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Sample records for frequency-domain near-infrared spectral

  1. Functional cerebral activation detected by frequency-domain near-infrared spectroscopy

    Science.gov (United States)

    Toronov, Vladislav Y.; Webb, Andrew G.; Choi, Jee H.; Wolf, Martin; Safonova, Larisa P.; Wolf, Ursula; Gratton, Enrico

    2002-07-01

    The aim of our study was to explore the possibility of detecting haemodynamic changes in the brain using frequency- domain near-IR spectroscopy by exploiting the phase of the intensity modulated optical signal. To obtain optical signals with eh highest possible signal-to-noise ratio, we performed simultaneous NIRS-fMRI measurements, with subsequent correlation of the time courses of both measurements. The cognitive paradigm used arithmetic calculations, with optical signals acquired with sensors placed on the forehead. In three subjects we demonstrated correlation between the haemodynamic signals obtained using NIRS and BOLD fMRI.

  2. Noninvasive assessment of testicular torsion in rabbits using frequency-domain near-infrared spectroscopy: prospects for pediatric urology

    Science.gov (United States)

    Hallacoglu, Bertan; Matulewicz, Richard S.; Paltiel, Harriet J.; Padua, Horacio; Gargollo, Patricio; Cannon, Glenn; Alomari, Ahmad; Sassaroli, Angelo; Fantini, Sergio

    2009-09-01

    We present a quantitative near-IR spectroscopy study of the absolute values of oxygen saturation of hemoglobin before and after surgically induced testicular torsion in adult rabbits. Unilateral testicular torsions (0, 540, or 720 deg) on experimental testes and contralateral sham surgery on control testes are performed in four adult rabbits. A specially designed optical probe for measurements at multiple source-detector distances and a commercial frequency-domain tissue spectrometer are used to measure absolute values of testicular hemoglobin saturation. Our results show: (1) a consistent baseline absolute tissue hemoglobin saturation value of 78+/-5%, (2) a comparable tissue hemoglobin saturation of 77+/-6% after sham surgery, and (3) a significantly lower tissue hemoglobin saturation of 36+/-2% after 540- and 720-deg testicular torsion surgery. Our findings demonstrate the feasibility of performing frequency-domain, multidistance near-IR spectroscopy for absolute testicular oximetry in the assessment of testicular torsion. We conclude that near-IR spectroscopy has potential to serve as a clinical diagnostic and monitoring tool for the assessment of absolute testicular hemoglobin desaturation caused by torsion, with the possibility of serving as a complement to conventional color and spectral Doppler ultrasonography.

  3. A Unified Near Infrared Spectral Classification Scheme for T Dwarfs

    CERN Document Server

    Burgasser, A J; Leggett, S K; Kirkpatrick, J D; Golimowski, D A; Burgasser, Adam J.; Golimowski, David A.

    2006-01-01

    A revised near infrared classification scheme for T dwarfs is presented, based on and superseding prior schemes developed by Burgasser et al. and Geballe et al., and defined following the precepts of the MK Process. Drawing from two large spectroscopic libraries of T dwarfs identified largely in the Sloan Digital Sky Survey and the Two Micron All Sky Survey, nine primary spectral standards and five alternate standards spanning spectral types T0 to T8 are identified that match criteria of spectral character, brightness, absence of a resolved companion and accessibility from both northern and southern hemispheres. The classification of T dwarfs is formally made by the direct comparison of near infrared spectral data of equivalent resolution to the spectra of these standards. Alternately, we have redefined five key spectral indices measuring the strengths of the major H$_2$O and CH$_4$ bands in the 1-2.5 micron region that may be used as a proxy to direct spectral comparison. Two methods of determining T spectra...

  4. Near-infrared spectral imaging Michelson interferometer for astronomical applications

    Science.gov (United States)

    Wells, C. W.; Potter, A. E.; Morgan, T. H.

    1980-01-01

    The design and operation of an imaging Michelson interferometer-spectrometer used for near-infrared (0.8 micron to 2.5 microns) spectral imaging are reported. The system employs a rapid scan interferometer modified for stable low resolution (250/cm) performance and a 42 element PbS linear detector array. A microcomputer system is described which provides data acquisition, coadding, and Fourier transformation for near real-time presentation of the spectra of all 42 scene elements. The electronic and mechanical designs are discussed and telescope performance data presented.

  5. Brain perfusion monitoring with frequency-domain and continuous-wave near-infrared spectroscopy: a cross-correlation study in newborn piglets

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, G.; Katz, A.; Alfano, R.R. [Institute for Ultrafast Spectroscopy and Lasers and New York State Center for Advanced Technology for Ultrafast Photonic Materials and Applications Department of Electrical Engineering and Physics, The City College of the City University of New York, 138th Street and Convent Avenue, New York, NY 10031 (United States); Kofinas, A.D.; Kofinas, D.A.; Beyer, D. [Departments of Obstetrics and Gynecology and Medicine, The Brooklyn Hospital Center, The Affiliate of Weill Medical College of Cornell University, 121 De Kalb Avenue, Brooklyn, NY 11201 (United States); Stubblefield, P.G. [Department of Obstetrics and Gynecology, Boston University School of Medicine, 1 Boston Medical Center Place, Boston, MA 02118 (United States); Rosenfeld, W.; Maulik, D. [Departments of Obstetrics and Gynecology and Pediatrics, Winthrop University Hospital, State University of New York at Stony Brook, 251 First Street, Mineola, New York 11501 (United States); Stankovic, M.R. [Departments of Obstetrics and Gynecology and Medicine, The Brooklyn Hospital Center, The Affiliate of Weill Medical College of Cornell University, 121 De Kalb Avenue, Brooklyn, NY 11201 (United States); Department of Obstetrics and Gynecology, Boston University School of Medicine, 1 Boston Medical Center Place, Boston, MA 02118 (United States); Departments of Obstetrics and Gynecology and Pediatrics, Winthrop University Hospital, State University of New York at Stony Brook, 251 First Street, Mineola, New York 11501 (United States)

    2000-11-01

    The newborn piglet brain model was used to correlate continuous-wave (CW) and frequency-domain (FD) near-infrared spectroscopy. Six ventilated and instrumented newborn piglets were subjected to a series of manipulations in blood oxygenation with the effects on brain perfusion known to be associated with brain hypoxia-ischaemia. An excellent agreement between the CW and FD was demonstrated. This agreement improved when the scattering properties (determined by the FD device) were employed to calculate the differential pathlength factor, an important step in CW data processing. (author)

  6. Correlation between skin, bone, and cerebrospinal fluid layer thickness and optical coefficients measured by multidistance frequency-domain near-infrared spectroscopy in term and preterm infants

    Science.gov (United States)

    Demel, Anja; Feilke, Katharina; Wolf, Martin; Poets, Christian F.; Franz, Axel R.

    2014-01-01

    Near-infrared spectroscopy (NIRS) is increasingly used in neonatal intensive care. We investigated the impact of skin, bone, and cerebrospinal fluid (CSF) layer thickness in term and preterm infants on absorption-(μa) and/or reduced scattering coefficients (μs‧) measured by multidistance frequency-domain (FD)-NIRS. Transcranial ultrasound was performed to measure the layer thicknesses. Correlations were only statistically significant for μa at 692 nm with bone thickness and μs‧ at 834 nm with skin thickness. There is no evidence that skin, bone, or CSF thickness have an important effect on μa and μs‧. Layer thicknesses of skin, bone, and CSF in the range studied do not seem to affect cerebral oxygenation measurements by multidistance FD-NIRS significantly.

  7. Classification of prefrontal activity due to mental arithmetic and music imagery using hidden Markov models and frequency domain near-infrared spectroscopy

    Science.gov (United States)

    Power, Sarah D.; Falk, Tiago H.; Chau, Tom

    2010-04-01

    Near-infrared spectroscopy (NIRS) has recently been investigated as a non-invasive brain-computer interface (BCI). In particular, previous research has shown that NIRS signals recorded from the motor cortex during left- and right-hand imagery can be distinguished, providing a basis for a two-choice NIRS-BCI. In this study, we investigated the feasibility of an alternative two-choice NIRS-BCI paradigm based on the classification of prefrontal activity due to two cognitive tasks, specifically mental arithmetic and music imagery. Deploying a dual-wavelength frequency domain near-infrared spectrometer, we interrogated nine sites around the frontopolar locations (International 10-20 System) while ten able-bodied adults performed mental arithmetic and music imagery within a synchronous shape-matching paradigm. With the 18 filtered AC signals, we created task- and subject-specific maximum likelihood classifiers using hidden Markov models. Mental arithmetic and music imagery were classified with an average accuracy of 77.2% ± 7.0 across participants, with all participants significantly exceeding chance accuracies. The results suggest the potential of a two-choice NIRS-BCI based on cognitive rather than motor tasks.

  8. Non-invasive and quantitative near-infrared haemoglobin spectrometry in the piglet brain during hypoxic stress, using a frequency-domain multidistance instrument†

    Science.gov (United States)

    Hueber, D. M.; Franceschini, M. A.; Ma, H. Y.; Zhang, Q.; Ballesteros, J. R.; Fantini, S.; Wallace, D.; Ntziachristos, V.; Chance, B.

    2001-01-01

    The frequency-domain multiple-distance (FDMD) method is capable of measuring the absolute absorption and reduced scattering coefficients of optically turbid media. Absolute measurement of absorption at two near-infrared (NIR) wavelengths makes possible the quantitation of tissue haemoglobin concentration and tissue haemoglobin oxygen-saturation (StO2). However, errors are introduced by the uncertainties of background absorption and the dissimilarities between real tissues and the simplified mathematical model on which these measurements are based. An FDMD-based tissue instrument has been used for the monitoring of tissue haemoglobin concentration and oxygenation in the brain of newborn piglets during periods of hypoxia and hyperoxia. These tissue haemoglobin saturation values were compared with arterial saturation (SaO2) and venous saturation (SvO2) measured by blood gas analyses. A linear correlation was observed between StO2 and the average of SaO2 and SvO2. However, StO2 is not equal to any fixed weighted average of SaO2 and SvO2 unless we introduce an effective background tissue absorption. The magnitude of the background absorption was about 0.08 cm-1 at 758 nm and 0.06 cm-1 at 830 nm, and it was nearly consistent between piglets. The origin of this `effective' background absorption may be real, an artefact caused by the application of a simplified model to a complex sample, or a combination of factors.

  9. Studying soil properties using visible and near infrared spectral analysis

    Science.gov (United States)

    Moretti, S.; Garfagnoli, F.; Innocenti, L.; Chiarantini, L.

    2009-04-01

    This research is carried out inside the DIGISOIL Project, whose purposes are the integration and improvement of in situ and proximal measurement technologies, for the assessment of soil properties and soil degradation indicators, going form the sensing technologies to their integration and their application in digital soil mapping. The study area is located in the Virginio river basin, about 30 km south of Firenze, in the Chianti area, where soils with agricultural suitability have a high economic value connected to the production of internationally famous wines and olive oils. The most common soil threats, such as erosion and landslide, may determine huge economic losses, which must be considered in farming management practices. This basin has a length of about 23 km for a basin area of around 60,3 Km2. Geological formations outcropping in the area are Pliocene to Pleistocene marine and lacustrine sediments in beds with almost horizontal bedding. Vineyards, olive groves and annual crops are the main types of land use. A typical Mediterranean climate prevails with a dry summer followed by intense and sometimes prolonged rainfall in autumn, decreasing in winter. In this study, three types of VNIR and SWIR techniques, operating at different scales and in different environments (laboratory spectroscopy, portable field spectroscopy) are integrated to rapidly quantify various soil characteristics, in order to acquire data for assessing the risk of occurrence for typically agricultural practice-related soil threats (swelling, compaction, erosion, landslides, organic matter decline, ect.) and to collect ground data in order to build up a spectral library to be used in image analysis from air-borne and satellite sensors. Difficulties encountered in imaging spectroscopy, such as influence of measurements conditions, atmospheric attenuation, scene dependency and sampling representation are investigated and mathematical pre-treatments, using proper algorithms, are applied and

  10. Spatially-dense, multi-spectral, frequency-domain diffuse optical tomography of breast cancer

    Science.gov (United States)

    Ban, Han Yong

    Diffuse optical tomography (DOT) employs near-infrared light to image the concentration of chromophores and cell organelles in tissue and thereby providing access to functional parameters that can differentiate cancerous from normal tissues. This thesis describes research at the bench and in the clinic that explores and identifies the potential of DOT breast cancer imaging. The bench and clinic instrumentation differ but share important features: they utilize a very large, spatially dense, set of source-detector pairs (10 7) for imaging in the parallel-plate geometry. The bench experiments explored three-dimensional (3D) image resolution and fidelity as a function of numerous parameters and also ascertained the effects of a chest wall phantom. The chest wall is always present but is typically ignored in breast DOT. My experiments clarified chest wall influences and developed schemes to mitigate these effects. Mostly, these schemes involved selective data exclusion, but their efficacy also depended on reconstruction approach. Reconstruction algorithms based on analytic (fast) Fourier inversion and linear algebraic techniques were explored. The clinical experiments centered around a DOT instrument that I designed, constructed, and have begun to test (in-vitro and in-vivo). This instrumentation offers many features new to the field. Specifically, the imager employs spatially-dense, multi-spectral, frequency-domain data; it possesses the world's largest optical source-detector density yet reported, facilitated by highly-parallel CCD-based frequency-domain imaging based on gain-modulation heterodyne detection. The instrument thus measures both phase and amplitude of the diffusive light waves. Other features include both frontal and sagittal breast imaging capabilities, ancillary cameras for measurement of breast boundary profiles, real-time data normalization, and mechanical improvements for patient comfort. The instrument design and construction is my most significant

  11. AKARI/IRC NEAR-INFRARED SPECTRAL ATLAS OF GALACTIC PLANETARY NEBULAE

    Energy Technology Data Exchange (ETDEWEB)

    Ohsawa, Ryou [Institute of Astronomy, Graduate School of Science, The University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Onaka, Takashi; Sakon, Itsuki [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Matsuura, Mikako [School of Physics and Astronomy, Cardiff University, Queen’s Buildings, 5 The Parade, Roath, Cardiff CF24 3AA (United Kingdom); Kaneda, Hidehiro, E-mail: ohsawa@ioa.s.u-tokyo.ac.jp [Division of Particle and Astrophysical Science, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8602 (Japan)

    2016-04-15

    Near-infrared (2.5–5.0 μm) low-resolution (λ/Δλ ∼ 100) spectra of 72 Galactic planetary nebulae (PNe) were obtained with the Infrared Camera (IRC) in the post-helium phase. The IRC, equipped with a 1′ × 1′ window for spectroscopy of a point source, was capable of obtaining near-infrared spectra in a slit-less mode without any flux loss due to a slit. The spectra show emission features including hydrogen recombination lines and the 3.3–3.5 μm hydrocarbon features. The intensity and equivalent width of the emission features were measured by spectral fitting. We made a catalog providing unique information on the investigation of the near-infrared emission of PNe. In this paper, details of the observations and characteristics of the catalog are described.

  12. AKARI/IRC Near-Infrared Spectral Atlas of Galactic Planetary Nebulae

    CERN Document Server

    Ohsawa, Ryou; Sakon, Itsuki; Matsuura, Mikako; Kaneda, Hidehiro

    2016-01-01

    Near-infrared (2.5-5.0$\\,\\mu$m) low-resolution ($\\lambda/\\Delta\\lambda{\\sim}100$) spectra of 72 Galactic planetary nebulae (PNe) were obtained with the Infrared Camera (IRC) in the post-helium phase. The IRC, equipped with a $1'{\\times}1'$ window for spectroscopy of a point source, was capable of obtaining near-infrared spectra in a slit-less mode without any flux loss due to a slit. The spectra show emission features including hydrogen recombination lines and the 3.3-3.5$\\,\\mu$m hydrocarbon features. The intensity and equivalent width of the emission features were measured by spectral fitting. We made a catalog providing unique information on the investigation of the near-infrared emission of PNe. In this paper, details of the observations and characteristics of the catalog are described.

  13. Composition, mineralogy, and porosity of multiple asteroid systems from visible and near-infrared spectral data

    OpenAIRE

    Lindsay, S.S.; Marchis, F.; Emery, J.P.; Enriquez Rascon, J.E.; Assafin, M.

    2015-01-01

    We provide a taxonomic and compositional characterization of Multiple Asteroid Systems (MASs) located in the main belt (MB) using visible and near-infrared (0.45-2.5 um) spectral data of 42 MB MASs. The mineralogical analysis is applied to determine meteorite analogs for the MASs, which, in turn, are applied to the MAS density measurements of Marchis et al. (2012) to estimate the system porosity. The macroporosities are used to evaluate the primary MAS formation hypotheses. The visible observ...

  14. Cerebral autoregulation in the preterm newborn using near-infrared spectroscopy: a comparison of time-domain and frequency-domain analyses

    Science.gov (United States)

    Eriksen, Vibeke R.; Hahn, Gitte H.; Greisen, Gorm

    2015-03-01

    The aim was to compare two conventional methods used to describe cerebral autoregulation (CA): frequency-domain analysis and time-domain analysis. We measured cerebral oxygenation (as a surrogate for cerebral blood flow) and mean arterial blood pressure (MAP) in 60 preterm infants. In the frequency domain, outcome variables were coherence and gain, whereas the cerebral oximetry index (COx) and the regression coefficient were the outcome variables in the time domain. Correlation between coherence and COx was poor. The disagreement between the two methods was due to the MAP and cerebral oxygenation signals being in counterphase in three cases. High gain and high coherence may arise spuriously when cerebral oxygenation decreases as MAP increases; hence, time-domain analysis appears to be a more robust-and simpler-method to describe CA.

  15. Spectral element method for elastic and acoustic waves in frequency domain

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Linlin; Zhou, Yuanguo; Wang, Jia-Min; Zhuang, Mingwei [Institute of Electromagnetics and Acoustics, and Department of Electronic Science, Xiamen, 361005 (China); Liu, Na, E-mail: liuna@xmu.edu.cn [Institute of Electromagnetics and Acoustics, and Department of Electronic Science, Xiamen, 361005 (China); Liu, Qing Huo, E-mail: qhliu@duke.edu [Department of Electrical and Computer Engineering, Duke University, Durham, NC, 27708 (United States)

    2016-12-15

    Numerical techniques in time domain are widespread in seismic and acoustic modeling. In some applications, however, frequency-domain techniques can be advantageous over the time-domain approach when narrow band results are desired, especially if multiple sources can be handled more conveniently in the frequency domain. Moreover, the medium attenuation effects can be more accurately and conveniently modeled in the frequency domain. In this paper, we present a spectral-element method (SEM) in frequency domain to simulate elastic and acoustic waves in anisotropic, heterogeneous, and lossy media. The SEM is based upon the finite-element framework and has exponential convergence because of the use of GLL basis functions. The anisotropic perfectly matched layer is employed to truncate the boundary for unbounded problems. Compared with the conventional finite-element method, the number of unknowns in the SEM is significantly reduced, and higher order accuracy is obtained due to its spectral accuracy. To account for the acoustic-solid interaction, the domain decomposition method (DDM) based upon the discontinuous Galerkin spectral-element method is proposed. Numerical experiments show the proposed method can be an efficient alternative for accurate calculation of elastic and acoustic waves in frequency domain.

  16. Spectral element method for elastic and acoustic waves in frequency domain

    Science.gov (United States)

    Shi, Linlin; Zhou, Yuanguo; Wang, Jia-Min; Zhuang, Mingwei; Liu, Na; Liu, Qing Huo

    2016-12-01

    Numerical techniques in time domain are widespread in seismic and acoustic modeling. In some applications, however, frequency-domain techniques can be advantageous over the time-domain approach when narrow band results are desired, especially if multiple sources can be handled more conveniently in the frequency domain. Moreover, the medium attenuation effects can be more accurately and conveniently modeled in the frequency domain. In this paper, we present a spectral-element method (SEM) in frequency domain to simulate elastic and acoustic waves in anisotropic, heterogeneous, and lossy media. The SEM is based upon the finite-element framework and has exponential convergence because of the use of GLL basis functions. The anisotropic perfectly matched layer is employed to truncate the boundary for unbounded problems. Compared with the conventional finite-element method, the number of unknowns in the SEM is significantly reduced, and higher order accuracy is obtained due to its spectral accuracy. To account for the acoustic-solid interaction, the domain decomposition method (DDM) based upon the discontinuous Galerkin spectral-element method is proposed. Numerical experiments show the proposed method can be an efficient alternative for accurate calculation of elastic and acoustic waves in frequency domain.

  17. Near-infrared Metallicities, Radial Velocities and Spectral Types for 447 Nearby M Dwarfs

    CERN Document Server

    Newton, Elisabeth R; Irwin, Jonathan; Berta-Thompson, Zachory K; Rojas-Ayala, Barbara; Covey, Kevin; Lloyd, James P

    2013-01-01

    We present metallicities, radial velocities and near-infrared spectral types for 447 M dwarfs determined from moderate resolution (R~2000) near-infrared (NIR) spectra obtained with IRTF/SpeX. These M dwarfs are targets of the MEarth Survey, a transiting planet survey searching for super Earths around mid-to-late M dwarfs within 33pc. We present NIR spectral types and new IRTF spectral templates in the Z, J, H and K-bands, created using M dwarfs with near-solar metallicities. We developed two spectroscopic distance calibrations that use NIR spectral type or an index based on the curvature of the K-band continuum. Our distance calibration has a scatter of 14%. We searched 27 NIR spectral lines and 10 spectral indices for metallicity sensitive features, taking into account correlated noise in our estimates of the errors on these parameters. We calibrated our relation using 36 M dwarfs in common proper pairs with an F, G or K-type star of known metallicity. We validated the physical association of these pairs usi...

  18. Near-infrared spectral reflectance of mineral mixtures - Systematic combinations of pyroxenes, olivine, and iron oxides

    Science.gov (United States)

    Singer, R. B.

    1981-01-01

    Near-infrared spectral reflectance data are presented for systematic variations in weight percent of two component mixtures of ferromagnesium and iron oxide minerals used to study the dark materials on Mars. Olivine spectral features are greatly reduced in contrast by admixture of other phases but remain distinctive even for low olivine contents. Clinopyroxene and orthopyroxene mixtures show resolved pyroxene absorptions near 2 microns. Limonite greatly modifies pyroxene and olivine reflectance, but does not fully eliminate distinctive spectral characteristics. Using only spectral data in the 1 micron region, it is difficult to differentiate orthopyroxene and limonite in a mixture. All composite mineral absorptions were either weaker than or intermediate in strength to the end-member absorptions and have bandwidths greater than or equal to those for the end members. In general, spectral properties in an intimate mixture combine in a complex, nonadditive manner, with features demonstrating a regular but usually nonlinear variation as a function of end-member phase proportions.

  19. Note: Near infrared spectral and transient measurements of PbS quantum dots luminescence

    Science.gov (United States)

    Parfenov, P. S.; Litvin, A. P.; Ushakova, E. V.; Fedorov, A. V.; Baranov, A. V.; Berwick, K.

    2013-11-01

    We describe an experimental setup for the characterization of luminescence from nanostructures. The setup is intended for steady-state and time-resolved luminescence measurements in the near-infrared region. The setup allows us to study spectral luminescence properties in the spectral range of 0.8-2.0 μm with high spectral resolution and kinetic luminescence properties between 0.8 and 1.7 μm with a time resolution of 3 ns. The capabilities of the system are illustrated by taking luminescence measurements from PbS quantum dots. We established the size dependencies of the optical properties of the PbS quantum dots over a wide spectral range. Finally, the energy transfer process was studied with a high temporal and spectral resolution.

  20. Near Infrared Spectral Linearisation in Quantifying Soluble Solids Content of Intact Carambola

    Directory of Open Access Journals (Sweden)

    Mohd Zubir MatJafri

    2013-04-01

    Full Text Available This study presents a novel application of near infrared (NIR spectral linearisation for measuring the soluble solids content (SSC of carambola fruits. NIR spectra were measured using reflectance and interactance methods. In this study, only the interactance measurement technique successfully generated a reliable measurement result with a coefficient of determination of (R2 = 0.724 and a root mean square error of prediction for (RMSEP = 0.461° Brix. The results from this technique produced a highly accurate and stable prediction model compared with multiple linear regression techniques.

  1. Revised Wavelength and Spectral Response Calibrations for AKARI Near-Infrared Grism Spectroscopy: Cryogenic Phase

    CERN Document Server

    Baba, S; Shirahata, M; Isobe, N; Usui, F; Ohyama, Y; Onaka, T; Yano, K; Kochi, C

    2016-01-01

    We perform revised spectral calibrations for the AKARI near-infrared grism to quantitatively correct for the effect of the wavelength-dependent refractive index. The near-infrared grism covering the wavelength range of 2.5--5.0 micron with a spectral resolving power of 120 at 3.6 micron, is found to be contaminated by second-order light at wavelengths longer than 4.9 micron which is especially serious for red objects. First, we present the wavelength calibration considering the refractive index of the grism as a function of the wavelength for the first time. We find that the previous solution is positively shifted by up to 0.01 micron compared with the revised wavelengths at 2.5--5.0 micron. In addition, we demonstrate that second-order contamination occurs even with a perfect order-sorting filter owing to the wavelength dependence of the refractive index. Second, the spectral responses of the system from the first- and second-order light are simultaneously obtained from two types of standard objects with dif...

  2. Near infrared spectral changes of cytochrome aa3 during potentiometric titrations.

    Science.gov (United States)

    Hendler, R W; Harmon, P A; Levin, I W

    1994-12-01

    Singular value decomposition (SVD) was used to deconvolute the spectral changes occurring in the near infrared region during potentiometric titrations of cytochrome aa3. Overall oxidized minus reduced difference spectra revealed a broad absorbance feature centered near 830 nm with an apparent Em near 250 mV. However, SVD did not isolate any spectral species with an absorbance centered near 830 nm. It was found that the spectral changes occurring in the wavelength region from 650 to 950 nm were associated mainly with cytochromes a and a3. It was concluded that the absorbance at 830 nm should not be used as an independent measure of the concentration of CuA in cytochrome aa3.

  3. Near infrared spectral imaging of explosives using a tunable laser source

    Energy Technology Data Exchange (ETDEWEB)

    Klunder, G L; Margalith, E; Nguyen, L K

    2010-03-26

    Diffuse reflectance near infrared hyperspectral imaging is an important analytical tool for a wide variety of industries, including agriculture consumer products, chemical and pharmaceutical development and production. Using this technique as a method for the standoff detection of explosive particles is presented and discussed. The detection of the particles is based on the diffuse reflectance of light from the particle in the near infrared wavelength range where CH, NH, OH vibrational overtones and combination bands are prominent. The imaging system is a NIR focal plane array camera with a tunable OPO/laser system as the illumination source. The OPO is programmed to scan over a wide spectral range in the NIR and the camera is synchronized to record the light reflected from the target for each wavelength. The spectral resolution of this system is significantly higher than that of hyperspectral systems that incorporate filters or dispersive elements. The data acquisition is very fast and the entire hyperspectral cube can be collected in seconds. A comparison of data collected with the OPO system to data obtained with a broadband light source with LCTF filters is presented.

  4. The optical properties of mouse skin in the visible and near infrared spectral regions.

    Science.gov (United States)

    Sabino, Caetano P; Deana, Alessandro M; Yoshimura, Tania M; da Silva, Daniela F T; França, Cristiane M; Hamblin, Michael R; Ribeiro, Martha S

    2016-07-01

    Visible and near-infrared radiation is now widely employed in health science and technology. Pre-clinical trials are still essential to allow appropriate translation of optical methods into clinical practice. Our results stress the importance of considering the mouse strain and gender when planning pre-clinical experiments that depend on light-skin interactions. Here, we evaluated the optical properties of depilated albino and pigmented mouse skin using reproducible methods to determine parameters that have wide applicability in biomedical optics. Light penetration depth (δ), absorption (μa), reduced scattering (μ's) and reduced attenuation (μ't) coefficients were calculated using the Kubelka-Munk model of photon transport and spectrophotometric measurements. Within a broad wavelength coverage (400-1400nm), the main optical tissue interactions of visible and near infrared radiation could be inferred. Histological analysis was performed to correlate the findings with tissue composition and structure. Disperse melanin granules present in depilated pigmented mouse skin were shown to be irrelevant for light absorption. Gender mostly affected optical properties in the visible range due to variations in blood and abundance of dense connective tissue. On the other hand, mouse strains could produce more variations in the hydration level of skin, leading to changes in absorption in the infrared spectral region. A spectral region of minimal light attenuation, commonly referred as the "optical window", was observed between 600 and 1350nm.

  5. Hyper-Spectral Imager in visible and near-infrared band for lunar compositional mapping

    Indian Academy of Sciences (India)

    A S Kiran Kumar; A Roy Chowdhury

    2005-12-01

    India ’s first lunar mission,Chandrayaan-1,will have a Hyper-Spectral Imager in the visible and near-infrared spectral bands along with other instruments.The instrument will enable mineralogical mapping of the Moon ’s crust in a large number of spectral channels.The planned Hyper-Spectral Imager will be the first instrument to map the lunar surface with the capability of resolving the spectral region,0.4 to 0.92 m in 64 continuous bands with a resolution of better than 15 nm and a spatial resolution of 80 m.Spectral separation will be done using a wedge filter and the image will be mapped onto an area detector.The detector output will be processed in the front-end processor to generate the 64-band data with 12-bit quantization.This paper gives a description of the Hyper-Spectral Imager instrument.

  6. [Local Regression Algorithm Based on Net Analyte Signal and Its Application in Near Infrared Spectral Analysis].

    Science.gov (United States)

    Zhang, Hong-guang; Lu, Jian-gang

    2016-02-01

    Abstract To overcome the problems of significant difference among samples and nonlinearity between the property and spectra of samples in spectral quantitative analysis, a local regression algorithm is proposed in this paper. In this algorithm, net signal analysis method(NAS) was firstly used to obtain the net analyte signal of the calibration samples and unknown samples, then the Euclidean distance between net analyte signal of the sample and net analyte signal of calibration samples was calculated and utilized as similarity index. According to the defined similarity index, the local calibration sets were individually selected for each unknown sample. Finally, a local PLS regression model was built on each local calibration sets for each unknown sample. The proposed method was applied to a set of near infrared spectra of meat samples. The results demonstrate that the prediction precision and model complexity of the proposed method are superior to global PLS regression method and conventional local regression algorithm based on spectral Euclidean distance.

  7. Spectral calibration for deriving surface mineralogy of Asteroid (25143) Itokawa from Hayabusa Near-Infrared Spectrometer (NIRS) Data

    CERN Document Server

    Bhatt, Megha; Corre, Lucille Le; Sanchez, Juan A; Dunn, Tasha; Izawa, Matthew R M; Li, Jian-Yang; Becker, Kris J; Weller, Lynn

    2015-01-01

    We present spectral calibration equations for determining mafic silicate composition of near-Earth asteroid (25143) Itokawa from visible/near-infrared spectra measured using the Near Infrared Spectrometer (NIRS), on board the Japanese Hayabusa spacecraft. Itokawa was the target of the Hayabusa sample return mission and has a surface composition similar to LL-type ordinary chondrites. Existing laboratory spectral calibrations use a spectral wavelength range that is wider (0.75-2.5 microns) than that of the NIRS instrument (0.85-2.1 microns) making them unfit for interpreting the Hayabusa spectral data currently archived in the Planetary Data System. We used laboratory measured near-infrared reflectance spectra of ordinary (H, L and LL) chondrites from the study of Dunn et al. (2010), which we resampled to the NIRS wavelength range. Using spectral parameters extracted from these resampled spectra we established a relationship between band parameters and their mafic silicate composition (olivine and low-Ca pyrox...

  8. Extending the Effective Ranging Depth of Spectral Domain Optical Coherence Tomography by Spatial Frequency Domain Multiplexing

    Directory of Open Access Journals (Sweden)

    Tong Wu

    2016-11-01

    Full Text Available We present a spatial frequency domain multiplexing method for extending the imaging depth range of a spectral domain optical coherence tomography (SDOCT system without any expensive device. This method uses two galvo scanners with different pivot-offset distances in two independent reference arms for spatial frequency modulation and multiplexing. The spatial frequency contents corresponding to different depth regions of the sample can be shifted to different frequency bands. The spatial frequency domain multiplexing SDOCT system provides an approximately 1.9-fold increase in the effective ranging depth compared with that of a conventional full-range SDOCT system. The reconstructed images of phantom and biological tissue demonstrate the expected increase in ranging depth. The parameters choice criterion for this method is discussed.

  9. Calibration and optimization of 3D digital breast tomosynthesis guided near infrared spectral tomography.

    Science.gov (United States)

    Michaelsen, Kelly E; Krishnaswamy, Venkataramanan; Shi, Linxi; Vedantham, Srinivasan; Poplack, Steven P; Karellas, Andrew; Pogue, Brian W; Paulsen, Keith D

    2015-12-01

    Calibration of a three-dimensional multimodal digital breast tomosynthesis (DBT) x-ray and non-fiber based near infrared spectral tomography (NIRST) system is challenging but essential for clinical studies. Phantom imaging results yielded linear contrast recovery of total hemoglobin (HbT) concentration for cylindrical inclusions of 15 mm, 10 mm and 7 mm with a 3.5% decrease in the HbT estimate for each 1 cm increase in inclusion depth. A clinical exam of a patient's breast containing both benign and malignant lesions was successfully imaged, with greater HbT was found in the malignancy relative to the benign abnormality and fibroglandular regions (11 μM vs. 9.5 μM). Tools developed improved imaging system characterization and optimization of signal quality, which will ultimately improve patient selection and subsequent clinical trial results.

  10. Chemometric analysis for near-infrared spectral detection of beef in fish meal

    Science.gov (United States)

    Yang, Chun-Chieh; Garrido-Novell, Cristóbal; Pérez-Marín, Dolores; Guerrero-Ginel, José E.; Garrido-Varo, Ana; Kim, Moon S.

    2015-05-01

    This paper reports the chemometric analysis of near-infrared spectra drawn from hyperspectral images to develop, evaluate, and compare statistical models for the detection of beef in fish meal. There were 40 pure-fish meal samples, 15 pure-beef meal samples, and 127 fish/beef mixture meal samples prepared for hyperspectral line-scan imaging by a machine vision system. Spectral data for 3600 pixels per sample, in which individual spectra was obtain, were retrieved from the region of interest (ROI) in every sample image. The spectral data spanning 969 nm to 1551 nm (across 176 spectral bands) were analyzed. Statistical models were built using the principal component analysis (PCA) and the partial least squares regression (PLSR) methods. The models were created and developed using the spectral data from the purefish meal and pure-beef meal samples, and were tested and evaluated using the data from the ROI in the mixture meal samples. The results showed that, with a ROI as large as 3600 pixels to cover sufficient area of a mixture meal sample, the success detection rate of beef in fish meal could be satisfactory 99.2% by PCA and 98.4% by PLSR.

  11. Near-infrared Spectral Detection of the Content of Soybean Fat Acids Based on Genetic Multilayer Feed forward Neural Network

    Institute of Scientific and Technical Information of China (English)

    CHAI Yu-hua; PAN Wei; NING Hai-long

    2005-01-01

    In the paper, a method of building mathematic model employing genetic multilayer feed forward neural network is presented, and the quantitative relationship of chemical measured values and near-infrared spectral data is established. In the paper, quantitative mathematic model related chemical assayed values and near-infrared spectral data is established by means of genetic multilayer feed forward neural network, acquired near-infrared spectral data are taken as input of network with the content of five kinds of fat acids tested from chemical method as output,weight values of multilayer feed forward neural network are trained by genetic algorithms and detection model of neural network of soybean is built. A kind of multilayer feed forward neural network trained by genetic algorithms is designed in the paper. Through experiments, all the related coefficients of five fat acids can approach 0.9 which satisfies the preliminary test of soybean breeding.

  12. Composition, Mineralogy, and Porosity of Multiple Asteroid Systems from Visible and Near-infrared Spectral Data

    CERN Document Server

    Lindsay, Sean S; Emery, Joshua P; Enriquez, J Emilio; Assafin, Marcelo

    2014-01-01

    We provide a taxonomic and compositional characterization of Multiple Asteroid Systems (MASs) located in the main belt (MB) using visible and near-infrared (0.45-2.5 um) spectral data of 42 MB MASs. The mineralogical analysis is applied to determine meteorite analogs for the MASs, which, in turn, are applied to the MAS density measurements of Marchis et al. (2012) to estimate the system porosity. The macroporosities are used to evaluate the primary MAS formation hypotheses. The visible observing campaign includes 25 MASs obtained using the SOAR telescope with the Goodman High Throughput Spectrometer. The infrared observing campaign includes 34 MASs obtained using the NASA IRTF with the SpeX spectragraph. The MASs are classified using the Bus-DeMeo taxonomic system. We perform a NIR spectral band parameter analysis using a new analysis routine, the Spectral Analysis Routine for Asteroids (SARA). The SARA routine determines band centers, areas, and depths by utilizing the diagnostic absorption features near 1- ...

  13. Visualization of Near-Infrared Spectral Data of Eros Using the Small Body Mapping Tool

    Science.gov (United States)

    Klima, Rachel L.; Ernst, Carolyn

    2016-10-01

    One of the primary drivers for many missions visiting asteroids is to advance our understanding of their composition beyond what can be (and is) already measured by telescopes. Without sample return or lander missions, this task relies primarily on resolved near-infrared spectroscopic measurements. Scientific analysis using spectral data collected by point spectrometers is not as straightforward as for imaging spectrometers, where the local spatial context is immediately available. In the case of Eros and other highly non-spherical bodies, this problem becomes even more severe when trying to locate spectra that cross a mapped feature that bends over an irregularly shaped surface. Thus, it is often the case that outside of the mission teams, few from the community at large delve into these data sets, as they lack the tools necessary to incorporate the spectral information into geological analyses of the asteroids. Ultimately, we seek to make such spectral datasets, which NASA has invested significant amounts of money to obtain, more widely accessible and user-friendly. The Small Bodies Mapping Tool (SBMT) is a Java-based, interactive, three-dimensional visualization tool written and developed at APL to map and analyze features on irregularly shaped solar system bodies. The SBMT can be used to locate and then "drape" spacecraft images, spectra, and laser altimetry around the shape model of such bodies. It provides a means for rapid identification of available data in a region of interest and allows features to be mapped directly onto the shape model. The program allows the free rotation of a shape model (including any overlain data) in all directions, so that the correlation and distribution of mapped features can be easily and globally observed.We will present the results of our work on the NEAR/Near-Infrared Spectrograph (NIS) data, including improvements to the calibration made by using the geometric information provided by the SBMT and improvements to the SMBT

  14. [Cotton identification and extraction using near infrared sensor and object-oriented spectral segmentation technique].

    Science.gov (United States)

    Deng, Jin-Song; Shi, Yuan-Yuan; Chen, Li-Su; Wang, Ke; Zhu, Jin-Xia

    2009-07-01

    The real-time, effective and reliable method of identifying crop is the foundation of scientific management for crop in the precision agriculture. It is also one of the key techniques for the precision agriculture. However, this expectation cannot be fulfilled by the traditional pixel-based information extraction method with respect to complicated image processing and accurate objective identification. In the present study, visible-near infrared image of cotton was acquired using high-resolution sensor. Object-oriented segmentation technique was performed on the image to produce image objects and spatial/spectral features of cotton. Afterwards, nearest neighbor classifier integrated the spectral, shape and topologic information of image objects to precisely identify cotton according to various features. Finally, 300 random samples and an error matrix were applied to undertake the accuracy assessment of identification. Although errors and confusion exist, this method shows satisfying results with an overall accuracy of 96.33% and a KAPPA coefficient of 0.926 7, which can meet the demand of automatic management and decision-making in precision agriculture.

  15. Continuous wavelet transform-based feature selection applied to near-infrared spectral diagnosis of cancer.

    Science.gov (United States)

    Chen, Hui; Lin, Zan; Mo, Lin; Wu, Hegang; Wu, Tong; Tan, Chao

    2015-01-01

    Spectrum is inherently local in nature since it can be thought of as a signal being composed of various frequency components. Wavelet transform (WT) is a powerful tool that partitions a signal into components with different frequency. The property of multi-resolution enables WT a very effective and natural tool for analyzing spectrum-like signal. In this study, a continuous wavelet transform (CWT)-based variable selection procedure was proposed to search for a set of informative wavelet coefficients for constructing a near-infrared (NIR) spectral diagnosis model of cancer. The CWT provided a fine multi-resolution feature space for selecting best predictors. A measure of discriminating power (DP) was defined to evaluate the coefficients. Partial least squares-discriminant analysis (PLS-DA) was used as the classification algorithm. A NIR spectral dataset associated to cancer diagnosis was used for experiment. The optimal results obtained correspond to the wavelet of db2. It revealed that on condition of having better performance on the training set, the optimal PLS-DA model using only 40 wavelet coefficients in 10 scales achieved the same performance as the one using all the variables in the original space on the test set: an overall accuracy of 93.8%, sensitivity of 92.5% and specificity of 96.3%. It confirms that the CWT-based feature selection coupled with PLS-DA is feasible and effective for constructing models of diagnostic cancer by NIR spectroscopy.

  16. [Optimizing spectral region in using near-infrared spectroscopy for donkey milk analysis].

    Science.gov (United States)

    Zheng, Li-Min; Zhang, Lu-Da; Guo, Hui-Yuan; Pang, Kun; Zhang, Wen-Juan; Ren, Fa-Zheng

    2007-11-01

    Donkey milk has aroused more attention in recent years since its nutrition composition shows a higher similarity to human milk than others. Due to the composition difference between cow milk and donkey milk, the present models available for cow milk analysis could not be applied to donkey milk without modifications. A rapid and reliable analysis method is required to measure the nutrition composition of donkey milk. Near infrared spectroscopy is a newly developed method in food industry, but no literature report was found regarding to its application in the analysis of donkey milk. Protein, fat, ash contents and energy value are the major nutrition factors of milk. In the present paper, these factors of donkey milk were investigated by Fourier transform near-infrared (FT-NIR) spectroscopy. The ranges of protein, fat and ash contents, and energy value in donkey milk samples were 1.15%-2.54%, 0.34%-2.67%, 0.28%-0.57% and 355.87-565.17 cal x kg(-1), respectively. The IR spectra ranged f from 3 899.6 to 12 493.4 cm(-1), with a 1 cm(-1) scanning interval. When the principal least square (PLS) regression algorithm is used for spectral regions information extraction, the additional constraint makes the principal components of matrix X to be related with the components of Y which is to be analyzed. Various spectral regions and data pretreatment methods were selected for principal least square (PLS) regression model development. A comparison of the whole and optimized spectral region NIR indicated that the models of selecting optimum spectral region were better than those of the whole spectral region. It was shown that the protein, fat and ash contents, and energy value in donkey milk obtained by chemical methods were well correlated to the respective values predicted by the NIR spectroscopy quantitative analysis model (alpha = 0.05). The RMSEP values were 0.18, 0.117, 0.040 6 and 23.5 respectively, indicating that these predicted values were reliable. These results

  17. Near-infrared metallicities, radial velocities, and spectral types for 447 nearby M dwarfs

    Energy Technology Data Exchange (ETDEWEB)

    Newton, Elisabeth R.; Charbonneau, David; Irwin, Jonathan; Berta-Thompson, Zachory K. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Rojas-Ayala, Barbara [Centro de Astrofsica, Universidade do Porto, Rua das Estrelas, 4150-762 Porto (Portugal); Covey, Kevin [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Lloyd, James P., E-mail: enewton@cfa.harvard.edu [Department of Astronomy, Cornell University, 226 Space Sciences Building, Ithaca, NY 14853 (United States)

    2014-01-01

    We present metallicities, radial velocities, and near-infrared (NIR) spectral types for 447 M dwarfs determined from moderate resolution (R ≈ 2000) NIR spectra obtained with the NASA Infrared Telescope Facility (IRTF)/SpeX. These M dwarfs are primarily targets of the MEarth Survey, a transiting planet survey searching for super Earths around mid-to-late M dwarfs within 33 pc. We present NIR spectral types for each star and new spectral templates for the IRTF in the Y, J, H, and K-bands, created using M dwarfs with near-solar metallicities. We developed two spectroscopic distance calibrations that use NIR spectral type or an index based on the curvature of the K-band continuum. Our distance calibration has a scatter of 14%. We searched 27 NIR spectral lines and 10 spectral indices for metallicity sensitive features, taking into account correlated noise in our estimates of the errors on these parameters. We calibrated our relation using 36 M dwarfs in common proper pairs with an F-, G-, or K-type star of known metallicity. We validated the physical association of these pairs using proper motions, radial velocities, and spectroscopic distance estimates. Our resulting metallicity calibration uses the sodium doublet at 2.2 μm as the sole indicator for metallicity. It has an accuracy of 0.12 dex inferred from the scatter between the metallicities of the primaries and the estimated metallicities of the secondaries. Our relation is valid for NIR spectral types from M1V to M5V and for –1.0 dex < [Fe/H] < +0.35 dex. We present a new color-color metallicity relation using J – H and J – K colors that directly relates two observables: the distance from the M dwarf main sequence and equivalent width of the sodium line at 2.2 μm. We used radial velocities of M dwarf binaries, observations at different epochs, and comparison between our measurements and precisely measured radial velocities to demonstrate a 4 km s{sup –1} accuracy.

  18. Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

    Science.gov (United States)

    Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

    2012-12-01

    The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

  19. Potential applications of near infrared auto-fluorescence spectral polarized imaging for assessment of food quality

    Science.gov (United States)

    Zhou, Kenneth J.; Chen, Jun

    2016-03-01

    The current growing of food industry for low production costs and high efficiency needs for maintenance of high-quality standards and assurance of food safety while avoiding liability issues. Quality and safety of food depend on physical (texture, color, tenderness etc.), chemical (fat content, moisture, protein content, pH, etc.), and biological (total bacterial count etc.) features. There is a need for a rapid (less than a few minutes) and accurate detection system in order to optimize quality and assure safety of food. However, the fluorescence ranges for known fluorophores are limited to ultraviolet emission bands, which are not in the tissue near infrared (NIR) "optical window". Biological tissues excited by far-red or NIR light would exhibit strong emission in spectral range of 650-1,100 nm although no characteristic peaks show the emission from which known fluorophores. The characteristics of the auto-fluorescence emission of different types of tissues were found to be different between different tissue components such as fat, high quality muscle food. In this paper, NIR auto-fluorescence emission from different types of muscle food and fat was measured. The differences of fluorescence intensities of the different types of muscle food and fat emissions were observed. These can be explained by the change of the microscopic structure of physical, chemical, and biological features in meat. The difference of emission intensities of fat and lean meat tissues was applied to monitor food quality and safety using spectral polarized imaging, which can be detect deep depth fat under the muscle food up to several centimeter.

  20. Lunar Resources Using Moderate Spectral Resolution Visible and Near-infrared Spectroscopy: Al/si and Soil Maturity

    Science.gov (United States)

    Fischer, Erich M.; Pieters, Carle M.; Head, James W.

    1992-01-01

    Modern visible and near-infrared detectors are critically important for the accurate identification and relative abundance measurement of lunar minerals; however, even a very small number of well-placed visible and near-infrared bandpass channels provide a significant amount of general information about crucial lunar resources. The Galileo Solid State Imaging system (SSI) multispectral data are an important example of this. Al/Si and soil maturity will be discussed as examples of significant general lunar resource information that can be gleaned from moderate spectral resolution visible and near-infrared data with relative ease. Because quantitative-albedo data are necessary for these kinds of analyses, data such as those obtained by Galileo SSI are critical. SSI obtained synoptic digital multispectral image data for both the nearside and farside of the Moon during the first Galileo Earth-Moon encounter in December 1990. The data consist of images through seven filters with bandpasses ranging from 0.40 microns in the ultraviolet to 0.99 microns in the near-infrared. Although these data are of moderate spectral resolution, they still provide information for the following lunar resources: (1) titanium content of mature mare soils based upon the 0.40/0.56-micron (UV/VIS) ratio; (2) mafic mineral abundance based upon the 0.76/0.99-micron ratio; and (3) the maturity or exposure age of the soils based upon the 0.56-0.76-micron continuum and the 0.76/0.99-micron ratio. Within constraints, these moderate spectral resolution visible and near-infrared reflectance data can also provide elemental information such as Al/Si for mature highland soils.

  1. Wavelength optimization using available laser diodes in spectral near-infrared optical tomography.

    Science.gov (United States)

    Chen, Liang-Yu; Pan, Min-Cheng; Yan, Chung-Chen; Pan, Min-Chun

    2016-07-20

    For employing optimized wavelengths, a near-infrared (NIR) tomographic imaging system with multiwavelengths in a continuous wave (CW) enables us to provide accurate information of chromophores. In this paper, we discuss wavelength optimization with a selection from commercial laser diodes. Through theoretical analysis, the residual norm (R) and the condition number (κ) represent the uniqueness of a matrix problem and the smooth singular-value distribution of each chromophore, respectively. The optimum wavelengths take place for large R and small κ. We considered a total of 38 wavelengths of laser diodes in the range of 633-980 nm commercially available to discover optimum sets for a broad range of chromophore combinations. In the 38 wavelengths, there exists 501,942 (C538), 2,760,681 (C638), and 12,620,256 (C738) combinations of five, six, and seven wavelength sets, respectively, for accurately estimating chromophores (HbO2, HbR, H2O, and lipids), water, lipids, and the scattering prefactor A. With the numerical calculation, the top 10 wavelength sets were selected based on the principle of large R and small κ. In the study, the chromophore concentration for young and elderly women are investigated; finally, choosing the laser diodes with a wavelength of 650, 690, 705, 730, 870/880, 915, and 937 nm is recommended either for young or elderly women to construct a spectral NIR tomographic imaging system in the CW domain. Simulated data were used to validate the claims.

  2. Visible and near-infrared spectral survey of lunar meteorites recovered by the National Institute of Polar Research

    Science.gov (United States)

    Hiroi, T.; Kaiden, H.; Yamaguchi, A.; Kojima, H.; Uemoto, K.; Ohtake, M.; Arai, T.; Sasaki, S.

    2016-12-01

    Lunar meteorite chip samples recovered by the National Institute of Polar Research (NIPR) have been studied by a UV-visible-near-infrared spectrometer, targeting small areas of about 3 × 2 mm in size. Rock types and approximate mineral compositions of studied meteorites have been identified or obtained through this spectral survey with no sample preparation required. A linear deconvolution method was used to derive end-member mineral spectra from spectra of multiple clasts whenever possible. In addition, the modified Gaussian model was used in an attempt of deriving their major pyroxene compositions. This study demonstrates that a visible-near-infrared spectrometer on a lunar rover would be useful for identifying these kinds of unaltered (non-space-weathered) lunar rocks. In order to prepare for such a future mission, further studies which utilize a smaller spot size are desired for improving the accuracy of identifying the clasts and mineral phases of the rocks.

  3. Quantification of simvastatin in mice plasma by near-infrared and chemometric analysis of spectral data.

    Science.gov (United States)

    Fahmy, Usama A

    2016-01-01

    Time and cost saving is an essential requirement in pharmacokinetics and bioequivalence studies. The aim of this study is to use a simple, fast, and nondestructive near-infrared transmission spectroscopic method to quantify simvastatin (SMV) concentrations in mice plasma and also to improve SMV bioavailability by using alpha-lipoic acid as a carrier. Calibration curve was built at a concentration range of 10-250 ng/mL, and HPLC method was considered as a reference method. A partial least squares regression analysis model was used for method development, which gave less root mean square error cross-validation. Comparison of SMV concentrations obtained from both instruments showed no statistically significant differences between all the data. Near-infrared spectroscopy was utilized as a rapid, simple accurate method to quantify drug-plasma concentrations without need for any extraction protocols, and the significant effect of alpha-lipoic acid as a novel carrier to enhance SMV bioavailability is also addressed.

  4. Detection of faint broad emission lines in type 2 AGN: I. Near infrared observations and spectral fitting

    Science.gov (United States)

    Onori, F.; La Franca, F.; Ricci, F.; Brusa, M.; Sani, E.; Maiolino, R.; Bianchi, S.; Bongiorno, A.; Fiore, F.; Marconi, A.; Vignali, C.

    2016-09-01

    We present medium resolution near infrared spectroscopic observations of 41 obscured and intermediate class AGN (type 2, 1.9 and 1.8; AGN2) with redshift z ≲0.1, selected from the Swift/BAT 70-month catalogue. The observations have been carried out in the framework of a systematic study of the AGN2 near infrared spectral properties and have been executed using ISAAC/VLT, X-shooter/VLT and LUCI/LBT, reaching an average S/N ratio of ˜30 per resolution element. For those objects observed with X-shooter we also obtained simultaneous optical and UV spectroscopy. We have identified a component from the broad line region in 13 out of 41 AGN2, with FWHM >800 km s-1. We have verified that the detection of the broad line region components does not significantly depend on selection effects due to the quality of the spectra, the X-ray or near infrared fluxes, the orientation angle of the host galaxy or the hydrogen column density measured in the X-ray band. The average broad line region components found in AGN2 has a significantly (a factor 2) smaller FWHM if compared with a control sample of type 1 AGN.

  5. Detection of faint broad emission lines in type 2 AGN - I. Near-infrared observations and spectral fitting

    Science.gov (United States)

    Onori, F.; La Franca, F.; Ricci, F.; Brusa, M.; Sani, E.; Maiolino, R.; Bianchi, S.; Bongiorno, A.; Fiore, F.; Marconi, A.; Vignali, C.

    2017-01-01

    We present medium resolution near-infrared spectroscopic observations of 41 obscured and intermediate class active galactic nuclei (AGN; type 2, 1.9 and 1.8; AGN2) with redshift z ≲ 0.1, selected from the Swift/Burst Alert Telescope 70-month catalogue. The observations have been carried out in the framework of a systematic study of the AGN2 near-infrared spectral properties and have been executed using Infrared Spectrometer And Array Camera/VLT, X-shooter/VLT and LUCI/LBT, reaching an average S/N ratio of ˜30 per resolution element. For those objects observed with X-shooter, we also obtained simultaneous optical and UV spectroscopy. We have identified a component from the broad line region in 13 out of 41 AGN2, with full width at half-maximum (FWHM) > 800 km s-1. We have verified that the detection of the broad line region components does not significantly depend on selection effects due to the quality of the spectra, the X-ray or near-infrared fluxes, the orientation angle of the host galaxy or the hydrogen column density measured in the X-ray band. The average broad line region components found in AGN2 has a significantly (a factor 2) smaller FWHM if compared with a control sample of type 1 AGN.

  6. Detection of faint broad emission lines in type 2 AGN: I. Near infrared observations and spectral fitting

    CERN Document Server

    Onori, F; Ricci, F; Brusa, M; Sani, E; Maiolino, R; Bianchi, S; Bongiorno, A; Fiore, F; Marconi, A; Vignali, C

    2016-01-01

    We present medium resolution near infrared spectroscopic observations of 41 obscured and intermediate class AGN (type 2, 1.9 and 1.8; AGN2) with redshift $z \\lesssim$0.1, selected from the Swift/BAT 70-month catalogue. The observations have been carried out in the framework of a systematic study of the AGN2 near infrared spectral properties and have been executed using ISAAC/VLT, X-shooter/VLT and LUCI/LBT, reaching an average S/N ratio of $\\sim$30 per resolution element. For those objects observed with X-shooter we also obtained simultaneous optical and UV spectroscopy. We have identified a component from the broad line region in 13 out of 41 AGN2, with FWHM ${\\rm > 800 }$ km/s. We have verified that the detection of the broad line region components does not significantly depend on selection effects due to the quality of the spectra, the X-ray or near infrared fluxes, the orientation angle of the host galaxy or the hydrogen column density measured in the X-ray band. The average broad line region components f...

  7. Quantification of simvastatin in mice plasma by near-infrared and chemometric analysis of spectral data

    Directory of Open Access Journals (Sweden)

    Fahmy UA

    2016-08-01

    Full Text Available Usama A Fahmy Department of Pharmaceutics & Industrial Pharmacy, Faculty of Pharmacy, King Abdulaziz University, Jeddah, Saudi Arabia Abstract: Time and cost saving is an essential requirement in pharmacokinetics and bioequivalence studies. The aim of this study is to use a simple, fast, and nondestructive near-infrared transmission spectroscopic method to quantify simvastatin (SMV concentrations in mice plasma and also to improve SMV bioavailability by using alpha-lipoic acid as a carrier. Calibration curve was built at a concentration range of 10–250 ng/mL, and HPLC method was considered as a reference method. A partial least squares regression analysis model was used for method development, which gave less root mean square error cross-validation. Comparison of SMV concentrations obtained from both instruments showed no statistically significant differences between all the data. Near-infrared spectroscopy was utilized as a rapid, simple accurate method to quantify drug–plasma concentrations without need for any extraction protocols, and the significant effect of alpha-lipoic acid as a novel carrier to enhance SMV bioavailability is also addressed. Keywords: alpha lipoic acid, bioavailability, non invasive, FTIR, pharmacokinetics

  8. Quantification of simvastatin in mice plasma by near-infrared and chemometric analysis of spectral data

    Science.gov (United States)

    Fahmy, Usama A

    2016-01-01

    Time and cost saving is an essential requirement in pharmacokinetics and bioequivalence studies. The aim of this study is to use a simple, fast, and nondestructive near-infrared transmission spectroscopic method to quantify simvastatin (SMV) concentrations in mice plasma and also to improve SMV bioavailability by using alpha-lipoic acid as a carrier. Calibration curve was built at a concentration range of 10–250 ng/mL, and HPLC method was considered as a reference method. A partial least squares regression analysis model was used for method development, which gave less root mean square error cross-validation. Comparison of SMV concentrations obtained from both instruments showed no statistically significant differences between all the data. Near-infrared spectroscopy was utilized as a rapid, simple accurate method to quantify drug–plasma concentrations without need for any extraction protocols, and the significant effect of alpha-lipoic acid as a novel carrier to enhance SMV bioavailability is also addressed. PMID:27540278

  9. Contrast enhancement of subcutaneous blood vessel images by means of visible and near-infrared hyper-spectral imaging

    Science.gov (United States)

    Katrašnik, Jaka; Bürmen, Miran; Pernuš, Franjo; Likar, Boštjan

    2009-02-01

    Visualization of subcutaneous veins is very difficult with the naked eye, but important for diagnosis of medical conditions and different medical procedures such as catheter insertion and blood withdrawal. Moreover, recent studies showed that the images of subcutaneous veins could be used for biometric identification. The majority of methods used for enhancing the contrast between the subcutaneous veins and surrounding tissue are based on simple imaging systems utilizing CMOS or CCD cameras with LED illumination capable of acquiring images from the near infrared spectral region, usually near 900 nm. However, such simplified imaging methods cannot exploit the full potential of the spectral information. In this paper, a new highly versatile method for enhancing the contrast of subcutaneous veins based on state-of-the-art high-resolution hyper-spectral imaging system utilizing the spectral region from 550 to 1700 nm is presented. First, a detailed analysis of the contrast between the subcutaneous veins and the surrounding tissue as a function of wavelength, for several different positions on the human arm, was performed in order to extract the spectral regions with the highest contrast. The highest contrast images were acquired at 1100 nm, however, combining the individual images from the extracted spectral regions by the proposed contrast enhancement method resulted in a single image with up to ten-fold better contrast. Therefore, the proposed method has proved to be a useful tool for visualization of subcutaneous veins.

  10. In situ sensing of subsurface contamination--part I: near-infrared spectral characterization of alkanes, aromatics, and chlorinated hydrocarbons.

    Science.gov (United States)

    Klavarioti, Maria; Kostarelos, Konstantinos; Pourjabbar, Anahita; Ghandehari, Masoud

    2014-05-01

    There is an imperative need for a chemical sensor capable of remote, in situ, long-term monitoring of chemical species at sites containing toxic chemical spills, specifically at chemical waste dumps, landfills, and locations with underground storage tanks. In the current research, a series of experiments were conducted measuring the near-infrared optical absorption of alkanes, aromatics, and chlorinated hydrocarbons. A spectral library was then developed to characterize the optical spectra of liquid hydrocarbons. Near-infrared analysis was chosen due to compatibility with optical fibers. The goal was to differentiate between classes of hydrocarbons and to also discriminate between compounds within a class of similar molecular structures. It was observed that unique absorption spectra can be obtained for each hydrocarbon, and this uniqueness can be used to discriminate between hydrocarbons from different families. Statistical analyses, namely, principal component analysis (PCA) and correlation coefficient (Spearman and Pearson methods), were attempted to match absorption spectra from an unknown hydrocarbon with the database with limited success. An algorithm was subsequently written to identify the characteristic peaks of each hydrocarbon that could be used to match data from an unknown chemical species with the database.

  11. Two-dimensional hetero-spectral mid-infrared and near-infrared correlation spectroscopy for discrimination adulterated milk.

    Science.gov (United States)

    Yang, Renjie; Liu, Rong; Dong, Guimei; Xu, Kexin; Yang, Yanrong; Zhang, Weiyu

    2016-03-15

    A new approach for discriminant analysis of adulterated milk is proposed based on two-dimensional (2D) hetero-spectral near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with level of melamine varying from 0.03 to 3 g·L(-1) were collected at room temperature. The synchronous 2D hetero-spectral IR/NIR correlation spectra of all samples were calculated to build a discriminant model to classify adulterated milk and pure milk. Also, the NPLS-DA models were built based on synchronous 2D homo-spectral NIR/NIR and IR/IR correlation spectra, respectively. Comparison results showed that the NPLS-DA model could provide better results using 2D hetero-spectral IR/NIR correlation spectra than using 2D homo-spectral NIR/NIR and 2D IR/IR correlation spectra.

  12. Two-dimensional hetero-spectral mid-infrared and near-infrared correlation spectroscopy for discrimination adulterated milk

    Science.gov (United States)

    Yang, Renjie; Liu, Rong; Dong, Guimei; Xu, Kexin; Yang, Yanrong; Zhang, Weiyu

    2016-03-01

    A new approach for discriminant analysis of adulterated milk is proposed based on two-dimensional (2D) hetero-spectral near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with level of melamine varying from 0.03 to 3 g·L- 1 were collected at room temperature. The synchronous 2D hetero-spectral IR/NIR correlation spectra of all samples were calculated to build a discriminant model to classify adulterated milk and pure milk. Also, the NPLS-DA models were built based on synchronous 2D homo-spectral NIR/NIR and IR/IR correlation spectra, respectively. Comparison results showed that the NPLS-DA model could provide better results using 2D hetero-spectral IR/NIR correlation spectra than using 2D homo-spectral NIR/NIR and 2D IR/IR correlation spectra.

  13. Near-Infrared Hyper-spectral Image Analysis of Astaxanthin Concentration in Fish Feed Coating

    DEFF Research Database (Denmark)

    Ljungqvist, Martin Georg; Ersbøll, Bjarne Kjær; Kobayashi, K.;

    2012-01-01

    The aim of this study was to investigate the possibility of predicting concentration levels of synthetic astaxanthin coating of aquaculture feed pellets by hyper-spectral image analysis in the near infra-red (NIR) range and optical filter design. The imaging devices used were a Videometer...... for prediction of the concentration level. The results show that it is possible to predict the level of synthetic astaxanthin coating using either hyper-spectral imaging or three bandpass filters (BPF)....

  14. Detection of Internal Leaf Structure Deterioration Using a New Spectral Ratio Index in the Near-Infrared Shoulder Region

    Institute of Scientific and Technical Information of China (English)

    LIU Liang-yun; HUANG Wen-jiang; PU Rui-liang; WANG Ji-hua

    2014-01-01

    Spectral relfectance in the near-infrared (NIR) shoulder (750-900 nm) region is affected by internal leaf structure, but it has rarely been investigated. In this study, a dehydration treatment and three paraquat herbicide applications were conducted to explore how spectral relfectance and shape in the NIR shoulder region responded to various stresses. A new spectral ratio index in the NIR shoulder region (NSRI), deifned by a simple ratio of relfectance at 890 nm to relfectance at 780 nm, was proposed for assessing leaf structure deterioration. Firstly, a wavelength-independent increase in spectral relfectance in the NIR shoulder region was observed from the mature leaves with slight dehydration. An increase in spectral slope in the NIR shoulder would be expected only when water stress developed sufifciently to cause severe leaf dehydration resulting in an alteration in cell structure. Secondly, the alteration of leaf cell structure caused by Paraquat herbicide applications resulted in a wavelength-dependent variation of spectral relfectance in the NIR shoulder region. The NSRI in the NIR shoulder region increased signiifcantly under an herbicide application. Although the dehydration process also occurred with the herbicide injury, NSRI is more sensitive to herbicide injury than the water-related indices (water index and normalized difference water index) and normalized difference vegetation index. Finally, the sensitivity of NSRI to stripe rust in winter wheat was examined, yielding a determination coefifcient of 0.61, which is more signiifcant than normalized difference vegetation index (NDVI), water index (WI) and normalized difference water index (NDWI), with a determination coefifcient of 0.45, 0.36 and 0.13, respectively. In this study, all experimental results demonstrated that NSRI will increase with internal leaf structure deterioration, and it is also a sensitive spectral index for herbicide injury or stripe rust in winter wheat.

  15. Visible and near-infrared spectral signatures for adulteration assessment of extra virgin olive oil

    Science.gov (United States)

    Mignani, A. G.; Ciaccheri, L.; Ottevaere, H.; Thienpont, H.; Conte, L.; Marega, M.; Cichelli, A.; Attilio, C.; Cimato, A.

    2010-04-01

    Because of its high price, the extra virgin olive oil is frequently target for adulteration with lower quality oils. This paper presents an innovative optical technique capable of quantifying the adulteration of extra virgin olive oil caused by lowergrade olive oils. It relies on spectral fingerprinting the test liquid by means of diffuse-light absorption spectroscopy carried out by optical fiber technology in the wide 400-1700 nm spectral range. Then, a smart multivariate processing of spectroscopic data is applied for immediate prediction of adulterant concentration.

  16. Single stellar populations in the near-infrared. I. Preparation of the IRTF spectral stellar library

    NARCIS (Netherlands)

    Meneses-Goytia, S.; Peletier, R. F.; Trager, S. C.; Falcón-Barroso, J.; Koleva, M.; Vazdekis, A.

    2015-01-01

    We present a detailed study of the stars of the NASA InfraRed Telescope Facility (IRTF) spectral library to understand its full extent and reliability for use with stellar population (SP) modeling. The library consist of 210 stars, with a total of 292 spectra, covering the wavelength range of 0.94 t

  17. Spectral evolution of two-dimensional kinetic plasma turbulence in the wavenumber-frequency domain

    CERN Document Server

    Comişel, H; Narita, Y; Motschmann, U

    2013-01-01

    We present a method for studying the evolution of plasma turbulence by tracking dispersion relations in the energy spectrum in the wavenumber-frequency domain. We apply hybrid plasma simulations in a simplified two-dimensional geometry to demonstrate our method and its applicability to plasma turbulence in the ion kinetic regime. We identify four dispersion relations: ion-Bernstein waves, oblique whistler waves, oblique Alfv\\'en/ion-cyclotron waves, and a zero-frequency mode. The energy partition and frequency broadening are evaluated for these modes. The method allows us to determine the evolution of decaying plasma turbulence in our restricted geometry and shows that it cascades along the dispersion relations during the early phase with an increasing broadening around the dispersion relations.

  18. Development of short-wavelength near-infrared spectral imaging for grain color classification

    Science.gov (United States)

    Archibald, Douglas D.; Thai, Chi N.; Dowell, Floyd E.

    1999-01-01

    Color class of wheat is an important attribute for the identification of cultivars and the marketing of wheat, but is not always easy to measure in the visible spectral range because of variation in vitreosity and surface structure of the kernels. This work examines whether short-wavelength near IR imaging in the range 632-1098 nm can be used to distinguish different cultivars. The spectral characteristics of six hard white winter and hard red spring wheats were first studied by bulk-sample SW-NIR reflectance spectroscopy using regression analysis to select appropriate wavelengths and sets of wavelengths. Prediction of percent red wheat was better if C-H or O-H vibrational overtones were included in the models in addition to the tail from the visible chromophore absorbance, apparently because the vibrational bands make it possible to normalize the color measurement to the dry matter content of the samples. Next, a reflectance spectral image of 640 X 480 spatial pixels and 11 wavelengths was acquired for a mixture of the two contrasting wheat samples using a CCD camera and a liquid crystal tunable filter. The cultivars were distinguished in the image of principal component (PC) score number two that was calculated from the spectral image. The discrimination is due to the tail from the absorbance band that peaks in the visible. PC images 3 and 6 seem to arise mainly from O-H and C-H bands, respectively, and it is speculated that these spectral features will be important for generating multivariate models to predict the color class of grain. It is shown that the contrast between the red-wheat, white- wheat and background can be increased by applying histogram equalization and segmentation of the kernels in the images.

