromustine.

    Science.gov (United States)

    Penketh, Philip G; Patridge, Eric; Shyam, Krishnamurthy; Baumann, Raymond P; Zhu, Rui; Ishiguro, Kimiko; Sartorelli, Alan C

    2014-08-18

    Prodrugs of 1,2-bis(methylsulfonyl)-1-(2-chloroethyl)hydrazine (90CE) are promising anticancer agents. The 90CE moiety is a readily latentiated, short-lived (t1/2 ∼ 30 s) chloroethylating agent that can generate high yields of oxophilic electrophiles responsible for the chloroethylation of the O-6 position of guanine in DNA. These guanine O-6 alkylations are believed to be responsible for the therapeutic effects of 90CE and its prodrugs. Thus, 90CE demonstrates high selectivity toward tumors with diminished levels of O(6)-alkylguanine-DNA alkyltransferase (MGMT), the resistance protein responsible for O(6)-alkylguanine repair. The formation of O(6)-(2-chloroethyl)guanine lesions ultimately leads to the generation of highly cytotoxic 1-(N(3)-cytosinyl),-2-(N(1)-guaninyl)ethane DNA interstrand cross-links via N(1),O(6)-ethanoguanine intermediates. The anticancer activity arising from this sequence of reactions is thus identical to this component of the anticancer activity of the clinically used chloroethylnitrosoureas. Herein, we evaluate the ability of glutathione (GSH) and other low molecular weight thiols, as well as GSH coupled with various glutathione S-transferase enzymes (GSTs) to attenuate the final yields of cross-links generated by 90CE when added prior to or immediately following the initial chloroethylation step to determine the major point(s) of interaction. In contrast to studies utilizing BCNU as a chloroethylating agent by others, GSH (or GSH/GST) did not appreciably quench DNA interstrand cross-link precursors. While thiols alone offered little protection at either alkylation step, the GSH/GST couple was able to diminish the initial yields of cross-link precursors. 90CE exhibited a very different GST isoenzyme susceptibility to that reported for BCNU, this could have important implications in the relative resistance of tumor cells to these agents. The protection afforded by GSH/GST was compared to that produced by MGMT.

  5. Binuclear copper(II), cobalt(II) and nickel(II) complexes of N1-ethyl-N2-(pyridin-2-yl) hydrazine-1,2-bis(carbothioamide): structural, spectral, pH-metric and biological studies.

    Science.gov (United States)

    El-Gammal, O A; Abu El-Reash, G M; El-Gamil, M M

    2012-10-01

    Binuclear Cu(II), Co(II) and Ni(II) complexes derived from N(1)-ethyl-N(2)-(pyridin-2-yl) hydrazine-1,2-bis(carbothioamide) (H(2)PET) have been prepared and characterized by elemental analysis, spectral (IR, UV-vis, EI mass, ESR and (1)HNMR) and magnetic measurements. The isolated complexes assigned the general formula, [M(HPET)(H(2)O)(n)Cl](2)·xH(2)O where M=Cu(II), Co(II) and Ni(II), n=2, 1, 0 and x=0, 0.5 and 0, respectively. IR data revealed that the ligand behaves as monobasic tridentate through (CN)(py), (C-S) and new azomethine, (NC)(∗) groups in the Co(II) complex but in Cu(II) complex, the ligand coordinate via both (CS) groups, one of them in thiol form as well as the new azomethine group. In Ni(II) complex, H(2)PET acts as NSNS monobasic tetradente via (CN)(py), (C-S), (CS) and the new azomethine, (NC)(∗) groups. An octahedral geometry is proposed for all complexes. pH- metric titration was carried out in 50% dioxane-water mixture at 298, 308 and 318 °K, respectively and the dissociation constant of the ligand as well as the stability constants of its complexes were evaluated. Also the kinetic and thermodynamic parameters for the different thermal decomposition steps of the complexes were determined by Coats-Redfern and Horowitz-Metzger methods. Moreover, the anti-oxidant, anti-hemolytic, and cytotoxic activities of the compounds have been tested.

  6. Synthesis of stable ultra-small Cu nanoparticles for direct writing flexible electronics

    Energy Technology Data Exchange (ETDEWEB)

    Li, Wei [School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Chen, Minfang, E-mail: mfchentj@126.com [School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

    2014-01-30

    In this study, pure Cu nanoparticles (NPs) have been successfully synthesized and the Cu nano-ink was prepared for direct writing on photo paper using a roller pen. The tri-sodium citrate was used as initial reducing-cum-surfactant agent followed by hydrazine as a second massive reducing agent and cetyltrimethylammonium bromide (CTAB) as extra surfactant agent. From the XRD, TEM, and HR-TEM analyses, the synthesized particles are confirmed to be Cu in spherical shape with sizes range of 2.5 ± 1.0 nm. By analyzing the FT-IR spectroscopy and TGA curves, it was found that the obtained particles capped with tri-sodium citrate and CTAB layers are stable to oxidation up to the temperature 228 °C. The reduced size and enhanced air-stability of the Cu NPs result in an improved particle density upon sintering, which is mainly responsible for the increased conductivity of the Cu patterns. The resistivity of Cu patterns sintered in Ar at 160 °C for 2 h is 7.2 ± 0.6 μΩ cm, which is 4.40 times the bulk Cu resistivity. The drawn Cu lines exhibited excellent integrity and good conductivity, which were experimentally tested. Moreover, a Cu electrode and a sample RFID antenna were successfully made.

  7. Highly active carbon supported Pd cathode catalysts for direct formic acid fuel cells

    Science.gov (United States)

    Mikolajczuk-Zychora, A.; Borodzinski, A.; Kedzierzawski, P.; Mierzwa, B.; Mazurkiewicz-Pawlicka, M.; Stobinski, L.; Ciecierska, E.; Zimoch, A.; Opałło, M.

    2016-12-01

    One of the drawbacks of low-temperature fuel cells is high price of platinum-based catalysts used for the electroreduction of oxygen at the cathode of the fuel cell. The aim of this work is to develop the palladium catalyst that will replace commonly used platinum cathode catalysts. A series of palladium catalysts for oxygen reduction reaction (ORR) were prepared and tested on the cathode of Direct Formic Acid Fuel Cell (DFAFC). Palladium nanoparticles were deposited on the carbon black (Vulcan) and on multiwall carbon nanotubes (MWCNTs) surface by reduction of palladium(II) acetate dissolved in ethanol. Hydrazine was used as a reducing agent. The effect of functionalization of the carbon supports on the catalysts physicochemical properties and the ORR catalytic activity on the cathode of DFAFC was studied. The supports were functionalized by treatment in nitric acid for 4 h at 80 °C. The structure of the prepared catalysts has been characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscope (TEM) and cyclic voltammetry (CV). Hydrophilicity of the catalytic layers was determined by measuring contact angles of water droplets. The performance of the prepared catalysts has been compared with that of the commercial 20 wt.% Pt/C (Premetek) catalyst. The maximum power density obtained for the best palladium catalyst, deposited on the surface of functionalized carbon black, is the same as that for the commercial Pt/C (Premetek). Palladium is cheaper than platinum, therefore the developed cathode catalyst is promising for future applications.

  8. Invariants of directed spaces

    DEFF Research Database (Denmark)

    Raussen, Martin

    2007-01-01

    Directed spaces are the objects of study within directed algebraic topology. They are characterised by spaces of directed paths associated to a source and a target, both elements of an underlying topological space. The algebraic topology of these path spaces and their connections are studied from...

  9. Crystal structure of benzyl (E)-2-(3,4-di-meth-oxy-benzyl-idene)hydrazine-1-carbodi-thio-ate.

    Science.gov (United States)

    Tan, Yew-Fung; Break, Mohammed Khaled Bin; Tahir, M Ibrahim M; Khoo, Teng-Jin

    2015-02-01

    The title compound, C17H18N2O2S2, synthesized via a condensation reaction between S-benzyl di-thio-carbazate and 3,4-di-meth-oxy-benzaldehyde, crystallized with two independent mol-ecules (A and B) in the asymmetric unit. Both mol-ecules have an L-shape but differ in the orientation of the benzyl ring with respect to the 3,4-di-meth-oxy-benzyl-idine ring, this dihedral angle is 65.59 (8)° in mol-ecule A and 73.10 (8)° in mol-ecule B. In the crystal, the A and B mol-ecules are linked via pairs of N-H⋯S hydrogen bonds, forming dimers with an R 2 (2)(8) ring motif. The dimers are linked via pairs of C-H⋯O hydrogen bonds, giving inversion dimers of dimers. These units are linked by C-H⋯π inter-actions, forming ribbons propagating in the [100] direction.

  10. Experiments on combustion and emission particulate size distribution characteristics of diesel engine fuelled with methanol-blending biodiesel fuel%甲醇-调合生物柴油燃烧及排放微粒粒径分布特性试验

    Institute of Scientific and Technical Information of China (English)

    杜家益; 李俊; 张登攀; 赵小明; 吴培振; 袁银男

    2016-01-01

    . Burning diesel mixed with methanol could improve combustion and reduce the emissions of particles, but the physicochemical properties of diesel and methanol are greatly different, and they are mutually immiscible. Generally, forming micro-emulsion fuels by mixing them with cosolvent is the most efficient way. At present, a series of achievements have been gained at home and abroad, but the researches about using the mixture of methanol and biodiesel are still few, especially about the size distribution of fine particles. As a kind of green renewable energy, biodiesel can improve the emission characteristics of engine; also, it could contribute to the formation of methanol-blending biodiesel micro-emulsion fuel. With the use of combustion analyzer and Engine Exhaust Particle Sizer 3090 spectrometer, the combustion process and the particulate number concentration distribution characteristics were studied with a diesel engine fuelled with methanol-blending biodiesel micro-emulsion fuel. Results showed that compared to the engine fuelled with blending biodiesel B20 (20% biodiesel and 80% diesel in volume fraction), the in-cylinder pressure, pressure rise rate and heat release rate curves for the engine fuelled with methanol-blending biodiesel micro-emulsion fuel were obviously retarded, and the maximum pressure rise rate and heat release rate increased; the particle presented nuclei mode and the size was mostly between 6 and 22 nm at low load, and the total number of nuclei mode particles showed that the B20 fuel was the most, followed by B20M5 (95% B20 and 5% methanol in volume fraction), B20M10 (90% B20 and 10% methanol in volume fraction) and B20M15 (85% B20 and 15% methanol in volume fraction) in order; at high load, the particulate number concentration distribution was unimodal with the size between 6 and 275 nm, the particle morphology was accumulation mode, and the peak of particulate size distribution was around 100 nm. The total particle numbers of nuclei mode

  11. Numerical studies about intermediate purification of using hydrogen peroxide to produce hydrazine hydrate%双氧水法制水合肼中间体提纯的数值模拟

    Institute of Scientific and Technical Information of China (English)

    王伟文; 朱国健; 李建隆

    2015-01-01

    在双氧水法制水合肼的过程中,通过研究产物的分离工艺流程,采用隔壁塔完成杂质的采出.用 Aspen Plus软件对组分的分离与提纯进行计算机模拟,同时考察进料位置、进料温度、回流比和塔压等因素对结果的影响,得到最佳工艺操作参数,为实际生产提供理论依据.从隔壁塔塔顶采出的杂质和丁酮的摩尔比为 0.023<0.03,符合回收的标准.同时,优化后冷凝器的能耗节省了 14.1%,再沸器的能耗节省了 10.8%.隔壁塔的主塔理论板数为 42 块,副塔理论板数为 14 块,进料位置为副塔第 13 块板,回流比为 7,操作压力为 0.101 MPa.塔底分离出的丁酮连氮百分数为 98.2%.%In the process of using hydrogen peroxide to produce hydrazine hydrate, the impurity was separated by the dividing wall column after the study on separation. Aspen Plus was used to simulation the process of isolation and purification of the components. The effect of factors such as feed location, feed temperature, reflux ratio and tower pressure were studied. The best process operating parameters were obtained to provide theoretical basis for the technology. The molar ratio of impurities to butanone collected from the top of the column was 0.023<0.03, reaching the standard for recovery. After optimization, 14.1% and 10.8% of the energy consumption of condenser and reboiler was saved, respectively. The theoretical plate number of main tower and deputy tower was 42 and 14, respectively. The feed position was 13 boards and the reflux ratio was 7 under operation pressure of 0.101 MPa. The percentage of the methyl ethyl ketone azine from the bottom of the tower was 98.2%.

  12. Intuitive Direction Concepts

    Directory of Open Access Journals (Sweden)

    Alexander Klippel

    2015-12-01

    Full Text Available Experiments in this article test the hypothesis that formal direction models used in artificial intelligence correspond to intuitive direction concepts of humans. Cognitively adequate formal models of spatial relations are important for information retrieval tasks, cognitive robotics, and multiple spatial reasoning applications. We detail two experiments using two objects (airplanes systematically located in relation to each other. Participants performed a grouping task to make their intuitive direction concepts explicit. The results reveal an important, so far insufficiently discussed aspect of cognitive direction concepts: Intuitive (natural direction concepts do not follow a one-size-fits-all strategy. The behavioral data only forms a clear picture after participants' competing strategies are identified and separated into categories (groups themselves. The results are important for researchers and designers of spatial formalisms as they demonstrate that modeling cognitive direction concepts formally requires a flexible approach to capture group differences.

  13. Directed Energy Anechoic Chamber

    Data.gov (United States)

    Federal Laboratory Consortium — The Directed Energy Anechoic Chamber comprises a power anechoic chamber and one transverse electromagnetic cell for characterizing radiofrequency (RF) responses of...

  14. Directional radiation detectors

    Energy Technology Data Exchange (ETDEWEB)

    Dowell, Jonathan L.

    2017-09-12

    Directional radiation detectors and systems, methods, and computer-readable media for using directional radiation detectors to locate a radiation source are provided herein. A directional radiation detector includes a radiation sensor. A radiation attenuator partially surrounds the radiation sensor and defines an aperture through which incident radiation is received by the radiation sensor. The aperture is positioned such that when incident radiation is received directly through the aperture and by the radiation sensor, a source of the incident radiation is located within a solid angle defined by the aperture. The radiation sensor senses at least one of alpha particles, beta particles, gamma particles, or neutrons.

  15. On Cyclic Variability in a Residual Effected HCCI Engine with Direct Gasoline Injection during Negative Valve Overlap

    Directory of Open Access Journals (Sweden)

    Jacek Hunicz

    2014-01-01

    Full Text Available This study contributes towards describing the nature of cycle-by-cycle variability in homogeneous charge compression ignition (HCCI engines. Experimental measurements were performed using a single cylinder research engine operated in the negative valve overlap (NVO mode and fuelled with direct gasoline injection. Both stoichiometric and lean mixtures were applied in order to distinguish between different exhaust-fuel reactions during the NVO period and their propagation into the main event combustion. The experimental results show that the mode of cycle-by-cycle variability depends on the NVO phenomena. Under stoichiometric mixture conditions, neither variability in the main event indicated mean effective pressure (IMEP nor the combustion timing was affected by the NVO phenomena; however, long period oscillations in IMEP were observed. In contrast, for lean mixture, where fuel oxidation during the NVO period took place, distinctive correlations between NVO phenomena and the main event combustion parameters were observed. A wavelet analysis revealed the presence of both long-term and short-term oscillations in IMEP, in accordance with the extent of NVO phenomena. Characteristic patterns in IMEP were recognized using an in-house algorithm.

  16. Differential electrochemical mass spectrometry study of Pt and PtSn nanocatalysts for direct ethanol fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Saidani, F.; Bommersbach, P.; Guay, D.; Mohamedi, M. [Quebec Univ., Institut National de la Recherche Scientifique, Varennes, PQ (Canada). Centre de l' Energie, Materiaux et Telecommunications; Rochefort, D. [Montreal Univ., PQ (Canada). Dept. of Chemistry

    2008-07-01

    This paper reported on a study that investigated Platinum (Pt) and Pt with tin (Sn) nanoparticles prepared under vacuum and under 2 Torr of He by pulsed laser ablation. This method was chosen because it is possible to control size of nanoparticles, structure and morphology of films by varying deposition conditions. The influence of deposition conditions on the electrocatalytic behaviour was determined. In particular, the objective of the study was to better understand the reaction mechanism involved during ethanol oxidation at Pt and PtSn catalysts by means of cyclic voltammetry combined with Differential Electrochemical Mass Spectrometry (DEMS), a powerful technique to elucidate the Ethanol Oxidation Reaction (EOR) mechanism. Ethanol was shown to be a very attractive liquid biofuel for direct-fuelled systems, since its partial oxidation products are less toxic than other alcohols. During pulsed laser ablation, the interaction between an intense laser and a target material resulted in the creation of plasma. This plasma enabled the transfer of matter from the target to the substrate. Highly nanocrystalline films can be prepared when deposition is performed into a moderate pressure gas. The electrochemical investigations showed that Pt deposited under 2 torr have a beneficial effect on the electrocatalytic activity towards ethanol oxidation. 5 refs., 1 fig.

  17. The role of technology in minimally invasive surgery: state of the art, recent developments and future directions.

    Science.gov (United States)

    Tonutti, Michele; Elson, Daniel S; Yang, Guang-Zhong; Darzi, Ara W; Sodergren, Mikael H

    2017-03-01

    The diffusion of minimally invasive surgery has thrived in recent years, providing substantial benefits over traditional techniques for a number of surgical interventions. This rapid growth has been possible due to significant advancements in medical technology, which partly solved some of the technical and clinical challenges associated with minimally invasive techniques. The issues that still limit its widespread adoption for some applications include the limited field of view; reduced manoeuvrability of the tools; lack of haptic feedback; loss of depth perception; extended learning curve; prolonged operative times and higher financial costs. The present review discusses some of the main recent technological advancements that fuelled the uptake of minimally invasive surgery, focussing especially on the areas of imaging, instrumentation, cameras and robotics. The current limitations of state-of-the-art technology are identified and addressed, proposing future research directions necessary to overcome them. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/.