  19. Toward noninvasive optical human brain mapping: improvements of the spectral, temporal, and spatial resolution of near-infrared spectroscopy

    Science.gov (United States)

    Heekeren, Hauke R.; Wenzel, Rudiger; Obrig, Hellmuth; Ruben, Jan; Ndayisaba, J.-P.; Luo, Qingming; Dale, A.; Nioka, Shoko; Kohl-Bareis, Matthias; Dirnagl, Ulrich; Villringer, Arno; Chance, Britton

    1997-08-01

    Near-infrared spectroscopy (NIRS) can detect changes in cerebral hemoglobin oxygenation in response to motor, visual or cognitive stimulation. This study explored potential improvements for functional human brain mapping with NIRS: (1) So far, only primary cortical areas, like motor cortex or primary visual areas were studied. We tested the feasibility of identifying an extrastriate visual motion area (MT) with single site NIRS. (2) The temporal resolution of commercial systems is on the order of seconds and their spectral resolution is poor. We tested the feasibility of the detection of cerebral hemoglobin oxygenation changes during visual stimulation at high temporal (100 ms) and spectral resolution (5 nm) using a whole spectrum approach (CCD-NIRS). (3) The spatial resolution of commercial systems is poor. In this study we used a 16 channel functional NIRS-imaging device to test the feasibility of mapping changes in cortical blood volume during visual stimulation (over primary and secondary areas). We show that (1) even conventional single site NIRS allows to identify secondary visual areas, (2) a CCD-NIRS system affords a high temporal (100 ms) and spectral (5 nm) resolution for the detection of changes in cerebral hemoglobin oxygenation during visual stimulation, (3) functional NIRS- imaging can localize focal blood volume changes over both primary and secondary cortical areas.

  20. [State Recognition of Solid Fermentation Process Based on Near Infrared Spectroscopy with Adaboost and Spectral Regression Discriminant Analysis].

    Science.gov (United States)

    Yu, Shuang; Liu, Guo-hai; Xia, Rong-sheng; Jiang, Hui

    2016-01-01

    In order to achieve the rapid monitoring of process state of solid state fermentation (SSF), this study attempted to qualitative identification of process state of SSF of feed protein by use of Fourier transform near infrared (FT-NIR) spectroscopy analysis technique. Even more specifically, the FT-NIR spectroscopy combined with Adaboost-SRDA-NN integrated learning algorithm as an ideal analysis tool was used to accurately and rapidly monitor chemical and physical changes in SSF of feed protein without the need for chemical analysis. Firstly, the raw spectra of all the 140 fermentation samples obtained were collected by use of Fourier transform near infrared spectrometer (Antaris II), and the raw spectra obtained were preprocessed by use of standard normal variate transformation (SNV) spectral preprocessing algorithm. Thereafter, the characteristic information of the preprocessed spectra was extracted by use of spectral regression discriminant analysis (SRDA). Finally, nearest neighbors (NN) algorithm as a basic classifier was selected and building state recognition model to identify different fermentation samples in the validation set. Experimental results showed as follows: the SRDA-NN model revealed its superior performance by compared with other two different NN models, which were developed by use of the feature information form principal component analysis (PCA) and linear discriminant analysis (LDA), and the correct recognition rate of SRDA-NN model achieved 94.28% in the validation set. In this work, in order to further improve the recognition accuracy of the final model, Adaboost-SRDA-NN ensemble learning algorithm was proposed by integrated the Adaboost and SRDA-NN methods, and the presented algorithm was used to construct the online monitoring model of process state of SSF of feed protein. Experimental results showed as follows: the prediction performance of SRDA-NN model has been further enhanced by use of Adaboost lifting algorithm, and the correct

  1. Synthesis and spectral properties of near-infrared aminophenyl-, hydroxyphenyl-, and phenyl-substituted heptamethine cyanines.

    Science.gov (United States)

    Lee, Hyeran; Mason, J Christian; Achilefu, Samuel

    2008-01-18

    Diverse meso-aminophenyl-, hydroxyphenyl-, and phenyl-substituted heptamethine cyanine dyes were prepared by a modified Suzuki--Miyaura method in good yields. In addition, direct Suzuki coupling of Vilsmeier--Haack reagent extends the procedure to the synthesis of otherwise difficult cyanine dyes containing multiple heteroatoms in the indolium ring. The new compounds possess excellent spectral properties and can be used to label bioactive molecules and nanoparticles. The one-pot synthesis procedure eliminates the cumbersome steps of protecting/deprotecting amino or hydroxy groups.

  2. Automated classification and visualization of healthy and pathological dental tissues based on near-infrared hyper-spectral imaging

    Science.gov (United States)

    Usenik, Peter; Bürmen, Miran; Vrtovec, Tomaž; Fidler, Aleš; Pernuš, Franjo; Likar, Boštjan

    2011-03-01

    Despite major improvements in dental healthcare and technology, dental caries remains one of the most prevalent chronic diseases of modern society. The initial stages of dental caries are characterized by demineralization of enamel crystals, commonly known as white spots which are difficult to diagnose. If detected early enough, such demineralization can be arrested and reversed by non-surgical means through well established dental treatments (fluoride therapy, anti-bacterial therapy, low intensity laser irradiation). Near-infrared (NIR) hyper-spectral imaging is a new promising technique for early detection of demineralization based on distinct spectral features of healthy and pathological dental tissues. In this study, we apply NIR hyper-spectral imaging to classify and visualize healthy and pathological dental tissues including enamel, dentin, calculus, dentin caries, enamel caries and demineralized areas. For this purpose, a standardized teeth database was constructed consisting of 12 extracted human teeth with different degrees of natural dental lesions imaged by NIR hyper-spectral system, X-ray and digital color camera. The color and X-ray images of teeth were presented to a clinical expert for localization and classification of the dental tissues, thereby obtaining the gold standard. Principal component analysis was used for multivariate local modeling of healthy and pathological dental tissues. Finally, the dental tissues were classified by employing multiple discriminant analysis. High agreement was observed between the resulting classification and the gold standard with the classification sensitivity and specificity exceeding 85 % and 97 %, respectively. This study demonstrates that NIR hyper-spectral imaging has considerable diagnostic potential for imaging hard dental tissues.

  3. Spectral characterization and discrimination of synthetic fibers with near-infrared hyperspectral imaging system.

    Science.gov (United States)

    Jin, Xiaoke; Memon, Hafeezullah; Tian, Wei; Yin, Qinli; Zhan, Xiaofang; Zhu, Chengyan

    2017-04-20

    Synthetic fibers account for about half of all fiber usage, with applications in every textile field. The phenomenon of fiber composition not matching the label harms consumer interests and impedes market development. Hyperspectral imaging technology as a potential technique can be utilized to discriminate mass synthetic fibers rapidly and nondestructively and achieves the functions that traditional Fourier transform infrared instruments do not have. On the basis of investigating the impact of dope-dyeing and wrapping processes on spectra, the spectral features (from 900 to 2500 nm) of six categories of synthetic fibers were extracted with a hyperspectral imaging system. A principal component analysis-linear discriminant analysis model was developed to discriminate the chemical content of fibers in different colors and structures, which showed 100% discrimination accuracy. Results demonstrated the feasibility of a hyperspectral imaging system in synthetic fiber discrimination. Therefore, this method offers a more convenient alternative for textile industry on-site discrimination.

  4. Ultraviolet to near-infrared spectral distributions of star-forming galaxies: Metallicity and age effects

    Science.gov (United States)

    Storchi-Bergmann, Thaisa; Calzetti, Daniela; Kinney, Anne L.

    1994-01-01

    Spectral distributions from the UV to the near-IR of a sample of 44 star-forming galaxies are used to calculate the metallicity (O/H), star-formation rate (SFR) and age of the starbursts. The oxygen abundance covers the range 8.3 less than O/H less than 9.4 and nitrogen (N) is found to be mostly a product of secondary nucleosynthesis for O/H greater than 8.4. Due to its secondary origin, N/O ratios up to approximately equals 4 times the solar value can be obtained for metal-rich starbursts. The SFR ranges 0.01 to 100 solar mass/year. The lower metallicity galaxies seem to be experiencing an instantaneous burst of star formation, with ages ranging from under 5 x 10(exp 6) to 10(exp 7) yr. The highest metallicity galaxies are most probably experiencing a continuous burst. Correlations between the calculated quantities and several spectral features are investigated. We found a highly significant correlation between the equivalent width W(C IV lambda 1550)-a stellar (absorption) feature- and the oxygen abundance of the emitting gas (O/H). Thus we show for the first time that the stellar metallicity is well correlated with the gas metallicity in star-bursting galaxies. The equivalent width W(Si IV lambda 1400) and the emission line ratio (N II) lambda lambda 6548.84/H(sub alpha) also correlate well with O/H, and all three features can be used as metallicity indicators for star-forming galaxies. The continuum color between lambda 1400 and lambda 3500 (C(14 - 35)) is shown to correlate with O/H, although it is better correlated with E(B - V). It was not possible to disentangle the metallicity from the reddening effect in C(14- 35). We estimate that the reddening affecting the UV continuum is about half the one derived from the Balmer decrement of the emitting gas. The SFR correlates well with the galaxy luminosity and there is no dependence of the continuum color on the SFR. The higher metallicities are only found in the more luminous galaxies, while low metallicities are

  5. Single Stellar Populations in the Near-Infrared - I. Preparation of the IRTF spectral stellar library

    CERN Document Server

    Meneses-Goytia, S; Trager, S C; Falcon-Barroso, J; Koleva, M; Vazdekis, A

    2015-01-01

    We present a detailed study of the stars of the IRTF spectral library to understand its full extent and reliability for use with Stellar Population (SP) modeling. The library consist of 210 stars, with a total of 292 spectra, covering the wavelength range of 0.94 to 2.41 micron at a resolution R = 2000. For every star we infer the effective temperature (Teff), gravity (logg) and metallicity ([Z/Zsun]) using a full-spectrum fitting approach in a section of the K band (2.19 to 2.34 micron) and temperature-NIR colour relations. We test the flux calibration of these stars by calculating their integrated colours and comparing them with the Pickles library colour-temperature relations. We also investigate the NIR colours as a function of the calculated effective temperature and compared them in colour-colour diagrams with the Pickles library. This latter test shows a good broad-band flux calibration, important for the SP models. Finally, we measure the resolution R as a function of wavelength. We find that the reso...

  6. Improving the Robustness and Stability of Partial Least Squares Regression for Near-infrared Spectral Analysis

    Institute of Scientific and Technical Information of China (English)

    SHAO, Xueguang; CHEN, Da; XU, Heng; LIU, Zhichao; CAI, Wensheng

    2009-01-01

    Partial least-squares (PLS) regression has been presented as a powerful tool for spectral quantitative measure- ment. However, the improvement of the robustness and stability of PLS models is still needed, because it is difficult to build a stable model when complex samples are analyzed or outliers are contained in the calibration data set. To achieve the purpose, a robust ensemble PLS technique based on probability resampling was proposed, which is named RE-PLS. In the proposed method, a probability is firstly obtained for each calibration sample from its resid- ual in a robust regression. Then, multiple PLS models are constructed based on probability resampling. At last, the multiple PLS models are used to predict unknown samples by taking the average of the predictions from the multi- ple models as final prediction result. To validate the effectiveness and universality of the proposed method, it was applied to two different sets of NIR spectra. The results show that RE-PLS can not only effectively avoid the inter- ference of outliers but also enhance the precision of prediction and the stability of PLS regression. Thus, it may pro- vide a useful tool for multivariate calibration with multiple outliers.

  7. Tunable MOEMS Fabry-Perot interferometer for miniaturized spectral sensing in near-infrared

    Science.gov (United States)

    Rissanen, A.; Mannila, R.; Tuohiniemi, M.; Akujärvi, A.; Antila, J.

    2014-03-01

    This paper presents a novel MOEMS Fabry-Perot interferometer (FPI) process platform for the range of 800 - 1050 nm. Simulation results including design and optimization of device properties in terms of transmission peak width, tuning range and electrical properties are discussed. Process flow for the device fabrication is presented, with overall process integration and backend dicing steps resulting in successful fabrication yield. The mirrors of the FPI consist of LPCVD (low-pressure chemical vapor) deposited polySi-SiN λ/4-thin film Bragg reflectors, with the air gap formed by sacrificial SiO2 etching in HF vapor. Silicon substrate below the optical aperture is removed by inductively coupled plasma (ICP) etching to ensure transmission in the visible - near infra-red (NIR), which is below silicon transmission range. The characterized optical properties of the chips are compared to the simulated values. Achieved optical aperture diameter size enables utilization of the chips in both imaging as well as single-point spectral sensors.

  8. A practical approach for near infrared spectral quantitative analysis of complex samples using partial least squares modeling

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The number of latent variables (LVs) or the factor number is a key parameter in PLS modeling to obtain a correct prediction. Although lots of work have been done on this issue, it is still a difficult task to determine a suitable LV number in practical uses. A method named independent factor diagnostics (IFD) is proposed for investigation of the contribution of each LV to the predicted results on the basis of discussion about the determination of LV number in PLS modeling for near infrared (NIR) spectra of complex samples. The NIR spectra of three data sets of complex samples, including a public data set and two tobacco lamina ones, are investigated. It is shown that several high order LVs constitute main contributions to the predicted results, albeit the contribution of the low order LVs should not be neglected in the PLS models. Therefore, in practical uses of PLS for analysis of complex samples, it may be better to use a slightly large LV number for NIR spectral analysis of complex samples.

  9. A practical approach for near infrared spectral quantitative analysis of complex samples using partial least squares modeling

    Institute of Scientific and Technical Information of China (English)

    LIU ZhiChao; MA Xiang; WEN YaDong; WANG Yi; CAI WenSheng; SHAO XueGuang

    2009-01-01

    The number of latent variables (LVs) or the factor number is a key parameter in PLS modeling to obtain a correct prediction.Although lots of work have been done on this issue,it is still a difficult task to determine a suitable LV number in practical uses.A method named independent factor diagnostics (IFD) is proposed for investigation of the contribution of each LV to the predicted results on the basis of discussion about the determination of LV number in PLS modeling for near infrared (NIR) spectra of complex samples.The NIR spectra of three data sets of complex samples,including a public data set and two tobacco lamina ones,are investigated.It is shown that several high order LVs constitute main contributions to the predicted results,albeit the contribution of the low order LVs should not be neglected in the PLS models.Therefore,in practical uses of PLS for analysis of complex samples,it may be better to use a slightly large LV number for NIR spectral analysis of complex samples.

  10. Eta Carinae across the 2003.5 Minimum: Analysis in the visible and near infrared spectral region

    CERN Document Server

    Nielsen, K E; Weis, K; Gull, T R; Stahl, O; Bomans, D J

    2009-01-01

    We present an analysis of the visible through near infrared spectrum of Eta Carinae and its ejecta obtained during the "Eta Carinae Campaign with the UVES at the ESO VLT". This is a part of larger effort to present a complete Eta Carinae spectrum, and extends the previously presented analyses with the HST/STIS in the UV (1240-3159 A) to 10,430 A. The spectrum in the mid and near UV is characterized by the ejecta absorption. At longer wavelengths, stellar wind features from the central source and narrow emission lines from the Weigelt condensations dominate the spectrum. However, narrow absorption lines from the circumstellar shells are present. This paper provides a description of the spectrum between 3060 and 10,430 A, including line identifications of the ejecta absorption spectrum, the emission spectrum from the Weigelt condensations and the P-Cygni stellar wind features. The high spectral resolving power of VLT/UVES enables equivalent width measurements of atomic and molecular absorption lines for element...

  11. Near-infrared spectroscopy (NIRS) and chemometric analysis of Malaysian and UK paracetamol tablets: a spectral database study.

    Science.gov (United States)

    Said, Mazlina M; Gibbons, Simon; Moffat, Anthony C; Zloh, Mire

    2011-08-30

    The influx of medicines from different sources into healthcare systems of developing countries presents a challenge to monitor their origin and quality. The absence of a repository of reference samples or spectra prevents the analysis of tablets by direct comparison. A set of paracetamol tablets purchased in Malaysian pharmacies were compared to a similar set of sample purchased in the UK using near-infrared spectroscopy (NIRS). Additional samples of products containing ibuprofen or paracetamol in combination with other actives were added to the study as negative controls. NIR spectra of the samples were acquired and compared by using multivariate modeling and classification algorithms (PCA/SIMCA) and stored in a spectral database. All analysed paracetamol samples contained the purported active ingredient with only 1 out of 20 batches excluded from the 95% confidence interval, while the negative controls were clearly classified as outliers of the set. Although the substandard products were not detected in the purchased sample set, our results indicated variability in the quality of the Malaysian tablets. A database of spectra was created and search methods were evaluated for correct identification of tablets. The approach presented here can be further developed as a method for identifying substandard pharmaceutical products. Copyright © 2011 Elsevier B.V. All rights reserved.

  12. Near-infrared spectral downshifting in Sr$_{(3−x)}$(VO$_4$)$_2$:${}_x$Nd$^{3+}$ phosphor

    Indian Academy of Sciences (India)

    N S SAWALA; K A KOPARKAR; N S BAJAJ; S K OMANWAR

    2016-12-01

    In this study, the spectral downshifting (DS) from ultraviolet (UV) light to near-infrared (NIR) radiation in Sr$_3$(VO$_4$)$_2$:Nd$^{3+}$ phosphor is reported. The prepared materials were characterized by X-ray powder diffraction(XRD) and photoluminescence (PL) properties along with steady state luminescence time decay curves were studied, which confirmed the energy transfer (ET) from VO$_4^{3−}$ ions to Nd$^{3+}$ ions. The DS phenomenon by phosphor was observed, which involved emission of NIR photons (1075 and 1064 nm) and visible photons (506 nm) from absorbed UV photons at 349 nm. The theoretical energy transfer efficiency (ETE) was calculated with the help of steady state luminescence time decay curves and the maximum ET efficiency approached up to 41.33%. The crystalline silicon (c-Si) cell has maximum efficiency in NIR region of solar spectrum due to an energy band gap of 1.12 eV.Sr$_3$(VO$_4$)$_2$:Nd$^{3+}$ can be potentially used as a NIR DC phosphor for c-Si solar cells.

  13. Robust spectral factor approximation of discrete-time frequency domain power spectras

    NARCIS (Netherlands)

    Hinnen, K.J.G.; Verhaegen, M.; Doelman, N.J.

    2005-01-01

    This paper presents a subspace-based identification algorithm for estimating the state-space quadruple [A,B,C,D] of a minimum-phase spectral factor from matrix-valued power spectrum data. For a given pair [A,C] with A stable, the minimum-phase property is guaranteed via the solution of a conic

  14. [Two-Dimensional Hetero-Spectral Near-Infrared and Mid-Infrared Correlation Spectroscopy for Discrimination Adulterated Milk].

    Science.gov (United States)

    Yu, Ge; Yang, Ren-jie; Lü, Ai-jun; Tan, En-zhong

    2015-08-01

    New approach for discriminant analysis of adulterated milk is proposed based on combining hetero-spectral two-dimensional (2D) near-infrared (NIR) and mid-infrared (IR) correlation spectroscopy along with multi-way partial least squares discriminant analysis (NPLS-DA). Firstly, 36 pure milk samples were collected and 36 adulterated milk with starch samples (0.01 to 1 g · L(-1)) were prepared by adding appropriate mass of starch into pure milk. Then, one-dimensional NIR transmittance spectra and IR attenuated total reflection spectra of pure milk and adulterated milk with starch were measured at room temperature. And the synchronous 2D NIR-IR (4200~4800 vs. 900~1700 cm(-1)) correlation spectra of all samples were calculated. Due to the trace of adulterants, the synchronous 2D IR-NIR correlation spectral differences between adulterated milk with starch and pure milk are very subtle. Consequently, it was impossible to directly distinguish whether the sample was pure milk or adulterated milk. Finally, 2D IR-NIR correlation spectra were to build a discriminant model to classify adulterated milk and pure milk. The classification accuracy rates of samples in calibration set and in prediction set were 95.8% and 100% respectively. Also, the NPLS-DA models were built based on 2D NIR and 2D IR correlation spectra, respectively. The classification accuracy rates of samples in prediction set were 95.8%. Comparison results showed that the NPLS-DA model could provide better results using 2D NIR-IR correlation spectra than using 2D NIR, and 2D IR correlation spectra. The proposed method can not only effectively extract the feature information of adulterants in milk, but also explores a new perspective method for detection of adulterated food.

  15. New Spectral Evidence of an Unaccounted Component of the Near-infrared Extragalactic Background Light from the CIBER

    Science.gov (United States)

    Matsuura, Shuji; Arai, Toshiaki; Bock, James J.; Cooray, Asantha; Korngut, Phillip M.; Kim, Min Gyu; Lee, Hyung Mok; Lee, Dae Hee; Levenson, Louis R.; Matsumoto, Toshio; Onishi, Yosuke; Shirahata, Mai; Tsumura, Kohji; Wada, Takehiko; Zemcov, Michael

    2017-04-01

    The extragalactic background light (EBL) captures the total integrated emission from stars and galaxies throughout the cosmic history. The amplitude of the near-infrared EBL from space absolute photometry observations has been controversial and depends strongly on the modeling and subtraction of the zodiacal light (ZL) foreground. We report the first measurement of the diffuse background spectrum at 0.8-1.7 μm from the CIBER experiment. The observations were obtained with an absolute spectrometer over two flights in multiple sky fields to enable the subtraction of ZL, stars, terrestrial emission, and diffuse Galactic light. After subtracting foregrounds and accounting for systematic errors, we find the nominal EBL brightness, assuming the Kelsall ZL model, is {42.7}-10.6+11.9 nW m-2 sr-1 at 1.4 μm. We also analyzed the data using the Wright ZL model, which results in a worse statistical fit to the data and an unphysical EBL, falling below the known background light from galaxies at λ EBL brightness, we find an EBL brightness of {28.7}-3.3+5.1 nWm-2 sr-1 at 1.4 μm. While the derived EBL amplitude strongly depends on the ZL model, we find that we cannot fit the spectral data to ZL, Galactic emission, and EBL from solely integrated galactic light from galaxy counts. The results require a new diffuse component, such as an additional foreground or an excess EBL with a redder spectrum than that of ZL.

  16. Compensation of spectral artifacts in dual-modality intravascular optical coherence tomography and near-infrared spectroscopy (Conference Presentation)

    Science.gov (United States)

    Fard, Ali M.; Gardecki, Joseph A.; Ughi, Giovanni J.; Hyun, Chulho; Tearney, Guillermo J.

    2016-02-01

    Intravascular optical coherence tomography (OCT) is a high-resolution catheter-based imaging method that provides three-dimensional microscopic images of coronary artery in vivo, facilitating coronary artery disease treatment decisions based on detailed morphology. Near-infrared spectroscopy (NIRS) has proven to be a powerful tool for identification of lipid-rich plaques inside the coronary walls. We have recently demonstrated a dual-modality intravascular imaging technology that integrates OCT and NIRS into one imaging catheter using a two-fiber arrangement and a custom-made dual-channel fiber rotary junction. It therefore enables simultaneous acquisition of microstructural and composition information at 100 frames/second for improved diagnosis of coronary lesions. The dual-modality OCT-NIRS system employs a single wavelength-swept light source for both OCT and NIRS modalities. It subsequently uses a high-speed photoreceiver to detect the NIRS spectrum in the time domain. Although use of one light source greatly simplifies the system configuration, such light source exhibits pulse-to-pulse wavelength and intensity variation due to mechanical scanning of the wavelength. This can be in particular problematic for NIRS modality and sacrifices the reliability of the acquired spectra. In order to address this challenge, here we developed a robust data acquisition and processing method that compensates for the spectral variations of the wavelength-swept light source. The proposed method extracts the properties of the light source, i.e., variation period and amplitude from a reference spectrum and subsequently calibrates the NIRS datasets. We have applied this method on datasets obtained from cadaver human coronary arteries using a polygon-scanning (1230-1350nm) OCT system, operating at 100,000 sweeps per second. The results suggest that our algorithm accurately and robustly compensates the spectral variations and visualizes the dual-modality OCT-NIRS images. These

  17. Model Research of Electric Coal Calorific Value Based on Near Infrared Frequency Domain Self-Adaption Analysis Method%基于近红外频域自适应分析法的电煤发热量模型研究

    Institute of Scientific and Technical Information of China (English)

    李智; 王圣毫; 赵勇; 王祥凤; 李耀铮

    2014-01-01

    At present ,because the blending coal was taken in some power stations as the major fuel which has too complex physical and chemical characters to build accurate normal near infrared quantitative models in some cases ,which brought difficulties for on-line electric coal calorific value detection .For this reason ,it was care-fully studied that the time domain and frequency domain properties of the power generation coal near infrared spectra ,and was proposed that a new quantitative near infrared method named frequency domain self-adaption analysis .The first step ,time domain near infrared spectra are converted into frequency domain near infrared signal by Fast Fourier Transform ;The second step ,the suitable frequency information range by means of valid spectra energy parameter ηE was obtained by this method ;The third step ,it was constructed that an informa-tion volume parameter which is formed by correlation coefficient ,standard deviation spectra and coordinate of harmonic in frequency domain to initialize the regression model input parameters ’ position;Finally ,the opti-mal model is established by way of discrete frequency domain scooping and synthesized performance function . At the same time ,compared with the principle component regression ,partial least squares regression ,back propagation artificial network ,support vector regression and partial least squares regression optimized by ge-netic algorithm models ,it is acquired that a more accurate method which can effectively avoid over fitting and virtual effective models and has a very useful application prospect by verifying the electric coal calorific value . Additionally ,this method can be used in other quantitative spectra analysis .%目前由于部分电站锅炉所用到的燃煤大多为配煤,在有些情况下,其复杂的物理化学特性导致难以获得高精确度的常规近红外定量分析模型,这给电煤发热量的在线检测带来了一定困难。针对该问题,

  18. SPECTRAL TYPING OF LATE-TYPE STELLAR COMPANIONS TO YOUNG STARS FROM LOW-DISPERSION NEAR-INFRARED INTEGRAL FIELD UNIT DATA

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, Lewis C.; Beichman, Charles A.; Burruss, Rick; Ligon, E. Robert; Lockhart, Thomas G.; Roberts, Jennifer E.; Shao, Michael [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Rice, Emily L.; Brenner, Douglas; Oppenheimer, Ben R. [American Museum of Natural History, Central Park West at 79th Street, New York, NY 10024 (United States); Crepp, Justin R.; Dekany, Richard G.; Hillenbrand, Lynne A.; Hinkley, Sasha [California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); King, David; Parry, Ian R. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 OHA (United Kingdom); Metchev, Stanimir [Department of Physics and Astronomy, State University of New York, Stony Brook, NY 11794-3800 (United States); Pueyo, Laurent; Sivaramakrishnan, Anand; Soummer, Remi, E-mail: lewis.c.roberts@jpl.nasa.gov [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); and others

    2012-07-15

    We used the Project 1640 near-infrared coronagraph and integral field spectrograph to observe 19 young solar-type stars. Five of these stars are known binary stars and we detected the late-type secondaries and were able to measure their JH spectra with a resolution of R {approx} 30. The reduced, extracted, and calibrated spectra were compared to template spectra from the IRTF spectral library. With this comparison, we test the accuracy and consistency of spectral-type determination with the low-resolution near-infrared spectra from P1640. Additionally, we determine effective temperature and surface gravity of the companions by fitting synthetic spectra calculated with the PHOENIX model atmosphere code. We also present several new epochs of astrometry of each of the systems. Together, these data increase our knowledge and understanding of the stellar make up of these systems. In addition to the astronomical results, the analysis presented helps validate the Project 1640 data reduction and spectral extraction processes and the utility of low-resolution, near-infrared spectra for characterizing late-type companions in multiple systems.

  19. The stellar spectral features of nearby galaxies in the near infrared: tracers of thermally pulsing asymptotic giant branch stars?

    Science.gov (United States)

    Riffel, Rogério; Mason, Rachel E.; Martins, Lucimara P.; Rodríguez-Ardila, Alberto; Ho, Luis C.; Riffel, Rogemar A.; Lira, Paulina; Gonzalez Martin, Omaira; Ruschel-Dutra, Daniel; Alonso-Herrero, Almudena; Flohic, Helene; McDermid, Richard M.; Ramos Almeida, Cristina; Thanjavur, Karun; Winge, Claudia

    2015-07-01

    We analyse the stellar absorption features in high signal-to-noise ratio (S/N) near-infrared (NIR) spectra of the nuclear region of 12 nearby galaxies, mostly spirals. The features detected in some or all of the galaxies in this sample are the TiO (0.843 and 0.886 μm), VO (1.048 μm), CN (1.1 and 1.4 μm), H2O (1.4 and 1.9 μm) and CO (1.6 and 2.3 μm) bands. The C2 (1.17 and 1.76 μm) bands are generally weak or absent, although C2 (1.76 μm) may be weakly present in the mean galaxy spectrum. A deep feature near 0.93 μm, likely caused by CN, TiO and/or ZrO, is also detected in all objects. Fitting a combination of stellar spectra to the mean spectrum shows that the absorption features are produced by evolved stars: cool giants and supergiant stars in the early- or thermally pulsing asymptotic giant branch (E-AGB or TP-AGB) phases. The high luminosity of TP-AGB stars, and the appearance of VO and ZrO features in the data, suggest that TP-AGB stars dominate these spectral features. However, a contribution from other evolved stars is also likely. Comparison with evolutionary population synthesis models shows that models based on empirical libraries that predict relatively strong NIR features provide a more accurate description of the data. However, none of the models tested accurately reproduces all of the features observed in the spectra. To do so, the models will need to not only improve the treatment of TP-AGB stars, but also include good quality spectra of red giant and E-AGB stars. The uninterrupted wavelength coverage, high S/N and quantity of features we present here will provide a benchmark for the next generation of models aiming to explain and predict the NIR properties of galaxies.

  20. High-Speed Scanning for the Quantitative Evaluation of Glycogen Concentration in Bioethanol Feedstock Synechocystis sp. PCC6803 Using a Near-Infrared Hyperspectral Imaging System with a New Near-Infrared Spectral Camera.

    Science.gov (United States)

    Ishigaki, Mika; Nakanishi, Akihito; Hasunuma, Tomohisa; Kondo, Akihiko; Morishima, Tetsu; Okuno, Toshiaki; Ozaki, Yukihiro

    2017-03-01

    In the present study, the high-speed quantitative evaluation of glycogen concentration accumulated in bioethanol feedstock Synechocystis sp. PCC6803 was performed using a near-infrared (NIR) imaging system with a hyperspectral NIR spectral camera named Compovision. The NIR imaging system has a feature for high-speed and wide area monitoring and the two-dimensional scanning speed is almost 100 times faster than the general NIR imaging systems for the same pixel size. For the quantitative analysis of glycogen concentration, partial least squares regression (PLSR) and moving window PLSR (MWPLSR) were performed with the information of glycogen concentration measured by high performance liquid chromatography (HPLC) and the calibration curves for the concentration within the Synechocystis sp. PCC6803 cell were constructed. The results had high accuracy for the quantitative estimation of glycogen concentration as the best squared correlation coefficient R(2) was bigger than 0.99 and a root mean square error (RMSE) was less than 2.9%. The present results proved not only the potential for the applicability of NIR spectroscopy to the high-speed quantitative evaluation of glycogen concentration in the bioethanol feedstock but also the expansivity of the NIR imaging instrument to in-line or on-line product evaluation on a factory production line of bioethanol in the future.

  1. An Approach for Identifying of Fusarium Infected Maize Grains by Spectral Analysis in the Visible and Near Infrared Region, SIMCA Models, Parametric and Neural Classifiers

    Directory of Open Access Journals (Sweden)

    Tsvetelina Draganova

    2010-08-01

    Full Text Available An approach for identifying of Fusarium infected single maize grains based on diffuse reflectance in visible and near infrared region is proposed in the paper. Spectral characteristics were collected in the range 400-2500 nm in steps of 2 nm. Soft independent modeling of class analogy (SIMCA is used for data processing. Maize grains classification is based on SIMCA classifier and Probabilistic neural network (PNN. Recognition accuracy which is achieved for both classes of grains is respectively 99.89% for healthy, and 93.7% for infected.

  2. Comparison of Bioradiolocation and Respiratory Plethysmography Signals in Time and Frequency Domains on the Base of Cross-Correlation and Spectral Analysis

    Directory of Open Access Journals (Sweden)

    Maksim Alekhin

    2013-01-01

    Full Text Available Comparison of bioradiolocation and standard respiratory plethysmography signals during simultaneous registration of different types of the human breathing movements is performed in both time and frequency domains. For all couples of synchronized signals corresponding to bioradiolocation and respiratory plethysmography methods, the cross-correlation and spectral functions are calculated, and estimates of their generalized characteristics are defined. The obtained results consider bioradiolocation to be a reliable remote sensing technique for noncontact monitoring of breathing pattern in medical applications.

  3. Evaluation of water-use efficiency in foxtail millet (Setaria italica) using visible-near infrared and thermal spectral sensing techniques.

    Science.gov (United States)

    Wang, Meng; Ellsworth, Patrick Z; Zhou, Jianfeng; Cousins, Asaph B; Sankaran, Sindhuja

    2016-05-15

    Water limitations decrease stomatal conductance (g(s)) and, in turn, photosynthetic rate (A(net)), resulting in decreased crop productivity. The current techniques for evaluating these physiological responses are limited to leaf-level measures acquired by measuring leaf-level gas exchange. In this regard, proximal sensing techniques can be a useful tool in studying plant biology as they can be used to acquire plant-level measures in a high-throughput manner. However, to confidently utilize the proximal sensing technique for high-throughput physiological monitoring, it is important to assess the relationship between plant physiological parameters and the sensor data. Therefore, in this study, the application of rapid sensing techniques based on thermal imaging and visual-near infrared spectroscopy for assessing water-use efficiency (WUE) in foxtail millet (Setaria italica (L.) P. Beauv) was evaluated. The visible-near infrared spectral reflectance (350-2500 nm) and thermal (7.5-14 µm) data were collected at regular intervals from well-watered and drought-stressed plants in combination with other leaf physiological parameters (transpiration rate-E, A(net), g(s), leaf carbon isotopic signature-δ(13)C(leaf), WUE). Partial least squares regression (PLSR) analysis was used to predict leaf physiological measures based on the spectral data. The PLSR modeling on the hyperspectral data yielded accurate and precise estimates of leaf E, gs, δ(13)C(leaf), and WUE with coefficient of determination in a range of 0.85-0.91. Additionally, significant differences in average leaf temperatures (~1°C) measured with a thermal camera were observed between well-watered plants and drought-stressed plants. In summary, the visible-near infrared reflectance data, and thermal images can be used as a potential rapid technique for evaluating plant physiological responses such as WUE.

  4. Near infrared spectral and polarization imaging observation of coronal emission lines during the 2008 total solar eclipse

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    During the 2008 total solar eclipse, the coronal emission lines were observed by using optical fibre spectrometric and polarization imaging system in near infrared waveband. The profiles of the coronal emission lines including Fe XIII 10747 , 10798  and He I 10830  were obtained with dispersion of 0.5 /pix. The intensity of Fe XIII 10747  remained unchanged in the two different coronal regions while the intensity of He I 10830  varied considerably in the two coronal locations no matter whether the prominence appeared or not. The coronal polarization images were observed at Fe XI 7892  with a bandpass of 30  in a series of exposure times.

  5. Near infrared spectral and polarization imaging observation of coronal emission lines during the 2008 total solar eclipse

    Institute of Scientific and Technical Information of China (English)

    BAO XingMing; WANG XiaoFan; ZHANG ZhiYong; DENG Jian; HU KeLiang; XUAN WeiJia; LIU YangBing; ZHANG HongQi; DENG YuanYong; WANG DongGuang

    2009-01-01

    During the 2008 total solar eclipse, the coronal emission lines were observed by using optical fibre spectrometric and polarization imaging system in near infrared waveband. The profiles of the coronal emission lines Including Fe ⅩⅢ 10747 A, 10798 A and He 1 10830 A were obtained with dispersion of 0.5 A/pix. The intensity of Fe ⅩⅢ 10747 A remained unchanged In the two different coronal regions while the intensity of He I 10830 A varied considerably in the two coronal locations no matter whether the prominence appeared or not. The coronal polarization images were observed at Fe XI 7892 A with a bandpass of 30 A in a series of exposure times.

  6. Improving the discriminatory power of a near-infrared microscopy spectral library with a support vector machine classifier.

    Science.gov (United States)

    Fernández-Ibáñez, V; Fearn, T; Montañés, E; Quevedo, J R; Soldado, A; de la Roza-Delgado, B

    2010-01-01

    A multi-group classifier based on the support vector machine (SVM) has been developed for use with a library of 48,456 spectra measured by near-infrared reflection microscopy (NIRM) on 227 samples representing 26 animal feed ingredients and 4 possible contaminants of animal origin. The performance of the classifier was assessed by a five-fold cross-validation, dividing at the sample level. Although the overall proportion of misclassifications was 27%, almost all of these involved the confusion of pairs of similar ingredients of vegetable origin. Such confusions are unimportant in the context of the intended use of the library, which is the detection of banned ingredients in animal feed. The error rate in discrimination between permitted and banned ingredients was just 0.17%. The performance of the SVM classifier was substantially better than that of the K-nearest-neighbors method employed in previous work with the same library, for which the comparable error rates are 36% overall and 0.39% for permitted versus banned ingredients.

  7. Analysis of the Intrinsic Mid-Infrared L-band to Visible--Near-Infrared Flux Ratios in Spectral Synthesis Models of Composite Stellar Populations

    CERN Document Server

    Kim, Duho; Windhorst, Rogier A

    2016-01-01

    We analyze the intrinsic flux ratios of various visible--near-infrared filters with respect to 3.5micron for simple and composite stellar populations, and their dependence on age, metallicity and star formation history. UV/optical light from stars is reddened and attenuated by dust, where different sightlines across a galaxy suffer varying amounts of extinction. Tamura et al. (2009) developed an approximate method to correct for dust extinction on a pixel-by-pixel basis, dubbed the "beta_V" method, by comparing the observed flux ratio to an empirical estimate of the intrinsic ratio of visible and ~3.5micron data. Through extensive modeling, we aim to validate the "beta_V" method for various filters spanning the visible through near-infrared wavelength range, for a wide variety of simple and composite stellar populations. Combining Starburst99 and BC03 models, we built spectral energy distributions (SEDs) of simple (SSP) and composite (CSP) stellar populations for various realistic star formation histories (SF...

  8. Near-Infrared high resolution spectral survey of comets with GIANO/TNG: The CN red-system at 1.1 μm

    Science.gov (United States)

    Faggi, Sara; Villanueva, Geronimo Luis; Mumma, Michael J.; Tozzi, Gian-Paolo; Brucato, John Robert

    2016-10-01

    High-resolution spectroscopy in the near-infrared spectral range is a powerful tool to investigate chemical composition and isotopic fractionation.Comets are the best preserved relic of the enfant stages of the solar system. By targeting biologically relevant species in cometary comae and retrieving isotopic (e.g. D/H) and spin isomeric (e.g., ortho- and para- water) ratios, we can study the formation and evolution of solar system matter, address the origin of Earth's oceans and characterize the delivery of organic matter that was essential for the appearance of life on early Earth. We initiated the first high resolution spectral survey of comets ever conducted in the 0.9-2.5 μm range, targeting C/2014 Q2 (Lovejoy), C/2013 US10 (Catalina) and C/2013 X1 (Panstarrs) with GIANO - the near-IR high resolution spectrograph on Telescopio Nazionale Galileo (TNG). In comet Lovejoy, we detected eight ro-vibrational bands of H2O (Faggi et al., 2016, ApJ in press), emission from the red-system of CN, and many other emission lines whose precursors are now being identified. In this talk we will present a new quantum mechanical solar fluorescence model for the CN red system and the retrievals obtained with it from our cometary spectra. These observations open new pathways for cometary science in the near-infrared spectral range (0.9-2.5 μm) and establish the feasibility of astrobiology-related scientific investigations with future high resolution IR spectrographs on 30-m class telescopes, e.g., the HIRES spectrograph on the E-ELT telescope. This work is part of Sara Faggi's Ph.D. thesis project. NASA's Planetary Astronomy Program supported GLV and MJM through funding awarded under proposal 11-PAST11-0045 (M. J. Mumma, PI ).

  9. Development of on-line sorting system for detection of infected seed potatoes using visible near-infrared transmittance spectral technique

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dae Yong; Cho, Byoung Kwan [Dept. of Biosystems Engineering, Chungnam National University, Daejeon (Korea, Republic of); Mo, Chang Yeun [Rural Development Administration, National Institute of Agricultural Engineering, Jeonju (Korea, Republic of); Kang, Jun Soon [Dept. of Horticultural Bioscience, Pusan National University, Pusan (Korea, Republic of)

    2015-02-15

    In this study, an online seed potato sorting system using a visible and near infrared (40 1100 nm) transmittance spectral technique and statistical model was evaluated for the nondestructive determination of infected and sound seed potatoes. Seed potatoes that had been artificially infected with Pectobacterium atrosepticum, which is known to cause a soil borne disease infection, were prepared for the experiments. After acquiring transmittance spectra from sound and infected seed potatoes, a determination algorithm for detecting infected seed potatoes was developed using the partial least square discriminant analysis method. The coefficient of determination(R{sup 2}{sub p}) of the prediction model was 0.943, and the classification accuracy was above 99% (n = 80) for discriminating diseased seed potatoes from sound ones. This online sorting system has good potential for developing a technique to detect agricultural products that are infected and contaminated by pathogens.

  10. Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies

    Science.gov (United States)

    Tromberg, Bruce J.; Berger, Andrew J.; Cerussi, Albert E.; Bevilacqua, Frederic; Jakubowski, Dorota

    2008-09-23

    A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

  11. Detection of wine grape nutrient levels using visible and near infrared 1nm spectral resolution remote sensing

    Science.gov (United States)

    Anderson, Grant; van Aardt, Jan; Bajorski, Peter; Vanden Heuvel, Justine

    2016-05-01

    The grape industry relies on regular crop assessment to aid in the day-to-day and seasonal management of their crop. More specifically, there are six key nutrients of interest to viticulturists in the growing of wine grapes, namely nitrogen, potassium, phosphorous, magnesium, zinc and boron. Traditional methods of determining the levels of these nutrients are through collection and chemical analysis of petiole samples from the grape vines themselves. We collected ground-level observations of the spectra of the grape vines, using a hyperspectral spectrometer (0.4-2.5um), at the same time that petioles samples were harvested. We then interpolated the data into a consistent 1 nm spectral resolution before comparing it to the nutrient data collected. This nutrient data came from both the industry standard petiole analysis, as well as an additional leaf-level analysis. The data were collected for two different grape cultivars, both during bloom and veraison periods to provide variability, while also considering the impact of temporal/seasonal change. A narrow-band NDI (Normalized Difference Index) approach, as well as a simple ratio index, was used to determine the correlation of the reflectance data to the nutrient data. This analysis was limited to the silicon photodiode range to increase the utility of our approach for wavelength-specific cameras (via spectral filters) in a low cost drone platform. The NDI generated correlation coefficients were as high as 0.80 and 0.88 for bloom and veraison, respectively. The ratio index produced correlation coefficient results that are the same at two decimal places with 0.80 and 0.88. These results bode well for eventual non-destructive, accurate and precise assessment of vineyard nutrient status.

  12. Near-Infrared Spectral Monitoring of Triton with IRTF/SpeX II: Spatial Distribution and Evolution of Ices

    CERN Document Server

    Grundy, W M; Stansberry, J A; Buie, M W; Olkin, C B; Young, E F

    2009-01-01

    This report arises from an ongoing program to monitor Neptune's largest moon Triton spectroscopically in the 0.8 to 2.4 micron range using IRTF/SpeX. Our objective is to search for changes on Triton's surface as witnessed by changes in the infrared absorption bands of its surface ices N2, CH4, H2O, CO, and CO2. We have recorded infrared spectra of Triton on 53 nights over the ten apparitions from 2000 through 2009. The data generally confirm our previously reported diurnal spectral variations of the ice absorption bands (Grundy & Young 2004). Nitrogen ice shows a large amplitude variation, with much stronger absorption on Triton's Neptune-facing hemisphere. We present evidence for seasonal evolution of Triton's N2 ice: the 2.15 micron absorption band appears to be diminishing, especially on the Neptune-facing hemisphere. Although it is mostly dissolved in N2 ice, Triton's CH4 ice shows a very different longitudinal variation from the N2 ice, challenging assumptions of how the two ices behave. Unlike Trito...

  13. A Quasar-Galaxy Mixing Diagram: Quasar Spectral Energy Distribution Shapes in the Optical to Near-Infrared

    CERN Document Server

    Hao, Heng; Kelly, Brandon C; Civano, Francesca; Bongiorno, Angela; Zamorani, Gianni; Celotti, Annalisa; Ho, Luis C; Merloni, Andrea; Jahnke, Knud; Comastri, Andrea; Trump, Jonathan R; Mainieri, Vincenzo; Salvato, Mara; Brusa, Marcella; Impey, Chris D; Koekemoer, Anton M; Lanzuisi, Giorgio; Vignali, Cristian; Silverman, John D; Urry, C Megan; Schawinski, Kevin

    2012-01-01

    We define the quasar-galaxy mixing diagram by the slopes of the spectral energy distribution (SED) of quasars from $1\\mu m$ to 3000 \\AA\\ and from $1\\mu m$ to 3 $\\mu m$ in the rest frame. The mixing diagram can easily distinguish among quasar-dominated, galaxy-dominated and reddening-dominated SED shapes. By studying the position of the 413 XMM selected Type 1 AGN in the wide-field "Cosmic Evolution Survey" (COSMOS) in the mixing diagram, we find that a combination of the Elvis et al. (1994, hereafter E94) quasar SED with various contributions from galaxy emission and some dust reddening is remarkably effective in describing the SED shape near $1\\mu m$ for large ranges of redshift, luminosity, black hole mass and Eddington ratio of type 1 AGN. In particular, the location in the mixing diagram of the highest luminosity AGN is very close (within 1$\\sigma$) to that expected on the basis of the E94 SED. The mixing diagram can also be used to estimate the host galaxy fraction and reddening in the SED. We also show ...

  14. Determining the von Mises stress power spectral density for frequency domain fatigue analysis including out-of-phase stress components

    NARCIS (Netherlands)

    Bonte, M.H.A.; Boer, de A.; Liebregts, R.

    2007-01-01

    This paper provides a new formula to take into account phase differences in the determination of an equivalent von Mises stress power spectral density (PSD) from multiple random inputs. The obtained von Mises PSD can subsequently be used for fatigue analysis. The formula was derived for use in the c

  15. Effect of simulated precompression, compression pressure and tableting speed on an offline diffuse transmittance and reflectance near-infrared spectral information of model intact caffeine tablets.

    Science.gov (United States)

    Vranic, Branko Z; Vandamme, Thierry F

    2015-01-01

    Near-infrared spectroscopy (NIRS) is used in the pharmaceutical industry for monitoring drug content during the tablet manufacturing process. It is of critical importance to understand the effect of process factors on NIRS performance. Design of Experiments (DoE) methodology was applied in this work for the systematic study of the effects of compression pressure, precompression pressure and tableting speed on an average Euclidean distance (AED), which reflects spectral features of the tablets, and root mean-squared error of prediction (RMSEP) as key performance indicator of NIRS calibration models. Caffeine tablets were manufactured in 17 experimental runs in accordance with D-optimal design. Developed diffuse transmittance (DT) and diffuse reflectance (DR) calibration models were tested on five independent test sets to confirm the conclusions of the DoE. Compression pressure and tableting speed have shown significant effect on the studied responses in DT mode, whereas all three studied factors have shown a significant effect in DR mode. Significant factors were considered in the development of the global calibration models. The authors suggest further study of RMSEP and AED responses to draw reliable conclusions on the effects of tableting process factors. The global calibration model in DT mode has shown superior performance compared to DR mode.

  16. Spectral two-dimensional inversion of frequency-domain induced polarization data from a mining slag heap

    Science.gov (United States)

    Günther, Thomas; Martin, Tina

    2016-12-01

    Abandoned mining waste dumps may become potential resources for mineral reuse. For evaluating such structures, their spatial extension, the mineral content and predominating grain size needs to be determined. Amongst geophysical prospection methods, induced polarization (IP) is particularly suited since ore minerals show significant polarization characteristics. From laboratory measurements it is known that there is a relation between mineral concentration and chargeability, whereas the frequency content is mainly dominated by grain size. Spectral IP (SIP) field data using a range of measuring frequencies can potentially map these quantities spatially. Instead of inverting the individual frequencies independently, we introduce a scheme where adjacent frequencies are constrained to each other. We test it using a synthetic model based on the Cole-Cole model with a body containing two parts of differing time constants. The inversion approach is able to reliably recover the Cole-Cole parameters. We apply the method to a field data set from a slag dump containing melting residuals from different minerals. The resulting models exhibit distinct zones of decreased conductivity and increased polarization that are not fully coincident. Furthermore, we observe a significant change in the spectral content. Taking into account recent laboratory investigations, the obtained chargeabilities hint to the occurrence of sufficient mineral concentration. In comparison with direct current resistivity, there is a clear benefit from using SIP field data in general and spectral analysis in particular.

  17. Broadband near-infrared tomography for breast cancer imaging

    Science.gov (United States)

    Wang, Jia

    Near-infrared (NIR) light provides potential for a new approach to non-invasive detection, diagnosis and clinical management of breast cancer. Using NIR spectroscopic imaging techniques, the physiological information about breast tissue composition can be quantitatively estimated, including hemoglobin, water and lipid concentrations, together with scattering properties. In this thesis work, strategies to improve the accuracy of NIR imaging have been explored experimentally and numerically. A novel Ti:Sapphire laser-based frequency domain tomography system was developed to achieve maximum spectral information, using intrinsic phase-locked detection of the signal propagation. The improvement in quantification through addition of more wavelengths was demonstrated in simulations and in tissue-phantom experiments. A hybrid NIR tomography system combining frequency domain and continuous wave spectroscopy approaches was implemented for imaging healthy subjects and women with malignant breast tumors. Adding measurements at wavelengths above 850nm with the continuous wave method significantly improved the accuracy of water and lipid estimation. When used in cancer imaging in vivo, the NIR contrast information is consistent with physiological and pathological values expected in tumor as seen by investigational studies with Magnetic Resonance Imaging (MRI) and pathology analysis.

  18. Pragmatic circuits frequency domain

    CERN Document Server

    Eccles, William

    2006-01-01

    Pragmatic Circuits: Frequency Domain goes through the Laplace transform to get from the time domain to topics that include the s-plane, Bode diagrams, and the sinusoidal steady state. This second of three volumes ends with a-c power, which, although it is just a special case of the sinusoidal steady state, is an important topic with unique techniques and terminology. Pragmatic Circuits: Frequency Domain is focused on the frequency domain. In other words, time will no longer be the independent variable in our analysis. The two other volumes in the Pragmatic Circuits series include titles on DC

  19. Near Infrared Spectroscopy

    Science.gov (United States)

    2009-01-01

    directly, but to evaluate the performance of each of these systems in their recommended (UMMS) and mar- keted (HT) configurations. Although we did not...son Technology (HT) oximeter is mar- keted specifically for use on the thenar muscle. We therefore used the thenar site for the HT sensor because...critical fourth fac- tor which differentiates near-infrared spectroscopic tissue monitors—the de- sign of the spectroscopic system . There are multiple

  20. Research and application of spectral inversion technique in frequency domain to improve resolution of converted PS-wave

    Science.gov (United States)

    Zhang, Hua; He, Zhen-Hua; Li, Ya-Lin; Li, Rui; He, Guamg-Ming; Li, Zhong

    2017-06-01

    Multi-wave exploration is an effective means for improving precision in the exploration and development of complex oil and gas reservoirs that are dense and have low permeability. However, converted wave data is characterized by a low signal-to-noise ratio and low resolution, because the conventional deconvolution technology is easily affected by the frequency range limits, and there is limited scope for improving its resolution. The spectral inversion techniques is used to identify λ/8 thin layers and its breakthrough regarding band range limits has greatly improved the seismic resolution. The difficulty associated with this technology is how to use the stable inversion algorithm to obtain a high-precision reflection coefficient, and then to use this reflection coefficient to reconstruct broadband data for processing. In this paper, we focus on how to improve the vertical resolution of the converted PS-wave for multi-wave data processing. Based on previous research, we propose a least squares inversion algorithm with a total variation constraint, in which we uses the total variance as a priori information to solve under-determined problems, thereby improving the accuracy and stability of the inversion. Here, we simulate the Gaussian fitting amplitude spectrum to obtain broadband wavelet data, which we then process to obtain a higher resolution converted wave. We successfully apply the proposed inversion technology in the processing of high-resolution data from the Penglai region to obtain higher resolution converted wave data, which we then verify in a theoretical test. Improving the resolution of converted PS-wave data will provide more accurate data for subsequent velocity inversion and the extraction of reservoir reflection information.

  1. Comparability of red/near-infrared reflectance and NDVI based on the spectral response function between MODIS and 30 other satellite sensors using rice canopy spectra.

    Science.gov (United States)

    Huang, Weijiao; Huang, Jingfeng; Wang, Xiuzhen; Wang, Fumin; Shi, Jingjing

    2013-11-26

    Long-term monitoring of regional and global environment changes often depends on the combined use of multi-source sensor data. The most widely used vegetation index is the normalized difference vegetation index (NDVI), which is a function of the red and near-infrared (NIR) spectral bands. The reflectance and NDVI data sets derived from different satellite sensor systems will not be directly comparable due to different spectral response functions (SRF), which has been recognized as one of the most important sources of uncertainty in the multi-sensor data analysis. This study quantified the influence of SRFs on the red and NIR reflectances and NDVI derived from 31 Earth observation satellite sensors. For this purpose, spectroradiometric measurements were performed for paddy rice grown under varied nitrogen levels and at different growth stages. The rice canopy reflectances were convoluted with the spectral response functions of various satellite instruments to simulate sensor-specific reflectances in the red and NIR channels. NDVI values were then calculated using the simulated red and NIR reflectances. The results showed that as compared to the Terra MODIS, the mean relative percentage difference (RPD) ranged from -12.67% to 36.30% for the red reflectance, -8.52% to -0.23% for the NIR reflectance, and -9.32% to 3.10% for the NDVI. The mean absolute percentage difference (APD) compared to the Terra MODIS ranged from 1.28% to 36.30% for the red reflectance, 0.84% to 8.71% for the NIR reflectance, and 0.59% to 9.32% for the NDVI. The lowest APD between MODIS and the other 30 satellite sensors was observed for Landsat5 TM for the red reflectance, CBERS02B CCD for the NIR reflectance and Landsat4 TM for the NDVI. In addition, the largest APD between MODIS and the other 30 satellite sensors was observed for IKONOS for the red reflectance, AVHRR1 onboard NOAA8 for the NIR reflectance and IKONOS for the NDVI. The results also indicated that AVHRRs onboard NOAA7-17 showed

  2. NEAR-INFRARED SPECTROSCOPY OF POST-AGB STARS

    NARCIS (Netherlands)

    OUDMAIJER, RD; WATERS, LBFM; VANDERVEEN, WECJ; GEBALLE, TR

    1995-01-01

    The results of a medium resolution near-infrared spectral survey of 18 post-AGB candidate stars are presented. Most of the stars have near-infrared hydrogen lines in absorption, which is normal for their spectral types. Three stars, HD 101584, HD 179821 and HD 170756 have the CO first overtone bands

  3. Taxonomic Classification of Asteroids via Broadband Near-Infrared Photometry

    NARCIS (Netherlands)

    Petersen, Eric; Thomas, C.; Trilling, D.; Emery, J.; Delbo, M.; Mueller, M.; Dave, R.

    2010-01-01

    For faint asteroids, it is not practical to obtain near-infrared spectra. However, it may be possible to use broadband photometry to infer spectral classifications and study composition. As a test of this, we processed SpeX near-infrared asteroid spectral data to simulate colors that would be obtain

  4. Note: Near infrared interferometric silicon wafer metrology.

    Science.gov (United States)

    Choi, M S; Park, H M; Joo, K N

    2016-04-01

    In this investigation, two near infrared (NIR) interferometric techniques for silicon wafer metrology are described and verified with experimental results. Based on the transparent characteristic of NIR light to a silicon wafer, the fiber based spectrally resolved interferometry can measure the optical thickness of the wafer and stitching low coherence scanning interferometry can reconstruct entire surfaces of the wafer.

  5. Spectral characterization of crude oil using fluorescence (synchronous and time-resolved) and NIR (Near Infrared Spectroscopy); Caracterizacao espectral do petroleo utilizando fluorescencia (sincronizada e resolvida no tempo) e NIR (Near Infrared Spectroscopy)

    Energy Technology Data Exchange (ETDEWEB)

    Falla Sotelo, F.; Araujo Pantoja, P.; Lopez-Gejo, J.; Le Roux, G.A.C.; Nascimento, C.A.O. [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Quimica. Lab. de Simulacao e Controle de Processos; Quina, F.H. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Quimica. Centro de Capacitacao e Pesquisa em Meio Ambiente (CEPEMA)

    2008-07-01

    The objective of the present work is to evaluate the performance of two spectroscopic techniques employed in the crude oil characterization: NIR spectroscopy and fluorescence spectroscopy (Synchronous fluorescence - SF and Time Resolved Fluorescence - TRF) for the development of correlation models between spectral profiles of crude oil samples and both physical properties (viscosity and API density) and physico-chemical properties (SARA analysis: Saturated, Aromatic, Resins and Asphaltenes). The better results for viscosity and density were obtained using NIR whose prediction capacity was good (1.5 cP and 0.5 deg API, respectively). For SARA analysis, fluorescence spectroscopy revealed its potential in the model calibration showing good results (R2 coefficients greater than 0.85). TRF spectroscopy had better performance than SF spectroscopy. (author)

  6. Near-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Virendra Jain

    2015-01-01

    Full Text Available Tissue ischaemia can be a significant contributor to increased morbidity and mortality. Conventional oxygenation monitoring modalities measure systemic oxygenation, but regional tissue oxygenation is not monitored. Near-infrared spectroscopy (NIRS is a non-invasive monitor for measuring regional oxygen saturation which provides real-time information. There has been increased interest in the clinical application of NIRS following numerous studies that show improved outcome in various clinical situations especially cardiac surgery. Its use has shown improved neurological outcome and decreased postoperative stay in cardiac surgery. Its usefulness has been investigated in various high risk surgeries such as carotid endarterectomy, thoracic surgeries, paediatric population and has shown promising results. There is however, limited data supporting its role in neurosurgical population. We strongly feel, it might play a key role in future. It has significant advantages over other neuromonitoring modalities, but more technological advances are needed before it can be used more widely into clinical practice.

  7. Near-infrared hyperspectral reflective confocal microscopy

    Science.gov (United States)

    Huang, Wei; Zhang, Yunhai; Miao, Xin; Xue, Xiaojun; Xiao, Yun

    2016-10-01

    A Near-Infrared HyperSpectral Reflective Confocal Microscopy (NIHS-RCM) is proposed in order to get high resolution images of deep biological tissues such as skin. The microscopy system uses a super-continuum laser for illumination, an acousto-optic tunable filter (AOTF) for rapid selection of near-infrared spectrum, a resonant galvanometer scanner for high speed imaging (15f/s) and near-infrared avalanche diode as detector. Porcine skin and other experiments show that the microscopy system could get deep tissue images (180 μm), and show the different ingredients of tissue with different wavelength of illumination. The system has the ability of selectively imaging of multiple ingredients at deep tissue which can be used in skin diseases diagnosis and other fields.

  8. Development of a tunable Fabry-Perot etalon-based near-infrared interference spectrometer for measurement of the HeI 2{sup 3}S-2{sup 3}P spectral line shape in magnetically confined torus plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ogane, S.; Shikama, T., E-mail: shikama@me.kyoto-u.ac.jp; Hasuo, M. [Department of Mechanical Engineering and Science, Graduate School of Engineering, Kyoto University, Kyoto 615-8540 (Japan); Zushi, H. [Research Institute for Applied Mechanics, Kyushu University, Fukuoka 816-8580 (Japan)

    2015-10-15

    In magnetically confined torus plasmas, the local emission intensity, temperature, and flow velocity of atoms in the inboard and outboard scrape-off layers can be separately measured by a passive emission spectroscopy assisted by observation of the Zeeman splitting in their spectral line shape. To utilize this technique, a near-infrared interference spectrometer optimized for the observation of the helium 2{sup 3}S–2{sup 3}P transition spectral line (wavelength 1083 nm) has been developed. The applicability of the technique to actual torus devices is elucidated by calculating the spectral line shapes expected to be observed in LHD and QUEST (Q-shu University Experiment with Steady State Spherical Tokamak). In addition, the Zeeman effect on the spectral line shape is measured using a glow-discharge tube installed in a superconducting magnet.

  9. Robust Colloidal Nanoparticles of Pyrrolopyrrole Cyanine J-Aggregates with Bright Near-Infrared Fluorescence in Aqueous Media: From Spectral Tailoring to Bioimaging Applications.

    Science.gov (United States)

    Yang, Cangjie; Wang, Xiaochen; Wang, Mingfeng; Xu, Keming; Xu, Chenjie

    2017-03-28

    Colloidal nanoparticles (NPs) containing near-infrared-fluorescent J-aggregates (JAGGs) of pyrrolopyrrole cyanines (PPcys) stabilized by amphiphilic block co-polymers were prepared in aqueous medium. JAGG formation can be tuned by means of the chemical structure of PPcys, the concentration of chromophores inside the polymeric NPs, and ultrasonication. The JAGG NPs exhibit a narrow emission band at 773 nm, a fluorescence quantum yield comparable to that of indocyanine green, and significantly enhanced photostability, which is ideal for long-term bioimaging.

  10. Origin of the spectral deformation in the near infrared radiation from Tore-Supra carbon components; Origine de la deformation spectrale de la luminance proche infrarouge des composants en carbone de Tore Supra

    Energy Technology Data Exchange (ETDEWEB)

    Delchambre, E

    2004-03-01

    This work concerns the understanding of a physical phenomenon which is important for the future course of magnetic confinement fusion research: namely the anomalous deformation in the near infrared of radiation from tokamak plasma facing components under plasma particle impact. The goal of this work was to reproduce this phenomenon in laboratory experiments, characterize it and explain it, so that the measurements of the temperature of plasma facing components can be made with confidence. Laboratory experiments have been performed using an ECR ions source and a helicon plasma source. The spectral luminance deformation has been observed on graphite surface under electrons and ions bombardment and the amplitude of this phenomenon was found to depend on the type of material used and the power density of the incident particles. A systematic consideration and evaluation of alternative explanations for the observed spectral deformation has been made. A number of plausible interpretations has been considered and discarded as e.g. Bremsstrahlung radiation, or assigned a low probability as the luminescence effect. The possible partial transparency of the material has also been considered at some length, but finally discarded because the low thermal conductivity of the graphite materials under consideration does not permit a strong enough temperature gradient to cause the observed deformation. The possible explanation is reduced to the non uniform surface temperature due to the presence of hot spots during particle bombardment. This hypothesis implies that the measured luminance is the contribution of several temperatures. The measured spectral luminance deformation, basing on hot spots hypothesis, is simulated. This hypothesis allows to asses the surface temperature, the hot spots temperature and the hot spots coverage on the surface. These results are validated using a thermal model of dust in radiate equilibrium. This model allows us to deduce an average size of the dust

  11. The Stellar Spectral Features of Nearby Galaxies in the Near-Infrared: Tracers of Thermally-Pulsing Asymptotic Giant Branch Stars?

    CERN Document Server

    Riffel, Rogério; Martins, Lucimara P; Rodíguez-Ardila, Alberto; Ho, Luis C; Riffel, Rogemar A; Lira, Paulina; Martin, Omaira Gonzalez; Ruschel-Dutra, Daniel; Alonso-Herrero, Almudena; Flohic, Helene; McDermid, Richard M; Almeida, Cristina Ramos; Thanjavur, Karun; Winge, Claudia

    2015-01-01

    We analyze the stellar absorption features in high signal-to-noise ratio near-infrared (NIR) spectra of the nuclear region of 12 nearby galaxies, mostly spirals. The features detected in some or all of the galaxies in this sample are the TiO (0.843 $\\mu$m\\ and 0.886 $\\mu$m), VO (1.048 $\\mu$m), CN (1.1 $\\mu$m\\ and 1.4 $\\mu$m), H$\\rm _2$O (1.4 $\\mu$m\\ and 1.9 $\\mu$m) and CO (1.6 $\\mu$m\\ and 2.3 $\\mu$m) bands. The C$\\rm _2$ (1.17 $\\mu$m\\ and 1.76 $\\mu$m) bands are generally weak or absent, although C$\\rm _2$ (1.76 $\\mu$m) may be weakly present in the mean galaxy spectrum. A deep feature near 0.93 $\\mu$m, likely caused by CN, TiO and/or ZrO, is also detected in all objects. Fitting a combination of stellar spectra to the mean spectrum shows that the absorption features are produced by evolved stars: cool giants and supergiant stars in the early- or thermally-pulsing asymptotic giant branch (E-AGB or TP-AGB) phases. The high luminosity of TP-AGB stars, and the appearance of VO and ZrO features in the data, suggest...

  12. Broadband absorption spectroscopy by combining frequency-domain and steady-state techniques

    Science.gov (United States)

    Berger, Andrew J.; Bevilacqua, Frederic; Jakubowski, Dorota B.; Cerussi, Albert E.; Butler, John A.; Hsiang, D.; Tromberg, Bruce J.

    2001-06-01

    A technique for measuring broadband near-infrared absorption spectra of turbid media is presented using a combination of frequency-domain (FD) and steady-state (SS) reflectance methods. Most of the wavelength coverage is provided by a white-light SS measurement, while the FD data are acquired at a few selected wavelengths. Coefficients of absorption ((mu) a) and reduced scattering ((mu) s') derived from the FD data are used to intensity-calibrate the SS measurements and to estimate (mu) s' at all wavelengths in the spectral window of interest. After these steps are performed, (mu) a can be determined by comparing the SS reflectance values to the predictions of diffusion theory, wavelength by wavelength. We present an application of this method to breast tumor characterization. A case study of a fibroadenoma is shown, where different absorption spectra were found between the normal and the tumor sides.

  13. Adapting photosynthesis to the near-infrared: non-covalent binding of phycocyanobilin provides an extreme spectral red-shift to phycobilisome core-membrane linker from Synechococcus sp. PCC7335.

    Science.gov (United States)

    Miao, Dan; Ding, Wen-Long; Zhao, Bao-Qing; Lu, Lu; Xu, Qian-Zhao; Scheer, Hugo; Zhao, Kai-Hong

    2016-06-01

    Phycobiliproteins that bind bilins are organized as light-harvesting complexes, phycobilisomes, in cyanobacteria and red algae. The harvested light energy is funneled to reaction centers via two energy traps, allophycocyanin B and the core-membrane linker, ApcE1 (conventional ApcE). The covalently bound phycocyanobilin (PCB) of ApcE1 absorbs near 660 nm and fluoresces near 675 nm. In cyanobacteria capable of near infrared photoacclimation, such as Synechococcus sp. PCC7335, there exist even further spectrally red shifted components absorbing >700 nm and fluorescing >710 nm. We expressed the chromophore domain of the extra core-membrane linker from Synechococcus sp. PCC7335, ApcE2, in E. coli together with enzymes generating the chromophore, PCB. The resulting chromoproteins, PCB-ApcE2(1-273) and the more truncated PCB-ApcE2(24-245), absorb at 700 nm and fluoresce at 714 nm. The red shift of ~40 nm compared with canonical ApcE1 results from non-covalent binding of the chromophore by which its full conjugation length including the Δ3,3(1) double bond is preserved. The extreme spectral red-shift could not be ascribed to exciton coupling: dimeric PCB-ApcE2(1-273) and monomeric-ApcE2(24-245) absorbed and fluoresced similarly. Chromophorylation of ApcE2 with phycoerythrobilin- or phytochromobilin resulted in similar red shifts (absorption at 615 and 711 nm, fluorescence at 628 or 726 nm, respectively), compared to the covalently bound chromophores. The self-assembled non-covalent chromophorylation demonstrates a novel access to red and near-infrared emitting fluorophores. Brightly fluorescent biomarking was exemplified in E. coli by single-plasmid transformation.

  14. [Drug release system controlled by near infrared light].

    Science.gov (United States)

    Niidome, Takuro

    2013-01-01

    Gold nanorods have absorption bands in the near-infrared region; in this spectral range, light penetrates deeply into tissues. The absorbed light energy is converted into heat by gold nanorods. This is the so-called photothermal effect. Gold nanorods are therefore expected to act not only as thermal converters for photothermal therapy, but also as controllers for drug-release systems responding to irradiation with near-infrared light. To achieve a controlled-release system that could be triggered by light irradiation, the gold nanorods were modified with double-stranded DNA (dsDNA). When the dsDNA-modified gold nanorods were irradiated with near-infrared light, single-stranded DNA (ssDNA) was released from the gold nanorods because of the photothermal effect. The release of ssDNA was also observed in tumors grown on mice after near-infrared light irradiation. We also proposed a different controlled-release system responding to near-infrared light. Gold nanorods were modified with polyethylene glycol (PEG) through Diels-Alder cycloadducts. When the gold nanorods were irradiated with near-infrared light, the PEG chains were released from the gold nanorods because of the retro Diels-Alder reaction induced by the photothermal effect. Such controlled-release systems triggered by near-infrared light irradiation will be expanded for gold nanorod drug delivery system applications.

  15. Precise Near-Infrared Radial Velocities

    CERN Document Server

    Plavchan, Peter; Gagne, Jonathan; Furlan, Elise; Brinkworth, Carolyn; Bottom, Michael; Tanner, Angelle; Anglada-Escude, Guillem; White, Russel; Davison, Cassy; Mills, Sean; Beichman, Chas; Johnson, John Asher; Ciardi, David; Wallace, Kent; Mennesson, Bertrand; Vasisht, Gautam; Prato, Lisa; Kane, Stephen; Crawford, Sam; Crawford, Tim; Sung, Keeyoon; Drouin, Brian; Lin, Sean; Leifer, Stephanie; Catanzarite, Joe; Henry, Todd; von Braun, Kaspar; Walp, Bernie; Geneser, Claire; Ogden, Nick; Stufflebeam, Andrew; Pohl, Garrett; Regan, Joe

    2016-01-01

    We present the results of two 2.3 micron near-infrared radial velocity surveys to detect exoplanets around 36 nearby and young M dwarfs. We use the CSHELL spectrograph (R ~46,000) at the NASA InfraRed Telescope Facility, combined with an isotopic methane absorption gas cell for common optical path relative wavelength calibration. We have developed a sophisticated RV forward modeling code that accounts for fringing and other instrumental artifacts present in the spectra. With a spectral grasp of only 5 nm, we are able to reach long-term radial velocity dispersions of ~20-30 m/s on our survey targets.

  16. Visible, near-infrared spectrometry for simultaneous assessment of geophysical sediment properties (water and grain size) using the Spectral Derivative-Modified Gaussian Model

    Science.gov (United States)

    Verpoorter, C.; Carrère, V.; Combe, J.-P.

    2014-10-01

    The main objective of this study is to extract from reflectance spectra the geophysical properties of mudflat sediments such as water content and grain size. As mentioned in the literature, difficulties remain in separating the respective contributions of grain size and water on the reflectance continuum. This paper deals with the evaluation of a new methodological approach, the Spectral Derivative-Modified Gaussian Model (SD-MGM) for establishing the relationship between the spectral features and the geophysical properties of sediments. The SD-MGM enables the deconvolution of spectra into two main components: (1) Gaussian curves for the absorption bands and (2) a straight line in the wave number domain for the portion of the spectrum that represents continuum. While the retrieved Gaussian features are known to be reliable indicators of the composition, it is shown that the retrieved continuum can be used as a novel approach for determining grain size and water content. Based on regression analyses between the SD-MGM spectral output parameters and the geophysical properties, a quantitative relationship between water content and the way in which the shape of the water band depth at 0.97 µm and 2.8 µm changes has been found during dehydration. It is shown that it is possible to separate three water types present in the sediment structure: saturated, free, and adsorbed waters with high coefficients of determination (r2) of 0.97, 0.98, and 0.94, respectively. The continuum is also revealed to be a useful water content indicator because it is less affected by atmospheric effects.

  17. Science Impacts of the SPHEREx All-Sky Optical to Near-Infrared Spectral Survey: Report of a Community Workshop Examining Extragalactic, Galactic, Stellar and Planetary Science

    CERN Document Server

    Doré, Olivier; Ashby, Matt; Banerjee, Pancha; Battaglia, Nick; Bauer, James; Benjamin, Robert A; Bleem, Lindsey E; Bock, Jamie; Boogert, Adwin; Bull, Philip; Capak, Peter; Chang, Tzu-Ching; Chiar, Jean; Cohen, Seth H; Cooray, Asantha; Crill, Brendan; Cushing, Michael; de Putter, Roland; Driver, Simon P; Eifler, Tim; Feng, Chang; Ferraro, Simone; Finkbeiner, Douglas; Gaudi, B Scott; Greene, Tom; Hillenbrand, Lynne; Höflich, Peter A; Hsiao, Eric; Huffenberger, Kevin; Jansen, Rolf A; Jeong, Woong-Seob; Joshi, Bhavin; Kim, Duho; Kim, Minjin; Kirkpatrick, J Davy; Korngut, Phil; Krause, Elisabeth; Kriek, Mariska; Leistedt, Boris; Li, Aigen; Lisse, Carey M; Mauskopf, Phil; Mechtley, Matt; Melnick, Gary; Mohr, Joseph; Murphy, Jeremiah; Neben, Abraham; Neufeld, David; Nguyen, Hien; Pierpaoli, Elena; Pyo, Jeonghyun; Rhodes, Jason; Sandstrom, Karin; Schaan, Emmanuel; Schlaufman, Kevin C; Silverman, John; Su, Kate; Stassun, Keivan; Stevens, Daniel; Strauss, Michael A; Tielens, Xander; Tsai, Chao-Wei; Tolls, Volker; Unwin, Stephen; Viero, Marco; Windhorst, Rogier A; Zemcov, Michael

    2016-01-01

    SPHEREx is a proposed SMEX mission selected for Phase A. SPHEREx will carry out the first all-sky spectral survey and provide for every 6.2" pixel a spectra between 0.75 and 4.18 $\\mu$m [with R$\\sim$41.4] and 4.18 and 5.00 $\\mu$m [with R$\\sim$135]. The SPHEREx team has proposed three specific science investigations to be carried out with this unique data set: cosmic inflation, interstellar and circumstellar ices, and the extra-galactic background light. It is readily apparent, however, that many other questions in astrophysics and planetary sciences could be addressed with the SPHEREx data. The SPHEREx team convened a community workshop in February 2016, with the intent of enlisting the aid of a larger group of scientists in defining these questions. This paper summarizes the rich and varied menu of investigations that was laid out. It includes studies of the composition of main belt and Trojan/Greek asteroids; mapping the zodiacal light with unprecedented spatial and spectral resolution; identifying and stud...

  18. Advances in near-infrared measurements

    CERN Document Server

    Patonay, Gabor

    1991-01-01

    Advances in Near-Infrared Measurements, Volume 1 provides an overview of near-infrared spectroscopy. The book is comprised of six chapters that tackle various areas of near-infrared measurement. Chapter 1 discusses remote monitoring techniques in near-infrared spectroscopy with an emphasis on fiber optics. Chapter 2 covers the applications of fibers using Raman techniques, and Chapter 3 tackles the difficulties associated with near-infrared data analysis. The subsequent chapters present examples of the capabilities of near-infrared spectroscopy from various research groups. The text wi

  19. Intersubband absorption of cubic GaN/Al(Ga)N quantum wells in the near-infrared to terahertz spectral range

    Science.gov (United States)

    Machhadani, H.; Tchernycheva, M.; Sakr, S.; Rigutti, L.; Colombelli, R.; Warde, E.; Mietze, C.; As, D. J.; Julien, F. H.

    2011-02-01

    The intersubband absorption of cubic GaN/Al(Ga)N quantum wells is studied experimentally and theoretically over a wide spectral range. By changing the quantum well thickness it is possible to tune the intersubband absorption peak wavelength from 1.4 μm (214 THz) to 63 μm (4.76 THz). Comparing the experimental results with simulations based on the effective-mass model we demonstrate that the GaN/AlN conduction-band offset is higher than 1.2 eV. The best fit with the experimental data is achieved for a conduction-band offset of 1.4 eV and for a GaN effective mass of 0.11m0.

  20. Detection limits for blood on four fabric types using infrared diffuse reflection spectroscopy in mid- and near-infrared spectral windows.

    Science.gov (United States)

    DeJong, Stephanie A; Lu, Zhenyu; Cassidy, Brianna M; O'Brien, Wayne L; Morgan, Stephen L; Myrick, Michael L

    2015-09-01

    Detection limits (DL) for blood on four fabric types were estimated for calibrations derived using partial least squares regression applied to infrared (IR) diffuse reflection spectra. Samples were prepared by dip-coating acrylic, cotton, nylon, and polyester fabrics from solutions of diluted rat blood. While DLs often appear in terms of dilution factor in the forensic community, mass percentage, coverage (mass per unit area), or film thickness are often more relevant when comparing experimental methods. These alternate DL units are related to one another and presented here. The best IR diffuse reflection DLs for blood on acrylic and cotton fabrics were in the mid-IR spectral window corresponding to the protein Amide I/II absorption bands. These DLs were dilution by a factor of 2300 (0.019% w/w blood solids) for acrylic and a factor of 610 (0.055% w/w blood solids) for cotton. The best DL for blood on polyester was found in the mid-IR spectral window corresponding to the protein Amide A absorption band at dilution by a factor of 900 (0.034% w/w blood solids). Because of the similarity between the IR spectra of blood solids and nylon fabrics, no satisfactory IR DLs were determined for the calibration of blood on nylon. We compare our values to DLs reported for blood detection using the standard luminol method. The most commonly reported luminol DLs are of the order of 1000-fold dilution, which we estimate are a factor of 2-7 lower than our reported IR DLs on a coverage basis.

  1. Global Monitoring of Terrestrial Chlorophyll Fluorescence from Moderate-spectral-resolution Near-infrared Satellite Measurements: Methodology, Simulations, and Application to GOME-2

    Science.gov (United States)

    Joiner, J.; Gaunter, L.; Lindstrot, R.; Voigt, M.; Vasilkov, A. P.; Middleton, E. M.; Huemmrich, K. F.; Yoshida, Y.; Frankenberg, C.

    2013-01-01

    Globally mapped terrestrial chlorophyll fluorescence retrievals are of high interest because they can provide information on the functional status of vegetation including light-use efficiency and global primary productivity that can be used for global carbon cycle modeling and agricultural applications. Previous satellite retrievals of fluorescence have relied solely upon the filling-in of solar Fraunhofer lines that are not significantly affected by atmospheric absorption. Although these measurements provide near-global coverage on a monthly basis, they suffer from relatively low precision and sparse spatial sampling. Here, we describe a new methodology to retrieve global far-red fluorescence information; we use hyperspectral data with a simplified radiative transfer model to disentangle the spectral signatures of three basic components: atmospheric absorption, surface reflectance, and fluorescence radiance. An empirically based principal component analysis approach is employed, primarily using cloudy data over ocean, to model and solve for the atmospheric absorption. Through detailed simulations, we demonstrate the feasibility of the approach and show that moderate-spectral-resolution measurements with a relatively high signal-to-noise ratio can be used to retrieve far-red fluorescence information with good precision and accuracy. The method is then applied to data from the Global Ozone Monitoring Instrument 2 (GOME-2). The GOME-2 fluorescence retrievals display similar spatial structure as compared with those from a simpler technique applied to the Greenhouse gases Observing SATellite (GOSAT). GOME-2 enables global mapping of far-red fluorescence with higher precision over smaller spatial and temporal scales than is possible with GOSAT. Near-global coverage is provided within a few days. We are able to show clearly for the first time physically plausible variations in fluorescence over the course of a single month at a spatial resolution of 0.5 deg × 0.5 deg

  2. Spectral responses in near-infrared of the mixed compounds III-V ternary and quaternary, based on GaSb

    Science.gov (United States)

    Mbow, B.; Rezzoug, N.; Peremarti, C.; Mezerreg, A.; Llinares, C.

    1993-09-01

    From the simulation of the spectral response of the different photodetector devices elaborated in our laboratory (C.E.M.), we determine the influence of geometrical and physical parameters in order to achieve the best photodetector operating at the wavelength 2.55 μm. In this paper we present: Gao{0.6}In{0.4}Sbn/Ga{0.6}In{0.4}Sbp homojunctions matched on GaSbp substrate, Ga{0.75}In{0.25}As{0.23}Sbp/GaSbn ternary heterojunction and GaSbp/Ga{0.74}In{0.26}As{0.23}Sb0.77p/GaSbn quaternary heterojunction. The GaSbp layer with an energy band gap greater than Ga{0.74}In{0.26}As{0.23}Sb0.77p optical gap will act as a window, reducing the effect of surface recombinaison. Results of the simulation are compared to experimental curves to determine the values of photoelectrical parameters (diffusion length, recombination velocity at the surface ...). Les mesures de réponse spectrale dans la gamme [0,4 eV à 2 eV] ont été effectuées sur des homojonctions, Ga{0,6}In{0,4}Sbn/Ga{0,6}In{0,4}Sbp déposées sur un substrat de GaSb et des hétérostructures ternaires Ga{0,75}In{0,25}Sbp/GaSbn et quaternaires GaSbp/Ga{0,74}In{0,26}As{0,23}Sb0,77p/GaSbn. La couche de GaSbp avec un gap plus grand que celui de Ga{0,74}In{0,26}As{0,23}Sb0,77p joue le rôle d'effet fenêtre. En s'appuyant sur les résultats de la simulation et en accordant les spectres expérimentaux aux spectres théoriques, on détermine les valeurs des paramètres photoélectriques (longueurs de diffusion, les vitesses de recombinaison en surface ... ) intervenant dans le rendement quantique.

  3. Quantitative detection of hemoglobin saturation on piglet brain by near-infrared frequency-domain spectroscopy

    Science.gov (United States)

    Du, Congwu; Andersen, Carol; Chance, Britton

    1998-01-01

    An approach of using phase modulation spectroscopy (PMS) system has been proposed which has single frequency, dual- wavelength with phase-only output for oximetry to minimize the influences of room light in the clinical environment. The availability of this method has been verified by laboratory experiments both in vitro and in vivo. In this study, a 200 Mhz PMS system has been used for measuring on piglet brain in vivo, to detect blood volume and saturation change during normoxia to hypoxia periods, and to monitor the brain depolarization in the hypoxic stress. Our experimental results show that the brain saturation estimated by PMS is approximately 84% and lies between arterial and venous blood values of 97% and 80% in normoxia, and tends to move close to the venous side in hypoxia. In addition, the excessive hypoxic stress triggers the brain to be bio-energetic deficits and finally introduced the neural depolarization, which can be effectively detected by recording the increment of tissue scattering.

  4. Luminophores of tunable colors from ternary Ag-In-S and quaternary Ag-In-Zn-S nanocrystals covering the visible to near-infrared spectral range.

    Science.gov (United States)

    Gabka, Grzegorz; Bujak, Piotr; Kotwica, Kamil; Ostrowski, Andrzej; Lisowski, Wojciech; Sobczak, Janusz W; Pron, Adam

    2017-01-04

    Ternary Ag-In-S or quaternary Ag-In-Zn-S nanocrystals were prepared from simple precursors (silver nitrate, indium(iii) chloride, zinc stearate in a mixture of DDT and ODE) by injecting a solution of elemental sulfur into OLA. Ternary nanocrystals were modified by depositing either a ZnS or a CdS shell, yielding type I and type II core/shell systems exhibiting photoluminescence QY in the range of 12-16%. Careful optimization of the reaction conditions allowed alloyed quaternary Ag-In-Zn-S nanocrystals exhibiting tunable photoluminescence in the spectral range of 520-720 nm with a QY of 48% and 59% for green and red radiations, respectively, to be obtained. (1)H NMR analysis of the nanocrystal organic shell, after dissolution of its inorganic core, indicated that surfacial sulfur atoms were covalently bonded to aliphatic chains whereas surfacial cations were coordinated by amines and carboxylate anions. No thiol-type ligands were detected. Transfer of the prepared nanocrystals to water could be achieved in one step by exchanging the initial ligands for 11-mercaptoundecanoic ones resulting in a QY value of 31%. A new Ag-In-Zn-S nanocrystal preparation method was elaborated in which indium and zinc salts of fatty acids were used as cation precursors and DDT was replaced by thioacetamide. This original DDT-free method enabled similar tuning of the photoluminescence properties of the nanocrystals as in the previous method; however the measured photoluminescence QYs were three times lower. Hence, further optimization of the new method is required.

  5. The value of time and frequency domain, and spectral temporal mapping analysis of the signal-averaged electrocardiogram in identification of patients with hypertrophic cardiomyopathy at increased risk of sudden death.

    Science.gov (United States)

    Kulakowski, P; Counihan, P J; Camm, A J; McKenna, W J

    1993-07-01

    Late potentials detected by the signal-averaged ECG (SAECG) identify post-infarction patients at risk from sustained ventricular tachycardia (VT) and sudden death. Hypertrophic cardiomyopathy (HCM) is also associated with increased risk of sudden death. In adults, episodes of non-sustained VT on ambulatory ECG monitoring are a marker of high risk patients. In children and adolescents, however, there is no reliable ECG marker, and clinical features have low predictive accuracy. The prognostic value of the SAECG in HCM has not been systematically evaluated. We examined the relation of detailed time domain, frequency domain, and spectral temporal mapping analysis of the SAECG and clinical and echocardiographic features, and the results of 48 h ambulatory ECG monitoring in 121 consecutive patients with HCM. Non-sustained VT on Holter monitoring was recorded in 27 (23%) patients. An abnormal time domain SAECG was present in three (11%) patients with VT vs three (3%) without VT (ns). Of the SAECG variables, reduced (below 150 microV) voltage of the initial 40 ms of the signal-averaged QRS complex was the best predictor for non-sustained VT (sensitivity: 95%; specificity: 74%: positive predictive accuracy: 64%; negative predictive accuracy: 97%). Nine patients (of whom eight were < or = 30 years of age) experienced catastrophic events: three died suddenly and six had been resuscitated from out-of-hospital ventricular fibrillation. None of them had an abnormal time domain SAECG. The frequency domain analysis and spectral temporal mapping of the SAECG did not improve the identification of patients with VT or patients with catastrophic events. In conclusion, alterations of the initial portion of the signal-averaged QRS complex identified patients with HCM and non-sustained VT, but the SAECG was not useful in identifying young patients who suffered cardiac arrest.

  6. Electromagnetically induced transparency in metamaterials at near-infrared frequency

    DEFF Research Database (Denmark)

    Zhang, Jingjing; Xiao, Sanshui; Jeppesen, Claus

    2010-01-01

    We employ a planar metamaterial structure composed of a splitring-resonator (SRR) and paired nano-rods to experimentally realize a spectral response at near-infrared frequencies resembling that of electromagnetically induced transparency. A narrow transparency window associated with low loss...

  7. Frequency-Domain Optical Mammogram

    Science.gov (United States)

    2002-10-01

    the tumor. * Combination of the above two points into a composite false-color breast image containing structural information (from the second...Antonangeli, A. Savoia, T. Parasassi, and N. Rosato, " Plastique : a synchrotron radiation beamline for time resolved fluorescence in the frequency domain

  8. Analysis of Leucaena mimosine, Acacia tannins and total phenols by near infrared reflectance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Prasad, M.N.V. [Hyderabad Univ. (India). Dept. of Plant Sciences

    1995-11-01

    The mimosine contents of Leucaena foliage, Acacia tannins and total phenols from leaf, bark and pod were analyzed by a near infrared relectance spectrophotometer (Compscan 3000). A calibration equation (linear summation regression) was developed with near infrared spectral analysis software, using 30 spectra from old and young leaves of Leucaena and 23 spectra from different samples of Acacia. The near infrared analyzer calculated that the percentages of mimosine, total phenols and tannins are closely comparable to laboratory results. (author)

  9. Near-infrared Mueller matrix imaging for colonic cancer detection

    Science.gov (United States)

    Wang, Jianfeng; Zheng, Wei; Lin, Kan; Huang, Zhiwei

    2016-03-01

    Mueller matrix imaging along with polar decomposition method was employed for the colonic cancer detection by polarized light in the near-infrared spectral range (700-1100 nm). A high-speed (colonic tissues (i.e., normal and caner) were acquired. Polar decomposition was further implemented on the 16 images to derive the diattentuation, depolarization, and the retardance images. The decomposed images showed clear margin between the normal and cancerous colon tissue samples. The work shows the potential of near-infrared Mueller matrix imaging for the early diagnosis and detection of malignant lesions in the colon.

  10. NEWS: the near-infrared Echelle for wideband spectroscopy

    Science.gov (United States)

    Veyette, Mark J.; Muirhead, Philip S.; Hall, Zachary J.; Taylor, Brian; Ye, Jimmy

    2016-08-01

    We present an updated optical and mechanical design of NEWS: the Near-infrared Echelle for Wide-band Spectroscopy (formerly called HiJaK: the High-resolution J, H and K spectrometer), a compact, high-resolution, near-infrared spectrometer for 5-meter class telescopes. NEWS provides a spectral resolution of 60,000 and covers the full 0.8-2.5 μm range in 5 modes. We adopt a compact, lightweight, monolithic design and have developed NEWS to be mounted to the instrument cube at the Cassegrain focus of the new 4.3-meter Discovery Channel Telescope.

  11. NEWS: the near-infrared Echelle for wideband spectroscopy

    CERN Document Server

    Veyette, Mark; Hall, Zachary; Taylor, Brian; Ye, Jimmy

    2016-01-01

    We present an updated optical and mechanical design of NEWS: the Near-infrared Echelle for Wide-band Spectroscopy (formerly called HiJaK: the High-resolution J, H and K spectrometer), a compact, high-resolution, near-infrared spectrometer for 5-meter class telescopes. NEWS provides a spectral resolution of 60,000 and covers the full 0.8-2.5 micron range in 5 modes. We adopt a compact, lightweight, monolithic design and developed NEWS to be mounted to the instrument cube at the Cassegrain focus of the the new 4.3-meter Discovery Channel Telescope.

  12. Raman crystal lasers in the visible and near-infrared

    Institute of Scientific and Technical Information of China (English)

    EICHLERH.J.; GADG.M.A.; KAMINSKIIA.A.; RHEEH.

    2003-01-01

    Raman lasers based on potassium gadolinium tungstate and lead tungstate crystals pumped by a≈120 ps Nd: YAG laser at 1.064/μm were developed. High reflection mirrors for the Stokes wavelength have been used to generate near-infrared and eye safe spectral region of 1.15 - 1.32/μm. Second harmonic generation of the generated Raman lasers was observed. Eifficient multiple Stokes and anti-Stokes picosecond generation in 64 crystals have been shown to exhibit stimulated Raman scattering on about 700 lines covering the whole visible and near-infrared spectrum. All stimulated Raman scattering (SRS) wavelengths in the visible and near-infrared spectrum are identified and attributed to the SRS-active vibration modes of these crystals.

  13. Raman crystal lasers in the visible and near-infrared

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Raman lasers based on potassium gadolinium tungstate and lead tungstate crystals pumped by a≈120 ps Nd: YAG laser at 1.064 μm were developed. High reflection mirrors for the Stokes wavelength have been used to generate near-infrared and eye safe spectral region of 1.15-1.32 μm. Second harmonic generation of the generated Raman lasers was observed. Eifficient multiple Stokes and anti-Stokes picosecond generation in 64 crystals have been shown to exhibit stimulated Raman scattering on about 700 lines covering the whole visible and near-infrared spectrum. All stimulated Raman scattering (SRS) wavelengths in the visible and near-infrared spectrum are identified and attributed to the SRS-active vibration modes of these crystals.

  14. RCSED—A Value-added Reference Catalog of Spectral Energy Distributions of 800,299 Galaxies in 11 Ultraviolet, Optical, and Near-infrared Bands: Morphologies, Colors, Ionized Gas, and Stellar Population Properties

    Science.gov (United States)

    Chilingarian, Igor V.; Zolotukhin, Ivan Yu.; Katkov, Ivan Yu.; Melchior, Anne-Laure; Rubtsov, Evgeniy V.; Grishin, Kirill A.

    2017-02-01

    We present RCSED, the value-added Reference Catalog of Spectral Energy Distributions of galaxies, which contains homogenized spectrophotometric data for 800,299 low- and intermediate-redshift galaxies (0.007information on galaxy properties obtained with state-of-the-art data analysis, RCSED enables direct studies of galaxy formation and evolution over the last 5 Gyr. We provide tabulated color transformations for galaxies of different morphologies and luminosities, and analytic expressions for the red sequence shape in different colors. RCSED comprises integrated k-corrected photometry in up to 11 ultraviolet, optical, and near-infrared bands published by the GALEX, SDSS, and UKIDSS wide-field imaging surveys; results of the stellar population fitting of SDSS spectra including best-fitting templates, velocity dispersions, parameterized star formation histories, and stellar metallicities computed for instantaneous starburst and exponentially declining star formation models; parametric and non-parametric emission line fluxes and profiles; and gas phase metallicities. We link RCSED to the Galaxy Zoo morphological classification and galaxy bulge+disk decomposition results of Simard et al. We construct the color–magnitude, Faber–Jackson, and mass–metallicity relations; compare them with the literature; and discuss systematic errors of the galaxy properties presented in our catalog. RCSED is accessible from the project web site and via VO simple spectrum access and table access services using VO-compliant applications. We describe several examples of SQL queries to the database. Finally, we briefly discuss existing and future scientific applications of RCSED and prospective catalog extensions to higher redshifts and different wavelengths. .

  15. The DENIS & 2MASS Near Infrared Surveys

    CERN Document Server

    Mamon, G A

    1996-01-01

    The DENIS and 2MASS near infrared surveys are presented. Their applications in extragalactic astronomy and cosmology are listed. The prospects for a rapid spectroscopic followup survey of a near infrared selected sample of nearly $10^5$ galaxies are illustrated with Monte-Carlo simulations.

  16. Functional Near Infrared Spectroscopy: Watching the Brain in Flight

    Science.gov (United States)

    Harrivel, Angela; Hearn, Tristan A.

    2012-01-01

    Functional Near Infrared Spectroscopy (fNIRS) is an emerging neurological sensing technique applicable to optimizing human performance in transportation operations, such as commercial aviation. Cognitive state can be determined via pattern classification of functional activations measured with fNIRS. Operational application calls for further development of algorithms and filters for dynamic artifact removal. The concept of using the frequency domain phase shift signal to tune a Kalman filter is introduced to improve the quality of fNIRS signals in real-time. Hemoglobin concentration and phase shift traces were simulated for four different types of motion artifact to demonstrate the filter. Unwanted signal was reduced by at least 43%, and the contrast of the filtered oxygenated hemoglobin signal was increased by more than 100% overall. This filtering method is a good candidate for qualifying fNIRS signals in real time without auxiliary sensors.

  17. Rapid Classification of Common Plastics Based on Near-Infrared Spectral Technology%基于近红外光谱技术的常见塑料快速分类方法研究

    Institute of Scientific and Technical Information of China (English)

    郭慧玲; 邓文怡; 李晓英

    2012-01-01

    对废弃塑料进行回收再生利用具有重要的意义,首要的问题是对塑料进行鉴别分类。本文主要对塑料快速分类方法做了深入的研究。设计并搭建了采集数据的实验系统,编写了处理数据的处理软件。分别采用了全局相关分析、特征相关分析、欧氏距离和k_means聚类分析对数据进行了处理。对常见PE,PET,PP,PVC等塑料进行快速分类鉴别。其中k_means聚类分析法对89个未知样品的预测结果准确率为92.1%,说明近红外光谱结合k_means聚类法进行常见塑料种类鉴别在技术上是可行的。另外提出采用多模式共识可以进一步提高分类的准确率和可靠性。%Recycling of waste plastics is of great significance and the primary problem is the identification and classification of plastics.An in-depth research on rapid classification of plastics has been made.The experimental system of data collection were designed and set up,the software of data processing was written,then data were processed by using global correlation analysis,characteristics related correlation analysis,Euclidean distance analysis and k_means cluster analysis.The common waste plastics such as PE,PET,PP,and PVC were identified and classified Rapidly.The accuracy rate is 92.1% on the predicted results to 89 unknown samples using k_means cluster analysis method.It is indicated that using the near-infrared spectral technology combined with k_means cluster analysis method to identify common plastic types are technically feasible.In addition,it is proposed that adopting consensus of multi-mode can further improve the classification accuracy and reliability.

  18. ANALYSIS OF SWITCHGRASS CHARACTERISTICS USING NEAR INFRARED SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    Nicole Labbé

    2008-11-01

    Full Text Available Switchgrass varieties grown under various environments were investi-gated by dispersive and Fourier Transform Near-Infrared (NIR spectro-meters. The collected NIR spectra were analyzed using multivariate approaches. More specifically, principal component analysis (PCA and projection to latent structures (PLS regression techniques were employed to classify and predict characteristics of the switchgrass samples. The multivariate results were compared to reflectance indices that are commonly used to study the physiological performance of plants. From near infrared spectra, discrimination between the two growth locations was successfully achieved by PCA. Separation based on the ecotype and the rate of fertilizer applied to the field was also possible by the multivariable analysis of the spectral data. For the classification/ discrimination of the switchgrass samples, the near infrared spectra collected by the dispersive and the Fourier Transform spectrometers provided similar results. From the two near infrared data sets robust models were developed to predict non-structural carbohydrates content and the rate of nitrogen applied to the field. However, the spectra collected by the dispersive spectrometer resulted in more accurate models for these samples.

  19. A Near-Infrared Photon Counting Camera for High Sensitivity Astronomical Observation Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovation is a Near Infrared Photon-Counting Sensor (NIRPCS), an imaging device with sufficient sensitivity to capture the spectral signatures, in the...

  20. Near Infrared Spectroscopy Facilitates Rapid Identification of Both Young and Mature Amazonian Tree Species

    National Research Council Canada - National Science Library

    Lang, Carla; Costa, Flávia Regina Capellotto; Camargo, José Luís Campana; Durgante, Flávia Machado; Vicentini, Alberto

    2015-01-01

    .... Near-infrared spectroscopy (FT-NIR) has previously been shown to be effective in species discrimination of adult plants, so if young and adults have a similar spectral signature, discriminant functions based on FT-NIR spectra of adults...

  1. Near infrared spectroscopy and chemometrics analysis of complex traits in animal physiology

    Science.gov (United States)

    Near infrared reflectance (NIR) applications have been expanding from the traditional framework of small molecule chemical purity and composition (as defined by spectral libraries) to complex system analysis and holistic exploratory approaches to questions in biochemistry, biophysics and environment...

  2. Practical guide to interpretive near-infrared spectroscopy

    CERN Document Server

    Workman, Jr, Jerry

    2007-01-01

    Containing focused, comprehensive coverage, Practical Guide to Interpretive Near-Infrared Spectroscopy gives you the tools necessary to interpret NIR spectra. The authors present extensive tables, charts, and figures with NIR absorption band assignments and structural information for a broad range of functional groups, organic compounds, and polymers. They include visual spectral representation of all major compound functional groupings and NIR frequency ranges. Organized by functional group type and chemical structure, based on standard compound classification, the chapters are easy to

  3. Bioprocess monitoring using near-infrared spectroscopy.

    Science.gov (United States)

    Suehara, Ken-ichiro; Yano, Takuo

    2004-01-01

    Near-infrared spectroscopy (NIR) is a nondestructive analytical technique that has been used for simultaneous prediction of the concentrations of several substrates, products and constructs in mixtures sampled from fermentation processes. In this chapter, we discuss applications of NIR for the monitoring of bioprocesses involving rice vinegar, compost, glycolipid, L-glutamic acid, lactic acid fermentation, mushroom cultivation, and Koji production. This includes detailed discussion of applications of NIR to process management of rice vinegar fermentation and compost fermentation. In the present study, absorbance at wavelengths between 400 and 2500 nm was measured at 2 nm intervals. To obtain calibration equations, multiple linear regression (MLR) was performed on NIR spectral data and conventional analysis values of a calibration sample set. To validate these calibration equations, they were used to calculate concentrations of a prediction sample set, which were then compared with concentrations measured by conventional methods. There was excellent agreement between the results of the conventional method and those of the NIR method, when both were used to analyze culture broth of rice vinegar fermentation and solid-state fermented compost. These results indicate that NIR is a useful method for monitoring and control of bioprocesses.

  4. Comments on the paper: M. Pawlak, K. Strzałkowski, Identification of the photoluminescence response in the frequency domain modulated infrared radiometry signal of ZnTe:Cr bulk crystal, Infrared Phys. Technol. 78 (2016) 190-194

    Science.gov (United States)

    Pawlak, M.

    2017-09-01

    The frequency-domain expression for the photoluminescence signal SPL (the photocarrier radiometry signal which is the form of the near infrared photoluminescence) which consists of the discrete lifetimes can be written as following [1

  5. Higher order statistical frequency domain decomposition for operational modal analysis

    Science.gov (United States)

    Nita, G. M.; Mahgoub, M. A.; Sharyatpanahi, S. G.; Cretu, N. C.; El-Fouly, T. M.

    2017-02-01

    Experimental methods based on modal analysis under ambient vibrational excitation are often employed to detect structural damages of mechanical systems. Many of such frequency domain methods, such as Basic Frequency Domain (BFD), Frequency Domain Decomposition (FFD), or Enhanced Frequency Domain Decomposition (EFFD), use as first step a Fast Fourier Transform (FFT) estimate of the power spectral density (PSD) associated with the response of the system. In this study it is shown that higher order statistical estimators such as Spectral Kurtosis (SK) and Sample to Model Ratio (SMR) may be successfully employed not only to more reliably discriminate the response of the system against the ambient noise fluctuations, but also to better identify and separate contributions from closely spaced individual modes. It is shown that a SMR-based Maximum Likelihood curve fitting algorithm may improve the accuracy of the spectral shape and location of the individual modes and, when combined with the SK analysis, it provides efficient means to categorize such individual spectral components according to their temporal dynamics as coherent or incoherent system responses to unknown ambient excitations.

  6. Near infrared lasers in flow cytometry.

    Science.gov (United States)

    Telford, William G

    2015-07-01

    Technology development in flow cytometry has closely tracked laser technology, the light source that flow cytometers almost exclusively use to excite fluorescent probes. The original flow cytometers from the 1970s and 1980s used large water-cooled lasers to produce only one or two laser lines at a time. Modern cytometers can take advantage of the revolution in solid state laser technology to use almost any laser wavelength ranging from the ultraviolet to the near infrared. Commercial cytometers can now be equipped with many small solid state lasers, providing almost any wavelength needed for cellular analysis. Flow cytometers are now equipped to analyze 20 or more fluorescent probes simultaneously, requiring multiple laser wavelengths. Instrument developers are now trying to increase this number by designing fluorescent probes that can be excited by laser wavelength at the "edges" of the visible light range, in the near ultraviolet and near-infrared region. A variety of fluorescent probes have been developed that excite with violet and long wavelength ultraviolet light; however, the near-infrared range (660-800 nm) has yet seen only exploitation in flow cytometry. Fortunately, near-infrared laser diodes and other solid state laser technologies appropriate for flow cytometry have been in existence for some time, and can be readily incorporated into flow cytometers to accelerate fluorescent probe development. The near infrared region represents one of the last "frontiers" to maximize the number of fluorescent probes that can be analyzed by flow cytometry. In addition, near infrared fluorescent probes used in biomedical tracking and imaging could also be employed for flow cytometry with the correct laser wavelengths. This review describes the available technology, including lasers, fluorescent probes and detector technology optimal for near infrared signal detection. Published by Elsevier Inc.

  7. Frequency domain FIR and IIR adaptive filters

    Science.gov (United States)

    Lynn, D. W.

    1990-01-01

    A discussion of the LMS adaptive filter relating to its convergence characteristics and the problems associated with disparate eigenvalues is presented. This is used to introduce the concept of proportional convergence. An approach is used to analyze the convergence characteristics of block frequency-domain adaptive filters. This leads to a development showing how the frequency-domain FIR adaptive filter is easily modified to provide proportional convergence. These ideas are extended to a block frequency-domain IIR adaptive filter and the idea of proportional convergence is applied. Experimental results illustrating proportional convergence in both FIR and IIR frequency-domain block adaptive filters is presented.

  8. Near-infrared imaging spectrometer onboard NEXTSat-1

    Science.gov (United States)

    Jeong, Woong-Seob; Park, Sung-Joon; Moon, Bongkon; Lee, Dae-Hee; Pyo, Jeonghyun; Park, Won-Kee; Park, Youngsik; Kim, Il-Joong; Ko, Kyeongyeon; Lee, Dukhang; Kim, Min Gyu; Kim, Minjin; Ko, Jongwan; Shin, Goo-Hwan; Chae, Jangsoo; Matsumoto, Toshio

    2016-07-01

    The NISS (Near-infrared Imaging Spectrometer for Star formation history) is the near-infrared instrument optimized to the first next generation of small satellite (NEXTSat-1) in Korea. The spectro-photometric capability in the near-infrared range is a unique function of the NISS. The major scientific mission is to study the cosmic star formation history in local and distant universe. For those purposes, the NISS will perform the large areal imaging spectroscopic survey for astronomical objects and low background regions. We have paid careful attention to reduce the volume and to increase the total throughput. The newly implemented off-axis optics has a wide field of view (2° x 2°) and a wide wavelength range from 0.9 to 3.8μm. The mechanical structure is designed to consider launching conditions and passive cooling of the telescope. The compact dewar after relay-lens module is to operate the infrared detector and spectral filters at 80K stage. The independent integration of relay-lens part and primary-secondary mirror assembly alleviates the complex alignment process. We confirmed that the telescope and the infrared sensor can be cooled down to around 200K and 80K, respectively. The engineering qualification model of the NISS was tested in the space environment including the launch-induced vibration and shock. The NISS will be expected to demonstrate core technologies related to the development of the future infrared space telescope in Korea.

  9. Synopsis of current satellite snow mapping techniques, with emphasis on the application of near-infrared data

    Science.gov (United States)

    Barnes, J. C.; Smallwood, M. D.

    1975-01-01

    The Skylab EREP S192 Multispectral Scanner data have provided for the first time an opportunity to examine the reflectance characteristics of snowcover in several spectral bands extending from the visible into the near-infrared spectral region. The analysis of the S192 imagery and digital tape data indicates a sharp drop in reflectance of snow in the near-infrared, with snow becoming essentially nonreflective in Bands 11 (1.55-1.75 micron) and 12 (2.10-2.35 micron). Two potential applications to snow mapping of measurements in the near-infrared spectral region are possible: (1) the use of a near-infrared band in conjunction with a visible band to distinguish automatically between snow and water droplet clouds; and (2) the use of one or more near-infrared bands to detect areas of melting snow.

  10. Near Infrared Spectra of SAGE LMC AGB Stars

    Science.gov (United States)

    Blum, Robert D.; Volk, K.; Srinivasan, S.

    2011-01-01

    We present K-band spectra of a sample of Spitzer SAGE LMC sources obtained on the 4-m SOAR telescope in Chile. The near infrared spectral classifications are compared to classifications from Spitzer IRS spectra of the same sources and to the original SAGE IRAC and MIPS photometric classifications. The SOAR Telescope is a joint project of: Conselho Nacional de Pesquisas Cientficas e Tecnolgicas CNPq-Brazil, The University of North Carolina at Chapel Hill, Michigan State University, and NOAO (which is run by the Association of Universities for Research in Astronomy on behalf of the National Science Foundation).

  11. Near Infrared absorbing iron-complexed colorants for photovoltaic applications

    Energy Technology Data Exchange (ETDEWEB)

    Sekar, N., E-mail: n.sekar@ictmumbai.edu.i [Department of Dyestuff Technology, University Institute of Chemical Technology (UICT), University of Bombay, Mumbai 400019 (India); Raut, Rajesh K.; Umape, Prashant G. [Department of Dyestuff Technology, University Institute of Chemical Technology (UICT), University of Bombay, Mumbai 400019 (India)

    2010-04-15

    Near Infrared absorbing colorants have several applications in the high technology area like heat ray blocking, energy conversion, and optical data storage. All these applications require that the colorants need to have broadband absorption extending up to the NIR region as well improved thermal stability. With the above objective in mind several analogues of pigment Green B (C.I. Acid Green 1) are prepared with improved thermal stability. These novel colorants are obtained by the incorporation of carboxamide group which imparts higher thermal stability. The spectral and TGA studies have shown that they are superior colorants, for application into photovoltaic cells.

  12. Near-infrared spectroscopy of comet Bradfield 1979l

    Science.gov (United States)

    Danks, A. C.; Dennefeld, M.

    1981-02-01

    Spectroscopic observations using an unintensified reticon detector are presented of comet Bradfield 1979l, covering the spectral region from 6100 to 11,000 A. The red CN 2-0, 3-1, and 1-0 bands are easily identified in the nuclear region and their intensity ratios are used to determine that the vibrational transition probability for the ground electronic state lies between 0.32 and 1/sec. The CN 2-0 and 1-0 bands are also present in the coma. The interest in simultaneous measurements of the near-infrared and space UV of future comets is pointed out.

  13. Frequency Domain Image Filtering Using CUDA

    Directory of Open Access Journals (Sweden)

    Muhammad Awais Rajput

    2014-10-01

    Full Text Available In this paper, we investigate the implementation of image filtering in frequency domain using NVIDIA?s CUDA (Compute Unified Device Architecture. In contrast to signal and image filtering in spatial domain which uses convolution operations and hence is more compute-intensive for filters having larger spatial extent, the frequency domain filtering uses FFT (Fast Fourier Transform which is much faster and significantly reduces the computational complexity of the filtering. We implement the frequency domain filtering on CPU and GPU respectively and analyze the speed-up obtained from the CUDA?s parallel processing paradigm. In order to demonstrate the efficiency of frequency domain filtering on CUDA, we implement three frequency domain filters, i.e., Butterworth, low-pass and Gaussian for processing different sizes of images on CPU and GPU respectively and perform the GPU vs. CPU benchmarks. The results presented in this paper show that the frequency domain filtering with CUDA achieves significant speed-up over the CPU processing in frequency domain with the same level of (output image quality on both the processing architectures

  14. A New Gas Cell for High-Precision Doppler Measurements in the Near-Infrared

    CERN Document Server

    Valdivielso, L; Martín, E

    2010-01-01

    High-resolution spectroscopy in the near-infrared could become the leading method for discovering extra-solar planets around very low-mass stars and brown dwarfs. To help to achieve an accuracy of ~m/s, we are developing a gas cell which consists of a mixture of gases whose absorption spectral lines span all over the near-infrared region. We present the most promising mixture, made of acetylene, nitrous oxide, ammonia, chloromethans and hydrocarbons. The mixture is contained in a small size 13 cm long gas cell and covers most of the H and K-bands. It also shows small absorptions in the J-band but they are few and not sharp enough for near infrared wavelength calibration. We describe the working method and experiments and compare our results with the state of the art for near infrared gas cells.

  15. Absolute near-infrared oximetry for urology: a quantitative study of the tissue hemoglobin saturation before and after testicular torsion in a rabbit model

    Science.gov (United States)

    Hallacoglu, Bertan; Matulewicz, Richard S.; Paltiel, Harriet J.; Padua, Horacio; Gargollo, Patricio; Cannon, Glenn; Alomari, Ahmad; Sassaroli, Angelo; Fantini, Sergio

    2009-02-01

    We present an experimental study on four rabbits to demonstrate the feasibility of near-infrared spectroscopy in the noninvasive assessment of testicular torsion. We used a multi-distance frequency-domain method, based on a fixed detector position and a 9-mm linear scan of the illumination optical fibers, to measure absolute values of pre- and post-operative testicular oxygen saturation. Unilateral testicular torsions (by 0°, 540° or 720°) on experimental testes and contralateral sham surgeries (no torsion) on control testes were performed and studied. Our results showed (a) a consistent baseline absolute tissue oxygen saturation value of 78% +/- 5%; (b) a comparable absolute saturation of 77% +/- 6% on the control side (testes after sham surgery); and (c) a significantly lower tissue oxygen saturation of 36% +/- 2% on the experimental side (testes after 540° or 720° torsion surgery). These results demonstrate the capability of frequency domain nearinfrared spectroscopy in the assessment of absolute testicular hemoglobin desaturation caused by torsion, and show promise as a potential method to serve as a complement to conventional color and spectral Doppler ultrasonography.

  16. Near infrared polymer light-emitting diodes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yong; YANG Jian; HOU Qiong; MO Yueqi; PENG Junbiao; CAO Yong

    2005-01-01

    High efficiency of near infrared polymer light-emitting diodes with bilayer structure was obtained. The diode structure is ITO/PEDOT/L1/L2/Ba/Al, where L1 is phenyl-substituted poly [p-phenylphenylene vinylene] derivative (P-PPV), L2 is 9,9-dioctylfluorene (DOF) and 4,7- bis(3-hexylthiophen)-2-yl-2,1,3-naphthothiadiazole (HDNT) copolymer (PFHDNT10). The electroluminescence (EL) spectrum of diodes from PFHDNT10 is at 750 nm located in the range of near infrared. The maximum external quantum efficiency is up to 2.1% at the current density of 35 mA/cm2. The improvement of the diode's performances was considered to be the irradiative excitons confined in the interface between L1 and L2 layers.

  17. Near infrared transmission through clothing: applications in sensing and screening

    Science.gov (United States)

    Hutchins, D. A.; Canal, C. M.; Saleem, A.; Davis, L. A. J.; Green, R. J.

    2011-11-01

    Experiments have been performed to demonstrate that near infrared (NIR) transmission through a wide range of clothing materials is possible. Studies have shown that the characteristics of NIR transmission are affected by both the type of fibre used, and the weave pattern. A series of experiments has indicated that NIR transmission is also dependent on other variables such as fabric porosity and dye colour. It is shown that, in many cases, transmission coefficients are sufficiently high that imaging and spectroscopy of objects hidden behind clothing samples should be possible. However, while transmission through clothing at NIR wavelengths in the 750-1,700 nm range is often more effective than in the visible or IR regions, the fabrics themselves will modify the transmitted signal in terms of spatial effects, intensity and spectral content. The paper also describes the possible use of near infrared signals to identify objects that are hidden behind clothing layers. This can be done using spectroscopy. It is important, however, to distinguish the various contributions that exist within the backscattered signal. A set of careful laboratory experiments have demonstrated that transmission through a set of different clothing fabrics does modify the spectral content of signals, but that the spectrum of a particular chemical can still be identified, provided certain steps are taken. These involve a set of careful calibration measurements, and the use of processing techniques for the retrieval of data. It will be shown that this is possible for both granular solids and selected liquids.

  18. Near infrared few-cycle pulses for high harmonic generation

    CERN Document Server

    Driever, Steffen; Delagnes, Jean-Christophe; Fedorov, Nikita; Arnold, Martin; Bigourd, Damien; Cormier, Eric; Guichard, Roland; Constant, Eric; Zair, Amelle

    2014-01-01

    We report on the development of tunable few-cycle pulses with central wavelengths from 1.6 um to 2 um. Theses pulses were used as a proof of principle for high harmonic generation in atomic and molecular targets. In order to generate such pulses we produced a filament in a 4 bar krypton cell. Spectral broadening by a factor of 2 to 3 of a 40 fs near infrared input pulse was achieved. The spectrally broadened output pulses were then compressed by fused silica plates down to the few-cycle regime close to the Fourier limit. The auto-correlation of these pulses revealed durations of about 3 cycles for all investigated central wavelengths. Pulses with a central wavelength of 1.7 um and up to 430 uJ energy per pulse were employed to generate high order harmonics in Xe, Ar and N2. Moving to near infrared few-cycle pulses opens the possibility to operate deeply in the non-perturbative regime with a Keldysh parameter smaller than 1. Hence, this source is suitable for the study of the non-adiabatic tunneling regime in ...

  19. Quantitative frequency-domain fluorescence spectroscopy in tissues and tissue-like media

    Science.gov (United States)

    Cerussi, Albert Edward

    1999-09-01

    In the never-ending quest for improved medical technology at lower cost, modern near-infrared optical spectroscopy offers the possibility of inexpensive technology for quantitative and non-invasive diagnoses. Hemoglobin is the dominant chromophore in the 700-900 nm spectral region and as such it allows for the optical assessment of hemoglobin concentration and tissue oxygenation by absorption spectroscopy. However, there are many other important physiologically relevant compounds or physiological states that cannot be effectively sensed via optical methods because of poor optical contrast. In such cases, contrast enhancements are required. Fluorescence spectroscopy is an attractive component of optical tissue spectroscopy. Exogenous fluorophores, as well as some endogenous ones, may furnish the desperately needed sensitivity and specificity that is lacking in near-infrared optical tissue spectroscopy. The main focus of this thesis was to investigate the generation and propagation of fluorescence photons inside tissues and tissue-like media (i.e., scattering dominated media). The standard concepts of fluorescence spectroscopy have been incorporated into a diffusion-based picture that is sometimes referred to as photon migration. The novelty of this work lies in the successful quantitative recovery of fluorescence lifetimes, absolute fluorescence quantum yields, fluorophore concentrations, emission spectra, and both scattering and absorption coefficients at the emission wavelength from a tissue-like medium. All of these parameters are sensitive to the fluorophore local environment and hence are indicators of the tissue's physiological state. One application demonstrating the capabilities of frequency-domain lifetime spectroscopy in tissue-like media is a study of the binding of ethidium bromide to bovine leukocytes in fresh milk. Ethidium bromide is a fluorescent dye that is commonly used to label DNA, and hence visualize chromosomes in cells. The lifetime of

  20. [Near infrared light irradiator using halogen lamp].

    Science.gov (United States)

    Ide, Yasuo

    2012-07-01

    The practical electric light bulb was invented by Thomas Alva Edison in 1879. Halogen lamp is the toughest and brightest electric light bulb. With light filter, it is used as a source of near infrared light. Super Lizer and Alphabeam are made as near infrared light irradiator using halogen lamp. The light emmited by Super Lizer is linear polarized near infrared light. The wave length is from 600 to 1,600 nm and strongest at about 1,000 nm. Concerning Super Lizer, there is evidence of analgesic effects and normalization of the sympathetic nervous system. Super Lizer has four types of probes. SG type is used for stellate ganglion irradiation. B type is used for narrow area irradiation. C and D types are for broad area irradiation. The output of Alphabeam is not polarized. The wave length is from 700 to 1,600 nm and the strongest length is about 1,000nm. Standard attachment is used for spot irradiation. Small attachment is used for stellate ganglion irradiation. Wide attachment is used for broad area irradiation. The effects of Alphabeam are thought to be similar to that of Super Lizer.

  1. A frequency-domain derivation of shot-noise

    Science.gov (United States)

    Rice, Frank

    2016-01-01

    A formula for shot-noise is derived in the frequency-domain. The derivation is complete and reasonably rigorous while being appropriate for undergraduate students; it models a sequence of random pulses using Fourier sine and cosine series, and requires some basic statistical concepts. The text here may serve as a pedagogic introduction to the spectral analysis of random processes and may prove useful to introduce students to the logic behind stochastic problems. The concepts of noise power spectral density and equivalent noise bandwidth are introduced.

  2. Matching Performance among Visible and near Infrared Coating, Low Infrared Emitting Coating and Microwave Absorbing Coating

    Institute of Scientific and Technical Information of China (English)

    XIE Guohua; ZHANG Zuoguang; WU Ruibin

    2005-01-01

    The matching performance among the visible and near infrared conting, the low infrared emitting coating and the microwave absorbing coating was investigated. Experimental results shaw that the resulting material is characteristic of wideband effect ranging from the visible, near infrared and 3-5μm, 8- 14 μm infrared portion of the spectrum, as well as the radar region from 8 to 18 GHz when these three materials form a layerstructure material system. The microwave absorbing ability of material is hardly changed. The resonance peak moves towards lower frequency as the thickness of the visible, near infrared coating and the low infrared emitting coating increases. This problem can be resolved by controlling the thickness of the material. On the other hand,the infrared emissivity ε of the material system increases as the thickness of the visible, near infrared coating increases. This can be resolved by increasing infrared transparency of the visible and near infrared topcoating or controlling its thickness. The experimental resulting material system has spectral reflection characteristics in visible and near infrared regions that are similar to those of the natural bnckground.

  3. Enhanced spatial near-infrared modulation of graphene-loaded perfect absorbers using plasmonic nanoslits.

    Science.gov (United States)

    Cai, Yijun; Zhu, Jinfeng; Liu, Qing Huo; Lin, Timothy; Zhou, Jianyang; Ye, Longfang; Cai, Zhiping

    2015-12-14

    Modulating spatial near-infrared light for ultra-compact electro-optic devices is a critical issue in optical communication and imaging applications. To date, spatial near-infrared modulators based on graphene have been reported, but they showed limited modulation effects due to the relatively weak light-graphene interaction. In combination with graphene and metallic nanoslits, we design a kind of ultrathin near-infrared perfect absorber with enhanced spatial modulation effects and independence on a wide range of incident angles. The modulated spectral shift of central wavelength is up to 258.2 nm in the near-infrared range, which is more promising in applications than state-of-the-art devices. The modulation enhancement is attributed to the plasmonic nanoslit mode, in which the optical electric field is highly concentrated in the deep subwavelength scale and the light-graphene interaction is significantly strengthened. The physical insight is deeply revealed by a combination of equivalent circuit and electromagnetic field analysis. The design principles are not only crucial for spatial near-infrared modulators, but also provide a key guide for developing active near-infrared patch nanoantennas based on graphene.

  4. Design of planar chiral metamaterials for near-infrared regime

    Science.gov (United States)

    Kaya, Sabri; Turkmen, Mustafa; Topaktas, Omer

    2017-01-01

    Planar chiral metamaterials (PCMs) comprising double-layer dielectric-metal-dielectric resonant structures in the shape of a windmill are presented for near-infrared regime. The circular dichroism is retrieved from transmission spectra. Effects of used materials on circular dichroism characteristics of PCM arrays are investigated for the first time. The dependence of spectral characteristics on the geometrical parameters of the PCMs is analyzed by the finite-difference time-domain method. The observations indicated that the circular dichroism characteristics of the proposed PCM arrays are strongly dependent on the type of metal and dielectric materials. Due to the enhanced chiroptical near-field response and tunable spectral behavior, proposed PCM arrays may have potential for biosensing applications of chiral biomolecules.

  5. Frequency comb vernier spectroscopy in the near infrared

    CERN Document Server

    Zhu, F; Bicer, A; Strohaber, J; Kolomenskii, A A; Gohle, C; Amani, M; Schuessler, H A

    2014-01-01

    We perform femtosecond frequency comb vernier spectroscopy in the near infrared with a femtosecond Er doped fiber laser, a scanning high-finesse cavity and an InGaAs camera. By utilizing the properties of a frequency comb and a scanning high-finesse cavity such spectroscopy provides broad spectral bandwidth, high spectral resolution, and high detection sensitivity on a short time scale. We achieved an absorption sensitivity of ~8E-8 cm-1Hz-1/2 corresponding to a detection limit of ~70 ppbv for acetylene, with a resolution of ~1.1 GHz in single images taken in 0.5 seconds and covering a frequency range of ~5 THz. These measurements have broad applications for sensing other greenhouse gases in this fingerprint near IR region with a simple apparatus.

  6. [Near-infrared Raman spectroscopy for diagnosis of gastric cancer].

    Science.gov (United States)

    Jin, Shaoqin; Mao, Hua

    2014-03-01

    To establish a method for early diagnosis of gastric cancer using near-infrared Raman spectroscopy. A rapid near-infrared Raman system was used to examine the tissue specimens of pathologically confirmed gastric cancer (33 cases), gastric precancerous lesions (27 cases), and normal gastric mucosa (45 cases). All the specimens were obtained from 105 patients undergoing gastrectomy or endoscopic biopsy of suspected gastric lesions. High-quality Raman spectra ranging from 700 to 1800 cm(-1) were acquired from the gastric tissues within 5 s. The distribution pattern of Raman spectra in gastric cancer differed significantly from those of gastric precancerous lesions and normal gastric mucosa, particularly in the spectral ranges of 853 cm(-1), 936 cm(-1), 1003 cm(-1), 1032 cm(-1), 1174 cm(-1), 1208 cm(-1), 1323 cm(-1), 1335 cm(-1), 1450 cm(-1), and 1655 cm(-1), which contained signals related to proteins, nucleic acids and lipids. The diagnostic decision algorithm based on the Raman peak intensity ratios of I1003/ I1337, I1003/I1445, I1003/I1655, and I1156/I1655 yielded remarkable differences in gastric cancer from gastric precancerous lesions and normal gastric mucosa, and the ratios were significantly higher in normal gastric tissues (Pinfrared Raman spectroscopy using PCA-LDA algorithms associated with leave- one-out and cross-validation method showed diagnostic sensitivities of 81.5%, 85.3%, and 100%, and specificities of 86.4%, 100%, and 97.4% for normal gastric mucosa, precancerous lesions and gastric cancer, respectively. near-infrared Raman spectroscopy in conjunction with intensity ratio algorithms shows the potential for noninvasive diagnosis and detection of gastric malignancy at the molecular level.

  7. In vivo spatial frequency domain spectroscopy of two layer media

    Science.gov (United States)

    Yudovsky, Dmitry; Nguyen, John Quan M.; Durkin, Anthony J.

    2012-10-01

    Monitoring of tissue blood volume and local oxygen saturation can inform the assessment of tissue health, healing, and dysfunction. These quantities can be estimated from the contribution of oxyhemoglobin and deoxyhemoglobin to the absorption spectrum of the dermis. However, estimation of blood related absorption in skin can be confounded by the strong absorption of melanin in the epidermis and epidermal thickness and pigmentation varies with anatomic location, race, gender, and degree of disease progression. Therefore, a method is desired that decouples the effect of melanin absorption in the epidermis from blood absorption in the dermis for a large range of skin types and thicknesses. A previously developed inverse method based on a neural network forward model was applied to simulated spatial frequency domain reflectance of skin for multiple wavelengths in the near infrared. It is demonstrated that the optical thickness of the epidermis and absorption and reduced scattering coefficients of the dermis can be determined independently and with minimal coupling. Then, the same inverse method was applied to reflectance measurements from a tissue simulating phantom and in vivo human skin. Oxygen saturation and total hemoglobin concentrations were estimated from the volar forearms of weakly and strongly pigmented subjects using a standard homogeneous model and the present two layer model.

  8. Note: A simple broad bandwidth undersampling frequency-domain digital diffuse optical spectroscopy system

    Science.gov (United States)

    Jung, Justin; Istfan, Raeef; Roblyer, Darren

    2014-07-01

    Near-Infrared frequency-domain technologies, such as Diffuse Optical Spectroscopy (DOS), have demonstrated growing potential in a number of clinical applications. The broader dissemination of this technology is limited by the complexity and cost of instrumentation. We present here a simple system constructed with off-the-shelf components that utilizes undersampling for digital frequency-domain dDOS measurements. Broadband RF sweeps (50-300 MHz) were digitally sampled at 25 MSPS; amplitude, phase, and optical property extractions were within 5% of network analyzer derived values. The use of undersampling for broad bandwidth dDOS provides a significant reduction in complexity, power consumption, and cost compared with high-speed ADCs and analog techniques.

  9. Load Estimation by Frequency Domain Decomposition

    DEFF Research Database (Denmark)

    Pedersen, Ivar Chr. Bjerg; Hansen, Søren Mosegaard; Brincker, Rune;

    2007-01-01

    When performing operational modal analysis the dynamic loading is unknown, however, once the modal properties of the structure have been estimated, the transfer matrix can be obtained, and the loading can be estimated by inverse filtering. In this paper loads in frequency domain are estimated...... by analysis of simulated responses of a 4 DOF system, for which the exact modal parameters are known. This estimation approach entails modal identification of the natural eigenfrequencies, mode shapes and damping ratios by the frequency domain decomposition technique. Scaled mode shapes are determined by use...

  10. System Identification A Frequency Domain Approach

    CERN Document Server

    Pintelon, Rik

    2012-01-01

    System identification is a general term used to describe mathematical tools and algorithms that build dynamical models from measured data. Used for prediction, control, physical interpretation, and the designing of any electrical systems, they are vital in the fields of electrical, mechanical, civil, and chemical engineering. Focusing mainly on frequency domain techniques, System Identification: A Frequency Domain Approach, Second Edition also studies in detail the similarities and differences with the classical time domain approach. It high??lights many of the important steps in the identi

  11. Near Infrared Spectroscopy of Young Brown Dwarfs in Upper Scorpius

    CERN Document Server

    Dawson, P; Ray, T P; Peterson, D E; Rodgers-Lee, D; Geers, V

    2014-01-01

    Spectroscopic follow-up is a pre-requisite for studies of the formation and early evolution of brown dwarfs. Here we present IRTF/SpeX near-infrared spectroscopy of 30 candidate members of the young Upper Scorpius association, selected from our previous survey work. All 24 high confidence members are confirmed as young very low mass objects with spectral types from M5 to L1, 15-20 of them are likely brown dwarfs. This high yield confirms that brown dwarfs in Upper Scorpius can be identified from photometry and proper motions alone, with negligible contamination from field objects (<4%). Out of the 6 candidates with lower confidence, 5 might still be young very low mass members of Upper Scorpius, according to our spectroscopy. We demonstrate that some very low mass class II objects exhibit radically different near infrared (0.6 - 2.5micron) spectra from class III objects, with strong excess emission increasing towards longer wavelengths and partially filled in features at wavelengths shorter than 1.25micron...

  12. The Vela Pulsar in the Near-Infrared

    CERN Document Server

    Shibanov, Y A; Sollerman, J; Lundqvist, P

    2003-01-01

    We report on the first detection of the Vela pulsar in the near-infrared with the VLT/ISAAC in the Js and H bands. The pulsar magnitudes are Js=22.71 +/- 0.10 and H=22.04 +/- 0.16. We compare our results with the available multiwavelength data and show that the dereddened phase-averaged optical spectrum of the pulsar can be fitted with a power law F_nu propto nu^(-alpha_nu) with alpha_nu = 0.12 +/- 0.05, assuming the color excess E(B-V)=0.055 +/-0.005 based on recent spectral fits of the emission of the Vela pulsar and its supernova remnant in X-rays. The negative slope of the pulsar spectrum is different from the positive slope observed over a wide optical range in the young Crab pulsar spectrum. The near-infrared part of the Vela spectrum appears to have the same slope as the phase-averaged spectrum in the high energy X-ray tail, obtained in the 2-10 keV range with the RXTE. Both of these spectra can be fitted with a single power law suggesting their common origin. Because the phase-averaged RXTE spectrum i...

  13. Near-infrared scintillation of liquid argon

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, T. [Fermilab; Escobar, C. O. [Campinas State U.; Lippincott, W. H. [Fermilab; Rubinov, P. [Fermilab

    2016-03-03

    Since the 1970s it has been known that noble gases scintillate in the near infrared (NIR) region of the spectrum (0.7 $\\mu$m < $\\lambda$; < 1.5$\\mu$m). More controversial has been the question of the NIR light yield for condensed noble gases. We first present the motivation for using the NIR scintillation in liquid argon detectors, then briefly review early as well as more recent efforts and finally show encouraging preliminary results of a test performed at Fermilab.

  14. Near-infrared scintillation of liquid argon

    CERN Document Server

    Alexander, T; Lippincott, W H; Rubinov, P

    2016-01-01

    Since the 1970s it has been known that noble gases scintillate in the near infrared (NIR) region of the spectrum (0.7 $\\mu$m < $\\lambda$; < 1.5$\\mu$m). More controversial has been the question of the NIR light yield for condensed noble gases. We first present the motivation for using the NIR scintillation in liquid argon detectors, then briefly review early as well as more recent efforts and finally show encouraging preliminary results of a test performed at Fermilab.

  15. The Gemini Near-Infrared Imager (NIRI)

    Science.gov (United States)

    Hodapp, Klaus W.; Jensen, Joseph B.; Irwin, Everett M.; Yamada, Hubert; Chung, Randolph; Fletcher, Kent; Robertson, Louis; Hora, Joseph L.; Simons, Douglas A.; Mays, Wendy; Nolan, Robert; Bec, Matthieu; Merrill, Michael; Fowler, Albert M.

    2003-12-01

    This paper presents the basic design of the Gemini Near-Infrared Imager (NIRI) and discusses its capabilities. NIRI offers three different pixel scales to match different operating modes of the Gemini telescope and allows polarimetric and spectroscopic observations. It is equipped with an infrared on-instrument wave-front sensor (OIWFS) to allow tip-tilt and focus correction even in highly obscured regions. The science detector array is an Aladdin II InSb 1024×1024 pixel device sensitive from 1.0 to 5.5 μm.

  16. Silicon-Vacancy Color Centers in Nanodiamonds: Cathodoluminescence Imaging Marker in the Near Infrared

    OpenAIRE

    Zhang, Huiliang; Aharonovich, Igor; Glenn, David R.; Schalek, R.; Magyar, Andrew P.; Lichtman, Jeff W.; Hu, Evelyn L.; Walsworth, Ronald L.

    2013-01-01

    We demonstrate that nanodiamonds fabricated to incorporate silicon-vacancy (Si-V) color centers provide bright, spectrally narrow, and stable cathodoluminescence (CL) in the near-infrared. Si-V color centers containing nanodiamonds are promising as non-bleaching optical markers for correlated CL and secondary electron microscopy, including applications to nanoscale bioimaging.

  17. A New Indicator for Optimal Preprocessing and Wavelengths Selection of Near-Infrared Spectra

    NARCIS (Netherlands)

    Skibsted, E.; Boelens, H.F.M.; Westerhuis, J.A.; Witte, D.T.; Smilde, A.K.

    2004-01-01

    Preprocessing of near-infrared spectra to remove unwanted, i.e., non-related spectral variation and selection of informative wavelengths is considered to be a crucial step prior to the construction of a quantitative calibration model. The standard methodology when comparing various preprocessing

  18. A New Indicator for Optimal Preprocessing and Wavelengths Selection of Near-Infrared Spectra

    NARCIS (Netherlands)

    Skibsted, E.; Boelens, H.F.M.; Westerhuis, J.A.; Witte, D.T.; Smilde, A.K.

    2004-01-01

    Preprocessing of near-infrared spectra to remove unwanted, i.e., non-related spectral variation and selection of informative wavelengths is considered to be a crucial step prior to the construction of a quantitative calibration model. The standard methodology when comparing various preprocessing tec

  19. A New Indicator for Optimal Preprocessing and Wavelengths Selection of Near-Infrared Spectra

    NARCIS (Netherlands)

    E. Skibsted; H.F.M. Boelens; J.A. Westerhuis; D.T. Witte; A.K. Smilde

    2004-01-01

    Preprocessing of near-infrared spectra to remove unwanted, i.e., non-related spectral variation and selection of informative wavelengths is considered to be a crucial step prior to the construction of a quantitative calibration model. The standard methodology when comparing various preprocessing tec

  20. Remote Sensing of Rock Type in the Visible and Near-Infrared,

    Science.gov (United States)

    Visible and near-infrared spectra of minerals and rocks have been measured and evaluated in terms of remote sensing applications. The authors...difficult or impossible to use in a generalized remote sensing effort in which the composition of all rocks is to be mapped. Instead, this spectral

  1. Sorting in-shell walnuts using near infrared spectroscopy for improved drying efficiency and product quality

    Science.gov (United States)

    In the current walnut drying practice, dryers comingle nuts with varying moisture contents (MC) which results in over drying of nuts with low MC and thereby decrease product quality. The objectives of this research were to investigate correlations among near infrared (NIR) spectral data and MC of fr...

  2. Time and Frequency Domain Identification and Analysis of a Gas Turbine Engine

    OpenAIRE

    Boaghe, O.M.; S. A. Billings; L. M. Li; Fleming, P J; Liu, J

    2000-01-01

    The NARMAX (Nonlinear Auto Regressive Moving Average model with eXogenous inputs) approach has been used to analyse the dynamics of a gas turbine engine. The fuel flow-shaft speed relationship is analysed by identifying both time and frequency domain models of the system. The frequency domain analysis is studied by mapping the discrete-time NARMAX models into the Generalised Frequency Response Functions (GFRF's) to reveal the nonlinear coupling between the various input spectral components an...