  18. Decisions Concerning Directional Dependence

    Science.gov (United States)

    von Eye, Alexander; DeShon, Richard P.

    2012-01-01

    In this rejoinder, von Eye and DeShon discuss the decision strategies proposed in their original article ("Directional Dependence in Developmental Research," this issue), as well as the ones proposed by the authors of the commentary (Pornprasertmanit and Little, "Determining Directional Dependency in Causal Associations," this issue). In addition,…

  19. Direct current transformer

    Science.gov (United States)

    Khanna, S. M.; Urban, E. W. (Inventor)

    1979-01-01

    A direct current transformer in which the primary consists of an elongated strip of superconductive material, across the ends of which is direct current potential is described. Parallel and closely spaced to the primary is positioned a transformer secondary consisting of a thin strip of magnetoresistive material.

  20. Directed Energy Weapons

    Science.gov (United States)

    2007-12-01

    the USD (I) staff to be afocalpointfor advocating improvement in all dimensions of directed energy intelligence. - The Director, Defense Inteligence ...staff to be afocalpoint for advocating iprovement in all dimensions of directed energy intelligence. The Director, Defense Inteligence Ageng7 should

  1. Renovated treating method for the high-concentrated saline sewage from preparing hydrazine hydrate by means of ketazine process%酮连氮法制肼废水处理研究

    Institute of Scientific and Technical Information of China (English)

    李柏春; 黄会; 张文林; 许沉娜

    2012-01-01

    In this paper, we would like to introduce a renovated method for treating the high-concentrated saline sewage from preparing hydrazine hydrate by means of ketazine process, that is to say, a combined method that can integrate the chemical precipitation method and the sodium hypochlorite oxidation process into one to treat the sewage from preparing hydrazine hydrate in processing ketazine. The reason is that, on the part of sewage treatment, it can help to shift the treating process from the traditional removal to the recovery. As is known, the traditional biochemical method has been limited in use because the sewage to be treated is at low concentration of Chemical Oxygen Demand (CODCr)and high-salinity. Neither the chemical precipitation method can satisfy the need, for there come two chemicals containing Mg2+ and PO34- ions to be put into the sewage to generate the magnesium ammonium phosphate ( MAP) precipitation. Therefore, we prefer to choose MAP chemical precipitation technique for the MAP decomposition residues to be heated under the alkali condition can be reused in a recycling manner as magnesium and phosphate chemicals. Besides, the MAP chemical precipitation method enjoys a lot of advantages, such as simple in technology, fast in reaction speed, free from temperature limit, and high in the heavy-metal-ions-removing efficiency. To improve the removing efficiency, we have installed a special device for producing chlorine gas and sodium hypochlorite, which can be used as an oxidant in preparing azine. Since we have sufficient sodium hypochlorite, which is safe and convenient in use, it would be possible for us to use sodium hypochlorite to remove the sewage. Therefore, we have chosen the chemical precipitation method and the sodium hypochlorite oxidation process to treat the sewage under question in our research. The experimental results demonstrate that the ammonia removal efficiency could be achieved to 96.8% , when pH is regulated to 9.0, and the compo

  2. Direction and Description

    Science.gov (United States)

    Ben-Menahem, Yemima

    This paper deals with the dependence of directionality in the course of events-or our claims concerning such directionality-on the modes of description we use in speaking of the events in question. I argue that criteria of similarity and individuation play a crucial role in assessments of directionality. This is an extension of Davidson's claim regarding the difference between causal and explanatory contexts. The argument is based on a characterisation of notions of necessity and contingency that differ from their modal logic counterparts on the one hand, and from causality and chance on the other. I show that some types of directionality are perfectly compatible with both determinism and indeterminism at the microscopic level, and that there is no likelihood of, or advantage to, reducing such directionality to other laws or causal processes.

  3. Direct peroral cholangioscopy

    Science.gov (United States)

    Parsi, Mansour A

    2014-01-01

    Peroral cholangioscopy is an important tool for diagnosis and treatment of various biliary disorders. Peroral cholangioscopy can be performed by using a dedicated cholangioscope that is advanced through the accessory channel of a duodenoscope, or by direct insertion of a small-diameter endoscope into the bile duct. Direct peroral cholangioscopy refers to insertion of an ultraslim endoscope directly into the bile duct for visualization of the biliary mucosa and lumen. This approach provides a valuable and economic solution for diagnostic and therapeutic applications in the biliary tree. Compared to ductoscopy using a dedicated cholangioscope, the direct approach has several advantages and disadvantages. In this editorial, I discuss the advantages, disadvantages, and possible future developments pertaining to direct peroral cholangioscopy. PMID:24527174

  4. Lighting Studies for Fuelling Machine Deployed Visual Inspection Tool

    Energy Technology Data Exchange (ETDEWEB)

    Stoots, Carl [Idaho National Lab. (INL), Idaho Falls, ID (United States); Griffith, George [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-04-01

    Under subcontract to James Fisher Nuclear, Ltd., INL has been reviewing advanced vision systems for inspection of graphite in high radiation, high temperature, and high pressure environments. INL has performed calculations and proof-of-principle measurements of optics and lighting techniques to be considered for visual inspection of graphite fuel channels in AGR reactors in UK.

  5. A cislunar transportation system fuelled by lunar resources

    Science.gov (United States)

    Sowers, G. F.

    2016-11-01

    A transportation system for a self sustaining economy in cislunar space is discussed. The system is based on liquid oxygen (LO2), liquid hydrogen (LH2) propulsion whose fuels are derived from ice mined at the polar regions of the Moon. The elements of the transportation system consist of the Advanced Cryogenic Evolved Stage (ACES) and the XEUS lander, both being developed by United Launch Alliance (ULA). The main propulsion elements and structures are common between ACES and XEUS. Both stages are fully reusable with refueling of their LO2/LH2 propellants. Utilization of lunar sourced propellants has the potential to dramatically lower the cost of transportation within the cislunar environs. These lower costs dramatically lower the barriers to entry of a number of promising cislunar based activities including space solar power. One early application of the architecture is providing lunar sourced propellant to refuel ACES for traditional spacecraft deployment missions. The business case for this application provides an economic framework for a potential lunar water mining operation.

  6. Modeling economic growth fuelled by science and technology

    Directory of Open Access Journals (Sweden)

    Leonardo Costa Ribeiro

    2010-06-01

    Full Text Available This paper suggests a simulation model to investigate how science and technology fuel economic growth. This model is built upon a synthesis of technological capabilities represented by national innovation systems. This paper gathers data of papers and patents for 183 countries between 1999 and 2003, as well as GDP and population for 2003. These data show a strong correlation between science, technology and income. Three simulation exercises are performed. Feeding our algorithm with data for population, patents and scientific papers, we obtain the world income distribution. These results support our conjecture on the role of science and technology as sources of the wealth of nations.Este artigo propõe um modelo de simulação para investigar a contribuição da ciência e da tecnologia para o crescimento econômico. O ponto de partida são os sistemas nacionais de inovação, um conceito que sintetiza a capacitação tecnológica das nações. Desta forma, o modelo pode preservar simplicidade e parcimônia. Os dados coletados (patentes, artigos e PIB e população, para 183 países indicam uma forte correlação entre ciência, tecnologia e renda. Três exercícios com simulações são realizados para diversos momentos do tempo, mostrando a progressiva aderência do modelo a essas variáveis tecnológicas.

  7. The Magnetic Shielding Effect of a Re-Fuelling Pellet

    DEFF Research Database (Denmark)

    Chang, C. T.

    1975-01-01

    The magnetic shielding effect of a refuelling pellet is considered by first briefly reviewing the existing balloon model. The limitation of the model is pointed out and discussed. Since solid deuterium is an insulator and the ablated plasma is expected to be cold and dense, it is felt...... that the existence of a field-free balloon is questionable; rather some field will be trapped by the pellet. On the assumption that the flow of the ablated plasma is governed by a flexible magnetic nozzle, it is shown that the reduction of the ablation rate of the pellet is not due to the exclusion of the field...... by a balloon, but to the reduction of the ablated plasma pressure through the trapping of the field inside the nozzle. The model also indicates that the penetration of a mm-size pellet into the centre of a low-β reactor might be possible, provided an injection speed around 104 m centerdots−1 can be attained...