  3. Predicting rapeseed oil content with near-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Roberta Rossato

    2013-12-01

    Full Text Available The objective of this work was to establish a calibration equation and to estimate the efficiency of near-infrared reflectance (NIR spectroscopy for evaluating rapeseed oil content in Southern Brazil. Spectral data from 124 half-sib families were correlated with oil contents determined by the chemical method. The accuracy of the equation was verified by coefficient of determination (R² of 0.92, error of calibration (SEC of 0.78, and error of performance (SEP of 1.22. The oil content of ten genotypes, which were not included in the calibration with NIR, was similar to the one obtained by the standard chemical method. NIR spectroscopy is adequate to differentiate oil content of rapeseed genotypes.

  4. Canopy near-infrared reflectance and terrestrial photosynthesis

    Science.gov (United States)

    Badgley, Grayson; Field, Christopher B.; Berry, Joseph A.

    2017-01-01

    Global estimates of terrestrial gross primary production (GPP) remain highly uncertain, despite decades of satellite measurements and intensive in situ monitoring. We report a new approach for quantifying the near-infrared reflectance of terrestrial vegetation (NIRV). NIRV provides a foundation for a new approach to estimate GPP that consistently untangles the confounding effects of background brightness, leaf area, and the distribution of photosynthetic capacity with depth in canopies using existing moderate spatial and spectral resolution satellite sensors. NIRV is strongly correlated with solar-induced chlorophyll fluorescence, a direct index of photons intercepted by chlorophyll, and with site-level and globally gridded estimates of GPP. NIRV makes it possible to use existing and future reflectance data as a starting point for accurately estimating GPP.

  5. Near-infrared spectrometric determination of dipyrone in closed ampoules.

    Science.gov (United States)

    Sanches, Fátima Aparecida C; Abreu, Rosimeri B; Pontes, Márcio José Coelho; Leite, Flaviano C; Costa, Daniel Jackson E; Galvão, Roberto Kawakami H; Araujo, Mario Cesar U

    2012-04-15

    The present paper proposes an analytical method for fast near-infrared (NIR) determination of dipyrone in injectable formulations with a nominal content of 50.0%mv(-1) without violation of the ampoule. For this purpose, two multivariate calibration methods are evaluated, namely Partial-Least-Squares (PLS) and Multiple Linear Regression (MLR) with variable selection by the Successive Projections Algorithm (SPA). The resulting models comprised four latent variables (PLS) and five spectral variables (MLR-SPA). Appropriate predictions were obtained in both cases, with RMSEP values of 0.39 (PLS) and 0.35%mv(-1) (MLR-SPA) and correlation coefficients of 0.9970 (PLS) and 0.9975 (MLR-SPA) for a calibration range of 40-60%mv(-1). No systematic error was observed and no significant differences were found between the predicted and reference values, according to a paired t-test at 95% confidence level.

  6. Diagnosis potential of near infrared Mueller Matrix imaging for colonic adenocarcinoma

    Science.gov (United States)

    Wang, Jianfeng; Zheng, Wei; Lin, Kan; Huang, Zhiwei

    2016-03-01

    Mueller matrix imaging along with polar decomposition method was employed for the colonic adenocarcinoma detection by polarized light in the near-infrared spectral range (700-1100 nm). A high-speed (caner) were acquired. Polar decomposition was further implemented on the 16 images to derive the diattentuation, depolarization, and the retardance images. The decomposed images showed clear margin between the normal and adenocarcinomaous colon tissue samples. The work shows the potential of near-infrared Mueller matrix imaging for the early diagnosis and detection of malignant lesions in the colon.

  7. Characterization of materials for optimal near-infrared and x-ray imaging of the breast.

    Science.gov (United States)

    Michaelsen, Kelly; Krishnaswamy, Venkataramanan; Pogue, Brian W; Brooks, Ken; Defreitas, Ken; Shaw, Ian; Poplack, Steven P; Paulsen, Keith D

    2012-09-01

    Development of a detector case for complete co-registration of images in a non-fiber-based combined near-infrared spectral tomography and digital breast tomosynthesis, required analysis to find materials that could support a breast under full mammographic compression without affecting the x-ray images or the quality of the near infrared measurements. Several possible solutions were considered, and many types of plastics were tested in the development of the detector case. Light channeling within the detector case changed the data obtained in resin and agarose phantoms, lowering recovered absorption values. Additional developments focusing on blocking stray light were successful and permitted a normal subject imaging exam.

  8. Near Infrared (nir) Imaging for Nde

    Science.gov (United States)

    Diamond, G. G.; Pallav, P.; Hutchins, D. A.

    2008-02-01

    A novel application of near infrared (NIR) signals is presented, which can be used to provide images of many different materials and objects. It is effectively a very low cost non-ionising alternative to many applications currently being investigated using electromagnetic waves at other frequencies, such as THz and X-ray imaging. This alternative technique can be realised by very simple and inexpensive electronics and is inherently far more portable and easy to use. Transmission imaging results from this technique are presented from examples industrial quality control, food inspection and various security applications, and the results compared to existing techniques. In addition, this technique can be used in through-transmission mode on biological and medical samples, and images are presented that differentiate between not only flesh and bone, but also various types of soft tissue.

  9. Near Infrared Spectroscopy Systems for Tissue Oximetry

    DEFF Research Database (Denmark)

    Petersen, Søren Dahl

    We present exible silicon device platforms, which combine polyimide with polydimethylsiloxane in order to add flexibility and biocompatibility to the silicon devices. The device platforms are intended as tissue oximeters, using near infrared spectroscopy, but could potentially also be used...... for other medical applications. The tissue oximeters are realised by incorporation of pn-diodes into the silicon in order to form arrays of infrared detectors. These arrays can then be used for spatially resolved spectroscopy measurements, with the targeted end user being prematurely born infant children...... of incidence. Thus, also minimising the drop in quantum efficiency for light incident at 38 from normal to only 5.2 % compared to a drop of 9.1 % for devices without the black silicon nanostructures. In conclusion both the flexible device platforms and infrared detectors were found to work....

  10. Optical glass: dispersion in the near infrared

    Science.gov (United States)

    Hartmann, Peter

    2011-10-01

    With deliveries of optical glass lots measurement data are given for the visible range usually from 436 nm (g-line) to 656 nm (C-line). Sometimes the question arises if refractive index values in the near infrared can be calculated from these data. With near infrared we mean the range from the C-line up to 1700 nm in this publication. The reason is that up to 1700 nm most optical glasses have hardly any reduction in their transmission. On the basis of a large amount of production data obtained over more than ten years with precision v-block refractometer evaluations are possible up to 1014 nm. The precision spectrometer URIS developed by SCHOTT enables to analyze the refractive index with measurement uncertainty fairly below 10-5 for even longer wavelengths up to 2325 nm, however on a much smaller data basis. The variability of the IR dispersion is shown for selected glass types. Frequency distributions for the different deviation shapes give information how reliable extrapolations are from the visible range to the near IR. The precision refractometer data were used to simulate such extrapolations employing partial dispersion data from catalog data sheets and to check the consistency of simulated with real data. For some glass types extrapolations seem to be possible. However, there are also glass types, where the method using catalog partial dispersions leads to significant deviations from reality. So if extrapolations are intended to be done, a general check should be performed if this is justified for the glass type of interest.

  11. 近红外特征谱段相关系数法测定胶囊中非法添加格列齐特和氢氯噻嗪%Near Infrared Correlation Coefficient Method with Characteristic Spectral Band for Determination of Illegally Added Gliclazide and Hydrochlorothiazide in Capsule Preparations

    Institute of Scientific and Technical Information of China (English)

    夏方亮

    2015-01-01

    Objective To detect the illegally added gliclazide and hydrochlorothiazide in capsule preparations with the near infrared (NIR) correlation coefficient method. Methods The near infrared spectrum of the chemical reference substance of gliclazide and hydrochlorothiazide was used as reference spectrum, the specific spectrum was selected. According to the added amount of gliclazide and hydrochlorothiazide in capsule preparations, the threshold value of similarity coefficient in this spectral band of the tested sample spectrum and the reference spectrum was established. Whether the tested sample contained gliclazide or hydrochlorothiazide was qualitatively estimated. Results The spectral band 5 850~5 700 cm-1 was selected as the characteristic band for gliclazide, and the threshold value was set as 60%. The spectral band 6 150~5 950 cm-1 was selected as the characteristic band for hydrochlorothiazide, and the threshold value was set as 70%. Conclusion The two models have high accuracy and strong applicability, which may be used as a fast detection method to determine illegally added gliclazide and hydrochlorothiazide in traditional Chinese medicine and health food capsule preparations on market.%目的:利用近红外特征谱段相关系数法检测胶囊中是否非法添加格列齐特和氢氯噻嗪。方法以格列齐特和氢氯噻嗪化学对照品的近红外光谱为参照光谱,选择特征谱段,根据格列齐特和氢氯噻嗪被掺入胶囊中的量建立待测样品光谱和参照光谱在该谱段的相似系数阈值,定性判断胶囊中是否含有格列齐特或氢氯噻嗪。结果选定5850~5700 cm-1谱段为格列齐特的特征谱段,设定阈值为60%;选定6150~5950 cm-1谱段为氢氯噻嗪的特征谱段,设定阈值为70%。结论两个模型均有较高的准确性和较强的适用性,可作为检测市售中成药和保健品胶囊剂中非法添加格列齐特和氢氯噻嗪的快检方法。

  12. Quantitative analysis of peanut oil content in ternary blended edible oil using near infrared spectroscopy

    Science.gov (United States)

    Chen, Huacai; Liu, Fuli; Wang, Zhilan; Jin, Shangzhong

    2008-03-01

    Calibration models of quantitative analysis of peanut oil content in ternary blended edible oil by near infrared spectroscopy were built using partial least square (PLS) regression. A total of 92 samples blended with three kinds of pure oil in different proportion (V/V) were prepared. Near infrared diffuse reflectance spectra of the samples were collected over 4 000 cm -1-10 000 cm -1 spectral region with a FT-NIR spectrometer. A calibration model of prediction to the peanut oil content was established with PLS using the original spectra and validated with leave-one-out cross validation method. The correlation coefficient and the RMSEC of the model were 0.9926 and 2.91%, respectively. The result showed that near infrared spectroscopy could be an ideal tool for fast determination to the peanut oil content in blended edible oil.

  13. Near infrared single photon avalanche detector with negative feedback and self quenching

    Science.gov (United States)

    Linga, Krishna; Yevtukhov, Yuriy; Liang, Bing

    2009-08-01

    We present the design and development of a negative feedback devices using the internal discrete amplifier approach used for the development of a single photon avalanche photodetector in the near infrared wavelength region. This new family of photodetectors with negative feedback, requiring no quenching mechanism using Internal Discrete Amplification (IDA) mechanism for the realization of very high gain and low excess noise factor in the visible and near infrared spectral regions, operates in the non-gated mode under a constant bias voltage. The demonstrated device performance far exceeds any available solid state Photodetectors in the near infrared wavelength range. The measured devices have Gain > 2×105, Excess noise factor Lidar, free space optical communication, 3D imaging, industrial and scientific instrumentation, night vision, quantum cryptography, and other military, defence and aerospace applications.

  14. Huanglongbing (citrus greening) detection using visible, near infrared and thermal imaging techniques.

    Science.gov (United States)

    Sankaran, Sindhuja; Maja, Joe Mari; Buchanon, Sherrie; Ehsani, Reza

    2013-02-06

    This study demonstrates the applicability of visible-near infrared and thermal imaging for detection of Huanglongbing (HLB) disease in citrus trees. Visible-near infrared (440-900 nm) and thermal infrared spectral reflectance data were collected from individual healthy and HLB-infected trees. Data analysis revealed that the average reflectance values of the healthy trees in the visible region were lower than those in the near infrared region, while the opposite was the case for HLB-infected trees. Moreover, 560 nm, 710 nm, and thermal band showed maximum class separability between healthy and HLB-infected groups among the evaluated visible-infrared bands. Similarly, analysis of several vegetation indices indicated that the normalized difference vegetation index (NDVI), Vogelmann red-edge index (VOG) and modified red-edge simple ratio (mSR) demonstrated good class separability between the two groups. Classification studies using average spectral reflectance values from the visible, near infrared, and thermal bands (13 spectral features) as input features indicated that an average overall classification accuracy of about 87%, with 89% specificity and 85% sensitivity could be achieved with classification models such as support vector machine for trees with symptomatic leaves.

  15. Huanglongbing (Citrus Greening Detection Using Visible, Near Infrared and Thermal Imaging Techniques

    Directory of Open Access Journals (Sweden)

    Reza Ehsani

    2013-02-01

    Full Text Available This study demonstrates the applicability of visible-near infrared and thermal imaging for detection of Huanglongbing (HLB disease in citrus trees. Visible-near infrared (440–900 nm and thermal infrared spectral reflectance data were collected from individual healthy and HLB-infected trees. Data analysis revealed that the average reflectance values of the healthy trees in the visible region were lower than those in the near infrared region, while the opposite was the case for HLB-infected trees. Moreover, 560 nm, 710 nm, and thermal band showed maximum class separability between healthy and HLB-infected groups among the evaluated visible-infrared bands. Similarly, analysis of several vegetation indices indicated that the normalized difference vegetation index (NDVI, Vogelmann red-edge index (VOG and modified red-edge simple ratio (mSR demonstrated good class separability between the two groups. Classification studies using average spectral reflectance values from the visible, near infrared, and thermal bands (13 spectral features as input features indicated that an average overall classification accuracy of about 87%, with 89% specificity and 85% sensitivity could be achieved with classification models such as support vector machine for trees with symptomatic leaves.

  16. Low-Resolution Near-infrared Stellar Spectra Observed by the Cosmic Infrared Background Experiment (CIBER)

    Science.gov (United States)

    Kim, Min Gyu; Lee, Hyung Mok; Arai, Toshiaki; Bock, James; Cooray, Asantha; Jeong, Woong-Seob; Kim, Seong Jin; Korngut, Phillip; Lanz, Alicia; Lee, Dae Hee; Lee, Myung Gyoon; Matsumoto, Toshio; Matsuura, Shuji; Nam, Uk Won; Onishi, Yosuke; Shirahata, Mai; Smidt, Joseph; Tsumura, Kohji; Yamamura, Issei; Zemcov, Michael

    2017-02-01

    We present near-infrared (0.8–1.8 μm) spectra of 105 bright ({m}J < 10) stars observed with the low-resolution spectrometer on the rocket-borne Cosmic Infrared Background Experiment. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination, which makes them a unique resource for near-infrared spectral calibration. Two-Micron All-Sky Survey photometry information is used to identify cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of the observed stars by comparing them with spectral templates from the Infrared Telescope Facility library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines.

  17. AU-FREDI - AUTONOMOUS FREQUENCY DOMAIN IDENTIFICATION

    Science.gov (United States)

    Yam, Y.

    1994-01-01

    typically done in ground structural testing, AU-FREDI identifies only the key transfer function parameters and uncertainty bounds that are necessary for on-line design and tuning of robust controllers. AU-FREDI's system identification algorithms are independent of the JPL-LSCL environment, and can easily be extracted and modified for use with input/output data files. The basic approach of AU-FREDI's system identification algorithms is to non-parametrically identify the sampled data in the frequency domain using either stochastic or sine-dwell input, and then to obtain a parametric model of the transfer function by curve-fitting techniques. A cross-spectral analysis of the output error is used to determine the additive uncertainty in the estimated transfer function. The nominal transfer function estimate and the estimate of the associated additive uncertainty can be used for robust control analysis and design. AU-FREDI's I/O data transfer routines are tailored to the environment of the CALTECH/ JPL-LSCL which included a special operating system to interface with the testbed. Input commands for a particular experiment (wideband, narrowband, or sine-dwell) were computed on-line and then issued to respective actuators by the operating system. The operating system also took measurements through displacement sensors and passed them back to the software for storage and off-line processing. In order to make use of AU-FREDI's I/O data transfer routines, a user would need to provide an operating system capable of overseeing such functions between the software and the experimental setup at hand. The program documentation contains information designed to support users in either providing such an operating system or modifying the system identification algorithms for use with input/output data files. It provides a history of the theoretical, algorithmic and software development efforts including operating system requirements and listings of some of the various special purpose subroutines

  18. Demultiplexing Visible and Near-Infrared Information in Single- Sensor Multispectral Imaging

    OpenAIRE

    Sadeghipoor, Zahra; Thomas, Jean-Baptiste; Süsstrunk, Sabine

    2016-01-01

    In this paper, we study a single-sensor imaging system that uses a multispectral filter array to spectrally sample the scene. Our system captures information in both visible and near-infrared bands of the electromagnetic spectrum. Due to manufacturing limitations, the visible filters in this system also transmit the NIR radiation. Similarly, visible light is transmitted by the NIR filter, leading to inaccurate mixed spectral measurements. We present an algorithm that resolves this issue by se...

  19. Photon sorting in the near field using subwavelength cavity arrays in the near-infrared

    Energy Technology Data Exchange (ETDEWEB)

    Mandel, Isroel M., E-mail: imandel@gc.cuny.edu; Lansey, Eli [Department of Physics, Graduate Center and City College of the City University of New York, New York 10016 (United States); Gollub, Jonah N.; Sarantos, Chris H.; Akhmechet, Roman [Phoebus Optoelectronics, New York, New York 10013 (United States); Golovin, Andrii B.; Crouse, David T. [Department of Electrical Engineering, The City College of New York, New York, New York 10031 (United States)

    2013-12-16

    A frequency selective metasurface capable of sorting photons in the near-infrared spectral range is designed, fabricated, and characterized. The metasurface, a periodic array of dielectric cylindrical cavities in a gold film, localizes and transmits light of two spectral frequency bands into spatially separated cavities, resulting in near-field light splitting. The design and fabrication methodologies of the metasurface are discussed. The transmittance and photon sorting properties of the designed structure is simulated numerically and the measured transmission is presented.

  20. Near-infrared spectroscopy is feasible to discriminate hazelnut cultivars

    Directory of Open Access Journals (Sweden)

    Elisabetta Stella

    2013-09-01

    Full Text Available The study demonstrated the feasibility of the near infrared (NIR spectroscopy use for hazelnut-cultivar sorting. Hazelnut spectra were acquired from 600 fruit for each cultivar sample, two diffuse reflectance spectra were acquired from opposite sides of the same hazelnut. Spectral data were transformed into absorbance before the computations. A different variety of spectral pretreatments were applied to extract characteristics for the classification. An iterative Linear Discriminant Analysis (LDA algorithm was used to select a relatively small set of variables to correctly classify samples. The optimal group of features selected for each test was analyzed using Partial Least Squares Discriminant Analysis (PLS-DA. The spectral region most frequently chosen was the 1980-2060 nm range, which corresponds to best differentiation performance for a total minimum error rate lower than 1.00%. This wavelength range is generally associated with stretching and bending of the N-H functional group of amino acids and proteins. The feasibility of using NIR Spectroscopy to distinguish different hazelnut cultivars was demonstrated.

  1. Breast Cancer Spatial Heterogeneity in Near-Infrared Spectra and the Prediction of Neoadjuvant Chemotherapy Response

    Science.gov (United States)

    Santoro, Ylenia

    Breast cancer accounts for more than 20% of all female cancers. Many of these patients receive neoadjuvant chemotherapy (NAC) to reduce the size of the tumor before surgery and to anticipate the efficacy of treatments for after the procedure. Breast cancer is a heterogeneous disease that comes in several clinical and histological forms. The prediction of the efficacy of chemotherapy would potentially select good candidates who would respond while excluding poor candidates who would not benefit from treatment. In this work we investigate the possibility of noninvasively predicting chemotherapy response prior to treatment based on optical biomarkers obtained from tumor spatial heterogeneities of spectral features measured using Diffuse Optical Spectroscopy. We describe an algorithm to calculate an index that characterizes spatial differences in broadband near-infrared absorption spectra of tumor-containing breast tissue. Patient-specific tumor spatial heterogeneities are visualized through a Heterogeneity Spectrum (HS). HS is a biomarker that can be attributed to different molecular distributions within the tumor. To classify lesion heterogeneities, we built a Heterogeneity Index (HI) from the HS by weighing specific absorption bands. It has been shown that NAC response is potentially related to tumor heterogeneity. Therefore, we correlate the HI obtained prior to treatment with the final response to NAC. In this thesis we also present a novel digital parallel frequency domain system for tissue imaging. The systems employs a supercontinuum laser with high brightness, and a photomultiplier with a large detection area, both allowing a deep penetration with extremely low power on the sample. The digital parallel acquisition is performed through the use of the Flimbox and it decreases the time required for standard serial systems that need to scan through all modulation frequencies. The all-digital acquisition removes analog noise, avoids the analog mixer and it does not

  2. A near-infrared magnetic aptasensor for Ochratoxin A based on near-infrared upconversion nanoparticles and magnetic nanoparticles.

    Science.gov (United States)

    Dai, Shaoliang; Wu, Shijia; Duan, Nuo; Wang, Zhouping

    2016-09-01

    A multiplexed, sensitive and specific detection method is highly desirable for the simultaneous detection of several pathogenic bacteria and bio-toxins. In our previous work, multicolor upconversion nanoparticles (UCNPs) via doping with various rare-earth ions to obtain well-separated emission peaks by means of a solvothermal method were synthesized and were successfully applied as luminescence labels in the detection of three pathogenic bacteria. One of the basic achievements of our group has been to establish that the key to increasing the number of simultaneous detection components is the preparation of more UCNPs, the emission peaks of which can be distinguished from each other. According to this vision, NaYF4:Yb0.2, Tm0.02 UCNPs were obtained via a thermal-decomposition protocol, which has a main near-infrared (NIR) UC emission at 804nm under 980nm excitation. The emission peak at 804nm was well-separated from the emission peaks of UCNPs we have reported at 477nm, 542nm, and 660nm. It means both the excitation and the emission of NaYF4:Yb0.2, Tm0.02 UCNPs are located in the NIR spectral range (NIR-to-NIR UC emission), the so-called biological window. This result establishes the basis of achieving simultaneous detection of four components. To confirm the analytical performance of this NaYF4:Yb0.2, Tm0.02 UCNPs, a novel near-infrared magnetic aptasensor for the detection of Ochratoxin A (OTA) was developed using the OTA aptamer-conjugated near-infrared upconversion nanoparticles (apt-UCNPs) and the complementary oligonucleotide-modified magnetic nanoparticles (cDNA-MNPs). The apt-UCNPs and cDNA-MNPs were hybridized to form a poly-network structure of MNP-UCNP nanocomposites. When the target OTA was introduced, the aptamer combined with the priority target and the cDNA-MNPs were replaced. The proposed method achieved a linear range between 0.01 and 100ngmL(-1), with a detection limit as low as 0.005ngmL(-1). Then, we successfully applied this method to measure

  3. Near-Infrared Intraoperative Chemiluminescence Imaging

    KAUST Repository

    Büchel, Gabriel E.

    2016-08-03

    Intraoperative imaging technologies recently entered the operating room, and their implementation is revolutionizing how physicians plan, monitor, and perform surgical interventions. In this work, we present a novel surgical imaging reporter system: intraoperative chemiluminescence imaging (ICI). To this end, we have leveraged the ability of a chemiluminescent metal complex to generate near-infrared light upon exposure to an aqueous solution of Ce4+ in the presence of reducing tissue or blood components. An optical camera spatially resolves the resulting photon flux. We describe the construction and application of a prototype imaging setup, which achieves a detection limit as low as 6.9pmolcm-2 of the transition-metal-based ICI agent. As a proof of concept, we use ICI for the invivo detection of our transition metal tracer following both systemic and subdermal injections. The very high signal-to-noise ratios make ICI an interesting candidate for the development of new intraoperative imaging technologies. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Probing brain oxygenation with near infrared spectroscopy

    CERN Document Server

    Gersten, Alexander; Raz, Amir; Fried, Robert

    2011-01-01

    The fundamentals of near infrared spectroscopy (NIRS) are reviewed. This technique allows to measure the oxygenation of the brain tissue. The particular problems involved in detecting regional brain oxygenation (rSO2) are discussed. The dominant chromophore (light absorber) in tissue is water. Only in the NIR light region of 650-1000 nm, the overall absorption is sufficiently low, and the NIR light can be detected across a thick layer of tissues, among them the skin, the scull and the brain. In this region, there are many absorbing light chromophores, but only three are important as far as the oxygenation is concerned. They are the hemoglobin (HbO2), the deoxy-hemoglobin (Hb) and cytochrome oxidase (CtOx). In the last 20 years there was an enormous growth in the instrumentation and applications of NIRS. . The devices that were used in our experiments were : Somanetics's INVOS Brain Oximeter (IBO) and Toomim's HEG spectrophotometer. The performances of both devices were compared including their merits and draw...

  5. Near-Infrared Diffuse Optical Tomography

    Directory of Open Access Journals (Sweden)

    A. H. Hielscher

    2002-01-01

    Full Text Available Diffuse optical tomography (DOT is emerging as a viable new biomedical imaging modality. Using near-infrared (NIR light, this technique probes absorption as well as scattering properties of biological tissues. First commercial instruments are now available that allow users to obtain cross-sectional and volumetric views of various body parts. Currently, the main applications are brain, breast, limb, joint, and fluorescence/bioluminescence imaging. Although the spatial resolution is limited when compared with other imaging modalities, such as magnetic resonance imaging (MRI or X-ray computerized tomography (CT, DOT provides access to a variety of physiological parameters that otherwise are not accessible, including sub-second imaging of hemodynamics and other fast-changing processes. Furthermore, DOT can be realized in compact, portable instrumentation that allows for bedside monitoring at relatively low cost. In this paper, we present an overview of current state-of-the -art technology, including hardware and image-reconstruction algorithms, and focus on applications in brain and joint imaging. In addition, we present recent results of work on optical tomographic imaging in small animals.

  6. A near-infrared confocal scanner

    Science.gov (United States)

    Lee, Seungwoo; Yoo, Hongki

    2014-06-01

    In the semiconductor industry, manufacturing of three-dimensional (3D) packages or 3D integrated circuits is a high-performance technique that requires combining several functions in a small volume. Through-silicon vias, which are vertical electrical connections extending through a wafer, can be used to direct signals between stacked chips, thus increasing areal density by stacking and connecting multiple patterned chips. While defect detection is essential in the semiconductor manufacturing process, it is difficult to identify defects within a wafer or to monitor the bonding results between bonded surfaces because silicon and many other semiconductor materials are opaque to visible wavelengths. In this context, near-infrared (NIR) imaging is a promising non-destructive method to detect defects within silicon chips, to inspect bonding between chips and to monitor the chip alignment since NIR transmits through silicon. In addition, a confocal scanner provides high-contrast, optically-sectioned images of the specimen due to its ability to reject out-of-focus noise. In this study, we report an NIR confocal scanner that rapidly acquires high-resolution images with a large field of view through silicon. Two orthogonal line-scanning images can be acquired without rotating the system or the specimen by utilizing two orthogonally configured resonant scanning mirrors. This NIR confocal scanner can be efficiently used as an in-line inspection system when manufacturing semiconductor devices by rapidly detecting defects on and beneath the surface.

  7. Near infrared spectroscopy in natural products analysis.

    Science.gov (United States)

    Cozzolino, Daniel

    2009-06-01

    Several medicinal and herbal plants properties are related to individual compounds such as essential oils, terpenoids, flavonoids, which are present in natural products in low concentrations (e. g., ppm or ppb). For many years, the use of classical separation and chromatographic and spectrometric techniques such as high performance liquid chromatography (HPLC), gas chromatography (GC), liquid chromatography (LC) and mass spectrometry (MS) were initially used for the elucidation of isolated compounds from different plant matrices. Spectroscopic techniques in the infrared (IR) wavelength region of the electromagnetic spectrum have been used in the food industry to monitor and evaluate the composition of foods. Although Herschel discovered light in the near-infrared (NIR) region as early as 1800, most spectroscopists of the first half of the last century ignored it, in the belief that it lacked any analytical interest. However, during the last 40 years NIR spectroscopy has become one of the most attractive and used methods for analysis. This mini-review highlights recent applications of NIR spectroscopy to the qualitative and quantitative analysis of plant natural products.

  8. TIRSPEC : TIFR Near Infrared Spectrometer and Imager

    CERN Document Server

    Ninan, J P; Ghosh, S K; D'Costa, S L A; Naik, M B; Poojary, S S; Sandimani, P R; Meshram, G S; Jadhav, R B; Bhagat, S B; Gharat, S M; Bakalkar, C B; Prabhu, T P; Anupama, G C; Toomey, D W

    2014-01-01

    We describe the TIFR Near Infrared Spectrometer and Imager (TIRSPEC) designed and built in collaboration with M/s. Mauna Kea Infrared LLC, Hawaii, USA, now in operation on the side port of the 2-m Himalayan Chandra Telescope (HCT), Hanle (Ladakh), India at an altitude of 4500 meters above mean sea level. The TIRSPEC provides for various modes of operation which include photometry with broad and narrow band filters, spectrometry in single order mode with long slits of 300" length and different widths, with order sorter filters in the Y, J, H and K bands and a grism as the dispersing element as well as a cross dispersed mode to give a coverage of 1.0 to 2.5 microns at a resolving power R of ~1200. The TIRSPEC uses a Teledyne 1024 x 1024 pixel Hawaii-1 PACE array detector with a cutoff wavelength of 2.5 microns and on HCT, provides a field of view of 307" x 307" with a plate scale of 0.3"/pixel. The TIRSPEC was successfully commissioned in June 2013 and the subsequent characterization and astronomical observatio...

  9. Near-Infrared Grating Spectrometer for Mobile Phone Applications.

    Science.gov (United States)

    Pügner, Tino; Knobbe, Jens; Grüger, Heinrich

    2016-05-01

    Near-infrared (NIR) spectroscopy is a well-established technique for the chemical analysis of organic and inorganic matter. Accordingly, spectroscopic instrumentation of different complexity has been developed and is currently commercially available. However, there are an increasing number of new mobile applications that have come into focus and that cannot be addressed by the existing technology due to size and cost. Therefore, a new miniaturized scanning grating spectrometer for NIR spectroscopy has been developed at Fraunhofer IPMS. It is based on micro-electro-mechanical systems (MEMS) technology, and has been designed to meet the requirements for mobile application, regarding spectral range, resolution, overall size, robustness, and cost. The MEMS spectrometer covers a spectral range from 950 nm to 1900 nm at a resolution of 10 nm. The instrument is extremely small and has a volume of only 2.1 cm(3) Therefore, it is well suited for integration, even into a mobile phone. A first sample of the new spectrometer has been manufactured and put into operation. The results of a series of test measurements are in good agreement with the requirements and specifications.

  10. Standardization of near infrared spectra measured on multi-instrument.

    Science.gov (United States)

    Liu, Yan; Cai, Wensheng; Shao, Xueguang

    2014-07-11

    Calibration model transfer is essential for practical applications of near infrared (NIR) spectroscopy because the measurements of the spectra may be performed on different instruments and the difference between the instruments must be corrected. An approach for calibration transfer based on alternating trilinear decomposition (ATLD) algorithm is proposed in this work. From the three-way spectral matrix measured on different instruments, the relative intensity of concentration, spectrum and instrument is obtained using trilinear decomposition. Because the relative intensity of instrument is a reflection of the spectral difference between instruments, the spectra measured on different instruments can be standardized by a correction of the coefficients in the relative intensity. Two NIR datasets of corn and tobacco leaf samples measured with three instruments are used to test the performance of the method. The results show that, for both the datasets, the spectra measured on one instrument can be correctly predicted using the partial least squares (PLS) models built with the spectra measured on the other instruments.

  11. Degradation of near infrared and shortwave infrared imager performance due to atmospheric scattering of diffuse night illumination.

    Science.gov (United States)

    Vollmerhausen, Richard

    2013-07-20

    On moonless nights, airglow is the primary source of natural ground illumination in the near infrared and shortwave infrared spectral bands. Therefore, night vision imagers operating in these spectral bands view targets that are diffusely illuminated. Aerosol scattering of diffuse airglow illumination causes atmospheric path radiance and that radiance causes increased imager noise. These phenomena and their quantification are described in this paper.

  12. Systematic optimization of MRI guided near infrared diffuse optical spectroscopy in breast

    Science.gov (United States)

    Zhao, Yan; Mastanduno, Michael A.; Jiang, Shudong; El-Ghussein, Fadi; Xu, Junqing; Gui, Jiang; Pogue, Brian W.; Paulsen, Keith D.

    2015-03-01

    A hybrid frequency domain (FD)-continuous wave (CW) MRI/NIRS system was validated in a clinical trial involving patients with at least ACR 4 radiologic findings in Xi'an, China. In this study, MRI guided nonlinear iterative reconstruction of near-infrared spectroscopy (NIRS) images with limited phase data is investigated. In addition, a systematic optimization of the system hardware design has been conducted as well. We are able to get less than 3% variation in tumor contrast to the surrounding normal tissue, by reducing the number of FD detectors from 16 to 6, showing the potential of reducing the FD detectors. Furthermore, a lookup table of the scattering properties has been made by averaging four MRI-identified breast density groups. By using this look-up table for the patient with the noisy phase data, similar AUCs and p-values are achieved for differentiating the malignant from benign patients.

  13. Applicability of near-infrared spectroscopy to measure cerebral autoregulation noninvasively in neonates: a validation study in piglets

    DEFF Research Database (Denmark)

    Holst Hahn, Gitte; Heiring, Christian; Pryds, Ole;

    2011-01-01

    Impaired cerebral autoregulation (CA) is common and is associated with brain damage in sick neonates. Frequency analysis using spontaneous changes in arterial blood pressure (ABP) and cerebral near-infrared spectroscopy (NIRS) has been used to measure CA in several clinical studies. Coherence...... of the NIRS and ABP signals (i.e. correlation in the frequency domain) detects impairment of CA, whereas gain (i.e. magnitude of ABP variability passing from systemic to cerebral circulation) estimates the degree of this impairment. So far, however, this method has not been validated. In 12 newborn piglets...

  14. [Rapid determination of fatty acids in soybean oils by transmission reflection-near infrared spectroscopy].

    Science.gov (United States)

    Song, Tao; Zhang, Feng-ping; Liu, Yao-min; Wu, Zong-wen; Suo, You-rui

    2012-08-01

    In the present research, a novel method was established for determination of five fatty acids in soybean oil by transmission reflection-near infrared spectroscopy. The optimum conditions of mathematics model of five components (C16:0, C18:0, C18:1, C18:2 and C18:3) were studied, including the sample set selection, chemical value analysis, the detection methods and condition. Chemical value was analyzed by gas chromatography. One hundred fifty eight samples were selected, 138 for modeling set, 10 for testing set and 10 for unknown sample set. All samples were placed in sample pools and scanned by transmission reflection-near infrared spectrum after sonicleaning for 10 minute. The 1100-2500 nm spectral region was analyzed. The acquisition interval was 2 nm. Modified partial least square method was chosen for calibration mode creating. Result demonstrated that the 1-VR of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.8839, 0.5830, 0.9001, 0.9776 and 0.9596, respectively. And the SECV of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.42, 0.29, 0.83, 0.46 and 0.21, respectively. The standard error of the calibration (SECV) of five fatty acids between the reference value of testing sample set and the near infrared spectrum predictive value were 0.891, 0.790, 0.900, 0.976 and 0.942, respectively. It was proved that the near infrared spectrum predictive value was linear with chemical value and the mathematical model established for fatty acids of soybean oil was feasible. For validation, 10 unknown samples were selected for analysis by near infrared spectrum. The result demonstrated that the relative standard deviation between predict value and chemical value was less than 5.50%. That was to say that transmission reflection-near infrared spectroscopy had a good veracity in analysis of fatty acids of soybean oil.

  15. The Nuclear Near-Infrared Spectral Properties of Nearby Galaxies

    CERN Document Server

    Mason, R E; Martins, L; Riffel, R; Martin, O Gonzalez; Almeida, C Ramos; Dutra, D Ruschel; Ho, L C; Thanjavur, K; Flohic, H; Alonso-Herrero, A; Lira, P; McDermid, R; Riffel, R A; Schiavon, R P; Winge, C; Hoenig, M D; Perlman, E

    2015-01-01

    We present spectra of the nuclear regions of 50 nearby (D = 1 - 92 Mpc, median = 20 Mpc) galaxies of morphological types E to Sm. The spectra, obtained with the Gemini Near-IR Spectrograph on the Gemini North telescope, cover a wavelength range of approximately 0.85-2.5 microns at R~1300--1800. There is evidence that most of the galaxies host an active galactic nucleus (AGN), but the range of AGN luminosities (log (L2-10 keV [erg/s]) = 37.0-43.2) in the sample means that the spectra display a wide variety of features. Some nuclei, especially the Seyferts, exhibit a rich emission-line spectrum. Other objects, in particular the type 2 Low Ionisation Nuclear Emission Region galaxies, show just a few, weak emission lines, allowing a detailed view of the underlying stellar population. These spectra display numerous absorption features sensitive to the stellar initial mass function, as well as molecular bands arising in cool stars, and many other atomic absorption lines. We compare the spectra of subsets of galaxie...

  16. Prostate Cancer Detection Using Near Infrared Spectral Polarization Imaging

    Science.gov (United States)

    2005-07-01

    Distribution Unlimited 13. SUPPLEMENTARY NOTES Original contains color plates: ALL DTIC reproductions will be in black and white 14. ABSTRACT Abstract follows...flower and the anthocyanin pigments extracted from Streptocarpus holstii and Anthuriumn andreanum were performed in our lab [13]. The results show that the...P. Sekuler and R. R. Alfano, "Picosecond fluorescence kinetics and polarization anisotropy from anthocyanin pigment", Photobiochemistry and

  17. An atlas of bright star spectra in the near infrared from Cassini-VIMS

    CERN Document Server

    Stewart, Paul N; Nicholson, Philip D; Sloan, G C; Hedman, Matthew M

    2015-01-01

    We present the Cassini Atlas Of Stellar Spectra (CAOSS), comprised of near-infrared low-resolution spectra of bright stars recovered from space-based observations by the Cassini spacecraft. The 65 stellar targets in the atlas are predominately M, K and S giants. However it also contains spectra of other bright nearby stars including carbon stars and main sequence stars from A to F. The spectra presented are free of all spectral contamination caused by the Earth's atmosphere, including the detrimental telluric molecular bands which put parts of the near-infrared spectrum out of reach of terrestrial observations. With a single instrument, a spectro-photometric dataset is recovered that spans the near-infrared from 0.8 to 5.1 microns with spectral resolution ranging from R=53.5 to R=325. Spectra have been calibrated into absolute flux units after careful characterisation of the instrumental spectral efficiency. Spectral energy distributions for most stars match closely with literature values. All final data prod...

  18. AN ATLAS OF BRIGHT STAR SPECTRA IN THE NEAR-INFRARED FROM CASSINI-VIMS

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, Paul N.; Tuthill, Peter G. [Sydney Institute for Astronomy, School of Physics, The University of Sydney, NSW 2006 (Australia); Nicholson, Philip D. [Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States); Sloan, G. C. [Cornell Center for Astrophyics and Planetary Science, Cornell University, Ithaca, NY 14853 (United States); Hedman, Matthew M., E-mail: p.stewart@physics.usyd.edu.au [Department of Physics, University of Idaho, Moscow, ID 83844 (United States)

    2015-12-15

    We present the Cassini Atlas Of Stellar Spectra (CAOSS), comprised of near-infrared, low-resolution spectra of bright stars recovered from space-based observations by the Cassini spacecraft. The 65 stellar targets in the atlas are predominately M, K, and S giants. However, it also contains spectra of other bright nearby stars including carbon stars and main-sequence stars from A to F. The spectra presented are free of all spectral contamination caused by the Earth's atmosphere, including the detrimental telluric molecular bands which put parts of the near-infrared spectrum out of reach of terrestrial observations. With a single instrument, a spectro-photometric data set is recovered that spans the near-infrared from 0.8 to 5.1 μm with spectral resolution ranging from R = 53.5 to R = 325. Spectra have been calibrated into absolute flux units after careful characterization of the instrumental spectral efficiency. Spectral energy distributions for most stars match closely with literature values. All final data products have been made available online.

  19. Communicating oscillatory networks: frequency domain analysis

    Directory of Open Access Journals (Sweden)

    Ihekwaba Adaoha EC

    2011-12-01

    Full Text Available Abstract Background Constructing predictive dynamic models of interacting signalling networks remains one of the great challenges facing systems biology. While detailed dynamical data exists about individual pathways, the task of combining such data without further lengthy experimentation is highly nontrivial. The communicating links between pathways, implicitly assumed to be unimportant and thus excluded, are precisely what become important in the larger system and must be reinstated. To maintain the delicate phase relationships between signals, signalling networks demand accurate dynamical parameters, but parameters optimised in isolation and under varying conditions are unlikely to remain optimal when combined. The computational burden of estimating parameters increases exponentially with increasing system size, so it is crucial to find precise and efficient ways of measuring the behaviour of systems, in order to re-use existing work. Results Motivated by the above, we present a new frequency domain-based systematic analysis technique that attempts to address the challenge of network assembly by defining a rigorous means to quantify the behaviour of stochastic systems. As our focus we construct a novel coupled oscillatory model of p53, NF-kB and the mammalian cell cycle, based on recent experimentally verified mathematical models. Informed by online databases of protein networks and interactions, we distilled their key elements into simplified models containing the most significant parts. Having coupled these systems, we constructed stochastic models for use in our frequency domain analysis. We used our new technique to investigate the crosstalk between the components of our model and measure the efficacy of certain network-based heuristic measures. Conclusions We find that the interactions between the networks we study are highly complex and not intuitive: (i points of maximum perturbation do not necessarily correspond to points of maximum

  20. Simultaneous optical and near-infrared linear spectropolarimetry of the earthshine

    CERN Document Server

    Miles-Páez, P A; Osorio, M R Zapatero

    2014-01-01

    Aims: We aim to extend our current observational understanding of the integrated planet Earth spectropolarimetry from the optical to the near-infrared wavelengths. Major biomarkers like O$_{\\rm 2}$ and water vapor are strong flux absorbents in the Earth atmosphere and some linear polarization of the reflected stellar light is expected to occur at these wavelengths. Methods: Simultaneous optical ($0.4-0.9$ $\\mu$m) and near-infrared ($0.9-2.3$ $\\mu$m) linear spectropolarimetric data of the earthshine were acquired by observing the nightside of the waxing Moon. The data have sufficient spectral resolution (2.51 nm in the optical, and 1.83 and 2.91 nm in the near-infrared) to resolve major molecular species present in the Earth atmosphere. Results: We find the highest values of linear polarization ($\\ge 10\\%$) at the bluest wavelengths, which agrees with the literature. Linear polarization intensity steadily decreases towards red wavelengths reaching a nearly flat value beyond $\\sim$0.8 $\\mu$m. In the near-infrar...

  1. Time-series surveys and pulsating stars: The near-infrared perspective

    Science.gov (United States)

    Matsunaga, Noriyuki

    2017-09-01

    The purpose of this review is to discuss the advantages and problems of nearinfrared surveys in observing pulsating stars in the Milky Way. One of the advantages of near-infrared surveys, when compared to optical counterparts, is that the interstellar extinction is significantly smaller. As we see in this review, a significant volume of the Galactic disk can be reached by infrared surveys but not by optical ones. Towards highly obscured regions in the Galactic mid-plane, however, the interstellar extinction causes serious problems even with near-infrared data in understanding the observational results. After a review on previous and current near-infrared surveys, we discuss the effects of the interstellar extinction in optical (including Gaia) to near-infrared broad bands based on a simple calculation using synthetic spectral energy distribution. We then review the recent results on classical Cepheids towards the Galactic center and the bulge, as a case study, to see the impact of the uncertainty in the extinction law. The extinction law, i.e. the wavelength dependency of the extinction, is not fully characterized, and its uncertainty makes it hard to make the correction. Its characterization is an urgent task in order to exploit the outcomes of ongoing large-scale surveys of pulsating stars, e.g. for drawing a map of pulsating stars across the Galactic disk.

  2. Bilateral connectivity in the somatosensory region using near-infrared spectroscopy (NIRS) by wavelet coherence

    Science.gov (United States)

    Fernandez Rojas, Raul; Huang, Xu; Ou, Keng-Liang

    2016-12-01

    Near-infrared spectroscopy (NIRS) has been used in medical imaging to obtain oxygenation and hemodynamic response in the cerebral cortex. This technique has been applied in cortical activation detection and functional connectivity in brain research. Despite some advances in functional connectivity, most of the studies have focused on the prefrontal cortex and little has been done to study the somatosensory region (S1). For that reason, the aim of our present study is to assess bilateral connectivity in the somatosensory region by using NIRS and noxious stimulation. Eleven healthy subjects were investigated using near-infrared spectroscopy during an acupuncture stimulation procedure to safely induce pain in subjects. A multiscale analysis based on wavelet transform coherence (WTC) was designed to assess the functional connectivity of corresponding channel pairs within the left and right s1 region. The cortical activation in the somatosensory region was higher after the acupuncture stimulation, which was consistent with similar studies. The coherence in time-frequency domain between homologous signals generated by contralateral channel pairs revealed two main periods (3.2 s and 12.8 s) with high coherence. Based on the WTC analysis, it was also found that the coherence increase in these periods was task-related. This study contributes to the research field to investigate cerebral hemodynamic response of pain perception using NIRS and demonstrates the use of wavelet transform as a method to investigate functional lateralization in the cerebral cortex.

  3. Time delay measurement in the frequency domain

    Energy Technology Data Exchange (ETDEWEB)

    Durbin, Stephen M., E-mail: durbin@purdue.edu; Liu, Shih-Chieh [Purdue University, West Lafayette, IN 47907 (United States); Dufresne, Eric M.; Li, Yuelin; Wen, Haidan [Argonne National Laboratory, Argonne, IL 60439 (United States)

    2015-08-06

    A simple frequency domain technique for determining the time delay between laser pump and X-ray probe pulses achieves 1 ps resolution even for ∼100 ps synchrotron pulses, permitting improved pump–probe characterization of ultrafast processes. Pump–probe studies at synchrotrons using X-ray and laser pulses require accurate determination of the time delay between pulses. This becomes especially important when observing ultrafast responses with lifetimes approaching or even less than the X-ray pulse duration (∼100 ps). The standard approach of inspecting the time response of a detector sensitive to both types of pulses can have limitations due to dissimilar pulse profiles and other experimental factors. Here, a simple alternative is presented, where the frequency response of the detector is monitored versus time delay. Measurements readily demonstrate a time resolution of ∼1 ps. Improved precision is possible by simply extending the data acquisition time.

  4. Realization of Thermal Inertia in Frequency Domain

    Directory of Open Access Journals (Sweden)

    Boe-Shong Hong

    2014-02-01

    Full Text Available To realize the lagging behavior in heat conduction observed in these two decades, this paper firstly theoretically excludes the possibility that the underlying thermal inertia is a result of the time delay in heat diffusion. Instead, we verify in experiments the electro-thermal analogy, wherein the thermal inertial is parameterized by thermal inductance that formulates hyperbolic heat-conduction. The thermal hyperbolicity exhibits a special frequency response in Bode plot, wherein the amplitude ratios is kept flat after crossing some certain frequency, as opposed to Fourier heat-conduction. We apply this specialty to design an instrument that reliably identifies thermal inductances of some materials in frequency domain. The instrument is embedded with a DSP-based frequency synthesizer capable of modulating frequencies in utmost high-resolution. Thermal inertia implies a new possibility for energy storage in analogy to inductive energy storage in electricity or mechanics.

  5. Non-destructive prediction of quality of intact apple using near infrared spectroscopy

    OpenAIRE

    2010-01-01

    Potential of near infrared spectroscopy (NIRS) in the wavelength range of 900–1700 nm for determination of sweetness (total soluble solids, TSS); sourness (acidity) and their ratio for 5 cultivars of apple was studied. Partial least square and multiple linear regression (MLR) employing pre-processing techniques were carried out. MLR models were found to be the best for prediction after treating the spectral data with multiple scatter correction technique. The multiple correlation coefficients...

  6. Near infrared iron absorption bands: Applications to geologic mapping and mineral exploration

    Science.gov (United States)

    Rowan, L. C.

    1972-01-01

    A spectroscopic analysis of the difference in reflectance of iron-rich and iron-poor minerals was made. Attempts were made to use these minima contrast in geological mapping and metallic mineral exploration of large areas from near infrared and visible satellite images. Data cover pertinent laboratory spectroscopic investigations, applications of spectral differences to the discrimination of two important metamorphic rock types, and mineral exploration by aircraft in Beartooth Mountains, Montana.

  7. Perylene anhydride fused porphyrins as near-infrared sensitizers for dye-sensitized solar cells

    KAUST Repository

    Jiao, Chongjun

    2011-07-15

    Two perylene anhydride fused porphyrins 1 and 2 have been synthesized and employed successfully in dye-sensitized solar cells (DSCs). Both compounds showed broad incident monochromatic photon-to-current conversion efficiency spectra covering the entire visible spectral region and even extending into the near-infrared (NIR) region up to 1000 nm, which is impressive for ruthenium-free dyes in DSCs. © 2011 American Chemical Society.

  8. Electro-optic sampling of near-infrared waveforms

    Science.gov (United States)

    Keiber, Sabine; Sederberg, Shawn; Schwarz, Alexander; Trubetskov, Michael; Pervak, Volodymyr; Krausz, Ferenc; Karpowicz, Nicholas

    2016-03-01

    Access to the complete electric field evolution of a laser pulse is essential for attosecond science in general, and for the scrutiny and control of electron phenomena in solid-state physics specifically. Time-resolved field measurements are routine in the terahertz spectral range, using electro-optic sampling (EOS), photoconductive switches and field-induced second harmonic generation. EOS in particular features outstanding sensitivity and ease of use, making it the basis of time-resolved spectroscopic measurements for studying charge carrier dynamics and active optical devices. In this Letter, we show that careful optical filtering allows the bandwidth of this technique to be extended to wavelengths as short as 1.2 μm (230 THz) with half-cycle durations 2.3 times shorter than the sampling pulse. In a proof-of-principle application, we measure the influence of optical parametric amplification (OPA) on the electric field dynamics of a few-cycle near-infrared (NIR) pulse.

  9. Adaptive optics near infrared integral field spectroscopy of NGC 2992

    CERN Document Server

    Friedrich, S; Hicks, E K S; Engel, H; Müller-Sánchez, F; Genzel, R; Tacconi, L J

    2010-01-01

    NGC 2992 is an intermediate Seyfert 1 galaxy showing outflows on kilo parsec scales which might be due either to AGN or starburst activity. We therefore aim at investigating its central region for a putative starburst in the past and its connection to the AGN and the outflows. Observations were performed with the adaptive optics near infrared integral field spectrograph SINFONI on the VLT, complemented by longslit observations with ISAAC on the VLT, as well as N- and Q-band data from the Spitzer archive. The spatial and spectral resolutions of the SINFONI data are 50 pc and 83 km/s, respectively. The field of view of 3" x 3" corresponds to 450 pc x 450 pc. Br_gamma equivalent width and line fluxes from PAHs were compared to stellar population models to constrain the age of the putative recent star formation. A simple geometric model of two mutually inclined disks and an additional cone to describe an outflow was developed to explain the observed complex velocity field in H_2 1-0S(1). The morphologies of the B...

  10. Rapid analysis of Radix puerariae by near-infrared spectroscopy.

    Science.gov (United States)

    Lau, Ching-Ching; Chan, Chi-On; Chau, Foo-Tim; Mok, Daniel Kam-Wah

    2009-03-13

    A new, rapid analytical method using near-infrared spectroscopy (NIRS) was developed to differentiate two species of Radix puerariae (GG), Pueraria lobata (YG) and Pueraria thomsonii (FG), and to determine the contents of puerarin, daidzin and total isoflavonoid in the samples. Five isoflavonoids, puerarin, daidzin, daidzein, genistin and genistein were analyzed simultaneously by high-performance liquid chromatography-diode array detection (HPLC-DAD). The total isoflavonoid content was exploited as critical parameter for successful discrimination of the two species. Scattering effect and baseline shift in the NIR spectra were corrected and the spectral features were enhanced by several pre-processing methods. By using linear discriminant analysis (LDA) and soft independent modeling class analogy (SIMCA), samples were separated successfully into two different clusters corresponding to the two GG species. Furthermore, sensitivity and specificity of the classification models were determined to evaluate the performance. Finally, partial least squares (PLS) regression was used to build the correlation models. The results showed that the correlation coefficients of the prediction models are R=0.970 for the puerarin, R=0.939 for daidzin and R=0.969 for total isoflavonoid. The outcome showed that NIRS can serve as routine screening in the quality control of Chinese herbal medicine (CHM).

  11. Red/near-infrared reflectance sensor system for detecting plants

    Science.gov (United States)

    Von Bargen, Kenneth; Meyer, George E.; Mortensen, David A.; Merritt, Steven J.; Woebbecke, David M.

    1993-05-01

    Growing plants, soil types, and surfaces and residues on a soil surface have distinct natural light reflectances. These reflectance characteristics have been determined using current spectroradiometry technology. Detection of plants is possible based upon the distinct reflectance characteristics of plants, soil, and residues. An optical plant reflectance sensor was developed which utilizes a pair of red and near infrared sensitive photodetectors to measure the radiancy from the plant and soil. Another pair of sensors measures radiancy from a highly radiant reference surface to accommodate varying intensities of the natural light. The ratio of the target and reference radiancies is the target reflectance. Optical filters were used to select the spectral bandwidth sensitivities for the red and NIR photodetectors. The reflectance values were digitized for incorporation into a normalized difference index in order to provide a stronger indication that a live plant is present within the field of view of the sensor. This sensor system was combined with a microcontroller for activating a solenoid controlled spray nozzle on a single unit prototype spot agricultural sprayer.

  12. The near-infrared spectrum of ethynyl radical

    CERN Document Server

    Le, Anh T; Sears, Trevor J

    2016-01-01

    Transient diode laser absorption spectroscopy has been used to measure three strong vibronic bands in the near infrared spectrum of the C$_2$H, ethynyl, radical not previously observed in the gas phase. The radical was produced by ultraviolet excimer laser photolysis of either acetylene or (1,1,1)-trifluoropropyne in a slowly flowing sample of the precursor diluted in inert gas, and the spectral resolution was Doppler-limited. The character of the upper states was determined from the rotational and fine structure in the observed spectra and assigned by measurement of ground state rotational combination differences. The upper states include a $^2\\Sigma ^+$ state at 6696 cm$^{-1}$, a second $^2\\Sigma ^+$ state at 7088 cm$^{-1}$, and a $^2\\Pi$ state at 7110 cm$^{-1}$. By comparison with published calculations (R. Tarroni and S. Carter, \\textit{J. Chem. Phys} \\textbf{119}, 12878 (2003) and \\textit{Mol. Phys}. \\textbf{102}, 2167 (2004)), the vibronic character of these levels was also assigned. The observed states...

  13. Advances in Organic Near-Infrared Materials and Emerging Applications.

    Science.gov (United States)

    Qi, Ji; Qiao, Wenqiang; Wang, Zhi Yuan

    2016-06-01

    Much progress has been made in the field of research on organic near-infrared materials for potential applications in photonics, communications, energy, and biophotonics. This account mainly describes our research work on organic near-infrared materials; in particular, donor-acceptor small molecules, organometallics, and donor-acceptor polymers with the bandgaps less than 1.2 eV. The molecular designs, structure-property relationships, unique near-infrared absorption, emission and color/wavelength-changing properties, and some emerging applications are discussed.

  14. Nonlinear wave equation in frequency domain: accurate modeling of ultrafast interaction in anisotropic nonlinear media

    DEFF Research Database (Denmark)

    Guo, Hairun; Zeng, Xianglong; Zhou, Binbin

    2013-01-01

    We interpret the purely spectral forward Maxwell equation with up to third-order induced polarizations for pulse propagation and interactions in quadratic nonlinear crystals. The interpreted equation, also named the nonlinear wave equation in the frequency domain, includes quadratic and cubic...

  15. Precise radial velocities in the near infrared

    Science.gov (United States)

    Redman, Stephen L.

    Since the first detection of a planet outside our Solar System byWolszczan & Frail (1992), over 500 exoplanets have been found to date2, none of which resemble the Earth. Most of these planets were discovered by measuring the radial velocity (hereafter, RV) of the host star, which wobbles under the gravitational influence of any existing planetary companions. However, this method has yet to achieve the sub-m/s precision necessary to detect an Earth-mass planet in the Habitable Zone (the region around a star that can support liquid water; hereafter, HZ) (Kasting et al. 1993) around a Solar-type star. Even though Kepler (Borucki et al. 2010) has announced several Earth-sized HZ candidates, these targets will be exceptionally difficult to confirm with current astrophysical spectrographs (Borucki et al. 2011). The fastest way to discover and confirm potentiallyhabitable Earth-mass planets is to observe stars with lower masses - in particular, late M dwarfs. While M dwarfs are readily abundant, comprising some 70% of the local stellar population, their low optical luminosity presents a formidable challenge to current optical RV instruments. By observing in the near-infrared (hereafter, NIR), where the flux from M dwarfs peaks, we can potentially reach low RV precisions with significantly less telescope time than would be required by a comparable optical instrument. However, NIR precision RV measurements are a relatively new idea and replete with challenges: IR arrays, unlike CCDs, are sensitive to the thermal background; modal noise is a bigger issue in the NIR than in the optical; and the NIR currently lacks the calibration sources like the very successful thorium-argon (hereafter, ThAr) hollow-cathode lamp and Iodine gas cell of the optical. The PSU Pathfinder (hereafter, Pathfinder) was designed to explore these technical issues with the intention of mitigating these problems for future NIR high-resolution spectrographs, such as the Habitable-Zone Planet Finder (HZPF

  16. Deep near-infrared survey of the Southern Sky (DENIS)

    Science.gov (United States)

    Deul, E.

    1992-01-01

    DENIS (Deep Near-Infrared Survey of the Southern Sky) will be the first complete census of astronomical sources in the near-infrared spectral range. The challenges of this novel survey are both scientific and technical. Phenomena radiating in the near-infrared range from brown dwarfs to galaxies in the early stages of cosmological evolution, the scientific exploitation of data relevant over such a wide range requires pooling expertise from several of the leading European astronomical centers. The technical challenges of a project which will provide an order of magnitude more sources than given by the IRAS space mission, and which will involve advanced data-handling and image-processing techniques, likewise require pooling of hardware and software resources, as well as of human expertise. The DENIS project team is composed of some 40 scientists, computer specialists, and engineers located in 5 European Community countries (France, Germany, Italy, The Netherlands, and Spain), with important contributions from specialists in Australia, Brazil, Chile, and Hungary. DENIS will survey the entire southern sky in 3 colors, namely in the I band at a wavelength of 0.8 micron, in the 1.25 micron J band, and in the 2.15 micron K' band. The sensitivity limits will be 18th magnitude in the I band, 16th in the J band, and 14.5th in the K' band. The angular resolution achieved will be 1 arcsecond in the I band, and 3.0 arcseconds in the J and K' bands. The European Southern Observatory 1 m telescope on La Silla will be dedicated to survey use during operations expected to last four years, commencing in late 1993. DENIS aims to provide the astronomical community with complete digitized infrared images of the full southern sky and a catalogue of extracted objects, both of the best quality and in readily accessible form. This will be achieved through dedicated software packages and specialized catalogues, and with assistance from the Leiden and Paris Data Analysis Centers. The data

  17. Cerebral near infrared spectroscopy oximetry in extremely preterm infants

    DEFF Research Database (Denmark)

    Hyttel-Sorensen, Simon; Pellicer, Adelina; Alderliesten, Thomas

    2015-01-01

    OBJECTIVE: To determine if it is possible to stabilise the cerebral oxygenation of extremely preterm infants monitored by cerebral near infrared spectroscopy (NIRS) oximetry. DESIGN: Phase II randomised, single blinded, parallel clinical trial. SETTING: Eight tertiary neonatal intensive care units...

  18. Cerebral near infrared spectroscopy oximetry in extremely preterm infants

    DEFF Research Database (Denmark)

    Hyttel-Sorensen, Simon; Pellicer, Adelina; Alderliesten, Thomas;

    2015-01-01

    OBJECTIVE: To determine if it is possible to stabilise the cerebral oxygenation of extremely preterm infants monitored by cerebral near infrared spectroscopy (NIRS) oximetry. DESIGN: Phase II randomised, single blinded, parallel clinical trial. SETTING: Eight tertiary neonatal intensive care units...

  19. [The research progress in determining lignocellulosic content by near infrared reflectance spectroscopy technology].

    Science.gov (United States)

    Du, Juan; An, Dong; Xia, Tian; Huang, Yan-Hua; Li, Hong-Chao; Zhang, Yun-Wei

    2013-12-01

    Near infrared reflectance spectroscopy technology, as a new analytic method, can be used to determine the content of lignin, cellulose and hemi-cellulose which is faster, effective, easier to operate, and more accurate than the traditional wet chemical methods. Nowadays it has been widely used in measuring the composition of lignocelluloses in woody plant and herbaceous plant. The domestic and foreign research progress in determining the lignin, cellulose and hemi-cellulose content in woody plant ( wood and bamboo used as papermaking raw materials and wood served as potential biomass energy) and herbaceous plant (forage grass and energy grass) by near infrared reflectance spectroscopy technology is comprehensively summarized and the advances in method studies of measuring the composition of lignocelluloses by near infrared reflectance spectroscopy technology are summed up in three aspects, sample preparation, spectral data pretreatment and wavelength selection methods, and chemometric analysis respectively. Four outlooks are proposed combining the development statues of wood, forage grass and energy grass industry. First of all, the authors need to establish more feasible and applicable models for a variety of uses which can be used for more species from different areas, periods and anatomical parts. Secondly, comprehensive near infrared reflectance spectroscopy data base of grass products quality index needs to be improved to realize on-line quality and process control in grassproducts industry, which can guarantee the quality of the grass product. Thirdly, the near infrared reflectance spectroscopy quality index model of energy plant need to be built which can not only contribute to breed screening, but also improve the development of biomass industry. Besides, modeling approaches are required to be explored and perfected any further. Finally, the authors need to try our best to boost the advancement in the determination method of lignin, cellulose and hemi

  20. Nano-plasmonic antennas in the near infrared regime.

    Science.gov (United States)

    Berkovitch, N; Ginzburg, P; Orenstein, M

    2012-02-22

    Plasmonic nano-antennas constitute a central research topic in current science and engineering with an enormous variety of potential applications. Here we review the recent progress in the niche of plasmonic nano-antennas operating in the near infrared part of the spectrum which is important for a variety of applications. Tuning of the resonance into the near infrared regime is emphasized in the perspectives of fabrication, measurement, modeling, and analytical treatments, concentrating on the vast recent achievements in these areas.

  1. Near-infrared branding efficiently correlates light and electron microscopy.

    Science.gov (United States)

    Bishop, Derron; Nikić, Ivana; Brinkoetter, Mary; Knecht, Sharmon; Potz, Stephanie; Kerschensteiner, Martin; Misgeld, Thomas

    2011-06-05

    The correlation of light and electron microscopy of complex tissues remains a major challenge. Here we report near-infrared branding (NIRB), which facilitates such correlation by using a pulsed, near-infrared laser to create defined fiducial marks in three dimensions in fixed tissue. As these marks are fluorescent and can be photo-oxidized to generate electron contrast, they can guide re-identification of previously imaged structures as small as dendritic spines by electron microscopy.

  2. Improvement of Frequency Domain Output Only Modal Identification from the Application of the Random Decrement Technique

    DEFF Research Database (Denmark)

    Rodrigues, J.; Brincker, Rune; Andersen, P.

    2004-01-01

    from the time series, are due to the noise reduction that results from the time averaging procedure of the random decrement technique, and from avoiding leakage in the spectral densities, as long as the random decrement functions are evaluated with sufficient time length to have a complete decay within......This paper explores the idea of estimating the spectral densities as the Fourier transform of the random decrement functions for the application of frequency domain output-only modal identification methods. The gains in relation to the usual procedure of computing the spectral densities directly...... that length. The idea is applied in the analysis of ambient vibration data collected in a ¼ scale model of a 4-story building. The results show that a considerable improvement is achieved, in terms of noise reduction in the spectral density functions and corresponding quality of the frequency domain modal...

  3. Damping Estimation by Frequency Domain Decomposition

    DEFF Research Database (Denmark)

    Brincker, Rune; Ventura, C. E.; Andersen, P.

    2001-01-01

    frequencies can be accurately estimated without being limited by the frequency resolution of the discrete Fourier transform. It is explained how the spectral density matrix is decomposed into a set of single degree of freedom systems, and how the individual SDOF auto spectral density functions are transformed...

  4. 注射用单唾液酸四己糖神经节苷脂钠近红外特征谱段相关系数模型的建立%Construction of Characteristic Spectral Correlation Coefficient Model for Monosialotetrahexosyl Ganglio-side Sodium Injections by Near-Infrared Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    马金金; 尹利辉; 丁永辉; 肖新月; 马双成; 任丽萍; 杨锡

    2014-01-01

    Objective:To construct characteristic spectral correlation coefficient model for monosialotetrahexosyl ganglioside sodi-um injections ( GM1 injections) from different manufacturers by near-infrared ( NIR) diffuse reflectance spectroscopy to provide refer-ence for the rapid test. Methods:NIR spectral correlation coefficient model for 9 batches of GM1 injections from 2 manufacturers was constructed, and the accuracy and transitivity of the model was validated. Results: The correlation coefficient model can accurately distinguish the samples from the 2 manufacturers. Conclusion:The method is simple, fast and reliable, and has the potential to be em-ployed in the mobile laboratory to identify GM1 injections.%目的:运用近红外(NIR)漫反射光谱法建立不同厂家注射用单唾液酸四己糖神经节苷脂钠(注射用GM1)的特征谱段相关系数模型,为该品种药品(国产)快速检验提供依据。方法:对国内2个厂家的共9个批次注射用GM1进行研究,通过扫描其近红外光谱,建立注射用GM1的特征谱段相关系数模型,并验证模型的准确性和可传递性。结果:建立的相关系数模型能够准确区分2个厂家的样品。结论:本方法简便、快捷、可靠,可对国内不同厂家生产的注射用GM1进行快速的初步定性分析,适用于药品检验车的快速无损检测。

  5. Spectra Transfer Between a Fourier Transform Near-Infrared Laboratory and a Miniaturized Handheld Near-Infrared Spectrometer.

    Science.gov (United States)

    Hoffmann, Uwe; Pfeifer, Frank; Hsuing, Chang; Siesler, Heinz W

    2016-05-01

    The aim of this contribution is to demonstrate the transfer of spectra that have been measured on two different laboratory Fourier transform near-infrared (FT-NIR) spectrometers to the format of a handheld instrument by measuring only a few samples with both spectrometer types. Thus, despite the extreme differences in spectral range and resolution, spectral data sets that have been collected and quantitative as well as qualitative calibrations that have been developed thereof, respectively, over a long period on a laboratory instrument can be conveniently transferred to the handheld system. Thus, the necessity to prepare completely new calibration samples and the effort required to develop calibration models when changing hardware platforms is minimized. The enabling procedure is based on piecewise direct standardization (PDS) and will be described for the data sets of a quantitative and a qualitative application case study. For this purpose the spectra measured on the FT-NIR laboratory spectrometers were used as "master" data and transferred to the "target" format of the handheld instrument. The quantitative test study refers to transmission spectra of three-component liquid solvent mixtures whereas the qualitative application example encompasses diffuse reflection spectra of six different current polymers. To prove the performance of the transfer procedure for quantitative applications, partial least squares (PLS-1) calibrations were developed for the individual components of the solvent mixtures with spectra transferred from the master to the target instrument and the cross-validation parameters were compared with the corresponding parameters obtained for spectra measured on the master and target instruments, respectively. To test the retention of the discrimination ability of the transferred polymer spectra sets principal component analyses (PCAs) were applied exemplarily for three of the six investigated polymers and their identification was demonstrated by

  6. Quantitative Determination of Germinability of Puccinia striiformis f. sp. tritici Urediospores Using Near Infrared Spectroscopy Technology

    Directory of Open Access Journals (Sweden)

    Yaqiong Zhao

    2015-01-01

    Full Text Available Stripe rust caused by Puccinia striiformis f. sp. tritici (Pst is an important disease on wheat. In this study, quantitative determination of germinability of Pst urediospores was investigated by using near infrared reflectance spectroscopy (NIRS combined with quantitative partial least squares (QPLS and support vector regression (SVR. The near infrared spectra of the urediospore samples were acquired using FT-NIR MPA spectrometer and the germination rate of each sample was measured using traditional spore germination method. The best QPLS model was obtained with vector correction as the preprocessing method of the original spectra and 4000–12000 cm−1 as the modeling spectral region while the modeling ratio of the training set to the testing set was 4 : 1. The best SVR model was built when vector normalization was used as the preprocessing method, the modeling ratio was 5 : 1 and the modeling spectral region was 8000–11000 cm−1. The results showed that the effect of the best model built using QPLS or SVR was satisfactory. This indicated that quantitative determination of germinability of Pst urediospores using near infrared spectroscopy technology is feasible. A new method based on NIRS was provided for rapid, automatic, and nondestructive determination of germinability of Pst urediospores.