  8. Titanium doped LSCM anode for hydrocarbon fuelled SOFCs

    Energy Technology Data Exchange (ETDEWEB)

    Azad, Abul K.; Hakem, Afizul; Petra, Pg. M. Iskandar [Faculty of Integrated Technologies, Universiti Brunei Darussalam, Gadong BE 1410 (Brunei Darussalam)

    2015-05-15

    La{sub 0.75}Sr{sub 0.25}Cr{sub 0.5-x}Mn{sub 0.5}Ti{sub x}O{sub 3} (x = 0.1, 0.2) has been synthesized in solid state reaction method and tested as a potential anode material for solid oxide fuel cells. Rietveld refinement of X-ray powder diffraction data using Fullprof software shows that the materials crystallize in the rhombohedral symmetry in the R-3C space group. The cell parameters are: a = b = 5.5286 (4) Å, c = 13.408(1) Å, α = β = 90°, γ = 120°. Particle size distribution measurements show that the average particle size for x = 0.1 and 0.2 was 232.66 nm and 176.63 nm, respectively. The potential on particles were found to be −22.86 mV and −27.73 mV, for x = 0.1 and x = 0.2, respectively. Thermal expansion measurement using thermo-mechanical analyzer shows that the thermal expansion coefficient is 13.96 × 10{sup −6}/°C which is close to the thermal expansion of the state-of–the art YSZ electrolyte. Microstructure has been observed from scanning electron microscopy which shows a porous structure. Energy dispersive X-ray shows that the percentage of the different cations and anions in the structure are close to the chemical occupancies.

  9. Detailed experimental characterization of a reformate fuelled PEM stack

    DEFF Research Database (Denmark)

    Korsgaard, Anders; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2006-01-01

    Increasing attention is given to fuel cells for micro combined heat and power systems for local households. Currently, mainly three different types of fuel cells are commercially competitive: SOFC, low- and high-temperature PEM fuel cells. In the present paper the Low Temperature PEM technology...... performance and process input variations need to be carefully accounted for. Such data will additionally provide valuable input for system modeling and optimization. The paper presents an advanced experimental test facility capable of performing static as well as dynamic tests on fuel cell stacks...

  10. Can hydrogen win?: exploring scenarios for hydrogen fuelled vehicles

    OpenAIRE

    Muncaster, Katherine Aminta

    2008-01-01

    This study explored the conditions under which hydrogen might succeed in Canada’s transportation sector in a carbon-constrained world. Long-run simulations were created using CIMS, a hybrid energy-economy model that is technologically explicit, behaviourally realistic, and incorporates drivers of technological change. A hydrogen supply submodel was built to simulate economies of scale in infrastructure. Capital costs, technology performance, infrastructure, fuel prices, and other conditions w...

  11. Amazon River carbon dioxide outgassing fuelled by wetlands

    NARCIS (Netherlands)

    Abril, G.; Martinez, J.M.; Artigas, L.F.; Moreira-Turcq, P.; Benedetti, M.F.; Vidal, L.; Meziane, T.; Kim, J.-H.; Bernardes, M.C.; Savoye, N.; Deborde, J.; Souza, E.L.; Alberic, P.; de Souza, M.F.L.; Roland, F.

    2014-01-01

    River systems connect the terrestrial biosphere, the atmosphere and the ocean in the global carbon cycle(1). A recent estimate suggests that up to 3 petagrams of carbon per year could be emitted as carbon dioxide (CO2) from global inland waters, offsetting the carbon uptake by terrestrial

  12. Amazon River carbon dioxide outgassing fuelled by wetlands

    Science.gov (United States)

    Abril, Gwenaël; Martinez, Jean-Michel; Artigas, L. Felipe; Moreira-Turcq, Patricia; Benedetti, Marc F.; Vidal, Luciana; Meziane, Tarik; Kim, Jung-Hyun; Bernardes, Marcelo C.; Savoye, Nicolas; Deborde, Jonathan; Souza, Edivaldo Lima; Albéric, Patrick; Landim de Souza, Marcelo F.; Roland, Fabio

    2014-01-01

    River systems connect the terrestrial biosphere, the atmosphere and the ocean in the global carbon cycle. A recent estimate suggests that up to 3 petagrams of carbon per year could be emitted as carbon dioxide (CO2) from global inland waters, offsetting the carbon uptake by terrestrial ecosystems. It is generally assumed that inland waters emit carbon that has been previously fixed upstream by land plant photosynthesis, then transferred to soils, and subsequently transported downstream in run-off. But at the scale of entire drainage basins, the lateral carbon fluxes carried by small rivers upstream do not account for all of the CO2 emitted from inundated areas downstream. Three-quarters of the world's flooded land consists of temporary wetlands, but the contribution of these productive ecosystems to the inland water carbon budget has been largely overlooked. Here we show that wetlands pump large amounts of atmospheric CO2 into river waters in the floodplains of the central Amazon. Flooded forests and floating vegetation export large amounts of carbon to river waters and the dissolved CO2 can be transported dozens to hundreds of kilometres downstream before being emitted. We estimate that Amazonian wetlands export half of their gross primary production to river waters as dissolved CO2 and organic carbon, compared with only a few per cent of gross primary production exported in upland (not flooded) ecosystems. Moreover, we suggest that wetland carbon export is potentially large enough to account for at least the 0.21 petagrams of carbon emitted per year as CO2 from the central Amazon River and its floodplains. Global carbon budgets should explicitly address temporary or vegetated flooded areas, because these ecosystems combine high aerial primary production with large, fast carbon export, potentially supporting a substantial fraction of CO2 evasion from inland waters.

  13. Prospects for advanced coal-fuelled fuel cell power plants

    Science.gov (United States)

    Jansen, D.; Vanderlaag, P. C.; Oudhuis, A. B. J.; Ribberink, J. S.

    1994-04-01

    As part of ECN's in-house R&D programs on clean energy conversion systems with high efficiencies and low emissions, system assessment studies have been carried out on coal gasification power plants integrated with high-temperature fuel cells (IGFC). The studies also included the potential to reduce CO2 emissions, and to find possible ways for CO2 extraction and sequestration. The development of this new type of clean coal technology for large-scale power generation is still far off. A significant market share is not envisaged before the year 2015. To assess the future market potential of coal-fueled fuel cell power plants, the promise of this fuel cell technology was assessed against the performance and the development of current state-of-the-art large-scale power generation systems, namely the pulverized coal-fired power plants and the integrated coal gasification combined cycle (IGCC) power plants. With the anticipated progress in gas turbine and gas clean-up technology, coal-fueled fuel cell power plants will have to face severe competition from advanced IGCC power plants, despite their higher efficiency.

  14. Detailed experimental characterization of a reformate fuelled PEM stack

    DEFF Research Database (Denmark)

    Korsgaard, Anders; Nielsen, Mads Pagh; Kær, Søren Knudsen

    2006-01-01

    is in focus. To be able to design highly efficient micro CHP systems, it is critical to have a reliable performance map of not only the stack performance in the nominal operating point but also at system part load.  Issues like parasitic power consumption of the balance of plant components, dynamic...

  15. Experimental investigations on CRDI diesel engine fuelled with acid ...

    African Journals Online (AJOL)

    In this work the biodiesel is produced by acid oil a waste by-product of vegetable oil ... refinery sites, value addition for the unwanted byproduct acid oil, considerable reduction in energy demands of vegetable oil ... Acid oil principally consist of extended-chain free fatty-acid combination in conjunction with .... Power Supply.

  16. Bio-oil fuelled diesel power plant; Biooeljyllae toimiva dieselvoimala

    Energy Technology Data Exchange (ETDEWEB)

    Vuorinen, A. [Modigen Oy, Helsinki (Finland)

    1997-12-01

    The project mission is to develop a diesel power plant which is capable of using liquid bio-oils as the main fuel of the power plant. The applicable bio-oils are rape seed oils and pyrolysis oils. The project was started in 1994 by installing a 1.5 MW Vasa 4L32 engine in VTT Energy laboratory in Otaniemi. During 1995 the first tests with the rape seed oils were made. The tests show that the rape seed oil can be used in Vasa 32 engines without difficulties. In the second phase of the project during 1996 pyrolysis oil made of wood was tested. Finally a diesel power plant concept with integrated pyrolysis oil, electricity and heat production will be developed

  17. Direct Conversion of Energy

    Energy Technology Data Exchange (ETDEWEB)

    Corliss, William R

    1964-01-01

    Topics include: direct versus dynamic energy conversion; laws governing energy conversion; thermoelectricity; thermionic conversion; magnetohydrodynamic conversion; chemical batteries; the fuel cell; solar cells; nuclear batteries; and advanced concepts including ferroelectric conversion and thermomagnetic conversion.

  18. Direct sale in USA

    OpenAIRE

    Koula, Alexandr

    2014-01-01

    This thesis deals with direct sales. The thesis discuss the connection between theoretical part of my personal experience as a door to door sales person in the US, describing a sales process, using a techniques of direct sales and communication skills in practice. It stresses the importance of understanding the basic concepts of personality and communication. The main objective of this work is a suggestion to improve the sales manual for increasing sales success of door to door sales persons ...

  19. Directed GF-spaces

    Directory of Open Access Journals (Sweden)

    F.G. Arenas

    2001-10-01

    Full Text Available In this paper we introduce the concept of directed fractal structure, which is a generalization of the concept of fractal structure (introduced by the authors. We study the relation with transitive quasiuniformities and inverse limits of posets. We define the concept of GF-compactification and apply it to prove that the Stone-Cech compactification can be obtained as the GF-compactification of the directed fractal structure associated to the Pervin quasi-uniformity.

  20. Laboratory Evaluation of a Colorimetric Hydrazine Dosimeter

    Science.gov (United States)

    1990-06-12

    Dose Response Curve at T=O for PDAB (D12) without Diffusion Membrane o 0.1 ppm x 0.2 ppm v 0.4 ppm - 1-6 ppm 10 0 - 9 o x a 0 8 0 7 x 6 0 O 5 -V...x x 4 0- 1X 3r V x 2 0- x 00 0 2 4 6 8 10 12 14 16 18 20 Dose (TLV-hrs) Fig. 6b. MMH Dose Response Curve at T=I for PDAB (D12) without Diffusion...TLV-hrs) Fig. 6c. MMH Dose Response Curve at T=0 for PDAB (D12) with Diffusion Membrane 11 o 0.1 ppm x 0.2 ppm v 0.4 ppm * 1-6 ppm 10 9 B 8 0 a; xx7

  1. Hydrazine and the Methylation of DNA Guanine

    Science.gov (United States)

    1983-08-01

    WRIGHT-PATTERSON AIR FORCE BASE, OHIO 45433 1 COMUNIY AN E RONENTA MEDCIN NOTICES When US Government drawings, specifications, or other data are used for...electrophiles. In Origins of Human Cancer, Book B, Mechanisms of Carcinogenesis, H.H. Hiatt, J.D. Watson and J.A. Winston, eds., Cold Spring Harbor

  2. Optoacoustic Spectroscopy to Detect Hydrazine Fuels.

    Science.gov (United States)

    1981-07-01

    difference between the total pressure P, and its average value, Po: p = p - p 01)0 Morse and Ingard (228) have shown there is an acoustic velocity u(r,t...sound. New York: McGraw-Hill, 1948. 227. Morse, P. M., and K. V. Ingard . Encyclopedia of physics, vol XI, p. 1. Berlin: Springer-Verlag, 1961. 228...Morse, P. M., and K. V. Ingard . Theoretical acoustics. New York: McGraw-Hill, 1968. 229. Motchenbacher, C. D., and F. C. Fitchen. Low noise electronic

  3. Oxidation of Hydrazine in Aqueous Solutions

    Science.gov (United States)

    1978-03-01

    mechanism is different in the two different temperature regions [ Levenspiel (Reference 21)]. Lurker (Reference 7) also observed that at 6°C a kinetic...and Bielski, B., Kinetic Systems: Mathematical Descriptions of Chemical Kinetics in Solution, Wiley Interscience, New York (1972). 21. Levenspiel , 0

  4. UV-visible digital imaging of split injection in a Gasoline Direct Injection engine

    Directory of Open Access Journals (Sweden)

    Merola Simona Silvia

    2015-01-01

    Full Text Available Ever tighter limits on pollutant emissions and the need to improve energy conversion efficiency have made the application of gasoline direct injection (GDI feasible for a much wider scale of spark ignition engines. Changing the way fuel is delivered to the engine has thus provided increased flexibility but also challenges, such as higher particulate emissions. Therefore, alternative injection control strategies need to be investigated in order to obtain optimum performance and reduced environmental impact. In this study, experiments were carried out on a single-cylinder GDI optical engine fuelled with commercial gasoline in lean-burn conditions. The single-cylinder was equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio and wall guided fuel injection. Optical accessibility was ensured through a conventional elongated hollow Bowditch piston and an optical crown, accommodating a fused-silica window. Experimental tests were performed at fixed engine speed and injection pressure, whereas the injection timing and the number of injections were adjusted to investigate their influence on combustion and emissions. UV-visible digital imaging was applied in order to follow the combustion process, from ignition to the late combustion phase. All the optical data were correlated with thermodynamic analysis and measurements of exhaust emissions. Split injection strategies (i.e. two injections per cycle with respect to single injection increased combustion efficiency and stability thanks to an improvement of fuel air mixing. As a consequence, significant reduction in soot formation and exhaust emission with acceptable penalty in terms of HC and NOx were measured.

  5. Electrohydrodynamic direct-writing

    Science.gov (United States)

    Huang, Yongan; Bu, Ningbin; Duan, Yongqing; Pan, Yanqiao; Liu, Huimin; Yin, Zhouping; Xiong, Youlun

    2013-11-01

    The electrohydrodynamic (EHD) direct-writing technique can be used to print solid/liquid straight/serpentine nanofibers onto a large-area substrate, in a direct, continuous, and controllable manner. It is a high-efficiency and cost-effective solution-processable technique to satisfy increasing demands of large-area micro/nano-manufacturing. It is ground-breaking to direct-write sub-100 nm fibers on a rigid/flexible substrate using organic materials. A comprehensive review is presented on the research and developments related to the EHD direct-writing technique and print heads. Many developments have been presented to improve the controllability of the electrospun fibers to form high-resolution patterns and devices. EHD direct-writing is characterized by its non-contact, additive and reproducible processing, high resolution, and compatibility with organic materials. It combines dip-pen, inkjet, and electrospinning by providing the feasibility of controllable electrospinning for sub-100 nm nanofabrication, and overcomes the drawbacks of conventional electron-beam lithography, which is relatively slow, complicated and expensive.

  6. Direct conversion technology

    Energy Technology Data Exchange (ETDEWEB)

    Massier, P.F.; Back, L.H.; Ryan, M.A.; Fabris, G.

    1992-01-07

    The overall objective of the Direct Conversion Technology task is to develop an experimentally verified technology base for promising direct conversion systems that have potential application for energy conservation in the end-use sectors. This report contains progress of research on the Alkali Metal Thermal-to-Electric Converter (AMTEC) and on the Two-Phase Liquid-Metal MHD Electrical Generator (LMMHD) for the period January 1, 1991 through December 31, 1991. Research on AMTEC and on LMMHD was initiated during October 1987. Reports prepared on previous occasions (Refs. 1--5) contain descriptive and performance discussions of the following direct conversion concepts: thermoelectric, pyroelectric, thermionic, thermophotovoltaic, thermoacoustic, thermomagnetic, thermoelastic (Nitionol heat engine); and also, more complete descriptive discussions of AMTEC and LMMHD systems.

  7. Directional loudness perception

    DEFF Research Database (Denmark)

    Sivonen, Ville Pekka

    reaches the listener affect its perceived loudness. The results obtained in a series of listening experiments show that loudness depends considerably on direction for a variety of sound stimuli. Furthermore, these directional dependencies could be largely accounted for by determining binaural at......Loudness, the perceived intensity of sound, is a fundamental attribute in psychoacoustics. An immense body of literature on loudness has been accumulated, and based on the reported findings, models for predicting loudness from monophonic, acoustical measurements of sound pressure have been...... developed. The research and modeling of loudness have mainly been concerned with the temporal and spectral aspects of sounds, while the spatial aspects have mostly been overlooked. This PhD thesis investigates the spatial aspects of loudness perception, namely, how does the direction from which a sound...

  8. Eletroanálise de derivados acetaldeído com hidrazina e determinação em amostras de álcool combustível por voltametria de onda quadrada Electroanalysis of acetaldehyde derivatized with hydrazine and determination in fuel ethanol by square wave voltammetry

    Directory of Open Access Journals (Sweden)

    Vanessa S. Rodgher

    2006-07-01

    Full Text Available A square wave voltammetric method is described for the determination of acetaldehyde using the derivatization reaction with hydrazine sulphate, based on the reduction of hydrazone generated as a product that exhibits a single well-defined peak at -1.19V in acetate buffer at pH 5. Calibration graphs were obtained from 1.0 x 10-6 mol L-1 to 10 x 10-6 mol L-1 of acetaldehyde, using a reaction time of 8 min and a hidrazine concentration of 0.02 mol L-1. The detection limit was 2.38 x 10-7 mol L-1. The method was applied satisfactorily to the determination of total aldehyde in fuel ethanol samples without any pre-treatment.

  9. Modelling directional solidification

    Science.gov (United States)

    Wilcox, William R.; Regel, Liya L.

    1994-01-01

    This grant, NAG8-831, was a continuation of a previous grant, NAG8-541. The long range goal of this program has been to develop an improved understanding of phenomena of importance to directional solidification, in order to enable explanation and prediction of differences in behavior between solidification on Earth and in space. Emphasis in the recently completed grant was on determining the influence of perturbations on directional solidification of InSb and InSb-GaSb alloys. In particular, the objective was to determine the influence of spin-up/spin-down (ACRT), electric current pulses and vibrations on compositional homogeneity and grain size.