  7. CRIRES-POP: A library of high resolution spectra in the near-infrared

    CERN Document Server

    Lebzelter, T; Uttenthaler, S; Ramsay, S; Hartman, H; Nieva, M -F; Przybilla, N; Smette, A; Wahlgren, G M; Wolff, B; Hussain, G A J; Kaeufl, H U; Seemann, U

    2012-01-01

    New instrumental capabilities and the wealth of astrophysical information extractable from the near-infrared wavelength region have led to a growing interest in the field of high resolution spectroscopy at 1-5 mu. We aim to provide a library of observed high-resolution and high signal-to-noise-ratio near-infrared spectra of stars of various types throughout the Hertzsprung-Russell diagram. This is needed for the exploration of spectral features in this wavelength range and for comparison of reference targets with observations and models. High quality spectra were obtained using the CRIRES near-infrared spectrograph at ESO's VLT covering the range from 0.97 to 5.3 mu at high spectral resolution. Accurate wavelength calibration and correction for of telluric lines were performed by fitting synthetic transmission spectra for the Earth's atmosphere to each spectrum individually. We describe the observational strategy and the current status and content of the library which includes 13 objects. The first examples o...

  8. Bi-color near infrared thermoreflectometry: a method for true temperature field measurement.

    Science.gov (United States)

    Sentenac, Thierry; Gilblas, Rémi; Hernandez, Daniel; Le Maoult, Yannick

    2012-12-01

    In a context of radiative temperature field measurement, this paper deals with an innovative method, called bicolor near infrared thermoreflectometry, for the measurement of true temperature fields without prior knowledge of the emissivity field of an opaque material. This method is achieved by a simultaneous measurement, in the near infrared spectral band, of the radiance temperature fields and of the emissivity fields measured indirectly by reflectometry. The theoretical framework of the method is introduced and the principle of the measurements at two wavelengths is detailed. The crucial features of the indirect measurement of emissivity are the measurement of bidirectional reflectivities in a single direction and the introduction of an unknown variable, called the "diffusion factor." Radiance temperature and bidirectional reflectivities are then merged into a bichromatic system based on Kirchhoff's laws. The assumption of the system, based on the invariance of the diffusion factor for two near wavelengths, and the value of the chosen wavelengths, are then discussed in relation to a database of several material properties. A thermoreflectometer prototype was developed, dimensioned, and evaluated. Experiments were carried out to outline its trueness in challenging cases. First, experiments were performed on a metallic sample with a high emissivity value. The bidirectional reflectivity was then measured from low signals. The results on erbium oxide demonstrate the power of the method with materials with high emissivity variations in near infrared spectral band.

  9. A near-infrared SETI experiment: probability distribution of false coincidences

    CERN Document Server

    Maire, Jérôme; Werthimer, Dan; Treffers, Richard R; Marcy, Geoffrey W; Stone, Remington P S; Drake, Frank; Siemion, Andrew

    2014-01-01

    A Search for Extraterrestrial Life (SETI), based on the possibility of interstellar communication via laser signals, is being designed to extend the search into the near-infrared spectral region (Wright et al, this conference). The dedicated near-infrared (900 to 1700 nm) instrument takes advantage of a new generation of avalanche photodiodes (APD), based on internal discrete amplification. These discrete APD (DAPD) detectors have a high speed response ($>$ 1 GHz) and gain comparable to photomultiplier tubes, while also achieving significantly lower noise than previous APDs. We are investigating the use of DAPD detectors in this new astronomical instrument for a SETI search and transient source observations. We investigated experimentally the advantages of using a multiple detector device operating in parallel to remove spurious signals. We present the detector characterization and performance of the instrument in terms of false positive detection rates both theoretically and empirically through lab measureme...

  10. Background correction in near-infrared spectra of plant extracts by orthogonal signal correction

    Institute of Scientific and Technical Information of China (English)

    QU Hai-bin; OU Dan-lin; CHENG Yi-yu

    2005-01-01

    In near-infrared (NIR) analysis of plant extracts, excessive background often exists in near-infrared spectra. The detection of active constituents is difficult because of excessive background, and correction of this problem remains difficult. In this work, the orthogonal signal correction (OSC) method was used to correct excessive background. The method was also compared with several classical background correction methods, such as offset correction, multiplicative scatter correction (MSC),standard normal variate (SNV) transformation, de-trending (DT), first derivative, second derivative and wavelet methods. A simulated dataset and a real NIR spectral dataset were used to test the efficiency of different background correction methods. The results showed that OSC is the only effective method for correcting excessive background.

  11. Near-infrared line identification in type Ia supernovae during the transitional phase

    Energy Technology Data Exchange (ETDEWEB)

    Friesen, Brian; Baron, E.; Wisniewski, John P.; Miller, Timothy R. [Homer L. Dodge Department of Physics and Astronomy, 440 West Brooks Street, Room 100, Norman, OK 73019 (United States); Parrent, Jerod T. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Thomas, R. C. [Computational Cosmology Center, Computational Research Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road MS 50B-4206, Berkeley, CA 94720 (United States); Marion, G. H. [University of Texas at Austin, 1 University Station C1400, Austin, TX 78712-0259 (United States)

    2014-09-10

    We present near-infrared synthetic spectra of a delayed-detonation hydrodynamical model and compare them to observed spectra of four normal Type Ia supernovae ranging from day +56.5 to day +85. This is the epoch during which supernovae are believed to be undergoing the transition from the photospheric phase, where spectra are characterized by line scattering above an optically thick photosphere, to the nebular phase, where spectra consist of optically thin emission from forbidden lines. We find that most spectral features in the near-infrared can be accounted for by permitted lines of Fe II and Co II. In addition, we find that [Ni II] fits the emission feature near 1.98 μm, suggesting that a substantial mass of {sup 58}Ni exists near the center of the ejecta in these objects, arising from nuclear burning at high density.

  12. Gastric cancer differentiation using Fourier transform near-infrared spectroscopy with unsupervised pattern recognition

    Science.gov (United States)

    Yi, Wei-song; Cui, Dian-sheng; Li, Zhi; Wu, Lan-lan; Shen, Ai-guo; Hu, Ji-ming

    2013-01-01

    The manuscript has investigated the application of near-infrared (NIR) spectroscopy for differentiation gastric cancer. The 90 spectra from cancerous and normal tissues were collected from a total of 30 surgical specimens using Fourier transform near-infrared spectroscopy (FT-NIR) equipped with a fiber-optic probe. Major spectral differences were observed in the CH-stretching second overtone (9000-7000 cm-1), CH-stretching first overtone (6000-5200 cm-1), and CH-stretching combination (4500-4000 cm-1) regions. By use of unsupervised pattern recognition, such as principal component analysis (PCA) and cluster analysis (CA), all spectra were classified into cancerous and normal tissue groups with accuracy up to 81.1%. The sensitivity and specificity was 100% and 68.2%, respectively. These present results indicate that CH-stretching first, combination band and second overtone regions can serve as diagnostic markers for gastric cancer.

  13. NIMBUS: A Near-Infrared Multi-Band Ultraprecise Spectroimager for SOFIA

    Science.gov (United States)

    McElwain, Michael W.; Mandell, Avi; Woodgate, Bruce E.; Spiegel, David S.; Madhusudhan, Nikku; Amatucci, Edward; Blake, Cullen; Budinoff, Jason; Burgasser, Adam; Burrows, Adam; Clampin, Mark C.; Conroy, Charlie; Deming, L. Drake; Dunham, Edward; Foltz, Roger; Gong, Qian; Knutson, Heather; Muench, Theodore; Murray-Clay, Ruth; Peabody, Hume; Rauscher, Bernard J.; Rinehart, Stephen A.; Villanueva, Geronimo

    2012-01-01

    We present a new and innovative near-infrared multi-band ultraprecise spectroimager (NIMBUS) for SOFIA. This instrument will enable many exciting observations in the new age of precision astronomy. This optical design splits the beam into 8 separate spectral bandpasses, centered around key molecular bands from 1 to 4 microns. Each spectral channel has a wide field of view for simultaneous observations of a reference star that can decorrelate time-variable atmospheric and optical assembly effects, allowing the instrument to achieve ultraprecise photometry for a wide variety of astrophysical sources

  14. Optical and Near-Infrared spectroscopy of Nova V1494 Aquilae 1999 #2

    CERN Document Server

    Kamath, U S; Ashok, N M; Mayya, Y D; Sahu, D K

    2005-01-01

    Optical and near-infrared spectroscopic observations of the fast nova V1494 Aquilae 1999 #2 covering various phases -- early decline, transition and nebular -- during the first eighteen months of its post-outburst evolution are presented in this paper. During this period, the nova evolved in the P_fe P_fe^o C_o spectral sequence. The transition from an optically thick wind to a polar blob - equatorial ring geometry is seen in the evolution of the spectral line profiles. There is evidence of density and temperature stratification in the ejecta. Physical conditions in the ejecta have been estimated based on our observations.

  15. The Near-infrared Spectrum of the Brown Dwarf Gliese 229B

    OpenAIRE

    Geballe, T. R.; Kulkarni, S.R.; Woodward, C. E.; Sloan, G.C.

    1996-01-01

    A medium resolution 1.0-2.5um spectrum of the brown dwarf, Gliese 229B has been obtained using CGS4 on UKIRT. In addition to the broad spectral structure seen in earlier low resolution observations, the new spectrum reveals a large number of absorption lines, many of which can be identified with water vapor. Water and methane are both shown to be strong absorbers in the near-infrared spectrum of the object. Several spectral features in Gl 229B that are attributable to methane match ones seen ...

  16. [Testing of germination rate of hybrid rice seeds based on near-infrared reflectance spectroscopy].

    Science.gov (United States)

    Li, Yi-nian; Jiang, Dan; Liu, Ying-ying; Ding, Wei-min; Ding, Qi-shuo; Zha, Liang-yu

    2014-06-01

    Germination rate of rice seeds was measured according to technical stipulation of germination testing for agricultural crop seeds at present. There existed many faults for this technical stipulation such as long experimental period, more costing and higher professional requirement. A rapid and non-invasive method was put forward to measure the germination rate of hybrid rice seeds based on near-infrared reflectance spectroscopy. Two varieties of hybrid rice seeds were aged artificially at temperature 45 degrees C and humidity 100% condition for 0, 24, 48, 72, 96, 120 and 144 h. Spectral data of 280 samples for 2 varieties of hybrid rice seeds with different aging time were acquired individually by near-infrared spectra analyzer. Spectral data of 280 samples for 2 varieties of hybrid rice seeds were randomly divided into calibration set (168 samples) and prediction set (112 samples). Gormination rate of rice seed with different aging time was tested. Regression model was established by using partial least squares (PLS). The effect of the different spectral bands on the accuracy of models was analyzed and the effect of the different spectral preprocessing methods on the accuracy of models was also compared. Optimal model was achieved under the whole bands and by using standardization and orthogonal signal correction (OSC) preprocessing algorithms with CM2000 software for spectral data of 2 varieties of hybrid rice seeds, the coefficient of determination of the calibration set (Rc) and that of the prediction set (Rp) were 0.965 and 0.931 individually, standard error of calibration set (SEC) and that of prediction set (SEP) were 1.929 and 2.899 respectively. Relative error between tested value and predicted value for prediction set of rice seeds is below 4.2%. The experimental results show that it is feasible that rice germination rate is detected rapidly and nondestructively by using the near-infrared spectroscopy analysis technology.

  17. The near-infrared spectrum of ethynyl radical.

    Science.gov (United States)

    Le, Anh T; Hall, Gregory E; Sears, Trevor J

    2016-08-21

    Transient diode laser absorption spectroscopy has been used to measure three strong vibronic bands in the near infrared spectrum of the C2H, ethynyl, radical not previously observed in the gas phase. The radical was produced by ultraviolet excimer laser photolysis of either acetylene or (1,1,1)-trifluoropropyne in a slowly flowing sample of the precursor diluted in inert gas, and the spectral resolution was Doppler-limited. The character of the upper states was determined from the rotational and fine structure in the observed spectra and assigned by measurement of ground state rotational combination differences. The upper states include a (2)Σ(+) state at 6696 cm(-1), a second (2)Σ(+) state at 7088 cm(-1), and a (2)Π state at 7110 cm(-1). By comparison with published calculations [R. Tarroni and S. Carter, J. Chem. Phys 119, 12878 (2003); Mol. Phys. 102, 2167 (2004)], the vibronic character of these levels was also assigned. The observed states contain both X(2)Σ(+) and A(2)Π electronic characters. Several local rotational level perturbations were observed in the excited states. Kinetic measurements of the time-evolution of the ground state populations following collisional relaxation and reactive loss of the radicals formed in a hot, non-thermal, population distribution were made using some of the strong rotational lines observed. The case of C2H may be a good place to investigate the behavior at intermediate pressures of inert colliders, where the competition between relaxation and reaction can be tuned and observed to compare with master equation models, rather than deliberately suppressed to measure thermal rate constants.

  18. The near-infrared spectrum of ethynyl radical

    Science.gov (United States)

    Le, Anh T.; Hall, Gregory E.; Sears, Trevor J.

    2016-08-01

    Transient diode laser absorption spectroscopy has been used to measure three strong vibronic bands in the near infrared spectrum of the C2H, ethynyl, radical not previously observed in the gas phase. The radical was produced by ultraviolet excimer laser photolysis of either acetylene or (1,1,1)-trifluoropropyne in a slowly flowing sample of the precursor diluted in inert gas, and the spectral resolution was Doppler-limited. The character of the upper states was determined from the rotational and fine structure in the observed spectra and assigned by measurement of ground state rotational combination differences. The upper states include a 2Σ+ state at 6696 cm-1, a second 2Σ+ state at 7088 cm-1, and a 2Π state at 7110 cm-1. By comparison with published calculations [R. Tarroni and S. Carter, J. Chem. Phys 119, 12878 (2003); Mol. Phys. 102, 2167 (2004)], the vibronic character of these levels was also assigned. The observed states contain both X2Σ+ and A2Π electronic characters. Several local rotational level perturbations were observed in the excited states. Kinetic measurements of the time-evolution of the ground state populations following collisional relaxation and reactive loss of the radicals formed in a hot, non-thermal, population distribution were made using some of the strong rotational lines observed. The case of C2H may be a good place to investigate the behavior at intermediate pressures of inert colliders, where the competition between relaxation and reaction can be tuned and observed to compare with master equation models, rather than deliberately suppressed to measure thermal rate constants.

  19. New and Better Near-Infrared Detectors for JWST Near Infrared Spectrograph

    Science.gov (United States)

    Rauscher, Bernard J.; Mott, D. Brent; Wen, Yiting; Linder, Don; Greenhouse, Matthew A.; Hill, Robert J.

    2014-01-01

    ESA and NASA recently selected two 5 m cutoff Teledyne H2RG sensor chip assemblies (SCA) for flight on the James Webb Space Telescope (JWST) Near Infrared Spectrograph (NIRSpec). These HgCdTe SCAs incorporate Teledynes improved barrier layer design that eliminates the degradation that affected earlier JWST H2RGs(Rauscher et al. 2012a). The better indium barrier, together with other design changes, has improved the performance and reliability of JWSTs SCAs. In this article, we describe the measured performance characteristics that most directly affect scientific observations including read noise, total noise, dark current, quantum efficiency (QE), and image persistence. As part of measuring QE, we measured the quantum yield as a function of photon energy,, and found that it exceeds unity for photon energies E (2.65.2) Eg, where Eg is the HgCdTe bandgap energy. This corresponds to. 2 m for NIRSpecs 5 m cutoff HgCdTe. Our measurements agree well with a previous measurement by McCullough et al. (2008) for. 1.3. For 1.3, we find a slower increase in with photon energy than McCullough et al. did. However, and as McCullough et al. note, their two state model of the yield process is not valid for large 1.

  20. Intraoperative near-infrared autofluorescence imaging of parathyroid glands.

    Science.gov (United States)

    Ladurner, Roland; Sommerey, Sandra; Arabi, Nora Al; Hallfeldt, Klaus K J; Stepp, Herbert; Gallwas, Julia K S

    2017-08-01

    To identify parathyroid glands intraoperatively by exposing their autofluorescence using near-infrared light. Fluorescence imaging was carried out during minimally invasive and open parathyroid and thyroid surgery. After identification, the parathyroid glands as well as the surrounding tissue were exposed to near-infrared (NIR) light with a wavelength of 690-770 nm using a modified Karl Storz near-infrared/indocyanine green (NIR/ICG) endoscopic system. Parathyroid tissue was expected to show near-infrared autofluorescence, captured in the blue channel of the camera. Whenever possible the visual identification of parathyroid tissue was confirmed histologically. In preliminary investigations, using the original NIR/ICG endoscopic system we noticed considerable interference of light in the blue channel overlying the autofluorescence. Therefore, we modified the light source by interposing additional filters. In a second series, we investigated 35 parathyroid glands from 25 patients. Twenty-seven glands were identified correctly based on NIR autofluorescence. Regarding the extent of autofluorescence, there were no noticeable differences between parathyroid adenomas, hyperplasia and normal parathyroid glands. In contrast, thyroid tissue, lymph nodes and adipose tissue revealed no substantial autofluorescence. Parathyroid tissue is characterized by showing autofluorescence in the near-infrared spectrum. This effect can be used to distinguish parathyroid glands from other cervical tissue entities.

  1. Perdeuterated liquid crystals for near infrared applications

    Science.gov (United States)

    Kula, P.; Bennis, N.; Marć, P.; Harmata, P.; Gacioch, K.; Morawiak, P.; Jaroszewicz, L. R.

    2016-10-01

    For majority of Liquid Crystalline compounds the absorption occurs at two spectral regions: ultraviolet UV (due to electronic excitations) and infrared IR (caused by molecular vibrations). Both cause the absorption which deteriorates electro-optical modulation abilities of LC. In the MWIR and LWIR regions, there are many fundamental molecular vibration bands. The most intense are the ones with high anharmonicity, which in the case of LCs corresponds to the Csbnd H bonds, especially present in the aliphatic chains. In the NIR region, overtone molecular vibration bands derived from IR region begin to appear. In the case of Csbnd H bond system, the first overtones are present at 1.6-1.7 μm. To reduce NIR absorptions, perdeuterated Liquid crystal has been proposed. In this paper, we report the physical and optical properties of liquid crystals based on polarimetry measurements method. We also provide a polar decomposition of experimentally measured Mueller matrix in order to determine polarization properties of the device such as depolarization and diattenuation which cannot be obtained from absorption spectra.

  2. Near-Infrared All-Silicon Photodetectors

    Directory of Open Access Journals (Sweden)

    M. Casalino

    2012-01-01

    Full Text Available We report the fabrication and characterization of all-silicon photodetectors at 1550 nm based on the internal photoemission effect. We investigated two types of structures: bulk and integrated devices. The former are constituted by a Fabry-Perot microcavity incorporating a Schottky diode, and their performance in terms of responsivity, free spectral range, and finesse was experimentally calculated in order to prove an enhancement in responsivity due to the cavity effect. Results show a responsivity peak of about 0.01 mA/W at 1550 nm with a reverse bias of 100 mV. The latter are constituted by a Schottky junction placed transversally to the optical field confined into the waveguide. Preliminary results show a responsivity of about 0.1 mA/W at 1550 nm with a reverse bias of 1 V and an efficient behaviour in both C and L bands. Finally, an estimation of bandwidth for GHz range is deduced for both devices. The technological steps utilized to fabricate the devices allow an efficiently monolithic integration with complementary metal-oxide semiconductor (CMOS compatible structures.

  3. Comparison of the domain and frequency domain state feedbacks

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S.Y.

    1986-01-01

    In this paper, we present explicitly the equivalence of the time domain and frequency domain state feedbacks, as well as the dynamic state feedback and a modified frequency domain state feedback, from the closed-loop transfer function point of view. The difference of the two approaches is also shown.

  4. Estimated Frequency Domain Model Uncertainties used in Robust Controller Design

    DEFF Research Database (Denmark)

    Tøffner-Clausen, S.; Andersen, Palle; Stoustrup, Jakob;

    1994-01-01

    This paper deals with the combination of system identification and robust controller design. Recent results on estimation of frequency domain model uncertainty are......This paper deals with the combination of system identification and robust controller design. Recent results on estimation of frequency domain model uncertainty are...

  5. [Determination of isorhamnetin in Hippophae rhamnoides Linn from West Sichuan plateau using near infrared diffuse reflectance spectroscopy].

    Science.gov (United States)

    Ye, Li-Ming; Zhou, Min; Zhang, Hao; Chen, Chu; Li, Zhang-Wan; Chen, Cong; Wang, Yan-Ping

    2008-02-01

    The objective of this study was to develop a method for the determination of isorhamnetin in Hippophae rhamnoides Linn from West Sichuan plateau using near infrared diffuse reflectance spectroscopy. Applying the method of mixing with SiO2, the near infrared spectra (NIS) with the range of 12 000-4 000 cm(-1) were recorded for the Hippophae rhamnoides Linn containing isorhamnetin with the content of 0.1%-0.8%. Calibration models were established using the PLS (partial least squares). Different spectra pretreatments methods were compared. The study showed that spectral information can be extracted thoroughly by constant offset elimination (COE) pretreatments method with the correlation coefficient (r2) of 0.739 8, SEC of 0.107 (standard deviation of the calibration sets) and SEP of 0.073 (standard deviation of the prediction sets). The results indicate that near infrared diffuse reflectance spectroscopy is more rapid and convenient than conventional methods.

  6. Near infrared reflectance analysis by Gauss-Jordan linear algebra

    Science.gov (United States)

    Honigs, D. E.; Freelin, J. M.; Hieftje, G. M.

    1983-02-01

    Near-infrared reflectance analysis (NIRA) is an analytical technique that uses the near-infrared diffuse reflectance of a sample at several discrete wavelengths to predict the concentration of one or more of the chemical species in that sample. However, because near-infrared bands from solid samples are both abundant and broad, the reflectance at a given wavelength usually contains contributions from several sample components, requiring extensive calculations on overlapped bands. In the present study, these calculations have been performed using an approach similar to that employed in multi-component spectrophotometry, but with Gauss-Jordan linear algebra serving as the computational vehicle. Using this approach, correlations for percent protein in wheat flour and percent benzene in hydrocarbons have been obtained and are evaluated. The advantages of a linear-algebra approach over the common one employing stepwise regression are explored.

  7. A near-infrared SETI experiment: instrument overview

    CERN Document Server

    Wright, Shelley A; Treffers, Richard R; Maire, Jerome; Marcy, Geoffrey W; Stone, Remington P S; Drake, Frank; Meyer, Elliot; Dorval, Patrick; Siemion, Andrew

    2014-01-01

    We are designing and constructing a new SETI (Search for Extraterrestrial Intelligence) instrument to search for direct evidence of interstellar communications via pulsed laser signals at near-infrared wavelengths. The new instrument design builds upon our past optical SETI experiences, and is the first step toward a new, more versatile and sophisticated generation of very fast optical and near-infrared pulse search devices. We present our instrumental design by giving an overview of the opto-mechanical design, detector selection and characterization, signal processing, and integration procedure. This project makes use of near-infrared (950-1650 nm) discrete amplification Avalanche Photodiodes (APD) that have greater than 1 GHz bandwidths with low noise characteristics and moderate gain (~10^4). We have investigated the use of single versus multiple detectors in our instrument (see Maire et al., this conference), and have optimized the system to have both high sensitivity and low false coincidence rates. Our ...

  8. New applications of near infrared spectroscopy in the food industry

    Energy Technology Data Exchange (ETDEWEB)

    Groenewald, C.A. (Peter Rassloff Instruments and Services, Norwood, South Africa)

    The near infrared spectroscopic method of analysis was initially developed for rapid analyses of protein in wheat. A brief explanation of the theory and history of near infrared spectroscopic analysis will be given. Research was done on the application of near infrared spectroscopic (NIR) in the food industry. Especially exciting was the breakthrough achieved in applying NIR to determine the dry solid content of bread. Such application could revolutionise the baking industry. Results will also be presented of research done on the application of NIR techniques for the determination of protein and fat in bread based on dry matter; hardness in wheat; absorption and sedimentation in pasta products; and use in process control in snack products manufacture. The limitations that were found in the application of NIR analysis will also be covered. The developments in NIR technology may result in these methods becoming standard practice in many food laboratories.

  9. Near-infrared roll-off-free electroluminescence from highly stable diketopyrrolopyrrole light emitting diodes

    Science.gov (United States)

    Sassi, Mauro; Buccheri, Nunzio; Rooney, Myles; Botta, Chiara; Bruni, Francesco; Giovanella, Umberto; Brovelli, Sergio; Beverina, Luca

    2016-09-01

    Organic light emitting diodes (OLEDs) operating in the near-infrared spectral region are gaining growing relevance for emerging photonic technologies, such as lab-on-chip platforms for medical diagnostics, flexible self-medicated pads for photodynamic therapy, night vision and plastic-based telecommunications. The achievement of efficient near-infrared electroluminescence from solution-processed OLEDs is, however, an open challenge due to the low photoluminescence efficiency of most narrow-energy-gap organic emitters. Diketopyrrolopyrrole-boron complexes are promising candidates to overcome this limitation as they feature extremely high photoluminescence quantum yield in the near-infrared region and high chemical stability. Here, by incorporating suitably functionalized diketopyrrolopyrrole derivatives emitting at ~760 nm in an active matrix of poly(9,9-dioctylfluorene-alt-benzothiadiazole) and without using complex light out-coupling or encapsulation strategies, we obtain all-solution-processed NIR-OLEDs with external quantum efficiency as high as 0.5%. Importantly, our test-bed devices show no efficiency roll-off even for high current densities and high operational stability, retaining over 50% of the initial radiant emittance for over 50 hours of continuous operation at 10 mA/cm2, which emphasizes the great applicative potential of the proposed strategy.

  10. Near-infrared roll-off-free electroluminescence from highly stable diketopyrrolopyrrole light emitting diodes

    Science.gov (United States)

    Sassi, Mauro; Buccheri, Nunzio; Rooney, Myles; Botta, Chiara; Bruni, Francesco; Giovanella, Umberto; Brovelli, Sergio; Beverina, Luca

    2016-01-01

    Organic light emitting diodes (OLEDs) operating in the near-infrared spectral region are gaining growing relevance for emerging photonic technologies, such as lab-on-chip platforms for medical diagnostics, flexible self-medicated pads for photodynamic therapy, night vision and plastic-based telecommunications. The achievement of efficient near-infrared electroluminescence from solution-processed OLEDs is, however, an open challenge due to the low photoluminescence efficiency of most narrow-energy-gap organic emitters. Diketopyrrolopyrrole-boron complexes are promising candidates to overcome this limitation as they feature extremely high photoluminescence quantum yield in the near-infrared region and high chemical stability. Here, by incorporating suitably functionalized diketopyrrolopyrrole derivatives emitting at ~760 nm in an active matrix of poly(9,9-dioctylfluorene-alt-benzothiadiazole) and without using complex light out-coupling or encapsulation strategies, we obtain all-solution-processed NIR-OLEDs with external quantum efficiency as high as 0.5%. Importantly, our test-bed devices show no efficiency roll-off even for high current densities and high operational stability, retaining over 50% of the initial radiant emittance for over 50 hours of continuous operation at 10 mA/cm2, which emphasizes the great applicative potential of the proposed strategy. PMID:27677240

  11. Near infrared spectroscopy for estimating wood basic density in Eucalyptus urophylla and Eucalyptus grandis

    Directory of Open Access Journals (Sweden)

    Paulo Ricardo Gherardi Hein

    2009-06-01

    Full Text Available Wood basic density is indicative of several other wood properties and is considered as a key feature for many industrialapplications. Near infrared spectroscopy (NIRS is a fast, efficient technique that is capable of estimating that property. However,it should be improved in order to complement the often time-consuming and costly conventional method. Research on woodtechnological properties using near infrared spectroscopy has shown promising results. Thus the aim of this study was to evaluatethe efficiency of near infrared spectroscopy for estimating wood basic density in both Eucalyptus urophylla and Eucalyptus grandis.The coefficients of determination of the predictive models for cross validation ranged between 0.74 and 0.86 and the ratio performanceof deviation (RPD ranged between 1.9 and 2.7. The application of spectral filter, detection and removal of outlier samples, andselection of variables (wavelength improved the adjustment of calibrations, thereby reducing the standard error of calibration (SECand cross validation (SECV as well as increasing the coefficient of determination (R² and the RPD value. The technique of nearinfrared spectroscopy can therefore, be used for predicting wood basic density in Eucalyptus urophylla and Eucalyptus grandis.

  12. [Rapid discriminating hogwash oil and edible vegetable oil using near infrared optical fiber spectrometer technique].

    Science.gov (United States)

    Zhang, Bing-Fang; Yuan, Li-Bo; Kong, Qing-Ming; Shen, Wei-Zheng; Zhang, Bing-Xiu; Liu, Cheng-Hai

    2014-10-01

    In the present study, a new method using near infrared spectroscopy combined with optical fiber sensing technology was applied to the analysis of hogwash oil in blended oil. The 50 samples were a blend of frying oil and "nine three" soybean oil according to a certain volume ratio. The near infrared transmission spectroscopies were collected and the quantitative analysis model of frying oil was established by partial least squares (PLS) and BP artificial neural network The coefficients of determina- tion of calibration sets were 0.908 and 0.934 respectively. The coefficients of determination of validation sets were 0.961 and 0.952, the root mean square error of calibrations (RMSEC) was 0.184 and 0.136, and the root mean square error of predictions (RMSEP) was all 0.111 6. They conform to the model application requirement. At the same time, frying oil and qualified edible oil were identified with the principal component analysis (PCA), and the accurate rate was 100%. The experiment proved that near infrared spectral technology not only can quickly and accurately identify hogwash oil, but also can quantitatively detect hog- wash oil. This method has a wide application prospect in the detection of oil.

  13. Near-infrared-to-visible highly selective thermal emitters based on an intrinsic semiconductor.

    Science.gov (United States)

    Asano, Takashi; Suemitsu, Masahiro; Hashimoto, Kohei; De Zoysa, Menaka; Shibahara, Tatsuya; Tsutsumi, Tatsunori; Noda, Susumu

    2016-12-01

    Control of the thermal emission spectra of emitters will result in improved energy utilization efficiency in a broad range of fields, including lighting, energy harvesting, and sensing. In particular, it is challenging to realize a highly selective thermal emitter in the near-infrared-to-visible range, in which unwanted thermal emission spectral components at longer wavelengths are significantly suppressed, whereas strong emission in the near-infrared-to-visible range is retained. To achieve this, we propose an emitter based on interband transitions in a nanostructured intrinsic semiconductor. The electron thermal fluctuations are first limited to the higher-frequency side of the spectrum, above the semiconductor bandgap, and are then enhanced by the photonic resonance of the structure. Theoretical calculations indicate that optimized intrinsic Si rod-array emitters with a rod radius of 105 nm can convert 59% of the input power into emission of wavelengths shorter than 1100 nm at 1400 K. It is also theoretically indicated that emitters with a rod radius of 190 nm can convert 84% of the input power into emission of emissivity of 0.77 at a wavelength of 790 nm and a very low background emissivity of <0.02 to 0.05 at 1100 to 7000 nm, under operation at 1273 K. Use of a nanostructured intrinsic semiconductor that can withstand high temperatures is promising for the development of highly efficient thermal emitters operating in the near-infrared-to-visible range.

  14. Near-infrared spectroscopy during peripheral vascular surgery

    DEFF Research Database (Denmark)

    Eiberg, J P; Schroeder, T V; Vogt, K C;

    1997-01-01

    Near-infrared spectroscopy was performed perioperatively on the dorsum of the foot in 14 patients who underwent infrainguinal bypass surgery using a prosthesis or the greater saphenous vein. Dual-wavelength continuous light spectroscopy was used to assess changes in tissue saturation before, during...... and after the operation. Following the use of peripheral vascular grafts an immediate postoperative increase in tissue saturation of median 28 (range -10 to +81) arbitrary units was noted (P ... that near-infrared spectroscopy is appropriate for perioperative monitoring during vascular grafting....

  15. Near-infrared face recognition utilizing open CV software

    Science.gov (United States)

    Sellami, Louiza; Ngo, Hau; Fowler, Chris J.; Kearney, Liam M.

    2014-06-01

    Commercially available hardware, freely available algorithms, and authors' developed software are synergized successfully to detect and recognize subjects in an environment without visible light. This project integrates three major components: an illumination device operating in near infrared (NIR) spectrum, a NIR capable camera and a software algorithm capable of performing image manipulation, facial detection and recognition. Focusing our efforts in the near infrared spectrum allows the low budget system to operate covertly while still allowing for accurate face recognition. In doing so a valuable function has been developed which presents potential benefits in future civilian and military security and surveillance operations.

  16. Breast phantom for mammary tissue characterization by near infrared spectroscopy

    Science.gov (United States)

    Miranda, D. A.; Cristiano, K. L.; Gutiérrez, J. C.

    2013-11-01

    Breast cancer is a disease associated to a high morbidity and mortality in the entire world. In the study of early detection of breast cancer the development of phantom is so important. In this research we fabricate a breast phantom using a ballistic gel with special modifications to simulate a normal and abnormal human breast. Optical properties of woman breast in the near infrared region were modelled with the phantom we developed. The developed phantom was evaluated with near infrared spectroscopy in order to study its relation with breast tissue. A good optical behaviour was achieved with the model fabricated.

  17. Near-Infrared Properties of Type Ia Supernovae

    Science.gov (United States)

    Phillips, M. M.

    2012-02-01

    The photometric properties of Type Ia supernovae (SNe Ia) in the near-infrared as garnered from observations made over the last 30 years are reviewed. During this period, light curves for more than 120 nearby SNe Ia have been published, revealing considerable homogeneity but also some fascinating differences. These data have confirmed that, for all but the fastest declining objects, SNe Ia are essentially perfect standard candles in the near-infrared, displaying only a slight dependence of peak luminosity on decline rate and color.

  18. A Near-Infrared Imaging Survey of Coalsack Globule 2

    OpenAIRE

    Racca, German; Gomez, Mercedes; Kenyon, Scott J.

    2002-01-01

    We describe a near-infrared imaging survey of Globule 2 in the Coalsack. This Bok globule is the highest density region of this southern hemisphere molecular cloud and is the most likely location for young stars in this complex. The survey is complete for K < 14.0, H < 14.5, and J < 15.5, several magnitudes more sensitive than previous observations of this globule. From the large number of background stars, we derive an accurate near-infrared extinction law for the cloud. Our result, E_{J-H}/...

  19. Nanostructures graphene plasmon works close to near-infrared window

    DEFF Research Database (Denmark)

    Wang, Zhongli; Li, Tao; Almdal, Kristoffer

    concepts with existing mature technologies in the near-infrared region. We investigate localized graphene plasmons supported by graphene nanodisks and experimentally demonstrated graphene plasmon working at 2 μm with the aid of a fully scalable block copolymer selfassembly method. Our results show......Due to strong mode-confinement, long propagation-distance, and unique tunability, graphene plasmons have been widely explored in the mid-infrared and terahertz windows. However, it remains a big challenge to push graphene plasmons to shorter wavelengths in order to integrate graphene plasmon...... a promising way to promote graphene plasmons for both fundamental studies and potential applications in the near-infrared window....

  20. Steps Toward a Common Near-Infrared Photometric System

    CERN Document Server

    Tokunaga, A T

    2007-01-01

    The proliferation of near-infrared (1--5 $\\mu$m) photometric systems over the last 30 years has made the comparison of photometric results difficult. In an effort to standardize infrared filters in use, the Mauna Kea Observatories near-infrared filter set has been promoted among instrument groups through combined filter production runs. The characteristics of this filter set are summarized, and some aspects of the filter wavelength definitions, the flux density for zero magnitude, atmospheric extinction coefficients, and color correction to above the atmosphere are discussed.

  1. Color vision in the comb frequency domain.

    Science.gov (United States)

    Bonnardel, Valérie; Varela, Francisco J

    2003-01-01

    In 1982, Horace Barlow considered the question of human trichromacy in the context of information theory: according to the Sampling Theorem, three types of receptors covering the visible spectrum (400-700 nm) might be sufficient to reconstruct the color signal. Although Barlow was led to reject the direct application of the Sampling Theorem to explain color dimensionality, the theoretical framework offers a fresh point of view for analyzing the color system in conjunction with the physical characteristics of natural color signals. This review aims to illustrate that if the strict mathematical reconstruction (as implied by the Sampling Theorem) is replaced by a pragmatic approximation of color signals, then trichromacy, with its subsequent opponent-color process, could be regarded as an optimization of color constancy abilities in the spectral environment of primates. Higher dimension systems (tetrachromacy) found in other species can also serve the purpose of color constancy optimization in environments where color signals exhibit a finer spectral structure.

  2. Detection and visualization of intracutaneous allergic type-specific elements using long-wavelength near-infrared hyperspectral imaging.

    Science.gov (United States)

    Nishino, Ken; Fujiyama, Toshiharu; Hashizume, Hideo; Nakauchi, Shigeki

    2013-02-01

    This study aimed to develop a method for the assessment of allergic dermatitis by using the long-wavelength near-infrared spectrum (more than 1000 nm) to detect intracutaneous allergic type-specific elements. Such a method was realized by establishing a spectral classifier for the spectra of type I and type IV allergic dermatitis reactions. Near-infrared spectral images of histamine-induced cutaneous reaction (type I) and contact hypersensitivity erythema elicited by squaric acid dibutylester (SADBE; type IV) were obtained, and the absorption spectra of normal and inflamed skin were extracted from these spectral images. A spectral classifier was established from these training datasets, and it was then applied to two test cases, red flare by methyl nicotinate (normal) and metal allergy (type IV). The spectral classifier established by canonical discriminant analysis (CDA) achieved very accurate detection (normal: 87.67%, type I: 87.00%, type IV: 98.5%). Furthermore, the test cases were also correctly classified: the red flare induced by methyl nicotinate was categorized as normal skin and the metal allergy was categorized as a type IV allergic reaction. These results suggest a possible application of near-infrared spectral imaging to the assessment of allergic dermatitis. © 2012 John Wiley & Sons A/S.

  3. Near Infrared Photoacoustic Detection of Heptane in Synthetic Air

    DEFF Research Database (Denmark)

    Duggen, Lars; Albu, Mihaela; Willatzen, Morten

    2013-01-01

    Trace contaminations of n-heptane in synthetic air is measured in the parts-per-billion (ppb) range using near infrared photoacoustic detection. We describe the fundamental theory used in the design of the photoacoustic cell for trace gas analysis and determine the detection limit of the cell...

  4. X-Shooter Survey of Near-Infrared DIBs

    NARCIS (Netherlands)

    Cox, N.L.J.; Cami, J.; Kaper, L.; Foing, B.H.; Ehrenfreund, P.; Ochsendorf, B.B.; van Hooff, S.H.M.; Salama, F.

    2014-01-01

    We present the first results of an exploratory VLT/X-Shooter survey of near-infrared diffuse interstellar bands (DIBs) in diffuse to translucent interstellar clouds. These observations confirm the presence of recently discoved NIR DIBs and provide more accurate rest wavelengths and line widths.

  5. Near Infrared Photoacoustic Detection of Heptane in Synthetic Air

    DEFF Research Database (Denmark)

    Duggen, Lars; Albu, Mihaela; Willatzen, Morten

    2013-01-01

    Trace contaminations of n-heptane in synthetic air is measured in the parts-per-billion (ppb) range using near infrared photoacoustic detection. We describe the fundamental theory used in the design of the photoacoustic cell for trace gas analysis and determine the detection limit of the cell...

  6. Near infrared photoacoustic detection of heptane in synthetic air

    DEFF Research Database (Denmark)

    Duggen, Lars; Albu, Mihaela; Willatzen, Morten

    2013-01-01

    Trace contaminations of n-heptane in synthetic air is measured in the parts-per-billion (ppb) range using near infrared photoacoustic detection. We describe the fundamental theory used in the design of the photoacoustic cell for trace gas analysis and determine the detection limit of the cell...

  7. Spiral galaxy distance indicators based on near-infrared photometry

    NARCIS (Netherlands)

    Grijs, R. de; Peletier, R. F.

    1999-01-01

    We compare two methods of distance determination to spiral galaxies using optical/near-infrared (NIR) observations, the (I-K) versus M-K colour-absolute magnitude (CM) relation and the I- and K-band Tully-Fisher relation (TFR). Dust-free colours and NIR absolute magnitudes greatly enhance the

  8. Social Perception in Infancy: A Near Infrared Spectroscopy Study

    Science.gov (United States)

    Lloyd-Fox, Sarah; Blasi, Anna; Volein, Agnes; Everdell, Nick; Elwell, Claire E.; Johnson, Mark H.

    2009-01-01

    The capacity to engage and communicate in a social world is one of the defining characteristics of the human species. While the network of regions that compose the social brain have been the subject of extensive research in adults, there are limited techniques available for monitoring young infants. This study used near infrared spectroscopy to…

  9. Cotton micronaire measurements by small portable near infrared (nir) analyzers

    Science.gov (United States)

    A key quality and processing parameter for cotton fiber is micronaire, which is a function of the fiber’s maturity and fineness. Near Infrared (NIR) spectroscopy has previously shown the ability to measure micronaire, primarily in the laboratory and using large, research-grade laboratory NIR instru...

  10. Near-infrared transillumination photography of intraocular tumours.

    Science.gov (United States)

    Krohn, Jørgen; Ulltang, Erlend; Kjersem, Bård

    2013-10-01

    To present a technique for near-infrared transillumination imaging of intraocular tumours based on the modifications of a conventional digital slit lamp camera system. The Haag-Streit Photo-Slit Lamp BX 900 (Haag-Streit AG) was used for transillumination photography by gently pressing the tip of the background illumination cable against the surface of the patient's eye. Thus the light from the flash unit was transmitted into the eye, leading to improved illumination and image resolution. The modification for near-infrared photography was done by replacing the original camera with a Canon EOS 30D (Canon Inc) converted by Advanced Camera Services Ltd. In this camera, the infrared blocking filter was exchanged for a 720 nm long-pass filter, so that the near-infrared part of the spectrum was recorded by the sensor. The technique was applied in eight patients: three with anterior choroidal melanoma, three with ciliary body melanoma and two with ocular pigment alterations. The good diagnostic quality of the photographs made it possible to evaluate the exact location and extent of the lesions in relation to pigmented intraocular landmarks such as the ora serrata and ciliary body. The photographic procedure did not lead to any complications. We recommend near-infrared transillumination photography as a supplementary diagnostic tool for the evaluation and documentation of anteriorly located intraocular tumours.

  11. Gum Arabic authentication and mixture quantification by near infrared spectroscopy

    DEFF Research Database (Denmark)

    Dong, Yongjiang; Sørensen, Klavs Martin; He, Sailing

    2017-01-01

    A rapid and reliable method is developed for Gum Arabic authentication based on Near Infrared (NIR) spectroscopy and chemometric methods. On a large industrial collection of authentic gum Arabics, the two major Acacia gum species, Acacia senegal and Acacia seyal could be assigned perfectly...

  12. Near-infrared spectroscopy (NIRS) in a piglet model

    DEFF Research Database (Denmark)

    Clausen, Nicola Groes; Spielmann, Nelly; Ringer, Simone K.

    2017-01-01

    by Medtronic (Schweiz) AG - 3053 Münchenbuchsee | Switzerland. 1. Murphy GS, Szokol JW, Marymont JH, Greenberg SB, Avram MJ, Vender JS, et al. Cerebral oxygen desaturation events assessed by near-infrared spectroscopy during shoulder arthroscopy in the beach chair and lateral decubitus positions. Anesthesia...

  13. Near-infrared spectroscopy during peripheral vascular surgery

    DEFF Research Database (Denmark)

    Eiberg, J P; Schroeder, T V; Vogt, K C

    1997-01-01

    Near-infrared spectroscopy was performed perioperatively on the dorsum of the foot in 14 patients who underwent infrainguinal bypass surgery using a prosthesis or the greater saphenous vein. Dual-wavelength continuous light spectroscopy was used to assess changes in tissue saturation before, during...

  14. Social Perception in Infancy: A Near Infrared Spectroscopy Study

    Science.gov (United States)

    Lloyd-Fox, Sarah; Blasi, Anna; Volein, Agnes; Everdell, Nick; Elwell, Claire E.; Johnson, Mark H.

    2009-01-01

    The capacity to engage and communicate in a social world is one of the defining characteristics of the human species. While the network of regions that compose the social brain have been the subject of extensive research in adults, there are limited techniques available for monitoring young infants. This study used near infrared spectroscopy to…

  15. Multivariate calibration and moisture control in yerba mate by near infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Larize Mazur

    2014-04-01

    Full Text Available This work describes the development of a multivariate model based on near infrared reflectance spectroscopy (NIR and partial least squares regression for the prediction of the moisture content in yerba mate samples. The multivariate model based on derivatized and multiplicative sign correction (MSC spectral signals (4000-8500 cm-1 was elaborated with 3 latent variables, allowing the fast evaluation of the moisture content with average prediction errors of about 2.5%. The minimal manipulation of the samples permits a high analytical speed that facilitates the implementation of quality control operations.

  16. Optical inspection of smartphone camera modules by near-infrared low-coherence interferometry

    Science.gov (United States)

    Lee, Chang-Yun; Hyun, Sang-Won; Kim, Young-Jin; Kim, Seung-Woo

    2016-09-01

    High-resolution cameras used for smartphones are comprised of multiple aspheric lenses, a spectral filter, and a semiconductor image sensor, which are packaged together into a single module with tight geometrical tolerances. We investigated the technical possibility of near-infrared low-coherence interferometry for nondestructive geometrical inspection of the complex camera module to examine the inside packaging state. This tomographic scheme enabled us to measure the relative axial position of each inside component and also the lateral surface profile of the image sensor, allowing for comprehensive three-dimensional quality assurance of the whole camera module during the packaging process.

  17. Near-infrared III-nitride-on-silicon nanophotonic platform with microdisk resonators.

    Science.gov (United States)

    Roland, I; Zeng, Y; Checoury, X; El Kurdi, M; Sauvage, S; Brimont, C; Guillet, T; Gayral, B; Gromovyi, M; Duboz, J Y; Semond, F; de Micheli, M P; Boucaud, P

    2016-05-02

    We have developed a nanophotonic platform with microdisks using epitaxial III-nitride materials on silicon. The two-dimensional platform consists of suspended waveguides and mushroom-type microdisks as resonators side-coupled with a bus waveguide. Loaded quality factors up to 80000 have been obtained in the near-infrared spectral range for microdisk diameters between 8 and 15 μm. We analyze the dependence of the quality factors as a function of coupling efficiency. We have performed continuous-wave second harmonic generation experiments in resonance with the whispering gallery modes supported by the microdisks.

  18. Long distance active hyperspectral sensing using high-power near-infrared supercontinuum light source.

    Science.gov (United States)

    Manninen, Albert; Kääriäinen, Teemu; Parviainen, Tomi; Buchter, Scott; Heiliö, Miika; Laurila, Toni

    2014-03-24

    A hyperspectral remote sensing instrument employing a novel near-infrared supercontinuum light source has been developed for active illumination and identification of targets. The supercontinuum is generated in a standard normal dispersion multi-mode fiber and has 16 W total optical output power covering 1000 nm to 2300 nm spectral range. A commercial 256-channel infrared spectrometer was used for broadband infrared detection. The feasibility of the presented hyperspectral measurement approach was investigated both indoors and in the field. Reflection spectra from several diffusive targets were successfully measured and a measurement range of 1.5 km was demonstrated.

  19. Capillary method for measuring near-infrared spectra of microlitre volume liquids

    Institute of Scientific and Technical Information of China (English)

    YUAN Bo; MURAYAMA Koichi

    2007-01-01

    The present study theoretically explored the feasibility of the capillary method for measuring near-infrared (NIR) spectra of liquid or solution samples with microlitre volume, which was proposed in our previous studies. Lambert-Beer absorbance rule was applied to establish a model for the integral absorbance of capillary, which was then implemented in numerical analyses of the effects of capillary on various spectral features and dynamic range of absorption measurement. The theoretical speculations indicated that the capillary method might be used in NIR spectroscopy, which was further supported by the empirical data collected from our experiments by comparison between capillary NIR spectra of several organic solvents and cuvette cell NIR spectra.

  20. Breast cancer detection using Ktrans MRI imaging to guide near infrared spectroscopy tomography

    Science.gov (United States)

    Feng, Jinchao; Jiang, Shudong; Xu, Junqing; Zhao, Yan; Gui, Jiang; Pogue, Brian W.; Paulsen, Keith D.

    2017-02-01

    The parametric image of Volume Transfer Coefficient (Ktrans) in MRI has been used to guide image reconstruction of Near-Infrared Spectral Tomography (NIRST). The image reconstruction used direct regularization, in which no segmentation has been involved. A total of 24 patients were involved in this study and the reconstructed results show that the tumor total hemoglobin (HbT) contrast could be used to differentiate the malignant from the benign cases (p-value= 0.018). The addition of the MRI information allows more accurate and definitive HbT values from the NIRST.

  1. Statistics and frequency-domain moveout for multiple-taper receiver functions

    Science.gov (United States)

    Park, J.; Levin, V.

    2016-10-01

    The multiple-taper correlation (MTC) algorithm for the estimation of teleseismic receiver functions (RFs) has desirable statistical properties. This paper presents several adaptations to the MTC algorithm that exploit its frequency-domain uncertainty estimates to generate stable RFs that include moveout corrections for deeper interfaces. Narrow-band frequency averaging implicit in spectral cross-correlation restricts the MTC-based RF estimates to resolve Ps converted phases only at short delay times, appropriate to the upper 100 km of Earth's lithosphere. The Ps conversions from deeper interfaces can be reconstructed by the MTC algorithm in two ways. Event cross-correlation computes a cross-correlation of single-taper spectrum estimates for a cluster of events rather than for a set of eigenspectrum estimates of a single P coda. To extend the reach of the algorithm, pre-stack moveout corrections in the frequency domain preserves the formal uncertainties of the RF estimates, which are used to weight RF stacks. Moving-window migration retains the multiple-taper approach, but cross-correlates the P-polarized motion with time-delayed SH and SV motion to focus on a Ps phase of interest. The frequency-domain uncertainties of bin-averaged RFs do not translate directly into the time domain. A jackknife over data records in each bin stack offers uncertainty estimates in the time domain while preserving uncertainty weighting in the frequency-domain RF stack.

  2. Near infrared spectroscopy in animal science production: principles and applications

    Directory of Open Access Journals (Sweden)

    Roberto Riovanto

    2010-01-01

    Full Text Available Near infrared (NIR is one of the techniques belonging to vibrational spectroscopy. Its radiation (750 to 2500nm interacts with organic matter, and the absorption spectrum is rich in chemical and physical information of organic molecules. In order to extract valuable information on the chemical properties of samples, it is necessary to mathematically process spectral data by chemometric tools. The most important part in the development of an NIR method is building the predicting model generally called calibration. NIR spectroscopy has several advantages over other analytical techniques: rapidity of analysis, no use of chemicals, minimal or no samples preparation, easily applicable in different work environments (on/in/at line applications. On the other hand, NIR spectroscopy has some disadvantages: low ability to predict compounds at low concentration (<0.1%, necessity of accurate analysis as reference, development of calibration models required high trained personnel, need of a large and up-to-date calibration data set (often difficult to obtain, difficulties to transfer calibration among instruments, initial high financial investments. In the feed industry, NIR spectroscopy is used for: feed composition, digestibility (in vivo, in vitro, in situ, traceability assessment (to avoid possible frauds. As far as animal products are concerned, NIR spectroscopy has been used to determine the main composition of meat, milk, fish, cheese, eggs. Furthermore, it was also used to predict some physical properties (tenderness, WHC (Water Holding Capacity, drip loss, colour and pH in meat; coagulation ability in milk; freshness, flavour and other sensorial parameters in cheese. Interesting applications of NIR spectroscopy regard issues like: determination of animal products’ authenticity and the detection of adulteration (in order to prevent frauds, discrimination PDO (Protected Designation of Origin and PGI (Protected Geographical Indication from other non

  3. Near-infrared spectroscopy (NIRS) analysis of major components of milk and the development of analysis instrument

    Science.gov (United States)

    Liu, Jingwei; Ji, Zhongpeng; Tian, Mi

    2014-11-01

    In this study, we introduce a new spectroscopy analysis instrument, along with applied research based on the near-infrared spectroscopy (NIRS) of the major components of milk. Firstly, we analyzed and compared the characteristics of existing near-infrared spectrometers. Then, according to the major component spectra of milk, the spectral range, spectral resolution, and other parameters of the analysis instrument were determined, followed by the construction of a spectroscopy-analysis instrument based on acousto-optic tunable filters (AOTFs). Secondly, on the basis of application requirements, we obtained spectral information from a variety of test samples. Finally, qualitative and quantitative testing of the major components of the milk samples was carried out via typical analysis methods and a mathematical model of NIRS. Thus, this study provides a technical reference for the development of spectroscopy instruments and their applied research.

  4. Frequency domain modeling and dynamic characteristics evaluation of existing wind turbine systems

    Science.gov (United States)

    Chiang, Chih-Hung; Yu, Chih-Peng

    2016-04-01

    It is quite well accepted that frequency domain procedures are suitable for the design and dynamic analysis of wind turbine structures, especially for floating offshore wind turbines, since random wind loads and wave induced motions are most likely simulated in the frequency domain. This paper presents specific applications of an effective frequency domain scheme to the linear analysis of wind turbine structures in which a 1-D spectral element was developed based on the axially-loaded member. The solution schemes are summarized for the spectral analyses of the tower, the blades, and the combined system with selected frequency-dependent coupling effect from foundation-structure interactions. Numerical examples demonstrate that the modal frequencies obtained using spectral-element models are in good agreement with those found in the literature. A 5-element mono-pile model results in less than 0.3% deviation from an existing 160-element model. It is preliminarily concluded that the proposed scheme is relatively efficient in performing quick verification for test data obtained from the on-site vibration measurement using the microwave interferometer.

  5. Causality between Regional Stock Markets: A Frequency Domain Approach

    National Research Council Canada - National Science Library

    Nikola Gradojevic; Eldin Dobardzic

    2013-01-01

    ...), this paper presents a frequency domain analysis of a causal relationship between the returns on the CROBEX, SBITOP, CETOP and DAX indices, and the return on the major Serbian stock exchange index, BELEX 15...

  6. Organic narrowband near-infrared photodetectors based on intermolecular charge-transfer absorption.

    Science.gov (United States)

    Siegmund, Bernhard; Mischok, Andreas; Benduhn, Johannes; Zeika, Olaf; Ullbrich, Sascha; Nehm, Frederik; Böhm, Matthias; Spoltore, Donato; Fröb, Hartmut; Körner, Christian; Leo, Karl; Vandewal, Koen

    2017-06-05

    Blending organic electron donors and acceptors yields intermolecular charge-transfer states with additional optical transitions below their optical gaps. In organic photovoltaic devices, such states play a crucial role and limit the operating voltage. Due to its extremely weak nature, direct intermolecular charge-transfer absorption often remains undetected and unused for photocurrent generation. Here, we use an optical microcavity to increase the typically negligible external quantum efficiency in the spectral region of charge-transfer absorption by more than 40 times, yielding values over 20%. We demonstrate narrowband detection with spectral widths down to 36 nm and resonance wavelengths between 810 and 1,550 nm, far below the optical gap of both donor and acceptor. The broad spectral tunability via a simple variation of the cavity thickness makes this innovative, flexible and potentially visibly transparent device principle highly suitable for integrated low-cost spectroscopic near-infrared photodetection.

  7. Frequency Domain Electroretinography in Retinitis Pigmentosa versus Normal Eyes

    Directory of Open Access Journals (Sweden)

    Homa Hassan-Karimi

    2012-01-01

    Full Text Available Purpose: To compare electroretinogram (ERG characteristics in patients with retinitis pigmentosa (RP and normal subjects using frequency domain analysis. Methods: Five basic ERG recordings were performed in normal subjects and patients with a clinical diagnosis of RP according to the ISCEV (International Society of Clinical Electrophysiology of Vision protocol. Frequency domain analysis was performed by MATLAB software. Different frequency domain parameters were compared between the study groups. Results: Peak frequency (Fmod of flicker and oscillatory responses in RP patients showed significant (P<0.0001 high pass response as compared to normal controls. Peak frequency (Fmod of the other responses was not significantly different between the two groups. Conclusion: In addition to conventional ERG using time domain methods, frequency domain analysis may be useful for diagnosis of RP. Oscillatory and flicker responses may be analyzed in frequency domain. Fast Fourier transform may reveal two distinct high pass responses (shift to higher frequencies in Fmod. Time and frequency domain analyses may be performed simultaneously with many modern ERG machines and may therefore be recommended in RP patients.

  8. Near Infrared Quantum Cutting Luminescence of Er(3+)/Tm(3+) Ion Pairs in a Telluride Glass.

    Science.gov (United States)

    Chen, Xiaobo; Li, Song; Hu, Lili; Wang, Kezhi; Zhao, Guoying; He, Lizhu; Liu, Jinying; Yu, Chunlei; Tao, Jingfu; Lin, Wei; Yang, Guojian; Salamo, Gregory J

    2017-05-16

    The multiphoton near-infrared, quantum cutting luminescence in Er(3+)/Tm(3+) co-doped telluride glass was studied. We found that the near-infrared 1800-nm luminescence intensity of (A) Er(3+)(8%)Tm(3+)(0.5%):telluride glass was approximately 4.4 to 19.5 times larger than that of (B) Tm(3+)(0.5%):telluride glass, and approximately 5.0 times larger than that of (C) Er(3+)(0.5%):telluride glass. Additionally, the infrared excitation spectra of the 1800 nm luminescence, as well as the visible excitation spectra of the 522 nm and 652 nm luminescence, of (A) Er(3+)(8%)Tm(3+)(0.5%):telluride glass are very similar to those of Er(3+) ions in (C) Er(3+)(0.5%):telluride glass, with respect to the shapes of their excitation spectral waveforms and peak wavelengths. Moreover, we found that there is a strong spectral overlap and energy transfer between the infrared luminescence of Er(3+) donor ions and the infrared absorption of Tm(3+) acceptor ions. The efficiency of this energy transfer {(4)I13/2(Er(3+)) → (4)I15/2(Er(3+)), (3)H6(Tm(3+)) → (3)F4(Tm(3+))} between the Er(3+) and Tm(3+) ions is approximately 69.8%. Therefore, we can conclude that the observed behaviour is an interesting multiphoton, near-infrared, quantum cutting luminescence phenomenon that occurs in novel Er(3+)-Tm(3+) ion pairs. These findings are significant for the development of next-generation environmentally friendly germanium solar cells, and near-to-mid infrared (1.8-2.0 μm) lasers pumped by GaN light emitting diodes.

  9. Diffuse reflectance near infrared-chemometric methods development and validation of amoxicillin capsule formulations

    Directory of Open Access Journals (Sweden)

    Ahmed Nawaz Khan

    2016-01-01

    Full Text Available Objective: The aim of present study was to establish near infrared-chemometric methods that could be effectively used for quality profiling through identification and quantification of amoxicillin (AMOX in formulated capsule which were similar to commercial products. In order to evaluate a large number of market products easily and quickly, these methods were modeled. Materials and Methods: Thermo Scientific Antaris II near infrared analyzer with TQ Analyst Chemometric Software were used for the development and validation of the identification and quantification models. Several AMOX formulations were composed with four excipients microcrystalline cellulose, magnesium stearate, croscarmellose sodium and colloidal silicon dioxide. Development includes quadratic mixture formulation design, near infrared spectrum acquisition, spectral pretreatment and outlier detection. According to prescribed guidelines by International Conference on Harmonization (ICH and European Medicine Agency (EMA developed methods were validated in terms of specificity, accuracy, precision, linearity, and robustness. Results: On diffuse reflectance mode, an identification model based on discriminant analysis was successfully processed with 76 formulations; and same samples were also used for quantitative analysis using partial least square algorithm with four latent variables and 0.9937 correlation of coefficient followed by 2.17% root mean square error of calibration (RMSEC, 2.38% root mean square error of prediction (RMSEP, 2.43% root mean square error of cross-validation (RMSECV. Conclusion: Proposed model established a good relationship between the spectral information and AMOX identity as well as content. Resulted values show the performance of the proposed models which offers alternate choice for AMOX capsule evaluation, relative to that of well-established high-performance liquid chromatography method. Ultimately three commercial products were successfully evaluated

  10. [Evaluation of Sugar Content of Huanghua Pear on Trees by Visible/Near Infrared Spectroscopy].

    Science.gov (United States)

    Liu, Hui-jun; Ying, Yi-bin

    2015-11-01

    A method of ambient light correction was proposed to evaluate the sugar content of Huanghua pears on tree by visible/near infrared diffuse reflectance spectroscopy (Vis/NIRS). Due to strong interference of ambient light, it was difficult to collect the efficient spectral of pears on tree. In the field, covering the fruits with a bag blocking ambient light can get better results, but the efficiency is fairly low, the instrument corrections of dark and reference spectra may help to reduce the error of the model, however, the interference of the ambient light cannot be eliminated effectively. In order to reduce the effect of ambient light, a shutter was attached to the front of probe. When opening shutter, the spot spectrum were obtained, on which instrument light and ambient light acted at the same time. While closing shutter, background spectra were obtained, on which only ambient light acted, then the ambient light spectra was subtracted from spot spectra. Prediction models were built using data on tree (before and after ambient light correction) and after harvesting by partial least square (PLS). The results of the correlation coefficient (R) are 0.1, 0.69, 0.924; the root mean square error of prediction (SEP) are 0. 89°Brix, 0.42°Brix, 0.27°Brix; ratio of standard deviation (SD) to SEP (RPD) are 0.79, 1.69, 2.58, respectively. The results indicate that, method of background correction used in the experiment can reduce the effect of ambient lighting on spectral acquisition of Huanghua pears in field, efficiently. This method can be used to collect the visible/near infrared spectrum of fruits in field, and may give full play to visible/near-infrared spectroscopy in preharvest management and maturity testing of fruits in the field.

  11. Activation detection in functional near-infrared spectroscopy by wavelet coherence

    Science.gov (United States)

    Zhang, Xin; Yu, Jian; Zhao, Ruirui; Xu, Wenting; Niu, Haijing; Zhang, Yujin; Zuo, Nianming; Jiang, Tianzi

    2015-01-01

    Functional near-infrared spectroscopy (fNIRS) detects hemodynamic responses in the cerebral cortex by transcranial spectroscopy. However, measurements recorded by fNIRS not only consist of the desired hemodynamic response but also consist of a number of physiological noises. Because of these noises, accurately detecting the regions that have an activated hemodynamic response while performing a task is a challenge when analyzing functional activity by fNIRS. In order to better detect the activation, we designed a multiscale analysis based on wavelet coherence. In this method, the experimental paradigm was expressed as a binary signal obtained while either performing or not performing a task. We convolved the signal with the canonical hemodynamic response function to predict a possible response. The wavelet coherence was used to investigate the relationship between the response and the data obtained by fNIRS at each channel. Subsequently, the coherence within a region of interest in the time-frequency domain was summed to evaluate the activation level at each channel. Experiments on both simulated and experimental data demonstrated that the method was effective for detecting activated channels hidden in fNIRS data.

  12. Near-Infrared Polarimetry toward the Galactic Center

    CERN Document Server

    Nishiyama, Shogo; Hatano, Hirofumi; Kanai, Saori; Kurita, Mikio; Sato, Shuji; Nagata, Tetsuya

    2008-01-01

    Near-infrared polarimetry of point sources reveals the presence of a toroidal magnetic field in the central 20' x 20' region of our Galaxy. Comparing the Stokes parameters between high extinction stars and relatively low extinction ones, we have obtained a polarization originating from magnetically aligned dust grains at the central region of our Galaxy of at most 1-2 kpc. The derived direction of the magnetic field is in good agreement with that obtained from far-infrared/submillimeter observations, which detect polarized thermal emission from dust in the molecular clouds at the Galactic center. Our results show that by subtracting foreground components, near-infrared polarimetry allows investigation of the magnetic field structure at the Galactic center. The distribution of the position angles shows a peak at around 20deg, nearly parallel to the direction of the Galactic plane, suggesting a toroidal magnetic configuration.

  13. Near-infrared uncaging or photosensitizing dictated by oxygen tension

    Science.gov (United States)

    Anderson, Erin D.; Gorka, Alexander P.; Schnermann, Martin J.

    2016-11-01

    Existing strategies that use tissue-penetrant near-infrared light for the targeted treatment of cancer typically rely on the local generation of reactive oxygen species. This approach can be impeded by hypoxia, which frequently occurs in tumour microenvironments. Here we demonstrate that axially unsymmetrical silicon phthalocyanines uncage small molecules preferentially in a low-oxygen environment, while efficiently generating reactive oxygen species in normoxic conditions. Mechanistic studies of the uncaging reaction implicate a photoredox pathway involving photoinduced electron transfer to generate a key radical anion intermediate. Cellular studies demonstrate that the biological mechanism of action is O2-dependent, with reactive oxygen species-mediated phototoxicity in normoxic conditions and small molecule uncaging in hypoxia. These studies provide a near-infrared light-targeted treatment strategy with the potential to address the complex tumour landscape through two distinct mechanisms that vary in response to the local O2 environment.

  14. A calibration unit for the near-infrared spectropolarimeter SPIRou

    Science.gov (United States)

    Boisse, Isabelle; Perruchot, Sandrine; Bouchy, François; Dolon, François; Moreau, François; Sottile, Rico; Wildi, François

    2016-08-01

    SPIRou is a near-infrared spectropolarimeter and high precision radial velocity instrument, to be implemented at CFHT in end 2017. It focuses on the search for Earth-like planets around M dwarfs and on the study of stellar and planetary formation in the presence of stellar magnetic field. The calibration unit and the radial-velocity reference module are essential to the short- and long-term precision (1 m/s). We highlight the specificities in the calibration techniques compared to the spectrographs HARPS (at LaSilla, ESO) or SOPHIE (at OHP, France) due to the near-infrared wavelengths, the CMOS detectors, and the instrument design. We also describe the calibration unit architecture, design and production.

  15. Noninvasive detection of gas exchange rate by near infrared spectroscopy

    Science.gov (United States)

    Xu, Guodong; Mao, Zongzhen; Wang, Bangde

    2008-12-01

    In order to study the relationship among the oxygen concentration in skeletal muscle tissues and the heart rate (HR), oxygen uptake (VO2), respiratory exchange ratio (RER) during incremental running exercises on a treadmill, a near-infrared spectroscopy muscle oxygen monitor system is employed to measure the relative change in muscle oxygenation, with the heart rate, oxygen uptake, production of carbon dioxide (VCO2) and respiratory exchange ratio are recorded synchronously. The results indicate parameters mentioned above present regular changes during the incremental exercise. High correlations are discovered between relative change of oxy-hemoglobin concentration and heart rate, oxygen uptake, respiratory exchange ratio at the significance level (P=0.01). This research might introduce a new measurement technology and/or a novel biological monitoring parameter to the evaluation of physical function status, control the training intensity, estimation of the effectiveness of exercise. Keywords: near-infrared spectroscopy; muscle oxygen concentration; heart rate; oxygen uptake; respiratory exchange ratio.

  16. Cross Correlation Analysis of Multi-Channel Near Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Raul Fernandez Rojas

    2016-02-01

    Full Text Available In this paper we present the use of a signal proces sing technique to find dominant channels in near infrared spectroscopy (NIRS. Cross correlatio n is computed to compare measuring channels and identify delays among the channels. In addition, visual inspection was used to detect potential dominant channels. The results sho wed that the visual analysis exposed pain- related activations in the primary somatosensory co rtex (S1 after stimulation which is consistent with similar studies and the cross corre lation analysis found dominant channels on both cerebral hemispheres. The analysis also showed a relationship between dominant channels and neighbouring channels. Therefore, our results p resent a new method to detect dominant regions in the cerebral cortex using near-infrared spectroscopy. These results have also implications in the reduction of number of channels by eliminating irrelevant channels for the experiment

  17. TIRCAM2: The TIFR Near Infrared Imaging Camera

    CERN Document Server

    Naik, M B; Ghosh, S K; Poojary, S S; Jadhav, R B; Meshram, G S; Sandimani, P R; Bhagat, S B; D'Costa, S L A; Gharat, S M; Bakalkar, C B; Ninan, J P; Joshi, J S

    2012-01-01

    TIRCAM2 (TIFR Near Infrared Imaging Camera - II) is a closed cycle cooled imager that has been developed by the Infrared Astronomy Group at the Tata Institute of Fundamental Research for observations in the near infrared band of 1 to 3.7 microns with existing Indian telescopes. In this paper, we describe some of the technical details of TIRCAM2 and report its observing capabilities, measured performance and limiting magnitudes with the 2-m IUCAA Girawali telescope and the 1.2-m PRL Gurushikhar telescope. The main highlight is the camera's capability of observing in the nbL (3.59 microns) band enabling our primary motivation of mapping of Polycyclic Aromatic Hydrocarbon (PAH) emission at 3.3 microns.

  18. Near infrared organic photodetector utilizing a double electron blocking layer.

    Science.gov (United States)

    Shafian, Shafidah; Hwang, Heewon; Kim, Kyungkon

    2016-10-31

    A near infrared organic photodiode (OPD) utilizing a double electron blocking layer (EBL) fabricated by the sequential deposition of molybdenum (VI) oxide (MoO3) and poly(3,4ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) is reported. The double EBL improves the on/off current ratio of OPD up to 1.36 x 104 at -1V, which is one order of magnitude higher than PEDOT:PSS single EBL (2.45 x 103) and three orders of magnitude higher than that of MoO3 single EBL (7.86). The detectivity at near infrared (800 nm) at -1V is 4.90 x 1011 Jones, which is 2.83 times higher than the PEDOT:PSS single EBL and 2 magnitudes higher compared to the MoO3 single EBL.

  19. Near-infrared photodetector with reduced dark current

    Science.gov (United States)

    Klem, John F; Kim, Jin K

    2012-10-30

    A photodetector is disclosed for the detection of near-infrared light with a wavelength in the range of about 0.9-1.7 microns. The photodetector, which can be formed as either an nBp device or a pBn device on an InP substrate, includes an InGaAs light-absorbing layer, an InAlGaAs graded layer, an InAlAs or InP barrier layer, and an InGaAs contact layer. The photodetector can detect near-infrared light with or without the use of an applied reverse-bias voltage and is useful as an individual photodetector, or to form a focal plane array.

  20. GUI-based Processing of Near Infrared Imaging

    Science.gov (United States)

    Lambert, Dustin; Crews, L. J.; Huard, T. L.; Gutermuth, R. A.

    2007-05-01

    As part of The University of Tennessee at Martin's University Scholars mentored research program, we have developed GUI-based, interactive software to aid in the processing of ground-based, near-infrared images. The software is coded in Perl and Tcl/Tk to maximize cross-platform compatibility. The software reduces the raw images to a final set of flat-fielded, sky-subtracted images, which are then input into PhotVis (Gutermuth et al. 2004) to extract the positions and photometric magnitudes of the sources. The final result is a band-merged catalog of sources ready for scientific analysis. Using near-infrared observations of molecular cloud cores obtained with the Magellan 6.5-meter Baade telescope at Las Campanas Observatory, we demonstrate the capability of this software.

  1. [Recognition of corn seeds based on pattern recognition and near infrared spectroscopy technology].

    Science.gov (United States)

    Liu, Tian-Ling; Su, Qi-Ya; Sun, Qun; Yang, Li-Ming

    2012-06-01

    Pattern recognition technology and data mining methods have become a hot topic in chemometrics. Near infrared (NIR) spectroscopic analysis has been widely used in spectrum signal processing and modeling due to its advantages of quickness, simplicity and nondestructiveness. Based on five different methods of pattern recognition, namely the locally linear embedding (LLE), wavelet transform (WT), principal component analysis (PCA), partial least squares (PLS) and support vector machine (SVM), the pattern recognition system for corn seeds is proposed using NIR technology, and applied to classification of 108 hybrid samples and 178 female samples for corn seeds. Firstly, we get rid of noise or reduce the dimension using LLE, WT, PCA and PLS, and then use SVM to identify two-class samples. In the meantime, 1-norm SVM is the method of direct classification and identification. Experimental results for three different spectral regions show that the performances of three methods, i. e. PCA+SVM, LLE+SVM, PLS+SVM, are superior to WT+SVM and 1-norm SVM methods, and obtain a high classification accuracy, which indicates the feasibility and effectiveness of the proposed methods. Moreover, this investigation provides the theoretical support and practical method for recognition of corn seeds utilizing near infrared spectral data.

  2. Rapid discrimination of main red meat species based on near-infrared hyperspectral imaging technology

    Science.gov (United States)

    Qiao, Lu; Peng, Yankun; Chao, Kuanglin; Qin, Jianwei

    2016-05-01

    Meat is the necessary source of essential nutrients for people including protein, fat, and so on. The discrimination of meat species and the determination of meat authenticity have been an important issue in the meat industry. The objective of this study is to realize the fast and accurate identification of three main red meats containing beef, lamb and pork by using near-infrared hyperspectral imaging (HSI) technology. After acquiring the hyperspectral images of meat samples, the calibration of acquired images and selection of the region of interest (ROI) were carried out. Then spectral preprocessing method of standard normal variate correction (SNV) was used to reduce the light scattering and random noise before the spectral analysis. Finally, characteristic wavelengths were extracted by principal component analysis (PCA), and the Fisher linear discriminant method was applied to establish Fisher discriminant functions to identify the meat species. All the samples were collected from different batches in order to improve the coverage of the models. In addition to the validation of sample itself in train set and cross validation, three different meat samples were sliced at the size of 2cm×2cm×2 cm approximately and were spliced together in one interface to be scanned by HSI system. The acquired hyperspectral data was applied to further validate the discriminant model. The results demonstrated that the near-infrared hyperspectral imaging technology could be applied as an effective, rapid and non-destructive discrimination method for main red meats.

  3. Discriminant analysis of milk adulteration based on near-infrared spectroscopy and pattern recognition

    Science.gov (United States)

    Liu, Rong; Lv, Guorong; He, Bin; Xu, Kexin

    2011-03-01

    Since the beginning of the 21st century, the issue of food safety is becoming a global concern. It is very important to develop a rapid, cost-effective, and widely available method for food adulteration detection. In this paper, near-infrared spectroscopy techniques and pattern recognition were applied to study the qualitative discriminant analysis method. The samples were prepared and adulterated with one of the three adulterants, urea, glucose and melamine with different concentrations. First, the spectral characteristics of milk and adulterant samples were analyzed. Then, pattern recognition methods were used for qualitative discriminant analysis of milk adulteration. Soft independent modeling of class analogy and partial least squares discriminant analysis (PLSDA) were used to construct discriminant models, respectively. Furthermore, the optimization method of the model was studied. The best spectral pretreatment methods and the optimal band were determined. In the optimal conditions, PLSDA models were constructed respectively for each type of adulterated sample sets (urea, melamine and glucose) and all the three types of adulterated sample sets. Results showed that, the discrimination accuracy of model achieved 93.2% in the classification of different adulterated and unadulterated milk samples. Thus, it can be concluded that near-infrared spectroscopy and PLSDA can be used to identify whether the milk has been adulterated or not and the type of adulterant used.

  4. Cryogenic Tm: YAG Laser in the Near Infrared

    Science.gov (United States)

    2015-05-29

    REPLACE THIS LINE WITH YOUR PAPER IDENTIFICATION NUMBER (DOUBLE-CLICK HERE TO EDIT) < Cryogenic Tm:YAG Laser in the Near Infrared* Tso Yee Fan...therefore limits operation. However, operation at cryogenic temperature depopulates the lower laser level, reduces laser threshold, increases...efficiency, and greatly mitigates thermo-optic effects in crystalline host materials [21]-[23]. Here, we have used cryogenic cooling to enable laser

  5. [Near infrared spectroscopy study on water content in turbine oil].

    Science.gov (United States)

    Chen, Bin; Liu, Ge; Zhang, Xian-Ming

    2013-11-01

    Near infrared (NIR) spectroscopy combined with successive projections algorithm (SPA) was investigated for determination of water content in turbine oil. Through the 57 samples of different water content in turbine oil scanned applying near infrared (NIR) spectroscopy, with the water content in the turbine oil of 0-0.156%, different pretreatment methods such as the original spectra, first derivative spectra and differential polynomial least squares fitting algorithm Savitzky-Golay (SG), and successive projections algorithm (SPA) were applied for the extraction of effective wavelengths, the correlation coefficient (R) and root mean square error (RMSE) were used as the model evaluation indices, accordingly water content in turbine oil was investigated. The results indicated that the original spectra with different water content in turbine oil were pretreated by the performance of first derivative + SG pretreatments, then the selected effective wavelengths were used as the inputs of least square support vector machine (LS-SVM). A total of 16 variables selected by SPA were employed to construct the model of SPA and least square support vector machine (SPA-LS-SVM). There is 9 as The correlation coefficient was 0.975 9 and the root of mean square error of validation set was 2.655 8 x 10(-3) using the model, and it is feasible to determine the water content in oil using near infrared spectroscopy and SPA-LS-SVM, and an excellent prediction precision was obtained. This study supplied a new and alternative approach to the further application of near infrared spectroscopy in on-line monitoring of contamination such as water content in oil.

  6. Near-infrared sensitive organic-inorganic photorefractive device

    Science.gov (United States)

    Marinova, Vera; Liu, Ren-Chung; Lin, Shiuan-Huei; Chen, Ming-Syuan; Lin, Yi-Hsin; Hsu, Ken-Yuh

    2016-10-01

    Organic-inorganic hybrid structure, assembled by Rh-doped Bi12TiO20 crystal and liquid crystal (LC) layer, operating at near-infrared range is proposed and demonstrated. Due to the photorefractive properties of inorganic substrate, light illumination caused a space charge field which acts as a driving force for LC molecules re-alignment and subsequent refractive index modulation. All optically controlled phase retardation ability has been demonstrated supporting possibilities for further infrared applications.

  7. Study of local cerebral hemodynamics by frequency-domain near-infrared spectroscopy and correlation with simultaneously acquired functional magnetic resonance imaging

    Science.gov (United States)

    Toronov, Vladislav; Webb, Andrew; Choi, Jee Hyun; Wolf, Martin; Safonova, Larisa; Wolf, Ursula; Gratton, Enrico

    2001-10-01

    The aim of our study was to explore the possibility of detecting hemodynamic changes in the brain using the phase of the intensity modulated optical signal. To obtain optical signals with the highest possible signal-to-noise ratio, we performed a series of simultaneous NIRS-fMRI measurements, with subsequent correlation of the time courses of both measurements. The cognitive paradigm used arithmetic calculations, with optical signals acquired with sensors placed on the forehead. Measurements were done on seven healthy subjects. In five subjects we demonstrated correlation between the hemodynamic signals obtained using NIRS and BOLD fMRI. In four subjects correlation was found for the hemodynamic signal obtained using the phase of the intensity modulated signal.

  8. Tunable Near-Infrared Luminescence in Tin Halide Perovskite Devices.

    Science.gov (United States)

    Lai, May L; Tay, Timothy Y S; Sadhanala, Aditya; Dutton, Siân E; Li, Guangru; Friend, Richard H; Tan, Zhi-Kuang

    2016-07-21

    Infrared emitters are reasonably rare in solution-processed materials. Recently, research into hybrid organo-lead halide perovskite, originally popular in photovoltaics,1-3 has gained traction in light-emitting diodes (LED) due to their low-cost solution processing and good performance.4-9 The lead-based electroluminescent materials show strong colorful emission in the visible region, but lack emissive variants further in the infrared. The concerns with the toxicity of lead may, additionally, limit their wide-scale applications. Here, we demonstrate tunable near-infrared electroluminescence from a lead-free organo-tin halide perovskite, using an ITO/PEDOT:PSS/CH3NH3Sn(Br1-xIx)3/F8/Ca/Ag device architecture. In our tin iodide (CH3NH3SnI3) LEDs, we achieved a 945 nm near-infrared emission with a radiance of 3.4 W sr(-1) m(-2) and a maximum external quantum efficiency of 0.72%, comparable with earlier lead-based devices. Increasing the bromide content in these tin perovskite devices widens the semiconductor bandgap and leads to shorter wavelength emissions, tunable down to 667 nm. These near-infrared LEDs could find useful applications in a range of optical communication, sensing and medical device applications.

  9. Near-Infrared Fluorescent Materials for Sensing of Biological Targets

    Directory of Open Access Journals (Sweden)

    Julia Xiaojun Zhao

    2008-05-01

    Full Text Available Near-infrared fluorescent (NIRF materials are promising labeling reagents for sensitive determination and imaging of biological targets. In the near-infrared region biological samples have low background fluorescence signals, providing high signal to noise ratio. Meanwhile, near-infrared radiation can penetrate into sample matrices deeply due to low light scattering. Thus, in vivo and in vitro imaging of biological samples can be achieved by employing the NIRF probes. To take full advantage of NIRF materials in the biological and biomedical field, one of the key issues is to develop intense and biocompatible NIRF probes. In this review, a number of NIRF materials are discussed including traditional NIRF dye molecules, newly developed NIRF quantum dots and single-walled carbon nanotubes, as well as rare earth metal compounds. The use of some NIRF materials in various nanostructures is illustrated. The enhancement of NIRF using metal nanostructures is covered as well. The fluorescence mechanism and bioapplications of each type of the NIRF materials are discussed in details.

  10. NIP: the near infrared imaging photometer for Euclid

    Science.gov (United States)

    Schweitzer, Mario; Bender, Ralf; Katterloher, Reinhard; Eisenhauer, Frank; Hofmann, Reiner; Saglia, Roberto; Holmes, Rory; Krause, Oliver; Rix, Hans-Walter; Booth, Jeff; Fagrelius, Parker; Rhodes, Jason; Seshadri, Suresh; Refregier, Alexandre; Amiaux, Jerome; Augueres, Jean-Louis; Boulade, Olivier; Cara, Christophe; Amara, Adam; Lilly, Simon; Atad-Ettedgui, Eli; di Giorgio, Anna-Maria; Duvet, Ludovic; Kuehl, Christopher; Syed, Mohsin

    2010-07-01

    The NIP is a near infrared imaging photometer that is currently under investigation for the Euclid space mission in context of ESA's 2015 Cosmic Vision program. Together with the visible camera (VIS) it will form the basis of the weak lensing measurements for Euclid. The NIP channel will perform photometric imaging in 3 near infrared bands (Y, J, H) covering a wavelength range from ~ 0.9 to 2 μm over a field of view (FoV) of ~ 0.5 deg2. With the required limiting point source magnitude of 24 mAB (5 sigma) the NIP channel will be used to determine the photometric redshifts of over 2 billion galaxies collected over a wide survey area of 20 000 deg2. In addition to the photometric measurements, the NIP channel will deliver unique near infrared (NIR) imaging data over the entire extragalactic sky, enabling a wide variety of ancillary astrophysical and cosmological studies. In this paper we will present the results of the study carried out by the Euclid Imaging Consortium (EIC) during the Euclid assessment phase.

  11. Performance of Spatial Division Multiplexing MIMO with Frequency Domain Packet Scheduling

    DEFF Research Database (Denmark)

    Wei, Na; Pokhariyal, Akhilesh; Sørensen, Troels Bundgaard;

    2008-01-01

    This paper addresses the performance of Spatial Division Multiplexing (SDM) Multiple-input Multiple-output (MIMO) techniques together with Frequency Domain Packet Scheduling (FDPS) in both theory and practice. We start with a theoretical analysis under some ideal assumptions to derive the perform......This paper addresses the performance of Spatial Division Multiplexing (SDM) Multiple-input Multiple-output (MIMO) techniques together with Frequency Domain Packet Scheduling (FDPS) in both theory and practice. We start with a theoretical analysis under some ideal assumptions to derive...... is to investigate the impact of realistic factors on performance. Results confirm that the combination of SDM and FDPS can increase the spectral efficiency significantly, particularly in a micro-cell scenario, and up to 30%-60% gain is observed over 1x2 with FDPS depending on the traffic models considered. Finally...

  12. Wavelet-denoising technique in near-infrared methane detection based on tunable diode laser absorption spectroscopy

    Science.gov (United States)

    Gao, Zong-li; Ye, Wei-lin; Zheng, Chuan-tao; Wang, Yi-ding

    2014-07-01

    A novel wavelet denoising (WD) assisted wavelength modulation technique is proposed for improving near-infrared detection performance on methane concentration based on tunable diode laser absorption spectroscopy (TDLAS). Due to the ability of multi-level analytical resolutions both in time- and frequency-domains, the noise contained in the differential signal is greatly suppressed. Sensor mechanical part, optical part and electrical part are integrated, and a portable detection device is finally developed. Theory and formulations of the WD-assisted wavelength modulation technique are presented, and experiments are carried out to prove the normal function on the extraction of the second harmonic (2f) signal from severely polluted differential signal by using the technique. By virtue of WD's suppression on noises, the sensing characteristics on CH4 concentration are improved, and the limit of detection (LOD) is decreased from 4×10-6 (without WD processing) to 10-6. The proposed technique can also be used for the measurement on the concentration of other gases with corresponding near-infrared distributed feedback lasers.

  13. Characterization and correction of the false-discovery rates in resting state connectivity using functional near-infrared spectroscopy

    Science.gov (United States)

    Santosa, Hendrik; Aarabi, Ardalan; Perlman, Susan B.; Huppert, Theodore J.

    2017-05-01

    Functional near-infrared spectroscopy (fNIRS) is a noninvasive neuroimaging technique that uses low levels of red to near-infrared light to measure changes in cerebral blood oxygenation. Spontaneous (resting state) functional connectivity (sFC) has become a critical tool for cognitive neuroscience for understanding task-independent neural networks, revealing pertinent details differentiating healthy from disordered brain function, and discovering fluctuations in the synchronization of interacting individuals during hyperscanning paradigms. Two of the main challenges to sFC-NIRS analysis are (i) the slow temporal structure of both systemic physiology and the response of blood vessels, which introduces false spurious correlations, and (ii) motion-related artifacts that result from movement of the fNIRS sensors on the participants' head and can introduce non-normal and heavy-tailed noise structures. In this work, we systematically examine the false-discovery rates of several time- and frequency-domain metrics of functional connectivity for characterizing sFC-NIRS. Specifically, we detail the modifications to the statistical models of these methods needed to avoid high levels of false-discovery related to these two sources of noise in fNIRS. We compare these analysis procedures using both simulated and experimental resting-state fNIRS data. Our proposed robust correlation method has better performance in terms of being more reliable to the noise outliers due to the motion artifacts.

  14. Robust time and frequency domain estimation methods in adaptive control

    Science.gov (United States)

    Lamaire, Richard Orville

    1987-01-01

    A robust identification method was developed for use in an adaptive control system. The type of estimator is called the robust estimator, since it is robust to the effects of both unmodeled dynamics and an unmeasurable disturbance. The development of the robust estimator was motivated by a need to provide guarantees in the identification part of an adaptive controller. To enable the design of a robust control system, a nominal model as well as a frequency-domain bounding function on the modeling uncertainty associated with this nominal model must be provided. Two estimation methods are presented for finding parameter estimates, and, hence, a nominal model. One of these methods is based on the well developed field of time-domain parameter estimation. In a second method of finding parameter estimates, a type of weighted least-squares fitting to a frequency-domain estimated model is used. The frequency-domain estimator is shown to perform better, in general, than the time-domain parameter estimator. In addition, a methodology for finding a frequency-domain bounding function on the disturbance is used to compute a frequency-domain bounding function on the additive modeling error due to the effects of the disturbance and the use of finite-length data. The performance of the robust estimator in both open-loop and closed-loop situations is examined through the use of simulations.

  15. Near-Infrared Imaging Using a High-Speed Monitoring Near Infrared Hyperspectral Camera (Compovision)

    Institute of Scientific and Technical Information of China (English)

    Daitaro Ishikawa; Asako Motomura; Yoko Igarashi; Yukihiro Ozaki

    2015-01-01

    This review paper reports near‐infrared (NIR) imaging studies using a newly‐developed NIR camer‐a ,Compovision .Compovision can measure a significantly wide area of 150 mm × 250 mm at high speed of be‐tween 2 and 5 s .It enables a wide spectral region measurement in the 1 000~2 350 nm range at 6 nm inter‐vals .We investigated the potential of Compovision in the applications to industrial problems such as the evalu‐ation of pharmaceutical tablets and polymers .Our studies have demonstrated that NIR imaging based on Com‐povision can solve several issues such as long acquisition times and relatively low sensitivity of detection .NIR imaging with Compovision is strongly expected to be applied not only to pharmaceutical tablet monitoring and polymer characterization but also to various applications such as those to food products ,biomedical substances and organic and inorganic materials .

  16. Single stellar populations in the near-infrared II. Synthesis models

    CERN Document Server

    Meneses-Goytia, S; Trager, S C; Vazdekis, A

    2015-01-01

    We present unresolved single stellar population synthesis models in the near-infrared (NIR) range. The extension to the NIR is important for the study of early-type galaxies, since these galaxies are predominantly old and therefore emit most of their light in this wavelength range. The models are based on a library of empirical stellar spectra, the NASA infrared telescope facility (IRTF) spectral library. Integrating these spectra along theoretical isochrones, while assuming an initial mass function (IMF), we have produced model spectra of single age-metallicity stellar populations at a resolution R~2000. These models can be used to fit observed spectral of globular clusters and galaxies, to derive their age distribution, chemical abundances and IMF. The models have been tested by comparing them to observed colours of elliptical galaxies and clusters in the Magellanic Clouds. Predicted absorption line indices have been compared to published indices of other elliptical galaxies. The comparisons show that our m...

  17. Broad-band time-resolved near infrared spectroscopy in the TJ-II stellarator

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, M.C.; Pastor, I.; Cal, E. de la; McCarthy, K.J. [Laboratorio Nacional de Fusion, CIEMAT, Madrid (Spain); Diaz, D. [Universidad Autonoma de Madrid, Dept Quimica Fisica Aplicada, Madrid (Spain)

    2014-11-15

    First experimental results on broad-band, time-resolved Near Infrared (NIR;here loosely defined as covering from 750 to 1650 nm) passive spectroscopy using a high sensitivity InGaAs detector are reported for the TJ-II Stellarator. Experimental set-up is described together with its main characteristics, the most remarkable ones being its enhanced NIR response, broadband spectrum acquisition in a single shot, and time-resolved measurements with up to 1.8 kHz spectral rate. Prospects for future work and more extended physics studies in this newly open spectral region in TJ-II are discussed. (copyright 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  18. NIMBUS: The Near-Infrared Multi-Band Ultraprecise Spectroimager for SOFIA

    CERN Document Server

    McElwain, Michael W; Woodgate, Bruce; Spiegel, David S; Madhusudhan, Nikku; Amatucci, Edward; Blake, Cullen; Budinoff, Jason; Burgasser, Adam; Burrows, Adam; Clampin, Mark; Conroy, Charlie; Deming, L Drake; Dunham, Edward; Foltz, Roger; Gong, Qian; Knutson, Heather; Muench, Theodore; Murray-Clay, Ruth; Peabody, Hume; Rauscher, Bernard; Rinehart, Stephen A; Villanueva, Geronimo

    2012-01-01

    We present a new and innovative near-infrared multi-band ultraprecise spectroimager (NIMBUS) for SOFIA. This design is capable of characterizing a large sample of extrasolar planet atmospheres by measuring elemental and molecular abundances during primary transit and occultation. This wide-field spectroimager would also provide new insights into Trans-Neptunian Objects (TNO), Solar System occultations, brown dwarf atmospheres, carbon chemistry in globular clusters, chemical gradients in nearby galaxies, and galaxy photometric redshifts. NIMBUS would be the premier ultraprecise spectroimager by taking advantage of the SOFIA observatory and state of the art infrared technologies. This optical design splits the beam into eight separate spectral bandpasses, centered around key molecular bands from 1 to 4 microns. Each spectral channel has a wide field of view for simultaneous observations of a reference star that can decorrelate time-variable atmospheric and optical assembly effects, allowing the instrument to ac...

  19. THREE NEW GALACTIC CENTER X-RAY SOURCES IDENTIFIED WITH NEAR-INFRARED SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    DeWitt, Curtis [Department of Physics, University of California, Davis, CA 95616 (United States); Bandyopadhyay, Reba M.; Eikenberry, Stephen S.; Sarajedini, Ata [Department of Astronomy, University of Florida, 211 Bryant Space Center, P.O. Box 112055, Gainesville, FL 32611 (United States); Sellgren, Kris [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Blum, Robert; Olsen, Knut [National Optical Astronomy Observatories, Tucson, AZ 85719 (United States); Bauer, Franz E., E-mail: curtis.n.dewitt@nasa.gov [Departamento de Astronomía y Astrofísica, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 22 (Chile)

    2013-11-01

    We have conducted a near-infrared spectroscopic survey of 47 candidate counterparts to X-ray sources discovered by the Chandra X-Ray Observatory near the Galactic center (GC). Though a significant number of these astrometric matches are likely to be spurious, we sought out spectral characteristics of active stars and interacting binaries, such as hot, massive spectral types or emission lines, in order to corroborate the X-ray activity and certify the authenticity of the match. We present three new spectroscopic identifications, including a Be high-mass X-ray binary (HMXB) or a γ Cassiopeiae (Cas) system, a symbiotic X-ray binary, and an O-type star of unknown luminosity class. The Be HMXB/γ Cas system and the symbiotic X-ray binary are the first of their classes to be spectroscopically identified in the GC region.

  20. Quantitative determination of the human breast milk macronutrients by near-infrared Raman spectroscopy

    Science.gov (United States)

    Motta, Edlene d. C. M.; Zângaro, Renato A.; Silveira, Landulfo, Jr.

    2012-03-01

    This work proposes the evaluation of the macronutrient constitution of human breast milk based on the spectral information provided by near-infrared Raman spectroscopy. Human breast milk (5 mL) from a subject was collected during the first two weeks of breastfeeding and stocked in -20°C freezer. Raman spectra were measured using a Raman spectrometer (830 nm excitation) coupled to a fiber based Raman probe. Spectra of human milk were dominated by bands of proteins, lipids and carbohydrates in the 600-1800 cm-1 spectral region. Raman spectroscopy revealed differences in the biochemical constitution of human milk depending on the time of breastfeeding startup. This technique could be employed to develop a classification routine for the milk in Human Milk Banking (HMB) depending on the nutritional facts.

  1. Erbium-doped oxide and oxyhalide lead borate glasses for near-infrared broadband optical amplifiers

    Science.gov (United States)

    Pisarski, Wojciech A.; Pisarska, Joanna; Lisiecki, Radosław; Grobelny, Łukasz; Dominiak-Dzik, Grażyna; Ryba-Romanowski, Witold

    2009-04-01

    Near-infrared luminescence spectra at 1.53 μm due to main 4I 13/2- 4I 15/2 laser transition of Er 3+ ions in oxide and oxyhalide lead borate glasses were examined. Spectroscopic parameters like spectral linewidth and luminescence lifetime were analyzed with PbX 2 (X = F, Cl or Br) doping. An introduction of lead halide to the borate glass results in the reduction of spectral linewidth and the increase of luminescence lifetime of Er 3+. The luminescence decay from the 4I 13/2 upper state of Er 3+ is longer for glass sample with PbF 2 than PbX 2 (X = Cl or Br).

  2. [Evaluation of cerebral oxygenation in newborns with prematurity apnea: new frequency domain NIR oximeter].

    Science.gov (United States)

    Pratesi, S; Donzelli, G

    2000-01-01

    Near infrared spectroscopy (NIRS) is a non invasive, portable, safe technique for monitoring cerebral oxygenation and haemodynamics. A new frequency-domain tissue oximeter based on a multi-distance measurement protocol is presented. The effects of apneic episodes on cerebral and peripheral arterial oxygen saturation (SatO2) in preterm newborns, as monitored by NIRS and by pulse oximetry, are reported. The study population consist of 5 preterms (26 to 30 weeks of gestational age), in the second week of postnatal age, affected by apnea of prematurity. NIRS and pulse oximetric measurements were made contemporarily for a 40-minutes period for each infant. All monitorized apneic events were associated with bradicardia, and resolved spontaneously or after tactile stimulation. As results: a) there was always cerebral deoxygenation in association with apneic events, b) the mean SatO2 as measured by NIRS was slightly lower than the pulse oximeter readings, c) cerebral SatO2 decreased faster and the absolute value of the cerebral SaO2 decrease was greater than that measured peripherally (mean value of 27 versus 13%), d) increases of cerebral deoxyhemoglobin and total hemoglobin and a decrease of oxyhemoglobin were also observed. These preliminary results show that peripheral oxygen saturation measurements as measured by pulse oximetry could not always reflect brain oxygenation.

  3. Evaluation of Damping Using Frequency Domain Operational Modal Analysis Techniques

    DEFF Research Database (Denmark)

    Bajric, Anela; Georgakis, Christos T.; Brincker, Rune

    2015-01-01

    Operational Modal Analysis (OMA) techniques provide in most cases reasonably accurate estimates of structural frequencies and mode shapes. In contrast though, they are known to often produce uncertain structural damping estimates, which is mainly due to inherent random and/or bias errors...... domain techniques, the Frequency Domain Decomposition (FDD) and the Frequency Domain Polyreference (FDPR). The response of a two degree-of-freedom (2DOF) system is numerically established with specified modal parameters subjected to white noise loading. The system identification is evaluated with well...

  4. Frequency domain simultaneous algebraic reconstruction techniques: algorithm and convergence

    Science.gov (United States)

    Wang, Jiong; Zheng, Yibin

    2005-03-01

    We propose a simultaneous algebraic reconstruction technique (SART) in the frequency domain for linear imaging problems. This algorithm has the advantage of efficiently incorporating pixel correlations in an a priori image model. First it is shown that the generalized SART algorithm converges to the weighted minimum norm solution of a weighted least square problem. Then an implementation in the frequency domain is described. The performance of the new algorithm is demonstrated with fan beam computed tomography (CT) examples. Compared to the traditional SART and its major alternative ART, the new algorithm offers superior image quality and potential application to other modalities.

  5. Error Analysis in Frequency Domain for Linear Multipass Algorithms

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Error analysis methods in frequency domain are developed in this paper for determining the characteristic root and transfer function errors when the linear multipass algorithms are used to solve linear differential equations.the relation between the local truncation error in time domain and the error in frequency domain is established, which is the basis for developing the error estimation methods. The error estimation methods for the digital simulation model constructed by using the Runge-Kutta algorithms and the linear multistep predictor-corrector algorithms are also given.

  6. Finite-Difference Frequency-Domain Method in Nanophotonics

    DEFF Research Database (Denmark)

    Ivinskaya, Aliaksandra

    is often indispensable. This thesis presents the development of rigorous finite-difference method, a very general tool to solve Maxwell’s equations in arbitrary geometries in three dimensions, with an emphasis on the frequency-domain formulation. Enhanced performance of the perfectly matched layers...... is obtained through free space squeezing technique, and nonuniform orthogonal grids are built to greatly improve the accuracy of simulations of highly heterogeneous nanostructures. Examples of the use of the finite-difference frequency-domain method in this thesis range from simulating localized modes...

  7. High-speed optical frequency-domain imaging

    OpenAIRE

    Yun, S. H.; Tearney, G. J.; Boer; Iftimia, N. V.; Bouma, B. E.

    2003-01-01

    We demonstrate high-speed, high-sensitivity, high-resolution optical imaging based on optical frequency-domain interferometry using a rapidly-tuned wavelength-swept laser. We derive and show experimentally that frequency-domain ranging provides a superior signal-to-noise ratio compared with conventional time-domain ranging as used in optical coherence tomography. A high sensitivity of −110 dB was obtained with a 6 mW source at an axial resolution of 13.5 µm and an A-line rate of 15.7 kHz, rep...

  8. An Improved Traffic Matrix Decomposition Method with Frequency Domain Regularization

    CERN Document Server

    Wang, Zhe; Yin, Baolin

    2012-01-01

    In this letter, we propose a novel network traffic matrix decomposition method named as Stable Principal Component Pursuit with Frequency Domain Regularization (SPCP-FDR). SPCP-FDR improves the Stable Principal Component Pursuit (SPCP) method by using a new noise regularization function defined in frequency domain. Compared with SPCP, SPCP-FDR is more adaptive to empirical frequency properties of diverse traffic components. The Accelerated Proximal Gradient (APG) algorithm for SPCP-FDR is presented. Our experiment results demonstrate the rationality of this new method.

  9. [Detection of Adulteration in Milk Powder with Starch Near Infrared].

    Science.gov (United States)

    Wang, Ning-ning; Shen, Bing-hui; Guan, Jian-jun; Zhao, Zhong-rui; Zhu, Ye-wei; Zhang, Lu-da; Yan, Yan-lu; Zheng, Yu-yan; Dong, Cheng-yu; Kang, Ding-ming

    2015-08-01

    Three China trademarks of milk powder called Mengniu, Yili, Wandashan were taken as testing samples. Each of them mixed varied amount of starch in different gradient, which were consisted of 32 adulterated milk powder samples mixed with starch, was taken as standard samples for constructing predicted model. To those 32 samples, the reflecting spectrum characteristics in middle wave of near infrared spectrum with Near Infrared Spectrum Analyzer (Micro NIR 1700) produced by JDSU Ltd. USA were collected for five repeats in five different days. The time span was nearly two months. Firstly, we build the model used the reflecting spectrum characteristics of those samples with biomimetic pattern recognition (BPR) arithmetic to do the qualitative analysis. The analysis included the reliability of testing result and stability of the model. When we took ninety percent as the evaluation threshold of testing result of CAR (Correct Acceptance Rate) and CRR (Correct Rejection Rate), the lowest starch content of adulterate milk powder in all tested samples which the tested result were bigger than that abovementioned threshold was designated CAR threshold (CAR-T) and CRR threshold (CRR-T). CAR means the correct rate of accepting a sample which is belong to itself, CRR means correct rate of refusing to accept a sample which is not belong to itself. The results were shown that, when we constructed a model based on the near infrared spectrum data from each of three China trademark milk powders, respectively, if we constructed a model with infrared spectrum data tested in a same day, both the CAR-T and CRR-T of adulterate starch content of a sample can reach 0.1% in predicting the remainder infrared spectrum data tested within a same day. The three China trademarks of milk powder had the same result. In addition, when we ignored the trademarks, put the spectrum data of adulterate milk powder samples mixed with the same content of starch of three China trademarks milk powder together

  10. The importance of ultraviolet and near-infrared sensitivity for visual discrimination in two species of lacertid lizards.

    Science.gov (United States)

    Martin, Mélissa; Le Galliard, Jean-François; Meylan, Sandrine; Loew, Ellis R

    2015-02-01

    Male and female Lacertid lizards often display conspicuous coloration that is involved in intraspecific communication. However, visual systems of Lacertidae have rarely been studied and the spectral sensitivity of their retinal photoreceptors remains unknown. Here, we characterise the spectral sensitivity of two Lacertid species from contrasting habitats: the wall lizard Podarcis muralis and the common lizard Zootoca vivipara. Both species possess a pure-cone retina with one spectral class of double cones and four spectral classes of single cones. The two species differ in the spectral sensitivity of the LWS cones, the relative abundance of UVS single cones (potentially more abundant in Z. vivipara) and the coloration of oil droplets. Wall lizards have pure vitamin A1-based photopigments, whereas common lizards possess mixed vitamin A1 and A2 photopigments, extending spectral sensitivity into the near infrared, which is a rare feature in terrestrial vertebrates. We found that spectral sensitivity in the UV and near infrared improves discrimination of small variations in throat coloration among Z. vivipara. Thus, retinal specialisations optimise chromatic resolution in common lizards, indicating that the visual system and visual signals might co-evolve.

  11. Late-time near-infrared observations of SN 2005df

    CERN Document Server

    Diamond, Tiara; Gerardy, Christopher L

    2014-01-01

    We present late-time ($200-400$ days) near-infrared spectral evolution for the Type Ia supernova SN 2005df. The spectra show numerous strong emission features of [CoII], [CoIII], and [FeII] throughout the $0.8-1.8$\\mu m region. As the spectrum ages, the cobalt features fade as would be expected from the decay of $^{56}$Co to $^{56}$Fe. We show that the strong and isolated [FeII] emission line at $1.644$\\mu m provides a unique tool to analyze near-infrared spectra of Type Ia supernovae. Normalization of spectra to this line allows separation of features produced by stable versus unstable isotopes of iron group elements. We develop a new method of determining the initial central density, $\\rho_c$, and the magnetic field, $B$, of the white dwarf using the width of the $1.644$\\mu m line. The line width is sensitive because of electron capture in the early stages of burning, which increases as a function of density. The sensitivity of the line width to $B$ increase with time and the effects of the magnetic field s...

  12. Near-infrared microscopy imaging for quantitative analysis of active component in counterfeit imidacloprid

    Science.gov (United States)

    Huang, Yue; Cao, Jinli; Ye, Shengfeng; Duan, Jia; Wu, Lijun; Li, Qianqian; Min, Shungeng

    2012-01-01

    Near-infrared (NIR) imaging systems simultaneously record spectral and spatial information. Near-infrared imaging was applied to the identification of imidacloprid in both artificially mixed samples and commercial formulation in this study. The distributions of technical imidacloprid and additive in the heterogeneous counterfeit were obtained by the relationship imaging (RI) mode. Furthermore a series of samples which consisted of different contents of uniformly distributed imidacloprid were prepared and three data cubes were generated at each content. Extracted spectra from those images were imported to establish the partial least squares model. The model's results were: R2 99.21%, RMSEC 0.0306, RMSECV 0.0183, RMSECV/mean value 0.0348 and RSEP 0.0784. The prediction relative error of commercial formulation is 0.0680, indicating the predicted value was correlated to the real content. Lastly the chemical value reconstruction image of imidacloprid formulation products was calculated by MATLAB program. NIR microscopy imaging manifests herein its potential in qualitatively identifying the active component in counterfeit pesticide and quantifying the active component in scanned image.

  13. Penggolongan Mangga Gedong Gincu Berdasarkan Rasio Kandungan Gula Asam Menggunakan Prediksi Near Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Noneng Fahr

    2016-04-01

    Full Text Available The objective of this research was to classify the quality of ‘Gedong gincu’ mango based on its sugar acid ratio detected nondestructively using spectroscopy near infrared reflectance (NIR. The near infrared wavelength used was in 1000-2500 nm. Some NIR spectral processing and partial least square was selected to develop calibration and validation model of the correlation between NIR reflectance and destructive measurement data. The best model of calibration and validation in predicting sugar acid ratio was found for those model using combination of NIR data treatment of normalization and first derivative (N01, DG1 with 4 PLS factors. The accuracy of model was indicated by the value of r, SEC, CVc and RPDc i.e. 0.89, 29.81%, 24%, 2.23 for calibration model and 0.78, 34.92%, 30%, 1.61 for validation model. It could be concluded that the developed NIR method could classifying the quality of ‘Gedong gincu’ mango based on the sugar acid ratio content with accuracy of 77%.

  14. A near-infrared SETI experiment: probability distribution of false coincidences

    Science.gov (United States)

    Maire, Jérôme; Wright, Shelley A.; Werthimer, Dan; Treffers, Richard R.; Marcy, Geoffrey W.; Stone, Remington P. S.; Drake, Frank; Siemion, Andrew

    2014-07-01

    A Search for Extraterrestrial Life (SETI), based on the possibility of interstellar communication via laser signals, is being designed to extend the search into the near-infrared spectral region (Wright et al, this conference). The dedicated near-infrared (900 to 1700 nm) instrument takes advantage of a new generation of avalanche photodiodes (APD), based on internal discrete amplification. These discrete APD (DAPD) detectors have a high speed response (laser light pulse detection in our experiment. These criteria are defined to optimize the trade between high detection efficiency and low false positive coincident signals, which can be produced by detector dark noise, background light, cosmic rays, and astronomical sources. We investigate experimentally how false coincidence rates depend on the number of detectors in parallel, and on the signal pulse height and width. We also look into the corresponding threshold to each of the signals to optimize the sensitivity while also reducing the false coincidence rates. Lastly, we discuss the analytical solution used to predict the probability of laser pulse detection with multiple detectors.

  15. HIGH-CONTRAST NEAR-INFRARED IMAGING POLARIMETRY OF THE PROTOPLANETARY DISK AROUND RY TAU

    Energy Technology Data Exchange (ETDEWEB)

    Takami, Michihiro; Karr, Jennifer L.; Kim, Hyosun; Chou, Mei-Yin [Institute of Astronomy and Astrophysics, Academia Sinica. P.O. Box 23-141, Taipei 10617, Taiwan (China); Hashimoto, Jun; Kandori, Ryo; Kusakabe, Nobuhiko; Kwon, Jungmi [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Wisniewski, John [H. L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 West Brooks Street, Norman, OK 73019 (United States); Henning, Thomas; Brandner, Wolfgang [Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany); Grady, Carol A. [Eureka Scientific, 2452 Delmer, Suite 100, Oakland, CA 96002 (United States); Hodapp, Klaus W. [Institute for Astronomy, University of Hawaii, 640 North A' ohoku Place, Hilo, HI 96720 (United States); Kudo, Tomoyuki [Subaru Telescope, 650 North A' ohoku Place, Hilo, HI 96720 (United States); Itoh, Yoichi [Nishi-Harima Astronomical Observatory, Center for Astronomy, University of Hyogo, 407-2 Nishigaichi, Sayo, Hyogo 679-5313 (Japan); Momose, Munetake [College of Science, Ibaraki University, 2-1-1 Bunkyo, Mito, Ibaraki 310-8512 (Japan); Mayama, Satoshi [The Center for the Promotion of Integrated Sciences, The Graduate University for Advanced Studies (SOKENDAI), Shonan International Village, Hayama-cho, Miura-gun, Kanagawa 240-0193 (Japan); Currie, Thayne [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON (Canada); Follette, Katherine B. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson AZ 85721 (United States); Abe, Lyu, E-mail: hiro@asiaa.sinica.edu.tw [Laboratoire Lagrange (UMR 7293), Universite de Nice-Sophia Antipolis, CNRS, Observatoire de la Cote d' Azur, 28 Avenue Valrose, F-06108 Nice Cedex 2 (France); and others

    2013-08-01

    We present near-infrared coronagraphic imaging polarimetry of RY Tau. The scattered light in the circumstellar environment was imaged at the H band at a high resolution ({approx}0.''05) for the first time, using Subaru/HiCIAO. The observed polarized intensity (PI) distribution shows a butterfly-like distribution of bright emission with an angular scale similar to the disk observed at millimeter wavelengths. This distribution is offset toward the blueshifted jet, indicating the presence of a geometrically thick disk or a remnant envelope, and therefore the earliest stage of the Class II evolutionary phase. We perform comparisons between the observed PI distribution and disk models with (1) full radiative transfer code, using the spectral energy distribution (SED) to constrain the disk parameters; and (2) monochromatic simulations of scattered light which explore a wide range of parameters space to constrain the disk and dust parameters. We show that these models cannot consistently explain the observed PI distribution, SED, and the viewing angle inferred by millimeter interferometry. We suggest that the scattered light in the near-infrared is associated with an optically thin and geometrically thick layer above the disk surface, with the surface responsible for the infrared SED. Half of the scattered light and thermal radiation in this layer illuminates the disk surface, and this process may significantly affect the thermal structure of the disk.

  16. Chromatic aberration correction of the human eye for retinal imaging in the near infrared.

    Science.gov (United States)

    Fernández, Enrique J; Unterhuber, Angelika; Povazay, Boris; Hermann, Boris; Artal, Pablo; Drexler, Woflgang

    2006-06-26

    An achromatizing lens has been designed for the human eye in the near infrared range, from 700 to 900 nm, for retinal imaging purposes. Analysis of the performance of the lens, including tolerance to misalignments, has been mathematically accomplished by using an existing eye model. The calculations have shown a virtually perfect correction of the ocular longitudinal chromatic aberration, while still keeping a high optical quality. Ocular aberrations in five subjects have been measured with and without the achromatizing lens by using a Hartmann-Shack wavefront sensor and a broad bandwidth femtosecond Ti:sapphire laser in the spectral range of interest with a set of interference filters, studying the benefits and limits in the use of the achromatizing lens. Ocular longitudinal chromatic aberration has been experimentally demonstrated to be fully corrected by the proposed lens, with no induction of any other parasitic aberration. The practical implementation of the achromatizing lens for Ophthalmoscopy, specifically for optical coherence tomography where the use of polychromatic light sources in the near infrared portion of the spectrum is mandatory, has been considered. The potential benefits of using this lens in combination with adaptive optics to achieve a full aberration correction of the human eye for retinal imaging have also been discussed.

  17. Feeding versus feedback in AGN from near-infrared Integral Field Spectroscopy X: NGC5929

    CERN Document Server

    Riffel, Rogemar A; Riffel, Rogerio

    2015-01-01

    We present near-infrared emission-line flux distributions, excitation and kinematics, as well as stellar kinematics, of the inner 520x520 pc2$ of the Seyfert 2 galaxy NGC5929. The observations were performed with the Gemini's Near-Infrared Integral Field Spectrograph (NIFS) at a spatial resolution of 20 pc and spectral resolution of 40km/s in the J- and K-bands. The flux distributions of H2, [FeII], [PII] and recombination lines are extended over most of the field of view, with the highest intensity levels observed along PA=60/240deg, and well correlated with the radio emission. The H2 and [FeII] line emission are originated in thermal processes, mainly due to heating of the gas by X-rays from the central Active Galactic Nucleus (AGN). Contribution of shocks due to the radio jet is observed at locations co-spatial with the radio hotspots at 0.5" northeast and 0.6" southwest of the nucleus, as evidenced by the emission-line ratio and gas kinematics. The stellar kinematics shows rotation with an amplitude at 25...

  18. Pocket-size near-infrared spectrometer for narcotic materials identification

    Science.gov (United States)

    Pederson, Christopher G.; Friedrich, Donald M.; Hsiung, Chang; von Gunten, Marc; O'Brien, Nada A.; Ramaker, Henk-Jan; van Sprang, Eric; Dreischor, Menno

    2014-05-01

    While significant progress has been made towards the miniaturization of Raman, mid-infrared (IR), and near-infrared (NIR) spectrometers for homeland security and law enforcement applications, there remains continued interest in pushing the technology envelope for smaller, lower cost, and easier to use analyzers. In this paper, we report on the use of the MicroNIR Spectrometer, an ultra-compact, handheld near infrared (NIR) spectrometer, the, that weighs less than 60 grams and measures heroin, oxycodone, diazepam), as well as synthetic cathinones (also known as bath salts), and synthetic cannabinoids. A library of the materials was created from a master MicroNIR spectrometer. A set of 25 unknown samples were then identified with three other MicroNIRs showing: 1) the ability to correctly identify the unknown with a very low rate of misidentification, and 2) the ability to use the same library with multiple instruments. In addition, we have shown that through the use of innovative chemometric algorithms, we were able to identify the individual compounds that make up an unknown mixture based on the spectral library of the individual compounds only. The small size of the spectrometer is enabled through the use of high-performance linear variable filter (LVF) technology.

  19. [The evaluation of hydrocarbon potential generation for source rocks by near-infrared diffuse reflection spectra].

    Science.gov (United States)

    Zhang, Yu-Jia; Xu, Xiao-Xuan; Song, Ning; Wu, Zhong-Chen; Zhou, Xiang; Chen, Jin; Cao, Xue-Wei; Wang, Bin

    2011-04-01

    Near-infrared (NIR) and mid-infrared (MIR) diffuse reflection spectra were compared and evaluated for hydrocarbon potential generation of source rocks. Near-infrared diffuse reflectance often exhibits significant differences in the spectra due to the non-homogeneous distribution of the particles, so the signal-to-noise ratio of NIR is much lower than MIR It is too difficult to get accurate results by NIR without using a strong spectral preprocessing method to remove systematic noise such as base-line variation and multiplicative scatter effects. In the present paper, orthogonal signal correction (OSC) and an improved algorithm of it, i.e. direct orthogonal signal correction (DOSC), are used as different methods to preprocess both the NIR and MIR spectra of the hydrocarbon source rocks. Another algorithm, wavelet multi-scale direct orthogonal signal correction (WMDOSC), which is a combination of discrete wavelet transform (DWT) and DOSC, is also used as a preprocessing method. Then, the calibration model of hydrocarbon source rocks before and after pretreatment was established by interval partial least square (iPLS). The experimental results show that WMDOSC is more successfully applied to preprocess the NIR spectra data of the hydrocarbon source rocks than other two algorithms, and NIR performed as good as MIR in the analysis of hydrocarbon potential generation of source rocks with WMDOSC-iPLS pretreatment calibration model.

  20. Perovskite-Erbium Silicate Nanosheet Hybrid Waveguide Photodetectors at the Near-Infrared Telecommunication Band.

    Science.gov (United States)

    Zhang, Xuehong; Yang, Shuzhen; Zhou, Hong; Liang, Junwu; Liu, Huawei; Xia, Hui; Zhu, Xiaoli; Jiang, Ying; Zhang, Qinglin; Hu, Wei; Zhuang, Xiujuan; Liu, Hongjun; Hu, Weida; Wang, Xiao; Pan, Anlian

    2017-06-01

    Methylammonium lead halide perovskites have attracted enormous attentions due to their superior optical and electronic properties. However, the photodetection at near-infrared telecommunication wavelengths is hardly achievable because of their wide bandgaps. Here, this study demonstrates, for the first time, novel perovskite-erbium silicate nanosheet hybrid photodetectors with remarkable spectral response at ≈1.54 µm. Under the near-infrared light illumination, the erbium silicate nanosheets can give strong upconversion luminescence, which will be well confined in their cavities and then be efficiently coupled into and simultaneously excite the adjacent perovskite to realize photodetection. These devices own prominent responsivity and external quantum efficiency as high as previously reported microscale silicon-based subbandgap photodetectors. More importantly, the photoresponse speed (≈900 µs) is faster by five orders than the ever reported hot electron silicon-based photodetectors at telecommunication wavelengths. The realization of perovskite-based telecommunication band photodetectors will open new chances for applications in advanced integrated photonics devices and systems. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Nanoscale Biomolecular Detection Limit for Gold Nanoparticles Based on Near-Infrared Response

    Directory of Open Access Journals (Sweden)

    Mario D’Acunto

    2012-01-01

    Full Text Available Gold nanoparticles have been widely used during the past few years in various technical and biomedical applications. In particular, the resonance optical properties of nanometer-sized particles have been employed to design biochips and biosensors used as analytical tools. The optical properties of nonfunctionalized gold nanoparticles and core-gold nanoshells play a crucial role for the design of biosensors where gold surface is used as a sensing component. Gold nanoparticles exhibit excellent optical tunability at visible and near-infrared frequencies leading to sharp peaks in their spectral extinction. In this paper, we study how the optical properties of gold nanoparticles and core-gold nanoshells are changed as a function of different sizes, shapes, composition, and biomolecular coating with characteristic shifts towards the near-infrared region. We show that the optical tenability can be carefully tailored for particle sizes falling in the range 100–150 nm. The results should improve the design of sensors working at the detection limit.

  2. An Ensemble Successive Project Algorithm for Liquor Detection Using Near Infrared Sensor

    Directory of Open Access Journals (Sweden)

    Fangfang Qu

    2016-01-01

    Full Text Available Spectral analysis technique based on near infrared (NIR sensor is a powerful tool for complex information processing and high precision recognition, and it has been widely applied to quality analysis and online inspection of agricultural products. This paper proposes a new method to address the instability of small sample sizes in the successive projections algorithm (SPA as well as the lack of association between selected variables and the analyte. The proposed method is an evaluated bootstrap ensemble SPA method (EBSPA based on a variable evaluation index (EI for variable selection, and is applied to the quantitative prediction of alcohol concentrations in liquor using NIR sensor. In the experiment, the proposed EBSPA with three kinds of modeling methods are established to test their performance. In addition, the proposed EBSPA combined with partial least square is compared with other state-of-the-art variable selection methods. The results show that the proposed method can solve the defects of SPA and it has the best generalization performance and stability. Furthermore, the physical meaning of the selected variables from the near infrared sensor data is clear, which can effectively reduce the variables and improve their prediction accuracy.

  3. [Research on zinc content in leaf of Olinda Valencia orange using visible near infrared spectroscopy model].

    Science.gov (United States)

    Yi, Shi-lai; Deng, Lie; He, Shao-lan; Zheng, Yong-qiang; Wang, Liang; Zhao, Xu-yang

    2010-11-01

    Olinda valencia orange leaves dry powder-like were taken as sample, and chemical analysis combined with technology of visible near-infrared spectroscopy (Vis/NIRS) was used, through the treatment process of second derivative spectrum of samples of the original spectrum and denoising (Noise). Meanwhile, method of partial least squares (PLS) and cross-validation were used to establish maths model of Zn concentration which applying band combination composited by 400-500 and 1201-1300 nm of characteristic wavelength band. The coefficient of establishing models is 0.9975, while the coefficient of correlation coefficient of prediction is 0.9920. The root mean square error of prediction (RMSEP) of cross-validation is 0.5868. Therefore, the means using visible near-infrared spectroscopy (Vis/NIRS) and the methods of cross-validation and PLS to establish the spectral correction model reflecting the Zn content in leaves and characteristic wavelength bands can detect the Zn content in citrus leaves quantitatively and quickly.

  4. Through Skull Fluorescence Imaging of the Brain in a New Near-Infrared Window

    CERN Document Server

    Hong, Guosong; Chang, Junlei; Antaris, Alexander L; Chen, Changxin; Zhang, Bo; Zhao, Su; Atochin, Dmitriy N; Huang, Paul L; Andreasson, Katrin I; Kuo, Calvin J; Dai, Hongjie

    2014-01-01

    To date, brain imaging has largely relied on X-ray computed tomography and magnetic resonance angiography with limited spatial resolution and long scanning times. Fluorescence-based brain imaging in the visible and traditional near-infrared regions (400-900 nm) is an alternative but currently requires craniotomy, cranial windows and skull thinning techniques, and the penetration depth is limited to 1-2 mm due to light scattering. Here, we report through-scalp and through-skull fluorescence imaging of mouse cerebral vasculature without craniotomy utilizing the intrinsic photoluminescence of single-walled carbon nanotubes in the 1.3-1.4 micrometre near-infrared window. Reduced photon scattering in this spectral region allows fluorescence imaging reaching a depth of >2 mm in mouse brain with sub-10 micrometre resolution. An imaging rate of ~5.3 frames/s allows for dynamic recording of blood perfusion in the cerebral vessels with sufficient temporal resolution, providing real-time assessment of blood flow anomaly...

  5. Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil

    Science.gov (United States)

    Sut, Magdalena; Fischer, Thomas; Repmann, Frank; Raab, Thomas

    2013-04-01

    In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of 'hot spots', is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination 'hot spots', where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection.

  6. Thermal removal from near-infrared imaging spectroscopy data of the Moon

    Science.gov (United States)

    Clark, R.N.; Pieters, C.M.; Green, R.O.; Boardman, J.W.; Petro, N.E.

    2011-01-01

    In the near-infrared from about 2 ??m to beyond 3 ??m, the light from the Moon is a combination of reflected sunlight and emitted thermal emission. There are multiple complexities in separating the two signals, including knowledge of the local solar incidence angle due to topography, phase angle dependencies, emissivity, and instrument calibration. Thermal emission adds to apparent reflectance, and because the emission's contribution increases over the reflected sunlight with increasing wavelength, absorption bands in the lunar reflectance spectra can be modified. In particular, the shape of the 2 ??m pyroxene band can be distorted by thermal emission, changing spectrally determined pyroxene composition and abundance. Because of the thermal emission contribution, water and hydroxyl absorptions are reduced in strength, lowering apparent abundances. It is important to quantify and remove the thermal emission for these reasons. We developed a method for deriving the temperature and emissivity from spectra of the lunar surface and removing the thermal emission in the near infrared. The method is fast enough that it can be applied to imaging spectroscopy data on the Moon. Copyright ?? 2011 by the American Geophysical Union.

  7. Near infrared emission photometer for measuring the oxidative stability of edible oils.

    Science.gov (United States)

    Vieira, Francisco Senna; Pasquini, Celio

    2013-09-24

    Near infrared emission spectroscopy (NIRES) allows the determination of the induction time (IT) of edible oils in accelerated oxidation experiments by monitoring the emissivity of a band at 2900 nm, which corresponds to the formation of hydroperoxides. In this work, a new near infrared emission photometer dedicated to the determination of oxidative stability is described. The photometer presents several advantages compared to the previously reported NIRES instrument, such as lower cost and extreme simplicity of design and maintenance. The results obtained in the evaluation of the proposed instrument were compared with the official Rancimat method and instrument. The significant advantages include: faster analysis, lower sample consumption and operational simplicity. It is demonstrated that the procedure for determination of oxidative stability of oils can be significantly simplified and performed by measuring the sample emission at only one spectral region centered at 2900 nm. Also, the proposed instrument and method present precision equivalent to the Rancimat method (coefficient of variation=5.0%). A significant correlation between the methods has been found (R(2)=0.81).

  8. Near-infrared line identification in type Ia supernovae during the transitional phase

    CERN Document Server

    Friesen, Brian; Wisniewski, John P; Parrent, Jerod T; Thomas, R C; Miller, Timothy R; Marion, G H

    2014-01-01

    We present near-infrared synthetic spectra of a delayed-detonation hydrodynamical model and compare them to observed spectra of four normal type Ia supernovae ranging from day +56.5 to day +85. This is the epoch during which supernovae are believed to be undergoing the transition from the photospheric phase, where spectra are characterized by line scattering above an optically thick photosphere, to the nebular phase, where spectra consist of optically thin emission from forbidden lines. We find that most spectral features in the near-infrared can be accounted for by permitted lines of Fe II and Co II. In addition, we find that [Ni II] fits the emission feature near 1.98 {\\mu}m, suggesting that a substantial mass of 58Ni exists near the center of the ejecta in these objects, arising from nuclear burning at high density. A tentative identification of Mn II at 1.15 {\\mu}m may support this conclusion as well.

  9. High-Contrast Near-Infrared Imaging Polarimetry of the Protoplanetary Disk around RY Tau

    Science.gov (United States)

    Takami, Michihiro; Karr, Jennifer L.; Hashimoto, Jun; Kim, Hyosun; Wisenewski, John; Henning, Thomas; Grady, Carol; Kandori, Ryo; Hodapp, Klaus W.; Kudo, Tomoyuki; hide

    2013-01-01

    We present near-infrared coronagraphic imaging polarimetry of RY Tau. The scattered light in the circumstellar environment was imaged at H-band at a high resolution (approx. 0.05) for the first time, using Subaru-HiCIAO. The observed polarized intensity (PI) distribution shows a butterfly-like distribution of bright emission with an angular scale similar to the disk observed at millimeter wavelengths. This distribution is offset toward the blueshifted jet, indicating the presence of a geometrically thick disk or a remnant envelope, and therefore the earliest stage of the Class II evolutionary phase. We perform comparisons between the observed PI distribution and disk models with: (1) full radiative transfer code, using the spectral energy distribution (SED) to constrain the disk parameters; and (2) monochromatic simulations of scattered light which explore a wide range of parameters space to constrain the disk and dust parameters. We show that these models cannot consistently explain the observed PI distribution, SED, and the viewing angle inferred by millimeter interferometry. We suggest that the scattered light in the near-infrared is associated with an optically thin and geometrically thick layer above the disk surface, with the surface responsible for the infrared SED. Half of the scattered light and thermal radiation in this layer illuminates the disk surface, and this process may significantly affect the thermal structure of the disk.

  10. Somatic cell count determination in cow's milk by near-infrared spectroscopy: a new diagnostic tool.

    Science.gov (United States)

    Tsenkova, R; Atanassova, S; Kawano, S; Toyoda, K

    2001-10-01

    The potential of near-infrared spectroscopy (NIR) in the region from 1,100 to 2,500 nm to measure somatic cell count (SCC) content of cow's milk was investigated. A total of 196 milk samples from seven Holstein cows were collected for 28, consecutive days, starting from 7th d after calving, and analyzed for fat, protein, lactose, and SCC. Three of the cows were healthy, and the remainder had periods of mastitis during the experiment. Near-infrared transflectance milk spectra were obtained using an InfraAlyzer 500 spectrophotometer. The calibration for logSCC was performed using partial least square (PLS) regression and different spectral data pretreatment. The best accuracy of determination was found for an equation that was obtained using smoothed absorbance data and 10 PLS factors. The standard error of calibration was 0.361, the calibration coefficient of multiple correlation was 0.868, the standard error of prediction for independent validation set of samples was 0.382, the correlation coefficient was 0.854, and the coefficient of variation was 7.63%. The accuracy of logSCC determination by NIR spectroscopy would allow health screening of cows and differentiation between healthy and mastitic milk samples. It has been found that SCC determination by NIR milk spectra is based on the related changes in milk composition. The most significant factors that simultaneously influenced milk spectra with the elevation of SCC were alteration of milk proteins and changes in ionic concentration of milk.

  11. Temperature-Dependent Detectivity of Near-Infrared Organic Bulk Heterojunction Photodiodes.

    Science.gov (United States)

    Wu, Zhenghui; Yao, Weichuan; London, Alexander E; Azoulay, Jason D; Ng, Tse Nga

    2017-01-18

    Bulk heterojunction photodiodes are fabricated using a new donor-acceptor polymer with a near-infrared absorption edge at 1.2 μm, achieving a detectivity up to 10(12) Jones at a wavelength of 1 μm and an excellent linear dynamic range of 86 dB. The photodiode detectivity is maximized by operating at zero bias to suppress dark current, while a thin 175 nm active layer is used to facilitate charge collection without reverse bias. Analysis of the temperature dependence of the dark current and spectral response demonstrates a 2.8-fold increase in detectivity as the temperature was lowered from 44 to -12 °C, a relatively small change when compared to that of inorganic-based devices. The near-infrared photodiode shows a switching speed reaching up to 120 μs without an external bias. An application using our NIR photodiode to detect arterial pulses of a fingertip is demonstrated.

  12. Near infrared polarimetry of a sample of blazars*

    Directory of Open Access Journals (Sweden)

    Pulido J. A. Acosta

    2013-12-01

    Full Text Available Polarization variability is one of the most ubiquitous characteristic of blazars. Near infrared (NIRpolarization measurements of blazars are not common, contrary to the optical ones. Nonetheless, the NIR regime can be essential to understand correlated or non-correlated behaviour between the optical and radio energy ranges. In this work, we report on NIR polarimetry measurements of a sample of 28 blazars, collected with LIRIS at WHT/La Palma in several campaigns during 2011. The majority of the blazars were observed more than one epoch using two filters (J and Ks. Here we present preliminary results for few selected targets.

  13. Monitoring Key Parameters in Bioprocesses Using Near-Infrared Technology

    Directory of Open Access Journals (Sweden)

    Elena Tamburini

    2014-10-01

    Full Text Available Near-infrared spectroscopy (NIRS is known to be a rapid and non-destructive technique for process monitoring. Bioprocesses are usually complex, from both the chemical (ill-defined medium composition and physical (multiphase matrix aspects, which poses an additional challenge to the development of robust calibrations. We investigated the use of NIRS for on-line and in-line monitoring of cell, substrate and product concentrations, during aerobic and anaerobic bacterial fermentations, in different fermentation strategies. Calibration models were built up, then validated and used for the automated control of fermentation processes. The capability of NIR in-line to discriminate among differently shaped bacteria was tested.

  14. Exploring process dynamics by near infrared spectroscopy in lactic fermentations

    DEFF Research Database (Denmark)

    Svendsen, Carina; Cieplak, Tomasz; van der Berg, Franciscus Winfried J

    2016-01-01

    In the industrial production of yoghurt, measurement of pH is normally the only in-line technique applied as a real-time monitoring signalfor following the dynamics during the fermentation process. However, every dairy company would benefit from an in-line technique giving information about...... the chemical composition, physical/textural properties and/or microbial contamination. In this study lactic fermentation batches with the starter bacteria Streptococcus thermophilus and Lactobacillus delbrueckii subsp. bulgaricus are explored by in-line near infrared (NIR) spectroscopy. The dynamics obtained...

  15. Transrectal Near-Infrared Optical Tomography for Prostate Imaging

    Science.gov (United States)

    2011-03-01

    2009. CA Cancer J Clin. 2009;59:225-249. 2. Hodge KK, McNeal JE, Stamey TA. Ultrasound guided transrectal core biopsies of the palpably abnormal...near-infrared spectroscopy: pilot results in the breast," Radiology 218, 261-266 (2001). [4] Tara Yates, Jeremy C Hebden, Adam Gibson, Nick ...digital rectal examination as screening tests for prostate carcinoma,” J Am Board Fam Pract.; 16(2):95- 101 (2003). 3. Hodge KK, McNeal JE, Stamey TA

  16. Near-infrared organic materials and emerging applications

    CERN Document Server

    Wang, Zhi Yuan

    2013-01-01

    Highlighting emerging applications of near-infrared (NIR) organic materials that are currently receiving great attention due to their potential use in optical communications, biomedicine, and camouflage materials, this cutting-edge book reviews important recent advances in an accessible style suitable for researchers and graduates in the field on organic/polymer solar cells, optical communications, and advanced optoelectronics. A beacon in the field literature, this comprehensive work discusses several areas of research and development including thermal control and emission detectors in which

  17. On the near infrared variability of chemically peculiar stars

    CERN Document Server

    Catalano, F A

    1998-01-01

    Some CP stars have recently been discovered by Catalano et al. (1991) to be variable also in the near infrared, although with smaller amplitudes than in the visible. Hence an observational campaign was started in which the infrared light variability of a number of CP2 and CP4 stars has been investigated at the ESO-La Silla Observatory in the bands J, H, and K. As a general result, infrared variations show the same behavior in all three filters but amplitudes are smaller than in the visible.

  18. Measuring moisture in cheese by near infrared absorption spectroscopy.

    Science.gov (United States)

    McKenna, D

    2001-01-01

    Data in the literature indicate that the measurement of moisture in cheese by near infrared transmittance (NIT) is more accurate than by reflectance (NIR). The accuracy of the NIT measurement (SEP) was calculated for Edam, Gouda, Brie, Colby, and Cheddar. A range of SEP values (0.12-0.35) was obtained using different methods of calibration for different types of samples. There was close agreement between these results, as they related to the precision of the reference method. The calibration validation technique described as Standard Error of Cross Validation (SECV) generated results that compared very closely to the equivalent SEP values for independent sample sets.

  19. Investigation of a near-infrared-ray computed tomography scanner

    Science.gov (United States)

    Sato, Eiichi; Oda, Yasuyuki; Satoi, Yuichi; Yamaguchi, Satoshi; Ishii, Tomotaka; Hagiwara, Osahiko; Matsukiyo, Hiroshi; Watanabe, Manabu; Kusachi, Shinya

    2016-10-01

    In the near-infrared-ray computed tomography (NIR-CT) scanner, NIR rays are produced from a light-emitting diode (LED) and detected using an NIR phototransistor (PT). The wavelengths of the LED peak intensity and the PT high sensitivity in the data table are both 940 nm. The photocurrents flowing through the PTR are converted into voltages using an emitter-follower circuit, and the output voltages are sent to a personal computer through an analog-digital converter. The NIR projection curves for tomography are obtained by repeated linear scans and rotations of the object, and the scanning is conducted in both directions of its movement.

  20. The PAH contribution to AGN near-infrared emission

    Science.gov (United States)

    Marco, O.; Brooks, K.

    In the course of building ``unified models'' of Active Galactic Nuclei, the near infrared emission in the central kilo-parsec nuclear region is a key parameter: this wavelength range corresponds to the hot to warm dust emission, which originates in the torus and the Narrow Line Region (from a few parsecs to hundreds of parsecs). The measured flux is interpreted in terms of thermal emission and, via a dust modelisation, torus models are built. Using ISAAC at VLT, we observed a sample of AGNs in order to estimate the relative contribution between the thermal continuum emission from silicate & graphite dust grains and PAH molecules.

  1. [Application of near infrared spectroscopy in analysis of wood properties].

    Science.gov (United States)

    Yao, Sheng; Pu, Jun-wen

    2009-04-01

    There is substantial interest in the improvement of wood properties through genetic selection or a change in silviculture prescription. Tree breeding purpose requires measurement of a large number of samples. However, traditional methods of assessing wood properties are both time consuming and destructive, limiting the numbers of samples that can be processed, so new method would be needed to find. Near infrared spectroscopy (NIR) is an advanced spectroscopic tool for nondestructive evaluation of wood and it can quickly, accurately estimate the properties of increment core, solid wood or wood meal. The present paper reviews the advances in the research on the wood chemistry properties and anatomical properties using NIR.