  10. The direction of time

    CERN Document Server

    Reichenbach, Hans

    1999-01-01

    Ever a source of philosophical conjecture and debate, the concept of time represents the beating heart of physics. This final work by the distinguished physicist Hans Reichenbach represents the culmination and integration of a lifetime's philosophical contributions and inquiries into the analysis of time. The result is an outstanding overview of such qualitative, or topological, attributes of time as order and direction.Beginning with a discussion of the emotive significance of time, Reichenbach turns to an examination of the time order of mechanics, the time direction of thermodynamics and m

  11. Incretin secretion: direct mechanisms

    DEFF Research Database (Denmark)

    Balk-Møller, Emilie; Holst, Jens Juul; Kuhre, Rune Ehrenreich

    2014-01-01

    The incretin hormones glucose-dependent insulinotropic polypeptide (GIP) and glucagon-like peptide 1 (GLP-1) are secreted from gastro-intestinal K- and L-cells, respectively, and play an important role in post-prandial blood glucose regulation. They do this by direct stimulation of the pancreatic β...... enzyme responsible for incretin degradation (dipeptidyl peptidase-4) is inhibited (drugs are already on the market) while the secretion of endogenous GLP-1 secretion is stimulated at the same time may prove particularly rewarding. In this section we review current knowledge on the mechanisms for direct...

  12. Direct policy search

    DEFF Research Database (Denmark)

    Heidrich-Meisner, V.; Igel, Christian

    2010-01-01

    process. Exploration is realized by stochastic perturbations, which can be applied at different levels. When considering direct policy search in the space of neural network policies, exploration can be applied on the synaptic level or on the level of neuronal activity. We propose neuroevolution strategies...... (NeuroESs) for direct policy search in RL. Learning using NeuroESs can be interpreted as modelling of extrinsic perturbations on the level of synaptic weights. In contrast, policy gradient methods (PGMs) can be regarded as intrinsic perturbation of neuronal activity. We compare these two approaches...

  13. [New direct restorative materials].

    Science.gov (United States)

    Hickel, R; Dasch, W; Janda, R; Tyas, M; Anusavice, K

    1999-04-01

    People worldwide have become increasingly aware of the potential adverse effects on the environment, of pollution control and of toxic effects of food, drugs and biomaterials. Amalgam and its potential toxic side effects (still scientifically unproven) continue to be discussed with increasing controversy by the media in some countries. Consequently, new direct restorative materials are now being explored by dentists, materials scientists and patients who are searching for the so-called 'amalgam substitute' or 'amalgam alternative'. From a critical point of view some of the new direct restorative materials are good with respect in aesthetics, but all material characteristics must be considered, such as mechanical properties, biological effects, and longterm clinical behaviour.

  14. Directions for further research

    DEFF Research Database (Denmark)

    Minsaas, Atle; Psaraftis, Harilaos N.

    2015-01-01

    chapter of this book we discuss directions for further research in this area. We do so by taking stock of (1) related recommendations of project SuperGreen, and (2) related activities mainly in European research. Links between research and policy-making as two activities that should go hand in hand...

  15. Advanced directives: open issues

    Directory of Open Access Journals (Sweden)

    Gabriella Negrini

    2013-05-01

    Full Text Available BACKGROUND In Italy Advanced directives have not been regulated by law yet. Moreover, there is a confusion of concepts: advanced directives, refusal of treatment, medical futility and euthanasia are not synonymous.DISCUSSION The following aspects are then discussed: object of directives; elapse of time between their expression and their application; knowledge of the directives and their obligatory nature. The refusal of a treatment that can save a person’s life is a critical subject. There are different ethical points of view: according to lay ethics, the patient’s self-determination prevails; the religious viewpoint, instead, says that life is a gift which we cannot dispose of. In any case, the patient will be confronted with the professional autonomy of the doctor. Should the doctor save a patient’s life in any case or should he achieve best clinical practice, in respect of his will? The doctor should interpret the patient’s will but with caution and judgment. An exemption from responsibility should be provided by law for doctors who respect patient’s living will.

  16. Direct Sulfation of Limestone

    DEFF Research Database (Denmark)

    Hu, Guilin; Dam-Johansen, Kim; Wedel, Stig

    2007-01-01

    The direct sulfation of limestone was studied in a laboratory fixed-bed reactor. It is found that the direct sulfation of limestone involves nucleation and crystal grain growth of the solid product (anhydrite). At 823 K and at low-conversions (less than about 0.5 %), the influences of SO2, O-2...... and CO2 on the direct sulfation of limestone corresponds to apparent reaction orders of about 0.2, 0.2 and -0.5, respectively. Water is observed to promote the sulfation reaction and increase the apparent reaction orders of SO2 and O-2. The influence of O-2 at high O-2 concentrations (> about 15...... %) becomes negligible. In the temperature interval from 723 K to 973 K, an apparent activation energy of about 104 kJ/mol is observed for the direct sulfation of limestone. At low temperatures and low conversions, the sulfation process is most likely under mixed control by chemical reaction and solid...

  17. Direct vision internal urethrotomy

    DEFF Research Database (Denmark)

    Jakobsen, H; Willumsen, H; Søndergaard Jensen, L

    1984-01-01

    During a five-year period, direct vision internal urethrotomy was used for the treatment of urethral strictures in 34 men. After the primary operation the patients were followed for an average period of 29 months (range 3-73 months). During this period 53% of the patients were found to have one...

  18. Directed and diode percolation

    Science.gov (United States)

    Redner, S.

    1982-03-01

    We study the novel percolation phenomena that occur in random-lattice networks consisting of resistor-like and diode-like bonds. Resistor bonds connect or "transmit information" in either direction along their length, while diodes connect in one direction only. We first treat the special case of directed bond percolation, in which the diodes are aligned along a preferred axis. Mean-field theory shows that clusters become extremely anisotropic near the percolation transition and that their shapes are characterized by two correlation lengths, one parallel and one transverse to the preferred axis. These lengths diverge with exponents ν∥=1 and ν⊥=12, respectively, from which we can show that the upper critical dimension for this system must be five. We also treat a more general random network on the square lattice containing resistors and diodes of arbitrary orientation. Duality arguments are applied to obtain exact results for the location of phase transitions in this system. We then use a position-space renormalization-group approach to map out the phase diagram and calculate critical exponents. This system has an isotropic percolating phase, and phases which percolate in only one direction. Novel types of transitions occur between these phases, in which the diode orientation plays a fundamental role. These percolating phases meet with the nonpercolating phase along a line of multicritical points, where concentration and orientational fluctuations are simultaneously critical.

  19. The Directed Case Method.

    Science.gov (United States)

    Cliff, William H.; Curtin, Leslie Nesbitt

    2000-01-01

    Provides an example of a directed case on human anatomy and physiology. Uses brief real life newspaper articles and clinical descriptions of medical reference texts to describe an actual, fictitious, or composite event. Includes interrelated human anatomy and physiology topics in the scenario. (YDS)

  20. Polymer Directed Protein Assemblies

    Directory of Open Access Journals (Sweden)

    Patrick van Rijn

    2013-05-01

    Full Text Available Protein aggregation and protein self-assembly is an important occurrence in natural systems, and is in some form or other dictated by biopolymers. Very obvious influences of biopolymers on protein assemblies are, e.g., virus particles. Viruses are a multi-protein assembly of which the morphology is dictated by poly-nucleotides namely RNA or DNA. This “biopolymer” directs the proteins and imposes limitations on the structure like the length or diameter of the particle. Not only do these bionanoparticles use polymer-directed self-assembly, also processes like amyloid formation are in a way a result of directed protein assembly by partial unfolded/misfolded biopolymers namely, polypeptides. The combination of proteins and synthetic polymers, inspired by the natural processes, are therefore regarded as a highly promising area of research. Directed protein assembly is versatile with respect to the possible interactions which brings together the protein and polymer, e.g., electrostatic, v.d. Waals forces or covalent conjugation, and possible combinations are numerous due to the large amounts of different polymers and proteins available. The protein-polymer interacting behavior and overall morphology is envisioned to aid in clarifying protein-protein interactions and are thought to entail some interesting new functions and properties which will ultimately lead to novel bio-hybrid materials.

  1. Direct formation of small Cu2O nanocubes, octahedra, and octapods for efficient synthesis of triazoles

    Science.gov (United States)

    Tsai, Ya-Huei; Chanda, Kaushik; Chu, Yi-Ting; Chiu, Chun-Ya; Huang, Michael H.

    2014-07-01

    In most studies describing the preparation of Cu2O crystals of various morphologies, the particle sizes are normally hundreds of nanometers to micrometers due to rapid particle growth, so they are not exactly nanocrystals. Here we report surfactant-free formation of sub-100 nm Cu2O nanocrystals with systematic shape evolution from cubic to octahedral structures by preparing an aqueous mixture of Cu(OAc)2, NaOH, and N2H4 solution. Adjustment of the hydrazine volume enables the particle shape control. Uniform nanocubes and octahedra were synthesized with edge lengths of 37 and 67 nm, respectively. Novel Cu2O octapods with an edge length of 135 nm were also produced by mixing CuCl2 solution, SDS surfactant, NaOH solution, and NH2OH.HCl reductant solution. All of them are nearly the smallest Cu2O nanocrystals of the same shapes ever reported. These small cubes, octahedra, and octapods were employed as catalysts in the direct synthesis of 1,2,3-triazoles from the reaction of alkynes, organic halides, and NaN3 at 55 °C. All of them displayed high product yields in short reaction times. The octahedra enclosed by the {111} facets are the best catalysts, and can catalyze this cycloaddition reaction with high yields in just 2 h when different alkynes were used to make diverse triazole products. Hence, the small Cu2O particles provide time-saving, energy-efficient, and high product yield benefits to organocatalysis.In most studies describing the preparation of Cu2O crystals of various morphologies, the particle sizes are normally hundreds of nanometers to micrometers due to rapid particle growth, so they are not exactly nanocrystals. Here we report surfactant-free formation of sub-100 nm Cu2O nanocrystals with systematic shape evolution from cubic to octahedral structures by preparing an aqueous mixture of Cu(OAc)2, NaOH, and N2H4 solution. Adjustment of the hydrazine volume enables the particle shape control. Uniform nanocubes and octahedra were synthesized with edge

  2. Polar Direct Drive

    Science.gov (United States)

    Skupsky, S.

    2003-10-01

    Direct drive offers the potential of higher target gain on the National Ignition Facility (NIF) than x-ray drive: The initial direct-drive target design had a 1-D gain of 45 and consisted primarily of a pure cryogenic DT shell. Using the expected levels of target and laser nonuniformities for the NIF, two-dimensional (2-D) hydrodynamic simulations predicted target gains around 30.(P.W. McKenty et al.), Phys. Plasmas 8, 2315 (2001). More-recent designs have shown that higher target gains could be obtained by replacing a portion of the DT shell with ``wetted'' CH foam and by using adiabat shaping: (1) Higher-Z material (C) in the foam increases laser absorption by about 40% (from 60% absorption to 85%).(S. Skupsky et al.), in Inertial Fusion Sciences and Applications 2001, edited by K. Tanaka et al. (Elsevier, Paris, 2002), p. 240. (2) Adiabat shaping allows the main portion of the fuel to be placed on a lower adiabat without compromising target stability.(V.N. Goncharov et al.), Phys. Plasmas 10, 1906 (2003). These direct-drive concepts can be tested on the NIF, long before that facility is converted to a direct-drive (spherically symmetric) irradiation configuration. Using the NIF x-ray-drive beam configuration, some of the near-polar beams could be pointed to better illuminate the target's equator. These more-oblique, equatorial beams will have lower absorption and reduced drive efficiency than the polar beams. One strategy to compensate for the difference in polar and equatorial drive is to reduce the irradiation at the poles and employ different pulse shapes to accommodate the time-dependent variations in drive and absorption. This concept of polar direct drive (PDD) has been studied using the 2-D hydrocode DRACO to determine the requirements for achieving ignition and moderate target gain for the NIF. Experiments on the OMEGA laser will examine the effects of oblique irradiation on target drive. Results of simulations for different direct-drive target designs

  3. Direction sensitive neutron detector

    Energy Technology Data Exchange (ETDEWEB)

    Ahlen, Steven; Fisher, Peter; Dujmic, Denis; Wellenstein, Hermann F.; Inglis, Andrew

    2017-01-31

    A neutron detector includes a pressure vessel, an electrically conductive field cage assembly within the pressure vessel and an imaging subsystem. A pressurized gas mixture of CF.sub.4, .sup.3He and .sup.4He at respective partial pressures is used. The field cage establishes a relatively large drift region of low field strength, in which ionization electrons generated by neutron-He interactions are directed toward a substantially smaller amplification region of substantially higher field strength in which the ionization electrons undergo avalanche multiplication resulting in scintillation of the CF.sub.4 along scintillation tracks. The imaging system generates two-dimensional images of the scintillation patterns and employs track-finding to identify tracks and deduce the rate and direction of incident neutrons. One or more photo-multiplier tubes record the time-profile of the scintillation tracks permitting the determination of the third coordinate.

  4. [Direct biosynthesis of ethylene].

    Science.gov (United States)

    Sun, Zhilan; Chen, Yifeng

    2013-10-01

    Ethylene is the most widely used petrochemical feedstock globally. The development of bio-ethylene is essential due to limited fossil fuels and rising oil prices. Bio-ethylene is produced primarily by the dehydration of ethanol, but can alternatively be directly produced from ethylene biosynthesis pathways in plants, algae, or microorganisms by using cheap and renewable substrates. This review addressed the biosynthesis of ethylene in plants and microorganisms, the characterization of key enzymes, genetic engineering strategies for ethylene biosynthesis in microorganisms, and evaluated its perspective and successful cases toward the industrial application. The direct production of bio-ethylene from a biological process in situ is promising to supplement and even replace the petrochemical ethylene production.

  5. Direct photons at FAIR

    Energy Technology Data Exchange (ETDEWEB)

    Baeuchle, Bjoern [Frankfurt Institute for Advanced Studies (FIAS), Ruth-Moufang-Str. 1, D-60438 Frankfurt am Main (Germany); Bleicher, Marcus; Grimm, Andreas [Frankfurt Institute for Advanced Studies (FIAS), Ruth-Moufang-Str. 1, D-60438 Frankfurt am Main (Germany); Frankfurt Univ. (Germany). Inst. fuer Theoretische Physik

    2013-07-01

    Photons, as all electromagnetic probes, can give direct access to the hot and dense phase of a heavy-ion reaction. We show calculations of direct photon emission at SiS100- and SiS-300 energies with the UrQMD-hybrid model. UrQMD is a full microscopic+macroscopic transport/fluid-dynamics hybrid model with hadron- and string-driven equilibration phase, a full (3+1)-dimensional fluiddynamic hot and dense phase and a hadronic after-burner. Unequilibrated matter at high rapidity is preserved during the fluid phase. A strong emphasis is set on the impact of viscosity and Equation of State at zero and non-zero baryon density to the spectra and flow patterns of thermal and non-thermal photons in A+A-collisions at the colliding systems relevant for FAIR.

  6. On directed coverings

    DEFF Research Database (Denmark)

    Fajstrup, Lisbeth

    In [1], we study coverings in the setting of directed topology. Unfortunately, there is a condition missing in the definition of a directed covering. Some of the results in [1] require this extra condition and in fact it was claimed to follow from the original definition. It is the purpose...... of this note to give the right definition and point out how this affects the statements in that paper. Moreover, we give an example of a dicovering in the sense of [1], which does not satisfy the extra condition. Fortunately, with the extra condition, the subsequent results are now correct. [1] L. Fajstrup......, Dicovering spaces, Homology Homotopy Appl. 5 (2003), no. 2, 1-17....

  7. Direct Olive Oil Analysis

    OpenAIRE

    2002-01-01

    The practical impact of “direct analysis” is undeniable as it strong contributes to enhance the so-called productive analytical features such as expeditiousness, reduction of costs and minimisation of risks for the analysts and environment. The main objective is to establish a reliable bypass to the conventional preliminary operations of the analytical process. This paper offers a systematic approach in this context and emphasises the great field of action of...

  8. Site-directed mutagenesis.

    Science.gov (United States)

    Bachman, Julia

    2013-01-01

    Site-directed mutagenesis is a PCR-based method to mutate specified nucleotides of a sequence within a plasmid vector. This technique allows one to study the relative importance of a particular amino acid for protein structure and function. Typical mutations are designed to disrupt or map protein-protein interactions, mimic or block posttranslational modifications, or to silence enzymatic activity. Alternatively, noncoding changes are often used to generate rescue constructs that are resistant to knockdown via RNAi.

  9. Directional Solidification of Ledeburite

    Directory of Open Access Journals (Sweden)

    M. Trepczyńska-Łent

    2013-07-01

    Full Text Available Directional solidification of ledeburite was realised out using a Bridgman’s device. The growth rate for movement sample v=83.3 μm/s was used. In one sample the solidification front was freezing. The value of temperature gradient in liquid at the solidification front was determined. Interfacial distance λ on the samples was measured with NIS-Elements application for image analysis.

  10. Direct hydrocarbon fuel cells

    Science.gov (United States)

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  11. Future directions for QCD

    Energy Technology Data Exchange (ETDEWEB)

    Bjorken, J.D.

    1996-10-01

    New directions for exploring QCD at future high-energy colliders are sketched. These include jets within jets. BFKL dynamics, soft and hard diffraction, searches for disoriented chiral condensate, and doing a better job on minimum bias physics. The new experimental opportunities include electron-ion collisions at HERA, a new collider detector at the C0 region of the TeVatron, and the FELIX initiative at the LHC.

  12. Direct Olive Oil Analysis

    OpenAIRE

    Peña, F.; Cárdenas, S.; Gallego, M.; Valc?rcel, M.

    2002-01-01

    The practical impact of “direct analysis” is undeniable as it strong contributes to enhance the so-called productive analytical features such as expeditiousness, reduction of costs and minimisation of risks for the analysts and environment. The main objective is to establish a reliable bypass to the conventional preliminary operations of the analytical process. This paper offers a systematic approach in this context and emphasises the great field of action of...