  2. Modal Identification from Ambient Responses Using Frequency Domain Decomposition

    DEFF Research Database (Denmark)

    Brincker, Rune; Zhang, Lingmi; Andersen, Palle

    2000-01-01

    In this paper a new frequency domain technique is introduced for the modal identification from ambient responses, i.e. in the case where the modal parameters must be estimated without knowing the input exciting the system. By its user friendliness the technique is closely related to the classical...

  3. Modal Identification from Ambient Responses using Frequency Domain Decomposition

    DEFF Research Database (Denmark)

    Brincker, Rune; Zhang, L.; Andersen, P.

    2000-01-01

    In this paper a new frequency domain technique is introduced for the modal identification from ambient responses, ie. in the case where the modal parameters must be estimated without knowing the input exciting the system. By its user friendliness the technique is closely related to the classical...

  4. A Frequency Domain Design Method For Sampled-Data Compensators

    DEFF Research Database (Denmark)

    Niemann, Hans Henrik; Jannerup, Ole Erik

    1990-01-01

    A new approach to the design of a sampled-data compensator in the frequency domain is investigated. The starting point is a continuous-time compensator for the continuous-time system which satisfy specific design criteria. The new design method will graphically show how the discrete...

  5. Frequency-domain thermal modelling of power semiconductor devices

    DEFF Research Database (Denmark)

    Ma, Ke; Blaabjerg, Frede; Andresen, Markus

    2015-01-01

    to correctly predict the device temperatures, especially when considering the thermal grease and heat sink attached to the power semiconductor devices. In this paper, the frequency-domain approach is applied to the modelling of thermal dynamics for power devices. The limits of the existing RC lump...

  6. Automated Frequency Domain Decomposition for Operational Modal Analysis

    DEFF Research Database (Denmark)

    Brincker, Rune; Andersen, Palle; Jacobsen, Niels-Jørgen

    2007-01-01

    The Frequency Domain Decomposition (FDD) technique is known as one of the most user friendly and powerful techniques for operational modal analysis of structures. However, the classical implementation of the technique requires some user interaction. The present paper describes an algorithm for au...

  7. Measuring stellar magnetic fields from high resolution spectroscopy of near-infrared lines

    Science.gov (United States)

    Leone, F.; Vacca, W. D.; Stift, M. J.

    2003-10-01

    Zeeman splitting of otherwise degenerate levels provides a straight-forward method of measuring stellar magnetic fields. In the optical, the relative displacements of the Zeeman components are quite small compared to the rotational line broadening, and therefore observations of Zeeman splitting are usually possible only for rather strong magnetic fields in very slowly rotating stars. However, the magnitude of the Zeeman splitting is proportional to the square of the wavelength, whereas rotational line broadening mechanisms are linear in wavelength; therefore, there is a clear advantage in using near-infrared spectral lines to measure surface stellar magnetic fields. We have obtained high resolution (R >= 25 000) spectra in the 15 625-15 665 Å region for two magnetic chemically peculiar stars, viz. HD 176232 and HD 201601, and for the suspected magnetic chemically peculiar star HD 180583, as part of a pilot study aimed at determining the accuracy with which we can measure stellar magnetic fields using the Zeeman splitting of near-infrared lines. We confirm that in principle the magnetic field strength can be estimated from the magnetic intensification of spectral lines, i.e. the increase in equivalent width of a line over the zero-field value. However, due to line blending as well as the dependence of this intensification on abundance and field geometry, accurate estimates of the magnetic field strengths can be obtained only by modelling the line profiles by means of spectral synthesis techniques. Using this approach, we find a 1.4 kG magnetic field modulus in HD 176132 and an upper limit of 0.2 kG in HD 180583. The very weak infrared lines in the spectrum of HD 201601 are consistent with a 3.9 kG field modulus estimated from the splitting of the Fe II 6149.258 Å line seen in an optical spectrum. Finally, we would like to draw attention to the fact that there are no sufficiently detailed and reliable atomic line lists available for the near-infrared region that

  8. Ischemic stroke assessment with near-infrared spectroscopy

    Science.gov (United States)

    Chen, Weiguo; Li, Pengcheng; Zeng, Shaoqun; Luo, Qingming; Hu, Bo

    1999-09-01

    Many authors have elucidated the theory about oxygenated hemoglobin, deoxygenated hemoglobin absorption in near-infrared spectrum. And the theory has opened a window to measure the hemodynamic changes caused by stroke. However, no proper animal model still has established to confirm the theory. The aim of this study was to validate near-infrared cerebral topography (NCT) as a practical tool and to try to trace the focal hemodynamic changes of ischemic stroke. In the present study, middle cerebral artery occlusion model and the photosensitizer induced intracranial infarct model had been established. NCT and functional magnetic resonance image (fMRI) were obtained during pre- and post-operation. The geometric shape and infarct area of NCT image was compared with the fMRI images and anatomical samples of each rat. The results of two occlusion models in different intervene factors showed the NCT for infarct focus matched well with fMRI and anatomic sample of each rats. The instrument might become a practical tool for short-term prediction of stroke and predicting the rehabilitation after stroke in real time.

  9. Length-free near infrared measurement of newborn malnutrition

    Science.gov (United States)

    Mustafa, Fatin Hamimi; Bek, Emily J.; Huvanandana, Jacqueline; Jones, Peter W.; Carberry, Angela E.; Jeffery, Heather E.; Jin, Craig T.; McEwan, Alistair L.

    2016-11-01

    Under-nutrition in neonates can cause immediate mortality, impaired cognitive development and early onset adult disease. Body fat percentage measured using air-displacement-plethysmography has been found to better indicate under-nutrition than conventional birth weight percentiles. However, air-displacement-plethysmography equipment is expensive and non-portable, so is not suited for use in developing communities where the burden is often the greatest. We proposed a new body fat measurement technique using a length-free model with near-infrared spectroscopy measurements on a single site of the body - the thigh. To remove the need for length measurement, we developed a model with five discrete wavelengths and a sex parameter. The model was developed using air-displacement-plethysmography measurements in 52 neonates within 48 hours of birth. We identified instrumentation required in a low-cost LED-based screening device and incorporated a receptor device that can increase the amount of light collected. This near-infrared method may be suitable as a low cost screening tool for detecting body fat levels and monitoring nutritional interventions for malnutrition in neonates and young children in resource-constrained communities.

  10. Advancing Nebular Astrophysics through Near-Infrared Spectroscopic Mapping

    Science.gov (United States)

    Waller, William H.; Kutyrev, A.; Silverberg, R.; Woodgate, B.; Allen, L.

    2006-12-01

    Infrared continuum surveys, optical emission-line surveys, and radio CO and HI surveys have revealed the star-forming ISM as a complex "froth" of shells, filaments, blobs, and myriad "working surfaces" whose origin and evolution remain poorly understood. The generic relations between these nebular structures and the embedded star clusters that have been discovered in abundance throughout the Galaxy by the Spitzer Space Telescope have yet to be deciphered. To address these challenges, we consider the options for carrying out wide-field narrow-band imaging surveys of the near-infrared line emission from the Milky Way and other nearby star-forming galaxies. The near-IR part of the EM spectrum is rich with diagnostic nebular emission features. We draw from the experiences gained from the ABU/SPIREX near-IR telescope that operated in Antarctica in the late 1990s, and from the Brackett-Alpha Mapper (BAM) -a Fabry-Perot spectrometer that successfully measured kinematics of the warm-ionized hydrogen gas in the northern Milky Way. Options for deploying a multi-line near-infrared spectroscopic mapper on SOFIA, high-altitude balloons, and the lunar surface will be discussed.

  11. Near-infrared neuroimaging with NinPy

    Directory of Open Access Journals (Sweden)

    Gary E Strangman

    2009-05-01

    Full Text Available There has been substantial recent growth in the use of non-invasive optical brain imaging in studies of human brain function in health and disease. Near-infrared neuroimaging (NIN is one of the most promising of these techniques and, although NIN hardware continues to evolve at a rapid pace, software tools supporting optical data acquisition, image processing, statistical modeling and visualization remain less refined. Python, a modular and computationally efficient development language, can support functional neuroimaging studies of diverse design and implementation. In particular, Python's easily readable syntax and modular architecture allow swift prototyping followed by efficient transition to stable production systems. As an introduction to our ongoing efforts to develop Python software tools for structural and functional neuroimaging, we discuss: (i the role of noninvasive diffuse optical imaging in measuring brain function, (ii the key computational requirements to support NIN experiments, (iii our collection of software tools to support near-infrared neuroimaging, called NinPy, and (iv future extensions of these tools that will allow integration of optical with other structural and functional neuroimaging data sources. Source code for the software discussed here will be made available at www.nmr.mgh.harvard.edu/Neural_SystemsGroup/software.html.

  12. Type Ia Supernova as Standard Candles in the Near Infrared

    Science.gov (United States)

    Wood-Vasey, Michael; Garnavich, Peter; Matheson, Thomas; Jha, Saurabh; Rest, Armin; Allen, Lori

    2011-08-01

    We propose to observe 15 SNeIa in the near infrared (NIR) with WHIRC on the WIYN telescope during 12 nights of bright time in 2011B. These observations will create an infrared Hubble diagram extending to z~0.1 to verify recent evidence that SNIa are excellent standard candles in the NIR. We will observe 15 SNeIa at 0.02color evolution in the near infrared where dust extinction is significantly reduced. In addition these NIR data will allow us to (1) explore the recent correlation between optical luminosity and host galaxy mass; (2) improve our understanding of intrinsic colors of SNeIa, (3) and study the nature of dust in galaxies beyond our Milky Way. Our ideal observing plan would consist of nights spaced every three days in each of four consecutive lunations in 2011B. This is a pilot proposal. If successful, this project will lead to a larger survey to obtain NIR luminosity distances to 100 SNeIa out to z<0.1 to provide a solid anchor for measuring luminosity distances in the Universe. We are not asking for long-term status at this time.

  13. NIRS3: The Near Infrared Spectrometer on Hayabusa2

    Science.gov (United States)

    Iwata, Takahiro; Kitazato, Kohei; Abe, Masanao; Ohtake, Makiko; Arai, Takehiko; Arai, Tomoko; Hirata, Naru; Hiroi, Takahiro; Honda, Chikatoshi; Imae, Naoya; Komatsu, Mutsumi; Matsunaga, Tsuneo; Matsuoka, Moe; Matsuura, Shuji; Nakamura, Tomoki; Nakato, Aiko; Nakauchi, Yusuke; Osawa, Takahito; Senshu, Hiroki; Takagi, Yasuhiko; Tsumura, Kohji; Takato, Naruhisa; Watanabe, Sei-ichiro; Barucci, Maria Antonietta; Palomba, Ernesto; Ozaki, Masanobu

    2017-03-01

    NIRS3: The Near Infrared Spectrometer is installed on the Hayabusa2 spacecraft to observe the target C-type asteroid 162173 Ryugu at near infrared wavelengths of 1.8 to 3.2 μm. It aims to obtain reflectance spectra in order to detect absorption bands of hydrated and hydroxide minerals in the 3 μm-band. We adopted a linear-image sensor with indium arsenide (InAs) photo diodes and a cooling system with a passive radiator to achieve an optics temperature of 188 K ( -85°C), which enables to retaining sufficient sensitivity and noise level in the 3 μm wavelength region. We conducted ground performance tests for the NIRS3 flight model (FM) to confirm its baseline specifications. The results imply that the properties such as the signal-to-noise ratio (SNR) conform to scientific requirements to determine the degree of aqueous alteration, such as CM or CI chondrite, and the stage of thermal metamorphism on the asteroid surface.

  14. Infrared and Near-Infrared Spectroscopy of Acetylacetone and Hexafluoroacetylacetone.

    Science.gov (United States)

    Howard, Daryl L; Kjaergaard, Henrik G; Huang, Jing; Meuwly, Markus

    2015-07-23

    The infrared and near-infrared spectra of acetylacetone, acetylacetone-d8, and hexafluoroacetylacetone are characterized from experiment and computations at different levels. In the fundamental region, the intramolecular hydrogen bonded OH-stretching transition is clearly observed as a very broad band with substantial structure and located at significantly lower frequency compared to common OH-stretching frequencies. There is no clear evidence for OH-stretching overtone transitions in the near-infrared region, which is dominated by the CH-stretching overtones of the methine and methyl CH bonds. From molecular dynamics (MD) simulations, with a potential energy surface previously validated for tunneling splittings, the infrared spectra are determined and used in assigning the experimentally measured ones. It is found that the simulated spectrum in the region associated with the proton transfer mode is exquisitely sensitive to the height of the barrier for proton transfer. Comparison of the experimental and the MD simulated spectra establishes that the barrier height is around 2.5 kcal/mol, which favorably compares with 3.2 kcal/mol obtained from high-level electronic structure calculations.

  15. NIRS3: The Near Infrared Spectrometer on Hayabusa2

    Science.gov (United States)

    Iwata, Takahiro; Kitazato, Kohei; Abe, Masanao; Ohtake, Makiko; Arai, Takehiko; Arai, Tomoko; Hirata, Naru; Hiroi, Takahiro; Honda, Chikatoshi; Imae, Naoya; Komatsu, Mutsumi; Matsunaga, Tsuneo; Matsuoka, Moe; Matsuura, Shuji; Nakamura, Tomoki; Nakato, Aiko; Nakauchi, Yusuke; Osawa, Takahito; Senshu, Hiroki; Takagi, Yasuhiko; Tsumura, Kohji; Takato, Naruhisa; Watanabe, Sei-ichiro; Barucci, Maria Antonietta; Palomba, Ernesto; Ozaki, Masanobu

    2017-07-01

    NIRS3: The Near Infrared Spectrometer is installed on the Hayabusa2 spacecraft to observe the target C-type asteroid 162173 Ryugu at near infrared wavelengths of 1.8 to 3.2 μm. It aims to obtain reflectance spectra in order to detect absorption bands of hydrated and hydroxide minerals in the 3 μm-band. We adopted a linear-image sensor with indium arsenide (InAs) photo diodes and a cooling system with a passive radiator to achieve an optics temperature of 188 K (-85°C), which enables to retaining sufficient sensitivity and noise level in the 3 μm wavelength region. We conducted ground performance tests for the NIRS3 flight model (FM) to confirm its baseline specifications. The results imply that the properties such as the signal-to-noise ratio (SNR) conform to scientific requirements to determine the degree of aqueous alteration, such as CM or CI chondrite, and the stage of thermal metamorphism on the asteroid surface.

  16. The Surface of 2003EL61 in the Near Infrared

    CERN Document Server

    Trujillo, C A; Barkume, K M; Schaller, E L; Rabinowitz, D L

    2006-01-01

    We report the detection of crystalline water ice on the surface of 2003EL61. Reflectance spectra were collected from Gemini North telescope from 1.0 to 2.4 micron wavelength range, and from the Keck telescope across the 1.4 to 2.4 micron wavelength range. The signature of crystalline water ice is clear and obvious in all data collected. Like the surface of many outer solar system bodies, the surface of 2003EL61 is rich in crystalline water ice, which is energetically less favored than amorphous water ice at cold temperatures, suggesting resurfacing processes may be taking place. The near infrared color of the object is much bluer than a pure water ice model. Adding a near infrared blue component such as hydrogen cyanide or phyllosilicate clays improves the fit considerably, with hydrogen cyanide providing the greatest improvement. The addition of hydrated tholins and bitumens also improves the fit but is inconsistent with the neutral V-J reflectance of 2003EL61. A small decrease in reflectance beyond 2.3 micr...

  17. Application of ceramic phosphors for near infrared biomedical imaging technologies

    Science.gov (United States)

    Soga, Kohei; Tokuzen, Kimikazu; Tsuji, Kosuke; Yamano, Tomoyoshi; Venkatachalam, Nallusamy; Hyodo, Hiroshi; Kishimoto, Hidehiro

    2010-02-01

    Near infrared wavelength region between 0.8 and 2 μm is an attractive region for biomedical imaging due to the low loss in biomedical objects in the region. Rare-earth doped ceramic phosphors are known to emit efficient fluorescence in the same wavelength region. The authors have developed micro fluorescence bioimaging system for cellular or tissue imaging and macro one for in vivo imaging. This paper will review the materials synthesis for the near infrared fluorescence probes as well as the system development and demonstrative works. Er-doped or Yb/Er-doped ceramic phosphors were synthesized with required particle size. The phosphors were partly modified with polyethylene glycol to give dispersion and controlled interaction with the biological objects. By using the micro imaging system, nematodes, mouse tissue and M1 cells were observed by detecting 1.5 μm emission from Er doped in the ceramic phosphor. in vivo imaging with the same fluorescence scheme was also performed for the digestive organs of live mouse.

  18. A rapid and sensitive method for the evaluation of cereal grains in bioethanol production using near infrared reflectance spectroscopy.

    Science.gov (United States)

    Pohl, Ferdinand; Senn, Thomas

    2011-02-01

    The potential of near infrared spectroscopy (NIRS) for determining fermentable substance and also ethanol yield in wheat, rye and triticale grains as a feedstock for fuel ethanol production was investigated. The total sample set contained 480 samples of 10 types of wheat, 24 types of triticale and 6 types of rye, which were grown on 10 locations in Germany from 2006 to 2008. Samples were scanned by NIRS as whole or ground grains, and their reference values regressed against different spectral transformations by partial least squares regression (PLS-1). Ground grains were scanned on a dispersive NIR-Spectrometer. Whole grains were scanned on a diode array NIR-Spectrometer. Principal Component Analysis (PCA) revealed that samples could be classified by crop season, growth location and species. It is shown that near infrared spectroscopy is an appropriate and useful tool for prediction of biofuel yield for both industry and research.

  19. Simulation of power fluctuation of wind farms based on frequency domain

    DEFF Research Database (Denmark)

    Lin, Jin; Sun, Yuanzhang; Li, Guojie

    2011-01-01

    With the capacity of installed wind power generators steadily increasing in China, power fluctuation from wind farms will significantly affect the security and reliability of the power system. Traditional modeling of power fluctuation is based on the time domain or statistics methodology which...... the power spectral density of wind speed, the frequency domain model of a wind power generator and the information on weather and geography of the wind farms. The correctness and effectiveness of the model are verified by comparing the measurement data with simulation results of a certain wind farm. © 2011...

  20. Regressive Analysis on Leaf Nitrogen Content and Near Infrared Reflectance and Its Application for Agricultural Farm Monitoring with Helicopter Mounted Near Infrared Camera

    Directory of Open Access Journals (Sweden)

    Kohei Arai

    2013-03-01

    Full Text Available Method for evaluation of nitrogen richness of tealeaves with near infrared reflectance is proposed. Also tea farm monitoring with helicopter mounted near infrared camera is proposed. Through experiments and regressive analysis, it is found that the proposed method and monitoring system is validated.

  1. Rapid detection method of soil organic matter contents using visible/near infrared diffuse reflectance spectral%基于可见/近红外漫反射光谱的土壤有机质含量估算方法研究

    Institute of Scientific and Technical Information of China (English)

    岑益郎; 宋韬; 何勇; 鲍一丹

    2011-01-01

    The effect of different soil particle sizes on the visible/near infrared spectra to detect soil organic matter contents was analyzed. The visible/near infrared spectra of soil samples with the particle sizes of 0. 169-2 mm and <0. 169 mm were measured at the range of 325-1 075 nm. Then the principal component analysis-hack propagation neural network (PCA-BPNN), least squarea-support vector machine (LS-SVM) and partial least squares (PLS) models were established to detect the soil organic matter contents. When the soil particle size range was from 0. 169 to 2 mm, the correlation coefficients (r) of prediction of all three models were above 0. 84 and root mean square errors of prediction (RMSEP) were below 0. 20. When the soil particle size range was smaller than 0. 169 mm, the r values of the models were below 0. 71 and RMSEPs were above 0. 23. When either the soil particle size range was from 0. 169 to 2 mm or smaller than 0. 169 mm, PLS models obtained better results than LS-SVM and PCA-BPNN models. The overall results show that the difference of soil particle size can significantly affect the prediction results of visible/near infrared spectra to detect the soil organic matter contents.%为研究不同土壤颗粒粒径对可见/近红外光谱分析技术在土壤有机质含量快速检测应用中的影响,获取粒径为0.169~2 mm和<0.169 mm的2种土壤样本(各53个)的可见/近红外光谱(325~1075 nm),分别建立各自的主成分-反向传播神经网络(PCA-BPNN)、最小二乘-支持向量机(LS-SVM)和偏最小二乘法(PLS)土壤有机质含量检测模型.结果表明:当土壤粒径为0.169~2 mm时,所建立模型的土壤有机质含量预测相关系数r均在0.84以上,且预测均方根误差(RMSEP)都在0.20以下;而当土壤粒径<0.169 mm时,所建立模型的预测相关系数r均不超过0.71.而RMSEP都在0.23以上;对于相同粒径的土壤,PLS模型对土壤有机质含量的预测效果优于LS-SVM和PCA-BPNN模型.

  2. Near infrared spectra indicate specific mutant endosperm genes and reveal a new mechanism for substituting starch with (1-->3,1-->4)-[beta]-glucan in barley

    DEFF Research Database (Denmark)

    Munck, L.; Møller, B.; Jacobsen, Susanne

    2004-01-01

    Near Infrared Reflectance spectroscopy was tested as a screening method to characterise high lysine mutants from a barley collection by classification through Principal Component Analysis (PCA). Mean spectra of the samples within each cluster identified gene-specific patterns in the 2270-2360 nm ...... the phenotype by chemometric classification of a spectral library, representing the digitised phenome from a barley gene bank....

  3. The near infrared (0.8-2.6 mu m) absorption spectrum of a dense sodium vapor and possible mechanisms of the spectrum formation

    NARCIS (Netherlands)

    Grigoryan, GG; Leonov, AG; Manykin, EA; Rudenko, AA; Sitnikov, MG; Starostin, AN

    2003-01-01

    The absorption coefficient of a dense sodium vapor (N(0)similar to10(17)-10(18) cm(-3)) in the near infrared spectral range (0.8-2.6 mum) was measured in a homogeneously heated isolated cell. In the range of parameters studied, the sample exhibits significant absorption. Neither the observed spectra

  4. Design of a Solar Greenhouse with Energy Delivery by the Conversion of Near Infrared Radiation - Part 1 Optics and PV-cells

    NARCIS (Netherlands)

    Sonneveld, Piet; Swinkels, Gert-Jan; Bot, G.P.A.

    2009-01-01

    In this paper the design and development of a new type of greenhouse with an integrated filter for reflecting near infrared radiation (NIR) and a solar energy delivery system is described. Especially the optical parts as the spectral selective film, the properties of the circular reflector and the e

  5. Observations of the Near-Infrared Spectrum of the Zodiacal Light with CIBER

    CERN Document Server

    Tsumura, K; Bock, J; Cooray, A; Hristov, V; Keating, B; Lee, D H; Levenson, L R; Mason, P; Matsumoto, T; Matsuura, S; Nam, U W; Renbarger, T; Sullivan, I; Suzuki, K; Wada, T; Zemcov, M

    2010-01-01

    Interplanetary dust (IPD) scatters solar radiation which results in the zodiacal light that dominates the celestial diffuse brightness at optical and near-infrared wavelengths. Both asteroid collisions and cometary ejections produce the IPD, but the relative contribution from these two sources is still unknown. The Low Resolution Spectrometer (LRS) onboard the Cosmic Infrared Background Experiment (CIBER) observed the astrophysical sky spectrum between 750 and 2100 nm over a wide range of ecliptic latitude. The resulting zodiacal light spectrum is redder than the solar spectrum, and shows a broad absorption feature, previously unreported, at approximately 900 nm, suggesting the existence of silicates in the IPD material. The spectral shape of the zodiacal light is isotropic at all ecliptic latitudes within the measurement error. The zodiacal light spectrum, including the extended wavelength range to 2500 nm using IRTS data, is qualitatively similar to the reflectance of S-type asteroids. This result can be ex...

  6. Outlier detection in near-infrared spectroscopic analysis by using Monte Carlo cross-validation

    Institute of Scientific and Technical Information of China (English)

    LIU ZhiChao; CAI WenSheng; SHAO XueGuang

    2008-01-01

    An outlier detection method is proposed for near-infrared spectral analysis. The underlying philosophy of the method is that, in random test (Monte Carlo) cross-validation, the probability of outliers pre-senting in good models with smaller prediction residual error sum of squares (PRESS) or in bad mod-els with larger PRESS should be obviously different from normal samples. The method builds a large number of PLS models by using random test cross-validation at first, then the models are sorted by the PRESS, and at last the outliers are recognized according to the accumulative probability of each sam-ple in the sorted models. For validation of the proposed method, four data sets, including three pub-lished data sets and a large data set of tobacco lamina, were investigated. The proposed method was proved to be highly efficient and veracious compared with the conventional leave-one-out (LOO) cross validation method.

  7. Non-destructive prediction of quality of intact apple using near infrared spectroscopy.

    Science.gov (United States)

    Jha, S N; Garg, Ruchi

    2010-03-01

    Potential of near infrared spectroscopy (NIRS) in the wavelength range of 900-1700 nm for determination of sweetness (total soluble solids, TSS); sourness (acidity) and their ratio for 5 cultivars of apple was studied. Partial least square and multiple linear regression (MLR) employing pre-processing techniques were carried out. MLR models were found to be the best for prediction after treating the spectral data with multiple scatter correction technique. The multiple correlation coefficients for calibration and validation were found to be 0.887, 0.745 °Brix for TSS, 0.890, 0.752 % for acidity and 0.893, 0.751 for acidity/TSS ratio, respectively. The standard errors of calibration, prediction, biases and differences in them were low, which indicated that NIRS has potential to predict internal quality of apple non-destructively.

  8. Single-photon emission in the near infrared from diamond colour centre

    Energy Technology Data Exchange (ETDEWEB)

    Wu, E [Laboratoire de Photonique Quantique et Moleculaire, UMR CNRS 8537, ENS de Cachan, 61 avenue du President Wilson, 94235 Cachan Cedex (France); Key Laboratory of Optical and Magnetic Resonance Spectroscopy, East China Normal University, 3663 Zhongshan Road North, Shanghai 200062 (China); Jacques, V. [Laboratoire de Photonique Quantique et Moleculaire, UMR CNRS 8537, ENS de Cachan, 61 avenue du President Wilson, 94235 Cachan Cedex (France); Treussart, F. [Laboratoire de Photonique Quantique et Moleculaire, UMR CNRS 8537, ENS de Cachan, 61 avenue du President Wilson, 94235 Cachan Cedex (France)]. E-mail: francois.treussart@physique.ens-cachan.fr; Zeng, H. [Key Laboratory of Optical and Magnetic Resonance Spectroscopy, East China Normal University, 3663 Zhongshan Road North, Shanghai 200062 (China); Grangier, P. [Laboratoire Charles Fabry de l' Institut d' Optique, UMR CNRS 8501, BP 147, 91403 Orsay Cedex (France); Roch, J.-F. [Laboratoire de Photonique Quantique et Moleculaire, UMR CNRS 8537, ENS de Cachan, 61 avenue du President Wilson, 94235 Cachan Cedex (France)

    2006-07-15

    Optically active colour centres based on nickel-nitrogen impurities are observed in natural diamond under continuous-wave excitation. The spectral analysis shows that the single emitters have a narrow band emission in the near infrared, around 780 nm, which is almost entirely concentrated in the zero phonon line even at room temperature. The colour centre excited-state lifetime is as short as 2 ns, and the photoluminescence light is linear polarized. These striking features pave the way to the realization of a triggered single-photon source based on this colour centre emission well suited for open-air single-photon Quantum Key Distribution operating in day-light conditions.

  9. Modelling of sensory and instrumental texture parameters in processed cheese by near infrared reflectance spectroscopy.

    Science.gov (United States)

    Blazquez, Carmen; Downey, Gerard; O'Callaghan, Donal; Howard, Vincent; Delahunty, Conor; Sheehan, Elizabeth; Everard, Colm; O'Donnell, Colm P

    2006-02-01

    This study investigated the application of near infrared (NIR) reflectance spectroscopy to the measurement of texture (sensory and instrumental) in experimental processed cheese samples. Spectra (750 to 2498 nm) of cheeses were recorded after 2 and 4 weeks storage at 4 degrees C. Trained assessors evaluated 9 sensory properties, a texture profile analyser (TPA) was used to record 5 instrumental parameters and cheese 'meltability' was measured by computer vision. Predictive models for sensory and instrumental texture parameters were developed using partial least squares regression on raw or pre-treated spectral data. Sensory attributes and instrumental texture measurements were modelled with sufficient accuracy to recommend the use of NIR reflectance spectroscopy for routine quality assessment of processed cheese.

  10. A Near-Infrared (NIR) Global Multispectral Map of the Moon from Clementine

    Science.gov (United States)

    Eliason, E. M.; Lee, E. M.; Becker, T. L.; Weller, L. A.; Isbell, C. E.; Staid, M. I.; Gaddis, L. R.; McEwen, A. S.; Robinson, M. S.; Duxbury, T.

    2003-01-01

    In May and June of 1994, the NASA/DoD Clementine Mission acquired global, 11- band, multispectral observations of the lunar surface using the ultraviolet-visible (UVVIS) and near-infrared (NIR) camera systems. The global 5-band UVVIS Digital Image Model (DIM) of the Moon at 100 m/pixel was released to the Planetary Data System (PDS) in 2000. The corresponding NIR DIM has been compiled by the U.S. Geological Survey for distribution to the lunar science community. The recently released NIR DIM has six spectral bands (1100, 1250, 1500, 2000, 2600, and 2780 nm) and is delivered in 996 quads at 100 m/pixel (303 pixels/degree). The NIR data were radiometrically corrected, geometrically controlled, and photometrically normalized to form seamless, uniformly illuminated mosaics of the lunar surface.

  11. Retrieval of Precise Radial Velocities from Near-Infrared High Resolution Spectra of Low Mass Stars

    CERN Document Server

    Gao, Peter; Gagné, Jonathan; Furlan, Elise; Bottom, Michael; Anglada-Escudé, Guillem; White, Russel; Davison, Cassy; Beichman, Charles; Brinkworth, Carolyn; Johnson, John; Ciardi, David; Wallace, James; Mennesson, Bertrand; von Braun, Kaspar; Vasisht, Gautam; Prato, Lisa; Kane, Stephen; Tanner, Angelle; Crawford, Timothy; Latham, David; Rougeot, Raphaël; Geneser, Claire; Catanzarite, Joseph

    2016-01-01

    Given that low-mass stars have intrinsically low luminosities at optical wavelengths and a propensity for stellar activity, it is advantageous for radial velocity (RV) surveys of these objects to use near-infrared (NIR) wavelengths. In this work we describe and test a novel RV extraction pipeline dedicated to retrieving RVs from low mass stars using NIR spectra taken by the CSHELL spectrograph at the NASA Infrared Telescope Facility, where a methane isotopologue gas cell is used for wavelength calibration. The pipeline minimizes the residuals between the observations and a spectral model composed of templates for the target star, the gas cell, and atmospheric telluric absorption; models of the line spread function, continuum curvature, and sinusoidal fringing; and a parameterization of the wavelength solution. The stellar template is derived iteratively from the science observations themselves without a need for separate observations dedicated to retrieving it. Despite limitations from CSHELL's narrow wavelen...

  12. How to predict the sugariness and hardness of melons: A near-infrared hyperspectral imaging method.

    Science.gov (United States)

    Sun, Meijun; Zhang, Dong; Liu, Li; Wang, Zheng

    2017-03-01

    Hyperspectral imaging (HSI) in the near-infrared (NIR) region (900-1700nm) was used for non-intrusive quality measurements (of sweetness and texture) in melons. First, HSI data from melon samples were acquired to extract the spectral signatures. The corresponding sample sweetness and hardness values were recorded using traditional intrusive methods. Partial least squares regression (PLSR), principal component analysis (PCA), support vector machine (SVM), and artificial neural network (ANN) models were created to predict melon sweetness and hardness values from the hyperspectral data. Experimental results for the three types of melons show that PLSR produces the most accurate results. To reduce the high dimensionality of the hyperspectral data, the weighted regression coefficients of the resulting PLSR models were used to identify the most important wavelengths. On the basis of these wavelengths, each image pixel was used to visualize the sweetness and hardness in all the portions of each sample.

  13. New quasars behind the Magellanic Clouds. Spectroscopic confirmation of near-infrared selected candidates

    CERN Document Server

    Ivanov, Valentin D; Bekki, Kenji; de Grijs, Richard; Emerson, Jim; Gibson, Brad K; Kamath, Devika; van Loon, Jacco Th; Piatti, Andres E; For, Bi-Qing

    2015-01-01

    Quasi--stellar objects (quasars) located behind nearby galaxies provide an excellent absolute reference system for astrometric studies, but they are difficult to identify because of fore- and background contamination. Deep wide--field, high angular resolution surveys spanning the entire area of nearby galaxies are needed to obtain a complete census of such quasars. We embarked on a program to expand the quasar reference system behind the Large and the Small Magellanic Clouds, the Magellanic Bridge, and the Magellanic Stream, connecting the Clouds with the Milky Way. Hundreds of quasar candidates were selected based on their near--infrared colors and variability properties from the ongoing public ESO VISTA Magellanic Clouds survey. A subset of 49 objects was followed up with optical spectroscopy. We confirmed the quasar nature of 37 objects (34 new identifications), four are low redshift objects, three are probably stars, and the remaining three lack prominent spectral features for a secure classification; bon...

  14. Gastric cancer target detection using near-infrared hyperspectral imaging with chemometrics

    Science.gov (United States)

    Yi, Weisong; Zhang, Jian; Jiang, Houmin; Zhang, Niya

    2014-09-01

    Gastric cancer is one of the leading causes of cancer death in the world due to its high morbidity and mortality. Hyperspectral imaging (HSI) is an emerging, non-destructive, cutting edge analytical technology that combines conventional imaging and spectroscopy in one single system. The manuscript has investigated the application of near-infrared hyperspectral imaging (900-1700 nm) (NIR-HSI) for gastric cancer detection with algorithms. Major spectral differences were observed in three regions (950-1050, 1150-1250, and 1400-1500 nm). By inspecting cancerous mean spectrum three major absorption bands were observed around 975, 1215 and 1450 nm. Furthermore, the cancer target detection results are consistent and conformed with histopathological examination results. These results suggest that NIR-HSI is a simple, feasible and sensitive optical diagnostic technology for gastric cancer target detection with chemometrics.

  15. Outlier detection in near-infrared spectroscopic analysis by using Monte Carlo cross-validation

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    An outlier detection method is proposed for near-infrared spectral analysis. The underlying philosophy of the method is that,in random test(Monte Carlo) cross-validation,the probability of outliers presenting in good models with smaller prediction residual error sum of squares(PRESS) or in bad models with larger PRESS should be obviously different from normal samples. The method builds a large number of PLS models by using random test cross-validation at first,then the models are sorted by the PRESS,and at last the outliers are recognized according to the accumulative probability of each sample in the sorted models. For validation of the proposed method,four data sets,including three published data sets and a large data set of tobacco lamina,were investigated. The proposed method was proved to be highly efficient and veracious compared with the conventional leave-one-out(LOO) cross validation method.

  16. Eliminating the interference pattern in near-infrared spectra used for identification of thin plastic foils.

    Science.gov (United States)

    Jeszenszky, Eva; Kocsányi, Lászlo; Richter, Péter

    2004-06-01

    A Fourier type filtering method is proposed for the pretreatment of near-infrared (NIR) spectra of thin (plastic foils before their identification by means of multivariate calibration methods. The interference of multiply reflected beams from the boundary surfaces of the foil causes a disturbing signal component in the spectrum and the identification becomes impossible. The purpose of the filtering is to eliminate the interference pattern from the spectrum. In the Fourier transformed NIR spectrum against the wavenumber there appears a discrete spectral component caused by the interference. This component can be recognized and cut off. After inverse Fourier transformation of such pretreated spectra, absorption peaks are free from interference modulation, so application of multivariate calibration methods is much more effective. With principal component analysis (PCA) on cluster plots, visual distinction between different plastics becomes possible. Correct class membership is provided by use of the Mahalanobis distance.

  17. The Formation of Massive Stars: from Herschel to Near-Infrared

    Directory of Open Access Journals (Sweden)

    Paolo Persi

    2014-12-01

    Full Text Available We have studied a number of selected high mass star forming regions, including high resolution near-infrared broad- and narrow-band imaging, Herschel (70, 160, 250, 350 and 500 μm and Spitzer (3.6, 4.5, 5.8 and 8.0 m images. The preliminary results of one of this region, IRAS 19388+2357(MOL110 are discussed. In this region a dense core has been detected in the far-infrared, and a young stellar cluster has been found around this core. Combining near-IR data with Spitzer and Herschel photometry we have derived the spectral energy distribution of Mol110. Finally comparing our H2 and Kc narrow-band images, we have found an H2 jet in this region.

  18. Iron variation within a granitic pluton as determined by near-infrared reflectance

    Science.gov (United States)

    Baird, A. K.

    1984-01-01

    One-hundred fifty-one previously chemically analyzed samples of tonalite from the Lakeview Mountains pluton, southern California batholith, were analyzed for their iron content using near-infrared spectrophotometry. Compared to the earlier analyses of the same sample set by X-ray fluorescence spectrography, the infrared data have higher analytical variance but clearly define patterns of compositional zonation in the pluton which are closely similar to those patterns obtained from X-ray data; petrogenetic interpretations for the pluton would be the same from either data set. Infrared spectral data can be obtained directly in the field with relatively simple instruments and field measurements can be made to average local heterogeneities that often mask significant plutonic variations.

  19. High-Contrast Near-Infrared Imaging Polarimetry of the Protoplanetary Disk around RY Tau

    CERN Document Server

    Takami, Michihiro; Hashimoto, Jun; Kim, Hyosun; Wisnewski, John; Henning, Thomas; Grady, Carol A; Kandori, Ryo; Hodapp, Klaus W; Kudo, Tomoyuki; Kusakabe, Nobuhiko; Chou, Mei-Yin; Itoh, Yoichi; Momose, Munetake; Mayama, Satoshi; Currie, Thayne; Follette, Katherine B; Kwon, Jungmi; Abe, Lyu; Brandner, Wolfgang; Brandt, Timothy D; Carson, Joseph; Egner, Sebastian E; Feldt, Markus; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko; Ishii, Miki; Iye, Masanori; Janson, Markus; Knapp, Gillian R; Kuzuhara, Masayuki; McElwain, Michael W; Matsuo, Taro; Miyama, Shoken; Morino, Jun-Ichi; Moro-Martin, Amaya; Nishimura, Tetsuo; Pyo, Tae-Soo; Serabyn, Eugene; Suto, Hiroshi; Suzuki, Ryuji; Takato, Naruhisa; Terada, Hiroshi; Thalmann, Christian; Tomono, Daigo; Turner, Edwin L; Watanabe, Makoto; Yamada, Toru; Takami, Hideki; Usuda, Tomonori; Tamura, Motohide

    2013-01-01

    We present near-infrared coronagraphic imaging polarimetry of RY Tau. The scattered light in the circumstellar environment was imaged at H-band at a high resolution (~0".05) for the first time, using Subaru-HiCIAO. The observed polarized intensity (PI) distribution shows a butterfly-like distribution of bright emission with an angular scale similar to the disk observed at millimeter wavelengths. This distribution is offset toward the blueshifted jet, indicating the presence of a geometrically thick disk or a remnant envelope, and therefore the earliest stage of the Class II evolutionary phase. We perform comparisons between the observed PI distribution and disk models with: (1) full radiative transfer code, using the spectral energy distribution (SED) to constrain the disk parameters; and (2) monochromatic simulations of scattered light which explore a wide range of parameters space to constrain the disk and dust parameters. We show that these models cannot consistently explain the observed PI distribution, S...

  20. WAHRSIS: A Low-cost, High-resolution Whole Sky Imager With Near-Infrared Capabilities

    CERN Document Server

    Dev, Soumyabrata; Lee, Yee Hui; Winkler, Stefan

    2016-01-01

    Cloud imaging using ground-based whole sky imagers is essential for a fine-grained understanding of the effects of cloud formations, which can be useful in many applications. Some such imagers are available commercially, but their cost is relatively high, and their flexibility is limited. Therefore, we built a new daytime Whole Sky Imager (WSI) called Wide Angle High-Resolution Sky Imaging System. The strengths of our new design are its simplicity, low manufacturing cost and high resolution. Our imager captures the entire hemisphere in a single high-resolution picture via a digital camera using a fish-eye lens. The camera was modified to capture light across the visible as well as the near-infrared spectral ranges. This paper describes the design of the device as well as the geometric and radiometric calibration of the imaging system.

  1. Determination of the protein content in brine from salted herring using near-infrared spectroscopy

    DEFF Research Database (Denmark)

    Svensson, V.T.; Nielsen, Henrik Hauch; Bro, Rasmus

    2004-01-01

    Near-infrared reflectance (NIR) spectroscopy in the spectral range of 1000-2500 nm, was measured directly on brine from barrel salted herring, to investigate the potential of NIR as a fast method to determine the protein content. A principal component analysis performed on the NIR spectra shows two...... clearly indicate that NIR spectroscopy has a potential as a fast and noninvasive method for assessing the protein content in brine from barrel salted herring, which again may be used as an indicator for the ripening quality of barrel salted herring....... groups, separating the first 100 days of storage from the storage time exceeding 100 days. A partial least-squares regression model between selected regions of the NIR spectra and the protein content yields a correlation coefficient of 0.93 and a prediction error (RMSECV) of 0.25 g/100 g. The results...

  2. The Munich Near-Infrared Cluster Survey -- IV. Biases in the Completeness of Near-Infrared Imaging Data

    CERN Document Server

    Snigula, J; Bender, R; Botzler, C S; Feulner, G; Hopp, U

    2002-01-01

    We present the results of completeness simulations for the detection of point sources as well as redshifted elliptical and spiral galaxies in the K'-band images of the Munich Near-Infrared Cluster Survey (MUNICS). The main focus of this work is to quantify the selection effects introduced by threshold-based object detection algorithms used in deep imaging surveys. Therefore, we simulate objects obeying the well-known scaling relations between effective radius and central surface brightness, both for de Vaucouleurs and exponential profiles. The results of these simulations, while presented for the MUNICS project, are applicable in a much wider context to deep optical and near-infrared selected samples. We investigate the detection probability as well as the reliability for recovering the true total magnitude with Kron-like (adaptive) aperture photometry. The results are compared to the predictions of the visibility theory of Disney and Phillipps in terms of the detection rate and the lost-light fraction. Addit...

  3. Astrometry and Near-Infrared Photometry of Neptune's Inner Satellites and Ring Arcs

    Science.gov (United States)

    Dumas, Christophe; Terrile, Richard J.; Smith, Bradford A.; Schneider, Glenn

    2002-03-01

    We report 1.87 μm photometry and astrometry of the inner satellites (Proteus, Larissa, Galatea, and Despina) and ring arcs of Neptune, obtained with the Hubble Space Telescope and its near-infrared camera NICMOS. From comparison with the Voyager data obtained at visible wavelengths, the small bodies orbiting within the ring region of Neptune have a near-infrared albedo consistently low, but higher than at visible wavelengths for most of the satellites, ranging from p1.87μm=0.058 (Despina) to p1.87μm=0.094 (Proteus). The ring arcs display a reddish spectral response similar to the satellites' in the 0.5-1.9 μm wavelength range. If we consider an earlier photometric measurement of Proteus obtained at K band, the satellite's albedo shows a depression at 2.2 μm that could be the first spectral evidence for the presence of CH or CN bearing material on its surface. Although astrometry of the inner moons of Neptune yields positions consistent with the predictions derived from Voyager images, the long time base between the Voyager and NICMOS observations allows us to refine our knowledge of their mean motions and semimajor axes, and to decrease the errors associated with these measurements. In addition, we confirm a mismatch between the mean semimajor axis of the ring arcs and the location of the 42:43 corotation inclined resonance due to Galatea. This result calls into question the ability of this resonance to confine the arcs azimuthally.

  4. On-line near-infrared spectrometer to monitor urea removal in real time during hemodialysis.

    Science.gov (United States)

    Cho, David S; Olesberg, Jonathon T; Flanigan, Michael J; Arnold, Mark A

    2008-08-01

    The ex vivo removal of urea during hemodialysis treatments is monitored in real time with a noninvasive near-infrared spectrometer. The spectrometer uses a temperature-controlled acousto optical tunable filter (AOFT) in conjunction with a thermoelectrically cooled extended wavelength InGaAs detector to provide spectra with a 20 cm(-1) resolution over the combination region (4000-5000 cm(-1)) of the near-infrared spectrum. Spectra are signal averaged over 15 seconds to provide root mean square noise levels of 24 micro-absorbance units for 100% lines generated over the 4600-4500 cm(-1) spectral range. Combination spectra of the spent dialysate stream are collected in real-time as a portion of this stream passes through a sample holder constructed from a 1.1 mm inner diameter tube of Teflon. Real-time spectra are collected during 17 individual dialysis sessions over a period of 10 days. Reference samples were extracted periodically during each session to generate 87 unique samples with corresponding reference concentrations for urea, glucose, lactate, and creatinine. A series of calibration models are generated for urea by using the partial least squares (PLS) algorithm and each model is optimized in terms of number of factors and spectral range. The best calibration model gives a standard error of prediction (SEP) of 0.30 mM based on a random splitting of spectra generated from all 87 reference samples collected across the 17 dialysis sessions. PLS models were also developed by using spectra collected in early sessions to predict urea concentrations from spectra collected in subsequent sessions. SEP values for these prospective models range from 0.37 mM to 0.52 mM. Although higher than when spectra are pooled from all 17 sessions, these prospective SEP values are acceptable for monitoring the hemodialysis process. Selectivity for urea is demonstrated and the selectivity properties of the PLS calibration models are characterized with a pure component selectivity

  5. Pure Electric and Pure Magnetic Resonances in Near-Infrared Metal Double-Triangle Metamaterial Arrays

    Institute of Scientific and Technical Information of China (English)

    CAO Zhi-Shen; PAN Jian; CHEN Zhuo; ZHAN Peng; MIN Nai-Ben; WANG Zhen-Lin

    2011-01-01

    @@ We experimentally and numerically investigate the optical properties of metamaterial arrays composed of double partially-overlapped metallic nanotriangles fabricated by an angle-resolved nanosphere lithography.We demonstrate that each double-triangle can be viewed as an artificial magnetic element analogous to the conventional metal split-ring-resonator.It is shown that under normal-incidence conditions,individual double-triangle can exhibit a strong local magnetic resonance,but the collective response of the metamaterial arrays is purely electric because magnetic resonances of the two double-triangles in a unit cell having opposite openings are out of phase.For oblique incidences the metamaterial arrays are shown to support a pure magnetic response at the same frequency band.Therefore,switchable electric and magnetic resonances are achieved in double-triangle arrays.Moreover,both the electric and magnetic resonances axe shown to allow for a tunability over a large spectral range down to near-infrared.%We experimentally and numerically investigate the optical properties of metamaterial arrays composed of double partially-overlapped metallic nanotriangles fabricated by an angle-resolved nanosphere lithography. We demonstrate that each double-triable can be viewed as an artificial magnetic element analogous to the conventional metal split-ring-resonator. It is shown that under normal-incidence conditions, individual double-triangle can exhibit a strong local magnetic resonance, but the collective response of the metamaterial arrays is purely electric because magnetic resonances of the two double-triangles in a unit cell having opposite openings are out of phase.For oblique incidences the metamaterial arrays are shown to support a pure magnetic response at the same frequency band. Therefore, switchable electric and magnetic resonances are achieved in double-triangle arrays.Moreover, both the electric and magnetic resonances are shown to allow for a tunability over

  6. Calibration of high resolution remote sensing instruments in the visible and near infrared

    Science.gov (United States)

    Schüller, L.; Fischer, J.; Armbruster, W.; Bartsch, B.

    1997-05-01

    Measurements of the reflected solar radiation with high spectral resolution airborne instruments are usually used to develop new remote sensing techniques. The observed spectral features in the signals provide the possibility to define useful band settings for future satellite instruments. A precise wavelength and radiometric calibration is a prerequisite for such tasks. In this paper, a calibration procedure for the airborne spectrometer OVID is presented. The Optical Visible and near Infrared Detector consists of two similar detector systems, (600 - 1100 nm = VIS and 900 - 1700 nm = NIR). The spectral resolution is ~1.7 nm for the VIS-system and ~6 nm for the IR-system. This instrument is applied for the retrieval of water vapour content, aerosol and cloud properties. Besides the spectral and intensity calibration, also corrections for the dark current signals and for defective pixels have been performed. An indirect verification of the calibration procedure by the comparison of OVID measurements in cloudy and cloud free atmospheres with radiative transfer simulations is discussed in this paper. The used radiation transfer model MOMO is based on the matrix operator method.

  7. The Peltier driven frequency domain approach in thermal analysis.

    Science.gov (United States)

    De Marchi, Andrea; Giaretto, Valter

    2014-10-01

    The merits of Frequency Domain analysis as a tool for thermal system characterization are discussed, and the complex thermal impedance approach is illustrated. Pure AC thermal flux generation with negligible DC component is possible with a Peltier device, differently from other existing methods in which a significant DC component is intrinsically attached to the generated AC flux. Such technique is named here Peltier Driven Frequency Domain (PDFD). As a necessary prerequisite, a novel one-dimensional analytical model for an asymmetrically loaded Peltier device is developed, which is general enough to be useful in most practical situations as a design tool for measurement systems and as a key for the interpretation of experimental results. Impedance analysis is possible with Peltier devices by the inbuilt Seebeck effect differential thermometer, and is used in the paper for an experimental validation of the analytical model. Suggestions are then given for possible applications of PDFD, including the determination of thermal properties of materials.

  8. The Peltier driven frequency domain approach in thermal analysis

    Science.gov (United States)

    Marchi, Andrea De; Giaretto, Valter

    2014-10-01

    The merits of Frequency Domain analysis as a tool for thermal system characterization are discussed, and the complex thermal impedance approach is illustrated. Pure AC thermal flux generation with negligible DC component is possible with a Peltier device, differently from other existing methods in which a significant DC component is intrinsically attached to the generated AC flux. Such technique is named here Peltier Driven Frequency Domain (PDFD). As a necessary prerequisite, a novel one-dimensional analytical model for an asymmetrically loaded Peltier device is developed, which is general enough to be useful in most practical situations as a design tool for measurement systems and as a key for the interpretation of experimental results. Impedance analysis is possible with Peltier devices by the inbuilt Seebeck effect differential thermometer, and is used in the paper for an experimental validation of the analytical model. Suggestions are then given for possible applications of PDFD, including the determination of thermal properties of materials.

  9. A Visible Watermarking Scheme for Digital Images in Frequency Domain

    Directory of Open Access Journals (Sweden)

    D.R.Denslin Brabin

    2012-11-01

    Full Text Available A novel method is proposed for visible watermarking of digital image in frequency domain. The method is based on DCT modification of original image with respect to watermark image. The host image pixels are transformed into frequency coefficients as well as the watermark image pixels are also transformed into frequency coefficients using DCT. The compound mapping function is used to adjust the pixel values close to those of desired visible watermarks. Thus the watermarking is done in frequency domain using compound mapping function. One who has the watermark image and mapping function parameters only can remove the watermark. Thus it enhances the security. Experimental results demonstrate the effectiveness of the proposed approach.

  10. Microcirculation monitoring with real time spatial frequency domain imaging

    Science.gov (United States)

    Chen, Xinlin; Cao, Zili; Lin, Weihao; Zhu, Danfeng; Zhu, Xiuwei; Zeng, Bixin; Xu, M.

    2017-01-01

    We present a spatial frequency domain imaging (SFDI) study of local hemodynamics in the forearm of healthy volunteers performing paced breathing. Real time Single Snapshot Multiple Frequency Demodulation - Spatial Frequency Domain Imaging (SSMD-SFDI) was used to map the optical properties of the subsurface of the forearm continuously. The oscillations of the concentrations of deoxy- and oxyhemoglobin at the subsurface of the forearm induced by paced breathing are found to be close to out-of-phase, attributed to the dominance of the blood flow modulation by paced breathing. The properties of local microcirculation including the blood transit times through capillaries and venules are extracted by fitting to Simplified Hemodynamics Model. Our preliminary results suggest that the real time SSMD-SFDI platform may serve as one effective imaging modality for microcirculation monitoring.

  11. Domain Decomposition Solvers for Frequency-Domain Finite Element Equations

    KAUST Repository

    Copeland, Dylan

    2010-10-05

    The paper is devoted to fast iterative solvers for frequency-domain finite element equations approximating linear and nonlinear parabolic initial boundary value problems with time-harmonic excitations. Switching from the time domain to the frequency domain allows us to replace the expensive time-integration procedure by the solution of a simple linear elliptic system for the amplitudes belonging to the sine- and to the cosine-excitation or a large nonlinear elliptic system for the Fourier coefficients in the linear and nonlinear case, respectively. The fast solution of the corresponding linear and nonlinear system of finite element equations is crucial for the competitiveness of this method. © 2011 Springer-Verlag Berlin Heidelberg.

  12. Very bright, near-infrared single photon emitters in diamond

    Directory of Open Access Journals (Sweden)

    D. W. M. Lau

    2013-09-01

    Full Text Available We demonstrate activation of bright diamond single photon emitters in the near infrared range by thermal annealing alone, i.e., without ion implantation. The activation is crucially dependent on the annealing ambient. The activation of the single photon emitters is only observed when the sample is annealed in forming gas (4% H2 in Ar above temperatures of 1000 °C. By contrast, no emitters are activated by annealing in vacuum, oxygen, argon or deuterium. The emitters activated by annealing in forming gas exhibit very bright emission in the 730-760 nm wavelength range and have linewidths of ∼1.5-2.5 nm at room temperature.

  13. Diverse Near-Infrared Resonant Gold Nanostructures for Biomedical Applications

    KAUST Repository

    Huang, Jianfeng

    2015-12-08

    The ability of near-infrared (NIR) light to penetrate tissues deeply and to target malignant sites with high specificity via precise temporal and spatial control of light illumination makes it useful for diagnosing and treating diseases. Owing to their unique biocompatibility, surface chemistry and optical properties, gold nanostructures offer advantages as in vivo NIR photosensitizers. This chapter describes the recent progress in the varied use of NIR-resonant gold nanostructures for NIR-light-mediated diagnostic and therapeutic applications. We begin by describing the unique biological, chemical and physical properties of gold nanostructures that make them excellent candidates for biomedical applications. From here, we make an account of the basic principles involved in the diagnostic and therapeutic applications where gold nanostructures have set foot. Finally, we review recent developments in the fabrication and use of diverse NIR-resonant gold nanostructures for cancer imaging and cancer therapy.

  14. Neuroimaging with functional near infrared spectroscopy: From formation to interpretation

    Science.gov (United States)

    Herrera-Vega, Javier; Treviño-Palacios, Carlos G.; Orihuela-Espina, Felipe

    2017-09-01

    Functional Near Infrared Spectroscopy (fNIRS) is gaining momentum as a functional neuroimaging modality to investigate the cerebral hemodynamics subsequent to neural metabolism. As other neuroimaging modalities, it is neuroscience's tool to understand brain systems functions at behaviour and cognitive levels. To extract useful knowledge from functional neuroimages it is critical to understand the series of transformations applied during the process of the information retrieval and how they bound the interpretation. This process starts with the irradiation of the head tissues with infrared light to obtain the raw neuroimage and proceeds with computational and statistical analysis revealing hidden associations between pixels intensities and neural activity encoded to end up with the explanation of some particular aspect regarding brain function.To comprehend the overall process involved in fNIRS there is extensive literature addressing each individual step separately. This paper overviews the complete transformation sequence through image formation, reconstruction and analysis to provide an insight of the final functional interpretation.

  15. Biochemical and physiological basis of medical near-infrared spectroscopy

    Science.gov (United States)

    Joebsis-vander Vliet, Frans F.; Joebsis, Paul

    1999-10-01

    Near infrared spectroscopy (NIRS) can monitor both the redox status of Cytochrome c oxidase located in the mitochondria within the cell and the oxygenation of the blood in the tissue being monitored. Since the enzyme catalyzes more than 90% of oxygen utilization, it is the sink for the oxygen while the hemoglobin in the capillaries is the oxygen source. In order to evaluate the oxidative metabolic status of a tissue the optical data obtained from both molecules are commonly interpreted in the basis of test tube experiments with purified preparations. We are concerned that the validity of this practice may not have been tested sufficiently and raise four basic questions that have not yet been answered. Citing some examples of in vitro versus in vivo differences we conclude that more effort should be expended on the in vivo testing of the range of the signals, their natural variability, and the physiological and pathological meaning of their deviations from norm.

  16. Near-Infrared Fluorescent NanoGUMBOS for Biomedical Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Bwambok, David [Louisiana State University; El-Zahab, Bilal [Lousianna State University; Challa, Santhosh [Louisiana State University; Li, Min [Lousianna State University; Chandler, Lin [Horiba Jobin Yvon Inc.; Baker, Gary A [ORNL; Warner, Isiah M [ORNL

    2009-01-01

    Herein, we report on near-infrared (NIR) fluorescent nanoparticles generated from an emergent class of materials we refer to as a Group of Uniform Materials Based on Organic Salts (GUMBOS). GUMBOS are largely frozen ionic liquids, although the concept is more general and is also easily applied to solid ionic materials with melting points in excess of 100 C. Nanoparticles based on GUMBOS (nanoGUMBOS) derived from a NIR fluorophore are prepared using a reprecipitation method and evaluated for in vivo fluorescence imaging. Due to their uniformity, single-step preparation, and composite nature, nanoGUMBOS help to resolve issues with dye leakage problems innate to alternate cellular stains and unlock a myriad of applications for these materials, highlighting exciting possibilities for multifunctional nanoGUMBOS.

  17. Usefulness of portable near infrared spectroscopy in olive breeding programs

    Energy Technology Data Exchange (ETDEWEB)

    Leon-Moreno, L.

    2012-11-01

    The usefulness of portable near infrared (NIR) spectroscopy as a simple and efficient method to determine some of the main selection traits in olive breeding is evaluated in this work. Calibration models were developed and evaluated using partial least squares (PLS) regression from samples collected in different selection steps of the breeding work and under different experimental conditions. The results showed that accurate enough models (values of correlation between actual and predicted constituent higher than 0.9) were obtained for oil and moisture content in both cross validation and prediction results. Portable NIR spectroscopy could be used for selection of genotypes on the basis of these characters, providing similar ranking of genotypes than reference methods both in different selection steps of the breeding process (progenies and selection plots) and different experimental conditions (on-tree or under laboratory conditions). The advantages of this technique to improve the efficiency of the evaluation process in olive breeding programs are discussed. (Author) 21 refs.

  18. Near infrared reflectance measurement of nitrogen faecal losses.

    Science.gov (United States)

    Benini, L; Caliari, S; Bonfante, F; Guidi, G C; Brentegani, M T; Castellani, G; Sembenini, C; Bardelli, E; Vantini, I

    1992-06-01

    Chemical methods of measuring nitrogen in stools are complex, unpleasant, and therefore rarely performed. Recently, near infrared reflectance (NIRA) has been suggested for stool analysis. The aim of this study was to evaluate the possible application of this method in routine faecal nitrogen measurement. Nitrogen concentration and daily output were measured in the stools of 83 patients using NIRA and, for comparison, the Kjeldahl method. Nitrogen concentration and output ranged between 0.4-2.72 g% and 0.45-8.96 g/day respectively. Correlation coefficients (r), of 0.89 and 0.97 were found between the two methods for concentration and output respectively, and similar values were found in patients on enteral nutrition. Repeated measurements from the same stool collection, requiring only a few minutes, allowed homogenisation to be avoided. NIRA seems to be an easy, fast, and reliable alternative to chemical assays of nitrogen measurement in the management of patients with digestive disorders.

  19. Near-infrared spectroscopy for monitoring muscle oxygenation

    DEFF Research Database (Denmark)

    Boushel, Robert Christopher; Piantadosi, C A

    2000-01-01

    Near-infrared spectroscopy (NIRS) is a non-invasive method for monitoring oxygen availability and utilization by the tissues. In intact skeletal muscle, NIRS allows semi-quantitative measurements of haemoglobin plus myoglobin oxygenation (tissue O2 stores) and the haemoglobin volume. Specialized...... algorithms allow assessment of the oxidation-reduction (redox) state of the copper moiety (CuA) of mitochondrial cytochrome c oxidase and, with the use of specific tracers, accurate assessment of regional blood flow. NIRS has demonstrated utility for monitoring changes in muscle oxygenation and blood flow...... during submaximal and maximal exercise and under pathophysiological conditions including cardiovascular disease and sepsis. During work, the extent to which skeletal muscles deoxygenate varies according to the type of muscle, type of exercise and blood flow response. In some instances, a strong...

  20. PANIC: A Near-infrared Camera for the Magellan Telescopes

    CERN Document Server

    Martini, P; Murphy, D C; Birk, C; Shectman, S A; Grunnels, S M; Koch, E

    2004-01-01

    PANIC (Persson's Auxiliary Nasmyth Infrared Camera) is a near-infrared camera designed to operate at any one of the f/11 folded ports of the 6.5m Magellan telescopes at Las Campanas Observatory, Chile. The instrument is built around a simple, all-refractive design that reimages the Magellan focal plane to a plate scale of 0.125'' pixel^{-1} onto a Rockwell 1024x1024 HgCdTe detector. The design goals for PANIC included excellent image quality to sample the superb seeing measured with the Magellan telescopes, high throughput, a relatively short construction time, and low cost. PANIC has now been in regular operation for over one year and has proved to be highly reliable and produce excellent images. The best recorded image quality has been ~0.2'' FWHM.

  1. NIRS - Near infrared spectroscopy - investigations in neurovascular diseases

    DEFF Research Database (Denmark)

    Schytz, Henrik Winther

    2015-01-01

    in cerebral blood flow (CBF), the first study investigated a multi-source detector separation configuration and indocyanine green (ICG) as a tracer to calculate a corrected blood flow index (BFI) value. The study showed no correlation between CBF changes measured by 133Xenon single photon emission computer......The purpose of this thesis was to explore and develop methods, where continuous wave near infrared spectroscopy (CW-NIRS) can be applied in different neurovascular diseases, in order to find biological markers that are useful in clinical neurology. To develop a new method to detect changes...... tomography (133Xe-SPECT) and the corrected BFI value. It was concluded, that it was not possible to obtain reliable BFI data with the ICG CW-NIRS method. NIRS measurements of low frequency oscillations (LFOs) may be a reliable method to investigate vascular alterations in neurovascular diseases...

  2. Cylindrical luminescent solar concentrators with near-infrared quantum dots.

    Science.gov (United States)

    Inman, R H; Shcherbatyuk, G V; Medvedko, D; Gopinathan, A; Ghosh, S

    2011-11-21

    We investigate the performance of cylindrical luminescent solar concentrators (CLSCs) with near-infrared lead sulfide quantum dots (QDs) in the active region. We fabricate solid and hollow cylinders from a composite of QDs in polymethylmethacrylate, prepared by radical polymerization, and characterize sample homogeneity and optical properties using spectroscopic techniques. We additionally measure photo-stability and photocurrent outputs under both laboratory and external ambient conditions. The experimental results are in good agreement with theoretical calculations which demonstrate that the hollow CLSCs have higher absorption of incident radiation and lower self-absorption compared to solid cylindrical and planar geometries with similar geometric factors, resulting in a higher optical efficiency. © 2011 Optical Society of America

  3. Near-infrared LIF spectroscopy of HfF

    CERN Document Server

    Grau, Matt; Loh, Huanqian; Sinclair, Laura C; Stutz, Russel P; Yahn, Tylser S; Cornell, Eric A

    2012-01-01

    The molecular ion HfF$^+$ is the chosen species for a JILA experiment to measure the electron electric dipole moment (eEDM). Detailed knowledge of the spectrum of HfF is crucial to prepare HfF$^+$ in a state suitable for performing an eEDM measurement\\cite{Leanhardt}. We investigated the near-infrared electronic spectrum of HfF using laser-induced fluorescence (LIF) of a supersonic molecular beam. We discovered eight unreported bands, and assign each of them unambiguously, four to vibrational bands belonging to the transition $[13.8]0.5 \\leftarrow X1.5$, and four to vibrational bands belonging to the transition $[14.2]1.5 \\leftarrow X1.5$. Additionally, we report an improved measurement of vibrational spacing of the ground state, as well as anharmonicity $\\omega_e x_e$.

  4. Recent advances in fetal near-infrared spectroscopy

    Science.gov (United States)

    D'Antona, Donato; Aldrich, Clive J.; O'Brien, Patrick; Lawrence, Sally; Delpy, David T.; Wyatt, John S.

    1997-01-01

    Fetal brain injury resulting from hypoxia and ischemia during labor remains an important cause of death and long- term disability. However, little is known about fetal brain oxygenation and hemodynamics. There are currently no satisfactory clinical techniques for fetal monitoring and there remains a need for a new method to assess brain oxygenation. Fetal near infrared spectroscopy (NIRS) is a new technique that allows noninvasive observation of changes in the cerebral concentrations of oxyhemoglobin and deoxyhemoglobin to be made during labor. A specially designed optical probe is inserted through the dilated cervix and placed against the fetal head. It is then possible to compare changes in NIRS data with other observations of fetal conditions, such as fetal heart rate and acid-base status.

  5. Near infrared spectroscopy of food systems using a supercontinuum laser

    DEFF Research Database (Denmark)

    Ringsted, Tine

    applied near- and mid-infrared incandescent light bulbs. This thesis aim to explore the utility of using a supercontinuum source in two food applications. (1) The supercontinuum light was applied for the first time to barley seeds in transmission mode in the long wavelength near-infrared region from 2260......-2380 nm. From these spectra it was possible to predict the β-glucan content of individual seeds. The measurements of single seeds can be used in plant breeding to sort according to trait or in grain industries to sort according to quality or property. (2) The supercontinuum light has been used with a new...... wavelength separation method called dispersive Fourier transformation. Different wavelengths travel at different speed through a dispersive element, which in this case is a 10.6 km long silica fiber, and the polychromatic light pulses will therefore be separated by wavelength. The signal...

  6. Near-infrared light responsive polymeric nanocomposites for cancer therapy.

    Science.gov (United States)

    Min, Cong; Zou, Xueqing; Yang, Quanzhu; Liao, Liqiong; Zhou, Guofu; Liu, Lijian

    2016-11-22

    Inorganic nanoparticles, which can absorb and convert near infrared (NIR) light to heat to ablate cancer cells, have been widely investigated in photothermal therapy. However, the inherent poor solubility and acute systemic toxicity of these inorganic particles hinder their application in clinical practice. Polymeric nnanocomposites materials containing both inorganic nanoparticles and polymers could be harnessed to achieve enhanced photothermal therapeutic effect as well as improved biocompatibility and multi-responsiveness. Synergistic chemo-photothermal efficacy towards cancer cells and tumor tissue can thus be realized through such multi-functional and multi-responsive polymeric nanocomposites. In this review, the recent developments in polymeric nanocomposites based on different types of inorganic nanoparticles (i.e. gold, carbon nanotube, graphene, and up-conversion nanoparticles) for NIR-triggered cancer therapy are summarized.

  7. On the Near-Infrared Size of Vega

    CERN Document Server

    Ciardi, D R; Akeson, R L; Thompson, R R; Lada, E A; Howell, S B; Ciardi, David R.; Belle, Gerard T. van; Akeson, Rachel L.; Thompson, Robert R.; Lada, Elizabeth A.; Howell, Steve B.

    2001-01-01

    Near-infrared (2.2 um) long baseline interferometric observations of Vega are presented. The stellar disk of the star has been resolved, and the data have been fitted with a limb darkened stellar disk of diameter Theta_{LD} = 3.28 +/- 0.01 mas. The derived effective temperature is T_eff = 9553 +/- 111 K. However, the residuals resulting from the stellar disk model appear to be significant and display organized structure. Instrumental artifacts, stellar surface structure, stellar atmosphere structure, and extended emission/scattering from the debris disk are discussed as possible sources of the residuals. While the current dataset cannot uniquely determine the origin of the residuals, the debris disk is found to be the most likely source. A simple debris disk model, with 3-6% of Vega's flux emanating from the disk at r < 4 AU, can explain the residuals.

  8. Near-Infrared Bulge-Disk Correlations of Lenticular Galaxies

    CERN Document Server

    Barway, Sudhanshu; Kembhavi, Ajit K; Mayya, Y D

    2008-01-01

    We consider the luminosity and environmental dependence of structural parameters of lenticular galaxies in the near-infrared K band. Using a two-dimensional galaxy image decomposition technique, we extract bulge and disk structural parameters for a sample of 36 lenticular galaxies observed by us in the K band. By combining data from the literature for field and cluster lenticulars with our data, we study correlations between parameters that characterise the bulge and the disk as a function of luminosity and environment. We find that scaling relations such as the Kormendy relation, photometric plane and other correlations involving bulge and disk parameters show a luminosity dependence. This dependence can be explained in terms of galaxy formation models in which faint lenticulars (M_T > -24.5) formed via secular formation processes that likely formed the pseudobulges of late-type disk galaxies, while brighter lenticulars (M_T < -24.5) formed through a different formation mechanism most likely involving maj...

  9. Near-infrared extinction with discretised stellar colours

    CERN Document Server

    Juvela, M

    2015-01-01

    Several methods exist to convert near-infrared (NIR) stellar observations into extinction maps. We present a new method based on NIR multiband observations. The method uses a discretised version of the distribution of intrinsic stellar colours. A number of variations of the basic method are tested, and the results are compared to NICER calculations. When photometric errors are large, the results are close to those of NICER method but some advantages can be seen when the distribution of intrinsic colours cannot be described well with a single covariance matrix. A priori information about relative column density variations at sub-beam scales can result in a significant increase in accuracy. The results may be further improved by considering the magnitude dependence of the intrinsic colours. Thus, the new methods are useful mostly when photometric errors are small, the distribution of intrinsic colours is well known, or one has prior knowledge of the small-scale structures.

  10. Discrimination and content analysis of fritillaria using near infrared spectroscopy.

    Science.gov (United States)

    Meng, Yu; Wang, Shisheng; Cai, Rui; Jiang, Bohai; Zhao, Weijie

    2015-01-01

    Fritillaria is a traditional Chinese herbal medicine which can be used to moisten the lungs. The objective of this study is to develop simple, accurate, and solvent-free methods to discriminate and quantify Fritillaria herbs from seven different origins. Near infrared spectroscopy (NIRS) methods are established for the rapid discrimination of seven different Fritillaria samples and quantitative analysis of their total alkaloids. The scaling to first range method and the partial least square (PLS) method are used for the establishment of qualitative and quantitative analysis models. As a result of evaluation for the qualitative NIR model, the selectivity values between groups are always above 2, and the mistaken judgment rate of fifteen samples in prediction sets was zero. This means that the NIR model can be used to distinguish different species of Fritillaria herbs. The established quantitative NIR model can accurately predict the content of total alkaloids from Fritillaria samples.

  11. Near-infrared Spectroscopy in the Brewing Industry.

    Science.gov (United States)

    Sileoni, Valeria; Marconi, Ombretta; Perretti, Giuseppe

    2015-01-01

    This article offers an exhaustive description of the use of Near-Infrared (NIR) Spectroscopy in the brewing industry. This technique is widely used for quality control testing of raw materials, intermediates, and finished products, as well as process monitoring during malting and brewing. In particular, most of the reviewed works focus on the assessment of barley properties, aimed at quickly selecting the best barley varieties in order to produce a high-quality malt leading to high-quality beer. Various works concerning the use of NIR in the evaluation of raw materials, such as barley, malt, hop, and yeast, are also summarized here. The implementation of NIR sensors for the control of malting and brewing processes is also highlighted, as well as the use of NIR for quality assessment of the final product.

  12. Functional near-infrared spectroscopy studies in children

    Directory of Open Access Journals (Sweden)

    Nagamitsu Shinichiro

    2012-03-01

    Full Text Available Abstract Psychosomatic and developmental behavioral medicine in pediatrics has been the subject of significant recent attention, with infants, school-age children, and adolescents frequently presenting with psychosomatic, behavioral, and psychiatric symptoms. These may be a consequence of insecurity of attachment, reduced self-confidence, and peer -relationship conflicts during their developmental stages. Developmental cognitive neuroscience has revealed significant associations between specific brain lesions and particular cognitive dysfunctions. Thus, identifying the biological deficits underlying such cognitive dysfunction may provide new insights into therapeutic prospects for the management of those symptoms in children. Recent advances in noninvasive neuroimaging techniques, and especially functional near-infrared spectroscopy (NIRS, have contributed significant findings to the field of developmental cognitive neuroscience in pediatrics. We present here a comprehensive review of functional NIRS studies of children who have developed normally and of children with psychosomatic and behavioral disorders.

  13. [Rapid determination of beet sugar content using near infrared spectroscopy].

    Science.gov (United States)

    Yang, Yong; Ren, Jian; Zheng, Xi-Qun; Zhao, Li-Ying; Li, Mao-Mao

    2014-10-01

    In order to classify and set different prices on basis of difference of beet sugar content in the acquisition process and promote the development of beet sugar industry healthily, a fast, nondestructive, accurate method to detect sugar content of beet was determined by applying near infrared spectroscopy technology. Eight hundred twenty samples from 28 representative varieties of beet were collected as calibration set and 70 samples were chosen as prediction set. Then near infrared spectra of calibration set samples were collected by scanning, effective information was extracted from NIR spectroscopy, and the original spectroscopy data was optimized by data preprocessing methods appropriately. Then partial least square(PLS)regression was used to establish beet sugar quantitative prediction mathematical model. The performances of the models were evaluated by the root mean square of cross-validation (RMSECV), the coefficient of determination (R2) of the calibration model and the standard error of prediction (SEP), and the predicted results of these models were compared. Results show that the established mathematical model by using first derivative (FD) and standard normal variate transformation (SNV) coupled with partial least squares has good predictive ability. The R2 of calibration models of sugar content of beet is 0.908 3, and the RMSECV is 0.376 7. Using this model to forecast the prediction set including 70 samples, the correlation coefficient is 0.921 4 between predicted values and measured values, and the standard error of prediction (SEP) is 0.439, without significant difference (p > 0.05) between predicted values and measured values. These results demonstrated that NIRS can take advantage of simple, rapid, nondestructive and environmental detection method and could be applied to predict beet sugar content. This model owned high accuracy and can meet the precision need of determination of beet sugar content. This detection method could be used to classify

  14. Near-infrared photoimmunotherapy: a comparison of light dosing schedules.

    Science.gov (United States)

    Ogata, Fusa; Nagaya, Tadanobu; Nakamura, Yuko; Sato, Kazuhide; Okuyama, Shuhei; Maruoka, Yasuhiro; Choyke, Peter L; Kobayashi, Hisataka

    2017-05-23

    Near infrared photoimmunotherapy (NIR-PIT) is a newly-developed cancer therapy in which a monoclonal antibody is conjugated to a near-infrared photoabsorber, IR700 to form an antibody photoabsorber conjugate (APC). After the APC binds to cancer cells expressing the cognate antigen, exposure to NIR light results in rapid, highly selective necrotic cell death of the cancer cells with minimal off-target effects. Several hours after NIR-PIT, the tumor vessels become supraphysiologically permeable and circulating APC can therefore readily leak into the already-treated tumor space where it can bind with viable cancer cells that is called super-enhanced permeability and retention effect. The presence of the SUPR effect after NIR-PIT has prompted regimens in which there is a repeat exposure of NIR light 24 hours after the initial NIR-PIT to take advantage of the leakage of additional APC deeper into the tumor. However, this post-treatment APC penetration was fully induced within 3 hours, therefore, it is possible that repeated exposures of NIR light could be administered much earlier than 24 hours and still produce the same effects. To test this idea, we compared several modes of delivering additional doses of light after initial NIR-PIT. We found that repeated exposures of NIR light starting 3 hours after initial NIR-PIT produced equal or superior results to more delayed exposures of NIR light. This finding has practical implications of an easy-to-perform regimen as repeated light exposures could be performed during a single day rather than extending the procedure over two days which is the current recommendation.

  15. Investigation of graphene applied on near infrared photodetector (Conference Presentation)

    Science.gov (United States)

    Lien, I.-Chun; Chen, Sheng-Hui

    2016-10-01

    The particular Graphene-Germanium-Graphene photodetector (GSG PD) is investigated in this research. Germanium has good absorption coefficient in near infrared such as 850 nm, 1310 nm and 1550 nm which are commonly used in optics communication. Generally, the metal electrode was utilized for photodetector and there were lots of light being loss. In recent years, graphene is found to be a good conductive film. It is a two-dimensional monolayer of sp2-bonded carbon atoms. In cases where synthesized by chemical vapor deposition (CVD), graphene is especially a promising candidate for transparent conductive films (TCFs) due to its exceptional electrical conductivity and high optical transmittance which is almost transparent in the wide wavelength range, especially including near infrared. Therefore, the higher photo current and responsivity of the device can be achieved. In this investigation, interdigitated graphene electrodes are used on the devices with the purposes of a relatively easy process for high-speed devices and a comparable process for the integrated circuit. We used the n-type Germanium as the substrates for the absorption of photodetector and different layers of graphene as the interdigitated electrodes. The interdigitated graphene electrode is prepared by transferred the graphene which is grown by CVD on the substrate first and then pattern by O2 plasma. The most direct method of measuring the photo current is to be incident a laser source by fiber and give a DC bias then using KEITHLEY 2400 Source Meter to measure current from photodetectors. As the result of that, we can calculate the responsivity by formula.

  16. Frequency domain analysis of noise in autoregulated gene circuits

    OpenAIRE

    Simpson, Michael L.; Cox, Chris D.; Sayler, Gary S.

    2003-01-01

    We describe a frequency domain technique for the analysis of intrinsic noise within negatively autoregulated gene circuits. This approach is based on the transfer function around the feedback loop (loop transmission) and the equivalent noise bandwidth of the system. The loop transmission, T, is shown to be a determining factor of the dynamics and the noise behavior of autoregulated gene circuits, and this T-based technique provides a simple and flexible method for the analysis of noise arisin...

  17. Reduced Order Internal Models in the Frequency Domain

    OpenAIRE

    Laakkonen, Petteri; Paunonen, Lassi

    2016-01-01

    The internal model principle states that all robustly regulating controllers must contain a suitably reduplicated internal model of the signal to be regulated. Using frequency domain methods, we show that the number of the copies may be reduced if the class of perturbations in the problem is restricted. We present a two step design procedure for a simple controller containing a reduced order internal model achieving robust regulation. The results are illustrated with an example of a five tank...

  18. Frequency domain stability criteria for fractional-order control systems

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This paper concerns about the frequency domain stability criteria for fractional-order control systems. On the base of characteristics of the fractional-order equations solutions, we consider the Nyquist stability criterion in a wider sense and obtain a more common means to analyze the stability of fractional-order systems conveniently. Finally, this paper illustrates the generalized stability criteria with an example to show the effect of the parameters variation on the fractional-order control systems.

  19. Near-Infrared Coloring via a Contrast-Preserving Mapping Model.

    Science.gov (United States)

    Son, Chang-Hwan; Zhang, Xiao-Ping

    2017-11-01

    Near-infrared gray images captured along with corresponding visible color images have recently proven useful for image restoration and classification. This paper introduces a new coloring method to add colors to near-infrared gray images based on a contrast-preserving mapping model. A naive coloring method directly adds the colors from the visible color image to the near-infrared gray image. However, this method results in an unrealistic image because of the discrepancies in the brightness and image structure between the captured near-infrared gray image and the visible color image. To solve the discrepancy problem, first, we present a new contrast-preserving mapping model to create a new near-infrared gray image with a similar appearance in the luminance plane to the visible color image, while preserving the contrast and details of the captured near-infrared gray image. Then, we develop a method to derive realistic colors that can be added to the newly created near-infrared gray image based on the proposed contrast-preserving mapping model. Experimental results show that the proposed new method not only preserves the local contrast and details of the captured near-infrared gray image, but also transfers the realistic colors from the visible color image to the newly created near-infrared gray image. It is also shown that the proposed near-infrared coloring can be used effectively for noise and haze removal, as well as local contrast enhancement.

  20. Near-Infrared Band Strengths of Molecules Diluted in N2 and H2O Ice Mixtures Relevant to Interstellar and Planetary Ices

    Science.gov (United States)

    Richey, Christina Rae; Gerakines, P.A.

    2012-01-01

    The relative abundances of ices in astrophysical environments rely on accurate laboratory measurements of physical parameters, such as band strengths (or absorption intensities), determined for the molecules of interest in relevant mixtures. In an extension of our previous study on pure-ice samples, here we focus on the near-infrared absorption features of molecules in mixtures with the dominant components of interstellar and planetary ices, H2O and N2. We present experimentally measured near-infrared spectral information (peak positions, widths, and band strengths) for both H2O- and N2-dominated mixtures of CO (carbon monoxide), CO2 (carbon dioxide), CH4 (methane), and NH3 (ammonia). Band strengths were determined during sample deposition by correlating the growth of near-infrared features (10,000-4000 per centimeter, 1-2.5 micrometers) with better-known mid-infrared features (4000-400 per centimeter, 2.5-25 micrometers) at longer wavelengths.

  1. Integration of Multiple Plasmonic and Co-Catalyst Nanostructures on TiO2 Nanosheets for Visible-Near-Infrared Photocatalytic Hydrogen Evolution.

    Science.gov (United States)

    Jiang, Wenya; Bai, Song; Wang, Limin; Wang, Xijun; Yang, Li; Li, Yanrui; Liu, Dong; Wang, Xiaonong; Li, Zhengquan; Jiang, Jun; Xiong, Yujie

    2016-03-23

    Utilization of visible and near-infrared light has always been the pursuit of photocatalysis research. In this article, an approach is developed to integrate dual plasmonic nanostructures with TiO2 semiconductor nanosheets for photocatalytic hydrogen production in visible and near-infrared spectral regions. Specifically, the Au nanocubes and nanocages used in this work can harvest visible and near-infrared light, respectively, and generate and inject hot electrons into TiO2 . Meanwhile, Pd nanocubes that can trap the energetic electrons from TiO2 and efficiently participate in the hydrogen evolution reaction are employed as co-catalysts for improved catalytic activity. Enabled by this unique integration design, the hydrogen production rate achieved is dramatically higher than those of its counterpart structures. This work represents a step toward the rational design of semiconductor-metal hybrid structures for broad-spectrum photocatalysis.

  2. Spatial frequency domain spectroscopy of two layer media

    Science.gov (United States)

    Yudovsky, Dmitry; Durkin, Anthony J.

    2011-10-01

    Monitoring of tissue blood volume and oxygen saturation using biomedical optics techniques has the potential to inform the assessment of tissue health, healing, and dysfunction. These quantities are typically estimated from the contribution of oxyhemoglobin and deoxyhemoglobin to the absorption spectrum of the dermis. However, estimation of blood related absorption in superficial tissue such as the skin can be confounded by the strong absorption of melanin in the epidermis. Furthermore, epidermal thickness and pigmentation varies with anatomic location, race, gender, and degree of disease progression. This study describes a technique for decoupling the effect of melanin absorption in the epidermis from blood absorption in the dermis for a large range of skin types and thicknesses. An artificial neural network was used to map input optical properties to spatial frequency domain diffuse reflectance of two layer media. Then, iterative fitting was used to determine the optical properties from simulated spatial frequency domain diffuse reflectance. Additionally, an artificial neural network was trained to directly map spatial frequency domain reflectance to sets of optical properties of a two layer medium, thus bypassing the need for iteration. In both cases, the optical thickness of the epidermis and absorption and reduced scattering coefficients of the dermis were determined independently. The accuracy and efficiency of the iterative fitting approach was compared with the direct neural network inversion.

  3. Signals features extraction in liquid-gas flow measurements using gamma densitometry. Part 2: frequency domain

    Directory of Open Access Journals (Sweden)

    Hanus Robert

    2016-01-01

    Full Text Available Knowledge of the structure of a flow is really significant for the proper conduct a number of industrial processes. In this case a description of a two-phase flow regimes is possible by use of the time-series analysis e.g. in frequency domain. In this article the classical spectral analysis based on Fourier Transform (FT and Short-Time Fourier Transform (STFT were applied for analysis of signals obtained for water-air flow using gamma ray absorption. The presented method was illustrated by use data collected in experiments carried out on the laboratory hydraulic installation with a horizontal pipe of 4.5 m length and inner diameter of 30 mm equipped with two 241Am radioactive sources and scintillation probes with NaI(Tl crystals. Stochastic signals obtained from detectors for plug, bubble, and transitional plug – bubble flows were considered in this work. The recorded raw signals were analyzed and several features in the frequency domain were extracted using autospectral density function (ADF, cross-spectral density function (CSDF, and the STFT spectrogram. In result of a detail analysis it was found that the most promising to recognize of the flow structure are: maximum value of the CSDF magnitude, sum of the CSDF magnitudes in the selected frequency range, and the maximum value of the sum of selected amplitudes of STFT spectrogram.

  4. Signals features extraction in liquid-gas flow measurements using gamma densitometry. Part 2: frequency domain

    Science.gov (United States)

    Hanus, Robert; Zych, Marcin; Petryka, Leszek; Jaszczur, Marek; Hanus, Paweł

    2016-03-01

    Knowledge of the structure of a flow is really significant for the proper conduct a number of industrial processes. In this case a description of a two-phase flow regimes is possible by use of the time-series analysis e.g. in frequency domain. In this article the classical spectral analysis based on Fourier Transform (FT) and Short-Time Fourier Transform (STFT) were applied for analysis of signals obtained for water-air flow using gamma ray absorption. The presented method was illustrated by use data collected in experiments carried out on the laboratory hydraulic installation with a horizontal pipe of 4.5 m length and inner diameter of 30 mm equipped with two 241Am radioactive sources and scintillation probes with NaI(Tl) crystals. Stochastic signals obtained from detectors for plug, bubble, and transitional plug - bubble flows were considered in this work. The recorded raw signals were analyzed and several features in the frequency domain were extracted using autospectral density function (ADF), cross-spectral density function (CSDF), and the STFT spectrogram. In result of a detail analysis it was found that the most promising to recognize of the flow structure are: maximum value of the CSDF magnitude, sum of the CSDF magnitudes in the selected frequency range, and the maximum value of the sum of selected amplitudes of STFT spectrogram.

  5. Herbig stars' near-infrared excess: An origin in the protostellar disk's magnetically supported atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Turner, N. J. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Benisty, M.; Dullemond, C. P. [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); Hirose, S., E-mail: neal.turner@jpl.nasa.gov [Institute for Research on Earth Evolution, Japan Agency for Marine-Earth Science and Technology, 3173-25 Showamachi, Kanazawa-ku, Yokohama, Kanagawa 236-0001 (Japan)

    2014-01-01

    Young stars with masses 2-8 times solar, the Herbig Ae and Be stars, often show a near-infrared excess too large to explain with a hydrostatically supported circumstellar disk of gas and dust. At the same time, the accretion flow carrying the circumstellar gas to the star is thought to be driven by magnetorotational turbulence, which, according to numerical MHD modeling, yields an extended low-density atmosphere supported by the magnetic fields. We demonstrate that the base of the atmosphere can be optically thick to the starlight and that the parts lying near 1 AU are tall enough to double the fraction of the stellar luminosity reprocessed into the near-infrared. We generate synthetic spectral energy distributions (SEDs) using Monte Carlo radiative transfer calculations with opacities for submicron silicate and carbonaceous grains. The synthetic SEDs closely follow the median Herbig SED constructed recently by Mulders and Dominik and, in particular, match the large near-infrared flux, provided the grains have a mass fraction close to interstellar near the disk's inner rim.

  6. Application of Wavelet Transform in the Prediction of Navel Orange Vitamin C Content by Near-Infrared Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    This study was to search for an approach for rapid measurement of orange vitamin C (Vc) content. By using different decomposing levels of Daubechies 3 wavelet transform, the near-infrared spectra signals obtained from intact fruits of 100 navel orange samples were denoised, and the results of the predicted Vc contents for the corresponding samples determined by the reconstructed spectra after denoising were validated by means of PLS-CV (partial least squared-cross validation).It was shown that the prediction effects verified by PLS-CV analysis varied when different wavelet transform decomposing levels were employed. At the wavelet decomposing level 4, the best prediction effect was obtained, with the correlation coefficient R between the prediction and true values being 0.9574 and the expected variance RMSECV being as low as 3.9 mg 100 g-1. Furthermore, the 11 different approaches for the pretreatment of the near-infrared spectrum were compared.It was found that the calibration model established by PLS using spectra pretreated by wavelet transform denoising provided the best prediction for Vc content, exhibiting the highest correlation between the prediction and true values by cross validation. In conclusion, the near infrared spectral model denoised by means of wavelet transform can be used for accurate, rapid, and nondestructive quantitative analysis on navel orange Vc content.

  7. Spitzer SAGE-Spec: Near Infrared Spectroscopy, Dust Shells, and Cool Envelopes in Extreme Large Magellanic Cloud AGB Stars

    CERN Document Server

    Blum, R D; Kemper, F; Ling, B; Volk, K

    2014-01-01

    K-band spectra are presented for a sample of 39 Spitzer IRS SAGE-Spec sources in the Large Magellanic Cloud. The spectra exhibit characteristics in very good agreement with their positions in the near infrared - Spitzer color-magnitude diagrams and their properties as deduced from the Spitzer IRS spectra. Specifically, the near infrared spectra show strong atomic and molecular features representative of oxygen-rich and carbon-rich asymptotic giant branch stars, respectively. A small subset of stars were chosen from the luminous and red extreme "tip" of the color magnitude diagram. These objects have properties consistent with dusty envelopes but also cool, carbon-rich "stellar" cores. Modest amounts of dust mass loss combine with the stellar spectral energy distribution to make these objects appear extreme in their near infrared and mid infrared colors. One object in our sample, HV 915, a known post asymptotic giant branch star of the RV Tau type exhibits CO 2.3 micron band head emission consistent with previ...

  8. On the feasibility of near infrared spectroscopy to detect contaminants in water using single salt solutions as model systems.

    Science.gov (United States)

    Gowen, A A; Marini, F; Tsuchisaka, Y; De Luca, S; Bevilacqua, M; O'Donnell, C; Downey, G; Tsenkova, R

    2015-01-01

    This research work evaluates the feasibility of NIRS to detect contaminants in water using single salt solutions as model systems. Previous research has indicated the potential of near infrared spectroscopy (NIRS) for detecting solutes in water; however, a comprehensive investigation of the limit of detection of this technique has not been carried out. Near infrared transmittance spectra of aqueous salt solutions in the concentration range 0.002-0.1 mol L(-1) (equivalent to 117-13,334 ppm or 0.0001-0.01% mass/mass) were investigated. The first overtone region of the near infrared spectrum (1300-1600 nm) was found to be the most effective wavelength range for prediction of salt concentration in aqueous solutions. Calibration models built using this wavelength range and employing the extended multiplicative scatter spectral pre-treatment resulted in root mean squared error of prediction values ranging from 0.004 to 0.01 mol L(-1). The limit of detection (LOD) was estimated to be of the order of 0.1% (mass/mass) or 1000 ppm. Within the framework of Aquaphotomics, it was possible to examine the effect of different salts on the NIR spectra of water in the first overtone range. Our results were confirmed through test experiments at various geographical locations employing dispersive and Fourier transform type NIRS instruments.

  9. On-line near infrared bioreactor monitoring of cell density and concentrations of glucose and lactate during insect cell cultivation.

    Science.gov (United States)

    Qiu, Jiang; Arnold, Mark A; Murhammer, David W

    2014-03-10

    Near infrared spectroscopy is demonstrated as a suitable method for monitoring real time cell density and concentrations of glucose and lactate during insect cell cultivation. The utility of this approach is illustrated during the cultivation of Trichoplusia ni BTI-Tn-5B1-4 insect cells in a stirred-tank bioreactor. On-line near infrared measurements are made by passing unaltered culture medium through an autoclavable near infrared flow-through sample cell during the cultivation process. Single-beam near infrared spectra were collected over the combination spectral range (5000-4000cm(-1)) through a 1.5mm path length sample. Cell density calibration model was established by uni-variable linear regressions with measured mean absorbance values of on-line spectra collected during a cultivation run. Calibration models are generated for glucose and lactate by regression analysis of both off line and on line spectra collected during a series of pre-measurement cultivation runs. Analyte-specific calibration models are generated by using a combination of spectra from both natural, unaltered samples and samples spiked with known levels of glucose and lactate. Spiked samples are used to destroy concentration correlations between solutes, thereby enhancing the selectivity of the calibration models. Absorbance spectra are used to build partial least squares calibration models for glucose and lactate. The calibration model for cell density corresponds to a univariate linear regression calibration model based on the mean absorbance between 4750 and 4250cm(-1). The standard errors of prediction are 1.54mM, 0.83mM, and 0.38×10(6)cells/mL for the glucose, lactate, and cell density models, respectively.

  10. [Discriminant analysis of raw milk adulterated with botanical filling material using near infrared spectroscopy].

    Science.gov (United States)

    Li, Liang; Ding, Wu

    2010-05-01

    In order to find out a fast measure method of adulterated milk based on near infrared spectroscopy, milk adulterated with plant butter, vegetable protein and starch was collected respectively. Using Fourier transform near infrared spectroscopy to scan the samples, the spectrum data were obtained. The samples were scanned in the spectral region between 4 000 and 12 000 cm(-1) by FT-NIR spectrometer with an optic fiber of 2 mm path-length and an InGaAs detector. Then all data were analyzed by principal component analysis combined with Fisher line discriminant analysis (FLDA) and partial least squares (PLS). Results show that the accumulative reliabilities of the first six components were more than 99%, so the first six components were applied as FLDA inputs and the values of the type of milk were applied as the outputs. An adulterated milk qualitative discriminant model based on Fisher line discriminant analysis was developed finally. The result indicated that the accuracy of detection of calibration samples is 97.78%. The unknown test samples were tested by this model and the correct identification rate is 94.44%. Partial least square models for detecting the content of material added to raw milk were set up with good veracity. The predictive correlation coefficient (R2) of calibration sets of milk adulterated with plant butter, vegetable protein and starch are 99.08%, 99.96% and 99.39%, respectively, while the root mean square errors of cross validation (RMSECV) of the three calibration sets are 0.304%, 0.013 5% and 0.060%, respectively. The R2 of validation sets of the three kinds of adulterated milk are 98.50%, 99.94% and 98.50%, respectively, while the root mean square errors of prediction (RMSEP) of the three validation sets are 0.323%, 0.028 8% and 0.068%, respectively. All of these suggested that near infrared spectroscopy has good potential for rapid qualitative and quantitative detection of milk adulterated with botanical filling material.

  11. Prediction of mechanical properties of Chinese fir wood by near infrared spectroscopy

    Institute of Scientific and Technical Information of China (English)

    Huaqiang YU; Rongjun ZHAO; Feng FU; Benhua FEI; Zehui JIANG

    2009-01-01

    Mechanical properties and the visible and near infrared (NIR) (350-2500nm) spectra obtained from longitudinal and transverse face of 155 small clear wood samples of Chinese fir (Cunninghamia lanceolata) were measured, and 103 of them were used to establish calibration models. Calibrations were tested on an independent set (52 samples). Differences between calibrations developed by using the longitudinal and transverse face were small. The calibrations developed by using NIR spectra (350-2500nm) collected from transverse face were slightly inferior to those developed by using NIR spectra collected from longitudinal face. When reducing the spectral range to between 780 and 1050 nm, the calibrations developed by using NIR spectra collected from longitudinal face were slightly inferior to those developed by using NIR spectra collected from transverse face, and reducing the spectral range causes no decrease in the quality of the models developed using NIR spectra collected from transverse face. Partial lease square (PLS) modeling and test showed that calibrations developed using the visible and NIR spectra from transverse and longitudinal faces and calibrations developed by using the reducing spectral range (780- 1050nm) from the transverse face were moderate, and have a RPD range from 1.51 to 1.90. It is concluded that NIR spectroscopy can be used as an initial screening.

  12. Diagnosis of colorectal cancer by near-infrared optical fiber spectroscopy and random forest

    Science.gov (United States)

    Chen, Hui; Lin, Zan; Wu, Hegang; Wang, Li; Wu, Tong; Tan, Chao

    2015-01-01

    Near-infrared (NIR) spectroscopy has such advantages as being noninvasive, fast, relatively inexpensive, and no risk of ionizing radiation. Differences in the NIR signals can reflect many physiological changes, which are in turn associated with such factors as vascularization, cellularity, oxygen consumption, or remodeling. NIR spectral differences between colorectal cancer and healthy tissues were investigated. A Fourier transform NIR spectroscopy instrument equipped with a fiber-optic probe was used to mimic in situ clinical measurements. A total of 186 spectra were collected and then underwent the preprocessing of standard normalize variate (SNV) for removing unwanted background variances. All the specimen and spots used for spectral collection were confirmed staining and examination by an experienced pathologist so as to ensure the representative of the pathology. Principal component analysis (PCA) was used to uncover the possible clustering. Several methods including random forest (RF), partial least squares-discriminant analysis (PLSDA), K-nearest neighbor and classification and regression tree (CART) were used to extract spectral features and to construct the diagnostic models. By comparison, it reveals that, even if no obvious difference of misclassified ratio (MCR) was observed between these models, RF is preferable since it is quicker, more convenient and insensitive to over-fitting. The results indicate that NIR spectroscopy coupled with RF model can serve as a potential tool for discriminating the colorectal cancer tissues from normal ones.

  13. A Near-Infrared Spectroscopic Study of Young Field Ultracool Dwarfs

    CERN Document Server

    Allers, K N

    2013-01-01

    We present a near-infrared (0.9-2.4 microns) spectroscopic study of 73 field ultracool dwarfs having spectroscopic and/or kinematic evidence of youth (~10-300 Myr). Our sample is composed of 48 low-resolution (R~100) spectra and 41 moderate-resolution spectra (R>~750-2000). First, we establish a method for spectral typing M5-L7 dwarfs at near-IR wavelengths that is independent of gravity. We find that both visual and index-based classification in the near-IR provide consistent spectral types with optical spectral types, though with a small systematic offset in the case of visual classification at J and K band. Second, we examine features in the spectra of ~10 Myr ultracool dwarfs to define a set of gravity-sensitive indices based on FeH, VO, K, Na and H-band continuum shape. We then create an index-based method for classifying the gravities of M6-L5 dwarfs that provides consistent results with gravity classifications from optical spectroscopy. Our index-based classification can distinguish between young and d...

  14. Diagnosis of colorectal cancer by near-infrared optical fiber spectroscopy and random forest.

    Science.gov (United States)

    Chen, Hui; Lin, Zan; Wu, Hegang; Wang, Li; Wu, Tong; Tan, Chao

    2015-01-25

    Near-infrared (NIR) spectroscopy has such advantages as being noninvasive, fast, relatively inexpensive, and no risk of ionizing radiation. Differences in the NIR signals can reflect many physiological changes, which are in turn associated with such factors as vascularization, cellularity, oxygen consumption, or remodeling. NIR spectral differences between colorectal cancer and healthy tissues were investigated. A Fourier transform NIR spectroscopy instrument equipped with a fiber-optic probe was used to mimic in situ clinical measurements. A total of 186 spectra were collected and then underwent the preprocessing of standard normalize variate (SNV) for removing unwanted background variances. All the specimen and spots used for spectral collection were confirmed staining and examination by an experienced pathologist so as to ensure the representative of the pathology. Principal component analysis (PCA) was used to uncover the possible clustering. Several methods including random forest (RF), partial least squares-discriminant analysis (PLSDA), K-nearest neighbor and classification and regression tree (CART) were used to extract spectral features and to construct the diagnostic models. By comparison, it reveals that, even if no obvious difference of misclassified ratio (MCR) was observed between these models, RF is preferable since it is quicker, more convenient and insensitive to over-fitting. The results indicate that NIR spectroscopy coupled with RF model can serve as a potential tool for discriminating the colorectal cancer tissues from normal ones.

  15. Near infrared fluorescent biliproteins generated from bacteriophytochrome AphB of Nostoc sp. PCC 7120.

    Science.gov (United States)

    Yuan, Che; Li, Hui-Zhen; Tang, Kun; Gärtner, Wolfgang; Scheer, Hugo; Zhou, Ming; Zhao, Kai-Hong

    2016-04-01

    The genome of the cyanobacterium Nostoc sp. PCC 7120 encodes a large number of putative bacteriophytochrome and cyanobacteriochrome photoreceptors that, due to their long-wavelength absorption and fluorescence emission, might serve as fluorescent tags in intracellular investigations. We show that the PAS-GAF domain of the bacteriophytochrome, AphB, binds biliverdin covalently and exhibits, besides its reversible photochemistry, a moderate fluorescence in the near infrared (NIR) spectral region. It was selected for further increasing the brightness while retaining the NIR fluorescence. In the first step, amino acids assumed to improve fluorescence were selectively mutated. The resulting variants were then subjected to several rounds of random mutagenesis and screened for enhanced fluorescence in the NIR. The brightness of optimized PAS-GAF variants increased more than threefold compared to that of wt AphB(1-321), with only insignificant spectral shifts (Amax around 695 nm, and Fmax around 720 nm). In general, the brightness increases with decreasing wavelengths, which allows for a selection of the fluorophore depending on the optical properties of the tissue. A spectral heterogeneity was observed when residue His260, located in close proximity to the chromophore, was mutated to Tyr, emphasizing the strong effects of the environment on the electronic properties of the bound biliverdin chromophore.

  16. Maize kernel hardness classification by near infrared (NIR) hyperspectral imaging and multivariate data analysis.

    Science.gov (United States)

    Williams, Paul; Geladi, Paul; Fox, Glen; Manley, Marena

    2009-10-27

    The use of near infrared (NIR) hyperspectral imaging and hyperspectral image analysis for distinguishing between hard, intermediate and soft maize kernels from inbred lines was evaluated. NIR hyperspectral images of two sets (12 and 24 kernels) of whole maize kernels were acquired using a Spectral Dimensions MatrixNIR camera with a spectral range of 960-1662 nm and a sisuChema SWIR (short wave infrared) hyperspectral pushbroom imaging system with a spectral range of 1000-2498 nm. Exploratory principal component analysis (PCA) was used on absorbance images to remove background, bad pixels and shading. On the cleaned images, PCA could be used effectively to find histological classes including glassy (hard) and floury (soft) endosperm. PCA illustrated a distinct difference between glassy and floury endosperm along principal component (PC) three on the MatrixNIR and PC two on the sisuChema with two distinguishable clusters. Subsequently partial least squares discriminant analysis (PLS-DA) was applied to build a classification model. The PLS-DA model from the MatrixNIR image (12 kernels) resulted in root mean square error of prediction (RMSEP) value of 0.18. This was repeated on the MatrixNIR image of the 24 kernels which resulted in RMSEP of 0.18. The sisuChema image yielded RMSEP value of 0.29. The reproducible results obtained with the different data sets indicate that the method proposed in this paper has a real potential for future classification uses.

  17. Effect of Sampling Frequency for Real-Time Tablet Coating Monitoring Using Near Infrared Spectroscopy.

    Science.gov (United States)

    Igne, Benoît; Arai, Hiroaki; Drennen, James K; Anderson, Carl A

    2016-09-01

    While the sampling of pharmaceutical products typically follows well-defined protocols, the parameterization of spectroscopic methods and their associated sampling frequency is not standard. Whereas, for blending, the sampling frequency is limited by the nature of the process, in other processes, such as tablet film coating, practitioners must determine the best approach to collecting spectral data. The present article studied how sampling practices affected the interpretation of the results provided by a near-infrared spectroscopy method for the monitoring of tablet moisture and coating weight gain during a pan-coating experiment. Several coating runs were monitored with different sampling frequencies (with or without co-adds (also known as sub-samples)) and with spectral averaging corresponding to processing cycles (1 to 15 pan rotations). Beyond integrating the sensor into the equipment, the present work demonstrated that it is necessary to have a good sense of the underlying phenomena that have the potential to affect the quality of the signal. The effects of co-adds and averaging was significant with respect to the quality of the spectral data. However, the type of output obtained from a sampling method dictated the type of information that one can gain on the dynamics of a process. Thus, different sampling frequencies may be needed at different stages of process development.

  18. A Monitoring Campaign for Luhman 16AB. I. Detection of Resolved Near-Infrared Spectroscopic Variability

    CERN Document Server

    Burgasser, Adam J; Faherty, Jacqueline K; Radigan, Jacqueline; J., Amaury H M; Plavchan, Peter; Street, Rachel; Jehin, E; Delrez, L; Opitom, C

    2014-01-01

    [abbreviated] We report resolved near-infrared spectroscopic monitoring of the nearby L dwarf/T dwarf binary WISE J104915.57-531906.1AB (Luhman 16AB), as part of a broader campaign to characterize the spectral energy distribution and temporal variability of this system. A continuous 45-minute sequence of low-resolution IRTF/SpeX data spanning 0.8-2.4 micron were obtained, concurrent with combined-light optical photometry with ESO/TRAPPIST. Our spectral observations confirm the flux reversal of this binary, and we detect a wavelength-dependent decline in the relative spectral fluxes of the two components coincident with a decline in the combined-light optical brightness of the system over the course of the observation. These data are successfully modeled as a combination of brightness and color variability in the T0.5 Luhman 16B, consistent cloud variations; and no significant variability in L7.5 Luhman 16A. We estimate a peak-to-peak amplitude of 13.5% at 1.25 micron over the full lightcurve. Using a two-spot...

  19. Near infrared cavity enhanced absorption spectra of atmospherically relevant ether-1, 4-Dioxane

    Science.gov (United States)

    Chandran, Satheesh; Varma, Ravi

    2016-01-01

    1, 4-Dioxane (DX) is a commonly found ether in industrially polluted atmosphere. The near infrared absorption spectra of this compound has been recorded in the region 5900-8230 cm- 1 with a resolution of 0.08 cm- 1 using a novel Fourier transform incoherent broadband cavity-enhanced absorption spectrometer (FT-IBBCEAS). All recorded spectra were found to contain regions that are only weakly perturbed. The possible combinations of fundamental modes and their overtone bands corresponding to selected regions in the measured spectra are tabulated. Two interesting spectral regions were identified as 5900-6400 cm- 1 and 8100-8230 cm- 1. No significant spectral interference due to presence of water vapor was observed suggesting the suitability of these spectral signatures for spectroscopic in situ detection of DX. The technique employed here is much more sensitive than standard Fourier transform spectrometer measurements on account of long effective path length achieved. Hence significant enhancement of weaker absorption lines above the noise level was observed as demonstrated by comparison with an available measurement from database.

  20. Detection of UV-induced cyclobutane pyrimidine dimers by near-infrared spectroscopy and aquaphotomics.

    Science.gov (United States)

    Goto, Noriko; Bazar, Gyorgy; Kovacs, Zoltan; Kunisada, Makoto; Morita, Hiroyuki; Kizaki, Seiichiro; Sugiyama, Hiroshi; Tsenkova, Roumiana; Nishigori, Chikako

    2015-07-02

    Ultraviolet (UV) radiation causes cellular DNA damage, among which cyclobutane pyrimidine dimers (CPDs) are responsible for a variety of genetic mutations. Although several approaches have been developed for detection of CPDs, conventional methods require time-consuming steps. Aquaphotomics, a new approach based on near-infrared spectroscopy (NIRS) and multivariate analysis that determines interactions between water and other components of the solution, has become an effective method for qualitative and quantitative parameters measurement in the solutions. NIR spectral patterns of UVC-irradiated and nonirradiated DNA solutions were evaluated using aquaphotomics for detection of UV-induced CPDs. Groups of UV-irradiated and nonirradiated DNA samples were classified (87.5% accuracy) by soft independent modeling of class analogy (SIMCA). A precise regression model calculated from NIR water spectral patterns based on UVC doses (r Val = 0.9457) and the concentration of cis-syn cyclobutane thymine dimers (cis-syn TTs; r Val = 0.9993) was developed using partial least squares regression (PLSR), while taking advantage of water spectral patterns, particularly around 1400-1500 nm. Our results suggested that, in contrast to DNA, the formation of cis-syn TTs increased the strongly hydrogen bonded water. Additionally, NIRS could qualitatively and quantitatively detect cis-syn TTs in isolated DNA aqueous solutions upon UVC exposure.

  1. Study of Fast, Near-Infrared Photodetectors for the ITER Core LIDAR Thomson Scattering

    Science.gov (United States)

    Giudicotti, L.; Pasqualotto, R.; Alfier, A.; Beurskens, M.; Kempenaars, M.; Walsh, M. J.

    2008-03-01

    A key component for the ITER core LIDAR Thomson Scattering (TS) diagnostic would be a detector with good sensitivity in the 850-1060 nm near infrared (NIR) spectral region. Covering this spectral region becomes necessary if a Nd:YAG laser system operating at λ = 1.06 μm is used as the laser source, which is a very attractive choice in terms of available energy, repetition rate, reliability and cost. In this paper we review the state of the art of two types of detectors available for the above spectral range: the transferred electron (TE) InGaAs/InP hybrid photodiode and the InxGa1-xAs microchannel plate (MCP) image intensifier and we describe the advancements necessary for a possible application in the ITER LIDAR TS. In addition we describe the preliminary characterization of new GaAsP fast MCP photomultipliers (PMTs) suitable for the detection of the visible part of the LIDAR TS spectrum in JET and ITER.

  2. Evaluation of cross-polarized near infrared hyperspectral imaging for early detection of dental caries

    Science.gov (United States)

    Usenik, Peter; Bürmen, Miran; Fidler, Aleš; Pernuš, Franjo; Likar, Boštjan

    2012-01-01

    Despite major improvements in dental healthcare and oral hygiene, dental caries remains one of the most prevalent oral diseases and represents the primary cause of oral pain and tooth loss. The initial stages of dental caries are characterized by demineralization of enamel crystals and are difficult to diagnose. Near infrared (NIR) hyperspectral imaging is a new promising technique for detection of early changes in the surfaces of carious teeth. This noninvasive imaging technique can characterize and differentiate between the sound tooth surface and initial or advanced tooth caries. The absorbing and scattering properties of dental tissues reflect in distinct spectral features, which can be measured, quantified and used to accurately classify and map different dental tissues. Specular reflections from the tooth surface, which appear as bright spots, mostly located around the edges and the crests of the teeth, act as a noise factor which can significantly interfere with the spectral measurements and analysis of the acquired images, degrading the accuracy of the classification and diagnosis. Employing cross-polarized imaging setup can solve this problem, however has yet to be systematically evaluated, especially in broadband hyperspectral imaging setups. In this paper, we employ cross-polarized illumination setup utilizing state-of-the-art high-contrast broadband wire-grid polarizers in the spectral range from 900 nm to 1700 nm for hyperspectral imaging of natural and artificial carious lesions of various degrees.

  3. A Frequency Domain Method for the Generation of Partially Coherent Normal Stationary Time Domain Signals

    Directory of Open Access Journals (Sweden)

    David O. Smallwood

    1993-01-01

    , that relates pairs of elements of the vector random process {X(t},−∞spectral density matrix is decomposed into the form [Gxx(f]=[U(f][S(f][U(f]' where [U(f] is a matrix of complex frequency response functions, and [S(f] is a diagonal matrix of real functions that can vary with frequency. The factors of the spectral density matrix, [U(f] and [S(f], are then used to generate a frame of random data in the frequency domain. The data is transformed into the time domain using an inverse FFT to generate a frame of data in the time domain. Successive frames of data are then windowed, overlapped, and added to form a vector of normal stationary sampled time histories, {X(t}, of arbitrary length.

  4. Non-thermal DNA damage of cancer cells using near-infrared irradiation.

    Science.gov (United States)

    Tanaka, Yohei; Tatewaki, Naoto; Nishida, Hiroshi; Eitsuka, Takahiro; Ikekawa, Nobuo; Nakayama, Jun

    2012-08-01

    Previously, we reported that near-infrared irradiation that simulates solar near-infrared irradiation with pre- and parallel-irradiational cooling can non-thermally induce cytocidal effects in cancer cells. To explore these effects, we assessed cell viability, DNA damage response pathways, and the percentage of mitotic cancer cells after near-infrared treatment. Further, we evaluated the anti-cancer effects of near-infrared irradiation compared with doxorubicin in xenografts in nude mice by measuring tumor volume and assessing protein phosphorylation by immunoblot analysis. The cell viability of A549 lung adenocarcinoma cells was significantly decreased after three rounds of near-infrared irradiation at 20 J/cm(2). Apoptotic cells were observed in near-infrared treated cells. Moreover, near-infrared treatment increased the phosphorylation of ataxia-telangiectasia mutated (ATM) at Ser(1981), H2AX at Ser(139), Chk1 at Ser(317), structural maintenance of chromosome (SMC) 1 at Ser(966), and p53 at Ser(15) in A549 cells compared with control. Notably, near-infrared treatment induced the formation of nucleic foci of γH2AX. The percentage of mitotic A549 cells, as measured by histone H3 phosphorylation, decreased significantly after three rounds of near-infrared irradiation at 20 J/cm(2). Both near-infrared and doxorubicin inhibited the tumor growth of MDA-MB435 melanoma cell xenografts in nude mice and increased the phosphorylation of p53 at Ser(15), Chk1 at Ser(317), SMC1 at Ser(966), and H2AX at Ser(139) compared with control mice. These results indicate that near-infrared irradiation can non-thermally induce cytocidal effects in cancer cells as a result of activation of the DNA damage response pathway. The near-infrared irradiation schedule used here reduces discomfort and side effects. Therefore, this strategy may have potential application in the treatment of cancer.

  5. Gratings and Random Reflectors for Near-Infrared PIN Diodes

    Science.gov (United States)

    Gunapala, Sarath; Bandara, Sumith; Liu, John; Ting, David

    2007-01-01

    Crossed diffraction gratings and random reflectors have been proposed as means to increase the quantum efficiencies of InGaAs/InP positive/intrinsic/ negative (PIN) diodes designed to operate as near-infrared photodetectors. The proposal is meant especially to apply to focal-plane imaging arrays of such photodetectors to be used for near-infrared imaging. A further increase in quantum efficiency near the short-wavelength limit of the near-infrared spectrum of such a photodetector array could be effected by removing the InP substrate of the array. The use of crossed diffraction gratings and random reflectors as optical devices for increasing the quantum efficiencies of quantum-well infrared photodetectors (QWIPs) was discussed in several prior NASA Tech Briefs articles. While the optical effects of crossed gratings and random reflectors as applied to PIN photodiodes would be similar to those of crossed gratings and random reflectors as applied to QWIPs, the physical mechanisms by which these optical effects would enhance efficiency differ between the PIN-photodiode and QWIP cases: In a QWIP, the multiple-quantum-well layers are typically oriented parallel to the focal plane and therefore perpendicular or nearly perpendicular to the direction of incidence of infrared light. By virtue of the applicable quantum selection rules, light polarized parallel to the focal plane (as normally incident light is) cannot excite charge carriers and, hence, cannot be detected. A pair of crossed gratings or a random reflector scatters normally or nearly normally incident light so that a significant portion of it attains a component of polarization normal to the focal plane and, hence, can excite charge carriers. A pair of crossed gratings or a random reflector on a PIN photodiode would also scatter light into directions away from the perpendicular to the focal plane. However, in this case, the reason for redirecting light away from the perpendicular is to increase the length of the

  6. [Analysis of tobacco site features using near-infrared spectroscopy and projection model].

    Science.gov (United States)

    Yang, Kai; Cai, Jia-yue; Zhang, Chao-ping; Shu, Ru-xin; Liang, Miao; Zhao, Long-lian; Zhang, Lu-da; Zhang, Ye-hui; Li, Jun-hui

    2014-12-01

    In this paper, total of 5170 flue-cured tobacco samples collected from 2003 to 2012 in the domestic and foreign origin by Shanghai Tobacco Group Technical Center were tested by near infrared spectroscopy, including the typical upper leaves 1394, central 2550, the lower part of 1226. Using projection model of based on principal component and Fisher criterion (PPF), follow the projected results to get no statistically significant differences at adjacent principal components, and the number of principal components as little as possible, in this paper, four main components to build projection analysis model, the model results show that: the near-infrared spectral characteristics of the upper and lower leaves have a significant difference that can be achieved almost entirely distinguished; while the middle leaves with upper and lower have a certain degree of overlap, which is consistent to the actual situation of the continuity of tobacco leaf. At the same time, Euclidean distance between the predicted sample projection values and the mean projection values of each class in the model, a description is given for the prediction samples to quantify the extent of the site features, and its first and second close categories. Using the dispersion of projected values in model and the given threshold value, prediction results can be refined into typically upper, upper to central, central to upper, typical central, central to the lower, the lower to central, typically the lower, or super-model range. The model was validated by 34 tobacco samples obtained from the re-drying process in 2012 with different origins and parts. This kind of analysis methods, not only can achieve discriminant analysis, and get richer feature attribute information, can provide guidance on the raw tobacco processing and formulations.

  7. THE EARLIEST NEAR-INFRARED TIME-SERIES SPECTROSCOPY OF A TYPE Ia SUPERNOVA

    Energy Technology Data Exchange (ETDEWEB)

    Hsiao, E. Y.; Phillips, M. M.; Morrell, N.; Contreras, C.; Roth, M. [Carnegie Observatories, Las Campanas Observatory, Colina El Pino, Casilla 601 (Chile); Marion, G. H.; Kirshner, R. P. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Burns, C. R.; Freedman, W. L.; Persson, S. E. [Carnegie Observatories, 813 Santa Barbara St, Pasadena, CA 91101 (United States); Winge, C. [Gemini South Observatory, c/o AURA Inc., Casilla 603, La Serena (Chile); Kromer, M.; Gall, E. E. E. [Max-Planck-Institut fuer Astrophysik, Karl-Schwarzschild-Str. 1, D-85741 Garching bei Muenchen (Germany); Gerardy, C. L.; Hoeflich, P. [Department of Physics, Florida State University, Tallahassee, FL 32306 (United States); Im, M.; Jeon, Y. [CEOU/Astronomy Program, Department of Physics and Astronomy, Seoul National University, Seoul (Korea, Republic of); Nugent, P. E. [Computational Cosmology Center, Computational Research Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road MS 50B-4206, Berkeley, CA 94611 (United States); Pignata, G. [Departamento de Ciencias Fisicas, Universidad Andres Bello, Avda. Republica 252, Santiago (Chile); Stanishev, V., E-mail: hsiao@lco.cl [CENTRA - Centro Multidisciplinar de Astrofisica, Instituto Superior Tecnico, Av. Rovisco Pais 1, 1049-001 Lisbon (Portugal); and others

    2013-04-01

    We present ten medium-resolution, high signal-to-noise ratio near-infrared (NIR) spectra of SN 2011fe from SpeX on the NASA Infrared Telescope Facility (IRTF) and Gemini Near-Infrared Spectrograph (GNIRS) on Gemini North, obtained as part of the Carnegie Supernova Project. This data set constitutes the earliest time-series NIR spectroscopy of a Type Ia supernova (SN Ia), with the first spectrum obtained at 2.58 days past the explosion and covering -14.6 to +17.3 days relative to B-band maximum. C I {lambda}1.0693 {mu}m is detected in SN 2011fe with increasing strength up to maximum light. The delay in the onset of the NIR C I line demonstrates its potential to be an effective tracer of unprocessed material. For the first time in a SN Ia, the early rapid decline of the Mg II {lambda}1.0927 {mu}m velocity was observed, and the subsequent velocity is remarkably constant. The Mg II velocity during this constant phase locates the inner edge of carbon burning and probes the conditions under which the transition from deflagration to detonation occurs. We show that the Mg II velocity does not correlate with the optical light-curve decline rate {Delta}m{sub 15}(B). The prominent break at {approx}1.5 {mu}m is the main source of concern for NIR k-correction calculations. We demonstrate here that the feature has a uniform time evolution among SNe Ia, with the flux ratio across the break strongly correlated with {Delta}m{sub 15}(B). The predictability of the strength and the onset of this feature suggests that the associated k-correction uncertainties can be minimized with improved spectral templates.

  8. Wide-field near-infrared fluorescence endoscope for real-time in vivo imaging

    Science.gov (United States)

    Liu, Zhongyao; Miller, Sharon J.; Joshi, Bishnu P.; Wang, Thomas D.

    2012-02-01

    A diode-pumped solid state laser is used to deliver excitation at λex = 671 nm. The beam is expanded by a pair of relay lenses (f1 = 30 and f2 = 50 mm) to 3 mm diameter, filling the aperture of a fluid light cable that is coupled to a Hopkins II rigid endoscope. Near-infrared fluorescence images are collected by the endoscope and transmitted by another set of relay lenses onto a CCD detector that has dimensions of 8.7x6.9 mm2 (1388x1040 pixels). A zoom lens system (F#1.6-16 aperture) with a tunable focal length (20-100 mm) magnifies the image to fill the dimensions of the CCD. A band pass filter allows fluorescence with spectral range λem = 696 to 736 nm to be collected. The system achieves a resolution of 9.8 μm and field-of-view of 3.6 mm at a distance of 2.5 mm between the distal end of the endoscope and the tissue. Images are collected at a rate of 10 frames per second. A filter wheel is incorporated into the handle of the instrument housing to rapidly switch between reflectance and fluorescence images. Cy5.5-labeled peptides were delivered through the 1 mm diameter instrument channel in the endoscope. Near-infrared fluorescence images demonstrated specific peptide binding to spontaneous adenomas that developed beginning at 2 months of age in a genetically-engineered mouse with mutation of one allele in the APC gene. This integrated methodology represents a powerful tool that can achieve real time detection of disease in the colon and other hollow organs.

  9. Visible-near infrared spectroscopy as a tool to improve mapping of soil properties

    Science.gov (United States)

    Evgrafova, Alevtina; Kühnel, Anna; Bogner, Christina; Haase, Ina; Shibistova, Olga; Guggenberger, Georg; Tananaev, Nikita; Sauheitl, Leopold; Spielvogel, Sandra

    2017-04-01

    Spectroscopic measurements, which are non-destructive, precise and rapid, can be used to predict soil properties and help estimate the spatial variability of soil properties at the pedon scale. These estimations are required for quantifying soil properties with higher precision, identifying the changes in soil properties and ecosystem response to climate change as well as increasing the estimation accuracy of soil-related models. Our objectives were to (i) predict soil properties for nested samples (n = 296) using the laboratory-based visible-near infrared (vis-NIR) spectra of air-dried (Germany). Inorganic C was removed from the mineral soil samples with pH values higher than 7 prior to the elemental analysis using the volatilization method (HCl, 6 hours). The pH of soil samples was measured in 0.01 M CaCl2 using a 1:2 soil:solution ratio. However, for soil sample with a high in organic matter content, a 1:10 ratio was applied. We also measured oxalate and dithionite extracted iron, aluminum and manganese oxides and hydroxides using inductively coupled plasma optical emission spectroscopy (Varian Vista MPX ICP-OES, Agilent Technologies, USA). We predicted the above-mentioned soil properties for all nested samples using partial least squares regression, which was performed using R program. We can conclude that vis-NIR spectroscopy can be used effectively in order to describe, estimate and further map the spatial patterns of soil properties using geostatistical methods. This research could also help to improve the global soil spectral library taking into account that only few previous applications of vis-NIR spectroscopy were conducted on permafrost-affected soils of Northern Siberia. Keywords: Visible-near infrared spectroscopy, vis-NIR, permafrost-affected soils, Siberia, partial least squares regression.

  10. Optical and near-infrared linear polarization of low and intermediate-gravity ultracool dwarfs

    Science.gov (United States)

    Miles-Páez, P. A.; Zapatero Osorio, M. R.; Pallé, E.; Peña Ramírez, K.

    2017-04-01

    We aim to study the optical and near-infrared linear polarimetric properties of a sample of young M7-L7 dwarfs (≈ 1-500 Myr) with spectroscopic signatures of low- and intermediate-gravity atmospheres. We collected optical (RIZ) and near-infrared (YJHKs) linear polarimetry images on various time-scales from ∼0.2 h to months. Linear polarization degrees in the interval 0-1.5 per cent (I and J bands) were measured with accuracies ranging from ±0.1 to ±0.9 per cent depending on the observing filter and the target brightness. We found that the young field dwarfs in our sample show similar polarimetric degrees at both I and J bands, and that there is no obvious trend with the spectral type. The two Taurus sources in our sample show intense levels of J-band linear polarization probably due to surrounding discs. By compiling data from the literature for high-gravity M7-L7 dwarfs with likely ages ≥500 Myr, we did not observe any apparent difference in the linear polarimetry intensity between the young and old samples that could be ascribed to differing atmospheric gravities. Polarimetric variability with peak to peak amplitudes up to 1.5 per cent is detected on scales of about a rotation in two out of four targets that were monitored over several hours. Long-term polarimetric variability is also detected in nearly all dwarfs of the sample with data spanning months to years.

  11. Characterization of red-near infrared transition for wheat and chickpea using 3 nm bandwidth data

    Science.gov (United States)

    Gupta, R. K.; Vijayan, D.; Prasad, T. S.

    2001-01-01

    Enhancement of space based capabilities to discriminate different crops and different varieties of a particular crop needs measurement of (i) the shift in red edge and (ii) the slope of the sudden rise of reflectance in 680 - 760 nm spectral region as a function of Days After Sowing (DAS). To develop the knowledge base for catering to the analysis of future space-based hyperspectral measurements, ground based measurements in 3 nm bandwidth in visible - near Infrared region together with corresponding Leaf Area Index (LAI) observations were taken over the Crop Growth Cycle (CGC) of Wheat and Chickpea. The red edge for wheat crop was at 679 nm for 25 DAS and reached the upper limit i.e., 693.7 nm at 84 DAS and thereafter shifted backward to 679 nm at 108 DAS. There was no change in red edge value of 684.9 nm during 40 to 49 DAS and of 687.8 nm during 55 to 71 DAS. The slope of Red to NIR transition for wheat varied from 0.457 to peak value of 0.784 during 25 to 71 DAS and thereafter decreased to 0.073 at 108 DAS. The peak of Red to Near Infrared (NIR) transition slope and Ratio Vegetation Index (RVI) occurred at the same time i.e., 71 DAS. However, the upper most value of red edge shift occurred at 84 DAS. Paper discusses the above aspects including role of mid point of Red to NIR transition, interrelationships among the Red-NIR transition Slope, Red Edge, LAI and RVI for wheat and chickpea.

  12. Biodiesel classification by base stock type (vegetable oil) using near infrared spectroscopy data

    Energy Technology Data Exchange (ETDEWEB)

    Balabin, Roman M., E-mail: balabin@org.chem.ethz.ch [Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zurich (Switzerland); Safieva, Ravilya Z. [Gubkin Russian State University of Oil and Gas, 119991 Moscow (Russian Federation)

    2011-03-18

    The use of biofuels, such as bioethanol or biodiesel, has rapidly increased in the last few years. Near infrared (near-IR, NIR, or NIRS) spectroscopy (>4000 cm{sup -1}) has previously been reported as a cheap and fast alternative for biodiesel quality control when compared with infrared, Raman, or nuclear magnetic resonance (NMR) methods; in addition, NIR can easily be done in real time (on-line). In this proof-of-principle paper, we attempt to find a correlation between the near infrared spectrum of a biodiesel sample and its base stock. This correlation is used to classify fuel samples into 10 groups according to their origin (vegetable oil): sunflower, coconut, palm, soy/soya, cottonseed, castor, Jatropha, etc. Principal component analysis (PCA) is used for outlier detection and dimensionality reduction of the NIR spectral data. Four different multivariate data analysis techniques are used to solve the classification problem, including regularized discriminant analysis (RDA), partial least squares method/projection on latent structures (PLS-DA), K-nearest neighbors (KNN) technique, and support vector machines (SVMs). Classifying biodiesel by feedstock (base stock) type can be successfully solved with modern machine learning techniques and NIR spectroscopy data. KNN and SVM methods were found to be highly effective for biodiesel classification by feedstock oil type. A classification error (E) of less than 5% can be reached using an SVM-based approach. If computational time is an important consideration, the KNN technique (E = 6.2%) can be recommended for practical (industrial) implementation. Comparison with gasoline and motor oil data shows the relative simplicity of this methodology for biodiesel classification.

  13. Intraoperative near-infrared fluorescent imaging during robotic operations.

    Science.gov (United States)

    Macedo, Antonio Luiz de Vasconcellos; Schraibman, Vladimir

    2016-01-01

    The intraoperative identification of certain anatomical structures because they are small or visually occult may be challenging. The development of minimally invasive surgery brought additional difficulties to identify these structures due to the lack of complete tactile sensitivity. A number of different forms of intraoperative mapping have been tried. Recently, the near-infrared fluorescence imaging technology with indocyanine green has been added to robotic platforms. In addition, this technology has been tested in several types of operations, and has advantages such as safety, low cost and good results. Disadvantages are linked to contrast distribution in certain clinical scenarios. The intraoperative near-infrared fluorescent imaging is new and promising addition to robotic surgery. Several reports show the utility of this technology in several different procedures. The ideal dose, time and site for dye injection are not well defined. No high quality evidence-based comparative studies and long-term follow-up outcomes have been published so far. Initial results, however, are good and safe. RESUMO A identificação intraoperatória de certas estruturas anatômicas, por seu tamanho ou por elas serem ocultas à visão, pode ser desafiadora. O desenvolvimento da cirurgia minimamente invasiva trouxe dificuldades adicionais, pela falta da sensibilidade tátil completa. Diversas formas de detecção intraoperatória destas estruturas têm sido tentadas. Recentemente, a tecnologia de fluorescência infravermelha com verde de indocianina foi associada às plataformas robóticas. Além disso, essa tecnologia tem sido testada em uma variedade de cirurgias, e suas vantagens parecem estar ligadas a baixo custo, segurança e bons resultados. As desvantagens estão associadas à má distribuição do contraste em determinados cenários. A imagem intraoperatória por fluorescência infravermelha é uma nova e promissora adição à cirurgia robótica. Diversas séries mostram

  14. Practical Steps for Applying a New Dynamic Model to Near-Infrared Spectroscopy Measurements of Hemodynamic Oscillations and Transient Changes

    Science.gov (United States)

    Kainerstorfer, Jana M.; Sassaroli, Angelo; Hallacoglu, Bertan; Pierro, Michele L.; Fantini, Sergio

    2015-01-01

    Rationale and Objectives Perturbations in cerebral blood volume (CBV), blood flow (CBF), and metabolic rate of oxygen (CMRO2) lead to associated changes in tissue concentrations of oxy- and deoxy-hemoglobin (ΔO and ΔD), which can be measured by near-infrared spectroscopy (NIRS). A novel hemodynamic model has been introduced to relate physiological perturbations and measured quantities. We seek to use this model to determine functional traces of cbv(t) and cbf(t) − cmro2(t) from time-varying NIRS data, and cerebrovascular physiological parameters from oscillatory NIRS data (lowercase letters denote the relative changes in CBV, CBF, and CMRO2 with respect to baseline). Such a practical implementation of a quantitative hemodynamic model is an important step toward the clinical translation of NIRS. Materials and Methods In the time domain, we have simulated O(t) and D(t) traces induced by cerebral activation. In the frequency domain, we have performed a new analysis of frequency-resolved measurements of cerebral hemodynamic oscillations during a paced breathing paradigm. Results We have demonstrated that cbv(t) and cbf(t) − cmro2(t) can be reliably obtained from O(t) and D(t) using the model, and that the functional NIRS signals are delayed with respect to cbf(t) − cmro2(t) as a result of the blood transit time in the microvasculature. In the frequency domain, we have identified physiological parameters (e.g., blood transit time, cutoff frequency of autoregulation) that can be measured by frequency-resolved measurements of hemodynamic oscillations. Conclusions The ability to perform noninvasive measurements of cerebrovascular parameters has far-reaching clinical implications. Functional brain studies rely on measurements of CBV, CBF, and CMRO2, whereas the diagnosis and assessment of neurovascular disorders, traumatic brain injury, and stroke would benefit from measurements of local cerebral hemodynamics and autoregulation. PMID:24439332

  15. Random vibration of linear and nonlinear structural systems with singular matrices: A frequency domain approach

    Science.gov (United States)

    Kougioumtzoglou, I. A.; Fragkoulis, V. C.; Pantelous, A. A.; Pirrotta, A.

    2017-09-01

    A frequency domain methodology is developed for stochastic response determination of multi-degree-of-freedom (MDOF) linear and nonlinear structural systems with singular matrices. This system modeling can arise when a greater than the minimum number of coordinates/DOFs is utilized, and can be advantageous, for instance, in cases of complex multibody systems where the explicit formulation of the equations of motion can be a nontrivial task. In such cases, the introduction of additional/redundant DOFs can facilitate the formulation of the equations of motion in a less labor intensive manner. Specifically, relying on the generalized matrix inverse theory, a Moore-Penrose (M-P) based frequency response function (FRF) is determined for a linear structural system with singular matrices. Next, relying on the M-P FRF a spectral input-output (excitation-response) relationship is derived in the frequency domain for determining the linear system response power spectrum. Further, the above methodology is extended via statistical linearization to account for nonlinear systems. This leads to an iterative determination of the system response mean vector and covariance matrix. Furthermore, to account for singular matrices, the generalization of a widely utilized formula that facilitates the application of statistical linearization is proved as well. The formula relates to the expectation of the derivatives of the system nonlinear function and is based on a Gaussian response assumption. Several linear and nonlinear MDOF structural systems with singular matrices are considered as numerical examples for demonstrating the validity and applicability of the developed frequency domain methodology.

  16. A frequency domain approach to handling qualities design

    Science.gov (United States)

    Wolovich, W. A.

    1978-01-01

    A method for designing linear multivariable feedback control systems based on desired closed loop transfer matrix information is introduced. The technique which was employed to achieve the final design was based on a theoretical result, known as the structure theorem. The structure theorem was a frequency domain relationship which simplified the expression for the transfer matrix (matrix of transfer functions) of a linear time-invariant multivariable system. The effect of linear state variable feedback on the closed loop transfer matrix of the system was also clarified.

  17. Statistical multiresolution analysis in amplitude-frequency domain

    Institute of Scientific and Technical Information of China (English)

    SUN Hong; GUAN Bao; Henri Maitre

    2004-01-01

    A concept of statistical multiresolution analysis in amplitude-frequency domain is proposed, which is to employ the wavelet transform on the statistical character of a signal in amplitude domain. In terms of the theorem of generalized ergodicity, an algorithm to estimate the transform coefficients based on the amplitude statistical multiresolution analysis (AMA) is presented. The principle of applying the AMA to Synthetic Aperture Radar (SAR) image processing is described, and the good experimental results imply that the AMA is an efficient tool for processing of speckled signals modeled by the multiplicative noise.

  18. Small signal frequency domain model of an HVDC converter

    Energy Technology Data Exchange (ETDEWEB)

    Osauskas, C.M.; Hume, D.J.; Wood, A.R. [UnIversity of Canterbury, Christchurch (New Zealand). Dept. of Electrical and Electronic Engineering

    2001-11-01

    A small-signal analytic frequency domain model of a 6-pulse HVDC converter is presented. The model consists of a set of explicit algebraic equations which relate the transfer of distortion from AC voltage, DC current and firing angle modulation, to AC current and DC voltage. The equations represent the linearisation of the transfers around a base operating point, and are derived from a piecewise linear description of the AC current and DC voltage waveforms. The model provides an understanding of the transfer of distortion by the converter and is in excellent agreement with time domain simulations. (author)

  19. Baseband feedback for SAFARI-SPICA using Frequency Domain Multiplexing

    Science.gov (United States)

    Bounab, A.; de Korte, P.; Cros, A.; van der Kuur, J.; van Leeuwen, B. J.; Monna, B.; Mossel, R.; Nieuwenhuizen, A.; Ravera, L.

    We report on the performance of the digital baseband feedback circuit developed to readout and process signals from arrays of transition edge sensors for SPICA-SAFARI in frequency domain multiplexing (FDM). The standard procedure to readout the SQUID current amplifiers is to use a feedback loop (flux-locked loop: FLL). However the achievable FFL bandwidth is limited by the cable transport delay t_d, which makes standard feedback inconvenient. A much better approach is to use baseband feedback. We have developed a model of the electronic readout chain for SPICA-SAFARI instrument by using an Anlog-digital co-simulation based on Simulink-System Generator environment.

  20. Selection of representative calibration sample sets for near-infrared reflectance spectroscopy to predict nitrogen concentration in grasses

    DEFF Research Database (Denmark)

    Shetty, Nisha; Rinnan, Åsmund; Gislum, René

    2012-01-01

    The effect of using representative calibration sets with fewer samples was explored and discussed. The data set consisted of near-infrared reflectance (NIR) spectra of grass samples. The grass samples were taken from different years covering a wide range of species and cultivars. Partial least...... squares regression (PLSR), a chemometric method, has been applied on NIR spectroscopy data for the determination of the nitrogen (N) concentration in these grass samples. The sample selection method based on NIR spectral data proposed by Puchwein and the CADEX (computer aided design of experiments...