  13. Multi Response Optimization of NOx Emission of a Stationary Diesel Engine Fuelled with Crude Rice Bran Oil Methyl Ester Optimisation à réponses multiples de l’émission de NOx d’un moteur Diesel stationnaire alimenté par de l’ester méthylique d’huile de riz brut

    Directory of Open Access Journals (Sweden)

    Saravanan S.

    2012-05-01

    Full Text Available In the present work, an attempt was made to reduce the NOx emission of crude rice bran oil methyl ester without any considerable increase in smoke density, when used as a fuel in a stationary CI engine. Three factors namely, fuel injection timing, Exhaust Gas Recirculation (EGR and fuel injection pressure were chosen and their combined effect in controlling the NOx emission of a stationary Diesel engine fuelled with crude rice bran oil methyl ester was investigated. Three levels were chosen in each factor and NOx emission, smoke density and brake thermal efficiency were taken as the response variables. Experiments were designed by employing design of experiments method and Taguchi’s L9 orthogonal array was used to conduct the engine tests with different levels of the chosen factors. Multi Response Signal-to-Noise ratio (MRSN was calculated for the response variables and the optimum combination level of factors was obtained simultaneously using Taguchi’s parametric design. Confirmation experiment was conducted for the obtained optimum combination level of factors and the results were compared with normal operating conditions and significant improvement was observed in the response variables. Dans la présente étude, il a été tenté de réduire les émissions de NOx de l'ester méthylique d'huile de riz brut sans accroissement considérable de la densité de fumée lorsqu'il est utilisé comme carburant dans un moteur stationnaire à allumage par compression. Trois facteurs, à savoir le calage d'injection de carburant, le pourcentage de recirculation des gaz d'échappement (EGR ; Exhaust Gas Recirculation et la pression d'injection de carburant ont été choisis, et leur effet combiné a été examiné en matière de maîtrise des émissions de NOx d'un moteur Diesel stationnaire alimenté avec de l'ester méthylique d'huile de riz brut. Trois niveaux ont été choisis pour chaque facteur et les émissions de NOx, la densité de fum

  14. Direct imaging of exoplanets.

    Science.gov (United States)

    Lagrange, Anne-Marie

    2014-04-28

    Most of the exoplanets known today have been discovered by indirect techniques, based on the study of the host star radial velocity or photometric temporal variations. These detections allowed the study of the planet populations in the first 5-8 AU from the central stars and have provided precious information on the way planets form and evolve at such separations. Direct imaging on 8-10 m class telescopes allows the detection of giant planets at larger separations (currently typically more than 5-10 AU) complementing the indirect techniques. So far, only a few planets have been imaged around young stars, but each of them provides an opportunity for unique dedicated studies of their orbital, physical and atmospheric properties and sometimes also on the interaction with the 'second-generation', debris discs. These few detections already challenge formation theories. In this paper, I present the results of direct imaging surveys obtained so far, and what they already tell us about giant planet (GP) formation and evolution. Individual and emblematic cases are detailed; they illustrate what future instruments will routinely deliver for a much larger number of stars. I also point out the limitations of this approach, as well as the needs for further work in terms of planet formation modelling. I finally present the progress expected in direct imaging in the near future, thanks in particular to forthcoming planet imagers on 8-10 m class telescopes.

  15. [Advance directives. Representatives' opinions].

    Science.gov (United States)

    Busquets I Font, J M; Hernando Robles, P; Font I Canals, R; Diestre Ortin, G; Quintana, S

    The use and usefulness of Advance Directives has led to a lot of controversy about their validity and effectiveness. Those areas are unexplored in our country from the perspective of representatives. To determine the opinion of the representatives appointed in a registered Statement of Advance Directives (SAD) on the use of this document. Telephone survey of representatives of 146 already dead people and who, since February 2012, had registered a SAD document. More the two-thirds (98) of respondents recalled that the SAD was consulted, with 86 (58.9%) saying that their opinion as representative was consulted, and 120 (82.1%) believe that the patient's will was respected. Of those interviewed, 102 (69.9%) believe that patients who had previously planned their care using a SAD had a good death, with 33 (22.4%) saying it could have been better, and 10 (6.9%) believe they suffered greatly. The SAD were mostly respected and consulted, and possibly this is related to the fact that most of the representatives declare that the death of those they represented was perceived as comfortable. It would be desirable to conduct further studies addressed at health personnel in order to know their perceptions regarding the use of Advance Directives in the process of dying. Copyright © 2016 SECA. Publicado por Elsevier España, S.L.U. All rights reserved.

  16. Ion-exclusion chromatography with the direct UV detection of non-absorbing inorganic cations using an anion-exchange conversion column in the iodide-form.

    Science.gov (United States)

    Mori, Masanobu; Itabashi, Hideyuki; Ikedo, Mikaru; Tanaka, Kazuhiko

    2006-08-15

    An ion-exclusion chromatographic method for the direct UV detection of non-absorbing inorganic cations such as sodium (Na(+)), ammonium (NH(4)(+)) and hydrazine (N(2)H(5)(+)) ions was developed by connecting an anion-exchange column in the I(-)-form after the separation column. For example, NH(4)(+) is converted to a UV-absorbing molecule, NH(4)I, by the anion-exchange column in the I(-)-form after the ion-exclusion separation on anion-exchange column in the OH(-)-form with water eluent. As a result, the direct UV detection of Na(+), NH(4)(+) and N(2)H(5)(+) could be successfully obtained as well as the well-resolved separation. The calibration graphs of the analyte cations detected with UV at 230nm were linear in the range of 0.001-5.0mM. The detection limits at S/N=3 of the cations were below 0.1muM. This method was applied to real water analysis, the determination of NH(4)(+) in river and rain waters, or that of N(2)H(5)(+) in boiler water, with the satisfactory results. This could be applied also to low- or non-absorbing anions such as fluoride or hydrogencarbonate ions by the combination of a weakly acidic cation-exchange resin in the H(+)-form as the separation column and the anion-exchange conversion column.

  17. Directional Antineutrino Detection

    Science.gov (United States)

    Safdi, B. R.; Suerfu, J.

    2014-12-01

    We propose the first truly directional antineutrino detector for antineutrinos near the threshold for the inverse beta decay (IBD) of hydrogen, with potential applications including the spatial mapping of geo-neutrinos, searches for stellar antineutrinos, and the monitoring of nuclear reactors. The detector consists of adjacent and separated target and neutron-capture layers. The IBD events, which result in a neutron and a positron, take place in the target layers. These layers are thin enough so that the neutrons escape without scattering elastically. The neutrons are detected in the thicker neutron-capture layers. The location of the IBD event is determined from the energy deposited by the positron as it slows in the medium and from the two gamma rays that come from the positron annihilation. Since the neutron recoils in the direction of the antineutrino's motion, a line may then be drawn between the IBD event location and the neutron-capture location to approximate the antineutrino's velocity. In some events, we may even measure the positron's velocity, which further increases our ability to reconstruct the antineutrino's direction of motion. Our method significantly improves upon previous methods by allowing the neutron to freely travel a long distance before diffusing and being captured. Moreover, our design is a straightforward modification of existing antineutrino detectors; a prototype could easily be built with existing technology. We verify our design through Monte Carlo simulations in Geant4, using commercially-available boron-loaded plastic scintillators for the target and neutron-capture layer materials. We are able to discriminate from background using multiple coincidence signatures within a short, ~microsecond time interval. We conclude that the detector could likely operate above ground with minimal shielding.

  18. Omni-directional railguns

    Energy Technology Data Exchange (ETDEWEB)

    Shahinpoor, M.

    1994-12-31

    This invention is comprised of a device for electromagetically accelerating projectiles. The invention features two parallel conducting circular plates, a plurality of electrode connections to both upper and lower plates, a support base, and a projectile magazine. A projectile is spring-loaded into a firing position concentrically located between the parallel plates. A voltage source is applied to the plates to cause current to flow in directions defined by selectable, discrete electrode connections on both upper and lower plates. Repulsive Lorentz forces are generated to eject the projectile in a 360 degree range of fire.

  19. AngularJS directives

    CERN Document Server

    Vanston, Alex

    2013-01-01

    This book uses a practical, step-by-step approach, starting with how to build directives from the ground up before moving on to creating web applications comprised of multiple modules all working together to provide the best user experience possible.This book is intended for intermediate JavaScript developers who are looking to enhance their understanding of single-page web application development with a focus on AngularJS and the JavaScript MVC frameworks.It is expected that readers will understand basic JavaScript patterns and idioms and can recognize JSON formatted data.

  20. Direct reading inductance meter

    Science.gov (United States)

    Kolby, R. B. (Inventor)

    1977-01-01

    A direct reading inductance meter comprised of a crystal oscillator and an LC tuned oscillator is presented. The oscillators function respectively to generate a reference frequency, f(r), and to generate an initial frequency, f(0), which when mixed produce a difference equal to zero. Upon connecting an inductor of small unknown value in the LC circuit to change its resonant frequency to f(x), a difference frequency (f(r)-f(x)) is produced that is very nearly a linear function of the inductance of the inductor. The difference frequency is measured and displayed on a linear scale in units of inductance.